443 Sherwin Williams 3 1000glkt Kit Paint Epoxy Whi Bac702 Gallon
User Manual: 443
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MSDS: 443-3-1000
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MATERIAL SAFETY DATA SHEET
AkzoNobel
443-3-1000; White BAC 702 #715480
1. Identification ofthe Product and Company
Product Code & Name:
443-3-1000; White BAC 702 #715480
Manufacturer:
AkzoNobel Aerospace Coatings, a division of intemational Paint LLC
1 East Water Street
Waukegan, IL 60065 USA
Tel. 847 623 4200
Fax 847 625 3200
Emergency.
Emergency lelephone (US) CHEMTREC - 600 424 9300
Emergency telephone (Outside US) CHEMTREC - 703 527 3887
Product Use:
Coating
NOTE: CHEMTREC numbers to be usad only in the event of emofgenaes involving a spill, l«ak. fire, exposure or acddent involving (
RevisionDatc:
06/30/2010
2. Hazards Identification
" * Emergency Overview " *
and flame.—
white liquid with solvent odor
Class IB - Flammable Liquid
Keep away from heat, sparks
Potenttal Acute Heahh Effects
Eye: Moderate imtation with redness and minor discomfort after direct splash to eye. Vapors may cause eye imtation with redness and minor
discomfort ofthe eye.
Skin: Moderately irritating with possible redness and discomfort. May cause dry skin by dissolving skin oils. Product can be absort>ed through
the skin, but no adverse health effects are expected with normal occupational exposure.
Inhalation: Moderately irritating to nose, throat or breathing passages. May cause unconsciousness by depressing the central nervous
system after prolonged exposure to high concentrations. May increase risk for sudden death from irregular heart rhythms caused by stressful
conditkins that increase the levels of adrenalin in the blood.
Ingestion: Moderately irritating to the mouth, stomach, and digestive system. Ingestion of small amounts of the hydrocarbon in this product
may be accidentally aspirated into the lungs and cause a chemical pneumonia that can be life-threatening. No ingesiion exposure expected
with normal occupational use.
Potential Chronic Health Effects
Eye: Chronic exposure may cause inflammation of the lens of the eye (cornea). Chronic exposure can cause redness and irritation of the
membrane that covers the eyeball and the inside of ^ e eyelids (conjunctivitis).
Skin; Repeated contact can cause skin to crack and peel.
Inhalation; Chronic inhalation exposure may cause coughing or tightness in chest. May cause slight increase in liver size without affecting the
function of the liver. May cause small changes in the hearing system. Chronic inhalation may lower the count of certain types of blood cells.
Chronic alcohol use can increase the potential for toxidty from the repeated exposure to the aromatic hydrocarbon in this product. May
accumulate in the body with daily exposure.
Ingestion: Chronic ingestion exposure would be unlikely due to the method of use or physicai properties of this product.
The components Iisted in Section 3 may affect the following target organs: Blood. Central Nervous System. Eyes. Hematopoietic System.
Kidneys. Uver. Lymphatic System. Respiratory System. Skin.
Primary Roule{s) Of Entry: Skin Contact, Skin Absorption, Inhalation, Eye Contact
3. Composition / Information on Ingredients
Chemical Name
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CAS Number
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TITANIUM DIOXIDE
METHYL ETHYL KETONE
TOLUENE
BUTYL ACETATE
2-BUTOXYETHANOL
CRYSTALLINE SILICA (QUARTZ)
13463-67-7
78-93-3
108-88-3
123-86-4
111-76-2
14808-60-7
15-40
10-30
7-13
5-10
1-5
O.M.O
4. First Aid Measures
First Aid - Eye Conlact: If this product contacts the eyes, immediately wash the eyes with large amounts of water, occasionally lifting the lower
and upper lids. Get medical attention.
First Aid - Skin Contact: If this product contacts the skin, promptly wash the contaminated skin wilh soap & water. If this product penetrates
the clothing, promptly remove the clothing and wash the skin with soap & water. If imtation persists after washing, get medical attenlion.
Launder clothing before reuse.
First Aid - Inhalation: If a person breathes large amounts of this product, move the exposed person to fresh air at once, ifbreaihing is difficult,
get medical attention.
First Aid - Ingestion: If this product has been swallowed, get medical attention immedialely.
5. Fire-Fighting Measures
Flash Point (F): 25
LOWER EXPLOSIVE LIMIT: 0.9
Auto Ignition Temperature (F): N.D.
UPPER EXPLOSIVE LIMIT: 11.5
Extinguishing Media: Cart>on Dioxide, Dry Chemical, Foam
Special Fire Fighiing Procedures: Firefighters and others exposed to vapors or products of combuslion should wear self-contained brealhing
apparatus.
Conditions of Flammabilily: Vapors are heavier than air and may travel to a source of ignition and flash back.
Hazardous Combustion Producis: Combustion may produce carbon monoxide, carbon dioxide and irritating or toxic vapors and gases.
Explosion Data - Sensitivity lo Mechanical Impact: Avoid any sparking between metals. Use of non-sparking tools is recommended.
Explosion Data - Sensitivity lo Static Discharge: To avoid fire or exptosion, dissipate static electridty during transfer by grounding and bonding
containers and equipment before transferring material.
6. Accidental Release Measures
Personal Precautions: Use personal protection recommended in Seclion 6. Evacuate personnel to safe areas.
Environmental Precautions; Do not allow material to enter sewers or ground.
Methods for Containment: Ventilate area to maintain exposure below permissible exposure limits. Slop or control the spill, if this can be done
with undue risk.
Methods for Clean-Up: Eliminate all ignition sources. Wipe, scrape, or soak up in an ineri material. Wash spill area with soap and water. Use
spark-proof tools to containerize. Use caution as spill may create a slip hazard. Isolate discharge material for proper disposal.
7. Handling and Storage
Handling; Grounding or bonding of containers is recommended before material transtisr. Activities such as sanding, buming off, etc, of paint
films may generate dust and/or fumes hazardous to the skin and lungs. Sanding dust may contain levels of unreacted materials which may
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cause irritation and sensitization; these are highest in the first 24/48 hours after application. Wori( in well ventilated areas. Use local exhaust
ventilation and personal skin and respiratory protective equipment as appropriate. Use exptoslon-proof electrical (ventilating, lighting and
material handling) equlpmont. Use non-sparking tools. Take precautionary measures against electrostatic discharges. Store away from heat,
sparks, open flame and other ignition sources.
Storage: Store inside between 40F-100F. Storage areas should be dry and well-ventilated. Eliminate atl igniflon sources
8. Exposure Controls / Personal Protection
Engineering Controls: It Is recommended that work be done in an adequately venfllated area (i.e., ventilation sufficient to maintain
concentrations below one half of the PEL and other relevant standards). Local exhaust ventilation is recommended when general ventilation is
not suffident to control airbome contamination. Use explosion-proof venfllation equipment.
Respiratory Protection; Appropriate respirators must be used, and a program that follows 29 CFR 1910.134 or other applicable regulatory
requirements must be followed, when workplace hazards warrant the use of a respirator. NIOSH-approved or other appropriate respirators
must be used when respiratory prolection is necessary.
Eye Prolection; Wear appropriate goggles, face shieWs or other PPE, which will be effeciive under the circumstances if the possibility of
contact exists. A program meeflng 29 CFR 1910.133 or other applicable regulatory requiremenls must be followed when PPE is necessary.
Other Protective Equipment: Ltee impermeable gloves and protective dothing as necessary to prevent skin conlact.
Hygienic Practices: Do not eat, drink, chew tobacco or gum, or apply cosmetics while working with this product. Wash hands before
perfomiing any of these activities.
ChomU
Number ACGIH TLV TWA ACGIH TLV STEL OSHA PEL C
TITANIUM DIOXIDE
13463-67-7
10 m g / m 3 dust
N.D.
N.D.
METHYL ETHYL KETONE
TOLUENE
BUTYL ACETATE
2-BUTOXYETHANOL
CRYSTALLINE SILICA (QUARTZ)
78-93-3
108-88-3
123-86-4
111-76-2
14808-60-7
200 p p m
20 ppm
ISOppm
20 ppm
0.025 m g / m 3
300 ppm
N.D.
200 ppm
N.D.
N.D.
N.D.
300 p p m
N.D.
N.D.
N.D.
QSHA
PEL
TWA
i 5 mg/m3
dust
200 ppm
200 ppm
150 ppm
50 ppm
0.1
mg/m3
9. Physical and Chemical Properties
Theoretical Values
Boiling Range (F);
175-380
VOC (g/l)(less water A exempt):
491
Freeze Point (F):
N.D.
VOC (lb/gal)(less water & exempt)-
4.1
Specific Gravity.
1.3
% Solids By Weighi:
61
Appearance:
white
% Solids By Volume:
42
Physical State:
liquid
Density (Ib/gal):
10.5
Odor,
solvent
Flashpoint (F):
25
Odor Threshold (ppm):
N.D.
Vapor Pressure;
N.D.
Vapor Density;
<4.60
Evaporation Rate.
N.D.
pH.
N.A.
Coefficient of waler/oil distribution;
N.D.
10. Stability and Reactivity
Conditions To Avoid: Avoid contact with heat, open flame, sparies, or ignition sources. Open flames and sparies.
Hazardous Polymerization'. Will not occur.
Stability; Stable.
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111. Toxicological Information
Chemical Name
TITANIUM DIOXIDE
METHYL ETHYL KETONE
TOLUENE
BUTYL ACETATE
2-BUTOXYETHANOL
CRYSTALLINE SILICA (QUARTZ)
LDSO
LCSO
IARC
Oral rat >10,000 mg/kg Inhalation rat >6.8 mg/l
Oral Rat: 2.9 g/kg
Inhalation Rat: 23500
mg/m3/8H
Oral Rate: 5000 mg/kg Inhalation Rat: 8000 ppm/4H
Oral Rat: 14130 mg/kg Inhalation Rat: 2000 ppm/4H
Oral Rat: 470 mg/kg
Inhalation Rat: 450 ppm/4H
Oral rat: 500 mg/kg
N.D.
GnDup 1
NTP
OSHA
Anticipated
Care
IARC has Issued a notice that they will publish a monograph that lists titanium dioxide (Ti02) as possibly carcinogenic to humans (Group 2B)
by inhalation (based solely on animal data). Human epidemtology studies do not suggest an increased risk of cancer in humans for
occupational exposure b titanium dioxide. According to the IARC summary on titanium dioxide, 'No significant exposure to titanium dioxide is
thought to occur during the use of products in which titanium dioxide is bound to other materials, such as paint.*
Irritancy of Product: This product contains ingredient(s) that are irritating to skin and eyesSensitization to Product; This product contains ingredient(s) that are known skin sensitizers.
Carcinogenicity: See IARC, NTP and OSHA data above.
Reproductive Toxicity: No Information.
Teralogenicity: No Infonnation.
Mulagenicity: No Information.
12. Ecological Infomnation
AkzoNobel has not conducted specific studies on the eco toxicity or environmental fate of this product. Commonly available data on certain
ingredients indicate that acute or chronic effects could result from uncontrolled releases to soil, ground water, storm waters, or air. Appropriate
measures should be taken to prevent uncontrolled releases. Prompt containment and clean up should be performed if releases do occur.
13. Disposal Considerations
Legaldispositionofwastesis the responsibility ofthe owner/generator of the waste, /applicable federal, state, and/or local regulations must be
followed during treatment, storage, or disposal of waste containing this product. Do not dispose of in an uncontrolled manner.
14. Transport Information
DOT Proper Shipping Name.
DOT Hazard Class
OOT UN NurfiDSl:
DOT Packing Group:
l^boi CodsG
Rosp. Guide F^ge
Paint
3
UN1263
11
3
128
Chemical Name
METHYL ETHYL KETONE
TOLUENE
BUTYL ACETATE
IATA Proper Shipping Narre
IATA IHazard Class
lATAUNNumoer
IATA Packing Group
IATA Hazard Subciaw
Paint
3
UNISBS
II
N/A
CAS Number
78-93-3
108-88-3
123-86-4
Painl
3
UN 1263
II
WA
No
lUO Proper Shipping Name
lUO Hazaid Class
IMO UN Numtwr
IMO Packing Group.
IMO SuDsidiary RisK.
Marino Pollulant
CERCLA RQ
5000 LBS
1000 LBS
5000 LBS
IS. Regulatory Information
U.S. FEDERAL REGULATIONS: A s follows -
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CERCLA - SARA Hazard Category: This product is considered, under applicabie deflnitions, to meet Uie following categories: IMMEDIATE
HEALTH HAZARD, CHRONIC HEALTH HAZARD, FIRE H/\ZARD
SARA Secfion 3^3; Thia product contains the following substances subject to the reporting requirements of Section 313 ofthe Superfund
Amendment and Reaulhorizatton Act of 1986 (SARA Tifle III) and 40 CFR 372:
ChemicalName
TOLUENE
2-BUTOXYETHANOL
313 Category
Glycol Ethers
CAS Number
108-86-3
111-76-2
WT%
9.6
2.1
Clean Air Act: This product contains the followir^ chemical substances listed as Hazardous Air Pollutants (HAPs) under the Clean Air Act of
1990:
Chemical Name
TOLUENE
HAP Category
CAS Number
108-88-3
WT %
9.6
7"oxicSu6sfanc9sCon/ro/Acf: All the components of Uiis product comply with applicable requrements of the US EPA TSCA inventory.
Contains the following chemical(s) subject to the reporting requirements of TSCA 12b if exported from Uie US.
None Known.
U.S. STATE REGULATIONS: A s follows California Proposition 65: WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or
other reproductive harm.
INTERNATIONAL REGULATIONS: A s follows Canadian WHMIS Class: B2 D2A
CPRC: This product has been classified in accordance with Uie hazard criteria of the ConUolled Product Regulations and the MSDS contains
all of the information required by the Controlled Product Regulations.
Canadian DSL - All the components of this pmduct are listed or are exempt from listing.
European EINECS - All Uie components of this product are listed or are exempt from listing.
Austalian AICS - The status of one or more components of this product is not known.
16. Other Information
National Paint & Coatings Assodation (NPCA) Hazardous Material Identification System (HMIS):
Health: 3
Flammability: 3
Reactivity: 1
Personal Protection: See Section 8
Lagand: N.A. - Not Applicable, N.D. - Not Dotorminod
FOR PROFESSIONAL USE ONLY
IMPORTANT NOTE The information in this data sheet is not intended to be exhaustive and is based on the present state of our knowledge
and on current laws: any person using the product for any purpose oUier than that spectflcally recommended in the lechnical data ^ e e t
without first obtaining written confirmation from us as to the suitability of the product for the intended purpose does so at his own risk. It is
always the responsibility of the user to take all necessary steps to fulfill the demands set out in Uie local rules and legislation. Always read the
Material Oata Sheet and the Technical Data Sheet for this product if available. All advice we give or any statement made about the product by
us (whether In this data sheet or othenwise) is correct to the best of our knowledge but we have no control over the quality or the condition of
the substrate or the many factors affecting the use and applicaflon ofthe product. Therefore, unless we specifically agree in writing otherwise,
we do not accept any liability whatsoever for the performance of the product or for any loss or damage arising out of the use of the product. All
products supplied and technical advice given are subject to our standard terms and conditions of sale. You should request a copy of this
document and review It carefully. The infomnation contained in this data sheet is subjeci to modification from time to time in the light of
experience and our polk:y of continuous development. It Is the user's responsibility to verify that this dala sheet is current prior to using ttie
product.
Brand names mentioned in this dala sheet are trademarks of or are licensed to AkzoNobel.
Head Office
AkzoNobel Aerospace Coalings, a division of Intemational Paint LLC, 1 East Water Slreet, Waukegan, IL 60085, USA.
www.akzonobel.com/aerospace
Revision Date: 06/30/2010
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I NPCA Label Statements
WARNINGI Flammable liquid and vapor. Vapor harmful. Harmful if inhaled. Harmful if swallowed.
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous syslem
damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Causes aye irritation. Causes skin
imtation. Causes nose and throat imtation. Vapor harmful. May affect Uie brain or nervous system causing dizziness, headache or nausea.
Overexposure may cause lung and kidney damage. Cancer hazard. Contains ingredients which can cause cancer. (Risk of cancer depends
on duration and level of exposure.)
Firsl Aid: In case of eye contact, flush immediately wiUi plenty of water for at least 15 minutes and get medical attention immediately; for skin,
wash thoroughly wiUi soap and water. If you experience difficulty in breathing, leave Uie area to obtain fresh air. If continued difficulty is
experienced, get medical attention immediately. If swallowed, do not induce vomiting. Get medical attention immedialely.
Vapors may cause flash fire. Keep away from heat, sparks and flame. Do not smoke. Extinguish all flames and pilot lights, and turn off stoves
& ovens, heaters, electric motors and other sources of ignition during use and until all vapors are gone. Use only with adequate ventilation.
Preveni build-up of vapors by opening att windows and doors to achieve cross-ventilation. Ensure fresh air entry during appicali'on and drying.
If you experience eye watering, headache or dizziness or if air monitoring demonstrates vapor/mist levels are atiove applicable limits, wear an
appropriate, properiy fitted respirator (NIOSH approved) during and after application. Follow respirator manufacturer's directions for respirator
use. Close container after each use. Do not get in eyes, on skin or clothing. Do not breathe vapors. Wadh Uioroughly afler handling, FOR
INDUSTRIAL USE ONLY.
If spilled, contain spilled material and remove wKh inert absorbent. Dispose of contaminated absorbent, container and unused contenls in
accordance with local, state and federal regulations.
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