456053
2016-12-28
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456053 Safety Data Sheet Issue Date: 18-Sep-2013 Revision Date: 18-Jun-2014 Version 1 1. IDENTIFICATION Product Identifier Product Name Pre-mixed Tile Grout Other means of identification SDS # RD-0022PTG Product Code 0420, 0422, 0424, 0425, 0428 (incl. 438 Sq. Tube) Series Recommended use of the chemical and restrictions on use Recommended Use A premium, acrylic latex based, water-resistant compound for grouting ceramic & mosaic tile. Details of the supplier of the safety data sheet Supplier Address Red Devil, Inc. 4175 Webb Street Pryor, Oklahoma 74361 www.reddevil.com Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr) 918-825-5744 Fax: 918-825-5761 INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America) 2. HAZARDS IDENTIFICATION Appearance White paste Physical State Paste Odor Mild Acrylic/slight ammoniacal Classification This chemical does not meet the hazardous criteria set forth by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). However, this Safety Data Sheet (SDS) contains valuable information critical to the safe handling and proper use of this product. This SDS should be retained and available for employees and other users of this product. _____________________________________________________________________________________________ Page 1 / 10 Revision Date: 18-Jun-2014 RD-0022PTG - Pre-mixed Tile Grout _____________________________________________________________________________________________ 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Calcium Carbonate Acrylic Emulsion Non-hazardous Ingredients* Titanium Dioxide Soda lime borosilicate glass Propylene Glycol Ammonium Hydroxide Petroleum Hydrocarbon CAS No 1317-65-3 MIXTURE Proprietary 13463-67-7 65997-17-3 57-55-6 7664-41-7 64742-48-9 Weight-% <70 <25 <5 <2 <1 <1 <0.15 <1 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** * Unlisted ingredients are not considered hazardous under the OSHA Hazard Communication Standard (29 CFR 1910.1200). (Calcium Carbonate, Titanium Dioxide and Soda lime borosilicate glass) Inhalation of particulates unlikely due to product ’s physical state. 4. FIRST-AID MEASURES First Aid Measures General Advice Provide this SDS to medical personnel for treatment. Eye Contact Immediately flush with large quantities of water for at least 15 minutes until irritation subsides. Get medical attention. Skin Contact Wash w/ soap & water for @ least 15 minutes. Get medical attention if symptoms persist. Remove & wash contaminated clothing. Inhalation Remove to fresh air. If breathing is difficult, leave area to obtain fresh air. If breathing remains difficult, get medical attention. Ingestion Do not induce vomiting unless directed by medical personnel. If vomiting occurs, lean patient forward to maintain an open airway & prevent aspiration. Get immediate medical attention. Most important symptoms and effects Symptoms Prolonged or repeated skin contact may result in dermatitis (red, dry skin). Direct contact with eyes may cause temporary irritation. Exposed individuals may experience eye tearing, redness and discomfort. Irritating to mouth, throat, and stomach if ingested. May cause gastrointestinal irritation, nausea, diarrhea, and vomiting. Overexposure to vapors during application and curing may mildly irritate respiratory tract and result in coughing and sneezing. Indication of any immediate medical attention and special treatment needed Notes to Physician Medical Conditions Aggravated by Exposure: Asthma & asthma -like conditions may worsen from prolonged or repeated exposure to dust, should sanding be performed. _____________________________________________________________________________________________ Page 2 / 10 Revision Date: 18-Jun-2014 RD-0022PTG - Pre-mixed Tile Grout _____________________________________________________________________________________________ 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Carbon dioxide (CO2). Dry chemical. Water spray (fog). Foam. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Product is combustible & may ignite if exposed to high temperature or direct flame. Hazardous Combustion Products Carbon oxides. Nitrogen oxides (NOx). Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Use water spray to keep fire-exposed containers cool. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Wear protective clothing as described in Section 8 of this safety data sheet. Other Information Small Spills: 1 drum or less – Level D Equipment (gloves, chemical resistant apron, boots & eye protection). Large Spills: Rubber gloves, rubber boots, face shield & Tyvek suit as a minimum. Minimum level of PPE for releases in which the oxygen level is < 19.5% or is unknown, should be Level B: triple gloves (rubber gloves & nitrile gloves over latex gloves), chemical resistant suit, fire-retardant clothing & boots, hard hat & self-contained breathing apparatus. For Emergency Responders Restrict access to spill area. Environmental Precautions Minimize use of water to prevent environmental contamination. Prevent spill or rinse from contaminating storm drains, sewers, soil or groundwater. Do not allow discharge containing this material to enter streams, ponds, estuaries, oceans or other waters un less in accordance w/ requirements of National Pollutant Discharge Elimination System (NPDES) permit & permitting authority has been notified in writing prior to discharge. Do not allow discharge containing this material to enter sewer systems w/o previous ly notifying local sewage treatment plant authority. For information, contact State Water Board or EPA Regional Office Other: U.S. regulations may require reporting of spills of this material reaching surface waters if sheen is formed. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Use absorbent material to contain spill. Methods for Clean-Up Sweep up absorbed material and shovel into suitable containers for disposal. Wash area with soap and water. For waste disposal, see section 13 of the SDS. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Keep out of reach of children & pets. Do not take internally. Do not breathe vapors or dust. If dry sanding use NIOSH-approved dust mask. Use only w/ adequate ventilation. Wash thoroughly after handling. Avoid contact w/ eyes, skin & clothing. Open windows & doors to ensure cross-ventilation & fresh air during application & curing. Do not eat or drink while handling this material. In event of spill – see Section 6. _____________________________________________________________________________________________ Page 3 / 10 Revision Date: 18-Jun-2014 RD-0022PTG - Pre-mixed Tile Grout _____________________________________________________________________________________________ Conditions for safe storage, including any incompatibilities Storage Conditions Stable under normal conditions of handling, use & storage. Store containers in a cool, dry location, away from direct sunlight & high temperatures. Protect from freezing. Store away from incompatible materials (caustics & oxidizers). Close container after each use & keep tightly closed when not in use. To maximize shelf life, store @ temperatures below 26C (80F). Incompatible Materials Strong bases. Oxidizing agents. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Exposure guidelines / protective equipment are for routine handling and accidental spills Chem ical Nam e Calcium Carbonate 1317-65-3 ACGIH TLV - Titanium Dioxide 13463-67-7 TWA: 10 mg/m3 Soda lime borosilicate glass 65997-17-3 Ammonium Hydroxide 7664-41-7 TWA: 1 fiber/cm3 respirable fibers: length >5 µm, aspect ratio >=3:1, as determined by the membrane filter method at 400-450X magnification [4-mm objective], using phase-contrast illumination TWA: 5 mg/m3 inhalable fraction STEL: 35 ppm TWA: 25 ppm Petroleum Hydrocarbon 64742-48-9 ACGIH TWA: 5 mg/m3; ACGIH STEL: 10 mg/m3 OSHA PEL NIOSH IDLH TWA: 15 mg/m3 total dust TWA: 10 mg/m3 total dust TWA: 5 mg/m3 respirable TWA: 5 mg/m3 respirable dust fraction (vacated) TWA: 15 mg/m3 total dust (vacated) TWA: 5 mg/m3 respirable fraction TWA: 15 mg/m3 total dust IDLH: 5000 mg/m3 (vacated) TWA: 10 mg/m3 total dust - TWA: 50 ppm TWA: 35 mg/m3 (vacated) STEL: 35 ppm (vacated) STEL: 27 mg/m3 - IDLH: 300 ppm TWA: 25 ppm TWA: 18 mg/m3 STEL: 35 ppm STEL: 27 mg/m3 - Appropriate engineering controls Engineering Controls Ventilation must be adequate to maintain the ambient workplace atmosphere below the exposure limit(s) outlined in the SDS. Provide appropriate local exhaust ventilation if material is to be sanded. _____________________________________________________________________________________________ Page 4 / 10 Revision Date: 18-Jun-2014 RD-0022PTG - Pre-mixed Tile Grout _____________________________________________________________________________________________ Individual protection measures, such as personal protective equipment Eye/Face Protection Use approved safety goggles or safety glasses. If necessary, refer to appropriate regulations & standards. Skin and Body Protection Skin: Wear chemical res istant rubber gloves for repeated or prolonged use. Body: Not required w/ normal use. Respiratory Protection Avoid breathing of dust. Avoid breathing of vapors, mists or spray. If concentrations exceed exposure limits specified, use a NIOSH-approved supplied air respirator. If protection factor exceeded, use self contained breathing apparatus (SCBA). A respiratory protection program that exceeds OSHA 1910.134 & ANSI Z88.2 requirements should be followed when conditions warrant respirator use. If dry sanding preferred, use approved NIOSH/OSHA respirator. General Hygiene Considerations Wash hands w/ soap & water before breaks & @ end of workday. Remove & wash contaminated clothing prior to re-use. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Appearance Paste White paste Odor Color White Odor Threshold Property Note: The information below is not intended for use in preparing product specifications 7.0-10.0 ~ 0 °C / ~32 °F Not established > 93.33 °C / > 200 °F Not determined Not determined Unknown Unknown Not established Heavier than air ~1.5-2.00 Soluble in water Not determined Not determined Not determined Not determined Not determined Not determined Not determined Not determined <1.5% < 40 g/L Remarks • Method pH Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties VOC Content (%) VOC Content Mild Acrylic/slight ammoniacal Not determined Ceta Closed Cup @ 25 °C (77 °F) 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. _____________________________________________________________________________________________ Page 5 / 10 Revision Date: 18-Jun-2014 RD-0022PTG - Pre-mixed Tile Grout _____________________________________________________________________________________________ Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to Avoid Incompatible Materials. Excessive heat or cold. Incompatible Materials Strong bases. Oxidizing agents. Hazardous Decomposition Products Carbon oxides. Nitrogen oxides (NOx). 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact Eye contact may result in tearing, redness & pain. Skin Contact Prolonged and frequent contact may cause redness and irritation. Repeated skin contact may cause dermatitis. Inhalation Overexposure to vapors during application & curing may mildly irritate respiratory tract & result in coughing & sneezing. Ingestion May cause gastrointestinal irritation, nausea, diarrhea, and vomiting. Component Information Chem ical Nam e Titanium Dioxide 13463-67-7 Propylene Glycol 57-55-6 Ammonium Hydroxide 7664-41-7 Petroleum Hydrocarbon 64742-48-9 Oral LD50 > 10000 mg/kg ( Rat ) Derm al LD50 - Inhalation LC50 - = 20000 mg/kg ( Rat ) = 20800 mg/kg ( Rabbit ) - = 350 mg/kg ( Rat ) - > 5000 mg/kg ( Rat ) > 3160 mg/kg ( Rabbit ) = 5.1 mg/L ( Rat ) 1 h = 2000 ppm ( Rat ) 4 h - Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. _____________________________________________________________________________________________ Page 6 / 10 Revision Date: 18-Jun-2014 RD-0022PTG - Pre-mixed Tile Grout _____________________________________________________________________________________________ Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization Not known to be human skin or respiratory sensitizers. Carcinogenicity Titanium dioxide is a possible carcinogen when it appears as a respirable dust Product contains trace amounts of residual Formaldehyde. OSHA & NTP identify Formaldehyde as a potential carcinogen. IARC identifies Formaldehyde as a human carcinogen. Formaldehyde has been shown to cause mutations in a variety of in -vitro test systems, w/ human significance unknown. Rats have shown carcinogenic effects in respiratory system. Risk should be minimal when used w/ adequate ventilation. Maintain adequate ventilation to prevent exposure above OSHA exposure limits. Chem ical Nam e Titanium Dioxide 13463-67-7 Soda lime borosilicate glass 65997-17-3 ACGIH IARC Group 2B NTP OSHA X Group 3 IARC (International Agency for Research on Cancer) Group 2B - Possibly Carcinogenic to Humans Group 3 IARC components are "not classifiable as human carcinogens" OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Target organ effects Acute: Eyes & Skin. Chronic: Skin. Numerical measures of toxicity Not determined 12. ECOLOGICAL INFORMATION Ecotoxicity PRACTICES SHOULD BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION. . not tested for aquatic or animal toxicity. Release of product to terrestrial, atmospheric & aquatic environments should be avoided. Chem ical Nam e Algae/aquatic plants Fish Propylene Glycol 57-55-6 19000: 96 h Pseudokirchneriella subcapitata mg/L EC50 51600: 96 h Oncorhynchus mykiss mg/L LC50 static 41 47: 96 h Oncorhynchus mykiss mL/L LC50 static 51400: 96 h Pimephales promelas mg/L LC50 static 710: 96 h Pimephales promelas mg/L LC50 0.44: 96 h Cyprinus carpio mg/L LC50 0.26 - 4.6: 96 h Lepomis macrochirus mg/L LC50 1.17: 96 h Lepomis macrochirus mg/L LC50 flow -through 0.73 - 2.35: 96 h Pimephales promelas mg/L LC50 5.9: 96 h Pimephales promelas mg/L LC50 static 1.5: 96 h Poecilia reticulata mg/L LC50 1.19: 96 h Poecilia reticulata mg/L LC50 static 2200: 96 h Pimephales promelas mg/L LC50 Ammonium Hydroxide 7664-41-7 Petroleum Hydrocarbon 64742-48-9 Toxicity to m icroorganism s Crustacea 10000: 24 h Daphnia magna mg/L EC50 1000: 48 h Daphnia magna mg/L EC50 Static 25.4: 48 h Daphnia magna mg/L LC50 2.6: 96 h Chaetogammarus marinus mg/L LC50 Persistence/Degradability Not tested for persistence & biodegradability. _____________________________________________________________________________________________ Page 7 / 10 Revision Date: 18-Jun-2014 RD-0022PTG - Pre-mixed Tile Grout _____________________________________________________________________________________________ Bioaccumulation Not tested for bio-accumulation potential. Mobility Not tested for mobility in soil Chem ical Nam e Ammonium Hydroxide 7664-41-7 Partition Coefficient -1.14 Other Adverse Effects Environmental Exposure Controls: Should be maintained so as to prevent release to the environment (atmospheric release, release to waterways & spills) Ozone Not expected to produce any ozone depletion 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. US EPA Waste Number Not Applicable 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT Not regulated IATA Not regulated IMDG Not regulated 15. REGULATORY INFORMATION International Inventories TSCA DSL NDSL Listed Listed Listed Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances _____________________________________________________________________________________________ Page 8 / 10 Revision Date: 18-Jun-2014 RD-0022PTG - Pre-mixed Tile Grout _____________________________________________________________________________________________ US Federal Regulations CERCLA Chem ical Nam e Ammonium Hydroxide 7664-41-7 Hazardous Substances RQs 100 lb CERCLA/SARA RQ 100 lb Reportable Quantity (RQ) RQ 100 lb final RQ RQ 45.4 kg final RQ SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Yes No No No No SARA 313 Chem ical Nam e CAS No Weight-% Ammonium Hydroxide - 7664-41-7 7664-41-7 <0.15 SARA 313 - Threshold Values % 1.0 CWA (Clean Water Act) Com ponent Ammonium Hydroxide 7664-41-7 ( <0.15 ) CWA - Reportable Quantities 100 lb CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances X US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals. Chem ical Nam e Titanium Dioxide - 13463-67-7 California Proposition 65 Carcinogen U.S. State Right-to-Know Regulations Chem ical Nam e Calcium Carbonate 1317-65-3 Titanium Dioxide 13463-67-7 Propylene Glycol 57-55-6 Ammonium Hydroxide 7664-41-7 New Jersey X Massachusetts X Pennsylvania X X X X X X X X X _____________________________________________________________________________________________ Page 9 / 10 Revision Date: 18-Jun-2014 RD-0022PTG - Pre-mixed Tile Grout _____________________________________________________________________________________________ 16. OTHER INFORMATION NFPA HMIS Issue Date: Revision Date: Revision Note: Health Hazards 1 Health Hazards 1 Flammability 0 Flammability 0 Instability 0 Physical Hazards 0 Special Hazards Not determined Personal Protection X 18-Sep-2013 18-Jun-2014 New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet _____________________________________________________________________________________________ Page 10 / 10
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