704405 SDS
2018-03-31
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DOKTOR DOOM Total Release Foggers Item #:5.5 oz - 44606
Safety Data Sheet
DOKTOR DOOM Total Release Foggers Item #:5.5 oz - 44606
PRODUCT NAME:
EPA REGISTRATION#:
EPA EST #:
CHEMICAL DESCRIPTION:
SYNONYM(S):
PRODUCT DESCRIPTION:
Product Codes:
Doktor Doom Total Release Foggers
72804-1
11623-GA-1
Mixture; a.i.'s: Pyrethrum, Piperonyl Butoxide
None
For formulation into insecticides only.
5.5 oz - 44606
MANUFACTURER
753146 Alberta Ltd. o/a Ultrasol Industries Ltd.
107555 - 69 Avenue
Edmonton, AB T6H 2C9
24 HR. EMERGENCY TELEPHONE NUMBERS
FOR TRANSPORTATION:
CHEMTREC® U.S. and CANADA: 1 (800) 424-9300
CHEMTREC® All other Areas: 1 (703) 527-3887
EMERGENCY CONTACT: SafetyCall®
Emergency Phone: 1 (800) 222-1222
Alternate Emergency Phone: 1 (800) 452-0023
Service Number: 1 (800) 645-6466
E-Mail: doktordoom@doktordoom.com
Comments: Ultrasol Hours of operation are 8:00 am to 4:30 pm MDT,
For MEDICAL EMERGENCIES OR PESTICIDE INCIDENTS, call 24 hours a day to 1-800-222-1222
EMERGENCY OVERVIEW
WARNING
•
•
•
•
Harmful if swallowed
Causes substantial but temporary eye irritation
Toxic to aquatic organisms, including fish and invertebrates
Keep out of reach of children.
POTENTIAL HEALTH EFFECTS
Acute Toxicity (Primary Routes of Exposure): Ingestion, eye and skin contact.
Signs and Symptoms of Systemic Effects: May cause gastrointestinal effects such as nausea, vomiting and
diarrhea. Ingestion of large quantities can result in nervous system effects such as dizziness, loss of coordination,
tremors and loss of consciousness. Symptoms usually regress with no long lasting effects.
Acute Eye Contact: Causes substantial but temporary eye injury.
Acute Skin Contact: This product is slightly toxic when absorbed through the skin. May cause slight irritation to skin.
Acute Ingestion: This product may be harmful if swallowed.
DOKTOR DOOM Total Release Foggers Item #:5.5 oz - 44606
Acute Inhalation: This product is minimally toxic when inhaled.
Potentially Aggravated Medical Conditions: None known
For complete discussion of the toxicology data from which this evaluation was made, refer to Section 11. For
Ecotox/Environmental Information, refer to Section 12. For Regulatory Information, refer to Section 15.
Chemical Name
CAS Number
Weight/ Percent
Purpose
Piperonyl butoxide
8003-34-7
51-03-6
.4%
2.0%
Active Ingredient
Active Ingredient
(5-[12-(2-butoxyethoxy)ethoxy)methyl]-6-pro
pyl-1,3-benzodioxole)
Synthetic lsooaraffinic Hvdrocarbon
Others
64742-47-8
NoCAS#
9
55
Solvent
Other Ingredients
Pyrethrin
Other ingredients, which are maintained as trade secrets, are any substances other than an active ingredient
contained in this product. Some of these may be hazardous, but their identity is withheld because they are considered
trade secrets. The hazards associated with the other ingredients are addressed in this document. Specific information
on other ingredients for the management of exposures, spills, or safety assessments can be obtained by a treating
physician or nurse by calling (888) 740-8712 (within the United States) or (952) 852-9509 (outside the United States)
at anytime.
EYE CONTACT:
Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the
first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.
SKIN CONTACT:
Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control
center or doctor for treatment advice.
INGESTION:
Immediately call a poison control center or doctor. Do not induce vomiting unless told to do so by a poison control
center or doctor. Do not give any liquid to the person. Do not give anything by mouth to an unconscious person.
INHALATION:
Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration,
preferably by mouth-to-mouth, if possible. Call a poison control center or doctor for further treatment advice.
NOTES TO PHYSICIAN:
Contains petroleum distillates - vomiting may cause aspiration pneumonia. If ingested, probable mucosal damage
may contraindicate the use of gastric lavage.
FLASH POINT:
FLASH POINT METHOD:
EXTINGUISHING MEDIA:
OSHA FLAMMABILITY CLASS:
146° F (63° C)
SetaFlash Closed Cup
Carbon dioxide, dry chemical, foam, or water.
Class IIIA Combustible Liquid
NFPA RATING:
1
Health:
Flammability:
2
Emergency Telephone: Transportation 1-800-424-9300 Medical 1-800-222-1222
REVISION NUMBER:
2
MSOSNO.:
REVISION DATE:
ENV-0033A
08/28/2015
DOKTOR DOOM Total Release Foggers Item #:5.5 oz - 44606
Reactivity:
Special:
0
None
(Least-0, Slight-1, Moderate-2, High-3, Extreme-4). These values are obtained using professional judgement. Values
were not available in the guidelines or published evaluations prepared by the National Fire Protection Association,
NFPA.
FIRE FIGHTING INSTRUCTIONS: As in any fire, wear self-contained breathing apparatus pressure-demand,
MSHA/NIOSH approved (or equivalent) and full protective gear. Keep upwind. Isolate hazard area. Avoid inhalation of
smoke and fumes. Use water or foam to reduce fumes. Do not touch spilled material. If possible, move containers
from area. Extinguish only ifflow of water can be stopped. Use flooding amounts of water as a fog. Cool containers
wtth flooding amounts of water from as far a distance as possible. Avoid breathing vapors.
HAZARDOUS DECOMPOSITION PRODUCTS: May form toxic materials such as: Carbon dioxide, Carbon
monoxide, various hydrocarbons, etc.
ULTRASOL EMERGENCY PHONE NUMBER:
WITHIN THE UNITED STATES: 1-800-452-0023
OUTSIDE OF THE UNITED STATES: 1-800-452-0023
UN/NA NUMBER:
UN3082
EMERGENCY RESPONSE GUIDEBOOK NO.: 128
If it is safe to do so:
• Evacuate non-essential personnel from the area to prevent human exposure.
• Remove all sources of ignition.
• Ventilate area, especially low areas where vapors may accumulate.
• Slop the source of the spill. Contain the spill to prevent further contamination of the soil, surface water, or ground
water.
• May produce slippery conditions.
GENERAL AND DISPOSAL: Use proper protective equipment to minimize personal exposure (see Section 8). Take
all necessary action to prevent and to remedy the adverse effect of the spill. For additional spill response information
refer to the North American Emergency Response Guidebook , if applicable. Ensure that the disposal is in
compliance with all Federal, State, and local regulations. Refer to Section 14 for applicable Reportable Quantity (RQ)
and other regulatory requirements.
FOR SPILLS AND LEAKS
CONTAINMENT: If can is punctured or leaking, soak up liquid with an absorbent material such as sand, sawdust
earth, fuller's earth, etc. Place in an approved chemical waste container for disposal. Do not allow spill material to
enter any body of water.
CLEANUP: Clean up spill immediately. Absorb spill with inert material (such as dry sand or earth), then place in a
chemical waste container. Wash area with soap and water. Pick up wash liquid with additional absorbent and
place in a chemical waste container.
Emergency Telephone: Transportation 1-800-424-9300 Medical 1-800-222-1222
REVISION NUMBER:
2
MSDS NO.: ENV-0033A
REVISION DATE: 08/28/2015
Page 3 of 8
DOKTOR DOOM Total Release Foggers Item #:5.5 oz - 44606
END USER MUST READ AND OBSERVE ALL PRECAUTIONS ON PRODUCT LABEL.
HANDLING PRECAUTIONS: Avoid contact with skin, eyes or clothing. Wash thoroughly with soap and water after
handling and before eating, drinking, chewing gum, or using tobacco. Remove contaminated clothing and wash
clothing before reuse. Do not use near heat or open flame. Avoid contamination of feed and foodstuff.
STORAGE: Keep pesticide in original container only. Store in a cool, dry place, away from heat, flame and
incompatible materials. Do not contaminate water, food or feed by storage or disposal.
WORK/HYGIENIC PRACTICES: Wash thoroughly with soap and water after handling and before eating, drinking,
chewing gum or using tobacco.
END USER MUST READ AND OBSERVE ALL PRECAUTIONS ON PRODUCT LABEL.
INFORMATION FOR MANUFACTURER ($)/ FORMULATOR($)
EYES & FACE: Do not get this material in your eyes. Eye contact can be avoided by wearing safety goggles or a
face shield. Eyewash facilities should be available.
RESPIRATORY PROTECTION: Use this material only in well ventilated areas. If ventilation is not adequate to keep
airborne concentrations below recommended exposure standards, approved respiratory protection should be worn.
SKIN & HAND PROTECTION: Avoid contact with skin or clothing. Skin contact can be minimized by wearing
protective clothing including gloves. Immediately take off all contaminated clothing and wash before reuse.
ENGINEERING CONTROLS:
Formulators, mixers, loaders, applicators and other handlers should refer to the product label before use for
detailed information on personal protective equipment (PPE).
EXPOSURE LIMITS
Chemical Name
ACGIH Exposure
Limits
OSHA Exposure
Limits
Manufacturer's
Exposure
5 mg/m 3 TW A
None
5 ma/m3 TWA
None
None
Synthetic lsoparaffinic Hydrocarbon
None
None
1200 mQlm' lWA
Others
None
None
None
1-'Vrethrin
Plperonyl butoxide
(5-[12-(2-butoxyethoxy)ethoxy]methyl]-6-pro pvl-1,3benzodioxole)
PHYSICAL FORM:
COLOR:
ODOR:
FLASH POINT:
FLASH POINT METHOD:
DENSITY:
pH:
VISCOSITY:
Limits
None
Liquid
Yellow
Hydrocarbon
146" F (63" C)
SetaFlash Closed Cup
1.007 g/ml; (8.4 lb/gal)
4.6 @ 26" C; (1% solution in water)
168 cps @ 20" C, 68.4 cps @ 40" C
Page 4 of 8
Emergency Telephone: Transportation 1-800-424-9300 Medical 1-800-222-1222
REVISION NUMBER:
2
MSDS NO.: ENV-0033A
REVISION DATE: 08/28/2015
DOKTOR DOOM Total Release Foggers Item #:5.5 oz - 44606
CORROSION CHARACTERISTICS:
Not corrosive lo containers for 1 year at ambient
temperature.
Not intended for use with non-polar solvents.
SOLUBILITY:
CHEMICAL STABILITY:
INCOMPATIBILITY:
OXIDATION/REDUCTION PROPERTIES:
Stable
None known
Product does not have the potential to act as a strong
oxidizing or reducing agent.
Product contains no explosive ingredients.
Will not occur.
May form toxic materials such as: Carbon dioxide, Carbon
monoxide, various hydrocarbons, etc.
Heat or open flame
EXPLODABILITY:
HAZARDOUS POLYMERIZATION:
HAZARDOUS DECOMPOSITION PRODUCTS:
CONDITIONS TO AVOID:
ACUTE TOXICITY:
The following information is for the formulated product.
Oral Toxicity LD so (rats)
> 5,050 mg/kg (males)
3,517 mg/kg (females)
EPA Tax Category
Ill
Dermal Toxicity LD so (rabbits)
Inhalation Toxicity LCso(rats)
Eye Irritation (rabbits)
> 5,050 mg/kg
> 2.02 mg/L
EPA Tax Category
EPA Tax Category
EPA Tax Category
IV
IV
II
EPA Tox Category
EPA Tax Category
IV
Not available
Skin Irritation (rabbits)
Skin Sensitization (guinea pigs)
Chemical Name
Substantial; no effects by
Day 10.
Mildly irritating
Not a sensitizer
IARC - Group 1
(carcinogenic to
humans\
IARC - Group 2A
{Probably carcinogenic)
IARC - Group 2B
(Possibly carcinogenic)
NTP Carcinogen List
IP\irethrin
No
No
No
Not listed
Piperonyl butoxide
(5-112-(2-butoxyethoxy)elhoxy)methy
l]-6-oron"l-1,3-benzodioxole)
Svnthetic lsonaraffinic Hydrocarbon
Others
No
No
No
Not listed
No
No
No
No
No
No
Not listed
Not listed
CHRONIC/CARCINOGENICITY: In a recent study, marginally higher incidences of benign thyroid, parathyroid,
ovary, and liver tumors were observed in rats and in lungs of mice following lifetime high dose exposure to pyrethrum.
The significance of these observations is questionable and under review. The doses of pyrethrum at which tumors
were observed for both greatly exceeded potential human exposure from labeled uses. Independent and industry
toxicological experts who have reviewed the data agree that the findings of the study do not indicate a health risk to
human beings.
Page 5 of 8
Emergency Telephone: Transportation 1-800-424-9300 Medical 1-800-222-1222
REVISION NUMBER:
2
MSDS NO.: ENV-0033A
REVISION DATE: 08/28/2015
DOKTOR DOOM Total Release Foggers Item #:5.5 oz - 44606
MUTAGENICITY:
Pyrethrum was not found to be genotoxic and did not damage DNA in any study conducted (Ames mutagenicity
assay, chromosome aberration in Chinese hamster ovary (CHO) cells, CHO/HGPRT assay with S9 activation, and in
the unscheduled DNA sysnthesis (UDS) assay in cultered human liver cells).
Piperonyl butoxide was not genotoxic in several tests including the Ames mutagenicity assay, chromosome aberration
in Chinese hamster ovary (CHO) cells, CHO/HGPRT assay with S9 activation, and in the unscheduled DNA systhesis
(UDS) assay in cultured human liver cells.
DEVELOPMENTAL TOXICITY: There were no birth defects or adverse effects on reproductive parameters in tests
with rats or rabbits for either pyrethrum or piperonyl butoxide. They are not considered to be tetratogenic.
For a summary of the potential for adverse health effects from exposure to this product, refer to Section 2. For
information regarding regulations pertaining to this product, refer to Section 15.
AQUATIC ORGANISM TOXICITY:This material is highly toxic to aquatic organisms including fish and invertebrates.
OTHER ENVIRONMENTAL INFORMATION:
Do not discharge effluent containing this product into lakes , streams, ponds, estuaries, oceans or other waters unless
in accordance with the requirements of a National Pollution Discharge Elimination System (NPDES) permit and the
permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product
into sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your
State Water Board or Regional Office of the Environmental Protection Agency (EPA.) Do not contaminate water by
cleaning of equipment of disposal of wastes.
END USERS MUST DISPOSE OF ANY UNUSED PRODUCT AS PER THE LABEL RECOMMENDATIONS.
PRODUCT DISPOSAL:
Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility.
CONTAINER DISPOSAL:
Non-refillable container. Do not reuse or refill this container. Offer for recycling if available or reconditioning if
appropriate, or puncture and dispose of in a sanitary landfill or by other procedures approved by state and local
authorities.
DISPOSAL METHODS:
Check government regulations and local authorities for approved disposal of this material. Dispose in accordance with
applicable laws and regulations.
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: UN3082, Environmentally Hazardous Substance, Liquid, N.O.S., RQ (Pyrethrins)
PRIMARY HAZARD CLASS/DIVISION: 9, PACKING GROUP: Ill
REPORTABLE QUANTITY (RQ) UNDER CERCLA: 1 Lb. (Pyrethrins)
OTHER SHIPPING INFORMATION: This material is not regulated as hazardous by the DOT when Pyrethrin content is < 1
pound or less per shipping container (i.e., 33.3 Lbs. per shipping container, or less).
Shipping name for quantities less than< 33.3 Lbs. : Insecticides, Insect or Animal Repellents, Liquid, N.O.S.
Page 6 of 8
Emergency Telephone: Transportation 1-800-424-9300 Medical 1-800-222-1222
REVISION NUMBER:
2
MSDS NO.: ENV-0033A
REVISION DATE: 08/28/2015
DOKTOR DOOM Total Release Foggers Item #:5.5 oz - 44606
AIR (ICAO/IATA)
SHIPPING NAME: UN3082, Environmentally Hazardous Substance, Liquid, N.O.S., RQ (Pyrethrins)
PRIMARY HAZARD CLASS/DIVISION: 9
PACKING GROUP: Ill
VESSEL (IMO/IMDG)
SHIPPING NAME: UN3082, Environmentally Hazardous Substance, Liquid, N.O.S., RQ (Pyrethrins)
PRIMARY HAZARD CLASS/DIVISION: 9
PACKING GROUP: Ill
PESTICIDE REGULATIONS: All pesticides are governed under FIFRA (Federal Insecticide, Fungicide, and
Rodenticide Act). Therefore, the regulations presented below are pertinent only when handled outside of the normal
use and applications of pesticides. This includes waste streams resulting from manufacturing/formulation facilities,
spills or misuse of products, and storage of large quantities of products containing hazardous or extremely hazardous
substances.
U.S. FEDERAL REGULATIONS:
Ingredients in this product are reviewed against an inclusive list of federal regulations. Therefore, the user should
consult appropriate authorities. The federal regulations reviewed include: Clean Water Act, SARA, CERCLA, RCRA,
DOT, TSCA and OSHA. If no components or information is listed in the space below this paragraph, then none of the
regulations reviewed are applicable.
Pyrethrin
CERCLA Reportable Quantity (RQ):
0.454kg
1 lb
Piperonyl butoxide (5-[[2-(2-butoxyethoxy)ethoxy]methyl]-6-propyl-1,3-benzodioxole)
TSCA Inventory List Listed
SARA 313 Chemicals
1.0% de minimis concentration
Synthetic lsoparaffinic Hydrocarbon
TSCA Inventory List Listed
SARA (311, 312):
Immediate Health:
Chronic Health:
Fire'
Sudden Pressure:
Reactivity:
Yes
No
Yes
No
No
STATE REGULATIONS:
Each state may promulgate standards more stringent than the federal government. This section cannot encompass
an inclusive list of all slate regulations. Therefore, the user should consult state or local authorities. The state
regulations reviewed include: California Proposttion 65, California Directors List of Hazardous Substances,
Massachusetts Right to Know, Michigan Critical Materials List, New Jersey Right to Know, Pennsylvania Right to
Know, Rhode Island Right to Know and the Minnesota Hazardous Substance list. For Washington State Right to
Know, see Section 8 for Exposure Limit information. For Louisiana Right to Know refer to SARA information listed
under U.S. Regulations above. If no components or information is listed in the space below this paragraph, then none
of the regulations reviewed are applicable.
Emergency Telephone: Transportation 1-800-424-9300 Medical 1-800-222-1222
REVISION NUMBER:
2
MSDSNO.:
REVISION DATE:
ENV-0033A
08/28/2015
DOKTOR DOOM Total Release Foggers Item #:5.5 oz - 44606
Pyrethrin
California - Directors List of
Present
Hazardous Substances
MA Right To Know
Listed
NJ Right To Know
Listed
PA Right To Know
Listed
RI Right To Know
Listed
MN Hazardous Substance
Listed
Piperonyl butoxide (5-1[2-(2-butoxyethoxy)ethoxy]methyl]-6-propyl-1,3-benzodioxole)
NJ Righi To Know
Listed
For information regarding potential adverse health effects from exposure to this product, re fer to Sections 2 and 11.
REASON FOR ISSUE:
EPA REGISTRATION #:
EPA EST#:
PRODUCT CODE:
REVISION NUMBER:
REVISION DATE:
SUPERCEDES DA TE:
Name change from Pyrenone to PYROCIDE®.
72804-1
11623-GA-1
5.5 oz - 44606
01/01/2018
01/01/2018
The data contained herein are based on information currently available to Ultrasol Industries Ltd. and, to the best of our knowledge,
are accurate and based on sound expert opinion. Our statements herein, are not be be taken as a warranty or representation of
which Ultrasol Industries Ltd. assumes legal responsibility.
Dated January 1 2018. Valid for 3 years from date of issue.
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