DPD4_Buffer_Solution_GHS_SDS_269676 001_A 1 DPD4 Buffer Solution GHS SDS 269676 001 A

User Manual: DPD4_Buffer_Solution_GHS_SDS_269676-001_A-1

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SAFETY DATA SHEET DPD4 Buffer Solution
Prepared according to U.S. OSHA, CMA, ANSI, Canadian WHMIS regulations
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME:
DPD4 Buffer Solution
PRODUCT CODE:
970-210-0121
PRODUCT DESCRIPTION:
For water testing applications only
U.N. NUMBER:
UN1824
U.N. DANGEROUS GOODS CLASS:
Sodium Hydroxide Solution, Class 8, PGII
SUPPLIER/MANUFACTURER'S NAME:
Blue I Water Technologies LTD
ADDRESS:
18 Hamelacha St, Rosh Ha’ayin 4809148
ISRAEL P.O.Box 11433
EMERGENCY PHONE:
972-976-8004
BUSINESS PHONE:
972-976-8004
(For product information)
WEB SITE:
www.blueitechnologies.com
DATE OF PREPARATION:
November 12, 2013
DATE OF LAST REVISION:
November 12, 2013
SECTION 2 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
PRODUCT DESCRIPTION: This product is a colorless liquid with no odor.
HEALTH HAZARDS: Harmful if ingested. May cause irritation to skin and eyes upon contact. Inhalation of spray
or mist may cause respiratory irritation
FLAMMABILITY: This product is a Non-Flammable product with a flash point greater than 200°F.
ENVIRONMENTAL EFFECTS: The Environmental effects of this product have not been investigated, however
this product contains ingredients that may cause adverse effects to aquatic life.
US DOT SYMBOL(S) CANADA (WHMIS) SYMBOL(S) GHS HAZARD SYMBOL(S)
Signal Word: Danger!
COMPONENTS DETERMINING HAZARDS:
Tri-Sodium Citrate, Potassium Iodide, Sodium Hydroxide, EDTA Disodium Salt
GHS HAZARD CLASSIFICATION(S):
Acute Oral Toxicity Category
4 Eye Irritant Category 2
STOT SE Category 3
Skin Corrosive Category 1A
HAZARD STATEMENTS:
Harmful if swallowed
Causes serious skin burns and eye
damage May cause respiratory irritation
PRECAUTIONARY STATEMENTS:
Wear protective gloves/protective clothing/eye
protection Do not breath mist/spray
Use only in a well ventilated area Wash
hands thoroughly after handling
HEALTH HAZARDS OR RISKS FROM EXPOSURE:
ACUTE:
INHALATION: Inhalation of mist/spray may cause respiratory irritation.
EYE CONTACT: Direct eye contact can cause irritation with redness, tearing and blurred vision. Possible serious
eye damage.
SKIN CONTACT: May cause skin irritation with possible skin burns.
INGESTION: Ingestion of this product can cause chemical burns of mouth and throat. Causes severe pain,
nausea, vomiting and diarrhea.
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SAFETY DATA SHEET DPD4 Buffer Solution
CHRONIC: Prolonged or repeated contact with product and poor hygiene conditions may result in skin dryness
or dermatitis.
TARGET ORGANS: ACUTE: Eye, Skin, Respiratory System CHRONIC: Skin
SECTION 3 - COMPOSITION and INFORMATION ON INGREDIENTS
HAZARDS DISCLOSURE: This product does contain known hazardous materials in reportable levels as defined by
the OSHA Hazard Communication Standard 29 CFR 1910.1200. As defined under Sara 311 and 312, this product
contains known hazardous materials.
HAZARDOUS INGREDIENTS:
WT %
HAZARD CLASSIFICATION;
RISK PHRASES
Deionized Water
70 – 80%
HAZARD CLASSIFICATION: None
RISK PHRASES: None
Tri-Sodium Citrate
10 – 20%
HAZARD CLASSIFICATION: [Xi] Irritant
RISK PHRASES: R36/38
Potassium Iodide
1 – 10%
HAZARD CLASSIFICATION: [Xi] Irritant
RISK PHRASES: R36/37/38
Sodium Hydroxide
<5.5%
HAZARD CLASSIFICATION: [C] Corrosive
RISK PHRASES: R35
EDTA Disodium Salt
0.01 – 0.1%
HAZARD CLASSIFICATION: [Xn] Harmful
RISK PHRASES: R22
Each of the other components present are less than 1 percent concentration (0.1% concentration for potential carcinogens, reproductive toxins,
respiratory tract sensitizers, and mutagens)
NOTE: ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-2010 format.
SECTION 4 - FIRST-AID MEASURES
Contaminated individuals of chemical exposure must be taken for medical attention if any adverse effect occurs. Rescuers should
be taken for medical attention, if necessary. Take copy of label and SDS to health professional with contaminated individual.
EYE CONTACT: If product enters the eyes, open eyes while under gentle running water for at least 15 minutes. Seek
medical attention.
SKIN CONTACT: Wash skin thoroughly after handling. Seek medical attention if irritation develops and persists.
INHALATION: If breathing becomes difficult, remove victim to fresh air. If necessary, use artificial respiration to
support vital functions. Seek medical attention immediately.
INGESTION: If product is swallowed, call physician or poison control center for most current information. If professional
advice is not available, do not induce vomiting. Never induce vomiting or give diluents (milk or water) to someone who is
unconscious, having convulsions, or who cannot swallow. Seek medical advice. Take a copy of the label and/or SDS with
the victim to the health professional.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Individuals with pre-existing skin disorders should avoid
contact with this product.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and reduce over-exposure.
SECTION 5 - FIRE-FIGHTING MEASURES
FLASH POINT:
AUTOIGNITION TEMPERATURE: FLAMMABLE
LIMITS (in air by volume, %): FIRE
EXTINGUISHING MATERIALS: UNUSUAL FIRE
AND EXPLOSION HAZARDS:
Explosion Sensitivity to Mechanical Impact:
Explosion Sensitivity to Static Discharge:
SPECIAL FIRE-FIGHTING PROCEDURES:
NFPA Rating System
1
2 1
>200°F
Not Established
Lower (LEL): Not Established Upper (UEL): Not Established
Dry chemical, carbon dioxide, foam or water
spray. None known
Not Sensitive.
Not Sensitive
Incipient fire responders should wear eye protection. Structural
firefighters must wear Self-Contained Breathing Apparatus and full
protective equipment. Isolate materials not yet involved in the fire and
protect personnel. Move containers from fire area if this can be done
without risk; otherwise, cool with carefully applied water spray.
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SAFETY DATA SHEET DPD4 Buffer Solution
If possible, prevent runoff water from entering storm drains, bodies
of water, or other environmentally sensitive areas.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK RESPONSE: Personnel should be trained for spill response operations. Contain and recover if
possible. Cover spilled product with sand, earth or other non-combustible absorbent material. Pickup spilled
material immediately and place in appropriate containers. Dispose of in accordance with applicable Federal, State,
and local procedures (see Section 13, Disposal Considerations).
Do not discharge to sewers and surface waters. Notify authorities if entry occurs.
U.S. Regulations (CERCLA) requires reporting spills and releases to soil, water and air in excess of reportable
quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802.
SECTION 7 - HANDLING and STORAGE
WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product on you. Wash
thoroughly after handling this product. Use in a well-ventilated location.
STORAGE AND HANDLING PRACTICES: Store containers in a cool, dry location. Keep away from sources of
ignition. Keep container tightly closed when not in use. Protect from physical damage.
SECTION 8 - EXPOSURE CONTROLS - PERSONAL PROTECTION
EXPOSURE LIMITS/GUIDELINES:
Chemical Name
CAS#
ACGIH TWA
OSHA TWA
Deionized Water
7732-18-5
Not Listed
Not Listed
Tri-Sodium Citrate
6132-04-3
Not Listed
Not Listed
Potassium Iodide
7681-11-0
Not Listed
Not Listed
Sodium Hydroxide
1310-73-2
Not Listed
2 mg/m³
EDTA Disodium Salt
6381-92-6
Not Listed
Not Listed
Currently, International exposure limits are not established for all the components of this product. Please check with
competent authority in each country for the most recent limits in place.
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are
maintained below the limits provided above. Use local exhaust ventilation to control airborne vapors.
The following information on appropriate Personal Protective Equipment is provided to assist employers in complying
with OSHA regulations found in 29 CFR Subpart I (beginning at 1910.132) or equivalent standard of Canada. Please
reference applicable regulations and standards for relevant details.
RESPIRATORY PROTECTION: Not normally required when using this product. Maintain airborne contaminant
concentrations below guidelines listed above, if applicable. If necessary, use only respiratory protection authorized in
the U.S. Federal OSHA Respiratory Protection Standard (29 CFR 1910.134), equivalent U.S. State standards,
Canadian CSA Standard Z94.4-93.
EYE PROTECTION: Wear safety glasses or chemical goggles as appropriate where splashing is possible. If necessary,
refer to U.S. OSHA 29 CFR 1910.133 or appropriate Canadian Standards.
HAND PROTECTION: Wear chemical resistant gloves as appropriate to prevent skin contact. If necessary, refer to
U.S. OSHA 29 CFR 1910.138 or appropriate Standards of Canada.
BODY PROTECTION: Use body protection appropriate to prevent skin contact (e.g. lab coat, overalls). If necessary,
refer to appropriate Standards of U.S., Canada, or appropriate Standards of the EU, Australian Standards, or relevant
Japanese Standards.
SECTION 9 - PHYSICAL and CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
APPEARANCE & ODOR: Colorless liquid with no odor.
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SAFETY DATA SHEET
DPD4 Buffer Solution
ODOR THRESHOLD (PPM):
None
VAPOR PRESSURE (mmHg):
Not Available
VAPOR DENSITY (AIR=1):
Not Available
EVAPORATION RATE (nBuAc = 1):
Not Available
BOILING POINT (C°):
Not Available
FREEZING POINT (C°):
Not Available
pH:
13.5
SPECIFIC GRAVITY 20°C: (WATER =1)
>1
SOLUBILITY IN WATER (%)
Completely miscible
VOC:
None
SECTION 10 - STABILITY and REACTIVITY
STABILITY: Product is stable
DECOMPOSITION PRODUCTS: When heated to decomposition this product produces oxides of carbon and sodium
oxide, sodium peroxide fumes
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Strong
acids. HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Contact with incompatible materials
SECTION 11 - TOXICOLOGICAL INFORMATION
TOXICITY DATA: Toxicity data is available for the following
components: CAS# 6132-04-3
No LD50 Data Available
CAS# 1310-73-2
No LD50 Data Available
SUSPECTED CANCER AGENT: None of the ingredients are found on the following lists: FEDERAL OSHA Z LIST,
NTP, CAL/OSHA, IARC and therefore are not considered to be, nor suspected to be a cancer-causing agent by these
agencies.
IRRITANCY OF PRODUCT: Contact with this product can be irritating to skin, respiratory system and
eyes. SENSITIZATION OF PRODUCT: Ingredients in this product are not considered a sensitizer.
REPRODUCTIVE TOXICITY INFORMATION: No information available
SECTION 12 - ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ENVIRONMENTAL STABILITY: No specific data is available for this product, however this product is expected to be
readily biodegradable
EFFECT OF MATERIAL ON PLANTS or ANIMALS: No data available
EFFECT OF CHEMICAL ON AQUATIC LIFE: No data available
SECTION 13 - DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate Federal, State, and
local regulations.
SECTION 14 - TRANSPORTATION INFORMATION
US DOT; IATA; IMO; ADR:
THIS PRODUCT IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF
TRANSPORTATION.
PROPER SHIPPING NAME: Sodium Hydroxide Solution
HAZARD CLASS NUMBER and DESCRIPTION: Class 8
Corrosive UN IDENTIFICATION NUMBER: UN1824
PACKING GROUP: PGII
DOT LABEL(S) REQUIRED: Corrosive
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SAFETY DATA SHEET DPD4 Buffer Solution
NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (2012): 154
MARINE POLLUTANT: None of the ingredients are classified by the DOT as a Marine Pollutant (as defined by
49 CFR 172.101, Appendix B)
U.S. DEPARTMENT OF TRANSPORTATION (DOT) SHIPPING REGULATIONS:
This product is classified as Hazardous Material, per U.S. DOT regulations, under 49 CFR
172.101. TRANSPORT CANADA, TRANSPORTATION OF DANGEROUS GOODS REGULATIONS:
This product is classified as Dangerous Goods, per regulations of Transport
Canada. INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA):
This product is classified as Dangerous Goods, by rules of IATA:
INTERNATIONAL MARITIME ORGANIZATION (IMO) DESIGNATION:
This product is classified as Dangerous Goods by the International Maritime Organization.
SECTION 15 - REGULATORY INFORMATION
UNITED STATES REGULATIONS
SARA REPORTING REQUIREMENTS: This product is subject to the reporting requirements of Sections 302, 304
and 313 of Title III of the Superfund Amendments and Reauthorization Act., as follows: None
TSCA: All components in this product are listed on the US Toxic Substances Control Act (TSCA) inventory of
chemicals.
SARA 311/312:
Acute Health: Yes Chronic Health: No Fire: No Reactivity: No
U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for this
product. The default Federal SDS submission and inventory requirement filing threshold of 10,000 lb (4,540 kg)
may apply, per 40 CFR 370.20.
U.S. CERCLA REPORTABLE QUANTITY (RQ): CAS# 1310-73-2: final RQ = 1000 pounds (454 kg)
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): None of the
ingredients are on the California Proposition 65 lists.
CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS: All of the components of this product are on the DSL Inventory
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: No component of
this product is on the CEPA First Priorities Substance Lists.
CANADIAN WHMIS CLASSIFICATION and SYMBOLS: This is considered to be a hazardous material under the
Hazardous Products Act as defined by the Controlled Products Regulations and is therefore subject to the labeling
and SDS requirements of the Workplace Hazardous Materials Information System (WHMIS).Class D2B Materials
having other toxic effects and Class E Corrosive material.
INTERNATIONAL CHEMICAL INVENTORIES:
Listing of the components on individual country Chemical Inventories is as follows:
Asia-Pac:
Listed or Exempt
Australian Inventory of Chemical Substances (AICS):
Listed or Exempt
Korean Existing Chemicals List (ECL):
Listed or Exempt
Japanese Existing National Inventory of Chemical Substances (ENCS):
Listed or Exempt
Philippines Inventory if Chemicals and Chemical Substances (PICCS):
Listed or Exempt
Swiss Giftliste List of Toxic Substances:
Listed or Exempt
U.S. TSCA:
Listed
SECTION 16 - OTHER INFORMATION
GHS MSDS Compliance PLUS
Disclaimer:
This information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Blue I Water
Technologies. The data on this sheet is related only to the specific material designated herein. Blue I Water Technologies assumes no legal
responsibility for use or reliance upon this data.
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its
subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of
suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
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