SUPER DILAC VA4 SS-PIS-SDS 080919 03HC2619-2620
File info: application/pdf · 12 pages · 236.25KB
SUPER DILAC VA4 SS-PIS-SDS 080919 03HC2619-2620
SUPER DILAC VA4 - Hugh Crane Cleaning Equipment Ltd.
PREVENTION AND CONDUCT. The following information applies for the uses indicated in subsection 1.2 of the Safety Data Sheet.
Extracted Text
SUPER DILAC VA4 Safety Summary - Revised 18/10/2019 Super Dilac VA4 Page 1 of 12 SDS Revision Date: 08/09/2019 Print Date 06/02/2020 1. HAZARDS FOR HUMANS AND THE ENVIRONMENT. Contains nitric acid (Nitric Acid), phosphoric acid (Phosphoric Acid) Signal word: Hazard statements: Danger. H314 - Causes severe skin burns and eye damage. H290 - May be corrosive to metals. 2. PREVENTION AND CONDUCT. The following information applies for the uses indicated in subsection 1.2 of the Safety Data Sheet. If available, please refer to the product information sheet for application and handling instructions. Normal use conditions are assumed for this section. Recommended Safety Measures For Handling The Undiluted Product: Covering activities such as filling and transfer of product to application equipment, flasks or buckets. Appropriate engineering controls: If the product is diluted by using specific dosing systems with no risk of splashes or direct skin contact, the personal protection equipment as described in this section is not required. Appropriate organisational controls: Avoid direct contact and/or splashes where possible. Train personnel. Personal protective equipment Eye / face protection: Safety glasses or goggles (EN166). The use of a full-face shield or other full-face protection is strongly recommended when handling open containers or if splashes may occur. Hand protection: Chemical-resistant protective gloves (EN 374). Consider specific local use conditions, such as risk of splashes, cuts, contact time and temperature. Body protection: Wear chemical-resistant clothing and boots in case direct dermal exposure and/or splashes may occur. (EN14605). Respiratory protection: No special requirements under normal use conditions. Environmental Exposure Controls: Should not reach sewage water or drainage ditch undiluted or unneutralised. Recommended Safety Measures For Handling The Diluted Product: Recommended maximum concentration (%): 13 Appropriate engineering controls: No special requirements under normal use conditions. Appropriate organisational controls: Avoid direct contact and/or splashes where possible. Train personnel. Personal protective equipment Eye / face protection: Safety glasses or goggles (EN166). Hand protection: Chemical resistant protective gloves (EN374). Consider specific local use conditions, such as risk of splashes, cuts, contact time and temperature. Body protection: No special requirements under normal use conditions. Respiratory Protection: If the product is applied in a closed system, as recommended, no respiratory protection equipment will be required. Environmental exposure controls: No special requirements under normal use conditions. 3. EMERGENCY PROCEDURES. Suitable extinguishing media: Carbon dioxide. Dry powder. Water spray jet. Fight larger fires with water spray jet or alcohol- resistant foam. Environmental precautions: Do not allow to enter drainage system, surface or ground water. Dilute with plenty of water. Methods for cleaning up: Dyke to collect large liquid spills. Use neutralising agent. Absorb onto dry sand or similar inert material. Do not place spilled material back into the original container. Collect in closed and suitable containers for disposal 4. FIRST AID MEASURES. Inhalation: Skin contact: Get medical attention if you feel unwell. Wash skin with plenty of lukewarm, gently flowing water for at least 30 minutes. Take off immediately all contaminated clothing and wash it before re-use. Immediately call a POISON CENTRE, doctor or physician. Eye contact: Hold eyelids apart and flush eyes with plenty of lukewarm water for at least 15 minutes. Remove Ingestion: contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTRE, doctor or physician. Rinse mouth. Immediately drink 1 glass of water. Do NOT induce vomiting. Keep at rest. Immediately call a POISON CENTRE, doctor or physician. Always check the product labels and consult the Safety Data Sheet for details. The information in this document is based on our best present knowledge. However, it does not constitute a guarantee for any specific product features and does not establish a legally binding contract. Product Information Sheet Super Dilac VA4 Page 2 of 12 SDS Revision Date: 08/09/2019 Print Date 06/02/2020 SUPER DILAC VA4 Description: Key properties: Benefits: Use instructions: Technical data: Super Dilac is a low foaming, high active, non-fuming nitric/phosphoric acid detergent descaler for use in a wide range of CIP applications in the Food and Beverage industry. Super Dilac is highly effective at removing inorganic scale deposits, including calcium oxalate (beerstone). Super Dilac is low foaming and suitable for use in CIP applications under conditions of high pressure and turbulence. Super Dilac is highly economical at in use concentrations. Super Dilac is a conductive liquid detergent and suitable for automatic dosing and control. Highly effective in removing most inorganic scale deposits, improving operational efficiency. Can be used for the passivation of new stainless steel CIP and Bottlewashing installations. Suitable for automatic dosing and control by conductivity, ensuring consistent delivery of product. Super Dilac is typically used for descaling at concentrations between 2.5 - 13%w/w (2-10%v/v) at temperatures between 20-60�C. Super Dilac is typically used for CIP applications at concentrations between 1.0-2.5%w/w (0.82%v/v) for descaling, depending upon the application and level of scale. NB: The exact concentration, time and temperature when using Super Dilac will depend upon the application. All detergents and disinfectants should be thoroughly rinsed after use to remove them from all food and beverage contact surfaces. Appearance: clear, colourless liquid Relative density at 20�C: 1.28 pH (1% solution at 20�C): 1 Chemical Oxygen Demand (COD):none Nitrogen Content (N): 85 g/Kg Phosphorous Content (P): 21 g/Kg Safe handling and storage Information: Product compatibility: Test method: Calculation: Super Dilac Specific conductivity at 25�C (%w/w) (mS/cm) 0.5 12.8 1 25.1 2 46 3 66 4 85 The above data is typical of normal production and should not be taken as a specification. Store in original closed containers or (where applicable) in an approved bulk tank, away from extreme temperatures. Full guidance on the handling and disposal of this product is provided in a separate Material Safety Data Sheet. Super Dilac is safe to use on all type of materials commonly found in CIP circuits when applied under the recommended conditions. In the event of uncertainty it is advisable to evaluate individual materials before any prolonged use. Reagents: 0.1N Sodium hydroxide solution Phenolphthalein Indicator Procedure: Add 2-3 drops of the Indicator solution to 10mls of the test solution. Titrate with the caustic to a red end point. %w/w Super Dilac = titre (mls) x 0.14%v/v Super Dilac = titre (mls) x 0.11 Available pack sizes: 20L SAFETY DATA SHEET according to 1907/2006/EC Super Dilac VA4 Page 3 of 12 SDS Revision Date: 08/09/2019 Print Date 06/02/2020 SUPER DILAC VA4 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING Product Name: Super Dilac VA4 Product Code: MSDS1994 Supplier: Hugh Crane (Cleaning Equipment) Ltd South Walsham Rd, Acle Norwich, NR13 3ES Telephone: 01493 750072 Fax 01493 751854 Emergency telephone number: 0800 052 0185 For medical or environmental emergency only: Relevant identified uses of the substance or mixture and uses advised against Identified uses: For industrial use only. AISE-P801 - Food process cleaner. Cleaning In place (CIP) process Uses advised against: Uses other than those identified are not recommended 2. HAZARDS IDENTIFICATION Classification of the substance or mixture Skin Corr. 1A (H314) Eye Dam 1 (H318) Met Corr (H290) Label elements Signal word: Hazard statements: Precautionary statements: Other hazards: Danger Contains nitric acid (Nitric Acid). Phosphoric acid (Phosphoric Acid). H314 Causes severe skin burns and eye damage H290 May be corrosive to metals. P280 Wear protective gloves, protective clothing and eye or face protection P303+361+353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P305+351+338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 Immediately call a POISON CENTRE, doctor or physician No other hazards known. The product does not meet the criteria for PBT or vPvB in accordance with Regulation (EC) No 1907/2006, Annex XIII. 3. COMPOSITION/INFORMATION ON INGREDIENTS Mixtures Ingredient(s) EC No, CAS No. REACH No. Classification EC 1272/2008 Nitric Acid 231-741-2 7697-37-2 01-2119487297-23 Ox Liq 2 (H272) Ox Liq 3 (H272) Acute Tox 3 (H331) Skin Corr 1A (H314) Met Corr 1 (H290) Phosphoric Acid 231-633-2 7664-38-2 01-2119485924-24 Skin Corr 1B (H314) Met Corr 1 (H290) For the full text of the H and EUH phrases mentioned in this Section, see Section 16. Workplace exposure limit(s), if available, are listed in subsection 8.1. Notes Weight % 30-50 3-10 4. FIRST AID MEASURES Description Of First Aid Measures General Information: If unconscious place in recovery position and seek medical advice. Provide fresh air. If breathing is irregular or stopped, administer artificial respiration. No mouth-to-mouth or mouth-to-nose resuscitation. Use Ambu bag or ventilator. Inhalation: Seek medical attention or advice if you feel unwell. Skin contact: Eye contact: Ingestion: Self-protection of first aider: Super Dilac VA4 Page 4 of 12 SDS Revision Date: 08/09/2019 Print Date 06/02/2020 Wash skin with plenty of lukewarm, gently flowing water for at least 30 minutes. Take off immediately all contaminated clothing and wash it before re-use. Immediately call a POISON CENTRE, doctor or physician. Hold eyelids apart and flush eyes with plenty of lukewarm water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTRE, doctor or physician. Rinse mouth. Immediately drink 1 glass of water. Never give anything by mouth to an unconscious person. Do NOT induce vomiting. Keep at rest. Immediately call a POISON CENTRE, doctor or physician. Consider personal protective equipment as indicated in subsection 8.2. Most Important Symptoms And Effects, Both Acute And Delayed Inhalation: No known effects or symptoms in normal use. Skin contact: Causes severe burns. Eye contact: Causes severe or permanent damage. Ingestion: Ingestion will lead to a strong caustic effect on mouth and throat and to the danger of perforation of oesophagus and stomach. Indication Of Any Immediate Medical Attention And Special Treatment Needed No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if available, can be found in section 11 5. FIREFIGHTING MEASURES Extinguishing media: Carbon dioxide. Dry powder. Water spray jet. Fight larger fires with water spray jet or alcohol- resistant foam. Special hazards arising from the substance or mixture: No special hazards known. Advice for firefighters: As in any fire, wear self contained breathing apparatus and suitable protective clothing including gloves and eye/face protection. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective Eqpt & emergency procedures Personal Precautions: Wear suitable protective clothing, gloves and eye/face protection. Environmental precautions: Do not allow to enter drainage system, surface or ground water. Dilute with plenty of water. Methods and material for containment and cleaning up Clean-up Methods: Dyke to collect large spills. Use neutralising agent. Absorb onto dry sand or similar inert material. Do not place spilled materials back into the original container. Collect in closed and suitable containers for disposal. Reference to other sections: For personal protective equipment see Section 8. For disposal considerations see section 13. 7. HANDLING AND STORAGE Precautions For Safe Handling Measures To Prevent Fire And Explosions: No special precautions required. Measures Required To Protect The Environment: For environmental exposure controls see subsection 8.2. Advice On General Occupational Hygiene: Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not mix with other products unless advised by Diversey. Wash face, hands and any exposed skin thoroughly after handling. Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. Avoid contact with skin and eyes. Use only with adequate ventilation. See section 8, Exposure Controls/Personal Protection. Conditions For Safe Storage, Store in accordance with local and national regulations. Store in a closed container. Keep only in Including Any Incompatibilities: original packaging. Keep cool. Keep away from heat and direct sunlight.. For conditions and materials to avoid see section 10. Specific End Use(s): No specific advice for end use available. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control Parameters Workplace exposure limits Air limit values, if available: Ingredient(s) UK - Long Term Values Nitric Acid Phosphoric Acid 1 mg/m3 UK � Short Term Values 1ppm 2.6 mg/m3 2 mg/m3 Biological limit values, if available: Super Dilac VA4 Page 5 of 12 SDS Revision Date: 08/09/2019 Print Date 06/02/2020 Recommended monitoring procedures if available: Additional exposure limits under the conditions of use, if available: DNEL/DMEL and PNEC values Human exposure DNEL oral exposure - Consumer (mg/kg bw) Ingredient(s) Short term � Local effects Nitric Acid - Phosphoric Acid - Short term � Systemic effects - Long term � Local effects - Long term � Systemic effects - DNEL dermal exposure � Worker Ingredient(s) Short term � Local effects Nitric Acid - Phosphoric Acid No data available Short term � Systemic effects (mg/kg bw) - Long term � Local effects No data available Long term � Systemic effects (mg/kg bw) - DNEL dermal exposure � Consumer Ingredient(s) Short term � Local effects Nitric Acid - Phosphoric Acid No data available DNEL inhalatory exposure - Worker (mg/m3) Ingredient(s) Short term � Local effects Nitric Acid No data available Phosphoric Acid - DNEL inhalatory exposure - Consumer (mg/m3) Ingredient(s) Short term � Local effects Nitric Acid No data available Phosphoric Acid - Short term � Systemic effects (mg/kg bw) - Short term � Systemic effects - Short term � Systemic effects - Long term � Local effects No data available Long term � Local effects 2.6 2.92 Long term � Local effects 1.3 0.73 Long term � Systemic effects (mg/kg bw) - Long term � Systemic effects 1 Long term � Systemic effects - Environmental exposure Environmental exposure � PNEC Ingredient(s) Surface water, fresh (mg/l) Nitric Acid - Phosphoric Acid - Surface water, marine (mg/l) - Intermittent (mg/l) - Sewage treatment plant (mg/l) - Environmental exposure - PNEC, continued Ingredient(s) Sediment, freshwater (mg/kg) Nitric Acid - Phosphoric Acid - Sediment, marine (mg/kg) - Soil (mg/kg) - Air (mg/m3) - Exposure Controls The following information applies for the uses indicated in subsection 1 of the Safety Data Sheet. If available, please refer to the product information sheet for application and handling instructions. Normal use conditions are assumed for this section. Recommended safety measures for handling the undiluted product: Covering activities such as filling and transfer of product to application equipment, flasks or buckets Appropriate engineering controls: If the product is diluted by using specific dosing systems with no risk of splashes or direct skin contact, the personal protection equipment as described in this section is not required. Appropriate organisational controls: Avoid direct contact and/or splashes where possible. Train personnel. Personal Protective Equipment Eye / face protection: Safety glasses or goggles (EN 166). The use of a full-face shield or other full-face protection is strongly recommended when handling open containers or if splashes may occur Super Dilac VA4 Page 6 of 12 SDS Revision Date: 08/09/2019 Print Date 06/02/2020 Hand protection: Chemical-resistant protective gloves (EN 374). Verify instructions regarding permeability and breakthrough time, as provided by the gloves supplier. Consider specific local use conditions, such as risk of splashes, cuts, contact time and temperature. Suggested gloves for prolonged contact: Material: butyl rubber Penetration time: >= 480 min Material thickness: >= 0.7 mm Suggested gloves for protection against splashes: Material: nitrile rubber Penetration time: >= 30 min Material thickness: >= 0.4 mm In consultation with the supplier of protective gloves a different type providing similar protection may be chosen. Body protection: Wear chemical-resistant clothing and boots in case direct dermal exposure and/or splashes may occur. (EN 14605). Respiratory protection: No special requirements under normal use conditions. Environmental exposure controls: Should not reach sewage water or drainage ditch undiluted or unneutralised. Recommended safety measures for handling the diluted product: Recommended maximum concentration (%): 13 Appropriate engineering controls: No special requirements under normal use conditions. Appropriate organisational controls: Avoid direct contact and/or splashes where possible. Train personnel. Personal protective equipment . Eye / face protection: Safety glasses or goggles (EN166). Hand protection: Chemical-resistant protective gloves (EN 374). Verify instructions regarding permeability and breakthrough time, as provided by the gloves supplier. Consider specific local use conditions, such as risk of splashes, cuts, contact time and temperature. Suggested gloves for prolonged contact: Material: butyl rubber Penetration time: >= 480 min Material thickness: >= 0.7 mm Suggested gloves for protection against splashes: Material: nitrile rubber Penetration time: >= 30 min Material thickness: >= 0.4 mm In consultation with the supplier of protective gloves a different type providing similar protection may be chosen. Body protection: No special requirements under normal use conditions. Respiratory protection: No special requirements under normal use conditions.. Environmental exposure controls: No special requirements under normal use conditions. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Information in this section refers to the product, unless it is specifically stated that substance data is listed. Method / Remark Physical State: Liquid Colour: Clear colourless Odour: Product specific Odour Threshold: Not applicable pH: <2 (neat) ISO 4316 Melting/Freezing Point (�C): Not determined. Not relevant to classification of product. Initial Boiling point/range (�C): Not determined See substance data. Substance Data, Boiling Point Ingredient(s) Value (�C) Method Atmospheric Pressure (hPa) Nitric Acid 116 Method not given Phosphoric Acid 158 Method not given 1013 Flammability (liquid): Flash point (�C): Sustained Combustion: Evaporation Rate: Flammability (solid, gas): Upper/lower flammability Limit: Not flammable. Not determined. Not applicable Not determined. Not applicable to liquids. Not determined. Substance Data, Flammability or Explosive Limits, if Available: UN Manual of Tests & Criteria, Section 32, L2 Not relevant to classification of product. Vapour Pressure: Substance Data, Vapour Pressure Ingredient(s) Nitric Acid Phosphoric Acid Not determined. Value (Pa) 770 4 See substance data. Method Method not given Method not given Super Dilac VA4 Page 7 of 12 SDS Revision Date: 08/09/2019 Print Date 06/02/2020 Temperature (�C) 20 20 Vapour Density: Not determined. Relative Density: Approx 1.28 g/cm3 (20�C) Solubility in / Miscibility with Water: Fully miscible Not relevant to classification of this product. OECD 109 (EU A.3) Substance Data, Solubility in Water Ingredient(s) Nitric Acid Phosphoric Acid Value (g/l) >500 Soluble Method Method not given Temperature (�C) Substance Data, Partition Coefficient N-Octanol/Water (log/Kow): See section 12. Autoignition Temperature: Decomposition Temperature: Viscosity: Explosive Properties: Oxidising properties: Not determined. Not applicable. Not determined. Not explosive. Not oxidising. Other information Surface Tension (N/m): Corrosion To Metals: Not determined. Corrosive Not relevant to classification of this product. Weight of evidence. Substance Data, Dissociation Constant, if available. 10. STABILITY AND REACTIVITY Reactivity: No reactivity hazards known under normal storage and use conditions. Chemical stability: Stable under normal storage and use conditions. Possibility of hazardous reactions: No hazardous reactions known under normal storage and use conditions. Conditions to avoid: None known under normal storage and use conditions. Incompatible materials: Keep away from products containing chlorine-based bleaching agents or sulphites. Reacts with alkali and metals. Hazardous decomposition products: Nitrogen oxides (NOx). 11. TOXICOLOGICAL INFORMATION Information On Toxicological Effects Mixture Data Acute Inhalation Toxicity Result: Species: Method: Mist Not applicable Weight of evidence Relevant Calculated ATE(s) ATE - Oral (mg/kg): ATE _ Inhalatory, mists (mg/l): Not applicable >5 Substance data, where relevant and available, are listed below. Acute toxicity Acute oral toxicity Ingredients Nitric Acid Phosphoric Acid Acute dermal toxicity Ingredients Nitric Acid Phosphoric Acid Endpoint LD50 Endpoint LD50 Value (mg/kg) No data available >300-5000 Value (mg/kg) No data available 2740 Species Rat Method Exposure Time (h) OECD 423 (EU B.1 tris). Species Rabbit Method Method not given Exposure Time (h) Acute inhalative toxicity Ingredients Nitric Acid Phosphoric Acid Irritation and corrosivity Skin irritation and corrosivity Ingredients Nitric Acid Phosphoric Acid Endpoint LC50 LC50 Result Corrosive Corrosive Value (mg/l) >2.65 (vapour)_ 850 Species Rat Rat Super Dilac VA4 Page 8 of 12 SDS Revision Date: 08/09/2019 Print Date 06/02/2020 Method OECD 403 (EU B.2) Method not given Exposure Time (h) 2 Species Rabbit Rabbit Method Method not given OECD 404 (EU B.4) Exposure Time (h) Eye irritation and corrosivity Ingredients Nitric Acid Phosphoric Acid Result Corrosive Severe damage Species Rabbit Method Method not given Method not given Exposure Time (h) Respiratory tract irritation and corrosivity Ingredients Result Nitric Acid No data available Phosphoric Acid No data available Species Method Exposure Time (h) Sensitisation - Sensitisation by skin contact Ingredients Result Nitric Acid No data available Phosphoric Acid Not sensitising Species Human Method Human Experience Exposure Time (h) Sensitisation by inhalation Ingredients Nitric Acid Phosphoric Acid Result No data available No data available Species Method Exposure Time (h) CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction) Mutagenicity Ingredients Result (in vitro) Method (in vitro) Nitric Acid No evidence for mutagenicity, negative test results OECD 471 (EU B.12/13) Phosphoric Acid No evidence for mutagenicity, negative test results OECD 471 (EU B.12/13) OECD 473 OECD 476 (Mouse lymphoma) Result (in vivo) No data available No data available Method (in vivo) Carcinogenicity Ingredient(s) Nitric Acid Phosphoric Acid Effect No evidence for carcinogenicity, negative test results No data available Toxicity for reproduction Ingredient(s) End point Nitric Acid NOAEL Phosphoric Acid NOAEL Specific effect Developmental toxicity Developmental toxicity Value (mg/kg bw/d) 1500 410 Species Rat Rat Method OECD 422 oral OECD 422 oral Exposure Time 28 days 10 days Remarks & other effects reported Not toxic for reproduction No evidence for reproductive or developmental toxicity Repeated dose toxicity � Sub-acute or sub-chronic oral toxicity Ingredient(s) Endpoint Value (mg/kg bw/d) Nitric Acid NOAEL 1500 Phosphoric Acid NOAEL 250 Sub-chronic dermal toxicity Ingredient(s) Nitric Acid Phosphoric Acid Endpoint Value (mg/kg bw/d) No data available No data available Species Rat Rat Method OECD 422 oral OECD 422 oral Exposure time (days) 28 Specific effects & organs affected Species Method Exposure Specific effects & time (days) organs affected Sub-chronic inhalation toxicity Ingredient(s) Endpoint Nitric Acid Phosphoric Acid Value (mg/kg bw/d) No data available No data available Species Method Super Dilac VA4 Page 9 of 12 SDS Revision Date: 08/09/2019 Print Date 06/02/2020 Exposure Specific effects & time (days) organs affected Chronic toxicity Ingredient(s) Nitric Acid Phosphoric Acid Exposure route End point Value (mg/kg bw/d) No data available No data available Species Method Exposure time Specific effects & Remark organs affected STOT � Single Exposure Ingredient(s) Nitric Acid Phosphoric Acid Affected organ(s) No data available No data available STOT � Repeated Exposure Ingredient(s) Nitric Acid Phosphoric Acid Affected organ(s) No data available No data available Aspiration Hazard: Substances with an aspiration hazard (H304), if any, are listed in section 3. If relevant, see section 9 for dynamic viscosity and relative density of the product. Potential Adverse Health Effects And Symptoms: Effects and symptoms related to the product, if any, are listed in section 4. 12. ECOLOGICAL INFORMATION Toxicity No data is available on the mixture. Substance data, where relevant and available, are listed below Aquatic short-term toxicity Aquatic short-term toxicity � fish Ingredient(s) Endpoint Nitric Acid LC50 Phosphoric Acid LC50 Value (mg/l) 12.5 138 Species Gambusia Affinis Gambusia Affinis Aquatic short-term toxicity � crustacea Ingredient(s) Endpoint Value (mg/l) Nitric Acid EC50 8609 Phosphoric Acid EC50 >100 Species Daphnia Magna Straus Daphna Magna Straus Aquatic short-term toxicity � algae Ingredient(s) Endpoint Nitric Acid Phosphoric Acid EC50 Value (mg/l) No data available >100 Species Desmodesmus Subspicatus Aquatic short-term toxicity - marine species Ingredient(s) Endpoint Value (mg/l) Nitric Acid No data available Phosphoric Acid No data available Species Method Method not given Method not given Exposure Time (h) 96 96 Method Non guideline test OECD 202 Exposure Time (h) 24 48 Method OECD 201 (EU C.3) Exposure Time (h) 72 Method Exposure Time (h) Impact on sewage plants - toxicity to bacteria Ingredient(s) Endpoint Value (mg/l) Nitric Acid No data available Phosphoric Acid EC50 270 Aquatic long-term toxicity Aquatic long-term toxicity � fish Ingredients Endpoint Value (mg/l) Nitric Acid Phosphoric Acid LD50 8226 No data available Inoculum Activated sludge Method Method not given Exposure Time (h) Species Method Oncorhynchus Mykiss Method not given Exposure Time 96 hrs Effects Observed Aquatic long-term toxicity � crustacea Ingredients Endpoint Value (mg/l) Nitric Acid No data available Phosphoric Acid No data available Species Method Super Dilac VA4 Page 10 of 12 SDS Revision Date: 08/09/2019 Print Date 06/02/2020 Exposure Time Effects Observed Aquatic toxicity to other aquatic benthic organisms, including sediment-dwelling organisms, if available: Ingredients Endpoint Value (mg/kg dw sediment) Species Method Exposure Time Nitric Acid No data available Phosphoric Acid No data available Effects Observed Terrestrial Toxicity Terrestrial toxicity - soil invertebrates, including earthworms, if available: Ingredients Endpoint Value (mg/kg dw soil ) Species Nitric Acid No data available Phosphoric Acid No data available Method Exposure Time Effects Observed Terrestrial toxicity - plants, if available Ingredients Endpoint Value (mg/kg dw soil ) Nitric Acid No data available Phosphoric Acid No data available Species Method Exposure Time Effects Observed Terrestrial toxicity - birds, if available Ingredients Endpoint Value Nitric Acid No data available Phosphoric Acid No data available Species Method Exposure Time Effects Observed Terrestrial toxicity - beneficial insects, if available Ingredients Endpoint Value (mg/kg dw soil ) Nitric Acid No data available Phosphoric Acid No data available Species Method Exposure Time Effects Observed Terrestrial toxicity - soil bacteria, if available Ingredients Endpoint Value (mg/kg dw soil ) Nitric Acid No data available Phosphoric Acid No data available Species Method Exposure Time Effects Observed Persistence And Degradability Abiotic degradation - photodegradation in air, if available: Abiotic degradation - hydrolysis, if available: Abiotic degradation - other processes, if available: Biodegradation Ready biodegradability - aerobic conditions Ingredient(s) Inoculum Analytical Method DT50 Nitric Acid Phosphoric Acid Ready biodegradability - anaerobic and marine conditions, if available: Degradation in relevant environmental compartments, if available: Bioaccumulative potential Partition coefficient n-octanol/water (log Kow) Ingredient(s) Value Nitric Acid -2.3 Phosphoric Acid No data available Method Method not given Bioconcentration factor (BCF) Ingredient(s) Value Nitric Acid No data available Phosphoric Acid No data available Method Method Evaluation Not applicable � (inorganic substance) Not applicable � (inorganic substance) Evaluation Not relevant, does not bioaccumulate. No bioaccumulation expected. Evaluation No bioaccumulation expected. Remark Remark Mobility in soil Adsorption/Desorption to soil or sediment Ingredient(s) Adsorption coefficient Log Koc Nitric Acid No data available Phosphoric Acid No data available Desorption coefficient Log Koc(des) Method Results of PBT and vPvB assessment Substances that fulfill the criteria for PBT/vPvB, if any, are listed in section 3. Other adverse effects No other adverse effects known. Soil / sediment type Super Dilac VA4 Page 11 of 12 SDS Revision Date: 08/09/2019 Print Date 06/02/2020 Evaluation Mobile in aqueous environment Potential for mobility in soil, soluble in water. 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Waste from residues/unused The concentrated contents or contaminated packaging should be disposed of by a certified Products: handler or according to the site permit. Release of waste to sewers is discouraged. The cleaned packaging is suitable for energy recovery or recycling in line with local legislation. European Waste Catalogue: 20 01 14* - acids . Empty packaging Recommendation: Dispose of observing national or local regulations. Suitable cleaning agents: Water, if necessary with cleaning agent. 14. TRANSPORT INFORMATION Land transport (ADR/RID), Sea transport (IMDG), Air transport (ICAO-TI / IATA-DGR) UN number: 2031 UN proper shipping name: Nitric acid, solution Transport hazard class(es) Class (and subsidiary risk): 8 Packing group: II Environmental hazards: Environmentally hazardous: Marine pollutant: Special precautions for user: No No None known. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: The product is not transported in bulk tankers. Other Relevant Information ADR Classification code: C1 Tunnel restriction code: E Hazard identification number: 80 IMO/IMDG EmS: F-A, S-B The product has been classified, labelled and packaged in accordance with the requirements of ADR and the provisions of the IMDG Code. Transport regulations include special provisions for certain classes of dangerous goods packed in limited quantities. 15. REGULATORY INFORMATION Safety, Health And Environmental Regulations/Legislation Specific For The Substance Or Mixture EU regulations: Regulation (EC) No. 1907/2006 - REACH Regulation (EC) No 1272/2008 - CLP Regulation (EC) No. 648/2004 - Detergents regulation Authorisations or restrictions (Regulation [EC] No 1907/2006, Title VIII, respectively Title VIII): Not applicable UFI: W394-90EC-A00Y-0HPS Ingredients according to EC Detergents Regulation 648/2004: Super Dilac VA4 Page 12 of 12 SDS Revision Date: 08/09/2019 Print Date 06/02/2020 Chemical safety assessment: A chemical safety assessment has not been carried out on the mixture 16. OTHER INFORMATION The information in this document is based on our best present knowledge. However, it does not constitute a guarantee for any specific product features and does not establish a legally binding contract MSDS code: MSDS1994 Revision: 8th September 2019. Reason for revision: Overall design adjusted in accordance with Amendment 453/2010, Annex II of Regulation (EC) No 1907/2006, Classification procedure: The classification of the mixture is in general based on calculation methods using substance data, as required by Regulation (EC) No 1272/2008. If for certain classifications data on the mixture is available or for example bridging principles or weight of evidence can be used for classification, this will be indicated in the relevant sections of the Safety Data Sheet. See section 9 for physical chemical properties, section 11 for toxicological information and section 12 for ecological information Full text of theH and EUH H272 phrases mentioned in section 3: H290 H303 H314 H331 May intensify fire; oxidiser. May be corrosive to metals May be harmful if swallowed. Causes sever skin burns and eye damage. Toxic if inhaled. Abbreviations and acronyms: AISE The international Association for Soaps, Detergents and Maintenance Products ATE Acute Toxicity Estimate. DNEL Derived No Effect Limit EC50 Effective concentration, 50% EUH CLP Specific hazard statement LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal dose NOAEL No observed adverse effect level NOEL No observed effect level OECD Organization for Economic Cooperation and Development PBT Persistent, Bioaccumulative and Toxic PNEC Predicted No Effect Concentration REACH number - REACH registration number, without supplier specific part vPvB very Persistent and very Bioaccumulative End of Safety Data Sheet.