SDS_Cafiza_Espresso_Cleaner_(GB)_v6 Safety Data Sheet Cafiza 1

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Page 1/8

Safety Data Sheet

according to 1907/2006/EC, Article 31

Printing date: 09.02.2015 Revision: 09.02.2015Version No: 6

40.0.6

*

SECTION 1: Identification of the substance/mixture and of the company/undertaking

· 1.1 Product identifier

· Trade name: Cafiza Espresso Cleaner

· 1.2 Relevant identified uses of the substance or mixture and uses advised against

· Application of the substance / the preparation: Coffee/Espresso machine/equipment cleaner

· Uses advised against: No further relevant information available.

· 1.3 Details of the supplier of the safety data sheet

· Manufacturer/Supplier:

Urnex Brands, Inc. Urnex Brands, Inc.

700 Executive Blvd. 29 Harley Street, London, W1G 9QR

Elmsford, NY 10523 USA United Kingdom

Phone: +1-914-963-2042 Tel: +44 (0)20 7927 6881

Fax: +1-914-963-2145

Email: info@urnex.com

· Further information obtainable from:

Urnex Brands, Inc.

700 Executive Blvd.

Elmsford, NY 10523 USA

Phone: +1-914-963-2042

Fax: +1-914-963-2145

Email: info@urnex.com

· 1.4 Emergency telephone number:

Tel.: 800-424-9300 (USA)

Tel.: 001-703-527-3887 (INTERNATIONAL COLLECT ACCEPTED)

*

SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture

· Classification according to Regulation (EC) No 1272/2008

Skin Irrit. 2 H315 Causes skin irritation.

Eye Irrit. 2 H319 Causes serious eye irritation.

STOT SE 3 H335 May cause respiratory irritation.

· Classification according to Directive 67/548/EEC or Directive 1999/45/EC

Xi; Irritant

R36/37/38: Irritating to eyes, respiratory system and skin.

· Information concerning particular hazards for human and environment:

The product has to be labelled due to the calculation procedure of the "General Classification guideline for

preparations of the EU" in the latest valid version.

· Classification system:

The classification is according to the latest editions of the EU-lists, and extended by company and literature

data.

· 2.2 Label elements

· Labelling according to Regulation (EC) No 1272/2008

The product is classified and labelled according to the CLP regulation.

· Hazard pictograms

~

GHS07

(Contd. on page 2)

GB

Page 2/8

Safety Data Sheet

according to 1907/2006/EC, Article 31

Printing date: 09.02.2015 Revision: 09.02.2015Version No: 6

Trade name: Cafiza Espresso Cleaner

(Contd. of page 1)

40.0.6

· Signal word Warning

· Hazard-determining components of labelling:

Phosphoric acid, trisodium salt, dodecahydrate

· Hazard statements

H315 Causes skin irritation.

H319 Causes serious eye irritation.

H335 May cause respiratory irritation.

· Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if

present and easy to do. Continue rinsing.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P312 Call a POISON CENTER/doctor if you feel unwell.

P405 Store locked up.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P501 Dispose of contents/container in accordance with local/regional/national/international

regulations.

· 2.3 Other hazards

· Results of PBT and vPvB assessment

· PBT: Not determined

· vPvB: Not determined

*

SECTION 3: Composition/information on ingredients

· 3.2 Chemical characterisation: Mixtures

· Dangerous components:

CAS: 10101-89-0 Phosphoric acid, trisodium salt, dodecahydrate

?@G?@G

Xi R36/37/38

~

Skin Irrit. 2, H315; Eye Irrit. 2, H319; STOT SE 3, H335

< 50%

CAS: 15630-89-4

EINECS: 239-707-6

disodium carbonate, compound with hydrogenperoxide (2:3)

?@G?@G

Xn R22;

?@G?@G

Xi R41;

?@E?@E

O R8

~

Ox. Liq. 2, H272;

~

Eye Dam. 1, H318;

~

Acute Tox. 4, H302

< 20%

CAS: 25155-30-0

EINECS: 246-680-4

sodium dodecylbenzenesulphonate, pure

?@G?@G

Xn R22

~

Acute Tox. 4, H302

< 5%

CAS: 497-19-8

EINECS: 207-838-8

Index number: 011-005-00-2

sodium carbonate

?@G?@G

Xi R36

~

Eye Irrit. 2, H319

< 5%

CAS: 68439-46-3 Alcohols, C9-11, ethoxylated

?@G?@G

Xn R22;

?@G?@G

Xi R36/38

~

Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Irrit. 2, H319

≤

1%

· Regulation (EC) No 648/2004 on detergents / Labelling for contents

phosphates

≥

30%

oxygen-based bleaching agents 15 - 30%

non-ionic surfactants < 5%

· Additional information: For the wording of the listed risk phrases refer to section 16.

GB

(Contd. on page 3)

Page 3/8

Safety Data Sheet

according to 1907/2006/EC, Article 31

Printing date: 09.02.2015 Revision: 09.02.2015Version No: 6

Trade name: Cafiza Espresso Cleaner

(Contd. of page 2)

40.0.6

*

SECTION 4: First aid measures

· 4.1 Description of first aid measures

· General information:

Take affected persons out of danger area and lay down.

Immediately remove any clothing soiled by the product.

· After inhalation: Supply fresh air; consult doctor in case of complaints.

· After skin contact:

Immediately wash with water and soap and rinse thoroughly.

If skin irritation continues, consult a doctor.

· After eye contact:

Rinse opened eye for several minutes under running water. Then consult a doctor.

Remove contact lenses, if present and easy to do. Continue rinsing.

· After swallowing:

Rinse out mouth and then drink plenty of water.

Seek immediate medical advice.

· 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.

· 4.3 Indication of any immediate medical attention and special treatment needed

No further relevant information available.

*

SECTION 5: Firefighting measures

· 5.1 Extinguishing media

· Suitable extinguishing agents:

CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

Use fire extinguishing methods suitable to surrounding conditions.

· For safety reasons unsuitable extinguishing agents: Water with full jet

· 5.2 Special hazards arising from the substance or mixture

Formation of toxic gases is possible during heating or in case of fire.

Carbon monoxide

Carbon dioxide

Under certain fire conditions, traces of other toxic gases cannot be excluded.

· 5.3 Advice for firefighters

· Protective equipment: Wear self-contained respiratory protective device.

· Additional information

Cool endangered receptacles with water spray.

Collect contaminated fire fighting water separately. It must not enter the sewage system.

SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures

Ensure adequate ventilation.

Wear protective clothing.

Avoid formation of dust.

· 6.2 Environmental precautions:

Dilute with plenty of water.

Do not allow to enter sewers/ surface or ground water.

· 6.3 Methods and material for containment and cleaning up:

Pick up mechanically.

Ensure adequate ventilation.

Dispose of the material collected according to regulations.

· 6.4 Reference to other sections

See Section 7 for information on safe handling.

See Section 8 for information on personal protection equipment.

(Contd. on page 4)

GB

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Safety Data Sheet

according to 1907/2006/EC, Article 31

Printing date: 09.02.2015 Revision: 09.02.2015Version No: 6

Trade name: Cafiza Espresso Cleaner

(Contd. of page 3)

40.0.6

See Section 13 for disposal information.

SECTION 7: Handling and storage

· 7.1 Precautions for safe handling

Ensure good ventilation/exhaustion at the workplace.

Any unavoidable deposit of dust must be regularly removed.

· Information about fire and explosion protection: Keep respiratory protective device available.

· 7.2 Conditions for safe storage, including any incompatibilities

· Storage:

· Requirements to be met by storerooms and receptacles: Store only in the original receptacle.

· Information about storage in one common storage facility: Store away from oxidising agents.

· Further information about storage conditions:

Keep container tightly sealed.

Store under lock and key and out of the reach of children.

Protect from humidity and water.

· 7.3 Specific end use(s) No further relevant information available.

*

SECTION 8: Exposure controls/personal protection

· 8.1 Control parameters

· Ingredients with limit values that require monitoring at the workplace:

The product does not contain any relevant quantities of materials with critical values that have to be

monitored at the workplace.

· 8.2 Exposure controls

· Personal protective equipment:

· General protective and hygienic measures:

Do not inhale dust / smoke / mist.

Avoid contact with the eyes and skin.

The usual precautionary measures are to be adhered to when handling chemicals.

· Respiratory protection: Not necessary if room is well-ventilated.

· Protection of hands:

`SProtective gloves

Avoid direct contact with the chemical/ the product/ the preparation by organisational measures.

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.

· Material of gloves

Natural rubber, NR

Nitrile rubber, NBR

The selection of the suitable gloves does not only depend on the material, but also on further marks of quality

and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the

resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the

application.

· Penetration time of glove material

The exact break through time has to be found out by the manufacturer of the protective gloves and has to be

observed.

· Eye protection: Safety glasses

(Contd. on page 5)

GB

Page 5/8

Safety Data Sheet

according to 1907/2006/EC, Article 31

Printing date: 09.02.2015 Revision: 09.02.2015Version No: 6

Trade name: Cafiza Espresso Cleaner

(Contd. of page 4)

40.0.6

· Body protection: Protective work clothing

*

SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties

· General Information

· Appearance:

Form: Solid

Colour: White

· Odour: Characteristic

· pH-value (10 g/l) at 20 °C: 11.15 - 11.4

· Change in condition

Melting point/Melting range: Not determined.

Boiling point/Boiling range: Not determined.

· Flash point: Not determined.

· Flammability (solid, gaseous): Product is not flammable.

· Ignition temperature: Not determined.

· Decomposition temperature: Not determined.

· Self-igniting: Product is not selfigniting.

· Danger of explosion: Product does not present an explosion hazard.

· Explosion limits:

Oxidising properties No

· Density: Not determined.

· Solubility in / Miscibility with

water: Soluble.

· 9.2 Other information No further relevant information available.

*

SECTION 10: Stability and reactivity

· 10.1 Reactivity No further relevant information available.

· 10.2 Chemical stability No decomposition if used and stored according to specifications.

· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.

· 10.3 Possibility of hazardous reactions No dangerous reactions known.

· 10.4 Conditions to avoid No further relevant information available.

· 10.5 Incompatible materials:

Strong oxidizing agents

Reducing agent

· 10.6 Hazardous decomposition products: No dangerous decomposition products known.

GB

(Contd. on page 6)

Page 6/8

Safety Data Sheet

according to 1907/2006/EC, Article 31

Printing date: 09.02.2015 Revision: 09.02.2015Version No: 6

Trade name: Cafiza Espresso Cleaner

(Contd. of page 5)

40.0.6

SECTION 11: Toxicological information

· 11.1 Information on toxicological effects

· Acute toxicity:

· LD/LC50 values relevant for classification:

10101-89-0 Phosphoric acid, trisodium salt, dodecahydrate

Oral LD50 7400 mg/kg (Rat)

15630-89-4 disodium carbonate, compound with hydrogenperoxide (2:3)

Oral LD50 1034 mg/kg (Rat)

25155-30-0 sodium dodecylbenzenesulphonate, pure

Oral LD50 438 mg/kg (Rat)

497-19-8 sodium carbonate

Oral LD50 4090 mg/kg (Rat)

68439-46-3 Alcohols, C9-11, ethoxylated

Oral LD50 >500-5000 mg/kg (Rat)

Dermal LD50 >2000

≤

20000 mg/kg (Rabbit)

· Primary irritant effect:

· on the skin: Irritant to skin and mucous membranes.

· on the eye: Irritating effect.

· Sensitisation: No sensitising effects known.

· Additional toxicological information:

The product shows the following dangers according to the calculation method of the General EU

Classification Guidelines for Preparations as issued in the latest version:

Irritant

SECTION 12: Ecological information

· 12.1 Toxicity

· Aquatic toxicity: No further relevant information available.

· 12.2 Persistence and degradability

Anorganic product, is not eliminable from water by means of biological cleaning processes.

The organic portion of the product is biodegradable.

· 12.3 Bioaccumulative potential No further relevant information available.

· 12.4 Mobility in soil No further relevant information available.

· Additional ecological information:

· General notes:

Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage

system.

Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water

Do not allow product to reach ground water, water course or sewage system.

· 12.5 Results of PBT and vPvB assessment

· PBT: Not determined

· vPvB: Not determined

· 12.6 Other adverse effects No further relevant information available.

GB

(Contd. on page 7)

Page 7/8

Safety Data Sheet

according to 1907/2006/EC, Article 31

Printing date: 09.02.2015 Revision: 09.02.2015Version No: 6

Trade name: Cafiza Espresso Cleaner

(Contd. of page 6)

40.0.6

SECTION 13: Disposal considerations

· 13.1 Waste treatment methods

· Recommendation: Smaller quantities can be disposed of with household waste.

· Uncleaned packaging

· Recommendation: Disposal must be made according to official regulations.

SECTION 14: Transport information

· 14.1 UN-Number

· ADR, ADN, IMDG, IATA Void

· 14.2 UN proper shipping name

· ADR, ADN, IMDG, IATA Void

· 14.3 Transport hazard class(es)

· ADR, ADN, IMDG, IATA

· Class Void

· 14.4 Packing group

· ADR, IMDG, IATA Void

· 14.5 Environmental hazards:

· Marine pollutant: No

· 14.6 Special precautions for user Not applicable.

· 14.7 Transport in bulk according to Annex II of

MARPOL73/78 and the IBC Code: Not applicable.

· Transport/Additional information: Not dangerous according to the above specifications.

· UN "Model Regulation": -

*

SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

No further relevant information available.

· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee for any

specific product features and shall not establish a legally valid contractual relationship.

· Relevant phrases

H272 May intensify fire; oxidiser.

H302 Harmful if swallowed.

H315 Causes skin irritation.

H318 Causes serious eye damage.

H319 Causes serious eye irritation.

H335 May cause respiratory irritation.

R22 Harmful if swallowed.

R36 Irritating to eyes.

(Contd. on page 8)

GB

Page 8/8

Safety Data Sheet

according to 1907/2006/EC, Article 31

Printing date: 09.02.2015 Revision: 09.02.2015Version No: 6

Trade name: Cafiza Espresso Cleaner

(Contd. of page 7)

40.0.6

R36/37/38 Irritating to eyes, respiratory system and skin.

R36/38 Irritating to eyes and skin.

R41 Risk of serious damage to eyes.

R8 Contact with combustible material may cause fire.

· Department issuing SDS:

Chemservice GmbH

Herrnsheimer Hauptstrasse 1b

D-67550 Worms

Tel.: +49 (0)6241-95480-0

Fax: +49 (0)6241-95480-25

Email: sds@chemservice-group.com

· Contact: sds@chemservice-group.com

· Abbreviations and acronyms:

REACH: Registration, Evaluation, Authorisation and Restriction of Chemicals

MARPOL: (from Marine Pollutant) International Convention for the Prevention of Marine Pollution from Ships

IBC Code: International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk

UN: United Nations (also UNO: United Nations Organization)

NOEC: No Observed Effect Concentration

OECD: Organisation for Economic Co-operation and Development

ASTM: American Society for Testing and Materials

WAF: Water Accommodated Fraction

ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International

Carriage of Dangerous Goods by Road)

IMDG: International Maritime Code for Dangerous Goods

IATA: International Air Transport Association

GHS: Globally Harmonised System of Classification and Labelling of Chemicals

EINECS: European Inventory of Existing Commercial Chemical Substances

ELINCS: European List of Notified Chemical Substances

CAS: Chemical Abstracts Service (division of the American Chemical Society)

LC50: Lethal concentration, 50 percent

LD50: Lethal dose, 50 percent

PBT: Persistent, Bioaccumulative and Toxic

vPvB: very Persistent and very Bioaccumulative

Ox. Liq. 2: Oxidising Liquids, Hazard Category 2

Acute Tox. 4: Acute toxicity, Hazard Category 4

Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2

Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1

Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2

STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3

· * Data compared to the previous version altered.

GB