DPD4_Indicator_Solution_GHS_SDS_269679 001_A DPD4 Indicator Solution GHS SDS 269679 001 A
User Manual: DPD4_Indicator_Solution_GHS_SDS_269679-001_A
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SAFETY DATA SHEET DPD4 Indicator Solution Prepared according to U.S. OSHA, CMA, ANSI, Canadian WHMIS regulations SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: PRODUCT CODE: PRODUCT DESCRIPTION: U.N. NUMBER: U.N. DANGEROUS GOODS CLASS: DPD4 Indicator Solution SUPPLIER/MANUFACTURER'S NAME: Blue I Water Technologies LTD ADDRESS: EMERGENCY PHONE: BUSINESS PHONE: WEB SITE: DATE OF PREPARATION: DATE OF LAST REVISION: 970-210-0121 For water testing applications only UN2796 Sulphuric Acid (with not more than 51% acid), Class 8, PGII 18 Hamelacha St, Rosh Ha’ayin 4809148 ISRAEL P.O.Box 11433 97297680004 972-976-8004 (For product information) www.blueitechnologies.com November 12, 2013 November 12, 2013 SECTION 2 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: PRODUCT DESCRIPTION: This product is a colorless liquid with no odor. HEALTH HAZARDS: Harmful if ingested. May cause severe irritation to skin and eyes upon contact. Inhalation of spray or mist may cause respiratory irritation FLAMMABILITY: This product is a Non-Flammable product with a flash point greater than 200°F. ENVIRONMENTAL EFFECTS: The Environmental effects of this product have not been investigated, however this product contains ingredients that may cause adverse effects to aquatic life. US DOT SYMBOLS CANADA (WHMIS) SYMBOLS GHS HAZARD SYMBOL(S) Signal Word: Danger! COMPONENTS DETERMINING HAZARDS: Sulfuric Acid GHS HAZARD CLASSIFICATION(S): Acute Oral Toxicity Category 4 Eye Irritant Category 2 STOT SE Category 3 Skin Corrosive Category 1A HAZARD STATEMENTS: Harmful if swallowed Causes serious skin burns and eye damage May cause respiratory irritation PRECAUTIONARY STATEMENTS: Wear protective gloves/protective clothing/eye protection Do not breath mist/spray Use only in a well ventilated area Wash hands thoroughly after handling HEALTH HAZARDS OR RISKS FROM EXPOSURE: ACUTE: INHALATION: Inhalation of vapors/mist/spray may cause respiratory irritation. EYE CONTACT: Direct eye contact can cause irritation with redness, tearing and blurred vision. Possible serious eye damage. SKIN CONTACT: May cause skin irritation with possible skin burns. INGESTION: Ingestion of this product can cause chemical burns of mouth and throat. Causes severe pain, nausea, vomiting and diarrhea. June 2017 Page 1 of 5 SAFETY DATA SHEET DPD4 Indicator Solution CHRONIC: Prolonged or repeated contact with product and poor hygiene conditions may result in skin dryness or dermatitis. TARGET ORGANS: ACUTE: Eye, Skin, Respiratory System CHRONIC: Skin SECTION 3 - COMPOSITION and INFORMATION ON INGREDIENTS HAZARDS DISCLOSURE: This product does contain known hazardous materials in reportable levels as defined by the OSHA Hazard Communication Standard 29 CFR 1910.1200. As defined under Sara 311 and 312, this product contains known hazardous materials. HAZARDOUS INGREDIENTS: CAS # Deionized Water 7732-18-5 WT % 90 – 99% HAZARD CLASSIFICATION; RISK PHRASES HAZARD CLASSIFICATION: None RISK PHRASES: None Sulfuric Acid 7664-93-9 <5.5% HAZARD CLASSIFICATION: [Xi] Irritant RISK PHRASES: R36/38 (C ≥ 15%, R35) Each of the other components present are less than 1 percent concentration (0.1% concentration for potential carcinogens, reproductive toxins, respiratory tract sensitizers, and mutagens) NOTE: ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-2010 format. SECTION 4 - FIRST-AID MEASURES Contaminated individuals of chemical exposure must be taken for medical attention if any adverse effect occurs. Rescuers should be taken for medical attention, if necessary. Take copy of label and SDS to health professional with contaminated individual. EYE CONTACT: If product enters the eyes, open eyes while under gentle running water for at least 15 minutes. Seek medical attention. SKIN CONTACT: Wash skin thoroughly after handling. Seek medical attention if irritation develops and persists. INHALATION: If breathing becomes difficult, remove victim to fresh air. If necessary, use artificial respiration to support vital functions. Seek medical attention immediately. INGESTION: If product is swallowed, call physician or poison control center for most current information. If professional advice is not available, do not induce vomiting. Never induce vomiting or give diluents (milk or water) to someone who is unconscious, having convulsions, or who cannot swallow. Seek medical advice. Take a copy of the label and/or SDS with the victim to the health professional. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Individuals with pre-existing skin disorders should avoid contact with this product. RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and reduce over-exposure. SECTION 5 - FIRE-FIGHTING MEASURES FLASH POINT: >200°F AUTOIGNITION TEMPERATURE: FLAMMABLE LIMITS (in air by volume, %): FIRE EXTINGUISHING MATERIALS: UNUSUAL FIRE AND EXPLOSION HAZARDS: Not Established Lower (LEL): Not Established Explosion Sensitivity to Mechanical Impact: Explosion Sensitivity to Static Discharge: SPECIAL FIRE-FIGHTING PROCEDURES: NFPA Rating System Not Sensitive. Not Sensitive 1 2 1 - Upper (UEL): Not Established Dry chemical, carbon dioxide, foam or water spray. None known Incipient fire responders should wear eye protection. Structural firefighters must wear Self-Contained Breathing Apparatus and full protective equipment. Isolate materials not yet involved in the fire and protect personnel. Move containers from fire area if this can be done without risk; otherwise, cool with carefully applied water spray. If possible, prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive areas. SECTION 6 - ACCIDENTAL RELEASE MEASURES SPILL AND LEAK RESPONSE: Personnel should be trained for spill response operations. Contain and recover if possible. Cover spilled product with sand, earth or other non-combustible absorbent material. Pickup spilled material June 2017 Page 2 of 5 SAFETY DATA SHEET DPD4 Indicator Solution immediately and place in appropriate containers. Dispose of in accordance with applicable Federal, State, and local procedures (see Section 13, Disposal Considerations). Do not discharge to sewers and surface waters. Notify authorities if entry occurs. U.S. Regulations (CERCLA) requires reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802. SECTION 7 - HANDLING and STORAGE WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product on you. Wash thoroughly after handling this product. Use in a well-ventilated location. STORAGE AND HANDLING PRACTICES: Store containers in a cool, dry location. Keep away from sources of ignition. Keep container tightly closed when not in use. Protect from physical damage. SECTION 8 - EXPOSURE CONTROLS - PERSONAL PROTECTION EXPOSURE LIMITS/GUIDELINES: Chemical Name CAS# ACGIH TWA OSHA TWA Deionized Water 7732-18-5 Not Listed Not Listed Sulfuric Acid 7664-93-9 0.2 mg/m³ 1 mg/m³ Currently, International exposure limits are not established for all the components of this product. Please check with competent authority in each country for the most recent limits in place. VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained below the limits provided above. Use local exhaust ventilation to control airborne vapors. The following information on appropriate Personal Protective Equipment is provided to assist employers in complying with OSHA regulations found in 29 CFR Subpart I (beginning at 1910.132) or equivalent standard of Canada. Please reference applicable regulations and standards for relevant details. RESPIRATORY PROTECTION: Not normally required when using this product. Maintain airborne contaminant concentrations below guidelines listed above, if applicable. If necessary, use only respiratory protection authorized in the U.S. Federal OSHA Respiratory Protection Standard (29 CFR 1910.134), equivalent U.S. State standards, Canadian CSA Standard Z94.4-93. EYE PROTECTION: Wear safety glasses or chemical goggles as appropriate where splashing is possible. If necessary, refer to U.S. OSHA 29 CFR 1910.133 or appropriate Canadian Standards. HAND PROTECTION: Wear chemical resistant gloves as appropriate to prevent skin contact. If necessary, refer to U.S. OSHA 29 CFR 1910.138 or appropriate Standards of Canada. BODY PROTECTION: Use body protection appropriate to prevent skin contact (e.g. lab coat, overalls). If necessary, refer to appropriate Standards of U.S., Canada, or appropriate Standards of the EU, Australian Standards, or relevant Japanese Standards. SECTION 9 - PHYSICAL and CHEMICAL PROPERTIES PHYSICAL STATE: APPEARANCE & ODOR: ODOR THRESHOLD (PPM): VAPOR PRESSURE (mmHg): VAPOR DENSITY (AIR=1): EVAPORATION RATE (nBuAc = 1): BOILING POINT (C°): FREEZING POINT (C°): pH: SPECIFIC GRAVITY 20°C: (WATER =1) SOLUBILITY IN WATER (%) VOC: June2017 Liquid Colorless liquid with no odor. None Not Available Not Available Not Available Not Available Not Available <2 >1 Completely miscible None Page 3 of 5 SAFETY DATA SHEET DPD4 Indicator Solution SECTION 10 - STABILITY and REACTIVITY STABILITY: Product is stable DECOMPOSITION PRODUCTS: When heated to decomposition this product produces oxides of carbon and sulfur MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Strong oxidizers and bases HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: Contact with incompatible materials SECTION 11 - TOXICOLOGICAL INFORMATION TOXICITY DATA: Toxicity data is available for the following components: CAS# 7664-93-9 Oral LD50 Rat: 2140 mg/kg SUSPECTED CANCER AGENT: One of the ingredients are found on the following lists: FEDERAL OSHA Z LIST, NTP, CAL/OSHA, IARC and therefore are considered to be, or suspected to be a cancer-causing agent by these agencies. CAS# 7664-93-9: ACGIH: A2 - Suspected Human Carcinogen (contained in strong inorganic acid mists) OSHA: Select carcinogen IARC: Group 1 carcinogen IRRITANCY OF PRODUCT: Contact with this product can be irritating to skin, respiratory system and eyes. SENSITIZATION OF PRODUCT: Ingredients in this product are not considered a sensitizer. REPRODUCTIVE TOXICITY INFORMATION: No information available SECTION 12 - ECOLOGICAL INFORMATION ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION. ENVIRONMENTAL STABILITY: No specific data is available for this product, however this product is expected to be readily biodegradable EFFECT OF MATERIAL ON PLANTS or ANIMALS: No data available EFFECT OF CHEMICAL ON AQUATIC LIFE: No data available SECTION 13 - DISPOSAL CONSIDERATIONS PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate Federal, State, and local regulations. SECTION 14 - TRANSPORTATION INFORMATION US DOT; IATA; IMO; ADR: THIS PRODUCT IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF TRANSPORTATION. PROPER SHIPPING NAME: Sulphuric Acid (with not more than 51% acid) HAZARD CLASS NUMBER and DESCRIPTION: Class 8 Corrosive UN IDENTIFICATION NUMBER: UN2796 PACKING GROUP: PGII DOT LABEL(S) REQUIRED: Corrosive NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (2012): 157 MARINE POLLUTANT: None of the ingredients are classified by the DOT as a Marine Pollutant (as defined by 49 CFR 172.101, Appendix B) U.S. DEPARTMENT OF TRANSPORTATION (DOT) SHIPPING REGULATIONS: This product is classified as Hazardous Materials, per U.S. DOT regulations, under 49 CFR 172.101. TRANSPORT CANADA, TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This product is classified as Dangerous Goods, per regulations of Transport Canada. INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA): This product is classified as Dangerous Goods, by rules of IATA: November 2013 Page 4 of 5 SAFETY DATA SHEET DPD4 Indicator Solution INTERNATIONAL MARITIME ORGANIZATION (IMO) DESIGNATION: This product is classified as Dangerous Goods by the International Maritime Organization SECTION 15 - REGULATORY INFORMATION UNITED STATES REGULATIONS SARA REPORTING REQUIREMENTS: This product is subject to the reporting requirements of Sections 302, 304 and 313 of Title III of the Superfund Amendments and Reauthorization Act., as follows: SARA 302 RQ: CAS# 7664-93-9: final RQ = 1000 pounds (454 kg) SARA 302 TPQ: CAS# 7664-93-9: TPQ = 1000 pounds; RQ = 1000 pounds SARA 313 Reporting: This material contains Sulfuric acid (CAS# 7664-93-9, <5.5%), which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373. TSCA: All components in this product are listed on the US Toxic Substances Control Act (TSCA) inventory of chemicals. SARA 311/312: Acute Health: Yes Chronic Health: No Fire: No Reactivity: No U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for this product. The default Federal SDS submission and inventory requirement filing threshold of 10,000 lb (4,540 kg) may apply, per 40 CFR 370.20. U.S. CERCLA REPORTABLE QUANTITY (RQ): CAS# 7664-93-9: final RQ = 1000 pounds (454 kg) CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): One or more of the ingredients are on the California Proposition 65 lists. WARNING! This product contains ingredients that are known to the State of California to cause cancer or reproductive harm. CANADIAN REGULATIONS: CANADIAN DSL/NDSL INVENTORY STATUS: All of the components of this product are on the DSL Inventory CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: No component of this product is on the CEPA First Priorities Substance Lists. CANADIAN WHMIS CLASSIFICATION and SYMBOLS: This is considered to be a hazardous material under the Hazardous Products Act as defined by the Controlled Products Regulations and is therefore subject to the labeling and SDS requirements of the Workplace Hazardous Materials Information System (WHMIS).Class D2B Materials having other toxic effects and Class E Corrosive materials. INTERNATIONAL CHEMICAL INVENTORIES: Listing of the components on individual country Chemical Inventories is as follows: Asia-Pac: Listed or Exempt Australian Inventory of Chemical Substances (AICS): Listed or Exempt Korean Existing Chemicals List (ECL): Listed or Exempt Japanese Existing National Inventory of Chemical Substances (ENCS): Listed or Exempt Philippines Inventory if Chemicals and Chemical Substances (PICCS): Listed or Exempt Swiss Giftliste List of Toxic Substances: Listed or Exempt U.S. TSCA: Listed SECTION 16 - OTHER INFORMATION GHS MSDS Compliance PLUS Disclaimer: This information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Blue I Water Technologies. The data on this sheet is related only to the specific material designated herein. Blue I Water Technologies assumes no legal responsibility for use or reliance upon this data. To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. June 2017 Page 5 of 5
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