W F Young Absorbine Hooflex Original Liquid Conditioner GHS SDS FEb 2018
knorkaitis
HooflexConditionerSDSFeb2018 SAFETY DATA SHEET
ABSORBINE® HOOFLEX® ORIGINAL LIQUID CONDITIONER
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
1.1 Trade Name (as labeled):
Absorbine® Hooflex® Original Liquid Conditioner
Synonyms:
N/A
CAS No:
Mixture
1.2Product Use: 1.3Company Name:
Conditions to maintain healthy hooves W.F. Young
Company Address:
302 Benton Dr
Company Address Cont:
East Longmeadow, MA 01028
Business Phone: Website:
(413) 526-9999 www.wfyoung.com
1.4Emergency Telephone Number:
(413) 526-9999
Date of Current Revision:
February 16,2018
Date of Last Revision:
October 26, 2015
SECTION 2 - HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: This product is a brown thick liquid with a pine-like odor.
Health Hazards: This product may cause eye and skin irritation. May cause allergic skin reaction.
Flammability Hazards: This product is non-flammable.
Reactivity Hazards: None.
Environmental Hazards: The environmental effects of this product have not been investigated, however release may cause long term adverse environmental effects.
US DOT Symbols:
Not Regulated
EU and GHS Symbols:
Signal Word:
Warning!
2.1EU Labeling and Classification:
This product meets the definition of a hazardous substance or preparation as defined by the European Union Council Directives 67/548/EEC, 1999/45/EC, 1272/2008/EC and subsequent Directives. EU HAZARD CLASSIFICATION OF INGREDIENTS PER DIRECTIVE 1272/2008/EC: Index Number: EC# 201-793-8 is listed in Annex VI Index# 604-038-00-4 EC# 232-475-7 is listed in Annex VI Index# 650-015-00-7 EC# 232-350-7 is listed in Annex VI Index# 650-002-00-6 EC# 232-374-8 is not listed in Annex VI EC# 232-384-2 is not listed in Annex VI
Substances not listed either individually or in group entries must be self-classified.
Components Contributing to Classification:
Chloroxylenol, Gum Rosin, Pine Tar, Wood Turpentine, Mineral Oil
2.2Label Elements:
GHS Hazard Classifications: Hazard Statements:
Skin Irritant Category 2 Eye Irritant Category 2 Skin Sensitizer Category 1 STOT SE 3 (Respiratory tract irritation) H315: Causes skin irritation H319: Causes serious eye irritation H317: May cause an allergic skin reaction H335: May cause respiratory irritation
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ABSORBINE® HOOFLEX® ORIGINAL LIQUID CONDITIONER
Precautionary Statements:
Response Statements:
Storage Statements: Disposal Statements: 2.3Health Hazards or Risks From Exposure:
P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P264: Wash thoroughly after handling. P272: Contaminated work clothing should not be allowed out of the workplace. P271: Use only outdoors or in a well-ventilated area. P280: Wear protective gloves/protective clothing/eye protection/face protection P302+P352: IF ON SKIN: Wash with plenty of water. P333+P313: If skin irritation or rash occurs: Get medical advice/attention. P362+P364: Take off contaminated clothing and wash it before reuse. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312: Call a POISON CENTER/doctor if you feel unwell. P337+P313 If eye irritation persists: Get medical advice/attention. P403+P233: Store in well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container in accordance with local/regional/national/international regulations
Symptoms of Overexposure by Route of Exposure:
The most significant routes of overexposure for this product are by contact with skin or eyes. The symptoms of overexposure are described in the following paragraphs.
Acute:
Inhalation: Inhalation of vapors may cause irritation.
Skin Contact: Skin contact may cause irritation. May cause allergic skin reaction.
Eye Contact: Contact with eyes may cause irritation.
Ingestion: Ingestion of this product may cause irritation.
Chronic: None known
Target Organs:
Acute: Skin, Eyes and Respiratory
Chronic: None known
SECTION 3 - COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous Ingredients:
Mineral Oil
WT%
30-40%
CAS No.
8012-95-1
EINECS No.
232-384-2
Hazard Classification
H315: Skin Irrit. 2, H319: Eye Irrit 2, H335: STOT SE 3
Wood Turpentine
5-8%
8006-64-2
232-350-7
H226: Flam. Liq. Cat 3, H302, H312: Acute Tox 4 (Oral, Dermal), H314: Aspiration Tox 1, H315: Skin Irrit. 2
Pine Tar
2-5%
8011-48-1
232-374-8
H317: Skin Sensitizer Cat 1, H412: Aquatic Chronic 3
Chloroxylenol
1-3%
88-04-0
201-793-8
H302: Acute Tox 4 (Oral), H315: Skin Irrit. 2, H317: Skin Sensitizer Cat 1, H319: Eye Irrit 2
Gum Rosin
1-3%
8050-09-7
232-475-7
H317: Skin Sensitizer Cat 1
Balance of other ingredients are non-hazardous or less than 1% in concentration (or 0.1% for carcinogens, reproductive toxins, or respiratory sensitizers).
Note: All WHMIS required information is included in appropriate sections based on the ANSI Z400.1-2010 format. This product has been classified
in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR, EU Directives and the Japanese Industrial Standard JIS Z 7250:2000
SECTION 4 - FIRST AID MEASURES
4.1Description of First Aid Measures:
Eye Contact:
If product enters the eyes, flush with plenty of water or eye wash solution for several minutes. Remove contacts if present and easy to do. Seek medical attention if irritation persists.
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Skin Contact: Inhalation:
Ingestion:
Medical Conditions Generally Aggravated by Exposure: 4.2Symptoms and Effects Both Acute and Delayed: 4.3Recommendations to Physicians:
SECTION 5 - FIRE FIGHTING MEASURES
5.1Fire Extinguishing Materials: Use the following fire extinguishing materials:
5.2 Unusual Fire and Explosion Hazards:
ABSORBINE® HOOFLEX® ORIGINAL LIQUID CONDITIONER
Wash skin thoroughly with soap and water after handling. Seek medical attention if irritation develops and persists.
If breathing becomes difficult, remove victim to fresh air. If necessary, use artificial respiration to support vital functions. Seek medical attention.
If product is swallowed, call physician or poison center immediately. If professional advice is not available, do not induce vomiting. Never induce vomiting or give diluents (milk or water) to someone who is unconscious, having convulsions, or who cannot swallow. Seek medical advice. Take a copy of the label and/or SDS with the victim to the health professional.
Pre-existing skin problems may be aggravated by prolonged contact. Exposure to skin, eyes and respiratory system may cause irritation. Treat symptoms and eliminate overexposure.
Water Spray: Yes Foam: Yes Halon: Yes
Carbon Dioxide: Yes Dry Chemical: Yes Other: Any "C" Class
Explosive Sensitivity to Mechanical Impact: Explosive Sensitivity to Static Discharge:
5.3 Special Fire-Fighting Procedures:
NFPA RATING SYSTEM Flammability
No
No
Incipient fire responders should wear eye protection. Structural firefighters must wear Self-Contained Breathing
Apparatus (SCBA) and full protective equipment. Isolate materials not yet involved in the fire and protect personnel.
Move containers from fire area if this can be done without risk; otherwise, cool with carefully applied water spray. If possible, prevent run-off water from entering storm drains, bodies of water, or other environmentally sensitive areas.
HMIS RATING SYSTEM
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
HEALTH HAZARD (BLUE)
2
Health
0
2
0
-
Other
FLAMMABILITY HAZARD (RED)
Reactivity
PHYSICAL HAZPARRODT(EYCELTLIVOEWE)QUIPMENT
EYES
RESPIRATORY
HANDS
See Sect 8
0
0
BODY
See Sect 8
For Routine Industrial Use and Handling Applications Hazard Scale: 0 = Minimum 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic Hazard
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ABSORBINE® HOOFLEX® ORIGINAL LIQUID CONDITIONER
SECTION 6 - ACCIDENTAL RELEASE MEASURES (STEPS FOR SPILLS)
6.1Personal Precautions, Protective Equipment and Emergency Procedures:
Use cautious judgment when cleaning up spill. Wear suitable protective clothing, gloves, and eye/face protection.
6.2Environmental Precautions:
Construct a dike to prevent spreading. Keep out of sewers, storm drains, surface waters, and soils. 6.3Spill and Leak Response:
Small Spills: Large Spills:
Collect material via broom or mop. Place in tightly sealed containers for proper disposal.
Approach spill areas with caution. If liquid was introduced, create a dike or trench to contain material.
Soak up with absorbent material such as clay, sand or other suitable non-reactive material. Place in leak-proof containers. Seal tightly for proper disposal. Dispose of in accordance with U.S. Federal, State, and local hazardous waste disposal regulations and those of Canada and its Provinces, those of Australia, Japan and EU Member States (see Section 13, Disposal Considerations).
SECTION 7 - HANDLING AND STORAGE
7.1Precautions for Safe Handling:
To prevent eye contact under the foreseeable conditions of use, wear appropriate safety eyewear. When handling, do not eat, drink, or smoke. Wash thoroughly after handling. Do not handle or store near heat, sparks, or flame.
7.2Storage and Handling Practices:
Keep away from incompatible materials. Keep container closed when not in use and store in well ventilated area.
7.3Specific Uses:
Conditions to maintain healthy hooves
SECTION 8 - EXPOSURE CONTROL/PERSONAL PROTECTION
8.1Exposure Parameters:
Ingredients
Mineral Oil Wood Turpentine Pine Tar Chloroxylenol Gum Rosin
CAS No.
8012-95-1 8006-64-2 8011-48-1 88-04-0 8050-09-7
OSHA PEL
5 mg/m3 100 ppm Not listed Not listed Not listed
NIOSH PEL
5 mg/m3 100 ppm Not listed Not listed Not listed
8.2Exposure Controls:
Ventilation and Engineering Controls:
Use with adequate ventilation to ensure exposure levels are maintained below the limits provided above.
The following information on appropriate Personal Protective Equipment is provided to assist employers in complying with OSHA regulations found in 29 CFR Subpart I (beginning at 1910.132), or standards of EU member states (including EN 149 for respiratory PPE, and EN 166 for face/eye protection), and those of Japan. Please reference applicable regulations and standards for relevant details.
Respiratory Protection:
Not required for properly ventilated areas. Maintain airborne contaminant concentrations below guidelines listed above, if applicable. If necessary, use only respiratory protection authorized in the U.S. Federal OSHA Respiratory Protection Standard (29 CFR 1910.134), equivalent U.S. State standards, Canadian CSA Standard Z94.4-93, the European Standard EN149, or EU member states.
Eye Protection:
Safety glasses or goggles are required. If necessary, refer to U.S. OSHA 29 CFR 1910.133, Canadian Standards, and the European Standard EN166, Australian Standards, or relevant Japanese Standards.
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Hand Protection:
Body Protection:
ABSORBINE® HOOFLEX® ORIGINAL LIQUID CONDITIONER
Chemical resistant gloves are required to prevent skin contact. If necessary, refer to U.S. OSHA 29 CFR 1910.138, the European Standard DIN EN 374, the appropriate Standards of Canada, Australian Standards, or relevant Japanese Standards.
Use body protect appropriate to task being performed. If necessary, refer to appropriate Standards of Canada, or appropriate Standards of the EU, Australian Standards, or relevant Japanese Standards. If a hazard of injury to the feet exists due to falling objects, rolling objects, where objects may pierce the soles of the feet or where employee's feet may be exposed to electrical hazards, use foot protection, as described in U.S. OSHA 29 CFR 1910.136.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
9.1Information on Basic Physical and Chemical Properties:
Appearance (Physical State and Color): Brown thick liquid
Odor: Pine-like odor
Odor Threshold: No data available
pH: No data available
Melting/Freezing Point: No data available
Boiling Point: No data available
Flash Point: No data available
Evaporation Rate: No data available
Flammability (Solid; Gas): Not applicable
Upper/Lower Flammability or Explosion Limits: Not applicable
Vapor Pressure (mm Hg @ 20°C (68° F): No data available
Vapor Density: No data available
Relative Density: 0.895@25°C
Specific Gravity: No data available
Solubility in Water: Insoluble
Weight per Gallon: No data available
Partition Coefficient (n-octanol/water): No data available
Auto-Ignition Temperature: No data available
Decomposition Temperature: No data available
Viscosity: >350 cps @20°C
9.2Other Information:
No data available
SECTION 10 - STABILITY AND REACTIVITY
10.1 Reactivity: 10.2 Stability: 10.3Possibility of Hazardous Reactions: 10.4Conditions to Avoid: 10.5Incompatible Substances: 10.6Hazardous Decomposition Products:
This product is not reactive. Stable under conditions of normal storage and use. Will not occur. Avoid heat, sparks and flame Strong oxidizing agents. Carbon dioxide and carbon monoxide.
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ABSORBINE® HOOFLEX® ORIGINAL LIQUID CONDITIONER
SECTION 11 - TOXICOLOGICAL INFORMATION
11.1 Information on Toxicological Effects:
Toxicity Data:
Hazardous Component
Mineral Oil Wood Turpentine Chloroxylenol Gum Rosin
CAS#
8012-95-1 8006-64-2
88-04-0 8050-09-7
LD 50 of Ingredient
Oral LD 50: 22 mg/kg(Mouse)
Oral LD 50: 5760 mg/kg(Rat)
Oral LD 50: 3830 mg/kg (Rat)
Oral LD 50: 2800 mg/kg(Rat) Dermal LD 50: >2000 mg/kg(Rat)
LC 50 of Ingredient
N/A N/A N/A
N/A
Suspected Cancer Agent:
Irritancy: Sensitization to the Product:
Ingredients within this product are not found on one or more of the following lists: FEDERAL OSHA Z LIST, NTP, IARC, or CAL/OSHA and therefore are not considered to be cancer-causing agents by these agencies.
Skin, eye and respiratory irritant.
This product is expected to cause skin sensitization.
Germ Cell Mutagenicity: Reproductive Toxicity:
This product does not contain ingredients that are suspected to be a germ cell mutagenic.
This product is not expected to be a human reproductive toxicant.
SECTION 12 - ECOLOGICAL INFORMATION
12.1 Toxicity:
Hazardous Component
CAS#
Wood Turpentine
8006-64-2
LC50 of Ingredient
96 hr Fish LC 50: 29 mg/L
EC 50 of Ingredient
48 hr Fish EC 50: 6.4 mg/L
Chloroxylenol
88-04-0
96 hr Fish LC 50: 0.36 mg/L
48 hr Fish EC 50: 7.7 mg/L
Gum Rosin
8050-09-7
96 hr Fish LC 50: 60.3 mg/L
N/A
12.2Persistence and Degradability:
No specific data available on this product.
12.3Bioaccumulative Potential:
No specific data available on this product.
12.4Mobility in Soil:
No specific data available on this product.
12.5 Results of PBT and vPvB Assessment:
No specific data available on this product.
12.6 Other Adverse Effects:
No data available
12.7 Water Endangerment Class:
At present, there are no ecotoxicological assessments for this product.
SECTION 13 - DISPOSAL CONSIDERATIONS
13.1 Waste Treatment Methods: 13.2 EU Waste Code:
Waste disposal must be in accordance with appropriate U.S. Federal, State, and local regulations, those of Australia, EU Member States and Japan.
Not determined
SECTION 14 - TRANSPORTATION INFORMATION
14.1U.S. Department of Transportation (DOT) Shipping Regulations (BULK):
This product is classified (per 49 CFR 172.101) by the U.S. Department of Transportation, as follows.
UN Identification Number: Proper Shipping Name: Hazard Class Number and Description: Packing Group: DOT Label(s) Required: North American Emergency Response Guidebook
Number:
Not regulated Not regulated Not applicable Not applicable Not applicable
Not applicable
14.2Environmental Hazards:
Marine Pollutant:
14.3Special Precaution for User: 14.4International Air Transport Association Shipping Information (IATA):
The components of this product are not designated by the Department of Transportation to be Marine Pollutants (49 CFR 172.101, Appendix B).
None
This product is not considered as dangerous goods.
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14.5International Maritime Organization Shipping Information (IMO):
UN Identification Number: Proper Shipping Name: Hazard Class Number and Description: Packing Group: EMS-No:
ABSORBINE® HOOFLEX® ORIGINAL LIQUID CONDITIONER
Not applicable Not regulated Not applicable Not applicable Not applicable
SECTION 15 - REGULATORY INFORMATION
15.1Safety, Health and Environmental Regulations Specific for the Substance or Mixture:
United States Regulations:
U.S. SARA Reporting Requirements: The components of this product are subject to the reporting requirements of Sections 302, 304, and 313 of Title III of the Superfund Amendments and Reauthorization Act. U.S. SARA 311/312: Acute Health: Yes; Chronic Health: No; Fire: No; Reactivity; No U.S. CERCLA Reportable Quantity:
None known
U.S. TSCA Inventory Status: The components of this product are listed on the TSCA Inventory or are exempted from listing. Other U.S. Federal Regulations:
None known California Safe Drinking Water and Toxic Enforcement Act (Proposition 65): This product does not contain ingredients on the Proposition 65 Lists.
15.2Canadian Regulations:
Canadian DSL/NDSL Inventory Status: Components are DSL Listed, NDSL Listed and/or are exempt from listing Other Canadian Regulations: Not applicable Canadian Environmental Protection Act (CEPA) Priorities Substances Lists: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations. Canadian WHMIS Classification and Symbols: This product is classified per WHMIS Controlled Product Regulations.
15.3European Economic Community Information:
This product meets the definition of a hazardous substance or preparation as defined by the European Union Council Directives 67/548/EEC, 1999/45/EC, 1272/2008/EC and subsequent Directives. See Section 2 for Details. Chemical Safety Assessment: No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier. 15.4Australian Information for Product: Components of this product are listed on the International Chemical Inventory list. 15.5Japanese Information for Product: Japanese Minister of International Trade and Industry (MITI) Status: The components of this product are not listed as Class I specified Chemical Substances, Class II Specified Chemical Substances, or Designated Chemical Substances by the Japanese MITI. 15.6International Chemical Inventories: Listing of the components on individual country Chemical Inventories is as follows: Australian Inventory of Chemical Substances (AICS): Listed Korean Existing Chemicals List (ECL): Listed Japanese Existing National Inventory of Chemical Substances (ENCS): Listed Philippines Inventory if Chemicals and Chemical Substances (PICCS): Listed U.S. TSCA: Listed
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SECTION 16 - ADDITIONAL INFORMATION
Updated By:
Karen Norkaitis
Date of Printing: February 16, 2018
ABSORBINE® HOOFLEX® ORIGINAL LIQUID CONDITIONER
The information contained herein is believed to be accurate but is not warranted to be so. Data and calculations are based on information furnished by the manufacturer of the product and manufacturers of the components of the product. Users are advised to confirm in advance of the need that information is current, applicable and suited to the circumstances of use. This safety sheet cannot cover all possible situations which the user may experience during processing. Each aspect of your operation should be examined to determine if, or where, additional precautions may be necessary. All health and safety information contained in this bulletin should be provided to your employees or customers. W. F. Young assumes no responsibility for injury to vendee or third party person proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Furthermore, W. F. Young assumes no responsibility for injury caused by abnormal use of this material even if reasonable safety procedures are followed. Compliance with all applicable federal, state, and local laws and local regulations remains the responsibility of the user.
END OF SDS SHEET
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