MATERIAL SAFETY DATA SHEET 1000326190 MSDS

2016-10-06

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Revision Date: July 22, 2015
Revision Number: 5 supersedes 4
Page 1 of 7
SAFETY DATA SHEET
1. Identification of the substance/mixture and of the company
1.1 Product identifier
Product Name:
Type P7
™
Penetrating Oil Aerosol
Product ID numbers: P7-12, P7-12LA, P7M
1.2 Relevant identified uses of the mixture and uses advised against
Identified uses:
Lubricating Oil and Corrosion Inhibitor
List of advices against:
Not applicable.
1.3 Details of the supplier of the safety data sheet
Supplier/Manufacturer:
American Polywater Corporation
11222 - 60th Street North
Stillwater, MN 55082 USA
Tel: 1-651-430-2270
Email: sds@polywater.com
Polywater Europe BV
Zuidhaven 9-11 Unit B2
4761 CR Zevenbergen
Netherlands
Tel: +31 (0)10 2330578
Email: sds@ polywater.com
1.4 Emergency telephone numbers
INFOTRAC 1-352-323-3500 (USA)
2. Hazards Identification
Flam Aerosol 1
H222, H229
Gas under pressure, liquefied gas
H280
Asp. Tox. 1
H304
Skin Irrit. 2
H315
Eye Irrit. 2A
H319
guidelines listed below. It is safe for consumers and other users under normal and reasonably foreseeable
Pictograms:
Signal word:
Danger
H222
Extremely flammable aerosol
H229
Pressurized container: May burst if heated.
H280
Contains gas under pressure; may explode if heated
H315
Causes skin irritation
H319
Causes serious eye irritation
Product Name: Type P7™ Penetrating Oil Aerosol Revision Date: July 22, 2015
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P210
Keep away from sparks, flames and hot surfaces. No smoking.
P211
Do not spray on an open flame or other ignition source.
P251
Do not pierce or burn, even after use.
P303 + P361 +
P353
IF ON SKIN: Take off immediately all contaminated clothing. Rinse skin with water.
P305 + P351 +
P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
P410 + P412
Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F
P501
Dispose of contents/container in accordance with local/regional/national/international
regulations.
Notes:
Aspiration classification not applied due to the physical form of the product.
2.3 Other hazards:
No information available.
3. Composition/Information on Ingredients
Component
CAS #
EC #
Wt. %
GHS/CLP Classification
Solvent naphtha (petroleum),
medium aliphatic
64742-88-7
265-191-7
25-50
Flam Liq 3 H226;
Acute Tox. 4 H302
Distillates (petroleum),
hydrotreated heavy naphthenic
64742-52-5
265-155-0
25-50
Carc. 1B H350
Barium petroleum sulfonate
61790-48-5
263-140-3
10-25
Skin Irrit. 2 H315;
Eye Irrit. 2A H319
2-Butoxyethanol
111-76-2
203-905-0
2.5-10
Acute Tox. 4 H302, H312, H332;
Skin Irrit. 2 H315;
Eye Irrit. 2 H319
Propane
74-98-6
200-827-9
Propellant,
<15%
Isobutane
75-28-5
200-857-2
Propellant,
<15%
4. First Aid Measures
4.1 Description of first aid measures
Eye Contact:
If eye irritation from exposure to vapors develops, move to fresh air. Flush eyes
with clean water. If irritation persists, seek medical attention. For direct eye
contact, flush with large quantity of water for 15 minutes. Seek medical attention.
Skin Contact:
Remove contaminated clothing; flush skin thoroughly with water. If irritation
occurs, seek medical attention.
Inhalation (Breathing):
If irritation of nose or throat develops, move to fresh air. If irritation persists, seek
medical attention. If breathing is difficult, provide oxygen. If not breathing, give
artificial respiration. Seek immediate medical attention.
Ingestion (Swallowing):
Do not induce vomiting or give anything by mouth. If victim is drowsy or
unconscious, place on the left side with head down. Do not leave victim
unattended. Seek medical attention.
4.2 Most important symptoms and effects, both acute and delayed
Refer to Section 11 for more information.
4.3 Indication of immediate medical attention and special treatment needed.
Aspiration hazard. If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. This
route not expected in aerosol package.
5. Firefighting Measures
5.1 Extinguishing media:
Carbon dioxide, sand, dry chemical or foam. Do not use water.
Product Name: Type P7™ Penetrating Oil Aerosol Revision Date: July 22, 2015
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5.2 Special hazards arising from the substance or mixture
Hazardous decomposition and by-products:
Burning generates CO, CO2 and smoke. Smoke may be acrid and fumes irritating.
5.3 Advice for firefighters
Wear appropriate, protective clothing, including self-contained, positive pressure or pressure-demand
breathing apparatus. Sealed container can build up pressure when exposed to high heat. Use water spray to
cool fire exposed containers. Aerosol cans can build up pressure and explode when exposed to temperatures
greater than 120°F (49°C).
6. Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures:
Keep away from heat/sparks/open flames/hot surfaces. No smoking. For a spill in a confined space, provide
mechanical ventilation to disperse or exhaust vapors. For emergency responders: use respiratory protection:
half-face or full-face respirator with filter(s) for organic vapor for spills in a confined space. Chemical goggles
are recommended if splashes or contact with eyes is possible. For small spills: normal antistatic work clothes
are usually adequate.
6.2 Environmental precautions:
Avoid release to the environment. Dyke the spill to prevent entry into waterways, sewers, basements or
confined areas.
6.3 Methods materials for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid m=binders, universal binders, sawdust). Dispose
contaminated material according to local and national regulations. Ensure adequate ventilation. Do not flush
with water or aqueous cleansing agents.
6.4 Reference to other sections:
Refer to Sections 4, 5, 8, and 13 for more information.
7. Handling and Storage
7.1 Precautions for safe handling
Extremely flammable aerosol. Keep containers cool, dry, and away from sources of ignition. Do not expose
container to direct sunlight or temperatures above 50°C/122°F. Do not transport or store near heat sources.
No smoking. Avoid breathing vapors or spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or
smoke when using this product. Wash thoroughly after handling. Wash contaminated clothing before reuse.
Use only outdoors or in a well-ventilated area. For industrial or professional use only.
7.2 Conditions for safe storage, including incompatibilities
Do not transport or store near heat sources. Keep cans dry and away from sources of ignition. Do not
puncture or incinerate container. Store this product with adequate ventilation.
7.3 Specific end uses
See technical data sheet on this product for further information.
8. Exposure Controls / Personal Protection
8.1 Control parameters
Exposure limits and recommendations:
Component Name
Limit
Standard
Source/Note
Medium Aliphatic Petroleum Solvent
100 ppm
ACGIH TWA
United States
Medium Aliphatic Petroleum Solvent
500 ppm
OSHA TWA
United States
Medium Aliphatic Petroleum Solvent
1200 mg/m3
RCP* TWA
ACGIH, Manufacturer
*reciprocal
calculation
procedure for total
hydrocarbons
2-Butoxy Ethanol
240 mg/m3,
50 ppm
PEL, Skin
Product Name: Type P7™ Penetrating Oil Aerosol Revision Date: July 22, 2015
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2-Butoxy Ethanol
24 mg/m3,
5 ppm
REL, Skin
8.2 Exposure controls
Respiratory protection:
If exposure exceeds recommended limits, respirator protection is recommended. Use a respirator or gas
mask with cartridges for organic vapors (NIOSH-approved) or use supplied air equipment.
Protective gloves:
Use of impermeable, resistant gloves is recommended.
Eye protection:
Eye protection is recommended, especially if the material is used in ways where it could spray or mist into the
eyes.
Other protective equipment:
It is suggested that a source of clean water be available in work area for flushing eyes and skin. Impervious
clothing should be worn as needed.
9. Physical and Chemical
9.1 Information of basic physical and chemical properties (bulk liquid)
Appearance:
Clear, light to amber liquid with mild hydrocarbon odor.
Odor threshold:
Not available
pH:
Does not apply
Freezing point:
Not available
Boiling point:
307°F / 153°C
Flash point:
106°F / 41°C
(- 100°F / - 74°C - estimated for propellant, lowest flashing component)
Evaporation rate:
Not available
Flammability (solid, gas):
Not applicable to liquids
Upper/lower flammability or
explosive limits:
LEL: 0.6%
UEL: 6.5%
Vapor pressure:
6.6 hPa (5 mmHg) @20°C
Vapor density (Air = 1):
Not available
Specific gravity (H2O = 1):
Not available
Solubility in water:
Not miscible
Coefficient of Water/Oil
Distribution:
Not available
Ignition temperature
509 °F / 265 °C
Auto-ignition temperature:
Product is not self-igniting
Decomposition temperature:
Not available
Viscosity:
Not available
9.2 Other Information
Volatiles (Weight %):
49.3%
10. Stability and Reactivity
10.1 Reactivity:
See remaining headings in Section 10.
10.2 Chemical stability:
Stable
10.3 Possibility of hazardous reactions:
None known.
10.4 Conditions to avoid:
Product Name: Type P7™ Penetrating Oil Aerosol Revision Date: July 22, 2015
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Avoid heat, flame, and sparks.
10.5 Incompatible materials :
No further information available.
10.6 Hazardous decomposition products:
Carbon dioxide, carbon monoxide.
11. Toxicological Information
11.1 Information on toxicological effects:
Acute toxicity
Eye contact:
Direct eye contact may cause eye irritation. This irritation is minimal and expected to be transient.
Skin contact:
Prolonged or repeated skin exposure can remove oils, causing redness, drying and cracking. Persons with
pre-existing skin disorders may be more susceptible to skin irritation from this material.
Irritation and Sensitization Potential:
Product may be irritating to skin and eyes. It is not a sensitizer.
Inhalation (Breathing):
Concentrated solvent vapors may cause irritation of the nose and throat. Prolonged exposure to excessively
high vapor concentrations can result in central nervous system depression (e.g., drowsiness, dizziness, loss
of coordination, and fatigue.
Ingestion:
Ingestion of large quantities may cause irritation of the digestive tract, nervous system depression (e.g.,
drowsiness, dizziness, loss of coordination, and fatigue).
Toxicity to Animals:
Solvent naphtha (petroleum),
medium aliphatic
LD50 (oral rat) >6500 mg/kg
LD50 (dermal rabbit) >3000 mg/kg
LC50 (inhl rat) >14 mg/l, 4 hours
Alkyltriazole
LD50 (oral rat) 675 mg/kg
Chronic Exposure:
Reproductive Toxicity:
Not classified as a reproductive system toxin.
Mutagenicity:
Not classified as a mutagen.
Teratogenicity:
Not classified as teratogenic or embryotoxic.
Specific Target Organ
Toxicity (STOT)
No end point data.
Toxicologically Synergistic
Products:
Not available.
Carcinogenic Status:
Contains 2-Butoxy Ethanol, listed Group 3, Not Classifiable by IARC. This
substance contains no other components identified as a carcinogen or
probable carcinogen by NTP, IARC, or OSHA.
12. Ecological Information
12.1 Toxicity:
Ecotoxicity:
No information available.
12.2 Persistence and degradability:
No information available
12.3 Bioaccumulation potential:
No information available
12.4 Mobility in soil:
No information available
12.5 Results of PBT and vPvB
Assessment:
This product is not, nor does it contain a substance that is a
PBT or vPvB.
12.6 Other adverse effects:
None known.
Product Name: Type P7™ Penetrating Oil Aerosol Revision Date: July 22, 2015
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13. Disposal Considerations
Dispose of product in accordance with National and Local Regulations.
14. Transport Information
UN Number:
1950
UN Proper shipping name:
AEROSOLS, Flammable, less than 1 liter each, Class 2.1, LTD QTY
Transport hazard class(es):
Class 9
Packing group:
Not Applicable
Environmental hazards:
None known
Special precautions:
None known
TDG:
Not Regulated
ICAO/IATA-DGR:
Consumer Commodity, ID 8000, Class 9, LTD QTY
IMDG:
UN 1950, AEROSOLS, Flammable, less than 1 liter each, Class 2.1, LTD
QTY
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
USA Federal and State
All components are listed on the TSCA inventory.
Hazard Categories for SARA
Section 311/312 Reporting
Acute
Chronic
Fire
Pressure
Reactive
Yes
No
Yes
No
No
CERCLA/SARA Sec 302
SARA Sec. 313
Toxic Release
Components
Hazardous Substance RQ
EHS TPQ
Barium petroleum sulfonate (CAS 61790-48-5)
1%
Components are not affected by these Superfund regulations.
NFPA Ratings:
Health:
1
Fire:
3
Reactivity:
0
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel
during spill, fire or similar emergencies. Hazard ratings are based on physical and toxic properties of combustion or
decomposition.
European Union
All components are listed on the European Inventory of Existing Chemical Substances (EINECS).
Product complies with the communication requirements of REACH Regulation (EC) No. 1907/2006. It does not
contain Substances of Very High Concern (SVHC).
Canada
All components are listed on the DSL inventory.
This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
WHMIS Classification:
B5
Australia
All components are listed on the AICS.
Hazardous according to criteria of NOHSC Australia.
15.2 Chemical Safety Assessment
Product Name: Type P7™ Penetrating Oil Aerosol Revision Date: July 22, 2015
Page 7 of 7
No chemical safety assessment has been carried out for the mixture by the supplier.
16. Other Information
Abbreviations and acronyms:
OSHA = Occupational Safety and Health Administration
CLP = Classification, Labeling and Packaging Regulation
STOT = Specific Target Organ Toxicity
LD50 = Median Lethal Dose
DNEL = Derived No Effect Level
ACGIH = American Conference of Governmental Industrial Hygienists
TSCA = Toxic Substances Control Act (USA)
DSL = Domestic Substances List (Canada)
AICS = Australian Inventory of Chemical Substances
Revision Date:
July 22, 2015
Revision Number:
5
Supersedes:
May 22, 2015
Other:
Not Applicable
Indication of Changes:
Section 2.2 Label elements updated (gas under pressure).
Updated precaution statements in accordance with the provisions of OSHA 1910.1200
App D and REACH Annex II (EU No 453/2010). (GHS format)
The information and recommendations contained herein are believed to be reliable. However, the supplier makes
no warranties, express or implied, concerning the use of this product. The buyer must determine conditions of safe
usage and assumes all risk and liability in handling this product.

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