5118 Safer Brand Insect Killing Soap Concentrate II (16 Oz) 704116 SDS
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SAFETY DATA SHEET
Issuing Date 5/01/2015
The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and
all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no representations
or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of this information
or the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved.
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
GHS Label elements, including precautionary statements
Emergency Overview
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Name Safer Brand Insect Killing Soap Concentrate II
Other means of identification
Synonyms None
Recommended use of the chemical and restrictions on use
Recommended Use Insecticide - Crawling Bug - Non-Aerosol
Uses advised against It is a violation of Federal law to use this product in a manner inconsistent with its labeling.
Details of the supplier of the safety data sheet
Supplier Name Woodstream Corp.
Supplier Address
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69 North Locust St.
Lititz
PA
17543
US
Supplier Phone Number Phone:(717) 626-2125
Fax:(717) 626-1912
Contact Phone: (800) 800-1819
Supplier Email mandre@woodstream.com
Emergency telephone number
Flammable liquids Category 2
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Signal word Danger
5118
Size
16 oz
Woodstream Corporation
Regulatory Licenses
EPA Reg. No. 42697-60
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1187216 - Safer Brand Insect Killing Soap Concentrate II
Precautionary Statements - Prevention
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ ventilating/ lighting/ equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Wear protective gloves/protective clothing/eye protection/face protection
Precautionary Statements - Response
Skin
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
Fire
In case of fire: Use CO2, dry chemical, or foam for extinction
Precautionary Statements - Storage
Store in a well-ventilated place. Keep cool
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Unknown Toxicity
49.52% of the mixture consists of ingredient(s) of unknown toxicity
Other information
May cause slight eye irritation
PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION
Toxic to aquatic life with long lasting effects
Interactions with Other Chemicals
Use of alcoholic beverages may enhance toxic effects.
Hazard Statements
Highly flammable liquid and vapor
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Appearance Amber
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Physical State Liquid Odor Alcohol
5118 Safer Brand Insect Killing Soap Concentrate II
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1187216 - Safer Brand Insect Killing Soap Concentrate II
4. FIRST AID MEASURES
First aid measures
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Keep eye wide open while rinsing. Do not rub affected area. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists:
Get medical advice/attention.
Skin Contact Wash off immediately with soap and plenty of water while removing all
contaminated clothes and shoes. In the case of skin irritation or allergic reactions
see a physician.
Inhalation Remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, (trained personnel should) give oxygen.
Ingestion Rinse mouth immediately and drink plenty of water. Never give anything by mouth
to an unconscious person.
Self-protection of the first aider Remove all sources of ignition. Ensure that medical personnel are aware of the
material(s) involved, take precautions to protect themselves and prevent spread of
contamination.
Most important symptoms and effects, both acute and delayed
Most Important Symptoms and
Effects
No information available.
Indication of any immediate medical attention and special treatment needed
Notes to Physician Treat symptomatically.
3. COMPOSITION/INFORMATION ON INGREDIENTS
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Chemical Name CAS No. Weight-% Trade Secret
Ethyl alcohol 64-17-5 15 - 40
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*
*The exact percentage (concentration) of composition has been withheld as a trade secret
5118 Safer Brand Insect Killing Soap Concentrate II
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1187216 - Safer Brand Insect Killing Soap Concentrate II
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Dry chemical. Carbon dioxide (CO2). Alcohol resistant foam.
Unsuitable extinguishing media
CAUTION: All these products have a very low flash point. Use of water spray when fighting fire may be inefficient.
Specific Hazards Arising from the Chemical
Vapors can form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than
air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard
indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard.
Uniform Fire Code Flammable Liquid: I-B
Hazardous Combustion Products
Carbon oxides.
Explosion Data
Sensitivity to Mechanical Impact No.
Sensitivity to Static Discharge Yes.
Protective equipment and precautions for firefighters
Move containers from fire area if you can do it without risk.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
All equipment used when handling the product must be grounded. Do not touch or walk
through spilled material. Stop leak if you can do it without risk.
Other Information Water spray may reduce vapor; but may not prevent ignition in closed spaces.
Environmental Precautions
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Environmental Precautions Prevent entry into waterways, sewers, basements or confined areas.
Methods and material for containment and cleaning up
Methods for Containment A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth,
sand or other non-combustible material and transfer to containers.
Methods for cleaning up
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Use clean non-sparking tools to collect absorbed material. Dike far ahead of liquid spill for
later disposal.
5118 Safer Brand Insect Killing Soap Concentrate II
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1187216 - Safer Brand Insect Killing Soap Concentrate II
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Ethyl alcohol
64-17-5
STEL: 1000 ppm TWA: 1000 ppm
TWA: 1900 mg/m3
(vacated) TWA: 1000 ppm
(vacated) TWA: 1900 mg/m3
IDLH: 3300 ppm 10% LEL
TWA: 1000 ppm
TWA: 1900 mg/m3
ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health
Administration - Permissible Exposure Limits NIOSH IDLH Immediately Dangerous to Life or Health
Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992) See section 15 for national exposure control parameters
Appropriate engineering controls
Engineering Measures Showers
Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/Face Protection Tight sealing safety goggles.
Skin and Body Protection Wear protective gloves and protective clothing. Long sleeved clothing. Chemical resistant
apron. Impervious gloves. Antistatic boots.
Respiratory Protection No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.
7. HANDLING AND STORAGE
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Precautions for safe handling
Handling Handle in accordance with good industrial hygiene and safety practice. Use personal
protection equipment. Avoid contact with skin and eyes. Avoid breathing vapors or mists.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use grounding and
bonding connection when transferring this material to prevent static discharge, fire or
explosion. Use with local exhaust ventilation. Use spark-proof tools and explosion-proof
equipment. Keep in an area equipped with sprinklers. Use according to package label
instructions.
Conditions for safe storage, including any incompatibilities
Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from
heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static
electricity). Keep in properly labeled containers. Do not store near combustible materials.
Keep in an area equipped with sprinklers. Store in accordance with the particular national
regulations. Store in accordance with local regulations.
Page 5 / 12
Incompatible Products None known based on information supplied.
5118 Safer Brand Insect Killing Soap Concentrate II
STORAGE AND DISPOSAL:
Do not contaminate water, feed or foodstuffs by storage and disposal.
PESTICIDE STORAGE: Store only in original container in a cool, dry area inaccessible to children and pets. Do not store full or
partial containers in direct sunlight. Keep container tightly sealed when not in use.
PESTICIDE DISPOSAL AND CONTAINER HANDLING: If Empty: Non-refillable container. Do not reuse or refill this container.
Place in trash or offer for recycling if available. If Partly Filled: Call your local solid waste agency for disposal instructions. Never
place unused product down any indoor or outdoor drain.
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1187216 - Safer Brand Insect Killing Soap Concentrate II
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or
smoke when using this product. Contaminated work clothing should not be allowed out of
the workplace. Regular cleaning of equipment, work area and clothing is recommended.
Wash hands before breaks and immediately after handling the product.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Physical State Liquid
Explosive properties No data available
Oxidizing Properties No data available
Other Information
Softening Point No data available
VOC Content (%) No data available
Particle Size No data available
Particle Size Distribution
Appearance Amber Odor Alcohol
Color No information available Odor Threshold No information available
Property Values Remarks/ Method
pH 10.6 None known
Melting / freezing point No data available None known
Boiling point / boiling range 80 °C / 176 °F None known
Flash Point 15 C / 60 F None known
Evaporation Rate No data available None known
Flammability (solid, gas) No data available None known
Flammability Limit in Air
Upper flammability limit No data available
Lower flammability limit No data available
Vapor pressure No data available None known
Vapor density No data available None known
Specific Gravity No data available None known
Water Solubility Completely soluble None known
Solubility in other solvents No data available None known
Partition coefficient: n-octanol/water0 None known
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Autoignition temperature No data available None known
Decomposition temperature No data available None known
Kinematic viscosity No data available None known
Dynamic viscosity
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3 None known
5118 Safer Brand Insect Killing Soap Concentrate II
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1187216 - Safer Brand Insect Killing Soap Concentrate II
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information .
Inhalation Specific test data for the substance or mixture is not available.
Eye Contact Specific test data for the substance or mixture is not available.
Skin Contact Specific test data for the substance or mixture is not available.
Ingestion Specific test data for the substance or mixture is not available.
Component Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Ethyl alcohol
64-17-5
- - = 124.7 mg/L ( Rat ) 4 h
Information on toxicological effects
Symptoms No information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization No information available.
Mutagenic Effects No information available.
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
10. STABILITY AND REACTIVITY
Reactivity
Chemical stability
Stable under recommended storage conditions.
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Possibility of Hazardous Reactions
None under normal processing.
Hazardous Polymerization
Hazardous polymerization does not occur.
Conditions to avoid
Heat, flames and sparks.
Incompatible materials
None known based on information supplied.
Hazardous Decomposition Products
Carbon oxides.
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No data available.
5118 Safer Brand Insect Killing Soap Concentrate II
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1187216 - Safer Brand Insect Killing Soap Concentrate II
Chemical Name ACGIH IARC NTP OSHA
Ethyl alcohol
64-17-5
A3 Group 1 Known X
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer)
Group 1 - Carcinogenic to Humans
NTP (National Toxicology Program)
Known - Known Carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
Reproductive Toxicity No information available.
STOT - single exposure No information available.
STOT - repeated exposure No information available.
Chronic Toxicity No known effect based on information supplied. Contains a known or suspected
carcinogen. Ethanol has been shown to be carcinogenic in long-term studies only when
consumed as alcoholic beverage. May cause adverse effects on the bone marrow and
blood-forming system. May cause adverse liver effects. Contains a known or suspected
reproductive toxin. Ethanol has been shown to be a reproductive toxin only when consumed
as an alcoholic beverage.
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Target Organ Effects Blood. Central Nervous System (CNS). Eyes. Liver. Reproductive System. Respiratory
system. Skin.
Aspiration Hazard No information available.
Numerical measures of toxicity Product Information
The following values are calculated based on chapter 3.1 of the GHS document
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ATEmix (inhalation-dust/mist)
176.80 mg/l
5118 Safer Brand Insect Killing Soap Concentrate II
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1187216 - Safer Brand Insect Killing Soap Concentrate II
14. TRANSPORT INFORMATION
DOT
Proper Shipping Name Limited Quantity
3
II
Hazard Class
Packing Group
Description UN1170, ETHANOL SOLUTION, 3, II
12. ECOLOGICAL INFORMATION
This product contains a chemical which is listed as a marine pollutant according to DOT
Ecotoxicity
Toxic to aquatic life with long lasting effects.
Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to
Microorganisms
Daphnia Magna (Water
Flea)
Ethyl alcohol
64-17-5
96h LC50: > 100 mg/L
(Pimephales promelas) 96h
LC50: 13400 - 15100 mg/L
(Pimephales promelas) 96h
LC50: 12.0 - 16.0 mL/L
(Oncorhynchus mykiss)
EC50 = 34634 mg/L 30 min
EC50 = 35470 mg/L 5 min
48h LC50: 9268 - 14221
mg/L 48h EC50: = 2 mg/L
24h EC50: = 10800 mg/L
Persistence and Degradability
No information available.
Bioaccumulation
Chemical Name Log Pow
Ethyl alcohol
64-17-5
-0.32
Other adverse effects
No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal methods This material, as supplied, is a hazardous waste according to federal regulations (40 CFR
261).
Contaminated Packaging Dispose of contents/containers in accordance with local regulations.
US EPA Waste Number D001
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California Hazardous Waste Codes 232
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California Hazardous Waste
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Ethyl alcohol
64-17-5
Toxic
Ignitable
5118 Safer Brand Insect Killing Soap Concentrate II
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1187216 - Safer Brand Insect Killing Soap Concentrate II
Emergency Response Guide
Number
127
TDG
UN-No. UN1170
Proper Shipping Name ETHANOL
Hazard Class 3
Packing Group II
Description UN1170, ETHANOL, 3, II
MEX
UN-No. UN1170
Proper Shipping Name ETHANOL
Hazard Class 3
Packing Group II
Description UN1170, ETHANOL, 3, II
ICAO
UN-No. UN1170
Proper Shipping Name ETHANOL
Hazard Class 3
Packing Group II
Description UN1170, ETHANOL, 3, II
IATA
UN-No. UN1170
Proper Shipping Name Limited Quantity- Not Labeled for Air Shipments
Hazard Class 3
Packing Group II
Description UN1170, ETHANOL, 3, II
IMDG/IMO
UN-No. UN1170
Proper Shipping Name Limited Quantity
Hazard Class 3
Packing Group II
EmS-No. F-E, S-D
Description UN1170, ETHANOL, 3, II, (22°C C.C.)
RID
UN-No. UN1170
Proper Shipping Name ETHANOL
Hazard Class 3
Packing Group II
Classification code F1
Description UN1170, ETHANOL, 3, II
ADR
UN-No. UN1170
Proper Shipping Name ETHANOL
Hazard Class 3
Packing Group II
Classification code F1
Tunnel restriction code (D/E)
Description UN1170, ETHANOL, 3, II
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ADN
UN-No. UN1170
Proper Shipping Name ETHANOL
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Hazard Class 3
5118 Safer Brand Insect Killing Soap Concentrate II
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1187216 - Safer Brand Insect Killing Soap Concentrate II
Packing Group II
Classification code F1
Special Provisions 144, 601
Description UN1170, ETHANOL, 3, II
Limited Quantity 1 L
Ventilation VE01
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL All components are listed either on the DSL or NDSL.
IECSC -
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories
Acute Health Hazard No
Chronic Health Hazard No
Fire Hazard Yes
Sudden release of pressure hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals.
Chemical Name California Proposition 65
Ethyl alcohol - 64-17-5 Carcinogen
Developmental
U.S. State Right-to-Know Regulations
.
Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island Illinois
Oleic acid
112-80-1
X
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Ethyl alcohol
64-17-5
X
Potassium hydroxide
1310-58-3
X X X
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X
5118 Safer Brand Insect Killing Soap Concentrate II
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling
requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required
for safety data sheets and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is
reproduced below. The pesticide label also includes other important information, including directions for use.
Pesticide label signal word: WARNING
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1187216 - Safer Brand Insect Killing Soap Concentrate II4
International Regulations
Mexico
National occupational exposure limits
Component Carcinogen Status Exposure Limits
Ethyl alcohol
64-17-5 ( 15 - 40 )
Mexico: TWA 1000 ppm
Mexico: TWA 1900 mg/m3
Mexico - Occupational Exposure Limits - Carcinogens
Canada
WHMIS Hazard Class
B2 - Flammable liquid
D2A - Very toxic materials
16. OTHER INFORMATION
Prepared By Product Stewardship
23 British American Blvd.
Latham, NY 12110
1-800-572-6501
Revision Date 12-Nov-2014
Revision Note No information available
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text
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End of Safety Data Sheet
NFPA Health Hazards 1Flammability 3Instability 0Physical and
Chemical Hazards -
HMIS Health Hazards 1Flammability 3
Page 12 / 12
Physical Hazard 0Personal Protection
X
5118 Safer Brand Insect Killing Soap Concentrate II
PRECAUTIONARY STATEMENTS
Causes skin irritation. Causes substantial but temporary eye injury. Harmful if absorbed through the skin. Harmful in inhaled. Do
not get on skin, in eyes or on clothing. Avoid breathing spray mist. Wash thoroughly with soap and water after handling and before
eating, drinking, chewing gum, or using tobacco. Remove and wash contaminated clothing before reuse. Wear protective eyewear
(goggles, face shield, or safety glasses).
ENVIRONMENTAL HAZARDS:
This product may be hazardous to aquatic invertebrates. For terrestrial uses, do not apply directly to water, or to areas where
surface water is present or to intertidal areas below the mean high water mark. Do not contaminate water by cleaning of equipment
or disposal of rinsate.
PHYSICAL OR CHEMICAL HAZARDS:
Flammable. Keep away from heat and open flame.
