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Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 Page: 1/30 Section 1: Identification 1.1 Product Identifier / Product Name REF Product Name - 931301 VISOCOLOR ECO reagent case new 1 x 7 mL CH-1 2 x 30 mL CH-2 1 x 8 mL GH-1 2 x 30 mL GH-2 2 x 24 mL pH-1 1 x 30 mL NH4 -1 1 x 2,5 g NH4 -2 1 x 6 mL NH4 -3 1 x 30 mL NO3 -1 1 x 5 g NO3 -2 1 x 30 mL NO2 -1 1 x 5 g NO2 -2 1 x 25 mL PO4 -1 1 x 25 mL PO4 -2 1.2 Relevant identified Uses of the Substance or Mixture and Uses advised against Relevant identified uses Product for Analytical Use. The Exposure scenario is integrated into sections 1-16. Uses advised against not described 1.3 Details of the Supplier and of the Safety Data Sheet Manufactured by: MACHEREY-NAGEL GmbH & Co. KG Neumann-Neander-Str. 6-8, 52355 Dueren, GERMANY Tel.: +49 2421 969 0 E-mail: sds@mn-net.com (msds@mn-net.com) 1.4 Emergency Telephone Number For Chemical Emergency Spill, Leak, Fire, Exposure, or Accident Call CHEMTREC Day or Night (CCN685047) Within USA and Canada: 1-800-424-9300 Outside USA and Canada: +1 703-527-3887 (collect calls accepted) You find our current versions of SDS (22 languages) in Internet: http://www.mn-net.com/SDS Section 2: Hazard(s) Identification 2.0 Classification of the complete Product Signal Word GHS02 GHS05 GHS07 GHS09 DANGER Version: M V 4.10.1 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 Hazard Identification EUH031 H225 H226 H290 H314 H315 H318 H319 H411 H412 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 Hazard Classes/Categories 031 not defined Flam. Liq. 2 Flam. Liq. 3 Met. Corr. 1 Skin Corr. 1A Skin Irrit. 2 Eye Dam. 1 Eye Irrit. 2 Aquatic Chronic 2 Aquatic Chronic 3 2.1 Classification of the Substance(s) or Mixture(s) 7 mL CH-1 Signal Word Hazard Identification H225 30 mL CH-2 Signal Word No Hazard Class 8 mL GH-1 GHS02 DANGER Hazard Classes/Categories Flam. Liq. 2 Do not need labelling as hazardous - Signal Word Hazard Identification H226 H315 H319 30 mL GH-2 Signal Word No Hazard Class 24 mL pH-1 GHS02 GHS07 WARNING Hazard Classes/Categories Flam. Liq. 3 Skin Irrit. 2 Eye Irrit. 2 Do not need labelling as hazardous - GHS02 Version: M V 4.10.1 Page: 2/30 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 Signal Word Hazard Identification H225 DANGER Hazard Classes/Categories Flam. Liq. 2 30 mL NH4 -1 Signal Word Hazard Identification H290 H314 2,5 g NH4 -2 Signal Word No Hazard Class 6 mL NH4 -3 GHS05 DANGER Hazard Classes/Categories Met. Corr. 1 Skin Corr. 1A Do not need labelling as hazardous - Signal Word Hazard Identification H226 H314 H412 30 mL NO3 -1 Signal Word No Hazard Class 5 g NO3 -2 GHS02 GHS05 DANGER Hazard Classes/Categories Flam. Liq. 3 Skin Corr. 1B Aquatic Chronic 3 Do not need labelling as hazardous - Signal Word Hazard Identification H411 GHS09 WARNING Hazard Classes/Categories Aquatic Chronic 2 Version: M V 4.10.1 Page: 3/30 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 30 mL NO2 -1 Signal Word Hazard Identification H290 Do not need labelling as hazardous - Hazard Classes/Categories Met. Corr. 1 5 g NO2 -2 Signal Word No Hazard Class Do not need labelling as hazardous - 25 mL PO4 -1 Page: 4/30 Signal Word Hazard Identification H315 H319 25 mL PO4 -2 GHS07 WARNING Hazard Classes/Categories Skin Irrit. 2 Eye Irrit. 2 Signal Word Hazard Identification EUH031 H318 GHS05 DANGER Hazard Classes/Categories 031 not defined Eye Dam. 1 2.2 Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture According the implementation of GHS immediate packages only must be labelled with product identificator(s), GHS symbol(s), signal word, manufacturer name and phone number (OSHA's interpretation of HCS 2012). Harmful chemicals/mixtures with signal word: WARNING and highly flammable chemicals/mixtures must not be labelled with H and P phrases until 125 mL (EU 1272/2008 Annex I - 1.5.2) / until 100 mL (Canada WHMIS 2015). This labelling exemption does not apply to U.S.A. 7 mL CH-1 GHS02 Signal Word: DANGER 30 mL CH-2 Do not need labelling as hazardous Version: M V 4.10.1 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 Signal Word: - VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 8 mL GH-1 Page: 5/30 GHS02 GHS07 Signal Word: WARNING 30 mL GH-2 Do not need labelling as hazardous Signal Word: - 24 mL pH-1 GHS02 Signal Word: DANGER 30 mL NH4 -1 GHS05 Signal Word: DANGER H314 Causes severe skin burns and eye damage. P260sh, P280sh, P303+361+353, P305+351+338, P310 Do not breathe dust/vapors. Wear protective gloves/eye protection. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. 2,5 g NH4 -2 Do not need labelling as hazardous Signal Word: - 6 mL NH4 -3 GHS02 GHS05 Signal Word: DANGER H314 Causes severe skin burns and eye damage. P260sh, P280sh, P303+361+353, P305+351+338, P310 Do not breathe dust/vapors. Wear protective gloves/eye protection. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. Version: M V 4.10.1 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 30 mL NO3 -1 Do not need labelling as hazardous Signal Word: - 5 g NO3 -2 Page: 6/30 GHS09 Signal Word: WARNING 30 mL NO2 -1 Do not need labelling as hazardous Signal Word: - 5 g NO2 -2 Do not need labelling as hazardous Signal Word: - 25 mL PO4 -1 GHS07 Signal Word: WARNING 25 mL PO4 -2 GHS05 Signal Word: DANGER H318 Causes serious eye damage. P280sh, P305+351+338, P310 Wear protective gloves/eye protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. 2.3 Other Hazards Possible Hazards from physicochemical Properties Generally in the case of pH values are less than 2 or higher than 11.5 then it is corrosive. In the case of pH values are less than 5 or higher than 9 then it is irritant. Flammable properties. --- Information pertaining to particular Risks to Human and possible Symptoms Causes varying degrees of acid burns on the skin, to the eyes and to the mucous membranes and wounds which do not heal quickly depending on the concentration, temperature and the exposure time. Vapors especially which steam from hot liquids and mist can have a severe irritant effect upon the eyes and the respiratory organs. - Information pertaining to particular Risks to the Environment Avoid contact of substance/mixture to environment. PBT: not applicable vPvB: not applicable Version: M V 4.10.1 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 Other Hazards Contains an odor intensive reagent. --- Section 3: Composition/Information on Ingredients 3.1 Substances or 3.2 Mixtures 7 mL CH-1 Chemical: methyl red (pH indicator) Classification: No criteria for classification or naming of chemical is not required. Chemical Formula: C15 H15 N3 O2 Synonyms: 4-(dimethylamino)-azobenzene-1,2'-carbonic acid TSCA Inventory: listed RTECS: DG8960000 MFCD: EC No.: 207-776-1 Weight Percent: < 0.10 % acc. GHS: The criteria for classification are not fulfilled. Chemical: ethanol (denatured with 1%IPA/1%MEK, acc.2016/1867/EU) Classification: H225, Flam. Liq. 2 Chemical Formula: C2 H6 O; C2 H5 OH Synonyms: ethyl alcohol, methylated spirit TSCA Inventory: listed RTECS: KQ6300000 MFCD: EC No.: 200-578-6 Indice No.: Weight Percent: 55 - <75 % acc. GHS: H225, Flam. Liq. 2 Chemical: indicator dye(s) Classification: No criteria for classification or naming of chemical is not required. TSCA Inventory: all listed, <1% Weight Percent: 0.1 - <1 % acc. GHS: The criteria for classification are not fulfilled. CAS No.: 493-52-7 00002425 CAS No.: 64-17-5 00003568 603-002-00-5 CAS No.: - 30 mL CH-2 Chemical: hydrochloric acid CAS No.: 7647-01-0 Classification: H290, Met. Corr. 1, H314, Skin Corr. 1B, H331, Acute Tox. 3 inh. Chemical Formula: HCl�H2 O Synonyms: aqueous hydrogen chloride TSCA Inventory: listed RTECS: MW4025000 EC No.: 231-595-7 Indice No.: 017-002-01-X Weight Percent: 0.1 - <1 % acc. GHS: The criteria for classification are not fulfilled. 8 mL GH-1 Chemical: triethanolamine Classification: H315, Skin Irrit. 2, H319, Eye Irrit. 2, H335, STOT SE 3 Chemical Formula: C6 H15 NO3 Synonyms: 2,2',2"-nitrilotriethanol; tris(2-hydroxyethyl)amine TSCA Inventory: listed RTECS: KL9275000 EC No.: 203-049-8 Weight Percent: 20 - <45 % acc. GHS: H315, Skin Irrit. 2, H319, Eye Irrit. 2 CAS No.: 102-71-6 Page: 7/30 Version: M V 4.10.1 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 Chemical: ethanol (denatured with 1%IPA/1%MEK, acc.2016/1867/EU) Classification: H225, Flam. Liq. 2 Chemical Formula: C2 H6 O; C2 H5 OH Synonyms: ethyl alcohol, methylated spirit TSCA Inventory: listed RTECS: KQ6300000 MFCD: EC No.: 200-578-6 Indice No.: Weight Percent: 20 - <35 % acc. GHS: H226, Flam. Liq. 3 Chemical: indicator dye(s) Classification: No criteria for classification or naming of chemical is not required. TSCA Inventory: all listed, <1% Weight Percent: 0.1 - <1 % acc. GHS: The criteria for classification are not fulfilled. CAS No.: 64-17-5 00003568 603-002-00-5 CAS No.: - 30 mL GH-2 Chemical: ammonia solution CAS No.: 1336-21-6 Classification: H314, Skin Corr. 1B, H335, STOT SE 3, H400, Aquatic Acute 1 Chemical Formula: NH3 �H2 O Synonyms: ammonium hydroxide, Aqua ammonia, aqueous ammonia TSCA Inventory: listed RTECS: BQ9625000 MFCD: 00011418 EC No.: 215-647-6 Indice No.: 007-001-01-2 Weight Percent: 0.1 - <1 % acc. GHS: The criteria for classification are not fulfilled. Chemical: ethylendinitrilo tetraacetic acid, di Na-salt (EDTA-Na) Classification: H332, Acute Tox. 4 inh., H373, STOT RE 2 Chemical Formula: C10 H14 N2 Na2 O8 �2 H2 O TSCA Inventory: listed (CAS 139-33-3) RTECS: AH4410000; AH4375000 MFCD: EC No.: 205-358-3 Weight Percent: 0.1 - <1 % acc. GHS: The criteria for classification are not fulfilled. CAS No.: 6381-92-6 00150037 24 mL pH-1 Chemical: methyl red (pH indicator) Classification: No criteria for classification or naming of chemical is not required. Chemical Formula: C15 H15 N3 O2 Synonyms: 4-(dimethylamino)-azobenzene-1,2'-carbonic acid TSCA Inventory: listed RTECS: DG8960000 MFCD: EC No.: 207-776-1 Weight Percent: < 0.10 % acc. GHS: The criteria for classification are not fulfilled. Chemical: ethanol (denatured with 1%IPA/1%MEK, acc.2016/1867/EU) Classification: H225, Flam. Liq. 2 Chemical Formula: C2 H6 O; C2 H5 OH Synonyms: ethyl alcohol, methylated spirit TSCA Inventory: listed RTECS: KQ6300000 MFCD: EC No.: 200-578-6 Indice No.: Weight Percent: 90 - <98 % acc. GHS: H225, Flam. Liq. 2 CAS No.: 493-52-7 00002425 CAS No.: 64-17-5 00003568 603-002-00-5 Page: 8/30 Version: M V 4.10.1 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 Page: 9/30 Chemical: phenolphthalein (pH indicator) Classification: H341, Muta. 2, H350, Carc. 1A, H361f, Repr. 2 Chemical Formula: C20 H14 O4 Synonyms: 3,3-bis(4-hydroxyphenyl)-1(3H)-isobenzofuranone TSCA Inventory: listed RTECS: SM8380000 MFCD: EC No.: 201-004-7 Indice No.: Weight Percent: 0.01 - <0.1 % acc. GHS: The criteria for classification are not fulfilled. Chemical: indicator dye(s) Classification: No criteria for classification or naming of chemical is not required. TSCA Inventory: all listed, <1% Weight Percent: 0.01 - <0.1 % acc. GHS: The criteria for classification are not fulfilled. CAS No.: 77-09-8 00005913 604-076-00-1 CAS No.: - 30 mL NH4 -1 Chemical: sodium hydroxide solution Classification: H290, Met. Corr. 1, H314, Skin Corr. 1B Chemical Formula: NaOH�H2 O Synonyms: soda lye TSCA Inventory: listed RTECS: WB4900000 EC No.: 215-185-5 Indice No.: Weight Percent: 5 - <10 % acc. GHS: H290, Met. Corr. 1, H314, Skin Corr. 1B Chemical: tri-sodium citrate Classification: No criteria for classification or naming of chemical is not required. Chemical Formula: C6 H5 Na3 O7 �2H2 O TSCA Inventory: listed (CAS 68-04-2) RTECS: GE8300000 EC No.: 200-675-3 Weight Percent: 10 - <20 % acc. GHS: The criteria for classification are not fulfilled. CAS No.: 1310-73-2 011-002-00-6 CAS No.: 6132-04-3 2,5 g NH4 -2 Chemical: dichloroisocyanuric acid, Na salt CAS No.: 2893-78-9 Classification: H272, Ox. Liq. 2, H302, Acute Tox. 4 oral, H319, Eye Irrit. 2, H335, STOT SE 3, H410, Aquatic Chronic 1, EUH031, 031 not defined Chemical Formula: C3 Cl2 N3 NaO3 Synonyms: troclosene sodium, sodium 3,5-dichloro-2,4,6-trioxo-1,3,5-triazinan-1-ide TSCA Inventory: listed RTECS: XZ1900000 MFCD: 00006036 EC No.: 220-767-7 Indice No.: 613-030-01-7 Weight Percent: 3 - <10 % acc. GHS: The criteria for classification are not fulfilled. Chemical: sodium chloride Classification: No criteria for classification or naming of chemical is not required. Chemical Formula: NaCl Synonyms: salt TSCA Inventory: listed RTECS: VZ4725000 EC No.: 231-598-3 Weight Percent: 80 - <100 % acc. GHS: The criteria for classification are not fulfilled. CAS No.: 7647-14-5 6 mL NH4 -3 Version: M V 4.10.1 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 Chemical: sodium nitroprusside Classification: H301, Acute Tox. 3 oral Chemical Formula: Na2 [Fe(CN)5 NO]2 �2 H2 O Synonyms: disodium pentacyanonitrosylferrate TSCA Inventory: listed (CAS 14402-89-2) RTECS: LJ89250000 EC No.: 238-373-9 Weight Percent: 1 - <5 % acc. GHS: The criteria for classification are not fulfilled. CAS No.: 13755-38-9 Chemical: ethanol (denatured with 1%IPA/1%MEK, acc.2016/1867/EU) Classification: H225, Flam. Liq. 2 Chemical Formula: C2 H6 O; C2 H5 OH Synonyms: ethyl alcohol, methylated spirit TSCA Inventory: listed RTECS: KQ6300000 MFCD: EC No.: 200-578-6 Indice No.: Weight Percent: 35 - <55 % acc. GHS: H226, Flam. Liq. 3 CAS No.: 64-17-5 00003568 603-002-00-5 Chemical: thymol CAS No.: 89-83-8 Classification: H302, Acute Tox. 4 oral, H314, Skin Corr. 1B, H411, Aquatic Chronic 2 Chemical Formula: C10 H14 O Synonyms: 5-methyl-2-(1-methylethyl)-phenol TSCA Inventory: listed RTECS: XP2275000 MFCD: 00002309 EC No.: 201-944-8 Indice No.: 604-032-00-1 Weight Percent: 5 - <10 % acc. GHS: H314, Skin Corr. 1B, H412, Aquatic Chronic 3 30 mL NO3 -1 Chemical: m-phenylenediammonium dichloride Classification: No criteria for classification or naming of chemical is not required. Chemical Formula: C6 H10 Cl2 N2 Synonyms: 1,3-benzenediamine, dihydrochloride TSCA Inventory: listed RTECS: SS9800000 MFCD: EC No.: 208-790-0 Indice No.: Weight Percent: < 1.00 % acc. GHS: The criteria for classification are not fulfilled. CAS No.: 541-69-5 00012975 612-148-00-9 Chemical: citric acid CAS No.: 77-92-9 Classification: H303, Acute Tox. 5 oral, H316, Skin Irrit. 3, H319, Eye Irrit. 2 Chemical Formula: C6 H8 O7 Synonyms: 2-hydroxy-1,2,3-propanetricarboxylic acid TSCA Inventory: listed RTECS: GE7350000/GE7810000 EC No.: 201-069-1 Weight Percent: 1 - <10 % acc. GHS: The criteria for classification are not fulfilled. 5 g NO3 -2 Chemical: zinc powder (stabilizied) Classification: H410, Aquatic Chronic 1 Chemical Formula: Zn TSCA Inventory: listed RTECS: ZG8600000 EC No.: 231-175-3 Weight Percent: 2.5 - <10 % acc. GHS: H411, Aquatic Chronic 2 Indice No.: CAS No.: 7440-66-6 030-002-01-9 30 mL NO2 -1 Page: 10/30 Version: M V 4.10.1 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 Chemical: sulfanilamide Classification: H303, Acute Tox. 5 oral Chemical Formula: C6 H8 N2 O2 S Synonyms: 4-aminobenzene sulfonamide TSCA Inventory: listed RTECS: WO8400000 EC No.: 200-563-4 Weight Percent: 1 - <10 % acc. GHS: The criteria for classification are not fulfilled. MFCD: CAS No.: 63-74-1 00007939 Chemical: o-phosphoric acid CAS No.: 7664-38-2 Classification: H290, Met. Corr. 1, H302, Acute Tox. 4 oral, H314, Skin Corr. 1B Chemical Formula: H3 PO4 �H2 O Synonyms: orthophosphoric acid TSCA Inventory: listed RTECS: TB6300000 EC No.: 231-633-2 Indice No.: 015-011-00-6 Weight Percent: 1 - <10 % acc. GHS: H290, Met. Corr. 1 5 g NO2 -2 Chemical: N-(1-naphthyl)-ethylendiamine dihydrochloride Classification: H315, Skin Irrit. 2, H319, Eye Irrit. 2 Chemical Formula: C12 H16 Cl2 N2 Synonyms: N1-1-naphthalenyl-1,2-ethanediamine, dihydrochloride TSCA Inventory: listed RTECS: KV5330000 MFCD: EC No.: 215-981-2 Weight Percent: 1 - <10 % acc. GHS: The criteria for classification are not fulfilled. CAS No.: 1465-25-4 00012556 Chemical: citric acid CAS No.: 77-92-9 Classification: H303, Acute Tox. 5 oral, H316, Skin Irrit. 3, H319, Eye Irrit. 2 Chemical Formula: C6 H8 O7 Synonyms: 2-hydroxy-1,2,3-propanetricarboxylic acid TSCA Inventory: listed RTECS: GE7350000/GE7810000 EC No.: 201-069-1 Weight Percent: 1 - <10 % acc. GHS: The criteria for classification are not fulfilled. 25 mL PO4 -1 Chemical: ammonium heptamolybdate CAS No.: 12054-85-2 Classification: No criteria for classification or naming of chemical is not required. Chemical Formula: H24 Mo7 N6 O24 Synonyms: hexaammonium heptamolybdate TSCA Inventory: listed (CAS 11098-84-3) RTECS: QA5076000 / QA4900000 MFCD: 00167059 EC No.: 234-722-4 Weight Percent: 0.5 - <2 % Correlation Factor: x 0.58 (= %Mo) acc. GHS: The criteria for classification are not fulfilled. Chemical: sulfuric acid (diluted < 5 %) Classification: H315, Skin Irrit. 2, H319, Eye Irrit. 2 Chemical Formula: H2 SO4 �H2 O TSCA Inventory: listed RTECS: WS5600000 EC No.: 231-639-5 Indice No.: Weight Percent: 5 - <15 % acc. GHS: H315, Skin Irrit. 2, H319, Eye Irrit. 2 CAS No.: 7664-93-9d 016-020-00-8 25 mL PO4 -2 Page: 11/30 Version: M V 4.10.1 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 Chemical: sodium disulfite CAS No.: 7681-57-4 Classification: H302, Acute Tox. 4 oral, H318, Eye Dam. 1, EUH031, 031 not defined Chemical Formula: Na2 O5 S2 Synonyms: sodium metabisulphite, sodium pyrosulfite TSCA Inventory: listed RTECS: UX8225000 EC No.: 231-673-0 Indice No.: 016-063-00-2 Weight Percent: 10 - <25 % acc. GHS: H318, Eye Dam. 1, EUH031, 031 not defined 3.3 Remarks When not listed, mixtures are added with water [CAS No. 7732-18-5] to 100%. List of Hazard and Precaution phrases: see section 16.1 Page: 12/30 Section 4: First-Aid Measures 4.1 4.1.1 4.1.2 4.1.3 4.1.4 4.2 4.3 Description of First-Aid Measures Place insured person out of danger zone to fresh air immediately. Ensure quiet, warmth, and provide resuscitation if necessary. If necessary contact medical advice. Remove contaminated clothing. Show product package, packing insert and this material safety data sheet to the doctor. After SKIN Contact Remove contaminated clothing immediately. Rinse the affected skin or mucous membrane thoroughly for min. 15 minutes under running water. (If possible) use soap. Avoid neutralisation. Then apply a loose bandage. After EYE Contact After contact with the eyes rinse thoroughly under running water with the eyelid wide open for min. 10 minutes with eye washing bottle, eye douche or running water (protect intact eye). Before (if possible) apply eye drops Proxymetacaine 0.5%, if the opening the eyelid convulsion is painful. Further treatment to be carried out by an eye specialist. After INHALATION of Vapors After inhalation of foam or vapor fresh air should be inhaled. Keep airways free. If vomiting and if insensible place patient in recovery position and keep airways free. After ORAL Intake After oral intake lots of water with activated charcoal supplement should be drunk after it has been ingested. Do not induce vomiting under any circumstances. Do not make any efforts to neutralize it. Contact medical advice for possible consequences. Most important Symptoms and Effects, both acute and delayed --- Indication of any immediate Medical Attention and Special Treatment needed CORROSIVE DAMAGE: After SKIN CONTACT rinse with water for a long time. Efforts to neutralise the substance can frequently make matters worse. Apply glucocorticosteroides following inflammatory reactions. After EYE CONTACT rinse immediately with plenty of water for a long time. Eyelid convulsion measures. Name the corrosive substance. Further treatment must to be carried out by an eye specialist. After INTAKE administer aluminium oxide drug suspensions. Administer a prophylaxis to counter pulmonary oedema following the INGESTION of corrosive aerosols. In the event of RESPIRATORY DISTREES ensure that the patient inhales oxygen. --- Section 5: Fire-Fighting Measures 5.1 Extinguishable Media Fire extinguishers appropriate to the fire classification, and, if applicable, a fire blanket must be available in a prominent location in the work area. All extinguishers like WATER FOG, WATER SPRAY, alcohol-resistant FOAM, DRY CHEMICAL, CARBON DIOXIDE can be used. 5.2 Special Hazards arising from the Substance or Mixture WARNING: Flammable. May form explosive vapor-air mixtures. DANGER: Highly flammable. Forms explosive vapor-air mixtures. Formation of hazardous and caustic vapor-air mixtures possible. --- 5.3 Advice for Firefighters No, for listed product. Product package burns like paper or plastic. Spray any vapors released with water. Retent fire water. Use only acid-resistant safety equipment. For great amount - if necessary - protective breathing apparatus which is independent of the ambient air (isolated equipment), and sealed protective clothing is necessary in the event of a large-scale formation of toxic substances. Version: M V 4.10.1 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 Page: 13/30 5.4 Additional Information Danger for environment only in the event of a large-scale leakage or formation of hazardous substances. --- Section 6: Accidental Release Measures 6.1 Personal Precautions, Protective Equipment and Emergency Procedure Do not breathe vapors. Wear suitable protective gloves (see 8.2.2). Wear eye protection, respectively face protection. Regular staff training is necessary, indicating hazards and precautions on the basis of operating instructions. Restrictions on activity must be observed. 6.2 Environmental Precautions not necessary, contains only small amounts of these substances 6.3 Methods and Material for Containment and Cleaning up Bind any escaping liquid with inert absorbent. And dispose in accordance to local regulations for the disposal of hazards. Clean any contaminated equipment and floors with plenty of water. Collect small amounts of leaked liquid and flush with water into sewer. 6.4 Reference to other Sections see information in section 5.4 --- Section 7: Handling and Storage 7.1 7.2 7.2.1 7.3 Precautions for Safe Handling Handling in accordance with the test instruction, that comes with the product. Conditions for Safe Storage, including any Incompatibilities The original product package of MACHEREY-NAGEL allows a safe storage. Storage class (VCI): 3 Water hazard class (DE): 3 Conditions for Safe Storage, including any Incompatibilities Keep original product packages tightly closed during handling and storage. Use inbreakable container for transport of glass bottles. Specific End Use(s) Product for analytical use. Section 8: Exposure Controls/Personal Protection 8.1 Control Parameters 7 mL CH-1 Chemical: methyl red (pH indicator) CAS No.: 493-52-7 Chemical: ethanol DNEL: [derm] 343 mg/kg; [inh] 950 mg/m� DNEL = Derived No-Effect Level (for workers) CAS No.: 64-17-5 PNEC(fresh water) : 0.96 mg/L PNEC = Predicted No Effected Concentration NIOSH: [TWA] 1000 ppm / 1900 mg/m� [TWA] Time-weighted average to a reference period of 8 hours, [STEL] Short-term exposure limit related to a 15-minute period OSHA: [TWA] 1000 ppm / 1900 mg/m� Chemical: indicator dye(s) CAS No.: - 30 mL CH-2 Chemical: hydrochloric acid DNEL: [inh] 8 mg/m� DNEL = Derived No-Effect Level (for workers) CAS No.: 7647-01-0 PNEC(fresh water) : 36 �g/L PNEC = Predicted No Effected Concentration NIOSH: [C] 5 ppm / 7 mg/m� [TWA] Time-weighted average to a reference period of 8 hours, [STEL] Short-term exposure limit related to a 15-minute period OSHA: mg/m� EU value: List of highly hazardous chemicals, toxics and reactives Yes (TQ = 5000 lbs) n/a; TWA 5 ppm / 7 [TWA] 5 ppm / 8 mg/m3 ; [STEL] 10 ppm/ 15 mg/m� Version: M V 4.10.1 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 8 mL GH-1 Chemical: triethanolamine DNEL: [derm] 6.3; [inh] 5 mg/m� DNEL = Derived No-Effect Level (for workers) CAS No.: 102-71-6 PNEC(fresh water) : 0.32 mg/L PNEC = Predicted No Effected Concentration NIOSH: not listed [TWA] Time-weighted average to a reference period of 8 hours, [STEL] Short-term exposure limit related to a 15-minute period OSHA: not listed Chemical: ethanol DNEL: [derm] 343 mg/kg; [inh] 950 mg/m� DNEL = Derived No-Effect Level (for workers) CAS No.: 64-17-5 PNEC(fresh water) : 0.96 mg/L PNEC = Predicted No Effected Concentration NIOSH: [TWA] 1000 ppm / 1900 mg/m� [TWA] Time-weighted average to a reference period of 8 hours, [STEL] Short-term exposure limit related to a 15-minute period OSHA: [TWA] 1000 ppm / 1900 mg/m� Chemical: indicator dye(s) CAS No.: - 30 mL GH-2 Chemical: ammonia solution DNEL: [inh] 14 mg/m� DNEL = Derived No-Effect Level (for workers) CAS No.: 1336-21-6 PNEC(fresh water) : 0.0011 mg/L PNEC = Predicted No Effected Concentration NIOSH: [TWA] 25 ppm / 18 mg/m� NIOSH STEL: 35 ppm / 27 mg/m� [TWA] Time-weighted average to a reference period of 8 hours, [STEL] Short-term exposure limit related to a 15-minute period OSHA: EU value: Yes (TQ = 15000 lbs) - n/a; [TWA] 50 ppm / 35 mg/m� 20 ppm / 14 mg/m� Chemical: ethylendinitrilo tetraacetic acid, di Na-salt (EDTA-Na) DNEL: [inh] 1.5 mg/m� DNEL = Derived No-Effect Level (for workers) PNEC(fresh water) : 2.2 mg/L PNEC = Predicted No Effected Concentration CAS No.: 6381-92-6 Page: 14/30 24 mL pH-1 Chemical: methyl red (pH indicator) CAS No.: 493-52-7 Chemical: ethanol DNEL: [derm] 343 mg/kg; [inh] 950 mg/m� DNEL = Derived No-Effect Level (for workers) CAS No.: 64-17-5 PNEC(fresh water) : 0.96 mg/L PNEC = Predicted No Effected Concentration NIOSH: [TWA] 1000 ppm / 1900 mg/m� [TWA] Time-weighted average to a reference period of 8 hours, [STEL] Short-term exposure limit related to a 15-minute period OSHA: [TWA] 1000 ppm / 1900 mg/m� Chemical: phenolphthalein (pH indicator) CAS No.: 77-09-8 NIOSH: not listed, NTP Report on Carcinogens (RoC) List Yes (Reasonably anticipated to be a human carcinogen) [TWA] Time-weighted average to a reference period of 8 hours, [STEL] Short-term exposure limit related to a 15-minute period OSHA: not listed Chemical: indicator dye(s) CAS No.: - 30 mL NH4 -1 Chemical: sodium hydroxide solution DNEL: [inh] 1 mg/m� DNEL = Derived No-Effect Level (for workers) CAS No.: 1310-73-2 NIOSH: 2 mg/m� [TWA] Time-weighted average to a reference period of 8 hours, [STEL] Short-term exposure limit related to a 15-minute period OSHA: [TWA] 2 mg/m� Version: M V 4.10.1 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 Chemical: tri-sodium citrate CAS No.: 6132-04-3 2,5 g NH4 -2 Chemical: dichloroisocyanuric acid, Na salt CAS No.: 2893-78-9 NIOSH: not listed [TWA] Time-weighted average to a reference period of 8 hours, [STEL] Short-term exposure limit related to a 15-minute period OSHA: not listed Chemical: sodium chloride CAS No.: 7647-14-5 6 mL NH4 -3 Chemical: sodium nitroprusside CAS No.: 13755-38-9 Chemical: ethanol DNEL: [derm] 343 mg/kg; [inh] 950 mg/m� DNEL = Derived No-Effect Level (for workers) CAS No.: 64-17-5 PNEC(fresh water) : 0.96 mg/L PNEC = Predicted No Effected Concentration NIOSH: [TWA] 1000 ppm / 1900 mg/m� [TWA] Time-weighted average to a reference period of 8 hours, [STEL] Short-term exposure limit related to a 15-minute period OSHA: [TWA] 1000 ppm / 1900 mg/m� Chemical: thymol CAS No.: 89-83-8 30 mL NO3 -1 Chemical: m-phenylenediammonium dichloride Chemical: citric acid PNEC(fresh water) : 440 mg/L PNEC = Predicted No Effected Concentration CAS No.: 541-69-5 CAS No.: 77-92-9 Page: 15/30 5 g NO3 -2 Chemical: zinc powder (stabilizied) DNEL: 1inh mg/m� DNEL = Derived No-Effect Level (for workers) CAS No.: 7440-66-6 30 mL NO2 -1 Chemical: sulfanilamide CAS No.: 63-74-1 Chemical: o-phosphoric acid DNEL: 2.92 mg/m� DNEL = Derived No-Effect Level (for workers) CAS No.: 7664-38-2 NIOSH: TWA 1 / ST 3 mg/m� NIOSH STEL: 3 mg/m3 [TWA] Time-weighted average to a reference period of 8 hours, [STEL] Short-term exposure limit related to a 15-minute period OSHA: EU value: TWA 1 mg/m� [TWA] 1 /[STEL] 2 mg/m� 5 g NO2 -2 Chemical: N-(1-naphthyl)-ethylendiamine dihydrochloride Chemical: citric acid PNEC(fresh water) : 440 mg/L PNEC = Predicted No Effected Concentration CAS No.: 1465-25-4 CAS No.: 77-92-9 25 mL PO4 -1 Chemical: ammonium heptamolybdate CAS No.: 12054-85-2 Chemical: sulfuric acid DNEL: 50 �g/m� DNEL = Derived No-Effect Level (for workers) CAS No.: 7664-93-9d PNEC(fresh water) : 2.5 �g/L PNEC = Predicted No Effected Concentration NIOSH: NTP Report on Carcinogens (RoC) List Yes (Known to be a human carcinogen); TWA 1 mg/m� [TWA] Time-weighted average to a reference period of 8 hours, [STEL] Short-term exposure limit related to a 15-minute period OSHA: [TWA] 1 mg/m� Version: M V 4.10.1 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 Page: 16/30 8.2 8.2.1 8.2.2 8.2.3 8.2.4 8.2.5 25 mL PO4 -2 Chemical: sodium disulfite DNEL: [inh] 225 mg/m� DNEL = Derived No-Effect Level (for workers) CAS No.: 7681-57-4 NIOSH: [TWA] 5 mg/m� [TWA] Time-weighted average to a reference period of 8 hours, [STEL] Short-term exposure limit related to a 15-minute period OSHA: none Exposure Controls Good ventilation and extraction system in the room, floor resistant to chemicals with floor drainage and washing facilities. The highest level of cleanliness must be maintained at the workplace. Respiratory Protection No additional recommendations. Hand Protection Yes, gloves (permeation time >30 min - level 2), consist of PVC, Natural latex, Neopren, or Nitril. Use for short times chemical resistant Latex gloves f.ex. with code EN 374-3 level 1. Eye/Face Protection Yes, Splash Goggles or Face Protection. Skin Protection Recommended to avoid clothing damage, and to avoid contamination with these hazards. Hygiene Measures Eating, drinking, smoking, taking snuff and storage of food in work areas and at outdoor workplaces is prohibited. Avoid contact with the skin, eyes and clothing. Rinse any clothing on which the substance has been spilled, and soak it in water. Wash hands thoroughly with soap and water when stopping work and before eating, and then apply protective skin cream. Section 9: Physical and Chemical Properties 9.1 Information on Basic Physical and Chemical Properties 7 mL CH-1 a) Appearance: liquid Color: red c) Odor Threshold: data not available d) pH: - e) Melting Point: data not available f) Boiling Point: data not available g) Flash Point: data not available h) Evaporation Rate(ether=1) : data not available i) Flammability (solid, gas): data not available j) Explosive Limits: data not available k) Vapor Pressure (68�F): data not available l) Vapor Density(air=1) : data not available m) Specific Gravity: 0,88 g/cm� n) Soluble in Water: data not available o) Partition Coefficient (o-w): data not available p) Autoignition Temperature: data not available q) Decomposition temperature: data not available r) Viscosity: data not available s) Explosive properties: data not available t) Oxidizing properties: --- b) Odor: alcoholic 30 mL CH-2 a) Appearance: liquid c) Odor Threshold: d) pH: e) Melting Point: f) Boiling Point: g) Flash Point: h) Evaporation Rate(ether=1) : i) Flammability (solid, gas): j) Explosive Limits: k) Vapor Pressure (68�F): l) Vapor Density(air=1) : Color: colorless data not available 1-2 data not available data not available data not available data not available data not available data not available data not available data not available b) Odor: odorless Version: M V 4.10.1 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 m) Specific Gravity: 1,00 g/cm� n) Soluble in Water: 0-100 % o) Partition Coefficient (o-w): data not available p) Autoignition Temperature: data not available q) Decomposition temperature: data not available r) Viscosity: data not available s) Explosive properties: data not available t) Oxidizing properties: --- 8 mL GH-1 a) Appearance: liquid Color: green c) Odor Threshold: data not available d) pH: 10 e) Melting Point: data not available f) Boiling Point: data not available g) Flash Point: 27 �C h) Evaporation Rate(ether=1) : data not available i) Flammability (solid, gas): data not available j) Explosive Limits: data not available k) Vapor Pressure (68�F): data not available l) Vapor Density(air=1) : data not available m) Specific Gravity: data not available n) Soluble in Water: data not available o) Partition Coefficient (o-w): data not available p) Autoignition Temperature: data not available q) Decomposition temperature: data not available r) Viscosity: data not available s) Explosive properties: data not available t) Oxidizing properties: --- 30 mL GH-2 a) Appearance: liquid Color: colorless c) Odor Threshold: data not available d) pH: 10,5 e) Melting Point: data not available f) Boiling Point: data not available g) Flash Point: data not available h) Evaporation Rate(ether=1) : data not available i) Flammability (solid, gas): data not available j) Explosive Limits: data not available k) Vapor Pressure (68�F): data not available l) Vapor Density(air=1) : data not available m) Specific Gravity: data not available n) Soluble in Water: data not available o) Partition Coefficient (o-w): data not available p) Autoignition Temperature: data not available q) Decomposition temperature: data not available r) Viscosity: data not available s) Explosive properties: data not available t) Oxidizing properties: --- 24 mL pH-1 a) Appearance: liquid c) Odor Threshold: d) pH: e) Melting Point: f) Boiling Point: g) Flash Point: h) Evaporation Rate(ether=1) : i) Flammability (solid, gas): j) Explosive Limits: k) Vapor Pressure (68�F): l) Vapor Density(air=1) : m) Specific Gravity: n) Soluble in Water: o) Partition Coefficient (o-w): p) Autoignition Temperature: Color: red 19...93 mg/m� 7 -114 �C 78 �C > 12 �C data not available data not available 3.5 ...15 Vol% 59 hPa 1,59 0,79-0,86 g/cm� 0-100 % data not available 425 �C b) Odor: alcoholic b) Odor: aminic b) Odor: alcoholic Version: M V 4.10.1 Page: 17/30 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 q) Decomposition temperature: data not available r) Viscosity: data not available s) Explosive properties: data not available t) Oxidizing properties: --- 30 mL NH4 -1 a) Appearance: liquid Color: colorless c) Odor Threshold: data not available d) pH: 11,5-12,5 e) Melting Point: data not available f) Boiling Point: data not available g) Flash Point: data not available h) Evaporation Rate(ether=1) : data not available i) Flammability (solid, gas): data not available j) Explosive Limits: data not available k) Vapor Pressure (68�F): data not available l) Vapor Density(air=1) : data not available m) Specific Gravity: data not available n) Soluble in Water: data not available o) Partition Coefficient (o-w): data not available p) Autoignition Temperature: data not available q) Decomposition temperature: data not available r) Viscosity: data not available s) Explosive properties: data not available t) Oxidizing properties: --- 2,5 g NH4 -2 a) Appearance: powder (solid) Color: colorless c) Odor Threshold: data not available d) pH: 5-7 e) Melting Point: data not available f) Boiling Point: data not available g) Flash Point: data not available h) Evaporation Rate(ether=1) : data not available i) Flammability (solid, gas): data not available j) Explosive Limits: data not available k) Vapor Pressure (68�F): data not available l) Vapor Density(air=1) : data not available m) Specific Gravity: data not available n) Soluble in Water: data not available o) Partition Coefficient (o-w): data not available p) Autoignition Temperature: data not available q) Decomposition temperature: data not available r) Viscosity: data not available s) Explosive properties: data not available t) Oxidizing properties: --- 6 mL NH4 -3 a) Appearance: liquid Color: rose c) Odor Threshold: data not available d) pH: 6-8 e) Melting Point: data not available f) Boiling Point: data not available g) Flash Point: 23 �C h) Evaporation Rate(ether=1) : data not available i) Flammability (solid, gas): data not available j) Explosive Limits: data not available k) Vapor Pressure (68�F): data not available l) Vapor Density(air=1) : data not available m) Specific Gravity: 0,9 g/cm� n) Soluble in Water: data not available o) Partition Coefficient (o-w): data not available p) Autoignition Temperature: data not available q) Decomposition temperature: data not available r) Viscosity: data not available s) Explosive properties: data not available t) Oxidizing properties: --- b) Odor: odorless b) Odor: chloric b) Odor: organic Version: M V 4.10.1 Page: 18/30 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 30 mL NO3 -1 a) Appearance: liquid Color: rose c) Odor Threshold: data not available d) pH: 2-3 e) Melting Point: data not available f) Boiling Point: data not available g) Flash Point: data not available h) Evaporation Rate(ether=1) : data not available i) Flammability (solid, gas): data not available j) Explosive Limits: data not available k) Vapor Pressure (68�F): data not available l) Vapor Density(air=1) : data not available m) Specific Gravity: data not available n) Soluble in Water: data not available o) Partition Coefficient (o-w): data not available p) Autoignition Temperature: data not available q) Decomposition temperature: data not available r) Viscosity: data not available s) Explosive properties: data not available t) Oxidizing properties: --- 5 g NO3 -2 a) Appearance: powder (solid) Color: slightly grey c) Odor Threshold: data not available d) pH: 6,5-7,5 e) Melting Point: data not available f) Boiling Point: data not available g) Flash Point: data not available h) Evaporation Rate(ether=1) : data not available i) Flammability (solid, gas): data not available j) Explosive Limits: data not available k) Vapor Pressure (68�F): data not available l) Vapor Density(air=1) : data not available m) Specific Gravity: data not available n) Soluble in Water: data not available o) Partition Coefficient (o-w): data not available p) Autoignition Temperature: data not available q) Decomposition temperature: data not available r) Viscosity: data not available s) Explosive properties: data not available t) Oxidizing properties: --- 30 mL NO2 -1 a) Appearance: liquid Color: colorless c) Odor Threshold: data not available d) pH: 2-3 e) Melting Point: data not available f) Boiling Point: data not available g) Flash Point: data not available h) Evaporation Rate(ether=1) : data not available i) Flammability (solid, gas): data not available j) Explosive Limits: data not available k) Vapor Pressure (68�F): data not available l) Vapor Density(air=1) : data not available m) Specific Gravity: 1,04 g/cm� n) Soluble in Water: data not available o) Partition Coefficient (o-w): data not available p) Autoignition Temperature: data not available q) Decomposition temperature: data not available r) Viscosity: data not available s) Explosive properties: data not available t) Oxidizing properties: --- b) Odor: odorless b) Odor: odorless b) Odor: odorless Page: 19/30 Version: M V 4.10.1 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 5 g NO2 -2 a) Appearance: powder (solid) Color: colorless c) Odor Threshold: data not available d) pH: 2-3 e) Melting Point: data not available f) Boiling Point: data not available g) Flash Point: data not available h) Evaporation Rate(ether=1) : data not available i) Flammability (solid, gas): data not available j) Explosive Limits: data not available k) Vapor Pressure (68�F): data not available l) Vapor Density(air=1) : data not available m) Specific Gravity: data not available n) Soluble in Water: data not available o) Partition Coefficient (o-w): data not available p) Autoignition Temperature: data not available q) Decomposition temperature: data not available r) Viscosity: data not available s) Explosive properties: data not available t) Oxidizing properties: --- b) Odor: odorless 25 mL PO4 -1 a) Appearance: liquid Color: colorless c) Odor Threshold: data not available d) pH: 1-2 e) Melting Point: data not available f) Boiling Point: data not available g) Flash Point: data not available h) Evaporation Rate(ether=1) : data not available i) Flammability (solid, gas): data not available j) Explosive Limits: data not available k) Vapor Pressure (68�F): data not available l) Vapor Density(air=1) : data not available m) Specific Gravity: 1,07 g/cm� n) Soluble in Water: data not available o) Partition Coefficient (o-w): data not available p) Autoignition Temperature: data not available q) Decomposition temperature: data not available r) Viscosity: data not available s) Explosive properties: data not available t) Oxidizing properties: --- b) Odor: odorless 25 mL PO4 -2 a) Appearance: liquid Color: colorless c) Odor Threshold: data not available d) pH: 6-7 e) Melting Point: data not available f) Boiling Point: data not available g) Flash Point: data not available h) Evaporation Rate(ether=1) : data not available i) Flammability (solid, gas): data not available j) Explosive Limits: data not available k) Vapor Pressure (68�F): data not available l) Vapor Density(air=1) : data not available m) Specific Gravity: data not available n) Soluble in Water: data not available o) Partition Coefficient (o-w): data not available p) Autoignition Temperature: data not available q) Decomposition temperature: data not available r) Viscosity: data not available s) Explosive properties: data not available t) Oxidizing properties: --- b) Odor: sulfuric 9.2 Other Information Data for the other parameters of the mixtures are not available. Relevant Properties of Substance Group Substances are very volantile and form flammable vapor-air mixtures. --- Version: M V 4.10.1 Page: 20/30 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 Page: 21/30 Section 10: Stability and Reactivity 10.1 10.2 10.3 10.4 10.5 10.6 Reactivity No further data available. Chemical Stability No known instability. Possibility of Hazardous Reactions Can react violently with organic material. No further data available. Conditions to avoid Not necessary. --- Incompatible Materials Avoid contact with strong acids or alkalines. --- Hazardous Decomposition Products In the original package all parts/all reagents are safety and separated stored. Decompositions are not observed during the expiration period under recommended conditions. Section 11: Toxicological Information 11.1 Information on Toxicological Effects Following information is valid for pure chemicals. Quantitative data on the toxicity of this product are not available. 7 mL CH-1 Chemical: TSCA Inventory: methyl red (pH indicator) listed CAS No.: 493-52-7 Chemical: ethanol CAS No.: 64-17-5 TSCA Inventory: listed California Prop. 65 List: not listed ACGIH: 1000 ppm Exposure Routes: inhalation, ingestion, skin and/or eye contact Target Organs: Eyes, skin, respiratory system, central nervous system, liver, blood, reproductive system Symptoms: irritation eyes, skin, nose; headache, drowsiness, lassitude (weakness, exhaustion), narcosis; cough; liver damage; anemia; reproductive, teratogenic Canada CEPA 1999: DSL yes LD50orl rat : 6200 mg/kg LC_Lowihl gpg : 21.9 g/m� LC_Loworl hmn : 1400 mg/kg LC50ihl mouse : [4h] 39 g/m� LC50ihl rat : [10h] 20 g/m� LD50drm rbt : 20 000 mg/kg LD50oral mouse : 3450 mg/kg Chemical: TSCA Inventory: indicator dye(s) all listed, <1% CAS No.: - 30 mL CH-2 Chemical: hydrochloric acid CAS No.: 7647-01-0 TSCA Inventory: listed California Prop. 65 List: not listed Exposure Routes: inhalation, ingestion (solution), skin and/or eye contact Target Organs: Eyes, skin, respiratory system Symptoms: irritation nose, throat, larynx; cough, choking; dermatitis; solution: eye, skin burns; liquid: frostbite; in animals: laryngeal spasm; pulmonary ede Canada CEPA 1999: DSL Yes LD50orl rat : 900 mg/kg LC50drm rbt : >5010 mg/kg 8 mL GH-1 Chemical: triethanolamine TSCA Inventory: listed Canada CEPA 1999: DSL Yes LD50orl rat : > 5000 mg/kg LD50drm rbt : > 2000 mg/kg CAS No.: 102-71-6 California Prop. 65 List: not listed Version: M V 4.10.1 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 Page: 22/30 Chemical: ethanol CAS No.: 64-17-5 TSCA Inventory: listed California Prop. 65 List: not listed ACGIH: 1000 ppm Exposure Routes: inhalation, ingestion, skin and/or eye contact Target Organs: Eyes, skin, respiratory system, central nervous system, liver, blood, reproductive system Symptoms: irritation eyes, skin, nose; headache, drowsiness, lassitude (weakness, exhaustion), narcosis; cough; liver damage; anemia; reproductive, teratogenic Canada CEPA 1999: DSL yes LD50orl rat : 6200 mg/kg LC_Lowihl gpg : 21.9 g/m� LC_Loworl hmn : 1400 mg/kg LC50ihl mouse : [4h] 39 g/m� LC50ihl rat : [10h] 20 g/m� LD50drm rbt : 20 000 mg/kg LD50oral mouse : 3450 mg/kg Chemical: TSCA Inventory: indicator dye(s) all listed, <1% CAS No.: - 30 mL GH-2 Chemical: ammonia solution CAS No.: 1336-21-6 TSCA Inventory: listed California Prop. 65 List: not listed Exposure Routes: inhalation, ingestion (solution), skin and/or eye contact (solution/liquid) Target Organs: Eyes, skin, respiratory system Symptoms: irritation eyes, nose, throat; dyspnea (breathing difficulty), wheezing, chest pain; pulmonary edema; pink frothy sputum; skin burns, vesiculation; l Canada CEPA 1999: DSL yes, Toxic Substances (Schedule 1) Yes (Item 53.) LD50orl rat : 350 mg/kg LC_Lowihl hmn : 5000 mg/m� LC50ihl rat : [4h] 2000 ppm LD50drm rbt : [5min] 5000 ppm Chemical: TSCA Inventory: LD50orl rat : ethylendinitrilo tetraacetic acid, di Na-salt (EDTA-Na) listed (CAS 139-33-3) 2800 mg/kg CAS No.: 6381-92-6 24 mL pH-1 Chemical: TSCA Inventory: methyl red (pH indicator) listed CAS No.: 493-52-7 Chemical: ethanol CAS No.: 64-17-5 TSCA Inventory: listed California Prop. 65 List: not listed ACGIH: 1000 ppm Exposure Routes: inhalation, ingestion, skin and/or eye contact Target Organs: Eyes, skin, respiratory system, central nervous system, liver, blood, reproductive system Symptoms: irritation eyes, skin, nose; headache, drowsiness, lassitude (weakness, exhaustion), narcosis; cough; liver damage; anemia; reproductive, teratogenic Canada CEPA 1999: DSL yes LD50orl rat : 6200 mg/kg LC_Lowihl gpg : 21.9 g/m� LC_Loworl hmn : 1400 mg/kg LC50ihl mouse : [4h] 39 g/m� LC50ihl rat : [10h] 20 g/m� LD50drm rbt : 20 000 mg/kg LD50oral mouse : 3450 mg/kg Chemical: phenolphthalein (pH indicator) CAS No.: 77-09-8 TSCA Inventory: listed California Prop. 65 List: listed, cancer Canada CEPA 1999: DSL yes LD50orl rat : >1000 mg/kg EU carcinogen: Carcinogenicity cat. 2, Germ Cell Mutagenicity cat. 3, >5% Reproductive Toxicity cat. 3 Chemical: TSCA Inventory: indicator dye(s) all listed, <1% CAS No.: - Version: M V 4.10.1 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 Page: 23/30 30 mL NH4 -1 Chemical: sodium hydroxide solution CAS No.: 1310-73-2 TSCA Inventory: listed California Prop. 65 List: not listed Exposure Routes: inhalation, ingestion, skin and/or eye contact Target Organs: Eyes, skin, respiratory system Symptoms: irritation eyes, skin, mucous membrane; pneumonitis; eye, skin burns; temporary loss of hair Canada CEPA 1999: DSL Yes LD50orl rat : LD50orl mus : [40%] 1250 / [<25%] >2000 mg/kg 40 mg/kg Chemical: TSCA Inventory: LD50orl rat : tri-sodium citrate listed (CAS 68-04-2) >8000 mg/kg CAS No.: 6132-04-3 2,5 g NH4 -2 Chemical: dichloroisocyanuric acid, Na salt TSCA Inventory: Canada CEPA 1999: LD50orl rat : LC_Loworl hmn : LD50drm rbt : listed DSL Yes 550-1600 mg/kg 3570 mg/kg >5000 mg/kg California Prop. 65 List: not listed Chemical: TSCA Inventory: LD50orl rat : LD50drm rbt : sodium chloride listed 3000 mg/kg 10 g/kg CAS No.: 2893-78-9 CAS No.: 7647-14-5 6 mL NH4 -3 Chemical: TSCA Inventory: LD50orl rat : LC_Loworl rat : sodium nitroprusside listed (CAS 14402-89-2) 99 mg/kg 20 mg/kg CAS No.: 13755-38-9 Chemical: ethanol CAS No.: 64-17-5 TSCA Inventory: listed California Prop. 65 List: not listed ACGIH: 1000 ppm Exposure Routes: inhalation, ingestion, skin and/or eye contact Target Organs: Eyes, skin, respiratory system, central nervous system, liver, blood, reproductive system Symptoms: irritation eyes, skin, nose; headache, drowsiness, lassitude (weakness, exhaustion), narcosis; cough; liver damage; anemia; reproductive, teratogenic Canada CEPA 1999: DSL yes LD50orl rat : 6200 mg/kg LC_Lowihl gpg : 21.9 g/m� LC_Loworl hmn : 1400 mg/kg LC50ihl mouse : [4h] 39 g/m� LC50ihl rat : [10h] 20 g/m� LD50drm rbt : 20 000 mg/kg LD50oral mouse : 3450 mg/kg Chemical: TSCA Inventory: LD50orl rat : LD50drm rat : thymol listed 980 mg/kg > 2000 mg/kg CAS No.: 89-83-8 30 mL NO3 -1 Chemical: TSCA Inventory: LD50orl rat : EU carcinogen: Chemical: TSCA Inventory: LD50orl rat : LC50ihl rat : LD50drm rat : LD50orl mus : m-phenylenediammonium dichloride listed 280 mg/kg mut. 3 citric acid listed >3000 mg/kg 5800 mg/m� >2000 mg/kg 5400 mg/kg CAS No.: 541-69-5 CAS No.: 77-92-9 Version: M V 4.10.1 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 LD50scu rat : 5500 mg/kg 5 g NO3 -2 Chemical: TSCA Inventory: LD50orl rat : LC_Lowinh hmn : LC50ihl rat : zinc powder (stabilizied) listed >2000 mg/kg 12450min mg/m� >5.44h mg/m� CAS No.: 7440-66-6 30 mL NO2 -1 Chemical: TSCA Inventory: LD50orl rat : sulfanilamide listed 3900 mg/kg CAS No.: 63-74-1 Chemical: o-phosphoric acid CAS No.: 7664-38-2 TSCA Inventory: listed California Prop. 65 List: not listed ACGIH: 1 ppm Exposure Routes: inhalation, ingestion, skin and/or eye contact Target Organs: Eyes, skin, respiratory system Symptoms: irritation eyes, skin, upper respiratory system; eye, skin, burns; dermatitis Canada CEPA 1999: DSL Yes LD50orl rat : 1530 mg/kg LC50ihl rbt : 1.689 mg/L LD50drm rbt : 2750 mg/kg 5 g NO2 -2 Chemical: TSCA Inventory: Chemical: TSCA Inventory: LD50orl rat : LC50ihl rat : LD50drm rat : LD50orl mus : LD50scu rat : N-(1-naphthyl)-ethylendiamine dihydrochloride listed citric acid listed >3000 mg/kg 5800 mg/m� >2000 mg/kg 5400 mg/kg 5500 mg/kg CAS No.: 1465-25-4 CAS No.: 77-92-9 25 mL PO4 -1 Chemical: TSCA Inventory: ammonium heptamolybdate listed (CAS 11098-84-3) Chemical: sulfuric acid TSCA Inventory: listed California Prop. 65 List: not listed ACGIH: 1 ppm Exposure Routes: inhalation, ingestion, skin and/or eye contact Target Organs: Eyes, skin, respiratory system, teeth Symptoms: irritation eyes, skin, nose Canada CEPA 1999: DSL Yes LD50orl rat : 2140 mg/kg LC50ihl rat : [8h] 600/ [4h] 850 mg/m� CAS No.: 12054-85-2 CAS No.: 7664-93-9d 25 mL PO4 -2 Chemical: sodium disulfite TSCA Inventory: listed California Prop. 65 List: not listed Exposure Routes: Target Organs: Symptoms: inhalation, ingestion, skin and/or eye contact Eyes, skin, respiratory system irritation eyes, skin, mucous membrane Canada CEPA 1999: DSL yes LD50orl rat : LD50drm rat : 1540 mg/kg 2000 mg/kg CAS No.: 7681-57-4 Page: 24/30 Version: M V 4.10.1 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 Section 12: Ecological Information 12.1 Toxicity Following information is valid for pure chemicals. 7 mL CH-1 Chemical: methyl red (pH indicator) Chemical: ethanol PNEC(fresh water) : 0.96 mg/L PNEC = Predicted No Effected Concentration LC50daphnia magna/48h : LC50pimephales promelas/96h : LC50leuciscus idus/96h : LC50fish/96h : EC50daphnia/48h : IC50scenedesmus quadricauda/72h : EC10pseudomonas putita/16h : Partition Coefficient (o-w): >100 mg/L 13400 - 15100 mg/L [48h] 8140 mg/L 13 g/L 9.3-14.2 g/L [7d] 5000 mg/L [EC5] 6500 mg/L -0.31 Chemical: indicator dye(s) 30 mL CH-2 Chemical: hydrochloric acid PNEC(fresh water) : 36 �g/L PNEC = Predicted No Effected Concentration LC50fish/96h : 24.6 mg/L EC50daphnia/48h : 0.492 mg/L EC50pseudokirchneriella subcapitata/72h : 0.78 mg/L 8 mL GH-1 Chemical: triethanolamine PNEC(fresh water) : 0.32 mg/L PNEC = Predicted No Effected Concentration LC50fish/96h : EC50daphnia/48h : Partition Coefficient (o-w): >1000 mg/L >100024h mg/L -2.3 Chemical: ethanol PNEC(fresh water) : 0.96 mg/L PNEC = Predicted No Effected Concentration LC50daphnia magna/48h : LC50pimephales promelas/96h : LC50leuciscus idus/96h : LC50fish/96h : EC50daphnia/48h : IC50scenedesmus quadricauda/72h : EC10pseudomonas putita/16h : Partition Coefficient (o-w): >100 mg/L 13400 - 15100 mg/L [48h] 8140 mg/L 13 g/L 9.3-14.2 g/L [7d] 5000 mg/L [EC5] 6500 mg/L -0.31 Chemical: indicator dye(s) 30 mL GH-2 Chemical: ammonia solution PNEC(fresh water) : 0.0011 mg/L PNEC = Predicted No Effected Concentration LC50fish/96h : EC50daphnia/48h : 0,89 mg/L 101 mg/L Chemical: ethylendinitrilo tetraacetic acid, di Na-salt (EDTA-Na) PNEC(fresh water) : 2.2 mg/L PNEC = Predicted No Effected Concentration LC50fish/96h : EC50daphnia/48h : IC50scenedesmus quadricauda/72h : EC10pseudomonas putita/16h : Partition Coefficient (o-w): [4d] 41-1592 mg/L 140 mg/L [72h] 2.77-1000 mg/L [EC10, 30h] 500 mg/L -4.3 Page: 25/30 CAS No.: 493-52-7 CAS No.: 64-17-5 CAS No.: CAS No.: 7647-01-0 CAS No.: 102-71-6 CAS No.: 64-17-5 CAS No.: CAS No.: 1336-21-6 CAS No.: 6381-92-6 Version: M V 4.10.1 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 24 mL pH-1 Chemical: methyl red (pH indicator) Chemical: ethanol PNEC(fresh water) : 0.96 mg/L PNEC = Predicted No Effected Concentration LC50daphnia magna/48h : LC50pimephales promelas/96h : LC50leuciscus idus/96h : LC50fish/96h : EC50daphnia/48h : IC50scenedesmus quadricauda/72h : EC10pseudomonas putita/16h : Partition Coefficient (o-w): >100 mg/L 13400 - 15100 mg/L [48h] 8140 mg/L 13 g/L 9.3-14.2 g/L [7d] 5000 mg/L [EC5] 6500 mg/L -0.31 Chemical: phenolphthalein (pH indicator) Partition Coefficient (o-w): 0.9 Chemical: indicator dye(s) Page: 26/30 CAS No.: 493-52-7 CAS No.: 64-17-5 CAS No.: 77-09-8 CAS No.: - 30 mL NH4 -1 Chemical: sodium hydroxide solution Avoid contact of chemical/mixture to environment. LC50leuciscus idus/96h : 35-189 mg/L LC50fish/96h : 45.4 mg/L EC50daphnia/48h : >100 mg/L Chemical: tri-sodium citrate LC50fish/96h : 18-32 g/L EC50daphnia/48h : 5.6-10 g/L EC50chlorella vulgaris/5d : >18-32 g/L EC10pseudomonas putita/16h : EC50ps. fluorescens/8h : >1.8-3.2 g/L CAS No.: 1310-73-2 CAS No.: 6132-04-3 2,5 g NH4 -2 Chemical: Chemical: dichloroisocyanuric acid, Na salt sodium chloride CAS No.: 2893-78-9 CAS No.: 7647-14-5 6 mL NH4 -3 Chemical: sodium nitroprusside CAS No.: 13755-38-9 Chemical: ethanol PNEC(fresh water) : 0.96 mg/L PNEC = Predicted No Effected Concentration LC50daphnia magna/48h : LC50pimephales promelas/96h : LC50leuciscus idus/96h : LC50fish/96h : EC50daphnia/48h : IC50scenedesmus quadricauda/72h : EC10pseudomonas putita/16h : Partition Coefficient (o-w): >100 mg/L 13400 - 15100 mg/L [48h] 8140 mg/L 13 g/L 9.3-14.2 g/L [7d] 5000 mg/L [EC5] 6500 mg/L -0.31 CAS No.: 64-17-5 Chemical: thymol CAS No.: 89-83-8 Harmful to aquatic life with long lasting effects. Avoid contact of chemical/mixture to environment. Environmental hazards must not be labelled with P phrases until 125 mL (EU-CLP 1272/2008 Annex I - 1.5.2). LC50pimephales promelas/96h : 3.2 mg/L EC50daphnia/48h : 3.2 mg/L 30 mL NO3 -1 Chemical: m-phenylenediammonium dichloride Chemical: citric acid PNEC(fresh water) : 440 mg/L PNEC = Predicted No Effected Concentration LC50leuciscus idus/96h : EC50daphnia/48h : IC50scenedesmus quadricauda/72h : 440-760 mg/L 153524h mg/L 7d: 425-640 mg/L CAS No.: 541-69-5 CAS No.: 77-92-9 Version: M V 4.10.1 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 Page: 27/30 12.2 12.3 12.4 12.5 12.6 EC10pseudomonas putita/16h : Partition Coefficient (o-w): EC0: >10 g/L -1.72 5 g NO3 -2 Chemical: zinc powder (stabilizied) CAS No.: 7440-66-6 Toxic to aquatic life with long lasting effects. Avoid contact of chemical/mixture to environment. Environmental hazards must not be labelled with H and P phrases until 125 mL (EU-CLP 1272/2008 Annex I - 1.5.2). LC50fish/96h : 2.01 mg/L EC50daphnia/48h : 0.131 mg/L EC50pseudokirchneriella subcapitata/72h : IC50: 0.713 mg/L 30 mL NO2 -1 Chemical: Chemical: LC50fish/96h : sulfanilamide o-phosphoric acid 3-3.5 mg/L CAS No.: 63-74-1 CAS No.: 7664-38-2 5 g NO2 -2 Chemical: N-(1-naphthyl)-ethylendiamine dihydrochloride Chemical: citric acid PNEC(fresh water) : 440 mg/L PNEC = Predicted No Effected Concentration LC50leuciscus idus/96h : EC50daphnia/48h : IC50scenedesmus quadricauda/72h : EC10pseudomonas putita/16h : Partition Coefficient (o-w): 440-760 mg/L 153524h mg/L 7d: 425-640 mg/L EC0: >10 g/L -1.72 CAS No.: 1465-25-4 CAS No.: 77-92-9 25 mL PO4 -1 Chemical: ammonium heptamolybdate Chemical: sulfuric acid PNEC(fresh water) : 2.5 �g/L PNEC = Predicted No Effected Concentration LC50fish/96h : EC50daphnia/48h : EC10pseudomonas putita/16h : [NOEC, 65d] 25 �g/L 100 mg/L [72h] 100 mg/L CAS No.: 12054-85-2 CAS No.: 7664-93-9d 25 mL PO4 -2 Chemical: sodium disulfite LC50fish/96h : 150-220 mg/L EC50daphnia/48h : 89 mg/L IC50scenedesmus quadricauda/72h : 48 mg/L Persistence and Degradability not necessary Bioaccumulative Potential not necessary Mobility in Soil not necessary Results of PBT and vPvB Assessment no data available Other Adverse Effects no additional data available CAS No.: 7681-57-4 Version: M V 4.10.1 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 Page: 28/30 Section 13: Disposal Considerations Please observe local regulations for collection and disposal of hazardous waste and contact waste disposal company, where you will obtain information on laboratory waste disposal (RCRA Code D002/D003, EU waste code number 16 05 06). 13.1 Waste Treatment Methods Normally it is possible to empty small amounts (diluted!) into drains. Empty containers of corrosive reagents prior to disposal, rinse with water. Section 14: Transport Information 14.1. UN/NA: 3316 14.2. Proper Shipping Name: Chemical Kit 14.3. Hazard Class: 9 14.4. Packing Group: II Transportation by Road Classification code: M11 Tunnel Restriction Code: E Limited Quantity: acc. ADR 3.3.1/251: see LQ in "Alternative Declaration for Transportation" Air Transportation PAX: 960 max. weight PAX: 10 KG CAO: 960 max. weight CAO: 10 KG Maritime Transport EmS: F-A, S-P Storage Category: A Or use the alternative Declaration for Transportation: UN/NA: (see below) UN/NA 1993 Class 3 II, Class 8 II, Excepted Quantities (30 mL/500 mL) = ADR/ IATA E2 or 14.1. UN/NA: 1993 14.2. Proper Shipping Name: Flammable liquid, n.o.s. (ethanol mixture) 14.3. Hazard Class: 3 14.4. Packing Group: II Transportation by Road Classification code: F1 Limited Quantity: 1 L Tunnel restriction code: E Excepted Quantity: E 2 Special instructions: 640C Air Transportation PAX: 353 max. weight PAX: 5 L CAO: 364 max. weight CAO: 60 L Maritime Transport EmS: F-E, S-E Storage Category: B 14.1. UN/NA: 3264 14.2. Proper Shipping Name: Corrosive liquid, acidic, inorganic, n.o.s. (hydrochloric acid, o-phosphoric acid, sodium disulfite solution) 14.3. Hazard Class: 8 14.4. Packing Group: II Transportation by Road Classification code: C1 Limited Quantity: 1 L Tunnel restriction code: E Excepted Quantity: E 2 Air Transportation PAX: 851 max. weight PAX: 1 L CAO: 855 max. weight CAO: 30 L Maritime Transport EmS: F-A, S-B Storage Category: B 14.1. UN/NA: 3266 14.2. Proper Shipping Name: Corrosive liquid, basic, inorganic, n.o.s. (sodium hydroxide solution, ammonia solution) 14.3. Hazard Class: 8 14.4. Packing Group: II Transportation by Road Classification code: C5 Limited Quantity: 1 L Tunnel restriction code: E Excepted Quantity: E 2 Air Transportation PAX: 851 max. weight PAX: 1 L CAO: 855 max. weight CAO: 30 L Maritime Transport EmS: F-A, S-B Storage Category: B 14.5 Environmental Hazards none, contains only small quantities of hazardous substances, contains only small amounts of these substances 14.6 Special Precautions for User not necessary Version: M V 4.10.1 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 14.7 Transport in Bulk according to Annex II of MARPOL and the IBC Code not applicable Page: 29/30 Section 15: Regulatory Information 15.1 Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture U.S. Federal Regulations OSHA "A Guide to The Globally Harmonized System of Classification and Labelling of Chemicals (GHS)" https://www.osha.gov/dsg/hazcom/ghs.html 29 CFR 1910.1200 Hazard communication. NIOSH Pocket Guide to Chemical Hazards NIOSH Workplace Safety & Health Topics TSCA Inventory U.S. State Regulations California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986 Canada Canada CEPA 1999 - Domestic Substances List (DSL), List of Toxic Substances (Schedule 1) 15.2 MN Leaflet/User manual, also see www.mn-net.com Chemical Safety Assessment not necessary for these small amounts --- Section 16: Other Information 16.1 16.1.1 16.1.2 16.2 16.3 16.4 List of Hazard and Precaution Phrases List of relevant H Phrases H225 Highly flammable liquid and vapor. H226 Flammable liquid and vapor. H290 May be corrosive to metals. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H318 Causes serious eye damage. H319 Causes serious eye irritation. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. EUH031 Contact with acids liberates toxic gas. List of relevant P Phrases P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container tightly closed. P260D Do not breathe vapors. P260sh Do not breathe dust/vapors. P273 Avoid release to the environment. P280sh Wear protective gloves/eye protection. P303+361+353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER/doctor. P390 Absorb spillage to prevent material damage. Training Advice Multiple safety training of staffs about danger and protection by using hazards in working area. Additionally training and introduction of staffs for using these products. Recommended Restriction on Use Only for Professional User. Look about employee restrictions for young people! Look about employee restrictions for pregnant women and nursing women! An individual package of this product or test kit has a moderate hazardous potential. Further Information MACHEREY-NAGEL GmbH & Co. KG provides the information contained herein in good faith being up-to-date of own realizations at revision time. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgement in determining its appropriateness for a particular purpose. MACHEREY-NAGEL GmbH & Co. KG makes NO REPRESENTATIONS or WARRANTIES, either expressed or implied, including without limitation any warranties of merchantability, fitness for a particular purpose with respect to the information set forth herein or the Version: M V 4.10.1 Safety Data Sheet SDS acc. Hazard Communication Standard REF: 931301 Printing Date: 28.05.2020 VISOCOLOR ECO reagent case new Date of Issue: 04.12.2019 Page: 30/30 16.5 product to which the information refers. Accordingly MACHEREY-NAGEL GmbH & Co. KG will not be responsible for damages resulting from use of or reliance upon this information. See terms and conditions at the end of our price lists for additional information. Sources of Key Data GHS: EU Regulation 1272/2008/EC on Classification, Labelling and Packaging of Substances and Mixtures, amending and repealing EU Directives 67/548/EEC and 1999/45/EC, and amending EU Regulation 1907/2006/EC SDS: EU Regulation 453/2010/EU REACH - Requirements for the Compilation of Safety Data Sheets K�HN, BIRETT (German), Data Sheets of Hazardous Substances Revisions/Updates Reason for Revision: 2016-03 Adaptation of European Regulation 1221/2015/EU You find our current Versions of SDS in Internet: http://www.mn-net.com/SDS [U.S. English] Version: M V 4.10.1