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41.1.0 352162 Page 1/10 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Printing date 31.07.2015 Revision: 31.07.2015 SECTION 1: Identification of the substance/mixture and of the company/ undertaking · 1.1 Product identifier · Trade name: Moldstat Coating Clear v.1 · Article number: 100356 · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Biocide Coating · 1.3 Details of the supplier of the Safety Data Sheet · Manufacturer/Supplier: Theochem Laboratories 7373 Rowlett Park Drive Tampa, FL 33610 Phone: 813-237-6463 · 1.4 Emergency telephone number: ChemTel Inc. (800)255-3924, +1 (813)248-0585 SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 The following Hazard Statements are applicable only according to OSHA regulations within the United States. These Statements are not applicable for the CLP regulation (1272/2008/EC) in the EU: H360. Repr. 1 H360: May damage fertility or the unborn child health hazard Muta. 1B H340 May cause genetic defects. · Additional information: There are no other hazards not otherwise classified that have been identified. 0 % of the mixture consists of component(s) of unknown toxicity. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS08 · Signal word Danger · Hazard-determining components of labelling: carbendazim (ISO) (Cont'd. on page 2) 41.1.0 Safety Data Sheet Page 2/10 according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Printing date 31.07.2015 Revision: 31.07.2015 Trade name: Moldstat Coating Clear v.1 (Cont'd. from page 1) · Hazard statements The following Hazard Statements are applicable only according to OSHA regulations within the United States. These Statements are not applicable for the CLP regulation (1272/2008/EC) in the EU: H360. H360 May damage fertility or the unborn child. H340 May cause genetic defects. · Precautionary statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P280 Wear protective gloves/protective clothing/eye protection. P308+P313 IF exposed or concerned: Get medical advice/attention. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Additional information: Restricted to professional users. · NFPA ratings (scale 0 - 4) 0 0 Health = 0 Fire = 0 Reactivity = 0 0 · HMIS-ratings (scale 0 - 4) HEALTH 0 FIRE 0 REACTIVITY 0 Health = 0 Fire = 0 Reactivity = 0 * - Indicates a long term health hazard from repeated or prolonged exposures. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: Mixture of substances listed below with nonhazardous additions. · Dangerous components: CAS: 10605-21-7 carbendazim (ISO) < 1% EINECS: 234-232-0 Muta. 1B, H340; Repr. 1B, H360FD Index number: 613-048-00-8 Aquatic Acute 1, H400; Aquatic Chronic 1, H410 · Additional information: For the listed ingredient(s), the identity and exact percentages are being withheld as a trade secret. SECTION 4: First aid measures · 4.1 Description of first aid measures · After inhalation: Supply fresh air; consult doctor in case of complaints. (Cont'd. on page 3) 41.1.0 Page 3/10 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Printing date 31.07.2015 Revision: 31.07.2015 Trade name: Moldstat Coating Clear v.1 (Cont'd. from page 2) · After skin contact: Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. · After eye contact: Remove contact lenses if worn. Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting; call for medical help immediately. · 4.2 Most important symptoms and effects, both acute and delayed Headache Dizziness Breathing difficulty Nausea · Hazards Danger of impaired breathing. Danger of disturbed cardiac rhythm. · 4.3 Indication of any immediate medical attention and special treatment needed Monitor circulation, possible shock treatment. If necessary oxygen respiration treatment. Medical supervision for at least 48 hours. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · For safety reasons unsuitable extinguishing agents: Water with full jet · 5.2 Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit. · Additional information Cool endangered receptacles with water spray. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation · 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water. Prevent from spreading (e.g. by damming-in or oil barriers). Inform respective authorities in case of seepage into water course or sewage system. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. (Cont'd. on page 4) 41.1.0 Page 4/10 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Printing date 31.07.2015 Revision: 31.07.2015 Trade name: Moldstat Coating Clear v.1 Send for recovery or disposal in suitable receptacles. Dispose contaminated material as waste according to section 13. · 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. (Cont'd. from page 3) SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Keep receptacles tightly sealed. · Information about fire - and explosion protection: Keep respiratory protective device available. · 7.2 Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Avoid storage near extreme heat, ignition sources or open flame. · Information about storage in one common storage facility: Store away from foodstuffs. Do not store together with oxidising and acidic materials. · Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. · 7.3 Specific end use(s) No further relevant information available. SECTION 8: Exposure controls/personal protection · Additional information about design of technical facilities: No further data; see section 7. · 8.1 Control parameters · Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · DNELs No further relevant information available. · PNECs No further relevant information available. · Additional information: The lists valid during the making were used as basis. · 8.2 Exposure controls · Personal protective equipment: · General protective and hygienic measures: The usual precautionary measures are to be adhered to when handling chemicals. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes and skin. Do not inhale gases / fumes / aerosols. Pregnant women should strictly avoid inhalation or skin contact. (Cont'd. on page 5) 41.1.0 Page 5/10 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Printing date 31.07.2015 Revision: 31.07.2015 Trade name: Moldstat Coating Clear v.1 · Respiratory protection: Not required under normal conditions of use. Use suitable respiratory protective device in case of insufficient ventilation. Use suitable respiratory protective device when aerosol or mist is formed. For spills, respiratory protection may be advisable. · Protection of hands: (Cont'd. from page 4) Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. · Eye protection: Safety glasses · Body protection: Protective work clothing · Limitation and supervision of exposure into the environment No further relevant information available. · Risk management measures See Section 7 for additional information. No further relevant information available. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Liquid Colour: Whitish · Odour: Acrid · Odour threshold: Not determined. · pH-value at 20 °C (68 °F): 7,0 - 8,0 · Change in condition Melting point/Melting range: Boiling point/Boiling range: Not Determined. Undetermined. · Flash point: Not applicable. · Flammability (solid, gaseous): Not applicable. · Auto/Self-ignition temperature: Not determined. · Decomposition temperature: Not determined. · Self-igniting: Product is not self-igniting. · Danger of explosion: Product does not present an explosion hazard. (Cont'd. on page 6) 41.1.0 Page 6/10 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Printing date 31.07.2015 Revision: 31.07.2015 Trade name: Moldstat Coating Clear v.1 (Cont'd. from page 5) · Explosion limits: Lower: Upper: Not determined. Not determined. · Vapour pressure at 20 °C (68 °F): 23 hPa (17 mm Hg) · Density at 20 °C (68 °F): · Relative density · Vapour density · Evaporation rate 1,02 - 1,03 g/cm³ (8,512 - 8,595 lbs/gal) Not determined. Not determined. Not determined. · Solubility in / Miscibility with water: Dispersible. · Partition coefficient (n-octanol/water): Not determined. · Viscosity: Dynamic: Kinematic: · 9.2 Other information Not determined. Not determined. No further relevant information available. SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications. · 10.3 Possibility of hazardous reactions Reacts with strong acids. Reacts with strong oxidising agents. Toxic fumes may be released if heated above the decomposition point. · 10.4 Conditions to avoid Keep ignition sources away - Do not smoke. Store away from oxidising agents. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: Carbon monoxide and carbon dioxide Aldehyde Nitrogen oxides (NOx) SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity · LD/LC50 values relevant for classification: None. · Primary irritant effect: · Skin corrosion/irritation Based on available data, the classification criteria are not met. · Serious eye damage/irritation Based on available data, the classification criteria are not met. (Cont'd. on page 7) 41.1.0 Safety Data Sheet Page 7/10 according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Printing date 31.07.2015 Revision: 31.07.2015 Trade name: Moldstat Coating Clear v.1 (Cont'd. from page 6) · Respiratory or skin sensitisation Based on available data, the classification criteria are not met. · Additional toxicological information: May cause genetic defects. · Acute effects (acute toxicity, irritation and corrosivity): The product can cause inheritable damage. · Repeated dose toxicity: May cause damage to organs through prolonged or repeated exposure. Danger of very serious irreversible effects. · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction): · Germ cell mutagenicity May cause genetic defects. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: The product contains materials that are harmful to the environment. · 12.2 Persistence and degradability The product is partially biodegradable. Significant residuals remain. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Ecotoxical effects: · Remark: Due to mechanical actions of the product (e.g. agglutinations) damages may occur. Inhibition of the growth rate · Additional ecological information: · General notes: Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water This statement was deduced from the properties of the single components. Harmful to aquatic organisms · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. Can be burned with household garbage after consulting with the waste disposal facility operator and the pertinent authorities and adhering to the necessary technical regulations. The user of this material has the responsibility to dispose of unused material, residues and containers in compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and disposal for hazardous and nonhazardous wastes. Residual materials should be treated as hazardous. (Cont'd. on page 8) 41.1.0 Page 8/10 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Printing date 31.07.2015 Revision: 31.07.2015 Trade name: Moldstat Coating Clear v.1 (Cont'd. from page 7) · Uncleaned packaging: · Recommendation: Disposal must be made according to local official regulations. · Recommended cleansing agents: Water, if necessary together with cleansing agents. SECTION 14: Transport information · 14.1 UN-Number · DOT, ADR, IMDG, IATA · 14.2 UN proper shipping name · DOT, ADR, IMDG, IATA · 14.3 Transport hazard class(es) Not Regulated Not Regulated · DOT, ADR, ADN, IMDG, IATA · Class Not Regulated · 14.4 Packing group · DOT, ADR, IMDG, IATA Not Regulated · 14.5 Environmental hazards: · Marine pollutant: No · 14.6 Special precautions for user Not applicable. · 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. · UN "Model Regulation": Not Regulated SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · United States (USA) · SARA · Section 355 (extremely hazardous substances): None of the ingredients are listed. · Section 313 (Specific toxic chemical listings): None of the ingredients are listed. · TSCA (Toxic Substances Control Act): All ingredients are listed. · Proposition 65 (California): · Chemicals known to cause cancer: Present in trace quantities. 75-07-0 acetaldehyde 140-88-5 ethyl acrylate 123-91-1 1,4-dioxane · Chemicals known to cause reproductive toxicity for females: None of the ingredients are listed. (Cont'd. on page 9) 41.1.0 Page 9/10 Safety Data Sheet according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Printing date 31.07.2015 Revision: 31.07.2015 Trade name: Moldstat Coating Clear v.1 (Cont'd. from page 8) · Chemicals known to cause reproductive toxicity for males: None of the ingredients are listed. · Chemicals known to cause developmental toxicity: None of the ingredients are listed. · Carcinogenic Categories · EPA (Environmental Protection Agency) None of the ingredients are listed. · IARC (International Agency for Research on Cancer) None of the ingredients are listed. · TLV (Threshold Limit Value established by ACGIH) None of the ingredients are listed. · NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients are listed. · Canada · Canadian Domestic Substances List (DSL) All ingredients are listed. · Canadian Ingredient Disclosure list (limit 0.1%) None of the ingredients are listed. · Canadian Ingredient Disclosure list (limit 1%) None of the ingredients are listed. · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients are listed. · National regulations: · Other regulations, limitations and prohibitive regulations · Substances of very high concern (SVHC) according to REACH, Article 57 None of the ingredients are listed. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H340 May cause genetic defects. H360FD May damage fertility. May damage the unborn child. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. (Cont'd. on page 10) 41.1.0 Safety Data Sheet Page 10/10 according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA GHS Printing date 31.07.2015 Revision: 31.07.2015 Trade name: Moldstat Coating Clear v.1 (Cont'd. from page 9) · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) DNEL: Derived No-Effect Level (REACH) PNEC: Predicted No-Effect Concentration (REACH) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic SVHC: Substances of Very High Concern vPvB: very Persistent and very Bioaccumulative Muta. 1B: Germ cell mutagenicity, Hazard Category 1B Repr. 1B: Reproductive toxicity, Hazard Category 1B Aquatic Acute 1: Hazardous to the aquatic environment - AcuteHazard, Category 1 Aquatic Chronic 1: Hazardous to the aquatic environment - Chronic Hazard, Category 1 · Sources SDS Prepared by: ChemTel Inc. 1305 North Florida Avenue Tampa, Florida USA 33602-2902 Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573 Website: www.chemtelinc.com