Systemic Insect Control, 239 2461 4 704760 MSDS

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Material Safety Data Sheet U.S Department of Labor
May be used to comply with Occupational Safety and Health Administration
OSHA's Hazard Communication Standard, (Non-Mandatory Form)
29 CFR 1910.1200. Standard must be consulted Form Approved
for specific requirements. OMB No. 1218-0072
IDENTITY (As Used on Label and List)
Bonide Systemic Insect Control ID # 23924614
Date: March 10, 2008
Section I
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Bonide Products, Inc. (800) 424-9300
6301 Sutliff Rd. (315) 736-8231
Oriskany, NY 13424
Section II - Hazardous Ingredients/Identity
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Hazardous Components (Specific Chemical Identity: Common Name(s) OSHA PEL ACGIH TLV Other Limits % (Optional)
Acephate 30560-19-1 None None None 9.4%
Section III - Physical/Chemical Ingredients
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ODOR: Sulfurous Odor pH: N/A APPEARANCE: Clear to amber color liquid
SPECIFIC GRAVITY: 0.83 at 20°C FLASH POINT: 64° F closed cup
SOLUBILITY (H2O): Emulsifies VAPOR DENSITY: ND % VOLATILES: ND
BOILING POINT: ND VAPOR PRESSURE: ND
Section IV - Fire and Explosion Data
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FLASHPOINT: 64° F closed cup FLAMMABILITY LIMITS: UFL: N/A LFL: N/A
EXTINGUISHING MEDIA: Foam CO2 or dry chemical.
DEGREE OF FIRE/EXPLOSION HAZARD: This product presents an extreme fire hazard. Liquid very quickly
evaporates, even at low temperatures, and forms vapor (fumes) which can catch fire and burn with explosive
violence. Invisible vapor spreads easily and can be set on fire by many sources such as pilot lights, welding
equipment, electrical motors and switches. Overheated, sealed containers are an explosion hazard. Vapors which
form inside empty containers may also present an explosion hazard during a fire. SPECIAL FIRE FIGHTING
PROCEDURES: Isolate fire area. Evacuate downwind residents and all areas where fire seriously threatens the
product containers. Wear full protective clothing including rubber boots, neoprene gloves and self-contained
breathing apparatus. Attempt to keep containers cool. Do no breathe or contact smoke or vapors. CONDITIONS
TO AVOID (INCOMPATIBILITY): Heat and fire. Thermal decomposition and burning may produce toxic by-
products and an explosion hazard. HAZARDOUS DECOMPOSITION PRODUCTS: Normal combustion forms
carbon dioxide, water vapor and may produce oxides of sulfur, nitrogen and phosphorous. Incomplete combustion
can produce carbon monoxide.
Section V - Reactivity Data
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STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur
CONDITIONS TO AVOID: Excessive heat and fire. May react with strong oxidizing agents, such as chlorates,
nitrates, peroxides, etc. May react with aluminum, acetaldehyde, chlorine and ethylene oxide.
Section VI - Health Hazard Information
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PRIMARY ROUTES OF ENTRY: Acute and chronic effects from overexposure may result from inhalation and
ingestion.
Carcinogenicity Comments: EPA has classed acephate in category C – possible human carcinogen, based on the
increased incidence of liver tumors observed in the high dose, 1000 ppm (37.5 mg/kg/dy), female mice in the
lifetime feeding study. Acephate was not carcinogenic in the other female and male mouse dose levels or the rat
lifetime feeding study.
Bonide Systemic Insect Control page 2 of 2
Systemic Insect Control
Section VII - Precautions for Safe Handling/Use
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FIRST AID:
INGESTION: If swallowed, immediately call a poison control center or doctor. Do not induce vomiting unless told
to do so by a poison control center or doctor. Do not give any liquid to the person. Do not give anything by mouth
to an unconscious person..
EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present,
after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.
SKIN: Remove contaminated clothing and wash with soap and water immediately. Obtain medical attention if
irritation persists.
INHALATION: Remove to fresh air. If breathing is difficult or if any discomfort persists, obtain medical attention.
NOTE TO PHYSICIAN: This product contains a cholinesterase inhibitor. If signs and symptoms of cholinesterase
inhibition are present, atropine is antidotal. 2-PAM may also be given in conjunction with atropine. This product
contains petroleum distillates – vomiting may cause aspiration pneumonia. Consideration should be given to gastric
lavage with an endotracheal tube in place.
PROTECTIVE REQUIREMENTS:
VENTILATION: Thoroughly ventilate all transport vehicles prior to unloading. Store in a cool, dry, well-
ventilated place. General exhaust ventilation is considered sufficient.
WORK CLOTHING: Wear long-sleeved coveralls or uniform, cap, safety shoes and neoprene gloves.
EYE PROTECTION: Where potential of splashing exists, or contact with mist, protective goggles and face shield
should be worn. A source of clean water for flushing the eyes should be nearby.
RESPIRATORY PROTECTION.: Use only NIOSH/MESA approved respirator.
GLOVES: Where chemical protective gloves made of neoprene when handling this product.
Section VIII - Environmental and Disposal Information
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STORAGE AND HANDLING: Store in a cool, dry place and avoid excess heat. Store in original container only.
Keep out of reach of children. Do not get in the eyes, on skin, or on clothing. After use, wash hands and other
exposed skin prior to smoking or consuming food or beverages. Shower after handling or applying the product. Do
not put concentrate or dilute material into food or drink containers. Do not contaminate other pesticides, fertilizers,
water, food or feed by storage or disposal.
SPILL OR LEAK: Isolate and post spill area. Keep away from ignition sources. Wear prescribed protective
clothing and equipment. Keep material out of streams and sewers. Contain and absorb spilled material with a solid
absorbent such as sand, cat litter, commercial clay or other suitable absorbent. Use caustic or soda ash with alcohol
(methanol, ethanol or isopropanol) to neutralize spill area. Place in an approved drum and dispose of material
following the method outlined below under "Waste Disposal". To decontaminate spill area, tools and equipment,
wash with a suitable solution (e.g. organic solvent, detergent, bleach or caustic) and dispose of solution following
the method outlined below under "Waste Disposal".
WASTE DISPOSAL: Open dumping or burning of this material is prohibited. An acceptable method of disposal is
to burn in an incinerator in accordance with all local, state and federal environmental laws, rules, standards and
regulations. Because acceptable methods of disposal may vary by location and because regulatory requirements
may change, the appropriate regulatory agencies should be contacted prior to disposal. Steel containers which
contained these materials must be crushed and disposed of in a sanitary landfill. Do not cut or weld steel containers.
KEEP OUT OF REACH OF CHILDREN
ABBREVIATION KEY
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N/A: NOT AVAILABLE OR APPLICABLE N/E: NOT ESTABLISHED ND: Not Determined
TLV: THRESHOLD LIMIT VALUE TWA: TIME WEIGHTED AVG./8 HOUR WORKDAY
STEL: SHORT TERM EXPOSURE LIMIT D.O.T.: DEPARTMENT OF TRANSPORTATION
DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES
Buyer assumes all risks of use, storage and handling of this material not in strict accordance with directions given herewith.

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