MethAlert Step 2 Developer SAFETY DATA SHEET (SDS) Form 79894 PDF
User Manual: 79894
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SKC Inc. skcinc.com SAFETY DATA SHEET Revision Date 07/31/2015 1. PRODUCT AND COMPANY IDENTIFICATION 1.1 1.2 Product identifiers Product name : MethAlert Step 2 Developer Product Number Brand : : 560-001, Component SKC Inc. Relevant identified uses of the substance or mixture and uses advised against Identified uses 1.3 : Used with SKC MethAlert Kit Details of the supplier of the safety data sheet Company : SKC, Inc. 863 Valley View Rd. Eighty Four, PA 15330 USA Telephone Fax 1.4 : : 724-941-9701; 800-752-8472 (Mon - Fri, 8:30 a.m. - 5:00 p.m. EST) 724-941-1369 (Mon-Fri, 8:30 a.m. - 5:00 p.m. EST) Emergency telephone number Emergency Phone # : CHEMTREC at 800-424-9300 (U.S./Canada); 703-741-5970 (Global) 2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) Flammable liquids (Category 1), H224 Eye irritation (Category 2A), H319 Carcinogenicity (Category 2), H351 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 Acute aquatic toxicity (Category 3), H402 + H301 For the full text of the H-Statements mentioned in this Section, see Section 16. 2.2 GHS Label elements, including precautionary statements Pictogram Signal word Danger Hazard statement(s) H224 H301 H319 H335 H351 H402 Extremely flammable liquid and vapour. Toxic if swallowed. Causes serious eye irritation. May cause respiratory irritation. Suspected of causing cancer. Harmful to aquatic life. Precautionary statement(s) P201 P202 Form # 79894 Rev 1507 Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Page 1 of 9 P210 P233 P240 P241 P242 P243 P261 P264 P270 P271 P273 P280 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ ventilating/ lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Wash skin thoroughly after handling. Do not eat, drink, or smoke when using this product. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear protective gloves/ protective clothing/ eye protection/ face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Rinse mouth. IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up. Dispose of contents/ container to an approved waste disposal plant. P301 + P310 + P330 P303 + P361 + P353 P304 + P340 P305 + P351 + P338 P308 + P313 P337 + P313 P370 + P378 P403 + P233 P403 + P235 P405 P501 2.3 Hazards not otherwise classified (HNOC) or not covered by GHS Lachrymator., Photosensitizer. May form explosive peroxides. 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Substances Hazardous components Component Classification Concentration Component 1 Trade Secret Flam. Liq. 1; Eye Irrit. 2A; STOT SE 3; Aquatic Acute 3; H224, H319, H335, H402 6% Component 2 Trade Secret Acute Tox. 3, H301 2% Distilled water 92 % For the full text of the H-Statements mentioned in the Section, see Section 16. Important Note: As required by OSHA regulations, hazardous information supplied is based on exposure to reagent-grade (fullstrength) chemicals. SKC MethAlert Kit contains a dilute solution of component 1 and component 2. Component 1 has been reported to be possibly carcinogenic based on its IARC, ACGIH, NTP, and EPA classification. Component 2 is not listed as a carcinogen. 4. FIRST AID MEASURES 4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. Form # 79894 Rev 1507 Page 2 of 9 In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available 5. FIREFIGHTING MEASURES 5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides, nitrogen oxides (NOx), sodium oxides, iron oxides 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information Use water spray to cool unopened containers. 6. ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). 6.4 Reference to other sections For disposal see section 13. 7. HANDLING AND STORAGE 7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Avoid formation of aerosols. Use explosion-proof equipment.Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature 2 - 8 °C Refrigerate before opening. 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated Form # 79894 Rev 1507 Page 3 of 9 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters Components with workplace control parameters Component Value Control parameters Basis Component 1 C 25 ppm USA. ACGIH Threshold Limit Values (TLV) Trade Secret Remarks Upper Respiratory Tract irritation Eye irritation Adopted values or notations enclosed are those for which changes are proposed in the NIC See Notice of Intended Changes (NIC) Confirmed animal carcinogen with unknown relevance to humans Potential Occupational Carcinogen See Appendix C See Appendix A TWA 200 ppm USA. Occupational Exposure Limits (OSHA) 360 mg/m3 Table Z-1 Limits for Air Contaminants The value in mg/m3 is approximate. C 25 ppm USA. ACGIH Threshold Limit Values (TLV) Upper Respiratory Tract irritation Eye irritation 2014 Adoption Suspected human carcinogen Component Component 2 Trade Secret 8.2 Value TWA Remarks Control parameters 5 mg/m3 CAS number varies with compound Skin designation C 5 mg/m3 Upper Respiratory Tract irritation Headache Nausea Thyroid effects Danger of cutaneous absorption varies TWA 1 mg/m3 Upper Respiratory Tract irritation Skin irritation varies C 4.7 ppm 5 mg/m3 10 minute ceiling value TWA 1 mg/m3 Basis USA. Occupational Exposure Limits (OSHA) Table Z-1 Limits for Air Contaminants USA. ACGIH Threshold Limit Values (TLV) USA. ACGIH Threshold Limit Values (TLV) USA. NIOSH Recommended Exposure Limits USA. NIOSH Recommended Exposure Limits Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove’s outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Form # 79894 Rev 1507 Page 4 of 9 Full contact Material: butyl-rubber Minimum layer thickness: 0.3 mm Break through time: 480 min Material tested:Butoject® (KCL 897 / Aldrich Z677647, Size M) Splash contact Material: butyl-rubber Minimum layer thickness: 0.3 mm Break through time: 480 min Material tested:Butoject® (KCL 897 / Aldrich Z677647, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario. Body Protection Complete suit protecting against chemicals, Flame retardant antistatic protective clothing., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multipurpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties a) Appearance Form: liquid, clear Colour: colourless b) Odour no data available c) Odour Threshold no data available d) pH no data available e) Melting point/freezing point no data available f) Initial boiling point and boiling range no data available g) Flash point no data available h) Evapouration rate no data available i) Flammability (solid, gas) no data available j) Upper/lower flammability or explosive limits no data available k) Vapour pressure no data available l) Vapour density no data available m) Relative density no data available n) Water solubility completely miscible Form # 79894 Rev 1507 Page 5 of 9 9.2 o) Partition coefficient: noctanol/water no data available p) Auto-ignition temperature no data available q) Decomposition temperature no data available r) Viscosity no data available s) Explosive properties no data available t) Oxidizing properties no data available Other safety information no data available 10. STABILITY AND REACTIVITY 10.1 Reactivity No data available 10.2 Chemical stability Avoid exposure to air any longer than necessary so as to prevent peroxide formation. Stable under recommended storage conditions. Test for peroxide formation before distillation or evaporation. Test for peroxide formation or discard after 1 year. 10.3 Possibility of hazardous reactions Vapours may form explosive mixture with air. 10.4 Conditions to avoid Heat, flames and sparks. Extremes of temperature and direct sunlight. 10.5 Incompatible materials Oxidizing agents, Reducing agents, acids, Nitric acid, Peroxides, Bases, Sodium Hydroxide, Amines, Ammonia, Oxygen, Warning: Component 1 is oxidized rapidly and exothermically by air, to acetic acid, Acid anhydrides, Alcohols, Halogens, Ketones, Phenol, Hydrogen sulfide gas, Hydrogen peroxide 10.6 Hazardous decomposition products Other decomposition products - No data available In the event of fire: see section 5 11. TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects Acute toxicity Lowest observed effect level Oral - Rat - 675 mg/kg LC50 Inhalation - Rat - 4 h - 13300 ppm (OECD Test Guideline 403) Remarks: Behavioral:Excitement. Lungs, Thorax, or Respiration:Dyspnea. LD50 Dermal - Rabbit - 3,540 mg/kg LD50 Oral - Rat - 99 mg/kg No data available Skin corrosion/irritation Skin - Rabbit Result: Mild skin irritation (OECD Test Guideline 404) Serious eye damage/eye irritation No data available Respiratory or skin sensitisation Maximisation Test (GPMT) - Guinea pig Did not cause sensitisation on laboratory animals. (OECD Test Guideline 406) Form # 79894 Rev 1507 Page 6 of 9 Germ cell mutagenicity Laboratory experiments have shown mutagenic effects. Carcinogenicity This product is or contains a component that has been reported to be possibly carcinogenic based on its IARC, ACGIH, NTP, or EPA classification. Limited evidence of carcinogenicity in animal studies IARC: 2B - Group 2B: Possibly carcinogenic to humans (Component 1, Trade Secret) 1 - Group 1: Carcinogenic to humans (Component 1, Trade Secret) NTP: Reasonably anticipated to be a human carcinogen (Component 1, Trade Secret) OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. Reproductive toxicity No data available No data available Specific target organ toxicity - single exposure May cause respiratory irritation. Specific target organ toxicity - repeated exposure No data available Aspiration hazard No data available Additional Information RTECS: AB1925000 Blurred vision, Unconsciousness, Headache, Vomiting, Nausea, Pulmonary edema. Effects may be delayed., Convulsions, sneezing, Cough, Shortness of breath To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Liver - Irregularities - Based on Human Evidence Liver - Irregularities - Based on Human Evidence RTECS: LJ8925000 May cause cyanosis. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Stomach - Irregularities - Based on Human Evidence Stomach - Irregularities - Based on Human Evidence 12. ECOLOGICAL INFORMATION 12.1 Toxicity Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 31 mg/l - 96 h Toxicity to daphnia and other aquatic invertebrates Immobilization EC50 - Daphnia magna (Water flea) - 57.4 mg/l - 48 h (OECD Test Guideline 202) Toxicity to algae Growth inhibition EC50 - Pseudokirchneriella subcapitata (green algae) - > 100 mg/l - 24 h (OECD Test Guideline 201) Form # 79894 Rev 1507 Page 7 of 9 12.2 Persistence and degradability Biodegradability Biotic/Aerobic - Exposure time 14 d Result: 80 % - Readily biodegradable (OECD Test Guideline 301C) 12.3 Bioaccumulative potential No data available 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted 12.6 Other adverse effects An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Harmful to aquatic life. 13. DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Contaminated packaging Dispose of as unused product. 14. TRANSPORT INFORMATION DOT (US) UN number: 1089 Class: 3 Packing group: I Proper shipping name: (Component 1, Trade Secret) Reportable Quantity (RQ): 1000 lbs Poison Inhalation Hazard: No UN number: 3288 Class: 6.1 Packing group: III Proper shipping name: Toxic solid, inorganic, n.o.s. (Component 2, Trade Secret) Reportable Quantity (RQ): 1000 lbs Poison Inhalation Hazard: No IMDG UN number: 1089 Class: 3 Packing group: I Proper shipping name: (Component 1, Trade Secret) EMS-No: F-E, S-D UN number: 3288 Class: 6.1 Packing group: III EMS-No: F-A, S-A Proper shipping name: TOXIC SOLID, INORGANIC, N.O.S. (Component 2, Trade Secret) IATA UN number: 1089 Class: 3 Packing group: I Proper shipping name: (Component 1, Trade Secret) IATA Passenger: Not permitted for transport UN number: 3288 Class: 6.1 Packing group: III Proper shipping name: Toxic solid, inorganic, n.o.s. (Component 2, Trade Secret) 15. REGULATORY INFORMATION SARA 302 Components No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 Components The following components are subject to reporting levels established by SARA Title III, Section 313: Form # 79894 Rev 1507 Page 8 of 9 Comp 1 & 2 listed Trade Secret CAS-No. Revision Date CAS-No. Revision Date CAS-No. Revision Date CAS-No. Revision Date CAS-No. Revision Date CAS-No. Revision Date SARA 311/312 Hazards Fire Hazard, Acute Health Hazard, Chronic Health Hazard Massachusetts Right To Know Components Comp 1 listed Trade Secret Pennsylvania Right To Know Components Comp 1 & 2 listed Trade Secret New Jersey Right To Know Components Comp 1 & 2 listed Trade Secret California Prop. 65 Components Component 1 WARNING! This product contains a chemical known to the State of California to cause cancer. Component 2 WARNING! This product contains a chemical known to the State of California to cause birth defects and other reproductive harm. 16. OTHER INFORMATION Full text of H-Statements referred to under sections 2 and 3. Acute Tox. Aquatic Acute Eye Irrit. Flam. Liq. H224 H301 H319 H335 H351 H402 STOT SE Acute Toxicity Acute aquatic toxicity Eye irritation Flammable liquids Extremely flammable liquid and vapour. Toxic if swallowed. Causes serious eye irritation. May cause respiratory irritation. Suspected of causing cancer. Harmful to aquatic life. Specific target organ toxicity - single exposure Disclaimer For approved uses only. Not for drug, household, or other uses. The above information is believed to be correct but does not purport to be all-inclusive and shall be used only as a guide. SKC Inc. shall not be held liable for any damage resulting from handling or from contact with the above product. Latest Change(s): Updated SDS to bring into compliance with the GHS Last Update: July 2015 Form # 79894 Rev 1507 Page 9 of 9
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