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Material Safety Data Sheet
WHMIS (Pictograms)

WHMIS (Classification)

Personal Protective Equipment

Class D-1A: Material causing immediate and serious toxic effects
(VERY TOXIC).
Class E: Corrosive liquid.

Section 1. Product and Company Identification
Associated
Product’s Item
Code

WIP-12280
12-284EXP

Hydrochloric acid

CAS #

7647-01-0

Chemical Family

Inorganic acid.

July 08 2004
Validation Date 7/8/2004.

Chemical Formula

HCl (aq)

Print Date

Manufacturer

Recochem Inc.
850 Montee de Liesse
Montreal, Quebec
514-341-3550

In Case of Recochem Inc.
Emergency C o m m u n i c a t i o n s a n d R e g u l a t o r y
Affairs Department
(905) 791-1788

Material Uses

Consumer products: Cleaning solution.

Product Name /
Trade name

Muriatic Acid

Synonym

Muriatic Acid

July 08 2004
7/8/2004.

Section 2. Hazardous Ingredients
Name
Hydrochloric acid

CAS #

% by
Weight

7647-01-0

31-32%
/ 20º
Baume

Exposure Limits
Canadian Values (ACGIH)
U.S. Values (OSHA)
Muriatic
Acid

Not available.

Section 3. Hazard Identification
Emergency Overview

DANGER!
CAUSES SEVERE EYE AND SKIN BURNS. MAY BE FATAL IF SWALLOWED.
Do not get in eyes, on skin or on clothing. Do not ingest. Do not breathe vapor or mist. Keep container closed. Use
only with adequate ventilation. Wash thoroughly after handling.

Potential Acute Health
Effects

See Section #11: "Toxicological Information" for further human health effects.
Very dangerous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant), of inhalation.
Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory
tract.
Skin contact may produce burns.
Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or
shortness of breath.
Inflammation of the eye is characterized by redness, watering, and itching.
Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.

Note to Physician

Not available.

Continued on Next Page

July 08 2004
Validated on 7/8/2004.

Muriatic
Muriatic
Acid Acid

Page: 2/5

Section 4. First Aid Measures
Eye Contact

IMMEDIATELY flush eyes with running water for at least 15 minutes, keeping eyelids open. SEEK IMMEDIATE
MEDICAL ATTENTION.

Skin Contact

If the chemical got onto the clothed portion of the body, remove the contaminated clothes as quickly as possible.
Place the victim under a deluge shower. Gently and thoroughly wash the contaminated skin with running water and
non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Seek medical attention. Wash
contaminated clothing before reusing.

Inhalation

Allow the victim to rest in a well ventilated area. Seek medical attention.

Ingestion

DO NOT induce vomiting. Have conscious person drink several glasses of water or milk. Seek medical attention.

Section 5. Fire Fighting Measures
Products of Combustion

Not applicable.

Fire Fighting Media
and Instructions

Use DRY chemicals, CO2, water spray or foam.

Fire Hazards

Flammable hydrogen gas may be produced on prolonged contact with metals.

Explosion Hazards

Flammable hydrogen gas may be produced on prolonged contact with metals.

Section 6. Accidental Release Measures
Small Spill and Leak

Dilute with water and mop up, or absorb with an inert DRY material and place in an appropriate waste disposal
container. If necessary: Neutralize the residue with a dilute solution of sodium carbonate.

Large Spill and Leak

Corrosive liquid.
Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Place in appropriate
container and dispose of in accordance with regional regulations. Neutralize the residue with a dilute solution of
sodium carbonate.

Section 7. Handling and Storage
Handling

Not available.

Storage

See Section #10 for applicable incompatible materials.
May corrode metallic surfaces. Store in a polyethylene container. Keep away from incompatibles. Keep container
tighltly closed in a cool, well-ventilated place.

Section 8. Exposure Controls, Personal Protection
Engineering Controls

Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station
location.

Personal Protection
Eyes Face shield.
Body Synthetic apron.
Respiratory Wear appropriate respirator when ventilation is inadequate.
Hands Impervious gloves.

Continued on Next Page

July 08 2004
Validated on 7/8/2004.

Page: 3/5

Muriatic
Muriatic
Acid Acid

Section 9. Physical and Chemical Properties
Physical State and
Appearance

Liquid.

Odour

Irritant.

Molecular Weight

Not applicable.

Taste

Not available.

pH (1% Soln/Water)

1 [Acidic.]

Colour

Clear colorless to light yellow.

Boiling/Condensation
Point

>81°C (177.8°F)

Volatility

Not available.

Melting/Freezing Point

Not available.

Evaporation Not available.
Rate

Specific Gravity

1.16 (Water = 1)

Odour
Threshold

Not available.

Vapour Pressure

25 mm of Hg (@ 20°C)

Viscosity

Not available.

Vapour Density

Not available.

Solubility

Soluble in water, methanol.

VOC Content

Not available.

Other
Properties

Not available.

The Product is:

Non-flammable.

Auto-ignition
Temperature

Not applicable.

Flash Point

Not applicable.

Flammable Limits

Not applicable.

Fire Hazards in Presence Not applicable.
of Various Substances

Section 10. Stability and Reactivity
Stability

The product is stable.

Conditions of Instability

No additional remark.

Incompatibility with
Various Substances

Reactive with oxidizing agents, metals, alkalis.

Section 11. Toxicological Information
Routes of Entry

Skin contact. Eye contact. Inhalation. Ingestion.

Toxicity to Animals

Acute oral toxicity (LD50): 900 mg/kg [Rabbit.]. (Hydrochloric acid).

Acute Effects on Humans
Eyes Very hazardous in case of eye contact (irritant). Corrosive to eyes. Inflammation of the eye is characterized by
redness, watering, and itching.

Skin Very hazardous in case of skin contact (corrosive, irritant). Skin contact may produce burns. Severe over-exposure
can result in death. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.

Inhalation Very hazardous in case of inhalation. Inhalation of the spray mist may produce severe irritation of respiratory tract,
characterized by coughing, choking, or shortness of breath. Over-exposure by inhalation may cause respiratory
irritation. May be fatal if inhaled.

Continued on Next Page

July 08 2004
Validated on 7/8/2004.

Page: 4/5

Muriatic
Muriatic
Acid Acid

Ingestion May be fatal if swallowed. May cause burns to mouth, throat and stomach.
Chronic Effects on
Humans

CARCINOGENIC EFFECTS: Classified NONE.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.
Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated
or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial
infection. Repeated exposure to a highly toxic material may produce general deterioration of health by an
accumulation in one or many human organs.

Section 12. Ecological Information
Ecotoxicity

For accidential discharges into environment, see Section #6: "Accidential Release Measures" for suggested
instructions.
Not available.

Section 13. Disposal Considerations
Waste Information

Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14. Transport Information
Canada Transportation of Dangerous Goods (TDG) Information
Primary Class
Subsidiary Class (if
applicable)

Class 8: Corrosive material

Proper shipping name
Hazard Identification
Number
Packing Group

hydrochloric acid
1789

Special Provisions

In containers of 1 L (1Kg) capacity or less this product is
classified as a "Limited Quantities""Consumer Commodity" under
TDG regulations.

8

II

International Maritime Dangerous Goods (IMDG) Transportation Information
Primary Class
Subsidiary Class (if
applicable)

Class 8: Corrosive material

Proper shipping name
Hazard Identification
Number
Packing Group

Hydrochloric acid
1789

Marine Pollutant
Special Provisions

Not pollutant.

-

II

-

United States Department of Transportation (DOT) Information

Continued on Next Page

8

No placard (handling and hazard label) required.

July 08 2004
Validated on 7/8/2004.

Page: 5/5

Muriatic
Muriatic
Acid Acid

Primary Class

Class 8: Corrosive material

Subsidiary class (if
applicable)

-

Proper shipping name
Hazard Identification
Number
Packing Group

hydrochloric acid

Special Provisions

In containers of 1 L (1Kg) this product is qualified as a "consumer
commodity" ORM-D under DOT

International Air
Transport Association
(IATA)

For air shipment classification and associated regulations, please refer to the latest edition of
IATA Dangerous Goods Regulations.

CORROSIVE

8

1789
II

Section 15. Other Regulatory Information and Pictograms
WHMIS Classification
(Canada)
Canada Domestic
Substances List (DSL)
Status

Class D-1A: Material causing immediate and serious toxic effects
(VERY TOXIC).
Class E: Corrosive liquid.
This product and/ or all of its components are on the DSL.

HCS Classification
(U.S.A.)

Corrosive Material

U.S.A. Regulatory Lists

This product and/ or all of its components are on the TSCA inventory list.

Hazardous Material
Information System
(U.S.A.)

Health
Flammability
Reactivity
Personal Protection

3
0
2
D

National Fire
Protection
Association
(U.S.A.)

Flammability

Health

0
3 2

Reactivity

Specific Hazard

Section 16. Other Information
Validated and verified by Compliance and Technical Information Manager on 7/8/2004.
July 08 2004

Printed 7/8/2004.
July 08 2004

Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for
the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain
hazards are described herein, we cannot guarantee that these are the only hazards that exist.

MSDS are available at www.recochem.com



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