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362252 SAFETY DATA SHEET 1. Identification Product identifier Sulfuric Acid .12N Product code R-0009 Recommended use Use as directed by manufacturer for purposes directly related to water testing. Recommended restrictions None known Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name Taylor Technologies, Inc. Address 31 Loveton Circle Sparks, MD 21152 United States Telephone (410) 472-4340 Website www.taylortechnologies.com E-mail Not available Monday─Friday, 8:00 a.m.–4:30 p.m. Emergency phone number (800) 837-8548 2. Hazard(s) identification Physical hazards Corrosive to metals Category 1 Health hazards Eye damage/irritation Category 1 Skin corrosion/irritation Category 1C Specific target organ toxicity, single exposure Category 3 respiratory tract irritation Environmental hazards Not currently regulated by OSHA; refer to section 12 of the SDS for additional information. Label elements Signal word Danger Hazard statement May be corrosive to metals. Causes severe skin burns and eye damage. May cause respiratory irritation. Precautionary statement Prevention Keep only in original container. Do not breathe mist or vapor. Wash skin thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Response Absorb spillage to prevent material damage. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (OR HAIR): Take off immediately all contaminated clothing. Rinse skin with water. Wash contaminated clothing before reuse. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Immediately call a physician or poison control center. Storage Store locked up. Store in a corrosive-resistant container with a corrosive resistant liner. Material name: Sulfuric Acid .12N; R-0009 SDS U.S. Page 1 of 10 Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified May cause pulmonary edema (fluid accumulation). Symptoms of pulmonary edema (chest pain, shortness of breath) may be delayed. Ingestion may produce burns to the lips, oral cavity, upper airway, esophagus, and possibly the digestive tract. Supplemental information None 3. Composition/information on ingredients Mixtures Chemical name Deionized water Common name and synonyms Dihydrogen oxide Hydrogen sulfate; Oil of vitriol Sulfuric acid CAS number 7732-18-5 % 95–99 7664-93-9 0.1–5 4. First-aid measures Inhalation Move to fresh air. Give oxygen or artificial respiration if needed. Get medical attention immediately. Skin contact Immediately flush skin with running water for at least 20 minutes. Immediately take off all contaminated clothing. Call a physician or poison control center immediately. Chemical burns must be treated by a physician. Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 20 minutes. Remove contact lenses if present and easy to do. Continue rinsing. Call a physician or poison control center immediately. Ingestion Call a physician or poison control center immediately. Rinse mouth. Never give anything by mouth to a person who is unconscious or is having convulsions. Do NOT induce vomiting unless directed by physician. If vomiting occurs, keep head low so that stomach content does not get into the lungs. Most important symptoms/effects, acute and delayed Direct skin contact may cause corrosive skin burns, deep ulcerations, and possibly permanent scarring. Direct contact with concentrated solutions may be corrosive to the eyes and may cause severe damage, including blindness. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Inhalation of mists can cause severe respiratory irritation. Symptoms may include coughing, choking, and wheezing. Inhalation could result in pulmonary edema (fluid accumulation). Symptoms of pulmonary edema (chest pain, shortness of breath) may be delayed. Indication of immediate medical attention and special treatment needed General information Ingestion may produce burns to the lips, oral cavity, upper airway, esophagus, and possibly the digestive tract. Symptoms may include abdominal pain, vomiting, burns, perforations, bleeding. Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep person under observation. Symptoms may be delayed. Ensure medical personnel are aware of the material(s) involved and take precautions to protect themselves. 5. Firefighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Firefighting equipment/instructions Firefighters should wear full protective gear. Evacuate the area promptly. Fight fire from upwind to avoid exposure to combustion products. Cool containers/tanks with water spray. Do not get water inside container. Move containers from fire area if it can be done without risk. Prevent fireextinguishing water from contaminating surface water or the ground water system. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards Not combustible; however, the product can react with metals to form flammable and explosive hydrogen gas. Material name: Sulfuric Acid .12N; R-0009 SDS U.S. Page 2 of 10 Hazardous combustion products Sulfur oxides. Other irritating fumes and smoke. 6. Accidental release measures Personal precautions, protective equipment, and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during cleanup. Do not breathe mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protective equipment, refer to section 8 of the SDS. Methods and materials for containment and cleaning up This product is miscible in water. Large Spills: Dike the spilled material where this is possible. Stop leak if it can be done without risk. Absorb spillage to prevent material damage. Absorb in vermiculite, dry sand or earth, and place into containers. Prevent entry into waterways, sewer, basements, or confined areas. Following product recovery, flush area with water. Small Spills: Absorb spillage with noncombustible, absorbent material. Clean surface thoroughly to remove residual contamination. Never return spills to original containers for reuse. For waste disposal, refer to section 13 of the SDS. Dilute acid with water and neutralize with dilute base. If not recoverable, dilute with water or flush to holding area and neutralize. Contaminated absorbent material may pose the same hazards as the spilled product. In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. Environmental precautions Avoid discharge into drains, watercourses, or onto the ground. 7. Handling and storage Precautions for safe handling Do not breathe mist or vapor. Do not get in eyes, on skin, or on clothing. Do not taste or swallow. Avoid prolonged exposure. Provide adequate ventilation. Wear appropriate personal protective equipment. For personal protective equipment, refer to section 8 of the SDS. Keep away from metals and other incompatibles. Observe good industrial hygiene practices. Label containers appropriately. Conditions for safe storage, including any incompatibilities Store locked up. Store in corrosive-resistant container with a corrosive-resistant inner liner. Store in original tightly closed container. Keep only in the original container. Store in a cool, dry place out of direct sunlight. Store away from incompatible materials (refer to section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits U.S. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Sulfuric acid (CAS 7664-93-9) PEL Value 3 1 mg/m Form Not applicable U.S. ACGIH Threshold Limit Values Components Sulfuric acid (CAS 7664-93-9) Value 3 0.2 mg/m Form Thoracic fraction Value 3 1 mg/m Form Not applicable Type TWA U.S. NIOSH: Pocket Guide to Chemical Hazards Components Type Sulfuric acid (CAS 7664-93-9) TWA Biological limit values No biological exposure limits noted for the ingredient(s) Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eyewash facilities and emergency shower must be available when handling this product. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles) and a face shield. Provide an emergency eyewash fountain and quick-drench shower in the immediate work area. Skin protection Hand protection Wear appropriate chemical-resistant gloves. Advice should be sought from glove suppliers. Other Wear appropriate chemical-resistant clothing. Material name: Sulfuric Acid .12N; R-0009 SDS U.S. Page 3 of 10 Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. Use a NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fumes at levels exceeding the exposure limits. Advice should be sought from respiratory protection suppliers. Thermal hazards When necessary, wear appropriate thermal protective clothing. General hygiene considerations Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking and/or smoking. Routinely wash work clothing and protective equipment to remove contamination. 9. Physical and chemical properties Appearance Physical state Liquid Form Liquid Color Clear colorless or nearly colorless Odor Odorless Odor threshold Not available pH 1.3 Melting point/freezing point Not available Initial boiling point and boiling range 212°F (100°C) Flash point Not applicable (does not burn) Evaporation rate Not available Flammability (solid, gas) Not applicable Upper/lower flammability or explosive limits Flammability limit, lower (%) Not applicable Flammability limit, upper (%) Not applicable Explosive limit, lower (%) Not applicable Explosive limit, upper (%) Not applicable Vapor pressure 17 mm Hg Vapor density 0.6 Relative density 1.00 g/cm 3 Solubility(ies) Solubility (water) Soluble in all proportions Partition coefficient (n-octanol/water) Not available Auto-ignition temperature Not applicable Decomposition temperature Not available Viscosity Not available Other information Explosive properties Not applicable Oxidizing properties Not applicable Percent volatile 100% Specific gravity 1.00 10. Stability and reactivity Reactivity This product is stable and nonreactive under normal conditions of use, storage, transport. Chemical stability Material is stable under normal conditions. Decomposes at ~ 644°F (340°C) to form sulfur trioxide. Material name: Sulfuric Acid .12N; R-0009 SDS U.S. Page 4 of 10 Possibility of hazardous reactions No dangerous reaction known under conditions of normal use Conditions to avoid Contact with incompatible materials. Direct sunlight. Do not use in areas without adequate ventilation. Incompatible materials Metal compounds. Nitromethane. Oxidizing agents. Sugars. Hazardous decomposition products None known. For hazardous combustion products, refer to section 5 of the SDS. 11. Toxicological information Information on likely routes of exposure Inhalation May cause irritation to the respiratory system Skin contact Causes severe skin burns Eye contact Causes serious eye damage Ingestion Causes digestive tract burns Most important symptoms/effects, acute and delayed Direct skin contact may cause corrosive skin burns, deep ulcerations, and possibly permanent scarring. Direct contact with concentrated solutions may be corrosive to the eyes and may cause severe damage, including blindness. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Inhalation of mists can cause severe respiratory irritation. Symptoms may include coughing, choking, and wheezing. Inhalation could result in pulmonary edema (fluid accumulation). Symptoms of pulmonary edema (chest pain, shortness of breath) may be delayed. Ingestion may produce burns to the lips, oral cavity, upper airway, esophagus, and possibly the digestive tract. Symptoms may include abdominal pain, vomiting, burns, perforations, bleeding. Acute toxicity This product is not classified as an acute toxicity hazard. See below for individual ingredient acute toxicity data. Components Sulfuric acid (CAS 7664-93-9) Species Test Results Rabbit Not available Rat 0.375 mg/L, 4 hours (mist) Rat 2140 mg/kg Rabbit Not available Rat Not available Rat >89840 mg/kg Acute Dermal LD50 Inhalation LC50 Oral LD50 Deionized water (CAS 7732-18-5) Acute Dermal LD50 Inhalation LC50 Oral LD50 Skin corrosion/irritation Causes severe skin burns and eye damage Serious eye damage/eye irritation Causes serious eye damage Respiratory sensitization Not expected to be a respiratory sensitizer Skin sensitization Not expected to be a skin sensitizer Germ cell mutagenicity Not expected to be mutagenic Material name: Sulfuric Acid .12N; R-0009 SDS U.S. Page 5 of 10 Carcinogenicity This product is not considered to be a carcinogen by IARC, NTP, OSHA, or U.S. ACGIH. Occupational exposure to strong inorganic acid mists containing sulfuric acid is carcinogenic to humans. The information located is insufficient to conclude that sulfuric acid itself is a carcinogen. IARC has concluded there is sufficient evidence that occupational exposure to strong inorganic acid mists containing sulfuric acid is carcinogenic to humans (Group 1). ACGIH has designated strong inorganic acid mists containing sulfuric acid as A2 (suspected human carcinogen). US NTP has listed strong inorganic acid mists containing sulfuric acid as a known human carcinogen. These classifications are for inorganic acid mists containing sulfuric acid and do not apply to sulfuric acid or sulfuric acid solutions. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1096) Not regulated Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity, single exposure May cause respiratory irritation Specific target organ toxicity, repeated exposure Not classified as a specific target organ toxicity – repeated exposure Aspiration toxicity Not expected to be an aspiration hazard Chronic effects Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. 12. Ecological information Ecotoxicity This product is not classified as environmentally hazardous; however, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Components Species Sulfuric acid (CAS 7664-93-9) – Aquatic Test Results Acute Algae EC50 Green algae (Pseudokirchneriella subcapitata) >100 mg/L, 72 hours Water flea (Daphnia magna) 29 mg/L, 24 hours Bluegill (Lepomis macrochirus) 16–28 mg/L, 96 hours Crustacea EC50 Fish LC50 Persistence and degradability Not available Bioaccumulative potential Not available Mobility in soil High water solubility indicates a high mobility in soil. Other adverse effects No other adverse environmental effects (e.g., ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose of in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose of in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion with the user, the producer, and the waste disposal company. Waste from residues/unused products Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (refer to Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste-handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transportation information DOT UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk UN3264 Corrosive liquid, acidic, inorganic, N.O.S. (Sulphuric acid) 8 Not listed Material name: Sulfuric Acid .12N; R-0009 SDS U.S. Page 6 of 10 Label(s) Packing group Special precautions for user Special provisions Packaging exceptions Packaging, non-bulk Packaging, bulk IATA UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Packing group Environmental hazards ERG code Special precautions for user Other information Passenger and cargo aircraft Cargo aircraft only IMDG UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Packing group Environmental hazards Marine pollutant EmS Special precautions for user 8 III Read safety instructions, SDS, and emergency procedures before handling. IB3, T7, TP1, TP28 154 203 241 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code This substance/mixture is not intended to be transported in bulk. UN3264 Corrosive liquid, acidic, inorganic, N.O.S. (Sulphuric acid) 8 Not listed III Not listed 8L Read safety instructions, SDS, and emergency procedures before handling. Allowed Allowed UN3264 Corrosive liquid, acidic, inorganic, N.O.S. (Sulphuric acid) 8 Not listed III Not listed F-A, S-B Read safety instructions, SDS, and emergency procedures before handling. DOT IATA; IMDG 15. Regulatory information U.S. federal regulations This product is a “Hazardous Chemical” as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory list. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated Material name: Sulfuric Acid .12N; R-0009 SDS U.S. Page 7 of 10 CERCLA Hazardous Substance (40 CFR 302.4) Sulfuric acid (CAS 7664-93-9) SARA 304 Emergency Release Notification Sulfuric acid (CAS 7664-93-9) 1000 lb. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1096) Not regulated Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate hazard ─ yes Delayed hazard ─ no Fire hazard – no Pressure hazard ─ no Reactivity hazard – yes SARA 302 Extremely Hazardous Substance Chemical name CAS number Reportable quantity (lb.) Threshold planning quantity (lb.) Threshold planning quantity lower value Threshold planning quantity upper value Sulfuric acid 7664-93-9 1000 1000 Not applicable Not applicable SARA 311/312 Hazardous Chemical Not listed SARA 313 (TRI reporting) Chemical name CAS number % by weight Sulfuric acid 7664-93-9 0.1–5 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) Not regulated Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Sulfuric acid (CAS 7664-93-9) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Sulfuric acid (CAS 7664-93-9) 6552 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Sulfuric acid (CAS 7664-93-9) 20% W/V DEA Exempt Chemical Mixtures Code Number Sulfuric acid (CAS 7664-93-9) Safe Drinking Water Act (SDWA) 6552 Not regulated U.S. state regulations California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not regulated Massachusetts Right-to-Know Act Sulfuric acid (CAS 7664-93-9) New Jersey Worker and Community Right-to-Know Act Sulfuric acid (CAS 7664-93-9) Pennsylvania Worker and Community Right-to-Know Act Sulfuric acid (CAS 7664-93-9) Rhode Island Right-to-Know Act Sulfuric acid (CAS 7664-93-9) California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. California Proposition 65 - CRT: Listed date/carcinogenic substance Sulfuric acid (CAS 7664-93-9) Material name: Sulfuric Acid .12N; R-0009 This product is not an inorganic acid mist containing sulfuric acid; therefore, the Proposition 65 statement does not apply. SDS U.S. Page 8 of 10 International inventories Country(ies) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) yes Canada Domestic Substances List (DSL) yes Canada Non-Domestic Substances List (NDSL) no China Inventory of Existing Chemical Substances Produced or Imported in China (IECSC) yes Europe European Inventory of Existing Commercial Chemical Substances (EINECS) yes Europe European List of Notified Chemical Substances (ELINCS) no Japan Existing and New Chemical Substances (ENCS) yes Korea Existing Chemicals List (ECL) yes New Zealand New Zealand Inventory of Chemicals (NZIoC) yes Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) yes United States & Puerto Rico Toxic Substances Control Act (TSCA) yes *A “yes” indicates that all components of this product comply with the inventory requirements administered by the governing country(ies). A “no” indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(ies). 16. Other information, including date of preparation or last revision List of abbreviations ACGIH: American Conference of Governmental Industrial Hygienists AICS: Australian Inventory of Chemical Substances CAA: Clean Air Act CAS: Chemical Abstract Services CERCLA: Comprehensive Environmental Response, Compensation, and Liability Act CFR: Code of Federal Regulations CSA: Canadian Standards Association DEA: Drug Enforcement Agency DOT: Department of Transportation DSL: Domestic Substances List EC: effective concentration ECL: Existing Chemicals List EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances ENCS: Existing and New Chemical Substances EPA: Environmental Protection Agency HAP: hazardous air pollutants HMIS: Hazardous Materials Identification System HNOC: hazards not otherwise classified HPA: Hazardous Products Act HSDB: Hazardous Substances Data Bank IARC: International Agency for Research on Cancer IATA: International Air Transport Association IBC Code: International Code for the Construction and Equipment of Ships Carrying Dangerous Chemicals in Bulk ICAO: International Civil Aviation Organization IECSC: Inventory of Existing Chemical Substances Produced or Imported in China IMDG: International Maritime Dangerous Goods IUCLID: International Uniform Chemical Information Database LC: lethal concentration LD: lethal dose MARPOL: marine pollution MSHA: Mine Safety and Health Administration NDSL: Non-Domestic Substances List NFPA: National Fire Protection Association NIOSH: National Institute of Occupational Safety and Health NOEC: no observable effect concentration NTP: National Toxicology Program NZIoC: New Zealand Inventory of Chemicals OECD: Organisation for Economic Co-operation and Development OEL: occupational exposure limits OSHA: Occupational Safety and Health Administration PEL: permissible exposure limits Material name: Sulfuric Acid .12N; R-0009 SDS U.S. Page 9 of 10 PICCS: Philippine Inventory of Chemicals and Chemical Substances PPE: personal protective equipment RCRA: Resource Conservation and Recovery Act RQ: reportable quantity RTECS: Registry of Toxic Effects of Chemical Substances RTK: right to know SARA: Superfund Amendments and Reauthorization Act SDS: Safety Data Sheet SDWA: Safe Drinking Water Act STEL: short-term exposure limit TLV: threshold limit values TSCA: Toxic Substances Control Act TWA: time-weighted average VOC: volatile organic compounds WEL: workplace exposure limit Disclaimer The information in the Safety Data Sheet is offered for your consideration and guidance for safe handling, use, storage, transportation, disposal, and release of this product and is not considered a warranty or quality specification. Taylor Technologies, Inc., disclaims all expressed or implied warranties and assumes no responsibility for the accuracy of completeness of the data contained herein. The data in this SDS does not apply to use with any other product or in any other process. Issue date License granted to make unlimited paper copies for internal use only. This Safety Data Sheet may not be changed, or altered, in any way without the expressed knowledge and permission of Taylor Technologies, Inc. The information contained in this sheet is based on lab experience and the most current data available. April 2015 Last revision April 2015 Material name: Sulfuric Acid .12N; R-0009 SDS U.S. Page 10 of 10
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