FS 50 Du Pont(TM) Capstone(R) Fluorosurfactants Brochure K 24287

User Manual: FS 50

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DuPont Capstone
Fluorosurfactants
™

®

High value-in-use applications that
require maximum performance

Solutions to Fuel Your Innovation
DuPont Capstone surfactants are the result of our
commitment to world-class science that delivers
more sustainable solutions through superior product
performance—products that help protect people as well
as the environment. Providing a range of benefits not
available with traditional surfactants, DuPont Capstone
fluoroadditives give you the ability to enhance the
performance properties of your existing products, as well
as the freedom to create unique and innovative products
that help meet your customer needs worldwide.
™

®

™

low as 18 dynes/cm at extremely low concentrations
(see Figure 2).
High surface tension liquid
Does
not wet

Wets surface

®

Low surface energy substrate

As a major global manufacturer and supplier of innovative
short-chain products, DuPont has a robust supply of
DuPont Capstone fluorosurfactants, so you can be
confident your production lines will run smoothly—no
matter where in the world you operate.
™

Low surface tension liquid

Low surface energy substrate

Substrate

Typical Surface Energies,
dyn/cm

Polyurethane

43

Alkyd

38

Polyethylene

31

Paraffin

26

®

Silicone

24

Teflon PTFE

19

®

Figure 1. Schematic for Wetting

The DuPont Capstone fluorosurfactants team stands
ready to work with you to help your business grow—from
choosing the DuPont Capstone fluoroadditive that is
right for your application and business needs to answering
technical questions.
™

®

™

®

DuPont Capstone fluorosurfactants enable
simplified formulations and higher performance
end-products.
™

®

For applications such as paints and coatings, adhesives,
waxes and polishes, and industrial cleaning products,
DuPont Capstone fluorosurfactants enhance the
properties of formulations by improving properties such
as wetting and spreading, leveling, penetrating, foaming
control, and substantially reducing surface tension.
™

®

To effectively wet a substrate, the surface energy of the
formulation must be lower than the surface energy of the
substrate (see Figure 1). Capstone fluorosurfactants offer
unparalleled wetting and leveling power in both waterand solvent-borne formulations with surface energies as
®

2

Static surface tension curves for select Capstone
fluorosurfactants with enhanced wetting capabilities.
®

80
Surface Tension, dynes/cm

DuPont cares about what happens after our products
are designed into end-use applications. Our rigorous
product stewardship process evaluates product hazards
and potential for exposure to ensure the products are
safe for their intended use. A more detailed summary
is available in our “Product Stewardship Detail”
brochure, number K-20614, which can be found at
www.capstone.dupont.com under Technical Information.

70

FS-65

60

FS-30

50
40
30

FS-31

20
10
0

0.001

0.01

0.1

0.5

Concentration, % active ingredient
Note: Individual results may vary.

Figure 2. Static Surface Tension in Deionized Water

Capstone fluorosurfactants work well in harsh chemical
and thermal conditions and can also help reduce the
amount and number of other additives in formulations,
helping to reduce complexity while creating higherperforming products. For more detailed information,
please refer to the DuPont Capstone Fluoroadditive
Application Guide on page 7.
®

™

®

Cost Synergies in Formulating with Capstone

®

Capstone fluorosurfactants are used in combination with
conventional surfactants to lower the total cost of the
formulation-–by reducing the total amount of surfactant
used, while providing better performance.
®

As demonstrated in Figure 3, a mixture of a Capstone
fluorosurfactant with a hydrocarbon surfactant can provide
greater wetting power at an equivalent cost. Mixed
surfactant systems are applied in cleaning and coating
formulations, with additional benefits of reducing foam
and improving dynamic surface tension reduction.
®

35

Capstone fluorosurfactants perform at very low
concentrations, allowing for the development of
concentrates that can be diluted as much as 100:1. This
is a key advantage when designing cleaning systems for
industrial and institutional cleaning applications where
large volumes of formulations are often required.
®

Sodium Lauryl Sulfate

33

Floor Polishes/Waxes and Strippers

31
Surface Tension, dynes/cm

Concentrates

When a cleaner or polish/wax is spread on a substrate,
two new interfaces are created: (1) the interface between
the liquid layer and the substrate (flooring, in this case),
and (2) the upper (and visible) surface of the coating. In
polishes and waxes, Capstone fluorosurfactants provide
wetting power to give a uniform film on the substrate.
Furthermore, they improve gloss and rewet characteristics
on the upper surface, permitting multi-coat application
without haze. Capstone fluorosurfactants are widely
used in this application and are recommended by nearly
every resin manufacturer. At the low concentrations used
(typically 200 ppm or less), they do not interfere with the
hydrocarbon surfactants that are added to emulsify resins
and waxes in the formulation, and minimal foaming is
observed. FS-60, FS-61, FS-64, FS-65, FS-34, and
FS-35 are the most common grades for this use. A visual
demonstration of improved performance can be seen
in Figure 4.

Triton X-100
™

29
27
25

®

Neodol 91-6

23
21
19

®

17
15
Hydrocarbon
Surfactant

HC+ FS-31

FS-31

$0.04/lb of Formulated Product
Note: Individual results may vary.

Figure 3. Cost vs. Performance Comparison

Cleaners for Glass or Other Hard Surfaces
The key to good performance on glass and hard surface
applications is wetting power at low concentrations.
Because low surface tension is realized with a small
amount of fluorosurfactants (e.g., 200 ppm) there is less
residue on evaporation and the residual film is thinner.
This results in faster drying times as well as less haze
and streaking.
FS-30 and FS-31, nonionic surfactants, will leave an
invisible absorbed monolayer that encourages rewet
of the surface. This will decrease the tendency of the
surface to ‘fog’ in high humidity environments, a major
benefit in glass cleaners. FS-61 and FS-65, anionic and
nonionic surfactants respectively, provide good wetting
properties to improve scale removal. FS-61 and FS-64
bind to metal, polymeric, or ceramic surfaces, to repel
water or oily soils. These products are more strongly
adsorbed onto those surfaces and provide protection
against re-soiling, while still being very effective at low
concentrations. When foam is used to promote adhesion
of the active cleaning ingredient on the surface, Capstone
fluorosurfactant grades such as the amphoteric FS-50 and
FS-51 fluorosurfactants are best at creating stable foam
for these applications.

In ‘strippers’ for floor polish removal systems,
the chemical stability (i.e., resistance to alkali) of
fluorosurfactants is an important performance attribute.
Good performance depends on the ability of the stripper
to completely wet and penetrate the layer(s) of old polish/
wax, so that they can be separated from the substrate to
provide a surface ready for refinish. These surfaces can be
difficult to wet; the addition of Capstone fluorosurfactants
can eliminate this concern. In stripper formulations,
Capstone fluorosurfactants work with the detergency of
hydrocarbon surfactants (which emulsify the old finish to
guard against redeposition) to give superior performance.
®

®

®

Floor finish without Capstone
fluorosurfactant shows clearly
visible orange peel and
significant surface defects.

®

Floor finish dosed with FS-60 at
75 ppm has drastically improved
leveling and surface appearance
of the floor finish on the vinyl tile.

Figure 4. Improved Performance of Floor Finish Formulations

3

Low-VOC or VOC-Free Latex Paints
Capstone fluorosurfactants are multifunctional additives
in paints and coatings, especially when formulated with
low- or no-VOC products. New research demonstrates
that adding Capstone fluorosurfactants into both the grind
and the letdown phases of production will help to simplify
the formulation, improve performance and reduce raw
material costs.
®

®

The addition of Capstone fluorosurfactants in the grind
phase of production replaces the need for a pigmentwetting agent. As a result, the reduction in non-fluorinated
surfactants can lead to a reduction of foam and defoamer
agents, which will improve oily stain resistance of the
paint film and reduce the amount of foam generated
during the letdown phase.
®

The addition of Capstone fluorosurfactants in the letdown
phase eliminates the need to add substrate wetting and
film leveling agents. It also eliminates the need to use
wax, silicone or other anti-blocking agents and reduces
the need for a defoamer. For a summary, see Table 1.
®

Table 1. General Guidelines for Adding Capstone Fluorosurfactants
During Paint Production
®

Grind Phase

Letdown Phase

Additive

Adjustment

Additive

Adjustment

Dispersant

No Adjustment
Reduce by 30%
to 100%

Resin/Emulsion
Binder

No Adjustment

Pigment Wetting
Agent

Wetting Agent

Capstone Fluorosurfactant
0.01-0.05%

ADD

Reduce by 50%
to 100%

Pigment TiO2

No Adjustment

Filler (CaCO3,
Clay, Talc)

No Adustment

Rheology
Modifier

May Require Minor
Adjustment

Improved cleanability of oily dirt, oil repellency, good
dirt pick-up resistance (DPR) and enhanced wetting
are achieved in architectural flat paints and waterborne
coatings with the use of FS-81 as an additive. Additionally,
FS-81 does not interfere with recoat adhesion or create
water repellency (see Figure 6). Using this fluoroadditive
results in an improvement in washability of oil-based
stains, such as dirty handprints, for low-sheen latex paints.
In order to obtain optimal results, it is recommended
that the coating be reformulated to minimize additives
that attract oil and excess surfactants. The combination
of anionic fluorosurfactants (e.g., FS-61) and FS-81
provides maximum performance for DPR. The use rates
recommended for FS-81 as an additive are dependent on
the particular coating system, end-use application and the
desired outcome. Table 2 provides guidance based on the
knowledge DuPont has gained from evaluations
of FS-81.

Capstone Fluorosurfactant
0.01-0.05%
®

ADD

1

Defoamer

Eliminate

®

1

Defoamer

Reduce2

Leveling Agent

Eliminate

Wax and Other
Anti-blocking
Agents

Eliminate

In-can and Film
Preservatives

No Adjustment

1. For selection and use rate of Capstone fluorosurfactants, refer to technical data
sheets or ask your DuPont technical representative.
®

2. If required, use minimal amount of water-dispersible polysiloxane.
Note: Individual results may vary.

Improvement in cleanability in flat latex paint
demonstrated through contact angle data.
45.0
Contact angle, degree

®

an effect due to the presence of surface imperfections or
contaminants. The benefits are summarized in Figure 5.
The nonionic and amphoteric Capstone fluorosurfactants
(e.g., FS-30, FS-31, FS-50 and FS-51) provide enhanced
wetting and leveling properties. Anti-block properties are
demonstrated at low-use rates of 200-300 ppm in latex
paints with FS-61, FS-63 and FS-64. A more detailed
summary is available in our “Simplify Formulations and
Improve Performance in Architectural/Decorative Paints
and Coatings” brochure, number K-23574, which can
be found at www.capstone.dupont.com under
Technical Information.

40.0

40.3

37.9

35.0

31.7

30.0
25.0
20.0
15.0
10.0
5.0

0.0

0.0

Without
DuPont Capstone
Fluorosurfactants
™

Benefits in paint formulations include wetting (improved
intercoat adhesion, and the ability to wet out low energy
surfaces), leveling (improved gloss, and reduced
“orange peel”, or decreased incidence of Benard cells),
anti-blocking (reduce tendency of glossy paints to stick
to themselves), and the ability to reduce cratering,

4

Water

®

FS-81
(0.1% active ingredient)
Hexadecane

Note: Individual results may vary.

Figure 6. Flat Latex Paint Advancing Contact Angle Data

FS-30 and FS-31

FS-61 and FS-63

Substrate Wetting

Substrate Wetting

Oily Stain
Removal

Oily Stain
Removal

Pigment
Wetting

Dirt
Pickup

Substrate Wetting

Anti-blocking

Pigment
Wetting

Dirt
Pickup

Leveling

Low Foam

Open-time

Oily Stain
Removal

Pigment
Wetting

Dirt
Pickup

Leveling

Low Foam

FS-81

Anti-blocking

Leveling

Low Foam

Open-time

Anti-blocking
Open-time

Figure 5. Demonstrating the Multi-Functional and Easy to Use Performance Benefits of Specific Capstone Fluorosurfactants
®

Table 2. FS-81 Use Rate for Various Applications
Application
Interior Stain
Washability

Dirt Pick-up
Resistance (DPR)

Wetting
Agent

Use Rate (Product Weight)

0.3–0.5%

0.3–1%

0.2%

Use Rate (Active Ingredient)

0.1–0.2%

0.1–0.3%

0.07%

Solvent, Radiation-Cured and 100% Solids Systems
Manufacturers using solvent-based coatings, container
manufacturers, ink formulation companies, and converters
(finish films for printing, metalizing or tape manufacturers)
all find a need for the use of multifunctional additives
for their coating systems. FS-3100, FS-22 and FS-83 can
provide improved properties to these systems.

provide reduced surface defects, dynamic surface
tension reduction (in combination with existing surfactant
package), and penetration of the adhesive.

Films
Surface energy of the film is increased by ionization, flame
treatment, or because the film contains some manner
of “roughener” to improve adhesion of subsequent
coatings. For print acceptors, Capstone fluorosurfactants
improve wetting and leveling of coatings for ink, improve
adhesion, abrasion resistance, reduce transfer, and
improve general “printability”. In a variety of coating
applications, Capstone fluorosurfactants can provide
antistatic properties. In addition to wetting, Capstone
fluorosurfactants migrate to the top of a coating and thus
encourage rewetting in multi-coat operations.
®

®

®

Ink and Graphics Arts
Excellent wetting and leveling properties for ink and
graphic arts types of coatings are achieved with the
addition of Capstone fluorosurfactants, without interfering
with the dispersed phase dyes and pigments. Further,
since Capstone fluorosurfactants rise to the air interface,
they reduce “transfer” to the next surface when sheet or
roll-type products are stacked. The primary performance
functions include anti-block, ink acceptance, leveling and
wetting. For aqueous-based systems, FS-34, FS-35 and
FS-65 provide enhanced wetting and leveling. FS-22 and
FS-83 are ideal for non-polar solvent-based applications.

Suitable Capstone fluorosurfactants for these
applications include: FS-10, FS-30, FS-31 and FS-50.
In release coatings, there are two general types of films:
CAST (polymer is dissolved in solvent, cast on a belt
or drum, and the solvent is driven off and recovered)
and EXTRUDED (melted resin is pushed through a
die). Since Capstone fluorosurfactants migrate to the
liquid-air interface in coatings, they can impart release
characteristics to that coating surface. Fluorosurfactants
such as FS-66 and FS-63 are ideal for release coating
applications.

Adhesives, Sealants, Caulks

Overall, a variety of Capstone fluorosurfactants can
provide the performance benefits in film applications of
anti-block, antistatic, improved surface properties, film
leveling (even thickness), reduction in cratering (due to the
presence of impurities), water repellency, wetting and film
release (off the belt/drum without deformation, tearing
or edge effects). For a summary specific features and
applications of Capstone fluorosurfactants, refer to the
Application Guide on page 7.

®

®

Adhesive applications exist in many forms, such as
adhesives for tape, for hot-melt, for wood (and other
porous surfaces). Adhesives are used in packaging,
construction, and many OEM applications. The addition of
a small amount of a Capstone fluorosurfactant improves
the wetting and penetration of the adhesive into the pore
structure of the substrates, thus strengthening the bond.
Capstone fluorosurfactants such as FS-30 and FS-31
®

®

®

®

®

®

5

Highlights of DuPont Capstone Fluorosurfactants
™

®

FS-10
FS-10 is an anionic fluorosurfactant that reduces the
surface tension of aqueous solutions to low levels and
demonstrates exceptional stability in corrosive, and in
particular, highly acidic media, while creating minimal to
no foam. This is effective in chrome plating and metal
treatment applications. FS-10 is useful as a wetting and
antistatic aid in films.

FS-30 and FS-65
FS-30 and FS-65 combine the performance of superior
wetting and leveling agents with the surface protection
qualities of a coating additive. FS-30 is VOC-free, APEOfree and non-flammable. It is stable in acidic, basic,
brine and hard water environments. FS-65 is VOC-free
and APEO-free, and has a strong non-ionic character
under all conditions. It is stable in acidic, basic and
brine environments. In addition to providing superior
performance, both FS-30 and FS-65 meet the OECD 301B
test methods criteria pertaining to biodegradability.

FS-31, FS-3100, FS-34 and FS-35
FS-31, FS-34 and FS-35 are non-ionic, VOC-free and
APEO-free fluorosurfactants that provide exceptionally
low surface tension in aqueous or solvent-based products,
enabling better wetting, spreading, leveling and other
beneficial properties. FS-34 and FS-35 have shown
enhanced leveling and wetting properties in floor care
and ink applications. FS-31, FS-3100, FS-34 and FS-35 are
stable in acidic, basic, brine and hard water environments,
making it easy to formulate into a variety of systems.

FS-50 and FS-51
FS-50 and FS-51 are amphoteric fluorosurfactants that
significantly reduce the surface tensions of aqueous
fluids and are effective in providing sustainable foams.
Both products are effective additives in industrial and
institutional cleaning, floor care, and latex and water-based
alkyd paints.

6

FS-60, FS-61 and FS-63
FS-61 is a VOC-free and APEO-free anionic
fluorosurfactant dispersion that provides excellent
anti-blocking, oil repellency and dirt pick-up resistance
properties. FS-60 and FS-63 are similar to FS-61, but
contain isopropyl alcohol. Both of these waterborne
surface-modifying products provide outstanding
multi-functional performance for both interior and
exterior paint and coating applications, as well as
Industrial and Institutional applications.

FS-64
FS-64, a VOC-free anionic fluorosurfactant, combines
the unique properties of fluorine with the strength of a
DuPont Renewably Sourced material, which contains
a minimum of 20% renewably sourced ingredients
by weight. FS-64 is an environmentally preferred
fluorosurfactant that provides all the general performance
attributes you would expect from a fluorosurfactant,
including: superior surface tension reduction, anti-block,
oil repellency, dirt pick-up resistance, excellent leveling
characteristics and stability in highly acidic and alkaline
media.
™

™

FS-81
FS-81 is a self-dispersed, waterborne, partially fluorinated
polymeric coating additive designed to improve
cleanability of oily dirt and common household stains on
flat architectural waterborne coatings and latex paints. As
shown in Figure 6, FS-81 improves oil contact angles on
interior, flat finish, latex coatings.

FS-22 and FS-83
FS-22 and FS-83 are solvent-borne, partially fluorinated
copolymers that provide surface tension reduction and
superior easy-clean performance in solvent-based coating
systems, which enables better wetting, spreading and
leveling.

DuPont Capstone Fluoroadditive Application Guide
™

Features

®

FS-10

FS-22

FS-30

FS-31

FS-34

FS-35

FS-50

FS-51

FS-60

FS-61

FS-63

FS-64

FS-65

•

•

•

•

•

•

•

•

•

•

•

FS-66

FS-81

FS-83

FS-3100

Waxes/Polishes
Wetting

•

•

Leveling

•

•

•

•

•

•

•

•

•

•

Gloss

•

•

•

•

•

•

•

•

•

•

Strippers

•

•

•

•

•

•

•

Wetting

•

•

•

•

•

•

•

•

•

•

•

•

Leveling

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

Cleaners

Antifog
Antistatic

•

Oxidizing

•

•

Acidic

•

•

•

•

Basic

•

•

•

•

•

•

Metal Plating/Etch

•

•

•

•
•

•

•

•

•

•

•

•

•

•

Paints & Coatings
Anti-block
Open-time
Wetting

•

Leveling

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

•

Cleanability
Water-based

•
•

•

•

•

•

•

•

•

•

•

•

•

•

•

Solvent-based

•

Mold Release
Inks

•

Films

•

Adhesives

•

•

•
•

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•

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•

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Foamers
Aqueous

•

•

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•
•

•

Biodegradability
VOC-free

•

•

Solvent

•

•

•
•

•

•

•

•

•

•

•

Please visit www.capstone.dupont.com
for immediate access to:
• Product literature
• Material safety data sheets (MSDS)
• Technical data sheets
• Sample requests
• Customer support

7

Please contact us for pricing, orders or customer service.

DuPont Fluoropolymer Solutions
Regional Sales
Asia Pacific: +886.2.2514.4412
Europe: +33.1.41.97.45.59
Latin America: +52.55.5722.1150
North America: 1-877-786-6383 Sales
1-866-828-7009 Technical Help Line
Customer Service Center Americas
Wilmington, DE 19805
1-866-828-7009
Customer Service Center Europe/Middle East/Africa
DuPont de Nemours (France) SAS
1 Allée de Chantereine
78711 Mantes la Ville–France
+33.1.30.92.82.12
Customer Service Center Asia Pacific
DuPont (Taiwan) Office, Taipei
+886.2.2514.4412

www.capstone.dupont.com

The information set forth herein is furnished free of charge and is based on technical data that DuPont believes to be reliable. It is intended
for use by persons having technical skill, at their own discretion and risk. Because conditions of product use are outside our control, DuPont
makes no warranties, express or implied, and assumes no liability in connection with any use of this information. As with any material,
evaluation of any compound under end-use conditions prior to specification is essential.
Copyright © 2012 DuPont. All rights reserved. The DuPont Oval Logo, DuPont , The miracles of science , and Capstone are trademarks
or registered trademarks of E.I. du Pont de Nemours and Company or its affiliates. K-24287 (05/12)
™

Neodol is a trademark of the Shell Group of Companies.
Triton is a trademark of The Dow Chemical Company (“Dow”) or an affiliated company of Dow.
™

™

™

®



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History When                    : 2011:03:07 11:43:40-05:00, 2011:03:07 11:43:40-05:00, 2011:03:07 12:27:52-05:00, 2011:03:07 12:28:36-05:00, 2011:03:07 12:28:36-05:00, 2011:03:07 12:30:14-05:00, 2011:03:07 13:21:06-05:00, 2011:03:07 13:43:59-05:00, 2011:03:07 14:10:36-05:00, 2011:03:07 14:18:57-05:00, 2011:03:07 15:03:18-05:00, 2011:03:07 15:21:17-05:00, 2011:03:07 15:22:13-05:00, 2011:03:07 15:24:02-05:00, 2011:03:07 15:27:21-05:00, 2011:03:07 15:33:34-05:00, 2011:03:07 15:41:59-05:00, 2011:03:07 16:02:18-05:00, 2011:03:07 16:02:35-05:00, 2011:03:07 16:05:25-05:00, 2011:03:07 16:18:33-05:00, 2011:03:07 16:26:29-05:00, 2011:03:07 16:30:22-05:00, 2011:03:07 16:31:12-05:00, 2011:03:07 16:35:52-05:00, 2011:03:07 16:37:42-05:00, 2011:03:07 16:43:16-05:00, 2011:03:07 17:38:46-05:00, 2011:03:07 17:41:07-05:00, 2011:03:07 17:41:57-05:00, 2011:03:07 17:44:54-05:00, 2011:03:07 17:45:54-05:00, 2011:03:07 17:46:50-05:00, 2011:03:07 17:51:48-05:00, 2011:03:07 17:52:53-05:00, 2011:03:07 17:57:23-05:00, 2011:03:08 07:50:31-05:00, 2011:03:08 07:50:31-05:00, 2011:03:08 07:59:02-05:00, 2011:03:08 08:02:58-05:00, 2011:03:08 08:44:32-05:00, 2011:03:08 08:48:31-05:00, 2011:03:08 08:53:26-05:00, 2011:03:08 08:55:12-05:00, 2011:03:08 09:01:46-05:00, 2011:03:08 09:05:09-05:00, 2011:03:08 09:14:13-05:00, 2011:03:08 09:14:57-05:00, 2011:03:08 09:15:33-05:00, 2011:03:08 09:30:50-05:00, 2011:03:08 09:32:21-05:00, 2011:03:08 09:34:37-05:00, 2011:03:08 09:37:27-05:00, 2011:03:08 09:39:03-05:00, 2011:03:08 09:43:59-05:00, 2011:03:08 09:46:40-05:00, 2011:03:08 09:56:11-05:00, 2011:03:08 09:58:27-05:00, 2011:03:08 10:14:42-05:00, 2011:03:08 10:24:13-05:00, 2011:03:08 10:24:55-05:00, 2011:03:08 10:36:13-05:00, 2011:03:08 10:37:10-05:00, 2011:03:08 10:37:46-05:00, 2011:03:08 10:43:15-05:00, 2011:03:08 10:54:06-05:00, 2011:03:08 10:54:15-05:00, 2011:03:08 10:55:18-05:00, 2011:03:08 10:55:46-05:00, 2011:03:08 10:59:25-05:00, 2011:03:08 11:00:27-05:00, 2011:03:08 11:01:05-05:00, 2011:03:08 11:02:56-05:00, 2011:03:08 11:07:04-05:00, 2011:03:08 11:11:01-05:00, 2011:03:08 11:25:57-05:00, 2011:03:08 11:28:36-05:00, 2011:03:08 11:29:32-05:00, 2011:03:08 11:29:48-05:00, 2011:03:08 11:33:30-05:00, 2011:03:08 11:35:56-05:00, 2011:03:08 11:37:06-05:00, 2011:03:08 11:41:27-05:00, 2011:03:08 11:41:46-05:00, 2011:03:08 11:46:58-05:00, 2011:03:08 11:54:50-05:00, 2011:03:08 12:02:10-05:00, 2011:03:08 12:03:30-05:00, 2011:03:08 12:05:57-05:00, 2011:03:08 12:06:35-05:00, 2011:03:08 12:17:15-05:00, 2011:03:08 12:21:08-05:00, 2011:03:08 12:21:30-05:00, 2011:03:08 12:22:02-05:00, 2011:03:08 12:22:25-05:00, 2011:03:08 12:22:44-05:00, 2011:03:08 12:24:15-05:00, 2011:03:08 12:35:45-05:00, 2011:03:08 12:39:07-05:00, 2011:03:08 12:42:37-05:00, 2011:03:08 12:43:56-05:00, 2011:03:08 12:57:28-05:00, 2011:03:08 13:00:19-05:00, 2011:03:08 13:08:20-05:00, 2011:03:08 13:10:21-05:00, 2011:03:08 13:11:41-05:00, 2011:03:08 13:12:38-05:00, 2011:03:08 13:20:57-05:00, 2011:03:08 13:26:16-05:00, 2011:03:08 13:33:32-05:00, 2011:03:08 14:33:52-05:00, 2011:03:08 14:41:11-05:00, 2011:03:08 14:44:29-05:00, 2011:03:08 14:47:26-05:00, 2011:03:08 14:47:37-05:00, 2011:03:08 14:47:49-05:00, 2011:03:08 14:48:22-05:00, 2011:03:08 14:50:11-05:00, 2011:03:08 14:53:15-05:00, 2011:03:08 15:02:14-05:00, 2011:03:08 15:03:09-05:00, 2011:03:08 15:03:34-05:00, 2011:03:08 15:07:26-05:00, 2011:03:08 15:11:08-05:00, 2011:03:08 16:08:06-05:00, 2011:03:08 16:08:23-05:00, 2011:03:08 16:10:20-05:00, 2011:03:08 16:10:54-05:00, 2011:03:08 16:24:56-05:00, 2011:03:08 16:26:20-05:00, 2011:03:08 16:32:25-05:00, 2011:03:08 16:56:50-05:00, 2011:03:08 17:13:30-05:00, 2011:03:08 17:16:03-05:00, 2011:03:09 09:12:43-05:00, 2011:03:09 10:39:22-05:00, 2011:03:15 10:12:39-04:00, 2011:03:15 10:13-04:00, 2011:03:15 10:16:25-04:00, 2011:03:15 10:17:21-04:00, 2011:03:15 10:20:17-04:00, 2011:03:15 10:20:54-04:00, 2011:03:15 10:23:37-04:00, 2011:03:15 10:28:04-04:00, 2011:03:15 10:29:10-04:00, 2011:03:15 10:30:42-04:00, 2011:03:15 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Format                          : application/pdf
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