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Common Name: CRYSTAL SIMPLE GREEN
Manufacturer: SUNSHINE MAKERS
MSDS Revision Date: 8/1/2006

Grainger Item Number(s): 3UP37, 3UP38, 3UP39, 3UP40
Manufacturer Model Number(s):

MSDS Table of Contents
Click the desired link below to jump directly to that section in the MSDS.
I. PRODUCT & COMPANY INFORMATION
II. INGREDIENT INFORMATION
III. HAZARDS IDENTIFICATION
IV. FIRST AID MEASURES
V. FIRE FIGHTING MEASURES
VI. ACCIDENTAL RELEASE MEASURES
VII. HANDLING, STORAGE & TRANSPORT INFORMATION
VIII. EXPOSURE CONTROLS
IX. PERSONAL PROTECTION
X. PHYSICAL AND CHEMICAL PROPERTIES
XI. STABILITY AND REACTIVITY INFORMATION
XII. TOXICOLOGICAL INFORMATION
XIII. BIODEGRADABILITY AND ENVIRONMENTAL TOXICITY INFORMATION
XIV. DISPOSAL CONSIDERATIONS
XV. OTHER INFORMATION

MATERIAL SAFETY DATA SHEET: CRYSTAL SIMPLE GREEN(R*)
ALSO FOR: SIMPLE GREEN(R*) SAFETY TOWELS
VERSION NO.: 4013
ISSUE DATE: AUGUST 2006

I. PRODUCT & COMPANY INFORMATION

PRODUCT NAME: CRYSTAL SIMPLE GREEN(R*)
OTHER NAMES:
CRYSTAL SIMPLE GREEN(R*) - SPECIALIZED CLEANER / DEGREASER
SIMPLE GREEN(R*) SAFETY TOWELS (FLUID ONLY)
COMPANY NAME:
SUNSHINE MAKERS, INC.
15922 PACIFIC COAST HIGHWAY
HUNTINGTON HARBOUR, CA 92649
USA
TELEPHONE:
800-228-0709

562-795-6000
FAX: 562-592-3034
FOR 24-HOUR EMERGENCY, CALL CHEM-TEL, INC.: 800-255-3924
WEBSITE: WWW.SIMPLEGREEN.COM
USE OF PRODUCT:
A SPECIALIZED CLEANER AND DEGREASER FOR USE IN THE INDUSTRIAL AND
INSTITUTIONAL WORKPLACE. (SIMPLE GREEN(R*) SAFETY TOWELS CONTAIN DILUTED
CRYSTAL SIMPLE GREEN(R*).)

II. INGREDIENT INFORMATION

THE ONLY INGREDIENT OF CRYSTAL SIMPLE GREEN(R*) WITH ESTABLISHED EXPOSURE
LIMITS IS UNDILUTED 2-BUTOXYETHANOL (<6%) (BUTYL) CELLOSOLVE; CAS NO.
111-76-2: THE ACGIH TLV-TWA IS: 20 PPM (97 MG/M3.)
THE QUANTITY OF 2-BUTOXYETHANOL IN SIMPLE GREEN SAFETY TOWELS IS <1%.
BASED UPON CHEMICAL ANALYSIS, CRYSTAL SIMPLE GREEN(R*) CONTAINS NO KNOWN EPA
PRIORITY POLLUTANTS, HEAVY METALS, OR CHEMICALS LISTED UNDER RCRA, CERCLA,
OR CWA. ANALYSIS BY TCLP (TOXICITY CHARACTERISTIC LEACHING PROCEDURE)
ACCORDING TO RCRA REVEALED NO TOXIC ORGANIC OR INORGANIC CONSTITUENTS.
ALL COMPONENTS OF CRYSTAL SIMPLE GREEN(R*) ARE LISTED ON THE TSCA CHEMICAL
SUBSTANCE INVENTORY.

III. HAZARDS IDENTIFICATION

UN NUMBER: NOT REQUIRED
DANGEROUS GOODS CLASS: NONHAZARDOUS
NJ TRADE SECRET REGISTRATION NUMBERS:
80100235-5000P
80100235-5001P
80100235-5002P
80100235-5003P
80100235-5004P
80100235-5005P
80100235-5006P
80100235-5007P
80100235-5008P
80100235-5009P
HAZARD RATING (NFPA/HMIS):
HEALTH
1*
REACTIVITY 0
FIRE
0
SPECIAL
0
NFPA:
1
0
0
0
RATING SCALE:
0 = MINIMAL
1 = SLIGHT

2 = MODERATE
3 = SERIOUS
4 = SEVERE
*MILD EYE IRRITANT, NON-MUTAGENIC AND NON-CARCINOGENIC. NONE OF THE
INGREDIENTS IN CRYSTAL SIMPLE GREEN(R*) ARE REGULATED OR LISTED AS CANCER
AGENTS BY FEDERAL OSHA, NTP, OR IARC.

IV. FIRST AID MEASURES

SYMPTOMS OF OVEREXPOSURE AND FIRST AID TREATMENT:
EYE CONTACT:
REDDENING MAY DEVELOP. IMMEDIATELY RINSE THE EYE WITH LARGE QUANTITIES OF
COOL WATER; CONTINUE 10-15 MINUTES OR UNTIL THE MATERIAL HAS BEEN REMOVED;
BE SURE TO REMOVE CONTACT LENSES, IF PRESENT, AND TO LIFT UPPER AND LOWER
LIDS DURING RINSING. GET MEDICAL ATTENTION IF IRRITATION PERSISTS.
SKIN CONTACT:
MINIMAL EFFECTS, IF ANY; RINSE SKIN WITH WATER, RINSE SHOES AND LAUNDER
CLOTHING BEFORE REUSE. REVERSIBLE REDDENING MAY OCCUR IN SOME
DERMAL-SENSITIVE USERS; THOROUGHLY RINSE AREA AND GET MEDICAL ATTENTION IF
REACTION PERSISTS.
SWALLOWING:
ESSENTIALLY NON-TOXIC. GIVE SEVERAL GLASSES OF WATER TO DILUTE; DO NOT
INDUCE VOMITING. IF STOMACH UPSET OCCURS, CONSULT PHYSICIAN.
INHALATION:
NON-TOXIC. EXPOSURES TO CONCENTRATE-MIST MAY CAUSE MILD IRRITATION OF NASAL
PASSAGES OR THROAT; REMOVE TO FRESH AIR. GET MEDICAL ATTENTION IF IRRITATION
PERSISTS.

V. FIRE FIGHTING MEASURES

CRYSTAL SIMPLE GREEN(R*) IS STABLE, NOT FLAMMABLE, AND WILL NOT BURN.
FLASH POINT/AUTO-IGNITION: NOT FLAMMABLE.
FLAMMABILITY LIMITS: NOT FLAMMABLE.
EXTINGUISHING MEDIA:
NOT FLAMMABLE/NONEXPLOSIVE. NO SPECIAL PROCEDURES REQUIRED.
SPECIAL FIRE FIGHTING PROCEDURES: NONE REQUIRED.

VI. ACCIDENTAL RELEASE MEASURES

RECOVER USABLE MATERIAL BY CONVENIENT METHOD; RESIDUAL MAY BE REMOVED BY
WIPE OR WET MOP. IF NECESSARY, UNRECOVERABLE MATERIAL MAY BE WASHED TO DRAIN
WITH LARGE QUANTITIES OF WATER.

VII. HANDLING, STORAGE & TRANSPORT INFORMATION

NO SPECIAL PRECAUTIONS ARE REQUIRED. THIS PRODUCT IS NON-HAZARDOUS FOR
STORAGE AND TRANSPORT ACCORDING TO THE U.S. DEPARTMENT OF TRANSPORTATION
REGULATIONS. CRYSTAL SIMPLE GREEN(R*) REQUIRES NO SPECIAL LABELING OR

PLACARDING TO MEET U.S. DEPARTMENT OF TRANSPORTATION REQUIREMENTS.
UN NUMBER: NOT REQUIRED
DANGEROUS GOODS CLASS: NONHAZARDOUS

VIII. EXPOSURE CONTROLS

EXPOSURE LIMITS:
THE CRYSTAL SIMPLE GREEN(R*) FORMULATION PRESENTS NO HEALTH HAZARDS TO THE
USER WHEN USED ACCORDING TO LABEL DIRECTIONS FOR ITS INTENDED PURPOSES. MILD
SKIN AND EYE IRRITATION IS POSSIBLE (PLEASE SEE EYE CONTACT AND SKIN CONTACT
IN SECTION IV.).
VENTILATION:
NO SPECIAL VENTILATION IS REQUIRED DURING USE. LARGE-SCALE USES INDOORS
SHOULD PROVIDE AN INCREASED RATE OF AIR EXCHANGE.
HUMAN HEALTH EFFECTS OR RISKS FROM EXPOSURE:
ADVERSE EFFECTS ON HUMAN HEALTH ARE NOT EXPECTED FROM CRYSTAL SIMPLE
GREEN(R*), BASED UPON TWENTY YEARS OF USE OF SIMPLE GREEN WITHOUT REPORTED
ADVERSE HEALTH INCIDENCE IN DIVERSE POPULATION GROUPS, INCLUDING EXTENSIVE
USE BY INMATES OF U.S. FEDERAL PRISONS IN CLEANING OPERATIONS.
CRYSTAL SIMPLE GREEN(R*) IS A MILD EYE IRRITANT; MUCOUS MEMBRANES MAY BECOME
IRRITATED BY CONCENTRATE-MIST.
CRYSTAL SIMPLE GREEN(R*) IS NOT LIKELY TO IRRITATE THE SKIN IN THE MAJORITY
OF USERS. REPEATED DAILY APPLICATION TO THE SKIN WITHOUT RINSING, OR
CONTINUOUS CONTACT OF CRYSTAL SIMPLE GREEN(R*) ON THE SKIN MAY LEAD TO
TEMPORARY, BUT REVERSIBLE, IRRITATION.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
NO AGGRAVATION OF EXISTING MEDICAL CONDITIONS IS EXPECTED; DERMAL-SENSITIVE
USERS MAY REACT TO DERMAL CONTACT BY CRYSTAL SIMPLE GREEN(R*).

IX. PERSONAL PROTECTION

PRECAUTIONARY MEASURES: NO SPECIAL REQUIREMENTS UNDER NORMAL USE CONDITIONS.
EYE PROTECTION:
CAUTION, INCLUDING REASONABLE EYE PROTECTION, SHOULD ALWAYS BE USED TO AVOID
EYE CONTACT WHERE SPLASHING MAY OCCUR.
SKIN PROTECTION:
NO SPECIAL PRECAUTIONS REQUIRED; RINSE COMPLETELY FROM SKIN AFTER CONTACT.
RESPIRATORY PROTECTION:
NO SPECIAL PRECAUTIONS REQUIRED EXCEPT DURING LARGE-SCALE SPRAY APPLICATIONS
WHERE SPRAY MIST LEVELS ARE HIGH.
WORK AND HYGIENIC PRACTICES:
WASH OR RINSE HANDS BEFORE TOUCHING EYES OR CONTACT LENSES. FOLLOW STANDARD
HYGIENIC PRACTICES FOR HANDLING CLEANING AGENTS.

X. PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE/ODOR: CLEAR LIQUID
SPECIFIC GRAVITY: 1.020

pH OF CONCENTRATE: 9.35
EVAPORATION: >1 (BUTYL ACETATE = 1)
BOILING POINT: 100.6 DEG. C (212 DEG. F )
FREEZING POINT: -9 DEG. C (16 DEG. F)
IF PRODUCT FREEZES, IT WILL RECONSTITUTE WITHOUT LOSS OF EFFICACY WHEN
BROUGHT BACK TO ROOM TEMPERATURE AND AGITATED.
VAPOR PRESSURE:
18 MMHg @ 20 DEG. C
23.5 MMHg @ 26 DEG. C
VAPOR DENSITY: 1.3 (AIR = 1)
DENSITY: 8.5 LBS./GALLON
VOC COMPOSITE PARTIAL PRESSURE: 0 MMHg @ 20 DEG. C
VOLATILE ORGANIC COMPOUNDS (VOCS):
0 G/L PER ASTM METHOD 3960-90. PER EPA METHOD 24, VOCS ARE 5.9% AND PRODUCT
MUST BE DILUTED AT LEAST 1 PART OF WATER TO 1 PART SIMPLE GREEN(R*) IN ORDER
TO MEET CARB 2005 VOC REGULATIONS - OR 1 PART SIMPLE GREEN TO 3 PARTS WATER
TO MEET SCAQMD RULE 1171 & RULE 1122 AND BAAQMD REGULATION 8-16 VOC
REQUIREMENTS FOR SOLVENT CLEANING OPERATIONS.
SAFETY TOWEL VOCS: PER EPA METHOD 24, VOCS ARE 0.5%.
SAFETY TOWEL pH: 8.1 - 8.8
WATER SOLUBILITY: CRYSTAL SIMPLE GREEN(R*) IS COMPLETELY SOLUBLE IN WATER.
DETECTION:
CRYSTAL SIMPLE GREEN(R*) AND SIMPLE GREEN(R*) SAFETY TOWELS HAVE A
CHARACTERISTIC ODOR THAT IS NOT INDICATIVE OF ANY HAZARDOUS SITUATION.

XI. STABILITY AND REACTIVITY INFORMATION

NONREACTIVE. CRYSTAL SIMPLE GREEN(R*) IS STABLE, EVEN UNDER FIRE CONDITIONS,
AND WILL NOT REACT WITH WATER OR OXIDIZERS. HAZARDOUS POLYMERIZATION WILL
NOT OCCUR.

XII. TOXICOLOGICAL INFORMATION

THE INFORMATION AND CONCLUSIONS CITED IN THIS SECTION ARE BASED ON DATA AND
TESTING OF SIMPLE GREEN(R*). THE DATA ARE DIRECTLY APPLICABLE TO CRYSTAL
SIMPLE GREEN(R*) BECAUSE BOTH FORMULATIONS ARE VIRTUALLY IDENTICAL, EXCEPT
FOR FRAGRANCE AND COLOR.
NONHUMAN TOXICITY:
ACUTE MORTALITY STUDIES:
ORAL LD50 (RAT): >5.0 G/KG BODY WEIGHT
DERMAL LD50 (RABBIT): >2.0 G/KG BODY WEIGHT
DERMAL IRRITATION:
ONLY MILD, BUT REVERSIBLE, IRRITATION WAS FOUND IN A STANDARD 72-HR TEST ON
RABBITS. A VALUE OF 0.2 (NON-IRRITATING) WAS FOUND ON A SCALE OF 8.
EYE IRRITATION:

WITH OR WITHOUT RINSING WITH WATER, THE IRRITATION SCORES IN RABBITS AT 24
HOURS DID NOT EXCEED 15 (MILD IRRITANT) ON A SCALE OF 110.
SUBCHRONIC DERMAL EFFECTS:
NO ADVERSE EFFECTS, EXCEPT REVERSIBLE DERMAL IRRITATION, WERE FOUND IN
RABBITS EXPOSED TO SIMPLE GREEN(R*) (UP TO 2.0 G/KG/DAY FOR 13 WEEKS)
APPLIED TO THE SKIN OF 25 MALES AND 25 FEMALES. ONLY FEMALE BODY WEIGHT GAIN
WAS AFFECTED. DETAILED MICROSCOPIC EXAMINATION OF ALL MAJOR TISSUES SHOWED
NO ADVERSE CHANGES.
FERTILITY ASSESSMENT BY CONTINUOUS BREEDING:
THE SIMPLE GREEN(R*) FORMULATION HAD NO ADVERSE EFFECT ON FERTILITY AND
REPRODUCTION IN CD-1 MICE WITH CONTINUOUS ADMINISTRATION FOR 18 WEEKS, AND
HAD NO ADVERSE EFFECT ON THE REPRODUCTIVE PERFORMANCE OF THEIR OFFSPRING.

XIII. BIODEGRADABILITY AND ENVIRONMENTAL TOXICITY INFORMATION

BIODEGRADABILITY:
LIKE SIMPLE GREEN(R*), CRYSTAL SIMPLE GREEN(R*) IS READILY DECOMPOSED BY
NATURALLY OCCURRING MICROORGANISMS. THE BIOLOGICAL OXYGEN DEMAND (BOD), AS A
PERCENTAGE OF THE CHEMICAL OXYGEN DEMAND (COD), AFTER 4, 7, AND 11 DAYS WAS
56%, 60%, AND 70%, RESPECTIVELY. PER OECD CLOSED BOTTLE TEST, CRYSTAL SIMPLE
GREEN(R*) MEETS OECD AND EPA RECOMMENDATIONS FOR READY BIODEGRADABILITY.
IN A STANDARD BIODEGRADATION TEST WITH SOILS FROM THREE DIFFERENT COUNTRIES,
BUTYL CELLOSOLVE REACHED 50% DEGRADATION IN 6 TO 23 DAYS, DEPENDING UPON
SOIL TYPE, AND EXCEEDED THE RATE OF DEGRADATION FOR GLUCOSE, WHICH WAS USED
AS A CONTROL FOR COMPARISON.
ENVIRONMENTAL TOXICITY INFORMATION:
CRYSTAL SIMPLE GREEN(R*) IS CONSIDERED PRACTICALLY NON-TOXIC PER EPA'S
AQUATIC TOXICITY SCALE.

XIV. DISPOSAL CONSIDERATIONS

CRYSTAL SIMPLE GREEN(R*) IS FULLY WATER SOLUBLE AND BIODEGRADABLE AND WILL
NOT HARM SEWAGE-TREATMENT MICROORGANISMS IF DISPOSAL BY SEWER OR DRAIN IS
NECESSARY. DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE, AND
FEDERAL LAWS.

XV. OTHER INFORMATION

CONTAINERS:
CRYSTAL SIMPLE GREEN(R*) RESIDUES CAN BE COMPLETELY REMOVED BY RINSING WITH
WATER; THE CONTAINER MAY BE RECYCLED OR APPLIED TO OTHER USES.
CONTACT POINT:
SUNSHINE MAKERS, INC., RESEARCH AND DEVELOPMENT DIVISION: 562-795-6000.
NATIONAL STOCK NUMBERS:
PART#

NSN

SIZE

19024

7930-01-418-1151

24 OZ. SPRAY (12/CS)

19128

7930-01-418-1152

1 GAL. (6/CS)

19005

7930-01-418-1153

5 GAL.

19055

7930-01-418-1155

55 GAL.

SIMPLE GREEN SAFETY TOWEL PART NUMBERS:
PART #

SIZE

13353

5-COUNT POUCH (50/CS)

13351

75-COUNT CANISTER (6/CS)

NOTICE:
ALL INFORMATION APPEARING HEREIN IS BASED UPON DATA OBTAINED BY THE
MANUFACTURER AND RECOGNIZED TECHNICAL SOURCES. JUDGMENTS AS TO THE
SUITABILITY OF INFORMATION HEREIN FOR PURCHASER'S PURPOSES ARE NECESSARILY
PURCHASER'S RESPONSIBILITY. THEREFORE, ALTHOUGH REASONABLE CARE HAS BEEN
TAKEN IN THE PREPARATION OF THIS INFORMATION, SUNSHINE MAKERS, INC. OR ITS
DISTRIBUTORS EXTENDS NO WARRANTIES, MAKES NO REPRESENTATIONS AND ASSUMES NO
RESPONSIBILITY AS TO THE SUITABILITY OF SUCH INFORMATION FOR APPLICATION TO
PURCHASER'S INTENDED PURPOSES OR FOR CONSEQUENCES OF ITS USE.



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