2003757 SDS 3000 PAPCO Gasoline All Grades Ethanol

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Safety Data Sheet

SDS No. 3000

Material Name: Gasoline All Grades w/ Ethanol
Synonyms:
Reformulated Gasoline with Ethanol, RFG, (all grades); Conventional Gasoline with Ethanol, Oxygenated, (all grades);
Automotive Gasoline

Section 1 - Product and Company Identification
Supplier Information

Material Name
Gasoline All Grades w/ Ethanol

PAPCO, Inc.
4920 Southern Blvd.

Synonyms

Virginia Beach, VA 23462
Corporate Phone: 757-499-5977
Emergency Health & Safety:
800-424-9300 CHEMTREC

Reformulated Gasoline with Ethanol, RFG, (all grades);
Conventional Gasoline with Ethanol, Oxygenated, (all
grades); Automotive Gasoline
Intended Use
Fuel

Section 2 - Hazards Identification
GHS Classification
Flammable Liquid - Category 2
Skin Corrosion/Irritation - Category 2
Germ Cell Mutagenicity - Category 1B
Carcinogenicity - Category 1B
Toxic to Reproduction - Category 1A
Specific Target Organ Toxicity (Single Exposure) - Category 3 (respiratory irritation, narcosis)
Specific Target Organ Toxicity (Repeat Exposure) - Category 1 (liver, kidneys, bladder, blood, bone marrow,
nervous system)
Aspiration Hazard - Category 1
Hazardous to the Aquatic Environment – Acute Hazard - Category 3
GHS LABEL ELEMENTS:
Symbol(s)

Signal Word
DANGER
Hazard Statements
Highly flammable liquid and vapor.
Causes skin irritation.
May cause genetic defects.
May cause cancer.
May damage fertility or the unborn child.
May cause respiratory irritation.
May cause drowsiness or dizziness.
Causes damage to organs (liver, kidneys, bladder, blood, bone marrow, nervous system) through prolonged or
repeated exposure.
May be fatal if swallowed and enters airways.
Harmful to aquatic life.

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Safety Data Sheet

SDS No. 3000

Material Name: Gasoline All Grades w/ Ethanol

Section 2 - Hazards Identification - continued
Precautionary Statements:
Prevention
Keep away from heat/sparks/open flames/hot surfaces. No smoking
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Wear protective gloves/protective clothing/eye protection/face protection.
Wash hands and forearms thoroughly after handling.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not breathe mist/vapours/spray.
Use only outdoors or in well-ventilated area.
Do not eat, drink or smoke when using this product.
Avoid release to the environment.
Response
IN CASE OF FIRE: Use water spray, fog, dry chemical fire extinguishers or hand held fire extinguisher.
IF ON SKIN (OR HAIR): Wash with plenty of soap and water. Remove/Take off immediately all contaminated clothing and wash
before reuse. If skin irritation occurs, get medical advice/attention.
IF EXPOSED OR CONCERNED: Get medical advice/attention.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center or doctor/
physician if you feel unwell.
Get medical advice/attention if you feel unwell.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do not induce vomiting.
Storage
Store in a well-ventilated place.
Keep cool. Keep container tightly closed.
Store locked up.
Disposal
Dispose of contents/container in accordance with local/regional/national/international regulations.

Section 3 - Composition / Information on Ingredients
CAS #

Component

Percent

86290-81-5

Gasoline, motor fuel

100

108-88-3

Toluene

1-25

106-97-8

Butane

<10

1330-20-7

Xylenes (o-, m-, p- isomers)

1-15

95-63-6

Benzene, 1,2,4-trimethyl-

64-17-5

Ethyl alcohol

0-10

100-41-4

Ethylbenzene

71-43-2

Benzene

0.1-4.9

110-54-3

Hexane

0.5-4

A complex blend of petroleum-derived normal and branched-chain alkane, cycloalkane, alkene, and aromatic hydrocarbons. May
contain antioxidant and multifunctional additives. Non-oxygenated Conventional Gasoline and RBOB do not have oxygenates
(Ethanol). Oxygenated Conventional and Reformulated Gasoline will have oxygenates for octane enhancement or as legally
required.

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Safety Data Sheet

SDS No. 3000

Material Name: Gasoline All Grades w/ Ethanol

Section 4 - First Aid Measures
First Aid: Eyes
In case of contact with eyes, immediately flush with clean, low-pressure water for at least 15 min. Hold eyelids open to ensure
adequate flushing. Seek medical attention.
First Aid: Skin
Remove contaminated clothing. Wash contaminated areas thoroughly with soap and water or with waterless hand cleanser.
Obtain medical attention if irritation or redness develops.
First Aid: Ingestion
DO NOT INDUCE VOMITING. Do not give liquids. Obtain immediate medical attention. If spontaneous vomiting occurs, lean
victim forward to reduce the risk of aspiration. Monitor for breathing difficulties. Small amounts of material which enter the
mouth should be rinsed out until the taste is dissipated.
First Aid: Inhalation
Remove person to fresh air. If person is not breathing, provide artificial respiration. If necessary, provide additional oxygen once
breathing is restored if trained to do so. Seek medical attention immediately.

Section 5 - Fire Fighting Measures
General Fire Hazards
See Section 9 for Flammability Properties.
Vapors may be ignited rapidly when exposed to heat, spark, open flame or other source of ignition. Flowing product may be
ignited by self-generated static electricity. When mixed with air and exposed to an ignition source, flammable vapors can burn in
the open or explode in confined spaces. Being heavier than air, vapors may travel long distances to an ignition source and flash
back. Runoff to sewer may cause fire or explosion hazard.
Hazardous Combustion Products
Carbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke). Contact with nitric and sulfuric acids will form
nitrocresols that can decompose violently.
Extinguishing Media
SMALL FIRES: Any extinguisher suitable for Class B fires, dry chemical, CO2, water spray, fire fighting foam, or gaseous
extinguishing agent.
LARGE FIRES: Water spray, fog or fire fighting foam. Water may be ineffective for fighting the fire, but may be used to cool fireexposed containers.
Firefighting foam suitable for polar solvents is recommended for fuel with greater than 10% oxygenate concentration.
Unsuitable Extinguishing Media
None
Fire Fighting Equipment/Instructions
Small fires in the incipient (beginning) stage may typically be extinguished using handheld portable fire extinguishers and other
fire fighting equipment. Firefighting activities that may result in potential exposure to high heat, smoke or toxic by-products of
combustion should require NIOSH/MSHA- approved pressure-demand self-contained breathing apparatus with full facepiece
and full protective clothing. Isolate area around container involved in fire. Cool tanks, shells, and containers exposed to fire
and excessive heat with water. For massive fires the use of unmanned hose holders or monitor nozzles may be advantageous
to further minimize personnel exposure. Major fires may require withdrawal, allowing the tank to burn. Large storage tank fires
typically require specially trained personnel and equipment to extinguish the fire, often including the need for properly applied
fire fighting foam.

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Safety Data Sheet

SDS No. 3000

Material Name: Gasoline All Grades w/ Ethanol

Section 6 - Accidental Release Measures
Recovery and Neutralization
Carefully contain and stop the source of the spill, if safe to do so.
Materials and Methods for Clean-Up
Take up with sand or other oil absorbing materials. Carefully shovel, scoop or sweep up into a waste container for reclamation or
disposal. Caution, flammable vapors may accumulate in closed containers.
Emergency Measures
Evacuate nonessential personnel and remove or secure all ignition sources. Consider wind direction; stay upwind and uphill, if
possible. Evaluate the direction of product travel, diking, sewers, etc. to confirm spill areas. Spills may infiltrate subsurface soil
and groundwater; professional assistance may be necessary to determine the extent of subsurface impact.
Personal Precautions and Protective Equipment
Response and clean-up crews must be properly trained and must utilize proper protective equipment (see Section 8).
Environmental Precautions
Protect bodies of water by diking, absorbents, or absorbent boom, if possible. Do not flush down sewer or drainage systems,
unless system is designed and permitted to handle such material. The use of fire fighting foam may be useful in certain
situations to reduce vapors. The proper use of water spray may effectively disperse product vapors or the liquid itself, preventing
contact with ignition sources or areas/equipment that require protection.
Prevention of Secondary Hazards
None

Section 7 - Handling and Storage
Handling Procedures
USE ONLY AS A MOTOR FUEL.
DO NOT SIPHON BY MOUTH
Handle as a flammable liquid. Keep away from heat, sparks, and open flame! Electrical equipment should be approved for
classified area. Bond and ground containers during product transfer to reduce the possibility of static-initiated fire or explosion.
Special slow load procedures for “switch loading” must be followed to avoid the static ignition hazard that can exist when higher
flash point material (such as fuel oil) is loaded into tanks previously containing low flash point products (such as this product) see API Publication 2003, “Protection Against Ignitions Arising Out Of Static, Lightning and Stray Currents.”
Storage Procedures
Keep away from flame, sparks, excessive temperatures and open flame. Use approved vented containers. Keep containers closed
and clearly labeled. Empty product containers or vessels may contain explosive vapors. Do not pressurize, cut, heat, weld or
expose such containers to sources of ignition.
Store in a well-ventilated area. This storage area should comply with NFPA 30 “Flammable and Combustible Liquid Code”. Avoid
storage near incompatible materials. The cleaning of tanks previously containing this product should follow API Recommended
Practice (RP) 2013 “Cleaning Mobile Tanks In Flammable and Combustible Liquid Service” and API RP 2015 “Cleaning Petroleum
Storage Tanks”.
Incompatibilities
Keep away from strong oxidizers.

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Safety Data Sheet

SDS No. 3000

Material Name: Gasoline All Grades w/ Ethanol

Section 8 - Exposure Controls / Personal Protection
Component Exposure Limits
Gasoline, motor fuel
ACGIH: 300 ppm TWA
500 ppm STEL
Toluene

Butane

ACGIH: 20 ppm TWA
OSHA: 200 ppm TWA; 375 mg/m3 TWA
150 ppm STEL; 560 mg/m3 STEL
NIOSH: 100 ppm TWA; 375 mg/m3 TWA
150 ppm STEL; 560 mg/m3 STEL
ACGIH: 1000 ppm TWA (listed under
Aliphatic hydrocarbon gases: Alkane C1-4)
OSHA: 800 ppm TWA; 1900 mg/m3 TWA
NIOSH: 800 ppm TWA; 1900 mg/m3 TWA

Xylenes (o-, m-, p- isomers)
ACGIH: 100 ppm TWA
150 ppm STEL
OSHA: 100 ppm TWA; 435 mg/m3 TWA
150 ppm STEL; 655 mg/m3 STEL
Benzene, 1,2,4-trimethylNIOSH: 25 ppm TWA; 125 mg/m3 TWA

Ethylbenzene
ACGIH: 20 ppm TWA
OSHA: 100 ppm TWA; 435 mg/m3 TWA
125 ppm STEL; 545 mg/m3 STEL
NIOSH: 100 ppm TWA; 435 mg/m3 TWA
125 ppm STEL; 545 mg/m3 STEL
Benzene
ACGIH: 0.5 ppm TWA
2.5 ppm STEL
Skin - potential significant contribution to overall
exposure by the cutaneous route
OSHA: 5 ppm STEL (Cancer hazard, Flammable,
See 29 CFR 1910.1028, 15 min); 0.5 ppm
Action Level; 1 ppm TWA
NIOSH: 0.1 ppm TWA
1 ppm STEL
Hexane

ACGIH: 50 ppm TWA
Skin - potential significant contribution to overall
exposure by the cutaneous route
OSHA: 500 ppm TWA; 1800 mg/m3 TWA
NIOSH: 50 ppm TWA; 180 mg/m3 TWA

Ethyl alcohol
ACGIH: 1000 ppm STEL
OSHA: 1000 ppm TWA; 1900 mg/m3 TWA
NIOSH: 1000 ppm TWA; 1900 mg/m3 TWA

Note: State, local or other agencies or advisory groups may have established more stringent limits. Consult an industrial hygienist or
similar professional, or your local agencies, for further information.

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Safety Data Sheet

SDS No. 3000

Material Name: Gasoline All Grades w/ Ethanol

Section 8 - Exposure Controls / Personal Protection - continued
Engineering Measures
Use adequate ventilation to keep vapor concentrations of this product below occupational exposure and flammability limits,
particularly in confined spaces.
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Respiratory
A NIOSH/MSHA-approved air-purifying respirator with organic vapor cartridges or canister may be permissible under certain
circumstances where airborne concentrations are or may be expected to exceed exposure limits or for odor or irritation.
Protection provided by air-purifying respirators is limited.
Use a positive pressure, air-supplied respirator if there is a potential for uncontrolled release, exposure levels are not known, in
oxygen-deficient atmospheres, or any other circumstance where an air-purifying respirator may not provide adequate protection.
Personal Protective Equipment: Hands
Gloves constructed of nitrile, neoprene, or PVC are recommended.
Personal Protective Equipment: Eyes
Safety glasses or goggles are recommended where there is a possibility of splashing or spraying.
Personal Protective Equipment: Skin and Body
Chemical protective clothing such as of E.I. DuPont TyChem®, Saranex® or equivalent recommended based on degree of
exposure.
Note: The resistance of specific material may vary from product to product as well as with degree of exposure. Consult
manufacturer specifications for further information.

Section 9 - Physical and Chemical Properties
Appearance:

Translucent, straw-colored
or light yellow

Specific Gravity:

0.70-0.78

Odor:

Strong, characteristic aromatic
hydrocarbon odor. Sweet-ether
like

Evaporation Rate:

10-11

VOC:

Percent Volatile:

100%

Octanol/H2O Coeff.:

Physical State:

Liquid

pH:

Flash Point:

-45 °F (-43 °C)

Vapor Pressure:

6.4 - 15 RVP @ 100 °F (38 °C)
(275-475 mm Hg @ 68 °F
(20 °C)

Flash Point Method:

PMCC

Upper Flammability
Limit (UFL):

7.6%

Vapor Density:

AP 3-4

Boiling Point:

85-437 °F (39-200 °C)

Lower Flammability
Limit (LFL):

1.4%

Melting Point:

Burning Rate:

Solubility (H2O):

Negligible to Slight

Auto Ignition:

>530°F (>280°C)

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Safety Data Sheet

SDS No. 3000

Material Name: Gasoline All Grades w/ Ethanol

Section 10 - Chemical Stability and Reactivity Information
Chemical Stability
This is a stable material.
Hazardous Reaction Potential
Will not occur.
Conditions to Avoid
Avoid high temperatures, open flames, sparks, welding, smoking and other ignition sources.
Incompatible Products
Keep away from strong oxidizers.
Hazardous Decomposition Products
Carbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke). Contact with nitric and sulfuric acids will form
nitrocresols that can decompose violently.

Section 11 - Toxicological Information
ACUTE TOXICITY
A: General Product Information
Harmful if swallowed.
B: Component Analysis - LD50/LC50
Gasoline, motor fuel
Inhalation LC50 Rat >5.2 mg/L 4 h; Oral LD50 Rat 14000 mg/kg; Dermal LD50 Rabbit >2000 mg/kg
Toluene
Inhalation LC50 Rat 12.5 mg/L 4 h; Inhalation LC50 Rat >26700 ppm 1 h; Oral LD50 Rat 636 mg/kg; Dermal LD50 Rabbit 8390
mg/kg; Dermal LD50 Rat 12124 mg/kg
Butane
Inhalation LC50 Rat 658 mg/L 4 h
Xylenes (o-, m-, p- isomers)
Inhalation LC50 Rat 5000 ppm 4 h; Inhalation LC50 Rat 47635 mg/L 4 h; Oral LD50 Rat 4300 mg/kg; Dermal LD50 Rabbit
>1700 mg/kg
Benzene, 1,2,4-trimethylInhalation LC50 Rat 18 g/m3 4 h; Oral LD50 Rat 3400 mg/kg; Dermal LD50 Rabbit >3160 mg/kg
Ethyl alcohol
Oral LD50 Rat 7060 mg/kg; Inhalation LC50 Rat 124.7 mg/L 4 h
Ethylbenzene
Inhalation LC50 Rat 17.2 mg/L 4 h; Oral LD50 Rat 3500 mg/kg; Dermal LD50 Rabbit 15354 mg/kg
Benzene
Inhalation LC50 Rat 13050-14380 ppm 4 h; Oral LD50 Rat 1800 mg/kg
Hexane
Inhalation LC50 Rat 48000 ppm 4 h; Oral LD50 Rat 25 g/kg; Dermal LD50 Rabbit 3000 mg/kg
Potential Health Effects: Skin Corrosion Property/Stimulativeness
Practically non-toxic if absorbed following acute (single) exposure. May cause skin irritation with prolonged or repeated contact.
Liquid may be absorbed through the skin in toxic amounts if large areas of skin are repeatedly exposed.
Potential Health Effects: Eye Critical Damage/Stimulativeness
Contact with eyes may cause mild to moderate irritation.
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Safety Data Sheet

SDS No. 3000

Material Name: Gasoline All Grades w/ Ethanol

Section 11 - Toxicological Information - continued
Potential Health Effects: Ingestion
Ingestion may cause gastrointestinal disturbances, including irritation, nausea, vomiting and diarrhea, and central nervous
system (brain) effects similar to alcohol intoxication. In severe cases, tremors, convulsions, loss of consciousness, coma,
respiratory arrest, and death may occur.
Potential Health Effects: Inhalation
Excessive exposure may cause irritations to the nose, throat, lungs and respiratory tract. Central nervous system (brain) effects
may include headache, dizziness, loss of balance and coordination, unconsciousness, coma, respiratory failure, and death.
WARNING: the burning of any hydrocarbon as a fuel in an area without adequate ventilation may result in hazardous levels of
combustion products, including carbon monoxide, and inadequate oxygen levels, which may cause unconsciousness, suffocation,
and death.
Respiratory Organs Sensitization/Skin Sensitization
This product is not reported to have any skin sensitization effects.
Generative Cell Mutagenicity
This product is not reported to have any skin sensitization effects.
CARCINOGENICITY
A: General Product Information
May cause cancer.
IARC has determined that gasoline and gasoline exhaust are possibly carcinogenic in humans. Inhalation exposure to completely
vaporized unleaded gasoline caused kidney cancers in male rats and liver tumors in female mice. The U.S. EPA has determined
that the male kidney tumors are species-specific and are irrelevant for human health risk assessment. The significance of the
tumors seen in female mice is not known. Exposure to light hydrocarbons in the same boiling range as this product has been
associated in animal studies with effects to the central and peripheral nervous systems, liver, and kidneys. The significance of
these animal models to predict similar human response to gasoline is uncertain.
This product contains benzene. Human health studies indicate that prolonged and/or repeated overexposure to benzene may
cause damage to the blood-forming system (particularly bone marrow), and serious blood disorders such as aplastic
B: Component Carcinogenicity
Gasoline, motor fuel
ACGIH: A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans
Toluene

ACGIH: A4 - Not Classifiable as a Human Carcinogen
IARC: Monograph 71 [1999]; Monograph 47 [1989] (Group 3 (not classifiable))

Xylenes (o-, m-, p- isomers)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
IARC: Monograph 71 [1999]; Monograph 47 [1989] (Group 3 (not classifiable))
Ethyl alcohol
ACGIH: A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans
IARC: Monograph 100E [in preparation] (in alcoholic beverages); Monograph 96 [2010] (in alcoholic beverages)

(Group 1 (carcinogenic to humans))
Ethylbenzene
ACGIH: A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans
IARC: Monograph 77 [2000] (Group 2B (possibly carcinogenic to humans))
Benzene
ACGIH:
OSHA:
NIOSH:
NTP:
IARC:

A1 - Confirmed Human Carcinogen
5 ppm STEL (Cancer hazard, Flammable, See 29 CFR 1910.1028, 15 min); 0.5 ppm Action Level; 1 ppm TWA
potential occupational carcinogen
Known Human Carcinogen (Select Carcinogen)
Monograph 100F [in preparation]; Supplement 7 [1987]; Monograph 29 [1982]
(Group 1 (carcinogenic to humans))
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Safety Data Sheet

SDS No. 3000

Material Name: Gasoline All Grades w/ Ethanol

Section 11 - Toxicological Information - continued
Reproductive Toxicity
This product is suspected of damaging fertility or the unborn child.
Specified Target Organ General Toxicity: Single Exposure
This product may cause drowsiness or dizziness.
Specified Target Organ General Toxicity: Repeated Exposure
This product causes damage to organs through prolonged or repeated exposure.
Aspiration Respiratory Organs Hazard
The major health threat of ingestion occurs from the danger of aspiration (breathing) of liquid drops into the lungs, particularly
from vomiting. Aspiration may result in chemical pneumonia (fluid in the lungs), severe lung damage, respiratory failure and
even death.

Section 12 - Ecological Information
ECOTOXICITY
A: General Product Information
Very toxic to aquatic life with long lasting effects. Keep out of sewers, drainage areas and waterways. Report spills and releases,
as applicable, under Federal and State regulations.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Gasoline, motor fuel (86290-81-5)
Test & Species
96 Hr LC50 Alburnus alburnus
96 Hr LC50 Cyprinodon variegatus
72 Hr EC50 Pseudokirchneriella subcapitata
24 Hr EC50 Daphnia magna

Conditions
119 mg/L [static]
82 mg/L [static]
56 mg/L
170 mg/L

Toluene (108-88-3)
Test & Species
96 Hr LC50 Pimephales promelas
96 Hr LC50 Pimephales promelas
96 Hr LC50 Oncorhynchus mykiss
96 Hr LC50 Oncorhynchus mykiss
96 Hr LC50 Oncorhynchus mykiss
96 Hr LC50 Lepomis macrochirus
96 Hr LC50 Oryzias latipes
96 Hr LC50 Poecilia reticulata
96 Hr LC50 Poecilia reticulata
96 Hr EC50 Pseudokirchneriella subcapitata
72 Hr EC50 Pseudokirchneriella subcapitata
48 Hr EC50 Daphnia magna
48 Hr EC50 Daphnia magna

Conditions
15.22-19.05 mg/L [flow-through] 1 day old
12.6 mg/L [static]
5.89-7.81 mg/L [flow-through]
14.1-17.16 mg/L [static]
5.8 mg/L [semi-static]
11.0-15.0 mg/L [static]
54 mg/L [static]
28.2 mg/L [semi-static]
50.87-70.34 mg/L [static]
>433 mg/L
12.5 mg/L [static]
5.46 - 9.83 mg/L [Static]
11.5 mg/L

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Safety Data Sheet
Material Name: Gasoline All Grades w/ Ethanol

Section 12 - Ecological Information - continued
Xylenes (o-, m-, p- isomers) (1330-20-7)
Test & Species
96 Hr LC50 Pimephales promelas
96 Hr LC50 Oncorhynchus mykiss
96 Hr LC50 Oncorhynchus mykiss
96 Hr LC50 Lepomis macrochirus
96 Hr LC50 Lepomis macrochirus
96 Hr LC50 Lepomis macrochirus
96 Hr LC50 Pimephales promelas
96 Hr LC50 Cyprinus carpio
96 Hr LC50 Cyprinus carpio
96 Hr LC50 Poecilia reticulata
48 Hr EC50 water flea
48 Hr LC50 Gammarus lacustris

Conditions
13.4 mg/L [flow-through]
2.661-4.093 mg/L [static]
13.5-17.3 mg/L
13.1-16.5 mg/L [flow-through]
19 mg/L
7.711-9.591 mg/L [static]
23.53-29.97 mg/L [static]
780 mg/L [semi-static]
>780 mg/L
30.26-40.75 mg/L [static]
3.82 mg/L
0.6 mg/L

Benzene, 1,2,4-trimethyl- (95-63-6)
Test & Species
96 Hr LC50 Pimephales promelas
48 Hr EC50 Daphnia magna

Conditions
7.19-8.28 mg/L [flow-through]
6.14 mg/L

Ethyl alcohol (64-17-5)
Test & Species
96 Hr LC50 Oncorhynchus mykiss
96 Hr LC50 Pimephales promelas
96 Hr LC50 Pimephales promelas
48 Hr LC50 Daphnia magna
24 Hr EC50 Daphnia magna
48 Hr EC50 Daphnia magna

Conditions
12.0 - 16.0 mL/L [static]
>100 mg/L [static]
13400 - 15100 mg/L [flow-through]
9268 - 14221 mg/L
10800 mg/L
2 mg/L [Static]

Ethylbenzene (100-41-4)
Test & Species
96 Hr LC50 Oncorhynchus mykiss
96 Hr LC50 Oncorhynchus mykiss
96 Hr LC50 Pimephales promelas
96 Hr LC50 Lepomis macrochirus
96 Hr LC50 Pimephales promelas
96 Hr LC50 Poecilia reticulata
72 Hr EC50 Pseudokirchneriella subcapitata
96 Hr EC50 Pseudokirchneriella subcapitata
72 Hr EC50 Pseudokirchneriella subcapitata
96 Hr EC50 Pseudokirchneriella subcapitata
48 Hr EC50 Daphnia magna

Conditions
11.0-18.0 mg/L [static]
4.2 mg/L [semi-static]
7.55-11 mg/L [flow-through]
32 mg/L [static]
9.1-15.6 mg/L [static]
9.6 mg/L [static]
4.6 mg/L
>438 mg/L
2.6 - 11.3 mg/L [static]
1.7 - 7.6 mg/L [static]
1.8 - 2.4 mg/L

Benzene (71-43-2)
Test & Species
96 Hr LC50 Pimephales promelas
96 Hr LC50 Oncorhynchus mykiss
96 Hr LC50 Lepomis macrochirus
96 Hr LC50 Poecilia reticulata
96 Hr LC50 Pimephales promelas
96 Hr LC50 Lepomis macrochirus
72 Hr EC50 Pseudokirchneriella subcapitata
48 Hr EC50 Daphnia magna
48 Hr EC50 Daphnia magna

Conditions
10.7-14.7 mg/L [flow-through]
5.3 mg/L [flow-through]
22.49 mg/L [static]
28.6 mg/L [static]
22330-41160 μg/L [static]
70000-142000 μg/L [static]
29 mg/L
8.76 - 15.6 mg/L [Static]
10 mg/L

Hexane (110-54-3)
Test & Species
96 Hr LC50 Pimephales promelas
24 Hr EC50 Daphnia magna

Conditions
2.1-2.98 mg/L [flow-through]
>1000 mg/L

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SDS No. 3000

Safety Data Sheet

SDS No. 3000

Material Name: Gasoline All Grades w/ Ethanol

Section 12 - Ecological Information - continued
Persistence/Degradability
No information available.
Bioaccumulation
No information available.
Mobility in Soil
No information available.

Section 13 - Disposal Considerations
Waste Disposal Instructions
See Section 7 for Handling Procedures. See Section 8 for Personal Protective Equipment recommendations.
Disposal of Contaminated Containers or Packaging
Dispose of contents/container in accordance with local/regional/national/international regulations.

Section 14 - Transportation Information
Component Marine Pollutants
This material contains one or more of the following chemicals required by US DOT to be identified as marine pollutants.
Component
Gasoline, motor fuel

CAS #
86290-81-5

DOT regulated marine pollutant

DOT Information
Shipping Name:

Gasoline

Placard:

UN#: 1203
Hazard Class:

Packing Group:

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SDS No. 3000

Material Name: Gasoline All Grades w/ Ethanol

Section 15 - Regulatory Information
Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355
Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Toluene (108-88-3)
SARA 313:
1.0 % de minimis concentration
CERCLA:
1000 lb final RQ; 454 kg final RQ
Xylenes (o-, m-, p- isomers) (1330-20-7)
SARA 313:
1.0 % de minimis concentration
CERCLA:
100 lb final RQ; 45.4 kg final RQ
Benzene, 1,2,4-trimethyl- (95-63-6)
SARA 313:
1.0 % de minimis concentration
Ethylbenzene (100-41-4)
SARA 313:
0.1 % de minimis concentration
CERCLA:
1000 lb final RQ; 454 kg final RQ
Benzene (71-43-2)
SARA 313:
0.1 % de minimis concentration
CERCLA:
10 lb final RQ (received an adjusted RQ of 10 lbs based on potential carcinogenicity in an August 14, 1989

final rule); 4.54 kg final RQ (received an adjusted
Hexane (110-54-3)
SARA 313:
1.0 % de minimis concentration
CERCLA:
5000 lb final RQ; 2270 kg final RQ
SARA Section 311/312 - Hazard Classes
Acute Health

Chronic Health

Fire

Sudden Release of Pressure

Reactive

Component Marine Pollutants
This material contains one or more of the following chemicals required by US DOT to be identified as marine pollutants.
Component
Gasoline, motor fuel

CAS #
86290-81-5

DOT regulated marine pollutant

State Regulations
Component Analysis - State
None of this product’s components are listed on the state lists from CA, MA, MN, NJ, PA, or RI.
Component
Gasoline, motor fuel
Toluene
Butane
Xylenes (o-, m-, p- isomers)
Benzene, 1,2,4-trimethylEthyl alcohol
Ethylbenzene
Benzene
Hexane

CAS
86290-81-5
108-88-3
106-97-8
1330-20-7
95-63-6
64-17-5
100-41-4
71-43-2
110-54-3

CA
No
Yes
Yes
Yes
No
Yes
Yes
Yes
No

MA
No
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes

MN
No
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes

NJ
No
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes

PA
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes

RI
No
No
No
No
No
No
No
No
No

The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986
(Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer.
WARNING! This product contains a chemical known to the state of California to cause reproductive/developmental effects.

Page 12 of 14 - Revision Date: 11/08/2013

Safety Data Sheet
Material Name: Gasoline All Grades w/ Ethanol

Section 15 - Regulatory Information - continued
Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component
Toluene
Butane
Benzene, 1,2,4-trimethylEthyl alcohol
Ethylbenzene
Benzene
Hexane

CAS #
108-88-3
106-97-8
95-63-6
64-17-5
100-41-4
71-43-2
110-54-3

Minimum Concentration
1%
1%
0.1 %
0.1 %
0.1 %
0.1 %
1%

Additional Regulatory Information
Component Analysis - Inventory
Component

CAS #

TSCA

CAN

EEC

Gasoline, motor fuel

86290-81-5

DSL

EINECS

Toluene

108-88-3

Yes

DSL

EINECS

Butane

106-97-8

Yes

DSL

EINECS

Xylenes (o-, m-, p- isomers)

1330-20-7

Yes

DSL

EINECS

Benzene, 1,2,4-trimethyl-

95-63-6

Yes

DSL

EINECS

Ethyl alcohol

64-17-5

Yes

DSL

EINECS

Ethylbenzene

100-41-4

Yes

DSL

EINECS

Benzene

71-43-2

Yes

DSL

EINECS

Hexane

110-54-3

Yes

DSL

EINECS

Page 13 of 14 - Revision Date: 11/08/2013

SDS No. 3000

Safety Data Sheet

SDS No. 3000

Material Name: Gasoline All Grades w/ Ethanol

Section 16 - Other Information
NFPA® Hazard Rating
Health

Fire

Reactivity

3
2

HMIS® Hazard Rating
Health

Moderate

Fire

Serious

Physical

Minimal

*Chronic

Key/Legend
EPA = Environmental Protection Agency; TSCA = Toxic Substance Control Act; ACGIH = American Conference of Governmental
Industrial Hygienists; IARC = International Agency for Research on Cancer; NIOSH = National Institute for Occupational Safety
and Health; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration., NJTSR = New Jersey
Trade Secret Registry.
Literature References
None
Other Information
Information presented herein has been compiled from sources considered to be dependable, and is accurate and reliable to the
best of our knowledge and belief, but is not guaranteed to be so. Since conditions of use are beyond our control, we make no
warranties, expressed or implied, except those that may be contained in our written contract of sale or acknowledgment.
Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if reasonable safety
procedures are not adhered to as stipulated in the data sheet. Additionally, vendor assumes no responsibility for injury to
vendee or third persons proximately caused by abnormal use of the material, even if reasonable safety procedures are followed.
Furthermore, vendee assumes the risk in their use of the material.

End of Sheet

Page 14 of 14 - Revision Date: 11/08/2013

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