443 Sherwin Williams 3 1000glkt Kit Paint Epoxy Whi Bac702 Gallon
User Manual: 443
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MSDS: 443-3-1000 Page 1 of6 MATERIAL SAFETY DATA SHEET AkzoNobel 443-3-1000; White BAC 702 #715480 1. Identification ofthe Product and Company Product Code & Name: 443-3-1000; White BAC 702 #715480 Manufacturer: AkzoNobel Aerospace Coatings, a division of intemational Paint LLC 1 East Water Street Waukegan, IL 60065 USA Tel. 847 623 4200 Fax 847 625 3200 Emergency. Emergency lelephone (US) CHEMTREC - 600 424 9300 Emergency telephone (Outside US) CHEMTREC - 703 527 3887 Product Use: Coating NOTE: CHEMTREC numbers to be usad only in the event of emofgenaes involving a spill, l«ak. fire, exposure or acddent involving ( RevisionDatc: 06/30/2010 2. Hazards Identification " * Emergency Overview " * and flame.— white liquid with solvent odor Class IB - Flammable Liquid Keep away from heat, sparks Potenttal Acute Heahh Effects Eye: Moderate imtation with redness and minor discomfort after direct splash to eye. Vapors may cause eye imtation with redness and minor discomfort ofthe eye. Skin: Moderately irritating with possible redness and discomfort. May cause dry skin by dissolving skin oils. Product can be absort>ed through the skin, but no adverse health effects are expected with normal occupational exposure. Inhalation: Moderately irritating to nose, throat or breathing passages. May cause unconsciousness by depressing the central nervous system after prolonged exposure to high concentrations. May increase risk for sudden death from irregular heart rhythms caused by stressful conditkins that increase the levels of adrenalin in the blood. Ingestion: Moderately irritating to the mouth, stomach, and digestive system. Ingestion of small amounts of the hydrocarbon in this product may be accidentally aspirated into the lungs and cause a chemical pneumonia that can be life-threatening. No ingesiion exposure expected with normal occupational use. Potential Chronic Health Effects Eye: Chronic exposure may cause inflammation of the lens of the eye (cornea). Chronic exposure can cause redness and irritation of the membrane that covers the eyeball and the inside of ^ e eyelids (conjunctivitis). Skin; Repeated contact can cause skin to crack and peel. Inhalation; Chronic inhalation exposure may cause coughing or tightness in chest. May cause slight increase in liver size without affecting the function of the liver. May cause small changes in the hearing system. Chronic inhalation may lower the count of certain types of blood cells. Chronic alcohol use can increase the potential for toxidty from the repeated exposure to the aromatic hydrocarbon in this product. May accumulate in the body with daily exposure. Ingestion: Chronic ingestion exposure would be unlikely due to the method of use or physicai properties of this product. The components Iisted in Section 3 may affect the following target organs: Blood. Central Nervous System. Eyes. Hematopoietic System. Kidneys. Uver. Lymphatic System. Respiratory System. Skin. Primary Roule{s) Of Entry: Skin Contact, Skin Absorption, Inhalation, Eye Contact 3. Composition / Information on Ingredients Chemical Name file://N:\MSDS\MSDSstoPublish\443-3-1000 USA ENG.HTM CAS Number WT% 6/30/2010 MSDS: 443-3-1000 Page 2 of 6 TITANIUM DIOXIDE METHYL ETHYL KETONE TOLUENE BUTYL ACETATE 2-BUTOXYETHANOL CRYSTALLINE SILICA (QUARTZ) 13463-67-7 78-93-3 108-88-3 123-86-4 111-76-2 14808-60-7 15-40 10-30 7-13 5-10 1-5 O.M.O 4. First Aid Measures First Aid - Eye Conlact: If this product contacts the eyes, immediately wash the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention. First Aid - Skin Contact: If this product contacts the skin, promptly wash the contaminated skin wilh soap & water. If this product penetrates the clothing, promptly remove the clothing and wash the skin with soap & water. If imtation persists after washing, get medical attenlion. Launder clothing before reuse. First Aid - Inhalation: If a person breathes large amounts of this product, move the exposed person to fresh air at once, ifbreaihing is difficult, get medical attention. First Aid - Ingestion: If this product has been swallowed, get medical attention immedialely. 5. Fire-Fighting Measures Flash Point (F): 25 LOWER EXPLOSIVE LIMIT: 0.9 Auto Ignition Temperature (F): N.D. UPPER EXPLOSIVE LIMIT: 11.5 Extinguishing Media: Cart>on Dioxide, Dry Chemical, Foam Special Fire Fighiing Procedures: Firefighters and others exposed to vapors or products of combuslion should wear self-contained brealhing apparatus. Conditions of Flammabilily: Vapors are heavier than air and may travel to a source of ignition and flash back. Hazardous Combustion Producis: Combustion may produce carbon monoxide, carbon dioxide and irritating or toxic vapors and gases. Explosion Data - Sensitivity lo Mechanical Impact: Avoid any sparking between metals. Use of non-sparking tools is recommended. Explosion Data - Sensitivity lo Static Discharge: To avoid fire or exptosion, dissipate static electridty during transfer by grounding and bonding containers and equipment before transferring material. 6. Accidental Release Measures Personal Precautions: Use personal protection recommended in Seclion 6. Evacuate personnel to safe areas. Environmental Precautions; Do not allow material to enter sewers or ground. Methods for Containment: Ventilate area to maintain exposure below permissible exposure limits. Slop or control the spill, if this can be done with undue risk. Methods for Clean-Up: Eliminate all ignition sources. Wipe, scrape, or soak up in an ineri material. Wash spill area with soap and water. Use spark-proof tools to containerize. Use caution as spill may create a slip hazard. Isolate discharge material for proper disposal. 7. Handling and Storage Handling; Grounding or bonding of containers is recommended before material transtisr. Activities such as sanding, buming off, etc, of paint films may generate dust and/or fumes hazardous to the skin and lungs. Sanding dust may contain levels of unreacted materials which may file://N;\MSDS\MSDSstoPublish\443-3-1000 USA ENG.HTM 6/30/2010 MSDS: 443-3-1000 Page 3 of 6 cause irritation and sensitization; these are highest in the first 24/48 hours after application. Wori( in well ventilated areas. Use local exhaust ventilation and personal skin and respiratory protective equipment as appropriate. Use exptoslon-proof electrical (ventilating, lighting and material handling) equlpmont. Use non-sparking tools. Take precautionary measures against electrostatic discharges. Store away from heat, sparks, open flame and other ignition sources. Storage: Store inside between 40F-100F. Storage areas should be dry and well-ventilated. Eliminate atl igniflon sources 8. Exposure Controls / Personal Protection Engineering Controls: It Is recommended that work be done in an adequately venfllated area (i.e., ventilation sufficient to maintain concentrations below one half of the PEL and other relevant standards). Local exhaust ventilation is recommended when general ventilation is not suffident to control airbome contamination. Use explosion-proof venfllation equipment. Respiratory Protection; Appropriate respirators must be used, and a program that follows 29 CFR 1910.134 or other applicable regulatory requirements must be followed, when workplace hazards warrant the use of a respirator. NIOSH-approved or other appropriate respirators must be used when respiratory prolection is necessary. Eye Prolection; Wear appropriate goggles, face shieWs or other PPE, which will be effeciive under the circumstances if the possibility of contact exists. A program meeflng 29 CFR 1910.133 or other applicable regulatory requiremenls must be followed when PPE is necessary. Other Protective Equipment: Ltee impermeable gloves and protective dothing as necessary to prevent skin conlact. Hygienic Practices: Do not eat, drink, chew tobacco or gum, or apply cosmetics while working with this product. Wash hands before perfomiing any of these activities. ChomU Number ACGIH TLV TWA ACGIH TLV STEL OSHA PEL C TITANIUM DIOXIDE 13463-67-7 10 m g / m 3 dust N.D. N.D. METHYL ETHYL KETONE TOLUENE BUTYL ACETATE 2-BUTOXYETHANOL CRYSTALLINE SILICA (QUARTZ) 78-93-3 108-88-3 123-86-4 111-76-2 14808-60-7 200 p p m 20 ppm ISOppm 20 ppm 0.025 m g / m 3 300 ppm N.D. 200 ppm N.D. N.D. N.D. 300 p p m N.D. N.D. N.D. QSHA PEL TWA i 5 mg/m3 dust 200 ppm 200 ppm 150 ppm 50 ppm 0.1 mg/m3 9. Physical and Chemical Properties Theoretical Values Boiling Range (F); 175-380 VOC (g/l)(less water A exempt): 491 Freeze Point (F): N.D. VOC (lb/gal)(less water & exempt)- 4.1 Specific Gravity. 1.3 % Solids By Weighi: 61 Appearance: white % Solids By Volume: 42 Physical State: liquid Density (Ib/gal): 10.5 Odor, solvent Flashpoint (F): 25 Odor Threshold (ppm): N.D. Vapor Pressure; N.D. Vapor Density; <4.60 Evaporation Rate. N.D. pH. N.A. Coefficient of waler/oil distribution; N.D. 10. Stability and Reactivity Conditions To Avoid: Avoid contact with heat, open flame, sparies, or ignition sources. Open flames and sparies. Hazardous Polymerization'. Will not occur. Stability; Stable. file://N:\MSDS\MSDSstoPub!ish\443-3-1000 USA ENG.HTM 6/30/2010 MSDS: 443-3-1000 Page 4 of6 111. Toxicological Information Chemical Name TITANIUM DIOXIDE METHYL ETHYL KETONE TOLUENE BUTYL ACETATE 2-BUTOXYETHANOL CRYSTALLINE SILICA (QUARTZ) LDSO LCSO IARC Oral rat >10,000 mg/kg Inhalation rat >6.8 mg/l Oral Rat: 2.9 g/kg Inhalation Rat: 23500 mg/m3/8H Oral Rate: 5000 mg/kg Inhalation Rat: 8000 ppm/4H Oral Rat: 14130 mg/kg Inhalation Rat: 2000 ppm/4H Oral Rat: 470 mg/kg Inhalation Rat: 450 ppm/4H Oral rat: 500 mg/kg N.D. GnDup 1 NTP OSHA Anticipated Care IARC has Issued a notice that they will publish a monograph that lists titanium dioxide (Ti02) as possibly carcinogenic to humans (Group 2B) by inhalation (based solely on animal data). Human epidemtology studies do not suggest an increased risk of cancer in humans for occupational exposure b titanium dioxide. According to the IARC summary on titanium dioxide, 'No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium dioxide is bound to other materials, such as paint.* Irritancy of Product: This product contains ingredient(s) that are irritating to skin and eyesSensitization to Product; This product contains ingredient(s) that are known skin sensitizers. Carcinogenicity: See IARC, NTP and OSHA data above. Reproductive Toxicity: No Information. Teralogenicity: No Infonnation. Mulagenicity: No Information. 12. Ecological Infomnation AkzoNobel has not conducted specific studies on the eco toxicity or environmental fate of this product. Commonly available data on certain ingredients indicate that acute or chronic effects could result from uncontrolled releases to soil, ground water, storm waters, or air. Appropriate measures should be taken to prevent uncontrolled releases. Prompt containment and clean up should be performed if releases do occur. 13. Disposal Considerations Legaldispositionofwastesis the responsibility ofthe owner/generator of the waste, /applicable federal, state, and/or local regulations must be followed during treatment, storage, or disposal of waste containing this product. Do not dispose of in an uncontrolled manner. 14. Transport Information DOT Proper Shipping Name. DOT Hazard Class OOT UN NurfiDSl: DOT Packing Group: l^boi CodsG Rosp. Guide F^ge Paint 3 UN1263 11 3 128 Chemical Name METHYL ETHYL KETONE TOLUENE BUTYL ACETATE IATA Proper Shipping Narre IATA IHazard Class lATAUNNumoer IATA Packing Group IATA Hazard Subciaw Paint 3 UNISBS II N/A CAS Number 78-93-3 108-88-3 123-86-4 Painl 3 UN 1263 II WA No lUO Proper Shipping Name lUO Hazaid Class IMO UN Numtwr IMO Packing Group. IMO SuDsidiary RisK. Marino Pollulant CERCLA RQ 5000 LBS 1000 LBS 5000 LBS IS. Regulatory Information U.S. FEDERAL REGULATIONS: A s follows - file://N:\MSDS\MSDSstoPublish\443-3-1000 USA ENG.HTM 6/30/2010 MSDS: 443-3-1000 Page 5 of 6 CERCLA - SARA Hazard Category: This product is considered, under applicabie deflnitions, to meet Uie following categories: IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD, FIRE H/\ZARD SARA Secfion 3^3; Thia product contains the following substances subject to the reporting requirements of Section 313 ofthe Superfund Amendment and Reaulhorizatton Act of 1986 (SARA Tifle III) and 40 CFR 372: ChemicalName TOLUENE 2-BUTOXYETHANOL 313 Category Glycol Ethers CAS Number 108-86-3 111-76-2 WT% 9.6 2.1 Clean Air Act: This product contains the followir^ chemical substances listed as Hazardous Air Pollutants (HAPs) under the Clean Air Act of 1990: Chemical Name TOLUENE HAP Category CAS Number 108-88-3 WT % 9.6 7"oxicSu6sfanc9sCon/ro/Acf: All the components of Uiis product comply with applicable requrements of the US EPA TSCA inventory. Contains the following chemical(s) subject to the reporting requirements of TSCA 12b if exported from Uie US. None Known. U.S. STATE REGULATIONS: A s follows California Proposition 65: WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. INTERNATIONAL REGULATIONS: A s follows Canadian WHMIS Class: B2 D2A CPRC: This product has been classified in accordance with Uie hazard criteria of the ConUolled Product Regulations and the MSDS contains all of the information required by the Controlled Product Regulations. Canadian DSL - All the components of this pmduct are listed or are exempt from listing. European EINECS - All Uie components of this product are listed or are exempt from listing. Austalian AICS - The status of one or more components of this product is not known. 16. Other Information National Paint & Coatings Assodation (NPCA) Hazardous Material Identification System (HMIS): Health: 3 Flammability: 3 Reactivity: 1 Personal Protection: See Section 8 Lagand: N.A. - Not Applicable, N.D. - Not Dotorminod FOR PROFESSIONAL USE ONLY IMPORTANT NOTE The information in this data sheet is not intended to be exhaustive and is based on the present state of our knowledge and on current laws: any person using the product for any purpose oUier than that spectflcally recommended in the lechnical data ^ e e t without first obtaining written confirmation from us as to the suitability of the product for the intended purpose does so at his own risk. It is always the responsibility of the user to take all necessary steps to fulfill the demands set out in Uie local rules and legislation. Always read the Material Oata Sheet and the Technical Data Sheet for this product if available. All advice we give or any statement made about the product by us (whether In this data sheet or othenwise) is correct to the best of our knowledge but we have no control over the quality or the condition of the substrate or the many factors affecting the use and applicaflon ofthe product. Therefore, unless we specifically agree in writing otherwise, we do not accept any liability whatsoever for the performance of the product or for any loss or damage arising out of the use of the product. All products supplied and technical advice given are subject to our standard terms and conditions of sale. You should request a copy of this document and review It carefully. The infomnation contained in this data sheet is subjeci to modification from time to time in the light of experience and our polk:y of continuous development. It Is the user's responsibility to verify that this dala sheet is current prior to using ttie product. Brand names mentioned in this dala sheet are trademarks of or are licensed to AkzoNobel. Head Office AkzoNobel Aerospace Coalings, a division of Intemational Paint LLC, 1 East Water Slreet, Waukegan, IL 60085, USA. www.akzonobel.com/aerospace Revision Date: 06/30/2010 file://N:\MSDS\MSDSstoPublish\443-3-1000 USA ENG.HTM 6/30/2010 MSDS: 443-3-1000 Page 6 of 6 I NPCA Label Statements WARNINGI Flammable liquid and vapor. Vapor harmful. Harmful if inhaled. Harmful if swallowed. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous syslem damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Causes aye irritation. Causes skin imtation. Causes nose and throat imtation. Vapor harmful. May affect Uie brain or nervous system causing dizziness, headache or nausea. Overexposure may cause lung and kidney damage. Cancer hazard. Contains ingredients which can cause cancer. (Risk of cancer depends on duration and level of exposure.) Firsl Aid: In case of eye contact, flush immediately wiUi plenty of water for at least 15 minutes and get medical attention immediately; for skin, wash thoroughly wiUi soap and water. If you experience difficulty in breathing, leave Uie area to obtain fresh air. If continued difficulty is experienced, get medical attention immediately. If swallowed, do not induce vomiting. Get medical attention immedialely. Vapors may cause flash fire. Keep away from heat, sparks and flame. Do not smoke. Extinguish all flames and pilot lights, and turn off stoves & ovens, heaters, electric motors and other sources of ignition during use and until all vapors are gone. Use only with adequate ventilation. Preveni build-up of vapors by opening att windows and doors to achieve cross-ventilation. Ensure fresh air entry during appicali'on and drying. If you experience eye watering, headache or dizziness or if air monitoring demonstrates vapor/mist levels are atiove applicable limits, wear an appropriate, properiy fitted respirator (NIOSH approved) during and after application. Follow respirator manufacturer's directions for respirator use. Close container after each use. Do not get in eyes, on skin or clothing. Do not breathe vapors. Wadh Uioroughly afler handling, FOR INDUSTRIAL USE ONLY. If spilled, contain spilled material and remove wKh inert absorbent. Dispose of contaminated absorbent, container and unused contenls in accordance with local, state and federal regulations. fiIe://N:\MSDS\MSDSstoPublish\443-3-1000 USA ENG.HTM 6/30/2010
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