EMMERICH_LIION_AKKU_14500_MIT_KABELN Ver. 01 001221199 Si En EMMERICH LIION AKKU 14500 MIT KABELN
User Manual: EMMERICH_LIION_AKKU_14500_MIT_KABELN - Ver. 01 Non-standard battery (rechargeable) 14500 Cable Li-ion Emmerich from Conrad.com
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Conrad Electronic SE, Klaus-Conrad-Str. 1, D-92240 Hirschau Item no.: 1221199 Material Safety Data Sheet 1. Product & Company Identification Product: LiIon rechargeable battery 14500 Manufacturer: Conrad Electronic SE Nominal voltage: 3,7 V Nominal capacity: 800 mAh Address: Klaus-Conrad-Str. 1, D-92240 Hirschau Telephone: +49 (0) 9604 / 40 - 8988 Date of issue: 22.07.2014 2. Information on Ingredients IMPORTANT NOTE: The battery should not be opened or exposed to heat because exposure of the following ingredients contained within could be harmful under some circumstances. Chemical Composition Weight% CAS No. Lithium 25 - 40% 12190-70-3 Graphite (natural) 10 - 20% 7782-42-5 Graphite (artificial) 7740-44-0 Electrolyte 10 - 20% ---- Iron 15 - 25% 7439-86-6 Copper cord 5 - 15% 7440-50-8 Stannum 2 - 4% 7440-31-5 3. Hazards Identification Preparation hazards and classification Not dangerous with normal use. Do not dismantle, open or shred Li-ion Battery. Exposure to the ingredients contained within or their ingredients products could be harmful. Appearance, Colour, and Odor Solid object with no odor, no colour. Primary Route(s) of Exposure These chemicals are contained in a sealed stainless steel enclosure. Risk of exposure occurs only if the cell is mechanically, thermally or electrically abused to the point of compromising the enclosure. If this occurs, exposure to the electrolyte solution contained within can occur by Inhalation, Ingestion, Eye contact and Skin contact. Potential Health Effects: ACUTE (short term): see Section 8 for exposure controls In the event that this battery has been ruptured, the electrolyte solution contained within the battery would be corrosive and can cause burns. Inhalation: Inhalation of materials from a sealed battery is not an expected route of exposure. Vapours or mists from a ruptured battery may cause respiratory irritation. Ingestion: Swallowing of materials from a sealed battery is not an expected route of exposure. Swallowing the contents of an open battery can cause serious chemical burns of mouth, oesophagus, and gastrointestinal tract. Page 1 of 8 Conrad Electronic SE, Klaus-Conrad-Str. 1, D-92240 Hirschau Item no.: 1221199 Material Safety Data Sheet Skin: Contact between the battery and skin will not cause any harm. Skin contact with contents of an open battery can cause severe irritation or burns to the skin. Eye: Contact between the battery and the eye will not cause any harm. Eye contact with contents of an open battery can cause severe irritation or burns to the eye. CHRONIC (long term): see Section 11 for additional toxicological data Medical Conditions Aggravated by Exposure Not applicable Reported as carcinogen Not applicable 4. First aid Measures Inhalation If contents of an opened battery are inhaled, remove source of contamination or move victim to fresh air. Obtain medical advice. Skin contact If skin contact with contents of an open battery occurs, as quickly as possible remove contaminated clothing, shoes and leather goods. Immediately flush with lukewarm, gently flowing water for at least 30 minutes. If irritation or pain persists, seek medical attention. Completely decontaminate clothing, shoes and leather goods before reuse or discard. Eye contact If eye contact with contents of an open battery occurs, immediately flush the contaminated eye(s) with lukewarm, gently flowing water for at least 30 minutes while holding the eyelids open. Neutral saline solution may be used as soon as it is available. If necessary, continue flushing during transport to emergency care facility. Take care not to rinse contaminated water into the unaffected eye or onto face. Quickly transport victim to an emergency care facility. Ingestion If ingestion of contents of an open battery occurs, never give anything by mouth if victim is rapidly losing consciousness, or is unconscious or convulsing. Have victim rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. Have victim drink 60 to 240 mL (2-8 oz.) of water. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Have victim rinse mouth with water again. Quickly transport victim to an emergency care facility. Page 2 of 8 Conrad Electronic SE, Klaus-Conrad-Str. 1, D-92240 Hirschau Item no.: 1221199 Material Safety Data Sheet 5. Fire Fighting Measures Flammable Properties In the event that this battery has been ruptured, the electrolyte solution contain within the battery would be flammable. Like any sealed container, battery cells may rupture when exposed to excessive heat; this could result in the release of flammable or corrosive materials. Suitable extinguishing Media Use extinguishing media suitable for the materials that are burning. Unsuitable extinguishing Media Not available Explosion Data Sensitivity to Mechanical Impact: This may result in rupture in extreme cases Sensitivity to Static Discharge: Not Applicable Specific Hazards arising from the chemical Fires involving Li-ion Battery can be controlled with water. When water is used, however, hydrogen gas may evolve. In a confined space, hydrogen gas can form an explosive mixture. In this situation, smothering agents are recommended to extinguish the fire Protective Equipment and precautions for firefighters As for any fire, evacuate the area and fight the fire from a safe distance. Wear a pressure-demand, self-contained breathing apparatus and full protective gear. Fight fire from a protected location or a safe distance. Use NIOSH/MSHA approved full-face self-contained breathing apparatus (SCBA) with full protective gear. NFPA Health: 0 Flammability: 0 Instability: 0 6. Accidental Release Measures Personal Precautions, protective equipment, and emergency procedures Restrict access to area until completion of clean-up. Do not touch the spilled material. Wear adequate personal protective equipment as indicated in Section 8. Environmental Precautions Prevent material from contaminating soil and from entering sewers or waterways. Methods and materials for Containment Stop the leak if safe to do so. Contain the spilled liquid with dry sand or earth. Clean up spills immediately. Methods and materials for cleaning up Absorb spilled material with an inert absorbent (dry sand or earth). Scoop contaminated absorbent into an acceptable waste container. Collect all contaminated absorbent and dispose of according to directions in Section 13. Scrub the area with detergent and water; collect all contaminated wash water for proper disposal. Page 3 of 8 Conrad Electronic SE, Klaus-Conrad-Str. 1, D-92240 Hirschau Item no.: 1221199 Material Safety Data Sheet 7. Handling and Storage Handling Don’t handling Li-ion Battery with metalwork. Do not open, dissemble, crush or burn battery. Ensure good ventilation/ exhaustion at the workplace. Prevent formation of dust. Information about protection against explosions and fires: Keep ignition sources away- Do not smoke. Storage If the Li-ion Battery are subject to storage for such a long term as more than 3 months, it is recommended to recharge the Liion Battery periodically. 3 months: -10 °C.....+40 °C, 45 to 85%RH And recommended at 0 °C.....+35 °C for long period storage. The capacity recovery rate in the delivery state (50% capacity of fully charged) after storage is assumed to be 80% or more. The voltage for a long time storage shall be 3.7V.....4.2V range. Do not storage Li-ion Battery haphazardly in a box or drawer where they may short-circuit each other or be short-circuited by other metal objects. Keep out of reach of children. Do not expose Li-ion Battery to heat or fire. Avoid storage in direct sunlight. Do not store together with oxidizing and acidic materials. 8. Exposure Controls/ Personal Protection Engineering Controls Use local exhaust ventilation or other engineering controls to control sources of dust, mist, fumes and vapor. Keep away from heat and open flame. Store in a cool, dry place. Personal Protective Equipment Respiratory Protection: Not necessary under normal conditions. Skin and body Protection: Not necessary under normal conditions, Wear neoprene or nitrile rubber gloves if handling an open or leaking battery. Hand protection: Wear neoprene or natural rubber material gloves if handling an open or leaking battery. Eye Protection: Not necessary under normal conditions, Wear safety glasses if handling an open or leaking battery. Other Protective Equipment Have a safety shower and eye wash fountain readily available in the immediate work area. Hygiene Measures Do not eat, drink, or smoke in work area. Maintain good housekeeping. Page 4 of 8 Conrad Electronic SE, Klaus-Conrad-Str. 1, D-92240 Hirschau Item no.: 1221199 Material Safety Data Sheet 9. Physical and Chemical Properties Physical State Form: Solid Colour: White Odour: Monotony Change in condition: pH, with indication of the concentration Not applicable Melting point/freezing point Not available. Boiling Point, initial boiling point and Boiling range: Not available. Flash Point Not available. Upper/lower flammability or explosive limits Not available. Vapor Pressure: Not applicable Vapor Density: (Air = 1) Not applicable Density/relative desity Not available. Solubility in Water: Insoluble n-octanol/water partition coefficient Not available. Auto-ignition temperature 130 °C Decomposition temperature Not available. Odout threshold Not available. Evaporation rate Not available. Flammability (soil, gas) Not available. Viscosity Not applicable 10. Stability and Reactivity Stability The product is stable under normal conditions. Conditions to Avoid (e.g. static discharge, shockor vibration) Do not subject Li-ion Battery to mechanical shock. Vibration encoutered during transportation does not cause leakage, fire or explosion. Do not disassemble, crush, short or install with incorrect polarity. Avoid mechanical or electrical abuse. Incompatible Materials Not Available Hazardous Decomposition Products This material may release toxic fumes if burned or exposed to fire Possibility of Hazardous Reaction Not Available Page 5 of 8 Conrad Electronic SE, Klaus-Conrad-Str. 1, D-92240 Hirschau Item no.: 1221199 Material Safety Data Sheet 11. Toxicological Information Irritation Risk of irritation occurs only if the cell is mechanically, thermally or electrically abused to the point of compromising the enclosure. If this occurs, irritation to the skin, eyes and respiratory tract may occur. Sensitization Not Available Neurological Effects Not Available Teratoaenicitv Not Available Reproductive Toxicity Not Available Mutagenicity (Genetic Effects) Not Available Toxicologically Synergistic Materials Not Available 12. Ecological Information General note: Water hazard class 1(Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Anticipated behavior of a chemical product in environment/possible environmental impace/ecotoxicity Not Available Mobility in soil Not Available Persistence and Degradability Not Available Bioaccumulation potential Not Available Other Adverse Effects Not Available Page 6 of 8 Conrad Electronic SE, Klaus-Conrad-Str. 1, D-92240 Hirschau Item no.: 1221199 Material Safety Data Sheet 13. Disposal Considerations Product disposal recommendation: Observe local, state and federal laws and regulations. Packaging disposal recommendation: Be aware discarded batteries may cause fire, tape the battery terminals to insulate them. Don’t disassembly the battery. Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used. Observe local, state and federal laws and regulations. The potential effects on the environment and human health of the substances used in batteries and accumulations; the desirability of not disposing of waste batteries and accumulators as unsorted municipal waste and of participating in their separate collection so as to facilitate treatment and recycling. 14. Transport Information This report applies to by sea, by air and by land; The Li-ion Battery tested according to the requirements of the 5th revised edition of the UN manual of tests and Criteria, Part III, subsection 38.3 Lithium ion battery was protected so as to prevent short circuits. This includes protection against contact with conductive materials within the same packaging that could lead to short circuit; The LITHIUM ION BATTERY according to Section II/IA/IB of PACKING INSTRUCTION 965/ 966 /967 of the 2014 IATA Dangerous Goods regulations 55th Edition may be transported and applicable U.S.DOT regulations for the safe transport of Li-ion Battery. More information concerning shipping, testing, marking and packaging can be obtained from label master at http://www.labelmaster.com/ . The packaging shall be adequate to avoid mechanical damage during transport, handling and stacking. The materials and pack design shall be chosen so as to prevent the development of unintentional electrical conduction, corrosion of the terminals and ingress of moisture. The package must be handled with care and that a flammability hazard exists if the package is damaged; Each package must be labeled with a Li-ion Battery handling label or in addition to the Class 9 hazard label. With regard to transport, the following regulations are cited and considered: - The International Civil Aviation Organization (ICAO) Technical Instructions. - The International Air transport Association (IATA) Dangerous Goods Regulations. UN number of lithium battery: UN3480 or UN3481; UN Proper shipping name/Description (technical name): Lithium ion batteries or Lithium ion batteries contained in equipment or Lithium ion batteries packed with equipment; UN Classification (Transport hazard class): Non dangerous; Marine pollutant (Y/N): N; - The International Maritime Dangerous Goods (IMDG) Code. For lithium-ion batteries by sea, provided that packaging is strong and prevent the products from short-circuit. UN number of lithium battery: UN3480 or UN3481; UN Proper shipping name/Description (technical name): Lithium ion batteries or Lithium ion batteries contained in equipment or Lithium ion batteries packed with equipment; UN Classification (Transport hazard class): Non dangerous; Marine pollutant (Y/N): Y; Special Provision: International maritime dangerous goods code (IMDG) 188, 230, 310, 348, 957; - The US Hazardous Materials Regulation (HMR) pursuant to a final rule issued by RSPA - The Office of Hazardous Materials Safety within the US Department of Transportations’ (DOT) Research and Special Programs Administration (RSPA) Page 7 of 8 Conrad Electronic SE, Klaus-Conrad-Str. 1, D-92240 Hirschau Item no.: 1221199 Material Safety Data Sheet 15. Transport Information US: This MSDS meets/exceeds OSHA requirements International: this MSDS conforms to European Union (UN), the International Standards Organisation (ISO) and the International Labor Organization (ILO) and as documental in ANSI (American National Standards Institute) Standard Z400.11993. 16. Other Information The information above is believed to be accurate and represents the best information currently available to us. However, concord makes no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. Although reasonable precautions have been taken in the preparation of the data contained herein, it is offered solely for your information, consideration of investigation. This material safety data sheet provides guidelines for the safe handling and use of this product; it does not and cannot advise on all possible situations, therefore, your specific use of this product should be evaluated to determine if additional precautions are required. The data/information contained herein has been reviewed and approved for general release on the basis that this document contains no export controlled information. Page 8 of 8
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