C KEMI301B Superfloc 491kvp (MSDS)
User Manual: KEMI301B
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MSDS: 0013645 Print Date: 08/30/2008 Revision Date: 08/22/2008 SAFETY DATA SHEET _____________________________________________________________________________ 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING Product Name: SUPERFLOC® C-491KVP Product Description: Intended/Recommended Use: Cationic polyacrylamide Flocculant Kemira Kemi AB, P.O. Box 902, SE-25109, HELSINGBORG, Sweden - Phone No.: +46 42 17 10 00 ProductSafety.NL.Botlek@kemira.com EMERGENCY PHONE: IN THE NETHERLANDS: 0181-295500; OUTSIDE THE NETHERLANDS: 31-181-295500 ® indicates trademark registered in the U.S. Outside the U.S., mark may be registered, pending or a trademark. Mark is or may be used under license. _____________________________________________________________________________ 2. HAZARDS IDENTIFICATION HUMAN AND ENVIRONMENTAL HAZARDS None −⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯−− 3. COMPOSITION/INFORMATION ON INGREDIENTS HAZARDOUS INGREDIENTS Component / CAS No. Adipic acid 124-04-9 % ~ 4.5 (w/w) EC-No 204-673-3 Symbol / Risk Phrases Xi; R36 See Section 16 for Ingredient Risk Phrase Text _____________________________________________________________________________ 4. FIRST AID MEASURES Ingestion: Material is not expected to be harmful by ingestion. No specific first aid measures are required. Skin Contact: Wash immediately with plenty of water and soap. Eye Contact: Rinse immediately with plenty of water for at least 15 minutes. Inhalation: Remove to fresh air. If breathing is difficult, give oxygen. Obtain medical advice if there are persistent symptoms. −⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯−− SUPERFLOC® C-491KVP MSDS: 0013645 Print Date: 08/30/2008 Page 2 of 7 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Use water spray or fog, carbon dioxide or dry chemical. Protective Equipment: Firefighters, and others exposed, wear self-contained breathing apparatus. Wear full firefighting protective clothing. See MSDS Section 8 (Exposure Controls/Personal Protection). Special Hazards: Dust may be explosive if mixed with air in critical proportions and in the presence of a source of ignition. −⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯−− 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Refer to Section 8 (Exposure Controls/Personal Protection) for appropriate personal protective equipment. Methods For Cleaning Up: Slippery when wet. Sweep up into containers for disposal. Flush spill area with water. If slipperiness remains apply more dry-sweeping compound. Prevent liquid entering sewers. −⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯−− 7. HANDLING AND STORAGE HANDLING Maintain good housekeeping to control dust accumulations. STORAGE To avoid product degradation and equipment corrosion, do not use iron, copper or aluminum containers or equipment. Material is hygroscopic and should not be exposed to moisture in order to maintain product integrity. Storage Temperature: Room temperature Reason: Integrity. _____________________________________________________________________________ 8. EXPOSURE CONTROLS / PERSONAL PROTECTION CONTROL PARAMETERS - Limits Adipic acid 124-04-9 The Netherlands: MAC (Maximal Aanvaarde Concentratie) Denmark: Graensevaerdier ACGIH (TLV) 5 mg/m3 (MAC) 5 mg/m3 (TWA) 5 mg/m3 (TWA) Engineering Measures: Engineering controls are not usually necessary if good hygiene practices are followed. Respiratory Protection: Where exposures are below the established exposure limit, no respiratory protection is required. Where exposures exceed the established exposure limit, use respiratory protection recommended for the material and level of exposure. Eye Protection: Wear eye/face protection. MSDS: SUPERFLOC® C-491KVP 0013645 Print Date: 08/30/2008 Page 3 of 7 Skin Protection: Avoid skin contact. Wear impermeable gloves. Additional Advice: Before eating, drinking, or smoking, wash face and hands thoroughly with soap and water. _____________________________________________________________________________ 9. PHYSICAL AND CHEMICAL PROPERTIES Color: Appearance: Odor: Boiling Point: Melting Point: Vapor Pressure: Specific Gravity/Density: Vapor Density: Percent Volatile (% by wt.): pH: Saturation In Air (% By Vol.): Evaporation Rate: Solubility In Water: Volatile Organic Content (EU): Flash Point: Flammable Limits (% By Vol): Autoignition Temperature: Decomposition Temperature: Partition coefficient (noctanol/water): off white crystalline powder none Not applicable Not available Not applicable 0.75 Not applicable 7 3 - 5(0.5% aqueous solution) Not applicable Not applicable Limited by viscosity Not available Not applicable Not applicable >150 °C >150 °C Not applicable _____________________________________________________________________________ 10. STABILITY AND REACTIVITY Stability: Conditions To Avoid: Polymerization: Conditions To Avoid: Materials To Avoid: Stable None known Will not occur None known Strong oxidizing agents. Carbon dioxide Carbon monoxide (CO) Ammonia (NH3) oxides of nitrogen oxides of sulfur (includes sulfur di and tri oxides) −⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯−− Hazardous Decomposition Products: 11. TOXICOLOGICAL INFORMATION POTENTIAL HEALTH EFFECTS None PRODUCT TOXICITY INFORMATION SUPERFLOC® C-491KVP MSDS: 0013645 Print Date: Page 4 of 7 08/30/2008 ACUTE TOXICITY DATA oral dermal inhalation rat rabbit rat Acute LD50>5,000 mg/kg Acute LD50 Acute LC50 LOCAL EFFECTS ON SKIN AND EYE Acute Irritation Acute Irritation skin eye Not irritating Not irritating ALLERGIC SENSITIZATION Sensitization Sensitization dermal inhalation No data No data >2,000 mg/kg .>20.0 mg/l . GENOTOXICITY Assays for Gene Mutations Ames Salmonella Assay No data HAZARDOUS INGREDIENT TOXICITY DATA ACUTE TOXICITY DATA Adipic acid oral (gavage) rat Acute LD50 > 11000 mg/kg LOCAL EFFECTS ON SKIN AND EYE Adipic acid Acute Eye Irritation rabbit Irritating Acute Dermal Irritation Not irritating _____________________________________________________________________________ SUPERFLOC® C-491KVP MSDS: 0013645 Print Date: 08/30/2008 Page 5 of 7 12. ECOLOGICAL INFORMATION This material is not classified as dangerous for the environment. The effects on aquatic organisms are due to an external (non-systemic) mode of action, and are significantly reduced (by a factor of 7-20) within 30 minutes due to binding of the product to dissolved organic carbon and inorganic sorbents such as clays and silts. All ecological information provided was conducted on a structurally similar product. Acute toxicity tests conducted using environmentally representative water gave the following results: ALGAE TEST RESULTS Test: Growth Inhibition (OECD 201) Due to the cationicity of the polymer, an algae growth inhibition test is not appropriate. FISH TEST RESULTS Test: Acute toxicity, freshwater (OECD 203) Duration: 96 hr. Species: Zebra Fish (Brachydanio rerio) LC50 >1 - 10 mg/l INVERTEBRATE TEST RESULTS Test: Acute Immobilization (OECD 202) Duration: 48 hr Species: Water Flea (Daphnia magna) >10 - 100 mg/l EC50 DEGRADATION Test: CO2 Evolution: Modified Sturm (OECD 301B) Duration: 28 day SUPERFLOC® C-491KVP MSDS: 0013645 Print Date: 08/30/2008 Page 6 of 7 This material is not readily biodegradable (OECD 301B), but degradable by hydrolysis. The large polymer size is incompatible with transport across biological membranes and diffusion; the bioconcentration factor is therefore considered to be zero. −⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯−− 13. DISPOSAL CONSIDERATIONS The Company encourages the recycle, recovery and reuse of materials, where permitted. If disposal is necessary, The Company recommends that organic materials, especially when classified as hazardous waste, be disposed of by thermal treatment or incineration at approved facilities. All local and national regulations should be followed. −⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯−− 14. TRANSPORT INFORMATION This section provides basic shipping classification information. Refer to appropriate transportation regulations for specific requirements. ADR/RID Class: Not Applicable/Not Regulated IMO Proper Shipping Name: Not applicable/Not regulated ICAO / IATA Proper Shipping Name: Not applicable/Not regulated Packing Instructions/Maximum Net Quantity Per Package: Passenger Aircraft: Cargo Aircraft: −⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯−− 15. REGULATORY INFORMATION EU MARKING AND LABELING Symbol(s): None required Risk Phrases: None Safety Phrases: S82 - Spills are very slippery when wet. INVENTORY INFORMATION European Union (EU): All components of this product are included on the European Inventory of Existing Chemical Substances (EINECS) or are not required to be listed on EINECS. United States (USA): All components of this product are included on the TSCA Chemical Inventory or are not required to be listed on the TSCA Chemical Inventory. MSDS: SUPERFLOC® C-491KVP 0013645 Print Date: 08/30/2008 Page 7 of 7 Canada: All components of this product are included on the Domestic Substances List (DSL) or are not required to be listed on the DSL. Australia: All components of this product are included in the Australian Inventory of Chemical Substances (AICS). China: All components of this product are included on the Chinese inventory or are not required to be listed on the Chinese inventory. Japan: All components of this product are included on the Japanese (ENCS) inventory or are not required to be listed on the Japanese inventory. Korea: All components of this product are included on the Korean (ECL) inventory or are not required to be listed on the Korean inventory. Philippines: All components of this product are included on the Philippine (PICCS) inventory or are not required to be listed on the Philippine inventory. _____________________________________________________________________________ 16. OTHER INFORMATION Reasons for Issue: New Format Component Risk Phrases Adipic acid R36 - Irritating to eyes. −⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯−− Richard Moye, Product Regulatory, 1-251-662-1581 −⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯−− This information is given without any warranty or representation. We do not assume any legal responsibility for same, nor do we give permission, inducement, or recommendation to practice any patented invention without a license. It is offered solely for your consideration, investigation, and verification. Before using any product, read its label. −⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯−−
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