FAX (17).TIF Chadwell Supply MSDS
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DOW CORNING CORPORATION Material Safety Data Sheet Page: 1 of 7 Version: 1.3 Revision Date: 2006/01/23 DOW CORNING(R) HVAC/R SEALANT CLEAR 1. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY 24 Hour Emergency Telephone: Customer Service: Product Disposal Information: CHEMTREC: Dow Corning Corporation South Saginaw Road Midland, Michigan 48686 MSDS No.: 04045032 Revision Date: 2006/01/23 Generic Description: Physical Form: Color: Odor: Silicone elastomer Paste Colorless Acetic acid odor NFPA Profile: Health 2 Flammability 1 Instability/Reactivity Note: NFPA = National Fire Protection Association 2. OSHA HAZARDOUS COMPONENTS CAS Number (989) 496-5900 (989) 496-6000 (989) 496-6315 (800) 424-9300 Wt % Component Name 17689-77-9 1.0 - 5.0 Ethyltriacetoxysilane 4253-34-3 1.0 - 5.0 Methyltriacetoxysilane The above components are hazardous as defined in 29 CFR 1910.1200. 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS Acute Effects Eye: Direct contact may cause moderate irritation. Skin: May cause moderate irritation. Inhalation: Irritates respiratory passages very slightly. Oral: Low ingestion hazard in normal use. Prolonged/Repeated Exposure Effects Skin: No known applicable information. Inhalation: No known applicable information. Oral: No known applicable information. 0 DOW CORNING CORPORATION Material Safety Data Sheet Page: 2 of 7 Version: 1.3 Revision Date: 2006/01/23 DOW CORNING(R) HVAC/R SEALANT CLEAR Signs and Symptoms of Overexposure No known applicable information. Medical Conditions Aggravated by Exposure No known applicable information. The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar compositions, component data and/or expert review of the product. Please refer to Section 11 for the detailed toxicology information. 4. FIRST AID MEASURES Eye: Immediately flush with water for 15 minutes. Get medical attention. Skin: Remove from skin and wash thoroughly with soap and water or waterless cleanser. Get medical attention if irritation or other ill effects develop or persist. Inhalation: No first aid should be needed. Oral: No first aid should be needed. Comments: Treat according to person's condition and specifics of exposure. 5. FIRE FIGHTING MEASURES Flash Point: Not applicable. Autoignition Temperature: Not determined. Flammability Limits in Air: Not determined. Extinguishing Media: On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide (CO2), dry chemical or water spray. Water can be used to cool fire exposed containers. Fire Fighting Measures: Self-contained breathing apparatus and protective clothing should be worn in fighting large fires involving chemicals. Determine the need to evacuate or isolate the area according to your local emergency plan. Use water spray to keep fire exposed containers cool. Unusual Fire Hazards: None. Hazardous Decomposition Products Thermal breakdown of this product during fire or very high heat conditions may evolve the following hazardous decomposition products: Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide. Formaldehyde. 6. ACCIDENTAL RELEASE MEASURES DOW CORNING CORPORATION Material Safety Data Sheet Page: 3 of 7 Version: 1.3 Revision Date: 2006/01/23 DOW CORNING(R) HVAC/R SEALANT CLEAR Containment/Clean up: Observe all personal protection equipment recommendations described in Sections 5 and 8. Wipe up or scrape up and contain for salvage or disposal. Clean area as appropriate since spilled materials, even in small quantities, may present a slip hazard. Final cleaning may require use of steam, solvents or detergents. Dispose of saturated absorbant or cleaning materials appropriately, since spontaneous heating may occur. Local, state and federal laws and regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which federal, state and local laws and regulations are applicable. Sections 13 and 15 of this MSDS provide information regarding certain federal and state requirements. Note: See section 8 for Personal Protective Equipment for Spills. Call (989) 496-5900, if additional information is required. 7. HANDLING AND STORAGE Use with adequate ventilation. Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide ventilation during use to control HOAc within exposure guidelines or use respiratory protection. Avoid eye contact. Keep container closed and store away from water or moisture. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Component Exposure Limits CAS Number Component Name Exposure Limits 17689-77-9 Ethyltriacetoxysilane See acetic acid comments. 4253-34-3 Methyltriacetoxysilane See acetic acid comments. Acetic acid is formed upon contact with water or humid air. Provide adequate ventilation to control exposures within guidelines of OSHA PEL: TWA 10 ppm and ACGIH TLV: TWA 10 ppm, STEL 15 ppm. Engineering Controls Local Ventilation: General Ventilation: None should be needed. Recommended. Personal Protective Equipment for Routine Handling Eyes: Use proper protection - safety glasses as a minimum. Skin: Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are recommended. Suitable Gloves: Silver Shield(R). 4H(R). DOW CORNING CORPORATION Material Safety Data Sheet Page: 4 of 7 Version: 1.3 Revision Date: 2006/01/23 DOW CORNING(R) HVAC/R SEALANT CLEAR Inhalation: No respiratory protection should be needed. Suitable Respirator: None should be needed. Personal Protective Equipment for Spills Eyes: Use proper protection - safety glasses as a minimum. Skin: Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are recommended. Inhalation/Suitable Respirator: No respiratory protection should be needed. Precautionary Measures: Avoid eye contact. Use reasonable care. Comments: Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide ventilation during use to control HOAc within exposure guidelines or use respiratory protection. Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require added precautions. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical Form: Color: Odor: Specific Gravity @ 25°C: Viscosity: Freezing/Melting Point: Boiling Point: Vapor Pressure @ 25°C: Vapor Density: Solubility in Water: pH: Volatile Content: Paste Colorless Acetic acid odor 1.04 Not determined. Not determined. Not determined. Not determined. Not determined. Not determined. Not determined. Not determined. Note: The above information is not intended for use in preparing product specifications. Contact Dow Corning before writing specifications. 10. STABILITY AND REACTIVITY Chemical Stability: Stable. Hazardous Polymerization: Conditions to Avoid: Hazardous polymerization will not occur. None. DOW CORNING CORPORATION Material Safety Data Sheet Page: 5 of 7 Version: 1.3 Revision Date: 2006/01/23 DOW CORNING(R) HVAC/R SEALANT CLEAR Materials to Avoid: Oxidizing material can cause a reaction. Water, moisture, or humid air can cause hazardous vapors to form as described in Section 8. 11. TOXICOLOGICAL INFORMATION Special Hazard Information on Components No known applicable information. 12. ECOLOGICAL INFORMATION Environmental Fate and Distribution Complete information is not yet available. Environmental Effects Complete information is not yet available. Fate and Effects in Waste Water Treatment Plants Complete information is not yet available. Hazard Parameters (LC50 or EC50) Acute Aquatic Toxicity (mg/L) Acute Terrestrial Toxicity Ecotoxicity Classification Criteria High Medium <=1 >1 and <=100 <=100 >100 and <= 2000 Low >100 >2000 This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34, 1993. This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information presented in the section concerning the overall ecological safety of this material. 13. DISPOSAL CONSIDERATIONS RCRA Hazard Class (40 CFR 261) When a decision is made to discard this material, as received, is it classified as a hazardous waste? No State or local laws may impose additional regulatory requirements regarding disposal. Call (989) 496-6315, if additional information is required. 14. TRANSPORT INFORMATION DOT Road Shipment Information (49 CFR 172.101) Not subject to DOT. Ocean Shipment (IMDG) DOW CORNING CORPORATION Material Safety Data Sheet Page: 6 of 7 Version: 1.3 Revision Date: 2006/01/23 DOW CORNING(R) HVAC/R SEALANT CLEAR Not subject to IMDG code. Air Shipment (IATA) Not subject to IATA regulations. Call Dow Corning Transportation, (989) 496-8577, if additional information is required. 15. REGULATORY INFORMATION Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200. TSCA Status: All chemical substances in this material are included on or exempted from listing on the TSCA Inventory of Chemical Substances. EPA SARA Title III Chemical Listings Section 302 Extremely Hazardous Substances (40 CFR 355): None. Section 304 CERCLA Hazardous Substances (40 CFR 302): None. Section 311/312 Hazard Class (40 CFR 370): Acute: Yes Chronic: No Fire: No Pressure: No Reactive: No Section 313 Toxic Chemicals (40 CFR 372): None present or none present in regulated quantities. Supplemental State Compliance Information California Warning: This product contains the following chemical(s) listed by the State of California under the Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer, birth defects or other reproductive harm. None known. Massachusetts CAS Number Wt % Component Name DOW CORNING CORPORATION Material Safety Data Sheet Page: 7 of 7 Version: 1.3 Revision Date: 2006/01/23 DOW CORNING(R) HVAC/R SEALANT CLEAR 7631-86-9 7.0 - 13.0 Silica, amorphous CAS Number Wt % Component Name 70131-67-8 > 60.0 Dimethyl siloxane, hydroxy-terminated 7631-86-9 7.0 - 13.0 Silica, amorphous 17689-77-9 1.0 - 5.0 Ethyltriacetoxysilane 4253-34-3 1.0 - 5.0 Methyltriacetoxysilane New Jersey Pennsylvania CAS Number Wt % Component Name 70131-67-8 > 60.0 Dimethyl siloxane, hydroxy-terminated 7631-86-9 7.0 - 13.0 Silica, amorphous 16. OTHER INFORMATION Prepared by: Dow Corning Corporation These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate. (R) indicates Registered Trademark MATERIAL SAFETY DATA SHEET IDENTIFICATION Name: Chemical Family: Formula: Synonyms: Hazard Class: Other Identifying Data: REFRIGERANT (R414b) Halogenated Hydrocarbons Mixture of CHClFCF3, CH3CClF2, CH(CH3)2-CH3, CHClF2 N/A 2.2 This product is a direct replacement for CFC-12 & HFC-134a, without modification of the user's equipment. CAS Name: Chlorodifluoromethane 1-Chloro-1, 1-difluoroethane Isobutane 2-Chloro-1,1,1,2-Tetrafluoroethane CAS Registry No. 000075-45-6 000075-68-3 068476-85-7 002837-89-0 FIRE AND EXPLOSION DATA: Flash point: Flammability Classification: Health Hazard Code: Flammable Limits in Air Extinguishing Media: NA will not burn Nonhazardous LEL: NA % UEL: NA % Stop Flow of Gas, Use Class A Ext. Agent, Use Class B Ext. Agent, Water may be used to blanket fire. EXPLODES ON HEATING Unusual Fire/Explosion Hazards: Cylinders may vent or rupture in fire conditions, leading to decomposition. Vapours may decompose if exposed to direct flame conditions. The vapour may displace oxygen making breathing difficult and causing light-headedness or suffocation. Special Fire Fighting Procedures:The material is not flammable and does not support combustion. The choice of fire extinguishing media depends on the surrounding materials involved in the fire. Use self-contained breathing apparatus and full protective gear. Use water spray to cool fire-exposed containers. HEALTH HAZARD INFORMATION: Manufacturer / Distributor: U.S. Environment Specialty Products 10640 East 59th Street, PO Box 36626 841 Brock Rd. South, Indianapolis IN 46236 Pickering ON LIW 3J2 EMER:1-800-457-4280 CHEMTREC, 24 Hrs 1-613-996-6666 CANUTEC, chemical emer. only INFO: 1-800-497-6805 (weekdays 7:30am-4:00pm)1-800-495-4062 (weekdays 9:00am-5:00pm) Immediate: The greatest hazard is contact with escaping gas which can cause frostbite and damage to exposed tissue. The escaping gas may displace oxygen and cause light-headedness, eye irritation and suffocation. Long Term: Exposure to high concentrations may lead to cardiac irregularities, unconsciousness or death. Other Hazards: None listed PHYSICAL DATA FIRST AID CANADA ICOR International Inc Boiling Point: -29.8°F Vapour Pressure: NDA Evaporation Rate: NDA ( Butyl Acetate =1) Vapour Density (Air =1) >1 very slight Solubility in H2O: Specific Gravity: 1.1 Pure or Mixture: Melting Point (F): pH: Ignition Temperature: Physical State: Mixture NDA NA 1170°F Gas HAZARDOUS COMPONENTS: Material(s): Chlorodifluoromethane 1-Chloro-1, 1-difluoroethane Isobutane 2-Chloro-1,1,1,2-Tetrafluoroethane Approximate weight % 50 9.5 1.5 39 HAZARDOUS REACTIVITY: AVOID INTENSE HEAT AND OPEN FLAME Stability: Material is normally stable. However, avoid open flames and high temperatures. Incompatibility (materials to avoid): Strong oxidants, including oxygen, freshly scraped aluminium, alkali metals, and alkali earth metals (sodium, magnesium, etc.) may cause exothermic reaction. The aluminum in refrigeration systems contains an oxide/chloride coating to prevent reaction with metal. Hazardous decomposition products: Hydrofluoric and hydrochloric acids, chlorine, fluorine, possibly phosgene, carbon dioxide, and carbon monoxide. Polymerization: Will not occur. Other Reactivity Data: Cylinders of used product may contain oil as well as refrigerant. A liquid leak or venting during a fire will produce a cloud of oil mist that is very flammable. Inhalation: Remove to fresh air, call a physician. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do not give epinephrine or similar drugs. Note to physicians: Because of possible increased risk or eliciting cardiac dysrythmias, catecholamine drugs, such as epinephrine, should be considered only as a last resort in life threatening emergencies. Eyes: Flush immediately with water for at least 15 minutes. Call a physician. Skin: Warm the area gradually by flushing with plenty of water. Call a physician Swallowed: DO NOT INDUCE VOMITTING, Call a physician Medical Conditions Aggravated by Exposure: Persons subject to cardiac problems may be at increased risk by exposure. PRECAUTIONS / PROCEDURES: Spill or leak: Remove or extinguish ignition or combustion sources. Evacuate enclosed spaces until gas is dispersed. Keep upwind. Stop the release of gas, if possible without risk. Disperse the gas with floor level forced-air ventilation. Exhaust vapours outdoors. Contain the spill by building a dike using absorbent material. Collect the remainder of the spill with absorbent material and place into a drum for waster disposal or recovery. Wash contaminated clothing before reuse. Work/Hygiene Practices: Use insulated or lined butyl gloves, face shield or goggles, and impervious clothing. Special Measures: Good general ventilation is usually adequate, but local ventilation may be needed if gas is vented to atmosphere. Use self-contained breathing apparatus if local ventilation is not adequate. SHIPPING INFORMATION: DOT Other information: Proper shipping name: LIQUEFIED GAS, N.O.S. Hazard Class: 2.2 DOT Identification: UN3163 Do not heat above 120°F Date revised: 03-01-04 MATERIAL SAFETY DATA SHEET NFPA SYMBOL HMIS SEVERE 4 SERIOUS MODERATE SLIGHT MINIMAL HMIS SYMBOL HEALTH 1 FLAMMABILITY 1 REACTIVITY 0 NFPA EXTREME FIRE 3 HIGH 2 MODERATE 1 SLIGHT TOXICITY 0 INSIGNIFICANT 1 1 REACTIVITY 0 SPECIAL MAY BE USED TO COMPLY WITH OSHA’S HAZARD COMMUNICATIONS STANDSRD (HSC) 29 CFR 1910.1200 ================================================================================== SECTION I - PRODUCT IDENTIFICATION ================================================================================== Product name / Identity : ZOOM-SPOUT OILER DO-1 A-1 Components Product Code #: 6403 Product use : Oil Chemical family : Petroleum Hydrocarbonate Supplier name and address : Manufacturer name and address: A-1 COMPONENTS CORP. th 625 West 18 St. Hialeah, Florida 33010 Phone # : (305) 885-1911 Same as Supplier Emergency Telephone Numbers, 24-hour : INFOTRAC 1-800-535-5053 WHMIS CLASS: D2B ================================================================================== SECTION II - HAZARDOUS INGREDIENTS ================================================================================== LC50 ppm LD50 mg/kg Ingredients CAS # wt.% (Rat, ihl.) (Rat, oral) Oil mist 64742-65-0 95-99.99 n/av n/av ================================================================================== SECTION III - PHYSICAL DATA ================================================================================== Physical State : Liquid Odor and appearance : Clear, yellow characteristic odor. Odor threshold : n/ap Specific gravity : 0.866 Coefficient of water/oil distribution : n/av Vapor pressure (mm Hg at 20oC) : n/av Boiling point : above 555°F (291°C) Freezing/Melting Point : n/av pH : n/ap Vapor density (Air = 1) : Heavier than air Evaporation rate (BuAe = 1) : Slower than ether Volatiles, wt.% : Negligible Viscosity: 31.5 CST, @ 40°C Solubility in water: Negligible TELE-SPOUT OILER DO-1 ================================================================================== SECTION IV - FIRE AND EXPLOSION DATA ================================================================================== Conditions of flammability :. This material will burn but will not ignite readily. Means of extinction : Dry chemical, CO@, water spray, foam, sand or earth. Water or foam may cause frothing. Sensitivity to mechanical impact/static discharge : n/av Flash point (Method) : 365°F (202°C) (COC) Upper flammable limit % : n/ap Lower flammable limit % : n/ap Auto-ignition temperature : n/ap Special Fire Fighting Procedures: Water spray may be useful in minimizing vapors and cooling containers exposed to heat and flame. Avoid spreading burning liquid with water used for cooling purposes. Move undamaged containers from fire area if you can do so without risk. Hazardous Combustion Products: Refer to "Hazardous Decomposition Products". Unusual Fire and Explosion Hazards: ================================================================================== SECTION V - REACTIVITY DATA ================================================================================== Stability : Stable under ambient pressure and temperature. Hazardous polymerization will not occur. Incompatible materials : Strong oxidizing agents. Avoid contact with any source of ignition. Extended exposure to hugh temperatures may cause decomposition. Conditions of reactivity: n/ap Hazardous decomposition products : Thermal decomposition in the presence of air may yield major amounts of oxides of carbon and minor amounts of oxides of sulphur and nitrogen. ================================================================================== SECTION VI - TOXICOLOGICAL PROPERTIES ================================================================================== *** Routes of exposure and acute/chronic effects *** Exposure limit : TLV-TWA Oil mist 5 mg/m3 Irritancy of Product: Inhalation, ingestion, skin and eye contact. Inhalation : Exposure of mists, or prolonged or repeated exposure to fumes or vapors that may be generated when this material is heated, may cause irritation of nose and throat.. Skin :This material can cause skin irritation. Prolonged or repeated contact may cause redness, burning, or dermatitis. Eyes : This material may cause eye irritation. Direct contact may cause burning, tearing, and redness. Ingestion : Accidental ingestion of this material may cause irritation of the digestive tract. Chronic effects : None. Carcinogenicity: Not listed by IARC and ACGIH as carcinogenic. Reproductive effects, Teratogenicity, Mutagenicity: n/av. Sensitization to Product: None known. Name of Toxicologically Synergistic Products: n/av TELE-SPOUT OILER DO-1 ================================================================================== SECTION VII FIRST AID ================================================================================== Inhalation : Move victim from source of exposure if irritation of nose or throat develops. If symptoms of exposure develop, seek medical attention. If victim is not breathing, artificial respiration should be administered. Seek medical attention immediately. Eyes : Immediately move victim away from exposure. For direct contact, flush the affected eye(s) with clean water for at least 15 minutes. Seek medical attention immediately. Skin : Do not use gasoline, thinners or solvents to remove product from skin. Wipe material from skin and remove contaminated clothing. Cleanse affected area thoroughly with soap and water if necessarily a waterless hand cleaner. . If irritation or redness develops and persists, seek medical attention immediately. Ingestion : If victim is conscious and alert, give 2 to 3 cups of water or milk to drink. Seek medical attention immediately. NOTE TO PHYSICIAN: Emesis of lavage is not recommended for ingestions of minute quantities or tastes of most hydrocarbons. Medical opinion is divided for large ingestions. Emesis of lavage has been recommended for these petroleum products which have a high oral toxicity. Gastric lavage with a cuffed endotracheal tube is recommended by some physicians to prevent aspiration. ================================================================================== SECTION VIII - PREVENTIVE MEASURES ================================================================================== Spill, leak or release : Collect leaking fluid in sealable containers. Absorb spilled liquid in sand or inert absorbant. Contact fire authorities and appropriate local/provincial agencies. Waste disposal : Review federal, provincial and local government requirements prior to disposal. *** PROTECTIVE EQUIPMENT *** Respiratory protection : If airborne concentrations exceed recommended exposure limits, a suitable filter-type respirator should be worn. Ventilation : If current ventilation practices are not adequate to maintain airborne concentration below established exposure limits (see Section VI), additional ventilation or exhaust system may be required. Protective gloves : Impermeable to the specific material handled is advised to prevent skin contact and possible irritation. Eye protection : Approved eye protection to safeguard against potential eye contact. Other protective equipment : Eye wash and quick drench shower facilities should be available in the work area. Barrier creams that are specific for oil-based materials are recommended when gloves are impractical. *** STORAGE & HANDLING *** Storage and handling conditions : Handling: Avoid generating oil mists while handling. Avoid prolonged or repeated skin contact. wash thoroughly after handling. Do not wear oil-soaked clothing or shoes. Storage: Store in a cool, dry location. Store in original container. Keep container closed when not in use. Special Shipping Information: TDG - Not Regulated ================================================================================== Additional notes or references : Abbreviations : n/av : not available n/ap : not applicable IARC : International Agency for Research on Cancer ACGIH : American Conference of Governmental Industrial Hygienists TLV : Threshold Limit Values NIOSH: National Institute of Occupational Safety and Health STEL: Short Term Exposure Limit TDG : Transportation of Dangerous Goods Act. References : 1. ACGIH, Threshold Limit Values and Biological Exposure Indices for 1993-94. 2. International Agency for Research on Cancer Monographs, Supplement 7, 1988. 3. Canadian Centre for Occupational Health and Safety. Cheminfo Database. 4. N. Irving Sax. Dangerous Properties of Industrial Materials. Seventh Edition. ================================================================================== SECTION IX PREPARATION INFORMATION ================================================================================== Prepared by : A-1 COMPONENTS CORP. Telephone # : (305) 885-1911 Preparation date : December 16, 2005 TELE-SPOUT OILER DO-1 MATERIAL SAFETY DATA SHEET PRO-TREAT 200 CATALOG NO. PT-200, PT-236 SECTION I-IDENTIFICATION HAZARD RATINGS HMIS DATA HEALTH 2 0=MINIMAL FIRE 1 1=SLIGHT REACTIVITY 1 2 =MODERATE 3=HIGH 4=EXTREME Personal Protection Index B MANUFACTURED BY: Diversitech, Inc ADDRESS: 2530 Lantrac Court Decatur, GA 30035 EMERGENCY Phone No. 800-255-3924 Chem-Tel (Chemical Emergencies Only) PHONE NUMBER FOR INFORMATION: 800-995-2222 DATE REVISED: 3/29/2006 NAME OF PREPARER: ANTHONY E. JERNIGAN INGREDIENT SECTION II HAZARDOUS INGREDIENTS INFORMATION CAS NO OSHA ACIGH OTHER PEL TLV STEL Tetradecyl Dimethylbenzyl ammonium chloride 139-08-2 LD50: 18 mg/kg (mouse) % or RNG <25% SECTION III – PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: >112°C Specific gravity (H2O = 1): 1.-25-1.35 Vapor pressure (mm Hg): < 0.1 Melting Point (Pour Point): >40°C Vapor Density (Air = 1): N/A Evaporation Rate (Water = 1): N/A Solubility in water: 100 Appearance and odor: Blue tablet with a characteristic cationic surfactant odor. SECTION IV- FIRE AND EXPLOSION HAZARD DATA Flash Point (Method Used): None Flammable Limits: None Extinguishing media: Not applicable Special Fire Fighting Procedures: Keep containers cooled with a water spray if involved in a fire. Unusual Fire and Explosion Hazards: This product may evolve toxic fumes (ammonia, hydrogen chloride if heated to decomposition. Stability-Stable SECTION V – REACTIVITY DATA Conditions to avoid: None Incompatibility (Materials to avoid): Strong oxidizers, strong acids, formaldehyde, anionic surfactants & soap Hazardous Decomposition or Byproducts: May evolve carbon monoxide, carbon dioxide, hydrogen chloride, ammonia gas and other unidentified fragments if this product is involved in a fire. Hazardous Polymerization: Will not occur. 1 PRO-TREAT 200 MSDS SECTION VI– HEALTH HAZARD DATA Routes of Entry: Inhalation: no Skin: yes Ingestion: yes Eyes: yes Health Hazards (acute and chronic): Pro-Treat 200 is moderately toxic if ingested. Eye contact causes extreme irritation. May cause skin irritation in sensitive individuals. Carcinogenicity: NTP? No IARC Monographs? No OSHA Regulated? No Signs and symptoms of exposure: Inhalation: Dust may cause chemical pnuemonitis. This product is not toxic by inhalation. Skin: Minimally irritating. Prolonged contact may cause dermatitis or drying of skin. Ingestion: Do not take internally. If ingested, it may damage throat and digestive tissue. Swallowing may cause diarrhea, nausea, vomiting, unconsciousness. Eyes: May cause severe eye irritation, permanent damage or blindness. Medical Conditions Aggravated by Exposure: Contact with skin or eyes, or breathing dust can cause eye skin or tissue damage or affect individuals with respiratory disorders. Emergency and First Aid Procedures: Eyes: Flush with water for 15 minutes. Consult a physician if irritation persists Skin: Remove contaminated clothing. Wash the affected area with soap and water. Launder or dry clean clothes before reuse.. Inhalation: Evacuate to a safe area with plenty of fresh air. Allow the affected individual to rest in a well ventilated area, then seek medical aid immediately. Ingestion: DO NOT induce vomiting. Force fluids. Contact the nearest Poison Control Center SECTION VII – PRECAUTIONS FOR SAFE HANDLING AND STORAGE STEPS TO BE TAKEN IF MATERIAL IS SPILLED OR RELEASED: Wear recommended protective clothing. Remove contaminated garments promptly. Sweep up tablets and dispose of contaminated product in accordance with local, state, and federal regulations. Undamaged product may be recovered and used according to label instructions. DO NOT contaminate municipal sewers or other open bodies of water with runoff form cleanup. WASTE DISPOSAL METHODS: Incinerate this material and all associated wastes, or bury in an approved landfill in accordance with governmental regulations. HANDLING AND STORAGE: Avoid contact with skin and eyes. Avoid breathing dust. Keep containers closed when not in use. Store in a dry, cool, area Empty containers may retain residue. All containers should be disposed of in an environmentally safe manner, and in accordance with all governmental regulations. Keep this and all chemicals out of the reach of children. 2 PRO-TREAT 200 MSDS SECTION VIII – CONTROL MEASURES Respiratory Protection (Specify Type): Use in a well-ventilated area. If dust is being generated and exceeds the TLV, a respiratory program meeting OSHA 1910.134 and ANSI Z88.2 requirements must be followed. Ventilation: Local exhaust is recommended when used in enclosed areas. Protective Gloves: Neoprene, latex or other materials may be used if there is documented evidence of compatibility. Eye protection: Safety glasses (ANSI Z87.1) or approved equivalent as necessary to minimize eye contact hazards. Other Protective Clothing: Neoprene aprons, overshoes, oversleeves or other impervious clothing as necessary to minimize exposure. Work Hygienic Practices: Use proper industrial hygiene practices to minimize hazardous exposure. Wash hands after handling this material, and before eating or smoking. SECTION IX – ADDITIONAL INFORMATION Transportation Information: DOT HAZARD LABEL: None DOT Description: Cleaning Compound, NOI, other than liquid TSCA: All ingredients are TSCA listed SARA TITLE III Reporting Requirements: Section 302: EHS reporting not required Section 304: Hazardous releases reporting not required Section 311: Community Right To Know reporting is required if the inventory is above the Threshold Planning Quantity. Section 312: R-T-K Inventory data reporting is not required. Section 313: Emissions and release reporting may be required for users of this product within the manufacturing sector. This does not apply to service companies. This information is, to the best of our knowledge and belief, accurate and reliable as of the date completed. However no representation, warranty or guarantee is made as to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself as to the completeness and suitability of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information, nor do we offer any warranty against patent infringement 3 MATERIAL SAFETY DATA SHEET MSDS 0165 ============================================================================= Section 1 -- PRODUCT AND COMPANY IDENTIFICATION ----------------------------------------------------------------------------HMIS CODES PRODUCT NAME Health 1 Acid - Away Flammability 2 Reactivity 0 PRODUCT CODES PPI B 45004,45010 CHEMICAL FAMILY: Organic USE Compressor Burnout Acid Neutralizer MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. The RectorSeal Corporation Chemtrec 24 Hours 2601 Spenwick Drive (800) 424-9300 Houston, Texas 77055 USA VALIDATION DATE TECHNICAL SERVICE TELEPHONE NO. June 14, 2006 (800) 231-3345 REVISION DATE June 14, 2006 ============================================================================= Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS ----------------------------------------------------------------------------% by WT CAS No. INGREDIENT UNITS -64742-44-5 Petroleum Oil ACGIH TLV 5 mg/m3 OSHA PEL 5 mg/m3 ============================================================================= Section 3 -- HAZARDS IDENTIFICATION ----------------------------------------------------------------------------SUMMARY OF ACUTE HAZARDS Repeated inhalation may cause dizziness and nausea. Ingestion may cause cramps and diarrhea. ROUTE OF EXPOSURE, SIGNS AND SYMPTOMS INHALATION Upper respiratory tract irritation and dizziness. EYE CONTACT Irritation, watering may occur. SKIN CONTACT Frequent or prolonged contact may irritate and cause dermatitis. INGESTION May cause nausea, vomiting and gastro-intestinal irritation. SUMMARY OF CHRONIC HAZARDS Prolonged skin contact may result in irritation and dermatitis. Prolonged eye contact may result in irritation or chemical burns. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Individuals with pre-existing or chronic diseases of the eyes, skin or persons with chemical sensitivity may have increased susceptibility to excessive exposures. ============================================================================= Section 4 -- FIRST AID MEASURES ----------------------------------------------------------------------------If INHALED: If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial respiration as needed. Obtain emergency medical attention. Prompt action is essential. If on SKIN: Wash with soap and water. Remove contaminated clothing. If irritation occurs, seek medical attention. If in EYES: Flush with large amounts of water for at least 15 minutes. Get medical attention if irritation persists. If SWALLOWED: If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person. ============================================================================= Section 5 -- FIRE FIGHTING MEASURES ----------------------------------------------------------------------------FLASH POINT LEL UEL >148 F (64 C) SETA CC N/D N/D EXTINGUSING MEDIA Foam, dry chemical, carbon dioxide or water fog. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus (SCBA) and other protective clothing. Hazardous decomposition products possible (see Section 10). UNUSUAL FIRE AND EXPLOSION HAZARDS: Combustible - moderate flash point. Heat may build up pressure and rupture closed containers. ============================================================================= Section 6 -- ACCIDENTAL RELEASE MEASURES ----------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove all sources of ignition. Use absorbent materials to prevent footing hazard and to contain. Ventilate area with natural or explosion-proof, forced air ventilation. Avoid flushing into sewers, drains, waterways, and soil. Wear protective clothing and respiratory protection during cleanup. ============================================================================= Section 7 -- HANDLING AND STORAGE ----------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed and upright when not in use. Do not store near heat, sparks, or open flames. OTHER PRECAUTIONS: Avoid prolonged or repeated contact with skin or clothing. Empty containers may contain residues; treat as if full and observe all products precautions. Do not reuse empty containers. KEEP OUT OF REACH OF CHILDREN. ============================================================================= Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION ----------------------------------------------------------------------------RESPIRATORY PROTECTION (SPECIFY TYPE): In confined poorly ventilated areas, use NIOSH/MSHA approved air purifying or supplied air purifying or supplied air respirators. VENTILATION - LOCAL EXHAUST: Acceptable SPECIAL: Explosion-proof equipment MECHANICAL (GENERAL): Preferable OTHER: N/A PROTECTIVE GLOVES: Rubber or neoprene EYE PROTECTION: Chemical splash goggles (ANSI Z-87.1 or equivalent) OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Coveralls recommended. WORK/HYGIENIC PRACTICES: Where use can result in skin contact, wash exposed areas thoroughly before eating, drinking, smoking, or leaving work area. Launder contaminated clothing before reuse. ============================================================================= Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES ----------------------------------------------------------------------------BOILING POINT: 320 F (160 C) @ 760mm Hg SPECIFIC GRAVITY (H20 = 1): 0.9 VAPOR PRESSURE (mm Hg): <5 @ 68 F (20 C) MELTING POINT: N/A VAPOR DENSITY (AIR = 1): >5 EVAPORATION RATE (ETHYL ACETATE = 1): <1 APPEARANCE/ODOR: Pale Yellow Oil/Petroleum Odor SOLUBILITY IN WATER: Insoluble VOLATILE ORGANIC COMPOUNDS(VOC)Content (Theoretical Percentage By Weight): 0% or (0 g/L) ============================================================================= Section 10 -- STABILITY AND REACTIVITY ----------------------------------------------------------------------------STABILITY: Stable CONDITIONS TO AVOID: Heat, sparks, open flames, and strong oxidizing conditions. INCOMPATIBILITY (MATERIALS TO AVOID): Gaseous oxygen and strong oxidizing materials. HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO2 and fragmented hydrocarbons. HAZARDOUS POLYMERIZATION: Will not occur. ============================================================================= Section 11 -- TOXICOLOGY INFORMATION ----------------------------------------------------------------------------CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. ----------------------------------------------------------------------------TOXICOLOGY DATA Ingredient Name ----------------------------------------------------------------------------Petroleum Oil Oral-Rat LD50: N/D Inhalation-Rat LC50: N/D ============================================================================= Section 12 -- Ecological Information ----------------------------------------------------------------------------ECOLOGICAL DATA Ingredient Name ----------------------------------------------------------------------------Petroleum Oil Food Chain Concentration Potential N/D WATERFOWL TOXICITY N/D BOD N/D AQUATIC TOXICITY N/D ============================================================================= Section 13 -- DISPOSAL CONSIDERATIONS ----------------------------------------------------------------------------Waste Classification: Non-regulated waste oil Disposal Method: Used oil recycler Waste from this product is not considered hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Dispose of in accordance with Federal, State, and Local regulation regarding pollution. ============================================================================= Section 14 -- TRANSPORTATION INFORMATION ----------------------------------------------------------------------------DOT: Non-Regulated OCEAN (IMDG): Non-Regulated AIR (IATA): Non-Regulated WHMIS (CANADA): Non-Regulated ============================================================================= Section 15 -- REGULATORY INFORMATION ----------------------------------------------------------------------------REGULATORY DATA Ingredient Name ----------------------------------------------------------------------------Petroleum Oil SARA 313 No TSCA Inventory Yes CERCLA RQ N/A RCRA Code N/A ============================================================================= Section 16 -- OTHER INFORMATION ----------------------------------------------------------------------------This document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.1200). The information herein is given in good faith, but no warranty, expressed or implied is made. Consult RectorSeal for further information: (713) 263-8001 Page 1 of 1 CHEMetrics, Inc. 4295 Catlett Rd., Calverton, VA 20138 (800) 356-3072 (540) 788-9026 Fax (540) 788-4856 E-mail technical@chemetrics.com 24 Hour Emergency Numbers: Creation Date: Revision Date: (703) 590-9204 (540) 439-3860 04/22/86 (1072-17) 12/22/06 MATERIAL SAFETY DATA SHEET I. CHEMICAL IDENTIFICATION VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION TRADE NAMES: DISSOLVED OXYGEN CHEMets® and ULR CHEMets® CATALOG NOS.: R-7501, R-7501V, R-7511, R-7518, R-7540, R-7540G and R-7540V OSHA PEL & ACGIH TLV: N/A PROTECTIVE EQUIPMENT: Safety glasses IX. PHYSICAL AND CHEMICAL PROPERTIES DESCRIPTION: Reagent ampoules for the determination of dissolved oxygen in water. Each CHEMet™ contains approximately 0.50 mL of liquid reagent sealed under vacuum. Each ULR CHEMet™ contains approximately 1 mL of liquid reagent sealed under vacuum. NFPA RATINGS: HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0 STATE: Liquid APPEARANCE: Colorless to pale yellow ODOR: None SOLUBILITY IN WATER: Miscible pH: 11.5 BOILING POINT: 150EC MELTING POINT: -5.0EC VAPOR PRESSURE: N/A SPECIFIC GRAVITY: 1.03 VAPOR DENSITY: N/A II. COMPOSITION/INFORMATION ON INGREDIENTS X. STABILITY AND REACTIVITY COMPONENT: CAS NO.: Diethylene Glycol 111-46-6 PERCENT: < 28.5 COMPONENT: CAS NO.: Deionized Water 7732-18-5 PERCENT: > 70 INCOMPATIBILITIES: Acids HAZARDOUS DECOMPOSITION PRODUCTS: When heated to decomposition, oxides of carbon may be emitted. Stable under normal conditions. COMPONENT: CAS NO.: Other components N/A PERCENT: XI. TOXICOLOGICAL INFORMATION < 1.0 Any component of this mixture not specifically listed (e.g. "other components") is not considered to present a carcinogen hazard. III. HAZARDS IDENTIFICATION Harmful if swallowed. ACUTE TOXICITY: Irritation, nausea, diarrhea, nerve depression CHRONIC TOXICITY: Irritation, liver or kidney lesions MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye, skin, liver or kidney disorders CARCINOGEN STATUS: None No other data available at this time. XII. ECOLOGICAL INFORMATION Diethylene glycol has a low bioconcentration potential and is practically nontoxic to aquatic organisms. No other data available at this time. XIII. DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with Federal, State and Local Regulations. IV. FIRST AID MEASURES XIV. TRANSPORT INFORMATION EYE AND SKIN CONTACT: Immediately flush eyes and skin with water for 15 minutes. INGESTION: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Seek medical attention. INHALATION: Remove individual to fresh air. Not regulated. V. FIRE FIGHTING MEASURES FLASH POINT: N/A AUTOIGNITION POINT: N/A FLAMMABILITY LIMITS: UPPER: N/A LOWER: N/A EXTINGUISHING MEDIA: Dry chemical, carbon dioxide, water spray or foam XV. REGULATORY INFORMATION EUROPEAN INFORMATION: EU Symbols: Xn - HARMFUL Risk Phrases: Harmful if swallowed. Safety Phrases: If swallowed, seek medical advice immediately (show the label where possible). CANADIAN INFORMATION: WHMIS Classification: D2A All chemical components of this product are listed on Canada’s DSL. VI. ACCIDENTAL RELEASE MEASURES Take up with absorbent material. Place in small containers for disposal. U.S. INFORMATION: All chemical components of this product are listed on the TSCA Inventory. VII. HANDLING AND STORAGE XVI. OTHER INFORMATION Always wear eye protection when working with these ampoules. WARNING: Do not break the tip of the ampoule unless it is completely immersed in your sample. Breaking the tip in the air may cause the glass ampoule to shatter. If this product is used as directed, the user will not come in contact with or be exposed to any of its chemical components. Wash thoroughly after handling. Avoid contact with eyes. Fragile. Liquid in glass. Handle with care. Exposure of this product to temperatures up to 120EF (49EC) or even below 32EF (0EC) will not create a safety hazard. For optimum analytical accuracy, the product should be stored in the dark and at room temperature. THE ABOVE INFORMATION IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST INFORMATION CURRENTLY AVAILABLE TO US. ALL PRODUCTS ARE OFFERED IN ACCORDANCE WITH THE MANUFACTURER'S CURRENT PRODUCTION SPECIFICATIONS AND ARE INTENDED SOLELY FOR USE IN ANALYTICAL TESTING. THE MANUFACTURER SHALL IN NO EVENT BE LIABLE FOR ANY INJURY, LOSS OR DAMAGE RESULTING FROM THE HANDLING, USE OR MISUSE OF THESE PRODUCTS. CHEMets® and ULR CHEMets® are registered trademarks of CHEMetrics, Inc. MSDS #GGC-12, #GGC-6 SWOOSH CO2 Cartridge SECTION 1: IDENTIFICATION Product Name: Swoosh CO2 Cartridges MANUFACTURED FOR: Diversitech, Inc ADDRESS: 2530 Lantrac Court, Decatur, GA 30035 PHONE NUMBER: 800-255-3924 Chem-Tel (Chemical Emergencies Only) PHONE NUMBER (For Information): 800-995-2222 DATE REVISED: 5/5/2004 PREPARED BY: Anthony Jernigan SECTION 2: HAZARDOUS INGREDIENTS INFORMATION INGREDIENT CAS NO OSHA PEL ACIGH TLV OTHER STEL % Carbon dioxide 124-38-9 5000 ppm 3000 ppm ~100 SECTION 3: HAZARD IDENTIFICATION Emergency Overview: Colorless odorless gas. Contact with desublimed solid may cause frostbite. This product is nonflammable. Breathing high concentrations of vapors may produce drowsiness and a headache. Potential Health Effects: Eyes: Contact with desublimed solid may cause frostbite. Skin: Contact with desublimed solid may cause frostbite Ingestion: Unlikely. Contact with desublimed solid may cause frostbite. Inhalation: High concentrations of vapors in immediate area can displace oxygen and can cause dizziness and unconsciousness. Use with adequate ventilation. Pre-Existing Medical Conditions Aggravated by Exposure: Heart, lung, skin, eye. SECTION 4: FIRST AID MEASURES Eyes: Treat for frostbite immediately. Have eyes examined and tested by medical personnel if irritation develops or persists. Skin: Treat for frostbite immediately. Get medical attention if irritation develops or persist. Ingestion: Not a possible route of entry. Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES Flash Point: None to boiling (TCC) LEL/UEL: Nonflammable Extinguishing Media: Use extinguishing media as suitable for the combustible materials involved in the fire. Fire Fighting Instructions: As in any fire, wear self-contained breathing apparatus (pressuredemand, MSHA/NIOSH approved or equivalent) and full protective gear. Unusual Fire and Explosion Hazards: Contents under pressure. Do not store near heat sources. SECTION 6: ACCIDENTAL RELEASE MEASURES Large Spills: Shut off leak if possible and safe to do so. Wear self-contained breathing apparatus and appropriate personal protective equipment. Allow condensed solid to sublime. Small Spills: Allow condensed solid to sublime. 1 MSDS #GGC-12, #GGC-6 SWOOSH CO2 Cartridge SECTION 7: HANDLING AND STORAGE Avoid prolonged or repeated contact with eyes, skin, and clothing. Wash hands before eating. Protect cartridges from abuse, and extreme temperatures. Keep this product out of the reach of children. Do not puncture cartridge unless it is contained in an approved appliance. Do not attempt to refill spent cartridges. Maintain a well-ventilated work area; use with adequate ventilation. Avoid breathing product vapor or mist. Store in a cool dry place, away from heat, sparks, flame and direct sunlight. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines: CHEMICAL NAME ACGIH TWA OSHA PEL ACGIH STEL Carbon Dioxide 5,000 ppm 5,000 ppm 30,000 ppm Work/Hygienic Practices: Good general ventilation should be sufficient to control airborne levels. Local exhaust ventilation may be necessary to control any air contaminants to within their TLVs during the use of this product. Wear safety glasses with side shields (or goggles) and rubber, neoprene or other chemically resistant gloves if there is documented evidence of compatibility when handling this material. NFPA and HMIS Codes: NFPA HMIS Health 1 1 Flammability 0 0 Reactivity 0 0 Personal Protection - B SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Physical State: Colorless gas Solubility in Water: Very Soluble Odor: Slight ethereal Specific Gravity: (Water =1) 1.53 pH: NA Evaporation Rate: >1 (Butyl acetate=1) Vapor Pressure: 856 psia @ 70 F Vapor Density: 1.65 @ 70°F (Air = 1) Viscosity: NA Percent Volatile: 100% SECTION 10: STABILITY AND REACTIVITY Stability: This product is stable. Conditions to Avoid: None known Incompatibility: None known Products of Decomposition: None known Hazardous Polymerization: Will not occur Conditions to Avoid: NA SECTION 11: TOXICOLOGICAL INFORMATION Inhalation: Carbon Dioxide: LCLo/human 9ppm/5 min Cancer Information: No ingredients listed as human carcinogens by NTP or IARC Reproductive effects: none Teratogenic effects: none Mutagenic effects: none 2 MSDS #GGC-12, #GGC-6 SWOOSH CO2 Cartridge SECTION 12: ECOLOGICAL INFORMATION Environmental Impact Information: No sufficient effect known from discharge of gas or desublimed solid. Environmental Impact Data REPORTING (percent by weight): CFC 0.0% VOC 0.0%; HFC 0.0% HFC 0.0%; Cl. Solv. 0.0% ODP 0.00 US regulations require reporting spills of this material that could reach any surface waters. The toll free number for the US Coast Guard National Response Center is: 800-424-8802. SECTION 13: DISPOSAL CONSIDERATIONS Dispose of in accordance with all federal, state and local regulations. SECTION 14: TRANSPORTATION INFORMATION Proper Sub. Pkg. Hazard Pkg. Max. Shipping Name UN Number Class Risk Group Label Instr. Quantity Air: Carbon Dioxide UN 1013 2.2 NA NA Non-flammable 200 75kg;150kg. Gas Ground: Consumer NA ORM-D NA NA ORM-D Pkg. Commodity, ORM-D Auth. 173.306 SECTION 15: REGULATORY INFORMATION SECTION 313 SUPPLIER NOTIFICATION This product contains the following toxic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372): None TOXIC SUBSTANCES CONTROL ACT (TSCA): All ingredients of this product are listed on the TSCA Inventory. WHMIS: Class A This product is classified according to the hazard criteria of the CPR, and the MSDS contains all of the information required by the CPR. EEC: Supply Classification: Not Listed Hazard Pictogram: None Risk Phrases: R-20 Harmful by Inhalation Safety Phrases: S-2 Keep out of reach of children S-47 Keep at temperatures not exceeding 49 degrees C S-57 Refer to supplier for information on recycling SECTION 16: OTHER INFORMATION Do not puncture or incinerate containers. Normal ventilation for standard manufacturing practices is usually adequate. Local exhaust should be used when large amounts are released. REFERENCES: 29 CFR 1910.1200 40 CFR 300-700 ANSI Z400.1-1998; EEC Dangerous Substances Classification, Packaging and Labeling List (Annexes 1, 2, 3 & 4) This information is, to the best of our knowledge and belief, accurate and reliable as of the date completed. However no representation, warranty or guarantee is made as to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself as to the completeness and suitability of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information, nor do we offer any warranty against patent infringement. 3 J/B Industries Inc. Section 1: Product And Company Identification COMPANY: LOCATION: J/B INDUSTRIES INC. 601 N. Farnsworth Ave. Aurora, IL 60507 Emergency Telephone Number: 630/851-9444 PRODUCT NAME: Vacuum Pump Oil PRODUCT GRADES: PRODUCT CODE: DATE ISSUED: December 28, 1992 DATE REVISED: September 18, 2006 Sept. 1 , 2003 Section 2: Composition/ Information On Ingredients CAS NAME: Distillates, hydrotreated heavy paraffinic CAS NUMBER: 64742-54-7 AMOUNT: 100% weight This product is not approved for direct food use [CFR 178.3620 (a) & (b)] Section 3: Hazards Identification EMERGENCY OVERVIEW Clear colorless to pale yellow liquid. IMMEDIATE HEALTH EFFECTS EYE: Not expected to cause prolonged or significant eye irritation. SKIN: Contact with the skin is not expected to cause prolonged or significant irritation. Not expected to be harmful to internal organs if absorbed through the skin. Contact with the skin is not expected to cause an allergic skin response. INGESTION: Not expected to be harmful if swallowed. INHALATION: Not expected to be harmful if inhaled. Contains a petroleum-based mineral oil. May cause respiratory irritation or other pulmonary effects following prolonged or repeated inhalation of oil mist at airborne levels above the recomm ended mineral oil mist exposure limit. Symptoms of respiratory irritation may include coughing and difficulty breathing. Material Safety Data Sheet Section 4: First Aid Measures EYE: No specific first aid measures are required because this material is not expected to cause eye irritation. As a precaution, remove contact lenses, if worn, and flush eyes with water. SKIN: No specific first aid measures are required because this material is not expected to be harmful if it contacts the skin. As a precaution, remove clothing and shoes if contaminated. To remove the material from skin, use soap and water. Discard contaminated clothing and shoes or thoroughly clean before reuse. No specific first aid measures are required because this material is not expected to be harmful if swallowed. Do not induce vomiting. As a precaution, give the person a glass of water or milk to drink and get medical advice. Never give anything by mouth to an unconscious person. INHALATION: No specific first aid measures are required because this material is not expected to be harmful if inhaled. If exposed to excessive levels of material in the air, move the exposed person to fresh air. Get medical attention if coughing or respiratory discomfort occurs. Section 5: Fire Fighting Measures FIRE CLASSIFICATION; OSHA Classification (29 CFR 1910.1200): Not classified by OSHA as flammable or combustible. NFPA RATINGS: HEALTH FLAMMABILITY REACTIVITY 1 0 FLAMMABLE PROPERTIES: FLASH POINT: Cleveland Open Cup 378°F (190°C) (Min) AUTOIGNITION: No data available FLAMMABLE (EXPLOSIVE) LIMITS (% by volume in air): Lower N/A Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic compounds will be evolved when this material undergoes combustion. Section 6. Accidental Release Measures PROTECTIVE MEASURES: Eliminate all sources of ignition in vicinity of spilled material. SPILL MANAGEMENT: INGESTION: 0 material, do not enter any enclosed or confined fire space without proper protective equipment, including selfcontained breathing apparatus. Upper N/A EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. PROTECTION OF FIRE FIGHTERS: Fire Fighting Instructions: This material will burn although it is not easily ignited. For fires involving this Stop the source of the release if you can do it without risk. Contain release to prevent further contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing precautions in Exposure Controls/ Personal Protection. Use appropriate techniques such as applying noncombustible absorbent materials or pumping. Where feasible and appropriate, remove contaminated soil. Place contaminated materials in disposable containers and dispose of in a manner consistent with applicable regulations. REPORTING: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at (800) 424-8802 as appropriate or required. Section 7. Handling and Storage GENERAL HANDLING INFORMATION: Avoid contaminating soil or releasing this material into sewage and drainage systems and bodies of water. STATIC HAZARD: Electrostatic charge may accumulate and create a hazardous condition when handling this material. To minimize this hazard, bonding and grounding may be necessary but may not, by themselves, be sufficient. Review all operations which have the potential of generating an accumulation of electrostatic charge and/ or a flammable atmosphere (including tank and container filling, splash filling, tank cleaning, sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations) and use appropriate mitigating procedures. For more information, refer to OSHA 1 Standard 29 CFR 1910.106, 'Flammable and Combustible Liquids', National Fire Protection Association (NFPA 77, 'Recommended Practice on Static Electricity; and /or the American Petroleum Institute (API) Recommended Practice 2003, 'Protection Against Ignitions Arising Out of Static, Lightning and Stray Currents'. CONTAINER WARNING: Container is not designed to contain pressure. Do not use pressure to empty container or it may rupture with explosive force. Empty containers retain product residue (solid, liquid, and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode and cause injury or death. Empty containers should be completely drained, properly closed, and promptly returned to a drum reconditioner or disposed of properly. RESPIRATORY PROTECTION: No respiratory protection is normally required. If user operations generate an oil mist, determine if airborne concentrations are below the OSHA Permissible Exposure Limit (PEL) of 5 mg/m3 for mineral oil mist. If not, wear a NIOSH approved respirator that provides adequate protection from the measured concentrations of this material. For air-purifying respirators use a particulate cartridge. Use a positive pressure, air-supplying respirator if there is potential for uncontrolled release, exposure levels are not known, or other circumstances where air-purifying respirators may not provide adequate protection. Section 9: Physical And Chemical Properties APPEARANCE AND ODOR: Clear colorless to pale yellow liquid. PH: Not Available Section 8. Exposure Controls/ Personal Protection VAPOR PRESSURE: GENERAL CONSIDERATIONS: VAPOR DENSITY (Air =1): Consider the potential hazards of this material (see Section 3), applicable exposure limits, job activities, and other substances in the work place when designing engineering controls and selecting personal protective equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the personal protective equipment listed below is recommended. The user should read and understand all instructions and limitations supplied with the equipment since protection is usually provided for a limited time or under certain circumstances. ENGINEERING CONTROLS: Use in a well-ventilated area. PERSONAL PROTECTIVE EQUIPMENT: EYE/FACE PROTECTION: No special eye protection is normally required. Where splashing is possible, wear safety glasses with side shields as a good safety practice. SKIN PROTECTION: No special protective clothing is normally required. Where splashing is possible, select protective clothing depending on operations conducted, physical requirements and other substances. Suggested materials for protective gloves include: Nitrile Rubber, Silver Shield, Viton. <0.01 mmHg @ 100°F >1 BOILING POINT: >600°F (>315° C) SOLUBILITY: Soluble in hydrocarbons, insoluble in water FREEZING POINT NA MELTING POINT NA SPECIFIC GRAVITY: 0.85-0.87 @ 15.6 °C/15.6°C VOLATILE ORGANIC COMPOUNDS (VOC): 2.9% weight (Approximate) VISCOSITY: 18.7 cST - 105 cST @40°C Section 11. Toxicological Information IMMEDIATE HEALTH EFFECTS EYE IRRITATION: The mean 24-hour Draize eye irritation score in rabbits is 4.0/110. SKIN IRRITATION: For a 24-hour exposure, the Primary Irritation Score (PIS) in rabbits is: 0.2/8.0. SKIN SENSITIZATION: This material did not cause skin sensitization reactions in a Buehler guinea pig test. ACUTE DERMAL TOXICITY: The 24 hour(s) LD50 in the rabbit is >5g/kg. ACUTE ORAL TOXICITY: The LD50 in the rat is >5 g/kg. ACUTE INHALATION TOXICITY: The acute inhalation toxicity hazard is based on evaluation of data for similar materials or product components. GENETIC TOXICITY: This product gave negative results in the following mutagenicity assays: Microbial/Microsome Reverse Mutation Assay. ADDITIONAL TOXICOLOGY INFORMATION: This product contains petroleum base oils which may be refined by various processes including severe solvent extraction, severe hydrocracking, or severe hydrotreating. None of the oils requires a cancer warning under the OSHA Hazard Communication Standard (29 CFR 1910.1200). These oils have not been listed in the National Toxicology Program (NTP) Annual Report nor have they been classified by the International Agency for Research on Cancer (IARC) as; carcinogenic to humans (Group 1), probably carcinogenic to humans (Group 2A), or possibly carcinogenic to humans (Group 2B). Section 10. Stability And Reactivity Section 12. Ecological Information: CHEMICAL STABILITY: EXOTOXICITY This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. INCOMPATIBILITY WITH OTHER MATERIALS: May react with strong oxidizing agents, such as chlorates, nitrates, peroxides, etc. HAZARDOUS DECOMPOSITION PRODUCTS: None known (None expected) HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. Ten 96 hour(s) LC50 for rainbow trout (Oncorhynchus mykiss) is >1000 mg/l. ENVIRONMENTAL FATE READY BIODEGRADABILITY: This material is not expected to be readily biodegradable. Section 13. Disposal Considerations Oil collection services are available for used oil recycling or disposal. Place contaminated materials in containers and dispose of in a manner consistent 2 with applicable regulations. Contact your sales representative or local environmental or health authorities for approved disposal or recyling methods. Section 14. Transportation Information The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous Goods Regulations, for additional description requirements (e.g., technical name) and mode-specific or quantity-specific shipping requirements. DOT SHIPPING NAME: Not regulated as a hazardous material for transportation under 49 CFR DOT HAZARD CLASS: Not Applicable DOT IDENTIFICATION NUMBER: Not Applicable DOT PACKING GROUP: Not Applicable Section 15. Regulatory Information SARA 311/312 CATEGORIES: 1. 2. 3. 4. Immediate (Acute) Health Effects: Delayed (Chronic) Health Effects: Fire Hazard: Sudden Release of Pressure Hazard: 5. Reactivity Hazard: REGULATORY LISTS SEARCHED: 4_I1=IARC Group 1 4_I2A=IARC Group 2A 4_I28B=IARC Group 2B 05=NTP Carcinogen 06-OSHA Carcinogen 09-TSCA 12(b) 10=TSCA Section 4 11=TSCA Section 8(a) CAIR 12=TSCA Section 8(a) PAIR 13=TSCA Section 8(d) 15=SARA Section 313 16=CA Proposition 65 17=MA RTK 18=NJ RTK 19=DOT Marine Pollutant 20=PA RTK 21=TSCA Section 5(a) 25=CAA Section 112 HAPs 26=CWA Section 311 28=CWA Section 307 30=RCRA Waste P-List 31-RCRA Waste U-List 32=RCRA Appendix VIII No components of this material were found on the regulatory lists above. No No No No No CHEMICAL INVENTORIES: AUSTRALIA: All the components of this material are listed on the Australian Inventory of Chemical Substances (AICS). KOREA: All the components of this product are on the Existing Chemicals List (ECL) in Korea. PHILIPPINES: All the components of this product are listed on the Philippine Inventory of Chemicals and Chemical Substances (PICCS). CANADA: All the components of this material are on the Canadian Domestic Substances List (DSL). EUROPEAN UNION: All the components of this material are in compliance with the EU Seventh Amendment Directive 92/32/EEC. UNITED STATES: All of the components of this material are on the Toxic Substances Control Act (TSCA) Chemical Inventory. NEW JERSEY RTK CLASSIFICATION: Under the New Jersey Right-to-Know Act L. 1983 Chapter 315 N.J.S.A.34:5A-1 et. seq., the product is to be indentified as follows: PETROLEUM OIL WHMIS CLASSIFICATION: This product is not considered a controlled product according to the criteria of the Canadian Controlled Products Regulations. Section 16. Other Information NFPA RATINGS: Health: Flammability: 0 1 Reactivity: 0 HMIS RATINGS: Health: Flammability: Reactivity 1 1 0 (0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:-Personal Protection Equipment Index recommendation, *Chronic Effect Indicator). These values are obtained using the guidelines or published evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint and Coating Association (for HMIS ratings). Prepared according to the OSHA Hazard Communication Standard (29 CFR 1910.1200) and the ANSI MSDS Standard (Z400.1). The above information is based on the data of which we are aware and is believed to be correct as of the date hereof. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may suggest modifications of the information, we do not assume any responsibility for the results of it use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose. 3 Date Prepared: July 1, 1992 Date Reviewed: January 8, 2001 MATERIAL SAFETY DATA SHEET Product Name: Acetylene January 8, 2001 1. Chemical, Product and Company Identification Linweld, Inc 9911 Deer Park Road Waverly, NE 68462 Telephone Number Information: (402) 786-3330 Emergency: (402) 786-5277 Product Name: Acetylene Chemical Name: Acetylene Common Names: Acetylene; Ethyne 2. Hazard Ingredients and Identity Information COMPONENT Acetylene Acetone % VOLUME 95.0 to 99.6 Unavailable OSHA-PEL Not Available 1000 ppm TWA ACGIH-TLV Simple Asphyxiant 750 ppm TWA 1000 ppm STEL CAS NUMBER 000074-86-2 000067-64-1 3. Physical and Chemical Characteristics Boiling Point: Melting Point: Vapor Pressure: -118.8o F -116o F 635 psig Specific Gravity: Evaporation Rate: Solubility (H2O): 0.906 N/A Soluble pH: Physical State: N/A Gas Appearance and Odor: Pure acetylene is a colorless gas with an ethereal odor. Commercial (carbide) acetylene has a distinctive garlic-like odor. How to Detect This Substance: N/A Other Physical and Chemical Data: Liquid density at boiling point, 38.8 lb/ft3 (622 kg/m3) Gas density at 70o F 1 atm, 0.0691 lb/ft3 (1.107 kg/m3) 4. Fire and Explosion Hazard Data Flammability Classification: Ignition Temperature: Flammable 565o F Flash Point (F): Method: N/A N/A LEL (%): UEL (%): 2.2 82.5 Extinguishing Media: Carbon dioxide; Dry chemical; Water spray Fire Fighting Procedures: Stop flow of gas before extinguishing fire. If flame is small and originating from fusible plug or valve stem, attempt to extinguish flame. A glove, heavy cloth or any wet material slapped across the flame will frequently extinguish it. If flame is large and originating from fusible plug, do not attempt to extinguish unless cylinder is outdoors or in a well-ventilated area away from sources of ignition. Escaping gas may be easily re-ignited by adjacent ignition sources. Use water spray to keep fire-exposed containers cool. Burning or heated cylinders may rupture violently. Approach fire from upwind to avoid hazardous vapors and toxic decomposition products. Fight fire from protected location or maximum possible distance. Fire & Explosion Hazard: Gaseous acetylene is spontaneously combustible in air at pressure above 30 pi. Acetylene requires very low ignition energy; therefore extinguished fires may easily re-ignite if the flow of gas is not stopped. Acetylene has a density very similar to that of air, so leaking acetylene does not readily dissipate. Gas may travel to an ignition source and flash back. 5. Reactivity Data Stability: Unstable Hazardous Polymerization: May occur Incompatibility: Oxygen and oxidizers including halogens and halogen compounds. Forms explosive acetylide compounds with copper, mercury, silver, brass (>66% copper), and brazing materials containing silver or copper. Page 1 of 4 Product Name: Acetylene January 8, 2001 5. Reactivity Data (Continued) Conditions to Avoid: Do not allow free gas (outside of cylinder) to exceed 30 psi. Cylinders should not be exposed to sudden shock or sources of heat. Hazardous Decomposition or Byproducts: Under high pressure, acetylene decomposes to carbon and hydrogen. Carbon monoxide may be produced from burning. Under certain conditions, acetylene forms acetylide compounds when in contact with copper, silver and mercury. Other Reactivity Data: Flammable over an extremely wide range in air. Explosive reactions may occur on ignition. Reacts explosively with halogens and halogenated compounds. Electrical classification: Class 1, Group A 6. Health Hazard Data Route(s) of Entry: Health Hazards: Acute Chronic Eye contact No Skin Contact No Inhalation Yes Ingestion No Skin Absorption No Product is a simple asphyxiant. Effects of oxygen deficiency may include any, all or none of the following: rapid breathing, diminished mental alertness, impaired muscle coordination, blurred speech, and fatigue. As asphyxiation progresses, nausea, vomiting, and loss of consciousness may occur, eventually leading to convulsions, coma and death. N/A Carcinogenicity: NTP No IARC Monographs No OSHA No Signs and Symptoms of Exposure and Emergency First Aid Procedures: Eye Contact N/A Skin Contact Inhalation N/A Product is a simple asphyxiant. Effects of oxygen deficiency may include any, all or none of the following: rapid breathing, diminished mental alertness, impaired muscle coordination, blurred speech, and fatigue. As asphyxiation progresses, nausea, vomiting, and loss of consciousness may occur, eventually leading to convulsions, coma and death. Under normal operating conditions, acetone is not released from the cylinder. However, if the cylinder is overcharged with acetone or acetylene, acetone may occasionally "spit" out. Acetone is primarily a central nervous system toxin causing headache, nausea, dizziness, vomiting and fatigue. Moderate concentrations may cause respiratory irritation. Conscious victim should be assisted to an uncontaminated area and allowed to inhale fresh air. Unconscious victim should be moved to an uncontaminated area and given assisted respiration with supplemental oxygen. Further treatment should be symptomatic and supportive. Ingestion N/A Medical Conditions Aggravated by Exposure: Persons having health conditions that may be aggravated by exposure to acetylene should not be allowed to work with this product. 7. Precautions for Safe Handling and Use Actions if Released or Spilled: Evacuate all personnel from affected area. Use appropriate personal protective equipment. If possible to do so safely, shut off all ignition sources and close cylinder valve. For small leaks, the cylinder may be moved outdoors and away from ignition sources. If leak is in the user's equipment, be certain to purge piping with inert gas prior to attempting repairs. If leak is in cylinder or cylinder valve, contact the nearest distributor. Page 2 of 4 Product Name: Acetylene January 8, 2001 7. Precautions for Safe Handling and Use (Continued) Waste Disposal Method: Do not attempt to dispose of waste or unused quantities. Return in properly labeled shipping container, with any valve outlet plugs or caps secured and valve protection caps in place. Handling and Storage Precautions: Use only in well-ventilated areas. Valve protection caps must remain in place unless cylinder is secured with valve outlet piped to point of use. Do not drag, slide or roll cylinders. Use a suitable hand truck for cylinder movement. Use a pressure-reducing regulator when connecting cylinder to lower pressure piping or systems. Do not heat cylinder. Use a check valve or trap in the discharge line to prevent hazardous backflow into the cylinder. Protect cylinders from physical damage. Store in cool, dry, well-ventilated area away from heavy traffic areas and emergency exits. Do not allow temperature of cylinder storage area to exceed 125o F. Cylinders should be stored upright and firmly secured to prevent falling or being knocked over. Full and empty cylinders should be segregated. Acetylene cylinders should never be stored on their sides. This makes the acetylene unstable and increases the likelihood of solvent release during use. Do not attempt to repair or alter cylinders. Do not tamper with the valve, pressure relief devices or fusible plugs. If the fusible plug or valve begins to leak, move the cylinder to an open area and contact the nearest distributor. A leaking cylinder should be properly marked to prevent further use. Never allow a torch flame to come in contact with the cylinder or fusible plug. Do not store acetylene within 20 feet of oxygen or combustible materials unless separated by a one-half hour rated 5 feet high firewall. Post "NO SMOKING OR OPEN FLAMES" signs in the storage and use area. Other Precautions: To prevent solvent withdrawal from the cylinder during use, always follow supplier instructions for maximum withdrawal rate for each size of cylinder. Compressed gas cylinders should only be refilled by qualified personnel. Shipment of compressed gas cylinders, which have been filled without the consent of the cylinder owner, is a violation of federal law (49 CFR). Always secure cylinders in an upright position during transportation. Never transport cylinders in enclosed space such as a vehicle truck or van. For additional recommendations, see CGA Pamphlets P-1, G-1, SB-4; NFPA 51; OSHA 1910 Subpart H and Q. Transportation Information: Shipping Name Hazard Class ID Number Shipping Label - 1 NFPA Rating: Health: 0 Acetylene, dissolved 2.1 UN1001 Flammable Gas Flammability: 4 Reactivity: 0 8. Control Measures Eye Protection: Safety goggles or glasses as appropriate. Protective Gloves: PVC or rubber gloves for laboratory use; as required for welding and cutting. Respiratory Protection: Positive pressure air line with mask or self-contained breathing apparatus should be available for emergency use. Ventilation: Local exhaust to prevent acetylene accumulation above the exposure limit and to maintain oxygen concentration above 19.5%. Mechanical ventilation should be designed in accordance with electrical codes. Other Protective Clothing or Equipment: Safety shoes, safety shower. Page 3 of 4 Product Name: Acetylene January 8, 2001 9. Regulatory Information Acetone is regulated as a Hazardous Substance under CERCLA Acetylene is listed under the Clean Air Act (CAA) Section 112(r) with a threshold quantity (TQ) of 10,000 pounds. SARA TITLE III NOTIFICATIONS AND INFORMATION Releases of acetone in quantities equal to or greater than the reportable quantity (RQ) of 5,000 pounds are subject to reporting to the National Response Center under CERCLA, Section 304 SARA Title III. Sara Title III – Section 313 Supplier Notification This product does not contain toxic chemicals subject to reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372. SARA Title III – Hazard Classes Acute Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactivity Hazard Disclaimer of Expressed and Implied Warranties Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained herein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purpose. Page 4 of 4 Date Prepared: July 1, 1992 Date Reviewed: January 8, 2001 MATERIAL SAFETY DATA SHEET Product Name: Acetylene January 8, 2001 1. Chemical, Product and Company Identification Linweld, Inc 9911 Deer Park Road Waverly, NE 68462 Telephone Number Information: (402) 786-3330 Emergency: (402) 786-5277 Product Name: Acetylene Chemical Name: Acetylene Common Names: Acetylene; Ethyne 2. Hazard Ingredients and Identity Information COMPONENT Acetylene Acetone % VOLUME 95.0 to 99.6 Unavailable OSHA-PEL Not Available 1000 ppm TWA ACGIH-TLV Simple Asphyxiant 750 ppm TWA 1000 ppm STEL CAS NUMBER 000074-86-2 000067-64-1 3. Physical and Chemical Characteristics Boiling Point: Melting Point: Vapor Pressure: -118.8o F -116o F 635 psig Specific Gravity: Evaporation Rate: Solubility (H2O): 0.906 N/A Soluble pH: Physical State: N/A Gas Appearance and Odor: Pure acetylene is a colorless gas with an ethereal odor. Commercial (carbide) acetylene has a distinctive garlic-like odor. How to Detect This Substance: N/A Other Physical and Chemical Data: Liquid density at boiling point, 38.8 lb/ft3 (622 kg/m3) Gas density at 70o F 1 atm, 0.0691 lb/ft3 (1.107 kg/m3) 4. Fire and Explosion Hazard Data Flammability Classification: Ignition Temperature: Flammable 565o F Flash Point (F): Method: N/A N/A LEL (%): UEL (%): 2.2 82.5 Extinguishing Media: Carbon dioxide; Dry chemical; Water spray Fire Fighting Procedures: Stop flow of gas before extinguishing fire. If flame is small and originating from fusible plug or valve stem, attempt to extinguish flame. A glove, heavy cloth or any wet material slapped across the flame will frequently extinguish it. If flame is large and originating from fusible plug, do not attempt to extinguish unless cylinder is outdoors or in a well-ventilated area away from sources of ignition. Escaping gas may be easily re-ignited by adjacent ignition sources. Use water spray to keep fire-exposed containers cool. Burning or heated cylinders may rupture violently. Approach fire from upwind to avoid hazardous vapors and toxic decomposition products. Fight fire from protected location or maximum possible distance. Fire & Explosion Hazard: Gaseous acetylene is spontaneously combustible in air at pressure above 30 pi. Acetylene requires very low ignition energy; therefore extinguished fires may easily re-ignite if the flow of gas is not stopped. Acetylene has a density very similar to that of air, so leaking acetylene does not readily dissipate. Gas may travel to an ignition source and flash back. 5. Reactivity Data Stability: Unstable Hazardous Polymerization: May occur Incompatibility: Oxygen and oxidizers including halogens and halogen compounds. Forms explosive acetylide compounds with copper, mercury, silver, brass (>66% copper), and brazing materials containing silver or copper. Page 1 of 4 Product Name: Acetylene January 8, 2001 5. Reactivity Data (Continued) Conditions to Avoid: Do not allow free gas (outside of cylinder) to exceed 30 psi. Cylinders should not be exposed to sudden shock or sources of heat. Hazardous Decomposition or Byproducts: Under high pressure, acetylene decomposes to carbon and hydrogen. Carbon monoxide may be produced from burning. Under certain conditions, acetylene forms acetylide compounds when in contact with copper, silver and mercury. Other Reactivity Data: Flammable over an extremely wide range in air. Explosive reactions may occur on ignition. Reacts explosively with halogens and halogenated compounds. Electrical classification: Class 1, Group A 6. Health Hazard Data Route(s) of Entry: Health Hazards: Acute Chronic Eye contact No Skin Contact No Inhalation Yes Ingestion No Skin Absorption No Product is a simple asphyxiant. Effects of oxygen deficiency may include any, all or none of the following: rapid breathing, diminished mental alertness, impaired muscle coordination, blurred speech, and fatigue. As asphyxiation progresses, nausea, vomiting, and loss of consciousness may occur, eventually leading to convulsions, coma and death. N/A Carcinogenicity: NTP No IARC Monographs No OSHA No Signs and Symptoms of Exposure and Emergency First Aid Procedures: Eye Contact N/A Skin Contact Inhalation N/A Product is a simple asphyxiant. Effects of oxygen deficiency may include any, all or none of the following: rapid breathing, diminished mental alertness, impaired muscle coordination, blurred speech, and fatigue. As asphyxiation progresses, nausea, vomiting, and loss of consciousness may occur, eventually leading to convulsions, coma and death. Under normal operating conditions, acetone is not released from the cylinder. However, if the cylinder is overcharged with acetone or acetylene, acetone may occasionally "spit" out. Acetone is primarily a central nervous system toxin causing headache, nausea, dizziness, vomiting and fatigue. Moderate concentrations may cause respiratory irritation. Conscious victim should be assisted to an uncontaminated area and allowed to inhale fresh air. Unconscious victim should be moved to an uncontaminated area and given assisted respiration with supplemental oxygen. Further treatment should be symptomatic and supportive. Ingestion N/A Medical Conditions Aggravated by Exposure: Persons having health conditions that may be aggravated by exposure to acetylene should not be allowed to work with this product. 7. Precautions for Safe Handling and Use Actions if Released or Spilled: Evacuate all personnel from affected area. Use appropriate personal protective equipment. If possible to do so safely, shut off all ignition sources and close cylinder valve. For small leaks, the cylinder may be moved outdoors and away from ignition sources. If leak is in the user's equipment, be certain to purge piping with inert gas prior to attempting repairs. If leak is in cylinder or cylinder valve, contact the nearest distributor. Page 2 of 4 Product Name: Acetylene January 8, 2001 7. Precautions for Safe Handling and Use (Continued) Waste Disposal Method: Do not attempt to dispose of waste or unused quantities. Return in properly labeled shipping container, with any valve outlet plugs or caps secured and valve protection caps in place. Handling and Storage Precautions: Use only in well-ventilated areas. Valve protection caps must remain in place unless cylinder is secured with valve outlet piped to point of use. Do not drag, slide or roll cylinders. Use a suitable hand truck for cylinder movement. Use a pressure-reducing regulator when connecting cylinder to lower pressure piping or systems. Do not heat cylinder. Use a check valve or trap in the discharge line to prevent hazardous backflow into the cylinder. Protect cylinders from physical damage. Store in cool, dry, well-ventilated area away from heavy traffic areas and emergency exits. Do not allow temperature of cylinder storage area to exceed 125o F. Cylinders should be stored upright and firmly secured to prevent falling or being knocked over. Full and empty cylinders should be segregated. Acetylene cylinders should never be stored on their sides. This makes the acetylene unstable and increases the likelihood of solvent release during use. Do not attempt to repair or alter cylinders. Do not tamper with the valve, pressure relief devices or fusible plugs. If the fusible plug or valve begins to leak, move the cylinder to an open area and contact the nearest distributor. A leaking cylinder should be properly marked to prevent further use. Never allow a torch flame to come in contact with the cylinder or fusible plug. Do not store acetylene within 20 feet of oxygen or combustible materials unless separated by a one-half hour rated 5 feet high firewall. Post "NO SMOKING OR OPEN FLAMES" signs in the storage and use area. Other Precautions: To prevent solvent withdrawal from the cylinder during use, always follow supplier instructions for maximum withdrawal rate for each size of cylinder. Compressed gas cylinders should only be refilled by qualified personnel. Shipment of compressed gas cylinders, which have been filled without the consent of the cylinder owner, is a violation of federal law (49 CFR). Always secure cylinders in an upright position during transportation. Never transport cylinders in enclosed space such as a vehicle truck or van. For additional recommendations, see CGA Pamphlets P-1, G-1, SB-4; NFPA 51; OSHA 1910 Subpart H and Q. Transportation Information: Shipping Name Hazard Class ID Number Shipping Label - 1 NFPA Rating: Health: 0 Acetylene, dissolved 2.1 UN1001 Flammable Gas Flammability: 4 Reactivity: 0 8. Control Measures Eye Protection: Safety goggles or glasses as appropriate. Protective Gloves: PVC or rubber gloves for laboratory use; as required for welding and cutting. Respiratory Protection: Positive pressure air line with mask or self-contained breathing apparatus should be available for emergency use. Ventilation: Local exhaust to prevent acetylene accumulation above the exposure limit and to maintain oxygen concentration above 19.5%. Mechanical ventilation should be designed in accordance with electrical codes. Other Protective Clothing or Equipment: Safety shoes, safety shower. Page 3 of 4 Product Name: Acetylene January 8, 2001 9. Regulatory Information Acetone is regulated as a Hazardous Substance under CERCLA Acetylene is listed under the Clean Air Act (CAA) Section 112(r) with a threshold quantity (TQ) of 10,000 pounds. SARA TITLE III NOTIFICATIONS AND INFORMATION Releases of acetone in quantities equal to or greater than the reportable quantity (RQ) of 5,000 pounds are subject to reporting to the National Response Center under CERCLA, Section 304 SARA Title III. Sara Title III – Section 313 Supplier Notification This product does not contain toxic chemicals subject to reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372. SARA Title III – Hazard Classes Acute Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactivity Hazard Disclaimer of Expressed and Implied Warranties Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained herein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purpose. Page 4 of 4 Page 1 of 1 CHEMetrics, Inc. 4295 Catlett Rd., Calverton, VA 20138 (800) 356-3072 (540) 788-9026 Fax (540) 788-4856 E-mail technical@chemetrics.com 24 Hour Emergency Numbers: Creation Date: Revision Date: (703) 590-9204 (540) 439-3860 04/22/86 (1072-14) 07/22/04 MATERIAL SAFETY DATA SHEET I. CHEMICAL IDENTIFICATION IX. PHYSICAL AND CHEMICAL PROPERTIES TRADE NAMES: DISSOLVED OXYGEN CHEMets®, ULR CHEMets®, and Vacu-vials® STATE: Liquid APPEARANCE: Colorless to pale yellow ODOR: None SOLUBILITY IN WATER: Miscible pH: 11.5 BOILING POINT: 150°C MELTING POINT: -5.0°C VAPOR PRESSURE: N/A SPECIFIC GRAVITY: 1.03 VAPOR DENSITY: N/A CATALOG NOS.: R-7501, R-7501V, R-7511, R-7518, R-7540, R-7540G, R-7540V and R-7553 DESCRIPTION: Reagent ampoules for the determination of dissolved oxygen in water. Each CHEMet™ contains approximately 0.50 mL of liquid reagent sealed under vacuum. Each ULR CHEMet™ contains approximately 1 mL of liquid reagent sealed under vacuum. Each Vacu-vial™ contains approximately 2 mL of liquid reagent sealed under vacuum. X. STABILITY AND REACTIVITY INCOMPATIBILITIES: Acids HAZARDOUS DECOMPOSITION PRODUCTS: When heated to decomposition, oxides of carbon may be emitted. Stable under normal conditions. NFPA RATINGS: HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0 II. COMPOSITION/INFORMATION ON INGREDIENTS COMPONENT: Diethylene Glycol CAS NO.: 111-46-6 PERCENT: XI. TOXICOLOGICAL INFORMATION CARCINOGEN STATUS: None No other data available at this time. 25.0 XII. ECOLOGICAL INFORMATION COMPONENT: Deionized Water CAS NO.: 7732-18-5 PERCENT: >74.0 COMPONENT: Other components CAS NO.: N/A PERCENT: < 1.0 Diethylene Glycol has a low bioconcentration potential and is practically nontoxic to aquatic organisms. No other data available at this time. XIII. DISPOSAL CONSIDERATIONS Any component of this mixture not specifically listed (e.g. "other components") is not considered to present a carcinogen hazard. Dispose of in a manner consistent with Federal, State and Local Regulations. III. HAZARDS IDENTIFICATION XIV. TRANSPORT INFORMATION Harmful if swallowed. ACUTE TOXICITY: Irritation, nausea, diarrhea, nerve depression CHRONIC TOXICITY: Irritation, liver or kidney lesions MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye, skin, liver or kidney disorders Not regulated. XV. REGULATORY INFORMATION EYE AND SKIN CONTACT: Immediately flush eyes and skin with water for 15 minutes. INGESTION: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Seek medical attention. INHALATION: Remove individual to fresh air. EUROPEAN INFORMATION: EU Symbols: Xn - HARMFUL Risk Phrases: Harmful if swallowed. Safety Phrases: If swallowed, seek medical advice immediately (show the label where possible). CANADIAN INFORMATION: WHMIS Classification: D2B All chemical components of this product are listed on Canada’s DSL list. U.S. INFORMATION: All chemical components of this product are listed on the TSCA Inventory. V. FIRE FIGHTING MEASURES XVI. OTHER INFORMATION FLASH POINT: N/A AUTOIGNITION POINT: N/A FLAMMABILITY LIMITS: UPPER: N/A LOWER: N/A EXTINGUISHING MEDIA: Dry chemical, carbon dioxide, water spray or foam VI. ACCIDENTAL RELEASE MEASURES THE ABOVE INFORMATION IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST INFORMATION CURRENTLY AVAILABLE TO US. ALL PRODUCTS ARE OFFERED IN ACCORDANCE WITH THE MANUFACTURER'S CURRENT PRODUCTION SPECIFICATIONS AND ARE INTENDED SOLELY FOR USE IN ANALYTICAL TESTING. THE MANUFACTURER SHALL IN NO EVENT BE LIABLE FOR ANY INJURY, LOSS OR DAMAGE RESULTING FROM THE HANDLING, USE OR MISUSE OF THESE PRODUCTS. Take up with absorbent material. Place in small containers for disposal. CHEMets®, ULR CHEMets® and Vacu-vials® are registered trademarks of CHEMetrics, Inc. IV. FIRST AID MEASURES VII. HANDLING AND STORAGE If this product is used as directed, the user will not come in contact with or be exposed to any of its chemical components. Wash thoroughly after handling. Avoid contact with eyes. Fragile. Liquid in glass. Handle with care. The reagent in these ampoules is light sensitive. Product should be stored in the dark and at room temperature; however, temperatures up to 120°F or even below freezing will not normally affect reagent performance. VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION OSHA PEL & ACGIH TLV: N/A PROTECTIVE EQUIPMENT: Safety glasses B C Page : 1 / 4 SAFETY DATA SHEET Revised edition no : 1 Date : 15/7/2005 Supersedes : 0/0/0 Nitrous oxide (refrigerated) AL093B nó ó t Label 2.2 : Non flammable, non toxic gas. ê O Label 5.1 : Oxidizing substances. O : Oxidizing 1 IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING : : : : Nitrous oxide (refrigerated) AL093B N2O AIR LIQUIDE SA France See paragraph 16 "OTHER INFORMATION" : See paragraph 16 "OTHER INFORMATION" Trade name MSDS No Chemical formula Company identification Emergency phone nr 2 COMPOSITION / INFORMATION ON INGREDIENTS : Substance. Substance / Preparation Substance name Nitrous oxide (refrigerated) : Contents 100 % CAS No 10024-97-2 EC No 233-032-0 Index No ----- Classification O; R8 Contains no other components or impurities which will influence the classification of the product. 3 HAZARDS IDENTIFICATION Hazards identification : Refrigerated liquefied gas. Contact with product may cause cold burns or frostbite. Oxidant. Strongly supports combustion. May react violently with combustible materials. 4 FIRST AID MEASURES First aid measures - Inhalation - Skin/eye contact - Ingestion : In high concentrations may cause asphyxiation. Symptoms may include loss of mobility/consciousness. Victim may not be aware of asphyxiation. In low concentrations may cause narcotic effects. Symptoms may include dizziness, headache, nausea and loss of co-ordination. Remove victim to uncontaminated area wearing self contained breathing apparatus. Keep victim warm and rested. Call a doctor. Apply artificial respiration if breathing stopped. : Immediately flush eyes thoroughly with water for at least 15 minutes. In case of frostbite spray with water for at least 15 minutes. Apply a sterile dressing. Obtain medical assistance. : Ingestion is not considered a potential route of exposure. 5 FIRE-FIGHTING MEASURES Flammable class Specific hazards Hazardous combustion products AIR LIQUIDE SA France : Non flammable. : Exposure to fire may cause containers to rupture/explode. Supports combustion. : If involved in a fire the following toxic and/or corrosive fumes may be produced by thermal decomposition : Nitric oxide/nitrogen dioxide. B C Page : 2 / 4 SAFETY DATA SHEET Revised edition no : 1 Date : 15/7/2005 Supersedes : 0/0/0 Nitrous oxide (refrigerated) AL093B 5 FIRE-FIGHTING MEASURES (continued) Extinguishing media - Suitable extinguishing media Specific methods : All known extinguishants can be used. : If possible, stop flow of product. Move away from the container and cool with water from a protected position. If leaking do not spray water onto container. Water surrounding area (from protected position) to contain fire. Special protective equipment for fire : Use self-contained breathing apparatus and chemically protective clothing. fighters 6 ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Clean up methods : Evacuate area. Ensure adequate air ventilation. Eliminate ignition sources. Wear self-contained breathing apparatus when entering area unless atmosphere is proved to be safe. Use protective clothing. : Try to stop release. Prevent from entering sewers, basements and workpits, or any place where its accumulation can be dangerous. : Ventilate area. Keep area evacuated and free from ignition sources until any spilled liquid has evaporated. (Ground free from frost). 7 HANDLING AND STORAGE Storage Handling : Segregate from flammable gases and other flammable materials in store. Keep container below 50°C in a well ventilated place. : Use no oil or grease. Open valve slowly to avoid pressure shock. Suck back of water into the container must be prevented. Do not allow backfeed into the container. Use only properly specified equipment which is suitable for this product, its supply pressure and temperature. Contact your gas supplier if in doubt. Keep away from ignition sources (including static discharges). Refer to supplier's container handling instructions. 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Personal protection Occupational Exposure Limits : Do not smoke while handling product. Ensure adequate ventilation. Protect eyes, face and skin from liquid splashes. : Nitrous oxide (refrigerated) : TLV© -TWA [ppm] : 50 Nitrous oxide (refrigerated) : OEL (UK)-LTEL [ppm] : 100 Nitrous oxide (refrigerated) : MAK - Germany [ppm] : 100 9 PHYSICAL AND CHEMICAL PROPERTIES Physical state at 20 °C Colour Odo(u)r AIR LIQUIDE SA France : Refrigerated liquefied gas. : Colourless liquid. : Sweetish. Poor warning properties at high concentrations. B C Page : 3 / 4 SAFETY DATA SHEET Revised edition no : 1 Date : 15/7/2005 Supersedes : 0/0/0 Nitrous oxide (refrigerated) AL093B 9 PHYSICAL AND CHEMICAL PROPERTIES (continued) Molecular weight Melting point [°C] Boiling point [°C] Critical temperature [°C] Vapour pressure, 20°C Relative density, gas (air=1) Relative density, liquid (water=1) Solubility in water [mg/l] Flammability range [vol% in air] Auto-ignition temperature [°C] Other data : : : : : : : : : : : 44 -90.81 -88.5 36.4 50.8 bar 1.5 1.2 2.2 Oxidiser. Not applicable. Gas/vapour heavier than air. May accumulate in confined spaces, particularly at or below ground level. 10 STABILITY AND REACTIVITY Stability and reactivity : May react violently with combustible materials. May react violently with reducing agents. Violently oxidises organic material. Thermal decomposition yields toxic products which can be corrosive in the presence of moisture. At temperatures over 575°C and at atmospheric pressure, nitrous oxide decomposes into nitrogen and oxygen. Pressurized nitrous oxide can also decompose at temperatures equal or greater than 300°C. In the presence of catalysts (e.g. halogen products, mercury, nickel, platinum) the rate of decomposition increases and decomposition can occur at even lower temperatures. Nitrous oxide dissociation is irreversible and exothermic, leading to a considerable rise in pressure. Liquid spillages can cause embrittlement of structural materials. 11 TOXICOLOGICAL INFORMATION Toxicity information : No known toxicological effects from this product. 12 ECOLOGICAL INFORMATION Ecological effects information Global warming factor [CO2=1] : Can cause frost damage to vegetation. When discharged in large quantities may contribute to the greenhouse effect. : 310 13 DISPOSAL CONSIDERATIONS General : To atmosphere in a well ventilated place. Do not discharge into any place where its accumulation could be dangerous. Contact supplier if guidance is required. Discharge to atmosphere in large quantities should be avoided. 14 TRANSPORT INFORMATION UN No. H.I. nr ADR/RID AIR LIQUIDE SA France : 2201 : 225 B C Page : 4 / 4 SAFETY DATA SHEET Revised edition no : 1 Date : 15/7/2005 Supersedes : 0/0/0 Nitrous oxide (refrigerated) AL093B 14 TRANSPORT INFORMATION (continued) - Proper shipping name - ADR Class - ADR/RID Classification code - Labelling ADR Other transport information : : : : NITROUS OXIDE, REFRIGERATED LIQUID 2 3O Label 2.2 : Non flammable, non toxic gas. Label 5.1 : Oxidizing substances. : Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency. Before transporting product containers : - Ensure that containers are firmly secured. - Ensure cylinder valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided) is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted. - Ensure there is adequate ventilation. - Compliance with applicable regulations. 15 REGULATORY INFORMATION EC Classification EC Labelling - Symbol(s) - R Phrase(s) - S Phrase(s) : Not included in Annex I. Proposed by the industry. O; R8 : O : Oxidizing : R8 : Contact with combustible material may cause fire. : S9 : Keep container in a well-ventilated place. S17 : Keep away from combustible material. S36 : Wear suitable protective clothing. 16 OTHER INFORMATION Asphyxiant in high concentrations. May cause frostbite. The hazard of asphyxiation is often overlooked and must be stressed during operator training. Ensure all national/local regulations are observed. This Safety Data Sheet has been established in accordance with the applicable European Directives and applies to all countries that have translated the Directives in their national laws. Before using this product in any new process or experiment, a thorough material compatibility and safety study should be carried out. Details given in this document are believed to be correct at the time of going to press. Whilst proper care has been taken in the preparation of this document, no liability for injury or damage resulting from its use can be accepted. Recommended uses and restrictions : This SDS is for information purposes only and is subject to change without notice. [ Prior to purchase of products, please contact your local AIR LIQUIDE office for a complete SDS (with Manufacturer's name and emergency phone number).] End of document AIR LIQUIDE SA France Material Safety Data Sheet: Nitrogen Product Name: Nitrogen CAS: 7727-37-9 Nitrogen; Nitrogen, compressed (D.O.T.) DOT I.D No.: UN 1066 Chemical Name and Synonyms: Nitrogen DOT Hazard Class: Division 2.2 Formula: N2 Chemical Family: Inert Gas HEALTH HAZARD DATA Time Weighted Average Exposure Limit: Nitrogen is defined as a simple asphyxiant (ACGIH 1994-1995i; OSHA 1993 PEL (8 Hr. TWA) = None listed. Symptoms of Exposure: Effects of exposure to high concentrations so as to displace the oxygen in air necessary for life may include any, all or none of the following: • Loss of balance or dizziness • Tightness in the frontal area of the forehead. Toxicological Properties: • Nitrogen is nontoxic but the liberation of a large amount in a confined area could displace the amount of oxygen in air necessary to support life. • Nitrogen is not listed in the LARC, NTP or by OSHA as a carcinogen or potential carcinogen. • Persons in ill health where such illness would be aggravated by exposure to nitrogen should not be allowed to work with or handle this product. Recommended First Aid Treatment: Prompt medical attention is mandatory in all cases of overexposure to nitrogen. Rescue personnel should be equipped with self-contained breathing apparatus. Inhalation: Conscious persons should be assisted to an uncontaminated area and inhale fresh air. Quick removal from the contaminated area is most important. Unconscious persons should be moved to an uncontaminated area, given assisted respiration and supplemental oxygen. Further treatment should be symptomatic and supportive. Hazardous Mixtures of other Liquids, Solids or Gases: None. PHYSICAL DATA Boiling Point: -320.5°F (-195.8°C) Liquid Density at Boiling Point: 4.43 lb/ft3 (70.96 kg/m3) Vapor Pressure @ 70°F (21.1°C) = Above the critical temperature of -232.6°F (-147°C) Gas Density at 70°F. 1 atm .0725 lb/ft3 (1.161 kq/m3) Solubility in Water: Very slightly Freezing Point: -345.9°F (-209.9°C) Evaporation Rate: N/A (Gas) Specific Gravity (AIR=1) @ 70°F (21.1°C) = 0.97 Appearance and Odor: Colorless, odorless gas FIRE AND EXPLOSION HAZARD DATA Flash Point (Method used): N/A Gas Auto Ignition Temperature: N/A Extinguishing Media: Carbon dioxide, dry chemical Flammable Limits % by Volume: LEL N/A UEL N/A Electrical Classification: Nonhazardous Special Fire fighting Procedures: Nonflammable inert gas Unusual Fire and Explosion Hazards: If cylinders are involved in a fire, safely relocate or keep cool with water spray. REACTIVITY DATA Stability: Stable Incompatibility (Materials to Avoid): None Hazardous Decomposition Products: None Hazardous Polymerization: Will not occur Conditions to Avoid: None SPILL OR LEAK PROCEDURES Steps to be taken in case material is released or spilled: Evacuate all personnel from affected area. Use appropriate protective equipment. If leak is in container or container valve, contact your closest supplier location or call the emergency telephone number listed herein. Waste disposal methods: Do not attempt to dispose of waste or unused quantities. Return in the shipping container properly labeled, with any valve outlet plugs or caps secured and valve protection cap in place to your supplier. For emergency disposal assistance, contact your closest supplier location or call the emergency telephone number listed herein. SPECIAL PROTECTION INFORMATION Respiratory Protection (Specify type): Positive pressure air line with mask or selfcontained breathing apparatus should be available for emergency use. Ventilation: See Local Exhaust Protective Gloves: Any material Eye Protection: Safety goggles or glasses Other Protective Equipment: Safety shoes SPECIAL PRECAUTIONS Special Labeling Information: DOT Shipping Name: Nitrogen, Compressed DOT Hazard Class: Division 2.2 DOT Shipping Label: Nonflammable Gas I.D. No.: UN 1066 Special Handling Recommendation: Use only in well-ventilated areas. Valve protection caps must remain in place unless cylinder is secured with valve outlet piped to use point. Do not drag, slide or roll cylinders. Use a suitable hand truck for cylinder movement. Use a pressure reducing regulator when connecting cylinder to lower pressure (<3,000 psig) piping or systems. Do not heat cylinder by any means to increase the discharge rate of product from cylinder. Use a check valve or trap in the discharge line to prevent hazardous back flow into the cylinder. For additional handling recommendations, consult Compressed Gas Association’s Pamphlets P-1, P-9, P-14, and Safety Bulletin SB-2. Special Storage Recommendations: Protect cylinders from physical damage. Store in cool, dry, well-ventilated area away from heavily trafficked areas and emergency exits. Do not allow the temperature where cylinders are stored to exceed 125F (52C). Cylinders should be stored upright and firmly secured to prevent falling or being knocked over. Full and empty cylinders should be segregated. Use a “first in -first out” inventory system to prevent full cylinders being stored for excessive periods of time. For additional storage recommendations, consult Compressed Gas Association’s Pamphlets P-1, P-9, P-14, and Safety Bulletin SB-2. Other Recommendations or Precautions: Compressed gas cylinders should not be refilled except by qualified producers of compressed gases. Shipment of a compressed gas cylinder which has not been filled by the owner or with his (written) consent is a violation of Federal Law (49CFR). Special Packaging Recommendations: Nitrogen is non-corrosive and may be used with any common structural materials. www.isocinfo.com Material Safety Data Sheet: Nitrogen Product Name: Nitrogen CAS: 7727-37-9 Nitrogen; Nitrogen, compressed (D.O.T.) DOT I.D No.: UN 1066 Chemical Name and Synonyms: Nitrogen DOT Hazard Class: Division 2.2 Formula: N2 Chemical Family: Inert Gas HEALTH HAZARD DATA Time Weighted Average Exposure Limit: Nitrogen is defined as a simple asphyxiant (ACGIH 1994-1995i; OSHA 1993 PEL (8 Hr. TWA) = None listed. Symptoms of Exposure: Effects of exposure to high concentrations so as to displace the oxygen in air necessary for life may include any, all or none of the following: • Loss of balance or dizziness • Tightness in the frontal area of the forehead. Toxicological Properties: • Nitrogen is nontoxic but the liberation of a large amount in a confined area could displace the amount of oxygen in air necessary to support life. • Nitrogen is not listed in the LARC, NTP or by OSHA as a carcinogen or potential carcinogen. • Persons in ill health where such illness would be aggravated by exposure to nitrogen should not be allowed to work with or handle this product. Recommended First Aid Treatment: Prompt medical attention is mandatory in all cases of overexposure to nitrogen. Rescue personnel should be equipped with self-contained breathing apparatus. Inhalation: Conscious persons should be assisted to an uncontaminated area and inhale fresh air. Quick removal from the contaminated area is most important. Unconscious persons should be moved to an uncontaminated area, given assisted respiration and supplemental oxygen. Further treatment should be symptomatic and supportive. Hazardous Mixtures of other Liquids, Solids or Gases: None. PHYSICAL DATA Boiling Point: -320.5°F (-195.8°C) Liquid Density at Boiling Point: 4.43 lb/ft3 (70.96 kg/m3) Vapor Pressure @ 70°F (21.1°C) = Above the critical temperature of -232.6°F (-147°C) Gas Density at 70°F. 1 atm .0725 lb/ft3 (1.161 kq/m3) Solubility in Water: Very slightly Freezing Point: -345.9°F (-209.9°C) Evaporation Rate: N/A (Gas) Specific Gravity (AIR=1) @ 70°F (21.1°C) = 0.97 Appearance and Odor: Colorless, odorless gas FIRE AND EXPLOSION HAZARD DATA Flash Point (Method used): N/A Gas Auto Ignition Temperature: N/A Extinguishing Media: Carbon dioxide, dry chemical Flammable Limits % by Volume: LEL N/A UEL N/A Electrical Classification: Nonhazardous Special Fire fighting Procedures: Nonflammable inert gas Unusual Fire and Explosion Hazards: If cylinders are involved in a fire, safely relocate or keep cool with water spray. REACTIVITY DATA Stability: Stable Incompatibility (Materials to Avoid): None Hazardous Decomposition Products: None Hazardous Polymerization: Will not occur Conditions to Avoid: None SPILL OR LEAK PROCEDURES Steps to be taken in case material is released or spilled: Evacuate all personnel from affected area. Use appropriate protective equipment. If leak is in container or container valve, contact your closest supplier location or call the emergency telephone number listed herein. Waste disposal methods: Do not attempt to dispose of waste or unused quantities. Return in the shipping container properly labeled, with any valve outlet plugs or caps secured and valve protection cap in place to your supplier. For emergency disposal assistance, contact your closest supplier location or call the emergency telephone number listed herein. SPECIAL PROTECTION INFORMATION Respiratory Protection (Specify type): Positive pressure air line with mask or selfcontained breathing apparatus should be available for emergency use. Ventilation: See Local Exhaust Protective Gloves: Any material Eye Protection: Safety goggles or glasses Other Protective Equipment: Safety shoes SPECIAL PRECAUTIONS Special Labeling Information: DOT Shipping Name: Nitrogen, Compressed DOT Hazard Class: Division 2.2 DOT Shipping Label: Nonflammable Gas I.D. No.: UN 1066 Special Handling Recommendation: Use only in well-ventilated areas. Valve protection caps must remain in place unless cylinder is secured with valve outlet piped to use point. Do not drag, slide or roll cylinders. Use a suitable hand truck for cylinder movement. Use a pressure reducing regulator when connecting cylinder to lower pressure (<3,000 psig) piping or systems. Do not heat cylinder by any means to increase the discharge rate of product from cylinder. Use a check valve or trap in the discharge line to prevent hazardous back flow into the cylinder. For additional handling recommendations, consult Compressed Gas Association’s Pamphlets P-1, P-9, P-14, and Safety Bulletin SB-2. Special Storage Recommendations: Protect cylinders from physical damage. Store in cool, dry, well-ventilated area away from heavily trafficked areas and emergency exits. Do not allow the temperature where cylinders are stored to exceed 125F (52C). Cylinders should be stored upright and firmly secured to prevent falling or being knocked over. Full and empty cylinders should be segregated. Use a “first in -first out” inventory system to prevent full cylinders being stored for excessive periods of time. For additional storage recommendations, consult Compressed Gas Association’s Pamphlets P-1, P-9, P-14, and Safety Bulletin SB-2. Other Recommendations or Precautions: Compressed gas cylinders should not be refilled except by qualified producers of compressed gases. Shipment of a compressed gas cylinder which has not been filled by the owner or with his (written) consent is a violation of Federal Law (49CFR). Special Packaging Recommendations: Nitrogen is non-corrosive and may be used with any common structural materials. www.isocinfo.com MATERIAL SAFETY DATA SHEET S O S PRODUCTS COMPANY INC PO BOX 47 East Greenville, Pa. 18041 Phone (215)-679-6262 (215)-679-6263 PAGE 1 ----------------------------------------------------------------------------SECTION I - GENERAL INFORMATION ----------------------------------------------------------------------------Product Code: HS Revision Date: 08/06/07 Identification: HOT STOP LIQUID ----------------------------------------------------------------------------SECTION II - HAZARDOUS INGREDIENTS ----------------------------------------------------------------------------This product is not classified as hazardous in accordance with OSHA 1910.1200 ----------------------------------------------------------------------------Carcinogenicity: This product is NOT considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the Occupational Safety and Health Administration. ----------------------------------------------------------------------------SECTION III - PHYSICAL CHARACTERISTICS ----------------------------------------------------------------------------Boiling Point: 230 Specific Gravity: 1.00 Vapor Pressure: 17.00 Melting Point: NOT APPLICABLE Vapor Density: .06 Evaporation Rate: GT 1 Solubility in Water: SOLUBLE Odor and Appearance: ----------------------------------------------------------------------------SECTION IV - FIRE AND EXPLOSION HAZARD DATA ----------------------------------------------------------------------------Flash Point: NOT APPLICABLE LEL: N/A Flammable Limits: NONE VEL: N/A Extinguishing Media: NOT APPLICABLE Special Fire Fighting Procedures: WATER FOG, DRY CHEMICAL. NONE. Unusual Fire and Explosion Hazards: NOT APPLICABLE ----------------------------------------------------------------------------SECTION V - REACTIVITY DATA ----------------------------------------------------------------------------This product is STABLE. Conditions to avoid: NONE Incompatibility: COMPATIBLE Hazardous Decomposition: NONE Hazardous Polymerization: WILL NOT OCCUR ----------------------------------------------------------------------------SECTION VI - HEALTH HAZARD DATA ----------------------------------------------------------------------------Routes of Entry: Inhalation? NO Skin? YES - PRIMARY Ingestion? YES - SECONDARY Health Hazards (Acute and Chronic): NONE KNOWN Carcinogenicity: NTP? NO IARC Monographs? NO OSHA Regulated? NO Signs and Symptoms of Exposure: NONE Medical Conditions Generally Aggravated by Exposure: NONE KNOWN Emergency and First Aid Procedures: EYE: FLUSH 15 MINUTES AND CALL PHYCIAN. SKIN WASH WITH SOAP AND WATER. INGESTION: DO NOT INDUCE VOMITING CALL PHYSICAN ----------------------------------------------------------------------------SECTION VII - HANDLING PRECAUTIONS ----------------------------------------------------------------------------Steps to be Taken if Material is Released or Spilled: FLUSH WITH WATER INTO DRAIN; SOAK UP REMAINDER WITH OBSORBENT FLOOR COMPOUND & SWEEP UP. Waste Disposal Method: NON-HAZARDOUS LANDFILL. COMPLY WITH LOCAL ORDINANCES Precautions to be Taken in Handling and Storage: NONE Other Precautions: NONE ----------------------------------------------------------------------------SECTION VIII - CONTROL MEASURES ----------------------------------------------------------------------------Respiratory Protection: NONE REQUIRED Ventilation Required: LOCAL EXHAUST ADEQUATE Protective Gloves: NOT REQUIRED Eye Protection: SAFETY GOGGLES Other Protective Equipment: NONE REQUIRED FOR NORMAL USE Work/Hygienic Practices: WASH AFTER USING ----------------------------------------------------------------------------The above information pertains to the product as it is currently formulated and is based upon the information available at this time. Additions of reducers or other additives to this product may substantially alter the composition and subsequent hazards of the product. Since conditions of use are outside of our control, we make no warranties, either expressed or implied, and assume no liability in connection with any use of this information. Kidde de México Av. División del Golfo 3308 87019 Cd. Victoria, Tamaulipas, México e-mail: kidde.mexico@kidde.com.mx MATERIAL SAFETY DATA SHEET ABC 90 DRY CHEMICAL POWDER – POLVO QUÍMICO SECO ABC 90 SECTION 1 – CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Trade Name / Label Name: ABC 90% Made to Badger Formulation CAS Number: N/A Chemical Name / Family N/A It is a mixture ABC 90 fire extinguishing powder Multipurpose Fire extinguishing agent KIDDE DE MEXICO, S. A. de C. V. Synonyms: Manufacturer's Name: Business phone / Fax: Av. División del Golfo 3308 Nte. 87019 Cd. Victoria, Tamaulipas, MÉXICO +52 (834) 318-75-00 / +52 (834) 318-75-29 Date of preparation: October 13, 2005 Address: SECTION 2 – COMPOSITION AND INFORMATION ON INGREDIENTS CAS N° % w/w OSHA PEL mg/m3 ACGIH TLV mg/m3 TOXICITY DATA Monoammonium phosphate 7722-76-1 92 - 94 NONE NONE NONE Mica 12001-26-2 1–3 3 3 NONE Attapulgus clay 8031-18-3 2-4 NONE NONE NONE Amorphous silica 7631-86-9 0.2 – 1.5 6 10 NONE Methyl Hydrogen Polysiloxane 63148-57-2 0.4 – 1.0 NONE NONE NONE CHEMICAL NAME SECTION 3 – PHYSICAL AND CHEMICAL CHARACTERISTICS Boiling point, °C: Vapor pressure, mm Hg: Vapor density (Air=1): Reactivity in water: Document: GT05310 N/A N/A N/A Unreactive Specific gravity (H20=1) Percent volatile by volume: Evaporation rate (Butyl acetate=1) Appearance and odor: ABOUT 1.9 Viscosity @ 20°C: N/A N/A Melting point, °C: NDA N/A Solubility in water: 22.7 g/100g Odorless, pale yellow coloured fine powder Issuing date: 13/10/05 Document: GT05310 Page 2 of 3 SECTION 4 – FIRE AND EXPLOSION HAZARD DATA Flash point: Flammable limits in air, % by volume N/A N/A Auto-ignition temperature: Extinguishing media: N/A – The product is a fire extinguishing agent Unusual fire and explosion hazards: NONE Special fire fighting procedures: N/A The material is a fire extinguishing agent and will not burn. However, if other materials are involved, use standard chemical fire fighting procedures and consider the hazards of those materials. In enclosed areas, fire fighters must wear self-contained breathing apparatus and full protective equipment. SECTION 5 – REACTIVITY DATA Stability: Stable Incompatibility (materials to avoid): Hazardous decomposition products: Conditions to avoid: Extreme heat Hazardous polymerization: Will not occur Strong alkalis. Do not mix with BC type dry chemical extinguishing agents. Ammonia, phosphorus oxides. SECTION 6 – HEALTH HAZARD DATA Threshold limit value: Routes of entry: Signs and symptoms of overexposure: Medical conditions generally aggravated by exposure: Chemical listed as carcinogen or potential: Emergency and first aid procedures: ACGIH TLV for particulates not otherwise classified: 10 mg/m3 OSHA PEL for nuisance dust limit total: 15 mg/m3 Inhalation: YES; may be irritant to the respiratory tract. Eye contact: YES; mildly irritant for a short period. Skin contact: YES; may be mildly irritating. Ingestion: NOT an expected route of entry. Acute: Transient cough, shortness of breath, irritation of airways. Chronic: This product is not known to cause chronic illness. Asthma, emphysema, bronchitis or other respiratory illness. NTP program: No IARC monographs: No OSHA: No Eye contact: Flush with large amounts of water for at least 15 minutes. If irritation persists, seek medical attention. Skin contact: Wash with soap and water. If irritation persists, seek medical attention. Inhalation: Move victim to fresh air. Seek medical attention if discomfort continues. Ingestion: Rinse mouth, drink large amounts of water and induce vomiting. Seek medical help. SECTION 7 – SPECIAL PRECAUTIONS AND SPILL / LEAK PROCEDURES Precautions to be taken in handling and storage: Should be stored in original containers. Store in dry, cool, well-ventilated place away from alkaline compounds. Wash after handling. Do not cut, grind, weld or drill on or near product containers. Treat empty containers as if they were full. Other precautions: Do not mix with alkaline materials. Steps to be taken in case materials is released or spilled: Waste disposal method: Direction of Operations Sweep up or vacuum. Store in covered containers. Do not reuse. In case of large spills, use rubber gloves, chemically resistant suit and boots, hard hat and air purifying respirator. Dispose of in compliance with local, state and federal regulations. Components are non hazardous, sanitary landfill disposal may be acceptable Issuing date: 13/10/05 Document: GT05310 Page 3 of 3 SECTION 8 – SPECIAL PROTECTION INFORMATION Respiratory protection: Dust mask where dustiness is prevalent or TLV exceeded. Mechanical filter respirator if exposure is prolonged. Ventilation: Use adequate ventilation. Use fan or vent to outside. Protective gloves: Wear rubber gloves for routine industrial use. Eye protection: Recommended as mechanical barrier for prolonged exposure. Safety glasses or chemical type goggles. Other protective equipment: If irritation occurs, long sleeves and impervious gloves should be worn. Work / Hygienic practices: Use good personal hygiene and good housekeeping practices. Avoid breathing of dust. Wash with soap and water. SECTION 9 – REGULATORY INFORMATION U.S. OSHA HAZARD COMMUNICATION STANDARD RCRA INFORMATION SARA Reporting Requirements TSCA Inventory status Product assessed in accordance with OSHA 20 CFR 1910.1200 and determined not to be hazardous. The unused product, in our opinion, is not specifically listed by the EPA as hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrosivity or reactivity, and is not formulated with contaminants as determined by the toxicity characteristics leaching procedure (TCLP). However, used product may be regulated. No component of this product is subject to the reporting requirements of Sections 302, 304 and 313 of Title III of the Superfund Amendments and Reauthorization Act. Kidde de México certifies that the product described herein complies with all applicable rules or orders under TSCA and no chemical substance for entry in violation under TSCA or any applicable rule or order thereunder TSCA is being offered. HAZARDOUS MATERIAL IDENTIFICATION SYSTEM RATINGS HEALTH: 1 HAZARD INDEX: 0 Minimal hazard 1 Slight hazard 2 Moderate hazard 3 Serious hazard 4 Sever hazard FLAMMABILITY: 0 REACTIVITY: 0 GENERAL KEYS: N/A: Not applicable. NDA: No data available. The information herein is given in good faith. It is based on available data and is believed to be true and accurate, but no warranty, expressed or implied, is made. Therefore, KIDDE DE MEXICO. assumes NO responsibility for damage or injury from the use of the product described herein. Direction of Operations Issuing date: 13/10/05 Kidde de México Av. División del Golfo 3308 87019 Cd. Victoria, Tamaulipas, México e-mail: kidde.mexico@kidde.com.mx MATERIAL SAFETY DATA SHEET ABC 90 DRY CHEMICAL POWDER – POLVO QUÍMICO SECO ABC 90 SECTION 1 – CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Trade Name / Label Name: ABC 90% Made to Badger Formulation CAS Number: N/A Chemical Name / Family N/A It is a mixture ABC 90 fire extinguishing powder Multipurpose Fire extinguishing agent KIDDE DE MEXICO, S. A. de C. V. Synonyms: Manufacturer's Name: Business phone / Fax: Av. División del Golfo 3308 Nte. 87019 Cd. Victoria, Tamaulipas, MÉXICO +52 (834) 318-75-00 / +52 (834) 318-75-29 Date of preparation: October 13, 2005 Address: SECTION 2 – COMPOSITION AND INFORMATION ON INGREDIENTS CAS N° % w/w OSHA PEL mg/m3 ACGIH TLV mg/m3 TOXICITY DATA Monoammonium phosphate 7722-76-1 92 - 94 NONE NONE NONE Mica 12001-26-2 1–3 3 3 NONE Attapulgus clay 8031-18-3 2-4 NONE NONE NONE Amorphous silica 7631-86-9 0.2 – 1.5 6 10 NONE Methyl Hydrogen Polysiloxane 63148-57-2 0.4 – 1.0 NONE NONE NONE CHEMICAL NAME SECTION 3 – PHYSICAL AND CHEMICAL CHARACTERISTICS Boiling point, °C: Vapor pressure, mm Hg: Vapor density (Air=1): Reactivity in water: Document: GT05310 N/A N/A N/A Unreactive Specific gravity (H20=1) Percent volatile by volume: Evaporation rate (Butyl acetate=1) Appearance and odor: ABOUT 1.9 Viscosity @ 20°C: N/A N/A Melting point, °C: NDA N/A Solubility in water: 22.7 g/100g Odorless, pale yellow coloured fine powder Issuing date: 13/10/05 Document: GT05310 Page 2 of 3 SECTION 4 – FIRE AND EXPLOSION HAZARD DATA Flash point: Flammable limits in air, % by volume N/A N/A Auto-ignition temperature: Extinguishing media: N/A – The product is a fire extinguishing agent Unusual fire and explosion hazards: NONE Special fire fighting procedures: N/A The material is a fire extinguishing agent and will not burn. However, if other materials are involved, use standard chemical fire fighting procedures and consider the hazards of those materials. In enclosed areas, fire fighters must wear self-contained breathing apparatus and full protective equipment. SECTION 5 – REACTIVITY DATA Stability: Stable Incompatibility (materials to avoid): Hazardous decomposition products: Conditions to avoid: Extreme heat Hazardous polymerization: Will not occur Strong alkalis. Do not mix with BC type dry chemical extinguishing agents. Ammonia, phosphorus oxides. SECTION 6 – HEALTH HAZARD DATA Threshold limit value: Routes of entry: Signs and symptoms of overexposure: Medical conditions generally aggravated by exposure: Chemical listed as carcinogen or potential: Emergency and first aid procedures: ACGIH TLV for particulates not otherwise classified: 10 mg/m3 OSHA PEL for nuisance dust limit total: 15 mg/m3 Inhalation: YES; may be irritant to the respiratory tract. Eye contact: YES; mildly irritant for a short period. Skin contact: YES; may be mildly irritating. Ingestion: NOT an expected route of entry. Acute: Transient cough, shortness of breath, irritation of airways. Chronic: This product is not known to cause chronic illness. Asthma, emphysema, bronchitis or other respiratory illness. NTP program: No IARC monographs: No OSHA: No Eye contact: Flush with large amounts of water for at least 15 minutes. If irritation persists, seek medical attention. Skin contact: Wash with soap and water. If irritation persists, seek medical attention. Inhalation: Move victim to fresh air. Seek medical attention if discomfort continues. Ingestion: Rinse mouth, drink large amounts of water and induce vomiting. Seek medical help. SECTION 7 – SPECIAL PRECAUTIONS AND SPILL / LEAK PROCEDURES Precautions to be taken in handling and storage: Should be stored in original containers. Store in dry, cool, well-ventilated place away from alkaline compounds. Wash after handling. Do not cut, grind, weld or drill on or near product containers. Treat empty containers as if they were full. Other precautions: Do not mix with alkaline materials. Steps to be taken in case materials is released or spilled: Waste disposal method: Direction of Operations Sweep up or vacuum. Store in covered containers. Do not reuse. In case of large spills, use rubber gloves, chemically resistant suit and boots, hard hat and air purifying respirator. Dispose of in compliance with local, state and federal regulations. Components are non hazardous, sanitary landfill disposal may be acceptable Issuing date: 13/10/05 Document: GT05310 Page 3 of 3 SECTION 8 – SPECIAL PROTECTION INFORMATION Respiratory protection: Dust mask where dustiness is prevalent or TLV exceeded. Mechanical filter respirator if exposure is prolonged. Ventilation: Use adequate ventilation. Use fan or vent to outside. Protective gloves: Wear rubber gloves for routine industrial use. Eye protection: Recommended as mechanical barrier for prolonged exposure. Safety glasses or chemical type goggles. Other protective equipment: If irritation occurs, long sleeves and impervious gloves should be worn. Work / Hygienic practices: Use good personal hygiene and good housekeeping practices. Avoid breathing of dust. Wash with soap and water. SECTION 9 – REGULATORY INFORMATION U.S. OSHA HAZARD COMMUNICATION STANDARD RCRA INFORMATION SARA Reporting Requirements TSCA Inventory status Product assessed in accordance with OSHA 20 CFR 1910.1200 and determined not to be hazardous. The unused product, in our opinion, is not specifically listed by the EPA as hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corrosivity or reactivity, and is not formulated with contaminants as determined by the toxicity characteristics leaching procedure (TCLP). However, used product may be regulated. No component of this product is subject to the reporting requirements of Sections 302, 304 and 313 of Title III of the Superfund Amendments and Reauthorization Act. Kidde de México certifies that the product described herein complies with all applicable rules or orders under TSCA and no chemical substance for entry in violation under TSCA or any applicable rule or order thereunder TSCA is being offered. HAZARDOUS MATERIAL IDENTIFICATION SYSTEM RATINGS HEALTH: 1 HAZARD INDEX: 0 Minimal hazard 1 Slight hazard 2 Moderate hazard 3 Serious hazard 4 Sever hazard FLAMMABILITY: 0 REACTIVITY: 0 GENERAL KEYS: N/A: Not applicable. NDA: No data available. The information herein is given in good faith. It is based on available data and is believed to be true and accurate, but no warranty, expressed or implied, is made. Therefore, KIDDE DE MEXICO. assumes NO responsibility for damage or injury from the use of the product described herein. Direction of Operations Issuing date: 13/10/05 MATERIAL SAFETY DATA SHEET Section 1. Chemical product and company identification Product Name: Synonym: Manufacturer: Internet Address: Address: Super D Dry Powder Extinguishant Class D Powder AMEREX CORPORATION www.amerex-fire.com 7595 Gadsden Highway P.O. Box 81 Trussville, AL 35173-0081 (205) 655-3271 Chemtrec 1(800) 424-9300 or (703) 527–3887 December, 2003 Telephone: Emergency Contacts: Revised: Section 2. Hazard identification and emergency overview Emergency overview: Off-white, fine solid powder, odorless. Adverse health effects and symptoms: Moderate irritant to the respiratory system and eyes; mild irritant to the skin. Symptoms may include stinging of eyes and abraded skin, coughing, shortness of breath, and irritation of the lungs, eyes, and skin. Exposure guidelines: Ingredients Sodium chloride Mica Attapulgite clay Mineralite (Zeolite) Magnesium stearate OSHA PEL ACGIH TLV DFG MAK * PNOC** Total dust, 15 mg/m3 Respirable fraction, 5 mg/m3 PNOC Total dust, 10 mg/m3 Respirable fraction, 3 mg/m3 20 mppcf*** PNOC Total dust, 15 mg/m3 Respirable fraction, 5 mg/m3 3 mg/m3 respirable fraction PNOC Total dust, 10 mg/m3 Respirable fraction, 3 mg/m3 PNOC Total dust, 4 mg/m3 Respirable fraction, 1.5 mg/m3 ------PNOC Total dust, 4 mg/m3 Respirable fraction, 1.5 mg/m3 4 mg/m3 10 mg/m3 80 mg/m3 % SiO2 PNOC PNOC Total dust, 15 mg/m3 Total dust, 10 mg/m3 3 Respirable fraction, 5 mg/m Respirable fraction, 3 mg/m3 Page 1 of 7 Pages SUPER – D PNOC Total dust, 4 mg/m3 Respirable fraction, 1.5 mg/m3 Silica, amorphous (fumed) PNOC Total dust, 15 mg/m3 Respirable fraction, 5 mg/m3 2 mg/m3 0.3 mg/m3 *German regulatory limits **PNOC = Particulates not otherwise classified (ACGIH) also known as Particulates not otherwise regulated (OSHA) *** mppcf = million particles per cubic foot. All values are 8 hour time weighted average concentrations. Hazard symbols: WHMIS (Canadian workplace hazardous materials identification system) D2B may irritate eyes, mucous membranes, or skin Section 3. Composition/information on ingredients Name/Compound Weight % CAS # Sodium chloride evaporated flour grade 87 7647-14-5 Attapulgite clay or Fullers earth magnesium aluminum silicatecontains > 1% crystalline silica 4.2 12174-11-7 Mica potassium aluminum silicate 4.2 12001-26-2 Zeolite, synthetic amorphous precipitated silica 2.1 112926-00-8 Silica, amorphous, fumed <2 69012-64-2 Magnesium stearate octadecanoic acid, Mg salt <1 557-04-0 14808-60-7 Section 4. First Aid Measures Eye Exposure: Irrigate eyes at eye wash station and repeat until pain free. Seek medical attention if irritation develops or persists, or if visual changes occur. Skin Exposure: In case of contact, wash with plenty of soap and water. Seek medical attention if irritation develops or persists. Page 2 of 7 Pages SUPER – D Inhalation: If respiratory irritation or distress occurs remove victim to fresh air. Seek medical attention if irritation develops or persists. Ingestion: Not known to present an ingestion hazard. Medical conditions possibly aggravated by exposure: Inhalation of product may aggravate existing chronic respiratory problems such as asthma, emphysema, or bronchitis. Skin contact may aggravate existing skin disease. Chronic overexposure may cause pneumoconiosis (“dusty lung” disease). Section 5. Fire fighting measures Extinguishing media: non combustible and non flammable – product is an extinguishing agent Unusual fire/explosion hazards: none known Insensitive to mechanical impact or static discharge. HMIS Hazard Ranking: health = 1, flammability = 0, reactivity = 0, personal protective equipment: use N-95 dust mask (see Section 8) Section 6. Accidental release measures Clean up released material using vacuum or wet sweep and shovel to minimize generation of dust. Wear appropriate respiratory protection. Bag and drum for disposal. If product is used and/or contaminated, use PPE and containment appropriate to the nature of the mixture. Section 7. Handling and storage Avoid skin, eye, or respiratory exposure. Use appropriate PPE when handling or maintaining equipment, and wash thoroughly after handling (see Section 8). Keep product in original container or extinguisher. Contents may be under pressure – inspect for extinguisher rust periodically to insure container integrity. Do not mix with other extinguishing agents. Page 3 of 7 Pages SUPER – D Section 8. Exposure controls/ personal protection During the application of this product against fires, exhaust gases and the products of incomplete combustion (PICs) are the principal respiratory hazards. In the manufacture of extinguishers, automated systems and point source ventilation controls sufficiently minimize respiratory exposure. Employers and employees must use their collective judgment in determining occupational settings where the use of a dust mask or air purifying respirator is prudent. The need for respiratory protection is not likely for short-term use in well ventilated areas. Respiratory protection: use N95 dust mask for limited exposure, use air-purifying respirator (APR) with high efficiency particulate air (HEPA) filters for prolonged exposure. Eye protection: wear chemical goggles Skin protection: use nitrile, latex, or similar gloves and coveralls. Good personal hygiene practices essential, such as avoiding food, tobacco products, or other hand-tomouth contact when handling. Wash thoroughly after handling. Section 9. Physical and chemical properties Appearance: off-white powder, finely divided odorless solid. Specific gravity: ~ 1.0 Solubility: product is coated, not immediately soluble in water Non –flammable Flash point: none Vapor pressure: < 1 mm Hg pH: approximately 7 for a 10% solution Boiling point: not applicable No explosive or oxidizing properties Section 10. Stability and reactivity Stability: stable Incompatibles: strong acids and strong oxidizers like bleach. Page 4 of 7 Pages SUPER – D Decomposition products: heat of fire may release chlorine compounds and oxides of sodium. Possibility of hazardous reactions: none Section 11. Toxicological information Acute toxicity: Sodium chloride LD50 (rat): oral, 3000 mg/kg body weight, LD50 (mouse): oral, 4000 mg/kg body weight, LDLo (lowest lethal dose) (rat): subcutaneous, 3500 mg/kg body weight, LDLo (dog): intraperitoneal, 364 mg/kg body weight. Target organs in man: None. While an essential nutrient, sodium chloride is a mild irritant to epithelial tissue, (eyes, mucous membranes, skin) and may aggravate dermatitis. No information was found indicating the product causes sensitization. Chronic toxicity: This product’s ingredients are not considered as “probable” or “suspected” carcinogens by OSHA, IARC, or ACGIH. Pneumoconiosis, or “dusty lung” disease, may result from chronic exposure to any dust. Reproductive toxicity: This product’s ingredients are not known to have reproductive or teratogenic effects. Section 12. Ecological information Ecotoxicity: negative effects unknown. Persistence/ Degradability: degrades slowly in humid/wet environment Bioaccummulation: extent unknown Mobility in soil: insoluble coating, poor mobility Page 5 of 7 Pages SUPER – D Section 13. Disposal considerations This product is not a RCRA characteristically hazardous or listed hazardous waste. Dispose of according to state or local laws, which may be more restrictive than federal laws or regulations. Used product may be altered or contaminated, creating different disposal considerations. Section 14. Transportation information This product is not defined as a hazardous material under U.S. Department of Transportation (DOT) 49 CFR 172, or by Transport Canada “Transportation of Dangerous Goods” regulations. Section 15. Regulatory information International Inventory Status: All ingredients are on the following inventories Country(ies) United States of America Canada Europe Australia Japan South Korea Agency TSCA DSL EINECS/ELINCS AICS MITI KECL Status Yes Yes Yes Yes Yes Yes European Risk and Safety phrases: EU Classification: R Phrases: S Phrases: Irritant 20 36/37 22 24/25 26 Harmful by inhalation. Irritating to eyes, respiratory system. Do not breathe dust. Avoid contact with skin and eyes In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Page 6 of 7 Pages SUPER – D U.S. federal regulatory information: None of the chemicals in this product are under SARA reporting requirements or have SARA threshold planning quantities (TPQs) or CERCLA reportable quantities (RQs), or are regulated under TSCA 8(d). State regulatory information: Chemicals in this product are covered under specific State regulations, as denoted below: Alaska - Designated Toxic and Hazardous Substances: None California – Permissible Exposure Limits for Chemical Contaminants: None Florida – Substance List: Mica Dust Illinois – Toxic Substance List: None Kansas – Section 302/303 List: None Massachusetts – Substance List: Mica Dust Minnesota – List of Hazardous Substances: None Missouri – Employer Information/Toxic Substance List: None New Jersey – Right to Know Hazardous Substance List: None North Dakota – List of Hazardous Chemicals, Reportable Quantities: None Pennsylvania – Hazardous Substance List: None Rhode Island – Hazardous Substance List: Mica Dust Texas – Hazardous Substance List: No West Virginia – Hazardous Substance List: None Wisconsin – Toxic and Hazardous Substances: None California Proposition 65: No component is listed on the California Proposition 65 list. _____________________________________________________________________ Section 16. Other information This MSDS conforms to requirements under U.S., U.K., Canadian, Australian, and EU regulations or standards, and conforms to the proposed 2003 ANSI Z400.1 format. The information herein is given in good faith but no warranty, expressed or implied, is made. Updated by Lindsay R. Hill, CIH Page 7 of 7 Pages SUPER – D MATERIAL SAFETY DATA SHEET Kidde 55 Multi-Purpose Dry Chemical (Fire Extinguishing Agent) 1. PRODUCT AND COMPANY IDENTIFICATION Product Name Other Trade Names Manufacturer/Supplier Address Phone Number Chemtrec Number (for emergencies only) Revision Date: MSDS Date: Kidde 55 Multi –Purpose Dry Chemical (Fire Extinguishing Agent) ABC, Ammonium Phosphate, Monoammonium Phosphate Kidde – Residential and Commercial A United Technologies Company 1016 Corporate Park Drive Mebane, NC 27302 USA (919) 304-8200 (919) 563-5911 (800) 424-9300 (703) 527-3887 (International) August 7, 2007 January 15, 2007 This MSDS has been compiled in accordance with - EC Directive 91/155/EC - OSHA's Hazcom Standard (29 CFR 1910.1200) 2. 3. COMPOSITION/INFORMATION ON THE COMPONENTS Component Name Monoammonium Phosphate CAS#/Codes Concentration R Phrases 7722-76-1 55 - 65% None EC#2317645 EU Classification None Ammonium Sulfate 7783-20-2 30 - 40% EC#2319841 None None Mica Clay 12001-26-2 8031-18-3 None None None None Amorphous Silica 7631-86-9 <2% EC#2315454 None None Dye NA None None 1 - 4% <2% <0.1% HAZARD IDENTIFICATION EU Main Hazards Non Hazardous Powder Routes of Entry - Eye contact - Inhalation - Skin contact Carcinogenic Status See Section 11 - Toxicity Target Organs - Respiratory System - Skin - Eye Health Effects - Eyes Contact for short periods of time may cause irritation. Health Effects - Skin Contact may cause mild irritation. Revision Date: August 7, 2007 Page 1 of 6 MATERIAL SAFETY DATA SHEET Kidde 55 Multi-Purpose Dry Chemical (Fire Extinguishing Agent) 3. HAZARD IDENTIFICATION Health Effects - Ingestion Ingestion is not an expected route of exposure. Health Effects - Inhalation May irritate the respiratory tract. May cause transient cough and shortness of breath. 4. FIRST AID MEASURES Eyes Immediately flood the eye with plenty of water of warm water for at least 15 minutes, holding the eye open. Obtain medical attention if soreness or redness persists. Skin Wash affected area with soap and water. Obtain medical attention if irritation persists. Ingestion Dilute by drinking large quantities of water and obtain medical attention. Inhalation Move victim to fresh air. Obtain medical attention immediately for any breathing difficulty. Advice to Physicians Treat symptomatically. 5. FIRE FIGHTING MEASURES Extinguishing Media This preparation is used as an extinguishing agent and therefore is not a problem when trying to control a blaze. Use extinguishing agent appropriate to other materials involved. Keep pressurized extinguishers and surroundings cool with water spray as they may rupture or burst in the heat of a fire. Unusual Fire and Explosion Hazards Pressurized containers may explode in heat of fire. Protective Equipment for Fire-Fighting Wear full protective clothing and self-contained breathing apparatus as appropriate for specific fire conditions. 6. ACCIDENTAL RELEASE MEASURES Sweep up or vacuum. Prevent skin and eye contact. Wear appropriate protective equipment. 7. HANDLING AND STORAGE Pressurized extinguishers should be properly stored and secured to prevent falling or being knocked over. Do not drag, slide or roll extinguishers. Do not drop extinguishers or permit them to strike against each other. Never apply flame or localized heat directly to any part of the extinguisher or plastic container. Store pressurized extinguishers and plastic containers away from high heat sources. Storage area should be: - cool - dry - well ventilated - under cover - out of direct sunlight Revision Date: August 7, 2007 Page 2 of 6 MATERIAL SAFETY DATA SHEET Kidde 55 Multi-Purpose Dry Chemical (Fire Extinguishing Agent) 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Standards Occupational exposure limits are listed below, if they exist. Mica ACGIH TLV: 3 mg/m3 TWA, measured as respirable fraction of the aerosol. OSHA PEL: 20 mppcf, <1% crystalline silica Nuisance Dust Limit OSHA PEL: 50 mppcf or 15 mg/m3 TWA, total dust 15 mppcf or 5 mg/m3 TWA, respirable fraction Engineering Control Measures Use with adequate ventilation. There should be local procedures for the selection, training, inspection and maintenance of this equipment. When used in large volumes, use local exhaust ventilation. Respiratory Protection Not normally required. Use dust mask where dustiness is prevalent, or TLV is exceeded. Hand Protection Not normally needed when used as a portable fire extinguisher. Use gloves if irritation occurs. Eye Protection Chemical goggles or safety glasses with side shields. Body Protection Normal work wear. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Color Odor Specific Gravity Boiling Range/Point (°C/F) Flash Point (PMCC) (°C/F) Solubility in Water Vapor Density (Air = 1) Vapor Pressure Evaporation Rate 10. Powder Pale Yellow Odorless Not available Not applicable Not Flammable Not applicable Heavier than air. Not applicable Not applicable STABILITY AND REACTIVITY Stability Stable under normal conditions. Conditions to Avoid - Heat - High temperatures - Exposure to direct sunlight Materials to Avoid - Strong oxidizing agents - strong acids - sodium hypochlorite Revision Date: August 7, 2007 Page 3 of 6 MATERIAL SAFETY DATA SHEET Kidde 55 Multi-Purpose Dry Chemical (Fire Extinguishing Agent) 10. STABILITY AND REACTIVITY Hazardous Polymerization Will not occur. Hazardous Decomposition Products - oxides of carbon - ammonia – oxides of phosphorus – nitrogen oxides 11. TOXICOLOGICAL INFORMATION Acute Toxicity Low order of acute toxicity. Chronic Toxicity/Carcinogenicity This product is not expected to cause long term adverse health effects. Mica and clay may contain small quantities of quartz (crystalline silica) as an impurity. Prolonged exposure to respirable crystalline silica dust at concentrations exceeding the occupational exposure limits may increase the risk of developing a disabling lung disease known as silicosis. IARC found limited evidence for pulmonary carcinogenicity of crystalline silica in humans. Genotoxicity This product is not expected to cause any mutagenic effects. Reproductive/Developmental Toxicity This product is not expected to cause adverse reproductive effects. 12. ECOLOGICAL INFORMATION Mobility No relevant studies identified. Persistence/Degradability No relevant studies identified. Bio-accumulation No relevant studies identified. Ecotoxicity No relevant studies identified. 13. DISPOSAL Dispose of container in accordance with all applicable local and national regulations. Do not cut, puncture or weld on or near to the container. No harm to the environment is expected from this preparation. 14. TRANSPORT INFORMATION DOT CFR 172.101 Data UN Proper Shipping Name UN Class UN Number UN Packaging Group Revision Date: August 7, 2007 Not regulated Not regulated None None None Page 4 of 6 MATERIAL SAFETY DATA SHEET Kidde 55 Multi-Purpose Dry Chemical (Fire Extinguishing Agent) 15. REGULATORY INFORMATION EU Label Information Classification and labelling have been performed according to EU directives 67/548/EEC and 99/45/EC including amendments. EU Hazard Symbol and Indication of Danger. This preparation is not classified as dangerous. R phrases None S phrases None. US REGULATIONS (Federal, State) and INTERNATIONAL CHEMICAL REGISTRATION LAWS TSCA Listing This product contains ingredients that are listed on or exempt from listing on the EPA Toxic Substance Control Act Chemical Substance Inventory. EINECS Listing All ingredients in this product have not been verified for listing on the European Inventory of Existing Commercial Chemical Substances (EINECS) or the European List of New Chemical Substances (ELINCS). DSL/NDSL (Canadian) Listing All ingredients in this product are listed on the Domestic Substance List (DSL) or the Non-Domestic Substance List (NDSL) or are exempt from listing. WHMIS Classification D2B This product was classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations and the MSDS contains all the information required by these regulations. MA Right To Know Law All components have been checked for inclusion on the Massachusetts Substance List (MSL). Those components present at or above the de minimus concentration include: - Mica (12001-26-2) 1-4% Amorphous Silica (7631-86-9) <2% - Ammonium Sulfate (7783-20-2) 30 - 40% PA Right To Know Law This product contains the following chemicals found on the Pennsylvania Hazardous Substance List: Mica (12001-26-2) 1-4% - Amorphous Silica (7631-86-9) <2% - Ammonium Sulfate (7783-20-2) 30 - 40% NJ Right To Know Law This product contains the following chemicals found on the NJ Right To Know Hazardous Substance List: - Mica (12001-26-2) 1-4% - Amorphous Silica (7631-86-9) <2% California Proposition 65 This product does not contain materials which the State of California has found to cause cancer, birth defects or other reproductive harm. SARA Title III Sect. 302 (EHS) This product does not contain any chemicals subject to SARA Title III Section 302. SARA Title III Sect. 304 This product does not contain any chemicals subject to SARA Title III Section 304. Revision Date: August 7, 2007 Page 5 of 6 MATERIAL SAFETY DATA SHEET Kidde 55 Multi-Purpose Dry Chemical (Fire Extinguishing Agent) 15. REGULATORY INFORMATION SARA Title III Sect. 311/312 Categorization - Immediate (Acute) Health Hazard SARA Title III Sect. 313 This product does not contain any chemicals that are listed in Section 313 at or above de minimis concentrations. 16. OTHER INFORMATION NFPA Ratings NFPA Code for Health - 1 NFPA Code for Flammability - 0 NFPA Code for Reactivity - 0 NFPA Code for Special Hazards - None HMIS Ratings HMIS Code for Health - 1 HMIS Code for Flammability - 0 HMIS Code for Reactivity - 0 HMIS Code for Personal Protection - See Section 8 Abbreviations N/A: Denotes no applicable information found or available CAS#: Chemical Abstracts Service Number ACGIH: American Conference of Governmental Industrial Hygienists OSHA: Occupational Safety and Health Administration TLV: Threshold Limit Value PEL: Permissible Exposure Limit STEL: Short Term Exposure Limit NTP: National Toxicology Program IARC: International Agency for Research on Cancer R: Risk S: Safety EnviroNet LLC. Prepared By: The information contained herein is based on data believed to be accurate. However, no representation, warranty, or guarantee is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for its own particular use. Badger Fire Protection assumes no responsibility for personal injury or property damage resulting from use, handling or from contact with this product. Revision Date: August 7, 2007 Page 6 of 6 MATERIAL SAFETY DATA SHEET #KFFM010 ABC Multipurpose Dry Chemical Fire Extinguisher Section 1 – NAME & HAZARD SUMMARY Material Name: DRY CHEMICAL Multipurpose Ammonium Phosphate Supplier Name and Address: Kidde Fire Fighting 150 Gordon Drive · P.O. Box 695 Exton, PA 19341-0695 USA Phone: (610) 363-1400 · Fax: (610) 524-9073 www.Kidde-Fire.com Section 2 – INGREDIENTS Material name: Siliceous Muscovite Mica, Mica OSHA PEL: 20 MPPCF* ACGIH TLV: 20 MPPCF* Other Exposure Limits: None CAS No.: 12001-26-2 *Million particles per cubic foot Section 3 – PHYSICAL DATA Boiling Point: NA Specific Gravity (H2O = 1): 1.80 Vapor Pressure (mm Hq): NA Vapor Density (Air -1): NA Solubility In Water: Slightly water soluble Appearance and Odor: Yellow powder, odorless Melting Point: 374° Fahrenheit Section 4 – FIRE & EXPLOSION HAZARD Flash Point: Noncombustible Method Used: NA Flammable Limits in Air, % by Volume: LEL Lower: NA; UEL Upper: NA Auto-Ignition Temperature: NA Extinguisher Media: NA, This material is a fire extinguisher agent KFFM010 Page 1 of 2 6/1/04 Special Fire Fighting Procedures: NA Unusual Fire and Explosion Hazards: NA Section 5 – REACTIVITY DATA Stability: Stable Conditions to Avoid: NA Incompatibility (Materials to Avoid): Do not mix with different types of dry chemical extinguishing agents Hazardous Polymerization: Will Not Occur Conditions to Avoid: NA Section 6 – HEALTH HAZARD ASSESSMENT Acute: Transient cough, Irritation of airways, and shortness of breath Chronic: Pneumonconiosis Signs and Symptoms of Exposure: Coughing and irritation of airways Medical Conditions Generally Aggravated by Exposure: Asthma, Bronchitis, or other respiratory illness Chemical Listed as Carcinogen or Potential Carcinogen: N/A Emergency and First Aid Procedures: Move victims to fresh air. Wash affected area with soap and water. Flush from eyes with large amounts of water for at least 15 minutes. Seek medical attention if necessary. Routes of Entry: Inhalation, Eyes, Skin, Ingestion Section 7 – SPILL OR LEAK PROCEDURES Precautions to be Taken in Handling and Storage: Multipurpose (ABC) Dry Chemical should be stored in original container or in sealed extinguishers. Other Precautions: None Steps to be Taken in Case Material is Released or Spilled: Sweep up. Store in covered containers. Do not reuse. Section 8 – SPECIAL PROTECTION INFORMATION Respiratory Protection: Dust respirator approved by NIOSH/MSHA schedule TC-ZIC Ventilation: NA Local Exhaust: NA Mechanical General: NA Special: NA Other: NA Protective Gloves: Sensitive individuals should wear gloves Eye Protection: Safety glasses are recommended Other Protective Clothing or Equipment: NA Work/Hygienic Practices: Avoid breathing of dust. Wash off with soap and water. The information herein is given in good faith but no warranty, expressed or implied, is made. KFFM010 Page 2 of 2 6/1/04 MATERIAL SAFETY DATA SHEET S O S PRODUCTS COMPANY INC P. O. Box 47 East Greenville, Pa. 18041 Phone (215-679)-6262 (215)-679-6263 SECTION I PAGE 1 Product Code: Identification: - GENERAL WG8 / WGP WAX GASKET INFORMATION Revision Date: 08/06/07 SECTION II - HAZARDOUS INGREDIENTS This product is not classified as hazardous in accordance with OSHA 1910.1200 Carcinogenicity: This product is NOT considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the Occupational Safety and Health Administration. SECTION III - PHYSICAL CHARACTERISTICS Boiling Point: < 650o F Specific Gravity: .85 Vapor Pressure: 0.01 Melting Point: 140o-170o F. Vapor Density: N/A Evaporation Rate: N/A Solubility in Water: NEGLIGIBLE Odor and Appearance: AMBER WAXY SOLID WITH TYPICAL PETROLEUM WAX ODOR SECTION IV - FIRE AND EXPLOSION HAZARD Flash Point: 500o F. COC LEL: N/A Flammable Limits: NOT DETERMINED UEL: N/A Extinguishing Media: DRY CHEMICAL, FOAM, FIRE EXTINGUISHER Special Fire Fighting Procedures: USE WATER SPRAY, DRY CHEMICAL FOAM, OR CARBON DIOXIDE. WATER OR FOAM MAY CAUSE FROTHING. WATER MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL. USE PROTECTIVE CLOTHING WHEN ENTERING CONFINED AREAS WITH WAX FIRES. Unusual Fire and Explosion Hazards: WHEN HEATED ABOVE FLASH POINT, FLAMMABLE VAPORS COULD BE RELEASED WHICH COULD BURN IN CONFINED AREAS. SECTION V This product is STABLE. Conditions to avoid: Incompatibility: - REACTIVITY DATA HIGH HEAT, TEMPERATURES OVER 160 DEG F. STRONG OXIDIZING AGENTS Hazardous Decomposition: BY OPEN FLAME: CARBON DIOXIDE & CARBON MONOXIDE Hazardous Polymerization WILL NOT OCCUR. Routes of Entry: SECTION VI - HEALTH HAZARD DATA Inhalation? NO Skin? YES - SECONDARY Ingestion? YES - SECONDARY Health Hazards (Acute and Chronic): NONE KNOWN Carcinogenicity: NTP? IARC Monographs? OSHA Regulated? Signs and Symptoms of Exposure: NO NO NO NONE Medical Conditions Generally Aggravated by Exposure: NONE KNOWN Emergency and First Aid Procedures: SKIN: WASH WITH SOAP & WATER THOROUGHLY. EYES: FLUSH 15 MINUTES WITH WATER. INGESTION: MAY CAUSE IRRITATION OF DIGESTIVE TRACT. QUANTITY, CALL PHYSICIAN. IF LARGE SECTION VII - HANDLING PRECAUTIONS Steps to be Taken if Material is Released or Spilled: REPLACE INTO CONTAINER AND PACKAGE APPROPRIATELY FOR DISPOSAL. FOR MOLTEN MATERIAL, ABSORB WITH SAND OR INERT ABSORBENT AND NOTIFY STATE AND LOCAL AGENCIES. Waste Disposal Method: WAX- COMPLY WITH FEDERAL, STATE AND LOCAL REGULATIONS. Precautions to be Taken in Handling and Storage: STORE IN A COOL, DRY LOCATION. TO PREVENT MELTING OR DEFORMING DO NOT STORE OVER 110o F. Other Precautions: NONE SECTION VIII - CONTROL MEASURES Respiratory Protection: NONE REQUIRED FOR NORMAL USE. Ventilation Required: ADEQUATE VENTILATION Protective Gloves: NONE REQUIRED FOR NORMAL USE. Eye Protection: WEAR SAFETY GLASSES Other Protective Equipment: NONE Work/Hygienic Practices: USE GOOD PERSONAL HYGIENE PRACTICES. The above information pertains to the product as it is currently formulated and is based upon the information available at this time. Additions of reducers or other additives to this product may substantially alter the composition and subsequent hazards of the product. Since conditions of use are outside of our control, we make no warranties, either expressed or implied, and assume no liability in connection with any use of this information. MATERIAL SAFETY DATA SHEET S O S PRODUCTS COMPANY INC P. O. Box 47 East Greenville, Pa. 18041 Phone (215-679)-6262 (215)-679-6263 SECTION I PAGE 1 Product Code: Identification: - GENERAL WG8 / WGP WAX GASKET INFORMATION Revision Date: 08/06/07 SECTION II - HAZARDOUS INGREDIENTS This product is not classified as hazardous in accordance with OSHA 1910.1200 Carcinogenicity: This product is NOT considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the Occupational Safety and Health Administration. SECTION III - PHYSICAL CHARACTERISTICS Boiling Point: < 650o F Specific Gravity: .85 Vapor Pressure: 0.01 Melting Point: 140o-170o F. Vapor Density: N/A Evaporation Rate: N/A Solubility in Water: NEGLIGIBLE Odor and Appearance: AMBER WAXY SOLID WITH TYPICAL PETROLEUM WAX ODOR SECTION IV - FIRE AND EXPLOSION HAZARD Flash Point: 500o F. COC LEL: N/A Flammable Limits: NOT DETERMINED UEL: N/A Extinguishing Media: DRY CHEMICAL, FOAM, FIRE EXTINGUISHER Special Fire Fighting Procedures: USE WATER SPRAY, DRY CHEMICAL FOAM, OR CARBON DIOXIDE. WATER OR FOAM MAY CAUSE FROTHING. WATER MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL. USE PROTECTIVE CLOTHING WHEN ENTERING CONFINED AREAS WITH WAX FIRES. Unusual Fire and Explosion Hazards: WHEN HEATED ABOVE FLASH POINT, FLAMMABLE VAPORS COULD BE RELEASED WHICH COULD BURN IN CONFINED AREAS. SECTION V This product is STABLE. Conditions to avoid: Incompatibility: - REACTIVITY DATA HIGH HEAT, TEMPERATURES OVER 160 DEG F. STRONG OXIDIZING AGENTS Hazardous Decomposition: BY OPEN FLAME: CARBON DIOXIDE & CARBON MONOXIDE Hazardous Polymerization WILL NOT OCCUR. Routes of Entry: SECTION VI - HEALTH HAZARD DATA Inhalation? NO Skin? YES - SECONDARY Ingestion? YES - SECONDARY Health Hazards (Acute and Chronic): NONE KNOWN Carcinogenicity: NTP? IARC Monographs? OSHA Regulated? Signs and Symptoms of Exposure: NO NO NO NONE Medical Conditions Generally Aggravated by Exposure: NONE KNOWN Emergency and First Aid Procedures: SKIN: WASH WITH SOAP & WATER THOROUGHLY. EYES: FLUSH 15 MINUTES WITH WATER. INGESTION: MAY CAUSE IRRITATION OF DIGESTIVE TRACT. QUANTITY, CALL PHYSICIAN. IF LARGE SECTION VII - HANDLING PRECAUTIONS Steps to be Taken if Material is Released or Spilled: REPLACE INTO CONTAINER AND PACKAGE APPROPRIATELY FOR DISPOSAL. FOR MOLTEN MATERIAL, ABSORB WITH SAND OR INERT ABSORBENT AND NOTIFY STATE AND LOCAL AGENCIES. Waste Disposal Method: WAX- COMPLY WITH FEDERAL, STATE AND LOCAL REGULATIONS. Precautions to be Taken in Handling and Storage: STORE IN A COOL, DRY LOCATION. TO PREVENT MELTING OR DEFORMING DO NOT STORE OVER 110o F. Other Precautions: NONE SECTION VIII - CONTROL MEASURES Respiratory Protection: NONE REQUIRED FOR NORMAL USE. Ventilation Required: ADEQUATE VENTILATION Protective Gloves: NONE REQUIRED FOR NORMAL USE. Eye Protection: WEAR SAFETY GLASSES Other Protective Equipment: NONE Work/Hygienic Practices: USE GOOD PERSONAL HYGIENE PRACTICES. The above information pertains to the product as it is currently formulated and is based upon the information available at this time. Additions of reducers or other additives to this product may substantially alter the composition and subsequent hazards of the product. Since conditions of use are outside of our control, we make no warranties, either expressed or implied, and assume no liability in connection with any use of this information. Friday, April 21, 2006 Page 1 of 7 MSDS - Material Safety Data Sheet Product Name: C-12 CPVC Cement MSDS No.: 018750 Part Numbers Covered: 018750-24 018752-24 018760-24 018762-24 018770-12 018772-12 018780-12 018782-12 018790 1. Basic Information: Manufacturer: WILLIAM H. HARVEY COMPANY 4 Address: 4334 SOUTH 67TH STREET City, ST Zip: OMAHA, NE 68117-1019 2 1 Emergency Contact: CHEMTREC Emergency Telephone Number: (800)424-9300 Contact: Information Telephone Number Information Telephone Number: (800)228-9681 Last Update: 04/21/2006 Chemical State: Chemical Type: X 2 4 Expiration Date: Liquid Gas Pure X 1 Solid G Mixture 2. Ingredients: Trade Secret EHS IARC NTP SARA 313 OSHA SUB Z PEL ACGIH TLV Other Limits CAS No. Chemical Name % Range 68648-82-8 CPVC RESIN 10 - 20 NI 10 MG/M3 NI 108-94-1 CYCLOHEXANONE 5 - 15 25 PPM 25 PPM NI 112945-52-5 FUMED SILICA 1-5 5 mg/m3 3 mg/m3 NI 78-93-3 METHYL ETHYL KETONE 20 - 30 200 PPM 200 PPM NI 109-99-9 TETRAHYDROFURAN 40 - 48 200 PPM 50 PPM NI 3. Hazardous Identification: Hazard Category: X Acute X Chronic X Fire Pressure Reactive Hazardous Identification Information: HAZARDS OVERVIEW: Clear orange colored, moderately viscous liquid with a distinct and penetrating odor. Extremely flammable liquid and vapor. Vapors may cause flash fire. May cause eye and skin irritation. Inhalation of vaors or mists may cause respiratory irritation and central nervous system effects. Ingestion may cause irritation, nausea, vomiting, diarrhea and kidney and liver disorders. May be fatal if swallowed. Aspiration hazard. Symptoms may be delayed. Friday, April 21, 2006 Page 2 of 7 MSDS - Material Safety Data Sheet Product Name: C-12 CPVC Cement MSDS No.: 018750 4. First Aid Measures: Route(s) of Entry: EYES: Liquid causes severe irritation. Vapors cause slight to moderate irritation. SKIN: Liquid or vapors may cause severe irritation. INHALATION: May cause nose and throat irritation, headache, nausea, vomiting, drowsiness and incoordination. INGESTION: Swallowing may cause irritation, nausea, vomiting, diarrhea and kidney and liver disorders. May be fatal if swallowed. TARGET ORGANS: Eyes, Skin, Lungs, Kidney, Liver, Central Nervous System. Health Hazards (Acute and Chronic): ACUTE: Severe skin irritant. Fast skin penetrant. Not expected to be a sensitizer. Eye irritant. Inhalation hazard. Overexposure may cause coughing, shortness of breath, dizziness, vomiting, central nervous system depression, intoxication, and collapse. Ingestion hazard. May produce symptoms of nervous system depression including headache, dizziness, nausea, loss of sense of balance, drowsiness, and visual disturbances. CHRONIC: Prolonged or repeated eye contact may cause conjunctivitis. Prolonged or repeated skin contact may cause defatting and dermatitis. May cause liver and kidney damage. May cause reproductive and fetal effects May cause lung damage. Narcotic in high concentrations. Signs and Symptoms: See HEALTH HAZARDS above. Medical Conditions Generally Aggravated by Exposure: AGGRAVATION OF EXISTING CONDITIONS: Persons with pre-existing skin disorders or eye problems or impaired liver or kidney function may be more susceptible to the effects of the substance. Emergency and First Aid Procedures: FOR EMERGENCY FIRST AID HELP CALL 1-303-623-5716 COLLECT. SKIN CONTACT: Immediately wash skin with soap and water while removing contaminated clothing and shoes. Remove dried cement with HARVEY'S POWER SCRUB HAND CLEANER or baby oil. Launder clothing before reuse. Seek medical attention if irritation persists. EYES: Liquid: Immediately flush with plenty of water for 5 minutes. Remove contacts if present and continue flushing with water while holding eyelids open with thumb and index finger for 15 minutes. Seek medical attention if irritation develops or persists. Vapors: If vapors cause irritation, move to fresh air and flush eyes as above. Seek medical attention if irritation develops or persists. INHALATION: Move to fresh air. Give oxygen if breathing is difficult. Give artificial respiration if required. Call a physician or poison control center (1-303-623-576 collect) immediately. INGESTION: DO NOT INDUCE VOMITING. Rinse mouth with water. Never give anything by mouth to a person who is unconscious or drowsy. Get immediate medical attention by calling a Poison Control Center (1-303-623-5716 Collect), or hospital emergency room. If medical advice cannot be obtained, then take the person and product to the nearest medical emergency treatment center or hospital. Other Health Warnings: NI Friday, April 21, 2006 Page 3 of 7 MSDS - Material Safety Data Sheet Product Name: C-12 CPVC Cement MSDS No.: 018750 5. Fire Fighting Measures: Flash Point: 0 - 6 ºF Lower Explosive Limit: 1.1 %by vol. Upper Explosive Limit: 11.8 %by vol F.P. Method: TCC Fire Extinguishing Media: Use dry chemical, CO2, or foam to extinguish fire. Cool fire exposed container with water. Water may be ineffective as an extinguishing agent. Special Fire Fighting Procedures: Firefighters should wear positive pressure self contained breathing apparatus and full protective clothing for fires in areas where chemicals are used or stored. Unusual Fire and Explosion: Extremely flammable liquid. Keep away from heat and all sources of ignition including sparks, flames, lighted cigarettes and pilot lights. containers may rupture or explode in the heat of a fire. Vapors are heavier than air and may travel to a remote ingition source and flash back. This product contains Tetrahydrofuran that may form explosive organic peroxides when exposed to air or light or with age. Combustion will produce toxic and irritating vapors including carbon monoxide and carbon dioxide. 6. Accidental Release Measures: Steps to be Taken in Case Material is Released or Spilled: Remove all sources of ignition and ventilate area. Stop leak if it can be done without risk. Prevent liquid from entering watercourses, natural waterways, drainage collection areas or sewers. Personnel cleaning up the spill should wear appropriate Ppersonal Protective Equipment, including respirators if vapor concentrations are high. Soak up spill with an inert absorbent such as sand, earth or other non-combusting material. Put spent absorbent material in covered, labeled metal containers. See Section XIII for disposal information. Report releases to proper authorities as required. 7. Handling and Storage: Precautions to be Taken: HANDLING: Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists. Use with adequate ventilation (equivalent to outdoors). Wash thoroughly after handling. do not eat, drink or smoke in the work area. Keep product away from heat, sparks, flames and all other sources of ignition. No smoking in use or storage areas. Keep containers closed when not in use. STORAGE: Store in a cool, dry, well ventilated area away from incompatable materials. Keep containers closed when not in use. Other Precautions: "Empty" containers can retain product residue and can be hazardous. Follow all MSDS precations in handling empty containers. Do not cut or weld on or near empty or full containers. Prevent prolonged or repeated breathing of vapors released during application process. Reports have associated repeated and prolonged overexposure to solvents with permanent brain damage and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. 8. Exposure Controls/Personal Protection: Ventilation Requirements: GENERAL MECHANICAL: Exhaust ventilation capable of maintaining emissions at the point of use below OSHA PEL. LOCAL EXHAUST: Open doors & windows. If used in an enclosed area, use exhaust fans. Exhaust fans should be explosion-proof or set up in a way that flammable concentrations of vapors are not exposed to electrical fixtures or hot surfaces. Personal Protective Equipment: Friday, April 21, 2006 Page 4 of 7 MSDS - Material Safety Data Sheet Product Name: C-12 CPVC Cement MSDS No.: 018750 RESPIRATORY PROTECTION: For operations where the exposure limits may be exceeded, a NIOSH approved organic vapor respirator or supplied air respirator is recommended. Equipment selection depends on the contaminant type and concentration. Select in accordance with 29 CFR 1910.134 and good industrial hygiene practice. For firefighting, use self-contained breathing apparatus. EYE PROTECTION: Safety glasses with side shields or safety goggles. SKIN PROTECTION: Rubber gloves are adequate for normal use of the product. For long exposures to the substance, chemical resistant gloves may be required to avoid prolonged exposure. OTHER PROTECTION: An eye wash and safety shower should be available in the work area. 9. Physical and Chemical Properties: Boiling Point: 155 ºF Melting Point: NA Evaporation Rate (Butyl Acetate = 1): 3.7 - 8.0 Vapor Pressure (mm Hg.): ~ 157 Specific Gravity (H20 = 1): 0.95000 Vapor Density (AIR = 1): ~ 2.5 Solubility In Water: Negligible Appearance and Odor: Clear orange colored, moderately viscous liquid with Ether-like odor Other Information: Specific Gravity = ~.95 10. Stability and Reactivity: Stability: Stable. Incompatibility (Materials to Avoid): Oxidizing agents, alkalis, amines, ammonia, acids, chlorine compounds, chlorinated inorganics (potassium, calcium and sodium hypochlorite) and hydrogen peroxides. May attack plastic and rubber compounds. Decomposition/By Products: Burning can produce carbon monoxide, carbon dioxide, water, cyanide, hydrogen cyanide, and vapors of chemicals listed in Section II. Hazardous Polymerization: Will not occur. 11. Toxicological Information: Friday, April 21, 2006 Page 5 of 7 MSDS - Material Safety Data Sheet Product Name: C-12 CPVC Cement MSDS No.: 018750 THIS PRODUCT IS TOXIC BY INGESTION. MAY CAUSE NARCOSIS, GASTRIC INJURY OR DEATH. CHRONIC TOXICITY: Prolonged or reapeated overexposure can cause dermatitis and damage to the kidney, liver, lungs and central nervous system. TOXICITY DATA: Cyclohexanone: Oral rat LD50: 1,620 mg/kg. Inhalation rat LC50: 8,000 ppm/4 hours Skin rabbit: 1 mL/kg Methyl Ethyl Ketone: Oral rat LD50: 2,737 mg/kg. Inhalation rat LC50: 23,500 mg/m3/8 hours Skin rabbit: 6480 mg/kg Tetrahydrofuran: Oral rat LD50: 1,650 mg/kg Inhalation rat LC50: 21,000 ppm/ 3 hours CPVC Resin: No toxicity studies have been conducted on this product. As with all chemicals for which test data are limited or do not exist, caution must be exercised through the prudent use of protective equipment and handling procedures to minimize exposure. SENSITIZATION: None of the components are known to cause sensitization. CARCINOGENICITY: None of the components are listed as a carcinogen or suspect cacinogen by NTP, IARC or OSHA. The NTP has reported that exposure of mice and rats to Tetrahydrofuran vapor levels up to 1800 ppm 6 hr/day, 5 days/week for their lifetime caused an increased incidence of kidney tumors in male rats and liver tumors in female mice. The significance of these findings for human health is unclear at this time, and may be related to "species specific" effects. Elevated incidences of tumors in humans have not been reported for Tetrahydrofuran. ACGIH has classified Cyclohexanone and Tetrahydrofuran as "A3", Confirmed Animal Carcinogen with Unknown Relevance to Humans. MUTAGENICITY: Cyclohexanone has been positive in bacterial and mammalian assays. Methyl Ethyl Ketone and Tetrahydrofuran are generally thought not to be mutagenic. REPRODUCTIVE TOXICITY: Methyl Ethyl Ketone and Cyclohexanone have been shown to cause embryofetal toxicity and birth defects in laboratory animals. Tetrahydrofuran have been found to cause adverse developmental effects only when exposure levels cause othe toxic effects to the mother. 12. Ecological Information: THIS PRODUCT IS NOT EXPECTED TO BE TOXIC TO AQUATIC ORGANISMS. Cyclohexanone: 96 hour LC50 values for fish is over 100mg/L. Methyl Ethyl Ketone: 96 hour LC50 values for fish is over 100mg/L. Tetrahydrofuran: 96 hour LC50 for fathead minnow: 2160 mg/L. VOC Information: This product emits VOC's (Volatile Organic Compounds) in its use. Make sure that use of this product complies with local VOC emission regulations, where they exist. VOC Content (as manufactured): 776 grams/liter 13. Disposal Considerations: Friday, April 21, 2006 Page 6 of 7 MSDS - Material Safety Data Sheet Product Name: C-12 CPVC Cement MSDS No.: 018750 DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. RCRA Hazardous Waste Number: U057, U159, U213 EPA Hazardous Waste ID Number: D001, D035, F003, F005 EPA Hazardous Waste Class: Ignitable Waste. Toxic Waste (Methyl Ethyl Ketone content) 14. Transport Information: DOT (DEPARTMENT OF TRANSPORTATION) U.S.: Proper Shipping Name: Less than 1 Liter = Consumer Commodity 1 Liter or Greater = Adhesives, Containing Flammable Liquid Hazard Class/Packing Group: Less than 1 Liter = ORM-D 1 Liter or Greater = 3, PGII UN/NA Number: Less than 1 Liter = None 1 Liter or Greater = UN1133 Hazard Labels: Less than 1 Liter = None 1 Liter or Greater = Flammable Liquid INTERNATIONAL MARITIME DANGEROUS GOODS: Proper Shipping Name: Flammable Liquid, N.O.S. Limited Quantity Hazard Class/Packing Group: 3, II UN Number: UN1993 Label: None (Limited Quantities are excepted from labeling) 2004 NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER: 128 15. Regulatory Information: Friday, April 21, 2006 Page 7 of 7 MSDS - Material Safety Data Sheet Product Name: C-12 CPVC Cement MSDS No.: 018750 SARA, Section 311 / 312, Hazard Category: Acute Health Chronic Health Flammable SARA, Section 302, Extremely Hazardous Substances: This product does not contain chemical regulated under SARA Section 302. SARA, Section 313, Toxic Chemical: This product does not contains any chemical subject to SARA Title III, Section 313 reporting requirements: CERCLA 103, Reportable Quantity: Spills of this product over the RQ (reportable quantity) must be reported to the National Response Center; The RQ for the product, based on the RQ for Methyl Ethyl Ketone (100% maximum) of 5,000 lbs. is 5,000 lbs. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. CALIFORNIA PROPOSITON 65: This product contains trace amounts of chemicals known to the State of California to cause cancer. Under normal use conditions, exposure to these chemicals at levels above the State of California "No Significant Risk Level" (NSRL) are unlikely. The Willliam H. Harvey Company strongly recommends and encourages the proper selection and use of Personal Protective Equipment and engineered ventilation noted in Section VIII of this MSDS. TSCA INVENTORY: All of the components of this product are listed on the TSCA inventory. CANADIAN WHIMS CLASSIFICATION: Class B, Division 2; Class D, Division 2, Subdivision A. This product has been classified in accordance with the hazard criteria of the Conrtrolled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. 16. Other Information: KEEP AWAY FROM HEAT SPARK AND FLAMES AT ALL TIMES. STORE IN A COOL DRY PLACE. ABBREVIATIONS: ~ = Approximately < = Less Than > = Greater Than ACGIH = American Conference of Governmental Industrial Hygienists AIHA = American Industrial Hygiene Association C = Degrees Celcius CERCLA = The Comprehensive Environmental Response, Compensation, and Liability Act Deg = Degrees EPA = Environmental Protection Agency F = Degrees Farenheit HMIS = Hazardous Materials Information System IARC = International Agency for Research on Cancer NA = Not Applicable NDA = No Data Available NE = Not Established NFPA = National Fire Protection Association NI = Not Indicated NIOSH = National Institure of Occupational Safety and Health NTP= National Toxicology Program OSHA = Occupational Safety and Health Administration SARA = Superfund Amendment and Reauthorization Act DISCLAIMER: The information herein has been compiled from sources believed to be reliable, up-to-date, and is accurate to the best of our knowledge. However, the William H. Harvey Company cannot give any guarantees regarding information from other sources, and expressly does not make warranties, nor assumes any liability for its uses. PIPE JOINT COMPOUND 80-067 HMIS RATING Health 2 Flammability 3 Reactivity 0 NFPA 704 RATING MATERIAL SAFETY DATA SHEET Kimball-Midwest P.O. Box 2470 Columbus, OH 43216-2470 Corporate telephone: 614-219-6100 Emergency Telephone: 800-424-9300 Health 2 Flammability 3 Reactivity 0 NFPA 30B LEVEL N/A 1. PRODUCT IDENTIFICATION PART NUMBER............................. 80-067 PRODUCT NAME.......................... LOCTITE PIPE JOINT COMPOUND, 30556 CHEMICAL FAMILY....................... N/A DOT SHIPPING.............................. Consumer Commodity ORM-D 2. HAZARDOUS INGREDIENTS Specific Chemical Identity, Common Names OSHA PEL ACGIH TLV STEL Clay (1332-58-7) 15mg/m3 2mg/m3 None Vegetable Oil (68187-84-8) None None None Rosin (8050-09-7) None None None Isopropyl alcohol (67-63-0) 200ppm 200ppm 400ppm Talc (14807-96-6) 20mppcf 2mg/m3 3ppm Carbon, black (133-86-4) 3.5mg/m3 3.5mg/m3 None Silica, quartz (14808-60-7) 0.1mg/m3 .05mg/m3 None % 30-60 10-30 10-30 10-30 1-5 0.1-1 0.1-1 All chemical compounds marked with an asterisk (*) are toxic chemicals subject to the reporting of Section 313 of Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372. You must notify each person to whom this mixture of trade name product is sold. This statement must not be detached. Any copy or redistribution of this Material Safety Data Sheet shall include this statement. **Ceiling 3. PHYSICAL DATA BOILING POINT (RANGE)...................................>149°C to (300°F) VAPOR PRESSURE PSIG @ 68°F...................... 33mmHg VAPOR DENSITY (AIR = 1).................................. Heavier than air SOLUBILITY IN WATER....................................... Partial SPECIFIC GRAVITY (H2O = 1)............................ 1.37 MELTING/FREEZING POINT............................... N/A EVAPORATION RATE (61%=1)........................... Not available VOC content (by weight)....................................... 15.2% APPEARANCE AND ODOR................................. Dark Brown Viscous liquid/ Alcoholic Odor 4. FIRE AND EXPLOSION DATA FLASH POINT....................................................... 76°F TCC UPPER EXPLOSIVE LIMIT (%)............................ 12.7 LOWER EXPLOSIVE LIMIT (%)........................... 2.3 EXTINGUISHING MEDIA...................................... Foam, dry chemical, CO2 SPECIAL FIREFIGHTING PROCEDURES........... As in any fire, wear self-contained breathing apparatus pressure-demand (MSHA/ NIOSH approved or equivalent) and full protective gear. HAZARDOUS COMBUSTION PRODUCTS......... Alehydes. Oxides of carbon. Carboxylic acids. Irritating organic carbon. 5. HEALTH EFFECTS DATA SHORT TERM EFFECTS OF EXPOSURE ROUTE OF ENTRY...............Skin absorption, Inhalation, Eye contact, Ingestion HEALTH HAZARDS (ACUTE AND CHRONIC)......May cause allergic skin reaction, may cause eye, skin and respiratory tract irritation. May be harmful if swallowed. EYE CONTACT.....................May cause irritation. Redness. Swelling. Stinging. INGESTION...........................Not expected to be harmful by ingestion. INHALATION.........................May cause to nose and throat. SKIN CONTACT....................May cause skin irritation. May cause allergic skin reaction. Burning Sensation. Redness MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE Eye, skin and respiratory disorders 5. HEALTH EFFECTS DATA CON’T. FIRST AID PROCEDURES EYE CONTACT.....................Flush with copious amounts of water, preferably, lukewarm water for at least 15 minutes, holding eyelids open at all times. Obtain medical attention. SKIN CONTACT....................Wash with soap and water. Remove contaminated clothing and shoes. Wash clothing before reuse. Get medical attention if symptoms occur. Ingestion...........................Do not induce vomiting. Keep individual calm. Obtain medical attention. INHALATION.........................Remove to fresh air. If symptoms develop and persist, get medical attention. SPECIAL HEALTH EFFECTS CARCINOGEN (OSHA Guidelines) Silica, quartz, is a known carcinogen. CALIFORNIA PROP 65 This product contains a chemical known to the State of California to cause cancer. 6. REACTIVITY STABILITY............................................................ Stable under normal conditions. INCOMPATIBILITIES............................................ Oxidizing and spontaneously flammable products. HAZARDOUS DECOMPOSITION PRODUCTS.......................................................... Oxides of carbon. Aldehydes. Carboxylic acid. HAZARDOUS POLYMERIZATION....................... Will not occur under normal conditions. HAZARDOUS POLYMERIZATION CONDITIONS.....None known. 7. PRECAUTIONS FOR SAFE HANDLING & USE PROTECTIVE EQUIPMENT REQUIREMENTS..................Tightly sealed goggles with side shields, impermeable gloves and protective clothing as necessary to prevent skin contact. Local exhaust ventilation may be necessary to control air contaminants to within TLVs during the use of this product. WASH REQUIREMENTS......Wash with soap and water. SPILL OR LEAK PROCEDURES Remove all sources of ignition. Ensure adequate ventilation. Scrape up spilled material and place in sealed container for disposal. WASTE DISPOSAL METHODS Dispose of in accordance with local, state, and federal regulations. HANDLING & STORAGE......Avoid contact with eyes, skin and clothing. Avoid breathing vapor and mist. Wash thoroughly after handling. Use only adequate ventilation. Store below 100oF. OTHER PRECAUTIONS.......Use NIOSH approved respirator with an organic vapor cartridge; avoid prolonged breathing of vapors; protection provided by air purifying respirators is limited. 8. ADDITIONAL INFORMATION Use self-contained breathing apparatus if TLV limits are exceeded. Do not eat or smoke while using. Wash hands after use. Use positive pressure air supplied respirator if there is potential for uncontrolled release, if exposure levels are unknown, or in any circumstance where air purifying respirators may not provide adequate protection. The information GIVEN AND THE RECOMMENDATIONS MADE HEREIN APPLY TO OUR PRODUCT(S) ALONE AND ARE NOT COMBINED WITH OTHER PRODUCTS. SUCH INFORMATION IS BASED UPON OUR RESEARCH AND ON DATA FROM OTHER RELIABLE SOURCES AND IS BELIEVED TO BE ACCURATE. NO GUARANTEE OF ACCURACY IS MADE. IT IS THE PURCHASER’S RESPONSIBILITY BEFORE USING ANY PRODUCT TO VERIFY THIS DATA UNDER THEIR OWN OPERATING CONDITIONS AND TO DETERMINE WHETHER THE PRODUCT IS SUITABLE FOR THEIR PURPOSES. COPYRIGHT© 1984 KIMBALL MIDWEST UPDATE 9/06 HEAT PRUF GREASE Revision Date: 2007/05/15 Section 1: PRODUCT INFORMATION Chemical family: Mixture. Product uses: Industrial material. Supplier: Radiator Specialty Co., of Canada 1711 Aimco Blvd. Mississauga, Ontario L4W 1H7. Emergency Phone Number: 303−623−5716 Manufacturer: Refer to supplier. TDG classification: Not regulated. WHMIS classification: Not controlled. DSL status: Not available. Section 2: HAZARDOUS INGREDIENTS C.A.S. CONCENTRATION % Ingredient Name T.L.V. LD/50 LC/50 60.0−100.0 MINERAL OIL NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE Section 2A: ADDITIONAL INGREDIENT INFORMATION Note: Mineral Oil − TLV 5 mg/m3. Section 3: PHYSICAL DATA Physical state: Semi−solid. Appearance & odor: Gel Petroleum odour. Odor threshold (ppm): Not available. Vapour pressure (mmHg): <0.1 Vapour density (air=1): >1.0 Volatiles (%) By volume: Not available. Evaporation rate <0.01 (butyl acetate = 1): Boiling point (°C): Not available. Freezing point (°C): 284 pH: Not available. Specific gravity @ 20 °C: (water = 1). 0.99500 Solubility in water (%): Negligible. GR1, GR1V − HEAT PRUF GREASE 1/4 Coefficient of water\oil dist.: Not available. VOC: Not available. Section 4: FIRE & EXPLOSION DATA Flammability: Not flammable. Conditions of flammability: At temperatures at or above flash point. Extinguishing media: Carbon dioxide, dry chemical, foam. Water spray. Special procedures: Positive pressure self−contained breathing apparatus required and full protection to prevent skin contact. Auto−ignition temperature: Not available. Flash point (°C), method: Cleveland Open Cup. 450 Lower flammability Not applicable. limit (% vol): Upper flammability Not applicable. limit (% vol): Explosion Data Sensitivity to static discharge: Not available. Sensitivity to mechanical impact: Not available. Hazardous combustion products: Oxides of carbon (CO, CO2). Unidentified organic compounds. Explosive power: Not available. Section 5: REACTIVITY DATA Chemical stability: Stable under normal conditions. Conditions of instability: None known. Hazardous polymerization: Will not occur. Incompatible substances: Strong oxidizers. Hazardous decomposition See hazardous combustion products. products: Section 6: TOXICOLOGICAL PROPERTIES Route of entry: Ingestion. Skin and eye contact. Effects of acute exposure Eye contact: No adverse effects expected. Skin contact: No adverse effects expected. Inhalation: No adverse effects expected. Ingestion: Aspiration of liquid into lungs may cause chemical pneumonitis which can be fatal. Aspiration may result in pulmonary edema. GR1, GR1V − HEAT PRUF GREASE 2/4 Effects of chronic exposure: None known. LD50 of product, species & route: Not available. LC50 of product, species & route: Not available. Exposure limit of material: Not available for mixture, see section 2A. Sensitization to product: Not available. Carcinogenic effects: Not available. Reproductive effects: Not available. Teratogenicity: Not available. Mutagenicity: Not available. Synergistic materials: Not available. Section 7: PREVENTATIVE MEASURES Precautionary Measures Gloves/Type: Wear appropriate gloves. Respiratory/Type: Wear a NIOSH approved respirator if TLV is exceeded. Eye/Type: Safety glasses. Do not wear contact lenses. Footwear/Type: Safety shoes per local regulations. Clothing/Type: Wear adequate protective clothes. Other/Type: Eye wash facility should be in close proximity. Emergency shower should be in close proximity. Ventilation requirements: Maintain adequate ventilation. Leak/Spill: Contain the spill. Absorb with inert material. Wear appropriate protective equipment. Place in a chemical waste container for disposal. Waste disposal: Recycle waste where applicable. Dispose in accordance with local, provincial/state, and federal regulations. Handling procedures and Keep away from heat, sparks, and open flame. equipment: Use adequate ventilation. Wash thoroughly after using, particularly before eating or smoking. Wear personal protective equipment appropriate to task. Keep out of reach of children. Launder contaminated clothing prior to reuse. GR1, GR1V − HEAT PRUF GREASE 3/4 Storage requirements: Store away from all sources of ignition. Store away from incompatible materials. Keep containers tightly closed. TDG classification: Not regulated. Special shipping information: See transportation information. Section 8: FIRST AID MEASURES Skin contact: Wash thoroughly with soap and water. Seek medical attention if irritation persists. Eye contact: Immediately flush eyes with large amounts of water for at least 15 minutes, lifting upper and lower lids. Get prompt medical attention. Inhalation: Remove victim to fresh air. If breathing is difficult get medical attention. Ingestion: Guard against aspiration of liquids into lungs. Never give anything by mouth to an unconscious person. Do not induce vomiting, seek immediate medical attention. Additional information: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any inaccuracies. Section 9: ADDITIONAL INFORMATION General note: This material safety data sheet was prepared from information obtained from various sources, including product suppliers and the Canadian Center for Occupational Health and Safety. This MSDS was generated by Conform−Plus Application Service. Visit us at www.netmsds.com. GR1, GR1V − HEAT PRUF GREASE 4/4 MATERIAL SAFETY DATA SHEET PRODUCT NAME: WATER PUTTY PRODUCT CODE: 8040 ================== HMIS CODES: H 0 SECTION I - MANUFACTURER IDENTIFICATION F 0 R 0 P ================= MANUFACTURER'S NAME: Custom Building Products, Inc. ADDRESS: 6511 SALT LAKE AVE., BELL, CA. 90201 EMERGENCY PHONE: (323) 582-0846 INFORMATION PHONE: (323) 582-0846 NAME OF PREPARER : STEVE TAYLOR DATE REVISED : 10-11-04 REASON REVISED : NEW ========== SECTION II - HAZARDOUS INGREDIENTS/SARA III INFORMATION ========= OCCUPATIONAL EXPOSURE VAPOR LIMITS PRESSURE Wt. HAZARDOUS COMPONENTS CAS NUMBER OSHA PEL ACGIH TLV mm Hg @ TEMP % --------------------------------------------------------------------------------CALCIUM CARBONATE/ LIMESTONE 1317-65-3 10mg/M3 N/A 40 *** No toxic chemical(s) subject to the reporting requirements of section 313 of Title III and of 40 CFR 372 are present. *** ============== SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS ============= BOILING RANGE: N/A SPECIFIC GRAVITY (H2O=1): 2.6 VAPOR DENSITY: HEAVIER THAN AIR EVAPORATION RATE: SLOWER THAN ETHER SOLUBILITY IN WATER: SLIGHT APPEARANCE AND ODOR: YELLOW POWDER; NO ODOR ================ SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT: N/A FLAMMABLE LIMITS IN AIR BY VOLUME - LOWER: EXTINGUISHING MEDIA: NONE KNOWN SPECIAL FIREFIGHTING PROCEDURES N/A UPPER: N/A =============== NONE UNUSUAL FIRE AND EXPLOSION HAZARDS NONE 8040 MATERIAL SAFETY DATA SHEET ======================== SECTION V - REACTIVITY DATA PAGE 2 OF 3 ======================= STABILITY: STABLE CONDITIONS TO AVOID NONE INCOMPATIBILITY (MATERIALS TO AVOID) POSSIBLE REACTIVITY WITH STRONG MINERAL ACIDS. HAZARDOUS DECOMPOSITION OR BYPRODUCTS REACTION WITH ACIDS WILL EVOLVE CARBON DIOXIDE. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR ===================== SECTION VI - HEALTH HAZARD DATA ====================== INHALATION HEALTH RISKS AND SYMPTOMS OF EXPOSURE REMOVE TO FRESH AIR. SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE MAY DEVELOP SUFFICIENT HEAT TO CAUSE BURNS TO SKIN IF A LARGE MASS IS KEPT IN CONTACT WITH SKIN WHILE HARDENING. PARTICLES MAY CAUSE IRRITATION TO EYES. SKIN ABSORPTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE NONE INGESTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE PLASTER HARDENS WHEN WETTED AND IF INGESTED MAY RESULT IN OBSTRUCTION. SEE PHYSICIAN. HEALTH HAZARDS (ACUTE AND CHRONIC) ACUTE: NONE CHRONIC: NONE CARCINOGENICITY: NTP? NO IARC MONOGRAPHS? NO OSHA REGULATED? NO NONE MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE NONE EMERGENCY AND FIRST AID PROCEDURES EYE CONTACT: FLUSH WITH WATER TO REMOVE PARTICLES. IF IRRITATION PERSISTS, SEE PHYSICIAN. SKIN CONTACT: WASH WITH SOAP AND WATER. INHALED: REMOVE TO FRESH AIR. SWALLOWED: IF INGESTED, SEE PHYSICIAN BECAUSE OF POSSIBLE BLOCKAGE. 8040 =========== MATERIAL SAFETY DATA SHEET SECTION VII - PAGE 3 OF 3 PRECAUTIONS FOR SAFE HANDLING AND USE ============ STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED CLEAN UP USING DRY METHODS THAT DO NOT DISPERSE DUST INTO THE AIR. AVOID BREATHING DUST. EMERGENCY PROCEDURES ARE NOT REQUIRED. WASTE DISPOSAL METHOD CAN BE TREATED AS COMMON WASTE. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING NONE OTHER PRECAUTIONS NONE ===================== SECTION VIII - CONTROL MEASURES ====================== RESPIRATORY PROTECTION NIOSH APPROVED RESPIRATOR FOR NUISANCE DUST. VENTILATION LOCAL EXHAUST. PROTECTIVE GLOVES NONE REQUIRED. EYE PROTECTION DUST GOGGLES OR SAFETY GLASSES. OTHER PROTECTIVE CLOTHING OR EQUIPMENT NONE REQUIRED. WORK/HYGIENIC PRACTICES KEEP SPILLED MATERIALS CLEANED UP. ========================= SECTION IX - DISCLAIMER ========================== DISCLAIMER THE INFORMATION PRESENTED HERE IS BELIEVED TO BE ACCURATE BUT IS NOT WARRANTED TO BE, WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED, THAT THE INFORMATION IS CURRENT, APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. Handy & Harman of Canada, Limited MATERIAL SAFETY DATA SHEET SECTION 1 MATERIAL IDENTIFICATION AND USE SIL-FOS, FOS-FLO MATERIAL NAME IDENTIFIER: Manufacturer’s Name: HANDY & HARMAN OF CANADA, LIMITED City: REXDALE CODE BA-3 rev 10/06 Province/State/Country: Street Address: ONTARIO, CANADA M9W 5G1 Supplier’s Name: 290 CARLINGVIEW DRIVE Emergency Phone No: (416) 675-1860 Street Address: City: Province/State/Country: Chemical Name: Silver Brazing Filler Metal Molecular Weight: N/Avl. SECTION 2 Emergency Phone No: Chemical Family: Ag/Cu/P; Cu/P; Cu/P/Sn; Cu/P/Sn/Ni Alloys Trade Names, Synonyms: Refer To Chart Chemical Formula: Refer To Chart Material Use: Filler Metals For Brazing HAZARDOUS CHEMICAL COMPONENTS Chemical Component CAS Number SILVER (Ag) 7440-22-4 COPPER (Cu) 7440-50-8 PHOSPHOROUS (P) (red allotropic form) 7723-14-0 TIN (Sn) 7440-31-5 NICKEL (Ni) 7440-02-0 (Refer to filler metal chart below for nominal composition %) ACGIH: TLVs (2000) 0.1 mg/m3 TWA (metal) 3 OSHA PEL: 0.01 mg/m TWA LC 50 N/Avl. LD 50 N/Avl. ACGIH: TLVs (2000) 0.2 mg/m3 TWA (fume); 1.0 mg/m3 TWA (dusts & mists) 3 3 OSHA PELS: 0.1 mg/m TWA (fume); 1.0 mg/m TWA (dusts & mists) LC 50 N/Avl. LD 50 470 mg/kg oral-mouse ACGIH: TLVs N/Avl. OSHA PEL: N/Avl. LC 50 N/Avl. LD 50 N/Avl. ACGIH: TLVs (2000) 2.0 mg/m3 TWA (metal, oxide, and inorganic compounds, as Sn) 3 OSHA PEL: 2.0 mg/m TWA LC 50 15 mg/m3/10m inhal.-monkey LD 50 72 mg/kg oral-mouse 3 ACGIH: TLVs (2000) 1.0 mg/m TWA (metal)(inhalable fraction) 0.2 mg/m3 TWA (insoluble compounds, as Ni)(inhalable fraction) 3 OSHA PEL: 1.0 mg/m TWA (metal & insoluble compounds, as Ni) LC 50 N/Avl. LD 50 N/Avl. HANDY & HARMAN BRAZING FILLER METALS CHART Solidus FILLER METAL NAME SIL-FOS 18 SIL-FOS SIL-FOS 6 SIL-FOS 6M SIL-FOS 5 SIL-FOS 5F SIL-FOS 2 SIL-FOS 2M SIL-FOS 1 FOS-FLO 7 FOS-FLO 6 FOS-FLO 5 FOS-FLO 670 FOS-FLO 671 Nominal Composition, % AWS / SFA CLASS BCuP5 BCuP-4 BCuP-3 BCuP-7 BCuP-6 BCuP-2 BCuP-1 Others (Melt Point) Liquidus (Flow Point) Brazing Range Specific Ag Cu P ºF ºC ºF ºC ºF 18 15 6 6 5 5 2 2 9 74.75 80 86.75 88 89 88.25 91 91.4 92.6 7.25 5 7.25 6 6 6.75 7 6.6 6.5 1190-645 1190-645 1190-645 1475-800 1190-1300 1300-1500 645-705 705-815 8.1 8.44 1190-645 1325-720 1275-1450 690-785 7.9 1190-645 1190-645 1190-645 1190-645 1190-645 1190-645 1460-795 1495-815 1420-770 1450-785 1495-815 1500-815 1300-1500 1325-1500 1300-1500 1325-1500 1350-1550 1350-1600 705-815 720-815 705-815 720-815 730-845 730-870 8.1 8.14 8.14 8.0 8.1 8.1 0 0 0 92.75 94 95 7.25 6 5 1310-710 1310-710 1310-710 1460-795 1570-855 1695-925 1350-1550 1375-1575 1450-1700 730-845 745-855 790-925 8.01 8.12 8.1 0 0 87 85.3 6 6.2 1215-657 1134-612 1270-687 1260-682 1270-1450 1260-1425 687-788 682-774 8.4 8.47 7 Sn 7 Sn, 1.5 Ni ºC Gravity Handy & Harman of Canada, Limited MATERIAL SAFETY DATA SHEET SECTION 3 PHYSICAL DATA Physical State: Gas Liquid Solid ■ Odour Threshold (ppm): N/Avl. Evaporation Rate: Solid - N/Appl. % Volatile (By Volume): N/Appl. Specific Gravity: Refer To Chart SECTION 4 CODE BA-3 rev 10/06 Odour & Appearance: No Odour; Solid Metal Wire, Strip, Powder, Paste Vapour Pressure (mm.Hg): N/Avl. Vapour Density (AIR=1):Solid-N/Appl. Boiling Point (ºC): Solid - N/Appl. Freezing Point (ºC): Solid - N/Appl. Solubility In Water (20ºC): Insoluble pH: N/Appl. Coeff.-Water Oil Disp.: N/Appl. FIRE AND EXPLOSION DATA Flammability: Yes ■ No If yes, under which conditions? Dust, powder and fumes are flammable when exposed to flame or by chemical reaction with oxidizing agents (see Section 5 for incompatible materials). Fires or explosions involving these alloys may release potentially toxic emissions of metal or metal oxide fumes (see Section 2 for hazardous components). Means Of Extinction: Dry powder for metal fires. Do not use water on dust, powder or fume fires. Special Procedures: Use self-contained breathing apparatus with full face-piece operated in pressure demand or other positive pressure mode. Flashpoint(ºC) & Method: Solid Metal - Non-Flammable Upper Explosion Limit (% By Volume): N/Appl. Lower Explosion Limit (%By Volume): Solid Metal - N/Appl. Auto Ignition Temperature (ºC): Solid Metal - N/Appl. TDG Flammability Classification: None Hazardous Combustion Products: Solid Metal - N/Appl. Sensitivity To Impact Explosion Data: N/Appl. Rate Of Burning: N/Appl. Explosive Power: N/Appl. Sensitivity To Static Discharge: N/Appl. SECTION 5 REACTIVITY DATA ***AVOID DISPERSION OF FINELY DIVIDED PARTICLES IN AIR*** Chemical Stability: Yes ■ No If yes, under which conditions? Normal Ambient Environment. Incompatibility With Other Substances: Yes ■ No If yes, which ones? Ammonia; HNO3; Azides; Ethanol; Ethylenimine; Mg; Chlorates; Bromates; C12; CIF3; Chlorine Oxides; Inorganic Peroxides; Peroxyformic Acid; Permonosulphuric Acid; Fluorine; CS2; SeOCI; SeOF; SeF4; Iodates. Reactivity And Under What Conditions: Silver and copper can form explosive acetylides upon contact with uncombusted acetylene. Hazardous Decomposition Products: Hazardous polymerization will not occur. Upon heating, danger is mostly from inhalation of metal (oxide) fumes. Overexposure to elemental oxide fumes or dust can cause nausea and metal fume fever. Use hooded exhaust ventilation to carry all fumes away from work area and, if necessary, use air supplied respirator (see Section 7). Thought should be given to the heating methods, flux and base metals being joined which could emit fumes on heating depending on their particular chemistry. Avoid overheating (see chart, Brazing Range). SECTION 6 TOXICOLOGICAL PROPERTIES Route Of Exposure: Inhalation Inhalation of the components of these products are not known to present a significant risk to health when used according to instructions and with appropriate protective measures (see Section 7). Inhalation of the component/elements has been reported to cause one or more of the following symptoms/effects upon excessively high and/or prolonged inhalation/exposure. SILVER: Acute May cause grey discolouration of mucous membranes. Chronic May produce argyria, a permanent blue-grey discolouration of the skin, eyes, mucous membranes, and the respiratory tract. COPPER: Acute Acute exposure to dust or fume may cause respiratory tract irritation, fever, muscle ache, chills, cough, weakness, and a metallic taste. Chronic Exposure may cause damage to the liver, kidney, spleen, pancreas, and brain. PHOSPHOROUS: Acute When heated in air, fume is corrosive and irritating to eyes, nose, throat, and mucous membranes. Chronic Unlikely. TIN Acute Dust or fume may cause respiratory tract irritation, nausea, joint/muscle pains. Chronic May cause stannosis, a benign pneumoconeosis, as well as possible dyspnea. NICKEL: Acute Dust or fumes may produce headache, nausea, vertigo, asthma, and pulmonary edema. Chronic May increase the risk of cancer to the nasopharynx, lungs, prostate, and kidney. Miscellaneous Toxicological Information Nickel is classified as a potential human carcinogen by the following organizations (with respective sub-classifications): 1. IARC (Group 2B) 2. NTP (Group 2B) Nickel has also produced fetotoxic and teratogenic effects in animal studies, and mutagenic responses in mammalian cell cultures. Neither Silver, Copper, Tin, nor Phosphorous are classified as potential or demonstrated human carcinogens by IARC, NIOSH, NTP, OSHA, or ACGIH. Page 2 Handy & Harman of Canada, Limited MATERIAL SAFETY DATA SHEET SECTION 6 (cont’d) TOXICOLOGICAL PROPERTIES CODE BA-3 rev 10/06 Health Conditions Aggravated By Exposure: Pre-existing pulmonary diseases (e.g., bronchitis, emphysema) may be aggravated by inhalation exposure to these materials, particularly as fume. Exposure to nickel by inhalation and/or ingestion may aggravate pre-existing diseases of the liver, kidneys, central nervous system, and musculoskeletal system. Route Of Exposure Skin: In solid form, materials are not known to be hazardous. In finely divided form, skin contact may produce localized irritation, localized argyria, skin discolouration, and contact or allergic dermatitis. Eyes: Exposure of the eyes to finely divided form of these materials may produce localized argyria, irritation, conjunctivitis, and ulceration of the cornea. Ingestion: Finely divided form of these materials may produce gastric irritation, vomiting, abdominal pain, hemorrhage, and diarrhea. Longterm chronic ingestion may produce damage to the liver, kidney, spleen, pancreas, musculoskeletal system, blood-forming organs, and central nervous system. Exposure Limit Of Material: Irritancy Of Material: LD 50 Of Material - Specify LC 50 Of Material N/Avl. N/Avl. Species And Route: N/Avl. Specify Species: N/Avl. Sensitizing Capability Of Carcinogenicity Of Material: Reproductive Effects Of Synergistic Materials: N/Avl. N/Avl. Material: N/Avl. Material: N/Avl. SECTION 7 PREVENTATIVE MEASURES Personal Protective Equipment: Personal protective equipment will be required when using these materials. The nature of the processing activity will determine what form of equipment is necessary, i.e., safety glasses, respirator, protective clothing, etc. Personal protective equipment should not be substituted for proper handling and engineering controls. Gloves: Wear appropriate protective gloves to prevent injury from the hazards of brazing and/or repeated contact with finely divided material. Avoid flammable fabrics. Respiratory: Local exhaust, mechanical ventilation, and/or respiratory equipment may be required to maintain a protection factor appropriate to the airborne concentrations of the contaminants generated and provide sufficient clean air for breathing. If exposure levels exceed OSHA PELS, wear a NIOSH/MSHA-approved respirator (or other approving authority) for protection from the airborne contaminants. All adjacent persons in the immediate vicinity of brazing or “soldering” operations shall be similarly protected as necessary by ventilation or approved respirators. Eyes: Wear eye protection (safety glasses, dust-proof goggles) adequate to prevent eye contact with this material in finely divided form and to prevent eye injury from the hazards of brazing. Plastic-frame safety spectacles with side shields and filter lenses (shade #3 or #4) are recommended. Footwear: Refer to workplace safety regulations. Clothing: Avoid flammable fabrics. Wear appropriate clothing to prevent skin injuries from the hazards of brazing. Other Protection: Practice good housekeeping and personal hygiene procedures. To avoid ingestion of material, wash hands and face before eating, drinking, or consumption of tobacco. Brazing alloys may be used with a separately applied flux which, when heated, may emit irritating and/or toxic gases and fumes. Consult the MSDS for the specific flux in use to determine its hazards and appropriate protective measures. For general guidance, refer to American National Standards Institute (ANSI) Z49.1, “Safety in Welding and Cutting” (American Welding Society, Miami, FL 33135). Engineering Controls: Adequate ventilation, sinks, showers, and eyewash stations should be provided. The best industrial control practice is to maintain concentrations of all chemical fumes and dusts as low as is practical. Leak And Spill Procedure: If metal is molten, allow to solidify and cool. Clean up any spilled material so as to minimize dispersion of dusts. Wet sweeping or vacuuming using HEPA, or similarly approved filtration, are recommended methods. Waste Disposal: Return to manufacturer for reclaim. Sara Title III - Hazard Classes: Acute Health Hazard; Chronic Health Hazard Handling Procedure And Equipment: Avoid heating above brazing range (see chart, Section 2) as excessive fumes may result. When applicable, use sufficient flux or atmosphere to protect the metals and minimize oxidation/vapourization during use. Storage Requirements: Avoid storage near incompatible materials (see also Section 5). Also avoid conditions which create toxic fumes or dusts. Wash exposed skin after handling material. Stable at room temperature. Special Shipping Information: No special requirements. WHMIS Classification: Class D, Division 2, Subdivision B. Page 3 Handy & Harman of Canada, Limited MATERIAL SAFETY DATA SHEET SECTION 8 FIRST AID MEASURES CODE BA-3 rev 10/06 Emergency And First Aid Procedures Inhalation: Move victim to fresh air at once. Give oxygen if breathing is laboured, artificial respiration if victim is not breathing. Keep person warm and quiet. Get medical attention immediately. Skin: Contact in solid forms is not known to be hazardous. If clothing is contaminated with finely divided particles, remove. Wash affected area with large quantities of water for at least 5 minutes. Get medical attention if necessary. Eyes: Flush immediately with large amounts of water for at least 15 minutes while lifting the lower and upper eyelids. If irritation continues, get medical attention. Ingestion: If person is conscious, give large amounts of water and induce vomiting. Seek medical attention. If person is unconscious or convulsive, get immediate medical attention. ***SEEK MEDICAL ATTENTION IN ALL CASES OF EXPOSURE*** SIGNS AND SYMPTOMS OF EXPOSURE: Acute Inhalation: Chills, fever, aching muscles, sneezing, dry throat, coughing, constriction of throat, nausea, irritation of nose and trachea, discolouration of mucous membranes, difficulty in breathing, chest pain, headache. Skin: Particles may cause irritation, pain, nausea, vomiting. Eyes: Particles may cause irritation, redness, itching. Ingestion: Nausea, vomiting, headache, diarrhea, fever, abdominal pain. Chronic Inhalation: Cough, difficulty in breathing, laryngitis, discolouration of mucous membranes, kidney and liver disorders. Skin: May cause argaria, discolouration, contact dermatitis and/or allergic sensitization among hyper-susceptible individuals. Eyes: Irritation Ingestion: May cause damage to the liver, kidneys, musculoskeletal system and nervous system. Medical Conditions Generally Aggravated By Exposure: (see Section 6). Sources Used: Canadian Centre For Occupational Health And Safety, Hamilton, Ontario; American Welding Society, Miami, Florida; ACGIH, Cincinnati, Ohio; Lucas-Milhaupt Inc., Cudahy, Wisconsin. Additional Information: The information contained herein is only for the manufactured product. The composition and hazards of any resultant fumes due to heating methods, filler metal alloy, flux and base metals employed may vary significantly. Brazing fumes consist of various airborne substances which may create hazards to health when they are inhaled or swallowed. The degree of hazard to the worker(s) in the work area depends upon the composition of the total fume, the concentration of contaminants in the breathing air and the time-length of exposure to it. It is the responsibility of the user/employer to ensure the suitability of the material use and that TLV, TWA, and STEL values are not exceeded. Assessment of the possible exposure to the worker(s) to hazardous fumes, when required, should be carried out by a competent person and may involve air concentration measurements SECTION 9 PREPARED BY: Marketing Department PREPARATION DATE OF MSDS PHONE NO: (416) 675-1860 DATE: Revised 10/06 Page 4 Handy & Harman of Canada, Limited MATERIAL SAFETY DATA SHEET SECTION 1 MATERIAL IDENTIFICATION AND USE SIL-FOS, FOS-FLO MATERIAL NAME IDENTIFIER: Manufacturer’s Name: HANDY & HARMAN OF CANADA, LIMITED City: REXDALE CODE BA-3 rev 10/06 Province/State/Country: Street Address: ONTARIO, CANADA M9W 5G1 Supplier’s Name: 290 CARLINGVIEW DRIVE Emergency Phone No: (416) 675-1860 Street Address: City: Province/State/Country: Chemical Name: Silver Brazing Filler Metal Molecular Weight: N/Avl. SECTION 2 Emergency Phone No: Chemical Family: Ag/Cu/P; Cu/P; Cu/P/Sn; Cu/P/Sn/Ni Alloys Trade Names, Synonyms: Refer To Chart Chemical Formula: Refer To Chart Material Use: Filler Metals For Brazing HAZARDOUS CHEMICAL COMPONENTS Chemical Component CAS Number SILVER (Ag) 7440-22-4 COPPER (Cu) 7440-50-8 PHOSPHOROUS (P) (red allotropic form) 7723-14-0 TIN (Sn) 7440-31-5 NICKEL (Ni) 7440-02-0 (Refer to filler metal chart below for nominal composition %) ACGIH: TLVs (2000) 0.1 mg/m3 TWA (metal) 3 OSHA PEL: 0.01 mg/m TWA LC 50 N/Avl. LD 50 N/Avl. ACGIH: TLVs (2000) 0.2 mg/m3 TWA (fume); 1.0 mg/m3 TWA (dusts & mists) 3 3 OSHA PELS: 0.1 mg/m TWA (fume); 1.0 mg/m TWA (dusts & mists) LC 50 N/Avl. LD 50 470 mg/kg oral-mouse ACGIH: TLVs N/Avl. OSHA PEL: N/Avl. LC 50 N/Avl. LD 50 N/Avl. ACGIH: TLVs (2000) 2.0 mg/m3 TWA (metal, oxide, and inorganic compounds, as Sn) 3 OSHA PEL: 2.0 mg/m TWA LC 50 15 mg/m3/10m inhal.-monkey LD 50 72 mg/kg oral-mouse 3 ACGIH: TLVs (2000) 1.0 mg/m TWA (metal)(inhalable fraction) 0.2 mg/m3 TWA (insoluble compounds, as Ni)(inhalable fraction) 3 OSHA PEL: 1.0 mg/m TWA (metal & insoluble compounds, as Ni) LC 50 N/Avl. LD 50 N/Avl. HANDY & HARMAN BRAZING FILLER METALS CHART Solidus FILLER METAL NAME SIL-FOS 18 SIL-FOS SIL-FOS 6 SIL-FOS 6M SIL-FOS 5 SIL-FOS 5F SIL-FOS 2 SIL-FOS 2M SIL-FOS 1 FOS-FLO 7 FOS-FLO 6 FOS-FLO 5 FOS-FLO 670 FOS-FLO 671 Nominal Composition, % AWS / SFA CLASS BCuP5 BCuP-4 BCuP-3 BCuP-7 BCuP-6 BCuP-2 BCuP-1 Others (Melt Point) Liquidus (Flow Point) Brazing Range Specific Ag Cu P ºF ºC ºF ºC ºF 18 15 6 6 5 5 2 2 9 74.75 80 86.75 88 89 88.25 91 91.4 92.6 7.25 5 7.25 6 6 6.75 7 6.6 6.5 1190-645 1190-645 1190-645 1475-800 1190-1300 1300-1500 645-705 705-815 8.1 8.44 1190-645 1325-720 1275-1450 690-785 7.9 1190-645 1190-645 1190-645 1190-645 1190-645 1190-645 1460-795 1495-815 1420-770 1450-785 1495-815 1500-815 1300-1500 1325-1500 1300-1500 1325-1500 1350-1550 1350-1600 705-815 720-815 705-815 720-815 730-845 730-870 8.1 8.14 8.14 8.0 8.1 8.1 0 0 0 92.75 94 95 7.25 6 5 1310-710 1310-710 1310-710 1460-795 1570-855 1695-925 1350-1550 1375-1575 1450-1700 730-845 745-855 790-925 8.01 8.12 8.1 0 0 87 85.3 6 6.2 1215-657 1134-612 1270-687 1260-682 1270-1450 1260-1425 687-788 682-774 8.4 8.47 7 Sn 7 Sn, 1.5 Ni ºC Gravity Handy & Harman of Canada, Limited MATERIAL SAFETY DATA SHEET SECTION 3 PHYSICAL DATA Physical State: Gas Liquid Solid ■ Odour Threshold (ppm): N/Avl. Evaporation Rate: Solid - N/Appl. % Volatile (By Volume): N/Appl. Specific Gravity: Refer To Chart SECTION 4 CODE BA-3 rev 10/06 Odour & Appearance: No Odour; Solid Metal Wire, Strip, Powder, Paste Vapour Pressure (mm.Hg): N/Avl. Vapour Density (AIR=1):Solid-N/Appl. Boiling Point (ºC): Solid - N/Appl. Freezing Point (ºC): Solid - N/Appl. Solubility In Water (20ºC): Insoluble pH: N/Appl. Coeff.-Water Oil Disp.: N/Appl. FIRE AND EXPLOSION DATA Flammability: Yes ■ No If yes, under which conditions? Dust, powder and fumes are flammable when exposed to flame or by chemical reaction with oxidizing agents (see Section 5 for incompatible materials). Fires or explosions involving these alloys may release potentially toxic emissions of metal or metal oxide fumes (see Section 2 for hazardous components). Means Of Extinction: Dry powder for metal fires. Do not use water on dust, powder or fume fires. Special Procedures: Use self-contained breathing apparatus with full face-piece operated in pressure demand or other positive pressure mode. Flashpoint(ºC) & Method: Solid Metal - Non-Flammable Upper Explosion Limit (% By Volume): N/Appl. Lower Explosion Limit (%By Volume): Solid Metal - N/Appl. Auto Ignition Temperature (ºC): Solid Metal - N/Appl. TDG Flammability Classification: None Hazardous Combustion Products: Solid Metal - N/Appl. Sensitivity To Impact Explosion Data: N/Appl. Rate Of Burning: N/Appl. Explosive Power: N/Appl. Sensitivity To Static Discharge: N/Appl. SECTION 5 REACTIVITY DATA ***AVOID DISPERSION OF FINELY DIVIDED PARTICLES IN AIR*** Chemical Stability: Yes ■ No If yes, under which conditions? Normal Ambient Environment. Incompatibility With Other Substances: Yes ■ No If yes, which ones? Ammonia; HNO3; Azides; Ethanol; Ethylenimine; Mg; Chlorates; Bromates; C12; CIF3; Chlorine Oxides; Inorganic Peroxides; Peroxyformic Acid; Permonosulphuric Acid; Fluorine; CS2; SeOCI; SeOF; SeF4; Iodates. Reactivity And Under What Conditions: Silver and copper can form explosive acetylides upon contact with uncombusted acetylene. Hazardous Decomposition Products: Hazardous polymerization will not occur. Upon heating, danger is mostly from inhalation of metal (oxide) fumes. Overexposure to elemental oxide fumes or dust can cause nausea and metal fume fever. Use hooded exhaust ventilation to carry all fumes away from work area and, if necessary, use air supplied respirator (see Section 7). Thought should be given to the heating methods, flux and base metals being joined which could emit fumes on heating depending on their particular chemistry. Avoid overheating (see chart, Brazing Range). SECTION 6 TOXICOLOGICAL PROPERTIES Route Of Exposure: Inhalation Inhalation of the components of these products are not known to present a significant risk to health when used according to instructions and with appropriate protective measures (see Section 7). Inhalation of the component/elements has been reported to cause one or more of the following symptoms/effects upon excessively high and/or prolonged inhalation/exposure. SILVER: Acute May cause grey discolouration of mucous membranes. Chronic May produce argyria, a permanent blue-grey discolouration of the skin, eyes, mucous membranes, and the respiratory tract. COPPER: Acute Acute exposure to dust or fume may cause respiratory tract irritation, fever, muscle ache, chills, cough, weakness, and a metallic taste. Chronic Exposure may cause damage to the liver, kidney, spleen, pancreas, and brain. PHOSPHOROUS: Acute When heated in air, fume is corrosive and irritating to eyes, nose, throat, and mucous membranes. Chronic Unlikely. TIN Acute Dust or fume may cause respiratory tract irritation, nausea, joint/muscle pains. Chronic May cause stannosis, a benign pneumoconeosis, as well as possible dyspnea. NICKEL: Acute Dust or fumes may produce headache, nausea, vertigo, asthma, and pulmonary edema. Chronic May increase the risk of cancer to the nasopharynx, lungs, prostate, and kidney. Miscellaneous Toxicological Information Nickel is classified as a potential human carcinogen by the following organizations (with respective sub-classifications): 1. IARC (Group 2B) 2. NTP (Group 2B) Nickel has also produced fetotoxic and teratogenic effects in animal studies, and mutagenic responses in mammalian cell cultures. Neither Silver, Copper, Tin, nor Phosphorous are classified as potential or demonstrated human carcinogens by IARC, NIOSH, NTP, OSHA, or ACGIH. Page 2 Handy & Harman of Canada, Limited MATERIAL SAFETY DATA SHEET SECTION 6 (cont’d) TOXICOLOGICAL PROPERTIES CODE BA-3 rev 10/06 Health Conditions Aggravated By Exposure: Pre-existing pulmonary diseases (e.g., bronchitis, emphysema) may be aggravated by inhalation exposure to these materials, particularly as fume. Exposure to nickel by inhalation and/or ingestion may aggravate pre-existing diseases of the liver, kidneys, central nervous system, and musculoskeletal system. Route Of Exposure Skin: In solid form, materials are not known to be hazardous. In finely divided form, skin contact may produce localized irritation, localized argyria, skin discolouration, and contact or allergic dermatitis. Eyes: Exposure of the eyes to finely divided form of these materials may produce localized argyria, irritation, conjunctivitis, and ulceration of the cornea. Ingestion: Finely divided form of these materials may produce gastric irritation, vomiting, abdominal pain, hemorrhage, and diarrhea. Longterm chronic ingestion may produce damage to the liver, kidney, spleen, pancreas, musculoskeletal system, blood-forming organs, and central nervous system. Exposure Limit Of Material: Irritancy Of Material: LD 50 Of Material - Specify LC 50 Of Material N/Avl. N/Avl. Species And Route: N/Avl. Specify Species: N/Avl. Sensitizing Capability Of Carcinogenicity Of Material: Reproductive Effects Of Synergistic Materials: N/Avl. N/Avl. Material: N/Avl. Material: N/Avl. SECTION 7 PREVENTATIVE MEASURES Personal Protective Equipment: Personal protective equipment will be required when using these materials. The nature of the processing activity will determine what form of equipment is necessary, i.e., safety glasses, respirator, protective clothing, etc. Personal protective equipment should not be substituted for proper handling and engineering controls. Gloves: Wear appropriate protective gloves to prevent injury from the hazards of brazing and/or repeated contact with finely divided material. Avoid flammable fabrics. Respiratory: Local exhaust, mechanical ventilation, and/or respiratory equipment may be required to maintain a protection factor appropriate to the airborne concentrations of the contaminants generated and provide sufficient clean air for breathing. If exposure levels exceed OSHA PELS, wear a NIOSH/MSHA-approved respirator (or other approving authority) for protection from the airborne contaminants. All adjacent persons in the immediate vicinity of brazing or “soldering” operations shall be similarly protected as necessary by ventilation or approved respirators. Eyes: Wear eye protection (safety glasses, dust-proof goggles) adequate to prevent eye contact with this material in finely divided form and to prevent eye injury from the hazards of brazing. Plastic-frame safety spectacles with side shields and filter lenses (shade #3 or #4) are recommended. Footwear: Refer to workplace safety regulations. Clothing: Avoid flammable fabrics. Wear appropriate clothing to prevent skin injuries from the hazards of brazing. Other Protection: Practice good housekeeping and personal hygiene procedures. To avoid ingestion of material, wash hands and face before eating, drinking, or consumption of tobacco. Brazing alloys may be used with a separately applied flux which, when heated, may emit irritating and/or toxic gases and fumes. Consult the MSDS for the specific flux in use to determine its hazards and appropriate protective measures. For general guidance, refer to American National Standards Institute (ANSI) Z49.1, “Safety in Welding and Cutting” (American Welding Society, Miami, FL 33135). Engineering Controls: Adequate ventilation, sinks, showers, and eyewash stations should be provided. The best industrial control practice is to maintain concentrations of all chemical fumes and dusts as low as is practical. Leak And Spill Procedure: If metal is molten, allow to solidify and cool. Clean up any spilled material so as to minimize dispersion of dusts. Wet sweeping or vacuuming using HEPA, or similarly approved filtration, are recommended methods. Waste Disposal: Return to manufacturer for reclaim. Sara Title III - Hazard Classes: Acute Health Hazard; Chronic Health Hazard Handling Procedure And Equipment: Avoid heating above brazing range (see chart, Section 2) as excessive fumes may result. When applicable, use sufficient flux or atmosphere to protect the metals and minimize oxidation/vapourization during use. Storage Requirements: Avoid storage near incompatible materials (see also Section 5). Also avoid conditions which create toxic fumes or dusts. Wash exposed skin after handling material. Stable at room temperature. Special Shipping Information: No special requirements. WHMIS Classification: Class D, Division 2, Subdivision B. Page 3 Handy & Harman of Canada, Limited MATERIAL SAFETY DATA SHEET SECTION 8 FIRST AID MEASURES CODE BA-3 rev 10/06 Emergency And First Aid Procedures Inhalation: Move victim to fresh air at once. Give oxygen if breathing is laboured, artificial respiration if victim is not breathing. Keep person warm and quiet. Get medical attention immediately. Skin: Contact in solid forms is not known to be hazardous. If clothing is contaminated with finely divided particles, remove. Wash affected area with large quantities of water for at least 5 minutes. Get medical attention if necessary. Eyes: Flush immediately with large amounts of water for at least 15 minutes while lifting the lower and upper eyelids. If irritation continues, get medical attention. Ingestion: If person is conscious, give large amounts of water and induce vomiting. Seek medical attention. If person is unconscious or convulsive, get immediate medical attention. ***SEEK MEDICAL ATTENTION IN ALL CASES OF EXPOSURE*** SIGNS AND SYMPTOMS OF EXPOSURE: Acute Inhalation: Chills, fever, aching muscles, sneezing, dry throat, coughing, constriction of throat, nausea, irritation of nose and trachea, discolouration of mucous membranes, difficulty in breathing, chest pain, headache. Skin: Particles may cause irritation, pain, nausea, vomiting. Eyes: Particles may cause irritation, redness, itching. Ingestion: Nausea, vomiting, headache, diarrhea, fever, abdominal pain. Chronic Inhalation: Cough, difficulty in breathing, laryngitis, discolouration of mucous membranes, kidney and liver disorders. Skin: May cause argaria, discolouration, contact dermatitis and/or allergic sensitization among hyper-susceptible individuals. Eyes: Irritation Ingestion: May cause damage to the liver, kidneys, musculoskeletal system and nervous system. Medical Conditions Generally Aggravated By Exposure: (see Section 6). Sources Used: Canadian Centre For Occupational Health And Safety, Hamilton, Ontario; American Welding Society, Miami, Florida; ACGIH, Cincinnati, Ohio; Lucas-Milhaupt Inc., Cudahy, Wisconsin. Additional Information: The information contained herein is only for the manufactured product. The composition and hazards of any resultant fumes due to heating methods, filler metal alloy, flux and base metals employed may vary significantly. Brazing fumes consist of various airborne substances which may create hazards to health when they are inhaled or swallowed. The degree of hazard to the worker(s) in the work area depends upon the composition of the total fume, the concentration of contaminants in the breathing air and the time-length of exposure to it. It is the responsibility of the user/employer to ensure the suitability of the material use and that TLV, TWA, and STEL values are not exceeded. Assessment of the possible exposure to the worker(s) to hazardous fumes, when required, should be carried out by a competent person and may involve air concentration measurements SECTION 9 PREPARED BY: Marketing Department PREPARATION DATE OF MSDS PHONE NO: (416) 675-1860 DATE: Revised 10/06 Page 4 Page 1/7 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 07/25/2003 Reviewed on 07/14/2003 1 Identification of substance Product details Trade name: 256GS Sn55Pb45, Sn60Pb40, Sn62Pb38, Sn63Pb37, Sn65Pb35 Application of the substance / the preparation: Solder paste Manufacturer/Supplier: Kester 515 E. Touhy Ave. Des Plaines, IL 60018 Information department: MSDS Coordinator Emergency information: CHEMTREC 24-Hour Emergency Telephone Number: CHEMTREC 24-Hour Emergency Telephone Number (Outside of the U.S. and Canada): Tel.(847) 297-1600 Fax.(847) 390-9338 Tel. (847) 699-5755 (800)424-9300 (703)527-3887 2 Composition/Data on components Chemical characterization Description: Mixture of the substances listed below with nonhazardous additions. Dangerous components: 7440-31-5 tin 7439-92-1 lead 65997-05-9 Rosin, polymerized 8050-09-7 Rosin 143-24-8 bis(2-(2-methoxyethoxy)ethyl) ether 50-100% 25-50% 2.5-10% ≤ 2.5% ≤ 2.5% 3 Hazards identification WHMIS Hazard Symbols = Information pertaining to particular dangers for man and environment: The product has to be labelled due to the calculation procedure of international guidelines. Harmful by inhalation and if swallowed. Danger of cumulative effects. May cause sensitisation by skin contact. Possible risk of impaired fertility. Contains lead. Should not be used on surfaces liable to be chewed or sucked by children. Classification system: NFPA ratings (scale 0 - 4) 2 1 0 Health = 2 Fire = 1 Reactivity = 0 (Contd. on page 2) USA DR Page 2/7 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 07/25/2003 Reviewed on 07/14/2003 Trade name: 256GS Sn55Pb45, Sn60Pb40, Sn62Pb38, Sn63Pb37, Sn65Pb35 (Contd. of page 1) HMIS-ratings (scale 0 - 4) HEALTH *2 FIRE 1 REACTIVITY 0 Health = *2 Fire = 1 Reactivity = 0 4 First aid measures General information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: Induce vomiting, if person is conscious. Seek medical help. 5 Fire fighting measures Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Special hazards caused by the material, its products of combustion or resulting gases: In case of fire, the following can be released: Carbon monoxide (CO) Carbon dioxide (CO2) Aliphatic aldehydes Melted solder above 1000°F will liberate toxic lead and/or antimony fumes. Protective equipment: Wear self-contained respiatory protective device. 6 Accidental release measures Person-related safety precautions: Ensure adequate ventilation Measures for environmental protection: Do not allow product to reach sewage system or any water course. Measures for cleaning/collecting: Scoop up paste and deposit in appropriate containers. 7 Handling and storage Handling: Information for safe handling: Wash hands after handling paste and before eating or smoking. Care should be taken to remove paste from under fingernails. Information about protection against explosions and fires: Keep respiratory protective device available. Storage: o Requirements to be met by storerooms and receptacles: Store at or near 5 C in a dry location. Information about storage in one common storage facility: Not required. (Contd. on page 3) USA DR Page 3/7 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 07/25/2003 Reviewed on 07/14/2003 Trade name: 256GS Sn55Pb45, Sn60Pb40, Sn62Pb38, Sn63Pb37, Sn65Pb35 (Contd. of page 2) Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. 8 Exposure controls and personal protection Additional information about design of technical systems: No further data; see item 7. Components with limit values that require monitoring at the workplace: 7440-31-5 tin PEL 2 mg/m³ Metal REL 2 mg/m³ Tin, Metal TLV 2 mg/m³ 7439-92-1 lead PEL 0.05* mg/m³ as Pb REL <0.1* mg/m³ as Pb; *Blood Pb <0.06 mg/100 g whole blood TLV 0.05 mg/m³ as Pb; BEI 8050-09-7 Rosin PEL (Colophony) TLV SEN; (L) Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Breathing equipment: When ventilation is not sufficient to remove fumes from the breathing zone, a safety approved respirator or selfcontained breathing apparatus should be worn. Protection of hands: S Protective gloves Material of gloves: Nitrile rubber, NBR Natural rubber, NR Penetration time of glove material: The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: R Tightly sealed goggles (Contd. on page 4) USA DR Page 4/7 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 07/25/2003 Reviewed on 07/14/2003 Trade name: 256GS Sn55Pb45, Sn60Pb40, Sn62Pb38, Sn63Pb37, Sn65Pb35 (Contd. of page 3) Safety glasses 9 Physical and chemical properties General Information Form: Color: Odor: Pasty Silver grey Mild Change in condition Melting point/Melting range: > 100°C (> 212°F) Boiling point/Boiling range: Undetermined. Flash point: > 93°C (> 199°F) Danger of explosion: Product does not present an explosion hazard. Density at 20°C (68°F): > 7 g/cm³ Solubility in / Miscibility with Water: Insoluble. 10 Stability and reactivity Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Materials to be avoided: Strong acids, strong oxidizers. Dangerous reactions No dangerous reactions known. Dangerous products of decomposition: When heated to soldering temperatures, the solvents are evaporated and rosin may be thermally degraded to liberate aliphatic aldehydes and acids. 11 Toxicological information Acute toxicity: Primary irritant effect: on the skin: Possible local irritation by contact with flux or fumes. on the eye: Smoke during soldering can cause eye irritation. through inhalation: Flux fumes during soldering may cause irritation and damage of mucous membranes and respiratory system. through ingestion: May be harmful if swallowed. Sensitization: Sensitization possible through skin contact. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Harmful Irritant USA (Contd. on page 5) DR Page 5/7 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 07/25/2003 Reviewed on 07/14/2003 Trade name: 256GS Sn55Pb45, Sn60Pb40, Sn62Pb38, Sn63Pb37, Sn65Pb35 (Contd. of page 4) 12 Ecological information General notes: Do not allow product to reach ground water, water course or sewage system. 13 Disposal considerations Product: Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. 14 Transport information DOT regulations: Hazard class: Not regulated. Land transport ADR/RID (cross-border): ADR/RID class: Not regulated. Maritime transport IMDG: IMDG Class: Not regulated. Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: Not regulated. 15 Regulations USA The following information relates to product regulation specific to the USA. SARA (Superfund Amendments and Reauthorization Act) Section 355 (extremely hazardous substances): None of the ingredient is listed. Section 313 (Specific toxic chemical listings): 7439-92-1 lead TSCA (Toxic Substances Control Act): All ingredients are listed. California Proposition 65 Chemicals known to cause cancer: WARNING: This product contains a chemical known to the State of California to cause cancer. 7439-92-1 lead (Contd. on page 6) USA DR Page 6/7 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 07/25/2003 Reviewed on 07/14/2003 Trade name: 256GS Sn55Pb45, Sn60Pb40, Sn62Pb38, Sn63Pb37, Sn65Pb35 (Contd. of page 5) 25013-16-5 tert-butyl-4-methoxyphenol 7440-43-9 cadmium 7440-02-0 nickel Chemicals known to cause reproductive toxicity: WARNING: This product contains a chemical known to the State of California to cause birth defects and/or other reproductive harm. 7439-92-1 lead 872-50-4 N-methyl-2-pyrrolidone 7440-43-9 cadmium Carcinogenicity categories EPA (Environmental Protection Agency) 7439-92-1 lead B2 IARC (International Agency for Research on Cancer) 7439-92-1 lead 2B NTP (National Toxicology Program) None of the ingredients is listed. TLV (Threshold Limit Value established by ACGIH) None of the ingredients is listed. NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. CANADA: The following information relates to product regulation specific to Canada. Workplace Hazardous Materials Identification (WHMIS): This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulation (CPR) and the MSDS contains all of the information required by the CPR. WHMIS Classification: D2A D2B Components on Ingredient List for WHMIS: Rosin, polymerized lead tin EUROPEAN UNION The following information relates to product regulation specific to the directives of the Euopean Union. Risk phrases: Harmful by inhalation and if swallowed. Danger of cumulative effects. May cause sensitisation by skin contact. Possible risk of impaired fertility. (Contd. on page 7) USA DR Page 7/7 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 07/25/2003 Reviewed on 07/14/2003 Trade name: 256GS Sn55Pb45, Sn60Pb40, Sn62Pb38, Sn63Pb37, Sn65Pb35 (Contd. of page 6) Safety phrases: Avoid exposure - obtain special instructions before use. Keep locked up and out of the reach of children. Avoid contact with skin. Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. Wear suitable gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Special labeling of certain preparations: Contains lead. Should not be used on surfaces liable to be chewed or sucked by children. 16 Other information The information contained herein is based on data considered accurate and is offered solely for information, consideration and investigation. Kester extends no warranties, makes no representations and assumes no responsibilty as to the accuracy, completeness or suitability of this data for any purchaser's use. The data on this Material Safety Data Sheet relates only to this product and does not relate to use with any other material or in any process. All chemical products should be used only by, or under the direction of, technically qualified personnel who are aware of the hazards involved and the necessity for reasonable care in handling. Hazard communication regulations require that employees must be trained on how to use a Material Safety Data Sheet as a source for hazard information. Department issuing MSDS: Product Safety Contact: Heather Holich, MSDS Coordinator Tel. (847)699-5755 USA DR 1 of 2 Quality Through People and Technology Amerway Silver Solder Flux Material Safety Data Sheet Section 01 Information furnished by: Date effective: Emergency phone: Chemtrec: Product or trade name: Product Use: Person to contact: Identification Amerway, Inc. 3701 Beale Avenue Altoona, PA 16601 1/01/08 1-814-944-0200 1-800-424-9300 Amerway Silver Solder Flux Silver Soldering Terry Buck Section 02 Constituents Chem CAS %Wt. PEL/PPM Zinc Chloride 7646-85-7 30-45 1 mg/m^3 Ammonium Chloride 12125-02-09 5-15 10.0 mg/m^3 Ammonium Biflouride 1341-49-7 2-7 2.5 mg/mg^3 Hydrochloric Acid 7647-01-0 3-6 5 ppm All ingredients are reported in EPA and TSCA inventory. Unlisted ingredients are considered non-toxic. None of the materials in this product are listed in NTP, IARC, or OSHA as carcinogens. TLV/PPM 1 mg/m^3 10.0 mg/m^3 2.5 mg/mg^3 5 ppm Section 03 Melting Point Boiling Point Vapor Pressure Vapor Density ( air is 1) Solubility in Water Appearance & Color Specific Gravity Odor % Volatile pH Evaporation Rate :(nBuAc=1) Physical Data N/A 212 F N/A N/A 100 % Clear Liquid 1.5 Acidic 65% 1.0 6 Section 04 Flash Point / Method Used Flammable Limits Extinguishing Media Fire Fighting Equipment Special Precautions Fire and Explosion Hazard Data None None N/A Water or with non-flammable salts. None Section 05 Stability Conditions to Avoid Hazardous Polymerization Incompatibility Hazardous Decomposition Products Reactivity Data Stable Inhalation of fumes. Will not occur. Alkalis None known. Section 06 Action to take for spills/leaks Disposal method Spill, Leak and Disposal Procedures Dilute with water. Dispose of per federal, state and local regulations. 2 of 2 Section 07 Eye Skin Contact Skin Absorption Ingestion Inhalation Systemic & Other Effects Section 08 Eyes Skin Ingestion Inhalation Note to Physician Section 09 Ventilation Respiratory Protection Eye Protection Skin Protection Other Section 10 Storage Handling Information Website by Precision Business Solutions Health Hazard Data Higher concentrations can cause eye irritations. May cause skin irritation. Will cause skin irritation. Do not induce vomiting, give two glasses of milk or water, contact a physician. Remove to fresh air, contact a physician. None known. First Aid Procedures Wash with water for 10 minutes, contact physician. Wash with soap and water. Do not induce vomiting, give two glasses of milk or water. Contact a physician. Remove to fresh air, contact a physician. Salt solution of chlorine and fluorine. Special Handling Information Fume hood or mechanical ventilation must be provided to maintain exposure levels below TLV’s. Use NIOSH/OSHA approved respirator for dust and acid fumes. Wear safety goggles during use. Wear rubber apron and gloves. Follow NIOSH/OSHA health guidelines for chemical hazards. Special Precautions and Additional Information Store in dry cool place. When handling use proper safety procedures. © Amerway.com MATERIAL SAFETY DATA SHEET PLEASE CAREFULLY READ AND UNDERSTAND THIS MATERIAL SAFETY DATA SHEET BEFORE USING THIS PRODUCT May be used to comply with OSHA’s Hazards Communication Standard, 29 CFR 1910.1200. Standard must be consulted for specific requirements. SECTION I (IDENTIFICATION) Manufacturer/Supplier Name: UNIWELD PRODUCTS, INC. 2850 Ravenswood Road Fort Lauderdale, FL 33312 Emergency Phone No.: Product Name(s): Product Classification: PROPANE ODORIZED LIQUIFIED PETROLEUM GAS (PARAFFINIC HYDROCARBONS) (954) 584-2000 SECTION II (HAZARDOUS INGREDIENTS/IDENTITY INFORMATION) Important: Propane may contain various percentages of these hazardous components, depending on the source of supply. EXPOSURE LIMIT (mg/m3) INGREDIENT % WEIGHT CAS NO. 85-100 74-98-6 PROPYLENE 0-10 115-07-1 BUTANE & HEAVIER 0-2.5 106-97-8 ETHANE 0-5 74-84-0 ETHYL MERCAPTAN (ODORANT) <0.1 75-08-1 PROPANE OSHA PEL/TWA ACGIH TLV/TWA 1,000 PPM 800 PPM 800 PPM SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS Property Value Appearance and odor Colorless gas, liquid under pressure. Mercaptan “rotten eggs” odor Boiling point -44 degrees F. Evaporation rate (Butyl Acetate = 1) <1 (diffuses readily) Flash point -156 degrees F. Liquid to vapor expansion ratio 1:270 Molecular weight 44.096 Solubility in water Slight Specific gravity (liquid) 0.500 - 0.510 (Water = 1) Specific gravity (vapor) 1.52 (Air = 1) Vapor pressure (maximum) 208 PSIG @ 100 degrees F. SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flammability limits Ignition temperature Extinguishing media Special fire-fighting procedures and precautions Flammability limits by volume in air. Lower 2.15 percent Upper 9.6 percent Auto ignition temperature is 940 degrees Fahrenheit. Allow product to burn if source cannot be shut off safely. Class B-C or A-B-C dry chemical or halon extinguishers can be used on small fires. Apply water from a safe distance to cool containers, surrounding equipment, and structures. Extremely flammable. Containers may explode if not sufficiently cooled with water spray. Evacuate surrounding area of unprotected personnel and isolate. Do not enter confined fire space without full bunker gear (helmet with face shield, bunker coats, gloves, and rubber boots) and a positive pressure NIOSH-approved self-contained breathing apparatus. SECTION V - REACTIVITY DATA Stability and hazardous polymerization Conditions and materials vapor accumulation. This product is stable. Hazardous polymerization will not occur. Avoid heat, sparks, flame, and contact with strong oxidizing agents. Avoid buildups of static electricity. Prevent to avoid Hazardous decomposition products Carbon monoxide and unidentified organic products may be formed during combustion. Purpose Eye contact Skin contact Inhalation The health effects are consistent with requirements of the OSHA Hazard Communication Standard (29 CFR 1910.1200). Direct contact with liquid propane can result in eye burns. Direct contact with liquid propane can result in skin burns (frostbite). This product is classified as a simple asphyxiant. High vapor concentrations may produce a reversible central nervous system depression (anesthesia). Higher concentrations may produce asphyxiation. WARNING: DO NOT BREATHE FUMES! Ingestion is not likely. Eye or skin burns (frostbite) as noted previously. Early to moderate central nervous system depression may be evidenced by giddiness, headache, dizziness, and nausea. In extreme cases, unconsciousness may occur. Asphyxiation may be noted by a sudden loss of consciousness. Death may quickly follow. Caution is recommended for personnel with pre-existing central nervous system or chronic respiratory diseases. SECTION VI - HEALTH HAZARD DATA Ingestion Signs and symptoms Aggravated medical conditions Acute toxicity data Carcinogenicity Occupational exposure limits Cardiac effects Acute toxicity data is not applicable to this product. This product is not classified as a carcinogen. See the table in section 2 While there is no evidence that exposure to industrially acceptable levels of hydrocarbons have produced cardiac effects in humans, animal studies have shown that inhalation of high vapor levels of the components of this product have produced CONTINUED ON THE BACK Effects of propylene cardiac sensitization. Such sensitization may cause fatal changes in heart rhythms. This latter effect was shown to be enhanced by hypoxia or the injection of adrenaline-like agents. Laboratory animals exposed to high levels of propylene for prolonged periods of time showed evidence of effects in the liver, kidneys, and nasal cavity. SECTION VII - PRECAUTIONS FOR SAFE HANDLING & USE Release, spill, or leak procedures Warning! Extremely flammable. Eliminate sources of ignition. Isolate hazard area and deny entry to unnecessary or unprotected personnel. Stay upwind and keep out of low areas. Notify local fire department. Disperse vapor clouds with water spray. Shut off source of leak only if it can be done safely. Training Train all personnel involved in handling propane in proper handling and operating procedures. Document all training. Handling and storing Handle and store propane in accordance with NFPA 58 and local fire codes. Keep containers away from heat sources or temperatures exceeding 130 degrees Fahrenheit. Do not drop or roll any container. Store and transport containers with relief valves in vapor space. Keep all container valves closed when not in use. Keep protective caps (if applicable) on containers when not in use. DOT cylinders Take these precautions when using DOT cylinders: Periodically inspect and requalify DOT cylinders in accordance with DOT and NFPA 58 codes. Store and use cylinders with valves off and the relief valves in the container vapor space. Shut all valves and follow recommended procedures before exchanging cylinders. Special precautions Containers, even those that have been emptied, can contain explosive vapors. Do not cut, drill, grind, weld or perform similar operations on or near containers. Propane odorization Warning! Any smell of odorant, even a faint one, may indicate a dangerous situation. Ethyl mercaptan is the preferred warning agent for propane. Although ethyl mercaptan has excellent warning properties, “It is recognized that no odorant will be completely effective as a warning agent in every circumstance” (NFPA 58 A-1-4.1, 1992 edition). Instances in which odorants may lose their effectiveness include, but are not limited to the following: Odor may fade due to chemical oxidation in improperly prepared new tanks and cylinders or from rust, air and water in used containers that have been allowed to stand open to the atmosphere. Odor may be absorbed and adsorbed by the walls of containers and distribution systems. Odor in the gas escaping from underground leaks may be absorbed by certain types of soils. Effectiveness of the odorant may be reduced by cold temperatures. Other odors, such as from cooking or from a musty basement, may mask or cover up the mercaptan odor in propane. Exposure to the mercaptan odor of propane for extended periods of time may affect a person’s ability to detect the odorant. Physical disabilities or the use of alcohol, tobacco, or drugs may decrease a person’s ability to detect the odorant. WARNING: CALIFORNIA PROPOSITION 65: This product, when used for welding, soldering, brazing, cutting and other metal working or flame processes, produces fumes, particulates, residues and/or other by-products which contain chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. SECTION VIII - FIRE AND EXPLOSION HAZARDS Flammability limits Ignition temperature Extinguishing media Flammability limits by volume in air. Lower 2.15 percent Upper 9.6 percent Auto ignition temperature is 940 degrees Fahrenheit. Allow product to burn if source cannot be shut off safely. Class B-C or A-B-C dry chemical or halon extinguishers can be used on small fires. Apply water from a safe distance to cool containers, surrounding equipment, and structures. Extremely flammable compressed gas.• Asphyxiant in high concentrations. • Skin contact with liquid causes burns similar to frostbite. • Ethyl mercaptan used as a warning agent may not be entirely effective in all situations. Read the warnings in section 7. NFPA hazard Hazard ratings are in the following table rating Fire Hazard Health hazard = 1 Health Fire hazard = 4 Hazard Reactivity = 0 Where: 0 = Least 3 = High Reactivity 1 = Slight 4 = Extreme 2 = Moderate Warning! 4 1 0 SECTION VIIII - EMERGENCY AND FIRST AID PROCEDURES Purpose Eye contact with liquid Skin contact with liquid Inhalation Ingestion Follow these procedures in case of personal injuries resulting from use of this product. Flush eyes with water. Get medical attention. Flush with water. If frostbite or burn occurs, get medical attention. Remove victim to fresh air and provide oxygen if breathing is difficult. Seek immediate medical attention if victim is not breathing. Give artificial respiration. Not applicable to this product. SECTION X - EMPLOYEE PROTECTION Respiratory protection Use a NIOSH-approved respirator as required when airborn exposure limits are exceeded. In accord with 29 CFR 1910.134, use either an atmosphere supplying respirator or an air purifying respirator for organic vapors. WARNING: DO NOT BREATHE FUMES! Protective clothing Avoid liquid contact with eyes or skin. Wear safety glasses or goggles as appropriate. Wear protective clothing as appropriate. Additional protective measures Use explosion-proof ventilation as required to control vapor concentrations. SECTION XI - TRANSPORTATION REQUIREMENTS DOT shipping name DOT classification Other DOT requirements Liquefied Petroleum Gas Division 2.1 (Flammable Gas) UN 1075, Hazardous Materials Guide Number 115. EPA/TSCA EPA Hazard Classification The components of this product are listed on the EPA/TSCA inventory of chemical substances. This product is classified by 40 CFR 372 (SARA Section 313) as: SECTION XII - OTHER REGULATORY CONTROLS Acute Hazard Chronic Hazard XXX Ozone-depleting substances RCRA Information State regulatory information Fire Hazard Pressure Hazard XXX XXX Reactive Hazard This product does not contain, nor was it directly manufactured with, any class I or class II ozone-depleting substances. This product is not subject to 40CFR 268.30 ban on the disposal of hazardous wastes. If this product becomes a waste material, it would be an ignitable hazardous waste, having a waste code number D0001. Refer to latest EPA or state regulations regarding proper disposal. Under EPA-RCRA, containers are considered hazardous unless depressurized to a pressure approaching atmospheric. Depressurize containers at a controlled rate to a flare. The ingredients in this product are specifically listed by individual states; other product specific health and safety data in other sections of the MSDS may also be applicable for state requirements. Contact the appropriate agency in your state for details on your regulatory requirements. Uniweld Products, Inc. believes this data to be accurate and to reflect qualified expert opinion regarding current research. Uniweld Products, Inc. cannot make any expressed or implied warranty as to this information. MSD50 Effective Date: January, 2008 Material Safety Data Sheet Section 1 Product Name: Revision #: 2.0 Product and Company Identification BLOC-IT Heat Sink Paste Date Prepared: May 23, 1991 Manufacturer: Date Revised: June 14, 2004 Supplier/Importer: LA-CO INDUSTRIES, Inc./Markal Co. 1201 Pratt Blvd. Elk Grove Village, IL, USA 60007-5746 Information Telephone: 847-956-7600 Emergency Telephone: Call CHEMTREC USA 800-424-9300 International (Call Collect) 1-703-527-3887 Chemical Formula: Mixture CAS No.: Not Applicable. Derivation: Not Applicable. Synonyms: Not Applicable. General Use: Heat sink paste for protecting heat sensitive areas when soldering, brazing or welding. Section 2 Composition/Information on Ingredients Ingredient CAS No. No Hazardous ingredients according to the U.S. OSHA Hazard Communication Standard 29 CFR 1910.1200, Canadian WHMIS regulations, British CHIP2 regulation 6, and Australian Regulations for the Control of Workplace Hazardous Substances. (For Section 2 footnotes: See Section 15) Section 3 Hazards Identification EMERGENCY OVERVIEW: None. POTENTIAL HEALTH EFFECTS Primary Exposure Routes: Not Applicable. Acute Effects Eyes: Not Applicable. Skin: Not Applicable. Ingestion: Not Applicable. Inhalation: Not Applicable. Chronic Effects Eyes: Not Applicable. Skin: Not Applicable. Ingestion: Not Applicable. Inhalation: Not Applicable. Carcinogenicity: Not Applicable. Target Organ Effects: Not Applicable. Medical Conditions Aggravated by Long-Term Exposure: Not Determined. Other Information: Not Applicable. Page 1 of 5 % Product Name: Revision #: 2.0 BLOC-IT Heat Sink Paste Date Prepared: May 23, 1991 Section 4 Date Revised: June 14, 2004 First Aid Eye Contact: Flush with water. Skin Contact: Rinse with water. Ingestion: Not Applicable. Inhalation: Not Applicable. Other Information: Not Applicable. Section 5 Fire Fighting Measures Flash Point (method): Not Applicable. Autoignition Temperature: Not Applicable. LEL: Not Applicable. UEL: Not Applicable. Flammability Classification: Not Applicable. Extinguishing Media: Not Applicable. Hazardous Combustion Products: Possibly carbon monoxide. Unusual Fire or Explosion Hazards: Not Applicable. Fire-Fighting Instructions/Equipment: Keep personnel removed and upwind of any fire. Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA). Section 6 Accidental Release Measures Use recommended personal protective equipment (see Section 8). Spill: CAUTION: Spill area may be slippery. Scrape up bulk. Mop spill area with water. Section 7 Handling and Storage Handling Precautions: Use recommended personal protective equipment (see Section 8). Wash thoroughly after handling. Storage Requirements: Store away from incompatible chemicals (see Sec. 10). Store in a cool, dry area. Section 8 Exposure Controls/Personal Protection Eye/Face Protection: Suitable for related activities where this product is used. Skin/Hand Protection: Suitable for related activities where this product is used. Respiratory Protection: Suitable for related activities where this product is used. Other Equipment: Eye wash and safety shower. Suitable for related activities where this product is used. Engineering Controls: Suitable for related activities where this product is used. Administrative Controls: Users of this product must be properly trained and qualified in its use. Other Information: No food or beverage should be consumed in the work area. Wash thoroughly before eating, drinking, or smoking. Section 9 Physical and Chemical Properties Appearance/Physical State: Light pink to beige paste. Odor: Negligible. Odor Threshold (ppm): Not Determined. Specific Gravity (H2O = 1): 1.0 to 1.1 Page 2 of 5 Product Name: Revision #: 2.0 BLOC-IT Heat Sink Paste Date Prepared: May 23, 1991 Date Revised: June 14, 2004 Solubility - Water: Soluble - Fat: Insoluble Coefficient of Water/Oil Solubility: >>1 Partition Coefficient (n-octanol/water): <<1 pH: Neutral Melting Point: Not Determined. Boiling Point: 2120F/1000C Vapor Pressure (mm Hg at 200C): Not Determined. Vapor Density (Air = 1): Not Determined. Evaporation Rate (n-BuAc=1): <1 V.O.C.: 0%(w/w), 0%(v/v), 0 lbs./gal.(U.S.), 0 kg/l Flash Point (method): (see Section 5) Autoignition Temperature: (see Section 5) Flammability Classification: (see Section 5) Unusual Fire or Explosion Hazards: (see Section 5) Oxidizing Properties: Not Applicable. Other Information: None. Note: The physical data represented above are typical values and should not be construed as a specification. Section 10 Stability and Reactivity Chemical Stability: Stable Hazardous Polymerization: Will Not Occur Conditions to Avoid: Not Applicable. Chemicals to Avoid: Not Determined. Hazardous Decomposition Products (non-thermal): Not Applicable. Section 11 Toxicological Information Sensitization to Product: Not Applicable. Irritancy of Product: Not Applicable. Reproductive Toxicity: Not Applicable. Teratogenicity: Not Applicable. Mutagenicity: Not Applicable. Further hazard information, if applicable, may be found in Section 3. Toxicological information regarding individual ingredients, if applicable, may be found in Section 2. Section 12 Ecological Information Mobility: Not Determined. Degradability: Not Determined. Accumulation: Not Determined. Section 13 Ecotoxicity: Not Determined. Other Adverse Effects: Not Determined. Disposal Considerations Dispose of in accordance with all applicable regulations. Page 3 of 5 Product Name: Revision #: 2.0 Section 14 BLOC-IT Heat Sink Paste Date Prepared: May 23, 1991 Date Revised: June 14, 2004 Transport Information D.O.T. (U.S.) Proper Shipping Name: Not Regulated. Hazard Class or Division: Not Regulated. Hazard Label: Not Regulated. I.D. Number: Not Regulated. TDG (Canada): Not Regulated. IATA: Not Regulated. ICAO: Not Regulated. IMO: Not Regulated. Australian Code for the Transport of Dangerous Goods Dangerous Goods Class and Subsidiary Risk: Not Regulated. Section 15 Regulatory Information Footnotes for Section 2: 1 2 3 4 5 6 Subject to the reporting requirements of SARA Title III, Section 313. Appears on the California Safe Drinking Water and Toxic Enforcement Act (Prop. 65) Substances List. Appears on the Massachusetts Substances List. Appears on the New Jersey Right-To-Know Hazardous Substances List. Appears on the Pennsylvania Hazardous Substances List. Appears on the Canadian WHMIS Ingredient Disclosure List. U.S.A. OSHA Hazard Status: This product is not considered to be hazardous as defined by the U.S. OSHA HCS (29 CFR 1910.1200). EPA SARA sec. 311/312 Hazard Categories: Not Applicable. Toxic Substances Control Act (TSCA): All ingredients contained in this product are listed on the U.S. EPA TSCA Chemical Substance Inventory. HMIS Rating: Health 0, Flammability 0, Reactivity 0 NFPA Rating: Health 0, Flammability 0, Reactivity 0 CANADA WHMIS Status: This product is not considered to be hazardous as defined by Canadian WHMIS Controlled Products Regulations. WHMIS Rating: None. WHMIS Risk Phrases: None. WHMIS Precautionary Statements: None. Domestic Substances List (DSL): All ingredients contained in this product are listed on the Canadian EPA (CEPA) Domestic Substances List (DSL). E.U. European Inventory of Existing Chemical Substances (EINECS): All ingredients contained in this product are listed on the European Inventory of Existing Chemical Substances (EINECS). Categories of Danger (Labeling Information): None. Risk (R) Phrases: None. Safety (S) Phrases: Keep out of reach of children (S2 AUSTRALIA Worksafe Australia Status: This product is not classified as hazardous according to criteria of Worksafe Australia. HAZCHEM Code: None allocated. Poisons Schedule Number: None allocated. Page 4 of 5 Product Name: Revision #: 2.0 BLOC-IT Heat Sink Paste Date Prepared: May 23, 1991 Date Revised: June 14, 2004 Further regulatory information regarding individual ingredients, if applicable, may be found in Section 2. This product has been classified in accordance with the hazard criteria of the U.S. OSHA Hazard Communication Standard, the Canadian WHMIS Controlled Products Regulations, the British CHIP2 regulation 6, and the Australian NMRCWHS. This MSDS contains the information required by the above regulations and conforms to ANSI Z400.1-1993. Section 16 Other Information MSDS Prepared By: Director of Chemical Safety The information contained herein is based on data available to us and is accurate and reliable to the best of our knowledge and belief. However, LA-CO Industries, Inc. makes no representations as to its completeness or accuracy. Information is supplied on condition that persons receiving such information will make their own determination as to its suitability for their purposes prior to use. In no event will LA-CO Industries, Inc. be responsible for damages of any nature whatsoever resulting from the use of or reliance upon the information contained herein. Page 5 of 5 MATERIAL SAFETY DATA SHEET S O S PRODUCTS COMPANY INC 4th and Railroad Streets East Greenville, Pa. 18041 Phone (215-679-6262 (215)-679-6263 PAGE 1 ----------------------------------------------------------------------------SECTION I - GENERAL INFORMATION ----------------------------------------------------------------------------Product Code: PVCC Revision Date:08/06/07 Identification: PVC CEMENT MEDIUM BODY ----------------------------------------------------------------------------SECTION II - HAZARDOUS INGREDIENTS ----------------------------------------------------------------------------OSHA ACG/H RATING INGREDIENT: PEL TLV H-F-R CAS. NO ----------------------------------------------------------------------------TETRAHYDROFURAN 200 PPM 200 PPM 2-3-1 109-99-9 *METHYL ETHYL KETONE 200 PPM 200 PPM 1-3-0 78-93-3 CYCLOHEXANONE 25 PPM 25 PPM 1-2-0 108-94-1 *ACETONE 750 PPM 750 PPM 1-3-0 67-64-1 ----------------------------------------------------------------------------*SUBJECT TO REPORTING REQUIREMENTS OF SARA TITLE III SECTIION 313. ----------------------------------------------------------------------------Carcinogenicity: This product is NOT considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the Occupational Safety and Health Administration. ----------------------------------------------------------------------------SECTION III - PHYSICAL CHARACTERISTICS ----------------------------------------------------------------------------Boiling Point: 133 F Specific Gravity: (Water = 1) 0.91 Vapor Pressure: (mm Hg) 182 Melting Point: N/A Vapor Density: (Air = 1) 2.5 Evaporation Rate: 8 Solubility in Water: NIL (Butyl Acetate = 1) Odor and Appearance: COLORED LIQUID, ACETONE-LIKE ODOR ----------------------------------------------------------------------------SECTION IV - FIRE AND EXPLOSION HAZARD DATA ----------------------------------------------------------------------------Flash Point: -4 F LEL: 2% Flammable Limits: N/A UEL: 13% Extinguishing Media: DRY CHEMICAL OR CARBON DIOXIDE OR FOAM. Special Fire Fighting Procedures: DIRECT EXTINGUISHER AT BASE OF FLAMES. Unusual Fire and Explosion Hazards: VAPOR HEAVIER THAN AIR & MAY TRAVEL ALONG FLOOR OR GROUND TO IGNITION SOURCES FROM USE AREA. ----------------------------------------------------------------------------SECTION V - REACTIVITY DATA ----------------------------------------------------------------------------This product is STABLE. Conditions to avoid: KEEP IN CLOSED CONTAINERS, AWAY FROM SPARKS &/OR FLAME. Incompatibility: STRONG OXIDIZERS. Hazardous Decomposition: CARBON DIOXIDE, CARBON MONOXIDE, HYDROGEN CHLORIDE. Hazardous Polymerization: WILL NOT OCCUR. ----------------------------------------------------------------------------SECTION VI - HEALTH HAZARD DATA PAGE 2 ----------------------------------------------------------------------------Routes of Entry: Inhalation? YES - PRIMARY Skin? YES - PRIMARY Ingestion? YES - SECONDARY Health Hazards (Acute and Chronic): BREATHING: EXCESSIVE INHALATION CAN CAUSE NASAL & RESPIRATORY IRRITATION & CENTRAL NERVOUS SYSTEM DEFECTS. SKIN: PROLONGED OR REPEATED CONTACT CAN CAUSE MODERATE IRRITATION, BURNS IF NOT REMOVED. CHRONIC OVEREXPOSURE HAS APPARANTLY BEEN FOUND TO CAUSE THE FOLLOWING EFFECTS IN LAB ANIMALS: LIVER ABNORMALITIES, KIDNEY, LUNG, & BRAIN DAMAGE. Carcinogenicity: NTP? NO IARC Monographs? NO OSHA Regulated? NO Signs and Symptoms of Exposure: INHALATION: DIZZINESS, HEADACHE, NAUSEA. SKIN: IRRITATION, DEFATTING. EYES: IRRITATION, REDNESS. Medical Conditions Generally Aggravated by Exposure: NO INFORMATION AVAILABLE. Emergency and First Aid Procedures: INHALATION: REMOVE TO FRESH AIR. SKIN: FLUSH WITH WATER & REMOVE CONTAMINATED CLOTHING. EYES: FLUSH REPEATEDLY WITH WATER. ----------------------------------------------------------------------------SECTION VII - HANDLING PRECAUTIONS ----------------------------------------------------------------------------Steps to be Taken if Material is Released or Spilled: ELIMINATE IGNITION SOURCES, FLAMES, PILOT LIGHTS & TURN OFF ELECTRIC MOTORS. ABSORB LIQUID ON RAGS OR PAPER TOWELS & REMOVE TO OUTDOORS. VENTILATE AREA. Waste Disposal Method: DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, LOCAL REGULATIONS. Precautions to be Taken in Handling and Storage: STORE IN COOL AREA AWAY FROM PILOT LIGHTS & IGNITION SOURCES. Other Precautions: KEEP CONTAINER CLOSED WHEN NOT IN USE. ----------------------------------------------------------------------------SECTION VIII - CONTROL MEASURES ----------------------------------------------------------------------------Respiratory Protection: USE NIOSH APPROVED RESPIRATOR IF TLV EZPOSUER LIMITS ARE EXCEEDED. Ventilation Required: LOCAL EXHAUST: OPEN DOORS & WINDOWS. USE ONLY IN A WELL-VENTILATED AREA. USE MECHANICAL EXHAUST IF NECESSARY TO MAINTAIN EXPOSURE BELOW TLV. Protective Gloves: WEAR RUBBER GLOVES IF EXCESSIVE SKIN CONTACT MAY OCCUR. Eye Protection: WEAR EYE PROTECTION IF SPLASHING OF PRODUCT IS LIKELY. Other Protective Equipment: NONE. Work/Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. ----------------------------------------------------------------------------The above information pertains to the product as it is currently formulated and is based upon the information available at this time. Additions of reducers or other additives to this product may substantially alter the composition and subsequent hazards of the product. Since conditions of use are outside of our control, we make no warranties, either expressed or implied, and assume no liability in connection with any use of this information. Silicone Grease IMS Company Validation Date: September 4, 2013 Page 1 of 3 Material Safety Data Sheet Section 1 - Manufacturer Information Manufacturer/Distributor IMS Company 10373 Stafford Road Chagrin Falls, OH 44023-5296 WEB: http://www.imscompany.com Emergency Phone # 800-424-9300 Prepared by Safety Advisor Prepared/Revised February 28, 2007 Sales: sales@imscompany.com Trade Names ...........Silicone Grease Part Numbers ...........100585 100586 100830 1 gallon can 5.3 ounce tube 2 ounce tube Replaces AER1-G128-G Replaces AER1-G053-T Replaces STXX-SG2 Hazardous Material Information System Health ................1 Flammability.............1 Reactivity ................. 0 Protection................. X * Chronic (Accumulates) 0 Normal use Material 0 Will Not Burn 0 Stable X = Consult the 1 Unstable if Heated MSDS and 1 Slight Hazard (temporary) 1 Possible to Burn 2 Health Affected (lengthy) 2 Burns if Heated 2 Violent Chemical Change your supervisor 3 Extreme Danger 3 Easily Burns 3 Shock and Heat Sensitive for your special 4 Very Easily Burns 4 Severe or Fatal 4 May Explode workplace need NOTE The HMIS may not be enough hazard information for this chemical in all workplaces. The HMIS system requires employee training about the system and about information in this MSDS. Section 2 - Ingredients Chemical/Common Name CAS-Number % PEL-OSHA Silica, Amorphous Fumed Polydimethylsiloxane Dimethyl Siloxane, hydro-terminated 7631-86-9 63148-62-9 70131-67-8 0.1 to 20 60 to 80 0.1 to 10 6 mg/m3 TWA 10 mg/m3 (2) (1) (1) (1) (1) (1) (2) TLV-ACGIH None Established Total dust Does this product contain carcinogens (NTP, IARC, or OSHA)? No Section 3 - Health Data HEALTH EFFECTS - (Acute and Chronic) Ingestion low ingestion hazard in normal use. Large amounts may cause digestive discomfort, but no known injury. Inhalation No significant effects expected from a single short-term exposure. Eye Direct contact could cause temporary discomfort with mild redness and dryness similar to windburn. Skin No significant irritation expected from a single short-term exposure. PRIMARY ROUTES OF ENTRY Inhalation, Skin MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE No known applicable information. EMERGENCY FIRST AID PROCEDURES IMS Company Validation Date: September 4, 2013 Eye Contact Silicone Grease Page 2 of 3 Material Safety Data Sheet Immediately flush thoroughly with water. Skin Contact Wipe off and flush with water. Inhalation No first aid should be needed. Ingestion No first aid should be needed. Section 4 - Chemical Data Boiling Point (F)................................ > 95° F (35° C) Vapor Pressure (PSIG) .................... NA Vapor Density (Air=1) ....................... NA Solubility in Water............................. NA Specific Gravity (Water=1) ...................... 1.1 Percent Volatile by Weight (%)................NA Evaporation Rate (Ether).........................NA Viscosity ..................................................500,000 cSt Appearance and Odor Information Viscous liquid (paste-like), translucent white, some odor Section 5 - Physical Data Flash Point (CC) ................................. > 214° F (101° C) Flammable Limits ............... LEL = NA UEL = NA Extinguishing Media Water spray, water fog, carbon dioxide, dry chemical, foam. Special Fire Fighting Procedures Self-contained breathing apparatus and protective clothing should be worn in fighting fires involving chemicals. Determine the need to evacuate or isolate the area according to your local emergency plan. Use water spray to keep exposed containers cool. Unusual Fire and Explosion Hazards None known. Incompatibility (Materials to Avoid) Oxidizing material can cause a reaction. Hazardous Decomposition Products Silicon Dioxide, Carbon oxides, traces of incompletely burned carbon products, formaldehyde. NOTICE This product contains methylpolysiloxanes, which when heated to temperatures above 300° F (150° C), in the presence of air, can form formaldehyde vapors. Formaldehyde is a potential cancer hazard, a known skin and respiratory sensitizer, eye and throat irritant, and an acute toxicant. Vapors irritate eyes, nose, and throat. Safe handing conditions may be maintained by keeping vapor concentrations within the OSHA permissible exposure limit for formaldehyde. (Note Product does not contain formaldehyde). Will Hazardous Polymerization Occur? No Conditions to Avoid for Polymerization NA Is the Product Stable? Yes Conditions to Avoid for Stability NA Section 6 - Spill or Leak Procedures Steps to be Taken in Case Material is Released or Spilled Small spill and general procedure; remove product and use absorbent material to take care of any oil-like residues. Large and unusual conditions; determine whether to evacuate or isolate the areas according to your local emergency plan. Observe all personal protective equipment recommendations. For large spills, provide diking or other appropriate containment to keep material from spreading. Clean up remaining materials as appropriate since silicone materials, even in small quantities, present a slip hazard. IMS Company Validation Date: September 4, 2013 Silicone Grease Page 3 of 3 Material Safety Data Sheet Final cleaning may require use of steam, solvents, or detergents. Dispose of saturated absorbent or cleaning materials in a sealed container, or totally exposed to air, since spontaneous heating – combustion may occur. Waste Disposal Methods Not classified as a hazardous waste. If uncontaminated, use as appropriate. If not useable, mix with absorbent materials such dried clay or absorbent pads, or set out to harden in open air – may take a long time, and send to landfill. Follow local, State and Federal disposal procedures. Section 7 - Exposure Control Information Ventilation No local exhaust should be needed. Mechanical (general) ventilation recommended. Respiratory Protection None should be needed if not sprayed. If sprayed, use appropriated mist respirator. Consult with your safety equipment supplier. Protective Gloves Where prolonged or repeated contact with the spray mist or the deposited product is likely, the use of impervious gloves (for example neoprene or nitrile) is indicated. Other Protective Equipment If contact with the material in any manner is likely, eye protection is recommended. Chemical Monogoggles or safety glasses with side shields and a face shield will provide protection in most situations. Do not wear contact lenses. Other Engineering Controls To determine exposure levels, monitoring should be performed Work Practices Do not use in confined or closed space. Ventilation should maintain the concentration of the product or its components below the TLV/PEL value. Hygienic Practices Wash thoroughly before eating or smoking after using this or any chemical product. This product transferred to a lighted cigarette will result in the hazardous decomposition products. It is good practice to remove large amount of any chemical from the skin as soon as practical. Section 8 - Special Precautions Precautions to be Taken in Handling and Storage Avoid spreading onto red hot surfaces, which may cause decomposition. Maintenance Precautions Do not remove or deface label. Additional Comments CAUTION Intentional misuse of this chemical product, as with any industrial chemical, in contact with the body can be harmful or fatal. This includes such things as deliberately breathing, placing in mouth, swallowing, placing on skin, or any other body contact, or repeated, or continuous contact. IMS provides this information in good faith, but makes no representation as to its comprehensiveness or its accuracy. This document is offered as a guide to a trained person, for appropriate precautionary handling. Persons using the product and receiving the information must exercise independent judgment in determining the appropriateness of the use and the safety information for their particular purpose. IMS MAKES NO REPRESENTATIONS OR WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THIS INFORMATION OR TO THE PRODUCT. ACCORDINGLY, IMS WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE ON THIS INFORMATION. MATERIAL SAFETY DATA SHEET S O S PRODUCTS COMPANY INC P. O. Box 47 East Greenville, Pa. 18041 Phone (215)-679-6262 (215)-679-6263 Product Code: SECTION I TFD - PAGE 1 GENERAL INFORMATION Revision Date: 08/06/07 SECTION II - HAZARDOUS INGREDIENTS This product is not classified as hazardous in accordance with OSHA 1910.1200 Carcinogenicity: This product is NOT considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the Occupational Safety and Health Administration. SECTION III - PHYSICAL CHARACTERISTICS Boiling Point: N/A Specific Gravity: 1.55 Vapor Pressure: N/A Melting Point: N/A Vapor Density: N/A Evaporation Rate: N/A N/A Evaporation Rate: N/A Solubility in Water: NOT SOLUBLE Odor and Appearance: WHITE PASTE WITH PLEASANT ODOR SECTION IV Flash Point: N/A Flammable Limits: N/A Extinguishing Media: - FIRE AND EXPLOSION HAZARD DATA LEL: N/A UEL: N/A DRY CHEMICAL, FOAM, CARBON DIOXIDE Special Fire Fighting Procedures: USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS. Unusual Fire and Explosion Hazards: TOXIC FUMES GIVEN OFF ABOVE 800 DEG F. SECTION V - REACTIVITY DATA This product is STABLE. Conditions to avoid: DIRECT CONTACT WITH OPEN FLAME. Incompatibility: SODIUM POTASSIUM ALLOY Hazardous Decomposition: FLUOROCARBON GASES PRESENT IN TEFLON DECOMPOSITION Hazardous Polymerization WILL NOT OCCUR. Routes of Entry: SECTION VI - HEALTH HAZARD DATA Inhalation? NO Skin? YES - PRIMARY Ingestion? YES - SECONDARY Health Hazards (Acute and Chronic): Carcinogenicity: NONE NTP? IARC Monographs? OSHA Regulated? Signs and Symptoms of Exposure: NONE NO NO NO Medical Conditions Generally Aggravated by Exposure: NONE KNOWN Emergency and First Aid Procedures: SKIN: WASH WITH SOAP & WATER THOROUGHLY. EYES: FLUSH 15 MINUTES WITH WATER. INGESTION: DO NOT INDUCE VOMITING. CALL PHYSICIAN. SECTION VII - HANDLING PRECAUTIONS Steps to be Taken if Material is Released or Spilled: USE ABSORBENT MATERIAL & SWEEP UP. Waste Disposal Method: NON-HAZARDOUS LANDFILL. REGULATIONS. COMPLY WITH FEDERAL, STATE AND LOCAL Precautions to be Taken in Handling and Storage: Other Precautions: NONE KEEP AWAY FROM DIRECT CONTACT WITH SPARKS & OPEN FLAME. SECTION VII - CONTROL MEASURES Respiratory Protection: NONE REQUIRED FOR NORMAL USE. Ventilation Required: NORMAL VENTILATION Protective Gloves: WEAR RUBBER GLOVES Eye Protection: WEAR SAFETY GOGGLES Other Protective Equipment: NONE REQUIRED FOR NORMAL USE. Work/Hygienic Practices: WASH THOROUGHLY WITH SOAP & WATER AFTER USING. The above information pertains to the product as it is currently formulated and is based upon the information available at this time. Additions of reducers or other additives to this product may substantially alter the composition and subsequent hazards of the product. Since conditions of use are outside of our control, we make no warranties, either expressed or implied, and assume no liability in connection with any use of this information. MSDS No: Issue Date: Page: OTH050E5 10 June 2005 1 of 4 MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION Trade Name: OATEY PLUMBER’S PUTTY Product Use: Stainless fixture setting compound. Formula: See SECTION 2 Synonyms: Putty. Firm Name & OATEY CO. 4700 West 160th Street P.O. Box 35906 Cleveland, Mailing Address: Ohio 44135, U.S.A. http://www.oatey.com Oatey Phone Number: (216) 267-7100 or (800) 321-9532 Emergency Phone For Emergency First Aid call 1-303-623-5716 COLLECT. For Numbers: chemical transportation emergencies ONLY, call Chemtrec at 1-800-424-9300. Outside the US: 1-703-527-3887. Prepared By: Corporate Director – Safety and Environmental Compliance Preparation Date: June 10, 2005 SECTION 2 INGREDIENTS: Limestone Hydrocarbon oil Talc Clay COMPOSITION/INFORMATION ON INGREDIENTS %wt/wt: CAS NUMBER: ACGIH TLV TWA: OSHA PEL TWA: 60 - 90% 1317-65-3 10 mg/M3 15 mg/M3 (Total dust) 10 - 30% 64742-52-5 5 mg/M3 5 mg/M3 2 mg/M3 2 mg/M3 1 - 5% 14807-96-6 10 mg/M3 10 mg/M3 1 – 5% 68953-58-2 OSHA Hazard Classification: OTHER: None None None None Not hazardous SECTION 3 HAZARDS IDENTIFICATION Emergency Overview: White putty with a mild petroleum odor. May cause mechanical irritation of the eyes. SECTION 4 FIRST AID MEASURES CALL 1-303-623-5716 COLLECT Skin: Wash all exposed areas with soap and water. Eyes: As with most foreign materials, should eye contact occur, flush eyes with water until foreign matter is removed. If irritation develops, seek medical attention. Inhalation: Not a likely route of entry. Ingestion: DO NOT INDUCE VOMITING. Rinse mouth with water. Call a physician. SECTION 5 FIRE FIGHTING MEASURES Flashpoint / Method: Not applicable Flammability: LEL = Not determined, UEL = Not determined Extinguishing Use dry chemical, CO2, or foam to extinguish fire. Cool fire Media: exposed container with water. Water may be ineffective as an extinguishing agent. Special Fire As appropriate for surrounding fire. Fighting Procedure: Unusual Fire and None Explosion Hazards: Hazardous Combustion will produce toxic and irritating vapors including Decomposition carbon monoxide and carbon dioxide. Products: MSDS No: Issue Date: Page: OTH050E5 10 June 2005 2 of 4 SECTION 6 Spill or Leak Procedures: ACCIDENTAL RELEASE MEASURES Sweep up dried material and dispose of with ordinary trash. SECTION 7 Handling: HANDLING AND STORAGE No special handling required. Use good hygiene practices. Store in a cool, dry area. None. Storage: Other: SECTION 8 Ventilation: Respiratory Protection: Skin Protection: Eye Protection: Other: Wash thoroughly after handling. EXPOSURE CONTROLS/PERSONAL PROTECTION Use with adequate ventilation. If putty dries and becomes dusty, wear a dust respirator during clean-up. Gloves are not normally required. Safety glasses with side shields are recommended. Eye wash should be available. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: Not applicable Melting Point: Not applicable Vapor Pressure: Not determined Vapor Density: Not determined Volatile Components: Not determined Solubility In Water: Negligible. pH: Not applicable Specific Gravity: 2.0 @ 20 Degrees C Evaporation Rate: Not applicable Appearance: White Putty Odor: Petroleum odor Will Dissolve In: Not determined Material Is: Putty SECTION 10 STABILITY AND REACTIVITY Stability: Stable. Conditions To Avoid: Avoid heat, flames and other sources of ignition. Hazardous Combustion will produce toxic and irritating vapors Decomposition including carbon monoxide and carbon dioxide. Products: Incompatibility/ Strong oxidizing agents. Materials To Avoid: Hazardous Will not occur. Polymerization: MSDS No: Issue Date: Page: SECTION 11 Inhalation: Skin: Eye: Ingestion: Chronic Toxicity: Toxicity Data: Sensitization: Carcinogenicity: Mutagenicity: Reproductive Toxicity: Medical Conditions Aggravated By Exposure: SECTION 12 VOC Information: OTH050E5 10 June 2005 3 of 4 TOXICOLOGICAL INFORMATION Not a likely route of entry. May cause mild irritation. Prolonged and repeated contact may cause dermatitis. Contact may cause irritation. Swallowing may cause a laxative effect including cramps and diarrhea. Prolonged or repeated overexposure cause dermatitis. Not available None of the components are None of the components are carcinogen by NTP, IARC or None of the components are None of the components are known to cause sensitization. listed as a carcinogen or suspect OSHA. known to be mutagenic. known to be toxic to reproduction. None known. ECOLOGICAL INFORMATION No ecotoxicological information known. This product has very low VOC level. SECTION 13 DISPOSAL CONSIDERATIONS Waste Disposal: Dispose in accordance with current local, state and federal regulations. RCRA Hazardous Waste Number: Not a hazardous waste. EPA Hazardous Waste ID Number: Not a hazardous waste. EPA Hazard Waste Class: Not a hazardous waste. SECTION 14 TRANSPORT INFORMATION Less than 1 Liter (0.3 gal) Greater than 1 Liter (0.3 gal) DOT Proper Shipping Name: Not regulated. Not regulated. Hazard Class/Packing Group: None None UN/NA Number: None None Hazard Labels: None None IMDG Proper Shipping Name: Not regulated Hazard Class/Packing Group: None UN Number: None Label: None 2004 North American Emergency Response Guidebook Number: None MSDS No: Issue Date: Page: OTH050E5 10 June 2005 4 of 4 SECTION 15 REGULATORY INFORMATION Hazard Category for Section Not hazardous. Section 302 Extremely This product does not contain chemicals regulated Hazardous Substances (TPQ): under SARA Section 302. Section 313 Toxic Chemicals: This product does not contain any chemicals regulated under SARA Title III Section 313. CERCLA 103 Reportable This product does not contain any chemicals regulated Quantity: under CERCLA. California Proposition 65: This product does not contain any chemicals subject To California Proposition 65 regulation. TSCA Inventory: All of the components of this product are listed on the TSCA inventory. Canadian WHIMS Classification: Not a controlled product. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. SECTION 16 OTHER INFORMATION NFPA and HMIS: NFPA Hazard Signal: Health: 0 Flammability: 0 HMIS Hazard Signal: Health: 0 Flammability: 0 Reactivity: 0 Reactivity: 0 Special: None PPE: A Disclaimer: The information herein has been compiled from sources believed to be reliable, upto-date, and is accurate to the best of our knowledge. However, Oatey cannot give any guarantees regarding information from other sources, and expressly does not make warranties, nor assumes any liability for its use. MATERIAL SAFETY DATA SHEET POWER O PRODUCTS 1 - IDENTIFICATION Manufacturer: Address: City, State, Zip: Telephone: 24-Hour Emergency: Date Prepared: 6 - HEALTH HAZARD DATA Ormco Corporation 1717 West Collins Avenue Orange, CA 92867 1-800-854-1741 Chemtrec 1-800-424-9300 September 24, 2001 Routes of Entry: Skin: None known Eyes: May cause mechanical irritation and damage. Inhalation: N/A Ingestion: N/A Carcinogenicity NTP: No IARC Monographs: No OSHA Regulated Carcinogen: No 2 - COMPOSITION INFORMATION 7 - EMERGENCY FIRST AID PROCEDURES Hazardous Ingredients This product contains no hazardous components as defined in the OSHA Hazard Communication Standard ( 29 CFR 1910.1200 ). Other Ingredients Polyurethane elastomer 3 - PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: N/D Specific Gravity (H20 = 1): N/D Vapor Pressure (mm Hg): N/D Vapor Density (AIR = 1): N/D Freezing/Melting Point: N/D Solubility in Water: N/D Appearance and Odor: Clear or colored elastomer material with no odor Skin: N/A Eyes: N/A Inhalation: N/A Ingestion: N/A 8 - PRECAUTIONS FOR SAFE HANDLING & USE Steps to be taken in case material is released or spilled: N/A Waste Disposal Method: Dispose of properly in accordance with all federal, state and local regulations. Precautions to be taken in handling and storing: Store in a cool and dry place away from heat and light. 9 - CONTROL MEASURES Flash Point (Method Used): N/D Flammable Limits: LEL: N/D UEL: N/D Extinguishing Media: Chemical foam, CO2 or dry chemical Special Fire Fighting Procedures: Wear a self-contained breathing apparatus. Unusual Fire and Explosion Hazards: N/A Respiratory Protection: N/A VENTILATION: Local Exhaust: N/A Mechanical (General): N/A Protective Gloves: Not required Eye Protection: Safety glasses recommended. Work/Hygiene Practices: Handle in accordance with good personal hygiene and safety practices. These practices include avoiding unnecessary exposure to uncured material. Avoid contamination of food. 5 - REACTIVITY DATA 10 - TRANSPORTATION INFORMATION Stability: Stable if stored as directed. Conditions to Avoid: Heat, light, aging and contamination Incompatibility (Material to Avoid): N/A Hazardous Decomposition Byproducts: Oxides of carbon Hazardous Polymerization: Will not occur Not DOT regulated. 4 - FIRE AND EXPLOSION HAZARD DATA 11 - SPECIAL INFORMATION HMIS (Hazardous Material Identification System) Rating: H0 F0 R0-Safety glasses [HMIS Hazard Index: 4 – Severe Hazard; 3 – Serious Hazard; 2 – Moderate Hazard; 1 – Slight Hazard; 0 – Minimum Hazard] Note: This MSDS was prepared in accordance with the requirements of the OSHA Hazard Communication Standard (29 CFR 1910.1200) and is to be used only for this product. The information contained in this MSDS is, to the best of our knowledge, believed to be accurate. NFPA Hazard Rating Flammability 0 0 Health MATERIAL SAFETY DATA SHEET L-82E 0 Reactivity 0 = Minimum 1 = Light 2 = Moderate 3 = Serious 4 = Extreme Section 1 - Product Identification Bio-Chem Surface Technology Trade name: Gold Matrix All Purpose 5977 Transcanada Highway Pointe-Claire, Quebec H9R 1C1 Emergency: CANUTEC (613) 996-6666 Product name: Order no.: WHMIS Classification: Controlled under WHMIS: Industrial cleaner/degreaser 53-G 603, 53-G 607, 53-G608 Non-hazardous No Section 2 - Hazardous Ingredients Ingredients CAS Number % by Weight LD50RAT LC50RAT No hazardous substances to declare. Section 3 - Physical / Chemical Characteristics Physical state: pH: Specific gravity: Evaporation rate: Liquid 12 1.00 g/ml @ 20ºC N/Av Odour & appearance:Lavender, blue Boiling point: 98ºC Vapour pressure: N/Av VOC g/l: N/Av Odour threshold: None Freezing point: 0ºC Vapour density: N/Av Water solubility: Soluble Section 4 - Fire & Explosion Hazard Flammability: No Flashpoint: N/A Conditions: None Auto ignition temperature: N/A Flammable limits (%): Upper: N/A Lower: N/A Extinguishing media: None Hazardous combustion products: None Sensitivity to mechanical impact or static discharge: No Section 5 - Reactivity Data Chemical stability: Yes Conditions: None Incompatible substances: Do not mix with other chemicals. Hazardous decomposition products: None N/A - Not Applicable Reactivity conditions: None N/Av - Not Available Page 1 of 2 MATERIAL SAFETY DATA SHEET L-82E Section 6 - Toxicological Data Route of entry: Eye and skin contact, ingestion. Acute exposure effects: None Chronic exposure effects: None Exposure limits (TLV/TWA): N/Av Carcinogenicity Mutagenicity Reproductive toxicity No No No If yes to any of the above, specify: Teratogenicity No Synergistic effects No Section 7 - Preventive Measures Protective equipment: Handling procedures: Waste disposal methods: Leak/spill procedures: Storage requirements: Engineering controls: Handling equipment: Special shipping information: Gloves in case of prolonged contact. Keep container tightly closed. Dispose as per municipal, provincial and federal regulations. Soak up with absorbent material. Rinse small amount with quantity of water. Neutralize. Store below 50ºC and above 0ºC. Keep upright. None None Section 8 - First Aid Measures Skin contact: Eye contact: Inhalation: Ingestion: Other: Wash off with water and soap. Apply cream. Rinse eyes thoroughly with water. Consult a physician. N/A Do not induce vomitting. Rinse mouth with water and give plenty of water to drink. Consult a physician. Section 9 - Preparation of MSDS Prepared by: Telephone: Date: Division Manager WCB (514) 733-3315 June 21th, 2007 This data is offered in good faith as typical values and not as a product specification. No warranty, either express or implied is hereby made. The recommended industrial hygiene and safe handling procedures are believed to bee generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate. N/A - Not Applicable N/Av - Not Available Page 2 of 2 Material Safety Data Sheet Section 1. Product and Company Identification Product Name PROFESSIONAL LYSOL® BRAND DISINFECTANT FOAM CLEANER (AEROSOL) Product Description Aerosol disinfectant cleaner for multiple surfaces. Manufacturer Reckitt Benckiser North America, Inc. Morris Corporate Center IV 399 Interpace Parkway (P.O. Box 225) Parsippany, N.J. 07054-0225 Product Identifier EPA Reg. No. 777-71-675 Item Number 36241-02775-09 MSDS# Not available. Validation Date 9/1/2005 Print Date 9/1/2005 In case of Emergency: Telephone: 800-677-9218 (Professional Products) Transportation Emergencies: Chemtrec: 1-800-424-9300 (U.S. & Canada) Outside the U.S & Canada (North America), call: 703-527-3887 Formula Number (794-103) F/F 376360 UPC Number 36241-02775 (24 oz.) Section 2. Composition and Information on Ingredients Name CAS # 1) DIETHYLENE GLYCOL MONOBUTYL ETHER 2) ISOBUTANE % by Weight Exposure Limits : TLV/PEL 112-34-5 5.6 Not available. 75-28-5 7.0 Not available. Section 3. Hazards Identification Emergency Overview CAUTION: May cause eye irritation. Avoid contact with eyes and skin. Contents under pressure. Do not use or store near heat or open flame. Do not puncture or incinerate container. Exposure to temperature above 55º C (130ºF) or in sun or discarding can in fire or incinerator may cause bursting. KEEP OUT OF REACH OF CHILDREN. Section 4. First Aid Measures Eye Contact In case of eye contact, hold eyes open and IMMEDIATELY rinse eyes thoroughly with plenty of water. Remove any contact lenses and continue rinsing for at least 15 minutes. If irritation persists, consult a physician. Skin Contact In case of skin contact, wash skin thoroughly with soap and water. If irritation persists, consult a physician. Inhalation Remove to fresh air. Ingestion Rinse mouth with water. Contact a physician or poison control center if symptoms develop. NEVER give an unconscious person anything to ingest. Continued on Next Page PROFESSIONAL LYSOL® BRAND DISINFECTANT FOAM CLEANER (AEROSOL) Page Number: 2 Section 5. Fire and Explosion Data Flammability See Section 14 for any Shipping Classifications. Flash Point Not applicable. Flame extension less than 18 inches or 45 cm. Explosive Limits in Air Not available. Products of Combustion Not available. Fire and Explosion Hazards CONTENTS UNDER PRESSURE. Do not use or store near hear or open flame. Do not puncture or incinerate. Do not expose to heat or store at temperatures above 55º C (130º F) as container may burst. Fire Fighting Media and Instructions Use water spray, foam, dry chemical or carbon dioxide, as suitable for surrounding fire. Special Fire Fighting Instructions Wear self-contained breathing apparatus and protective clothing appropriate for fighting a typical chemical fire. Move containers away from fire if possible and safe to do so. Use water spray to cool fire exposed containers. Provide shielding for venting, rupturing or bursting containers. Section 6. Accidental Release Measures Accidental Spill Small spills of liquid can be wiped up with a wet paper towel and residue may be flushed to sink or sanitary sewer with water. Large spills of liquid from ruptured cans: Eliminate all sources of ignition and ventilate the area with equipment rated for use in flammable environments. Spilled liquid should be diked, contained, collected and stored in metal containers for later disposal according to local, state or federal regulations. Section 7. Handling and Storage Handling and Storage CAUTION: May cause eye irritation. Avoid contact with eyes or skin. Contents under pressure. Do not store near heat or open flame. Store container in a cool, dry area inaccessible to small children. Do not reuse empty container. Replace cap and discard in trash. Do not incinerate or puncture. KEEP OUT OF REACH OF CHILDREN. It is a violation of federal law to use this product in a manner inconsistent with its labeling. Section 8. Exposure Controls/Personal Protection Ventilation Requirements None required. Eye Protection None required when used as recommended. Appropriate eye protection should be worn if the possibility of eye contact exists. Emergency responders should wear eye protection. Skin Protection For sensitive skin or prolonged use, wear rubber gloves. Emergency responders should wear impermeable gloves. Respiratory Protection None required. Other Protection None required. Emergency responders should wear impermeable clothing and footwear when responding to a situation where contact with the liquid is possible. Work/Hygienic Practices Washing with soap and water after use is recommended as good hygienic practice to prevent possible skin irritation and / or eye irritation from the residue that may be left on the hands. Continued on Next Page Page Number: 3 PROFESSIONAL LYSOL® BRAND DISINFECTANT FOAM CLEANER (AEROSOL) Section 9. Physical and Chemical Properties Description Aerosol container. White foam when sprayed. Odor Not available. pH 12.35 [Basic.] Color White foam when sprayed as an aerosol. Boiling/Condensation Point Not available. Specific Gravity 1.007-1.036 Vapor Pressure 34-40 PSIG @ 70°F. Vapor Density >1 (concentrate) Viscosity Not available. Solubility Miscible Physical Chemical Comments Not available. Section 10. Stability and Reactivity Data Chemical Stability The product is stable. Conditions of Instability Temperatures above 130° F (55° C) which may cause aerosol container to rupture. Incompatibility with Various Substances Oxidizing agents and acids. Hazardous Decomposition Products Oxides of nitrogen and/or carbon and other unidentified organic compounds may be formed during thermal decomposition. Hazardous Polymerization Will not occur. Section 11. Toxicological Information Exposure effects Eye Contact May cause eye irritation. Avoid contact with eyes. Skin Contact May cause skin irritation. Avoid skin contact. Inhalation None expected. Ingestion None expected. Carcinogenicity Not listed as carcinogenic by OSHA, NTP or IARC. Section 12. Ecological Information Ecotoxicity Not available. Continued on Next Page Page Number: 4 PROFESSIONAL LYSOL® BRAND DISINFECTANT FOAM CLEANER (AEROSOL) Section 13. Disposal Considerations Waste Disposal Dispose of in accordance with local, state and federal regulations. Container Disposal: Do not reuse empty container. Replace cap and discard in trash. Section 14. Transport Information DOT Classification ORM-D Proper Shipping Name Consumer Commodity DOT Identification Number Not applicable Packing Group Not applicable Maritime Transportation Not applicable. Hazardous Substances Reportable Quantity Not applicable. Special Provisions for Transport ORM-D: For US Domestic Shipments Only TDG Classification Consumer Commodity - Transborder Consignment ADR Classification Not applicable. IMDG Classification UN1950 - Aerosols, class 2.2 - Limited Quantity IATA Classification Consumer Commodity, 9 ID8000 Section 15. Regulatory Information Federal and State Regulations SARA Title III, Section 313 Toxic Chemical Notification & Release Reporting: 1) DIETHYLENE GLYCOL MONOBUTYL ETHER CAS #: 112-34-5 5.6 % California Proposition 65: This product contains the following ingredients which require a warning under the Safe Drinking Water & Toxic Enforcement Act: None Other Classifications New Jersey Right-To-Know Regulation: WHMIS (Canada) Not a WHMIS controlled product. NEW JERSEY WORKER AND COMMUNITY RIGHT TO KNOW ACT: This EPA Registered Product is exempt from the labeling requirements of the above act. N.J.A.C. 8:59-5.5 #1. Section 16. Other Information HMIS (U.S.A.) Health Hazard Fire Hazard Reactivity Personal Protection 1 2 0 B Continued on Next Page 1 Health 1 0 Reactivity Specific hazard NFPA Aerosol Level Validated by Product Safety on 9/1/2005. Fire Hazard National Fire Protection Association (U.S.A.) Printed 9/1/2005. 1, per NFPA 30B PROFESSIONAL LYSOL® BRAND DISINFECTANT FOAM CLEANER (AEROSOL) Page Number: 5 Notice to Reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. MATERIAL SAFETY DATA SHEET Product Name: PINE CLEANER & DEODORANT Product No. 094.00 SAVIN PRODUCTS COMPANY, INC. 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: PINE CLEANER & DEODORANT Emergency phone: Chemtrec: 800-424-9300 Company: Product Information: 781-961-2744 SAVIN PRODUCTS COMPANY, INC. 214 HIGH STREET RANDOLPH, MA 02368 Date Prepared: 04-23-04 Supersedes: 01-15-02 Prepared by: KJS 2. COMPOSITION/INFORMATION ON INGREDIENTS Component 1. Nonylphenol Ethoxylate CAS No. 9016-45-9 Exposure Limits N/A Typical % by Weight 1-5 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW CAUTION: May causes eye irritation. May cause skin irritation with prolonged contact. Harmful if swallowed. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Do not take internally. EFFECTS of OVEREXPOSURE CARCINOGENICITY: NTP: No IARC: No OSHA: No EYES: May cause severe eye irritation. SKIN: Repeated or prolonged contact may cause skin irritation. INHALATION: Mist may cause irritation to mucous membranes and respiratory tract. INGESTION: May result in gastric disturbances. CHRONIC EFFECTS and MEDICAL CONDITIONS: The effects of long-term, low-level exposures to this product have not been determined. Safe handling of this material on a long-term basis should emphasize the avoidance of all effects from repetitive acute exposure. This product may aggravate existing eye, skin and respiratory conditions. 4. FIRST AID MEASURES EYES: Flush with copious amounts of water for at least 15 minutes, lifting upper and lower lids occasionally. Get immediate medical attention. SKIN: Immediately flush with water. Remove contaminated clothing. Launder contaminated clothing before reuse. INHALATION: Remove to fresh air. If breathing is difficult, oxygen may be given, preferably with a physician’s advice. Get medical attention. INGESTION: If swallowed, give several glasses of water. Do not induce vomiting. If vomiting does occur, give fluids again and keep head below hips to help prevent aspiration. Do not give anything by mouth to an unconscious person. Get immediate medical attention. 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES: Flash Point: >200 F Test: Tag Closed Cup (Method D-56) Explosive Limits: LEL: N/A UEL: N/A EXTINGUISHING MEDIA: Use water spray, dry chemical, CO2, or alcohol foam. SPECIAL PROCEDURES AND UNUSUAL HAZARDS: Combustion may produce noxious and irritating gases which will require fresh air source in fire fighting. FIREFIGHTING INSTRUCTIONS: Firefighters should wear NIOSH approved, positive pressure, self-contained breathing apparatus and full protective clothing when appropriate. Page 1 of 3 MATERIAL SAFETY DATA SHEET Product Name: PINE CLEANER & DEODORANT Product No. 094.00 6. ACCIDENTAL RELEASE MEASURES SMALL SPILLS: Soak up small spills with inert solids. Use suitable disposal container. LARGE SPILLS: Limit access to area. Dike and contain spill with inert material (sand, earth, etc.) and transfer the liquid and solid separately to containers for recovery or disposal. Keep spill out of sewers and open bodies of water. CAUTION: Floor may become slippery. 7. HANDLING AND STORAGE Handle according to good manufacturing and warehousing practices. Keep containers tightly closed when not in use. Use good personal hygiene practices. Wash hand before eating, drinking, smoking or using toilet facilities. Promptly remove soiled clothing and wash thoroughly before reuse. Store in tightly closed containers away from heat, sparks, open flame or strong oxidizing agents. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION EYE PROTECTION: Avoid splashing. Wear chemical-resistant safety goggles if necessary. Contact lenses must not be worn. PROTECTIVE GLOVES: Depending on conditions of use, protective gloves, apron, boots, head and face protection should be worn. This equipment should be cleaned thoroughly after each use. RESPIRATORY PROTECTION: No occupational exposure standards have been developed for this material. Where exposure through inhalation may occur from use, NIOSH/MSHA approved respiratory protection equipment is recommended. VENTILATION: Either local exhaust or general room ventilation is usually adequate. OTHER PROTECTIVE EQUIPMENT: Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. 9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear, green, thin, foamy liquid. BOILING POINT: approx. >212F >100C @ 1ATM FREEZE/MELT POINT: approx. 0C VAPOR PRESSURE (mm): ca water VAPOR DENSITY (air=1): ca water EVAPORATION RATE: approx. water VOLATILE CONTENT: 97% SOLUBILITY IN WATER: Complete. SPECIFIC GRAVITY: 1.01 @ 20C DENSITY: 8.4 lb./gal. @ 20C pH(as is): 7.0 ODOR: Pine ODOR THRESHOLD (ppm): Not determined. 10. STABILITY AND REACTIVITY CHEMICAL STABILITY (CONDITIONS TO AVOID): Stable. INCOMPATIBILITY: Strong acids, strong oxidizers and excessive heat. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, Carbon Dioxide, Ammonia, Nitrous oxides and other toxic gases. HAZARDOUS POLYMERIZATION: None 11. TOXICOLOGICAL INFORMATION No LD50 or LC50 found for oral, dermal or inhalation routes of administration. 12. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL/CHEMICAL FATE INFORMATION: Not available. 13. DISPOSAL CONSIDERATIONS RCRA: This product, if disposed as shipped, is not considered a hazardous waste as specified in 40 CFR 261. Dispose in accordance with all applicable federal, state and local regulations. Page 2 of 3 MATERIAL SAFETY DATA SHEET Product Name: PINE CLEANER & DEODORANT Product No. 094.00 14. TRANSPORT INFORMATION SHIPPING NAME: HAZARD CLASS: ID #: PACKING GROUP: LABEL: Compound, Cleaning, Liquid Not regulated as HAZMAT. N/A N/A N/A 15. REGULATORY INFORMATION This material does not contain nor was it manufactured using ozone-depleting chemicals. U.S. FEDERAL REGULATIONS: TSCA STATUS: All ingredients on Toxic Substance Control Act Inventory. CERCLA REPORTABLE QUANTITY: N/A SARA TITLE III: Section 302 Extremely Hazardous Substances: Section 311/312 Hazardous Categories: Section 313 Toxic Chemicals: None. Immediate (Acute) None. RCRA STATUS: Based on chemical composition and pH (40 CFR Sec. 261.22), this material is not classified as a hazardous waste if disposed as shipped. 16. OTHER INFORMATION All label precautions must be observed when handling, storing and transporting empty containers due to product residues. Do not reuse this container unless it is professionally cleaned and reconditioned. REFERENCES: • U.S. Dept. of Health and Human Services, NIOSH: Registry of Toxic Effects of Chemical Substances, 1985-86 Editions. • Sax, N. Irving and Lewis, R.J.: Dangerous Properties of Industrial Materials, 7th Edition, Van Nostrand Reinhold Co., 1989. • Lewis, R.J.: Hawley’s Condensed Chemical Dictionary,12th Edition, Van Nostrand Reinhold Co., 1993. • U.S. Dept. of Transportation, U.S. Coast Guard: CHRIS Hazardous Chemical Data, 1982. • U.S. Dept. of Labor, OSHA: Air Contaminants - Permissible Exposure Limits, 1989. • National Fire Protection Association (NFPA): Fire Protection Guide on Hazardous Materials (NFPA 325M/49/491M/704), 9th Edition, 1986. • National Fire Protection Association (NFPA): Hazardous Materials Response Handbook, Henry, M.F., Editor, 1989. • Merck & Co., Inc.: The Merck Index, 11th Edition, 1989. Information herein is given in good faith as authoritative and valid; no warranty, express or implied can be made. 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PRODUCT IDENTIFICATION AND USE Product Identification Product Name: Glass and Window Cleaner - Windex(r) type Product Number: GPG202 Synonyms: Window and Glass Cleaner CAS Number: Blend Company Identification NuGeneration Technologies, LLC 100 Professional Center Drive suite 101 Rohnert Park, CA 94928 USA www.nugentec.com (707) 820-4080 (For product information) 1-800-424-9300 or 1-202-483-7616 (For emergencies CHEMTREC) SPECIAL NOTES: 2. Non-streaking Fast drying window cleaner. HAZARDOUS INGREDIENTS Chemical Name ------------SEC-PROPYL ALCOHOL BALANCE NON-HAZARDOUS INGREDIENTS Amount -------< 10.0 % > 90.0 % CAS Number ---------67-63-0 N/A COMPOSITION COMMENT: This Product Meets FDA/USDA requirements for cleaning in the food processing industry. This product is formulated with NON-Hazardous ingredients only. EXPOSURE GUIDELINES: Canadian Disclosure List 3. No Information Available. SEC-PROPYL ALCOHOL (67-63-0) PHYSICAL DATA FORM ...............................: COLOR ..............................: ODOR ...............................: BOILING POINT ......................: SOLUBILITY IN WATER ................: SPECIFIC GRAVITY ...................: BULK DENSITY .......................: MELTING/FREEZING POINT .............: PH .................................: % VOLATILES ........................: VOLATILE ORGANIC COMPOUNDS (VOC) ...: Liquid Colorless Faint ether-like odor >212 F Complete 0.996 (Water = 1) 8.31 32 F 10.5 6 % <60 g/l NuGenTec Glass Cleaner - Windex(r) type PRD Number: GPG202 Page 2 of 5 May 29, 2007 INHALATION: No hazards expected in normal industrial use at room temperature. INGESTION: Ingestion is not considered a potential route of exposure. CARCINOGENICITY INFORMATION: No known cancer hazards. MISCELLANEOUS: Slippery, can cause falls if walked on. 4. FIRE AND EXPLOSION DATA FLAMMABLE PROPERTIES COC Flash Point: N/A Autoignition Temperature: FLAMMABLE LIMITS IN AIR EXTINGUISHING MEDIA: N/A LEL: N/A UEL: N/A Carbon dioxide, foam, or dry powder. FIRE & EXPLOSION HAZARDS: High concentrations of vapors may burn in a fire. FIRE FIGHTING INSTRUCTIONS: Contaminated extinguishing water must be disposed of in accordance with applicable regulations. 5. REACTIVITY DATA STABILITY: Stable. POLYMERIZATION: Hazardous polymerization will not occur. INCOMPATIBILITY WITH OTHER MATERIALS: None known. DECOMPOSITION: Decomposition will not occur if handled and stored properly. CONDITIONS TO AVOID: This material is safe under normal storage and handling conditions. NuGenTec Glass Cleaner - Windex(r) type PRD Number: GPG202 6. Page 3 of 5 May 29, 2007 TOXICOLOGICAL PROPERTIES EYE: Contact may cause eye irritation. eye tissue. Not known to cause permanent injury to SKIN: Prolonged or repeated contact may cause skin irritation. INHALATION: No hazards expected in normal industrial use at room temperature. INGESTION: Ingestion is not considered a potential route of exposure. CARCINOGENICITY INFORMATION: No known cancer hazards. MISCELLANEOUS: Slippery, can cause falls if walked on. EYE EFFECTS: Contact may cause eye irritation. SKIN EFFECTS: Contact may cause slight skin irritation. ACUTE ORAL EFFECTS: No know hazards in normal industrial use. ACUTE INHALATION EFFECTS: No know hazards in normal industrial use. 7. PREVENTITIVE MEASURES RECOMMENDED STORAGE TEMPERATURE Minimum: 4.4 C (39.9 F) Maximum: 48.9 C (120.0 F) HANDLING (PERSONNEL): Avoid contact with eyes, skin, and clothing. HANDLING (PHYSICAL ASPECTS): Keep container closed to avoid contamination. STORAGE PRECAUTIONS: Keep container closed when not in use. pallets high. Do not stack drums more than three NuGenTec Glass Cleaner - Windex(r) type PRD Number: GPG202 Page 4 of 5 May 29, 2007 ENGINEERING CONTROLS: Good general ventilation should be sufficient to control airborne levels. EYE / FACE PROTECTION REQUIREMENTS: When splashing of the material may occur, chemical goggles and a face shield are recommended. SKIN PROTECTION REQUIREMENTS: For brief contact, normal work attire should be sufficient. thoroughly after handling. Wash hands RESPIRATORY PROTECTION REQUIREMENTS: Under normal use conditions, with adequate ventilation, no special handling equipment is required. SAFEGUARDS (PERSONNEL): Protect skin and eyes from exposure. INITIAL CONTAINMENT: Floor may become slippery. Wash area to prevent slipping. Contain spilled material. Treat or dispose of waste material in accordance with all local, state/provincial, and national requirements. LARGE SPILLS PROCEDURE: Flush spill area with water to wastewater treatment system. Treat or dispose of waste material in accordance with all local, state/provincial, and national requirements. SMALL SPILLS PROCEDURE: Floor may become slippery. Wash with water. Treat or dispose of waste material in accordance with all local, state/provincial, and national requirements. WASTE DISPOSAL: Uncleaned empty containers should be disposed of in the same manner as the contents. Treat or dispose of waste material in accordance with all local, state/provincial, and national requirements. CONTAINER DISPOSAL: 8. Clean out containers prior to disposal. FIRST AID MEASURES EYE CONTACT FIRST AID: Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation develops or persists. SKIN CONTACT FIRST AID: Flush skin with plenty of water. develops or persists. Get medical attention if irritation NuGenTec Glass Cleaner - Windex(r) type PRD Number: GPG202 Page 5 of 5 May 29, 2007 INHALATION FIRST AID: Not an expected route of exposure. Remove from area of exposure. Seek immediate medical attention if respiratory irritation or distress continues. INGESTION FIRST AID: Ingestion is not considered a potential route of exposure. get medical attention immediately. If ingested NOTES TO PHYSICIAN: Treat patient symptomatically. 9. PREPARATION DATE OF MSDS Prepared By.......: Approval Date.....: Supersedes Date...: PRD Number........: Donato Polignone May 29, 2007 August 30, 2001 GPG202 (Official Copy) ********************************************************************** This information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of NuGeneration Technologies, LLC. The data on this sheet are related only to the specific material designated herein. NuGeneration Technologies, LLC assumes no legal responsibility for use or reliance upon these data. ********************************************************************** END OF MSDS ********************************************************************** PRODUCT DATA SHEET Tile & Grout Cleaner Ready to Use Cleaner For ■ Sanded Grout ■ Non-sanded Grout ■ Ceramic Tile ■ Quarry Tile ■ Glazed Ceramic ■ Honed Marble ■ Honed Limestone ■ Honed Travertine Special Features ■ Non Acid ■ Removes Mildew ■ Environmentally Safe ■ Mortar ■ Porcelain Tile ■ Tumbled Marble ■ Granite ■ Non Bleach ■ Pleasant Odor ■ Fast Acting ■ User Friendly PRODUCT DE SCRIPTION KEEP OUT OF REACH OF CHILDREN. Tile & Grout Cleaner is a non abrasive, non acidic cleaner designed for use on all grout and ceramic tiles. Strong enough to remove difficult stains, soap scum, dirt, water deposits, mildew and mold, yet is gentle enough for regular use. Tile & Grout Cleaner is easy to use and will not harm sanded and non sanded grout as many household products can. Environmentally friendly Tile & Grout Cleaner will not harm tile, chrome, glass, Formica or Corian (NOT FOR USE ON POLISHED MARBLE, LIMESTONE OR TRAVERTINE) Sample Testing Due to the differences of each substrate, several inconspicuous test patches should be completed to assure maximum performance. User must determine suitability of the product for their intended use. Protect Neighboring Surfaces Always protect neighboring surfaces including wood, carpet, metal, landscaping and other non masonry surfaces. APPLIC ATION INSTRUCTIONS Read entire label and PDS/MSDS before using. Spray Tile & Grout Cleaner onto soiled surface and allow to dwell for several minutes. Wipe clean with a clean scrub pad, brush, sponge or cloth. Do not allow Tile & Grout Cleaner to dry on the surface. Rinse if necessary. Heavy soiled surfaces and more porous surfaces may require scrubbing. Use the appropriate brush for the surface being cleaned. Grout can be cleaned with a small nylon brush. To remove heavy build up of mold or mildew use H2O Strip as directed first. Not for use on polished, marble, travertine or limestone. Heavy Duty Cleaning: Use Phosphoric Acid Cleaner , GCFR or Liquid Poultice as directed. Light Cleaning: Use Mira Clean #1, Porcelain & Ceramic Tile Cleaner, Mira Soap, Grout Cleaner, or Counter Kleen as directed. Water, Stain & Slip Protection To protect cleaned area from future soiling and staining and increase static coefficient of friction, we recommend applying the appropriate Miracle Penetrating Sealer/Impregnator. 6.11.2007 Color and Gloss Enhancement For added color with “Textured and Non polished” surfaces, 511 Seal & Enhance may be used. For porous type “Paver”, Stone Polish, MiraPolish, Granite Brite, 511 Seal & Enhance, Mira Dust, Marble Conditioner or Tile Brite may be used as directed. www.miraclesealants.com Mold, Mildew and Bacteria Sanitation For best results in killing mold, mildew, bacteria and other micro organisms, use Miracle Disinfectant or Miracle Wipes as directed. Coverage Coverage will vary depending on density, porosity, texture. surface absorption, weather, time solution left on surface and application methods. Used as directed, Tile & Grout Cleaner will clean approximately 4,000 square feet per gallon (363 s.m. per 3.785 liters) and 250 square feet per 8 ounce bottle (22 s.m. per .16 liters). MAINTENANCE For ongoing maintenance instructions please refer to Miracle Sealants Care Guide. Refer to the Miracle Sealants Product Recommendation Chart for specific product recommendations. Storage Store Tile & Grout Cleaner in the original upright container, properly sealed and unmixed. Stored at 770 F (400 C), Tile & Grout Cleaner will have a shelf life of 12 months. Do not allow to freeze. Technical Support For additional technical support, contact Miracle Sealants Company at 1-800-350-1901 or 626-814-8988 ext. 3013 Office Hours Monday - Friday from 8:30 am - 5:00 pm PT. 1-626-443-6433 or 1-800-350-1901 • Fax: 1-626-443-1435 website: www.miraclesealants.com Product Damaged During Transportation If product is damaged during transportation contact Info Trac @ 1-800-535-5053 Additional Products Miracle Sealants Company offers a complete line of water & stain repellents, sealers, cleaner, polishing compounds, diamond abrasives, machinery and accessories for the tile, stone, concrete, metal, fabric and carpet professional or do-it yourself specialist. Caution Store in cool area. Only use this product in well ventilated areas. Good ventilation means that fresh air is flowing in such a way to feel a slight breeze. Continue to ventilate until odors are completely eliminated. Avoid contact with skin. Chemical resistant gloves should be worn at all times. Keep small children and pets out of area until product or surface has thoroughly dried. Refer to the MSDS for additional information. Warranty Instructions are a condensed guide and should not be considered complete. In the event of failure, the only obligation of Miracle Sealants Company shall be to replace such products proven to be defective. Before using, user shall determine the suitability of the product for their intended use. User assumes all risks and liability whatsoever in connection therein. Neither seller nor manufacturer shall be liable for any injury or inability to use this product. MATERIAL SAFETY DATA SHEET Tile & Grout Cleaner Osha’s Hazard Communication Standard U.S. Department Of Labor 29 CFR 1910.1200 OMB No. 1218-0072 Identity No: Name: Tile & Grout Cleaner Section 1 Manufacturers Name: Address: Emergency Phone: City: State: Phone: Date Prepared: Miracle Sealants Company 12318 Lower Azusa Road 800-350-1901 Arcadia CA 626-443-6433 June 2007 Section 2 - Hazardous Ingredient/Identity Information Hazardous Components CAS # OSHA PEL None None None VOC: 6% by weight before dilution or 68 g/L ACGIH TLV None Section 3 - Physical/Chemical Characteristics Specific gravity: 1.066 Boiling point: 2100 F Vapor pressure: Not tested Melting point: Not tested Vapor density: Not tested Evaporation rate: Not tested Solubility in water: 100% Appearance and odor: Colorless liquid, citrus odor Section 4 - Fire And Explosion Hazard Data Flash Point: Not Available Flammable limits: Not tested LEL: Not tested UEL: Not tested pH: 8.5-10.0 NFPA hazard rating (o = Least, 4 = Extreme) Health: 1 Fire: 0 Reactivity: 0 Other: 0 HMIS Hazard Rating: Health: 1 Reactivity: 0 Fire: 0 Extinguishing media: CO2, dry foam Special fire fighting procedures: None Unusual fire and explosion hazards: None www.miraclesealants.com Emergency and First Aid Procedures: Eyes: Flush with water for 15 minutes. If irritation persists, call physician. Skin: Wash off with soap and water. If irritation persists, call physician. Ingestion: Do not induce vomiting. Call physician or Poison Control Center immediately.. Inhalation: Get person to fresh air if unconscious. Call physician. Section 7 - Precautions For Safe Handling And Use Steps to be taken in case material is released or spilled: Soak up with inert, absorbent material. Scoop up and place in a proper waste disposal container. Waste disposal method: Dispose of in accordance with state and local regulations. Precautions to be taken in handling and storing: Store in a cool, dry place, out of direct sunlight. Do not freeze less than or equal to 320 F or heat above 1100 F. Other precautions: KEEP OUT OF REACH OF CHILDREN. Follow directions on the container for proper use of this product. Section 8 - Control Measures Respiratory protection: Ventilate by opening all doors and windows. Ventilation: Local exhaust - If available Mechanical - If available Protective gloves: Plastic or rubber, chemical resistant. Eye protection: Tight fitting splash proof safety glasses or goggles. Other protective clothing or equipment: None Work hygienic practices: Wash hands thoroughly before handling food stuffs, liquids or tobacco products. Use common sense and care around chemicals. Never mix this product with other chemicals. Consult your supervisor for all other hygienic and safety practices. All practices depend on your specific business. Directions for use normally found on label which will dictate engineering and control measures. Section 9 - Shipping & Regulatory Classification DOT Shipping Name: Please refer to the Bill of Lading receiving/documents for up-to-date information. DOT#: Not Available Section 5 - Reactivity Data Stability: Stable Conditions to avoid: None Incompatible materials to avoid: Strong oxidizer Hazardous decomposition byproducts: CO, CO2 Hazardous polymerization: Will not occur. Section 6 - Health Hazard Data Routes of Entry: Eyes - Possible Inhalation - Possible Skin - Possible Ingestion - Possible Health Hazards - Same as signs and symptoms of exposure. Special - None Other - None DOT Hazard Class: Not Available Toxic Substances Control Act (TSCA): This product and/or all the ingredients contained in this product have been registered under the Toxic Substances Control Act. SARA: No SARA 313 chemicals identified. NOTE: Miracle Sealants believes the data set forth are accurate. Miracle Sealants makes no warranty with respects thereto and disclaims all liability or reliance thereon. Such data are offered solely for consideration, investigation and verification. Also, the data set forth is for the concentrated finished product. All lab samples are for experimental purposes only and used at the customers discretion. Carcinogenicity: OSHA: None NTP: None IARC Monographs: None 6.11.2007 Signs and Symptoms of Over Exposure: Eyes: Burning sensation. Skin: Slight Irritation. Ingestion: Nausea. Inhalation: Slight Irritation. MATERIAL SAFETY DATA SHEET TEMP TILE, ENAMEL, METAL AND PORCELAIN CLEANER (SUMA) HMIS Health Fire Hazard Reactivity 2 0 0 NFPA 2 0 0 Personal protective equipment None / Aucune / Ninguno Version Number: 1 Preparation date: 2006-10-12 1. PRODUCT AND COMPANY IDENTIFICATION Product name: TEMP TILE, ENAMEL, METAL AND PORCELAIN CLEANER (SUMA) MSDS #: Product code: Recommended use: 203201436001 04410279 Cleaning product. Manufacturer, importer, supplier: US Headquarters JohnsonDiversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-0902 Phone: 1-888-352-2249 MSDS Internet Address: www.johnsondiversey.com Emergency telephone number: Canadian Headquarters JohnsonDiversey - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-800-668-3131 1-800-851-7145 (Prosar); 1-651-917-6133 (Int'l Prosar); 01-800-710-3400 (México) 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW CAUTION. CAUSES EYE IRRITATION. MAY BE MILDLY IRRITATING TO SKIN. Principle routes of exposure: Eye contact: Skin contact: Inhalation: Ingestion: Eye contact. Skin contact. Inhalation. Moderately irritating to the eyes. May be mildly irritating to skin. None known. May cause irritation to mouth, throat and stomach . 3. COMPOSITION/INFORMATION ON INGREDIENTS HAZARDOUS COMPONENTS Ingredient(s) Ethylene glycol Sodium carbonate Quartz CAS # Weight % LD50 Oral - Rat 107-21-1 497-19-8 14808-60-7 1 - 5% 1 - 5% 100 =4000 mg/kg =4090 mg/kg =500 mg/kg LD50 Dermal Rabbit =9530 µL/kg Not available Not available LC50 Inhalation - Rat 200 mg/m3 Not available Not available 4. FIRST AID MEASURES Eye contact: Skin contact: Inhalation: Ingestion: Aggravated Medical Conditions: Flush immediately with plenty of water. If irritation persists, get medical attention. Flush immediately with plenty of water. If irritation develops get medical attention. No specific first aid measures are required. If swallowed, give a cupful of water or milk. None known. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: Specific hazards: Unusual hazards: Specific methods: The product is not flammable. Extinguish fire using agent suitable for surrounding fire. Not applicable None known No special methods required Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons: No information available TEMP TILE, ENAMEL, METAL AND PORCELAIN CLEANER (SUMA) 1 of 4 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Environmental precautions and clean-up methods: Use personal protective equipment Clean-up methods - large spillage. Shovel into suitable container for disposal. Use a water rinse for final clean-up. 7. HANDLING AND STORAGE Handling: Avoid contact with skin, eyes and clothing. Wash thoroughly after handling. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Keep tightly closed in a dry, cool and well-ventilated place. KEEP OUT OF THE REACH OF CHILDREN. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: No special ventilation requirements. General room ventilation is adequate. Personal Protective Equipment Eye protection: Hand protection: Skin and body protection: Respiratory protection: Hygiene measures: No special requirements under normal use conditions. No special requirements under normal use conditions No special requirements under normal use conditions. No special requirements under normal use conditions. Handle in accordance with good industrial hygiene and safety practice Ingredient(s) Ethylene glycol Quartz CAS # 107-21-1 14808-60-7 ACGIH 100 mg/m3 (Ceiling) 0.05 mg/m3 (TWA) OSHA Mexico 100 mg/m3 (Peak) 0.1 mg/m3 (TWA) 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: pH: Appearance: Color: Odor: Specific gravity: Density: VOC: Flash point: Solubility: Viscosity: Solid 10.4 Paste Yellow - Green Lavender 1.5497 12.93 lbs/gal 0% * >200 (°F) >93.3 (°C) Soluble No information available Bulk density: No information available Dilution pH: No information available. Vapor density: No information available Evaporation Rate No information available Boiling point/range: Not determined Melting point/range: Not determined Decomposition temperature: Not determined Autoignition temperature: No information available Partition coefficient (n-octanol/water): No information available Solubility in other solvents: No information available Elemental Phosphorus: 0 %P * - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508 10. STABILITY AND REACTIVITY Stability: Polymerization: Hazardous decomposition products: The product is stable Hazardous polymerization does not occur None reasonably foreseeable. 11. TOXICOLOGICAL INFORMATION Acute toxicity Component Information: Oral LD50 estimated to be greater than 5000 mg/kg See Section 3 Chronic toxicity: This product contains Quartz (silica) which is listed as a carcinogen, however, the formulation is a heavy, viscous liquid and therefore, chronic effects from exposure to respirable-size particles of this product are minimal. Specific effects Carcinogenic effects: Mutagenic effects: Reproductive toxicity: Target organ effects: None known None known None known None known TEMP TILE, ENAMEL, METAL AND PORCELAIN CLEANER (SUMA) 2 of 4 11. TOXICOLOGICAL INFORMATION HAZARDOUS COMPONENTS Ingredient(s) Quartz CAS # 14808-60-7 NTP X IARC 1 OSHA X 12. ECOLOGICAL INFORMATION Environmental Information: No data available 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Dispose of according to all federal, state and local applicable regulations 14. TRANSPORT INFORMATION DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information 15. REGULATORY INFORMATION International Inventories All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL). U.S. Regulations California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 STATE RIGHT TO KNOW Ingredient(s) Ethylene glycol Water Sodium carbonate Coconut Oil Based Soap Tallow Quartz CERCLA/ SARA Ingredient(s) Ethylene glycol CAS # 107-21-1 7732-18-5 497-19-8 TS* 61789-97-7 14808-60-7 CAS # 107-21-1 Ingredient(s) Ethylene glycol SARA 311/312 Hazard Categories Immediate: Delayed: Fire: Reactivity: Sudden Release of Pressure: MARTK: X X Weight % 1 - 5% NJRTK: X X CERCLA/SARA RQ (lbs) 5000 CAA HAP X CAA ODS PARTK: X X X RIRTK: X X - Section 302 TPQ (lbs) Section 313 X CWA Priority Pollutants X - Canada WHMIS hazard class: D2B Toxic materials . Ingredient(s) Ethylene glycol CAS # 107-21-1 NPRI X 16. OTHER INFORMATION Reason for revision: Prepared by: Additional advice: Not applicable NAPRAC None TEMP TILE, ENAMEL, METAL AND PORCELAIN CLEANER (SUMA) 3 of 4 16. OTHER INFORMATION Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. TEMP TILE, ENAMEL, METAL AND PORCELAIN CLEANER (SUMA) 4 of 4 Eli Lilly and Company Material Safety Data Sheet MSDS Index Sodium Bicarbonate Effective Date: 05-Aug-2004 Section 1 - Chemical Product and Company Emergency Phone: 1-317-276-2000 CHEMTREC: 1-800-424-9300 (North America) 1-703-527-3887 (International) Manufacturer: Eli Lilly and Company Lilly Corporate Center Indianapolis, IN 46285 Common Name: Sodium Bicarbonate CAS Number(s): 144-55-8 EINECS Number: 2056-33-8 Chemical Name: Carbonic acid monosodium salt Chemical Family: Inorganic salt Chemical Formula: C H O3 . Na Molecular Weight: 84.01 Synonym(s): Sodium bicarbonate tablets; Soludal; Meylon; Soda; Monosodium carbonate; Sodium hydrogen carbonate; Sodium acid carbonate; Bicarbonate of soda; Baking soda; Soda mint; NaHCO3; Sodium bicarbonate - cell culture grade; Sodium bicarbonate tablet mix Lilly Serial Number(s): 237728 Lilly Item Code(s): QA049K; QA116D; QA192M; QA241X; QA281L; QA384W; QA476V; QD400T; QD472B; TA1260; TA1264; TA1265 See attached glossary for abbreviations. Section 2 - Composition / Information on Ingredients Ingredient Sodium Bicarbonate CAS 144-55-8 Exposure Guidelines: Sodium bicarbonate - Exposure Guideline 1500 micrograms/m3 TWA for 12 hours, 2300 micrograms/m3 TWA for 8 hours. (Lilly-established guideline) Dow Chemical Exposure Guideline 10 mg/m3 TWA. Section 3 - Hazards Identification Appearance: White crystalline powder or granules or compressed uncoated tablets Physical State: Solid Odor: Odorless Emergency Overview Emergency Overview Effective Date: 07-Aug-2002 Lilly Laboratory Labeling Codes: Health 1 Fire 0 Reactivity 0 Primary Physical and Health Hazards: No Significant Health Hazards. Caution Statement: No significant health hazards have been reported for Sodium Bicarbonate. Routes of Entry: Inhalation and skin contact. Effects of Overexposure: Material has low acute oral or inhalation toxicity. Material may be slightly irritating to the eyes, skin, and respiratory tract. Inhalation of dust may cause coughing. Medical Conditions Aggravated by Exposure: None known. Carcinogenicity: No carcinogenicity data found. Not listed by IARC, NTP, ACGIH, or OSHA. Section 4 - First Aid Measures Eyes: Flush eyes with plenty of water. Get medical attention. Skin: Remove contaminated clothing and clean before reuse. Wash all exposed areas of skin with plenty of soap and water. Get medical attention if irritation develops. Inhalation: Move individual to fresh air. Get medical attention if breathing difficulty occurs. If not breathing, provide artificial respiration assistance (mouth-to-mouth) and call a physician immediately. Ingestion: Call a physician or poison control center. No first aid procedures are normally required. Section 5 - Fire Fighting Measures Flash Point: Not applicable UEL: Not applicable LEL: Not applicable Extinguishing Media: Use water, carbon dioxide, dry chemical, foam, or Halon. Unusual Fire and Explosion Hazards: None known. Hazardous Combustion Products: May emit toxic fumes when exposed to heat or fire. Section 6 - Accidental Release Measures Spills: Wear protective equipment, including eye protection, to avoid exposure (see Section 8 for specific handling precautions). Vacuum material with appropriate dust collection filter in place. Be aware of potential for dust explosion when using electrical equipment. If vacuum is not available, lightly mist material and remove by sweeping or wet wiping. Section 7 - Handling and Storage Lilly Warehouse Storage Category: 140X Storage Conditions: Warehouse: 10 to 40 C (45 to 104 F). For certain items, other storage conditions may be required. Section 8 - Exposure Controls / Personal Protection See Section 2 for Exposure Guideline information. Respiratory Protection: Use an approved respirator. Eye Protection: Chemical goggles and/or face shield. Ventilation: Laboratory fume hood or local exhaust ventilation. Other Protective Equipment: Chemical-resistant gloves and body covering to minimize skin contact. If handled in a ventilated enclosure, as in a laboratory setting, respirator and goggles or face shield may not be required. Safety glasses are always required. Section 9 - Physical and Chemical Properties Boiling Point: Not applicable Melting Point: Not applicable Specific Gravity: 2.159 pH: 8.2 (1% solution) Evaporation Rate: Not applicable Water Solubility: 8.6 g/100 ml @ 20 C (68 F) Vapor Density: Not applicable Vapor Pressure: Not applicable Section 10 - Stability and Reactivity Stability: Stable at normal temperatures and pressures. Incompatibility: May react with strong oxidizing agents (e.g., peroxides, permanganates, nitric acid, etc.) and strong acids. Hazardous Decomposition: May emit toxic fumes when heated to decomposition. Hazardous Polymerization: Will not occur. Section 11 - Toxicological Information Acute Exposure Oral: Sodium bicarbonate - Rat, median lethal dose 4220 mg/kg. Skin: No applicable information found. Inhalation: Sodium bicarbonate - Rat, median lethal concentration greater than 4740 mg/m3 (duration unspecified). Skin Contact: No applicable information found. Eye Contact: Sodium bicarbonate - Rabbit, mild irritant Chronic Exposure Target Organ Effects: No applicable information found. Reproduction: Sodium bicarbonate - No teratogenic effects reported in rats or mice given large doses during pregnancy. Sensitization: No applicable information found. Mutagenicity: Sodium bicarbonate - Negative in Ames assay. Section 12 - Ecological Information Ecotoxicity Data: Sodium bicarbonate Daphnia magna 48-hour median lethal concentration: 11.7 mmol/L to 26.3 mmol/L Western mosquitofish 96-hour median lethal concentration: 5.6 g/L Bluegill 96-hour median lethal concentration: 8.25 g/L Rainbow trout median lethal concentration (duration unspecified): 7.7 g/L Environmental Fate: No applicable information found. Environmental Summary: Sodium bicarbonate - This material is practically non-toxic to aquatic organisms. Material is soluble in water and may leach from soil into groundwater. Section 13 - Disposal Considerations Waste Disposal: Dispose of any cleanup materials and waste residue according to all applicable laws and regulations. Section 14 - Transport Information Regulatory Organizations: DOT: Not Regulated ICAO/IATA: Not Regulated IMO: Not Regulated Section 15 - Regulatory Information Below is selected regulatory information chosen primarily for possible Eli Lilly and Company usage. This section is not a complete analysis or reference to all applicable regulatory information. Please consider all applicable laws and regulations for your country/state. U.S. Regulations Sodium bicarbonate TSCA - Yes CERCLA - Not on this list SARA 302 - Not on this list SARA 313 - Not on this list OSHA Substance Specific - No EU Regulations EC Classification Not assigned an overall EC classification. Section 16 - Other Information MSDS Sections Revised: Section 7. As of the date of issuance, we are providing available information relevant to the handling of this material in the workplace. All information contained herein is offered with the good faith belief that it is accurate. THIS MATERIAL SAFETY DATA SHEET SHALL NOT BE DEEMED TO CREATE ANY WARRANTY OF ANY KIND (INCLUDING WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE). In the event of an adverse incident associated with this material, this safety data sheet is not intended to be a substitute for consultation with appropriately trained personnel. Nor is this safety data sheet intended to be a substitute for product literature which may accompany the finished product. For additional information contact: Eli Lilly and Company Hazard Communication 317-433-7171 GLOSSARY: ACGIH = American Conference of Governmental Industrial Hygienists AIHA = American Industrial Hygiene Association BEI = Biological Exposure Index CAS Number = Chemical Abstract Service Registry Number CERCLA = Comprehensive Environmental Response Compensation and Liability Act (of 1980) CHAN = Chemical Hazard Alert Notice CHEMTREC = Chemical Transportation Emergency Center DOT = Department of Transportation EC = European Community EINECS = European Inventory of Existing Chemical Substances ELINCS = European List of New Chemical Substances EPA = Environmental Protection Agency HEPA = High Efficiency Particulate Air (Filter) IARC = International Agency for Research on Cancer ICAO/IATA = International Civil Aviation Organization/International Air Transport Association IEG = Lilly Interim Exposure Guideline IMO = International Maritime Organization Kow = Octanol/Water Partition Coefficient LEG = Lilly Exposure Guideline LEL = Lower Explosive Limit MSDS = Material Safety Data Sheet MSHA = Mine Safety and Health Administration NA = Not Applicable, except in Section 14 where NA = North America NADA = New Animal Drug Application NAIF = No Applicable Information Found NCI = National Cancer Institute NIOSH = National Institute for Occupational Safety and Health NOS = Not Otherwise Specified NTP = National Toxicology Program OSHA = Occupational Safety and Health Administration PEL = Permissible Exposure Limit (OSHA) RCRA = Resource Conservation and Recovery Act RQ = Reportable Quantity RTECS = Registry of Toxic Effects of Chemical Substances SARA = Superfund Amendments and Reauthorization Act STEG = Lilly Short Term Exposure Guideline STEL = Short Term Exposure Limit TLV = Threshold Limit Value (ACGIH) TPQ = Threshold Planning Quantity TSCA = Toxic Substances Control Act TWA = Time Weighted Average/8 Hours Unless Otherwise Noted UEL = Upper Explosive Limit UN = United Nations WEEL = Workplace Environmental Exposure Level (AIHA) Material Safety Data Sheet: Simple Green® Lime Scale Remover Version No. 00004 Date of Issue: January 2007 Section 1: ANSI-Z400.1-2003 Format PRODUCT & COMPANY IDENTIFICATION Product Name: Additional Names: Simple Green® Lime Scale Remover AROMA CLEAN™ by Simple Green® Bath, Tub & Tile Cleaner Manufacturer’s Product Code Numbers: Lime Scale Remover 50022 – 22 oz trigger spray bottle 50032* – 32 oz trigger spray bottle 50005* – 5 gallon pail Company: Telephone: Emergency Phone: Use of Product: Section 2: Aroma Clean Bath, Tub & Tile 16201 – 24 oz Trigger Spray Bottle 50128* – 1 gallon bottle 50155* – 55 Gallon Drum * GSA Available Sunshine Makers, Inc. 15922 Pacific Coast Highway Huntington Harbour, CA 92649 USA 800-228-0709 ● 562-795-6000 Fax: 562-592-3830 Chem-Tel 24-Hour Emergency Service: 800-225-3924 Ready to use liquid for removal of soap scum, mineral scale, hard-water spots, calcium and lime deposits on hard, non-porous surfaces. Not for use on any natural stone surface. HAZARDS IDENTIFICATION Emergency Overview: CAUTION. Eye irritant. This product contains no substances which at their given concentration, are considered to be hazardous to health. 0 0 1 0 NFPA/HMIS Rating: Health = 1 = slight Fire, Reactivity, and Special = 0 = minimal Principal Routes of Exposure: Eye, Skin contact, Ingestion Eye Contact: Eye Irritant. Skin Contact: Substance may cause slight skin irritation. May cause gastrointestinal irritation, nausea, vomiting and diarrhea. Ingestion: Carcinogens: No ingredients are listed by OSHA, IARC, or NTP as known or suspected carcinogens. No medical conditions are known to be aggravated by exposure to Simple Green® Lime Scale Medical Conditions: Remover. Section 3: COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Urea monohydrochloride CAS Number 506-89-8 Hazardous Substances Present: SARA 313 Substances Present: Clean Air Act Sec. 112 Substances Present: Section 4: Eye Contact: Skin Contact: Inhalation: Ingestion: % Weight 3-5% ACGIH TWA Not applicable Acute Toxicity LD50 1121 mg/kg rat (oral) None None None FIRST AID MEASURES In case of eye contact, remove contact lenses and rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Flush with water. Wash off the soap and water. Obtain medical attention if irritation persists. Wsh contaminated clothing well before reuse. Not a normal route of exposure. If symptoms develop, move victim to fresh air. If symptoms persist, call a physician. Clean mouth with water and afterwards drink plenty of water. Never give anything by mouth to an unconscious person. Consult a physician if necessary. Material Safety Data Sheet: SIMPLE GREEN® LIME SCALE REMOER Pg 1 of 3 Material Safety Data Sheet: Simple Green® Lime Scale Remover Date of Issue: January 2007 Version No. 00004 Section 5: FIRE FIGHTING MEASURES Flash Point: Hazardous Combustion Products: Suitable extinguishing media: Specific hazards: Section 6: ANSI-Z400.1-2003 Format Not flammable May include, but not limited to, oxides of carbon Treat for surrounding material. Fire fighters should wear self-contained breathing apparatus. ACCIDENTAL RELEASE MEASURES Method for cleaning up: Before initiating cleanup, refer to hazard data on this MSDS • Retrieve any useable product and store in properly marked containers • Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container • Prevent large spills from entering sewers and waterways. Section 7: HANDLING AND STORAGE Safe Handling: Storage: Incompatible Products: Section 8: Avoid contact with eyes. Wash hands immediately after contact to avoid hand-eye transfer. Keep out of reach of children. Keep containers tightly closed in cool, well-ventilated place. Bleach, mildew stain removers, caustics, oxidizers, reducers. EXPOSURE CONTROLS/PERSONAL PROTECTION Hand Protection Eye Protection Respiratory Protection Other Protective Equipment Engineering measures General hygiene conditions: Section 9: There are no known hazards associated with this material when used as recommended. The following general hygiene considerations are recognized as common good industrial hygiene practices: - Avoid breathing vapor or mist. - Avoid contact with eyes. - Wash thoroughly after handling and before eating, drinking, or smoking. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Odor: Vapor Density: pH: Boiling Point: Freezing Point: Water Content: Specific Gravity: Section 10: Rubber Safety Glasses Not normally required As required by employer code None, under normal processing Lime Scale Remover is a pale aqua liquid; AROMA CLEAN is a pale purple liquid. Lime Scale Remover has a wintergreen fragrance; AROMA CLEAN has a lavender fragrance. Not determined Completely water soluble. Water Solubility: 1.0 – 1.5 8.52 lbs/gallon Bulk Density: o o ~ 100 C (~212 F) None observed to boiling point. Flash Point: Ca. 0oC < 0.01% Insoluble matter: > 70% 0 g/L per EPA Method 24 VOCs: 1.0230 STABILITY AND REACTIVITY Stability: Materials to Avoid: Hazardous Decomposition Products: Stable None known None expected Material Safety Data Sheet: SIMPLE GREEN® LIME SCALE REMOER Pg 2 of 3 Material Safety Data Sheet: Simple Green® Lime Scale Remover Version No. 00004 Date of Issue: January 2007 Section 11: ANSI-Z400.1-2003 Format TOXICOLOGICAL INFORMATION Acute Toxicity: Oral LD50 (rat) - > 10 g/kg body weight Toxicity extrapolated from ingredients. Animal testing not conducted. Eye Irritation: This product may cause irritation to the eyes. Dermal Irritation: Not expected under normal use conditions. Repeat Exposure Via Skin Contact: No toxic effects are expected to be associated with normal daily exposure Section 12: ECOLOGICAL INFORMATION Hazard to wild mammals: Hazard to avian species: Hazard to aquatic organisms: Chemical Fate Information: Low, based on toxicology profile Low, based on toxicology profile > 100 mg/L (rainbow trout, 96 hours) Biodegradable; Based on formula & biodegradability, the bioaccumulation potential is low. Section 13: DISPOSAL CONSIDERATIONS Waste from residues/unused product: Empty Containers: Dispose in accordance with all national and local regulations. Triple-rinse with water and offer for recycling if available in your area. Otherwise, dispose as non-hazardous waste. Dispose of used or unused product, and empty containers in accordance with the local, State provincial, and Federal regulations for your location. Never dispose into lakes, streams, and open bodies of water or storm drains. Section 14: TRANSPORT INFORMATION DOT: Proper Shipping Name: Not regulated for ground shipments Cleaning Compound Class 55 UN No.: Packing Group: Not required. Not applicable Section 15: REGULATORY INFORMATION All components are listed on Canadian DSL, EINECS and TSCA Chemical Substances Inventory. RCRA Status: Not a hazardous waste. CERCLA Status: Not Listed. TSCA TIR Reporting: Not required / Not Listed. CA PROP. 65 Status: Not Listed. Section 16: OTHER INFORMATION Questions about the information found on this MSDS should be directed to: SUNSHINE MAKERS, INC. – TECHNICAL DEPARTMENT 15922 Pacific Coast Hwy. Huntington Harbour, CA 92649 Phone: 800/228-0709 [8am-5pm Pacific time, Mon-Fri] Fax: 562/592-3830 Email: infoweb@simplegreen.com DISCLAIMER: The information provided with this MSDS is furnished in good faith and without warranty of any kind. Personnel handling this material must make independent determinations of the suitability and completeness of information from all sources to assure proper use and disposal of this material and the safety and health of employees and customers. Sunshine Makers, Inc. assumes no additional liability or responsibility resulting from the use of, or reliance on this information. Material Safety Data Sheet: SIMPLE GREEN® LIME SCALE REMOER Pg 3 of 3 Material Safety Data Sheet Product Name: Number: DMN-308 Sparkle Floor Cleaner, #2473 A liquid alkaline detergent. Revised: 9/4/98 24 hour Emergency Only phone: 1-800-535-5053 Information phone: 1-800-362-9850 or 330-821-5310 fax: 330-821-6355 Damon Industries, Inc. Box 2120 Alliance, OH 44601 Section 2 - Composition / Information on Hazardous Ingredients Ingredient 1-Butoxy-2-propanol Potassium hydroxide Cas No. 5131-66-8 1310-58-3 Percent 2 - 10% 2 - 5% Carcinogen No No Section 3 - Hazards Identification Emergency Overview: Concentrate is corrosive to all body parts. Diluted solutions may be irritating or corrosive depending on their strength. Excessive inhalation of vapors may cause irritation. Product is water based and presents little or no hazard in a fire. Product has a high pH and large amounts should not be allowed into sewers without neutralizing. A green liquid with a sharp odor. Health Hazards: Corrosive, Irritant Primary Routes of Entry: X Through Skin Physical Hazards: None X Inhalation X Ingestion Potential Health Effects: Eyes - concentrate and strong solutions cause eye damage. Milder solutions cause irritation and redness. Skin - prolonged contact with concentrate and strong solutions can cause skin damage and loss. There is little or no effect if rinsed off thoroughly right away. Weaker solutions cause irritation. Swallowing - may result in damage to mucous membranes and gastrointestinal irritation. Breathing - excessive inhalation of mist or spray can cause coughing, irritation of nose and throat. Section 4 - First Aid Measures Eye Contact: Immediately flush eyes with water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention immediately. Skin Contact: With concentrate and strong (1:10) solutions immediately flush exposed area with running water for 15 minutes. Remove contaminated clothing and shoes. With weaker solutions wash exposed area with soap and water. If irritation persists, call a physician. Wash contaminated clothing before reuse. Inhalation: If affected, move exposed person to fresh air. If irritation persists get medical attention. Ingestion: If the product is swallowed, do NOT induce vomiting. If the affected person is conscious, give a glass of water or milk to drink. Get medical attention immediately. Section 5 - Fire-Fighting Measures Flash Point: None (ASTM D-56 closed cup) Lower Explosive Limit: Not Applicable Extinguishing Media: Any Special Fire Fighting Procedures: None. Unusual Fire And Explosion Hazards: None. Upper Explosive Limit: Not Applicable Section 6 - Accidental Release Measures Steps To Be Taken If Material Is Released Or Spilled: Small spills of a few gallons may be cleaned up with a rag or mop. Larger spills should diked to prevent spreading and then collected into clean pails or drums. Section 7 - Handling and Storage Empty containers retain product residue and may be hazardous. Observe all precautions given in this data sheet. Keep from freezing. DMN-308 Sparkle Floor Cleaner Page 1 of 2 9/4/98 Section 8 - Exposure Controls / Personal Protection Ingredient 1-Butoxy-2-propanol Potassium hydroxide C.A.S. No. 5131-66-8 1310-58-3 (1)=OSHA (2)=NIOSH (3)=ACGIH (4)=CANADA Percent 2 - 10% 2 - 5% TWA(source) STEL Ceiling no established limits are available 2 mg/m3(2) 2 mg/m3(3,4) TWA=8 hr Time Weighted Average STEL=15 minute TWA Ceiling=Instantaneous Ventilation: Good room ventilation. Respiratory Protection: None, except when spraying overhead use an approved respirator with an organic vapor cartridge. Gloves: Use rubber or latex gloves when handling concentrate or strong dilutions. Persons with sensitive skin or who use the product for prolonged periods may wish to use rubber or latex gloves when using any dilution. Eye Protection: Most uses of diluted product do not require eye protection although the use of safety glasses with side shields, especially for contact lens wearers, is always a good idea. Using concentrate or strong (1:10) solutions requires safety glasses with side shields. Overhead spraying requires goggles or a face shield, or if considerable spray will fall on the user, complete head and body protection. Other Protective Equipment: An eyewash station should be located within 10 seconds travel time of the concentrate use/mixing area. Section 9 - Physical and Chemical Properties Boiling Point: 215° F. Specific Gravity: 1.05 Percent Volatiles: 85% Solubility In Water: Complete Appearance and Odor: Green liquid with sharp odor. Vapor Pressure: Not Available Vapor Density: Not Available Evaporation Rate: Same as water. pH: concentrate 13.5 ± 0.5 Section 10 - Stability and Reactivity Incompatibility: None Hazardous Decomposition Products: None Section 11 - Toxicological Information Target Organs: None. Section 12 - Ecological Information When scrubbing outdoors or where the solution will enter a storm sewer, flood the cleaned area with plenty of water to dilute and reduce pH of run-off. Do not use more product than necessary. Do not dispose of unusable product in the environment. Be sure to comply with any applicable regulations. Section 13 - Disposal Considerations Waste Disposal Method: Dispose of up to 2 gallons of concentrate in the sanitary sewer with a large amount of water. Larger amounts must be neutralized to within the pH limits of your waste water treatment system. Section 14 - Transport Information D.O.T. Hazard Class: Not considered hazardous by D.O.T., I.M.C.O., I.A.T.A. or U.N. Section 15 - Regulatory Information The components of this product are on the TSCA inventory of chemical substances. Section 16 - Other Information NFPA / HMIS Ratings: Health: Flammability: Reactivity: 2 0 0 0 = Insignificant 3 = Serious 1 = Slight 2 = Moderate 4 = Severe The information accumulated herein is believed to be accurate but is not warranted to be. Recipients are advised to confirm in advance that the information is current, applicable, and suitable to their circumstances. DMN-308 Sparkle Floor Cleaner Page 2 of 2 9/4/98 MATERIAL SAFETY DATA SHEET VANISH NON-ACID BOWL & BATHROOM CLEANER II HMIS Health Fire Hazard Reactivity 1 1 0 NFPA 1 1 0 Personal protective equipment Preparation date: 2005-08-23 Version Number: 1 1. PRODUCT AND COMPANY IDENTIFICATION Product name: VANISH NON-ACID BOWL & BATHROOM CLEANER II MSDS #: Product code: Recommended use: 126478001 126478001, 90158 Cleaning product. Manufacturer, importer, supplier: US Headquarters JohnsonDiversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-0902 Phone: 1-888-352-2249 MSDS Internet Address: www.johnsondiversey.com Emergency telephone number: Canadian Headquarters JohnsonDiversey - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-800-668-3131 1-800-851-7145 (Prosar); 1-651-917-6133 (Int'l Prosar); 01-800-710-3400 (México) 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Moderately irritating to the eyes. Moderately irritating to the skin. Principle routes of exposure: Skin contact: Eye contact: Inhalation: Ingestion: Inhalation. Skin contact. Eye contact. May be mildly irritating to skin. Moderately irritating to the eyes. None known. None known. 3. COMPOSITION/INFORMATION ON INGREDIENTS HAZARDOUS COMPONENTS Ingredient N-alkyl dimethyl benzyl ammonium chlorides N-alkyl dimethyl ethylbenzyl ammonium chlorides Isopropyl alcohol CAS # 68391-01-5 Weight % 0.1 - 1.5% LD50 Oral Not available LD50 Dermal Not available LC50 Inhalation Not available 68956-79-6 0.1 - 1.5% Not available Not available Not available 67-63-0 1 - 5% 5000 mg/kg (rat) 12800 mg/kg (rabbit) 16000 ppm/8H (rat) 4. FIRST AID MEASURES Eye contact: Skin contact: Inhalation: Ingestion: Aggravated Medical Conditions: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eyes. If irritation persists, get medical attention. Flush immediately with plenty of water. Get medical attention if irritation occurs. No specific first aid measures are required. No specific first aid measures are required. Persons with pre-existing skin disorders may be more susceptable to irritating effects 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: Use dry chemical, CO2, water spray or "alcohol" foam. VANISH NON-ACID BOWL & BATHROOM CLEANER II 1 of 3 Specific hazards: Unusual hazards: Specific methods: Although this product has a flash point below 200 Deg. F, it is an aqueous solution containing an alcohol and does not sustain combustion. None known. No special methods required. Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Extinguishing media which must not be used for safety reasons: No information available 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Environmental precautions and clean-up methods: Put on appropriate personal protective equipment (see Section 8.). Use appropriate containment to avoid environmental contamination. Sweep up and shovel into suitable containers for disposal. Keep in suitable and closed containers for disposal. Use a water rinse for final clean-up. 7. HANDLING AND STORAGE Handling: Avoid contact with skin, eyes and clothing. Wash thoroughly after handling. FOR COMMERCIAL AND INDUSTRIAL USE ONLY Storage: Keep tightly closed in a dry, cool and well-ventilated place. Protect from freezing . Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: None known Personal Protective Equipment Eye protection: Hand protection: Skin and body protection: Respiratory protection: Hygiene measures: Ingredient Isopropyl alcohol No special requirements under normal use conditions No special requirements under normal use conditions No special requirements under normal use conditions No special requirements under normal use conditions Handle in accordance with good industrial hygiene and safety practice CAS # 67-63-0 ACGIH 400 ppm (STEL) 200 ppm (TWA) OSHA 980 mg/m3 400 ppm Mexico 1225 mg/m3 (STEL) 980 mg/m3 (TWA) 9. PHYSICAL AND CHEMICAL PROPERTIES Liquid Physical State: Color: Clear Blue Odor: No information available Specific gravity: No information available Dilution pH: No information available Bulk density: No information available Vapor density: No information available Evaporation rate: No information available Solubility in other No information available solvents: Viscosity: No information available Partition coefficient (n-octanol/water): No information available Appearance: No information available Boiling point/range: >199.4 (°F) Melting point/range: <32 (°F) pH: 7.5 Density: No information available Decomposition temperature: Not determined Autoignition temperature: No information available Solubility: Soluble VOC: 2% Flash point: 141.8 (°F) 61 (°C) 10. STABILITY AND REACTIVITY Stability: Polymerization: Hazardous decomposition products: Materials to avoid: Conditions to avoid: The product is stable. Not applicable. None reasonably foreseeable None known . Keep away from heat. 11. TOXICOLOGICAL INFORMATION Acute toxicity Component Information: LD50 estimated to be greater than 5000 mg/kg. See Section 3 Chronic toxicity: None known Specific effects Carcinogenic effects: None known VANISH NON-ACID BOWL & BATHROOM CLEANER II 2 of 3 Mutagenic effects: Reproductive toxicity: Target organ effects: None known None known None known 12. ECOLOGICAL INFORMATION Environmental Information: When used for its intended purpose this product should not cause adverse effects in the environment 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: PESTICIDAL WASTE - Observe all applicable Federal/Provincial/State regulations and Local/Municipal ordinances regarding disposal of pesticide wastes . 14. TRANSPORT INFORMATION DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information 15. REGULATORY INFORMATION International Inventories All components of this product are listed on the following inventories: Korea (ECL), Philippines (PICCS), China (IECSC). U.S. Regulations EPA Reg. No. : 70627-3 California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65 STATE RIGHT TO KNOW Ingredient Water Isopropyl alcohol Alcohol ethoxylates CAS # 7732-18-5 67-63-0 68131-39-5 CERCLA / SARA Ingredient Isopropyl alcohol CAS # 67-63-0 MARTK: Listed - NJRTK: Listed - Weight % 1 - 5% PARTK: Listed - CERCLA/SARA RQ (lbs) 100 RIRTK: Listed - ILRTK: Listed - Section 302 TPQ (lbs) CTRTK: Listed - Section 313 Listed. Canada WHMIS hazard class: Not for sale in Canada . Ingredient Isopropyl alcohol CAS # 67-63-0 NPRI Listed 16. OTHER INFORMATION Reason for revision: Prepared by: Additional advice: Not applicable NAPRAC None Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. VANISH NON-ACID BOWL & BATHROOM CLEANER II 3 of 3 MATERIAL SAFETY DATA SHEET 24 HOUR EMERGENCY CHEMTREC TELEPHONE 1-(800)-424-9300 24 HOUR MEDICAL EMERGENCY TELEPHONE 1-(888)-324-7596 WD-40 COMPANY, 1061 Cudahy Place (92110), P.O. Box 80607, San Diego, CA 92138-0607 TELEPHONE (619)-275-1400 DATE PREPARED: December, 2004 I. GENERAL INFORMATION PRODUCT NAME: Maximum Strength X-14 Instant Mildew Stain Remover PRODUCT CATEGORY: Household Cleaner II. INGREDIENTS HAZARDOUS INGREDIENTS: % Sodium hypochlorite 3-6% Sodium carbonate 0.5-2% CAS # 7681-52-9 497-19-8 TLV/PEL Not established Not established HAZARD DATA Irritant/Corrosive Irritant III. HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE: SKIN: May cause skin irritation. EYE: Causes eye irritation. INHALATION: Mist may be irritating to the upper respiratory tract. Not recommended for use by persons with heart conditions or chronic respiratory problems. INGESTION: May cause gastrointestinal irritation, nausea, vomiting and diarrhea. FIRST AID PROCEDURE: SKIN: Flush immediately and thoroughly with water. EYE: Flush with large amounts of water for at least 15 minutes while holding eyelids open. Contact a physician. INHALATION: Discontinue use. Remove to fresh air. INGESTION: Do not induce vomiting. Drink several glasses of water. Call a poison control center or a physician immediately. Do not give anything by mouth to unconscious individuals. IV. SPECIAL PROTECTION INFORMATION EYE PROTECTION: Safety glasses should be worn in an industrial/institutional setting. SKIN PROTECTION: For sensitive skin or prolonged use, wear rubber gloves. RESPIRATORY PROTECTION: Not needed when product is used according to label directions. Appropriate cartridge respirator may be needed in an institutional setting. Use in a well-ventilated area. V. FIRE AND EXPLOSION HAZARD DATA FLAMMABLE LIMITS: Non-flammable liquid. EXTINGUISHING MEDIA: As applicable to type of fire. SPECIAL FIRE FIGHTING PROCEDURES: Fire can be fought with standard procedures but hazards are present that can be handled safely by wearing self contained breathing apparatus. UNUSUAL FIRE/EXPLOSION HAZARDS: None VI. ENVIRONMENTAL PROTECTION PROCEDURES SPILL RESPONSE: Wipe up spill with absorbent material. Rinse spill area with water to remove residue. WASTE DISPOSAL METHOD: Do not reuse container. Dispose of in accordance with federal, state and local regulations. VII. SPECIAL PRECAUTIONS HANDLING: Avoid contact with eyes, contact lens or eyeglasses. Avoid contact with skin. Avoid breathing fumes. STORAGE: Do not store next to acids or heat source. Keep container tightly closed. TRANSPORTATION: In accordance with federal, state and local regulations. VIII. REACTIVITY DATA STABILITY: Stable. INCOMPATIBILITY: Do not mix with acids, ammonia or other household chemicals. HAZARDOUS DECOMPOSITION PRODUCTS: When heated can form carbon monoxide, carbon dioxide and chlorine. IX. PHYSICAL DATA BOILING POINT (°F): Not determined. VAPOR PRESSURE (mm Hg): Not determined. VAPOR DENSITY (AIR=1): Not determined. APPEARANCE AND ODOR: Clear, yellow liquid with chlorine odor. SPECIFIC GRAVITY (H2O=1): 1.03-1.15 % VOLATILE BY VOLUME: Greater than 85%. SOLUBILITY IN WATER: Soluble pH: 11.5-12.0 The information provided in this Material Safety Data Sheet has been compiled from our experience and data with similar commercially available materials and is believed to be accurate. No guarantee of accuracy is made. It is the user's responsibility to determine the suitability of this information for the adoption of necessary safety precautions and disposal procedures. PLEASE BE ADVISED THAT THIS MATERIAL SAFETY DATA SHEET IS INTENDED FOR INDUSTRIAL PURCHASERS WHICH MAY USE LARGE QUANTITIES OF THE PRODUCT. DEPENDING ON THE SCOPE OF TOXICOLOGICAL TESTS CONDUCTED ON THE FORMULATION AND/OR THE RAW MATERIALS, THE LISTED HAZARD DATA MAY REFLECT HAZARDS RELATED TO THE FORMULATION AS A WHOLE OR TO INDIVIDUAL COMPONENTS AT 100% CONCENTRATION. THEREFORE, CERTAIN WARNINGS AND HAZARD STATEMENTS CONTAINED ON THIS MSDS MAY NOT BE APPLICABLE TO OR INCLUDED IN THE PACKAGE LABELING AVAILABLE TO THE GENERAL PUBLIC. SIGNATURE: Peter Fougner TITLE: REVISION DATE: SUPERSEDES: MSDS No.:X14MSR December, 2004 Director - Global Quality Assurance October, 2003 U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET (Prepared According to 29 CFR 1910.1200) ______________________________________________________________________________ SECTION 1 IDENTIFICATION Product Name: Manufacturer's Name: Manufacturer's Address: Manufacturer's Phone Number: Emergency Phone Number: Proper Shipping Name: Effective Date: FORMULA 499185 ZENAGEL ZENEX International 7777 First Place, Cleveland Ohio 44146 (440) 232-4155 1-800-535-5053 Consumer Commodity, ORM-D 10-15-01 ______________________________________________________________________________ SECTION 2 IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS Chemical Name: Sodium Hydroxide Butane Triethylene Glycol Propane Ethanolamine CAS No.: 1310-73-2 106-97-8 112-27-6 74-98-6 141-43-5 TLV: 2 mg/m3 ceiling 800ppm N.A. 2500ppm 3ppm ______________________________________________________________________________ SECTION 3 Boiling Point: Solubility in Water: pH: PHYSICAL DATA <0 to 5670 F Soluble 13.5 + 0.5 Specific Gravity(H2O=1): Evaporation Rate: Vapor Density(Air=1): 0.99 + 0.05 Slower than Ether Heavier than air _______________________________________________________________________________________________________________________________________ SECTION 4 FIRE AND EXPLOSION HAZARD DATA Flash Point: Flash Point(Propellant): Flammable Limits(Propellant): Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: Non-Flammable <0OF LEL: 0.9 UEL: 9.5 Use water fog, dry chemical or carbon dioxide. Aerosol cans may rupture when heated. Heated cans may burst. _______________________________________________________________________________________________________________________________________ SECTION 5 Unstable______ Stable __X___ Incompatability (Materials to Avoid): Conditions to Avoid: Hazardous Decomposition or Byproducts: Hazardous Polymerization: REACTIVITY DATA Stability: Acids High temperatures. In fire, will decompose to carbon dioxide, carbon monoxide Will not occur __________________________________________________________________________________________________________________________________________ SECTION 6 STORAGE AND HANDLING INFORMATION Precautions to be Taken in Handling and Storing: When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved respirator. STORE AT TEMPERATURES BELOW 120oF KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME KEEP AWAY FROM CHILDREN FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY FOR USE BY TRAINED PERSONNEL ONLY KEEP CONTAINER CLOSED DURING STORAGE __________________________________________________________________________________________________________________________________________ SECTION 7 HEALTH HAZARDS AND FIRST AID Effects of Overexposure: SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible. EYES: Eye irritant. Will cause redness and burning sensation. INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness, nausea, and loss of coordination.Extreme overexposure may result in unconsciousness and possibly death. INGESTION: Aspiration hazard if swallowed. First Aid Procedures: SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get medical attention. Remove contaminated clothing and launder before reuse. EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Seek medical attention. INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention. INGESTION: DO NOT induce vomiting. Seek medical attention immediately. Note: Never give anything by mouth to an unconscious or convulsing victim. Keep person warm and quiet. __________________________________________________________________________________________________________________________________________ SECTION 8 SPECIAL PROTECTION INFORMATION Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: Self-contained breathing apparatus if above TLV limit. Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit. None required if spraying. As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we recommend the use of safety glasses or chemical splash goggles. Other Protective Equipment: Long sleeves and long pants. Work/Hygienic Practices: Do not smoke while using. Wash hands after use. __________________________________________________________________________________________________________________________________________ SECTION 9 SPILL OR LEAK PROCEDURE Steps To Be Taken In Case Material Is Released or Spilled: Use absorbent sweeping compound to soak up material. Put into container. Dispose as hazardous waste. Waste Disposal Method: Dispose as hazardous waste in accordance with EPA RCRA. _________________________________________________________________________________________________________________________________________ SECTION 10 REGULATORY INFORMATION SARA Title III, Section 313 Components: None __________________________________________________________________________________________________________________________________________ This information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties, express or implied, and assume no liability in connection with any use of this information. 499185 Friday, January 18, 2008 Page 1 of 4 MSDS - Material Safety Data Sheet Product Name: CARPET AND UPHOLSTERY ALL PURPOSE FOAM CLEANER MSDS No.: MPC22 I. Basic Information: Manufacturer: RADIATOR SPECIALTY COMPANY 2 Address: 600 RADIATOR ROAD City, ST Zip: INDIAN TRAIL, NC 28079 1 Emergency Contact: Rocky Mountain Poision Control Center Emergency Telephone Number: 303-623-5716 Contact: Robert Geer Information Telephone Number: 704-684-1811 Last Update: 01/18/2008 Chemical State: X Chemical Type: 1 2 Expiration Date: Liquid Pure Gas X 0 Solid B Mixture II. Ingredients: Trade Secret EHS IARC NTP SARA 313 OSHA SUB Z PEL ACGIH TLV X 25 ppm 25 ppm CAS No. Chemical Name % Range 111-76-2 2-Butoxyethanol 1-5 106-97-8 Butane 1-4 N/E 800 ppm 74-98-6 Propane 1-4 N/E 1000 ppm 1310-73-2 Sodium hydroxide 0-3 2 mg/m3 2 mg/m3 Other Limits III. Hazardous Identification: Hazard Category: X Acute Chronic Fire X Pressure Hazardous Identification Information: CAUTION: Eye Irritant, Contents Under Pressure. Level 1 Aerosol IV. First Aid Measures: Route(s) of Entry: Absorption, Eye, Inhalation, and Ingestion. Health Hazards (Acute and Chronic): See signs and symptoms below. Signs and Symptoms: Eye Contact: Direct spray of vapors may be irritating or harmful to eyes. Skin Contact: Prolonged contact may cause irritation due to defatting of skin. Inhalation: High concentration of vapors may irritate nose and throat and cause headaches and nausea. Ingestion: Can cause irritation, gastric disturbances, and nausea.. Medical Conditions Generally Aggravated by Exposure: Reactive Friday, January 18, 2008 Page 2 of 4 MSDS - Material Safety Data Sheet Product Name: CARPET AND UPHOLSTERY ALL PURPOSE FOAM CLEANER MSDS No.: MPC22 None known Emergency and First Aid Procedures: Eye Contact: Flush eyes with water for 15 minutes while lifting upper and lower eyelid. Get prompt medical attention. Skin Contact: Wash with soap and water. If irritation persists, get prompt medical attention. Inhalation: Move to fresh air. If breathing becomes difficult get prompt medical attention. Ingestion: Drink water or milk. Call Poison Control Center, physician, or hospital emergency room immediately. . Other Health Warnings: None known V. Fire Fighting Measures: Flash Point: None F.P. Method: Lower Explosive Limit: N/D Upper Explosive Limit: N/D TCC Fire Extinguishing Media: Water Fog, Foam, Carbon Dioxide, Dry Chemical Special Fire Fighting Procedures: Wear self-contained , positive pressure breathing apparatus and protective clothes. Cool containers exposed to heat with water fog. Unusual Fire and Explosion: Use shield to protect from venting, rupturing, or bursting cans. VI. Accidental Release Measures: Steps to be Taken in Case Material is Released or Spilled: Use appropiate protective equipment. Contain spill and then absorb spill with inert material or rags and scoop into a chemical waste container. Neutralize remaining traces of material and flush with water followed by liberal covering with sodium bicarbonate. All clean-up material should be removed and placed in approved containers for disposal. Rinse water may be disposed of down a sanitary sewer system if authorized by the local municipality. VII. Handling and Storage: Precautions to be Taken: Use with adequate ventilation. Do not take internally. Do not expose to heat or store at temperatures above 120 F. Do no puncture or incinerate container. Other Precautions: Avoid contact with strong oxidizing agents. VIII. Exposure Controls/Personal Protection: Ventilation Requirements: See Section 2 for applicable exposure limits. Use with adequate ventilation. If TLV is exceeded, wear NIOSH approved respirator. Personal Protective Equipment: See Section 2 for applicable exposure limits. For prolonged exposure wear protective safety glasses, gloves, and apron. Friday, January 18, 2008 Page 3 of 4 MSDS - Material Safety Data Sheet Product Name: CARPET AND UPHOLSTERY ALL PURPOSE FOAM CLEANER MSDS No.: MPC22 IX. Physical and Chemical Properties: Boiling Point: 212 F Melting Point: N/A Evaporation Rate (Butyl Acetate = 1): < 1 Vapor Pressure (mm Hg.): N/D Specific Gravity (H20 = 1): 1.00000 Vapor Density (AIR = 1): N/D Solubility In Water: Soluble Appearance and Odor: Other Information: pH: 11.5 - 12.5 White spray foam with light citrus floral scent X. Stability and Reactivity: Stability: Stable Incompatibility (Materials to Avoid): Avoid contact with strong oxidizing agents Decomposition/By Products: Carbon Monoxide, Carbon Dioxide Hazardous Polymerization: Will not occur XI. Toxicological Information: N/D XII. Ecological Information: N/D XIII. Disposal Considerations: DISPOSAL: This container may be recycled in aerosol recycling centers when empty. Before offering for recycling, empty the can by using the product according to the label. DO NOT PUNCTURE! If recycling is not available, wrap the container and discard in the trash. Dispose of unused product in accordance with all local, state government and federal laws and regulations. XIV. Transport Information: DOT Hazard Class: ORM-D Shipping Name: Consumer Commodity The DOT description is provided to assist in the proper shipping classification of this product and may not be suitable for all shipping purposes. XV. Regulatory Information: See Section 2 for SARA Reportable Chemicals. USA TSCA: All components of this material are listed on the US TSCA Inventory. Friday, January 18, 2008 Page 4 of 4 MSDS - Material Safety Data Sheet Product Name: CARPET AND UPHOLSTERY ALL PURPOSE FOAM CLEANER MSDS No.: MPC22 XVI. Other Information: Do not used in confined area without proper ventilation. Contact lenses may cause further damage in case of splash into eye. KEEP AWAY FROM CHILDREN AND ANIMALS! N/E: Not Established N/D: Not Determined N/A: Not Applicable N/AV: Not Available While Radiator Specialty Company believes this data is accurate as of the revision date, we make no warranty with respect to the data and we expressly disclaim all liability for reliance thereon. The data is offered solely for information, investigation, and verification. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. MATERIAL SAFETY DATA SHEET Complies with OSHA hazard communication standard 29 CFR 1910.1200 Scot Laboratories 16841 Park Circle Drive Chagrin Falls, OH 44023 Phone: Fax: Date: (440) 543-3033 (440) 543-1825 September 26, 2000 SECTION I - Product Identification Product Name: Carpet Shampoo for Extraction Cleaners HMIS Rating Health1 Fire0 Reactivity-0 0= minimal, 1= slight, 2= moderate, 3= serious, 4= severe Code: 237 SECTION II - Hazardous Ingredients/Identity Information - NONE SECTION III - Physical/Chemical Characteristics Physical State: Liquid Vapor Density (AIR = 1): Color: Clear, Lt. Amber Vapor Pressure (mm Hg): Odor: Pleasant Solubility in Water: o Boiling Point: 212 F Specific Gravity (H2 O): o Melting Point: 32 F Evaporation Rate: Heavier than air Unknown Complete 1.055 < 1 (Butyl Acetate = 1) SECTION IV - Fire and Explosion Hazard Flash Point: Flammability Limits in Air: Extinguishing Media: Data None N/A N/A SECTION V - Reactivity Data Stability: Material to Avoid: Conditions to Avoid: Hazardous Decomposition or Byproducts: Stable Do not mix with other chemicals. Follow instructions on label. Unknown Unknown (Hazardous Polymerization will not occur) Fire Fighting Procedure: Unusual Fire or Explosion Hazards: None None SECTION VI - Health Hazard Data Product hazard classification: None Carcinogenic ingredients: Unknown Effects of overexposure: Ingestion may cause nausea or diarrhea. May be irritating to eyes. Medical Conditions aggravated by use: Unknown First Aid Procedures: INGESTION: Do not induce vomiting, drink plenty of water, contact a physician immediately. SKIN/EYE CONTACT: Flush with water for 15 minutes. If irritation persists, consult a physician. SECTION VII - Pre cautions for Safe Handling and Use In case of Release or Spill: Recover liquid with absorbent. Mop up or wet vac. Rinse area with water to remove. Waste Disposal Method: Small amounts - down drain or sanitary landfill. Large amounts - obey local ordinances. Handling and Storing:Do not store near heat. Do not freeze. Other Precautions: If frozen, thaw to room temperature and mix before using. Do not pour unused portion back into container - it contaminate product. SECTION VIII - Control Measures Gloves: None Eye Protection: None Other Protection: None Respirator: Ventilation: Work/Hygienic Practices: may None Local exhaust is normally adequate. Follow good manufacturing and housekeeping rules. SECTION IX - Special Precautions - None SECTION X - Department of Transportation Shipping Hazard Classification: None DISCLAIMER The information contained herein was obtained from current and reliable sources. However, the data is provided without any warranty, expressed or implied, regarding its correctness or accuracy. Since the conditions for use, handling, storage and disposal of this product are beyond Scot Laboratories' control, it is the user's responsibility both to determine safe conditions for use of this product and to assume liability for loss, injury, damage or expense arising from the product's improper use. No warranty, expressed or implied, regarding the product described herein shall be created by or inferred from any statement or omission in this MSDS. Various government agencies (e.g., DOT, EPA, FDA) may have specific regulations concerning the transportation, handling, storage, use or disposal of this product which may not be reflected in this MSDS. The user should review these regulations to ensure full compliance. Manufactured By: Product Name: PRODUCTS CHEMICAL COMPANY CARPET SPOT CLEANER 6400 Herman Av Cleveland OH 44102 216-281-1155 EMERGENCY: phone number involving spill, leak, fire or accident: MATERIAL SAFETY DATA INFOTRAC 800-535-5053 (Prepared According to 29CFR 1910,1200) 1611 SECTION 1 -- PRODUCT IDENTIFICATION Product Code # PRODUCT NAME: HMIS Rating Health Fire Reactivity Personal Protection PRODUCT TYPE: CARRPET SPOT CLEANER COMPANY NAME: COMPANY ADDRESS: Proper Shipping Name: COMPOUND, CLEANING LIQUID, NOI CAS NO. SULFONIC ACID 27176-87-0 2 BUTOXYETHANOL 111-76-2 ... ... ... ... 1 0 0 B Formula Proprietary SECTION 2 -- INGREDIENTS CHEMICAL NAME 1611 PERCENT WT Revision Date: 08/06 313 / CHEM 5 to 10 N 7.813 Y PEL TWA-TLV CARCINOGEN NO 25ppm 25ppm Yes NOTE: This product contains materials subject to the reporting requirements of SARA, Section 313 Emergency Planning & Right-to-Know Act. The balance of the chemicals in this mixture are either considered nonhazardous or are below the listing limits for hazardous substances. These chemicals are considered trade secrets. The specific identity of these chemicals is available to health professionals. SECTION 3 -- PHYSICAL DATA SECTION 4 -- FIRE AND EXPLOSION DATA 212 Boil Point Specific Gravity Volatile: Vapor Press.(mmhg) 20@68f VaporDensity (AIR=1) N/A pH Soluble in water Evap. Rate(H20=1) = 1 VOC = 82.9 (g/l) VOS of Concentrate = 7.9% CLEAR LIQUID/CHARACTERISTIC Appearance / Odor: 1.046 90 10 SECTION 5 -- REACTIVITY DATA Flash Point: N/A (TCP) Flammable Limits: N/A Non-Flammable Extinguishing Media: N/A Special Fire Fighting Procedures: Fire, Explosion Hazards: N/A SECTION 6 -- STORAGE AND HANDLING Stability: STABLE Hazardous Polymerization: WILL NOT OCCUR NONE KNOWN Incompatibility: NONE KNOWN Hazardous Decomposition: KEEP OUT OF THE REACH OF CHILDREN For industrial use only SECTION 7 -- HEALTH AND FIRST AID EYES: May Cause eye irritation. SKIN: May cause skin irritation. EYES: Flush eyes with large amounts of water. Consult physician if irritation continues. SKIN: Flush with water. INHALATION: INHALATION: Move person to fresh air. Consult physician INGESTION: May cause irritation to the intestine, mouth, throat, & esophagus. INGESTION: Do not induce vomiting or give anything by mouth to an unconscious person. Consult Physician. SECTION 8 -- SPECIAL PROTECTION DATA Respiratory Protection: Adequate ventilation Ventilation as required to maintain TLV Protective Gloves: Rubber Gloves Recommended. Eye Protection: Safety Glasses Recommended N/A = Not Applicable SECTION 9 -- SPILL OR LEAK PRECAUTIONS Steps to be taken in case of spill or leak: Mop or absorb for disposal Waste disposal Method: Sewer or incinerate with local approval. CMP = Complete END OF GENERATE Spot Shot Carpet and Stain Remover 5/25/05 Material Safety Data Sheet (MSDS) Section 1 - Chemical Product and Company Identification MANUFACTURER/SUPPLIER: US Office: Spot Shot Products A Division of WD-40 Company 1061 Cudahy Place San Diego, CA 92110 Information Phone #: (619) 275-1400 Emergency Phone # 24 hr: Chemtrec: (800) 424-9300 – Designated for use only in the event of chemical emergencies involving a spill, leak, fire exposure or accident involving chemicals. Canadian Office: WD-40 Products [Canada] LTD. P.O. Box 220 Toronto, Ontario M9C 4V3 Information Phone #: (416) 622-9881 Emergency Phone # 24 hr: Canutec: (613) 996-6666 – Designated for use only in the event of chemical emergencies involving a spill, leak, fire exposure or accident involving chemicals PRODUCT NAME: SPOT SHOT CARPET STAIN REMOVER (14 oz.) FORMULA: Mixture GENERAL CLASS: Aerosol Cleaning Aid MSDS DATE OF PREPARATION: May 25, 2005 HMIS Rating Health: 2 Flammability: 2 Reactivity: 1 Section 2 - Composition/Information on Ingredients Ingredient 2-Butoxyethanol Liquefied Petroleum Gas See Section 8 for Exposure Limits CAS # 111-76-2 68476-85-7 Weight Percent Less than 25% Less than 10% Section 3 – Hazards Identification AEROSOL SPRAY. PLEASANT ODOR. CAUTION! CONTENTS UNDER PRESSURE. AVOID HEAT AND FLAMES. MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. HARMFUL IF INTENTIONALLY INHALED. HARMFUL IF ABSORBED THROUGH SKIN. MAY AFFECT LIVER, KIDNEYS, BLOOD, LYMPHATIC SYSTEM OR CENTRAL NERVOUS SYSTEM. Avoid breathing concentrated vapors. Use with adequate ventilation. Avoid getting on skin, in eyes, and on clothing. Wash thoroughly after handling. Potential Health Effects: Primary Routes of Entry: Inhalation, skin and eye contact. Acute Effects: Inhalation: Excessive inhalation can cause headache, drowsiness, nausea and lack of coordination. Can cause irritation of respiratory tract. Skin Contact: Can cause skin irritation. Toxic amounts may be absorbed through the skin with symptoms similar to those under inhalation and ingestion. Eye Contact: Liquid sprayed into eyes causes corneal irritation and pain. Ingestion: Symptoms are similar to those of inhalation including pain, diarrhea and vomiting. May cause damage to the liver and kidneys. Chronic Effects: 2-butoxyethanol has caused lymphatic system, blood, liver and kidney damage. Medical Conditions Aggravated by Exposure: Pre-existing respiratory, skin, eye, liver, kidney and lymphatic disorders. Page 1 of 4 Spot Shot Carpet and Stain Remover 5/25/05 Section 4 – First Aid Measures IF INHALED: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. IF SWALLOWED: Do not induce vomiting. Call a physician or poison control center. Give one eightounce glass of water to drink if the patient if conscious and responsive. Never give anything by mouth to an unconscious person. IF ON SKIN: Wash skin with soap and water. Remove contaminated clothing and wash before reuse. Get medical attention if irritation persists or symptoms of exposure develop. IF IN EYES: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention if irritation persists. Section 5 – Fire Fighting Measures Flammability Properties: Not flammable per flame projection test. Extinguishing Media: Carbon dioxide, dry chemical, water fog Special Fire Fighting Instructions: Keep fire-exposed containers cool with water spray. In the event of a fire, wear full protective clothing and a NIOSH approved self-contained breathing apparatus with full face piece and operated in positive pressure mode. Unusual Fire and Explosion Hazards: Exposure of containers to extreme heat and flames can cause them to rupture often with violent force and subsequent fire. Section 6 – Accidental Release Measures Ventilate area of spill and remove all sources of ignition. Observe all hazards mentioned in Section 3. Wear personal protective equipment specified in Section 8. Spills: Wipe, scrape or soak up contents in an inert material. Pick up spill for recovery or disposal and place in a closed container. Section 7 – Handling and Storage Handling: Use with adequate ventilation. Do not smoke or use around open flames or sources of extreme heat. Intentional misuse by deliberately concentrating vapors and inhaling can be harmful or fatal. Avoid getting in eyes or on skin and clothing. Do not breathe vapors. Wash thoroughly after handling, and wash contaminated clothing before reuse. Storage: Store in a cool, dry ventilated area. Protect from physical damage. Do not store in direct sunlight, near open flames or above temperatures greater than 120 F. Do not place can in hot water or near radiators, stoves or other sources of heat. Section 8 – Exposure Controls/Personal Protection Occupational Exposure Limits 2-Butoxyethanol Liquefied Petroleum Gas 20 ppm TWA ACGIH-TLV 50 ppm TWA OSHA PEL skin 1000 ppm TWA ACGIH TLV 1000 ppm TWA OSHA PEL (as propane) The Following Controls are Recommended for Normal Consumer Use of this Product Engineering Controls: Good general ventilation is adequate for normal use. When using large amounts, open windows or use a fan to ventilate the area. Personal Protection: Eye Protection: Avoid eye contact. Always spray product away from your face. Skin Protection: Avoid prolonged or repeated skin contact. Wash hands with soap and water after use. Respiratory Protection: None required. Use in a well-ventilated area. Page 2 of 4 Spot Shot Carpet and Stain Remover 5/25/05 For Bulk Processing or Workplace Use the Following Controls are Recommended Engineering Controls: A system of local and/or general exhaust is recommended to control airborne levels below the occupational exposure limits. Personal Protection: Eye Protection: Safety glasses with side shields or chemical goggles are recommended. Skin Protection: Wear appropriate protective clothing and chemical-resistant gloves to prevent skin contact. Wash thoroughly after handling. Respiratory Protection: Use in a well-ventilated area. Appropriate respiratory protection shall be worn when applied engineering controls are not adequate to protect against inhalation exposure. Work/Hygiene Practices: Eye wash facilities should be available. Wash hands before eating and smoking. Section 9 – Physical and Chemical Properties Vapor Pressure: Specific Gravity (Water = 1): Boiling Range: Solubility in water (20 C): Appearance and Odor: 55 psig @ 70 F (propellant) N/D 43 F – 343F (propellant) miscible Aerosol spray. Pleasant odor. Vapor Density (air = 1): >1 Evaporation Rate (Butyl Acetate = 1): % Volatiles by Volume: VOC’s lbs/gal: Coefficient of Water/Oil Distribution: Less than 1 N/D N/D N/D Section 10 – Stability and Reactivity Stability: Stable under normal storage conditions. Hazardous Polymerization: Will not occur Conditions to Avoid: Extreme heat, sources of ignition, physical damage to can. Incompatibilities: Avoid strong oxidizers, strong bases, acids and chlorinated solvents. Hazardous Decomposition Products: Burning can produce carbon monoxide and/or carbon dioxide and trace amounts of phosgene gas. Section 11 – Toxicological Information 2-Butoxyethanol Inhalation LC50 (ppm) 4-HR: 450 (RAT) Acute oral LD50 (mg/kg): 1,480 (RAT) Acute Dermal LD50 (kg/kg): 490 (RBT) Irritation, Skin, open, 500 mg: MILD (RBT) Irritation, Eye, 18 mg: SEVERE (RBT) Liquefied Petroleum Gas: No data is available Section 12 – Ecological Information This product is not expected to be harmful for the environment. Section13 Disposal Considerations Aerosol containers should not be punctured, compacted in home trash compactors or incinerated. Empty containers may be disposed of through normal waste management options. Dispose of all waste product, absorbents, and other materials in accordance with applicable Federal, state and local regulations. Section 14 – Transportation Information_ DOT Classification: Consumer Commodity ORM-D Page 3 of 4 Spot Shot Carpet and Stain Remover 5/25/05 Section 15 – Regulatory Information SARA 302: None found SARA 311/312 Hazard Categories: Immediate (acute), Chronic (delayed), Flammability SARA 313: Toxic Chemicals: 2-butoxyethanol 17% by wt. (glycol ether compound) OSHA: Hazardous under criteria of the OSHA Hazard Communication Standard (29 CFR 1910.1200) California Proposition 65: No components listed. Canadian Environmental Protection Act: All of the ingredients are listed on the Canadian Domestic Substances List. Canadian WHMIS Classification: Class D, Division 2, Subdivision B (Toxic material causing other chronic effects) This MSDS has been prepared according to the criteria of the Controlled Products Regulation (CPR) and the MSDS contains all of the information required by the CPR. Section 16 – Other Information__ HMIS Hazard Rating: Health – 2 (moderate hazard), Fire Hazard – 2 (moderate hazard), Reactivity – 1 (low hazard) Prepared By: Industrial Health & Safety Consultants, Inc. Revision Date: 05/25/2005 Supercedes: 02/18/05 This MSDS complies with OSHA guidelines set by 29 CFR 1910.1200 and the Canadian WHMIS regulations. The foregoing information has been compiled from sources believed to be accurate but is not warranted to be. Recipients are advised to confirm in advance of need that data is correct. Standards change without notice. It is the responsibility of the recipient to insure that their personnel have been notified of any changes which may affect them. The data provided on this MSDS are not meant to be used as specifications, only as guideline information as to the safe use of this product. User should refer to applicable laws before use. N/D = Not Determined N/E = Not Established N/A = Not Applicable Page 4 of 4 Material Safety Data Sheet DRAIN FLOW Inhibited Sulfuric Acid Conforms with OSHA form OMB No. 1218-0072 Roebic Laboratories, Inc. 25 Connair Road, PO Box 927 Orange, CT 06477 Emergency Telephone NumbersROEBIC (203) 795-1283 CHEMTREC (800) 424-9300 (Note: Emergency numbers are to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure, or accident) Date: 01/01/01 Preparer: Dave Lawler Packaging Lot No.: Stamped on carton top SECTION I – PRODUCT IDENTIFICATION Product Name Common Synonyms Chemical Family Formula CAS No. Precautionary Labeling US Precautionary Labeling International Labeling DRAIN FLOW Drain Opener, (Blended Sulfuric Acid) Sulfuric Acid H2S04 (Approx. 90%) 7664-93-9 (sulfuric acid) Health 3 Flammability 0 Reactivity 0 Contact 2 Do not get in eyes, on skin, or on clothing. Do not take internally. Avoid breathing mist or fumes. Keep separate from powdered metals, organics, combustible materials, solvents, oxidizers, alkalis, and amines. Keep out of reach of children. Do not get in eyes, on skin, or on clothing. Do not take internally. Avoid breathing mist or fumes. Keep separate from powdered metals, organics, combustible materials, solvents, oxidizers, alkalis, and amines. Keep out of reach of children. SECTION II – COMPONENTS Component Diluted Sulfuric Acid Fortifying Agents CAS No. Wt % 7664-93-9 80 N/A (none carcinogenic) OSHA/PEL N/A ACGIH/TLV 1-mg/m3 SECTION III – PHYSICAL DATA Boiling Point Freezing Point Specific Gravity Water Solubility pH Viscosity Odor Appearance 221°F 105C -20°F -10C 1.75 Complete 1.25 30 SSU @ 100F 32.7C Sulfur (sulfur trioxide fumes) Viscous Black Liquid (for safety identification) SECTION IV – FIRE, REACTIVITY, & EXPLOSION DATA Non-Flammable: Extinguishing Media: Fire Fighting Techniques: Toxic Gas Produced: Explosion Data: But explosive hydrogen gas can accumulate if transferred into metal containers. Use extinguishing media appropriate for surrounding fire. Wear full protective clothing including self-contained breathing apparatus with full-face piece operated in a positive pressure mode. Reaction with certain metals can produce flammable hydrogen gas. Provide adequat e ventilation when applying. No sensitivity to mechanical impact. No sensitivity to static discharge. 1 SECTION V – HEALTH HAZARD DATA Toxicity of Components Carcinogenic: None Identified Reproductive effect: None identified Effects of Overexposure Inhalation: Irritation of upper respiratory tract Skin Contact: Irritation Eye Contact: Irritation Ingestion: Internal irritation Emergency and First Aid Procedures Inhalation: Remove from contaminated atmosphere. Apply artificial respiration if necessary. Call a physician. Skin Contact: Flush with cool water, then baking soda solution. If irritation persists get medical attention. Ingestion: Give large quantities of water or milk. Do not induce vomiting. Do not drink carbonated water. Call a physician. Eye Contact: Immediately flush with large quantities of water. Call a physician. SECTION VI – REACTIVITY DATA Stability Conditions to Avoid Decomposition Stable Do not allow product to come in contact with strong alkalis. May cause eruption of hot acid when poured in drain. Do not mix with other household chemicals. Never add water to acid while in container because of violent reaction. When empty rinse thoroughly with water before discarding. Sulfur fumes SECTION VII – SPILLS AND DISPOSAL PROCEDURES Small Spill Large Spill Neutralize with sodium bicarbonate or soda ash and flush with large amounts of water. Pump to a soda ash and slack lime solution, then dispose of with large amounts of water. SECTION VIII – INDUSTRIAL PROTECTIVE EQUIPMENT Ventilation: Respiratory Protection: Eye and Skin Protection: Use general or local exhaust ventilation to meet TVL requirements and to minimize exposure. Respiratory protection is required if airborne concentrations exceed TLV. Above this level use NIOSH approved equipment with full-face piece. Follow respirator manufacturer’s recommendations. Safety goggles, protective clothing and rubber or plastic gloves are recommended. SECTION IX – STORAGE AND HANDLING PRECAUTIONS Storage Store in high-density polyethylene, rubber lined, fiber glass, or 316 stainless steel containers. Do not store in extreme heat or cold areas. Avoid contact with organic matter. DRAIN FLOW is a strong chemical digester of dead organics. SECTION X - TRANSPORTATION DATA AND ADDITIONAL INFORMATION Domestic (D.O.T.) Proper Shipping Name Hazard Class UN/NA Labels Frt. Classification Sulfuric Acid 66 Be (blended with buffing agents) Corrosive Material UN1830/NA Corrosive Cleaning Compound – Class 55 2 International (I.M.O.) Proper Shipping Name Hazard Class UN/NA Labels Marine Shipping Air Shipping Sulfuric Acid 66 Be (blended with buffing agents) Corrosive Material UN1830/NA Corrosive Non-pollutant Not allowed on passenger flights SECTION XI – OTHER COMMENTS This document is intended only as a guide. The user is responsible for determining the precautions and dangers of this chemical formulation for his/her particular application. Supplier cannot warn of all the potential dangers of use or interaction with other chemicals or materials, therefore; disclaims any warranties, expressed or implied with regard to its merchantability or its fitness for a particular purpose. The user is responsible for reading all precautionary information and handling accordingly. 3 Institutional 80240 JSDYL T MATERIAL SAFETY DATA SHEET I - PRODUCT IDENTIFICATION AND USE PRODUCT NAME: USE: MSDS ID: 80240 DISHWASHER ALL Machine Warewashing Detergent SUPPLIER: EMERGENCY PHONE: JohnsonDiversey Canada, Inc. 2401 Bristol Circle Oakville Ontario, L6H 6P1, Canada WHMIS CLASSIFICATION: CHEMICAL FAMILY: 1-800-668-7171 D2B TRADE NAME / SYNONYMS: Chlorinated alkali CHEMICAL NAME: not applicable not applicable II - HAZARDOUS INGREDIENTS HAZARDOUS INGREDIENT % w/w CAS # LD50 / LC50 Route / Species 30-60 000497-19-8 LD50 4090 mg/kg oral/rat Sodium carbonate Disodium dichlorosiocyanuratedihydrate Sodium metasilicate 1-5 051580-86-0 LD50 620 mg/kg oral/rat 7-13 006834-92-0 LD50 1153 mg/kg oral/rat 1-5 069227-21-0 LD50 3400 mg/kg oral/rat Linear alcohol ethoxylate/propoxylate III - HANDLING AND DISPOSAL PROCEDURES PERSONAL PROTECTIVE EQUIPMENT: Gloves: Nitrile, Neoprene or Natural rubber Respiratory: Eye: safety glasses NIOSH approved dust mask as required. SPECIAL HANDLING PROCEDURES AND EQUIPMENT: VENTILATION REQUIREMENTS: WASTE DISPOSAL: not required Other: not required Avoid breathing dust. Avoid eye and skin contact. General ventilation. INCOMPATIBILITY (Material to Avoid): SPILL PROCEDURES: Footwear: Strong acids Sweep or scoop up material for disposal. Dispose according to municipal, provincial, and federal regulations. STORAGE / SHIPPING REQUIREMENT: Store in a cool dry area in a closed container. IV - PHYSICAL PROPERTIES APPEARANCE / ODOUR: White, free-flowing powder with blue speckles - floral odour S.G. / BULK DENSITY(g/cc): 1.00 - 1.09 VAPOUR PRESSURE (mmHg): ODOUR THRESHOLD: FREEZING POINT: pH: not applicable VAPOUR DENSITY (air=1): 0.2-0.4 ppm chlorine BOILING POINT: not applicable SOLUBILITY IN WATER: (0.1% solution) 11.0 ± 0.5 PERCENT VOLATILE: soluble not applicable not applicable not applicable EVAPORATION RATE (water=1): not applicable V - TOXICOLOGICAL PROPERTIES EFFECTS OF ACUTE EXPOSURE TO MATERIAL: EYES: May cause severe irritation. May cause permanent damage if not treated promptly. SKIN: Repeated or prolonged contact may result in irritation. INGESTION: May cause severe irritation of the digestive tract. May cause temporary or permanent damage if not treated promptly. INHALATION: Breathing dust may cause respiratory irritation. JohnsonDiversey Material Safety Data Sheet: DISHWASHER ALL Page 1 of 2 Institutional 80240 LD50 (calculated): 4462 mg/kg OTHER TOXIC EFFECTS: LC50 (calculated): Not applicable TLV (Sodium metalsilicate): 2 mg/m3 EFFECTS OF CHRONIC EXPOSURE TO MATERIAL: None known. VI - FIRST AID MEASURES EYES: Flush eyes with plenty of water for at least 15 minutes. Hold eyelids open while rinsing. Contact a physician immediately. SKIN: Flush affected area thoroughly with water. If irritation develops, contact a physician. INGESTION: Drink large volumes of water . Never give anything by mouth to an unconscious patient. Do not induce vomiting. Contact a physician immediately. INHALATION: Remove patient to fresh air. Get medical attendion for any breathing difficulty. VII - FIRE AND EXPLOSION DATA FLAMMABLE: No. FLASH POINT, °C: not applicable EXTINGUISHING MEDIA: Water [x] AUTO IGNITION TEMPERATURE,°C: Dry Chemical [x] Carbon Dioxide [x] SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus. HAZARDOUS COMBUSTION PRODUCTS: Chlorine gas. Oxides of carbon, nitrogen. EXPLOSIVE SENSITIVITY TO: Foam [x] N/Ap Other [ ] not applicable VIII - REACTIVITY DATA STABILITY: Stable [x] CONDITIONS TO AVOID: Unstable [ ] not applicable INCOMPATIBILITY (Material to Avoid) : HAZARDOUS DECOMPOSITION PRODUCTS: REACTIVITY: Acids. Contact with acids generates chlorine gas. Chloramines. not dangerously reactive IX - MSDS PREPARATION SOURCES USED: PREPARATION DATE: RTECS, ChemInfo PREPARED BY: April 15, 2003 JohnsonDiversey Canada, Inc. Regulatory Department Institutional Division Phone (905) 829-1200 Information on this form is furnished in compliance with the Regulations respecting Controlled Products under the Hazardous Products Act and is not to be used for any other purpose, nor is it to be reproduced or published. JohnsonDiversey Canada assumes no responsibility for injury to any person or property resulting from any use of the material if reasonable safety procedures are not adhered to. In addition, JohnsonDiversey Canada assumes no responsibility for injury to any person or property resulting from any abnormal use or theft of the material, even if reasonable safety procedures are followed. Each user assumes the risk in his use of the material and should review the data and recommendations in the specific context of the intended use. JohnsonDiversey Material Safety Data Sheet: DISHWASHER ALL Page 2 of 2 Industrial ______________________________________________________________________________ MATERIAL __________________________ SAFETY DATA SHEET Page 1 of 3 Revised 2/02/04 WHITE LOTION HAND SOAP Replaces 8/12/03 Printed 2/03/04 MSDS ______________________________________________________________________________ ID: 04617 ______________________________________________________________________________ ______________________________________________________________________________ I. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Product Discriptor: MANUFACTURER: JOHNSONDIVERSEY, INC. 3630 E. KEMPER ROAD CINCINNATI, OH. 45241 EMERGENCY PHONE NUMBER:(800)851-7145 ______________________________________________________________________________ ______________________________________________________________________________ II. HAZARDOUS COMPONENTS Component Name CAS Number % Exposure Limits Units ----------------------------- ----------- ---------- ---------------- ------WHITE LOTION HAND SOAP >30% None established ______________________________________________________________________________ ______________________________________________________________________________ III. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: SIGNS AND SYMPTOMS OF OVEREXPOSURE ACUTE: MAY IRRITATE EYES CHRONIC: SAME AS ACUTE MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Sensitive skin ______________________________________________________________________________ ______________________________________________________________________________ IV. FIRST AID MEASURES ______________________________________________________________________________ ______________________________________________________________________________ V. FIRE FIGHTING MEASURES FLASH POINT (degrees F): NONE FLAME EXTENSION: N/A FLAMMABLE LIMITS IN AIR BY VOLUME: LEL: N/A UEL: N/A EXTINGUISHING MEDIA: CO2, FOAM, DRY CHEMICALS FIRE FIGHTING INSTRUCTIONS: Wear full protective gear and positive pressure breathing apparatus (SCBA) in fire area. ______________________________________________________________________________ ______________________________________________________________________________ VI. ACCIDENTAL RELEASE MEASURES IF MATERIAL IS RELEASED OR SPILLED: FLUSH TO DRAIN AND RINSE TO AVOID SLIPPERY CONDITIONS This product does not contain a reportable quantity (RQ) under CERCLA. ______________________________________________________________________________ ______________________________________________________________________________ VII. HANDLING AND STORAGE HANDLING AND STORAGE PRECAUTIONS: DO NOT SPILL. WILL CAUSE A SLICK WORKING SURFACE. KEEP FROM FREEZING. IF FROZEN, THAW AND MIX TO MAKE USABLE. DO NOT PRESSURE CONTAINER TO EMPTY. Industrial ______________________________________________________________________________ MATERIAL __________________________ SAFETY DATA SHEET Page 2 of 3 Revised 2/02/04 WHITE LOTION HAND SOAP Replaces 8/12/03 Printed 2/03/04 MSDS ______________________________________________________________________________ ID: 04617 ______________________________________________________________________________ ______________________________________________________________________________ VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION EYE/FACE PROTECTION: NONE PROTECTIVE GLOVES: NONE OTHER PROTECTIVE CLOTHING/EQUIPMENT: NONE ENGINEERING CONTROLS: MECHANICAL VENTILATION: PRODUCING NORMAL AIR DILUTION LOCAL VENTILATION: NO ______________________________________________________________________________ ______________________________________________________________________________ IX. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE AND ODOR: BOILING POINT (DEG F): 212 FREEZING POINT: Not determined SPECIFIC GRAVITY/BULK DENSITY: pH: pH 1% SOLUTION: Not Determined VOLATILE BY VOLUME: 80 VAPOR PRESSURE(mmHg): 17.5 at 20 F VAPOR DENSITY: N/A ______________________________________________________________________________ ______________________________________________________________________________ X. STABILITY AND REACTIVITY CHEMICAL STABILITY: STABLE INCOMPATIBILITY WITH OTHER MATERIALS: CO WITH INCOMPLETE COMBUSTION HAZARDOUS DECOMPOSITION PRODUCTS: None known. HAZARDOUS POLYMERIZATION: NONE ______________________________________________________________________________ ______________________________________________________________________________ XI. TOXICOLOGICAL INFORMATION No data available. TOXICITY TEST DATA: No data available. ______________________________________________________________________________ ______________________________________________________________________________ XII. ECOLOGICAL INFORMATION ECOTOXICITY TEST DATA: No data available. ENVIRONMENTAL FATE: No data available. ______________________________________________________________________________ ______________________________________________________________________________ XIII. DISPOSAL CONSIDERATIONS RCRA REGULATED: Not Regulated. POUR OR FLUSH DOWN DRAIN OR LAND FILL. CONTAINS NO PHOSPHATES, 100% BIODEGRADABLE. USE UNTIL LESS THAN 1 INCH REMAINS IN CONTAINER, EMPTY CONTAINER TRIPLE RINSE WITH WATER, ADD TO OPERATION REMOVE OR DEFACE LABEL BEFORE SELLING CONTAINER OR DISPOSAL ______________________________________________________________________________ ______________________________________________________________________________ XIV. TRANSPORT INFORMATION Please refer to the Bill of Lading/receiving documents for up to date shipping information. Industrial ______________________________________________________________________________ MATERIAL __________________________ SAFETY DATA SHEET Page 3 of 3 Revised 2/02/04 WHITE LOTION HAND SOAP Replaces 8/12/03 Printed 2/03/04 MSDS ______________________________________________________________________________ ID: 04617 ______________________________________________________________________________ ______________________________________________________________________________ XV. REGULATORY INFORMATION U.S. Federal Regulations: TSCA: All ingredients in this product are on TSCA inventory. HAPS: Contains no hazardous air pollutants. VOC CONTENT (EPA Method 24A): % VOC: Lb/Gal VOC: CERCLA/EPCRA: Section 313 Toxic Chemicals: None SARA Section 311/312: ACUTE:NO CHRONIC:NO FIRE:NO REACTIVITY:NO SUDDEN RELEASE OF PRESSURE:NO LISTED CARCINOGEN: NONE NTP: NO IARC: NO OSHA: NO HMIS RATINGS: HEALTH: FIRE: REACTIVITY: PERSONAL PROTECTIVE EQUIPMENT: NFPA RATING: HEALTH: FIRE: REACTIVITY: SPECIAL: STATE RIGHT-TO-KNOW INFORMATION: CALIFORNIA PROPOSITION 65: None of the ingredients are on the California proposition 65 list. ______________________________________________________________________________ ______________________________________________________________________________ XVI. OTHER INFORMATION DISCLAIMER: The information contained in this material safety data sheet is based on the knowledge of this specific product and current national legislation. It applies to the product as sold, use dilutions may be less hazardous. It may not be valid for this material if used in combination with any other materials or in a process. It is the user's responsibility to evaluate the handling, and use. MATERIAL SAFETY DATA SHEET Effective Date: 08/06 (Prepared According To 29 CFR 1910.1200) N/A = Not Applicable SECTION 1 - PRODUCT IDENTIFICATION Product Name: North Woods™ Natures Stuff Chemical Family: N/A Generic Name: Citrus Hand Cleaner Formula: N/A Suppliers Name: SUPERIOR CHEMICAL CORP. Suppliers Address: 1331 Wisconsin Avenue, Sheboygan, WI 53081 Phone: 800-242-7694 EMERGENCY PHONE: 800-535-5053 NPCA Hazardous Materials Identification System Health 0 Flammability 1 Reactivity 0 Maximum Personal Protection A SECTION 2 - HAZARDOUS INGREDIENTS CHEMICAL NAME CAS NO. WT.% PEL TWA-TLV STEL-TLV CARCINOGEN No hazardous ingredients. SECTION 3 - PHYSICAL DATA Specific Gravity: 0.963 Boiling Range (˚F): 175°F Vapor Density: <1.0 Vapor Pressure: N/D pH: 6.8 - 7.4 % Volatile: N / A Evaporation Rate: >1.0 Solubility in Water: Soluble Physical Description: Yellow, opaque liquid; pleasant citrus fragrance. SECTION 5 - REACTIVITY DATA SECTION 4 - FIRE & EXPLOSION HAZARD DATA Flash Point (method used): N / A Upper Explosive Limit: N/A Lower Explosive Limit: N/A Extinguishing Media: Foam, carbon dioxide, dry chemical. Special Fire Fighting Procedures: Self contained breathing apparatus. Unusual Fire & Explosion Hazards: Cool fire exposed containers with water spray. SECTION 6 - STORAGE & HANDLING INFO Hazardous Polymerization: Will not occur. Stability: Stable Precautions To Be Taken In Handling & Storage: Incompatibility (materials to avoid): Strong acids and oxidizing agents. Keep out of reach of children. For institutional and industrial use only. Store in a cool, dry place, away from heat or open flame. Keep continer slightly closed when not in use. Hazardous Decomposition Products: Thermal decomposition may yield oxides of carbon. SECTION 7 - HEALTH HAZARDS AND FIRST AID Effects of Overexposure Primary Route of Entry: Skin: Irritation. First Aid Procedures: Skin: Wash with soap and water. If irritation persists, obtain medical attention. Eyes: Severe irritation, redness and tearing. Eyes: Flush eyes and under eyelids with plenty of cool water for at least 15 minutes. Obtain medical attention if irritation persists. Inhalation: None under normal use. Inhalation: Remove person to fresh air. Ingestion: Gastrointestinal irritation, nausea, vomiting, diarrhea. Ingestion: Contact physician or poison center immediately. DO NOT INDUCE VOMITING. Never give anything by mouth to an unconscious person. SECTION 8 - SPECIAL PROTECTION INFORMATION Respiratory Protection: Use adequate ventilation. Ventilation: General ventilation should be sufficient for most conditions. Local exhaust ventilation may be necessary for some operations. Protective Gloves: Not required. Other Protective Equipment: None. Eyes: None. SECTION 9 - SPILL OR LEAK PROCEDURES Steps to be taken in case material is released or spilled: Mop up or otherwise absorb and hold material for disposal. Waste disposal method: Any method in accordance with applicable laws. Notice to reader: To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. MATERIAL SAFETY DATA SHEET SECTION I – MATERIAL IDENTIFICATION AND USE MATERIAL NAME: SUPER STRENGTH BOWL CLEANER 4521-253 4521-253 900mL MANUFACTURERS NAME: CP INDUSTRIES LTD. 225 BLACK STREET FERGUS, ONTARIO N1M 1A5 SUPPLIERS NAME: HOME HARDWARE 34 HENRY STREET WEST ST JACOBS, ONTARIO N0B 2N0 EMERGENCY TELEPHONE NUMBER: (613) 996-6666 EMERGENCY TELEPHONE NUMBER: (613) 996-6666 Non-Office Hours, Weekends, or Holidays – (CANUTEC) Call Collect Non-Office Hours, Weekends, or Holidays – (CANUTEC) Call Collect CHEMICAL NAME Not Applicable (mixture) MOLECULAR WEIGHT Not Applicable CHEMICAL FAMILY Mineral Acid TRADE NAME AND SYNONYMS Not Available CHEMICAL FORMULA Not Applicable MATERIAL USE WHMIS CLASS Toilet Bowl Cleaner E D1A SECTION II – HAZARDOUS INGREDIENTS OF MATERIAL HAZARDOUS INGREDIENTS Hydrogen Chloride APPROXIMATE CONCENTRATION % 10 - 20 C.A.S.N.A. “EXPOSURE LIMITS” LD50 / LC50 SPECIFY SPECIES & ROUTE 007647-01-0 TLV (ACGIH) 5 ppm Ceiling Hydrochloric Acid: LD50 Not Determined LC50 3124 ppm for 1 hour (inhalation/rat) SECTION III – PHYSICAL DATA FOR MATERIAL PHYSICAL STATE GAS LIQUID X SOLID ODOUR AND APPEARANCE ODOUR THRESHOLD Clear dark blue liquid, slight pungent odour Not Available SPECIFIC GRAVITY 1.08 VAPOUR PRESSURE (mm) Not Available VAPOUR DENSITY (Air=1) Not Available BOILING POINT (°C) Not Available EVAPORATION RATE Not Available FREEZING POINT (°C) SOLUBILITY IN WATER -10°C approx. Infinite COEFFICIENT OF WATER/OIL DISTRIBUTION: Not Available % VOLATILE (by volume) 99% (approx.) pH Strong acid less than 1 SECTION IV – FIRE AND EXPLOSION DATA FLAMMABILITY YES NO X IF YES, UNDER WHAT CONDITIONS MEANS OF EXTINCTION: None Required. Not Flammable. SPECIAL PROCEDURES: Hydrochloric acid itself is non-flammable. There is, however, a latent fire or explosion hazard due to hydrogen gas generated when acid is in contact with metals. Wear full protective equipment including self contained breathing apparatus. FLASH POINT (°C) AND METHOD: None AUTO IGNITION TEMPERATURE (°C): Not Applicable UPPER EXPLOSION LIMIT (% BY VOLUME): Not Applicable LOWER EXPLOSION LIMIT (% BY VOLUME): Not Applicable HAZARDOUS COMBUSTION PRODUCTS: Toxic and Corrosive HCL Gas may be released. EXPLOSION DATA SENSITIVITY TO MECHANICAL IMPACT: Not Applicable RATE OF BURNING Not Applicable EXPLOSIVE POWER Not Applicable SENSITIVITY TO STATIC DISCHARGE Not Applicable SECTION V – REACTIVITY DATA CHEMICAL STABILITY IF NO, UNDER WHAT CONDITIONS? YES X NO INCOMPATIBILITY TO OTHER SUBSTANCES IF SO, WHICH ONES? YES X NO REACTIVITY AND UNDER WHAT CONDITIONS: Contact with alkalis will generate heat. Contact with most metals will generate hydrogen gas. Contact with oxidizing chlorinated materials will generate toxic chlorine gas. HAZARDOUS DECOMPOSITION PRODUCTS: See above MATERIAL NAME: SUPER STRENGTH BOWL CLEANER SECTION VI – TOXICOLOGICAL PROPERTIES OF PRODUCT ROUTE OF ENTRY SKIN CONTACT: X SKIN ABSORPTION: EYE CONTACT: X INHALATION ACUTE: X INHALATION CHRONIC: X INGESTION: X EFFECTS OF ACUTE EXPOSURE TO PRODUCT EYE: CORROSIVE. Contact may cause pain, lachrymation (tears), and severe irritation with corneal injury, may even cause blindness. SKIN: CORROSIVE. Short single skin exposure may cause burns. INHALATION: CORROSIVE. Excessive vapour concentrations inhaled may cause serious adverse effects, even death. INGESTION: CORROSIVE. May cause burns of the mouth and throat and gastro intestinal irritation and ulceration. EFFECTS OF CHRONIC EXPOSURE TO PRODUCT: Repeated excessive exposure may cause erosion of teeth and bleeding and ulceration of nose, mouth and gums. LD50 OF PRODUCT (SPECIFY SPECIES & ROUTE) IRRITANCY OF PRODUCT EXPOSURE LIMITS OF PRODUCT Not Determined High ACGIH TLV 5 ppm Ceiling LC50 OF PRODUCT (SPECIFY SPECIES) Hydrochloric Acid: 3124 ppm for 1 hr (inhal/rat) CARCINOGENICITY Not Applicable SENSITIZATION TO PRODUCT Not Available REPRODUCTIVE EFFECTS Not Available SYNERGISTIC MATERIALS None Known TERATOGENICITY Not Available MUTAGENICITY Not Available SECTION VII – PREVENTATIVE MEASURES PERSONAL PROTECTIVE EQUIPMENT GLOVES RESPIRATORY (SPECIFY) Neoprene, Rubber or PVC Approved air purity respirator if exposure guidelines or comfort levels may be exceeded. EYE (SPECIFY) Chemical Goggles FOOTWEAR (SPECIFY) Rubber Boots OTHER (SPECIFY) Not Applicable CLOTHING (SPECIFY) Apron ENGINEERING CONTROLS (E.G. VENTILATION, ENCLOSED PROCESS, (SPECIFY): Local mechanical exhaust ventilation to control airborne contamination below exposure levels. LEAK AND SPILL PROCEDURE: Ventilated area. Do not allow spilled material to go to drain. Contain leak or spill, soak up with sand, ashes, or gravel. Dispose of into covered polyethylene containers. WASTE DISPOSAL: Dispose of according to local, provincial, and federal regulations. HANDLING PROCEDURES & EQUIPMENT: Use only with adequate ventilation. Avoid eye and skin contact. Avoid breathing vapours. STORAGE REQUIREMENTS: Store in a cool, dry place in a closed container away from heat, metals and oxidizers. SPECIAL SHIPPING INFORMATION: Not Applicable. SECTION VIII – FIRST AID PROCEDURES SKIN: Immediate, continued and thorough washing in flowing water for 30 minutes, is imperative while removing contaminated clothing. Seek medical attention immediately. EYE: Immediate and continuous irrigation with flowing water for at least 30 minutes is imperative. Prompt medical attention is essential. INHALATION: Remove patient to fresh air if effects occur. Seek medical attention immediately. INGESTION: DO NOT induce vomiting. Give large amounts of water or milk if available and transport to medical facility immediately. GENERAL ADVICE: Safety shower and eyewash must be readily available. CORROSIVE. May cause stricture. If lavage is performed, suggest endotracheal and esophagoscopic control if burn is present, treat as any thermal burn after decontamination. SECTION IX – PREPARATION DATE OF MSDS ADDITIONAL INFORMATION/COMMENTS: None SOURCES USED: Supplier MSDS PREPARED BY: CP INDUSTRIES LTD. PHONE NUMBER: (519) 843-6300 DEVELOPMENT DEPT. INSTITUTIONAL DIVISION DATE: MARCH 24, 2004 MATERIAL SAFETY DATA SHEET SECTION I - PRODUCT IDENTIFICATION AND USE Product Identifier: CLING TYPE BOWL CLEANER Product Use: HEAVY DUTY BOWL CLEANER FOR USE ON PORCELAIN, PLASTIC TILE, FIBREGLASS, VITREOUS CHINA AND STAINLESS STEEL. Supplier: SHARE CANADA Address: 1691 CHURCH AVENUE, WINNIPEG, MANITOBA R2X 2Y7 Telephone Number: (204) 633-8553 Fax: (204) 633-8453 CANUTEC: (613) 996-6666 SECTION II - HAZARDOUS INGREDIENTS Hazardous ingredients PHOSPHORIC ACID CAS Number 7664-38-2 Exposure limits 1 mg / m 3 Weight % 10 30 % LD 50 LC50 1530 mg /kg (rat/ oral) 2740 mg /kg (rabbit/ dermal) SECTION III- PHYSICAL DATA Physical State: Specific Gravity (20oC): Odour and appearance: LIQUID 1.1 TRANSLUSCENT TO OPAQUE GREEN LIQUID, WINTERGREEN ODOUR. Odour threshold: Not available. pH: 1.2 Vapour pressure (mm Hg): 2.3 kPa @ 20oC. Vapour density (air = 1): 1 Evaporation rate (water = 1): 1 % volatile by volume: Not available. Solubility in water: EASILY SOLUBLE IN COLD WATER. Boiling point (Co): 102 o C. Freezing point (Co): Not available. Coefficient of oil/water distribution: Not available. SECTION IV - FIRE AND EXPLOSION DATA Flammable or combustible: Not flammable or combustible. Flash point (Co): NONE Conditions of flammability: NONE Upper flammable limit: Not applicable. Lower flammable limit: Not applicable. Autoignition temperature: Not applicable. Flammability classification: NONE Special fire fighting procedures: SPRAY WATER TO COOL CONTAINERS AND CONTROL VAPOURS. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID BREATHING FUMES. Means of extinction: SMALL FIRE USE DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR FOAM, LARGE FIRE USE WATER SPRAY, FOG OR FOAM. DO NOT USE WATER JET. Hazardous combustion products: PHOSPHATES AND CARBON OXIDES. Sensitivity to mechanical impact: Not sensitive. Sensitivity to static discharge: Not sensitive. SECTION V - REACTIVITY DATA Is the product stable? STABLE Conditions of reactivity: DO NOT MIX WITH OTHER CLEANING PRODUCTS. Incompatible substances: HIGHLY REACTIVE WITH ALKALIS. SLIGHTLY REACTIVE WITH ORGANIC MATERIALS. NON-REACTIVE WITH OXIDIZING AGENTS, ACIDS. Hazardous decomposition products: PHOSPHATES AND CARBON OXIDES. Not found. . Product Identifier: CLING TYPE BOWL CLEANER SECTION VI - TOXICOLOGICAL PROPERTIES WHMIS CLASSIFICATION: CLASS D2B, E - CORROSIVE MATERIAL Primary routes of exposure: SKIN AND EYE CONTACTAND INGESTION. Exposure limits: SEE SECTION II FOR LIMITS FOR INGREDIENTS. Acute effects of exposure: DANGEROUS IN CASE OF SKIN CONTACT (CORROSIVE, IRRITANT), OF EYE CONTACT (IRRITANT), OF INGESTION, OF INHALATION. LIQUID OR SPRAY MIST MAY PRODUCE TISSUE DAMAGE PARTICULARLY ON MUCOUS MEMBRANES OF EYES, MOUTH AND RESPIRATORY TRACT. Chronic effects of exposure: REPEATED EXPOSURE MAY CAUSE CHRONIC EYE, SKIN AND RESPIRATORY TRACT IRRITATION. Sensitizer: NOT KNOWN TO BE A SENSITIZER. Carcinogen: NOT LISTED - IARC, NTP, OSHA Mutagen: NOT KNOWN AS A MUTAGEN. SECTION VII - PREVENTION MEASURES Gloves: IMPERVIOUS GLOVES Respirator: IF VENTILATION IS INSUFFICIENT, WEAR SUITABLE RESPIRATORY EQUIPMENT. Eye protection: SPLASH GOGGLES, FACE`SHIELD. Footwear: RUBBER BOOTS Clothing: PROTECTIVE CLOTHING TO PREVENT SKIN CONTACT. Other: EYE WASH STATION AND SAFETY SHOWER. Engineering controls: PROVIDE EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATIONS OF VAPOURS BELOW TLV. Leak and spill procedures: ABSORB WITH INERT DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE DISPOSAL CONTAINER. Waste disposal: DISPOSE ACCORDING TO FEDERAL, PROVINCIAL OR LOCAL REGULATIONS. CONSULT LOCAL OR REGIONAL AUTHORITIES. Handling and storage requirements: KEEP LOCKED UP, KEEP CONTAINER TIGHTLY CLOSED AND DRY. KEEP AWAY FROM HEAT, METALS AND OXIDIZING MATERIALS AND SOURCES OF IGNITION. STRONG ACIDS THAT ARE NOT STRONG OXIDANTS SHOULD BE STORED IN A SEPARATE SAFETY STORAGE CABINET OR ROOM. KEEP LOCKED UP AND OUT OF THE REACH OF CHILDREN. KEEP CONTAINER DRY. DO NOT BREATHE GAS, FUMES, VAPOUR OR SPRAY. AVOID CONTACT WITH SKIN AND EYES. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. KEEP OUT OF THE REACH OF CHILDREN. Special shipping information: T.D.G CLASS 8 PHOSPHORIC ACID, LIQUID. UN 1805, PACKING GROUP III. LIMITED QUANTITY IN CONTAINERS UP TO 5 LITRES. SECTION VIII - FIRST AID MEASURES Eye contact: IMMEDIATELY FLUSH EYES AND UNDER EYELIDS WITH PLENTY OF COOL WATER FOR 15 MINUTES HOLDING THE EYELIDS OPEN. GET MEDICAL ATTENTION. Skin contact: WASH SKIN WITH PLENTY OF COOL WATER AND NON-ABRASIVE SOAP AND COVER WITH AN EMOLIENT. IF IRRITATION PERSISTS GET MEDICAL ATTENTION. Ingestion: CONTACT PHYSICIAN OR POISON CONTROL CENTRE IMMEDIATELY. DO NOT INDUCE VOMITING. RINSE MOUTH THOROUGHLY. GIVE CONSCIOUS PERSON SEVERAL GLASSES OF WATER OR MILK. Inhalation: ALLOW THE VICTIM TO REST IN A WELL-VENTILATED AREA. SEEK IMMEDIATE MEDICAL ATTENTION. SECTION IX - PREPARATION DATA Information sources: Prepared by: Telephone Number: Preparation Date: MANUFACTURER S MSDS, CCOHS CCINFO SHARE CANADA (204) 633-8553 September 2, 2005 MATERIAL SAFETY DATA SHEET Atlantic Chemical Equipment Co. 2190 DeFoor Hills Rd NW Atlanta, GA 30318 404-355-5522 PRODUCT NAME: ODOR NEUTRALIZER (ON & ONjr) EMERGENCY PHONE: 1-800-424-9300 VII - PRECAUTIONS FOR SAFE HANDLING AND USE May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200. Standard must be consulted for specific requirements. This product contains no substances subject to SARA TITLE III and 40 CRF. HMIS SYMBOLS HEALTH 1 FLAMMABILITY 1 REACTIVITY 0 STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED: SMALL SPILLS: Sweep up material and shovel into waste container. LARGE SPILLS: Contain and collect for reuse. WASTE DISPOSAL METHOD: Deposit in landfill in accordance with local, State, and Federal regulations. 1 - IDENTIFICATION VIII - SPECIAL PROTECTION INFORMATION PRODUCT NAME: (ON) Odor Neutralizer PACKAGE TYPE: pint, quart, gallon PREPARED DEPARTMENT OF HAZARDOUS COMMUNICATIONS DATE PREPARED: June 2003 RESPIRATORY: Needed in misty conditions. Use approved NIOSH organic vapor HEPA respirator. EYE: Wear chemical splash goggles. II - HAZARDOUS INGREDIENTS PRINCIPLE HAZARDOUS COMPONENT(S) (CHEMICAL NAMES) 2 - hydroxybenzoic acid methyl ester CAS NO ACGIH TLV OSHA 119-36-8 N/E PEL % or RANGE SKIN: Prevent all possible contact. Use impervious apron, boots, goggles. PROTECTIVE GLOVES: PVC or rubber <37% OTHER: DO not eat, drink, or smoke in work area. Wash hands before eating. VENTILATION REQUIREMENTS: Local exhaust adequate IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep containers closed when not in use. III - PHYSICAL DATA BOILING POINT ( 0F) : N/A VAPOR PRESSURE (mm Hg) : N/A MELTING POINT : N/E VAPOR DENSITY (Air = 1) : Heavier EVAPORATION RATE (H20 = 1) : <1 pH : NA APPEARANCE AND ODOR : Dark brown granules - wintergreen odor SPECIFIC GRAVITY (H20= 1) : N/A SPECIAL PRECAUTIONARY STATEMENTS: Keep this and all chemicals out of reach of children. SOLUBILITY IN WATER : Not Soluble IV - FIRE AND EXPLOSION HAZARD DATA NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of merchantability fitness or otherwise is made. FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Flash point 2140F SARA Title III Reporting Requirements SPECIAL FIRE FIGHTING PROCEDURES: Wear impervious clothing and SCBA; dike spills to prevent runoff UNUSUAL FIRE AND EXPLOSION HAZARDS: Products of decomposition include carbon monoxide and low molecular weight hydro carbons V - REACTIVITY DATA CHEMICAL STABILITY UNSTABLE 302 (Extremely Hazardous Substances): Reporting not required. 304/CERCLA (Spills Notification): Not required. 311 Community Right-To-Know, RTK): Reporting not required. 312 (RTK Inventory Data): Reporting required above TPQ. CONDITIONS TO AVOID: X STABLE INCOMPATIBILITY (Materials to avoid): Oxidizing agents, heat, sparks, open flame, bases HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO2 HAZARDOUS POLYMERIZATION MAY OCCUR CONDITIONS TO AVOID: WILL NOT OCCUR X VI - HEALTH HAZARD AREA ROUTE(S) OF ENTRY: EYES Yes SKIN Yes INGESTION Yes 313 (Emissions and Releases): Reporting not required. DOT NOT HAZARDOUS INHALATION Yes References EFFECTS OF OVER EXPOSURE: Irritant INHALATION: May irritate sensitive persons TOXIC SUBSTANCE CONTROL CT LIST (TSCA) - INGREDIENTS LISTED SKIN CONTACT/ABSORPTION: Irritation PERMISSIBLE EXPOSURE REFERENCES: Registry of Toxic Effects of Chemical Substances. INGESTION: Toxic if ingested Title 29 Code of Federal Regulations. National Toxicology Program (NTP) Report on Carcinogens. EYES: Eye irritant CARCINOGENICITY: NTP? Not listed IARC MONOGRAPHS? Not listed OSHA REGULATED? Not listed EMERGENCY AND FIRST AID PROCEDURES: EYES AND SKIN: EYES - wash eyes with plenty of water. GET MEDICAL ATTENTION IMMEDIATELY. SKIN - Rinse skin with plenty of water and soap. Get medical help if nauseated, treat as ingested products INHALATION: Remove to fresh air. GET IMMEDIATE MEDICAL ATTENTION, if symptoms persist. INGESTION: Immediately induce vomiting. GET IMMEDIATE MEDICAL ATTENTION. Call poison control center. Treat for salicylate poisons. International Agency for Research on Cancer (IARC) Monographs. Title 40 Code of Federal Regulations REGULATORY STANDARDS: DOT Title 49 Code of Federal Regulations 172.101 SARA Title III Nuclear Regulatory Commission 1 MATERIAL SAFETY DATA SHEET SECTION I - PRODUCT IDENTIFICATION AND USE Product Identifier: ODOUR NEUTRALIZER Product Use: WATER BASED DEODERANT FOR USE AS AN ODOUR NEUTRALIZER. Supplier: Address: SHARE CANADA 1691 CHURCH AVENUE, WINNIPEG, MANITOBA R2X 2Y7 Telephone Number: (204) 633-8553 Fax: (204) 633-8453 CANUTEC: (613) 996-6666 SECTION II - HAZARDOUS INGREDIENTS Ingredient CAS Number Weight % LD 50 LC 50 Isopropanol 67-63-0 5 5840 mg/kg oral /rat 16,000 ppm rat, 2 hr 10 % SECTION III - PHYSICAL DATA Physical State: LIQUID Specific gravity: 0.995 pH: Not available. Odour and appearance: CLEAR, LIGHT YELLOW LIQUID. FLORAL FRAGRANCE. Odour threshold: Not available. Vapour pressure (PSI): Not available. Vapour density (air = 1): Not available. Evaporation rate (water = 1): Not available. % volatile by volume: 1-10 Solubility in water: SOLUBLE. 0 0 Boiling Point ( C ): Not available. Freezing Point ( C ): Not available. Coefficient of water/oil distribution: Not available. SECTION IV - FIRE AND EXPLOSION DATA Flammable or combustible: COMBUSTIBLE 0 Flash point and method: 42 C CLOSED CUP Upper flammable limit: Not Available. Lower flammable limit: Not Available. Autoignition temperature: Not Available. Flammability classification: COMBUSTIBLE LIQUID. Conditions of flammability: EXPOSURE TO HEAT OR OPEN FLAME. Means of extinction: WATER, FOAM, CARBON DIOXIDE, DRY CHEMICAL. Special fire fighting procedures: COOL FIRE-EXPOSED CONTAINERS WITH WATER FOG. FIREFIGHTERS SHOULD BE EQUIPPED WITH FULL PROTECTIVE GEAR, INCLUDING SELFCONTAINED BREATHING APPARATUS. Hazardous combustion products: OXIDES OF CARBON. Sensitivity to mechanical impact: NOT SENSITIVE Sensitivity to static discharge: NOT SENSITIVE SECTION V - REACTIVITY DATA Is the product stable: Incompatible substances: Conditions of Reactivity: Hazardous decomposition products: CARBON. YES- STABLE. OXIDIZERS NONE THERMAL DECOMPOSITION MAY PRODUCE OXIDES OF Product identifier: ODOUR NEUTRALIZER SECTION VI - TOXICOLOGICAL PROPERTIES Primary routes of exposure: SKIN AND EYE CONTACT, INHALATION, INGESTION. Exposure Limits: ACGIH -TLV: ISOPROPANOL TLV-TWA 400 ppm TLV STEL 500 ppm WHMIS CLASS: B- 3 COMBUSTIBLE LIQUID, D 2B OTHER TOXIC EFFECTS (EYE IRRITANT). Irritant: YES Carcinogen: NO - IARC / OSHA / NTP Sensitizer: NO Mutagen: NO Reproductive effects: NONE KNOWN Synergistic products: NONE KNOWN Effects of acute exposure: Eyes: MILD IRRITATION AND REDNESS. Ingestion: GASTROINTESTINAL IRRITATION, NAUSEA, CRAMPS AND VOMITING. ASPIRATION MAY BE A HAZARD. Skin: REDNESS, DRYNESS AND IRRITATION WITH PROLONGED AND REPEATED EXPOSURE. Inhaled: MOVE TO FRESH AIR. IF IRRITATION PERSISTS OBTAIN MEDICAL ATTENTION. SECTION VII - PREVENTION MEASURES Gloves: CHEMICAL RESISTANT GLOVES Respirator: USE WITH ADEQUATE VENTILATION. Eye protection: SAFETY GLASSES OR CHEMICAL GOGGLES Footwear: NO SPECIAL REQUIREMENTS. Clothing: NO SPECIAL REQUIREMENTS. Other requirements: EYE WASH STATION Engineering Controls: NO SPECIAL VENTILATION REQUIRED. Respiratory protection: USE WITH ADEQUATE VENTILATION. Leak or spill procedures: VENTILATE AREA AND EXTINGUISH ALL SOURCES OF IGNITION. SOAK UP ON INERT ABSORBENT MATERIAL AND PLACE IN A PROPERLY MARKED CLOSED CONTAINER FOR PROPER DISPOSAL. Waste disposal: CONSULT LOCAL ENVIRONMENTAL AUTHORITIES. Handling and storage requirements: STORE IN A COOL, DRY PLACE. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. KEEP OUT OF THE REACH OF CHILDREN. Special shipping information: NOT REGULATED BY TDG. SECTION VIII - FIRST AID MEASURES Eyes: FLUSH EYES AND UNDER EYELIDS FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS, OBTAIN MEDICAL ATTENTION. Skin: WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, OBTAIN MEDICAL ATTENTION. Ingestion: CONTACT PHYSICIAN OR POISON CONTROL CENTRE IMMEDIATELY. RINSE MOUTH WITH WATER ANG GIVE PERSON 1 OR 2 GLASSES OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. Inhalation: MOVE TO FRESH AIR. IF IRRITATION PERSISTS, OBTAIN MEDICAL ATTENTION. SECTION IX - PREPARATION DATA Information Sources: Prepared by: Telephone: Preparation date: SUPPLIERS' MATERIAL SAFETY DATA SHEET, CCOSH - CHEMINFO SHARE CANADA 1-204-633-8553 March 11, 2005 U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET (Prepared According to 29 CFR 1910.1200) ______________________________________________________________________________ SECTION 1 IDENTIFICATION Product Name: Manufacturer's Name: Manufacturer's Address: Manufacturer's Phone Number: Emergency Phone Number: Proper Shipping Name: Effective Date: FORMULA 491705 MANGO ZENEX International 7777 First Place, Cleveland Ohio 44146 (440) 232-4155 1-800-535-5053 Consumer Commodity, ORM-D 10-15-01 ______________________________________________________________________________ SECTION 2 IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS Chemical Name: Acetone Propane Isobutane n-Butane Fragrance CAS No.: 67-64-1 74-98-6 75-28-5 106-97-8 Not available TLV: 500ppm 2500ppm Not established 800ppm Not available ______________________________________________________________________________ SECTION 3 Boiling Point: Solubility in Water: Physical Description: PHYSICAL DATA <0 to 1330 F Slightly Clear/mango scent Specific Gravity(H2O=1): Evaporation Rate: Vapor Density(Air=1): 0.80 + 0.05 Slower than Ether Heavier than air _______________________________________________________________________________________________________________________________________ SECTION 4 FIRE AND EXPLOSION HAZARD DATA Flash Point: Flammable Limits: Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: <0OF LEL: 1.8 UEL: 9.5 Use water fog, dry chemical or carbon dioxide. Aerosol cans may rupture when heated. Heated cans may burst. _______________________________________________________________________________________________________________________________________ SECTION 5 Unstable______ Stable __X___ Incompatability (Materials to Avoid): Conditions to Avoid: Hazardous Decomposition or Byproducts: Hazardous Polymerization: REACTIVITY DATA Stability: None known. High temperatures. In fire, will decompose to carbon dioxide, carbon monoxide Will not occur __________________________________________________________________________________________________________________________________________ SECTION 6 STORAGE AND HANDLING INFORMATION Precautions to be Taken in Handling and Storing: When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved respirator. STORE AT TEMPERATURES BELOW 120oF KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME KEEP AWAY FROM CHILDREN FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY FOR USE BY TRAINED PERSONNEL ONLY KEEP CONTAINER CLOSED DURING STORAGE __________________________________________________________________________________________________________________________________________ SECTION 7 HEALTH HAZARDS AND FIRST AID Effects of Overexposure: SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible. EYES: Eye irritant. Will cause redness and burning sensation. INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness, nausea, and loss of coordination.Extreme overexposure may result in unconsciousness and possibly death. INGESTION: Aspiration hazard if swallowed. First Aid Procedures: SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get medical attention. Remove contaminated clothing and launder before reuse. EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Seek medical attention. INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention. INGESTION: DO NOT induce vomiting. Seek medical attention immediately. Note: Never give anything by mouth to an unconscious or convulsing victim. Keep person warm and quiet. __________________________________________________________________________________________________________________________________________ SECTION 8 SPECIAL PROTECTION INFORMATION Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: Self-contained breathing apparatus if above TLV limit. Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit. None required if spraying. As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we recommend the use of safety glasses or chemical splash goggles. Other Protective Equipment: Long sleeves and long pants. Work/Hygienic Practices: Do not smoke while using. Wash hands after use. __________________________________________________________________________________________________________________________________________ SECTION 9 SPILL OR LEAK PROCEDURE Steps To Be Taken In Case Material Is Released or Spilled: Use absorbent sweeping compound to soak up material. Put into container. Dispose as hazardous waste. Waste Disposal Method: Dispose as hazardous waste in accordance with EPA RCRA. _________________________________________________________________________________________________________________________________________ SECTION 10 REGULATORY INFORMATION SARA Title III, Section 313 Components: None __________________________________________________________________________________________________________________________________________ This information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties, express or implied, and assume no liability in connection with any use of this information. 491705 U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET (Prepared According to 29 CFR 1910.1200) ______________________________________________________________________________ SECTION 1 IDENTIFICATION Product Name: Manufacturer's Name: Manufacturer's Address: Manufacturer's Phone Number: Emergency Phone Number: Proper Shipping Name: Effective Date: FORMULA 491655 TROPICAL NECTAR ZENEX International 7777 First Place, Cleveland Ohio 44146 (440) 232-4155 1-800-535-5053 Consumer Commodity, ORM-D 10-15-01 ______________________________________________________________________________ SECTION 2 IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS Chemical Name: Acetone Propane Isobutane n-Butane Fragrance CAS No.: 67-64-1 74-98-6 75-28-5 106-97-8 Not available TLV: 500ppm 2500ppm Not established 800ppm Not available ______________________________________________________________________________ SECTION 3 Boiling Point: Solubility in Water: Physical Description: PHYSICAL DATA <0 to 1330 F Slightly Clear/tropical scent Specific Gravity(H2O=1): Evaporation Rate: Vapor Density(Air=1): 0.80 + 0.05 Slower than Ether Heavier than air _______________________________________________________________________________________________________________________________________ SECTION 4 FIRE AND EXPLOSION HAZARD DATA Flash Point: Flammable Limits: Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: <0OF LEL: 1.8 UEL: 9.5 Use water fog, dry chemical or carbon dioxide. Aerosol cans may rupture when heated. Heated cans may burst. _______________________________________________________________________________________________________________________________________ SECTION 5 Unstable______ Stable __X___ Incompatability (Materials to Avoid): Conditions to Avoid: Hazardous Decomposition or Byproducts: Hazardous Polymerization: REACTIVITY DATA Stability: None known. High temperatures. In fire, will decompose to carbon dioxide, carbon monoxide Will not occur __________________________________________________________________________________________________________________________________________ SECTION 6 STORAGE AND HANDLING INFORMATION Precautions to be Taken in Handling and Storing: When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved respirator. STORE AT TEMPERATURES BELOW 120oF KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME KEEP AWAY FROM CHILDREN FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY FOR USE BY TRAINED PERSONNEL ONLY KEEP CONTAINER CLOSED DURING STORAGE __________________________________________________________________________________________________________________________________________ SECTION 7 HEALTH HAZARDS AND FIRST AID Effects of Overexposure: SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible. EYES: Eye irritant. Will cause redness and burning sensation. INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness, nausea, and loss of coordination.Extreme overexposure may result in unconsciousness and possibly death. INGESTION: Aspiration hazard if swallowed. First Aid Procedures: SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get medical attention. Remove contaminated clothing and launder before reuse. EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Seek medical attention. INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention. INGESTION: DO NOT induce vomiting. Seek medical attention immediately. Note: Never give anything by mouth to an unconscious or convulsing victim. Keep person warm and quiet. __________________________________________________________________________________________________________________________________________ SECTION 8 SPECIAL PROTECTION INFORMATION Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: Self-contained breathing apparatus if above TLV limit. Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit. None required if spraying. As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we recommend the use of safety glasses or chemical splash goggles. Other Protective Equipment: Long sleeves and long pants. Work/Hygienic Practices: Do not smoke while using. Wash hands after use. __________________________________________________________________________________________________________________________________________ SECTION 9 SPILL OR LEAK PROCEDURE Steps To Be Taken In Case Material Is Released or Spilled: Use absorbent sweeping compound to soak up material. Put into container. Dispose as hazardous waste. Waste Disposal Method: Dispose as hazardous waste in accordance with EPA RCRA. _________________________________________________________________________________________________________________________________________ SECTION 10 REGULATORY INFORMATION SARA Title III, Section 313 Components: None __________________________________________________________________________________________________________________________________________ This information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties, express or implied, and assume no liability in connection with any use of this information. 491655 U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET (Prepared According to 29 CFR 1910.1200) ______________________________________________________________________________ SECTION 1 IDENTIFICATION Product Name: Manufacturer's Name: Manufacturer's Address: Manufacturer's Phone Number: Emergency Phone Number: Proper Shipping Name: Effective Date: FORMULA 491805 PEACH KIWI ZENEX International 7777 First Place, Cleveland Ohio 44146 (440) 232-4155 1-800-535-5053 Consumer Commodity, ORM-D 10-15-01 ______________________________________________________________________________ SECTION 2 IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS Chemical Name: Acetone Propane Isobutane n-Butane Fragrance CAS No.: 67-64-1 74-98-6 75-28-5 106-97-8 Not available TLV: 500ppm 2500ppm Not established 800ppm Not available ______________________________________________________________________________ SECTION 3 Boiling Point: Solubility in Water: Physical Description: PHYSICAL DATA <0 to 1330 F Slightly Clear/peach kiwi scent Specific Gravity(H2O=1): Evaporation Rate: Vapor Density(Air=1): 0.80 + 0.05 Slower than Ether Heavier than air _______________________________________________________________________________________________________________________________________ SECTION 4 FIRE AND EXPLOSION HAZARD DATA Flash Point: Flammable Limits: Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: <0OF LEL: 1.8 UEL: 9.5 Use water fog, dry chemical or carbon dioxide. Aerosol cans may rupture when heated. Heated cans may burst. _______________________________________________________________________________________________________________________________________ SECTION 5 Unstable______ Stable __X___ Incompatability (Materials to Avoid): Conditions to Avoid: Hazardous Decomposition or Byproducts: Hazardous Polymerization: REACTIVITY DATA Stability: None known. High temperatures. In fire, will decompose to carbon dioxide, carbon monoxide Will not occur __________________________________________________________________________________________________________________________________________ SECTION 6 STORAGE AND HANDLING INFORMATION Precautions to be Taken in Handling and Storing: When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved respirator. STORE AT TEMPERATURES BELOW 120oF KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME KEEP AWAY FROM CHILDREN FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY FOR USE BY TRAINED PERSONNEL ONLY KEEP CONTAINER CLOSED DURING STORAGE __________________________________________________________________________________________________________________________________________ SECTION 7 HEALTH HAZARDS AND FIRST AID Effects of Overexposure: SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible. EYES: Eye irritant. Will cause redness and burning sensation. INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness, nausea, and loss of coordination.Extreme overexposure may result in unconsciousness and possibly death. INGESTION: Aspiration hazard if swallowed. First Aid Procedures: SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get medical attention. Remove contaminated clothing and launder before reuse. EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Seek medical attention. INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention. INGESTION: DO NOT induce vomiting. Seek medical attention immediately. Note: Never give anything by mouth to an unconscious or convulsing victim. Keep person warm and quiet. __________________________________________________________________________________________________________________________________________ SECTION 8 SPECIAL PROTECTION INFORMATION Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: Self-contained breathing apparatus if above TLV limit. Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit. None required if spraying. As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we recommend the use of safety glasses or chemical splash goggles. Other Protective Equipment: Long sleeves and long pants. Work/Hygienic Practices: Do not smoke while using. Wash hands after use. __________________________________________________________________________________________________________________________________________ SECTION 9 SPILL OR LEAK PROCEDURE Steps To Be Taken In Case Material Is Released or Spilled: Use absorbent sweeping compound to soak up material. Put into container. Dispose as hazardous waste. Waste Disposal Method: Dispose as hazardous waste in accordance with EPA RCRA. _________________________________________________________________________________________________________________________________________ SECTION 10 REGULATORY INFORMATION SARA Title III, Section 313 Components: None __________________________________________________________________________________________________________________________________________ This information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties, express or implied, and assume no liability in connection with any use of this information. 491805 MATERIAL SAFETY DATA SHEET GLASER MANUFACTURING #27 - 547 MAIN STREET, E. MILTON, ON L9T 3J2 (905) 876-4420 EMERGENCY CANUTEC #: 613-996-6666 SECTION I - PRODUCT IDENTIFICATION AND USE PRODUCT NAME: CHEMICAL FAMILY: PRODUCT USE: BIO-ZYME BIOLOGICAL DRAIN OPENER DRAIN CONTROL/STACK MAINTAINER SECTION II - HAZARDOUS INGREDIENTS HAZARDOUS INGREDIENT APPROX. % CAS# LD50/RAT, ORAL LC50 VIABLE BACTERIAL CULTURES 60-100 N/A NOT KNOWN NOT KNOWN SECTION III - PHYSICAL DATA PHYSICAL STATE: LIQUID ODOUR & APPEARANCE: SPICE ODOUR, WHITE ODOUR THRESHOLD: N/E VAPOUR PRESSURE: N/AP EVAPORATION RATE: N/E BOILING POINT: 100ºC COEFFICIENT OF WATER/OIL DISTRIBUTION: SPECIFIC GRAVITY: VAPOUR DENSITY (AIR=1): SOLUBILITY IN WATER: pH: 1.01 N/AP MODERATE 8.0 – 8.5 N/E SECTION IV - FIRE AND EXPLOSION DATA CONDITIONS OF FLAMMABILITY: EXTINGUISHING MEDIA: HAZARDOUS COMBUSTION PRODUCTS: UPPER FLAMMABILITY LIMIT: AUTO IGNITION TEMP: SENSITIVITY TO STATIC CHARGE: NONE N/AP NONE KNOWN N/AP N/AP N/AP LOWER FLAMMABILITY LIMIT: EXPLOSION DATA: N/AP N/AP SECTION V - REACTIVITY DATA CHEMICAL STABILITY: CONDITIONS TO AVOID: INCOMPATIBLE SUBSTANCES: HAZARDOUS DECOMPOSITION: HAZARDOUS POLYMERIZATION: STABLE NONE STRONG ACIDS OR ALKALIS MAY INACTIVATE SOME BACTERIAL CULTURES. NONE KNOWN WILL NOT OCCUR. SECTION VI - TOXICOLOGICAL PROPERTIES ROUTE OF ENTRY: SKIN CONTACT: YES INHALATION: YES SKIN ABSORPTION: YES INGESTION: YES EYE CONTACT: YES EFFECTS OF ACUTE EXPOSURE TO MATERIAL: THIS MATERIAL MAY CAUSE EYE OR SKIN IRRITATION. ORGANISMS USED ARE NON PATHOGENIC, BUT CAN CAUSE INFECTION WHEN IN CONTACT WITH OPEN WOUNDS. THESE ORGANISMS ARE SUSCEPTIBLE TO COMMONLY USED ANTIBIOTICS. EFFECTS OF CHRONIC EXPOSURE: NONE KNOWN. LIMITED TOXIC DATA ARE AVAILABLE ON THIS SPECIFIC PRODUCT. THIS HEALTH HAZARD ASSESSMENT IS BASED ON THE RESULTS OF SCREENING TESTS. EXPOSURE LIMITS: N/E SENSITIZATION OF MATERIAL: NONE KNOWN IRRITANCY OF MATERIAL: SLIGHT CARCINOGENICITY: NONE KNOWN 1 REPRODUCTIVE TOXICITY: MUTAGENICITY: PRODUCT NAME: NONE KNOWN NONE KNOWN TERATOGENICITY: SYNERGISTIC PRODUCTS: NONE KNOWN NONE KNOWN BIO-ZYME SECTION VII - PREVENTIVE MEASURES HAND PROTECTION: RUBBER OR VINYL GLOVES EYE PROTECTION: SAFETY GLASSES DEPENDING ON SEVERITY OF EXPOSURE: RESPIRATORY PROTECTION: LOCAL EXHAUST ADEQUATE. USE NOISH APPROVED RESPIRATOR IF MISTING PRODUCT. FOOT WEAR: RUBBER BOOTS IF CONTACT POSSIBLE CLOTHING: AVOID SKIN CONTACT. LONG SLEEVE CLOTHING. ENGINEERING CONTROLS: LOCAL EXHAUST ADEQUATE. USE NOISH APPROVED RESPIRATOR IF IN CONFINED AREAS. LEAKS AND SPILL PROCEDURES: SMALL SPILLS: FLUSH WITH LARGE AMOUNTS OF WATER. LARGE SPILLS: COLLECT WITH ABSORBENT AND PLACE IN CONTAINERS FOR DISPOSAL. WASTE DISPOSAL: REVIEW LOCAL GOVERNMENT REGULATIONS AND DISPOSE THROUGH LICENSED FACILITY. HANDLING PROCEDURES & EQUIPMENT: AVOID EYE CONTACT. STORAGE REQUIREMENTS: STORE IN A COOL, DRY AREA. DO NOT FREEZE. SECTION VIII - FIRST AID MEASURES PROCEDURES: SKIN: REMOVE CONTAMINATED CLOTHING, WASH AND FLUSH GENEROUSLY WITH SOAP AND WATER. IF IRRITATION PERSISTS, SEEK MEDICAL ATTENTION. EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL ATTENTION IF IRRITATION PERSISTS. INGESTION: DO NOT INDUCE VOMITING. RINSE MOUTH WITH WATER. DRINK LARGE AMOUNTS OF MILK OR WATER. SEEK MEDICAL ATTENTION IMMEDIATELY. SECTION IX - TDG SHIPPING INFORMATION WHMIS CLASSIFICATION: CLASS D, DIVISION 2B TDG CLASSIFICATION: NONE PIN #: NONE PACKING GROUP: N/AP SECTION X - HMIS HAZARD RATING INFORMATION HEALTH: 1 FIRE: 0 REACTIVITY: 0 SPECIAL: NONE HAZARD RATING SCALE: 0=MINIMAL, 1=SLIGHT, 2=MODERATE, 3=SERIOUS, 4=SEVERE SECTION XI - PREPARATION INFORMATION PREPARED BY: PREPARATION DATE: GLASER MANUFACTURING JAN 2006 DISCLAIMER THE INFORMATION CONTAINED HEREIN IS COMPILED FROM SOURCES BELIEVED TO BE RELIABLE. THE MANNER AND CONDITIONS OF USE AND HANDLING MAY INVOLVE OTHER AND ADDITIONAL CONSIDERATIONS. WE ACCEPT NO RESPONSIBILITY FOR THE ACCURACY, SUFFICIENCY, RELIABILITY OR FOR ANY LOSS OR INJURY RESULTING FROM THE USE OF THE INFORMATION. 2 MATERIAL SAFETY DATA SHEET Page: 1 of 4 NATIONAL SANITARY SUPPLY CO. 13217 S. Figueroa Street Los Angeles, California 90061 Emergency No. 1-800-535-5053 (INFOTRAC) ----------------------------------------------------------------------------SECTION 1. IDENTIFICATION OF PRODUCT ----------------------------------------------------------------------------Product Name: MINT O LINE MINT ODOR Date Issued: 07/15/93 DEODORANT CLEANER Supercedes: 06/01/90 National Item#: 1720XX ----------------------------------------------------------------------------SECTION 2. INGREDIENTS CAS NUMBER PERCENT EXPOSURE LIMITS IN AIR OSHA PEL ACGIH TLV OTHER ----------------------------------------------------------------------------ISOPROPYL ALCOHOL 67-63-01 14-16 400 ppm TWA 400 ppm COCONUT OIL SOAP 61788-47-4 8-10 NOT ESTABLISHED METHYL SALICYLATE 119-36-8 <2 NOT ESTABLISHED WATER >50.00 N/A = Not Applicable; N/D = Not Determined ----------------------------------------------------------------------------SECTION 3. PHYSICAL DATA ----------------------------------------------------------------------------Boiling Point (F): <212 Specific Gravity (Water=1): .86 Vapor Pressure (mm Hg.): 16 Percent Volatile (By Volume): 88 Vapor Density (Air=1): ND Evaporation Rate (Water =1): 1 Solubility in Water: SOLUBLE pH Range: 10.5 Appearance and Odor: CLEAR COLORLESS/MINT SCENT ----------------------------------------------------------------------------Section 4. FIRE AND EXPLOSION HAZARD DATA ----------------------------------------------------------------------------Flash Point (Test Method): 108 F (TOC) Extinguishing Media: CO2, DRY CHEMICAL, FOAM, WATER FOG Special Fire Fighting Procedures: NORMAL FIRE FIGHTING PROCEDURES MAY BE USED. COOL AND USE CAUTION WHEN APPROACHING OR HANDLING FIRE- EXPOSED CONTAINERS. Unusual Fire & Explosion Hazards: CONTAINERS MAY BURST IN HEAT. MATERIAL SAFETY DATA SHEET Page: 2 of 4 Product Name: MINT O LINE MINT ODOR DEODORANT CLEANER Date Issued: 07/15/93 National Item#: 1720 ----------------------------------------------------------------------------SECTION 5. REACTIVITY DATA ----------------------------------------------------------------------------Stability: STABLE Incompatibility - Materials to Avoid: NONE KNOWN TO NSS Hazardous Polymerization: WILL NOT OCCUR Conditions to Avoid: NONE KNOWN TO NSS Hazardous Decomposition Products: WHEN EXPOSED TO FIRE, PRODUCES NORMAL PRODUCTS OF COMBUSTION. ----------------------------------------------------------------------------SECTION 6. SPILL, LEAK AND DISPOSAL PROCEDURES ----------------------------------------------------------------------------Spill Response: FOR SMALL SPILLS. DILUTE WITH WATER AND PICK UP WITH MOP AND PAIL OR WET PICK UP VACUUM. FOR LARGE SPILLS, DIKE AREA TO CONTAIN SPILL. CLEAN UP USING ABSORBENT MATERIAL. PLACE ALL CONTAMINATED MATERIAL IN A CLOSED CONTAINER FOR DISPOSAL. Product Disposal: WASTE FOR DILUTED PRODUCT MAY BE FLUSHED TO SEWER. UNDILUTED PRODUCT RECOVERED FROM SPILLS MAY BE SENT TO A LICENSED DISPOSAL FACILITY TO BE DISPOSED OF IN ACCORDANCE WITH FEDERAL/STATE REGULATIONS AND LOCAL ORDINANCES. Container Disposal: TRIPLE RINSE EMPTY CONTAINER THOROUGHLY WITH WATER AND DISCARD IN REGULAR TRASH COLLECTION IF ALLOWED BY LOCAL, STATE AND FEDERAL REGULATIONS. ----------------------------------------------------------------------------SECTION 7. HEALTH HAZARD DATA MATERIAL SAFETY DATA SHEET Page: 3 of 4 Product Name: MINT O LINE MINT ODOR DEODORANT CLEANER Date Issued: 07/15/93 National Item#: 1720 ----------------------------------------------------------------------------Symptoms of Overexposure: Eye Contact: EYE IRRITANT. IF NOT PROMPTLY TREATED, EYE DAMAGE MAY RESULT. Skin Contact: SKIN IRRITANT. IRRITATION CAN OCCUR FROM CONTACT WITH CONCENTRATED PRODUCT OR FROM PROLONGED CONTACT WITH DILUTED PRODUCT. REPEATED OR PROLONGED EXPOSURE TO DILUTED PRODUCT MAY LEAD TO DERMATITIS. Inhalation: NO HEALTH EFFECTS ARE KNOWN TO OCCUR FROM INHALATION OF THIS PRODUCT UNDER NORMAL USE IN A WELL VENTILATED AREA. HIGH AIRBORNE CONCENTRATIONS OF MISTS OR SPRAYS OF THIS PRODUCT MAY CA USE IRRITATION OF THE UPPER RESPIRATORY TRACT. Ingestion: INGESTION OF THIS PRODUCT MAY CAUSE DAMAGE TO THE MEMBRANES OF THE MOUTH, THROAT, AND GASTROINTESTINAL TRACT WHICH THE PRODUCT CONTACTS. BURNS OF THE MOUTH AND THROAT, NAUSEA, VOMITING, CRAMPS, AND DIARRHEA MAY OCCUR. Primary Routes of Entry: EYES, SKIN THE ISOPROYL ALCOHOL LISTED IN SECTION 2 IS NOT LISTED ON THE OSHA, NTP OR IARC MONOGRAPH CARCINOGEN LISTS. ----------------------------------------------------------------------------SECTION 8. EMERGENCY AND FIRST AID PROCEDURES ----------------------------------------------------------------------------Eye Contact: IMMEDIATELY FLUSH THE EYE WITH LARGE QUANTITIES OF RUNNING WATER FOR A MINIMUM OF 15 MINUTES. HOLD THE EYELIDS APART DURING THE IRRIGATION TO ENSURE FLUSHING OF THE ENTIRE SURFACE OF THE EYE LID WITH WATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. Skin Contact: FLUSH THE EFFECTED AREA WITH LARGE QUANTITIES OF RUNNING WATER WHILE REMOVING CONTAMINATED CLOTHES AND SHOES. WASH CLOTHING BEFORE REUSE. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. Inhalation: REMOVE FROM CONTAMINATED AREA. IF SYMPTOMS OF RESPIRATORY DISCOMFORT PERSISTS, GET MEDICAL ATTENTION. Ingestion: REQUIRES IMMEDIATE MEDICAL MANAGEMENT. DRINK MILK OR WATER AND GET MEDICAL ADVICE. VOMITING SHOULD BE INDUCED ONLY ON RECOMMENDATION OF MEDICAL PERSONNEL. ----------------------------------------------------------------------------SECTION 9. SPECIAL PROTECTION INFORMATION ----------------------------------------------------------------------------Respiratory Protection: NO SPECIAL REQUIREMENTS UNDER NORMAL USE CONDITIONS. Ventilation: ROOM VENTILATION IS ADEQUATE. Protection Gloves: NO SPECIAL REQUIREMENTS UNDER NORMAL USE CONDITIONS. Eye Protection: NO SPECIAL REQUIREMENTS UNDER NORMAL USE CONDITIONS. Other Protective Clothing/Equipment: WHERE GROSS EYE OR SKIN CONTACT MAY OCCUR, USE APPROPRIATE PROTECTIVE EQUIPMENT. MATERIAL SAFETY DATA SHEET Page: 4 of 4 Product Name: MINT O LINE MINT ODOR DEODORANT CLEANER Date Issued: 07/15/93 National Item#: 1720 ----------------------------------------------------------------------------SECTION 10. ADDITIONAL INFORMATION AND PRECAUTIONS ----------------------------------------------------------------------------Handling and Storage Precautions: STORE IN A COOL DRY PLACE. REPLACE CAP AFTER USE. KEEP OUT OF REACH OF CHILDREN. SARA TITLE III H&P RATINGS: Acute, YES; Chronic, NO; Fire, YES; Press. Release, NO; Reactive, NO; NFPA RATINGS: HEALTH - 1 FIRE -3 REACTIVITY -0 SPECIFIC -1 ----------------------------------------------------------------------------THE INFORMATION ON THIS MATERIAL SAFETY DATA SHEET REPRESENTS THE LATEST DATA AND BEST OPINION AS TO THE PROPER USE AND HANDLING OF THIS PRODUCT UNDER NORMAL CONDITIONS. ANY USE OF THIS PRODUCT OR METHOD OF APPLICATION WHICH IS NOT IN CONFORMANCE WITH THIS DATA SHEET AND THE PRODUCT LABEL DIRECTIONS, IS THE RESPONSIBILITY OF THE USER. THIS MATERIAL SAFETY DATA SHEET WAS PREPARED TO COMPLY WITH THE OSHA HAZARD COMMUNICATION REGULATION. ----------------------------------------------------------------------------- Material Safety Data Sheet U.S. DEPARTMENT OF LABOR May be used to comply with OSHA=S Hazard Communication Standard 29 CFR 2910.1200. Standard must be consulted for specific requirements. Occupational Safety and Health (Non-Mandatory Form) Form Approved OMB No. 1218-0072 Note: Blank spaces are not permitted. If any item is not applicable, or no information is available, the space must be marked to indicate that. Identity (As Used on Label and List) #202 Big D Fire D One-Shot Section I Big D Industries, Inc. Manufacturer=s Name Emergency Telephone Number (800) 535-5053 Address (number, Street, City, State, and ZIP Code) Telephone Number for Information 5620 S. W. 29th Street (73179) 2541 P. O. Box 82219 Date Prepared Oklahoma City, OK 73148 Signature of Preparer (optional) (800) 654-4752 (800) 654-4752 (405) 682- 01/01/2007 Section II - HMIS Rating Health 1 4 Flammability 1 Reactivity Section III - Hazardous Ingredients/Identity Information Hazardous Components (Specific Chemical Identity: Common Name(s)) OSHA PEL ACGIH TLV Other Limits %(optional) Rcmnd. Acetone CAS #67-64-1 500 ppm 500 ppm - Amyl Acetate CAS #628-63-7 100 ppm 100 ppm - Ethyl Acetate CAS #141-78-6 400 ppm 400 ppm Liq. Petrole\um Gas - CAS #68476-85-7 1000 ppm 1000 ppm Section IV - Physical/Chemical Characteristics Boiling Point -44 - 1350F Conc. Specific Gravity (H2O = 1) 0.5677 N/E Vapor Pressure (mm Hg.) N/E Melting Point N/A Vapor Density (AIR = 1) >1 Evaporation Rate <1 Solubility in Water: Slight Appearance and Odor: Produces fine mist with pleasant fragrance. Liquid is transparent. Section V - Fire and Explosion Hazard Data Flash Point (Method Used) Extinguishing Media Flammable Limits Carbon dioxide, dry foam, water spray Self contained air supply suggested. Special Fire Fighting Procedures Unusual Fire and Explosion Hazards N/A - Not Applicable N/A Keep containers cool (below 1300F) to avoid bursting. N/D - Not Determined Page 1 N/E - Not Established LEL UEL 1.8% 12.8 #202 Section VI - Reactivity Data Stability Unstable Conditions to Avoid: Stable X Avoid contact with strong oxidizing agents such as nitric acid. Incompatibility (Materials to Avoid): Hazardous Decomposition or Byproducts: Hazardous Polymerization None None May Occur Conditions to Avoid: Will Not Occur None X Section VII - Health Hazard Data Route(s) of Entry: Inhalation? Yes Skin? Yes Ingestion? Yes Health Hazards (Acute and Chronic): Acute - Propellant is an asphyxiant and may exhibit properties at high concentrate. Chronic - Unconsciousness Carcinogenicity: NTP? No Signs and Symptoms of Exposure: IARC Monographs? No OSHA Regulated? No Skin - possible frostbite burn. Eyes - burning sensation. Inhalation - Headache, nausea, disorientation. Medical Conditions Generally Aggravated by Exposure: Emphysema Emergency and First Aid Procedures: Eye contact: flush with large amounts of water. May cause corneal damage on prolonged contact. Seek medical attn. Ingestion: Do not give anything by mouth to an unconscious person. Seek Medical attn. Inhalation: remove person to fresh air . Administer artificial respiration if not breathing. Seek medical attn. Section VIII - Precautions for Safe Handling and Use Steps to be Taken in Case Material is Released or Spilled: If container is ruptured and begins to leak, place in a well ventilated area and eliminate all ignition sources. Waste Disposal Method: do not discard empty container in incinerator or fire. Dispose of in accordance with Local, State, and Federal regulations. 0 Precautions to be Taken in Handling and Storing: Store in cool area away from heat or open flame. Do not store above 130 F as containers may burst releasing the highly flammable propellant. AStore as Level Aerosol (NFPA 30B) Other precautions: In case of rupture, ventilate to prevent concentrations from reaching flammable levels. Note: any copies or redistribution of this M.S.D. Sheet must not be modified in any way. Section IX - Control Measures Respiratory Protection (Specify Type): Self contained breathing apparatus. Ventilation Protective Gloves: Rubber or plastic for prolonged contact Other Protective Clothing or Equipment: Work/Hygienic Practices: N.A. = Not Applicable Local Exhaust:: Doors & windows open Special N/A Mechanical (General) Other N/A Fan Eye Protection: Safety goggles for splash protection Eye wash/shower facility nearby Good housekeeping practices. Avoid skin/eye contact. N.D. - Not Determined Page 2 N/E - Not Established OSHA 174, Sept. 1985 MATERIAL SAFETY DATA SHEET MSDS 0091 ============================================================================= Section 1 -- PRODUCT AND COMPANY IDENTIFICATION ----------------------------------------------------------------------------HMIS CODES PRODUCT NAME Health 2 RectorSeal Concentrated Evaporator Coil Cleaner Flammability 0 Reactivity 0 PRODUCT CODES PPI B 82552, 82555, 82558 CHEMICAL FAMILY Organic/Inorganic USE Coil Cleaner MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. The RectorSeal Corporation Chemtrec 24 Hours 2601 Spenwick Drive (800) 424-9300 Houston, Texas 77055 USA DATE OF PREPARATION TECHNICAL SERVICE TELEPHONE NO. June 30, 2005 (800) 231-3345 ============================================================================= Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS ----------------------------------------------------------------------------% by WT CAS No. INGREDIENT UNITS 1-5 111-76-2 Glycol Ether EB ACGIH TLV 25 ppm OSHA PEL 25 ppm ============================================================================= Section 3 -- HAZARDS IDENTIFICATION ----------------------------------------------------------------------------SUMMARY OF ACUTE HAZARDS Irritation to eyes, nose, and throat; drowsiness, narcosis, tremors, and other CNS effects at high concentrations. Skin irritation, dermatitis, and defatting. ROUTE OF EXPOSURE, SIGNS AND SYMPTOMS INHALATION Nasal and respiratory irritation, dizziness, narcosis, headache, nausea, CNS depression, and unconsciousness. EYE CONTACT Watering, blurred vision, inflammation, and irritation which can result in corneal injury. SKIN CONTACT Irritation, dermatitis. INGESTION Nausea, vomiting; CNS depression; irritation of gastrointestinal tract, liver and peritoneal wall; lung congestion. SUMMARY OF CHRONIC HAZARDS Skin irritation, contact dermatitis, and defatting. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Individuals with pre-existing or chronic diseases of the eyes, skin, respiratory system, cardiovascular system, gastrointestinal system, liver, or kidneys may have increased susceptibility to excessive exposure. ============================================================================= Section 4 -- FIRST AID MEASURES ----------------------------------------------------------------------------If INHALED: If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial respiration as needed. Obtain emergency medical attention. Prompt action is essential. Immediately wash with soap and water. Remove and wash any contaminated clothing. If in EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention if irritation persists. If SWALLOWED: If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person. ============================================================================= Section 5 -- FIRE FIGHTING MEASURES ----------------------------------------------------------------------------FLASH POINT LEL UEL None N/D N/D EXTINGUSING MEDIA Non-flammable. Use agents appropriate for surrounding fires. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained full face piece breathing apparatus and other protective clothing. Hazardous decomposition products possible (see Section 10). UNUSUAL FIRE AND EXPLOSION HAZARDS: None ============================================================================= Section 6 -- ACCIDENTAL RELEASE MEASURES ----------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove all sources of ignition. Use absorbent materials to prevent footing hazard and to contain. Ventilate area with natural or explosion-proof, forced air ventilation. Avoid flushing into sewers, drains, waterways, and soil. Wear protective clothing and respiratory protection during cleanup. ============================================================================= Section 7 -- HANDLING AND STORAGE ----------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed and upright when not in use. Do not store near heat, sparks, or open flames. OTHER PRECAUTIONS: Avoid prolonged or repeated contact with skin or clothing. Empty containers may contain residues; treat as if full and observe all products precautions. Do not reuse empty containers. ============================================================================= Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION ----------------------------------------------------------------------------RESPIRATORY PROTECTION (SPECIFY TYPE): In confined, poorly ventilated areas, use NIOSH/MSHA approved air purifying or supplied air respirators during soldering operations until fumes have dissipated. VENTILATION - LOCAL EXHAUST: Acceptable SPECIAL: Explosion proof MECHANICAL (GENERAL): Acceptable OTHER: N/A PROTECTIVE GLOVES: Wear rubber gloves. EYE PROTECTION: Safety glasses (ANSI Z-87.1 or equivalent) OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Chemical resistant coveralls recommended. WORK/HYGIENIC PRACTICES: Where use can result in skin contact, wash exposed areas thoroughly before eating, drinking, smoking, or leaving work area. Launder contaminated clothing before reuse. ============================================================================= Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES ----------------------------------------------------------------------------BOILING POINT: 212 F (100 C) @ 760mm Hg SPECIFIC GRAVITY (H20 = 1): 0.99 VAPOR PRESSURE (mm Hg): 17 @ 68 F (20 C) MELTING POINT: N/A VAPOR DENSITY (AIR = 1): <1 If on SKIN: EVAPORATION RATE (ETHYL ACETATE = 1): >1 APPEARANCE/ODOR: Green Liquid / Mild Odor SOLUBILITY IN WATER: Soluble ============================================================================= Section 10 -- STABILITY AND REACTIVITY ----------------------------------------------------------------------------STABILITY: Stable CONDITIONS TO AVOID: None INCOMPATIBILITY (MATERIALS TO AVOID): Heat, sparks and open flames. HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO, and fragmented hydrocarbons. HAZARDOUS POLYMERIZATION: Will not occur. ============================================================================= Section 11 -- TOXICOLOGY INFORMATION ----------------------------------------------------------------------------CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. ----------------------------------------------------------------------------TOXICOLOGY DATA Ingredient Name ----------------------------------------------------------------------------Glycol Ether EB Oral-Rat LD50:470 mg/kg Inhalation-Rat TCLo:200 ppm/6H ============================================================================= Section 12 -- Ecological Information ----------------------------------------------------------------------------ECOLOGICAL DATA Ingredient Name ----------------------------------------------------------------------------Glycol Ether EB Food Chain Concentration Potential None WATERFOWL TOXICITY N/A BOD 26% AQUATIC TOXICITY 1000 ppm/24 hr/brine shrimp/TLm ============================================================================= Section 13 -- DISPOSAL CONSIDERATIONS ----------------------------------------------------------------------------Waste Classification: Non-regulated liquid waste. Disposal Method: Dispose of in accordance with local, state and federal regulations. ============================================================================= Section 14 -- TRANSPORTATION INFORMATION ----------------------------------------------------------------------------DOT: Non-regulated OCEAN (IMDG): Non-regulated AIR (IATA): Non-regulated WHMIS (CANADA): Non-regulated ============================================================================= Section 15 -- REGULATORY INFORMATION ----------------------------------------------------------------------------REGULATORY DATA Ingredient Name ----------------------------------------------------------------------------Glycol Ether EB SARA 313 Yes TSCA Inventory Yes CERCLA RQ N/A RCRA Code N/A ============================================================================= Section 16 -- OTHER INFORMATION ----------------------------------------------------------------------------This document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.1200). The information herein is given in good faith, but no warranty, expressed or implied is made. Consult RectorSeal for further information: (713) 263-8001 MATERIAL SAFETY DATA SHEET MSDS 0091 ============================================================================= Section 1 -- PRODUCT AND COMPANY IDENTIFICATION ----------------------------------------------------------------------------HMIS CODES PRODUCT NAME Health 2 RectorSeal Concentrated Evaporator Coil Cleaner Flammability 0 Reactivity 0 PRODUCT CODES PPI B 82552, 82555, 82558 CHEMICAL FAMILY Organic/Inorganic USE Coil Cleaner MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. The RectorSeal Corporation Chemtrec 24 Hours 2601 Spenwick Drive (800) 424-9300 Houston, Texas 77055 USA DATE OF PREPARATION TECHNICAL SERVICE TELEPHONE NO. June 30, 2005 (800) 231-3345 ============================================================================= Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS ----------------------------------------------------------------------------% by WT CAS No. INGREDIENT UNITS 1-5 111-76-2 Glycol Ether EB ACGIH TLV 25 ppm OSHA PEL 25 ppm ============================================================================= Section 3 -- HAZARDS IDENTIFICATION ----------------------------------------------------------------------------SUMMARY OF ACUTE HAZARDS Irritation to eyes, nose, and throat; drowsiness, narcosis, tremors, and other CNS effects at high concentrations. Skin irritation, dermatitis, and defatting. ROUTE OF EXPOSURE, SIGNS AND SYMPTOMS INHALATION Nasal and respiratory irritation, dizziness, narcosis, headache, nausea, CNS depression, and unconsciousness. EYE CONTACT Watering, blurred vision, inflammation, and irritation which can result in corneal injury. SKIN CONTACT Irritation, dermatitis. INGESTION Nausea, vomiting; CNS depression; irritation of gastrointestinal tract, liver and peritoneal wall; lung congestion. SUMMARY OF CHRONIC HAZARDS Skin irritation, contact dermatitis, and defatting. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Individuals with pre-existing or chronic diseases of the eyes, skin, respiratory system, cardiovascular system, gastrointestinal system, liver, or kidneys may have increased susceptibility to excessive exposure. ============================================================================= Section 4 -- FIRST AID MEASURES ----------------------------------------------------------------------------If INHALED: If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial respiration as needed. Obtain emergency medical attention. Prompt action is essential. Immediately wash with soap and water. Remove and wash any contaminated clothing. If in EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention if irritation persists. If SWALLOWED: If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person. ============================================================================= Section 5 -- FIRE FIGHTING MEASURES ----------------------------------------------------------------------------FLASH POINT LEL UEL None N/D N/D EXTINGUSING MEDIA Non-flammable. Use agents appropriate for surrounding fires. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained full face piece breathing apparatus and other protective clothing. Hazardous decomposition products possible (see Section 10). UNUSUAL FIRE AND EXPLOSION HAZARDS: None ============================================================================= Section 6 -- ACCIDENTAL RELEASE MEASURES ----------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove all sources of ignition. Use absorbent materials to prevent footing hazard and to contain. Ventilate area with natural or explosion-proof, forced air ventilation. Avoid flushing into sewers, drains, waterways, and soil. Wear protective clothing and respiratory protection during cleanup. ============================================================================= Section 7 -- HANDLING AND STORAGE ----------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed and upright when not in use. Do not store near heat, sparks, or open flames. OTHER PRECAUTIONS: Avoid prolonged or repeated contact with skin or clothing. Empty containers may contain residues; treat as if full and observe all products precautions. Do not reuse empty containers. ============================================================================= Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION ----------------------------------------------------------------------------RESPIRATORY PROTECTION (SPECIFY TYPE): In confined, poorly ventilated areas, use NIOSH/MSHA approved air purifying or supplied air respirators during soldering operations until fumes have dissipated. VENTILATION - LOCAL EXHAUST: Acceptable SPECIAL: Explosion proof MECHANICAL (GENERAL): Acceptable OTHER: N/A PROTECTIVE GLOVES: Wear rubber gloves. EYE PROTECTION: Safety glasses (ANSI Z-87.1 or equivalent) OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Chemical resistant coveralls recommended. WORK/HYGIENIC PRACTICES: Where use can result in skin contact, wash exposed areas thoroughly before eating, drinking, smoking, or leaving work area. Launder contaminated clothing before reuse. ============================================================================= Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES ----------------------------------------------------------------------------BOILING POINT: 212 F (100 C) @ 760mm Hg SPECIFIC GRAVITY (H20 = 1): 0.99 VAPOR PRESSURE (mm Hg): 17 @ 68 F (20 C) MELTING POINT: N/A VAPOR DENSITY (AIR = 1): <1 If on SKIN: EVAPORATION RATE (ETHYL ACETATE = 1): >1 APPEARANCE/ODOR: Green Liquid / Mild Odor SOLUBILITY IN WATER: Soluble ============================================================================= Section 10 -- STABILITY AND REACTIVITY ----------------------------------------------------------------------------STABILITY: Stable CONDITIONS TO AVOID: None INCOMPATIBILITY (MATERIALS TO AVOID): Heat, sparks and open flames. HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO, and fragmented hydrocarbons. HAZARDOUS POLYMERIZATION: Will not occur. ============================================================================= Section 11 -- TOXICOLOGY INFORMATION ----------------------------------------------------------------------------CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. ----------------------------------------------------------------------------TOXICOLOGY DATA Ingredient Name ----------------------------------------------------------------------------Glycol Ether EB Oral-Rat LD50:470 mg/kg Inhalation-Rat TCLo:200 ppm/6H ============================================================================= Section 12 -- Ecological Information ----------------------------------------------------------------------------ECOLOGICAL DATA Ingredient Name ----------------------------------------------------------------------------Glycol Ether EB Food Chain Concentration Potential None WATERFOWL TOXICITY N/A BOD 26% AQUATIC TOXICITY 1000 ppm/24 hr/brine shrimp/TLm ============================================================================= Section 13 -- DISPOSAL CONSIDERATIONS ----------------------------------------------------------------------------Waste Classification: Non-regulated liquid waste. Disposal Method: Dispose of in accordance with local, state and federal regulations. ============================================================================= Section 14 -- TRANSPORTATION INFORMATION ----------------------------------------------------------------------------DOT: Non-regulated OCEAN (IMDG): Non-regulated AIR (IATA): Non-regulated WHMIS (CANADA): Non-regulated ============================================================================= Section 15 -- REGULATORY INFORMATION ----------------------------------------------------------------------------REGULATORY DATA Ingredient Name ----------------------------------------------------------------------------Glycol Ether EB SARA 313 Yes TSCA Inventory Yes CERCLA RQ N/A RCRA Code N/A ============================================================================= Section 16 -- OTHER INFORMATION ----------------------------------------------------------------------------This document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.1200). The information herein is given in good faith, but no warranty, expressed or implied is made. Consult RectorSeal for further information: (713) 263-8001 MATERIAL SAFETY DATA SHEET MSDS 0128 ============================================================================= Section 1 -- PRODUCT AND COMPANY IDENTIFICATION ----------------------------------------------------------------------------HMIS CODES PRODUCT NAME Health 2 Clean-N-Safe Aerosol Coil Cleaner Flammability 2 Reactivity 0 PRODUCT CODES PPI B 83780 CHEMICAL FAMILY Organic/Inorganic USE Coil Cleaner MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. The RectorSeal Corporation Chemtrec 24 Hours 2601 Spenwick Drive (800) 424-9300 Houston, Texas 77055 USA DATE OF PREPARATION TECHNICAL SERVICE TELEPHONE NO. June 8, 2005 (800) 231-3345 ============================================================================= Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS ----------------------------------------------------------------------------% by WT CAS No. INGREDIENT UNITS -9036-19-5 Octylphenoxypolyethoxyethanol ACGIH TLV N/D OSHA PEL N/D -57018-52-7 Polylene Glycol Butyl Ether ACGIH TLV N/D OSHA PEL N/D -6834-92-0 Sodium Metasilicate ACGIH TLV N/D OSHA PEL N/D ============================================================================= Section 3 -- HAZARDS IDENTIFICATION ----------------------------------------------------------------------------SUMMARY OF ACUTE HAZARDS Irritation to eyes, nose, and throat; drowsiness, narcosis, tremors, and other CNS effects at high concentrations. Skin irritation, dermatitis, and defatting. ROUTE OF EXPOSURE, SIGNS AND SYMPTOMS INHALATION Nasal and respiratory irritation, dizziness, narcosis, headache, nausea, CNS depression, and unconsciousness. EYE CONTACT Watering, blurred vision, inflammation, and irritation which can result in corneal injury. SKIN CONTACT Irritation, dermatitis. INGESTION Nausea, vomiting; CNS depression; irritation of gastrointestinal tract, liver and peritoneal wall; lung congestion. SUMMARY OF CHRONIC HAZARDS Skin irritation, contact dermatitis, and defatting. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Individuals with pre-existing or chronic diseases of the eyes, skin, respiratory system, cardiovascular system, gastrointestinal system, liver, or kidneys may have increased susceptibility to excessive exposure. ============================================================================= Section 4 -- FIRST AID MEASURES ----------------------------------------------------------------------------If INHALED: If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial respiration as needed. Obtain emergency medical attention. Prompt action is essential. If on SKIN: Immediately wash with soap and water. Remove and wash any contaminated clothing. If in EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention if irritation persists. If SWALLOWED: If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person. ============================================================================= Section 5 -- FIRE FIGHTING MEASURES ----------------------------------------------------------------------------FLASH POINT LEL UEL Not combustible, Negative Flame Extension N/D N/D NFPA Level 1 Aerosol EXTINGUSING MEDIA Use extinguishing agents appropriate for surrounding fires. UNUSUAL FIRE AND EXPLOSION HAZARDS: Aerosol cans are under pressure exposure to temperatures above 120F can cause bursting or "rocketing" of cans. ============================================================================= Section 6 -- ACCIDENTAL RELEASE MEASURES ----------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Depressurize and dispose of empty cans ============================================================================= Section 7 -- HANDLING AND STORAGE ----------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Shake well before using. Keep away from heat, sparks and open flames. Prolonged exposure to direct sunshine or storage above 120 F may cause can to burst. Do not puncture or incinerate can. OTHER PRECAUTIONS: Avoid prolonged or repeated contact with skin or clothing. Empty containers may contain residues; treat as if full and observe all products precautions. ============================================================================= Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION ----------------------------------------------------------------------------RESPIRATORY PROTECTION (SPECIFY TYPE): None required. VENTILATION - LOCAL EXHAUST: N/A SPECIAL: N/A MECHANICAL (GENERAL): N/A OTHER: N/A PROTECTIVE GLOVES: None required. EYE PROTECTION: Safety glasses (ANSI Z-87.1 or equivalent) OTHER PROTECTIVE CLOTHING OR EQUIPMENT: None normally required. WORK/HYGIENIC PRACTICES: Where use can result in skin contact, wash exposed areas thoroughly before eating, drinking, smoking, or leaving work area. Launder contaminated clothing before reuse. ============================================================================= Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES ----------------------------------------------------------------------------BOILING POINT: >230 F (110 C) @ 760mm Hg SPECIFIC GRAVITY (H20 = 1): 1.0 VAPOR PRESSURE (mm Hg): N/D MELTING POINT: N/A VAPOR DENSITY (AIR = 1): N/D EVAPORATION RATE (ETHYL ACETATE = 1): Similar to water APPEARANCE/ODOR: Clear Liquid / Fresh Odor SOLUBILITY IN WATER: Soluble ============================================================================= Section 10 -- STABILITY AND REACTIVITY ----------------------------------------------------------------------------STABILITY: Stable CONDITIONS TO AVOID: Do not store in temperatures above 120 F. INCOMPATIBILITY (MATERIALS TO AVOID): None known HAZARDOUS DECOMPOSITION PRODUCTS: None known HAZARDOUS POLYMERIZATION: Will not occur. ============================================================================= Section 11 -- TOXICOLOGY INFORMATION ----------------------------------------------------------------------------CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. ----------------------------------------------------------------------------TOXICOLOGY DATA Ingredient Name ----------------------------------------------------------------------------Octylphenoxypolyethoxyethanol Oral-Rat LD50:4190 mg/kg Inhalation-Rat LC50:N/D Polylene Glycol Butyl Ether Oral-Rat LD50:N/D Inhalation-Rat LC50:N/D Sodium Metasilicate Oral-Rat LD50:1153 mg/kg Inhalation-Rat LC50:N/D ============================================================================= Section 12 -- Ecological Information ----------------------------------------------------------------------------ECOLOGICAL DATA Ingredient Name ----------------------------------------------------------------------------Octylphenoxypolyethoxyethanol Food Chain Concentration Potential N/D WATERFOWL TOXICITY N/D BOD N/D AQUATIC TOXICITY N/D Polylene Glycol Butyl Ether Food Chain Concentration Potential N/D WATERFOWL TOXICITY N/D BOD N/D AQUATIC TOXICITY N/D Sodium Metasilicate Food Chain Concentration Potential N/D WATERFOWL TOXICITY N/D BOD N/D AQUATIC TOXICITY N/D ============================================================================= Section 13 -- DISPOSAL CONSIDERATIONS ----------------------------------------------------------------------------Waste Classification: Aerosols Disposal Method: Empty containers can be disposed of in trash. Full containers should be depressurized to separate liquid phase. The liquid phase is considered a D001 ignitable waste and should be incinerated. Dispose of all liquid waste in accordance with all local, state and federal regulations. ============================================================================= Section 14 -- TRANSPORTATION INFORMATION ----------------------------------------------------------------------------DOT: Consumer Commodity, ORM-D OCEAN (IMDG): Aerosols, Class 2, UN 1950, IMDG#2102, EMS#2-13 AIR (IATA): Aerosols, 2.2, UN1950, ERG#126 WHMIS (CANADA): Class A ============================================================================= Section 15 -- REGULATORY INFORMATION ----------------------------------------------------------------------------REGULATORY DATA Ingredient Name ----------------------------------------------------------------------------Octylphenoxypolyethoxyethanol SARA 313 No TSCA Inventory Yes CERCLA RQ N/A RCRA Code N/A Polylene Glycol Butyl Ether SARA 313 No TSCA Inventory Yes CERCLA RQ N/A RCRA Code N/A Sodium Metasilicate SARA 313 No TSCA Inventory Yes CERCLA RQ N/A RCRA Code N/A ============================================================================= Section 16 -- OTHER INFORMATION ----------------------------------------------------------------------------This document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.1200). The information herein is given in good faith, but no warranty, expressed or implied is made. Consult RectorSeal for further information: (713) 263-8001 U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET (Prepared According to 29 CFR 1910.1200) ______________________________________________________________________________ SECTION 1 IDENTIFICATION Product Name: Manufacturer's Name: Manufacturer's Address: Manufacturer's Phone Number: Emergency Phone Number: Proper Shipping Name: Effective Date: FORMULA 496655 ZENASHEEN H20 ZENEX International 7777 First Place, Cleveland Ohio 44146 (440) 232-4155 1-800-535-5053 Consumer Commodity, ORM-D 10-15-01 ______________________________________________________________________________ SECTION 2 IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS Chemical Name: Mineral Oil Propane Butane Isoparaffinic Hydrocarbon Silicone Isobutane Ester CAS No.: 8042-47-5 74-98-6 106-97-8 64741-66-8 63148-62-9 75-28-5 9007-48-1 TLV: 5 mg/m3 as mist 2500ppm 800ppm Not established Not established Not established Not established ______________________________________________________________________________ SECTION 3 Boiling Point: Solubility in Water: Vapor Density(Air=1): PHYSICAL DATA <0 to 4510 F Emulsion Heavier than air Specific Gravity(H2O=1): Evaporation Rate: pH: 0.89 + 0.05 Slower than Ether 10.75 + 0.5 _______________________________________________________________________________________________________________________________________ SECTION 4 FIRE AND EXPLOSION HAZARD DATA Flash Point: Flash Point(Propellant): Flammable Limits(Propellant): Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: 150OF <0OF LEL: 1.9 UEL: 9.5 Use water fog, dry chemical or carbon dioxide. Aerosol cans may rupture when heated. Heated cans may burst. _______________________________________________________________________________________________________________________________________ SECTION 5 Unstable______ Stable __X___ Incompatability (Materials to Avoid): Conditions to Avoid: Hazardous Decomposition or Byproducts: Hazardous Polymerization: REACTIVITY DATA Stability: None known. High temperatures. In fire, will decompose to carbon dioxide, carbon monoxide Will not occur __________________________________________________________________________________________________________________________________________ SECTION 6 STORAGE AND HANDLING INFORMATION Precautions to be Taken in Handling and Storing: When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved respirator. STORE AT TEMPERATURES BELOW 120oF KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME KEEP AWAY FROM CHILDREN FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY FOR USE BY TRAINED PERSONNEL ONLY KEEP CONTAINER CLOSED DURING STORAGE __________________________________________________________________________________________________________________________________________ SECTION 7 HEALTH HAZARDS AND FIRST AID Effects of Overexposure: SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible. EYES: Eye irritant. Will cause redness and burning sensation. INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness, nausea, and loss of coordination.Extreme overexposure may result in unconsciousness and possibly death. INGESTION: Aspiration hazard if swallowed. First Aid Procedures: SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get medical attention. Remove contaminated clothing and launder before reuse. EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Seek medical attention. INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention. INGESTION: DO NOT induce vomiting. Seek medical attention immediately. Note: Never give anything by mouth to an unconscious or convulsing victim. Keep person warm and quiet. __________________________________________________________________________________________________________________________________________ SECTION 8 SPECIAL PROTECTION INFORMATION Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: Self-contained breathing apparatus if above TLV limit. Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit. None required if spraying. As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we recommend the use of safety glasses or chemical splash goggles. Other Protective Equipment: Long sleeves and long pants. Work/Hygienic Practices: Do not smoke while using. Wash hands after use. __________________________________________________________________________________________________________________________________________ SECTION 9 SPILL OR LEAK PROCEDURE Steps To Be Taken In Case Material Is Released or Spilled: Use absorbent sweeping compound to soak up material. Put into container. Dispose as hazardous waste. Waste Disposal Method: Dispose as hazardous waste in accordance with EPA RCRA. _________________________________________________________________________________________________________________________________________ SECTION 10 REGULATORY INFORMATION SARA Title III, Section 313 Components: None __________________________________________________________________________________________________________________________________________ This information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties, express or implied, and assume no liability in connection with any use of this information. 496655 MATERIAL SAFETY DATA SHEET (SIMILAR TO OSHA FORM 174) N.A. = Not Applicable Not Est. = Not Established Prop. = Proprietary SECTION 1 - MANUFACTURER / DISTRIBUTOR INFORMATION Product Name: FRESH START Concentrated Malodor Counteractant Supplier’s Name: National Chemical Laboratories of PA, Inc. Supplier’s Address: 401 N. 10th Street · Philadelphia PA 19123 HMIS Hazard Code: Health: 1 Flammability: 0 Reactivity: 0 Other: 0 Chemical Family: Odor Control Agent D.O.T. Shipping Name: N/A Product #: 1415 Emergency Phone #: CHEM-TEL (800) 255-3924 Chemical Name: N.A. Proprietary Blend Formula: N.A. Blended Product Hazard Class: N/A D.O.T. ID#: N/A SECTION 2 - HAZARDOUS INGREDIENTS CHEMICAL NAME None CAS NUMBER % Concentration Range Hazard Ratings (TLV/PEL) SECTION 3 - PHYSICAL DATA Specific Gravity: 1.001 Evaporation Rate: = To Water Boiling Point (°F): 212 Vapor Pressure: = To Water Vapor Density: = To Water Solubility in Water: Complete Appearance: Clear Blue Liquid Odor: Astra SECTION 4 - FIRE AND EXPLOSION DATA Flash Point (°F): None to boiling (TOC) Flammable Limits: Not Flammable Extinguising Media: Foam, CO2, water fog, BC/ABC extinguisher may be used in area where material is stored. Special Fire Fighting Procedures: None known Unusual Fire & Explosion Hazards: None known. SECTION 5 - HEALTH HAZARD DATA Route(s) of Entry: Inhalation: No Skin: Yes Ingestion: Yes Threshold Limit Value: Not Est. Effects of Overexposure: May cause skin and eye irritation. May be harmful if swallowed. Emergency & First Aid Procedures: For Eyes: Flush eyes with water for at least fifteen minutes. If irritation persists seek medical attention. For Skin: Flush skin thoroughly with water. If irritation persists seek medical attention. If ingested: Do not induce vomiting. Give large quantities of water. Seek medical attention. Never give anything by mouth to an unconscious person. Conditions Aggravated by Exposure: May aggravate pre-existing pulmonary conditions. Listed Carcinogen, Mutagen, Teratogen (Ingredient, Source, Amount): None SECTION 6 - REACTIVITY DATA Stability: Stable Conditions to Avoid: None Incompatibility: Avoid contact with acids and oxidizers. Hazardous Decomposition Products: None known Hazardous Polymerization: Will not occur. SECTION 7 - SPILL OR LEAK PROCEDURES Steps to be taken if material is released or spilled: Ventilate area and recontainerize by mopping, wet vacuum, or the use of a suitable absorbent. Waste disposal method: Follow local, state and federal regulations. SECTION 8 - SPECIAL PROTECTION INFORMATION Respiratory Protection: Not required Ventilation: Local Protective Gloves: Recommended for prolonged contact. Eye Protection: Goggles or safety glasses with side shields. Other Protective Equipment: None. SECTION 9 – SPECIAL PRECAUTIONS Precautions to be taken in handling and storage: Store between 40°F and 120°F. Avoid contact with skin and eyes. Do not ingest. Other Precautions: Keep out of reach of children. For professional use only. The information contained in this MSDS was obtained from current and reliable sources, however the data is provided without any warranty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of this company, it is not responsible for loss, injury and expense arising out of the product’s improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use or disposal of this product which may be covered by this MSDS. The user is responsible for full compliance. Date Prepared – 03/24/08 By: G.C. MATERIAL SAFETY DATA SHEET (SIMILAR TO OSHA FORM 174) N.A. = Not Applicable Not Est. = Not Established Prop. = Proprietary SECTION 1 - MANUFACTURER / DISTRIBUTOR INFORMATION Product Name: FRESH START Concentrated Malodor Counteractant Supplier’s Name: National Chemical Laboratories of PA, Inc. Supplier’s Address: 401 N. 10th Street · Philadelphia PA 19123 HMIS Hazard Code: Health: 1 Flammability: 0 Reactivity: 0 Other: 0 Chemical Family: Odor Control Agent D.O.T. Shipping Name: N/A Product #: 1415 Emergency Phone #: CHEM-TEL (800) 255-3924 Chemical Name: N.A. Proprietary Blend Formula: N.A. Blended Product Hazard Class: N/A D.O.T. ID#: N/A SECTION 2 - HAZARDOUS INGREDIENTS CHEMICAL NAME None CAS NUMBER % Concentration Range Hazard Ratings (TLV/PEL) SECTION 3 - PHYSICAL DATA Specific Gravity: 1.001 Evaporation Rate: = To Water Boiling Point (°F): 212 Vapor Pressure: = To Water Vapor Density: = To Water Solubility in Water: Complete Appearance: Clear Blue Liquid Odor: Astra SECTION 4 - FIRE AND EXPLOSION DATA Flash Point (°F): None to boiling (TOC) Flammable Limits: Not Flammable Extinguising Media: Foam, CO2, water fog, BC/ABC extinguisher may be used in area where material is stored. Special Fire Fighting Procedures: None known Unusual Fire & Explosion Hazards: None known. SECTION 5 - HEALTH HAZARD DATA Route(s) of Entry: Inhalation: No Skin: Yes Ingestion: Yes Threshold Limit Value: Not Est. Effects of Overexposure: May cause skin and eye irritation. May be harmful if swallowed. Emergency & First Aid Procedures: For Eyes: Flush eyes with water for at least fifteen minutes. If irritation persists seek medical attention. For Skin: Flush skin thoroughly with water. If irritation persists seek medical attention. If ingested: Do not induce vomiting. Give large quantities of water. Seek medical attention. Never give anything by mouth to an unconscious person. Conditions Aggravated by Exposure: May aggravate pre-existing pulmonary conditions. Listed Carcinogen, Mutagen, Teratogen (Ingredient, Source, Amount): None SECTION 6 - REACTIVITY DATA Stability: Stable Conditions to Avoid: None Incompatibility: Avoid contact with acids and oxidizers. Hazardous Decomposition Products: None known Hazardous Polymerization: Will not occur. SECTION 7 - SPILL OR LEAK PROCEDURES Steps to be taken if material is released or spilled: Ventilate area and recontainerize by mopping, wet vacuum, or the use of a suitable absorbent. Waste disposal method: Follow local, state and federal regulations. SECTION 8 - SPECIAL PROTECTION INFORMATION Respiratory Protection: Not required Ventilation: Local Protective Gloves: Recommended for prolonged contact. Eye Protection: Goggles or safety glasses with side shields. Other Protective Equipment: None. SECTION 9 – SPECIAL PRECAUTIONS Precautions to be taken in handling and storage: Store between 40°F and 120°F. Avoid contact with skin and eyes. Do not ingest. Other Precautions: Keep out of reach of children. For professional use only. The information contained in this MSDS was obtained from current and reliable sources, however the data is provided without any warranty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of this company, it is not responsible for loss, injury and expense arising out of the product’s improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use or disposal of this product which may be covered by this MSDS. The user is responsible for full compliance. Date Prepared – 03/24/08 By: G.C. U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET (Prepared According to 29 CFR 1910.1200) ______________________________________________________________________________ SECTION 1 IDENTIFICATION Product Name: Manufacturer's Name: Manufacturer's Address: Manufacturer's Phone Number: Emergency Phone Number: Proper Shipping Name: Effective Date: FORMULA 491963 ZENEZE FOGGER ZENEX International 7777 First Place, Cleveland Ohio 44146 (440) 232-4155 1-800-535-5053 Consumer Commodity, ORM-D 5-31-02 ______________________________________________________________________________ SECTION 2 Chemical Name: Water Surfactant Surfactant Methyl Ether Perfume IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS CAS No.: 7732-18-5 68298-20-4 68412-54-4 115-10-6 Proprietary TLV: Not applicable Not established Not established Not established Not available Carcinogen: No No No No No This formula contains no ingredients subject to the reporting requirements of SARA title III, section 313. ______________________________________________________________________________ SECTION 3 Boiling Point: Solubility in Water: Physical Description: PHYSICAL DATA <00 F Complete Clear liquid, unique scent Specific Gravity : Evaporation Rate(H2O=1): pH (Concentrate): 1.01 + .01 1.0 + 0.2 10.0 + 0.5 _______________________________________________________________________________________________________________________________________ SECTION 4 FIRE AND EXPLOSION HAZARD DATA Flash Point: Propellant: <00 F Flammable Limits: LEL: 3.4 UEL: 27 Extinguishing Media: Use water fog, dry chemical or carbon dioxide. Special Fire Fighting Procedures: Aerosol cans may rupture when heated Unusual Fire and Explosion Hazards: Heated cans may burst. _______________________________________________________________________________________________________________________________________ SECTION 5 Unstable______ Stable __X___ Incompatability (Materials to Avoid): Conditions to Avoid: Hazardous Decomposition or Byproducts: Hazardous Polymerization: REACTIVITY DATA Stability: None known. High temperatures. In fire, will decompose to carbon dioxide and carbon monoxide. Will not occur. __________________________________________________________________________________________________________________________________________ SECTION 6 STORAGE AND HANDLING INFORMATION Precautions to be Taken in Handling and Storing: When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved respirator. STORE AT TEMPERATURES BELOW 120oF KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME KEEP AWAY FROM CHILDREN FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY FOR USE BY TRAINED PERSONNEL ONLY KEEP CONTAINER CLOSED DURING STORAGE __________________________________________________________________________________________________________________________________________ SECTION 7 HEALTH HAZARDS AND FIRST AID Effects of Overexposure: SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible. EYES: Eye irritant. Will cause redness and burning sensation. INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness, nausea, and loss of coordination. Extreme overexposure may result in unconsciousness and possibly death. INGESTION: Aspiration hazard if swallowed. First Aid Procedures: SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get medical attention. Remove contaminated clothing and launder before reuse. EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Seek medical attention. INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention. INGESTION: DO NOT induce vomiting. Seek medical attention immediately. Note: Never give anything by mouth to an unconscious or convulsing victim. Keep person warm and quiet. __________________________________________________________________________________________________________________________________________ SECTION 8 SPECIAL PROTECTION INFORMATION Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: None normally required. Provide local exhaust. None required if spraying. ZENEX supports employee safety as priority #1. Therefore, we recommend the use of safety glasses or chemical splash goggles. Other Protective Equipment: Long sleeves and long pants. Work/Hygienic Practices: Do not smoke while using. Wash hands after use. __________________________________________________________________________________________________________________________________________ SECTION 9 SPILL OR LEAK PROCEDURE Steps To Be Taken In Case Material Is Released or Spilled: Use absorbent sweeping compound to soak up material. Put into container. Dispose as hazardous waste. Waste Disposal Method: Dispose as hazardous waste in accordance with EPA RCRA. _________________________________________________________________________________________________________________________________________ SECTION 10 REGULATORY INFORMATION SARA Title III, Section 313 Components: None __________________________________________________________________________________________________________________________________________ This information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties, express or implied, and assume no liability in connection with any use of this information. 491963 The Procter & Gamble Company P&G Household Care Fabric & Home Care Innovation Center 5299 Spring Grove Avenue Cincinnati, OH 45217-1087 MATERIAL SAFETY DATA SHEET MSDS #:FH/F/2007/RPRL-6YWNSS FH/F/2006/NMNE-6SCML6 Supersedes: FH/F/2004/VBVV-63YQ5Y Issue Date: 3/22/07 Issue Date: 8/30/04 SECTION I - PRODUCT IDENTIFICATION Identity: Fabric Refresher Finished Product Brands: FEBREZE FABRIC REFRESHER (Allergen Reducer, Extra Strength, Pet Odor Eliminator, Spring & Renewal, Meadows & Rain, Linen & Sky, Citrus & Light, Auto, and Lavender Vanilla & Comfort) P&G Telephone Number: 1-800-308-EASY (1-800-308-3279) or call Local Poison Control Center or your physician. SECTION II - HAZARDS IDENTIFICATION Potential Health Hazards (Acute and Chronic): (See Section 11 for more information) Ingestion: None known. Eye Contact: Mild eye irritant. Skin Contact: Prolonged skin contact may result in transient, superficial effects similar to those produced by mild toilet soap Inhalation: None known. Signs and Symptoms of Exposure: Ingestion: Possible mild gastrointestinal irritation with nausea, vomiting, and/or diarrhea. Eye Contact: Instillation into the eye may result in transient, superficial effects similar to those produced by mild toilet soap. Skin Contact: Prolonged skin contact may result in transient, superficial effects similar to those produced by mild toilet soap. Inhalation: None known. Medical Conditions Generally Known to be Aggravated by Exposure: None known. Potential Environmental Effects: (See Section 12 for more information) SECTION III - COMPOSITION AND INGREDIENTS Ingredients listed on the product label are: Water, alcohol, odor eliminator derived from corn, and fragrance. Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200. and/or WHMIS under the HPA: Common Name LD50/LC50 CAS No. Composition Chemical Name Range Ethyl Alcohol Ethanol 64-17-5 1-5% 7.06 g/kg rat, oral Febreze Fabric Refresher Page 1 of 5 SECTION IV – FIRST AID INFORMATION First Aid Procedures: Ingestion: Dilute with fluids and treat symptomatically. Eye Contact: Rinse well with water for at least 15 minutes. Skin Contact: Rinse with water. Inhalation: Remove to fresh air. Note to Physician: Treat symptomatically. Other: Consumer product package has the following precautionary statement: USE ONLY AS INTENDED. KEEP OUT OF THE REACH OF CHILDREN. Do not spray directly toward face. If eye contact occurs, rinse well with water. SECTION V - FIRE FIGHTING INFORMATION Flash Point (Method Used): Allergen Reducer: 136 ºF / 58 ºC (Closed Cup) Other scent variants: 156 – 159 ºF / 68 – 71 ºC (Closed Cup) Products do not sustain combustion (ASTM D 4206) Flammable Properties: Products are not considered flammable, and do not sustain combustion Upper Flammable Limit: N/K Lower Flammable Limit: N/K Explosive Limits: UEL: N/A LEL: N/A Auto-ignition Temperature: N/K Hazardous Combustion Products: None known Explosion Data (Sensitivity to Mechanical Impact): N/A Explosion Data (Sensitivity to Static Discharge): N/A Extinguishing Media: Suitable: CO2, water, or dry chemical may be used. Unsuitable: N/K Protection of Firefighters: Specific Hazards Arising from the Material: None known Protective Equipment and Precautions for Firefighters: Normal fire-fighting gear. SECTION VI - ACCIDENTAL RELEASE MEASURES Personal Precautions: None Environmental Precautions: Disposal is to be performed in compliance with federal, state/provincial and local regulations. Slowly flush down sewer with excess water or dispose as liquid scrap. Discard empty container in trash. Do not landfill liquids. Methods for Containment: Dike or contain spill. Absorb with inert material and dispose. Flush area with water. Prevent washings from entering waterways. Sorbents may be used. Methods for Cleanup: Use water spray to dilute and/or wash away spills to avoid exposure and to protect persons working to stop/repair leak. Any spills are to be prevented from entering waterways. Sorbents may be used. Other Information: (if applicable) Febreze Fabric Refresher Page 2 of 5 SECTION VII – HANDLING AND STORAGE Precautions To Be Taken in Handling: None. Precautions To B e Taken in Storage: Store at room temperature. SECTION VIII - EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines: Ethanol (CAS# 64-17-5) ACGIH-TLV 1000 ppm OSHA Z-1 PEL 1000 ppm Engineering Controls: None required Personal Protective Equipment (PPE): Eye/Face Protection: None required for normal consumer use. Industrial setting: If a splash of solution is likely, chemical goggles may be needed. Skin Protection: None required for normal consumer use. Industrial setting: Minimize skin contact with protective gloves (rubber or neoprene). Respiratory Protection: None required with normal consumer use. Industrial setting: Use ventilation to minimize exposure to vapor or mist (ethanol). SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES Appearance (color, physical form, shape): Flash Point (Method Used): Clear liquid Allergen Reducer: 136 ºF / 58 ºC (CC) Other scent variants: 156 – 159 ºF / 68 – 71 ºC (CC) Products do not sustain combustion (ASTM D 4206) Odor: Products are perfumed. Reserve Alkalinity: N/A Odor Threshold: N/A Solubility in Water: Soluble Physical State: Liquid Decomposition Temperature: N/A Vapor Pressure (mm Hg): N/A Evaporation Rate (nBuOAc=1): Vapor Density (Air=1): N/A Specific Gravity/Density: ~ 1.0 Boiling Point: ~ 212 ºF / ~ 100 ºC Melting/Freezing Point: N/A Partition Coefficient (n-octanol/water): N/A pH (100% solution): N/K Allergen Reducer: pH = 6.5 -6.9 Other scent variants: pH = 7.8 – 8.0 Volatile Organic Compound (VOC): Product complies with State and Federal regulations for VOC content. SECTION X - STABILITY AND REACTIVITY Chemical Stability: Stable Conditions to Avoid: N/K Incompatible Materials: N/K Hazardous Decomposition Products: N/K Possibility of Hazardous Reactions: N/K Febreze Fabric Refresher Page 3 of 5 SECTION XI - TOXICOLOGICAL INFORMATION Febreze is practically nontoxic. If ingested, it may be mildly irritating. LD50 (oral): > 5000 mg/kg (estimated). LD50 (dermal): > 5000 mg/kg (estimated). Chronic Effects: No chronic health effects reported. Target Organs: No target organs reported. Carcinogenicity: NTP: No IARC: No OSHA: No SECTION XII - ECOLOGICAL INFORMATION There are no concerns at relevant environmental concentrations. Based on ecotoxicity and fate data for the individual ingredients in this formulation and for similar consumer product formulations, this product is anticipated to be non-hazardous to the environment following consumer usage. SECTION XIII - DISPOSAL CONSIDERATIONS Waste Disposal Method: Disposal is to be performed in compliance with federal, state/provincial and local regulations. Non-household Setting (US Federal): Products covered by this MSDS, in their original form, when disposed as waste, are considered non hazardous waste according to Federal RCRA regulations (40 CFR 261). Disposal should be in accordance with local, state and federal regulations. Non-Household Setting (California): Not hazardous. Household Use: Product used in household may be disposed of in refuse or in sewer. SECTION XIV - TRANSPORT INFORMATION Ground Transport (US DOT): Products covered by this MSDS, in their original form, are not regulated for transportation. Air Transport (IATA): – not regulated Marine/Water Transport (IMDG): – not regulated Febreze Fabric Refresher Page 4 of 5 SECTION XV - REGULATORY INFORMATION United States: All intentionally-added components of this (these) product(s) are listed on the US TSCA Inventory. EPA Registration Number: Not Applicable SARA 313/302/304/311/312 chemicals: None California: This product has been evaluated and does not require warning labeling under California Proposition 65. California Registration Number: Not Applicable State Right-to-Know and CERCLA: The following ingredients present in the finished product are listed on state right-to-know lists or state worker exposure lists Ingredient Ethanol CAS # 64-17-5 Level 1-5% CERCLA RQ 100 lbs. IL X MA X State NJ X PA X RI X Canada: All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and this MSDS contains all information required by the Controlled Products Regulations. Other: Perfumes contained within the products covered by this MSDS comply with appropriate IFRA guidance. P&G Hazard Rating: *N/A. - Not Applicable SECTION XVI - OTHER INFORMATION Health: 1 4=EXTREME Flammability: 2 3=HIGH Reactivity: 0 2=MODERATE 1=SLIGHT 0=NOT SIGNIFICANT *N/K. - Not Known Data supplied is for use only in connection with occupational safety and health. DISCLAIMER: This MSDS is intended to provide a brief summary of our knowledge and guidance regarding the use of this material. The information contained here has been compiled from sources considered by Procter & Gamble to be dependable and is accurate to the best of the Company’s knowledge. It is not meant to be an allinclusive document on worldwide hazard communication regulations. This information is offered in good faith. Each user of this material needs to evaluate the conditions of use and design the appropriate protective mechanisms to prevent employee exposures, property damage or release to the environment. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, or for any damage to any property resulting from misuse of the product. Febreze Fabric Refresher Page 5 of 5 Material Safety Data Sheet GLADE ODOR COUNTERACTANT Fire Hazard National Fire Protection Association (NFPA) Health 4 0 0 Hazardous Material Information System (HMIS) Reactivity Health Fire Hazard 0 4 Reactivity 0 Specific Hazard Protective None required. Clothing Emergency Overview Colorless. Aerosol. See Section 9. CAUTION: CONTENTS UNDER PRESSURE. May be mildly irritating to eyes. Section 1. Chemical Product and Company Identification Product Name GLADE ODOR COUNTERACTANT Code 94783 Product Use Industrial/Institutional: Air care. PMS# 433317 126232001 Validation Date 04/19/2000 Print Date Supersedes 04/20/2000 04/13/2000. In Case of Emergency (800) 851-7145 MSDS# U.S. Headquarters Drackett Professional A Division of S.C. Johnson Commercial Markets, Inc. 8310 16th Street Sturtevant, Wisconsin 53177-0902 Phone: (888) 352-2249 Section 2. Composition and Information on Ingredients Ingredients CAS # % by Weight Exposure Limits Isobutane 75-28-5 5-10 Not available. Propane 74-98-6 5-10 Butane 106-97-8 10-30 Water 7732-18-5 60-100 TWA: 1800 (mg/m3) from OSHA (PEL) [United States] TWA: 4508 (mg/m3) from ACGIH (TLV) [United States] TWA: 1900 (mg/m3) from OSHA (PEL) [United States] TWA: 1900 (mg/m3) from ACGIH (TLV) [United States] Not available. LC50/LD50 VAPOR (LC50): Acute: 0.0057 ppm 0.25 hours [Rat]. Not available. Not available. Not applicable. Section 3. Hazards Identification Inhalation. Skin contact. Eye contact. Routes of Entry Potential Acute Health Effects Eyes May be mildly irritating to eyes. Skin None known. Inhalation None known. Ingestion None known. Medical Conditions None known. Aggravated by Overexposure: See Toxicological Information (section 11) Continued on Next Page Page: 1/4 Material Safety Data Sheet GLADE ODOR COUNTERACTANT Section 4. First Aid Measures Eye Contact Flush immediately with plenty of water. Get medical attention if irritation occurs. Skin Contact Rinse with plenty of running water. Inhalation No specific first aid measures are required. Ingestion No specific first aid measures are required. Section 5. Fire Fighting Measures Flammability of the Product Flash Points NFPA 30B Level 1 Aerosol. CLOSED CUP: <-7°C (19.4°F). Products of Combustion None known. Fire Fighting Media and Instructions Special Remarks on Fire and Explosion Hazards Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire fighting procedure may be used. Aerosol product - Containers may rocket or explode in heat of fire. Section 6. Accidental Release Measures Personal Precautions Put on appropriate personal protective equipment (see Section 8). Environmental Precautions and Clean-up Methods In the event of major spillage: Use appropriate containment to avoid environmental contamination. Sweep or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a water rinse for final clean-up. Section 7. Handling and Storage Handling Avoid contact with eyes. Do not puncture or incinerate. FOR INDUSTRIAL USE ONLY Storage Store in a dry, cool and well-ventilated area. Protect from freezing. Keep away from heat, sparks and flame. Pressurized container: protect from sunlight and do not expose to temperature exceeding 50°C. Do not pierce or burn, even after use. KEEP OUT OF REACH OF CHILDREN. Section 8. Exposure Controls/Personal Protection Engineering Controls No special ventilation requirements. General room ventilation is adequate. Personal Protection Eyes No special protective clothing is required. Hands No special protective clothing is required. Respiratory No special protective clothing is required. Feet No special protective clothing is required. Body No special protective clothing is required. Section 9. Physical and Chemical Properties Physical State and Appearance Odor Liquid. (Aerosol.) Color Colorless. pH Not applicable. Solubility in water Complete. Fragrance like. Continued on Next Page Page: 2/4 Material Safety Data Sheet GLADE ODOR COUNTERACTANT Section 10. Stability and Reactivity Stability and Reactivity The product is stable. Conditions of Instability Excessive heat. Incompatibility with Various Substances Not available. Hazardous Decomposition Products Produces normal products of combustion. Hazardous Polymerization Will not occur. Section 11. Toxicological Information ORAL (LD50) Estimated to be greater than 5000 mg/kg (rat). Acute toxicity Effects of Chronic Exposure None known. Not available. Other Toxic Effects Section 12. Ecological Information Not available. Section 13. Disposal Considerations If possible, recycle empty aerosol cans to the nearest steel recycling center. Use up package or give to someone who can. Dispose of according to all federal, state and local regulations. Waste Information Section 14. Transport Information DOT Classification Aerosols DOT Proper Shipping Name DOT Class CLASS 2.1: Flammable gas. UN/NA UN1950 DOT Special Considerations Limited Quantity TDG Classification TDG Proper Shipping Name TDG Class Aerosols PIN/NIP UN1950 TDG Special Considerations Limited Quantity CLASS 2.1: Flammable gas. Section 15. Regulatory Information Reporting in this section is based on ingredients disclosed in Section 2 US Regulations Federal Clean air act (CAA) 112 accidental release prevention: Butane Clean air act (CAA) 112 regulated flammable substances: Propane, Isobutane, Butane CERCLA: Hazardous substances.: Propane, Isobutane State New Jersey: Propane, Isobutane, Butane Massachusetts spill list: Propane, Isobutane, Butane Massachusetts RTK: Propane, Isobutane, Butane Pennsylvania RTK: Propane, Isobutane, Butane This product is not subject to the reporting requirements under California's Proposition 65. Registered Product Not applicable. Information Canadian Regulations WHMIS Classification CLASS A: Compressed gas. Continued on Next Page Page: 3/4 Material Safety Data Sheet GLADE ODOR COUNTERACTANT WHMIS Icon Registered Product Not applicable. Information Chemical Inventory Status All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Section 16. Other Information Other Special Considerations Version Not available. 1 Notice to Reader This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Material Safety Data Sheet Section 1. Product and Company Identification Product Name Product Description Manufacturer LYSOL® BRAND II DISINFECTANT SPRAY, ALL SCENTS (AEROSOL) CANADIAN MSDS# Validation Date Antibacterial action. Kills viruses, bacteria, mold and mildew. Eliminates odours. Print Date Reckitt Benckiser (Canada) Inc. 2 Wickman Road Toronto, Ontario M8Z 5M5 Product Identifier Reg. No. 25094, P.C.P. Act Item Number 59631-50709-06 Not available. 2/28/2006 2/28/2006 In case of Emergency: Telephone: 800-888-0192 Transportation Emergencies: Chemtrec: 1-800-424-9300 (U.S. & Canada) Outside the U.S & Canada (North America), call: 703-527-3887 Formula Number 432-124A (359979) Original scent; 147-082 (356595) Country scentTM; 147-083 (356596) Mountain scent; 73-087 (356593) Fresh scent; 258-011 (356597) Linen®; 192-031 (364000) Soft Powder®; 550-095 (367851) Spring WaterfallTM. UPC Number 59631-33072, 59631-50706 (Original/Parfum Originale); 59631-34082, 59631-50709 (Country/Parfum Campagnard); 59631-50615 (Mountain Air/Parfum de Montagne); 59631-32102 (Fresh/Parfum de Fraîcheur); 59631-26710, -34052 & -50710 (Linen/Linge); 59631-75571 (Spring Waterfall/Chute D'Eau Printainière) & 59631-75393 (364000) Soft Powder/Parfum Tendre de Poudre. Section 2. Composition and Information on Ingredients Name CAS # 1) ETHANOL 64-17-5 79 124-38-9 4.0 2) CARBON DIOXIDE % by Weight Exposure Limits : TLV/PEL TWA: 1880 (mg/m3) from ACGIH (TLV) TWA: 1000 (ppm) from ACGIH (TLV) TWA: 1900 (mg/m3) from OSHA (PEL) TWA: 1000 (ppm) from OSHA (PEL) TWA: 9000 (mg/m3) from ACGIH (TLV) TWA: 5000 (ppm) from ACGIH (TLV) TWA: 9000 STEL: 54 (mg/m3) from OSHA (PEL) TWA: 5000 (ppm) from OSHA (PEL) Section 3. Hazards Identification Emergency Overview DANGER: Extremely Flammable. Container may explode if heated. Keep away from heat, sparks and open flame. Exposure to temperatures above 55º C (130º F) may cause bursting. Causes eye irritation. Do not spray in eyes, on skin or on clothing. KEEP OUT OF REACH OF CHILDREN. Section 4. First Aid Measures Eye Contact In case of eye contact, hold eyes open and IMMEDIATELY rinse eyes thoroughly with plenty of water. Remove any contact lenses and continue rinsing for at least 15 minutes. If irritation persists, consult a physician. Skin Contact In keeping with good hygienic practices, wash exposed areas thoroughly with soap and water. Inhalation None required under recommended use conditions. Remove to fresh air. Ingestion Call a physician or poison control center immediately. Contains denatured ethanol; ingestion may result in ethanol poisoning. NEVER give an unconscious person anything to ingest. Continued on Next Page LYSOL® BRAND II DISINFECTANT SPRAY, ALL SCENTS (AEROSOL) - CANADIAN Page Number: 2 Section 5. Fire and Explosion Data Flammability Extremely flammable. See Section 14 for any Shipping Classifications. Flash Point Not applicable. Aerosol flame extension greater than 18 inches or 45 cm. Explosive Limits in Air LOWER: 3.3% UPPER: 19% Products of Combustion Carbon monoxide, carbon dioxide and other unknown organic compounds. Fire and Explosion Hazards Contents under pressure. Do not use in presence of open flame or sparks. Do not puncture or incinerate container or store at temperatures over 50°C. Container may explode if heated. Fire Fighting Media and Instructions Use DRY chemicals, CO2, water spray or foam. Use extinguishing media suitable for surrounding materials. Special Fire Fighting Instructions Product contents under pressure. Cool containers with water spray. Wear full protective equipment: eye/face (shield), body (full bunker gear), respiratory (SCBA). Provide shielding for venting, rupturing or bursting containers. Move containers away from fire, if possible and safe to do so. Section 6. Accidental Release Measures Accidental Spill Small spills: Eliminate all sources of ignition. Absorb with an inert material and place in appropriate waste disposal container. Large spills: Eliminate all sources of ignition and ventilate the area with equipment rated for use in flammable environments. Collect liquid and store in metal containers for later disposal according to local, provincial or federal regulations. Section 7. Handling and Storage Handling and Storage DANGER: Extremely flammable. Container may explode if heated. Contents under pressure. Do not use in presence of open flame or sparks. Do not puncture or incinerate container or store at temperatures over 50°C. Causes eye irritation. Do not spray in eyes, on skin or on clothing. Avoid contact with eyes or food. KEEP OUT REACH OF CHILDREN. It is an offence under the PEST CONTROL PRODUCTS ACT to use a control product under unsafe conditions. Section 8. Exposure Controls/Personal Protection Ventilation Requirements None required. General ventilation should be sufficient to control airborne levels. Eye Protection Avoid contact with eyes. Emergency responders should wear full eye and face protection. Skin Protection May cause mild skin irritation after prolonged or repeated use. Emergency responders should wear impermeable gloves. Respiratory Protection None required under normal use conditions. Emergency responders should wear suitable respiratory protection where long term exposure to vapors from large areas of spilled liquid is possible such as a major spill, a fire or a clean-up operation. Other Protection None required under normal use conditions. Work/Hygienic Practices Washing with soap and water after use is recommended as good hygienic practice to prevent possible skin irritation and / or eye irritation from the residue that may be left on the hands. Continued on Next Page Page Number: 3 LYSOL® BRAND II DISINFECTANT SPRAY, ALL SCENTS (AEROSOL) - CANADIAN Section 9. Physical and Chemical Properties Description Aerosol spray. Odor Various scents. pH 10 [Basic.] Color Clear (Spray mist). Boiling/Condensation Point Not available. Specific Gravity 0.835 @ 25°C Vapor Pressure 95-105 psig. Vapor Density The highest known value is 1.6 (Air = 1) (ETHANOL). Viscosity Not available. Solubility Complete. Physical Chemical Comments Not available. Section 10. Stability and Reactivity Data Chemical Stability The product is stable. Conditions of Instability Danger: Extremely flammable. Container may explode if heated. Contents under pressure. Do not use in presence of open flame or sparks. Do not puncture or incinerate container or store at temperatures over 50°C. Incompatibility with Various Substances Do not use on polished wood furniture, rayon fabrics or acrylic plastics. Avoid contact with food. Hazardous Decomposition Products Toxic sulfur oxides can be released if heated to decomposition temperature. Hazardous Polymerization Will not occur. Section 11. Toxicological Information Exposure effects Eye Contact Avoid contact with eyes. Causes eye irritation. Skin Contact None expected under recommended use conditions. Prolonged or repeated skin contact may result in slight to moderate skin irritation. Inhalation None expected. Ingestion Contains denatured alcohol; ingestion may result in ethanol poisoning. Carcinogenicity Not listed as carcinogenic by OSHA, NTP or IARC. Section 12. Ecological Information Ecotoxicity Not available. Continued on Next Page Page Number: 4 LYSOL® BRAND II DISINFECTANT SPRAY, ALL SCENTS (AEROSOL) - CANADIAN Section 13. Disposal Considerations Waste Disposal This container may be recycled in communities where aerosol can recycling is available. Before offering for recycling, empty the can by using product according to the label (DO NOT PUNCTURE OR INCINERATE). If recycling is not available, contact your municipality or provincial Ministry of Environment for disposal information. Section 14. Transport Information DOT Classification ORM-D Proper Shipping Name Consumer Commodity DOT Identification Number Not applicable. Packing Group Not applicable Maritime Transportation Not applicable. Hazardous Substances Reportable Quantity Not applicable. Special Provisions for Transport Not applicable. TDG Classification Consumer Commodity - Transborder Consignment. ADR Classification Not applicable. IMDG Classification Aerosols, Class 2.1, UN1950 - Limited Quantity. IATA Classification Consumer Commoditity, 9 ID8000 Section 15. Regulatory Information Federal and State Regulations SARA Title III, Section 313 Toxic Chemical Notification & Release Reporting: None California Proposition 65: This product contains the following ingredients which require a warning under the Safe Drinking Water & Toxic Enforcement Act: None Other Classifications WHMIS (Canada) CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). Section 16. Other Information HMIS (U.S.A.) Health Hazard Fire Hazard Reactivity Personal Protection 1 3 0 B Continued on Next Page 1 Health 1 0 Reactivity Specific hazard NFPA Aerosol Level Validated by Product Safety on 2/28/2006. Fire Hazard National Fire Protection Association (U.S.A.) Printed 2/28/2006. 1, per NFPA 30B LYSOL® BRAND II DISINFECTANT SPRAY, ALL SCENTS (AEROSOL) - CANADIAN Page Number: 5 Notice to Reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET (Prepared According to 29 CFR 1910.1200) ______________________________________________________________________________ SECTION 1 IDENTIFICATION Product Name: Manufacturer's Name: Manufacturer's Address: Manufacturer's Phone Number: Emergency Phone Number: Proper Shipping Name: Effective Date: FORMULA 494725 ZENABRITE LEMON ZENEX International 7777 First Place, Cleveland Ohio 44146 (440) 232-4155 1-800-535-5053 Consumer Commodity, ORM-D 10-15-01 ______________________________________________________________________________ SECTION 2 IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS Chemical Name: Isoparaffinic HC Solvent Butane Propane Poly (dimethylsiloxane) CAS No.: 64742-48-9 106-97-8 74-98-6 63148-62-9 TLV: Not Established 800ppm 2500ppm Not Established ______________________________________________________________________________ SECTION 3 Boiling Point: Solubility in Water: Vapor Density(Air=1): PHYSICAL DATA <0 to 3720 F Nil Heavier than air Specific Gravity(H2O=1): Evaporation Rate: pH: 0.89 + 0.05 Slower than Ether NA _______________________________________________________________________________________________________________________________________ SECTION 4 FIRE AND EXPLOSION HAZARD DATA Flash Point: Flash Point(Propellant): Flammable Limits(Propellant): Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: Non-Flammable 7OF LEL: 1.3 UEL: 9.8 Use water fog, dry chemical or carbon dioxide. Aerosol cans may rupture when heated. Heated cans may burst. _______________________________________________________________________________________________________________________________________ SECTION 5 Unstable______ Stable __X___ Incompatability (Materials to Avoid): Conditions to Avoid: Hazardous Decomposition or Byproducts: Hazardous Polymerization: REACTIVITY DATA Stability: None known. High temperatures. In fire, will decompose to carbon dioxide, carbon monoxide Will not occur __________________________________________________________________________________________________________________________________________ SECTION 6 STORAGE AND HANDLING INFORMATION Precautions to be Taken in Handling and Storing: When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved respirator. STORE AT TEMPERATURES BELOW 120oF KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME KEEP AWAY FROM CHILDREN FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY FOR USE BY TRAINED PERSONNEL ONLY KEEP CONTAINER CLOSED DURING STORAGE __________________________________________________________________________________________________________________________________________ SECTION 7 HEALTH HAZARDS AND FIRST AID Effects of Overexposure: SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible. EYES: Eye irritant. Will cause redness and burning sensation. INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness, nausea, and loss of coordination.Extreme overexposure may result in unconsciousness and possibly death. INGESTION: Aspiration hazard if swallowed. First Aid Procedures: SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get medical attention. Remove contaminated clothing and launder before reuse. EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Seek medical attention. INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention. INGESTION: DO NOT induce vomiting. Seek medical attention immediately. Note: Never give anything by mouth to an unconscious or convulsing victim. Keep person warm and quiet. __________________________________________________________________________________________________________________________________________ SECTION 8 SPECIAL PROTECTION INFORMATION Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: Self-contained breathing apparatus if above TLV limit. Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit. None required if spraying. As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we recommend the use of safety glasses or chemical splash goggles. Other Protective Equipment: Long sleeves and long pants. Work/Hygienic Practices: Do not smoke while using. Wash hands after use. __________________________________________________________________________________________________________________________________________ SECTION 9 SPILL OR LEAK PROCEDURE Steps To Be Taken In Case Material Is Released or Spilled: Use absorbent sweeping compound to soak up material. Put into container. Dispose as hazardous waste. Waste Disposal Method: Dispose as hazardous waste in accordance with EPA RCRA. _________________________________________________________________________________________________________________________________________ SECTION 10 REGULATORY INFORMATION SARA Title III, Section 313 Components: None __________________________________________________________________________________________________________________________________________ This information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties, express or implied, and assume no liability in connection with any use of this information. 494725 MATERIAL SAFETY DATA SHEET 81410 02 00 =========================================================================== Section 1 −− PRODUCT AND COMPANY IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT NUMBER HMIS CODES Health 2 81410 Flammability 2 Reactivity 0 PRODUCT NAME DURA SEAL* DURA FINISH* Liquid Floor Wax, Neutral MANUFACTURER’S NAME EMERGENCY TELEPHONE NO. MINWAX Company (216) 566−2917 10 Mountainview Road Upper Saddle River, NJ 07458 DATE OF PREPARATION INFORMATION TELEPHONE NO. 31−MAR−07 (800) 364−1359 =========================================================================== Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 51 64742−88−7 Mineral Spirits ACGIH TLV 100 ppm 2 mm OSHA PEL 100 ppm 3 64741−65−7 Mineral Spirits (Odorless) ACGIH TLV 100 ppm 1 mm OSHA PEL 100 ppm =========================================================================== Section 3 −− HAZARDS IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Continued on page 2 81410 page 2 =========================================================================== Section 4 −− FIRST AID MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re−use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. =========================================================================== Section 5 −− FIRE FIGHTING MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− FLASH POINT LEL UEL 103 F PMCC 1.0 7.0 FLAMMABILITY CLASSIFICATION Combustible, Flash above 99 and below 200 F EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build−up of pressure) when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self−contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build−up and possible autoignition or explosion when exposed to extreme heat. =========================================================================== Section 6 −− ACCIDENTAL RELEASE MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. =========================================================================== Section 7 −− HANDLING AND STORAGE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STORAGE CATEGORY DOL Storage Class II Continued on page 3 81410 page 3 =========================================================================== PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Contents are COMBUSTIBLE. Keep away from heat and open flame. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. To minimize the possibility of spontaneous combustion: control the accumulation of overspray; soak wiping rags and waste immediately after use in a water−filled, closed metal container; air dry filters outside, far from any combustible material and separated by bricks or other non−combustible spacers; dispose of all contaminated materials and waste properly. Consult OSHA 29 CFR 1910.107(b)(5) and NFPA 33, Chapter 8 (8−9) for the proper procedures. =========================================================================== Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1−800−424−LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Continued on page 4 81410 page 4 =========================================================================== Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT WEIGHT 7.28 lb/gal 872 g/l SPECIFIC GRAVITY 0.88 BOILING POINT 212 − 412 F 100 − 211 C MELTING POINT Not Available VOLATILE VOLUME 78 % EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 7.2 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical − As Packaged) 4.73 lb/gal 566 g/l Less Water and Federally Exempt Solvents 3.90 lb/gal 468 g/l Emitted VOC =========================================================================== Section 10 −− STABILITY AND REACTIVITY −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STABILITY −− Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur =========================================================================== Section 11 −− TOXICOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver and urinary systems. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− TOXICOLOGY DATA CAS No. Ingredient Name −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 64742−88−7 Mineral Spirits LC50 RAT 4HR Not Available LD50 RAT Not Available 64741−65−7 Mineral Spirits (Odorless) LC50 RAT 4HR Not Available LD50 RAT Not Available =========================================================================== Section 12 −− ECOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ECOTOXICOLOGICAL INFORMATION No data available. Continued on page 5 81410 page 5 =========================================================================== Section 13 −− DISPOSAL CONSIDERATIONS −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. =========================================================================== Section 14 −− TRANSPORT INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− US Ground (DOT) May be Classed as a Combustible Liquid for U.S. Ground. UN1263, PAINT, 3, PG III, (ERG#128) Bulk Containers may be Shipped as: UN1263, PAINT, COMBUSTIBLE LIQUID, PG III, (ERG#128) Canada (TDG) May be Classed as a Combustible Liquid for Canadian Ground. UN1263, PAINT, CLASS 3, PG III, (ERG#128) IMO UN1263, PAINT, CLASS 3, PG III, (39 C c.c.), EmS F−E, S−E =========================================================================== Section 15 −− REGULATORY INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. =========================================================================== Section 16 −− OTHER INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Material Safety Data Sheet U. S. Department of Labor May be used to comply with OSHA's Hazard Communication Standard 29 CFR 1910.1200. Standard must be consulted for specific requirements. Occupational Safety and Health Administration (Non-Mandatory Form) Form Approved IDENTITY (As Used on Label and List) NOTE: Blank spaces are not permitted. If any item is not applicable, or no information is available, the space must be marked to indicate that. Bab-O Powdered Cleanser OMB No. 1218-0072 SECTION I Manufacturer's Name Emergency Telephone Number Fitzpatrick Bros., Inc. (262) 947-3500 X 617 Address (Number, Street, City, State and ZIP Code) Telephone Number for Information (262) 947-3500 X 617 Date Prepared 625 North Sacramento Boulevard 07/25/2005 Signature of Preparer (optional) Chicago, Illinois 60612 SECTION II - Hazardous Ingredients/Identity Information Hazardous Components (Specify Chemical Identity: Common Name[s]) OSHA PEL THIS PRODUCT CONTAINS: ACGIH TLV Other Limits Recommended % (optional) Calcium Carbonate (CAS# 1317-65-3) Sodium Carbonate (CAS# 497-19-8) Sodium Dodecylbenzene Sulfonate (CAS# 25155-30-0 These basic materials have been identified as eye, skin, mucous membrane irritants. SECTION III - Physical/Chemical Characteristics Boiling Point Specific Gravity (H2O = 1) N/A N/A Vapor Pressure (mm Hg.) Melting Point N/A N/A Vapor Density (AIR = 1) Evaporation Rate (Butyl Acetate = 1) N/A N/A Solubility in Water Partially soluble in water Appearance and Odor White powder, no odor SECTION IV - Fire and Explosion Hazard Data Flash Point (Method Used) Flammable Limits N/A N/A Extinguishing Media Not a fire or explosive hazard Special Fire Fighting Procedures None Unusual Fire and Explosion Hazards None (Reproduce locally) Page 1 LEL UEL N/A N/A SECTION V - Reactivity Data Stability Unstable Stable Conditions to Avoid X Do not mix with ammonia or other household chemicals Incompatability (Materials to Avoid) Hazardous Decomposition or Byproducts Hazardous Polymerization May Occur Will Not Occur Conditions to Avoid X SECTION VI - Health Hazard Data Routes of Entry: Inhalation? Skin? Yes Ingestion? No No Health Hazards (Acute and Chronic) This material is identified as an irritant to eyes and the respiratory tract. Scouring powder is not irritating to the skin and is harmful if swallowed. Carcinogenicity: NTP? IARC Monographs? OSHA Regulated? Non-carcinogen Signs and Symptoms of Exposure Eye and mucous membrane irritation Medical Conditions Generally Aggravated by Exposure Avoid contact with eyes. Avoid breathing dust. Emergency and First Aid Procedures In case of contact with eyes, wash with plenty of water for at least 15 minutes. Get medical attention if excessive inhalation occurs. Remove victim to fresh air. SECTION VII - Precautions for Safe Handling and Use Steps to be Taken in Case Material is Released or Spilled Normal clean-up procedures Waste Disposal Method Conform to state, federal and local regulations Precautions to be Taken in Handling and Storing Store in cool, dry, ventilated area Other Precautions SECTION VIII - Control Measures Respiratory Protection (Specify Type) If dusty, wear mask Ventilation Local Exhaust Special Natural Mechanical (General) Other Protective Gloves Eye Protection If needed Wear goggles, if needed Other Protective Clothing or Equipment Optional Work/Hygienic Practices Page 2 Material Safety Data Sheet PROFESSIONAL VANISH MILDEW STAIN CLEANER Fire Hazard National Fire Protection Association (NFPA) Health 1 2 0 Hazardous Material Information System (HMIS) Reactivity Health Fire Hazard Reactivity 2 1 0 Specific Hazard Emergency Straw color. Liquid. See Section 9. WARNING: CAUSES EYE IRRITATION. May be mildly Overview irritating to skin. Protective Clothing Section 1. Chemical Product and Company Identification Product Name PROFESSIONAL VANISH MILDEW STAIN CLEANER Code Product Use MSDS# 90156 Industrial/Institutional: Washroom care. PMS# 433230 126095001 Validation Date 6/26/2003 Print Date Supersedes 6/26/2003 No Previous Validation In Case of Emergency (800) 851-7145 U.S. Headquarters Drackett Professional A Division of S.C. Johnson Commercial Markets, Inc. 8310 16th Street Sturtevant, Wisconsin 53177-0902 Phone: (888) 352-2249 Section 2. Composition and Information on Ingredients Ingredients CAS # % by Weight Sodium Hydroxide 1310-73-2 1-5 Sodium Hypochlorite Tert-butyl Alcohol 7681-52-9 75-65-0 1-5 1-5 Water 7732-18-5 60-100 Exposure Limits OSHA (United States). CEIL: 2 mg/m3 ACGIH (United States). STEL: 2 mg/m3 Not available. OSHA (United States). TWA: 300 mg/m3 ACGIH (United States). TWA: 303 mg/m3 Not available. LC50/LD50 Not available. Not available. ORAL (LD50): Acute: 3500 mg/kg [Rat]. Not available. Section 3. Hazards Identification Inhalation. Skin contact. Eye contact. Routes of Entry Potential Acute Health Effects Eyes May be moderately irritating to eyes. Skin May be mildly irritating to skin. Inhalation May be irritating to nose, throat, and respiratory tract. Ingestion May cause abdominal discomfort, nausea, vomiting and diarrhea. Medical Conditions Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, emphysema, etc., may Aggravated by Overexposure: be more susceptible to irritating effects. See Toxicological Information (section 11) Continued on Next Page Page: 1/4 Material Safety Data Sheet PROFESSIONAL VANISH MILDEW STAIN CLEANER Section 4. First Aid Measures Eye Contact Flush immediately with plenty of water. If irritation persists, get medical attention. Skin Contact Flush immediately with plenty of water. Get medical attention if irritation occurs. Inhalation If breathing is difficult: Remove to fresh air. Get medical attention immediately. Ingestion Immediately drink plenty of water. If discomfort persists, get medical attention. Section 5. Fire Fighting Measures Flammability of the Product None known. CLOSED CUP: >103°C (217.4°F). Flash Points None known. Products of Combustion Fire Fighting Media Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire and Instructions fighting procedure may be used. Special Remarks on Fire and None known. Explosion Hazards Section 6. Accidental Release Measures Personal Precautions Put on appropriate personal protective equipment (see Section 8). Environmental Precautions and Clean-up Methods In the event of major spillage: Use appropriate containment to avoid environmental contamination. Sweep or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a water rinse for final clean-up. Section 7. Handling and Storage Handling Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage Store in a dry, cool and well-ventilated area. Protect from freezing. KEEP OUT OF REACH OF CHILDREN. Section 8. Exposure Controls/Personal Protection Engineering Controls Good general ventilation should be sufficient to control airborne levels. Respiratory protection is not required if good ventilation is maintained. Personal Protection Eyes Safety glasses recommended. Hands For prolonged or repeated contact with skin: Rubber gloves. Respiratory No special requirements under normal use conditions. Feet No special requirements under normal use conditions. Body No special protective clothing is required. Section 9. Physical and Chemical Properties Physical State and Appearance Odor Liquid. Color Straw color. pH 12.8 [Basic.] Specific Gravity 1 Evaporation Rate <1 Solubility in water Complete. Bleach. Continued on Next Page Page: 2/4 Material Safety Data Sheet PROFESSIONAL VANISH MILDEW STAIN CLEANER Section 10. Stability and Reactivity Stability and Reactivity The product is stable. Conditions of Instability None known. Incompatibility with Various Avoid mixing with: acids , Ammonia. Do not mix with any other chemicals or products unless specified by label. Substances Hazardous Decomposition Products When exposed to fire: Produces normal products of combustion. Hazardous Polymerization Will not occur. Section 11. Toxicological Information ORAL (LD50) Estimated to be greater than 5000 mg/kg (rat). DERMAL (LD50) Between 2000 - 20000 mg/kg (rat). Acute toxicity Effects of Chronic Exposure None known. Not available. Other Toxic Effects Section 12. Ecological Information Not available. Section 13. Disposal Considerations No special precautions. Dispose of according to all federal, state and local regulations. Waste Information Section 14. Transport Information DOT Classification Please refer to the Bill of Lading/receiving documents for up to date shipping information. DOT Proper Shipping Name TDG Classification Please refer to the Bill of Lading/receiving documents for up to date shipping information. TDG Proper Shipping Name Section 15. Regulatory Information Reporting in this section is based on ingredients disclosed in Section 2 US Regulations Federal SARA 313 toxic chemical notification and release reporting: Tert-butyl Alcohol Clean Water Act (CWA) 311: Sodium hydroxide, Sodium Hypochlorite CERCLA: Hazardous substances.: Sodium hydroxide, Sodium Hypochlorite, Tert-butyl Alcohol State New Jersey spill list: Sodium hydroxide, Sodium Hypochlorite, Tert-butyl Alcohol New Jersey: Sodium hydroxide, Sodium Hypochlorite, Tert-butyl Alcohol Massachusetts spill list: Sodium hydroxide, Sodium Hypochlorite, Tert-butyl Alcohol Massachusetts RTK: Sodium hydroxide, Sodium Hypochlorite, Tert-butyl Alcohol Pennsylvania RTK: Sodium hydroxide, Sodium Hypochlorite, Tert-butyl Alcohol This product is not subject to the reporting requirements under California's Proposition 65. Registered Product Not applicable. Information Canadian Regulations WHMIS Classification Not applicable. WHMIS Icon Registered Product Not applicable. Information Chemical Inventory Status All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory Continued on Next Page Page: 3/4 Material Safety Data Sheet PROFESSIONAL VANISH MILDEW STAIN CLEANER Section 16. Other Information Other Special Considerations Version Not available. 1.01 Notice to Reader This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. FICHE DE DONNÉES DE SÉCURITÉ CARPET SCIENCE Détachant HMIS Santé Risque d'incendie Réactivité NFPA 1 1 0 1 1 0 Protection individuelle None / Aucune / Ninguno None / Aucune / Ninguno Numéro de révision: 1 Date de révision: 2007-06-08 1. IDENTIFICATION DE LA SUBSTANCE/PREPARATION ET DE LA SOCIETE/ENTREPRISE Nom du produit: CARPET SCIENCE Détachant MSDS #: Code du produit: Utilisation recommandée: 126097001 94350 Industriel/Institutionnel. Soins des Moquettes . Producteur, importateur, fournisseur: US Headquarters JohnsonDiversey, Inc. 8310 16th St. Sturtevant, Wisconsin 53177-0902 Phone: 1-888-352-2249 MSDS Internet Address: www.johnsondiversey.com Téléphone en cas d'urgence: Canadian Headquarters JohnsonDiversey - Canada, Inc. 2401 Bristol Circle Oakville, Ontario L6H 6P1 Phone: 1-800-668-3131 1-800-851-7145 (Prosar); 1-651-917-6133 (Int'l Prosar); 01-800-710-3400 (México) 2. IDENTIFICATION DES DANGERS Aperçu des premiers secours ATTENTION. PEUT IRRITER MODÉRÉMENT LES YEUX. PEUT IRRITER MODÉRÉMENT LA PEAU . LIQUIDE ET VAPEUR COMBUSTIBLES. Principales voies entree: Contact avec les yeux: Contact avec la peau: Inhalation: Ingestion: Contact avec les yeux. Contact avec la peau. Inhalation. Peut irriter modérément les yeux. Peut irriter modérément la peau. Aucun à notre connaissance. Aucun à notre connaissance. 3. COMPOSITION/INFORMATION SUR LES COMPOSANTS Composants Dangereux Composant(s) Alcool isopropylique CAS # 67-63-0 % en poids 1 - 5% DL50 Orale =4396 mg/kg DL50 Cutanée =12800 mg/kg CL50 Inhalatoire =72.6 mg/L (4 h) 4. PREMIERS SOINS Contact avec les yeux: Contact avec la peau: Inhalation: Ingestion: Conditions médicales aggravées: Rincer immédiatement à grande eau . Si une irritation apparaît, consulter un médecin. Rincer immédiatement à grande eau . Si une irritation apparaît, consulter un médecin.. Les premiers secours ne sont pas nécessaires. Les premiers secours ne sont pas nécessaires. Aucun à notre connaissance. 5. MESURES DE LUTTE CONTRE L'INCENDIE Moyen d'extinction approprié: Dangers spécifiques: Risques Inhabituels Méthodes particulières d'intervention: Poudre, eau pulvérisée, mousse, dioxide de carbone. Alors que ce produit possede un point d'eclair inferieur a 200 Deg. F, il constitue une solution aqueuse a base d'alcool qui ne soutient pas la combustion . Aucun à notre connaissance Aucune méthodes spéciale n'est requise . Equipements spéciaux pour la protection des intervenants: Comme pour tout incendie, porter un respirateur à air comprimé, MSHA/NIOSH (approuvé ou équivalent), ainsi qu'une combinaison complète de protection Moyen d'extinction à ne pas utiliser pour des raisons de sécurité: Pas d'information disponible 6. MESURES A PRENDRE EN CAS DE DÉVERSEMENT ACCIDENTEL Précautions individuelles: CARPET SCIENCE Détachant Revêtir un équipement de protection individuelle approprié (voir Section 8). 1 of 3 6. MESURES A PRENDRE EN CAS DE DÉVERSEMENT ACCIDENTEL Méthodes de nettoyage: Utiliser un récipient approprié pour éviter toute contamination du milieu ambiant. Absorber l'écoulement avec un matériau inerte (p.e.sable sec ou terre), puis mettre dans un conteneur pour déchets chimiques. 7. MANIPULATION ET STOCKAGE Manipulation: Éviter le contact avec la peau et les yeux. LIQUIDE ET VAPEUR COMBUSTIBLES . Tenir à l'abri des flammes nues, des surfaces chaudes et des sources d'inflammation. Utiliser seulement dans des zones bien ventilées. POUR UTILISATOIN COMMERCIALE ET INDUSTRIELLE SEULEMENT Stockage: Protéger du gel . Conserver hermétiquement fermé dans un endroit sec, frais et bien ventilé. GARDER HORS DE LA PORTÉE DES ENFANTS. 8. MESURES DE CONTRÔLE DE L'EXPOSITION/PROTECTION INDIVIDUELLE Mesures d'ordre technique: Aucune ventilation particulière requise. Ventilation adéquate du local. Protection individuelle Protection des yeux: Protection des mains: Protection de la peau et du corps: Protection respiratoire: Mesures d'hygiène: Composant(s) Alcool isopropylique Aucune condition particulière dans les conditions normales d'utilisation. Aucune condition particulière dans les conditions normales d'utilisation Aucune condition particulière dans les conditions normales d'utilisation. Aucune condition particulière dans les conditions normales d'utilisation . A manipuler conformément aux normes d'hygiène industrielle et aux consignes de sécurité. CAS # 67-63-0 ACGIH 400 ppm (STEL) 200 ppm (TWA) OSHA 980 mg/m3 (TWA) 400 ppm (TWA) Mexico 500 ppm (STEL) 1225 mg/m3 (STEL) 400 ppm (TWA) 980 mg/m3 (TWA) 9. PROPRIETES PHYSIQUES ET CHIMIQUES État de la matière: pH: Aspect: Couleur: Odeur: Densité: Densité: Teneur (%) en COV (composés organiques volatils): Point d'éclair: Solubilité: Viscosité: liquide 7.5 liquide opaque blanc cassé fruité 1 8.35 lbs/gal 2.75% * Masse volumique apparente: pH de la solution diluée Densité gazeuse: Vitesse d'évaporation Point/intervalle d'ébullition: Point/intervalle de fusion: Température de décomposition: Température d'auto-inflammation: Pas d'information disponible Pas d'information disponible. Pas d'information disponible Pas d'information disponible 212°F 100°C 30.2 °F-1 °C indéterminé Pas d'information disponible 129°F 54°C soluble Pas d'information disponible Coefficient de partage (n-octanol/eau): Pas d'information disponible Solubilité dans d'autres solvants: Pas d'information disponible phosphore élémental : 0 %P * - Titre 17, Code des règlements de la Californie, division 3, chapitre 1, sous-chapitre 8.5, article 2, Produits de consommation, sections 94508 10. STABILITÉ ET RÉACTIVITÉ Stabilité: polymérisation: Produits de décomposition dangereux: Conditions à éviter: Le produit est stable. Une polymérisation dangereuse ne se produit pas.. Aucun raisonnablement prévisible. Ne pas congeler. 11. INFORMATIONS TOXICOLOGIQUES Toxicité aiguë Information sur les composants: Oral(e) Estimée à un niveau supérieur à 5000 mg/kg; Cutanée Toxicité orale exprimée en DL50 > 2000 mg/kg Voir la Section 3 Toxicité chronique: Aucun à notre connaissance Effets spécifiques effets cancérogènes: effets mutagènes: Toxicité pour la reproduction: Effets sur l'organe-cible: Aucun à notre connaissance Aucun à notre connaissance Aucun à notre connaissance Aucun à notre connaissance CARPET SCIENCE Détachant 2 of 3 11. INFORMATIONS TOXICOLOGIQUES Composants Dangereux 12. INFORMATIONS ÉCOLOGIQUES Information environnementales donnée non disponible 13. CONSIDERATIONS RELATIVES À L'ÉLIMINATION Déchets des résidus / produits non utilisés: Le produit non dilué est réglementée par les lois concernant l'environnement et le transport en tant que déchet allumable . Éliminer selon les dispositions prévues par les différentes réglementations fédérales, provinciales, locales ou d'État . 14. INFORMATIONS RELATIVES AU TRANSPORT DOT/TDG: S' il vous plait, consulter le document d'expédition pour les renseignements à jour sur le transport 15. INFORMATIONS RÉGLEMENTAIRES Inventaires internationales Tous les éléments de ce produit sont énumérés dans les inventaires suivants: États-Unis (TSCA), Canada (DSL/NDSL). Réglementation des É.-U. Proposition 65 de la Californie: Ils n'y a pas des ingrédients qui sont assujettis à la déclaration en suivant 'Proposition 65' de Californie LOI DU DROIT DE SAVOIR DE L'ÉTAT Composant(s) Eau Hexyloxyéthanol Alcool isopropylique CAS # 7732-18-5 112-25-4 67-63-0 CERCLA/ SARA Composant(s) Hexyloxyéthanol Alcool isopropylique CAS # 112-25-4 67-63-0 Composant(s) Hexyloxyéthanol MARTK: X % en poids 1 - 5% 1 - 5% NJRTK: X CERCLA/SARA RQ (lbs) CAA HAP X CAA ODS PARTK: X X RIRTK: X Section 302, TPQ kg) Section 313 X X CWA Polluants en Priorité Catégories de risque en vertu de la loi SARA, section 311/312 Immédiat Différée Feu: X Réactivité Décompression soudaine Canada Catégories de risque du SIMDUT : B3 liquides combustibles. Composant(s) Alcool isopropylique CAS # 67-63-0 NPRI X 16. AUTRES INFORMATIONS Cause de la révision: Préparé par: Conseils supplémentaires: Sans objet NAPRAC aucune Avis au lecteur: Ce document a etè prèparè de sources considèrèes techniquement sèrieuses. If ne constitue pas une garantie, ènoncèe ou tacite, de l'exactitude des renseignements ci-incluses. Les conditions actuelles d'usage et de manutention sont hors du contrôle du vendeur. L'utilisateur doit s'assurer qu'il posè'de toutes les donnèes en cours, en regard de son utilization particulière et qu'il respecte tous les règlements fèdèraux, des ètats, provinciaux et municipaux. CARPET SCIENCE Détachant 3 of 3 The Valspar Corporation Material Safety Data Sheet 1. PRODUCT AND COMPANY IDENTIFICATION Material Identification Product ID: 011.0002400 Product Name: Product Use: Print date Revision Date GOOF OFF Paint product. 31/Jan/2007 31/Aug/2005 Company Identification The Valspar Corporation - Architectural Coatings Division 1191 Wheeling Road Wheeling, IL 60090 Manufacturer's Phone: 1-847-520-8580 24-Hour Medical Emergency Phone: 1-888-345-5732 2. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS Common Name CAS-No. XYLENE 1330-20-7 ETHYLBENZENE 100-41-4 DIETHYLENE GLYCOL MONOMETHYL ETHER 111-77-3 TOLUENE 108-88-3 Approx. Chemical name Weight % 75 - 80 Xylenes (o-, m-, p- isomers) 15 - 20 Ethyl benzene 1-5 Diethylene glycol monomethyl ether 1-5 Toluene If this section is blank there are no hazardous components per OSHA guidelines. 3. HAZARDS IDENTIFICATION Primary Routes of Exposure: Inhalation Ingestion Skin absorption Emergency Overview: This section not in use. This product contains ingredients that may contribute to the following potential acute health effects: Inhalation Effects: Harmful if inhaled. May affect the brain, nervous system, or respiratory system, causing dizziness, headache, nausea or respiratory irritation. Eye Contact: Corneal Injury/eye damage. Product ID: 011.0002400 Page 1 / 7 Skin Contact: May cause moderate skin irritation. Acute Ingestion: None known Other Effects: May cause central nervous system depression. May cause liver damage. May cause kidney damage. This product contains ingredients that may contribute to the following potential chronic health effects: Notice: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Possible birth defects hazard. Contains ingredients which may cause birth defects based on animal data. May cause kidney damage. May cause liver damage. See Section 11 for toxicological information about Mutagens, Teratogens and Carcinogens. If this section is blank, no information is available. 4. FIRST AID MEASURES Inhalation: If affected by inhalation, move victim to fresh air. If symptoms persist, seek medical attention. Eye Contact: In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing. Skin Contact: In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. If irritation persists get medical attention. Ingestion: If swallowed , do not induce vomiting. Give large quantities of water. If available, give several glasses of milk. Never give anything by mouth to an unconscious person. Get medical attention immediately. If swallowed, get medical attention immediately. Medical conditions aggravated by exposure: Any respiratory or skin condition. 5. FIRE FIGHTING MEASURES Flash point (Fahrenheit): Lower explosive limit: Upper explosive limit: Autoignition temperature: Sensitivity to impact: Sensitivity to static discharge: Hazardous combustion products: 80º F ( 27º C) TCC/PM 1% 7% Not available. º F ( º C) No. Subject to static discharge hazards. Please see bonding and grounding information in Section 7. See Section 10. Unusual fire and explosion hazards: None known. Extinguishing media: Carbon dioxide, dry chemical, foam and/or water fog. Fire fighting procedures: Use water spray to cool nearby containers and structures exposed to fire. Product ID: 011.0002400 Page 2 / 7 6. ACCIDENTAL RELEASE MEASURES Action to be taken if material is released or spilled: Ventilate area. Avoid breathing of vapors. Use self-containing breathing apparatus or airmask for large spills in a confined area. Wipe, scrape or soak up in an inert material and put in a container for disposal. See section 5, "Unusual Fire and Explosion Hazards", for proper container and storage procedures. Remove sources of ignition. Remove with inert absorbent and non sparking tools. Avoid contact with eyes. 7. HANDLING AND STORAGE Precautions to be taken in handling and storage: Keep away from heat, sparks, and flames. Keep container closed when not in use. Do not store above 120 degrees F. (49 degrees C). Based on flash point and vapor pressure, suitable storage should be provided in accordance with OSHA regulation 1910.106, Ontario OH&S regulation 851 section 22. Empty containers may contain product residue, including flammable or explosive vapors. Do not cut, puncture or weld on or near container. All label warnings must be observed until the container has been commercially cleaned or reconditioned. If the product is used near or above the flashpoint, an ignition hazard may be present. Activities, uses, or operations which liberate vapor (such as mixing or free fall of liquids) may also present an ignition hazard. Please ensure containers and other interconnected equipment are properly bonded and grounded at all times. 8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS Personal Protective Equipment Eye and face protection: Avoid contact with eyes. Wear chemical goggles if there is the possibility of contact or splashing in the eye. Skin protection: Appropriate chemical resistant gloves should be worn.To prevent skin contact wear protective clothing covering all exposed areas. Respiratory protection: If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator such as an air purifying respirator with organic vapor cartridge and dust/mist filter. Consult the respirator manufacturer's literature to ensure that the respirator will provide adequate protection. Read and follow all respirator manufacturer's instructions. Ventilation Required when spraying or applying in confined area. Ventilation equipment should be explosion proof. Eliminate ignition sources. Exposure Guidelines OSHA Permissible Exposure Limits (PEL's) Common Name CAS-No. XYLENE 1330-20-7 ETHYLBENZENE 100-41-4 TOLUENE 108-88-3 Approx. TWA (final) Weight % 75 - 80 435 mg/m³ 100 ppm 15 - 20 435 mg/m³ 100 ppm 1-5 200 ppm Ceilings limits (final) Skin designations 300 ppm ACGIH Threshold Limit Value (TLV's) Common Name CAS-No. Approx. TWA Weight % STEL Product ID: 011.0002400 Page 3 / 7 Ceiling limits Skin designations XYLENE 1330-20-7 ETHYLBENZENE 100-41-4 TOLUENE 108-88-3 75 - 80 100 ppm 150 ppm 15 - 20 100 ppm 125 ppm 1-5 50 ppm Can be absorbed through the skin. If this section is blank, no information is available. 9. PHYSICAL PROPERTIES Odor: Physical State: pH: Vapor pressure: Vapor density (air = 1.0): Boiling point: Solubility in water: Coefficient of water/oil distribution: Density (lbs per US gallon): Specific Gravity Evaporation rate (butyl acetate = 1.0): Normal for this product type. Liquid Not determined. 28 mmHG @ 68º F ( 20º C) 4.1 230º F ( 110º C) Insoluble. Not determined. 7.29 .87 2 10. STABILITY AND REACTIVITY Stability Conditions to Avoid: Incompatibility: Hazardous Polymerization: Hazardous Decomposition Products: Stable None known. Strong oxidizers. None anticipated. Carbon monoxide and carbon dioxide. Sensitivity to static discharge: Subject to static discharge hazards. Please see bonding and grounding information in Section 7. 11. TOXICOLOGICAL INFORMATION Mutagens: Common Name CAS-No. TOLUENE 108-88-3 Approx. California Prop 65 - Developmental Weight % Toxicity 1-5 Listed: January 1, 1991 Developmental toxin. California Prop 65 - Reproductive (Male) Teratogens: Carcinogens: Contains ethylbenzene, which has been determined by NTP to be an animal carcinogen with no known relevance to humans. IARC has classified ethylbenzene as possibly carcinogenic to humans (2b) on the basis of sufficient evidence of carcinogenicity in laboratory animals but inadequate evidence of cancer in humans. Common Name CAS-No. ETHYLBENZENE 100-41-4 Approx. IARC Group 1 - Human Weight % Evidence 15 - 20 Product ID: 011.0002400 Page 4 / 7 IARC Group 2A - Limited IARC Group 2B Human Data Sufficient Animal Data Monograph 77, 2000 Common Name CAS-No. ETHYLBENZENE 100-41-4 Approx. NTP Known Weight % Carcinogens 15 - 20 NTP Suspect Carcinogens NTP Evidence of Carcinogenicity male rat-clear evidence; female rat-some evidence; male micesome evidence; female mice-some evidence Common Name CAS-No. ETHYLBENZENE 100-41-4 Approx. OSHA Select Weight % Carcinogens 15 - 20 OSHA Possible Select Carcinogens ACGIH Carcinogens Group A3 Confirmed animal carcinogen with unknown relevance to humans. If this section is blank, no information is available. 12. ECOLOGICAL DATA Not available at this time. 13. DISPOSAL CONSIDERATIONS Disposal should be made in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION U.S. Department of Transportation Proper Shipping Name: PAINT RELATED MATERIAL Hazard Class: 3 UN ID Number: UN1263 Packing Group: III 49 CFR Hazardous Material Regulations Parts 100-180 The supplier will apply the combustible liquid exception in 49 CFR 173.150(f), limited quantity or "does not sustain combustion" exceptions and consumer commodity rules, when authorized. Please check 49 CFR Parts 100-180 to determine if the use of these exceptions applies to your shipments when re-shipping our products. International Air Transport Association: Proper Shipping Name: PAINT RELATED MATERIAL Hazard Class: 3 UN ID Number: UN1263 Packing Group: III International Maritime Organization: Proper Shipping Name: PAINT RELATED MATERIAL Hazard Class: 3 Non-Bulk UN ID Number: UN1263 Packing Group: III 15. REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: Product ID: 011.0002400 Page 5 / 7 15. REGULATORY INFORMATION Common Name CAS-No. XYLENE 1330-20-7 Approx. SARA 302 Weight % 75 - 80 ETHYLBENZENE 100-41-4 15 - 20 DIETHYLENE GLYCOL MONOMETHYL ETHER 111-77-3 TOLUENE 108-88-3 1-5 SARA 313 form R reporting required 100 for 1.0% de minimis concentration form R reporting required 1000 for 1.0% de minimis concentration YES 1-5 SARA 311/312 Hazard Class: Acute: Chronic: Flammability: Reactivity: Sudden Pressure: CERCLA RQ in lbs. form R reporting required 1000 for 1.0% de minimis concentration Yes Yes Yes No No U.S. STATE REGULATIONS: Pennsylvania Right To Know: ETHYLBENZENE TOLUENE DIETHYLENE GLYCOL MONOMETHYL ETHER XYLENE 100-41-4 108-88-3 111-77-3 1330-20-7 California Proposition 65: WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. Rule 66 status of product Photochemically reactive. INTERNATIONAL REGULATIONS - Chemical Inventories TSCA Inventory: All components of this product are in compliance with U.S. TSCA Chemical Substance Inventory Requirements. Canada Domestic Substances List: All components of this product are listed on the Domestic Substances List. 16. OTHER INFORMATION HMIS Codes Health: Flammability: Reactivity: PPE: 2 3 1 X - See Section 8 for Personal Protective Equipment (PPE). Product ID: 011.0002400 Page 6 / 7 Abbreviations: OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer, NIOSH National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH - American Conference of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management District, TSCA - Toxic Substances Control Act, IATA - International Air Transport Association, IMO - International Maritime Organization, DOT Department of Transportation, NA - Not applicable, NOT ESTAB - Not established, N.A.V. - Not available, RQ Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L - Grams per liter, MM - Millimeters, MPPCF - Millions of particles per cubic foot, PPM - parts per million, PPT - parts per thousand, TCC/PM - Tag closed cup / Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time Weighted Average, STEL - Short term exposure limit, C - Celsius, F - Fahrenheit. Disclaimer: The data on this sheet represent typical values. Since application variables are a major factor in product performance, this information should serve only as a general guide. Valspar assumes no obligation or liability for use of this information. UNLESS VALSPAR AGREES OTHERWISE IN WRITING, VALSPAR MAKES NO WARRANTIES, EXPRESS OR IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. VALSPAR WILL NOT BE LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only remedy for any defect in this product is the replacement of the defective product, or a refund of its purchase price, at our option. This MSDS contains additional information required by the state of Pennsylvania. Product ID: 011.0002400 Page 7 / 7 The Valspar Corporation Material Safety Data Sheet 1. PRODUCT AND COMPANY IDENTIFICATION Material Identification Product ID: 011.0002417.004 Product Name: Product Use: Effective date: Revision Date UN ID Number: WHMIS Classification: CAN GOOF OFF 16 OZ 12P Paint product. 12/Oct/2005 31/Aug/2005 UN1263 D2B Toxic Material D2A Very Toxic Material B2 Flammable Liquids Company Identification 1191 Wheeling Road Wheeling, IL 60090 Tech Info Phone: 847-520-8580 24-Hour Medical Emergency Phone: 1-888-345-5732 2. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS Common Name CAS-No. XYLENE 1330-20-7 ETHYLBENZENE 100-41-4 DIETHYLENE GLYCOL MONOMETHYL ETHER 111-77-3 TOLUENE 108-88-3 Approx. Chemical Name Weight % 75 - 80 Xylenes (o-, m-, pisomers) 15 - 20 Ethyl benzene CAS Number 1-5 Diethylene glycol monomethyl ether 111-77-3 1-5 Toluene 108-88-3 Trade Secret Number 1330-20-7 100-41-4 If this section is blank there are no hazardous components per OHSA guidelines. 3. HAZARDS IDENTIFICATION Primary Routes of Exposure: Inhalation Ingestion Skin absorption Emergency Overview: This section not in use. This product contains ingredients that may contribute to the following potential acute health effects: Inhalation Effects: Harmful if inhaled. May affect the brain, nervous system, or respiratory system, causing dizziness, headache, nausea or respiratory irritation. Product ID: 011.0002417.004 Page 1 of 7 Eye Contact: Corneal Injury/eye damage. Skin Contact: May cause moderate skin irritation. Acute Ingestion: None known Other Effects: May cause central nervous system depression. May cause liver damage. May cause kidney damage. This product contains ingredients that may contribute to the following potential chronic health effects: Notice: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Possible birth defects hazard. Contains ingredients which may cause birth defects based on animal data. May cause kidney damage. May cause liver damage. See Section 11 for toxicological information about Mutagens, Teratogens and Carcinogens. If this section is blank, no information is available. 4. FIRST AID MEASURES Inhalation: If affected by inhalation, move victim to fresh air. If symptoms persist, seek medical attention. Eye Contact: In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing. Skin Contact: In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. If irritation persists get medical attention. Ingestion: If swallowed , do not induce vomiting. Give large quantities of water. If available, give several glasses of milk. Never give anything by mouth to an unconscious person. Get medical attention immediately. If swallowed, get medical attention immediately. Medical conditions aggravated by exposure: Any respiratory or skin condition. 5. FIRE FIGHTING MEASURES Flash point (Fahrenheit): Lower explosive limit: Upper explosive limit: Autoignition temperature: Sensitivity to impact: Sensitivity to static discharge: Hazardous combustion products: 80º F ( 27º C) TCC/PM 1% 7% Not available. º F ( º C) No. Subject to static discharge hazards. Please see bonding and grounding information in Section 7. See Section 10. Unusual fire and explosion hazards: None known. Extinguishing media: Carbon dioxide, dry chemical, foam and/or water fog. Product ID: 011.0002417.004 Page 2 of 7 Fire fighting procedures: Use water spray to cool nearby containers and structures exposed to fire. 6. ACCIDENTAL RELEASE MEASURES Action to be taken if material is released or spilled: Ventilate area. Avoid breathing of vapors. Use self-containing breathing apparatus or airmask for large spills in a confined area. Wipe, scrape or soak up in an inert material and put in a container for disposal. See section 5, "Unusual Fire and Explosion Hazards", for proper container and storage procedures. Remove sources of ignition. Remove with inert absorbent and non sparking tools. Avoid contact with eyes. 7. HANDLING AND STORAGE Precautions to be taken in handling and storage: Keep away from heat, sparks, and flames. Keep container closed when not in use. Do not store above 120 degrees F. (49 degrees C). Based on flash point and vapor pressure, suitable storage should be provided in accordance with OSHA regulation 1910.106, Ontario OH&S regulation 851 section 22. Empty containers may contain product residue, including flammable or explosive vapors. Do not cut, puncture or weld on or near container. All label warnings must be observed until the container has been commercially cleaned or reconditioned. If the product is used near or above the flashpoint, an ignition hazard may be present. Activities, uses, or operations which liberate vapor (such as mixing or free fall of liquids) may also present an ignition hazard. Please ensure containers and other interconnected equipment are properly bonded and grounded at all times. 8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS Personal Protective Equipment Eye and face protection: Avoid contact with eyes. Wear chemical goggles if there is the possibility of contact or splashing in the eye. Skin protection: Appropriate chemical resistant gloves should be worn.To prevent skin contact wear protective clothing covering all exposed areas. Respiratory protection: If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator such as an air purifying respirator with organic vapor cartridge and dust/mist filter. Consult the respirator manufacturer's literature to ensure that the respirator will provide adequate protection. Read and follow all respirator manufacturer's instructions. Ventilation Required when spraying or applying in confined area. Ventilation equipment should be explosion proof. Eliminate ignition sources. Exposure Guidelines OSHA Permissible Exposure Limits (PEL's) Common Name CAS-No. XYLENE 1330-20-7 ETHYLBENZENE 100-41-4 TOLUENE 108-88-3 Approx. TWA (final) Weight % 75 - 80 435 mg/m3 100 ppm 15 - 20 435 mg/m3 100 ppm 1-5 200 ppm Ceilings limits (final) 300 ppm ACGIH Threshold Limit Value (TLV's) Product ID: 011.0002417.004 Page 3 of 7 Skin designations Common Name CAS-No. XYLENE 1330-20-7 ETHYLBENZENE 100-41-4 TOLUENE 108-88-3 Approx. TWA Weight % 75 - 80 100 ppm STEL 15 - 20 100 ppm 125 ppm 1-5 50 ppm Ceiling limits Skin designations 150 ppm Can be absorbed through the skin. If this section is blank, no information is available. 9. PHYSICAL PROPERTIES Odor: Odor threshold: Physical State: pH: Vapor pressure: Vapor density (air = 1.0): Boiling point: Solubility in water: Coefficient of water/oil distribution: Density (lbs per US gallon): Specific Gravity Evaporation rate (butyl acetate = 1.0): Normal for this product type. Not available. Liquid Not determined. 28 mmHG @ 68º F ( Not Available. º C) 4.1 230º F ( 110º C) Insoluble. Not determined. 7.29 .87 2 10. STABILITY AND REACTIVITY Stability Conditions to Avoid: Incompatibility: Hazardous Polymerization: Hazardous Decomposition Products: Stable None known. Strong oxidizers. None anticipated. Carbon monoxide and carbon dioxide. Sensitivity to static discharge: Subject to static discharge hazards. Please see bonding and grounding information in Section 7. 11. TOXICOLOGICAL INFORMATION Common Name CAS-No. XYLENE 1330-20-7 ETHYLBENZENE 100-41-4 DIETHYLENE GLYCOL MONOMETHYL ETHER 111-77-3 TOLUENE 108-88-3 Approx. NIOSH - Selected LD50s and LC50s Weight % 75 - 80 Inhalation LC50 Rat : 5000 ppm/4H Oral LD50 Rat : 4300 mg/kg Dermal LD50 Rabbit : >1700 mg/kg 15 - 20 Oral LD50 Rat : 3500 mg/kg Dermal LD50 Rabbit : 17800 uL/kg 1-5 Oral LD50 Rat : 4 mL/kg Oral LD50 Mouse : 8222 mg/kg Dermal LD50 Rabbit : 2500 uL/kg 1-5 Inhalation LC50 Rat : 49 gm/m3/4H Inhalation LC50 Mouse : 400 ppm/24H Oral LD50 Rat : 636 mg/kg Dermal LD50 Rabbit : 14100 uL/kg Mutagens: Product ID: 011.0002417.004 Page 4 of 7 Common Name CAS-No. TOLUENE 108-88-3 Approx. Calif- Prop. 65. Developmental Weight % Toxicity 1-5 Listed: January 1, 1991 Developmental toxin. California Prop 65 - reproductive male Teratogens: Carcinogens: Contains ethylbenzene, which has been determined by NTP to be an animal carcinogen with no known relevance to humans. IARC has classified ethylbenzene as possibly carcinogenic to humans (2b) on the basis of sufficient evidence of carcinogenicity in laboratory animals but inadequate evidence of cancer in humans. Common Name CAS-No. ETHYLBENZENE 100-41-4 Approx. IARC Group 1 - Human IARC Group 2A - limited IARC Group 2b Weight % Evidence human data sufficient animal data 15 - 20 Monograph 77, 2000 Common Name CAS-No. ETHYLBENZENE 100-41-4 Approx. NTP Known Weight % carcinogens 15 - 20 NTP Suspect carcinogens NTP Evidence of carcinogenicity male rat-clear evidence; female rat-some evidence; male micesome evidence; female mice-some evidence Common Name CAS-No. ETHYLBENZENE 100-41-4 Approx. OSHA Select Weight % carcinogens 15 - 20 OSHA Possible select carcinogens ACGIH Carcinogens If this section is blank, no information is available. 12. ECOLOGICAL DATA Not available at this time. 13. DISPOSAL CONSIDERATIONS Disposal should be made in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION Canadian Transport of Dangerous Goods Proper Shipping Name: PAINT Hazard Class: 3 UN ID Number: UN1263 Packing Group: III International Air Transport Association: Proper Shipping Name: PAINT Hazard Class: 3 UN ID Number: UN1263 Packing Group: III Product ID: 011.0002417.004 Page 5 of 7 Group A3 Confirmed animal carcinogen with unknown relevance to humans. International Maritime Organization: Proper Shipping Name: PAINT Hazard Class: 3 UN ID Number: UN1263 Packing Group: III 15. REGULATORY INFORMATION INTERNATIONAL REGULATIONS - Chemical Inventories TSCA Inventory: All components of this product are in compliance with U.S. TSCA Chemical Substance Inventory Requirements. Canada Domestic Substances List: All components of this product are listed on the Domestic Substances List. Canada National Pollutant Release Inventory: Common Name CAS-No. XYLENE 1330-20-7 ETHYLBENZENE 100-41-4 DIETHYLENE GLYCOL MONOMETHYL ETHER 111-77-3 TOLUENE 108-88-3 Approx. NPRI Status Weight % 75 - 80 [reporting required] 15 - 20 [reporting required] 1-5 YES 1-5 [reporting required] This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by the Controlled Products Regulations. 16. OTHER INFORMATION HMIS Codes Health: Flammability: Reactivity: PPE: 2 3 1 X - See Section 8 for Personal Protective Equipment (PPE). Abbreviations: OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer, NIOSH - National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH American Conference of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management District, TSCA - Toxic Substances Control Act, IATA - International Air Transport Association, IMO - International Maritime Organization, DOT - Department of Transportation, NA - Not applicable, NOT ESTAB - Not established, N.A.V. - Not available, RQ - Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L - Grams per liter, MM - Millimeters, MPPCF - Millions of particles per cubic foot, PPM - parts per million, PPT - parts per thousand, TCC/PM - Tag closed cup / Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time Weighted Average, STEL - Short term exposure limit, C - Celsius, F - Fahrenheit. Product ID: 011.0002417.004 Page 6 of 7 Disclaimer: The data on this sheet represent typical values. Since application variables are a major factor in product performance, this information should serve only as a general guide. Valspar assumes no obligation or liability for use of this information. UNLESS VALSPAR AGREES OTHERWISE IN WRITING, VALSPAR MAKES NO WARRANTIES, EXPRESS OR IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. VALSPAR WILL NOT BE LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only remedy for any defect in this product is the replacement of the defective product, or a refund of its purchase price, at our option. This MSDS contains additional information required by the state of Pennsylvania. Preparation Information: Prepared By: Print date Revision Date Regulatory Affairs Department 12/Oct/2005 31/Aug/2005 Technical Information: The Valspar Corporation - Architectural Coatings Division 1191 Wheeling Road Wheeling, IL 60090 Tech Info Phone: 847-520-8580 24-Hour Medical Emergency Phone: 1-888-345-5732 Product ID: 011.0002417.004 Page 7 of 7 The Valspar Corporation Material Safety Data Sheet 1. PRODUCT AND COMPANY IDENTIFICATION Material Identification Product ID: 011.0002316.077 Product Name Product Use: Print date Revision Date GRAF RMVR 16OZ SPRAY Paint product. 2005/04/14 2005/04/14 6U Company Identification The Valspar Corporation - Architectural Coatings Division 1000 Lake Road Medina, OH 44256 Manufacturer's Phone: 1-330-725-4511 24-Hour Medical Emergency Phone: 1-888-345-5732 2. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS Common Name CAS-No. XYLENE 1330-20-7 TOLUENE 108-88-3 ETHYLBENZENE 100-41-4 PROPANE 74-98-6 DIETHYLENE GLYCOL MONOMETHYL ETHER 111-77-3 BUTANE 106-97-8 METHYL ALCOHOL 67-56-1 approx. Weight % 45 - 50 Chemical name Xylenes (o-, m-, p- isomers) 15 - 20 Toluene 10 - 15 Ethyl benzene 10 - 15 Propane 5 - 10 Diethylene glycol monomethyl ether 1-5 Butane 1-5 Methyl alcohol If this section is blank there are no hazardous components per OSHA guidelines. 3. HAZARDS IDENTIFICATION Primary Routes of Exposure: Inhalation Ingestion Skin absorption Product ID: 011.0002316.077 Page 1 of 8 Emergency Overview: This section not in use. This product contains ingredients that may contribute to the following potential acute health effects: Inhalation Effects: Harmful if inhaled. May affect the brain, nervous system, or respiratory system, causing dizziness, headache, nausea or respiratory irritation. Eye Contact: Corneal Injury/eye damage. Skin Contact: May cause moderate skin irritation. May be harmful if absorbed through skin. Acute Ingestion: May be fatal or cause blindness if swallowed. Other Effects: May cause central nervous system depression. May cause liver damage. Contains ingredient which is considered highly toxic. May cause kidney damage. This product contains ingredients that may contribute to the following potential chronic health effects: Notice: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.Possible birth defects hazard. Contains ingredients which may cause birth defects based on animal data. May cause kidney damage. May cause liver damage. See Section 11 for toxicological information about Mutagens, Teratogens and Carcinogens. If this section is blank, no information is available. 4. FIRST AID MEASURES Inhalation: If affected by inhalation, move victim to fresh air. If symptoms persist, seek medical attention. Eye Contact: In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing. Skin Contact: In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. If irritation persists get medical attention. Ingestion: Poison! Get medical attention immediately. If swallowed, contact medical personnel immediately to determine best course of action. Medical conditions aggravated by exposure: Any respiratory or skin condition. 5. FIRE FIGHTING MEASURES Product ID: 011.0002316.077 Page 2 of 8 Flash point (Fahrenheit): Lower explosive limit: Upper explosive limit: Autoignition temperature: Sensitivity to impact: Sensitivity to static discharge: information in Section 7. Hazardous combustion products: -31º F ( -35º C) TCC/PM 1% 23 % Not available.º F ( º C) No. Subject to static discharge hazards. Please see bonding and grounding See Section 10. Unusual fire and explosion hazards: None known. Extinguishing media: Carbon dioxide, dry chemical, foam and/or water fog. Fire fighting procedures: Use water spray to cool nearby containers and structures exposed to fire. 6. ACCIDENTAL RELEASE MEASURES Action to be taken if material is released or spilled: Ventilate area. Avoid breathing of vapors. Use self-containing breathing apparatus or airmask for large spills in a confined area. Wipe, scrape or soak up in an inert material and put in a container for disposal. See section 5, "Unusual Fire and Explosion Hazards", for proper container and storage procedures. Remove sources of ignition. Remove with inert absorbent and non sparking tools. Avoid contact with eyes. 7. HANDLING AND STORAGE Precautions to be taken in handling and storage: Keep away from heat, sparks, and flames. Keep container closed when not in use. Do not store above 120 degrees F. (49 degrees C). Based on flash point and vapor pressure, suitable storage should be provided in accordance with OSHA regulation 1910.106, Ontario OH&S regulation 851 section 22. Empty containers may contain product residue, including flammable or explosive vapors. Do not cut, puncture or weld on or near container. All label warnings must be observed until the container has been commercially cleaned or reconditioned. If the product is used near or above the flashpoint, an ignition hazard may be present. Activities, uses, or operations which liberate vapor (such as mixing or free fall of liquids) may also present an ignition hazard. Please ensure containers and other interconnected equipment are properly bonded and grounded at all times. 8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS Personal Protective Equipment Eye and face protection: Avoid contact with eyes. Wear chemical goggles if there is the possibility of contact or splashing in the eye. Skin protection: Appropriate chemical resistant gloves should be worn.To prevent skin contact wear protective clothing covering all exposed areas. Respiratory protection: If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator such as an air purifying respirator with organic vapor cartridge and dust/mist filter. Consult the respirator manufacturer's literature to ensure that the respirator will provide adequate protection. Read and follow all respirator manufacturer's instructions. Product ID: 011.0002316.077 Page 3 of 8 Ventilation Required when spraying or applying in confined area. Ventilation equipment should be explosion proof. Eliminate ignition sources. Exposure Guidelines OSHA Permissible Exposure Limits (PEL's) Common Name CAS-No. XYLENE 1330-20-7 TOLUENE 108-88-3 ETHYLBENZENE 100-41-4 PROPANE 74-98-6 METHYL ALCOHOL 67-56-1 approx. Weight % 45 - 50 TWA (final) Ceilings limits (final) Skin designations 435 MGM3 100 ppm 15 - 20 200 ppm 300 ppm 10 - 15 435 MGM3 100 ppm 10 - 15 1800 MGM3 1000 ppm 1-5 260 MGM3 200 ppm ACGIH Threshold Limit Value (TLV's) Common Name CAS-No. XYLENE 1330-20-7 TOLUENE 108-88-3 ETHYLBENZENE 100-41-4 PROPANE 74-98-6 BUTANE 106-97-8 METHYL ALCOHOL 67-56-1 approx. Weight % 45 - 50 TWA STEL 100 ppm 15 - 20 50 ppm 10 - 15 100 ppm 10 - 15 1000 ppm 1-5 1000 ppm 1-5 200 ppm Ceiling limits 150 ppm Can be absorbed through the skin. 125 ppm 250 ppm If this section is blank, no information is available. 9. PHYSICAL PROPERTIES Odor: Physical State: pH: Vapor pressure: Vapor density (air = 1.0): Boiling point: Solubility in water: Coefficient of water/oil distribution: Density (lbs per US gallon): Product ID: Skin designations Normal for this product type. Liquid Not determined. NOT DETERMINED mmHG @ 68º F ( 20º C) 4.1 -42º F ( -41º C) Not determined. Not determined. 6.7 011.0002316.077 Page 4 of 8 Can be absorbed through the skin. Specific Gravity Evaporation rate (butyl acetate = 1.0): .8 5.9 10. STABILITY AND REACTIVITY Stability Conditions to Avoid: Incompatibility: Hazardous Polymerization: Hazardous Decomposition Products: Stable None known. Strong oxidizers. None anticipated. Carbon monoxide and carbon dioxide. Sensitivity to static discharge: Subject to static discharge hazards. Please see bonding and grounding information in Section 7. 11. TOXICOLOGICAL INFORMATION Mutagens: Common Name CAS-No. TOLUENE 108-88-3 approx. Weight % 15 - 20 Calif- Prop. 65. Developmental Toxicity Listed: January 1, 1991 Developmental toxin. California Prop 65 - reproductive male Teratogens: Carcinogens: Contains ethylbenzene, which has been determined by NTP to be an animal carcinogen with no known relevance to humans. IARC has classified ethylbenzene as possibly carcinogenic to humans (2b) on the basis of sufficient evidence of carcinogenicity in laboratory animals but inadequate evidence of cancer in humans. Common Name approx. IARC Group 1 - Human IARC Group 2A IARC Group 2b CAS-No. Weight % Evidence limited human data sufficient animal data ETHYLBENZENE 10 - 15 Monograph 77, 2000 100-41-4 Common Name CAS-No. ETHYLBENZENE 100-41-4 approx. Weight % 10 - 15 NTP Known carcinogens NTP Suspect carcinogens Common Name CAS-No. ETHYLBENZENE 100-41-4 approx. Weight % 10 - 15 OSHA Select carcinogens OSHA Possible select ACGIH Carcinogens carcinogens Group A3 Confirmed animal carcinogen with unknown relevance to humans. Product ID: 011.0002316.077 Page 5 of 8 NTP Evidence of carcinogenicity male rat-clear evidence; female ratsome evidence; male mice-some evidence; female mice-some evidence If this section is blank, no information is available. 12. ECOLOGICAL DATA Not available at this time. 13. DISPOSAL CONSIDERATIONS Disposal should be made in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION U.S. Department of Transportation Proper Shipping Name: CONSUMER COMMODITY ORM-D UN ID Number: CONCOM 49 CFR Hazardous Material Regulations Parts 100-180 The supplier will apply the combustible liquid exception in 49 CFR 173.150(f), limited quantity or "does not sustain combustion" exceptions and consumer commodity rules, when authorized. Please check 49 CFR Parts 100-180 to determine if the use of these exceptions applies to your shipments when re-shipping our products. International Air Transport Association: Proper Shipping Name: AEROSOLS, FLAMMABLE Hazard Class: 2.1 UN ID Number: UN1950 International Maritime Organization: Proper Shipping Name: AEROSOLS Hazard Class: 2 UN ID Number: UN1950 15. REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: Common Name approx. CAS-No. Weight % XYLENE 45 - 50 1330-20-7 TOLUENE 108-88-3 15 - 20 ETHYLBENZENE 100-41-4 10 - 15 DIETHYLENE GLYCOL MONOMETHYL ETHER 111-77-3 METHYL ALCOHOL 67-56-1 5 - 10 Product ID: SARA 302 1-5 011.0002316.077 Page 6 of 8 SARA 313 CERCLA RQ IN LBS. form R reporting required for 1.0% de minimis concentration form R reporting required for 1.0% de minimis concentration form R reporting required for 1.0% de minimis concentration YES 100 form R reporting required for 1.0% de minimis concentration 5000 1000 1000 SARA 311/312 Hazard Class: Acute: Yes Chronic: Yes Flammability: Yes Reactivity: No Sudden Pressure: Yes U.S. STATE REGULATIONS: Pennsylvania Right To Know: XYLENE METHYL ALCOHOL PROPANE DIETHYLENE GLYCOL MONOMETHYL ETHER ETHYLBENZENE BUTANE TOLUENE 1330-20-7 67-56-1 74-98-6 111-77-3 100-41-4 106-97-8 108-88-3 California Proposition 65: WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. Rule 66 status of product Photochemically reactive. INTERNATIONAL REGULATIONS - Chemical Inventories TSCA Inventory: All components of this product are in compliance with U.S. TSCA Chemical Substance Inventory Requirements. Canada Domestic Substances List: All components of this product are listed on the Domestic Substances List. 16. OTHER INFORMATION HMIS Codes Health: Flammability: Reactivity: PPE: 2 4 1 X - See Section 8 for Personal Protective Equipment (PPE). Abbreviations: OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer, NIOSH National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH - American Conference of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management District, TSCA - Toxic Substances Control Act, IATA - International Air Transport Association, IMO - International Maritime Organization, DOT Department of Transportation, NA - Not applicable, NOT ESTAB - Not established, N.A.V. - Not available, RQ Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L - Grams per liter, MM - Millimeters, Product ID: 011.0002316.077 Page 7 of 8 MPPCF - Millions of particles per cubic foot, PPM - parts per million, PPT - parts per thousand, TCC/PM - Tag closed cup / Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time Weighted Average, STEL - Short term exposure limit, C - Celsius, F - Fahrenheit. Disclaimer: The data on this sheet represent typical values. Since application variables are a major factor in product performance, this information should serve only as a general guide. Valspar assumes no obligation or liability for use of this information. UNLESS VALSPAR AGREES OTHERWISE IN WRITING, VALSPAR MAKES NO WARRANTIES, EXPRESS OR IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. VALSPAR WILL NOT BE LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only remedy for any defect in this product is the replacement of the defective product, or a refund of its purchase price, at our option. This MSDS contains additional information required by the state of Pennsylvania. Product ID: 011.0002316.077 Page 8 of 8 Material Safety Data Sheet WHMIS (Pictograms) WHMIS (Classification) Personal protective equipment WHMIS CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). Section 1. Product and Company Identification Product name / Trade name Solvent Mineral Spirit Paint Thinner Associated Product’s Item Code SOLV 1 83-326 Synonym Petroleum Distillate CAS # Not available. Chemical family Aliphatic hydrocarbon (Solvent.) Validation date 11/8/2007. Nov. 08 2007 Chemical formula Not available. Print date 11/8/2007. Nov. 08 2007 Manufacturer Recochem Inc. 850 Montee de Liesse Montreal, Quebec 514-341-3550 In case of emergency Material uses Not available. Recochem Inc. Communications and Regulatory Affairs Department (905) 791-1788 Section 2. Hazardous Ingredients Canada Name Petroleum Distillate CAS number % 100 There are no ingredients or additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Section 3. Hazard Identification Emergency Overview WARNING ! FLAMMABLE LIQUID AND VAPOR. COMBUSTIBLE. Flammable liquid. Keep away from heat, sparks and flame. Avoid breathing vapor or mist. Avoid contact with skin and clothing. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Potential Acute Health Effects See Section #11: "Toxicological Information" for further human health effects. This product may cause mild irritatation to eyes and skin upon contact. Prolonged and repeated contact with skin can cause drying of the skin resulting in irritation and dermatitis. Inflammation of the eye is characterized by mild redness, watering, and itching. Skin inflammation is characterized by mild itching, scaling, reddening. Ingestion can cause burning sensation, vomiting, drowsiness and in severe cases pulmonary edema. Inhalation of excessive amounts may result in impairment, such as drowsiness, lack of coordination, headache and nausea. Continued on next page Nov. 08 2007 Validated on 11/8/2007. Note to Physician PaintMineral ThinnerSpirit Solvent Page: 2/6 Aspiration hazard if swallowed. Can enter lungs and cause damage. Small amounts of liquid aspirated into the respiratory system during ingestion or from vomiting may cause mild to severe pulmonary injury and possible death. Section 4. First aid measures Eye contact Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Skin contact Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Inhalation Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Ingestion Wash out mouth with water. Remove dentures if any. Move exposed person to fresh air. Keep person warm and at rest. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 5. Fire fighting measures Products of combustion No specific data. Fire-fighting media and instructions Use dry chemical, CO2, water spray (fog) or foam. Fire Hazards Container explosion may occur under fire conditions or when heated. Vapor may travel a considerable distance to source of ignition and flash back. Vigorously supports combustion. Combustible when exposed to heat or flame. Explosion Hazards Vapours may travel along ground and flashback along vapour trail. Section 6. Accidental release measures Small spill and leak Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosionproof equipment. Dispose of via a licensed waste disposal contractor. Large spill and leak Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section 13 for waste disposal. Section 7. Handling and Storage Handling Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not breathe vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before Continued on next page Nov. 08 2007 Validated on 11/8/2007. PaintMineral ThinnerSpirit Solvent Page: 3/6 transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container. See Section #10 for applicable incompatible materials. Do not store above the following temperature: 42°C (107.6°F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Storage Section 8. Exposure controls, personal protection Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Engineering controls Personal protection Eyes Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. Recommended: splash goggles Body Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Hands Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. >8 hours (breakthrough time): nitrile rubber Product name Exposure limits Canada Petroleum Distillate ACGIH (Canada, 2003). TWA: 100 ppm 8 hour(s). TWA: 525 mg/m³ 8 hour(s). United States Petroleum Distillate OSHA (United States, 2003). TWA: 500 ppm 8 hour(s). TWA: 2900 mg/m³ 8 hour(s). Section 9. Physical and chemical properties Physical State and Appearance Liquid. Odour Petroleum distillates Molecular weight Not applicable. Taste Not available. pH Not applicable. Colour Not available. Boiling/condensation point 150 to 210°C (302 to 410°F) Volatility 100% (v/v), 100% (w/w) Melting/freezing point -58°C (-72.4°F) Evaporation 0.1 (Butyl acetate. = 1) rate Relative density 0.79 Odour Threshold Continued on next page Not available. Nov. 08 2007 Validated on 11/8/2007. PaintMineral ThinnerSpirit Solvent Page: 4/6 Vapour Pressure 0.29 kPa (2.2 mm Hg) Viscosity Kinematic: 0.0114 cm2/s (1.14 cSt) Vapour Density 5 [Air = 1] Solubility Easily soluble in the following materials: diethyl ether, noctanol. Insoluble in the following materials: water. VOC Content 790 (g/l). Other Properties Not available. The product is: Combustible. Auto-ignition temperature 229°C (444.2°F) Flash Point Closed cup: 42°C (107.6°F) [Tagliabue. (ASTM D56)] Flammable limits Lower: 1% Upper: 13.3% Fire hazards in the presence of various substances Flammable in the presence of open flames, sparks and static discharge. This product is combustible if exposed to heat or when in involved in a fire and in contact with combustible materials which may act as a wick. Section 10. Stability and reactivity Stability The product is stable. Under normal conditions of storage and use, hazardous polymerization will not occur. Conditions of instability No additional remark. Incompatibility with various substances Reactive with oxidizing agents. Section 11. Toxicological information Routes of entry Eye contact. Inhalation. Ingestion. Environmental effects No known significant effects or critical hazards. Acute effects on humans Eyes May cause mild eye irritation. Skin May cause mild skin irritation. Inhalation Slightly hazardous by the following route of exposure: of inhalation. Exposure to very high concentrations can cause dizziness, lightheadness, headache, nausea, and blurrred vision. Higher levels may cause unconsciousness. Ingestion This product is of very low acute toxicity. Aspiration hazard if swallowed. Can enter lungs and cause damage. Chronic effects on humans Continued on next page Nov. 08 2007 Validated on 11/8/2007. PaintMineral ThinnerSpirit Solvent Page: 5/6 Section 12. Ecological information Ecotoxicity For accidential discharges into environment, see Section #6: "Accidential Release Measures" for suggested instructions. No known significant effects or critical hazards. Not available. Section 13. Disposal considerations Waste information The generation of waste should be avoided or minimized wherever possible. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal should be in accordance with applicable regional, national and local laws and regulations. Section 14. Transport information Canada Transportation of Dangerous Goods (TDG) Information Primary Class Subsidiary Class (if applicable) Class 3: Flammable liquid. Proper shipping name Hazard identification number Packing group PETROLEUM DISTILLATES, N.O.S. UN 1268 Special Provisions In containers of 450L or less this product is not classified as a Dangerous Goods according to TDG exemption 1.33 - III International Maritime Dangerous Goods (IMDG) Transportation Information Primary Class Subsidiary Class (if applicable) Class 3: Flammable liquid. Proper shipping name Hazard identification number Packing group PETROLEUM DISTILLATES, N.O.S. UN 1268 Marine pollutant Special Provisions Not a pollutant. - III In containers of 5 L (5Kg) capacity or less this product is classified as a "Consumer Commodity" under IMDG regulations. United States Department of Transportation (DOT) Information Primary Class Class 3: Flammable liquid. Subsidiary class (if applicable) - Proper shipping name PETROLEUM DISTILLATES, N.O.S. Continued on next page Nov. 08 2007 Validated on 11/8/2007. Page: 6/6 PaintMineral ThinnerSpirit Solvent Hazard identification number Packing group UN 1268 Special Provisions In containers of 454L or less this product is not classified as a Gangerous Good according to exception 173.150 f(1-2) International Air Transport Association (IATA) For air shipment classification and associated regulations, please refer to the latest edition of IATA Dangerous Goods Regulations. III Section 15. Other Regulatory Information and Pictograms WHMIS Classification (Canada) Canada Domestic Substances List (DSL) Status WHMIS CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). HCS Classification (U.S.A.) Combustible liquid U.S.A. Regulatory Lists This product and/ or all of its components are on the TSCA inventory list. Hazardous Material Information System (U.S.A.) This product and/ or all of its components are on the DSL. Health Flammability Reactivity Personal protection 1 2 0 G National Fire Protection Association (U.S.A.) Flammability Health 2 1 0 Reactivity Specific hazard Section 16. Other information Validated and verified by Compliance and Technical Information Manager on 11/8/2007 ph.# Printed 11/8/2007. 905-791-1788. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. MSDS are available at www.recochem.com Common Name: CRYSTAL SIMPLE GREEN Manufacturer: SUNSHINE MAKERS MSDS Revision Date: 8/1/2006 Grainger Item Number(s): 3UP37, 3UP38, 3UP39, 3UP40 Manufacturer Model Number(s): MSDS Table of Contents Click the desired link below to jump directly to that section in the MSDS. I. PRODUCT & COMPANY INFORMATION II. INGREDIENT INFORMATION III. HAZARDS IDENTIFICATION IV. FIRST AID MEASURES V. FIRE FIGHTING MEASURES VI. ACCIDENTAL RELEASE MEASURES VII. HANDLING, STORAGE & TRANSPORT INFORMATION VIII. EXPOSURE CONTROLS IX. PERSONAL PROTECTION X. PHYSICAL AND CHEMICAL PROPERTIES XI. STABILITY AND REACTIVITY INFORMATION XII. TOXICOLOGICAL INFORMATION XIII. BIODEGRADABILITY AND ENVIRONMENTAL TOXICITY INFORMATION XIV. DISPOSAL CONSIDERATIONS XV. OTHER INFORMATION MATERIAL SAFETY DATA SHEET: CRYSTAL SIMPLE GREEN(R*) ALSO FOR: SIMPLE GREEN(R*) SAFETY TOWELS VERSION NO.: 4013 ISSUE DATE: AUGUST 2006 I. PRODUCT & COMPANY INFORMATION PRODUCT NAME: CRYSTAL SIMPLE GREEN(R*) OTHER NAMES: CRYSTAL SIMPLE GREEN(R*) - SPECIALIZED CLEANER / DEGREASER SIMPLE GREEN(R*) SAFETY TOWELS (FLUID ONLY) COMPANY NAME: SUNSHINE MAKERS, INC. 15922 PACIFIC COAST HIGHWAY HUNTINGTON HARBOUR, CA 92649 USA TELEPHONE: 800-228-0709 562-795-6000 FAX: 562-592-3034 FOR 24-HOUR EMERGENCY, CALL CHEM-TEL, INC.: 800-255-3924 WEBSITE: WWW.SIMPLEGREEN.COM USE OF PRODUCT: A SPECIALIZED CLEANER AND DEGREASER FOR USE IN THE INDUSTRIAL AND INSTITUTIONAL WORKPLACE. (SIMPLE GREEN(R*) SAFETY TOWELS CONTAIN DILUTED CRYSTAL SIMPLE GREEN(R*).) II. INGREDIENT INFORMATION THE ONLY INGREDIENT OF CRYSTAL SIMPLE GREEN(R*) WITH ESTABLISHED EXPOSURE LIMITS IS UNDILUTED 2-BUTOXYETHANOL (<6%) (BUTYL) CELLOSOLVE; CAS NO. 111-76-2: THE ACGIH TLV-TWA IS: 20 PPM (97 MG/M3.) THE QUANTITY OF 2-BUTOXYETHANOL IN SIMPLE GREEN SAFETY TOWELS IS <1%. BASED UPON CHEMICAL ANALYSIS, CRYSTAL SIMPLE GREEN(R*) CONTAINS NO KNOWN EPA PRIORITY POLLUTANTS, HEAVY METALS, OR CHEMICALS LISTED UNDER RCRA, CERCLA, OR CWA. ANALYSIS BY TCLP (TOXICITY CHARACTERISTIC LEACHING PROCEDURE) ACCORDING TO RCRA REVEALED NO TOXIC ORGANIC OR INORGANIC CONSTITUENTS. ALL COMPONENTS OF CRYSTAL SIMPLE GREEN(R*) ARE LISTED ON THE TSCA CHEMICAL SUBSTANCE INVENTORY. III. HAZARDS IDENTIFICATION UN NUMBER: NOT REQUIRED DANGEROUS GOODS CLASS: NONHAZARDOUS NJ TRADE SECRET REGISTRATION NUMBERS: 80100235-5000P 80100235-5001P 80100235-5002P 80100235-5003P 80100235-5004P 80100235-5005P 80100235-5006P 80100235-5007P 80100235-5008P 80100235-5009P HAZARD RATING (NFPA/HMIS): HEALTH 1* REACTIVITY 0 FIRE 0 SPECIAL 0 NFPA: 1 0 0 0 RATING SCALE: 0 = MINIMAL 1 = SLIGHT 2 = MODERATE 3 = SERIOUS 4 = SEVERE *MILD EYE IRRITANT, NON-MUTAGENIC AND NON-CARCINOGENIC. NONE OF THE INGREDIENTS IN CRYSTAL SIMPLE GREEN(R*) ARE REGULATED OR LISTED AS CANCER AGENTS BY FEDERAL OSHA, NTP, OR IARC. IV. FIRST AID MEASURES SYMPTOMS OF OVEREXPOSURE AND FIRST AID TREATMENT: EYE CONTACT: REDDENING MAY DEVELOP. IMMEDIATELY RINSE THE EYE WITH LARGE QUANTITIES OF COOL WATER; CONTINUE 10-15 MINUTES OR UNTIL THE MATERIAL HAS BEEN REMOVED; BE SURE TO REMOVE CONTACT LENSES, IF PRESENT, AND TO LIFT UPPER AND LOWER LIDS DURING RINSING. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. SKIN CONTACT: MINIMAL EFFECTS, IF ANY; RINSE SKIN WITH WATER, RINSE SHOES AND LAUNDER CLOTHING BEFORE REUSE. REVERSIBLE REDDENING MAY OCCUR IN SOME DERMAL-SENSITIVE USERS; THOROUGHLY RINSE AREA AND GET MEDICAL ATTENTION IF REACTION PERSISTS. SWALLOWING: ESSENTIALLY NON-TOXIC. GIVE SEVERAL GLASSES OF WATER TO DILUTE; DO NOT INDUCE VOMITING. IF STOMACH UPSET OCCURS, CONSULT PHYSICIAN. INHALATION: NON-TOXIC. EXPOSURES TO CONCENTRATE-MIST MAY CAUSE MILD IRRITATION OF NASAL PASSAGES OR THROAT; REMOVE TO FRESH AIR. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. V. FIRE FIGHTING MEASURES CRYSTAL SIMPLE GREEN(R*) IS STABLE, NOT FLAMMABLE, AND WILL NOT BURN. FLASH POINT/AUTO-IGNITION: NOT FLAMMABLE. FLAMMABILITY LIMITS: NOT FLAMMABLE. EXTINGUISHING MEDIA: NOT FLAMMABLE/NONEXPLOSIVE. NO SPECIAL PROCEDURES REQUIRED. SPECIAL FIRE FIGHTING PROCEDURES: NONE REQUIRED. VI. ACCIDENTAL RELEASE MEASURES RECOVER USABLE MATERIAL BY CONVENIENT METHOD; RESIDUAL MAY BE REMOVED BY WIPE OR WET MOP. IF NECESSARY, UNRECOVERABLE MATERIAL MAY BE WASHED TO DRAIN WITH LARGE QUANTITIES OF WATER. VII. HANDLING, STORAGE & TRANSPORT INFORMATION NO SPECIAL PRECAUTIONS ARE REQUIRED. THIS PRODUCT IS NON-HAZARDOUS FOR STORAGE AND TRANSPORT ACCORDING TO THE U.S. DEPARTMENT OF TRANSPORTATION REGULATIONS. CRYSTAL SIMPLE GREEN(R*) REQUIRES NO SPECIAL LABELING OR PLACARDING TO MEET U.S. DEPARTMENT OF TRANSPORTATION REQUIREMENTS. UN NUMBER: NOT REQUIRED DANGEROUS GOODS CLASS: NONHAZARDOUS VIII. EXPOSURE CONTROLS EXPOSURE LIMITS: THE CRYSTAL SIMPLE GREEN(R*) FORMULATION PRESENTS NO HEALTH HAZARDS TO THE USER WHEN USED ACCORDING TO LABEL DIRECTIONS FOR ITS INTENDED PURPOSES. MILD SKIN AND EYE IRRITATION IS POSSIBLE (PLEASE SEE EYE CONTACT AND SKIN CONTACT IN SECTION IV.). VENTILATION: NO SPECIAL VENTILATION IS REQUIRED DURING USE. LARGE-SCALE USES INDOORS SHOULD PROVIDE AN INCREASED RATE OF AIR EXCHANGE. HUMAN HEALTH EFFECTS OR RISKS FROM EXPOSURE: ADVERSE EFFECTS ON HUMAN HEALTH ARE NOT EXPECTED FROM CRYSTAL SIMPLE GREEN(R*), BASED UPON TWENTY YEARS OF USE OF SIMPLE GREEN WITHOUT REPORTED ADVERSE HEALTH INCIDENCE IN DIVERSE POPULATION GROUPS, INCLUDING EXTENSIVE USE BY INMATES OF U.S. FEDERAL PRISONS IN CLEANING OPERATIONS. CRYSTAL SIMPLE GREEN(R*) IS A MILD EYE IRRITANT; MUCOUS MEMBRANES MAY BECOME IRRITATED BY CONCENTRATE-MIST. CRYSTAL SIMPLE GREEN(R*) IS NOT LIKELY TO IRRITATE THE SKIN IN THE MAJORITY OF USERS. REPEATED DAILY APPLICATION TO THE SKIN WITHOUT RINSING, OR CONTINUOUS CONTACT OF CRYSTAL SIMPLE GREEN(R*) ON THE SKIN MAY LEAD TO TEMPORARY, BUT REVERSIBLE, IRRITATION. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: NO AGGRAVATION OF EXISTING MEDICAL CONDITIONS IS EXPECTED; DERMAL-SENSITIVE USERS MAY REACT TO DERMAL CONTACT BY CRYSTAL SIMPLE GREEN(R*). IX. PERSONAL PROTECTION PRECAUTIONARY MEASURES: NO SPECIAL REQUIREMENTS UNDER NORMAL USE CONDITIONS. EYE PROTECTION: CAUTION, INCLUDING REASONABLE EYE PROTECTION, SHOULD ALWAYS BE USED TO AVOID EYE CONTACT WHERE SPLASHING MAY OCCUR. SKIN PROTECTION: NO SPECIAL PRECAUTIONS REQUIRED; RINSE COMPLETELY FROM SKIN AFTER CONTACT. RESPIRATORY PROTECTION: NO SPECIAL PRECAUTIONS REQUIRED EXCEPT DURING LARGE-SCALE SPRAY APPLICATIONS WHERE SPRAY MIST LEVELS ARE HIGH. WORK AND HYGIENIC PRACTICES: WASH OR RINSE HANDS BEFORE TOUCHING EYES OR CONTACT LENSES. FOLLOW STANDARD HYGIENIC PRACTICES FOR HANDLING CLEANING AGENTS. X. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE/ODOR: CLEAR LIQUID SPECIFIC GRAVITY: 1.020 pH OF CONCENTRATE: 9.35 EVAPORATION: >1 (BUTYL ACETATE = 1) BOILING POINT: 100.6 DEG. C (212 DEG. F ) FREEZING POINT: -9 DEG. C (16 DEG. F) IF PRODUCT FREEZES, IT WILL RECONSTITUTE WITHOUT LOSS OF EFFICACY WHEN BROUGHT BACK TO ROOM TEMPERATURE AND AGITATED. VAPOR PRESSURE: 18 MMHg @ 20 DEG. C 23.5 MMHg @ 26 DEG. C VAPOR DENSITY: 1.3 (AIR = 1) DENSITY: 8.5 LBS./GALLON VOC COMPOSITE PARTIAL PRESSURE: 0 MMHg @ 20 DEG. C VOLATILE ORGANIC COMPOUNDS (VOCS): 0 G/L PER ASTM METHOD 3960-90. PER EPA METHOD 24, VOCS ARE 5.9% AND PRODUCT MUST BE DILUTED AT LEAST 1 PART OF WATER TO 1 PART SIMPLE GREEN(R*) IN ORDER TO MEET CARB 2005 VOC REGULATIONS - OR 1 PART SIMPLE GREEN TO 3 PARTS WATER TO MEET SCAQMD RULE 1171 & RULE 1122 AND BAAQMD REGULATION 8-16 VOC REQUIREMENTS FOR SOLVENT CLEANING OPERATIONS. SAFETY TOWEL VOCS: PER EPA METHOD 24, VOCS ARE 0.5%. SAFETY TOWEL pH: 8.1 - 8.8 WATER SOLUBILITY: CRYSTAL SIMPLE GREEN(R*) IS COMPLETELY SOLUBLE IN WATER. DETECTION: CRYSTAL SIMPLE GREEN(R*) AND SIMPLE GREEN(R*) SAFETY TOWELS HAVE A CHARACTERISTIC ODOR THAT IS NOT INDICATIVE OF ANY HAZARDOUS SITUATION. XI. STABILITY AND REACTIVITY INFORMATION NONREACTIVE. CRYSTAL SIMPLE GREEN(R*) IS STABLE, EVEN UNDER FIRE CONDITIONS, AND WILL NOT REACT WITH WATER OR OXIDIZERS. HAZARDOUS POLYMERIZATION WILL NOT OCCUR. XII. TOXICOLOGICAL INFORMATION THE INFORMATION AND CONCLUSIONS CITED IN THIS SECTION ARE BASED ON DATA AND TESTING OF SIMPLE GREEN(R*). THE DATA ARE DIRECTLY APPLICABLE TO CRYSTAL SIMPLE GREEN(R*) BECAUSE BOTH FORMULATIONS ARE VIRTUALLY IDENTICAL, EXCEPT FOR FRAGRANCE AND COLOR. NONHUMAN TOXICITY: ACUTE MORTALITY STUDIES: ORAL LD50 (RAT): >5.0 G/KG BODY WEIGHT DERMAL LD50 (RABBIT): >2.0 G/KG BODY WEIGHT DERMAL IRRITATION: ONLY MILD, BUT REVERSIBLE, IRRITATION WAS FOUND IN A STANDARD 72-HR TEST ON RABBITS. A VALUE OF 0.2 (NON-IRRITATING) WAS FOUND ON A SCALE OF 8. EYE IRRITATION: WITH OR WITHOUT RINSING WITH WATER, THE IRRITATION SCORES IN RABBITS AT 24 HOURS DID NOT EXCEED 15 (MILD IRRITANT) ON A SCALE OF 110. SUBCHRONIC DERMAL EFFECTS: NO ADVERSE EFFECTS, EXCEPT REVERSIBLE DERMAL IRRITATION, WERE FOUND IN RABBITS EXPOSED TO SIMPLE GREEN(R*) (UP TO 2.0 G/KG/DAY FOR 13 WEEKS) APPLIED TO THE SKIN OF 25 MALES AND 25 FEMALES. ONLY FEMALE BODY WEIGHT GAIN WAS AFFECTED. DETAILED MICROSCOPIC EXAMINATION OF ALL MAJOR TISSUES SHOWED NO ADVERSE CHANGES. FERTILITY ASSESSMENT BY CONTINUOUS BREEDING: THE SIMPLE GREEN(R*) FORMULATION HAD NO ADVERSE EFFECT ON FERTILITY AND REPRODUCTION IN CD-1 MICE WITH CONTINUOUS ADMINISTRATION FOR 18 WEEKS, AND HAD NO ADVERSE EFFECT ON THE REPRODUCTIVE PERFORMANCE OF THEIR OFFSPRING. XIII. BIODEGRADABILITY AND ENVIRONMENTAL TOXICITY INFORMATION BIODEGRADABILITY: LIKE SIMPLE GREEN(R*), CRYSTAL SIMPLE GREEN(R*) IS READILY DECOMPOSED BY NATURALLY OCCURRING MICROORGANISMS. THE BIOLOGICAL OXYGEN DEMAND (BOD), AS A PERCENTAGE OF THE CHEMICAL OXYGEN DEMAND (COD), AFTER 4, 7, AND 11 DAYS WAS 56%, 60%, AND 70%, RESPECTIVELY. PER OECD CLOSED BOTTLE TEST, CRYSTAL SIMPLE GREEN(R*) MEETS OECD AND EPA RECOMMENDATIONS FOR READY BIODEGRADABILITY. IN A STANDARD BIODEGRADATION TEST WITH SOILS FROM THREE DIFFERENT COUNTRIES, BUTYL CELLOSOLVE REACHED 50% DEGRADATION IN 6 TO 23 DAYS, DEPENDING UPON SOIL TYPE, AND EXCEEDED THE RATE OF DEGRADATION FOR GLUCOSE, WHICH WAS USED AS A CONTROL FOR COMPARISON. ENVIRONMENTAL TOXICITY INFORMATION: CRYSTAL SIMPLE GREEN(R*) IS CONSIDERED PRACTICALLY NON-TOXIC PER EPA'S AQUATIC TOXICITY SCALE. XIV. DISPOSAL CONSIDERATIONS CRYSTAL SIMPLE GREEN(R*) IS FULLY WATER SOLUBLE AND BIODEGRADABLE AND WILL NOT HARM SEWAGE-TREATMENT MICROORGANISMS IF DISPOSAL BY SEWER OR DRAIN IS NECESSARY. DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE, AND FEDERAL LAWS. XV. OTHER INFORMATION CONTAINERS: CRYSTAL SIMPLE GREEN(R*) RESIDUES CAN BE COMPLETELY REMOVED BY RINSING WITH WATER; THE CONTAINER MAY BE RECYCLED OR APPLIED TO OTHER USES. CONTACT POINT: SUNSHINE MAKERS, INC., RESEARCH AND DEVELOPMENT DIVISION: 562-795-6000. NATIONAL STOCK NUMBERS: PART# NSN SIZE 19024 7930-01-418-1151 24 OZ. SPRAY (12/CS) 19128 7930-01-418-1152 1 GAL. (6/CS) 19005 7930-01-418-1153 5 GAL. 19055 7930-01-418-1155 55 GAL. SIMPLE GREEN SAFETY TOWEL PART NUMBERS: PART # SIZE 13353 5-COUNT POUCH (50/CS) 13351 75-COUNT CANISTER (6/CS) NOTICE: ALL INFORMATION APPEARING HEREIN IS BASED UPON DATA OBTAINED BY THE MANUFACTURER AND RECOGNIZED TECHNICAL SOURCES. JUDGMENTS AS TO THE SUITABILITY OF INFORMATION HEREIN FOR PURCHASER'S PURPOSES ARE NECESSARILY PURCHASER'S RESPONSIBILITY. THEREFORE, ALTHOUGH REASONABLE CARE HAS BEEN TAKEN IN THE PREPARATION OF THIS INFORMATION, SUNSHINE MAKERS, INC. OR ITS DISTRIBUTORS EXTENDS NO WARRANTIES, MAKES NO REPRESENTATIONS AND ASSUMES NO RESPONSIBILITY AS TO THE SUITABILITY OF SUCH INFORMATION FOR APPLICATION TO PURCHASER'S INTENDED PURPOSES OR FOR CONSEQUENCES OF ITS USE. Material Safety Data Sheet: Version No. 10013c Section 1: Simple Green® All-Purpose Cleaner Simple Green® Scrubbing Pad Date of Issue: July 2007 PRODUCT & COMPANY IDENTIFICATION Product Name: Additional Name: Simple Green® All-Purpose Cleaner Simple Green® Scrubbing Pad Simple Green® Concentrated Cleaner/Degreaser/Deodorizer Manufacturer’s Product Code Numbers: Company: Telephone: Emergency Phone: Use of Product: Section 2: ANSI-Z400.1-2003 Format *Please refer to page 4 Sunshine Makers, Inc. 15922 Pacific Coast Highway Huntington Harbour, CA 92649 USA 800-228-0709 ● 562-795-6000 Fax: 562-592-3830 Chem-Tel 24-Hour Emergency Service: 800-255-3924 An all purpose cleaner and degreaser used diluted in water for direct, spray and dip tank procedures. Scrubbing pad is used with water for manual scrubbing applications. HAZARDS IDENTIFICATION Emergency Overview: CAUTION. Mild eye irritant. Simple Green@ is a dark green liquid with a sassafras odor. Scrubbing Pad is a green fibrous rectangle. 0 0 1 0 HMIS Rating: Health = 1 = slight Fire = 0 Reactivity, and Special = 0 = minimal Eye Contact: Mild Eye Irritant. Skin Contact: No adverse effects expected under typical use conditions. Prolonged exposure may cause dryness. Under this condition, use of gloves or skin moisturizer after washing may be indicated. Ingestion: May cause stomach or intestinal upset if swallowed (due to detersive properties.) Inhalation: No adverse effects expected under typical use conditions. Adequate ventilation should be present when using Simple Green® over a prolonged period of time. Open windows or ventilate via fan or other airmoving equipment if necessary. Carcinogens: No ingredients are listed by OSHA, IARC, or NTP as known or suspected carcinogens. Medical Conditions: Not Required UN Number: Section 3: No medical conditions are known to be aggravated by exposure to Simple Green®. Dermalsensitive users may experience mild but reversible reactions. Dangerous Goods Class: Nonhazardous COMPOSITION/INFORMATION ON INGREDIENTS The only ingredient of Simple Green® with established exposure limits is undiluted 2-butoxyethanol (<6%) (Butyl Cellosolve; CAS No. 111-76-2): the ACGIH TLV-TWA is 20 ppm (97 mg/m3). Based upon chemical analysis, Simple Green® contains no known EPA priority pollutants, heavy metals or chemicals listed under RCRA, CERCLA, or CWA. Analysis by TCLP (Toxicity Characteristic Leaching Procedure) according to RCRA revealed no toxic organic or inorganic constituents. All components of Simple Green® are listed on the TSCA Chemical Substance Inventory. 80100235-5000p 80100235-5001p 80100235-5002p 80100235-5003p NJ Trade Secret Numbers 80100235-5004p 80100235-5006p 80100235-5005p 80100235-5007p Material Safety Data Sheet: SIMPLE GREEN® ALL-PURPOSE CLEANER & SCRUBBING PAD 80100235-5008p 80100235-5009p Pg 1 of 4 Material Safety Data Sheet: Version No. 10013c Simple Green® All-Purpose Cleaner Simple Green® Scrubbing Pad Date of Issue: July 2007 ANSI-Z400.1-2003 Format Section 4: FIRST AID MEASURES Eye Contact: Reddening may develop. Immediately rinse the eye with large quantities of cool water; continue 10-15 minutes or until the material has been removed; be sure to remove contact lenses, if present, and to lift upper and lower lids during rinsing. Get medical attention if irritation persists. Skin Contact: Minimal effects, if any; rinse skin with water, rinse shoes and launder clothing before reuse. Reversible reddening may occur in some dermal-sensitive users; thoroughly rinse area and get medical attention if reaction persists. Swallowing; Essentially non-toxic. Give several glasses of water to dilute; do not induce vomiting. If stomach upset occurs, consult physician. Inhalation: Non-toxic. Exposure to concentrate may cause mild irritation of nasal passages or throat; remove to fresh air. Get medical attention if irritation persists. Section 5: FIRE FIGHTING MEASURES Simple Green® is stable, not flammable, and will not burn. No special procedures required. Flash Point/Auto-Ignition: Not flammable. Flammability Limits: Not flammable. Section 6: Extinguishing Media: Not flammable/nonexplosive. Special Fire Fighting Procedures: None required. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with eyes. Do not rub eyes with hands during cleanup. No special precautions for dermal contact are needed. Wash hands thoroughly after cleaning up spill or leak. Method for cleaning up: Recover usable material by convenient method, residual may be removed by wipe or wet mop. If necessary, unrecoverable material may be washed to drain with large quantities of water. Section 7: HANDLING AND STORAGE No Special precautions are required. This product is non-hazardous for storage and transport according to the U.S. Department of Transportation Regulations. Simple Green® requires no special labeling or placarding to meet U.S. Department of Transportation requirements. Not Required UN Number: Section 8: Dangerous Goods Class: Nonhazardous EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Limits: The Simple Green® formulation presents no health hazards to the user when used according to label directions for its intended purposes. Mild skin and eye irritation is possible (please see Eye contact and Skin contact in section IV.) No special precautionary measures required under normal use conditions. Ventilation: No special ventilation, precautions or respiratory protection is required during normal use. Largescale use indoors should provide an increased rate of air exchange. Human Health Effects or Risks From Exposure: Adverse effects on human health are not expected from Simple Green®, based on 20 years of use of Simple Green® without reported adverse health incidence in diverse population groups, including extensive use by inmates of U.S. Federal prisons in cleaning operations. Eye protection: Simple Green® is a mild eye irritant; mucous membranes may become irritated by concentrate. Eye protection not generally required. Wash hands after using wipes. Skin protection: Simple Green® is not likely to irritate the skin in the majority of users. Repeated daily application to the skin without rinsing, or continuous contact on the skin may lead to temporary, but reversible, irritation. Rinse completely from skin after contact. Material Safety Data Sheet: SIMPLE GREEN® ALL-PURPOSE CLEANER & SCRUBBING PAD Pg 2 of 4 Simple Green® All-Purpose Cleaner Simple Green® Scrubbing Pad Date of Issue: July 2007 Material Safety Data Sheet: Version No. 10013c Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION – continued – General hygiene conditions: Section 9: ANSI-Z400.1-2003 Format There are no known hazards associated with this material when used as recommended. The following general hygiene considerations are recognized as common good industrial hygiene practices: - Avoid breathing vapor or mist. - Avoid contact with eyes. - Wash thoroughly after handling and before eating, drinking, or smoking. PHYSICAL AND CHEMICAL PROPERTIES Appearance & Odor: Cleaner is a dark green liquid, pad is a fibrous green matrix; both exhibit a sassafras odor. Specific Gravity: 1.020 Vapor Pressure: 18 mm Hg @ 20oC; 23.5 mmHg @ 26oC Evaporation: >1 (butyl acetate = 1) Vapor Density: 1.3 (air = 1) Water Solubility: 100% Density: 8.5 lbs/gallon pH: 9.35; Boiling Point: o o 100.6 C (212 F) Safety Towel pH is 8.1 - 8.8 o At 600 F: 1.86% by weight Nutrient Content: Phosphorus: 0.3% by formula Approx -9 C (16 F) Freezing Point: Nitrogen <1.0% by weight (fusion and qualitative test for ammonia) If product freezes, it will reconstitute without loss of efficacy Sulfur: 0.6% by weight (barium chloride precipitation method) when brought back to room temperature and agitated. o VOC Composite Partial Pressure: 0.006 mmHg @ 20 C Ash Content: o o Volatile Organic Compounds (VOCs): Per EPA Method 24, VOC’s are 5.9%. Cleaner must be diluted at least 1 part Simple Green to 2 parts water to meet CARB, and 1 part Simple Green to 3 parts water to meet SCAQMD Rule 1171 & Rule 1122 and BAAQMD Regulation 8-16 VOC requirements for solvent cleaning operations. Towel VOCs are 1.2%. Section 10: STABILITY AND REACTIVITY Stability: Materials to Avoid: Hazardous Decomposition Products: Stable None known None expected Section 11: TOXICOLOGICAL INFORMATION Nonhuman Toxicity (Data for Simple Green®) Acute Toxicity: Oral LD50 (rat): >5.0 g/kg body weight Dermal LD50 (rabbit) >2.0 g/kg body weight Eye Irritation: With or without rinsing with water, the irritation scores in rabbits at 24 hours did not exceed 15 (mild irritant) on a scale of 0-110. Dermal Irritation: Only mild, but reversible, irritation was found in a standard 72 hour test on rabbits. A value of 0.2 (non-irritating) was found on a scale of 0-8. Subchronic Dermal effects: No adverse effects, except reversible dermal irritation, were found in rabbits exposed to Simple Green (up to 2.0 g/kg/day for 13 weeks) applied to the skin of 25 males and 25 females. Only female body weight gain was affected. Fertility Assessment by Continuous Breeding: The Simple Green® formulation had no adverse effect on fertility and reproduction in Cd-1 mice with continuous administration for 18 weeks, and had no adverse effect on the reproductive performance of their offspring. Material Safety Data Sheet: SIMPLE GREEN® ALL-PURPOSE CLEANER & SCRUBBING PAD Pg 3 of 4 Simple Green® All-Purpose Cleaner Simple Green® Scrubbing Pad Material Safety Data Sheet: Version No. 10013c ANSI-Z400.1-2003 Format Date of Issue: July 2007 Section 12: ECOLOGICAL INFORMATION Biodegradability: Simple Green® is readily decomposed by naturally occurring microorganisms. The biological oxygen demand (BOD), as a percentage of the chemical oxygen demand (COD), after 4, 7, and 11 days was 56%, 60% and 70%, respectively. Per OECD Closed Bottle Test, Simple Green® meets OECD and EPA recommendations for ready biodegradability. In a standard biodegradation test with soils from three different countries, Butyl Cellosolve reached 50% degradation in 6 to 23 days, depending upon soil type, and exceeded the rate of degradation for glucose which was used as a control for comparison. Environmental Toxicity Information: Simple Green® is considered practically non-toxic per EPA’s Aquatic toxicity scale. Section 13: DISPOSAL CONSIDERATIONS Dispose of in accordance with all applicable local, state and federal laws. Dispose of used or unused product, and empty containers in accordance with the local, State, Provincial, and Federal regulations for your location. Never dispose of used degreasing rinsates into lakes, streams, and open bodies of water or storm drains. Section 14: TRANSPORT INFORMATION This product is non-hazardous for transport according to the U.S. Department of Transportation Services UN Number: Not required Dangerous Goods Class: Nonhazardous Section 15: REGULATORY INFORMATION All components are listed on: *Reportable components: RCRA Status: TSCA TRI Reporting: EINECS and TSCA Inventory None. No components listed under: Not a hazardous waste. CERCLA Status: Not required / Not listed CA PROP. 65 Status: Clean Air Act Section 112 No components listed No components listed Section 16: OTHER INFORMATION Questions about the information found on this MSDS should be directed to: SUNSHINE MAKERS, INC. – TECHNICAL DEPARTMENT 15922 Pacific Coast Hwy. Huntington Harbour, CA 92649 Phone: 800/228-0709 [8am-5pm Pacific time, Mon-Fri] Fax: 562/592-3830 National Stock Numbers & Industrial Numbers: Simple Green Scrubbing Pad Part Number 13012 13005 13006 13016 13008 Part Number 10224 NSN 7930-01-342-5315 7930-01-306-8369 7930-01-342-5316 7930-01-342-5317 7930-01-342-4145 NSN 7930-01-346-9148 Email: infoweb@simplegreen.com Retail Numbers: Size 24 oz spray (12/case) 1 Gallon (6/case) 5 Gallon 15 Gallon 55 Gallon Size Each (24/case) Part Number 13002 13005 13013 13014 13033 Size 16 oz Trigger (12/case) 1 Gallon (6/case) 24 oz Trigger (12/case) 67 oz / 2 L (6/case) 32 oz Trigger (12/case) * part number is for both industrial and retail **International Part Numbers May Differ. DISCLAIMER: The information provided with this MSDS is furnished in good faith and without warranty of any kind. Personnel handling this material must make independent determinations of the suitability and completeness of information from all sources to assure proper use and disposal of this material and the safety and health of employees and customers. Sunshine Makers, Inc. assumes no additional liability or responsibility resulting from the use of, or reliance on this information. Material Safety Data Sheet: SIMPLE GREEN® ALL-PURPOSE CLEANER & SCRUBBING PAD Pg 4 of 4 Material Safety Data Sheet: Version No. 10013c Section 1: Simple Green® All-Purpose Cleaner Simple Green® Scrubbing Pad Date of Issue: July 2007 PRODUCT & COMPANY IDENTIFICATION Product Name: Additional Name: Simple Green® All-Purpose Cleaner Simple Green® Scrubbing Pad Simple Green® Concentrated Cleaner/Degreaser/Deodorizer Manufacturer’s Product Code Numbers: Company: Telephone: Emergency Phone: Use of Product: Section 2: ANSI-Z400.1-2003 Format *Please refer to page 4 Sunshine Makers, Inc. 15922 Pacific Coast Highway Huntington Harbour, CA 92649 USA 800-228-0709 ● 562-795-6000 Fax: 562-592-3830 Chem-Tel 24-Hour Emergency Service: 800-255-3924 An all purpose cleaner and degreaser used diluted in water for direct, spray and dip tank procedures. Scrubbing pad is used with water for manual scrubbing applications. HAZARDS IDENTIFICATION Emergency Overview: CAUTION. Mild eye irritant. Simple Green@ is a dark green liquid with a sassafras odor. Scrubbing Pad is a green fibrous rectangle. 0 0 1 0 HMIS Rating: Health = 1 = slight Fire = 0 Reactivity, and Special = 0 = minimal Eye Contact: Mild Eye Irritant. Skin Contact: No adverse effects expected under typical use conditions. Prolonged exposure may cause dryness. Under this condition, use of gloves or skin moisturizer after washing may be indicated. Ingestion: May cause stomach or intestinal upset if swallowed (due to detersive properties.) Inhalation: No adverse effects expected under typical use conditions. Adequate ventilation should be present when using Simple Green® over a prolonged period of time. Open windows or ventilate via fan or other airmoving equipment if necessary. Carcinogens: No ingredients are listed by OSHA, IARC, or NTP as known or suspected carcinogens. Medical Conditions: Not Required UN Number: Section 3: No medical conditions are known to be aggravated by exposure to Simple Green®. Dermalsensitive users may experience mild but reversible reactions. Dangerous Goods Class: Nonhazardous COMPOSITION/INFORMATION ON INGREDIENTS The only ingredient of Simple Green® with established exposure limits is undiluted 2-butoxyethanol (<6%) (Butyl Cellosolve; CAS No. 111-76-2): the ACGIH TLV-TWA is 20 ppm (97 mg/m3). Based upon chemical analysis, Simple Green® contains no known EPA priority pollutants, heavy metals or chemicals listed under RCRA, CERCLA, or CWA. Analysis by TCLP (Toxicity Characteristic Leaching Procedure) according to RCRA revealed no toxic organic or inorganic constituents. All components of Simple Green® are listed on the TSCA Chemical Substance Inventory. 80100235-5000p 80100235-5001p 80100235-5002p 80100235-5003p NJ Trade Secret Numbers 80100235-5004p 80100235-5006p 80100235-5005p 80100235-5007p Material Safety Data Sheet: SIMPLE GREEN® ALL-PURPOSE CLEANER & SCRUBBING PAD 80100235-5008p 80100235-5009p Pg 1 of 4 Material Safety Data Sheet: Version No. 10013c Simple Green® All-Purpose Cleaner Simple Green® Scrubbing Pad Date of Issue: July 2007 ANSI-Z400.1-2003 Format Section 4: FIRST AID MEASURES Eye Contact: Reddening may develop. Immediately rinse the eye with large quantities of cool water; continue 10-15 minutes or until the material has been removed; be sure to remove contact lenses, if present, and to lift upper and lower lids during rinsing. Get medical attention if irritation persists. Skin Contact: Minimal effects, if any; rinse skin with water, rinse shoes and launder clothing before reuse. Reversible reddening may occur in some dermal-sensitive users; thoroughly rinse area and get medical attention if reaction persists. Swallowing; Essentially non-toxic. Give several glasses of water to dilute; do not induce vomiting. If stomach upset occurs, consult physician. Inhalation: Non-toxic. Exposure to concentrate may cause mild irritation of nasal passages or throat; remove to fresh air. Get medical attention if irritation persists. Section 5: FIRE FIGHTING MEASURES Simple Green® is stable, not flammable, and will not burn. No special procedures required. Flash Point/Auto-Ignition: Not flammable. Flammability Limits: Not flammable. Section 6: Extinguishing Media: Not flammable/nonexplosive. Special Fire Fighting Procedures: None required. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with eyes. Do not rub eyes with hands during cleanup. No special precautions for dermal contact are needed. Wash hands thoroughly after cleaning up spill or leak. Method for cleaning up: Recover usable material by convenient method, residual may be removed by wipe or wet mop. If necessary, unrecoverable material may be washed to drain with large quantities of water. Section 7: HANDLING AND STORAGE No Special precautions are required. This product is non-hazardous for storage and transport according to the U.S. Department of Transportation Regulations. Simple Green® requires no special labeling or placarding to meet U.S. Department of Transportation requirements. Not Required UN Number: Section 8: Dangerous Goods Class: Nonhazardous EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Limits: The Simple Green® formulation presents no health hazards to the user when used according to label directions for its intended purposes. Mild skin and eye irritation is possible (please see Eye contact and Skin contact in section IV.) No special precautionary measures required under normal use conditions. Ventilation: No special ventilation, precautions or respiratory protection is required during normal use. Largescale use indoors should provide an increased rate of air exchange. Human Health Effects or Risks From Exposure: Adverse effects on human health are not expected from Simple Green®, based on 20 years of use of Simple Green® without reported adverse health incidence in diverse population groups, including extensive use by inmates of U.S. Federal prisons in cleaning operations. Eye protection: Simple Green® is a mild eye irritant; mucous membranes may become irritated by concentrate. Eye protection not generally required. Wash hands after using wipes. Skin protection: Simple Green® is not likely to irritate the skin in the majority of users. Repeated daily application to the skin without rinsing, or continuous contact on the skin may lead to temporary, but reversible, irritation. Rinse completely from skin after contact. Material Safety Data Sheet: SIMPLE GREEN® ALL-PURPOSE CLEANER & SCRUBBING PAD Pg 2 of 4 Simple Green® All-Purpose Cleaner Simple Green® Scrubbing Pad Date of Issue: July 2007 Material Safety Data Sheet: Version No. 10013c Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION – continued – General hygiene conditions: Section 9: ANSI-Z400.1-2003 Format There are no known hazards associated with this material when used as recommended. The following general hygiene considerations are recognized as common good industrial hygiene practices: - Avoid breathing vapor or mist. - Avoid contact with eyes. - Wash thoroughly after handling and before eating, drinking, or smoking. PHYSICAL AND CHEMICAL PROPERTIES Appearance & Odor: Cleaner is a dark green liquid, pad is a fibrous green matrix; both exhibit a sassafras odor. Specific Gravity: 1.020 Vapor Pressure: 18 mm Hg @ 20oC; 23.5 mmHg @ 26oC Evaporation: >1 (butyl acetate = 1) Vapor Density: 1.3 (air = 1) Water Solubility: 100% Density: 8.5 lbs/gallon pH: 9.35; Boiling Point: o o 100.6 C (212 F) Safety Towel pH is 8.1 - 8.8 o At 600 F: 1.86% by weight Nutrient Content: Phosphorus: 0.3% by formula Approx -9 C (16 F) Freezing Point: Nitrogen <1.0% by weight (fusion and qualitative test for ammonia) If product freezes, it will reconstitute without loss of efficacy Sulfur: 0.6% by weight (barium chloride precipitation method) when brought back to room temperature and agitated. o VOC Composite Partial Pressure: 0.006 mmHg @ 20 C Ash Content: o o Volatile Organic Compounds (VOCs): Per EPA Method 24, VOC’s are 5.9%. Cleaner must be diluted at least 1 part Simple Green to 2 parts water to meet CARB, and 1 part Simple Green to 3 parts water to meet SCAQMD Rule 1171 & Rule 1122 and BAAQMD Regulation 8-16 VOC requirements for solvent cleaning operations. Towel VOCs are 1.2%. Section 10: STABILITY AND REACTIVITY Stability: Materials to Avoid: Hazardous Decomposition Products: Stable None known None expected Section 11: TOXICOLOGICAL INFORMATION Nonhuman Toxicity (Data for Simple Green®) Acute Toxicity: Oral LD50 (rat): >5.0 g/kg body weight Dermal LD50 (rabbit) >2.0 g/kg body weight Eye Irritation: With or without rinsing with water, the irritation scores in rabbits at 24 hours did not exceed 15 (mild irritant) on a scale of 0-110. Dermal Irritation: Only mild, but reversible, irritation was found in a standard 72 hour test on rabbits. A value of 0.2 (non-irritating) was found on a scale of 0-8. Subchronic Dermal effects: No adverse effects, except reversible dermal irritation, were found in rabbits exposed to Simple Green (up to 2.0 g/kg/day for 13 weeks) applied to the skin of 25 males and 25 females. Only female body weight gain was affected. Fertility Assessment by Continuous Breeding: The Simple Green® formulation had no adverse effect on fertility and reproduction in Cd-1 mice with continuous administration for 18 weeks, and had no adverse effect on the reproductive performance of their offspring. Material Safety Data Sheet: SIMPLE GREEN® ALL-PURPOSE CLEANER & SCRUBBING PAD Pg 3 of 4 Simple Green® All-Purpose Cleaner Simple Green® Scrubbing Pad Material Safety Data Sheet: Version No. 10013c ANSI-Z400.1-2003 Format Date of Issue: July 2007 Section 12: ECOLOGICAL INFORMATION Biodegradability: Simple Green® is readily decomposed by naturally occurring microorganisms. The biological oxygen demand (BOD), as a percentage of the chemical oxygen demand (COD), after 4, 7, and 11 days was 56%, 60% and 70%, respectively. Per OECD Closed Bottle Test, Simple Green® meets OECD and EPA recommendations for ready biodegradability. In a standard biodegradation test with soils from three different countries, Butyl Cellosolve reached 50% degradation in 6 to 23 days, depending upon soil type, and exceeded the rate of degradation for glucose which was used as a control for comparison. Environmental Toxicity Information: Simple Green® is considered practically non-toxic per EPA’s Aquatic toxicity scale. Section 13: DISPOSAL CONSIDERATIONS Dispose of in accordance with all applicable local, state and federal laws. Dispose of used or unused product, and empty containers in accordance with the local, State, Provincial, and Federal regulations for your location. Never dispose of used degreasing rinsates into lakes, streams, and open bodies of water or storm drains. Section 14: TRANSPORT INFORMATION This product is non-hazardous for transport according to the U.S. Department of Transportation Services UN Number: Not required Dangerous Goods Class: Nonhazardous Section 15: REGULATORY INFORMATION All components are listed on: *Reportable components: RCRA Status: TSCA TRI Reporting: EINECS and TSCA Inventory None. No components listed under: Not a hazardous waste. CERCLA Status: Not required / Not listed CA PROP. 65 Status: Clean Air Act Section 112 No components listed No components listed Section 16: OTHER INFORMATION Questions about the information found on this MSDS should be directed to: SUNSHINE MAKERS, INC. – TECHNICAL DEPARTMENT 15922 Pacific Coast Hwy. Huntington Harbour, CA 92649 Phone: 800/228-0709 [8am-5pm Pacific time, Mon-Fri] Fax: 562/592-3830 National Stock Numbers & Industrial Numbers: Simple Green Scrubbing Pad Part Number 13012 13005 13006 13016 13008 Part Number 10224 NSN 7930-01-342-5315 7930-01-306-8369 7930-01-342-5316 7930-01-342-5317 7930-01-342-4145 NSN 7930-01-346-9148 Email: infoweb@simplegreen.com Retail Numbers: Size 24 oz spray (12/case) 1 Gallon (6/case) 5 Gallon 15 Gallon 55 Gallon Size Each (24/case) Part Number 13002 13005 13013 13014 13033 Size 16 oz Trigger (12/case) 1 Gallon (6/case) 24 oz Trigger (12/case) 67 oz / 2 L (6/case) 32 oz Trigger (12/case) * part number is for both industrial and retail **International Part Numbers May Differ. DISCLAIMER: The information provided with this MSDS is furnished in good faith and without warranty of any kind. Personnel handling this material must make independent determinations of the suitability and completeness of information from all sources to assure proper use and disposal of this material and the safety and health of employees and customers. Sunshine Makers, Inc. assumes no additional liability or responsibility resulting from the use of, or reliance on this information. Material Safety Data Sheet: SIMPLE GREEN® ALL-PURPOSE CLEANER & SCRUBBING PAD Pg 4 of 4 Page 1 of 4 Procter & Gamble CPG TN 6 2 Procter & Gamble Plaza Cincinnati, OH 45202 MATERIAL SAFETY DATA SHEET Issue Date: 12/2005 Issue Date: 8/01 Supersedes: N/A SECTION I - CHEMICAL PRODUCT Identity: Granular Cleaner with Bleach Brands: SPIC and SPAN Floor Cleaner with BLEACH (non-phosphate & phosphate) Hazard Rating: 1 Health: 1 4=EXTREME Flammability: 0 3=HIGH Reactivity: 0 2= MODERATE 1=SLIGHT Emergency Telephone Number: - 1-800-332-7787 or call Local Poison Control Center SECTION II - COMPOSITION AND INGREDIENTS Ingredients/Chemical Name: Anionic surfactants, water softeners (sodium carbonate, complex sodium phosphates [phosphate version]), dry chlorine bleach, processing aids (sodium sulfate), metal protection agents (sodium silicates). This product is a mild eye irritant within the meaning of the OSHA Hazard Communication Standard Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200 and/or WHMIS under the Hazardous Product Act. Common CAS No. Recommended Limits Composition LD50/LC50 Chemical Name Name Range Sodium carbonate Soda Ash 497-19-8 N/A 15-40% (OP) LD50=1.86 10-25% (P) g/kg LC50=N/A Sodium 2893-78-9 AGCY OSHA 10-15% LD50=735 Sodium DCC TLV PEL mg/kg rat dichloroisocynanurate 10 mg/m3 15 mg/m3 dihydrate C12.3 LAS 68081-81-2 15-30% LD50=0.65Linear alkyl benzene 1.26 g/kg sulfonate N/A LC50=N/A SECTION III - HAZARDS IDENTIFICATION Health Hazards & Symptoms (Acute and Chronic): Ingestion: May cause transient gastrointestinal irritation with nausea, vomiting and/or diarrhea. Eye Contact: May cause mild, transient irritation with stinging, tearing, itching,swelling and redness. Inhalation: Heavy or prolonged exposure to dust may cause transient respiratory tract irritation with coughing, sore throat, wheezing or transitiory shortness of breath. SPIC and SPAN Floor Cleaner with BLEACH (non-phosphate & phosphate) MSDS (Continued) Page 2 of 4 SECTION IV - FIRST AID INFORMATION Emergency and First Aid Procedures: Ingestion: Drink 1 or 2 large glasses of water. If large amounts are ingested, call a physician. Eye Contact: Flush with large amounts of water for at 10-15 minutes. Skin: Rinse skin thoroughly with water. Discontinue use. Inhalation: Leave dusty area. Other: Product package has a caution statement: CAUTION:. May cause eye/skin irritation. Eye irritant. Avoid eye contact. Do not mix with other cleaning products as irritating fumes may be released. May be irritating to skin. For sensitive skin or prolonged use, wear gloves. If eye or skin contact occurs, flush with water for 15 minutes. If irritation persists, seek medical attention. KEEP OUT OF REACH OF CHILDREN SECTION V - FIRE FIGHTING INFORMATION Flash Point (Method Used): N/A Explosive Limits: LEL: N/A UEL: N/A Extinguishing Media: CO2 , water, or dry chemical Special Fire Fighting Procedures: None known. Unusual Fire Hazards : N/A SECTION VI - ACCIDENTAL RELEASE MEASURES Personal Precautions: None Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL, PROVINCIAL AND LOCAL REGULATIONS. Solutions may be disposed of in sewer. Dry product may be landfilled if permitted by local regulations. Discard empty container in trash. Steps To Be Taken in Case Material is Released or Spilled: Dispose as dry scrap or flush small quantities down acceptable sewer (contains biodegradable surfactants). Dispose of according to local regulations. Prevent heavy exposure to dust with NIOSH approved dust mask. SECTION VII - HANDLING AND STORAGE Precautions To Be Taken in Handling and Storing: Store in a cool, dry place. Keep product dry to maintain freeflowing granules. Other Precautions: None SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION Respiratory Protection (Specify Type): None required with normal use. Ventilation Local Exhaust: None required with normal use. Special: None Mechanical (General): Acceptable. Other: None Eye Protection: None required with normal use. Manufacturing Setting: With dusty conditions or if a splash is likely, chemical goggles may be needed. Protective Gloves: None required with normal use. Manufacturing Setting: Protective gloves (rubber, neoprene) should be used for any prolonged direct contact. Other Protective Equipment: None required with normal use. 2 SPIC and SPAN Floor Cleaner with BLEACH (non-phosphate & phosphate) MSDS (Continued) Page 3 of 4 SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES Boiling Point ° F: N/A Specific Gravity (H2 O=1): N/A Vapor Pressure (mm Hg): N/A Percent Volatile by Volume (%): N/A Vapor Density (Air=1): N/A Evaporation Rate (nBuOAc=1): N/A Odor Threshold: N/A Freezing Point: N/A Coefficient of Water/Oil Distribution: N/A pH (1% solution): ~10.9 Scooped Density: 0.4/cc (bulk density) Solubility in Water: Mostly Appearance and Odor: White granule with green specks and bland odor Reserve Alkalinity: 4.0 max SECTION X - STABILITY AND REACTIVITY Possible Hazardous Reactions/Conditions: None known Conditions to Avoid: None Materials to Avoid: Products which contain ammonia or are acidic Hazardous Decomposition Products: Chlorine gas Other Recommendations: None Stability: Stable Hazardous Polymerization: Will not occur SECTION XI - TOXICOLOGICAL INFORMATION LD50 (rats oral): 2.9g/kg SECTION XII - ECOLOGICAL INFORMATION None SECTION XIII - DISPOSAL CONSIDERATIONS Waste Disposal Method: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH FEDERAL, PROVINCIAL AND LOCAL REGULATIONS. Small quantities may be disposed of in sewer. Dry product may be landfilled. Discard empty container in trash. SECTION XIV - TRANSPORT INFORMATION DOT Classification: The finished product is not DOT hazardous. 3 SPIC and SPAN Floor Cleaner with BLEACH (non-phosphate & phosphate) MSDS (Continued) Page 4 of 4 SECTION XV - ADDITIONAL REGULATORY INFORMATION All components are listed on the US TSCA Inventory. No components are affected by Significant New Use Rules (SNURs) under TSCA §5. No components of Spic and Span with Bleach are subject to California Proposition 65. All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified with Hazard Criteria of the Canadian Control Products Regulation (CPR) and this MSDS contains all information required by the Canadian Products Regulation. *N/A. - Not Applicable SECTION XVI - OTHER INFORMATION *N/K. - Not Known The submission of this MSDS may be required by law, but this is not an assertion that the substance is hazardous when used in accordance with proper safety practices and normal handling procedures. Data supplied is for use only in connection with occupational safety and health. The information contained herein has been compiled from sources considered by Procter & Gamble to be dependable and is accurate to the best of the Company’s knowledge. The information relates to the specific material designated herein, and does not relate to the use in combination with any other material or any other process. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, for any damage to any property resulting from misuse of the controlled product. 4 Page 1 de 4 Procter & Gamble CPG TN 6 2, Procter & Gamble Plaza Cincinnati (Ohio) 45202 FICHE SIGNALÉTIQUE Date de publication : 12-2005 Date de publication : 8-01 Remplace : S.O. SECTION 1 – IDENTIFICATION DU PRODUIT Identification : Nettoyant granulaire avec javellisant Marques : Nettoyant avec JAVELLISANT pour planchers SPIC and SPAN (sans phosphate et avec phosphate) Évaluation du danger : 1 Santé : 1 4 = EXTRÊME Inflammabilité : 0 3 = ÉLEVÉ Réactivité : 0 2 = MODÉRÉ 1 = LÉGER Numéro de téléphone en cas d’urgence : 1 800 332-7787 ou appelez le centre antipoison de votre localité. SECTION II – COMPOSITION ET INGRÉDIENTS Ingrédients/Nom chimique : Agents de surface anioniques, adoucisseurs d’eau (carbonate de sodium, complexe de phosphates sodiques [version avec phosphate]), produit à blanchir au chlore en poudre, agent technologique [sulfate de sodium], agent de protection contre les particules métalliques [silicate de sodium]) Ce produit est un irritant oculaire léger en vertu de la norme de communication de la Occupational Safety and Health Administration (OSHA). Ingrédients dangereux tels que définis par la OSHA, 29 CFR 1910.1200 et/ou la SIMDUT en vertu de la Loi sur les produits dangereux. No de CAS Limites recommandées Écart de la DL50/CL50 Nom chimique Nom commun composition chimique Carbonate de Bicarbonate de 497-19-8 S.O. 15 à 40 % DL50=1,86 g/kg sodium soude (O.P.) 10 à 25 % CL50 = S.O. (PHOSPHO RE) Dichloroisocyanur ate de sodium dihydraté Sodium DCC 2893-78-9 AGCY VLE 10 à 15 % DL50=735 mg/kg chez le rat 15 à 30 % DL50=0,651,26 g/kg CL50 = S.O. 10 mg/m3 OSHA PEL 15mg/m3 Alkyl benzène sulfonate linéaire alkylsulfonate linéaire 68081-81-2 S.O. Nettoyant avec JAVELLISANT pour planchers SPIC and SPAN (sans phosphate et avec phosphate) – Fiche signalétique (suite) Page 2 de 4 SECTION III – IDENTIFICATION DES DANGERS Dangers pour la santé (aigus et chroniques) : Ingestion : L’ingestion du produit peut causer une irritation gastro-intestinale passagère provoquant nausées, vomissements et/ou diarrhée. Contact avec les yeux : Peut causer une irritation passagère légère accompagnée d’une sensation de brûlure, des larmoiements, un prurit, de l’œdème et des rougeurs. Inhalation : L’exposition intense ou prolongée à la poussière du produit peut causer une irritation passagère des voies respiratoires accompagnée de toux, de maux de gorge, de sifflement ou de dyspnée passagère. SECTION IV – PREMIERS SOINS Procédures d’urgence et de premiers soins : Ingestion : Boire un ou deux grands verres d’eau. Si une quantité importante de produit est ingérée, consultez un médecin. Contact avec les yeux : Rincer à grande eau pendant au moins 10 à 15 minutes. Peau : Rincez abondamment avec de l’eau. Cesser l’emploi. Inhalation : Quitter le lieu empoussiéré. Autre : L’emballage du produit comporte un énoncé de risques : MISE EN GARDE : Peut causer une irritation des yeux/de la peau. Irritant oculaire : Éviter le contact avec les yeux. Ne pas mélanger avec d’autres produits nettoyants puisque des vapeurs irritantes pourraient être émises. Peut être irritant pour la peau. En cas de peau sensible ou de contact prolongé, le port de gants est recommandé. Dans le cas d’un contact avec les yeux ou la peau, rincer à grande eau pendant au moins 15 minutes. Si l’irritation persiste, consulter un médecin. TENIR HORS DE LA PORTÉE DES ENFANTS. SECTION – RENSEIGNEMENTS CONCERNANT LES MOYENS D’EXTINCTION Point d’éclair (méthode utilisée) : S.O. Limites d’explosion : LIE : S.O. LES : S.O. Moyens d’extinction : CO2, eau ou poudre extinctrice Procédures spéciales d’extinction : Aucune connue Risques d’incendie inhabituels : S.O. SECTION VI – MESURES À PRENDRE EN CAS DE DÉVERSEMENT ACCIDENTEL Précautions personnelles : S.O. Précautions environnementales : ÉLIMINER CONFORMÉMENT AUX RÈGLEMENTS FÉDÉRAUX, PROVINCIAUX ET LOCAUX. Les solutions domestiques peuvent être évacuées dans l’égout. Le produit sec peut être enfoui si les règlements locaux le permettent. Jeter les contenants vides dans la poubelle. Mesures à prendre en cas de fuite ou de déversement : Les petites quantités peuvent être progressivement évacuées dans les égouts appropriés (contient des surfactifs biodégradables). Éliminer conformément aux règlements applicables. Prévenir l’exposition intense à la poussière au moyen d’un appareil respiratoire approuvé par le NIOSH. 2 Nettoyant avec JAVELLISANT pour planchers SPIC and SPAN (sans phosphate et avec phosphate) – Fiche signalétique (suite) Page 3 de 4 SECTION VII – MANUTENTION ET ENTREPOSAGE Précautions à prendre pour la manutention et l’entreposage : Entreposer dans un lieu frais et sec. Éviter l’humidité pour éviter que les granules ne s’agglomèrent. Autres précautions : Aucune SECTION VIII – PROTECTION PERSONNELLE ET CONTRÔLE DE L’EXPOSITION AU PRODUIT Protection des voies respiratoires (spécifier le type) : Aucune dans des conditions normales d’utilisation. Ventilation : Ventilation par aspiration à la source : Aucune dans des conditions normales d’utilisation.. Spéciale : Aucune Mécanique (générale) : Acceptable. Autre : Aucune Protection des yeux : Non requise à l’usage normal. Industrie manufacturière : Dans des conditions poussiéreuses ou si une éclaboussure est probable, des lunettes protectrices contre les agents chimiques pourraient s’avérer nécessaires. Gants de protection : Non requis à l’usage normal. Industrie manufacturière : Des gants de protection (caoutchouc, néoprène) s’imposent dans le cas des contacts directs prolongés. Autre équipement de protection : Non requis à l’usage normal. SECTION IX – PROPRIÉTÉS PHYSIQUES ET CHIMIQUES Point d’ébullition (°°F) : S.O. Densité (H2O=1) : S.O. Tension de vapeur (mm Hg) : S.O. Pourcentage volatile au volume (%) : S.O. Densité de vapeur (Air=1) : S.O. Taux d’évaporation (nBuOAc=1) : S.O. Seuil de l’odeur : S.O. Point de congélation : S.O. Coefficient de répartition eau-huile : S.O. pH (solution 1 %) : environ10,9 Densité volumique : 0,4/en vase fermé (densité apparente) Solubilité dans l’eau : Importante Apparence et odeur : Poudre blanche avec granules verts à la senteur neutre Alcalinité : 4,0 max SECTION X – STABILITÉ ET RÉACTIVITÉ Réactions/conditions dangereuses possibles : Aucune connue Conditions à éviter : Aucune Matériaux à éviter : Produits contenant de l’ammoniaque et acides Produits de décomposition dangereux : Chlore gazeux Autres recommandations : Aucune Stabilité chimique : Stable Polymérisation dangereuse : Impossible 3 Nettoyant avec JAVELLISANT pour planchers SPIC and SPAN (sans phosphate et avec phosphate) – Fiche signalétique (suite) Page 4 de 4 SECTION XI – PROPRIÉTÉS TOXICOLOGIQUES DL50 (ingestion chez le rat) : 2,9 g/kg SECTION XII – INFORMATION ÉCOLOGIQUE Aucune. SECTION XIII – RÈGLEMENTS CONCERNANT L’ÉLIMINATION Méthode d’élimination : ÉLIMINER CONFORMÉMENT AUX RÈGLEMENTS FÉDÉRAUX, PROVINCIAUX ET LOCAUX. Les petites quantités peuvent être évacuées dans l’égout. Le produit sec peut être enfoui. Jeter les contenants vides dans la poubelle. SECTION XIV – INFORMATION CONCERNANT LE TRANSPORT Classification DOT : Le produit fini est non-toxique selon le ministère des Transports (DOT). SECTION XV – RENSEIGNEMENTS SUPPLÉMENTAIRES SUR LA RÈGLEMENTATION Toutes les composantes figurent sur l’inventaire du TSCA. Les règles de la nouvelle utilisation importante ne modifie en aucun cas les composantes conformément à l’inventaire du TSCA §5. Aucune des composantes du nettoyant avec javellisant Spic and Span n’est assujettie à la proposition 65 de la Californie. Tous les ingrédients ont été approuvés par la LCPE et peuvent être importés au Canada par Procter & Gamble. Ce produit a été classé sous la catégorie Critères de risque du règlement canadien régissant les produits contrôlés et cette fiche signalétique contient toute l’information requise par ledit règlement. *S.O. - Sans objet SECTION XVI – AUTRES RENSEIGNEMENTS *INC. - Inconnu La présentation de cette fiche signalétique est requise par la loi, mais ce n’est pas une affirmation que la substance est dangereuse lorsque celle-ci est utilisée en respectant les bonnes règles de sécurité et les méthodes de manutention normales. Les données fournies ne peuvent être utilisées que dans le cadre de la sécurité et de la santé au travail. Les renseignements de la présente fiche ont été compilés à partir de sources considérées comme fiables par la société Procter & Gamble, et sont exacts à sa connaissance. Ces renseignements ne concernent que la matière désignée par la présente fiche et non son utilisation en combinaison avec toute autre matière ou tout autre procédé. Procter & Gamble n’est pas responsable des blessures infligées au destinataire ou à une tierce personne, ni d’aucun dommage à la propriété résultant d’une utilisation incorrecte de produit contrôlé. 4 MATERIAL SAFETY DATA SHEET SECTION 1. PRODUCT/MANUFACTURER'S IDENTITY PRODUCT NAME: OVEN & GRILL CLEANER PRODUCT I.D. NUMBER (PIN): 1719 PRODUCT NUMBER: 02806FS PRODUCT USE: Oven and grill cleaner WHMIS CLASS: 3 0 1 C DOT HAZARD CLASS: Corrosive Material COMPANY: Essential Industries, Inc. P.O. Box 12 Merton, WI 53056-0012 DOT SHIPPING NAME: Caustic Alkali Liquid, N.O.S. (Potassium hydroxide, Sodium metasilicate) 8, UN1719, PGIII 800-843-6174 EMERGENCY PHONE: H.M.I.S. E; D2B HEALTH HAZARD RATING FIRE 4 = Extreme 3 = High 2 = Moderate 1 = Slight 0 = Insignificant REACTIVITY MAXIMUM PERSONAL PROTECTION A = Goggles B = Goggles & Gloves C = Goggles, Gloves & Apron ABBREVIATION KEY: N.A. - Not Applicable N.E. = Not Established N.D. = Not Determined SECTION 2 - HAZARDOUS INGREDIENTS INFORMATION % 60-100 5-10 1-5 10-30 CAS NO. 7732-18-5 1310-58-3 6834-92-0 N.A. HAZARDOUS CHEMICAL IDENTITY Water Potassium hydroxide Sodium metasilicate Surfactants PEL N.E. 2mg/m3 2mg/m3 N.E. TLV N.E. 2mg/m3 2mg/m3 N.E. LD50 N.D. 365mg/kg 847mg/kg N.D. LC50 N.D. N.D. N.D. N.D. This mixture does not contain components which are subject to the reporting requiements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR, Part 372. SECTION 3 - PHYSICAL DATA Color: Boiling Point: Purple Odor: Bland Physical State: Liquid Solubility in Water: Complete 100°C (212°F) Freezing Point: 0°C (32°F) Water/Oil Distribution: N.E. Vapor Density (Air=1): <1 Evaporation Rate (Water=1): Odor Threshold: VOC Content: pH: 13.0 - 14.0 Vapor Pressure: <30 mm of Hg N.E. 1% pH: 11.8 N.E. 0.0% Specific Gravity: 1.10 gm/ml Weight per Gallon: 9.19 lbs./gal. SECTION 4 - FIRE AND EXPLOSION HAZARD DATA Flash Point and Method: N.A. Autoignition Temperature: N.A. Extinguishing Media: Flammable Limits: N.A. LEL: N.A. Special Fire Fighting Procedures: UEL: N.A. Hazardous Combustion Products: N.A. Use dry chemical or CO2. Use proper protective equipment. Unusual Fire and Explosion Hazards: None. SECTION 5 - REACTIVITY DATA Chemical Stability: Hazardous decomposition of By-Products: None known. Stable. Incompatibility (Materials to Avoid): Acids, aluminum and other soft metals. Hazardous Polymerization: Will not occur. SECTION 6 - TOXICOLOGICAL PROPERTIES Routes of Entry: Ingestion. Inhalation. Skin contact. Eye contact. Toxicologically Synergistic Products: No. Sensitization: None known. Medical Conditions Aggravated by Exposure: None known. EFFECTS OF OVEREXPOSURE (Acute and/or Chronic): Eyes: May cause severe irritation, redness, burns and possible corneal injury. Carcinogenic Effects: NO carcinogenic effect. Skin: May cause severe irritation, redness, burns. Mutagenic Effects: NO mutagenic effect. Ingestion: May cause severe irritation or burning of gastrointestinal tract and possible mucosal Teratogenic Effects: NO teratogenic effect. injury. Reproductive Toxicity: Inhalation: May irritate respiratory tract when used with inadequate ventilation. NO reproductive toxicity effect. SECTION 7 - PREVENTATIVE AND CONTROL MEASURES Respiratory Protection: None normally required with adequate ventilation. Protective Gloves: Rubber/Neoprene. Protective Clothing and Equipment: Full cover clothing - rubber apron. Storage Requirements: Store in cool, dry area. Follow good housekeeping practices. Steps to be Taken if Material is Spilled or Released: Waste Disposal: Ventilation: Local Exhaust: Acceptable Mechanical: Recommended Eye Protection: Chemical splash goggles. Work and Hygienic Practices: After handling, always wash hands thoroughly with soap and water. Other Requirements: Keep out of reach of children. Collect and reuse if possible. Dilute and flush to sewer with large quantities of water if permitted by regulatory authorities or absorb on inert material (sand, clay, etc.) and place into container for proper disposal. Do not allow runoff into public waterways. Dispose of as permitted by all federal, provincial, state and local regulatory authorities. SECTION 8 - EMERGENCY FIRST AID PROCEDURES FIRST AID - NOTES TO PHYSICIAN: Eyes: Flush with a large amount of water for 30 minutes holding eyelids open. Seek medical attention. Skin: Remove contaminated clothing and footwear. Flood/shower with water for 30 minutes. Ingestion: Rinse mouth with water. Give 2-3 large glasses of water. Do not induce vomiting. Seek medical attention. Inhalation:Remove to fresh air and rest. In all cases if symptoms persist, seek medical attention. Note to Physician: No additional information. SECTION 9 - PREPARATION INFORMATION Prepared By: Regulatory Affairs Department Phone: 262-538-1122 Date of Preparation: 1/1/2005. MATERIAL SAFETY DATA SHEET SECTION 1. PRODUCT/MANUFACTURER'S IDENTITY PRODUCT NAME: OVEN & GRILL CLEANER PRODUCT I.D. NUMBER (PIN): 1719 PRODUCT NUMBER: 02806FS PRODUCT USE: Oven and grill cleaner WHMIS CLASS: 3 0 1 C DOT HAZARD CLASS: Corrosive Material COMPANY: Essential Industries, Inc. P.O. Box 12 Merton, WI 53056-0012 DOT SHIPPING NAME: Caustic Alkali Liquid, N.O.S. (Potassium hydroxide, Sodium metasilicate) 8, UN1719, PGIII 800-843-6174 EMERGENCY PHONE: H.M.I.S. E; D2B HEALTH HAZARD RATING FIRE 4 = Extreme 3 = High 2 = Moderate 1 = Slight 0 = Insignificant REACTIVITY MAXIMUM PERSONAL PROTECTION A = Goggles B = Goggles & Gloves C = Goggles, Gloves & Apron ABBREVIATION KEY: N.A. - Not Applicable N.E. = Not Established N.D. = Not Determined SECTION 2 - HAZARDOUS INGREDIENTS INFORMATION % 60-100 5-10 1-5 10-30 CAS NO. 7732-18-5 1310-58-3 6834-92-0 N.A. HAZARDOUS CHEMICAL IDENTITY Water Potassium hydroxide Sodium metasilicate Surfactants PEL N.E. 2mg/m3 2mg/m3 N.E. TLV N.E. 2mg/m3 2mg/m3 N.E. LD50 N.D. 365mg/kg 847mg/kg N.D. LC50 N.D. N.D. N.D. N.D. This mixture does not contain components which are subject to the reporting requiements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR, Part 372. SECTION 3 - PHYSICAL DATA Color: Boiling Point: Purple Odor: Bland Physical State: Liquid Solubility in Water: Complete 100°C (212°F) Freezing Point: 0°C (32°F) Water/Oil Distribution: N.E. Vapor Density (Air=1): <1 Evaporation Rate (Water=1): Odor Threshold: VOC Content: pH: 13.0 - 14.0 Vapor Pressure: <30 mm of Hg N.E. 1% pH: 11.8 N.E. 0.0% Specific Gravity: 1.10 gm/ml Weight per Gallon: 9.19 lbs./gal. SECTION 4 - FIRE AND EXPLOSION HAZARD DATA Flash Point and Method: N.A. Autoignition Temperature: N.A. Extinguishing Media: Flammable Limits: N.A. LEL: N.A. Special Fire Fighting Procedures: UEL: N.A. Hazardous Combustion Products: N.A. Use dry chemical or CO2. Use proper protective equipment. Unusual Fire and Explosion Hazards: None. SECTION 5 - REACTIVITY DATA Chemical Stability: Hazardous decomposition of By-Products: None known. Stable. Incompatibility (Materials to Avoid): Acids, aluminum and other soft metals. Hazardous Polymerization: Will not occur. SECTION 6 - TOXICOLOGICAL PROPERTIES Routes of Entry: Ingestion. Inhalation. Skin contact. Eye contact. Toxicologically Synergistic Products: No. Sensitization: None known. Medical Conditions Aggravated by Exposure: None known. EFFECTS OF OVEREXPOSURE (Acute and/or Chronic): Eyes: May cause severe irritation, redness, burns and possible corneal injury. Carcinogenic Effects: NO carcinogenic effect. Skin: May cause severe irritation, redness, burns. Mutagenic Effects: NO mutagenic effect. Ingestion: May cause severe irritation or burning of gastrointestinal tract and possible mucosal Teratogenic Effects: NO teratogenic effect. injury. Reproductive Toxicity: Inhalation: May irritate respiratory tract when used with inadequate ventilation. NO reproductive toxicity effect. SECTION 7 - PREVENTATIVE AND CONTROL MEASURES Respiratory Protection: None normally required with adequate ventilation. Protective Gloves: Rubber/Neoprene. Protective Clothing and Equipment: Full cover clothing - rubber apron. Storage Requirements: Store in cool, dry area. Follow good housekeeping practices. Steps to be Taken if Material is Spilled or Released: Waste Disposal: Ventilation: Local Exhaust: Acceptable Mechanical: Recommended Eye Protection: Chemical splash goggles. Work and Hygienic Practices: After handling, always wash hands thoroughly with soap and water. Other Requirements: Keep out of reach of children. Collect and reuse if possible. Dilute and flush to sewer with large quantities of water if permitted by regulatory authorities or absorb on inert material (sand, clay, etc.) and place into container for proper disposal. Do not allow runoff into public waterways. Dispose of as permitted by all federal, provincial, state and local regulatory authorities. SECTION 8 - EMERGENCY FIRST AID PROCEDURES FIRST AID - NOTES TO PHYSICIAN: Eyes: Flush with a large amount of water for 30 minutes holding eyelids open. Seek medical attention. Skin: Remove contaminated clothing and footwear. Flood/shower with water for 30 minutes. Ingestion: Rinse mouth with water. Give 2-3 large glasses of water. Do not induce vomiting. Seek medical attention. Inhalation:Remove to fresh air and rest. In all cases if symptoms persist, seek medical attention. Note to Physician: No additional information. SECTION 9 - PREPARATION INFORMATION Prepared By: Regulatory Affairs Department Phone: 262-538-1122 Date of Preparation: 1/1/2005. MATERIAL SAFETY DATA SHEET SECTION I - PRODUCT IDENTIFICATION AND USE Product Name Softsoap Liquid Hand Soap Supplier’s Name Colgate-Palmolive Canada Inc. Telephone No.: (416) 421-6000 Product Use Address: Liquid Hand Soap NCP Whmis Classification: Two Morneau Sobeco Centre, 6th Floor 895 Don Mills Road, Toronto, Ontario M3C 1W3 Check your local Poison Control Centre in your telephone white pages. Emergency Contacts: SECTION II - PREPARATION OF MSDS Technical Services PREPARED BY: N/A = Not Applicable; PHONE: (416) 421-6000 DATE: January 1, 2007 N/E = Not Established/Available SECTION III - HAZARDOUS INGREDIENTS Hazardous Ingredient Concentration Range % C.A.S. or U.N. Number Exposure Limits LD50/LC50 Specify Species and Route N/A SECTION IV - PHYSICAL DATA Physical State Liquid Odour and Appearance Various scents and colours Vapour Density N/E Evaporation Rate N/E Odour Threshold N/E Boiling Point N/E Freezing Point N/E Specific Gravity 1.07(20°/20° C) pH 6.0 - 6.5 Vapour Pressure N/E Coefficient of Water/Oil Distribution N/E SECTION V - FIRE OR EXPLOSION HAZARD Flammable: Yes ( ) No (X) If yes, under which conditions: If involved in fire, use water, dry alcohol type or all purpose foam, dry chemical, carbon dioxide or other Class B extinguishing agents. Means of Extinction: Flashpoint and Method N/E Upper Flammable Limit N/E Hazardous Combustion Products: Explosion Data Sensitivity To Mechanical Impact Lower Flammable Limit N/E Auto-ignition Temperature N/E Carbon Monoxide, Sulphur Dioxide, Oxides of Nitrogen N/E Explosion Data Sensitivity To Static Charge N/E SECTION VI - REACTIVITY DATA Chemical Instability: Yes ( ) No (X) If yes, under which conditions? Incompatibility To Other Substances: Yes ( ) No (X) If yes, which ones? Reactivity: Yes ( ) No (X) If yes, under which conditions? Hazardous Decomposition Products: None known SECTION VII - TOXICOLOGICAL PROPERTIES OF PRODUCT This product has not been tested as a whole. Routes of Entry: Skin Contact X Skin Absorption Eye Contact X Inhalation Effects of Acute Exposure To Product: Skin Contact: No evidence of dermal toxicity Skin Absorption N/A Eye Contact: Contact with eye can produce conjunctival irritation. Inhalation: N/A Ingestion: May cause vomiting with persistant, unpleasant aftertaste. Ingestion X MATERIAL SAFETY DATA SHEET Product Name Softsoap Liquid Hand Soap SECTION VII - TOXICOLOGICAL PROPERTIES OF PRODUCT This product has not been tested as a whole. Effects of Chronic Exposure To Product: N/E LD50 of Product (Specify Species and Route) N/E Exposure Limits N/E LC50 of Product (Specify Species) N/A Irritancy of Product N/E Sensitization of Product N/E Carcinogenicity N/E Teratogenicity N/E Mutagenicity N/E Synergistic Materials N/E Reproductive Toxicity N/E SECTION VIII - PREVENTATIVE MEASURES Personal Protective Equipment: Rubber or Plastic Gloves, Goggles or Safety Glasses, Protective Clothing Engineering Controls: Safety Showers and Eyewash Fountains should be available. The product should be used in a well ventilated area. Leak and Spill Procedures: Rinse with water Waste Disposal: Dispose in accordance with Federal, Provincial and Local regulations. Handling Procedures and Equipment: Follow routine safe handling procedures. Avoid contact when handling. Storage Requirements: Store in suitably labeled containers. Keep containers tightly closed. Protect from damage. Store in a cool, dry, well-ventilated area, out of direct sunlight. Special Shipping Instruction: None SECTION IX - TRANSPORTATION OF DANGEROUS GOODS TDG Regulated Product: PIN Number: Yes ( ) No N/A (X) Product TDG or CFR 49 Shipping Name (If CFR so indicate) Packaging Group N/A N/A SECTION X - FIRST AID MEASURES Skin: Flush the contact area well with lukewarm running water for at least 15 minutes. If irritation persists, call a physician. Eye: Flush the contaminated eye(s) for at least 15 minutes with lukewarm water, holding the eyelid open. Take care not to rinse contaminated water into the non-affected eye. Always seek medical attention for eye injuries. Inhalation: N/A Ingestion: If swallowed drink 3 - 4 glasses of water. DO NOT INDUCE VOMITING. Call a physician. This product is labeled in accordance with the requirements of the Hazardous Products Act and/or the Pest Control Products Act in that the use pattern and exposure in the workplace is generally consistent with that experienced by consumers. In certain respects, the requirements of the Workplace Hazardous Materials Information System applicable to the drafting of this Material Safety Data Sheet may differ from the requirements of those acts and regulations and as a result, this MSDS may contain additional information to that found on the label. Because we cannot anticipate or control the many different conditions under which this information and our products may be used, we do not guarantee the applicability of this information or the suitability of our products in any given situation. Users of our products should make their own tests to determine the safety and suitability of each such product for their particular purposes. U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET (Prepared According to 29 CFR 1910.1200) ______________________________________________________________________________ SECTION 1 IDENTIFICATION Product Name: Manufacturer's Name: Manufacturer's Address: Manufacturer's Phone Number: Emergency Phone Number: Proper Shipping Name: Effective Date: FORMULA 491705 MANGO ZENEX International 7777 First Place, Cleveland Ohio 44146 (440) 232-4155 1-800-535-5053 Consumer Commodity, ORM-D 10-15-01 ______________________________________________________________________________ SECTION 2 IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS Chemical Name: Acetone Propane Isobutane n-Butane Fragrance CAS No.: 67-64-1 74-98-6 75-28-5 106-97-8 Not available TLV: 500ppm 2500ppm Not established 800ppm Not available ______________________________________________________________________________ SECTION 3 Boiling Point: Solubility in Water: Physical Description: PHYSICAL DATA <0 to 1330 F Slightly Clear/mango scent Specific Gravity(H2O=1): Evaporation Rate: Vapor Density(Air=1): 0.80 + 0.05 Slower than Ether Heavier than air _______________________________________________________________________________________________________________________________________ SECTION 4 FIRE AND EXPLOSION HAZARD DATA Flash Point: Flammable Limits: Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: <0OF LEL: 1.8 UEL: 9.5 Use water fog, dry chemical or carbon dioxide. Aerosol cans may rupture when heated. Heated cans may burst. _______________________________________________________________________________________________________________________________________ SECTION 5 Unstable______ Stable __X___ Incompatability (Materials to Avoid): Conditions to Avoid: Hazardous Decomposition or Byproducts: Hazardous Polymerization: REACTIVITY DATA Stability: None known. High temperatures. In fire, will decompose to carbon dioxide, carbon monoxide Will not occur __________________________________________________________________________________________________________________________________________ SECTION 6 STORAGE AND HANDLING INFORMATION Precautions to be Taken in Handling and Storing: When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved respirator. STORE AT TEMPERATURES BELOW 120oF KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME KEEP AWAY FROM CHILDREN FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY FOR USE BY TRAINED PERSONNEL ONLY KEEP CONTAINER CLOSED DURING STORAGE __________________________________________________________________________________________________________________________________________ SECTION 7 HEALTH HAZARDS AND FIRST AID Effects of Overexposure: SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible. EYES: Eye irritant. Will cause redness and burning sensation. INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness, nausea, and loss of coordination.Extreme overexposure may result in unconsciousness and possibly death. INGESTION: Aspiration hazard if swallowed. First Aid Procedures: SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get medical attention. Remove contaminated clothing and launder before reuse. EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Seek medical attention. INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention. INGESTION: DO NOT induce vomiting. Seek medical attention immediately. Note: Never give anything by mouth to an unconscious or convulsing victim. Keep person warm and quiet. __________________________________________________________________________________________________________________________________________ SECTION 8 SPECIAL PROTECTION INFORMATION Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: Self-contained breathing apparatus if above TLV limit. Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit. None required if spraying. As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we recommend the use of safety glasses or chemical splash goggles. Other Protective Equipment: Long sleeves and long pants. Work/Hygienic Practices: Do not smoke while using. Wash hands after use. __________________________________________________________________________________________________________________________________________ SECTION 9 SPILL OR LEAK PROCEDURE Steps To Be Taken In Case Material Is Released or Spilled: Use absorbent sweeping compound to soak up material. Put into container. Dispose as hazardous waste. Waste Disposal Method: Dispose as hazardous waste in accordance with EPA RCRA. _________________________________________________________________________________________________________________________________________ SECTION 10 REGULATORY INFORMATION SARA Title III, Section 313 Components: None __________________________________________________________________________________________________________________________________________ This information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties, express or implied, and assume no liability in connection with any use of this information. 491705 U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET (Prepared According to 29 CFR 1910.1200) ______________________________________________________________________________ SECTION 1 IDENTIFICATION Product Name: Manufacturer's Name: Manufacturer's Address: Manufacturer's Phone Number: Emergency Phone Number: Proper Shipping Name: Effective Date: FORMULA 491655 TROPICAL NECTAR ZENEX International 7777 First Place, Cleveland Ohio 44146 (440) 232-4155 1-800-535-5053 Consumer Commodity, ORM-D 10-15-01 ______________________________________________________________________________ SECTION 2 IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS Chemical Name: Acetone Propane Isobutane n-Butane Fragrance CAS No.: 67-64-1 74-98-6 75-28-5 106-97-8 Not available TLV: 500ppm 2500ppm Not established 800ppm Not available ______________________________________________________________________________ SECTION 3 Boiling Point: Solubility in Water: Physical Description: PHYSICAL DATA <0 to 1330 F Slightly Clear/tropical scent Specific Gravity(H2O=1): Evaporation Rate: Vapor Density(Air=1): 0.80 + 0.05 Slower than Ether Heavier than air _______________________________________________________________________________________________________________________________________ SECTION 4 FIRE AND EXPLOSION HAZARD DATA Flash Point: Flammable Limits: Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: <0OF LEL: 1.8 UEL: 9.5 Use water fog, dry chemical or carbon dioxide. Aerosol cans may rupture when heated. Heated cans may burst. _______________________________________________________________________________________________________________________________________ SECTION 5 Unstable______ Stable __X___ Incompatability (Materials to Avoid): Conditions to Avoid: Hazardous Decomposition or Byproducts: Hazardous Polymerization: REACTIVITY DATA Stability: None known. High temperatures. In fire, will decompose to carbon dioxide, carbon monoxide Will not occur __________________________________________________________________________________________________________________________________________ SECTION 6 STORAGE AND HANDLING INFORMATION Precautions to be Taken in Handling and Storing: When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved respirator. STORE AT TEMPERATURES BELOW 120oF KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME KEEP AWAY FROM CHILDREN FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY FOR USE BY TRAINED PERSONNEL ONLY KEEP CONTAINER CLOSED DURING STORAGE __________________________________________________________________________________________________________________________________________ SECTION 7 HEALTH HAZARDS AND FIRST AID Effects of Overexposure: SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible. EYES: Eye irritant. Will cause redness and burning sensation. INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness, nausea, and loss of coordination.Extreme overexposure may result in unconsciousness and possibly death. INGESTION: Aspiration hazard if swallowed. First Aid Procedures: SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get medical attention. Remove contaminated clothing and launder before reuse. EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Seek medical attention. INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention. INGESTION: DO NOT induce vomiting. Seek medical attention immediately. Note: Never give anything by mouth to an unconscious or convulsing victim. Keep person warm and quiet. __________________________________________________________________________________________________________________________________________ SECTION 8 SPECIAL PROTECTION INFORMATION Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: Self-contained breathing apparatus if above TLV limit. Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit. None required if spraying. As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we recommend the use of safety glasses or chemical splash goggles. Other Protective Equipment: Long sleeves and long pants. Work/Hygienic Practices: Do not smoke while using. Wash hands after use. __________________________________________________________________________________________________________________________________________ SECTION 9 SPILL OR LEAK PROCEDURE Steps To Be Taken In Case Material Is Released or Spilled: Use absorbent sweeping compound to soak up material. Put into container. Dispose as hazardous waste. Waste Disposal Method: Dispose as hazardous waste in accordance with EPA RCRA. _________________________________________________________________________________________________________________________________________ SECTION 10 REGULATORY INFORMATION SARA Title III, Section 313 Components: None __________________________________________________________________________________________________________________________________________ This information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties, express or implied, and assume no liability in connection with any use of this information. 491655 U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET (Prepared According to 29 CFR 1910.1200) ______________________________________________________________________________ SECTION 1 IDENTIFICATION Product Name: Manufacturer's Name: Manufacturer's Address: Manufacturer's Phone Number: Emergency Phone Number: Proper Shipping Name: Effective Date: FORMULA 491805 PEACH KIWI ZENEX International 7777 First Place, Cleveland Ohio 44146 (440) 232-4155 1-800-535-5053 Consumer Commodity, ORM-D 10-15-01 ______________________________________________________________________________ SECTION 2 IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS Chemical Name: Acetone Propane Isobutane n-Butane Fragrance CAS No.: 67-64-1 74-98-6 75-28-5 106-97-8 Not available TLV: 500ppm 2500ppm Not established 800ppm Not available ______________________________________________________________________________ SECTION 3 Boiling Point: Solubility in Water: Physical Description: PHYSICAL DATA <0 to 1330 F Slightly Clear/peach kiwi scent Specific Gravity(H2O=1): Evaporation Rate: Vapor Density(Air=1): 0.80 + 0.05 Slower than Ether Heavier than air _______________________________________________________________________________________________________________________________________ SECTION 4 FIRE AND EXPLOSION HAZARD DATA Flash Point: Flammable Limits: Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: <0OF LEL: 1.8 UEL: 9.5 Use water fog, dry chemical or carbon dioxide. Aerosol cans may rupture when heated. Heated cans may burst. _______________________________________________________________________________________________________________________________________ SECTION 5 Unstable______ Stable __X___ Incompatability (Materials to Avoid): Conditions to Avoid: Hazardous Decomposition or Byproducts: Hazardous Polymerization: REACTIVITY DATA Stability: None known. High temperatures. In fire, will decompose to carbon dioxide, carbon monoxide Will not occur __________________________________________________________________________________________________________________________________________ SECTION 6 STORAGE AND HANDLING INFORMATION Precautions to be Taken in Handling and Storing: When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved respirator. STORE AT TEMPERATURES BELOW 120oF KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME KEEP AWAY FROM CHILDREN FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY FOR USE BY TRAINED PERSONNEL ONLY KEEP CONTAINER CLOSED DURING STORAGE __________________________________________________________________________________________________________________________________________ SECTION 7 HEALTH HAZARDS AND FIRST AID Effects of Overexposure: SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible. EYES: Eye irritant. Will cause redness and burning sensation. INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness, nausea, and loss of coordination.Extreme overexposure may result in unconsciousness and possibly death. INGESTION: Aspiration hazard if swallowed. First Aid Procedures: SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get medical attention. Remove contaminated clothing and launder before reuse. EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Seek medical attention. INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention. INGESTION: DO NOT induce vomiting. Seek medical attention immediately. Note: Never give anything by mouth to an unconscious or convulsing victim. Keep person warm and quiet. __________________________________________________________________________________________________________________________________________ SECTION 8 SPECIAL PROTECTION INFORMATION Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: Self-contained breathing apparatus if above TLV limit. Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit. None required if spraying. As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we recommend the use of safety glasses or chemical splash goggles. Other Protective Equipment: Long sleeves and long pants. Work/Hygienic Practices: Do not smoke while using. Wash hands after use. __________________________________________________________________________________________________________________________________________ SECTION 9 SPILL OR LEAK PROCEDURE Steps To Be Taken In Case Material Is Released or Spilled: Use absorbent sweeping compound to soak up material. Put into container. Dispose as hazardous waste. Waste Disposal Method: Dispose as hazardous waste in accordance with EPA RCRA. _________________________________________________________________________________________________________________________________________ SECTION 10 REGULATORY INFORMATION SARA Title III, Section 313 Components: None __________________________________________________________________________________________________________________________________________ This information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties, express or implied, and assume no liability in connection with any use of this information. 491805 U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET (Prepared According to 29 CFR 1910.1200) ______________________________________________________________________________ SECTION 1 IDENTIFICATION Product Name: NEUTRAZEN Natural Scents 491153 Cinnamon 491105 Citrus Creme 491325 Citrus Peel 491235 Cranberry Spice 491123 Fresh Linen Manufacturer's Name: Manufacturer's Address: Manufacturer's Phone Number: Emergency Phone Number: Proper Shipping Name: Effective Date: (Hand Held Cans) 491075 Fruit Basket 491255 Green Apple 491455 Mango 491155 Orchard Spice 491405 Peach Kiwi 491355 Pina Colada 491305 Powder Fresh 491055 Tropical Nectar 491205 Vanilla Delight ZENEX International 7777 First Place, Cleveland Ohio 44146 (440) 232-4155 1-800-535-5053 Consumer Commodity, ORM-D 10-15-01 ______________________________________________________________________________ SECTION 2 IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS Chemical Name: Dimethyl Ketal Isobutane Propane Butane Fragrance CAS No.: 67-64-1 75-28-5 74-98-6 106-97-8 Not available TLV: 500ppm Not established 2500ppm 800ppm Not available ______________________________________________________________________________ SECTION 3 Boiling Point: Solubility in Water: Physical Description: PHYSICAL DATA <0 to 1330 F Slightly Clear Specific Gravity(H2O=1): Evaporation Rate: Vapor Density(Air=1): 0.80 + 0.05 Slower than Ether Heavier than air _______________________________________________________________________________________________________________________________________ SECTION 4 FIRE AND EXPLOSION HAZARD DATA Flash Point: Flammable Limits: Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: <0OF LEL: 1.8 UEL: 9.5 Use water fog, dry chemical or carbon dioxide. Aerosol cans may rupture when heated. Heated cans may burst. _______________________________________________________________________________________________________________________________________ SECTION 5 Unstable______ Stable __X___ Incompatability (Materials to Avoid): Conditions to Avoid: Hazardous Decomposition or Byproducts: Hazardous Polymerization: REACTIVITY DATA Stability: None known. High temperatures. In fire, will decompose to carbon dioxide, carbon monoxide Will not occur __________________________________________________________________________________________________________________________________________ SECTION 6 STORAGE AND HANDLING INFORMATION Precautions to be Taken in Handling and Storing: When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved respirator. STORE AT TEMPERATURES BELOW 120oF KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME KEEP AWAY FROM CHILDREN FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY FOR USE BY TRAINED PERSONNEL ONLY KEEP CONTAINER CLOSED DURING STORAGE __________________________________________________________________________________________________________________________________________ SECTION 7 HEALTH HAZARDS AND FIRST AID Effects of Overexposure: SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible. EYES: Eye irritant. Will cause redness and burning sensation. INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness, nausea, and loss of coordination.Extreme overexposure may result in unconsciousness and possibly death. INGESTION: Aspiration hazard if swallowed. First Aid Procedures: SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get medical attention. Remove contaminated clothing and launder before reuse. EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Seek medical attention. INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention. INGESTION: DO NOT induce vomiting. Seek medical attention immediately. Note: Never give anything by mouth to an unconscious or convulsing victim. Keep person warm and quiet. __________________________________________________________________________________________________________________________________________ SECTION 8 SPECIAL PROTECTION INFORMATION SECTION 9 SPILL OR LEAK PROCEDURE Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: Self-contained breathing apparatus if above TLV limit. Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit. None required if spraying. As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we recommend the use of safety glasses or chemical splash goggles. Other Protective Equipment: Long sleeves and long pants. Work/Hygienic Practices: Do not smoke while using. Wash hands after use. __________________________________________________________________________________________________________________________________________ Steps To Be Taken In Case Material Is Released or Spilled: Use absorbent sweeping compound to soak up material. Put into container. Dispose as hazardous waste. Waste Disposal Method: Dispose as hazardous waste in accordance with EPA RCRA. _________________________________________________________________________________________________________________________________________ SECTION 10 REGULATORY INFORMATION SARA Title III, Section 313 Components: None __________________________________________________________________________________________________________________________________________ This information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties, express or implied, and assume no liability in connection with any use of this information. 491153,491105,491325,491235,491123,491075,491255,491455,491155,491405,491355,491305,491055, 491205 U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET (Prepared According to 29 CFR 1910.1200) ______________________________________________________________________________ SECTION 1 IDENTIFICATION Product Name: NEUTRAZEN Natural Scents 491153 Cinnamon 491105 Citrus Creme 491325 Citrus Peel 491235 Cranberry Spice 491123 Fresh Linen Manufacturer's Name: Manufacturer's Address: Manufacturer's Phone Number: Emergency Phone Number: Proper Shipping Name: Effective Date: (Hand Held Cans) 491075 Fruit Basket 491255 Green Apple 491455 Mango 491155 Orchard Spice 491405 Peach Kiwi 491355 Pina Colada 491305 Powder Fresh 491055 Tropical Nectar 491205 Vanilla Delight ZENEX International 7777 First Place, Cleveland Ohio 44146 (440) 232-4155 1-800-535-5053 Consumer Commodity, ORM-D 10-15-01 ______________________________________________________________________________ SECTION 2 IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS Chemical Name: Dimethyl Ketal Isobutane Propane Butane Fragrance CAS No.: 67-64-1 75-28-5 74-98-6 106-97-8 Not available TLV: 500ppm Not established 2500ppm 800ppm Not available ______________________________________________________________________________ SECTION 3 Boiling Point: Solubility in Water: Physical Description: PHYSICAL DATA <0 to 1330 F Slightly Clear Specific Gravity(H2O=1): Evaporation Rate: Vapor Density(Air=1): 0.80 + 0.05 Slower than Ether Heavier than air _______________________________________________________________________________________________________________________________________ SECTION 4 FIRE AND EXPLOSION HAZARD DATA Flash Point: Flammable Limits: Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: <0OF LEL: 1.8 UEL: 9.5 Use water fog, dry chemical or carbon dioxide. Aerosol cans may rupture when heated. Heated cans may burst. _______________________________________________________________________________________________________________________________________ SECTION 5 Unstable______ Stable __X___ Incompatability (Materials to Avoid): Conditions to Avoid: Hazardous Decomposition or Byproducts: Hazardous Polymerization: REACTIVITY DATA Stability: None known. High temperatures. In fire, will decompose to carbon dioxide, carbon monoxide Will not occur __________________________________________________________________________________________________________________________________________ SECTION 6 STORAGE AND HANDLING INFORMATION Precautions to be Taken in Handling and Storing: When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved respirator. STORE AT TEMPERATURES BELOW 120oF KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME KEEP AWAY FROM CHILDREN FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY FOR USE BY TRAINED PERSONNEL ONLY KEEP CONTAINER CLOSED DURING STORAGE __________________________________________________________________________________________________________________________________________ SECTION 7 HEALTH HAZARDS AND FIRST AID Effects of Overexposure: SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible. EYES: Eye irritant. Will cause redness and burning sensation. INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness, nausea, and loss of coordination.Extreme overexposure may result in unconsciousness and possibly death. INGESTION: Aspiration hazard if swallowed. First Aid Procedures: SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get medical attention. Remove contaminated clothing and launder before reuse. EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Seek medical attention. INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention. INGESTION: DO NOT induce vomiting. Seek medical attention immediately. Note: Never give anything by mouth to an unconscious or convulsing victim. Keep person warm and quiet. __________________________________________________________________________________________________________________________________________ SECTION 8 SPECIAL PROTECTION INFORMATION SECTION 9 SPILL OR LEAK PROCEDURE Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: Self-contained breathing apparatus if above TLV limit. Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit. None required if spraying. As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we recommend the use of safety glasses or chemical splash goggles. Other Protective Equipment: Long sleeves and long pants. Work/Hygienic Practices: Do not smoke while using. Wash hands after use. __________________________________________________________________________________________________________________________________________ Steps To Be Taken In Case Material Is Released or Spilled: Use absorbent sweeping compound to soak up material. Put into container. Dispose as hazardous waste. Waste Disposal Method: Dispose as hazardous waste in accordance with EPA RCRA. _________________________________________________________________________________________________________________________________________ SECTION 10 REGULATORY INFORMATION SARA Title III, Section 313 Components: None __________________________________________________________________________________________________________________________________________ This information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties, express or implied, and assume no liability in connection with any use of this information. 491153,491105,491325,491235,491123,491075,491255,491455,491155,491405,491355,491305,491055, 491205 U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET (Prepared According to 29 CFR 1910.1200) ______________________________________________________________________________ SECTION 1 IDENTIFICATION Product Name: NEUTRAZEN Natural Scents 491153 Cinnamon 491105 Citrus Creme 491325 Citrus Peel 491235 Cranberry Spice 491123 Fresh Linen Manufacturer's Name: Manufacturer's Address: Manufacturer's Phone Number: Emergency Phone Number: Proper Shipping Name: Effective Date: (Hand Held Cans) 491075 Fruit Basket 491255 Green Apple 491455 Mango 491155 Orchard Spice 491405 Peach Kiwi 491355 Pina Colada 491305 Powder Fresh 491055 Tropical Nectar 491205 Vanilla Delight ZENEX International 7777 First Place, Cleveland Ohio 44146 (440) 232-4155 1-800-535-5053 Consumer Commodity, ORM-D 10-15-01 ______________________________________________________________________________ SECTION 2 IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS Chemical Name: Dimethyl Ketal Isobutane Propane Butane Fragrance CAS No.: 67-64-1 75-28-5 74-98-6 106-97-8 Not available TLV: 500ppm Not established 2500ppm 800ppm Not available ______________________________________________________________________________ SECTION 3 Boiling Point: Solubility in Water: Physical Description: PHYSICAL DATA <0 to 1330 F Slightly Clear Specific Gravity(H2O=1): Evaporation Rate: Vapor Density(Air=1): 0.80 + 0.05 Slower than Ether Heavier than air _______________________________________________________________________________________________________________________________________ SECTION 4 FIRE AND EXPLOSION HAZARD DATA Flash Point: Flammable Limits: Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: <0OF LEL: 1.8 UEL: 9.5 Use water fog, dry chemical or carbon dioxide. Aerosol cans may rupture when heated. Heated cans may burst. _______________________________________________________________________________________________________________________________________ SECTION 5 Unstable______ Stable __X___ Incompatability (Materials to Avoid): Conditions to Avoid: Hazardous Decomposition or Byproducts: Hazardous Polymerization: REACTIVITY DATA Stability: None known. High temperatures. In fire, will decompose to carbon dioxide, carbon monoxide Will not occur __________________________________________________________________________________________________________________________________________ SECTION 6 STORAGE AND HANDLING INFORMATION Precautions to be Taken in Handling and Storing: When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved respirator. STORE AT TEMPERATURES BELOW 120oF KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME KEEP AWAY FROM CHILDREN FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY FOR USE BY TRAINED PERSONNEL ONLY KEEP CONTAINER CLOSED DURING STORAGE __________________________________________________________________________________________________________________________________________ SECTION 7 HEALTH HAZARDS AND FIRST AID Effects of Overexposure: SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible. EYES: Eye irritant. Will cause redness and burning sensation. INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness, nausea, and loss of coordination.Extreme overexposure may result in unconsciousness and possibly death. INGESTION: Aspiration hazard if swallowed. First Aid Procedures: SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get medical attention. Remove contaminated clothing and launder before reuse. EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Seek medical attention. INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention. INGESTION: DO NOT induce vomiting. Seek medical attention immediately. Note: Never give anything by mouth to an unconscious or convulsing victim. Keep person warm and quiet. __________________________________________________________________________________________________________________________________________ SECTION 8 SPECIAL PROTECTION INFORMATION SECTION 9 SPILL OR LEAK PROCEDURE Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: Self-contained breathing apparatus if above TLV limit. Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit. None required if spraying. As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we recommend the use of safety glasses or chemical splash goggles. Other Protective Equipment: Long sleeves and long pants. Work/Hygienic Practices: Do not smoke while using. Wash hands after use. __________________________________________________________________________________________________________________________________________ Steps To Be Taken In Case Material Is Released or Spilled: Use absorbent sweeping compound to soak up material. Put into container. Dispose as hazardous waste. Waste Disposal Method: Dispose as hazardous waste in accordance with EPA RCRA. _________________________________________________________________________________________________________________________________________ SECTION 10 REGULATORY INFORMATION SARA Title III, Section 313 Components: None __________________________________________________________________________________________________________________________________________ This information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties, express or implied, and assume no liability in connection with any use of this information. 491153,491105,491325,491235,491123,491075,491255,491455,491155,491405,491355,491305,491055, 491205 U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET (Prepared According to 29 CFR 1910.1200) ______________________________________________________________________________ SECTION 1 IDENTIFICATION Product Name: NEUTRAZEN Natural Scents 491153 Cinnamon 491105 Citrus Creme 491325 Citrus Peel 491235 Cranberry Spice 491123 Fresh Linen Manufacturer's Name: Manufacturer's Address: Manufacturer's Phone Number: Emergency Phone Number: Proper Shipping Name: Effective Date: (Hand Held Cans) 491075 Fruit Basket 491255 Green Apple 491455 Mango 491155 Orchard Spice 491405 Peach Kiwi 491355 Pina Colada 491305 Powder Fresh 491055 Tropical Nectar 491205 Vanilla Delight ZENEX International 7777 First Place, Cleveland Ohio 44146 (440) 232-4155 1-800-535-5053 Consumer Commodity, ORM-D 10-15-01 ______________________________________________________________________________ SECTION 2 IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS Chemical Name: Dimethyl Ketal Isobutane Propane Butane Fragrance CAS No.: 67-64-1 75-28-5 74-98-6 106-97-8 Not available TLV: 500ppm Not established 2500ppm 800ppm Not available ______________________________________________________________________________ SECTION 3 Boiling Point: Solubility in Water: Physical Description: PHYSICAL DATA <0 to 1330 F Slightly Clear Specific Gravity(H2O=1): Evaporation Rate: Vapor Density(Air=1): 0.80 + 0.05 Slower than Ether Heavier than air _______________________________________________________________________________________________________________________________________ SECTION 4 FIRE AND EXPLOSION HAZARD DATA Flash Point: Flammable Limits: Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: <0OF LEL: 1.8 UEL: 9.5 Use water fog, dry chemical or carbon dioxide. Aerosol cans may rupture when heated. Heated cans may burst. _______________________________________________________________________________________________________________________________________ SECTION 5 Unstable______ Stable __X___ Incompatability (Materials to Avoid): Conditions to Avoid: Hazardous Decomposition or Byproducts: Hazardous Polymerization: REACTIVITY DATA Stability: None known. High temperatures. In fire, will decompose to carbon dioxide, carbon monoxide Will not occur __________________________________________________________________________________________________________________________________________ SECTION 6 STORAGE AND HANDLING INFORMATION Precautions to be Taken in Handling and Storing: When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved respirator. STORE AT TEMPERATURES BELOW 120oF KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME KEEP AWAY FROM CHILDREN FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY FOR USE BY TRAINED PERSONNEL ONLY KEEP CONTAINER CLOSED DURING STORAGE __________________________________________________________________________________________________________________________________________ SECTION 7 HEALTH HAZARDS AND FIRST AID Effects of Overexposure: SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible. EYES: Eye irritant. Will cause redness and burning sensation. INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness, nausea, and loss of coordination.Extreme overexposure may result in unconsciousness and possibly death. INGESTION: Aspiration hazard if swallowed. First Aid Procedures: SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get medical attention. Remove contaminated clothing and launder before reuse. EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Seek medical attention. INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention. INGESTION: DO NOT induce vomiting. Seek medical attention immediately. Note: Never give anything by mouth to an unconscious or convulsing victim. Keep person warm and quiet. __________________________________________________________________________________________________________________________________________ SECTION 8 SPECIAL PROTECTION INFORMATION SECTION 9 SPILL OR LEAK PROCEDURE Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: Self-contained breathing apparatus if above TLV limit. Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit. None required if spraying. As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we recommend the use of safety glasses or chemical splash goggles. Other Protective Equipment: Long sleeves and long pants. Work/Hygienic Practices: Do not smoke while using. Wash hands after use. __________________________________________________________________________________________________________________________________________ Steps To Be Taken In Case Material Is Released or Spilled: Use absorbent sweeping compound to soak up material. Put into container. Dispose as hazardous waste. Waste Disposal Method: Dispose as hazardous waste in accordance with EPA RCRA. _________________________________________________________________________________________________________________________________________ SECTION 10 REGULATORY INFORMATION SARA Title III, Section 313 Components: None __________________________________________________________________________________________________________________________________________ This information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties, express or implied, and assume no liability in connection with any use of this information. 491153,491105,491325,491235,491123,491075,491255,491455,491155,491405,491355,491305,491055, 491205 U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET (Prepared According to 29 CFR 1910.1200) ______________________________________________________________________________ SECTION 1 IDENTIFICATION Product Name: NEUTRAZEN Natural Scents 491153 Cinnamon 491105 Citrus Creme 491325 Citrus Peel 491235 Cranberry Spice 491123 Fresh Linen Manufacturer's Name: Manufacturer's Address: Manufacturer's Phone Number: Emergency Phone Number: Proper Shipping Name: Effective Date: (Hand Held Cans) 491075 Fruit Basket 491255 Green Apple 491455 Mango 491155 Orchard Spice 491405 Peach Kiwi 491355 Pina Colada 491305 Powder Fresh 491055 Tropical Nectar 491205 Vanilla Delight ZENEX International 7777 First Place, Cleveland Ohio 44146 (440) 232-4155 1-800-535-5053 Consumer Commodity, ORM-D 10-15-01 ______________________________________________________________________________ SECTION 2 IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS Chemical Name: Dimethyl Ketal Isobutane Propane Butane Fragrance CAS No.: 67-64-1 75-28-5 74-98-6 106-97-8 Not available TLV: 500ppm Not established 2500ppm 800ppm Not available ______________________________________________________________________________ SECTION 3 Boiling Point: Solubility in Water: Physical Description: PHYSICAL DATA <0 to 1330 F Slightly Clear Specific Gravity(H2O=1): Evaporation Rate: Vapor Density(Air=1): 0.80 + 0.05 Slower than Ether Heavier than air _______________________________________________________________________________________________________________________________________ SECTION 4 FIRE AND EXPLOSION HAZARD DATA Flash Point: Flammable Limits: Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: <0OF LEL: 1.8 UEL: 9.5 Use water fog, dry chemical or carbon dioxide. Aerosol cans may rupture when heated. Heated cans may burst. _______________________________________________________________________________________________________________________________________ SECTION 5 Unstable______ Stable __X___ Incompatability (Materials to Avoid): Conditions to Avoid: Hazardous Decomposition or Byproducts: Hazardous Polymerization: REACTIVITY DATA Stability: None known. High temperatures. In fire, will decompose to carbon dioxide, carbon monoxide Will not occur __________________________________________________________________________________________________________________________________________ SECTION 6 STORAGE AND HANDLING INFORMATION Precautions to be Taken in Handling and Storing: When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved respirator. STORE AT TEMPERATURES BELOW 120oF KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME KEEP AWAY FROM CHILDREN FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY FOR USE BY TRAINED PERSONNEL ONLY KEEP CONTAINER CLOSED DURING STORAGE __________________________________________________________________________________________________________________________________________ SECTION 7 HEALTH HAZARDS AND FIRST AID Effects of Overexposure: SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible. EYES: Eye irritant. Will cause redness and burning sensation. INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness, nausea, and loss of coordination.Extreme overexposure may result in unconsciousness and possibly death. INGESTION: Aspiration hazard if swallowed. First Aid Procedures: SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get medical attention. Remove contaminated clothing and launder before reuse. EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Seek medical attention. INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention. INGESTION: DO NOT induce vomiting. Seek medical attention immediately. Note: Never give anything by mouth to an unconscious or convulsing victim. Keep person warm and quiet. __________________________________________________________________________________________________________________________________________ SECTION 8 SPECIAL PROTECTION INFORMATION SECTION 9 SPILL OR LEAK PROCEDURE Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: Self-contained breathing apparatus if above TLV limit. Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit. None required if spraying. As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we recommend the use of safety glasses or chemical splash goggles. Other Protective Equipment: Long sleeves and long pants. Work/Hygienic Practices: Do not smoke while using. Wash hands after use. __________________________________________________________________________________________________________________________________________ Steps To Be Taken In Case Material Is Released or Spilled: Use absorbent sweeping compound to soak up material. Put into container. Dispose as hazardous waste. Waste Disposal Method: Dispose as hazardous waste in accordance with EPA RCRA. _________________________________________________________________________________________________________________________________________ SECTION 10 REGULATORY INFORMATION SARA Title III, Section 313 Components: None __________________________________________________________________________________________________________________________________________ This information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties, express or implied, and assume no liability in connection with any use of this information. 491153,491105,491325,491235,491123,491075,491255,491455,491155,491405,491355,491305,491055, 491205 U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET (Prepared According to 29 CFR 1910.1200) ______________________________________________________________________________ SECTION 1 IDENTIFICATION Product Name: NEUTRAZEN Natural Scents 491153 Cinnamon 491105 Citrus Creme 491325 Citrus Peel 491235 Cranberry Spice 491123 Fresh Linen Manufacturer's Name: Manufacturer's Address: Manufacturer's Phone Number: Emergency Phone Number: Proper Shipping Name: Effective Date: (Hand Held Cans) 491075 Fruit Basket 491255 Green Apple 491455 Mango 491155 Orchard Spice 491405 Peach Kiwi 491355 Pina Colada 491305 Powder Fresh 491055 Tropical Nectar 491205 Vanilla Delight ZENEX International 7777 First Place, Cleveland Ohio 44146 (440) 232-4155 1-800-535-5053 Consumer Commodity, ORM-D 10-15-01 ______________________________________________________________________________ SECTION 2 IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS Chemical Name: Dimethyl Ketal Isobutane Propane Butane Fragrance CAS No.: 67-64-1 75-28-5 74-98-6 106-97-8 Not available TLV: 500ppm Not established 2500ppm 800ppm Not available ______________________________________________________________________________ SECTION 3 Boiling Point: Solubility in Water: Physical Description: PHYSICAL DATA <0 to 1330 F Slightly Clear Specific Gravity(H2O=1): Evaporation Rate: Vapor Density(Air=1): 0.80 + 0.05 Slower than Ether Heavier than air _______________________________________________________________________________________________________________________________________ SECTION 4 FIRE AND EXPLOSION HAZARD DATA Flash Point: Flammable Limits: Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: <0OF LEL: 1.8 UEL: 9.5 Use water fog, dry chemical or carbon dioxide. Aerosol cans may rupture when heated. Heated cans may burst. _______________________________________________________________________________________________________________________________________ SECTION 5 Unstable______ Stable __X___ Incompatability (Materials to Avoid): Conditions to Avoid: Hazardous Decomposition or Byproducts: Hazardous Polymerization: REACTIVITY DATA Stability: None known. High temperatures. In fire, will decompose to carbon dioxide, carbon monoxide Will not occur __________________________________________________________________________________________________________________________________________ SECTION 6 STORAGE AND HANDLING INFORMATION Precautions to be Taken in Handling and Storing: When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved respirator. STORE AT TEMPERATURES BELOW 120oF KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME KEEP AWAY FROM CHILDREN FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY FOR USE BY TRAINED PERSONNEL ONLY KEEP CONTAINER CLOSED DURING STORAGE __________________________________________________________________________________________________________________________________________ SECTION 7 HEALTH HAZARDS AND FIRST AID Effects of Overexposure: SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible. EYES: Eye irritant. Will cause redness and burning sensation. INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness, nausea, and loss of coordination.Extreme overexposure may result in unconsciousness and possibly death. INGESTION: Aspiration hazard if swallowed. First Aid Procedures: SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get medical attention. Remove contaminated clothing and launder before reuse. EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Seek medical attention. INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention. INGESTION: DO NOT induce vomiting. Seek medical attention immediately. Note: Never give anything by mouth to an unconscious or convulsing victim. Keep person warm and quiet. __________________________________________________________________________________________________________________________________________ SECTION 8 SPECIAL PROTECTION INFORMATION SECTION 9 SPILL OR LEAK PROCEDURE Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: Self-contained breathing apparatus if above TLV limit. Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit. None required if spraying. As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we recommend the use of safety glasses or chemical splash goggles. Other Protective Equipment: Long sleeves and long pants. Work/Hygienic Practices: Do not smoke while using. Wash hands after use. __________________________________________________________________________________________________________________________________________ Steps To Be Taken In Case Material Is Released or Spilled: Use absorbent sweeping compound to soak up material. Put into container. Dispose as hazardous waste. Waste Disposal Method: Dispose as hazardous waste in accordance with EPA RCRA. _________________________________________________________________________________________________________________________________________ SECTION 10 REGULATORY INFORMATION SARA Title III, Section 313 Components: None __________________________________________________________________________________________________________________________________________ This information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties, express or implied, and assume no liability in connection with any use of this information. 491153,491105,491325,491235,491123,491075,491255,491455,491155,491405,491355,491305,491055, 491205 NFPA Hazard Rating Flammability 0 0 Health MATERIAL SAFETY DATA SHEET L-82E 0 Reactivity 0 = Minimum 1 = Light 2 = Moderate 3 = Serious 4 = Extreme Section 1 - Product Identification Bio-Chem Surface Technology Trade name: Gold Matrix All Purpose 5977 Transcanada Highway Pointe-Claire, Quebec H9R 1C1 Emergency: CANUTEC (613) 996-6666 Product name: Order no.: WHMIS Classification: Controlled under WHMIS: Industrial cleaner/degreaser 53-G 603, 53-G 607, 53-G608 Non-hazardous No Section 2 - Hazardous Ingredients Ingredients CAS Number % by Weight LD50RAT LC50RAT No hazardous substances to declare. Section 3 - Physical / Chemical Characteristics Physical state: pH: Specific gravity: Evaporation rate: Liquid 12 1.00 g/ml @ 20ºC N/Av Odour & appearance:Lavender, blue Boiling point: 98ºC Vapour pressure: N/Av VOC g/l: N/Av Odour threshold: None Freezing point: 0ºC Vapour density: N/Av Water solubility: Soluble Section 4 - Fire & Explosion Hazard Flammability: No Flashpoint: N/A Conditions: None Auto ignition temperature: N/A Flammable limits (%): Upper: N/A Lower: N/A Extinguishing media: None Hazardous combustion products: None Sensitivity to mechanical impact or static discharge: No Section 5 - Reactivity Data Chemical stability: Yes Conditions: None Incompatible substances: Do not mix with other chemicals. Hazardous decomposition products: None N/A - Not Applicable Reactivity conditions: None N/Av - Not Available Page 1 of 2 MATERIAL SAFETY DATA SHEET L-82E Section 6 - Toxicological Data Route of entry: Eye and skin contact, ingestion. Acute exposure effects: None Chronic exposure effects: None Exposure limits (TLV/TWA): N/Av Carcinogenicity Mutagenicity Reproductive toxicity No No No If yes to any of the above, specify: Teratogenicity No Synergistic effects No Section 7 - Preventive Measures Protective equipment: Handling procedures: Waste disposal methods: Leak/spill procedures: Storage requirements: Engineering controls: Handling equipment: Special shipping information: Gloves in case of prolonged contact. Keep container tightly closed. Dispose as per municipal, provincial and federal regulations. Soak up with absorbent material. Rinse small amount with quantity of water. Neutralize. Store below 50ºC and above 0ºC. Keep upright. None None Section 8 - First Aid Measures Skin contact: Eye contact: Inhalation: Ingestion: Other: Wash off with water and soap. Apply cream. Rinse eyes thoroughly with water. Consult a physician. N/A Do not induce vomitting. Rinse mouth with water and give plenty of water to drink. Consult a physician. Section 9 - Preparation of MSDS Prepared by: Telephone: Date: Division Manager WCB (514) 733-3315 June 21th, 2007 This data is offered in good faith as typical values and not as a product specification. No warranty, either express or implied is hereby made. The recommended industrial hygiene and safe handling procedures are believed to bee generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate. N/A - Not Applicable N/Av - Not Available Page 2 of 2 MATERIAL SAFETY DATA SHEET Atlantic Chemical Equipment Co. 3471 Atlanta Industrial Parkway Suite 200 Atlanta, GA 30331 404-505-6626 PRODUCT NAME: (CCL) NON-RINSE EVAPORATOR COIL CLEANER EMERGENCY PHONE: 1-800-424-9300 VII - PRECAUTIONS FOR SAFE HANDLING AND USE May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200. Standard must be consulted for specific requirements. This product contains no substances subject to SARA TITLE III and 40 CRF. HMIS SYMBOLS HEALTH 1 FLAMMABILITY 0 REACTIVITY 0 STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED: SMALL SPILLS: Dilute and wash to drain. LARGE SPILLS: Due to packaging, large spills cannot occur. WASTE DISPOSAL METHOD: Deposit in approved hazardous waste landfill in accordance with local, state, and federal regulations. 1 - IDENTIFICATION VIII - SPECIAL PROTECTION INFORMATION PRODUCT NAME: CCL - EVAPORATOR COIL CLEANER PACKAGE TYPE: 16oz, 1, 5, 55 gal PREPARED DEPARTMENT OF HAZARDOUS COMMUNICATIONS DATE PREPARED: January 2006 RESPIRATORY: Wear approved mist respirator for mist conditions or in enclosed areas. EYE: Chemical goggles recommended. II - HAZARDOUS INGREDIENTS PRINCIPLE HAZARDOUS COMPONENT(S) (CHEMICAL NAMES) Sodium Silicate CAS NO ACGIH TLV 6824-92-0 ND ND 2-Butoxyethanol* 111-76-2 25ppm 25ppm OSHA % or RANGE PEL SKIN: Wear impervious gloves, apron, boots. PROTECTIVE GLOVES: Recommended Butyl/alkaline resistant OTHER: do not eat, drink, or smoke in work area. Wash hands before eating. VENTILATION REQUIREMENTS: Local exhaust adequate *2-Butyloxyethanol is a TITLE III Section 313 Chemical subject to reporting; a listed air contaminate with skin designation. IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed when not in use. III - PHYSICAL DATA BOILING POINT ( 0F) : ND VAPOR PRESSURE (mm Hg) : ND MELTING POINT: N.A. VAPOR DENSITY (Air = 1) : ND EVAPORATION RATE (H20 = 1) : ND pH : 13.0 APPEARANCE AND ODOR : Clear green liquid. Bland odor SPECIFIC GRAVITY (H20= 1) : 1.062 SPECIAL PRECAUTIONARY STATEMENTS: Keep this and all chemicals out of reach of children. NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of merchantability fitness or otherwise is made. SOLUBILITY IN WATER : Complete IV - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Not Flammable SARA Title III Reporting Requirements SPECIAL FIRE FIGHTING PROCEDURES: None known UNUSUAL FIRE AND EXPLOSION HAZARDS: None known V - REACTIVITY DATA CHEMICAL STABILITY UNSTABLE 302 (Extremely Hazardous Substances): Reporting not required. 304/CERCLA (Spills Notification): Not required. 311 Community Right-To-Know, RTK): Reporting required. Acute health hazard. 312 (RTK Inventory Data): Reporting required for inventories above TPQ. CONDITIONS TO AVOID: STABLE X INCOMPATIBILITY (Materials to avoid): Oxidizers or acids HAZARDOUS DECOMPOSITION PRODUCTS: HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID: MAY OCCUR X WILL NOT OCCUR VI - HEALTH HAZARD AREA ROUTE(S) OF ENTRY: EYES Yes SKIN Yes INGESTION Yes 313 (Emissions and Releases): Reporting required for 2-Butoxyethanol above RQ. DOT NOT HAZARDOUS INHALATION Yes References EFFECTS OF OVER EXPOSURE: Corrosive to eyes, skin, and mucous membranes INHALATION: Irritation of nasal passages. Possible light headedness. TOXIC SUBSTANCE CONTROL CT LIST (TSCA) - INGREDIENTS LISTED SKIN CONTACT/ABSORPTION: Causes burning and irritation. 2-butoxyethanol enters bloodstream through skin absorption. PERMISSIBLE EXPOSURE REFERENCES: Registry of Toxic Effects of Chemical Substances. Title 29 Code of Federal Regulations. INGESTION: causes nausea - gastric distress. Possible pulmonary edema if aspiration of material in lungs occurs while vomiting. National Toxicology Program (NTP) Report on Carcinogens. EYES: Will cause burning and severe irritation. CARCINOGENICITY: NTP? Not listed IARC MONOGRAPHS?N/L OSHA REGULATED? Not listed Title 40 Code of Federal Regulations EMERGENCY AND FIRST AID PROCEDURES: EYES AND SKIN: EYES - Wash with plenty of water for 15 minutes. GET IMMEDIATE MEDICAL ATTENTION. soap and water. Get medical help if irritation persists. If nausea occurs seek medical help. International Agency for Research on Cancer (IARC) Monographs. SKIN - Wash well with REGULATORY STANDARDS: INHALATION: Move to fresh air. If breathing difficulty does not improve seek medical attention. INGESTION: Drink water. Do not cause vomiting. GET IMMEDIATE MEDICAL ATTENTION. CALL POISON CONTROL CENTER. DOT Title 49 Code of Federal Regulations 172.101 SARA Title III Nuclear Regulatory Commission 1 MATERIAL SAFETY DATA SHEET Atlantic Chemical Equipment Co. 3471 Atlanta Industrial Parkway Suite 200 Atlanta, GA 30331 404-505-6626 PRODUCT NAME: (CCL) NON-RINSE EVAPORATOR COIL CLEANER EMERGENCY PHONE: 1-800-424-9300 VII - PRECAUTIONS FOR SAFE HANDLING AND USE May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200. Standard must be consulted for specific requirements. This product contains no substances subject to SARA TITLE III and 40 CRF. HMIS SYMBOLS HEALTH 1 FLAMMABILITY 0 REACTIVITY 0 STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED: SMALL SPILLS: Dilute and wash to drain. LARGE SPILLS: Due to packaging, large spills cannot occur. WASTE DISPOSAL METHOD: Deposit in approved hazardous waste landfill in accordance with local, state, and federal regulations. 1 - IDENTIFICATION VIII - SPECIAL PROTECTION INFORMATION PRODUCT NAME: CCL - EVAPORATOR COIL CLEANER PACKAGE TYPE: 16oz, 1, 5, 55 gal PREPARED DEPARTMENT OF HAZARDOUS COMMUNICATIONS DATE PREPARED: January 2006 RESPIRATORY: Wear approved mist respirator for mist conditions or in enclosed areas. EYE: Chemical goggles recommended. II - HAZARDOUS INGREDIENTS PRINCIPLE HAZARDOUS COMPONENT(S) (CHEMICAL NAMES) Sodium Silicate CAS NO ACGIH TLV 6824-92-0 ND ND 2-Butoxyethanol* 111-76-2 25ppm 25ppm OSHA % or RANGE PEL SKIN: Wear impervious gloves, apron, boots. PROTECTIVE GLOVES: Recommended Butyl/alkaline resistant OTHER: do not eat, drink, or smoke in work area. Wash hands before eating. VENTILATION REQUIREMENTS: Local exhaust adequate *2-Butyloxyethanol is a TITLE III Section 313 Chemical subject to reporting; a listed air contaminate with skin designation. IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed when not in use. III - PHYSICAL DATA BOILING POINT ( 0F) : ND VAPOR PRESSURE (mm Hg) : ND MELTING POINT: N.A. VAPOR DENSITY (Air = 1) : ND EVAPORATION RATE (H20 = 1) : ND pH : 13.0 APPEARANCE AND ODOR : Clear green liquid. Bland odor SPECIFIC GRAVITY (H20= 1) : 1.062 SPECIAL PRECAUTIONARY STATEMENTS: Keep this and all chemicals out of reach of children. NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of merchantability fitness or otherwise is made. SOLUBILITY IN WATER : Complete IV - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Not Flammable SARA Title III Reporting Requirements SPECIAL FIRE FIGHTING PROCEDURES: None known UNUSUAL FIRE AND EXPLOSION HAZARDS: None known V - REACTIVITY DATA CHEMICAL STABILITY UNSTABLE 302 (Extremely Hazardous Substances): Reporting not required. 304/CERCLA (Spills Notification): Not required. 311 Community Right-To-Know, RTK): Reporting required. Acute health hazard. 312 (RTK Inventory Data): Reporting required for inventories above TPQ. CONDITIONS TO AVOID: STABLE X INCOMPATIBILITY (Materials to avoid): Oxidizers or acids HAZARDOUS DECOMPOSITION PRODUCTS: HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID: MAY OCCUR X WILL NOT OCCUR VI - HEALTH HAZARD AREA ROUTE(S) OF ENTRY: EYES Yes SKIN Yes INGESTION Yes 313 (Emissions and Releases): Reporting required for 2-Butoxyethanol above RQ. DOT NOT HAZARDOUS INHALATION Yes References EFFECTS OF OVER EXPOSURE: Corrosive to eyes, skin, and mucous membranes INHALATION: Irritation of nasal passages. Possible light headedness. TOXIC SUBSTANCE CONTROL CT LIST (TSCA) - INGREDIENTS LISTED SKIN CONTACT/ABSORPTION: Causes burning and irritation. 2-butoxyethanol enters bloodstream through skin absorption. PERMISSIBLE EXPOSURE REFERENCES: Registry of Toxic Effects of Chemical Substances. Title 29 Code of Federal Regulations. INGESTION: causes nausea - gastric distress. Possible pulmonary edema if aspiration of material in lungs occurs while vomiting. National Toxicology Program (NTP) Report on Carcinogens. EYES: Will cause burning and severe irritation. CARCINOGENICITY: NTP? Not listed IARC MONOGRAPHS?N/L OSHA REGULATED? Not listed Title 40 Code of Federal Regulations EMERGENCY AND FIRST AID PROCEDURES: EYES AND SKIN: EYES - Wash with plenty of water for 15 minutes. GET IMMEDIATE MEDICAL ATTENTION. soap and water. Get medical help if irritation persists. If nausea occurs seek medical help. International Agency for Research on Cancer (IARC) Monographs. SKIN - Wash well with REGULATORY STANDARDS: INHALATION: Move to fresh air. If breathing difficulty does not improve seek medical attention. INGESTION: Drink water. Do not cause vomiting. GET IMMEDIATE MEDICAL ATTENTION. CALL POISON CONTROL CENTER. DOT Title 49 Code of Federal Regulations 172.101 SARA Title III Nuclear Regulatory Commission 1 MATERIAL SAFETY DATA SHEET Atlantic Chemical Equipment Co. 2190 DeFoor Hills Rd NW Atlanta, GA 30318 404-355-5522 PRODUCT NAME: HEAVY DUTY COIL CLEANER (HDC) EMERGENCY PHONE: 1-800-424-9300 VII - PRECAUTIONS FOR SAFE HANDLING AND USE May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200. Standard must be consulted for specific requirements. This product contains no substances subject to SARA TITLE III and 40 CRF. HMIS SYMBOLS HEALTH 2 FLAMMABILITY 0 REACTIVITY 0 STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED: SMALL SPILLS: Neutralize with vinegar and flush to sanitary sewer. LARGE SPILLS: Due to packaging, large spills can not occur. WASTE DISPOSAL METHOD: Deposit in landfill in accordance with Local, State, and Federal regulations. 1 - IDENTIFICATION VIII - SPECIAL PROTECTION INFORMATION PRODUCT NAME: (HDC) HEAVY DUTY COIL CLEANER PACKAGE TYPE: 16oz, 1, 5, 55gallon PREPARED DEPARTMENT OF HAZARDOUS COMMUNICATIONS DATE PREPARED: June 2003 RESPIRATORY: Needed to keep exposure below TLV for mists. Use NIOSH approved cartridge type respirator for mists. EYE: Chemical goggles recommended II - HAZARDOUS INGREDIENTS OSHA % or RANGE PEL PRINCIPLE HAZARDOUS COMPONENT(S) (CHEMICAL NAMES) Caustic Potash (Potassium Hydroxide) CAS NO ACGIH TLV 1310-58-3 2 mg/m3 Hexylene Glycol 107-41-5 26 ppm Triethanolamine 102-71-6 N/E N/E >1 Sodium Metasilicate 6834-92-0 N/E N/E >2 SKIN: Avoid contact with eyes, skin, and clothing. Wash hands PROTECTIVE GLOVES: Recommended. Chemical resistant rubber or and face thoroughly after handling. plastic gloves. <2 2 mg/m3 >4 OTHER: Rubber of PVC footwear, apron in misty conditions. VENTILATION REQUIREMENTS: Local exhaust adequate. IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed when not in use. Do not store in aluminum drums and separate from acids. III - PHYSICAL DATA BOILING POINT ( 0F) : 2120F VAPOR PRESSURE (mm Hg) : 17 MELTING POINT: N/D VAPOR DENSITY (Air = 1) : 1.0 EVAPORATION RATE (H20 = 1) : pH : 13.5 APPEARANCE AND ODOR : Clear yellow liquid - Slight glycol odor SPECIFIC GRAVITY (H20= 1) : 1.12 SPECIAL PRECAUTIONARY STATEMENTS: Keep this and all chemicals out of reach of children. SOLUBILITY IN WATER : Complete IV - FIRE AND EXPLOSION HAZARD DATA NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of merchantability fitness or otherwise is made. FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Non-Flammable SARA Title III Reporting Requirements SPECIAL FIRE FIGHTING PROCEDURES: Wear impervious gear to prevent all contact UNUSUAL FIRE AND EXPLOSION HAZARDS: V - REACTIVITY DATA CHEMICAL STABILITY UNSTABLE 302 (Extremely Hazardous Substances): Reporting not required. 304/CERCLA (Spills Notification): Reporting required for spills above 1000 lbs. 311 Community Right-To-Know, RTK): Reporting required. Acute & chronic health hazard, corrosive & toxic 312 (RTK Inventory Data): Reporting required for above TPQ. CONDITIONS TO AVOID: X STABLE INCOMPATIBILITY (Materials to avoid): Acids, acid products, oxidizing agents HAZARDOUS DECOMPOSITION PRODUCTS: Heat, Carbon Monoxide, Carbon Dioxide HAZARDOUS POLYMERIZATION MAY OCCUR CONDITIONS TO AVOID: WILL NOT OCCUR X VI - HEALTH HAZARD AREA ROUTE(S) OF ENTRY: EYES Yes SKIN Yes INGESTION Yes 313 (Emissions and Releases): Reporting not required. DOT Corrosive liquid, basic, inorganic, N.O.S. (contains potassium hydroxide) 8, UN3264, PGIII INHALATION Yes References EFFECTS OF OVER EXPOSURE: Corrosive to eyes and mucous membranes INHALATION: Mists are irritating to nasal passages TOXIC SUBSTANCE CONTROL CT LIST (TSCA) - INGREDIENTS LISTED SKIN CONTACT/ABSORPTION: Irritation, redness INGESTION: Gastric distress. Corrosive to digestive tract. May cause central nervous system depression PERMISSIBLE EXPOSURE REFERENCES: Registry of Toxic Effects of Chemical Substances. Title 29 Code of Federal Regulations. National Toxicology Program (NTP) Report on Carcinogens. EYES: Burning, irritation, redness. Corrosive to eyes. CARCINOGENICITY: NTP? Not listed IARC MONOGRAPHS? Not listed OSHA REGULATED? Not listed Title 40 Code of Federal Regulations EMERGENCY AND FIRST AID PROCEDURES: EYES AND SKIN: EYES - Wash eyes with plenty of water for 15 minutes. SEEK IMMEDIATE MEDICAL ATTENTION soap and water. SEEK MEDICAL ATTENTION if irritation persists International Agency for Research on Cancer (IARC) Monographs. SKIN - Wash well with REGULATORY STANDARDS: INHALATION: Remove to fresh air. If breathing is difficult SEEK IMMEDIATE MEDICAL ATTENTION INGESTION: Drink water. DO NOT induce vomiting. SEEK IMMEDIATE MEDICAL ATTENTION. CALL POISON CONTROL CENTER DOT Title 49 Code of Federal Regulations 172.101 SARA Title III Nuclear Regulatory Commission 1 MATERIAL SAFETY DATA SHEET Atlantic Chemical Equipment Co. 2190 DeFoor Hills Rd NW Atlanta, GA 30318 404-355-5522 PRODUCT NAME: ALKALINE COIL CLEANER (ACC) EMERGENCY PHONE: 1-800-424-9300 VII - PRECAUTIONS FOR SAFE HANDLING AND USE May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200. Standard must be consulted for specific requirements. This product contains no substances subject to SARA TITLE III and 40 CRF. HMIS SYMBOLS HEALTH 3 FLAMMABILITY 0 REACTIVITY 0 STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED: SMALL SPILLS: Neutralize with diluted acid flush with water to drain. LARGE SPILLS: Due to packaging, large spills can not occur. WASTE DISPOSAL METHOD: Deposit in accordance to local, state, and federal regulations 1 - IDENTIFICATION VIII - SPECIAL PROTECTION INFORMATION PRODUCT NAME: Alkaline Coil Cleaner (ACC) PACKAGE TYPE: Pint, Gallon, Pail, or Drum PREPARED DEPARTMENT OF HAZARDOUS COMMUNICATIONS DATE PREPARED: June 2003 RESPIRATORY: Vapor cartridge for mists and vapors/Not normally needed with local exhaust EYE: Chemical goggles - Recommended II - HAZARDOUS INGREDIENTS PRINCIPLE HAZARDOUS COMPONENT(S) (CHEMICAL NAMES) Caustic Soda (Sodium Hydroxide)* CAS NO ACGIH TLV 1310-73-2 2mg/m OSHA 3 % or RANGE PEL 2mg/m 3 SKIN: Wear impervious clothing, boots, splash apron PROTECTIVE GLOVES: Chemical resistant rubber or plastic gloves < 17 * listed air contaminate (see 29 CFR per 1910.1000) OTHER: Do not eat, drink, or smoke in work area. Wash hands before eating VENTILATION REQUIREMENTS: Local exhaust adequate III - PHYSICAL DATA BOILING POINT ( 0F) : 2120F VAPOR PRESSURE (mm Hg) : N/D MELTING POINT: N/A VAPOR DENSITY (Air = 1) : 1 EVAPORATION RATE (H20 = 1) : > 1 pH : 13.5 APPEARANCE AND ODOR : Clear liquid - slight ester odor SPECIFIC GRAVITY (H20= 1) : 1.18 IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed when not in use SOLUBILITY IN WATER : Complete SPECIAL PRECAUTIONARY STATEMENTS: Keep this and all chemicals out of reach of children. IV - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Flash Point: None NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of merchantability fitness or otherwise is made. SPECIAL FIRE FIGHTING PROCEDURES: Flood with water; compound is corrosive to exposed skin, wear protective clothing UNUSUAL FIRE AND EXPLOSION HAZARDS: May react with oxidizers CHEMICAL STABILITY UNSTABLE SARA Title III Reporting Requirements CONDITIONS TO AVOID: STABLE X 302 (Extremely Hazardous Substances): Reporting not required. 304/CERCLA (Spills Notification): Reporting required if release is above RQ for sodium hydroxide (1000 lbs) 311 Community Right-To-Know, RTK): Reporting required. Acute health hazard, corrosive, toxic. 312 (RTK Inventory Data): Reporting required for inventories above threshold planning quantity. EFFECTS OF OVER EXPOSURE: Corrosive to skin, eyes, and mucous membranes, digestive tract 313 (Emissions and Releases): Reporting not required. INHALATION: Irritation of respiratory system/mists can cause damage to respiratory passages. DOT Corrosive liquid, basic, inorganic, N.O.S. (contains sodium hydroxide) 8, UN3266, PGII INCOMPATIBILITY (Materials to avoid): Acids and acids products. Soft metals. Oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Carbon dioxide, Heat, Carbon Monoxide HAZARDOUS POLYMERIZATION MAY OCCUR CONDITIONS TO AVOID: WILL NOT OCCUR X VI - HEALTH HAZARD AREA ROUTE(S) OF ENTRY: EYES Yes SKIN Yes INGESTION Yes INHALATION Yes SKIN CONTACT/ABSORPTION: causes burning and possible deep ulceration References INGESTION: Gastric distress (severe damage to membranes and deep tissues) TOXIC SUBSTANCE CONTROL CT LIST (TSCA) - INGREDIENTS LISTED PERMISSIBLE EXPOSURE REFERENCES: EYES: Will cause burning and severe damage even blindness rapidly CARCINOGENICITY: NTP? Notlisted IARC MONOGRAPHS? Not listed OSHA REGULATED? Not listed EYES AND SKIN: EYES - Flush eyes with plenty of water for 15 minutes. GET IMMEDIATE MEDICAL ATTENTION neutralize skin then wash well with soap and water. Get medical help if irritation persists INHALATION: Move to fresh air, if breathing is difficult or stops then start artificial respiration. GET MEDICAL ATTENTION INGESTION: Drink water. Do Not induce vomiting. GET IMMEDIATE MEDICAL ATTENTION. Call Poison Control Center. Registry of Toxic Effects of Chemical Substances. Title 29 Code of Federal Regulations. EMERGENCY AND FIRST AID PROCEDURES: SKIN - Use vinegar to National Toxicology Program (NTP) Report on Carcinogens. International Agency for Research on Cancer (IARC) Monographs. Title 40 Code of Federal Regulations REGULATORY STANDARDS: DOT Title 49 Code of Federal Regulations 172.101 SARA Title III Nuclear Regulatory Commission 1 PROTECH™ Super Concentrated Condenser Coil Cleaner 85-H4X32, 85-4X08 Page 1 of 2 MATERIAL SAFETY DATA SHEET SECTION 1 CHEMICAL PRODUCT AND COMPANY INFORMATION Product Name: PROTECH™ Super Concentrated Condenser Coil Cleaner Product Number(s): 85-H4X32, 85-4X08 Product Use: Coil cleaner Company Name: North American Research Corporation P.O. Box 1318 Lewisville, TX 75067 Telephone Numbers: (972) 492-1800, (800) 527-7520, Fax (972) 394-6755 Emergencies: Infotrac (800) 535-5053 (24 hours, everyday) SECTION 2 Date Prepared Jan. 24, 2003 Replaces Apr. 04, 2001 COMPOSITION / INFORMATION ON INGREDIENTS OSHA Hazardous Components (29 CFR 1910.1200): Potassium Hydroxide SECTION 3 CAS Registry No. 1310-58-3 OSHA PEL 3 2 mg/m Ceiling ACGIH TLV 3 2 mg/m Ceiling Other Limits None known % (Optional) < 70 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW POISON! DANGER! CORROSIVE. CAUSES SEVERE BURNS TO SKIN, EYES, AND OTHER BODY TISSUE. HARMFUL OR FATAL IF SWALLOWED. POTENTIAL HEALTH EFFECTS EYE CONTACT: Corrosive. May cause permanent damage including blindness. SKIN CONTACT: Corrosive. May cause permanent damage. INHALATION: May cause irritation and corrosive effects to the nose, throat, and respiratory tract. Severe injury is usually avoided by self-limiting coughing and sneezing symptoms. INGESTION: Corrosive. May cause burns to mouth, throat, and stomach. CHRONIC EXPOSURE: No known chronic effects. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: None known other than existing skin disorders. CARCINOGENICITY: NTP? No IARC Monographs? No OSHA Regulated? No SECTION 4 FIRST-AID MEASURES EYE CONTACT: Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Get medical attention immediately. SKIN CONTACT: Flush immediately with plenty of water for at least 15 minutes. Get medical attention immediately. INHALATION: If breathing is difficult: Remove to fresh air. Get medical attention immediately. INGESTION: Do not induce vomiting! Immediately drink large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. SECTION 5 FIRE-FIGHTING MEASURES FLASHPOINT: Not flammable METHOD: Not applicable FLAMMABLE LIMITS: LEL: Not applicable UEL: Not applicable AUTOIGNITION TEMP: Not applicable GENERAL HAZARD: Not considered to be a fire hazard. Will react with some metals, eg. Aluminum, tin, zinc to form flammable hydrogen gas. FIRE EXTINGUISHING MEDIA: Use means suitable for extinguishing surrounding fire. Water spray may be used to keep fire-exposed containers cool. SPECIAL INFORMATION: Corrosive material. See sections 8 and 10. SECTION 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: Put on appropriate personal protective equipment. ENVIRONMENTAL PRECAUTIONS AND CLEAN-UP: Small spills: Mop up or soak up with rags and flush with water. In the event of major spillage: Use appropriate containment consistent with good industrial or environmental practice. Recover as much as possible. Pump, sweep or scrape up the remaining material and place in suitable clean containers for disposal by proper methods. Use a water rinse for final clean-up. PROTECH™ Super Concentrated Condenser Coil Cleaner SECTION 7 85-H4X32, 85-4X08 Page 2 of 2 STORAGE AND HANDLING HANDLING: Avoid contact with eyes, skin, and clothing. Do not taste or swallow. Avoid breathing vapors or spray mists. Wash thoroughly after handling. Remove and wash contaminated clothing and footwear before reuse. Product residue may remain on/in empty containers. All precautions for handling the product must be used in handling the empty container and residue. FOR INDUSTRIAL USE ONLY. STORAGE: Keep tightly closed in original container. Store in a cool, dry, ventilated area. Protect against physical damage. Tip: For transport on service truck, place container inside of plastic pail and immobilize pail. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE CONTROLS: Good general ventilation should be sufficient to control airborne levels. Respiratory protection is not required if good ventilation is maintained. PERSONAL PROTECTION: EYES: Chemical splash goggles. HANDS: Chemical resistant gloves; rubber, neoprene, or other impervious material. RESPIRATORY: If mists/vapors are not adequately controlled by ventilation, use appropriate respiratory protection to avoid over exposure. A respiratory protection program that meets OSHA’s 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator’s use. FEET: Chemical resistant boots; rubber, neoprene, or other impervious material. BODY: If major exposure is possible, wear suitable, impervious protective clothing. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE AND ODOR: Semi-viscous, amber to clear liquid. Bland odor. VAPOR PRESSURE: Not determined SOLUBILITY IN WATER: Complete BOILING POINT: 212°F EVAPORATION RATE (Butyl Acetate = 1): Not determined SECTION 10 SPECIFIC GRAVITY: 1.42 VAPOR DENSITY: Not determined pH: 13.5 FREEZING / MELTING POINT: Not determined STABILITY AND REACTIVITY STABILITY: Stable under ordinary conditions of use and storage. HAZARDOUS POLYMERIZATION: Will not occur. INCOMPATIBILITY (Materials to Avoid): Reactive with oxidizing agents, acids, chlorinated hydrocarbons, acetone. Will react with some metals, e.g., aluminum, tin, zinc, to form flammable hydrogen gas. HAZARDOUS DECOMPOSITION PRODUCTS: When exposed to fire, produces normal products of combustion. SECTION 11 TOXICOLOGICAL INFORMATION For Potassium Hydroxide (1310-58-3): Oral LD50 (rat): 365 mg/kg. Primary skin irritation: (rabbit, 24hr) severe. Primary eye irritation: (rabbit, 24hr) severe. SECTION 12 ECOLOGICAL INFORMATION For Potassium Hydroxide (1310-58-3): LC50 (96hr) Fathead minnow, 45% KOH solution = 179 mg/L. SECTION 13 DISPOSAL CONSIDERATIONS Disposal of unused product is regulated under environmental and transportation laws as a corrosive waste. Dispose of container and unused contents in accordance with federal, state, and local requirements. SECTION 14 TRANSPORT INFORMATION U.S. Department of Transportation: Potassium Hydroxide Solution, 8, UN1814, PG II SECTION 15 REGULATORY INFORMATION TSCA: All ingredients of this product are listed or are excluded from listing on the U.S. TSCA chemical substances inventory. CERCLA: Potassium Hydroxide (1310-58-3); RQ 1000 lbs. SARA TITLE III: Section 311/312 Hazard Category: Acute: Yes Chronic: No Fire: No Pressure: No Reactive Hazard: Yes Section 313 Reportable Ingredients: None SECTION 16 OTHER INFORMATION NFPA RATING: Health – 3, Flammability – 0, Reactivity – 1 ® HMIS RATING: Health – 3, Flammability – 0, Reactivity – 2 ® ® ® HMIS ratings are to be used with a fully implemented HMIS program. HMIS is a registered mark of the National Paint and Coatings Association (NPCA). NOTICE: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to accuracy of the information contained within. Actual conditions of use and handling are beyond seller’s control. User is responsible to evaluate all available information when using product for any particular use and to comply with all federal, state, provincial, and local laws and regulations. PROTECH™ Super Concentrated Condenser Coil Cleaner 85-4X08, 85-H4X32 Page 1 of 2 MATERIAL SAFETY DATA SHEET SECTION 1 CHEMICAL PRODUCT AND COMPANY INFORMATION Product Name: PROTECH™ Super Concentrated Condenser Coil Cleaner Product Number(s): 85-4X08, 85-H4X32 Product Use: Coil cleaner Company Name: North American Research Corporation P.O. Box 1318 Lewisville, TX 75067 Telephone Numbers: (972) 492-1800, (800) 527-7520, Fax (972) 394-6755 Emergencies: Infotrac (800) 535-5053 (24 hours, everyday) SECTION 2 Date Prepared Jan. 14, 2004 Replaces COMPOSITION / INFORMATION ON INGREDIENTS OSHA Hazardous Components (29 CFR 1910.1200): Potassium Hydroxide SECTION 3 CAS Registry No. 1310-58-3 OSHA PEL 3 2 mg/m Ceiling ACGIH TLV 3 2 mg/m Ceiling Other Limits None known % (Optional) < 70 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW POISON! DANGER! CORROSIVE. CAUSES SEVERE BURNS TO SKIN, EYES, AND OTHER BODY TISSUE. HARMFUL OR FATAL IF SWALLOWED. POTENTIAL HEALTH EFFECTS EYE CONTACT: Corrosive. May cause permanent damage including blindness. SKIN CONTACT: Corrosive. May cause permanent damage. INHALATION: May cause irritation and corrosive effects to the nose, throat, and respiratory tract. Severe injury is usually avoided by self-limiting coughing and sneezing symptoms. INGESTION: Corrosive. May cause burns to mouth, throat, and stomach. CHRONIC EXPOSURE: No known chronic effects. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: None known other than existing skin disorders. CARCINOGENICITY: NTP? No IARC Monographs? No OSHA Regulated? No SECTION 4 FIRST-AID MEASURES EYE CONTACT: Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Get medical attention immediately. SKIN CONTACT: Flush immediately with plenty of water for at least 15 minutes. Get medical attention immediately. INHALATION: If breathing is difficult: Remove to fresh air. Get medical attention immediately. INGESTION: Do not induce vomiting! Immediately drink large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. SECTION 5 FIRE-FIGHTING MEASURES FLASHPOINT: Not flammable METHOD: Not applicable FLAMMABLE LIMITS: LEL: Not applicable UEL: Not applicable AUTOIGNITION TEMP: Not applicable GENERAL HAZARD: Not considered to be a fire hazard. Will react with some metals, eg. Aluminum, tin, zinc to form flammable hydrogen gas. FIRE EXTINGUISHING MEDIA: Use means suitable for extinguishing surrounding fire. Water spray may be used to keep fire-exposed containers cool. SPECIAL INFORMATION: Corrosive material. See sections 8 and 10. SECTION 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: Put on appropriate personal protective equipment. ENVIRONMENTAL PRECAUTIONS AND CLEAN-UP: Small spills: Mop up or soak up with rags and flush with water. In the event of major spillage: Use appropriate containment consistent with good industrial or environmental practice. Recover as much as possible. Pump, sweep or scrape up the remaining material and place in suitable clean containers for disposal by proper methods. Use a water rinse for final clean-up. PROTECH™ Super Concentrated Condenser Coil Cleaner SECTION 7 85-4X08, 85-H4X32 Page 2 of 2 STORAGE AND HANDLING HANDLING: Avoid contact with eyes, skin, and clothing. Do not taste or swallow. Avoid breathing vapors or spray mists. Wash thoroughly after handling. Remove and wash contaminated clothing and footwear before reuse. Product residue may remain on/in empty containers. All precautions for handling the product must be used in handling the empty container and residue. FOR INDUSTRIAL USE ONLY. STORAGE: Keep tightly closed in original container. Store in a cool, dry, ventilated area. Protect against physical damage. Tip: For transport on service truck, place container inside of plastic pail and immobilize pail. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE CONTROLS: Good general ventilation should be sufficient to control airborne levels. Respiratory protection is not required if good ventilation is maintained. PERSONAL PROTECTION: EYES: Chemical splash goggles. HANDS: Chemical resistant gloves; rubber, neoprene, or other impervious material. RESPIRATORY: If mists/vapors are not adequately controlled by ventilation, use appropriate respiratory protection to avoid over exposure. A respiratory protection program that meets OSHA’s 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator’s use. FEET: Chemical resistant boots; rubber, neoprene, or other impervious material. BODY: If major exposure is possible, wear suitable, impervious protective clothing. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE AND ODOR: Semi-viscous, amber to clear liquid. Bland odor. VAPOR PRESSURE: Not determined SOLUBILITY IN WATER: Complete BOILING POINT: 212°F EVAPORATION RATE (Butyl Acetate = 1): Not determined SECTION 10 SPECIFIC GRAVITY: 1.42 VAPOR DENSITY: Not determined pH: 13.5 FREEZING / MELTING POINT: Not determined STABILITY AND REACTIVITY STABILITY: Stable under ordinary conditions of use and storage. HAZARDOUS POLYMERIZATION: Will not occur. INCOMPATIBILITY (Materials to Avoid): Reactive with oxidizing agents, acids, chlorinated hydrocarbons, acetone. Will react with some metals, e.g., aluminum, tin, zinc, to form flammable hydrogen gas. HAZARDOUS DECOMPOSITION PRODUCTS: When exposed to fire, produces normal products of combustion. SECTION 11 TOXICOLOGICAL INFORMATION For Potassium Hydroxide (1310-58-3): Oral LD50 (rat): 365 mg/kg. Primary skin irritation: (rabbit, 24hr) severe. Primary eye irritation: (rabbit, 24hr) severe. SECTION 12 ECOLOGICAL INFORMATION For Potassium Hydroxide (1310-58-3): LC50 (96hr) Fathead minnow, 45% KOH solution = 179 mg/L. SECTION 13 DISPOSAL CONSIDERATIONS Disposal of unused product is regulated under environmental and transportation laws as a corrosive waste. Dispose of container and unused contents in accordance with federal, state, and local requirements. SECTION 14 TRANSPORT INFORMATION U.S. Department of Transportation: Potassium Hydroxide Solution, 8, UN1814, PG II SECTION 15 REGULATORY INFORMATION TSCA: All ingredients of this product are listed or are excluded from listing on the U.S. TSCA chemical substances inventory. CERCLA: Potassium Hydroxide (1310-58-3); RQ 1000 lbs. SARA TITLE III: Section 311/312 Hazard Category: Acute: Yes Chronic: No Fire: No Pressure: No Reactive Hazard: Yes Section 313 Reportable Ingredients: None SECTION 16 OTHER INFORMATION NFPA RATING: Health – 3, Flammability – 0, Reactivity – 1 ® HMIS RATING: Health – 3, Flammability – 0, Reactivity – 2 ® ® ® HMIS ratings are to be used with a fully implemented HMIS program. HMIS is a registered mark of the National Paint and Coatings Association (NPCA). NOTICE: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to accuracy of the information contained within. Actual conditions of use and handling are beyond seller’s control. User is responsible to evaluate all available information when using product for any particular use and to comply with all federal, state, provincial, and local laws and regulations. MATERIAL SAFETY DATA SHEET Atlantic Chemical Equipment Co. 2190 DeFoor Hills Rd NW Atlanta, GA 30318 404-355-5522 Toll Free: 1-800-929-2436 PRODUCT NAME: (FNC) FOAM N' CLEAN COIL CLEANER EMERGENCY PHONE: 1-800-424-9300 VII - PRECAUTIONS FOR SAFE HANDLING AND USE May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200. Standard must be consulted for specific requirements. This product contains no substances subject to SARA TITLE III and 40 CRF. HMIS SYMBOLS HEALTH 3 FLAMMABILITY 0 REACTIVITY 0 STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED: SMALL SPILLS: Neutralize with water and vinegar. Wash to drain LARGE SPILLS: Due to packaging, large spills cannot occur WASTE DISPOSAL METHOD: Deposit in landfill in accordance with local, state, and federal regulations 1 - IDENTIFICATION VIII - SPECIAL PROTECTION INFORMATION PRODUCT NAME: Foam N' Clean Coil Cleaner (FNC) PACKAGE TYPE: 32oz, 1, 2.5, 5, & 55 gallon units PREPARED BY GENE HUNT/CHEMIST SUPERSCEEDES MAY 2002 MSDS DATE PREPARED: Revised August 2003 RESPIRATORY: Keep face away from spray mist. Do not breathe vapors. EYE: Use tight fitting, splash proof safety goggles. Contact lenses should no be worn when handling this material. II - HAZARDOUS INGREDIENTS CAS NO ACGIH TLV OSHA % or RANGE PEL PRINCIPLE HAZARDOUS COMPONENT(S) (CHEMICAL NAMES) Sodium Metasilicate 6834-92-0 N/E N/E < 1.5 Sodium Hydroxide 50% 1310-73-2 2mg/m2 < 38 Potassium Hydroxide 45% 1310-58-3 2mg/m3 2mg/m3 NE SKIN: Wear impervious clothing and footwear to prevent all skin contact. Use of face shield is recommended. PROTECTIVE GLOVES: Chemical resistant rubber/neoprene OTHER: Avoid contact with eyes, skin, and clothing. Wash hands and face thoroughly after handling <4 VENTILATION REQUIREMENTS: If vapors are detected, ventilate work area by opening windows and using exhaust fans. Always work with wind from behind. III - PHYSICAL DATA BOILING POINT ( 0F) : 2120F VAPOR PRESSURE (mm Hg) : 17 MELTING POINT: VAPOR DENSITY (Air = 1) : 2 EVAPORATION RATE (H20 = 1) : 1.0 pH : 11.6 - 13.0 @ 20 0C SOLUBILITY IN WATER : Complete APPEARANCE AND ODOR : Clear brown liquid, Herbal Odor SPECIFIC GRAVITY (H20= 1) : 1.20 N/A IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed when not in use SPECIAL PRECAUTIONARY STATEMENTS: Keep this and all chemicals out of reach of children. IV - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Flash Point: Not Combustible SPECIAL FIRE FIGHTING PROCEDURES: Standard fire fighting techniques / Wear impervious to strong Alkaline Products Clothing UNUSUAL FIRE AND EXPLOSION HAZARDS: Avoid mixing with acids and soft metals CHEMICAL STABILITY UNSTABLE NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of merchantability fitness or otherwise is made. SARA Title III Reporting Requirements CONDITIONS TO AVOID: STABLE X INCOMPATIBILITY (Materials to avoid): Acids and acid products 302 (Extremely Hazardous Substances): Reporting not required. 304/CERCLA (Spills Notification): Reporting required for spills above RQ. Sodium hydroxide and Potassium hydroxide are listed by CERCLA. Spills in excess of 1000 lbs. Each must be reported. 311 Community Right-To-Know, RTK): Reporting required. Acute & chronic health hazard, corrosive, toxic. 312 (RTK Inventory Data): Reporting required for inventories above threshold planning quantity. HAZARDOUS DECOMPOSITION PRODUCTS: Heat HAZARDOUS POLYMERIZATION MAY OCCUR CONDITIONS TO AVOID: WILL NOT OCCUR X VI - HEALTH HAZARD AREA ROUTE(S) OF ENTRY: EYES Yes SKIN Yes INGESTION Yes INHALATION Yes EFFECTS OF OVER EXPOSURE: Very corrosive to skin, eyes, and mucous membranes; causes deep immediate burns, any cause blindness 313 (Emissions and Releases): Reporting not required. INHALATION: Irritation to nasal passages DOT Corrosive liquids, basic, inorganic, N.O.S. (contains sodium hydroxide) 8, UN3266, PGII SKIN CONTACT/ABSORPTION: Severe burns to exposed skin INGESTION: Nausea, Corrosive to digestive tract EYES: Corrosive to eyes/Blindness may occur NTP? Not listed CARCINOGENICITY: No References PERMISSIBLE EXPOSURE REFERENCES: Registry of Toxic Effects of Chemical Substances. IARC MONOGRAPHS? Not listed OSHA REGULATED? See ss II for exposure EMERGENCY AND FIRST AID PROCEDURES: Title 29 Code of Federal Regulations. EYES AND SKIN: EYES - Wash with plenty of water for 15 minutes. GET IMMEDIATE MEDICAL ATTENTION SKIN - Neutralize with very diluted vinegar solution, wash with soap and water, apply skin cream. For large burns - GET IMMEDIATE MEDICAL ATTENTION National Toxicology Program (NTP) Report on Carcinogens. INHALATION: Remove to fresh air. If breathing stops, start artificial respiration, GET IMMEDIATE MEDICAL ATTENTION Title 40 Code of Federal Regulations International Agency for Research on Cancer (IARC) Monographs. INGESTION: Drink water. DO NOT induce vomiting. SEEK IMMEDIATE MEDICAL ATTENTION. NOTE: Vomiting may cause aspiration of material REGULATORY STANDARDS: to lungs causing Pulmonary Edema DOT Title 49 Code of Federal Regulations 172.101 SARA Title III Nuclear Regulatory Commission 1 MATERIAL SAFETY DATA SHEET Atlantic Chemical Equipment Co. 2190 DeFoor Hills Rd NW Atlanta, GA 30318 404-355-5522 PRODUCT NAME: ENVIRO-SAFE COIL CLEANER (ECS) EMERGENCY PHONE: 1-800-424-9300 May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200. Standard must be consulted for specific requirements. This product contains no substances subject to SARA TITLE III and 40 CRF. VII - PRECAUTIONS FOR SAFE HANDLING AND USE STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED: Neutralize with diluted vinegar solution to pH of 7 the flush to sewer. HMIS SYMBOLS HEALTH 1 FLAMMABILITY 0 REACTIVITY 0 WASTE DISPOSAL METHOD: Flush to sanitary sewer or dispose with other sanitary waste. 1 - IDENTIFICATION VIII - SPECIAL PROTECTION INFORMATION PRODUCT NAME: (ECS) ENVIRO-SAFE COIL CLEANER PACKAGE TYPE: 1, 5, 55 gal PREPARED DEPARTMENT OF HAZARDOUS COMMUNICATIONS DATE PREPARED: June 2003 RESPIRATORY: Required in misty conditions EYE: Chemical goggles with side shields II - HAZARDOUS INGREDIENTS PRINCIPLE HAZARDOUS COMPONENT(S) (CHEMICAL NAMES) None known CAS NO ACGIH TLV OSHA PEL % or RANGE SKIN: Required to prevent skin contact PROTECTIVE GLOVES: Required OTHER: Follow good housekeeping practices/Empty container may contain hazardous residue. Do not reuse for food or drink. VENTILATION REQUIREMENTS: Recommended for enclosed areas IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed when not in use. Do not freeze. Follow label instructions. III - PHYSICAL DATA BOILING POINT ( 0F) : 2140F VAPOR PRESSURE (mm Hg) : NA MELTING POINT: N/A VAPOR DENSITY (Air = 1) : NA EVAPORATION RATE (H20 = 1) : 14.0 pH : 8.5 APPEARANCE AND ODOR : Clear, no odor liquid SPECIFIC GRAVITY (H20= 1) : 1.09 SPECIAL PRECAUTIONARY STATEMENTS: Keep this and all chemicals out of reach of children. NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of merchantability fitness or otherwise is made. SOLUBILITY IN WATER : Complete IV - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Flash Point - Not Flammable SARA Title III Reporting Requirements SPECIAL FIRE FIGHTING PROCEDURES: Keep containers cool with water spray UNUSUAL FIRE AND EXPLOSION HAZARDS: None known V - REACTIVITY DATA CHEMICAL STABILITY UNSTABLE 302 (Extremely Hazardous Substances): Reporting not required. 304/CERCLA (Spills Notification): Not required. 311 Community Right-To-Know, RTK): Reporting not required. 312 (RTK Inventory Data): Not required. 313 (Emissions and Releases): Reporting not required. DOT NOT HAZARDOUS CONDITIONS TO AVOID: STABLE X INCOMPATIBILITY (Materials to avoid): Avoid oxidizers or acids HAZARDOUS DECOMPOSITION PRODUCTS: Heat, carbon dioxide, carbon monoxide HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID: MAY OCCUR WILL NOT OCCUR X VI - HEALTH HAZARD AREA ROUTE(S) OF ENTRY: EYES Yes SKIN Yes INGESTION Yes INHALATION Yes References EFFECTS OF OVER EXPOSURE: INHALATION: Mists are corrosive to respiratory tract TOXIC SUBSTANCE CONTROL CT LIST (TSCA) - INGREDIENTS LISTED SKIN CONTACT/ABSORPTION: Irritating PERMISSIBLE EXPOSURE REFERENCES: Registry of Toxic Effects of Chemical Substances. INGESTION: Corrosive to digestive system Title 29 Code of Federal Regulations. National Toxicology Program (NTP) Report on Carcinogens. EYES: Corrosive to eyes CARCINOGENICITY: NTP? Not listed IARC MONOGRAPHS? Not listed OSHA REGULATED? Not listed EMERGENCY AND FIRST AID PROCEDURES: International Agency for Research on Cancer (IARC) Monographs. Title 40 Code of Federal Regulations EYES AND SKIN: EYES - Wash with plenty of water for 15 minutes, lifting upper and lower lids. GET IMMEDIATE MEDICAL ATTENTION. SKIN - REGULATORY STANDARDS: Rinse skin with water. If irritation results apply skin cream and discontinue use. DOT Title 49 Code of Federal Regulations 172.101 INHALATION: Move to fresh air. If breathing is difficult seek IMMEDIATE medical attention INGESTION: Drink water or orange juice to dilute. DO NOT induce vomiting, GET IMMEDIATE MEDICAL ATTENTION, call Poison Control Center SARA Title III Nuclear Regulatory Commission 1 MATERIAL SAFETY DATA SHEET Atlantic Chemical Equipment Co. 2190 DeFoor Hills Rd NW Atlanta, GA 30318 404-355-5522 PRODUCT NAME: ACESEAL MASTIC 181 (MAS) EMERGENCY PHONE: 1-800-424-9300 VII - PRECAUTIONS FOR SAFE HANDLING AND USE May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200. Standard must be consulted for specific requirements. This product contains no substances subject to SARA TITLE III and 40 CRF. HMIS SYMBOLS HEALTH - FLAMMABILITY - REACTIVITY - STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED: SMALL SPILLS: Dilute and neutralize and wash to drain LARGE SPILLS: Due to packaging, large spills cannot occur. WASTE DISPOSAL METHOD: Deposit in landfill in accordance with local, state, and federal regulations. 1 - IDENTIFICATION VIII - SPECIAL PROTECTION INFORMATION PRODUCT NAME: (MAS) ACESEAL MASTIC 181 PACKAGE TYPE: 1, 2 gal PREPARED DEPARTMENT OF HAZARDOUS COMMUNICATIONS DATE PREPARED: June 2003 RESPIRATORY: None required in ventilated areas. EYE: Follow good industrial practice by wearing safety glasses. II - HAZARDOUS INGREDIENTS PRINCIPLE HAZARDOUS COMPONENT(S) (CHEMICAL NAMES) Ammonium Hydroxide (29%) Methyl Alcohol OSHA PEL % or RANGE CAS NO ACGIH TLV 1136-21-6 10 mg/cu. M 10 mg/cu. M 0.07 67-56-1 250 ppm 250 ppm 2.9 SKIN: No significant concern. PROTECTIVE GLOVES: Chemical resistant rubber or plastic. OTHER: N/A VENTILATION REQUIREMENTS: General good ventilation is recommended. IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed when not in use. Store with adequate ventilation. III - PHYSICAL DATA BOILING POINT ( 0F) : 1000F VAPOR PRESSURE (mm Hg) : N/E MELTING POINT: N/A VAPOR DENSITY (Air = 1) : N/E EVAPORATION RATE (H20 = 1) : Less than 1 pH : NA APPEARANCE AND ODOR : White or gray with slight ammonia odor SPECIFIC GRAVITY (H20= 1) : 1.37 SPECIAL PRECAUTIONARY STATEMENTS: Keep this and all chemicals out of reach of children. SOLUBILITY IN WATER : Soluble IV - FIRE AND EXPLOSION HAZARD DATA NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of merchantability fitness or otherwise is made. FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Flash Point Non TCC SARA Title III Reporting Requirements SPECIAL FIRE FIGHTING PROCEDURES: None, however firefighters should always use self contained breathing apparatus as nitrogen oxides and carbon monoxides may be involved. UNUSUAL FIRE AND EXPLOSION HAZARDS: None V - REACTIVITY DATA CHEMICAL STABILITY UNSTABLE 302 (Extremely Hazardous Substances): Reporting not required. 304/CERCLA (Spills Notification): Not required. 311 Community Right-To-Know, RTK): Reporting not required. 312 (RTK Inventory Data): Not required. CONDITIONS TO AVOID: X STABLE INCOMPATIBILITY (Materials to avoid): Materials that react with water HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, ammonia, nitrogen oxides HAZARDOUS POLYMERIZATION MAY OCCUR CONDITIONS TO AVOID: WILL NOT OCCUR X VI - HEALTH HAZARD AREA ROUTE(S) OF ENTRY: EYES SKIN INGESTION 313 (Emissions and Releases): Reporting not required. DOT NOT HAZARDOUS INHALATION References EFFECTS OF OVER EXPOSURE: No evidence INHALATION: N/E TOXIC SUBSTANCE CONTROL CT LIST (TSCA) - INGREDIENTS LISTED SKIN CONTACT/ABSORPTION: N/E PERMISSIBLE EXPOSURE REFERENCES: Registry of Toxic Effects of Chemical Substances. INGESTION: N/E Title 29 Code of Federal Regulations. National Toxicology Program (NTP) Report on Carcinogens. EYES: N/E CARCINOGENICITY: NTP? Not listed IARC MONOGRAPHS? N/L OSHA REGULATED? II for exposure limits Title 40 Code of Federal Regulations EMERGENCY AND FIRST AID PROCEDURES: EYES AND SKIN: EYES - Wash with plenty of water for 15 minutes. GET IMMEDIATE MEDICAL ATTENTION. with running water and soap and water. INHALATION: Move to fresh air. If breathing difficult seek IMMEDIATE medical attention International Agency for Research on Cancer (IARC) Monographs. SKIN - Wash well REGULATORY STANDARDS: DOT Title 49 Code of Federal Regulations 172.101 SARA Title III INGESTION: DO NOT INDUCE VOMITING. Vomiting may cause pulmonary edema which may be fatal. GET IMMEDIATE MEDICAL ATTENTION. Nuclear Regulatory Commission CALL POISON CONTROL CENTER - contains sulfite and caustic. 1 SAFETY DATA SHEET LEAK DETECTOR SPRAY Page 1 Issued: 08/06/2005 Revision No: 2 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING Product name: LEAK DETECTOR SPRAY Product code: 32030 Company name: ROCOL Lubricants ROCOL House Swillington Leeds West Yorkshire LS26 8BS ENGLAND Tel: +44 (0) 113 232 2700 Fax: +44 (0) 113 232 2740 Emergency tel: +44 (0) 113 232 2600 2. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous ingredients: AMIDE DERIVATIVE 1-5% [Xi] R36/38 3. HAZARDS IDENTIFICATION Main hazards: None 4. FIRST AID MEASURES (SYMPTOMS) Skin contact: Eye contact: Ingestion: Inhalation: There may be mild irritation at the site of contact. There may be irritation and redness. There may be irritation of the throat. No symptoms. 4. FIRST AID MEASURES (ACTION) Skin contact: Eye contact: Ingestion: Inhalation: Wash immediately with plenty of soap and water. Bathe the eye with running water for 15 minutes. Consult a doctor. Wash out mouth with water. Do not induce vomiting. Consult a doctor. Remove casualty from exposure ensuring one's own safety whilst doing so. 5. FIRE-FIGHTING MEASURES Extinguishing media: Use water spray to cool containers. Protection of fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Refer to section 8 of SDS for personal protection details. Environmental precautions: Do not discharge into drains or rivers. Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. 7. HANDLING AND STORAGE Handling requirements: Ensure there is sufficient ventilation of the area. Storage conditions: Store in cool, well ventilated area. Keep away from sources of ignition. Keep away from direct sunlight. Suitable packaging: Must only be kept in original packaging. [cont...] Issued: 08/06/2005 SAFETY DATA SHEET LEAK DETECTOR SPRAY Page 2 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures: Respiratory protection: Hand protection: Eye protection: Skin protection: Ensure there is sufficient ventilation of the area. Respiratory protection not required. Protective gloves. Safety glasses with side-shields. Protective clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES State: Colour: Odour: Evaporation rate: Oxidising: Solubility in water: Viscosity: Boiling point/range°C: Melting point/range°C: Flash point°C: Autoflammability°C: Relative density: Aerosol Colourless Odourless Slow Non-oxidising (by EC criteria) Miscible in all proportions Non-viscous 100 0 > 200 >200 1 10. STABILITY AND REACTIVITY Stability: Conditions to avoid: Materials to avoid: Haz. decomp. products: Stable under normal conditions. Direct sunlight. Heat. Sources of ignition. Strong oxidising agents. Strong reducing agents. In combustion emits toxic fumes of carbon dioxide / carbon monoxide. 11. TOXICOLOGICAL INFORMATION Routes of exposure: Refer to section 4 of SDS for routes of exposure and corresponding symptoms. 12. ECOLOGICAL INFORMATION Mobility: Volatile. Readily absorbed into soil. Persistence and degradability: Biodegradable. Bioaccumulative potential: No bioaccumulation potential. 13. DISPOSAL CONSIDERATIONS Disposal of packaging: Dispose of in a regulated landfill site or other method for hazardous or toxic wastes. NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal. 14. TRANSPORT INFORMATION ADR / RID UN no: Classification code: Shipping name: Labelling: 1950 5A AEROSOLS 2.2 ADR Class: 2 [cont...] Issued: 08/06/2005 SAFETY DATA SHEET LEAK DETECTOR SPRAY Page 3 IMDG / IMO UN no: 1950 EmS: F-D,S-U Labelling: 2.2 Class: 2 Marine pollutant: . IATA / ICAO UN no: 1950 Labelling: 2.2 Class: 2 15. REGULATORY INFORMATION Hazard symbols: No significant hazard. Risk phrases: None Safety phrases: S16: Keep away from sources of ignition - No smoking. S23: Do not breathe spray. S51: Use only in well-ventilated areas. Precautionary phrases: Safety data sheet available for professional user on request. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Note: The regulatory information given above only indicates the principal regulations specifically applicable to the product described in the safety data sheet. The user's attention is drawn to the possible existence of additional provisions which complete these regulations. Refer to all applicable national, international and local regulations or provisions. 16. OTHER INFORMATION Other information: EC Directive 1999/45/EC relating to the classification, packaging and labelling of dangerous preparations. EC Directive 91/155/EEC defining the laying down and detailed arrangements for the system of specific information relating to dangerous preparations. EC Directive 94/1/EC adapting some technicalities of Council Directive 75/324/EEC on the approximation of the laws of Member States relating to aerosol dispensers. Risk phrases used in s.2: R36/38: Irritating to eyes and skin. Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product. [final page] U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET (Prepared According to 29 CFR 1910.1200) ______________________________________________________________________________ SECTION 1 IDENTIFICATION Product Name: NEUTRAZEN Natural Scents (Metered Cans) 491143 Black Cherry 491120 Country Garden 491375 Gingerbread 491275 Candy Cane 491605 Cranberry Spice 491855 Green Apple 491113 Cinnamon 491250 Dutch Apple 491163 Hawaiian Kiss 491505 Citrus Creme 491333 Fresh Linen 491705 Mango 491125 Citrus Peel 491525 Fruit Basket 491755 Orchard Spice Manufacturer's Name: Manufacturer's Address: Manufacturer's Phone Number: Emergency Phone Number: Proper Shipping Name: Effective Date: ZENEX International 7777 First Place, Cleveland Ohio 44146 (440) 232-4155 1-800-535-5053 Consumer Commodity, ORM-D 10-15-01 491805 Peach Kiwi 491955 Pina Colada 491025 Pine Forest 491905 Powder Fresh 491655 Tropical Nectar 491555 Vanilla Delight ______________________________________________________________ SECTION 2 IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS Chemical Name: Acetone Propane Isobutane n-Butane Fragrance CAS No.: 67-64-1 74-98-6 75-28-5 106-97-8 Not available TLV: 500ppm 2500ppm Not established 800ppm Not available ______________________________________________________________________________ SECTION 3 Boiling Point: Solubility in Water: Physical Description: PHYSICAL DATA <0 to 1330 F Slightly Clear Specific Gravity(H2O=1): Evaporation Rate: Vapor Density(Air=1): 0.80 + 0.05 Slower than Ether Heavier than air _______________________________________________________________________________________________________________________________________ SECTION 4 FIRE AND EXPLOSION HAZARD DATA Flash Point: Flammable Limits: Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: <0OF LEL: 1.8 UEL: 9.5 Use water fog, dry chemical or carbon dioxide. Aerosol cans may rupture when heated. Heated cans may burst. _______________________________________________________________________________________________________________________________________ SECTION 5 Unstable______ Stable __X___ Incompatability (Materials to Avoid): Conditions to Avoid: Hazardous Decomposition or Byproducts: Hazardous Polymerization: REACTIVITY DATA Stability: None known. High temperatures. In fire, will decompose to carbon dioxide, carbon monoxide Will not occur __________________________________________________________________________________________________________________________________________ SECTION 6 STORAGE AND HANDLING INFORMATION Precautions to be Taken in Handling and Storing: When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved respirator. STORE AT TEMPERATURES BELOW 120oF KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME KEEP AWAY FROM CHILDREN FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY FOR USE BY TRAINED PERSONNEL ONLY KEEP CONTAINER CLOSED DURING STORAGE __________________________________________________________________________________________________________________________________________ SECTION 7 HEALTH HAZARDS AND FIRST AID Effects of Overexposure: SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible. EYES: Eye irritant. Will cause redness and burning sensation. INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness, nausea, and loss of coordination.Extreme overexposure may result in unconsciousness and possibly death. INGESTION: Aspiration hazard if swallowed. First Aid Procedures: SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get medical attention. Remove contaminated clothing and launder before reuse. EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Seek medical attention. INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention. INGESTION: DO NOT induce vomiting. Seek medical attention immediately. Note: Never give anything by mouth to an unconscious or convulsing victim. Keep person warm and quiet. __________________________________________________________________________________________________________________________________________ SECTION 8 SPECIAL PROTECTION INFORMATION SECTION 9 SPILL OR LEAK PROCEDURE Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: Self-contained breathing apparatus if above TLV limit. Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit. None required if spraying. As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we recommend the use of safety glasses or chemical splash goggles. Other Protective Equipment: Long sleeves and long pants. Work/Hygienic Practices: Do not smoke while using. Wash hands after use. __________________________________________________________________________________________________________________________________________ Steps To Be Taken In Case Material Is Released or Spilled: Use absorbent sweeping compound to soak up material. Put into container. Dispose as hazardous waste. Waste Disposal Method: Dispose as hazardous waste in accordance with EPA RCRA. _________________________________________________________________________________________________________________________________________ SECTION 10 REGULATORY INFORMATION SARA Title III, Section 313 Components: None __________________________________________________________________________________________________________________________________________ This information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties, express or implied, and assume no liability in connection with any use of this information. 491143,491275,491113,491505,491125,491120,491605,491250,491333,491525,491375, 491855,491163, 491705,491755,491805, 491955, 491025, 491905, 491655, 491555 U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET (Prepared According to 29 CFR 1910.1200) ______________________________________________________________________________ SECTION 1 IDENTIFICATION Product Name: NEUTRAZEN Natural Scents (Metered Cans) 491143 Black Cherry 491120 Country Garden 491375 Gingerbread 491275 Candy Cane 491605 Cranberry Spice 491855 Green Apple 491113 Cinnamon 491250 Dutch Apple 491163 Hawaiian Kiss 491505 Citrus Creme 491333 Fresh Linen 491705 Mango 491125 Citrus Peel 491525 Fruit Basket 491755 Orchard Spice Manufacturer's Name: Manufacturer's Address: Manufacturer's Phone Number: Emergency Phone Number: Proper Shipping Name: Effective Date: ZENEX International 7777 First Place, Cleveland Ohio 44146 (440) 232-4155 1-800-535-5053 Consumer Commodity, ORM-D 10-15-01 491805 Peach Kiwi 491955 Pina Colada 491025 Pine Forest 491905 Powder Fresh 491655 Tropical Nectar 491555 Vanilla Delight ______________________________________________________________ SECTION 2 IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS Chemical Name: Acetone Propane Isobutane n-Butane Fragrance CAS No.: 67-64-1 74-98-6 75-28-5 106-97-8 Not available TLV: 500ppm 2500ppm Not established 800ppm Not available ______________________________________________________________________________ SECTION 3 Boiling Point: Solubility in Water: Physical Description: PHYSICAL DATA <0 to 1330 F Slightly Clear Specific Gravity(H2O=1): Evaporation Rate: Vapor Density(Air=1): 0.80 + 0.05 Slower than Ether Heavier than air _______________________________________________________________________________________________________________________________________ SECTION 4 FIRE AND EXPLOSION HAZARD DATA Flash Point: Flammable Limits: Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: <0OF LEL: 1.8 UEL: 9.5 Use water fog, dry chemical or carbon dioxide. Aerosol cans may rupture when heated. Heated cans may burst. _______________________________________________________________________________________________________________________________________ SECTION 5 Unstable______ Stable __X___ Incompatability (Materials to Avoid): Conditions to Avoid: Hazardous Decomposition or Byproducts: Hazardous Polymerization: REACTIVITY DATA Stability: None known. High temperatures. In fire, will decompose to carbon dioxide, carbon monoxide Will not occur __________________________________________________________________________________________________________________________________________ SECTION 6 STORAGE AND HANDLING INFORMATION Precautions to be Taken in Handling and Storing: When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved respirator. STORE AT TEMPERATURES BELOW 120oF KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME KEEP AWAY FROM CHILDREN FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY FOR USE BY TRAINED PERSONNEL ONLY KEEP CONTAINER CLOSED DURING STORAGE __________________________________________________________________________________________________________________________________________ SECTION 7 HEALTH HAZARDS AND FIRST AID Effects of Overexposure: SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible. EYES: Eye irritant. Will cause redness and burning sensation. INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness, nausea, and loss of coordination.Extreme overexposure may result in unconsciousness and possibly death. INGESTION: Aspiration hazard if swallowed. First Aid Procedures: SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get medical attention. Remove contaminated clothing and launder before reuse. EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Seek medical attention. INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention. INGESTION: DO NOT induce vomiting. Seek medical attention immediately. Note: Never give anything by mouth to an unconscious or convulsing victim. Keep person warm and quiet. __________________________________________________________________________________________________________________________________________ SECTION 8 SPECIAL PROTECTION INFORMATION SECTION 9 SPILL OR LEAK PROCEDURE Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: Self-contained breathing apparatus if above TLV limit. Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit. None required if spraying. As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we recommend the use of safety glasses or chemical splash goggles. Other Protective Equipment: Long sleeves and long pants. Work/Hygienic Practices: Do not smoke while using. Wash hands after use. __________________________________________________________________________________________________________________________________________ Steps To Be Taken In Case Material Is Released or Spilled: Use absorbent sweeping compound to soak up material. Put into container. Dispose as hazardous waste. Waste Disposal Method: Dispose as hazardous waste in accordance with EPA RCRA. _________________________________________________________________________________________________________________________________________ SECTION 10 REGULATORY INFORMATION SARA Title III, Section 313 Components: None __________________________________________________________________________________________________________________________________________ This information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties, express or implied, and assume no liability in connection with any use of this information. 491143,491275,491113,491505,491125,491120,491605,491250,491333,491525,491375, 491855,491163, 491705,491755,491805, 491955, 491025, 491905, 491655, 491555 U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET (Prepared According to 29 CFR 1910.1200) ______________________________________________________________________________ SECTION 1 IDENTIFICATION Product Name: NEUTRAZEN Natural Scents 491153 Cinnamon 491105 Citrus Creme 491325 Citrus Peel 491235 Cranberry Spice 491123 Fresh Linen Manufacturer's Name: Manufacturer's Address: Manufacturer's Phone Number: Emergency Phone Number: Proper Shipping Name: Effective Date: (Hand Held Cans) 491075 Fruit Basket 491255 Green Apple 491455 Mango 491155 Orchard Spice 491405 Peach Kiwi 491355 Pina Colada 491305 Powder Fresh 491055 Tropical Nectar 491205 Vanilla Delight ZENEX International 7777 First Place, Cleveland Ohio 44146 (440) 232-4155 1-800-535-5053 Consumer Commodity, ORM-D 10-15-01 ______________________________________________________________________________ SECTION 2 IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS Chemical Name: Dimethyl Ketal Isobutane Propane Butane Fragrance CAS No.: 67-64-1 75-28-5 74-98-6 106-97-8 Not available TLV: 500ppm Not established 2500ppm 800ppm Not available ______________________________________________________________________________ SECTION 3 Boiling Point: Solubility in Water: Physical Description: PHYSICAL DATA <0 to 1330 F Slightly Clear Specific Gravity(H2O=1): Evaporation Rate: Vapor Density(Air=1): 0.80 + 0.05 Slower than Ether Heavier than air _______________________________________________________________________________________________________________________________________ SECTION 4 FIRE AND EXPLOSION HAZARD DATA Flash Point: Flammable Limits: Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: <0OF LEL: 1.8 UEL: 9.5 Use water fog, dry chemical or carbon dioxide. Aerosol cans may rupture when heated. Heated cans may burst. _______________________________________________________________________________________________________________________________________ SECTION 5 Unstable______ Stable __X___ Incompatability (Materials to Avoid): Conditions to Avoid: Hazardous Decomposition or Byproducts: Hazardous Polymerization: REACTIVITY DATA Stability: None known. High temperatures. In fire, will decompose to carbon dioxide, carbon monoxide Will not occur __________________________________________________________________________________________________________________________________________ SECTION 6 STORAGE AND HANDLING INFORMATION Precautions to be Taken in Handling and Storing: When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved respirator. STORE AT TEMPERATURES BELOW 120oF KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME KEEP AWAY FROM CHILDREN FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY FOR USE BY TRAINED PERSONNEL ONLY KEEP CONTAINER CLOSED DURING STORAGE __________________________________________________________________________________________________________________________________________ SECTION 7 HEALTH HAZARDS AND FIRST AID Effects of Overexposure: SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible. EYES: Eye irritant. Will cause redness and burning sensation. INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness, nausea, and loss of coordination.Extreme overexposure may result in unconsciousness and possibly death. INGESTION: Aspiration hazard if swallowed. First Aid Procedures: SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get medical attention. Remove contaminated clothing and launder before reuse. EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Seek medical attention. INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention. INGESTION: DO NOT induce vomiting. Seek medical attention immediately. Note: Never give anything by mouth to an unconscious or convulsing victim. Keep person warm and quiet. __________________________________________________________________________________________________________________________________________ SECTION 8 SPECIAL PROTECTION INFORMATION SECTION 9 SPILL OR LEAK PROCEDURE Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: Self-contained breathing apparatus if above TLV limit. Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit. None required if spraying. As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we recommend the use of safety glasses or chemical splash goggles. Other Protective Equipment: Long sleeves and long pants. Work/Hygienic Practices: Do not smoke while using. Wash hands after use. __________________________________________________________________________________________________________________________________________ Steps To Be Taken In Case Material Is Released or Spilled: Use absorbent sweeping compound to soak up material. Put into container. Dispose as hazardous waste. Waste Disposal Method: Dispose as hazardous waste in accordance with EPA RCRA. _________________________________________________________________________________________________________________________________________ SECTION 10 REGULATORY INFORMATION SARA Title III, Section 313 Components: None __________________________________________________________________________________________________________________________________________ This information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties, express or implied, and assume no liability in connection with any use of this information. 491153,491105,491325,491235,491123,491075,491255,491455,491155,491405,491355,491305,491055, 491205 U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET (Prepared According to 29 CFR 1910.1200) ______________________________________________________________________________ SECTION 1 IDENTIFICATION Product Name: NEUTRAZEN Natural Scents 491153 Cinnamon 491105 Citrus Creme 491325 Citrus Peel 491235 Cranberry Spice 491123 Fresh Linen Manufacturer's Name: Manufacturer's Address: Manufacturer's Phone Number: Emergency Phone Number: Proper Shipping Name: Effective Date: (Hand Held Cans) 491075 Fruit Basket 491255 Green Apple 491455 Mango 491155 Orchard Spice 491405 Peach Kiwi 491355 Pina Colada 491305 Powder Fresh 491055 Tropical Nectar 491205 Vanilla Delight ZENEX International 7777 First Place, Cleveland Ohio 44146 (440) 232-4155 1-800-535-5053 Consumer Commodity, ORM-D 10-15-01 ______________________________________________________________________________ SECTION 2 IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS Chemical Name: Dimethyl Ketal Isobutane Propane Butane Fragrance CAS No.: 67-64-1 75-28-5 74-98-6 106-97-8 Not available TLV: 500ppm Not established 2500ppm 800ppm Not available ______________________________________________________________________________ SECTION 3 Boiling Point: Solubility in Water: Physical Description: PHYSICAL DATA <0 to 1330 F Slightly Clear Specific Gravity(H2O=1): Evaporation Rate: Vapor Density(Air=1): 0.80 + 0.05 Slower than Ether Heavier than air _______________________________________________________________________________________________________________________________________ SECTION 4 FIRE AND EXPLOSION HAZARD DATA Flash Point: Flammable Limits: Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: <0OF LEL: 1.8 UEL: 9.5 Use water fog, dry chemical or carbon dioxide. Aerosol cans may rupture when heated. Heated cans may burst. _______________________________________________________________________________________________________________________________________ SECTION 5 Unstable______ Stable __X___ Incompatability (Materials to Avoid): Conditions to Avoid: Hazardous Decomposition or Byproducts: Hazardous Polymerization: REACTIVITY DATA Stability: None known. High temperatures. In fire, will decompose to carbon dioxide, carbon monoxide Will not occur __________________________________________________________________________________________________________________________________________ SECTION 6 STORAGE AND HANDLING INFORMATION Precautions to be Taken in Handling and Storing: When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved respirator. STORE AT TEMPERATURES BELOW 120oF KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME KEEP AWAY FROM CHILDREN FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY FOR USE BY TRAINED PERSONNEL ONLY KEEP CONTAINER CLOSED DURING STORAGE __________________________________________________________________________________________________________________________________________ SECTION 7 HEALTH HAZARDS AND FIRST AID Effects of Overexposure: SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible. EYES: Eye irritant. Will cause redness and burning sensation. INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness, nausea, and loss of coordination.Extreme overexposure may result in unconsciousness and possibly death. INGESTION: Aspiration hazard if swallowed. First Aid Procedures: SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get medical attention. Remove contaminated clothing and launder before reuse. EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Seek medical attention. INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention. INGESTION: DO NOT induce vomiting. Seek medical attention immediately. Note: Never give anything by mouth to an unconscious or convulsing victim. Keep person warm and quiet. __________________________________________________________________________________________________________________________________________ SECTION 8 SPECIAL PROTECTION INFORMATION SECTION 9 SPILL OR LEAK PROCEDURE Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: Self-contained breathing apparatus if above TLV limit. Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit. None required if spraying. As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we recommend the use of safety glasses or chemical splash goggles. Other Protective Equipment: Long sleeves and long pants. Work/Hygienic Practices: Do not smoke while using. Wash hands after use. __________________________________________________________________________________________________________________________________________ Steps To Be Taken In Case Material Is Released or Spilled: Use absorbent sweeping compound to soak up material. Put into container. Dispose as hazardous waste. Waste Disposal Method: Dispose as hazardous waste in accordance with EPA RCRA. _________________________________________________________________________________________________________________________________________ SECTION 10 REGULATORY INFORMATION SARA Title III, Section 313 Components: None __________________________________________________________________________________________________________________________________________ This information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties, express or implied, and assume no liability in connection with any use of this information. 491153,491105,491325,491235,491123,491075,491255,491455,491155,491405,491355,491305,491055, 491205 Date: Supercedes: 15 October 2007 15 November 2004 MATERIAL SAFETY DATA SHEET IN CASE OF EMERGENCY CALL CHEMTREC AT 1-800-424-9300 1. 2. PRODUCT IDENTIFICATION AND COMPANY IDENTIFICATION: Product Name: GOJO® PINK CONCENTRATE HAND SOAP Company Name & Address: GOJO Industries, Inc. One GOJO Plaza, Suite 500 Akron, OH 44311 Emergency Phone: Non-Emergency Phone: MSDS Request Phone: 1-800-424-9300 CHEMTREC (330) 255-6000 (330) 255-6000 x8804 INFORMATION ON INGREDIENTS: HAZARDOUS INGREDIENTS Ammonium Chloride as dust CAS NUMBER 12125-02-9 Not established Other ingredient(s) with notification requirements: Sodium Lauryl Sulfate Ammonium Chloride 3. OSHA PEL ACGIH TLV TWA: 10 mg/m CAS NUMBER List 151-21-3 CN 1 12125-02-9 % RANGE 3 <3 MA 1; NJ 1;PA 1; CN 1 HAZARDS IDENTIFICATION: EMERGENCY OVERVIEW When used according to instructions, the product applicable to this MSDS is safe and presents no immediate or long-term health hazard. However, abnormal entry routes, such as gross ingestion, may require immediate medical attention. Potential Health Effects: 4. HMIS: Health 1 Flammability 0 Reactivity 0 Personal Protection None Eye Contact: Skin Contact: Inhalation: Ingestion: Carcinogenicity: May cause eye irritation. No irritation or reaction expected. Not applicable. May cause upset stomach, nausea (Abnormal entry route). Not listed as a carcinogen by NTP, IARC, OSHA or ACGIH. FIRST AID MEASURES: Eye Contact: Skin Contact: Inhalation: Ingestion: Do not rub eyes. Flush eyes thoroughly with water for 15 minutes. If condition worsens or irritation persists, contact physician. Not applicable. Not applicable. Do not induce vomiting. Contact a physician or Poison Control Center. GOJO® PINK CONCETRATE HAND SOAP 5. Page 2 of 2 FIRE FIGHTING MEASURES: NFPA: Health 0 Fire Flashpoint °F/°C (PMCC method): Not determined. Unusual Fire and Explosion Hazards: None known. Special Fire Fighting Procedures: None known. Extinguishing Media: X Water Fog X Alcohol Foam 6. 0 Reactivity X CO2 X 0 Dry Chemical Other ACCIDENTAL RELEASE MEASURES: No special requirements. Water clean up and rinse. CAUTION – WILL CAUSE SLIPPERY SURFACES. 7. HANDLING AND STORAGE: Store at normal room temperature away from reach of small children. Keep containers sealed. Use older containers first. Avoid freezing conditions. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION: Eye Protection: Skin Protection: Respiratory Protection: Ventilation: Protective Equipment or Clothing: 9. PHYSICAL AND CHEMICAL PROPERTIES: Appearance and Odor pH (undiluted): VOC , %: 10. None required under normal conditions. None required under normal conditions. None required under normal conditions. None required under normal conditions. None required under normal conditions. Pink pearlescent liquid, coconut fragrance 4.5 – 9.5 0 STABILITY AND REACTIVITY: Stable/Non reactive product. 11. TOXICOLOGICAL INFORMATION: No acute or chronic toxic effects expected when used according to directions. 12. ECOLOGICAL CONSIDERATIONS: No ecological or special considerations when used according to directions. Not considered environmentally harmful from normal dilution, expected usage and typical drainage to sewers, septic systems and treatment plants. 13. DISPOSAL CONSIDERATIONS: No special considerations when disposed according to local, state and Federal regulations. 14. TRANSPORT INFORMATION: Not classified as a hazardous material. 15. REGULATORY AND OTHER INFORMATION: TSCA: All ingredients are listed or exempt per reference 15 USC 2602 (2)(B)(iv). Complies with current FDA regulations for cosmetic and/or over-the-counter drug products. Notice: The information herein is based on data considered to be accurate as of the date of preparation of this material safety data sheet. However, no warranty or representation, expressed or implied, is made as to the accuracy or completeness of the foregoing data and safety information. The user assumes all liability for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices or from any hazards inherent in the nature of the product. Document#: 9400-500 Page 1 of 4 The Procter & Gamble Company P&G Household Care Fabric & Home Care Innovation Center 5299 Spring Grove Avenue Cincinnati, OH 45217-1087 MATERIAL SAFETY DATA SHEET MSDS #: Supersedes: FH/H/2003/TWTA-5HRJZ8 MSDS issued March 4, 2004 Issue Date: May 9, 2006 Issue Date: Not Applicable SECTION I - CHEMICAL PRODUCT Identity: Mr Clean Magic Eraser Original, Duo, Extra Strength Finished Product Brands: MR CLEAN Magic Eraser P&G Telephone Number: 1-800-248-1612 or call your Poison Control Center or your physician SECTION II - COMPOSITION AND INGREDIENTS Mr. Clean Magic Eraser is a melamine foam with cleaning agents. Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200. Common CAS No. Composition Range Chemical Name Name (Wet Chemistry None LD50/LC50 SECTION III - HAZARDS IDENTIFICATION Potential Health Hazards (Acute and Chronic): (See Section 11 for more information) Ingestion: Blockage of the gastrointestinal tract may occur if swallowed. Do not ingest Eye Contact: Irritating to eye Skin Contact: Irritating to skin Inhalation: Ensure adequate ventilation Signs and Symptoms of Exposure: Ingestion: May caust irritation and/or bloacage of the gastroinstestinal track. Eye Contact: Dust from foam may cause mechanical irritation. Skin Contact: Dust from foam may cause mechanical irritation. Inhalation: Dust from foam may cause irritation of the respiratory track. Medical Conditions Generally Known to be Aggravated by Exposure: Potential Environmental Effects: (See Section 12 for more information) SECTION IV – FIRST AID INFORMATION First Aid Procedures: Ingestion: If foam is ingested, contact a physician or veterinarian immediately. Intestinal blockage may be life threatening to some household pets. Eye Contact: In case of eye irritation, flush thoroughly with water for 15 minutes. If irritation persisits, seek medical advice. Skin Contact: In case of skin irritation, flush affected area thoroughly with water and apply a cold compress. If irritation persists, seek medical advise. Remove any contaminated clothing. Inhalation:If respiratioy irritation occurs, moving from the site of exposure to an area with fresh air. If irritation perists, seek medical advise. Note to Physician: (if applicable): Treat symptomatically. Other: Consumer product package has the following precautionary statement: “Caution: keep out of reach of children. Keep out of reach of toddlers and pets to avoid accidental ingestion. Do not use on skin or other parts of the body. Using on skin will likely cause abrasions.” Mr Clean Magic Eraser Plus Foaming Cleaner Page 2 of 4 SECTION V - FIRE FIGHTING INFORMATION Flammable Properties: 580 C/ 1076F Extinguishing Media: Suitable: Regular dry chemical, carbon dioxide, water, regular foam. For large fires: use regulary foam of flood with fine water spray. Unsuitable: NA Protection of Firefighters: Specific Hazards Arising from the Material: Dust / air mixture may cause explosion. Protective Equipment and Precautions for Firefighters: SECTION VI - ACCIDENTAL RELEASE MEASURES Personal Precautions: None Known Environmental Precautions: Disposal is to be performed in compliance with all Federal, State, Provincial and Local Regulations. Methods for Containment: Collect spilled material in an approporate container for disposal. Methods for Cleanup: Keep out of water supplies and sewers. Other Information: (if applicable) Keep unnecessary people away, isolate hazard and deny entry to area. SECTION VII – HANDLING AND STORAGE Precautions To Be Taken in Handling: None known. Precautions To Be Taken in Storage:: None known. SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION Exposure Guidelines: Engineering Controls: Provide local ventilation Personal Protective Equipment (PPE): Under conditions of frequent use or heavy exposure, respiratory protection may be needed. (Any chemical cartridge respirator with an organic vapor cartridge(s), dust and mist filter(s)). Eye/Face Protection: Provide an emergenacy eye wash fountain and quick drench shower in the immediate work area. Skin Protection: Do not rub on skin, foam can cause abrasion to skin. SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES Appearance (color, physical form, shape): Flash Point (Method Used): NK White and Yellow foam Odor: None Explosive Limits: LEL: Odor Threshold: Not applicable Auto-Ignition Temperature: NK Physical State: foam Decomposition Temperature: NK Vapor Pressure (mm Hg): NK Evaporation Rate (nBuOAc=1): NK Vapor Density (Air=1): NA Specific Gravity/Density: NK Boiling Point: NA Melting/Freezing Point: NK Partition Coefficient (n-octanol/water): NA pH: Not applicable Solubility in Water: Yes Reserve Alkalinity: Not applicable UEL: 2 Mr Clean Magic Eraser Plus Foaming Cleaner Page 3 of 4 SECTION X - STABILITY AND REACTIVITY Chemical Stability: Stable at normal temperatures and pressures Conditions to Avoid: Avoid heat, flames, sparks, and other sources of ignition. Avoid contact with incompatable materials. Incompatible Materials: Oxizidizing materials Hazardous Decomposition Products: Oxides of carbon, oxides of sulfur, aromatic compounds, formaldehyde, hydrogen cyanide. Possibility of Hazardous Reactions: None known SECTION XI - TOXICOLOGICAL INFORMATION Do not use on skin or other parts of the body. Using on skin will likely cause abrasions. Chronic Effects: No chronic health effects reported. Target Organs: No target organs reported. Carcinogenicity: NTP: No IARC: No OSHA: No SECTION XII - ECOLOGICAL INFORMATION Not available. SECTION XIII - DISPOSAL CONSIDERATIONS Waste Disposal Method: Industrial Setting: Products covered by this MSDS, in their original form, when disposed as waste, are considered non hazardous waste according to Federal RCRA regulations (40 CFR 261). Disposal should be in accordance with local, state/provincial and federal regulations. Household Use: Product used in household may be disposed of in refuse. SECTION XIV - TRANSPORT INFORMATION Ground Transport (US DOT): Not Regulated Air Transport (IATA): Not Regulated Marine/Water Transport (IMDG): Not Regulated SECTION XV - ADDITIONAL REGULATORY INFORMATION While this finished product is not considered hazardous as defined by OSHA in 29 CFR 1910.1200 (d), this MSDS contains valuable information critical to the safe handling and proper use of the product. All intentionally-added components of this product are listed on the US TSCA Inventory. EPA Reg. No: Not applicable This product is not subject to warning labeling under California Proposition 65. Canada All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and this MSDS contains all information required by the Controlled Products Regulations. 3 Mr Clean Magic Eraser Plus Foaming Cleaner P&G Hazard Rating: *N/A. - Not Applicable Page 4 of 4 SECTION XVI - OTHER INFORMATION Health: 1 4=EXTREME Flammability: 1 3=HIGH Reactivity: 0 2=MODERATE 1=SLIGHT 0=NOT SIGNIFICANT *N/K. - Not Known Data supplied is for use only in connection with occupational safety and health. The information contained herein has been compiled from sources considered by Procter & Gamble to be dependable and is accurate to the best of the Company’s knowledge. The information relates to the specific material designated herein, and does not relate to the use in combination with any other material or any other process. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, for any damage to any property resulting from misuse of the controlled product. 4 PRO-LINK MATERIAL SAFETY DATA SHEET PRO-LINK 510 CHAPMAN STREET CANTON, MA 02021 Data Sheet No. Issue Date 5/7/99 Issued By J. Irwin PH: 781-828-9550 FX: 781-828-9551 SECTION 1 Trade Name/Synonyms 1401 Urinal Screen - Red/Cherry Chemical Name/Synonyms Chemical Family/Formula SECTION 2 - Product/Component Data Component(s) Chemical Name Di (2-Ethylhexy 1) Phthalate CAS Registry 117-81-7 % Approx. OSHA/PEL <45.0 ACGIH TLV-TWA 5mg/m# 5mg/m3 SECTION 3 - Physical Data Boiling Point (F) Data Not Available Data Not Available Vapor Pressure (mm Hg) Vapor Density (Air = 1) N/A Appearance and Odor 1.39 %, Volatile by Volume Evaporation Rate (_ = 1) N/A Solubility in Water Specific Gravity (H O = 1) Melting Point N/A 330 F Pellet, slight odor SECTION 4 - Fire & Explosion Hazard Data Flash Point (Method Used) Flammable Limits N/A LEL UCL N/A N/A Extinguishing Media Water is most effective. ABC dry chemical, APPP and protein type air foam Special Fire Fighting Procedures self-contained breathing apparatus and turnout equipment should be worn Unusual Fire & Explosion Hazards NFPA Codes: None under normal processing conditions Flammability: Health: NE = Not Established NA = Not Applicable Reactivity: SECTION 5 - Health Hazard Data Route(s) of Entry Inhalation: Yes (as fumes) Skin: No Ingestion: Yes Effects of Overexposure Health Hazards: Contains hazardous chemicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right To Know Act of 1986. Fumes produced during normal hot melt processing may cause irritation to the eyes, respiratory tract or skin of employees who may be sensitive to these fumes. Emergency/First Aid Procedures Thoroughly wash skin with soap and water. If affected by fumes, remove to fresh air. If swallowed, induce vomiting by means of finger in throat, salt water, or syrup of Ipecak. Call physician. SECTION 6 - Reactivity Data Stability __Stable __Unstable X Incompatibility (Materials to Avoid) Conditions to Avoid Avoid prolonged/excessive heating; 1 hr. at 350 F 10 mins.; at 400 F and 5 mins. at 450 F. Oxidizing agents Hazardous Decomposition Products Hydrogen chloride, carbon monoxide and carbon dioxide Conditions to Avoid Hazardous Polymerization ___May Occur ___Will Not Occur X None during normal use SECTION 7 - Spill or Leak Procedures Steps To Be Taken In Case Material is Released/Spilled Normal housekeeping procedures Waste Disposal Method Do not incinerate. Dispose of waste in a licensed landfill in accordance with federal, state, and local regulations. SECTION 8 - Special Protection Information Respiratory Protection (Specify Type) Ventilation Not under normal processing conditions using adequate ventilation. Special N/A Local Exhaust As needed to remove fumes. Mechanical (General) As needed to remove fumes. Other N/A Protective Gloves Heat impervious gloves to handle hot melt Eye Protection Safety glasses in all industrial workplaces Other Protective Equipment Not normally required. SECTION 9 - Special Precautions Precautions To Be Taken In Handling and Storing None - Always practice good housekeeping and hygienic measures. This information is given in good faith but no warranty, expressed or implied, is made. Impact Products, Inc. believes that it is accurate to the best of its knowledge and relates only to the specific material designated herein. MATERIAL SAFETY DATA SHEET HMIS HAZARD RATINGS OSHA - Meets 29 CFR 1910.1200 Standards HEALTH FLAMMABILITY REACTIVITY 3 = HIGH 4 = EXTREME 0 = INSIGNIFICANT 1 = SLIGHT 2 = MODERATE 2 2 0 TRANSPORTATION INFORMATION PROPER SHIPPING NAME: Environmentally hazardous substance, solid, n.o.s. (pdichlorobenzene) HAZARD CLASS / PKG GRP: IDENTIFICATION NUMBER: 9 / III UN 3077 REF: LABEL: 49 CFR 173.155, .213, .240 Miscellaneous SECTION 1 - PRODUCT / COMPANY IDENTIFICATION IDENTITY (AS USED ON LABEL AND LIST) PARADICHLOROBENZENE BLOCKS MANUFACTURER'S NAME Hospital Specialty Company ADDRESS (NUMBER, STREET, P.O. BOX) 670 Alpha Drive (CITY, STATE AND ZIP CODE) Highland Heights, OH 44143 ( 08161, 08241, 08411, 06301, 06311, 06931, 06401, Page 1 of 2 06411, 06901, 01931, 01991 ) EMERGENCY TELEPHONE NUMBER CHEM • TEL (800) 255-3924 Outside USA (813) 248-0585 TELEPHONE NUMBER FOR INFORMATION (440) 720-1800 DATE PREPARED: April 21, 2005 SUPERSEDES: December 15, 2001; March 18, 2002 SECTION 2 - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION HAZARDOUS COMPONENTS (SPECIFIC CHEMICAL IDENTITY; COMMON NAME(S)) CAS # p-Dichlorobenzene (a,b,c,d,e,f) 106-46-7 % (OPTIONAL) 60 - 100 OSHA PEL PPM 75 MG/M3 ACGIH TWA PPM 450 10 MG/M3 SARA RQ TITLE III LBS Yes 100 (a) Indicates a toxic chemical subject to annual reporting requirements of Section 313 of SARA Title III of the Emergency Planning and Community Right-ToKnow Act of 1986 and of 40 CFR 372. (b) Indicates that the Resource Conservation and Recovery Act (RCRA) has determined the waste for this chemical is listed as hazardous and must be handled according to regulations in 40 CFR 260-281. (c) The Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) has notification requirements for releases or spills to the environment of the Reportable Quantity (RQ for this mixture = 100 lbs) or greater amounts, according to 40 CFR 302. (d) Indicates substance appears on National Toxicology Program (NTP) list of carcinogens, International Agency for Research on Cancer (IARC) list of carcinogens or is regulated by the Occupational Safety and Health Administration (OSHA) as a possible carcinogen. (e) California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986, chemicals known to the state to cause cancer or reproductive toxicity. A person in the course of doing business must warn others who may consume, come into contact with, or otherwise be exposed to this chemical. (f) Product is listed or defined as a marine pollutant in IMDG Code or 49 CFR 172.101 Appendix B, List of Marine Pollutants and must be classified as an Environmentally Hazardous Substance, Class 9, in addition to any other defined hazards for this product. SECTION 3 - HEALTH HAZARD DATA ROUTES OF ENTRY - SIGNS AND SYMPTOMS OF EXPOSURE EMERGENCY AND FIRST AID PROCEDURES INHALATION: Inhalation of dust or vapors may irritate the respiratory tract; may cause headache, dizziness, nausea, vomiting, weight loss and liver and kidney damage. May also cause swelling around the eyes and runny nose. Remove affected person to fresh air; provide oxygen if breathing is difficult; if affected person is not breathing, administer CPR and seek emergency medical attention. SKIN: Causes skin irritation, with a slight burning sensation. Red blotching of the skin due to allergic reactions may occur. May be absorbed through the skin; symptoms may parallel inhalation. Remove contaminated clothing; wash affected area with soap and water; launder contaminated clothing before reuse; if irritation persists, seek medical attention. EYES: Contact causes severe irritation and pain associated with redness and swelling of the conjunctiva. Remove contact lenses. Flush eyes with clear running water for 15 minutes while holding eyelids open; if irritation persists, seek medical attention. INGESTION: Material is toxic; may cause headache, dizziness,; may cause headache, dizziness, diarrhea and general weakness; swallowing can produce adverse health effects paralleling inhalation. Give two glasses of water for dilution; Induce vomiting by sticking fingers down throat; never give anything by mouth to an unconscious person; seek medical attention. IARC MONOGRAPHS? OSHA REGULATED? CARCINOGENICITY NTP? Yes Yes p-Dichlorobenzene is listed as an anticipated carcinogen by NTP and 2B possibly carcinogenic to humans by IARC. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Preexisting skin, eye, or respiratory disorders may become aggravated through prolonged exposure. No Form revised 09 / 01 MATERIAL SAFETY DATA SHEET IDENTITY (AS USED ON LABEL AND LIST) PARADICHLOROBENZENE BLOCKS ( 08161, 08241, 08411, 06301, 06311, 06931, 06401, 06411, 06901, 01931, 01991 ) Page 2 of 2 Date: March 18, 2002 SECTION 4 - FIRE FIGHTING MEASURES FLASH POINT (METHOD USED) 151º F (66º C) CC NFPA RATING IIA FLAMMABLE LIMITS LEL: 2.5% UEL: 16.0% EXTINGUISHING MEDIA Carbon dioxide, water, water fog, dry chemical, chemical foam SPECIAL FIRE FIGHTING PROCEDURES Airborne dusts may form explosive mixtures if allowed to concentrate in confined area. Contact with strong oxidizers may cause fire. UNUSUAL FIRE AND EXPLOSION HAZARDS In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. SECTION 5 - ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: COMBUSTIBLE. Evacuate and ventilate area; avoid breathing dust. Recover and segregate product for reuse; shovel product into approved container for disposal.; for spills in excess of allowable limits (RQ) notify the National Response Center (800) 424 - 8802; refer to CERCLA 40 CFR 302 and SARA Title III, Section 313 40 CFR 372 for detailed instructions concerning reporting requirements. Do not discharge into lakes, ponds, streams or public waters. P-Dichlorobenzene is listed as a Marine Pollutant. SECTION 6 - HANDLING AND STORAGE PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: This material is combustible. It should be stored in tightly closed containers in a cool, dry, well ventilated area. Vapor may form explosive mixtures in air. All sources of ignition should be controlled. Keep this and other chemicals out of reach of children. Avoid inhaling concentrated fumes or vapors. SECTION 7 - EXPOSURE CONTROLS / PERSONAL PROTECTION RESPIRATORY PROTECTION (SPECIFY TYPE): None required while threshold limits (Section 2) are kept below maximum allowable concentrations; if TWA exceeds limits, NIOSH approved respirator must be worn. Refer to 29 CFR 1910.134 or European Standard EN 149 for complete regulations. VENTILATION LOCAL EXHAUST: Required SPECIAL: To maintain minimum TWA and STEL levels. MECHANICAL (GENERAL): Yes OTHER: Engineering and work controls as required. PROTECTIVE GLOVES: Neoprene or rubber gloves with cuffs. EYE PROTECTION: Protective eyeglasses or chemical safety goggles. OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Coveralls, apron, or other equipment should be worn to minimize skin contact. WORK / HYGIENIC PRACTICES: Practice safe workplace habits. Minimize body contact with this, as well as all chemicals in general. SECTION 8 - PHYSICAL / CHEMICAL PROPERTIES BOILING POINT 345º F (174º C) VAPOR PRESSURE (MM Hg) 0.6 mm Hg @ 20° C VAPOR DENSITY (AIR = 1) 5.08 SOLUBILITY IN WATER Practically insoluble in water. APPEARANCE AND ODOR White / pink solid blocks, penetrating mothball odor SPECIFIC GRAVITY (WATER = 1) 1.500 pH Not determined EVAPORATION RATE (WATER = 1) Not applicable % VOLATILE (BY WEIGHT) 100% @ 70º F SECTION 9 - STABILITY AND REACTIVITY CONDITIONS TO AVOID: Extreme temperatures, open flames, avoid UNSTABLE: generating airborne dust STABLE: XXX INCOMPATIBILITY (MATERIALS TO AVOID): Oxidizing agents, aluminum and its alloys STABILITY HAZARDOUS DECOMPOSITION OR BYPRODUCTS: May produce carbon monoxide, carbon dioxide, hydrogen chloride and phosgene when heated to decomposition. HAZARDOUS POLYMERIZATION MAY OCCUR: WILL NOT OCCUR: XXX CONDITIONS TO AVOID: None SECTION 10 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: Dispose of in accordance with Local, State, and Federal Regulations. This product may produce concentrated hazardous vapors or fumes in a disposal container creating a dangerous environment. Refer to "40 CFR Protection of Environment Parts 260 - 299" for complete waste disposal regulations for ignitable materials. Consult your local, state, or Federal Environmental Protection Agency before disposing of any chemicals. Do not flush to sanitary sewer or waterway. The information contained herein is believed to be accurate but is not warranted to be so. Data and calculations are based on information furnished by the manufacturer of the product and manufacturers of the components of the product. Users are advised to confirm in advance of need that information is current, applicable and suited to the circumstances of use. Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Furthermore, vendor assumes no responsibility for injury caused by abnormal use of this material even if reasonable safety procedures are followed. Any questions regarding this product should be directed to the manufacturer of the product as described in Section 1. MSDS PREPARED BY: CDB, Inc., P.O. Box 5604, Lakeland, FL 33807 (863) 644 - 3298 www.compdatabase.com Date: Supercedes: 15 October 2007 15 November 2004 MATERIAL SAFETY DATA SHEET IN CASE OF EMERGENCY CALL CHEMTREC AT 1-800-424-9300 1. 2. PRODUCT IDENTIFICATION AND COMPANY IDENTIFICATION: Product Name: PURELL® HAND SANITIZER WITH ALOE Company Name & Address: GOJO Industries, Inc. One GOJO Plaza, Suite 500 Akron, OH 44311 Emergency Phone: Non-Emergency Phone: MSDS Request Phone: 1-800-424-9300 CHEMTREC (330) 255-6000 (330) 255-6000 x8804 INFORMATION ON INGREDIENTS: HAZARDOUS INGREDIENTS CAS NUMBER OSHA PEL ACGIH TLV % RANGE Ethyl Alcohol 64-17-5 1000 ppm 1000 ppm 62 Isopropanol 67-63-0 400 ppm 400 ppm <5 Other ingredient(s) with notification requirements: 3. CAS NUMBER List Ethyl Alcohol 64-17-5 MA 1; NJ 1S; PA 1; CN 2 Isopropanol 67-63-0 MA 1; NJ 1S; CN 1 HAZARDS IDENTIFICATION: EMERGENCY OVERVIEW When used according to instructions, the product applicable to this MSDS is safe and presents no immediate or long-term health hazard. However, abnormal entry routes, such as gross ingestion, may require immediate medical attention. Potential Health Effects: 4. HMIS: Health 1 Flammability 3 Reactivity 0 Personal Protection None Eye Contact: Skin Contact: Inhalation: Ingestion: Carcinogenicity: May cause eye irritation. No irritation or reaction expected. Not applicable. May cause upset stomach, nausea (Abnormal entry route). Not listed as a carcinogen by NTP, IARC, OSHA or ACGIH. FIRST AID MEASURES: Eye Contact: Skin Contact: Inhalation: Ingestion: Do not rub eyes. Flush eyes thoroughly with water for 15 minutes. If condition worsens or irritation persists, contact physician. Not applicable. Not applicable. Do not induce vomiting. Contact a physician or Poison Control Center. Purell is a trademark of Warner-Lambert Company LLC PURELL® HAND SANITIZER WITH ALOE 5. FIRE FIGHTING MEASURES: NFPA: Flashpoint °F/°C (PMCC method): Unusual Fire and Explosion Hazards: Special Fire Fighting Procedures: Extinguishing Media: X Water Fog 6. Page 2 of 2 Health 0 Fire 3 Reactivity 0 74°F/23°C Product is flammable due to alcohol content. None known. X Alcohol Foam X CO2 X Dry Chemical Other ACCIDENTAL RELEASE MEASURES: Avoid contact with ignition sources since product is flammable. Absorb onto inert material and dispose in appropriate manner. Water clean up and rinse. CAUTION – WILL CAUSE SLIPPERY SURFACES. 7. HANDLING AND STORAGE: Keep away from fire or flame. Store at normal room temperature away from reach of small children. Keep containers sealed. Use older containers first. Avoid freezing conditions. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION: Eye Protection: Skin Protection: Respiratory Protection: Ventilation: Protective Equipment or Clothing: 9. PHYSICAL AND CHEMICAL PROPERTIES: Appearance and Odor pH (undiluted): VOC , %: 10. None required under normal conditions. None required under normal conditions. None required under normal conditions. None required under normal conditions. None required under normal conditions. Clear green liquid, floral fragrance 4.5 – 9.5 65 STABILITY AND REACTIVITY: Stable/Non reactive product. Avoid ignition sources. 11. TOXICOLOGICAL INFORMATION: No acute or chronic toxic effects expected when used according to directions. 12. ECOLOGICAL CONSIDERATIONS: No ecological or special considerations when used according to directions. Not considered environmentally harmful from normal dilution, expected usage and typical drainage to sewers, septic systems and treatment plants. 13. DISPOSAL CONSIDERATIONS: Characteristic hazardous waste-flammable liquid. Dispose according to local, state and Federal regulations. 14. TRANSPORT INFORMATION: Hazardous by transport regulations. When transported by Ground and Rail, this product typically is shipped as Consumer Commodity ORM-D. When transported by air, this product is typically shipped as Consumer Commodity or Alcohols N.O.S. depending on package size. When transported by ocean, this product is typically shipped as Limited Quantities. Refer to current regulations for exact requirements. 15. REGULATORY AND OTHER INFORMATION: TSCA: All ingredients are listed or exempt per reference 15 USC 2602 (2)(B)(iv). Complies with current FDA regulations for cosmetic and/or over-the-counter drug products. Notice: The information herein is based on data considered to be accurate as of the date of preparation of this material safety data sheet. However, no warranty or representation, expressed or implied, is made as to the accuracy or completeness of the foregoing data and safety information. The user assumes all liability for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices or from any hazards inherent in the nature of the product. Document#: 9650-506 MATERIAL SAFETY DATA SHEET SECTION 1 – MATERIAL IDENTIFICATION AND USE MATERIAL NAME IDENTIFIER EZE-FLO - Fumeless Alkaline Liquid Drain Opener and Cleaner MANUFACTURERS NAME/ADDRESS CONTACTS Cantol Limited 199 Steelcase Road West Markham, ON L3R 2M4 Canutec (24 hours) (613) 996-6666 Web: www.cantol.com SECTION 2 – HAZARDOUS INGREDIENTS HAZARDOUS INGREDIENTS Potassium Hydroxide % CAS NUMBER 40-70 1310-58-3 LD50 OF MATERIAL (SPECIFY SPECIES AND ROUTE) 365 mg/kg, ORAL, RAT LC50 OF MATERIAL (SPECIFY SPECIES) NONE SECTION 3 – PHYSICAL DATA PHYSICAL STATE GAS LIQUID ODOUR AND APPEARANCE ODOUR THRESHOLD (PPM) Clear red liquid with no odour SOLID Not Applicable VAPOUR PRESSURE (mm Hg.) VAPOUR DENSITY (AIR=1) EVAPORATION RATE % VOLATILE (BY VOLUME) SOLUBILITY IN WATER (20°C) pH Practically Zero Not Available Not Applicable Complete BOILING POINT (°C) Not Applicable FREEZING POINT (°C) 133 (271°F) SPECIFIC GRAVITY 13.0 @ 1% Soln. 1.45 -29 (-20°F) COEFF. WATER OIL DIST. Not Available SECTION 4 – FIRE AND EXPLOSION DATA FLAMMABILITY YES IF YES, UNDER WHICH CONDITIONS? NO MEANS OF EXTINCTION Not Applicable SPECIAL PROCEDURES Wear protective clothing. Product is highly alkaline. Self-contained breathing apparatus should be worn in areas where stored. FLASHPOINT (C°) AND METHOD UPPER EXPLOSION LIMIT (% BY VOLUME) Not Applicable Not Applicable AUTO IGNITION TEMPERATURE (°C) EXPLOSION DATA Not Applicable TDG FLAMMABILITY CLASSIFICATION Not Applicable Not Applicable SENSITIVITY TO IMPACT RATE OF BURNING Not Available Not Available LOWER EXPLOSION LIMIT (% BY VOLUME) HAZARDOUS COMBUSTION PRODUCTS None EXPLOSIVE POWER SENSITIVITY TO STATIC DISCHARGE Not Available Not Available SECTION 5 – REACTIVITY DATA CHEMICAL STABILITY YES ✘ NO IF NO, UNDER WHICH CONDITIONS? COMPATIBILITY WITH OTHER SUBSTANCES YES NO IF NO, WHICH ONES? REACTIVITY, AND UNDER WHAT CONDITIONS HAZARDOUS DECOMPOSITION PRODUCTS Acids, aluminum, tin, zinc, combustible material, organohalogens, aldehydes. Reacts with aluminum, tin, zinc to generate hydrogen gas. Contact with water may generate heat. Reacts with food sugars to generate carbon monoxide. NONE EZE-FLO SECTION 6 – TOXICOLOGICAL PROPERTIES ROUTE OF ENTRY SKIN CONTACT ✘ SKIN ABSORPTION EYE CONTACT ✘ INHALATION ACUTE INHALATION CHRONIC INGESTION ✘ EFFECTS OF ACUTE EXPOSURE TO MATERIAL Corrosive to skin and eyes. Harmful if swallowed. EFFECTS OF CHRONIC EXPOSURE TO MATERIAL None Known LD 50 OF MATERIAL SPECIFY SPECIES AND ROUTE Not Available LC50 OF MATERIAL SPECIFY SPECIES EXPOSURE LIMIT OF MATERIAL Not Applicable SENSITIZING CAPABILITY OF MATERIAL CARCINOGENICITY OF MATERIAL Not Available IRRITANCY OF MATERIAL Causes severe burns to skin and eyes ACGIH TLV for Potassium Hydroxide 2mg/m3 REPRODUCTIVE EFFECTS OF MATERIAL None SYNERGESTIC MATERIALS None None Known SECTION 7 – PREVENTIVE MEASURES PERSONAL PROTECTIVE EQUIPMENT Gloves, eye protection GLOVES (SPECIFY) RESPIRATORY (SPECIFY) EYE (SPECIFY) Rubber, Neoprene, Plastic None Goggles FOOTWEAR (SPECIFY) CLOTHING (SPECIFY) OTHER (SPECIFY) None None None ENGINEERING CONTROLS (SPECIFY E.G. VENTILATION ENCLOSED PROCESS) None LEAK AND SPILL PROCEDURE Soak up spill with oil absorbant. Flush area with water. WASTE DISPOSAL Discard used absorbant in proper receptacle. Follow all government disposal regulations. Never add water to the container. Violent reaction can occur. Always add product slowly to water according to label directions. Wear gloves and goggles. Do not get in eyes, on skin or clothing. HANDLING PROCEDURES AND EQUIPMENT Keep container closed. Do not store near combustible materials. KEEP OUT OF THE REACH OF CHILDREN. STORAGE REQUIREMENTS SPECIAL SHIPPING INFORMATION LTD. QTY. SECTION 8 – FIRST AID MEASURES EYES: Immediately flush with plenty of water for at least 15 minutes. Seek prompt medical attention. SKIN: Flush with water immediately. Seek prompt medical attention. INGESTION: Do not induce vomiting. Drink large quantities of water. Call a physician. SOURCES USED Canadian Centre for Occupational Health and Safety, Vendor Material Safety Data Sheets ADDITIONAL INFORMATION For industrial and institutional use only. Read and follow all label directions and precautions. Do not mix with other chemicals. SECTION 9 – PREPARATION DATE OF THE MSDS PREPARED BY D1B, E Cantol WHMIS Group PHONE NUMBER (905) 475-6141 DATE February 1, 2007 Pumice Scouring Stick Item Number:100714 U.S. Department Of Labor Occupational Safety And Health Administration MATERIAL SAFETY DATA SHEET Required Under USDL Safety And Health Regulations (29 CFP 1910.1200 "Hazards Communication Standard") Section I Manufactured For: Gabriel First Corp. Emergency Telephone: 1-800-424-9300 Address: 233 W Commercial Street East Rochester, NY 14445 Chemical Name & Synonyms: Cleaning, Compound, Liquid Trade Name & Synonyms: Pumice Scouring Stick Prepared On: 6/30/2005 Section I - Hazardous Ingredients/Identity Information Section II - Product & Component Data Component(s)/ Chemical Names TLV PEL Pumice (Volcanic Glass) There is No Free Crystalline Silica Present CAS Registry No % Section III - Physical Data Boiling Point: N/A Specific Gravity (H 2O=1): N/A Melting Point: 2390° F Vapor Pressure: N/A Percent, Volatile By Volume (%): N/A Vapor Density (Air=1): N/A Evaporation Rate: N/A Solubility In Water: Not Soluble Appearance And Odor: Odorless Solid Section IV - Fire And Explosion Hazard Data Special Fire Fighting Procedures: None. Unusual Fire and Explosion Hazards: None Flash Point/Method Used: N/A Flammable Limits: N/A LEL: N/A UEL: N/A Extinguishing Media: N/A Section V - Health Hazard Data Route(s) of Entry: Inhalation? Yes Skin? No Ingestion: Yes Health Hazards (Acute and Chronic): Dry sawing or grinding may result in the release of dust particles which, acute, may cause irritation of eyes, nose or throat and chronic, may result in lung disease (Silicosis) if exposed for prolonged time. Carcinogenicity: NTP? IARC Monographs? OSHA Regulated? No No No Signs and Symptoms of Exposure: Irritation of eyes, nose and throat or shortness of breath. Medical Conditions Generally Aggravated by Exposure: Pre -existing lung disease such as Emphysema or Asthma. Emergency First Aid Procedures: Irrigate eyes generously with clean water for 15 minutes. If irritation persists call a physician. Section VI - Reactivity Data Stability Conditions To Avoid Stable None Materials To Avoid: None Hazardous Decomposition Products: None Hazardous Polymerization Conditions To Avoid Will Not Occur None Section VII - Spill Or Leak Procedures Steps To Be Taken In Case Material Is Released Or Spilled: Sweep up and properly dispose. Waste Disposal Method: Dispose as common waste. Precautions To Be Taken in Handling and Storing: None Other Precautions: Wear NIOSH approved respirator and tight fitting goggles. When dry sawing or grinding, or saw and grind when wet. Section VIII - Special Protection Information Control Measures (When Sawing or Grinding) Respiratory Protection (Type): NIOSH Approved Particulate Respirator Ventilation: Mechanical (General) in Confined Area Protective Gloves: When Required Eye Protection: Tight Fitting Goggles Other Protective Equipment: None Work/Hygienic Practices: N/A Section IX - Special Precautions Precautions To Be Taken In Handling And Storing: None This information is given in good faith, but no warranty expressed or implied is made. Our company believes that it is accurate to the best of its knowledge and relates only to the specific material designated herein. ORTHO® Home Defense® MAX™ Perimeter & Indoor Insect Killer RTU Pull'N Spray Page 1 of 4 MATERIAL SAFETY DATA SHEET DATE PREPARED:07/08/2004 MSDS No:7202 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: ORTHO® Home Defense® MAX™ Perimeter & Indoor Insect Killer RTU Pull'N Spray PRODUCT DESCRIPTION: Insecticide MANUFACTURER The ORTHO Group P.O. Box 190 Marysville, OH 43040 24 HR. EMERGENCY TELEPHONE NUMBERS CHEMTREC (U.S.): Emergency Phone: (800) 424-9300 1-800-225-2883 EPA REG. NO.: 239-2663D PN: 6061 2. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name Bifenthrin Other Ingredients Wt.% 0.05 99.95 CAS# 82657-04-3 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW IMMEDIATE CONCERNS: CAUSES MODERATE EYE IRRITATION AVOID CONTACT WITH EYES OR CLOTHING KEEP OUT OF REACH OF CHILDREN POTENTIAL HEALTH EFFECTS EYES: This substance may cause moderate eye irritation. See Toxicological Information, section 11. SKIN: This substance is not expected to cause skin irritation and is only slightly toxic if absorbed through the skin. See Toxicological Information, section 11. INGESTION: This substance is slightly toxic if swallowed. The degree of injury will depend on the amount absorbed from the gut. See Toxicological Information, Section 11. INHALATION: Overexposure to the spray mist may be irritating to the respiratory tract. If inhaled, this substance is considered practically non-toxic to internal organs. See Toxicological Information, section 11. 4. FIRST AID MEASURES EYES: Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eyes. Call a poison control center or doctor for treatment advice. SKIN: If on skin or clothing, take off contaminated clothing. Rinse skin immediately with plenty of water for 15 to 20 minutes. Call a poison control center or doctor for treatment advice. INGESTION: If swallowed, call a poison control center or doctor immediately for treatment advice. Have person sip glass of water if able to swallow. Do not induce vomiting unless told to by a poison control center or doctor. Never give anything by mouth to an unconscious person. INHALATION: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably by mouth-to-mouth, if possible. Call a poison control center or doctor for further treatment advice. file://K:\ORTHO%20MSDS\max.htm 7/8/2004 ORTHO® Home Defense® MAX™ Perimeter & Indoor Insect Killer RTU Pull'N Spray Page 2 of 4 COMMENTS: See product label for specific First Aid Measures. The above measures are the most conservative - Pesticide Registration (PR) Notice 2001-1, January 2, 2001, and would apply in the event a product label is not immediately available. 5. FIRE FIGHTING MEASURES FLASHPOINT AND METHOD: None EXTINGUISHING MEDIA: Use CO2, Dry Chemical or Foam extinguishing media. HAZARDOUS COMBUSTION PRODUCTS: Heating this material may generate carbon monoxide, carbon dioxide, hydrogen chloride and hydrogen fluoride. FIRE FIGHTING PROCEDURES: Products of combustion from fires involving this material may be toxic. Avoid breathing smoke and mists. Avoid personnel and equipment contact with fallout and runoff. Minimize the amount of water used for fire fighting. Do not enter any enclosed area without full protective equipment, including self-contained breathing equipment. Contain and isolate runoff and debris for proper disposal. Decontaminate personal protective equipment and fire fighting equipment before reuse. Read the entire document. 6. ACCIDENTAL RELEASE MEASURES SMALL SPILL: While wearing rubber gloves, soak up spilled material with paper towels and discard in trash. LARGE SPILL: Dike or contain release. Keep material out of lakes, streams, ponds, and sewer drains. Large spills should be covered to prevent dispersal. Absorb with a non-combustible absorbent such as clay, sand or soil. Vacuum, shovel, or pump all waste material, including absorbent, into drums and label contents for disposal. Clean spill area of residues and absorbent. GENERAL PROCEDURES: Observe all protection and safety precautions when cleaning up spills -- see Section 8. "EXPOSURE CONTROLS/PERSONAL PROTECTION". 7. HANDLING AND STORAGE GENERAL PROCEDURES: Store this product only in its original container in a secured storage area. Protect container from freezing. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION ENGINEERING CONTROLS: No special ventilation is necessary under normal product use conditions. However, if workplace operating conditions create high airborne concentrations of the material, special ventilation may be needed to reduce levels below OSHA exposure limits. PERSONAL PROTECTION EYES AND FACE: For application of product in accordance with label instructions, no special eye protection is needed. Handling of this product during manufacturing or in the event of an accidental discharge of the material which could cause eye contact, workers should wear goggles or a face shield. SKIN: Follow label precautions for skin protection. Avoid contact with skin and clothing. Wash thoroughly with soap and water after handling. Remove contaminated clothing and wash before reuse. RESPIRATORY: Avoid breathing vapor or mist. This product is not likely to pose an airborne exposure concern when handled and used in accordance with label instructions. OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200): Chemical Name Bifenthrin OSHA PEL None EXPOSURE LIMITS ACGIH TLV ACGIH STEL None None 9. PHYSICAL AND CHEMICAL PROPERTIES file://K:\ORTHO%20MSDS\max.htm 7/8/2004 ORTHO® Home Defense® MAX™ Perimeter & Indoor Insect Killer RTU Pull'N Spray Page 3 of 4 PHYSICAL STATE: Liquid APPEARANCE: Clear to cloudy white liquid pH: ~7.0 to 7.3 SOLUBILITY IN WATER: Miscible with water. DENSITY: 8.32 Lbs/gal at 20°C 10. STABILITY AND REACTIVITY STABLE: YES HAZARDOUS POLYMERIZATION: NO CONDITIONS TO AVOID: DO NOT APPLY THIS PRODUCT IN OR ON ELECTRICAL EQUIPMENT DUE TO THE POSSIBILITY OF SHOCK HAZARD. 11. TOXICOLOGICAL INFORMATION ACUTE EYES: Rabbit - moderately irritating, irritation cleared by 48 hours. EPA FIFRA toxicity category - lll. DERMAL LD50: Rat = >10 g/kg. EPA FIFRA toxicity category - IV. SKIN IRRITATION: Rabbit - nonirritating, contact with bifenthrin may produce reversible skin sensations such as numbness, burning and tingling. The skin sensations usually subside within 12 hours. EPA FIFRA toxicity category - IV. ORAL LD50: Rat = > 5 g/kg. EPA FIFRA toxicity Category - IV. INHALATION LC50: Rat - 4 hour inhalation = > 5.0 mg/liter. EPA FIFRA toxicity category - IV. SENSITIZATION: Guinea pig - no evidence of allergic skin reactions. CHRONIC: CARCINOGENICITY : Mouse lifetime feeding study - high dose males - demonstrated an increase in urinary bladder hemangiopericytomas. There was no evidence of increased tumors in the other male or female mice dose levels. The mouse no observed effect level (NOEL) was male 75 mg/kg/dy, female 90 mg/kg/dy. Rat lifetime feeding study - no findings of tumors. The rat NOEL was 10 mg/kg/dy. EPA classified bifenthrin - Group C carcinogen. NEUROTOXICITY: Bifenthrin has not been associated with delayed peripheral neuropathy. Overexposure to pyrethroids results in a transient disruption in the depolarization of nerve membranes by interfering with the closing of the sodium channels. Depending upon the degree of overexposure, signs of overexposure may be displayed by tremors, muscle fasciculations, ataxia, spasms, hyperexcitability, hyperactivity and convulsions. Localized skin contact with bifenthrin may result in temporay burning, tingling or numbness sensations. TERATOGENICITY: Bifenthrin is not considered to be a teratogen (a substance that causes birth defects). The rat and rabbit developmental NOELs were 1 and 8 mg/kg/dy, respectively. REPRODUCTIVE TOXIN: Bifenthrin is not considered to cause adverse reproductive effects. Results of a rat multigeneration reproduction study indicated no developmental toxicity or reproductive effects at the highest dose level of approximately 15 mg/kg/dy. The maternal toxicity NOEL was approximately 5 mg/kg/dy. MUTAGENICITY: The results of a series of mutation testing indicate that bifenthrin has a low order of mutagenic potential. 12. ECOLOGICAL INFORMATION ENVIRONMENTAL DATA: In soil, bifenthrin is stable over a wide pH range and degrades at a slow rate which is governed by soil characteristcs. Bifenthrin will also persist in aquatic sediments. Bifenthrin has a high Log Pow (>6.0), a high affinity for organic matter, and is not mobile in soil. Therefore, there is little potential for movement into ground water. There is the potential for bifenthrin to bioconcentrate (BCF = 11,750). ECOTOXICOLOGICAL INFORMATION: This pesticide is extremely toxic to fish and aquatic invertebrates. Do not apply directly to water. Drift and runoff from treated areas may be hazardous to aquatic organisms in neighboring areas. Care should be used when spraying to avoid fish and reptile pets in/around ornamental ponds. This product is highly toxic to bees exposed to direct treatment on residues on blooming plants. Do not apply this product or allow it to drift to blooming plants if bees are visiting the treatment area. file://K:\ORTHO%20MSDS\max.htm 7/8/2004 ORTHO® Home Defense® MAX™ Perimeter & Indoor Insect Killer RTU Pull'N Spray Page 4 of 4 13. DISPOSAL CONSIDERATIONS FOR LARGE SPILLS: Material collected that cannot be reprocessed should be disposed of in a landfill approved for pesticide disposal or in accordance with applicable Federal, state, or local procedures. PRODUCT DISPOSAL: Call local solid waste agency or 1-800-CLEANUP for disposal instructions. Never place unused product down any drain. 14. TRANSPORT INFORMATION DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: Not Regulated U.S. SURFACE FREIGHT CLASS: Insecticides, Fungicides, Insect or animal repellents or vermin exterminators, NOI, Other than poison SPECIAL SHIPPING NOTES: The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous Goods Regulations, for additional description requirements (e.g., technical name) and mode-specific or quantity-specific shipping requirements. 15. REGULATORY INFORMATION UNITED STATES SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) PRODUCT CLASSIFICATION UNDER SECTION 311 OF SARA ACUTE: YES CHRONIC: NO FIRE: NO REACTIVITY: NO PRESSURE GENERATING: NO STATE REGULATIONS CALIFORNIA PROPOSITION 65: No ingredients on list. GENERAL COMMENTS: Contact local authorities for disposal of large quantities of unused product. 16. OTHER INFORMATION HMIS CODES FLAMMABILITY: 0 NFPA CODES FIRE: 0 HEALTH: 1 HEALTH: 1 PHYSICAL HAZARD: 0 REACTIVITY: 0 APPROVAL DATE: 07/08/2004 REVISION SUMMARY New MSDS ADDITIONAL MSDS INFORMATION: NFPA/HMIS Hazard Rating: 0=Least; 1=Slight; 2=Moderate; 3=High; 4=Severe. COMMENTS: Use of this product is regulated by the U.S. Environmental Protection Agency (EPA) through the approved product label. It is a violation of Federal law to use this product in a manner inconsistent with its labeling. MANUFACTURER DISCLAIMER: The information contained herein is, to the best of the Manufacturer's (see Section 1) knowledge and belief, accurate and reliable as of the date of preparation of this document. However, no warranty or guarantee, express or implied, is made as to the accuracy or reliability, and the Manufacturer shall not be liable for any loss or damage arising out of the use thereof. No authorization is given or implied to use any patented invention without a license. In addition, the Manufacturer shall not be liable for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices or from any hazards inherent in the nature of the product. file://K:\ORTHO%20MSDS\max.htm 7/8/2004 MATERIAL SAFETY DATA SHEET S00857 01 00 =========================================================================== Section 1 -- PRODUCT AND COMPANY IDENTIFICATION --------------------------------------------------------------------------PRODUCT NUMBER HMIS CODES Health 2 S00857 Flammability 2 Reactivity 0 PRODUCT NAME SPRAYON® BLAST'EM® Wasp & Hornet Killer MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. THE SHERWIN-WILLIAMS COMPANY (216) 566-2917 Consumer Group - Industrial Cleveland, OH 44115 DATE OF PREPARATION INFORMATION TELEPHONE NO. 21-MAY-07 (800) 251-2486 =========================================================================== Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE --------------------------------------------------------------------------91 64742-47-8 Heavy Aliphatic Solvent ACGIH TLV Not Available 0.2 mm OSHA PEL Not Available 5 67-63-0 2-Propanol ACGIH TLV 400 ppm 33 mm ACGIH TLV 500 ppm STEL OSHA PEL 400 ppm OSHA PEL 500 ppm STEL 0.5 51-03-6 Piperonyl Butoxide ACGIH TLV Not Available OSHA PEL Not Available 0.3 52645-53-1 Permethrin ACGIH TLV Not Available OSHA PEL Not Available 2 124-38-9 Carbon Dioxide ACGIH TLV 5000 ppm 760 mm OSHA PEL 5000 ppm =========================================================================== Section 3 -- HAZARDS IDENTIFICATION --------------------------------------------------------------------------ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Continued on page 2 S00857 page 2 =========================================================================== SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Prolonged or frequent repeated skin contact may cause allergic reactions in some individuals. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. =========================================================================== Section 4 -- FIRST AID MEASURES --------------------------------------------------------------------------EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. =========================================================================== Section 5 -- FIRE FIGHTING MEASURES --------------------------------------------------------------------------FLASH POINT LEL UEL 165 °F PMCC 0.7 12.7 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. =========================================================================== Section 6 -- ACCIDENTAL RELEASE MEASURES --------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. =========================================================================== Section 7 -- HANDLING AND STORAGE --------------------------------------------------------------------------This product is toxic to fish. Do not allow product to enter groundwater, streams, lakes or ponds. Do not contaminate water by cleaning of equipment or disposal of wastes. STORAGE CATEGORY Not Available Continued on page 3 S00857 page 3 =========================================================================== PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat and open flame. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. =========================================================================== Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION --------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. Do not use in commercial food/feed handling establishments, restaurants or other sites where food/feed is commercially prepared or processed. Do not use in Federally Inspected meat and poultry plants. Do not allow children or pets to contact treated surfaces until spray has dried. Do not spray air in rooms or use on plants. Avoid spraying vegetation directly. Apply as a surface spray only. Do not spray to contact food, feedstuffs or water supplies. Thoroughly wash dishes and food-handling utensils contaminated with this product. Remove pets and cover fish bowls before spraying. Do not contaminate water, food or feed by storage or disposal. Do not store near heat or open flame. Store in cool area away from children. It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Read entire label. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. PROTECTIVE GLOVES Wear chemical-resistant gloves to prevent skin contact. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. =========================================================================== Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES --------------------------------------------------------------------------PRODUCT WEIGHT 6.54 lb/gal 783 g/l SPECIFIC GRAVITY 0.79 BOILING POINT <0 - 500 F <-18 - 260 C MELTING POINT Not Available VOLATILE VOLUME 99 % EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. VOLATILE ORGANIC COMPOUNDS (VOC Theoretical) Volatile Weight 96.65 % Less Water and Federally Exempt Solvents Continued on page 4 S00857 page 4 =========================================================================== Section 10 -- STABILITY AND REACTIVITY --------------------------------------------------------------------------STABILITY -- Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur =========================================================================== Section 11 -- TOXICOLOGICAL INFORMATION --------------------------------------------------------------------------CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. --------------------------------------------------------------------------TOXICOLOGY DATA CAS No. Ingredient Name --------------------------------------------------------------------------64742-47-8 Heavy Aliphatic Solvent LC50 RAT 4HR Not Available LD50 RAT Not Available 67-63-0 2-Propanol LC50 RAT 4HR Not Available LD50 RAT 5045 mg/kg 51-03-6 Piperonyl Butoxide LC50 RAT 4HR Not Available LD50 RAT Not Available 52645-53-1 Permethrin LC50 RAT 4HR Not Available LD50 RAT 410 mg/kg 124-38-9 Carbon Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available =========================================================================== Section 12 -- ECOLOGICAL INFORMATION --------------------------------------------------------------------------ENVIRONMENTAL HAZARDS This product is toxic to fish and aquatic invertebrates. Do not apply directly to water. ECOTOXICOLOGICAL INFORMATION No data available. =========================================================================== Section 13 -- DISPOSAL CONSIDERATIONS --------------------------------------------------------------------------WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Continued on page 5 S00857 page 5 =========================================================================== Section 14 -- TRANSPORT INFORMATION --------------------------------------------------------------------------US Ground (DOT) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, 2.2, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, CLASS 2.2, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2, LIMITED QUANTITY, EmS F-D, S-U =========================================================================== Section 15 -- REGULATORY INFORMATION --------------------------------------------------------------------------SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. =========================================================================== Section 16 -- OTHER INFORMATION --------------------------------------------------------------------------This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. MATERIAL SAFETY DATA SHEET Date stamp: 01-Sep-2005 MSDS Ref. No.: 011771025 Revision Number: 5 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Description: ORTHO Indoor Insect Fogger Insecticide 24-HOUR EMERGENCY TELEPHONE NUMBERS: CHEMTREC (U.S.): 1-800-424-9300 CHEMTREC (International): 1-703-527-3887 Non-Emergency Calls: 1-937-644-0011 Company The Scotts Company 14111 Scottslawn Road Marysville, OH 43041 EPA Registration No.: 239-2626 Formula No.: S1112 2. HAZARDS IDENTIFICATION Labelling Signal word: Precautionary Statement CAUTION. Causes substantial but temporary eye injury. Do not get in eyes. Wear safety glases. Wear goggles. Harmful if absorbed through the skin. Avoid contact with eyes, skin, and clothing. Wash with soap and water after handling. Keep out of reach of children. Potential health effects Eye contact: Skin contact: Ingestion: Inhalation: Irritating to eyes. Irritation not expected. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea. May cause irritation of respiratory tract. Aggravated Medical Conditions: Principle routes of exposure: Target organ effects: Inhalation may aggravate asthma. Skin, Eyes, Inhalation Irritation. 3. COMPOSITION/INFORMATION ON INGREDIENTS Components Natural Pyrethrine Permethrin MGK 264, N-octyl bicycloheptene dicarboximide Inert Ingredients CAS-No 8003-34-7 52645-53-1 113-48-4 PROPRIETARY Weight % 0.05 0.4 0.4 99.115 4. FIRST AID MEASURES Eye contact: Hold eye open and rins slowly and gently with water for 15-20 minutes. Remove contact lenses, if present after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice Skin contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice Ingestion: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so be a poison control center or doctor. Do not give anything by mouth to an unconscious person Inhalation: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferabley by mouth-to-mouth, if possible. Call a poison control center or doctor for further treatment advice 5. FIRE-FIGHTING MEASURES Flammable properties: Suitable extinguishing media: Explosion potential: Explosive properties: Revision date: 10-May-2005 Flammable aerosol. N.F.P.A. (Code 30B) Level I Aerosol. Water spray, carbon dioxide, dry chemical, chemical foam. Closed containers may rupture violently under fire conditions. Heating may cause an explosion.. Page 1 of 4 MSDS Ref. No.: ORTHO Indoor Insect Fogger 011771025 _______________________________________________________________________________________________ Hazardous combustion products: Fire fighting procedures: Special protective equipment for firefighters: Flammability Limits in Air: Toxic fumes may be produced. Select appropriate method to surround and extinguish fire. Flood with water to cool containers. As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. No information available 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Environmental precautions: Methods for containment: Methods for cleaning up: Wear personal protective equipment Prevent product from entering drains Control spill with dykes and absorb with inert absorbant material Detergent and water. 7. HANDLING AND STORAGE Handling: Avoid container breakage. Avoid inhalation or contact with skin, eyes, or clothing. Do not use near heat. Do not use near an ignition source. Do not puncture or incinerate. Storage: Store in a cool, dry area away from incompatible materials and heat sources. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Components Natural Pyrethrine Permethrin MGK 264, N-octyl bicycloheptene dicarboximide Engineering controls ACGIH: 5 mg/m³ TWA Not Listed Not Listed OSHA: 5 mg/m³ TWA Not Listed Not Listed Use adequate ventilation to keep the airborne concentrations of this material below the recommended exposure standard Personal Protective Equipment Eye/face protection: Skin and body protection: Respiratory protection: General hygiene considerations: Eye/face protection is not required, but is recommended in manufacturing situations where contact may occur. Safety glasses with side shields or goggles. Face-shield. No special protective clothing is required under normal workplace conditions. Wear suitable protective clothing if contact is anticipated during manufacturing. If airborne levels are high or product does not remain intact, use a combination of engineering controls (e.g. ventilation) and personal protection (e.g. NIOSH/MSHA approved respirator for dusts, mists, and fumes. Remove and wash contaminated clothing before re-use. Wash hands before breaks and immediately after handling the product.. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Color: Solubility: Density: Method: Liquid Light yellow Miscible 8.13 lbs/gal TAG CC Appearance: Odor: Specific gravity: Flash point: clear solvent 0.975 165° F 10. STABILITY AND REACTIVITY Chemically Stable: Conditions to avoid: Materials to avoid: Hazardous decomposition products: Possibility of hazardous reactions: Yes Temperatures above 130F. Oxidising agents (strong). Toxic fumes and gases may be generated. Poses little or no immediate hazard. 11. TOXICOLOGICAL INFORMATION Acute toxicity Revision date: 10-May-2005 Page 2 of 4 MSDS Ref. No.: ORTHO Indoor Insect Fogger 011771025 _______________________________________________________________________________________________ LD50/oral: >5 g/kg, rat LD50/dermal: >5 g/kg, rabbit LC50/inhalation: >5.98 mg/L, (vapor), rat Eye effects: Mild eye irritation, rabbit Skin effects: Mild skin irritation, rabbit Sensitization: No sensitization, guinea pig Chronic toxicity Carcinogenic effects: The table below indicates whether each agency has listed any indgredient as a carcinogen. Components Natural Pyrethrine Permethrin MGK 264, N-octyl bicycloheptene dicarboximide Ingestion: Inhalation: Target organ effects: NTP: Not listed Not listed Not listed IARC: Not listed 3 Not listed OSHA: Not listed Not listed Not listed Ingestion may cause irritation to mucous membranes. Possible irritation of the respiratory tract. Irritation. 12. ECOLOGICAL INFORMATION Ecotoxicity effects: Persistence and degradability: Bioaccumulative potential: Mobility: Aquatic toxicity: Toxic to aquatic organisms. Inherently biodegradable. No information available. Water contaminating. No information available. 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Contaminated packaging: If partially filled, call the local solid waste agency or 1-800-CLEANUP for disposal instructions. Do not place product down any indoor or outdoor drain. If empty, place in trash or offer for recycling if available. 14. TRANSPORT INFORMATION The description shown may not apply to all situations. Consult 49 CFR, or appropriate dangerous goods regulations for additional description requirements (e.g. technical name) and mode-specific or quantity-specific shipping requirements. DOT Proper shipping name: Consumer Commodity, ORM-D 15. REGULATORY INFORMATION Natural Pyrethrine Components CAS-No 8003-34-7 Permethrin MGK 264, N-octyl bicycloheptene dicarboximide 52645-53-1 113-48-4 General Information CERCLA/SARA 313 0.454 kg final RQ 1 lb final RQ 1 lb final RQ Not Listed Not Listed CERCLA/SARA 302 Not Listed Not Listed Not Listed Contact local authorities for disposal of large quantities of product 16. OTHER INFORMATION NFPA: Health: 1 Flammability: 4 Reactivity: 0 HMIS: Health: 1 Flammability: 4 Reactivity: 1 Hazard Rating: 0=Least; 1-Slight; 2=Moderate; 3=High; 4=Severe Revision date: 10-May-2005 Page 3 of 4 MSDS Ref. No.: ORTHO Indoor Insect Fogger 011771025 _______________________________________________________________________________________________ EPA FIFRA Comment: Use of this product is regulated by the U.S. Environmental Protection Agency (EPA) through the approved product label. It is a violation of Federal law to use this product in a manner inconsistent with its labeling. General comment: This document contains health, safety, and environmental information useful to emergency response agencies, health care providers, manufacturers, and workers/employees. It does not replace the precautionary language, use directions, or the storage and disposal information found on the product label. Revision date: 10-May-2005 Additional Information: This information contained herein is, to the best of Scott's knowledge and belief, accurate and reliable as of the date of preparation of this document. However, no warranty or guarantee, express or implied, is made as to the accuracy or reliability, and Scotts shall not be liable for any loss or damage arising out of the use thereof. No authorization is given or implied to use any patented invention without a license. In addition, Scotts shall not be liable for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices or from any hazards inherent in the nature of the product. Revision date: 10-May-2005 Page 4 of 4 MATERIAL SAFETY DATA SHEET S00859 01 00 =========================================================================== Section 1 −− PRODUCT AND COMPANY IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT NUMBER HMIS CODES Health 2 S00859 Flammability 2 Reactivity 0 PRODUCT NAME HIT SQUAD Industrial Insecticide MANUFACTURER’S NAME EMERGENCY TELEPHONE NO. THE SHERWIN−WILLIAMS COMPANY (216) 566−2917 Consumer Group − Industrial Cleveland, OH 44115 DATE OF PREPARATION INFORMATION TELEPHONE NO. 04−JUN−03 (800) 251−2486 =========================================================================== Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 5 64741−65−7 Mineral Spirits (Odorless) ACGIH TLV 100 ppm 1 mm OSHA PEL 100 ppm 92 64742−47−8 Heavy Aliphatic Solvent ACGIH TLV Not Available 0.1 mm OSHA PEL Not Available 0.3 Proprietary Fenvalerate ACGIH TLV Not Available OSHA PEL Not Available 3 124−38−9 Carbon Dioxide ACGIH TLV 5000 ppm OSHA PEL 5000 ppm =========================================================================== Section 3 −− HAZARDS IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE Irritation of eyes, skin and upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Continued on page 2 S00859 page 2 =========================================================================== Section 4 −− FIRST AID MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− If INHALED: If affected, remove from exposure. Restore breathing. Keep warm and quiet. If on SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re−use. If in EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. If SWALLOWED: Do not induce vomiting. Get medical attention immediately. =========================================================================== Section 5 −− FIRE FIGHTING MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− FLASH POINT LEL UEL 175 F TCC 1.0 8.8 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self−contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build−up and possible autoignition or explosion when exposed to extreme heat. =========================================================================== Section 6 −− ACCIDENTAL RELEASE MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. =========================================================================== Section 7 −− HANDLING AND STORAGE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ENVIRONMENTAL HAZARDS This product is toxic to fish and aquatic invertebrates. Do not apply directly to water. STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat and open flame. Consult NFPA Code. Use approved Bonding and Grounding procedures. Store container upright to prevent leakage. Avoid storage near feed or food products. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. Continued on page 3 S00859 page 3 =========================================================================== Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Do not spray to contact food, feedstuffs or water supplies. Thoroughly wash dishes and food−handling utensils contaminated with this product. It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Read entire label. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. =========================================================================== Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT WEIGHT 6.68 lb/gal 800 g/l SPECIFIC GRAVITY 0.80 BOILING POINT <0 − 484 F <−18 − 251 C MELTING POINT Not Available VOLATILE VOLUME 99 % EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. VOLATILE ORGANIC COMPOUNDS (VOC Theoretical) Volatile Weight 96.50 % Less Water and Federally Exempt Solvents =========================================================================== Section 10 −− STABILITY AND REACTIVITY −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STABILITY −− Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Continued on page 4 S00859 page 4 =========================================================================== Section 11 −− TOXICOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− TOXICOLOGY DATA CAS No. Ingredient Name −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 64741−65−7 Mineral Spirits (Odorless) LC50 RAT 4HR Not Available LD50 RAT Not Available 64742−47−8 Heavy Aliphatic Solvent LC50 RAT 4HR Not Available LD50 RAT Not Available Proprietary Fenvalerate LC50 RAT 4HR Not Available LD50 RAT 451 mg/kg 124−38−9 Carbon Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available =========================================================================== Section 12 −− ECOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ECOTOXICOLOGICAL INFORMATION No data available. =========================================================================== Section 13 −− DISPOSAL CONSIDERATIONS −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. =========================================================================== Section 14 −− TRANSPORT INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− No data available. =========================================================================== Section 15 −− REGULATORY INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Continued on page 5 S00859 page 5 =========================================================================== Section 16 −− OTHER INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. PAGE 1 OF 2 PRODUCT CODE: MG-2, 4 MATERIAL SAFETY DATA SHEET I. GENERAL INFORMATION ENFORCER PRODUCTS, INC. P. O. BOX 1060 CARTERSVILLE, GA. 30120 PRODUCT NAME: MANUFACTURER’S PHONE NUMBER: (770) 386-0801 24 HOUR EMERGENCY NUMBER: 1-800-255-3924 HAZARD RATINGS: HEALTH_0_ REACTIVITY_0_ FLAMMABILITY_0_ PERSONAL PROTECTION_0_ EPA REG. NO.: N/A MOUSE GLUE TRAP PREPARED BY: TRESSIE DEMPSEY DATE: NOVEMBER 22, 1999 II. INGREDIENTS PRINCIPAL COMPONENTS CAS NUMBER PERCENT OSHA PEL ACGIH TLV OTHER HAZARD NONE III. PHYSICAL DATA BOILING POINT: NOT DETERMINED SPECIFIC GRAVITY: 0.95 TO 1.08 VAPOR PRESSURE (mm Hg.): N/A PERCENT VOLATILE BY VOLUME: N/A VAPOR DENSITY: N/A SOLUBILITY IN WATER: NOT SOLUBLE APPEARANCE & ODOR: OFF-WHITE TO TAN COLORED TACKY SOLID WITH REINOUS ODOR EVAPORATION RATE (Butyl Acetate = 1): N/A IV. FIRE & EXPLOSION DATA FLASHPOINT (Method used): > 400°F AUTOIGNITION TEMPERATURE: N/A LEL: N/A EXTINGUISHING MEDIA: WATER SPRAY, FOAM, DRY CHEMICAL UEL: N/A FLAMMABLE LIMITS: NOT DETERMINED SPECIAL FIRE FIGHTING PROCEDURES: WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES. UNUSUAL FIRE & EXPLOSION HAZARDS: DECOMPOSITION MAY PRODUCE SMOKE, HAZARDOUS CHEMICALS SUCH AS COx, NOx AND OTHER UNKNOWN HAZARDOUS. V. REACTIVITY HAZARD DATA STABILITY: |X| STABLE | | UNSTABLE CONDITIONS TO AVOID: OVER-HEATING INCOMPATABILITY (Materials to avoid): HAZARDOUS POLYMERIZATION: OXIDIZING MATERIALS MAY CAUSE REACTION. | | WILL OCCUR | X | WILL NOT OCCUR HAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF CARBON AND SMOKE. CONDITIONS TO AVOID: NONE KNOWN PAGE 2 OF 2 PRODUCT CODE: MG-2, 4 VI. HEALTH HAZARD DATA PRIMARY ROUTES OF ENTRY: INHALATION | | INGESTION | | SKIN ABSORPTION | | EYE | | NOT HAZARDOUS | X | ACUTE EFFECTS OF OVEREXPOSURE: INGESTION: NONE SKIN CONTACT: NONE INHALATION: NONE EYE CONTACT: NONE CHRONIC EFFECTS OF OVEREXPOSURE: CARCINOGENICITY: NONE NTP? N/A IARC? N/A MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: OSHA REGULATED? N/A NONE KNOWN. EMERGENCY FIRST AID PROCEDURES: INGESTION: FREE THROAT FROM BLOCKAGE. SKIN CONTACT: WASH WITH SOAP AND WATER. INHALATION: GET FRESH AIR. EYE CONTACT: FLUSH WITH WATER. VII. CONTROL AND PROTECTIVE MEASURES EYE PROTECTION: NONE RESPIRATORY PROTECTION (specify): NONE SKIN PROTECTION: NONE VENTILATION: NONE OTHER PROTECTION: NONE VIII. SPECIAL PRECAUTIONS HANDLING AND STORING PROCEDURES: NONE RELEASE OR SPILL PROCEDURES: SWEEP UP AND PLACE IN A CONTAINER FOR DISPOSAL. WASTE DISPOSAL METHOD: DISPOSE OF AS A SOLID WASTE. OTHER PRECAUTIONS: KEEP THIS AND ALL CHEMICALS OUT OF REACH OF CHILDREN AND PETS. IX. ADDITIONAL INFORMATION PROPER DOT SHIPPING NAME: DEVICE, NOS (NOT DOT / IMO REGULATED) BIODEGRADABILITY: NOT BIODEGRADABLE LEAK PROCEDURES: NOT LIKELY, A RESINOUS SOLID. THIS INFORMATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200. ********************** END OF REPORT ********************** PAGE 1 OF 2 PRODUCT CODE: RG-2 MATERIAL SAFETY DATA SHEET I. GENERAL INFORMATION ENFORCER PRODUCTS, INC. P. O. BOX 1060 CARTERSVILLE, GA. 30120 PRODUCT NAME: MANUFACTURER’S PHONE NUMBER: (770) 386-0801 24 HOUR EMERGENCY NUMBER: 1-800-255-3924 HAZARD RATINGS: HEALTH_0_ REACTIVITY_0_ FLAMMABILITY_0_ PERSONAL PROTECTION_0_ EPA REG. NO.: N/A ENFORCER RAT AND MOUSE GLUE TRAP PREPARED BY: TRESSIE DEMPSEY DATE: NOVEMBER 22,1999 II. INGREDIENTS PRINCIPAL COMPONENTS CAS NUMBER PERCENT OSHA PEL ACGIH TLV OTHER HAZARD NONE III. PHYSICAL DATA BOILING POINT: NOT DETERMINED SPECIFIC GRAVITY: 0.95 TO 1.08 VAPOR PRESSURE (mm Hg.): N/A PERCENT VOLATILE BY VOLUME: N/A VAPOR DENSITY: N/A SOLUBILITY IN WATER: NOT SOLUBLE APPEARANCE & ODOR: OFF-WHITE TO TAN COLORED TACKY SOLID WITH RESINOUS ODOR. EVAPORATION RATE (Butyl Acetate = 1): N/A IV. FIRE & EXPLOSION DATA FLASHPOINT (Method used): > 400°F (COC) AUTOIGNITION TEMPERATURE: N/A LEL: N/A EXTINGUISHING MEDIA: WATER SPRAY, FOAM, DRY CHEMICAL UEL: N/A FLAMMABLE LIMITS: NOT DETERMINED SPECIAL FIRE FIGHTING PROCEDURES: WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES. UNUSUAL FIRE & EXPLOSION HAZARDS: DECOMPOSITION MAY PRODUCE SMOKE, HAZARDOUS CHEMICALS SUCH AS COx, NOx AND OTHER UNKNOWN HAZARDOUS SUBSTANCES. V. REACTIVITY HAZARD DATA STABILITY: |X| STABLE | | UNSTABLE CONDITIONS TO AVOID: OVER-HEATING INCOMPATABILITY (Materials to avoid): OXIDIZING MATERIALS MAY CAUSE REACTION. | X | WILL NOT OCCUR HAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF CARBON AND SMOKE. HAZARDOUS POLYMERIZATION: | | WILL OCCUR CONDITIONS TO AVOID: NONE KNOWN PAGE 2 OF 2 PRODUCT CODE: RG-2 VI. HEALTH HAZARD DATA PRIMARY ROUTES OF ENTRY: INHALATION | | INGESTION | | SKIN ABSORPTION | | EYE | | NOT HAZARDOUS | X | ACUTE EFFECTS OF OVEREXPOSURE: INGESTION: NONE SKIN CONTACT: NONE INHALATION: NONE EYE CONTACT: NONE CHRONIC EFFECTS OF OVEREXPOSURE: CARCINOGENICITY: NONE NTP? N/A IARC? N/A MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: OSHA REGULATED? N/A NONE KNOWN. EMERGENCY FIRST AID PROCEDURES: INGESTION: FREE THROAT FROM BLOCKAGE. SKIN CONTACT: WASH WITH SOAP AND WATER. INHALATION: GET FRESH AIR. EYE CONTACT: FLUSH WITH WATER. VII. CONTROL AND PROTECTIVE MEASURES EYE PROTECTION: NONE RESPIRATORY PROTECTION (specify): NONE SKIN PROTECTION: NONE VENTILATION: NONE OTHER PROTECTION: NONE VIII. SPECIAL PRECAUTIONS HANDLING AND STORING PROCEDURES: NONE RELEASE OR SPILL PROCEDURES: SWEEP UP AND PLACE IN A CONTAINER FOR DISPOSAL. WASTE DISPOSAL METHOD: DISPOSE OF AS A SOLID WASTE. OTHER PRECAUTIONS: KEEP THIS AND ALL CHEMICALS OUT OF REACH OF CHILDREN AND PETS. IX. ADDITIONAL INFORMATION PROPER DOT SHIPPING NAME: DEVICE, NOS (NOT DOT / IMO REGULATED) BIODEGRADABILITY: NOT BIODEGRADABLE LEAK PROCEDURES: NOT LIKELY, A RESINOUS SOLID. THIS INFORMATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200. ********************** END OF REPORT ********************** Material Safety Data Sheet Calcium hypochlorite, available chlorine >65% ACC# 03990 Section 1 - Chemical Product and Company Identification MSDS Name: Calcium hypochlorite, available chlorine >65% Catalog Numbers: AC199030010, AC199030200, AC300340000, AC300340010, AC300340050, AC300341000, S79945, C100-250, C100-500 Synonyms: Calcium oxychloride; losantin; Hypochlorous acid; Calcium salt; Lime chloride Company Identification: Fisher Scientific 1 Reagent Lane Fair Lawn, NJ 07410 For information, call: 201-796-7100 Emergency Number: 201-796-7100 For CHEMTREC assistance, call: 800-424-9300 For International CHEMTREC assistance, call: 703-527-3887 Section 2 - Composition, Information on Ingredients CAS# 7778-54-3 Chemical Name Calcium hypochlorite Percent EINECS/ELINCS 100 231-908-7 Section 3 - Hazards Identification EMERGENCY OVERVIEW Appearance: white crystalline powder. Danger! Strong oxidizer. Contact with other material may cause a fire. Corrosive. Causes eye and skin burns. Harmful if swallowed. Contact with acids liberates toxic gas. May cause severe respiratory tract irritation with possible burns. May cause severe digestive tract irritation with possible burns. Air sensitive. Target Organs: Lungs, respiratory system, eyes, skin, mucous membranes. Potential Health Effects Eye: Causes eye burns. May result in corneal injury. May cause blindness. May cause blepharitis (inflammation of the margins of the eyelids). Skin: Causes severe burns with delayed tissue destruction. Ingestion: Harmful if swallowed. May cause severe and permanent damage to the digestive tract. May cause perforation of the digestive tract. Causes digestive tract burns with immediate pain, swelling of the throat, convulsions, and possible coma. Ingestion of Calcium hypochlorite solutions may cause death. As little as 1 ounce may be lethal if the available chlorine concentration exceeds 15%. Inhalation: Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause systemic effects. Causes corrosive action on the mucous membranes. Chronic: Prolonged or repeated skin contact may cause dermatitis. Prolonged or repeated eye contact may cause conjunctivitis. Effects may be delayed. Section 4 - First Aid Measures Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes). Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. Notes to Physician: Treat symptomatically and supportively. Section 5 - Fire Fighting Measures General Information: As in any fire, wear a self-contained breathing apparatus in pressuredemand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Use water with caution and in flooding amounts. Contaminating or mixing with foreign materials such as combustibles, grease, and fuels can cause fire. Containers may explode when heated. Extinguishing Media: Use water only! Do NOT use carbon dioxide or dry chemical. Contact professional fire-fighters immediately. Cool containers with flooding quantities of water until well after fire is out. Flash Point: Not available. Autoignition Temperature: Not available. Explosion Limits, Lower:Not available. Upper: Not available. NFPA Rating: (estimated) Health: 3; Flammability: 0; Instability: 1; Special Hazard: OX Section 6 - Accidental Release Measures General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Remove all sources of ignition. Provide ventilation. Do not get water inside containers. Do not use combustible materials such as paper towels to clean up spill. Section 7 - Handling and Storage Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid contact with clothing and other combustible materials. Do not ingest or inhale. Discard contaminated shoes. Use only a clean, dry scoop made of metal or plastic each time product is taken from container. Never use scoops containing remnants of other products as it may cause a violent reaction leading to fire or an explosion. Storage: Keep away from sources of ignition. Do not store near combustible materials. Do not store in direct sunlight. Keep container closed when not in use. Store in a tightly closed container. Keep away from acids. Section 8 - Exposure Controls, Personal Protection Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits Chemical Name Calcium hypochlorite ACGIH none listed NIOSH OSHA - Final PELs none listed none listed OSHA Vacated PELs: Calcium hypochlorite: No OSHA Vacated PELs are listed for this chemical. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - Physical and Chemical Properties Physical State: Crystalline powder Appearance: white Odor: strong odor - chlorine-like pH: 11.4 (1% aq. sol.) Vapor Pressure: Not applicable. Vapor Density: Not applicable. Evaporation Rate:Not applicable. Viscosity: Not available. Boiling Point: Decomposes Freezing/Melting Point:100 deg C Decomposition Temperature:180 deg C Solubility: Slightly soluble. Specific Gravity/Density:2.350 Molecular Formula:CaCl2O2 Molecular Weight:142.9848 Section 10 - Stability and Reactivity Chemical Stability: All hypochlorite solutions are unstable and slowly decompose on contact with air. Calcium hypochlorite is corrosive to most metals and will evolve toxic chlorine and chlorine monoxide gas when heated above 350°F. Sudden heating above 212°F may cause an explosion. Pure, dry calcium hypochlorite is not sensitive to friction or impact. However, in the presence of small amounts of water, it can decompose to form dangerously unstable dichlorine monoxide, which is sensitive to friction, shock or static spark. Conditions to Avoid: Ignition sources, dust generation, excess heat, moisture, high humidity. Incompatibilities with Other Materials: Reducing agents, ammonia, iron oxide, phenols, sulfur, aliphatic amines, acetylene, cyanides (e.g. potassium cyanide, sodium cyanide), sulfides (inorganic, e.g. ferric sulfide, lead sulfide, sodium sulfide), carbontetrachloride, aromatic amines, carbon, ammonium chloride, charcoal, glycerol, air, ethanol, menthol, rust, hydroxy compounds (e.g. ethanol, ethylene glycol, gycerol, sugar), metal oxides, turpentine, diethylene glycol monomethyl ether, acetic acid + potassium, N,N-dichloromethylamine + heat, 1-propanethiol, isobutanethiol, sodium hydrogen sulfate + starch + sodium carbonate, combustible materials (e.g. anthracene, grease, oil, mercaptans, methyl carbitol, nitromethane, organic matter, and propylmercaptan). Hazardous Decomposition Products: Hydrogen chloride, oxygen, chlorine, calcium hydroxide, calcium carbonate, dichlorine monoxide, Calcium chlorate. Hazardous Polymerization: Has not been reported. Section 11 - Toxicological Information RTECS#: CAS# 7778-54-3: NH3485000 LD50/LC50: CAS# 7778-54-3: Oral, rat: LD50 = 850 mg/kg; . Carcinogenicity: CAS# 7778-54-3: Not listed by ACGIH, IARC, NTP, or CA Prop 65. Epidemiology: No information found Teratogenicity: No information found Reproductive Effects: No information found Mutagenicity: Mutation in bacteria. Neurotoxicity: No information found Other Studies: Section 12 - Ecological Information Ecotoxicity: Fish: Striped bass: LC50 = 0.5 mg/L; 24 Hr; Static bioassay (70% hypochlorite) Section 13 - Disposal Considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: None listed. Section 14 - Transport Information US DOT Canada TDG Shipping Name: CALCIUM HYPOCHLORITE, DRY CALCIUM HYPOCHLORITE, DRY Hazard Class: 5.1 5.1 UN Number: UN1748 UN1748 Packing Group: II II Section 15 - Regulatory Information US FEDERAL TSCA CAS# 7778-54-3 is listed on the TSCA inventory. Health & Safety Reporting List None of the chemicals are on the Health & Safety Reporting List. Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule. Section 12b None of the chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA. CERCLA Hazardous Substances and corresponding RQs CAS# 7778-54-3: 10 lb final RQ; 4.54 kg final RQ SARA Section 302 Extremely Hazardous Substances None of the chemicals in this product have a TPQ. SARA Codes CAS # 7778-54-3: immediate, fire. Section 313 No chemicals are reportable under Section 313. Clean Air Act: This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors. Clean Water Act: CAS# 7778-54-3 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. OSHA: None of the chemicals in this product are considered highly hazardous by OSHA. STATE CAS# 7778-54-3 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Massachusetts. California Prop 65 California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: OCN Risk Phrases: R 22 Harmful if swallowed. R 31 Contact with acids liberates toxic gas. R 34 Causes burns. R 8 Contact with combustible material may cause fire. R 50 Very toxic to aquatic organisms. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr otection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S 61 Avoid release to the environment. Refer to special instructions /safety data sheets. WGK (Water Danger/Protection) CAS# 7778-54-3: 2 Canada - DSL/NDSL CAS# 7778-54-3 is listed on Canada's DSL List. Canada - WHMIS This product has a WHMIS classification of C, E. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations. Canadian Ingredient Disclosure List Section 16 - Additional Information MSDS Creation Date: 7/19/1999 Revision #7 Date: 5/16/2007 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages. f 8RENNTAG~II_II. BRENNTAG MID-SOUTH, INC. MATERIAL SAFETY DATA SHEET Effective Date: July 19, 2004 SODIUM HYPOCHLORITE SOLUTION L SECTIONI -MATERIAL mENTIFIC~TiON MANUFACTURER'S BRENNTAG NAME & ADDRES~: MID-SOUTH, EMERGENCY Inc. TELEPHONE .::J NUMBER: 270-830-1222 1405 Highway 136 West / Geneva Road Henderson, Kentucky 42420 CHEMICAL NAME AND SYNONYMS: Sodium Hypochlorite Solution (10-14.2%); Hypochlorite Solution; Bleach Solution, Hypochlorous acid, sodium salt, &/or AB Bleach; sodium hypochlorite/DIWater CHEMICAL FAMILY: Hypochlorite C' FORMULA: SECTION n -HAZARDOUS NaOCI INGRED THRESHOLD LIMIT VALUES (UNITS) OSHA: _1 ACGm: PEL J STEL I TLV 1 STEL CAS NUMBER CHEMICAL NAME(S) .WT % 7681-52-9 Sodium hypochlorite** 10 -14.2 1310-73-2 Sodium hydroxide 0.3-1.0 7647-14-5 Sodium Chloride 9 -12.5 -NON 497-19-8 Sodium carbonate ::;0.5 -NONE ESTABLISHED - 7732-18-5 Water Balance -NONE ESTABLISHED - -NON 2mgim3Ceiling E EST A B LIS 1 1 E EST A B LIS H ED - 2mgim3Ceiling H ED 1 - - This product does not contain any chemical (5) subject to reporting requirements of Section 313, Title III of SARA, Part 372. ** %(w/w) as CI1 9.5 to 13.55% TL vrrw A (ACGIH) O.5ppm C11; TL V/STEL (ACGIH) Ippm CI1 & PEL (OSHA) Ippm CI1 CO BOILING SECTIONllI-PHYSICALDATA POINT of (OC): 110°Cfor15%NaOCI I SPECIFIC GRAVITY lH!O=l): VAPOR DENSITY (AIR =1): n.a. EVAPORATION VAPOR PRESSURE (mmH2): Vapor pressure of water plus decomposition products. PERCENT VOLATILE SOLU~ILITY IN WATER: Complete APPEARANCE ...';' l SECTION IV -FIRE AND EXPLOSION FLASH POINT (METHOD USED): Non -flammable EXTINGUISHING MEDIA: .FLAMMABLE RATE: 1.08-1.27 n.a. BY VOLUME (%): Water vapor plus decomposition products. AND ODOR: Light, yellow-green liquid with pungent-like chlorine odor. HAZARD LIMITS D (% BY VOLUME): n.a. Use water spray, fog, foam, dry chemicals, or carbon dioxide. SPECIAL FIRE FIGHTING PROCEDURES: Firefighters'shouldwearprotectiveequipmentincluding self containedbreathingapparatus. Avoid fumes. Dilute spill with copius amountsof water.ventilate. Be preparedto userespirator. UNUSUAL FIRE AND EXPLOSION HAZARDS: Possiblevigorous reactionupon contaminationwith organics or oxidizing agents. Bleachdecomposeswhen heated,decompositionproductsmaycausecontainersto ruptureor explode. Many reactionscan causefire and explosion. This material will reactwith somemetalswhich maycauseliberationof oxygen. Toxic fumescanbe liberated by contact with acid or heat. C:\RDl\WORD\MSDS\MSSOHYPO.DOC Page I of 5 FORMATREVISIONDATE: April 23. 2001 .';1:' ~j BRENNTAG~II_I(~ BRENNTAG MID-SOUTH,INC. - MATERIAL SAFETYDATA SHEET Effective Date: July 19, 2004 SODIUM HYPOCHLORITE SOLUTION Vigorousreactionscanoccurwith oxidizablematerials andorganics.Keepmaterialcool usinga watersprayfroma safedistance.Keepall unnecessary peopleaway. Stayup windandstayoutof low-lyingareas. I SECTION V -HEAL EFFECTS TH HAZARD DATA I OF OVEREXPOSURE: PRECAUTIONARY STATEMENTS (Hazards to humans anddomesticanimals):Danger! Corrosive! May causesevereskin and eye irritation or chemicalbums to brokenskin. Causeseyedamage.Exposureto skin may causesensitizationor other allergic responses. INHALATION: Corrosive! Productmay causesevereirritation of the nose,throatand respiratorytract. Repeatedand/orprolonged exposuresmay causeproductive cough, runny nose,bronchopneumonia, pulmonaryedema(fluid build-up in lungs), and reductionof pulmonaryfunction. Repeatedinhalationexposuremay causeimpairmentof lung functionand permanentlung damage. EYE CONTACT: Extremelycorrosive! This productcausescornealscarringandclouding. Glaucoma,cataractsand permanent blindnessmay occur. SKIN CONTACT: Corrosive! Concentratedsolutionsmay causepain and deepandseverebums to the skin. Prolongedand repeatedexposureto diluted solutions oftencausesirrita~ion,redness,pain anddrying andcracking of the skin. Human evidencehas indicatedthat an ingredientin this productcancauseskin sensitization. INGESTION: Corrosive! Will immediatelycauseseverecorrosionof and damageto the gastrointestinaltract. Exposure characterizedby nausea,vomiting, diarrhea,abdominalpain, bleeding,and/ortissueulceration. PRIMARY ROUTES OF ENTRY: Inhalationandcontact. CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN: ~/No * as Chlorine ~/No OSHA/No ACGllI/A4* EMERGENCY AND FIRST AID PROCEDURES: INHALATION: Removevictim to freshair. Give artificial respirationif not breathing. Get medicalattention. EYE CONTACT: Washeyeswith plenty of waterfor at least15 minuteswhile holding eyelidsopen. Consultan eye specialist immediately. SKIN CONTACT: Flush skin with plenty of waterwhile removingcontaminatedclothing. Get medical attentionfor persistent irritation. Cleanclothing before reuse. INGESTION: If swallowed drink large quantitiesof water. Do NOT inducevomiting. Call a poison control centeror doctor immediatelyfor treatmentadvice. If spontaneous vomiting °£C.UfS, have victim leanforward with head down to avoid breathing in of vomitus,rinse mouthand administermore water. I SECTION VI -TOXICOLOGICAL INFO TI TOXICITY DATA: Oral LD50: 8,910mgikg. (Rats) Acute dermaltoxicity: III; LD50, > 3,000mgikg Dermal LD 50: > 10,000mgikg.(Rabbits) Primaryeye irritati9n: I; Corrosive Inhalation 0.25-hourLC 50: >10.5 mg/l (Rats) Primary skin irritation: I; Corrosive Acute oral toxicity: IV; LD50, 192mgikg SUMMARY: The concentratedsolution is corrosiveto skin, and a 5% solutionis a severeeye irritant. Solutionscontainingmore than 5% availablechlorine are classified by DOT corrosive.Toxicity describedin animalsfrom single exposuresby ingestion includesmuscularweakness,and hyperactivity. Repeatedingestionexposurein animalscausedan increasein the relative weight of adrenalglands in one study,but no pathologicalchangewere observedin two otherstudies. Long-term administrationof compound C:\RDI\WORD\MSDS\MSSOHYPO.DOC Page2 of 5 FORMAT REVISION DATE:April23.2001 .BR~~NTA:: BRENNTAGMID-SOUTH, INC. - MATERIAL SAFETY DATA SHEET Effective Date: July 19, 2004 SODIUM HYPOCHLORITE SOLUTION in drinking water of ratscauseddepressionof the immunesystem. No adversechangeswere observedin an eight-weekdermal study of a 1% solution in guineapigs. Tests in animalsdemonstrateno carcinogenicactivity by eitherthe oral or dermalroutes. Tests in bacterialand mammaliancell culturesdemonstratemutagenicactivity. I SECTION VII -ECOLOGICAL INFORMATION I ENVIRONMENTAL HAZARDS: This pesticideis toxic to fish and aquaticorganisms.Do not dischargeeffluents containingthis productinto lakes,streams,ponds,estuaries,oceansor otherwatersunlessin accordancewith the requirementsof a National PollutantDischargeElimination System(NPDES)permit and the permitting authorityhas beennotified in writing prior to discharge. Do not dischargeeffluent containingthis productto sewersystemswithout previouslynotifying the sewagetreatmentplant authority. For guidance,contactyou State WaterBoard or RegionalOffice of the EPA. Acute oral-bobwhitequail: LD50, > 2510mgikg Acute dietary-mallardduck: LC50, > 5220 ppm Acute dietary-bobwhitequail: LC50, > 5620ppm Acute fish-rainbowtrout: LC50, 0.18-0.22mgil Acute fish-bluegill sunfish: LC50, 0.44-0.79mgil I SECTION STABILITY: Acute invertebrate-daphnia: LC50, 0.033-0.048mg/l Fatheadminnows: 96-hourLC50, 5.9 mg/LO RainbowTrout: 96-hourLC50, 0.2mg/liter Bluegill sunfish: 96-hourLC50, 0.58mg/liter vm -REACTIVITY Unstable (Contingent upontemperature, DATA I HAZARDOUS POLYMERIZATION: Will not occur. contamination(metals),and pH.) CONDITIONS TO AVOW: copperand iron. Heat, light exposure,decreasein pH, and contaminationwith heavymetals, suchas nickel, cobalt, INCOMPATffiILITY (MATERIALS TO AVOm): Heavy metals,reducingagents,organics,ether,ammonia,ammoniumacetate, ammoniumcarbonate,ammoniumnitrate, ammoniumoxalate,ammoniumphosphate,ureaand acids. HAZARDOUS DECOMPOSITION PRODUCTS: Hypochlorousacid, chlorine,hydrochloric acid, sodiumchloride, sodium chlorate,and oxygen. Decompositionof sodiumhypochloritetakesplace within a few secondswith following salts: ammonium acetate,ammoniumcarbonate,ammoniumnitrate,ammoniumoxalate,and ammoniumphosphate.Hypochlorites reactwith ureato form nitrogentrichloride, which explodesspontaneouslyin air. I SECTION IX -SPILL OR LEAK PROCEDURES I STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Personnelwith properprotective equipment ~houldcontainspill. Flush areawith large amountsofwater,.;t)se reducing agentssuchasbisulfites or ferrous salt solutionsto neutralize. WASTE DISPOSAL METHOD: Disposalis to be in accordancewith all Federal,State,and Local regulations. SECTION X -SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: Whenfumespresent,useNIOSH approvedrespiratorwith acid type canister. VENTILATION: Local exhaustpreferableasrequiredto control fumes. PROTECTIVE GLOVES: Rubberor plastic. EYE PROTECTION: Chemicalgoggles. OTHER PROTECTIVE EOUIPMENT: Clothing to protectskin. Safetyshowerandeye washfountain. C:\RDl\WORD\MSDS\MSSOHYPO.DOC 1_'.- Page3 of 5 FORMAT REVISION DATE:April23,2001 0_- Ow,", "~;~."'m- BRENNT AGMID-SOUTH, INC. ~II- BRENNTAG~ 1111.1 MATERIAL SAFETY DATA SHEET Effective Date: July 19, 2004 SODIUM HYPOCHLORITE I SECTION XI -SPECIAL SOLUTION PRECAUTIONS -l PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Storethis productin a cool dry area; away form direct sunlight and heatto avoid deterioration. In caseof spill, flood areaswith largequantitiesof water. Productor rinsatesthat cannotbe usedshouldbe diluted with waterbefore disposalin a sanitarysewer. Do not reusecontainer. Do not contaminatefood or feed by storage,disposalor cleaning of equipment. Mostmetalsand metalalloys are NOT suitablefor use in contactwith sodium hypochlorite solutionsincluding aluminum, brass,bronze,copper,castiron, galvanizedsteel,mild steel,nickel, or stainlesssteel, sincethesemetals act asa catalystwhich will causerapid decompositionof the sodiumhypochlorite solution through the releaseof oxygen. Sodiumhypochlorite solutionsare basically unstable,and on exposureto heatand/orlight, will slowly decompose,becomingless concentratedwith time. Sodiumhypochloritesolutionsshould neverbe allowedto contactor mix with acids or other low pH compounds,due to the releaseof chlorine gas. Do not allow sodiumhypochloriteto mix with ammonia,since chloroaminesmaybe formed. Decompositionof sodiumhypochlorite takesplacewithin a few secondswith following salts: ammoniumacetate,ammonium carbonate,ammoniumnitrate, ammoniumoxalate,and ammoniumphosphate. Hypochlorites reactwith ureato form nitrogentrichloride, which explodesspontaneouslyin air. Solutions of sodiumhypochloriteare corrosiveto the skin,eyes,and mucousmembranes.Propersafety equipmentshouldbe used whenworking with or in close proximity of sodiumhypochlorite. OTHER PRECAUTIONS: Use with adequateventilation. Washthoroughly afterhandling. Do not get in eyes,on skin or clothing. Do NOT breathefumes or mist. Mixing this productwith chemicals(e.g. commonhouseholdcleaners,ammonia, acids,detergents, etc.) or organic matterwill releasechlorine gas,which is irritating to eyes,lungs,and mucousmembranes. STRONGOXIDIZING AGENT: Mix only with wateraccordingto labeldirections. Mixing this product with chemicals(e.g. commonhouseholdcleaners,ammonia,acids,detergents,etc.) or organic matter(e.g. urine,feces,etc.) will releasechlorine gas, which is irritating to eyes,lungs and mucousmembranes. HAZARD RATING: Health 3 SECTION Flammability 0 XII -D.O. Ti' .SHIPPING Reactivity 2 INFORMATION PROPER SHIPPING .NAME: Hypochlorite Solutions HAZARD CLASS: 8 (Corrosive) D.O.T. LABEL REQUffiED: Corrosive C:\RD1\WORD\MSDS\MSSOHYPO.DOC UN/NA: UN 1791 PACKING GROUP: III ~EPORTABLE OUANTITY OF PRODUCT: 800 to 2,000 lbs. Page4 of 5 FORMAT REVISION DATE:April23.2001 " .~'" BRENNTAG ..8.1; - BRENNTAG MID-SOUTH, INC. MATERIAL SAFETY Effective Date: DATA SHEET July 19, 2004 SODIUM HYPOCHLORITE I SECTION TSCA (Toxic CERCLA Substance Control Act}: AND SARA XIII SARA Extremely Discharge AIR ACT': OTHER REGULA Know Laws. " = 100 pounds (100% NaOCl) Acute: yes CERCLA Hazardous Material: SARA Toxic Chemical: Chronic: yes Fire: no This product does not contain nor is it manufactured nONS/LEGISLA INFORMATION 40 CFR §300-373: Hazardous substance: No Title III Hazard Classifications: EPA " CLEAN TORY All components of this product are listed on the TSCA inventory. REGULA nONS, Super fund Reportable -REGULA SOLUTION TION THAT APPLY TO THIS PRODUCT: Reactivity: yes yes No Pressure: No with ozone depleting substances. Massachusetts, Pennsylvania, and New Jersey Right-to ,,~~'.' ~i.E BRENNTAd MI~O~~~~GEVEs ~T THE ~Fo~rib~~6NT AlNED HEREIN IS FACfUAL; rr IS NOT TO BE TAKEN AS A WARRANTY OR REPRESENTATIONFOR WlDCH BRENNTAG MID-SOUTH, INC. ASSUMESLEGAL RESPONSffiILITY. rr IS OFFERED SOLELY FOR YOUR CONSffiERA TION, INVESTIGATION AND VERIFICATION. ANY USE OF THIS INFORMATION AND DATA MUST BE DETERMINED BY THE USERTO BE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS. , """ :I: ~ A(iJJ~ 71 ,::;(P 'f:~~~~~~~ ..;. C:\RDI\WORD\MSDS\MSSOHYPO.DOC "-_~_k!CJ,", ",'- "!':: ~~~~- := .. Page 5 of 5 FORMAT REVISION DATE: April 23, 2001 MATERIAL SAFETY DATA SHEET 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Product ID: SYNONYMS: No. 0310 ISSUE DATE: EDITION NO.: Pittclor® Dry Chlorinating Granules 0310D Calcium Hypochlorite Granular; Cal Hypo Granules; Ca(OCl) 2; MSDS 03/09/2007 11 PPG Industries, Inc. One PPG Place, Pittsburgh, PA 15272, USA 24-hour Emergency Telephone Number: 1-412-434-4515 For Product Information (8am-5pm Eastern time): 1-800-245-2974 (Cal Hypo) PREPARER: Product Safety, Chemicals 2. COMPOSITION/INFORMATION ON INGREDIENTS Material/CAS Number Percent Calcium Hypochlorite 7778-54-3 Calcium Chlorate 10137-74-3 Calcium Carbonate 471-34-1 Calcium Hydroxide 1305-62-0 >65 <2 <2 <2 Note: Minimum 65% Available Chlorine. 35% inert ingredients (includes 5.5-8.5% water). 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: DANGER! Corrosive - Causes severe and irreversible burns to eye and skin. Harmful if inhaled. May cause irritation and inflammation to the respiratory tract. Harmful or fatal if swallowed. Strong Oxidizing Agent! Mix only with water. Never add water to product. Always add the product to large quantities of water. Do not mix with any other chemicals. Contamination with moisture, acids, organic materials and other easily combustible materials such as petroleum, paint products, wood or paper Page 1 of 7 PPG: 0310D Pittclor® Dry Chlorinating Granules 03/09/2007 may cause fire or explosion and the liberation of hazardous gases. Do not add this product to any dispensing device containing remnants of any other product. Such use may cause violent reaction leading to fire or explosion. Very toxic to aquatic organisms. Precautions: Do not get in eyes, on skin, or on clothing. Avoid breathing dust. Irritating to nose and throat. Do not swallow. Do not eat, drink or smoke in work area. Wash hands after handling. Remove and wash contaminated clothing before reuse. Keep out of reach of children. 4. FIRST AID MEASURES INHALATION: Remove from area to fresh air. If symptomatic, contact a poison control center, emergency room or physician for treatment information. EYE/SKIN CONTACT: EYE: Remove contact lens and pour a gentle stream of warm water through the affected eye for at least 15 minutes. Contact a poison control center, emergency room or physician right away as further treatment will be necessary. SKIN: Run a gentle stream of water over the affected area for 15 minutes. A mild soap may be used if available. Contact a poison control center, emergency room or physician right away as further treatment will be necessary. INGESTION: Gently wipe or rinse the inside of the mouth with water. Sips of water may be given if person is fully conscious. Never give anything by mouth to an unconscious or convulsing person. Do Not induce vomiting. Contact a poison control center, emergency room or physician right away as further treatment will be necessary. 5. FIRE-FIGHTING MEASURES FLASH POINT: Not Applicable. EXTINGUISHING MEDIA: Drench with large quantities of water only. Do not use dry chemicals or foams. Product supplies own oxygen, therefore attempts to smother fire with a wet blanket, carbon dioxide, dry chemical extinguisher or other means are not effective. SPECIAL FIREFIGHTING PROCEDURES: Product decomposes at approximately 338-356°F (170180°C) releasing oxygen gas. Container may rupture. Fire-fighters must wear NIOSH approved, pressure demand, self-contained breathing apparatus with full face piece for possible exposure to hazardous gases. Emits toxic fumes under fire conditions. 6. ACCIDENTAL RELEASE MEASURES ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Use extreme caution in handling spilled material. Do not mix with any other chemicals. Contamination with moisture, acids, organics or other easily combustible materials such as petroleum, paint products, wood or paper may cause fire or violent decomposition. If fire or decomposition occurs in area of spill, immediately douse with plenty of water. Otherwise, sweep up all visible material using a clean (new, if possible), dry shovel and broom and dissolve material in water. Spilled material that has been swept up and dissolved in water should be used immediately in the normal application for which this product is being consumed. 7. HANDLING AND STORAGE Page 2 of 7 PPG: 0310D Pittclor® Dry Chlorinating Granules 03/09/2007 PRECAUTIONS TO BE TAKEN DURING HANDLING AND STORAGE: Store in a cool, dry, well-ventilated place. Keep in original container. Keep container closed when not in use. Keep away from heat, sparks, flames, direct sunlight, and other sources of heat, including lighted tobacco products. Use only a clean (new, if possible), dry scoop made of metal or plastic each time product is taken from the container. Do not add this product to any dispensing device containing remnants of any other product. Such use may cause violent reaction leading to fire or explosion. Add this product only to water. Never add water to product. Always add the product to large quantities of water. May cause fire or explosion if mixed with other chemicals. Fire may result if contaminated with acids, organic materials and other easily combustible materials such as oil, kerosene, gasoline, paint products wood and paper. Do not reuse container. Residual material remaining in empty container can react to cause fire. Thoroughly flush empty container with water then destroy by placing in trash collection. Do not contaminate water, food, or feed by storage or disposal of this product. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Limits: 8-hour Time Weighted Average (TWA); 15-minute Short-Term Exposure Limit (STEL) OSHA: The OSHA exposure limit(s) for Calcium hydroxide: 5 mg/m3 TWA. Calcium carbonate: 15 mg/m3 (total dust) 5 mg/m3 (respirable dust) ACGIH: The ACGIH exposure limit(s) for Calcium hydroxide: 5 mg/m3 TWA. Calcium carbonate: 10 mg/m3 (total dust) 3 mg/m3 (respirable nuisance particulate) TWA. ONTARIO: The Ontario Exposure limit(s) for Calcium hydroxide: 5 mg/m3TWAEV Calcium carbonate: 10 mg/m3TWAEV PPG Internal Permissible Exposure Limit (IPEL): TWA. 2 mg/m3 STEL. Calcium hypochlorite: 1 mg/m3 RESPIRATORY PROTECTION: Where the potential for exposure to dust exists, use the appropriate regulatory compliant full facepiece air-purifying respirator with acid gas cartridge and particulate prefilter. Carefully read and follow the respirator manufacturer's instructions and information. VENTILATION: Use local exhaust or general room/dilution ventilation sufficient to maintain employee exposure below permissible exposure limits. EYE AND FACE PROTECTION: Splashproof goggles and faceshield. PROTECTIVE GLOVES: Butyl rubber. Neoprene. Nitrile. OTHER PROTECTIVE EQUIPMENT: Boots, aprons, or chemical suits should be used when necessary to prevent skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: Vapor Density (Air=1): Decomposes at approximately 338-356°F (170-180°C) NA Page 3 of 7 PPG: 0310D Pittclor® Dry Chlorinating Granules Specific Gravity (Water=1): pH: FREEZING/MELTING POINT: SOLUBILITY (wt.% in water): Bulk Density (kg/M3): VOLUME % VOLATILE: VAPOR PRESSURE: Evaporation Rate: HEAT OF SOLUTION: Physical State: Odor: COLOR: 03/09/2007 NA Alkaline NA 217 g/l @ 27°C 65-67 lbs./cu.ft. NA NA NA Slightly exothermic Granules slight chlorine White 10. STABILITY AND REACTIVITY Stability: Unstable above 338°F (170°C). HAZARDOUS POLYMERIZATION: Will not occur. INCOMPATIBILITY (CONDITIONS/MATERIALS TO AVOID): Contamination. Excessive heat above 338°F (170°C). Moisture. Acids. Reducing agents. Organics. Combustible materials. Petroleum products. Paint products. Wood and paper. HAZARDOUS THERMAL DECOMPOSITION/COMBUSTION PRODUCTS: Acid or ammonia contamination will release toxic gases. Excessive heat will cause decomposition resulting in the release of oxygen and chlorine gas. 11. ACUTE INHALATION LC50: toxicity. ACUTE DERMAL LD50: SKIN IRRITATION: EYE IRRITATION: ACUTE ORAL LD50: TOXICOLOGICAL INFORMATION No mortality at 3.5 mg/l (rat) (1 hour). Slight to very low >1000 mg/kg. (rabbit) Slight to very low toxicity. Corrosive. Corrosive. 850 mg/kg. (rat) Moderate toxicity. CARCINOGENICITY STATUS: This product is NOT listed as a carcinogen or suspected carcinogen by NTP, IARC, ACGIH, or OSHA. MEDICAL CONDITIONS AGGRAVATED: None known. EFFECTS OF OVEREXPOSURE: ACUTE: Inhalation: Inhalation of calcium hypochlorite dust and deposition of particles in the respiratory tract can lead to irritation of the tissue and cause a variety of effects. These effects are dependent on concentration and include: upper respiratory tract irritation, nasal congestion, coughing, sore throat, laryngitis and shortness of breath. In operations where there are high concentrations of respirable Page 4 of 7 PPG: 0310D Pittclor® Dry Chlorinating Granules 03/09/2007 particulates, pulmonary edema (fluid in the lung) may be produced. If not treated immediately, pulmonary edema can be life threatening. Since this product is in granular or tablet form, particles of respirable size are not generally encountered. Eye/Skin: Calcium hypochlorite is corrosive to the eyes. Contact of calcium hypochlorite dust with the eyes, even a minute amount for a short duration, can cause severe irritation and even blindness. Contact with the skin may cause severe irritation, burns, or tissue destruction. In studies utilizing rabbits, the skin irritation score was 8/8 and the eye irritation score was 98.5/110. Ingestion: Calcium hypochlorite, if swallowed, causes severe burns to the digestive tract and can be fatal. CHRONIC: Genotoxicity: Calcium hypochlorite produced positive responses in in-vitro assays using bacterial systems (the Ames test) and chromosomal aberrations in Chinese hamster fibroblasts. In a whole animal experiment (mouse micronucleus test), exposures ranging from 20 to 160 mg/kg produced no compound related chromosomal abnormalities. Carcinogenisis: Although no study has been conducted with calcium hypochlorite, the carcinogenic potential of sodium hypochlorite was studied in F344 rats. After 104 weeks of drinking water containing up to 2000 ppm sodium hypochlorite, there was no evidence that this chemical produced any carcinogenic response. In addition, this exposure did not result in any adverse effects 12. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION: 0.088 mg/l (Bluegill) 96-hour LC50. Extreme toxicity. ENVIRONMENTAL FATE: No data at this time. 13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Spilled material that has been swept up and dissolved in water should be used immediately in the normal application for which this product is being used. If this is not possible, dissolve material in water and carefully neutralize dissolved material by adding hydrogen peroxide (one pint of 35% hydrogen peroxide solution per pound of calcium hypochlorite to be neutralized) then dilute the neutralized material with plenty of water and flush to sewer. Note: Only properly neutralized material should be flushed to sewer. Unneutralized material can cause environmental damage to receiving water or can interfere with treatment plant operation. Care must be taken when using or disposing of chemical materials and/or their containers to prevent environmental contamination. It is your duty to dispose of the chemical materials and/or their containers in accordance with the U.S. Clean Air Act, the Clean Water Act, the Resource Conservation and Recovery Act, as well as any other relevant Federal, State, or local laws/regulations regarding disposal. 14. Proper Shipping Name: TRANSPORT INFORMATION Calcium Hypochlorite, Hydrated Page 5 of 7 PPG: 0310D Pittclor® Dry Chlorinating Granules 03/09/2007 Hazard Class: 5.1 (Oxidizer) UN Number: UN2880 Packing Group: II 10 lbs./4.5 kg. (calcium USA-RQ, Hazardous Substance and Quantity: hypochlorite) Marine Pollutant: None Additional Information: USA Shipments Only - Hazardous Substances are regulated in the USA when shipped above their Reportable Quantity (RQ). 15. REGULATORY INFORMATION USA TSCA: All components of this product are listed on the TSCA Inventory. EU EINECS: All components in this product are listed on EINECS. CANADA DOMESTIC SUBSTANCES LIST (DSL): This product and/or all of its components are listed on the Canadian DSL. AUSTRALIA AICS: All components of this product are listed on AICS. KOREA ECL: All components in this product are listed on the Korean Existing Chemicals Inventory (KECI). JAPAN MITI (ENCS): All components in this product are listed on the Japanese Existing and New Chemical Substances (ENCS) chemical inventory. PHILIPPINES PICCS: All of the components in this product are listed on the Philippines Inventory of Chemicals and Chemical Substances (PICCS). CHINA IECSC: All components of this product are listed on the Inventory of Existing Chemical Substances in China (IECSC) or otherwise exempt. SARA TITLE III: SARA (311, 312) Hazard Class: Acute Health Hazard. Reactive Hazard. Fire Hazard. SARA (313) Chemicals: Not listed. SARA Extremely Hazardous Substance: Not listed. CERCLA Hazardous Substance: The following materials are listed as CERCLA Hazardous Substances in Table 302.4 of 40 CFR Part 302: Calcium Hypochlorite (7778-54-3) RQ = 10 lbs./4.54 kg. CANADA REGULATIONS (WHMIS): Class C - Oxidizing material. FIFRA: This product is registered with EPA as a pesticide. 16. OTHER INFORMATION Other Information: NSF Drinking Water Treatment Chemicals Listing - PPG calcium hypochlorite is certified for maximum use at 15 mg/L under NSF/ANSI Standard 60. The following has been revised since the last issue of this MSDS: Page 6 of 7 PPG: 0310D Pittclor® Dry Chlorinating Granules 03/09/2007 Date. Edition. Section 1 has been updated. Section 8 has been updated. Section 12 has been updated. Section 15 has been updated. Section 16 has been updated. Previous revision date: Previous edition number: 01/02/2004 010 NA = Not Available Page 7 of 7 Material Safety Data Sheet PO Box 24600 Houston, Tx 77229-4600 281-457-4888 888-647-7717 www.dxgroup.com Provided by: DPC Industries, Inc. DX Distributors, Inc. DPC Enterprises DX Systems Company DXI Industries, Inc. DX Terminals SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name TRICHLOR TABLETS Synonyms 1,3,5- TRIAZINE, TRICHLOR, CRYSTAL CARE TABLETS, HYDROTECH TABLETS Chemical Name TRICHLORISOCYANURIC ACID Emergency phone: Chemtrec: 281-457-4888 800-424-9300 Date of Issue: Revised Date: 1/2/01 N/A SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS COMPONENTS PERCENT TRICHLORISOCYANURIC ACID 99% CAS NO. 87-90-1 SECTION 3 - HAZARDS IDENTIFICATION Potential Health Effects ACGIH - TLV: Eye Contact NOT ESTABLISHED. Skin Contact CAN CAUSE SKIN BURNS, IRRITATION AND POSSIBLE ALLERGIC REACTION. Ingestion CORROSIVE AND MAY CAUSE SEVERE AND PERMANENT DAMAGE TO MOUTH, THROAT AND STOMACH. Inhalation CAUSES RESPIRATORY TRACT IRRITATION. Carcinogenicity: CAN CAUSE EYE BURNS AND PERMANENT TISSUE DAMAGE. NTP NO IARC NO OSHA NO SECTION 4 - FIRST AID PROCEDCURES Eye Contact: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. Skin Contact: IMMEDIATELY REMOVE CONTAMINATED CLOTHING OR SHOES, WIPE EXCESS FROM SKIN AND FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. USE SOAP IF AVAILABLE OR FOLLOW BY WASHING WITH SOAP AND WATER. DO NOT REUSE CLOTHING UNTIL THOROUGHLY CLEANED. GET MEDICAL ATTENTION. Inhalation: REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS DIFFICULT. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. GET MEDICAL ATTENTION. Ingestion: DO NOT INDUCE VOMITING. RINSE MOUTH WITH WATER. IF CONSCIOUS, GIVE LARGE QUANTITIES OF WATER OR MILK AND GET IMMEDIATE MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON! SECTION 5 -FIRE FIGHTING MEASURES Flash Point NONFLAMMABLE. Extinguishing Media USE MEDIA APPROPRIATE FOR SURROUNDING AREA. TRICHLOR TABLETS Page 1 of 3 WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE GEAR. STAY UPWIND AND KEEP OUT OF LOW AREAS. Special Firefighting Procedures/Precuations SECTION 6 -ACCIDENTAL RELEASE MEASURES For Spill: SWEEP OR VACUUM MATERIAL AND PLACE IN CONTAINER FOR DISPOSAL. FLUSH REMAINING MATERIAL WITH LARGE AMOUNTS OF WATER. PREVENT IT FROM ENTERING WATERWAYS OR SEWERS. SECTION 7 - HANDLING AND STORAGE Keep container tightly closed when not in use. Store in a cool, dry, well-ventilated area, away from heat and incompatible materials. Protect containers from physical damage. AVOID MOISTURE CONTAMINATION. KEEP OFF WET FLOORS. SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION Respiratory Protection USE A NIOSH/MSHA APPROVED RESPIRATOR FOLLOWING MANUFACTURER'S RECOMMENDATIONS. Ventilation LOCAL AND MECHANICAL RECOMMENDED. Protective Gloves CHEMICAL IMPERVIOUS GLOVES. Eye/Face Protection CHEMICAL SAFETY GOGGLES AND/OR FULL-FACE SHIELD. Other Protection CHEMICAL RESISTANT CLOTHING SUCH AS COVERALLS/APRON, BOOTS, ETC. Work Practices USE GOOD PERSONAL HYGIENE PRACTICES. WASH HANDS BEFORE EATING, DRINKING, SMOKING, OR USING TOILET FACILITIES. PROMPTLY REMOVE SOILED CLOTHING AND WASH THOROUGHLY BEFORE REUSE. SHOWER AFTER WORK USING PLENTY OF SOAP AND WATER. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Boiling Point (ºF): Vapor Pressure (mmHg): NOT APPLICABLE Freezing Point (ºF): NOT APPLICABLE Vapor Density (Air=1): NOT APPLICABLE Solubility (H2O): SOLUBLE Specific Gravity (H2O=1): <1 pH 2.6 Evaporation Rate: NOT DETERMINED Appearance/Odor: WHITE SOLID WITH CHLORINE-LIKE/BLEACH ODOR. DECOMP AT 230 SECTION 10 - STABILITY AND REACTIVITY Chemical Stability: YES Incompatible Materials OXIDIZING AGENTS, REDUCING AGENTS, INORGANIC NITROGEN AND ORGANIC MATERIALS. Decomposition Products MAY EVOLE CHLORINE CONTAINING GAS. Hazardous Polymerization: WILL NOT OCCUR. TRICHLOR TABLETS Page 2 of 3 SECTION 11 - TOXICITY INFORMATION LD50 SKIN = 7600 mg/kgLD50 ORAL = 600 mg/kg SECTION 12 - ECOLOGICAL INFORMATION NO DATA AVAILABLE. SECTION 13 - DISPOSAL CONSIDERATIONS DISPOSE OF WASTE MATERIALS ACCORDING TO ALL FEDERAL, STATE AND LOCAL REGULATIONS. SECTION 14 - TRANSPORT INFORMATION USA DOT Shipping Name: TRICHLOROISOCYANURIC ACID, DRY Hazard Class: 5.1 UN/NA Number: UN2468 Packing Group: II Subsidiary Hazard NO Marine Pollutant: SECTION 15 - REGULATORY INFORMATION CERCLA RQ (lbs): NOT APPLICABLE SARA Title III Section 312: Acute Chronic Flammable SARA Title III Section 313: Sudden Release of Pressure Reactive No SARA Extremely Hazardous Substance: No HMIS HAZARD RATING Health: 0 - Least Fire: 3 1 - Slight Reactivity: 1 2 - Moderate 3 - High 2 4 - Extreme SECTION 16 - OTHER INFORMATION EPA Pesticide Registration Number: NOT APPLICABLE NSF Maximum Use Level for Potable Water (Standard 60): NOT APPLICABLE TSCA (Toxic Substance Control Act), 40 CFR 710: Sources of the raw materials used in this mixture assure that all chemical ingredients present are in compliance with Section 8(b) Chemical Substance Inventory, or are otherwise in compliance with TSCA. DISCLAIMER THE DATA PRESENTED IS TRUE AND CORRECT TO THE BEST OF OUR KNOWLEDGE AND BELIEF; HOWEVER, NEITHER SELLER NOR PREPARER MAKES ANY WARRANTIES, EXPRESSED OR IMPLIED, CONCERNING THE INFORMATION PRESENTED. THE USER IS CAUTIONED TO PERFOM HIS OWN HAZARD EVALUATION AND TO RELY UPON HIS OWN DETERMINATIONS. TRICHLOR TABLETS Page 3 of 3 MATERIAL SAFETY DATA SHEET Section 1 - Product Identification & Use Product Name: Bromine Tablets WHMIS Classification: Class C: Oxidizing Material TDG Classification: Oxidizing solid, n.o.s. (bromo-chlorodimethylhydantoin) Class 5.1, UN 1479, Packing Group II Supplier: Advance Chemicals Ltd. 2023 Kingsway Ave Port Coquitlam, BC V3C 1S9 phone (604)945-9666 fax (604)945-9617 Emergency phone: CANUTEC 24 hrs (613) 996-6666 Section 2 - Hazardous Ingredients Hazardous Components %(w/w) C.A.S. No. LD50 & LC50 1-bromo-3-chloro-5, 5-dimethylhydantoin 92.5 126-06-7 no data found Section 3 - Physical Data Physical state: solid Boiling point: N/A Specific Gravity: N/A Freezing point:120-148°C% Volatile(By volume): <0.5 Solubility in water: 0.54g/100g @ 25°C Vapour pressure: N/A Evaporation rate: no data found Odour & Appearance: Pungent, off-white tablets. Section 4 - Fire or Explosion Hazard Flammability: The product is considered to be flammable. Contamination with organic chemicals, acids, or ammonia may generate fumes leading to fire or explosion. Flash Point: Decomposes at 165°C. Extinguishing media: Use copious quantities of water. Hazardous Combustion/Decomposition Products: Produces noxious gases: Br2 Section 5 - Reactivity Data Stability: Stable. Incompatible substances: Strong acids and alkalis, high storage temperatures, organic materials, ammonia bearing compounds, strong reducing agents and moisture. Polymerization: Will not occur. Hazardous decomposition products: Thermal decomposition releases unidentified noxious gases. Section 6 - Toxicological Properties Route of Entry: Skin, eye, ingestion and acute inhalation. Inhalation: May cause damage to lungs (systemic absorption). Severe to nose and throat. Skin contact: Acute exposure may cause severe skin damage. Eye contact: Acute exposure may cause severe eye damage. Section 7 - Preventative Measures Personal Protective Equipment: Avoid contact with skin and eyes. Wear chemical protective gloves, goggles and face shield, rubber apron and boots. Eye wash fountains and safety shower facilities should be provided nearby for emergency use. Respiratory protection: Use an NIOSH/MSHA approved air purifying, dust, mist and particulate respirator. Action to take for spills & leaks: Wear chemical protective clothing, rubber gloves and suitable respiratory protection. Small spills should be swept or vacuumed up and disposed of in government approved waste containers. The spill area may then be flushed with large quantities of water. Larger spills should be contained by diking with sand, soil or other non-combustible material, then transferred into approved waste containers for proper disposal. Do not allow spilled, or waste product to flow into waterways. Keep product out of sewers, storm drains, surface runoff water and soil. Restrict access to non-protected personnel. Comply with all government regulations on spill reporting, and handling and disposal of waste. Incinerate or dissolve in water and neutralize halogen. Wet spills should be collected and neutralized. Revision #: 03 Disposal methods: Dispose of contaminated product and materials used in cleaning up spills or leaks in a manner approved for this material. Consult appropriate federal, provincial and local regulatory agencies to ascertain proper disposal procedures. Note: Empty containers can have residues, gasses and mists, and are subject to proper waste disposal as mentioned above. Storage & Handling Precautions: Warning, harmful or fatal if swallowed. Causes eye, skin and respiratory irritation. Avoid contact with eyes and repeated contact with skin and clothing. Do not ingest. Keep container tightly closed when not in use. Store upright in a cool, dry, well-ventilated place away from incompatible materials. Do not use pressure to empty container. Wash thoroughly after handling. Use with adequate ventilation. Repair and Maintenance Precautions: Do not cut, grind, weld or drill in, on or near this container. Section 8 - First Aid Measures If inhaled: Remove victim to fresh air. Give artificial respiration if not breathing. Get immediate emergency medical attention. Keep patient warm and at rest. Give supplemental oxygen if victim is having trouble breathing. In case of eye contact: Immediately flush eyes with clean water for at least twenty (20) minutes, lifting the upper and lower eyelids to ensure complete flushing action of the eyeball. Get immediate emergency medical attention. Do not transport victim until the recommended flushing period has been completed, unless eye flushing can be carried out during transport. In case of skin contact: Wipe away excess material with a dry cloth then immediately flush skin with plenty of clean running water for at least twenty (20) minutes. Remove contaminated clothing and shoes. If irritation persists, get emergency medical attention. Wash and launder clothes before re-use. In case of ingestion or swallowing: If victim is conscious, dilute stomach contents by giving one or two glasses of water. DO NOT INDUCE VOMITING. Never give anything by mouth to an unconscious victim. GET IMMEDIATE EMERGENCY MEDICAL ATTENTION. Section 9 - Preparation Information Advance Chemicals Limited expressly disclaims all expressed or implied warranties of merchantability and fitness for a particular purpose with respect to the product provided. The information contained herein is offered only as a guide to the handling of this specific product, and has been prepared in good faith by technically knowledgeable personnel. This M.S.D.S. is not intended to be allinclusive, and the manner and conditions of use may involve other and additional considerations. Revised: 5 July 2004; 27 October 2006; 15 December 2006 S:\MSDS\MSDS - Advance\Advance Updated MSDS\Bromine Tablets.DOC Page 1 of 1 MATERIAL SAFETY DATA SHEET GLB Stabilizer 1. Product And Company Identification Supplier GLB 1400 Bluegrass Lakes Parkway Alpharetta, GA 30004 United States Manufacturer Advantis Technologies Inc. 1400 Bluegrass Lakes Parkway Alpharetta, GA 30004 United States Telephone Number: (770)521-5999 FAX Number: (770)521-5959 Web Site: www.poolspacare.com Telephone Number: (770) 521-5999 FAX Number: (770) 521-5959 Web Site: www.poolspacare.com Supplier Emergency Contacts & Phone Number CHEMTREC - DAY OR NIGHT: (800) 424-9300 Manufacturer Emergency Contacts & Phone Number CHEMTREC - DAY OR NIGHT: (800) 424-9300 Issue Date: 04/18/2001 Product Name: GLB Stabilizer CAS Number: Not Established Chemical Family: Cyanurate Chemical Formula: C3H3N3O3 MSDS Number: 57 Synonyms CYA 2. Composition/Information On Ingredients Ingredient Name CAS Number CYANURIC ACID Percent Of Total Weight 108-80-5 Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as carcinogens are listed if they comprise 0.1% or more of the composition. Information on proprietary materials is available in 29CFR 1910.1200(i)(1). 3. Hazards Identification Primary Routes(s) Of Entry Skin Contact Eye Hazards May cause eye irritation. Skin Hazards May cause skin irritation. Ingestion Hazards Harmful if swallowed.If ingested, get immediate medical attention Inhalation Hazards May cause respiratory tract irritation. Signs And Symptoms Low Toxicity irritating only as a dust Page 1 of 4 MATERIAL SAFETY DATA SHEET GLB Stabilizer 3. Hazards Identification - Continued Conditions Aggravated By Exposure None Known First Aid (Pictograms) 4. First Aid Measures Eye In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Consult Physician. Skin In case of contact, immediately flush skin with plenty of water for at least 15 minutes. Ingestion Call a physician or a poison control center immediately. Inhalation If inhaled, remove to fresh air. Fire Fighting (Pictograms) 5. Fire Fighting Measures Flash Point: N/A °F Flammability Class: NOT FLAMMABLE Extinguishing Media Use the appropriate extinguishing media for the surrounding fire. Fire Fighting Instructions Firefighters should wear self-contained breathing apparatus and full protective gear. 6. Accidental Release Measures Sweep up and remove immediately. Clean up on dry basis. Avoid release to the environment. Collect and dispose. 7. Handling And Storage Handling And Storage Precautions Keep out of reach of children. Do not store with acids. Keep containers tightly closed. Store material in a cool and dry place. Away from food. Handling Precautions Avoid unnecessary contact with eyes skin and clothing. Storage Precautions Store in a cool dry place. Keep away from food Work/Hygienic Practices Use safe chemical handling procedures suitable for the hazards presended by this material. Page 2 of 4 MATERIAL SAFETY DATA SHEET GLB Stabilizer Protective Clothing (Pictograms) 8. Exposure Controls/Personal Protection Engineering Controls Local exhaust acceptable. Special exhaust not required unless dust accumulation is a problem. Eye/Face Protection Safety glasses with side shields or goggles recommended. Skin Protection Chemical-resistant gloves. Respiratory Protection None normally required. If dust accumulation is a problem a dust mask is suggested. Full Cover clothing should be worn 9. Physical And Chemical Properties Appearance White to gray Crystalline powder Odor None Chemical Type: Mixture Physical State: Solid Melting Point: DECOMPOSES °F Boiling Point: DECOMPOSES @ 70C °C Specific Gravity: 0.83-0.93 Percent Volitales: NOT APPLICABLE Percent VOCs: NOT APPLICABLE Vapor Pressure: NIL Vapor Density: NOT VOLATILE Solubility: 1% AT 25C IN WATER Viscosity: NOT APPLICABLE Evaporation Rate: NOT APPLICABLE 10. Stability And Reactivity Stability: Stable Hazardous Polymerization: Will not occur Incompatible Materials NONE Hazardous Decomposition Products Oxides of Nitrogen and Carbon anc Cyanuric Acid 11. Toxicological Information Acute Oral Effects LD50 mg/kg Rat >5g/kg Page 3 of 4 MATERIAL SAFETY DATA SHEET GLB Stabilizer 12. Ecological Information No Data Available... 13. Disposal Considerations Dispose in accordance with applicable federal, state and local government regulations. 14. Transport Information Proper Shipping Name NOT REGULATED Hazard Class NOT REGULATED DOT Identification Number NONE DOT Shipping Label NOT ASSIGNED 15. Regulatory Information No Data Available... NFPA HMIS 0 1 0 HEALTH 1 FLAMMABILITY 0 REACTIVITY 0 PERSONAL PROTECTION E 16. Other Information Revision/Preparer Information MSDS Preparer: JHW3 This MSDS Superceeds A Previous MSDS Dated: 07/26/2000 Disclaimer Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitablility of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purposes(s). GLB Printed Using MSDS Generator™ 2000 Page 4 of 4 MATERIAL SAFETY DATA SHEET GLB Alkalinity Up 1. Product And Company Identification Supplier GLB 1400 Bluegrass Lakes Parkway Alpharetta, GA 30004 United States Manufacturer Advantis Technologies Inc. 1400 Bluegrass Lakes Parkway Alpharetta, GA 30004 United States Telephone Number: (770)521-5999 FAX Number: (770)521-5959 Web Site: www.poolspacare.com Telephone Number: (770) 521-5999 FAX Number: (770) 521-5959 Web Site: www.poolspacare.com Supplier Emergency Contacts & Phone Number CHEMTREC - DAY OR NIGHT: (800) 424-9300 Manufacturer Emergency Contacts & Phone Number CHEMTREC - DAY OR NIGHT: (800) 424-9300 Issue Date: 01/19/05 Product Name: GLB Alkalinity Up CAS Number: Not Established Chemical Family: Alkali Salt Chemical Formula: NaHCO3 MSDS Number: 48 2. Composition/Information On Ingredients Ingredient Name CAS Number SODIUM BICARBONATE Percent Of Total Weight 144-55-8 Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as carcinogens are listed if they comprise 0.1% of more of the composition. Information on proprietary materials is available in 29CFR 1910.1200(i)(1). 3. Hazards Identification Primary Routes(s) Of Entry Skin Contact Eye Hazards Causes eye irritation. Skin Hazards Causes skin irritation. Ingestion Hazards Harmful if swallowed. If ingested, get immediate medical attention Inhalation Hazards May cause respiratory tract irritation. Signs And Symptoms none known Page 1 of 5 MATERIAL SAFETY DATA SHEET GLB Alkalinity Up First Aid (Pictograms) 4. First Aid Measures Eye In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Consult Physician. Skin Wash the affected area under tepid running water using a mild soap. Ingestion INDUCE VOMITING. Drink large amounts of water. Contact a physician or poison control. Inhalation If inhaled, remove to fresh air. Fire Fighting (Pictograms) 5. Fire Fighting Measures Flash Point: N/A °F Flammability Class: NOT FLAMMABLE Extinguishing Media Use the appropriate extinguishing media for the surrounding fire. Fire Fighting Instructions Firefighters should wear self-contained breathing apparatus and full protective gear. This material is used as a dry powder extinguishing agent for all classes of fires 6. Accidental Release Measures Sweep up and remove immediately. Collect and dispose. 7. Handling And Storage Handling And Storage Precautions Keep out of reach of children. Do not store with acids. Keep containers tightly closed. Store material in a cool and dry place. Handling Precautions Avoid contact with eyes. Storage Precautions Keep away from acids. Store in a cool dry place. Work/Hygienic Practices Use safe chemical handling procedures suitable for the hazards presended by this material. Page 2 of 5 MATERIAL SAFETY DATA SHEET GLB Alkalinity Up Protective Clothing (Pictograms) 8. Exposure Controls/Personal Protection Engineering Controls Use with adequate general and local exhaust ventilation. Eye/Face Protection Safety glasses with side shields or goggles recommended. Skin Protection Chemical-resistant gloves. Respiratory Protection None normally required. If dust accumulation is a problem a dust mask is suggested. 9. Physical And Chemical Properties Appearance White Granules Odor None Chemical Type: Mixture Physical State: Solid Melting Point: DECOMPOSES °F Boiling Point: DECOMPOSES °F Percent Volitales: NOT APPLICABLE Percent VOCs: NOT APPLICABLE Vapor Pressure: NOT APPLICABLE Vapor Density: NOT APPLICABLE pH Factor: 8.5 At a Concentration Of 1% SOLUTION IN WATER Solubility: 9.6G/100ML AT 20C IN WATER Viscosity: NOT APPLICABLE Evaporation Rate: NOT APPLICABLE 10. Stability And Reactivity Stability: Stable Hazardous Polymerization: Will not occur Conditions To Avoid (Stability) High Humidity Causes Caking Incompatible Materials All Acids Hazardous Decomposition Products CO2 11. Toxicological Information Acute Oral Effects LD50 mg/kg Rat >4.22g/kg MAY CAUSE IRRITATION OF EYES AND RESPIATORY PASSAGES. INGESTATION MAY CAUSE GASTROINTESTINAL IRRITATION Page 3 of 5 MATERIAL SAFETY DATA SHEET GLB Alkalinity Up 12. Ecological Information No Data Available... 13. Disposal Considerations Dispose in accordance with applicable federal, state and local government regulations. 14. Transport Information Proper Shipping Name NOT REGULATED Hazard Class NOT REGULATED Secondary Hazard Class NOT REGULATED DOT Identification Number NONE DOT Shipping Label NOT ASSIGNED Freight Class NOT REGULATED Packaging Requirements NOT REGULATED 15. Regulatory Information State Regulations Sodium Bicarbonate is considered a hazardous waste in California Canadian Regulatory Information Class D, Div 2b - Poisonous or Infectious Material: other toxic effects NFPA HMIS 0 0 0 HEALTH 0 FLAMMABILITY 0 REACTIVITY 0 PERSONAL PROTECTION E 16. Other Information Revision/Preparer Information MSDS Preparer: JHW3 This MSDS Superceeds A Previous MSDS Dated: 07/26/2000 Disclaimer Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitablility of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purposes(s). Page 4 of 5 MATERIAL SAFETY DATA GLB Alkalinity Up Disclaimer - Continued GLB Printed Using MSDS Generator™ 2000 Page 5 of 5 SHEET MATERIAL SAFETY DATA SHEET GLB Clear Blue 1. Product And Company Identification Supplier GLB 1400 Bluegrass Lakes Parkway Alpharetta, GA 30004 United States Manufacturer Advantis Technologies, Inc. 1400 Bluegrass Lakes Parkway Alpharetta, GA 30004 United States Telephone Number: (770)521-5999 FAX Number: (770)521-5959 Web Site: www.poolspacare.com Telephone Number: (770) 521-5999 FAX Number: (770) 521-5959 Web Site: www.poolspacare.com Supplier Emergency Contacts & Phone Number CHEMTREC - DAY OR NIGHT: (800) 424-9300 Manufacturer Emergency Contacts & Phone Number CHEMTREC - DAY OR NIGHT: (800) 424-9300 Issue Date: 02/08/2006 Product Name: GLB Clear Blue Chemical Name: Catonic Polyamide in water CAS Number: Not Established Chemical Formula: Proprietery MSDS Number: 36 2. Composition/Information On Ingredients Ingredient Name CAS Number Polydimethyldiallyammonium Chloride Percent Of Total Weight 26062-79-3 Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as carcinogens are listed if they comprise 0.1% or more of the composition. Information on proprietary materials is available in 29CFR 1910.1200(i)(1). 3. Hazards Identification Primary Routes(s) Of Entry Skin Contact Eye Hazards May cause eye irritation. Skin Hazards May cause skin irritation. Non-sensitizer for skin. Ingestion Hazards Harmful if swallowed. Inhalation Hazards Slightly hazardous in case of inhalation. Signs And Symptoms Irritant to eyes and skin 4. First Aid Measures No Data Available... Page 1 of 4 MATERIAL SAFETY DATA SHEET GLB Clear Blue 4. First Aid Measures - Continued Eye In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Skin Remove contaminated clothing and shoes.Rinse the affected area with tepid water for at least 15 minutes. Ingestion DO NOT INDUCE VOMITING. Drink large amounts of water or milk. Contact a physician or poison control. In cases where individual is semi-comatose, comatose, or convulsing, DO NOT GIVE FLUIDS BY MOUTH. Inhalation If inhaled, remove to fresh air. Fire Fighting (Pictograms) 5. Fire Fighting Measures Flash Point: >100 °C Flash Point Method: Closed Cup Flammability Class: NOT FLAMMABLE Fire And Explosion Hazards In a fire situation, may liberate oxides of nitrogen or carbon, and hydrogen chloride. Extinguishing Media Use the appropriate extinguishing media for the surrounding fire. Fire Fighting Instructions CAUTION Surfaces wet with this product are slippery. Keep containers cool by spraying with water if exposed to fire. 6. Accidental Release Measures Clean up spill immediately. Contain and/or absorb spill with inert material (e.g. sand, vermiculite). Flush spill area with water. Use appropriate containers to avoid environmental contamination. CAUTION Surfaces wet with this product are slippery. 7. Handling And Storage Handling And Storage Precautions Keep out of reach of children. Store material in a cool and dry place. Wash thoroughly after handling. Storage Precautions Avoid contact with skin and clothing. Work/Hygienic Practices Wash thoroughly with soap and water after handling. Page 2 of 4 MATERIAL SAFETY DATA SHEET GLB Clear Blue 7. Handling And Storage - Continued Protective Clothing (Pictograms) 8. Exposure Controls/Personal Protection Engineering Controls Local exhaust acceptable. Special exhaust not required. Eye/Face Protection Safety glasses with side shields or goggles recommended. Skin Protection Chemical-resistant gloves. Respiratory Protection None normally required. 9. Physical And Chemical Properties Appearance Clear Blue Odor Mild amine Chemical Type: Mixture Physical State: Liquid Melting Point: NOT APPLICABLE °F Boiling Point: 212 °F Specific Gravity: 1.0-1.1 Molecular Weight: Proprietary Percent Volitales: NEGLIGIBLE Packing Density: NOT DETERMINED Vapor Pressure: NOT DETERMINED Vapor Density: NOT DETERMINED pH Factor: 2-3 Solubility: Soluble in Water Viscosity: NOT DETERMINED Evaporation Rate: <1 10. Stability And Reactivity Sta bility: Stable Hazardous Polymerization: will not occur Conditions To Avoid (Stability) Strong Oxidizers Incompatible Materials Avoid contact with strong oxidizers Hazardous Decomposition Products When heated toxic fumes such as Oxides of Carbon, Nitrogen and Hydrogen chloride may be present Page 3 of 4 MATERIAL SAFETY DATA SHEET GLB Clear Blue 11. Toxicological Information No Data Available... 12. Ecological Information No Data Available... 13. Disposal Considerations Refer to applicable federal, state, and local regulations prior to disposition of container and residual contents. 14. Transport Information Proper Shipping Name NOT REGULATED Hazard Class NONE ASSIGNED DOT Identification Number NONE 15. Regulatory Information No Data Available... NFPA HMIS 0 1 0 HEALTH 1 FLAMMABILITY 0 REACTIVITY 0 PERSONAL B PROTECTION 16. Other Information Revision/Preparer Information MSDS Preparer: JHW This MSDS Superceeds A Previous MSDS Dated: 07/24/2000 Disclaimer Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitablility of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purposes(s). GLB Printed Using MSDS Generator™ 2000 Page 4 of 4 MATERIAL SAFETY DATA SHEET Page 1 of 5 GLB Filter Cleanse 1. Product And Company Identification Supplier GLB 1400 Bluegrass Lakes Parkway Alpharetta, GA 30004 United States Manufacturer Advantis Technologies, Inc. 1400 Bluegrass Lakes Parkway Alpharetta, GA 30004 United States Telephone Number: (770)521-5999 FAX Number: (770)521-5959 Web Site: www.poolspacare.com Telephone Number: (770) 521-5999 FAX Number: (770) 521-5959 Web Site: www.poolspacare.com Supplier Emergency Contacts & Phone Number CHEMTREC - DAY OR NIGHT: (800) 424-9300 Manufacturer Emergency Contacts & Phone Number CHEMTREC - DAY OR NIGHT: (800) 424-9300 Issue Date: 05/05/2004 Product Name: GLB Filter Cleanse Chemical Name: Acid surfactant cleaner Chemical Family: Acid Chemical Formula: Proprietary Mixture MSDS Number: 116 2. Composition/Information On Ingredients Ingredient Name CAS Number CITRICACID Percent Of Total Weight 77-92-9 SODIUMBISULFATE 7681-38-1 Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as carcinogens are listed if they comprise 0.1% or more of the composition. Information on proprietary materials is available in 29CFR 1910.1200(i)(1). EMERGENCY OVERVIEW Corrosive to eyes skin and respiatory tract. Hazards Identification (Pictograms) 3. Hazards Identification Primary Routes(s) Of Entry Skin Contact Eye Hazards Causes eye damage. Skin Hazards May cause skin irritation. Ingestion Hazards Harmful if swallowed. MATERIAL SAFETY DATA SHEET Page 2 of 5 GLB Filter Cleanse 3. Hazards Identification - Continued Inhalation Hazards Causes respiratory tract irritation. Signs And Symptoms Irritation of Eyes, Skin and Respiratory Passages First Aid (Pictograms) 4. First Aid Measures Eye In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Call a physician or a poison control center immediately. Skin In case of contact, immediately flush skin with soap and plenty of water. Remove contaminated clothing and shoes. Ingestion DO NOT INDUCE VOMITING. Call a physician or a poison control center immediately. If victim is fully conscious, give one or two cups of water or milk to drink. Inhalation If breathing is difficult, give oxygen. If inhaled, remove to fresh air. Fire Fighting (Pictograms) 5. Fire Fighting Measures Flash Point: N/A °F Fire And Explosion Hazards At temperatures in excess of 570 F, hazardous fumes of sulfur dioxide and sulfur trioxide are evolved. Use forced draft ventilation or gas mask. Extinguishing Media Use the appropriate extinguishing media for the surrounding fire. Fire Fighting Instructions Firefighters should wear self-contained breathing apparatus and full protective gear. Water can be used to cool and protect exposed material. 6. Accidental Release Measures Clean up spill immediately. Neutralize spill area with soda ash or lime. Flush spill area with water. Use appropriate containers to avoid environmental contamination. MATERIAL SAFETY DATA SHEET GLB Filter Cleanse Handling & Storage (Pictograms) 7. Handling And Storage Handling And Storage Precautions Keep out of reach of children. Store material in a cool and dry place. Keep containers tightly closed. Handling Precautions Use only with adequate personal protection. Storage Precautions Store in a cool dry place. Work/Hygienic Practices Use safe chemical handling procedures suitable for the hazards presended by this material. Avoid contact with eyes. Solutions of this material are acidic and strongly irritating. Will attack most metals. Protective Clothing (Pictograms) 8. Exposure Controls/Personal Protection Engineering Controls Local exhaust acceptable. Special exhaust not required Eye/Face Protection Safety glasses with side shields or goggles recommended. Skin Protection Chemical-resistant gloves. Respiratory Protection None normally required. 9. Physical And Chemical Properties Appearance Purple to Red Granular Odor Slightly Acidic Chemical Type: Mixture Physical State: Solid Melting Point: n/a °F Boiling Point: 220 °F Specific Gravity: 1.30 Molecular Weight: NOT DETERMINED Percent Volitales: NOT DETERMINED Vapor Pressure: NOT DETERMINED pH Factor: <1 At a Concentration Of 1% solution in water Solubility: <30% Page 3 of 5 MATERIAL SAFETY DATA SHEET Page 4 of 5 GLB Filter Cleanse 10. Stability And Reactivity Sta bility: Stable Hazardous Polymerization: Will not occur. Incompatible Materials Oxidizers, Cyanides, Sulfides, Strong Alkaline or caustic material. Hazardous Decomposition Products At Temperatures in excess of 570F Hazardous fumes of Sulfur Dioxide and Sulfer Trioxide are evolved. 11. Toxicological Information No Data Available... 12. Ecological Information No Data Available... 13. Disposal Considerations Dispose in accordance with applicable federal, state and local government regulations. 14. Transport Information Proper Shipping Name NOT REGULATED Hazard Class NOT REGULATED DOT Identification Number NONE 15. Regulatory Information Ingredient(s) - State Regulations SODIUM BISULFATE New Jersey - Workplace Hazard New Jersey - Special Hazard New York City - Hazardous Substance NFPA HMIS 0 1 1 HEALTH 1 FLAMMABILITY 0 REACTIVITY 1 PERSONAL F PROTECTION 16. Other Information Revision/Preparer Information MSDS Preparer: JHW This MSDS Superceeds A Previous MSDS Dated: 11/03/2000 Disclaimer Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitablility of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purposes(s). MATERIAL SAFETY DATA SHEET GLB Filter Cleanse Disclaimer - Continued GLB Printed Using MSDS Generator™ 2000 Page 5 of 5 Product #SASH, SAL* Page 1 of 7 MATERIAL SAFETY DATA SHEET Sodium Carbonate Section 01 - Chemical And Product And Company Information Product Identifier ……………………... Sodium Carbonate (Soda Ash) Product Use …………………………..... Glass manufacture, detergent manufacture, sodium chemical manufacture, carbonate chemicals manufacture, pulp and paper, brine treatment,water hardness removal, pH adjustment in water or waste water, flue gas desulfurization, coal treatment, ion exchange resin regeneration Supplier Name……………………….…. ClearTech Industries Inc. 2302 Hanselman Avenue Saskatoon, SK. Canada S7L 5Z3 Prepared By................……………..….. ClearTech Industries Inc. Technical Department Phone: (306)664-2522 Preparation Date.........…………….…... December 21, 2007 24-Hour Emergency Phone…………... 306-664-2522 Section 02 - Composition / Information on Ingredients Hazardous Ingredients....………….... Sodium Carbonate 99.8% CAS Number...................…….…….....Sodium Carbonate 497-19-8 Synonym (s)...................……………...Disodium carbonate, calcined soda, soda ash, lite soda ash, dense soda ash, carbonic acid, disodium salt, sodium carbonate anhydrous Product #SASH, SAL* Page 2 of 7 Section 03 - Hazard Identification Inhalation...................………….….... May cause upper respiratory tract irritation. Skin Contact / Absorption…….…... May cause redness, swelling from prolonged contact, especially in hot weather. Eye Contact................………….….... Causes irritation, may burn eyes. Ingestion.....................………………. Low acute oral toxicity. May cause nausea, vomiting, diarrhea, irritation, and stomach ache. Exposure Limits……………………... Treat as a nuisance particulate: TWA(OSHA)= 5mg/m3; TWA(Ontario Ministry of Labour)= 10mg/m3 Section 04 - First Aid Measures Inhalation....................……………….. Remove victim to fresh air. Give artificial respiration only if breathing has stopped. If breathing is difficult, give oxygen. Seek immediate medical attention. Skin Contact / Absorption………….. Remove contaminated clothing. Wash affected area with soap and water. Seek medical attention if irritation occurs or persists. Eye Contact..................…………….... Flush immediately with water for at least 20 minutes. Forcibly hold eyelids apart to ensure complete irrigation of eye tissue. Seek immediate medical attention Ingestion......................………………. Do not induce vomiting. If vomiting occurs, lean victim forward to prevent breathing in vomitus. Give large amounts of water. Do not give anything by mouth to an unconscious or convulsing person. Seek immediate medical attention. Additional Information.....…………... While internal toxicity is low, irritant effects of high concentrations may produce corneal opacities, and vesicular skin reactions in humans with abraded skin only. Treatment is symptomatic and supportive. Section 05 - Fire Fighting Conditions of Flammability……….... Non flammable Means of Extinction........…………..... Product does not burn. Use appropriate extinguishing media for material that is supplying the fuel to the fire. Flash Point....………………………….. Not applicable Product #SASH, SAL* Page 3 of 7 Auto-ignition Temperature…………. Not applicable Upper Flammable Limit …………….. Not applicable Lower Flammable Limit...……….…... Not applicable Hazardous Combustible Products... Heating sodium carbonate liberates CO2 and fumes of sodium oxide. Special Fire Fighting Procedures..... Wear NIOSH-approved self-contained breathing apparatus and protective clothing. Explosion Hazards………………….... Not applicable Section 06 - Accidental Release Measures Leak / Spill................….……………... Wear appropriate personal protective equipment. Ventilate area. Stop or reduce leak if safe to do so. Prevent material from entering sewers. Deactivating Materials...……….…... Use an acid to neutralize after the soda ash has been made into a solution. Section 07 - Handling and Storage Handling Procedures.......…………... Use proper equipment for lifting and transporting all containers. Use sensible industrial hygiene and housekeeping practices. Wash thoroughly after handling. Avoid all situations that could lead to harmful exposure. Storage Requirements......……...….. Product is hygroscopic and tends to cake on storage. Store in a cool, dry, well ventilated place. Keep container tightly closed, and away from acids. Section 08 - Personal Protection and Exposure Controls Protective Equipment Eyes.………………………….………... Chemical goggles, full-face shield, or a full-face respirator is to be worn at all times when product is handled. Contact lenses should not be worn; they may contribute to severe eye injury. Respiratory………………………….... Respiratory protection is not normally required. If use creates dust formations, then a NIOSH approved respirator with a dust cartridge is recommended. Product #SASH, SAL* Page 4 of 7 Gloves………………………………..... Impervious gloves of chemically resistant material (rubber or PVC) should be worn at all times. Wash contaminated clothing and dry thoroughly before reuse. Clothing………………………..…….... Body suits, aprons, and/or coveralls of chemical resistant material should be worn at all times. Wash contaminated clothing and dry thoroughly before reuse. Footwear……………………………..... No special footwear is required other than what is mandated at place of work. Engineering Controls Ventilation Requirements………...... Mechanical ventilation (dilution or local exhaust), process or personnel enclosure and control of process conditions should be provided. Supply sufficient replacement air to make up for air removed by exhaust systems. Other………………………………….... Emergency shower and eyewash should be in close proximity. Section 09 - Physical and Chemical Properties Physical State.......……....………….... Solid Odor and Appearance…..…………... White granular solid, no odour Odor Threshold....……………............ Not applicable Specific Gravity (Water=1)………….. ~2.53 @ 20oC Vapor Pressure (mm Hg, 20C)….….. Not applicable Vapor Density (Air=1)..…………….... Not applicable Evaporation Rate........……..…….….. Not applicable Boiling Point...............………….…..... Not available Freeze/Melting Point....…………….... 851oC pH............................……………….….. 11.3 (1% solution) Water/Oil Distribution Coefficient.... Not available Bulk Density..............…………….…... 0.70-1.12g/cm3 % Volatiles by Volume………..……... Not applicable Product #SASH, SAL* Page 5 of 7 Solubility in Water...………………..... 33.2%(w/w) Molecular Formula......………….….... Na2CO3 Molecular Weight........……………..... 105.99 Section 10 - Stability and Reactivity Stability.................…………....……………. Stable under normal conditions. Avoid conditions of extreme heat (i.e.:temperatures greater than 400oC). Heating liberates fumes of sodium oxide. Incompatibility..............…………..……….. Aluminium, fluorine, humid air, moisture, acids, sulfuric acid, magnesium, phosphorus pentaoxide, molten lithium. Hazardous Products of Decomposition.. Carbon dioxide and heat form from reaction with acids. Polymerization...........…………….…….…. Will not occur Section 11 - Toxicological Information Irritancy.................……..………….…. Mild irritant. Skin and eye irritant. Sensitization........…….......………….. Non-sensitizing (humans, 0.25% Sodium carbonate) Chronic/Acute Effects……...……….. May cause severe irritation of the eyes, including corneal opacities. Dusts and mists may be irritating to the skin, mucous membranes and upper respiratory tract. No significant acute toxicological effects expected. Synergistic Materials...……....……... Not available Animal Toxicity Data......…..………... LD50(Rat, Oral)= 4090mg/kg LC50(Rat, Inhalation, 2hr)= 2.3mg/L Carcinogenicity......……......……….... Not considered to be carcinogenic by IARC, NTP, ACGIH, and OSHA Reproductive Toxicity..…...………... Not available Teratogenicity..........….....…………... Not available Mutagenicity...........…….....…………. Not available Product #SASH, SAL* Page 6 of 7 Section 12 - Ecological Information Fish Toxicity..................……………... TLm(48hr, Mosquito Fish)= 840mg/L TLm(96hr, Mosquito Fish)= 1200mg/L LC50(Daphina magna, 96hr)= 265-565mg/L LC50(Bluegill sunfish, 96hr)= 300-320mg/L Biodegradability.............……….….... Not applicable Environmental Effects………………. Not available Section 13 - Disposal Consideration Waste Disposal...........…...…………...Dispose in accordance with all federal, provincial, and/or local regulations including the Canadian Environmental Protection Act. Section 14 - Transportation Information TDG Classification Class……………..………………..….... Not regulated Group...............…………….......……... Not regulated PIN Number.................……..……….... Not regulated Other…………………………………..... Secure containers (full and/or empty) with suitable hold down devises during shipment. Section 15 - Regulatory Information WHMIS Classification.......…………....D2, E NOTE: THE PRODUCT LISTED ON THIS MSDS HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CANADIAN CONTROLLED PRODUCTS REGULATIONS. THIS MSDS CONTAINS ALL INFORMATION REQUIRED BY THOSE REGULATIONS. NSF Certification................................Product is certified under ANSI/NSF Standard 60 for corrosion control, scale control and pH adjustment at a maximum dosage of 150mg/L. Section 16 - Other Information Note: The responsibility to provide a safe workplace remains with the user. The user should consider the health hazards and safety information contained herein as a guide and should take those precautions required in an individual operation to instruct employees and develop work practice procedures for a safe work environment. The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages Product #SASH, SAL* Page 7 of 7 incurred by the use of this material. It is the responsibility of the user to comply with all applicable laws and regulations. Attention: Receiver of the chemical goods / MSDS coordinator As part of our commitment to the Canadian Association of Chemical Distributors (CACD) Responsible Distribution® initiative, ClearTech Industries Inc. and its associated companies require, as a condition of sale, that you forward the attached Material Safety Data Sheet(s) to all affected employees, customers, and end-users. ClearTech will send any available supplementary handling, health, and safety information to you at your request. If you have any questions or concerns please call our customer service or technical service department. ClearTech Industries Inc. - Locations Corporate Head Office: 2302 Hanselman Avenue, Saskatoon, SK, S7L 5Z3 Phone: 306-664-2522 Fax: 306-665-6216 Location Richmond, B.C. Calgary, AB. Edmonton, AB. Saskatoon, SK. Regina, SK. Winnipeg, MB. Mississauga, ON. www.ClearTech.ca Address Postal Code 12431 Horseshoe Way V7A 4X6 5516E - 40th St. S.E. T2C 2A1 11750 - 180th Street T5S 1N7 2302 Hanselman Avenue S7L 5Z3 555 Henderson Drive S42 5X2 340 Saulteaux Crescent R3J 3T2 7480 Bath Road L4T 1L2 Phone Number 604-272-4000 403-279-1096 780-452-6000 306-933-0177 306-721-7737 204-987-9777 905-612-0566 Fax Number 604-272-4596 403-236-0989 780-452-4600 306-933-3282 306-721-8611 204-987-9770 905-612-0575 24 Hour Emergency Number - All Locations - 306-664-2522 Material Safety Data Sheet WHMIS (Pictograms) WHMIS (Classification) Personal Protective Equipment Class D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). Class E: Corrosive liquid. Section 1. Product and Company Identification Product Name / Trade name Muriatic Acid Associated Product’s Item Code WIP-12280 12-284EXP Synonym Hydrochloric acid CAS # 7647-01-0 Chemical Family Inorganic acid. July 08 2004 Validation Date 7/8/2004. Chemical Formula HCl (aq) Print Date Manufacturer Recochem Inc. 850 Montee de Liesse Montreal, Quebec 514-341-3550 In Case of Recochem Inc. Emergency C o m m u n i c a t i o n s a n d R e g u l a t o r y Affairs Department (905) 791-1788 Material Uses Consumer products: Cleaning solution. Muriatic Acid July 08 2004 7/8/2004. Section 2. Hazardous Ingredients Name Hydrochloric acid CAS # % by Weight 7647-01-0 31-32% / 20º Baume Exposure Limits Canadian Values (ACGIH) U.S. Values (OSHA) Muriatic Acid Not available. Section 3. Hazard Identification Emergency Overview DANGER! CAUSES SEVERE EYE AND SKIN BURNS. MAY BE FATAL IF SWALLOWED. Do not get in eyes, on skin or on clothing. Do not ingest. Do not breathe vapor or mist. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Potential Acute Health Effects See Section #11: "Toxicological Information" for further human health effects. Very dangerous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant), of inhalation. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Note to Physician Not available. Continued on Next Page July 08 2004 Validated on 7/8/2004. Muriatic Muriatic Acid Acid Page: 2/5 Section 4. First Aid Measures Eye Contact IMMEDIATELY flush eyes with running water for at least 15 minutes, keeping eyelids open. SEEK IMMEDIATE MEDICAL ATTENTION. Skin Contact If the chemical got onto the clothed portion of the body, remove the contaminated clothes as quickly as possible. Place the victim under a deluge shower. Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Seek medical attention. Wash contaminated clothing before reusing. Inhalation Allow the victim to rest in a well ventilated area. Seek medical attention. Ingestion DO NOT induce vomiting. Have conscious person drink several glasses of water or milk. Seek medical attention. Section 5. Fire Fighting Measures Products of Combustion Not applicable. Fire Fighting Media and Instructions Use DRY chemicals, CO2, water spray or foam. Fire Hazards Flammable hydrogen gas may be produced on prolonged contact with metals. Explosion Hazards Flammable hydrogen gas may be produced on prolonged contact with metals. Section 6. Accidental Release Measures Small Spill and Leak Dilute with water and mop up, or absorb with an inert DRY material and place in an appropriate waste disposal container. If necessary: Neutralize the residue with a dilute solution of sodium carbonate. Large Spill and Leak Corrosive liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Place in appropriate container and dispose of in accordance with regional regulations. Neutralize the residue with a dilute solution of sodium carbonate. Section 7. Handling and Storage Handling Not available. Storage See Section #10 for applicable incompatible materials. May corrode metallic surfaces. Store in a polyethylene container. Keep away from incompatibles. Keep container tighltly closed in a cool, well-ventilated place. Section 8. Exposure Controls, Personal Protection Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. Personal Protection Eyes Face shield. Body Synthetic apron. Respiratory Wear appropriate respirator when ventilation is inadequate. Hands Impervious gloves. Continued on Next Page July 08 2004 Validated on 7/8/2004. Page: 3/5 Muriatic Muriatic Acid Acid Section 9. Physical and Chemical Properties Physical State and Appearance Liquid. Odour Irritant. Molecular Weight Not applicable. Taste Not available. pH (1% Soln/Water) 1 [Acidic.] Colour Clear colorless to light yellow. Boiling/Condensation Point >81°C (177.8°F) Volatility Not available. Melting/Freezing Point Not available. Evaporation Not available. Rate Specific Gravity 1.16 (Water = 1) Odour Threshold Not available. Vapour Pressure 25 mm of Hg (@ 20°C) Viscosity Not available. Vapour Density Not available. Solubility Soluble in water, methanol. VOC Content Not available. Other Properties Not available. The Product is: Non-flammable. Auto-ignition Temperature Not applicable. Flash Point Not applicable. Flammable Limits Not applicable. Fire Hazards in Presence Not applicable. of Various Substances Section 10. Stability and Reactivity Stability The product is stable. Conditions of Instability No additional remark. Incompatibility with Various Substances Reactive with oxidizing agents, metals, alkalis. Section 11. Toxicological Information Routes of Entry Skin contact. Eye contact. Inhalation. Ingestion. Toxicity to Animals Acute oral toxicity (LD50): 900 mg/kg [Rabbit.]. (Hydrochloric acid). Acute Effects on Humans Eyes Very hazardous in case of eye contact (irritant). Corrosive to eyes. Inflammation of the eye is characterized by redness, watering, and itching. Skin Very hazardous in case of skin contact (corrosive, irritant). Skin contact may produce burns. Severe over-exposure can result in death. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Inhalation Very hazardous in case of inhalation. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Over-exposure by inhalation may cause respiratory irritation. May be fatal if inhaled. Continued on Next Page July 08 2004 Validated on 7/8/2004. Page: 4/5 Muriatic Muriatic Acid Acid Ingestion May be fatal if swallowed. May cause burns to mouth, throat and stomach. Chronic Effects on Humans CARCINOGENIC EFFECTS: Classified NONE. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many human organs. Section 12. Ecological Information Ecotoxicity For accidential discharges into environment, see Section #6: "Accidential Release Measures" for suggested instructions. Not available. Section 13. Disposal Considerations Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Section 14. Transport Information Canada Transportation of Dangerous Goods (TDG) Information Primary Class Subsidiary Class (if applicable) Class 8: Corrosive material Proper shipping name Hazard Identification Number Packing Group hydrochloric acid 1789 Special Provisions In containers of 1 L (1Kg) capacity or less this product is classified as a "Limited Quantities""Consumer Commodity" under TDG regulations. 8 II International Maritime Dangerous Goods (IMDG) Transportation Information Primary Class Subsidiary Class (if applicable) Class 8: Corrosive material Proper shipping name Hazard Identification Number Packing Group Hydrochloric acid 1789 Marine Pollutant Special Provisions Not pollutant. - II - United States Department of Transportation (DOT) Information Continued on Next Page 8 No placard (handling and hazard label) required. July 08 2004 Validated on 7/8/2004. Page: 5/5 Muriatic Muriatic Acid Acid Primary Class Class 8: Corrosive material Subsidiary class (if applicable) - Proper shipping name Hazard Identification Number Packing Group hydrochloric acid Special Provisions In containers of 1 L (1Kg) this product is qualified as a "consumer commodity" ORM-D under DOT International Air Transport Association (IATA) For air shipment classification and associated regulations, please refer to the latest edition of IATA Dangerous Goods Regulations. CORROSIVE 8 1789 II Section 15. Other Regulatory Information and Pictograms WHMIS Classification (Canada) Canada Domestic Substances List (DSL) Status Class D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). Class E: Corrosive liquid. This product and/ or all of its components are on the DSL. HCS Classification (U.S.A.) Corrosive Material U.S.A. Regulatory Lists This product and/ or all of its components are on the TSCA inventory list. Hazardous Material Information System (U.S.A.) Health Flammability Reactivity Personal Protection 3 0 2 D National Fire Protection Association (U.S.A.) Flammability Health 0 3 2 Reactivity Specific Hazard Section 16. Other Information Validated and verified by Compliance and Technical Information Manager on 7/8/2004. July 08 2004 Printed 7/8/2004. July 08 2004 Notice to Reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. MSDS are available at www.recochem.com MATERIAL SAFETY DATA SHEET Page 1 of 5 GLB Stain Magnet 1. Product And Company Identification Supplier GLB 1400 Bluegrass Lakes Parkway Alpharetta, GA 30004 United States Manufacturer Advantis Technologies, Inc. 1400 Bluegrass Lakes Parkway Alpharetta, GA 30004 United States Telephone Number: (770)521-5999 FAX Number: (770)521-5959 Web Site: www.poolspacare.com Telephone Number: (770) 521-5999 FAX Number: (770) 521-5959 Web Site: www.poolspacare.com Supplier Emergency Contacts & Phone Number CHEMTREC - DAY OR NIGHT: (800) 424-9300 Manufacturer Emergency Contacts & Phone Number CHEMTREC - DAY OR NIGHT: (800) 424-9300 Issue Date: 03/05/2004 Product Name: GLB Stain Magnet Chemical Family: Formulated Stain Remover Chemical Formula: Proprietary Mixture MSDS Number: 32 2. Composition/Information On Ingredients Ingredient Name CAS Number SODIUMERYTHROBATE 6381-77-7 SODIUMSULFITE 7757-83-7 Percent Of Total Weight Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as carcinogens are listed if they comprise 0.1% or more of the composition. Information on proprietary materials is available in 29CFR 1910.1200(i)(1). 3. Hazards Identification Primary Routes(s) Of Entry Skin Contact Eye Hazards Causes eye irritation. Skin Hazards Causes skin irritation. Ingestion Hazards Harmful if swallowed. May cause colic and diarrhea, circulatory disturbances, CNS depression and Death. If ingested, get immediate medical attention Inhalation Hazards May cause respiratory tract irritation. May cause Central Nervous System effects. May cause delayed lung injury. Signs And Symptoms Irritation of Eyes, Skin and Respiratory Passages MATERIAL SAFETY DATA SHEET Page 2 of 5 GLB Stain Magnet First Aid (Pictograms) 4. First Aid Measures Eye In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Call a physician or a poison control center immediately. Skin Wash the affected area under tepid running water using a mild soap. Get medical attention immediately if irritation (redness, rash, blistering) develops and persists. Ingestion If swallowed, induce vomiting immediately. Call a physician or a poison control center immediately. Inhalation If inhaled, remove to fresh air.If breathing is difficult, give oxygen. Consult Physician Fire Fighting (Pictograms) 5. Fire Fighting Measures Flash Point: N/A °F Flammability Class: NOT FLAMMABLE Extinguishing Media Use CO2 (Carbon Dioxide), dry chemical, or foam. Fire Fighting Instructions Firefighters should wear self-contained breathing apparatus and full protective gear. Water can be used to cool, protect exposed material and knock down fumes. 6. Accidental Release Measures Sweep up and remove immediately.Flood with water in accordance with applicable regulations. Handling & Storage (Pictograms) 7. Handling And Storage Handling And Storage Precautions Keep out of reach of children. Wear necessary protective equipment. If substantial dust in in the air take measures to remove sources of ignition to prevent possible dust combustion or explosion. Promptly ventilate area. Keep containers tightly closed. Keep away from Acids and Oxiders Handling Precautions Avoid creating dust. Avoid contact with eyes. Use NIOSH/MSHA approved mist respirator. MATERIAL SAFETY DATA SHEET GLB Stain Magnet 7. Handling And Storage - Continued Work/Hygienic Practices Use safe chemical handling procedures suitable for the hazards presented by this material. Protective Clothing (Pictograms) 8. Exposure Controls/Personal Protection Engineering Controls Use with adequate ventilation if dusty conditions prevail or sulfur dioxide gas is released. Eye/Face Protection Safety glasses with side shields or goggles recommended. Skin Protection Chemical-resistant gloves. Respiratory Protection Use NIOSH/MSHA approved dust and mist respirator Ingredient(s) - Exposure Limits SODIUM SULFITE PEL TLV 5ppm 2ppm Full Work Clothing, including long sleeved shirt and trousers required. 9. Physical And Chemical Properties Appearance White Granules Odor None Chemical Type: Mixture Physical State: Solid Melting Point: NOT DETERMINED °F Specific Gravity: 1.2-2.7 Molecular Weight: NOT DETERMINED Percent Volitales: NOT DETERMINED Vapor Pressure: NOT APPLICABLE Vapor Density: NOT APPLICABLE pH Factor: 8-10 At a Concentration Of 1% SOLUTION IN WATER Solubility: SOLUBLE IN WATER Evaporation Rate: NOT APPLICABLE 10. Stability And Reactivity Sta bility: Stable Hazardous Polymerization: Will not occur Conditions To Avoid (Stability) High temperatures. Before melting may yield sulfur dioxide with a hazardous residue Incompatible Materials Avoid contact with strong acids and oxidizers Page 3 of 5 MATERIAL SAFETY DATA SHEET Page 4 of 5 GLB Stain Magnet 10. Stability And Reactivity - Continued Hazardous Decomposition Products Sulfur dioxide gas and sodium sulfide residue 11. Toxicological Information No Data Available... 12. Ecological Information No Data Available... 13. Disposal Considerations Dissolve in water, using caution as solution may increase in temperature. Neutralize with acid and flush to sewer if in accordance with applicable federal, state and local government regulations. Good ventilation is required during neutralization due to the release of SO2 gas. Oxidation to sodium sulfate solution may be required, as for example by adding a slight excess hydrogen peroxide carefully and stirring. Neutralized waste may have to be disposed of by a contractor. 14. Transport Information Proper Shipping Name NOT REGULATED Hazard Class NOT REGULATED DOT Identification Number NONE 15. Regulatory Information Canadian Regulatory Information Class D, Div 2b - Poisonous or Infectious Material: other toxic effects Class C - Oxidizing Material WHMIS - Canada (Pictograms) NFPA HMIS 0 1 0 HEALTH 2 FLAMMABILITY 0 REACTIVITY 0 PERSONAL B PROTECTION 16. Other Information Revision/Preparer Information MSDS Preparer: JHW3 This MSDS Superceeds A Previous MSDS Dated: 07/21/2000 Disclaimer Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitablility of this information for the user's intended purposes MATERIAL SAFETY DATA SHEET Page 5 of 5 GLB Stain Magnet Disclaimer - Continued or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purposes(s). GLB Printed Using MSDS Generator™ 2000 MATERIAL SAFETY DATA SHEET GLB Natural Clear 1. Product And Company Identification Supplier GLB 1400 Bluegrass Lakes Parkway Alpharetta, GA 30004 United States Manufacturer Advantis Technologies, Inc. 1400 Bluegrass Lakes Parkway Alpharetta, GA 30004 United States Telephone Number: (770)521-5999 FAX Number: (770)521-5959 Web Site: www.poolspacare.com Telephone Number: (770) 521-5999 FAX Number: (770) 521-5959 Web Site: www.poolspacare.com Supplier Emergency Contacts & Phone Number CHEMTREC - DAY OR NIGHT: (800) 424-9300 Manufacturer Emergency Contacts & Phone Number CHEMTREC - DAY OR NIGHT: (800) 424-9300 Issue Date: 04/16/2007 Product Name: GLB Natural Clear Chemical Name: Enzymatic Cleaner CAS Number: Not Established Chemical Family: Enzyme Chemical Formula: Proprietary MSDS Number: 21 2. Composition/Information On Ingredients Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as carcinogens are listed if they comprise 0.1% or more of the composition. Information on proprietary materials is available in 29CFR 1910.1200(i)(1). 3. Hazards Identification Primary Routes(s) Of Entry Eye Contact, Skin Contact Eye Hazards May cause eye irritation. Skin Hazards May cause skin irritation. Ingestion Hazards If ingested, get immediate medical attention Inhalation Hazards None known First Aid (Pictograms) 4. First Aid Measures No Data Available... Page 1 of 4 MATERIAL SAFETY DATA SHEET GLB Natural Clear 4. First Aid Measures - Continued Eye In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Skin Remove contaminated clothing and shoes. Wash affected areas with soap and water. Ingestion DO NOT INDUCE VOMITING. Drink large amounts of water. Contact a physician or poison control. Inhalation No known hazard Fire Fighting (Pictograms) 5. Fire Fighting Measures Flash Point: n/a °F Extinguishing Media Use the appropriate extinguishing media for the surrounding fire. Fire Fighting Instructions Firefighters should wear self-contained breathing apparatus and full protective gear. 6. Accidental Release Measures Clean up spill immediately. Contain and/or absorb spill with inert material (e.g. sand, vermiculite). 7. Handling And Storage Handling And Storage Precautions Keep out of reach of children. Store material in a cool and dry place. Storage Precautions Keep out of reach of children. Store in a cool dry place. Work/Hygienic Practices Use safe chemical handling procedures suitable for the hazards presented by this material. Protective Clothing (Pictograms) 8. Exposure Controls/Personal Protection Engineering Controls Local exhaust acceptable. Special exhaust not required Eye/Face Protection Safety glasses with side shields or goggles. Skin Protection Chemical-resistant gloves. Page 2 of 4 MATERIAL SAFETY DATA GLB Natural Clear 8. Exposure Controls/Personal Protection - Continued Respiratory Protection None normally required. 9. Physical And Chemical Properties Appearance Clear yellow liquid Odor Floral Chemical Type: Mixture Physical State: Liquid Melting Point: NOT DETERMINED °F Boiling Point: 212 °F Specific Gravity: 0.99-1.1 Percent Volitales: Nil Packing Density: NOT DETERMINED Vapor Pressure: NOT DETERMINED Vapor Density: >AIR pH Factor: 6-8 Solubility: SOLUBLE IN WATER 10. Stability And Reactivity Stability: Stable Hazardous Polymerization: Will not occur Conditions To Avoid (Stability) None Known Incompatible Materials None known 11. Toxicological Information No Data Available... 12. Ecological Information No Data Available... 13. Disposal Considerations Dispose in accordance with applicable federal, state and local government regulations. 14. Transport Information Proper Shipping Name NON REGULATED Hazard Class NON REGULATED DOT Identification Number NONE DOT Shipping Label NOT ASSIGNED Page 3 of 4 SHEET MATERIAL SAFETY DATA SHEET GLB Natural Clear 15. Regulatory Information Canadian Regulatory Information Class D, Div 2b - Poisonous or Infectious Material: other toxic effects WHMIS - Canada (Pictograms) NFPA HMIS 0 1 0 HEALTH 1 FLAMMABILITY 0 REACTIVITY 0 PERSONAL B PROTECTION 16. Other Information Revision/Preparer Information MSDS Preparer: JHW Disclaimer Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitablility of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purposes(s). GLB Printed Using MSDS Generator™ 2000 Page 4 of 4 MATERIAL SAFETY DATA SHEET Page 1 of 4 Leisure Time Foam Down 1. Product And Company Identification Supplier Leisure Time 1400 Bluegrass Lakes Parkway Alpharetta, GA 30004 United States Manufacturer Advantis Technologies, Inc. 1400 Bluegrass Lakes Parkway Alpharetta, GA 30004 United States Telephone Number: (770) 521-5999 FAX Number: (770) 521-5959 Web Site: www.poolspacare.com Telephone Number: (770) 521-5999 FAX Number: (770) 521-5959 Web Site: www.poolspacare.com Supplier Emergency Contacts & Phone Number CHEMTREC - DAY OR NIGHT: (800) 424-9300 Manufacturer Emergency Contacts & Phone Number CHEMTREC - DAY OR NIGHT: (800) 424-9300 Issue Date: 09/01/2004 Product Name: Leisure Time Foam Down Chemical Family: Silicone Emulsion Chemical Formula: Proprietary MSDS Number: 25 2. Composition/Information On Ingredients Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as carcinogens are listed if they comprise 0.1% or more of the composition. Information on proprietary materials is available in 29CFR 1910.1200(i)(1). 3. Hazards Identification Primary Routes(s) Of Entry Skin Contact Eye Hazards Causes eye irritation. Skin Hazards May cause skin irritation. Ingestion Hazards May be harmful if swallowed. Inhalation Hazards None normally associated with this product First Aid (Pictograms) 4. First Aid Measures Eye In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Skin In case of contact, immediately flush skin with soap and plenty of water. MATERIAL SAFETY DATA SHEET Page 2 of 4 Leisure Time Foam Down 4. First Aid Measures - Continued Ingestion If swallowed, induce vomiting immediately. Call a physician or a poison control center immediately. Inhalation If inhaled, remove to fresh air. If breathing is difficult, give oxygen. Fire Fighting (Pictograms) 5. Fire Fighting Measures Flash Point: n/a °F Fire And Explosion Hazards Burning causes oxides of carbon and silicone Extinguishing Media Use the appropriate extinguishing media for the surrounding fire. Fire Fighting Instructions Firefighters should wear self-contained breathing apparatus and full protective gear. 6. Accidental Release Measures Contain and/or absorb spill with inert material (e.g. sand, vermiculite). Collect and dispose. Flush spill area with water. 7. Handling And Storage Handling And Storage Precautions Keep out of reach of children. Store material in a cool and dry place. Work/Hygienic Practices Use safe chemical handling procedures suitable for the hazards presended by this material. Protective Clothing (Pictograms) 8. Exposure Controls/Personal Protection Engineering Controls Local exhaust acceptable. Special exhaust not required Eye/Face Protection Safety glasses with side shields or goggles. Skin Protection Chemical-resistant gloves. Respiratory Protection None normally required. 9. Physical And Chemical Properties Appearance Creamy white liquid MATERIAL SAFETY DATA SHEET Leisure Time Foam Down 9. Physical And Chemical Properties - Continued Odor Mild Chemical Type: Mixture Physical State: Liquid Melting Point: n/a °F Boiling Point: 212 °F Specific Gravity: 1.0 Percent Volitales: NOT ESTABLISHED Vapor Pressure: NOT ESTABLISHED Vapor Density: NOT ESTABLISHED pH Factor: 6-7 Solubility: SOLUBLE IN WATER Viscosity: NOT ESTABLISHED Evaporation Rate: NOT ESTABLISHED 10. Stability And Reactivity Sta bility: Stable Hazardous Polymerization: Will not occur Incompatible Materials Strong Oxidants Hazardous Decomposition Products Burning causes oxides of carbon and silicone 11. Toxicological Information No Data Available... 12. Ecological Information No Data Available... 13. Disposal Considerations Dispose in accordance with applicable federal, state and local government regulations. 14. Transport Information Proper Shipping Name NOT REGULATED Hazard Class NOT REGULATED DOT Identification Number NONE 15. Regulatory Information No Data Available... Page 3 of 4 MATERIAL SAFETY DATA SHEET Page 4 of 4 Leisure Time Foam Down NFPA HMIS 0 1 0 HEALTH 1 FLAMMABILITY 0 REACTIVITY 0 PERSONAL B PROTECTION 16. Other Information Revision/Preparer Information MSDS Preparer: JHW3 Disclaimer Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitablility of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purposes(s). Leisure Time Printed Using MSDS Generator™ 2000 Vanson HaloSource, Inc Material Safety Data Sheet Material Name: SeaKlear® Natural Clarifier for Pools Telephone No: 425-881-6464 VHI-MSDS-02.13 Rev 03 Date Prepared: 04-28-05 24-HOUR EMERGENCY PHONE: CHEMTREC 800-424-9300 SECTION I – CHEMICAL PRODUCT & COMPANY IDENTIFICATION Manufacturer's Name: Corporate Address: Emergency Phone: Manufacturer's Phone: Material Name: Chemical Name: Vanson HaloSource, Inc. 14716 NE 87th Street, Redmond, WA 98052 800-424-9300 Chemtrec (425) 881-6464 SeaKlear Natural Clarifier Chitosan acetate SECTION II – COMPOSITION, INFORMATION ON INGREDIENTS CAS NO. 9012-76-4 64-19-7 INGREDIENT EXPOSURE LIMITS Chitosan Acetic Acid Water NA SECTION III – HAZARDS IDENTIFICATION PRINCIPAL HEALTH HAZARDS, INCLUDING SIGNIFICANT ROUTES, EFFECTS, AND SYMPTOMS OF OVEREXPOSURE AND MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE MAY BE: EYE: May be mildly irritating to eyes. SKIN: Not hazardous to skin. INHALATION: See first aid section below. INGESTION: Not likely to be hazardous by ingestion. CARCINOGENICITY: Not listed by National Toxicology Program (NTP) OSHA, or International Agency for Research on Cancer (IARC) SECTION IV - FIRST AID EYES: Remove contact lenses (if applicable), flush with water for 15 minutes. Call a physician. SKIN: Cleansing the skin after exposure is advisable. INHALATION: If large amounts of fumes are inhaled, remove to fresh air and consult a physician. INGESTION: Consult a physician if necessary. Page 1 of 5 Vanson HaloSource, Inc Material Safety Data Sheet Material Name: SeaKlear® Natural Clarifier for Pools Telephone No: 425-881-6464 VHI-MSDS-02.13 Rev 03 Date Prepared: 04-28-05 SECTION V - FIRE FIGHTING MEASURES HAZARDOUS COMBUSTION PRODUCTS: NA EXTINGUISHING MEDIA: Does not burn. Use water, dry chemicals, carbon dioxide, sand or foam. Use extinguishing media appropriate for surrounding fire. FIREFIGHTING INSTRUCTIONS: Do not enter confined fire space without full bunker gear (helmet with face shield, bunker coat, gloves and rubber boots), including a positive pressure NIOSH approved self-contained breathing apparatus. Water may be used to keep fire-exposed containers cool until fire is out. FLASH POINT: NA SECTION VI – ACCIDENTAL RELEASE MEASURES SPILL: Wear suitable protective clothing. Dilute with water and hose down. DISPOSAL INFORMATION: Material is 100% biodegradable, is nontoxic and can be disposed of in any approved manner. Treatment, storage, transportation and disposal must be in accordance with applicable Federal State/Provincial and local regulations. DISPOSAL METHODS: Dilute with water and hose down. SECTION VII - HANDLING & STORAGE HANDLING & STORAGE PRECAUTIONS: 10-50°C recommended (will freeze @ ~3°C). Shelf life is indefinite but viscosity will decrease over time. The container should be kept covered to prevent contamination. SECTION VIII - EXPOSURE CONTROLS/ PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT (PPE): Good hygiene practices should be strictly followed. Before eating, drinking or smoking, wash face and hands thoroughly. Emergency showers and eyewash facilities should be accessible. EYE PROTECTION: Safety glasses recommended. SKIN PROTECTION: Rubber gloves recommended. PROTECTIVE CLOTHING: NA Page 2 of 5 Vanson HaloSource, Inc Material Safety Data Sheet Material Name: SeaKlear® Natural Clarifier for Pools Telephone No: 425-881-6464 VHI-MSDS-02.13 Rev 03 Date Prepared: 04-28-05 PROTECTIVE FOOTWEAR: NA RESPIRATORY PROTECTION: NA . VENTILATION REQUIREMENTS: Generally adequate SECTION IX - PHYSICAL & CHEMICAL PROPERTIES PHYSICAL FORM: Clear to pale yellow viscous liquid with a pungent vinegar odor. BOILING POINT: 211°F MELTING POINT: NA pH: 3.0-4.5 SOLUBILITY IN WATER: Soluble. SPECIFIC GRAVITY: 1.0-1.1 g/mL SECTION X - STABILITY & REACTIVITY DATA CHEMICAL STABILITY: Stable. HAZARDOUS POLYMERIZATION: Will not occur. INCOMPATIBLES: Strong oxidizing material and strong bases. DECOMPOSITION PRODUCTS: Decomposition will not occur. Material is bio-degradable. SECTION XI - TOXICOLOGICAL INFORMATION ORAL Rat LD50 (MG/KG): NA NA Ipr Rat, LD50(MG/KG): SCU Mouse, LD50(MG/KG): NA IV-Mouse, LD50(MG/KG): NA DERMAL LD50 (rabbit): NA EYE IRRITATION (rabbit): NA SKIN IRRITATION (rabbit): NA Page 3 of 5 Vanson HaloSource, Inc Material Safety Data Sheet Material Name: SeaKlear® Natural Clarifier for Pools Telephone No: 425-881-6464 VHI-MSDS-02.13 Rev 03 Date Prepared: 04-28-05 SECTION XII - ECOLOGICAL INFORMATION Fish 96-hour LC50 Daphnia 48-hour LC50 Green algae 96-hour EC50 Fish Chronic Value (ChV) Daphnia ChV Algae ChV = = = = = = NA NA NA NA NA NA SECTION XIII - DISPOSAL CONSIDERATION WASTE DISPOSAL METHOD: Dispose of in accordance with all applicable federal, local and State environmental regulations. Material is 100% biodegradable, is nontoxic and can be disposed of in any approved manner. SECTION XIV - TRANSPORTATION INFORMATION DOT Proper Shipping Name: DOT Hazard Class: Packing Group: UN Number: Product RQ (lbs.): DOT Label: DOT Placard: Chemicals, N.O.S. (non-regulated) (Domestic & International) Not regulated as a hazardous material NA NA NA NA NA SECTION XV - REGULATORY INFORMATION MATERIAL IS REPORTED IN EPA TSCA INVENTORY LIST?: No MATERIAL IS LISTED AS A CARCINOGEN/POTENTIAL CARCINOGEN IN FOLLOWING?: No NTP ANNUAL REPORT: No IARC GROUP I OR II: No OSHA 29CFR PART 1910 SUBPART Z: No DOES PRODUCT CONTAIN A TOXIC CHEMICAL SUBJECT TO SARA TITLE III SECTION 313 REPORTING: No SARA TITLE III SECTION 311/312 CLASSIFICATIONS: None Page 4 of 5 Vanson HaloSource, Inc Material Safety Data Sheet Material Name: SeaKlear® Natural Clarifier for Pools Telephone No: 425-881-6464 VHI-MSDS-02.13 Rev 03 Date Prepared: 04-28-05 SECTION XVI – OTHER INFORMATION The above information is based upon information Vanson-HaloSource, Inc. believes to be reliable and is supplied for informational purposes only. Vanson-HaloSource, Inc. disclaims any liability for damage which results from the use of the above information and nothing contained therein shall constitute a guarantee, warranty (including fitness for a particular purpose) or representation with respect to the accuracy or completeness of the data, the product described or their use for any specific purpose even if that purpose is known to Vanson-HaloSource, Inc. The final determination of the suitability of the information, the manner of use of the information or product and potential infringement is the sole responsibility of the user. Page 5 of 5 MATERIAL SAFETY DATA SHEET GLB TLC 1. Product And Company Identification Supplier GLB 1400 Bluegrass Lakes Parkway Alpharetta, GA 30004 United States Manufacturer Advantis Technologies Inc. 1400 Bluegrass Lakes Parkway Alpharetta, GA 30004 United States Telephone Number: (770)521-5999 FAX Number: (770)521-5959 Web Site: www.poolspacare.com Telephone Number: (770) 521-5999 FAX Number: (770) 521-5959 Web Site: www.poolspacare.com Supplier Emergency Contacts & Phone Number CHEMTREC - DAY OR NIGHT: (800) 424-9300 Manufacturer Emergency Contacts & Phone Number CHEMTREC - DAY OR NIGHT: (800) 424-9300 Issue Date: 04/01/2005 Product Name: GLB TLC CAS Number: Not Established Chemical Family: Acid Mixture Chemical Formula: Proprietary MSDS Number: 19 Product Code: Proprietary 2. Composition/Information On Ingredients Ingredient Name CAS Number Bis(2-hydroxyethyl)tallowammonium ethanoate Percent Of Total Weight 70750-46-8 HYDROCHLORIC ACID 7647-01-0 PHOSPHORICACID 7664-38-2 SULFURIC ACID 7664-93-9 Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as carcinogens are listed if they comprise 0.1% or more of the composition. Information on proprietary materials is available in 29CFR 1910.1200(i)(1). Hazards Identification (Pictograms) 3. Hazards Identification Primary Routes(s) Of Entry Eye Contact, Skin Contact Eye Hazards Causes severe eye burns. Skin Hazards Causes severe skin burns. Page 1 of 6 MATERIAL SAFETY DATA SHEET GLB TLC 3. Hazards Identification - Continued Ingestion Hazards Corrosive to living tissue. Inhalation Hazards May cause severe allergic respiratory reaction. Signs And Symptoms Irritation of Eyes, Skin and Respiratory Passages First Aid (Pictograms) 4. First Aid Measures Eye In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes.Call a physician or a poison control center immediately. Skin Rinse the affected area with tepid water for at least 15 minutes.Get medical attention immediately if irritation (redness, rash, blistering) develops and persists. Ingestion DO NOT INDUCE VOMITING. Drink large amounts of water. Contact a physician or poison control. Inhalation If inhaled, remove to fresh air. If breathing is difficult, give oxygen. Call a physician or a poison control center immediately. Fire Fighting (Pictograms) 5. Fire Fighting Measures Flash Point: N/A °F Extinguishing Media Use the appropriate extinguishing media for the surrounding fire. Fire Fighting Instructions Water can be used to cool and protect exposed material. Firefighters should wear self-contained breathing apparatus and full protective gear. 6. Accidental Release Measures Neutralize spill area with soda ash or lime. Flood with water. Use appropriate containers to avoid environmental contamination. Use appropriate personal protective equipment (PPE). 7. Handling And Storage Handling And Storage Precautions Keep out of reach of children. Do not store with alkalis. Page 2 of 6 MATERIAL SAFETY DATA SHEET GLB TLC 7. Handling And Storage - Continued Handling Precautions Avoid contact with eyes. Avoid contact with skin and clothing. Wash thoroughly after handling. Storage Precautions Avoid contact with Alkalis, Amines, and Metals. Keep out of reach of children. Work/Hygienic Practices Use safe chemical handling procedures suitable for the hazards presended by this material. Protective Clothing (Pictograms) 8. Exposure Controls/Personal Protection Engineering Controls Local exhaust acceptable. Special exhaust not required Eye/Face Protection Safety glasses with side shields or goggles recommended. Skin Protection Chemical-resistant gloves. Respiratory Protection None normally required. Ingredient(s) - Exposure Limits Bis(2-hydroxyethyl)tallowammonium ethanoate NOT ESTABLISHED HYDROCHLORIC ACID ACGIH TLV-CEILING 5 ppm OSHA PEL-CEILING 5 ppm PHOSPHORIC ACID ACGIH TLV-STEL 3 mg/m3 ACGIH TLV-TWA 1 mg/m3 OSHA PEL-TWA 1 mg/m3 SULFURIC ACID ACGIH TLV-STEL 3 mg/m3 ACGIH TLV-TWA 1 mg/m3 OSHA PEL-TWA 1 mg/m3 9. Physical And Chemical Properties Appearance Pale amber liquid Odor Mild Chemical Type: Mixture Physical State: Liquid Melting Point: n/a °F Boiling Point: 212 °F Specific Gravity: 1.1-1.2 Percent Volitales: NOT DETERMINED Page 3 of 6 MATERIAL SAFETY DATA SHEET GLB TLC 9. Physical And Chemical Properties - Continued Odor - Continued Packing Density: NOT DETERMINED Vapor Pressure: NOT DETERMINED Vapor Density: >1 pH Factor: 0-2 Solubility: Soluble in Water Viscosity: NOT DETERMINED Evaporation Rate: <1 10. Stability And Reactivity Sta bility: Stable Hazardous Polymerization: Will not occur Conditions To Avoid (Stability) Avoid contact with strong Amines, Alkalis, and Metals. Heat can cause hydrogen chloride. Incompatible Materials Alkalis, Amines and Metals Hazardous Decomposition Products Hydrogen Chloride 11. Toxicological Information Ingredient(s) - Carginogenicity SULFURIC ACID NTP - Listed On The National Toxicology Program Listed In The IARC Monographs 12. Ecological Information No Data Available... 13. Disposal Considerations Refer to applicable federal, state, and local regulations prior to disposition of container and residual contents. 14. Transport Information Proper Shipping Name Corrosive Liquid, Acidic, Inorganic, N.O.S. (Hydrochloric and Sulfuric Acids) Hazard Class 8, PGII (<1L Consumer Commodity ORM-D) DOT Identification Number UN3264 DOT (Pictograms) 15. Regulatory Information Ingredient(s) - U.S. Regulatory Information HYDROCHLORIC ACID SARA Title III - Section 313 Form "R"/TRI Reportable Chemical SARA - Acute Health Hazard Page 4 of 6 MATERIAL SAFETY DATA SHEET GLB TLC 15. Regulatory Information - Continued Ingredient(s) - U.S. Regulatory Information - Continued SULFURIC ACID SARA Title III - EPA Part 355 Extremely Hazardous Substance SARA Title III - Section 313 Form "R"/TRI Reportable Chemical SARA - Acute Health Hazard SARA - Chronic Health Hazard SARA - Fire Hazard SARA - Reactivity Hazard Ingredient(s) - State Regulations HYDROCHLORIC ACID New Jersey - Workplace Hazard New Jersey - Environmental Hazard New Jersey - Special Hazard New Jersey - TCPA Extraordinarily Hazardous Substance Pennsylvania - Workplace Hazard Pennsylvania - Environmental Hazard Massachusetts - Hazardous Substance New York City - Hazardous Substance SULFURIC ACID New Jersey - Workplace Hazard New Jersey - Environmental Hazard New Jersey - Special Hazard Pennsylvania - Workplace Hazard Pennsylvania - Environmental Hazard California - CalARP Table 3 Regulated Substance Massachusetts - Hazardous Substance New York City - Hazardous Substance Canadian Regulatory Information Class D, Div 1a - Poisonous or Infectious Material: immediate and serious toxic effects Class D, Div 2a - Poisonous or Infectious Material: other toxic effects Class D, Div 2b - Poisonous or Infectious Material: other toxic effects Class E - Corrosive Material WHMIS - Canada (Pictograms) NFPA HMIS 1 2 2 HEALTH 3 FLAMMABILITY 0 REACTIVITY 1 PERSONAL C PROTECTION 16. Other Information Revision/Preparer Information MSDS Preparer: JHW Page 5 of 6 MATERIAL SAFETY DATA SHEET GLB TLC Disclaimer Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitablility of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purposes(s). GLB Printed Using MSDS Generator™ 2000 Page 6 of 6 Product #DESP Page 1 of 7 MATERIAL SAFETY DATA SHEET Diatomaceous Earth Section 01 - Chemical And Product And Company Information Product Identifier ……………………... Diatomaceous earth; Celatom FP-4, FW-10, FW-12, FW-14, FW-18, FW-20, FW-40, FW-50, FW-60, FW-70, FW-80, or SP Product Use …………………………..... Filter aid Supplier Name……………………….…. ClearTech Industries Inc. 2303 Hanselman Avenue Saskatoon, SK. Canada S7L 5Z3 Prepared By................……………..….. ClearTech Industries Inc. Technical Department Phone: (306)664-2522 Preparation Date.........…………….…... August 18, 2005 24-Hour Emergency Phone…………... 306-664-2522 Section 02 - Composition / Information on Ingredients Hazardous Ingredients....………….... Diatomaceous Earth, Flux-Calcined(Diatomite) 100% Crystalline silica(Cristobalite) 35-50% CAS Number...................…….…….....Diatomaceous Earth, Flux-Calcined(Diatomite) 68855-54-9 Crystalline silica(Cristobalite) 14464-46-1 Synonym (s)...................……………...Aqua-cel; flux calcined diatomaceous earth Section 03 - Hazard Identification Inhalation...................………….….... Upper respiratory irritant. May cause coughing or throat irritation. Breathing dust containing crystalline silica over a long period may cause lung damage. Product #DESP Page 2 of 7 Skin Contact / Absorption…….….... May cause slight irritation. Eye Contact................………….….... May cause slight irritation. Ingestion.....................………………. May cause slight irritation. Not hazardous when digested. Exposure Limits……………………... ACGIH/TLV: 0.05 mg/m3 (cristobalite) ACGIH/TLV: 0.10 mg/m3 (silica, crystalline quartz), local regulated limits may vary. Section 04 - First Aid Measures Inhalation....................……………….. Remove victim to fresh air. Give artificial respiration only if breathing has stopped. If breathing is difficult, give oxygen. Seek immediate medical attention. Skin Contact / Absorption………….. Remove contaminated clothing. Wash affected area with soap and water. Seek medical attention if irritation occurs or persists. Eye Contact..................…………….... Flush immediately with water for at least 20 minutes. Forcibly hold eyelids apart to ensure complete irrigation of eye tissue. Seek immediate medical attention Ingestion......................………………. No known health effects with short-term exposure. Drink water to reduce bulk and drying effects. Seek immediate medical attention if there is irritation. Additional Information.....…………... Not available Section 05 - Fire Fighting Conditions of Flammability……….... Non-flammable Means of Extinction........…………..... Product does not burn. Use appropriate extinguishing media for material that is supplying the fuel to the fire. Flash Point....………………………….. Not applicable Auto-ignition Temperature…………. Not applicable Upper Flammable Limit …………….. Not applicable Product #DESP Page 3 of 7 Lower Flammable Limit...……….…... Not applicable Hazardous Combustible Products... Not applicable Special Fire Fighting Procedures..... Wear NIOSH-approved protective clothing. self-contained breathing apparatus and Explosion Hazards………………….... Not applicable Section 06 - Accidental Release Measures Leak / Spill................….……………... Diatomaceous earth is a non-toxic, non-biodegradable mineral. Waste generated from this product would only be considered hazardous when mixed with a substance that would be considered hazardous. Flush area with water to remove any residue. Deactivating Materials...……….…... None Section 07 - Handling and Storage Handling Procedures.......…………... Use proper equipment for lifting and transporting all containers. Use sensible industrial hygiene and housekeeping practices. Wash thoroughly after handling. Avoid all situations that could lead to harmful exposure. Storage Requirements......……...….. Store in a cool, dry, well-ventilated place. Keep container tightly closed, and away from incompatible materials. Section 08 - Personal Protection and Exposure Controls Protective Equipment Eyes.………………………….………... Chemical goggles, full-face shield, or a full-face respirator is to be worn at all times when product is handled. Contact lenses should not be worn; they may contribute to severe eye injury. Respiratory………………………….... NIOSH approved respirators (standard 42CFR84, series N95) for protection against pneumoconiosis producing dusts recommended when dust is present. Gloves………………………………..... Impervious gloves of chemically resistant material (rubber or PVC) should be worn at all times. Wash contaminated clothing with soap and water, dry thoroughly before reuse. Product #DESP Page 4 of 7 Clothing………………………..…….... Body suits, aprons, and/or coveralls of chemical resistant material should be worn at all times. Wash contaminated clothing with soap and water, dry thoroughly before reuse. Footwear……………………………..... Impervious boots of chemically resistant material should be worn at all times Engineering Controls Ventilation Requirements………...... Mechanical ventilation (dilution or local exhaust), process or personnel enclosure, and control of process conditions. Supply sufficient replacement air to make up for air removed by exhaust systems. Other………………………………….... Emergency shower and eyewash should be in close proximity. Section 09 - Physical and Chemical Properties Physical State.......……....………….... Solid Odor and Appearance…..………….... Fine odourless white, buff, or pink powder Odor Threshold....……………............ Not available Specific Gravity (Water=1)………….. 2.33 Vapor Pressure (mm Hg, 20C)….….. Not available Vapor Density (Air=1)..…………….... Not available Evaporation Rate........……..…….….. Not available Boiling Point...............………….…..... Not available Freeze/Melting Point....…………….... Not available pH............................……………….….. 9-10 (10% slurry) Water/Oil Distribution Coefficient.... Not available Bulk Density..............…………….…... Varies with grade % Volatiles by Volume………..……... 0% Solubility in Water...………………..... <2% Molecular Formula......………….….... Not applicable Product #DESP Page 5 of 7 Molecular Weight........……………..... Not applicable Section 10 - Stability and Reactivity Stability.................…………....……………. Stable under normal conditions. Incompatibility..............…………..……….. Incompatible with hydrofluoric acid. Reaction with hydrofluoric acid will evolve silicon tetrafluoride. Hazardous Products of Decomposition.. Not available Polymerization...........…………….…….…. Will not occur Section 11 - Toxicological Information Irritancy.................……..………….…. May cause dryness to mucous membranes. Sensitization........…….......…………. Not available Chronic/Acute Effects……...……….. Inhalation of dust in excess of OSHA/PEL over an extended number of years may cause silicosis, a progressive and sometimes fatal lung disease. Although silicosis is a non-cancerous lung disease, crystalline silica has been determined by the International Agency for Research on Cancer to be 'probably carcinogenic to humans.' Synergistic Materials...……....……... Not available Animal Toxicity Data......…..………... Not available Carcinogenicity......……......………... IARC: crystalline silica classed as 2A; probably a human carcinogen. Reproductive Toxicity..…...………... Not available Teratogenicity..........….....…………... Not available Mutagenicity...........…….....…………. Not available Section 12 - Ecological Information Fish Toxicity..................……………... Not available Biodegradability.............……….….... Not available Environmental Effects………………. Insoluble mineral product, will not have an adverse affect on waterways. Product #DESP Page 6 of 7 Section 13 - Disposal Consideration Waste Disposal...........…...…………...Dispose in accordance with all federal, provincial, and/or local regulations including the Canadian Environmental Protection Act. Section 14 - Transportation Information TDG Classification Class……………..………………..….... Not regulated Group...............…………….......……... Not regulated PIN Number.................……..……….... Not regulated Other…………………………………..... Secure containers (full and/or empty) with suitable hold down devises during shipment. Section 15 - Regulatory Information WHMIS Classification.......…………....D2 NOTE: THE PRODUCT LISTED ON THIS MSDS HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CANADIAN CONTROLLED PRODUCTS REGULATIONS. THIS MSDS CONTAINS ALL INFORMATION REQUIRED BY THOSE REGULATIONS Section 16 - Other Information Note: The responsibility to provide a safe workplace remains with the user. The user should consider the health hazards and safety information contained herein as a guide and should take those precautions required in an individual operation to instruct employees and develop work practice procedures for a safe work environment. The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by the use of this material. It is the responsibility of the user to comply with all applicable laws and regulations. ClearTech Industries Inc. - Locations Corporate Head Office: 2302 Hanselman Avenue, Saskatoon, SK, S7L 5Z3 Phone: 306-664-2522 Fax: 306-665-6216 www.ClearTech.ca Location Richmond BC Calgary AB Edmonton AB Saskatoon SK Address 12431 Horseshoe way 5516E - 40th St. S.E. 11750 - 180th Street 2302 Hanselman Avenue Postal Code V7A 4X6 T2C 2A1 T5S 1N7 S7L 5Z3 Phone Number 604-272-4000 403-279-1096 780-452-6000 306-933-0177 Fax Number 604-272-4596 403-236-0989 780-452-4600 306-933-3282 Product #DESP Regina SK Winnipeg MB Mississauga ON Page 7 of 7 555 Henderson Drive 340 Saulteaux Crescent 7480 Bath Road S42 5X2 R3J 3T2 L4T 1L2 306-721-7737 204-987-9777 905-612-0566 306-721-8611 204-987-9770 905-612-0575 24 Hour Emergency Number - All Locations - 306-664-2522 Eli Lilly and Company Material Safety Data Sheet MSDS Index Sodium Bicarbonate Effective Date: 05-Aug-2004 Section 1 - Chemical Product and Company Emergency Phone: 1-317-276-2000 CHEMTREC: 1-800-424-9300 (North America) 1-703-527-3887 (International) Manufacturer: Eli Lilly and Company Lilly Corporate Center Indianapolis, IN 46285 Common Name: Sodium Bicarbonate CAS Number(s): 144-55-8 EINECS Number: 2056-33-8 Chemical Name: Carbonic acid monosodium salt Chemical Family: Inorganic salt Chemical Formula: C H O3 . Na Molecular Weight: 84.01 Synonym(s): Sodium bicarbonate tablets; Soludal; Meylon; Soda; Monosodium carbonate; Sodium hydrogen carbonate; Sodium acid carbonate; Bicarbonate of soda; Baking soda; Soda mint; NaHCO3; Sodium bicarbonate - cell culture grade; Sodium bicarbonate tablet mix Lilly Serial Number(s): 237728 Lilly Item Code(s): QA049K; QA116D; QA192M; QA241X; QA281L; QA384W; QA476V; QD400T; QD472B; TA1260; TA1264; TA1265 See attached glossary for abbreviations. Section 2 - Composition / Information on Ingredients Ingredient Sodium Bicarbonate CAS 144-55-8 Exposure Guidelines: Sodium bicarbonate - Exposure Guideline 1500 micrograms/m3 TWA for 12 hours, 2300 micrograms/m3 TWA for 8 hours. (Lilly-established guideline) Dow Chemical Exposure Guideline 10 mg/m3 TWA. Section 3 - Hazards Identification Appearance: White crystalline powder or granules or compressed uncoated tablets Physical State: Solid Odor: Odorless Emergency Overview Emergency Overview Effective Date: 07-Aug-2002 Lilly Laboratory Labeling Codes: Health 1 Fire 0 Reactivity 0 Primary Physical and Health Hazards: No Significant Health Hazards. Caution Statement: No significant health hazards have been reported for Sodium Bicarbonate. Routes of Entry: Inhalation and skin contact. Effects of Overexposure: Material has low acute oral or inhalation toxicity. Material may be slightly irritating to the eyes, skin, and respiratory tract. Inhalation of dust may cause coughing. Medical Conditions Aggravated by Exposure: None known. Carcinogenicity: No carcinogenicity data found. Not listed by IARC, NTP, ACGIH, or OSHA. Section 4 - First Aid Measures Eyes: Flush eyes with plenty of water. Get medical attention. Skin: Remove contaminated clothing and clean before reuse. Wash all exposed areas of skin with plenty of soap and water. Get medical attention if irritation develops. Inhalation: Move individual to fresh air. Get medical attention if breathing difficulty occurs. If not breathing, provide artificial respiration assistance (mouth-to-mouth) and call a physician immediately. Ingestion: Call a physician or poison control center. No first aid procedures are normally required. Section 5 - Fire Fighting Measures Flash Point: Not applicable UEL: Not applicable LEL: Not applicable Extinguishing Media: Use water, carbon dioxide, dry chemical, foam, or Halon. Unusual Fire and Explosion Hazards: None known. Hazardous Combustion Products: May emit toxic fumes when exposed to heat or fire. Section 6 - Accidental Release Measures Spills: Wear protective equipment, including eye protection, to avoid exposure (see Section 8 for specific handling precautions). Vacuum material with appropriate dust collection filter in place. Be aware of potential for dust explosion when using electrical equipment. If vacuum is not available, lightly mist material and remove by sweeping or wet wiping. Section 7 - Handling and Storage Lilly Warehouse Storage Category: 140X Storage Conditions: Warehouse: 10 to 40 C (45 to 104 F). For certain items, other storage conditions may be required. Section 8 - Exposure Controls / Personal Protection See Section 2 for Exposure Guideline information. Respiratory Protection: Use an approved respirator. Eye Protection: Chemical goggles and/or face shield. Ventilation: Laboratory fume hood or local exhaust ventilation. Other Protective Equipment: Chemical-resistant gloves and body covering to minimize skin contact. If handled in a ventilated enclosure, as in a laboratory setting, respirator and goggles or face shield may not be required. Safety glasses are always required. Section 9 - Physical and Chemical Properties Boiling Point: Not applicable Melting Point: Not applicable Specific Gravity: 2.159 pH: 8.2 (1% solution) Evaporation Rate: Not applicable Water Solubility: 8.6 g/100 ml @ 20 C (68 F) Vapor Density: Not applicable Vapor Pressure: Not applicable Section 10 - Stability and Reactivity Stability: Stable at normal temperatures and pressures. Incompatibility: May react with strong oxidizing agents (e.g., peroxides, permanganates, nitric acid, etc.) and strong acids. Hazardous Decomposition: May emit toxic fumes when heated to decomposition. Hazardous Polymerization: Will not occur. Section 11 - Toxicological Information Acute Exposure Oral: Sodium bicarbonate - Rat, median lethal dose 4220 mg/kg. Skin: No applicable information found. Inhalation: Sodium bicarbonate - Rat, median lethal concentration greater than 4740 mg/m3 (duration unspecified). Skin Contact: No applicable information found. Eye Contact: Sodium bicarbonate - Rabbit, mild irritant Chronic Exposure Target Organ Effects: No applicable information found. Reproduction: Sodium bicarbonate - No teratogenic effects reported in rats or mice given large doses during pregnancy. Sensitization: No applicable information found. Mutagenicity: Sodium bicarbonate - Negative in Ames assay. Section 12 - Ecological Information Ecotoxicity Data: Sodium bicarbonate Daphnia magna 48-hour median lethal concentration: 11.7 mmol/L to 26.3 mmol/L Western mosquitofish 96-hour median lethal concentration: 5.6 g/L Bluegill 96-hour median lethal concentration: 8.25 g/L Rainbow trout median lethal concentration (duration unspecified): 7.7 g/L Environmental Fate: No applicable information found. Environmental Summary: Sodium bicarbonate - This material is practically non-toxic to aquatic organisms. Material is soluble in water and may leach from soil into groundwater. Section 13 - Disposal Considerations Waste Disposal: Dispose of any cleanup materials and waste residue according to all applicable laws and regulations. Section 14 - Transport Information Regulatory Organizations: DOT: Not Regulated ICAO/IATA: Not Regulated IMO: Not Regulated Section 15 - Regulatory Information Below is selected regulatory information chosen primarily for possible Eli Lilly and Company usage. This section is not a complete analysis or reference to all applicable regulatory information. Please consider all applicable laws and regulations for your country/state. U.S. Regulations Sodium bicarbonate TSCA - Yes CERCLA - Not on this list SARA 302 - Not on this list SARA 313 - Not on this list OSHA Substance Specific - No EU Regulations EC Classification Not assigned an overall EC classification. Section 16 - Other Information MSDS Sections Revised: Section 7. As of the date of issuance, we are providing available information relevant to the handling of this material in the workplace. All information contained herein is offered with the good faith belief that it is accurate. THIS MATERIAL SAFETY DATA SHEET SHALL NOT BE DEEMED TO CREATE ANY WARRANTY OF ANY KIND (INCLUDING WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE). In the event of an adverse incident associated with this material, this safety data sheet is not intended to be a substitute for consultation with appropriately trained personnel. Nor is this safety data sheet intended to be a substitute for product literature which may accompany the finished product. For additional information contact: Eli Lilly and Company Hazard Communication 317-433-7171 GLOSSARY: ACGIH = American Conference of Governmental Industrial Hygienists AIHA = American Industrial Hygiene Association BEI = Biological Exposure Index CAS Number = Chemical Abstract Service Registry Number CERCLA = Comprehensive Environmental Response Compensation and Liability Act (of 1980) CHAN = Chemical Hazard Alert Notice CHEMTREC = Chemical Transportation Emergency Center DOT = Department of Transportation EC = European Community EINECS = European Inventory of Existing Chemical Substances ELINCS = European List of New Chemical Substances EPA = Environmental Protection Agency HEPA = High Efficiency Particulate Air (Filter) IARC = International Agency for Research on Cancer ICAO/IATA = International Civil Aviation Organization/International Air Transport Association IEG = Lilly Interim Exposure Guideline IMO = International Maritime Organization Kow = Octanol/Water Partition Coefficient LEG = Lilly Exposure Guideline LEL = Lower Explosive Limit MSDS = Material Safety Data Sheet MSHA = Mine Safety and Health Administration NA = Not Applicable, except in Section 14 where NA = North America NADA = New Animal Drug Application NAIF = No Applicable Information Found NCI = National Cancer Institute NIOSH = National Institute for Occupational Safety and Health NOS = Not Otherwise Specified NTP = National Toxicology Program OSHA = Occupational Safety and Health Administration PEL = Permissible Exposure Limit (OSHA) RCRA = Resource Conservation and Recovery Act RQ = Reportable Quantity RTECS = Registry of Toxic Effects of Chemical Substances SARA = Superfund Amendments and Reauthorization Act STEG = Lilly Short Term Exposure Guideline STEL = Short Term Exposure Limit TLV = Threshold Limit Value (ACGIH) TPQ = Threshold Planning Quantity TSCA = Toxic Substances Control Act TWA = Time Weighted Average/8 Hours Unless Otherwise Noted UEL = Upper Explosive Limit UN = United Nations WEEL = Workplace Environmental Exposure Level (AIHA) R B F INTERNATIONAL LTEE / LTD 780, Nobel street, St-Jérôme, Québec, J7Z 7A3 Tel.: (450) 438-4416, 1-800-433-0590 Fax: (450) 438-0827 Material Safety Data Sheet Section I - Identification 2009048 – 2009085 – 2009086 - RONA 3” TABLETS STABILIZED CHLORINE MANUFACTURER / SUPPLIER: R B F INTERNATIONAL 780, Nobel street St-Jerome, Quebec, J7Z 7A3 Tel.: (450) 438-4416, 1-800-433-0590 EMERGENCY LINES: (CANUTEC): 613 - 996 - 6666 1 - 800 - 463 - 5060 Chemical Name: Trichloro-s-triazine-trione Product Use: Destroys bacteria and algae in swimming pool water. Hazard Rating 4 Extreme 3 High 2 Moderate 1 Slight 0 None Designation Health Fire Reactivity Personal Protection 2 0 1 D Section II - Hazardous Ingredients Material Trichloro-s-triazine-trione % By Weight 99-100 CAS Nr Exposure Limits LD50 (Oral-Rat) 87-90-1 6375 ppm 10.000 mg/Kg MSDS Page 1 of 4 RONA 3" TABLETS STABILIZED CHLORINE Section III - Physical Data Appearance Boiling Point Freezing Point Odor pH (1%) Specific Gravity ( Water = 1) Vapor Density ( Air = 1) Vapor Pressure (mm Hg) Evaporation Rate Water Solubility % Volatile Coefficient water/oil distribution Odor Threshold White tablets. Decompose at 2250C N/A N/A 2,3 2.09 N/A N/A N/A Soluble (1g / 100 ml) N/A N/A N/A Section IV - Fire And Explosion Data Flash Point (oC , Test Method): Auto-Ignition Temperature: Flammable Limits In Air: ( g/l ): Extinguishing Media: Special Fire Fighting Procedure: Personal Protective Equipment: Conditions of flammability: Hazardous combustion products: Explosion Data: Sensitivity Impact: Sensitivity to static discharge: Mechanical Impact: None None LFL: None UFL: None Dry Chemical (Sodium Bicarbonate), Foam, CO2, Water Fight fires from a safe distance. DO NOT approach container because of danger of rupturing. Use water spray to cool containers exposed to fire. Wear self-contained breathing apparatus (pressure-demand MSHA/NIOSH approved or equivalent) and full protective gear. N/A N/A N/A N/A N/A N/A Section V - Health Hazard Information Of Product Routes of Exposure and Acute Effects. Inhalation: Skin Contact: Skin Absorption: Eye Contact: Ingestion: May cause irritations. May cause irritations. May cause irritations. May cause stinging or burning. Poison. See a physician immediately. MSDS Page 2 of 4 RONA 3" TABLETS STABILIZED CHLORINE Chronic Exposure. Irritancy of product: Sensitizing Capacity: Mutagenic effect: Teratogenic effect: Carcinogenic effect: Reproductive toxicity: Synergistic products: Irritating N/A N/A N/A N/A N/A N/A Emergency and First Aid Procedure. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician immediately. In case of contact, remove contaminated clothing and flush skin thoroughly with Skin: soap and water. Wash clothing before reusing. Inhalation: If inhaled, remove to area of fresh air. If irritation persists, call a physician. Ingestion: If swallowed, call a physician immediately. Eyes: Section VI - Reactivity Data Conditions Contributing to Instability: This product is stable under normal conditions. Avoid especially contact with oxidizing agents, Incompatibility: excessive heat, strong alkaline products. Carbon Oxides ( CO2, CO ), Nitrogene, Trichloroamine Decomposition Products: In contact with oxidizing agents, open flame, sparks Reactivity: or ignition sources, strong alkaline products, sodium and calcium hypochlorite, oil and grease. Section VII - Spill Or Leak Procedures Steps To Be Taken If Material Is Released Or Spilled Cleanup personnel must wear proper protective equipment. That is rubber gloves, face shield, safety goggles, safety shoes and protective clothing. Never collect the spilled product in containers to be reused. Neutralize with sodium thiosulfate and thoroughly wash area with water. Waste Disposal Method. Dispose according to Local, Provincial and Federal by-laws. Section VIII - Special Protection Information. Ventilation requirements Local ventilation absolutely necessary. MSDS Page 3 of 4 RONA 3" TABLETS STABILIZED CHLORINE Specific Personal Protective Information. Chemical resistant gloves and other body protection (rubber apron, boots, body covering clothes) to minimize skin contact. Chemical splash goggles and/or face shield. Eye Protection: Respiratory protection: Use an approved self-contained breathing apparatus (MSHA/NIOSH or equivalent). Eye wash station and safety shower in area. Other: Do not wear contact lenses when working with this compound. Skin Protection: Section IX - Special Precaution. Precaution To Be Taken In Handling. Avoid inhalation of dust. Avoid eye or skin contact. Do not take internally. Wash clothing before reuse. Practice good personal hygiene. Proper Storage, Handling and Disposal Requirements. Store in tightly closed containers in a cool, dry, well-ventilated area. Keep away from incompatible materials (oxidizing agents). NO SMOKING in areas of storage, handling or use. Section X - Transport And Regulatory Information. TDG DESIGNATION: UN NUMBER: TDG CLASSIFICATION: WHIMS CLASSIFICATION: PACKING GROUP Trichloroisocyanuric acid dry 2468 5.1 Schedule under the Pest Control Product Act II Material Safety Data Sheet: Prepared By: Verified By: Date Issued: R. Ioanin G. Radu April 01, 2005 The information herein is given in good faith but no warranty, expressed or implied is made. The persons receiving this information are urged to make their own determination as to the information’s suitability and completeness for their particular application. MSDS Page 4 of 4 Vanson HaloSource, Inc. Material Safety Data Sheet Material Name: SeaKlear® Phosphate Remover Telephone No: 425-881-6464 VHI-MSDS-02.36 REV 05 Date Prepared: 12-19-05 24-HOUR EMERGENCY PHONE: CHEMTREC 800-424-9300 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION Manufacturer's Name: Corporate Address: Manufacturer's Telephone: Emergency Telephone: Material/Trade/Product Name: Synonyms: Chemical Name: CAS No.: Product Use: Vanson HaloSource, Inc. 14716 NE 87th Street, Redmond, WA 98052 (425) 881-6464 (Monday-Friday, 8AM-5PM PDT) 800-424-9300 Chemtrec (24 Hours) Phosphate Remover None Lanthanum Chloride, 7 hydrate (99.9%) Not Applicable Removes phosphates from water SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS CAS NO. 20211-76-1 HAZARDOUS INGREDIENT (S) Lanthanum Chloride Hydrate % OSHA HAZARDOUS ? 99.99 YES NOTE: See Section 8 for permissible exposure limits. SECTION 3: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Clear to slightly yellow liquid. Can cause irritation to exposed areas of body. Severity of injury depends largely on duration of exposure. Immediate action is necessary to limit severity of injury. Hydrogen chloride will be produced from decomposition. POTENTIAL HEALTH EFFECTS EYE: May cause irritation. SKIN: Possible skin irritant. INHALATION: Should not be harmful if inhaled. INGESTION: Possible irritant if swallowed. Page 1 of 7 Vanson HaloSource, Inc. Material Safety Data Sheet Material Name: SeaKlear® Phosphate Remover Telephone No: 425-881-6464 VHI-MSDS-02.36 REV 05 Date Prepared: 12-19-05 CHRONIC EXPOSURE/CARCINOGENICITY: This substance not listed as a potential carcinogen by IARC. SIGNS AND SYMPTOMS OF OVEREXPOSURE: Eye and/or skin irritation. AGGRAVATION OF PRE-EXISTING CONDITIONS: None known. POTENTIAL ENVIRONMENTAL EFFECTS: None known. SECTION 4: FIRST AID MEASURES FIRST AID PROCEDURES EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes, lifting eyelids occasionally. Get medical attention at once. SKIN CONTACT: Remove contaminated clothing and immediately wash exposed area for 15 minutes. Get medical attention if necessary. INHALATION: Move to fresh air. If breathing has stopped administer artificial respiration. Get medical attention immediately. INGESTION: Give large amounts of water. Do not induce vomiting. Get medical attention immediately. NOTE TO PHYSICIANS: None SECTION 5: FIRE FIGHTING MEASURES FLASH POINT: Not applicable UPPER FLAMMABLE LIMIT: Not applicable FLAMMABLITY CLASS (OSHA): Not applicable AUTOIGNITION TEMPERATURE: Not applicable LOWER FLAMMABLE LIMIT: Not applicable FLAME PROPAGATION/BURNING RATE: Not applicable UNIQUE FIRE PROPERTIES: HCI is produced. HAZARDOUS COMBUSTION PRODUCTS: HCI is produced. EXTINGUISHING MEDIA: Use water, dry chemicals, carbon dioxide, sand or foam. Use extinguishing media appropriate for surrounding fire. PROTECTION OF FIREFIGHTERS: Do not enter confined fire space without full bunker gear (helmet with face shield, bunker coat, gloves and rubber boots), including a positive pressure NIOSH approved self-contained breathing apparatus. Water may be used to keep fire-exposed containers cool until fire is out. Page 2 of 7 Vanson HaloSource, Inc. Material Safety Data Sheet Material Name: SeaKlear® Phosphate Remover Telephone No: 425-881-6464 VHI-MSDS-02.36 REV 05 Date Prepared: 12-19-05 SECTION 6: ACCIDENTAL RELEASE MEASURES PERSONAL PROTECTIVE EQUIPMENT: See Section 8 (Personal Protective Equipment). ENVIRONMENTAL PRECAUTIONS: None METHODS FOR CLEANING UP: Contain large spills and pump to recover. Small spills can be mopped up and recovered. SECTION 7: HANDLING AND STORAGE SAFE HANDLING RECOMMENDATIONS VENTILATION: Use general ventilation FIRE PREVENTION: Not flammable SPECIAL HANDLING REQUIREMENTS: Use appropriate PPE SAFE STORAGE RECOMMENDATIONS CONTAINMENT: Secondary containment is recommended. STORAGE ROOM RECOMMENDATIONS: Store in cool, dry place. Keep container closed when not in use; keep out of the reach of children. INCOMPATIBLE MATERIALS: None known. STORAGE CONDITIONS: Store in cool, dry place. Keep container closed when not in use; keep out of the reach of children. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: General ventilation PERSONAL PROTECTIVE EQUIPMENT (PPE) EYE/FACE PROTECTION: Safety glasses are recommended under normal conditions. SKIN PROTECTION: Avoid contact with skin. Page 3 of 7 Vanson HaloSource, Inc. Material Safety Data Sheet Material Name: SeaKlear® Phosphate Remover Telephone No: 425-881-6464 VHI-MSDS-02.36 REV 05 Date Prepared: 12-19-05 HAND PROTECTION: Chemical resistant gloves are recommended to minimize potential irritation from handling. RESPIRATORY PROTECTION: None required where adequate ventilation conditions exist. GOOD HYGEIENE/WORK PRACTICES: Always follow good hygiene/work practices by avoiding vapors or mists and contact with eyes and skin. Thoroughly wash hands after handling and before eating or drinking. Always wear the appropriate PPE when repairing or performing maintenance on contaminated equipment. EXPOSURE GUIDELINES INGREDIENT CAS NO. Not applicable OSHA TWA Not applicable PERMISSIBLE EXPOSURE LIMITS WISHA STEL Not applicable TWA Not applicable STEL Not applicable ACGIH (TLV) TWA Not applicable STEL Not applicable SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES COLOR: Clear to slightly yellow PHYSICAL FORM: Liquid pH: Not applicable VAPOR DENSITY: 4.10 MELTING POINT: Not known SOLUBILITY IN WATER: Appreciable (more than 10%) SHAPE: Liquid ODOR: None VAPOR PRESSURE: Not known BOILING POINT: Not known FREEZING POINT: Not known SPECIFIC GRAVITY OR DENSITY: Not known SECTION 10: STABILITY AND REACTIVITY CHEMICAL STABILITY: Stable CONDITIONS TO AVOID: None known MATERIALS TO AVOID (INCOMPATIBILITY): None known HAZARDOUS DECOMPOSITION PRODUCTS: Hydrogen Chloride HAZARDOUS POLYMERIZATION: Will not occur SECTION 11: TOXICOLOGICAL INFORMATION ORAL LD50 (rat): 4200 DERMAL LD50 (rat): 106 Page 4 of 7 Vanson HaloSource, Inc. Material Safety Data Sheet Material Name: SeaKlear® Phosphate Remover Telephone No: 425-881-6464 VHI-MSDS-02.36 REV 05 Date Prepared: 12-19-05 SCU, LD50(MG/KG) (mouse): 2424 IV LD50 (MG/KG) (mouse): 18 SKIN IRRITATION (rabbit): Not available SKIN SENSITIZATION (guinea pig): Not available EYE IRRITATION (rabbit): Not available SECTION 12: ECOLOGICAL INFORMATION Fish 96-hour LC50 Daphnia 48-hour LC50 Green algae 96-hour EC50 Fish Chronic Value (ChV) Daphnia ChV Algae ChV =Not available =Not available =Not available =Not available =Not available =Not available SECTION 13: DISPOSAL CONSIDERATIONS If this product as supplied becomes a waste, it does meet the criteria of a hazardous waste as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Please be advised that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material. NOTE: Chemical additions, processing or otherwise altering this material may make the waste management information presented in this MSDS incomplete, inaccurate or otherwise inappropriate. SECTION 14: TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION (DOT): DOT Proper Shipping Name: DOT Hazard Class: Packing Group: UN Number: Not regulated Not regulated Not regulated Not regulated SECTION 15: REGULATORY INFORMATION TSCA STATUS: Not listed Page 5 of 7 Vanson HaloSource, Inc. Material Safety Data Sheet Material Name: SeaKlear® Phosphate Remover Telephone No: 425-881-6464 VHI-MSDS-02.36 REV 05 Date Prepared: 12-19-05 CERCLA REPORTABLE QUANTITY (RQ): CHEMICAL NAME RQ Not applicable Not applicable SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (EHS): CHEMICAL NAME None TPQ RQ Not applicable Not applicable SARA TITLE III SECTION 311/312 HAZARD CATEGORIES: Does this product/material meet the definition of the following hazard classes according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of SARA Title III? ACUTE HEALTH HAZARD Yes CHRONIC HEALTH HAZARD No FIRE HAZARD REACTIVE HAZARD No No SUDDEN RELEASE OF PRESSURE No SARA TITLE III SECTION 313 TOXIC CHEMICALS INFORMATION: CHEMICAL NAME None CAS NO. CONCENTRATION (%) Not applicable Not applicable CALIFORNIA PROPOSITION 65: The following chemical(s) is/are known to the state of California to cause cancer or reproductive toxicity: CHEMICAL NAME None CAS NO. CONCENTRATION (%) Not applicable Not applicable SECTION 16: OTHER INFORMATION REVISION INFORMATION: MSDS sections(s) changed since last revision of document: In an attempt to make Vanson-HaloSource’s MSDSs more user friendly, as well as to keep current with all applicable regulations, all of the sections in this MSDS have had slight to significant changes since the last revision. DISCLAIMER: **************************************************************************************************************************************** ** The above information is based upon information Vanson-HaloSource Inc. believes to be reliable and is supplied for informational purposes only. Vanson-HaloSource Inc. disclaims any liability for damage which results from the use of Page 6 of 7 Vanson HaloSource, Inc. Material Safety Data Sheet Material Name: SeaKlear® Phosphate Remover Telephone No: 425-881-6464 VHI-MSDS-02.36 REV 05 Date Prepared: 12-19-05 the above information and nothing contained therein shall constitute a guarantee, warranty (including fitness for a particular purpose) or representation with respect to the accuracy or completeness of the data, the product described or their use for any specific purpose even if that purpose is known to Vanson-HaloSource Inc. The final determination of the suitability of the information, the manner of use of the information or product and potential infringement is the sole responsibility of the user. **************************************************************************************************************************************** ** MSDS PREPARED BY: Jeremy Heath, EH&S Specialist Page 7 of 7 MATERIAL SAFETY DATA SHEET GLB Oxy-Brite 1. Product And Company Identification Supplier GLB 1400 Bluegrass Lakes Parkway Alpharetta, GA 30004 United States Manufacturer Advantis Technologies, Inc. 1400 Bluegrass Lakes Parkway Alpharetta, GA 30004 United States Telephone Number: (770)521-5999 FAX Number: (770)521-5959 Web Site: www.poolspacare.com Telephone Number: (770) 521-5999 FAX Number: (770) 521-5959 Web Site: www.poolspacare.com Supplier Emergency Contacts & Phone Number CHEMTREC - DAY OR NIGHT: (800) 424-9300 Manufacturer Emergency Contacts & Phone Number CHEMTREC - DAY OR NIGHT: (800) 424-9300 Issue Date: 04/16/2007 Product Name: GLB Oxy-Brite Chemical Name: Potassium Monopersulfate CAS Number: Not Established Chemical Family: Peroxygen Salt Chemical Formula: Proprietary MSDS Number: 314 2. Composition/Information On Ingredients Ingredient Name CAS Number MAGNESIUM CARBONATE Percent Of Total Weight 546-93-0 POTASSIUMBISULFATE 7646-93-7 POTASSIUMPEROXYDISULFATE 7727-21-1 POTASSIUMPEROXYMONOSULFATE 10058-23-8 POTASSIUMSULFATE 7778-80-5 SODIUMTETRABORATEPENTAHYDRATE 12179-04-3 Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as carcinogens are listed if they comprise 0.1% or more of the composition. Information on proprietary materials is available in 29CFR 1910.1200(i)(1). EMERGENCY OVERVIEW This product is a skin and eye corrosive, and a nose and throat irritant. Hazards Identification (Pictograms) 3. Hazards Identification Primary Routes(s) Of Entry Skin Contact Page 1 of 5 MATERIAL SAFETY DATA SHEET GLB Oxy-Brite 3. Hazards Identification - Continued Eye Hazards Corrosive to eyes. Eye contact may cause corrosion or ulceration. Severe eye damage may result if not immediately treated. Skin Hazards Corrosive to skin. Skin contact with aqueous solutions or the dry powder upon contact with moisture or perspiration may cause skin burns or ulceration; temporary body hair loss may occur in contacted areas. Skin contact with the product may cause allergic skin reactions in sensitive individuals. Ingestion Hazards May cause irritation of the throat. Ingestion may cause inflammation and damage to the lining of the stomach, resulting in bleeding. Ingestion may cause gastritis possibly progressing to necrosis or hemorrhage. Inhalation Hazards Inhalation may cause nose bleeds and irritation of the upper respiratory passages with coughing and discomfort. Signs And Symptoms Irritant to eyes and skin due to oxidizing properties First Aid (Pictograms) 4. First Aid Measures Eye In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Call a physician or a poison control center immediately. Skin Wash affected areas with soap and water. Call a physician. Wash clothing before reuse. Ingestion DO NOT INDUCE VOMITING. Drink large amounts of water. Call a physician or a poison control center immediately. Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Consult Physician Fire Fighting (Pictograms) 5. Fire Fighting Measures Flash Point: N/A °F Fire And Explosion Hazards Improper storage of large masses of this product can trap heat and lead to ignition of combustibles. Grinding or intensive mixing may cause decomposition with liberation of heat and oxygen; ignition of oxidizable material if present may occur. Extinguishing Media In case of fire, soak (flood) with water. Page 2 of 5 MATERIAL SAFETY DATA SHEET GLB Oxy-Brite 5. Fire Fighting Measures - Continued Fire Fighting Instructions Will release oxygen when heated, intensifying a fire. Firefighters should wear self-contained breathing apparatus and full protective gear. GRINDING OR INTENSIVE MIXING MAY GENERATE SUFFICIENT HEAT TO FUSE PRODUCT AND CAUSE IGNITION OF OXIDIZABLE MATERIAL PRESENT. 6. Accidental Release Measures Clean up spill immediately. Flush spill area with water in compliance with State and Federal Regulations. Handling & Storage (Pictograms) 7. Handling And Storage Handling And Storage Precautions Keep out of reach of children. Store material in a cool and dry place. Handling Precautions Avoid breathing dust or vapor. Avoid contact with skin and clothing. Avoid contact with eyes. Wash thoroughly after handling. Wash clothing after use. Storage Precautions Store in a cool dry place. Keep away from heat, sparks, flame, and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Work/Hygienic Practices Use safe chemical handling procedures suitable for the hazards presended by this material. Protective Clothing (Pictograms) 8. Exposure Controls/Personal Protection Engineering Controls Local exhaust acceptable. Special exhaust not required Eye/Face Protection Safety glasses with side shields or goggles recommended. Skin Protection Chemical-resistant gloves. Respiratory Protection The level of respiratory protection needed should be based on the required protection factor after evaluating chemical exposures using appropriate industrial hygiene monitoring and/or OSHA guidance. 9. Physical And Chemical Properties Appearance Blue granules or powder Page 3 of 5 MATERIAL SAFETY DATA SHEET GLB Oxy-Brite 9. Physical And Chemical Properties - Continued Odor None Chemical Type: Mixture Physical State: Solid Melting Point: DECOMPOSES °F Boiling Point: DECOMPOSES °F Specific Gravity: 1.2 Molecular Weight: PROPRIETARY Percent Volitales: NIL Vapor Pressure: NIL Vapor Density: NOT VOLATILE Solubility: >25% AT 20C (68F) Evaporation Rate: NOT VOLATILE Corrosive, Oxidizer 10. Stability And Reactivity Stability: Stable Hazardous Polymerization: Will not occur Conditions To Avoid (Stability) The mixture of this product with compounds containing halides or active halogens (bromine, chlorine, iodine) can cause the release of the respective halogen gas, if moisture is present. Avoid these gases (bromine and chlorine) because they are very irritating to eyes and lungs even at low concentrations. Never mix concentrated product with dry or concentrated bromine containing chemicals, such as bromates, bromides, or any concentrated bromine pool chemicals. Mixing this prodcut with dry or concentrated chlorine containing chemicals, such as hypochlorites, sodium dichloroisocyanurate, sodium triisocyanurate or with sodium chloride, may cause the release of chlorine gas. Mixing with cyanides can cause release of hydrogen cyanide gas. Mixing with heavy metal salts such as those of cobalt, nickel, copper, or manganese can cause decomposition with release of oxygen and heat. Incompatible Materials Alkalis, Heavy Metals cause evolution of Oxygen gas. Halogens and cyanides can cause release of gases of these compounds. Hazardous Decomposition Products Oxygen 11. Toxicological Information Acute Studies This product is a severe skin and eye irritant, but is not a skin sensitizer in animals. 12. Ecological Information No Data Available... 13. Disposal Considerations Dispose in accordance with applicable federal, state and local government regulations. 14. Transport Information Proper Shipping Name CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (Monopersulfate Compound) Page 4 of 5 MATERIAL SAFETY DATA SHEET GLB Oxy-Brite 14. Transport Information - Continued Proper Shipping Name - Continued Hazard Class 8, PGII (<=1kg Consumer Commodity ORM-D) DOT Identification Number UN3260 DOT (Pictograms) 15. Regulatory Information SARA Hazard Classes Acute Health Hazard Canadian Regulatory Information Class D, Div 2b - Toxic Material. Skin or Eye Irritant Class E - Corrosive Material Class C - Oxidizing Material WHMIS - Canada (Pictograms) NFPA HMIS 0 3 1 HEALTH 3 FLAMMABILITY 0 REACTIVITY 1 PERSONAL E PROTECTION 16. Other Information Revision/Preparer Information MSDS Preparer: JHW This MSDS Superceeds A Previous MSDS Dated: 10/13/2003 Disclaimer Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitablility of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purposes(s). GLB Printed Using MSDS Generator™ 2000 Page 5 of 5 Vanson HaloSource, Inc Material Safety Data Sheet Material Name: SEA-KLEAR 3-Month Algaecide Telephone No: 425-881-6464 VHI-MSDS-02-16-REV-2 Date Prepared: 12-23-02 24-HOUR EMERGENCY PHONE: CHEMTREC 800-424-9300 SECTION I – CHEMICAL PRODUCT & COMPANY IDENTIFICATION Manufacturer's Name: Corporate Address: Emergency Phone: Manufacturer's Phone: Material Name: Chemical Name: Vanson HaloSource, Inc. th 14716 NE 87 Street, Redmond, WA 98052 800-424-9300 Chemtrec (425) 881-6464 SEA-KLEAR 3-Month Algaecide Copper (11) Triethanolamine SECTION II – COMPOSITION, INFORMATION ON INGREDIENTS CAS NO. INGREDIENT EXPOSURE LIMITS Copper (11) Triethanolamine OSHA PEL: N/A OSHA STEL: N/A ACGIH TLV: N/A SECTION III – HAZARDS IDENTIFICATION PRINCIPAL HEALTH HAZARDS, INCLUDING SIGNIFICANT ROUTES, EFFECTS, AND SYMPTOMS OF OVEREXPOSURE AND MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE MAY BE: EYE: Possible eye irritant. SKIN: Not known to be a skin irritant. INHALATION: NA INGESTION: Low degree of toxicity by ingestion. CARCINOGENICITY: Not listed by National Toxicology Program (NTP) OSHA, or International Agency for Research on Cancer (IARC) SECTION IV - FIRST AID EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Contact a physician. SKIN: If skin contact occurs, wash thoroughly with soap and water. INHALATION: Use approved respirator for mists. INGESTION: Contact a physician. SECTION V - FIRE FIGHTING MEASURES Page 1 of 6 Vanson HaloSource, Inc Material Safety Data Sheet Material Name: SEA-KLEAR 3-Month Algaecide Telephone No: 425-881-6464 VHI-MSDS-02-16-REV-2 Date Prepared: 12-23-02 HAZARDOUS COMBUSTION PRODUCTS: NA EXTINGUISHING MEDIA: Use water, dry chemicals, carbon dioxide, sand or foam. Use extinguishing media appropriate for surrounding fire. FIREFIGHTING INSTRUCTIONS: Do not enter confined fire space without full bunker gear (helmet with face shield, bunker coat, gloves and rubber boots), including a positive pressure NIOSH approved self-contained breathing apparatus. Water may be used to keep fire-exposed containers cool until fire is out. FLASH POINT: Not applicable. SECTION VI – ACCIDENTAL RELEASE MEASURES SPILL: Vacuum collect in containers for disposal. Flush area with water. DISPOSAL INFORMATION: Contaminated material or waste should be placed in suitable receptacles and removed to chemical waste storage area for disposal in accordance with relevant federal, state, and local regulations. DISPOSAL METHODS: In accordance with local, State and federal regulations. Flush residue with water. SECTION VII - HANDLING & STORAGE HANDLING & STORAGE PRECAUTIONS: Store below 40 °C/104° F in cool dry area in well closed containers. Exercise normal handling precautions for liquids. Protect from freezing. Keep away from metals. SECTION VIII - EXPOSURE CONTROLS/ PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT (PPE): Good hygiene practices should be strictly followed. Before eating, drinking or smoking, wash face and hands thoroughly. For operations where eye or face contact may occur, wear chemical goggles or face shield. Showers and eyewash facilities should be accessible. EYE PROTECTION: eye protection recommended. SKIN PROTECTION: gloves. PROTECTIVE CLOTHING: NA PROTECTIVE FOOTWEAR: NA RESPIRATORY PROTECTION: NA . VENTILATION REQUIREMENTS: Generally adequate Page 2 of 6 Vanson HaloSource, Inc Material Safety Data Sheet Material Name: SEA-KLEAR 3-Month Algaecide Telephone No: 425-881-6464 VHI-MSDS-02-16-REV-2 Date Prepared: 12-23-02 SECTION IX - PHYSICAL & CHEMICAL PROPERTIES PHYSICAL FORM: Odorless Blue liquid. BOILING POINT: Same as water. MELTING POINT: NA pH: unknown SOLUBILITY IN WATER: Miscible in water SPECIFIC GRAVITY: 1.18-1.21 . SECTION X - STABILITY & REACTIVITY DATA CHEMICAL STABILITY: Stable. HAZARDOUS POLYMERIZATION: Will not occur. INCOMPATIBLES: NA DECOMPOSITION PRODUCTS: NA SECTION XI - TOXICOLOGICAL INFORMATION ORAL Rat LD50 (MG/KG): 4,500 mg/kg IV-Mouse, LD50(MG/KG): NA DERMAL LD50 (rabbit): 8,000 mg/kg EYE IRRITATION (rabbit): NA SKIN IRRITATION (rabbit): NA SECTION XII - ECOLOGICAL INFORMATION Fish 96-hour LC50 Daphnia 48-hour LC50 Green algae 96-hour EC50 = = = 5.4 ppm @ 96 hours NA NA Page 3 of 6 Vanson HaloSource, Inc Material Safety Data Sheet Material Name: SEA-KLEAR 3-Month Algaecide Telephone No: 425-881-6464 Fish Chronic Value (ChV) Daphnia ChV Algae ChV = = = VHI-MSDS-02-16-REV-2 Date Prepared: 12-23-02 NA NA NA GENERAL: SECTION XIII - DISPOSAL CONSIDERATION WASTE DISPOSAL METHOD: Dispose of in accordance with all applicable federal, local and State environmental regulations. SECTION XIV - TRANSPORTATION INFORMATION DOT Proper Shipping Name: DOT Hazard Class: Packing Group: UN Number: Product RQ (lbs.): DOT Label: DOT Placard: Freight Class (package): None Not regulated as a hazardous material Not determined Not determined No limit Miscellaneous Not required Not determined SECTION XV - REGULATORY INFORMATION MATERIAL IS REPORTED IN EPA TSCA INVENTORY LIST?: No MATERIAL IS LISTED AS A CARCINOGEN/POTENTIAL CARCINOGEN IN FOLLOWING?: No NTP ANNUAL REPORT: No IARC GROUP I OR II: No OSHA 29CFR PART 1910 SUBPART Z: No DOES PRODUCT CONTAIN A TOXIC CHEMICAL SUBJECT TO SARA TITLE III SECTION 313 REPORTING: No SARA TITLE III SECTION 311/312 CLASSIFICATIONS: None SECTION XVI – OTHER INFORMATION The above information is based upon information Vanson-HaloSource, Inc. believes to be reliable and is supplied for informational purposes only. Vanson-HaloSource, Inc. disclaims any liability for damage which results from the use of the above information and nothing contained therein shall constitute a guarantee, warranty (including fitness for a particular purpose) or representation with respect to the accuracy or completeness of the data, the product described or their use Page 4 of 6 Vanson HaloSource, Inc Material Safety Data Sheet Material Name: SEA-KLEAR 3-Month Algaecide Telephone No: 425-881-6464 VHI-MSDS-02-16-REV-2 Date Prepared: 12-23-02 for any specific purpose even if that purpose is known to Vanson-HaloSource, Inc. The final determination of the suitability of the information, the manner of use of the information or product and potential infringement is the sole responsibility of the user. Page 5 of 6 Vanson HaloSource, Inc. Material Safety Data Sheet Material Name: SeaKlear® Phosphate Remover Telephone No: 425-881-6464 VHI-MSDS-02.36 REV 05 Date Prepared: 12-19-05 24-HOUR EMERGENCY PHONE: CHEMTREC 800-424-9300 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION Manufacturer's Name: Corporate Address: Manufacturer's Telephone: Emergency Telephone: Material/Trade/Product Name: Synonyms: Chemical Name: CAS No.: Product Use: Vanson HaloSource, Inc. 14716 NE 87th Street, Redmond, WA 98052 (425) 881-6464 (Monday-Friday, 8AM-5PM PDT) 800-424-9300 Chemtrec (24 Hours) Phosphate Remover None Lanthanum Chloride, 7 hydrate (99.9%) Not Applicable Removes phosphates from water SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS CAS NO. 20211-76-1 HAZARDOUS INGREDIENT (S) Lanthanum Chloride Hydrate % OSHA HAZARDOUS ? 99.99 YES NOTE: See Section 8 for permissible exposure limits. SECTION 3: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Clear to slightly yellow liquid. Can cause irritation to exposed areas of body. Severity of injury depends largely on duration of exposure. Immediate action is necessary to limit severity of injury. Hydrogen chloride will be produced from decomposition. POTENTIAL HEALTH EFFECTS EYE: May cause irritation. SKIN: Possible skin irritant. INHALATION: Should not be harmful if inhaled. INGESTION: Possible irritant if swallowed. Page 1 of 7 Vanson HaloSource, Inc. Material Safety Data Sheet Material Name: SeaKlear® Phosphate Remover Telephone No: 425-881-6464 VHI-MSDS-02.36 REV 05 Date Prepared: 12-19-05 CHRONIC EXPOSURE/CARCINOGENICITY: This substance not listed as a potential carcinogen by IARC. SIGNS AND SYMPTOMS OF OVEREXPOSURE: Eye and/or skin irritation. AGGRAVATION OF PRE-EXISTING CONDITIONS: None known. POTENTIAL ENVIRONMENTAL EFFECTS: None known. SECTION 4: FIRST AID MEASURES FIRST AID PROCEDURES EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes, lifting eyelids occasionally. Get medical attention at once. SKIN CONTACT: Remove contaminated clothing and immediately wash exposed area for 15 minutes. Get medical attention if necessary. INHALATION: Move to fresh air. If breathing has stopped administer artificial respiration. Get medical attention immediately. INGESTION: Give large amounts of water. Do not induce vomiting. Get medical attention immediately. NOTE TO PHYSICIANS: None SECTION 5: FIRE FIGHTING MEASURES FLASH POINT: Not applicable UPPER FLAMMABLE LIMIT: Not applicable FLAMMABLITY CLASS (OSHA): Not applicable AUTOIGNITION TEMPERATURE: Not applicable LOWER FLAMMABLE LIMIT: Not applicable FLAME PROPAGATION/BURNING RATE: Not applicable UNIQUE FIRE PROPERTIES: HCI is produced. HAZARDOUS COMBUSTION PRODUCTS: HCI is produced. EXTINGUISHING MEDIA: Use water, dry chemicals, carbon dioxide, sand or foam. Use extinguishing media appropriate for surrounding fire. PROTECTION OF FIREFIGHTERS: Do not enter confined fire space without full bunker gear (helmet with face shield, bunker coat, gloves and rubber boots), including a positive pressure NIOSH approved self-contained breathing apparatus. Water may be used to keep fire-exposed containers cool until fire is out. Page 2 of 7 Vanson HaloSource, Inc. Material Safety Data Sheet Material Name: SeaKlear® Phosphate Remover Telephone No: 425-881-6464 VHI-MSDS-02.36 REV 05 Date Prepared: 12-19-05 SECTION 6: ACCIDENTAL RELEASE MEASURES PERSONAL PROTECTIVE EQUIPMENT: See Section 8 (Personal Protective Equipment). ENVIRONMENTAL PRECAUTIONS: None METHODS FOR CLEANING UP: Contain large spills and pump to recover. Small spills can be mopped up and recovered. SECTION 7: HANDLING AND STORAGE SAFE HANDLING RECOMMENDATIONS VENTILATION: Use general ventilation FIRE PREVENTION: Not flammable SPECIAL HANDLING REQUIREMENTS: Use appropriate PPE SAFE STORAGE RECOMMENDATIONS CONTAINMENT: Secondary containment is recommended. STORAGE ROOM RECOMMENDATIONS: Store in cool, dry place. Keep container closed when not in use; keep out of the reach of children. INCOMPATIBLE MATERIALS: None known. STORAGE CONDITIONS: Store in cool, dry place. Keep container closed when not in use; keep out of the reach of children. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: General ventilation PERSONAL PROTECTIVE EQUIPMENT (PPE) EYE/FACE PROTECTION: Safety glasses are recommended under normal conditions. SKIN PROTECTION: Avoid contact with skin. Page 3 of 7 Vanson HaloSource, Inc. Material Safety Data Sheet Material Name: SeaKlear® Phosphate Remover Telephone No: 425-881-6464 VHI-MSDS-02.36 REV 05 Date Prepared: 12-19-05 HAND PROTECTION: Chemical resistant gloves are recommended to minimize potential irritation from handling. RESPIRATORY PROTECTION: None required where adequate ventilation conditions exist. GOOD HYGEIENE/WORK PRACTICES: Always follow good hygiene/work practices by avoiding vapors or mists and contact with eyes and skin. Thoroughly wash hands after handling and before eating or drinking. Always wear the appropriate PPE when repairing or performing maintenance on contaminated equipment. EXPOSURE GUIDELINES INGREDIENT CAS NO. Not applicable OSHA TWA Not applicable PERMISSIBLE EXPOSURE LIMITS WISHA STEL Not applicable TWA Not applicable STEL Not applicable ACGIH (TLV) TWA Not applicable STEL Not applicable SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES COLOR: Clear to slightly yellow PHYSICAL FORM: Liquid pH: Not applicable VAPOR DENSITY: 4.10 MELTING POINT: Not known SOLUBILITY IN WATER: Appreciable (more than 10%) SHAPE: Liquid ODOR: None VAPOR PRESSURE: Not known BOILING POINT: Not known FREEZING POINT: Not known SPECIFIC GRAVITY OR DENSITY: Not known SECTION 10: STABILITY AND REACTIVITY CHEMICAL STABILITY: Stable CONDITIONS TO AVOID: None known MATERIALS TO AVOID (INCOMPATIBILITY): None known HAZARDOUS DECOMPOSITION PRODUCTS: Hydrogen Chloride HAZARDOUS POLYMERIZATION: Will not occur SECTION 11: TOXICOLOGICAL INFORMATION ORAL LD50 (rat): 4200 DERMAL LD50 (rat): 106 Page 4 of 7 Vanson HaloSource, Inc. Material Safety Data Sheet Material Name: SeaKlear® Phosphate Remover Telephone No: 425-881-6464 VHI-MSDS-02.36 REV 05 Date Prepared: 12-19-05 SCU, LD50(MG/KG) (mouse): 2424 IV LD50 (MG/KG) (mouse): 18 SKIN IRRITATION (rabbit): Not available SKIN SENSITIZATION (guinea pig): Not available EYE IRRITATION (rabbit): Not available SECTION 12: ECOLOGICAL INFORMATION Fish 96-hour LC50 Daphnia 48-hour LC50 Green algae 96-hour EC50 Fish Chronic Value (ChV) Daphnia ChV Algae ChV =Not available =Not available =Not available =Not available =Not available =Not available SECTION 13: DISPOSAL CONSIDERATIONS If this product as supplied becomes a waste, it does meet the criteria of a hazardous waste as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Please be advised that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material. NOTE: Chemical additions, processing or otherwise altering this material may make the waste management information presented in this MSDS incomplete, inaccurate or otherwise inappropriate. SECTION 14: TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION (DOT): DOT Proper Shipping Name: DOT Hazard Class: Packing Group: UN Number: Not regulated Not regulated Not regulated Not regulated SECTION 15: REGULATORY INFORMATION TSCA STATUS: Not listed Page 5 of 7 Vanson HaloSource, Inc. Material Safety Data Sheet Material Name: SeaKlear® Phosphate Remover Telephone No: 425-881-6464 VHI-MSDS-02.36 REV 05 Date Prepared: 12-19-05 CERCLA REPORTABLE QUANTITY (RQ): CHEMICAL NAME RQ Not applicable Not applicable SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (EHS): CHEMICAL NAME None TPQ RQ Not applicable Not applicable SARA TITLE III SECTION 311/312 HAZARD CATEGORIES: Does this product/material meet the definition of the following hazard classes according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of SARA Title III? ACUTE HEALTH HAZARD Yes CHRONIC HEALTH HAZARD No FIRE HAZARD REACTIVE HAZARD No No SUDDEN RELEASE OF PRESSURE No SARA TITLE III SECTION 313 TOXIC CHEMICALS INFORMATION: CHEMICAL NAME None CAS NO. CONCENTRATION (%) Not applicable Not applicable CALIFORNIA PROPOSITION 65: The following chemical(s) is/are known to the state of California to cause cancer or reproductive toxicity: CHEMICAL NAME None CAS NO. CONCENTRATION (%) Not applicable Not applicable SECTION 16: OTHER INFORMATION REVISION INFORMATION: MSDS sections(s) changed since last revision of document: In an attempt to make Vanson-HaloSource’s MSDSs more user friendly, as well as to keep current with all applicable regulations, all of the sections in this MSDS have had slight to significant changes since the last revision. DISCLAIMER: **************************************************************************************************************************************** ** The above information is based upon information Vanson-HaloSource Inc. believes to be reliable and is supplied for informational purposes only. Vanson-HaloSource Inc. disclaims any liability for damage which results from the use of Page 6 of 7 Vanson HaloSource, Inc. Material Safety Data Sheet Material Name: SeaKlear® Phosphate Remover Telephone No: 425-881-6464 VHI-MSDS-02.36 REV 05 Date Prepared: 12-19-05 the above information and nothing contained therein shall constitute a guarantee, warranty (including fitness for a particular purpose) or representation with respect to the accuracy or completeness of the data, the product described or their use for any specific purpose even if that purpose is known to Vanson-HaloSource Inc. The final determination of the suitability of the information, the manner of use of the information or product and potential infringement is the sole responsibility of the user. **************************************************************************************************************************************** ** MSDS PREPARED BY: Jeremy Heath, EH&S Specialist Page 7 of 7 Vanson HaloSource, Inc Material Safety Data Sheet Material Name: SeaKlear® Natural Clarifier for Pools Telephone No: 425-881-6464 VHI-MSDS-02.13 Rev 03 Date Prepared: 04-28-05 24-HOUR EMERGENCY PHONE: CHEMTREC 800-424-9300 SECTION I – CHEMICAL PRODUCT & COMPANY IDENTIFICATION Manufacturer's Name: Corporate Address: Emergency Phone: Manufacturer's Phone: Material Name: Chemical Name: Vanson HaloSource, Inc. 14716 NE 87th Street, Redmond, WA 98052 800-424-9300 Chemtrec (425) 881-6464 SeaKlear Natural Clarifier Chitosan acetate SECTION II – COMPOSITION, INFORMATION ON INGREDIENTS CAS NO. 9012-76-4 64-19-7 INGREDIENT EXPOSURE LIMITS Chitosan Acetic Acid Water NA SECTION III – HAZARDS IDENTIFICATION PRINCIPAL HEALTH HAZARDS, INCLUDING SIGNIFICANT ROUTES, EFFECTS, AND SYMPTOMS OF OVEREXPOSURE AND MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE MAY BE: EYE: May be mildly irritating to eyes. SKIN: Not hazardous to skin. INHALATION: See first aid section below. INGESTION: Not likely to be hazardous by ingestion. CARCINOGENICITY: Not listed by National Toxicology Program (NTP) OSHA, or International Agency for Research on Cancer (IARC) SECTION IV - FIRST AID EYES: Remove contact lenses (if applicable), flush with water for 15 minutes. Call a physician. SKIN: Cleansing the skin after exposure is advisable. INHALATION: If large amounts of fumes are inhaled, remove to fresh air and consult a physician. INGESTION: Consult a physician if necessary. Page 1 of 5 Vanson HaloSource, Inc Material Safety Data Sheet Material Name: SeaKlear® Natural Clarifier for Pools Telephone No: 425-881-6464 VHI-MSDS-02.13 Rev 03 Date Prepared: 04-28-05 SECTION V - FIRE FIGHTING MEASURES HAZARDOUS COMBUSTION PRODUCTS: NA EXTINGUISHING MEDIA: Does not burn. Use water, dry chemicals, carbon dioxide, sand or foam. Use extinguishing media appropriate for surrounding fire. FIREFIGHTING INSTRUCTIONS: Do not enter confined fire space without full bunker gear (helmet with face shield, bunker coat, gloves and rubber boots), including a positive pressure NIOSH approved self-contained breathing apparatus. Water may be used to keep fire-exposed containers cool until fire is out. FLASH POINT: NA SECTION VI – ACCIDENTAL RELEASE MEASURES SPILL: Wear suitable protective clothing. Dilute with water and hose down. DISPOSAL INFORMATION: Material is 100% biodegradable, is nontoxic and can be disposed of in any approved manner. Treatment, storage, transportation and disposal must be in accordance with applicable Federal State/Provincial and local regulations. DISPOSAL METHODS: Dilute with water and hose down. SECTION VII - HANDLING & STORAGE HANDLING & STORAGE PRECAUTIONS: 10-50°C recommended (will freeze @ ~3°C). Shelf life is indefinite but viscosity will decrease over time. The container should be kept covered to prevent contamination. SECTION VIII - EXPOSURE CONTROLS/ PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT (PPE): Good hygiene practices should be strictly followed. Before eating, drinking or smoking, wash face and hands thoroughly. Emergency showers and eyewash facilities should be accessible. EYE PROTECTION: Safety glasses recommended. SKIN PROTECTION: Rubber gloves recommended. PROTECTIVE CLOTHING: NA Page 2 of 5 Vanson HaloSource, Inc Material Safety Data Sheet Material Name: SeaKlear® Natural Clarifier for Pools Telephone No: 425-881-6464 VHI-MSDS-02.13 Rev 03 Date Prepared: 04-28-05 PROTECTIVE FOOTWEAR: NA RESPIRATORY PROTECTION: NA . VENTILATION REQUIREMENTS: Generally adequate SECTION IX - PHYSICAL & CHEMICAL PROPERTIES PHYSICAL FORM: Clear to pale yellow viscous liquid with a pungent vinegar odor. BOILING POINT: 211°F MELTING POINT: NA pH: 3.0-4.5 SOLUBILITY IN WATER: Soluble. SPECIFIC GRAVITY: 1.0-1.1 g/mL SECTION X - STABILITY & REACTIVITY DATA CHEMICAL STABILITY: Stable. HAZARDOUS POLYMERIZATION: Will not occur. INCOMPATIBLES: Strong oxidizing material and strong bases. DECOMPOSITION PRODUCTS: Decomposition will not occur. Material is bio-degradable. SECTION XI - TOXICOLOGICAL INFORMATION ORAL Rat LD50 (MG/KG): NA NA Ipr Rat, LD50(MG/KG): SCU Mouse, LD50(MG/KG): NA IV-Mouse, LD50(MG/KG): NA DERMAL LD50 (rabbit): NA EYE IRRITATION (rabbit): NA SKIN IRRITATION (rabbit): NA Page 3 of 5 Vanson HaloSource, Inc Material Safety Data Sheet Material Name: SeaKlear® Natural Clarifier for Pools Telephone No: 425-881-6464 VHI-MSDS-02.13 Rev 03 Date Prepared: 04-28-05 SECTION XII - ECOLOGICAL INFORMATION Fish 96-hour LC50 Daphnia 48-hour LC50 Green algae 96-hour EC50 Fish Chronic Value (ChV) Daphnia ChV Algae ChV = = = = = = NA NA NA NA NA NA SECTION XIII - DISPOSAL CONSIDERATION WASTE DISPOSAL METHOD: Dispose of in accordance with all applicable federal, local and State environmental regulations. Material is 100% biodegradable, is nontoxic and can be disposed of in any approved manner. SECTION XIV - TRANSPORTATION INFORMATION DOT Proper Shipping Name: DOT Hazard Class: Packing Group: UN Number: Product RQ (lbs.): DOT Label: DOT Placard: Chemicals, N.O.S. (non-regulated) (Domestic & International) Not regulated as a hazardous material NA NA NA NA NA SECTION XV - REGULATORY INFORMATION MATERIAL IS REPORTED IN EPA TSCA INVENTORY LIST?: No MATERIAL IS LISTED AS A CARCINOGEN/POTENTIAL CARCINOGEN IN FOLLOWING?: No NTP ANNUAL REPORT: No IARC GROUP I OR II: No OSHA 29CFR PART 1910 SUBPART Z: No DOES PRODUCT CONTAIN A TOXIC CHEMICAL SUBJECT TO SARA TITLE III SECTION 313 REPORTING: No SARA TITLE III SECTION 311/312 CLASSIFICATIONS: None Page 4 of 5 Vanson HaloSource, Inc Material Safety Data Sheet Material Name: SeaKlear® Natural Clarifier for Pools Telephone No: 425-881-6464 VHI-MSDS-02.13 Rev 03 Date Prepared: 04-28-05 SECTION XVI – OTHER INFORMATION The above information is based upon information Vanson-HaloSource, Inc. believes to be reliable and is supplied for informational purposes only. Vanson-HaloSource, Inc. disclaims any liability for damage which results from the use of the above information and nothing contained therein shall constitute a guarantee, warranty (including fitness for a particular purpose) or representation with respect to the accuracy or completeness of the data, the product described or their use for any specific purpose even if that purpose is known to Vanson-HaloSource, Inc. The final determination of the suitability of the information, the manner of use of the information or product and potential infringement is the sole responsibility of the user. Page 5 of 5 The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries. DuPont Material Safety Data Sheet Page 1 ---------------------------------------------------------------------DuPont(tm) Pool Care Metal Remover 6503CR Revised 8-DEC-2005 ------------------------------------------------------------------------------------------------------------------------------------------CHEMICAL PRODUCT/COMPANY IDENTIFICATION ---------------------------------------------------------------------Company Identification MANUFACTURER/DISTRIBUTOR DuPont Chemical Solutions Enterprise 1007 Market Street Wilmington, DE 19898 PHONE NUMBERS Product Information Transport Emergency Medical Emergency : 1-800-441-7515 (outside the U.S. 302-774-1000) : CHEMTREC 1-800-424-9300(outside U.S. 703-527-3887) : 1-800-441-3637 (outside the U.S. 302-774-1000) ---------------------------------------------------------------------COMPOSITION/INFORMATION ON INGREDIENTS ---------------------------------------------------------------------Components Material Sodium Citrate CAS Number 68-04-2 % ---------------------------------------------------------------------HAZARDS IDENTIFICATION ---------------------------------------------------------------------Potential Health Effects Eye Contact: May cause eye irritation. Skin Contact: May cause skin irritation. Ingestion: May cause irritation of the gastrointestinal tract, nausea, vomiting and diarrhea. Inhalation: May be harmful if inhaled. 6503CR DuPont Material Safety Data Sheet Page 2 (HAZARDS IDENTIFICATION - Continued) Carcinogenicity Information None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC, NTP, OSHA or ACGIH as a carcinogen. ---------------------------------------------------------------------FIRST AID MEASURES ---------------------------------------------------------------------First Aid INHALATION If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. SKIN CONTACT Flush skin with water after contact. before reuse. Wash contaminated clothing EYE CONTACT In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. INGESTION If swallowed, do not induce vomiting. Immediately give 2 glasses of water. Never give anything by mouth to an unconscious person. Call a physician. ---------------------------------------------------------------------FIRE FIGHTING MEASURES ---------------------------------------------------------------------Flammable Properties Not a fire or explosion hazard. Extinguishing Media Use media appropriate for surrounding material. Fire Fighting Instructions Evacuate personnel to a safe area. Wear self-contained breathing apparatus (SCBA) and full protective equipment. 6503CR DuPont Material Safety Data Sheet Page 3 ---------------------------------------------------------------------ACCIDENTAL RELEASE MEASURES ---------------------------------------------------------------------Safeguards (Personnel) NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. Wear self-contained breathing apparatus (SCBA) and full protective gear. Spill Clean Up Flush to sewer. ---------------------------------------------------------------------HANDLING AND STORAGE ---------------------------------------------------------------------Handling (Personnel) Avoid inhalation. Avoid contact with eyes, skin or clothing. Wash thoroughly after handling. Wash clothing after use. Handling (Physical Aspects) Keep container tightly closed. Storage Store in a cool, dry place. ---------------------------------------------------------------------EXPOSURE CONTROLS/PERSONAL PROTECTION ---------------------------------------------------------------------Engineering Controls Use only with adequate ventilation. Personal Protective Equipment EYE/FACE PROTECTION Wear coverall chemical splash goggles. Additionally, wear a face shield where the possibility exists for face contact due to splashing or spraying of material. RESPIRATORS Wear NIOSH approved respiratory protection as appropriate. PROTECTIVE CLOTHING Where there is potential for skin contact have available and wear as appropriate impervious gloves, apron, pants, jacket, hood and boots. 6503CR DuPont Material Safety Data Sheet Page 4 (EXPOSURE CONTROLS/PERSONAL PROTECTION - Continued) Exposure Guidelines Exposure Limits DuPont(tm) Pool Care Metal Remover PEL (OSHA) : None Established TLV (ACGIH) : None Established ---------------------------------------------------------------------PHYSICAL AND CHEMICAL PROPERTIES ---------------------------------------------------------------------Physical Data Boiling Point Solubility in Water Odor Color Specific Gravity Form : : : : : : >1500 C (>2732 F) Soluble None. Clear. 1 g/mL Liquid. ---------------------------------------------------------------------STABILITY AND REACTIVITY ---------------------------------------------------------------------Chemical Stability Stable. Incompatibility with Other Materials None reasonably foreseeable. Decomposition Hazardous decomposition products: POx. toxic fumes of Na2O and Polymerization Polymerization will not occur. ---------------------------------------------------------------------TOXICOLOGICAL INFORMATION ---------------------------------------------------------------------Animal Data Sodium Citrate: Oral LD50 mg/kg (rat): 1546 mg/kg 6503CR DuPont Material Safety Data Sheet Page 5 ---------------------------------------------------------------------DISPOSAL CONSIDERATIONS ---------------------------------------------------------------------Waste Disposal Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations. ---------------------------------------------------------------------TRANSPORTATION INFORMATION ---------------------------------------------------------------------Shipping Information Not Regulated as a hazardous material by DOT, IMO, or IATA. ---------------------------------------------------------------------REGULATORY INFORMATION ---------------------------------------------------------------------U.S. Federal Regulations TITLE III HAZARD CLASSIFICATIONS SECTIONS 311, 312 Acute Chronic Fire Reactivity Pressure : : : : : Yes No No No No ---------------------------------------------------------------------OTHER INFORMATION ---------------------------------------------------------------------NFPA, NPCA-HMIS NPCA-HMIS Rating Health Flammability Reactivity : 1 : 0 : 0 Personal Protection rating to be supplied by user depending on use conditions. ---------------------------------------------------------------------The data in this Material Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. Responsible for MSDS : MSDS Coordinator > : DuPont Chemical Solutions Enterprise Address : Wilmington, DE 19898 Telephone : (800) 441-7515 This information is based upon technical information believed to be reliable. It is subject to revision as additional knowledge and experience is gained. End of MSDS Material Safety Data Sheet POLY-BRITE Section 1. Chemical product and company identification : POLY-BRITE : Bottle wash additive : Ecolab Food and Beverage 5105 Tomken Road Mississauga ON L4W 2X5 1-800-352-5326 990283-01 : : 25-January-2006 EMERGENCY HEALTH INFORMATION: 1-800-328-0026 Outside United States and Canada CALL 1-651-222-5352 (in USA) Trade name Product use Supplier Code Date of issue Section 2. Composition, information on ingredients Name polyphosphoric acids, sodium salts triphosphoric acid, pentasodium salt disodium metasilicate sodium phosphate, tribasic CAS number% by weight 68915-31-1 5- 10 7758-29-4 3-7 6834-92-0 3-7 7601-54-9 1-5 Section 3. Hazards identification Physical state Emergency overview : Liquid. (Liquid.) : DANGER! CAUSES EYE AND SKIN BURNS. CAUSES SEVERE RESPIRATORY TRACT IRRITATION. HARMFUL IF SWALLOWED. Do not ingest. Do not get in eyes, on skin or clothing. Avoid breathing vapour or mist. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. : Skin contact, Eye contact, Inhalation, Ingestion Routes of entry Potential acute health effects Eyes : Skin : Inhalation : : Ingestion Corrosive to eyes. Corrosive to the skin. Severely irritating to the respiratory system. Harmful if swallowed. Causes burns to mouth, throat and stomach. See toxicological information (section 11) Section 4. First-aid measures Eye contact Skin Contact Inhalation Ingestion : In case of contact, immediately flush eyes with cool running water. Remove contact lenses and continue flushing with plenty of water for at least 15 minutes. Get medical attention immediately. : In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. : Rinse mouth; then drink one or two large glasses of water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Obtain medical attention immediately. Page: 2/4 POLY-BRITE Section 5. Fire-fighting measures Auto-ignition temperature Flash point Flammable limits Upper: Lower: Products of combustion Fire-fighting media and instructions : Not available. : > 100°C Not available. Not available. : Not available. : Use an extinguishing agent suitable for the surrounding fire. Dyke liquid for later disposal. No specific hazard. : Fire-fighters should wear appropriate protective equipment and self-contained Special protective equipment breathing apparatus (SCBA) with a full face-piece operated in positive pressure for fire-fighters mode. Risk of explosion of the product in the presence of mechanical impact: Not available. Risk of explosion of the product in the presence of static discharge: Not available. Section 6. Accidental release measures Personal Precautions Environmental precautions Methods for cleaning up : Ventilate area of leak or spill. Do not touch damaged containers or spilled material unless wearing appropriate protective equipment (Section 8). Stop leak if without risk. Do not allow to enter drains or watercourses. : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. : If emergency personnel are unavailable, contain spilt material. For small spills, add absorbent (soil may be used in the absence of other suitable materials), scoop up material and place in a sealable, liquid-proof container for disposal. For large spills, dyke spilt material or otherwise contain material to ensure runoff does not reach a waterway. Place spilt material in an appropriate container for disposal. Section 7. Handling and storage Handling Storage : Do not ingest. Do not get in eyes, on skin or on clothing. Keep container closed. Use only with adequate ventilation. Avoid breathing vapour or mist. Wash thoroughly after handling. : Keep out of the reach of children. Keep container tightly closed. Keep container in a cool, wellventilated area. Store between 40 and 0°C Section 8. Exposure controls, personal protection Engineering controls : Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapours below their respective occupational exposure limits. Provide eyewash and safety shower in area if contact or splash hazard exists. Personal protection Eyes : Use chemical splash goggles. For continued or severe exposure wear a face shield over the goggles. Hands : Use chemical-resistant, impervious gloves. Skin : Use synthetic apron, other protective equipment as necessary to prevent skin contact. Respiratory : Wear appropriate respirator when ventilation is inadequate and occupational exposure limits are exceeded. Consult local authorities for acceptable exposure limits. Page: 3/4 POLY-BRITE Section 9. Physical and chemical properties Physical state Colour Odour pH Boiling/condensation point Melting/freezing point Specific gravity Vapour pressure Vapour density Odour threshold Evaporation rate LogKow : : : : : : : : : : : : Liquid. (Liquid.) Clear. Faint odour. 12.98 (100%) Not available. Not available. 1.18 (Water = 1) Not applicable. Not available. Not available. Not available. Not available. Section 10. Stability and reactivity : The product is stable. : Not available. : Highly reactive with acids. Slightly reactive to reactive with metals. Incompatibility with various : Not available. substances Hazardous Decomposition : Not available. Products Stability Conditions of instability Reactivity Section 11. Toxicological information Potential acute health effects : Corrosive to eyes. Eyes : Corrosive to the skin. Skin : Severely irritating to the respiratory system. Inhalation : Harmful if swallowed. Causes burns to mouth, throat and stomach. Ingestion Irritancy of Product : Hazardous by WHMIS criteria. Potential chronic health effects : No known significant effects or critical hazards. Carcinogenic effects : No known significant effects or critical hazards. Mutagenic effects : No known significant effects or critical hazards. Teratogenic effects Reproductive effects : No known significant effects or critical hazards. Sensitization to Product : No known significant effects or critical hazards. Synergistic products : Not available. (toxicologically) Toxicity data Ingredient name Test Result Route Species polyphosphoric acids, sodium LD50 3053 mg/kg Oral Rat salts LD50 7572 mg/kg Oral Mouse triphosphoric acid, pentasodium LD50 3120 mg/kg Oral Rat salt LD50 3100 mg/kg Oral Mouse LD50 >4640 mg/kg Dermal Rabbit Oral Rat disodium metasilicate LD50 1153 mg/kg Oral Mouse LD50 770 mg/kg Oral Dog LDLo 250 mg/kg pig Oral LDLo 250 mg/kg : Not available. Target organs Page: 4/4 POLY-BRITE Section 12. Ecological information Products of degradation : These products are phosphates. Some metallic oxides. Section 13. Disposal considerations Waste disposal : The generation of waste should be avoided or minimised wherever possible. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Consult your local or regional authorities. Section 14. Transport information Regulatory information TDG Classification UN number Proper shipping name Class Packing group Additional information UN3253 III Explosive Limit and Limited Quantity Index 5 DISODIUM TRIOXOSILICATE 8 Passenger Carrying Road or Rail Index 25 APPLIES ONLY DURING ROAD TRANSPORT Any variation of the shipping description based on the packaging is not addressed. Section 15. Regulatory information WHMIS : Class E: Corrosive material. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Section 16. Other information Date of issue : 25-January-2006. Responsible name : Regulatory Affairs Date of previous issue : 25-January-2006. Notice to reader The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION. SAFETY DATA SHEET Date of issue: 18/08/94 1. Identification of the substance/preparation and of the company/undertaking Identification of the product Catalogue No: 16612 ID No.: 1661200 Product name: Aquamerck® Simple pH of swimming pool water test kit- Reagent 1 Manufacturer/supplier identification Company: VWR International Ltd., Merck House, Poole, Dorset, BH15 1TD, England Telephone : + 44 (0) 1202 669700 Telefax : + 44 (0) 1202 665599 Emergency telephone No.: + 44 (0) 1202 669700 2. Composition/information on ingredients Chemical characterization Solution in water Product name: Aquamerck® simple pH of swimming pool water test - Reagent 1 3. Hazards identification 4. First aid measures - Eye contact: Irrigate thoroughly with water. If discomfort persists obtain medical attention. - Inhalation: Remove from exposure. - Skin contact: Wash off thoroughly with soap and water. - Ingestion: Wash out mouth thoroughly with water. In severe cases obtain medical attention. 5. Fire-fighting measures Special risks: Not applicable. Suitable extinguishing media: Not applicable 6. Accidental release measures Wear appropriate protective clothing. If local regulations permit, mop up with plenty of water and run to waste, diluting greatly with running water. Otherwise transfer to container and arrange removal by disposal company. Wash site of spillage thoroughly with detergent and water. For large spillages liquids should be contained with sand or earth and both liquids and solids transferred to salvage containers. Any residues should be treated as for small spillages. 7. Handling and storage Handling: Storage: Store at room temperature (15 to 25°C recommended). Keep well closed and protected from direct sunlight and moisture. 8. Exposure controls/personal protection UK Exposure Limits: None assigned Personal protective equipment: As appropriate to the situation and the quantity handled. - Respirator: Not applicable - Ventilation: Not applicable - Gloves: Rubber or plastic - Eye Protection: Goggles or face-shield - Other Precautions: Plastic apron, sleeves, boots - if handling large quantities 9. Physical and chemical properties General information: Product description Red solution Health, safety and environmental information: Melting temperature Boiling temperature Density(g/ml) Vapour pressure Relative vapour density: Solubility in water Flash point Explosion limits: lower: Auto-ignition temperature n/a n/a n/a n/a n/a Miscible in all proportions n/a n/a n/a 10. Stability and reactivity Stable. No data 11. Toxicological information May be harmful if ingested in quantity. May irritate eyes. Stains. Further data No data We have no evidence of carcinogenic effects. We have no evidence of mutagenic or teratogenic effects. 12. Ecological information No environmental hazard is anticipated provided that the material is handled and disposed of with due care and attention. 13. Disposal considerations Chemical residues are generally classified as special waste, and as such are covered by regulations which vary according to location. Contact your local waste disposal authority for advice, or pass to a chemical disposal company. Rinse out empty containers thoroughly before returning for recycling. 14. Transport information Not subject to transport regulations. 15. Regulatory information Labelling according to EC directives Local Regulations 16. Other information Date of issue: Date of print: 18/08/94 13/07/05 HACH LANGE GmbH Safety Data Sheet according to Regulation (EU) No. 1907/2006 28262-53 APA 6000 Alkalinity Standard 2 Print date : 17.01.2008 Product code : 2826253 Page 1 of 4 1. Identification of the substance/preparation and of the company/undertaking Identification of the substance or preparation 28262-53 APA 6000 Alkalinity Standard 2 Use of the substance/preparation Water analysis Company/undertaking identification Company name : Street : Place : Telephone : e-mail : Internet : HACH LANGE GmbH Willstätterstr. 11 D-40549 Düsseldorf +49 (0)211 5288-383 marion.ives@hach-lange.de www.hach-lange.com Inquiry office : HACH LANGE Ltd. Pacific Way Salford Manchester M50 1DL - United Kingdom Tel. +44 (0) 161 872 1487 e-Mail: martin.butterfield@hach-lange.co.uk HACH LANGE Ltd. Unit 1, Chestnut Road Western Industrial Estate Dublin 12 - Ireland Tel. +353 (0)1 4602522 e-Mail: joseph.diver@hach-lange.ie 2. Hazards identification Classification The product does not need to be labelled in accordance with EC directives or respective national laws. 3. Composition/information on ingredients Chemical characterization ( preparation ) Hazardous components EC-No. 213-791-2 207-838-8 CAS-No. Chemical name Quantity Classification 7732-18-5 Water > 99 % 497-19-8 Sodium carbonate 0,1 - 1,0 % Xi R36 Full text of each relevant R phrase can be found in heading 16. 4. First aid measures After inhalation Move to fresh air. After contact with skin Wash off immediately with plenty of water. After contact with eyes Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. After ingestion Clean mouth with water and drink afterwards plenty of water. Revision no. : 1.00 GB - EN Revision date : 01.06.2007 HACH LANGE GmbH Safety Data Sheet according to Regulation (EU) No. 1907/2006 28262-53 APA 6000 Alkalinity Standard 2 Print date : 17.01.2008 Product code : 2826253 Page 2 of 4 Advice to doctor Treat symptomatically. 5. Fire-fighting measures Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. The product itself does not burn. Special exposure hazards arriving from substance or preparation itself, combustion products, resulting gases Fire may liberate hazardous vapours. Special protective equipment for fire-fighters In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. Additional information Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 6. Accidental release measures Personal precautions Use personal protective equipment. Environmental precautions Do not flush into surface water or sanitary sewer system. Methods for cleaning up/taking up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). 7. Handling and storage Handling Advice on safe handling Use only in well-ventilated areas. Storage Requirements for storage rooms and vessels Keep in a dry, cool place. 8. Exposure controls/personal protection Exposure limit values Exposure controls Protective and hygiene measures The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Hand protection Use barrier skin cream. Wash hands before breaks and after work. Chemical resistant protective gloves The protective gloves to be used must comply with the specifications of EC directive 89/686/EEC and the resultant standard EN374. Eye protection Safety glasses with side-shields Revision no. : 1.00 GB - EN Revision date : 01.06.2007 HACH LANGE GmbH Safety Data Sheet according to Regulation (EU) No. 1907/2006 28262-53 APA 6000 Alkalinity Standard 2 Print date : 17.01.2008 Product code : 2826253 Page 3 of 4 Skin protection Remove and wash contaminated clothing before re-use. 9. Physical and chemical properties General information Physical state : Colour : Odour : liquid colourless odourless Important health, safety and environmental information Test method Changes in the physical state Boiling point : 100 °C Flash point : not applicable Lower explosion limits : Upper explosion limits : Density (at 20 °C) : Water solubility : not applicable not applicable 1 g/cm³ miscible 10. Stability and reactivity Conditions to avoid No dangerous reaction known under conditions of normal use. Materials to avoid No dangerous reaction known under conditions of normal use. Hazardous decomposition products No decomposition if stored and applied as directed. 11. Toxicological information Acute toxicity No data is available on the product itself. Specific effects in experiment on an animal No data is available on the product itself. 12. Ecological information Ecotoxicity No data is available on the product itself. Do not flush into surface water or sanitary sewer system. 13. Disposal considerations Advice on disposal In accordance with local and national regulations. Waste disposal number of waste from residues/unused products 160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures of laboratory chemicals Classified as hazardous waste. Revision no. : 1.00 GB - EN Revision date : 01.06.2007 HACH LANGE GmbH Safety Data Sheet according to Regulation (EU) No. 1907/2006 28262-53 APA 6000 Alkalinity Standard 2 Print date : 17.01.2008 Product code : 2826253 Page 4 of 4 Waste disposal number of used product 160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures of laboratory chemicals Classified as hazardous waste. Waste disposal number of contaminated packaging 160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded chemicals; laboratory chemicals, consisting of or containing dangerous substances, including mixtures of laboratory chemicals Classified as hazardous waste. 14. Transport information Land transport (ADR/RID) Remarks (land transport) Not subject to transport regulations. Inland waterways transport Remarks (inland waterways transport) Not tested Marine transport Remarks (marine transport) Not subject to transport regulations. Air transport Remarks (air transport) Not subject to transport regulations. 15. Regulatory information Labelling Additional advice on labelling Classification according to European directive on classification of hazardous preparations 1999/45/EC. EU regulatory information Additional information The product does not need to be labelled in accordance with EC directives or respective national laws. National regulatory information Water contaminating class : - - not water contaminating 16. Other information Full text of R-phrases referred to under sections 2 and 3 36 Irritating to eyes. Other data The information is based on present level of our knowledge. It does not, however, give assurances of product properties and establishes no contract legal rights. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.) Revision no. : 1.00 GB - EN Revision date : 01.06.2007 SIGMA-ALDRICH MATERIAL SAFETY DATA SHEET Date Printed: 03/10/2007 Date Updated: 02/01/2006 Version 1.3 Section 1 - Product and Company Information Product Name 1,3,5-TRIS(2-HYDROXYETHYL)CYANURIC ACID, 97% 309001 ALDRICH Product Number Brand Company Address Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 US 800-325-5832 800-325-5052 314-776-6555 Technical Phone: Fax: Emergency Phone: Section 2 - Composition/Information on Ingredient Substance Name 1,3,5-TRIS(2-HYDROXYETHYL)CYANURIC ACID,97% Formula CAS # 839-90-7 SARA 313 No C9H15N3O6 Section 3 - Hazards Identification EMERGENCY OVERVIEW Irritant. Irritating to eyes, respiratory system and skin. For additional information on toxicity, please refer to Section 11. Section 4 - First Aid Measures ORAL EXPOSURE If swallowed, wash out mouth with water provided person is conscious. Call a physician. INHALATION EXPOSURE If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. DERMAL EXPOSURE In case of contact, immediately wash skin with soap and copious amounts of water. EYE EXPOSURE In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes. Section 5 - Fire Fighting Measures FLASH POINT N/A AUTOIGNITION TEMP N/A FLAMMABILITY N/A EXTINGUISHING MEDIA Suitable: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. FIREFIGHTING Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Specific Hazard(s): Emits toxic fumes under fire conditions. EXPOSURE HAZARD(S) Material: Irritant. Section 6 - Accidental Release Measures PROCEDURE(S) OF PERSONAL PRECAUTION(S) Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves. METHODS FOR CLEANING UP Sweep up, place in a bag and hold for waste disposal. Avoid raising dust. Ventilate area and wash spill site after material pickup is complete. Section 7 - Handling and Storage HANDLING User Exposure: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE Suitable: Keep tightly closed. Store in a cool dry place. Section 8 - Exposure Controls / PPE ENGINEERING CONTROLS Safety shower and eye bath. Mechanical exhaust required. PERSONAL PROTECTIVE EQUIPMENT Respiratory: Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Where risk assessment shows air-purifying respirators are appropriate use a dust mask type N95 (US) or type P1 (EN 143) respirator. Hand: Rubber gloves. Eye: Chemical safety goggles. GENERAL HYGIENE MEASURES Wash thoroughly after handling. Wash contaminated clothing before reuse. Section 9 - Physical/Chemical Properties Molecular Weight pH BP/BP Range ALDRICH - 309001 261.24 AMU N/A N/A www.sigma-aldrich.com Page 2 MP/MP Range Freezing Point Vapor Pressure Vapor Density Saturated Vapor Conc. SG/Density Bulk Density Odor Threshold Volatile% VOC Content Water Content Solvent Content Evaporation Rate Viscosity Surface Tension Partition Coefficient Decomposition Temp. Flash Point Explosion Limits Flammability Autoignition Temp Refractive Index Optical Rotation Miscellaneous Data Solubility 136.0 - 140.0 °C N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A = not available Section 10 - Stability and Reactivity STABILITY Materials to Avoid: Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide, Nitrogen oxides. Section 11 - Toxicological Information ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Causes eye and skin irritation. May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Section 12 - Ecological Information No data available. Section 13 - Disposal Considerations APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Observe all federal, state, and local environmental regulations. Section 14 - Transport Information ALDRICH - 309001 www.sigma-aldrich.com Page 3 DOT Proper Shipping Name: None Non-Hazardous for Transport: This substance is considered to be non-hazardous for transport. IATA Non-Hazardous for Air Transport: Non-hazardous for air transport. Section 15 - Regulatory Information EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26-37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. US CLASSIFICATION AND LABEL TEXT Indication of Danger: Irritant. Risk Statements: Irritating to eyes, respiratory system and skin. Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. UNITED STATES REGULATORY INFORMATION SARA LISTED: No CANADA REGULATORY INFORMATION WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR, and the MSDS contains all the information required by the CPR. DSL: Yes NDSL: No Section 16 - Other Information DISCLAIMER For R&D use only. Not for drug, household or other uses. WARRANTY The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Sigma-Aldrich Inc., shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. Copyright 2007 Sigma-Aldrich Co. License granted to make unlimited paper copies for internal use only. ALDRICH - 309001 www.sigma-aldrich.com Page 4 SIGMA-ALDRICH MATERIAL SAFETY DATA SHEET Date Printed: 03/10/2007 Date Updated: 02/01/2006 Version 1.3 Section 1 - Product and Company Information Product Name 1,3,5-TRIS(2-HYDROXYETHYL)CYANURIC ACID, 97% 309001 ALDRICH Product Number Brand Company Address Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 US 800-325-5832 800-325-5052 314-776-6555 Technical Phone: Fax: Emergency Phone: Section 2 - Composition/Information on Ingredient Substance Name 1,3,5-TRIS(2-HYDROXYETHYL)CYANURIC ACID,97% Formula CAS # 839-90-7 SARA 313 No C9H15N3O6 Section 3 - Hazards Identification EMERGENCY OVERVIEW Irritant. Irritating to eyes, respiratory system and skin. For additional information on toxicity, please refer to Section 11. Section 4 - First Aid Measures ORAL EXPOSURE If swallowed, wash out mouth with water provided person is conscious. Call a physician. INHALATION EXPOSURE If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. DERMAL EXPOSURE In case of contact, immediately wash skin with soap and copious amounts of water. EYE EXPOSURE In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes. Section 5 - Fire Fighting Measures FLASH POINT N/A AUTOIGNITION TEMP N/A FLAMMABILITY N/A EXTINGUISHING MEDIA Suitable: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. FIREFIGHTING Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Specific Hazard(s): Emits toxic fumes under fire conditions. EXPOSURE HAZARD(S) Material: Irritant. Section 6 - Accidental Release Measures PROCEDURE(S) OF PERSONAL PRECAUTION(S) Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves. METHODS FOR CLEANING UP Sweep up, place in a bag and hold for waste disposal. Avoid raising dust. Ventilate area and wash spill site after material pickup is complete. Section 7 - Handling and Storage HANDLING User Exposure: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE Suitable: Keep tightly closed. Store in a cool dry place. Section 8 - Exposure Controls / PPE ENGINEERING CONTROLS Safety shower and eye bath. Mechanical exhaust required. PERSONAL PROTECTIVE EQUIPMENT Respiratory: Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Where risk assessment shows air-purifying respirators are appropriate use a dust mask type N95 (US) or type P1 (EN 143) respirator. Hand: Rubber gloves. Eye: Chemical safety goggles. GENERAL HYGIENE MEASURES Wash thoroughly after handling. Wash contaminated clothing before reuse. Section 9 - Physical/Chemical Properties Molecular Weight pH BP/BP Range ALDRICH - 309001 261.24 AMU N/A N/A www.sigma-aldrich.com Page 2 MP/MP Range Freezing Point Vapor Pressure Vapor Density Saturated Vapor Conc. SG/Density Bulk Density Odor Threshold Volatile% VOC Content Water Content Solvent Content Evaporation Rate Viscosity Surface Tension Partition Coefficient Decomposition Temp. Flash Point Explosion Limits Flammability Autoignition Temp Refractive Index Optical Rotation Miscellaneous Data Solubility 136.0 - 140.0 °C N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A = not available Section 10 - Stability and Reactivity STABILITY Materials to Avoid: Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide, Nitrogen oxides. Section 11 - Toxicological Information ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Causes eye and skin irritation. May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Section 12 - Ecological Information No data available. Section 13 - Disposal Considerations APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Observe all federal, state, and local environmental regulations. Section 14 - Transport Information ALDRICH - 309001 www.sigma-aldrich.com Page 3 DOT Proper Shipping Name: None Non-Hazardous for Transport: This substance is considered to be non-hazardous for transport. IATA Non-Hazardous for Air Transport: Non-hazardous for air transport. Section 15 - Regulatory Information EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26-37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. US CLASSIFICATION AND LABEL TEXT Indication of Danger: Irritant. Risk Statements: Irritating to eyes, respiratory system and skin. Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. UNITED STATES REGULATORY INFORMATION SARA LISTED: No CANADA REGULATORY INFORMATION WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR, and the MSDS contains all the information required by the CPR. DSL: Yes NDSL: No Section 16 - Other Information DISCLAIMER For R&D use only. Not for drug, household or other uses. WARRANTY The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Sigma-Aldrich Inc., shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. Copyright 2007 Sigma-Aldrich Co. License granted to make unlimited paper copies for internal use only. ALDRICH - 309001 www.sigma-aldrich.com Page 4 R-0001 MATERIAL SAFETY DATA SHEET MANUFACTURER: TAYLOR TECHNOLOGIES, INC 31 LOVETON CIRCLE SPARKS, MD 21152 TELEPHONE: 410-472-4340 1.PRODUCT IDENTIFICATION CATALOG NO.: R-0001 PRODUCT NAME: DPD Reagent #1 CHEMICAL FAMILY: Inorganic salt solution 2.INGREDIENTS INGREDIENT Potassium phosphate Sodium phosphate Nonhazardous ingredients Deionized water CAS NO. 7778-77-0 7558-79-4 NA 7732-18-5 % <10 <10 <1 to 100 NATURE OF HAZARD Irritant Irritant None None 3.PHYSICAL/CHEMICAL CHARACTERISTICS STATE: Liquid APPEARANCE: Clear, colorless ODOR: None BOILING PT (F): 212 pH: 10 SPECIFIC GRAVITY: 1.24 VAPOR PRESSURE (mm Hg): 17 VAPOR DENSITY (AIR=1): .64 PERCENT VOLATILE BY VOLUME: 68 SOLUBILITY IN WATER: Soluble 4.FIRE, EXPLOSION HAZARD AND REACTIVITY DATA FLASH PT: NA METHOD: NA FLAMMABLE LIMITS: LEL: NA UEL: NA EXTINGUISHING MEDIA: Dry chemical, carbon dioxide, water spray or foam SPECIAL PROCEDURES: Wear self-contained (positive pressure if available) breathing apparatus and full-protective clothing FIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May emit toxic fumes of phosphorus oxides NFPA CODE: Health: 0 Flammability: 0 Reactivity: 0 Specific: NA CONDITIONS TO AVOID: Extreme heat, temperatures. 5.HEALTH HAZARD DATA INGREDIENT: NA TOXICITY: NA PEL: NA STEL: NA TLV: NA ROUTE(S) OF ENTRY: Inhalation Ingestion X Skin X TARGET ORGAN(S): Eyes, skin CARCINOGENICITY: NTP No IARC No OSHA No HEALTH HAZARDS AND SYMPTOMS OF EXPOSURE: EYES: Irritant. SKIN: Contact may cause irritation. INGESTION: Irritant. Large quantities may cause gastrointestinal irritation, nausea, and diarrhea. INHALATION: NA MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions R-0001 Page 2 6.PRECAUTIONARY MEASURES PROTECTIVE EQUIPMENT: General purpose gloves, safety glasses, lab coat HANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing chemical. Wash thoroughly after handling. STORAGE: Cool, dry area. Avoid direct sunlight. 7.EMERGENCY AND FIRST AID PROCEDURES EYE AND SKIN CONTACT: Immediately flush eyes with water for 20 minutes or until chemical is removed. Call physician. Wash skin thoroughly with soap and water. INGESTION: Give large amounts of water. Call physician. Treat symptoms as needed. DO NOT give anything by mouth to a person who is unconscious, rapidly losing consciousness, or convulsing. INHALATION: NA 8.SPILL AND DISPOSAL PROCEDURES SPILL OR RELEASE: Absorb with vermiculite or other inert material. Containerize for later disposal. DISPOSAL: Incineration or other method to comply with all local, state, and federal regulations. NA = Not applicable ND = Not determined NE = Not established This Material Safety Data Sheet has been prepared in accordance with 29 CFR Part 1910.1200 and contains information believed to be accurate and complete at the date of preparation. However, no warranty is expressed or implied. Advice given under "Spill and Disposal Procedures" assumes compliance with federal, state, and local regulations regarding the disposal of hazardous waste. DATE PREPARED: March 2006 R-0002 MATERIAL SAFETY DATA SHEET MANUFACTURER: TAYLOR TECHNOLOGIES, INC 31 LOVETON CIRCLE SPARKS, MD 21152 TELEPHONE: 410-472-4340 1.PRODUCT IDENTIFICATION CATALOG NO.: R-0002 PRODUCT NAME: DPD Reagent #2 CHEMICAL FAMILY: Acidic organic amine solution 2.INGREDIENTS INGREDIENT N,N-Diethyl-p-phenylenediamine sulfate Organic acid (trade secret) Nonhazardous ingredients Deionized water CAS NO. 6283-63-2 % <1 NATURE OF HAZARD Irritant, toxic Confidential <10 Irritant acid NA 7732-18-5 None None <1 to 100 3.PHYSICAL/CHEMICAL CHARACTERISTICS STATE: Liquid APPEARANCE: Clear, colorless ODOR: None BOILING PT (F): 212 pH: 1.3 SPECIFIC GRAVITY: 1.01 VAPOR PRESSURE (mm Hg): 17 VAPOR DENSITY (AIR=1): .65 PERCENT VOLATILE BY VOLUME: 99 SOLUBILITY IN WATER: Soluble 4.FIRE, EXPLOSION HAZARD AND REACTIVITY DATA FLASH PT: NA METHOD: NA FLAMMABLE LIMITS: LEL: NA UEL: NA EXTINGUISHING MEDIA: NA SPECIAL PROCEDURES: Wear self-contained (positive pressure if available) breathing apparatus and special protective clothing FIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May emit toxic fumes of carbon dioxide, carbon monoxide, nitrogen oxides, phosphine, phosphorus oxides, sulfur oxides. Contact with metals may produce hydrogen gas. NFPA CODE: Health: 1 Flammability: 0 Reactivity: 0 Specific: NA CONDITIONS TO AVOID: Extreme heat, temperatures. Contact with metals, oxidizers, strong caustic. 5.HEALTH HAZARD DATA INGREDIENT: Organic acid TOXICITY: LD50(orl-rat): 2400 mg/kg PEL: NE STEL: NE LD50(skn-rbt): >7940 mg/kg TLV: NE INGREDIENT: N,N-Diethyl-p-phenylenediamine sulfate TOXICITY: LD50(unr-rat): 450 mg/kg PEL: NE TLV: NE STEL: NE R-0002 Page 2 5.HEALTH HAZARD DATA - continued ROUTE(S) OF ENTRY: Inhalation Ingestion X Skin X TARGET ORGAN(S): Eyes, skin, gastrointestinal tract CARCINOGENICITY: NTP No IARC No OSHA No HEALTH HAZARDS AND SYMPTOMS OF EXPOSURE: EYES: Irritant SKIN: Irritant. Contact may cause dermatitis. INGESTION: Irritant, toxic. May cause gastrointestinal irritation, nausea, cramps, diarrhea. INHALATION: NA MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions 6.PRECAUTIONARY MEASURES PROTECTIVE EQUIPMENT: General purpose gloves, safety glasses, lab coat HANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing chemical. Wash thoroughly after handling. STORAGE: Cool, dry area. Avoid direct sunlight. 7.EMERGENCY AND FIRST AID PROCEDURES EYE AND SKIN CONTACT: Immediately flush eyes with water for 20 minutes or until chemical is removed. Call physician. Wash skin thoroughly with soap and water. INGESTION: Give large amounts of water or large amounts of water with milk of magnesia. Call physician. DO NOT INDUCE VOMITING. DO NOT give anything by mouth to a person who is unconscious, rapidly losing consciousness, or convulsing. INHALATION: NA 8.SPILL AND DISPOSAL PROCEDURES SPILL OR RELEASE: Neutralize with soda ash. Absorb with vermiculite or other inert material. Containerize for later disposal. DISPOSAL: Incineration or other method to comply with all local, state, and federal regulations. NA = Not applicable ND = Not determined NE = Not established This Material Safety Data Sheet has been prepared in accordance with 29 CFR Part 1910.1200 and contains information believed to be accurate and complete at the date of preparation. However, no warranty is expressed or implied. Advice given under "Spill and Disposal Procedures" assumes compliance with federal, state, and local regulations regarding the disposal of hazardous waste. DATE PREPARED: July 2005 R-0003 MATERIAL SAFETY DATA SHEET MANUFACTURER: TAYLOR TECHNOLOGIES, INC 31 LOVETON CIRCLE SPARKS, MD 21152 TELEPHONE: 410-472-4340 1.PRODUCT IDENTIFICATION CATALOG NO.: R-0003 PRODUCT NAME: DPD Reagent #3 CHEMICAL FAMILY: Inorganic salt solution 2.INGREDIENTS INGREDIENT Potassium iodide Nonhazardous ingredients Deionized water CAS NO. 7681-11-0 NA 7732-18-5 % <20 <1 to 100 NATURE OF HAZARD Irritant None None 3.PHYSICAL/CHEMICAL CHARACTERISTICS STATE: Liquid APPEARANCE: Clear, colorless ODOR: None BOILING PT (F): 212 pH: 7.6 SPECIFIC GRAVITY: 1.07 VAPOR PRESSURE (mm Hg): 17 VAPOR DENSITY (AIR=1): .6 PERCENT VOLATILE BY VOLUME: 80 SOLUBILITY IN WATER: Soluble 4.FIRE, EXPLOSION HAZARD AND REACTIVITY DATA FLASH PT: NA METHOD: NA FLAMMABLE LIMITS: LEL: NA UEL: NA EXTINGUISHING MEDIA: NA SPECIAL PROCEDURES: Wear self-contained (positive pressure if available) breathing apparatus and full-protective clothing FIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May emit toxic fumes of iodine. NFPA CODE: Health: 0 Flammability: 0 Reactivity: 0 Specific: NA CONDITIONS TO AVOID: Extreme heat, temperatures. Contact with oxidizers, acids. 5.HEALTH HAZARD DATA INGREDIENT: Potassium iodide TOXICITY: LD50(orl-mus): 1862 mg/kg PEL: NE STEL: NE TLV: NE ROUTE(S) OF ENTRY: Inhalation Ingestion X Skin X TARGET ORGAN(S): Eyes, skin CARCINOGENICITY: NTP No IARC No OSHA No HEALTH HAZARDS AND SYMPTOMS OF EXPOSURE: EYES: Contact may cause irritation. SKIN: Contact may cause irritation. INGESTION: Irritant. May cause gastrointestinal irritation. INHALATION: NA MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions R-0003 Page 2 6.PRECAUTIONARY MEASURES PROTECTIVE EQUIPMENT: General purpose gloves, safety glasses, lab coat HANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing chemical. Wash thoroughly after handling. STORAGE: Cool, dry area. Avoid direct sunlight. 7.EMERGENCY AND FIRST AID PROCEDURES EYE AND SKIN CONTACT: Immediately flush eyes with water for 20 minutes or until chemical is removed. Call physician. Wash skin thoroughly with soap and water. INGESTION: Give large amounts of water. Call physician. Treat symptoms as needed. DO NOT give anything by mouth to a person who is unconscious, rapidly losing consciousness, or convulsing. INHALATION: NA 8.SPILL AND DISPOSAL PROCEDURES SPILL OR RELEASE: Absorb with vermiculite or other inert material. Containerize for later disposal. DISPOSAL: Incineration or other method to comply with all local, state, and federal regulations. NA = Not applicable ND = Not determined NE = Not established This Material Safety Data Sheet has been prepared in accordance with 29 CFR Part 1910.1200 and contains information believed to be accurate and complete at the date of preparation. However, no warranty is expressed or implied. Advice given under "Spill and Disposal Procedures" assumes compliance with federal, state, and local regulations regarding the disposal of hazardous waste. DATE PREPARED: February 2007 R-0004 MATERIAL SAFETY DATA SHEET MANUFACTURER: TAYLOR TECHNOLOGIES, INC 31 LOVETON CIRCLE SPARKS, MD 21152 TELEPHONE: 410-472-4340 1.PRODUCT IDENTIFICATION CATALOG NO.: R-0004 PRODUCT NAME: pH Indicator Solution (Phenol Red) CHEMICAL FAMILY: Sulfonphthalein dye solution 2.INGREDIENTS INGREDIENT CAS NO. Nonhazardous ingredients, NA each Deionized water 7732-18-5 % <1 NATURE OF HAZARD None to 100 None 3.PHYSICAL/CHEMICAL CHARACTERISTICS STATE: Liquid APPEARANCE: Clear, red ODOR: Phenolic BOILING PT (F): 212 pH: 7.7 SPECIFIC GRAVITY: 1 VAPOR PRESSURE (mm Hg): 17 VAPOR DENSITY (AIR=1): .6 PERCENT VOLATILE BY VOLUME: 98 SOLUBILITY IN WATER: Soluble 4.FIRE, EXPLOSION HAZARD AND REACTIVITY DATA FLASH PT: NA METHOD: NA FLAMMABLE LIMITS: LEL: NA UEL: NA EXTINGUISHING MEDIA: NA SPECIAL PROCEDURES: Wear self-contained (positive pressure if available) breathing apparatus and full-protective clothing FIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May emit toxic fumes of carbon oxides, nitrogen oxides, ammonia. NFPA CODE: Health: 0 Flammability: 0 Reactivity: 0 Specific: NA CONDITIONS TO AVOID: Extreme heat, temperatures. 5.HEALTH HAZARD DATA INGREDIENT: NA TOXICITY: NA PEL: NA STEL: NA TLV: NA ROUTE(S) OF ENTRY: Inhalation Ingestion X Skin X TARGET ORGAN(S): Eyes, skin CARCINOGENICITY: NTP No IARC No OSHA No HEALTH HAZARDS AND SYMPTOMS OF EXPOSURE: EYES: Contact may cause irritation. SKIN: Contact may cause staining. INGESTION: Large quantities may cause gastrointestinal irritation. INHALATION: NA MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions R-0004 Page 2 6.PRECAUTIONARY MEASURES PROTECTIVE EQUIPMENT: General purpose gloves, safety glasses, lab coat HANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing chemical. Wash thoroughly after handling. STORAGE: Cool, dry area. Avoid direct sunlight. 7.EMERGENCY AND FIRST AID PROCEDURES EYE AND SKIN CONTACT: Immediately flush eyes with water for 20 minutes or until chemical is removed. Call physician. Wash skin thoroughly with soap and water. INGESTION: Give large amounts of water. Call physician. Treat symptoms as needed. DO NOT give anything by mouth to a person who is unconscious, rapidly losing consciousness, or convulsing. INHALATION: NA 8.SPILL AND DISPOSAL PROCEDURES SPILL OR RELEASE: Absorb with vermiculite or other inert material. Containerize for later disposal. DISPOSAL: Incineration or other method to comply with all local, state, and federal regulations. NA = Not applicable ND = Not determined NE = Not established This Material Safety Data Sheet has been prepared in accordance with 29 CFR Part 1910.1200 and contains information believed to be accurate and complete at the date of preparation. However, no warranty is expressed or implied. Advice given under "Spill and Disposal Procedures" assumes compliance with federal, state, and local regulations regarding the disposal of hazardous waste. DATE PREPARED: February 2007 R-0005 MATERIAL SAFETY DATA SHEET MANUFACTURER: TAYLOR TECHNOLOGIES, INC 31 LOVETON CIRCLE SPARKS, MD 21152 TELEPHONE: 410-472-4340 1.PRODUCT IDENTIFICATION CATALOG NO.: R-0005 PRODUCT NAME: Acid Demand Reagent (ADR) CHEMICAL FAMILY: Inorganic acid solution 2.INGREDIENTS INGREDIENT Sulfuric acid Deionized water CAS NO. 7664-93-9 7732-18-5 % <1 to 100 NATURE OF HAZARD Irritant acid None 3.PHYSICAL/CHEMICAL CHARACTERISTICS STATE: Liquid APPEARANCE: Clear, colorless ODOR: None BOILING PT (F): 212 pH: 1.3 SPECIFIC GRAVITY: 1 VAPOR PRESSURE (mm Hg): 17 VAPOR DENSITY (AIR=1): .6 PERCENT VOLATILE BY VOLUME: 100 SOLUBILITY IN WATER: Soluble 4.FIRE, EXPLOSION HAZARD AND REACTIVITY DATA FLASH PT: NA METHOD: NA FLAMMABLE LIMITS: LEL: NA UEL: NA EXTINGUISHING MEDIA: Dry chemical, carbon dioxide SPECIAL PROCEDURES: Wear self-contained (positive pressure if available) breathing apparatus and special protective clothing FIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May react violently with water. May react with metals to produce hydrogen gas. May ignite combustible materials. May emit toxic fumes of sulfur oxides. NFPA CODE: Health: 1 Flammability: 0 Reactivity: 0 Specific: NA CONDITIONS TO AVOID: Extreme heat, temperatures. Contact with strong alkali, metals. 5.HEALTH HAZARD DATA INGREDIENT: Sulfuric acid TOXICITY: LD50(orl-rat): 2140 mg/kg PEL: 1 mg/m3 STEL: 3 mg/m3 TLV: 1 mg/m3 ROUTE(S) OF ENTRY: Inhalation Ingestion X Skin X TARGET ORGAN(S): Eyes, skin CARCINOGENICITY: NTP No IARC No OSHA No HEALTH HAZARDS AND SYMPTOMS OF EXPOSURE: EYES: Irritant. Contact may cause burns. SKIN: Irritant. Contact may cause burns. INGESTION: Irritant. May cause gastrointestinal irritation. INHALATION: NA MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions R-0005 Page 2 6.PRECAUTIONARY MEASURES PROTECTIVE EQUIPMENT: General purpose gloves, safety glasses, lab coat HANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing chemical. Wash thoroughly after handling. STORAGE: Cool, dry area. Avoid direct sunlight. 7.EMERGENCY AND FIRST AID PROCEDURES EYE AND SKIN CONTACT: Immediately flush eyes with water for 20 minutes or until chemical is removed. Call physician. Wash skin thoroughly with soap and water. INGESTION: Give large amounts of water or large amounts of water with milk of magnesia. Call physician. DO NOT INDUCE VOMITING. DO NOT give anything by mouth to a person who is unconscious, rapidly losing consciousness, or convulsing. INHALATION: NA 8.SPILL AND DISPOSAL PROCEDURES SPILL OR RELEASE: Neutralize with soda ash. Absorb with vermiculite or other inert material. Containerize for later disposal. DISPOSAL: Incineration or other method to comply with all local, state, and federal regulations. NA = Not applicable ND = Not determined NE = Not established This Material Safety Data Sheet has been prepared in accordance with 29 CFR Part 1910.1200 and contains information believed to be accurate and complete at the date of preparation. However, no warranty is expressed or implied. Advice given under "Spill and Disposal Procedures" assumes compliance with federal, state, and local regulations regarding the disposal of hazardous waste. DATE PREPARED: October 2005 R-0006 MATERIAL SAFETY DATA SHEET MANUFACTURER: TAYLOR TECHNOLOGIES, INC 31 LOVETON CIRCLE SPARKS, MD 21152 TELEPHONE: 410-472-4340 1.PRODUCT IDENTIFICATION CATALOG NO.: R-0006 PRODUCT NAME: Base Demand Reagent (BDR) CHEMICAL FAMILY: Inorganic alkali solution 2.INGREDIENTS INGREDIENT Sodium carbonate Deionized water CAS NO. 497-19-8 7732-18-5 % <1 to 100 NATURE OF HAZARD Irritant alkali None 3.PHYSICAL/CHEMICAL CHARACTERISTICS STATE: Liquid APPEARANCE: Clear, colorless ODOR: None BOILING PT (F): 212 pH: 11.2 SPECIFIC GRAVITY: 1 VAPOR PRESSURE (mm Hg): 17 VAPOR DENSITY (AIR=1): .6 PERCENT VOLATILE BY VOLUME: 99 SOLUBILITY IN WATER: Soluble 4.FIRE, EXPLOSION HAZARD AND REACTIVITY DATA FLASH PT: NA METHOD: NA FLAMMABLE LIMITS: LEL: NA UEL: NA EXTINGUISHING MEDIA: NA SPECIAL PROCEDURES: Wear self-contained (positive pressure if available) breathing apparatus and full-protective clothing FIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May react violently with strong acids, fluorine, aluminum and lithium metals, and phosphorus pentoxide. May emit toxic fumes of sodium oxide and carbon dioxide. NFPA CODE: Health: 1 Flammability: 0 Reactivity: 0 Specific: NA CONDITIONS TO AVOID: Extreme heat, temperatures. Contact with strong acids, fluorine, metals, phosphorus pentoxide. 5.HEALTH HAZARD DATA INGREDIENT: Sodium carbonate TOXICITY: LD50(orl-rat): 4090 mg/kg PEL: NE STEL: NE TLV: NE ROUTE(S) OF ENTRY: Inhalation Ingestion X Skin X TARGET ORGAN(S): Eyes, skin CARCINOGENICITY: NTP No IARC No OSHA No HEALTH HAZARDS AND SYMPTOMS OF EXPOSURE: EYES: Irritant. SKIN: Irritant. Contact may cause irritation. INGESTION: Irritant. May cause gastrointestinal irritation. INHALATION: NA MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions R-0006 Page 2 6.PRECAUTIONARY MEASURES PROTECTIVE EQUIPMENT: General purpose gloves, safety glasses, lab coat HANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing chemical. Wash thoroughly after handling. STORAGE: Cool, dry area. Avoid direct sunlight. 7.EMERGENCY AND FIRST AID PROCEDURES EYE AND SKIN CONTACT: Immediately flush eyes with water for 20 minutes or until chemical is removed. Call physician. Wash skin thoroughly with soap and water. INGESTION: Give large amounts of water. Call physician. DO NOT INDUCE VOMITING. DO NOT give anything by mouth to a person who is unconscious, rapidly losing consciousness, or convulsing. INHALATION: NA 8.SPILL AND DISPOSAL PROCEDURES SPILL OR RELEASE: Neutralize with dilute acid. Absorb with vermiculite or other inert material. Containerize for later disposal. DISPOSAL: Incineration or other method to comply with all local, state, and federal regulations. NA = Not applicable ND = Not determined NE = Not established This Material Safety Data Sheet has been prepared in accordance with 29 CFR Part 1910.1200 and contains information believed to be accurate and complete at the date of preparation. However, no warranty is expressed or implied. Advice given under "Spill and Disposal Procedures" assumes compliance with federal, state, and local regulations regarding the disposal of hazardous waste. DATE PREPARED: July 2005 MSDS P.O. Box 329 - 802 Washington Avenue Chestertown, MD 21620 - USA TELEPHONE # FOR INFORMATION 410 778-3100 MATERIAL SAFETY DATA SHEET 24 HOUR EMERGENCY NUMBER (CHEM-TEL): USA, Canada, Puerto Rico 800-255-3924; Outside North American Continent 813-248-0585 (call Collect) 1. Product Identification Manufactured By: LaMotte Company 802 Washington Avenue Chestertown, MD 21620 Product Code: 2976 Product Description: 3-Way Instatest Pool & Spa Test Strips 2. Composition/Information On Ingredients Hazard CAS#/Name % N/A Dyes <1 N/A Buffers <1 N/A Polymers, binders <1 N/A Surfactant <1 N/A Organic acid <1 PEL NO HAZARDOUS INGREDIENTS in amounts >0.l% All other ingredients are proprietary Strips measure alkalinity, pH, and free chlorine in water. 1 TLV Product Code: 2976 Product Description: 3-Way Instatest Pool & Spa Test Strips 3. Hazards Overview Primary Route Of Entry: HMIS Hazard Scale: 4 = Extreme, 3 = High, 2 = Moderate, 1= Slight, 0 = Least Health: 0 Flammability: 0 Reactivity: 0 Carcinogenicity: None: Other Health Related Comments: Strips are non-toxic. 4. First Aid Measures Eye Contact: Flush with water. Skin Contact: Flush with water. Wash with soap and water. Ingestion: Consult a physician. Inhalation: N/A 5. Fire Fighting Measures Flash Point (Method Used): LEL: N/A N/A Extinguishing Media: Water spray Special Fire Fighting Procedures: N/A Unusual Fire & Explosion Hazard: N/A 6. Accidental Release Measures Sweep up and discard to trash. 2 UEL: N/A Product Code: 2976 Product Description: 3-Way Instatest Pool & Spa Test Strips 7. Handling & Storage Store in cool, dry, storage area. 8. Exposure Controls/Personal Protection Ventilation Normal Protection When Handling N/A Work/Hygenic Practices: N/A 9. Physical & Chemical Properties Appearance: Solubility In Water: Odor: pH: White Plastic Strip with colored paper pads Insoluble None N/A Vapor Density: Vapor Pressure: Boiling Point: Melting Point: 10. Stability & Reactivity Stable: Yes Conditions To Avoid: Heat, Light, Moisture, air. Incompatibility (Materials To Avoid): N/A Hazardous Decomposition Products: N/A 3 N/A N/A N/A N/A Product Code: 2976 Product Description: 3-Way Instatest Pool & Spa Test Strips 11. Toxicological Information non-toxic Target Organs: N/A 12. Ecological Information Information Not Yet Available 13. Disposal Considerations Discard to trash. Dispose according to federal, state and local regulations. 14.QRLabel53 Transportation Information Not Regulated For Transport 15. Regulatory Information Chemical Inventory Status Hazard Ingredient USA TSCA Europe EC --- Canada --DSL NDSL 4 Australia Japan Product Code: 2976 Product Description: 3-Way Instatest Pool & Spa Test Strips Federal, State, & International Regulations --- SARA 302 --Ingredient Ingredient product 2976 as a whole RQ --------- SARA 313 --------Listed TPQ Chemical Category --- SARA 311/312 --Hazard Categories Acute Chronic Fire Pressure Reactivity -------- Australia ------Hazchem Poison Code Schedule No None Allocated No No No No 16. Other Information Store in cool, dry place out of direct sunlight. Prepared By: IP, Regulatory Affairs Department Revised: 11/2/2005 5 RCRA 261.33 CERCLA TSCA 8(D) This MSDS Is WHMIS Compliant None Allocated MATERIAL SAFETY DATA SHEET Atlantic Chemical Equipment Co. 2190 DeFoor Hills Rd NW Atlanta, GA 30318 404-355-5522 PRODUCT NAME: DETERGENT TABLETS BLISTER PACK (DPT) EMERGENCY PHONE: 1-800-424-9300 May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200. Standard must be consulted for specific requirements. This product contains no substances subject to SARA TITLE III and 40 CRF. VII - PRECAUTIONS FOR SAFE HANDLING AND USE STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED: Wash off with soap and water. Do not get in eyes or on mucous membrane HMIS SYMBOLS HEALTH 1 FLAMMABILITY 0 REACTIVITY 0 WASTE DISPOSAL METHOD: Incinerate with adequate ventilation 1 - IDENTIFICATION VIII - SPECIAL PROTECTION INFORMATION PRODUCT NAME: (DPT) DETERGENT TABLETS BLISTER PACK PACKAGE TYPE: 12 Cards/8 tablets per card PREPARED DEPARTMENT OF HAZARDOUS COMMUNICATIONS DATE PREPARED: June 2003 RESPIRATORY: Use approved NIOSH respirator in dusty conditions EYE: Chemical goggles recommended II - HAZARDOUS INGREDIENTS PRINCIPLE HAZARDOUS COMPONENT(S) (CHEMICAL NAMES) N-Alkydimethyl Benzyl Ammonium Chloride CAS NO ACGIH TLV OSHA PEL % or RANGE SKIN: Wear impervious gloves PROTECTIVE GLOVES: Impervious rubber or neoprene 20 1733-96-6 OTHER: Do not eat, drink, or smoke in work area. Wash hands before eating VENTILATION REQUIREMENTS: None needed IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Do not remove tablets from pouch. III - PHYSICAL DATA BOILING POINT ( 0F) : N.A. VAPOR PRESSURE (mm Hg) : N.A. MELTING POINT: 0 VAPOR DENSITY (Air = 1) : N.A. EVAPORATION RATE (H20 = 1) : 0.0001 pH : APPEARANCE AND ODOR : White tablets, no odor SPECIFIC GRAVITY (H20= 1) : N.A. SPECIAL PRECAUTIONARY STATEMENTS: Do not get in eyes. Do not take internally. Keep this and all chemicals out of reach of children. NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of merchantability fitness or otherwise is made. SOLUBILITY IN WATER : 80% IV - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Flash Point NONE SARA Title III Reporting Requirements SPECIAL FIRE FIGHTING PROCEDURES: None UNUSUAL FIRE AND EXPLOSION HAZARDS: None V - REACTIVITY DATA CHEMICAL STABILITY UNSTABLE 302 (Extremely Hazardous Substances): Reporting not required. 304/CERCLA (Spills Notification): Not required. 311 Community Right-To-Know, RTK): Reporting not required. Acute health hazard, irritating, toxic. 312 (RTK Inventory Data): Reporting required for inventory above TPQ. 313 (Emissions and Releases): Reporting not required. DOT NOT HAZARDOUS CONDITIONS TO AVOID: X STABLE INCOMPATIBILITY (Materials to avoid): None HAZARDOUS DECOMPOSITION PRODUCTS: None HAZARDOUS POLYMERIZATION MAY OCCUR CONDITIONS TO AVOID: WILL NOT OCCUR X VI - HEALTH HAZARD AREA ROUTE(S) OF ENTRY: EYES Yes SKIN Yes INGESTION Yes INHALATION Yes References EFFECTS OF OVER EXPOSURE: INHALATION: If crushed or powdered, dusts are toxic TOXIC SUBSTANCE CONTROL CT LIST (TSCA) - INGREDIENTS LISTED SKIN CONTACT/ABSORPTION: Irritating to skin PERMISSIBLE EXPOSURE REFERENCES: Registry of Toxic Effects of Chemical Substances. INGESTION: Toxic by ingestion Title 29 Code of Federal Regulations. National Toxicology Program (NTP) Report on Carcinogens. EYES: Irritating on eye contact CARCINOGENICITY: NTP? Not listed IARC MONOGRAPHS? Not listed OSHA REGULATED? Not listed Title 40 Code of Federal Regulations EMERGENCY AND FIRST AID PROCEDURES: EYES AND SKIN: EYES - Wash eyes with large quantities of water for 15 minutes. If irritation persists, call physician. soap and water International Agency for Research on Cancer (IARC) Monographs. SKIN - Wash skin with INHALATION: Remove to fresh air. If breathing remains difficult GET IMMEDIATE MEDICAL ATTENTION INGESTION: If swallowed, drink large quantities of milk, egg white, gelatin. Do not induce vomiting. Avoid alcohol. GET IMMEDIATE MEDICAL ATTENTION. REGULATORY STANDARDS: DOT Title 49 Code of Federal Regulations 172.101 SARA Title III Nuclear Regulatory Commission 1 Pumice Scouring Stick Item Number:100714 U.S. Department Of Labor Occupational Safety And Health Administration MATERIAL SAFETY DATA SHEET Required Under USDL Safety And Health Regulations (29 CFP 1910.1200 "Hazards Communication Standard") Section I Manufactured For: Gabriel First Corp. Emergency Telephone: 1-800-424-9300 Address: 233 W Commercial Street East Rochester, NY 14445 Chemical Name & Synonyms: Cleaning, Compound, Liquid Trade Name & Synonyms: Pumice Scouring Stick Prepared On: 6/30/2005 Section I - Hazardous Ingredients/Identity Information Section II - Product & Component Data Component(s)/ Chemical Names TLV PEL Pumice (Volcanic Glass) There is No Free Crystalline Silica Present CAS Registry No % Section III - Physical Data Boiling Point: N/A Specific Gravity (H 2O=1): N/A Melting Point: 2390° F Vapor Pressure: N/A Percent, Volatile By Volume (%): N/A Vapor Density (Air=1): N/A Evaporation Rate: N/A Solubility In Water: Not Soluble Appearance And Odor: Odorless Solid Section IV - Fire And Explosion Hazard Data Special Fire Fighting Procedures: None. Unusual Fire and Explosion Hazards: None Flash Point/Method Used: N/A Flammable Limits: N/A LEL: N/A UEL: N/A Extinguishing Media: N/A Section V - Health Hazard Data Route(s) of Entry: Inhalation? Yes Skin? No Ingestion: Yes Health Hazards (Acute and Chronic): Dry sawing or grinding may result in the release of dust particles which, acute, may cause irritation of eyes, nose or throat and chronic, may result in lung disease (Silicosis) if exposed for prolonged time. Carcinogenicity: NTP? IARC Monographs? OSHA Regulated? No No No Signs and Symptoms of Exposure: Irritation of eyes, nose and throat or shortness of breath. Medical Conditions Generally Aggravated by Exposure: Pre -existing lung disease such as Emphysema or Asthma. Emergency First Aid Procedures: Irrigate eyes generously with clean water for 15 minutes. If irritation persists call a physician. Section VI - Reactivity Data Stability Conditions To Avoid Stable None Materials To Avoid: None Hazardous Decomposition Products: None Hazardous Polymerization Conditions To Avoid Will Not Occur None Section VII - Spill Or Leak Procedures Steps To Be Taken In Case Material Is Released Or Spilled: Sweep up and properly dispose. Waste Disposal Method: Dispose as common waste. Precautions To Be Taken in Handling and Storing: None Other Precautions: Wear NIOSH approved respirator and tight fitting goggles. When dry sawing or grinding, or saw and grind when wet. Section VIII - Special Protection Information Control Measures (When Sawing or Grinding) Respiratory Protection (Type): NIOSH Approved Particulate Respirator Ventilation: Mechanical (General) in Confined Area Protective Gloves: When Required Eye Protection: Tight Fitting Goggles Other Protective Equipment: None Work/Hygienic Practices: N/A Section IX - Special Precautions Precautions To Be Taken In Handling And Storing: None This information is given in good faith, but no warranty expressed or implied is made. Our company believes that it is accurate to the best of its knowledge and relates only to the specific material designated herein. For RICCA, SpectroPure, Red Bird, and Solutions Plus Brands Emergency Contact(24 hr) -- CHEMTREC® Domestic: 800-424-9300 International: 703-527-3887 BUFFER, REFERENCE STANDARD, pH 7.00; BUFFER, PRECISION REFERENCE STANDARD pH 7.000 (Color Coded Yellow) MSDS Material Safety Data Sheet Section 1: Chemical Product and Company Identification Catalog Number: 1551, 1552, B-285, B017740, R1551300, S1551, SB017740 Product Identity: BUFFER, REFERENCE STANDARD, pH 7.00; BUFFER, PRECISION REFERENCE STANDARD pH 7.000 (Color Coded Yellow) Emergency Contact(24 hr) -- CHEMTREC® Manufacturer's Name: RICCA CHEMICAL COMPANY LLC Domestic: 800-424-9300 International: 703-527-3887 CAGE Code: 0V553 Address: 448 West Fork Dr Arlington, TX 76012 Telephone Number For Information: 817-461-5601 Date Prepared: Revision: 7 6/16/98 Last Revised: 01/13/2006 Date Printed: 03/07/2006 9:31:07 pm Section 2. Composition/Information on Ingredients Component Sodium Phosphate, Dibasic CAS Registry # 7558-79-4 Concentration ACGIH TLV <1 Not Available Not Available Water, Deionized 7732-18-5 Balance Not Available <1 Not Available < 0.1 Not Available < 0.1 Not Available Not Available Potassium Phosphate, Monobasic 7778-77-0 Not Available Inert Dye proprietary Not Available Preservative (No Mercury compounds or Formaldehyde) pROPRIETARY Not Available OSHA PEL Not Available Not Available Not Available Not Available Not Available Not Available Not Available Not Available Not Available Not Available Section 3: Hazard Identification Emergency Overview: Non-flammable, non-toxic, non-corrosive. Does not present any significant health hazards. May cause irritation. Wash areas of contact with water Target Organs: eyes, skin Eye Contact: May cause slight irritation. Inhalation: May cause allergic respiratory reaction to those allergic to phosphates. Page 1 of 4 For RICCA, SpectroPure, Red Bird, and Solutions Plus Brands Emergency Contact(24 hr) -- CHEMTREC® Domestic: 800-424-9300 International: 703-527-3887 MSDS BUFFER, REFERENCE STANDARD, pH 7.00; BUFFER, PRECISION REFERENCE STANDARD pH 7.000 (Color Coded Yellow) Skin Contact: May cause slight irritation to those allergic to phosphates. Ingestion: Large doses may cause stomach upset. Chronic Effects/Carcinogenicity: None IARC - No. NTP - No. OSHA - No. Reproductive Information: Not Applicable. Teratology (Birth Defect) Information: Not Applicable. Section 4: First Aid Measures - In all cases, seek qualified evaluation. Eye Contact: Irrigate immediately with large quantity of water for at least 15 minutes. Call a physician if irritation develops. Inhalation: Remove to fresh air. Give artificial respiration if necessary. If breathing is difficult, give oxygen. Skin Contact: Flush with plenty of water for at least 15 minutes. Call a physician if irritation develops. Ingestion: Dilute with water or milk. Call a physician if necessary. Section 5: Fire Fighting Measures Flash Point: Not Available. Method Used: Not Available. LFL: Not Available. UFL: Not Available. Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Fire & Explosion Hazards: Not considered to be a fire or explosion hazard. Fire Fighting Instructions: Use normal procedures/instructions. Fire Fighting Equipment: Use protective clothing and breathing equipment appropriate for the surrounding fire. Section 6: Accidental Release Measures Absorb with suitable material (vermiculite, clay, etc.) and dispose of in accordance with local regulations. Check with local agencies for the proper disposal of phosphate containing solutions. Section 7. Handling and Storage As with all chemicals, wash hands thoroughly after handling. Avoid contact with eyes and skin. Protect from freezing and physical damage. Safety Storage Code: General Section 8: Exposure Control/Personal Protection Engineering Controls: No specific controls are needed. Normal room ventilation is adequate. Respiratory Protection: Normal room ventilation is adequate. Skin Protection: Chemical resistant gloves. Eye Protection: Safety glasses or goggles. Section 9: Physical and Chemical Properties Appearance: Clear, Yellow Liquid Odor: Odorless Solubility in Water: Inifinite Specific Gravity: Approximately 1 pH: 7 Boiling Point(°C): Approximately 100 Melting Point(°C): Approximately 0 Vapor Pressure: Not Applicable. Section 10: Stability and Reactivity Chemical Stability: Stable under normal conditions of use and storage. Incompatibility: None identified. Page 2 of 4 For RICCA, SpectroPure, Red Bird, and Solutions Plus Brands Emergency Contact(24 hr) -- CHEMTREC® Domestic: 800-424-9300 International: 703-527-3887 MSDS BUFFER, REFERENCE STANDARD, pH 7.00; BUFFER, PRECISION REFERENCE STANDARD pH 7.000 (Color Coded Yellow) Hazardous Decomposition Products: Phosphorus oxides may form when heated to decomposition Hazardous Polymerization: Will not occur. Section 11. Toxicological Information LD50, Oral, Rat: (Sodium Phosphate Dibasic) 17 gm/kg; LD50, Dermal, Rabbit: (Potassium Phosphate Monobasic) >4640 mg/kg; details of toxic effects not reported other than lethal dose value. Section 12. Ecological Information Ecotoxicological Information: No information found Chemical Fate Information: No information found Section 13. Disposal Considerations Dilute with water, then flush to sewer if local regulations allow for the flushing of phosphate containing solutions. If not allowed, save for recovery or recycling in an approved waste disposal facility. Always dispose of in accordance with local, state and federal regulations. Section 14. Transport Information Part Numbers: This product is not regulated. Section 15. Regulatory Information (Not meant to be all inclusive - selected regulation represented) OSHA Status:The above items either do not contain any specifically hazardous material or the potentially hazardous material is present in such low concentration that the items do not present any immediate threat to health and safety. These items do not meet the OSHA Hazard Communication Standard (29 CFR 1910.1200) definition of a hazardous material. TSCA Status:All components of this solution are listed on the TSCA Inventory or are mixtures (hydrates) of items listed on the TSCA Inventory. Sara Title III: Section 302 Extremely Hazardous Substances:Not Applicable. Section 311/312 Hazardous Catagories:No Section 313 Toxic Chemicals:Not Applicable. California: None Reported. Pennsylvania: Sodium Phosphate, Dibasic is listed as an Environmental Hazard on the state's Hazardous Substances List. RCRA Status: Not Applicable. CERCLA Reportable Quantity: Sodium Phosphate, Dibasic - 5,000 pounds. WHMIS: Not Applicable. Page 3 of 4 For RICCA, SpectroPure, Red Bird, and Solutions Plus Brands Emergency Contact(24 hr) -- CHEMTREC® Domestic: 800-424-9300 International: 703-527-3887 MSDS BUFFER, REFERENCE STANDARD, pH 7.00; BUFFER, PRECISION REFERENCE STANDARD pH 7.000 (Color Coded Yellow) Section 16. Other Information NFPA Ratings: Health: 1 Flammability: 0 Reactivity: 0 Special Notice Key:None Flammability: 0 Reactivity: 0 Protective Equipment:B (Protective Eyewear, Gloves) HMIS Ratings: Health: 1 Rev 1, 10-19-98: (Section 16) Removed periods from NFPA and HMIS, Added® to HMIS; Rev 2, 3-8-2000: Reformatted from WordPerfect® to Microsoft Word®, (Section 1) Revised emergency telephone number to CHEMTREC® 800-424-9300, (Section 3) Added “May cause…water.” in emergency overview, (Section 7) added storage code, (Section 10) added decomposition products, (Section 11) added toxicological data, (Section 15) added Pennsylvania listing. Rev 3, 8-25-2000: (Section 2) corrected concentration of preservative from 1 - 2 to < 0.1%. Rev 4, 10-09-2001: Reformatted to electronic data format. Rev 5, 04-25-2003: (Section 1) added Solutions Plus catalog number B017740. Rev 6, 04-01-2004: (Section 1) added catalog number S1551. Rev 7, 01-13-2006: (Section 1) added catalog number R1551300. When handled properly by qualified personnel, the product described herein does not present a significant health or safety hazard. Alteration of its characteristics by concentration, evaporation, addition of other substances, or other means may present hazards not specifically addressed herein and which must be evaluated by the user. The information furnished herein is believed to be accurate and represents the best data currently available to us. No warranty, expressed or implied, is made and RICCA CHEMICAL COMPANY assumes no legal responsibility or liability whatsoever resulting from its use. Page 4 of 4 00006472 MATERIAL SAFETY DATA SHEET Page 1 OSBORN INTERNATIONAL 5401 HAMILTON AVE. CLEVELAND; 44114 USA PRODUCT: 1515-01-002 76210 DRY GRAPHITE LUBRICANT 290G(10.25OZ) Section 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MANUFACTURER ................................................. PRODUCT NAME................................................... CHEMICAL FAMILY................................................ MOLECULAR WEIGHT........................................... CHEMICAL FORMULA........................................... TRADE NAMES & SYNONYMS.............................. PRODUCT USES.................................................... FORMULA/LAB BOOK #......................................... MANUFACTURED FOR: OSBORN INTERNATIONAL 5401 HAMILTON AVE. CLEVELAND USA 44114 216-361-1900 1515-01-002 76210 DRY GRAPHITE LUBRICANT 290G(10.25OZ) GRAPHITE. NOT APPLICABLE. MIXTURE. 1515-01-002 76210 DRY GRAPHITE LUBRICANT 290G(10.25OZ) COATING. F 01-040. Section 02: COMPOSITION/INFORMATION INGREDIENTS Hazardous Ingredients % Exposure Limit C.A.S.# LD/50, Route,Species ACETONE 30-60 750 ppm 67-64-1 >9750 mg/kg ORAL - RAT HEXANE 10-30 50 ppm 110-54-3 17,300 mg/kg ORAL-RAT ISOPROPANOL 5-10 400 ppm 67-63-0 >4720 mg/kg ORAL - RAT GRAPHITE POWDER ISOBUTANE 1-5 5 -10 2.5mg/m3 1000 ppm 7782-42-5 75-28-5 NOT AVAILABLE NOT APPLICABLE PROPANE 10-30 1000 ppm 74-98-6 NOT APPLICABLE LC/50 Route,Species >16,000 ppm (4 hr) INHAL RAT 48,000 mg/kg INHAL-MOUSE 12000 ppm (8hr) INHAL RAT NOT AVAILABLE 142,500 ppm (4h) INHAL RAT NOT AVAILABLE Section 03: HAZARDS IDENTIFICATION ROUTE OF ENTRY: INGESTION............................................................. MAY CAUSE HEADACHE, NAUSEA, VOMITING AND WEAKNESS. INHALATION........................................................... INHALATION OF SOLVENTS MAY CAUSE IRRITATION. PROPELLANT IS A SIMPLE ASPHYXIANT. EYE CONTACT....................................................... MAY CAUSE IRRITATION. SKIN ABSORPTION................................................ NO DATA AVAILABLE FOR THIS PRODUCT MIXTURE. SKIN CONTACT...................................................... MAY CAUSE IRRITATION. EFFECTS OF ACUTE EXPOSURE........................ DIZZINESS, NAUSEA. IRRITATION TO SKIN & EYES. EFFECTS OF CHRONIC EXPOSURE................... SOLVENTS MAY CAUSE DEFATTING DERMATITIS EXPOSURE LIMIT OF MATERIAL......................... SEE SECTION 2. . Section 04: FIRST AID MEASURES EMERGENCY FIRST AID PROCEDURE .............. IN CASE OF EYE CONTACT, FLUSH IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES AND GET MEDICAL ATTENTION. FOR SKIN, WASH THOROUGHLY WITH SOAP AND WATER. IF AFFECTED BY INHALATION OF VAPOUR OR SPRAY MIST, REMOVE TO FRESH AIR. IF SWALLOWED; DO NOT INDUCE VOMITING, GET MEDICAL ATTENTION. Section 05: FIRE FIGHTING MEASURES AUTO IGNITION TEMPERATURE (°C).................. 225-465. SPECIAL PROCEDURES....................................... WATER FROM FOGGING NOZZLES MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT BUILD-UP IF EXPOSED TO EXTREME TEMPERATURES. FULL PROTECTIVE EQUIPMENT INCLUDING SELF CONTAINED BREATHING APPARTATUS SHOULD BE WORN IN A FIRE INVOLVING THIS MATERIAL. FLAMMABILITY....................................................... EXTREMELY FLAMMABLE. IF YES, UNDER WHICH CONDITIONS?................ EXCESSIVE HEAT, SPARKS AND OPEN FLAME. EXTINGUISHING MEDIA........................................ WATER, CARBON DIOXIDE, DRY CHEMICAL, FOAM. UPPER FLAMMABLE LIMIT................................... 12.8. (% BY VOLUME) LOWER FLAMMABLE LIMIT.................................. 1.2. (% BY VOLUME) FLASH POINT (C), TAG CLOSED CUP................. LOWEST KNOWN VALUE IS ACETONE @ -18C. EXPLOSION DATA SENSITIVITY TO STATIC DISCHARGE........... NOT APPLICABLE. SENSITIVITY TO IMPACT................................. NOT APPLICABLE. 00006472 MATERIAL SAFETY DATA SHEET Page 2 PRODUCT: 1515-01-002 76210 DRY GRAPHITE LUBRICANT 290G(10.25OZ) Section 05: FIRE FIGHTING MEASURES HAZARDOUS COMBUSTION PRODUCTS............................................................ HYDROCARBON FUMES AND SMOKE. CARBON MONOXIDE WHERE COMBUSTION IS INCOMPLETE. AEROSOL FLAME PROJECTION CLASSIFIED AS:..................................................... >15cm BUT <100cm. FLASHBACK........................................................... NONE. Section 06: ACCIDENTAL RELEASE MEASURES LEAK/SPILL............................................................. REMOVE ALL SOURCES OF IGNITION. USE AN INERT ABSORBENT MATERIAL, AND NON-SPARKING TOOLS. VENTILATE AREA. PREVENT FROM ENTERING A WATERCOURSE. Section 07: HANDLING AND STORAGE STORAGE NEEDS.................................................. ENGINEERING CONTROLS.................................. HANDLING PROCEDURES AND EQUIPMENT..... SYNERGISTIC MATERIALS................................... KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAMES. VENTILATION - LOCAL (MECHANICAL IF USED INDOORS ON A CONTINUOUS BASIS). STORE IN A COOL, WELL VENTILATED AREA NOT TO EXCEED 50 DEG C. NONE KNOWN. Section 08: EXPOSURE CONTROLS/PERSONAL PROTECTION GLOVES/ TYPE...................................................... RESPIRATORY/TYPE............................................ WEAR CHEMICAL RESISTANT GLOVES. IF USED INDOORS ON A CONTINUOUS BASIS, USE OF A CARTRIDGE TYPE RESPIRATOR (NIOSH/MSHATC 23C OR EQUIVALENT) IS RECOMMENDED. EYE/TYPE............................................................... SAFETY GLASSES. FOOTWEAR/TYPE................................................. NOT NORMALLY REQUIRED. OTHER/TYPE.......................................................... NOT REQUIRED. Section 09: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE.................................................. APPEARANCE........................................................ ODOR...................................................................... ODOR THRESHOLD............................................... VAPOUR PRESSURE(PSIG)-AEROSOL............... @ 20 C BOILING POINT (°C)(CONC).................................. EVAPORATION RATE............................................ n-BUTYL ACETATE = 1 VAPOUR DENSITY (AIR=1)................................... (BY WEIGHT) SOLUBILITY IN WATER g/L (20°C)........................ pH............................................................................ SPECIFIC GRAVITY (LIQUID)................................ COEFFICIENT OF WATER\OIL DIST..................... FREEZING POINT: (°C).......................................... AEROSOL PERCENT VOLATILE........................... (BY WEIGHT). SPECIFIC GRAVITY (AEROSOL).......................... AEROSOL. BLACK/GREY. KETONE. NOT AVAILABLE. 50-60. 57-69. GREATER THAN 1. GREATER THAN 1. NOT AVAILABLE. NOT APPLICABLE. 0.75-0.82. NOT AVAILABLE. NOT AVAILABLE. 97-98. 0.66-0.70. Section 10: STABILITY AND REACTIVITY HAZARDOUS PRODUCTS OF DECOMPOSITION.................................................. HYDROCARBON FUMES AND SMOKE. CARBON MONOXIDE WHERE COMBUSTION IS INCOMPLETE. CHEMICAL STABILITY: YES......................................................................... UNDER NORMAL CONDITIONS. NO, WHICH CONDITIONS?................................... NOT APPLICABLE. COMPATIBILITY WITH OTHER SUBSTANCES: NO, WHICH ONES?................................................ STRONG OXIDIZING AGENTS. REACTIVITY CONDITIONS?.................................. NOT APPLICABLE. HAZARDOUS POLYMERIZATION......................... WILL NOT OCCUR. Section 11: TOXICOLOGICAL INFORMATION REPRODUCTIVE EFFECTS................................... NO INFORMATION IS AVAILABLE AND NO ADVERSE REPRODUCTIVE EFFECTS ARE ANTICIPATED. IRRITANCY OF MATERIAL.................................... SKIN/EYE IRRITANT. N-HEXANE MAY DAMAGE PERIPHERAL NERVE TISSUE. SENSITIZING CAPABILITY OF MATERIAL........... UNKNOWN. CARCINOGENICITY OF MATERIAL...................... THE INGREDIENTS OF THIS PRODUCT ARE NOT LISTED AS CARCINOGENS BY NTP, (NATIONAL TOXICOLOGY PROGRAM), NOT REGULATED AS CARCINOGENS BY OSHA, (OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION), AND HAVE NOT BEEN EVALUATED BY IARC,(INTERNATIONAL AGENCY FOR RESEARCH ON CANCER), NOR BY ACGIH (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS). TERATOGENICITY................................................. NO INFORMATION IS AVAILABLE AND NO ADVERSE TERATOGENIC EFFECTS ARE ANTICIPATED. MUTAGENICITY..................................................... NO INFORMATION IS AVAILABLE AND NO ADVERSE MUTAGENIC EFFECTS ARE ANTICIPATED. 00006472 MATERIAL SAFETY DATA SHEET Page 3 PRODUCT: 1515-01-002 76210 DRY GRAPHITE LUBRICANT 290G(10.25OZ) Section 12: ECOLOGICAL CONSIDERATIONS ENVIRONMENTAL.................................................. NOT AVAILABLE. Section 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL................................................. DO NOT PUNCTURE OR INCINERATE CONTAINERS, EVEN WHEN EMPTY. DISPOSE OF IN ACCORDANCE WITH LOCAL, PROVINCIAL AND FEDERAL REGULATIONS. Section 14: TRANSPORTATION INFORMATION T.D.G. CLASSIFICATION....................................... D.O.T. CLASSIFICATION....................................... CONSUMER COMMODITY (AEROSOLS, UN1950, CLASS 2.1) . CONSUMER COMMODITY, ORM-D. Section 15: REGULATORY INFORMATION CANADIAN REGULATIONS: -------------------------------------WHMIS CLASSIFICATION...................................... A,B5,D2B. CNFC SECTION 3.3.5............................................. LEVEL 3. CEPA (Canadian Enviromental Protection Act) ALL SUBSTANCES IN THIS PRODUCT ARE LISTED ON THE CANADIAN DOMESTIC SUBSTANCES LIST (DSL) OR ARE NOT REQUIRED TO BE LISTED. U.S. REGULATIONS: -----------------------------HMIS RATING HEALTH.......................................... 2 MODERATE HAZARD. HMIS RATING FLAMMABILITY.............................. 4 SEVERE HAZARD. HMIS RATING REACTIVITY................................... 0 MINIMAL HAZARD. HMIS RATING PERSONAL PROTECTION............ B. NFPA CODE 30B.................................................... LEVEL 3. SARA 313 INFORMATION:..................................... THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372: . CAS #: CHEMICAL NAME: . *110-54-3 N-HEXANE. CALIFORNIA PROPOSITION 65:........................... THE FOLLOWING STATEMENT IS MADE IN ORDER TO COMPLY WITH THE CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986: . WARNING: THIS PRODUCT DOES NOT INTENTIONALLY CONTAIN ANY CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. . CAS #: CHEMICAL NAME: . N/A. TSCA (Toxic Substances Control Act).................... ALL COMPONENT OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY. ANY IMPURITIES PRESENT IN THIS PRODUCT ARE EXEMPT FROM LISTING. VOC (w/w%)............................................................ 58-59. Section 16: OTHER INFORMATION NOTICE FROM KG PACKAGING INC ................... THE INFORMATION ON THIS MATERIAL SAFETY DATA SHEET IS PROVIDED BY K-G PACKAGING INC. FREE OF CHARGE. WHILE BELIEVED TO BE RELIABLE, IT IS INTENDED FOR USE BY SKILLED PERSONS AT THEIR OWN RISK. K-G PACKAGING INC. ASSUMES NO RESPONSIBILITY FOR EVENTS RESULTING OR DAMAGES INCURRED FROM ITS USE. THE INFORMATION ON THIS MATERIAL SAFETY DATA SHEET RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED HEREIN AND DOES NOT RELATE TO USE IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANY PROCESS. PREPARED BY....................................................... TECHNICAL SERVICES PREPARATION DATE ........................................... Jun11/07 MATERIAL SAFETY DATA PRODUCT NAME: 4” & 10” Glue Sticks PRODUCT CODE: 10-701 & 10-801 HMIS CODES: H F R P 000B SECTION 1 - MANUFACTURER IDENTIFICATION MANUFACTURER'S NAME: ROBERTS CONSOLIDATED INDUSTRIES, INC. ADDRESS: 2501 Lakeview Drive, Mexico, MO 65265 EMERGENCY PHONE: (800)424-9300 (Chemtrec) DATE REVISED: 09/01/01 INFORMATION PHONE: (905) 791-4444 NAME OF PREPARER: Peter Sharko SECTION 11 - HAZARDOUS INGREDIENTS/SARA 111 INFORMATION No reportable quantities of hazardous ingredients are present per OSHA regulation: 29 CFR 1910-1200. No toxic chemical(s) subject to the reporting requirements of Section 313 of Title 111 and of 40 CFR 372 are present. SECTION 111 - PHYSICAL/CHEMICAL CHARACTERISTICS BOILING POINT: N/A VAPOR DENSITY: N/A COATING V.O.C.: N/A SOLUBILITY IN WATER: Insoluble APPEARANCE AND ODOR: Transparent Solid SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT: N/A FLAMMABLE LIMITS IN AIR BY VOLUME EXTINGUISHING MEDIA: Foam, CO2, Dry Chemical SPECIFIC FIREFIGHTING PROCEDURES: None UNUSUAL FIRE AND EXPLOSION HAZARDS: None SPECIFIC GRAVITY (H20=1): .9 EVAPORATION RATE: Slower than ether pH: Neutral METHOD USED: N/A LOWER: N/A UPPER: N/A SECTION V - REACTIVITY DATA STABILITY: Stable INCOMPATIBILITY: (Materials to avoid): Strong oxidizers. HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Combustion products. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: Excessive Heat SECTION VI - HEALTH HAZARD DATA INHALATION HEALTH RISKS AND SYMPTOMS OF EXPOSURE: None SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE: Molten material will cause skin burns. SKIN ABSORPTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE: None INGESTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE: Not likely to occur. Should it occur potential G.I. Blockage. HEALTH HAZARDS (Acute and Chronic): ACUTE: None CHRONIC: None CARCINOGENICITY: NTP? No IARC MONOGRAPHS? No OSHA REGULATED? No This product contains no carcinogens as listed by NTP, IARC and OSHA MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: None known. EMERGENCY AND FIRST AID PROCEDURES: EYES: N/A SKIN: N/A INGESTION: N/A SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Contain for salvage or disposal. WASTE DISPOSAL METHOD: Discarded material may be incinerated. Dispose according to Federal, State and local regulations. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep package from excessive heat. Keep out of reach of children. OTHER PRECAUTIONS: None SECTION VIII - CONTROL MEASURES RESPIRATORY PROTECTION: None should be required. PROTECTIVE GLOVES: General purpose gloves to protect against burns. VENTILATION: None should be required. EYE PROTECTION: None OTHER PROTECTIVE CLOTHING OR EQUIPMENT: None WORK/HYGIENE PRACTICES: Standard hygiene and safe handling procedures are believed to be generally applicable. SECTION IX - DISCLAIMER DISCLAIMER: The information accumulated herein is believed to be accurate, but is not warranted to be whether originating with the company or not. Each user should review and determine for themselves, the applicability of the information in the specific context of the intended use. KEEP OUT OF REACH OF CHILDREN Manufactured by: ROBERTS CONSOLIDATED INDUSTRIES INC. American Lubricating Co 5OO SOUTH FRONT STREET * PO BOX 258 MEMPHIS, TN 38101 USA www.americanlubricating.com phone: 901 527 4707 fax: 901 525 7670 MATERIAL SAFETY DATA SHEET MANUFACTURER'S NAME: American Lubricating Company ADDRESS: PO Box 258, Memphis, TN 38101 PRODUCT NAME: No Smoke Two Stroke 2 Cycle Engine Oil /Fuel Stabilizer HAZARD MATERIAL ID SYSTEM: H-1 F-1 R-0 PP-B SECTION 1 - DESCRIPTION PRODUCT NAME: No Smoke Two Stroke Two Cycle Engine Oil w/Fuel Stabilizer DOT SHIPPING NAME: N/A DOT HAZARD CLASS: Non-Hazardous CAS REGISTRY NUMBER: 64742-54-7 or 64742-65-0 CHEMICAL NAME: Petroleum lubricating oil and fuel additive containing a polyamine condensation product based dispersant and other component judged not to affect the potential health or environmental impact of the product, and <1% proprietary fuel stabilizer. PREPARER: Chip Armstrong, October 2005 SECTION 2 - HAZARDOUS INGREDIENTS COMPONENTS: Blend of mineral oil, light distillate solvent, and proprietary additives. BOILING POINT, DEG F: N/A MELTING POINT, DEG F: N/A SPECIFIC GRAVITY: 0.88 APPEARANCE: Dyed blue SECTION 3 - PHYSICAL DATA VAPOR PRESSURE: negligible VAPOR DENSITY: above 1 SOLUBILITY IN WATER: negligible ODOR: mineral oil SECTION 4 - FIRE AND EXPLOSION DATA FLASH POINT, DEG F: 178 EXTINGUISHING MEDIUM: water fog, foam, dry chemical, carbon dioxide SPECIAL FIRE FIGHTING PROCEDURES: Use water spray to cool exposed containers Fire fighting personnel should use respiratory protection. UNUSUAL FIRE EXPLOSION HAZARDS: product of combustion includes fumes & CO2 SECTION 5 - REACTIVITY HAZARDS STABILITY: stable MATERIAL TO AVOID: strong oxidizers HAZARDOUS POLYMERIZATION: will not CONDITION TO AVOID: flame, extreme heat HAZARDOUS DECOMPOSITION PRODUCTS: carbon monoxide upon combustion, fumes, smoke SECTION 6 - HEALTH HAZARD INFORMATION ROUTE OF ENTRY: X INHALATION X SKIN X INGESTION ACUTE OVEREXPOSURE: may cause reversible eye and skin irritation; prolonged skin exposure may cause dermatitis; ingestion may cause cramps & diarrhea; breathing mists may cause dizziness CHRONIC OVEREXPOSURE: defined by IARC as Class I mineral oil CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN: NATIONAL TOXICOLOGY PROGRAM IARC MONOGRAPHS OSHA YES X NO YES X NO YES X NO THRESHOLD LIMIT VALUE: 5-mg/cubic meter as mist EMERGENCY AND FIRST AID: in all cases remove source of exposure 1. INHALATION: unlikely to occur except as mist 2. EYES: flush with water for at least 15 minutes or until irritation subsides 3. SKIN: wash well with soap and water; remove oil soaked clothing; wash clothes before reuse; if irritation develops, consult physician 4. INGESTION: DO NOT induce vomiting; consult physician; contains solvent SECTION 7 - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: normally not required with adequate ventilation; if exposure exceeds limits, use NIOSH/MSHA approved air respirator VENTILATION: if mists are present, provide adequate ventilation to control level below the Permissible Exposure Limit PROTECTIVE GLOVES: impermeable gloves EYE PROTECTION: goggles OTHER: none usually required SECTION 8 - SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES HANDLING & STORAGE PRECAUTIONS: Keep away from fire, flame & sparks OTHER PRECAUTIONS: never wear oil soaked clothing; discard oil soaked shoes; affix proper warning labels on containers according to 29 CFR 1010.1200 IN CASE OF SPILLS: no unusual hazard; use pump and/or oil absorbent; keep from entering waterways and sewers WASTE DISPOSAL METHODS: dispose according to current local, state and federal regulations; consider recycling; NOTE: material may become a hazardous waste through use NOTE: The above information is based on data of which we are aware and is believed to be correct. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. American Lubricating Company, Inc. assumes no responsibility for injury to vendee or third persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, we assume no responsibility for injury to vendee or third persons proximately caused by abnormal use of the material even if reasonable safety procedures are followed. Furthermore, vendee assumes the risk in his use of the material. J/B Industries Inc. Section 1: Product And Company Identification COMPANY: LOCATION: J/B INDUSTRIES INC. 601 N. Farnsworth Ave. Aurora, IL 60507 Emergency Telephone Number: 630/851-9444 PRODUCT NAME: Vacuum Pump Oil PRODUCT GRADES: PRODUCT CODE: DATE ISSUED: December 28, 1992 DATE REVISED: September 18, 2006 Sept. 1 , 2003 Section 2: Composition/ Information On Ingredients CAS NAME: Distillates, hydrotreated heavy paraffinic CAS NUMBER: 64742-54-7 AMOUNT: 100% weight This product is not approved for direct food use [CFR 178.3620 (a) & (b)] Section 3: Hazards Identification EMERGENCY OVERVIEW Clear colorless to pale yellow liquid. IMMEDIATE HEALTH EFFECTS EYE: Not expected to cause prolonged or significant eye irritation. SKIN: Contact with the skin is not expected to cause prolonged or significant irritation. Not expected to be harmful to internal organs if absorbed through the skin. Contact with the skin is not expected to cause an allergic skin response. INGESTION: Not expected to be harmful if swallowed. INHALATION: Not expected to be harmful if inhaled. Contains a petroleum-based mineral oil. May cause respiratory irritation or other pulmonary effects following prolonged or repeated inhalation of oil mist at airborne levels above the recomm ended mineral oil mist exposure limit. Symptoms of respiratory irritation may include coughing and difficulty breathing. Material Safety Data Sheet Section 4: First Aid Measures EYE: No specific first aid measures are required because this material is not expected to cause eye irritation. As a precaution, remove contact lenses, if worn, and flush eyes with water. SKIN: No specific first aid measures are required because this material is not expected to be harmful if it contacts the skin. As a precaution, remove clothing and shoes if contaminated. To remove the material from skin, use soap and water. Discard contaminated clothing and shoes or thoroughly clean before reuse. No specific first aid measures are required because this material is not expected to be harmful if swallowed. Do not induce vomiting. As a precaution, give the person a glass of water or milk to drink and get medical advice. Never give anything by mouth to an unconscious person. INHALATION: No specific first aid measures are required because this material is not expected to be harmful if inhaled. If exposed to excessive levels of material in the air, move the exposed person to fresh air. Get medical attention if coughing or respiratory discomfort occurs. Section 5: Fire Fighting Measures FIRE CLASSIFICATION; OSHA Classification (29 CFR 1910.1200): Not classified by OSHA as flammable or combustible. NFPA RATINGS: HEALTH FLAMMABILITY REACTIVITY 1 0 FLAMMABLE PROPERTIES: FLASH POINT: Cleveland Open Cup 378°F (190°C) (Min) AUTOIGNITION: No data available FLAMMABLE (EXPLOSIVE) LIMITS (% by volume in air): Lower N/A Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic compounds will be evolved when this material undergoes combustion. Section 6. Accidental Release Measures PROTECTIVE MEASURES: Eliminate all sources of ignition in vicinity of spilled material. SPILL MANAGEMENT: INGESTION: 0 material, do not enter any enclosed or confined fire space without proper protective equipment, including selfcontained breathing apparatus. Upper N/A EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. PROTECTION OF FIRE FIGHTERS: Fire Fighting Instructions: This material will burn although it is not easily ignited. For fires involving this Stop the source of the release if you can do it without risk. Contain release to prevent further contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing precautions in Exposure Controls/ Personal Protection. Use appropriate techniques such as applying noncombustible absorbent materials or pumping. Where feasible and appropriate, remove contaminated soil. Place contaminated materials in disposable containers and dispose of in a manner consistent with applicable regulations. REPORTING: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at (800) 424-8802 as appropriate or required. Section 7. Handling and Storage GENERAL HANDLING INFORMATION: Avoid contaminating soil or releasing this material into sewage and drainage systems and bodies of water. STATIC HAZARD: Electrostatic charge may accumulate and create a hazardous condition when handling this material. To minimize this hazard, bonding and grounding may be necessary but may not, by themselves, be sufficient. Review all operations which have the potential of generating an accumulation of electrostatic charge and/ or a flammable atmosphere (including tank and container filling, splash filling, tank cleaning, sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations) and use appropriate mitigating procedures. For more information, refer to OSHA 1 Standard 29 CFR 1910.106, 'Flammable and Combustible Liquids', National Fire Protection Association (NFPA 77, 'Recommended Practice on Static Electricity; and /or the American Petroleum Institute (API) Recommended Practice 2003, 'Protection Against Ignitions Arising Out of Static, Lightning and Stray Currents'. CONTAINER WARNING: Container is not designed to contain pressure. Do not use pressure to empty container or it may rupture with explosive force. Empty containers retain product residue (solid, liquid, and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode and cause injury or death. Empty containers should be completely drained, properly closed, and promptly returned to a drum reconditioner or disposed of properly. RESPIRATORY PROTECTION: No respiratory protection is normally required. If user operations generate an oil mist, determine if airborne concentrations are below the OSHA Permissible Exposure Limit (PEL) of 5 mg/m3 for mineral oil mist. If not, wear a NIOSH approved respirator that provides adequate protection from the measured concentrations of this material. For air-purifying respirators use a particulate cartridge. Use a positive pressure, air-supplying respirator if there is potential for uncontrolled release, exposure levels are not known, or other circumstances where air-purifying respirators may not provide adequate protection. Section 9: Physical And Chemical Properties APPEARANCE AND ODOR: Clear colorless to pale yellow liquid. PH: Not Available Section 8. Exposure Controls/ Personal Protection VAPOR PRESSURE: GENERAL CONSIDERATIONS: VAPOR DENSITY (Air =1): Consider the potential hazards of this material (see Section 3), applicable exposure limits, job activities, and other substances in the work place when designing engineering controls and selecting personal protective equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the personal protective equipment listed below is recommended. The user should read and understand all instructions and limitations supplied with the equipment since protection is usually provided for a limited time or under certain circumstances. ENGINEERING CONTROLS: Use in a well-ventilated area. PERSONAL PROTECTIVE EQUIPMENT: EYE/FACE PROTECTION: No special eye protection is normally required. Where splashing is possible, wear safety glasses with side shields as a good safety practice. SKIN PROTECTION: No special protective clothing is normally required. Where splashing is possible, select protective clothing depending on operations conducted, physical requirements and other substances. Suggested materials for protective gloves include: Nitrile Rubber, Silver Shield, Viton. <0.01 mmHg @ 100°F >1 BOILING POINT: >600°F (>315° C) SOLUBILITY: Soluble in hydrocarbons, insoluble in water FREEZING POINT NA MELTING POINT NA SPECIFIC GRAVITY: 0.85-0.87 @ 15.6 °C/15.6°C VOLATILE ORGANIC COMPOUNDS (VOC): 2.9% weight (Approximate) VISCOSITY: 18.7 cST - 105 cST @40°C Section 11. Toxicological Information IMMEDIATE HEALTH EFFECTS EYE IRRITATION: The mean 24-hour Draize eye irritation score in rabbits is 4.0/110. SKIN IRRITATION: For a 24-hour exposure, the Primary Irritation Score (PIS) in rabbits is: 0.2/8.0. SKIN SENSITIZATION: This material did not cause skin sensitization reactions in a Buehler guinea pig test. ACUTE DERMAL TOXICITY: The 24 hour(s) LD50 in the rabbit is >5g/kg. ACUTE ORAL TOXICITY: The LD50 in the rat is >5 g/kg. ACUTE INHALATION TOXICITY: The acute inhalation toxicity hazard is based on evaluation of data for similar materials or product components. GENETIC TOXICITY: This product gave negative results in the following mutagenicity assays: Microbial/Microsome Reverse Mutation Assay. ADDITIONAL TOXICOLOGY INFORMATION: This product contains petroleum base oils which may be refined by various processes including severe solvent extraction, severe hydrocracking, or severe hydrotreating. None of the oils requires a cancer warning under the OSHA Hazard Communication Standard (29 CFR 1910.1200). These oils have not been listed in the National Toxicology Program (NTP) Annual Report nor have they been classified by the International Agency for Research on Cancer (IARC) as; carcinogenic to humans (Group 1), probably carcinogenic to humans (Group 2A), or possibly carcinogenic to humans (Group 2B). Section 10. Stability And Reactivity Section 12. Ecological Information: CHEMICAL STABILITY: EXOTOXICITY This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. INCOMPATIBILITY WITH OTHER MATERIALS: May react with strong oxidizing agents, such as chlorates, nitrates, peroxides, etc. HAZARDOUS DECOMPOSITION PRODUCTS: None known (None expected) HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. Ten 96 hour(s) LC50 for rainbow trout (Oncorhynchus mykiss) is >1000 mg/l. ENVIRONMENTAL FATE READY BIODEGRADABILITY: This material is not expected to be readily biodegradable. Section 13. Disposal Considerations Oil collection services are available for used oil recycling or disposal. Place contaminated materials in containers and dispose of in a manner consistent 2 with applicable regulations. Contact your sales representative or local environmental or health authorities for approved disposal or recyling methods. Section 14. Transportation Information The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous Goods Regulations, for additional description requirements (e.g., technical name) and mode-specific or quantity-specific shipping requirements. DOT SHIPPING NAME: Not regulated as a hazardous material for transportation under 49 CFR DOT HAZARD CLASS: Not Applicable DOT IDENTIFICATION NUMBER: Not Applicable DOT PACKING GROUP: Not Applicable Section 15. Regulatory Information SARA 311/312 CATEGORIES: 1. 2. 3. 4. Immediate (Acute) Health Effects: Delayed (Chronic) Health Effects: Fire Hazard: Sudden Release of Pressure Hazard: 5. Reactivity Hazard: REGULATORY LISTS SEARCHED: 4_I1=IARC Group 1 4_I2A=IARC Group 2A 4_I28B=IARC Group 2B 05=NTP Carcinogen 06-OSHA Carcinogen 09-TSCA 12(b) 10=TSCA Section 4 11=TSCA Section 8(a) CAIR 12=TSCA Section 8(a) PAIR 13=TSCA Section 8(d) 15=SARA Section 313 16=CA Proposition 65 17=MA RTK 18=NJ RTK 19=DOT Marine Pollutant 20=PA RTK 21=TSCA Section 5(a) 25=CAA Section 112 HAPs 26=CWA Section 311 28=CWA Section 307 30=RCRA Waste P-List 31-RCRA Waste U-List 32=RCRA Appendix VIII No components of this material were found on the regulatory lists above. No No No No No CHEMICAL INVENTORIES: AUSTRALIA: All the components of this material are listed on the Australian Inventory of Chemical Substances (AICS). KOREA: All the components of this product are on the Existing Chemicals List (ECL) in Korea. PHILIPPINES: All the components of this product are listed on the Philippine Inventory of Chemicals and Chemical Substances (PICCS). CANADA: All the components of this material are on the Canadian Domestic Substances List (DSL). EUROPEAN UNION: All the components of this material are in compliance with the EU Seventh Amendment Directive 92/32/EEC. UNITED STATES: All of the components of this material are on the Toxic Substances Control Act (TSCA) Chemical Inventory. NEW JERSEY RTK CLASSIFICATION: Under the New Jersey Right-to-Know Act L. 1983 Chapter 315 N.J.S.A.34:5A-1 et. seq., the product is to be indentified as follows: PETROLEUM OIL WHMIS CLASSIFICATION: This product is not considered a controlled product according to the criteria of the Canadian Controlled Products Regulations. Section 16. Other Information NFPA RATINGS: Health: Flammability: 0 1 Reactivity: 0 HMIS RATINGS: Health: Flammability: Reactivity 1 1 0 (0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:-Personal Protection Equipment Index recommendation, *Chronic Effect Indicator). These values are obtained using the guidelines or published evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint and Coating Association (for HMIS ratings). Prepared according to the OSHA Hazard Communication Standard (29 CFR 1910.1200) and the ANSI MSDS Standard (Z400.1). The above information is based on the data of which we are aware and is believed to be correct as of the date hereof. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may suggest modifications of the information, we do not assume any responsibility for the results of it use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose. 3 Material Safety Data Sheet 1 - Chemical Product and Company Identification Manufacturer: WD-40 Company Chemical Name: Organic Mixture Address: 1061 Cudahy Place (92110) P.O. Box 80607 San Diego, California, USA 92138 –0607 Telephone: 1-800-448-9340 Emergency only: 1-888-324-7596 (PROZAR) Information: 1-888-324-7596 Trade Name: WD-40 Aerosol Product Use: Cleaner, Lubricant, Penetrant MSDS Date Of Preparation: 5/16/07 2 – Hazards Identification Emergency Overview: DANGER! Harmful of fatal if swallowed. Flammable aerosol. Contents under pressure. Avoid eye contact. Use with adequate ventilation. Keep away from heat, sparks and all other sources of ignition. Symptoms of Overexposure: Inhalation: High concentrations may cause nasal and respiratory irritation and central nervous system effects such as headache, dizziness and nausea. Intentional abuse may be harmful or fatal. Skin Contact: Prolonged and/or repeated contact may produce mild irritation and defatting with possible dermatitis. Eye Contact: Contact may be mildly irritating to eyes. May cause redness and tearing. Ingestion: This product has low oral toxicity. Swallowing may cause gastrointestinal irritation, nausea, vomiting and diarrhea. The liquid contents are an aspiration hazard. If swallowed, can enter the lungs and may cause chemical pneumonitis. Chronic Effects: None expected. Medical Conditions Aggravated by Exposure: Preexisting eye, skin and respiratory conditions may be aggravated by exposure. Suspected Cancer Agent: Yes No X 3 - Composition/Information on Ingredients Ingredient Aliphatic Hydrocarbon Petroleum Base Oil LVP Aliphatic Hydrocarbon Carbon Dioxide Non-Hazardous Ingredients CAS # 64742-47-8 64742-48-9 64742-88-7 64742-65-0 64742-47-8 124-38-9 Mixture Weight Percent 45-50 15-25 12-18 2-3 <10 4 – First Aid Measures Ingestion (Swallowed): Aspiration Hazard. DO NOT induce vomiting. Call physician, poison control center or the WD-40 Safety Hotline at 1-888-324-7596 immediately. Eye Contact: Flush thoroughly with water. Get medical attention if irritation persists. Skin Contact: Wash with soap and water. If irritation develops and persists, get medical attention. Page 1 of 4 Inhalation (Breathing): If irritation is experienced, move to fresh air. Get medical attention if irritation or other symptoms develop and persist. 5 – Fire Fighting Measures Extinguishing Media: Use water fog, dry chemical, carbon dioxide or foam. Do not use water jet or flooding amounts of water. Burning product will float on the surface and spread fire. Special Fire Fighting Procedures: Firefighters should always wear positive pressure selfcontained breathing apparatus and full protective clothing. Cool fire-exposed containers with water. Use shielding to protect against bursting containers. Unusual Fire and Explosion Hazards: Contents under pressure. Aerosol containers may burst under fire conditions. Vapors are heavier than air and may travel along surfaces to remote ignition sources and flash back. 6 – Accidental Release Measures Wear appropriate protective clothing (see Section 8). Eliminate all sources of ignition and ventilate area. Leaking cans should be placed in a plastic bag or open pail until the pressure has dissipated. Contain and collect liquid with an inert absorbent and place in a container for disposal. Clean spill area thoroughly. Report spills to authorities as required. 7 – Handling and Storage Handling: Avoid contact with eyes. Avoid prolonged contact with skin. Avoid breathing vapors or aerosols. Use with adequate ventilation. Keep away from heat, sparks, hot surfaces and open flames. Wash thoroughly with soap and water after handling. Do not puncture or incinerate containers. Keep can away from electrical current or battery terminals. Electrical arcing can cause burn-through (puncture) which may result in flash fire, causing serious injury. Keep out of the reach of children. Storage: Do not store above 120°F or in direct sunlight. U.F.C (NFPA 30B) Level 3 Aerosol. 8 – Exposure Controls/Personal Protection Occupational Exposure Limits Chemical Aliphatic Hydrocarbon 100 ppm TWA (ACGIH) 1200 mg/m3 TWA (manufacturer recommended) Petroleum Base Oil 5 mg/m3 TWA (OSHA/ACGIH) LVP Aliphatic Hydrocarbon 1200 mg/m3 TWA (manufacturer recommended) Carbon Dioxide 5000 ppm TWA (OSHA/ACGIH), 30,000 ppm STEL (ACGIH) Non-Hazardous Ingredients None Established The Following Controls are Recommended for Normal Consumer Use of this Product Engineering Controls: Use in a well-ventilated area. Personal Protection: Eye Protection: Avoid eye contact. Safety glasses or goggles recommended. Skin Protection: Avoid prolonged skin contact. Chemical resistant gloves recommended for operations where skin contact is likely. Respiratory Protection: None needed for normal use with adequate ventilation. For Bulk Processing or Workplace Use the Following Controls are Recommended Engineering Controls: Use adequate general and local exhaust ventilation to maintain exposure levels below that occupational exposure limits. Personal Protection: Eye Protection: Safety goggles recommended where eye contact is possible. Skin Protection: Wear chemical resistant gloves. Respiratory Protection: None required if ventilation is adequate. If the occupational exposure limits are exceeded, wear a NIOSH approved respirator. Respirator selection and use should be Page 2 of 4 based on contaminant type, form and concentration. Follow OSHA 1910.134, ANSI Z88.2 and good Industrial Hygiene practice. Work/Hygiene Practices: Wash with soap and water after handling. 9 – Physical and Chemical Properties Boiling Point: 323°F (minimum) Solubility in Water: Insoluble Vapor Pressure: 110 PSI @ 70°F Percent Volatile: 74% Coefficient of Not Determined Water/Oil Distribution: Flash Point: 131°F (concentrate) Tag Closed Cup Specific Gravity: pH: Vapor Density: VOC: Appearance/Odor Flammable Limits: (Solvent Portion) 0.817 @ 72°F Not Applicable Greater than 1 412 grams/liter (49.5%) Light amber liquid/mild odor LEL: 1.1% UE:: 8.9% 10 – Stability and Reactivity Stability: Stable Hazardous Polymerization: Will not occur. Conditions to Avoid: Avoid heat, sparks, flames and other sources of ignition. Do not puncture or incinerate containers. Incompatibilities: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide and carbon dioxide. 11 – Toxicological Information The oral toxicity of this product is estimated to be greater than 5,000 mg/kg based on an assessment of the ingredients. This product is not classified as toxic by established criteria. It is an aspiration hazard. None of the components of this product is listed as a carcinogen or suspected carcinogen or is considered a reproductive hazard. 12 – Ecological Information No data is currently available. 13 - Disposal Considerations If this product becomes a waste, it would be expected to meet the criteria of a RCRA ignitable hazardous waste (D001). However, it is the responsibility of the generator to determine at the time of disposal the proper classification and method of disposal. Dispose in accordance with federal, state, and local regulations. 14 – Transportation Information_ DOT Surface Shipping Description: Consumer Commodity, ORM-D IMDG Shipping Description: Aerosols, 2, UN1950 15 – Regulatory Information U.S. Federal Regulations: CERCLA 103 Reportable Quantity: This product is not subject to CERCLA reporting requirements, however, oil spills are reportable to the National Response Center under the Clean Water Act and many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. SARA TITLE III: Hazard Category For Section 311/312: Acute Health, Fire Hazard, Sudden Release of Pressure Page 3 of 4 Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA Title III Section 313 Reporting requirements: None Section 302 Extremely Hazardous Substances (TPQ): None EPA Toxic Substances Control Act (TSCA) Status: All of the components of this product are listed on the TSCA inventory Canadian Environmental Protection Act: All of the ingredients are listed on the Canadian Domestic Substances List or exempt from notification Canadian WHMIS Classification: Class B-5 (Flammable Aerosol) This MSDS has been prepared according to the criteria of the Controlled Products Regulation (CPR) and the MSDS contains all of the information required by the CPR. 16 – Other Information: HMIS Hazard Rating: Health – 1 (slight hazard), Fire Hazard – 4 (severe hazard), Reactivity – 0 (minimal hazard) SIGNATURE: TITLE: REVISION DATE: Revision Date: May 2007 Page 4 of 4 Director of Global Quality Assurance SUPERSEDES: December 2004 3M MATERIAL SAFETY DATA SHEET 3M 16-102 QUICK DRYING CONTACT CLEANER 12/05/2005 Material Safety Data Sheet Copyright, 2005, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M 16-102 QUICK DRYING CONTACT CLEANER MANUFACTURER: 3M DIVISION: Electrical Markets Division ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue Date: 12/05/2005 Supercedes Date: 08/15/2002 Document Group: 08-0837-8 Product Use: Intended Use: Limitations on Use: Specific Use: ELECTRICAL CONTACT CLEANER, QUICK DRYING AEROSOL AVOID HEAT,FLAME, SPARKS AND LIVE ELECTRICAL POWER. QUICK DRYING CONTACT CLEANER SECTION 2: INGREDIENTS Ingredient C.A.S. No. HEPTANE ETHYL ALCOHOL ISOPROPYL ALCOHOL CYCLOHEXANE PROPANE 142-82-5 64-17-5 67-63-0 110-82-7 74-98-6 % by Wt 45 - 55 3 - 12 6 - 12 2 - 10 20 Minute quantities of the substances listed below may be emitted during Normal Use: Substance Hydrocarbons Condition Normal Use SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Compressed Gas Odor, Color, Grade: hydrocarbon odor, clear. _________________________________________________________________________________________________ Page 1 of 10 3M MATERIAL SAFETY DATA SHEET 3M 16-102 QUICK DRYING CONTACT CLEANER 12/05/2005 General Physical Form: Liquid Immediate health, physical, and environmental hazards: Flammable liquefied gas. Aerosol container contains flammable gas under pressure. Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol container contains flammable material under pressure. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. May be absorbed through skin and cause target organ effects. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Intentional concentration and inhalation may be harmful or fatal. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause: Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: NOTE: This product contains ethanol. In IARC published Monograph No. 44, entitled, "Alcohol Drinking", the carcinogenicity of ethanol was determined based on chronic exposure to ethanol through human consumption of alcoholic beverages. This is not an expected effect during the foreseeable use of this product. _________________________________________________________________________________________________ Page 2 of 10 3M MATERIAL SAFETY DATA SHEET 3M 16-102 QUICK DRYING CONTACT CLEANER Ingredient ETHYL ALCOHOL 3.3 C.A.S. No. 64-17-5 Class Description Group 1 12/05/2005 Regulation International Agency for Research on Cancer POTENTIAL ENVIRONMENTAL EFFECTS The KOWWIN program estimates Log Pow, the logarithm of the octanol-water partition coefficient, Pow. Log Pow is a physical property used to describe a substance's lipophilic or hydrophobic properties. Syracuse Research Corporation developed the KOWWIN program. The components labeled "Highly volatile" are expected to be rapidly removed from the aquatic and terrestrial compartments by vaporization. The high potential of this substance to move from water to the atmosphere means its toxicity is likely to disappear rapidly from aerobic environments. The components labeled "readily biodegradable" are expected to fully degrade in wastewater treatment and in most aerobic water or soil environments. Tests that strongly promote biodegradation show that the components labeled "inherently biodegradable" underwent >20% biodegradation but may not fully biodegrade. There is insufficient component information to calculate the ecotoxicity of this product. The components labeled "Log Kow <3" have measured or calculated log Kow values <3 indicating they are unlikely to bioconcentrate to high concentrations in aquatic organisms by partitioning into lipid tissues. The components labeled "Log Kow > or = 3" have measured or calculated log Kow values of > or = 3 indicating they have a potential to bioconcentrate to high concentrations in aquatic organisms by partitioning into lipid tissues. Labelled Components: Readily Biodegradable - Heptane (110-54-3), Ethyl Alcohol (64-17-5); Highly Volatile - Isopropyl Alcohol (67-63-0); Inherently biodegradable - Cyclohexane (110-82-7) Log Kow < 3: Isopropyl Alcohol (67-63-0); Ethyl Alcohol (64-17-5); Propane (74-98-6) Log Kow > 3: Heptane (110-54-3); Cyclohexane (110-82-7) SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature Flash Point Flammable Limits - LEL Flammable Limits - UEL OSHA Flammability Classification: No Data Available <=0 ºF 1.1 % volume 19.0 % volume Class IB Flammable Liquid 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). If water is used, fog nozzles are preferred. Water may be used to cool containers to prevent pressure build-up and possible autoignition or explosion when exposed to _________________________________________________________________________________________________ Page 3 of 10 3M MATERIAL SAFETY DATA SHEET 3M 16-102 QUICK DRYING CONTACT CLEANER 12/05/2005 extreme heat. 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Flammable liquefied gas. Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol container contains flammable material under pressure. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only nonsparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Cover spill area with a fire-extinguishing foam designed for use on solvents, such as alcohols and acetone, that can dissolve in water. An AR - AFFF type foam is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Place in a metal container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Contents may be under pressure, open carefully. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Ground containers securely when transferring contents. Wear low static or properly grounded shoes. Do not pierce or burn container, even after use. Do not spray near flames or sources of ignition. Aerosol container contains flammable gas under pressure. Avoid breathing of airborne material. Avoid static discharge. Avoid eye contact with vapors, mists, or spray. For industrial or professional use only. Avoid contact with oxidizing agents. 7.2 STORAGE Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Keep container tightly closed. Store away from oxidizing agents. _________________________________________________________________________________________________ Page 4 of 10 3M MATERIAL SAFETY DATA SHEET 3M 16-102 QUICK DRYING CONTACT CLEANER 12/05/2005 SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Do not use in a confined area or areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Indirect Vented Goggles. 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Fluoroelastomer (Viton). 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface pressure demand self-contained breathing apparatus. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit CYCLOHEXANE CYCLOHEXANE ETHYL ALCOHOL ETHYL ALCOHOL HEPTANE HEPTANE HEPTANE HEPTANE HEPTANE ISOPROPYL ALCOHOL ISOPROPYL ALCOHOL ISOPROPYL ALCOHOL ISOPROPYL ALCOHOL PROPANE PROPANE ACGIH OSHA ACGIH OSHA ACGIH ACGIH OSHA OSHA OSHA ACGIH ACGIH OSHA OSHA ACGIH OSHA TWA TWA TWA TWA TWA STEL TWA, Vacated TWA STEL, Vacated TWA STEL TWA STEL TWA TWA 100 ppm 300 ppm 1000 ppm 1000 ppm 400 ppm 500 ppm 400 ppm 500 ppm 500 ppm 200 ppm 400 ppm 400 ppm 500 ppm 1000 ppm 1000 ppm Additional Information Table Z-1 Table A4 Table Z-1 Table Z-1 Table A4 Table A4 Table Z-1A Table Z-1A Table Z-1 VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local regulatory agency. SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) _________________________________________________________________________________________________ Page 5 of 10 3M MATERIAL SAFETY DATA SHEET 3M 16-102 QUICK DRYING CONTACT CLEANER 12/05/2005 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Odor, Color, Grade: General Physical Form: Autoignition temperature Flash Point Flammable Limits - LEL Flammable Limits - UEL Boiling point Compressed Gas hydrocarbon odor, clear. Liquid No Data Available <=0 ºF 1.1 % volume 19.0 % volume 0 - 212 ºF Vapor Density >=1 [Ref Std: AIR=1] Vapor Pressure 33 - 760 mmHg Specific Gravity pH Melting point Solubility In Water 0.67 [Ref Std: WATER=1] No Data Available Not Applicable Approximately 20 % weight Evaporation rate Volatile Organic Compounds Percent volatile VOC Less H2O & Exempt Solvents Viscosity >=1 [Ref Std: ETHER=1] 100 % weight 100 % volume 670 g/l No Data Available SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: Sparks and/or flames; Heat; Strong oxidizing agents; ***Missing Data -Materials/Condition to Avoid*** Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Acetic Acid Aldehydes Carbon monoxide Carbon dioxide Oxidative Degradation Heat During Combustion During Combustion SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. _________________________________________________________________________________________________ Page 6 of 10 3M MATERIAL SAFETY DATA SHEET 3M 16-102 QUICK DRYING CONTACT CLEANER 12/05/2005 SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION See Section 3.3 CHEMICAL FATE INFORMATION See Section 3.3 SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. Facility must be capable of handling aerosol cans. Dispose of empty product containers in a sanitary landfill. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): 80-6109-2788-3 Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No CYCLOHEXANE 110-82-7 % by Wt 2 - 10 This material contains a chemical which requires export notification under TSCA Section 12[b]: Ingredient (Category if applicable) C.A.S. No Regulation Status _________________________________________________________________________________________________ Page 7 of 10 3M MATERIAL SAFETY DATA SHEET 3M 16-102 QUICK DRYING CONTACT CLEANER CYCLOHEXANE 110-82-7 HEPTANE 142-82-5 12/05/2005 Toxic Substances Control Act (TSCA) 4 Test Rule Chemicals Toxic Substances Control Act (TSCA) 4 Test Rule Chemicals Applicable Applicable STATE REGULATIONS Contact 3M for more information. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. WHMIS: Hazardous This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 2 Flammability: 4 Reactivity: 0 Special Hazards: None Aerosol Storage Code: 3 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 2 Flammability: 4 Reactivity: 0 Protection: A Hazardous Material Identification System (HMIS(r)) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS(r) ratings are to be used with a fully implemented HMIS(r) program. HMIS(r) is a registered mark of the National Paint and Coatings Association (NPCA). _________________________________________________________________________________________________ Page 8 of 10 3M MATERIAL SAFETY DATA SHEET 3M 16-102 QUICK DRYING CONTACT CLEANER Reason for Reissue: 12/05/2005 Update to new format. Revision Changes: Section 16: NFPA hazard classification heading was modified. Section 16: HMIS hazard classification heading was modified. Section 16: NFPA hazard classification for health was modified. Section 3: Carcinogenicity heading was modified. Section 3: Potential environmental effects heading was modified. Section 3: Other potential health effects heading was modified. Section 1: Division name was modified. Section 2: Normal use heading was modified. Copyright was modified. Section 8: Exposure guidelines data source legend was modified. Section 3: Immediate physical hazard(s) was modified. Section 3: Potential effects from eye contact was modified. Section 3: Potential effects from skin contact information was modified. Section 3: Potential effects from inhalation information was modified. Section 3: Potential effects from ingestion information was modified. Section 3: Potential environmental effects information was modified. Section 5: Fire fighting procedures information was modified. Section 5: Unusual fire and explosion hazard information was modified. Section 7: Handling information was modified. Section 7: Storage information was modified. Section 8: Engineering controls information was modified. Section 8: Eye/face protection phrase was modified. Section 8: Respiratory protection - recommended respirators information was modified. Section 15: 311/312 hazard categories heading was modified. Section 15: International regulations information was modified. Section 15: State regulations information was modified. Section 15: US federal regulations information was modified. Section 4: First aid for skin contact - decontamination - was modified. Section 4: First aid for skin contact - medical assistance - was modified. Section 4: First aid for ingestion (swallowing) - decontamination - was modified. Section 4: First aid for ingestion (swallowing) - medical assistance - was modified. Section 10: Hazardous polymerization heading was modified. Section 3: Carcinogenicity phrase was modified. Section 3: Immediate other hazard(s) was modified. Section 2: Ingredient table was modified. Section 15: TSCA section 12[b] text was modified. Section 3: Other health effects information was modified. Section 16: HMIS explanation was modified. Section 16: NFPA explanation was modified. Section 15: Inventories information was modified. Section 15: EPCRA 313 text was modified. Section 12: Ecotoxicological information heading was modified. Section 12: Chemical fate information heading was modified. Section 8: Exposure guidelines ingredient information was modified. Section 8: Exposure guidelines legend was modified. Section 9: Property description for optional properties was modified. Section 16: NFPA hazard classification for special hazards was modified. Section 16: NFPA hazard classification for aerosol storage was modified. Section 15: TSCA section 12[b] information was modified. Section 16: Reason for reissue comment was added. Section 15: WHMIS regulations heading was added. Section 15: WHMIS regulations information was added. _________________________________________________________________________________________________ Page 9 of 10 3M MATERIAL SAFETY DATA SHEET 3M 16-102 QUICK DRYING CONTACT CLEANER 12/05/2005 Section 4: First aid for skin contact - termination of exposure - was added. Section 4: First aid for skin contact - handling - was added. Section 2: Ingredient phrase was added. Section 3: Other health effects information (reproductive hazards) was added. Section 16: Reason for reissue heading was added. Section 12: Ecotoxicological information comment was added. Section 12: Chemical Fate information comment was added. Section 12: Ecotoxicological ecotox article information was deleted. Section 12: Ecotoxicological ecofate information was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at www.3M.com _________________________________________________________________________________________________ Page 10 of 10 Faultless® Rust Buster MSDS Number: 16800 Page 1 June 29, 2007 ________________________________________ MATERIAL SAFETY DATA SHEET 1. MANUFACTURER / PRODUCT IDENTIFICATION ______________________ Product Identification Product Name: Faultless® Rust Buster Product Number: 16800 ______________________ Company Identification Faultless Starch / Bon Ami Co. 1025 W 8th Street Kansas City, MO 64101 1-816-842-1230 (For product information) 1-800-424-9300 or 1-703-527-3887 (For emergencies) Reason For Issue...: Prepared By........: Approved By........: Title..............: Approval Date......: Supercedes Date....: MSDS Number........: RTN Number.........: Update emergency contact Bill Wood Bill Wood Technical Director June 29, 2007 October 14, 2004 16800 00016800 (Official Copy) ***************** EMERGENCY OVERVIEW ***************** * * * May Cause Chemical Burns. * * * ********************************************************** NFPA Rating: Health - 3, Flammability - 0, Reactivity - 0 2. HAZARDOUS INGREDIENTS _____________ Chemical Name INGREDIENTS ARE PROPRIETARY ________ Amount Confidential COMPOSITION COMMENT: The ingredients in this product are considered proprietary. emergency, contact Info Trac. 1-800-535-5053. EXPOSURE GUIDELINES: No Information Available. __________ CAS Number In case of Faultless® Rust Buster Page 2 MSDS Number: 16800 June 29, 2007 ____________________________________________________________________________________________________ 3. PHYSICAL / CHEMICAL CHARACTERISTICS FORM ..................: COLOR .................: ODOR ..................: BOILING POINT .........: VAPOR PRESSURE ........: SOLUBILITY IN WATER ...: SPECIFIC GRAVITY ......: BULK DENSITY ..........: PH ....................: 4. Liquid Clear acid >200 F <0.01 mm Hg Complete 1.038 (Water = 1) 8.659 lb/gl 4.5 (1% solution in water) FIRE AND EXPLOSION HAZARD DATA FLAMMABLE PROPERTIES COC Flash Point: N/A Autoignition Temperature: N/A FLAMMABLE LIMITS IN AIR LEL: N/A UEL: N/A FLAMMABLE PROPERTIES: Active ingredient is not flammable, but packaging material will burn. EXTINGUISHING MEDIA: BC/ABC extinguisher may be used in area where material is stored. SPECIAL FIRE FIGHTING PROCEDURES: As in any fire, wear self-contained breathing apparatus pressure-demand MSHA/NIOSH (approved or equivalent) and full protective gear. UNUSUAL FIRE AND EXPLOSION HAZARDS: In case of fire, highly corrosive gasses may be emitted. 5. REACTIVITY DATA STABILITY: Stable. INCOMPATIBILITY (MATERIALS TO AVOID): Glass, silicon compounds; alkali. HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Highly corrosive fumes. HAZARDOUS POLYMERIZATION: Will not occur. Faultless® Rust Buster Page 3 MSDS Number: 16800 June 29, 2007 ____________________________________________________________________________________________________ 6. HEALTH HAZARD DATA INHALATION RISKS AND SYMPTOMS OF EXPOSURE: May cause respiratory irritation, osteofluorosis, and respiratory impairment. SKIN / EYE CONTACT RISKS AND SYMPTOMS OF EXPOSURE: Corrosive to the skin and eyes. SKIN ABSORPTION RISKS AND SYMPTOMS OF EXPOSURE: Skin contact can cause a burning sensation and dermatitis. INGESTION RISKS AND SYMPTOMS OF EXPOSURE: May be fatal if swallowed. HEALTH HAZARDS (ACUTE AND CHRONIC): Material may cause severe chemical burns upon prolonged contact, poisoning if injested. EYE CONTACT FIRST AID: Remove any contact lenses and flush with water for at least 15 minutes. Get immediate medical attention. SKIN CONTACT FIRST AID: Immediately flush skin with plenty of water. Remove contaminated clothing. Thoroughly wash (or discard) clothing and shoes before reuse. INHALATION FIRST AID: Remove to fresh air. Seek immediate medical attention. INGESTION FIRST AID: Rinse mouth at once, then drink 1 or 2 glasses of water or milk. DO NOT induce vomiting. NEVER give anything by mouth to an unconscious person. Get medical attention. 7. PRECAUTIONS FOR SAFE HANDLING AND USE ACTIONS IF MATERIAL IS RELEASED OR SPILLED: Stop leak. Contain spill. Absorb with an inert material and place in a suitable container. Flush spill area with large amounts of water. WASTE DISPOSAL METHOD: Dispose of in accordance with federal, state and local regulations. MISCELLANEOUS: Dispose of wash water and spill byproducts according to State and Federal regulations. Faultless® Rust Buster Page 4 MSDS Number: 16800 June 29, 2007 ____________________________________________________________________________________________________ (section 7 continued) PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in a cool, dry area. Do not allow product to freeze. eyes, on skin or clothing. Do not take internally. 8. Do not get in CONTROL MEASURES RESPIRATORY PROTECTION: Not required. VENTILATION: Local exhaust to take vapor away from user. PROTECTIVE GLOVES: Rubber gloves recommended. EYE PROTECTION: Wear approved safety glasses/goggles. OTHER PROTECTIVE CLOTHING OR EQUIPMENT: To prevent skin contact, wear impervious clothing and boots. WORK / HYGIENIC PRACTICES: Observe reasonable care, cleanliness, and caution. 9. TRANSPORTATION INFORMATION PRODUCT LABEL..........: D.O.T. SHIPPING NAME...: D.O.T. HAZARD CLASS....: UN NUMBER..............: PACKAGE CLASS..........: 10. Faultless® Rust Buster Consumer Commodity ORM-D N/A III REGULATORY INFORMATION CHEMICAL INVENTORY INFORMATION: This material or all of its components are listed on the Inventory of Existing Chemical Substances under the Toxic Substance Control Act (TSCA). 11. DISCLAIMER Faultless® Rust Buster Page 5 MSDS Number: 16800 June 29, 2007 ____________________________________________________________________________________________________ ********************************************************************** The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable and suitable to their circumstances. ********************************************************************** END OF MSDS ********************************************************************** Wednesday, February 27, 2008 Page 1 of 5 MSDS - Material Safety Data Sheet Product Name: LIQUID WRENCH PENETRATING OIL MSDS No.: L106 I. Basic Information: Manufacturer: RADIATOR SPECIALTY COMPANY Contact: Robert Geer Address: 600 RADIATOR ROAD Information Telephone Number: 704-684-1811 City, ST Zip: INDIAN TRAIL, NC 28079 Emergency Contact: Rocky Mountain Poision Control Center Country: Emergency Telephone Number: 303-623-5716 Emergency Restrictions: Product Name: LIQUID WRENCH PENETRATING OIL MSDS No.: L106 Issue Date: 02/19/2008 Supersedes Date: 10/12/2006 II. Hazards Identification: EMERGENCY OVERVIEW Danger: Flammable. Harmful or fatal if swallowed. Eye and skin irritant. Contents under pressure. Level 3 Aerosol OSHA Regulatory Status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Potential Health Effects Route(s) of Entry: Absorption, Inhalation, and Ingestion. Health Hazards (Acute and Chronic): N/D Signs and Symptoms: Eye Contact: Irritant. Prolonged contact may cause conjunctivitis. Skin Contact: Irritant. Defatting of tissue, dermatitis may occur. Inhalation: Irritant to mucous membranes. Repeated exposure may cause narcosis, dizziness, respiratory or lung irritation. Ingestion: HARMFUL OR FATAL IF SWALLOWED. May cause burns to mouth, throat & stomach. Medical Conditions Generally Aggravated by Exposure: N/D Other Health Warnings: Vomiting and subsequent aspiration into the lungs may lead to chemical pneumonia and pulmonary edema which is a potentially fatal condition. Potential Environmental Effects Not Available III. Composition/Information on Ingredients: Chemical Name CAS No. % Range Carbon dioxide 124-38-9 1.0 - 5.0 Fragrance Proprietary 0.1 - 1.0 Kerosene 8008-20-6 40.0 - 70.0 Naphthenic Petroleum Distillate 64742-52-5 15.0 - 40.0 Solvent-Refined Heavy Paraffinic 64741-88-4 0.1 - 1.0 IV. First Aid Measures: Emergency and First Aid Procedures: Trade Secret Wednesday, February 27, 2008 Page 2 of 5 MSDS - Material Safety Data Sheet Product Name: LIQUID WRENCH PENETRATING OIL MSDS No.: L106 Eye Contact: Flush eyes with clean water for 15 minutes while lifting eyelids. Get prompt medical attention. Skin Contact: Wash with soap and water thoroughly. If adverse effects persist, get prompt medical attention. Launder contaminated clothing before reuse. Inhalation: Remove to fresh air. If breathing becomes difficult give oxygen and get prompt medical attention. If breathing stops, give artificial respiration and get prompt medical attention. Ingestion: DO NOT INDUCE VOMITING! Call Poison Control Center, physician, or hospital emergency room immediately. Aspiration of vomitus into the lungs can cause pneumonitis, which can be fatal. Note to Physicians: N/E V. Fire Fighting Measures: Suitable Extinguishing Media: Water Fog, Foam, Carbon Dioxide, Dry Chemical Unsuitable Extinguishing Media: Do not use forced water stream as this could cause the fire to spread. Products of Combustion: Normal products of combustion, smoke, carbon dioxide, carbon monoxide, and sulfur trioxides. Protection of Firefighters: Wear self-contained positive pressure breathing apparatus and protective clothes. Use shield to protect from rupturing and venting containers. At elevated temperatures containers may vent, rupture or burst, even violently VI. Accidental Release Measures: Personal Precautions: Eliminate all ignition sources. Persons not wearing protective equipment should be excluded from area of spill until clean up has been completed. Environmental Precautions: Prevent run-off to sewers, streams, or other bodies of water. If run-off occurs, notify proper authorities as required that a spill has occurred. Run off to sewer may create fire or explosion hazard. Methods for Containment: Dike or contain spill and absorb with inert materials (sand, sawdust, absorbent sweeping compounds, rags, etc). Methods for Cleanup: Using a non-metalic scoop, place contaminated material into an approved chemical waste container. Where possible, vacuum spilled liquid using an explosion proof vacuum to recover material. Other Information: All equipment used with handling the concentrate must be grounded. If run-off occurs, notify proper authorities as required that a spill has occurred. VII. Handling and Storage: Handling Precautions: Use with adequate ventilation and proper protective equipment. Do not use or store near fire, sparks, or open flame. Do not puncture or incinerate container. Exposure to sunlight and temperatures above 120° may cause container to vent, rupture, or burst. Storage Precautions: Do not used in confined area without proper ventilation. Contact lenses may cause further damage in case of splash into eye. KEEP AWAY FROM CHILDREN AND ANIMALS! Danger: Flammable. VIII. Exposure Controls/Personal Protection: Wednesday, February 27, 2008 Page 3 of 5 MSDS - Material Safety Data Sheet Product Name: LIQUID WRENCH PENETRATING OIL MSDS No.: L106 Chemical Name OSHA PEL ACGIH TLV Other Limits Kerosene N/AV 100 ppm Not Available Naphthenic Petroleum Distillate 5 mg/m3 5 mg/m3 Not Available Solvent-Refined Heavy Paraffinic 5 mg/m3 5 mg/m3 Not Available Fragrance N/D N/D Not Available Carbon dioxide N/AV 5000 ppm Not Available Engineering Controls: Use with adequate ventilation. If TLV is exceeded, wear NIOSH approved respirator. Personal Protective Equipment: See Section 2 for applicable exposure limits. For prolonged exposure wear protective safety glasses, gloves, and apron. IX. Physical and Chemical Properties: Boiling Point: 320 F Melting Point: N/A Boiling Range: Not Available Freezing Point: Not Available Solubility In Water: Insoluble Evaporation Rate (Butyl Acetate = 1): N/A Flash Point: 132F Flash Point Method: TCC Odor Threshold: Not Available Appearance and Odor: Dark Liquid with petroleum odor Vapor Density (AIR = 1): N/A Vapor Pressure (mm Hg.): N/A pH Range: Not Available Partition Coefficient: Decomposition Temp: Not Available Lower Explosive Limit: 0.7% Upper Explosive Limit: 5% Specific Gravity (H20 = 1): 0.85 Other Information: VOC Content: 36.938 X. Stability and Reactivity: Stability: Product is stable Conditions to Avoid: See Incompatible Materials below Incompatible Materials: Avoid contact with strong oxidizers Hazardous Decomposition Products: Normal products of combustion, smoke, carbon dioxide, carbon monoxide, and sulfur trioxides. Possibility of Hazardous Reactions: Will not occur XI. Toxicological Information: N/D XII. Ecological Information: N/D Not Available Auto-Ignition Temp: Not Available Wednesday, February 27, 2008 Page 4 of 5 MSDS - Material Safety Data Sheet Product Name: LIQUID WRENCH PENETRATING OIL MSDS No.: L106 XIII. Disposal Considerations: DISPOSAL: This container may be recycled in aerosol recycling centers when empty. Before offering for recycling, empty the can by using the product according to the label. DO NOT PUNCTURE! If recycling is not available, wrap the container and discard in the trash. Dispose of unused product in accordance with all local, state government and federal laws and regulations. XIV. Transport Information: Shipping Name: Not Available DOT Hazard Class: Not Available DOT Subsidiary Hazard Class: Not Available UN/NA#: Not Available Packing Group: Not Available Transportation Information: DOT Hazard Class: ORM-D Shipping Name: Consumer Commodity The DOT description is provided to assist in the proper shipping classification of this product and may not be suitable for international and air shipping purposes. ICAO/IATA (US) Shipping Name: Aerosols Class: 2.1 UN number: UN1950 International: ICAO/IATA UN number: UN1950 Shipping Name: Aerosols Class: 2.1 IMDG UN number: UN1950 Shipping Name: Aerosols Class: 2. EmS: F-D, S-U XV. Regulatory Information: See Section 2 for SARA Reportable Chemicals. USA TSCA: All components of this material are listed on the US TSCA Inventory. Warning: This product contains a chemical(s) known to the State of California to cause cancer or birth defects or other reproductive harm. XVI. Other Information: Chemical State: X Chemical Type: Liquid Gas Pure X Mixture Chronic X Fire Solid 2 Hazard Category: X 2 Acute X Pressure Reactive Additional Manufacturer Warnings: Do not used in confined area without proper ventilation. Contact lenses may cause further damage in case of splash into eye. KEEP AWAY FROM CHILDREN AND ANIMALS! 2 N/E: Not Established N/D: Not Determined N/A: Not Applicable N/AV: Not Available 0 2 C 0 Wednesday, February 27, 2008 Page 5 of 5 MSDS - Material Safety Data Sheet Product Name: LIQUID WRENCH PENETRATING OIL MSDS No.: L106 Additional Product Information: While Radiator Specialty Company believes this data is accurate as of the revision date, we make no warranty with respect to the data and we expressly disclaim all liability for reliance thereon. The data is offered solely for information, investigation, and verification. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. DOW CORNING CORPORATION Fiche Signalétique Page: 1 de 8 Version: 1.4 Date de révision: 2007/06/27 MOLYKOTE(R) 557 SILICONE DRY FILM LUBRICANT 1. IDENTIFICATION DU PRODUIT ET DE LA SOCIETE No. de la F.S.: 02410885 NOM DU FOURNISSEUR: Dow Corning Canada Inc. 15-6400 Millcreek Drive, Suite 416 Mississauga, ON, Canada L5N 3E7 Préparé par Product Safety: (800) 248-2481 NEWALTA: (800) 567-7455 Date de révision: 2007/06/27 NOM DU FABRICANT: Dow Corning Corporation South Saginaw Road Midland, Michigan 48686 Téléphone d'urgence 24 heures: (989) 496-5900 CLASSIFICATION SIMDUT: Catégorie B, Division 3. Catégorie D, Division 2B. Utilisation du Produit: Lubrifiant 2. IDENTIFICATION DES DANGERS MESURES D'URGENCE GENERALES Description Générique: Etat Physique: Couleur: Odeur: Silicone dans solvant. Liquide. Incolore. Solvant. ++++++++++++++++++++++++++++++++++++++++++++ EFFETS SUR LA SANTE POTENTIELS Effets aigus Yeux: Le contact direct peut causer une légère irritation. Les vapeurs peuvent entraîner l'irritation des yeux. Peau: Aucune irritation significative n'est prévue à la suite d'une seule exposition à court terme. Inhalation: Les vapeurs peuvent irriter le nez et la gorge. La surexposition par inhalation peut causer la somnolence, des étourdissements, de la confusion ou une perte de coordination. Ingestion: L'aspiration de liquide au moment de vomir peut causer de graves lésions aux poumons. Effets suite a une exposition répétée/prolongée DOW CORNING CORPORATION Fiche Signalétique Page: 2 de 8 Version: 1.4 Date de révision: 2007/06/27 MOLYKOTE(R) 557 SILICONE DRY FILM LUBRICANT Peau: Le contact répété ou prolongé peut causer le dégraissage ou l'assèchemenent de la peau, ce qui peut entraîner une irritation cutanée et une dermatite. Inhalation: Aucun renseignement applicable connu. Ingestion: L'ingestion ou la déglutition répétée de grandes quantités peut causer des lésions internes. Signes et Symptômes d'une surexposition Aucun renseignement applicable connu. Certains Malaises et Maladies sont aggravés par suite d'une exposition Aucun renseignement applicable connu. Les effets potentiels d'une surexposition énumérés ci-dessus sont fondés sur des données et des résultats d'études menées sur des compositions similaires, des données portant sur les composants et/ou des études d'experts menées sur le produit. Veuillez vous référer à la section 11 pour connaître le détail des renseignements d'ordre toxicologique. 3. COMPOSITION/INFORMATION SUR LES INGRÉDIENTS Numéro de CAS Pds (%) Nom du composant 8052-41-3 > 60.0 Solvant Stoddard 108-11-2 3.0 - 7.0 4-Méthylpentane-2-ol Les ingrédients énumérés ci-dessus sont des produits contrôlés selon le Règlement sur les produits contrôlés (RPC) modifié. SOR/88-555. 4. PREMIERS SECOURS Yeux: Rincer immédiatement à grande eau pendant 15 minutes. Peau: Retirer de la peau et bien laver à l'eau et au savon ou à l'aide de détergent à sec. Consulter un médecin si l'irritation ou d'autres malaises se développent ou persistent. Inhalation: Amener la personne à l'air frais. Consulter un médecin si les malaises persistent. Ingestion: Consulter un médecin immédiatement. Ne provoquer le vomissement que sur instruction d'un médecin. Ne jamais donner quoi que ce soit par voie orale à une personne inconsciente. Notes au médecin: Traiter selon l'état de la personne et les conditions d'exposition. 5. MESURES DE LUTTE CONTRE L'INCENDIE Point d'éclair: 103.1 °F / 39.5 °C (Coupelle fermée) DOW CORNING CORPORATION Fiche Signalétique Page: 3 de 8 Version: 1.4 Date de révision: 2007/06/27 MOLYKOTE(R) 557 SILICONE DRY FILM LUBRICANT Auto-Inflammation: Pas disponible. Limites D'inflammabilité dans l'air: Pas disponible. Moyens d'extinction: Pour les gros incendies, utiliser de la poudre extinctrice, de la mousse ou de l'eau pulvérisée. Pour les petits incendies, utiliser du dioxyde de carbone (CO2), de la poudre extinctrice ou de l'eau pulvérisée. L'eau peut être utilisée pour refroidir les récipients exposés au feu. Mesures de lutte contre l'incendie: Il convient de porter un appareil respiratoire autonome et des vêtements de protection pour combattre de gros incendies de produits chimiques. Pulvériser avec de l'eau les conteneurs exposés au feu afin de les maintenir froids. Déterminer la nécessité d'évacuer ou d'isoler la zone en accord avec le plan d'urgence en vigueur. Risques d'incendie inhabituels: L'électricité statique s'accumulera et peut enflammer les vapeurs. Prévenir les risques d'incendie en procédant à la métallisation et à la mise à la terre ou à la purge des gaz inertes. 6. MESURES À PRENDRE EN CAS DE DISPERSION ACCIDENTELLE Retenue/Nettoyage: Eliminer toutes les sources possibles d'ignition. Procéder à l'évacuation ou à l'isolation de la zone conformément à la procédure d'urgence locale. Respecter toutes les recommandations liées au matériel de protection personnelle (décrites aux sections 5 et 8). Pour les déversements importants, installer des digues au d'autres méthodes de confinement pour empêcher la propagation du produit. Si le produit confiné par des digues peut être pompé, entreposer le produit récupéré dans un contenant approprié. Nettoyez les substances restantes du déversement à l'aide d'un absorbant approprié. Nettoyer la zone de façon appropriée puisque certains produits de silicone, méme en petites quantités, peuvent présenter un risque de dérapage. Le nettoyage final peut exiger l'utilisation de vapeur, de solvants ou de détergents. Éliminer l'absorbant ou les produits de nettoyage saturés de façon appropriée, puisqu'une combustion spontanée peut se produire. Des lois et des règlements locaux, provinciaux et fédéraux peuvent s'appliquer aux déversements et à l'élimination de ce produit et des produits et des articles utilisés pour le nettoyage des déversements. Note: Voir la section 8 sur l'équipement de protection personnelle sur les déversements. Appelez au (989) 496-5900, pour de plus amples renseignements. 7. MANIPULATION ET STOCKAGE Employer en présence d'un système de ventilation adéquate. Éviter le contact avec les yeux. Eviter tout contact avec la peau. Ne pas inhaler les vapeurs, le brouillard, les poussières ou les fumées. Maintenir le contenant fermé. Ne pas ingerer. L'électricité statique s'accumulera et peut enflammer les vapeurs. Prévenir les risques d'incendie en procédant à la métallisation et à la mise à la terre des contenants ou à la purge des gaz inertes. Maintenir le contenant fermé et le tenir à l'abri de la chaleur, des étincelles et des flammes. 8. CONTROLE DE L'EXPOSITION / PROTECTION INDIVIDUELLE DOW CORNING CORPORATION Fiche Signalétique Page: 4 de 8 Version: 1.4 Date de révision: 2007/06/27 MOLYKOTE(R) 557 SILICONE DRY FILM LUBRICANT Limite d'exposition du composant Consultez les autorités locales afin d'obtenir les normes provinciales acceptables. Numéro de CAS Nom du composant Limites d'exposition 8052-41-3 Solvant Stoddard OSHA PEL (final rule): TWA 500 ppm and ACGIH TLV: TWA 100 ppm. LD50: > 5,000 mg/kg - Ingestion Rat 108-11-2 4-Méthylpentane-2-ol OSHA PEL (final rule)-skin: TWA 25 ppm and ACGIH TLV-skin: TWA 25 ppm, STEL 40 ppm. LD50: Contrôles D'ngénierie Ventilation du poste de travail: Ventilation générale: Recommandé. Recommandé. Equipements de Protection Individuelle pour les Manipulations de Routine Yeux: Utiliser des lunettes à coques pour travailleur de l'industrie chimique. Peau: Se laver au moment des repas et à la fin des quarts de travail. Les vêtements et les souliers contaminés doivent être retirés dès que possible et bien lavés avant d'être réutilisés. Le port de gants de protection contre les produits chimiques est recommandé. Gants convenables: Évitez tout contact avec la peau en mettant en vigueur de bonnes procédures et pratiques d'hygiène industrielle. Choisissez et utilisez des gants et/ou des vêtements protecteurs pour réduire encore plus la possibilité de contact avec la peau. Consultez le fabricant de vos gants et/ou de votre équipement de protection personnelle pour le choix de matériaux compatibles appropriés. Inhalation: Utilisez une protection respiratoire à moins d'avoir une ventilation d'aspiration locale adéquate ou que l'évaluation de l'exposition indique que les expositions se situent dans les limites des directives d'exposition recommandées. Le personnel IH peut aider à juger la suffisance des contrôles techniques actuels. Respirateur Convenable: Une ventilation aspirante générale et locale est conseillée pour garder le niveau d'exposition aux vapeurs en dessous des seuils recommandés. Lorsque l'échantillonnage de l'air révèle des concentrations dépassant les seuils recommandés ou que ces concentrations sont inconnues, il faut porter une protection adéquate des voies respiratoires. Respectez la norme ACNOR Z94.4-93 et utilisez des respirateurs homologués NIOSH / ACNOR. Equipements de Protection Individuelle en Cas de Déversements DOW CORNING CORPORATION Fiche Signalétique Page: 5 de 8 Version: 1.4 Date de révision: 2007/06/27 MOLYKOTE(R) 557 SILICONE DRY FILM LUBRICANT Yeux: Utiliser un respirateur à masque complet. Peau: Se laver au moment des repas et à la fin des quarts de travail. Les vêtements et les souliers contaminés doivent être retirés dès que possible et bien lavés avant d'être réutilisés. Le port de gants de protection contre les produits chimiques est recommandé. Inhalation/Respirateur Convenable: Protection des voies respiratoires conseillée. Respectez la norme ACNOR Z94.4-93 et utilisez les respirateurs homologués NIOSH / ACNOR. La protection assurée par les respirateurs à adduction d'air filtré contre l'exposition à tout produit chimique dangereux est limitéeUtilisez un respirateur à adduction d'air à pression positive en cas de possibilité d'émission incontrôlée, si les niveaux d'exposition sont inconnus ou dans toute autre situation où la protection assurée par les respirateurs à adduction d'air filtré peut être insuffisante. Mesures de Précaution: Éviter le contact avec les yeux. Eviter tout contact avec la peau. Ne pas inhaler les vapeurs, le brouillard, les poussières ou les fumées. Maintenir le contenant fermé. Ne pas ingerer. Veuillez apporter de soin raisonnable Note: Ces précautions concernent une manipulation à la température de la pièce. L'utilisation a des températures élevées ou les applications en aérosol peut nécessiter des précautions supplémentaires. 9. PROPRIETES PHYSIQUES ET CHIMIQUES Etat Physique: Couleur: Odeur: Seuil olfactif: Densité @ 25°C: Viscosité: Point de Congélation: Point Ebullition: Tension de Vapeur @ 25°C: Densité de la vapeur: Taux d'évaporation: Solubilité dans l'eau: Coefficient de répartition eau / huile: pH: Contenu Volatile: Liquide. Incolore. Solvant. Non disponible. 0.77 1 cSt Pas disponible. > 65 °C Pas disponible. Pas disponible. Non disponible. Pas disponible. Non disponible. Pas disponible. 95 % Point d'éclair: 103.1 °F / 39.5 °C (Coupelle fermée) Auto-Inflammation: Pas disponible. Limites D'inflammabilité Pas disponible. dans l'air: Note: Ces informations ne sont pas destinées à la redaction de specification de produits. Veuillez contacter Dow Corning avant de rédiger vos spécifications. DOW CORNING CORPORATION Fiche Signalétique Page: 6 de 8 Version: 1.4 Date de révision: 2007/06/27 MOLYKOTE(R) 557 SILICONE DRY FILM LUBRICANT 10. STABILITE ET REACTIVITE stabilité chimique: Stable. Polymérisation dangereuse: Conditions à Eviter: La polymérisation dangereuse ne se produira pas. Materiaux à Eviter: Les comburants peuvent entraîner une réaction. Aucun(e). Produits de décomposition dangereux Le claquage thermique de ce produit durant un incendie ou sous des conditions de chaleur intense pourrait mener aux produits de décomposition suivants: Oxydes de carbone et traces de résidus de combustion de composés carbonés. Dioxyde de silicium. Formaldéhyde. 11. INFORMATIONS TOXICOLOGIQUES Renseignements sur les dangers particuliers des Composants Aucun renseignement applicable n'est connu. 12. INFORMATIONS ECOLOGIQUES Distribution et Evolution dans l'environnement Les renseignements complets ne sont pas encore disponibles. Les effets sur l'environnement Les renseignements complets ne sont pas encore disponibles. Evolution et les effets dans les stations d'épuration des eaux usée Les renseignements complets ne sont pas encore disponibles. Parametres De Danger (LC50 OR EC50) Toxicité Aigue en milieu Aquatique (MG/L) Toxicité Aigue en milieu terrestre (MG/L) Critère de classification de l'écotoxicité Elevé Moyen <=1 >1 and <=100 <=100 >100 and <= 2000 Faible >100 >2000 Ce Tableau est Adapté de "ENVIRONMENTAL TOXICOLOGY AND RISK ASSESSMENT", ASTM STP 1179, P. 34, 1993. Ce Tableau peut être utilisé pour classifier l'écotoxicité du produit quand des données ecotoxiques sont inscritent au dessus. Veuillez lire l'autre information sur la sécurité écologique de cette matière dans son ensemble. 13. CONSIDÉRATIONS RELATIVES À L'ÉLIMINATION DOW CORNING CORPORATION Fiche Signalétique Page: 7 de 8 Version: 1.4 Date de révision: 2007/06/27 MOLYKOTE(R) 557 SILICONE DRY FILM LUBRICANT Peut être incinéré conformément aux réglementations locales. Appelez la société locale d'élimination des déchets dangereux ou les autorités provinciales en matière de déchets pour plus de renseignements. 14. INFORMATIONS RELATIVES AU TRANSPORT Route du Canada (selon les règlements du code IMDG) Nom D'expedition: PETROLEUM DISTILLATES, N.O.S. Classe des dangers: 3 Numero UN/NA: UN 1268 Groupe D'emballage: III Étiquette(s) de risque: flammable liquid IMDG Maritime Nom D'expedition: PETROLEUM DISTILLATES, N.O.S. Classe des dangers: 3 Numero UN/NA: UN 1268 Groupe D'emballage: III Étiquette(s) de risque: flammable liquid ICAO Aérien Nom D'expedition: Petroleum distillates, n.o.s. Classe des dangers: 3 Numero UN/NA: UN 1268 Groupe D'emballage: III Classe des dangers: Flammable Liquid Appelez Dow Corning Transportation au (989) 496-8577 si vous avez besoin de renseignements supplémentaires. 15. INFORMATIONS REGLEMENTAIRES DOW CORNING CORPORATION Fiche Signalétique Page: 8 de 8 Version: 1.4 Date de révision: 2007/06/27 MOLYKOTE(R) 557 SILICONE DRY FILM LUBRICANT Ce produit a été classé conformément aux critères de danger énoncés dans le RPC, et la fiche signalétique contient tous les renseignements exigés par le RPC. CLASSIFICATION SIMDUT: Catégorie B, Division 3. Catégorie D, Division 2B. DSL STATUS: Toutes les substances chimiques dans ce produit figurent sur la LIS ou sont exemptées. 16. AUTRES INFORMATIONS Redigé par: Dow Corning Corporation Ces Données sont proposées de bonne foi comme valeurs typiques et non comme une spécification du produit. Aucune garantie, expresse ou tacite, n'est établie par la présente. Les méthodes recommandées pour l'hygiène industrielle et une manipulation sans risques sont considérées comme étant généralement applicables. Cependant, chaque utilisateur/trice devrait revoir ces recommandations dans le contexte spécifique de l'utilisation prévue et déterminer si celles-ci sont appropriées. (R) indique une Marque Déposée U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET (Prepared According to 29 CFR 1910.1200) ______________________________________________________________________________ SECTION 1 IDENTIFICATION Product Name: Manufacturer's Name: Manufacturer's Address: Manufacturer's Phone Number: Emergency Phone Number: Proper Shipping Name: Effective Date: FORMULA 494965 PENTRAZEN ZENEX International 7777 First Place, Cleveland Ohio 44146 (440) 232-4155 1-800-535-5053 Consumer Commodity, ORM-D 10-15-01 ______________________________________________________________________________ SECTION 2 IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS Chemical Name: Kerosene Mineral Spirits Propane Isobutane n-Butane Naphthenic Oil CAS No.: 8008-20-6 8052-41-3 74-98-6 75-28-5 106-97-8 64742-52-5 TLV: Not established 100ppm 2500ppm Not established 800ppm 5mg/m3 as mist ______________________________________________________________________________ SECTION 3 Boiling Point: Solubility in Water: Vapor Density(Air=1): PHYSICAL DATA <0 to >5500 F Nil Heavier than air Specific Gravity(H2O=1): Evaporation Rate: pH: 0.60 + 0.1 Slower than Ether NA _______________________________________________________________________________________________________________________________________ SECTION 4 FIRE AND EXPLOSION HAZARD DATA Flash Point: Flash Point(Propellant): Flammable Limits(Propellant): Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: 140OF <0OF LEL: 1.8 UEL: 12.0 Use water fog, dry chemical or carbon dioxide. Aerosol cans may rupture when heated. Heated cans may burst. _______________________________________________________________________________________________________________________________________ SECTION 5 Unstable______ Stable __X___ Incompatability (Materials to Avoid): Conditions to Avoid: Hazardous Decomposition or Byproducts: Hazardous Polymerization: REACTIVITY DATA Stability: None known. High temperatures. In fire, will decompose to carbon dioxide, carbon monoxide Will not occur __________________________________________________________________________________________________________________________________________ SECTION 6 STORAGE AND HANDLING INFORMATION Precautions to be Taken in Handling and Storing: When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved respirator. STORE AT TEMPERATURES BELOW 120oF KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME KEEP AWAY FROM CHILDREN FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY FOR USE BY TRAINED PERSONNEL ONLY KEEP CONTAINER CLOSED DURING STORAGE __________________________________________________________________________________________________________________________________________ SECTION 7 HEALTH HAZARDS AND FIRST AID Effects of Overexposure: SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible. EYES: Eye irritant. Will cause redness and burning sensation. INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness, nausea, and loss of coordination.Extreme overexposure may result in unconsciousness and possibly death. INGESTION: Aspiration hazard if swallowed. First Aid Procedures: SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get medical attention. Remove contaminated clothing and launder before reuse. EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Seek medical attention. INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention. INGESTION: DO NOT induce vomiting. Seek medical attention immediately. Note: Never give anything by mouth to an unconscious or convulsing victim. Keep person warm and quiet. __________________________________________________________________________________________________________________________________________ SECTION 8 SPECIAL PROTECTION INFORMATION Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: Self-contained breathing apparatus if above TLV limit. Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit. None required if spraying. As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we recommend the use of safety glasses or chemical splash goggles. Other Protective Equipment: Long sleeves and long pants. Work/Hygienic Practices: Do not smoke while using. Wash hands after use. __________________________________________________________________________________________________________________________________________ SECTION 9 SPILL OR LEAK PROCEDURE Steps To Be Taken In Case Material Is Released or Spilled: Use absorbent sweeping compound to soak up material. Put into container. Dispose as hazardous waste. Waste Disposal Method: Dispose as hazardous waste in accordance with EPA RCRA. _________________________________________________________________________________________________________________________________________ SECTION 10 REGULATORY INFORMATION SARA Title III, Section 313 Components: Mineral Spirits may contain 3.5% 1,2,4, Trimethylbenzene (CAS#95-63-6) which is subject to the reporting requirements of Section 313 of SARA Title III. Kerosene contains 0.5-1.5% xylene mix (CAS#1330-20-7), 0.5-1.5% naphthalene (CAS#91-20-3) and 0.4-1.2% biphenyl (CAS#92-52-4) which are subject to the reporting requirements of Section 313 of SARA Title III. __________________________________________________________________________________________________________________________________________ This information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties, express or implied, and assume no liability in connection with any use of this information. 494965 MATERIAL SAFETY DATA SHEET NAME OF PRODUCT MSDS DATE: 08/31/06 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: MANUFACTURED FOR: ADDRESS: EMERGENCY PHONE: CHEMTREC PHONE: 73491 Eye Wash Solution - 16 oz. Impact Products, LLC 2840 Centennial Road, Toledo, OH 43617 800-793-8740 CHEMICAL NAME: CHEMICAL FAMILY: CHEMICAL FORMULA: SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENT: CAS NO. % WT TLV/PEL This eye wash solution is a sterile, isotonic-preserved saline solution which complies with FDA regulations 21 CFR, parts 349 and 369. There are no ingredients in this eye wash solution which appeared on the OSHA standard 29 CFR 1910, subpart z. SECTION 3: HAZARDS IDENTIFICATION ROUTES OF ENTRY: Inhalation: No Skin: Yes Ingestion: Yes POTENTIAL HEALTH EFFECTS EYES: n/a SKIN: n/a INGESTION: n/a INHALATION: n/a ACUTE/CHRONIC HEALTH HAZARDS: Non-toxic to the skin and if accidentally ingested is non-hazardous, but might exert a mil emetic reaction accompanied by possible slight nausea. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: n/a CARCINOGENICITY No OSHA: NTP: No IARC: No OTHER: SECTION 4: FIRST AID MEASURES EYES: SKIN: INGESTION: INHALATION: n/a n/a Drink water if accidentally ingested to dilute the concentration n/a SECTION 5: FIRE-FIGHTING MEASURES FLAMMABLE LIMITS: non-flammable FLASH POINT: n/a METHOD USED: n/a HMIS HAZARD CLASSIFICATION: HEALTH: EXTINGUISHING MEDIA: n/a SPECIAL FIRE FIGHTING PROCEDURES: n/a UNUSUAL FIRE AND EXPLOSION HAZARDS: none LEL: n/a FLAMMABILITY: SECTION 6: ACCIDENTAL RELEASE MEASURES ACCIDENTAL RELEASE MEASURES: SECTION 7: HANDLING AND STORAGE HANDLING AND STORAGE: OTHER PRECAUTIONS: None None SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: VENTILATION : Local Exhaust: n/a Special: n/a PAGE 1 OF 3 UEL: n/a REACTIVITY: MATERIAL SAFETY DATA SHEET NAME OF PRODUCT MSDS DATE: 08/31/06 Mechanical: n/a Other: n/a RESPIRATORY PROTECTION: Not required EYE PROTECTION: Not required SKIN PROTECTION: Not required OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Not required WORK HYGIENIC PRACTICES: No special practices required SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE/ODOR: Clear, colorless, odorless liquid BOILING POINT: n/a MELTING POINT: n/a VAPOR PRESSURE (mmHg): n/a VAPOR DENSITY (AIR = 1): n/a SPECIAL GRAVITY (H2O = 1): n/a EVAPORATION RATE: n/a SOLUBILITY IN WATER: Complete PERCENT VOLATILE: VISCOSITY: SECTION 10: STABILITY AND REACTIVITY STABILITY: STABLE X UNSTABLE CONDITIONS TO AVOID (STABILITY): INCOMPATIBILITY (MATERIAL TO AVOID): HAZARDOUS DECOMPOSITION: HAZARDOUS POLYMERIZATION: CONDITIONS TO AVOID (POLYMERIZATION): None None None Will not occur None SECTION 11: TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION: SECTION 12: ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: SECTION 13: DISPOSAL CONSIDERATIONS/PROCEDURES FOR SPILL OR LEAK CLEANUP WASTE DISPOSAL METHOD: Standard PROCEDURE FOR SPILL OR LEAK CLEANUP: Consistent with local, state and federal regulations regarding disposal of nonhazardous materials. SECTION 14: TRANSPORT INFORMATION SECTION 15: REGULATORY INFORMATION SECTION 16: OTHER INFORMATION OTHER INFORMATION: DISCLAIMER: The information furished herein is believed to be accurate and represents the best data currently available to us. No warranty, expressed or implied is made and Impact Products LLC assumes no legal responsibility or liability resulting from its use. Additional Information: PAGE 2 OF 3 MATERIAL SAFETY DATA SHEET NAME OF PRODUCT MSDS DATE: 08/31/06 Effects of Freezing on Eye Saline Concentrate Freezing Point: 10 degrees F is the point where this product freezes solid, based on tests conducted by the manufacturer of the liquid. Sample bottles of Eye Wash Solution have been exposed to freezing conditions a number of times and allowed to thaw in order to test for degradation or breakdown of the product. No degradation or breakdown of eye wash has occurred under these circumstances. While liquid product is not harmed by freezing and sub-freezing temperatures, consideration should be given to the examination of the container/closure system (bottling) of the product to ensure that the bottle/cap has not been compromised. The bottle/cap and seal must be intact for assurance of continued sterility. Neutralizing Effects Eye Wash Solution is a buffered, isotonic, sterile saline solution, balanced to neutral pH 7. Being a neutral pH solution, acids or caustic liquid, thus lowering or raising the pH of the combination of fluids. PAGE 3 OF 3 MATERIAL SAFETY DATA SHEET A26W51 13 00 Section 1 -- PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER DATE OF PREPARATION HMIS CODES Health A26W51 30-SEP-07 Flammability Reactivity PRODUCT NAME CLASSIC 99® Interior Semi-Gloss Latex Enamel, Extra White 2* 0 0 MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY 101 Prospect Avenue N.W. Cleveland, OH 44115 TELEPHONE NUMBERS and WEBSITES Product Information www.sherwin-williams.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency for Chemical Emergency ONLY (spill, leak, (800) 424-9300 fire, exposure, or accident) % by WT 2 1 0.1 5 12 Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS CAS No. INGREDIENT UNITS VAPOR PRESSURE 112-34-5 2-(2-Butoxyethoxy)-ethanol ACGIH TLV Not Available 0.06 mm OSHA PEL Not Available 107-21-1 Ethylene Glycol ACGIH TLV 100 mg/m3 CEILI (aerosol) 0.12 mm OSHA PEL 50 ppm CEILING 14464-46-1 Cristobalite ACGIH TLV 0.05 mg/m3 as Resp. Dust OSHA PEL 0.05 mg/m3 as Resp. Dust 471-34-1 Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 15 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction Section 3 -- HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. Continued on page 2 A26W51 page 2 EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. In a confined area vapors in high concentration may cause headache, nausea or dizziness. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver and urinary systems. SIGNS AND SYMPTOMS OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Section 4 -- FIRST AID MEASURES EYES: SKIN: INHALATION: INGESTION: Flush eyes with large amounts of water for 15 minutes. Get medical attention. Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. If affected, remove from exposure. Restore breathing. Keep warm and quiet. Do not induce vomiting. Get medical attention immediately. Section 5 -- FIRE FIGHTING MEASURES FLASH POINT LEL UEL Not Applicable N.A. N.A. FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 -- ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Continued on page 3 A26W51 page 3 Section 7 -- HANDLING AND STORAGE STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. Continued on page 4 A26W51 page 4 Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 9.93 lb/gal 1189 g/l SPECIFIC GRAVITY 1.19 BOILING POINT 212 - 448 F 100 - 231 C MELTING POINT Not Available VOLATILE VOLUME 62 % EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 9.5 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.72 lb/gal 86 g/l Less Water and Federally Exempt Solvents 0.30 lb/gal 36 g/l Emitted VOC Section 10 -- STABILITY AND REACTIVITY STABILITY -- Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Section 11 -- TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Crystalline Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." Ethylene Glycol is considered an animal teratogen. It has been shown to cause birth defects in rats and mice at high doses when given in drinking water or by gavage. There is no evidence to indicate it causes birth defects in humans. TOXICOLOGY DATA Continued on page 5 A26W51 CAS No. 112-34-5 107-21-1 14464-46-1 471-34-1 13463-67-7 page 5 Ingredient Name 2-(2-Butoxyethoxy)-ethanol LC50 RAT LD50 RAT Ethylene Glycol LC50 RAT LD50 RAT Cristobalite LC50 RAT LD50 RAT Calcium Carbonate LC50 RAT LD50 RAT Titanium Dioxide LC50 RAT LD50 RAT 4HR Not Available 5660 mg/kg 4HR Not Available 4700 mg/kg 4HR Not Available Not Available 4HR Not Available Not Available 4HR Not Available Not Available Section 12 -- ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Section 13 -- DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Section 14 -- TRANSPORT INFORMATION US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. Section 15 -- REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND 107-21-1 Ethylene Glycol Glycol Ethers Continued on page 6 % by WT 1 2 % Element A26W51 page 6 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Section 16 -- OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. MATERIAL SAFETY DATA SHEET A26WQ8015 21 00 =========================================================================== Section 1 -- PRODUCT AND COMPANY IDENTIFICATION --------------------------------------------------------------------------PRODUCT NUMBER HMIS CODES Health 2* A26WQ8015 Flammability 0 Reactivity 0 PRODUCT NAME CLASSIC 99® Interior Latex Semi-Gloss Wall Paint, Antique White MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. THE SHERWIN-WILLIAMS COMPANY (216) 566-2917 170 Brunel Rd Mississauga, ON L4Z 1T5 DATE OF PREPARATION INFORMATION TELEPHONE NO. 20-APR-07 (905) 507-0166 =========================================================================== Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE --------------------------------------------------------------------------2 112-34-5 2-(2-Butoxyethoxy)-ethanol ACGIH TLV Not Available 0.06 mm OSHA PEL Not Available 1 107-21-1 Ethylene Glycol ACGIH TLV 100 mg/m3 CEILI (aerosol) 0.12 mm OSHA PEL 50 ppm CEILING 0.1 14464-46-1 Cristobalite ACGIH TLV 0.05 mg/m3 as Resp. Dust OSHA PEL 0.05 mg/m3 as Resp. Dust 3 471-34-1 Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 15 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction 15 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction =========================================================================== Section 3 -- HAZARDS IDENTIFICATION --------------------------------------------------------------------------ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. In a confined area vapors in high concentration may cause headache, nausea or dizziness. SIGNS AND SYMPTOMS OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. Continued on page 2 A26WQ8015 page 2 =========================================================================== MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. =========================================================================== Section 4 -- FIRST AID MEASURES --------------------------------------------------------------------------EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. =========================================================================== Section 5 -- FIRE FIGHTING MEASURES --------------------------------------------------------------------------FLASH POINT LEL UEL Not Applicable N.A. N.A. FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. =========================================================================== Section 6 -- ACCIDENTAL RELEASE MEASURES --------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. =========================================================================== Section 7 -- HANDLING AND STORAGE --------------------------------------------------------------------------STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Continued on page 3 A26WQ8015 page 3 =========================================================================== Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION --------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. =========================================================================== Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES --------------------------------------------------------------------------PRODUCT WEIGHT 10.07 lb/gal 1207 g/l SPECIFIC GRAVITY 1.21 BOILING POINT 212 - 448 F 100 - 231 C MELTING POINT Not Available VOLATILE VOLUME 61 % EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 9.5 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.73 lb/gal 87 g/l Less Water and Federally Exempt Solvents 0.31 lb/gal 37 g/l Emitted VOC Continued on page 4 A26WQ8015 page 4 =========================================================================== Section 10 -- STABILITY AND REACTIVITY --------------------------------------------------------------------------STABILITY -- Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur =========================================================================== Section 11 -- TOXICOLOGICAL INFORMATION --------------------------------------------------------------------------CHRONIC HEALTH HAZARDS Crystalline Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. Ethylene Glycol is considered an animal teratogen. It has been shown to cause birth defects in rats and mice at high doses when given in drinking water or by gavage. There is no evidence to indicate it causes birth defects in humans. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver and urinary systems. Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung cancer, however, such exposure levels are not attainable in the workplace. --------------------------------------------------------------------------TOXICOLOGY DATA CAS No. Ingredient Name --------------------------------------------------------------------------112-34-5 2-(2-Butoxyethoxy)-ethanol LC50 RAT 4HR Not Available LD50 RAT 5660 mg/kg 107-21-1 Ethylene Glycol LC50 RAT 4HR Not Available LD50 RAT 4700 mg/kg 14464-46-1 Cristobalite LC50 RAT 4HR Not Available LD50 RAT Not Available 471-34-1 Calcium Carbonate LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available =========================================================================== Section 12 -- ECOLOGICAL INFORMATION --------------------------------------------------------------------------ECOTOXICOLOGICAL INFORMATION No data available. Continued on page 5 A26WQ8015 page 5 =========================================================================== Section 13 -- DISPOSAL CONSIDERATIONS --------------------------------------------------------------------------WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. =========================================================================== Section 14 -- TRANSPORT INFORMATION --------------------------------------------------------------------------US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. =========================================================================== Section 15 -- REGULATORY INFORMATION --------------------------------------------------------------------------SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element --------------------------------------------------------------------------107-21-1 Ethylene Glycol 1 Glycol Ethers 2 TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. =========================================================================== Section 16 -- OTHER INFORMATION --------------------------------------------------------------------------This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Page 1 of 6 24 Hour Emergency: CHEMTREC: 1-800-424-9300 Material Safety Data Sheet National Response in Canada CANUTEC: 613-996-6666 Outside U.S. and Canada Chemtrec: 202-483-7616 NOTE: CHEMTREC, CANUTEC and National Response Center emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals Section 1 - Chemical Product / Company Information Product Name: KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer Identification Number: 125 Product Use/Class: Supplier: Preparer: Revision Date: Masterchem Industries, Inc. 3135 Old Highway M Imperial, MO 63052-7834 Div of Masco, Inc Crouse, Steve 02/13/2003 Manufacturer: Masterchem Industries, Inc. 3135 Old Highway M Imperial, MO 63052-7834 Div of Masco, Inc Section 2 - Composition / Information On Ingredients Chemical Name Ethylene Glycol Ammonium Hydroxide CAS Weight ACGIH Number % Less TLV-TWA Than 107-21-1 5.0 50 ppm 7664-41- 1.0 25 ppm 7 ACGIH TLVSTEL 20mg/m3 35 ppm OSHA OSHA PEL-TWA PELCEILING 50 ppm N.E. 50 ppm Section 3 - Hazards Identification *** Emergency Overview ***: Contains a material which may cause embryo/fetotoxicity based on animal data. Contains a material which can cause liver and kidney damage based on animal data. Irritant. Effects Of Overexposure - Eye Contact: Direct eye contact may cause irritation. Effects Of Overexposure - Skin Contact: Direct skin contact may cause irritation. Effects Of Overexposure - Inhalation: Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes). KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer 125 Page 2 of 6 Effects Of Overexposure - Ingestion: May cause severe gastrointestinal disturbance with headache, nausea, vomiting and diarrhea. Harmful if swallowed. Gross overexposure may cause severe kidney damage. Under normal use conditions, this product is not expected to cause adverse health effects. Effects Of Overexposure - Chronic Hazards: A component(s) of this product has been shown to cause adverse liver and kidney effects in laboratory animals. Primary Route(s) Of Entry: Unknown Section 4 - First Aid Measures First Aid - Eye Contact: If material gets into eyes, flush with water immediately for 15 minutes. Consult a physician. First Aid - Skin Contact: Wash skin thoroughly with soap and water. First Aid - Inhalation: No Information. First Aid - Ingestion: If swallowed do not induce vomiting. Seek immediate medical attention. Section 5 - Fire Fighting Measures Flash Point: Not applicable LOWER EXPLOSIVE LIMIT: UPPER EXPLOSIVE LIMIT : Extinguishing Media: Unknown Unusual Fire And Explosion Hazards: None known. Special Firefighting Procedures: No Information. Section 6 – Accidental Release Measures Steps To Be Taken If Material Is Released Or Spilled: Absorb residue with suitable chemical absorbent. Dike to prevent entering any sewer or waterway. Transfer liquid to a holding container. Dispose of material in accordance with all federal, state and local regulations. Spilled material becomes very slippery when wet. Section 7 - Handling And Storage Handling: Hazardous residue may remain in emptied container. Do not reuse empty containers without commercial cleaning or reconditioning. Use in well ventilated area. Storage: Keep container closed when not in use. KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer 125 Page 3 of 6 Section 8 - Exposure Controls / Personal Protection Engineering Controls: General ventilation should be provided to maintain ambient concentrations below nuisance levels. Respiratory Protection: Respirator use is not expected to be necessary under normal conditions of handling. In emergency situations, use of a NIOSH-approved respirator may be required. When concentrations exceed nuisance levels, use appropriate NIOSH-approved respirator. In extreme cases a Self Contained Breathing Apparatus (SCBA) may be necessary. Skin Protection: Chemical-resistant gloves may be required for individuals with sensitive skin. Sensitive individuals should wear gloves to prevent repeated contact. Eye Protection: No Information. Other protective equipment: No Information. Hygienic Practices: No Information. Section 9 - Physical And Chemical Properties Boiling Range: Odor: Appearance: Solubility in H2O: Freeze Point: Vapor Pressure: Physical State: 212 - 340 slight ammoniacal infinite 32F Liquid (See section 16 for abbreviation legend) Section 10 - Stability And Reactivity Conditions To Avoid: No Information. Incompatibility: No Information. Hazardous Decomposition: No Information. Hazardous Polymerization: No Information. Stability: No Information. Section 11 - Toxicological Information Product LD50: Product LC50: KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer 125 Vapor Density: Odor Threshold: Evaporation Rate: >air Specific Gravity: PH: Viscosity: 1.301 8.8 to 9.3 97 to 103KU Equal To Water Page 4 of 6 Chemical Name Ethylene Glycol LD50 Oral, rat: 4700 mg/kg Ammonium Hydroxide LC50 Inhalation: 10876 mg/m3 Inhalation-mouse 4230ppm/1H Section 12 - Ecological Information Ecological Information: No Information. Section 13 - Disposal Information Disposal Information: Dispose of material in accordance with applicable federal, state and local regulations. Section 14 - Transportation Information DOT Proper Shipping Name: DOT Technical Name: DOT Hazard Class: DOT UN/NA Number: Packing Group: Hazard Subclass: Resp. Guide Page: ORM-D Section 15 - Regulatory Information CERCLA – SARA Hazard Category This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: None Known. SARA Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Chemical Name Ethylene Glycol Toxic Substances Control Act: KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer 125 CAS Number 107-21-1 Page 5 of 6 This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: Chemical Name Ethylene Glycol CAS Number 107-21-1 U.S. State Regulations: As follows – New Jersey Right-to-Know: The following materials are non-hazardous, but are among the top five components in this product. Chemical Name Inert non-hazardous material Water Talc, containing no asbestos fibers Titanium Dioxide Calcium Carbonate CAS Number MIXTURE 7732-18-5 14807-96-6 13463-67-7 1317-65-3 Pennsylvania Right-to-Know: The following non-hazardous ingredients are present in the product at greater than 3%. Chemical Name Inert non-hazardous material Water Talc, containing no asbestos fibers Titanium Dioxide Calcium Carbonate Nepheline syenite CAS Number MIXTURE 7732-18-5 14807-96-6 13463-67-7 1317-65-3 37244-96-5 California Proposition 65: Warning: The following ingredients present in the product are known to the state of California to cause Cancer: No Proposition 65 Carcinogenic materials exist in this product Warning: The following ingredients present in the product are known to the state of California to cause birth defects, or other reproductive hazards. Chemical Name Ethylene Glycol International Regulations: As follows – CANADIAN WHMIS: KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer 125 CAS Number 107-21-1 Page 6 of 6 This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings. CANADIAN WHMIS CLASS: Section 16 - Other Information HMIS Ratings: Health: 1- Minor Hazard Flammability: 0 - No Hazard Reactivity: 0 Personal Protection: B VOLATILE ORGANIC COMPOUNDS, GR/LTR: 157 REASON FOR REVISION: Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined DISCLAIMER The information accumulated herein is believed to be accurate, but is not warranted to be, whether orginated with the company or not. Since the use of this information and the conditions of use are not within the control of the manufacturer, it is the user's obligation to determine for safe use of this product. All ingredients used in the manufacture of this product are, if required, listed on the TSCA inventory. KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer 125 Page 1 of 6 24 Hour Emergency: CHEMTREC: 1-800-424-9300 Material Safety Data Sheet National Response in Canada CANUTEC: 613-996-6666 Outside U.S. and Canada Chemtrec: 202-483-7616 NOTE: CHEMTREC, CANUTEC and National Response Center emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals Section 1 - Chemical Product / Company Information Product Name: KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer Identification Number: 125 Product Use/Class: Supplier: Preparer: Revision Date: Masterchem Industries, Inc. 3135 Old Highway M Imperial, MO 63052-7834 Div of Masco, Inc Crouse, Steve 02/13/2003 Manufacturer: Masterchem Industries, Inc. 3135 Old Highway M Imperial, MO 63052-7834 Div of Masco, Inc Section 2 - Composition / Information On Ingredients Chemical Name Ethylene Glycol Ammonium Hydroxide CAS Weight ACGIH Number % Less TLV-TWA Than 107-21-1 5.0 50 ppm 7664-41- 1.0 25 ppm 7 ACGIH TLVSTEL 20mg/m3 35 ppm OSHA OSHA PEL-TWA PELCEILING 50 ppm N.E. 50 ppm Section 3 - Hazards Identification *** Emergency Overview ***: Contains a material which may cause embryo/fetotoxicity based on animal data. Contains a material which can cause liver and kidney damage based on animal data. Irritant. Effects Of Overexposure - Eye Contact: Direct eye contact may cause irritation. Effects Of Overexposure - Skin Contact: Direct skin contact may cause irritation. Effects Of Overexposure - Inhalation: Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes). KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer 125 Page 2 of 6 Effects Of Overexposure - Ingestion: May cause severe gastrointestinal disturbance with headache, nausea, vomiting and diarrhea. Harmful if swallowed. Gross overexposure may cause severe kidney damage. Under normal use conditions, this product is not expected to cause adverse health effects. Effects Of Overexposure - Chronic Hazards: A component(s) of this product has been shown to cause adverse liver and kidney effects in laboratory animals. Primary Route(s) Of Entry: Unknown Section 4 - First Aid Measures First Aid - Eye Contact: If material gets into eyes, flush with water immediately for 15 minutes. Consult a physician. First Aid - Skin Contact: Wash skin thoroughly with soap and water. First Aid - Inhalation: No Information. First Aid - Ingestion: If swallowed do not induce vomiting. Seek immediate medical attention. Section 5 - Fire Fighting Measures Flash Point: Not applicable LOWER EXPLOSIVE LIMIT: UPPER EXPLOSIVE LIMIT : Extinguishing Media: Unknown Unusual Fire And Explosion Hazards: None known. Special Firefighting Procedures: No Information. Section 6 – Accidental Release Measures Steps To Be Taken If Material Is Released Or Spilled: Absorb residue with suitable chemical absorbent. Dike to prevent entering any sewer or waterway. Transfer liquid to a holding container. Dispose of material in accordance with all federal, state and local regulations. Spilled material becomes very slippery when wet. Section 7 - Handling And Storage Handling: Hazardous residue may remain in emptied container. Do not reuse empty containers without commercial cleaning or reconditioning. Use in well ventilated area. Storage: Keep container closed when not in use. KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer 125 Page 3 of 6 Section 8 - Exposure Controls / Personal Protection Engineering Controls: General ventilation should be provided to maintain ambient concentrations below nuisance levels. Respiratory Protection: Respirator use is not expected to be necessary under normal conditions of handling. In emergency situations, use of a NIOSH-approved respirator may be required. When concentrations exceed nuisance levels, use appropriate NIOSH-approved respirator. In extreme cases a Self Contained Breathing Apparatus (SCBA) may be necessary. Skin Protection: Chemical-resistant gloves may be required for individuals with sensitive skin. Sensitive individuals should wear gloves to prevent repeated contact. Eye Protection: No Information. Other protective equipment: No Information. Hygienic Practices: No Information. Section 9 - Physical And Chemical Properties Boiling Range: Odor: Appearance: Solubility in H2O: Freeze Point: Vapor Pressure: Physical State: 212 - 340 slight ammoniacal infinite 32F Liquid (See section 16 for abbreviation legend) Section 10 - Stability And Reactivity Conditions To Avoid: No Information. Incompatibility: No Information. Hazardous Decomposition: No Information. Hazardous Polymerization: No Information. Stability: No Information. Section 11 - Toxicological Information Product LD50: Product LC50: KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer 125 Vapor Density: Odor Threshold: Evaporation Rate: >air Specific Gravity: PH: Viscosity: 1.301 8.8 to 9.3 97 to 103KU Equal To Water Page 4 of 6 Chemical Name Ethylene Glycol LD50 Oral, rat: 4700 mg/kg Ammonium Hydroxide LC50 Inhalation: 10876 mg/m3 Inhalation-mouse 4230ppm/1H Section 12 - Ecological Information Ecological Information: No Information. Section 13 - Disposal Information Disposal Information: Dispose of material in accordance with applicable federal, state and local regulations. Section 14 - Transportation Information DOT Proper Shipping Name: DOT Technical Name: DOT Hazard Class: DOT UN/NA Number: Packing Group: Hazard Subclass: Resp. Guide Page: ORM-D Section 15 - Regulatory Information CERCLA – SARA Hazard Category This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: None Known. SARA Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Chemical Name Ethylene Glycol Toxic Substances Control Act: KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer 125 CAS Number 107-21-1 Page 5 of 6 This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: Chemical Name Ethylene Glycol CAS Number 107-21-1 U.S. State Regulations: As follows – New Jersey Right-to-Know: The following materials are non-hazardous, but are among the top five components in this product. Chemical Name Inert non-hazardous material Water Talc, containing no asbestos fibers Titanium Dioxide Calcium Carbonate CAS Number MIXTURE 7732-18-5 14807-96-6 13463-67-7 1317-65-3 Pennsylvania Right-to-Know: The following non-hazardous ingredients are present in the product at greater than 3%. Chemical Name Inert non-hazardous material Water Talc, containing no asbestos fibers Titanium Dioxide Calcium Carbonate Nepheline syenite CAS Number MIXTURE 7732-18-5 14807-96-6 13463-67-7 1317-65-3 37244-96-5 California Proposition 65: Warning: The following ingredients present in the product are known to the state of California to cause Cancer: No Proposition 65 Carcinogenic materials exist in this product Warning: The following ingredients present in the product are known to the state of California to cause birth defects, or other reproductive hazards. Chemical Name Ethylene Glycol International Regulations: As follows – CANADIAN WHMIS: KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer 125 CAS Number 107-21-1 Page 6 of 6 This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings. CANADIAN WHMIS CLASS: Section 16 - Other Information HMIS Ratings: Health: 1- Minor Hazard Flammability: 0 - No Hazard Reactivity: 0 Personal Protection: B VOLATILE ORGANIC COMPOUNDS, GR/LTR: 157 REASON FOR REVISION: Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined DISCLAIMER The information accumulated herein is believed to be accurate, but is not warranted to be, whether orginated with the company or not. Since the use of this information and the conditions of use are not within the control of the manufacturer, it is the user's obligation to determine for safe use of this product. All ingredients used in the manufacture of this product are, if required, listed on the TSCA inventory. KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer 125 U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET (Prepared According to 29 CFR 1910.1200) ______________________________________________________________________________ SECTION 1 IDENTIFICATION Product Name: Manufacturer's Name: Manufacturer's Address: Manufacturer's Phone Number: Emergency Phone Number: Proper Shipping Name: Effective Date: FORMULA 496905 ZENASTICK RP ZENEX International 7777 First Place, Cleveland Ohio 44146 (440) 232-4155 1-800-535-5053 Consumer Commodity, ORM-D 10-15-01 ______________________________________________________________________________ SECTION 2 IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS Chemical Name: Heptane Butane Acetone Styrene-Butadiene Polymer Propane CAS No.: 142-82-5 106-97-8 67-64-1 9003-55-3 74-98-6 TLV: 400ppm 800ppm 500ppm Not established 2500ppm ______________________________________________________________________________ SECTION 3 Boiling Point: Solubility in Water: Vapor Density(Air=1): PHYSICAL DATA <0 to 2120 F Nil Heavier than air Specific Gravity(H2O=1): Evaporation Rate: pH: 0.7 + 0.1 Slower than Ether NA _______________________________________________________________________________________________________________________________________ SECTION 4 FIRE AND EXPLOSION HAZARD DATA Flash Point: Flammable Limits: Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: <0OF LEL: 1.1 UEL: 12.8 Use water fog, dry chemical or carbon dioxide. Aerosol cans may rupture when heated. Heated cans may burst _______________________________________________________________________________________________________________________________________ SECTION 5 Unstable______ Stable __X___ Incompatability (Materials to Avoid): Conditions to Avoid: Hazardous Decomposition or Byproducts: Hazardous Polymerization: REACTIVITY DATA Stability: None known. High temperatures. In fire, will decompose to carbon dioxide, carbon monoxide. Will not occur __________________________________________________________________________________________________________________________________________ SECTION 6 STORAGE AND HANDLING INFORMATION Precautions to be Taken in Handling and Storing: When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved respirator. STORE AT TEMPERATURES BELOW 120oF KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME KEEP AWAY FROM CHILDREN FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY FOR USE BY TRAINED PERSONNEL ONLY KEEP CONTAINER CLOSED DURING STORAGE __________________________________________________________________________________________________________________________________________ SECTION 7 HEALTH HAZARDS AND FIRST AID Effects of Overexposure: SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible. EYES: Eye irritant. Will cause redness and burning sensation. INHALATION: Effects of overexposure include headache, dizziness, nausea, loss of coordination, nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. INGESTION: Aspiration hazard if swallowed. First Aid Procedures: SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get medical attention. Remove contaminated clothing and launder before reuse. EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Seek medical attention. INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention. INGESTION: DO NOT induce vomiting. Seek medical attention immediately. Note: Never give anything by mouth to an unconscious or convulsing victim. Keep person warm and quiet. __________________________________________________________________________________________________________________________________________ SECTION 8 SPECIAL PROTECTION INFORMATION Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: Self-contained breathing apparatus if above TLV limit. Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit. None required if spraying. As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we recommend the use of safety glasses or chemical splash goggles. Other Protective Equipment: Long sleeves and long pants. Work/Hygienic Practices: Do not smoke while using. Wash hands after use. __________________________________________________________________________________________________________________________________________ SECTION 9 SPILL OR LEAK PROCEDURE Steps To Be Taken In Case Material Is Released or Spilled: Use absorbent sweeping compound to soak up material. Put into container. Dispose as hazardous waste. Waste Disposal Method: Dispose as hazardous waste in accordance with EPA RCRA. _________________________________________________________________________________________________________________________________________ SECTION 10 REGULATORY INFORMATION SARA Title III, Section 313 Components: None __________________________________________________________________________________________________________________________________________ This information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties, express or implied, and assume no liability in connection with any use of this information. 496905 |-------------------------------------------------------| | M A T E R I A L S A F E T Y D A T A S H E E T | |-------------------------------------------------------| |-------------------------------------------------------------------------| | SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION | |-------------------------------------------------------------------------| THIS MSDS IS OFFERED IN CANADIAN-FRENCH UPON REQUEST. ON PEUT DEMANDER CETTE MSDS A LA LANGUE FRANCAISE-CANADIENNE. PRODUCT NAME UPC NUMBER PRODUCT USE/CLASS : DAP 2000 HEAVY DUTY ADHESIVE : 7079870555, 7079870565 : Construction Adhesive SUPPLED BY: 24 HOUR EMERGENCY: DAP INC. TRANSPORTATION: 1-800-535-5053 (352-323-3500) 475 FINCHDENE SQUARE MEDICAL : 1-800-327-3874 (513-558-5111) UNITE 5 SCARBOROUGH ONTARIO M1X 1B7 PREPARE DATE : 02/03/1999 GENERAL INFORMATION: REVISION NO. : 8 DAP INC. : 1-888-DAP-TIPS (1-888-327-8477) REVISION DATE: 07/08/2003 REVIEWED: 01/15/2005 |-------------------------------------------------------------------------| | SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |-------------------------------------------------------------------------| WT/WT % ITEM ------------ CHEMICAL NAME ------------CAS NUMBER RANGE --------------------------------------------------------------------------01 N-Hexane 110-54-3 5.0-10.0 % 02 Aliphatic Petroleum Distillate 64742-89-8 15.0-20.0 % 03 2-Methyl Pentane 107-83-5 5.0-10.0 % 04 3-Methyl Pentane 96-14-0 5.0-10.0 % ---------------------- EXPOSURE LIMITS -------------------ACGIH OSHA COMPANY ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN --------------------------------------------------------------------------01 50 ppm N.E. 50 ppm N.E. N.E. NO 02 400 ppm N.E. 400 ppm N.E. N.E. NO 03 N.E. N.E. N.E. N.E. N.E. NO 04 N.E. N.E. N.E. N.E. N.E. NO (See Section 16 for abbreviation legend) Remaining ingredients are not considered hazardous per the OSHA Hazard Communication Standard. Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); limits may vary between states. (Continued on Page 2) --------------------------------------------------------------------------- Product Name: DAP 2000 HEAVY DUTY ADHESIVE Revision Date: 07/08/2003 Reviewed: 01/15/2005 Page 2 |-------------------------------------------------------------------------| | SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |-------------------------------------------------------------------------| |-------------------------------------------------------------------------| | SECTION 3 - HAZARDS IDENTIFICATION | |-------------------------------------------------------------------------| EMERGENCY OVERVIEW: DANGER! Extremely flammable liquid and vapor. Vapor harmful. Harmful or fatal if swallowed. Vapors may cause flash fire or explosion. Aspiration hazard if swallowed - can enter lungs and cause damage. Harmful if inhaled. POTENTIAL HEALTH EFFECTS: EFFECTS OF OVEREXPOSURE - EYE CONTACT: May cause eye irritation. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May irritate skin. Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). EFFECTS OF OVEREXPOSURE - INHALATION: Vapor harmful if inhaled. Vapor may irritate nose and upper respiratory tract. Vapor inhalation may affect the brain or nervous system causing dizziness, headache or nausea. EFFECTS OF OVEREXPOSURE - INGESTION: This material may be harmful or fatal if swallowed. Aspiration of material into the lungs due to vomiting can cause chemical pneumonitis which can be fatal. If ingested, this product may cause vomiting, diarrhea, and depressed respiration. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated permanent brain and nervous system damage with prolonged and repeated occupational overexposure to solvents. Hexane exposure may cause damage to the arms and legs which may be permanent. Symptoms include: loss of memory, loss of intellectual ability, and loss of coordination. MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY CONTACT: PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT None known. INHALATION |-------------------------------------------------------------------------| | SECTION 4 - FIRST AID MEASURES | |-------------------------------------------------------------------------| EYE CONTACT: Flush with large quantities of water until irritation subsides. Contact a physician. SKIN CONTACT: Wash with soap and water. INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Contact a physician immediately. Note: Only trained personnel should give artificial respiration or administer oxygen. (Continued on Page 3) --------------------------------------------------------------------------- Product Name: DAP 2000 HEAVY DUTY ADHESIVE Revision Date: 07/08/2003 Reviewed: 01/15/2005 Page 3 |-------------------------------------------------------------------------| | SECTION 4 - FIRST AID MEASURES | |-------------------------------------------------------------------------| INGESTION: DO NOT INDUCE VOMITING. If irritation or complications arise, contact a physician or Regional Poison Control Center immediately. COMMENTS: None. |-------------------------------------------------------------------------| | SECTION 5 - FIRE FIGHTING MEASURES | |-------------------------------------------------------------------------| FLASH POINT: -34 C (SETAFLASH CLOSED CUP) LOWER EXPLOSIVE LIMIT: N.A. UPPER EXPLOSIVE LIMIT: N.A. AUTOIGNITION TEMPERATURE: N.E. EXTINGUISHING MEDIA: CO2 DRY CHEMICAL FOAM UNUSUAL FIRE AND EXPLOSION HAZARDS: Extremely flammable. Material will readily ignite at room temperature. Vapors may form an explosive mixture with air. Vapors can travel long distances to a source of ignition and flashback. Containers may explode if exposed to extreme heat. Eliminate sources of ignition: heat, electrical equipment, sparks, and flames. Do not put in contact with oxidizing or caustic materials. SPECIAL FIREFIGHTING PROCEDURES: Full protective equipment, including self-contained breathing apparatus, is recommended to protect from combustion products. Cool exposed containers with water. |-------------------------------------------------------------------------| | SECTION 6 - ACCIDENTAL RELEASE MEASURES | |-------------------------------------------------------------------------| SPILL OR LEAK PROCEDURES: Dike spill area. Immediately eliminate sources of ignition. Use absorbent material or scrape up dried material and place into containers. |-------------------------------------------------------------------------| | SECTION 7 - HANDLING AND STORAGE | |-------------------------------------------------------------------------| HANDLING INFORMATION: KEEP OUT OF REACH OF CHILDREN. Avoid skin and eye contact. Avoid breathing vapors. Use only in a well ventilated area. STORAGE INFORMATION: Store away from caustics and oxidizers. Keep away from heat, spark, and flame. Keep containers tightly closed when not in use. Keep containers from excessive heat and freezing. Do not store at temperatures above 49 degrees C. OTHER PRECAUTIONS: Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Do not take internally. Construction and repair activities can adversely affect indoor air quality. Consult with the occupants or a representative (i.e. maintenance, building (Continued on Page 4) --------------------------------------------------------------------------- Product Name: DAP 2000 HEAVY DUTY ADHESIVE Revision Date: 07/08/2003 Reviewed: 01/15/2005 Page 4 |-------------------------------------------------------------------------| | SECTION 7 - HANDLING AND STORAGE | |-------------------------------------------------------------------------| manager, industrial hygienist, or safety officer) to determine ways to minimize any impact. |-------------------------------------------------------------------------| | SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |-------------------------------------------------------------------------| ENGINEERING CONTROLS: Provide sufficient mechanical ventilation (local or general exhaust) to maintain exposure below PEL and TLV. Vapors are heavier than air and will collect in low areas. Check all low areas (basements, sumps, etc.) for vapors before entering. RESPIRATORY PROTECTION: If 8 hour exposure limit or value is exceeded for any component, use an approved NIOSH/OSHA respirator. Consult your safety equipment supplier and the OSHA regulation, 29 CFR 1910.134 for respirator requirements. A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. EYE PROTECTION: Goggles or safety glasses with side shields. SKIN PROTECTION: Solvent impervious gloves. OTHER PROTECTIVE EQUIPMENT: if body contact may occur. HYGIENIC PRACTICES: Provide eyewash and solvent impervious apron Remove contaminated clothing and wash before reuse. |-------------------------------------------------------------------------| | SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |-------------------------------------------------------------------------| BOILING RANGE ODOR APPEARANCE SOLUBILITY IN H2O SPECIFIC GRAVITY VAPOR PRESSURE PHYSICAL STATE : : : : : : : 66 - 71 C VAPOR DENSITY : Is heavier than air Gasoline-like Gray color paste EVAPORATION RATE: Is faster than Butyl Negligible Acetate 1.3058 125 mm Hg @ 20 C Paste See Section 16 for abbreviation legend) |-------------------------------------------------------------------------| | SECTION 10 - STABILITY AND REACTIVITY | |-------------------------------------------------------------------------| CONDITIONS TO AVOID: INCOMPATIBILITY: Excessive heat and freezing. Strong oxidizers and caustics. HAZARDOUS DECOMPOSITION PRODUCTS: NOx Normal decomposition products, i.e. COx, (Continued on Page 5) --------------------------------------------------------------------------- Product Name: DAP 2000 HEAVY DUTY ADHESIVE Revision Date: 07/08/2003 Reviewed: 01/15/2005 Page 5 |-------------------------------------------------------------------------| | SECTION 10 - STABILITY AND REACTIVITY | |-------------------------------------------------------------------------| HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. |-------------------------------------------------------------------------| | SECTION 11 - TOXICOLOGICAL PROPERTIES | |-------------------------------------------------------------------------| ---------------------- TOXICITY DATA -------------------ITEM ORAL-LD50 SKIN-LD50 INHALATION-LC50 --------------------------------------------------------------------------01 28710 mg/kg(rat) N.A. N.A. n-Hexane has shown experimental teratogenic and reproductive affects. (See Section 16 for abbreviation legend) |-------------------------------------------------------------------------| | SECTION 12 - ECOLOGICAL INFORMATION | |-------------------------------------------------------------------------| No Information. |-------------------------------------------------------------------------| | SECTION 13 - DISPOSAL CONSIDERATIONS | |-------------------------------------------------------------------------| WASTE MANAGEMENT/DISPOSAL: Dispose of according to Federal, State, and Local Standards. Discarded material should be incinerated at a permitted facility. Liquids cannot be disposed of in a landfill. Do not reuse empty container. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA WASTE CODE - If discarded (40 CFR 261): None, yields no liquid component when evaluated by EPA method 1311 (TCLP) |-------------------------------------------------------------------------| | SECTION 14 - TRANSPORTATION INFORMATION | |-------------------------------------------------------------------------| DOT PROPER SHIPPING NAME: Consumer Commodity DOT HAZARD CLASS: ORM-D DOT UN/NA NUMBER: NONE PACKING GROUP: NONE Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may apply if shipped via other (Continued on Page 6) --------------------------------------------------------------------------- Product Name: DAP 2000 HEAVY DUTY ADHESIVE Revision Date: 07/08/2003 Reviewed: 01/15/2005 Page 6 |-------------------------------------------------------------------------| | SECTION 14 - TRANSPORTATION INFORMATION | |-------------------------------------------------------------------------| modes of transportation and/or to non-domestic destinations. Shipped in accordance with 49 CFR as part of a transborder shipment. |-------------------------------------------------------------------------| | SECTION 15 - REGULATORY INFORMATION | |-------------------------------------------------------------------------| U.S. FEDERAL REGULATIONS: AS FOLLOWS OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200) SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: ----------- CHEMICAL NAME ----------N-Hexane CAS NUMBER 110-54-3 WT/WT % RANGE 5.0-10.0% TOXIC SUBSTANCES CONTROL ACT: This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: ----------- CHEMICAL NAME ----------None. CAS NUMBER All ingredients are listed on the TSCA inventory INTERNATIONAL REGULATIONS: AS FOLLOWS CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. CANADIAN WHMIS CLASS: Class B2, Class D2B. |-------------------------------------------------------------------------| | SECTION 16 - OTHER INFORMATION | |-------------------------------------------------------------------------| HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 4 REACTIVITY: 0 PREVIOUS MSDS REVISION DATE: 04/17/2000 VOC less water, less exempt solvent: 330-340 g/L (25-26 weight%) VOC material : 330-340 g/L (Continued on Page 7) --------------------------------------------------------------------------- Product Name: DAP 2000 HEAVY DUTY ADHESIVE Revision Date: 07/08/2003 Reviewed: 01/15/2005 Page 7 |-------------------------------------------------------------------------| | SECTION 16 - OTHER INFORMATION | |-------------------------------------------------------------------------| LEGEND: ACGIH N.A. N.E. PEL NTP SARA STEL TLV VOC NJRTK N.D. - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS NOT APPLICABLE NOT ESTABLISHED PERMISSIBLE EXPOSURE LIMIT NATIONAL TOXICOLOGY PROGRAM SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 SHORT TERM EXPOSURE LIMIT THRESHOLD LIMIT VALUE(8 HR. TIME WEIGHTED AVERAGE OR TWA) VOLATILE ORGANIC COMPOUND NEW JERSEY RIGHT TO KNOW LAW NOT DETERMINED MSDS 17008 --------------------------------------------------------------------------- This data is offered in good faith as typical values and not as a product specification. No warranty either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review the recommendations in specific context of the intended use and determine if they are appropriate. --------------------------------------------------------------------------< End OF MSDS > |-------------------------------------------------------| | M A T E R I A L S A F E T Y D A T A S H E E T | |-------------------------------------------------------| |-------------------------------------------------------------------------| | SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION | |-------------------------------------------------------------------------| PRODUCT NAME UPC NUMBER : BEATS THE NAIL ENVIROLINE - SQUEEZE TUBE : 05960 PRODUCT USE/CLASS : Latex Adhesive MANUFACTURER: DAP INC. 2400 BOSTON STREET BALTIMORE, MD 21224 24 HOUR EMERGENCY: TRANSPORTATION: 1-800-535-5053 (352-323-3500) MEDICAL : 1-800-327-3874 (513-558-5111) PREPARE DATE : 09/13/1996 GENERAL INFORMATION: REVISION NO. : 4 DAP INC. : 1-888-DAP-TIPS (1-888-327-8477) REVISION DATE: 01/04/2000 |-------------------------------------------------------------------------| | SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |-------------------------------------------------------------------------| WT/WT % ITEM ------------ CHEMICAL NAME ------------CAS NUMBER RANGE --------------------------------------------------------------------------01 Ethanol 64-17-5 1.0-5.0 % ---------------------- EXPOSURE LIMITS -------------------ACGIH OSHA COMPANY ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN --------------------------------------------------------------------------01 1000 ppm N.E. 1000 ppm N.E. N.E. NO (See Section 16 for abbreviation legend) Remaining ingredients are not considered hazardous per the OSHA Hazard Communication Standard. Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); limits may vary between states. |-------------------------------------------------------------------------| | SECTION 3 - HAZARDS IDENTIFICATION | |-------------------------------------------------------------------------| EMERGENCY OVERVIEW: CAUTION! May irritate eyes, skin, nose, and respiratory tract. (Continued on Page 2) --------------------------------------------------------------------------- Product Name: BEATS THE NAIL ENVIROLINE - SQUEEZE TUBE Revision Date: 01/04/2000 Page 2 |-------------------------------------------------------------------------| | SECTION 3 - HAZARDS IDENTIFICATION | |-------------------------------------------------------------------------| POTENTIAL HEALTH EFFECTS: EFFECTS OF OVEREXPOSURE - EYE CONTACT: EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause eye irritation. May cause skin irritation. EFFECTS OF OVEREXPOSURE - INHALATION: Vapor harmful if inhaled. Vapor may irritate nose and upper respiratory tract. Vapor inhalation may affect the brain or nervous system causing dizziness, headache or nausea. EFFECTS OF OVEREXPOSURE - INGESTION: This material may be harmful or fatal if swallowed. If ingested this product may cause vomiting, diarrhea, and depressed respiration. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated permanent brain and nervous system damage with prolonged and repeated occupational overexposure to solvents. MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY CONTACT: PRIMARY ROUTE(S) OF ENTRY: None known. SKIN CONTACT |-------------------------------------------------------------------------| | SECTION 4 - FIRST AID MEASURES | |-------------------------------------------------------------------------| EYE CONTACT: Flush with large quantities of water until irritation subsides. Contact a physician. SKIN CONTACT: INHALATION: Wash with soap and water. Remove to fresh air. INGESTION: DO NOT INDUCE VOMITING. Control Center immediately. COMMENTS: Contact a physician immediately. Contact a physician or Regional Poison None. |-------------------------------------------------------------------------| | SECTION 5 - FIRE FIGHTING MEASURES | |-------------------------------------------------------------------------| FLASH POINT: >200 F (SETAFLASH CLOSED CUP) LOWER EXPLOSIVE LIMIT: N.A. UPPER EXPLOSIVE LIMIT: N.A. |-------------------------------------------------------------------------| AUTOIGNITION TEMPERATURE: N.E. EXTINGUISHING MEDIA: CO2 DRY CHEMICAL UNUSUAL FIRE AND EXPLOSION HAZARDS: FOAM None known. (Continued on Page 3) --------------------------------------------------------------------------- Product Name: BEATS THE NAIL ENVIROLINE - SQUEEZE TUBE Revision Date: 01/04/2000 Page 3 |-------------------------------------------------------------------------| | SECTION 5 - FIRE FIGHTING MEASURES | |-------------------------------------------------------------------------| SPECIAL FIREFIGHTING PROCEDURES: As in any fire, wear self-contained breathing apparatus pressure-demand (MSHA/NIOSH approved or equivalent) and full protective gear. Use water spray to cool exposed surfaces. |-------------------------------------------------------------------------| | SECTION 6 - ACCIDENTAL RELEASE MEASURES | |-------------------------------------------------------------------------| SPILL OR LEAK PROCEDURES: containers. Scrape up dried material and place into |-------------------------------------------------------------------------| | SECTION 7 - HANDLING AND STORAGE | |-------------------------------------------------------------------------| HANDLING INFORMATION: KEEP OUT OF REACH OF CHILDREN. Avoid skin and eye contact. Avoid breathing vapors. Use only in a well ventilated area. STORAGE INFORMATION: Store away from caustics and oxidizers. Keep containers tightly closed when not in use. Keep containers from excessive heat and freezing. Do not store at temperatures above 120 degrees F. OTHER PRECAUTIONS: Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Do not take internally. Use in a well ventilated area. Provide fresh air such that chemical odors cannot be detected during use and while drying. Construction and repair activities can adversely affect indoor air quality. Consult with the occupants or a representative(i.e. maintenance, building manager, industrial hygienist, or safety officer) to determine ways to minimize any impact. |-------------------------------------------------------------------------| | SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |-------------------------------------------------------------------------| ENGINEERING CONTROLS: Provide sufficient mechanical ventilation (local or general exhaust) to maintain exposure below PEL and TLV. Vapors are heavier than air and will collect in low areas. Check all low areas (basements, sumps, etc.) for vapor before entering. RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Not required under normal usage and adequate ventilation. EYE PROTECTION: SKIN PROTECTION: skin. Goggles or safety glasses with side shields. Gloves recommended for repeated or prolonged contact with OTHER PROTECTIVE EQUIPMENT: None. (Continued on Page 4) --------------------------------------------------------------------------- Product Name: BEATS THE NAIL ENVIROLINE - SQUEEZE TUBE Revision Date: 01/04/2000 Page 4 |-------------------------------------------------------------------------| | SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |-------------------------------------------------------------------------| HYGIENIC PRACTICES: Wash contaminated clothing before reuse. |-------------------------------------------------------------------------| | SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |-------------------------------------------------------------------------| BOILING RANGE ODOR APPEARANCE SOLUBILITY IN H2O SPECIFIC GRAVITY VAPOR PRESSURE PHYSICAL STATE : : : : : : : 210 - 220 F VAPOR DENSITY : Is heavier than air Mild Odor White Paste EVAPORATION RATE: Is slower than Butyl Miscible Acetate 1.4115 17.5 mm Hg @ 68F. Paste (See Section 16 for abbreviation legend) |-------------------------------------------------------------------------| | SECTION 10 - STABILITY AND REACTIVITY | |-------------------------------------------------------------------------| CONDITIONS TO AVOID: INCOMPATIBILITY: Excessive heat and freezing. Strong oxidizers and caustics. HAZARDOUS DECOMPOSITION PRODUCTS: NOx Normal decomposition products, i.e. COx, HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. |-------------------------------------------------------------------------| | SECTION 11 - TOXICOLOGICAL PROPERTIES | |-------------------------------------------------------------------------| No product or component toxicological information is available. |-------------------------------------------------------------------------| | SECTION 12 - ECOLOGICAL INFORMATION | |-------------------------------------------------------------------------| No Information. (Continued on Page 5) --------------------------------------------------------------------------- Product Name: BEATS THE NAIL ENVIROLINE - SQUEEZE TUBE Revision Date: 01/04/2000 Page 5 |-------------------------------------------------------------------------| | SECTION 13 - DISPOSAL CONSIDERATIONS | |-------------------------------------------------------------------------| WASTE MANAGEMENT/DISPOSAL: Dispose of according to Federal, State, and Local Standards. Do not reuse empty containers. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA WASTE CODE - If discarded (40 CFR 261): None. |-------------------------------------------------------------------------| | SECTION 14 - TRANSPORTATION INFORMATION | |-------------------------------------------------------------------------| DOT PROPER SHIPPING NAME: Not Regulated by D.O.T. DOT HAZARD CLASS: NONE DOT UN/NA NUMBER: NONE PACKING GROUP: NONE |-------------------------------------------------------------------------| | SECTION 15 - REGULATORY INFORMATION | |-------------------------------------------------------------------------| U.S. FEDERAL REGULATIONS: AS FOLLOWS OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200) SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: ----------- CHEMICAL NAME ----------CAS NUMBER No SARA Section 313 components exist in this product. WT/WT % RANGE TOXIC SUBSTANCES CONTROL ACT: This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: ----------- CHEMICAL NAME ----------No information is available. CAS NUMBER NEW JERSEY RIGHT-TO-KNOW: The following materials are non-hazardous, but are among the top five components in this product: (Continued on Page 6) --------------------------------------------------------------------------- Product Name: BEATS THE NAIL ENVIROLINE - SQUEEZE TUBE Revision Date: 01/04/2000 Page 6 |-------------------------------------------------------------------------| | SECTION 15 - REGULATORY INFORMATION | |-------------------------------------------------------------------------| ----------- CHEMICAL NAME ----------Water Vinyl acetate copolymer Plasticizer Calcium Carbonate CAS NUMBER 7732-18-5 TSRN-618608-5056P TSRN-618608-5064P 1317-65-3 PENNSYLVANIA RIGHT-TO-KNOW: The following non-hazardous ingredients are present in the product at greater than 3%: ----------- CHEMICAL NAME ----------Water Vinyl acetate copolymer Plasticizer Calcium carbonate CAS NUMBER 7732-18-5 proprietary proprietary 1317-65-3 CALIFORNIA PROPOSITION 65: WARNING: The chemical(s) noted below and contained in this product, are known to the state of California to cause cancer, birth defects or other reproductive harm: ----------- CHEMICAL NAME ----------CAS NUMBER No Proposition 65 chemicals exist in this product. INTERNATIONAL REGULATIONS: AS FOLLOWS CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. CANADIAN WHMIS CLASS: No information available. (Continued on Page 7) --------------------------------------------------------------------------- Product Name: BEATS THE NAIL ENVIROLINE - SQUEEZE TUBE Revision Date: 01/04/2000 Page 7 |-------------------------------------------------------------------------| | SECTION 16 - OTHER INFORMATION | |-------------------------------------------------------------------------| HMIS RATINGS - HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0 PREVIOUS MSDS REVISION DATE: 02/01/1997 REASON FOR REVISION: SECTION 1: Address change and new emergency contact phone numbers. VOC less water, less exempt solvent: 80-85 gm/l(6%) VOC material: 50-55 gm/l(5-6%) LEGEND: ACGIH N.A. N.E. PEL NTP SARA STEL TLV VOC NJRTK N.D. - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS NOT APPLICABLE NOT ESTABLISHED PERMISSIBLE EXPOSURE LIMIT NATIONAL TOXICOLOGY PROGRAM SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 SHORT TERM EXPOSURE LIMIT THRESHOLD LIMIT VALUE(8 HR. TIME WEIGHTED AVERAGE OR TWA) VOLATILE ORGANIC COMPOUND NEW JERSEY RIGHT TO KNOW LAW NOT DETERMINED MSDS# 77086 --------------------------------------------------------------------------- This data is offered in good faith as typical values and not as a product specification. No warranty either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review the recommendations in specific context of the intended use and determine if they are appropriate. --------------------------------------------------------------------------< End OF MSDS > 00010009605 English Page 1 of 7 Material Safety Data Sheet 24 Hour Emergency Phone Numbers: Medical/Poison Control: In U.S.: Call 1-800-222-1222 Outside U.S.: Call your local poison control center Transportation/National Response Center: 1-800-535-5053 1-352-323-3500 NOTE: The National Response Center emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals. IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16. Section 1 - Chemical Product / Company Information This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request. On peut demader cette fiche signalétique (MSDS) a la langue francaise-canadienne. Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere. Product Name: Product UPC Number: Product Use/Class: Manufacturer: Kwik Seal Tub & Tile Adhesive Caulk - All Colors 070798710504, 070798710207, 070798710238 Latex Caulk Revision Date: Supercedes: 05/21/2008 MSDS Number: 00010009605 04/27/2005 DAP Canada 475 Finchdene Square Unit 5 Scarborough, Ontario M1X 1B7 888-327 -8477 (non-emergency) Section 2 - Hazards Identification Emergency Overview: A colored paste product with a very slight ammonia odor. WARNING! May cause eye, skin, nose, throat and respiratory tract irritation. May cause eye or skin irritation. Harmful if swallowed or absorbed through the skin. This product contains ethylene glycol. Refer to other MSDS sections for other detailed information. Effects Of Overexposure - Eye Contact: May cause eye irritation. Effects Of Overexposure - Skin Contact: May cause skin irritation. Harmful if absorbed through the skin. Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation of high concentrations may cause headache, nausea, and dizziness. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes). Inhalation may cause mild irritation to the respiratory tract (nose, mouth, mucous membranes). Effects Of Overexposure - Ingestion: Ingestion of ethylene glycol can cause gastrointestinal irritation, nausea, vomiting, diarrhea and if ingested in sufficient quantities, death. Harmful or fatal if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. If ingested, may cause vomiting, diarrhea, and depressed respiration. Ingestion may result in obstruction when material hardens. Effects Of Overexposure - Chronic Hazards: Repeated or prolonged exposure may cause skin, respiratory, kidney and 00010009605 English Page 2 of 7 liver damage. Prolonged and repeated skin contact may cause irritation and possibly dermatitis. The International Agency for Research on Cancer (IARC) has determined that crystalline silica in the form of quartz or cristobalite that is inhaled from occupational sources is carcinogenic to humans (Group 1- carcinogenic to humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (published in June 1997) in conjunction with the use of these materials. The National Toxicology Program (NTP) classifies respirable crystalline silica as "known to be a human carcinogen". Refer to the 9th Report on Carcinogens (2000). The American Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (Group A2). Breathing dust containing respirable crystalline silica may not cause noticeable injury or illness even though permanent lung damage may be occurring. Inhalation of dust may have the following serious chronic health effects: Excessive inhalation of respirable dust can cause pneumoconiosis, a respiratory disease, which can result in delayed, progressive, disabling and sometimes fatal lung injury. Symptoms include cough, shortness of breath, wheezing, non-specific chest illness and reduced pulmonary function. Smoking exacerbates this disease. Individuals with pneumoconiosis are predisposed to develop tuberculosis. There is some evidence that breathing respirable crystalline silica or the disease silicosis is associated with an increased incidence of significant disease endpoints such as scleroderma (an immune system disorder manifested by fibrosis of the lungs, skin and other internal organs) and kidney disease. Prolonged, repeated, or high exposures may cause weakness and depression of the central nervous system. Formaldehyde vapor is a known animal carcinogen according to OSHA and NTP and is considered possibly carcinogenic to humans by inhalation. The International Agency for Research on Cancer considers formaldehyde to be a human carcinogen. A mixture of diisodecyl phthalate and diisononyl phthalate has been tested in a two-generation toxicity study in laboratory animals. No effects on reproductive parameters were seen. However, a small but statistically significant increase in early offspring mortality was seen at high oral doses. The significance of this to humans is uncertain. The mixture of phthalate esters contained within this product has been shown to cause developmental effects at high doses in laboratory animals when administered orally by gavage in a developmental study and developmental and fertility effects when administered at high doses by feed in a two-generation reproduction study. The potential risk from occupational and consumer exposure is considered to be very low, based on limited relevance of the rodent findings to humans and the large safety margins between exposure and the effect levels. Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Studies have shown that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals. Ethylene glycol has been shown to cause birth defects in laboratory animals. Primary Route(s) Of Entry: Skin Contact, Inhalation, Eye Contact Medical Conditions which May be Aggravated by Exposure: None known. Carcinogenicity: CAS No. Chemical Name 13463-67-7 Titanium dioxide 14808-60-7 Silica, crystalline 50-00-0 Formaldehyde ACGIH OSHA IARC NTP Not Listed. Suspected human carcinogen. Suspected human carcinogen. Not Listed. Possible carcinogen. Not Listed. Not Listed. Human carcinogen. Known carcinogen. Potential cancer hazard. Human carcinogen. Anticipated carcinogen. Section 3 - Composition / Information On Ingredients Chemical Name Limestone Branched and linear phthalates Titanium dioxide n-Butyl acetate Silica, crystalline Ethylene glycol Formaldehyde CASRN 1317-65-3 Proprietary 13463-67 -7 123-86-4 14808-60 -7 107-21-1 50-00 -0 Wt% 30 -60 1-5 0.1-1.0 0.1-1.0 0.1-1.0 0.1-1.0 <0.02 00010009605 English Page 3 of 7 Section 4 - First Aid Measures First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes until irritation subsides. Get medical attention immediately. First Aid - Skin Contact: Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical aid if symptoms persist. If skin irritation persists, call a physician. Remove and wash contaminated clothing. In case of contact, immediately flush skin with plenty of water while removing contaminated clothing and shoes. First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If continued breathing difficulty is experienced, get medical attention immediately. First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately. If ingested, drink 2 glasses of water. Immediately see a physician. Never give anything by mouth to an unconscious person. Note to Physician: None. COMMENTS: If over-exposure occurs, call your local poison control center. Section 5 - Fire Fighting Measures Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog Unusual Fire And Explosion Hazards: No special protective measures against fire required. Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent) and full protective gear. Use water spray to cool exposed surfaces. Section 6 - Accidental Release Measures Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use absorbent material or scrape up dried material and place in container. Section 7 - Handling And Storage Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Avoid breathing vapor and contact with eyes, skin and clothing. Use only with adequate ventilation. Open all windows and doors or use other means to ensure cross-ventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous conditions. Wash thoroughly after handling. Storage: Do not store at temperatures above 120 degrees F. Store containers away from excessive heat and freezing. Close container after each use. Store away from caustics and oxidizers. Section 8 - Exposure Controls / Personal Protection Chemical Name CASRN ACGIH TWA ACGIH STEL ACGIH CEIL Limestone 1317-65-3 10 MGM3 N.E. N.E. Branched and linear phthalates Titanium dioxide n-Butyl acetate Proprietary 13463-67-7 123-86-4 N.E. 10 MGM3 150 PPM N.E. N.E. 200 PPM N.E. N.E. N.E. Silica, crystalline 14808-60-7 0.025 MGM. N.E. N.E. Ethylene glycol Formaldehyde 107-21-1 50-00-0 N.E. N.E. N.E. N.E. 100 MGM3 0.3 PPM OSHA TWA 5 MGM3 (respirable fraction) N.E. 15 MGM3 150 PPM 10/(%SiO2 + 2) MGM3 N.E. 0.75 PPM OSHA STEL OSHA CEIL Skin N.E. N.E. No N.E. N.E. N.E. N.E. N.E. N.E. No No No N.E. N.E. No N.E. 2 PPM N.E. N.E. No No 00010009605 English Page 4 of 7 Exposure Notes: 14808-60-7 The 2002 ACGIH Threshold Limit Values for Chemical Substances and Physical Agents lists the median Respirable Particulate Mass (RPM) point for crystalline silica at 4.0 microns in terms of the particle's aerodynamic diameter. The TLVs for crystalline silica represent the respirable fraction. OSHA PEL TWA for Quartz is calculated using the following formula: 10 mg/m3/(% SiO2 + 2). Both concentration and percent quartz for the application of this limit are to be determined from the fraction passing a size selector with the following characteristics. |------------------------------------------------------------------------------------ |-----------------------------------------| | ....... Aerodynamic diameter ( unit density sphere ) .....| Percent passing selector | | 2 ................................................................................|.................90....................| | 2.5 .............................................................................|..................75...................| | 3.5 .............................................................................|..................50...................| | 5.0 .............................................................................|..................25...................| | 10 ..............................................................................|...................0....................| 50-00-0 Formaldehyde is a specially regulated substance for which an OSHA chemical-specific exposure standard exits. Detailed information regarding this substance may be found in 29 CFR 1910.1048. Medical surveillance information regarding this substance may be found in Appendix C to 29 CFR 1910.1048. Precautionary Measures: Contact lenses pose a special hazard; soft lenses may absorb and all lenses concentrate irritants. Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Ensure adequate ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient concentrations below recommended exposure limits. Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSH-approved air purifying respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where airborne concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. National Institute for Occupational Safety and Health (NIOSH) has recommended that the permissible exposure limit be changed to 50 micrograms respirable free silica per cubic meter of air (0.05 mg/m3) as determined by a full shift sample up to 10-hour work shift. Skin Protection: Rubber gloves. Natural rubber, butyl rubber and polyvinyl chloride gloves are not suitable protection against the phthalates contained within this product; neoprene is recommended. Eye Protection: Goggles or safety glasses with side shields. Other protective equipment: Not required under normal use. Hygienic Practices: Wash hands before breaks and at the end of workday. Remove and wash contaminated clothing before re-use. Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary between states. Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work practices. Section 9 - Physical And Chemical Properties Boiling Range: Odor: 210 - 220 F Very Slight Ammonia Vapor Density: Odor Threshold: Heavier Than Air Not Established 00010009605 English Color: Solubility in H2O: Freeze Point: Vapor Pressure: Physical State: Flash Point, F: Lower Explosive Limit, %: Page 5 of 7 Colored Not Established Not Established Not Established Paste > 200 F Not Established Evaporation Rate: Slower Than n-Butyl Acetate Specific Gravity: 1.6 pH: Between 7.0 and 12.0 Viscosity: Not Established Flammability: Non-Flammable Method: (Seta Closed Cup) Upper Explosive Limit, %:Not Established When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally. (See section 16 for abbreviation legend) Section 10 - Stability And Reactivity Conditions To Avoid: Excessive heat and freezing. Incompatibility: Incompatible with strong bases and oxidizing agents. Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx. Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions. Stability: Stable under recommended storage conditions. Section 11 - Toxicological Information Product LD50: Not Established CASRN 123-86-4 107-21-1 50-00-0 Chemical Name n-Butyl acetate Ethylene glycol Formaldehyde Product LC50: Not Established LD50 Rat:10768 MG/KG Rat:4700 mg/kg ------------- LC50 Rat:2000 P Rat:10876 mg/kg Rat:203 mg/m3 Significant Data with Possible Relevance to Humans: This product contains trace amounts of free formaldehyde. OSHA and NTP identify formaldehyde as a potential carcinogen. IARC identifies formaldehyde as a human carcinogen. Formaldehyde has been shown to cause mutations in a variety of in-vitro test systems, the significance of which to humans is unknown. There should be minimal risk when used with ventilation adequate to keep the atmospheric concentration of formaldehyde below the recommended exposure limits. Maintain adequate ventilation to prevent exposure above current OSHA / ACGIH exposure limits. Workplace monitoring of the air to define formaldehyde exposure levels may be necessary. In a two-year inhalation study, rats showed carcinogenic effects in the respiratory system at 15 ppm of formaldehyde. Section 12 - Ecological Information Ecological Information: Ecological injuries are not known or expected under normal use. Section 13 - Disposal Information Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA Waste Code if Discarded (40 CFR Section 261): This product does not meet the definition of a hazardous waste according to U.S. EPA Hazardous Waste Management Regulation, 40 CFR Section 261. Section 14 - Transportation Information 00010009605 English DOT Proper Shipping Name: DOT Technical Name: DOT Hazard Class: Page 6 of 7 Not Regulated Packing Group: N.A. N.A. N.A. Hazard Subclass: DOT UN/NA Number: N.A. None Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may apply if shipped via other modes of transportation and/or to non-domestic destinations. Section 15 - Regulatory Information CERCLA - SARA Hazard Category: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Immediate Health Hazard, Chronic Health Hazard SARA Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: None Toxic Substances Control Act: All ingredients in this product are either on TSCA inventory list, or otherwise exempt. This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: Chemical Name CAS Number Mercury & compounds 7439-97-6 Canadian WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. Canadian WHMIS Class: Not Controlled. Section 16 - Other Information HMIS Ratings: Health: 1 Flammability: 1 Reactivity: 0 Volatile Organic Compounds (VOC), less water less exempts: g/L: Personal Protection: X 25.4 Volatile Organic Compounds (VOC), less water less exempts, less LVP -VOCs: lb/gal: 0.2 wt:wt%: 1.1 wt:wt%: 0.6 REASON FOR REVISION: Periodic Update Legend: N.A. – Not Applicable ACGIH – American Conference of Governmental Industrial Hygienists 00010009605 English Page 7 of 7 N.E. – Not Established SARA – Superfund Amendments and Reauthorization Act of 1986 N.D. – Not Determined NJRTK – New Jersey Right-to-Know Law VOC – Volatile Organic Compound OSHA – Occupational Safety and Health Administration PEL – Permissible Exposure Limit HMIS – Hazardous Materials Identification System TLV – Threshold Limit Value NTP – National Toxicology Program CEIL – Ceiling Exposure Limit STEL – Short Term Exposure Limit LD50 – Lethal Dose 50 LC50 – Lethal Concentration 50 F – Degree Fahrenheit MSDS – Material Safety Data Sheet C – Degree Celsius CASRN – The Chemical Abstracts Service Registry Number DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context of the intended use and (ii) determine if they are appropriate.MATERIAL SAFETY DATA SHEET PRODUCT: HANDI FOAM® MSDS No: 01009 ISSUE: 2 DATE OF ISSUE 7/7/03 Page 1 of 4 - Classified as Hazardous according to the criteria of NOHSC Ramset Fasteners (Aust) Pty Limited ACN 004 297 009 A Division of ITW Construction Products Maroondah Highway, Mooroolbark. Victoria. Australia. 3136 Telephone: 03 9726 6222 Emergency Telephone Number: 03 9726 6222 (Monday to Friday. 8 am to 5 pm EST) PRODUCT IDENTIFICATION Product Name: Manufacturer’s Product Code: Other Names: UN Number: Dangerous Goods Code: Hazchem Code: Poisons Schedule: Handi Foam® HDFM105, HDFM205, HDFM605 None UN1956 2.2 2T S6 Primary Use: A two component expanding foam for filling large cavities. The two components are under pressure. The operator releases a trigger, which causes the components to mix together through a static mixing nozzle. The components react rapidly to form a solid foam mass. Physical Description / Properties Appearance: Specific Gravity: Flammability Limit: Form: Boiling Point: Vapour Pressure: Flashpoint: Solubility in Water: Other Properties: Part A (Isocyanate): Amber to dark brown liquid. Froths when released from container. Part B (Resin): Light yellow to amber coloured liquid. Froths when released from container. 1.2 (Both components) Not Flammable Liquid -26°C: 1,1,1,2 – Tetrafluoroethane Contents under pressure 345 Kpa. Not flammable Part A: Insoluble. Reacts to form a solid and CO2. Part B: Partially soluble. None Ingredients Chemical Name Part A 1,1,1,2 – Tetrafluoroethane 4,4’ – Diphenylmethane Diisocyanate (MDI) Higher Oligomers of MDI (Polymeric MDI) Part B 1,1,1,2 – Tetrafluoroethane Components not classified as hazardous CAS Number Proportion 811-97-2 101-68-8 9016-87-9 10 - 30% 30 – 60% 30 – 60% 811-97-2 10 - <30% To 100% MATERIAL SAFETY DATA SHEET PRODUCT: HANDI FOAM® MSDS No: 01009 ISSUE: 2 DATE OF ISSUE 7/7/03 Page 1 of 4 HEALTH HAZARD INFORMATION Health Effects Acute: Eye – May cause irritation. May damage eyes due to adhesion. Skin – Will adhere to skin. May cause localised irritation, reddening or swelling. Prolonged or repeated exposure may lead to sensitisation and /or contact dermatitis. Inhaled – May irritate mucus membranes with tightness in chest, coughing or allergic asthma-like sensitivity. Extensive overexposure can lead to respiratory symptoms like bronchitis and pulmonary oedema. These effects are usually reversible. Ingestion: May cause irritation to mucus membranes in the mouth and digestive tract. Chronic: Overexposure to 1,1,1,2 – Tetrafluoroethane may cause light-headedness, headaches or lethargy. Persons with cardiac arrhythmia may be at increased risk in severe overexposure. Overexposure to MDI may cause sensitisation by inhalation. First Aid ****Take a copy of this MSDS to the Doctor**** Eyes – Flush with water for at least 15 minutes with eyelids held open. Seek immediate medical attention. Skin – Remove contaminated clothing. Acetone or nail polish remover will assist removal of the residue. DO NOT apply acetone or solvents to eyes or other sensitive skin areas. Acetone will defat skin and may cause dermatitis in some individuals. Wash skin thoroughly with soap and water and apply moisturiser. Alternatively, allow foam to harden and remove mechanically. Foam residue will come off skin gradually over a period of a few days. If irritation persists seek medical attention. Inhaled – If breathing difficulty experienced, remove to fresh air. If symptoms persist seek medical attention. Swallowed – Rinse out with plenty of water. If poisoning occurs, contact doctor or Poisons Information Centre. If swallowed do not induce vomiting. Give a glass of water. First Aid Facilities – Eye wash stations Advice to Doctor: Treat symptomatically. MATERIAL SAFETY DATA SHEET PRODUCT: HANDI FOAM® MSDS No: 01009 ISSUE: 2 DATE OF ISSUE 7/7/03 Page 1 of 4 PRECAUTIONS FOR USE Exposure Limits: None assigned by NOHSC Exposure Guidelines MDI Higher oligomers of MDI 1,1,1,2 – Tetrafluoroethane OSHA 0.020 ppm ceiling None Established None Established ACGIH 0.005 ppm TWA None Established None Established Engineering Controls: Dilution ventilation to keep concentration below recommended limits Personal Protection: Eyes – Safety glasses with side shields, chemical goggles. Contact lenses pose a hazard. Hands – Barrier cream and PVC gloves should be worn. Feet – Rubber boots. Respiratory system – Respirator in accordance with AS1716 Respiratory Protective Devices, where ventilation is not adequate. Clothing – Wear long sleeved overalls. Eyewash unit should be present to flush eyes in the event of contamination. Flammability: Non flammable. SAFE HANDLING INFORMATION Storage and Transport. Contents under pressure. Store in a cool, dry place. Ideal storage temperature is 16°C to 27°C. Storage above 32°C will shorten shelf life. Protect containers from physical abuse. Storage below 13°C will affect properties of dispensed foam. Protect product from freezing. UN 1956 Class 2.2 Non Flammable Compressed Gas Spills and Disposal If either Part A or Part B are spilled on their own. Wear skin, eye and respiratory protection. Soak up material with absorbent and shovel into chemical waste container. Loosely cover container and remove from work area. Decontaminate waste and spill area with a solution of 0.2- 0.5% liquid detergent and 3 – 8 % concentrated ammonium hydroxide in water (5 – 10% sodium bicarbonate may be substituted for ammonium hydroxide). Use 10 parts of solution for each part of spill and allow to react for at least 10 minutes. Allow loosely covered MATERIAL SAFETY DATA SHEET PRODUCT: HANDI FOAM® MSDS No: 01009 ISSUE: 2 DATE OF ISSUE 7/7/03 Page 1 of 4 container to stand for several days before disposing of in accordance with directions from local authorities. Cured foam can be removed from surfaces mechanically. Fire / Explosion Hazard Not flammable. Contents under pressure. High temperatures will raise the pressures in the containers, which may lead to rupturing. Extinguishing media include: dry chemical, carbon dioxide, halon 1211, chemical foam or water spray if used in large quantities. (water contamination will produce carbon dioxide. Fire fighters to wear self-contained breathing apparatus. Combustion of components or cured foam will result in decomposition to produce CO, CO2, NO and other oxides of nitrogen and carbon and traces of HCN or HCl. Reactivity: Stable under recommended storage conditions. Incompatibilities: Alcohols, strong bases, amines, metal compounds (such as small particle metal catalysts) and water. OTHER INFORMATION No data CONTACT POINT Product Manager – Construction Chemicals 03 9726 6222 MATERIAL SAFETY DATA SHEET MSDS Name: SA-167 SILICONIZED ACRYLIC LATEX CAULK MSDS Number: 16711-001 Version Number 2 MSDS Date: SEP-09-2002 Page Number: 1 ----------------------------------------------------------------------------- SECTION I - PRODUCT AND COMPANY INFORMATION Product Name: HMIS Hazard Rating: SA-167 SILICONIZED ACRYLIC LATEX CAULK Health: 1 Fire: 0 Reactivity: 0 PPE: B Company Identification: OSI SEALANTS, INC.a Subsidiary of Sovereign Specialty Chems. 7405 PRODUCTION DRIVE MENTOR OH 44060 Information phone/Fax: Emergency Phone (24 hour) Chemtrec (outside-USA) (440) 255-8900 (440) 974-8358 CHEMTREC (800) 424-9300 (703) 527-3887 Product Class Trade Name Product Code CAULK PRO-SERIES 16711-XXX SECTION II - INGREDIENT AND HAZARD INFORMATION Hazardous Ingredient Name CAS Number Percent Titanium Dioxide ** 13463-67-7 < 5.0 Y ETHYLENE GLYCOL 107-21-1 < 2.0 Y MINERAL SPIRITS 64742-48-9 < 2.0 Y TSCA Ingredient Notes: Remaining ingredients are not considered OSHA hazardous. **The main hazard for Titanium Dioxide is dust inhalation. Because of its incorporation into the caulk, exposure by inhalation is unlikely. - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION III - PHYSICAL AND CHEMICAL PROPERTIES Form: High viscosity caulk Appearance/Color: various colors Solubility (in water): yes pH Value, +/-.3: 7.5 -------------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET MSDS Name: SA-167 SILICONIZED ACRYLIC LATEX CAULK MSDS Number: 16711-001 Version Number 2 MSDS Date: SEP-09-2002 Page Number: 2 ----------------------------------------------------------------------------Boiling Range: Vapor Pressure (mmHg): Evaporation Rate: 212.øF (100.øC) 15.@ 68.øF (20.øC) 0.5 times Slower than n-Butyl Acetate Vapor Density: Heavier than air % Volatile, Weight % Volatile, Volume Specific Gravity: VOC (less H2O or exempt) approx. 20.% approx. 30.% 1.556 41 Gr/L (2%) NOTE: Odor : Mild acrylic odor. Freeze Point : 32 Deg F - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION IV - FIRE FIGHTING MEASURES (Flash,UEL,LEL for solvent only) Flammability Class N/A Flash Range: Not Available Explosive Range (LEL/UEL): Not Applicable EXTINGUISHING MEDIA: Dry chemical -- Carbon Dioxide -- Foam -- Water Fog Will not burn in wet state. SPECIAL FIRE-FIGHTING PROCEDURES: Water may be used to cool and protect exposed containers. Caution should be taken because uncured material is water soluble. UNUSUAL FIRE AND EXPLOSION HAZARDS: Any closed container may burst when exposed to extreme heat or fire. - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION V - HEALTH HAZARD DATA ROUTES OF ENTRY: ENTRY THROUGH...Inhalation and skin most likely CARCINOGENICITY... NTP? N/E | IARC Monographs? N/E | OHSA? NO EFFECTS OF OVEREXPOSURE Inhalation: May irritate respiratory tract. Skin/Eye Contact: May cause irritation. Ingestion: Swallowing large amounts may cause nausea, vomiting. ( an unlikely route of entry ) -------------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET MSDS Name: SA-167 SILICONIZED ACRYLIC LATEX CAULK MSDS Number: 16711-001 Version Number 2 MSDS Date: SEP-09-2002 Page Number: 3 ----------------------------------------------------------------------------FIRST AID MEASURES Inhalation: If affected by inhalation, remove to fresh air. Eye Contact: Flush with water for at least 15 minutes, and get prompt medical attention. Skin Contact: Wash skin thoroughly with soap and water. Ingestion: Drink water, and get medical attention. ------------------------------------------------------------------N/A= Not applicable N/AV=Not available N/E, N/est=Not established - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION VI - STABILITY AND REACTIVITY Stability: This product is stable Hazardous Polymerization: Hazardous polymerization will not occur INCOMPATABILITY: None CONDITIONS TO AVOID: None HAZARDOUS DECOMPOSITION PRODUCTS: May produce oxides of carbon and oxides of nitrogen when burned. - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION VII - ACCIDENTAL RELEASE AND DISPOSAL MEASURES: STEPS TO BE TAKEN IN CASE OF SPILL: Wear appropriate protective clothing. Add dry absorbent and shovel or sweep up. Place in an appropriate container and seal. WASTE DISPOSAL METHOD: Dispose of in accordance with Federal, State, and Local regulations. - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits ACGIH TLV ACGIH TLV-C ACGIH STEL OSHA STEL OSHA PEL Titanium Dioxide ** 10.00 mg/F3 N/est N/est N/est 15.00 mg/F3 ETHYLENE GLYCOL 50.00 PPM N/est N/est N/est 50.00 PPM MINERAL SPIRITS 100.00 PPM N/est N/est N/est 100.00 PPM -------------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET MSDS Name: SA-167 SILICONIZED ACRYLIC LATEX CAULK MSDS Number: 16711-001 Version Number 2 MSDS Date: SEP-09-2002 Page Number: 4 ----------------------------------------------------------------------------- RESPIRATORY PROTECTION: NIOSH respirators recommended if vapors and mists are generated. VENTILATION: Local exhaust is recommended for safe practice. PROTECTIVE CLOTHING: Gloves and clothing should be worn to prevent repeated skin contact. EYE PROTECTION: Splashproof goggles or safety glasses should be worn. HANDLING AND STORAGE PRECAUTIONS: Keep from freezing. Keep away from heat. Keep containers closed when not in use. Avoid prolonged or repeated contact with skin. Keep out of the reach of children. - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION IX - TRANSPORT INFORMATION: DOT CLASSIFICATIONS FOR ONE GALLON AND UNDER CONTAINERS DESCRIPTION: Non-hazardous DOT CLASSIFICATIONS for OVER 1 GALLON size CONTAINERS DESCRIPTION: Non-hazardous, Caulking product - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION X - REGULATORY INFORMATION: SARA TITLE III SECTION 313: This product contains the following toxic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right to Know Act of 1986 and of 40 CFR 372: Ingredient Name CAS Number Percent ETHYLENE GLYCOL 107-21-1 < 2.0 The following ingredients are registered for TSCA 12B Ingredient Name CAS Number Percent ETHYLENE GLYCOL < 2.0 107-21-1 Ethylene Glycol fits the EPA Hazard Category definition of Immediate (Acute) and Delayed (Chronic) Health Hazards under SARA Sect.311,312. -------------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET MSDS Name: SA-167 SILICONIZED ACRYLIC LATEX CAULK MSDS Number: 16711-001 Version Number 2 MSDS Date: SEP-09-2002 Page Number: 5 ----------------------------------------------------------------------------All chemical substances are TSCA listed. California PROP.65 Chemicals: none known DISCLAIMER: The information contained herein is based on data available as of the date of preparation of this MSDS and which we believe to be reliable. However, no warranty is expressed or implied regarding the accuracy of the data. We shall not be responsible for the use of this information, or of any product, method, or apparatus mentioned, and the user must make his own investigation to determine the suitability of the information or products for his particular purpose, for the protection of the environment, and the health and safety of the users of this material. -------------------------------------------------------------------------------- Last Page 00010011605 English Page 1 of 7 Material Safety Data Sheet 24 Hour Emergency Phone Numbers: Medical/Poison Control: In U.S.: Call 1-800-222-1222 Outside U.S.: Call your local poison control center Transportation/National Response Center: 1-800-535-5053 1-352-323-3500 NOTE: The National Response Center emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals. IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16. Section 1 - Chemical Product / Company Information This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request. On peut demader cette fiche signalétique (MSDS) a la langue francaise-canadienne. Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere. Product Name: Product UPC Number: Product Use/Class: Manufacturer: DAP Alex Painters Acrylic Latex Caulk - All Colors 070798736313, 070798736351 Revision Date: Supercedes: 04/01/2008 Latex Caulk MSDS Number: 00010011605 10/29/2004 DAP Canada 475 Finchdene Square Unit 5 Scarborough, Ontario M1X 1B7 888-327 -8477 (non-emergency) Section 2 - Hazards Identification Emergency Overview: A colored paste product with a very slight ammonia odor. WARNING! May cause eye, skin, nose, throat and respiratory tract irritation. May cause eye or skin irritation. Harmful if swallowed or absorbed through the skin. This product contains ethylene glycol. Refer to other MSDS sections for other detailed information. Effects Of Overexposure - Eye Contact: May cause eye irritation. Effects Of Overexposure - Skin Contact: May cause skin irritation. Harmful if absorbed through the skin. Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation of high concentrations may cause headache, nausea, and dizziness. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes). Inhalation may cause mild irritation to the respiratory tract (nose, mouth, mucous membranes). Effects Of Overexposure - Ingestion: Ingestion of ethylene glycol can cause gastrointestinal irritation, nausea, vomiting, diarrhea and if ingested in sufficient quantities, death. Harmful or fatal if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. If ingested, may cause vomiting, diarrhea, and depressed respiration. Ingestion may result in obstruction when material hardens. Effects Of Overexposure - Chronic Hazards: Repeated or prolonged exposure may cause respiratory system damage. 00010011605 English Page 2 of 7 Prolonged and repeated skin contact may cause irritation and possibly dermatitis. The International Agency for Research on Cancer (IARC) has determined that crystalline silica in the form of quartz or cristobalite that is inhaled from occupational sources is carcinogenic to humans (Group 1- carcinogenic to humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (published in June 1997) in conjunction with the use of these materials. The National Toxicology Program (NTP) classifies respirable crystalline silica as "known to be a human carcinogen". Refer to the 9th Report on Carcinogens (2000). The American Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (Group A2). Breathing dust containing respirable crystalline silica may not cause noticeable injury or illness even though permanent lung damage may be occurring. Inhalation of dust may have the following serious chronic health effects: Excessive inhalation of respirable dust can cause pneumoconiosis, a respiratory disease, which can result in delayed, progressive, disabling and sometimes fatal lung injury. Symptoms include cough, shortness of breath, wheezing, non-specific chest illness and reduced pulmonary function. Smoking exacerbates this disease. Individuals with pneumoconiosis are predisposed to develop tuberculosis. There is some evidence that breathing respirable crystalline silica or the disease silicosis is associated with an increased incidence of significant disease endpoints such as scleroderma (an immune system disorder manifested by fibrosis of the lungs, skin and other internal organs) and kidney disease. Prolonged, repeated, or high exposures may cause weakness and depression of the central nervous system. Overexposure may cause kidney, cardiovascular, skin and liver damage. Formaldehyde vapor is a known animal carcinogen according to OSHA and NTP and is considered possibly carcinogenic to humans by inhalation. The International Agency for Research on Cancer considers formaldehyde to be a human carcinogen. A mixture of diisodecyl phthalate and diisononyl phthalate has been tested in a two-generation toxicity study in laboratory animals. No effects on reproductive parameters were seen. However, a small but statistically significant increase in early offspring mortality was seen at high oral doses. The significance of this to humans is uncertain. The mixture of phthalate esters contained within this product has been shown to cause developmental effects at high doses in laboratory animals when administered orally by gavage in a developmental study and developmental and fertility effects when administered at high doses by feed in a two-generation reproduction study. The potential risk from occupational and consumer exposure is considered to be very low, based on limited relevance of the rodent findings to humans and the large safety margins between exposure and the effect levels. Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Studies have shown that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals. Ethylene glycol has been shown to cause birth defects in laboratory animals. Primary Route(s) Of Entry: Skin Contact, Inhalation, Eye Contact Medical Conditions which May be Aggravated by Exposure: None known. Carcinogenicity: CAS No. Chemical Name 14808-60-7 Silica, crystalline 13463-67-7 Titanium dioxide 50-00-0 Formaldehyde ACGIH OSHA Suspected human carcinogen. Not Listed. Suspected human carcinogen. IARC NTP Not Listed. Human carcinogen. Known carcinogen. Not Listed. Possible carcinogen. Not Listed. Potential cancer hazard. Human carcinogen. Anticipated carcinogen. Section 3 - Composition / Information On Ingredients Chemical Name Limestone Branched and linear phthalates Stoddard solvent Ethylene glycol Silica, crystalline Titanium dioxide CASRN 1317-65-3 Proprietary 8052-41-3 107-21-1 14808-60 -7 13463-67 -7 Wt% 40 -70 1-5 0.5-1.5 0.1-1.0 0.1-1.0 0.1-1.0 00010011605 English Page 3 of 7 Ammonia Formaldehyde 7664-41-7 50-00 -0 0.1-1.0 <0.009 Section 4 - First Aid Measures First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes until irritation subsides. Get medical attention immediately. First Aid - Skin Contact: Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical aid if symptoms persist. If skin irritation persists, call a physician. Remove and wash contaminated clothing. In case of contact, immediately flush skin with plenty of water while removing contaminated clothing and shoes. First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If continued breathing difficulty is experienced, get medical attention immediately. First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately. If ingested, drink 2 glasses of water. Immediately see a physician. Never give anything by mouth to an unconscious person. Note to Physician: None. COMMENTS: If over-exposure occurs, call your local poison control center. Section 5 - Fire Fighting Measures Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog Unusual Fire And Explosion Hazards: No special protective measures against fire required. Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent) and full protective gear. Use water spray to cool exposed surfaces. Section 6 - Accidental Release Measures Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use absorbent material or scrape up dried material and place in container. Section 7 - Handling And Storage Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Avoid breathing vapor and contact with eyes, skin and clothing. Use only with adequate ventilation. Open all windows and doors or use other means to ensure cross-ventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous conditions. Wash thoroughly after handling. Storage: Do not store at temperatures above 120 degrees F. Store containers away from excessive heat and freezing. Close container after each use. Store away from caustics and oxidizers. Section 8 - Exposure Controls / Personal Protection Chemical Name CASRN ACGIH TWA ACGIH STEL ACGIH CEIL Limestone 1317-65-3 10 MGM3 N.E. N.E. Branched and linear phthalates Stoddard solvent Ethylene glycol Proprietary 8052-41-3 107-21-1 N.E. 100 PPM N.E. N.E. N.E. N.E. N.E. N.E. 100 MGM3 OSHA TWA 5 MGM3 (respirable fraction) N.E. 500 PPM N.E. OSHA STEL OSHA CEIL Skin N.E. N.E. No N.E. N.E. N.E. N.E. N.E. N.E. No No No 00010011605 English Page 4 of 7 Silica, crystalline 14808-60-7 0.05 MGM3 N.E. N.E. Titanium dioxide Ammonia Formaldehyde 13463-67-7 7664-41-7 50-00-0 10 MGM3 25 PPM N.E. N.E. 35 PPM N.E. N.E. N.E. 0.3 PPM 10/(%SiO2 + 2) MGM3 15 MGM3 50 PPM 0.75 PPM N.E. N.E. No N.E. N.E. 2 PPM N.E. N.E. N.E. No No No Exposure Notes: 14808-60-7 The 2002 ACGIH Threshold Limit Values for Chemical Substances and Physical Agents lists the median Respirable Particulate Mass (RPM) point for crystalline silica at 4.0 microns in terms of the particle's aerodynamic diameter. The TLVs for crystalline silica represent the respirable fraction. OSHA PEL TWA for Quartz is calculated using the following formula: 10 mg/m3/(% SiO2 + 2). Both concentration and percent quartz for the application of this limit are to be determined from the fraction passing a size selector with the following characteristics. |------------------------------------------------------------------------------------ |-----------------------------------------| | ....... Aerodynamic diameter ( unit density sphere ) .....| Percent passing selector | | 2 ................................................................................|.................90....................| | 2.5 .............................................................................|..................75...................| | 3.5 .............................................................................|..................50...................| | 5.0 .............................................................................|..................25...................| | 10 ..............................................................................|...................0....................| 50-00-0 Formaldehyde is a specially regulated substance for which an OSHA chemical-specific exposure standard exits. Detailed information regarding this substance may be found in 29 CFR 1910.1048. Medical surveillance information regarding this substance may be found in Appendix C to 29 CFR 1910.1048. Precautionary Measures: Contact lenses pose a special hazard; soft lenses may absorb and all lenses concentrate irritants. Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Ensure adequate ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient concentrations below recommended exposure limits. Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSH-approved air purifying respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where airborne concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. National Institute for Occupational Safety and Health (NIOSH) has recommended that the permissible exposure limit be changed to 50 micrograms respirable free silica per cubic meter of air (0.05 mg/m3) as determined by a full shift sample up to 10-hour work shift. Skin Protection: Rubber gloves. Natural rubber, butyl rubber and polyvinyl chloride gloves are not suitable protection against the phthalates contained within this product; neoprene is recommended. Eye Protection: Goggles or safety glasses with side shields. Other protective equipment: Not required under normal use. Hygienic Practices: Wash hands before breaks and at the end of workday. Remove and wash contaminated clothing before re-use. Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary between states. Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work practices. 00010011605 English Page 5 of 7 Section 9 - Physical And Chemical Properties Boiling Range: Odor: Color: Solubility in H2O: Freeze Point: Vapor Pressure: Physical State: Flash Point, F: Not Established Very Slight Ammonia Colored Not Established Not Established Not Established Paste Greater than 200 degrees Fahrenheit Lower Explosive Limit, %: Not Established Vapor Density: Odor Threshold: Evaporation Rate: Specific Gravity: pH: Viscosity: Flammability: Method: Heavier Than Air Not Established Slower Than n-Butyl Acetate 1.6 Between 7.0 and 12.0 Not Established Non-Flammable (Seta Closed Cup) Upper Explosive Limit, %:Not Established When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally. (See section 16 for abbreviation legend) Section 10 - Stability And Reactivity Conditions To Avoid: Excessive heat and freezing. Incompatibility: Incompatible with strong bases and oxidizing agents. Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx. Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions. Stability: Stable under recommended storage conditions. Section 11 - Toxicological Information Product LD50: Not Established CASRN 107-21-1 7664-41-7 50-00-0 Chemical Name Ethylene glycol Ammonia Formaldehyde Product LC50: Not Established LD50 Rat:4700 mg/kg ------------------------- LC50 Rat:10876 mg/kg Rat:2000 ppm/4H Rat:203 mg/m3 Significant Data with Possible Relevance to Humans: This product contains trace amounts of free formaldehyde. OSHA and NTP identify formaldehyde as a potential carcinogen. IARC identifies formaldehyde as a human carcinogen. Formaldehyde has been shown to cause mutations in a variety of in-vitro test systems, the significance of which to humans is unknown. There should be minimal risk when used with ventilation adequate to keep the atmospheric concentration of formaldehyde below the recommended exposure limits. Maintain adequate ventilation to prevent exposure above current OSHA / ACGIH exposure limits. Workplace monitoring of the air to define formaldehyde exposure levels may be necessary. In a two-year inhalation study, rats showed carcinogenic effects in the respiratory system at 15 ppm of formaldehyde. Section 12 - Ecological Information Ecological Information: Ecological injuries are not known or expected under normal use. Section 13 - Disposal Information Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. 00010011605 English Page 6 of 7 EPA Waste Code if Discarded (40 CFR Section 261): None Section 14 - Transportation Information DOT Proper Shipping Name: DOT Technical Name: DOT Hazard Class: Not Regulated Packing Group: N.A. N.A. N.A. Hazard Subclass: DOT UN/NA Number: N.A. N.A. Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may apply if shipped via other modes of transportation and/or to non-domestic destinations. Section 15 - Regulatory Information CERCLA - SARA Hazard Category: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Immediate Health Hazard, Chronic Health Hazard SARA Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: None Toxic Substances Control Act: All ingredients in this product are either on TSCA inventory list, or otherwise exempt. This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: None Canadian WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. Canadian WHMIS Class: Not Controlled. Section 16 - Other Information HMIS Ratings: Health: 1 Flammability: 1 Reactivity: 0 Volatile Organic Compounds (VOC), less water less exempts: g/L: Personal Protection: X 56.0 Volatile Organic Compounds (VOC), less water less exempts, less LVP -VOCs: lb/gal: 0.5 wt:wt%: 2.5 wt:wt%: 0.9 00010011605 English Page 7 of 7 REASON FOR REVISION: Periodic Update Legend: N.A. – Not Applicable ACGIH – American Conference of Governmental Industrial Hygienists N.E. – Not Established SARA – Superfund Amendments and Reauthorization Act of 1986 N.D. – Not Determined NJRTK – New Jersey Right-to-Know Law VOC – Volatile Organic Compound OSHA – Occupational Safety and Health Administration PEL – Permissible Exposure Limit HMIS – Hazardous Materials Identification System TLV – Threshold Limit Value NTP – National Toxicology Program CEIL – Ceiling Exposure Limit STEL – Short Term Exposure Limit LD50 – Lethal Dose 50 LC50 – Lethal Concentration 50 F – Degree Fahrenheit MSDS – Material Safety Data Sheet C – Degree Celsius CASRN – The Chemical Abstracts Service Registry Number DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context of the intended use and (ii) determine if they are appropriate. Page 1 of 6 Material Safety Data Sheet 24 Hour Emergency Phone Numbers: Medical: 1-800-327-3874 1-513-558-5111 Transportation: 1-800-535-5053 1-352-323-3500 NOTE: National Response Center emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals. IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16. Section 1 - Chemical Product / Company Information This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request. Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en español a su solicitud. Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere. Product Name: Product UPC Number: Product Use/Class: Manufacturer: CAULK BE GONE 7079818025 7079818026 7079818045 7079871000 Latex Caulk DAP Inc. 2400 Boston Street Suite 200 Baltimore, MD 21224-4723 888-327 -8477 (non-emergency matters) Revision Date: 12/21/2005 Supercedes: 12/09/1999 MSDS Number: 00077182001 Section 2 - Composition / Information On Ingredients Chemical Name Dimethyl glutarate Dimethyl succinate Dimethyl adipate Ethylene glycol Diethanolamine CASRN 1119 -40-0 106-65-0 627-93-0 107-21-1 111-42-2 WT% ACGIH TWA 10-30 5-10 3-7 0.5-1.5 0.1-1.0 N.E. N.E. N.E. N.E. 2 MGM3 ACGIH STEL N.E. N.E. N.E. N.E. N.E. ACGIH CEIL OSHA TWA OSHA STEL OSHA CEIL Skin N.E. N.E. N.E. 100 MGM3 N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. No No No No Yes Exposure Notes: Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary between states. Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work practices Section 3 - Hazards Identification Emergency Overview: A light green gel with a fruity odor. WARNING! Harmful if swallowed or absorbed through Page 2 of 6 the skin. May cause eye, skin, nose, throat and respiratory tract irritation. This product contains ethylene glycol. Refer to other MSDS sections for other detailed information. Effects Of Overexposure - Eye Contact: Causes eye irritation. Signs and symptoms may include: pain, tears, swelling, redness and blurred vision. Effects Of Overexposure - Skin Contact: Harmful if absorbed through the skin. Prolonged or repeated contact with skin may cause irritation. Effects Of Overexposure - Inhalation: Vapor harmful. May affect the brain or nervous system causing dizziness, headache or nausea. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes). May cause blurred vision. Effects Of Overexposure - Ingestion: Harmful or fatal if swallowed. Ingestion of dibasic esters can cause gastrointestinal irritation, nausea, vomiting, and diarrhea. Effects Of Overexposure - Chronic Hazards: NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Symptoms include: loss of memory, loss of intellectual ability and loss of coordination. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Prolonged and repeated skin contact may cause irritation and possibly dermatitis. Repeated or prolonged exposure may cause respiratory system damage. Overexposure may cause kidney, cardiovascular, skin and liver damage. Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Studies have shown that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals. Ethylene glycol has been shown to cause birth defects in laboratory animals. Prolonged, repeated, or high exposures may cause weakness and depression of the central nervous system. Dimethyladipate may increase the incidence of abnormal embryo development, based on a single suboptimally analyzed rat study. There are no human data. Primary Route(s) Of Entry: Skin Contact, Inhalation, Ingestion, Eye Contact Medical Conditions which May be Aggravated by Exposure: None known. Section 4 - First Aid Measures First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes until irritation subsides. Get medical attention immediately. First Aid - Skin Contact: Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical aid if symptoms persist. Remove and wash contaminated clothing. First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If continued breathing difficulty is experienced, get medical attention immediately. First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately. Note to Physician: None. COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arises from any of the above routes of entry. Section 5 - Fire Fighting Measures Page 3 of 6 Flash Point, F: Greater than 200 Method: ( Seta Closed Cup) Lower Explosive Limit, %: Not Established Upper Explosive Limit, %: Not Established Extinguishing Media: Alcohol, Carbon Dioxide, Dry Chemical, Foam, Water Fog Unusual Fire And Explosion Hazards: No special protective measures against fire required. Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent) and full protective gear. Use water spray to cool exposed surfaces. Section 6 - Accidental Release Measures Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use absorbent material or scrape up dried material and place in container. Section 7 - Handling And Storage Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Use only with adequate ventilation. Avoid breathing vapor and contact with eyes, skin and clothing. Wash thoroughly after handling. Avoid prolonged or repeated contact with skin. Open all windows and doors or use other means to ensure crossventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous conditions. Storage: Close container after each use. Store containers away from excessive heat and freezing. Do not store at temperatures above 120 degrees F. Store away from caustics and oxidizers. Section 8 - Exposure Controls / Personal Protection Precautionary Measures: Please refer to other sections and subsections of this MSDS. Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Ensure adequate ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient concentrations below recommended exposure limits. Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSHapproved air purifying respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where airborne concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Skin Protection: Rubber gloves. Eye Protection: Goggles or safety glasses with side shields. Other protective equipment: Not required under normal use. Hygienic Practices: Remove and wash contaminated clothing before re-use. Wash hands before breaks and at the end of workday. Section 9 - Physical And Chemical Properties Page 4 of 6 Boiling Range: Odor: Appearance: Solubility in H2O: Freeze Point: Vapor Pressure: Physical State: 212 - 417 F Fruity Light green Not Established Not Established Not Established Gel Vapor Density: Odor Threshold: Evaporation Rate: Specific Gravity: pH: Viscosity: Not Established Not Established Slower Than n-Butyl Acetate 1.037 Not Established Not Established When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally. (See section 16 for abbreviation legend) Section 10 - Stability And Reactivity Conditions To Avoid: Excessive heat and freezing. Incompatibility: Incompatible with strong bases and oxidizing agents. Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx. Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions. Stability: Stable under recommended storage conditions. Section 11 - Toxicological Information Product LD50: Not Established CASRN Chemical Name 106-65-0 107-21-1 111-42-2 Product LC50: Not Established LD50 LC50 Dimethyl succinate Ethylene glycol Diethanolamine Oral Rat:>5 gm/kg Rat:4700 mg/kg Oral Rat:620 uL/kg ------------Rat:10876 mg/kg ------------- WT% 5-10 0.5-1.5 0.1-1.0 Carcinogenicity: CAS No. 111-42-2 Chemical Name Diethanolamine ACGIH ----- OSHA IARC NTP WT% ----- Classification not possible from current data. ----- 0.1-1.0 Significant Data with Possible Relevance to Humans: None Section 12 - Ecological Information Ecological Information: Ecological injuries are not known or expected under normal use. Section 13 - Disposal Information Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA Waste Code if Discarded (40 CFR Section 261): None Page 5 of 6 Section 14 - Transportation Information DOT Proper Shipping Name: DOT Technical Name: DOT Hazard Class: Not Regulated Packing Group: N.A. N.A. N.A. Hazard Subclass: DOT UN/NA Number: N.A. N.A. Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may apply if shipped via other modes of transportation and/or to non-domestic destinations. Section 15 - Regulatory Information CERCLA - SARA Hazard Category: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Immediate Health Hazard, Chronic Health Hazard SARA Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: None Toxic Substances Control Act: All ingredients in this product are either on TSCA inventory list, or otherwise exempt. This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: None U.S. State Regulations New Jersey Right-to-Know: The following materials are non-hazardous, but are among the top five components in this product: Chemical Name Water CAS Number 7732 -18-5 WT% 40-70 Pennsylvania Right-to-Know: The following non-hazardous ingredients are present in the product at greater than 3%: Chemical Name Water CAS Number 7732 -18-5 WT% 40-70 Page 6 of 6 California Proposition 65: Warning: The following ingredients present in the product are known to the State of California to cause cancer: None. Warning: The following ingredients present in the product are known to the State of California to cause birth defects or other reproductive harm: None. Section 16 - Other Information HMIS Ratings: Health: 2 Flammability: 1 Reactivity: 0 VOLATILE ORGANIC COMPOUNDS, GR/LTR: 999.8 LB/GAL: 8.3 Personal Protection: X WT%: 34.525 REASON FOR REVISION: Periodic Update Legend: N.A. – Not Applicable ACGIH – American Conference of Governmental Industrial Hygienists N.E. – Not Established SARA – Superfund Amendments and Reauthorization Act of 1986 N.D. – Not Determined NJRTK – New Jersey Right-to-Know Law VOC – Volatile Organic Compound OSHA – Occupational Safety and Health Administration PEL – Permissible Exposure Limit HMIS – Hazardous Materials Identification System TLV – Threshold Limit Value NTP – National Toxicology Program STEL – Short Term Exposure Limit CEIL – Ceiling Exposure Limit LD50 – Lethal Dose 50 LC50 – Lethal Concentration 50 F – Degree Fahrenheit C – Degree Celsius MSDS – Material Safety Data Sheet CASRN – The Chemical Abstracts Service Registry Number DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context of the intended use and (ii) determine if they are appropriate. [Du-Lite Home] | [Product Profiles] | [MSDS] | [Product Info Request] Du-Lite® Quick Response Email MATERIAL SAFETY DATA SHEET KWIKSEAL ==================================================================================== SECTION I - IDENTIFICATION ==================================================================================== NFPA PROTECTION ........ X TRANSPORTATION EMERGENCY: NFPA HEALTH ............ 0 CHEM-TEL 1-800-255-3924 NFPA FLAMMABILITY ...... 2 INFORMATION: 860-347-2505 NFPA REACTIVITY ........ 0 DU-LITE CORPORATION 171 RIVER ROAD MIDDLETOWN, CT 06457 PREPARED BY: WALTER J. SMITH DATE: 4/01/04 PRODUCT NAME .........KWIKSEAL DESCRIPTION ..........Rust Preventative Oil DOT DESCRIP.: COMBUSTIBLE LIQUID, N.O.S., (CONTAINS MINERAL SPIRITS) NA-1993, PG-III DOT LABEL: (No DOT label required) DOT PLACARD: Combustible or Flammable ==================================================================================== SECTION II - HAZARDOUS INGREDIENTS ==================================================================================== HAZARDOUS COMPONENT CAS NUMBER TLV(MG/M3) PEL(MG/M3) PERCENT LOW AROMATIC HYDROCARBON SOLVENT 8032-32-4 100 PPM REC. <77-87 NON-HAZARDOUS N/A N/A N/A <13-23 __________________________________________________________________________ N/E = NOT ESTABLISHED N/A = NOT APPLICABLE N/D = NOT DETERMINED ==================================================================================== SECTION III - PHYSICAL DATA ==================================================================================== BOILING POINT(°F).........300°F SPECIFIC GRAVITY (H20=1)... 0.815 VAPOR PRESSURE (mm Hg)....1 @ 100°F MELTING POINT.............. N/A VAPOR DENSITY (Air=1)....5.1 EVAPORATION RATE........... <0.1 SOLUBILITY IN H20.........Negligible PH.................Neutral APPEARANCE/ODOR....Clear, dark, low viscosity liquid - slight hydrocarbon odor. ==================================================================================== SECTION IV - REACTIVITY DATA ==================================================================================== CHEMICAL STABILITY: Stable CONDITIONS TO AVOID: Open flame or excessive heat. INCOMPATIBLE MATERIALS: Strong oxidizers. DECOMPOSITION PRODUCTS: Fumes, smoke, carbon monoxide, carbon dioxide and organic compounds. HAZARDOUS POLYMERIZATION: Will not occur. ==================================================================================== SECTION V - FIRE AND EXPLOSION HAZARD DATA ==================================================================================== FLASH POINT................112°F PMCC FLAMMABLE LIMITS..LEL-0.9% VEL-7% AUTOIGNITION TEMP..........490°F IN CASE OF FIRE: Material is flammable petroleum liquid. Use extinguishing carbon dioxide, foam or dry chemical media. SPECIAL FIREFIGHTING PROCEDURES: Wear protective clothing with self-contained breathing apparatus. UNUSUAL FIRE HAZARDS: Petroleum liquid. Product will float and spread on water. ==================================================================================== SECTION VI - HEALTH HAZARD DATA ==================================================================================== ROUTES OF ENTRY: Eye contact, skin contact, inhalation, ingestion. HEALTH HAZARDS (ACUTE, CHRONIC): Skin - repeated or prolonged contact may cause dermatitis or loss of skin oils. Eyes - Contact may cause mild irritation. Inhalation - Mildly irritating in high concentrations. Ingestion - Low oral toxicity. CARCINOGENICITY: None. NTP?: No. IARC?: No. OSHA REGULATED?: No. FIRST AID: INHALATION: Move victim to fresh air. If not breathing, use artificial respiration. If breathing is difficult, give oxygen. Seek medical attention. EYES: Flush well with water. SKIN: Wash well with soap and water. Remove contaminated clothing and launder. Seek medical attention if irritation occurs. INGESTION: Low oral toxicity. Do notinduce vomiting. ==================================================================================== SECTION VII - PRECAUTIONS/PROCEDURES ==================================================================================== IN CASE OF SPILL: Contain and collect free liquid. Contain spills with absorbent such as sand or clay. WASTE DISPOSAL METHOD: Dispose of in accordance with local, state and federal EPA regulations. Treat waste as an oil product. PRECAUTIONS: Wear proper protective clothing when using this product. Use with adequate ventilation. Wash thoroughly after handling. Store away from excessive heat or open flame. This is an oil product. Do not allow spills to enter waterways or drainage system. If spill enters waterway and causes sheen, report to National Response Center at 800-424-8602. OTHER PRECAUTIONS: Emptied containers of this product may contain hazardous vapors and residue. Clean thoroughly before reusing or discarding. Do not use a welding torch to cut container. Do not use for water or food storage. ==================================================================================== SECTION VIII - SPECIAL PROTECTION ==================================================================================== RESPIRATORY PROTECTION: Use NIOSH approved respirator if vapors are excessive. VENTILATION: Maintain below TLV. MECHANICAL EXHAUST...X PROTECTIVE GLOVES: Rubber. LOCAL EXHAUST........X EYE PROTECTION: Safety goggles, face shield. OTHER PROTECTIVE EQUIPMENT... Apron, boots, full cover work clothes. WORK/HYGIENIC PRACTICES...... Wash thoroughly after handling, launder clothes. ==================================================================================== SECTION IX - SARA TITLE III INFORMATION ==================================================================================== HAZARDOUS CERCLA SECT 302 SECT 313 SECT 311/312 COMPONENT RQ LBS. TPQ LBS. TOXIC HAZARDS Low Aromatic N/A N/A N/A A,C Hydrocarbon Solvent A=IMMEDIATE (ACUTE HEALTH HAZARD) B=DELAYED (CHRONIC) HEALTH HAZARD C=FIRE HAZARD D= SUDDEN RELEASE OF PRESSURE HAZARD E=REACTIVE HAZARD 00010009605 English Page 1 of 7 Material Safety Data Sheet 24 Hour Emergency Phone Numbers: Medical/Poison Control: In U.S.: Call 1-800-222-1222 Outside U.S.: Call your local poison control center Transportation/National Response Center: 1-800-535-5053 1-352-323-3500 NOTE: The National Response Center emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals. IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16. Section 1 - Chemical Product / Company Information This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request. On peut demader cette fiche signalétique (MSDS) a la langue francaise-canadienne. Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere. Product Name: Product UPC Number: Product Use/Class: Manufacturer: Kwik Seal Tub & Tile Adhesive Caulk - All Colors 070798710504, 070798710207, 070798710238 Latex Caulk Revision Date: Supercedes: 05/21/2008 MSDS Number: 00010009605 04/27/2005 DAP Canada 475 Finchdene Square Unit 5 Scarborough, Ontario M1X 1B7 888-327 -8477 (non-emergency) Section 2 - Hazards Identification Emergency Overview: A colored paste product with a very slight ammonia odor. WARNING! May cause eye, skin, nose, throat and respiratory tract irritation. May cause eye or skin irritation. Harmful if swallowed or absorbed through the skin. This product contains ethylene glycol. Refer to other MSDS sections for other detailed information. Effects Of Overexposure - Eye Contact: May cause eye irritation. Effects Of Overexposure - Skin Contact: May cause skin irritation. Harmful if absorbed through the skin. Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation of high concentrations may cause headache, nausea, and dizziness. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes). Inhalation may cause mild irritation to the respiratory tract (nose, mouth, mucous membranes). Effects Of Overexposure - Ingestion: Ingestion of ethylene glycol can cause gastrointestinal irritation, nausea, vomiting, diarrhea and if ingested in sufficient quantities, death. Harmful or fatal if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. If ingested, may cause vomiting, diarrhea, and depressed respiration. Ingestion may result in obstruction when material hardens. Effects Of Overexposure - Chronic Hazards: Repeated or prolonged exposure may cause skin, respiratory, kidney and 00010009605 English Page 2 of 7 liver damage. Prolonged and repeated skin contact may cause irritation and possibly dermatitis. The International Agency for Research on Cancer (IARC) has determined that crystalline silica in the form of quartz or cristobalite that is inhaled from occupational sources is carcinogenic to humans (Group 1- carcinogenic to humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (published in June 1997) in conjunction with the use of these materials. The National Toxicology Program (NTP) classifies respirable crystalline silica as "known to be a human carcinogen". Refer to the 9th Report on Carcinogens (2000). The American Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (Group A2). Breathing dust containing respirable crystalline silica may not cause noticeable injury or illness even though permanent lung damage may be occurring. Inhalation of dust may have the following serious chronic health effects: Excessive inhalation of respirable dust can cause pneumoconiosis, a respiratory disease, which can result in delayed, progressive, disabling and sometimes fatal lung injury. Symptoms include cough, shortness of breath, wheezing, non-specific chest illness and reduced pulmonary function. Smoking exacerbates this disease. Individuals with pneumoconiosis are predisposed to develop tuberculosis. There is some evidence that breathing respirable crystalline silica or the disease silicosis is associated with an increased incidence of significant disease endpoints such as scleroderma (an immune system disorder manifested by fibrosis of the lungs, skin and other internal organs) and kidney disease. Prolonged, repeated, or high exposures may cause weakness and depression of the central nervous system. Formaldehyde vapor is a known animal carcinogen according to OSHA and NTP and is considered possibly carcinogenic to humans by inhalation. The International Agency for Research on Cancer considers formaldehyde to be a human carcinogen. A mixture of diisodecyl phthalate and diisononyl phthalate has been tested in a two-generation toxicity study in laboratory animals. No effects on reproductive parameters were seen. However, a small but statistically significant increase in early offspring mortality was seen at high oral doses. The significance of this to humans is uncertain. The mixture of phthalate esters contained within this product has been shown to cause developmental effects at high doses in laboratory animals when administered orally by gavage in a developmental study and developmental and fertility effects when administered at high doses by feed in a two-generation reproduction study. The potential risk from occupational and consumer exposure is considered to be very low, based on limited relevance of the rodent findings to humans and the large safety margins between exposure and the effect levels. Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Studies have shown that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals. Ethylene glycol has been shown to cause birth defects in laboratory animals. Primary Route(s) Of Entry: Skin Contact, Inhalation, Eye Contact Medical Conditions which May be Aggravated by Exposure: None known. Carcinogenicity: CAS No. Chemical Name 13463-67-7 Titanium dioxide 14808-60-7 Silica, crystalline 50-00-0 Formaldehyde ACGIH OSHA IARC NTP Not Listed. Suspected human carcinogen. Suspected human carcinogen. Not Listed. Possible carcinogen. Not Listed. Not Listed. Human carcinogen. Known carcinogen. Potential cancer hazard. Human carcinogen. Anticipated carcinogen. Section 3 - Composition / Information On Ingredients Chemical Name Limestone Branched and linear phthalates Titanium dioxide n-Butyl acetate Silica, crystalline Ethylene glycol Formaldehyde CASRN 1317-65-3 Proprietary 13463-67 -7 123-86-4 14808-60 -7 107-21-1 50-00 -0 Wt% 30 -60 1-5 0.1-1.0 0.1-1.0 0.1-1.0 0.1-1.0 <0.02 00010009605 English Page 3 of 7 Section 4 - First Aid Measures First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes until irritation subsides. Get medical attention immediately. First Aid - Skin Contact: Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical aid if symptoms persist. If skin irritation persists, call a physician. Remove and wash contaminated clothing. In case of contact, immediately flush skin with plenty of water while removing contaminated clothing and shoes. First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If continued breathing difficulty is experienced, get medical attention immediately. First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately. If ingested, drink 2 glasses of water. Immediately see a physician. Never give anything by mouth to an unconscious person. Note to Physician: None. COMMENTS: If over-exposure occurs, call your local poison control center. Section 5 - Fire Fighting Measures Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog Unusual Fire And Explosion Hazards: No special protective measures against fire required. Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent) and full protective gear. Use water spray to cool exposed surfaces. Section 6 - Accidental Release Measures Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use absorbent material or scrape up dried material and place in container. Section 7 - Handling And Storage Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Avoid breathing vapor and contact with eyes, skin and clothing. Use only with adequate ventilation. Open all windows and doors or use other means to ensure cross-ventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous conditions. Wash thoroughly after handling. Storage: Do not store at temperatures above 120 degrees F. Store containers away from excessive heat and freezing. Close container after each use. Store away from caustics and oxidizers. Section 8 - Exposure Controls / Personal Protection Chemical Name CASRN ACGIH TWA ACGIH STEL ACGIH CEIL Limestone 1317-65-3 10 MGM3 N.E. N.E. Branched and linear phthalates Titanium dioxide n-Butyl acetate Proprietary 13463-67-7 123-86-4 N.E. 10 MGM3 150 PPM N.E. N.E. 200 PPM N.E. N.E. N.E. Silica, crystalline 14808-60-7 0.025 MGM. N.E. N.E. Ethylene glycol Formaldehyde 107-21-1 50-00-0 N.E. N.E. N.E. N.E. 100 MGM3 0.3 PPM OSHA TWA 5 MGM3 (respirable fraction) N.E. 15 MGM3 150 PPM 10/(%SiO2 + 2) MGM3 N.E. 0.75 PPM OSHA STEL OSHA CEIL Skin N.E. N.E. No N.E. N.E. N.E. N.E. N.E. N.E. No No No N.E. N.E. No N.E. 2 PPM N.E. N.E. No No 00010009605 English Page 4 of 7 Exposure Notes: 14808-60-7 The 2002 ACGIH Threshold Limit Values for Chemical Substances and Physical Agents lists the median Respirable Particulate Mass (RPM) point for crystalline silica at 4.0 microns in terms of the particle's aerodynamic diameter. The TLVs for crystalline silica represent the respirable fraction. OSHA PEL TWA for Quartz is calculated using the following formula: 10 mg/m3/(% SiO2 + 2). Both concentration and percent quartz for the application of this limit are to be determined from the fraction passing a size selector with the following characteristics. |------------------------------------------------------------------------------------ |-----------------------------------------| | ....... Aerodynamic diameter ( unit density sphere ) .....| Percent passing selector | | 2 ................................................................................|.................90....................| | 2.5 .............................................................................|..................75...................| | 3.5 .............................................................................|..................50...................| | 5.0 .............................................................................|..................25...................| | 10 ..............................................................................|...................0....................| 50-00-0 Formaldehyde is a specially regulated substance for which an OSHA chemical-specific exposure standard exits. Detailed information regarding this substance may be found in 29 CFR 1910.1048. Medical surveillance information regarding this substance may be found in Appendix C to 29 CFR 1910.1048. Precautionary Measures: Contact lenses pose a special hazard; soft lenses may absorb and all lenses concentrate irritants. Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Ensure adequate ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient concentrations below recommended exposure limits. Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSH-approved air purifying respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where airborne concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. National Institute for Occupational Safety and Health (NIOSH) has recommended that the permissible exposure limit be changed to 50 micrograms respirable free silica per cubic meter of air (0.05 mg/m3) as determined by a full shift sample up to 10-hour work shift. Skin Protection: Rubber gloves. Natural rubber, butyl rubber and polyvinyl chloride gloves are not suitable protection against the phthalates contained within this product; neoprene is recommended. Eye Protection: Goggles or safety glasses with side shields. Other protective equipment: Not required under normal use. Hygienic Practices: Wash hands before breaks and at the end of workday. Remove and wash contaminated clothing before re-use. Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary between states. Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work practices. Section 9 - Physical And Chemical Properties Boiling Range: Odor: 210 - 220 F Very Slight Ammonia Vapor Density: Odor Threshold: Heavier Than Air Not Established 00010009605 English Color: Solubility in H2O: Freeze Point: Vapor Pressure: Physical State: Flash Point, F: Lower Explosive Limit, %: Page 5 of 7 Colored Not Established Not Established Not Established Paste > 200 F Not Established Evaporation Rate: Slower Than n-Butyl Acetate Specific Gravity: 1.6 pH: Between 7.0 and 12.0 Viscosity: Not Established Flammability: Non-Flammable Method: (Seta Closed Cup) Upper Explosive Limit, %:Not Established When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally. (See section 16 for abbreviation legend) Section 10 - Stability And Reactivity Conditions To Avoid: Excessive heat and freezing. Incompatibility: Incompatible with strong bases and oxidizing agents. Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx. Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions. Stability: Stable under recommended storage conditions. Section 11 - Toxicological Information Product LD50: Not Established CASRN 123-86-4 107-21-1 50-00-0 Chemical Name n-Butyl acetate Ethylene glycol Formaldehyde Product LC50: Not Established LD50 Rat:10768 MG/KG Rat:4700 mg/kg ------------- LC50 Rat:2000 P Rat:10876 mg/kg Rat:203 mg/m3 Significant Data with Possible Relevance to Humans: This product contains trace amounts of free formaldehyde. OSHA and NTP identify formaldehyde as a potential carcinogen. IARC identifies formaldehyde as a human carcinogen. Formaldehyde has been shown to cause mutations in a variety of in-vitro test systems, the significance of which to humans is unknown. There should be minimal risk when used with ventilation adequate to keep the atmospheric concentration of formaldehyde below the recommended exposure limits. Maintain adequate ventilation to prevent exposure above current OSHA / ACGIH exposure limits. Workplace monitoring of the air to define formaldehyde exposure levels may be necessary. In a two-year inhalation study, rats showed carcinogenic effects in the respiratory system at 15 ppm of formaldehyde. Section 12 - Ecological Information Ecological Information: Ecological injuries are not known or expected under normal use. Section 13 - Disposal Information Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA Waste Code if Discarded (40 CFR Section 261): This product does not meet the definition of a hazardous waste according to U.S. EPA Hazardous Waste Management Regulation, 40 CFR Section 261. Section 14 - Transportation Information 00010009605 English DOT Proper Shipping Name: DOT Technical Name: DOT Hazard Class: Page 6 of 7 Not Regulated Packing Group: N.A. N.A. N.A. Hazard Subclass: DOT UN/NA Number: N.A. None Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may apply if shipped via other modes of transportation and/or to non-domestic destinations. Section 15 - Regulatory Information CERCLA - SARA Hazard Category: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Immediate Health Hazard, Chronic Health Hazard SARA Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: None Toxic Substances Control Act: All ingredients in this product are either on TSCA inventory list, or otherwise exempt. This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: Chemical Name CAS Number Mercury & compounds 7439-97-6 Canadian WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. Canadian WHMIS Class: Not Controlled. Section 16 - Other Information HMIS Ratings: Health: 1 Flammability: 1 Reactivity: 0 Volatile Organic Compounds (VOC), less water less exempts: g/L: Personal Protection: X 25.4 Volatile Organic Compounds (VOC), less water less exempts, less LVP -VOCs: lb/gal: 0.2 wt:wt%: 1.1 wt:wt%: 0.6 REASON FOR REVISION: Periodic Update Legend: N.A. – Not Applicable ACGIH – American Conference of Governmental Industrial Hygienists 00010009605 English Page 7 of 7 N.E. – Not Established SARA – Superfund Amendments and Reauthorization Act of 1986 N.D. – Not Determined NJRTK – New Jersey Right-to-Know Law VOC – Volatile Organic Compound OSHA – Occupational Safety and Health Administration PEL – Permissible Exposure Limit HMIS – Hazardous Materials Identification System TLV – Threshold Limit Value NTP – National Toxicology Program CEIL – Ceiling Exposure Limit STEL – Short Term Exposure Limit LD50 – Lethal Dose 50 LC50 – Lethal Concentration 50 F – Degree Fahrenheit MSDS – Material Safety Data Sheet C – Degree Celsius CASRN – The Chemical Abstracts Service Registry Number DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context of the intended use and (ii) determine if they are appropriate. 00010009605 English Page 1 of 7 Material Safety Data Sheet 24 Hour Emergency Phone Numbers: Medical/Poison Control: In U.S.: Call 1-800-222-1222 Outside U.S.: Call your local poison control center Transportation/National Response Center: 1-800-535-5053 1-352-323-3500 NOTE: The National Response Center emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals. IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16. Section 1 - Chemical Product / Company Information This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request. On peut demader cette fiche signalétique (MSDS) a la langue francaise-canadienne. Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere. Product Name: Product UPC Number: Product Use/Class: Manufacturer: Kwik Seal Tub & Tile Adhesive Caulk - All Colors 070798710504, 070798710207, 070798710238 Latex Caulk Revision Date: Supercedes: 05/21/2008 MSDS Number: 00010009605 04/27/2005 DAP Canada 475 Finchdene Square Unit 5 Scarborough, Ontario M1X 1B7 888-327 -8477 (non-emergency) Section 2 - Hazards Identification Emergency Overview: A colored paste product with a very slight ammonia odor. WARNING! May cause eye, skin, nose, throat and respiratory tract irritation. May cause eye or skin irritation. Harmful if swallowed or absorbed through the skin. This product contains ethylene glycol. Refer to other MSDS sections for other detailed information. Effects Of Overexposure - Eye Contact: May cause eye irritation. Effects Of Overexposure - Skin Contact: May cause skin irritation. Harmful if absorbed through the skin. Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation of high concentrations may cause headache, nausea, and dizziness. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes). Inhalation may cause mild irritation to the respiratory tract (nose, mouth, mucous membranes). Effects Of Overexposure - Ingestion: Ingestion of ethylene glycol can cause gastrointestinal irritation, nausea, vomiting, diarrhea and if ingested in sufficient quantities, death. Harmful or fatal if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. If ingested, may cause vomiting, diarrhea, and depressed respiration. Ingestion may result in obstruction when material hardens. Effects Of Overexposure - Chronic Hazards: Repeated or prolonged exposure may cause skin, respiratory, kidney and 00010009605 English Page 2 of 7 liver damage. Prolonged and repeated skin contact may cause irritation and possibly dermatitis. The International Agency for Research on Cancer (IARC) has determined that crystalline silica in the form of quartz or cristobalite that is inhaled from occupational sources is carcinogenic to humans (Group 1- carcinogenic to humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (published in June 1997) in conjunction with the use of these materials. The National Toxicology Program (NTP) classifies respirable crystalline silica as "known to be a human carcinogen". Refer to the 9th Report on Carcinogens (2000). The American Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (Group A2). Breathing dust containing respirable crystalline silica may not cause noticeable injury or illness even though permanent lung damage may be occurring. Inhalation of dust may have the following serious chronic health effects: Excessive inhalation of respirable dust can cause pneumoconiosis, a respiratory disease, which can result in delayed, progressive, disabling and sometimes fatal lung injury. Symptoms include cough, shortness of breath, wheezing, non-specific chest illness and reduced pulmonary function. Smoking exacerbates this disease. Individuals with pneumoconiosis are predisposed to develop tuberculosis. There is some evidence that breathing respirable crystalline silica or the disease silicosis is associated with an increased incidence of significant disease endpoints such as scleroderma (an immune system disorder manifested by fibrosis of the lungs, skin and other internal organs) and kidney disease. Prolonged, repeated, or high exposures may cause weakness and depression of the central nervous system. Formaldehyde vapor is a known animal carcinogen according to OSHA and NTP and is considered possibly carcinogenic to humans by inhalation. The International Agency for Research on Cancer considers formaldehyde to be a human carcinogen. A mixture of diisodecyl phthalate and diisononyl phthalate has been tested in a two-generation toxicity study in laboratory animals. No effects on reproductive parameters were seen. However, a small but statistically significant increase in early offspring mortality was seen at high oral doses. The significance of this to humans is uncertain. The mixture of phthalate esters contained within this product has been shown to cause developmental effects at high doses in laboratory animals when administered orally by gavage in a developmental study and developmental and fertility effects when administered at high doses by feed in a two-generation reproduction study. The potential risk from occupational and consumer exposure is considered to be very low, based on limited relevance of the rodent findings to humans and the large safety margins between exposure and the effect levels. Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Studies have shown that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals. Ethylene glycol has been shown to cause birth defects in laboratory animals. Primary Route(s) Of Entry: Skin Contact, Inhalation, Eye Contact Medical Conditions which May be Aggravated by Exposure: None known. Carcinogenicity: CAS No. Chemical Name 13463-67-7 Titanium dioxide 14808-60-7 Silica, crystalline 50-00-0 Formaldehyde ACGIH OSHA IARC NTP Not Listed. Suspected human carcinogen. Suspected human carcinogen. Not Listed. Possible carcinogen. Not Listed. Not Listed. Human carcinogen. Known carcinogen. Potential cancer hazard. Human carcinogen. Anticipated carcinogen. Section 3 - Composition / Information On Ingredients Chemical Name Limestone Branched and linear phthalates Titanium dioxide n-Butyl acetate Silica, crystalline Ethylene glycol Formaldehyde CASRN 1317-65-3 Proprietary 13463-67 -7 123-86-4 14808-60 -7 107-21-1 50-00 -0 Wt% 30 -60 1-5 0.1-1.0 0.1-1.0 0.1-1.0 0.1-1.0 <0.02 00010009605 English Page 3 of 7 Section 4 - First Aid Measures First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes until irritation subsides. Get medical attention immediately. First Aid - Skin Contact: Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical aid if symptoms persist. If skin irritation persists, call a physician. Remove and wash contaminated clothing. In case of contact, immediately flush skin with plenty of water while removing contaminated clothing and shoes. First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If continued breathing difficulty is experienced, get medical attention immediately. First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately. If ingested, drink 2 glasses of water. Immediately see a physician. Never give anything by mouth to an unconscious person. Note to Physician: None. COMMENTS: If over-exposure occurs, call your local poison control center. Section 5 - Fire Fighting Measures Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog Unusual Fire And Explosion Hazards: No special protective measures against fire required. Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent) and full protective gear. Use water spray to cool exposed surfaces. Section 6 - Accidental Release Measures Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use absorbent material or scrape up dried material and place in container. Section 7 - Handling And Storage Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Avoid breathing vapor and contact with eyes, skin and clothing. Use only with adequate ventilation. Open all windows and doors or use other means to ensure cross-ventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous conditions. Wash thoroughly after handling. Storage: Do not store at temperatures above 120 degrees F. Store containers away from excessive heat and freezing. Close container after each use. Store away from caustics and oxidizers. Section 8 - Exposure Controls / Personal Protection Chemical Name CASRN ACGIH TWA ACGIH STEL ACGIH CEIL Limestone 1317-65-3 10 MGM3 N.E. N.E. Branched and linear phthalates Titanium dioxide n-Butyl acetate Proprietary 13463-67-7 123-86-4 N.E. 10 MGM3 150 PPM N.E. N.E. 200 PPM N.E. N.E. N.E. Silica, crystalline 14808-60-7 0.025 MGM. N.E. N.E. Ethylene glycol Formaldehyde 107-21-1 50-00-0 N.E. N.E. N.E. N.E. 100 MGM3 0.3 PPM OSHA TWA 5 MGM3 (respirable fraction) N.E. 15 MGM3 150 PPM 10/(%SiO2 + 2) MGM3 N.E. 0.75 PPM OSHA STEL OSHA CEIL Skin N.E. N.E. No N.E. N.E. N.E. N.E. N.E. N.E. No No No N.E. N.E. No N.E. 2 PPM N.E. N.E. No No 00010009605 English Page 4 of 7 Exposure Notes: 14808-60-7 The 2002 ACGIH Threshold Limit Values for Chemical Substances and Physical Agents lists the median Respirable Particulate Mass (RPM) point for crystalline silica at 4.0 microns in terms of the particle's aerodynamic diameter. The TLVs for crystalline silica represent the respirable fraction. OSHA PEL TWA for Quartz is calculated using the following formula: 10 mg/m3/(% SiO2 + 2). Both concentration and percent quartz for the application of this limit are to be determined from the fraction passing a size selector with the following characteristics. |------------------------------------------------------------------------------------ |-----------------------------------------| | ....... Aerodynamic diameter ( unit density sphere ) .....| Percent passing selector | | 2 ................................................................................|.................90....................| | 2.5 .............................................................................|..................75...................| | 3.5 .............................................................................|..................50...................| | 5.0 .............................................................................|..................25...................| | 10 ..............................................................................|...................0....................| 50-00-0 Formaldehyde is a specially regulated substance for which an OSHA chemical-specific exposure standard exits. Detailed information regarding this substance may be found in 29 CFR 1910.1048. Medical surveillance information regarding this substance may be found in Appendix C to 29 CFR 1910.1048. Precautionary Measures: Contact lenses pose a special hazard; soft lenses may absorb and all lenses concentrate irritants. Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Ensure adequate ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient concentrations below recommended exposure limits. Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSH-approved air purifying respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where airborne concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. National Institute for Occupational Safety and Health (NIOSH) has recommended that the permissible exposure limit be changed to 50 micrograms respirable free silica per cubic meter of air (0.05 mg/m3) as determined by a full shift sample up to 10-hour work shift. Skin Protection: Rubber gloves. Natural rubber, butyl rubber and polyvinyl chloride gloves are not suitable protection against the phthalates contained within this product; neoprene is recommended. Eye Protection: Goggles or safety glasses with side shields. Other protective equipment: Not required under normal use. Hygienic Practices: Wash hands before breaks and at the end of workday. Remove and wash contaminated clothing before re-use. Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary between states. Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work practices. Section 9 - Physical And Chemical Properties Boiling Range: Odor: 210 - 220 F Very Slight Ammonia Vapor Density: Odor Threshold: Heavier Than Air Not Established 00010009605 English Color: Solubility in H2O: Freeze Point: Vapor Pressure: Physical State: Flash Point, F: Lower Explosive Limit, %: Page 5 of 7 Colored Not Established Not Established Not Established Paste > 200 F Not Established Evaporation Rate: Slower Than n-Butyl Acetate Specific Gravity: 1.6 pH: Between 7.0 and 12.0 Viscosity: Not Established Flammability: Non-Flammable Method: (Seta Closed Cup) Upper Explosive Limit, %:Not Established When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally. (See section 16 for abbreviation legend) Section 10 - Stability And Reactivity Conditions To Avoid: Excessive heat and freezing. Incompatibility: Incompatible with strong bases and oxidizing agents. Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx. Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions. Stability: Stable under recommended storage conditions. Section 11 - Toxicological Information Product LD50: Not Established CASRN 123-86-4 107-21-1 50-00-0 Chemical Name n-Butyl acetate Ethylene glycol Formaldehyde Product LC50: Not Established LD50 Rat:10768 MG/KG Rat:4700 mg/kg ------------- LC50 Rat:2000 P Rat:10876 mg/kg Rat:203 mg/m3 Significant Data with Possible Relevance to Humans: This product contains trace amounts of free formaldehyde. OSHA and NTP identify formaldehyde as a potential carcinogen. IARC identifies formaldehyde as a human carcinogen. Formaldehyde has been shown to cause mutations in a variety of in-vitro test systems, the significance of which to humans is unknown. There should be minimal risk when used with ventilation adequate to keep the atmospheric concentration of formaldehyde below the recommended exposure limits. Maintain adequate ventilation to prevent exposure above current OSHA / ACGIH exposure limits. Workplace monitoring of the air to define formaldehyde exposure levels may be necessary. In a two-year inhalation study, rats showed carcinogenic effects in the respiratory system at 15 ppm of formaldehyde. Section 12 - Ecological Information Ecological Information: Ecological injuries are not known or expected under normal use. Section 13 - Disposal Information Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA Waste Code if Discarded (40 CFR Section 261): This product does not meet the definition of a hazardous waste according to U.S. EPA Hazardous Waste Management Regulation, 40 CFR Section 261. Section 14 - Transportation Information 00010009605 English DOT Proper Shipping Name: DOT Technical Name: DOT Hazard Class: Page 6 of 7 Not Regulated Packing Group: N.A. N.A. N.A. Hazard Subclass: DOT UN/NA Number: N.A. None Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may apply if shipped via other modes of transportation and/or to non-domestic destinations. Section 15 - Regulatory Information CERCLA - SARA Hazard Category: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Immediate Health Hazard, Chronic Health Hazard SARA Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: None Toxic Substances Control Act: All ingredients in this product are either on TSCA inventory list, or otherwise exempt. This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: Chemical Name CAS Number Mercury & compounds 7439-97-6 Canadian WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. Canadian WHMIS Class: Not Controlled. Section 16 - Other Information HMIS Ratings: Health: 1 Flammability: 1 Reactivity: 0 Volatile Organic Compounds (VOC), less water less exempts: g/L: Personal Protection: X 25.4 Volatile Organic Compounds (VOC), less water less exempts, less LVP -VOCs: lb/gal: 0.2 wt:wt%: 1.1 wt:wt%: 0.6 REASON FOR REVISION: Periodic Update Legend: N.A. – Not Applicable ACGIH – American Conference of Governmental Industrial Hygienists 00010009605 English Page 7 of 7 N.E. – Not Established SARA – Superfund Amendments and Reauthorization Act of 1986 N.D. – Not Determined NJRTK – New Jersey Right-to-Know Law VOC – Volatile Organic Compound OSHA – Occupational Safety and Health Administration PEL – Permissible Exposure Limit HMIS – Hazardous Materials Identification System TLV – Threshold Limit Value NTP – National Toxicology Program CEIL – Ceiling Exposure Limit STEL – Short Term Exposure Limit LD50 – Lethal Dose 50 LC50 – Lethal Concentration 50 F – Degree Fahrenheit MSDS – Material Safety Data Sheet C – Degree Celsius CASRN – The Chemical Abstracts Service Registry Number DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context of the intended use and (ii) determine if they are appropriate. 00010002605 English Page 1 of 7 Material Safety Data Sheet 24 Hour Emergency Phone Numbers: Medical/Poison Control: In U.S.: Call 1-800-222-1222 Outside U.S.: Call your local poison control center Transportation/National Response Center: 1-800-535-5053 1-352-323-3500 NOTE: The National Response Center emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals. IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16. Section 1 - Chemical Product / Company Information This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request. On peut demader cette fiche signalétique (MSDS) a la langue francaise-canadienne. Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere. Product Name: Product UPC Number: Product Use/Class: Manufacturer: Alex Plus Acrylic Latex Caulk Plus Silicone - Revision All Colors Date: 070798742253, 070798742338, Supercedes: 070798742437, 070798742376, 070798742390, 070798742451, 07098742475 Latex Caulk MSDS Number: DAP Canada 475 Finchdene Square Unit 5 Scarborough, Ontario M1X 1B7 888-327 -8477 (non-emergency) 05/21/2008 04/21/2005 00010002605 Section 2 - Hazards Identification Emergency Overview: A colored paste product with a very slight ammonia odor. WARNING! May cause eye, skin, nose, throat and respiratory tract irritation. May cause eye or skin irritation. Harmful if swallowed or absorbed through the skin. This product contains ethylene glycol. Refer to other MSDS sections for other detailed information. Effects Of Overexposure - Eye Contact: May cause eye irritation. Effects Of Overexposure - Skin Contact: May cause skin irritation. Harmful if absorbed through the skin. Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation of high concentrations may cause headache, nausea, and dizziness. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes). Inhalation may cause mild irritation to the respiratory tract (nose, mouth, mucous membranes). Effects Of Overexposure - Ingestion: Ingestion of ethylene glycol can cause gastrointestinal irritation, nausea, vomiting, diarrhea and if ingested in sufficient quantities, death. Harmful or fatal if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. If ingested, may cause vomiting, diarrhea, and depressed respiration. Ingestion may result in obstruction when material hardens. 00010002605 English Page 2 of 7 Effects Of Overexposure - Chronic Hazards: Repeated or prolonged exposure may cause skin, respiratory, kidney and liver damage. Prolonged and repeated skin contact may cause irritation and possibly dermatitis. The International Agency for Research on Cancer (IARC) has determined that crystalline silica in the form of quartz or cristobalite that is inhaled from occupational sources is carcinogenic to humans (Group 1- carcinogenic to humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (published in June 1997) in conjunction with the use of these materials. The National Toxicology Program (NTP) classifies respirable crystalline silica as "known to be a human carcinogen". Refer to the 9th Report on Carcinogens (2000). The American Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (Group A2). Breathing dust containing respirable crystalline silica may not cause noticeable injury or illness even though permanent lung damage may be occurring. Inhalation of dust may have the following serious chronic health effects: Excessive inhalation of respirable dust can cause pneumoconiosis, a respiratory disease, which can result in delayed, progressive, disabling and sometimes fatal lung injury. Symptoms include cough, shortness of breath, wheezing, non-specific chest illness and reduced pulmonary function. Smoking exacerbates this disease. Individuals with pneumoconiosis are predisposed to develop tuberculosis. There is some evidence that breathing respirable crystalline silica or the disease silicosis is associated with an increased incidence of significant disease endpoints such as scleroderma (an immune system disorder manifested by fibrosis of the lungs, skin and other internal organs) and kidney disease. Prolonged, repeated, or high exposures may cause weakness and depression of the central nervous system. A mixture of diisodecyl phthalate and diisononyl phthalate has been tested in a two-generation toxicity study in laboratory animals. No effects on reproductive parameters were seen. However, a small but statistically significant increase in early offspring mortality was seen at high oral doses. The significance of this to humans is uncertain. The mixture of phthalate esters contained within this product has been shown to cause developmental effects at high doses in laboratory animals when administered orally by gavage in a developmental study and developmental and fertility effects when administered at high doses by feed in a two-generation reproduction study. The potential risk from occupational and consumer exposure is considered to be very low, based on limited relevance of the rodent findings to humans and the large safety margins between exposure and the effect levels. Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Studies have shown that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals. Ethylene glycol has been shown to cause birth defects in laboratory animals. Primary Route(s) Of Entry: Skin Contact, Inhalation, Eye Contact Medical Conditions which May be Aggravated by Exposure: None known. Carcinogenicity: CAS No. Chemical Name 13463-67-7 Titanium dioxide 14808-60-7 Silica, crystalline 50-00-0 Formaldehyde ACGIH OSHA IARC NTP Not Listed. Suspected human carcinogen. Suspected human carcinogen. Not Listed. Possible carcinogen. Not Listed. Not Listed. Human carcinogen. Known carcinogen. Potential cancer hazard. Human carcinogen. Anticipated carcinogen. Section 3 - Composition / Information On Ingredients Chemical Name Limestone Branched and linear phthalates Titanium dioxide Silica, crystalline Ethylene glycol Ammonia Formaldehyde Section 4 - First Aid Measures CASRN 1317-65-3 Proprietary 13463-67 -7 14808-60 -7 107-21-1 7664-41-7 50-00 -0 Wt% 40 -70 1-5 0.1-1.0 0.1-1.0 0.1-1.0 <0.08 <0.0010 00010002605 English Page 3 of 7 First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes until irritation subsides. Get medical attention immediately. First Aid - Skin Contact: Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical aid if symptoms persist. If skin irritation persists, call a physician. Remove and wash contaminated clothing. In case of contact, immediately flush skin with plenty of water while removing contaminated clothing and shoes. First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If continued breathing difficulty is experienced, get medical attention immediately. First Aid: If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical attention immediately. First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately. If ingested, drink 2 glasses of water. Immediately see a physician. Never give anything by mouth to an unconscious person. Note to Physician: None. COMMENTS: If over-exposure occurs, call your local poison control center. Section 5 - Fire Fighting Measures Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog Unusual Fire And Explosion Hazards: No special protective measures against fire required. Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent) and full protective gear. Use water spray to cool exposed surfaces. Section 6 - Accidental Release Measures Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use absorbent material or scrape up dried material and place in container. Section 7 - Handling And Storage Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Avoid breathing vapor and contact with eyes, skin and clothing. Use only with adequate ventilation. Open all windows and doors or use other means to ensure cross-ventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous conditions. Wash thoroughly after handling. Storage: Do not store at temperatures above 120 degrees F. Store containers away from excessive heat and freezing. Close container after each use. Store away from caustics and oxidizers. Section 8 - Exposure Controls / Personal Protection Chemical Name CASRN ACGIH TWA ACGIH STEL ACGIH CEIL Limestone 1317-65-3 10 MGM3 N.E. N.E. Branched and linear phthalates Titanium dioxide Proprietary 13463-67-7 N.E. 10 MGM3 N.E. N.E. N.E. N.E. Silica, crystalline 14808-60-7 0.025 MGM. N.E. N.E. Ethylene glycol Ammonia Formaldehyde 107-21-1 7664-41-7 50-00-0 N.E. 25 PPM N.E. N.E. 35 PPM N.E. 100 MGM3 N.E. 0.3 PPM OSHA TWA 5 MGM3 (respirable fraction) N.E. 15 MGM3 10/(%SiO2 + 2) MGM3 N.E. 50 PPM 0.75 PPM OSHA STEL OSHA CEIL Skin N.E. N.E. No N.E. N.E. N.E. N.E. No No N.E. N.E. No N.E. N.E. 2 PPM N.E. N.E. N.E. No No No Exposure Notes: 14808-60-7 The 2002 ACGIH Threshold Limit Values for Chemical Substances and Physical Agents lists the median 00010002605 English Page 4 of 7 Respirable Particulate Mass (RPM) point for crystalline silica at 4.0 microns in terms of the particle's aerodynamic diameter. The TLVs for crystalline silica represent the respirable fraction. OSHA PEL TWA for Quartz is calculated using the following formula: 10 mg/m3/(% SiO2 + 2). Both concentration and percent quartz for the application of this limit are to be determined from the fraction passing a size selector with the following characteristics. |------------------------------------------------------------------------------------ |-----------------------------------------| | ....... Aerodynamic diameter ( unit density sphere ) .....| Percent passing selector | | 2 ................................................................................|.................90....................| | 2.5 .............................................................................|..................75...................| | 3.5 .............................................................................|..................50...................| | 5.0 .............................................................................|..................25...................| | 10 ..............................................................................|...................0....................| Precautionary Measures: Contact lenses pose a special hazard; soft lenses may absorb and all lenses concentrate irritants. Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Ensure adequate ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient concentrations below recommended exposure limits. Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSH-approved air purifying respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where airborne concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. National Institute for Occupational Safety and Health (NIOSH) has recommended that the permissible exposure limit be changed to 50 micrograms respirable free silica per cubic meter of air (0.05 mg/m3) as determined by a full shift sample up to 10-hour work shift. Skin Protection: Rubber gloves. Natural rubber, butyl rubber and polyvinyl chloride gloves are not suitable protection against the phthalates contained within this product; neoprene is recommended. Eye Protection: Goggles or safety glasses with side shields. Other protective equipment: Not required under normal use. Hygienic Practices: Wash hands before breaks and at the end of workday. Remove and wash contaminated clothing before re-use. Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary between states. Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work practices. Section 9 - Physical And Chemical Properties Boiling Range: Odor: Color: Solubility in H2O: Freeze Point: Vapor Pressure: Physical State: Flash Point, F: 210 - 220 F Very Slight Ammonia Colored Not Established Not Established Not Established Paste Greater than 200 degrees Fahrenheit Lower Explosive Limit, %: Not Established Vapor Density: Odor Threshold: Evaporation Rate: Specific Gravity: pH: Viscosity: Flammability: Method: Heavier Than Air Not Established Slower Than n-Butyl Acetate 1.5 Between 7.0 and 12.0 Not Established Non-Flammable (Seta Closed Cup) Upper Explosive Limit, %:Not Established 00010002605 English Page 5 of 7 When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally. (See section 16 for abbreviation legend) Section 10 - Stability And Reactivity Conditions To Avoid: Excessive heat and freezing. Incompatibility: Incompatible with strong bases and oxidizing agents. Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx. Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions. Stability: Stable under recommended storage conditions. Section 11 - Toxicological Information Product LD50: Not Established CASRN 107-21-1 7664-41-7 50-00-0 Chemical Name Product LC50: Not Established LD50 Ethylene glycol Ammonia Formaldehyde Rat:4700 mg/kg ------------------------- LC50 Rat:10876 mg/kg Rat:2000 ppm/4H Rat:203 mg/m3 Significant Data with Possible Relevance to Humans: None. Section 12 - Ecological Information Ecological Information: Ecological injuries are not known or expected under normal use. Section 13 - Disposal Information Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA Waste Code if Discarded (40 CFR Section 261): None Section 14 - Transportation Information DOT Proper Shipping Name: DOT Technical Name: DOT Hazard Class: Not Regulated Packing Group: N.A. N.A. N.A. Hazard Subclass: DOT UN/NA Number: N.A. N.A. Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may apply if shipped via other modes of transportation and/or to non-domestic destinations. Section 15 - Regulatory Information CERCLA - SARA Hazard Category: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of 00010002605 English Page 6 of 7 the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Immediate Health Hazard, Chronic Health Hazard SARA Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: None Toxic Substances Control Act: All ingredients in this product are either on TSCA inventory list, or otherwise exempt. This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: Chemical Name CAS Number Mercury & compounds 7439-97-6 Canadian WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. Canadian WHMIS Class: Not Controlled. Section 16 - Other Information HMIS Ratings: Health: 1 Flammability: 1 Reactivity: 0 Volatile Organic Compounds (VOC), less water less exempts: g/L: Personal Protection: B 30.5 lb/gal: 0.3 Volatile Organic Compounds (VOC), less water less exempts, less LVP -VOCs: wt:wt%: 1.5 wt:wt%: 0.6 REASON FOR REVISION: Periodic Update Legend: N.A. – Not Applicable ACGIH – American Conference of Governmental Industrial Hygienists N.E. – Not Established SARA – Superfund Amendments and Reauthorization Act of 1986 N.D. – Not Determined NJRTK – New Jersey Right-to-Know Law VOC – Volatile Organic Compound OSHA – Occupational Safety and Health Administration PEL – Permissible Exposure Limit HMIS – Hazardous Materials Identification System TLV – Threshold Limit Value NTP – National Toxicology Program CEIL – Ceiling Exposure Limit STEL – Short Term Exposure Limit LD50 – Lethal Dose 50 LC50 – Lethal Concentration 50 F – Degree Fahrenheit MSDS – Material Safety Data Sheet 00010002605 English C – Degree Celsius Page 7 of 7 CASRN – The Chemical Abstracts Service Registry Number DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context of the intended use and (ii) determine if they are appropriate. MATERIAL SAFETY DATA SHEET MSDS Name: QUAD ADVANCED FORMULA SEALANT MSDS Number: 24011-001-4 Version Number 2 MSDS Date: SEP-09-2002 Page Number: 1 ----------------------------------------------------------------------------- SECTION I - PRODUCT AND COMPANY INFORMATION Product Name: HMIS Hazard Rating: QUAD ADVANCED FORMULA SEALANT Health: 1 Fire: 3 Reactivity: 0 Company Identification: OSI SEALANTS, INC.a Subsidiary of Sovereign Specialty Chems. 7405 PRODUCTION DRIVE MENTOR OH 44060 Information phone/Fax: Emergency Phone (24 hour) Chemtrec (outside-USA) (440) 255-8900 (440) 974-8358 CHEMTREC (800) 424-9300 (703) 527-3887 Product Class Trade Name Product Code SEALANT PRO-SERIES 24011-001,-xxx PPE: B SECTION II - INGREDIENT AND HAZARD INFORMATION Hazardous Ingredient Name CAS Number Percent STODDARD SOLVENT 8052-41-3 10 - 15 Y XYLENE 1330-20-7 10 - 15 Y Titanium Dioxide ** 13463-67-7 5 - 10 ETHYL BENZENE 100-41-4 < 5.0 TSCA Y Ingredient Notes: Remaining ingredients are not considered OSHA hazardous. *TITANIUM DIOXIDE IN WHITE ONLY! **The main hazard for Titanium Dioxide is in inhalation. Because of its incorporation into the polymer matrix, exposure by inhalation is unlikely. - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION III - PHYSICAL AND CHEMICAL PROPERTIES Form: High viscosity caulk (various colors) -------------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET MSDS Name: QUAD ADVANCED FORMULA SEALANT MSDS Number: 24011-001-4 Version Number 2 MSDS Date: SEP-09-2002 Page Number: 2 ----------------------------------------------------------------------------Solubility (in water): pH Value, +/-.3: Boiling Range: Vapor Pressure (mmHg): Evaporation Rate: insol. Not Applicable 280.øF - 380.øF (137.78øC - 193.33øC) 23.@ 68.øF (20.øC) 0.9 times Slower than n-Butyl Acetate Vapor Density: Heavier than air % Volatile, Weight % Volatile, Volume Specific Gravity: VOC (less H2O or exempt) approx. 25.% 40.% 1.18 340 gr/l.(25%) NOTE: *BOIL RANGE, EVAP RATE, VAPOR DENSITY AND PRESSURE FOR SOLVENT ONLY! - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION IV - FIRE FIGHTING MEASURES (Flash,UEL,LEL for solvent only) Flammability Class IC Flash Range: 80.øF (26.67øC) Tag Closed Cup Explosive Range (LEL/UEL): 1.% 7.% EXTINGUISHING MEDIA: Carbon Dioxide---Dry Chemical---Foam Use water fog to cool material in vicinity of fire. SPECIAL FIRE-FIGHTING PROCEDURES: Use self-contained breathing apparatus with full facepiece operated in pressure demand with full protective equipment. UNUSUAL FIRE AND EXPLOSION HAZARDS: Any closed container may rupture when exposed to extreme heat. Solvent vapors are heavier than air and travel along the ground. Vapors given off are flammable and may be ignited in air explosively. - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION V - HEALTH HAZARD DATA ROUTES OF ENTRY: ENTRY THROUGH... Inhalation and skin most likely CARCINOGENICITY... NTP? N/E | IARC Monographs? N/E | OHSA? NO This product contains Ethylbenzene. The International Agency for -------------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET MSDS Name: QUAD ADVANCED FORMULA SEALANT MSDS Number: 24011-001-4 Version Number 2 MSDS Date: SEP-09-2002 Page Number: 3 ----------------------------------------------------------------------------Research on Cancer has evaluated ethylbenzene and classified it as a possible human carcinogen (Group 2B) based on sufficient evidence for carcinogenicity in experimental animals, but inadequate evidence for cancer in exposed humans. EFFECTS OF OVEREXPOSURE Eyes: Can cause irritation, redness, tearing and blurred vision. Skin: Prolonged or repeated contact can cause moderate irritation, drying of the skin, and dermatitis. Inhalation: Excessive inhalation of vapors can cause respiratory irritation, headache, drowsiness and fatigue. High concentrations of vapors are anesthetic and may cause central nervous system effects such as dizziness. Ingestion: Can cause gastrointestinal irritation, nausea, vomiting and diarrhea. FIRST AID MEASURES Eyes: Flush eyes gently with water for at least 15 minutes lifting eyelids occasionally; get prompt medical attention Skin: Wash thoroughly with soap and water; apply a mild skin cream. Remove contaminated clothing. Inhalation: Move affected person to fresh air; if breathing is difficult, administer oxygen; if breathing has stopped, give artificial respiration. Get medical attention. Ingestion: DO NOT INDUCE VOMITING! Get immediate medical attention. CHRONIC HAZARDS NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain, nervous system, liver or kidney damage or may cause cardiac arrhythmia. INTENTIONAL misuse of this product by deliberately inhaling its vapors may be harmful or fatal. Overexposure to Xylene may cause injury to Liver, Kidney and blood. - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION VI - STABILITY AND REACTIVITY Stability: This product is stable Hazardous Polymerization: Hazardous polymerization will not occur INCOMPATABILITY: Keep away from strong oxidizing agents. CONDITIONS TO AVOID: Keep away from heat, spark, open flames and any ignition source. HAZARDOUS DECOMPOSITION PRODUCTS: Will produce fumes and smoke containing carbon monoxide and dioxide under fire conditions. -------------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET MSDS Name: QUAD ADVANCED FORMULA SEALANT MSDS Number: 24011-001-4 Version Number 2 MSDS Date: SEP-09-2002 Page Number: 4 ----------------------------------------------------------------------------- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION VII - ACCIDENTAL RELEASE AND DISPOSAL MEASURES: STEPS TO BE TAKEN IN CASE OF SPILL: Eliminate all ignition sources. Ventilate confined areas. (Open windows and doors). Wear appropriate protective clothing. Cover with absorbent. Scoop into sealable safety container. WASTE DISPOSAL METHOD: Dispose of following local, state, and federal regulations. - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits ACGIH TLV ACGIH TLV-C STODDARD SOLVENT 100.00 PPM N/est ACGIH STEL N/est OSHA STEL N/est OSHA PEL 100.00 PPM XYLENE 100.00 PPM N/est 150.00 PPM Titanium Dioxide ** 10.00 mg/F3 N/est N/est ETHYL BENZENE 100.00 PPM N/est N/est 150.00 PPM N/est 150.00 PPM 100.00 PPM 15.00 N/est 100.00 PPM RESPIRATORY PROTECTION: If TLV of the product is exceeded, a NIOSH/MSHA jointly approved air supply respirator is advised in the absence of proper ventilation. OSHA regulations also permit the use of other types of NIOSH/MSHA respirators under specified conditions. (See your safety equipment supplier for more information) VENTILATION: Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below TLV. Ventilate during application and curing of this product. PROTECTIVE CLOTHING: Rubber gloves should be worn where skin contact is likely. Wear impervious clothing and shoes. EYE PROTECTION: Chemical goggles or safety glasses should be worn. HANDLING AND STORAGE PRECAUTIONS: -------------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET MSDS Name: QUAD ADVANCED FORMULA SEALANT MSDS Number: 24011-001-4 Version Number 2 MSDS Date: SEP-09-2002 Page Number: 5 ----------------------------------------------------------------------------Keep away from heat, spark and flame. Keep out of reach of children. Keep container closed while not in use. Do not cut or burn recepticals that have contained a solvent based product. Do not reuse this container. Use only in a well ventilated area. -------------------------------------------------------------------N/A=NOT APPLICABLE N/AV=NOT AVAILABLE N/E, N/est=NOT ESTABLISHED - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION IX - TRANSPORT INFORMATION: DOT CLASSIFICATIONS FOR ONE GALLON AND UNDER CONTAINERS DESCRIPTION: CLASS/ UN NO.: DOT LABEL: IMDG class: IMDG BOL: ORM-D, Consumer commodity none ORM-D (Caulking) 3.3 Flammable Liquid nos.,3,UN1993,PG III,LTD QTY DOT CLASSIFICATIONS for OVER 1 GALLON size CONTAINERS DESCRIPTION: CLASS: DOT LABEL: IMDG CLASS: IMDG BOL: Flammable Class 3, Flammable 3.3 Flammable Liquid n.o.s. Pack group III Liquid, UN 1993 liquid n.o.s.,3,UN1993,PG III - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION X - REGULATORY INFORMATION: SARA TITLE III SECTION 313: This product contains the following toxic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right to Know Act of 1986 and of 40 CFR 372: Ingredient Name CAS Number Percent XYLENE 1330-20-7 10 - 15 ETHYL BENZENE 100-41-4 < 5.0 -------------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET MSDS Name: QUAD ADVANCED FORMULA SEALANT MSDS Number: 24011-001-4 Version Number 2 MSDS Date: SEP-09-2002 Page Number: 6 ----------------------------------------------------------------------------This material fits the EPA Hazard Category definition of Immediate (Acute) and Delayed (Chronic) Health Hazards under SARA Sections 311, 312. Chemical substances are TSCA listed. California PROP.65 Chemicals: none known DISCLAIMER: The information contained herein is based on data available as of the date of preparation of this MSDS and which we believe to be reliable. However, no warranty is expressed or implied regarding the accuracy of the data. We shall not be responsible for the use of this information, or of any product, method, or apparatus mentioned, and the user must make his own investigation to determine the suitability of the information or products for his particular purpose, for the protection of the environment, and the health and safety of the users of this material. -------------------------------------------------------------------------------- Last Page MSDS 3504 3504: Dap White Silicone MSDS Last updated: 10/02/2006 XIAMETER® MATERIAL SAFETY DATA SHEET Version: 1.4 Revision Date: 2005/06/01 DAP® 100% SILICONE RUBBER SEALANT WHITE, 8646 1. PRODUCT AND COMPANY IDENTIFICATION -------------------------------------------------------------------------------Dow Corning Corporation 24 Hour Emergency Telephone: (989) 496-5900 South Saginaw Road Customer Service: (989) 496-6000 Midland, Michigan 48686 Product Disposal Information: (989) 496-6315 CHEMTREC: (800) 424-9300 MSDS No.: 04061404 Revision date: 2005/06/01 Generic Description: Silicone elastomer Physical Form: Paste Color: See product name Odor: Acetic acid odor NFPA Profile: Health 2 Flammability 1 Instability/Reactivity 0 Note: NFPA = National Fire Protection Association 2. OSHA HAZARDOUS COMPONENTS -------------------------------------------------------------------------------CAS Number Wt % Component Name 17689-77-9 4253-34-3 1.0 - 5.0 1.0 - 5.0 Ethyltriacetoxysilane Methyltriacetoxysilane The above components are hazardous as defined in 29 CFR 1910.1200. 3. HAZARDS IDENTIFICATION -------------------------------------------------------------------------------POTENTIAL HEALTH EFFECTS Acute Effects Eye: Direct contact may cause moderate irritation. Skin: May cause moderate irritation. Inhalation: Material is not likely to present an inhalation hazard at ambient conditions. However, if material is heated or high vapor/aerosol concentrations are attained, central nervous system depression may occur, which is characterized by drowsiness, dizziness, confusion or loss of coordination. Oral: Low ingestion hazard in normal use. Prolonged/Repeated Exposure Effects Skin: Inhalation: Oral: No known applicable information. No known applicable information. Repeated ingestion or swallowing large amounts may injure internally. Signs and Symptoms of Overexposure No known applicable information. Medical Conditions Aggravated by Exposure No known applicable information. The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar composition, component data and/or expert review of the product. Please refer to Section 11 for the detailed toxicology information. 4. FIRST AID MEASURES -------------------------------------------------------------------------------Eye: Immediately flush with water for 15 minutes. Get medical attention. Skin: Remove from skin and wash thoroughly with soap and water or waterless cleanser. Get medical attention if irritation or other ill effects develop or persist. Inhalation; Material is not likely to present an inhalation hazard at ambient conditions. If material is heated or vapor/mist/dust/fumes are generated, care should be taken to prevent inhalation. In case of exposure to vapor/mist/dust/fumes, move to fresh air. Oral: Get medical attention. Comments: Treat according to person's condition and specifics of exposure. 5. FIRE FIGHTING MEASURES -------------------------------------------------------------------------------Flash Point: > 212 F / > 100 C (Closed Cup) Auto ignition Temperature: Not determined. Flammability Limits in Air: Not determined. Extinguishing Media: On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide (CO2), dry chemical or water spray. Water can be used to cool fire exposed containers. Fire Fighting Measures: Self-contained breathing apparatus and protective clothing should be worn in fighting large fires involving chemicals. Determine the need to evacuate or isolate the area according to your local emergency plan. Use water spray to keep fire exposed containers cool. Unusual Fire Hazards: None. Hazardous Decomposition Products Thermal breakdown of this product during fire or very high heat conditions may evolve the following hazardous decomposition products: Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide. Formaldehyde. Metal oxides. Nitrogen oxides. Sulfur oxides. Chlorine compounds. 6. ACCIDENTAL RELEASE MEASURES -------------------------------------------------------------------------------Containment/Clean up: Observe all personal protection equipment recommendations Described in Sections 5 and 8. Wipe up or scrape up and contain for salvage or disposal. Clean area as appropriate since spilled materials, even in small quantities, may present a slip hazard. Final cleaning may require use of steam, solvents or detergents. Dispose of saturated absorbent or cleaning materials appropriately, since spontaneous heating may occur. Local, state and federal laws and regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which federal, state and local laws and regulations are applicable. Sections 13 and 15 of this MSDS provide information regarding certain federal and state requirements. Note: See section 8 for Personal Protective Equipment for Spills. Call (989) 496-5900, if additional information is required. 7. HANDLING AND STORAGE -------------------------------------------------------------------------------Use with adequate ventilation. Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide ventilation during use to control HOAc within exposure guidelines or use respiratory protection. Avoid eye contact. Avoid skin contact. Do not take internally. Avoid breathing vapor. Keep container closed. Use reasonable care and store away from oxidizing materials. Keep container closed and store away from water or moisture. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION -------------------------------------------------------------------------------Component Exposure Limits CAS Number Component Name Exposure Limits 17689-77-9 Ethyltriacetoxysilane See acetic acid comments 4253-34-3 Methyltriacetoxysilane See acetic acid comments Acetic acid is formed upon contact with water or humid air. Provide adequate ventilation to control exposures within guidelines of OSHA PEL: TWA 10 ppm and ACGIH TLV: TWA 10 ppm, STEL 15 ppm. Engineering Controls Local Ventilation: General Ventilation: Recommended. Recommended. Personal Protective Equipment for Routine Handling Eyes: Use proper protection - safety glasses as a minimum. Skin: Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are recommended. Suitable Gloves: Butyl Rubber. Nitrile Rubber. Inhalation: Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. IH personnel can assist in judging the adequacy of existing engineering controls. Suitable Respirator: Respiratory protection is not needed under ambient conditions. if vapor/mist/dust/fumes are generated when material is heated or handled, the following is advised. General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Personal Protective Equipment for Spills Eyes: Use full face respirator. Skin: Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are recommended. Inhalation/Suitable Respiratory protection recommended. Follow OSHA Respirator Regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection. Precautionary Measures: Avoid eye contact. Avoid skin contact. Do not take internally. Avoid breathing vapor. Keep container closed. Use reasonable care. Comments: Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide ventilation during use to control HOAc within exposure guidelines or use respiratory protection. When heated to temperatures above 150 C (300 F) in the presence of air, product may form formaldehyde vapors. Physical and health hazard information is readily available from Dow Corning corporation and the Material Safety Data Sheet. Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require added precautions. 9. PHYSICAL AND CHEMICAL PROPERTIES -------------------------------------------------------------------------------- Physical Form; Color: Odor: Specific Gravity @ 25C: Viscosity: Freezing/Melting Point: Boiling Point: Vapor Pressure @ 25 C: Vapor Density: Solubility In Water: pH: Volatile Content: Paste See product name Acetic acid odor 1.007 Not Determined. Not Determined. Not Determined. Not Determined. Not Determined. Not Determined. Not Determined. Not Determined. Note: The above information is not intended for use in preparing product specifications. 10. STABILITY AND REACTIVITY -------------------------------------------------------------------------------Chemical Stability: Stable Hazardous Polymerization: Hazardous polymerization will not occur. Conditions to Avoid: None Materials to Avoid: Oxidizing material can cause a reaction. Water, moisture, Or humid air can cause hazardous vapors to form as described in Section 8. 11. TOXICOLOGICAL INFORMATION -------------------------------------------------------------------------------Component Toxicology Information Inhalation of fumes may result in metal fume fever, a flu-like illness with symptoms of metallic taste, fever and chills, aches, chest tightness, and cough. Special Hazard Information on Components No known applicable information. 12. ECOLOGICAL INFORMATION -------------------------------------------------------------------------------Environmental Fate and Distribution Complete information is not yet available. Environmental Effects Complete information is not yet available. Fate and Effects in Waste Water Treatment Plants Complete information is not yet available. Ecotoxicity Classification Criteria Hazard Parameters (LC50 or EC50) High Medium Low Acute Aquatic Toxicity (mg/L) <=1 >1 and <=100 >100 Acute Terrestrial Toxicity <=100 >100 and <=2000 >2000 This table is adapted from "Environmental Toxicology and Risk Assessment" ASTM STP 1179, p.34, 1993 This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information presented in the section concerning the overall ecological safety of this material. 13. DISPOSAL CONSIDERATIONS -------------------------------------------------------------------------------RCRA Hazard Class (40 CFR 261) When a decision is made to discard this material, as received, is it classified as a hazardous waste? No State or local laws may impose additional regulatory requirements regarding disposal. Call (989) 496-6315, if additional information is required. 14. TRANSPORT INFORMATION -------------------------------------------------------------------------------DOT Road Shipment Information (49 CFR 172.101) Not subject to DOT. Ocean Shipment (IMDG) Not subject to IMDG code. Air Shipment (IATA) Not subject to IATA regulations. 15. REGULATORY INFORMATION -------------------------------------------------------------------------------Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200. TSCA Status: All chemical substances in this material are included on or exempted from listing on the TSCA Inventory of Chemical Substances. EPA SARA Title III Chemical Listings Section 302 Extremely Hazardous Substances (40 CFR 355): None Section 304 CERCLA Hazardous Substances (40CFR 302): None Section 311/312 Hazard Class (40 CFR 370): Acute: Yes Chronic: No Fire: No Pressure: No Reactive: No Section 313 Toxic Chemicals (40 CFR 372): None present or none present in regulated quantities. Supplemental State Compliance Information California Warning: This product contains the following chemical(s) listed by the State of California under the Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer, birth defects or other reproductive harm. None known. Massachusetts CAS Number Wt % Component Name 7631-86-9 7.0 - 13.0 Silica, amorphous 1333-86-4 <=2.0 Carbon black 13463-67-7 <=1.8 Titanium dioxide 1309-37-1 <=1.0 Iron oxide New Jersey CAS Number Wt % Component Name 70131-67-8 >60.0 Dimethyl siloxane, hydroxyl-terminated 7631-86-9 7.0 - 13.0 Silica, amorphous 64742-46-7 distillates <=6.9 Hydro treated middle petroleum 1333-86-4 <=2.0 Carbon black 1332-37-2 <=2.0 Iron oxide 147-14-8 <=2.0 Tetrabenzo-5,10,15,20Diazaporphyrinephthalocyanine (Pigment blue 15) 63148-62-9 1.0 - 5.0 Polydimethylsiloxane 17689-77-9 1.0 - 5.0 Ethyltriacetoxysilane 13463-67-7 <=1.8 Titanium dioxide 4253-34-3 1.0 - 5.0 Methyltriacetoxysilane 1309-37-1 <=1.0 Iron oxide Pennsylvania CAS Number Wt % Component Name 70131-67-8 > 60.0 Dimethyl siloxane, hydroxyl-terminated 7631-86-9 7.0 - 13.0 Silica, amorphous 64742-46-7 distillates <=6.9 Hydro treated middle petroleum 1333-86-4 <=2.0 Carbon black 13463-67-7 <=1.8 1309-37-1 <=1.0 Titanium dioxide Iron oxide 16. OTHER INFORMATION -------------------------------------------------------------------------------Prepared by: Dow Corning Corporation These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate. XIAMETER® is a trademark of Dow Corning Corporation http://www.xiameter.com The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. XIAMETER(R) Material Safety Data Sheet Page: 1 of 8 Version: 1.5 Revision Date: 2005/06/01 DAP(R) 73473 SILICONE SEALANT CLEAR CDN 1. PRODUCT AND COMPANY IDENTIFICATION 24 Hour Emergency Telephone: Customer Service: Product Disposal Information: CHEMTREC: Dow Corning Corporation South Saginaw Road Midland, Michigan 48686 MSDS No.: 04061396 (989) 496-5900 (989) 496-6000 (989) 496-6315 (800) 424-9300 Revision Date: 2005/06/01 Generic Description: Physical Form: Color: Odor: Silicone elastomer Paste Colorless Acetic acid odor NFPA Profile: Health 2 Flammability 1 Instability/Reactivity 0 Note: NFPA = National Fire Protection Association 2. OSHA HAZARDOUS COMPONENTS CAS Number Wt % Component Name 17689-77-9 1.0 - 5.0 Ethyltriacetoxysilane 4253-34-3 1.0 - 5.0 Methyltriacetoxysilane The above components are hazardous as defined in 29 CFR 1910.1200. 3. HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS Acute Effects Eye: Direct contact may cause moderate irritation. Skin: May cause moderate irritation. Inhalation: Material is not likely to present an inhalation hazard at ambient conditions. However, if material is heated or high vapor/aerosol concentrations are attained, central nervous system depression may occur, which is characterized by drowsiness, dizziness, confusion or loss of coordination. Oral: Low ingestion hazard in normal use. Prolonged/Repeated Exposure Effects Skin: No known applicable information. XIAMETER(R) Material Safety Data Sheet Page: 2 of 8 Version: 1.5 Revision Date: 2005/06/01 DAP(R) 73473 SILICONE SEALANT CLEAR CDN Inhalation: No known applicable information. Oral: No known applicable information. Signs and Symptoms of Overexposure No known applicable information. Medical Conditions Aggravated by Exposure No known applicable information. The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar compositions, component data and/or expert review of the product. Please refer to Section 11 for the detailed toxicology information. 4. FIRST AID MEASURES Eye: Immediately flush with water for 15 minutes. Get medical attention. Skin: Remove from skin and wash thoroughly with soap and water or waterless cleanser. Get medical attention if irritation or other ill effects develop or persist. Inhalation: Material is not likely to present an inhalation hazard at ambient conditions. If material is heated or vapor/mist/dust/fumes are generated, care should be taken to prevent inhalation. In case of exposure to vapor/mist/dust/fumes, move to fresh air. Oral: No first aid should be needed. Comments: Treat according to person's condition and specifics of exposure. 5. FIRE FIGHTING MEASURES Flash Point: > 212 °F / > 100 °C (Closed Cup) Autoignition Temperature: Not determined. Flammability Limits in Air: Not determined. Extinguishing Media: On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide (CO2), dry chemical or water spray. Water can be used to cool fire exposed containers. Fire Fighting Measures: Self-contained breathing apparatus and protective clothing should be worn in fighting large fires involving chemicals. Determine the need to evacuate or isolate the area according to your local emergency plan. Use water spray to keep fire exposed containers cool. Unusual Fire Hazards: None. Hazardous Decomposition Products Thermal breakdown of this product during fire or very high heat conditions may evolve the following hazardous XIAMETER(R) Material Safety Data Sheet Page: 3 of 8 Version: 1.5 Revision Date: 2005/06/01 DAP(R) 73473 SILICONE SEALANT CLEAR CDN decomposition products: Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide. Formaldehyde. 6. ACCIDENTAL RELEASE MEASURES Containment/Clean up: Observe all personal protection equipment recommendations described in Sections 5 and 8. Wipe up or scrape up and contain for salvage or disposal. Clean area as appropriate since spilled materials, even in small quantities, may present a slip hazard. Final cleaning may require use of steam, solvents or detergents. Dispose of saturated absorbant or cleaning materials appropriately, since spontaneous heating may occur. Local, state and federal laws and regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which federal, state and local laws and regulations are applicable. Sections 13 and 15 of this MSDS provide information regarding certain federal and state requirements. Note: See section 8 for Personal Protective Equipment for Spills. Call (989) 496-5900, if additional information is required. 7. HANDLING AND STORAGE Use with adequate ventilation. Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide ventilation during use to control HOAc within exposure guidelines or use respiratory protection. Avoid eye contact. Avoid skin contact. Do not take internally. Avoid breathing vapor. Keep container closed. Use reasonable care and store away from oxidizing materials. Keep container closed and store away from water or moisture. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Component Exposure Limits CAS Number Component Name Exposure Limits 17689-77-9 Ethyltriacetoxysilane See acetic acid comments. 4253-34-3 Methyltriacetoxysilane See acetic acid comments. Acetic acid is formed upon contact with water or humid air. Provide adequate ventilation to control exposures within guidelines of OSHA PEL: TWA 10 ppm and ACGIH TLV: TWA 10 ppm, STEL 15 ppm. Engineering Controls Local Ventilation: General Ventilation: Recommended. Recommended. Personal Protective Equipment for Routine Handling XIAMETER(R) Material Safety Data Sheet Page: 4 of 8 Version: 1.5 Revision Date: 2005/06/01 DAP(R) 73473 SILICONE SEALANT CLEAR CDN Eyes: Use proper protection - safety glasses as a minimum. Skin: Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are recommended. Suitable Gloves: Nitrile Rubber. Butyl Rubber. Inhalation: Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. IH personnel can assist in judging the adequacy of existing engineering controls. Suitable Respirator: Respiratory protection is not needed under ambient conditions. If vapor/mist/dust/fumes are generated when material is heated or handled, the following is advised. General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Personal Protective Equipment for Spills Eyes: Use full face respirator. Skin: Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are recommended. Inhalation/Suitable Respirator: Respiratory protection recommended. Follow OSHA Respirator Regulations (29 CFR 1910.134) and use NIOSH/MHSA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection. Precautionary Measures: Avoid eye contact. Avoid skin contact. Do not take internally. Avoid breathing vapor. Keep container closed. Use reasonable care. Comments: Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide ventilation during use to control HOAc within exposure guidelines or use respiratory protection. When heated to temperatures above 150 C (300 F) in the presence of air, product may form formaldehyde vapors. Physical and health hazard information is readily available from Dow Corning Corporation and the Material Safety Data Sheet. Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require added precautions. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical Form: Paste XIAMETER(R) Material Safety Data Sheet Page: 5 of 8 Version: 1.5 Revision Date: 2005/06/01 DAP(R) 73473 SILICONE SEALANT CLEAR CDN Color: Odor: Specific Gravity @ 25°C: Viscosity: Freezing/Melting Point: Boiling Point: Vapor Pressure @ 25°C: Vapor Density: Solubility in Water: pH: Volatile Content: Colorless Acetic acid odor 1.007 Not determined. Not determined. Not determined. Not determined. Not determined. Not determined. Not determined. Not determined. Note: The above information is not intended for use in preparing product specifications. 10. STABILITY AND REACTIVITY Chemical Stability: Stable. Hazardous Polymerization: Conditions to Avoid: Hazardous polymerization will not occur. Materials to Avoid: Oxidizing material can cause a reaction. Water, moisture, or humid air can cause hazardous vapors to form as described in Section 8. None. 11. TOXICOLOGICAL INFORMATION Special Hazard Information on Components No known applicable information. 12. ECOLOGICAL INFORMATION Environmental Fate and Distribution Complete information is not yet available. Environmental Effects Complete information is not yet available. Fate and Effects in Waste Water Treatment Plants Complete information is not yet available. Hazard Parameters (LC50 or EC50) Acute Aquatic Toxicity (mg/L) Acute Terrestrial Toxicity Ecotoxicity Classification Criteria High Medium <=1 >1 and <=100 <=100 >100 and <= 2000 Low >100 >2000 XIAMETER(R) Material Safety Data Sheet Page: 6 of 8 Version: 1.5 Revision Date: 2005/06/01 DAP(R) 73473 SILICONE SEALANT CLEAR CDN This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34, 1993. This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information presented in the section concerning the overall ecological safety of this material. 13. DISPOSAL CONSIDERATIONS RCRA Hazard Class (40 CFR 261) When a decision is made to discard this material, as received, is it classified as a hazardous waste? No State or local laws may impose additional regulatory requirements regarding disposal. Call (989) 496-6315, if additional information is required. 14. TRANSPORT INFORMATION DOT Road Shipment Information (49 CFR 172.101) Not subject to DOT. Ocean Shipment (IMDG) Not subject to IMDG code. Air Shipment (IATA) Not subject to IATA regulations. 15. REGULATORY INFORMATION Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200. TSCA Status: All chemical substances in this material are included on or exempted from listing on the TSCA Inventory of Chemical Substances. EPA SARA Title III Chemical Listings Section 302 Extremely Hazardous Substances (40 CFR 355): None. Section 304 CERCLA Hazardous Substances (40 CFR 302): None. Section 311/312 Hazard Class (40 CFR 370): Acute: Yes Chronic: No Fire: No XIAMETER(R) Material Safety Data Sheet Page: 7 of 8 Version: 1.5 Revision Date: 2005/06/01 DAP(R) 73473 SILICONE SEALANT CLEAR CDN Pressure: No Reactive: No Section 313 Toxic Chemicals (40 CFR 372): None present or none present in regulated quantities. Supplemental State Compliance Information California Warning: This product contains the following chemical(s) listed by the State of California under the Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer, birth defects or other reproductive harm. None known. Massachusetts CAS Number Wt % Component Name 7.0 - 13.0 Silica, amorphous CAS Number Wt % Component Name 70131-67-8 > 60.0 Dimethyl siloxane, hydroxy-terminated 7631-86-9 7.0 - 13.0 64742-46-7 <=7.0 17689-77-9 1.0 - 5.0 Ethyltriacetoxysilane 4253-34-3 1.0 - 5.0 Methyltriacetoxysilane 7631-86-9 New Jersey Silica, amorphous Hydrotreated middle petroleum distillates Pennsylvania CAS Number Wt % Component Name 70131-67-8 > 60.0 Dimethyl siloxane, hydroxy-terminated 7631-86-9 7.0 - 13.0 64742-46-7 <=7.0 Silica, amorphous Hydrotreated middle petroleum distillates XIAMETER(R) Material Safety Data Sheet Page: 8 of 8 Version: 1.5 Revision Date: 2005/06/01 DAP(R) 73473 SILICONE SEALANT CLEAR CDN 16. OTHER INFORMATION Prepared by: Dow Corning Corporation These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate. XIAMETER(R) is a trademark of Dow Corning Corporation http://www.xiameter.com 0150 T ub & Wall Caulk Strip 0151 T ub & Wall Caulk Strip Material Safety Data Sheet (MSDS) MSDS # 0003 R ev is ion 1 E ME RGE N CY TE LE PH O N E NO. SECTION I TRADE NAME (IF NONE, PUT CHEMICAL) Tub & Wall Caulk Strip MANUFACTURER'S NAME AND TELEPHONE NO. Red Devil, Incorporated ADDRESS (Number, Street, 4175 Webb Street, Pryor, Oklahoma 74361 City, State, Zip Code ) 1-2-0 1-2-0-B NFPA Rating: HMIS Rating: (918) 825-5744 (24 Hrs.) (918) 825-5744 % SECTION II - HAZARDOUS INGREDIENTS TLV PEL U N ITS PRODUCT CONSISTS OF: Proprietary Butyl Mastic (Mixture) <20% NE NE NA Calcium carbonate** [1317-65-3] (as nuisance particulate, total) >70% 10 15 mg/m3 Non-hazardous ingredients* >10% NA NA NA *Unlisted ingredients are not considered hazardous under the OSHA Hazard Communication Standard (29 CFR 1910.1200). **Inhalation of particulates unlikely due to product's physical state VOC: 12.4%/wt. CARB Compliance: YES. Prop 65 Ingredients: NONE SECTION III - PHYSICAL DATA BOILING POINT (°F) NA SPECIFIC GRAVITY (H 2 0=1) NA VAPOR PRESSURE (MM Hg.) NA PERCENT VOLATILES BY VOLUME (%) NA VAPOR DENSITY (AIR=1) NA pH NA SOLUBILITY IN WATER Insoluble EVAPORATION RATE NA APPEARANCE AND ODOR White Caulk Strip, Slight Organic Odor SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Method used) NA FLAMMABLE LIMITS EXTINGUISHING MEDIA Water, foam, dry chemical, carbon dioxide SPECIAL FIRE FIGHTING PROCEDURES None Known UNUSUAL FIRE AND EXPLOSION HAZARDS None Known NA - Not Applicable NE - Not Established NA LEL UN - Unavailable UEL SECTION V - HEALTH HAZARD INFORMATION SYMPTOM/EFFECTS OR OVEREXPOSURE FIRS T AID EYES Solid or dust may cause mechanical irritation. In case of eye contact, immediately flush eye with running water for 15 minutes. Consult a physician if necessary. SKIN No adverse effects anticipated, as the product is not likely to be hazardous by skin contact. Consult a physician if necessary. INHALATION No adverse effects anticipated, as the product is not likely to be hazardous by inhalation. Consult a physician if necessary. INGESTION No adverse effects anticipated, as the product is not likely to be hazardous by ingestion. Consult a physician if necessary. SECTION VI - REACTIVITY DATA STABILITY Normally stable. Avoid heat, open flame. INCOMPATIBLE MATERIALS None Known HAZARDOUS DECOMPOSITION PRODUCTS Flammable hydrocarbons, oxides of carbon SECTION VII - SPILL OR LEAK PROCEDURES PROCEDURES NA WASTE DISPOSAL METHOD Comply with Federal, State & Local Regulations for disposal. SECTION VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY Not required EYEWEAR Not required CLOTHING/GLOVES Not required VENTILATION Use local ventilation SECTION IX - SPECIAL PRECAUTIONS Store in a closed container in cool area. Avoid heat & open flame. Reviewed By: 2004 Larry G. Brandon NAME VP Technology & General Manager TITLE June 24, DATE The information contained herein has been developed based upon current available scientific data. New information may be developed from time to time which may render the conclusions of this report obsolete. Therefore, no warranty is extended as to the applicability of this information to the user's intended purpose or for the consequences of its use or misuse. Material Safety Data Sheet 24 Hour Emergency Phone Numbers: Medical: 1-800 -327-3874 1-513-558 -5111 Transportation: 1-800-535 -5053 1-352-323 -3500 NOTE: National Response Center emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals IMPORTANT: Read this MSDS before handling or disposing of this product, and provide this information to the employees, customers, and users of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16. Section 1 - Chemical Product / Company Information This Material Safety Data Sheet is available in Canadian French and Spanish upon request. Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en español a su solicitud. Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere. Product Name: LTX WINDOW GLAZING - 12049 Product UPC Number: 7079812108 7079812049 7079870980 Product Use/Class: Latex Caulk Manufacturer: DAP Inc. 2400 Boston Street Suite 200 Baltimore, MD 21224-4723 888 -327-5477 ( non-emergency matters ) Revision Date: Supercedes: MSDS Number: 11/17/2003 11/17/2003 00010404001 Section 2 - Composition / Information On Ingredients Chemical Name Di(C9) ester branched & linear Di(c7) ester branch & linear Ester Branched & Linear(C7&C9) Ethylene glycol Silica, crystalline Formaldehyde Acetaldehyde Acrylonitrile CASRN Proprietary Proprietary Proprietary 107-21-1 14808-60-7 50 -00-0 75 -07-0 107-13-1 WT% 1-5 1-5 1-5 0.5-1.5 0.1-1.0 <0.02 <0.002 <0.0002 ACGIH TWA N.E. N.E. N.E. N.E. 0.05 MGM3 N.E. N.E. 2 PPM ACGIH STEL N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. ACGIH CEIL N.E. N.E. N.E. 100 MGM3 N.E. 0.3 PPM 25 PPM N.E. OSHA TWA N.E. N.E. N.E. N.E. N.E. 0.75 PPM 200 PPM 2 PPM OSHA STEL N.E. N.E. N.E. N.E. N.E. 2 PPM N.E. 10 PPM OSHA CEIL N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. SKIN No No No No No No No Yes Exposure Notes: CASRN Exposure Note 14808-60 -7 The 2002 ACGIH Threshold Limit Values for Chemical Substances and Physical Agents lists the median Respirable Particulate Mass (RPM) point for crystalline silica at 4.0 microns in terms of the particle's aerodynamic diameter. The TLVs for crystalline silica represent the respirable fraction. OSHA PEL TLV for Quartz is calculated using the following formula: 10 mg/m3/(% SiO2 + 2). Both concentration and percent quartz for the application of this limit are to be determined from the fraction passing a size selector with the following characteristics. |--------------------------------------------------------------------------------------------------------------------------- |-----------------------------------| | .................................... Aerodynamic diameter ( unit density sphere ) .....................................| Percent passing selector | | 2 ................................................................................................................................................|.................90....................| | 2.5 .............................................................................................................................................|..................75...................| 50-00-0 107-13-1 Important: | 3.5 .............................................................................................................................................|..................50...................| | 5.0 .............................................................................................................................................|..................25...................| | 10 ..............................................................................................................................................|...................0....................| Formaldehyde is a specially regulated substance for which an OSHA chemical-specific exposure standard exits. Detailed information regarding this substance may be found in 29 CFR 1910.1048. Medical surveillance information regarding this substance may be found in Appendix C to 29 CFR 1910.1048. Acrylonitrile is a specially regulated substance for which an OSHA chemical -specific exposure standard exits. Detailed information regarding this substance may be found in 29 CFR 1910.1045. Medical surveillance information regarding this substance may be found in Appendix C to 29 CFR 1910.1045. Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary between states. Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work practices Section 3 - Hazards Identification Emergency Overview: A(n) White to Off-White Paste product. WARNING! Harmful if swallowed or absorbed through the skin. This product contains ethylene glycol. May cause eye, skin, nose, throat and respiratory tract irritation. Refer to other MSDS sections for other detailed information. Effects Of Overexposure - Eye Contact: Causes eye irritation. Effects Of Overexposure - Skin Contact: Causes skin irritation. Prolonged or repeated contact with skin may cause irritation. May cause allergic skin reaction or sensitization. Harmful if absorbed through the skin. Effects Of Overexposure - Inhalation: Harmful if inhaled. Causes nose and throat irritation. Causes lung irritation. Vapor harmful. May affect the brain or nervous system causing dizziness, headache or nausea. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes). Effects Of Overexposure - Ingestion: Harmful or fatal if swallowed. Ingestion of ethylene glycol can cause gastrointestinal irritation, nausea, vomiting, diarrhea and if ingested in sufficient quantities, death. Effects Of Overexposure - Chronic Hazards: Studies have shown that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals. Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Repeated or prolonged exposure may cause respiratory system damage. Prolonged and repeated skin contact may cause irritation and possibly dermatitis. Formaldehyde vapor is a known animal carcinogen IARC and NTP and is considered possibly carcinogenic to humans by inhalation. Ethylene glycol has been shown to cause birth defects in laboratory animals. Overexposure may cause kidney, cardiovascular, skin and liver damage. Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation Medical Conditions which May be Aggravated by Exposure: None known. Section 4 - First Aid Measures First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes until irritation subsides. Get medical attention immediately. First Aid - Skin Contact: Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing. First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If continued breathing difficulty is experienced, get medical attention immediately. First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately. Note to Physician: No Information. COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arise from any of the above routes of entry. Section 5 - Fire Fighting Measures Flash Point, F: > 200 Fahrenheit Method: (Seta Closed Cup) Lower Explosive Limit, %: Not Established Upper Explosive Limit, %: Not Established Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog Unusual Fire And Explosion Hazards: No special protective measures against fire required. Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent) and full protective gear. Use water spray to cool exposed surfaces. Section 6 - Accidental Release Measures Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use absorbent material or scrape up dried material and place in container. Section 7 - Handling And Storage Handling: DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN! Use only with adequate ventilation. Ensure fresh air entry during application and drying. Avoid breathing vapor and contact with eyes, skin and clothing. Wash thoroughly after handling. Storage: Close container after each use. Store containers away from excessive heat and freezing. Store away from caustics and oxidizers. Do not store at temperatures above 120 degrees F. Section 8 - Exposure Controls / Personal Protection Precautionary Measures: No Information. Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Ensure adequate ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient concentrations below recommended exposure limits. Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSH-approved air purifying respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where airborne concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Skin Protection: Rubber gloves. Eye Protection: Goggles or safety glasses with side shields. Other protective equipment: Not required under normal use. Hygienic Practices: Remove and wash contaminated clothing before re-use. Wash hands before breaks and at the end of workday. Section 9 - Physical And Chemical Properties Boiling Range: Odor: Appearance: Solubility in H2O: Freeze Point: Vapor Pressure: Physical State: Not Established Not Established A white to off white paste product Not Established Not Established Not Established Paste Vapor Density: Odor Threshold: Evaporation Rate: Specific Gravity: pH: Viscosity: Not Established Not Established Not Established 1.826 Between 7.0 and 12.0 Not Established (See section 16 for abbreviation legend) Section 10 - Stability And Reactivity Conditions To Avoid: Excessive heat and freezing. Incompatibility: Incompatible with strong bases and oxidizing agents. Hazardous Decomposition Products: Normal decomposition products, i.e. COx, NOx. Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions. Stability: Stable under recommended storage conditions. Section 11 - Toxicological Information Product LD50: Not Established Product LC50: Not Established CASRN Chemical Name LD50 LC50 107-21-1 50-00-0 107-13-1 Ethylene glycol Formaldehyde Acrylonitrile Rat:4700 mg/kg ------------Oral Rat:78 mg/kg Rat:10876 mg/kg Rat:203 mg/m3 Rat:425 ppm/4H Carcinogenity: CAS No. Chemical Name ACGIH OSHA IARC NTP 14808-60 -7 50-00-0 Silica, crystalline Formaldehyde ----Potential cancer hazard. ----Probable carcinogen. Known carcinogen. Anticipated carcinogen. 107-13-1 Acrylonitrile Cancer hazard. Possible carcinogen. Anticipated carcinogen. 75-07-0 Acetaldehyde Suspected human carcinogen. Suspected human carcinogen. Confirmed animal carcinogen with unknown relevance to humans. Confirmed animal carcinogen with unknown relevance to humans. ----- Possible carcinogen. Anticipated carcinogen. Significant Data with Possible Relevance to Humans: This product contains trace amounts of free formaldehyde. OSHA, NTP and IARC identify formaldehyde as a potential carcinogen. Formaldehyde has been shown to cause mutations in a variety of invitro test systems, the significance of which to humans is unknown. In a two-year inhalation study, rats showed carcinogenic effects in the respiratory system at 15 ppm of formaldehyde. There should be minimal risk when used with ventilation adequate to keep the atmospheric concentration of formaldehyde below the recommended exposure limits. Maintain adequate ventilation to prevent exposure above current OSHA / ACGIH exposure limits. Workplace monitoring of the air to define formaldehyde exposure levels may be necessary. Section 12 - Ecological Information Ecological Information: Ecological injuries are not known or expected under normal use. Section 13 - Disposal Information Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA Waste Code if Discarded (40 CFR Section 261): This product does not meet the definition of a hazardous waste according to U.S. EPA Hazardous Waste Management Regulation, 40 CFR Section 261. Section 14 - Transportation Information DOT Proper Shipping Name: Not Regulated DOT Technical Name: N.A. DOT Hazard Class: N.A. Packing Group: Hazard Subclass: DOT UN/NA Number: N.A. N.A. N.A. Section 15 - Regulatory Information CERCLA - SARA Hazard Category: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Immediate Health Hazard, Chronic Health Hazard SARA Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Chemical Name CAS Number Ethylene glycol 107-21-1 Toxic Substances Control Act: All ingredients in this product are either on TSCA inventory list, or otherwise exempt. This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: None U.S. State Regulations: New Jersey Right-to-Know: The following materials are non-hazardous, but are among the top five components in this product: Chemical Name CAS Number Non-Hazardous Polymer Water Proprietary 7732-18-5 Pennsylvania Right-to-Know: The following non-hazardous ingredients are present in the product at greater than 3%: Chemical Name CAS Number Non-Hazardous Polymer Water Proprietary 7732-18-5 California Proposition 65: Warning: The following ingredients present in the product are known to the State of California to cause cancer: Chemical Name CAS Number Definition Date Listed Silica, crystalline Formaldehyde Acrylonitrile Acetaldehyde 14808-60 -7 50-00-0 107-13-1 75-07-0 Carcinogenic. Carcinogenic. Carcinogenic. Carcinogenic. Listed: October 1, 1988 Listed: January 1, 1988 Listed: July 1, 1987 Listed: April 1, 1988 Warning: The following ingredients present in the product are known to the State of California to cause birth defects or other reproductive harm. None Section 16 - Other Information HMIS Ratings: Health: Flammability: VOLATILE ORGANIC COMPOUNDS, GR/LTR: 48.7 Reactivity: LB/GAL: 0.4 Personal Protection: WT%: 2.2 REASON FOR REVISION: Legend: N.A. – Not Applicable ACGIH – American Conference of Governmental Industrial Hygienists N.E. – Not Established SARA – Superfund Amendments and Reauthorization Act of 1986 N.D. – Not Determined NJRTK – New Jersey Right-to-Know Law VOC – Volatile Organic Compound OSHA – Occupational Safety and Health Administration PEL – Permissible Exposure Limit HMIS – Hazardous Materials Identification System TLV – Threshold Limit Value NTP – National Toxicology Program STEL – Short Term Exposure Limit CEIL – Ceiling Exposure Limit LD50 – Lethal Dose 50 LC50 – Lethal Concentration 50 F – Degree Fahrenheit C – Degree Celcius CASRN – The Chemical Abstracts Service Registry Number MSDS – Material Safety Data Sheet DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context of the intended use and (ii) determine if they are appropriate. Page 1 of 7 Material Safety Data Sheet 24 Hour Emergency Phone Numbers: Medical: 1-800-327-3874 1-513-558-5111 Transportation: 1-800-535-5053 1-352-323-3500 NOTE: National Response Center emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals. IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16. Section 1 - Chemical Product / Company Information This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request. Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en español a su solicitud. Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere. Product Name: Product UPC Number: Product Use/Class: DAPTEX® LATEX FOAM MP SEALANT 7079818826 7079818833 7079818834 7079871060 Pressurized Latex Foam Manufacturer: DAP Inc. 2400 Boston Street Suite 200 Baltimore, MD 21224-4723 888-327-8477 (non-emergency matters) Revision Date: 02/23/2004 Supercedes: 01/19/2004 MSDS Number: 00077346001 Section 2 - Composition / Information On Ingredients Chemical Name Isopropyl alcohol Ethylene glycol Dimethyl ether Propane n-Butane Vinyl acetate Aliphatic amines CASRN 67-63 -0 107-21-1 115-10-6 74-98 -6 106-97-8 108-05-4 Proprietary WT% 1-5 1-5 1-5 1-5 1-5 0.1-1.0 0.1-1.0. ACGIH TWA ACGIH STEL ACGIH CEIL OSHA TWA 200 PPM 400 PPM N.E. 400 PPM N.E. N.E. 100 MGM3 N.E. N.E. N.E. N.E. N.E. 2500 PPM N.E. N.E. 1000 PPM 800 PPM N.E. N.E. N.E. 10 PPM 15 PPM N.E. N.E. N.E. N.E. N.E. N.E. OSHA STEL N.E. N.E. N.E. N.E. N.E. N.E. N.E. OSHA CEIL N.E. N.E. N.E. N.E. N.E. N.E. N.E. Skin No No No No No No N.E. Exposure Notes: Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary between states. Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work practices Section 3 - Hazards Identification Page 2 of 7 Emergency Overview: A white to off-white liquid with a slight alcoholic odor. DANGER! Contents under pressure. Harmful if swallowed or absorbed through the skin. Exposure to temperatures above 120 'F may cause can to rupture. May cause eye, skin, nose, throat and respiratory tract irritation. Vapors harmful if inhaled. Do not puncture can. This product contains ethylene glycol. Refer to other MSDS sections for other detailed information. Effects Of Overexposure - Eye Contact: May cause eye irritation. Effects Of Overexposure - Skin Contact: May causes skin irritation. Prolonged or repeated contact with skin may cause irritation. Harmful if absorbed through the skin. Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes). Vapor harmful. May affect the brain or nervous system causing dizziness, headache or nausea. Causes nose and throat irritation. Effects Of Overexposure - Ingestion: Harmful or fatal if swallowed. Ingestion of ethylene glycol can cause gastrointestinal irritation, nausea, vomiting, diarrhea and if ingested in sufficient quantities, death. Effects Of Overexposure - Chronic Hazards: This product contains vinyl acetate which is classified as a class 2B carcinogen by IARC. Vinyl acetate was found to cause cancer in the respiratory tract of laboratory animals. There is no evidence that vinyl acetate causes cancer in humans. The IARC published a monograph on vinyl acetate (1995). In this monograph, IARC indicates "there is inadequate evidence in humans for carcinogenicity of vinyl acetate. There is limited evidence in experimental animals for the carcinogenicity of vinyl acetate." Normally, this lack of conclusive evidence would place a substance in the IARC 3 classification (not classified as a human carcinogen). However, because vinyl acetate is metabolized to acetaldehyde, which has an IARC 2B (possibly carcinogenic to humans) classification, it also has been listed under Category 2B. Studies have shown that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals. Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Ethylene glycol has been shown to cause birth defects in laboratory animals. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Repeated or prolonged exposure may cause respiratory system damage. Prolonged and repeated skin contact may cause irritation and possibly dermatitis. Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation, Eye Contact Medical Conditions which May be Aggravated by Exposure: None known. Section 4 - First Aid Measures First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes until irritation subsides. Get medical attention immediately. First Aid - Skin Contact: Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing. First Aid - Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately. Note to Physician: No Information. Page 3 of 7 COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arise from any of the above routes of entry. Section 5 - Fire Fighting Measures Flash Point, F: Aerosol (Extremely Flammable) Method: ( Not Applicable) Lower Explosive Limit, %: Not Established Upper Explosive Limit, %: Not Established Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog Unusual Fire And Explosion Hazards: Do not smoke. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition during use and until all vapors are gone. Store away from caustics and oxidizers. Containers may explode if exposed to extreme heat. Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent) and full protective gear. Use water spray to cool exposed surfaces. Section 6 - Accidental Release Measures Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use absorbent material or scrape up dried material and place in container. Section 7 - Handling And Storage Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Provide fresh air such that chemical odors cannot be detected during use and while drying. Use only with adequate ventilation. Ensure fresh air entry during application and drying. Avoid breathing vapor and contact with eyes, skin and clothing. Make sure nozzle is directed away from yourself prior to discharge. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Open all windows and doors or use other means to ensure crossventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous conditions. Construction and repair activities can adversely affect indoor air quality. Consult with occupants or a representative (i.e. maintenance, building manager, industrial hygienist, or safety officer) to determine ways to minimize impact. Wash thoroughly after handling. Storage: Store containers away from excessive heat and freezing. Do not store at temperatures above 120 degrees F. Keep away from heat and sources of ignition. Protect material from direct sunlight. Store away from caustics and oxidizers. Section 8 - Exposure Controls / Personal Protection Precautionary Measures: Please refer to other sections and subsections of this MSDS. Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Vapors are heavier than air and may spread along floors. Check all low areas for presence of vapor. Ensure adequate ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient concentrations below recommended exposure limits. Provide sufficient general and/or local exhaust ventilation to maintain exposure below recommended exposure limit. Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSHapproved air purifying respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where airborne concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. If concentrations exceed the exposure limits specified, use of a NIOSH- Page 4 of 7 approved supplied air respirator is recommended. Where the protection factor is exceeded, use of a Self Contained Breathing Apparatus (SCBA) may be necessary. No personal respiratory protective equipment normally required. Skin Protection: Rubber gloves. Eye Protection: Goggles or safety glasses with side shields. Other protective equipment: Not required under normal use. Hygienic Practices: Remove and wash contaminated clothing before re-use. Wash hands before breaks and at the end of workday. Section 9 - Physical And Chemical Properties Boiling Range: Odor: Appearance: Not Established Slight Alcoholic White foaming liquid Vapor Density: Odor Threshold: Evaporation Rate: Heavier than air Not Established Solubility in H2O: Freeze Point: Vapor Pressure: Physical State: Not Established Not Established Not Established Liquid Specific Gravity: pH: Viscosity: 0.996 Between 7.0 and 12.0 Not Established Slower than n-butyl acetate When reported, the vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally. (See section 16 for abbreviation legend) Section 10 - Stability And Reactivity Conditions To Avoid: Excessive heat and freezing. Incompatibility: Incompatible with strong bases and oxidizing agents. Hazardous Decomposition Products: Normal decomposition products, i.e. COx, NOx. Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions. Stability: Stable under recommended storage conditions. Section 11 - Toxicological Information Product LD50: Not Established CASRN Chemical Name LD50 67-63-0 Isopropyl alcohol Rat:5045 mg/kg Rat:16000 ppm/8H 107-21-1 Ethylene glycol Rat:4700 mg/kg ------------- 106-97-8 n-Butane ------------- Rat:658 gm/m3/4H 108-05-4 Vinyl acetate ------------- Rat:11400 mg/m3/4H Carcinogenicity: Product LC50: Not Established LC50 Page 5 of 7 CAS No. 108-05-4 Chemical Name ACGIH OSHA IARC NTP Vinyl acetate Confirmed animal carcinogen with unknown relevance to humans. ----- Possible carcinogen. ----- Significant Data with Possible Relevance to Humans: None Section 12 - Ecological Information Ecological Information: Ecological injuries are not known or expected under normal use. Section 13 - Disposal Information Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA Waste Code if Discarded (40 CFR Section 261): D001 if residue remains Section 14 - Transportation Information DOT Proper Shipping Name: DOT Technical Name: DOT Hazard Class: Consumer Commodity Packing Group: N.A. Hazard Subclass: ORM-D Other regulated materialDOT UN/NA Number: N.A. N.A. N.A. Section 15 - Regulatory Information CERCLA - SARA Hazard Category: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Immediate Health Hazard, Chronic Health Hazard SARA Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Chemical Name CAS Number Isopropyl alcohol Ethylene glycol Vinyl acetate 67-63-0 107-21-1 108-05-4 Toxic Substances Control Act: All ingredients in this product are either on TSCA inventory list, or otherwise exempt. This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: Page 6 of 7 None U.S. State Regulations: New Jersey Right-to-Know: The following materials are non-hazardous, but are among the top five components in this product: Chemical Name CAS Number Non-Hazardous Polymer Water Proprietary 7732-18-5 Pennsylvania Right-to-Know: The following non-hazardous ingredients are present in the product at greater than 3%: Chemical Name CAS Number Non-Hazardous Polymer Water Proprietary 7732-18-5 California Proposition 65: Warning: The following ingredients present in the product are known to the State of California to cause cancer: None Warning: The following ingredients present in the product are known to the State of California to cause birth defects or other reproductive harm. None Section 16 - Other Information HMIS Ratings: Health: 0 Flammability: 3 Reactivity: 0 VOLATILE ORGANIC COMPOUNDS, GR/LTR: 170.3 LB/GAL: 1.4 WT%: 11.3 REASON FOR REVISION: Legend: N.A. – Not Applicable ACGIH – American Conference of Governmental Industrial Hygienists N.E. – Not Established SARA – Superfund Amendments and Reauthorization Act of 1986 N.D. – Not Determined NJRTK – New Jersey Right-to-Know Law VOC – Volatile Organic Compound OSHA – Occupational Safety and Health Administration PEL – Permissible Exposure Limit HMIS – Hazardous Materials Identification System TLV – Threshold Limit Value NTP – National Toxicology Program STEL – Short Term Exposure Limit CEIL – Ceiling Exposure Limit Page 7 of 7 LD50 – Lethal Dose 50 LC50 – Lethal Concentration 50 F – Degree Fahrenheit C – Degree Celcius MSDS – Material Safety Data Sheet CASRN – The Chemical Abstracts Service Registry Number DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context of the intended use and (ii) determine if they are appropriate. Page 1 of 7 Material Safety Data Sheet 24 Hour Emergency Phone Numbers: Medical: 1-800-327-3874 1-513-558-5111 Transportation: 1-800-535-5053 1-352-323-3500 NOTE: National Response Center emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals. IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16. Section 1 - Chemical Product / Company Information This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request. Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en español a su solicitud. Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere. Product Name: Product UPC Number: Product Use/Class: DAPTEX® LATEX FOAM MP SEALANT 7079818826 7079818833 7079818834 7079871060 Pressurized Latex Foam Manufacturer: DAP Inc. 2400 Boston Street Suite 200 Baltimore, MD 21224-4723 888-327-8477 (non-emergency matters) Revision Date: 02/23/2004 Supercedes: 01/19/2004 MSDS Number: 00077346001 Section 2 - Composition / Information On Ingredients Chemical Name Isopropyl alcohol Ethylene glycol Dimethyl ether Propane n-Butane Vinyl acetate Aliphatic amines CASRN 67-63 -0 107-21-1 115-10-6 74-98 -6 106-97-8 108-05-4 Proprietary WT% 1-5 1-5 1-5 1-5 1-5 0.1-1.0 0.1-1.0. ACGIH TWA ACGIH STEL ACGIH CEIL OSHA TWA 200 PPM 400 PPM N.E. 400 PPM N.E. N.E. 100 MGM3 N.E. N.E. N.E. N.E. N.E. 2500 PPM N.E. N.E. 1000 PPM 800 PPM N.E. N.E. N.E. 10 PPM 15 PPM N.E. N.E. N.E. N.E. N.E. N.E. OSHA STEL N.E. N.E. N.E. N.E. N.E. N.E. N.E. OSHA CEIL N.E. N.E. N.E. N.E. N.E. N.E. N.E. Skin No No No No No No N.E. Exposure Notes: Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary between states. Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work practices Section 3 - Hazards Identification Page 2 of 7 Emergency Overview: A white to off-white liquid with a slight alcoholic odor. DANGER! Contents under pressure. Harmful if swallowed or absorbed through the skin. Exposure to temperatures above 120 'F may cause can to rupture. May cause eye, skin, nose, throat and respiratory tract irritation. Vapors harmful if inhaled. Do not puncture can. This product contains ethylene glycol. Refer to other MSDS sections for other detailed information. Effects Of Overexposure - Eye Contact: May cause eye irritation. Effects Of Overexposure - Skin Contact: May causes skin irritation. Prolonged or repeated contact with skin may cause irritation. Harmful if absorbed through the skin. Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes). Vapor harmful. May affect the brain or nervous system causing dizziness, headache or nausea. Causes nose and throat irritation. Effects Of Overexposure - Ingestion: Harmful or fatal if swallowed. Ingestion of ethylene glycol can cause gastrointestinal irritation, nausea, vomiting, diarrhea and if ingested in sufficient quantities, death. Effects Of Overexposure - Chronic Hazards: This product contains vinyl acetate which is classified as a class 2B carcinogen by IARC. Vinyl acetate was found to cause cancer in the respiratory tract of laboratory animals. There is no evidence that vinyl acetate causes cancer in humans. The IARC published a monograph on vinyl acetate (1995). In this monograph, IARC indicates "there is inadequate evidence in humans for carcinogenicity of vinyl acetate. There is limited evidence in experimental animals for the carcinogenicity of vinyl acetate." Normally, this lack of conclusive evidence would place a substance in the IARC 3 classification (not classified as a human carcinogen). However, because vinyl acetate is metabolized to acetaldehyde, which has an IARC 2B (possibly carcinogenic to humans) classification, it also has been listed under Category 2B. Studies have shown that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals. Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Ethylene glycol has been shown to cause birth defects in laboratory animals. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Repeated or prolonged exposure may cause respiratory system damage. Prolonged and repeated skin contact may cause irritation and possibly dermatitis. Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation, Eye Contact Medical Conditions which May be Aggravated by Exposure: None known. Section 4 - First Aid Measures First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes until irritation subsides. Get medical attention immediately. First Aid - Skin Contact: Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing. First Aid - Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately. Note to Physician: No Information. Page 3 of 7 COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arise from any of the above routes of entry. Section 5 - Fire Fighting Measures Flash Point, F: Aerosol (Extremely Flammable) Method: ( Not Applicable) Lower Explosive Limit, %: Not Established Upper Explosive Limit, %: Not Established Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog Unusual Fire And Explosion Hazards: Do not smoke. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition during use and until all vapors are gone. Store away from caustics and oxidizers. Containers may explode if exposed to extreme heat. Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent) and full protective gear. Use water spray to cool exposed surfaces. Section 6 - Accidental Release Measures Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use absorbent material or scrape up dried material and place in container. Section 7 - Handling And Storage Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Provide fresh air such that chemical odors cannot be detected during use and while drying. Use only with adequate ventilation. Ensure fresh air entry during application and drying. Avoid breathing vapor and contact with eyes, skin and clothing. Make sure nozzle is directed away from yourself prior to discharge. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Open all windows and doors or use other means to ensure crossventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous conditions. Construction and repair activities can adversely affect indoor air quality. Consult with occupants or a representative (i.e. maintenance, building manager, industrial hygienist, or safety officer) to determine ways to minimize impact. Wash thoroughly after handling. Storage: Store containers away from excessive heat and freezing. Do not store at temperatures above 120 degrees F. Keep away from heat and sources of ignition. Protect material from direct sunlight. Store away from caustics and oxidizers. Section 8 - Exposure Controls / Personal Protection Precautionary Measures: Please refer to other sections and subsections of this MSDS. Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Vapors are heavier than air and may spread along floors. Check all low areas for presence of vapor. Ensure adequate ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient concentrations below recommended exposure limits. Provide sufficient general and/or local exhaust ventilation to maintain exposure below recommended exposure limit. Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSHapproved air purifying respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where airborne concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. If concentrations exceed the exposure limits specified, use of a NIOSH- Page 4 of 7 approved supplied air respirator is recommended. Where the protection factor is exceeded, use of a Self Contained Breathing Apparatus (SCBA) may be necessary. No personal respiratory protective equipment normally required. Skin Protection: Rubber gloves. Eye Protection: Goggles or safety glasses with side shields. Other protective equipment: Not required under normal use. Hygienic Practices: Remove and wash contaminated clothing before re-use. Wash hands before breaks and at the end of workday. Section 9 - Physical And Chemical Properties Boiling Range: Odor: Appearance: Not Established Slight Alcoholic White foaming liquid Vapor Density: Odor Threshold: Evaporation Rate: Heavier than air Not Established Solubility in H2O: Freeze Point: Vapor Pressure: Physical State: Not Established Not Established Not Established Liquid Specific Gravity: pH: Viscosity: 0.996 Between 7.0 and 12.0 Not Established Slower than n-butyl acetate When reported, the vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally. (See section 16 for abbreviation legend) Section 10 - Stability And Reactivity Conditions To Avoid: Excessive heat and freezing. Incompatibility: Incompatible with strong bases and oxidizing agents. Hazardous Decomposition Products: Normal decomposition products, i.e. COx, NOx. Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions. Stability: Stable under recommended storage conditions. Section 11 - Toxicological Information Product LD50: Not Established CASRN Chemical Name LD50 67-63-0 Isopropyl alcohol Rat:5045 mg/kg Rat:16000 ppm/8H 107-21-1 Ethylene glycol Rat:4700 mg/kg ------------- 106-97-8 n-Butane ------------- Rat:658 gm/m3/4H 108-05-4 Vinyl acetate ------------- Rat:11400 mg/m3/4H Carcinogenicity: Product LC50: Not Established LC50 Page 5 of 7 CAS No. 108-05-4 Chemical Name ACGIH OSHA IARC NTP Vinyl acetate Confirmed animal carcinogen with unknown relevance to humans. ----- Possible carcinogen. ----- Significant Data with Possible Relevance to Humans: None Section 12 - Ecological Information Ecological Information: Ecological injuries are not known or expected under normal use. Section 13 - Disposal Information Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA Waste Code if Discarded (40 CFR Section 261): D001 if residue remains Section 14 - Transportation Information DOT Proper Shipping Name: DOT Technical Name: DOT Hazard Class: Consumer Commodity Packing Group: N.A. Hazard Subclass: ORM-D Other regulated materialDOT UN/NA Number: N.A. N.A. N.A. Section 15 - Regulatory Information CERCLA - SARA Hazard Category: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Immediate Health Hazard, Chronic Health Hazard SARA Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Chemical Name CAS Number Isopropyl alcohol Ethylene glycol Vinyl acetate 67-63-0 107-21-1 108-05-4 Toxic Substances Control Act: All ingredients in this product are either on TSCA inventory list, or otherwise exempt. This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: Page 6 of 7 None U.S. State Regulations: New Jersey Right-to-Know: The following materials are non-hazardous, but are among the top five components in this product: Chemical Name CAS Number Non-Hazardous Polymer Water Proprietary 7732-18-5 Pennsylvania Right-to-Know: The following non-hazardous ingredients are present in the product at greater than 3%: Chemical Name CAS Number Non-Hazardous Polymer Water Proprietary 7732-18-5 California Proposition 65: Warning: The following ingredients present in the product are known to the State of California to cause cancer: None Warning: The following ingredients present in the product are known to the State of California to cause birth defects or other reproductive harm. None Section 16 - Other Information HMIS Ratings: Health: 0 Flammability: 3 Reactivity: 0 VOLATILE ORGANIC COMPOUNDS, GR/LTR: 170.3 LB/GAL: 1.4 WT%: 11.3 REASON FOR REVISION: Legend: N.A. – Not Applicable ACGIH – American Conference of Governmental Industrial Hygienists N.E. – Not Established SARA – Superfund Amendments and Reauthorization Act of 1986 N.D. – Not Determined NJRTK – New Jersey Right-to-Know Law VOC – Volatile Organic Compound OSHA – Occupational Safety and Health Administration PEL – Permissible Exposure Limit HMIS – Hazardous Materials Identification System TLV – Threshold Limit Value NTP – National Toxicology Program STEL – Short Term Exposure Limit CEIL – Ceiling Exposure Limit Page 7 of 7 LD50 – Lethal Dose 50 LC50 – Lethal Concentration 50 F – Degree Fahrenheit C – Degree Celcius MSDS – Material Safety Data Sheet CASRN – The Chemical Abstracts Service Registry Number DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context of the intended use and (ii) determine if they are appropriate. Page 1 of 7 Material Safety Data Sheet 24 Hour Emergency Phone Numbers: Medical: 1-800-327-3874 1-513-558-5111 Transportation: 1-800-535-5053 1-352-323-3500 NOTE: National Response Center emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals. IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16. Section 1 - Chemical Product / Company Information This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request. Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en español a su solicitud. Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere. Product Name: Product UPC Number: Product Use/Class: DAPTEX® LATEX FOAM MP SEALANT 7079818826 7079818833 7079818834 7079871060 Pressurized Latex Foam Manufacturer: DAP Inc. 2400 Boston Street Suite 200 Baltimore, MD 21224-4723 888-327-8477 (non-emergency matters) Revision Date: 02/23/2004 Supercedes: 01/19/2004 MSDS Number: 00077346001 Section 2 - Composition / Information On Ingredients Chemical Name Isopropyl alcohol Ethylene glycol Dimethyl ether Propane n-Butane Vinyl acetate Aliphatic amines CASRN 67-63 -0 107-21-1 115-10-6 74-98 -6 106-97-8 108-05-4 Proprietary WT% 1-5 1-5 1-5 1-5 1-5 0.1-1.0 0.1-1.0. ACGIH TWA ACGIH STEL ACGIH CEIL OSHA TWA 200 PPM 400 PPM N.E. 400 PPM N.E. N.E. 100 MGM3 N.E. N.E. N.E. N.E. N.E. 2500 PPM N.E. N.E. 1000 PPM 800 PPM N.E. N.E. N.E. 10 PPM 15 PPM N.E. N.E. N.E. N.E. N.E. N.E. OSHA STEL N.E. N.E. N.E. N.E. N.E. N.E. N.E. OSHA CEIL N.E. N.E. N.E. N.E. N.E. N.E. N.E. Skin No No No No No No N.E. Exposure Notes: Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary between states. Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work practices Section 3 - Hazards Identification Page 2 of 7 Emergency Overview: A white to off-white liquid with a slight alcoholic odor. DANGER! Contents under pressure. Harmful if swallowed or absorbed through the skin. Exposure to temperatures above 120 'F may cause can to rupture. May cause eye, skin, nose, throat and respiratory tract irritation. Vapors harmful if inhaled. Do not puncture can. This product contains ethylene glycol. Refer to other MSDS sections for other detailed information. Effects Of Overexposure - Eye Contact: May cause eye irritation. Effects Of Overexposure - Skin Contact: May causes skin irritation. Prolonged or repeated contact with skin may cause irritation. Harmful if absorbed through the skin. Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes). Vapor harmful. May affect the brain or nervous system causing dizziness, headache or nausea. Causes nose and throat irritation. Effects Of Overexposure - Ingestion: Harmful or fatal if swallowed. Ingestion of ethylene glycol can cause gastrointestinal irritation, nausea, vomiting, diarrhea and if ingested in sufficient quantities, death. Effects Of Overexposure - Chronic Hazards: This product contains vinyl acetate which is classified as a class 2B carcinogen by IARC. Vinyl acetate was found to cause cancer in the respiratory tract of laboratory animals. There is no evidence that vinyl acetate causes cancer in humans. The IARC published a monograph on vinyl acetate (1995). In this monograph, IARC indicates "there is inadequate evidence in humans for carcinogenicity of vinyl acetate. There is limited evidence in experimental animals for the carcinogenicity of vinyl acetate." Normally, this lack of conclusive evidence would place a substance in the IARC 3 classification (not classified as a human carcinogen). However, because vinyl acetate is metabolized to acetaldehyde, which has an IARC 2B (possibly carcinogenic to humans) classification, it also has been listed under Category 2B. Studies have shown that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals. Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Ethylene glycol has been shown to cause birth defects in laboratory animals. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Repeated or prolonged exposure may cause respiratory system damage. Prolonged and repeated skin contact may cause irritation and possibly dermatitis. Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation, Eye Contact Medical Conditions which May be Aggravated by Exposure: None known. Section 4 - First Aid Measures First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes until irritation subsides. Get medical attention immediately. First Aid - Skin Contact: Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing. First Aid - Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately. Note to Physician: No Information. Page 3 of 7 COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arise from any of the above routes of entry. Section 5 - Fire Fighting Measures Flash Point, F: Aerosol (Extremely Flammable) Method: ( Not Applicable) Lower Explosive Limit, %: Not Established Upper Explosive Limit, %: Not Established Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog Unusual Fire And Explosion Hazards: Do not smoke. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition during use and until all vapors are gone. Store away from caustics and oxidizers. Containers may explode if exposed to extreme heat. Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent) and full protective gear. Use water spray to cool exposed surfaces. Section 6 - Accidental Release Measures Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use absorbent material or scrape up dried material and place in container. Section 7 - Handling And Storage Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Provide fresh air such that chemical odors cannot be detected during use and while drying. Use only with adequate ventilation. Ensure fresh air entry during application and drying. Avoid breathing vapor and contact with eyes, skin and clothing. Make sure nozzle is directed away from yourself prior to discharge. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Open all windows and doors or use other means to ensure crossventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous conditions. Construction and repair activities can adversely affect indoor air quality. Consult with occupants or a representative (i.e. maintenance, building manager, industrial hygienist, or safety officer) to determine ways to minimize impact. Wash thoroughly after handling. Storage: Store containers away from excessive heat and freezing. Do not store at temperatures above 120 degrees F. Keep away from heat and sources of ignition. Protect material from direct sunlight. Store away from caustics and oxidizers. Section 8 - Exposure Controls / Personal Protection Precautionary Measures: Please refer to other sections and subsections of this MSDS. Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Vapors are heavier than air and may spread along floors. Check all low areas for presence of vapor. Ensure adequate ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient concentrations below recommended exposure limits. Provide sufficient general and/or local exhaust ventilation to maintain exposure below recommended exposure limit. Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSHapproved air purifying respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where airborne concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. If concentrations exceed the exposure limits specified, use of a NIOSH- Page 4 of 7 approved supplied air respirator is recommended. Where the protection factor is exceeded, use of a Self Contained Breathing Apparatus (SCBA) may be necessary. No personal respiratory protective equipment normally required. Skin Protection: Rubber gloves. Eye Protection: Goggles or safety glasses with side shields. Other protective equipment: Not required under normal use. Hygienic Practices: Remove and wash contaminated clothing before re-use. Wash hands before breaks and at the end of workday. Section 9 - Physical And Chemical Properties Boiling Range: Odor: Appearance: Not Established Slight Alcoholic White foaming liquid Vapor Density: Odor Threshold: Evaporation Rate: Heavier than air Not Established Solubility in H2O: Freeze Point: Vapor Pressure: Physical State: Not Established Not Established Not Established Liquid Specific Gravity: pH: Viscosity: 0.996 Between 7.0 and 12.0 Not Established Slower than n-butyl acetate When reported, the vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally. (See section 16 for abbreviation legend) Section 10 - Stability And Reactivity Conditions To Avoid: Excessive heat and freezing. Incompatibility: Incompatible with strong bases and oxidizing agents. Hazardous Decomposition Products: Normal decomposition products, i.e. COx, NOx. Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions. Stability: Stable under recommended storage conditions. Section 11 - Toxicological Information Product LD50: Not Established CASRN Chemical Name LD50 67-63-0 Isopropyl alcohol Rat:5045 mg/kg Rat:16000 ppm/8H 107-21-1 Ethylene glycol Rat:4700 mg/kg ------------- 106-97-8 n-Butane ------------- Rat:658 gm/m3/4H 108-05-4 Vinyl acetate ------------- Rat:11400 mg/m3/4H Carcinogenicity: Product LC50: Not Established LC50 Page 5 of 7 CAS No. 108-05-4 Chemical Name ACGIH OSHA IARC NTP Vinyl acetate Confirmed animal carcinogen with unknown relevance to humans. ----- Possible carcinogen. ----- Significant Data with Possible Relevance to Humans: None Section 12 - Ecological Information Ecological Information: Ecological injuries are not known or expected under normal use. Section 13 - Disposal Information Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA Waste Code if Discarded (40 CFR Section 261): D001 if residue remains Section 14 - Transportation Information DOT Proper Shipping Name: DOT Technical Name: DOT Hazard Class: Consumer Commodity Packing Group: N.A. Hazard Subclass: ORM-D Other regulated materialDOT UN/NA Number: N.A. N.A. N.A. Section 15 - Regulatory Information CERCLA - SARA Hazard Category: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Immediate Health Hazard, Chronic Health Hazard SARA Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Chemical Name CAS Number Isopropyl alcohol Ethylene glycol Vinyl acetate 67-63-0 107-21-1 108-05-4 Toxic Substances Control Act: All ingredients in this product are either on TSCA inventory list, or otherwise exempt. This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: Page 6 of 7 None U.S. State Regulations: New Jersey Right-to-Know: The following materials are non-hazardous, but are among the top five components in this product: Chemical Name CAS Number Non-Hazardous Polymer Water Proprietary 7732-18-5 Pennsylvania Right-to-Know: The following non-hazardous ingredients are present in the product at greater than 3%: Chemical Name CAS Number Non-Hazardous Polymer Water Proprietary 7732-18-5 California Proposition 65: Warning: The following ingredients present in the product are known to the State of California to cause cancer: None Warning: The following ingredients present in the product are known to the State of California to cause birth defects or other reproductive harm. None Section 16 - Other Information HMIS Ratings: Health: 0 Flammability: 3 Reactivity: 0 VOLATILE ORGANIC COMPOUNDS, GR/LTR: 170.3 LB/GAL: 1.4 WT%: 11.3 REASON FOR REVISION: Legend: N.A. – Not Applicable ACGIH – American Conference of Governmental Industrial Hygienists N.E. – Not Established SARA – Superfund Amendments and Reauthorization Act of 1986 N.D. – Not Determined NJRTK – New Jersey Right-to-Know Law VOC – Volatile Organic Compound OSHA – Occupational Safety and Health Administration PEL – Permissible Exposure Limit HMIS – Hazardous Materials Identification System TLV – Threshold Limit Value NTP – National Toxicology Program STEL – Short Term Exposure Limit CEIL – Ceiling Exposure Limit Page 7 of 7 LD50 – Lethal Dose 50 LC50 – Lethal Concentration 50 F – Degree Fahrenheit C – Degree Celcius MSDS – Material Safety Data Sheet CASRN – The Chemical Abstracts Service Registry Number DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context of the intended use and (ii) determine if they are appropriate. MATERIAL SAFETY DATA SHEET MSDS Name: SA-167 SILICONIZED ACRYLIC LATEX CAULK MSDS Number: 16711-001 Version Number 2 MSDS Date: SEP-09-2002 Page Number: 1 ----------------------------------------------------------------------------- SECTION I - PRODUCT AND COMPANY INFORMATION Product Name: HMIS Hazard Rating: SA-167 SILICONIZED ACRYLIC LATEX CAULK Health: 1 Fire: 0 Reactivity: 0 PPE: B Company Identification: OSI SEALANTS, INC.a Subsidiary of Sovereign Specialty Chems. 7405 PRODUCTION DRIVE MENTOR OH 44060 Information phone/Fax: Emergency Phone (24 hour) Chemtrec (outside-USA) (440) 255-8900 (440) 974-8358 CHEMTREC (800) 424-9300 (703) 527-3887 Product Class Trade Name Product Code CAULK PRO-SERIES 16711-XXX SECTION II - INGREDIENT AND HAZARD INFORMATION Hazardous Ingredient Name CAS Number Percent Titanium Dioxide ** 13463-67-7 < 5.0 Y ETHYLENE GLYCOL 107-21-1 < 2.0 Y MINERAL SPIRITS 64742-48-9 < 2.0 Y TSCA Ingredient Notes: Remaining ingredients are not considered OSHA hazardous. **The main hazard for Titanium Dioxide is dust inhalation. Because of its incorporation into the caulk, exposure by inhalation is unlikely. - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION III - PHYSICAL AND CHEMICAL PROPERTIES Form: High viscosity caulk Appearance/Color: various colors Solubility (in water): yes pH Value, +/-.3: 7.5 -------------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET MSDS Name: SA-167 SILICONIZED ACRYLIC LATEX CAULK MSDS Number: 16711-001 Version Number 2 MSDS Date: SEP-09-2002 Page Number: 2 ----------------------------------------------------------------------------Boiling Range: Vapor Pressure (mmHg): Evaporation Rate: 212.øF (100.øC) 15.@ 68.øF (20.øC) 0.5 times Slower than n-Butyl Acetate Vapor Density: Heavier than air % Volatile, Weight % Volatile, Volume Specific Gravity: VOC (less H2O or exempt) approx. 20.% approx. 30.% 1.556 41 Gr/L (2%) NOTE: Odor : Mild acrylic odor. Freeze Point : 32 Deg F - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION IV - FIRE FIGHTING MEASURES (Flash,UEL,LEL for solvent only) Flammability Class N/A Flash Range: Not Available Explosive Range (LEL/UEL): Not Applicable EXTINGUISHING MEDIA: Dry chemical -- Carbon Dioxide -- Foam -- Water Fog Will not burn in wet state. SPECIAL FIRE-FIGHTING PROCEDURES: Water may be used to cool and protect exposed containers. Caution should be taken because uncured material is water soluble. UNUSUAL FIRE AND EXPLOSION HAZARDS: Any closed container may burst when exposed to extreme heat or fire. - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION V - HEALTH HAZARD DATA ROUTES OF ENTRY: ENTRY THROUGH...Inhalation and skin most likely CARCINOGENICITY... NTP? N/E | IARC Monographs? N/E | OHSA? NO EFFECTS OF OVEREXPOSURE Inhalation: May irritate respiratory tract. Skin/Eye Contact: May cause irritation. Ingestion: Swallowing large amounts may cause nausea, vomiting. ( an unlikely route of entry ) -------------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET MSDS Name: SA-167 SILICONIZED ACRYLIC LATEX CAULK MSDS Number: 16711-001 Version Number 2 MSDS Date: SEP-09-2002 Page Number: 3 ----------------------------------------------------------------------------FIRST AID MEASURES Inhalation: If affected by inhalation, remove to fresh air. Eye Contact: Flush with water for at least 15 minutes, and get prompt medical attention. Skin Contact: Wash skin thoroughly with soap and water. Ingestion: Drink water, and get medical attention. ------------------------------------------------------------------N/A= Not applicable N/AV=Not available N/E, N/est=Not established - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION VI - STABILITY AND REACTIVITY Stability: This product is stable Hazardous Polymerization: Hazardous polymerization will not occur INCOMPATABILITY: None CONDITIONS TO AVOID: None HAZARDOUS DECOMPOSITION PRODUCTS: May produce oxides of carbon and oxides of nitrogen when burned. - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION VII - ACCIDENTAL RELEASE AND DISPOSAL MEASURES: STEPS TO BE TAKEN IN CASE OF SPILL: Wear appropriate protective clothing. Add dry absorbent and shovel or sweep up. Place in an appropriate container and seal. WASTE DISPOSAL METHOD: Dispose of in accordance with Federal, State, and Local regulations. - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits ACGIH TLV ACGIH TLV-C ACGIH STEL OSHA STEL OSHA PEL Titanium Dioxide ** 10.00 mg/F3 N/est N/est N/est 15.00 mg/F3 ETHYLENE GLYCOL 50.00 PPM N/est N/est N/est 50.00 PPM MINERAL SPIRITS 100.00 PPM N/est N/est N/est 100.00 PPM -------------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET MSDS Name: SA-167 SILICONIZED ACRYLIC LATEX CAULK MSDS Number: 16711-001 Version Number 2 MSDS Date: SEP-09-2002 Page Number: 4 ----------------------------------------------------------------------------- RESPIRATORY PROTECTION: NIOSH respirators recommended if vapors and mists are generated. VENTILATION: Local exhaust is recommended for safe practice. PROTECTIVE CLOTHING: Gloves and clothing should be worn to prevent repeated skin contact. EYE PROTECTION: Splashproof goggles or safety glasses should be worn. HANDLING AND STORAGE PRECAUTIONS: Keep from freezing. Keep away from heat. Keep containers closed when not in use. Avoid prolonged or repeated contact with skin. Keep out of the reach of children. - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION IX - TRANSPORT INFORMATION: DOT CLASSIFICATIONS FOR ONE GALLON AND UNDER CONTAINERS DESCRIPTION: Non-hazardous DOT CLASSIFICATIONS for OVER 1 GALLON size CONTAINERS DESCRIPTION: Non-hazardous, Caulking product - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION X - REGULATORY INFORMATION: SARA TITLE III SECTION 313: This product contains the following toxic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right to Know Act of 1986 and of 40 CFR 372: Ingredient Name CAS Number Percent ETHYLENE GLYCOL 107-21-1 < 2.0 The following ingredients are registered for TSCA 12B Ingredient Name CAS Number Percent ETHYLENE GLYCOL < 2.0 107-21-1 Ethylene Glycol fits the EPA Hazard Category definition of Immediate (Acute) and Delayed (Chronic) Health Hazards under SARA Sect.311,312. -------------------------------------------------------------------------------- MATERIAL SAFETY DATA SHEET MSDS Name: SA-167 SILICONIZED ACRYLIC LATEX CAULK MSDS Number: 16711-001 Version Number 2 MSDS Date: SEP-09-2002 Page Number: 5 ----------------------------------------------------------------------------All chemical substances are TSCA listed. California PROP.65 Chemicals: none known DISCLAIMER: The information contained herein is based on data available as of the date of preparation of this MSDS and which we believe to be reliable. However, no warranty is expressed or implied regarding the accuracy of the data. We shall not be responsible for the use of this information, or of any product, method, or apparatus mentioned, and the user must make his own investigation to determine the suitability of the information or products for his particular purpose, for the protection of the environment, and the health and safety of the users of this material. -------------------------------------------------------------------------------- Last Page 00010011605 English Page 1 of 7 Material Safety Data Sheet 24 Hour Emergency Phone Numbers: Medical/Poison Control: In U.S.: Call 1-800-222-1222 Outside U.S.: Call your local poison control center Transportation/National Response Center: 1-800-535-5053 1-352-323-3500 NOTE: The National Response Center emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals. IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16. Section 1 - Chemical Product / Company Information This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request. On peut demader cette fiche signalétique (MSDS) a la langue francaise-canadienne. Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere. Product Name: Product UPC Number: Product Use/Class: Manufacturer: DAP Alex Painters Acrylic Latex Caulk - All Colors 070798736313, 070798736351 Revision Date: Supercedes: 04/01/2008 Latex Caulk MSDS Number: 00010011605 10/29/2004 DAP Canada 475 Finchdene Square Unit 5 Scarborough, Ontario M1X 1B7 888-327 -8477 (non-emergency) Section 2 - Hazards Identification Emergency Overview: A colored paste product with a very slight ammonia odor. WARNING! May cause eye, skin, nose, throat and respiratory tract irritation. May cause eye or skin irritation. Harmful if swallowed or absorbed through the skin. This product contains ethylene glycol. Refer to other MSDS sections for other detailed information. Effects Of Overexposure - Eye Contact: May cause eye irritation. Effects Of Overexposure - Skin Contact: May cause skin irritation. Harmful if absorbed through the skin. Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation of high concentrations may cause headache, nausea, and dizziness. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes). Inhalation may cause mild irritation to the respiratory tract (nose, mouth, mucous membranes). Effects Of Overexposure - Ingestion: Ingestion of ethylene glycol can cause gastrointestinal irritation, nausea, vomiting, diarrhea and if ingested in sufficient quantities, death. Harmful or fatal if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. If ingested, may cause vomiting, diarrhea, and depressed respiration. Ingestion may result in obstruction when material hardens. Effects Of Overexposure - Chronic Hazards: Repeated or prolonged exposure may cause respiratory system damage. 00010011605 English Page 2 of 7 Prolonged and repeated skin contact may cause irritation and possibly dermatitis. The International Agency for Research on Cancer (IARC) has determined that crystalline silica in the form of quartz or cristobalite that is inhaled from occupational sources is carcinogenic to humans (Group 1- carcinogenic to humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (published in June 1997) in conjunction with the use of these materials. The National Toxicology Program (NTP) classifies respirable crystalline silica as "known to be a human carcinogen". Refer to the 9th Report on Carcinogens (2000). The American Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (Group A2). Breathing dust containing respirable crystalline silica may not cause noticeable injury or illness even though permanent lung damage may be occurring. Inhalation of dust may have the following serious chronic health effects: Excessive inhalation of respirable dust can cause pneumoconiosis, a respiratory disease, which can result in delayed, progressive, disabling and sometimes fatal lung injury. Symptoms include cough, shortness of breath, wheezing, non-specific chest illness and reduced pulmonary function. Smoking exacerbates this disease. Individuals with pneumoconiosis are predisposed to develop tuberculosis. There is some evidence that breathing respirable crystalline silica or the disease silicosis is associated with an increased incidence of significant disease endpoints such as scleroderma (an immune system disorder manifested by fibrosis of the lungs, skin and other internal organs) and kidney disease. Prolonged, repeated, or high exposures may cause weakness and depression of the central nervous system. Overexposure may cause kidney, cardiovascular, skin and liver damage. Formaldehyde vapor is a known animal carcinogen according to OSHA and NTP and is considered possibly carcinogenic to humans by inhalation. The International Agency for Research on Cancer considers formaldehyde to be a human carcinogen. A mixture of diisodecyl phthalate and diisononyl phthalate has been tested in a two-generation toxicity study in laboratory animals. No effects on reproductive parameters were seen. However, a small but statistically significant increase in early offspring mortality was seen at high oral doses. The significance of this to humans is uncertain. The mixture of phthalate esters contained within this product has been shown to cause developmental effects at high doses in laboratory animals when administered orally by gavage in a developmental study and developmental and fertility effects when administered at high doses by feed in a two-generation reproduction study. The potential risk from occupational and consumer exposure is considered to be very low, based on limited relevance of the rodent findings to humans and the large safety margins between exposure and the effect levels. Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Studies have shown that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals. Ethylene glycol has been shown to cause birth defects in laboratory animals. Primary Route(s) Of Entry: Skin Contact, Inhalation, Eye Contact Medical Conditions which May be Aggravated by Exposure: None known. Carcinogenicity: CAS No. Chemical Name 14808-60-7 Silica, crystalline 13463-67-7 Titanium dioxide 50-00-0 Formaldehyde ACGIH OSHA Suspected human carcinogen. Not Listed. Suspected human carcinogen. IARC NTP Not Listed. Human carcinogen. Known carcinogen. Not Listed. Possible carcinogen. Not Listed. Potential cancer hazard. Human carcinogen. Anticipated carcinogen. Section 3 - Composition / Information On Ingredients Chemical Name Limestone Branched and linear phthalates Stoddard solvent Ethylene glycol Silica, crystalline Titanium dioxide CASRN 1317-65-3 Proprietary 8052-41-3 107-21-1 14808-60 -7 13463-67 -7 Wt% 40 -70 1-5 0.5-1.5 0.1-1.0 0.1-1.0 0.1-1.0 00010011605 English Page 3 of 7 Ammonia Formaldehyde 7664-41-7 50-00 -0 0.1-1.0 <0.009 Section 4 - First Aid Measures First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes until irritation subsides. Get medical attention immediately. First Aid - Skin Contact: Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical aid if symptoms persist. If skin irritation persists, call a physician. Remove and wash contaminated clothing. In case of contact, immediately flush skin with plenty of water while removing contaminated clothing and shoes. First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If continued breathing difficulty is experienced, get medical attention immediately. First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately. If ingested, drink 2 glasses of water. Immediately see a physician. Never give anything by mouth to an unconscious person. Note to Physician: None. COMMENTS: If over-exposure occurs, call your local poison control center. Section 5 - Fire Fighting Measures Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog Unusual Fire And Explosion Hazards: No special protective measures against fire required. Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent) and full protective gear. Use water spray to cool exposed surfaces. Section 6 - Accidental Release Measures Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use absorbent material or scrape up dried material and place in container. Section 7 - Handling And Storage Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Avoid breathing vapor and contact with eyes, skin and clothing. Use only with adequate ventilation. Open all windows and doors or use other means to ensure cross-ventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous conditions. Wash thoroughly after handling. Storage: Do not store at temperatures above 120 degrees F. Store containers away from excessive heat and freezing. Close container after each use. Store away from caustics and oxidizers. Section 8 - Exposure Controls / Personal Protection Chemical Name CASRN ACGIH TWA ACGIH STEL ACGIH CEIL Limestone 1317-65-3 10 MGM3 N.E. N.E. Branched and linear phthalates Stoddard solvent Ethylene glycol Proprietary 8052-41-3 107-21-1 N.E. 100 PPM N.E. N.E. N.E. N.E. N.E. N.E. 100 MGM3 OSHA TWA 5 MGM3 (respirable fraction) N.E. 500 PPM N.E. OSHA STEL OSHA CEIL Skin N.E. N.E. No N.E. N.E. N.E. N.E. N.E. N.E. No No No 00010011605 English Page 4 of 7 Silica, crystalline 14808-60-7 0.05 MGM3 N.E. N.E. Titanium dioxide Ammonia Formaldehyde 13463-67-7 7664-41-7 50-00-0 10 MGM3 25 PPM N.E. N.E. 35 PPM N.E. N.E. N.E. 0.3 PPM 10/(%SiO2 + 2) MGM3 15 MGM3 50 PPM 0.75 PPM N.E. N.E. No N.E. N.E. 2 PPM N.E. N.E. N.E. No No No Exposure Notes: 14808-60-7 The 2002 ACGIH Threshold Limit Values for Chemical Substances and Physical Agents lists the median Respirable Particulate Mass (RPM) point for crystalline silica at 4.0 microns in terms of the particle's aerodynamic diameter. The TLVs for crystalline silica represent the respirable fraction. OSHA PEL TWA for Quartz is calculated using the following formula: 10 mg/m3/(% SiO2 + 2). Both concentration and percent quartz for the application of this limit are to be determined from the fraction passing a size selector with the following characteristics. |------------------------------------------------------------------------------------ |-----------------------------------------| | ....... Aerodynamic diameter ( unit density sphere ) .....| Percent passing selector | | 2 ................................................................................|.................90....................| | 2.5 .............................................................................|..................75...................| | 3.5 .............................................................................|..................50...................| | 5.0 .............................................................................|..................25...................| | 10 ..............................................................................|...................0....................| 50-00-0 Formaldehyde is a specially regulated substance for which an OSHA chemical-specific exposure standard exits. Detailed information regarding this substance may be found in 29 CFR 1910.1048. Medical surveillance information regarding this substance may be found in Appendix C to 29 CFR 1910.1048. Precautionary Measures: Contact lenses pose a special hazard; soft lenses may absorb and all lenses concentrate irritants. Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Ensure adequate ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient concentrations below recommended exposure limits. Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSH-approved air purifying respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where airborne concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. National Institute for Occupational Safety and Health (NIOSH) has recommended that the permissible exposure limit be changed to 50 micrograms respirable free silica per cubic meter of air (0.05 mg/m3) as determined by a full shift sample up to 10-hour work shift. Skin Protection: Rubber gloves. Natural rubber, butyl rubber and polyvinyl chloride gloves are not suitable protection against the phthalates contained within this product; neoprene is recommended. Eye Protection: Goggles or safety glasses with side shields. Other protective equipment: Not required under normal use. Hygienic Practices: Wash hands before breaks and at the end of workday. Remove and wash contaminated clothing before re-use. Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary between states. Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work practices. 00010011605 English Page 5 of 7 Section 9 - Physical And Chemical Properties Boiling Range: Odor: Color: Solubility in H2O: Freeze Point: Vapor Pressure: Physical State: Flash Point, F: Not Established Very Slight Ammonia Colored Not Established Not Established Not Established Paste Greater than 200 degrees Fahrenheit Lower Explosive Limit, %: Not Established Vapor Density: Odor Threshold: Evaporation Rate: Specific Gravity: pH: Viscosity: Flammability: Method: Heavier Than Air Not Established Slower Than n-Butyl Acetate 1.6 Between 7.0 and 12.0 Not Established Non-Flammable (Seta Closed Cup) Upper Explosive Limit, %:Not Established When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally. (See section 16 for abbreviation legend) Section 10 - Stability And Reactivity Conditions To Avoid: Excessive heat and freezing. Incompatibility: Incompatible with strong bases and oxidizing agents. Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx. Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions. Stability: Stable under recommended storage conditions. Section 11 - Toxicological Information Product LD50: Not Established CASRN 107-21-1 7664-41-7 50-00-0 Chemical Name Ethylene glycol Ammonia Formaldehyde Product LC50: Not Established LD50 Rat:4700 mg/kg ------------------------- LC50 Rat:10876 mg/kg Rat:2000 ppm/4H Rat:203 mg/m3 Significant Data with Possible Relevance to Humans: This product contains trace amounts of free formaldehyde. OSHA and NTP identify formaldehyde as a potential carcinogen. IARC identifies formaldehyde as a human carcinogen. Formaldehyde has been shown to cause mutations in a variety of in-vitro test systems, the significance of which to humans is unknown. There should be minimal risk when used with ventilation adequate to keep the atmospheric concentration of formaldehyde below the recommended exposure limits. Maintain adequate ventilation to prevent exposure above current OSHA / ACGIH exposure limits. Workplace monitoring of the air to define formaldehyde exposure levels may be necessary. In a two-year inhalation study, rats showed carcinogenic effects in the respiratory system at 15 ppm of formaldehyde. Section 12 - Ecological Information Ecological Information: Ecological injuries are not known or expected under normal use. Section 13 - Disposal Information Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. 00010011605 English Page 6 of 7 EPA Waste Code if Discarded (40 CFR Section 261): None Section 14 - Transportation Information DOT Proper Shipping Name: DOT Technical Name: DOT Hazard Class: Not Regulated Packing Group: N.A. N.A. N.A. Hazard Subclass: DOT UN/NA Number: N.A. N.A. Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may apply if shipped via other modes of transportation and/or to non-domestic destinations. Section 15 - Regulatory Information CERCLA - SARA Hazard Category: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Immediate Health Hazard, Chronic Health Hazard SARA Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: None Toxic Substances Control Act: All ingredients in this product are either on TSCA inventory list, or otherwise exempt. This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: None Canadian WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. Canadian WHMIS Class: Not Controlled. Section 16 - Other Information HMIS Ratings: Health: 1 Flammability: 1 Reactivity: 0 Volatile Organic Compounds (VOC), less water less exempts: g/L: Personal Protection: X 56.0 Volatile Organic Compounds (VOC), less water less exempts, less LVP -VOCs: lb/gal: 0.5 wt:wt%: 2.5 wt:wt%: 0.9 00010011605 English Page 7 of 7 REASON FOR REVISION: Periodic Update Legend: N.A. – Not Applicable ACGIH – American Conference of Governmental Industrial Hygienists N.E. – Not Established SARA – Superfund Amendments and Reauthorization Act of 1986 N.D. – Not Determined NJRTK – New Jersey Right-to-Know Law VOC – Volatile Organic Compound OSHA – Occupational Safety and Health Administration PEL – Permissible Exposure Limit HMIS – Hazardous Materials Identification System TLV – Threshold Limit Value NTP – National Toxicology Program CEIL – Ceiling Exposure Limit STEL – Short Term Exposure Limit LD50 – Lethal Dose 50 LC50 – Lethal Concentration 50 F – Degree Fahrenheit MSDS – Material Safety Data Sheet C – Degree Celsius CASRN – The Chemical Abstracts Service Registry Number DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context of the intended use and (ii) determine if they are appropriate. MATERIAL SAFETY DATA SHEET WL30067 04 00 Section 1 -- PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER DATE OF PREPARATION HMIS CODES Health WL30067 15-MAY-08 Flammability Reactivity PRODUCT NAME WHITE LIGHTNING® 3006™ Original Formula All Purpose Adhesive Caulk, Clear 1 0 0 MANUFACTURER'S NAME THE SHERWIN-WILLIAMS CO. Consumer Group - Industrial Cleveland, OH 44115 TELEPHONE NUMBERS and WEBSITES Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency for Chemical Emergency ONLY (spill, leak, (800) 424-9300 fire, exposure, or accident) Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE No ingredients in this product are hazardous as defined by the Department of Labor. Section 3 -- HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. In a confined area vapors in high concentration may cause headache, nausea or dizziness. SIGNS AND SYMPTOMS OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Continued on page 2 WL30067 page 2 Section 4 -- FIRST AID MEASURES EYES: SKIN: INHALATION: INGESTION: Flush eyes with large amounts of water for 15 minutes. Get medical attention. Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. If affected, remove from exposure. Restore breathing. Keep warm and quiet. Do not induce vomiting. Get medical attention immediately. Section 5 -- FIRE FIGHTING MEASURES FLASH POINT LEL UEL Not Applicable N.A. N.A. FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 -- ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Section 7 -- HANDLING AND STORAGE STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Continued on page 3 WL30067 page 3 Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 8.77 lb/gal 1050 g/l SPECIFIC GRAVITY 1.06 BOILING POINT 212 - 213 F 100 - 100 C MELTING POINT Not Available VOLATILE VOLUME 51 % EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 8.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.26 lb/gal 31 g/l Less Water and Federally Exempt Solvents 0.13 lb/gal 15 g/l Emitted VOC Continued on page 4 WL30067 page 4 Section 10 -- STABILITY AND REACTIVITY STABILITY -- Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Section 11 -- TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. TOXICOLOGY DATA CAS No. Ingredient Name No LC50 or LD50 data available. Section 12 -- ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Section 13 -- DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Section 14 -- TRANSPORT INFORMATION US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. Section 15 -- REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION Continued on page 5 WL30067 page 5 CAS No. CHEMICAL/COMPOUND % by WT % Element No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Section 16 -- OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. MATERIAL SAFETY DATA SHEET WL01010 05 00 Section 1 -- PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER DATE OF PREPARATION HMIS CODES Health WL01010 19-JUN-08 Flammability Reactivity PRODUCT NAME WHITE LIGHTNING® 3006™ Original Formula All Purpose Adhesive Caulk, Almond 2* 0 0 MANUFACTURER'S NAME THE SHERWIN-WILLIAMS CO. Consumer Group - Industrial Cleveland, OH 44115 TELEPHONE NUMBERS and WEBSITES Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency for Chemical Emergency ONLY (spill, leak, (800) 424-9300 fire, exposure, or accident) % by WT 1 59 0.8 Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS CAS No. INGREDIENT UNITS VAPOR PRESSURE 64742-88-7 Mineral Spirits ACGIH TLV 100 ppm 2 mm OSHA PEL 100 ppm 471-34-1 Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 15 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction Section 3 -- HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. In a confined area vapors in high concentration may cause headache, nausea or dizziness. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver and urinary systems. Continued on page 2 WL01010 page 2 SIGNS AND SYMPTOMS OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Section 4 -- FIRST AID MEASURES EYES: SKIN: INHALATION: INGESTION: Flush eyes with large amounts of water for 15 minutes. Get medical attention. Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. If affected, remove from exposure. Restore breathing. Keep warm and quiet. Do not induce vomiting. Get medical attention immediately. Section 5 -- FIRE FIGHTING MEASURES FLASH POINT LEL UEL Not Applicable N.A. N.A. FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 -- ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Section 7 -- HANDLING AND STORAGE STORAGE CATEGORY Not Applicable Continued on page 3 WL01010 page 3 PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT SPECIFIC GRAVITY BOILING POINT MELTING POINT VOLATILE VOLUME EVAPORATION RATE VAPOR DENSITY SOLUBILITY IN WATER pH Continued on page 4 13.70 lb/gal 1641 g/l 1.65 212 - 395 F 100 - 201 C Not Available 27 % Slower than ether Heavier than air N.A. 8.0 WL01010 page 4 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.38 lb/gal 46 g/l Less Water and Federally Exempt Solvents 0.29 lb/gal 35 g/l Emitted VOC Section 10 -- STABILITY AND REACTIVITY STABILITY -- Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Section 11 -- TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS TOXICOLOGY DATA CAS No. Ingredient Name 64742-88-7 Mineral Spirits LC50 RAT 4HR LD50 RAT 471-34-1 Calcium Carbonate LC50 RAT 4HR LD50 RAT 13463-67-7 Titanium Dioxide LC50 RAT 4HR LD50 RAT Not Available Not Available Not Available Not Available Not Available Not Available Section 12 -- ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Section 13 -- DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Continued on page 5 WL01010 page 5 Section 14 -- TRANSPORT INFORMATION US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. Section 15 -- REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Section 16 -- OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Material Safety Data Sheet Section 1 General Information Manufacturer: Zinsser Company, Inc. 173 Belmont Drive Somerset, NJ 08875 (732) 469-8100 Emergency Telephone: Product Name: Codes: Chemtrec (800) 424-9300 Date: December 1, 2006 Cover Stain Spray 03608 03610 03615 03616 03620 03624 03640 Section 2 Hazardous Ingredients Hazardous Component CAS# Acetone Aliphatic Petroleum Distillates Kaolin Limestone Propane Talc Titanium dioxide VM&P Naphtha 67-64-1 64742-89-8 1332-58-7 1317-65-3 74-98-6 14807-96-6 13463-67-7 8032-32-4 OSHA PEL ACGIH TLV 1000 ppm 500 ppm 15 mg/m3 (5 mg/m3 *) 15 mg/m3 (5 mg/m3 *) 1000 ppm 20 mppcf 15 mg/m3 500 ppm 500 ppm N/E 2 mg/m3* 3 10 mg/m (3 mg/m3 *) 1000 ppm 10 mg/m3 = (3 mg/m3) 10 mg/m3 300 ppm * Respirable Dust Fraction Section 3 Hazard Identification Emergency Overview: This material is an aerosol spray coating used as a primer/sealer. The aerosol container is pressurized and extremely flammable. As packaged, this material has a flashpoint of less than 32° F. Primary Routes of Exposure: Inhalation Skin Contact Eye Contact Potential Acute Health Effects: Eye: May cause eye irritation. Skin: Prolonged contact may cause skin irritation. N/A: Not Applicable N/D: Not Determined N/E: Not Established MSDS Code: Cover Stain Spray MSDS (12-1-06) N/R: Not Required Page 1 of 6 pages. Est.: Estimated Ingestion: Although ingestion is not anticipated route of exposure, this material can be harmful if swallowed. It may cause depression of the central nervous system, nausea, and vomiting. Inhalation: irritation. May cause headache, drowsiness, dizziness, nausea, and respiratory tract Potential Chronic Health Effects: None known. (See also Sections 4, 8, and 11 for related information) Section 4 First Aid Measures Eye contact: Flush eyes with water for 15 minutes. Skin contact: Wash affected area with soap and water. Ingestion: Call a physician or poison control center. Inhalation: Remove person to fresh air. Contact physician or poison control center if symptoms persist. Section 5 Fire Fighting Measures Flash Point (method): < 32° F (< 0° C) Extinguishing Media: Foam, CO2, dry chemical, water fog. Protection of Firefighters: As in any fire, wear NIOSH approved self-contained breathing apparatus in pressure-demand mode and full protective gear. Fire and Explosion Hazards: if exposed to heat (fire). Section 6 Contents under pressure. Containers can build up pressure Accidental Release Measures Personal Precautions: Use with adequate ventilation. Avoid breathing vapors. Avoid contact with eyes and skin. Do not eat, drink or smoke in areas of use or storage. Clean Up Methods: Dispose of in accordance with federal, state, local, regulations. (See also Section 8 for information on Exposure Controls and Personal Protective Equipment) N/A: Not Applicable N/D: Not Determined N/E: Not Established MSDS Code: Cover Stain Spray MSDS (12-1-06) N/R: Not Required Page 2 of 6 pages. Est.: Estimated Section 7 Handling and Storage Handling: Keep away from heat, spark, and flame. Keep operating temperatures below ignition temperatures at all times. Use only in a well-ventilated area. Storage: Store at ambient or lower temperature. Keep containers tightly closed and upright when not in use. Protect against physical damage. Contents under pressure. Do not expose to heat. Section 8 Exposure Controls / Personal Protection Engineering Controls: Local exhaust ventilation may be necessary to control vapors within applicable exposure limits. Personal Protective Equipment (PPE): Eye Protection: contact. Wear safety glasses, splash goggles, or full face shield to prevent eye Skin Protection: Wear rubber gloves to prevent skin contact. Respiratory Protection: Use NIOSH approved respirator with organic vapor cartridges if vapor levels exceed allowable workplace exposure limits. General Hygiene Practices: Wash thoroughly after handling. Prevent Eye contact. Avoid prolonged skin or inhalation contact. Section 9 Physical Data Appearance: White aerosol mist. Odor: Hydrocarbon type odor. Physical State: Spray mist pH: Boiling Point: N/D Melting Point: N/D Vapor Pressure: N/D Vapor Density: Greater than air Odor Threshold: N/D Viscosity: N/D Solubility in Water: N/D Section 10 Stability: N/A Specific Gravity (water = 1): 0.9 Stability and Reactivity Stable, non-reactive. N/A: Not Applicable N/D: Not Determined N/E: Not Established MSDS Code: Cover Stain Spray MSDS (12-1-06) N/R: Not Required Page 3 of 6 pages. Est.: Estimated Hazardous Polymerization: Will not occur. Hazardous Decomposition Products: Conditions to Avoid: None known. Heat, sparks, and open flames. Section 11 Toxicological Information Carcinocenicity: This material is not considered a carcinogen by IARC or NTP and is not regulated as a carcinogen by OSHA. (See also Section 15 for related information) Section 12 Ecological Information Chemical Fate and Effects: No data available. Section 13 Disposal Considerations RCRA Hazardous Waste: This material, when discarded or disposed of, could be a hazardous waste according to federal regulations (40 CFR 261) due to the characteristic of ignitability (D001). The transportation, storage, treatment, and disposal of this waste must be conducted in compliance with 40 CFR 262, 263, 264, 268, and 270. Disposal can only occur in properly permitted facilities. Check state and local regulations for any additional requirements as these may be more restrictive than federal laws and regulations. Chemical additions, processing or otherwise altering this material may make the waste management information presented in this MSDS incomplete, inaccurate, or otherwise inappropriate. Section 14 Regulated by the DOT: Transportation Information Yes DOT Proper Shipping Name: UN / NA Number: Paint UN 1950 Section 15 Regulatory Information CERCLA: The Comprehensive Environmental Response Compensation and Liability Act of 1980 (CERCLA) requires notification to the National Response Center for releases of quantities of Hazardous Substances equal to or greater than the reportable quantities (RQs) in 40 CFR 302.4 (for CERCLA 102). N/A: Not Applicable N/D: Not Determined N/E: Not Established MSDS Code: Cover Stain Spray MSDS (12-1-06) N/R: Not Required Page 4 of 6 pages. Est.: Estimated Components present in this product at a level which could require reporting under the statute are: Chemical Name None CAS# N/A Maximum Concentration (Wt. %) N/A SARA Title III, section 311/312: The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires emergency planning based on Threshold Planning Quantities (TPQs) and release reporting based on Reportable Quantities (RQs) in 40 CFR 355 (used for SARA 302, 304, 311 and 312). Components present in this product at a level which could require reporting under the statute are: Chemical Name None CAS# N/A Maximum Concentration (Wt. %) N/A SARA Title III, section 313: The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires submission of annual reports of release of toxic chemicals that appear in 40 CFR 372 (for SARA 313). Components present in this product at a level which could require reporting under the statute are: Chemical Name None CAS# N/A Maximum Concentration (Wt. %) N/A TSCA: The components of this mixture are listed in the Toxic Substance Control Act Inventory of Chemical Substances. This product contains the following chemicals which require export notification under section 12(b) of the TSCA regulation: Chemical Name Acetone Methyl ethyl ketoxime Section 16 CAS# 67-64-1 96-29-7 TSCA Section Sec. 4 Sec. 4 Other Information Legend: N/A: Not Applicable N/D: Not Determined N/E: Not Established N/R: Not Required STEL: Short Term Exposure Limit C: OSHA Ceiling Value cps: Centipoise mg/m3: milligrams per cubic meter mppcf: million particles per cubic foot of air. PPM: Parts Per Million PPB: Parts Per Billion PEL: Permissible Exposure Limit TLV: Threshold Limit Value TWA: Time Weighted Average ACGIH: American Conference of Governmental Industrial Hygienists N/A: Not Applicable N/D: Not Determined N/E: Not Established MSDS Code: Cover Stain Spray MSDS (12-1-06) N/R: Not Required Page 5 of 6 pages. Est.: Estimated CPSC: Consumer Product Safety Commission DOT: US Department of Transportation FHSA: Federal Hazardous Substance Act OSHA: Occupational Safety and Health Administration (US Dept. of Labor) RCRA: Resource Conservation and Recovery Act SARA: Superfund Amendment and Reauthorization Act Skin: This substance has the potential to be absorbed systemically through the skin. TSCA: Toxic Substance Control Act Prepared By: Zinsser Health and Safety Manager, Regulatory Compliance Dept. 173 Belmont Drive Somerset, NJ 08875 (732) 469-8100 Disclaimer: Zinsser Company, Inc. believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this material safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials and make no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and data and to comply with all applicable international, federal, state, and local laws and regulations. N/A: Not Applicable N/D: Not Determined N/E: Not Established MSDS Code: Cover Stain Spray MSDS (12-1-06) N/R: Not Required Page 6 of 6 pages. Est.: Estimated Material Safety Data Sheet Section 1 General Information Manufacturer: Zinsser Company, Inc. 173 Belmont Drive Somerset, NJ 08875 (732) 469-8100 Emergency Telephone: Chemtrec (800) 424-9300 Product Name: Codes: Zinsser Magic Strip 42072 Section 2 42074 Hazardous Ingredients Hazardous Component Clay Talc Quartz N-Methyl-2-Pyrrolidone Section 3 Date: February 5, 2007 CAS# 1332-58-7 14807-96-6 14808-60-7 872-50-4 OSHA PEL ACGIH TLV 2mg/m3 2mg/m3 5 mg/m3 10mg/m3 2mg/cm 10 mg/m3 NE NE Hazard Identification Emergency Overview: This material may cause eye, skin, nose, and throat irritation and may be harmful if inhaled. This material is a paint stripper. It is a green colored liquid with a mild amine type odor and flash pint greater than 200° F. Primary Routes of Exposure: Skin Contact Eye Contact Inhalation Potential Acute Health Effects: Eye: May cause eye irritation. Direct contact with the liquid or exposure to vapors or mists may cause stinging, tearing, redness, swelling, and eye damage. N/A: Not Applicable N/D: Not Determined Zinsser Magic Strip (2-05-07) N/E: Not Established N/R: Not Required Est.: Estimated Page 1 of 7 pages. Skin: May cause skin irritation. Prolonged or repeated contact may cause skin to become reddened, rough and dry due to the removal of natural oils and may result in dermatitis. May be harmful if absorbed through the skin. Ingestion: This material may be harmful if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Inhalation: Do not breathe vapor or spray mist Inhalation may cause respiratory tract irritation. Breathing high concentrations of vapors or mists may affect the brain or central nervous system causing dizziness, headaches, nausea, and drowsiness. Respiratory symptoms associated with preexisting lung disorders (e.g. asthma-like conditions) may be aggravated by exposure to this material. Potential Chronic Health Effects: Signs and Symptoms: Prolonged or repeated skin contact may cause dermatitis. Persons with pre-existing skin disorders or impaired liver, kidney, and pulmonary function may be more susceptible to the effects of this material. (See also Sections 4, 8, and 11for related information) Section 4 First Aid Measures Eye contact: In case of eye contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately. Skin contact: In case of skin contact, wash thoroughly with soap and water for at least 15 minutes. Get medical attention immediately. Remove contaminated clothing and shoes. Ingestion: If swallowed, contact a physician or poison control center immediately. DO NOT induce vomiting unless directed to do so by medical personnel. May cause irritation of the gastrointestinal tract with vomiting. Inhalation: If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical attention immediately. Section 5 Fire Fighting Measures Flash Point (method): N/D (estimated greater than 200° F) Extinguishing Media: Water, CO2, foam, dry chemical or water supply. Protection of Firefighters: As in any fire, wear self-contained breathing apparatus in pressure demand mode and full protective gear. Unusual Fire and Explosion Hazards: N/A: Not Applicable N/D: Not Determined Zinsser Magic Strip (2-05-07) None known. N/E: Not Established N/R: Not Required Est.: Estimated Page 2 of 7 pages. Section 6 Accidental Release Measures Clean Up Methods: Keep unnecessary people away. Dike and contain spill with inert material (sand, earth, etc.). Transfer liquid to containers for recovery or disposal, or absorb with absorbent materials and place into containers for disposal. Keep spill out of sewer and open bodies of water. Prevent runoff to sewers, streams or other bodies of water. Floors may be slippery; care should be exercised to avoid falls during clean up operations. Spillage: If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations. Clean up rags, papers and waste promptly. Allow solvent to evaporate then dispose of in metal container. Call your local sanitation department for aid in disposing of unwanted product in your area or call the Environmental Protection Agency Solvent and Hazardous Waste Hotline at 1-800-4249345. Do not dump on the ground or in local sewer of discharge system. (See also Section 8 for information on Exposure Controls and Personal Protective Equipment and Section 13 for Disposal information.) Section 7 Handling and Storage Handling: Open containers carefully and close after each use. Do not get in eyes, on skin or on clothing. Do not breathe vapors or spray mist. Wash thoroughly after handling. Wash clothing before reuse. Thoroughly clean contaminated shoes. Do not use pressure to empty containers. Containers, even those that have been emptied; will retain product residue and vapors. Always obey hazard warnings and handle empty containers as if they were full. Use this product outdoors, if possible. If you must use it indoors, open all windows and doors or use other means to ensure fresh air movement during application and drying. Ensure fresh air entry during application and drying. Prevent the build-up of vapors by opening windows and doors to achieve cross-ventilation. Storage: Store in a cool, dry, well-ventilated place away from incompatible materials. Keep containers tightly closed when not in use. Vapors of this product are heavier than air and will collect in low places, such as pits or degreasers or other poorly ventilated areas. Do not enter places where vapors are suspected unless special respirator protection is worn and an observer is present. Do not store near oxidizers, strong acids or bases. KEEP OUT OF REACH OF CHILDREN. (See also Section 8 for information on Exposure Controls and Personal Protective Equipment) Section 8 Exposure Controls / Personal Protection Engineering Controls: Use in well-ventilated are and ensure good cross ventilation during use and while drying. If necessary, use mechanical local exhaust ventilation or general room dilution ventilation to reduce vapor concentrations. WARNING! If you scrape, sand, or remove old paint, you may release lead dust. LEAD IS TOXIC. EXPOSURE TO LEAD DUST CAN CAUSE SERIOUS ILLNESS, SUCH AS BRAIN DAMAGE, N/A: Not Applicable N/D: Not Determined Zinsser Magic Strip (2-05-07) N/E: Not Established N/R: Not Required Est.: Estimated Page 3 of 7 pages. ESPECIALLY IN CHILDREN. PREGNANT WOMEN SHOULD ALSO AVOID EXPOSURE. Wear a NIOSH-approved respirator to control lead exposure. Clean up carefully with a HEPA vacuum and a wet mop. Before you start, find out how to protect yourself and your family by contacting the National Lead Information Hotline at 1-800-424-LEAD or log on to www.epa.gov/lead. Personal Protective Equipment (PPE) Eye Protection: Do not get in eyes. Wear chemical splash goggles or similar eye protection if the potential exists for eye contact Skin Protection: Prevent skin contact. It is recommended that PVA, rubber or other impermeable, chemically resistant gloves be worn to prevent skin contact. Depending on conditions of use additional protective equipment may be necessary such as face-shield, apron or coveralls. Respiratory Protection: If you experience eye watering, headache or dizziness or if air monitoring demonstrates vapor/mist levels exceed applicable occupational exposure limits, wear an appropriate, properly fitted respirator (NIOSH approved) during and after application. Follow respirator manufacturer’s directions for respirator use. For emergency or non-routine operations involving high vapor concentrations (such as enclosed areas) supplied air breathing apparatus (such as an airline respirator or SCBA) may be required. Protective Clothing: Wear chemical-resistant gloves, boots, and aprons to prevent skin contact. General Hygiene Practices: Wash after handling material. Prevent eye and skin contact. Wash thoroughly before handling food, cosmetics, or before smoking. Section 9 Physical Data Appearance: Green Odor: Mild amine type Physical State: liquid pH: Boiling Point: 212oF Melting Point: N/A Vapor Pressure: 0.2 mmHg @ 20°C Vapor Density: Heavier than air. Viscosity: Solubility in Water: Miscible N/D N/A Specific Gravity (water = 1): 1.31 Section 10 Stability: Stability and Reactivity Stable Hazardous Polymerization: N/A Hazardous Decomposition Products: N/A: Not Applicable N/D: Not Determined Zinsser Magic Strip (2-05-07) CO2, CO, release when heated. N/E: Not Established N/R: Not Required Est.: Estimated Page 4 of 7 pages. Incompatibility: Avoid contact with oxidizing agents, strong acids or bases. Section 11 Toxicological Information Carcinogenicity: Ingredients listed below are present at or greater than 0.1% and are classified by either IARC, NTP, or OSHA as carcinogenic: Ingredient CAS # Quartz 14808-60-7 Target Organs Effected: upon human reproduction. IARTC NTP OSHA Yes Yes No Animal tests indicate that N-Methyl-2-Pyrrolidone may cause toxic effects NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Section 12 Ecological Information Chemical Fate and Effects: Section 13 None known. Disposal Considerations Recommended Waste Disposal Method: This material, when discarded or disposed of, could be a hazardous waste according to federal regulations (40 CFR 261) due to the characteristic of ignitability (D001). The transportation, storage, treatment, and disposal of this waste must be conducted in compliance with 40 CFR 262, 263, 264, 268, and 270. Disposal can only occur in properly permitted facilities. Check state and local regulations for any additional requirements as these may be more restrictive than federal laws and regulations. Chemical additions, processing or otherwise altering this material may make the waste management information presented in this MSDS incomplete, inaccurate, or otherwise inappropriate Section 14 Transportation Information Regulated by the DOT: No DOT Proper Shipping Name: UN / NA Number: Not Applicable DOT Hazard Class: DOT Packing Group: N/A: Not Applicable Not Applicable Not Applicable Not Applicable N/D: Not Determined Zinsser Magic Strip (2-05-07) N/E: Not Established N/R: Not Required Est.: Estimated Page 5 of 7 pages. Section 15 Regulatory Information CERCLA: The Comprehensive Environmental Response Compensation and Liability Act of 1980 (CERCLA) requires notification to the National Response Center for releases of quantities of Hazardous Substances equal to or greater than the reportable quantities (RQs) in 40 CFR 302.4 (for CERCLA 102). Components present in this product at a level which could require reporting under the statute are: Chemical Name None CAS# N/A Maximum Concentration (Wt. %) N/A SARA Title III, section 311/312: The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires emergency planning based on Threshold Planning Quantities (TPQs) and release reporting based on Reportable Quantities (RQs) in 40 CFR 355 (used for SARA 302, 304, 311 and 312). Components present in this product at a level which could require reporting under the statute are: Chemical Name CAS# Maximum Concentration (Wt. %) None N/A N/A SARA Title III, section 313: The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires submission of annual reports of release of toxic chemicals that appear in 40 CFR 372 (for SARA 313). Components present in this product at a level which could require reporting under the statute are: Chemical Name N-Methyl-2-Pyrrolidone CAS# 872-50-4 Maximum Concentration (Wt. %) 9% TSCA: The components of this mixture are listed in the Toxic Substance Control Act Inventory of Chemical Substances. This product does not contain any chemicals that require export notification under Section 12(b) of the TSCA regulation. Section 16 Other Information Legend: N/A: Not Applicable N/E: Not Established cps: Centipoise STEL: Short Term Exposure Limit PPM: Parts Per Million N/A: Not Applicable N/D: Not Determined Zinsser Magic Strip (2-05-07) N/D: Not Determined N/R: Not Required KU: Krebs Units C: OSHA Ceiling Value PPB: Parts Per Billion N/E: Not Established N/R: Not Required Est.: Estimated Page 6 of 7 pages. PEL: Permissible Exposure Limit TLV: Threshold Limit Value TWA: Time Weighted Average mg/m3: Milligrams per cubic Meter mppcf: Million particles per cubic foot of air. ACGIH: American Conference of Governmental Industrial Hygienists OSHA: Occupational Safety and Health Administration (US Dept. of Labor) RCRA: Resource Conservation and recovery Act SARA: Superfund Amendment and Reauthorization Act TSCA: Toxic Substance Control Act FHSA: Federal Hazardous Substance Act Prepared By: Zinsser Health and Safety Manager, Regulatory Compliance Dept. 173 Belmont Drive Somerset, NJ 08875 (732) 469-8100 Disclaimer: Zinsser Co., Inc. believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this material safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials and make no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and data and to comply with all applicable international, federal, state, and local laws and regulations. N/A: Not Applicable N/D: Not Determined Zinsser Magic Strip (2-05-07) N/E: Not Established N/R: Not Required Est.: Estimated Page 7 of 7 pages. MSDS Page 1 of 7 View MSDS : 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION NFPA Product Name: 3 KILZ® Original Aerosol 0 1 MSDS Manufacturer Number: 1024 NA Manufacturer Name: Masterchem Industries LLC Address: 3135 Old Highway M Imperial, MO 63052-2834 General Phone Number: (636) 942-2510 General Fax Number: (636) 942-3663 Health Hazard 1 Customer Service Phone Number: (800) 325-3552 Fire Hazard CHEMTREC: For emergencies in the US, call CHEMTREC: 800-424-9300 REACTIVITY 0 Canutec: In Canada, call CANUTEC: (613) 996-6666 (call collect) MSDS Creation Date: 06/26/2006 Personal Protection MSDS Revision Date: 05/09/2007 * HMIS 3 x Chronic Health Effects: SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS# Ingredient Percent Silicate, mica 12001-26-2 10 - 30 by Weight Rutile 1317-80-2 5 - 10 by Weight Octanes, all isomers No data 5 - 10 by Weight Octanes, all isomers Mixture 5-10 by Weight Non-hazardous ingredients N/A 1 - 5 by Weight 1-Nitropropane 108-03-2 1-5 by Weight 10-30 by Weight Non-hazardous ingredients Acetone 67-64-1 10-30 by Weight Titanium dioxide 13463-67-7 10 - 30 by Weight Carbonic acid calcium salt 471-34-1 10 - 30 by Weight Propane 74-98-6 10-30 by Weight Isobutane 75-28-5 10-30 by Weight VM&P Naphtha/Aliphatic Hydrocarbon 8032-32-4 10 - 30 by Weight Nonane, all isomers Mixture 10-30 by Weight http://www.actiocms.com/view_msds/msdsdisplaycode_author_new_MASTER.cfm?edit_... 6/14/2007 MSDS Page 2 of 7 Nonanes No data 10 - 30 by Weight Talc, Magnesium silicate hydrate 14807-96-6 1 - 5 by Weight Xylene 1330-20-7 0.1 - 1 by Weight Palygorskite 12174-11-7 0.1 - 1 by Weight SECTION 3 - HAZARDS IDENTIFICATION Emergency Overview: Flammable. Irritant. Potential Health Effects: Eye: May cause irritation. Skin: May cause irritation. Inhalation: Prolonged or excessive inhalation may cause respiratory tract irritation. Ingestion: Harmful if swallowed. Ingestion can cause nausea, vomiting, diarrhea and gastrointestinal irritation. Chronic Health Effects: Prolonged or repeated contact can result in defatting and drying of the skin, which may result in skin irritation and dermatitis (rash). Repeated or prolonged inhalation may cause toxic effects. Signs/Symptoms: Overexposure can cause headaches, dizziness, nausea, and vomiting. Target Organs: Eyes. Skin. Respiratory system. Digestive system. Central nervous system. Kidney. Aggravation of Pre-Existing Conditions: May aggravate pre-existing respiratory disorders, allergy, eczema, or skin conditions. SECTION 4 - FIRST AID MEASURES Eye Contact: Immediately flush eyes with plenty of water for 15 to 20 minutes. Get medical attention, if irritation or symptoms of overexposure persists. Skin Contact: Immediately wash skin with soap and plenty of water. Get medical attention if irritation develops or persists. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek immediate medical attention. Ingestion: If swallowed, do NOT induce vomiting. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Other First Aid: Due to possible aspiration into the lungs, DO NOT induce vomiting if ingested. Provide a glass of water to dilute the material in the stomach. If vomiting occurs naturally, have the person lean forward to reduce the risk of aspiration. SECTION 5 - FIRE FIGHTING MEASURES Flammable Properties: Flammable liquid. Flash Point: <32°F (<0°C) Flash Point Method: Lower Flammable/Explosive Limit: 1% Upper Flammable/Explosive Limit: 7% Fire Fighting Instructions: Flammable. Cool fire-exposed containers using water spray. Extinguishing Media: Use alcohol foam, carbon dioxide, dry chemical, or water fog or spray when fighting fires involving this material. Protective Equipment: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Unusual Fire Hazards: Flammable liquid. Vapors can form an ignitable mixture with air. Vapors can flow along surfaces to a distant ignition source and flash back. http://www.actiocms.com/view_msds/msdsdisplaycode_author_new_MASTER.cfm?edit_... 6/14/2007 MSDS Page 3 of 7 NFPA Ratings: NFPA Flammability: 3 NFPA Health: 1 NFPA Reactivity: 0 NFPA Other: NA SECTION 6 - ACCIDENTAL RELEASE MEASURES Spill Cleanup Measures: Remove all sources of ignition. Absorb spill with inert material (e.g., dry sand or earth), then place in a chemical waste container. Provide ventilation. Collect spi with a non-sparking tool. Place into a suitable container for disposal. Personnel Precautions: Use proper personal protective equipment as listed in section 8. Environmental Precautions: Avoid runoff into storm sewers, ditches, and waterways. SECTION 7 - HANDLING and STORAGE Handling: Use with adequate ventilation. Avoid breathing vapor and contact with eyes, ski and clothing. Material will accumulate static charges which may cause an electrical spark (ignition source). Use proper grounding procedures. Storage: Store in a cool, dry, well ventilated area away from sources of heat, combustible materials, and incompatible substances. Keep container tightly closed when not in use. Work Practices: To reduce potential for static discharge, bond and ground containers when transferring material. Special Handling Procedures: Do not reuse containers without proper cleaning or reconditioning. Hygiene Practices: Wash thoroughly after handling. Avoid contact with eyes and skin. Avoid inhalin vapor or mist. SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION - EXPOSURE GUIDELINES Engineering Controls: Use appropriate engineering control such as process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Good general ventilation should be sufficient to control airborne levels. Where such systems are not effective wear suitable personal protective equipment, which performs satisfactorily and meets OSHA o other recognized standards. Consult with local procedures for selection, training inspection and maintenance of the personal protective equipment. Eye/Face Protection: Wear appropriate protective glasses or splash goggles as described by 29 CFR 1910.133, OSHA eye and face protection regulation, or the European standard EN 166. Skin Protection Description: Chemical-resistant gloves and chemical goggles, face-shield and synthetic apron or coveralls should be used to prevent contact with eyes, skin or clothing. Respiratory Protection: A NIOSH approved air-purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirato if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. Other Protective: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. EXPOSURE GUIDELINES http://www.actiocms.com/view_msds/msdsdisplaycode_author_new_MASTER.cfm?edit_... 6/14/2007 MSDS Page 4 of 7 Silicate, mica : Guideline ACGIH: TLV-TWA: 3 mg/m3 (Respirable) Guideline OSHA: OSHA-TWA: 20 mg/m3 1-Nitropropane : Guideline ACGIH: TLV-TWA: 25 ppm Guideline OSHA: OSHA-TWA: ppm Acetone : Guideline ACGIH: TLV-TWA: 500 ppm TLV-STEL: 750 ppm Guideline OSHA: OSHA-TWA: 1000 ppm Titanium dioxide : Guideline ACGIH: TLV-TWA: 10 mg/m3 Guideline OSHA: OSHA-TWA: 15 mg/m3 Carbonic acid calcium salt : Guideline ACGIH: TLV-TWA: 5 mg/m3 (Respirable) Guideline OSHA: OSHA-TWA: 5 mg/m3 Respirable Propane : Guideline ACGIH: TLV-TWA: 1000 ppm Guideline OSHA: OSHA-TWA: 1000 ppm Isobutane : Guideline ACGIH: TLV-TWA: 1000 ppm VM&P Naphtha/Aliphatic Hydrocarbon : Guideline ACGIH: TLV-TWA: 300 ppm Talc, Magnesium silicate hydrate : Guideline ACGIH: TLV-TWA: 2 mg/m3 (Respirable) Guideline OSHA: OSHA-TWA: 20 mg/m3 Xylene : Guideline ACGIH: TLV-TWA: 100 ppm TLV-STEL: 150 ppm Guideline OSHA: OSHA-TWA: 100 ppm SECTION 9 - PHYSICAL and CHEMICAL PROPERTIES Physical State Appearance: Liquid Boiling Point: No Data Melting Point: No Data Density: 10 - 12 Lbs./gal. Vapor Density: Greater than 1 (Air = 1) pH: No Data Molecular Formula: Mixture Molecular Weight: Mixture Flash Point: <32°F (<0°C) Flash Point Method: SECTION 10 - STABILITY and REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Hazardous Polymerization: Not reported. Conditions to Avoid: Heat, flames, ignition sources, and sparks. Incompatible materials. Freezing or temperatures below 32 deg. F. Incompatible Materials: Oxidizing agents. Strong acids and alkalis. http://www.actiocms.com/view_msds/msdsdisplaycode_author_new_MASTER.cfm?edit_... 6/14/2007 MSDS Page 5 of 7 SECTION 11 - TOXICOLOGICAL INFORMATION RTECS Number: VV8760000 RTECS Number: VM2940000 Acetone : Eye: Eye - Rabbit; Standard Draize Test : 10 uL - mild (RTECS) Skin: Skin - Guinea pig; LD50: >9400 uL/kg - Details of toxic effects not reported other than lethal dose value. (RTECS) Inhalation: Inhalation - Rat LC50: 50100 mg/m3/8H - [Details of toxic effects not reported other than lethal dose value Inhalation - Mouse LC50: 44 gm/m3/4H - Details of toxic effects not reported other than lethal dose value. (RTECS) Ingestion: Ingestion - Rat LD50: 5800 mg/kg - Behavioral - altered sleep time (including change in righting reflex) Behavioral - tremor Ingestion - Mouse LD50: 3 gm/kg - [Details of toxic effects not reported other than lethal dose value. (RTECS) Titanium dioxide : RTECS Number: XR2275000 Skin: Skin - Rabbit; Standard Draize Test : 300 ug/3D; (Intermittent) mild. (RTECS) Ingestion: Ingestion - Rat TDLo: 60 gm/kg; Gastrointestinal - hypermotility, diarrhea Gastrointestinal - other changes. (RTECS) Carcinogenicity: IARC: Group 2B: Possibly carcinogenic to humans RTECS Number: FF9335000 Isobutane : Inhalation: Inhalation - Rat LC50: 570,000 ppm/15M - [Behavioral - tremor Behavioral convulsions or effect on seizure threshold Lungs, Thorax, or Respiration respiratory depression] (RTECS) VM&P Naphtha/Aliphatic Hydrocarbon : RTECS Number: OI6180000 Eye: Eye's - Human: 880 ppm/15M; No effects reported. (RTECS) Talc, Magnesium silicate hydrate : RTECS Number: WW2710000 Carcinogenicity: IARC: Group 3: Unclassifiable as to carcinogenicity to humans Xylene : RTECS Number: ZE2100000 Eye: Eye - Rabbit; Standard Draize Test : 87 mg; mild. Eye - Rabbit; Standard Draize Test : 5 mg/24H; severe. (RTECS) Skin: Skin - Rabbit; Standard Draize Test : 100%; Moderate. Skin - Rabbit; Standard Draize Test : 500 mg/24H; Moderate. (RTECS) Inhalation: Inhalation - Rat LC50: 5000 ppm/4H; Details of toxic effects not reported other than lethal dose value (RTECS) Ingestion: Ingestion - Rat LD50: 4300 mg/kg; Liver - other changes Kidney, Ureter, Bladder - other changes Ingestion - Mouse LD50: 2119 mg/kg; Details of toxic effects not reported othe than lethal dose value (RTECS) Carcinogenicity: IARC: Group 3: Unclassifiable as to carcinogenicity to humans Palygorskite : RTECS Number: RT6400000 Carcinogenicity: IARC: Group 2B: Possibly carcinogenic to humans SECTION 12 - ECOLOGICAL INFORMATION Ecotoxicity: No ecotoxicity data was found for the product. Environmental Fate: No environmental information found for this product. http://www.actiocms.com/view_msds/msdsdisplaycode_author_new_MASTER.cfm?edit_... 6/14/2007 MSDS Page 6 of 7 SECTION 13 - DISPOSAL CONSIDERATIONS Waste Disposal: Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the classifications of hazardous waste prior to disposal. Furthermore, consult with your state and local waste requirements or guidelines, if applicable, to ensure compliance. Arrange disposal in accordance to the EPA and/or state and local guidelines. Important Disposal Information: DANGER! Rags, steel wool and waste soaked with this product may spontaneously catch fire if improperly discarded or stored. To avoid a spontaneous combustion fire, immediately after use, place rags, steel wool or waste in a sealed, water-filled, metal container. Do not store unused product inside the home. For disposal guidance, contact your household refuse collection service, fire department, county or state government environmental control agency. SECTION 14 - TRANSPORT INFORMATION DOT Shipping Name: Aerosol flammable DOT Hazard Class: 2.1 DOT Packing Group: III SECTION 15 - REGULATORY INFORMATION Silicate, mica : TSCA Inventory Status: Not listed State Regulations: Listed in the New Jersey State Right to Know List. Listed in the Pennsylvania State Hazardous Substances List. Canada DSL: Listed Rutile : TSCA Inventory Status: Listed State Regulations: Listed in the Pennsylvania State Hazardous Substances List. Canada DSL: Listed 1-Nitropropane : State Regulations: Listed in the Pennsylvania State Hazardous Substances List.. Canada DSL: Listed Non-hazardous ingredients : TSCA Inventory Status: Contains calcium carbonate (CAS:1317-65-3), which is listed in the TSCA inventory. Acetone : TSCA Inventory Status: Listed State Regulations: Listed in the Pennsylvania State Hazardous Substances List. Canada DSL: Listed Titanium dioxide : TSCA Inventory Status: Listed State Regulations: Listed in the New Jersey State Right to Know List. Listed in the Pennsylvania State Hazardous Substances List. Canada DSL: Listed Carbonic acid calcium salt : Canada DSL: Listed Propane : TSCA Inventory Status: Listed State Regulations: Listed in the Pennsylvania State Hazardous Substances List. Listed in the New Jersey State Right to Know List. http://www.actiocms.com/view_msds/msdsdisplaycode_author_new_MASTER.cfm?edit_... 6/14/2007 MSDS Page 7 of 7 Canada DSL: Listed Isobutane : TSCA Inventory Status: Listed State Regulations: Listed in the Pennsylvania State Hazardous Substances List. Listed in the New Jersey State Right to Know List.. Canada DSL: Listed VM&P Naphtha/Aliphatic Hydrocarbon : TSCA Inventory Status: Listed State Regulations: Listed in the New Jersey State Right to Know List. Listed in the Pennsylvania State Hazardous Substances List. Canada DSL: Listed Talc, Magnesium silicate hydrate : TSCA Inventory Status: Listed State Regulations: Listed in the New Jersey State Right to Know List. Listed in the Pennsylvania State Hazardous Substances List. Canada DSL: Listed Xylene : TSCA Inventory Status: Listed State Regulations: Listed in the New Jersey State Right to Know List. Listed in the Pennsylvania State Hazardous Substances List. Canada DSL: Listed Palygorskite : TSCA Inventory Status: Not listed Canada DSL: Not listed SECTION 16 - ADDITIONAL INFORMATION HMIS Fire Hazard: 3 HMIS Health Hazard: 1 HMIS Reactivity: 0 HMIS Personal Protection: x MSDS Creation Date: 06/26/2006 MSDS Revision Date: 05/09/2007 MSDS Revision Notes: Quarterly and format update MSDS Author: Actio Corporation Disclaimer: This Health and Safety Information is correct to the best of our knowledge and belief at the date of its publication but we cannot accept liability for any loss, injury or damage which may result from its use. We shall ensure, so far as is reasonably practicable, that any revision of this Data Sheet is sent to all customers to whom we have directly supplied this substance, but must point ou that it is the responsibility of any intermediate supplier to ensure that such revision is passed to the ultimate user. The information given in the Data Sheet is designed only as a guidance for safe handling, storage and the use of the substance. It is not a specification nor does it guarantee any specific properties. All chemicals should be handled only by competent personnel, within a controlled environment. Should further information be required, this can be obtained through the sales office whose address is at the top of this data sheet. Trademark: The trademarks, service marks, graphics and logos used on this MSDS are registered or unregistered trademarks of BEHR Process Corporation. All Rights Reserved. Copyright© 1996-2006 Actio Software Corporation. All Rights Reserved. http://www.actiocms.com/view_msds/msdsdisplaycode_author_new_MASTER.cfm?edit_... 6/14/2007 MSDS Page 1 of 8 View MSDS : 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION NFPA Product Name: 3 KILZ® Upshot 0 1 MSDS Manufacturer Number: 10007 NA Manufacturer Name: Masterchem Industries LLC Address: 3135 Old Highway M Imperial, MO 63052-2834 General Phone Number: (636) 942-2510 General Fax Number: (636) 942-3663 Health Hazard 1 Customer Service Phone Number: (800) 325-3552 Fire Hazard CHEMTREC: For emergencies in the US, call CHEMTREC: 800-424-9300 REACTIVITY 0 Canutec: In Canada, call CANUTEC: (613) 996-6666 (call collect) MSDS Creation Date: 07/15/2006 Personal Protection MSDS Revision Date: 05/09/2007 * HMIS 3 x Chronic Health Effects: SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS# Ingredient Percent Silicate, mica 12001-26-2 10 - 30 by Weight Limestone (calcium carbonate) 1317-65-3 1-10 by Weight Rutile 1317-80-2 5 - 10 by Weight Octanes, all isomers No data 5 - 10 by Weight Nonanes Mixture 1-10 by Weight Non-hazardous ingredients N/A 1 - 5 by Weight Octanes, all isomers Mixture 1-5 by Weight 1-Nitropropane 108-03-2 1-5 by Weight Acetone 67-64-1 10-30 by Weight Titanium dioxide 13463-67-7 10 - 30 by Weight Carbonic acid calcium salt 471-34-1 10 - 30 by Weight Propane 74-98-6 10-30 by Weight Isobutane 75-28-5 10-30 by Weight VM&P Naphtha/Aliphatic Hydrocarbon 8032-32-4 10 - 30 by Weight http://www.actiocms.com/view_msds/msdsdisplaycode_author_new_MASTER.cfm?edit_... 6/14/2007 MSDS Page 2 of 8 Nonanes No data 10 - 30 by Weight Talc, Magnesium silicate hydrate 14807-96-6 1 - 5 by Weight Talc (powder), containing no asbestos fibers 14807-96-6 1-5 by Weight Xylene 1330-20-7 0.1 - 1 by Weight Palygorskite 12174-11-7 0.1 - 1 by Weight SECTION 3 - HAZARDS IDENTIFICATION Emergency Overview: Flammable aerosol. Irritant. Contents under pressure. Potential Health Effects: Eye: May cause irritation. Skin: May cause irritation. Inhalation: Prolonged or excessive inhalation may cause respiratory tract irritation. Ingestion: Harmful if swallowed. Ingestion can cause nausea, vomiting, diarrhea and gastrointestinal irritation. Chronic Health Effects: Prolonged or repeated contact can result in defatting and drying of the skin, which may result in skin irritation and dermatitis (rash). Repeated or prolonged inhalation may cause toxic effects. Signs/Symptoms: Overexposure can cause headaches, dizziness, nausea, and vomiting. Target Organs: Eyes. Skin. Respiratory system. Digestive system. Central nervous system. Kidney. Aggravation of Pre-Existing Conditions: May aggravate pre-existing respiratory disorders, allergy, eczema, or skin conditions. SECTION 4 - FIRST AID MEASURES Eye Contact: Immediately flush eyes with plenty of water for 15 to 20 minutes. Get medical attention, if irritation or symptoms of overexposure persists. Skin Contact: Immediately wash skin with soap and plenty of water. Get medical attention if irritation develops or persists. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek immediate medical attention. Ingestion: If swallowed, do NOT induce vomiting. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Other First Aid: Due to possible aspiration into the lungs, DO NOT induce vomiting if ingested. Provide a glass of water to dilute the material in the stomach. If vomiting occurs naturally, have the person lean forward to reduce the risk of aspiration. SECTION 5 - FIRE FIGHTING MEASURES Flammable Properties: Flammable aerosol. Contents are under pressure. Will release flammable vapors at well below ambient temperatures and readily form flammable mixtures with air. It will burn in the open and may be explosive in confined spaces. Flash Point: <32°F (0°C) Flash Point Method: TOC Fire Fighting Instructions: Flammable. Cool fire-exposed containers using water spray. Extinguishing Media: Use alcohol foam, carbon dioxide, dry chemical, or water fog or spray when fighting fires involving this material. Protective Equipment: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Unusual Fire Hazards: Flammable liquid. Vapors can form an ignitable mixture with air. Vapors can flow http://www.actiocms.com/view_msds/msdsdisplaycode_author_new_MASTER.cfm?edit_... 6/14/2007 MSDS Page 3 of 8 along surfaces to a distant ignition source and flash back. NFPA Ratings: NFPA Flammability: 3 NFPA Health: 1 NFPA Reactivity: 0 NFPA Other: NA SECTION 6 - ACCIDENTAL RELEASE MEASURES Spill Cleanup Measures: Remove all sources of ignition. Absorb spill with inert material (e.g., dry sand or earth), then place in a chemical waste container. Provide ventilation. Collect spi with a non-sparking tool. Place into a suitable container for disposal. Personnel Precautions: Use proper personal protective equipment as listed in section 8. Environmental Precautions: Avoid runoff into storm sewers, ditches, and waterways. SECTION 7 - HANDLING and STORAGE Handling: Use with adequate ventilation. Avoid breathing vapor and contact with eyes, ski and clothing. Material will accumulate static charges which may cause an electrical spark (ignition source). Use proper grounding procedures. Storage: Store in a cool, dry, well ventilated area away from sources of heat, combustible materials, and incompatible substances. Keep container tightly closed when not in use. Do not store in temperatures above 120 °F. Work Practices: To reduce potential for static discharge, bond and ground containers when transferring material. Special Handling Procedures: Handle with care. Contents are under pressure. Excessive pressure and temperature will cause over pressurization and result in container bursting or exploding. Hygiene Practices: Wash thoroughly after handling. Avoid contact with eyes and skin. Avoid inhalin vapor or mist. SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION - EXPOSURE GUIDELINES Engineering Controls: Use appropriate engineering control such as process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Good general ventilation should be sufficient to control airborne levels. Where such systems are not effective wear suitable personal protective equipment, which performs satisfactorily and meets OSHA o other recognized standards. Consult with local procedures for selection, training inspection and maintenance of the personal protective equipment. Eye/Face Protection: Wear appropriate protective glasses or splash goggles as described by 29 CFR 1910.133, OSHA eye and face protection regulation, or the European standard EN 166. Skin Protection Description: Chemical-resistant gloves and chemical goggles, face-shield and synthetic apron or coveralls should be used to prevent contact with eyes, skin or clothing. Respiratory Protection: A NIOSH approved air-purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirato if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. Other Protective: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. http://www.actiocms.com/view_msds/msdsdisplaycode_author_new_MASTER.cfm?edit_... 6/14/2007 MSDS Page 4 of 8 EXPOSURE GUIDELINES Silicate, mica : Guideline ACGIH: TLV-TWA: 3 mg/m3 (Respirable) Guideline OSHA: OSHA-TWA: 20 mg/m3 1-Nitropropane : Guideline ACGIH: TLV-TWA: 25 ppm Guideline OSHA: OSHA-TWA: ppm Acetone : Guideline ACGIH: TLV-TWA: 500 ppm TLV-STEL: 750 ppm Guideline OSHA: OSHA-TWA: 1000 ppm Titanium dioxide : Guideline ACGIH: TLV-TWA: 10 mg/m3 Guideline OSHA: OSHA-TWA: 15 mg/m3 Carbonic acid calcium salt : Guideline ACGIH: TLV-TWA: 5 mg/m3 (Respirable) Guideline OSHA: OSHA-TWA: 5 mg/m3 Respirable Propane : Guideline ACGIH: TLV-TWA: 1000 ppm Guideline OSHA: OSHA-TWA: 1000 ppm Isobutane : Guideline ACGIH: TLV-TWA: 1000 ppm VM&P Naphtha/Aliphatic Hydrocarbon : Guideline ACGIH: TLV-TWA: 300 ppm Talc, Magnesium silicate hydrate : Guideline ACGIH: TLV-TWA: 2 mg/m3 (Respirable) Guideline OSHA: OSHA-TWA: 20 mg/m3 Talc (powder), containing no asbestos fibers : Guideline ACGIH: TLV-TWA: 2 mg/m3 (Respirable) Guideline OSHA: OSHA-TWA: 20 mg/m3 Xylene : Guideline ACGIH: TLV-TWA: 100 ppm TLV-STEL: 150 ppm Guideline OSHA: OSHA-TWA: 100 ppm SECTION 9 - PHYSICAL and CHEMICAL PROPERTIES Physical State Appearance: Liquid Boiling Point: No Data Melting Point: No Data Density: 10 - 12 Lbs./gal. Vapor Density: Greater than 1 (Air = 1) pH: No Data Molecular Formula: Mixture Molecular Weight: Mixture Flash Point: <32°F (0°C) Flash Point Method: TOC SECTION 10 - STABILITY and REACTIVITY http://www.actiocms.com/view_msds/msdsdisplaycode_author_new_MASTER.cfm?edit_... 6/14/2007 MSDS Page 5 of 8 Chemical Stability: Stable under normal temperatures and pressures. Hazardous Polymerization: Not reported. Conditions to Avoid: Heat, flames, ignition sources, and sparks. Incompatible materials. Freezing or temperatures below 32 deg. F. Temperatures above 120 °F. Incompatible Materials: Oxidizing agents. Strong acids and alkalis. SECTION 11 - TOXICOLOGICAL INFORMATION RTECS Number: VV8760000 RTECS Number: VM2940000 Acetone : Eye: Eye - Rabbit; Standard Draize Test : 10 uL - mild (RTECS) Skin: Skin - Guinea pig; LD50: >9400 uL/kg - Details of toxic effects not reported other than lethal dose value. (RTECS) Inhalation: Inhalation - Rat LC50: 50100 mg/m3/8H - [Details of toxic effects not reported other than lethal dose value Inhalation - Mouse LC50: 44 gm/m3/4H - Details of toxic effects not reported other than lethal dose value. (RTECS) Ingestion: Ingestion - Rat LD50: 5800 mg/kg - Behavioral - altered sleep time (including change in righting reflex) Behavioral - tremor Ingestion - Mouse LD50: 3 gm/kg - [Details of toxic effects not reported other than lethal dose value. (RTECS) Titanium dioxide : RTECS Number: XR2275000 Skin: Skin - Rabbit; Standard Draize Test : 300 ug/3D; (Intermittent) mild. (RTECS) Ingestion: Ingestion - Rat TDLo: 60 gm/kg; Gastrointestinal - hypermotility, diarrhea Gastrointestinal - other changes. (RTECS) Carcinogenicity: IARC: Group 2B: Possibly carcinogenic to humans RTECS Number: FF9335000 Isobutane : Inhalation: Inhalation - Rat LC50: 570,000 ppm/15M - [Behavioral - tremor Behavioral convulsions or effect on seizure threshold Lungs, Thorax, or Respiration respiratory depression] (RTECS) VM&P Naphtha/Aliphatic Hydrocarbon : RTECS Number: OI6180000 Eye: Eye's - Human: 880 ppm/15M; No effects reported. (RTECS) Talc, Magnesium silicate hydrate : RTECS Number: WW2710000 Carcinogenicity: IARC: Group 3: Unclassifiable as to carcinogenicity to humans Talc (powder), containing no asbestos fibers : Carcinogenicity: IARC: Group 3: Unclassifiable as to carcinogenicity to humans Xylene : RTECS Number: ZE2100000 Eye: Eye - Rabbit; Standard Draize Test : 87 mg; mild. Eye - Rabbit; Standard Draize Test : 5 mg/24H; severe. (RTECS) Skin: Skin - Rabbit; Standard Draize Test : 100%; Moderate. Skin - Rabbit; Standard Draize Test : 500 mg/24H; Moderate. (RTECS) Inhalation: Inhalation - Rat LC50: 5000 ppm/4H; Details of toxic effects not reported other than lethal dose value (RTECS) Ingestion: Ingestion - Rat LD50: 4300 mg/kg; Liver - other changes Kidney, Ureter, Bladder - other changes Ingestion - Mouse LD50: 2119 mg/kg; Details of toxic effects not reported othe than lethal dose value (RTECS) Carcinogenicity: IARC: Group 3: Unclassifiable as to carcinogenicity to humans Palygorskite : RTECS Number: RT6400000 Carcinogenicity: IARC: Group 2B: Possibly carcinogenic to humans http://www.actiocms.com/view_msds/msdsdisplaycode_author_new_MASTER.cfm?edit_... 6/14/2007 MSDS Page 6 of 8 SECTION 12 - ECOLOGICAL INFORMATION Ecotoxicity: No ecotoxicity data was found for the product. Environmental Fate: No environmental information found for this product. SECTION 13 - DISPOSAL CONSIDERATIONS Waste Disposal: Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the classifications of hazardous waste prior to disposal. Furthermore, consult with your state and local waste requirements or guidelines, if applicable, to ensure compliance. Arrange disposal in accordance to the EPA and/or state and local guidelines. Important Disposal Information: DANGER! Rags, steel wool and waste soaked with this product may spontaneously catch fire if improperly discarded or stored. To avoid a spontaneous combustion fire, immediately after use, place rags, steel wool or waste in a sealed, water-filled, metal container. Do not store unused product inside the home. For disposal guidance, contact your household refuse collection service, fire department, county or state government environmental control agency. SECTION 14 - TRANSPORT INFORMATION DOT Shipping Name: Aerosol flammable DOT Hazard Class: 2.1 DOT Packing Group: III SECTION 15 - REGULATORY INFORMATION Silicate, mica : TSCA Inventory Status: Not listed State Regulations: Listed in the New Jersey State Right to Know List. Listed in the Pennsylvania State Hazardous Substances List. Canada DSL: Listed Limestone (calcium carbonate) : TSCA Inventory Status: Contains calcium carbonate (CAS:1317-65-3), which is listed in the TSCA inventory. State Regulations: Listed in the Pennsylvania State Hazardous Substances List.. Rutile : TSCA Inventory Status: Listed State Regulations: Listed in the Pennsylvania State Hazardous Substances List. Canada DSL: Listed 1-Nitropropane : State Regulations: Listed in the Pennsylvania State Hazardous Substances List.. Canada DSL: Listed Acetone : TSCA Inventory Status: Listed State Regulations: Listed in the Pennsylvania State Hazardous Substances List. Canada DSL: Listed Titanium dioxide : http://www.actiocms.com/view_msds/msdsdisplaycode_author_new_MASTER.cfm?edit_... 6/14/2007 MSDS Page 7 of 8 TSCA Inventory Status: Listed State Regulations: Listed in the New Jersey State Right to Know List. Listed in the Pennsylvania State Hazardous Substances List. Canada DSL: Listed Carbonic acid calcium salt : Canada DSL: Listed Propane : TSCA Inventory Status: Listed State Regulations: Listed in the Pennsylvania State Hazardous Substances List. Listed in the New Jersey State Right to Know List. Canada DSL: Listed Isobutane : TSCA Inventory Status: Listed State Regulations: Listed in the Pennsylvania State Hazardous Substances List. Listed in the New Jersey State Right to Know List.. Canada DSL: Listed VM&P Naphtha/Aliphatic Hydrocarbon : TSCA Inventory Status: Listed State Regulations: Listed in the New Jersey State Right to Know List. Listed in the Pennsylvania State Hazardous Substances List. Canada DSL: Listed Talc, Magnesium silicate hydrate : TSCA Inventory Status: Listed State Regulations: Listed in the New Jersey State Right to Know List. Listed in the Pennsylvania State Hazardous Substances List. Canada DSL: Listed Talc (powder), containing no asbestos fibers : TSCA Inventory Status: Listed State Regulations: Listed in the New Jersey State Right to Know List. Listed in the Pennsylvania State Hazardous Substances List. Canada DSL: Listed Xylene : TSCA Inventory Status: Listed State Regulations: Listed in the New Jersey State Right to Know List. Listed in the Pennsylvania State Hazardous Substances List. Canada DSL: Listed Palygorskite : TSCA Inventory Status: Canada DSL: Not listed Not listed WARNING: This product contains a chemical known to the state of California to cause cancer and birth defects or other reproductive harm. SECTION 16 - ADDITIONAL INFORMATION HMIS Fire Hazard: 3 HMIS Health Hazard: 1 HMIS Reactivity: 0 HMIS Personal Protection: x MSDS Creation Date: 07/15/2006 MSDS Revision Date: 05/09/2007 MSDS Revision Notes: Quarterly and format update MSDS Author: Actio Corporation Disclaimer: This Health and Safety Information is correct to the best of our knowledge and belief at the date of its publication but we cannot accept liability for any loss, injury or damage which may result from its use. We shall ensure, so far as is reasonably practicable, that any revision of this Data Sheet is sent to all http://www.actiocms.com/view_msds/msdsdisplaycode_author_new_MASTER.cfm?edit_... 6/14/2007 MSDS Page 8 of 8 customers to whom we have directly supplied this substance, but must point ou that it is the responsibility of any intermediate supplier to ensure that such revision is passed to the ultimate user. The information given in the Data Sheet is designed only as a guidance for safe handling, storage and the use of the substance. It is not a specification nor does it guarantee any specific properties. All chemicals should be handled only by competent personnel, within a controlled environment. Should further information be required, this can be obtained through the sales office whose address is at the top of this data sheet. Trademark: The trademarks, service marks, graphics and logos used on this MSDS are registered or unregistered trademarks of BEHR Process Corporation. All Rights Reserved. Copyright© 1996-2006 Actio Software Corporation. All Rights Reserved. http://www.actiocms.com/view_msds/msdsdisplaycode_author_new_MASTER.cfm?edit_... 6/14/2007 FICHE SIGNALÉTIQUE SANTÉ−SÉCURITÉ DH1606 02 00 =========================================================================== Section 1 −− IDENTIFICATION DU PRODUIT ET DE LA SOCIÉTÉ −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− NUMÉRO DU PRODUIT Santé 2* DH1606 Inflammabilité 3 Réactivité 1 NOM DU PRODUIT DUPLI−COLOR* High Heat with Ceramic, Aluminum NOM DU FABRICANT NO. DE TÉLÉPHONE EN CAS D’URGENCE SHERWIN−WILLIAMS CANADA, INC. (216) 566−2917 DUPLI−COLOR Products Group Vaughan, ON L4K 4T8 DATE DE PRÉPARATION NO. DE TÉLÉPHONE ORDINAIRE 06−JAN−07 (905) 761−9185 =========================================================================== Section 2 −− COMPOSITION/INFORMATION SUR LES INGRÉDIENTS % EN POIDS CAS No. INGREDIENT UNITÉS PRESSION VAPEUR −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 14 74−98−6 Propane ACGIH TLV 2500 ppm 760 mm OSHA PEL 1000 ppm 13 106−97−8 Butane ACGIH TLV 800 ppm 760 mm OSHA PEL 800 ppm 2 64742−88−7 Solvant Naphta Aliphatique Moyen ACGIH TLV 100 ppm 2 mm OSHA PEL 100 ppm 8 108−88−3 Toluène ACGIH TLV 50 ppm (Peau) 22 mm OSHA PEL 100 ppm (Peau) OSHA PEL 150 ppm (Peau) STEL 1.0 100−41−4 Éthylbenzène ACGIH TLV 100 ppm 7.1 mm ACGIH TLV 125 ppm STEL OSHA PEL 100 ppm OSHA PEL 125 ppm STEL 5 1330−20−7 Xylène ACGIH TLV 100 ppm 5.9 mm ACGIH TLV 150 ppm STEL OSHA PEL 100 ppm OSHA PEL 150 ppm STEL 26 67−64−1 Acetone ACGIH TLV 500 ppm 180 mm ACGIH TLV 750 ppm STEL OSHA PEL 1000 ppm 12 108−10−1 Méthylisobutylcétone ACGIH TLV 50 ppm 16 mm ACGIH TLV 75 ppm STEL OSHA PEL 50 ppm OSHA PEL 75 ppm STEL Suite à la page 2 DH1606 page 2 =========================================================================== 2 763−69−9 3−Éthoxypropionate d’éthyle ACGIH TLV Pas Disponible 1.11 mm OSHA PEL Pas Disponible =========================================================================== Section 3 −− IDENTIFICATION DES RISQUES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− SOURCES D’EXPOSITION L’exposition peut se produire par l’INHALATION des vapeurs ou du brouillard de pulvérisation. La PEAU et les YEUX peuvent entrer en contact avec le produit, les vapeurs ou le brouillard de pulvérisation. EFFET DE LA SUREXPOSITION YEUX: Irritation des YEUX. PEAU: L’exposition prolongée ou répétée risque de provoquer l’irritation des peau. INHALATION: Irritation des voies respiratoires supérieures. Peut causer la dépression nerveuse. Une sur−exposition excessive à ce produit peut entrainer la perte de conscience, voire même la mort. SYMPTÔMES DE SUREXPOSITION Les maux de tête, l’étourdissement, la nausée et la perte de coordination des mouvements sont tous des symptômes d’exposition excessive aux vapeurs ou à la brume de pulvérisation. La rougeur et les démangeaisons ou la sensation de brûlure peuvent indiquer une exposition excessive des yeux ou de la peau. ETAT DE SANTÉ AGGRAVÉ PAR EXPOSITION En général, aucun exposition n’est reconnue. CANCÉROGÉNICITÉ Voir la Section 11. =========================================================================== Section 4 −− PREMIERS SOINS −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− YEUX: Rincer les yeux à grande eau pendant 15 minutes. Aller voir un médecin. PEAU: Laver à fond les parties affectées avec de l’eau et du savon. Enlever les habits contaminés et les laver avant de les porter de nouveau. INHALATION: Si une personne en est affectée, l’aider à sortir des lieux. Rétablir la respiration. Aider la personne á rester calme et au chaud. INGESTION: N’incitez pas la personne á vomir. Aller voir un médecin immédiatement. =========================================================================== Section 5 −− MESURES EN CAS D’INCENDIE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− POINT D’ÉCLAIR LIE LSE Propellant < 0 F 1.0 12.8 MOYENS D’EXTINCTION Dioxyde de carbone, produit chimique sec, mousse Suite à la page 3 DH1606 page 3 =========================================================================== DANGERS D’INCENDIE OU D’EXPLOSION EXCEPTIONNELS Les contenants peuvent exploser s’ils sont exposés à une très grande chaleur. L’application aux surfaces chaudes exige qu’on prenne des précautions spéciales. En cas d’urgence, une exposition excessive aux produits de décomposition peut constituer un danger pour la santé. Les symptômes peuvent ne pas se manifester immédiatement. Voir le médecin. MESURES PARTICULIÉRES DI PROTECTION CONTRE L’INCENDIE On doit utiliser l’équipement de protection complète y compris un appareil de respiration auto−alimenté. La pulvérisation avec de l’eau peut être inefficace. Si on se sert de l’eau, l’ajutage pour brume est préférable. On peut se servir de l’eau pour refroidir les contenants fermés afin d’empêcher l’augmentation de la pression et la possibilité d’une combustion automatique ou l’explosion en cas d’exposition à une chaleur extrêmement grande. =========================================================================== Section 6 −− MARCHE Á SUIVRE EN CAS DE DÉVERSEMENT ACCIDENTEL −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− MESURES À PRENDRE LORSQUE DES MATIÉRES SONT RENVERSÉES OU ÉVAPORÉES Enlever toute source de combustion. Bien aérer. Nettoyer avec un absorbant non réactif. =========================================================================== Section 7 −− MANUTENTION ET ENTREPOSAGE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− CATÉGORIE D’ENTREPOSAGE Pas Disponible PRÉCAUTIONS Á PRENDRE LORS DE L’ENTREPOSAGE DI LA MANIPULATION Tenir loin de la chaleur, étincelles et de flamme nue. Les vapeurs peuvent s’accumuler rapidement et s’enflammer et causer une explosion. Aucours de l’utilisation de ce produit jusqu’à la disparution de toutes les vapeurs: Garder l’endroit bien aéré. Eviter de fumer. Eteindre toute flamme, veilleuse d’appareils et réchauds. Couper la courant des poêles, des outils et appareils éléctriques ainsi que de toute autre source de combustion. Suivre les procédures approuvées pour attacher solidement et pour permettre l’écoulement de l’éléctricité dans le sol. Contenu sous pression. Ne pas ouvrir, incinérer ou exposer à des températures au dessus de 120 Fahrenheit. La chaleur des rayons du soleil, des radiateurs, des réchauds, de l’eau chaude, ou provenant de toute autre source, peut provoquer l’explosion du contenant. Ne pas avaler. Garder hors de la portée des enfants. Suite à la page 4 DH1606 page 4 =========================================================================== Section 8 −− CONTRÔLE DE L’EXPOSITION ET PROTECTION INDIVIDUELLE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRÉCAUTIONS À PRENDRE AUCOURS DE L’UTILISATION N’utiliser ce produit que dans un endroit bien aéré. Éviter tout contact avec la peau et les yeux. Eviter d’aspirer les vapeurs et la brume de vaporisation. Bien se laver les mains après l’utilisation. Ce produit peut contenir des matières classifiées comme petites particules irritantes, telles que le dioxyde de titane ou le carbonate de calcium (voir la liste ACGIH TLV, la préface et l’annexe D). On peut avoir ces particules dans des proportions dangereuses uniquement au moment du grattement et de l’éraflement de la couche séchée. Si la liste dans la 2e section ne fait aucune mention spécifique de la présence des poussières de particules, les limites applicables sont: pour ACGIH TLV 10 mg/m3 (concentration totale de poussière), 3 mg/m3 (fractionée de respiratoire). VENTILATION Un système permettant l’échappement local des produits est préférable. Si l’exposition aux produits de la 2e section est maintenue au−dessous des limites d’exposition applicables, le système d’échappement global est acceptable. PROTECTION DES VOIES RESPIRATOIRES Si on ne peut pas maintenir, par simple ventilation, le niveau auquel on s’expos personnellement en dessous des limites applicables, porter un respirateur à filtre de vapeur organique et particules approprié et bien ajusté approuvé par NIOSH/MSHA pour se protéger contre les produits de la 2e section. Pendant que vous frottez ou poncez la couche sechée, porter un respirateur à filtre de poussière et de brume, approuvé par NIOSH/MSHA pour vous protéger contre la poussière qui peut éventuellement se dégager de ce produit, de la peinture ou de l’abrasif. GANTS PROTECTEURS Aucun n’est exigé pour l’application normale des produits aérosol, lorsqu’on n’attend qu’un minimum de contact avec la peau. Pour un contact prolongé et repété, portez des gants resistants aux produits chimiques. LUNETTES DE SÉCURITÉ Porter les lunetttes de sécurité avec des protecteurs latéraux non perforés. AUTRES PRÉCAUTIONS L’utilisation inappropriée de ce produit en le concentrant et en l’aspirant intentionnellement peut être dangereuse ou peut même causer la mort. =========================================================================== Section 9 −− PROPRIÉTÉS PHYSIQUES ET CHIMIQUES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− POIDS DU PRODUIT 6.29 lb/gal 753 g/l DENSITÉ 0.76 COURBE D’ÉBULLITION <0 − 395 F <−18 − 201 C POINT DE FUSION P.D. VOLUME VOLATIL 91 % VITESSE D’ÉVAPORATION Plus vite que l’Éther DENSITÉ DE LA VAPEUR Plus lourd que l’Air SOLUBILITÉ DANS L’EAU P.D. COMPOSÉS ORGANIQUES VOLATILS (Théorique) Volatil Poids 58.28% Moins d’eau et de solvants exemptés Suite à la page 5 DH1606 page 5 =========================================================================== Section 10 −− STABILITÉ ET RÉACTIVITÉ −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STABILITÉ −− Stable CONDITIONS À ÉVITER Aucun connu. INCOMPATIBILITÉ Aucun connu. PRODUITS DANGEREUX DÛ À LA DÉCOMPOSITION Par combustion: Dioxyde de carbone, monoxyde de carbone POLYMÉRISATION DANGEREUSE Ne Peut Pas De Produire =========================================================================== Section 11 −− DONNÉES TOXICOLOGIQUES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− RISQUES DE SANTÉ CHRONIQUES À partir de données expérimentales provenant d’études suffisantes mendées chez les animaux et d’études insuffisantes menées chez humains, l’éthylbenzène est classifié par le CIRC comme étant possiblement carcinogène chez les humains (group 2B). On a constaté une augmentation de certains types de cancer, y compris des tumeurs du rein chez les rats et des tumeurs du poumon et du foie chez les souris, lorsque ces animaux ont été exposés à l’inhalation de concentrations élevées d’éthylbenzène à long terme. Toutefois, ces effets n’ont pas étéobservés chez les animaux exposés à de plus faibles concentrations d’éthylbenzène. Jusqu’à présent il n’y a aucune preuve suggérant que l’éthylbenzène provoque le cancer chez les humains. L’exposition, excessive et prolongée, aux solvants de la 2 section peut entrainer demauvaises conséquences aux systèmesdu fois,urinaire,cardio−vasculaire etreproductif. Il existe des rapports de recherches qui associent des troubles permanentes du cerveau et du système nerveux à l’exposition excessive, répétée et prolongée aux solvants. −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− INFORMATION TOXICOLOGIQUE Suite à la page 6 DH1606 page 6 =========================================================================== CAS No. Ingredient −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 74−98−6 Propane LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible 106−97−8 Butane LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible 64742−88−7 Solvant Naphta Aliphatique Moyen LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible 108−88−3 Toluène LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 100−41−4 Éthylbenzène LC50 RAT 4HR Pas Disponible LD50 RAT 3500 mg/kg 1330−20−7 Xylène LC50 RAT 4HR 5000 ppm LD50 RAT 4300 mg/kg 67−64−1 Acetone LC50 RAT 4HR Pas Disponible LD50 RAT 5800 mg/kg 108−10−1 Méthylisobutylcétone LC50 RAT 4HR Pas Disponible LD50 RAT 2080 mg/kg 763−69−9 3−Éthoxypropionate d’éthyle LC50 RAT 4HR Pas Disponible LD50 RAT 5000 mg/kg =========================================================================== Section 12 −− DONNÉES ÉCOLOGIQUES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− Aucunes donnies disponibles. =========================================================================== Section 13 −− DONNÉES SUR L’ÉLIMINATION DU PRODUIT −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− MÉTHODE D’ÉLIMINATION DES DÉCHETS Les déchets provenant de ce produit peuvent être dangereux, selon la définition donnée dans la "U.S. Resource Conservation and Recovery Act" (RCRA) 40 CFR 261. On doit soumettre les déchets au test de combustion afin de déterminer les numéros de l’EPA applicables. Ne pas incinérer. Eliminer la pression dans le contenant. Se débarrasser du contenu confermément aux lois anti−pollution fédérales, provinciales et municipales. =========================================================================== Section 14 −− DONNÉES SUR LE TRANSPORT −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− Aucunes donnies disponibles. Suite à la page 7 DH1606 page 7 =========================================================================== Section 15 −− DONNÉES SUR LA RÉGLEMENTATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− SARA 313 (40 CFR 372.65C) AVIS DE FOURNISSEUR CAS No. CHIMIQUE/COMPOSÉ % by WT % Element −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 108−88−3 Toluène 8 100−41−4 Éthylbenzène 0.9 1330−20−7 Xylène 5 108−10−1 Méthylisobutylcétone 12 DONNÉES SUR LA TSCA Tous les produits chimiques dans ce produit sont énumérés, ou exemptez de l’énumération, sur le inventaire de TSCA. =========================================================================== Section 16 −− AUTRES DONNÉES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− Cette FTSS a été préparée conformént aux exigences du SIMDUT; les données sont toutefois présentées sous 16 rubriques. Les renseignements donnés ci−haut se rapportent à ce produit suivant sa formule actuelle et s’appuient sur les données disponibles en ce moment. L’addition de diluant et autres additifs peut changer considérablement les risques associés à ce produit et sa composition. Etant donné que nous n’avons pas de contrôle sur les conditions d’utilisation, nous ne donnons aucune guarantie, explicite ou implicite et nous n’assumons aucune responsabilité concernant l’usage, quel qu’il soit, de ces renseignements. MATERIAL SAFETY DATA SHEET H101 01 00 =========================================================================== Section 1 -- PRODUCT AND COMPANY IDENTIFICATION --------------------------------------------------------------------------PRODUCT NUMBER HMIS CODES Health 2* H101 Flammability 4 Reactivity 0 PRODUCT NAME Hi-Heat Spray Paint, Hibachi Black MANUFACTURER’S NAME EMERGENCY TELEPHONE NO. SHERWIN-WILLIAMS CANADA, INC. (216) 566-2917 DUPLI-COLOR Products Group Vaughan, ON L4K 4T8 DATE OF PREPARATION INFORMATION TELEPHONE NO. 22-MAR-04 (905) 761-9185 =========================================================================== Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE --------------------------------------------------------------------------15 74-98-6 Propane ACGIH TLV 2500 ppm 760 mm OSHA PEL 1000 ppm 14 106-97-8 Butane ACGIH TLV 800 ppm 760 mm OSHA PEL 800 ppm 10 108-88-3 Toluene ACGIH TLV 50 ppm (skin) 22 mm OSHA PEL 100 ppm (skin) OSHA PEL 150 ppm (skin) STEL 2 100-41-4 Ethylbenzene ACGIH TLV 100 ppm 7.1 mm ACGIH TLV 125 ppm STEL OSHA PEL 100 ppm OSHA PEL 125 ppm STEL 11 1330-20-7 Xylene ACGIH TLV 100 ppm 5.9 mm ACGIH TLV 150 ppm STEL OSHA PEL 100 ppm OSHA PEL 150 ppm STEL 2 64742-94-5 Medium Aromatic Hydrocarbons ACGIH TLV Not Available 0.12 mm OSHA PEL Not Available 23 67-64-1 Acetone ACGIH TLV 500 ppm 180 mm ACGIH TLV 750 ppm STEL OSHA PEL 1000 ppm 6 14807-96-6 Talc ACGIH TLV 2 mg/m3 as Resp. Dust OSHA PEL 2 mg/m3 as Resp. Dust Continued on page 2 H101 page 2 =========================================================================== Section 3 -- HAZARDS IDENTIFICATION --------------------------------------------------------------------------ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. =========================================================================== Section 4 -- FIRST AID MEASURES --------------------------------------------------------------------------EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. =========================================================================== Section 5 -- FIRE FIGHTING MEASURES --------------------------------------------------------------------------FLASH POINT LEL UEL Propellant < 0 F 0.8 12.8 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Continued on page 3 H101 page 3 =========================================================================== Section 6 -- ACCIDENTAL RELEASE MEASURES --------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. =========================================================================== Section 7 -- HANDLING AND STORAGE --------------------------------------------------------------------------STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. =========================================================================== Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION --------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Continued on page 4 H101 page 4 =========================================================================== Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES --------------------------------------------------------------------------PRODUCT WEIGHT 6.56 lb/gal 785 g/l SPECIFIC GRAVITY 0.79 BOILING POINT <0 - 415 F <-18 - 212 C MELTING POINT Not Available VOLATILE VOLUME 90 % EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. VOLATILE ORGANIC COMPOUNDS (VOC Theoretical) Volatile Weight 55.71 % Less Water and Federally Exempt Solvents =========================================================================== Section 10 -- STABILITY AND REACTIVITY --------------------------------------------------------------------------STABILITY -- Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur =========================================================================== Section 11 -- TOXICOLOGICAL INFORMATION --------------------------------------------------------------------------CHRONIC HEALTH HAZARDS Ethylbenzene is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high ethylbenzene concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower concentrations. There is no evidence that ethylbenzene causes cancer in humans. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, cardiovascular and reproductive systems. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. --------------------------------------------------------------------------TOXICOLOGY DATA Continued on page 5 H101 page 5 =========================================================================== CAS No. Ingredient Name --------------------------------------------------------------------------74-98-6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106-97-8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 108-88-3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 100-41-4 Ethylbenzene LC50 RAT 4HR Not Available LD50 RAT 3500 mg/kg 1330-20-7 Xylene LC50 RAT 4HR 5000 ppm LD50 RAT 4300 mg/kg 64742-94-5 Medium Aromatic Hydrocarbons LC50 RAT 4HR Not Available LD50 RAT Not Available 67-64-1 Acetone LC50 RAT 4HR Not Available LD50 RAT 5800 mg/kg 14807-96-6 Talc LC50 RAT 4HR Not Available LD50 RAT Not Available =========================================================================== Section 12 -- ECOLOGICAL INFORMATION --------------------------------------------------------------------------ECOTOXICOLOGICAL INFORMATION No data available. =========================================================================== Section 13 -- DISPOSAL CONSIDERATIONS --------------------------------------------------------------------------WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. =========================================================================== Section 14 -- TRANSPORT INFORMATION --------------------------------------------------------------------------No data available. =========================================================================== Section 15 -- REGULATORY INFORMATION --------------------------------------------------------------------------SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION Continued on page 6 H101 page 6 =========================================================================== CAS No. CHEMICAL/COMPOUND % by WT % Element --------------------------------------------------------------------------108-88-3 Toluene 10 100-41-4 Ethylbenzene 2 1330-20-7 Xylene 11 Manganese Compound 5 0.9 TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. =========================================================================== Section 16 -- OTHER INFORMATION --------------------------------------------------------------------------This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. MATERIAL SAFETY DATA SHEET 1712 01 00 =========================================================================== Section 1 −− PRODUCT AND COMPANY IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT NUMBER HMIS CODES Health 2* 1712 Flammability 3 Reactivity 0 PRODUCT NAME KRYLON* Industrial TOUGH COAT* I.D. Fluorescent Paint, Fluorescent Red MANUFACTURER’S NAME EMERGENCY TELEPHONE NO. THE SHERWIN−WILLIAMS COMPANY (216) 566−2917 Diversified Brands Cleveland, OH 44115 DATE OF PREPARATION INFORMATION TELEPHONE NO. 04−MAY−07 (800) 247−3266 =========================================================================== Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 14 74−98−6 Propane ACGIH TLV 2500 ppm 760 mm OSHA PEL 1000 ppm 6 106−97−8 Butane ACGIH TLV 800 ppm 760 mm OSHA PEL 800 ppm 9 110−54−3 Hexane ACGIH TLV 50 ppm 127 mm OSHA PEL 50 ppm 4 107−83−5 Isohexane Isomers ACGIH TLV Not Available 211 mm OSHA PEL Not Available 1 96−14−0 3−Methylpentane ACGIH TLV 500 ppm 211 mm OSHA PEL Not Available 1 79−29−8 2,3−Dimethylbutane ACGIH TLV Not Available 230 mm OSHA PEL Not Available 7 64742−89−8 V. M. & P. Naphtha ACGIH TLV 300 ppm 12 mm OSHA PEL 300 ppm OSHA PEL 400 ppm STEL 2 108−88−3 Toluene ACGIH TLV 20 ppm 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 9 67−64−1 Acetone ACGIH TLV 500 ppm 180 mm ACGIH TLV 750 ppm STEL OSHA PEL 1000 ppm 21 14808−60−7 Quartz ACGIH TLV 0.05 mg/m3 as Resp. Dust OSHA PEL 0.1 mg/m3 as Resp. Dust Continued on page 2 1712 page 2 =========================================================================== 8 7727−43−7 Barium Sulfate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction =========================================================================== Section 3 −− HAZARDS IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. =========================================================================== Section 4 −− FIRST AID MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re−use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. =========================================================================== Section 5 −− FIRE FIGHTING MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− FLASH POINT LEL UEL Propellant < 0 F 0.9 12.8 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. Continued on page 3 1712 page 3 =========================================================================== SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self−contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build−up and possible autoignition or explosion when exposed to extreme heat. =========================================================================== Section 6 −− ACCIDENTAL RELEASE MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. =========================================================================== Section 7 −− HANDLING AND STORAGE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated − Do not smoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. =========================================================================== Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. Continued on page 4 1712 page 4 =========================================================================== PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. =========================================================================== Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT WEIGHT 7.54 lb/gal 903 g/l SPECIFIC GRAVITY 0.91 BOILING POINT <0 − 325 F <−18 − 162 C MELTING POINT Not Available VOLATILE VOLUME 79 % EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 7.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical − As Packaged) Volatile Weight 47.18% Less Water and Federally Exempt Solvents =========================================================================== Section 10 −− STABILITY AND REACTIVITY −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STABILITY −− Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur =========================================================================== Section 11 −− TOXICOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− CHRONIC HEALTH HAZARDS Crystalline Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. Prolonged and repeated exposure to Hexane may cause damage to nerve tissue of the arms and legs (peripheral neuropathy), resulting in muscular weakness and loss of sensation. This effect may be increased by the presence of Methyl Ethyl Ketone. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, cardiovascular and reproductive systems. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− TOXICOLOGY DATA Continued on page 5 1712 page 5 =========================================================================== CAS No. Ingredient Name −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 74−98−6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106−97−8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 110−54−3 Hexane LC50 RAT 4HR Not Available LD50 RAT 28700 mg/kg 107−83−5 Isohexane Isomers LC50 RAT 4HR Not Available LD50 RAT Not Available 96−14−0 3−Methylpentane LC50 RAT 4HR Not Available LD50 RAT Not Available 79−29−8 2,3−Dimethylbutane LC50 RAT 4HR Not Available LD50 RAT Not Available 64742−89−8 V. M. & P. Naphtha LC50 RAT 4HR Not Available LD50 RAT Not Available 108−88−3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 67−64−1 Acetone LC50 RAT 4HR Not Available LD50 RAT 5800 mg/kg 14808−60−7 Quartz LC50 RAT 4HR Not Available LD50 RAT Not Available 7727−43−7 Barium Sulfate LC50 RAT 4HR Not Available LD50 RAT Not Available =========================================================================== Section 12 −− ECOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ECOTOXICOLOGICAL INFORMATION No data available. =========================================================================== Section 13 −− DISPOSAL CONSIDERATIONS −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Continued on page 6 1712 page 6 =========================================================================== Section 14 −− TRANSPORT INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− US Ground (DOT) May be classed as Consumer Commodity, ORM−D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as Consumer Commodity, ORM−D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2, LIMITED QUANTITY, EmS F−D, S−U =========================================================================== Section 15 −− REGULATORY INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 110−54−3 Hexane 9 108−88−3 Toluene 2 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. =========================================================================== Section 16 −− OTHER INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. MATERIAL SAFETY DATA SHEET 49211 02 00 Section 1 -- PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER DATE OF PREPARATION HMIS CODES Health 49211 06-SEP-07 Flammability Reactivity PRODUCT NAME KRYLON® RUST TOUGH® Rust Preventive Enamel (aerosol), Sun Yellow 2* 3 0 MANUFACTURER'S NAME SHERWIN-WILLIAMS CANADA INC. KRYLON Products Group Vaughan, ON L4K 4T8 TELEPHONE NUMBERS and WEBSITES Product Information (800) 832-2541 Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency for Chemical Emergency ONLY (spill, leak, (800) 424-9300 fire, exposure, or accident) % by WT 14 7 5 11 0.5 3 Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS CAS No. INGREDIENT UNITS VAPOR PRESSURE 74-98-6 Propane ACGIH TLV 2500 ppm 760 mm OSHA PEL 1000 ppm 106-97-8 Butane ACGIH TLV 800 ppm 760 mm OSHA PEL 800 ppm 64742-89-8 V. M. & P. Naphtha ACGIH TLV 300 ppm 12 mm OSHA PEL 300 ppm OSHA PEL 400 ppm STEL 108-88-3 Toluene ACGIH TLV 20 ppm 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 100-41-4 Ethylbenzene ACGIH TLV 100 ppm 7.1 mm ACGIH TLV 125 ppm STEL OSHA PEL 100 ppm OSHA PEL 125 ppm STEL 1330-20-7 Xylene ACGIH TLV 100 ppm 5.9 mm ACGIH TLV 150 ppm STEL OSHA PEL 100 ppm OSHA PEL 150 ppm STEL Continued on page 2 49211 page 2 34 5 2 67-64-1 108-10-1 13463-67-7 Acetone ACGIH TLV 500 ACGIH TLV 750 OSHA PEL 1000 Methyl Isobutyl Ketone ACGIH TLV 50 ACGIH TLV 75 OSHA PEL 50 OSHA PEL 75 Titanium Dioxide ACGIH TLV 10 OSHA PEL 10 OSHA PEL 5 ppm ppm STEL ppm 180 mm ppm ppm STEL ppm ppm STEL 16 mm mg/m3 as Dust mg/m3 Total Dust mg/m3 Respirable Fraction Section 3 -- HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Section 4 -- FIRST AID MEASURES EYES: SKIN: INHALATION: INGESTION: Flush eyes with large amounts of water for 15 minutes. Get medical attention. Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. If affected, remove from exposure. Restore breathing. Keep warm and quiet. Do not induce vomiting. Get medical attention immediately. Section 5 -- FIRE FIGHTING MEASURES FLASH POINT LEL UEL Propellant < 0 F 0.9 12.8 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam Continued on page 3 49211 page 3 UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 -- ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Section 7 -- HANDLING AND STORAGE STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. Continued on page 4 49211 page 4 Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 6.44 lb/gal 771 g/l SPECIFIC GRAVITY 0.78 BOILING POINT <0 - 325 F <-18 - 162 C MELTING POINT Not Available VOLATILE VOLUME 87 % EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 7.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) Volatile Weight 46.19% Less Water and Federally Exempt Solvents Continued on page 5 49211 page 5 Section 10 -- STABILITY AND REACTIVITY STABILITY -- Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Section 11 -- TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Ethylbenzene is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high ethylbenzene concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower concentrations. There is no evidence that ethylbenzene causes cancer in humans. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, cardiovascular and reproductive systems. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. TOXICOLOGY DATA Continued on page 6 49211 CAS No. 74-98-6 106-97-8 64742-89-8 108-88-3 100-41-4 1330-20-7 67-64-1 108-10-1 13463-67-7 page 6 Ingredient Name Propane LC50 RAT LD50 RAT Butane LC50 RAT LD50 RAT V. M. & P. Naphtha LC50 RAT LD50 RAT Toluene LC50 RAT LD50 RAT Ethylbenzene LC50 RAT LD50 RAT Xylene LC50 RAT LD50 RAT Acetone LC50 RAT LD50 RAT Methyl Isobutyl Ketone LC50 RAT LD50 RAT Titanium Dioxide LC50 RAT LD50 RAT 4HR Not Available Not Available 4HR Not Available Not Available 4HR Not Available Not Available 4HR 4HR 4HR 4000 5000 ppm mg/kg Not Available 3500 mg/kg 5000 4300 ppm mg/kg 4HR Not Available 5800 mg/kg 4HR Not Available 2080 mg/kg 4HR Not Available Not Available Section 12 -- ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Section 13 -- DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Continued on page 7 49211 page 7 Section 14 -- TRANSPORT INFORMATION US Ground (DOT) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2, LIMITED QUANTITY, EmS F-D, S-U Section 15 -- REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. 108-88-3 100-41-4 1330-20-7 108-10-1 CHEMICAL/COMPOUND Toluene Ethylbenzene Xylene Methyl Isobutyl Ketone % by WT 11 0.4 3 5 % Element TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Section 16 -- OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. MATERIAL SAFETY DATA SHEET 1715 01 00 Section 1 -- PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER DATE OF PREPARATION HMIS CODES Health 2* 1715 22-DEC-07 Flammability 3 Reactivity 0 PRODUCT NAME KRYLON® Industrial TOUGH COAT™ I.D. Fluorescent Paint, Fluorescent Green MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY Diversified Brands Cleveland, OH 44115 TELEPHONE NUMBERS and WEBSITES Product Information (800) 247-3266 Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency for Chemical Emergency ONLY (spill, leak, (800) 424-9300 fire, exposure, or accident) % by WT 14 6 8 4 1 1 7 Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS CAS No. INGREDIENT UNITS VAPOR PRESSURE 74-98-6 Propane ACGIH TLV 2500 ppm 760 mm OSHA PEL 1000 ppm 106-97-8 Butane ACGIH TLV 800 ppm 760 mm OSHA PEL 800 ppm 110-54-3 Hexane ACGIH TLV 50 ppm 127 mm OSHA PEL 50 ppm 107-83-5 Isohexane Isomers ACGIH TLV Not Available 211 mm OSHA PEL Not Available 96-14-0 3-Methylpentane ACGIH TLV 500 ppm 211 mm OSHA PEL Not Available 79-29-8 2,3-Dimethylbutane ACGIH TLV Not Available 230 mm OSHA PEL Not Available 64742-89-8 V. M. & P. Naphtha ACGIH TLV 300 ppm 12 mm OSHA PEL 300 ppm OSHA PEL 400 ppm STEL Continued on page 2 1715 3 page 2 108-88-3 9 21 8 67-64-1 14808-60-7 7727-43-7 Toluene ACGIH TLV OSHA PEL OSHA PEL Acetone ACGIH TLV ACGIH TLV OSHA PEL Quartz ACGIH TLV OSHA PEL Barium Sulfate ACGIH TLV OSHA PEL OSHA PEL 20 100 150 ppm ppm (Skin) ppm (Skin) STEL 500 750 1000 ppm ppm STEL ppm 0.05 0.1 mg/m3 as Resp. Dust mg/m3 as Resp. Dust 10 10 5 22 mm 180 mm mg/m3 as Dust mg/m3 Total Dust mg/m3 Respirable Fraction Section 3 -- HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, cardiovascular and reproductive systems. SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Section 4 -- FIRST AID MEASURES EYES: SKIN: INHALATION: INGESTION: Flush eyes with large amounts of water for 15 minutes. Get medical attention. Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. If affected, remove from exposure. Restore breathing. Keep warm and quiet. Do not induce vomiting. Get medical attention immediately. Continued on page 3 1715 page 3 Section 5 -- FIRE FIGHTING MEASURES FLASH POINT LEL UEL Propellant < 0 F 0.9 12.8 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 -- ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Section 7 -- HANDLING AND STORAGE STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Continued on page 4 1715 page 4 VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 7.56 lb/gal 905 g/l SPECIFIC GRAVITY 0.91 BOILING POINT <0 - 325 F <-18 - 162 C MELTING POINT Not Available VOLATILE VOLUME 79 % EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 7.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) Volatile Weight 47.01% Less Water and Federally Exempt Solvents Section 10 -- STABILITY AND REACTIVITY STABILITY -- Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Continued on page 5 1715 page 5 Section 11 -- TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Prolonged and repeated exposure to Hexane may cause damage to nerve tissue of the arms and legs (peripheral neuropathy), resulting in muscular weakness and loss of sensation. This effect may be increased by the presence of Methyl Ethyl Ketone. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Crystalline Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. TOXICOLOGY DATA CAS No. Ingredient Name 74-98-6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106-97-8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 110-54-3 Hexane LC50 RAT 4HR Not Available LD50 RAT 28700 mg/kg 107-83-5 Isohexane Isomers LC50 RAT 4HR Not Available LD50 RAT Not Available 96-14-0 3-Methylpentane LC50 RAT 4HR Not Available LD50 RAT Not Available 79-29-8 2,3-Dimethylbutane LC50 RAT 4HR Not Available LD50 RAT Not Available 64742-89-8 V. M. & P. Naphtha LC50 RAT 4HR Not Available LD50 RAT Not Available 108-88-3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 67-64-1 Acetone LC50 RAT 4HR Not Available LD50 RAT 5800 mg/kg 14808-60-7 Quartz LC50 RAT 4HR Not Available LD50 RAT Not Available 7727-43-7 Barium Sulfate LC50 RAT 4HR Not Available LD50 RAT Not Available Continued on page 6 1715 page 6 Section 12 -- ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Section 13 -- DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Section 14 -- TRANSPORT INFORMATION US Ground (DOT) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U Section 15 -- REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND 110-54-3 Hexane 108-88-3 Toluene % by WT 8 3 % Element CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Section 16 -- OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. Continued on page 7 1715 page 7 The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. MATERIAL SAFETY DATA SHEET C20758 01 00 =========================================================================== Section 1 -- PRODUCT AND COMPANY IDENTIFICATION --------------------------------------------------------------------------PRODUCT NUMBER HMIS CODES Health 2 C20758 Flammability 4 Reactivity 0 PRODUCT NAME 15100 OSHA BLUE MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. THE SHERWIN-WILLIAMS COMPANY (216) 566-2917 101 Prospect Avenue N.W. Cleveland, OH 44115 DATE OF PREPARATION INFORMATION TELEPHONE NO. 02-JUN-05 (216) 566-2902 =========================================================================== Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE --------------------------------------------------------------------------14 74-98-6 Propane ACGIH TLV 2500 ppm 760 mm OSHA PEL 1000 ppm 13 106-97-8 Butane ACGIH TLV 800 ppm 760 mm OSHA PEL 800 ppm 22 108-88-3 Toluene ACGIH TLV 50 ppm (Skin) 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 33 67-64-1 Acetone ACGIH TLV 500 ppm 180 mm ACGIH TLV 750 ppm STEL OSHA PEL 1000 ppm 2 763-69-9 Ethyl 3-Ethoxypropionate ACGIH TLV Not Available 1.11 mm OSHA PEL Not Available 1 1332-58-7 Kaolin ACGIH TLV 2 mg/m3 as Resp. Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction 1 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction =========================================================================== Section 3 -- HAZARDS IDENTIFICATION --------------------------------------------------------------------------ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. Continued on page 2 C20758 page 2 =========================================================================== EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. =========================================================================== Section 4 -- FIRST AID MEASURES --------------------------------------------------------------------------EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. =========================================================================== Section 5 -- FIRE FIGHTING MEASURES --------------------------------------------------------------------------FLASH POINT LEL UEL Propellant < 0 F 1.0 12.8 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. =========================================================================== Section 6 -- ACCIDENTAL RELEASE MEASURES --------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Continued on page 3 C20758 page 3 =========================================================================== Section 7 -- HANDLING AND STORAGE --------------------------------------------------------------------------STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. =========================================================================== Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION --------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Continued on page 4 C20758 page 4 =========================================================================== Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES --------------------------------------------------------------------------PRODUCT WEIGHT 6.29 lb/gal 753 g/l SPECIFIC GRAVITY 0.76 BOILING POINT <0 - 342 F <-18 - 172 C MELTING POINT Not Available VOLATILE VOLUME 91 % EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 7.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical) Volatile Weight 51.59 % Less Water and Federally Exempt Solvents =========================================================================== Section 10 -- STABILITY AND REACTIVITY --------------------------------------------------------------------------STABILITY -- Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur =========================================================================== Section 11 -- TOXICOLOGICAL INFORMATION --------------------------------------------------------------------------CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, cardiovascular and reproductive systems. Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung cancer, however, such exposure levels are not attainable in the workplace. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. --------------------------------------------------------------------------TOXICOLOGY DATA Continued on page 5 C20758 page 5 =========================================================================== CAS No. Ingredient Name --------------------------------------------------------------------------74-98-6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106-97-8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 108-88-3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 67-64-1 Acetone LC50 RAT 4HR Not Available LD50 RAT 5800 mg/kg 763-69-9 Ethyl 3-Ethoxypropionate LC50 RAT 4HR Not Available LD50 RAT 5000 mg/kg 1332-58-7 Kaolin LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available =========================================================================== Section 12 -- ECOLOGICAL INFORMATION --------------------------------------------------------------------------ECOTOXICOLOGICAL INFORMATION No data available. =========================================================================== Section 13 -- DISPOSAL CONSIDERATIONS --------------------------------------------------------------------------WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. =========================================================================== Section 14 -- TRANSPORT INFORMATION --------------------------------------------------------------------------No data available. =========================================================================== Section 15 -- REGULATORY INFORMATION --------------------------------------------------------------------------SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element --------------------------------------------------------------------------108-88-3 Toluene 22 Continued on page 6 C20758 page 6 =========================================================================== CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. =========================================================================== Section 16 -- OTHER INFORMATION --------------------------------------------------------------------------This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. MATERIAL SAFETY DATA SHEET 368 01 00 =========================================================================== Section 1 −− PRODUCT AND COMPANY IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT NUMBER HMIS CODES Health 2 368 Flammability 4 Reactivity 0 PRODUCT NAME KRYLON* WEEKEND* Spray Paint, Almond MANUFACTURER’S NAME EMERGENCY TELEPHONE NO. THE SHERWIN−WILLIAMS COMPANY (216) 566−2917 Diversified Brands Cleveland, OH 44115 DATE OF PREPARATION INFORMATION TELEPHONE NO. 01−JUL−06 (800) 247−3266 =========================================================================== Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 14 74−98−6 Propane ACGIH TLV 2500 ppm 760 mm OSHA PEL 1000 ppm 13 106−97−8 Butane ACGIH TLV 800 ppm 760 mm OSHA PEL 800 ppm 19 108−88−3 Toluene ACGIH TLV 50 ppm (Skin) 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 39 67−64−1 Acetone ACGIH TLV 500 ppm 180 mm ACGIH TLV 750 ppm STEL OSHA PEL 1000 ppm 2 763−69−9 Ethyl 3−Ethoxypropionate ACGIH TLV Not Available 1.11 mm OSHA PEL Not Available 2 13463−67−7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction =========================================================================== Section 3 −− HAZARDS IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Continued on page 2 368 page 2 =========================================================================== SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. =========================================================================== Section 4 −− FIRST AID MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re−use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. =========================================================================== Section 5 −− FIRE FIGHTING MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− FLASH POINT LEL UEL Propellant < 0 F 1.0 12.8 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self−contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build−up and possible autoignition or explosion when exposed to extreme heat. =========================================================================== Section 6 −− ACCIDENTAL RELEASE MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. =========================================================================== Section 7 −− HANDLING AND STORAGE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STORAGE CATEGORY Not Available Continued on page 3 368 page 3 =========================================================================== PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated − Do not smoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. =========================================================================== Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Continued on page 4 368 page 4 =========================================================================== Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT WEIGHT 6.22 lb/gal 745 g/l SPECIFIC GRAVITY 0.75 BOILING POINT <0 − 342 F <−18 − 172 C MELTING POINT Not Available VOLATILE VOLUME 93 % EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 7.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical − As Packaged) Volatile Weight 48.54% Less Water and Federally Exempt Solvents =========================================================================== Section 10 −− STABILITY AND REACTIVITY −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STABILITY −− Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur =========================================================================== Section 11 −− TOXICOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, cardiovascular and reproductive systems. Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung cancer, however, such exposure levels are not attainable in the workplace. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− TOXICOLOGY DATA Continued on page 5 368 page 5 =========================================================================== CAS No. Ingredient Name −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 74−98−6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106−97−8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 108−88−3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 67−64−1 Acetone LC50 RAT 4HR Not Available LD50 RAT 5800 mg/kg 763−69−9 Ethyl 3−Ethoxypropionate LC50 RAT 4HR Not Available LD50 RAT 5000 mg/kg 13463−67−7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available =========================================================================== Section 12 −− ECOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ECOTOXICOLOGICAL INFORMATION No data available. =========================================================================== Section 13 −− DISPOSAL CONSIDERATIONS −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. =========================================================================== Section 14 −− TRANSPORT INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− No data available. =========================================================================== Section 15 −− REGULATORY INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 108−88−3 Toluene 19 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. Continued on page 6 368 page 6 =========================================================================== TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. =========================================================================== Section 16 −− OTHER INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. MATERIAL SAFETY DATA SHEET M107 01 00 =========================================================================== Section 1 −− PRODUCT AND COMPANY IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT NUMBER HMIS CODES Health 2* M107 Flammability 4 Reactivity 1 PRODUCT NAME Spray Paint, Silver MANUFACTURER’S NAME EMERGENCY TELEPHONE NO. CONSUMER BRANDS CANADA (216) 566−2917 200 Confederation Parkway Vaughan, ON L4K 4T8 DATE OF PREPARATION INFORMATION TELEPHONE NO. 08−OCT−05 (905) 761−8866 =========================================================================== Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 16 74−98−6 Propane ACGIH TLV 2500 ppm 760 mm OSHA PEL 1000 ppm 16 106−97−8 Butane ACGIH TLV 800 ppm 760 mm OSHA PEL 800 ppm 1 64742−88−7 Mineral Spirits ACGIH TLV 100 ppm 2 mm OSHA PEL 100 ppm 34 108−88−3 Toluene ACGIH TLV 50 ppm (Skin) 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 0.4 100−41−4 Ethylbenzene ACGIH TLV 100 ppm 7.1 mm ACGIH TLV 125 ppm STEL OSHA PEL 100 ppm OSHA PEL 125 ppm STEL 2 1330−20−7 Xylene ACGIH TLV 100 ppm 5.9 mm ACGIH TLV 150 ppm STEL OSHA PEL 100 ppm OSHA PEL 150 ppm STEL 10 67−64−1 Acetone ACGIH TLV 500 ppm 180 mm ACGIH TLV 750 ppm STEL OSHA PEL 1000 ppm Continued on page 2 M107 page 2 =========================================================================== Section 3 −− HAZARDS IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. =========================================================================== Section 4 −− FIRST AID MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re−use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. =========================================================================== Section 5 −− FIRE FIGHTING MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− FLASH POINT LEL UEL Propellant < 0 F 1.0 12.8 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self−contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build−up and possible autoignition or explosion when exposed to extreme heat. Continued on page 3 M107 page 3 =========================================================================== Section 6 −− ACCIDENTAL RELEASE MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. =========================================================================== Section 7 −− HANDLING AND STORAGE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated − Do not smoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. =========================================================================== Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1−800−424−LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. Continued on page 4 M107 page 4 =========================================================================== PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. =========================================================================== Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT WEIGHT 6.23 lb/gal 746 g/l SPECIFIC GRAVITY 0.75 BOILING POINT <0 − 395 F <−18 − 201 C MELTING POINT Not Available VOLATILE VOLUME 87 % EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. VOLATILE ORGANIC COMPOUNDS (VOC Theoretical) Volatile Weight 70.31 % Less Water and Federally Exempt Solvents =========================================================================== Section 10 −− STABILITY AND REACTIVITY −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STABILITY −− Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur =========================================================================== Section 11 −− TOXICOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− CHRONIC HEALTH HAZARDS Ethylbenzene is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high ethylbenzene concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower concentrations. There is no evidence that ethylbenzene causes cancer in humans. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, cardiovascular and reproductive systems. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− TOXICOLOGY DATA Continued on page 5 M107 page 5 =========================================================================== CAS No. Ingredient Name −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 74−98−6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106−97−8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 64742−88−7 Mineral Spirits LC50 RAT 4HR Not Available LD50 RAT Not Available 108−88−3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 100−41−4 Ethylbenzene LC50 RAT 4HR Not Available LD50 RAT 3500 mg/kg 1330−20−7 Xylene LC50 RAT 4HR 5000 ppm LD50 RAT 4300 mg/kg 67−64−1 Acetone LC50 RAT 4HR Not Available LD50 RAT 5800 mg/kg =========================================================================== Section 12 −− ECOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ECOTOXICOLOGICAL INFORMATION No data available. =========================================================================== Section 13 −− DISPOSAL CONSIDERATIONS −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. =========================================================================== Section 14 −− TRANSPORT INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− No data available. =========================================================================== Section 15 −− REGULATORY INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 108−88−3 Toluene 34 100−41−4 Ethylbenzene 0.3 1330−20−7 Xylene 2 Continued on page 6 M107 page 6 =========================================================================== TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. =========================================================================== Section 16 −− OTHER INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. MATERIAL SAFETY DATA SHEET 3202 01 00 =========================================================================== Section 1 −− PRODUCT AND COMPANY IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT NUMBER HMIS CODES Health 2 3202 Flammability 4 Reactivity 0 PRODUCT NAME KRYLON* Appliance Epoxy Paint, Almond MANUFACTURER’S NAME EMERGENCY TELEPHONE NO. THE SHERWIN−WILLIAMS COMPANY (216) 566−2917 KRYLON Products Group Cleveland, OH 44115 DATE OF PREPARATION INFORMATION TELEPHONE NO. 24−JAN−06 (800) 832−2541 =========================================================================== Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 14 74−98−6 Propane ACGIH TLV 2500 ppm 760 mm OSHA PEL 1000 ppm 13 106−97−8 Butane ACGIH TLV 800 ppm 760 mm OSHA PEL 800 ppm 19 108−88−3 Toluene ACGIH TLV 50 ppm (Skin) 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 23 67−64−1 Acetone ACGIH TLV 500 ppm 180 mm ACGIH TLV 750 ppm STEL OSHA PEL 1000 ppm 12 123−86−4 n−Butyl Acetate ACGIH TLV 150 ppm 10 mm ACGIH TLV 200 ppm STEL OSHA PEL 150 ppm OSHA PEL 200 ppm STEL 8 13463−67−7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction =========================================================================== Section 3 −− HAZARDS IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. Continued on page 2 3202 page 2 =========================================================================== EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. =========================================================================== Section 4 −− FIRST AID MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re−use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. =========================================================================== Section 5 −− FIRE FIGHTING MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− FLASH POINT LEL UEL Propellant < 0 F 1.0 12.8 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self−contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build−up and possible autoignition or explosion when exposed to extreme heat. =========================================================================== Section 6 −− ACCIDENTAL RELEASE MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Continued on page 3 3202 page 3 =========================================================================== Section 7 −− HANDLING AND STORAGE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated − Do not smoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. =========================================================================== Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1−800−424−LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. Continued on page 4 3202 page 4 =========================================================================== OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. =========================================================================== Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT WEIGHT 6.54 lb/gal 783 g/l SPECIFIC GRAVITY 0.79 BOILING POINT <0 − 264 F <−18 − 128 C MELTING POINT Not Available VOLATILE VOLUME 90 % EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 7.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical) Volatile Weight 57.89 % Less Water and Federally Exempt Solvents =========================================================================== Section 10 −− STABILITY AND REACTIVITY −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STABILITY −− Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur =========================================================================== Section 11 −− TOXICOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, blood forming, cardiovascular and reproductive systems. Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung cancer, however, such exposure levels are not attainable in the workplace. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− TOXICOLOGY DATA Continued on page 5 3202 page 5 =========================================================================== CAS No. Ingredient Name −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 74−98−6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106−97−8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 108−88−3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 67−64−1 Acetone LC50 RAT 4HR Not Available LD50 RAT 5800 mg/kg 123−86−4 n−Butyl Acetate LC50 RAT 4HR 2000 ppm LD50 RAT 13100 mg/kg 13463−67−7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available =========================================================================== Section 12 −− ECOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ECOTOXICOLOGICAL INFORMATION No data available. =========================================================================== Section 13 −− DISPOSAL CONSIDERATIONS −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. =========================================================================== Section 14 −− TRANSPORT INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− No data available. =========================================================================== Section 15 −− REGULATORY INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 108−88−3 Toluene 19 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. Continued on page 6 3202 page 6 =========================================================================== TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. =========================================================================== Section 16 −− OTHER INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. FICHE SIGNALÉTIQUE SANTÉ-SÉCURITÉ 460505 02 00 Section 1 -- IDENTIFICATION DU PRODUIT ET DE LA SOCIÉTÉ NUMÉRO DU PRODUIT DATE DE PRÉPARATION Santé 460505 29-SEP-07 Inflammabilité Réactivité NOM DU PRODUIT COLOUR ALL Spray Paint, Gloss Black 2* 3 0 NOM DU FABRICANT SHERWIN-WILLIAMS CANADA, INC. DUPLI-COLOR Products Group Vaughan, ON L4K 4T8 NUMÉROS DE TÉLÉPHONES ET SITES WEB Renseignements sur le produit (905) 761-9185 Renseignements réglementaires (216) 566-2902 www.paintdocs.com Urgence médicale (216) 566-2917 Urgence de transport pour une urgence chimique SEULEMENT (800) 424-9300 (déversement, fuite, incendie, exposition ou accident) Section 2 -- COMPOSITION/INFORMATION SUR LES INGRÉDIENTS CAS No. INGREDIENT UNITÉS PRESSION VAPEUR 74-98-6 Propane ACGIH TLV 2500 ppm 760 mm OSHA PEL 1000 ppm 106-97-8 Butane ACGIH TLV 800 ppm 760 mm OSHA PEL 800 ppm 108-88-3 Toluène ACGIH TLV 20 ppm 22 mm OSHA PEL 100 ppm (Peau) OSHA PEL 150 ppm (Peau) STEL 67-64-1 Acetone ACGIH TLV 500 ppm 180 mm ACGIH TLV 750 ppm STEL OSHA PEL 1000 ppm 763-69-9 3-Éthoxypropionate d'éthyle ACGIH TLV Pas Disponible 1.11 mm OSHA PEL Pas Disponible 1333-86-4 Noir de Carbone ACGIH TLV 3.5 mg/m3 OSHA PEL 3.5 mg/m3 % EN POIDS 14 13 21 40 3 0.4 Suite à la page 2 460505 page 2 Section 3 -- IDENTIFICATION DES RISQUES SOURCES D'EXPOSITION L'exposition peut se produire par l'INHALATION des vapeurs ou du brouillard de pulvérisation. La PEAU et les YEUX peuvent entrer en contact avec le produit, les vapeurs ou le brouillard de pulvérisation. EFFET DE LA SUREXPOSITION YEUX: Irritation des YEUX. PEAU: L'exposition prolongée ou répétée risque de provoquer l'irritation des peau. INHALATION: Irritation des voies respiratoires supérieures. Peut causer la dépression nerveuse. Une sur-exposition excessive à ce produit peut entrainer la perte de conscience, voire même la mort. L'exposition, excessive et prolongée, aux solvants de la 2 section peut entrainer de mauvaises conséquences aux systèmes du fois, urinaire, cardio-vasculaire et reproductif. SYMPTÔMES DE SUREXPOSITION Les maux de tête, l'étourdissement, la nausée et la perte de coordination des mouvements sont tous des symptômes d'exposition excessive aux vapeurs ou à la brume de pulvérisation. La rougeur et les démangeaisons ou la sensation de brûlure peuvent indiquer une exposition excessive des yeux ou de la peau. ETAT DE SANTÉ AGGRAVÉ PAR EXPOSITION En général, aucun exposition n'est reconnue. CANCÉROGÉNICITÉ Voir la Section 11. Section 4 -- PREMIERS SOINS YEUX: PEAU: INHALATION: INGESTION: Rincer les yeux à grande eau pendant 15 minutes. Aller voir un médecin. Laver à fond les parties affectées avec de l'eau et du savon. Enlever les habits contaminés et les laver avant de les porter de nouveau. Si une personne en est affectée, l'aider à sortir des lieux. Rétablir la respiration. Aider la personne á rester calme et au chaud. N'incitez pas la personne á vomir. Aller voir un médecin immédiatement. Section 5 -- MESURES EN CAS D'INCENDIE POINT D'ÉCLAIR LIE LSE Propellant < 0 F 1.0 12.8 MOYENS D'EXTINCTION Dioxyde de carbone, produit chimique sec, mousse Suite à la page 3 460505 page 3 DANGERS D'INCENDIE OU D'EXPLOSION EXCEPTIONNELS Les contenants peuvent exploser s'ils sont exposés à une très grande chaleur. L'application aux surfaces chaudes exige qu'on prenne des précautions spéciales. En cas d'urgence, une exposition excessive aux produits de décomposition peut constituer un danger pour la santé. Les symptômes peuvent ne pas se manifester immédiatement. Voir le médecin. MESURES PARTICULIÉRES DI PROTECTION CONTRE L'INCENDIE On doit utiliser l'équipement de protection complète y compris un appareil de respiration auto-alimenté. La pulvérisation avec de l'eau peut être inefficace. Si on se sert de l'eau, l'ajutage pour brume est préférable. On peut se servir de l'eau pour refroidir les contenants fermés afin d'empêcher l'augmentation de la pression et la possibilité d'une combustion automatique ou l'explosion en cas d'exposition à une chaleur extrêmement grande. Section 6 -- MARCHE Á SUIVRE EN CAS DE DÉVERSEMENT ACCIDENTEL MESURES À PRENDRE LORSQUE DES MATIÉRES SONT RENVERSÉES OU ÉVAPORÉES Enlever toute source de combustion. Bien aérer. Nettoyer avec un absorbant non réactif. Section 7 -- MANUTENTION ET ENTREPOSAGE CATÉGORIE D'ENTREPOSAGE Pas Disponible PRÉCAUTIONS Á PRENDRE LORS DE L'ENTREPOSAGE DI LA MANIPULATION Tenir loin de la chaleur, étincelles et de flamme nue. Les vapeurs peuvent s'accumuler rapidement et s'enflammer et causer une explosion. Aucours de l'utilisation de ce produit jusqu'à la disparution de toutes les vapeurs: Garder l'endroit bien aéré. Eviter de fumer. Eteindre toute flamme, veilleuse d'appareils et réchauds. Couper la courant des poêles, des outils et appareils éléctriques ainsi que de toute autre source de combustion. Suivre les procédures approuvées pour attacher solidement et pour permettre l'écoulement de l'éléctricité dans le sol. Contenu sous pression. Ne pas ouvrir, incinérer ou exposer à des températures au dessus de 120 Fahrenheit. La chaleur des rayons du soleil, des radiateurs, des réchauds, de l'eau chaude, ou provenant de toute autre source, peut provoquer l'explosion du contenant. Ne pas avaler. Garder hors de la portée des enfants. Suite à la page 4 460505 page 4 Section 8 -- CONTRÔLE DE L'EXPOSITION ET PROTECTION INDIVIDUELLE PRÉCAUTIONS À PRENDRE AUCOURS DE L'UTILISATION N'utiliser ce produit que dans un endroit bien aéré. Éviter tout contact avec la peau et les yeux. Eviter d'aspirer les vapeurs et la brume de vaporisation. Bien se laver les mains après l'utilisation. Ce produit peut contenir des matières classifiées comme petites particules irritantes, telles que le dioxyde de titane ou le carbonate de calcium (voir la liste ACGIH TLV, la préface et l'annexe D). On peut avoir ces particules dans des proportions dangereuses uniquement au moment du grattement et de l'éraflement de la couche séchée. Si la liste dans la 2e section ne fait aucune mention spécifique de la présence des poussières de particules, les limites applicables sont: pour ACGIH TLV 10 mg/m3 (concentration totale de poussière), 3 mg/m3 (fractionée de respiratoire). VENTILATION Un système permettant l'échappement local des produits est préférable. Si l'exposition aux produits de la 2e section est maintenue au-dessous des limites d'exposition applicables, le système d'échappement global est acceptable. PROTECTION DES VOIES RESPIRATOIRES Si on ne peut pas maintenir, par simple ventilation, le niveau auquel on s'expos personnellement en dessous des limites applicables, porter un respirateur à filtre de vapeur organique et particules approprié et bien ajusté approuvé par NIOSH/MSHA pour se protéger contre les produits de la 2e section. Pendant que vous frottez ou poncez la couche sechée, porter un respirateur à filtre de poussière et de brume, approuvé par NIOSH/MSHA pour vous protéger contre la poussière qui peut éventuellement se dégager de ce produit, de la peinture ou de l'abrasif. GANTS PROTECTEURS Aucun n'est exigé pour l'application normale des produits aérosol, lorsqu'on n'attend qu'un minimum de contact avec la peau. Pour un contact prolongé et repété, portez des gants resistants aux produits chimiques. LUNETTES DE SÉCURITÉ Porter les lunetttes de sécurité avec des protecteurs latéraux non perforés. AUTRES PRÉCAUTIONS L'utilisation inappropriée de ce produit en le concentrant et en l'aspirant intentionnellement peut être dangereuse ou peut même causer la mort. Section 9 -- PROPRIÉTÉS PHYSIQUES ET CHIMIQUES POIDS DU PRODUIT DENSITÉ COURBE D'ÉBULLITION POINT DE FUSION VOLUME VOLATIL VITESSE D'ÉVAPORATION DENSITÉ DE LA VAPEUR SOLUBILITÉ DANS L'EAU pH Suite à la page 5 6.08 lb/gal 728 g/l 0.73 <0 - 342 F <-18 - 172 C P.D. 94 % Plus vite que l'Éther Plus lourd que l'Air P.D. 7.0 460505 page 5 COMPOSÉS ORGANIQUES VOLATILS (Théorique) Volatil Poids 51.59% Moins d'eau et de solvants exemptés Section 10 -- STABILITÉ ET RÉACTIVITÉ STABILITÉ -- Stable CONDITIONS À ÉVITER Aucun connu. INCOMPATIBILITÉ Aucun connu. PRODUITS DANGEREUX DÛ À LA DÉCOMPOSITION Par combustion: Dioxyde de carbone, monoxyde de carbone POLYMÉRISATION DANGEREUSE Ne Peut Pas De Produire Section 11 -- DONNÉES TOXICOLOGIQUES RISQUES DE SANTÉ CHRONIQUES Il existe des rapports de recherches qui associent des troubles permanentes du cerveau et du système nerveux à l'exposition excessive, répétée et prolongée aux solvants. Le carbone noir est classifié par l'IARC comme étant possiblement carcinogène aux humains (groupe 2B) basé sur des données animales expérimentales. Cependant, dans les humains, l'évidence de carcinogénéité est insuffisante. INFORMATION TOXICOLOGIQUE CAS No. Ingredient 74-98-6 Propane LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible 106-97-8 Butane LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible 108-88-3 Toluène LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 67-64-1 Acetone LC50 RAT 4HR Pas Disponible LD50 RAT 5800 mg/kg 763-69-9 3-Éthoxypropionate d'éthyle LC50 RAT 4HR Pas Disponible LD50 RAT 5000 mg/kg 1333-86-4 Noir de Carbone LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible Section 12 -- DONNÉES ÉCOLOGIQUES Aucunes donnies disponibles. Suite à la page 6 460505 page 6 Section 13 -- DONNÉES SUR L'ÉLIMINATION DU PRODUIT MÉTHODE D'ÉLIMINATION DES DÉCHETS Les déchets provenant de ce produit peuvent être dangereux, selon la définition donnée dans la "U.S. Resource Conservation and Recovery Act" (RCRA) 40 CFR 261. On doit soumettre les déchets au test de combustion afin de déterminer les numéros de l'EPA applicables. Ne pas incinérer. Eliminer la pression dans le contenant. Se débarrasser du contenu confermément aux lois anti-pollution fédérales, provinciales et municipales. Section 14 -- DONNÉES SUR LE TRANSPORT US Ground (DOT) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2, LIMITED QUANTITY, EmS F-D, S-U Section 15 -- DONNÉES SUR LA RÉGLEMENTATION SARA 313 (40 CFR 372.65C) AVIS DE FOURNISSEUR CAS No. CHIMIQUE/COMPOSÉ 108-88-3 Toluène % by WT 21 % Element DONNÉES SUR LA TSCA Tous les produits chimiques dans ce produit sont énumérés, ou exemptez de l'énumération, sur le inventaire de TSCA. Section 16 -- AUTRES DONNÉES Cette FTSS a été préparée conformént aux exigences du SIMDUT; les données sont toutefois présentées sous 16 rubriques. Les renseignements donnés ci-haut se rapportent à ce produit suivant sa formule actuelle et s'appuient sur les données disponibles en ce moment. L'addition de diluant et autres additifs peut changer considérablement les risques associés à ce produit et sa composition. Etant donné que nous n'avons pas de contrôle sur les conditions d'utilisation, nous ne donnons aucune guarantie, explicite ou implicite et nous n'assumons aucune responsabilité concernant l'usage, quel qu'il soit, de ces renseignements. MATERIAL SAFETY DATA SHEET 368 01 00 =========================================================================== Section 1 −− PRODUCT AND COMPANY IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT NUMBER HMIS CODES Health 2 368 Flammability 4 Reactivity 0 PRODUCT NAME KRYLON* WEEKEND* Spray Paint, Almond MANUFACTURER’S NAME EMERGENCY TELEPHONE NO. THE SHERWIN−WILLIAMS COMPANY (216) 566−2917 Diversified Brands Cleveland, OH 44115 DATE OF PREPARATION INFORMATION TELEPHONE NO. 01−JUL−06 (800) 247−3266 =========================================================================== Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 14 74−98−6 Propane ACGIH TLV 2500 ppm 760 mm OSHA PEL 1000 ppm 13 106−97−8 Butane ACGIH TLV 800 ppm 760 mm OSHA PEL 800 ppm 19 108−88−3 Toluene ACGIH TLV 50 ppm (Skin) 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 39 67−64−1 Acetone ACGIH TLV 500 ppm 180 mm ACGIH TLV 750 ppm STEL OSHA PEL 1000 ppm 2 763−69−9 Ethyl 3−Ethoxypropionate ACGIH TLV Not Available 1.11 mm OSHA PEL Not Available 2 13463−67−7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction =========================================================================== Section 3 −− HAZARDS IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Continued on page 2 368 page 2 =========================================================================== SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. =========================================================================== Section 4 −− FIRST AID MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re−use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. =========================================================================== Section 5 −− FIRE FIGHTING MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− FLASH POINT LEL UEL Propellant < 0 F 1.0 12.8 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self−contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build−up and possible autoignition or explosion when exposed to extreme heat. =========================================================================== Section 6 −− ACCIDENTAL RELEASE MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. =========================================================================== Section 7 −− HANDLING AND STORAGE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STORAGE CATEGORY Not Available Continued on page 3 368 page 3 =========================================================================== PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated − Do not smoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. =========================================================================== Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Continued on page 4 368 page 4 =========================================================================== Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT WEIGHT 6.22 lb/gal 745 g/l SPECIFIC GRAVITY 0.75 BOILING POINT <0 − 342 F <−18 − 172 C MELTING POINT Not Available VOLATILE VOLUME 93 % EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 7.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical − As Packaged) Volatile Weight 48.54% Less Water and Federally Exempt Solvents =========================================================================== Section 10 −− STABILITY AND REACTIVITY −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STABILITY −− Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur =========================================================================== Section 11 −− TOXICOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, cardiovascular and reproductive systems. Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung cancer, however, such exposure levels are not attainable in the workplace. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− TOXICOLOGY DATA Continued on page 5 368 page 5 =========================================================================== CAS No. Ingredient Name −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 74−98−6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106−97−8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 108−88−3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 67−64−1 Acetone LC50 RAT 4HR Not Available LD50 RAT 5800 mg/kg 763−69−9 Ethyl 3−Ethoxypropionate LC50 RAT 4HR Not Available LD50 RAT 5000 mg/kg 13463−67−7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available =========================================================================== Section 12 −− ECOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ECOTOXICOLOGICAL INFORMATION No data available. =========================================================================== Section 13 −− DISPOSAL CONSIDERATIONS −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. =========================================================================== Section 14 −− TRANSPORT INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− No data available. =========================================================================== Section 15 −− REGULATORY INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 108−88−3 Toluene 19 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. Continued on page 6 368 page 6 =========================================================================== TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. =========================================================================== Section 16 −− OTHER INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. MATERIAL SAFETY DATA SHEET 368 01 00 =========================================================================== Section 1 −− PRODUCT AND COMPANY IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT NUMBER HMIS CODES Health 2 368 Flammability 4 Reactivity 0 PRODUCT NAME KRYLON* WEEKEND* Spray Paint, Almond MANUFACTURER’S NAME EMERGENCY TELEPHONE NO. THE SHERWIN−WILLIAMS COMPANY (216) 566−2917 Diversified Brands Cleveland, OH 44115 DATE OF PREPARATION INFORMATION TELEPHONE NO. 01−JUL−06 (800) 247−3266 =========================================================================== Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 14 74−98−6 Propane ACGIH TLV 2500 ppm 760 mm OSHA PEL 1000 ppm 13 106−97−8 Butane ACGIH TLV 800 ppm 760 mm OSHA PEL 800 ppm 19 108−88−3 Toluene ACGIH TLV 50 ppm (Skin) 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 39 67−64−1 Acetone ACGIH TLV 500 ppm 180 mm ACGIH TLV 750 ppm STEL OSHA PEL 1000 ppm 2 763−69−9 Ethyl 3−Ethoxypropionate ACGIH TLV Not Available 1.11 mm OSHA PEL Not Available 2 13463−67−7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction =========================================================================== Section 3 −− HAZARDS IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Continued on page 2 368 page 2 =========================================================================== SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. =========================================================================== Section 4 −− FIRST AID MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re−use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. =========================================================================== Section 5 −− FIRE FIGHTING MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− FLASH POINT LEL UEL Propellant < 0 F 1.0 12.8 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self−contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build−up and possible autoignition or explosion when exposed to extreme heat. =========================================================================== Section 6 −− ACCIDENTAL RELEASE MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. =========================================================================== Section 7 −− HANDLING AND STORAGE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STORAGE CATEGORY Not Available Continued on page 3 368 page 3 =========================================================================== PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated − Do not smoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. =========================================================================== Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Continued on page 4 368 page 4 =========================================================================== Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT WEIGHT 6.22 lb/gal 745 g/l SPECIFIC GRAVITY 0.75 BOILING POINT <0 − 342 F <−18 − 172 C MELTING POINT Not Available VOLATILE VOLUME 93 % EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 7.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical − As Packaged) Volatile Weight 48.54% Less Water and Federally Exempt Solvents =========================================================================== Section 10 −− STABILITY AND REACTIVITY −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STABILITY −− Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur =========================================================================== Section 11 −− TOXICOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, cardiovascular and reproductive systems. Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung cancer, however, such exposure levels are not attainable in the workplace. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− TOXICOLOGY DATA Continued on page 5 368 page 5 =========================================================================== CAS No. Ingredient Name −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 74−98−6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106−97−8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 108−88−3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 67−64−1 Acetone LC50 RAT 4HR Not Available LD50 RAT 5800 mg/kg 763−69−9 Ethyl 3−Ethoxypropionate LC50 RAT 4HR Not Available LD50 RAT 5000 mg/kg 13463−67−7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available =========================================================================== Section 12 −− ECOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ECOTOXICOLOGICAL INFORMATION No data available. =========================================================================== Section 13 −− DISPOSAL CONSIDERATIONS −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. =========================================================================== Section 14 −− TRANSPORT INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− No data available. =========================================================================== Section 15 −− REGULATORY INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 108−88−3 Toluene 19 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. Continued on page 6 368 page 6 =========================================================================== TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. =========================================================================== Section 16 −− OTHER INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. MATERIAL SAFETY DATA SHEET 368 01 00 =========================================================================== Section 1 −− PRODUCT AND COMPANY IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT NUMBER HMIS CODES Health 2 368 Flammability 4 Reactivity 0 PRODUCT NAME KRYLON* WEEKEND* Spray Paint, Almond MANUFACTURER’S NAME EMERGENCY TELEPHONE NO. THE SHERWIN−WILLIAMS COMPANY (216) 566−2917 Diversified Brands Cleveland, OH 44115 DATE OF PREPARATION INFORMATION TELEPHONE NO. 01−JUL−06 (800) 247−3266 =========================================================================== Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 14 74−98−6 Propane ACGIH TLV 2500 ppm 760 mm OSHA PEL 1000 ppm 13 106−97−8 Butane ACGIH TLV 800 ppm 760 mm OSHA PEL 800 ppm 19 108−88−3 Toluene ACGIH TLV 50 ppm (Skin) 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 39 67−64−1 Acetone ACGIH TLV 500 ppm 180 mm ACGIH TLV 750 ppm STEL OSHA PEL 1000 ppm 2 763−69−9 Ethyl 3−Ethoxypropionate ACGIH TLV Not Available 1.11 mm OSHA PEL Not Available 2 13463−67−7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction =========================================================================== Section 3 −− HAZARDS IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Continued on page 2 368 page 2 =========================================================================== SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. =========================================================================== Section 4 −− FIRST AID MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re−use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. =========================================================================== Section 5 −− FIRE FIGHTING MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− FLASH POINT LEL UEL Propellant < 0 F 1.0 12.8 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self−contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build−up and possible autoignition or explosion when exposed to extreme heat. =========================================================================== Section 6 −− ACCIDENTAL RELEASE MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. =========================================================================== Section 7 −− HANDLING AND STORAGE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STORAGE CATEGORY Not Available Continued on page 3 368 page 3 =========================================================================== PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated − Do not smoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. =========================================================================== Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Continued on page 4 368 page 4 =========================================================================== Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT WEIGHT 6.22 lb/gal 745 g/l SPECIFIC GRAVITY 0.75 BOILING POINT <0 − 342 F <−18 − 172 C MELTING POINT Not Available VOLATILE VOLUME 93 % EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 7.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical − As Packaged) Volatile Weight 48.54% Less Water and Federally Exempt Solvents =========================================================================== Section 10 −− STABILITY AND REACTIVITY −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STABILITY −− Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur =========================================================================== Section 11 −− TOXICOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, cardiovascular and reproductive systems. Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung cancer, however, such exposure levels are not attainable in the workplace. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− TOXICOLOGY DATA Continued on page 5 368 page 5 =========================================================================== CAS No. Ingredient Name −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 74−98−6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106−97−8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 108−88−3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 67−64−1 Acetone LC50 RAT 4HR Not Available LD50 RAT 5800 mg/kg 763−69−9 Ethyl 3−Ethoxypropionate LC50 RAT 4HR Not Available LD50 RAT 5000 mg/kg 13463−67−7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available =========================================================================== Section 12 −− ECOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ECOTOXICOLOGICAL INFORMATION No data available. =========================================================================== Section 13 −− DISPOSAL CONSIDERATIONS −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. =========================================================================== Section 14 −− TRANSPORT INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− No data available. =========================================================================== Section 15 −− REGULATORY INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 108−88−3 Toluene 19 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. Continued on page 6 368 page 6 =========================================================================== TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. =========================================================================== Section 16 −− OTHER INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. MATERIAL SAFETY DATA SHEET CW01024 01 00 =========================================================================== Section 1 −− PRODUCT AND COMPANY IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT NUMBER HMIS CODES Health 2* CW01024 Flammability 4 Reactivity 0 PRODUCT NAME COLORWORKS* from KRYLON* Interior/Exterior Spray Paint, Flat Black MANUFACTURER’S NAME EMERGENCY TELEPHONE NO. THE SHERWIN−WILLIAMS COMPANY (216) 566−2917 KRYLON Products Group Cleveland, OH 44115 DATE OF PREPARATION INFORMATION TELEPHONE NO. 30−JUL−05 (800) 832−2541 =========================================================================== Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 18 74−98−6 Propane ACGIH TLV 2500 ppm 760 mm OSHA PEL 1000 ppm 17 106−97−8 Butane ACGIH TLV 800 ppm 760 mm OSHA PEL 800 ppm 3 64742−89−8 Lt. Aliphatic Hydrocarbon Solvent ACGIH TLV 100 ppm 53 mm OSHA PEL 100 ppm 5 64742−89−8 V. M. & P. Naphtha ACGIH TLV 300 ppm 12 mm OSHA PEL 300 ppm OSHA PEL 400 ppm STEL 11 108−88−3 Toluene ACGIH TLV 50 ppm (Skin) 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 0.1 100−41−4 Ethylbenzene ACGIH TLV 100 ppm 7.1 mm ACGIH TLV 125 ppm STEL OSHA PEL 100 ppm OSHA PEL 125 ppm STEL 1 111−76−2 2−Butoxyethanol ACGIH TLV 20 ppm 0.88 mm OSHA PEL 25 ppm 23 67−64−1 Acetone ACGIH TLV 500 ppm 180 mm ACGIH TLV 750 ppm STEL OSHA PEL 1000 ppm 11 14807−96−6 Talc ACGIH TLV 2 mg/m3 as Resp. Dust OSHA PEL 2 mg/m3 as Resp. Dust Continued on page 2 CW01024 page 2 =========================================================================== 0.4 1333−86−4 Carbon Black ACGIH TLV 3.5 mg/m3 OSHA PEL 3.5 mg/m3 =========================================================================== Section 3 −− HAZARDS IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. =========================================================================== Section 4 −− FIRST AID MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re−use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. =========================================================================== Section 5 −− FIRE FIGHTING MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− FLASH POINT LEL UEL Propellant < 0 F 0.9 12.8 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. Continued on page 3 CW01024 page 3 =========================================================================== SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self−contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build−up and possible autoignition or explosion when exposed to extreme heat. =========================================================================== Section 6 −− ACCIDENTAL RELEASE MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. =========================================================================== Section 7 −− HANDLING AND STORAGE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated − Do not smoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. =========================================================================== Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1−800−424−LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. Continued on page 4 CW01024 page 4 =========================================================================== RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. =========================================================================== Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT WEIGHT 6.22 lb/gal 745 g/l SPECIFIC GRAVITY 0.75 BOILING POINT <0 − 343 F <−18 − 172 C MELTING POINT Not Available VOLATILE VOLUME 90 % EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 7.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical) Volatile Weight 57.23 % Less Water and Federally Exempt Solvents =========================================================================== Section 10 −− STABILITY AND REACTIVITY −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STABILITY −− Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Continued on page 5 CW01024 page 5 =========================================================================== Section 11 −− TOXICOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− CHRONIC HEALTH HAZARDS Ethylbenzene is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high ethylbenzene concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower concentrations. There is no evidence that ethylbenzene causes cancer in humans. Carbon Black is classified by IARC as possibly carcinogenic to humans (group 2B) based on experimental animal data, however, there is insufficient evidence in humans for its carcinogenicity. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, blood forming, cardiovascular and reproductive systems. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− TOXICOLOGY DATA CAS No. Ingredient Name −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 74−98−6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106−97−8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 64742−89−8 Lt. Aliphatic Hydrocarbon Solvent LC50 RAT 4HR Not Available LD50 RAT Not Available 64742−89−8 V. M. & P. Naphtha LC50 RAT 4HR Not Available LD50 RAT Not Available 108−88−3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 100−41−4 Ethylbenzene LC50 RAT 4HR Not Available LD50 RAT 3500 mg/kg 111−76−2 2−Butoxyethanol LC50 RAT 4HR Not Available LD50 RAT 470 mg/kg 67−64−1 Acetone LC50 RAT 4HR Not Available LD50 RAT 5800 mg/kg 14807−96−6 Talc LC50 RAT 4HR Not Available LD50 RAT Not Available 1333−86−4 Carbon Black LC50 RAT 4HR Not Available LD50 RAT Not Available Continued on page 6 CW01024 page 6 =========================================================================== Section 12 −− ECOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ECOTOXICOLOGICAL INFORMATION No data available. =========================================================================== Section 13 −− DISPOSAL CONSIDERATIONS −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. =========================================================================== Section 14 −− TRANSPORT INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− No data available. =========================================================================== Section 15 −− REGULATORY INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 108−88−3 Toluene 11 100−41−4 Ethylbenzene 0.1 Glycol Ethers 1 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. =========================================================================== Section 16 −− OTHER INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. MATERIAL SAFETY DATA SHEET M103 03 00 Section 1 -- PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER DATE OF PREPARATION HMIS CODES Health M103 30-SEP-07 Flammability Reactivity PRODUCT NAME Spray Paint, Aluminum 2* 3 1 MANUFACTURER'S NAME SHERWIN-WILLIAMS CANADA, INC. 200 Confederation Pkwy Vaughan, ON L4K 4T8 TELEPHONE NUMBERS and WEBSITES Product Information (905) 761-9185 Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency for Chemical Emergency ONLY (spill, leak, (800) 424-9300 fire, exposure, or accident) % by WT 16 16 1 34 0.4 2 Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS CAS No. INGREDIENT UNITS VAPOR PRESSURE 74-98-6 Propane ACGIH TLV 2500 ppm 760 mm OSHA PEL 1000 ppm 106-97-8 Butane ACGIH TLV 800 ppm 760 mm OSHA PEL 800 ppm 64742-88-7 Mineral Spirits ACGIH TLV 100 ppm 2 mm OSHA PEL 100 ppm 108-88-3 Toluene ACGIH TLV 20 ppm 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 100-41-4 Ethylbenzene ACGIH TLV 100 ppm 7.1 mm ACGIH TLV 125 ppm STEL OSHA PEL 100 ppm OSHA PEL 125 ppm STEL 1330-20-7 Xylene ACGIH TLV 100 ppm 5.9 mm ACGIH TLV 150 ppm STEL OSHA PEL 100 ppm OSHA PEL 150 ppm STEL Continued on page 2 M103 10 page 2 67-64-1 Acetone ACGIH TLV ACGIH TLV OSHA PEL 500 750 1000 ppm ppm STEL ppm 180 mm Section 3 -- HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, cardiovascular and reproductive systems. SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Section 4 -- FIRST AID MEASURES EYES: SKIN: INHALATION: INGESTION: Flush eyes with large amounts of water for 15 minutes. Get medical attention. Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. If affected, remove from exposure. Restore breathing. Keep warm and quiet. Do not induce vomiting. Get medical attention immediately. Section 5 -- FIRE FIGHTING MEASURES FLASH POINT LEL UEL Propellant < 0 F 1.0 12.8 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. Continued on page 3 M103 page 3 SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 -- ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Section 7 -- HANDLING AND STORAGE STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. Continued on page 4 M103 page 4 RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 6.24 lb/gal 747 g/l SPECIFIC GRAVITY 0.75 BOILING POINT <0 - 395 F <-18 - 201 C MELTING POINT Not Available VOLATILE VOLUME 87 % EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 7.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) Volatile Weight 69.51% Less Water and Federally Exempt Solvents Section 10 -- STABILITY AND REACTIVITY STABILITY -- Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Continued on page 5 M103 page 5 Section 11 -- TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Ethylbenzene is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high ethylbenzene concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower concentrations. There is no evidence that ethylbenzene causes cancer in humans. TOXICOLOGY DATA CAS No. Ingredient Name 74-98-6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106-97-8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 64742-88-7 Mineral Spirits LC50 RAT 4HR Not Available LD50 RAT Not Available 108-88-3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 100-41-4 Ethylbenzene LC50 RAT 4HR Not Available LD50 RAT 3500 mg/kg 1330-20-7 Xylene LC50 RAT 4HR 5000 ppm LD50 RAT 4300 mg/kg 67-64-1 Acetone LC50 RAT 4HR Not Available LD50 RAT 5800 mg/kg Section 12 -- ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Section 13 -- DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Continued on page 6 M103 page 6 Section 14 -- TRANSPORT INFORMATION US Ground (DOT) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2, LIMITED QUANTITY, EmS F-D, S-U Section 15 -- REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND 108-88-3 Toluene 100-41-4 Ethylbenzene 1330-20-7 Xylene % by WT 34 0.3 2 % Element TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Section 16 -- OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. MATERIAL SAFETY DATA SHEET DSCC362 02 00 Section 1 -- PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER DATE OF PREPARATION HMIS CODES Health DSCC362 29-SEP-07 Flammability Reactivity PRODUCT NAME AUTO SPRAY® Paint, Bright White 2* 3 0 MANUFACTURER'S NAME THE SHERWIN-WILLIAMS CO. DUPLI-COLOR Products Group Cleveland, OH 44115 TELEPHONE NUMBERS and WEBSITES Product Information (800) 247-3270 www.duplicolor.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency for Chemical Emergency ONLY (spill, leak, (800) 424-9300 fire, exposure, or accident) % by WT 10 10 9 1 40 7 8 Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS CAS No. INGREDIENT UNITS VAPOR PRESSURE 74-98-6 Propane ACGIH TLV 2500 ppm 760 mm OSHA PEL 1000 ppm 106-97-8 Butane ACGIH TLV 800 ppm 760 mm OSHA PEL 800 ppm 108-88-3 Toluene ACGIH TLV 20 ppm 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 64-17-5 Ethanol ACGIH TLV 1000 ppm 44 mm OSHA PEL 1000 ppm 67-64-1 Acetone ACGIH TLV 500 ppm 180 mm ACGIH TLV 750 ppm STEL OSHA PEL 1000 ppm 78-93-3 Methyl Ethyl Ketone ACGIH TLV 200 ppm 70 mm ACGIH TLV 300 ppm STEL OSHA PEL 200 ppm OSHA PEL 300 ppm STEL 763-69-9 Ethyl 3-Ethoxypropionate ACGIH TLV Not Available 1.11 mm OSHA PEL Not Available Continued on page 2 DSCC362 4 page 2 13463-67-7 Titanium Dioxide ACGIH TLV OSHA PEL OSHA PEL 10 10 5 mg/m3 as Dust mg/m3 Total Dust mg/m3 Respirable Fraction Section 3 -- HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, cardiovascular and reproductive systems. SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Section 4 -- FIRST AID MEASURES EYES: SKIN: INHALATION: INGESTION: Flush eyes with large amounts of water for 15 minutes. Get medical attention. Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. If affected, remove from exposure. Restore breathing. Keep warm and quiet. Do not induce vomiting. Get medical attention immediately. Section 5 -- FIRE FIGHTING MEASURES FLASH POINT LEL UEL Propellant < 0 F 1.0 19.0 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. Continued on page 3 DSCC362 page 3 SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 -- ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Section 7 -- HANDLING AND STORAGE STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. Continued on page 4 DSCC362 page 4 PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 6.48 lb/gal 776 g/l SPECIFIC GRAVITY 0.78 BOILING POINT <0 - 342 F <-18 - 172 C MELTING POINT Not Available VOLATILE VOLUME 92 % EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) Volatile Weight 46.44% Less Water and Federally Exempt Solvents Section 10 -- STABILITY AND REACTIVITY STABILITY -- Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Section 11 -- TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Methyl Ethyl Ketone may increase the nervous system effects of other solvents. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." TOXICOLOGY DATA Continued on page 5 DSCC362 CAS No. 74-98-6 106-97-8 108-88-3 64-17-5 67-64-1 78-93-3 763-69-9 13463-67-7 page 5 Ingredient Name Propane LC50 RAT LD50 RAT Butane LC50 RAT LD50 RAT Toluene LC50 RAT LD50 RAT Ethanol LC50 RAT LD50 RAT Acetone LC50 RAT LD50 RAT Methyl Ethyl Ketone LC50 RAT LD50 RAT Ethyl 3-Ethoxypropionate LC50 RAT LD50 RAT Titanium Dioxide LC50 RAT LD50 RAT 4HR Not Available Not Available 4HR Not Available Not Available 4HR 4000 5000 ppm mg/kg 4HR Not Available 7060 mg/kg 4HR Not Available 5800 mg/kg 4HR Not Available 2740 mg/kg 4HR Not Available 5000 mg/kg 4HR Not Available Not Available Section 12 -- ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Section 13 -- DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Continued on page 6 DSCC362 page 6 Section 14 -- TRANSPORT INFORMATION US Ground (DOT) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2, LIMITED QUANTITY, EmS F-D, S-U Section 15 -- REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND 108-88-3 Toluene % by WT 9 % Element CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Section 16 -- OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. FICHE SIGNALÉTIQUE SANTÉ−SÉCURITÉ 00861 04 00 =========================================================================== Section 1 −− IDENTIFICATION DU PRODUIT ET DE LA SOCIÉTÉ −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− NUMÉRO DU PRODUIT Santé 2* 00861 Inflammabilité 3 Réactivité 0 NOM DU PRODUIT RUST TOUGH* Rust Preventive Primer, Quick Dry Gray Primer NOM DU FABRICANT NO. DE TÉLÉPHONE EN CAS D’URGENCE THE SHERWIN−WILLIAMS COMPANY (216) 566−2917 Diversified Brands Cleveland, OH 44115 DATE DE PRÉPARATION NO. DE TÉLÉPHONE ORDINAIRE 30−JUL−05 (800) 247−3266 =========================================================================== Section 2 −− COMPOSITION/INFORMATION SUR LES INGRÉDIENTS % EN POIDS CAS No. INGREDIENT UNITÉS PRESSION VAPEUR −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 3 100−41−4 Éthylbenzène ACGIH TLV 100 ppm 7.1 mm ACGIH TLV 125 ppm STEL OSHA PEL 100 ppm OSHA PEL 125 ppm STEL 19 1330−20−7 Xylène ACGIH TLV 100 ppm 5.9 mm ACGIH TLV 150 ppm STEL OSHA PEL 100 ppm OSHA PEL 150 ppm STEL 3 64742−95−6 Solvant Naphta Aliphatique Léger ACGIH TLV Pas Disponible 3.8 mm OSHA PEL Pas Disponible 3 108−67−8 1,3,5−Triméthylbenzène ACGIH TLV 25 ppm 2 mm OSHA PEL 25 ppm 5 95−63−6 1,2,4−Triméthylbenzène ACGIH TLV 25 ppm 2.03 mm OSHA PEL 25 ppm 10 14807−96−6 Talc ACGIH TLV 2 mg/m3 de resp. poussiére OSHA PEL 2 mg/m3 de resp. poussiére 10 471−34−1 Carbonate de Calcium ACGIH TLV 10 mg/m3 de poussiére OSHA PEL 15 mg/m3 total de polva OSHA PEL 5 mg/m3 fracción respirable 8 7727−43−7 Sulfate de Baryum ACGIH TLV 10 mg/m3 de poussiére OSHA PEL 10 mg/m3 total de polva OSHA PEL 5 mg/m3 fracción respirable 9 13463−67−7 Dioxyde de Titane ACGIH TLV 10 mg/m3 de poussiére OSHA PEL 10 mg/m3 total de polva OSHA PEL 5 mg/m3 fracción respirable Suite à la page 2 00861 page 2 =========================================================================== 0.6 1333−86−4 Noir de Carbone ACGIH TLV 3.5 mg/m3 OSHA PEL 3.5 mg/m3 −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 3.09 Baryum (Ba; total) =========================================================================== Section 3 −− IDENTIFICATION DES RISQUES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− SOURCES D’EXPOSITION L’exposition peut se produire par l’INHALATION des vapeurs ou du brouillard de pulvérisation. La PEAU et les YEUX peuvent entrer en contact avec le produit, les vapeurs ou le brouillard de pulvérisation. EFFET DE LA SUREXPOSITION YEUX: Irritation des YEUX. PEAU: L’exposition prolongée ou répétée risque de provoquer l’irritation des peau. INHALATION: Irritation des voies respiratoires supérieures. Peut causer la dépression nerveuse. Une sur−exposition excessive à ce produit peut entrainer la perte de conscience, voire même la mort. SYMPTÔMES DE SUREXPOSITION Les maux de tête, l’étourdissement, la nausée et la perte de coordination des mouvements sont tous des symptômes d’exposition excessive aux vapeurs ou à la brume de pulvérisation. La rougeur et les démangeaisons ou la sensation de brûlure peuvent indiquer une exposition excessive des yeux ou de la peau. ETAT DE SANTÉ AGGRAVÉ PAR EXPOSITION En général, aucun exposition n’est reconnue. CANCÉROGÉNICITÉ Voir la Section 11. =========================================================================== Section 4 −− PREMIERS SOINS −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− YEUX: Rincer les yeux à grande eau pendant 15 minutes. Aller voir un médecin. PEAU: Laver à fond les parties affectées avec de l’eau et du savon. Enlever les habits contaminés et les laver avant de les porter de nouveau. INHALATION: Si une personne en est affectée, l’aider à sortir des lieux. Rétablir la respiration. Aider la personne á rester calme et au chaud. INGESTION: N’incitez pas la personne á vomir. Aller voir un médecin immédiatement. =========================================================================== Section 5 −− MESURES EN CAS D’INCENDIE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− POINT D’ÉCLAIR LIE LSE 87 F PMCC 0.7 7.0 CLASSIFICATION D’INFLAMMABILITÉ ETIQUETTE ROUGE −− Inflammable, point critique en dessous de 38 C (100 degré F) MOYENS D’EXTINCTION Dioxyde de carbone, produit chimique sec, mousse Suite à la page 3 00861 page 3 =========================================================================== DANGERS D’INCENDIE OU D’EXPLOSION EXCEPTIONNELS Les contenants fermés peuvent exploser s’ils sont exposés à une très grande chaleur. L’application aux surfaces chaudes exige qu’on prenne des précautions spéciales. En cas d’urgence, une exposition excessive aux produits de décomposition peut constituer un danger pour la santé. Les symptômes peuvent ne pas se manifester immédiatement. Voir le médecin. MESURES PARTICULIÉRES DI PROTECTION CONTRE L’INCENDIE On doit utiliser l’équipement de protection complète y compris un appareil de respiration auto−alimenté. La pulvérisation avec de l’eau peut être inefficace. Si on se sert de l’eau, l’ajutage pour brume est préférable. On peut se servir de l’eau pour refroidir les contenants fermés afin d’empêcher l’augmentation de la pression et la possibilité d’une combustion automatique ou l’explosion en cas d’exposition à une chaleur extrêmement grande. =========================================================================== Section 6 −− MARCHE Á SUIVRE EN CAS DE DÉVERSEMENT ACCIDENTEL −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− MESURES À PRENDRE LORSQUE DES MATIÉRES SONT RENVERSÉES OU ÉVAPORÉES Enlever toute source de combustion. Bien aérer. Nettoyer avec un absorbant non réactif. =========================================================================== Section 7 −− MANUTENTION ET ENTREPOSAGE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− CATÉGORIE D’ENTREPOSAGE U.S. DOL Storage Class IC PRÉCAUTIONS Á PRENDRE LORS DE L’ENTREPOSAGE DI LA MANIPULATION CONTENU INFLAMMABLE. Tenir loin de la chaleur, des étincelles et de la flamme nue. Aucours de l’utilisation de ce produit jusqu’à la disparution de toutes les vapeurs: Garder l’endroit bien aéré. Eviter de fumer. Eteindre toute flamme, veilleuse d’appareils et réchauds. Couper la courant des poêles, des outils et appareils éléctriques ainsi que de toute autre source de combustion. Suivre les procédures approuvées pour attacher solidement et pour permettre l’écoulement de l’éléctricité dans le sol. Garder le contenant fermé lorsqu’il n’est pas en usage. Transvaser seulement dans des contenants approuvés et ayant des étiquettes complètes et convenables. Ne pas avaler. Garder hors de la portée des enfants. Suite à la page 4 00861 page 4 =========================================================================== Section 8 −− CONTRÔLE DE L’EXPOSITION ET PROTECTION INDIVIDUELLE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRÉCAUTIONS À PRENDRE AUCOURS DE L’UTILISATION N’utiliser ce produit que dans un endroit bien aéré. Éviter tout contact avec la peau et les yeux. Eviter d’aspirer les vapeurs et la brume de vaporisation. Bien se laver les mains après l’utilisation. Ce produit peut contenir des matières classifiées comme petites particules irritantes, telles que le dioxyde de titane ou le carbonate de calcium (voir la liste ACGIH TLV, la préface et l’annexe D). On peut avoir ces particules dans des proportions dangereuses uniquement au moment du grattement et de l’éraflement de la couche séchée. Si la liste dans la 2e section ne fait aucune mention spécifique de la présence des poussières de particules, les limites applicables sont: pour ACGIH TLV 10 mg/m3 (concentration totale de poussière), 3 mg/m3 (fractionée de respiratoire). VENTILATION Un système permettant l’échappement local des produits est préférable. Si l’exposition aux produits de la 2e section est maintenue au−dessous des limites d’exposition applicables, le système d’échappement global est acceptable. PROTECTION DES VOIES RESPIRATOIRES Si on ne peut pas maintenir, par simple ventilation, le niveau auquel on s’expos personnellement en dessous des limites applicables, porter un respirateur à filtre de vapeur organique et particules approprié et bien ajusté approuvé par NIOSH/MSHA pour se protéger contre les produits de la 2e section. Aucours du ponçage, du nettoyage à la brosse métallique, de même qu’en frottant, en brulant, en brasant ou en soudant la couche sèche, il est recommandé de porter un respirateur à filtre de particules, approuvé par NIOSH/MSHA afin de se protéger contre les produits non volatils de la 2e section. GANTS PROTECTEURS Porter les gants recommandés par le fournisseur de gants pour se protéger contre les produits de la 2e section. LUNETTES DE SÉCURITÉ Porter les lunetttes de sécurité avec des protecteurs latéraux non perforés. AUTRES PRÉCAUTIONS L’utilisation inappropriée de ce produit en le concentrant et en l’aspirant intentionnellement peut être dangereuse ou peut même causer la mort. Suite à la page 5 00861 page 5 =========================================================================== Section 9 −− PROPRIÉTÉS PHYSIQUES ET CHIMIQUES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− POIDS DU PRODUIT 11.44 lb/gal 1370 g/l DENSITÉ 1.38 COURBE D’ÉBULLITION 277 − 360 F 136 − 182 C POINT DE FUSION P.D. VOLUME VOLATIL 57 % VITESSE D’ÉVAPORATION Plus lent que l’Éther DENSITÉ DE LA VAPEUR Plus lourd que l’Air SOLUBILITÉ DANS L’EAU P.D. COMPOSÉS ORGANIQUES VOLATILS (Théorique) 4.12 lb/gal 494 g/l Moins d’eau et de Solvants Exemptés 4.12 lb/gal 494 g/l Émis COV =========================================================================== Section 10 −− STABILITÉ ET RÉACTIVITÉ −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STABILITÉ −− Stable CONDITIONS À ÉVITER Aucun connu. INCOMPATIBILITÉ Aucun connu. PRODUITS DANGEREUX DÛ À LA DÉCOMPOSITION Par combustion: Dioxyde de carbone, monoxyde de carbone, oxydes des métaux de la 2e section POLYMÉRISATION DANGEREUSE Ne Peut Pas De Produire =========================================================================== Section 11 −− DONNÉES TOXICOLOGIQUES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− RISQUES DE SANTÉ CHRONIQUES À partir de données expérimentales provenant d’études suffisantes mendées chez les animaux et d’études insuffisantes menées chez humains, l’éthylbenzène est classifié par le CIRC comme étant possiblement carcinogène chez les humains (group 2B). On a constaté une augmentation de certains types de cancer, y compris des tumeurs du rein chez les rats et des tumeurs du poumon et du foie chez les souris, lorsque ces animaux ont été exposés à l’inhalation de concentrations élevées d’éthylbenzène à long terme. Toutefois, ces effets n’ont pas étéobservés chez les animaux exposés à de plus faibles concentrations d’éthylbenzène. Jusqu’à présent il n’y a aucune preuve suggérant que l’éthylbenzène provoque le cancer chez les humains. Le carbone noir est classifié par l’IARC comme étant possiblement carcinogène aux humains (groupe 2B) basé sur des données animales expérimentales. Cependant, dans les humains, l’évidence de carcinogénéité est insuffisante. L’exposition, excessive et prolongée, aux solvants de la 2 section peut entrainer demauvaises conséquences aux systèmesdu fois,urinaire etreproductif. Les rats exposés à la poussière de dioxyde de titanium à une concentrations de 250mg/m3 ont développé le cancer des poumons. Toutefois, on ne peut pas atteindre une telle concentration en milieu du travail. Il existe des rapports de recherches qui associent des troubles permanentes du cerveau et du système nerveux à l’exposition excessive, répétée et prolongée aux solvants. Suite à la page 6 00861 page 6 =========================================================================== INFORMATION TOXICOLOGIQUE CAS No. Ingredient −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 100−41−4 Éthylbenzène LC50 RAT 4HR Pas Disponible LD50 RAT 3500 mg/kg 1330−20−7 Xylène LC50 RAT 4HR 5000 ppm LD50 RAT 4300 mg/kg 64742−95−6 Solvant Naphta Aliphatique Léger LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible 108−67−8 1,3,5−Triméthylbenzène LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible 95−63−6 1,2,4−Triméthylbenzène LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible 14807−96−6 Talc LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible 471−34−1 Carbonate de Calcium LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible 7727−43−7 Sulfate de Baryum LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible 13463−67−7 Dioxyde de Titane LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible 1333−86−4 Noir de Carbone LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible =========================================================================== Section 12 −− DONNÉES ÉCOLOGIQUES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− Aucunes donnies disponibles. =========================================================================== Section 13 −− DONNÉES SUR L’ÉLIMINATION DU PRODUIT −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− MÉTHODE D’ÉLIMINATION DES DÉCHETS Les déchets provenant de ce produit peuvent être dangereux, selon la définition donnée dans la "U.S. Resource Conservation and Recovery Act" (RCRA) 40 CFR 261. On doit soumettre les déchets au test de combustion et d’extraction pour déterminer les numéros de l’EPA applicables. Incinérer dans un endroit approuvé. Ne pas incinérer les contenants fermés. Respecter les lois anti−pollution fédérales, provinciales et municipales. =========================================================================== Section 14 −− DONNÉES SUR LE TRANSPORT −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− Aucunes donnies disponibles. Suite à la page 7 00861 page 7 =========================================================================== Section 15 −− DONNÉES SUR LA RÉGLEMENTATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− SARA 313 (40 CFR 372.65C) AVIS DE FOURNISSEUR CAS No. CHIMIQUE/COMPOSÉ % by WT % Element −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 100−41−4 Éthylbenzène 3 1330−20−7 Xylène 19 95−63−6 1,2,4−Triméthylbenzène 5 Barium Compound 5 3.0 CALIFORNIA PROPOSITION 65 AVERTISSEMENT: Ce produit des matières chimiques connue de l’État de la Californie qui peut causer le cancer, dommages à la naissance ou autre malformation congénitale. DONNÉES SUR LA TSCA Tous les produits chimiques dans ce produit sont énumérés, ou exemptez de l’énumération, sur le inventaire de TSCA. =========================================================================== Section 16 −− AUTRES DONNÉES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− Cette FTSS a été préparée conformént aux exigences du SIMDUT; les données sont toutefois présentées sous 16 rubriques. Les renseignements donnés ci−haut se rapportent à ce produit suivant sa formule actuelle et s’appuient sur les données disponibles en ce moment. L’addition de diluant et autres additifs peut changer considérablement les risques associés à ce produit et sa composition. Etant donné que nous n’avons pas de contrôle sur les conditions d’utilisation, nous ne donnons aucune guarantie, explicite ou implicite et nous n’assumons aucune responsabilité concernant l’usage, quel qu’il soit, de ces renseignements. FICHE SIGNALÉTIQUE SANTÉ−SÉCURITÉ 49200 02 00 =========================================================================== Section 1 −− IDENTIFICATION DU PRODUIT ET DE LA SOCIÉTÉ −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− NUMÉRO DU PRODUIT Santé 2* 49200 Inflammabilité 3 Réactivité 0 NOM DU PRODUIT KRYLON* TOUGH COAT* Acrylic Aerosol Paint, Gloss White NOM DU FABRICANT NO. DE TÉLÉPHONE EN CAS D’URGENCE THE SHERWIN−WILLIAMS COMPANY (216) 566−2917 KRYLON Products Group Cleveland, OH 44115 DATE DE PRÉPARATION NO. DE TÉLÉPHONE ORDINAIRE 24−FEB−07 (800) 832−2541 =========================================================================== Section 2 −− COMPOSITION/INFORMATION SUR LES INGRÉDIENTS % EN POIDS CAS No. INGREDIENT UNITÉS PRESSION VAPEUR −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 15 74−98−6 Propane ACGIH TLV 2500 ppm 760 mm OSHA PEL 1000 ppm 7 106−97−8 Butane ACGIH TLV 800 ppm 760 mm OSHA PEL 800 ppm 4 64742−89−8 Solvant Naphta Aliphatique Léger ACGIH TLV 300 ppm 12 mm OSHA PEL 300 ppm OSHA PEL 400 ppm STEL 10 108−88−3 Toluène ACGIH TLV 50 ppm (Peau) 22 mm OSHA PEL 100 ppm (Peau) OSHA PEL 150 ppm (Peau) STEL 0.4 100−41−4 Éthylbenzène ACGIH TLV 100 ppm 7.1 mm ACGIH TLV 125 ppm STEL OSHA PEL 100 ppm OSHA PEL 125 ppm STEL 2 1330−20−7 Xylène ACGIH TLV 100 ppm 5.9 mm ACGIH TLV 150 ppm STEL OSHA PEL 100 ppm OSHA PEL 150 ppm STEL 32 67−64−1 Acetone ACGIH TLV 500 ppm 180 mm ACGIH TLV 750 ppm STEL OSHA PEL 1000 ppm 4 108−10−1 Méthylisobutylcétone ACGIH TLV 50 ppm 16 mm ACGIH TLV 75 ppm STEL OSHA PEL 50 ppm OSHA PEL 75 ppm STEL Suite à la page 2 49200 page 2 =========================================================================== 7 13463−67−7 Dioxyde de Titane ACGIH TLV 10 mg/m3 de poussiére OSHA PEL 10 mg/m3 total de polva OSHA PEL 5 mg/m3 fracción respirable =========================================================================== Section 3 −− IDENTIFICATION DES RISQUES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− SOURCES D’EXPOSITION L’exposition peut se produire par l’INHALATION des vapeurs ou du brouillard de pulvérisation. La PEAU et les YEUX peuvent entrer en contact avec le produit, les vapeurs ou le brouillard de pulvérisation. EFFET DE LA SUREXPOSITION YEUX: Irritation des YEUX. PEAU: L’exposition prolongée ou répétée risque de provoquer l’irritation des peau. INHALATION: Irritation des voies respiratoires supérieures. Peut causer la dépression nerveuse. Une sur−exposition excessive à ce produit peut entrainer la perte de conscience, voire même la mort. SYMPTÔMES DE SUREXPOSITION Les maux de tête, l’étourdissement, la nausée et la perte de coordination des mouvements sont tous des symptômes d’exposition excessive aux vapeurs ou à la brume de pulvérisation. La rougeur et les démangeaisons ou la sensation de brûlure peuvent indiquer une exposition excessive des yeux ou de la peau. ETAT DE SANTÉ AGGRAVÉ PAR EXPOSITION En général, aucun exposition n’est reconnue. CANCÉROGÉNICITÉ Voir la Section 11. =========================================================================== Section 4 −− PREMIERS SOINS −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− YEUX: Rincer les yeux à grande eau pendant 15 minutes. Aller voir un médecin. PEAU: Laver à fond les parties affectées avec de l’eau et du savon. Enlever les habits contaminés et les laver avant de les porter de nouveau. INHALATION: Si une personne en est affectée, l’aider à sortir des lieux. Rétablir la respiration. Aider la personne á rester calme et au chaud. INGESTION: N’incitez pas la personne á vomir. Aller voir un médecin immédiatement. =========================================================================== Section 5 −− MESURES EN CAS D’INCENDIE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− POINT D’ÉCLAIR LIE LSE Propellant < 0 F 0.9 12.8 MOYENS D’EXTINCTION Dioxyde de carbone, produit chimique sec, mousse Suite à la page 3 49200 page 3 =========================================================================== DANGERS D’INCENDIE OU D’EXPLOSION EXCEPTIONNELS Les contenants peuvent exploser s’ils sont exposés à une très grande chaleur. L’application aux surfaces chaudes exige qu’on prenne des précautions spéciales. En cas d’urgence, une exposition excessive aux produits de décomposition peut constituer un danger pour la santé. Les symptômes peuvent ne pas se manifester immédiatement. Voir le médecin. MESURES PARTICULIÉRES DI PROTECTION CONTRE L’INCENDIE On doit utiliser l’équipement de protection complète y compris un appareil de respiration auto−alimenté. La pulvérisation avec de l’eau peut être inefficace. Si on se sert de l’eau, l’ajutage pour brume est préférable. On peut se servir de l’eau pour refroidir les contenants fermés afin d’empêcher l’augmentation de la pression et la possibilité d’une combustion automatique ou l’explosion en cas d’exposition à une chaleur extrêmement grande. =========================================================================== Section 6 −− MARCHE Á SUIVRE EN CAS DE DÉVERSEMENT ACCIDENTEL −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− MESURES À PRENDRE LORSQUE DES MATIÉRES SONT RENVERSÉES OU ÉVAPORÉES Enlever toute source de combustion. Bien aérer. Nettoyer avec un absorbant non réactif. =========================================================================== Section 7 −− MANUTENTION ET ENTREPOSAGE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− CATÉGORIE D’ENTREPOSAGE Pas Disponible PRÉCAUTIONS Á PRENDRE LORS DE L’ENTREPOSAGE DI LA MANIPULATION Tenir loin de la chaleur, étincelles et de flamme nue. Les vapeurs peuvent s’accumuler rapidement et s’enflammer et causer une explosion. Aucours de l’utilisation de ce produit jusqu’à la disparution de toutes les vapeurs: Garder l’endroit bien aéré. Eviter de fumer. Eteindre toute flamme, veilleuse d’appareils et réchauds. Couper la courant des poêles, des outils et appareils éléctriques ainsi que de toute autre source de combustion. Suivre les procédures approuvées pour attacher solidement et pour permettre l’écoulement de l’éléctricité dans le sol. Contenu sous pression. Ne pas ouvrir, incinérer ou exposer à des températures au dessus de 120 Fahrenheit. La chaleur des rayons du soleil, des radiateurs, des réchauds, de l’eau chaude, ou provenant de toute autre source, peut provoquer l’explosion du contenant. Ne pas avaler. Garder hors de la portée des enfants. Suite à la page 4 49200 page 4 =========================================================================== Section 8 −− CONTRÔLE DE L’EXPOSITION ET PROTECTION INDIVIDUELLE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRÉCAUTIONS À PRENDRE AUCOURS DE L’UTILISATION N’utiliser ce produit que dans un endroit bien aéré. Éviter tout contact avec la peau et les yeux. Eviter d’aspirer les vapeurs et la brume de vaporisation. Bien se laver les mains après l’utilisation. Ce produit peut contenir des matières classifiées comme petites particules irritantes, telles que le dioxyde de titane ou le carbonate de calcium (voir la liste ACGIH TLV, la préface et l’annexe D). On peut avoir ces particules dans des proportions dangereuses uniquement au moment du grattement et de l’éraflement de la couche séchée. Si la liste dans la 2e section ne fait aucune mention spécifique de la présence des poussières de particules, les limites applicables sont: pour ACGIH TLV 10 mg/m3 (concentration totale de poussière), 3 mg/m3 (fractionée de respiratoire). VENTILATION Un système permettant l’échappement local des produits est préférable. Si l’exposition aux produits de la 2e section est maintenue au−dessous des limites d’exposition applicables, le système d’échappement global est acceptable. PROTECTION DES VOIES RESPIRATOIRES Si on ne peut pas maintenir, par simple ventilation, le niveau auquel on s’expos personnellement en dessous des limites applicables, porter un respirateur à filtre de vapeur organique et particules approprié et bien ajusté approuvé par NIOSH/MSHA pour se protéger contre les produits de la 2e section. Pendant que vous frottez ou poncez la couche sechée, porter un respirateur à filtre de poussière et de brume, approuvé par NIOSH/MSHA pour vous protéger contre la poussière qui peut éventuellement se dégager de ce produit, de la peinture ou de l’abrasif. GANTS PROTECTEURS Aucun n’est exigé pour l’application normale des produits aérosol, lorsqu’on n’attend qu’un minimum de contact avec la peau. Pour un contact prolongé et repété, portez des gants resistants aux produits chimiques. LUNETTES DE SÉCURITÉ Porter les lunetttes de sécurité avec des protecteurs latéraux non perforés. AUTRES PRÉCAUTIONS L’utilisation inappropriée de ce produit en le concentrant et en l’aspirant intentionnellement peut être dangereuse ou peut même causer la mort. =========================================================================== Section 9 −− PROPRIÉTÉS PHYSIQUES ET CHIMIQUES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− POIDS DU PRODUIT DENSITÉ COURBE D’ÉBULLITION POINT DE FUSION VOLUME VOLATIL VITESSE D’ÉVAPORATION DENSITÉ DE LA VAPEUR SOLUBILITÉ DANS L’EAU pH Suite à la page 5 6.68 lb/gal 800 g/l 0.80 <0 − 325 F <−18 − 162 C P.D. 87 % Plus vite que l’Éther Plus lourd que l’Air P.D. 7.0 49200 page 5 =========================================================================== COMPOSÉS ORGANIQUES VOLATILS (Théorique) Volatil Poids 44.90% Moins d’eau et de solvants exemptés =========================================================================== Section 10 −− STABILITÉ ET RÉACTIVITÉ −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STABILITÉ −− Stable CONDITIONS À ÉVITER Aucun connu. INCOMPATIBILITÉ Aucun connu. PRODUITS DANGEREUX DÛ À LA DÉCOMPOSITION Par combustion: Dioxyde de carbone, monoxyde de carbone POLYMÉRISATION DANGEREUSE Ne Peut Pas De Produire =========================================================================== Section 11 −− DONNÉES TOXICOLOGIQUES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− RISQUES DE SANTÉ CHRONIQUES À partir de données expérimentales provenant d’études suffisantes mendées chez les animaux et d’études insuffisantes menées chez humains, l’éthylbenzène est classifié par le CIRC comme étant possiblement carcinogène chez les humains (group 2B). On a constaté une augmentation de certains types de cancer, y compris des tumeurs du rein chez les rats et des tumeurs du poumon et du foie chez les souris, lorsque ces animaux ont été exposés à l’inhalation de concentrations élevées d’éthylbenzène à long terme. Toutefois, ces effets n’ont pas étéobservés chez les animaux exposés à de plus faibles concentrations d’éthylbenzène. Jusqu’à présent il n’y a aucune preuve suggérant que l’éthylbenzène provoque le cancer chez les humains. L’exposition, excessive et prolongée, aux solvants de la 2 section peut entrainer demauvaises conséquences aux systèmesdu fois,urinaire,cardio−vasculaire etreproductif. Les rats exposés à la poussière de dioxyde de titanium à une concentrations de 250mg/m3 ont développé le cancer des poumons. Toutefois, on ne peut pas atteindre une telle concentration en milieu du travail. Il existe des rapports de recherches qui associent des troubles permanentes du cerveau et du système nerveux à l’exposition excessive, répétée et prolongée aux solvants. −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− INFORMATION TOXICOLOGIQUE Suite à la page 6 49200 page 6 =========================================================================== CAS No. Ingredient −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 74−98−6 Propane LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible 106−97−8 Butane LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible 64742−89−8 Solvant Naphta Aliphatique Léger LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible 108−88−3 Toluène LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 100−41−4 Éthylbenzène LC50 RAT 4HR Pas Disponible LD50 RAT 3500 mg/kg 1330−20−7 Xylène LC50 RAT 4HR 5000 ppm LD50 RAT 4300 mg/kg 67−64−1 Acetone LC50 RAT 4HR Pas Disponible LD50 RAT 5800 mg/kg 108−10−1 Méthylisobutylcétone LC50 RAT 4HR Pas Disponible LD50 RAT 2080 mg/kg 13463−67−7 Dioxyde de Titane LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible =========================================================================== Section 12 −− DONNÉES ÉCOLOGIQUES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− Aucunes donnies disponibles. =========================================================================== Section 13 −− DONNÉES SUR L’ÉLIMINATION DU PRODUIT −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− MÉTHODE D’ÉLIMINATION DES DÉCHETS Les déchets provenant de ce produit peuvent être dangereux, selon la définition donnée dans la "U.S. Resource Conservation and Recovery Act" (RCRA) 40 CFR 261. On doit soumettre les déchets au test de combustion afin de déterminer les numéros de l’EPA applicables. Ne pas incinérer. Eliminer la pression dans le contenant. Se débarrasser du contenu confermément aux lois anti−pollution fédérales, provinciales et municipales. =========================================================================== Section 14 −− DONNÉES SUR LE TRANSPORT −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− Aucunes donnies disponibles. Suite à la page 7 49200 page 7 =========================================================================== Section 15 −− DONNÉES SUR LA RÉGLEMENTATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− SARA 313 (40 CFR 372.65C) AVIS DE FOURNISSEUR CAS No. CHIMIQUE/COMPOSÉ % by WT % Element −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 108−88−3 Toluène 10 100−41−4 Éthylbenzène 0.3 1330−20−7 Xylène 2 108−10−1 Méthylisobutylcétone 4 DONNÉES SUR LA TSCA Tous les produits chimiques dans ce produit sont énumérés, ou exemptez de l’énumération, sur le inventaire de TSCA. =========================================================================== Section 16 −− AUTRES DONNÉES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− Cette FTSS a été préparée conformént aux exigences du SIMDUT; les données sont toutefois présentées sous 16 rubriques. Les renseignements donnés ci−haut se rapportent à ce produit suivant sa formule actuelle et s’appuient sur les données disponibles en ce moment. L’addition de diluant et autres additifs peut changer considérablement les risques associés à ce produit et sa composition. Etant donné que nous n’avons pas de contrôle sur les conditions d’utilisation, nous ne donnons aucune guarantie, explicite ou implicite et nous n’assumons aucune responsabilité concernant l’usage, quel qu’il soit, de ces renseignements. MATERIAL SAFETY DATA SHEET 49219 03 00 Section 1 -- PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER DATE OF PREPARATION HMIS CODES Health 49219 06-SEP-07 Flammability Reactivity PRODUCT NAME KRYLON® RUST TOUGH® Rust Preventive Enamel (aerosol), Flat White 2* 3 0 MANUFACTURER'S NAME SHERWIN-WILLIAMS CANADA INC. KRYLON Products Group Vaughan, ON L4K 4T8 TELEPHONE NUMBERS and WEBSITES Product Information (800) 832-2541 Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency for Chemical Emergency ONLY (spill, leak, (800) 424-9300 fire, exposure, or accident) % by WT 15 7 4 11 0.2 32 Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS CAS No. INGREDIENT UNITS VAPOR PRESSURE 74-98-6 Propane ACGIH TLV 2500 ppm 760 mm OSHA PEL 1000 ppm 106-97-8 Butane ACGIH TLV 800 ppm 760 mm OSHA PEL 800 ppm 64742-89-8 V. M. & P. Naphtha ACGIH TLV 300 ppm 12 mm OSHA PEL 300 ppm OSHA PEL 400 ppm STEL 108-88-3 Toluene ACGIH TLV 20 ppm 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 100-41-4 Ethylbenzene ACGIH TLV 100 ppm 7.1 mm ACGIH TLV 125 ppm STEL OSHA PEL 100 ppm OSHA PEL 125 ppm STEL 67-64-1 Acetone ACGIH TLV 500 ppm 180 mm ACGIH TLV 750 ppm STEL OSHA PEL 1000 ppm Continued on page 2 49219 4 page 2 108-10-1 2 112926-00-8 7 13463-67-7 Methyl Isobutyl Ketone ACGIH TLV 50 ACGIH TLV 75 OSHA PEL 50 OSHA PEL 75 Amorphous Precipitated ACGIH TLV 10 OSHA PEL 6 Titanium Dioxide ACGIH TLV 10 OSHA PEL 10 OSHA PEL 5 ppm ppm STEL ppm ppm STEL Silica mg/m3 as Dust mg/m3 as Dust 16 mm mg/m3 as Dust mg/m3 Total Dust mg/m3 Respirable Fraction Section 3 -- HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Section 4 -- FIRST AID MEASURES EYES: SKIN: INHALATION: INGESTION: Flush eyes with large amounts of water for 15 minutes. Get medical attention. Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. If affected, remove from exposure. Restore breathing. Keep warm and quiet. Do not induce vomiting. Get medical attention immediately. Section 5 -- FIRE FIGHTING MEASURES FLASH POINT LEL UEL Propellant < 0 F 0.9 12.8 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam Continued on page 3 49219 page 3 UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 -- ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Section 7 -- HANDLING AND STORAGE STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. Continued on page 4 49219 page 4 Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 6.72 lb/gal 804 g/l SPECIFIC GRAVITY 0.81 BOILING POINT <0 - 325 F <-18 - 162 C MELTING POINT Not Available VOLATILE VOLUME 87 % EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 7.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) Volatile Weight 44.07% Less Water and Federally Exempt Solvents Continued on page 5 49219 page 5 Section 10 -- STABILITY AND REACTIVITY STABILITY -- Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Section 11 -- TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Ethylbenzene is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high ethylbenzene concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower concentrations. There is no evidence that ethylbenzene causes cancer in humans. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, cardiovascular and reproductive systems. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. TOXICOLOGY DATA Continued on page 6 49219 CAS No. 74-98-6 106-97-8 64742-89-8 108-88-3 100-41-4 67-64-1 108-10-1 112926-00-8 13463-67-7 page 6 Ingredient Name Propane LC50 RAT 4HR LD50 RAT Butane LC50 RAT 4HR LD50 RAT V. M. & P. Naphtha LC50 RAT 4HR LD50 RAT Toluene LC50 RAT 4HR LD50 RAT Ethylbenzene LC50 RAT 4HR LD50 RAT Acetone LC50 RAT 4HR LD50 RAT Methyl Isobutyl Ketone LC50 RAT 4HR LD50 RAT Amorphous Precipitated Silica LC50 RAT 4HR LD50 RAT Titanium Dioxide LC50 RAT 4HR LD50 RAT Not Available Not Available Not Available Not Available Not Available Not Available 4000 5000 ppm mg/kg Not Available 3500 mg/kg Not Available 5800 mg/kg Not Available 2080 mg/kg Not Available Not Available Not Available Not Available Section 12 -- ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Section 13 -- DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Continued on page 7 49219 page 7 Section 14 -- TRANSPORT INFORMATION US Ground (DOT) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2, LIMITED QUANTITY, EmS F-D, S-U Section 15 -- REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND 108-88-3 Toluene 100-41-4 Ethylbenzene 108-10-1 Methyl Isobutyl Ketone % by WT 11 0.1 4 % Element TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Section 16 -- OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. FICHE SIGNALÉTIQUE SANTÉ-SÉCURITÉ 460505 02 00 Section 1 -- IDENTIFICATION DU PRODUIT ET DE LA SOCIÉTÉ NUMÉRO DU PRODUIT DATE DE PRÉPARATION Santé 460505 29-SEP-07 Inflammabilité Réactivité NOM DU PRODUIT COLOUR ALL Spray Paint, Gloss Black 2* 3 0 NOM DU FABRICANT SHERWIN-WILLIAMS CANADA, INC. DUPLI-COLOR Products Group Vaughan, ON L4K 4T8 NUMÉROS DE TÉLÉPHONES ET SITES WEB Renseignements sur le produit (905) 761-9185 Renseignements réglementaires (216) 566-2902 www.paintdocs.com Urgence médicale (216) 566-2917 Urgence de transport pour une urgence chimique SEULEMENT (800) 424-9300 (déversement, fuite, incendie, exposition ou accident) Section 2 -- COMPOSITION/INFORMATION SUR LES INGRÉDIENTS CAS No. INGREDIENT UNITÉS PRESSION VAPEUR 74-98-6 Propane ACGIH TLV 2500 ppm 760 mm OSHA PEL 1000 ppm 106-97-8 Butane ACGIH TLV 800 ppm 760 mm OSHA PEL 800 ppm 108-88-3 Toluène ACGIH TLV 20 ppm 22 mm OSHA PEL 100 ppm (Peau) OSHA PEL 150 ppm (Peau) STEL 67-64-1 Acetone ACGIH TLV 500 ppm 180 mm ACGIH TLV 750 ppm STEL OSHA PEL 1000 ppm 763-69-9 3-Éthoxypropionate d'éthyle ACGIH TLV Pas Disponible 1.11 mm OSHA PEL Pas Disponible 1333-86-4 Noir de Carbone ACGIH TLV 3.5 mg/m3 OSHA PEL 3.5 mg/m3 % EN POIDS 14 13 21 40 3 0.4 Suite à la page 2 460505 page 2 Section 3 -- IDENTIFICATION DES RISQUES SOURCES D'EXPOSITION L'exposition peut se produire par l'INHALATION des vapeurs ou du brouillard de pulvérisation. La PEAU et les YEUX peuvent entrer en contact avec le produit, les vapeurs ou le brouillard de pulvérisation. EFFET DE LA SUREXPOSITION YEUX: Irritation des YEUX. PEAU: L'exposition prolongée ou répétée risque de provoquer l'irritation des peau. INHALATION: Irritation des voies respiratoires supérieures. Peut causer la dépression nerveuse. Une sur-exposition excessive à ce produit peut entrainer la perte de conscience, voire même la mort. L'exposition, excessive et prolongée, aux solvants de la 2 section peut entrainer de mauvaises conséquences aux systèmes du fois, urinaire, cardio-vasculaire et reproductif. SYMPTÔMES DE SUREXPOSITION Les maux de tête, l'étourdissement, la nausée et la perte de coordination des mouvements sont tous des symptômes d'exposition excessive aux vapeurs ou à la brume de pulvérisation. La rougeur et les démangeaisons ou la sensation de brûlure peuvent indiquer une exposition excessive des yeux ou de la peau. ETAT DE SANTÉ AGGRAVÉ PAR EXPOSITION En général, aucun exposition n'est reconnue. CANCÉROGÉNICITÉ Voir la Section 11. Section 4 -- PREMIERS SOINS YEUX: PEAU: INHALATION: INGESTION: Rincer les yeux à grande eau pendant 15 minutes. Aller voir un médecin. Laver à fond les parties affectées avec de l'eau et du savon. Enlever les habits contaminés et les laver avant de les porter de nouveau. Si une personne en est affectée, l'aider à sortir des lieux. Rétablir la respiration. Aider la personne á rester calme et au chaud. N'incitez pas la personne á vomir. Aller voir un médecin immédiatement. Section 5 -- MESURES EN CAS D'INCENDIE POINT D'ÉCLAIR LIE LSE Propellant < 0 F 1.0 12.8 MOYENS D'EXTINCTION Dioxyde de carbone, produit chimique sec, mousse Suite à la page 3 460505 page 3 DANGERS D'INCENDIE OU D'EXPLOSION EXCEPTIONNELS Les contenants peuvent exploser s'ils sont exposés à une très grande chaleur. L'application aux surfaces chaudes exige qu'on prenne des précautions spéciales. En cas d'urgence, une exposition excessive aux produits de décomposition peut constituer un danger pour la santé. Les symptômes peuvent ne pas se manifester immédiatement. Voir le médecin. MESURES PARTICULIÉRES DI PROTECTION CONTRE L'INCENDIE On doit utiliser l'équipement de protection complète y compris un appareil de respiration auto-alimenté. La pulvérisation avec de l'eau peut être inefficace. Si on se sert de l'eau, l'ajutage pour brume est préférable. On peut se servir de l'eau pour refroidir les contenants fermés afin d'empêcher l'augmentation de la pression et la possibilité d'une combustion automatique ou l'explosion en cas d'exposition à une chaleur extrêmement grande. Section 6 -- MARCHE Á SUIVRE EN CAS DE DÉVERSEMENT ACCIDENTEL MESURES À PRENDRE LORSQUE DES MATIÉRES SONT RENVERSÉES OU ÉVAPORÉES Enlever toute source de combustion. Bien aérer. Nettoyer avec un absorbant non réactif. Section 7 -- MANUTENTION ET ENTREPOSAGE CATÉGORIE D'ENTREPOSAGE Pas Disponible PRÉCAUTIONS Á PRENDRE LORS DE L'ENTREPOSAGE DI LA MANIPULATION Tenir loin de la chaleur, étincelles et de flamme nue. Les vapeurs peuvent s'accumuler rapidement et s'enflammer et causer une explosion. Aucours de l'utilisation de ce produit jusqu'à la disparution de toutes les vapeurs: Garder l'endroit bien aéré. Eviter de fumer. Eteindre toute flamme, veilleuse d'appareils et réchauds. Couper la courant des poêles, des outils et appareils éléctriques ainsi que de toute autre source de combustion. Suivre les procédures approuvées pour attacher solidement et pour permettre l'écoulement de l'éléctricité dans le sol. Contenu sous pression. Ne pas ouvrir, incinérer ou exposer à des températures au dessus de 120 Fahrenheit. La chaleur des rayons du soleil, des radiateurs, des réchauds, de l'eau chaude, ou provenant de toute autre source, peut provoquer l'explosion du contenant. Ne pas avaler. Garder hors de la portée des enfants. Suite à la page 4 460505 page 4 Section 8 -- CONTRÔLE DE L'EXPOSITION ET PROTECTION INDIVIDUELLE PRÉCAUTIONS À PRENDRE AUCOURS DE L'UTILISATION N'utiliser ce produit que dans un endroit bien aéré. Éviter tout contact avec la peau et les yeux. Eviter d'aspirer les vapeurs et la brume de vaporisation. Bien se laver les mains après l'utilisation. Ce produit peut contenir des matières classifiées comme petites particules irritantes, telles que le dioxyde de titane ou le carbonate de calcium (voir la liste ACGIH TLV, la préface et l'annexe D). On peut avoir ces particules dans des proportions dangereuses uniquement au moment du grattement et de l'éraflement de la couche séchée. Si la liste dans la 2e section ne fait aucune mention spécifique de la présence des poussières de particules, les limites applicables sont: pour ACGIH TLV 10 mg/m3 (concentration totale de poussière), 3 mg/m3 (fractionée de respiratoire). VENTILATION Un système permettant l'échappement local des produits est préférable. Si l'exposition aux produits de la 2e section est maintenue au-dessous des limites d'exposition applicables, le système d'échappement global est acceptable. PROTECTION DES VOIES RESPIRATOIRES Si on ne peut pas maintenir, par simple ventilation, le niveau auquel on s'expos personnellement en dessous des limites applicables, porter un respirateur à filtre de vapeur organique et particules approprié et bien ajusté approuvé par NIOSH/MSHA pour se protéger contre les produits de la 2e section. Pendant que vous frottez ou poncez la couche sechée, porter un respirateur à filtre de poussière et de brume, approuvé par NIOSH/MSHA pour vous protéger contre la poussière qui peut éventuellement se dégager de ce produit, de la peinture ou de l'abrasif. GANTS PROTECTEURS Aucun n'est exigé pour l'application normale des produits aérosol, lorsqu'on n'attend qu'un minimum de contact avec la peau. Pour un contact prolongé et repété, portez des gants resistants aux produits chimiques. LUNETTES DE SÉCURITÉ Porter les lunetttes de sécurité avec des protecteurs latéraux non perforés. AUTRES PRÉCAUTIONS L'utilisation inappropriée de ce produit en le concentrant et en l'aspirant intentionnellement peut être dangereuse ou peut même causer la mort. Section 9 -- PROPRIÉTÉS PHYSIQUES ET CHIMIQUES POIDS DU PRODUIT DENSITÉ COURBE D'ÉBULLITION POINT DE FUSION VOLUME VOLATIL VITESSE D'ÉVAPORATION DENSITÉ DE LA VAPEUR SOLUBILITÉ DANS L'EAU pH Suite à la page 5 6.08 lb/gal 728 g/l 0.73 <0 - 342 F <-18 - 172 C P.D. 94 % Plus vite que l'Éther Plus lourd que l'Air P.D. 7.0 460505 page 5 COMPOSÉS ORGANIQUES VOLATILS (Théorique) Volatil Poids 51.59% Moins d'eau et de solvants exemptés Section 10 -- STABILITÉ ET RÉACTIVITÉ STABILITÉ -- Stable CONDITIONS À ÉVITER Aucun connu. INCOMPATIBILITÉ Aucun connu. PRODUITS DANGEREUX DÛ À LA DÉCOMPOSITION Par combustion: Dioxyde de carbone, monoxyde de carbone POLYMÉRISATION DANGEREUSE Ne Peut Pas De Produire Section 11 -- DONNÉES TOXICOLOGIQUES RISQUES DE SANTÉ CHRONIQUES Il existe des rapports de recherches qui associent des troubles permanentes du cerveau et du système nerveux à l'exposition excessive, répétée et prolongée aux solvants. Le carbone noir est classifié par l'IARC comme étant possiblement carcinogène aux humains (groupe 2B) basé sur des données animales expérimentales. Cependant, dans les humains, l'évidence de carcinogénéité est insuffisante. INFORMATION TOXICOLOGIQUE CAS No. Ingredient 74-98-6 Propane LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible 106-97-8 Butane LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible 108-88-3 Toluène LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 67-64-1 Acetone LC50 RAT 4HR Pas Disponible LD50 RAT 5800 mg/kg 763-69-9 3-Éthoxypropionate d'éthyle LC50 RAT 4HR Pas Disponible LD50 RAT 5000 mg/kg 1333-86-4 Noir de Carbone LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible Section 12 -- DONNÉES ÉCOLOGIQUES Aucunes donnies disponibles. Suite à la page 6 460505 page 6 Section 13 -- DONNÉES SUR L'ÉLIMINATION DU PRODUIT MÉTHODE D'ÉLIMINATION DES DÉCHETS Les déchets provenant de ce produit peuvent être dangereux, selon la définition donnée dans la "U.S. Resource Conservation and Recovery Act" (RCRA) 40 CFR 261. On doit soumettre les déchets au test de combustion afin de déterminer les numéros de l'EPA applicables. Ne pas incinérer. Eliminer la pression dans le contenant. Se débarrasser du contenu confermément aux lois anti-pollution fédérales, provinciales et municipales. Section 14 -- DONNÉES SUR LE TRANSPORT US Ground (DOT) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2, LIMITED QUANTITY, EmS F-D, S-U Section 15 -- DONNÉES SUR LA RÉGLEMENTATION SARA 313 (40 CFR 372.65C) AVIS DE FOURNISSEUR CAS No. CHIMIQUE/COMPOSÉ 108-88-3 Toluène % by WT 21 % Element DONNÉES SUR LA TSCA Tous les produits chimiques dans ce produit sont énumérés, ou exemptez de l'énumération, sur le inventaire de TSCA. Section 16 -- AUTRES DONNÉES Cette FTSS a été préparée conformént aux exigences du SIMDUT; les données sont toutefois présentées sous 16 rubriques. Les renseignements donnés ci-haut se rapportent à ce produit suivant sa formule actuelle et s'appuient sur les données disponibles en ce moment. L'addition de diluant et autres additifs peut changer considérablement les risques associés à ce produit et sa composition. Etant donné que nous n'avons pas de contrôle sur les conditions d'utilisation, nous ne donnons aucune guarantie, explicite ou implicite et nous n'assumons aucune responsabilité concernant l'usage, quel qu'il soit, de ces renseignements. MATERIAL SAFETY DATA SHEET 3201 01 00 =========================================================================== Section 1 −− PRODUCT AND COMPANY IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT NUMBER HMIS CODES Health 2 3201 Flammability 4 Reactivity 0 PRODUCT NAME KRYLON* Appliance Epoxy Paint, White MANUFACTURER’S NAME EMERGENCY TELEPHONE NO. THE SHERWIN−WILLIAMS COMPANY (216) 566−2917 KRYLON Products Group Cleveland, OH 44115 DATE OF PREPARATION INFORMATION TELEPHONE NO. 24−JAN−06 (800) 832−2541 =========================================================================== Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 14 74−98−6 Propane ACGIH TLV 2500 ppm 760 mm OSHA PEL 1000 ppm 13 106−97−8 Butane ACGIH TLV 800 ppm 760 mm OSHA PEL 800 ppm 18 108−88−3 Toluene ACGIH TLV 50 ppm (Skin) 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 23 67−64−1 Acetone ACGIH TLV 500 ppm 180 mm ACGIH TLV 750 ppm STEL OSHA PEL 1000 ppm 12 123−86−4 n−Butyl Acetate ACGIH TLV 150 ppm 10 mm ACGIH TLV 200 ppm STEL OSHA PEL 150 ppm OSHA PEL 200 ppm STEL 7 13463−67−7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction =========================================================================== Section 3 −− HAZARDS IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. Continued on page 2 3201 page 2 =========================================================================== EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. =========================================================================== Section 4 −− FIRST AID MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re−use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. =========================================================================== Section 5 −− FIRE FIGHTING MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− FLASH POINT LEL UEL Propellant < 0 F 1.0 12.8 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self−contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build−up and possible autoignition or explosion when exposed to extreme heat. =========================================================================== Section 6 −− ACCIDENTAL RELEASE MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Continued on page 3 3201 page 3 =========================================================================== Section 7 −− HANDLING AND STORAGE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated − Do not smoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. =========================================================================== Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1−800−424−LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. Continued on page 4 3201 page 4 =========================================================================== OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. =========================================================================== Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT WEIGHT 6.55 lb/gal 784 g/l SPECIFIC GRAVITY 0.79 BOILING POINT <0 − 264 F <−18 − 128 C MELTING POINT Not Available VOLATILE VOLUME 89 % EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 7.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical) Volatile Weight 57.20 % Less Water and Federally Exempt Solvents =========================================================================== Section 10 −− STABILITY AND REACTIVITY −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STABILITY −− Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur =========================================================================== Section 11 −− TOXICOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, blood forming, cardiovascular and reproductive systems. Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung cancer, however, such exposure levels are not attainable in the workplace. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− TOXICOLOGY DATA Continued on page 5 3201 page 5 =========================================================================== CAS No. Ingredient Name −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 74−98−6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106−97−8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 108−88−3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 67−64−1 Acetone LC50 RAT 4HR Not Available LD50 RAT 5800 mg/kg 123−86−4 n−Butyl Acetate LC50 RAT 4HR 2000 ppm LD50 RAT 13100 mg/kg 13463−67−7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available =========================================================================== Section 12 −− ECOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ECOTOXICOLOGICAL INFORMATION No data available. =========================================================================== Section 13 −− DISPOSAL CONSIDERATIONS −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. =========================================================================== Section 14 −− TRANSPORT INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− No data available. =========================================================================== Section 15 −− REGULATORY INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 108−88−3 Toluene 18 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. Continued on page 6 3201 page 6 =========================================================================== TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. =========================================================================== Section 16 −− OTHER INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. MATERIAL SAFETY DATA SHEET SF31 03 00 Section 1 -- PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER DATE OF PREPARATION HMIS CODES Health SF31 29-SEP-07 Flammability Reactivity PRODUCT NAME Scratch Filler & Primer, Gray 3* 3 0 MANUFACTURER'S NAME THE SHERWIN-WILLIAMS CO. DUPLI-COLOR Products Group Cleveland, OH 44115 TELEPHONE NUMBERS and WEBSITES Product Information (800) 247-3270 www.duplicolor.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency for Chemical Emergency ONLY (spill, leak, (800) 424-9300 fire, exposure, or accident) % by WT 6 2 2 31 5 Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS CAS No. INGREDIENT UNITS VAPOR PRESSURE 108-88-3 Toluene ACGIH TLV 20 ppm 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 67-56-1 Methanol ACGIH TLV 200 ppm (Skin) 92 mm ACGIH TLV 250 ppm (Skin) STEL OSHA PEL 200 ppm (Skin) OSHA PEL 250 ppm (Skin) STEL 67-63-0 2-Propanol ACGIH TLV 400 ppm 33 mm ACGIH TLV 500 ppm STEL OSHA PEL 400 ppm OSHA PEL 500 ppm STEL 78-93-3 Methyl Ethyl Ketone ACGIH TLV 200 ppm 70 mm ACGIH TLV 300 ppm STEL OSHA PEL 200 ppm OSHA PEL 300 ppm STEL 108-10-1 Methyl Isobutyl Ketone ACGIH TLV 50 ppm 16 mm ACGIH TLV 75 ppm STEL OSHA PEL 50 ppm OSHA PEL 75 ppm STEL Continued on page 2 SF31 page 2 16 763-69-9 10 14807-96-6 4 471-34-1 6 13463-67-7 Ethyl 3-Ethoxypropionate ACGIH TLV Not Available 1.11 mm OSHA PEL Not Available Talc ACGIH TLV 2 mg/m3 as Resp. Dust OSHA PEL 2 mg/m3 as Resp. Dust Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 15 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction Section 3 -- HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, cardiovascular and reproductive systems. SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Section 4 -- FIRST AID MEASURES EYES: SKIN: INHALATION: INGESTION: Flush eyes with large amounts of water for 15 minutes. Get medical attention. Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. If affected, remove from exposure. Restore breathing. Keep warm and quiet. Do not induce vomiting. Get medical attention immediately. Continued on page 3 SF31 page 3 Section 5 -- FIRE FIGHTING MEASURES FLASH POINT LEL UEL 36 F PMCC 1.0 36.5 FLAMMABILITY CLASSIFICATION RED LABEL -- Flammable, Flash below 100 F (38 C) EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 -- ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Section 7 -- HANDLING AND STORAGE STORAGE CATEGORY DOL Storage Class IB PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Contents are FLAMMABLE. Keep away from heat, sparks, and open flame. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Continued on page 4 SF31 page 4 VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 8.89 lb/gal 1065 g/l SPECIFIC GRAVITY 1.07 BOILING POINT 148 - 342 F 64 - 172 C MELTING POINT Not Available VOLATILE VOLUME 78 % EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 5.52 lb/gal 661 g/l Less Water and Federally Exempt Solvents 5.52 lb/gal 661 g/l Emitted VOC Section 10 -- STABILITY AND REACTIVITY STABILITY -- Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Continued on page 5 SF31 page 5 Section 11 -- TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Methyl Ethyl Ketone may increase the nervous system effects of other solvents. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." TOXICOLOGY DATA CAS No. Ingredient Name 108-88-3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 67-56-1 Methanol LC50 RAT 4HR 64000 ppm LD50 RAT 5630 mg/kg 67-63-0 2-Propanol LC50 RAT 4HR Not Available LD50 RAT 5045 mg/kg 78-93-3 Methyl Ethyl Ketone LC50 RAT 4HR Not Available LD50 RAT 2740 mg/kg 108-10-1 Methyl Isobutyl Ketone LC50 RAT 4HR Not Available LD50 RAT 2080 mg/kg 763-69-9 Ethyl 3-Ethoxypropionate LC50 RAT 4HR Not Available LD50 RAT 5000 mg/kg 14807-96-6 Talc LC50 RAT 4HR Not Available LD50 RAT Not Available 471-34-1 Calcium Carbonate LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available Section 12 -- ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Continued on page 6 SF31 page 6 Section 13 -- DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Section 14 -- TRANSPORT INFORMATION US Ground (DOT) 1 Gallon and Less may be Classed as CONSUMER COMMODITY, ORM-D Larger Containers are Regulated as: UN1263, PAINT, 3, PG II, (ERG#128) DOT (Dept of Transportation) Hazardous Substances & Reportable Quantities Ethyl methyl ketone 5000 lb RQ Toluene 1000 lb RQ Xylenes (isomers and mixture) 100 lb RQ Bulk Containers may be Shipped as (check reportable quantities): UN1263, PAINT, 3, PG II, (ERG#128) Canada (TDG) UN1263, PAINT, CLASS 3, PG II, (ERG#128) IMO UN1263, PAINT, CLASS 3, PG II, MARINE POLLUTANT, (2 C c.c.), (TRICRESYL PHOSPHATE), EmS F-E, S-E Section 15 -- REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND 108-88-3 Toluene 67-56-1 Methanol 108-10-1 Methyl Isobutyl Ketone Zinc Compound % by WT 6 2 5 2 % Element 0.6 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Continued on page 7 SF31 page 7 Section 16 -- OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. MATERIAL SAFETY DATA SHEET SF31 03 00 Section 1 -- PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER DATE OF PREPARATION HMIS CODES Health SF31 29-SEP-07 Flammability Reactivity PRODUCT NAME Scratch Filler & Primer, Gray 3* 3 0 MANUFACTURER'S NAME THE SHERWIN-WILLIAMS CO. DUPLI-COLOR Products Group Cleveland, OH 44115 TELEPHONE NUMBERS and WEBSITES Product Information (800) 247-3270 www.duplicolor.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency for Chemical Emergency ONLY (spill, leak, (800) 424-9300 fire, exposure, or accident) % by WT 6 2 2 31 5 Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS CAS No. INGREDIENT UNITS VAPOR PRESSURE 108-88-3 Toluene ACGIH TLV 20 ppm 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 67-56-1 Methanol ACGIH TLV 200 ppm (Skin) 92 mm ACGIH TLV 250 ppm (Skin) STEL OSHA PEL 200 ppm (Skin) OSHA PEL 250 ppm (Skin) STEL 67-63-0 2-Propanol ACGIH TLV 400 ppm 33 mm ACGIH TLV 500 ppm STEL OSHA PEL 400 ppm OSHA PEL 500 ppm STEL 78-93-3 Methyl Ethyl Ketone ACGIH TLV 200 ppm 70 mm ACGIH TLV 300 ppm STEL OSHA PEL 200 ppm OSHA PEL 300 ppm STEL 108-10-1 Methyl Isobutyl Ketone ACGIH TLV 50 ppm 16 mm ACGIH TLV 75 ppm STEL OSHA PEL 50 ppm OSHA PEL 75 ppm STEL Continued on page 2 SF31 page 2 16 763-69-9 10 14807-96-6 4 471-34-1 6 13463-67-7 Ethyl 3-Ethoxypropionate ACGIH TLV Not Available 1.11 mm OSHA PEL Not Available Talc ACGIH TLV 2 mg/m3 as Resp. Dust OSHA PEL 2 mg/m3 as Resp. Dust Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 15 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction Section 3 -- HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, cardiovascular and reproductive systems. SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Section 4 -- FIRST AID MEASURES EYES: SKIN: INHALATION: INGESTION: Flush eyes with large amounts of water for 15 minutes. Get medical attention. Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. If affected, remove from exposure. Restore breathing. Keep warm and quiet. Do not induce vomiting. Get medical attention immediately. Continued on page 3 SF31 page 3 Section 5 -- FIRE FIGHTING MEASURES FLASH POINT LEL UEL 36 F PMCC 1.0 36.5 FLAMMABILITY CLASSIFICATION RED LABEL -- Flammable, Flash below 100 F (38 C) EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 -- ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Section 7 -- HANDLING AND STORAGE STORAGE CATEGORY DOL Storage Class IB PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Contents are FLAMMABLE. Keep away from heat, sparks, and open flame. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Continued on page 4 SF31 page 4 VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 8.89 lb/gal 1065 g/l SPECIFIC GRAVITY 1.07 BOILING POINT 148 - 342 F 64 - 172 C MELTING POINT Not Available VOLATILE VOLUME 78 % EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 5.52 lb/gal 661 g/l Less Water and Federally Exempt Solvents 5.52 lb/gal 661 g/l Emitted VOC Section 10 -- STABILITY AND REACTIVITY STABILITY -- Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Continued on page 5 SF31 page 5 Section 11 -- TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Methyl Ethyl Ketone may increase the nervous system effects of other solvents. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." TOXICOLOGY DATA CAS No. Ingredient Name 108-88-3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 67-56-1 Methanol LC50 RAT 4HR 64000 ppm LD50 RAT 5630 mg/kg 67-63-0 2-Propanol LC50 RAT 4HR Not Available LD50 RAT 5045 mg/kg 78-93-3 Methyl Ethyl Ketone LC50 RAT 4HR Not Available LD50 RAT 2740 mg/kg 108-10-1 Methyl Isobutyl Ketone LC50 RAT 4HR Not Available LD50 RAT 2080 mg/kg 763-69-9 Ethyl 3-Ethoxypropionate LC50 RAT 4HR Not Available LD50 RAT 5000 mg/kg 14807-96-6 Talc LC50 RAT 4HR Not Available LD50 RAT Not Available 471-34-1 Calcium Carbonate LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available Section 12 -- ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Continued on page 6 SF31 page 6 Section 13 -- DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Section 14 -- TRANSPORT INFORMATION US Ground (DOT) 1 Gallon and Less may be Classed as CONSUMER COMMODITY, ORM-D Larger Containers are Regulated as: UN1263, PAINT, 3, PG II, (ERG#128) DOT (Dept of Transportation) Hazardous Substances & Reportable Quantities Ethyl methyl ketone 5000 lb RQ Toluene 1000 lb RQ Xylenes (isomers and mixture) 100 lb RQ Bulk Containers may be Shipped as (check reportable quantities): UN1263, PAINT, 3, PG II, (ERG#128) Canada (TDG) UN1263, PAINT, CLASS 3, PG II, (ERG#128) IMO UN1263, PAINT, CLASS 3, PG II, MARINE POLLUTANT, (2 C c.c.), (TRICRESYL PHOSPHATE), EmS F-E, S-E Section 15 -- REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND 108-88-3 Toluene 67-56-1 Methanol 108-10-1 Methyl Isobutyl Ketone Zinc Compound % by WT 6 2 5 2 % Element 0.6 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Continued on page 7 SF31 page 7 Section 16 -- OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. MATERIAL SAFETY DATA SHEET SF31 03 00 Section 1 -- PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER DATE OF PREPARATION HMIS CODES Health SF31 29-SEP-07 Flammability Reactivity PRODUCT NAME Scratch Filler & Primer, Gray 3* 3 0 MANUFACTURER'S NAME THE SHERWIN-WILLIAMS CO. DUPLI-COLOR Products Group Cleveland, OH 44115 TELEPHONE NUMBERS and WEBSITES Product Information (800) 247-3270 www.duplicolor.com Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency for Chemical Emergency ONLY (spill, leak, (800) 424-9300 fire, exposure, or accident) % by WT 6 2 2 31 5 Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS CAS No. INGREDIENT UNITS VAPOR PRESSURE 108-88-3 Toluene ACGIH TLV 20 ppm 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 67-56-1 Methanol ACGIH TLV 200 ppm (Skin) 92 mm ACGIH TLV 250 ppm (Skin) STEL OSHA PEL 200 ppm (Skin) OSHA PEL 250 ppm (Skin) STEL 67-63-0 2-Propanol ACGIH TLV 400 ppm 33 mm ACGIH TLV 500 ppm STEL OSHA PEL 400 ppm OSHA PEL 500 ppm STEL 78-93-3 Methyl Ethyl Ketone ACGIH TLV 200 ppm 70 mm ACGIH TLV 300 ppm STEL OSHA PEL 200 ppm OSHA PEL 300 ppm STEL 108-10-1 Methyl Isobutyl Ketone ACGIH TLV 50 ppm 16 mm ACGIH TLV 75 ppm STEL OSHA PEL 50 ppm OSHA PEL 75 ppm STEL Continued on page 2 SF31 page 2 16 763-69-9 10 14807-96-6 4 471-34-1 6 13463-67-7 Ethyl 3-Ethoxypropionate ACGIH TLV Not Available 1.11 mm OSHA PEL Not Available Talc ACGIH TLV 2 mg/m3 as Resp. Dust OSHA PEL 2 mg/m3 as Resp. Dust Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 15 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction Section 3 -- HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, cardiovascular and reproductive systems. SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Section 4 -- FIRST AID MEASURES EYES: SKIN: INHALATION: INGESTION: Flush eyes with large amounts of water for 15 minutes. Get medical attention. Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. If affected, remove from exposure. Restore breathing. Keep warm and quiet. Do not induce vomiting. Get medical attention immediately. Continued on page 3 SF31 page 3 Section 5 -- FIRE FIGHTING MEASURES FLASH POINT LEL UEL 36 F PMCC 1.0 36.5 FLAMMABILITY CLASSIFICATION RED LABEL -- Flammable, Flash below 100 F (38 C) EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 -- ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Section 7 -- HANDLING AND STORAGE STORAGE CATEGORY DOL Storage Class IB PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Contents are FLAMMABLE. Keep away from heat, sparks, and open flame. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Continued on page 4 SF31 page 4 VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 8.89 lb/gal 1065 g/l SPECIFIC GRAVITY 1.07 BOILING POINT 148 - 342 F 64 - 172 C MELTING POINT Not Available VOLATILE VOLUME 78 % EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 5.52 lb/gal 661 g/l Less Water and Federally Exempt Solvents 5.52 lb/gal 661 g/l Emitted VOC Section 10 -- STABILITY AND REACTIVITY STABILITY -- Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Continued on page 5 SF31 page 5 Section 11 -- TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Methyl Ethyl Ketone may increase the nervous system effects of other solvents. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." TOXICOLOGY DATA CAS No. Ingredient Name 108-88-3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 67-56-1 Methanol LC50 RAT 4HR 64000 ppm LD50 RAT 5630 mg/kg 67-63-0 2-Propanol LC50 RAT 4HR Not Available LD50 RAT 5045 mg/kg 78-93-3 Methyl Ethyl Ketone LC50 RAT 4HR Not Available LD50 RAT 2740 mg/kg 108-10-1 Methyl Isobutyl Ketone LC50 RAT 4HR Not Available LD50 RAT 2080 mg/kg 763-69-9 Ethyl 3-Ethoxypropionate LC50 RAT 4HR Not Available LD50 RAT 5000 mg/kg 14807-96-6 Talc LC50 RAT 4HR Not Available LD50 RAT Not Available 471-34-1 Calcium Carbonate LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available Section 12 -- ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Continued on page 6 SF31 page 6 Section 13 -- DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Section 14 -- TRANSPORT INFORMATION US Ground (DOT) 1 Gallon and Less may be Classed as CONSUMER COMMODITY, ORM-D Larger Containers are Regulated as: UN1263, PAINT, 3, PG II, (ERG#128) DOT (Dept of Transportation) Hazardous Substances & Reportable Quantities Ethyl methyl ketone 5000 lb RQ Toluene 1000 lb RQ Xylenes (isomers and mixture) 100 lb RQ Bulk Containers may be Shipped as (check reportable quantities): UN1263, PAINT, 3, PG II, (ERG#128) Canada (TDG) UN1263, PAINT, CLASS 3, PG II, (ERG#128) IMO UN1263, PAINT, CLASS 3, PG II, MARINE POLLUTANT, (2 C c.c.), (TRICRESYL PHOSPHATE), EmS F-E, S-E Section 15 -- REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND 108-88-3 Toluene 67-56-1 Methanol 108-10-1 Methyl Isobutyl Ketone Zinc Compound % by WT 6 2 5 2 % Element 0.6 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Continued on page 7 SF31 page 7 Section 16 -- OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. FICHE SIGNALÉTIQUE SANTÉ-SÉCURITÉ B5WV1014 01 00 =========================================================================== Section 1 -- IDENTIFICATION DU PRODUIT ET DE LA SOCIÉTÉ --------------------------------------------------------------------------NUMÉRO DU PRODUIT Santé 1* B5WV1014 Inflammabilité 0 Réactivité 0 NOM DU PRODUIT Interior Latex Flat Paint, Antique White NOM DU FABRICANT NO. DE TÉLÉPHONE EN CAS D'URGENCE THE SHERWIN-WILLIAMS COMPANY (216) 566-2917 101 Prospect Avenue N.W. Cleveland, OH 44115 DATE DE PRÉPARATION NO. DE TÉLÉPHONE ORDINAIRE 18-APR-07 (216) 566-2902 =========================================================================== Section 2 -- COMPOSITION/INFORMATION SUR LES INGRÉDIENTS % EN POIDS CAS No. INGREDIENT UNITÉS PRESSION VAPEUR --------------------------------------------------------------------------0.3 14808-60-7 Quartz ACGIH TLV 0.05 mg/m3 de resp. poussiére OSHA PEL 0.1 mg/m3 de resp. poussiére 3 14464-46-1 Cristobalite ACGIH TLV 0.05 mg/m3 de resp. poussiére OSHA PEL 0.05 mg/m3 de resp. poussiére 7 1332-58-7 Kaolin ACGIH TLV 2 mg/m3 de resp. poussiére OSHA PEL 10 mg/m3 total de polva OSHA PEL 5 mg/m3 fracción respirable 4 14807-96-6 Talc ACGIH TLV 2 mg/m3 de resp. poussiére OSHA PEL 2 mg/m3 de resp. poussiére 6 471-34-1 Carbonate de Calcium ACGIH TLV 10 mg/m3 de poussiére OSHA PEL 15 mg/m3 total de polva OSHA PEL 5 mg/m3 fracción respirable 7 13463-67-7 Dioxyde de Titane ACGIH TLV 10 mg/m3 de poussiére OSHA PEL 10 mg/m3 total de polva OSHA PEL 5 mg/m3 fracción respirable =========================================================================== Section 3 -- IDENTIFICATION DES RISQUES --------------------------------------------------------------------------SOURCES D'EXPOSITION L'exposition peut se produire par l'INHALATION des vapeurs ou du brouillard de pulvérisation. La PEAU et les YEUX peuvent entrer en contact avec le produit, les vapeurs ou le brouillard de pulvérisation. Suite à la page 2 B5WV1014 page 2 =========================================================================== EFFET DE LA SUREXPOSITION YEUX: Irritation des YEUX. PEAU: L'exposition prolongée ou répétée risque de provoquer l'irritation des peau. INHALATION: Irritation des voies respiratoires supérieures. Dans un espace restreint, les vapeurs en grande concentration peuvent causer des maux de tête, des nausées ou l'étourdissement. SYMPTÔMES DE SUREXPOSITION La rougeur et les démangeaisons ou la sensation de brûlure peuvent indiquer une exposition excessive des yeux ou de la peau. ETAT DE SANTÉ AGGRAVÉ PAR EXPOSITION En général, aucun exposition n'est reconnue. CANCÉROGÉNICITÉ Voir la Section 11. =========================================================================== Section 4 -- PREMIERS SOINS --------------------------------------------------------------------------YEUX: Rincer les yeux à grande eau pendant 15 minutes. Aller voir un médecin. PEAU: Laver à fond les parties affectées avec de l'eau et du savon. Enlever les habits contaminés et les laver avant de les porter de nouveau. INHALATION: Si une personne en est affectée, l'aider à sortir des lieux. Rétablir la respiration. Aider la personne á rester calme et au chaud. INGESTION: N'incitez pas la personne á vomir. Aller voir un médecin immédiatement. =========================================================================== Section 5 -- MESURES EN CAS D'INCENDIE --------------------------------------------------------------------------POINT D'ÉCLAIR LIE LSE Non applicable P.D. P.D. CLASSIFICATION D'INFLAMMABILITÉ Non applicable MOYENS D'EXTINCTION Dioxyde de carbone, produit chimique sec, mousse d'alcool DANGERS D'INCENDIE OU D'EXPLOSION EXCEPTIONNELS Les contenants fermés peuvent exploser (à cause de l'augmentation de la pression) s'ils sont exposés à une chaleur extrême. En cas d'urgence, une exposition excessive aux produits de décomposition peut constituer un danger pour la santé. Les symptômes peuvent ne pas se manifester immédiatement. Voir le médecin. MESURES PARTICULIÉRES DI PROTECTION CONTRE L'INCENDIE On doit utiliser l'équipement de protection complète y compris un appareil de respiration auto-alimenté. La pulvérisation avec de l'eau peut être inefficace. Si on se sert de l'eau, l'ajutage pour brume est préférable. On peut se servir de l'eau pour refroidir les contenants fermés afin d'empêcher l'augmentation de la pression et la possibilité d'une combustion automatique ou l'explosion en cas d'exposition à une chaleur extrêmement grande. Suite à la page 3 B5WV1014 page 3 =========================================================================== Section 6 -- MARCHE Á SUIVRE EN CAS DE DÉVERSEMENT ACCIDENTEL --------------------------------------------------------------------------MESURES À PRENDRE LORSQUE DES MATIÉRES SONT RENVERSÉES OU ÉVAPORÉES Enlever toute source de combustion. Bien aérer. Nettoyer avec un absorbant non réactif. =========================================================================== Section 7 -- MANUTENTION ET ENTREPOSAGE --------------------------------------------------------------------------CATÉGORIE D'ENTREPOSAGE Non applicable PRÉCAUTIONS Á PRENDRE LORS DE L'ENTREPOSAGE DI LA MANIPULATION Garder le contenant fermé lorsqu'il n'est pas en usage. Transvaser seulement dans des contenants approuvés et ayant des étiquettes complètes et convenables. Ne pas avaler. Garder hors de la portée des enfants. =========================================================================== Section 8 -- CONTRÔLE DE L'EXPOSITION ET PROTECTION INDIVIDUELLE --------------------------------------------------------------------------PRÉCAUTIONS À PRENDRE AUCOURS DE L'UTILISATION N'utiliser ce produit que dans un endroit bien aéré. Éviter tout contact avec la peau et les yeux. Eviter d'aspirer les vapeurs et la brume de vaporisation. Bien se laver les mains après l'utilisation. Ce produit peut contenir des matières classifiées comme petites particules irritantes, telles que le dioxyde de titane ou le carbonate de calcium (voir la liste ACGIH TLV, la préface et l'annexe D). On peut avoir ces particules dans des proportions dangereuses uniquement au moment du grattement et de l'éraflement de la couche séchée. Si la liste dans la 2e section ne fait aucune mention spécifique de la présence des poussières de particules, les limites applicables sont: pour ACGIH TLV 10 mg/m3 (concentration totale de poussière), 3 mg/m3 (fractionée de respiratoire). L'enlèvement des anciennes peintures par ponçage, décapage ou toute autre méthode risque de dégager des poussières ou des vapeurs contaminées par le plomb. L'exposition à ces poussières ou vapeurs peut entraîner un dysfonctionnement du cerveau ou d'autres effets néfastes sur la santé, surtout chez les femmes enceintes et les enfants. L'utilisation d'équipement de protection approprié, tel qu'un appareil respiratoire bien ajusté et homologué par le NIOSH, ainsi que des moyens de confinement adéquats et un nettoyage convenable de ces substances sont nécessaires afin de contrôler l'exposition au plomb ou à d'autres substances dangereuses. Pour obtenir plus de renseignements, communiquer avec le National Lead Information Center au 1-800-424-5323 (aux É-U) ou avec le service local de santé publique. VENTILATION Un système permettant l'échappement local des produits est préférable. Si l'exposition aux produits de la 2e section est maintenue au-dessous des limites d'exposition applicables, le système d'échappement global est acceptable. Suite à la page 4 B5WV1014 page 4 =========================================================================== PROTECTION DES VOIES RESPIRATOIRES Si on ne peut pas maintenir, par simple ventilation, le niveau auquel on s'expos personnellement en dessous des limites applicables, porter un respirateur à filtre de vapeur organique et particules approprié et bien ajusté approuvé par NIOSH/MSHA pour se protéger contre les produits de la 2e section. Pendant que vous frottez ou poncez la couche sechée, porter un respirateur à filtre de poussière et de brume, approuvé par NIOSH/MSHA pour vous protéger contre la poussière qui peut éventuellement se dégager de ce produit, de la peinture ou de l'abrasif. GANTS PROTECTEURS Porter les gants recommandés par le fournisseur de gants pour se protéger contre les produits de la 2e section. LUNETTES DE SÉCURITÉ Porter les lunetttes de sécurité avec des protecteurs latéraux non perforés. =========================================================================== Section 9 -- PROPRIÉTÉS PHYSIQUES ET CHIMIQUES --------------------------------------------------------------------------POIDS DU PRODUIT 11.39 lb/gal 1364 g/l DENSITÉ 1.37 COURBE D'ÉBULLITION 212 - 213 F 100 - 100 C POINT DE FUSION P.D. VOLUME VOLATIL 65 % VITESSE D'ÉVAPORATION Plus lent que l'Éther DENSITÉ DE LA VAPEUR Plus lourd que l'Air SOLUBILITÉ DANS L'EAU P.D. pH 9.0 COMPOSÉS ORGANIQUES VOLATILS (Théorique) 0.37 lb/gal 44 g/l Moins d'eau et de Solvants Exemptés 0.13 lb/gal 16 g/l Émis COV =========================================================================== Section 10 -- STABILITÉ ET RÉACTIVITÉ --------------------------------------------------------------------------STABILITÉ -- Stable CONDITIONS À ÉVITER Aucun connu. INCOMPATIBILITÉ Aucun connu. PRODUITS DANGEREUX DÛ À LA DÉCOMPOSITION Par combustion: Dioxyde de carbone, monoxyde de carbone POLYMÉRISATION DANGEREUSE Ne Peut Pas De Produire Suite à la page 5 B5WV1014 page 5 =========================================================================== Section 11 -- DONNÉES TOXICOLOGIQUES --------------------------------------------------------------------------RISQUES DE SANTÉ CHRONIQUES La silice crystalline (tel que le quartz ou le cristobalite) figure sur la liste de l'IARC. L'exposition prolongée à de hautes concentrations de la poussière de silice (situation pouvant se développer seulement au moment du ponçage ou de l'éraflement de la couche sèche), peut provoquer des troubles des poumons(appelés silicosis) et même le cancer. Les rats exposés à la poussière de dioxyde de titanium à une concentrations de 250mg/m3 ont développé le cancer des poumons. Toutefois, on ne peut pas atteindre une telle concentration en milieu du travail. --------------------------------------------------------------------------INFORMATION TOXICOLOGIQUE CAS No. Ingredient --------------------------------------------------------------------------14808-60-7 Quartz LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible 14464-46-1 Cristobalite LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible 1332-58-7 Kaolin LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible 14807-96-6 Talc LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible 471-34-1 Carbonate de Calcium LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible 13463-67-7 Dioxyde de Titane LC50 RAT 4HR Pas Disponible LD50 RAT Pas Disponible =========================================================================== Section 12 -- DONNÉES ÉCOLOGIQUES --------------------------------------------------------------------------Aucunes donnies disponibles. =========================================================================== Section 13 -- DONNÉES SUR L'ÉLIMINATION DU PRODUIT --------------------------------------------------------------------------MÉTHODE D'ÉLIMINATION DES DÉCHETS Les déchets de ce produit ne présentent aucun danger, selon la définition donnée dans la "U.S. Resource Conservation and Recovery Act" (RCRA) 40 CFR 261. Incinérer dans un endroit approuvé. Ne pas incinérer les contenants fermés. Respecter les lois anti-pollution fédérales, provinciales et municipales. Suite à la page 6 B5WV1014 page 6 =========================================================================== Section 14 -- DONNÉES SUR LE TRANSPORT --------------------------------------------------------------------------US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. =========================================================================== Section 15 -- DONNÉES SUR LA RÉGLEMENTATION --------------------------------------------------------------------------SARA 313 (40 CFR 372.65C) AVIS DE FOURNISSEUR CAS No. CHIMIQUE/COMPOSÉ % by WT % Element --------------------------------------------------------------------------No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification CALIFORNIA PROPOSITION 65 AVERTISSEMENT: Ce produit des matières chimiques connue de l'État de la Californie qui peut causer le cancer, dommages à la naissance ou autre malformation congénitale. DONNÉES SUR LA TSCA Tous les produits chimiques dans ce produit sont énumérés, ou exemptez de l'énumération, sur le inventaire de TSCA. =========================================================================== Section 16 -- AUTRES DONNÉES --------------------------------------------------------------------------Cette FTSS a été préparée conformént aux exigences du SIMDUT; les données sont toutefois présentées sous 16 rubriques. Les renseignements donnés ci-haut se rapportent à ce produit suivant sa formule actuelle et s'appuient sur les données disponibles en ce moment. L'addition de diluant et autres additifs peut changer considérablement les risques associés à ce produit et sa composition. Etant donné que nous n'avons pas de contrôle sur les conditions d'utilisation, nous ne donnons aucune guarantie, explicite ou implicite et nous n'assumons aucune responsabilité concernant l'usage, quel qu'il soit, de ces renseignements. MATERIAL SAFETY DATA SHEET B30HV8003 04 00 =========================================================================== Section 1 -- PRODUCT AND COMPANY IDENTIFICATION --------------------------------------------------------------------------PRODUCT NUMBER HMIS CODES Health 1* B30HV8003 Flammability 0 Reactivity 0 PRODUCT NAME Interior Latex Flat Paint, Dover White MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. THE SHERWIN-WILLIAMS COMPANY (216) 566-2917 101 Prospect Avenue N.W. Cleveland, OH 44115 DATE OF PREPARATION INFORMATION TELEPHONE NO. 18-APR-07 (216) 566-2902 =========================================================================== Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE --------------------------------------------------------------------------1 64742-54-7 Heavy Paraffinic Oil ACGIH TLV 5 mg/m3 as Mist OSHA PEL 5 mg/m3 as Mist 0.2 14808-60-7 Quartz ACGIH TLV 0.05 mg/m3 as Resp. Dust OSHA PEL 0.1 mg/m3 as Resp. Dust 2 14464-46-1 Cristobalite ACGIH TLV 0.05 mg/m3 as Resp. Dust OSHA PEL 0.05 mg/m3 as Resp. Dust 21 471-34-1 Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 15 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction 12 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction =========================================================================== Section 3 -- HAZARDS IDENTIFICATION --------------------------------------------------------------------------ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. SIGNS AND SYMPTOMS OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION Continued on page 2 B30HV8003 page 2 =========================================================================== For complete discussion of toxicology data refer to Section 11. =========================================================================== Section 4 -- FIRST AID MEASURES --------------------------------------------------------------------------EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. =========================================================================== Section 5 -- FIRE FIGHTING MEASURES --------------------------------------------------------------------------FLASH POINT LEL UEL Not Applicable N.A. N.A. FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. =========================================================================== Section 6 -- ACCIDENTAL RELEASE MEASURES --------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. =========================================================================== Section 7 -- HANDLING AND STORAGE --------------------------------------------------------------------------STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Continued on page 3 B30HV8003 page 3 =========================================================================== Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION --------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Required for long or repeated contact. EYE PROTECTION Wear safety spectacles with unperforated sideshields. =========================================================================== Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES --------------------------------------------------------------------------PRODUCT WEIGHT 11.10 lb/gal 1329 g/l SPECIFIC GRAVITY 1.34 BOILING POINT 212 - 213 F 100 - 100 C MELTING POINT Not Available VOLATILE VOLUME 71 % EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 9.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.15 lb/gal 18 g/l Less Water and Federally Exempt Solvents 0.04 lb/gal 5 g/l Emitted VOC Continued on page 4 B30HV8003 page 4 =========================================================================== Section 10 -- STABILITY AND REACTIVITY --------------------------------------------------------------------------STABILITY -- Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur =========================================================================== Section 11 -- TOXICOLOGICAL INFORMATION --------------------------------------------------------------------------CHRONIC HEALTH HAZARDS Crystalline Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung cancer, however, such exposure levels are not attainable in the workplace. --------------------------------------------------------------------------TOXICOLOGY DATA CAS No. Ingredient Name --------------------------------------------------------------------------64742-54-7 Heavy Paraffinic Oil LC50 RAT 4HR Not Available LD50 RAT Not Available 14808-60-7 Quartz LC50 RAT 4HR Not Available LD50 RAT Not Available 14464-46-1 Cristobalite LC50 RAT 4HR Not Available LD50 RAT Not Available 471-34-1 Calcium Carbonate LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available =========================================================================== Section 12 -- ECOLOGICAL INFORMATION --------------------------------------------------------------------------ECOTOXICOLOGICAL INFORMATION No data available. =========================================================================== Section 13 -- DISPOSAL CONSIDERATIONS --------------------------------------------------------------------------WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Continued on page 5 B30HV8003 page 5 =========================================================================== Section 14 -- TRANSPORT INFORMATION --------------------------------------------------------------------------US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. =========================================================================== Section 15 -- REGULATORY INFORMATION --------------------------------------------------------------------------SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element --------------------------------------------------------------------------No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. =========================================================================== Section 16 -- OTHER INFORMATION --------------------------------------------------------------------------This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. MATERIAL SAFETY DATA SHEET 7915 01 00 Section 1 -- PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER DATE OF PREPARATION HMIS CODES Health 7915 29-SEP-07 Flammability Reactivity PRODUCT NAME KRYLON® Industrial ECO-GUARD™ Latex Enamel, Gray Primer 2* 2 0 MANUFACTURER'S NAME THE SHERWIN-WILLIAMS COMPANY Diversified Brands Cleveland, OH 44115 TELEPHONE NUMBERS and WEBSITES Product Information (800) 247-3266 Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917 Transportation Emergency for Chemical Emergency ONLY (spill, leak, (800) 424-9300 fire, exposure, or accident) % by WT 1 6 7 38 0.1 10 2 Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS CAS No. INGREDIENT UNITS VAPOR PRESSURE 71-36-3 1-Butanol ACGIH TLV 20 ppm (Skin) 5.5 mm OSHA PEL 50 ppm (Skin) CEILING 111-76-2 2-Butoxyethanol ACGIH TLV 20 ppm 0.88 mm OSHA PEL 25 ppm 67-64-1 Acetone ACGIH TLV 500 ppm 180 mm ACGIH TLV 750 ppm STEL OSHA PEL 1000 ppm 115-10-6 Dimethyl Ether ACGIH TLV Not Available 760 mm OSHA PEL Not Available 14808-60-7 Quartz ACGIH TLV 0.05 mg/m3 as Resp. Dust OSHA PEL 0.1 mg/m3 as Resp. Dust 14807-96-6 Talc ACGIH TLV 2 mg/m3 as Resp. Dust OSHA PEL 2 mg/m3 as Resp. Dust 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction Continued on page 2 7915 page 2 Section 3 -- HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary and blood forming systems. SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Section 4 -- FIRST AID MEASURES EYES: SKIN: INHALATION: INGESTION: Flush eyes with large amounts of water for 15 minutes. Get medical attention. Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. If affected, remove from exposure. Restore breathing. Keep warm and quiet. Do not induce vomiting. Get medical attention immediately. Section 5 -- FIRE FIGHTING MEASURES FLASH POINT LEL UEL Propellant < 0 F 1.1 27.0 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Continued on page 3 7915 page 3 Section 6 -- ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Section 7 -- HANDLING AND STORAGE STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Continued on page 4 7915 page 4 Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 7.40 lb/gal 886 g/l SPECIFIC GRAVITY 0.89 BOILING POINT <0 - 343 F <-18 - 172 C MELTING POINT Not Available VOLATILE VOLUME 88 % EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 7.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) Volatile Weight 46.70% Less Water and Federally Exempt Solvents Section 10 -- STABILITY AND REACTIVITY STABILITY -- Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Section 11 -- TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Crystalline Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer. IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint." TOXICOLOGY DATA Continued on page 5 7915 CAS No. 71-36-3 111-76-2 67-64-1 115-10-6 14808-60-7 14807-96-6 13463-67-7 page 5 Ingredient Name 1-Butanol LC50 LD50 2-Butoxyethanol LC50 LD50 Acetone LC50 LD50 Dimethyl Ether LC50 LD50 Quartz LC50 LD50 Talc LC50 LD50 Titanium Dioxide LC50 LD50 RAT RAT 4HR 8000 790 ppm mg/kg RAT RAT 4HR Not Available 470 mg/kg RAT RAT 4HR Not Available 5800 mg/kg RAT RAT 4HR Not Available Not Available RAT RAT 4HR Not Available Not Available RAT RAT 4HR Not Available Not Available RAT RAT 4HR Not Available Not Available Section 12 -- ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Section 13 -- DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Section 14 -- TRANSPORT INFORMATION US Ground (DOT) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2, LIMITED QUANTITY, EmS F-D, S-U Continued on page 6 7915 page 6 Section 15 -- REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND 71-36-3 1-Butanol Zinc Compound Glycol Ethers % by WT 1 2 6 % Element 0.6 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Section 16 -- OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. MATERIAL SAFETY DATA SHEET . 1. Product and Company Identification space Product Name Porcelain Repair: White - PA40FP88, Almond - PA40FP89, Grey - PA40FP90 Mixture space CAS # space Coating Product Use space Mumby & Associates Limited 7040 Financial Drive Mississauga, ON L5N 7H5 CA Phone 905-812-9319 Emergency Phone: 1-613-996-666 (CANUTEC) Manufacturer space LEGEND HMIS/NFPA Severe Serious Moderate Slight Minimal Health 4 3 2 1 0 * 2 Flammability 3 Physical Hazard 0 Personal Protection 3 2 0 B . 2. Hazards Identification space DANGER Flammable liquid - may release vapours that form flammable mixtures at or above the flash point. Containers may explode when heated. MAY CAUSE EYE AND SKIN IRRITATION. Contains a potential teratogen. Emergency Overview space Potential short term health effects Routes of exposure Eye, Skin contact, Skin absorption, Inhalation, Ingestion. space Eyes May cause irritation. Skin May cause irritation. Inhalation May cause respiratory tract irritation. Ingestion May cause stomach distress, nausea or vomiting. space space space space Target organs Blood. Eyes. Kidney. Liver. Respiratory system. Skin. space Chronic effects Prolonged or repeated exposure can cause drying, defatting and dermatitis. space Signs and symptoms Symptoms may include redness, oedema, drying, defatting and cracking of the skin. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. . 3. Composition/Information on Ingredients space Ingredient(s) CAS # Percent Xylene 1330-20-7 1-5 Solvent naphtha (petroleum), light aromatic 64742-95-6 10 - 30 1,2,4-Trimethylbenzene 95-63-6 10 - 30 Toluene 108-88-3 5 - 10 . 4. First Aid Measures space First aid procedures Eye contact space Skin contact space Inhalation space Ingestion #13802 Flush with cool water. Remove contact lenses, if applicable, and continue flushing. Obtain medical attention if irritation persists. Flush with cool water. Wash with soap and water. Obtain medical attention if irritation persists. If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention. Do not induce vomiting. Rinse mouth with water, then drink one or two glasses of water. Obtain medical attention. Never give anything by mouth if victim is unconscious, or is convulsing. Page 1 of 5 Issue date 08-Aug-2006 space Symptoms may be delayed. Notes to physician space If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. General advice . 5. Fire-fighting Measures space Flammable by WHMIS criteria. Vapours may travel to a source of ignition and flash back. Containers may explode when heated. Flammable properties space Extinguishing media Suitable extinguishing media Dry chemical. Foam. Carbon dioxide. space Unsuitable extinguishing media Not available space Protection of firefighters Specific hazards arising from the chemical Not available space Protective equipment for firefighers Firefighters should wear full protective clothing including self contained breathing apparatus. space Hazardous combustion products May include and are not limited to: Oxides of carbon. space Explosion data Sensitivity to mechanical impact Not available space Sensitivity to static discharge Not available . 6. Accidental Release Measures space Keep unnecessary personnel away. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill/leak. Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Remove sources of ignition. Personal precautions space Methods for containment space Methods for cleaning up . 7. Handling and Storage space Use according to package label instructions. Handling space Keep out of reach of children.Store in a closed container away from incompatible materials. Keep away from heat, open flames or other sources of ignition. Storage . 8. Exposure Controls / Personal Protection space Exposure limits Ingredient(s) Exposure limits 1,2,4-Trimethylbenzene ACGIH-TLV TWA: 25 ppm Solvent naphtha (petroleum), light aromatic ACGIH-TLV Not established Toluene ACGIH-TLV TWA: 50 ppm Skin: 50 ppm Xylene ACGIH-TLV TWA: 100 ppm STEL: 150 ppm space Engineering controls General ventilation normally adequate. space Personal protective equipment Eye/Face protection #13802 Safety glasses Page 2 of 5 Issue date 08-Aug-2006 space Rubber gloves. Confirm with a reputable supplier first. Hand protection space Skin and body protection As required by employer code. Respiratory protection Not normally required if good ventilation is maintained. space space General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. Wash hands before breaks and immediately after handling the product. . 9. Physical & Chemical Properties space Opaque. Appearance space Varies Colour space Liquid Form space Strong Hydrocarbon Odour space Not available Odour threshold space Liquid Physical state space Not available pH space Not available Freezing point space 110 °C (230.00 °F) Boiling point space 7.2 °C (44.96 °F) TCC Flash point space > 1 (Ether = 1) Evaporation Rate space Flammability limits in air, lower, % by volume 1 space Flammability Limits in Air, Upper, % 12.6 by Volume Not available Vapour pressure space space > 1 (Air = 1) Vapour density space 1.15 (H2O = 1) Specific gravity space Not available Octanol/water coefficient space Insoluble Solubility (H2O) space Auto-ignition temperature Not available space 45 - 55 VOC (Weight %) space Slightly viscous Viscosity . 10. Chemical Stability & Reactivity Information space Chemical stability Stable under recommended storage conditions. space Conditions to avoid Avoid high temperatures. Do not mix with other chemicals. space Incompatible materials Strong oxidizing agents. Acids. space Hazardous decomposition products May include and are not limited to: Oxides of carbon. Hazardous polymerisation does not occur. Possibility of hazardous reactions space . 11. Toxicological Information space Component analysis - LC50 Ingredient(s) LC50 1,2,4-Trimethylbenzene 3661 ppm rat Solvent naphtha (petroleum), light aromatic > 10.2 mg/L rat Toluene 5100 ppm rat; 19 mg/l/4h rat Xylene 6350 ppm rat space Component analysis - Oral LD50 Ingredient(s) LD50 1,2,4-Trimethylbenzene 3280 mg/kg rat Solvent naphtha (petroleum), light aromatic 4700 mg/kg rat Toluene 636 mg/kg rat Xylene 3523 mg/kg rat #13802 Page 3 of 5 Issue date 08-Aug-2006 space Effects of acute exposure Eye May cause irritation. space Skin May cause irritation. Inhalation May cause respiratory tract irritation. Ingestion May cause stomach distress, nausea or vomiting. space space space Non-hazardous by WHMIS criteria. Sensitisation space Contains a potential teratogen. Chronic effects space Non-hazardous by WHMIS criteria. Carcinogenicity ACGIH - Threshold Limits Values - Carcinogens Toluene Xylene 108-88-3 1330-20-7 A4 - Not Classifiable as a Human Carcinogen A4 - Not Classifiable as a Human Carcinogen space Mutagenicity Non-hazardous by WHMIS criteria. space Reproductive effects Non-hazardous by WHMIS criteria. space Teratogenicity Contains potential teratogens. . 12. Ecological Information space Ecotoxicity effects space Environmental effects Components of this product have been identified as having potential environmental concerns. Harmful to aquatic life. space Aquatic toxicity Not available space Persistence and degradability Not available space Bioaccumulation/accumulation Not available space Partition coefficient Not available space Mobility in environmental media Not available space Chemical fate information Not available . 13. Disposal Considerations space Waste codes Not available space Disposal instructions Review federal, provincial, and local government requirements prior to disposal. space Waste from residues / unused products Not available space Contaminated packaging Not available . 14. Transport Information space Transportation of Dangerous Goods (TDG) Basic shipping requirements: Proper shipping name PAINT Hazard class 3 UN number 1263 Packing group II Additional information: Special provisions 59 . 15. Regulatory Information space Canadian federal regulations space WHMIS classification #13802 This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Exempt - Consumer product Page 4 of 5 Issue date 08-Aug-2006 space Inventory Status Country(s) or region Canada Canada Inventory Name Domestic Substances List (DSL) Non-Domestic Substances List (NDSL) On Inventory (Yes/No)* Yes No . 16. Other Information space Disclaimer space Issue date Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. 08-Aug-2006 space Effective Date 15-Aug-2006 space Expiry Date 15-Aug-2009 space Prepared by #13802 Dell Tech Laboratories Ltd. (519) 858-5021 Page 5 of 5 Issue date 08-Aug-2006 MATERIAL SAFETY DATA SHEET SPRAYTEX, Inc. 28430 West Witherspoon Parkway Valencia, CA 91355 Emergency (800) 234-5979 Information (661) 257-8787 SPRAYTEX WHITE CEILING TEXTURE Latest Revision Date 6/21/94 Print Date 1/1/01 SECTION 1 PRODUCT IDENTIFICATION PRODUCT NAME OR NUMBER ................................................ SPRC004 [4044-W] TRADE NAME OR CHEMICAL NAME ....................................... SPRAYTEX WHITE CEILING TEXTURE SYNONYMS................................................................................ NA FORMULA................................................................................... TSP0401 (L29326) CHEMICAL FAMILY.................................................................... NA MOLECULAR WEIGHT .............................................................. NA NFPA........................................................................................... NA HMIS RATING............................................................................. HEALTH=1; FLAMMABILITY=0; REACTIVITY=0 SECTION 2 CHEMICAL NAMES HAZARDOUS INGREDIENTS / HAZARD DATA CAS NUMBER % WT TLV-TWA CALCIUM CARBONATE 471-34-1 47 0.1mg/m3 NOT ESTABLISHED NO DIMETHYL ETHER 115-10-6 9 NONE ESTABLISHED NONE ESTABLISHED NO 068476-86-8 1 1000ppm NOT ESTABLISHED NO MIXTURE OF: PROPANE/ISOBUTANE PEL SEC.313 *Information for mixtures is based on constituent MSDS which are available upon request. (Minus Proprietary Trade Names) SECTION 3 PHYSICAL DATA BOILING/MELTING POINT @760 mm Hg ................................. NOT ESTABLISHED pH................................................................................................ NOT ESTABLISHED VAPOR PRESSURE mm Hg @ 20° C........................................ 90 psig @ 70° F VAPOR DENSITY (Air = 1) ......................................................... >1 PERCENT VOLATILE BY WEIGHT(%) ...................................... NA SPECIFIC GRAVITY OR BULK DENSITY ................................. 1.25 SOLUBILITY IN WATER ............................................................. MISCIBLE EVAPORATION RATE (BuAc = 1).............................................. 1 APPEARANCE............................................................................ OFF WHITE, TAN & GRAY THICK PASTE ODOR.......................................................................................... CHARACTERISTIC FRAGRANCE INTENSITY.................................................................................. NA SECTION 4 FIRE AND EXPLOSION HAZARD DATA FLASH POINT °f (Test Method) .................................................. NON-FLAMMABLE AUTOIGNITION TEMPERATURE .............................................. NOT ESTABLISHED FLAMMABILITY LIMITS IN AIR (% V) ........................................ NA EXTINGUISHING MEDIA . . . . . . . . . . . ANY MEDIA CAPABLE OF EXTINGUISHING THE SUPPORTING FIRE. SPECIAL FIRE FIGHTING PROCEDURES . . KEEP TEMPERATURES OF CONTAINERS BELOW 120° f BY SPRAYING WITH WATER UNTIL FIRE HAS BEEN EXTINGUISHED. UNUSUAL FIRE & EXPLOSION HAZARDS . . CONTAINERS MAY RUPTURE AND RELEASE A SMALL AMOUNT OF FLAMMABLE GAS IF EXPOSED TO HEAT OF FIRE. SECTION 5 HEALTH HAZARDS DATA * EFFECTS OF OVEREXPOSURE SKIN CONTACT................WASH EXCESS MATERIAL FROM SKIN WITH SOAP & WATER. EYE CONTACT.................FLUSH EYES WITH WARM WATER FOR 10 MINUTES. CONSULT A PHYSICIAN IF IRRITATION OCCURS OR WORSENS. INHALATION.....................IF INHALED EXCESSIVELY, REMOVE TO FRESH AIR. INGESTION.......................PRODUCT IS NOT LIKELY TO BE INGESTED. IF THIS OCCURS TREAT SYMPTOMATICALLY. CHRONIC EFFECTS OF OVEREXPOSURE..........NONE WHEN USED AS DIRECTED. TOXICOLOGICAL TEST DATA ...............................NO RESULTS AVAILABLE. note: ALL CHEMICALS ARE LISTED ON THE TSCA INVENTORY. SPRAYTEX WHITE CEILING TEXTURE SECTION 6 EMERGENCY AND FIRST AID PROCEDURES SKIN .................. Wash affected area with water while removing contaminated clothing. GET IMMEDIATE MEDICAL ATTENTION. Launder contaminated clothing before reuse. EYES.................. Flush eyes with generous amounts of water for at least 15 minutes. GET IMMEDIATE MEDICAL ATTENTION. INGESTION........ If swallowed, DO NOT INDUCE VOMITING. Dilute with water or milk. CALL A PHYSICIAN IMMEDIATELY. Never give fluids or induce vomiting if the victim is unconscious or having convulsions. INHALATION...... Move to fresh air. Aid in breathing, if necessary and get immediate medical attention. SECTION 7 REACTIVITY DATA PRODUCT STABILITY ....................................... STABLE CONDITIONS TO AVOID ............................... NONE KNOWN. CONTENTS ARE STABLE BUT UNDER PRESSURE. DO NOT PUNCTURE OR INCINERATE CONTAINERS, EVEN WHEN EMPTY. CHEMICAL INCOMPATIBILITY.......................... KEEP AWAY FROM ACIDS. HAZARDOUS DECOMPOSITION PRODUCTS. CALCIUM OXIDE MAY BE PRODUCED ON DECOMPOSITION. HAZARDOUS POLYMERIZATION..................... WILL NOT OCCUR. CONDITIONS TO AVOID ............................... NONE KNOWN. CORROSIVE TO METAL.................................... NO. OXIDIZER ........................................................... NA SECTION 8 SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION............. NIOSH/MSHA - Approved organic vapor respirator when vapors are generated above ............................................................... the permissible limit VENTILATION........................................ Local exhaust to control to recommended P.E.L. PROTECTIVE CLOTHING..................... Gloves, coveralls, aprons, boots, - as necessary to prevent skin contact. EYE PROTECTION ............................... Chemical Goggles OTHER PRECAUTIONS........................ Avoid excessive inhalations. Read and follow all label directions and cautions. Eyewash fountains should be easily accessible. SECTION 9 ENVIRONMENTAL DATA ENVIRONMENTAL TOXICITY DATA ..............NA SPILL OR LEAK PROCEDURES ....................LEAKING CONTAINERS SHOULD BE PLACED IN AN OPENED CONTAINER, OUTDOORS, AWAY FROM SOURCES OF IGNITION, UNTIL ALL PRESSURE IS RELEASED. HAZARDOUS SUBSTANCE SUPERFUND ....NA WASTE DISPOSAL METHOD..... BURY OR INCINERATE IN APPROVED DISPOSAL FACILITIES IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATION. CONTAINER DISPOSAL ............. EMPTY CONTAINERS & DRIED PRODUCT MAY BE DISPOSED OF AS NORMAL REFUSE. SECTION 10 SHIPPING DATA D.O.T. PROPER SHIPPING NAME......................................CONSUMER COMMODITY HAZARDOUS SUBSTANCE 49CFR CERCLA.....................NA D.O.T. HAZARD CLASS .......................................................ORM-D D.O.T. LABELS REQUIRED .................................................NONE D.O.T. PLACARDS REQUIRED ...........................................NONE POISON CONSTITUENT......................................................NONE BILL OF LADING DESCRIPTION.........................................CONSUMER COMMODITY ORM-D CC NO...................................................................................NA UN/NA CODE........................................................................NONE SECTION 11 SUPPLIER INFORMATION The information contained herein is, to the best of our knowledge and belief, accurate and reliable as of the date of issued. We do not however, warrant or guarantee the accuracy or reliability, nor shall we be liable for any loss or damage arising out of the use thereof. The information is offered for the user's consideration and examination, and it is the user's responsibility to satisfy himself that it is suitable and complete for his particular use. PREPARED BY: J. STATEN, TECHNICAL SPECIALIST 6/21/94 / REFORMATTED: S. THOMAS 3/1/96 712828.txt MATERIAL SAFETY DATA SHEET SPRAYTEX, INC. 28430 WEST WITHERSPOON PARKWAY VALENCIA, CA 91355 EMERGENCY: (800) 234-5979 INFORMATION: (661) 257-8787 SPRAYTEX CONTRACTOR SIZE ORANGEPEEL DRYWALL SPRAY TEXTURE LATEST REVISION DATE: 6/21/94 PRINT DATE: 1/1/01 ------SECTION 1 PRODUCT IDENTIFICATION -----PRODUCT NAME OR NUMBER: SPRC003 (5055) TRADE NAME OR CHEMICAL NAME: SPRAYTEX CONTRACTOR SIZE ORANGEPEEL SYNONYMS: NA FORMULA: TSP0301 (L29145) CHEMICAL FAMILY: NA MOLECULAR WEIGHT: NA NFPA: HEALTH 1 FLAMMABILITY 4 REACTIVITY 0 HMIS RATING: HEALTH 1 FLAMMABILITY 4 REACTIVITY 0 ------SECTION 2 HAZARDOUS INGREDIENTS / HAZARD DATA -----CHEMICAL NAMES CAS NUMBER % WT TLV - TWA PEL SEC. 313 CALCIUM CARBONATE 471-34-1 47 0.1 MG/M3 NOT ESTABLISHED NO ISOPROPYL ALCOHOL 67-63-0 6 400 PPM 400 PPM NO 10 NONE ESTABLISHED NONE ESTABLISHED NO DIMETHYL ETHER 115-10-6 *INFORMATION FOR MIXTURES IS BASED ON CONSTITUENT MSDS WHICH ARE AVAILABLE UPON REQUEST. (MINUS PROPRIETARY TRADE NAMES) ------SECTION 3 PHYSICAL DATA -----BOILING/MELTING POINT @ 760 MMHg: NOT ESTABLISHED pH: NOT ESTABLISHED VAPOR PRESSURE MMHg @ 20 DEG. C: 60 PSIG @ 70 DEG. F Page 1 VAPOR DENSITY (AIR = 1): >1 712828.txt PERCENT VOLATILE BY WEIGHT (%): NA SPECIFIC GRAVITY OR BULK DENSITY: 1.25 SOLUBILITY IN WATER: MISCIBLE EVAPORATION RATE (BuAc = 1): 1 APPEARANCE: OFF WHITE THICK PASTE ODOR: CITRUS INTENSITY: NA ------SECTION 4 FIRE AND EXPLOSION HAZARD DATA -----FLASH POINT DEG. F (TEST METHOD): -42 DEG. F TOC AUTOIGNITION TEMPERATURE: 622 DEG. F FLAMMABILITY LIMITS IN AIR (% V): LEL: 3.4 % UEL: 18.0 % EXTINGUISHING MEDIA: ANY MEDIA CAPABLE OF EXTINGUISHING THE SUPPORTING FIRE. SPECIAL FIRE FIGHTING PROCEDURES: KEEP TEMPERATURES OF CONTAINERS BELOW 120 DEG. F BY SPRAYING WITH WATER UNTIL FIRE HAS BEEN EXTINGUISHED. UNUSUAL FIRE & EXPLOSION HAZARDS: CONTAINERS MAY RUPTURE AND RELEASE A SMALL AMOUNT OF FLAMMABLE GAS IF EXPOSED TO HEAT OF FIRE. ------SECTION 5 HEALTH HAZARDS DATA * EFFECTS OF OVEREXPOSURE -----SKIN CONTACT: WASH EXCESS MATERIAL FROM SKIN WITH SOAP & WATER. EYE CONTACT: FLUSH EYES WITH WARM WATER FOR 10 MINUTES. CONSULT A PHYSICIAN IF IRRITATION OCCURS OR WORSENS. INHALATION: IF INHALED EXCESSIVELY, REMOVE TO FRESH AIR. INGESTION: PRODUCT IS NOT LIKELY TO BE INGESTED. IF THIS OCCURS TREAT SYMPTOMATICALLY. CHRONIC EFFECTS OF OVEREXPOSURE: NONE WHEN USED AS DIRECTED. TOXICOLOGICAL TEST DATA: NO RESULTS AVAILABLE. NOTE: ALL CHEMICALS ARE LISTED ON THE TSCA INVENTORY. ------SECTION 6 EMERGENCY AND FIRST AID PROCEDURES -----SKIN: WASH AFFECTED AREA WITH WATER WHILE REMOVING CONTAMINATED CLOTHING. GET IMMEDIATE MEDICAL ATTENTION. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. EYES: FLUSH EYES WITH GENEROUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. Page 2 GET IMMEDIATE MEDICAL ATTENTION. 712828.txt INGESTION: IF SWALLOWED, DO NOT INDUCE VOMITING. DILUTE WITH WATER OR MILK. CALL A PHYSICIAN IMMEDIATELY. NEVER GIVE FLUIDS OR INDUCE VOMITING IF THE VICTIM IS UNCONSCIOUS OR HAVING CONVULSIONS. INHALATION: MOVE TO FRESH AIR. AID IN BREATHING, IF NECESSARY AND GET IMMEDIATE MEDICAL ATTENTION. ------SECTION 7 REACTIVITY DATA -----PRODUCT STABILITY: STABLE CONDITIONS TO AVOID: NONE KNOWN. CONTENTS ARE STABLE BUT UNDER PRESSURE. DO NOT PUNCTURE OR INCINERATE CONTAINERS, EVEN WHEN EMPTY. CHEMICAL INCOMPATIBILITY: KEEP AWAY FROM ACIDS. HAZARDOUS DECOMPOSITION PRODUCTS: CALCIUM OXIDE MAY BE PRODUCED ON DECOMPOSITION. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR. CONDITIONS TO AVOID: NONE KNOWN. CORROSIVE TO METAL: NO. OXIDIZER: NA ------SECTION 8 SPECIAL PROTECTION INFORMATION -----RESPIRATORY PROTECTION: NIOSH/MSHA - APPROVED ORGANIC VAPOR RESPIRATOR WHEN VAPORS ARE GENERATED ABOVE THE PERMISSIBLE LIMIT. VENTILATION: LOCAL EXHAUST TO CONTROL TO RECOMMENDED P.E.L. PROTECTIVE CLOTHING: GLOVES, COVERALLS, APRONS, BOOTS, - AS NECESSARY TO PREVENT SKIN CONTACT. EYE PROTECTION: CHEMICAL GOGGLES OTHER PRECAUTIONS: AVOID EXCESSIVE INHALATIONS. READ AND FOLLOW ALL LABEL DIRECTIONS AND CAUTIONS. EYEWASH FOUNTAINS SHOULD BE EASILY ACCESSIBLE. ------SECTION 9 ENVIRONMENTAL DATA -----ENVIRONMENTAL TOXICITY DATA: NA SPILL OR LEAK PROCEDURES: LEAKING CONTAINERS SHOULD BE PLACED IN AN OPENED CONTAINER, OUTDOORS, AWAY FROM SOURCES OF IGNITION, UNTIL ALL PRESSURE IS RELEASED. HAZARDOUS SUBSTANCE SUPERFUND: NA WASTE DISPOSAL METHOD: BURY OR INCINERATE IN APPROVED DISPOSAL FACILITIES IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATION. Page 3 712828.txt CONTAINER DISPOSAL: EMPTY CONTAINERS & DRIED PRODUCT MAY BE DISPOSED OF AS NORMAL REFUSE. ------SECTION 10 SHIPPING DATA -----D.O.T. PROPER SHIPPING NAME: CONSUMER COMMODITY HAZARDOUS SUBSTANCE 49 CFR CERCLA: NA D.O.T. HAZARD CLASS: ORM-D D.O.T. LABELS REQUIRED: NONE D.O.T. PLACARDS REQUIRED: NONE POISON CONSTITUENT: NONE BILL OF LADING DESCRIPTION: CONSUMER COMMODITY ORM-D CC NO: NA UN/NA CODE: NONE ------SECTION 11 SUPPLIER INFORMATION -----THE INFORMATION CONTAINED HEREIN IS, TO THE BEST OF OUR KNOWLEDGE AND BELIEF, ACCURATE AND RELIABLE AS OF THE DATE OF ISSUED. WE DO NOT HOWEVER, WARRANT OR GUARANTEE THE ACCURACY OR RELIABILITY, NOR SHALL WE BE LIABLE FOR ANY LOSS OR DAMAGE ARISING OUT OF THE USE THEREOF. THE INFORMATION IS OFFERED FOR THE USER'S CONSIDERATION AND EXAMINATION, AND IT IS THE USER'S RESPONSIBILITY TO SATISFY HIMSELF THAT IT IS SUITABLE AND COMPLETE FOR HIS PARTICULAR USE. PREPARED BY: J. STATEN, TECHNICAL, SPECIALIST 6/21/94 / REFORMATTED: S. THOMAS 3/1/96 Page 4 PART I What is the material and what do I need to know in an emergency? 1. PRODUCT IDENTIFICATION TRADE NAME (AS LABELED): PRODUCT CODES: PRODUCT USE: SUPPLIER/MANUFACTURER'S NAME: ADDRESS: CHEMTREC EMERGENCY NO.: BUSINESS PHONE: DATE OF PREPARATION: HOMAX Waterbased ORANGEPEEL & SPLATTER Spray Texture 4091, 4092, 4192, 4091-06,4092-06, 4091-10-06 Patching Interior Texture HOMAX PRODUCTS, INC. 200 Westerly Rd. Bellingham, WA 98226 1-800-424-9300 (United States) 1-703-527-3887 (International Collect) 1-800-729-9029 Nov. 16, 2006 2. COMPOSITION and INFORMATION ON INGREDIENTS CHEMICAL NAME CAS # % w/w EXPOSURE LIMITS IN AIR ACGIH-TLV OSHA-PEL NIOSH-REL TWA mg/m3 STEL mg/m3 TWA mg/m3 STEL mg/m3 TWA mg/m3 STEL mg/m3 IDLH/OTHER mg/m3 Calcium Carbonate 1317-65-3 30 - 60 10 NE 15 * 5 ** NE 10 * 5 ** NE NE Dimethyl Ether (Propellant) 115-10-6 7 - 13 NE NE NE NE NE NE DFG MAK: IDLH: 1900 Peak: II (8) NA 20 NA 2* NE 1000 984 980 NE 980 1225 2,000 (10% LEL) Talc Isopropyl alcohol Silica Quartz 14807-96-6 1-5 67-63-0 3-7 492 14808-60-7 0.1-1 10 mg/m3 ** NE 0.05 * NE 50 % SiO2+2 The ingredients in the balance of this product do not contribute significant hazards beyond those described in this document. All pertinent health, safety and environmental information have been presented, per the requirements of the US Federal OSHA Hazard Communication Standard (29 CFR 1910.1200) and Canadian WHMIS. Water and ingredients present in concentrations of less than 1% (or less than 0.1% if carcinogens) 2 ** 0.05 R Balance NE NE = Not Established. See Section 16 for Definitions of Terms Used. NOTE (1): ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format. This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. NOTE (2):* Total dust; ** Respirable fraction; R = Measured as respirable fraction of the aerosol. NOTE (3): The component Nicron 403, is free of crystalline silica and asbestos; therefore, carcinogenicity does not apply. 3. HAZARD IDENTIFICATION HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06 page 1 of 9 EMERGENCY OVERVIEW: PHYISCAL DESCRIPTION: This product is a white colored aerosol with a slight ethereal odor. HEALTH HAZARD: This product is harmful if it is inhaled or swallowed. This product may cause severe irritation to the eyes or skin. If particulates of this product are inhaled, severe irritation of the respiratory system (i.e. lungs, nose, and throat), central nervous system, and gastrointestinal tract could occur. FIRE HAZARD: This product is a flammable liquid and vapor (aerosol), with its contents under pressure. HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER propellant has a flash point of - 42oF / -41oC. REACTIVITY HAZARD: Minimal Hazard; the product is normally stable under ordinary conditions of use and storage. ENVIRONMENTAL HAZARD: This product is does not normally present a significant hazard to aquatic or terrestrial life. SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The most significant route of occupational overexposure is contact with skin, eyes, and inhalation. The symptoms of overexposure to this product are as follows: INHALATION: If inhalation of product s mists or vapors occurs, severe respiratory system irritation or nervous system depression may develop. Nervous system depression is characterized by headache, dizziness, nausea, or possible unconsciousness. CONTACT WITH SKIN or EYES: Contact can cause severe eye or skin irritation. Symptoms of eye exposure may include redness, pain, burning sensation, and tearing. Prolonged skin contact may result in redness, irritation, and dermatitis. SKIN ABSORPTION: May cause irritation or burning sensation. INGESTION: Ingestion is not anticipated to be a significant route of occupational exposure. If the product is swallowed, severe irritation of the mouth, throat, and other tissues of the gastro-intestinal system may occur. Ingestion of large amounts may cause irritation, pain, vomiting, and diarrhea. INJECTION: Accidental injection of this product may cause mild irritation and swelling, in addition to the wound. Hazardous Materials Identification System (HMIS) Health 1* Flammability 4 Physical Hazard 1 Protective Equipment A See Section 16 for Definition of Ratings HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. ACUTE: Depending on the duration of contact, overexposures can severely irritate the eyes, skin, lungs, respiratory tract and nervous system. Symptoms of exposure generally alleviated when overexposure ends. CHRONIC: Long-term skin contact may result in dermatitis. TARGET ORGANS: Acute: Eyes, Skin, Lungs, CNS, and Respiratory tract. Chronic: Skin PART II What should I do if a hazardous situation occurs? 4. FIRST-AID MEASURES Victims of chemical exposure must be taken for medical attention if any adverse effects occur. Take a copy of label and MSDS to physician or health professional with victim. SKIN EXPOSURE: If this product contaminates the skin, immediately begin decontamination with running water. Remove exposed or contaminated clothing, taking care not to contaminate eyes. Victim must seek immediate medical attention if any adverse exposure symptoms develop. EYE EXPOSURE: If this product enters the eyes, open victim's eyes while under gently running water. Use sufficient force to open eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. Victim must seek medical attention. INHALATION: If this product is inhaled, blow nose and remove victim to fresh air. INGESTION: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION. DO NOT INDUCE VOMITING, unless directed by medical personnel. Have victim rinse mouth with water, if conscious. Never induce vomiting or give 4. FIRST-AID MEASURES - Continued a diluent (e.g., water) to someone who is unconscious, having convulsions, or unable to swallow. If contaminated individual is convulsing, maintain an open airway and obtain immediate medical attention. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing conditions of pulmonary, dermatitis, and conjunctivitis disorders. HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06 page 2 of 9 RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure. 5. FIRE-FIGHTING MEASURES 0 FLASH POINT: 30 F (-1.10C) 0 NFPA RATING 0 AUTOIGNITION TEMPERATURE: 662 F (350 C) (Dimethyl ether propellant) FLAMMABILITY FLAMMABLE LIMITS (in air by volume, %): 4 Lower: 3.4% (Dimethyl ether propellant) Upper: 27% (Dimethyl ether propellant) FIRE EXTINGUISHING MATERIALS: Use extinguishing material suitable to the surrounding fire. Water Fog: OK Foam: OK Halon: OK HEALTH 1 2 Carbon Dioxide: OK Dry Chemical: OK 0 1 REACTIVITY OTHER UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode due to build up of pressure from extreme heat or fire. Explosion Sensitivity to Mechanical Impact: Do not puncture. Explosion Sensitivity to Static Discharge: Primarily vapors. SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection. Structural firefighters must wear Self-Contained Breathing Apparatus and full protective equipment. Move containers from See Section 16 for fire area if it can be done without risk to personnel. Exercise caution; contaminated floors Definition of Ratings and surfaces can be sticky. If possible, prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive areas. 6. ACCIDENTAL RELEASE MEASURES SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by trained personnel using pre-planned procedures. Proper protective equipment should be used. In case of a spill, clear the affected area and protect people. Releases of this material may be sticky. If the product is dried, and dusts may be generated during clean-up, dampen material prior to clean-up to avoid airborne particulates. RESPONSE TO INCIDENTAL RELEASES: Small scale releases, such as 1 container of this product, can generally be handled by personnel who have received basic chemical safety training. Respond to incidental chemical releases by wearing gloves, goggles, and appropriate body protection and by following the instructions for use presented above. RESPONSE TO NON-INCIDENTAL RELEASES: Respond to non-incidental chemical releases of this product, such as the simultaneous puncturing of several containers, by clearing the impacted area and contacting appropriate emergency personnel. Clean up should only be done by qualified personnel. Responders should wear the level of protection appropriate to the type of chemical released, the volume of the material spilled, and the location where the incident has occurred. Minimum Personal Protective Equipment should be Level C: triple-gloves, chemical resistant apron, boots, and splash goggles and an Air-Purifying respirator with high-efficiency particulate filter. RESPONSE EQUIPMENT AND PROCEDURES: Wipe-away spilled paste with damp polypads or other suitable absorbent materials, or scrape carefully with plastic tools. Decontaminate the area thoroughly. Place all spill residues in a suitable container and seal. Dispose of in accordance with applicable U.S. Federal, State, or local procedures or appropriate standards of Canada (see Section 13, Disposal Considerations). PART III How can I prevent hazardous situations from occurring? 7. HANDLING and STORAGE WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash thoroughly after using this product. Do not eat or drink while using this material. Avoid generating dusts and particulates of this product. If sanding, use with adequate ventilation. Remove contaminated clothing immediately. HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06 page 3 of 9 Deleted: STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to use it safely. Open containers carefully on a stable surface. Empty containers may contain residual material; therefore, empty containers should be handled with care. Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store away from incompatible materials (see Section 10, Stability and Reactivity). Keep container tightly closed when not in use. Inspect all incoming containers before storage, to ensure containers are properly labeled and not damaged. PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in Section 6 (Accidental Release Measures). Make certain that application equipment is locked and tagged-out safely if necessary. Collect all rinsates and dispose of according to applicable U.S. Federal, State, or local procedures or appropriate Canadian standards. 8. EXPOSURE CONTROLS - PERSONAL PROTECTION VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained below the limits provided in Section 2 (Composition and Information on Ingredients). Ensure adequate ventilation is available when sanding. Ensure eyewash/safety shower stations are available near areas where this product is used. RESPIRATORY PROTECTION: None needed under normal conditions of use. Use a dust respirator for large jobs if dusts cannot otherwise be eliminated. EYE PROTECTION: For consumer use, wearing eye protection (such as splash goggles) is advisable. However, for specific industrial applications, enhanced eye protection may be necessary. Use approved safety goggles or safety glasses, as described in OSHA 29 CFR 1910.133. If necessary, refer to U.S. OSHA 29 CFR 1910.133, or appropriate Canadian standards. HAND PROTECTION: For consumer use, wearing protective gloves is recommended. For specific industrial applications, wear chemical impervious gloves (e.g., Neoprene, nitrile). If necessary, refer to U.S. OSHA 29 CFR 1910.138 or the appropriate standards of Canada. BODY PROTECTION: For consumer use, no specific body protection is normally needed. For specific industrial applications, body protection is not routinely necessary, but may be warranted if excessive dusts may be generated. Use body protection appropriate for task (e.g., Tyvek suit, rubber apron). If a hazard of injury to the feet exists due to falling objects, rolling objects, where objects may pierce the soles of the feet or where employee s feet may be exposed to electrical hazards, use foot protection, as described in U.S. OSHA 29 CFR 1910.136. HMIS PERSONAL PROTECTIVE EQUIPMENT RATING: Industrial Use situations: (A) Eye Protection. 9. PHYSICAL and CHEMICAL PROPERTIES RELATIVE VAPOR DENSITY (air = 1): Heavier than air EVAPORATION RATE (BuAc =1): Faster than n-butyl acetate SPECIFIC GRAVITY: 0.9 MELTING POINT: 32oF (0oC) SOLUBILITY IN WATER: Soluble in water BOILING POINT: -13 oF (10.5 oC) VAPOR PRESSURE, mm Hg @ 24°C: pH: NA ODOR THRESHOLD: NA COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): NA V.O.C.: < 60% MIR: < 1.20 APPEARANCE, ODOR AND COLOR: This product is a white colored aerosol with a slight ethereal odor HOW TO DETECT THIS SUBSTANCE (warning properties): The appearance and odor of this product may act as warning properties in the event of an accidental release. 10. STABILITY and REACTIVITY STABILITY: Stable under normal circumstances of use and handling. DECOMPOSITION PRODUCTS: Thermal decomposition of this product may generate dusts, irritating fumes, and toxic gases (e.g., carbon monoxide, carbon dioxide). MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: This product is not compatible strong oxidizing agents. HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06 page 4 of 9 HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: Avoid contact with incompatible chemicals and high temperatures. PART IV Is there any other useful information about this material? 11. TOXICOLOGICAL INFORMATION TOXICITY DATA: The following toxicology information is available for components greater than 1% in concentration. The following data are available for Dimethyl ether: Inhalation-Rat LC50: 308 g/m3 Inhalation-Mouse LC50: 386,000 ppm/30M Inhalation-Rat TCLo: 2 pph/6H/30W-I The following data are available for Isopropyl alcohol: Skin-Rabbit, adult 500 mg Mild irritation effects Eye effects-Rabbit, adult 16 mg Eye effects-Rabbit, adult 10 mg Moderate irritation effects Cytogenetic Analysis System-Saccharomyces cerevisiae 200 mmol/tube Cytogenetic Analysis System-Rat-Inhalation 1030 mg/m3/16W-I Oral-Rat TDLo:6480 mg/kg (male 26W pre):Reproductive effects Inhalation-Rat TCLo:10,000 ppm/7H (female 1-19D post):Teratogenic effects Oral-Man TDLo:14,432 mg/kg: Central nervous system effects, Cardiovascular effects, Pulmonary system effects Oral-Human TDLo:223 mg/kg: Central nervous system effects, Cardiovascular effects Oral-Man LDLo:5272 mg/kg AJCPAI 38,144,62 Oral-Human LDLo:3570 mg/kg: Central nervous system effects, Pulmonary system effects, Gastrointestinal tract effects Unreported-Man LDLo:2770 mg/kg Oral-Rat LD50:5045 mg/kg Inhalation-Rat LCLo:16,000 ppm/4H Intraperitoneal-Rat LD50:2735 mg/kg Intravenous-Rat LD50:1099 mg/kg Oral-Mouse LD50:3600 mg/kg Inhalation-Mouse LCLo:12,800 ppm/3H Intraperitoneal-Mouse LD50:4477 mg/kg Subcutaneous-Mouse LDLo:6000 mg/kg Intravenous-Mouse LD50:1509 mg/kg Oral-Dog, adult LD50:4797 mg/kg Intravenous-Dog, adult LDLo:5120 mg/kg Intravenous-Cat, adult LDLo:1963 mg/kg Oral-Rabbit, adult LD50:6410 mg/kg Skin-Rabbit, adult LD50:12,800 mg/kg The following data are available for Talc: Skin-Human 300 mg/3D-I Mild irritation effects Inhalation-Rat TCLo:11 mg/m3/1Y-I:Equivocal tumorigenic agent The following data are available for Calcium Carbonate, Vinyl Acrylic Copolymer, and Silica Quartz: None available SUSPECTED CANCER AGENT: The following table summarizes the carcinogenicity listing for the components of this product. NO indicates that the substance is not considered to be, or suspected to be, a carcinogen by the listed agency. IARC NTP ACGIH NIOSH OSHA CA PROP 65 Calcium Carbonate CHEMICAL NO NO NO NO NO NO Dimethyl Ether NO NO NO NO NO NO 3 NO A4 NO NO NO NO Talc Vinyl Acrylic Copolymer NO NO NO NO NO Isopropyl alcohol 3 NO NO NO NO NO Silica Quartz 1 Known Ca NO A2 YES Note: See section 16 for definition of ratings HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06 page 5 of 9 11. TOXICOLOGICAL INFORMATION - Continued IRRITANCY OF PRODUCT: This product can be severely irritating to contaminated tissue. SENSITIZATION TO THE PRODUCT: The components of this product are not reported to be sensitizers. TOXICOLOGICAL SYNERGISTIC PRODUCTS: None known. REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product and its components on the human reproductive system. Mutagenicity: This product is not expected to produce mutagenic effects in humans when used as instructed. Embryotoxicity: This product is not expected to produce embryotoxic effects in humans when used as instructed. Teratogenicity: This product is not reported to cause teratogenic effects in humans when used as instructed. Reproductive Toxicity: This product is not reported to cause reproductive effects in humans when used as instructed. A mutagen is a chemical that causes permanent changes to genetic material (DNA) such that the changes will propagate through generational lines. An embryotoxin is a chemical that causes damage to a developing embryo (i.e. within the first eight weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical that causes damage to a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is any substance that interferes in any way with the reproductive process. BIOLOGICAL EXPOSURES INDICES (BEIs): There is no BEI currently established for this substance. 12. ECOLOGICAL INFORMATION ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION. ENVIRONMENTAL STABILITY: The following environmental data is available for components of this product: The mineral components of this product are stable in the environment. EFFECT OF MATERIAL ON PLANTS or ANIMALS: This product is not anticipated to cause significant effects on terrestrial plants or animals if released in small, consumer-sized volumes. This product may be harmful to animal life if large volumes of it are released into the environment. Refer to Section 11 (Toxicological Information) for specific animal data. EFFECT OF CHEMICAL ON AQUATIC LIFE: This product is not anticipated to cause significant effects on aquatic plants or animals if released in small, consumer-sized volumes. This product may be harmful to contaminated aquatic life (especially if large volumes of it are released into an aquatic environment). The following aquatic toxicity data is available for components of this product: NONE 13. DISPOSAL CONSIDERATIONS PREPARING WASTES FOR DISPOSAL: Consumer Waste: Dispose of according to pertinent state and local household waste and requirements. Industrial Use: Waste disposal must be in accordance with appropriate U.S. Federal, State, and local regulations or with regulations of Canada. EPA WASTE NUMBER: Not applicable to wastes consisting only of this product; however, the specific RCRA codes depend on the exact nature of the discarded material. 14. TRANSPORTATION INFORMATION THIS PRODUCT IS HAZARDOUS PER 49 CFR 172.101, THE U.S. DEPARTMENT OF TRANSPORTATION. PROPER SHIPPING NAME: Aerosols HAZARD CLASS NUMBER and DESCRIPTION: 2.1(Flammable Gas) UN IDENTIFICATION NUMBER: UN1950 DOT LABEL(S) REQUIRED: Flammable Gas PACKAGING GROUP: N/A NORTH AMERICAN RESPONSE GUIDEBOOK NUMBER (2000): 126 MARINE POLLUTANT: No component is designated as a DOT Marine Pollutant. Consumer commodities (per 173.306 (h)): A limited quantity that conforms to the provisions of paragraph (a) (1), (a) (3), or (b) of this section and is a "consumer commodity" (per 49 CFR 171.8) can be renamed Consumer commodity and reclassified as an ORMD Material. Each package may not exceed 30 kg (66 pounds)gross weight. Reference 173.306 (a) (3): Limited quantities of compressed gases may be shipped when in a metal container for the sole purpose of expelling a nonpoisonous liquid, paste, or powder. 14. TRANSPORTATION INFORMATION - Continued TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: description applies to this product under the regulations of Transport Canada. HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06 page 6 of 9 The above-listed DOT basic 15. REGULATORY INFORMATION ADDITIONAL U.S. REGULATIONS: EPA REPORTING REQUIREMENTS: The following reporting requirements are applicable to components of this product: CHEMICAL SECTION 302 SECTION 304 SECTION 313 (40 CFR 355, Appendix A) (40 CFR Table 302.4) (40 CFR 372.65) Calcium Carbonate NO NO NO Dimethyl Ether NO NO NO Talc NO NO NO NO NO NO NO NO NO NO NO NO Isopropyl alcohol Vinyl Acrylic Copolymer Silica Quartz U.S. SARA SECTION 311/312 FOR PRODUCT: Acute health effects; chronic health effects. U.S. TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory. OTHER U.S. FEDERAL REGULATIONS: Not applicable. CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): WARNING: This product contains a chemical known to the State of California to cause cancer. ANSI LABELING (Z129.1): DANGER! HARMFUL OR FATAL IF SWALLOWED. EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPOR HARMFUL. CONTENTS UNDER PRESSURE. MAY EXPLODE IF HEATED. AFFECTS CENTRAL NERVOUS SYSTEM. CAUSES SEVERE EYE IRRITATION. CAUSES IRRITATION TO SKIN AND RESPIRATORY TRACT. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL. ANSI LABEL PRECAUTIONS: Keep away from heat, sparks and flame. Do not expose to heat or store at temperatures above 120oF. Close container after use. Avoid breathing dust, vapors or mist. Do not take internally. Avoid contact with skin and clothing. Wash thoroughly after handling. Avoid contact with eyes. ENVIRONMENTAL HAZARDS: Do not discharge effluent containing this product into streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. 15. REGULATORY INFORMATION - Continued ADDITIONAL CANADIAN REGULATIONS: CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are listed on the DSL Inventory. CANADIAN WHMIS SYMBOLS: A - Compressed gas B1 - Flammable and combustible material - Flammable gas B2 - Flammable and combustible material - Flammable liquid HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06 page 7 of 9 D2A - Poisonous and infectious material - Other effects - Very toxic D2B - Poisonous and infectious material - Other effects - Toxic This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION PREPARED BY: DATE OF PRINTING John R. Kordosh Homax Products, Inc. 4505 E. Industrial St., Ste. 1B Simi Valley, CA 93063 (805) 581-3555 December 5, 2006 HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06 page 8 of 9 DEFINITIONS OF TERMS A large number of abbreviations and acronyms appear on a MSDS. Some of these, which are commonly used, include the following: CAS #: This is the Chemical Abstract Service Number that uniquely identifies each compound. ACGIH - American Conference of Governmental Industrial Hygienists, a professional association which establishes exposure limits. TLV - Threshold Limit Value - an airborne concentration of a substance that represents conditions under which it is generally believed that nearly all workers may be repeatedly exposed without adverse effect. The duration must be considered, including the 8-hour Time Weighted Average (TWA), the 15minute Short Term Exposure Limit, and the instantaneous Ceiling Level (C). Skin absorption effects must also be considered. OSHA - U.S. Occupational Safety and Health Administration. PEL - Permissible Exposure Limit - This exposure value means exactly the same as a TLV, except that it is enforceable by OSHA. The OSHA Permissible Exposure Limits are based in the 1989 PELs and the June, 1993 Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 40191). Both the current PELs and the vacated PELs are indicated. The phrase, Vacated 1989 PEL, is placed next to the PEL that was vacated by Court Order. IDLH - Immediately Dangerous to Life and Health - This level represents a concentration from which one can escape within 30-minutes without suffering escape-preventing or permanent injury. The DFG - MAK is the Republic of Germany s Maximum Exposure Level, similar to the U.S. PEL. NIOSH is the National Institute of Occupational Safety and Health, which is the research arm of the U.S. Occupational Safety and Health Administration (OSHA). NIOSH issues exposure guidelines called Recommended Exposure Levels (RELs). When no exposure guidelines are established, an entry of NE is made for reference. HAZARD RATINGS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM: Health Hazard: 0 (minimal acute or chronic exposure hazard); 1 (slight acute or chronic exposure hazard); 2 (moderate acute or significant chronic exposure hazard); 3 (severe acute exposure hazard; onetime overexposure can cause permanent injury and may be fatal); 4 (extreme acute exposure hazard; onetime overexposure can be fatal). Flammability Hazard: 0 (minimal hazard); 1 (materials that require substantial pre-heating before burning); 2 (combustible liquid or solids; liquids with a flash point of 38-93 C [100-200 F]); 3 (Class IB and IC flammable liquids with flash points below 38 C [100 F]); 4 (Class IA flammable liquids with flash points below 23 C [73 F] and boiling points below 38 C [100 F]. Reactivity Hazard: 0 (normally stable); 1 (material that can become unstable at elevated temperatures or which can react slightly with water); 2 (materials that are unstable but do not detonate or which can react violently with water); 3 (materials that can detonate when initiated or which can react explosively with water); 4 (materials that can detonate at normal temperatures or pressures). NATIONAL FIRE PROTECTION ASSOCIATION: Health Hazard: 0 (material that on exposure under fire conditions would offer no hazard beyond that of ordinary combustible materials); 1 (materials that on exposure under fire conditions could cause irritation or minor residual injury); 2 (materials that on intense or continued exposure under fire conditions could cause temporary incapacitation or possible residual injury); 3 (materials that can on short exposure could cause serious temporary or residual injury); 4 (materials that under very short exposure could cause death or major residual injury). Flammability Hazard and Reactivity Hazard: Refer to definitions for Hazardous Materials Identification System . FLAMMABILITY LIMITS IN AIR: Much of the information related to fire and explosion is derived from the National Fire Protection Association (NFPA). Flash Point - Minimum temperature at which a liquid gives off sufficient vapors to form an ignitable mixture with air. Autoignition Temperature: The minimum temperature required to initiate combustion in air with no other source of ignition. LEL - the lowest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. UEL - the highest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. TOXICOLOGICAL INFORMATION: Possible health hazards as derived from human data, animal studies, or from the results of studies with similar compounds are presented. Definitions of some terms used in this section are: LD50 - Lethal Dose (solids & liquids) which kills 50% of the exposed animals; LC50 - Lethal Concentration (gases) which kills 50% of the exposed animals; ppm concentration expressed in parts of material per million parts of air or water; mg/m3 concentration expressed in weight of substance per volume of air; mg/kg quantity of material, by weight, administered to a test subject, based on their body weight in kg. Other measures of toxicity include TDLo, the lowest dose to cause a symptom and TCLo the lowest concentration to cause a symptom; TDo, LDLo, LDo, TC, TCo, LCLo, and LCo, the lowest dose (or concentration) to cause lethal or toxic effects. BEI - Biological Exposure Indices, represent the levels of determinants which are most likely to be observed in specimens collected from a healthy worker who has been exposed to chemicals to the same extent as a worker with inhalation exposure to the TLV. Ecological Information: EC is the effect concentration in water. Data from several sources are used to evaluate the cancer-causing potential of the material. The sources and ratings are: IARC - the International Agency for Research on Cancer; 1 = Carcinogenic to humans, 2A, 2B = Probably carcinogenic to humans, 3 = Unclassifiable as to carcinogenicity in humans, and 4 = Probably not carcinogenic to humans. NTP - the National Toxicology Program; K =Known to be a human carcinogen, and R = Reasonably anticipated to be a human carcinogen. RTECS - the Registry of Toxic Effects of Chemical Substances. OSHA - Occupational Safety and Health Administration and CAL/OSHA - California s subunit of the Occupational Safety and Health Administration; Ca = Carcinogen defined with no further categorization. ACGIH American Conference of Governmental Industrial Hygienists; A1 = Confirmed human carcinogen, A2 = Suspected human carcinogen, A3 = Confirmed animal carcinogen with unknown relevance to humans, A4 = Not classifiable as a human carcinogen, and A5 = Not suspected as a human carcinogen. NIOSH U.S. National Institute for Occupational Safety and Health; Ca = Potential occupational carcinogen, with no further categorization. EPA U.S. Environmental Protection; A = Human carcinogen, B = Probable human carcinogen, C = Possible human carcinogen, D = Not classifiable as to human carcinogenicity, E = Evidence of Non-carcinogenicity for humans, K = Known human carcinogen, L = Likely to produce cancer in humans, CBD = Cannot be determined, NL = Not likely to be carcinogenic in humans, and I = Data are inadequate for an assessment of human carcinogenic potential. REGULATORY INFORMATION: This section explains the impact of various laws and regulations on the material. EPA is the U.S. Environmental Protection Agency. WHMIS is the Canadian Workplace Hazardous Materials Information System. DOT and TC are the U.S. Department of Transportation and the Transport Canada, respectively. Superfund Amendments and Reauthorization Act (SARA); the Canadian Domestic/Non-Domestic Substances List (DSL/NDSL); the U.S. Toxic Substance Control Act (TSCA); Marine Pollutant status according to the DOT; the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA or Superfund); and various state regulations. This section also includes information on the precautionary warnings that appear on a material s industrial package label. HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06 page 9 of 9 This document was created with Win2PDF available at http://www.daneprairie.com. The unregistered version of Win2PDF is for evaluation or non-commercial use only. PART I What is the material and what do I need to know in an emergency? TRADE NAME (AS LABELED): PRODUCT CODES: PRODUCT USE: SUPPLIER/MANUFACTURER'S NAME: ADDRESS: BUSINESS PHONE: CHEMTREC EMERGENCY NO.: BUSINESS PHONE: DATE OF PREPARATION: 1. PRODUCT IDENTIFICATION HOMAX EASY TOUCH COARSE ACOUSTIC TEXTURE 4070 Texture Patch HOMAX PRODUCTS, INC. 468 W. Horton Road Bellingham, WA 98226 1 800 729 9029 1-800-424-9300 (United States) 1-703-527-3887 (International Collect) 1-800-729-9029 April 20, 2004 This product is sold to consumers for household use in containers of relatively small volume (i.e. 5 gallon or less in size). This MSDS has been developed to address safety concerns affecting those individuals working in warehouses and other places where large numbers of these containers are stored, as well as those affecting potential users of this product in industrial /occupational settings. All pertinent health, safety and environmental information have been presented in this document, per the requirements of the US Federal OSHA Hazard Communication Standard (29 CFR 1910.1200) and Canadian WHMIS. 2. COMPOSITION and INFORMATION ON INGREDIENTS CHEMICAL NAME CAS # % w/w EXPOSURE LIMITS IN AIR ACGIH-TLV OSHA-PEL NIOSH-REL TWA mg/m3 STEL mg/m3 TWA mg/m3 STEL mg/m3 TWA mg/m3 STEL mg/m3 IDLH mg/m3 Calcium carbonate 1317-65-3 15 40 10 NE 15 * 5 ** NE 10 * 5 ** NE NE Aluminum silicate 1322-58-7 7 13 2 ** NE 15 * 5 ** NE NE 3000 Silica, crystalline 14808-60-7 1 5 0.05 ** NE NE 50 Starch 9005-84-9 1 5 10 NE 10 mg/m3 % SiO2+2 15 * NE 5 ** 10 * 5 ** 0.05 ** 10 * 5 ** NE NE Attapulgite 12174-11-7 1-5 NE NE NE NE NE Water and ingredients present in concentrations of less than 1% (or less than 0.1% if carcinogens) Balance NE NE The ingredients in the balance of this product do not contribute significant hazards beyond those described in this document. All pertinent health, safety and environmental information has been presented, per the requirements of the US Federal OSHA Hazard Communication Standard (29 CFR 1910.1200) and Canadian WHMIS. NE = Not Established; * Total dust; ** Respirable fraction. See Section 16 for Definitions of Terms Used. NOTE (1): ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format. This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. HOMAX EASY TOUCH COARSE ACOUSTIC TEXTURE Product ID#:4070, Revision Date: April 20, 2004 page 1 of 8 3. HAZARD IDENTIFICATION EMERGENCY OVERVIEW: PHYISCAL DESCRIPTION: This product is an odorless white aerosol texture. HEALTH HAZARD: This product can cause irritation to the eyes or skin. This product is harmful if swallowed or inhaled. If vapors, mists or particulates of this product are inhaled, irritation of the nose or throat could occur. FIRE HAZARD: This product is non-combustible. REACTIVITY HAZARD: This product is stable under ordinary conditions of use and storage. ENVIRONMENTAL HAZARD: This product does not normally present a significant hazard to aquatic or terrestrial life in consumer quantities. SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The most significant route of occupational overexposure is contact with skin and eyes. The symptoms of overexposure to this product are as follows: INHALATION: Vapors, mists, sprays, or dusts of this product can cause irritation to the respiratory tract. Dusts from this product can contain small amounts of crystalline Silica, a recognized carcinogen. Exposure to high concentrations of crystalline Silica can also cause silicosis. CONTACT WITH SKIN or EYES: Contact can cause eye or skin irritation. Prolonged skin contact can result in dermatitis. Prolonged eye exposure may include redness, pain, and tearing. SKIN ABSORPTION: No component of this product is reported to be absorbed through intact skin. INGESTION: If the product is swallowed, irritation of the mouth, throat, and other tissues of the gastro-intestinal system can occur. Ingestion of large amounts can cause irritation, pain, vomiting, and diarrhea. INJECTION: Accidental injection of this product can cause burning, reddening, and swelling in addition to the wound. Symptoms of such exposure can include those described under Inhalation , Contact with Skin or Eyes, and Ingestion . Hazardous Materials Identification System (HMIS) Health 2* Flammability 0 Physical Hazard 1 Protective Equipment B See Section 16 for Definition of Ratings HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. ACUTE: Depending on the duration of contact, overexposures can irritate the eyes, skin, mucous membranes, and other exposed tissue. CHRONIC: Long-term skin or eye contact can result in dermatitis or eye irritation. TARGET ORGANS: Acute: Eyes, respiratory system and skin. Chronic: Eyes and skin. PART II What should I do if a hazardous situation occurs? 4. FIRST-AID MEASURES Victims of chemical exposure must be taken for medical attention if any adverse effects occur. Take a copy of label and MSDS to physician or health professional with victim. SKIN EXPOSURE: If this product contaminates the skin, immediately begin decontamination with running water. Remove exposed or contaminated clothing, taking care not to contaminate eyes. Victim must seek immediate medical attention if any adverse exposure symptoms develop. EYE EXPOSURE: If this product enters the eyes, open victim's eyes while under gently running water. Use sufficient force to open eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. Victim must seek medical attention. 4. FIRST-AID MEASURES - Continued INHALATION: If vapors, mists, or sprays of this product are inhaled, remove victim to fresh air. Victim must seek immediate medical attention if any adverse exposure symptoms develop. If necessary, use artificial respiration to support vital functions. HOMAX EASY TOUCH COARSE ACOUSTIC TEXTURE Product ID#:4070, Revision Date: April 20, 2004 page 2 of 8 INGESTION: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION. DO NOT INDUCE VOMITING, unless directed by medical personnel. Have victim rinse mouth with water, if conscious. Never induce vomiting or give a diluent (e.g., water) to someone who is unconscious, having convulsions, or unable to swallow. If contaminated individual is convulsing, maintain an open airway and obtain immediate medical attention. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Persons with pre-existing skin disorders, eye problems, impaired liver, kidney, respiratory or lymphoid system function can be more susceptible to health effects associated with overexposures to this product. RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure. 5. FIRE-FIGHTING MEASURES FLASH POINT: Not applicable. AUTOIGNITION TEMPERATURE: Not applicable. FLAMMABLE LIMITS (in air by volume, %): NFPA RATING Lower: Not applicable. Upper: Not applicable. FLAMMABILITY FIRE EXTINGUISHING MATERIALS: surrounding fire. Water Spray: OK. Foam: OK Halon: OK Use extinguishing material suitable to the Carbon Dioxide: OK Dry Chemical: OK Other: Any ABC Class. 0 HEALT H UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode due to build up of pressure from extreme heat or fire. When involved in a fire, this material may decompose and, generating dusts, irritating fumes and toxic gases (e.g., Carbon monoxide and Carbon dioxide). 2 0 REACTIVIT Y OTHER See Section 16 for definitions of ratings Explosion Sensitivity to Mechanical Impact: Not sensitive under normal conditions. Explosion Sensitivity to Static Discharge: Not sensitive under normal conditions. SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection. Structural firefighters must wear Self-Contained Breathing Apparatus and full protective equipment. Move containers from fire area if it can be done without risk to personnel. If possible, prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive areas. 6. ACCIDENTAL RELEASE MEASURES SPILL AND LEAK RESPONSE: Trained personnel using pre-planned procedures should respond to uncontrolled releases. Proper protective equipment should be used. In case of a spill, clear the affected area and protect people. RESPONSE TO INCIDENTAL RELEASES: Personnel who have received basic chemical safety training can generally handle smallscale releases, such as 1 container of this product. Respond to incidental chemical releases by wearing gloves, goggles, and appropriate body protection. RESPONSE TO NON-INCIDENTAL RELEASES: Respond to non-incidental chemical releases of this product, such as the simultaneous puncturing of several containers, by clearing the impacted area and contacting appropriate emergency personnel. Clean up should only be done by qualified personnel. Responders should wear the level of protection appropriate to the type of chemical released, the volume of the material spilled, and the location where the incident has occurred. Minimum Personal Protective Equipment should be Level B: triple-gloves, chemical resistant apron, boots, and splash goggles and Self-Contained Breathing Apparatus. Level B should also be used when oxygen levels are below 19.5% or are unknown. RESPONSE EQUIPMENT AND PROCEDURES: Absorb spilled liquid with polypads or other suitable absorbent materials. Decontaminate the area thoroughly. Prevent spill rinsate from contamination of storm drains, sewers, soil or groundwater. Place all spill residues in a suitable container and seal. Dispose of in accordance with applicable U.S. Federal, State, or local procedures or appropriate standards of Canada (see Section 13, Disposal Considerations). HOMAX EASY TOUCH COARSE ACOUSTIC TEXTURE Product ID#:4070, Revision Date: April 20, 2004 page 3 of 8 PART III How can I prevent hazardous situations from occurring? 7. HANDLING and STORAGE WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash thoroughly after using this product. Do not eat or drink while using this material. Avoid generating dusts, mists or sprays of this product. Remove contaminated clothing immediately. STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to use it safely. Open containers carefully on a stable surface. Empty containers can contain residual material; therefore, empty containers should be handled with care. Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store away from incompatible materials (see Section 10, Stability and Reactivity). Keep container tightly closed when not in use. Inspect all incoming containers before storage, to ensure containers are properly labeled and not damaged. PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in Section 6 (Accidental Release Measures). Make certain that application equipment is locked and tagged-out safely if necessary. Collect all rinsates and dispose of according to applicable U.S. Federal, State, or local procedures or appropriate Canadian standards. 8. EXPOSURE CONTROLS - PERSONAL PROTECTION VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained below the limits provided in Section 2 (Composition and Information on Ingredients). RESPIRATORY PROTECTION: None needed under normal conditions of use. Use NIOSH approved respirators if ventilation is inadequate to control dusts, mists, fumes or vapors. Maintain airborne contaminate concentrations below guidelines listed in Section 2 (Composition and Information on Ingredients). Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres use of a full-face-piece pressure/demand SCBA or a full face-piece, supplied air respirator with auxiliary self-contained air supply is required under OSHA s Respiratory Protection Standard (29 CFR 1910.134). EYE PROTECTION: For consumer use, wearing eye protection (such as splash goggles) is advisable. However, for specific industrial applications, enhanced eye protection can be necessary. Use approved safety goggles or safety glasses, as described in OSHA 29 CFR 1910.133. If necessary, refer to U.S. OSHA 29 CFR 1910.133, or appropriate Canadian standards. HAND PROTECTION: For consumer use, wearing protective gloves is recommended. For specific industrial applications, wear chemical impervious gloves (e.g., Neoprene or Nitrile). If necessary, refer to U.S. OSHA 29 CFR 1910.138 or the appropriate standards of Canada. BODY PROTECTION: For consumer use, no specific body protection is normally needed. For specific industrial applications, body protection is not normally needed. Use body protection appropriate for task (e.g., Tyvek suit, rubber apron). If a hazard of injury to the feet exists due to falling objects, rolling objects, where objects can pierce the soles of the feet or where employee s feet can be exposed to electrical hazards, use foot protection, as described in U.S. OSHA 29 CFR 1910.136. HMIS PERSONAL PROTECTIVE EQUIPMENT RATING: Industrial Use situations: B; Safety glasses and gloves. 9. PHYSICAL and CHEMICAL PROPERTIES RELATIVE VAPOR DENSITY (air = 1): Heavier than air. EVAPORATION RATE (BuAc =1): Not applicable. SPECIFIC GRAVITY: Not applicable. MELTING/FREEZING POINT: Not applicable. SOLUBILITY IN WATER: Appreciable. BOILING POINT: Not applicable. VAPOR PRESSURE, mm Hg @ 24°C: Not applicable. pH: Not applicable. ODOR THRESHOLD: Not applicable. COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not applicable. Weight % V.O.C.: 0.2% APPEARANCE, ODOR AND COLOR: This product is an odorless white aerosol texture. HOW TO DETECT THIS SUBSTANCE (warning properties): The appearance of this product may act as warning properties in the event of an accidental release. HOMAX EASY TOUCH COARSE ACOUSTIC TEXTURE Product ID#:4070, Revision Date: April 20, 2004 page 4 of 8 10. STABILITY and REACTIVITY STABILITY: Stable under normal circumstances of use and handling. DECOMPOSITION PRODUCTS: Thermal decomposition of this product may generate dusts, irritating fumes, and toxic gases (e.g., Carbon monoxide and Carbon dioxide). MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: This product is not compatible with acids, strong oxidizing agents and ammonia. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: Avoid contact with incompatible chemicals, high temperature/humidity, ignition sources, and vapor buildup. PART IV Is there any other useful information about this material? 11. TOXICOLOGICAL INFORMATION TOXICITY DATA: There are currently no toxicity data available for this product; the following toxicology information is available for components greater than 1% in concentration. The following data are available for Attapulgite: Inhalation-Rat TCLo:10 mg/m3/6H/13W-I:Equivocal tumorigenic agent Intraperitoneal-Rat TDLo:338 mg/kg/2W-I:Neoplastic effects Implant-Rat TDLo:200 mg/kg:Equivocal tumorigenic agent The following data are available for Limestone: Oral - Rat: LD50: 6450 mg/kg The following data are available for Starch: Skin-Human 300 mg/3D-I Mild irritation effects Intraperitoneal-Mouse LD50:6600 mg/kg SUSPECTED CANCER AGENT: The following table summarizes the carcinogenicity listing for the components of this product. NO indicates that the substance is not considered to be, or suspected to be, a carcinogen by the listed agency. CHEMICAL IARC NTP NIOSH OSHA ACGIH PROP 65 Starch NO NO NO NO NO NO Calcium carbonate NO NO NO NO NO NO Aluminum silicate 3 NO NO NO A4 NO Silica, crystalline 1 K Ca NO A2 YES 2B (>5 m) NO NO NO NO YES (>5 m) Attapulgite 3 (< 5 m) IRRITANCY OF PRODUCT: This product can be irritating to contaminated tissue. Prolonged exposure can lead to tissue damage.SENSITIZATION TO THE PRODUCT: Starch dust, a component of this product, may be an allergen. TOXICOLOGICAL SYNERGISTIC PRODUCTS: None. HOMAX EASY TOUCH COARSE ACOUSTIC TEXTURE Product ID#:4070, Revision Date: April 20, 2004 page 5 of 8 11. TOXICOLOGICAL INFORMATION Continued REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product and its components on the human reproductive system. Mutagenicity: When used as directed, this product is not expected to produce mutagenic effects in humans. Embryotoxicity: When used as directed, this product is not expected to produce embryotoxic effects in humans. Teratogenicity: When used as directed, this product is not expected to produce teratogenic effects in humans. Reproductive Toxicity: When used as directed, this product is not expected to produce reproductive toxicity in humans. A mutagen is a chemical that causes permanent changes to genetic material (DNA) such that the changes will propagate through generational lines. An embryotoxin is a chemical that causes damage to a developing embryo (i.e. within the first eight weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical that causes damage to a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is any substance that interferes in any way with the reproductive process. BIOLOGICAL EXPOSURES INDICES (BEIs): There are no BEI s established for any component of this product at this time. 12. ECOLOGICAL INFORMATION ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION. ENVIRONMENTAL STABILITY: There is no environmental data for any component of this product at this time. EFFECT OF MATERIAL ON PLANTS or ANIMALS: This product can be harmful to terrestrial plant and animal life if large volumes of it are released into the environment. Refer to Section 11, Toxicological Information , for specific animal data. EFFECT OF CHEMICAL ON AQUATIC LIFE: This product can be harmful to animal life if large volumes of it are released into an aquatic environment. There is no aquatic toxicity for any component of this product at this time. 13. DISPOSAL CONSIDERATIONS PREPARING WASTES FOR DISPOSAL: Consumer Waste: Dispose of according to pertinent state and local household waste and requirements. Industrial Use: Waste disposal must be in accordance with appropriate U.S. Federal, State, and local regulations or with regulations of Canada. EPA WASTE NUMBER: Not applicable to wastes consisting only of this product; however, the specific RCRA codes depend on the exact nature of the discarded material. 14. TRANSPORTATION INFORMATION THIS PRODUCT IS HAZARDOUS PER 49 CFR 172.101, THE U.S. DEPARTMENT OF TRANSPORTATION. Aerosols PROPER SHIPPING NAME: HAZARD CLASS NUMBER and DESCRIPTION: 2.2 (Non-Flammable) UN 1950 UN IDENTIFICATION NUMBER: Non-Flammable Gas DOT LABEL(S) REQUIRED: Not applicable. PACKAGING GROUP: NORTH AMERICAN RESPONSE GUIDEBOOK NUMBER (2000): 126 MARINE POLLUTANT: No component is designated as a DOT Marine Pollutant. TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: description applies to this product under the regulations of Transport Canada. The above-listed DOT basic HOMAX EASY TOUCH COARSE ACOUSTIC TEXTURE Product ID#:4070, Revision Date: April 20, 2004 page 6 of 8 15. REGULATORY INFORMATION ADDITIONAL U.S. REGULATIONS: EPA REPORTING REQUIREMENTS: The following reporting requirements are applicable to components of this product: CHEMICAL SECTION 302 SECTION 304 SECTION 313 (40 CFR 355, Appendix A) (40 CFR Table 302.4) (40 CFR 372.65) Starch NO NO NO Calcium carbonate NO NO NO Aluminum silicate NO NO NO Silica, crystalline NO NO NO Attapulgite NO NO NO U.S. SARA SECTION 311/312 FOR PRODUCT: Acute health effects; chronic health effects. U.S. TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory. OTHER U.S. FEDERAL REGULATIONS: Not applicable. CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): WARNING: This product contains a chemical known to the State of California to cause cancer. ANSI LABELING (Z129.1): CAUTION! DUST AND VAPOR HARMFUL IF INHALED. MAY CAUSE SKIN, EYE AND LUNG IRRITATION. WARNING CONTENTS UNDER PRESSURE. ANSI LABEL PRECAUTIONS: Use with adequate ventilation, open windows and doors if using inside. Avoid breathing dust or vapors. Avoid contact with skin, eyes and clothing. Use safety glasses and gloves. Wash thoroughly after handling. Do not puncture or incinerate container. Do not expose to heat or store at temperatures above 120 F. ENVIRONMENTAL HAZARDS: Do not discharge effluent containing this product into streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. ADDITIONAL CANADIAN REGULATIONS: CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are listed on the DSL Inventory. CANADIAN WHMIS SYMBOLS: A - Compressed gas D2B - Poisonous and infectious material - Other effects - Toxic This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION PREPARED BY: DATE OF PRINTING ADVANCED CHEMICAL SAFETY, Inc. 7563 Convoy Court San Diego, CA 92111 (858)-874-5577 September 8, 2004 HOMAX EASY TOUCH COARSE ACOUSTIC TEXTURE Product ID#:4070, Revision Date: April 20, 2004 page 7 of 8 DEFINITIONS OF TERMS A large number of abbreviations and acronyms appear on a MSDS. Some of these, which are commonly used, include the following: CAS #: This is the Chemical Abstract Service Number that uniquely identifies each compound. ACGIH - American Conference of Governmental Industrial Hygienists, a professional association which establishes exposure limits. TLV - Threshold Limit Value - an airborne concentration of a substance that represents conditions under which it is generally believed that nearly all workers may be repeatedly exposed without adverse effect. The duration must be considered, including the 8-hour Time Weighted Average (TWA), the 15minute Short Term Exposure Limit, and the instantaneous Ceiling Level (C). Skin absorption effects must also be considered. OSHA - U.S. Occupational Safety and Health Administration. PEL - Permissible Exposure Limit - This exposure value means exactly the same as a TLV, except that it is enforceable by OSHA. The OSHA Permissible Exposure Limits are based in the 1989 PELs and the June, 1993 Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 40191). Both the current PELs and the vacated PELs are indicated. The phrase, Vacated 1989 PEL, is placed next to the PEL that was vacated by Court Order. IDLH - Immediately Dangerous to Life and Health - This level represents a concentration from which one can escape within 30-minutes without suffering escape-preventing or permanent injury. The DFG - MAK is the Republic of Germany s Maximum Exposure Level, similar to the U.S. PEL. NIOSH is the National Institute of Occupational Safety and Health, which is the research arm of the U.S. Occupational Safety and Health Administration (OSHA). NIOSH issues exposure guidelines called Recommended Exposure Levels (RELs). When no exposure guidelines are established, an entry of NE is made for reference. HAZARD RATINGS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM: Health Hazard: 0 (minimal acute or chronic exposure hazard); 1 (slight acute or chronic exposure hazard); 2 (moderate acute or significant chronic exposure hazard); 3 (severe acute exposure hazard; onetime overexposure can cause permanent injury and may be fatal); 4 (extreme acute exposure hazard; onetime overexposure can be fatal). Flammability Hazard: 0 (minimal hazard); 1 (materials that require substantial pre-heating before burning); 2 (combustible liquid or solids; liquids with a flash point of 38-93 C [100-200 F]); 3 (Class IB and IC flammable liquids with flash points below 38 C [100 F]); 4 (Class IA flammable liquids with flash points below 23 C [73 F] and boiling points below 38 C [100 F]. Reactivity Hazard: 0 (normally stable); 1 (material that can become unstable at elevated temperatures or which can react slightly with water); 2 (materials that are unstable but do not detonate or which can react violently with water); 3 (materials that can detonate when initiated or which can react explosively with water); 4 (materials that can detonate at normal temperatures or pressures). NATIONAL FIRE PROTECTION ASSOCIATION: Health Hazard: 0 (material that on exposure under fire conditions would offer no hazard beyond that of ordinary combustible materials); 1 (materials that on exposure under fire conditions could cause irritation or minor residual injury); 2 (materials that on intense or continued exposure under fire conditions could cause temporary incapacitation or possible residual injury); 3 (materials that can on short exposure could cause serious temporary or residual injury); 4 (materials that under very short exposure could cause death or major residual injury). Refer to definitions for Flammability Hazard and Reactivity Hazard: Hazardous Materials Identification System . FLAMMABILITY LIMITS IN AIR: Much of the information related to fire and explosion is derived from the National Fire Protection Association (NFPA). Flash Point - Minimum temperature at which a liquid gives off sufficient vapors to form an ignitable mixture with air. Autoignition Temperature: The minimum temperature required to initiate combustion in air with no other source of ignition. LEL - the lowest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. UEL - the highest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. TOXICOLOGICAL INFORMATION: Possible health hazards as derived from human data, animal studies, or from the results of studies with similar compounds are presented. Definitions of some terms used in this section are: LD50 - Lethal Dose (solids & liquids) which kills 50% of the exposed animals; LC50 - Lethal Concentration (gases) which kills 50% of the exposed animals; ppm concentration expressed in parts of material per million parts of air or water; mg/m3 concentration expressed in weight of substance per volume of air; mg/kg quantity of material, by weight, administered to a test subject, based on their body weight in kg. Other measures of toxicity include TDLo, the lowest dose to cause a symptom and TCLo the lowest concentration to cause a symptom; TDo, LDLo, LDo, TC, TCo, LCLo, and LCo, the lowest dose (or concentration) to cause lethal or toxic effects. BEI - Biological Exposure Indices, represent the levels of determinants which are most likely to be observed in specimens collected from a healthy worker who has been exposed to chemicals to the same extent as a worker with inhalation exposure to the TLV. Ecological Information: EC is the effect concentration in water. Data from several sources are used to evaluate the cancer-causing potential of the material. The sources and ratings are: IARC - the International Agency for Research on Cancer; 1 = Carcinogenic to humans, 2A, 2B = Probably carcinogenic to humans, 3 = Unclassifiable as to carcinogenicity in humans, and 4 = Probably not carcinogenic to humans. NTP - the National Toxicology Program; K =Known to be a human carcinogen, and R = Reasonably anticipated to be a human carcinogen. RTECS - the Registry of Toxic Effects of Chemical Substances. OSHA - Occupational Safety and Health Administration and CAL/OSHA - California s subunit of the Occupational Safety and Health Administration; Ca = Carcinogen defined with no further categorization. ACGIH American Conference of Governmental Industrial Hygienists; A1 = Confirmed human carcinogen, A2 = Suspected human carcinogen, A3 = Confirmed animal carcinogen with unknown relevance to humans, A4 = Not classifiable as a human carcinogen, and A5 = Not suspected as a human U.S. National Institute for Occupational Safety and carcinogen. NIOSH Health; Ca = Potential occupational carcinogen, with no further categorization. EPA U.S. Environmental Protection; A = Human carcinogen, B = Probable human carcinogen, C = Possible human carcinogen, D = Not classifiable as to human carcinogenicity, E = Evidence of Non-carcinogenicity for humans, K = Known human carcinogen, L = Likely to produce cancer in humans, CBD = Cannot be determined, NL = Not likely to be carcinogenic in humans, and I = Data are inadequate for an assessment of human carcinogenic potential. REGULATORY INFORMATION: This section explains the impact of various laws and regulations on the material. EPA is the U.S. Environmental Protection Agency. WHMIS is the Canadian Workplace Hazardous Materials Information System. DOT and TC are the U.S. Department of Transportation and the Transport Canada, respectively. Superfund Amendments and Reauthorization Act (SARA); the Canadian Domestic/Non-Domestic Substances List (DSL/NDSL); the U.S. Toxic Substance Control Act (TSCA); Marine Pollutant status according to the DOT; the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA or Superfund); and various state regulations. This section also includes information on the precautionary warnings that appear on a material s industrial package label. HOMAX EASY TOUCH COARSE ACOUSTIC TEXTURE Product ID#:4070, Revision Date: April 20, 2004 page 8 of 8 This document was created with Win2PDF available at http://www.daneprairie.com. The unregistered version of Win2PDF is for evaluation or non-commercial use only. 1 PRODUCT TRADE NAME: HAZARDOUS MATERIAL INFORMATION SYSTEM HOMAX PRODUCTS, INC. EASY TOUCH KNOCKDOWN HEALTH 2 FLAMMABILITY 0 REACTIVITY 0 PROTECTIVE EQUIPMENT A ITEM #4060, 4065,4165 (HAZARD RATING: 0=LEAST, 1=SLIGHT, 2=MODERATE, 3=HIGH, 4=EXTREME) (A=SAFETY GLASSES) SECTION I MANUFACTURER'S NAME: HOMAX PRODUCTS, INC. 840 WEST HORTON ROAD BELLINGHAM WA 98226 24 HOUR EMERGENCY PHONE NUMBER: CHEMTREC 1-800-424-9300 FORMATION PHONE NUMBER: 1-800-729-9029 DATE OF PREPARATION: SECTION II - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION CAS NUMBER DESCRIPTION PEL TLV 04/22/03 % 14807-96-6 107-21-1 TALC ETHYLENE GLYCOL 20 MPPCH\F 50PPM 2MG/M 50PPM 5-10% 1-5% 115-10-6 14807-96-6 DIMETHYL ETHER PROPELLA TALC N/A 20 MPPCH/F N/A 2MG/M 500PPM 5-10% THE DRIED FILM OF THIS PRODUCT MAY BECOME A DUST NUISANCE WHEN REMOVED BY SANDING OR GRINDING. OSHA RECOMMENDS A PEL/TWA OF 15 mg/m3 FOR TOTAL DUST AND 5mg/m3 FOR THE RESPIRABLE FRACTION. ACGIH RECOMMENDS A TLV/TWA OF 10mg/m3 FOR TOTAL DUST. SKIN ABSORPTION MAY CONTRIBUTE TO THE OVERALL EXPOSURE TO THIS MATERIAL. TAKE APPROPRIATE MEASURES TO PREVENT SKIN CONTACT. SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS APPEARANCE AND ODOR: GRAYISH-WHITE LIQUID WITH TYPICAL LATEX ODOR. BOILING POINT: N/E VAPOR PRESSURE: >1 WATER SOLUBILITY %: N/E VAPOR DENSITY (AIR = 1): >1 EVAPORATION RATE: <1 SPECIFIC GRAVITY (WATER = 1): 0.939 % VOLATILITY BY VOLUME: 59.74 N/E = NOT ESTABLISHED SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT (METHOD USED): N/E 2 LEL: FLAMMABLE LIMITS: UEL: EXTINGUISHING MEDIA: N/A N/E N/A USE WATER FOG, FOAM, DRY CHEMICAL OR CARBON DIOXIDE, ALCOHOL FOAM. LEVEL ONE AEROSOL UNIFORM FIRE CODE STANDARD 88-1 SPECIAL FIREFIGHTING PROCEDURES: FIREFIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS IF DUSTY CONDITIONS ARE PRESENT. USE WATER SPRAY TO COOL EXPOSED CONTAINTERS. IF POSSIBLE, LET BURN UNTIL SOURCE OF GAS IS SHUT OFF. SEVERE HAZARD WHEN EXPOSED TO HEAT OR FLAME. UNUSUAL FIRE AND EXPLOSION HAZARDS: CLOSED CONTAINERS MAY EXPLOSE DUE TO BUILD UP OF PRESSURE FROM EXTREME HEAT OF FIRE. MIXTURES WITH AIR ARE HIGHLY FLAMMABLE. SECTION V - REACTIVITY DATA STABILITY: MATERIAL IS STABLE. HAZARDOUS PLOYMERIZATION WILL NOT OCCUR. INCOMPATIBILITY (MATERIALS TO AVOID): BASED ON THE PRESENCE OF COMPONENET 2 AVOID OXIDIZING MATERIALS, AVOID ALKALIES, HIGH TEMPERATURE, KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. STRONG OXIDIZING AGENTS, OXYGEN, AVETIC ACID, ORGANIC ACID ANHYDRIDES. HAZARDOUS DECOMPOSITION PRODUCTS: CARBON DIOXIDE, CARBON MONOXIDE AND UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED BURING COMBUSTION. CONDITIONS TO AVOID: TEMPERATURES ABOVE 1500F. HYDROFLUORIC ACID. AVOID HIGH TEMPERATURE, IGNITION SOURCES. SECTION VI - HEALTH HAZARD DATA ROUTES OF ENTRY: INHALATION: YES SKIN: YES INGESTION: YES HEALTH HAZARDS (ACUTE AND CHRONIC): BASED ON THE PRESENCE OF COMPONENT 1 CHRONIC OVER EXPOSURE TO TALC DUST MAY CAUSE SCARRING OF THE LUNGS. BASED ON THE PRESENCE OF COMPONENT 2 PRODUCT IS PRESUMED TO BE AN ANIMAL TERATOGEN. EXPOSURE TO HIGH VAPOR CONCENTRATIONS MAY PRODUCE ANESTHETIC EFFECTS. EYE OR SKIN CONTACT WITH LIQUID MAY PRODUCE BURNS DUE TO THE FREEZING EFFECT. INHALATION: EXPOSURE MAY PRODUCE IRRITATION TO THE NOSE, THROAT, RESPIRATORY TRACT, AND OTHER MUCOUS MEMBRANES. BASED ON THE PRESENCE OF COMPONENT 2 EXPOSURE TO HIGH CONCENTRATIONS OF VAPOR MAY PRODUCE CENTRAL NERVOUS SYSTEM DEPRESSION. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENET MAY BE HARMFUL OR FATAL. EXPOSURE TO HIGH VAPOR CONCENTRATION MAY PRODUCE ANESTHETIC EFFECTS. INGESTION: BASED ON THE PRESENCE OF COMPONENT 2 PRODUCT IS PRESUMED TO BE MODERATELY TOXIC. BASED ON THE PRESENCE OF COMPONENT 2 INGESTION MAY CAUSE KIDNEY DAMAGE. BASED ON THE PRESENCE OF COMPONENT 2 INGESTION MAY CAUSE LUMBAR PAIN, OLIGURIA OR UREMIA. BASED ON THE PRESENCE OF COMPONENT 2 INGESTION MAY CAUSE CENTRAL NERVOUS SYSTEM DAMAGE. CARCINOGENICITY: NTP - NO IARC MONOGRAPHS - NO SIGNS AND SYMPTOMSOF EXPOSURE: OSHA REGULATED - NO 3 SYMPTOMS OR EYE IRRITATION INCLUDE PAIN, TEARING, REDDENING AND SWELLING. SYMPTOMS OF SKIN IRRITATION INCLUDE REDDENING, SWELLING, RASH AND REDNESS. SYMPTOMS OF RESPIRATORY IRRITATION INCLUDE RUNNY NOSE, SORE THROAT, COUGHING, CHEST DISCOMFORT, SHORTNESS OF BREATH, AND REDUCED LUNG FUNCTION. SYMPTOMS OF GASTROINTESTINAL IRRITATION INCLUDE SORE THROAT, ABDOMINAL PAIN, NAUSEA, VOMITING AND DIARRHEA. BASED ON THE PRESENCE OF COMPONENT 2 CENTRAL NERVOUS SYSTEM DEPRESSION MAY BE EVIDENCED BY HEADACHE, DIZZINESS, NAUSEA AND SYMPTOMS OF INTOXICATION; IN EXTREME CASES, UNCONSCIOUSNESS AND DEATH MAY OCCUR. SYMPTOMS OF CHRONIC OVEREXPOSURE INCLUDE LOSS OF MEMORY, LOSS OF INTELLECTUAL ABILITY AND LOSS OF COORDINATION. CONTACT WITH LIQUID MAY PRODUCE FREEZING EFFECTS. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: PREEXISTING EYE, SKIN OR REISPIRATORY DISORDERS MAY BE AGGREAVATED. IMPAIRED CENTRAL NERVOUS SYSTEM FUNCTIONS FROM PREEXISTING DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. EMERGENCY AND FIRST AID PROCEDURES: IF INHALED: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. GET IMMEDIATE MEDICAL ATTENTION. EYE CONTACT: IMMEDIATELY FLUSH EYES WITH LOTS OF RUNNING WATER FOR 15 MINUTES, LIFTING UPPER AND LOWER LIDS OCCASIONALLY. GET IMMEDIATE MEDICAL ATTENTION IF SYMPTOMS PERSIST. SKIN CONTACT: IMMEDIATELY WASH SKIN WITH LOTS OF SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES; WASH BEFORE REUSE. GET MEDICAL ATTENTION IF IRRITATION PERSISTS AFTER WASHING. INGESTION: DILUTE WITH TWO GLASSES OF WATER UNLESS THE VICTIM IS UNCONSCIOUS OR VERY DROWSY. INDUCE VOMITING BY GIVING TWO TABLESPOONS IPECAC OR BY TOUCHING A FINGER TO THE BACK OF THE VICTIM’S THROAT. KEEP THE VICTIM’S HEAD BELOW THE HIPS TO PREVENT ASPIRATION INTO THE LUNGS. CONSULT A PHYSICIAN, HOSPITAL OR POISON CONTROL CENTER AND / OR TRANSPORT TO AN EMERGENCY FACILITY IMMEDIATELY. NOTES TO PHYSICIAN: COMPONENT 2 ETHYLENE GLYCOL MAY CAUSE KIDNEY DAMAGE AND METABOLIC ACIDOSIS. ETHANOL IS ANTIDOTAL, AND ITS EARLY ADMINISTRATION MAY BLOCK THE FORMATION OF NEPHROTOXIC METABOLITES OF ETHYLENE GLYCOL IN THE LIVER. ETHANOL SHOULD BE GIVEN INTRAVENOUSLY, AS A 5% SOLUTION IN SODIUM BICARBONATE, AT A RATE OF ABOUT 10ml ETHANOL PER HOUR. A DESIRED THERAPEUTIC LEVEL OF ETHANOL IN BLOOD IS 100mg/dl. HEMODIALYSIS MAYBE REQUIRED. PULMONARY EDEMA WITH HYPOXEMIA HAS BEEN DESCRIBED IN A NUMBER OF PATIENTS FOLLOWING POISONING WITH ETHYLENE GLYCOL. THE MECHANISM OF PRODUCTION HAS NOT BEEN ELUCIDATED, BUT IT APPEARS TO BE NONCARDIOGENIC IN ORIGIN IN SEVERAL CASES. RESPIRATORY SUPPORT WITH MECHANICAL VENTILATION AND POSITIVE END-EXPIRATORY PRESSURE MAY BE REQUIRED. WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. SECTION VII – PRECAUTIONS FOR SAFE HANDLING AND USE STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: FOR LARGE SPILLS EVACUATE THE HAZARD AREA OF UNPROTECTED PERSONNEL. WEAR APPROPRIATE RESPIRATOR AND PROTECTIVE CLOTHING. SHUT OFF SOURCE OF LEAK ONLY IF SAFE TO DO SO. DIKE AND CONTAIN. IF VAPOR CLOUD FORMS, WATER FOG MAY BE USED TO SUPPRESS; CONTAIN RUN-OFF. REMOVE WITH VACUUM TRUCKS OR PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP RESIDUE WITH AN ABSORBENT SUCH AS CLAY, SAND OR OTHER SUITABLE MATERIAL; PLACE IN NONLEAKING CONTAINERS FOR PROPER DISPOSAL. FLUSH AREA WITH WATER TO REMOVE TRACE RESIDUE; DISPOSE OF FLUSH SOLUTIONS AS ABOVE. REMOVE ALL SOURCES OF IGNITION: SPARKS, 4 STATIC ELECTRICITY & ELECTRICAL. VENTILATE AREA. DISPERSE WITH WATER SPRAY. KEEP PERSONNEL UP-WIND. FOR SMALL SPILLS TAKE UP WITH AN ABSORBENT MATERIAL AND PLACE IN NONLEAKING CONTAINERS; SEAL TIGHTLY FOR PROPER DISPOSAL. WASTE DISPOSAL: DISPOSE OF CONTAMINATED PRODUCT AND MATERIALS USED IN CLEANING UP SPILLS AND LEAKS IN A MANNER APPROVED FOR THIS MATERIAL. CONSULT APPROPRIATE FEDERAL, STATE AND LOCAL REGULATORY AGENCIES TO ASCERTAIN PROPER PROCEDURES. BURN UNDER CONTROLLED CONDITIONS. DO NOT INCINERATE CLOSED CONTAINERS. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: STORE IN COOL, DRY PLACE. KEEP BAGS AND CONTAINERS DRY AT ALL TIMES. WASH THOROUGHLY AFTER HANDLING. DO NOT GET IN EYES, ON SKIN OR CLOTHING. DO NOT STORE ABOVE 120 DEG. F. DO NOT STORE NEAR HEAT, SPARKS OR FLAME. PROTECT FROM ALL SOURCES OF IGNITION. OTHER PRECAUTIONS: CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED, WILL RETAIN PRODUCT RESIDUE. ALWAYS OBEY HAZARD WARNINGS AND HANDLE EMPTY CONTAINERS AS IF THEY WERE FULL. DO NOT GET IN EYES, BREATHE VAPORS. AVOID SKIN CONTACT. DO NOT TAKE INTERNALLY. SMOKING WHEN USING THIS PRODUCT MUST BE STRICTLY PROHIBITED. SECTION VIII –CONTROL MEASURES RESPIRATORY PROTECTION: USE VENTILATION AS REQUIRED TO CONTROL VAPOR CONCENTRATIONS AT LEAST 10 AIR CHANGES PER HOUR AREA RECOMMENDED FOR GOOD GENERAL ROOM VENTILATION. IF EXPOSURE EXCEEDS THE PEL/TLV, USE A NIOSH-APPROVED DUST RESPIRATOR OR MASK PER REQUIREMENTS OF 29 CFR 1910.134. VENTILATION: USE LOCAL EXHAUST CAPABLE OF MINIMIZING VAPOR CONCENTRATIONS AT POINT OF USE. ALL APPLICATION AREAS SHOULD BE ADEQUATELY VENTILATED IN ORDER NOT TO EXCEED SECTION II COMPONENT TLV. PROTECTIVE GLOVES: USE NEOPRENE OR OTHER SOLVENT RESISTANT GLOVES TOPREVENT SKIN CONTACT. EYE PROTECTIONS: NIOSH-APPROVED DUST GOGGLES OR A SPLASH SHIELD SHOULD BE USED TO PREVENT SKIN CONTACT. CONTACT LENSES SHOULD NOT BE WORN. OTHER PROTECTIVE CLOTHING OR EQUIPMENT: LONG-SLEEVED SHIRT, TROUSERS AND SAFETY SHOES. FREEZING RESISTANT GLOVES ARE RECOMMENDED. WORK/HYGIENIC PRACTICES: AVOID SKIN OR EYE CONTACT. DO NOT BREATH VAPORS. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING, DRINKING OR SMOKING. AN EYEWASH AND SAFETY SHOWER SHOULD BE NEARBY AND READY FOR USE. SECTION IX- DISCLAIMER TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE, OBTAINED FROM SOURCES BELIEVED BY HOMAX PRODUCTS, INC. TO BE ACCURATE. SINCE THE CONDITIONS AND METHODS OF USE OF OUR PRODUCTS ARE BEYOND OUR CONTROL, WE DISCLAIM ANY AND ALL LIABILITY ARISING OUT OF THE IMPROPER USE OF THESE PRODUCTS OR THE INFORMATION PROVIDED HEREWITH. SHIPPING CLASSIFICATION: ORM-D HAZARDOUS MATERIAL DEFINED BY THE DOT. PROPER SHIPPING NAME: CONSUMER COMMODITY 1 PRODUCT TRADE NAME: HAZARDOUS MATERIAL INFORMATION SYSTEM HOMAX PRODUCTS, INC. EASY TOUCH SPRAY TEXTURE (R) HEALTH 2 FLAMMABILITY 4 REACTIVITY 0 PROTECTIVE EQUIPMENT J ITEM #4050, 4055, 4101, 4155 (HAZARD RATING: 0=LEAST, 1=SLIGHT, 2=MODERATE, 3=HIGH, 4=EXTREME) (J=SPLASH GOGGLES, GLOVES, SYNTHETIC APRON, DUST & VAPOR RESPIRATOR) SECTION I MANUFACTURER'S NAME: HOMAX PRODUCTS, INC. 468 W. HORTON RD. BELLINGHAM WA 98226 24 HOUR EMERGENCY PHONE NUMBER: CHEMTREC 1-800-424-9300 NFORMATION PHONE NUMBER: 1-800-729-9029 DATE OF PREPARATION: 03/05/03 SECTION IIA - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION CAS WEIGHT -OCCUPATIONAL EXPOSURE LIMITSVAPOR PRESS. NUMBER DESCRIPTION PERCENT OSHA PEL** AOGIH TLV OTHER mm HG TEMP 01330-20-7 00100-41-4 00071-13-2 64742-89-8 00074-98-6 00075-28-5 01330-20-7 13463-67-7 00067-64-1 XYLENE ETHYL BENZENE BENZENE PETROLEUM NAPTHA, ALKANES & NAPHTHENES PROPANE ISOBUTANE XYLENE TITANIUM DIOXIDE ACETONE 12 2.2 *Trace 8 100PPM 100PPM 100PPM 100PPM 434 mg/m3 434 mg/m3 NOT EST 300PPM 6 2 9 2 9 SIMPLE NOT EST 100PPM 10 mg/m3 750PPM ASPHIXIANT 800PPM 100PPM 10 mg/m3 750PPM 1000PPM (ESTIMATE) 434MG/M3 (DUST) 1780 mg/m3 25 10 77 77 80 70 3619 70 25 77 181 68 * Trace quantities less than 0.1% and greater than 0.005% **PELs represent lowered 1989 limits and may not be enforceable by Federal OSH SECTION IIB - OTHER REGULATORY INFORMATION CAS NUMBER 01330-20-7 00100-41-4 00071-13-2 64742-89-8 00074-98-6 00075-28-5 00108-88-3 DESCRIPTION XYLENE ETHYL BENZENE BENZENE PETROLEUM NAPTHA, ALKANES & NAPHTHENES PROPANE ISOBUTANE TOLUENE CARCINOGEN NTP IARC OSHA X SARA TITLE III 302 313 X X X X CALIFORNIA P65 I II X X X X X 2 13463-67-7 00087-84-1 TITANIUM DIOXIDE ACETONE SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS BOILING RANGE: -13 TO 2500 DEG F VAPOR DENSITY: HEAVIER THAN AIR CALCULATED V.O.C.: 3.95LB/GL(474GR/LT) SOLUBILITY IN WATER: NON-SOLUABLE APPEARANCE AND ODOR: OPAQUE LIQUID, PETROLEUM ODOR WT/GAL: 11.71 (WITH PROP: 8.85) EVAPORATION RATE: SAME AS (n-Butyl acetate=MEDIAN) SECTION IV - FIRE AND EXPLOSION HAZARD DATA OSHA FLAMMABILITY CLASS: FLAMMABLE LIQUID CLASS 1A UNIFORM FIRE CODE STANDARD 88-1 LEVEL 1 AEROSOL BULK FLASH POINT: -4 DEG F METHOD USED: P-MARTEN BULK PROPELLANT FLASH POINT: -158 DEG F PACKAGED PRODUCT FLAME EXTENSION: 28 FLAMMABLE LIMITS IN AIR BY VOLUME: LOWER: 1.0% UPPER: 12.8% EXTINGUISHING MEDIA: FOAM, CO2, DRY CHEMICAL, WATER FOG DOT/CERCLA: THE DOT/CERCLA REPORTABLE QUANTITY (RQ) FOR THIS PRODUCT IS 1004 GALLONS BASED ON XYLENE RQ 1000 LBS. SPECIAL FIREFIGHTING PROCEDURES: EVACUATE ALL UNNECESSARY PERSONNEL. USE FULL PROTECTIVE EQUIPMENT, INCLUDING SELFCONTAINED BREATHING APPARATUS. USE WATER SPRAY, PREFERABLY FOG, TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP AND POSSIBLE EXPLOSION. DO NOT ALLOW PRODUCT OR RUNOFF FROM FIRE CONTROL TO ENTER STORM OR SANITARY SEWERS, LAKES, RIVERS, STREAMS, OR WATERWAYS. UNUSUAL FIRE AND EXPLOSION HAZARDS: EXPLOSIVE AIR-VAPOR MIXTURES MAY FORM WHICH ARE DANGEROUS WHEN EXPOSED TO HEAT OR FLAME. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL ALONG THE GROUND, OR BE MOVED BY VENTILATION, AND IGNITED BY PILOT LIGHTS, STOVES, HEATERS, ELECTRIC MOTORS, SPARKS, FLAME, SMOKING, STATIC DISCHARGE OR OTHER IGNITION SOURCES EVEN AT LOCATIONS DISTANT FROM MATERIAL HANDLING SITE. CONTENTS UNDER PRESSURE. EXPOSURE TO HEAT OR PROLONGED EXPOSURE TO SUN MAY CAUSE BURSTING. SECTION V - REACTIVITY DATA HAZARDOUS DECOMPOSITION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE, IRRITATING FUMES, HYDROCARBONS, NITROGEN OXIDES, WATER VAPORS, TOXIC MATERIALS, AMMONIA FUMES. INCOMPATIBILITY (MATERIALS TO AVOID): STRONG OXIDIZING AGENTS, ACIDS, ALKALIS, WATER, CHLORINATED COMPOUNDS, COPPER, BASES. STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR. CONDITIONS TO AVOID: HIGH TEMPERATURE AND HUMIDITY, IGNITION SOURCE, VAPOR BUILD-UP. SECTION VI - HEALTH HAZARD DATA PRIMARY ROUTE(S) OF EXPOSURE: INHALATION, SKIN CONTACT ACUTE EFFECTS FORM SHORT TERM EXPOSURE: INHALATION: VAPORS AND MISTS IRRITATE NOSE, THROAT AND LUNGS (BURNING, STINGING, COUGHING). MAY CAUSE HEADACHE, DIZZINESS, NAUSEA, WEAKNESS, SHORTNESS OF BREATH AND LOSS OF COORDINATION. EXPOSURE TO EXTREMELY HIGH VAPOR CONCENTRATIONS MAY CAUSE 3 UNCONSCIOUSNESS AND ASPHYXIATION. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL. EYES: CONTACT WITH LIQUID OR VAPORS CAUSES SEVERE IRRITATION (REDNESS, WATERING, ITCHING, STINGING, BLURRED VISION). SKIN: CONTACT CAUSES SEVERE IRRITATION (DRYNESS, ITCHING, CRACKING, RASH, SWELLING) AND POSSIBLE BURNS. SKIN ABSORPTION: NONE KNOWN SWALLOWING: CAUSES NAUSEA, VOMITING, DIARRHEA AND CENTRAL NERVOUS SYSTEM DEPRESSION (HEADACHE, DIZZINESS, GIDDINESS, NAUSEA, LOSS OF COORDINATION). CHRONIC EFFECTS FROM LONG TERM/REPEATED EXPOSURE: LONG-TERM OR REPEATED OVER EXPOSURE, WITHOUT PROPER VENTILATION OR PERSONAL PROTECTION, MAY CAUSE DAMAGE TO: KIDNEYS, LIVER, HEART, BRAIN AND NERVOUS SYSTEM. OTHER: N/A CARCINOGEN DATA: N/A MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: RESPIRATORY TRACT IRRITATION, NAUSEA, SKIN AND EYE DISORDERS, SENSITIZATION TO CHEMICAL SUBSTANCES. SECTION VII - EMERGENCY AND FIRST AID PROCEDURES SWALLOWING: IN CASE OF ACCIDENTAL INGESTION, CALL POISON CENTER, EMERGENCY ROOM OR PHYSICIAN IMMEDIATELY. INHALATION: IF AFFECTED BY BREATHING ODORS OR VAPORS, REMOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYE: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES, WHILE LIFTING UPPER AND LOWER EYELIDS. GET MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER. REMOVE AND CLEAN CONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. OTHER: N/A SECTION VIII - PERSONAL PROTECTION RESPIRATORY PROTECTION: IF AFFECTED BY BREATHING VAPORS OR ODORS, WEAR A PROPERLY FITTED RESPIRATOR (NIOSH/MSHA TC23C OR EQUIVALENT) DURING USE. IF PRODUCT GIVES OFF SPRAY MIST, AVOID BREATHING BY WEARING RESPIRATOR PREFILTER OR PARTICLE MASK. VENTILATION: OPEN DOORS AND WINDOWS TO PROVIDE FRESH AIR VENTILATION, IN WORK AND IN SURROUNDING AREAS, DURING AND AFTER APPLICATION UNTIL ALL VAPOR (FUMES) ARE GONE. HAND PROTECTION: WEAR GLOVES TO AVOID SKIN CONTACT. EYE PROTECTION: WEAR SAFETY GLASSES OR GOGGLES TO PROTECT EYES FROM SPLASH AND SPRAY MIST. NOTE: CONTACT LENSES MAY CONTRIBUTE TO THE SEVERITY OF AN EYE INJURY AND SHOULD NOT BE WORN WHEN WORKING WITH CHEMICAL PRODUCTS. 4 OTHER PROTECTIVE EQUIPMENT: WHEN NECESSARY, WEAR PROTECTIVE CLOTHING TO AVOID SKIN CONTACT WITH LIQUID AND OVERSPRAY. WORK/HYGIENIC PRACTICES: WASH HANDS AFTER USING AND BEFORE EATING, DRINKING, OR USING TOBACCO PRODUCTS. THOROUGHLY CLEAN CONTAMINATED CLOTHING AND SHOES BEFORE REUSE. SPILL OR LEAK PROCEDURES: ELIMINATE IGNITION SOURCES AND VENTILATE AREA. EVACUATE ALL UNNECESSARY PERSONNEL. WEAR PROTECTIVE EQUIPMENT. DIKE DRAINS TO PREVENT ENTERING STORM OR SANITARY SEWERS, LAKES, RIVERS, STREAMS, OR WATERWAYS. CONTAIN SPILL AND COVER WITH INERT ABSORBENT MATERIAL. TAKE UP USING NON-SPARKING TOOLS (ALUMINUM, BRASS, OR COPPER) AND PLACE MIXTURE INTO CONTAINERS FOR DISPOSAL. NOTE: SOME SPILLS OR RELEASES MAY REQUIRE SPECIAL REPORTING TO LOCAL, STATE, OR FEDERAL AGENCIES. WASTE DISPOSAL: WASTE MATERIAL AND EMPTY CONTAINERS MUST BE DISPOSED OF IN ACCORDANCE WITH ALL LOCAL, STATE, AND FEDERAL ENVIRONMENTAL CONTROL REGULATIONS. USE ONLY APPROVED WASTE MANAGEMENT FACILITIES. SPECIAL PRECAUTIONS: HANDLING PRECAUTIONS: KEEP LIQUID AND VAPORS AWAY FROM HEAT, SPARKS AND FLAME. TURN OFF OR REMOVE ALL SOURCES OF IGNITION. USE PROPER METHODS OF VENTILATION TO PREVENT VAPOR BUILD-UP. AVOID SPRAYING HOT SURFACES. AVOID BREATHING VAPORS AND SPRAY MISTS. AVOID CONTACT WITH EYES AND SKIN. DO NOT TAKE INTERNALLY. USE ADEQUATE METHODS OF VENTILATION, RESPIRATORY AND PERSONAL PROTECTION EQUIPMENT. DO NOT HEAT, PUNCTURE OR INCINERATE CONTAINERS. CONTENTS ARE UNDER PRESSURE AND MAY CONTAIN EXPLOSIVE VAPORS, EVEN WHEN EMPTY. DO NOT REMOVE OR DEFACE LABEL. SHIPPING AND STORAGE PRECAUTIONS: CONTENTS UNDER PRESSURE. DO NOT STORE ABOVE 120 DEGREES F. OR PERMIT PROLONGED EXPOSURE TO SUNLIGHT. PROTECT CONTAINERS FROM DAMAGE. STORE IN BUILDINGS OR AREAS DESIGNED AND PROTECTED FOR STORAGE OR AEROSOLS. KEEP OUT OF REACH OF CHILDREN. SECTION IX- DISCLAIMER TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE, OBTAINED FROM SOURCES BELIEVED BY HOMAX PRODUCTS, INC. TO BE ACCURATE. SINCE THE CONDITIONS AND METHODS OF USE OF OUR PRODUCTS ARE BEYOND OUR CONTROL, WE DISCLAIM ANY AND ALL LIABILITY ARISING OUT OF THE IMPROPER USE OF THESE PRODUCTS OR THE INFORMATION PROVIDED HEREWITH. SHIPPING INFORMATION: PRODUCT CLASSIFICATION: ORM-D HAZARD CLASS: CONSUMER COMMODITY UN IDENTIFICATION NUMBER: N/A DOT LABEL (S) REQUIRED: N/A PACKAGING GROUP: N/A PART I What is the material and what do I need to know in an emergency? 1. PRODUCT IDENTIFICATION TRADE NAME (AS LABELED): PRODUCT CODES: PRODUCT USE: SUPPLIER/MANUFACTURER'S NAME: ADDRESS: CHEMTREC EMERGENCY NO.: BUSINESS PHONE: DATE OF PREPARATION: HOMAX Waterbased ORANGEPEEL & SPLATTER Spray Texture 4091, 4092, 4192, 4091-06,4092-06, 4091-10-06 Patching Interior Texture HOMAX PRODUCTS, INC. 200 Westerly Rd. Bellingham, WA 98226 1-800-424-9300 (United States) 1-703-527-3887 (International Collect) 1-800-729-9029 Nov. 16, 2006 2. COMPOSITION and INFORMATION ON INGREDIENTS CHEMICAL NAME CAS # % w/w EXPOSURE LIMITS IN AIR ACGIH-TLV OSHA-PEL NIOSH-REL TWA mg/m3 STEL mg/m3 TWA mg/m3 STEL mg/m3 TWA mg/m3 STEL mg/m3 IDLH/OTHER mg/m3 Calcium Carbonate 1317-65-3 30 - 60 10 NE 15 * 5 ** NE 10 * 5 ** NE NE Dimethyl Ether (Propellant) 115-10-6 7 - 13 NE NE NE NE NE NE DFG MAK: IDLH: 1900 Peak: II (8) NA 20 NA 2* NE 1000 984 980 NE 980 1225 2,000 (10% LEL) Talc Isopropyl alcohol Silica Quartz 14807-96-6 1-5 67-63-0 3-7 492 14808-60-7 0.1-1 10 mg/m3 ** NE 0.05 * NE 50 % SiO2+2 The ingredients in the balance of this product do not contribute significant hazards beyond those described in this document. All pertinent health, safety and environmental information have been presented, per the requirements of the US Federal OSHA Hazard Communication Standard (29 CFR 1910.1200) and Canadian WHMIS. Water and ingredients present in concentrations of less than 1% (or less than 0.1% if carcinogens) 2 ** 0.05 R Balance NE NE = Not Established. See Section 16 for Definitions of Terms Used. NOTE (1): ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format. This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. NOTE (2):* Total dust; ** Respirable fraction; R = Measured as respirable fraction of the aerosol. NOTE (3): The component Nicron 403, is free of crystalline silica and asbestos; therefore, carcinogenicity does not apply. 3. HAZARD IDENTIFICATION HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06 page 1 of 9 EMERGENCY OVERVIEW: PHYISCAL DESCRIPTION: This product is a white colored aerosol with a slight ethereal odor. HEALTH HAZARD: This product is harmful if it is inhaled or swallowed. This product may cause severe irritation to the eyes or skin. If particulates of this product are inhaled, severe irritation of the respiratory system (i.e. lungs, nose, and throat), central nervous system, and gastrointestinal tract could occur. FIRE HAZARD: This product is a flammable liquid and vapor (aerosol), with its contents under pressure. HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER propellant has a flash point of - 42oF / -41oC. REACTIVITY HAZARD: Minimal Hazard; the product is normally stable under ordinary conditions of use and storage. ENVIRONMENTAL HAZARD: This product is does not normally present a significant hazard to aquatic or terrestrial life. SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The most significant route of occupational overexposure is contact with skin, eyes, and inhalation. The symptoms of overexposure to this product are as follows: INHALATION: If inhalation of product s mists or vapors occurs, severe respiratory system irritation or nervous system depression may develop. Nervous system depression is characterized by headache, dizziness, nausea, or possible unconsciousness. CONTACT WITH SKIN or EYES: Contact can cause severe eye or skin irritation. Symptoms of eye exposure may include redness, pain, burning sensation, and tearing. Prolonged skin contact may result in redness, irritation, and dermatitis. SKIN ABSORPTION: May cause irritation or burning sensation. INGESTION: Ingestion is not anticipated to be a significant route of occupational exposure. If the product is swallowed, severe irritation of the mouth, throat, and other tissues of the gastro-intestinal system may occur. Ingestion of large amounts may cause irritation, pain, vomiting, and diarrhea. INJECTION: Accidental injection of this product may cause mild irritation and swelling, in addition to the wound. Hazardous Materials Identification System (HMIS) Health 1* Flammability 4 Physical Hazard 1 Protective Equipment A See Section 16 for Definition of Ratings HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. ACUTE: Depending on the duration of contact, overexposures can severely irritate the eyes, skin, lungs, respiratory tract and nervous system. Symptoms of exposure generally alleviated when overexposure ends. CHRONIC: Long-term skin contact may result in dermatitis. TARGET ORGANS: Acute: Eyes, Skin, Lungs, CNS, and Respiratory tract. Chronic: Skin PART II What should I do if a hazardous situation occurs? 4. FIRST-AID MEASURES Victims of chemical exposure must be taken for medical attention if any adverse effects occur. Take a copy of label and MSDS to physician or health professional with victim. SKIN EXPOSURE: If this product contaminates the skin, immediately begin decontamination with running water. Remove exposed or contaminated clothing, taking care not to contaminate eyes. Victim must seek immediate medical attention if any adverse exposure symptoms develop. EYE EXPOSURE: If this product enters the eyes, open victim's eyes while under gently running water. Use sufficient force to open eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. Victim must seek medical attention. INHALATION: If this product is inhaled, blow nose and remove victim to fresh air. INGESTION: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION. DO NOT INDUCE VOMITING, unless directed by medical personnel. Have victim rinse mouth with water, if conscious. Never induce vomiting or give 4. FIRST-AID MEASURES - Continued a diluent (e.g., water) to someone who is unconscious, having convulsions, or unable to swallow. If contaminated individual is convulsing, maintain an open airway and obtain immediate medical attention. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing conditions of pulmonary, dermatitis, and conjunctivitis disorders. HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06 page 2 of 9 RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure. 5. FIRE-FIGHTING MEASURES 0 FLASH POINT: 30 F (-1.10C) 0 NFPA RATING 0 AUTOIGNITION TEMPERATURE: 662 F (350 C) (Dimethyl ether propellant) FLAMMABILITY FLAMMABLE LIMITS (in air by volume, %): 4 Lower: 3.4% (Dimethyl ether propellant) Upper: 27% (Dimethyl ether propellant) FIRE EXTINGUISHING MATERIALS: Use extinguishing material suitable to the surrounding fire. Water Fog: OK Foam: OK Halon: OK HEALTH 1 2 Carbon Dioxide: OK Dry Chemical: OK 0 1 REACTIVITY OTHER UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode due to build up of pressure from extreme heat or fire. Explosion Sensitivity to Mechanical Impact: Do not puncture. Explosion Sensitivity to Static Discharge: Primarily vapors. SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection. Structural firefighters must wear Self-Contained Breathing Apparatus and full protective equipment. Move containers from See Section 16 for fire area if it can be done without risk to personnel. Exercise caution; contaminated floors Definition of Ratings and surfaces can be sticky. If possible, prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive areas. 6. ACCIDENTAL RELEASE MEASURES SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by trained personnel using pre-planned procedures. Proper protective equipment should be used. In case of a spill, clear the affected area and protect people. Releases of this material may be sticky. If the product is dried, and dusts may be generated during clean-up, dampen material prior to clean-up to avoid airborne particulates. RESPONSE TO INCIDENTAL RELEASES: Small scale releases, such as 1 container of this product, can generally be handled by personnel who have received basic chemical safety training. Respond to incidental chemical releases by wearing gloves, goggles, and appropriate body protection and by following the instructions for use presented above. RESPONSE TO NON-INCIDENTAL RELEASES: Respond to non-incidental chemical releases of this product, such as the simultaneous puncturing of several containers, by clearing the impacted area and contacting appropriate emergency personnel. Clean up should only be done by qualified personnel. Responders should wear the level of protection appropriate to the type of chemical released, the volume of the material spilled, and the location where the incident has occurred. Minimum Personal Protective Equipment should be Level C: triple-gloves, chemical resistant apron, boots, and splash goggles and an Air-Purifying respirator with high-efficiency particulate filter. RESPONSE EQUIPMENT AND PROCEDURES: Wipe-away spilled paste with damp polypads or other suitable absorbent materials, or scrape carefully with plastic tools. Decontaminate the area thoroughly. Place all spill residues in a suitable container and seal. Dispose of in accordance with applicable U.S. Federal, State, or local procedures or appropriate standards of Canada (see Section 13, Disposal Considerations). PART III How can I prevent hazardous situations from occurring? 7. HANDLING and STORAGE WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash thoroughly after using this product. Do not eat or drink while using this material. Avoid generating dusts and particulates of this product. If sanding, use with adequate ventilation. Remove contaminated clothing immediately. HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06 page 3 of 9 Deleted: STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to use it safely. Open containers carefully on a stable surface. Empty containers may contain residual material; therefore, empty containers should be handled with care. Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store away from incompatible materials (see Section 10, Stability and Reactivity). Keep container tightly closed when not in use. Inspect all incoming containers before storage, to ensure containers are properly labeled and not damaged. PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in Section 6 (Accidental Release Measures). Make certain that application equipment is locked and tagged-out safely if necessary. Collect all rinsates and dispose of according to applicable U.S. Federal, State, or local procedures or appropriate Canadian standards. 8. EXPOSURE CONTROLS - PERSONAL PROTECTION VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained below the limits provided in Section 2 (Composition and Information on Ingredients). Ensure adequate ventilation is available when sanding. Ensure eyewash/safety shower stations are available near areas where this product is used. RESPIRATORY PROTECTION: None needed under normal conditions of use. Use a dust respirator for large jobs if dusts cannot otherwise be eliminated. EYE PROTECTION: For consumer use, wearing eye protection (such as splash goggles) is advisable. However, for specific industrial applications, enhanced eye protection may be necessary. Use approved safety goggles or safety glasses, as described in OSHA 29 CFR 1910.133. If necessary, refer to U.S. OSHA 29 CFR 1910.133, or appropriate Canadian standards. HAND PROTECTION: For consumer use, wearing protective gloves is recommended. For specific industrial applications, wear chemical impervious gloves (e.g., Neoprene, nitrile). If necessary, refer to U.S. OSHA 29 CFR 1910.138 or the appropriate standards of Canada. BODY PROTECTION: For consumer use, no specific body protection is normally needed. For specific industrial applications, body protection is not routinely necessary, but may be warranted if excessive dusts may be generated. Use body protection appropriate for task (e.g., Tyvek suit, rubber apron). If a hazard of injury to the feet exists due to falling objects, rolling objects, where objects may pierce the soles of the feet or where employee s feet may be exposed to electrical hazards, use foot protection, as described in U.S. OSHA 29 CFR 1910.136. HMIS PERSONAL PROTECTIVE EQUIPMENT RATING: Industrial Use situations: (A) Eye Protection. 9. PHYSICAL and CHEMICAL PROPERTIES RELATIVE VAPOR DENSITY (air = 1): Heavier than air EVAPORATION RATE (BuAc =1): Faster than n-butyl acetate SPECIFIC GRAVITY: 0.9 MELTING POINT: 32oF (0oC) SOLUBILITY IN WATER: Soluble in water BOILING POINT: -13 oF (10.5 oC) VAPOR PRESSURE, mm Hg @ 24°C: pH: NA ODOR THRESHOLD: NA COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): NA V.O.C.: < 60% MIR: < 1.20 APPEARANCE, ODOR AND COLOR: This product is a white colored aerosol with a slight ethereal odor HOW TO DETECT THIS SUBSTANCE (warning properties): The appearance and odor of this product may act as warning properties in the event of an accidental release. 10. STABILITY and REACTIVITY STABILITY: Stable under normal circumstances of use and handling. DECOMPOSITION PRODUCTS: Thermal decomposition of this product may generate dusts, irritating fumes, and toxic gases (e.g., carbon monoxide, carbon dioxide). MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: This product is not compatible strong oxidizing agents. HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06 page 4 of 9 HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: Avoid contact with incompatible chemicals and high temperatures. PART IV Is there any other useful information about this material? 11. TOXICOLOGICAL INFORMATION TOXICITY DATA: The following toxicology information is available for components greater than 1% in concentration. The following data are available for Dimethyl ether: Inhalation-Rat LC50: 308 g/m3 Inhalation-Mouse LC50: 386,000 ppm/30M Inhalation-Rat TCLo: 2 pph/6H/30W-I The following data are available for Isopropyl alcohol: Skin-Rabbit, adult 500 mg Mild irritation effects Eye effects-Rabbit, adult 16 mg Eye effects-Rabbit, adult 10 mg Moderate irritation effects Cytogenetic Analysis System-Saccharomyces cerevisiae 200 mmol/tube Cytogenetic Analysis System-Rat-Inhalation 1030 mg/m3/16W-I Oral-Rat TDLo:6480 mg/kg (male 26W pre):Reproductive effects Inhalation-Rat TCLo:10,000 ppm/7H (female 1-19D post):Teratogenic effects Oral-Man TDLo:14,432 mg/kg: Central nervous system effects, Cardiovascular effects, Pulmonary system effects Oral-Human TDLo:223 mg/kg: Central nervous system effects, Cardiovascular effects Oral-Man LDLo:5272 mg/kg AJCPAI 38,144,62 Oral-Human LDLo:3570 mg/kg: Central nervous system effects, Pulmonary system effects, Gastrointestinal tract effects Unreported-Man LDLo:2770 mg/kg Oral-Rat LD50:5045 mg/kg Inhalation-Rat LCLo:16,000 ppm/4H Intraperitoneal-Rat LD50:2735 mg/kg Intravenous-Rat LD50:1099 mg/kg Oral-Mouse LD50:3600 mg/kg Inhalation-Mouse LCLo:12,800 ppm/3H Intraperitoneal-Mouse LD50:4477 mg/kg Subcutaneous-Mouse LDLo:6000 mg/kg Intravenous-Mouse LD50:1509 mg/kg Oral-Dog, adult LD50:4797 mg/kg Intravenous-Dog, adult LDLo:5120 mg/kg Intravenous-Cat, adult LDLo:1963 mg/kg Oral-Rabbit, adult LD50:6410 mg/kg Skin-Rabbit, adult LD50:12,800 mg/kg The following data are available for Talc: Skin-Human 300 mg/3D-I Mild irritation effects Inhalation-Rat TCLo:11 mg/m3/1Y-I:Equivocal tumorigenic agent The following data are available for Calcium Carbonate, Vinyl Acrylic Copolymer, and Silica Quartz: None available SUSPECTED CANCER AGENT: The following table summarizes the carcinogenicity listing for the components of this product. NO indicates that the substance is not considered to be, or suspected to be, a carcinogen by the listed agency. IARC NTP ACGIH NIOSH OSHA CA PROP 65 Calcium Carbonate CHEMICAL NO NO NO NO NO NO Dimethyl Ether NO NO NO NO NO NO 3 NO A4 NO NO NO NO Talc Vinyl Acrylic Copolymer NO NO NO NO NO Isopropyl alcohol 3 NO NO NO NO NO Silica Quartz 1 Known Ca NO A2 YES Note: See section 16 for definition of ratings HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06 page 5 of 9 11. TOXICOLOGICAL INFORMATION - Continued IRRITANCY OF PRODUCT: This product can be severely irritating to contaminated tissue. SENSITIZATION TO THE PRODUCT: The components of this product are not reported to be sensitizers. TOXICOLOGICAL SYNERGISTIC PRODUCTS: None known. REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product and its components on the human reproductive system. Mutagenicity: This product is not expected to produce mutagenic effects in humans when used as instructed. Embryotoxicity: This product is not expected to produce embryotoxic effects in humans when used as instructed. Teratogenicity: This product is not reported to cause teratogenic effects in humans when used as instructed. Reproductive Toxicity: This product is not reported to cause reproductive effects in humans when used as instructed. A mutagen is a chemical that causes permanent changes to genetic material (DNA) such that the changes will propagate through generational lines. An embryotoxin is a chemical that causes damage to a developing embryo (i.e. within the first eight weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical that causes damage to a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is any substance that interferes in any way with the reproductive process. BIOLOGICAL EXPOSURES INDICES (BEIs): There is no BEI currently established for this substance. 12. ECOLOGICAL INFORMATION ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION. ENVIRONMENTAL STABILITY: The following environmental data is available for components of this product: The mineral components of this product are stable in the environment. EFFECT OF MATERIAL ON PLANTS or ANIMALS: This product is not anticipated to cause significant effects on terrestrial plants or animals if released in small, consumer-sized volumes. This product may be harmful to animal life if large volumes of it are released into the environment. Refer to Section 11 (Toxicological Information) for specific animal data. EFFECT OF CHEMICAL ON AQUATIC LIFE: This product is not anticipated to cause significant effects on aquatic plants or animals if released in small, consumer-sized volumes. This product may be harmful to contaminated aquatic life (especially if large volumes of it are released into an aquatic environment). The following aquatic toxicity data is available for components of this product: NONE 13. DISPOSAL CONSIDERATIONS PREPARING WASTES FOR DISPOSAL: Consumer Waste: Dispose of according to pertinent state and local household waste and requirements. Industrial Use: Waste disposal must be in accordance with appropriate U.S. Federal, State, and local regulations or with regulations of Canada. EPA WASTE NUMBER: Not applicable to wastes consisting only of this product; however, the specific RCRA codes depend on the exact nature of the discarded material. 14. TRANSPORTATION INFORMATION THIS PRODUCT IS HAZARDOUS PER 49 CFR 172.101, THE U.S. DEPARTMENT OF TRANSPORTATION. PROPER SHIPPING NAME: Aerosols HAZARD CLASS NUMBER and DESCRIPTION: 2.1(Flammable Gas) UN IDENTIFICATION NUMBER: UN1950 DOT LABEL(S) REQUIRED: Flammable Gas PACKAGING GROUP: N/A NORTH AMERICAN RESPONSE GUIDEBOOK NUMBER (2000): 126 MARINE POLLUTANT: No component is designated as a DOT Marine Pollutant. Consumer commodities (per 173.306 (h)): A limited quantity that conforms to the provisions of paragraph (a) (1), (a) (3), or (b) of this section and is a "consumer commodity" (per 49 CFR 171.8) can be renamed Consumer commodity and reclassified as an ORMD Material. Each package may not exceed 30 kg (66 pounds)gross weight. Reference 173.306 (a) (3): Limited quantities of compressed gases may be shipped when in a metal container for the sole purpose of expelling a nonpoisonous liquid, paste, or powder. 14. TRANSPORTATION INFORMATION - Continued TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: description applies to this product under the regulations of Transport Canada. HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06 page 6 of 9 The above-listed DOT basic 15. REGULATORY INFORMATION ADDITIONAL U.S. REGULATIONS: EPA REPORTING REQUIREMENTS: The following reporting requirements are applicable to components of this product: CHEMICAL SECTION 302 SECTION 304 SECTION 313 (40 CFR 355, Appendix A) (40 CFR Table 302.4) (40 CFR 372.65) Calcium Carbonate NO NO NO Dimethyl Ether NO NO NO Talc NO NO NO NO NO NO NO NO NO NO NO NO Isopropyl alcohol Vinyl Acrylic Copolymer Silica Quartz U.S. SARA SECTION 311/312 FOR PRODUCT: Acute health effects; chronic health effects. U.S. TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory. OTHER U.S. FEDERAL REGULATIONS: Not applicable. CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): WARNING: This product contains a chemical known to the State of California to cause cancer. ANSI LABELING (Z129.1): DANGER! HARMFUL OR FATAL IF SWALLOWED. EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPOR HARMFUL. CONTENTS UNDER PRESSURE. MAY EXPLODE IF HEATED. AFFECTS CENTRAL NERVOUS SYSTEM. CAUSES SEVERE EYE IRRITATION. CAUSES IRRITATION TO SKIN AND RESPIRATORY TRACT. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL. ANSI LABEL PRECAUTIONS: Keep away from heat, sparks and flame. Do not expose to heat or store at temperatures above 120oF. Close container after use. Avoid breathing dust, vapors or mist. Do not take internally. Avoid contact with skin and clothing. Wash thoroughly after handling. Avoid contact with eyes. ENVIRONMENTAL HAZARDS: Do not discharge effluent containing this product into streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. 15. REGULATORY INFORMATION - Continued ADDITIONAL CANADIAN REGULATIONS: CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are listed on the DSL Inventory. CANADIAN WHMIS SYMBOLS: A - Compressed gas B1 - Flammable and combustible material - Flammable gas B2 - Flammable and combustible material - Flammable liquid HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06 page 7 of 9 D2A - Poisonous and infectious material - Other effects - Very toxic D2B - Poisonous and infectious material - Other effects - Toxic This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION PREPARED BY: DATE OF PRINTING John R. Kordosh Homax Products, Inc. 4505 E. Industrial St., Ste. 1B Simi Valley, CA 93063 (805) 581-3555 December 5, 2006 HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06 page 8 of 9 DEFINITIONS OF TERMS A large number of abbreviations and acronyms appear on a MSDS. Some of these, which are commonly used, include the following: CAS #: This is the Chemical Abstract Service Number that uniquely identifies each compound. ACGIH - American Conference of Governmental Industrial Hygienists, a professional association which establishes exposure limits. TLV - Threshold Limit Value - an airborne concentration of a substance that represents conditions under which it is generally believed that nearly all workers may be repeatedly exposed without adverse effect. The duration must be considered, including the 8-hour Time Weighted Average (TWA), the 15minute Short Term Exposure Limit, and the instantaneous Ceiling Level (C). Skin absorption effects must also be considered. OSHA - U.S. Occupational Safety and Health Administration. PEL - Permissible Exposure Limit - This exposure value means exactly the same as a TLV, except that it is enforceable by OSHA. The OSHA Permissible Exposure Limits are based in the 1989 PELs and the June, 1993 Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 40191). Both the current PELs and the vacated PELs are indicated. The phrase, Vacated 1989 PEL, is placed next to the PEL that was vacated by Court Order. IDLH - Immediately Dangerous to Life and Health - This level represents a concentration from which one can escape within 30-minutes without suffering escape-preventing or permanent injury. The DFG - MAK is the Republic of Germany s Maximum Exposure Level, similar to the U.S. PEL. NIOSH is the National Institute of Occupational Safety and Health, which is the research arm of the U.S. Occupational Safety and Health Administration (OSHA). NIOSH issues exposure guidelines called Recommended Exposure Levels (RELs). When no exposure guidelines are established, an entry of NE is made for reference. HAZARD RATINGS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM: Health Hazard: 0 (minimal acute or chronic exposure hazard); 1 (slight acute or chronic exposure hazard); 2 (moderate acute or significant chronic exposure hazard); 3 (severe acute exposure hazard; onetime overexposure can cause permanent injury and may be fatal); 4 (extreme acute exposure hazard; onetime overexposure can be fatal). Flammability Hazard: 0 (minimal hazard); 1 (materials that require substantial pre-heating before burning); 2 (combustible liquid or solids; liquids with a flash point of 38-93 C [100-200 F]); 3 (Class IB and IC flammable liquids with flash points below 38 C [100 F]); 4 (Class IA flammable liquids with flash points below 23 C [73 F] and boiling points below 38 C [100 F]. Reactivity Hazard: 0 (normally stable); 1 (material that can become unstable at elevated temperatures or which can react slightly with water); 2 (materials that are unstable but do not detonate or which can react violently with water); 3 (materials that can detonate when initiated or which can react explosively with water); 4 (materials that can detonate at normal temperatures or pressures). NATIONAL FIRE PROTECTION ASSOCIATION: Health Hazard: 0 (material that on exposure under fire conditions would offer no hazard beyond that of ordinary combustible materials); 1 (materials that on exposure under fire conditions could cause irritation or minor residual injury); 2 (materials that on intense or continued exposure under fire conditions could cause temporary incapacitation or possible residual injury); 3 (materials that can on short exposure could cause serious temporary or residual injury); 4 (materials that under very short exposure could cause death or major residual injury). Flammability Hazard and Reactivity Hazard: Refer to definitions for Hazardous Materials Identification System . FLAMMABILITY LIMITS IN AIR: Much of the information related to fire and explosion is derived from the National Fire Protection Association (NFPA). Flash Point - Minimum temperature at which a liquid gives off sufficient vapors to form an ignitable mixture with air. Autoignition Temperature: The minimum temperature required to initiate combustion in air with no other source of ignition. LEL - the lowest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. UEL - the highest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. TOXICOLOGICAL INFORMATION: Possible health hazards as derived from human data, animal studies, or from the results of studies with similar compounds are presented. Definitions of some terms used in this section are: LD50 - Lethal Dose (solids & liquids) which kills 50% of the exposed animals; LC50 - Lethal Concentration (gases) which kills 50% of the exposed animals; ppm concentration expressed in parts of material per million parts of air or water; mg/m3 concentration expressed in weight of substance per volume of air; mg/kg quantity of material, by weight, administered to a test subject, based on their body weight in kg. Other measures of toxicity include TDLo, the lowest dose to cause a symptom and TCLo the lowest concentration to cause a symptom; TDo, LDLo, LDo, TC, TCo, LCLo, and LCo, the lowest dose (or concentration) to cause lethal or toxic effects. BEI - Biological Exposure Indices, represent the levels of determinants which are most likely to be observed in specimens collected from a healthy worker who has been exposed to chemicals to the same extent as a worker with inhalation exposure to the TLV. Ecological Information: EC is the effect concentration in water. Data from several sources are used to evaluate the cancer-causing potential of the material. The sources and ratings are: IARC - the International Agency for Research on Cancer; 1 = Carcinogenic to humans, 2A, 2B = Probably carcinogenic to humans, 3 = Unclassifiable as to carcinogenicity in humans, and 4 = Probably not carcinogenic to humans. NTP - the National Toxicology Program; K =Known to be a human carcinogen, and R = Reasonably anticipated to be a human carcinogen. RTECS - the Registry of Toxic Effects of Chemical Substances. OSHA - Occupational Safety and Health Administration and CAL/OSHA - California s subunit of the Occupational Safety and Health Administration; Ca = Carcinogen defined with no further categorization. ACGIH American Conference of Governmental Industrial Hygienists; A1 = Confirmed human carcinogen, A2 = Suspected human carcinogen, A3 = Confirmed animal carcinogen with unknown relevance to humans, A4 = Not classifiable as a human carcinogen, and A5 = Not suspected as a human carcinogen. NIOSH U.S. National Institute for Occupational Safety and Health; Ca = Potential occupational carcinogen, with no further categorization. EPA U.S. Environmental Protection; A = Human carcinogen, B = Probable human carcinogen, C = Possible human carcinogen, D = Not classifiable as to human carcinogenicity, E = Evidence of Non-carcinogenicity for humans, K = Known human carcinogen, L = Likely to produce cancer in humans, CBD = Cannot be determined, NL = Not likely to be carcinogenic in humans, and I = Data are inadequate for an assessment of human carcinogenic potential. REGULATORY INFORMATION: This section explains the impact of various laws and regulations on the material. EPA is the U.S. Environmental Protection Agency. WHMIS is the Canadian Workplace Hazardous Materials Information System. DOT and TC are the U.S. Department of Transportation and the Transport Canada, respectively. Superfund Amendments and Reauthorization Act (SARA); the Canadian Domestic/Non-Domestic Substances List (DSL/NDSL); the U.S. Toxic Substance Control Act (TSCA); Marine Pollutant status according to the DOT; the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA or Superfund); and various state regulations. This section also includes information on the precautionary warnings that appear on a material s industrial package label. HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06 page 9 of 9 This document was created with Win2PDF available at http://www.daneprairie.com. The unregistered version of Win2PDF is for evaluation or non-commercial use only. 1 HAZARDOUS MATERIAL INFORMATION SYSTEM PRODUCT TRADE NAME: HOMAX PRODUCTS, INC. HEALTH 1 FLAMMABILITY 0 REACTIVITY 0 PROTECTIVE EQUIPMENT J ACOUSTIC TEXTURE II ITEM #4070 (HAZARD RATING: 0=LEAST, 1=SLIGHT, 2=MODERATE, 3=HIGH, 4=EXTREME) (I=SAFETY GLASSES, GLOVES, & VAPOR RESPIRATOR) SECTION I - MANUFACTURER IDENTIFICATION MANUFACTURER'S NAME: HOMAX PRODUCTS, INC. 468 W. HORTON ROAD BELLINGHAM WA 98226 24 HOUR EMERGENCY PHONE NUMBER: CHEMTREC 1-800-424-9300 NFORMATION PHONE NUMBER: 1-800-729-9029 DATE OF PREPARATION: 5/27/03 SECTION II A - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION CAS NUMBER DESCRIPTION PEL TLV 07727-37-9 14808-60-7 NITROGEN SILICA, CRYSTALLINE-QUARTZ % 1 0.1 MG/M3 0.1 MG/M2 TRACE TRACE QUANTITIES LESS THAN 1.0% AND GREATER THAN 0.009% PEL REPRESENTS LOWERED 1989 LIMITS AND MAY NOT BE ENFORCEABLE BY FEDERAL OSHA. SECTION IIB - OTHER REGULATORY INFORMATION CAS NUMBER DESCRIPTION CARCINOGEN SARA TITLE III CALIFORNIA 07727-37-9 NITROGEN NTP IARC OSHA 302 313 P65 I II 14808-60-7 SILICA CRYSTALLINE-QUARTZ X X 2 SECTION III- PHYSICAL/CHEMICAL CHARACTERISTICS APPEARANCE AND ODOR: VISCIOUS LUMPY LIQUID BOILING POINT: 0 TO 0 DEG. F WATER SOLUBILITY: APPRECIABLE VAPOR DENSITY: HEAVIER THAN AIR EVAPORATION RATE: SLOWER THAN N-BUTYL ACETATE= MEDIAN WT/GAL: 9.83 WITH PROP .89 CALCULATED V.O.C. .08 LB/GL (10GR/LT) SECTION IV-FIRE AND EXPLOSION DATA FLASH POINT (METHOD USED): N/A UNIFORM FIRE CODE STANDARD 88-1 LEVEL ONE AEROSOL BULK PRODUCT FLASH POINT: N/A N/A BULK PROPELLANT FLASH POINT: PACKAGED PRODUCT FLAME EXTENSION: 00 EXTINGUISHING MEDIA: USE FOAM, CO2, DRY CHEMICAL, WATER FOG SPECIAL FIREFIGHTING PROCEDURES: EVACUATE ALL UNNECESSARY PERSONNEL. USE FULL PROTECTIVE EQUIPMENT, INCLUDING SELFCONTAINED BREATHING APPARATUS. USE WATER SPRAY, PREFERABLY FOG, TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD UP AND POSSIBLE EXPLOSION. DO NOT ALLOW PRODUCT OR RUNOFF FROM FIRE CONTROL TO ENTER STORM OR SANITARY SEWERS, LAKES, RIVERS, STEAMS, OR WATERWAYS. UNUSUAL FIRE AND EXPLOSION HAZARDS: CONTENTS UNDER PRESSURE. EXPOSURE TO HEAT OR PROLONGED EXPOSURE TO SUN MAY CAUSE BURSTING. SECTION V – REACTIVITY DATA STABILITY: MATERIAL IS STABLE INCOMPATIBILTY (MATERIALS TO AVOID): STRONG OXIDIZING AGENTS, ACIDS, AMMONIA. HAZARDOUS DECOMPOSITION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE, NITROGEN OXIDES. CONDITIONS TO AVOID: HIGH TEMPERATURE AND HUMIDITY, IGNITION SOURCE, VAPOR BUILD UP. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR. SECTION VI – HEATLTH HAZARD DATA ROUTES OF ENTRY: INHALATION: YES SKIN: YES ACUTE EFFECTS FROM SHORT TERM EXPOSURE: INHALATION: DUST FROM PARTICLES CAUSE IRRITATION TO NOSE, THROAT AND LUNGS (POSSIBLE BURNING, STINGING, COUGHING) EYES: NONE KNOWN SKIN: NONE KNOWN SKIN ABSORPTION: NONE KNOWN CHRONIC EFFECTS FROM LONG TERM /REPEATED EXPOSURE: LONG TERM OR REPEATED OVEREXPOSURE, WITHOUT PROPER VENTILATION OR PERSONAL PROTECTION, MAY CAUSE DAMAGE TO LIVER. OTHER: THIS PRODUCT CONTAINS A FORM OF CRYSTALLINE SILICA. LONG TERM EXPOSURE TO HIGH LEVELS OF CHRYSTALLINE SILICA DUSTS MAY RESULT IN SILICOSIS, A DISABLING LUNG DISEASE. ALWAYS WEAR APPROPRIATE RESPIRATORY PROTECTION WHEN EXPOSED TO SANDING OR GRINDING DUSTS. CARCINOGEN DATA: CRYSTALLINE SILICAS ARE CLASSIFIED BY IARC AS POTENTIAL HUMAN CARCINOGENS, INHALATION OF CRYSTALLINE DUSTS MAY CAUSE LUNG TUMORS. RISK OF CANCER DEPENDS ON LEVEL AND DURATION 3 OF EXPOSURE. THE FOLLOWING STATEMENT IS REQUIRED BY CALIFORNIA PROPOSITION 65 (SAFE DRINKING WATER AND TOXIC REFORM ACT OF 1986) WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: RESPIRATORY TRACT IRRITATION, NAUSEA, SKIN AND EYE DISORDERS; SENSITIZATION TO CHEMICAL SUBSTANCES. EMERGENCY AND FIRST AID PROCEDURES: SWALLOWING: IN CASE OF ACCIDENTAL INGESTION, CALL POISON CENTER, EMERGENCY ROOM OR PHYSICIAN IMMEDIATELY. INHALATION: IF AFFECTED BY BREATHING ODORS OR VAPORS, REMOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS PERSISTS. EYE: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES, WHILE LIFTING THE UPPER AND LOWER EYELIDS. GET MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER. REMOVE AND CLEAN CONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. OTHER: N/A SECTION VIII – PERSONAL PROTECTION RESPIRATORY PROTECTION: IF AFFECTED BY BREATHING VAPORS OR ODORS, WEAR A PROPERLY FITTED RESPIRATOR (NIOSH/MSHA TC23C OR EQUILVALENT) DURING USE. IF PRODUCT GIVES OFF SPRAY MIST, AVOID BREATHING BY WEARING RESPIRATOR PREFILTER OR PARTICLE MASK. VENTILATION: OPEN DOORS AND WINDOWS TO PROVIDE FRESH VENTILATION. IN WORK AND SURROUNDING AREAS DURING AND AFTER APPLICATION UNTIL ALL VAPOR (FUMES) ARE GONE. HAND PROTECTION WEAR GLOVES TO AVOID SKIN CONTACT. EYE PROTECTION: SAFETY GLASSES OR GOGGLES TO PROTECT EYES FROM SPLASH AND SPRAY MISTS. NOTE: CONTACT LENS MAY CONTRIBUTE TO THE SEVERITY OF AND EYE INJURY AND SHOULD NOT BE WORN WHEN WORKING WITH CHEMICALS. OTHER PROTECTIVE CLOTHING OR EQUIPMENT: EYES - WASH FOUNTAIN AND SAFETY SHOWER. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE RE-USE. WORK/HYGIENIC PRACTICES: WASH HANDS AFTER USING AND BEFORE EATING, DRINKING OR USING TOBACCO PRODUCTS. THROUGHLY CLEAN CONTAMINATED CLOTHING AND SHOES BEFORE REUSE. SPILL OR LEAKAGE PROCEDURES: STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: ELIMINATE IGNITION SOURCES AND VENTILATE AREA. EVACUATE UNNECESSARY PERSONNEL. WEAR PROTECTIVE EQUIPMENT. DIKE AND CONAIN SPILL WITH INERT MATERIAL. TRANSFER LIQUID TO CONTAINERS FOR DISPOSAL OR RECOVERY. PREVENT MATERIAL FROM ENTERING STORM OR SANITARY SEWERS AND OPEN BODIES OF WATER. WASTE DISPOSAL: WASTE MATERIAL AND EMPTY CONTAINERS MUST BE DISPOSED OF IN ACCORDANCE WITH ALL LOCAL, STATE, AND FEDERAL ENVIRONMENTAL CONTROL REGULATIONS. USE ONLY APPROVED WASTE MANAGEMENT FACILITIES. SPECIAL PRECAUTIONS: HANDLING PRECAUTIONS: USE PROPER METHODS OF VENTILATION TO PREVENT VAPOR BUILD-UP. AVOID SPRAYING HOT SURFACES. DO NOT HEAT, PUNCTURE OR INCINERATE CONTAINERS. CONTENTS ARE UNDER PRESSURE AND MAY CONTAIN VAPORS, EVEN WHEN EMPTY. DO NOT REMOVE OR DEFACE LABEL. 4 SHIPPING AND STORAGE PRECAUTIONS: CONTENTS UNDER PRESSURE. DO NOT STORE ABOVE 120 DEGREES F OR PERMIT PROLONGED EXPOSURE TO SUNLIGHT. PROTECT CONTAINERS FROM DAMAGE. STORE IN BUILDINGS OR AREAS DESIGNED AND PROTECTED FROM STORAGE OF AEROSOLS. KEEP OUT OF REACH CHILDREN. SECTION IX - DISCLAIMER TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE, OBTAINED FROM SOURCES BELIEVED BY HOMAX PRODUCTS, INC. TO BE ACCURATE. SINCE THE CONDITIONS AND METHODS OF USE OF OUR PRODUCTS ARE BEYOND OUR CONTROL, WE DISCLAIM ANY AND ALL LIABILITY ARISING OUT OF THE IMPROPER USE OF THESE PRODUCTS OR THE INFORMATION PROVIDED HEREWITH. PROPER SHIPPING NAME: CONSUMER COMMODITY HAZARD CLASS NUMBER: ORM-D MATERIAL SAFETY DATA SHEET 3202 01 00 =========================================================================== Section 1 −− PRODUCT AND COMPANY IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT NUMBER HMIS CODES Health 2 3202 Flammability 4 Reactivity 0 PRODUCT NAME KRYLON* Appliance Epoxy Paint, Almond MANUFACTURER’S NAME EMERGENCY TELEPHONE NO. THE SHERWIN−WILLIAMS COMPANY (216) 566−2917 KRYLON Products Group Cleveland, OH 44115 DATE OF PREPARATION INFORMATION TELEPHONE NO. 24−JAN−06 (800) 832−2541 =========================================================================== Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 14 74−98−6 Propane ACGIH TLV 2500 ppm 760 mm OSHA PEL 1000 ppm 13 106−97−8 Butane ACGIH TLV 800 ppm 760 mm OSHA PEL 800 ppm 19 108−88−3 Toluene ACGIH TLV 50 ppm (Skin) 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL 23 67−64−1 Acetone ACGIH TLV 500 ppm 180 mm ACGIH TLV 750 ppm STEL OSHA PEL 1000 ppm 12 123−86−4 n−Butyl Acetate ACGIH TLV 150 ppm 10 mm ACGIH TLV 200 ppm STEL OSHA PEL 150 ppm OSHA PEL 200 ppm STEL 8 13463−67−7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction =========================================================================== Section 3 −− HAZARDS IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. Continued on page 2 3202 page 2 =========================================================================== EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. =========================================================================== Section 4 −− FIRST AID MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re−use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. =========================================================================== Section 5 −− FIRE FIGHTING MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− FLASH POINT LEL UEL Propellant < 0 F 1.0 12.8 EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self−contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build−up and possible autoignition or explosion when exposed to extreme heat. =========================================================================== Section 6 −− ACCIDENTAL RELEASE MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. Continued on page 3 3202 page 3 =========================================================================== Section 7 −− HANDLING AND STORAGE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated − Do not smoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. =========================================================================== Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1−800−424−LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. Continued on page 4 3202 page 4 =========================================================================== OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. =========================================================================== Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT WEIGHT 6.54 lb/gal 783 g/l SPECIFIC GRAVITY 0.79 BOILING POINT <0 − 264 F <−18 − 128 C MELTING POINT Not Available VOLATILE VOLUME 90 % EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 7.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical) Volatile Weight 57.89 % Less Water and Federally Exempt Solvents =========================================================================== Section 10 −− STABILITY AND REACTIVITY −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STABILITY −− Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur =========================================================================== Section 11 −− TOXICOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, blood forming, cardiovascular and reproductive systems. Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung cancer, however, such exposure levels are not attainable in the workplace. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− TOXICOLOGY DATA Continued on page 5 3202 page 5 =========================================================================== CAS No. Ingredient Name −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 74−98−6 Propane LC50 RAT 4HR Not Available LD50 RAT Not Available 106−97−8 Butane LC50 RAT 4HR Not Available LD50 RAT Not Available 108−88−3 Toluene LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg 67−64−1 Acetone LC50 RAT 4HR Not Available LD50 RAT 5800 mg/kg 123−86−4 n−Butyl Acetate LC50 RAT 4HR 2000 ppm LD50 RAT 13100 mg/kg 13463−67−7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available =========================================================================== Section 12 −− ECOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ECOTOXICOLOGICAL INFORMATION No data available. =========================================================================== Section 13 −− DISPOSAL CONSIDERATIONS −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. =========================================================================== Section 14 −− TRANSPORT INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− No data available. =========================================================================== Section 15 −− REGULATORY INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− 108−88−3 Toluene 19 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. Continued on page 6 3202 page 6 =========================================================================== TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. =========================================================================== Section 16 −− OTHER INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Common Name: KRYLON APPLIANCE EPOXY PAINT, WHITE Manufacturer: SHERWIN-WILLIAMS MSDS Revision Date: 1/6/2007 Grainger Item Number(s): 2X986, 4X590 Manufacturer Model Number(s): MSDS Table of Contents Click the desired link below to jump directly to that section in the MSDS. SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS SECTION 3 - HAZARDS IDENTIFICATION SECTION 4 - FIRST AID MEASURES SECTION 5 - FIRE FIGHTING MEASURES SECTION 6 - ACCIDENTAL RELEASE MEASURES SECTION 7 - HANDLING AND STORAGE SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES SECTION 10 - STABILITY AND REACTIVITY SECTION 11 - TOXICOLOGICAL INFORMATION SECTION 12 - ECOLOGICAL INFORMATION SECTION 13 - DISPOSAL CONSIDERATIONS SECTION 14 - TRANSPORT INFORMATION SECTION 15 - REGULATORY INFORMATION SECTION 16 - OTHER INFORMATION MATERIAL, SAFETY DATA SHEET 3201 01 00 SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER: 3201 PRODUCT NAME: KRYLON* APPLIANCE EPOXY PAINT, WHITE HMIS CODES: HEALTH 2 FLAMMABILITY 3 REACTIVITY 0 MANUFACTURER'S NAME: THE SHERWIN-WILLIAMS COMPANY KRYLON PRODUCTS GROUP CLEVELAND, OH 44115 EMERGENCY TELEPHONE NO.: (216) 566-2917 INFORMATION TELEPHONE NO.: (800) 832-2541 DATE OF PREPARATION: 06-JAN-07 SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS % BY WT CAS NO. INGREDIENT UNITS VAPOR PRESSURE 14 74-98-6 PROPANE ACGIH TLV: 2500 PPM OSHA PEL: 1000 PPM 760 MM 13 106-97-8 BUTANE ACGIH TLV: 800 PPM OSHA PEL: 800 PPM 760 MM 18 108-88-3 TOLUENE ACGIH TLV: 50 PPM (SKIN) OSHA PEL: 100 PPM (SKIN) OSHA PEL: 150 PPM (SKIN) STEL 22 MM 23 67-64-1 ACETONE ACGIH TLV: 500 PPM ACGIH TLV: 750 PPM STEL OSHA PEL: 1000 PPM 180 MM 12 123-86-4 n-BUTYL ACETATE ACGIH TLV: 150 ACGIH TLV: 200 OSHA PEL: 150 OSHA PEL: 200 10 MM 7 13463-67-7 PPM PPM STEL PPM PPM STEL TITANIUM DIOXIDE ACGIH TLV: 10 MG/M3 AS DUST OSHA PEL: 10 MG/M3 TOTAL DUST OSHA PEL: 5 MG/M3 RESPIRABLE FRACTION SECTION 3 - HAZARDS IDENTIFICATION ROUTES OF EXPOSURE: INHALATION OF VAPOR OR SPRAY MIST. EYE OR SKIN CONTACT WITH THE PRODUCT, VAPOR OR SPRAY MIST. EFFECTS OF OVEREXPOSURE: EYES: IRRITATION. SKIN: PROLONGED OR REPEATED EXPOSURE MAY CAUSE IRRITATION. INHALATION: IRRITATION OF THE UPPER RESPIRATORY SYSTEM. MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME OVEREXPOSURE MAY RESULT IN UNCONSCIOUSNESS AND POSSIBLY DEATH. SIGNS AND SYMPTOMS OF OVEREXPOSURE: HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF COORDINATION ARE INDICATIONS OF EXCESSIVE EXPOSURE TO VAPORS OR SPRAY MISTS. REDNESS AND ITCHING OR BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN EXPOSURE. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: NONE GENERALLY RECOGNIZED. CANCER INFORMATION: FOR COMPLETE DISCUSSION OF TOXICOLOGY DATA REFER TO SECTION 11. SECTION 4 - FIRST AID MEASURES EYES: FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. INHALATION: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET. INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY. SECTION 5 - FIRE FIGHTING MEASURES FLASH POINT: PROPELLANT <0 F LEL: 1.0 UEL: 12.8 EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, FOAM UNUSUAL FIRE AND EXPLOSION HAZARDS: CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. APPLICATION TO HOT SURFACES REQUIRES SPECIAL PRECAUTIONS. DURING EMERGENCY CONDITIONS OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. OBTAIN MEDICAL ATTENTION. SPECIAL FIRE FIGHTING PROCEDURES: FULL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS SHOULD BE USED. WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. SECTION 6 - ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: REMOVE ALL SOURCES OF IGNITION. VENTILATE THE AREA. REMOVE WITH INERT ABSORBENT. SECTION 7 - HANDLING AND STORAGE STORAGE CATEGORY: NOT AVAILABLE PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME. VAPORS WILL ACCUMULATE READILY AND MAY IGNITE EXPLOSIVELY. DURING USE AND UNTIL ALL VAPORS ARE GONE: KEEP AREA VENTILATED - DO NOT SMOKE - EXTINGUISH ALL FLAMES, PILOT LIGHTS, AND HEATERS - TURN OFF STOVES, ELECTRIC TOOLS AND APPLIANCES, AND ANY OTHER SOURCES OF IGNITION. CONSULT NFPA CODE. USE APPROVED BONDING AND GROUNDING PROCEDURES. CONTENTS UNDER PRESSURE. DO NOT PUNCTURE, INCINERATE, OR EXPOSE TO TEMPERATURE ABOVE 120F. HEAT FROM SUNLIGHT, RADIATORS, STOVES, HOT WATER, AND OTHER HEAT SOURCES COULD CAUSE CONTAINER TO BURST. DO NOT TAKE INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN. SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE: USE ONLY WITH ADEQUATE VENTILATION. AVOID CONTACT WITH SKIN AND EYES. AVOID BREATHING VAPOR AND SPRAY MIST. WASH HANDS AFTER USING. THIS COATING MAY CONTAIN MATERIALS CLASSIFIED AS NUISANCE PARTICULATES (LISTED "AS DUST" IN SECTION 2) WHICH MAY BE PRESENT AT HAZARDOUS LEVELS ONLY DURING SANDING OR ABRADING OF THE DRIED FILM. IF NO SPECIFIC DUSTS ARE LISTED IN SECTION 2, THE APPLICABLE LIMITS FOR NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 (TOTAL DUST), 3 MG/M3 (RESPIRABLE FRACTION) OSHA PEL 15 MG/M3 (TOTAL DUST), 5 MG/M3 (RESPIRABLE FRACTION). REMOVAL OF OLD PAINT BY SANDING, SCRAPING OR OTHER MEANS MAY GENERATE DUST OR FUMES THAT CONTAIN LEAD. EXPOSURE TO LEAD DUST OR FUMES MAY CAUSE BRAIN DAMAGE OR OTHER ADVERSE HEALTH EFFECTS, ESPECIALLY IN CHILDREN OR PREGNANT WOMEN. CONTROLLING EXPOSURE TO LEAD OR OTHER HAZARDOUS SUBSTANCES REQUIRES THE USE OF PROPER PROTECTIVE EQUIPMENT, SUCH AS A PROPERLY FITTED RESPIRATOR (NIOSH APPROVED) AND PROPER CONTAINMENT AND CLEANUP. FOR MORE INFORMATION, CALL THE NATIONAL LEAD INFORMATION CENTER AT 1-800-424-LEAD (IN US) OR CONTACT YOUR LOCAL HEALTH AUTHORITY. VENTILATION: LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE EXPOSURE TO MATERIALS IN SECTION 2 IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS. REFER TO OSHA STANDARDS 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION: IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW APPLICABLE LIMITS BY VENTILATION, WEAR A PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA FOR PROTECTION AGAINST MATERIALS IN SECTION 2. WHEN SANDING OR ABRADING THE DRIED FILM, WEAR A DUST/MIST RESPIRATOR APPROVED BY NIOSH/MSHA FOR DUST WHICH MAY BE GENERATED FROM THIS PRODUCT, UNDERLYING PAINT, OR THE ABRASIVE. PROTECTIVE GLOVES: NONE REQUIRED FOR NORMAL APPLICATION OF AEROSOL PRODUCTS WHERE MINIMAL SKIN CONTACT IS EXPECTED. FOR LONG OR REPEATED CONTACT, WEAR CHEMICAL RESISTANT GLOVES. EYE PROTECTION: WEAR SAFETY SPECTACLES WITH UNPERFORATED SIDESHIELDS. OTHER PRECAUTIONS: INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS CAN BE HARMFUL OR FATAL. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT: 6.55 LB/GAL 784 G/L SPECIFIC GRAVITY: 0.79 BOILING POINT: <0 - 264 F <-18 - 128 C MELTING POINT: NOT AVAILABLE VOLATILE VOLUME: 89 % EVAPORATION RATE: FASTER THAN ETHER VAPOR DENSITY: HEAVIER THAN AIR SOLUBILITY IN WATER: N.A. pH: 7.0 VOLATILE ORGANIC COMPOUNDS (VOC THEORETICAL - AS PACKAGED): VOLATILE WEIGHT 57.20% LESS WATER AND FEDERALLY EXEMPT SOLVENTS SECTION 10 - STABILITY AND REACTIVITY STABILITY: STABLE CONDITIONS TO AVOID: NONE KNOWN. INCOMPATIBILITY: NONE KNOWN. HAZARDOUS DECOMPOSITION PRODUCTS: BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR SECTION 11 - TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS: NO INGREDIENT IN THIS PRODUCT IS AN IARC, NTP OR OSHA LISTED CARCINOGEN. PROLONGED OVEREXPOSURE TO SOLVENT INGREDIENTS IN SECTION 2 MAY CAUSE ADVERSE EFFECTS TO THE LIVER, URINARY, BLOOD FORMING, CARDIOVASCULAR AND REPRODUCTIVE SYSTEMS. RATS EXPOSED TO TITANIUM DIOXIDE DUST AT 250 MG./M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOSURE LEVELS ARE NOT ATTAINABLE IN THE WORKPLACE. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. TOXICOLOGY DATA: CAS NO. INGREDIENT NAME 74-98-6 PROPANE LC50 RAT 4HR: NOT AVAILABLE LD50 RAT: NOT AVAILABLE 106-97-8 BUTANE LC50 RAT 4HR: NOT AVAILABLE LD50 RAT: NOT AVAILABLE 108-88-3 TOLUENE LC50 RAT 4HR: 4000 PPM LD50 RAT: 5000 MG/KG 67-64-1 ACETONE LC50 RAT 4HR: NOT AVAILABLE LD50 RAT: 5800 MG/KG 123-86-4 n-BUTYL ACETATE LC50 RAT 4HR: 2000 PPM LD50 RAT: 13100 MG/KG 13463-67-7 TITANIUM DIOXIDE LC50 RAT 4HR: NOT AVAILABLE LD50 RAT: NOT AVAILABLE SECTION 12 - ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION: NO DATA AVAILABLE. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS DEFINED UNDER THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE THE APPLICABLE EPA HAZARDOUS WASTE NUMBERS. DO NOT INCINERATE. DEPRESSURIZE CONTAINER. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE/PROVINCIAL, AND LOCAL REGULATIONS REGARDING POLLUTION. SECTION 14 - TRANSPORT INFORMATION NO DATA AVAILABLE. SECTION 15 - REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION: CAS NO. CHEMICAL/COMPOUND % BY WT 108-88-3 TOLUENE 18 % ELEMENT CALIFORNIA PROPOSITION 65: WARNING: THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. TSCA CERTIFICATION: ALL CHEMICALS IN THIS PRODUCT ARE LISTED, OR ARE EXEMPT FROM LISTING, ON THE TSCA INVENTORY. SECTION 16 - OTHER INFORMATION THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CANADIAN CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE MSDS CONTAINS ALL OF THE INFORMATION REQUIRED BY THE CPR. THE ABOVE INFORMATION PERTAINS TO THIS PRODUCT AS CURRENTLY FORMULATED, AND IS BASED ON THE INFORMATION AVAILABLE AT THIS TIME. ADDITION OF REDUCERS OR OTHER ADDITIVES TO THIS PRODUCT MAY SUBSTANTIALLY ALTER THE COMPOSITION AND HAZARDS OF THE PRODUCT. SINCE CONDITIONS OF USE ARE OUTSIDE OUR CONTROL, WE MAKE NO WARRANTIES, EXPRESS OR IMPLIED, AND ASSUME NO LIABILITY IN CONNECTION WITH ANY USE OF THIS INFORMATION. HENKEL CONSUMER ADHESIVES 08/08/00 AVON, OH 44011 TELEPHONE: (440) 937-7000 MATERIAL SAFETY DATA SHEET Page 01 of 04 1.5 OZ PORCELAIN REPAIR-WHITE 01-80234 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Item No.: Part No.: Product Type: 2. 1.5 OZ PORCELAIN REPAIR-WHITE 01-80234 PP-1 COATING COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. Additives aromatic petroleum solvents MB XYLENES* Acrylic resin Proprietary Proprietary 1330-20-7 Proprietary % 55-60 35-40 5-10 trace * This component is listed as a SARA Section 313 Toxic Chemical. Ingredients which have exposure limits Exposure Limits (TWA) Ingredients ACGIH (TLV) OSHA (PEL) OTHER XYLENES 100 ppm TWA 434 mg/m3 100 ppm TWA 435 mg/m3 None Exposure Limits (STEL) Ingredients ACGIH (TLV) OSHA (PEL) XYLENES 150 ppm 651 mg/m3 150 ppm 655 mg/m3 3. HAZARDS IDENTIFICATION Toxicity: Primary Routes of Entry: Signs and Symptoms of Exposure: Existing Conditions Aggravated by Exposure: IRRITANT TOXIC BY INGESTION AND INHALATION SKIN, INGESTION, INHALATION ANESTHETIC IRRITATION OF RESPIRATORY TRACT OR CENTRAL NERVOUS SYSTEM CHARACTERIZED BY HEADACHE DIZZINESS, OF NARCOSIS. PRIMARY IRRITATION OF SKIN OR EYES None known HENKEL CONSUMER ADHESIVES 08/08/00 AVON, OH 44011 TELEPHONE: (440) 937-7000 MATERIAL SAFETY DATA SHEET Product Name: Item No.: 3. Page 02 of 04 1.5 OZ PORCELAIN REPAIR-WHITE 01-80234 HAZARDS IDENTIFICATION Ingredients (continued) Literature Referenced Target Organ and Other Health Effects Carcinogen NTP IARC OSHA Additives No Data NO NO NO aromatic petroleum solvents MB No Data NO NO NO XYLENES CAR CNS IRR KID LIV NO NO NO Acrylic resin No Data NO NO NO ------------------------------------------------------------------------------Abbreviations CAR Cardiac IRR Irritant LIV Liver 4. CNS Central nervous system KID Kidney FIRST AID MEASURES Ingestion: Inhalation: Skin Contact: Eye Contact: DO NOT INDUCE VOMITING. CALL A PHYSICIAN IMMEDIATELY REMOVE TO FRESH AIR. CALL A PHYSICIAN WASH WITH LARGE AMOUNTS OF WATER. FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES SEEK MEDICAL HELP 5. FIRE FIGHTING MEASURES Flash Point: Recommended Extinguishing Agents: Special Firefighting Procedures: Hazardous Products formed by Fire or Thermal Decomp Unusual Fire or Explosion Hazards: Explosive Limits: (% by volume in air)Lower (% by volume in air)Upper 6. <100 DEG F CO2, DRY CHEMICAL ,FOAM Not available OXIDES OF CARBON AND NITROGEN WATER SPRAY MAY BE INEFFECTIVE. TO COOL CONTAINERS. WATER MAY BE USED Not available Not available ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: REMOVE ALL SOURCES OF IGNITION. AVOID BREATHING VAPORS. REMOVE WITH ABSORBENT AND NONSPARKING TOOLS HENKEL CONSUMER ADHESIVES 08/08/00 AVON, OH 44011 TELEPHONE: (440) 937-7000 MATERIAL SAFETY DATA SHEET Product Name: Item No.: 7. 1.5 OZ PORCELAIN REPAIR-WHITE 01-80234 HANDLING AND STORAGE Safe Storage: (Contact Loctite Customer Handling: 8. DO NOT STORE ABOVE 120 DEG F Service 1-800-243-4874 for shelf life information) OBSERVE NORMAL SAFETY PRECAUTIONS FOR FLAMMABLE MATERIALS. AVOID BREATHING VAPORS. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Skin: Ventilation: Safety glasses or goggles. Rubber or plastic gloves. SUFFICIENT TO MAINTAIN VAPOR CONCENTRATION BELOW TLV Not available Respiratory See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Odor: Boiling Point: pH: Solubility in Water: Specific Gravity Volatile Organic Compound (EPA Method 24) Vapor Pressure: Vapor Density: Evaporation Rate (Ether = 1) 10. WHITE LIQUID SOLVENT 280-344 DEG F Does not apply INSOLUBLE 1.1 47.7% <10 MM >1 Not available STABILITY AND REACTIVITY Stability: Hazardous Polymerization: Incompatibility: Conditions to Avoid: Hazardous Decomposition Products (non-thermal): 11. Stable Will not occur NONE KNOWN Not available NONE KNOWN TOXICOLOGICAL INFORMATION See Section 3. 12. Page 03 of 04 ECOLOGICAL INFORMATION No data available HENKEL CONSUMER ADHESIVES 08/08/00 AVON, OH 44011 TELEPHONE: (440) 937-7000 MATERIAL SAFETY DATA SHEET Product Name: Item No.: 13. 1.5 OZ PORCELAIN REPAIR-WHITE 01-80234 DISPOSAL CONSIDERATIONS Recommended methods of disposal: INCINERATE FOLLOWING FEDERAL, STATE, AND LOCAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS EPA Hazardous Waste Number 14. D001 - Hazardous waste per 40CFR 261.21 TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Hazard Class or Division: Identification Number: Marine Pollutant: IATA Proper Shipping Name: Class or Division: UN or ID Number: 15. CONSUMER COMMODITY ORM-D None None FLAMMABLE LIQUIDS NOS XYLENES FLAMMABLE, UN 1993 PG III UN 1993 REGULATORY INFORMATION CA Proposition 65: 16. Page 04 of 04 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: Fire Hazard: Reactivity Hazard: Specific Hazard: 3 3 0 Does not apply Estimated HMIS(R) Code: Health Hazard: Flammability Hazard: Reactivity Hazards: Personal Protection: 3 3 0 See Section 8. NFPA is a registered HMIS is a registered Prepared by: Company: (24hr.) Phone: trademark of the National Fire Protection Assn. trademark of the National Paint and Coatings Assn. Safety, Health and Regulatory Affairs - North America, Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 (860) 571-5100 MATERIAL SAFETY DATA SHEET DATE PRINTED: MAY 12, 2005 MSDS NO. SANDBLOCK Sanding Block SECTION OUTBOUND 1. CHEMICAL PRODUCT AND COMPANY INFORMATION PRODUCT NAME Sanding Block TRADE NAME MANUFACTURER(4) Saint-Gobain Abrasives, Inc. 1 New Bond St Worcester, MA. 01615 (800) 543-4335 REVISION DATE 1/20/2005 MSDS PRINT FORMAT NUSA SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS SUBSTANCE DESCRIPTION PERCENT CAS# -------------------------------------------------------------------------------Aluminum Oxide, Non-fibrous 20.000- 30.000 1344-28-1 Polyurethane polymer 5.000- 10.000 68400-67-9 Unvulcanized rubber 10.000- 20.000 Silicon Carbide 35.000- 45.000 409-21-2 OTHER Not Applicable SECTION 3. HAZARDS IDENTIFICATION INHALATION ACUTE EXPOSURE EFFECTS Dust may be slightly irritating to eyes and respiratory tract at high concentrations. INHALATION CHRONIC EXPOSURE EFFECTS May affect breathing capacity. EYE CONTACT ACUTE EXPOSURE EFFECTS Dust may irritate eyes. SKIN CONTACT ACUTE EXPOSURE EFFECTS Some may experience skin irritation from dust. INGESTION ACUTE EXPOSURE EFFECTS No known adverse effects, but ingestion not recommended. SECTION 4. FIRST AID MEASURES INHALATION Remove to fresh air. If breathing has stopped, give artificial respiration. Get medical attention immediately. SKIN CONTACT Wash affected areas with soap and water. Obtain medical assistance. EYE CONTACT Wash with large amounts of water. Obtain first aid and medical assistance, if needed. INGESTION Call poison control center, hospital emergency room or physician immediately. SECTION 5. FIRE FIGHTING MEASURES FIRE FIGHTING PROCEDURES Not Applicable HAZARDOUS PRODUCTS/COMBUSTION None. HAZARD RATING SOURCE NFPA HEALTH 1 FLAMMABILITY 0 REACTIVITY 0 OTHER SECTION 6. ACCIDENTAL RELEASE MEASURES CLEAN-UP Follow normal clean up procedures. SECTION 7. HANDLING AND STORAGE HANDLING Handle with adequate ventilation for nuisance dust. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION VENTILATION PROTECTION Recommend using local exhaust ventilation when general ventilation is not keeping the airborne concentration below the TLV. RESPIRATORY PROTECTION Respirators are required when airborne contaminant levels exceed the TLV(s). EYE PROTECTION Always WEAR SAFETY GLASSES or some type of eye protection while sanding. OTHER PROTECTION Use of this product may create elevated sound levels. Hearing protection should be worn where required (see OSHA 29 CFR 1910.134 and other applicable regulations). SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE & ODOR Solid article. Odorless. SECTION 10. STABILITY AND REACTIVITY INCOMPATIBILITIES Avoid acids of all types with a pH < 4.0. DECOMPOSITION In use, dust and decomposing odors may be generated. In most cases, the material removed from the workplace will be significantly greater than the sandpaper components. SECTION 11. TOXICOLOGICAL INFORMATION CARCINOGENICITY Not Applicable LD50/LC50 Values are not appropriate or available. SECTION 12. ECOLOGICAL INFORMATION CHEMICAL FATE Not Applicable SECTION 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL Use standard landfill methods consistent with applicable Federal, State, Provincial and local laws. SECTION 14. TRANSPORT INFORMATION HAZARD CLASS This product is not hazardous as defined by the Department of Transportation.(USA) This product is "Not Regulated" under the Transportation of Dangerous Goods Act. (CAN) SECTION 15. REGULATORY INFORMATION -------------------------------------------------------------------------------- EXPOSURE LIMITS/REGULATORY INFORMATION SUBSTANCE DESCRIPTION UNITS OSHA ACGIH MOL ________________________________________________________________________________ Aluminum Oxide, Non-fibrous MG/M3 15.0000 10.0000 10.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 10.0000 10.0000 10.0000 Polyurethane polymer PPM Unvulcanized rubber Silicon Carbide MG/M3 LEGEND: EXPOSURE LIMIT DESCRIPTIONS CA PROP 65 Not Applicable TSCA Section 8(b) - Inventory Status All components of this product are registered under the regulations of the Toxic Substance Control Act. DOMESTIC SUBSTANCE LIST All components of this product are found on the Domestic Substance List. SECTION 16. OTHER INFORMATION DISCLAIMER ___________________________________________________________________________ KEY TO ABBREVIATIONS: EQ=EQual AP=APproximately = LT=Less Than TR=TRace GT=Greater Than ND=No Data available Click here to go back to MSDS 1301 E. 9th Street, #700 Cleveland OH 44114 (800) 726-9626 Barnes Distribution Material Safety Data Sheet MSDS Form No. : MSDS22034 Item No. : 22034, 22034 **** MATERIAL SAFETY DATA SHEET **** FEL-PRO ALUMINUM PUTTY EPOXY (HARDENER) Part # MSDS22034 **** SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION **** MSDS Name: FEL-PRO ALUMINUM PUTTY EPOXY (HARDENER) Product CAS: (none) Product Code: Synonyms: 22034; FEL-PRO ALUMINUM PUTTY EPOXY (HARDENER) Company Identification: Name: BOWMAN DISTRIBUTION Address: 1301 E. 9TH ST., ST. 700 Address: City: CLEVELAND State: OH Zip: 44114 For information, call: HEALTH ISSUES AND TECHNICAL INFORMATION (8AM-5PM ET): 1-216-416-7200 X 5 60 Emergency Number: Emergency Agency: CHEMTREC (24 HOURS EVERYDAY) / ROCKY MOUNTAIN POISON CONTROL CENTER (24 HOURS EVERYDAY) Number: 800-424-9300 / 303-623-5716 MSDS Creation Date: 1/5/2005 Supersedes Date: 1/1/2003 **** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS **** Chemical Name ALUMINUM NONYL PHENOL POLYOXYALKLENEAMINE AMINOETHYLPIPERAZINE CAS 7429-90-5 25154-52-3 9046-10-0 140-31-8 MIN 15 5 10 10 MAX 15 5 10 10 BENZYL ALCOHOL BISPHENOL-A DIMER/TOFA, REACTION PRODUCTS W/TETA TRIETHYLENETETRAMINE AMORPHOUS SILICON DIOXIDE Miscellaneous: INGREDIENTS 100-51-6 80-05-7 68082-29-1 112-24-3 112945-52-5 5 10 40 25 3 5 10 40 25 3 % WT/WT LESS THAN ALUMINUM 15 NONYL PHENOL 5 POLYOXYALKLENEAMINE 10 AMINOETHYLPIPERAZINE 10 BENZYL ALCOHOL 5 BISPHENOL-A 10 DIMER/TOFA, REACTION PRODUCTS W/ TETA 40 TRIETHYLENETETRAMINE 25 NOTE: SEE BELOW FOR EXPOSURE LIMIT DATA FOR THESE INGREDIENTS INGREDIENT OSHA PEL ACGIH TLV OTHER LIMITS ALUMINUM NONYL PHENOL POLYOXYALKLENEAMINE AMINOETHYLPIPERAZINE BENZYL ALCOHOL BISPHENOL-A DIMER/TOFA, REACTION PRODUCTS W/ TETA TRIETHYLENETETRAMINE 10 MG/M3-TD N.E. N.E. N.E. N.E. N.E. 10 MG/M3-TD N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. Lbs of VOC per Gallon Coating (minus water): 0 Coating Density (lbs/gal): 0 Solvent Density (lbs/gal): 0 Percent Solvent (volume): 0 Percent Solids (volume): 0 Percent Water (volume): 0 **** SECTION 3 - HAZARDS IDENTIFICATION **** NFPA: Health: Fire: Reactivity: Other: HMIS: Health: 3 Fire: 1 Reactivity: 0 Special Protection: Miscellaneous: EMERGENCY OVERVIEW APPEARANCE AND ODOR: SILVERY; HMIS AND NFPA HAZARD RATINGS: CATEGORY NFPA MILD AMMONIA-LIKE ODOR. ACUTE HEALTH N.D. FLAMMABILITY N.D. REACTIVITY N.D. PERSONAL PROT./SPECIFIC HAZ.: * / N.D. *REFER TO SECTION 8. POTENTIAL HEALTH EFFECTS Target Organs: PRIMARY ROUTES OF EXPOSURE: INHALATION, INGESTION, SKIN CONTACT, EYE CONTACT, SKIN ABSORPTION. Eye: HEALTH HAZARDS - ACUTE EFFECTS: CORROSIVE TO THE EYES AND MAY CAUSE SEVERE DAMAGE INCLUDING BLINDNESS. PRODUCT VAPOR CAN CAUSE LACRIMATION, CONJUNCTIVITIS, AND CORNEAL EDEMA WHEN ABSORBED INTO THE TISSUE OF THE EYE. CORNEAL EDEMA MAY GIVE RISE TO A PERCEPTION OF "BLUE HAZE" OR "FOG" AROUND LIGHTS. THE EFFECT IS TRANSIENT AND HAS NO KNOW RESIDUAL EFFECT. Skin: HEALTH HAZARDS - ACUTE EFFECTS: SUBSTANCE CAN BE ABSORBED THROUGH THE SKIN IN HARMFUL AMOUNTS. STRONG SKIN SENSITIZER. PROLONGED CONTACT MAY CAUSE CHEMICAL BURNS AND BLISTERING. Ingestion: HEALTH HAZARDS - ACUTE EFFECTS: MODERATELY TOXIC. CAN BURN MOUTH, THROAT AND STOMACH, WITH NAUSEA, SEVERE PAIN, AND VOMITING. Inhalation: HEALTH HAZARDS - ACUTE EFFECTS: LIQUID ASPIRATED INTO LUNGS MAY CAUSE SERIOUS INJURY OR DEATH. POTENTIAL RESPIRATORY SENSITIZER. PROLONGED OR REPEATED INHALATION MAY CAUSE LUNG DAMAGE. PROLONGED INHALATION CAUSES INFLAMMATION AND ULCERATION OF THE RESPIRATORY TRACT. Miscellaneous: CONDITIONS TO AVOID: DO NOT GET IN EYES, ON SKIN OR CLOTHING. BREATHING DUST, VAPOR, MIST OR GAS. DO NOT TAKE INTERNALLY. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: AVOID NO DATA. CHRONIC HAZARDS: PREEXISTING PULMONARY AND DERMATOLOGICAL DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO HAZARDOUS COMPONENTS. PROLONGED OR REPEATED OVEREXPOSURE MAY CAUSE LUNG DAMAGE. **** SECTION 4 - FIRST AID MEASURES **** Eye: IMMEDIATELY FLUSH WITH PLENTY OF WATER. AFTER INITIAL FLUSHING, REMOVE ANY CONTACT LENSES AND CONTINUE FLUSHING FOR AT LEAST 15 MINUTES. HAVE EYES IMMEDIATELY EXAMINED AND TESTED BY MEDICAL PERSONNEL. Skin: IMMEDIATELY FLUSH AFFECTED AREA (S) THOROUGHLY WITH WATER AT LEAST 15 MINUTES. REMOVE AND 0WASH CONTAMINATED CLOTHING. CONTAMINATED LEATHER ARTICLES SHOULD BE DISPOSED OF. OBTAIN 1MEDICAL ATTENTION. Ingestion: IF SWALLOWED, DO NOT INDUCE VOMITING. MILK. CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. AN UNCONSCIOUS PERSON. GIVE VICTIM A GLASS OF WATER OR NEVER GIVE ANYTHING BY MOUTH TO Inhalation: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION. Notes to Physician: **** SECTION 5 - FIRE FIGHTING MEASURES **** Unusual Fire and Explosion Hazards: FINELY DIVIDED DUST IN AIR MAY PRESENT EXPLOSION HAZARD. PREVENT DUST BUILD-UP. CLOSED CONTAINERS MAY RUPTURE OR EXPLODE (DUE TO PRESSURE BUILD-UP) WHEN EXPOSED TO EXTREME HEAT. IRRITATING AND/OR TOXIC GASES OR FUMES MAY BE GENERATED BY THERMAL DECOMPOSITION OR COMBUSTION. Special Fire Fighting Procedures: USE NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. USE WATER 0TO COOL EXPOSED CONTAINERS. WATER STREAM DIRECTED INTO FIRE MAY CAUSE FROTHING WITH SUBSEQUENT 1SPREAD OF FLAME. Extinguishing Media: ALCOHOL FOAM, CO2, WATER FOG, DRY CHEMICAL, FOAM. Flash Point: AND METHOD: 200 F (SETAFLASH CLOSED CUP). Flammable Limits: Lower Limit: LEL(%): N.A. Upper Limit: UEL(%): N.A. AutoIgnition Temperature: (O F): NO DATA. General Information: FLAMMABILITY LIMITS (%): N.A. HAZARDOUS COMBUSTION PRODUCTS: NO DATA. **** SECTION 6 - ACCIDENTAL RELEASE MEASURES **** Disposal: DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS. DECONTAMINATE OR DISPOSE OF CONTAMINATED CLOTHING AND ARTICLES. WASH SPILL AREA WITH SOAP AND WATER. RCRA HAZARDOUS WASTE NUMBER: NOT REGULATED. Spills/Leaks: WEAR APPROPRIATE PROTECTIVE EQUIPMENT DURING CLEANUP. ABSORB WITH INERT MATERIAL, SUCH AS CLAY. SWEEP OR SHOVEL INTO LOOSELY-COVERED WASTE CONTAINER AND REMOVE TO APPROPRIATE WASTE AREA. **** SECTION 7 - HANDLING and STORAGE **** Handling: WASH THOROUGHLY AFTER HANDLING. USE WITH ADEQUATE VENTILATION. AVOID BREATHING DUST, VAPOR, MIST OR GAS. DO NOT GET IN EYES, ON SKIN OR CLOTHING. DO NOT TAKE INTERNALLY. FOR INDUSTRIAL USE ONLY. STORING: KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP OUT OF REACH OF CHILDREN. Storage: **** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION **** Engineering Controls: LOCAL EXHAUST NEEDED TO CONTROL VAPOR OR DUST LEVELS TO BELOW LOWEST COMPONENT TLV. Eyes: CHEMICAL SPLASH GOGGLES. FACE SHIELD. Skin: CLEAN CLOTHING TO COVER SKIN NITRILE GLOVES. TEFLON GLOVES. VITON GLOVES. Clothing: OTHER PROTECTIVE EQUIPMENT: BUTYL RUBBER GLOVES. NEOPRENE GLOVES. ACCESSIBLE EYE WASH AND SAFETY SHOWER. Respirators: NONE NORMALLY REQUIRED UNDER GENERAL VENTILATION. IF TLV/PEL IS EXCEEDED, IF USE IS PERFORMED IN A POORLY VENTILATED SPACE, OR IF INHALATION EFFECTS OCCUR, USE NIOSH-APPROVED VAPOR CARTRIDGE RESPIRATOR IN ACCORDANCE WITH APPLICABLE HEALTH AND SAFETY REGULATIONS AND MANUFACTURER'S RECOMMENDATIONS. **** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES **** Appearance/Odor: pH: ALK. Vapor Pressure: NO DATA Vapor Density: (AIR = 1): GT 1 HEAVIER THAN AIR Evaporation Rate: (N-BUTYL ACETATE=1): LT 1. HEAVIER THAN AIR Viscosity: HIGH Boiling Point: 278-560 F Freezing/Melting Point: FREEZING POINT: NO DATA. Decomposition Temperature: NA Solubility: IN WATER: SLIGHT Specific Gravity: 1.07 Molecular Formula: NA Molecular Weight: NA Miscellaneous: VOC (G/LITER): 0 MAX. % VOC BY WEIGHT: 0%.; METHOD USED: CALCULATED. COEFF. OF WATER/OIL DISTRIBUTION: NO DATA. **** SECTION 10 - STABILITY AND REACTIVITY **** Chemical Stability: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS. Conditions to Avoid: NO INFORMATION. Incompatibilities with Other Materials: STRONG LEWIS OR MINERAL ACIDS. STRONG BASES OR OXIDANTS. REACTION WITH EPOXY RESINS AND ISOCYANATES IN LARGE AMOUNTS OR UNDER UNCONTROLLED CONDITIONS RELEASES CONSIDERABLE HEAT AND MAY RELEASE ACRID FUMES. ALDEHYDES, KETONES, ACRYLATES, AND ORGANIC HALIDES. CLEANING SOLUTION SUCH AS CHROMERGE (SULFURIC ACID/ DICHROMATE) AND AQUA REGIA. REACTION WITH SOME NITRATES OR NITRITES CAN CAUSE THE FORMATION OF CANCERCAUSING NITROSOAMINES. EPOXIDES. SULFURIC ACID, HBR + IRON WHEN IT HEATS ABOVE 100 DEGREES C. Hazardous Decomposition Products: OXIDES OF CARBON. OXIDES OF NITROGEN, AMMONIA. IRRITATION ALDEHYDES AND KETONES. Hazardous Polymerization: WILL NOT OCCUR UNDER NORMAL CONDITIONS. **** SECTION 11 - TOXICOLOGICAL INFORMATION **** Toxicological Information: CARCINOGENICITY: NONE. INGREDIENT NTP OSHA IARC ALUMINUM NONYL PHENOL POLYOXYALKLENEAMINE BENZYL ALCOHOL BISPHENOL-A DIMER/TOFA, REACTION PRODUCTS W/ TETA TRIETHYLENETETRAMINE NO NO NO NO NO NO NO NO NO NO NO NO NO NO NO NO NO NO NO NO NO COMPONENT TOXICOLOGICAL INFORMATION: INGREDIENT LD 50 / LC50 ALUMINUM: NO INFORMATION / NO INFORMATION NONYL PHENOL: SKIN (RBT ) 2140 MG/KG / NO INFORMATION. POLYOXYALKLENEAMINE: DERM (RBT) 800 MG/KG / NO INFORMATION BENZYL ALCOHOL: ORAL (RAT) 1230 MG/KG / NO INFORMATION BISPHENOL-A: DERM (RBT) 3000 MG/KG / 200 MG/I/H DIMER/TOFA, REACTION PRODUCTS W/ TETA: NO INFORMATION / NO INFORMATION TRIETHYLENETETRAMINE: DERM (RBT) 805 MG/KG / NO INFORMATION. **** SECTION 12 - ECOLOGICAL INFORMATION **** Ecological Information: NO DATA AVAILABLE. **** SECTION 13 - OTHER PRECAUTIONS **** Other Precautions: Work/Hygienic Practices: FOLLOW GENERAL INDUSTRIAL SAFETY PRACTICES DURING USE. DO NOT SMOKE OR EAT DURING USE. WASH AFTER HANDLING. DO NOT REUSE EMPTY CONTAINERS. FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER CONTAINER IS EMPTIED. **** SECTION 14 - TRANSPORT INFORMATION **** Transportation Information: DOT SHIPPING NAME: N.A. HAZARD CLASS OR DIVISION: CARTON MARKINGS: N.A. IDENTIFICATION NUMBER: PACKING GROUP: LABELS: N.A. N.A. N.A. N.A. Label Information: **** SECTION 15 - REGULATORY INFORMATION **** Regulatory Information: COMPONENT RCRA CLASSIFICATIONS: NOT REGULATED. TSCA: THE CHEMICAL SUBSTANCES IN THIS PRODUCT ARE ON THE TSCA SECTION 8 INVENTORY. THIS PRODUCT CONTAINS THE FOLLOWING CHEMICALS SUBJECT TO REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE U.S.: NONYL PHENOL (25154-52-3), BISPHENOL-A (80-05-7). PENNSYLVANIA RIGHT TO KNOW: THE FOLLOWING ARE NON-HAZARDOUS, BUT ARE PRESENT IN THE PRODUCT AT GREATER THAN 3 %: AMORPHOUS SILICON DIOXIDE (CAS NUMBER 112945-52-5). NJ RIGHT TO KNOW: THE FOLLOWING MATERIALS ARE NON-HAZARDOUS, BUT ARE AMONG THE TOP FIVE COMPONENTS IN THIS PRODUCT: AMORPHOUS SILICON DIOXIDE (CAS NUMBER 112945-52-5). CANADIAN WHMIS CLASS: E, D2B. CHIP SUPPLY LABEL SAFETY PHRASES: CHIP SUPPLY LABEL RISK PHRASES: CHIP SUPPLY LABEL SYMBOLS: 36/37/39 34 43 26 21 CORROSIVE, C SARA TITLE III: HAZARD CATEGORIES: ACUTE HEALTH: YES CHRONIC HEALTH: YES FIRE HAZARD: YES PRESSURE HAZARD: YES REPORTABLE INGREDIENTS: SECTION 302/303: NONE. SECTION 313: NONE. CERCLA RQ: NONE KNOWN. **** SECTION 16 - ADDITIONAL INFORMATION **** Additional Information: N.A. NOT APPLICABLE N.D. NOT DETERMINED N.E. NOT ESTABLISHED **** MATERIAL SAFETY DATA SHEET **** FEL-PRO ALUMINUM PUTTY EPOXY (RESIN) Part # MSDS22034 **** SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION **** MSDS Name: FEL-PRO ALUMINUM PUTTY EPOXY (RESIN) MATERIAL SAFETY DATA SHEET S O S PRODUCTS COMPANY INC P. O. Box 47 East Greenville, Pa. 18041 Phone (215)-679-6262 (215)-679-6263 PAGE 1 -------------------------------------------------------------------------------SECTION I - GENERAL INFORMATION -------------------------------------------------------------------------------Product Code: EP Revision Date: July 26, 2005 Identification: EPOXY PUTTY -------------------------------------------------------------------------------SECTION II - HAZARDOUS INGREDIENTS -------------------------------------------------------------------------------PEL TLV TLV INGREDIENT: % PPM PPM MG/M3 LEL CAS. NO -------------------------------------------------------------------------------TRI(DIMETHYLAMINOMETHYL) PH 00090-72-2 EPOXY RESIN 250-68-386 -------------------------------------------------------------------------------2,4,6, TRI (DIMETHYLAMINOMETHYL) PHENOL ACGIH-5PPM EPOXY RESIN (DIGLYCIDYL ETHER OF BISPHENOL A) ACGIH - 19.8G/KG (ORAL LD50 RABBIT) ACGIH - 20G/KG (DERMAL LD50 RABBIT) -------------------------------------------------------------------------------Carcinogenicity: This product is NOT considered to be a carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, or the Occupational Safety and Health Administration. -------------------------------------------------------------------------------SECTION III - PHYSICAL CHARACTERISTIC -------------------------------------------------------------------------------Boiling Point: N/A Specific Gravity: 1.9 Vapor Pressure: N/A Melting Point: N/A Vapor Density: N/A Evaporation Rate: NONE Solubility in Water: NOT SOLUBLE Odor and Appearance: 2 COMPONENTS IN MASTIC FORM. ODOR: MERCAPTAN -------------------------------------------------------------------------------SECTION IV - FIRE AND EXPLOSION HAZARD DATA -------------------------------------------------------------------------------Flash Point: NONE LEL: N/A Flammable Limits: N/A UEL: N/A Extinguishing Media: WATER SPRAY, FOAM, CO2 AND DRY CHEMICAL Special Fire Fighting Procedures: CONVENTIONAL METHODS Unusual Fire and Explosion Hazards: N/A -------------------------------------------------------------------------------SECTION V - REACTIVITY DATA -------------------------------------------------------------------------------This product is STABLE Conditions to avoid: NONE Incompatibility: NONE Hazardous Decomposition: CO, ALDEHYDES, ACIDS, SO2 AND N2 MAY BE FORMED. Hazardous Polymerization: WILL NOT OCCUR. -------------------------------------------------------------------------------SECTION VI - HEALTH HAZARD DATA -------------------------------------------------------------------------------Routes of Entry: Inhalation? NO Skin? YES - SECONDARY Ingestion? YES - SECONDARY Health Hazards (Acute and Chronic): NONE KNOWN OR ESTABLISHED Carcinogenicity: NTP? NO IARC Monographs? NO OSHA Regulated? Signs and Symptoms of Exposure: NO NONE Medical Conditions Generally Aggravated by Exposure: NONE Emergency and First Aid Procedures: SKIN: WASH WITH SOAP AND WATER. EYES: FLUSH 15 MINUTES; GET MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR, INGESTION: INDUCE VOMITING. CALL PHYSICIAN IMMEDIATELY. -------------------------------------------------------------------------------SECTION VII - HANDLING PRECAUTIONS -------------------------------------------------------------------------------Steps to be Taken if Material is Released or Spilled: SWEEP UP IN NORMAL MANNER Waste Disposal Method: NON-HAZARDOUS LANDFILL Precautions to be Taken in Handling and Storage: NONE Other Precautions: NONE -------------------------------------------------------------------------------SECTION VIII - CONTROL MEASURES -------------------------------------------------------------------------------Respiratory Protection: NONE REQUIRED FOR NORMAL USE Ventilation Required: ADEQUATE Protective Gloves: WEAR POLYETHYLENE GLOVES FOR PROLONGED USE. Eye Protection: WEAR SAFETY GOGGLES Other Protective Equipment: NONE REQUIRED Work/Hygienic Practices: WASH THOROUGHLY AFTER USING. -----------------------------------------------------------------------------The above information pertains to the product as it is currently formulated and is based upon the information available at this time. Additions of reducers or other additives to this product may substantially alter the composition and subsequent hazards of the product. Since conditions of use are outside of our control, we make no warranties, either expressed or implied, and assume no liability in connection with any use of this information. |-------------------------------------------------------| | M A T E R I A L S A F E T Y D A T A S H E E T | |-------------------------------------------------------| |-------------------------------------------------------------------------| | SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION | |-------------------------------------------------------------------------| PRODUCT NAME UPC NUMBER PRODUCT USE/CLASS : EASY SOLUTIONS - Tile Grout Repair : 7079810726, 7079810731 : Tile Grout Repair MANUFACTURER: DAP INC. 2400 BOSTON STREET BALTIMORE, MD 21224 24 HOUR EMERGENCY: TRANSPORTATION: 1-800-535-5053 (352-323-3500) MEDICAL : 1-800-327-3874 (513-636-5118) PREPARE DATE : 10/16/2000 REVISION NO. : 1 REVISION DATE: 06/11/2001 GENERAL INFORMATION: DAP INC. : 1-888-DAP-TIPS (1-888-327-8477) |-------------------------------------------------------------------------| | SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |-------------------------------------------------------------------------| WT/WT % ITEM ------------ CHEMICAL NAME ------------CAS NUMBER RANGE --------------------------------------------------------------------------01 02 03 Ethylene glycol Calcium Carbonate Mineral spirits 107-21-1 1317-65-3 8052-41-3 1.0-5.0 % 70.0-75.0 % 1.0-5.0 % ---------------------- EXPOSURE LIMITS -------------------ACGIH OSHA COMPANY ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN --------------------------------------------------------------------------01 02 03 N.E. 10 mg/m3 100 ppm 50 ppm* N.E. N.E. N.E. 15 mg/m3 100 ppm 50 ppm N.E. N.E. N.E. N.E. N.E. NO NO NO (See Section 16 for abbreviation legend), * - TLV-Ceiling Value Remaining ingredients are not considered hazardous per the OSHA Hazard Communication Standard. Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); limits may vary between states. (Continued on Page 2) --------------------------------------------------------------------------- Product Name: EASY SOLUTIONS - Tile Grout Repair Revision Date: 06/11/2001 Page 2 |-------------------------------------------------------------------------| | SECTION 3 - HAZARDS IDENTIFICATION | |-------------------------------------------------------------------------| EMERGENCY OVERVIEW: CAUTION! May irritate eyes, skin, nose, and respiratory tract. Harmful if inhaled or swallowed. POTENTIAL HEALTH EFFECTS: EFFECTS OF OVEREXPOSURE - EYE CONTACT: May cause eye irritation. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation. Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). EFFECTS OF OVEREXPOSURE - INHALATION: Vapor harmful if inhaled. Vapor may irritate nose and upper respiratory tract. Vapor inhalation may affect the brain or nervous system causing dizziness, headache or nausea. EFFECTS OF OVEREXPOSURE - INGESTION: This fatal if swallowed. Ingestion of ethylene respiratory and/or cardiac failure as well ingested, this product may cause vomiting, respiration. material may be harmful or glycol in excess may lead to as kidney and liver damage. If diarrhea, and depressed EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated permanent brain and nervous system damage with prolonged and repeated occupational overexposure to solvents. Ingestion of Ethylene Glycol in excess may lead to respiratory and cardiac failure, and kidney and liver damage. MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY CONTACT: PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT None known. INHALATION |-------------------------------------------------------------------------| | SECTION 4 - FIRST AID MEASURES | |-------------------------------------------------------------------------| EYE CONTACT: Flush with large quantities of water until irritation subsides. If irritation persists, call Medical in Section I. SKIN CONTACT: Wash with soap and water. If irritation persists, call Medical in Section I. INHALATION: INGESTION: COMMENTS: Remove to fresh air. Call Medical in Section I immediately. DO NOT INDUCE VOMITING. Call Medical in Section I immediately. None. (Continued on Page 3) --------------------------------------------------------------------------- Product Name: EASY SOLUTIONS - Tile Grout Repair Revision Date: 06/11/2001 Page 3 |-------------------------------------------------------------------------| | SECTION 5 - FIRE FIGHTING MEASURES | |-------------------------------------------------------------------------| FLASH POINT: >200 F (SETAFLASH CLOSED CUP) LOWER EXPLOSIVE LIMIT: N.A. UPPER EXPLOSIVE LIMIT: N.A. AUTOIGNITION TEMPERATURE: N.E. EXTINGUISHING MEDIA: CO2 DRY CHEMICAL FOAM UNUSUAL FIRE AND EXPLOSION HAZARDS: Containers may burst if exposed to extreme heat. Eliminate sources of ignition: heat, electrical equipment, sparks, and flames. Do not put in contact with oxidizing or caustic materials. SPECIAL FIREFIGHTING PROCEDURES: Full protective equipment, including self-contained breathing apparatus, is recommended to protect from combustion products. Cool exposed containers with water. |-------------------------------------------------------------------------| | SECTION 6 - ACCIDENTAL RELEASE MEASURES | |-------------------------------------------------------------------------| SPILL OR LEAK PROCEDURES: Dike spill area. Absorb remaining liquid with absorbent material and place into containers. |-------------------------------------------------------------------------| | SECTION 7 - HANDLING AND STORAGE | |-------------------------------------------------------------------------| HANDLING INFORMATION: KEEP OUT OF REACH OF CHILDREN. Avoid skin and eye contact. Avoid breathing vapors. Use only in a well ventilated area. STORAGE INFORMATION: Store away from caustics and oxidizers. Keep away from heat, spark, and flame. Keep containers tightly closed when not in use. Keep containers from excessive heat and freezing. Do not store at temperatures above 120 degrees F. OTHER PRECAUTIONS: Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal. Do not take internally. |-------------------------------------------------------------------------| | SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |-------------------------------------------------------------------------| ENGINEERING CONTROLS: Provide sufficient mechanical ventilation (local or general exhaust) to maintain exposure below PEL and TLV. Vapors are heavier than air and will collect in low areas. Check all low areas (basements, sumps, etc.) for vapor before entering. (Continued on Page 4) --------------------------------------------------------------------------- Product Name: EASY SOLUTIONS - Tile Grout Repair Revision Date: 06/11/2001 Page 4 |-------------------------------------------------------------------------| | SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |-------------------------------------------------------------------------| RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. If 8 hour exposure limit or value is exceeded for any component, use an approved NIOSH/OSHA respirator. Consult your safety equipment supplier and the OSHA regulation, 29 CFR 1910.134 for respirator requirements. A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. EYE PROTECTION: SKIN PROTECTION: Goggles or safety glasses with side shields. Solvent impervious gloves. OTHER PROTECTIVE EQUIPMENT: if body contact may occur. HYGIENIC PRACTICES: Provide eyewash and solvent impervious apron Remove contaminated clothing and wash before reuse. |-------------------------------------------------------------------------| | SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |-------------------------------------------------------------------------| BOILING RANGE ODOR APPEARANCE SOLUBILITY IN H2O SPECIFIC GRAVITY VAPOR PRESSURE PHYSICAL STATE : : : : : : : 210 - 220 F Sl. amine odor White paste Negligible 1.9388 17.5 mm Hg@68F. Paste VAPOR DENSITY : Is heavier than air EVAPORATION RATE: Is slower than Butyl Acetate (See Section 16 for abbreviation legend) |-------------------------------------------------------------------------| | SECTION 10 - STABILITY AND REACTIVITY | |-------------------------------------------------------------------------| CONDITIONS TO AVOID: INCOMPATIBILITY: Excessive heat and freezing. Strong oxidizers and caustics. HAZARDOUS DECOMPOSITION PRODUCTS: NOx Normal decomposition products, i.e. COx, HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. |-------------------------------------------------------------------------| | SECTION 11 - TOXICOLOGICAL PROPERTIES | |-------------------------------------------------------------------------| No product or component toxicological information is available. (Continued on Page 5) --------------------------------------------------------------------------- Product Name: EASY SOLUTIONS - Tile Grout Repair Revision Date: 06/11/2001 Page 5 |-------------------------------------------------------------------------| | SECTION 12 - ECOLOGICAL INFORMATION | |-------------------------------------------------------------------------| No Information. |-------------------------------------------------------------------------| | SECTION 13 - DISPOSAL CONSIDERATIONS | |-------------------------------------------------------------------------| WASTE MANAGEMENT/DISPOSAL: Dispose of according to Federal, State, and Local Standards. This product does not meet the definition of a hazardous waste according to U.S. EPA Hazardous Waste Management Regulations, 40 CFR Section 261. However, it is recommended that discarded material be incinerated at a permitted facility. State and Local regulations/ restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA WASTE CODE - If discarded (40 CFR 261): None. |-------------------------------------------------------------------------| | SECTION 14 - TRANSPORTATION INFORMATION | |-------------------------------------------------------------------------| DOT PROPER SHIPPING NAME: Not Regulated by D.O.T. DOT HAZARD CLASS: NONE DOT UN/NA NUMBER: NONE PACKING GROUP: NONE Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may apply if shipped via other modes of transportation and/or non-domestic destinations. |-------------------------------------------------------------------------| | SECTION 15 - REGULATORY INFORMATION | |-------------------------------------------------------------------------| U.S. FEDERAL REGULATIONS: AS FOLLOWS OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200) SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: ----------- CHEMICAL NAME ----------Ethylene glycol CAS NUMBER 107-21-1 WT/WT % RANGE 1.0-5.0 % TOXIC SUBSTANCES CONTROL ACT: This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: ----------- CHEMICAL NAME ----------OLEIC ACID 1,2,4-TRIMETHYLBENZENE CAS NUMBER 112-80-1 95-63-6 (Continued on Page 6) --------------------------------------------------------------------------- Product Name: EASY SOLUTIONS - Tile Grout Repair Revision Date: 06/11/2001 Page 6 |-------------------------------------------------------------------------| | SECTION 15 - REGULATORY INFORMATION | |-------------------------------------------------------------------------| NEW JERSEY RIGHT-TO-KNOW: The following materials are non-hazardous, but are among the top five components in this product: ----------- CHEMICAL NAME ----------Water Acrylic Polymer CAS NUMBER 7732-18-5 TSRN-51-0344944-1943 PENNSYLVANIA RIGHT-TO-KNOW: The following non-hazardous ingredients are present in the product at greater than 3%: ----------- CHEMICAL NAME ----------Water Acrylic Polymer CAS NUMBER 7732-18-5 Proprietary CALIFORNIA PROPOSITION 65: WARNING: The chemical(s) noted below and contained in this product, are known to the state of California to cause cancer: ----------- CHEMICAL NAME ----------Chlorothalonil CAS NUMBER 1897-45-6 INTERNATIONAL REGULATIONS: AS FOLLOWS CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. CANADIAN WHMIS CLASS: No information available. (Continued on Page 7) --------------------------------------------------------------------------- Product Name: EASY SOLUTIONS - Tile Grout Repair Revision Date: 06/11/2001 Page 7 |-------------------------------------------------------------------------| | SECTION 16 - OTHER INFORMATION | |-------------------------------------------------------------------------| HMIS RATINGS - HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0 PREVIOUS MSDS REVISION DATE: 10/16/2000 VOC less water, less exempt solvent: 95-100 gm/L (0.5-1 lb/gal) (4-5 wt%VOC) VOC material : 50-60 gm/L LEGEND: ACGIH N.A. N.E. PEL NTP SARA STEL TLV VOC NJRTK N.D. - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS NOT APPLICABLE NOT ESTABLISHED PERMISSIBLE EXPOSURE LIMIT NATIONAL TOXICOLOGY PROGRAM SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 SHORT TERM EXPOSURE LIMIT THRESHOLD LIMIT VALUE(8 HR. TIME WEIGHTED AVERAGE OR TWA) VOLATILE ORGANIC COMPOUND NEW JERSEY RIGHT TO KNOW LAW NOT DETERMINED MSDS# 71031 --------------------------------------------------------------------------- This data is offered in good faith as typical values and not as a product specification. No warranty either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review the recommendations in specific context of the intended use and determine if they are appropriate. --------------------------------------------------------------------------< End OF MSDS > MATERIAL SAFETY DATA SHEET Pre-Mixed Tile Grout HMIS HEALTH 1 FLAMMABILITY 0 REACTIVITY 0 PERSONAL B PROTECTION 1. Product And Company Identification Supplier CUSTOM BUILDING PRODUCTS 10400 Pioneer Blvd., Unit #3 Santa Fe Springs, CA 90670 UNITED STATES Manufacturer CUSTOM BUILDING PRODUCTS 10400 Pioneer Blvd., Unit #3 Santa Fe Springs, CA 90670 UNITED STATES Company Contact: GEORGE MARCINA Telephone Number: (562) 968-2980 Ext 103 FAX Number: (562) 903-2697 E-Ma il: georgem@cbpmail.net Web Site: www.custombuildingproducts.com Company Contact: GEORGE MARCINA Telephone Number: (562) 968-2980 Ext 103 FAX Number: (562) 903-2697 E-Ma il: georgem@cbpmail.net Web Site: www.custombuildingproducts.com Supplier Emergency Contacts & Phone Number GEORGE MARCINA: (562) 968-2980 Manufacturer Emergency Contacts & Phone Number GEORGE MARCINA: (562) 968-2980 Issue Date: 04/24/2006 Product Name: Pre-Mixed Tile Grout CAS Number: Not Established Chemical Formula: Mixture MSDS Number: 645 Product Code: 1022 2. Composition/Information On Ingredients Ingredient Name CAS Number Percent Of Total Weight Acrylic Copolymer Proprietary 5 - 15 Calcium Carbonate 1317-65-3 65 - 75 3. Hazards Identification Primary Routes(s) Of Entry Eye and Skin Contact. Inhalation. Ingestion. Eye Hazards Causes eye irritation. Skin Hazards May cause skin irritation. Ingestion Hazards Harmful if swallowed. May cause gastrointestinal irritation, nausea and vomiting. Inhalation Hazards May cause nose, throat, and lung irritation. Chronic/Carcinogenicity Effects May contain trace amounts of chemicals that IARC classifies as possible carcinogens. Page 1 of 5 MATERIAL SAFETY DATA SHEET Pre-Mixed Tile Grout 3. Hazards Identification - Continued Teratogenicity (Birth Defects) May contain trace amounts of chemicals that caused birth defects in animal studies. It did not cause harm to the animal or fetus when applied on skin. Reproductive Effects May contain trace amounts of chemicals that caused birth defects in animal studies. It did not cause harm to the animal or fetus when applied on skin. Mutagenicity (Genetic Effect) May contain trace amounts of chemicals that caused birth defects in animal studies. It did not cause harm to the animal or fetus when applied on skin. Conditions Aggravated By Overexposure May cause eye and skin irritation. May cause nose, throat and lung irritation. May cause gastronomic disturbances. 4. First Aid Measures Eye Gently blot or wipe any residue remaining on the face, being careful not to get it in the victim's eyes or skin. Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately. Skin Remove excess from the skin. Wash skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Thoroughly clean before reuse. Get medical attention immediately if irritation (redness, rash, blistering) develops and persists. Ingestion If victim is fully conscious, give one or two cups of water or milk to drink. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Get medical attention immediately. If there is any discomfort from ingestion, consult a physician. Inhalation If inhaled, remove to fresh air. Get medical attention immediately. 5. Fire Fighting Measures Flash Point: NONE °F Flash Point Method: NONE Lower Explosive Limit: N/A Upper Explosive Limit: N/A Fire And Explosion Hazards Material will not burn until all water has evaporated. Cans may burst open and splatter material if temperatures reach 212 deg F and above. Extinguishing Media Foam, CO2, Dry chemical, Water fog. Fire Fighting Instructions Firefighters should wear self-contained breathing apparatus and full protective gear. 6. Accidental Release Measures Clean up spill immediately. Cover with absorbent to contain. Collect and dispose. Use appropriate containers to avoid environmental contamination. Avoid runoff to waterways and sewers. Avoid release to the environment. Use appropriate personal protective equipment (PPE). Page 2 of 5 MATERIAL SAFETY DATA SHEET Pre-Mixed Tile Grout 7. Handling And Storage Handling And Storage Precautions Store in cool, dry areas away from sunlight, heat and heat sources. Protect from freezing. Work/Hygienic Practices Wash thoroughly with soap and water after handling. Use good personal hygiene. Observe good housekeeping practices. 8. Exposure Controls/Personal Protection Eye/Face Protection Safety glasses with side shields or goggles recommended. Skin Protection Chemical-resistant gloves. Respiratory Protection General room ventilation is normally adequate. .In case of inadequate ventilation, use NIOSH-approved respirator. Other/General Protection General ventilation is usually sufficient. Fan or other device maybe needed if used in small and enclosed areas. Ingredient(s) - Exposure Limits Calcium Carbonate OSHA - PEL - TWA - 15mg/m3 Niosh - REL 10 mg/m3 ACGIH- TLV - 10 mg/m3 OSHA - PEL - TWA - 5 mg/m3 Adequate clothing to prevent skin contact. 9. Physical And Chemical Properties Appearance White paste Odor Mild acrylic odor. Chemical Type: Mixture Physical State: Liquid Boiling Point: 212 °F Specific Gravity: 1.9 Percent Volatiles: 25 Vapor Density: HEAVIER THAN AIR Solubility: Dilutable in water Evaporation Rate: Slower than ether 10. Stability And Reactivity Sta bility: Stable Hazardous Polymerization: Will not occur Incompatible Materials Avoid contact with strong oxidizers. Hazardous Decomposition Products Thermal decomposition in air may result in carbon monoxide and / or carbon dioxide. Conditions To Avoid (Polymerization) Hazardous polymerization will not occur. Heat may cause pressure build-up in closed containers Page 3 of 5 MATERIAL SAFETY DATA SHEET Pre-Mixed Tile Grout 11. Toxicological Information Chronic/Carcinogenicity May contain trace amounts of chemicals that IARC classifies as possible carcinogens. Teratogenicity (Birth Defects) May contain trace amounts of chemicals that caused birth defects in animal studies. It did not cause harm to the animal or fetus when applied on skin. Reproductive Effects May contain trace amounts of chemicals that caused birth defects in animal studies. It did not cause harm to the animal or fetus when applied on skin. Mutagenicity (Genetic Effects) May contain trace amounts of chemicals that caused birth defects in animal studies. It did not cause harm to the animal or fetus when applied on skin. Ingredient(s) - Toxicological Data Acrylic Copolymer Oral >5000mg / kg - rat 12. Ecological Information No Data Available... 13. Disposal Considerations Dispose in accordance with applicable federal, state and local government regulations and industry standards. RCRA Information Not considered RCRA waste 14. Transport Information DOT Shipping Label Not Regulated 15. Regulatory Information Ingredient(s) - State Regulations Acrylic Copolymer California - Proposition 65 Calcium Carbonate New Jersey - Workplace Hazard Pennsylvania - Workplace Hazard Massachusetts - Hazardous Substance 16. Other Information HMIS Rating He a lth: 1 Fire : 0 Re a ctivity: 0 Personal Protection: B Revision/Preparer Information MSDS Preparer: GEORGE MARCINA MSDS Preparer Phone Number: (562) 968-2980 ext 103 This MSDS Supersedes A Previous MSDS Dated: 04/20/2006 Page 4 of 5 MATERIAL SAFETY DATA SHEET Pre-Mixed Tile Grout Disclaimer THE INFORMATION PRESENTED HERE IS BELIEVED TO BE ACCURATE BUT IS NOT WARRANTED TO BE, WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED, THAT THE INFORMATION IS CURRENT, APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. CUSTOM BUILDING PRODUCTS Printed Using MSDS Generator™ 2000 Page 5 of 5 MATERIAL SAFETY DATA SHEET White Dry Non-Sanded Grout HMIS HEALTH 1 FLAMMABILITY 0 REACTIVITY 0 PERSONAL E PROTECTION 1. Product And Company Identification Supplier CUSTOM BUILDING PRODUCTS 10400 Pioneer Blvd., Unit #3 Santa Fe Springs, CA 90670 UNITED STATES Manufacturer CUSTOM BUILDING PRODUCTS 10400 Pioneer Blvd., Unit #3 Santa Fe Springs, CA 90670 UNITED STATES Company Contact: GEORGE MARCINA Telephone Number: (562) 968-2980 Ext 103 FAX Number: (562) 903-2697 E-Ma il: georgem@cbpmail.net Web Site: www.custombuildingproducts.com Company Contact: GEORGE MARCINA Telephone Number: (562) 968-2980 Ext 103 FAX Number: (562) 903-2697 E-Ma il: georgem@cbpmail.net Web Site: www.custombuildingproducts.com Supplier Emergency Contacts & Phone Number GEORGE MARCINA: (562) 968-2980 Manufacturer Emergency Contacts & Phone Number GEORGE MARCINA: (562) 968-2980 Issue Date: 04/20/2006 Product Name: White Dry Non-Sanded Grout CAS Number: Not Established Chemical Family: Mixture Chemical Formula: Mixture MSDS Number: 637 Product Code: 8012 2. Composition/Information On Ingredients Ingredient Name CAS Number Calcium Carbonate Portland Cement Percent Of Total Weight 1317-65-3 20 - 30 65997-15-1 70 - 80 3. Hazards Identification Primary Routes(s) Of Entry Inhalation, Skin Contac, Eye Contact, Ingestion Eye Hazards Irritant, severe eye irritation. May cause eye injury. Effects may be delayed. Skin Hazards Contains Portland cement and exposure to dry Portland cement may cause drying of skin with consequent mild irritation. Prolonged contact with wet Portland cement may cause severe, potentially irreversible damage to the skin in the form of chemical (caustic) burns. Ingestion Hazards Ingestion is not known to be harmful, however the product contains Portland cement which is caustic to mucus tissue and should not be consumed. Page 1 of 4 MATERIAL SAFETY DATA SHEET White Dry Non-Sanded Grout 3. Hazards Identification - Continued Inhalation Hazards Causes respiratory tract irritation. May cause nose, throat, and lung irritation. May cause delayed lung injury. Chronic/Carcinogenicity Effects May contain trace amounts of Silica sand, known Human Carcinogen (Category 1) 4. First Aid Measures Eye In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately if irritation develops and persists. Skin In case of contact, immediately flush skin with plenty of water for at least 15 minutes. Get medical attention immediately if irritation (redness, rash, blistering) develops and persists. Ingestion DO NOT INDUCE VOMITING. If victim is fully conscious, give one or two cups of water or milk to drink. Get medical attention immediately. Inhalation If inhaled, remove to fresh air. Consult a physician immediately if irritation persists. Do not give an unconscious person anything to drink. 5. Fire Fighting Measures Flash Point: N/A °F Flash Point Method: N/A Lower Explosive Limit: N/A Upper Explosive Limit: N/A 6. Accidental Release Measures Avoid generating dust. Sweep up and remove immediately.U se appropriate personal protective equipment (PPE). OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS REGARDING NOTIFICATIONS OF ACCIDENTAL RELEASES. 7. Handling And Storage Handling And Storage Precautions Use only with adequate ventilation. Handling Precautions Avoid creating dust. Avoid breathing dust. Avoid contact with skin and clothing. Avoid contact with eyes. Storage Precautions Keep dry until ready to use. Work/Hygienic Practices Use good personal hygiene. Wash thoroughly with soap and water after handling. 8. Exposure Controls/Personal Protection Engineering Controls Use with adequate ventilation. Eye/Face Protection Safety glasses with side shields or goggles recommended. Page 2 of 4 MATERIAL SAFETY DATA SHEET White Dry Non-Sanded Grout 8. Exposure Controls/Personal Protection - Continued Skin Protection If hands or feet will be exposed, wear impervious gloves and/or boots. Respiratory Protection In case of inadequate ventilation and when exposed to dust above the recommended limits, wear a suitable NIOSH-approved respirator. Ingredient(s) - Exposure Limits Calcium Carbonate OSHA - PEL - TWA - 15mg/m3 Niosh - REL 10 mg/m3 ACGIH- TLV - 10 mg/m3 OSHA - PEL - TWA - 5 mg/m3 Portland Cement OSHA - PEL - 5mg/m3 OSHA - PEL - TWA - 50mppcf ACGIH - TLV - 10mg/m3 9. Physical And Chemical Properties Appearance Free flowing white powder. Chemical Type: Mixture Physical State: Solid Boiling Point: N/A °F Specific Gravity: 2.7 Vapor Density: N/A Solubility: SLIGHT Evaporation Rate: N/A 10. Stability And Reactivity Sta bility: STABLE Hazardous Polymerization: WILL NOT OCCUR. Conditions To Avoid (Stability) Avoid unintentional contact with water. Incompatible Materials Contains portland cement which, when wet, is highly alkali. As a result, it is incompatible with acids, ammonium salts, aluminum and other alkali and alkaline earth metals. 11. Toxicological Information Chronic/Carcinogenicity May contain traces of Silica sand, known human carcinogen. 12. Ecological Information No Data Available... 13. Disposal Considerations Dispose in accordance with applicable federal, state and local government regulations. RCRA Information Not considered RCRA Hazardous Waste. Page 3 of 4 MATERIAL SAFETY DATA SHEET White Dry Non-Sanded Grout 14. Transport Information DOT Shipping Label NOT REGULATED 15. Regulatory Information SARA Hazard Classes Chronic Health Hazard SARA Section 313 Notification This product does not contains toxic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372. State Regulations Cal EPA -Toxic Hot Spots - OEHHA - REL - 3 micrograms /m3 Ingredient(s) - State Regulations Calcium Carbonate Pennsylvania - Workplace Hazard Portland Cement New Jersey - Workplace Hazard Pennsylvania - Workplace Hazard 16. Other Information HMIS Rating He a lth: 1 Fire : 0 Re a ctivity: 0 Personal Protection: E Revision/Preparer Information MSDS Preparer: GEORGE MARCINA MSDS Preparer Phone Number: (562) 968-2980 ext 103 This MSDS Supersedes A Previous MSDS Dated: 04/10/2006 Disclaimer Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitablility of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purposes(s). CUSTOM BUILDING PRODUCTS Printed Using MSDS Generator™ 2000 Page 4 of 4 Material Safety Data Sheet F S 1. Chemical Product and Company Identification DESCRIPTION: PRODUCT TYPE: APPLICATION: • ELMER'S CARPENTERS WOOD GLUE PVAC BASED ADHESIVE FOR PRODUCT CODES SEE SECTION 16 Manufacturer/Supplier Information MSDS Prepared by: Elmer's Products, Inc. Emergency Phone Number 1 Easton Oval Poison Control Center Columbus, OH 43219 888-516-2502 For additional health, safety or regulatory information, call 888-435-6377 Call 1-800-848-9400 to place an order or request additional MSDSs. 2. Composition, Information on Ingredients No hazardous ingredients known to company. 3. Hazards Identification 3.1 Emergency Overview Appearance Odor Not an immediate health hazard. • HMIS Rating Light yellow liquid Mild acetic aroma HEALTH = 0 (minimal) FLAMMABILITY = 0 (minimal) REACTIVITY = 0 (minimal) 3.2 Potential Health Effects • Immediate Hazards INGESTION: INHALATION: SKIN: EYES: • No No No No hazards hazards hazards hazards known known known known to to to to company. company. company. company. Delayed Hazards None of the components present in this product at concentrations equal to or greater than 0.1% have been listed by NTP, classified by IARC, nor regulated by OSHA as a carcinogen. 4. First Aid Measures INGESTION: EYES: If accidentally swallowed, dilute by drinking large quantities of water. Immediately contact poison control center or hospital emergency room for any other additional treatment directions. Immediately flush eyes with plenty of water. Call a physician if irritation persists. 5. Fire Fighting Measures Autoignition Temperature Not available Upper/Lower Flammable Limits Not applicable Up/Lower Explosive Limits, % by Vol Not applicable Flash Point Not applicable Will not burn unless water has evaporated. Dried material may burn. In case of fire, water should be used to keep fire-exposed containers cool. 6. Accidental Release Measures Soak up with absorbent material and remove to a chemical disposal area. Prevent entry into natural bodies of water. 7. Handling and Storage 7.1 Handling Handle in accordance with good industrial hygiene and safety practices. 7.2 Storage Keep from freezing. Store in a cool, dry place. Keep containers tightly closed. 8. Exposure Controls/Personal Protection 8.1 Exposure Controls No special control measures necessary under normal conditions of use. 8.2 Personal Protection No special protection necessary. 8.3 Exposure Guidelines None established 9. Physical and Chemical Properties Percent Volatiles pH @ 25 C Specific Gravity Appearance 54.5 5.0 1.08 Light yellow liquid Autoignition Temperature Boiling Point Vapor Density (Air=1) Vapor Pressure, mm Hg @ 20 C Evaporation Rate (Butyl Acetate=1) Upper/Lower Flammable Limits Up/Lower Explosive Limits, % by Vol Flash Point Freezing Point Odor Odor Threshold, ppm Solubility in Water Coefficient of Water/Oil Distrib. Not available 100°C (212°F) <1 17.5 <1 Not applicable Not applicable Not applicable 0°C (32°F) Mild acetic aroma Not available Dispersible Not available 10. Stability and Reactivity Normally stable as defined in NFPA 704-12(4-3.1). • Incompatibilities: Strong acids and alkaline materials. • Decomposition products may include: CO, CO2. • Hazardous polymerization: Will not occur. • Other Hazards: None known to company. 11. Toxicological Information INGESTION: INHALATION: SKIN ABSORPTION: A similar product was found to be non-toxic orally when tested as described in 16 CFR Part 1500.3(c)(1) and (2). A similar product was found to be non-toxic by inhalation when tested as described in 16 CFR Part 1500.3 (c)(1) and (2). A similar product was found to be non-toxic dermally when tested as described in 16 CFR Part 1500.3 (c)(1) SKIN: EYES: and (2). A similar described A similar described product was not an irritant when tested as in 16 CFR Part 1500.41. product was not an irritant when tested as in 16 CFR Part 1500.42. 12. Ecological Information Not determined. 13. Disposal Considerations Recover free liquid. Absorb residue and dispose of according to local, state/provincial, and federal requirements. 14. Transport Information 14.1 U.S. Department of Transportation (DOT) The data provided in this section is for information only and may not be specific to your package size. You will need to apply the appropriate regulations to properly classify your shipment for transportation. Non-Regulated. 14.2 Canadian Transportation of Dangerous Goods (TDG) Non-Regulated. 15. Regulatory Information (Selected Regulations) 15.1 U.S. Federal Regulations • OSHA Hazard Communication Standard 29CFR1910.1200 This material is not a "health hazard" or a "physical hazard" as determined when reviewed according to the requirements of the Occupational Safety and Health Administration 29 CFR Part 1910.1200 "Hazard Communication" Standard. • SARA Title III: Section 311/312 Does not meet any hazard category • SARA Title III Section 313 and 40 CFR Part 372 This product contains the following toxic chemical(s) subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and Subpart C-Supplier Notification Requirement of 40 CFR Part 372. None required per SARA TITLE III SECTION 313. • TSCA Section 8(b) Inventory All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications of compliance from our suppliers for chemical substances not manufactured by us. 15.2 Canadian Regulations • Workplace Hazardous Materials Information System (WHMIS) This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation (CPR) and the MSDS contains all the information required by the CPR. Not a controlled product • Canadian Environmental Protection Act (CEPA) All reportable chemical substances are listed on the Domestic Substances List (DSL) or otherwise comply with CEPA new substance notification requirements. • National Pollutant Release Inventory (NPRI) This product contains the following chemical(s) subject to the reporting requirements of the Canadian Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release Inventory. None required. 16. Other Information AP (Non-Toxic): Products bearing the AP (Non-Toxic) Product Seal of The Art & Creative Materials Institute, Inc. (ACMI) are certified in a program of toxicological evaluation by a medical expert to contain no materials in sufficient quantities to be toxic or injurious to humans or to cause acute or chronic health problems. This program is reviewed by ACMI's Toxicological Advisory Board. These products are certified by ACMI to be labeled in accordance with the chronic hazard labeling standard, ASTM D-4236 and Federal Law, P.L. 100-695. In addition, there is no physical hazard as defined within 29 CFR Part 1910.1200(c). MSDS covers items: U.S.: E614, E700, E701, E702, E704, E705, E706, E970, E980, E1367, E1825, E1850 Canada: 60613, 60614, 60615, 60616, 60617, 60618, 60619 • User's Responsibility The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace Hazardous Materials Information System (WHMIS) require that the information contained on these sheets be made available to your workers. Educate and train your workers regarding OSHA and WHMIS precautions. Instruct your workers to handle this product properly. Consult with appropriate experts to guard against hazards associated with use of this product and its ingredients. • Disclaimer SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product shall conform to contracted specifications, and that the product does not infringe any valid United States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, negligence or otherwise. CURRENT ISSUE: 27-JUN-06 PREVIOUS ISSUE: 13-JAN-05 Page 1 of 7 Material Safety Data Sheet 24 Hour Emergency Phone Numbers: Medical: 1-800-327-3874 1-513-558-5111 Transportation: 1-800-535-5053 1-352-323-3500 NOTE: National Response Center emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals. IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16. Section 1 - Chemical Product / Company Information This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request. Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en español a su solicitud. Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere. Product Name: Product UPC Number: FAST N FINAL PREMIUM 7079812140, 7079812141, 7079812142, 7079812143, 7079812145, 7079812146, 7079812147, 7079812148, 7079812149, 7079823030, 7079823050, 7079823090, 7079871354 Product Use/Class: RTU Spackle/Wallboard Repair Manufacturer: DAP Inc. 2400 Boston Street Suite 200 Baltimore, MD 21224-4723 888 -327-8477 (non-emergency matters) Revision Date: 01/31/2006 Supercedes: 07/08/2003 MSDS Number: 00010410001 Section 2 - Composition / Information On Ingredients Chemical Name Sodium silicate glass Ethylene glycol Vinyl acetate Formaldehyde Acetaldehyde CASRN 1344 -09-8 107-21-1 108-05-4 50-00-0 75-07-0 WT% ACGIH TWA 10-30 0.5-1.5 0.1-1.0 <0.004 <0.002 10 MGM3 N.E. 10 PPM N.E. N.E. ACGIH STEL N.E. N.E. 15 PPM N.E. N.E. ACGIH CEIL OSHA TWA OSHA STEL OSHA CEIL Skin N.E. 100 MGM3 N.E. 0.3 PPM 25 PPM 5 MGM3 N.E. N.E. 0.75 PPM 200 PPM N.E. N.E. N.E. 2 PPM N.E. N.E. N.E. N.E. N.E. N.E. No No No No No Exposure Notes: 50-00-0 Formaldehyde is a specially regulated substance for which an OSHA chemical-specific exposure standard exits. Detailed information regarding this substance may be found in 29 CFR 1910.1048. Medical surveillance information regarding this substance may be found in Appendix C to 29 CFR 1910.1048. Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary between states. Page 2 of 7 Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work practices Section 3 - Hazards Identification Emergency Overview: A white to off-white paste with a slight sweet odor. CAUTION! May cause eye, skin, nose, throat and respiratory tract irritation. This product contains ethylene glycol. Refer to other MSDS sections for other detailed information. Effects Of Overexposure - Eye Contact: May cause eye irritation. Effects Of Overexposure - Skin Contact: May cause skin irritation. May cause dry skin. Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes). Inhalation of dust may cause lung damage or other adverse pulmonary and respiratory effects. Effects Of Overexposure - Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Effects Of Overexposure - Chronic Hazards: Formaldehyde vapor is a known animal carcinogen according to OSHA and NTP and is considered possibly carcinogenic to humans by inhalation. The International Agency for Research on Cancer considers formaldehyde to be a human carcinogen. Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Studies have shown that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals. Ethylene glycol has been shown to cause birth defects in laboratory animals. This product contains vinyl acetate which is classified as a class 2B carcinogen by IARC. Vinyl acetate was found to cause cancer in the respiratory tract of laboratory animals. There is no evidence that vinyl acetate causes cancer in humans. The IARC published a monograph on vinyl acetate (1995). In this monograph, IARC indicates "there is inadequate evidence in humans for carcinogenicity of vinyl acetate. There is limited evidence in experimental animals for the carcinogenicity of vinyl acetate." Normally, this lack of conclusive evidence would place a substance in the IARC 3 classification (not classified as a human carcinogen). However, because vinyl acetate is metabolized to acetaldehyde, which has an IARC 2B (possibly carcinogenic to humans) classification, it also has been listed under Category 2B. Prolonged, repeated, or high exposures may cause weakness and depression of the central nervous system. Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation Medical Conditions which May be Aggravated by Exposure: If dry sanded, asthma and asthma-like conditions may worsen from prolonged or repeated exposure to dust. Section 4 - First Aid Measures First Aid - Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately. First Aid - Skin Contact: Wash off immediately with soap and plenty of water. First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If continued breathing difficulty is experienced, get medical attention immediately. Page 3 of 7 First Aid - Ingestion: Call a physician or Poison Control Center immediately. Do not induce vomiting. Note to Physician: None. COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arises from any of the above routes of entry. Section 5 - Fire Fighting Measures Flash Point, F: Greater than 200 degrees Method: (Seta Closed Cup) Lower Explosive Limit, %: Not Established Upper Explosive Limit, %: Not Established Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam Unusual Fire And Explosion Hazards: None known. Special Firefighting Procedures: Cool fire -exposed containers using water spray. Section 6 - Accidental Release Measures Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Scrape up dried material and place into containers. Section 7 - Handling And Storage Handling: KEEP OUT OF REACH OF CHILDREN! Do not breathe vapors. Wash thoroughly after handling. Avoid excessive heat and handling. Do not breathe dust. While dry sanding, use of a NIOSH-approved dust mask is recommended. Avoid contact with eyes, skin and clothing. Removal of this product after use will result in the generation of Dust. If dry-sanded, exposure to dust may result in the build -up of material in eyes, ears, nose, and mouth which may cause irritation. Storage: Store away from caustics and oxidizers. Do not store at temperatures above 120 degrees F. Keep tightly closed. Avoid excessive heat and freezing. Section 8 - Exposure Controls / Personal Protection Precautionary Measures: Please refer to other sections and subsections of this MSDS. Engineering Controls: Local ventilation of emission sources may be necessary to maintain ambient concentrations below recommended exposure limits. Wet sanding is recommended to avoid generation of dust. Prevent build-up of dust and vapors by opening windows and doors or use other means to ensure fresh air entry during application, drying and sanding. Respiratory Protection: A respiratory protection program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. If concentrations exceed the exposure limits specified, use of a NIOSH-approved supplied air respirator is recommended. Where the protection factor is exceeded, use of a Self Contained Breathing Apparatus (SCBA) may be necessary. Use an approved NIOSH/OSHA respirator if dry sanded. Skin Protection: Wear gloves with repeated or prolonged use. Eye Protection: Safety glasses with side-shields. Page 4 of 7 Other protective equipment: Not required under normal use. Hygienic Practices: Remove and wash contaminated clothing before re-use. Section 9 - Physical And Chemical Properties Boiling Range: Odor: Appearance: Solubility in H2O: Freeze Point: Vapor Pressure: Physical State: Not Established Slight Sweet White to Off-White Not Established Not Established Not Established Paste Vapor Density: Odor Threshold: Evaporation Rate: Specific Gravity: pH: Viscosity: Not Established Not Established Not Established 0.478 Between 7.0 and 12.0 Not Established When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally. (See section 16 for abbreviation legend) Section 10 - Stability And Reactivity Conditions To Avoid: Excessive heat and freezing. Incompatibility: Strong oxidizing agents. Strong bases. Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx. Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions. Stability: Stable under normal conditions. Section 11 - Toxicological Information Product LD50: Not Established CASRN Chemical Name 107-21-1 108-05-4 50-00-0 75-07-0 Product LC50: Not Established LD50 LC50 Ethylene glycol Vinyl acetate Formaldehyde Acetaldehyde Rat:4700 mg/kg ------------------------------------- Rat:10876 mg/kg Rat:11400 mg/m3/4H Rat:203 mg/m3 Rat:13300 ppm/4H WT% 0.5-1.5 0.1-1.0 <0.004 <0.002 Carcinogenicity: CAS No. Chemical Name 108-05-4 Vinyl acetate 50-00-0 Formaldehyde 75-07-0 Acetaldehyde ACGIH Confirmed animal carcinogen with unknown relevance to humans. Suspected human carcinogen. Confirmed animal carcinogen with unknown relevance to humans. OSHA IARC NTP WT% Not Listed. Possible carcinogen. Not Listed. 0.1-1.0 Potential cancer hazard. Human carcinogen. Anticipated carcinogen. <0.004 Not Listed. Possible carcinogen. Anticipated carcinogen. <0.002 Significant Data with Possible Relevance to Humans: This product contains trace amounts of free formaldehyde. OSHA and NTP identify formaldehyde as a potential carcinogen. IARC identifies formaldehyde as a human carcinogen. Formaldehyde has been shown to cause mutations in a variety of in-vitro test systems, the Page 5 of 7 significance of which to humans is unknown. In a two-year inhalation study, rats showed carcinogenic effects in the respiratory system at 15 ppm of formaldehyde. There should be minimal risk when used with ventilation adequate to keep the atmospheric concentration of formaldehyde below the recommended exposure limits. Maintain adequate ventilation to prevent exposure above current OSHA / ACGIH exposure limits. Workplace monitoring of the air to define formaldehyde exposure levels may be necessary. Section 12 - Ecological Information Ecological Information: Ecological injuries are not known or expected under normal use. Section 13 - Disposal Information Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA Waste Code if Discarded (40 CFR Section 261): None Section 14 - Transportation Information DOT Proper Shipping Name: DOT Technical Name: DOT Hazard Class: Not Regulated Packing Group: N.A. N.A. N.A. Hazard Subclass: DOT UN/NA Number: N.A. None Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may apply if shipped via other modes of transportation and/or to non-domestic destinations. Section 15 - Regulatory Information CERCLA - SARA Hazard Category: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: SARA Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Chemical Name Ethylene glycol Vinyl acetate CAS Number 107-21-1 108-05-4 WT% 0.5-1.5 0.1-1.0 Toxic Substances Control Act: All ingredients in this product are either on TSCA inventory list, or otherwise exempt. This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if Page 6 of 7 exported from the United States: None. U.S. State Regulations New Jersey Right-to-Know: The following materials are non-hazardous, but are among the top five components in this product: Chemical Name CAS Number Water Acetic acid, vinyl ester, polymer Sodium Borate; Boric Acid, Sodium Salt 7732 -18-5 Proprietary 7775 -19-1 WT% 30-60 10-30 1-5 Pennsylvania Right-to-Know: The following non-hazardous ingredients are present in the product at greater than 3%: Chemical Name CAS Number Water Acetic acid, vinyl ester, polymer Sodium Borate; Boric Acid, Sodium Salt 7732 -18-5 Proprietary 7775 -19-1 WT% 30-60 10-30 1-5 California Proposition 65: Warning: The following ingredients present in the product are known to the State of California to cause cancer: Chemical Name Formaldehyde Acetaldehyde CAS Number 50-00-0 75-07-0 Definition Date Listed WT% Carcinogenic. Carcinogenic. Listed: January 1, 1988 Listed: April 1, 1988 <0.004 <0.002 Warning: The following ingredients present in the product are known to the State of California to cause birth defects or other reproductive harm: None. Section 16 - Other Information HMIS Ratings: Health: 1 Flammability: 1 Reactivity: 0 VOLATILE ORGANIC COMPOUNDS, GR/LTR: 9.5 LB/GAL: 0.1 Personal Protection: X WT%: 1.485 REASON FOR REVISION: Periodic Update Legend: N.A. – Not Applicable ACGIH – American Conference of Governmental Industrial Hygienists N.E. – Not Established SARA – Superfund Amendments and Reauthorization Act of 1986 N.D. – Not Determined NJRTK – New Jersey Right-to-Know Law VOC – Volatile Organic Compound OSHA – Occupational Safety and Health Administration Page 7 of 7 PEL – Permissible Exposure Limit HMIS – Hazardous Materials Identification System TLV – Threshold Limit Value NTP – National Toxicology Program STEL – Short Term Exposure Limit CEIL – Ceiling Exposure Limit LD50 – Lethal Dose 50 LC50 – Lethal Concentration 50 F – Degree Fahrenheit C – Degree Celsius MSDS – Material Safety Data Sheet CASRN – The Chemical Abstracts Service Registry Number DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context of the intended use and (ii) determine if they are appropriate. Page 1 of 7 Material Safety Data Sheet 24 Hour Emergency Phone Numbers: Medical: 1-800-327-3874 1-513-558-5111 Transportation: 1-800-535-5053 1-352-323-3500 NOTE: National Response Center emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals. IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16. Section 1 - Chemical Product / Company Information This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request. Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en español a su solicitud. Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere. Product Name: Product UPC Number: FAST N FINAL PREMIUM 7079812140, 7079812141, 7079812142, 7079812143, 7079812145, 7079812146, 7079812147, 7079812148, 7079812149, 7079823030, 7079823050, 7079823090, 7079871354 Product Use/Class: RTU Spackle/Wallboard Repair Manufacturer: DAP Inc. 2400 Boston Street Suite 200 Baltimore, MD 21224-4723 888 -327-8477 (non-emergency matters) Revision Date: 01/31/2006 Supercedes: 07/08/2003 MSDS Number: 00010410001 Section 2 - Composition / Information On Ingredients Chemical Name Sodium silicate glass Ethylene glycol Vinyl acetate Formaldehyde Acetaldehyde CASRN 1344 -09-8 107-21-1 108-05-4 50-00-0 75-07-0 WT% ACGIH TWA 10-30 0.5-1.5 0.1-1.0 <0.004 <0.002 10 MGM3 N.E. 10 PPM N.E. N.E. ACGIH STEL N.E. N.E. 15 PPM N.E. N.E. ACGIH CEIL OSHA TWA OSHA STEL OSHA CEIL Skin N.E. 100 MGM3 N.E. 0.3 PPM 25 PPM 5 MGM3 N.E. N.E. 0.75 PPM 200 PPM N.E. N.E. N.E. 2 PPM N.E. N.E. N.E. N.E. N.E. N.E. No No No No No Exposure Notes: 50-00-0 Formaldehyde is a specially regulated substance for which an OSHA chemical-specific exposure standard exits. Detailed information regarding this substance may be found in 29 CFR 1910.1048. Medical surveillance information regarding this substance may be found in Appendix C to 29 CFR 1910.1048. Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary between states. Page 2 of 7 Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work practices Section 3 - Hazards Identification Emergency Overview: A white to off-white paste with a slight sweet odor. CAUTION! May cause eye, skin, nose, throat and respiratory tract irritation. This product contains ethylene glycol. Refer to other MSDS sections for other detailed information. Effects Of Overexposure - Eye Contact: May cause eye irritation. Effects Of Overexposure - Skin Contact: May cause skin irritation. May cause dry skin. Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes). Inhalation of dust may cause lung damage or other adverse pulmonary and respiratory effects. Effects Of Overexposure - Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Effects Of Overexposure - Chronic Hazards: Formaldehyde vapor is a known animal carcinogen according to OSHA and NTP and is considered possibly carcinogenic to humans by inhalation. The International Agency for Research on Cancer considers formaldehyde to be a human carcinogen. Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Studies have shown that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals. Ethylene glycol has been shown to cause birth defects in laboratory animals. This product contains vinyl acetate which is classified as a class 2B carcinogen by IARC. Vinyl acetate was found to cause cancer in the respiratory tract of laboratory animals. There is no evidence that vinyl acetate causes cancer in humans. The IARC published a monograph on vinyl acetate (1995). In this monograph, IARC indicates "there is inadequate evidence in humans for carcinogenicity of vinyl acetate. There is limited evidence in experimental animals for the carcinogenicity of vinyl acetate." Normally, this lack of conclusive evidence would place a substance in the IARC 3 classification (not classified as a human carcinogen). However, because vinyl acetate is metabolized to acetaldehyde, which has an IARC 2B (possibly carcinogenic to humans) classification, it also has been listed under Category 2B. Prolonged, repeated, or high exposures may cause weakness and depression of the central nervous system. Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation Medical Conditions which May be Aggravated by Exposure: If dry sanded, asthma and asthma-like conditions may worsen from prolonged or repeated exposure to dust. Section 4 - First Aid Measures First Aid - Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately. First Aid - Skin Contact: Wash off immediately with soap and plenty of water. First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If continued breathing difficulty is experienced, get medical attention immediately. Page 3 of 7 First Aid - Ingestion: Call a physician or Poison Control Center immediately. Do not induce vomiting. Note to Physician: None. COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arises from any of the above routes of entry. Section 5 - Fire Fighting Measures Flash Point, F: Greater than 200 degrees Method: (Seta Closed Cup) Lower Explosive Limit, %: Not Established Upper Explosive Limit, %: Not Established Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam Unusual Fire And Explosion Hazards: None known. Special Firefighting Procedures: Cool fire -exposed containers using water spray. Section 6 - Accidental Release Measures Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Scrape up dried material and place into containers. Section 7 - Handling And Storage Handling: KEEP OUT OF REACH OF CHILDREN! Do not breathe vapors. Wash thoroughly after handling. Avoid excessive heat and handling. Do not breathe dust. While dry sanding, use of a NIOSH-approved dust mask is recommended. Avoid contact with eyes, skin and clothing. Removal of this product after use will result in the generation of Dust. If dry-sanded, exposure to dust may result in the build -up of material in eyes, ears, nose, and mouth which may cause irritation. Storage: Store away from caustics and oxidizers. Do not store at temperatures above 120 degrees F. Keep tightly closed. Avoid excessive heat and freezing. Section 8 - Exposure Controls / Personal Protection Precautionary Measures: Please refer to other sections and subsections of this MSDS. Engineering Controls: Local ventilation of emission sources may be necessary to maintain ambient concentrations below recommended exposure limits. Wet sanding is recommended to avoid generation of dust. Prevent build-up of dust and vapors by opening windows and doors or use other means to ensure fresh air entry during application, drying and sanding. Respiratory Protection: A respiratory protection program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. If concentrations exceed the exposure limits specified, use of a NIOSH-approved supplied air respirator is recommended. Where the protection factor is exceeded, use of a Self Contained Breathing Apparatus (SCBA) may be necessary. Use an approved NIOSH/OSHA respirator if dry sanded. Skin Protection: Wear gloves with repeated or prolonged use. Eye Protection: Safety glasses with side-shields. Page 4 of 7 Other protective equipment: Not required under normal use. Hygienic Practices: Remove and wash contaminated clothing before re-use. Section 9 - Physical And Chemical Properties Boiling Range: Odor: Appearance: Solubility in H2O: Freeze Point: Vapor Pressure: Physical State: Not Established Slight Sweet White to Off-White Not Established Not Established Not Established Paste Vapor Density: Odor Threshold: Evaporation Rate: Specific Gravity: pH: Viscosity: Not Established Not Established Not Established 0.478 Between 7.0 and 12.0 Not Established When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally. (See section 16 for abbreviation legend) Section 10 - Stability And Reactivity Conditions To Avoid: Excessive heat and freezing. Incompatibility: Strong oxidizing agents. Strong bases. Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx. Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions. Stability: Stable under normal conditions. Section 11 - Toxicological Information Product LD50: Not Established CASRN Chemical Name 107-21-1 108-05-4 50-00-0 75-07-0 Product LC50: Not Established LD50 LC50 Ethylene glycol Vinyl acetate Formaldehyde Acetaldehyde Rat:4700 mg/kg ------------------------------------- Rat:10876 mg/kg Rat:11400 mg/m3/4H Rat:203 mg/m3 Rat:13300 ppm/4H WT% 0.5-1.5 0.1-1.0 <0.004 <0.002 Carcinogenicity: CAS No. Chemical Name 108-05-4 Vinyl acetate 50-00-0 Formaldehyde 75-07-0 Acetaldehyde ACGIH Confirmed animal carcinogen with unknown relevance to humans. Suspected human carcinogen. Confirmed animal carcinogen with unknown relevance to humans. OSHA IARC NTP WT% Not Listed. Possible carcinogen. Not Listed. 0.1-1.0 Potential cancer hazard. Human carcinogen. Anticipated carcinogen. <0.004 Not Listed. Possible carcinogen. Anticipated carcinogen. <0.002 Significant Data with Possible Relevance to Humans: This product contains trace amounts of free formaldehyde. OSHA and NTP identify formaldehyde as a potential carcinogen. IARC identifies formaldehyde as a human carcinogen. Formaldehyde has been shown to cause mutations in a variety of in-vitro test systems, the Page 5 of 7 significance of which to humans is unknown. In a two-year inhalation study, rats showed carcinogenic effects in the respiratory system at 15 ppm of formaldehyde. There should be minimal risk when used with ventilation adequate to keep the atmospheric concentration of formaldehyde below the recommended exposure limits. Maintain adequate ventilation to prevent exposure above current OSHA / ACGIH exposure limits. Workplace monitoring of the air to define formaldehyde exposure levels may be necessary. Section 12 - Ecological Information Ecological Information: Ecological injuries are not known or expected under normal use. Section 13 - Disposal Information Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA Waste Code if Discarded (40 CFR Section 261): None Section 14 - Transportation Information DOT Proper Shipping Name: DOT Technical Name: DOT Hazard Class: Not Regulated Packing Group: N.A. N.A. N.A. Hazard Subclass: DOT UN/NA Number: N.A. None Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may apply if shipped via other modes of transportation and/or to non-domestic destinations. Section 15 - Regulatory Information CERCLA - SARA Hazard Category: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: SARA Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Chemical Name Ethylene glycol Vinyl acetate CAS Number 107-21-1 108-05-4 WT% 0.5-1.5 0.1-1.0 Toxic Substances Control Act: All ingredients in this product are either on TSCA inventory list, or otherwise exempt. This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if Page 6 of 7 exported from the United States: None. U.S. State Regulations New Jersey Right-to-Know: The following materials are non-hazardous, but are among the top five components in this product: Chemical Name CAS Number Water Acetic acid, vinyl ester, polymer Sodium Borate; Boric Acid, Sodium Salt 7732 -18-5 Proprietary 7775 -19-1 WT% 30-60 10-30 1-5 Pennsylvania Right-to-Know: The following non-hazardous ingredients are present in the product at greater than 3%: Chemical Name CAS Number Water Acetic acid, vinyl ester, polymer Sodium Borate; Boric Acid, Sodium Salt 7732 -18-5 Proprietary 7775 -19-1 WT% 30-60 10-30 1-5 California Proposition 65: Warning: The following ingredients present in the product are known to the State of California to cause cancer: Chemical Name Formaldehyde Acetaldehyde CAS Number 50-00-0 75-07-0 Definition Date Listed WT% Carcinogenic. Carcinogenic. Listed: January 1, 1988 Listed: April 1, 1988 <0.004 <0.002 Warning: The following ingredients present in the product are known to the State of California to cause birth defects or other reproductive harm: None. Section 16 - Other Information HMIS Ratings: Health: 1 Flammability: 1 Reactivity: 0 VOLATILE ORGANIC COMPOUNDS, GR/LTR: 9.5 LB/GAL: 0.1 Personal Protection: X WT%: 1.485 REASON FOR REVISION: Periodic Update Legend: N.A. – Not Applicable ACGIH – American Conference of Governmental Industrial Hygienists N.E. – Not Established SARA – Superfund Amendments and Reauthorization Act of 1986 N.D. – Not Determined NJRTK – New Jersey Right-to-Know Law VOC – Volatile Organic Compound OSHA – Occupational Safety and Health Administration Page 7 of 7 PEL – Permissible Exposure Limit HMIS – Hazardous Materials Identification System TLV – Threshold Limit Value NTP – National Toxicology Program STEL – Short Term Exposure Limit CEIL – Ceiling Exposure Limit LD50 – Lethal Dose 50 LC50 – Lethal Concentration 50 F – Degree Fahrenheit C – Degree Celsius MSDS – Material Safety Data Sheet CASRN – The Chemical Abstracts Service Registry Number DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context of the intended use and (ii) determine if they are appropriate. |-------------------------------------------------------| | M A T E R I A L S A F E T Y D A T A S H E E T | |-------------------------------------------------------| |-------------------------------------------------------------------------| | SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION | |-------------------------------------------------------------------------| PRODUCT NAME : WALLBOARD JOINT COMPOUND RTU UPC NUMBER : 7079810100, 7079810102 PRODUCT USE/CLASS : Joint Compound MANUFACTURER: DAP INC. 2400 BOSTON STREET BALTIMORE, MD 21224 24 HOUR EMERGENCY: TRANSPORTATION: 1-800-535-5053 (352-323-3500) MEDICAL : 1-800-327-3874 (513-558-5111) PREPARE DATE: 12/23/1999 GENERAL INFORMATION: REVISION NO.: 9 DAP INC. : 1-888-DAP-TIPS (1-888-327-8477) REVISION DATE: 07/28/2003 |-------------------------------------------------------------------------| | SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |-------------------------------------------------------------------------| ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER RANGE WT/WT % --------------------------------------------------------------------------01 Mica 12001-26-2 1.0-5.0 % 02 Calcium Carbonate 1317-65-3 60.0-65.0 % 03 Crystalline Silica 14808-60-7 0.1-0.5 % 04 Attapulgite(polygorskite) 12174-11-7 0.1-5.0 % ---------------------- EXPOSURE LIMITS -------------------ACGIH OSHA COMPANY ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN --------------------------------------------------------------------------01 3 mg/m3-dust N.E. 3 mg/m3-dust N.E. N.E. NO 02 10 mg/m3 N.E. ** N.E. N.E. NO 03 0.05 mg/m3* N.E. 10 mg/m3dust N.E. N.E. NO 04 N.E. N.E. N.E. N.E. N.E. NO (See Section 16 for abbreviation legend) * The 2001 ACGIH Threshold Limit Values for Chemical Substances and Physical Agents lists the median Respirable Particulate Mass (RPM) point for crystalline silica at 4.0 microns in terms of the particle’s aerodynamic diameter. ** 10 mg/m3 / (% SiO2 + 2): Both concentration and percent quartz for the application of this limit are to be determined from the fraction passing a size selector with the following characteristics |-------------------------------------------------------------------------| | Aerodynamic diameter (unit density sphere) | Percent passing selector | |-------------------------------------------------------------------------| |2 |90 | |2.5 |75 | |3.5 |50 | |5.0 |25 | |10 |0 | |-------------------------------------------------------------------------| Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); limits may vary between states. Remaining ingredients are not considered hazardous per the OSHA Hazard Communication Standard. (Continued on Page 2) --------------------------------------------------------------------------- Product Name: WALLBOARD JOINT COMPOUND RTU Revision Date: 07/28/2003 Page 2 |-------------------------------------------------------------------------| | SECTION 3 - HAZARDS IDENTIFICATION | |-------------------------------------------------------------------------| POTENTIAL HEALTH EFFECTS: EFFECTS OF OVEREXPOSURE - EYE CONTACT: May cause eye irritation. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: EFFECTS OF OVEREXPOSURE - INHALATION: respiratory tract. EFFECTS OF OVEREXPOSURE - INGESTION: May dry skin. Vapor may irritate nose and upper None known. EFFECTS OF OVER EXPOSURE – CHRONIC HAZARDS The International Agency for Research on Cancer (IARC)has determined that crystalline silica in the form of quartz or cristobalite that is inhaled from occupational sources is carcinogenic to humans (Group 1– carcinogenic to humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (published in June 1997) in conjunction with the use of these materials. The National Toxicology Program (NTP) classifies respirable crystalline silica as known to be a human carcinogen. Refer to the 9th Report on Carcinogens (2000). The American Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (A2). Breathing dust containing respirable crystalline silica may not cause noticeable injury or illness even though permanent lung damage may be occurring. Inhalation of dust may have the following serious chronic health effects: Excessive inhalation of respirable dust can cause pneumoconiosis, a respiratory disease, which can result in delayed, progressive, disabling and sometimes fatal lung injury. Symptoms include cough, shortness of breath, wheezing, non-specific chest illness and reduced pulmonary function. Smoking exacerbates this disease. Individuals with pneumoconiosis are predisposed to develop tuberculosis. There is some evidence that breathing respirable crystalline silica or the disease silicosis is associated with an increased incidence of significant disease endpoints such as scleroderma (an immune system disorder manifested by fibrosis of the lungs, skin and other internal organs) and kidney disease. MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY CONTACT: Asthma and asthma-like conditions may worsen from prolonged and repeated exposure. PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT INHALATION |-------------------------------------------------------------------------| | SECTION 4 - FIRST AID MEASURES | |-------------------------------------------------------------------------| EYE CONTACT: Flush with large quantities of water until irritation subsides. Contact a physician. SKIN CONTACT: Wash with soap and water. (Continued on Page 3) --------------------------------------------------------------------------- Product Name: WALLBOARD JOINT COMPOUND RTU Revision Date: 07/28/2003 Page 3 |-------------------------------------------------------------------------| | SECTION 4 - FIRST AID MEASURES | |-------------------------------------------------------------------------| INHALATION: Remove to fresh air. Contact a physician immediately. INGESTION: DO NOT INDUCE VOMITING. Control Center immediately. COMMENTS: Contact a physician or Regional Poison In case of a medical emergency call: 1-800-327-3874. |-------------------------------------------------------------------------| | SECTION 5 - FIRE FIGHTING MEASURES | |-------------------------------------------------------------------------| FLASH POINT: >200 F (SETAFLASH CLOSED CUP) LOWER EXPLOSIVE LIMIT: N.A. UPPER EXPLOSIVE LIMIT: N.A. AUTOIGNITION TEMPERATURE: N.E. EXTINGUISHING MEDIA: CO2 DRY CHEMICAL UNUSUAL FIRE AND EXPLOSION HAZARDS: SPECIAL FIREFIGHTING PROCEDURES: FOAM None known. Use water spray to cool exposed surfaces. |-------------------------------------------------------------------------| | SECTION 6 - ACCIDENTAL RELEASE MEASURES | |-------------------------------------------------------------------------| SPILL OR LEAK PROCEDURES: containers. Scrape up dried material and place into |-------------------------------------------------------------------------| | SECTION 7 - HANDLING AND STORAGE | |-------------------------------------------------------------------------| CAUTION! Removal of this product after use will result in the generation of dust. If dry-sanded, exposure to dust may result in build-up of material in eyes, ears, nose, and mouth which may cause irritation. HANDLING INFORMATION: KEEP OUT OF REACH OF CHILDREN. Keep containers away from excessive heating and freezing. Avoid skin and eye contact. Do not inhale dusts of this product. STORAGE INFORMATION: Store away from caustics and oxidizers. Keep containers tightly closed when not in use. Keep containers from excessive heat and freezing. Do not store at temperatures above 120 degrees F. OTHER PRECAUTIONS: None. |-------------------------------------------------------------------------| | SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |-------------------------------------------------------------------------| (Continued on Page 4) --------------------------------------------------------------------------- Product Name: WALLBOARD JOINT COMPOUND RTU Revision Date: 07/28/2003 Page 4 |-------------------------------------------------------------------------| | SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |-------------------------------------------------------------------------| ENGINEERING CONTROLS: If dry-sanding, provide sufficient mechanical ventilation to maintain exposure below PEL and TLV. Wet sanding is recommended to avoid generation of dust. RESPIRATORY PROTECTION: Dry sanding of dried product results in the generation of dust which contains crystalline silica. Avoid exposure to dust by wearing an appropriate, properly fitted, dust respirator during dry sanding. Follow respiratory manufacturer’s directions for respirator use. If the 8 hour exposure limit or value is exceeded for any component, use an approved NIOSH/OSHA respirator. Consult your safety equipment supplier and the OSHA regulation, 29 CFR 1910.134 for respirator requirements. A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. The National Institute for Occupational Safety and Health (NIOSH) recommended permissible exposure limit of 50 micrograms respirable free silica per cubic meter of air (0.05 mg/m3) as determined by a full shift sample up to 10 hour working day, 40 hours per week. EYE PROTECTION: SKIN PROTECTION: skin. Safety glasses with side shields. Gloves recommended for repeated or prolonged contact with OTHER PROTECTIVE EQUIPMENT: HYGIENIC PRACTICES: None. Remove contaminated clothing and wash before reuse. |-------------------------------------------------------------------------| | SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |-------------------------------------------------------------------------| BOILING RANGE : 210 - 220 F VAPOR DENSITY : Is heavier than air ODOR : Musty Odor APPEARANCE : Gray Color Paste EVAPORATION RATE: Is slower than Butyl SOLUBILITY IN H2O : Miscible Acetate SPECIFIC GRAVITY : 1.7157 VAPOR PRESSURE : 17.5 mm Hg@68F. PHYSICAL STATE : Paste (See Section 16 for abbreviation legend) |-------------------------------------------------------------------------| | SECTION 10 - STABILITY AND REACTIVITY | |-------------------------------------------------------------------------| CONDITIONS TO AVOID: INCOMPATIBILITY: Excessive heat and freezing. Strong oxidizers and caustics. (Continued on Page 5) --------------------------------------------------------------------------- Product Name: WALLBOARD JOINT COMPOUND RTU Revision Date: 07/28/2003 Page 5 |-------------------------------------------------------------------------| | SECTION 10 - STABILITY AND REACTIVITY | |-------------------------------------------------------------------------| HAZARDOUS DECOMPOSITION PRODUCTS: NOx Normal decomposition products, i.e. COx, HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. |-------------------------------------------------------------------------| | SECTION 11 - TOXICOLOGICAL PROPERTIES | |-------------------------------------------------------------------------| No product or component toxicological information is available. |-------------------------------------------------------------------------| | SECTION 12 - ECOLOGICAL INFORMATION | |-------------------------------------------------------------------------| No Information. |-------------------------------------------------------------------------| | SECTION 13 - DISPOSAL CONSIDERATIONS | |-------------------------------------------------------------------------| WASTE MANAGEMENT/DISPOSAL: This product does not meet the definition of a hazardous waste according to U.S. EPA Hazardous Waste Management Regulations, 40 CFR Section 261. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA WASTE CODE - If discarded (40 CFR 261): None. |-------------------------------------------------------------------------| | SECTION 14 - TRANSPORTATION INFORMATION | |-------------------------------------------------------------------------| DOT PROPER SHIPPING NAME: Not Regulated by D.O.T. DOT HAZARD CLASS: NONE DOT UN/NA NUMBER: NONE PACKING GROUP: NONE |-------------------------------------------------------------------------| | SECTION 15 - REGULATORY INFORMATION | |-------------------------------------------------------------------------| U.S. FEDERAL REGULATIONS: AS FOLLOWS OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200) (Continued on Page 6) --------------------------------------------------------------------------- Product Name: WALLBOARD JOINT COMPOUND RTU Revision Date: 07/28/2003 Page 6 |-------------------------------------------------------------------------| | SECTION 15 - REGULATORY INFORMATION | |-------------------------------------------------------------------------| SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: ----------- CHEMICAL NAME ----------CAS NUMBER No SARA Section 313 components exist in this product. WT/WT % RANGE TOXIC SUBSTANCES CONTROL ACT: This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: ----------- CHEMICAL NAME ----------CAS NUMBER No TSCA 12(B) chemicals are known to exist in this product. NEW JERSEY RIGHT-TO-KNOW: The following materials are non-hazardous, but are among the top five components in this product: ----------- CHEMICAL NAME ----------Water Magnesium aluminum silicate Vinyl Acetate Polymer CAS NUMBER 7732-18-5 12174-11-7 TSRN-618608-5185P PENNSYLVANIA RIGHT-TO-KNOW: The following non-hazardous ingredients are present in the product at greater than 3%: ----------- CHEMICAL NAME ----------Water CAS NUMBER 7732-18-5 CALIFORNIA PROPOSITION 65: WARNING: The chemical(s) noted below and contained in this product, are known to the state of California to cause cancer: ----------- CHEMICAL NAME ----------Crystalline Silica CAS NUMBER 14808-60-7 INTERNATIONAL REGULATIONS: AS FOLLOWS CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. CANADIAN WHMIS CLASS: No information available. (Continued on Page 7) --------------------------------------------------------------------------- Product Name: WALLBOARD JOINT COMPOUND RTU Revision Date: 07/28/2003 Page 7 |-------------------------------------------------------------------------| | SECTION 15 - REGULATORY INFORMATION | |-------------------------------------------------------------------------| |-------------------------------------------------------------------------| | SECTION 16 - OTHER INFORMATION | |-------------------------------------------------------------------------| HMIS RATINGS - HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0 PREVIOUS MSDS REVISION DATE: 09/10/2002 REASON FOR REVISION: Section 2. Update exposure limits for crystalline silica. VOC less water, less exempt solvent: 15-20 g/L VOC material : 5-10 g/L LEGEND: ACGIH N.A. N.E. PEL NTP SARA STEL TLV VOC NJRTK N.D. - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS NOT APPLICABLE NOT ESTABLISHED PERMISSIBLE EXPOSURE LIMIT NATIONAL TOXICOLOGY PROGRAM SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 SHORT TERM EXPOSURE LIMIT THRESHOLD LIMIT VALUE(8 HR. TIME WEIGHTED AVERAGE OR TWA) VOLATILE ORGANIC COMPOUND NEW JERSEY RIGHT TO KNOW LAW NOT DETERMINED MSDS# 70288 --------------------------------------------------------------------------- This data is offered in good faith as typical values and not as a product specification. No warranty either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review the recommendations in specific context of the intended use and determine if they are appropriate. --------------------------------------------------------------------------< End OF MSDS > |-------------------------------------------------------| | M A T E R I A L S A F E T Y D A T A S H E E T | |-------------------------------------------------------| |-------------------------------------------------------------------------| | SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION | |-------------------------------------------------------------------------| PRODUCT NAME : WALLBOARD JOINT COMPOUND RTU UPC NUMBER : 7079810100, 7079810102 PRODUCT USE/CLASS : Joint Compound MANUFACTURER: DAP INC. 2400 BOSTON STREET BALTIMORE, MD 21224 24 HOUR EMERGENCY: TRANSPORTATION: 1-800-535-5053 (352-323-3500) MEDICAL : 1-800-327-3874 (513-558-5111) PREPARE DATE: 12/23/1999 GENERAL INFORMATION: REVISION NO.: 9 DAP INC. : 1-888-DAP-TIPS (1-888-327-8477) REVISION DATE: 07/28/2003 |-------------------------------------------------------------------------| | SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |-------------------------------------------------------------------------| ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER RANGE WT/WT % --------------------------------------------------------------------------01 Mica 12001-26-2 1.0-5.0 % 02 Calcium Carbonate 1317-65-3 60.0-65.0 % 03 Crystalline Silica 14808-60-7 0.1-0.5 % 04 Attapulgite(polygorskite) 12174-11-7 0.1-5.0 % ---------------------- EXPOSURE LIMITS -------------------ACGIH OSHA COMPANY ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN --------------------------------------------------------------------------01 3 mg/m3-dust N.E. 3 mg/m3-dust N.E. N.E. NO 02 10 mg/m3 N.E. ** N.E. N.E. NO 03 0.05 mg/m3* N.E. 10 mg/m3dust N.E. N.E. NO 04 N.E. N.E. N.E. N.E. N.E. NO (See Section 16 for abbreviation legend) * The 2001 ACGIH Threshold Limit Values for Chemical Substances and Physical Agents lists the median Respirable Particulate Mass (RPM) point for crystalline silica at 4.0 microns in terms of the particle’s aerodynamic diameter. ** 10 mg/m3 / (% SiO2 + 2): Both concentration and percent quartz for the application of this limit are to be determined from the fraction passing a size selector with the following characteristics |-------------------------------------------------------------------------| | Aerodynamic diameter (unit density sphere) | Percent passing selector | |-------------------------------------------------------------------------| |2 |90 | |2.5 |75 | |3.5 |50 | |5.0 |25 | |10 |0 | |-------------------------------------------------------------------------| Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); limits may vary between states. Remaining ingredients are not considered hazardous per the OSHA Hazard Communication Standard. (Continued on Page 2) --------------------------------------------------------------------------- Product Name: WALLBOARD JOINT COMPOUND RTU Revision Date: 07/28/2003 Page 2 |-------------------------------------------------------------------------| | SECTION 3 - HAZARDS IDENTIFICATION | |-------------------------------------------------------------------------| POTENTIAL HEALTH EFFECTS: EFFECTS OF OVEREXPOSURE - EYE CONTACT: May cause eye irritation. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: EFFECTS OF OVEREXPOSURE - INHALATION: respiratory tract. EFFECTS OF OVEREXPOSURE - INGESTION: May dry skin. Vapor may irritate nose and upper None known. EFFECTS OF OVER EXPOSURE – CHRONIC HAZARDS The International Agency for Research on Cancer (IARC)has determined that crystalline silica in the form of quartz or cristobalite that is inhaled from occupational sources is carcinogenic to humans (Group 1– carcinogenic to humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (published in June 1997) in conjunction with the use of these materials. The National Toxicology Program (NTP) classifies respirable crystalline silica as known to be a human carcinogen. Refer to the 9th Report on Carcinogens (2000). The American Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (A2). Breathing dust containing respirable crystalline silica may not cause noticeable injury or illness even though permanent lung damage may be occurring. Inhalation of dust may have the following serious chronic health effects: Excessive inhalation of respirable dust can cause pneumoconiosis, a respiratory disease, which can result in delayed, progressive, disabling and sometimes fatal lung injury. Symptoms include cough, shortness of breath, wheezing, non-specific chest illness and reduced pulmonary function. Smoking exacerbates this disease. Individuals with pneumoconiosis are predisposed to develop tuberculosis. There is some evidence that breathing respirable crystalline silica or the disease silicosis is associated with an increased incidence of significant disease endpoints such as scleroderma (an immune system disorder manifested by fibrosis of the lungs, skin and other internal organs) and kidney disease. MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY CONTACT: Asthma and asthma-like conditions may worsen from prolonged and repeated exposure. PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT INHALATION |-------------------------------------------------------------------------| | SECTION 4 - FIRST AID MEASURES | |-------------------------------------------------------------------------| EYE CONTACT: Flush with large quantities of water until irritation subsides. Contact a physician. SKIN CONTACT: Wash with soap and water. (Continued on Page 3) --------------------------------------------------------------------------- Product Name: WALLBOARD JOINT COMPOUND RTU Revision Date: 07/28/2003 Page 3 |-------------------------------------------------------------------------| | SECTION 4 - FIRST AID MEASURES | |-------------------------------------------------------------------------| INHALATION: Remove to fresh air. Contact a physician immediately. INGESTION: DO NOT INDUCE VOMITING. Control Center immediately. COMMENTS: Contact a physician or Regional Poison In case of a medical emergency call: 1-800-327-3874. |-------------------------------------------------------------------------| | SECTION 5 - FIRE FIGHTING MEASURES | |-------------------------------------------------------------------------| FLASH POINT: >200 F (SETAFLASH CLOSED CUP) LOWER EXPLOSIVE LIMIT: N.A. UPPER EXPLOSIVE LIMIT: N.A. AUTOIGNITION TEMPERATURE: N.E. EXTINGUISHING MEDIA: CO2 DRY CHEMICAL UNUSUAL FIRE AND EXPLOSION HAZARDS: SPECIAL FIREFIGHTING PROCEDURES: FOAM None known. Use water spray to cool exposed surfaces. |-------------------------------------------------------------------------| | SECTION 6 - ACCIDENTAL RELEASE MEASURES | |-------------------------------------------------------------------------| SPILL OR LEAK PROCEDURES: containers. Scrape up dried material and place into |-------------------------------------------------------------------------| | SECTION 7 - HANDLING AND STORAGE | |-------------------------------------------------------------------------| CAUTION! Removal of this product after use will result in the generation of dust. If dry-sanded, exposure to dust may result in build-up of material in eyes, ears, nose, and mouth which may cause irritation. HANDLING INFORMATION: KEEP OUT OF REACH OF CHILDREN. Keep containers away from excessive heating and freezing. Avoid skin and eye contact. Do not inhale dusts of this product. STORAGE INFORMATION: Store away from caustics and oxidizers. Keep containers tightly closed when not in use. Keep containers from excessive heat and freezing. Do not store at temperatures above 120 degrees F. OTHER PRECAUTIONS: None. |-------------------------------------------------------------------------| | SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |-------------------------------------------------------------------------| (Continued on Page 4) --------------------------------------------------------------------------- Product Name: WALLBOARD JOINT COMPOUND RTU Revision Date: 07/28/2003 Page 4 |-------------------------------------------------------------------------| | SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |-------------------------------------------------------------------------| ENGINEERING CONTROLS: If dry-sanding, provide sufficient mechanical ventilation to maintain exposure below PEL and TLV. Wet sanding is recommended to avoid generation of dust. RESPIRATORY PROTECTION: Dry sanding of dried product results in the generation of dust which contains crystalline silica. Avoid exposure to dust by wearing an appropriate, properly fitted, dust respirator during dry sanding. Follow respiratory manufacturer’s directions for respirator use. If the 8 hour exposure limit or value is exceeded for any component, use an approved NIOSH/OSHA respirator. Consult your safety equipment supplier and the OSHA regulation, 29 CFR 1910.134 for respirator requirements. A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. The National Institute for Occupational Safety and Health (NIOSH) recommended permissible exposure limit of 50 micrograms respirable free silica per cubic meter of air (0.05 mg/m3) as determined by a full shift sample up to 10 hour working day, 40 hours per week. EYE PROTECTION: SKIN PROTECTION: skin. Safety glasses with side shields. Gloves recommended for repeated or prolonged contact with OTHER PROTECTIVE EQUIPMENT: HYGIENIC PRACTICES: None. Remove contaminated clothing and wash before reuse. |-------------------------------------------------------------------------| | SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |-------------------------------------------------------------------------| BOILING RANGE : 210 - 220 F VAPOR DENSITY : Is heavier than air ODOR : Musty Odor APPEARANCE : Gray Color Paste EVAPORATION RATE: Is slower than Butyl SOLUBILITY IN H2O : Miscible Acetate SPECIFIC GRAVITY : 1.7157 VAPOR PRESSURE : 17.5 mm Hg@68F. PHYSICAL STATE : Paste (See Section 16 for abbreviation legend) |-------------------------------------------------------------------------| | SECTION 10 - STABILITY AND REACTIVITY | |-------------------------------------------------------------------------| CONDITIONS TO AVOID: INCOMPATIBILITY: Excessive heat and freezing. Strong oxidizers and caustics. (Continued on Page 5) --------------------------------------------------------------------------- Product Name: WALLBOARD JOINT COMPOUND RTU Revision Date: 07/28/2003 Page 5 |-------------------------------------------------------------------------| | SECTION 10 - STABILITY AND REACTIVITY | |-------------------------------------------------------------------------| HAZARDOUS DECOMPOSITION PRODUCTS: NOx Normal decomposition products, i.e. COx, HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. |-------------------------------------------------------------------------| | SECTION 11 - TOXICOLOGICAL PROPERTIES | |-------------------------------------------------------------------------| No product or component toxicological information is available. |-------------------------------------------------------------------------| | SECTION 12 - ECOLOGICAL INFORMATION | |-------------------------------------------------------------------------| No Information. |-------------------------------------------------------------------------| | SECTION 13 - DISPOSAL CONSIDERATIONS | |-------------------------------------------------------------------------| WASTE MANAGEMENT/DISPOSAL: This product does not meet the definition of a hazardous waste according to U.S. EPA Hazardous Waste Management Regulations, 40 CFR Section 261. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA WASTE CODE - If discarded (40 CFR 261): None. |-------------------------------------------------------------------------| | SECTION 14 - TRANSPORTATION INFORMATION | |-------------------------------------------------------------------------| DOT PROPER SHIPPING NAME: Not Regulated by D.O.T. DOT HAZARD CLASS: NONE DOT UN/NA NUMBER: NONE PACKING GROUP: NONE |-------------------------------------------------------------------------| | SECTION 15 - REGULATORY INFORMATION | |-------------------------------------------------------------------------| U.S. FEDERAL REGULATIONS: AS FOLLOWS OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200) (Continued on Page 6) --------------------------------------------------------------------------- Product Name: WALLBOARD JOINT COMPOUND RTU Revision Date: 07/28/2003 Page 6 |-------------------------------------------------------------------------| | SECTION 15 - REGULATORY INFORMATION | |-------------------------------------------------------------------------| SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: ----------- CHEMICAL NAME ----------CAS NUMBER No SARA Section 313 components exist in this product. WT/WT % RANGE TOXIC SUBSTANCES CONTROL ACT: This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: ----------- CHEMICAL NAME ----------CAS NUMBER No TSCA 12(B) chemicals are known to exist in this product. NEW JERSEY RIGHT-TO-KNOW: The following materials are non-hazardous, but are among the top five components in this product: ----------- CHEMICAL NAME ----------Water Magnesium aluminum silicate Vinyl Acetate Polymer CAS NUMBER 7732-18-5 12174-11-7 TSRN-618608-5185P PENNSYLVANIA RIGHT-TO-KNOW: The following non-hazardous ingredients are present in the product at greater than 3%: ----------- CHEMICAL NAME ----------Water CAS NUMBER 7732-18-5 CALIFORNIA PROPOSITION 65: WARNING: The chemical(s) noted below and contained in this product, are known to the state of California to cause cancer: ----------- CHEMICAL NAME ----------Crystalline Silica CAS NUMBER 14808-60-7 INTERNATIONAL REGULATIONS: AS FOLLOWS CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. CANADIAN WHMIS CLASS: No information available. (Continued on Page 7) --------------------------------------------------------------------------- Product Name: WALLBOARD JOINT COMPOUND RTU Revision Date: 07/28/2003 Page 7 |-------------------------------------------------------------------------| | SECTION 15 - REGULATORY INFORMATION | |-------------------------------------------------------------------------| |-------------------------------------------------------------------------| | SECTION 16 - OTHER INFORMATION | |-------------------------------------------------------------------------| HMIS RATINGS - HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0 PREVIOUS MSDS REVISION DATE: 09/10/2002 REASON FOR REVISION: Section 2. Update exposure limits for crystalline silica. VOC less water, less exempt solvent: 15-20 g/L VOC material : 5-10 g/L LEGEND: ACGIH N.A. N.E. PEL NTP SARA STEL TLV VOC NJRTK N.D. - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS NOT APPLICABLE NOT ESTABLISHED PERMISSIBLE EXPOSURE LIMIT NATIONAL TOXICOLOGY PROGRAM SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 SHORT TERM EXPOSURE LIMIT THRESHOLD LIMIT VALUE(8 HR. TIME WEIGHTED AVERAGE OR TWA) VOLATILE ORGANIC COMPOUND NEW JERSEY RIGHT TO KNOW LAW NOT DETERMINED MSDS# 70288 --------------------------------------------------------------------------- This data is offered in good faith as typical values and not as a product specification. No warranty either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review the recommendations in specific context of the intended use and determine if they are appropriate. --------------------------------------------------------------------------< End OF MSDS > MATERIAL SAFETY DATA SHEET -------------------------7677 PAGE 1 MATERIAL SAFETY DATA SHEET PAGE 1 -------------------------ABBREVIATIONS: NA=NOT APPLICABLE ND=NOT DETERMINED NE=NOT ESTABLISHED HEALTH= 0 FLAMMABILITY= 0 REACTIVITY= 0 PERSONAL PROTECTION= + WHMIS CLASSIFICATION: D2 + SEE SECTION VII ========================================================SECTION I PRODUCT IDENTIFICATION AND USE MATERIAL NAME/IDENTIFIER: 7677 - WALL PATCH / SHUR PATCH - LIGHTWEIGHT PATCHING COMPOUND MANUFACTURER/SUPPLIER: GH INTERNATIONAL a division of IKO Industries Ltd. 2540 RENA ROAD MISSISSAUGA, ONTARIO L4T3C9 PHONE: 1-905-677-5522 EMERGENCY: 1-613-996-6666 CANUTEC(24 hr. emergency information only) CHEMICAL FAMILY: Mixture CHEMICAL FORMULA/MOLECULAR WT: NA TRADE NAME AND SYNONYMS: NA MATERIAL USE: Spackling/patching compound ======================================================== SECTION II HAZARDOUS INGREDIENTS -----------------------------------------------------------------------------CHEMICAL NAME OSHA-PEL ACGIH-TLV Amorphous Silica 6 mg/m3 - 10 mg/m3 (Total Dust) CAS #63231-67-4 CARCINOGEN: NO ======================================================== SECTION III PHYSICAL DATA APPEARANCE, PHYSICAL STATE AND ODOR: ODOR THRESHOLD (PPM): ND SPECIFIC GRAVITY/DENSITY (G/ML): 0.43-0.47 VAPOR PRESSURE (MM): 25 Deg. C 18 mm VAPOR DENSITY (AIR=1): >1 EVAPORATION RATE (BUAC=1): <1 BOILING POINT: 200-215 Deg. F/93-101 Deg. C MELTING/FREEZING POINT: 0’C PH: 7.0-9.0 COEFFICIENT OF WATER/OIL DISTRIBUTION: ND SOLUBILITY IN WATER: Soluble % VOLATILE BY VOLUME: 20-30 White paste, latex odor. LD50/LC50 %WT/WT ND - 15-25 MATERIAL SAFETY DATA SHEET -------------------------- PAGE 2 ========================================================SECTION IV FIRE OR EXPLOSION DATA FLASH POINT: NA - Water based AUTO IGNITION TEMPERATURE: NA SENSITIVITY TO MECHANICAL IMPACT: NA EXPLOSIVE POWER: NA UPPER EXPLOSION LIMIT: NA LOWER EXPLOSION LIMIT: NA RATE OF BURNING: NA SENSITIVITY TO STATIC DISCHARGE: NA EXTINGUISHING MEDIA: NA SPECIAL FIRE FIGHTING PROCEDURES: NA UNUSUAL FIRE AND EXPLOSION HAZARDS: NA FLAMMABILITY: NO UNDER WHAT CONDITIONS: NA ========================================================SECTION V REACTIVITY DATA STABILITY - MATERIAL IS: Stable CONDITIONS TO AVOID: NA HAZARDOUS DECOMPOSITION/COMBUSTION PRODUCTS: Carbon dioxide, carbon monoxide INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: NA ========================================================SECTION VI TOXICOLOGICAL PROPERTIES PRIMARY ROUTES OF ENTRY: Skin - Ingestion EFFECTS OF OVEREXPOSURE, CHRONIC: None known EFFECTS OF OVEREXPOSURE, ACUTE: Skin: Prolonged/repeated contact may cause slight irritation to sensitive skin. Eyes: Contact may cause irritation. Ingestion: Can cause gastrointestinal upset. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: None known CARCINOGENICITY: NO LD50 OF PRODUCT: ND IRRITANT?: NO SYNERGISTIC MATERIALS: NA REPRODUCTIVE EFFECTS: NO WHMIS CLASSIFICATION: D2 LC50 OF PRODUCT: ND SENSITIZER?: NO TERATOGENIC: NO MUTAGENIC: NO MATERIAL SAFETY DATA SHEET -------------------------- PAGE 3 ========================================================SECTION VII PREVENTIVE MEASURES, SAFE HANDLING AND USE, REGULATORY INFORMATION LEAK AND SPILL PROCEDURES: Dike spill area, recover free liquid. Return to container. Add absorbent to spill area. WASTE DISPOSAL METHOD: Dispose of according to Federal, State and Local regulations. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in cool, dry area. Protect from freezing. OTHER: Keep out of the reach of children! VENTILATION: NA RESPIRATORY PROTECTION: NA PROTECTIVE GLOVES: NA EYE PROTECTION: NA OTHER PROTECTIVE EQUIPMENT: NA WORK/HYGIENIC PRACTICES: Remove contaminated clothing, launder before reuse. REPORTABLE QUANTITY (MIN. UNDER ANY ACT): None RCRA HAZARDOUS WASTE NO: None DOT PROPER SHIPPING NAME: Calking and glaziers compound DOT HAZARD CLASS: Not regulated IDENTIFICATION NO: NMFC Item No. 149610 VOLATILE ORGANIC COMPOUNDS (VOC): <30 G/L TDG CLASSIFICATION (CAN): Not regulated ========================================================SECTION VIII FIRST AID MEASURES EMERGENCY AND FIRST AID PROCEDURES: Skin: Wash with soap and water. Eyes: Flush with copious amounts of water. Contact a physician. Ingestion: Contact a physician immediately. ========================================================SECTION IX PREPARATION INFORMATION Prepared by: Technical Services Dept. Date: November 2007 The information accumulated herein is believed to be accurate but is not warranted to be, whether originating with the Company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. 7677 MATERIAL SAFETY DATA SHEET -------------------------7677 PAGE 1 MATERIAL SAFETY DATA SHEET PAGE 1 -------------------------ABBREVIATIONS: NA=NOT APPLICABLE ND=NOT DETERMINED NE=NOT ESTABLISHED HEALTH= 0 FLAMMABILITY= 0 REACTIVITY= 0 PERSONAL PROTECTION= + WHMIS CLASSIFICATION: D2 + SEE SECTION VII ========================================================SECTION I PRODUCT IDENTIFICATION AND USE MATERIAL NAME/IDENTIFIER: 7677 - WALL PATCH / SHUR PATCH - LIGHTWEIGHT PATCHING COMPOUND MANUFACTURER/SUPPLIER: GH INTERNATIONAL a division of IKO Industries Ltd. 2540 RENA ROAD MISSISSAUGA, ONTARIO L4T3C9 PHONE: 1-905-677-5522 EMERGENCY: 1-613-996-6666 CANUTEC(24 hr. emergency information only) CHEMICAL FAMILY: Mixture CHEMICAL FORMULA/MOLECULAR WT: NA TRADE NAME AND SYNONYMS: NA MATERIAL USE: Spackling/patching compound ======================================================== SECTION II HAZARDOUS INGREDIENTS -----------------------------------------------------------------------------CHEMICAL NAME OSHA-PEL ACGIH-TLV Amorphous Silica 6 mg/m3 - 10 mg/m3 (Total Dust) CAS #63231-67-4 CARCINOGEN: NO ======================================================== SECTION III PHYSICAL DATA APPEARANCE, PHYSICAL STATE AND ODOR: ODOR THRESHOLD (PPM): ND SPECIFIC GRAVITY/DENSITY (G/ML): 0.43-0.47 VAPOR PRESSURE (MM): 25 Deg. C 18 mm VAPOR DENSITY (AIR=1): >1 EVAPORATION RATE (BUAC=1): <1 BOILING POINT: 200-215 Deg. F/93-101 Deg. C MELTING/FREEZING POINT: 0’C PH: 7.0-9.0 COEFFICIENT OF WATER/OIL DISTRIBUTION: ND SOLUBILITY IN WATER: Soluble % VOLATILE BY VOLUME: 20-30 White paste, latex odor. LD50/LC50 %WT/WT ND - 15-25 MATERIAL SAFETY DATA SHEET -------------------------- PAGE 2 ========================================================SECTION IV FIRE OR EXPLOSION DATA FLASH POINT: NA - Water based AUTO IGNITION TEMPERATURE: NA SENSITIVITY TO MECHANICAL IMPACT: NA EXPLOSIVE POWER: NA UPPER EXPLOSION LIMIT: NA LOWER EXPLOSION LIMIT: NA RATE OF BURNING: NA SENSITIVITY TO STATIC DISCHARGE: NA EXTINGUISHING MEDIA: NA SPECIAL FIRE FIGHTING PROCEDURES: NA UNUSUAL FIRE AND EXPLOSION HAZARDS: NA FLAMMABILITY: NO UNDER WHAT CONDITIONS: NA ========================================================SECTION V REACTIVITY DATA STABILITY - MATERIAL IS: Stable CONDITIONS TO AVOID: NA HAZARDOUS DECOMPOSITION/COMBUSTION PRODUCTS: Carbon dioxide, carbon monoxide INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: NA ========================================================SECTION VI TOXICOLOGICAL PROPERTIES PRIMARY ROUTES OF ENTRY: Skin - Ingestion EFFECTS OF OVEREXPOSURE, CHRONIC: None known EFFECTS OF OVEREXPOSURE, ACUTE: Skin: Prolonged/repeated contact may cause slight irritation to sensitive skin. Eyes: Contact may cause irritation. Ingestion: Can cause gastrointestinal upset. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: None known CARCINOGENICITY: NO LD50 OF PRODUCT: ND IRRITANT?: NO SYNERGISTIC MATERIALS: NA REPRODUCTIVE EFFECTS: NO WHMIS CLASSIFICATION: D2 LC50 OF PRODUCT: ND SENSITIZER?: NO TERATOGENIC: NO MUTAGENIC: NO MATERIAL SAFETY DATA SHEET -------------------------- PAGE 3 ========================================================SECTION VII PREVENTIVE MEASURES, SAFE HANDLING AND USE, REGULATORY INFORMATION LEAK AND SPILL PROCEDURES: Dike spill area, recover free liquid. Return to container. Add absorbent to spill area. WASTE DISPOSAL METHOD: Dispose of according to Federal, State and Local regulations. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in cool, dry area. Protect from freezing. OTHER: Keep out of the reach of children! VENTILATION: NA RESPIRATORY PROTECTION: NA PROTECTIVE GLOVES: NA EYE PROTECTION: NA OTHER PROTECTIVE EQUIPMENT: NA WORK/HYGIENIC PRACTICES: Remove contaminated clothing, launder before reuse. REPORTABLE QUANTITY (MIN. UNDER ANY ACT): None RCRA HAZARDOUS WASTE NO: None DOT PROPER SHIPPING NAME: Calking and glaziers compound DOT HAZARD CLASS: Not regulated IDENTIFICATION NO: NMFC Item No. 149610 VOLATILE ORGANIC COMPOUNDS (VOC): <30 G/L TDG CLASSIFICATION (CAN): Not regulated ========================================================SECTION VIII FIRST AID MEASURES EMERGENCY AND FIRST AID PROCEDURES: Skin: Wash with soap and water. Eyes: Flush with copious amounts of water. Contact a physician. Ingestion: Contact a physician immediately. ========================================================SECTION IX PREPARATION INFORMATION Prepared by: Technical Services Dept. Date: November 2007 The information accumulated herein is believed to be accurate but is not warranted to be, whether originating with the Company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. 7677 Material Safety Data Sheet Series: #0511 (All Labels) MSDS # 0033 1-0-0 1-0-0-A NFPA Rating: HMIS Rating: SECTION I TRADE NAME (IF NONE, PUT CHEMICAL) EMERGENCY TELEPHONE NO. Wood Putty Powder (918) 825-5744 (24 Hrs.) CHEMICAL NAME AND SYNONYMS MANUFACTURER'S NAME AND TELEPHONE NO. Red Devil, Incorporated ADDRESS (Number, Street, 4175 Webb Street, Pryor, Oklahoma 74361 ) City, State, Zip Code (918) 825-5744 SECTION II - HAZARDOUS INGREDIENTS % TLV PEL UNITS 10 15 Mg/m3 NE Mg/m3 PRODUCT CONSISTS OF: Gypsum & Aluminum Silicate (8031-18-3) (as nuisance particulate) Wood Flour (as wood dust) >85.0 6.5 Non-Hazardous Ingredients* <10.0 1.0 NA NA * Unlisted ingredients are not considered hazardous under the OSHA Hazardous Communication Standard (29 CFR 1910.1200) VOC: 0%/wt. CARB Compliance: YES. Prop 65 Ingredients: NONE SECTION III - PHYSICAL DATA BOILING POINT (°F) NA SPECIFIC GRAVITY (H20=1) VAPOR PRESSURE (MM Hg.) NA PERCENT VOLATILES BY VOLUME (%) NA VAPOR DENSITY (AIR=1) NA pH NE EVAPORATION RATE NA SOLUBILITY IN WATER APPEARANCE AND ODOR Slight >2.0 Powder, odorless SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Method used) NA FLAMMABLE LIMITS EXTINGUISHING MEDIA Use media suitable for adjacent materials SPECIAL FIRE FIGHTING PROCEDURES No special procedures required UNUSUAL FIRE AND EXPLOSION HAZARDS None known NA - Not Applicable NE - Not Established 1 LEL UN - Unavailable NA UEL NA SECTION V - HEALTH HAZARD INFORMATION SYMPTOM/EFFECTS OR OVEREXPOSURE Inhalation of dust may cause respiratory irritation. Possible skin irritation. Eye contact causes irritation. Chronic overexposure may result in lung damage. FIRST AID EYES Flush eyes with large amounts of water. Get medical attention if irritation persists. SKIN Wash thoroughly with soap & water. Get medical attention if irritation persists. INHALATION Move victim to fresh air. Get medical help if irritation persists. INGESTION Contact local poison control center or physician immediately. SECTION VI - REACTIVITY DATA STABILITY Stable INCOMPATIBLE MATERIALS None Known HAZARDOUS DECOMPOSITION PRODUCTS Carbon monoxide, carbon dioxide, sulfur dioxide SECTION VII - SPILL OR LEAK PROCEDURES PROCEDURES Carefully clean up spilled material & place in dry containers for disposal. Avoid dust generation. WASTE DISPOSAL METHOD Dispose of in accordance with Local, State and Federal regulations. SECTION VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY For symptoms of overexposure, wear a NIOSH-approved respirator for dusts & mists. EYEWEAR If potential for eye contact exists, wear chemical goggles. CLOTHING/GLOVES Not normally required; in situations of extended skin contact, protective gloves are recommended. VENTILATION Local exhaust may be necessary under some handling/use conditions. SECTION IX - SPECIAL PRECAUTIONS Store in a closed container in dry area. This product does not contain ingredients listed in Section 313 of SARA Title III. Reviewed By: NAME Larry G. Brandon VP Technology & General Manager TITLE January 31, 2006 DATE The information contained herein has been developed based upon current available scientific data. New information may be developed from time to time which may render the conclusions of this report obsolete. Therefore, no warranty is extended as to the applicability of this information to the user's intended purpose or for the consequences of its use or misuse. 0511 2 MATERIAL SAFETY DATA SHEET WALLBOARD JOINT COMPOUND HMIS HEALTH 1 FLAMMABILITY 0 REACTIVITY 0 PERSONAL B PROTECTION 1. Product And Company Identification Supplier CUSTOM BUILDING PRODUCTS 13001 SEAL BEACH BLVD. SEAL BEACH, CA 90740 UNITED STATES Manufacturer CUSTOM BUILDING PRODUCTS 13001 SEAL BEACH BLVD. SEAL BEACH, CA 90740 UNITED STATES Company Contact: GEORGE MARCINA Telephone Number: (323) 582-0846 Company Contact: GEORGE MARCINA Telephone Number: (323) 582-0846 Supplier Emergency Contacts & Phone Number GEORGE MARCINA: (323) 582-0846 Manufacturer Emergency Contacts & Phone Number GEORGE MARCINA: (323) 582-0846 Issue Date: 08/05/2005 Product Name: WALLBOARD JOINT COMPOUND CAS Number: Not Established MSDS Number: 315 Product Code: 2017 Product Identification Text THIS MSDS IS APPLICABLE TO THE FOLLOWING PRODUCTS: WALLBOARD JOINT COMPOUND 2. Composition/Information On Ingredients Ingredient Name CAS Number CALCIUM CARBONATE BENTONITECLAY Percent Of Total Weight 471-34-1 60 - 70 1302-78-9 1 -5 3. Hazards Identification Primary Routes(s) Of Entry NUSANCE DUST CAN BE RELEASED DURING DRY SANDING. EYES, SKIN, NOSE Eye Hazards SLIGHT EYE IRRITATION. CORNEAL INJURY IS UNLIKELY. Skin Hazards PROLONGED EXPOSURE MAY IRRITATE SKIN. Ingestion Hazards INGESTION UNLIKELY Inhalation Hazards PROLONGED EXPOSURE TO NUSANCE DUST ABOVE THE THRESHOLD LIMIT VALUE MAY CAUSE IRRITATION TO THE NESE THROAT LUNGS AND UPPER RESPIRATORY TRACT. SHORTNESS OF BREATH Page 1 of 4 MATERIAL SAFETY DATA SHEET WALLBOARD JOINT COMPOUND 3. Hazards Identification - Continued Inhalation Hazards - Continued MAY ALSO OCCUR AFTER EXCESSIVE INHALATION. Chronic/Carcinogenicity Effects Contains Bentonite clay which may contain small amounts of Silica, Crystaline Quartz, Class 2A carcinogen Conditions Aggravated By Exposure NONE KNOWN. 4. First Aid Measures Eye IMMEDIATELY FLUSH WITH WATER. IF IRRITATION DEVELOPS, GET MEDICAL ATTENTION Skin WASH WITH SOAP AND WATER. IF IRRITATION DEVELOPS, GET MEDICAL ATTENTION. Ingestion NO KNOWN EFFECTS Inhalation REMOVE TO FRESH AIR. IF NECESSARY, SEEK MEDICAL ATTENTION. 5. Fire Fighting Measures Flash Point: NONE °F Flash Point Method: NONE Lower Explosive Limit: N/A Upper Explosive Limit: N/A Fire And Explosion Hazards MATERIAL IS NON FLAMMABLE 6. Accidental Release Measures IN CASE MATERIAL IS RELEASED OR SPILLED, AVOID ENTRY INTO SEWERS OR NATURAL WAER WAYS. SOAK UP SMALL SPILLS WITH ABSORBANT MATERIAL. FOR LARGE SPILLS, DIKE AND PUMP INTO SUITABLE CONTAINERS FOR DISPOSAL. 7. Handling And Storage Handling And Storage Precautions STORE IN COOL, DRY AREA OUT OF SUNLIGHT. STORE AWAY FROM HEAT OR ANY HEAT SOURCES. PROTECT FROM FREEZING. Work/Hygienic Practices HYGEINE AND GOOD HOUSEKEEPING PRACTICES SHOULD BE OBSERVED. 8. Exposure Controls/Personal Protection Eye/Face Protection SAFETY GLASSES ARE RECOMMENDED TO SAFEGUARD AGAINST POTENTIAL CONTACT. Skin Protection THE USE OF PLASTIC OR RUBBER GLOVES WILL PREVENT SKIN IRRITATION OF SENSITIVE INDIVIDUALS. Other/General Protection Page 2 of 4 MATERIAL SAFETY DATA SHEET WALLBOARD JOINT COMPOUND 8. Exposure Controls/Personal Protection - Continued Ingredient(s) - Exposure Limits CALCIUM CARBONATE ACGIH TLV-TWA 10 mg/m3 OSHA PEL-TWA 15 mg/m3 OSHA PEL-TWA 5 mg/m3 BENTONITE CLAY Classified as niusance dust but respirable dust may contain Silica, Crystali ne Quartz, If more than 1% of Silica is present then: OSHA PEL - 500 mg / m3 ACGIH - TLV - 10 mg / m3 9. Physical And Chemical Properties Appearance WHITE, CREAMY PASTE Odor MILD Chemical Type: Mixture Physical State: Liquid Boiling Point: 212 °F Specific Gravity: 1.6 Vapor Density: HEAVIER THAN AIR Solubility: MISSIBLE IN WATER UNTIL DRIED Evaporation Rate: SLOWER THAN ETHER 10. Stability And Reactivity Sta bility: STABLE Hazardous Polymerization: WILL NOT OCCUR. Conditions To Avoid (Stability) NONE KNOWN. Incompatible Materials AVOID CONTACT WITH STRONG STRONG ACIDS. Conditions To Avoid (Polymerization) HAZARDOUS POLYMERIZATION WILL NOT OCCUR. 11. Toxicological Information No Data Available... 12. Ecological Information No Data Available... 13. Disposal Considerations DISPOSE OF PRODUCT IN ACCORDANCE WITH APPLICABLE LOCAL, COUNTY, STATE AND FEDERAL REGULATIONS. RCRA Information Not considered RCRA waste Page 3 of 4 MATERIAL SAFETY DATA SHEET WALLBOARD JOINT COMPOUND 14. Transport Information No Data Available... 15. Regulatory Information Ingredient(s) - State Regulations CALCIUM CARBONATE Pennsylvania - Workplace Hazard BENTONITE CLAY California - Proposition 65 16. Other Information HMIS Rating He a lth: 1 Fire : 0 Re a ctivity: 0 Personal Protection: B Revision/Preparer Information MSDS Preparer: GEORGE MARCINA MSDS Preparer Phone Number: (323) 582-0846 This MSDS Supercedes A Previous MSDS Dated: 12/14/2003 Disclaimer THE INFORMATION PRESENTED HERE IS BELIEVED TO BE ACCURATE BUT IS NOT WARRANTED TO BE, WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED, THAT THE INFORMATION IS CURRENT, APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. CUSTOM BUILDING PRODUCTS Printed Using MSDS Generator™ 2000 Page 4 of 4 MATERIAL SAFETY DATA SHEET MSDS #88-910-005E Page 1 of 1 CGC Brand Fiberglass Tape CGC Inc. 350 Burnhamthorpe Rd. W., 5th Floor Mississauga, Ontario L5B 3J1 (905) 803-5600 Fax (905) 803-5688 A Subsidiary of USG Corporation Product Safety: 1 (800) 507-8899 www.cgcinc.com Version Date: April 2, 2004 Version: 3 SECTION 1 CHEMICAL PRODUCT AND IDENTIFICATION PRODUCT: CGC Brand Fiberglass Tape CHEMICAL FAMILY: Fiberglass with adhesive tape SECTION 2 COMPOSITION, INFORMATION ON INGREDIENTS MATERIAL Fibrous Glass (Continuous Filament) WT% 65-70 TLV (mg/m3) 1 f/cc(R) PEL( mg/m3) 15(T)/5(R) CAS NUMBER 65997-17-3 (T) – Total (R) – Respirable (NE) – Not Established mmpfc - million particles per cubic foot of air All ingredients of this product are included in the U.S. Environmental Protection Agency’s Toxic Substances Control Act Chemical Substance Inventory. All components of this product are included in the Canadian Domestic Substances List (DSL). SECTION 3 HAZARD IDENTIFICATION INFORMATION FOR HANDLING AND IDENTIFICATION OF CHEMICAL HAZARDS 0 = Minimal Hazard 0 HEALTH 0 NFPA Ratings: HIMS Ratings: 1 = Slight Hazard 0 FLAMMABILITY Health: 0 Health: 0 2 = Moderate Hazard 0 0 0 PHYSICAL HAZARD Fire: 0 Fire: 0 3 = Serious Hazard PERSONAL PROTECTION Reactivity: 0 Reactivity: 0 4 = Severe Hazard EMERGENCY OVERVIEW: This product is not expected to produce any unusual hazards during normal use. However, it may be possible to create and release nuisance dust if tape is sanded when sanding joints. Eye, nose and upper respiratory irritation may occur with prolonged exposure to high dust. POTENTIAL HEALTH EFFECTS ACUTE: Eyes: Direct contact of fibers may cause irritation. Direct contact of particulate may cause mechanical irritation of the eyes. If burning, redness, itching, pain or other symptoms persist or develop, consult a physician. Skin: Direct contact with the skin may cause irritation. Inhalation: Overexposure to glass fibers may produce irritation of the nose, throat, and upper respiratory system. Persons subjected to overexposure to large amounts of dust will be forced to leave area because of nuisance conditions such as coughing, sneezing and nasal irritation from dust. Labored breathing may occur after excessive inhalation. If respiratory symptoms persist, consult physician. Ingestion: There are no known health effects due to ingestion. Due to the physical nature of this product, ingestion is unlikely. Wash hands before eating. CHRONIC: Direct, prolonged or repeated contact with the skin may cause irritation. MATERIAL SAFETY DATA SHEET MSDS #88-910-005E Page 2 of 2 CGC Brand Fiberglass Tape SECTION 4 FIRST AID MEASURES FIRST AID PROCEDURES Eyes: In case of contact, do not rub or scratch your eyes. Flush thoroughly with water for 15 minutes to remove particulates. If irritation persists, consult physician. Skin: Wash with mild soap and water. If irritation persists, consult physician. Inhalation: Remove to fresh air. Leave the area of high dust exposure until coughing and other symptoms subside. Ingestion: Not likely to occur. If ingested, call physician. TARGT ORGANS: Eyes, Skin, and Respiratory System. PRIMARY ROUTES OF ENTRY: Eyes, Skin, and Respiratory System. SECTION 5 FIRE FIGHTING MEASURES None known. General Fire Hazards: Water or use extinguishing media appropriate for surrounding fire. Extinguishing Media: Fire fighters should wear protective gear appropriate for surrounding fire. Special Fire Fighting Procedures: None known. Unusual Fire & Explosion Hazards: None known. Hazardous Combustion Products: None Known Not Applicable Flash Point: Auto Ignition: Not Applicable Method Used: Flammability Not Applicable Classification: Upper Flammable Limit (UFL): Not Applicable Not Applicable Lower Flammable Limit (LFL): Not Applicable Rate of Burning: SECTION 6 ACCIDENTAL RELEASE MEASURES CONTAINMENT/ CLEAN-UP: No special precautions. Dust or loose fibers may be vacuumed or swept up with the aid of a dust suppressant. DISPOSAL: In most cases, woven fiberglass scrap can be disposed of in a sanitary landfill. SECTION 7 HANDLING AND STORAGE HANDLING: Avoid contact with skin and eyes. STORAGE: Keep dry MATERIAL SAFETY DATA SHEET MSDS #88-910-005E Page 3 of 3 CGC Brand Fiberglass Tape SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION ENGINEERING CONTROLS: Selection of engineering controls will depend on environmental working conditions and operations. RESPIRATORY PROTECTION: Special ventilation typically is not necessary, but may be desirable in specific work conditions. Use mechanical or local exhaust ventilation to keep levels below TLV. OTHER PERSONAL PROTECTIVE EQUIPMENT: Eye/Face: Wear eye protection (safety glasses or goggles) to avoid particulate irritation of the eye. Skin: Gloves or protective clothing are usually not necessary, but may be desirable in specific work conditions. General: Selection of Personal Protective Equipment will depend on environmental working conditions and operations. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical State Odor pH @ 25 º C Particle Size Molecular Weight Bulk Density Specific Gravity (H20 = 1) Percent Volatile VOC Content White woven scrim type fabric. Solid Viscosity Low to no odor Solubility (H2O) Not Applicable Boiling Point Not Applicable Melting Point Not Applicable Softening Point Not Applicable Freezing Point Not Applicable Vapor Density (Air = 1) Zero Vapor Pressure (mm Hg) Zero Evaporation Rate (BuAc = 1) SECTION 10 CHEMICAL STABILITY AND REACTIVITY STABILITY: CONDITIONS TO AVOID: INCOMPATIBILITY: HAZARDOUS POLYMERIZATION: HAZARDOUS DECOMPOSITION: Stable. Contact with incompatibles. Hydroflouric acid. Will not occur. None known. SECTION 11 TOXICOLOGICAL INFORMATION ACUTE EFFECTS: Direct contact may cause eye, skin and/or respiratory irritation. LD50: Not Available for product. LC50: Not Available for product. CHRONIC EFFECTS / CARCINOGENICITY: Direct, prolonged or repeated contact with the skin may cause irritation. Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable MSDS #88-910-005E Page 4 of 4 MATERIAL SAFETY DATA SHEET CGC Brand Fiberglass Tape SECTION 12 ECOLOGICAL INFORMATION ENVIRONMENTAL TOXICITY: This product has no known adverse effect on the ecology. Ecotoxicity value: Not determined. SECTION 13 DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: In most cases, woven fiberglass scrap can be disposed of in a sanitary landfill. Dispose of material in accordance with Federal, State, Provincial, and Local regulations SECTION 14 TRANSPORT INFORMATION U.S. DOT INFORMATION: Not a hazardous material per DOT shipping requirements. Not classified or regulated. Same as product name. Shipping Name Not classified Hazard Class: None. Not classified. UN/NA #: None. Packing Group: Not applicable. Label (s) Required: Not classified. GGVSec/MDG-Code: Not applicable. ICAO/IATA-DGR: None RID/ADR: None ADNR: SECTION 15 REGULATORY INFORMATION UNITED STATES REGULATIONS MATERIAL WT% 302 304 313 CERCLA CAA Sec. 112 RCRA Code All ingredients of this product are included in the U.S. Environmental Protection Agency’s Toxic Substances Control Act Chemical Substance Inventory. Fibrous Glass (Continuous Filament) 65-70 NL NL NL NL NL NL Key : NL = Not Listed SARA Title III Section 302 (EPCRA) Extremely Hazardous Substances: Threshold Planning Quantity (TPQ) SARA Title III Section 304 (EPCRA) Extremely Hazardous Substances: Reportable Quantity (RQ) SARA Title III Section 313 (EPCRA) Toxic Chemicals: X= Subject to reporting under section 313 CERCLA Hazardous Substances: Reportable Quantity (RQ) CAA Section 112 (r) Regulated Chemicals for Accidental Release Prevention: Threshold Quantities(TQ) RCRA Hazardous Waste: RCRA hazardous waste code MSDS #88-910-005E Page 5 of 5 MATERIAL SAFETY DATA SHEET CGC Brand Fiberglass Tape SECTION 15 REGULATORY INFORMATION (continued) CANADIAN REGULATIONS This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. All components of this product are included in the Canadian Domestic Substances List (DSL). MATERIAL Fibrous Glass (Continuous Filament) WT% 65-70 IDL Item # Not Listed WHMIS Classification: Not Listed IDL Item # : Canadian Hazardous Products Act – Ingredient Disclosure List Item # WHMIS Classification: Workplace Hazardous Material Information System CARCINOGENICITY CLASSIFICATION OF INGREDIENT(S): None SECTION 16 OTHER INFORMATION ∆WARNING! Avoid exposure to dust. Dust may cause eye, skin, nose, throat or respiratory irritation. Avoid eye contact or inhalation of dust. Wear eye protection. If eye contact occurs, flush thoroughly with water. If dusty conditions exist, wear a NIOSH/MSHA-approved respirator to prevent coughing, sneezing and respiratory irritation. Do not ingest. If ingested, call physician. Product safety information: (800) 507-8899 or www.cgcinc.com KEEP OUT OF REACH OF CHILDREN. Key/Legend TLV PEL CAS NIOSH MSHA OSHA ACGIH IARC DOT EPA NFPA HMIS PPE TSCA DSL NDSL SARA RCRA CERCLA UN/NA# CFR WHMIS Threshold Limit Value Permissible Exposure Limit Chemical Abstracts Service (Registry Number) National Institute for Occupational Safety and Health Mine Safety and Health Administration Occupational Health and Safety Administration American Conference of Governmental Industrial Hygienists International Agency for Research on Cancer United States Department of Transportation United States Environmental Protection Agency National Fire Protection Association Hazardous Materials Identification System Personal Protection Equipment Toxic Substances Control Act Canadian Domestic Substances List Canadian Non-Domestic Substances List Superfund Amendments and Reauthorization Act of 1986 Resource Conservation and Recovery Act Comprehensive Environmental Response, Compensation and Liability Act of 1980 United Nations/North America number Code of Federal Regulations Workplace Hazardous Material Information System MATERIAL SAFETY DATA SHEET CGC Brand Fiberglass Tape SECTION 16 OTHER INFORMATION (continued) Prepared by: Product Safety USG Corporation 125 South Franklin St. Chicago, Illinois 60606 MSDS #88-910-005E Page 6 of 6 Material Safety Data Sheet U.S. Department of Labor May be used to comply with OSHA’s Hazard Communication Standard, 29 CFR 1910 1200. Standard must be consulted for specific requirements. Occupational Safety and Health Administration (Non-Mandatory Form) Form Approved OMB No. 1218-0072 Note: Blank spaces are not permitted. If any item is not applicable or no information is available, the space must be marked to indicate that. IDENTITY (as Used on Label and List) Silicon Carbide Sanding Screen Section I Manufacturer’s name Superior Abrasives, Inc. Emergency Telephone Number 1-937-278-9123 Address (Number, Street, City, State and ZIP Code) Telephone Number for Information 1-937-278-9123 4800 Wadsworth Road Date Prepared January 1, 2006 Dayton, OH 45413 Signature of Preparer (optional) Section II—Hazardous Ingredients/Identity Information Hazardous Components (Specific Chemical Identity, Common Name(s)) OSHA PEL 3 Abrasive Grain: Silicon Carbide 15mg/m Binding Resin: Epoxy and Phenol Formaldehyde Resin (Cured) N/A Flexible Backing: Cloth N/A Other Limits Recommended ACGIH TLV 3 10mg/m N/A N/A % (optional) 55-65 5-15 20-30 Section III—Physical/Chemical Characteristics Boiling Point Specific Gravity (H20 = 1) N/A N/A Vapor Pressure (mm Hg) N/A Melting Point N/A Vapor Density (AIR = 1)N/A Evaporation Rate (Butyl Acetate = 1) N/A Solubility in Water N/A Appearance and Odor Cones of cloth coated with abrasive grain and resin binder Section IV—Fire and Explosion Hazard Data Flash Point (Method Used)N/A Flammable Limits LEL N/A UEL N/A Extinguishing Media Carbon Dioxide, Foam, Water, Dry Chemical Special Fire Fighting Procedures None Unusual Fire and Explosion Hazards (Reproduce locally) None OSHA 174 Sept. 1985 Section V—Reactivity Data Stability Unstable Conditions to Avoid None Stable XX Incompatibility (Materials to Avoid) None Hazardous Decomposition or Byproducts None May Occur Hazardous Polymerization Conditions to Avoid None Will Not Occur XX Section VI—Health Hazard Data Route(s) of Entry Inhalation? Airborne Dust Health Hazards (Acute and Chronic) Ingestion? N/A Acute: Breathing difficulty: skin, eye, nasal, and respiratory irritation. Carcinogenicity N/A NTP? N/A Signs and Symptoms of Exposure Skin? N/A IARC Monographs? N/A OSHA Regulated? no Deposits of Material on the skin, in the eyes and/or nasal passages. Coughing and/or difficulty Breathing may be present. Medical Conditions Generally Aggravated by Exposure Pulmonary Disorders Emergency and First Aid Procedures Provide fresh air. Flush eyes with approved eye wash. Section VII—Precautions for Safe Handling and Use Steps to Be Taken in Case Material Is Released or Spilled Waste Disposal Method By any conventional means Precautions to Be Taken in Handling and Storing Other Precautions No special procedures No special procedures Observe recommended running speeds Section VII—Control Measures Respiratory Protection (Specify Type) Ventilation Local Exhaust utilize approved respiratory protection for nuisance dust. Utilize to keep airborne concentration Special N/A below limits Mechanical (General) Appropriate hoods and dust collection recommended Protective Gloves Recommended to protect skin from abrasion Other Protective Clothing or Equipment Work/Hygienic Practices None Ordinary personal cleanliness practices Other N/A Eye Protection Face shield or goggles when grinding MATERIAL SAFETY DATA SHEET NPCA FOR COATINGS, RESINS AND RELATED MATERIALS (Approved by US Department of Labor Essentially Similar to Form OSHA 20) Date Issued 11/30/05 SECTION I MANUFACTURER’S NAME GARDNER ASPHALT CORPORATION. STREET ADDRESS 4161 E 7TH AVENUE CITY, STATE, AND ZIP CODE TAMPA, FL 33605 EMERGENCY TELEPHONE NUMBER 1-800-424-9300 PRODUCT CLASS ROOF CEMENT MASTIC A/F (WET/DRY) AKA PLASTIC RF CEMENT/FLASHING CEMENT TRADE NAME MANUFACTURER’S CODE IDENTIFICATION 0370-GA, 0375-GA GARDNER, WEATHERSEAL, STA-KOOL, BLACKJACK SECTION II- HAZARDOUS INGREDIENTS INGREDIENT PERCENT PETROLEUM ASPHALT CAS # - 8052-42-4 STODDARD SOLVENT CAS #- 8052-41-3 CELLULOSE FIBER CAS #- 9004-34-6 SILICATE MINERAL CAS #- 7631-86-9 TLV PPM <40% TLV Mg/M3 LEL VAPOR PRESSURE 0.5 Fume <20% 100 <10% 10* <20% 10* ADDITIONAL INFORMATION- * AS RESPIRABLE FRACTION OF DUST Hazardous Materials Identification System (HMIS) Health 1 Flammability 2 Reactivity Personal Protection C 1 SECTION III – PHYSICAL DATA BOILING RANGE: 300 ºF - 390ºF EVAPORATION RATE FASTER VAPOR DENSITY SLOWER, THAN ETHER HEAVIER LIGHTER, THAN AIR PERCENT VOTILE BY VOLUME 60 % WEIGHT PER GALLON BY VOLUME 8.4 LBS SECTION IV – FIRE AND EXPLOSION HAZARD DATA DOT CATEGORY - NA FLASH POINT- 105ºF Minimum EXTINGUISHING MEDIA- CO2, FOAM, & DRY CHEMICAL . DO NOT USE HALOGENATED EXTINGUISHING AGENTS. UNUSUAL FIRE AND EXPLOSION HAZARDS- CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. PRODUCTS OF COMBUSTION MAY BE TOXIC. SPECIAL FIRE FIGHTING PROCEDURES- WEAR MSHA/NIOSH APPROVED POSITIVE BREATHING APPARATUS IS RECOMMENDED FOR FIREFIGHTERS. WATER MAY BE USED TO COOL CLOSED CONTAINERS, BUT MAY CAUSE FROTHING, APPLY CAUTIOUSLY. HIGH PRESSURE STREAM WILL SPREAD FIRE. DO NOT USE HALOGENATED EXTINGUISHING AGENTS!. SECTION V – REACTIVITY DATA STABILITY: UNSTABLE STABLE CONDITIONS TO AVOID: SPARK, FLAMES, ELECTRICAL AND STATIC DISCHARGE. INCOMPATIBILTY (MATERIALS TO AVOID): STRONG OXIDIZERS, ACIDS, AND HALOGENATED CHEMICALS HAZARDOUS DECOMPOSITION PRODUCTS: CARBON DIOXIDE, CARBON MONOXIDE, NOX, SOX, H2S AND REACTIVE HYDROCARBONS HAZARDOUS POLYMERIZATION: MAY OCCUR WILL NOT OCCUR CONDITIONS TO AVOID: NONE SECTION VI-HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE- ACUTE: SKIN: PROLONGED REPEATED CONTACT MAY CAUSE IRRITATION. EYES: CONTACT MAY CAUSE IRRITATION, BLURRED VISION, REDNESS. INHALATION: EXCESSIVE BREATHING OF HIGH VAPOR CONCENTRATION CAN CAUSE POSSIBLE UNCONSCIOUSNESS AND EVEN ASPHYXIATION. INGESTION: CAN CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING AND DIARRHEA. CARCINOGENICITY: MATERIAL CONTAINS PETROLEUM ASPHALT. IARC HAS DETERMINED THAT THERE IS ANADEQUATE EVIDENCE THAT ASPHALT ALONE IS CARCINOGENIC TO HUMANS, IN SOLUTION; SOLVENT EXTRACTS CAN PRODUCE SKIN CANCER IN ANIMALS FOLLOWING PROLONGED AND REPEATED CONTACT. IARC HAS CONCLUDED THAT THERE IS SUFFICIENT EVIDENCE OF THE CARCINOGENICITY OF ASPHALT EXTRACTS. THEREFORE, CUTBACKS LIKE THIS PRODUCT MAY ALSO BE IMPLICATED AS POTENTIALLY CARCINOGENIC. PLEASE FOLLOW MSDS PRECAUTIONARY MEASURES. SYNERGISTIC MATERIALS: N/A. REPRODUCTIVE EFFECTS: ND. TERATOGENIC: NO. MUTAGENIC: NO. CALIF. PROP. 65 • CHEMICAL WARNING (CALIFORNIA HEALTH AND SAFETY CODE #25249.5 ET SEQ). WARNING: This product contains chemicals known to the State of California to cause cancer, birth defects or reproductive harm. Read and follow label directions and information given on Material Safety Data Sheets and use care when handling or using all petroleum products. EMERGENCY FIRST AID PROCEDURE- SKIN: WASH EXPOSED AREAS WITH SOAP AND WATER. EYES: FLUSH EYES WITH COPIOUS AMOUNTS OF WATER , IF SYMPTOMS PERSIST, CONSULT A PHYSICIAN. INHALATION: REMOVE PERSON TO FRESH AIR. IF BREATHING IS DIFFICULT ADMINISTER OXIGEN. IF BREATHING STOPS, GIVE ARTIFICIAL RESPIRATION. SEEK MEDICAL ATTENTION IMMEDIATELY. INGESTION: DO NOT INDUCE VOMITING. SECTION VII – SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: SOAK UP SPILL WITH SAND OR OTHER ABSORBENT. REMOVE SOURCES OF IGNITION. PLACE IN CONTAINERS. WASH AREA. WASTE DISPOSAL METHOD: DISPOSE IN ACCORDANCE WITH LOCAL, STATE OR FEDERAL REGULATIONS. SECTION VIII – SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: NOT NORMALLY REQUIRED IN WELL-VENTILATED AREA. IF TLV IS EXCEEDED, A NIOSH/MSHA APPROVED BREATHING APPARATUS IS RECOMMENDED. VENTILATION: USE WITH ADEQUATE VENTILATION. MAINTAIN EXPOSURE BELOW TLV LEVEL. PROTECTIVE GLOVES: NITRILE RUBBER GLOVES SHOULD BE USED, AS WELL AS LONG SLEEVES. EYE PROTECTION: FACE SHIELD AND SAFETY GOGGLES SHOULD BE USED. OTHER PROTECTIVE EQUIPMENT: SOLVENT RESISTANT APRON AND BOOTS SECTION IX – REGULATORY INFORMATION PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: STORE IN COOL DRY AREA. OTHER PRECAUTIONS: KEEP OUT OF REACH OF CHILDREN AND AWAY FROM SOURCES OF IGNITION. AVOID CONTACT WITH SKIN OR CLOTHING. KEEP CONTAINER CLOSED. WASH THOROUGHLY AFTER USING. MATERIAL SAFETY DATA SHEET MSDS Number: TP004997 Revision Date: May 2007 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION TRADE NAME: 808 Cold Application Cement, 829 Fibered Roof Coating LABEL: TAM-PRO USE & DESCRIPTION: Roofing Coatings CHEMICAL FAMILY: Asphalt Mixture MANUFACTURED FOR: TAMKO Building Products, Inc. P.O. Box 1404 Joplin, MO 64802-1404 EMERGENCY TELEPHONE NUMBERS; General Information: 1-904-284-7571 (8 a.m. - 5 p.m. EST) 1-620-429-1800 (8 a.m. - 5 p.m. CST) 1-417-624-6644 (8 a.m. - 5 p .m. CST) Chemtrec: 1-800-424-9300 2. COMPOSITION/INFORMATION ON INGREDIENTS Exposure Limits* Components Cas No. % by Wt. OSHA TWA ACGIH STEL TWA STEL Unit Petroleum asphalt 8052-42-4 <70 5 fume NE .5 fume NE mg/m³ Mineral spirits 8052-41-3 <30 200 NE 100 NE ppm Clay** 1332-58-7 <15 10 total dust 5 resp. dust NE mg/m³ mg/m³ Cellulose fibers 65996-61-4 <6 NE NE Calcium carbonate** 1317-65-3 <5 10 total dust 5 resp. dust NE mg/m³ mg/m³ 0.1 0.05 NE NE mg/m³ mg/m³ **contains: crystalline silica >0.1% quartz 14808-60-7 crystobalite 14464-46-1 15 total dust NE 5 resp. dust NE 15 total dust NE 5 resp. dust >0.1 0.1 0.05 *See Section 8 for additional relevant exposure limits NE = Not established Doc. No. 8165 NE 1 of 9 NE NE MSDS Number: TP004997 Revision Date: May 2007 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: WARNING! COMBUSTIBLE VAPORS, MISTS OR FUMES MAY IRRITATE THE EYES AND RESPIRATORY TRACT MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION DIRECT CONTACT MAY CAUSE EYE AND SKIN IRRITATION HEATING MAY RELEASE TOXIC HYDROGEN SULFIDE GAS (H2S) WHICH MAY ACCUMULATE IN CONFINED SPACES ASPIRATION HAZARD IF SWALLOWED ASPHALT MAY CONTAIN COMPONENTS THAT ARE SKIN CANCER HAZARDS HMIS Rating: Health - 1 Flammability - 2 Reactivity - 0 NFPA Rating: Health - 2 Flammability - 2 Reactivity - 0 Potential Health Effects: EYE CONTACT: May cause eye irritation resulting in tearing, stinging, redness or swelling. Vapors, mists, or fumes may be irritating. SKIN CONTACT: Contact may cause skin irritation. Redness, drying and cracking of the skin (dermatitis), may occur following prolonged and repeated contact. In addition, prolonged and repeated exposure to asphalt fumes has been reported to cause an acne-like skin condition, skin discoloration, and may increase sensitivity to the sun (photosensitization). SKIN ABSORPTION: Not expected to be significant with short-term skin contact. However, prolonged or repeated skin contact may result in absorption of hazardous components. INGESTION: In general, asphalt products have low toxicity when swallowed. However, this product may cause irritation of the digestive tract followed by vomiting and central nervous system depression (see “Inhalation” for symptoms). If vomiting occurs, small amounts of material can be aspirated into the lung and cause inflammation or damage with chemical pneumonia. INHALATION: Exposure to fumes, vapors, or mists may cause irritation of the nose and throat, and possible signs of central nervous system depression (symptoms may include headache, excitation, dizziness, a loss of coordination, and drowsiness). Loss of consciousness can occur in poorly ventilated or confined spaces. Additional signs and symptoms of exposure may include reduced appetite and abnormal fatigue. Use of this product in well-ventilated working conditions is not expected to cause adverse effects. Doc. No. 8165 2 of 9 MSDS Number: TP004997 Revision Date: May 2007 NOTE: Hydrogen sulfide (H2S), an extremely toxic gas, may be emitted from heated asphalt and may accumulate in storage tanks and other confined spaces. At low concentrations, H2S is irritating to the eyes, nose and throat, and at high concentrations (>500 ppm) can cause rapid unconsciousness and death. The odor of H2S cannot be used as an indicator of exposure, because the gas causes rapid olfactory fatigue which deadens the sense of smell. Use this product only under well-ventilated working conditions. CHRONIC EFFECT/CARCINOGENICITY/SPECIAL TOXIC EFFECTS: This product contains petroleum asphalt. Petroleum asphalt is not listed as a carcinogen by OSHA or NTP. The International Agency for Research on Cancer (IARC) has determined there is inadequate evidence that asphalt alone is carcinogenic to humans, and that there is inadequate evidence for the carcinogenicity of undiluted air-refined asphalts in experimental animals. The National Institute of Occupational Safety and Health (NIOSH) has, concluded that at higher temperatures roofing asphalt fumes are a potential occupational carcinogen. If this product is heated or comes in contact with heated material, avoid breathing fumes. This material contains a hydrocarbon solvent. When dissolved in hydrocarbon solvents, asphalt has produced skin tumors in animals following prolonged and repeated contact. Consequently, IARC has determined that there is sufficient evidence that extracts or cutbacks (asphalts dissolved in hydrocarbon solvents) are carcinogenic to experimental animals. This product may contain small amounts of polyaromatic hydrocarbons which are recognized carcinogens in humans and experimental animals. This material contains a hydrocarbon solvent. Reports have associated prolonged or repeated occupational overexposure to solvents with permanent brain and nervous system damage (sometimes referred to as “Solvent or Painters Syndrome”. Intentional misuse by deliberately inhaling vapors of this product may be harmful or fatal. This product contains small amounts of respirable crystalline silica (quartz and crystobalite). IARC and NTP have determined that there is sufficient evidence for the carcinogenicity of respirable crystalline silica in experimental animals and limited evidence for its carcinogenicity in humans. The presence of crystalline silica in this product is not expected to present an inhalation hazard since the material is not a dust and is typically troweled onto a surface and allowed to harden. In addition, the hardened product is not anticipated to present a health hazard unless is subjected to mechanical forces including grinding, drilling, or other demolition work. In such cases, the silica may be liberated in dust form. Prolonged and repeated exposure to respirable silica-containing dust may have serious lung effects, including silicosis, bronchitis, and lung cancer. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing medical conditions that may be aggravated by exposure include disorders of the skin and respiratory tract including asthma. Doc. No. 8165 3 of 9 MSDS Number: TP004997 Revision Date: May 2007 4. FIRST AID MEASURES EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the eye lids to ensure thorough rinsing. Get medical attention if irritation persists. Get immediate medical attention if there is direct eye contact with hot material. SKIN CONTACT: Clean any exposed skin with warm soapy water. Use a waterless hand cleaner to help remove the asphalt. Do not use solvents or thinners to remove material from skin. Get medical attention if irritation persists or develops. INGESTION: If swallowed, do not induce vomiting because of danger of aspirating material into lungs, resulting in damage and chemical pneumonia. Never give anything by mouth to an unconscious person. If vomiting occurs, keep head lower than hips to prevent aspiration. Get immediate medical attention. INHALATION: If inhalation overexposure to vapors, mists, or fumes occurs, remove person to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Get immediate medical attention. NOTES TO PHYSICIAN: Medical personnel can soften and remove asphalt with petroleum jelly or white mineral oil. In general, emesis induction is unnecessary in high viscosity products. Also contains mineral spirits that, when aspirated into the lung, may result in chemical pneumonia. If large volumes have been swallowed, gastric lavage should be considered. Patients may be predisposed to pneumonia during convalescence, and should be kept under observation. Inhalation exposure of hydrogen sulfide may also result in pulmonary congestion. Contact a Poison Center for additional treatment information. 5. FIRE FIGHTING MEASURES FLASH POINT (METHOD): 112 ºF (COC) FLAMMABLE LIMITS (% VOLUME IN AIR - SOLVENT COMPONENT): Lower= 0.8 Upper = 7.0 AUTOIGNITION TEMPERATURE: 460 ºF EXTINGUISHING MEDIA: Dry chemical and carbon dioxide or foam, are preferred. Avoid use of straight-stream water. SPECIAL FIRE FIGHTING PROCEDURES: Combustible. Avoid breathing irritating and potentially toxic fumes, including hydrogen sulfide gas. Firefighters should not enter confined spaces without wearing NIOSH approved positive pressure breathing apparatus (SCBA) with full face mask and full protective equipment. Water may be used to cool containers in a fire-exposed area. Doc. No. 8165 4 of 9 MSDS Number: TP004997 Revision Date: May 2007 UNUSUAL FIRE OR EXPLOSION HAZARDS: When heated above the flashpoint of the mineral spirit component (100oF), fumes may burn if ignition source is provided. Petroleum asphalt fumes can explode if emitted in an enclosed environment and supplied with an ignition source. Containers exposed to intense heat from fires should be cooled with water to prevent vapor pressure buildup which could result in container rupture. 6. ACCIDENTAL RELEASE MEASURES PRECAUTIONS IF MATERIAL IS SPILLED OR RELEASED: Combustible. Handling equipment must be grounded to prevent sparking. Remove ignition sources, ventilate area, and avoid inhalation or skin contact by using appropriate precautions outlined in this MSDS (see Section 8). Stop leak and contain spilled material with absorbent material. Collect adsorbed product and clean up materials in appropriate container for proper disposal. Move containers from spill area. For larger spills, keep unnecessary people away. Stay upwind of and away from spill. Notify proper authorities. Prevent materials from entering drains, sewers, or waterways. Spills entering surface waters or sewers (entering/leading to surface waters), that cause a sheen, must be reported to the National Response Center (1-800-424-8802). WASTE DISPOSAL METHODS: Dispose in accordance with applicable Federal, State and Local regulations. 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Store away from heat and all ignition sources and open flames in accordance with applicable laws and regulations. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Follow protective controls outlined in this MSDS (see Section 8). Avoid all ignition sources. Storage areas should be ventilated to reduce fire and explosion hazards, and possible overexposure of personnel to fumes and vapors. Keep containers closed when not in use. Do not store near food and beverages or smoking materials. NOTE: Hydrogen sulfide (H2S), an extremely toxic gas, may be emitted from heated asphalt and may accumulate in storage tanks and other confined spaces. Empty containers retain residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to clean since residue is difficult to remove. For work on tanks, refer to OSHA regulations, ANSI Z49.1, and other governmental and industrial references pertaining to cleaning, repairing, welding or other contemplated operations. To prevent fire or explosion risk from static accumulation and discharge, effectively ground product transfer system in accordance with NFPA standard for petroleum products. Doc. No. 8165 5 of 9 MSDS Number: TP004997 Revision Date: May 2007 8. EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION: Normally not needed in well-ventilated areas. If applicable standards are exceeded or are likely to be exceeded, use a NIOSH/MSHA approved, contaminantspecific, air-purifying respirator. If such concentrations are sufficiently high that this respirator is inadequate, or high enough to cause oxygen deficiency, use a positive pressure self-contained breathing apparatus (SCBA). Follow all applicable respirator use, fitting, and training standards and regulations. EYE PROTECTION: Chemical safety goggles or face shield needed if spraying or eye contact is possible. SKIN: Chemical resistant gloves, apron, or other protective clothing needed to prevent skin contact. VENTILATION: Use only with adequate ventilation to maintain exposures below appropriate exposure limits. Local exhaust ventilation and/or enclosure of the process may be required. All equipment must be explosion proof. EXPOSURE GUIDELINES: See section 2 for component materials. Additional potentially relevant exposure limits are listed below: Components Xylene CAS No. 1330-20-7 Exposure Limits OSHA ACGIH TWA STEL TWA STEL 100 150 100 150 Unit ppm Other Information: Avoid prolonged or repeated skin contact. Remove contaminated clothing; launder or dry clean before reuse. Workers should wash their hands before breaks, meals, smoking and using toilet facilities. Product is readily removed from skin by waterless hand cleaners followed by washing with soap and water. Do not use solvents or thinners to remove material from skin. A fresh water supply, including an eye wash for emergency first aid, and washing facilities should be readily available. An oil-dissolving skin cleaner should be available. 9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE AND ODOR: Black liquid solvent odor. BOILING POINT: 315 ºF Ph: Not applicable MELTING POINT: Not applicable Doc. No. 8165 6 of 9 MSDS Number: TP004997 Revision Date: May 2007 SPECIFIC GRAVITY: 0.98 – 1.0 VAPOR PRESSURE: 2mm @ 70 ºF VAPOR DENSITY (AIR = 1): 5 % VOLATILE, BY VOLUME: <30 SOLUBILITY IN WATER: Negligible EVAPORATION RATE (BUTYL ACETAT = 1): <0.1 OTHER PHYSICAL AND CHEMICAL DATA: None 10. STABILITY AND REACTIVITY STABILITY: Stable CONDITIONS TO AVOID: Keep from heat, sparks, open flame, and other sources of ignition. Avoid contact with strong oxidizing agents. Prevent vapor accumulation. HAZARDOUS POLYMERIZATION: Will not occur. INCOMPATIBILTY (MATERIALS TO AVOID): Strong acids or bases, oxidizing agents and selected amines. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, ozone, hydrogen sulfide, oxides of sulfur and various hydrocarbons. 11. TOXICOLOGICAL INFORMATION: According to NIOSH, research has identified low levels of Polycyclic Aromatic Hydrocarbons (PAHs) in laboratory generated asphalt fumes. Benzo(a)pyrenes, known carcinogens, have been identified in field-generated asphalt fumes. Asphalt roofing fume condensates and fractions have been shown to contain chemicals known as PAC’s, which have a chemical structure similar to known carcinogens and genotoxins. Laboratorygenerated asphalt fumes have been shown to be genotoxic. Laboratory-derived roofing asphalt fume condensates have been shown to be mutagenic, clastogenic, and inhibit intracellular communication in mammalian cells. Laboratory studies have shown chemical extracts of asphalt fumes to be carcinogenic to the skin of experimental animals following lifetime exposures, and to show positive mutagenicity in screening bioassays. The relevance of these studies to human exposures is not known at this time. Inhalation studies have not been conclusive regarding asphalt’s carcinogenic potential; however, adverse lung effects were seen in several species of laboratory animals. Skin application of undiluted air-refined (oxidized) asphalt to experimental animals has not resulted in skin tumors. The results were weakly positive when the samples were applied in a solvent vehicle. Doc. No. 8165 7 of 9 MSDS Number: TP004997 Revision Date: May 2007 12. ECOLOGICAL INFORMATION: No specific data on this product. Product may cause mechanical damage to aquatic organisms. The mineral spirit component is expected to volatilize in the environment and to be moderately toxic to both freshwater and marine organisms. The bioaccumulation potential is unknown. 13. DISPOSAL CONSIDERATIONS: Dispose in accordance with Federal, State and Local regulations. Prevent materials from entering drains, sewers, or waterways. Do not dump on the ground. 14. TRANSPORT INFORMATION: DOT PROPER SHIPPING NAME: TARS, LIQUID DOT HAZARD CLASSIFICATION: Combustible Liquid. Non-regulated in non-bulk quantities (less than 119 gallons each). This exception to 49 CFR is cited at 173.150(f). DOT LABELING REQUIREMENTS: Combustible Liquid UN/NA NUMBER: NA1999 PLACARDS: Combustible Liquid IMDG CODE: Hazardous for vessel transport under the IMDG Code IMDG SHIPPING NAME: Tars, Liquid IMDG HAZARD CLASS: 3 UN/ID NUMBER: UN 1999 PACKING GROUP NUMBER: PG III 15. REGULATORY INFORMATION TOXIC SUBSTANCES CONTROL ACT (TSCA): The components in this product are listed on the TSCA Inventory. COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT (CERCLA): The material contains xylene. The reportable quantities for xylene are 1000 lb. Any release of this product that results in a release of xylene equal to or exceeding the reportable quantity must be reported to the National Response Center (800-424-8802) and appropriate state and local regulatory agencies as described in 40 CFR 117,302. Doc. No. 8165 8 of 9 MSDS Number: TP004997 Revision Date: May 2007 SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA), TITLE III: SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES: None SECTION 311/312 HAZARD CATEGORIES: Immediate Health Delayed Health Fire Hazard SECTION 313 REPORTABLE INGREDIENTS: Chemical Name Xylene CAS Number 1330-20-7 Concentration (% by Wt.) <1 CALIFORNIA PROPOSITION 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. 16. OTHER INFORMATION • • • Preparation Date: March 1997 Revised: o August 2004 (DOT Transport information and Prop 65 language) o August 2005 (Changes in emergency contact information) o June 2006 (Company name change) o May 2007 (Formatting Issues) Replaces: None Disclaimer of Liability The information and recommendations contained herein are to the best of TAMKO Building Products, Inc.’s knowledge and belief, accurate and reliable as of the date issued. TAMKO Building Products, Inc. does not warrant or guarantee their accuracy or reliability, and TAMKO Building Products, Inc. shall not be liable for any loss or damage arising out of the use thereof. The information and recommendations are offered for the user’s consideration and examination, and it is the user’s responsibility to satisfy itself that they are suitable and complete for its particular use. Doc. No. 8165 9 of 9 Material Safety Data Sheet - MSDS ExpertSeal Asphalt Repair ExpertSeal Pot Hole Patch Section 1. Chemical Product and Company Identification Trade name Material Uses Supplier : ExpertSeal Asphalt Repair ExpertSeal Pot Hole Patch : Asphalt repair and maintenance. Validation Date : ExpertSeal 1483, Sainte-Marguerite Mercier, QC J6R 2L1 Tel: 1-800-573-7325 Tel: 1-450-698-0264 Fax: 1-450-698-0265 Manufacturer : 2/25/2004. In Case of Emergency : 1-800-573-7325 : ExpertSeal 1483, Sainte-Marguerite Mercier, QC J6R 2L1 Tel: 1-800-573-7325 Tel: 1-450-698-0264 Fax: 1-450-698-0265 Copeland Coatings Co. Inc. P.O. Box 595, 3600 Route 20 Nassau, NY, 12123 Tel: 1-800-303-4219 Section 2. Composition, Information on Ingredients CAS # Name % by Weight UN number Limestone 1317-65-3 70-100 Not regulated. Liquid Petroleum Asphalt 8052-42-4 3-5 Not regulated. Fuels, diesel 68334-30-5 1-3 UN1202 This product is a manufactured product under the Canadian WHMIS. Therefore it is EXEMPTED from the regulatory requirements under WHMIS. This MSDS has been written for workers using this product. Section 3. Hazards Identification Physical State and Appearance Emergency Overview : Solid. (Granular solid.) Potential Chronic Health Effects : CARCINOGENIC EFFECTS: Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. : Repeated or prolonged exposure is not known to aggravate any medical condition. This product contains substances that may be hazardous to human health but the risk of exposure to such substances is found negligeable. This is why it is not classified under WHMIS. : Not available. : WARNING! MAY CAUSE RESPIRATORY TRACT IRRITATION. Keep container closed. Use with adequate ventilation. Routes of Entry : Skin contact. Eye contact. Inhalation. Ingestion. Potential Acute Health Effects Eyes : Slightly hazardous in case of eye contact (irritant). Skin : Slightly hazardous in case of skin contact (irritant). Non-sensitizer for skin. Inhalation : Hazardous in case of inhalation (lung irritant). Ingestion : Slightly hazardous in case of ingestion. Medical Conditions Aggravated by Overexposure: Over-exposure signs/symptoms See Toxicological Information (section 11) for a partial list of welding fumes ingredients. Continued on Next Page ExpertSeal Asphalt Repair ExpertSeal Pot Hole Patch Page: 2/5 Section 4. First Aid Measures Eye Contact Skin Contact Inhalation Ingestion Notes to Physician : Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation occurs. : Wash with soap and water. Get medical attention if irritation develops. Do not attempt to remove cold asphalt. Do not use solvents to clean skin covered with asphalt. Vegetable oil may be used to remove asphalt residue on skin surface. : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. : Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention if symptoms appear. : No specific antidot, medical staff contact Poisons Information Centre. Section 5. Fire Fighting Measures Flammability of the Product Auto-ignition Temperature Flash Points Flammable Limits Products of Combustion Fire Hazards in Presence of Various Substances Explosion Hazards in Presence of Various Substances Fire Fighting Media and Instructions Protective Clothing (Fire) : : : : : : Non-flammable. Not applicable. Not applicable. Not applicable. Not applicable. Not applicable. : Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. : Use extinguishing media suitable for surrounding materials. : Not applicable. Section 6. Accidental Release Measures Small Spill and Leak Large Spill and Leak : Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. : Use a shovel to put the material into a convenient waste disposal container. Section 7. Handling and Storage : Keep container closed. Use with adequate ventilation. : Keep container tightly closed. Keep container in a cool, well-ventilated area. Handling Storage Section 8. Exposure Controls, Personal Protection Engineering Controls Personal Protection Eyes Body Respiratory Hands Feet Protective Clothing (Pictograms) : Keep in a cool, well-ventilated place. : : : : : Safety glasses. Chemical resistant protective suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots. : Continued on Next Page Page: 3/5 ExpertSeal Asphalt Repair ExpertSeal Pot Hole Patch Personal Protection in Case of a Large Spill : Splash goggles. Full suit. Boots. Gloves. Vapor respirator. A self-contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist before handling this product. Exposure Limits Liquid Petroleum Asphalt ACGIH TLV (Canada, 2001). : TWA: 0.5 mg/m3 8 hour(s). Form: Fume Consult local authorities for acceptable exposure limits. Section 9. Physical and Chemical Properties Physical State and Appearance Color Odor Molecular Weight Molecular Formula pH (1% Soln/Water) Boiling/Condensation Point Melting/Freezing Point Specific Gravity Vapor Pressure Vapor Density Volatility Odor Threshold Evaporation Rate VOC Viscosity LogKow Solubility : Solid. (Granular solid.) : : : : : : : : : : : : : : : : : Black. Petroleum. Not applicable. Not applicable. Not applicable. 295 to 705°C (563 to 1301°F) Not available. 2.6 to 2.8 (Water = 1) Not available. Not available. 1% (v/v). Not available. Not available. 1 (%) Not available. Not available. Insoluble in cold water, hot water. Section 10. Stability and Reactivity Stability and Reactivity Conditions of Instability Incompatibility with Various Substances Hazardous Decomposition Products Hazardous Polymerization : The product is stable. : None known. : Reactive with oxidizing agents, acids. : Not available. : Will not occur. Section 11. Toxicological Information Fuels, diesel LD50 7500 mg/kg Oral Rat : CARCINOGENIC EFFECTS: Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. : Hazardous in case of inhalation (lung irritant). Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion. Non-sensitizer for skin. Special Remarks on Toxicity : Not available. to Animals Special Remarks on Chronic : This product contains substances that may be hazardous to human health, but the risk of exposure to Effects on Humans such substances is found to be negligeable, in the normal conditions of use. Chronic Effects on Humans Other Toxic Effects on Humans Continued on Next Page Page: 4/5 ExpertSeal Asphalt Repair ExpertSeal Pot Hole Patch Section 12. Ecological Information BOD and COD Biodegradable/OECD Mobility Products of Degradation Toxicity of the Products of Biodegradation Special Remarks on the Products of Biodegradation : : : : : Not available. Not available. Not available. These products are carbon oxides (CO, CO2). Some metallic oxides. Not available. : Not available. Section 13. Disposal Considerations Waste Information : Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult your local or regional authorities. Section 14. Transport Information Regulatory Information UN number Proper shipping name Class Packing Group Canada (TDG) Not regulated. Not controlled under TDG. - - NAERG Label Additional information - : Not applicable. Section 15. Regulatory Information WHMIS (Canada) : Not controlled under WHMIS (Canada). CEPA DSL: Liquid Petroleum Asphalt; Fuels, diesel CEPA NDSL: Limestone This product is a manufactured product under the Canadian WHMIS. Therefore it is EXEMPTED from the regulatory requirements under WHMIS. This MSDS has been written for workers using this product. Section 16. Other Information Hazardous Material Information System (U.S.A.) Health Fire Hazard Reactivity Personal Protection References Responsible Name Date of Previous Issue Version Notice to Reader 1 1 0 C National Fire Protection Association (U.S.A.) 1 Health 1 Fire Hazard 0 Reactivity Specific Hazard : -Canada Gazette Part II, Vol. 122, No. 2 Registration SOR/88-64 31 December, 1987 Hazardous Products Act "Ingredient Disclosure List". - Canadian Transport of Dangerous Goods, Regulations and Schedules, Clear Language version 2002. -Manufacturer's Material Safety Data Sheet. : Kemika XXI inc. +1-450-435-7475 : No Previous Validation. : 1 Continued on Next Page ExpertSeal Asphalt Repair ExpertSeal Pot Hole Patch Page: 5/5 To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Home > Products > MSDS Sheets > MSDS 3503 -- [Back] WELCOME -Please Login Last Updated: 10/25/2003 Local Time, Green Bay, WI 9:22:01 AM CST 3503: GUTTER & LAP SEALANT MSDS Last updated: 03/29/1999 MSDS SHEET FOR DAP GUTTER & LAP SEALANT #3503 *** SECTION 1 PRODUCT IDENTIFICATION *** MANUFACTURER'S NAME: MANUFACTURER'S ADDRESS: EMERGENCY TELEPHONE: DISTRIBUTOR'S NAME: DISTRIBUTOR'S ADDRESS: DAP INC. P.O. BOX 277 DAYTON, OH 45401-0277 1-800-535-5053 (TRANSPORTATION) 1-800-327-3874 (MEDICAL) INFORMATION TELEPHONE: IMPERIAL SUPPLIES LLC 789 PACKER DRIVE GREEN BAY, WI 54304 1-800-558-2808 PRODUCT NAME: PRODUCT NO.: IMPERIAL NO.: DAP GUTTER & LAP SEALANT WH 18182 3503 *** SECTION 2 HAZARDOUS INGREDIENTS *** ITEM CHEMICAL NAME CAS # 01 MINERAL SPIRITS ITEM EXPOSURE LIMITS ACGIH OSHA TLV-TWA TLV-STEL PEL-TWA PEL-CEILING 01 100PPM N.E. 8052-41-3 % 100 PPM 10-15 COMPANY TLV-TWA N.E. N.E. SKIN NO *** SECTION 3 HAZARDS IDENTIFICATION *** EMERGENCY OVERVIEW: DANGER! COMBUSTIBLE LIQUID AND VAPOR. HARMFUL OR FATAL IF SWALLOWED. HARMFUL IF INHALED. VAPOR HARMFUL. POTENTIAL HEALTH EFFECTS: EFFECTS OF OVEREXPOSURE: EYE CONTACT: MAY CAUSE EYE IRRITATION. EFFECTS OF OVEREXPOSURE: SKIN CONTACT: MAY CAUSE SKIN IRRITATION. MAY IRRITATE SKIN. PROLONGED OR REPEATED CONTACT CAN RESULT IN DEFATTING AND DRYING OF THE SKIN WHICH MAY RESULT IN SKIN IRRITATION AND DERMATITIS (RASH). EFFECTS OF OVEREXPOSURE: INHALATION: VAPOR HARMFUL IF INHALED. VAPOR MAY IRRITATE NOSE AND UPPER RESPIRATORY TRACT. VAPOR INHALATION MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE, OR NAUSEA. EFFECTS OF OVEREXPOSURE: INGESTION: THIS MATERIAL MAY BE HARMFUL OR FATAL IF SWALLOWED. IF INGESTED, THIS PRODUCT MAY CAUSE VOMITING, DIARRHEA, AND DEPRESSED RESPIRATION. EFFECTS OF OVEREXPOSURE: CHRONIC HAZARDS: REPORTS HAVE ASSOCIATED PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE WITH PROLONGED AND REPEATED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS. MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY CONTACT: PRIMARY ROUTES OF ENTRY: SKIN CONTACT AND INHALATION NONE KNOWN. *** SECTION 4 FIRST AID MEASURES *** EYE CONTACT: FLUSH WITH LARGE QUANTITIES OF WATER UNTIL IRRITATION SUBSIDES. SKIN CONTACT: WASH WITH SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION: DO NOT INDUCE VOMITING. COMMENTS: CALL MEDICAL IN SECTION 1 IF IRRITATION OR COMPLICATIONS ARISE FROM ANY OF THE ABOVE ROUTES OF ENTRY. *** SECTION 5 FIRE FIGHTING MEASURES *** FLASH POINT: 120 F SETAFLASH CLOSED CUP LEL: N.A. UEL: N.A. AUTOIGNITION TEMPERATURE: N.A. EXTINGUISHING MEDIA: CO2, DRY CHEMICAL, FOAM, UNUSUAL FIRE AND EXPLOSION HAZARDS: CONTAINERS MAY EXPLODE IF EXPOSED TO EXTREME HEAT. ELIMINATE SOURCES OF IGNITION: HEAT, ELECTRICAL EQUIPMENT, SPARKS, AND FLAMES. DO NOT PUT IN CONTACT WITH OXIDIZING OR CAUSTIC MATERIALS. SPECIAL FIREFIGHTING PROCEDURES: AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND (MSHA/NIOSH APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR TO PROTECT FROM COMBUSTION PRODUCTS. USE WATER SPRAY TO COOL EXPOSED SURFACES. *** SECTION 6 ACCIDENTAL RELEASE MEASURES *** SPILL OR LEAK PROCEDURES: DIKE SPILL AREA. USE ABSORBENT MATERIAL OR SCRAPE UP DRIED MATERIAL AND PLACE INTO CONTAINERS. *** SECTION 7 HANDLING & STORAGE *** HANDLING INFORMATION: KEEP OUT OF REACH OF CHILDREN. AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. AVOID CONTACT WITH EYES. AVOID BREATHING VAPORS. USE ONLY IN A WELL VENTILATED AREA. STORAGE INFORMATION: STORE AWAY FROM CASUTICS AND OXIDIZERS. KEEP AWAY FROM HEAT, SPARK, AND FLAME. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. KEEP CONTAINERS FROM EXCESSIVE HEAT AND FREEZING. DO NOT STORE AT TEMPERATURES ABOVE 120 DEGREES F. OTHER PRECAUTIONS: INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING VAPORS MAY BE HARMFUL OR FATAL. DO NOT TAKE INTERNALLY. *** SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION *** ENGINEERING CONTROLS: PROVIDE SUFFICIENT MECHANICAL VENTILATION (LOCAL OR GENERAL EXHAUST) TO MAINTAIN EXPOSURE BELOW PEL AND TLV. VAPORS ARE HEAVIER THAN AIR AND WILL COLLECT IN LOW AREAS. CHECK ALL LOW AREAS (BASEMENTS, SUMPS, ETC.) FOR VAPOR BEFORE ENTERING. RESPIRATORY PROTECTION: A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. IF 8 HOUR EXPOSURE LIMIT OR VALUE IS EXCEEDED FOR ANY COMPONENT, USE AN APPROVEDNIOSH RESPIRATOR. CONSULT YOU SAFETY EQUIPMENT SUPPLIER AND THE OSHA REGULATION, 29 CFR 1910.134 FOR RESPIRATOR REQUIREMENTS. EYE PROTECTION: GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS RECOMMENDED. SKIN PROTECTION: SOLVENT IMPERVIOUS GLOVES. OTHER PROTECTIVE EQUIPMENT: PROVIDE EYEWASH AND SOLVENT IMPERVIOUS APRON IF BODY CONTACT MAY OCCUR. HYGIENIC PRACTICES: REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. *** SECTION 9 PHYSICAL & CHEMICAL PROPERTIES *** BOILING RANGE: 310-320 F ODOR: PETROLEUM ODOR APPEARANCE: COLORED PASTE SOLUBILITY IN H20: NEGLIGIBLE SPECIFIC GRAVITY: 1.4511 VAPOR PRESSURE: 2.0 MM HG @ 68 F PHYSICAL STATE: PASTE VAPOR DENSITY: IS HEAVIER THAN AIR EVAPORATION RATE: IS SLOWER THAN BUTYL ACETATE *** SECTION 10 STABILITY & REACTIVITY *** CONDITIONS TO AVOID: EXCESSIVE HEAT AND FREEZING. INCOMPATIBILITY: STRONG OXIDIZERS AND CAUSTICS. HAZARDOUS DECOMPOSITION PRODUCTS: NORMAL DECOMPOSITION PRODUCTS, I.E. COx, NOx HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS. STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS. *** SECTION 11 TOXICOLOGICAL PROPERTIES *** NO PRODUCT OR COMPONENT TOXICOLOGICAL INFORMATION IS AVAILABLE. *** SECTION 12 ECOLOGICAL INFORMATION *** NO INFORMATION *** SECTION 13 DISPOSAL CONSIDERATIONS *** WASTE MANAGEMENT/DISPOSAL: DISPOSE OF ACCORDING TO FEDERAL, STATE, AND LOCAL STANDARDS. THIS PRODUCT DOES NOT MEET THE DEFINITION OF A HAZARDOUS WASTE ACCORDING TO U.S. EPA HAZARDOUS WASTE MANAGEMENT REGULATIONS, 40 CFR SECTION 261. STATE AND LOCAL REGULATIONS/RESTRICTIONS ARE COMPLESX AND MAY DIFFER FROM FEDERAL REGULATIONS. RESPONSIBILITY FOR PROPER WASTE DISPOSAL IS WITH THE OWNER OF THE WASTE. EPA WASTE CODE: IF DISCARDED (40 CFR 261): D001-IGNITABLE *** SECTION 14 TRANSPORTATION INFORMATION *** DOT PROPER SHIPPING NAME: DOT HAZARD CLASS: NONE DOT UN/NA NUMBER: NONE PACKING GROUP: NONE NOT REGULATED BY D.0.T. *** SECTION 15 REGULATORY INFORMATION *** U.S. FEDERAL REGULATIONS: AS FOLLOWS - OSHA: HAZARDOUS BY DEFINITION OF HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) SARA SECTION 313: THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372: NONE. TOXIC SUBSTANCES CONTROL ACT: THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES: NONE. NEW JERSEY RIGHT-TO-KNOW: THE FOLLOWING MATERIALS ARE NON-HAZARDOUS, BUT ARE AMONG THE TOP FIVE COMPONENTS IN THIS PRODUCT: BUTYL RUBBER, SOYBEAN OIL, POLYMER, CALCIUM CARBONATE PENNSYLVANIA RIGHT-TO-KNOW: THE FOLLOWING NON-HAZARDOUS INGREDIENTS ARE PRESENT IN THE PRODUCT AT GREATER THAN 3%: BUTYL RUBBER, CALCIUM CARBONATE CALIFORNIA PROPOSITION 65: WARNING: THE CHEMCICAL NOTED BELOW AND CONTAINED IN THIS PRODUCT, ARE KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM: NONE. INTERNATIONAL REGULATIONS: AS FOLLOWS - CANADIAN WHMIS: THIS MSDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT REGULATIONS EXCEPT FOR USE OF THE 16 HEADINGS. CANADIAN WHMIS CLASS: B3 COMBUSTIBLE LIQUID. SOLD ON RETAIL MARKET. *** SECTION 16 OTHER INFORMATION *** HMIS RATINGS - HEALTH: 1 FLAMMABILITY: 2 REACTIVITY: VOC LESS WATER, LESS EXEMPT SOLVENTS: 175-185 GMS/1(12-13%) VOC MATERIAL: 175-185 GM/1 0 The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance. For more product information by email, click here . Imperial Supplies LLC does not provide services and products outside the United States Home | Site Search | Company Info | Catalog | New Products | Programs Your Account | Career Opportunities | Info Request | Downloads | Privacy Policy | Links | Site Map Copyright © Imperial, 2001 Questions or comments on these pages? Contact us. Spartan Chemical Company, Inc. Material Safety Data Sheet SECTION I: PRODUCT INFORMATION Product Name or Number (as it appears on label): Product Division: Janitorial CONCRETE SEAL Product Number: 2977 Spartan Chemical Company, Inc. 1110 Spartan Drive Product/Technical 1-(800)-537-8990 Information: Medical Emergency: 1-(888)-314-6171 (24 hours) Chemical Leak/Spil CHEMTREC 1-(800) 424-9300 (24 Emergency: hours) Maumee OH 43537 Shipping Description: Buffing, polishing compounds, liquid, n.o.s. NFPA Ratings: HMIS Ratings: Health: *2 - Moderate; Chronic Hazard Health: 2 - Moderate Fire: 2 - Moderate Fire: 2 - Moderate Reactivity: 0 - Minimal Reactivity: 0 - Minimal Pers. Prot. Equip.: See Section VIII SECTION II: HAZARDOUS INGREDIENTS (Listed when present at 1% or greater, carcinogens at 0.1% or greater) All component chemicals are listed or exempted from listing on the "TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency. Table Z- 1 - A Chemical Name(s) CAS % W Registry No. *1,2,4Trimethylbenzene 25-30 Acrylic polymer 15-20 95-63-6 STEL mg/m NTP, IARC or OSHA Carcinogen TWA mg/m3 3 CELING mg/m3 125 Not Established Not Established No Not Established Not Established No Proprietary Not Established *Xylene 1-5 1330-20-7 435 655 Not Established No Cumene 1-5 98-82-8 245 Not Established Not Established No 100 (ExxonMobile) Not Established Not Established No Aromatic hydrocarbon 45-55 64742-95-6 Comment: *This substance is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (SARA) and of 40 CFR 372. SECTION III: PHYSICAL DATA Boiling Point: 311 °F Vapor Pressure: 2.7 mm Hg @ 20°F Vapor Density (AIR = 1): >1 pH: N/A Evaporation Rate 0.19 (but.ace.=1): Solubility in Water: Nil Specific Gravity 0.90 (H2O=1): Percent Solid by 15-20 Weight: Physical State: Liquid Appearance & Odor: Water clear, slightly viscous, aromatic SECTION IV: FIRE & EXPLOSIVE HAZARD DATA Flash Point: 107°F Flammable Limits: LEL - 1.0 UEL - 6.5 Method Used: ASTM-D56 Flame Extension: N/A Extinguishing Media: Small Fires: extinguish with dry chemical, CO2, or foam. Large Fires: The use of dry chemical or foam is recommended. Water may be an ineffective extinguishing agent. Special Fire Fighting The use of a SCBA is recommended for fire fighters. Water may be useful in Procedures: minimizing vapors and cooling containers exposed to heat and flame. Avoid spreading burning liquid with water used for cooling purposes. Unusual Fire & Explosive This material is combustible and may be ignited by heat or flame. This Hazards: material will burn, but not ignite readily. SECTION V: HEALTH HAZARD DATA Threshold Limit Value: Not established Primary Routes of Inhalation, Skin Contact, Entry: Eyes Effects of Overexposure- Causes Eye irritation: Direct contact with the liquid or exposure to its Conditions to Avoid: vapors or mists may cause burning, tearing, redness and swelling. May Cause Skin Irritation: Prolonged or repeated exposure to this material may cause redness and burning, drying and cracking of the skin. Persons with pre-existing skin disorders may be more susceptible to the effects of this material. Inhalation: Breathing high concentrations of vapors or mists may cause irritation of the nose and throat, signs of nervous system depression (e.g., drowsiness, dizziness, loss of coordination, and fatigue). Prolonged or repeated exposure to vapors or mists may cause liver and kidney damage. Persons with impaired lung function or asthma-like conditions may experience additional breathing difficulties due to the irritant properties of this material. Harmful if Swallowed: Ingestion may cause irritation of the digestive tract and signs of nervous system depression (e.g. drowsiness, dizziness, loss of coordination, and fatigue). Aspiration hazard - this material can enter lungs during swallowing or vomiting and cause lung inflammation and damage. Conditions Aggravated by Use of this product may aggravate preexisting skin; eye and respiratory Use: disorders including asthma and dermatitis. Emergency & First Aid Procedures: Eyes: Move victim away from exposure to vapors and into fresh air. Remove contact lenses. If irritation or redness develops; seek medical attention. For direct contact; flush the affected eye(s) with clean water for at least 15 minutes. Seek medical attention. Skin: Removed contaminated clothing. Cleanse affected area(s) thoroughly by washing with mild soap and water. If irritation or redness develops and persists; seek medical attention. Ingestion: Call physician immediately. Do not induce vomiting. Keep person at rest. Small amounts of this product aspirated into the respiratory system during ingestion or vomiting may cause mild to severe pulmonary injury. Inhalation: If symptoms of exposure develop; move victim away from source of exposure and into fresh air. If symptoms persist; seek immediate medical attention. If victim is not breathing; artificial respiration should be administered. If breathing difficulties develop; oxygen should be administered by qualified personnel. SECTION VI: REACTIVITY DATA Stability: Stable Incompatible Materials: This product is incompatible with strong acids or bases; oxidizing agents and selected amines. Hazardous Decomposition CO, CO2 Products: Hazardous Will Not Occur Polymerization: SECTION VII: SPILL OR LEAK PROCEDURES Steps to be Taken in Case Pick up with absorbent material and dispose of in accordance with state and Material is Released or local regulations. Spilled: Waste Disposal Method: Use qualified disposal service. SECTION VIII: SPECIAL PROTECTION INFORMATION Respiratory Protection: The use of respiratory protection is advised when concentrations exceed the established exposure limits (see Section II), additional ventilation or exhaust systems may be required. Where explosive mixtures may be present, systems safe for such locations should be used. Ventilation: Good general ventilation should be sufficient for most conditions. Local exhaust ventilation may be necessary for some operations. Protective Gloves(Specify Wear neoprene, nitrile or other solvent resistant gloves. Type): Eye Protection(Specify Splash Goggles Type): Other Protective Equipment: Use of other protective equipment such as an impermeable apron should be considered in order to prevent or minimize contact with this product. See 29 CFR 1910.132-138 for further guidance. SECTION IX: SPECIAL PRECAUTIONS Precautions; Handling & Keep containers tightly closed. Keep containers cool; dry and away from Storing: sources of ignition. Use and store this product with adequate ventilation. Avoid inhalation of vapors and personal contact with the product. Use good personal hygiene practice. "Empty" containers retain residue (liquid and/or vapor) and can be dangerous. Do not pressurize; cut; weld; braze; solder; drill; grind or expose such containers to heat; flame; sparks or other sources of ignition; they may explode and cause injury or death. "Empty" drums should be completely drained; properly bunged and promptly shipped to the supplier or a drum reconditioner. All other containers should be disposed on in an environmentally safe manner and in accordance with governmental regulations. Before working on or in tanks which contain or have contained this product; refer to Occupational Safety and Health Administration regulations; ANSI Z49.1; and other governmental and industrial references pertaining to cleaning; repairing; welding or other contemplated operations. Other Precautions: During use; eliminate any source of ignition. Remove all foodstuffs and packaging materials from area to be coated. © SCC 12/14/2005 Name: Ronald T. Cook CONCRETE SEAL Effective Date: Changes: 12/14/2005 Title: Manager, Regulatory Affairs Supercedes: 01/05/2000 Ref: 29 CFR 1910.1200 Update Sections I, II, V, VIII (OSHA) This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State and Local laws and regulations. 'ttL} MATERIALSAFETYDATASHEET PortlandCement SECTION1 . ]DENTIFICATION Pt9.d!.ct_Nane: Types l, l/lllA, l/ll, lllLA, Red Bag, White Portland Manufacturer'sName and Address: ALAMO CEMENTCOMPANY P.O. Box 34807 San Antonio, Texas 78265 TelephoneNumbers: In Texas: 1(800)292-5510 - Other: 1(210)208-1880 Chemical Name and Synonyms: Portland Cement.Portland Cement is also know as hydraulic cement. PreparationDate: July 9, 2007. Replacesany prior versions. CneEic3l-Fjtrily: Calcium compounds. Calcium silicate compounds and other calcium compounds containing iron and aluminum make up the majority of this product, Maior Compounds: 3CaO-Si02 2CaO-SiO2 TricalciumSilicate DicalciumSilicate 3CaO-AlzOr TricalciumAluminate 4CaO-A12O3-Fe2O3 TetracalciumAluminoferrite CaSOr-2HzO CalciumSulfateDihydrateor Gypsum CaCO3 CalciumCarbonateor Limestone EAIOUA: This productconsistsof finely ground Portlandcementclinkermixedwith a small amountof calciumsulfatedihydrate(Gypsum). SECTION 2 - COMPONENTS HazardousInoredients:Portlandcementclinker(CAS#65997-5-1)apploximately95%by weight ACGIHTLV-TWA(1995-1996)=10m9 total dusum' OSHAPEL(8-hourTWA)=50millionparticles/ft3 - approximately Gypsum(CAS#7778-18-9) 5% !y weight ACGIHTLV-TWA(1995-1996)=10m9 total dusum' OSHAPEL(8-hourTWA)=1Omg totll dusUm3 OSHAPEL(8-hourTWA)=Smg respirabledusUm3 Quartz(CAS#14808-60-7)-less than 0.1%by weightor volumeACGIHTLV-TWA(1995-1996)=0.10m9 respirablequartzdusUm" OSHAPEL(8-hourTWA)=(10m9 of respirabledusum')/(Percent silica+ 2) NIOSHREL(8-hourTWA)=O.05mg respirablequartzdusUm" Trace Constituents: Portlandcementis made from materialsmined from the earth and is processed using energy provided by fossil fuels. Trace amounts of naturally occurring, potentiallyharmful chemicalsmight be detectedduringchemicalanalysis.For example,Portlandcementmay containup to 2.0% insoluableresidue,some of which may be free crystallinesilica. Other trace constituentsmay include calciumoxide (also known as free lime or quick lime),free magnesiumoxide, potassiumand sodiumsulfatecompounds,chromiumcompounds,and nickelcompounds, SECTION3 - HAZARDSIDENTIFICATION EmergencyOverview:PortlandCementis a light gray powderthat poseslittleimmediatehazard.A single short term exposureto the dry powder is not likely to cause serious harm. However,exposureof sufficientdurationto wet Portlandcementcan causeserious,potentiallyirreversibletissue (skinor eye) destructionin the form ot chemical(caustic)burns,includingthird degreeburns.The sametype of tissue destructioncan occur if wet or moistareasofthe bodyareexposedfor sufficientdurationto dry Portland Cement. Pgle$bl-HeallLEfferlt: RelevantRoutesof Exposure:EyeContact,skin contact,inhalation,and ingestion. @:Exposuretoairbornedustmaycauseimmediateorde|ayedirritation or inflammation. Eye contact by largeramountsof dry powderor splashesof wet Portlandcementmay cause etfects rangingfrom moderateeye irritationto chemicalburnsand blindness.Suchexposuresrequireimmediate first aid (seesection4) and medicalattentionto preventsignificantdamageto the eye. @:Discomfortorpaincannotbere|iedupontoa|ertapersontoa hazardousskin exposure.Consequently,the only effectivemeans of avoiding skin injury or illness involvesminimizingskin contact,particularlycontactwith wet cement.Exposedpersonsmay not feel discomfortuntil ours afterthe exposurehas endedand significantinjuryhas occurred. Exposureto dry Portlandcementmay causedrying of the skin with consequentmild irritationor more significanteffectsattributableto aggravationor other conditions,Dry Portlandcementcontactingwet skin or exposureto moist or wet Portlandcement may cause more severe skin effects including thickening,cracking,fissuringof the skin. Prolongedexposurecan causesevereskin bdamagein the form of (caustic)chemicalburns. Some individualsmay exhibitan allergicresponseupon exposureto Portlandcement,possiblydue to trace amountsot chromium.The responsemay appearin a varietyof forms rangingfrom a mild rashto severeskin ulcers.Personsalreadysensitizedmay react to their first contactwith the product.Other personsmayfirst experience this effectafteryearsof contactwith Portlandcementproducts. Portland cement may contain trace amounts of free crystalline silica. EtfeglllllliliDCja0-hhalAtiQ!: respirable free crystallinesilica may aggravateother lung conditions.lt also may Prolongedexposureto cause delayed injury including silicosis, a disabling and potentiallyfatal lung disease. (Also see potential"below). "Carcinogenic Exposureto Portlandcementmay causeirritationto the moist mucousmembranesof the nose,throat, and upperrespiratorysystem.lt may also leaveunpleasantdepositsin the nose. Eftectr.IeilfilCl[I9m-inCa$iC!: Although small quantitiesof dust are not known to be harmful,ill effects are possibleif largerquantitiesareconsumed.Portlandcementshouldnot be eaten. C3lgingCanic.-Aeleltial:Portland cement is not listed as a carcinogen by NTP, OSHA,or IARC. lt may however,containtraceamountsof substanceslistedas carcinogensby theseorganizations. Crystallinesilica,a potentialtrace levelcontaminantin Portlandcement,is now classifiedby IARCas a respirablesilica as "reasonablyanticipated known humancarcinogen(Group1). NTPhas characterized to be a carcinogen". Medicalconditionswhich mav be aooravatedbv inhalationor dermal exposure: Pre-existingupper respiratoryand lung diseases. salts. chromium(chromium*6) Unusual(hyper)sensitivityto hexavalent SECTION4-FIRSTAID EygS: lmmediatelyflush eyes thoroughlywith water. Continueflushing eye for at least 15 minutes, includingunderlids,to removeall particles.Callphysicianimmediately. Sf,itr: Washskin with cool water and pH-neutralsoap or a mild detergent.Seekmedicaltreatmentin all cases of prolongedexposureto wet cement,cementmixtures,liquidsfrom fresh cementproducts'or prolongedwet skin exposureto dry cement. Removeto fresh air. Seek medicalhelp if coughing and other symptoms do hhalatiq!-el@l$t: ("lnhalation" gross amountsof Portlandcementrequireimmediatemedicalattention.) of not subside. bgeEtieo: Do not inducevomiting.lf conscious,havethe victimdrink plentyofwater and call a physician immediately. DATA SECTION5 - FIRE& EXPLOSION F l a s hp o i n t . . . . . . . . . . . . . . . . . . . n o n e Limit.,,..............none LowerExplosive Limit.................none UpperExplosive combustible Autoignitiontemperature.............,not not combustible media.,................... Extinguishing Specialfirefightingprocedures...............none (AlthoughPortlandcementposesno fire relatedhazards,a self containedbreathingapparatusis to limitexposureto combustionproductswhenfightingany fire.) recommended products..............none Hazardous combustion Unusualfireandexplosionhazards.............none SECTION6 _ ACCIDENTAL RELEASEMEASURES Collectdry materialusinga scoop.Avoid actionsthat causedust to becomeairborne.Avoid inhalationof dust and contactwith skin.Wearappropriatepersonalprotectiveequipmentas describedin Section8. Scrapeup wet materialand placein appropriatecontainer.Allow the materialto dry beforedisposal.Do not attemptto wash Portlandcementdown drains, Disposeof wastematerialaccordingto local,state,and federalregulations. SECTION7 - HANDLING AND STORAGE KeepPortlandcementdry until used.Normaltemperatures and pressuresdo not affectthe material Promptlyremovedusty clothingor clothingwhich is wet with cementfluidsand launderbeforereuse. Washthoroughlyafterexposureto dust or wet cementmixturesor fluids. PROTECTION SECTION8 - EXPOSURE CONTROLS/PERSONAL Ski[PIOleCliA!: Preventionis essentialto avoiding potentiallysevereskin injury. Avoid contactwith unhardenedPortlandcement.lf contactoccurs,promptlywashaffectedareawith soapand water.Where prolongedexposureto unhardenedPortlandcementproductsmightoccur,wear imperviousclothingand glovesto eliminateskin contact.Whererequired,wearsturdybootsthat are imperviousto waterto eliminatefoot and ankleexposure. Do not relyon barriercreams:Barriercreamsshouldnot be usedin placeof gloves. Periodically washareascontactedby dry Portlandcementor by wet cementor concretefluidswith a pH neutralsoap.Washagainat the end of the work. lf irritationoccurs,immediately wash the affectedarea and seektreatment.lf clothingbecomessaturatedwith wet concrete,it shouldbe removedand replaced with cleandry clothing. RespiratorvProtection:Avoidactionsthat causedust to becomeairborne.Uselocalor general ventilationto controlexposuresbelowapplicableexposurelimits. (under30 CFR11) or N|OSH-approved (under42 CFR84)respiratorsin UseNIOSHAJMSHA-approved poorlyventilatedareas,if an applicableexposureIimit is exceeded,or when dust causesdiscomfortor irritation.(Advisory:Respiratorsand filterspurchasedafterJuly 10,1998must be certifiedunder42 CFR 84). Venlilalig!: Uselocalexhaustor generaldilutionventilationto controlexposurewithinapplicablelimits. Eyeggteglig!: Wherepotentiallysubject to splashesor puffs of cement,wear safety glasseswith side and unpredictable environments, wearunventedor shieldsor goggles.In extremelydusty environments indirectlyventedgogglesto avoideye irritationor injury.Contactlensesshouldnot be worn when workingwith Po(land cementor fresh cementproducts. SECTION9 - PHYS]CALAND CHEMICALPROPERTIES Appearance....,...,.Gray Powder Odor.....................No distinctodor (powder) Physical state........Solid pH (inwater)..........12 to 13 Solubilityin water..Slightly soluble(0.1to 1.0%) Vaporpressure......Not applicable Vapordensity.........Not applicable Boilingpoint..........Not applicable MeltingPoint..........Not applicable Specificgravity(HrO=1.0) 3.15 Evaporationrate.....Not Applicable SECTION1O- STABILITYAND REACTIVITY $lahilily: Stable Conditionsto Avoid: Unintentional contactwith water. with acids,ammoniumsalts lncqEpatihility:Wet Portlandcementis alkaline.As such it is incompatible and phosphorous. Hazardousdecomnosition:Will not spontaneously occur.Addingwaterproduces(caustic)calcium hydroxide. Hazardousoolvmerization:Will not occur, SECTION11 - TOXILOGICAL INFORMATION For a description of available,more detailedtoxicological information, contact the supplier or manufacturer. 12- ECOLOGICAL INFORMATION SECTION Ecoloricily: No recognizedunusualtoxicityto plantsor animals. Relevantnhvsicaland chemicalproperties:SeeSections9 and 10 sEciloN 13- DTSPOSAL Disposeof wastematerialaccordingto local,stateand federalregulations,(SincePortlandcementis table,uncontaminated materialmay be savedor futureuse.) Disposeof bagsin an approvedlandfillor incinerator. SECTION14- TRANSPORTATION DATA @ip!ilC-0g0e: (DOT)regulations. Department of Transportation Portlandcementis not hazardousunderU.S. HaZard-chss:NotApplicable ldentificaiion Number: Not Applicable BecsledlabgIerl: NotApplicable Hazardoussubstances/renortableouantities (RQl - Not applicable INFORMATION SECTION15 - OTHERREGULATORY HazardCommunication Rule.29 CFR1910.'1200:Portlandcementis StatusLjnderIJSDOL-OSHA considereda "hazardouschemical"underthis regulationand shouldbe part of any hazard program. communication (total)TWA 5MG/M3 (RESPI. StatusunderMSHACFR30 Part47: NIOSHREL:TWA10mg/m3 : Not listed : Portlandcementqualifiesas a "hazardous substance"with delayedhealtheffects. StatusunderSARA(Titlelll).Section3'l3: Not subjectto reportingrequirements undersection313. @):somesubstancesinPort|andcementareontheTScAinventory list. Statusunderthe FederalHazardousSubstancesAct: Portlandcementis "a hazardoussubstance" subjectto statutespromulgatedunderthe subjectact. @:Thisproductcontainschemica|s(tracemeta|s)knowntothe Stateof Californiato causecancer,birth defectsor otherreproductiveharm.Californialaw requiresthe manufacturer to givethe abovewarningin the absenceof definitivetestingto provethat the definedrisks do not exist. Status under CanadianEnvironmentalProtectionAct: Not listed. Portland cement is considered to be a hazardous material under the Hazardous SlaUfJldeLI{HM[i: Products Act as defined by the Controlled Products Regulations(Class E - Corrosive Metal) and is therefore subject to the labeling and MSDS requirementsof the Workplace HazardousMaterials InformationSystem (WHMIS). SECTION16 - OTHERINFORMATION Beyidq!-dale: July 9, 2007 Ele-ef-preyiels-UjiDs: December30, 2006 a$efJ0pqtantlOlC@aliC!: Portlandcementshould only be used by knowledgeablepersons.A key to using the product safely requiresthe user to recognizethat Portlandcementchemicallyreactswith water,and that some of the intermediateproductsof this reaction(that is, those presentwhile a Portland cementproduct is "setting" pose a far more severehazardthan does Portlandcement itself, While the informationprovidedin this materialsafetydata sheet is believedto provide a useful summary of the hazardsof Portlandcementas it is commonlyused,the sheetcannotanticipateand provideall of productusersshouldobtain the intormationthat might be neededin everysituation.Inexperienced proper training before using this product. SELLERMAKESNOWARRANTY,EXPRESS OR IMPLIED, CONCERNING THEPRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FORANY PURPOSE OR CONCERNING THEACCURACY OF ANY INFORMATION PROVIDED BY AlamoCementCo.,exceptthat the productshall performto contractedspecification.The informationprovidedhereinwas believedby Alamo CementCo. to be accurateat the time of preparationor preparedfrom the sources to believedto be reliable,but it is the responsibilityof the user to investigateand understandother pertinentsources of informationto comply with all lawsand proceduresapplicableto the safehandlingand useof productand to determinethe suitabilityof the productfor its intendeduse.Buyer'sexclusiveremedyshall be for damagesand no claimof any kind,whetheras to productdeliveredor for non-delivery or product,and whetherbasedon contract,breachof warranty , negligence,or otherwiseshall be greaterin amount than the purchaseprice of the quantityof productin respectof whlchdamagesareclaimed.In no eventshallSellerbe liablefor incidentalor consequentialdamages,whether Buyer's claim is basedon contract,breachof warranty, negligenceor otherwise, In particular,the datafurnishedin this do not addresshazardsthat may be posedby othermaterials mixed with Portlandcementto produce Portlandcementproducts.Usersshould reviewother relevant materialsafety data sheets beforeworking with this Portlandcementor working on Portlandcement products,for example,Portlandcementconcrete. Material Safety Data Sheet 24 Hour Emergency Phone Numbers: Medical: 1-800-327 -3874 1-513-558-5111 Transportation: 1-800-535-5053 1-352-323-3500 NOTE: National Response Center emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals. IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16. Section 1 - Chemical Product / Company Information This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request. Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en espa ñol a su solicitud. Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere . Product Name: DAP® Wallboard Joint Compound Product UPC Number: Product Use/Class: Manufacturer: 070798300705 070798301207 RTU Spackle/Wallboard Repair Revision Date: Supercedes: 04/27/2007 MSDS Number: 00070288605 07/28/2003 DAP Canada Corporation 475 Finchdene Square Unit 5 Scarborough, Ontario M1X 1B7 888-327-8477 (non-emergency matters) Section 2 - Composition / Information On Ingredients Chemical Name CASRN WT% Calcium carbonate 1317-65-3 40-70 Mica Magnesium aluminum silicate 12001-26-2 12174-11-7 1-5 1-5 Silica, crystalline 14808-60-7 0.1-1.0 Ethylene glycol 107-21-1 0.1-1.0 ACGIH TWA ACGIH STELACGIH CEIL OSHA TWA OSHA STEL OSHA CEIL 5 MGM3 10 MGM3 N.E. N.E. (respirable N.E. N.E. fraction) 3 MGM3 N.E. N.E. 5 MGM3 N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. 10/(%SiO2 + 0.05 MGM3 N.E. N.E. N.E. N.E. 2) MGM3 N.E. N.E. 100 MGM3 N.E. N.E. N.E. Skin No No No No No Exposure Notes: 14808-60-7 The 2002 ACGIH Threshold Limit Values for Chemical Substances and Physical Agents lists the median Respirable Particulate Mass (RPM) point for crystalline silica at 4.0 microns in terms of the particle's aerodynamic diameter. The TLVs for crystalline silica represent the respirable fraction. OSHA PEL TWA for Quartz is calculated using the following formula: 10 mg/m3/(% SiO2 + 2). Both concentration and percent quartz for the application of this limit are to be determined from the fraction passing a size selector with the following characteristics. |------------------------------------------------------------------------------------|-----------------------------------------| | ....... Aerodynamic diameter ( unit density sphere ) .....| Percent passing selector | | 2 ................................................................................|.................90....................| | 2.5 .............................................................................|..................75...................| | 3.5 .............................................................................|..................50...................| | 5.0 .............................................................................|..................25...................| | 10 ..............................................................................|...................0....................| Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary between states. Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work practices Section 3 - Hazards Identification Emergency Overview: A white to off-white paste product with a musty odor. CAUTION! This product contains ethylene glycol. Refer to other MSDS sections for other detailed information. Effects Of Overexposure - Eye Contact: Direct eye contact may cause irritation. Effects Of Overexposure - Skin Contact: May cause skin irritation. May cause dry skin. Effects Of Overexposure - Inhalation: Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes). Inhalation of dust may cause lung damage or other adverse pulmonary and respiratory effects. Effects Of Overexposure - Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Effects Of Overexposure - Chronic Hazards: Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Studies have shown that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals. Ethylene glycol has been shown to cause birth defects in laboratory animals. The International Agency for Research on Cancer (IARC) has determined that crystalline silica in the form of quartz or cristobalite that is inhaled from occupational sources is carcinogenic to humans (Group 1- carcinogenic to humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (published in June 1997) in conjunction with the use of these materials. The National Toxicology Program (NTP) classifies respirable crystalline silica as "known to be a human carcinogen". Refer to the 9th Report on Carcinogens (2000). The American Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (Group A2). Breathing dust containing respirable crystalline silica may not cause noticeable injury or illness even though permanent lung damage may be occurring. Inhalation of dust may have the following serious chronic health effects: Excessive inhalation of respirable dust can cause pneumoconiosis, a respiratory disease, which can result in delayed, progressive, disabling and sometimes fatal lung injury. Symptoms include cough, shortness of breath, wheezing, non-specific chest illness and reduced pulmonary function. Smoking exacerbates this disease. Individuals with pneumoconiosis are predisposed to develop tuberculosis. There is some evidence that breathing respirable crystalline silica or the disease silicosis is associated with an increased incidence of significant disease endpoints such as scleroderma (an immune system disorder manifested by fibrosis of the lungs, skin and other internal organs) and kidney disease. Primary Route(s) Of Entry: Skin Contact, Inhalation Medical Conditions which May be Aggravated by Exposure: If dry sanded, asthma and asthma-like conditions may worsen from prolonged or repeated exposure to dust. Section 4 - First Aid Measures First Aid - Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately. First Aid - Skin Contact: Wash off immediately with soap and plenty of water. First Aid - Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. First Aid - Ingestion: Do not induce vomiting. Call a physician or Poison Control Center immediately. Note to Physician: None. COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arises from any of the above routes of entry. Section 5 - Fire Fighting Measures Flash Point, F: Greater than 200 degrees Method: ( Seta Closed Cup) Lower Explosive Limit, %: Not Established Upper Explosive Limit, %: Not Established Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog Unusual Fire And Explosion Hazards: None known. Special Firefighting Procedures: Cool fire -exposed containers using water spray. Section 6 - Accidental Release Measures Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Scrape up dried material and place into containers. Section 7 - Handling And Storage Handling: KEEP OUT OF REACH OF CHILDREN! Avoid contact with skin and eyes. Wash thoroughly after handling. Do not breathe dust. While dry sanding, use of a NIOSH -approved dust mask is recommended. Removal of this product after use will result in the generation of Dust. If dry-sanded, exposure to dust may result in the build-up of material in eyes, ears, nose, and mouth which may cause irritation. Avoid excessive heat and handling. Storage: Store away from caustics and oxidizers. Do not store at temperatures above 120 degrees F. Keep tightly closed. Avoid excessive heat and freezing. Section 8 - Exposure Controls / Personal Protection Precautionary Measures: Please refer to other sections and subsections of this MSDS. Engineering Controls: Local ventilation of emission sources may be necessary to maintain ambient concentrations below recommended exposure limits. Wet sanding is recommended to avoid generation of dust. Prevent build-up of dust and vapors by opening windows and doors or use other means to ensure fresh air entry during application, drying and sanding. Respiratory Protection: A respiratory protection program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. If concentrations exceed the exposure limits specified, use of a NIOSH-approved supplied air respirator is recommended. Where the protection factor is exceeded, use of a Self Contained Breathing Apparatus (SCBA) may be necessary. Use an approved NIOSH/OSHA respirator if dry sanded. National Institute for Occupational Safety and Health (NIOSH) has recommended that the permissible exposure limit be changed to 50 micrograms respirable free silica per cubic meter of air (0.05 mg/m3) as determined by a full shift sample up to 10-hour work shift. Skin Protection: Wear gloves with repeated or prolonged use. Eye Protection: Safety glasses with side-shields. Other protective equipment: Not required under normal use. Hygienic Practices: Remove and wash contaminated clothing before re-use. Section 9 - Physical And Chemical Properties Boiling Range: Odor: Appearance: Solubility in H2O: Freeze Point: Vapor Pressure: Physical State: 210 - 220 F Musty White to Off-White Not Established Not Established 17.5 mm Hg @ 68F Paste Vapor Density: Odor Threshold: Evaporation Rate: Specific Gravity: pH: Viscosity: Heavier Than Air Not Established Slower Than n-Butyl Acetate 1.8 Between 7.0 and 12.0 Not Established When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally. (See section 16 for abbreviation legend) Section 10 - Stability And Reactivity Conditions To Avoid: Excessive heat and freezing. Incompatibility: Strong bases. Strong oxidizing agents. Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx. Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions. Stability: Stable under normal conditions. Section 11 - Toxicological Information Product LD50: Not Established CASRN Chemical Name 107-21-1 Product LC50: Not Established LD50 Ethylene glycol Rat:4700 mg/kg LC50 WT% Rat:10876 mg/kg 0.1-1.0 Carcinogenicity: CAS No. 14808-60-7 Chemical Name Silica, crystalline ACGIH OSHA IARC NTP WT% Suspected human carcinogen. Not Listed. Human carcinogen. Known carcinogen. 0.1-1.0 Significant Data with Possible Relevance to Humans: None. Section 12 - Ecological Information Ecological Information: Ecological injuries are not known or expected under normal use. Section 13 - Disposal Information Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA Waste Code if Discarded (40 CFR Section 261): none Section 14 - Transportation Information DOT Proper Shipping Name: DOT Technical Name: DOT Hazard Class: Not Regulated Packing Group: N.A. N.A. N.A. Hazard Subclass: DOT UN/NA Number: N.A. None Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may apply if shipped via other modes of transportation and/or to non-domestic destinations. Section 15 - Regulatory Information CERCLA - SARA Hazard Category: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Immediate Health Hazard, Chronic Health Hazard SARA Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: None Toxic Substances Control Act: All ingredients in this product are either on TSCA inventory list, or otherwise exempt. This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: None U.S. State Regulations New Jersey Right-to-Know: The following materials are non-hazardous, but are among the top five components in this product: Chemical Name CAS Number Water 7732-18-5 WT% 15-40 Pennsylvania Right-to-Know: The following non-hazardous ingredients are present in the product at greater than 3%: Chemical Name CAS Number Water 7732-18-5 WT% 15-40 California Proposition 65: WARNING: This product contains chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. Section 16 - Other Information HMIS Ratings: Health: 1 Flammability: 0 VOLATILE ORGANIC COMPOUNDS, GR/LTR: 15.3 Reactivity: 0 LB/GAL: 0.1 Personal Protection: X WT%: 0.4 REASON FOR REVISION: Periodic Update Legend: N.A. – Not Applicable ACGIH – American Conference of Governmental Industrial Hygienists N.E. – Not Established SARA – Superfund Amendments and Reauthorization Act of 1986 N.D. – Not Determined NJRTK – New Jersey Right-to-Know Law VOC – Volatile Organic Compound OSHA – Occupational Safety and Health Administration PEL – Permissible Exposure Limit HMIS – Hazardous Materials Identification System TLV – Threshold Limit Value NTP – National Toxicology Program STEL – Short Term Exposure Limit CEIL – Ceiling Exposure Limit LD50 – Lethal Dose 50 LC50 – Lethal Concentration 50 F – Degree Fahrenheit C – Degree Celsius MSDS – Material Safety Data Sheet CASRN – The Chemical Abstracts Service Registry Number DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context of the intended use and (ii) determine if they are appropriate. 00010421001 French Page 1 of 7 Fiche signalétique 24 heures – Numéros de téléphone en cas d’urgence: Urgence m édicale/ Empoisonner le Contrôle: 1-800-327-3874 1-513-558-5111 Urgence transport/Centre national de R éponse: 1-800-535-5053 1-352-323-3500 NOTE: Les numéros de t éléphone en cas d’urgence doivent être utilisés uniquement lors de déversement, de fuite, d’incendie, d’exposition ou d’accident impliquant des produits chimiques. IMPORTANT: Lire attentivement cette fiche signalétique avant de manipuler ou de disposer de ce produit. Remettre ces informations aux employés, clients et utilisateurs de ce produit. Ce produit est régit sous la gouverne de l’OSHA, Communication de renseignements à l’égard de matières dangereuses, et ce document a été préparé pour répondre aux exigences de ces standards. Les significations pour toutes les abréviations utilisées dans cette fiche signal étique sont décrites à la Section 16. Section 1 – Identification du produit et de la compagnie This MSDS is offered in English upon request. Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere. Nom du produit: Numéro UPC: Utilisation du produit/Classe: Fabricant: DAP DRYDEX SPACKLING (RTU) SERRE LE TUBE 070798123342, 070798123366, 070798123410, 070798123465 Pr êt à Utiliser la Réparation de Spackle/Panneau MURAL DAP Inc. 2400 Boston Street Suite 200 Baltimore, MD 21224-4723 888 -327-8477 (Pour toute information non urgente) Date de r évision: 10/09/2007 Date 05/17/2007 d’abrogation: Numéro de fiche: 00010421001 Section 2 - Identification des dangers Urgences générales: Un produit rose de pâte avec une odeur insignifiante. AVERTISSEMENT ! Peut causer une irritation des yeux, de la peau, du nez, de la gorge et des voies respiratoires. L’enlèvement de ce produit après usage ou lors de ponçage à sec générera de la poussière. L’exposition à cette poussière peut causer une irritation des yeux, des oreilles, du nez et de la bouche. Nocif par inhalation et par ingestion. Lors de ponçage à sec, une exposition à la poussière peut causer une accumulation de matériau dans les yeux, les oreilles, le nez et la bouche. Ce produit contient du glycol d'éthylène. Consulter les autres sections de cette fiche signalétique pour des informations plus détaillées. Effets de surexposition – Contact oculaire: Le contact direct avec les yeux peut provoquer une irritation. Effets de surexposition – Contact cutané: Peut causer une irritation de la peau. Peut causer un assèchement de la peau. Effets de surexposition – Inhalation: L'inhalation de ce produit peut provoquer l'irritation des voies respiratoires (nez, bouche, muqueuses). L'inhalation de poussi ère peut causer des dommages du poumon ou les effets autres, défavorables, pulmonaires et respiratoires. Effets de surexposition – Ingestion: L'ingestion peut provoquer une irritation de l'appareil digestif, des nausées, des vomissements et des diarrhées. Effets de surexposition – Dangers chroniques: 00010421001 French Page 2 of 7 L'Agence Internationale pour la Recherche sur le Cancer (IARC) a déterminé cette silice cristalline sous forme de quartz ou cristobalite qui est inhalé des sources de métier est cancérog ène aux humains (Groupe 1- cancérogène aux humains). Se référer à la Monographie de IARC 68, la Silice, Quelques Silicates et Quelques Fibres Organiques (a publié en juin 1997) conjointement avec l'usage de ces matériels. Le Programme National de Toxicologie (NTP) classifie respirable la silice cristalline comme " connu pour être une substance cancérogène humaine ". Se référer au neuvième Rapport sur les Substances Canc érogènes (2000). La Conférence Am éricaine d'Hygiénistes Industriels Gouvernementaux (ACGIH) classifie la silice cristalline, le quartz, comme une substance cancérogène humaine pr ésumée (le Groupe A2). Respirer de la poussière contenant de la silice cristalline peut ne pas causer de lésions ni de maladies apparentes m ême si des lésions permanentes aux poumons sont survenues. L’inhalation de poussi ère peut avoir des conséquences chroniques très sérieuses pour la santé : L’inhalation excessive de poussière respirable peut causer une pneumoconiose, une maladie respiratoire qui peut dégénérer sur un certain temps en incapacité progressive et quelques fois en lésions des poumons qui peut être mortelle. Les symptômes incluent : toux, respiration courte, sifflements, maladie de poitrine indéterminée et une réduction de la capacité pulmonaire. Fumer peut causer une accélération brutale de cette maladie. Les personnes atteintes de pneumoconiose sont prédisposées pour développer la tuberculose. Il y a plusieurs évidences démontrant que respirer de la silice cristalline ou la silicose est associ ée à une incidence accrue de maladies extrêmes significatives tel que le syndrome d’Erasmus (un désordre du système immunitaire manifeste caus é par une fibrose des poumons, de la peau et de d’autres organes internes) et une maladie des reins. Une exposition excessive et répétée à l’éthyl ène glycol peut causer des l ésions aux reins et au foie. Les études en laboratoire menées sur des animaux ont démontré que l ’inhalation répétée d’éthyl ène glycol cause des changements néfastes du système cardiovasculaire. Lors d’études en laboratoire sur les animaux, il a été démontré que l ’éthyl ène glycol cause des anomalies congénitales. Voie(s) d’absorption: Peau le Contact, Inhalation, Oeil le Contact Problèmes médicaux aggravés lors d’exposition au produit: Lors de pon çage à sec, la condition des personnes atteintes d’asthme ou de symptômes semblables à l’asthme peut s’aggraver en cas d’exposition excessive et répétée à la poussière. Effets cancérig ènes: CAS No. 14808-60-7 Chemical Name Silice cristalline ACGIH OSHA IARC NTP Présumée canc érogène humaine. Pas Enuméré. Cancérogène humaine. Cancérogène connue. Section 3 - Composition / Ingrédients dangereux Chemical Name Pierre à chaux Éthylène glycol Magnesium aluminum silicate Silice cristalline CASRN 1317-65-3 107-21-1 12174-11 -7 14808-60 -7 Wt% 60-100 0.5-1.5 0.5-1.5 0.1-1.0 Section 4 - Premiers soins Premiers soins – Contact oculaire: En cas de contact avec les yeux, rincer abondamment avec de l ’eau pendant au moins 15 minutes. Obtenir des soins médicaux immédiatement. Premiers soins – Contact cutané: Laver immédiatement et abondamment avec de l'eau et du savon. Premiers soins – Inhalation: En cas d’inhalation, amener la personne à l’air frais. Si la personne ne respire plus, appliquer la respiration artificielle. Si la personne a de la difficulté à respirer, donner de l’oxyg ène. Obtenir des soins médicaux immédiatement. 00010421001 French Page 3 of 7 Premiers soins – Ingestion: Appeler immédiatement un m édecin ou un Centre AntiPoison. Ne pas faire vomir. Note au médecin: Aucun. COMMENTAIRES: En cas d’apparition d’une irritation ou de complications suite à une exposition au produit, communiquer immédiatement avec l’urgence m édicale au 1-800-327 -3874. Section 5 - Mesures de protection en cas d’incendie Moyens d’extinction: Dioxyde de carbone, Sécher Chimique, Mousse, Arroser le Brouillard Risques particuliers d’explosions ou d’ignition: Aucune connue. Procédures spéciales de lutte contre les incendies: Utiliser une lance-brouillard afin de refroidir les contenants expos és au feu. Section 6 - Mesures en cas de déversement accidentel Procédures de nettoyage: Porter un équipement de protection personnel approprié tel que spécifié à la Section 8. Gratter le mat ériau sec puis déposer dans un contenant. Section 7 - Manutention et entreposage Manutention: TENIR HORS DE LA PORTÉE DES ENFANTS! Eviter le contact avec la peau et les yeux. Ne pas respirer la poussi ère. Pendant que sécher sanding, of a d'usage masque de poussière NIOSH-APPROUVE est recommandé. L’enlèvement de ce produit générera de la poussière. Lors de ponçage à sec, l’exposition à cette poussière produit une accumulation de matériau dans les yeux, les oreilles, le nez et la bouche et peut causer une irritation. Éviter la chaleur et la manipulation excessive. Laver vigoureusement après la manipulation. Entreposage: Éviter la chaleur excessive ou le froid excessif. Ne pas entreposer à des températures supérieures à 120º F (48,8º C). Conserver hermétiquement fermé. Entreposer loin des produits caustiques et des agents oxydants. Section 8 - Contrôles d’exposition / Protection personnelle Chemical Name CASRN ACGIH TWA ACGIH STEL ACGIH CEIL Pierre à chaux 1317-65-3 10 MGM3 N.E. N.E. Éthylène glycol Magnesium aluminum silicate 107-21-1 12174-11-7 N.E. N.E. N.E. N.E. 100 MGM3 N.E. Silice cristalline 14808-60-7 0.05 MGM3 N.E. N.E. OSHA TWA 5 MGM3 (respirable fraction) N.E. N.E. 10/(%SiO2 + 2) MGM3 OSHA STEL OSHA CEIL Skin N.E. N.E. Non N.E. N.E. N.E. N.E. Non Non N.E. N.E. Non Notes concernant l’exposition: 14808-60-7 La liste des valeurs d'exposition moyennes pondérées (VEMP) 2001 émise par l'ACGIH, section «Threshold Limit Values for Chemical Substances and Physical Agents» indique que la silice cristalline, en terme de particule aérodynamique, possède un diamètre de 4.0 microns. La limite volatile tolérable pour la silice cristalline représente la fraction respirable. La limite d'exposition permise et la limite volatile tolérable pour la silice cristalline, quartz, sont calculées par l'OSHA à partir de la formule suivante : 10 mg/m3/(% SiO2 + 2). Les deux, la concentration et le pourcentage de quartz pour l'application de ces limites, doivent être déterminées par le pourcentage de silice cristalline non capté lors du passage des particules en suspension dans un capteur-sélecteur de micro-organismes ayant les caractéristiques suivantes : |----------------------------------------------------------------------------|-------------------------------| | .. Diamètre aérodynamique (sphère de densit é égale à l'unité) .| Pourcentage non capté | |....................................................................................................| par un capteur-sélecteur | 00010421001 French Page 4 of 7 |....................................................................................................| de micro-organisme | | 2 ................................................................................................|.................90....................| | 2.5 .............................................................................................|..................75...................| | 3.5 .............................................................................................|..................50...................| | 5.0 .............................................................................................|..................25...................| | 10 ..............................................................................................|...................0....................| Mesures de précaution: S'il vous plaît se référer aux autres sections et aux autres sous -sections de ce MSDS. Contrôles d’ingénierie: Une ventilation locale près de la source d'émission peut être nécessaire pour maintenir la concentration ambiante au-dessous des niveaux limites recommandés. Empêcher l'accumulation de poussière et les vapeurs en ouvrant fenêtres et les portes ou utilise d'autres moyens pour assurer de l'entrée d'air fraîche pendant l'application, séchant et sanding. Un ponçage humide est recommandé afin d’éviter de générer de la poussière. Protection des voies respiratoires: Si la concentration dépasse les niveaux limites sp écifiés, il est recommandé d'utiliser un respirateur à adduction d'air pur agr éé par NIOSH. Lorsque la concentration dépasse le facteur de protection de ce type de respirateur, il peut être nécessaire d'utiliser un appareil respirateur autonome. Un programme de protection respiratoire défini selon les normes de l ’OSHA 1910.134 et de l’ANSI Z88.2 doit être appliqu é à chaque fois que les conditions sur les lieux de travail exigent de porter un respirateur. Lors de ponçage à sec, porter un respirateur approuvé NIOSH/OSHA. Le National Institute for Occupational Safety and Health (NIOSH) recommande que la limite d’exposition permise pour la silice en suspension soit abaissée à 50 microgrammes par mètre cube d’air (0,05 mg/m3) tel que déterminé lors de périodes de travail complètes pouvant aller jusqu’à 10 heures. Protection de la peau: En cas d’utilisation excessive et répétée, porter des gants. Protection des yeux: lunettes de sécurité avec protections latérales Équipements de protection additionnels: inutile dans les conditions normales d'utilisation. Pratiques hygiéniques: Enlever et laver les vêtements contaminés avant réutilisation. Important: Les limites d’exposition permises (LEP) décrites proviennent du Department of Labor des États-Unis, règlement final concernant les valeurs d’exposition moyennes pondérées de l’OSHA (CFR 29 1910.1000); ces limites peuvent varier selon les états. Note: Prendre tous les moyens selon les circonstances afin de prévenir ou réduire toute exposition de la peau des employés aux substances portant la mention «OUI» dans la colonne «PEAU» du tableau ci-dessus. Utiliser des gants, une combinaison, des lunettes étanches, tout autre équipement de protection personnel adéquat, les contrôles techniques et les pratiques appropriées au type de travail. Section 9 - Propriétés physiques et chimiques Point d’ébullition: Odeur: Apparence: Pas Etabli. Insignifiant Pink Densité de vapeur: Limite de détection olfactive: Taux d ’évaporation: Plus lourd Qu'Aérer Pas Etabli. Plus lent Que Acétate de n-Butyl 1.9 Solubilité dans l’eau (H 2 O): Point de congélation: Pression de vapeur: État physique: Point d’éclair, º F: Limite d ’explosibilité inférieure, %: Pas Etabli. Poids spécifique: Pas Etabli. Pas Etabli. Pâte Plus grand que 200 degrés Pas Etabli. Taux de pH: Entre 7,0 et 12,9 Viscosité: Pas Etabli. Inflammabilité: Ininflammable Méthode: (Seta A Fermé la Tasse) Limite d ’explosibilité supérieure, %:Pas Etabli. Quand rapporté, la pression de vapeur de ce produit a été basé son maquillage de constituant théoriquement calculée et n'a pas été expérimentalement. (Consulter la Section 16 pour conna ître la signification des abréviations) Section 10 - Stabilité et réactivité 00010421001 French Page 5 of 7 Conditions à éviter: Chaleur excessive ou froid excessif. Incompatibilité: des oxydants forts des bases fortes Produits de décomposition dangereux: Produits de d écomposition habituels : oxydes de carbone (COx) et oxydes d’azote (NOx). Risque de polym érisation: Aucune polymérisation dangereuse ne surviendra dans des conditions normales d’utilisation. Stabilité: Stable dans des conditions normales Section 11 - Propriétés toxicologiques Produit DL50: Pas Etabli. CASRN 107-21-1 Chemical Name Produit CL50: Pas Etabli. LD50 Éthylène glycol LC50 Rat:4700 mg/kg Rat:10876 mg/kg Données significatives possiblement pertinentes à l’humain: Aucun. Section 12 - Information écologique Information écologique: Aucune dégradation de l'environnement n'est connue ou prévisible dans les conditions normales d'utilisation. Section 13 - Information sur la mise au rebut Information concernant la mise au rebut: Disposer de ce matériau en respectant les lois fédérales, provinciales et municipales. Les lois et restrictions provinciales et municipales sont complexes et peuvent différer des lois f édérales. La responsabilité de la disposition appropriée des déchets appartient au propriétaire des déchets. Code de mise au rebut de l ’Agence de protection de l’environnement (40 CFR Section 261): Aucun Section 14 - Étiquetage selon le Ministère des Transports Nom du produit expédié: Nom technique: Classe de danger: Pas Réglé. Pas Applicable Pas Applicable Groupe d’emballage: Classe de transport: Numéro UN/NA: Pas Applicable Pas Applicable Pas Applicable Note : L'information d'expédition fournie est applicable pour le transport de sol domestique seulement. La catégorisation différente peut s'appliquer si exp édié via les autres modes de et/ou de transport aux destinations non résidentielles. Section 15 - Information sur les règlements CERCLA - Catégories de dangers selon le SARA: Ce produit a été revu en conformité avec les «Catégories de dangers» établies par l’Agence de protection de l’environnement et promulguées aux Sections 311 et 312 du Superfund Amendment and Reauthorization Act de 1986 (SARA Titre III). Selon les définitions applicables, il est considéré répondre aux catégories suivantes : RISQUE DE SANTE IMMEDIAT, RISQUE DE SANTE CHRONIQUE SARA Section 313: 00010421001 French Page 6 of 7 Ce produit contient les substances suivantes assujetties aux normes de déclaration de la Section 313, du Titre III de la Superfund Amendments and Reauthorization Act de 1986 et du 40 CFR partie 372: Aucun LOI SUR LE CONTRÔLE DES SUBSTANCES TOXIQUES: Tous ingrédients dans ce produit sont ou sur la liste d'inventaire de TSCA, ou autrement exempter. Ce produit contient les substances chimiques suivantes à déclarer selon les normes TSCA 12(B) si export é à l’extérieur des États -Unis: Aucun New Jersey Right-to-Know: Les substances suivantes sont non-dangereuses mais sont comptées parmi les 5 principaux ingrédients composant ce produit: Chemical Name CAS Number Eau 7732-18-5 Pennsylvania Right-to-Know: Les substances suivantes sont non-dangereuses mais sont présentes à plus de 3% dans ce produit: Chemical Name CAS Number Eau 7732-18-5 Proposition 65 de Californie: AVERTISSEMENT : Ce produit contient des produits chimiques connus à l'Etat de Californie pour causer le cancer, des anomalies congénitales ou d’autres problèmes reliés à la reproduction. Section 16 - Autres informations HMIS Classification des dangers: Santé: 1 Inflammabilité: 0 Réactivité: 0 Protection personnelle: X COMPOSÉ ORGANIQUE VOLATIL (VOC), moins d'eau exempte moins: G/LITRE : POIDS : POIDS % : 1.2 39.8 COMPOSÉ ORGANIQUE VOLATIL (VOC), moins d'eau exempte moins, moins LVP-VOCs: 0.3 RAISONS DE RÉVISION: Mise à jour p ériodique Légende: N.A. – Non applicable LD50 – Dose létale 50 N.É. – Non établi LC50 – Concentration létale 50 N.D. – Non déterminé NJRTK – New Jersey Right-to -Know Law OSHA – Occupational Safety and Health Administration VOC – Composé organique volatil LB/GALLON: 0.3 POIDS : POIDS %: 00010421001 French Page 7 of 7 HMIS – Hazardous Materials Identification System PEL – Limite d’exposition permise TWA – Valeur d’exposition moyenne pondérée TLV – Limite tolérable d’exposition NTP – National Toxicology Program F – Degré Fahrenheit STEL – Limite d’exposition à court terme C – Degré Celcius CASRN – Numéro enregistré selon le Chemical Abstracts Service ACGIH – American Conference of Governmental Industrial Hygienists SARA – Superfund Amendments and Reauthorization Act de 1986 CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act DAP croit que les données et renseignements stipulés dans cette fiche signal étique sont précis à la date de rédaction de cette fiche. Ces données sont offertes en toute bonne foi et représente des valeurs standard sans toutefois être des sp écifications du produit. AUCUNE GARANTIE SUR LA QUALITÉ MARCHANDE, GARANTIE D’APTITUDE POUR AUCUN TYPE D’EMPLOI PARTICULIER OU TOUTE AUTRE FORME DE GARANTIE N’EST EXPRESSÉMENT OU IMPLICITEMENT OFFERTE EN REGARD DES INFORMATIONS FOURNIES DANS CETTE FICHE OU DES INFORMATIONS RELATIVES AU PRODUIT. Cette fiche est produite uniquement à titre de guide pour les personnes formées à cet effet afin qu’elles puissent appliquer les procédures appropri ées de manutention auxquelles le produit réfère. Toutefois, c’est la responsabilité chaque utilisateur de revoir les recommandations selon le contexte spécifique de l’utilisation prévue et de déterminer si ces proc édures sont appropriées. < Fin de la fiche signalétique > MATERIAL SAFETY DATA SHEET Date Printed: 07/16/2001 Product Code(s): 4130, 4132, 4136 Page: ________________________________________________________________________________ 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product Name: Body Seam Tape Product Code(s): 4130, 4132, 4136 Manufacturer/Supplier: TRANSTAR AUTOBODY TECHNOLOGIES 2040 Heiserman Dr. Brighton, MI, 48114, USA 24 Hour Emergency Phone(s): 800-424-9300 (CHEMTREC), 613-996-6666 (CANUTEC) Business Phone: 810-220-3000 Product Use: Sealant MSDS Prepared By: V. Burgess Byrd ________________________________________________________________________________ 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient(s) CAS Number % by Weight --------------------------------------------------------------------------2-Ethylhexyl Acrylate 103-11-7 65- 80% Acrylic Acid, Glacial 79-10-7 5 - 10% n-Vinyl Pyrollidone 88-12-0 0 - 5% Isobornyl Acrylate 5888-33-5 0 - 5% See Section 15. Regulatory Information for code descriptions Weight percent (%) of 0.0 means chemical is in trace amounts. ________________________________________________________________________________ 3. HAZARDS IDENTIFICATION CAUTION! COMBUSTIBLE HMIS Hazard Ratings: Health =0 , Flammability =1, Chemical Reactivity =0 Note: HMIS ratings involve data and interpretations that may vary from company to company. They are intended only for rapid, general identification of the magnitude of the specific hazard. To deal adequately with the safe handling of this material, all the information contained in this MSDS must be considered. Potential Health Effects Eyes: Minimal to slight irritation to the eyes. and itching. Exposure can cause redness Skin: Slight irritation to the skin. Inhalation: Minimal to slight irritation to the respiratory system. Ingestion: Slight irritation to the digestive tract. ________________________________________________________________________________ 1 MATERIAL SAFETY DATA SHEET Date Printed: 07/16/2001 Product Code(s): 4130, 4132, 4136 Page: ________________________________________________________________________________ 4. FIRST AID MEASURES Seek professional medical attention for all over-exposures and/or persistent problems. Eyes Contact: Flush eyes with clean water for a minimum of 15 minutes. Seek medical attention. Skin Contact: Wash exposed area thoroughly with soap and water. Inhalation: Remove person from area to fresh air. difficulty persists, seek medical attention. Ingestion: DO NOT INDUCE VOMITTING. If breathing Seek immediate medical attention. ________________________________________________________________________________ 5. FIRE FIGHTING MEASURES Flammable Properties Flash Point: >200 Deg F, 93 Deg CMethod: TCC Upper Explosive Limit (UEL): n/a Lower Explosive Limit (LEL): n/a Autoignition Temperature: No data Extinguishing Media: Foam, Alcohol Foam, CO2, Dry Chemical, Water Fog, Other. Special Firefighting Procedures: Full fire fighter equipment including SCBA should be worn to avoid skin contact and inhalation of concentrated vapors. Minimize skin exposure. Highly toxic fumes may be generated by thermal decomposition. Hazardous Combustion Products: Carbon monoxide, carbon dioxide, oxides of nitrogen. Unusual Fire and Explosion Hazards: Vapors can travel to a source of ignition and flash back. Closed containers may explode when exposed to extreme heat or burst when contaminated with water (CO2 gas evolved). Hazards apply to empty containers. Combustion generates toxic fumes. ________________________________________________________________________________ 6. ACCIDENTAL RELEASE MEASURES For large spills or transportation accidents involving release of this product, contact the Emergency Response Center: 800-424-9300. Eliminate all sources of ignition, provide adequate ventilation, dike spill area and add absorbent earth or sawdust to spilled liquid. Sweep up and dispose of in appropriate containers in accordance with Federal, State and/or Local regulations. ________________________________________________________________________________ 7. HANDLING AND STORAGE 2 MATERIAL SAFETY DATA SHEET Date Printed: 07/16/2001 Product Code(s): 4130, 4132, 4136 Page: ________________________________________________________________________________ Use non-sparking tools when handling this material. Use in cool, well-ventilated areas. Keep containers closed when not in use. Keep away from excessive heat and open flames. Follow all MSDS/label precautions even after container is emptied because they may retain product residues. Store in a cool area away from heat and flames. Do not reuse container when empty. ________________________________________________________________________________ 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name/Exposure Limits CAS Number --------------------------------------------------------------------------2-Ethylhexyl Acrylate 103-11-7 (OSHA PEL: 5 mg/m3) Acrylic Acid, Glacial 79-10-7 (OSHA PEL: 10 ppm) n-Vinyl Pyrollidone 88-12-0 (OSHA PEL: Not Est, ACGIH TLV: Not Est, OTHER: Not Est) Isobornyl Acrylate 5888-33-5 (OSHA PEL: Not Est, ACGIH TLV: Not Est, OTHER: Not Est) Engineering Controls: General mechanical ventilation or local exhaust should be utilized to keep vapor concentrations below exposure limits (PEL & TLV). Ventilation equipment must be explosion proof. Respiratory Protection: Utilize engineering controls to reduce emission levels below the time weighted exposure limits (ACGIH TLV & OSHA PEL). Wear an approved respirator if exposure limits are above the exposure limits listed above. Eye Protection: Use safety glasses or splash goggles. Skin Protection: Use chemical resistant gloves. Safe Work Practices: Eye washes and safety showers in the workplace are recommended. Avoid contact with skin and eyes. Avoid breathing vapors. Wash hands thoroughly after using and before eating, drinking or smoking. Employee education and training in the safe use and handling of this product is required under the OSHA Hazard Communication Standard 29CFR1200. Smoking in area where this material is used should be strictly prohibited. Always use protective clothing and equipment. Remove all contaminated clothing and wash thoroughly when finished working. Keep food and drink away from material and from area where material is being used. ________________________________________________________________________________ 9. PHYSICAL AND CHEMICAL PROPERTIES Physical Form: Homogeneous mixture Physical State: Solid Color: Cloudy, colorless Odor: Characteristic acylate odor. Odor Threshold: No Data Specific Gravity (water=1) 1.00 Vapor Pressure: No data 3 MATERIAL SAFETY DATA SHEET Date Printed: 07/16/2001 Product Code(s): 4130, 4132, 4136 Page: ________________________________________________________________________________ Vapor Density: N/A Material VOC: 0.00 lb/gl 0 g/l Coating VOC: 0.00 lb/gl 0 g/l Evaporation Rate: N/A Boiling Point: n/a Melting Point: No data Freezing Point: No data Viscosity at Ambient Temperature: No data Solubility in Water: Insoluble Octanol/Water Partition Coefficient: No data pH: No data ________________________________________________________________________________ 10. STABILITY AND REACTIVITY Stability: Stable Incompatibility: Strong acids, strong bases and strong oxidizing agents. Hazardous Polymerization: WILL NOT OCCUR. ________________________________________________________________________________ 11. TOXICOLOGICAL INFORMATION Effects of Exposure: ACUTE: INHALATION - Minimal odor present during normal material handling and use. EYE CONTACT - Mild irritation, tearing, redness. SKIN CONTACT - Mild irritation possible. INGESTION - May cause mild gastrointestinal irritation, vomiting, nausea, & diarrhea. CHRONIC: No chronic health effects known. Acute Toxicity Data: No data. Carcinogenicity: NTP -No, IARC -No, OSHA -No This product has not been tested for carcinogenic effects. Some chemicals in this product may be identified by NTP, IARC and/or OSHA as carcinogenic, indicated above as "Yes". No further information available. Teratology: No data. Reproduction: No data. Mutagenicity: No data. ________________________________________________________________________________ 12. ECOLOGICAL INFORMATION No data. 4 MATERIAL SAFETY DATA SHEET Date Printed: 07/16/2001 Product Code(s): 4130, 4132, 4136 Page: ________________________________________________________________________________ ________________________________________________________________________________ 13. DISPOSAL CONSIDERATIONS This product when disposed represents a non-hazardous waste, as identified in 40CFR261. It is the responsibility of each waste generator to identify the proper classification of their waste streams. ________________________________________________________________________________ 14. TRANSPORT INFORMATION The following transportation information is provided based on Transtar Autobody Technologies interpretation of shipping regulations. Each shipper is responsible for identifying, naming, marking and labeling prior to offering for transport. USA (DOT) Status: Not regulated Water (IMDG) Status: Not regulated Air (ICAO,IATA) Status: Not regulated Canada (TDG) Status: Not regulated ________________________________________________________________________________ 15. REGULATORY INFORMATION The information listed in this section is not all inclusive of all regulations for this product or the chemical components of this product. US Federal Regulations TSCA Status: All known major components of this product are listed on the TSCA Inventory and/or are otherwise in compliance with TSCA. SARA 302 (EHS) Status: No EHS chemicals present. SARA 311/312 Status: No hazards to Emergency Responders identified. SARA 313 Status: *** No toxic chemical(s) subject to the reporting requirements of section 313 of Title III and of 40 CFR 372 are present. *** OSHA Status: This material meets the requirement of hazardous material and is subject to 29CFR1910.1200. USA State Information California Proposition 65: This product does not contain chemical(s) known to the State of California to cause cancer or birth defects or other reproductive harm. Pennsylvania RtK Status: This material contains chemical(s) subject to notification under Pennsylvania Right to Know. New Jersey RtK Status: This material contains chemical(s) subject to 5 MATERIAL SAFETY DATA SHEET Date Printed: 07/16/2001 Product Code(s): 4130, 4132, 4136 Page: ________________________________________________________________________________ notification under New Jersey Right to Know. Massachusetts RtK Status: This material contains chemical(s) subject to notification under Massachusetts Right to Know. Rhode Island RtK Status: This material contains chemical(s) subject to notification under Rhode Island Right to Know. International Regulations Canada DSL Status: All known major components of this product are listed on the DSL Inventory and/or are otherwise in compliance with the DSL WHMIS: E EINECS Status: All components of this material are listed on the EINECS Inventory. ________________________________________________________________________________ 16. OTHER INFORMATION To the best of our knowledge, the information contained herein is accurate, obtained from sources believed by Transtar Autobody Technologies to be accurate. As with all chemicals, KEEP AWAY FROM CHILDREN AND ANIMALS. FOR PROFESSIONAL USE ONLY. The hazard information contained herein is offered solely for the consideration of the user, subject to his own investigation and verification of compliance with applicable regulations, including the safe use of the product under every foreseeable condition. ________________________________________________________________________________ 6 MATERIAL SAFETY DATA SHEET WL30067 03 00 =========================================================================== Section 1 −− PRODUCT AND COMPANY IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT NUMBER HMIS CODES Health 1 WL30067 Flammability 0 Reactivity 0 PRODUCT NAME WHITE LIGHTNING* 3006* Original Formula All Purpose Adhesive Caulk, Clear MANUFACTURER’S NAME EMERGENCY TELEPHONE NO. THE SHERWIN−WILLIAMS CO. (216) 566−2917 Consumer Group − Industrial Cleveland, OH 44115 DATE OF PREPARATION INFORMATION TELEPHONE NO. 03−APR−07 (216) 566−2902 =========================================================================== Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− No ingredients in this product are hazardous as defined by the Department of Labor. =========================================================================== Section 3 −− HAZARDS IDENTIFICATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. In a confined area vapors in high concentration may cause headache, nausea or dizziness. SIGNS AND SYMPTOMS OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. Continued on page 2 WL30067 page 2 =========================================================================== Section 4 −− FIRST AID MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re−use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. =========================================================================== Section 5 −− FIRE FIGHTING MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− FLASH POINT LEL UEL Not Applicable N.A. N.A. FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build−up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self−contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build−up and possible autoignition or explosion when exposed to extreme heat. =========================================================================== Section 6 −− ACCIDENTAL RELEASE MEASURES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. =========================================================================== Section 7 −− HANDLING AND STORAGE −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Continued on page 3 WL30067 page 3 =========================================================================== Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1−800−424−LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. =========================================================================== Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− PRODUCT WEIGHT 8.77 lb/gal 1050 g/l SPECIFIC GRAVITY 1.06 BOILING POINT 212 − 213 F 100 − 100 C MELTING POINT Not Available VOLATILE VOLUME 51 % EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 8.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical − As Packaged) 0.26 lb/gal 31 g/l Less Water and Federally Exempt Solvents 0.13 lb/gal 15 g/l Emitted VOC Continued on page 4 WL30067 page 4 =========================================================================== Section 10 −− STABILITY AND REACTIVITY −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− STABILITY −− Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur =========================================================================== Section 11 −− TOXICOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− TOXICOLOGY DATA CAS No. Ingredient Name −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− No LC50 or LD50 data available. =========================================================================== Section 12 −− ECOLOGICAL INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− ECOTOXICOLOGICAL INFORMATION No data available. =========================================================================== Section 13 −− DISPOSAL CONSIDERATIONS −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. =========================================================================== Section 14 −− TRANSPORT INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation. IMO Not Regulated for Transportation. =========================================================================== Section 15 −− REGULATORY INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION Continued on page 5 WL30067 page 5 =========================================================================== CAS No. CHEMICAL/COMPOUND % by WT % Element −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. =========================================================================== Section 16 −− OTHER INFORMATION −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. Material Safety Data Sheet - MSDS Masking Tape Section 1. Chemical Product and Company Identification Masking Tape Common Name : Synonym Trade name Manufactured for : Not available. : DT339. : L.H. Dottie Company 6131 S. Garfield Avenue Commerce, California 90040 Tel: (323) 725-1000 Code : DT339 Validation Date : 2004-10-24. In Case of Emergency : (714) 739-1408 Section 2. Composition, Information on Ingredients Name CAS # % by Weight Polyethylene 9002-88-4 70-100 Exposure Limits OSHA PEL (United States, 2002). Notes: TWA: 5 mg/m3 8 hour(s). Form: Respirable dust TWA: 15 mg/m3 8 hour(s). Form: Total dust This material is classified as not hazardous under OSHA regulations. This product is an Article under the United States Hazard Communication System. Therefore it is EXEMPTED from the regulatory requirements under HCS. See Section 8 for Exposure Limits. See Section 11 for Toxicological Data. Section 3. Hazards Identification Physical State and Appearance Emergency Overview : Solid. Potential Chronic Health Effects : CARCINOGENIC EFFECTS: Classified None. by NIOSH [Polyethylene]. Classified 3 (Not classifiable for human.) by IARC [Polyethylene]. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. : Repeated or prolonged exposure is not known to aggravate medical condition. : No specific hazard. USE WITH CARE. Follow good industrial hygiene practice. : Ingestion. Routes of Entry Potential Acute Health Effects Eyes : Non-irritating to the eyes. Skin : Non-irritant for skin. Non-sensitizer for skin. Inhalation : Not available. Ingestion : Not available. Medical Conditions Aggravated by Overexposure: : Not available. Over-exposure signs/symptoms See Section 11 for Toxicological Data. Section 4. First Aid Measures Eye Contact Skin Contact Inhalation Ingestion Notes to Physician : Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation occurs. : In case of contact, immediately flush skin with plenty of water. Get medical attention. : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. : Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. : No specific antidote. Medical staff must contact Poison Information Center. Continued on Next Page Page: 2/5 Masking Tape Section 5. Fire Fighting Measures May be combustible at high temperature. The lowest known value is >343°C (649.4°F) (Polyethylene). Not available. Not available. These products are carbon oxides (CO, CO2). Non-flammable in presence of heat. Flammability of the Product Auto-ignition Temperature Flash Points Flammable Limits Products of Combustion Fire Hazards in Presence of Various Substances Explosion Hazards in Presence of Various Substances Fire Fighting Media and Instructions Protective Clothing (Fire) : : : : : : Special Remarks on Fire Hazards : Not available. : Risks of explosion of the product in presence of mechanical impact: Not applicable. Risks of explosion of the product in presence of static discharge: Not applicable. : SMALL FIRE: Use dry chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. : Be sure to use an approved/certified respirator or equivalent. Section 6. Accidental Release Measures Small Spill and Leak Large Spill and Leak : Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. : Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Section 7. Handling and Storage : After handling, always wash hands thoroughly with soap and water. : Keep container in a cool, well-ventilated area. Do not store above 49°C (120.2°F). Handling Storage Section 8. Exposure Controls, Personal Protection Engineering Controls Personal Protection Eyes Body Respiratory Hands Feet Protective Clothing (Pictograms) Personal Protection in Case of a Large Spill Exposure Limits Product Name Polyethylene : No special ventilation requirements. : : : : : Not required. Not required. Not applicable. Not applicable. Not applicable. : : None, under normal conditions of uses. Exposure Limits OSHA PEL (United States, 2002). Notes: TWA: 5 mg/m3 8 hour(s). Form: Respirable dust TWA: 15 mg/m3 8 hour(s). Form: Total dust Consult local authorities for acceptable exposure limits. Section 9. Physical and Chemical Properties Physical State and Appearance Color Odor Molecular Weight Molecular Formula pH (1% Soln/Water) : Solid. : : : : : Multiple. Acrylic. (Slight.) Not applicable. Not applicable. Not applicable. Continued on Next Page Page: 3/5 Masking Tape Boiling/Condensation Point Melting/Freezing Point Specific Gravity Vapor Pressure Vapor Density Volatility Odor Threshold Evaporation Rate VOC Viscosity LogKow Solubility : : : : : : : : : : : : Not available. 130.06 to 145.06°C (266.1 to 293.1°F) based on data for: Polyethylene. 1.1 (Water = 1) Not available. Not available. 0% (v/v). Not available. Not available. 0 (%) Not available. Not available. Insoluble in cold water, hot water. Section 10. Stability and Reactivity Stability and Reactivity Conditions of Instability Incompatibility with Various Substances Hazardous Decomposition Products Hazardous Polymerization : The product is stable. : Not available. : Not considered to be reactive. : Not available. : Will not occur. Section 11. Toxicological Information Chronic Effects on Humans : CARCINOGENIC EFFECTS: Classified None. by NIOSH [Polyethylene]. Classified 3 (Not classifiable for human.) by IARC [Polyethylene]. : Non-irritant for skin. Non-sensitizer for skin. Non-irritating to the eyes. Other Toxic Effects on Humans Special Remarks on Toxicity : Not available. to Animals Special Remarks on Chronic : Not available. Effects on Humans Special Remarks on Other Toxic Effects on Humans : Not available. Section 12. Ecological Information BOD and COD Biodegradable/OECD Mobility Products of Degradation Toxicity of the Products of Biodegradation Special Remarks on the Products of Biodegradation : : : : : Not available. Not available. Not available. These products are carbon oxides (CO, CO2) and water. The product itself and its products of degradation are not toxic. : Not available. Section 13. Disposal Considerations Waste Information : Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult your local or regional authorities. Continued on Next Page Page: 4/5 Masking Tape Section 14. Transport Information Regulatory Information UN number Proper shipping name Class Packing Group United States (DOT) Not regulated. - - - - IMDG Code Not regulated. - - - - IATA-DGR Class Not regulated. - - - - NAERG Label Additional information : Not applicable. Section 15. Regulatory Information HCS Classification U.S. Federal Regulations : Not controlled under the HCS (United States). : TSCA 8(b) inventory: All components listed. SARA 302/304/311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: No products were found. SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No products were found. Clean Water Act (CWA) 307: No products were found. Clean Water Act (CWA) 311: No products were found. Clean air act (CAA) 112 accidental release prevention: No products were found. Clean air act (CAA) 112 regulated flammable substances: No products were found. Clean air act (CAA) 112 regulated toxic substances: No products were found. SARA 313 Form R - Reporting Requirements : No products were found. Supplier Notification : No products were found. State Regulations : California prop. 65: No products were found. Section 16. Other Information Label Requirements : USE WITH CARE. Hazardous Material Information System (U.S.A.) Health Fire Hazard Reactivity Personal Protection 0 1 0 C National Fire Protection Association (U.S.A.) Health 0 1 Fire Hazard 0 Reactivity Specific Hazard References : - 29CFR Part1910.1200 OSHA MSDS Requirements. - 49CFR Table List of Hazardous Materials, UN#, Proper Shipping Names, PG. ANSI Z400.1, MSDS Standard, 2001. -Manufacturer's Material Safety Data Sheet. Responsible Name Date of printing : : : : : Date of issue Date of Previous Issue Version Kemika XXI Inc. +1-450-435-7475 2004-10-28. 2004-10-24. No Previous Validation. 1 Notice to Reader Continued on Next Page Masking Tape Page: 5/5 To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Page 1 of 6 Material Safety Data Sheet 24 Hour Emergency Phone Numbers: Medical: 1-800-327 -3874 1-513-558-5111 Transportation: 1-800-535-5053 1-352-323-3500 NOTE: National Response Center emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals. IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16. Section 1 - Chemical Product / Company Information This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request. Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en español a su solicitud. Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere. Product Name: Product UPC Number: Product Use/Class: Manufacturer: DAP WELDWOOD Multi-Purpose Floor Covering Adhesive 7079800144, 7079800142, 7079800141, 7079800140, 7079872054, 7079872052, 7079872049 Latex Floor Covering Adhesive Revision Date: 03/07/2005 Supercedes: 02/17/1999 MSDS Number: 00030807001 DAP Inc. 2400 Boston Street Suite 200 Baltimore, MD 21224-4723 888-327 -8477 (non-emergency matters) Section 2 - Composition / Information On Ingredients Chemical Name CASRN Kaolin 1332-58-7 Petroleum hydrocarbon oil 64742-52-5 Urea 57-13 -6 Ethylene glycol 107-21-1 Titanium dioxide 13463-67-7 4-Vinylcyclohexene 100-40-3 WT% 15-40 10-30 1-5 1-5 0.1-1.0 <0.0006 ACGIH TWA 2 MGM3 N.E. N.E. N.E. 10 MGM3 0.1 PPM ACGIH STEL N.E. N.E. N.E. N.E. N.E. N.E. ACGIH CEIL N.E. N.E. N.E. 100 MGM3 N.E. N.E. OSHA TWA N.E. N.E. N.E. N.E. 15 MGM3 N.E. OSHA STEL N.E. N.E. N.E. N.E. N.E. N.E. OSHA CEIL N.E. N.E. N.E. N.E. N.E. N.E. Skin No No No No No No Exposure Notes: Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary between states. Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work practices Section 3 - Hazards Identification Emergency Overview: A white to off-white paste with a very slight ammonia odor. WARNING! May cause irritation to the Page 2 of 6 respiratory tract. Harmful or fatal if swallowed. May cause eye, skin, nose, throat and respiratory tract irritation. This product contains ethylene glycol. Refer to other MSDS sections for other detailed information. Effects Of Overexposure - Eye Contact: May cause eye irritation. Effects Of Overexposure - Skin Contact: May cause skin irritation. Effects Of Overexposure - Inhalation: Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes). Vapors may be irritating to eyes, nose, throat, and lungs. Prolonged, repeated, or high exposures may cause weakness and depression of the central nervous system. Effects Of Overexposure - Ingestion: If ingested, may cause vomiting, diarrhea, and depressed respiration. Aspiration of material into the lungs due to vomiting can cause chemical pneumonitis, which can be fatal. Effects Of Overexposure - Chronic Hazards: Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Studies have shown that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals. Ethylene glycol has been shown to cause birth defects in laboratory animals. Prolonged or repeated contact with skin results in irritation and dermatitis. Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation Medical Conditions which May be Aggravated by Exposure: None known. Section 4 - First Aid Measures First Aid - Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately. First Aid - Skin Contact: Wash off with soap and water. First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If continued breathing difficulty is experienced, get medical attention immediately. First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately. Note to Physician: None. COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arise from any of the above routes of entry. Section 5 - Fire Fighting Measures Flash Point, F: greater than 200 degrees Fahrenheit Method: (Seta Closed Cup) Lower Explosive Limit, %: Not Established Upper Explosive Limit, %: Not Established Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam Unusual Fire And Explosion Hazards: None known. Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent) and full protective gear. Use water spray to cool exposed surfaces. Page 3 of 6 Section 6 - Accidental Release Measures Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Wet dried material before scraping up and place into containers. Section 7 - Handling And Storage Handling: Do not breathe vapors. Provide fresh air such that chemical odors cannot be detected during use and while drying. Use in well ventilated area. Construction and repair activities can adversely affect indoor air quality. Consult with occupants or a representative (i.e. maintenance, building manager, industrial hygienist, or safety officer) to determine ways to minimize impact. Wash thoroughly after handling. Do not sand, dry sweep, dry scrape, drill, saw, beadblast, mechanically chip, pulverize or otherwise machine existing resilient flooring, backing, lining felt, or asphaltic "cut -back" adhesives. These products may contain either asbestos fibers or crystalline silica. Avoid creating dust. Inhalation of such dust is a cancer and respiratory tract hazard. See current edition of the Resilient Floor Covering Institute's publication "Recommended Work Practices for Removal of Resilient Floor Coverings", for detailed information and instructions addressed to the task of removing all resilient floor covering materials. Avoid contact with eyes, skin and clothing. Storage: Store containers away from excessive heat and freezing. Keep containers tightly closed. Store away from caustics and oxidizers. Section 8 - Exposure Controls / Personal Protection Precautionary Measures: Please refer to other sections and subsections of this MSDS. Engineering Controls: Provide sufficient general and/or local exhaust ventilation to maintain exposure below recommended exposure limit. Use only in well-ventilated areas. Respiratory Protection: A respiratory protection program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Respirator use is not expected to be necessary under normal conditions of handling. In emergency situations, use of a NIOSH -approved respirator may be required. Skin Protection: Wear rubber gloves. Eye Protection: Goggles or safety glasses with side shields. Other protective equipment: None. Hygienic Practices: Although this product is not considered an eye irritant, inhalation hazard, or a skin contact hazard under normal conditions, it is advisable that personnel minimize skin contact, inhalation of vapors and eye contact. Remove and wash contaminated clothing before re-use. Section 9 - Physical And Chemical Properties Boiling Range: Odor: Appearance: Solubility in H2O: Freeze Point: Vapor Pressure: Physical State: Not Established Very Slight Ammonia White to Off-White Not Established Not Established Not Established Paste Vapor Density: Odor Threshold: Evaporation Rate: Specific Gravity: pH: Viscosity: Not Established Not Established Not Established 1.202 Between 7.0 and 12.0 Not Established When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally. Page 4 of 6 (See section 16 for abbreviation legend) Section 10 - Stability And Reactivity Conditions To Avoid: Excessive heat and freezing. Incompatibility: Strong oxidizing agents. Strong bases. Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx. Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions. Stability: Stable under normal conditions. Section 11 - Toxicological Information Product LD50: Not Established CASRN 57-13-6 107-21-1 100-40-3 Chemical Name Product LC50: Not Established LD50 Urea Ethylene glycol 4-Vinylcyclohexene Rat:8471 mg/kg Rat:4700 mg/kg 16620 mg/kg LC50 WT% ------------Rat:10876 mg/kg 4000 ppm rat 1-5 1-5 <0.0006 Carcinogenicity: CAS No. Chemical Name 13463-67 -7 Titanium dioxide 100-40-3 4-Vinylcyclohexene 14808-60 -7 Silica, crystalline ACGIH OSHA IARC NTP WT% ----- ----- Classification not possible from current data. ----- 0.1-1.0 ----- Possible carcinogen. ----- <0.0006 ----- ----- Known carcinogen. <0.00001 Confirmed animal carcinogen with unknown relevance to humans. Suspected human carcinogen. Significant Data with Possible Relevance to Humans: None Section 12 - Ecological Information Ecological Information: Ecological injuries are not known or expected under normal use. Section 13 - Disposal Information Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA Waste Code if Discarded (40 CFR Section 261): none Section 14 - Transportation Information DOT Proper Shipping Name: DOT Technical Name: DOT Hazard Class: None Packing Group: N.A. None N.A. Hazard Subclass: DOT UN/NA Number: N.A. None Page 5 of 6 Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may apply if shipped via other modes of transportation and/or to non-domestic destinations. Section 15 - Regulatory Information CERCLA - SARA Hazard Category: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: SARA Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Chemical Name Ethylene glycol CAS Number WT% 107-21-1 1-5 Toxic Substances Control Act: All ingredients in this product are either on TSCA inventory list, or otherwise exempt. This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: Chemical Name CAS Number 5-Chloro-2-methyl-4-isothazoli 2-Methyl-4-isothiazolin-3-one 26172-55 -4 2682-20-4 U.S. State Regulations: New Jersey Right-to-Know: The following materials are non-hazardous, but are among the top five components in this product: Chemical Name Water Hydrocarbon Petroleum Resin Butadiene-styrene copolymer CAS Number 7732-18 -5 Proprietary Proprietary WT% 30-60 3-7 3-7 Pennsylvania Right-to-Know: The following non-hazardous ingredients are present in the product at greater than 3%: Chemical Name Water Hydrocarbon Petroleum Resin Butadiene-styrene copolymer CAS Number 7732-18 -5 Proprietary Proprietary California Proposition 65: Warning: The following ingredients present in the product are known to the State of California to cause cancer: WT% 30-60 3-7 3-7 Page 6 of 6 Chemical Name CAS Number Definition Date Listed WT% 4-Vinylcyclohexene 100-40 -3 Carcinogenic. Listed: May 1, 1996 <0.0006 Silica, crystalline 14808-60-7 Carcinogenic. Listed: October 1, 1988 <0.00001 Warning: The following ingredients present in the product are known to the State of California to cause birth defects or other reproductive harm: None. Section 16 - Other Information HMIS Ratings: Health: 1 Flammability: 1 VOLATILE ORGANIC COMPOUNDS, GR/LTR: 34.3 Reactivity: 0 LB/GAL: 0.3 Personal Protection: X WT%: 1.557 REASON FOR REVISION: Periodic Update Legend: N.A. – Not Applicable ACGIH – American Conference of Governmental Industrial Hygienists N.E. – Not Established SARA – Superfund Amendments and Reauthorization Act of 1986 N.D. – Not Determined NJRTK – New Jersey Right-to-Know Law VOC – Volatile Organic Compound OSHA – Occupational Safety and Health Administration PEL – Permissible Exposure Limit HMIS – Hazardous Materials Identification System TLV – Threshold Limit Value NTP – National Toxicology Program STEL – Short Term Exposure Limit CEIL – Ceiling Exposure Limit LD50 – Lethal Dose 50 LC50 – Lethal Concentration 50 F – Degree Fahrenheit C – Degree Celcius MSDS – Material Safety Data Sheet CASRN – The Chemical Abstracts Service Registry Number DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context of the intended use and (ii) determine if they are appropriate. Page 1 of 7 Hoja de datos de la seguridad de los materiales Números telefónicos de emergencia las 24 horas: Emergencias médicas: 1-800-327-3874 1-513-558-5111 Transporte: 1-800-535-5053 1-352-323-3500 NOTA: Los números de emergencia del Centro de Respuesta Nacional s ólo se deben usar en caso de emergencias químicas que involucren un derramamiento, incendio, exposici ón o accidente que tengan que ver con químicos IMPORTANTE: Lea esta hoja de datos de la seguridad de los materiales antes de manipular o desechar este producto, y entregue esta información a los empleados, clientes y usuarios de este producto. Este producto está cubierto por la norma de comunicación de riesgos OSHA, y este documento fue preparado de acuerdo con los requisitos de dicha norma. Todos los términos abreviados utilizados en este documento se describen con más detalles en la sección 16. Sección 1 - Información del producto químico/ compañía Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en español a su solicitud. On peut demander cette MSDS a la langue Francaise Canadienne. Nombre de producto: Número de UPC del producto: Uso/ clase del producto: DAP WELDWOOD Multi-Purpose Floor Covering Adhesive 7079800144, 7079800142, 7079800141, 7079800140, 7079872054, 7079872052, 7079872049 Latex Floor Covering Adhesive Fabricante: DAP Inc. 2400 Boston Street Suite 200 Baltimore, MD 21224-4723 888-327-8477 (asuntos de no emergencia) Fecha de revisión: Reemplaza a: 03/07/2005 02/17/1999 Número de hoja 00030807001 de datos (MSDS): Sección 2 - Composición / Información sobre los Ingredientes Nombre Químico Caolín Destilados (Petróleo), Fracción Nafténica Pesada Tratada Con Hidrógeno Carbamida Etilen Glicol Dioxidodetitanio 4-Vinilciclohexeno CASRN 1332 -58-7 Peso% 15 -40 ACGIH TWA ACGIH STEL ACGIH CEIL 2 MGM3 N.E. N.E. 64742-52-5 10 -30 N.E. N.E. 57 -13-6 107-21-1 13463-67-7 100-40-3 1-5 1-5 0.1-1.0 <0.0006 N.E. N.E. 10 MGM3 0.1 PPM N.E. N.E. N.E. N.E. OSHA TWA N.E. OSHA STEL N.E. OSHA CEIL N.E. Piel No N.E. N.E. N.E. N.E. No N.E. 100 MGM3 N.E. N.E. N.E. N.E. 15 MGM3 N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. No No No No Notas sobre la exposición: Importante: Los niveles de exposición permitidos (PEL) señalados son suministrados por el Dept. del Trabajo de EE.UU., Límites de la norma final OSHA (CFR 29 1910.1000); Estos límites pueden variar de estado a estado. Nota: Se debe evitar o reducir al máximo la exposición de la piel de un empleado a substancias que tengan "S Í" en la columna "PIEL" en la tabla anterior, seg ún lo permitan las circunstancias mediante el uso de guantes, ropa de protecci ón, gafas de seguridad y otros equipos personales de protección, controles de ingeniería o prácticas de trabajo. Sección 3 - Identificación de riesgos Page 2 of 7 Generalidades sobre las emergencias: Un blanco a la pasta de-blanco con un olor muy leve del amoniaco. ¡ADVERTENCIA! Puede causar irritaci ón de las vías respiratorias. Dañino o fatal si se traga. Podría causar irritación de los ojos, piel, nariz, garganta y tracto respiratorio. Este producto contiene glicol de etileno. Consulte otras secciones de la hoja de datos de seguridad de los materiales para m ás información detallada. Efectos de la sobre exposición - Contacto visual: Podr ía causar irritación a los ojos. Efectos de la sobre exposición - Contacto de la piel: Podría causar irritación de la piel. Efectos de la sobre exposición - Inhalaci ón: La inhalaci ón puede causar irritación de las vías respiratorias (nariz, boca, membranas mucosas). Los vapores pueden irritar los ojos, la nariz, la garganta y los pulmones. Las exposiciones prolongadas, repetidas o elevadas pueden causar debilidad y depresi ón del sistema nervioso central. Efectos de la sobre exposición - Ingestión: Si se ingiere, podría causar vómito, diarrea y respiración deprimida. La aspiraci ón del material en los pulmones debido al vómito puede causar neumonitis química, lo que podría ser fatal. Efectos de la sobre exposición - Riesgos crónicos: El glicol de etileno puede causar daño al riñón e hígado con la sobre exposición prolongada y repetida. Los estudios han demostrado que la inhalación repetida al glicol de etileno ha producido cambios cardiovasculares adversos en los animales de laboratorio. Se ha demostrado que el glicol de etileno causa defectos de nacimiento en animales de laboratorio. El contacto prolongado o repetido con la piel resulta en irritación y dermatitis. Ruta(s) principal de entrada: Piel el Contacto, Pele la Absorción,Aspiración Condiciones m édicas que se pueden agravar a causa de la exposición: Ninguno conocido. Sección 4 - Medidas de primeros auxilios Primeros auxilios - Contacto visual: En caso de contacto, enjuague los ojos de inmediato con abundante agua por al menos 15 minutos. Obtenga atención médica de inmediato. Primeros auxilios - Contacto de la piel: Lavar con agua y jabón. Primeros auxilios - Inhalaci ón: Si se inhala, salga al aire fresco. Si se dificulta la respiración, abandone el área para obtener aire fresco. Si se experimenta dificultad continua para respirar, busque atenci ón médica de inmediato. Primeros auxilios - Ingestión: Si se traga, NO PROVOQUE EL VÓMITO. Obtenga atención médica de inmediato. Nota para el médico: Sin informaci ón COMENTARIOS: Llame para emergencias médicas al 1 -800-327-3874 si surgiera cualquier irritación o complicación de cualquiera de las rutas de entrada anteriores. Sección 5 - Medidas para combatir incendios Punto de inflamaci ón, F: Más que 200 grados Fahrenheit Método: ( Seta Cerró Copa) Límite explosivo menor, %: No Establecido Límite explosivo mayor, %: No Establecido Medios para extinguir: Bióxido de carbono, Seque Sustancia Química, Espuma Riesgos inusuales de incendio y explosi ón: Ninguno conocido. Procedimientos especiales para combatir incendios: Use un aparato para respiraci ón auto-contenida con demanda de Page 3 of 7 presi ón (aprobado por el Instituto NIOSH o equivalente) y equipo completo de protecci ón. Use rociador de agua para enfriar las superficies expuestas. Sección 6 - Medidas en caso de emisión accidental Pasos a seguir en el caso de emisión o derramamiento de materiales: Use el equipo de protección correcto según lo especifica la Secci ón 8. Moje el material seco antes de raspar y coloque en contenedores. Sección 7 - Manejo y almacenamiento Manejo: No respire los vapores. Suministre aire fresco de manera que los olores de los químicos no se puedan detectar durante el uso y mientras se seca. Usar en un área bien ventilada. Las actividades de construcci ón y de reparaciones pueden afectar de manera adversa la calidad del aire en interiores. Consulte con los ocupantes o un representante (es decir, mantenimiento, administrador de construcción, higienista industrial, u oficial de seguridad) para determinar las formas de reducir el impacto. Lave a fondo después de manipular. No lije, barra en seco, raspe en seco, perfore, asierre, pula, corte mecánicamente, pulverice o una acci ón similar los revestimientos elásticos existentes, refuerzos, fieltro de forro, o adhesivos asfálticos "cut back". Estos productos pueden contener ya sea fibras de asbestos o sílice cristalino. Evite crear polvo. La inhalación de este polvo es un riesgo de cáncer y de infección del tracto respiratorio. Consulte la edici ón actual de la publicaci ón del Instituto Resilient Floor Covering: “Pr ácticas de trabajo recomendadas para retirar los revestimientos elásticos", para informaci ón e instrucciones detalladas para la tarea de retirar todos los materiales de revestimiento elástico. Evite el contacto con los ojos, la piel y la ropa. Almacenamiento: Almacene los contenedores lejos del calor y congelamiento excesivos. Manténgase el recipiente bien cerrado. Almacene lejos de substancias cáusticas y oxidantes. Sección 8 - Controles de la exposición/ Protección personal Medidas de precaución: Refiérase por favor a otras secciones y subdivisiones de este MSDS. Controles de ingeniería: Ofrezca ventilación de escape general y/o local suficiente para mantener la exposición debajo del límite recomendado. Utilícese solo en zonas bien ventiladas. Protecci ón respiratoria: Se debe seguir un programa de protecci ón respiratoria que cumpla con los requisitos de OSHA 1910.134 y ANSI Z88.2 cada vez que las condiciones del lugar de trabajo exijan el uso de un respirador. No es de esperar que sea necesario usar un aparato de respiraci ón bajo condiciones normales de manejo. En situaciones de emergencia, puede que se requiera el uso de un aparato de respiraci ón aprobado por el NIOSH. Protecci ón de la piel: Usar guantes de goma. Protecci ón de la visión: Gafas de seguridad con protectores laterales. Otro equipo de protección: Ninguno. Prácticas higiénicas: No obstante este producto no se considera un irritante para los ojos, riesgo de inhalación o riesgo de contacto con la piel bajo condiciones normales, se recomienda que el personal reduzca el contacto con la piel, la inhalación de vapores y el contacto con los ojos. Quitar y lavar la ropa contaminada antes de reutilizar. Sección 9 - Propiedades físicas y químicas Rango de ebullición: No Establecido Densidad del vapor: No Establecido Page 4 of 7 Olor: Amoniaco muy Leve Umbral de olor: No Establecido Aspecto: Blanco a De-Blanco Índice de evaporación: No Establecido Solubilidad en H2O: No Establecido Gravedad específica: 1.202 Punto de congelamiento: No Establecido pH: Entre 7,0 y 12,0 Presi ón del vapor: No Establecido Viscosidad: No Establecido Estado físico: Pasta (Ver sección 16 para la leyenda de las abreviaturas) Sección 10 - Estabilidad y reactividad Condiciones a evitar: Calentamiento y congelamiento excesivos. Incompatibilidad: agentes oxidantes fuertes bases fuertes Productos de descomposición peligrosa: Productos de descomposición normal, es decir, COx, NOx. Polimerización peligrosa: No ocurrirá polimerización peligrosa bajo condiciones normales. Estabilidad: Estable en condiciones normales Sección 11 - Información toxicológica LD50 del producto: No Establecido CASRN Nombre Químico 57-13-6 107-21-1 100-40-3 LC50 del producto: No Establecido LD50 LC50 Carbamida Etilen Glicol 4-Vinilciclohexeno Rat:8471 mg/kg Rat:4700 mg/kg 16620 mg/kg ------------Rat:10876 mg/kg 4000 ppm rat Peso% 1-5 1-5 <0.0006 Carcinogenicidad: Número CAS Nombre Químico 13463-67 -7 Dioxidodetitanio 100-40-3 4-Vinilciclohexeno 14808-60 -7 Silicecristalina ACGIH OSHA IARC NTP Peso% ----- ----- Clasificación no posible de datos actuales. ----- 0.1-1.0 ----- Cancerígeno posible. ----- <0.0006 ----- ----- Cancerígeno conocido. <0.00001 Cancerígeno animal confirmado con la aplicabilidad desconocida a humanos. Cancerígeno humano sospechado. Datos significativos con posible relevancia para los humanos: Ninguno Sección 12 - Información ecológica Información ecológica: No se conocen ni esperan daños ecológicos bajo uso normal. Sección 13 - Información sobre desechos Información sobre desechos: Deseche los materiales de acuerdo con todas las normas federales, estatales y locales. Las normas/ restricciones estatales y locales son complejas y pueden diferir de las normas federales. La responsabilidad de eliminar los desechos correctamente recae en el propietario de los desechos. Page 5 of 7 Código de desechos de EPA en caso de desecho (CFR 40 Sección 261): Ninguno Sección 14 - Información sobre transporte Nombre correcto para envío a DOT: Nombre técnico para DOT: Clase de riesgo para DOT: Ninguno Grupo de empaque: No Aplicable Ninguno No Aplicable Sub-clase de riesgo: Número UN/NA para DOT: No Aplicable Ninguno Nota: La información del envío proporcionada es aplicable para el transporte doméstico del suelo sólo. Categorizaci ón diferente puede aplicar si enviado vía otros modos del transporte y/o a destino no-domésticos. Sección 15 - Información reglamentaria Categoría de riesgo CERCLA - SARA: Este producto ha sido revisado según las categorías de riesgo de EPA promulgadas según las secciones 311 y 312 de la Ley de enmienda y reautorización de fondos especiales de 1986 (SARA, por sus iniciales en inglés, Título III) y se considera, según las definiciones correspondientes, que cumple con las siguientes categorías: Sección 313 de la ley SARA: Este producto contiene las siguientes substancias sujeto a los requisitos de reporte de la sección 313 del título III de la ley SARA de 1986 y 40 CFR parte 372: Nombre Químico Etilen Glicol Número CAS Peso% 107-21-1 1-5 Ley para el control de substancias tóxicas: Todos ingredientes en este producto son o en lista de inventario de TSCA, o de otro modo exima. Este producto contiene las siguientes substancias químicas de acuerdo con los requisitos de reporte de la ley TSCA 12(B) si es exportado desde los Estados Unidos: Nombre Químico Número CAS 5-Chloro-2-Methyl-4-Isothazoli 2-Methyl-4-Isothiazolin-3-One 26172-55 -4 2682-20-4 Regulaciones estatales de EE.UU.: Ley del Derecho a saberde New Jersey: Los siguientes materiales no representan peligro, pero están entre los primeros cinco componentes de este producto: Nombre Químico Agua Hydrocarbon Petroleum Resin Copolymer De Estireno De Butadiene Número CAS 7732-18 -5 Propietario Propietario Peso% 30-60 3-7 3-7 Ley del Derecho a saber de Pennsylvania: Los siguientes ingredientes no peligrosos están presentes en el producto en una proporción mayor a 3%: Nombre Químico Número CAS Peso% Page 6 of 7 Agua Hydrocarbon Petroleum Resin Copolymer De Estireno De Butadiene 7732 -18-5 Propietario Propietario 30-60 3-7 3-7 Propuesta 65 de California: Advertencia: Los siguientes ingredientes presentes en el producto son conocidos para el Estado de California por causar cáncer: Nombre Químico 4-Vinilciclohexeno Ester Etilico Del Acido 2 -Propenoico Silicecristalina Número CAS 100-40 -3 140-88 -5 14808-60-7 Definición Fecha Listó Peso% Cancerígeno. Cancerígeno. Cancerígeno. Listed: May 1, 1996 Listed: July 1, 1989 Listed: October 1, 1988 <0.0006 <0.0001 <0.00001 Advertencia: Los siguientes ingredientes presentes en el producto son conocidos para el Estado de California por causar defectos de nacimiento u otros daños reproductivos: Ninguno. Sección 16 - Otra información Índices HMIS: Salud: 1 Inflamabilidad: 1 Reactividad: 0 COMPONENTES ORGÁNICOS VOLÁTILES, GR/LTR: 34.3 LB/GAL: 0.3 Protecci ón personal: X WT%: 1.557 RAZÓN DE LA REVISIÓN: Periódico Actualiza Leyenda: N.A. - No aplica ACGIH - Conferencia Americana de Higienistas Industriales gubernamentales N.E. - No establecido SARA - Ley Ley de enmienda y reautorizaci ón de fondos especiales de 1986 (SARA) N.D. - No determinado NJRTK - Ley del Derecho a saber de New Jersey VOC - Componente orgánico volátil OSHA - Administración de la seguridad y salud ocupacional PEL - Límites permitidos de exposición C - Grados centígrados TLV - Valor del límite umbral NTP - Programa nacional de toxicología STEL - Límite de exposición a corto plazo CEIL - Límite máximo de exposici ón LD50 - Dosis letal 50 LC50 - Concentración letal 50 HMIS - Sistema de identificación de materiales peligrosos MSDS - Hoja de datos de la seguridad de los materiales CASRN - Número de registro de servicios de abstractos químicos F - Grados Fahrenheit DAP cree que los datos y las declaraciones contenidos en el presente son exactos hasta la fecha. Se ofrecen de buena fe como valores típicos y no como las especificaciones del producto. NO SE OFRECE NINGUNA GARANT ÍA DE COMERCIABILIDAD, IDONEIDAD PARA UN PROPÓSITO EN PARTICULAR O CUALQUIER OTRA GARANTÍA, EXPRESA O IMPLÍCITA, CON RESPECTO A LA INFORMACIÓN SUMINISTRADA EN EL PRESENTE O DEL PRODUCTO AL CUAL LA INFORMACIÓN SE REFIERE. Dado que este documento tiene la intención de ser una guía únicamente para el uso correcto y el manejo preventivo del producto de la referencia por parte de personas correctamente entrenadas, es responsabilidad del usuario (i) revisar las recomendaciones con especial consideración al contexto específico del uso que se pretende y (ii) determinar si son correctas. Page 7 of 7 Page 1 of 7 Fiche signalétique 24 heures – Numéros de téléphone en cas d’urgence: Urgence médicale: 1-800-327 -3874 1-513-558 -5111 Urgence transport: 1-800-535 -5053 1-352-323 -3500 NOTE: Les numéros de téléphone en cas d’urgence doivent être utilisés uniquement lors de déversement, de fuite, d’incendie, d’exposition ou d’accident impliquant des produits chimiques. IMPORTANT: Lire attentivement cette fiche signalétique avant de manipuler ou de disposer de ce produit. Remettre ces informations aux employés, clients et utilisateurs de ce produit. Ce produit est régit sous la gouverne de l’OSHA, Communication de renseignements à l’égard de matières dangereuses, et ce document a été préparé pour répondre aux exigences de ces standards. Les significations pour toutes les abréviations utilisées dans cette fiche signalétique sont décrites à la Section 16. Section 1 – Identification du produit et de la compagnie This MSDS is offered in English upon request. Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere. Nom du produit: Numéro UPC: Utilisation du produit/Classe: Fabricant: DAP WELDWOOD Multi-Purpose Floor Covering Adhesive 7079800144, 7079800142, 7079800141, 7079800140, 7079872054, 7079872052, 7079872049 Latex Floor Covering Adhesive Date de r évision: 03/07/2005 Date 02/17/1999 d’abrogation: Numéro de fiche: 00030807001 DAP Inc. 2400 Boston Street Suite 200 Baltimore, MD 21224-4723 888-327 -8477 ( Pour toute information non urgente) Section 2 - Composition / Ingrédients dangereux Nom Chimique Kaolin Distillat naphténique lourd hydrotraité Urée Éthylène glycol Dioxyde de titane 4-Vinylcyclohexne CASRN 1332 -58-7 64742-52-5 57-13-6 107-21 -1 13463-67-7 100-40 -3 Poids% 15-40 10-30 1-5 1-5 0.1-1.0 <0.0006 ACGIH TWA ACGIH STEL ACGIH CEIL 2 MGM3 N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. 100 MGM3 10 MGM3 N.E. N.E. 0.1 PPM N.E. N.E. OSHA TWA N.E. N.E. N.E. N.E. 15 MGM3 N.E. OSHA STEL N.E. N.E. N.E. N.E. N.E. N.E. OSHA CEIL Peau N.E. Non N.E. Non N.E. Non N.E. Non N.E. Non N.E. Non Notes concernant l’exposition: Important: Les limites d’exposition permises (LEP) décrites proviennent du Department of Labor des États-Unis, règlement final concernant les valeurs d’exposition moyennes pondérées de l’OSHA (CFR 29 1910.1000); ces limites peuvent varier selon les états. Note: Prendre tous les moyens selon les circonstances afin de prévenir ou réduire toute exposition de la peau des employés aux substances portant la mention «OUI» dans la colonne «PEAU» du tableau ci-dessus. Utiliser des gants, une combinaison, des lunettes étanches, tout autre équipement de protection personnel adéquat, les contrôles techniques et les pratiques appropriées au type de travail. Section 3 – Identification des dangers Page 2 of 7 Urgences générales: Un blanc à la pâte de-blanc avec une odeur d'ammoniaque tr ès insignifiante. AVERTISSEMENT ! Peut provoquer une irritation des voies respiratoires. Nocif ou mortel si ingéré. Peut causer une irritation des yeux, de la peau, du nez, de la gorge et des voies respiratoires. Ce produit contient du glycol d'éthyl ène. Consulter les autres sections de cette fiche signalétique pour des informations plus détaillées. Effets de surexposition – Contact oculaire: Peut causer une irritation des yeux. Effets de surexposition – Contact cutané: Peut causer une irritation de la peau. Effets de surexposition – Inhalation: L'inhalation de ce produit peut provoquer l'irritation des voies respiratoires (nez, bouche, muqueuses). Les vapeurs peuvent être irritantes pour les yeux, le nez, la gorge et les poumons. L'exposition prolongée, ou répétée, ou à de fortes concentrations peut provoquer un affaiblissement et une dépression du système nerveux central. Effets de surexposition – Ingestion: En cas d’ingestion, peut causer des vomissements, de la diarrhée et une diminution de la capacité pulmonaire. L’aspiration de mat ériau dans les poumons lors de vomissements peut causer une pneumonie chimique qui peut être mortelle. Effets de surexposition – Dangers chroniques: Une exposition excessive et répétée à l’éthyl ène glycol peut causer des lésions aux reins et au foie. Les études en laboratoire menées sur des animaux ont démontré que l’inhalation r épétée d’éthyl ène glycol cause des changements néfastes du syst ème cardiovasculaire. Lors d’études en laboratoire sur les animaux, il a été démontré que l ’éthyl ène glycol cause des anomalies congénitales. Un contact excessif et répété avec la peau peut causer une irritation ou une dermatite. Voie(s) d’absorption: Peau le Contact, L'Absorption de peau, l'Inhalation Problèmes médicaux aggravés lors d’exposition au produit : Aucune connue. Section 4 – Premiers soins Premiers soins – Contact oculaire: En cas de contact avec les yeux, rincer abondamment avec de l ’eau pendant au moins 15 minutes. Obtenir des soins médicaux immédiatement. Premiers soins – Contact cutané: Laver avec de l'eau et du savon. Premiers soins – Inhalation: En cas d’inhalation, transporter la personne exposée à l’air frais. Si elle a de la difficulté à respirer, quitter les lieux afin d’obtenir de l’air frais. Si la difficulté à respirer persiste, obtenir des soins médicaux immédiatement. Premiers soins – Ingestion: En cas d’ingestion, NE PAS FAIRE VOMIR. Obtenir des soins m édicaux immédiatement. Note au médecin: Pas d'information. COMMENTAIRES: En cas d’apparition d’une irritation ou de complications suite à une exposition au produit, communiquer immédiatement avec l’urgence m édicale au 1-800-327-3874. Section 5 – Mesures de protection en cas d’incendie Point d’éclair, º F ( º C ): Plus grand que 200 degrés Fahrenheit Méthode: ( Seta A Fermé la Tasse) Limite d ’explosibilité inférieure, %: Pas Etabli Limite d ’explosibilité supérieure, %: Pas Etabli Moyens d’extinction: Dioxyde de carbone, Sécher Chimique, Mousse Page 3 of 7 Risques particuliers d’explosions ou d’ignition: Aucun connu. Procédures spéciales de lutte contre les incendies: Porter un respirateur autonome à pression d’air (approuvé NIOSH ou équivalent) et un équipement de protection personnel complet. Utiliser une lance-brouillard afin de refroidir les contenants expos és. Section 6 – Mesures en cas de déversement accidentel Procédures de nettoyage: Porter un équipement de protection personnel approprié tel que spécifié à la Section 8. Humidifier le matériau sec avant de le gratter puis disposer dans un contenant. Section 7 – Manutention et entreposage Manutention: Éviter de respirer les vapeurs. Assurer l’entrée d’air frais de façon à éliminer les odeurs des produits chimiques pendant l ’utilisation et le temps de séchage. Utilisez dans un espace bien aéré. Les activités de construction et de réparation peuvent affecter la qualité de l’air à l’intérieur. Vérifier avec les occupants ou un de leurs représentants (responsable de maintenance, gérant d’édifice, hygiéniste industriel ou responsable de sécurité) afin de déterminer les façons appropriées pour en diminuer l’impact. Laver vigoureusement après la manipulation. Ne pas poncer, balayer à sec, gratter à sec, percer, scier, utiliser un jet à billes, buriner et pulvériser mécaniquement ou à l’aide de tout autre outil les couvre-planchers élastiques, les supports, les blindages ou les adhésifs d’asphalte dilué existants. Ces produits peuvent contenir de l’amiante ou de la silice cristalline. Éviter de générer de la poussière. Éviter d’inhaler cette poussi ère, elle est canc érigène et dangereuse pour les voies respiratoires. Pour de plus amples informations concernant les pratiques d’enlèvement complet des couvre-planchers élastiques, consulter la r écente édition du bulletin du Resilient Floor Covering Institute; "Le Travail recommand é Pratique pour l'Enlèvement de Couvertures de Plancher Elastiques". Éviter tout contact avec les yeux, la peau et les vêtements. Entreposage: Entreposer les contenants loin de la chaleur excessive ou du froid excessif. Conserver le récipient bien fermé. Entreposer loin des produits caustiques et des agents oxydants. Section 8 – Contrôles d’exposition / Protection personnelle Mesures de précaution: S'il vous plaît se référer aux autres sections et aux autres sous -sections de ce MSDS. Contrôles d’ingénierie: Faire fonctionner au maximum le système de ventilation central et/ou le système d’évacuation local afin de maintenir le niveau des vapeurs organiques sous les limites d’exposition recommandées. Utiliser seulement dans des zones bien ventilées. Protection des voies respiratoires: Un programme de protection respiratoire défini selon les normes de l ’OSHA 1910.134 et de l’ANSI Z88.2 doit être appliqué à chaque fois que les conditions sur les lieux de travail exigent de porter un respirateur. On ne s'attend pas à ce qu'un masque soit nécessaire dans les conditions normales de manipulation. En cas de situation d'urgence, un masque de type agréé par NIOSH peut être nécessaire. Protection de la peau: Portez des gants en caoutchouc. Protection des yeux: Lunettes étanches ou lunettes de s écurité avec boucliers latéraux. Équipements de protection additionnels: Aucun. Pratiques hygiéniques: Dans des conditions normales d’utilisation, même si ce produit n’est pas considéré ni un irritant pour les yeux, ni un danger en cas d’inhalation ou de contact avec la peau, il est recommandé que le personnel minimise les risques de contact avec les yeux et la peau et évite d’inhaler les vapeurs. Enlever et laver les vêtements contaminés avant réutilisation. Page 4 of 7 Section 9 – Propriétés physiques et chimiques Point d’ébullition: Odeur: Pas Etabli L'Ammoniaque très Insignifiante Apparence: Blanc à De-Blanc Solubilité dans l’eau (H2O): Point de congélation: Pression de vapeur: État physique: Pas Etabli Pas Etabli Pas Etabli Pâte Densité de vapeur: Limite de détection olfactive: Taux d ’évaporation: Poids spécifique: Pas Etabli Pas Etabli Taux de pH: Viscosité: Entre 7,0 et 12,0 Pas Etabli Pas Etabli 1.202 (Consulter la Section 16 pour conna ître la signification des abréviations)) Section 10 – Stabilité et réactivité Conditions à éviter: Chaleur excessive ou froid excessif. Incompatibilité: des oxydants forts des bases fortes Produits de décomposition dangereux: Produits de d écomposition habituels : oxydes de carbone (COx) et oxydes d’azote (NOx). Risque de polym érisation: Aucune polymérisation dangereuse ne surviendra dans des conditions normales d’utilisation. Stabilité: Stable dans des conditions normales Section 11 – Propriétés toxicologiques Produit DL50: Pas Etabli CASRN 57-13-6 107-21-1 100-40-3 Nom Chimique Produit CL50: Pas Etabli LD50 Urée Éthylène glycol 4-Vinylcyclohexne Rat:8471 mg/kg Rat:4700 mg/kg 16620 mg/kg LC50 Poids% ------------Rat:10876 mg/kg 4000 ppm rat 1-5 1-5 <0.0006 Effets cancérig ènes: Numéro CAS Nom Chimique 13463-67 -7 Dioxyde de titane 100-40-3 4-Vinylcyclohexne 14808-60 -7 Silice cristalline ACGIH OSHA IARC NTP Poids% ----- ----- Classification pas possible des données actuelles. ----- 0.1-1.0 ----- Cancérog ène possible. ----- <0.0006 ----- ----- Cancérogène connue. <0.00001 Confirmée canc érog ène animale avec le pertinence inconnu aux humains. Présumée cancérogène humaine. Données significatives possiblement pertinentes à l’humain: Aucun Section 12 – Information écologique Information écologique: Aucune dégradation de l'environnement n'est connue ou prévisible dans les conditions normales d'utilisation. Page 5 of 7 Section 13 – Information sur la mise au rebut Information concernant la mise au rebut: Disposer de ce matériau en respectant les lois fédérales, provinciales et municipales. Les lois et restrictions provinciales et municipales sont complexes et peuvent différer des lois f édérales. La responsabilité de la disposition appropriée des déchets appartient au propriétaire des déchets. Code de mise au rebut de l ’Agence de protection de l’environnement (40 CFR Section 261): Aucun Section 14 – Étiquetage selon le Ministère des Transports Nom du produit expédié: Nom technique: Classe de danger: Aucun Aucun Pas Applicable Groupe d’emballage: Classe de transport: Numéro UN/NA: Pas Applicable Pas Applicable Aucun Note : L'information d'expédition fournie est applicable pour le transport de sol domestique seulement. La catégorisation différente peut s'appliquer si exp édié via les autres modes de et/ou de transport aux destinations non résidentielles. Section 15 – Information sur les règlements CERCLA - Catégories de dangers selon le SARA: Ce produit a été revu en conformité avec les «Catégories de dangers» établies par l’Agence de protection de l’environnement et promulguées aux Sections 311 et 312 du Superfund Amendment and Reauthorization Act de 1986 (SARA Titre III). Selon les définitions applicables, il est considéré répondre aux cat égories suivantes : SARA SECTION 313 : Ce produit contient les substances suivantes assujetties aux normes de déclaration de la Section 313, du Titre III de la Superfund Amendments and Reauthorization Act de 1986 et du 40 CFR partie 372 : Nom Chimique Éthylène glycol Numéro CAS 107-21-1 Poids% 1-5 LOI SUR LE CONTRÔLE DES SUBSTANCES TOXIQUES: Tous ingrédients dans ce produit sont ou sur la liste d'inventaire de TSCA, ou autrement exempter. Ce produit contient les substances chimiques suivantes à déclarer selon les normes TSCA 12(B) si export é à l’extérieur des États-Unis: Nom Chimique Numéro CAS 5-Chloro-2-Methyl-4-Isothazoli 2-Methyl-4-Isothiazolin-3-One 26172-55 -4 2682-20-4 Lois particulières selon les états aux États-Unis: NEW JERSEY RIGHT-TO-KNOW : Les substances suivantes sont non-dangereuses mais sont comptées parmi les 5 principaux ingrédients composant ce produit: Nom Chimique Eau Hydrocarbon Petroleum Resin Copolymère de styrène et de butadiène Numéro CAS 7732-18 -5 De propriété De propriété Poids% 30-60 3-7 3-7 Page 6 of 7 PENSYLVANIA RIGHT-TO-KNOW: Les substances suivantes sont non-dangereuses mais sont présentes à plus de 3% dans ce produit: Nom Chimique Numéro CAS Eau Hydrocarbon Petroleum Resin Copolymère de styrène et de butadiène Poids% 7732-18 -5 De propriété De propriété 30-60 3-7 3-7 PROPOSITION 65 DE CALIFORNIE: AVERTISSEMENT ! Les produits chimiques list és ci-dessous et contenus dans ce produit sont reconnus par l’État de la Californie pour causer le cancer: Nom Chimique Numéro CAS Définition Dater Enuméré Poids% 4-Vinylcyclohexne Silice cristalline 100-40 -3 14808-60-7 Cancérog ène. Cancérog ène. Listed: May 1, 1996 Listed: October 1, 1988 <0.0006 <0.00001 AVERTISSEMENT ! Les produits chimiques list és ci-dessous et contenus dans ce produit sont reconnus par l’État de la Californie pour causer le cancer, des anomalies congénitales ou d’autres problèmes reliés à la reproduction: Aucun. Section 16 – Autres informations Classification des dangers: Santé: 1 Inflammabilité: 1 COMPOSÉ ORGANIQUE VOLATIL, G/LITRE: 34.3 Réactivité: 0 LB/GALLON: 0.3 Protection personnelle: X POIDS %: 1.557 RAISONS DE RÉVISION: Mise à jour p ériodique Légende: N.A. – Non applicable ACGIH – American Conference of Governmental Industrial Hygienists N.É. – Non établi SARA – Superfund Amendments and Reauthorization Act de 1986 N.D. – Non déterminé NJRTK – New Jersey Right-to-Know Law VOC – Composé organique volatil OSHA – Occupational Safety and Health Administration PEL – Limite d’exposition permise HMIS – Hazardous Materials Identification System TLV – Limite tolérable d’exposition TWA – Valeur d’exposition moyenne pondérée NTP – National Toxicology Program F – Degré Fahrenheit STEL – Limite d’exposition à court terme C – Degré Celcius LD50 – Dose létale 50 LC50 – Concentration létale 50 CASRN – Numéro enregistré selon le Chemical Abstracts Service CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act DAP croit que les données et renseignements stipulés dans cette fiche signal étique sont précis à la date de rédaction de cette fiche. Ces données sont offertes en toute bonne foi et représente des valeurs standard sans toutefois être des sp écifications du produit. AUCUNE GARANTIE SUR LA QUALITÉ MARCHANDE, GARANTIE D’APTITUDE POUR AUCUN TYPE D’EMPLOI PARTICULIER OU TOUTE AUTRE FORME DE GARANTIE N’EST EXPRESSÉMENT OU IMPLICITEMENT OFFERTE EN REGARD DES INFORMATIONS FOURNIES DANS CETTE FICHE OU DES INFORMATIONS RELATIVES AU PRODUIT. Cette fiche est produite uniquement à titre de guide pour les personnes form ées à cet effet afin qu’elles puissent appliquer les procédures appropriées de manutention auxquelles le produit réfère. Toutefois, c’est la responsabilité chaque utilisateur de revoir les recommandations selon le contexte spécifique de l’utilisation prévue et de déterminer si ces proc édures sont appropriées. Page 7 of 7 MATERIAL SAFETY DATA SHEET PRODUCT NAME: Roberts 7032 Cove Base Adhesive Roberts MSDS Code #: 7032C PRODUCT USES: For installing vinyl and rubber cove base W.H.M.I.S. CLASSIFICATION: NON-CONTOLLED V.O.C. CONTENT: 88g/L SECTION I - MANUFACTURER IDENTIFICATION MANUFACTURER'S NAME: ROBERTS COMPANY CANADA LTD. ADDRESS: 2070 Steeles Ave. Bramalea, Ontario L6T 1A7 24 HOUR (CANUTEC) PHONE: (613) 996-6666 DATE REVISED: December 01/06 SECTION II - HAZARDOUS INGREDIENTS INFORMATION COMPONENT APPROX. % MINERAL SPIRITS 5-10 UN# 1256 SECTION III – PHYSICAL DATA BOILING POINT: 100° C FREEZING POINT: N/A VAPOUR DENSITY (AIR=1): 4-5 VAPOUR PRESSURE (MM OF MERCURY): Min. spirits 2 @ 20ºC SOLUBILITY IN WATER: Miscible APPEARANCE AND ODOUR: White, soft buttery paste, mild solvent odour. NAME OF PREPARER: Technical Dept. INFORMATION PHONE: (905) 791-4444 SOURCES USED: Raw material supplier M.S.D.S. CAS# 8052-41-3 LD50 LC50 1,400 PPM 8HR., RAT SPECIFIC GRAVITY (H20=1): 1.17 pH: 9.5 – 10.5 EVAPORATION RATE (BUTYL ACETATE=1): Slower EVAPORATION RATE (ETHYL ACETATE=1): Slower PERCENT VOLATILE: 46 ODOUR THRESHOLD (PPM): Not available SECTION IV - FIRE AND EXPLOSION DATA FLASHPOINT (specify method): Over 200ºF METHOD USED: P.M.C.C. IMPACT SENSITIVITY: Insensitive FLAMMABLE LIMITS (% BY VOLUME): LOWER: 0.8-0.9 UPPER: 7 SENSITIVITY TO STATIC DISCHARGE: Vapours may be FIRE EXTINGUISHING MEDIA: Foam, CO2, Dry Chemical AUTO IGNITION TEMP: N/A TDG FLAMMABILITY CLASSIFICATION: Not regulated. SPECIAL FIRE-FIGHTING PROCEDURES: Poses minimal fire hazard. Must be heated substantially. Self-contained breathing apparatus should be worn for fires involving this product. UNUSUAL FIRE AND EXPLOSION HAZARDS: Flammable vapours, heavier than air, may be able to collect in confined spaces and pose a hazard. SECTION V - REACTIVITY DATA STABILITY: Stable INCOMPATIBILITY (Materials to avoid): Strong oxidizing agents HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO2, and Hydrocarbons upon combustion. HAZARDOUS POLYMERIZATION: Will not occur SECTION VI – TOXICOLOGICAL PROPERTIES SKIN CONTACT X SKIN ABSORPTION CONDITIONS TO AVOID: Excessive Heat CONDITIONS TO AVOID: None ENTRY ROUTE TABLE EYE CONTACT X INHALATION ACUTE X INHALATION CHRONIC INGESTION X EFFECTS OF ACUTE EXPOSURE TO MATERIAL: Overexposure to vapours can cause eye, nose, throat irritation, dizziness, drowsiness, headache feelings of drunkenness, nausea, vomiting. Massive overexposure can cause respiratory failure. Ingestion causes similar symptoms. Aspiration causes severe pneumonitis. Product is eye and skin irritant. EFFECTS OF CHRONIC EXPOSURE TO MATERIAL: Prolonged or repeated contact with skin may cause drying and defatting of skin and dermatitis. Although unlikely to occur, overexposure to vapours may cause corneal damage, photophobia. In rare cases, severe overexposure may sensitize heart muscles causing heart arrhythmia. LD50 (SPECIFY SPECIES & ROUTE): Not available SENSITIZING CAPACITY: May sensitize heart muscles. See above. LC50 (SPECIFY SPECIES): Not available CARCINOGENICITY: None EXPOSURE LIMIT: TLV-TWA, PPM MINERAL SPIRITS, 100 REPRODUCTIVITY EFFECTS: None known IRRITANCY: Eye, nose, throat and skin irritant SYNERGISTIC MATERIALS: None known SECTION VII – PREVENTATIVE MEASURES RESPIRATORY PROTECTION (SPECIFY TYPE): Not required under normal conditions of use. If TLV is to be exceeded, employ an approved NIOSH/MSHA chemical cartridge respirator with organic vapour cartridge. Consult your safety equipment supplier for respirator requirements. VENTILATION: General dilution ventilation to keep vapours below TLV. PROTECTIVE GLOVES: Solvent resistant gloves should be worn. EYE PROTECTION: Goggles / glasses with side shields OTHER PROTECTIVE EQUIPMENT: None required. SPILL PROCEDURES: Provide adequate ventilation. Mechanically collect. Wash area with water. Prevent from entering sewers or waterways. Spilled material may cause slippery conditions. Promptly report significant spills to appropriate authorities. Consult local regulations. WASTE DISPOSAL METHOD: Destroy by incineration at an approved facility. Dried material only may be landfilled. Consult local regulations. STORAGE & HANDLING PRECAUTIONS: Store in ventilated area as close to 70ºF as possible. OTHER PRECAUTIONS: Keep containers closed when not in use. Keep out of reach of children. SECTION VIII – FIRST AID MEASURES INHALATION: EYES: SKIN: INGESTION: Remove to fresh air. If not breathing, trained personnel should administer artificial respiration. Obtain medical attention immediately. Flush with water for 20 minutes holding eyelids open. Obtain medical attention immediately. Wash with soap and water. Remove dried adhesive with mineral spirits followed by soap and water. Remove contaminated clothing and launder before re-use. Consult physician if irritation develops. Do not induce vomiting. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Contact physician immediately. Henry 314 Multipurpose Ceramic Tile Adhesive Page 1 of 5 SECTION 1 - PRODUCT IDENTIFICATION MATERIAL SAFETY DATA SHEET Manufacturer/Supplier identifier: Use in case of emergency only: CHEM-TEL – 1-800-255-3924 OR 1-813-248-0585 (call collect) ® The W.W. Henry Company 400 Ardex Park Drive Aliquippa, PA 15001 U.S.A. Tel: (724) 203-8499 Visit our Website: http://www.wwhenry.com Product identifier/Trade name: HMIS Hazard Index: Henry 314 Multipurpose Ceramic Tile Adhesive HEALTH = 1 FLAMMABILITY = 1 REACTIVITY = 0 4 = Severe 3 = Serious 2 = Moderate 1 = Slight 0 = Minimal WHMIS Classification: D2B – Toxic material with other effects CHEMICAL NAME CHEMICAL FAMILY CHEMICAL FORMULA Not Applicable Not Applicable Not Applicable TRADE NAME AND SYNONYMS MOLECULAR WEIGHT MATERIAL USE Henry® 314 Not Applicable Filled water-based adhesive SECTION 2 - CHEMICAL COMPOSITION / HAZARDOUS INGREDIENTS Hazardous Ingredients Stoddard solvent C.A.S. Numbers % (weight) 8052-41-3 5-10 OSHA PEL TWA STEL 100 ppm N/Av ACGIH TLV TWA STEL 100 ppm N/Av This material is classified as hazardous under OSHA regulations (29CFR 1910.1200). SECTION 3 - HAZARDS IDENTIFICATION Emergency Overview IRRITANT. White paste with mild hydrocarbon odor. May cause a moderate skin irritation. Vapours or mist may cause mild respiratory tracts irritations and central nervous system (CNS) effects, such as headache, dizziness, intellectual impairment and fatigue. May cause minor to moderate irritation to eyes. POTENTIAL HEALTH EFFECTS: Primary entry route(s): Skin, eye, ingestion and inhalation. Target organs: None Effects of short-term (acute) exposure: Inhalation: Vapours or mist may cause mild irritations and central nervous system (CNS) effects, such as headache, dizziness, intellectual impairment and fatigue. Skin: May cause a moderate skin irritation. Prolonged contact may cause drying and cracking of the skin and moderate irritations. Eye: May cause minor to moderate irritation to eyes. Ingestion: None expected. May cause nausea, and irritation to the mouth and digestive tract if ingested in large amounts. Effects of long-term (chronic) exposure: None expected. Conditions aggravated by exposure: Carcinogenic status: Skin conditions. See TOXICOLOGICAL INFORMATION, Section 11. Additional health hazards: Potential environmental effects: For further information, see TOXICOLOGICAL INFORMATION, See ECOLOGICAL INFORMATION (Section 12). Henry 314 Multipurpose Ceramic Tile Adhesive Page 2 of 5 Section 11. SECTION 4 - FIRST AID MEASURES Inhalation: In case of exposure to excessive quantities of dusts/vapours, remove victim to fresh air. Seek medical attention if symptoms persist. Skin contact: flush skin thoroughly with lukewarm water for at least 20 minutes. Under running water, remove contaminated clothing. Call a physician if irritation persists. Eye contact: Flush eyes thoroughly with lukewarm water for at least 20 minutes while holding the eyelid(s) open. Consult a physician if pain, irritation or vision problems persist after treatment. Ingestion: Do not induce vomiting. Never give anything by mouth if patient is unconscious. Seek medical attention if symptoms develop. SECTION 5 - FIRE FIGHTING MEASURES Fire hazards/conditions of flammability: Product is not flammable under normal conditions. Flammability classification (OSHA 29 CFR 1910.1200): Non-flammable. Flash point (Method): > 93.3oC / > 200oF (Setaflash Closed Tester) Lower flammable limit (% by volume): Upper flammable limit (% by volume): Not applicable Not applicable Auto-ignition temperature: Hazardous combustion products: N/Av Carbon monoxide, carbon dioxide, and other toxic vapors and gases that are common to thermal degradation or organic compounds. Sensitivity to mechanical impact: Sensitivity to static discharge: N/Av N/Av Suitable extinguishing media: Carbon dioxide, dry chemical powder, appropriate foam or water fog. Special fire-fighting procedures/equipment: Firefighters should wear proper chemically protective equipment and self-contained breathing apparatus. Move containers from fire area if it can be done without risk. Closed containers may explode with the pressure building from the heat. Use water to cool fire exposed containers. After fires have been extinguished, carefully clean all equipment and surfaces exposed to fumes. SECTION 6 - ACCIDENTAL RELEASE MEASURES Personal precautions: IRRITANT. Wear personal protective equipment during cleanup. Restrict access to area until completion of clean-up. All persons dealing with clean-up should wear the appropriate chemically protective equipment especially where exposure to vapor, dust or fume is possible. Spill response/Cleanup: Ventilate area of spill or release. Eliminate all sources of ignition. Contain material, preventing it from entering sewer lines or waterways. Use absorbents to assist the pick up of material. Scrape up product and place it into a container for disposal. Residual of product, while still wet, can be cleaned up with warm soapy water. Notify the appropriate authorities as required. Environmental precautions: Do not allow material to be discharged into the atmosphere or into sewers or ground water. Special spill response procedures: If a spill/release in excess of EPA reportable quantity is made into the environment, immediately notify the national response center in the United States (phone: 1-800-424-8002). DOT/CERCLA Reportable quantity (RQ): None to report. Henry 314 Multipurpose Ceramic Tile Adhesive Page 3 of 5 SECTION 7 - HANDLING AND STORAGE Safe handling procedures: IRRITANT. Wear suitable protective equipment. Use with adequate ventilation. Training the workers on the potential health hazards associated with product vapor, dust or fume is important. Secondary inhalation exposures could occur when cleaning equipment, or when removing or laundering the clothing. Do not breathe vapors, fumes or dust. Avoid contact with eyes, skin and clothing. Keep away from flame, sparks and other ignition sources. Avoid and control operations which create vapors/dusts. Storage requirements: Store in a cool (temperature below 32.2oC / 90oF), dry, well-ventilated area. No smoking in the area. Protect from damage. SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION Engineering controls: Use with adequate ventilation. Normal ambient ventilation should be sufficient. PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: Respiratory protection should not be required. Skin protection and other protective equipment: Impervious gloves appropriate to the material if skin contact with product is expected. Advice should be sought from glove suppliers. Where exposure to product is possible use protective clothing. An eyewash fountain and safety shower should be made available in the immediate working area. Eye / face protection: Wear safety glasses to prevent any product from entering the eyes. Permissible exposure levels: For individual ingredient exposure levels, see Section 2. General Hygiene Considerations: Avoid contact with eyes, skin and clothing. Avoid breathing vapors/dusts. Never eat, drink, or smoke in work areas. Clean all equipment and clothing at end of each work shift. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical state: Odor and appearance: Paste (liquid) White paste with mild hydrocarbon odor. Odor threshold: Specific gravity (water = 1): Vapor pressure: N/Av 1.39 N/Av Evaporation rate: Slower than Ether Boiling point: Melting/freezing point: 100oC / 212oF % volatile by volume: pH: N/Av 9.05 % volatile by weight: 25-35 % (30 min. at 135oC / 275oF) N/Av Vapor density: Heavier than air Solubility in water: Dispersible Coefficient of oil/water distribution: Particle size: N/Av N/Av Weight/Gallon: 11.5 lbs (water = 8.3 lbs) Volatile Organic Content (VOC): 121 g/L calculated at 21oC / 70oF, SCAQMD SECTION 10 – REACTIVITY AND STABILITY DATA Stability and reactivity: Stable under the recommended storage and handling conditions prescribed. Polymerization: Hazardous polymerization will not occur. Conditions to avoid: Temperatures above 32.2oC / 90oF. Materials to avoid: Strong oxidizing agents. Hazardous decomposition products: Carbon monoxide, carbon dioxide, and other toxic vapors and gases that are common to thermal degradation or organic compounds. Henry 314 Multipurpose Ceramic Tile Adhesive Page 4 of 5 SECTION 11 - TOXICOLOGICAL INFORMATION Toxicological data: There is no available data for the product itself. See below for individual ingredient acute toxicity data. Ingredients: LD50 (route, species): LC50 (species): Stoddard Solvent Not available. Not available. Carcinogenicity: No ingredient classified as carcinogenic to humans by IARC, NTP, OSHA and ACGIH. Teratogenicity, mutagenicity, other reproductive effects: None known. Sensitization to material: Synergistic materials: None known. N/Av Irritancy of material: Moderate degree of irritation. For more details, refer to Section 3. SECTION 12 - ECOLOGICAL INFORMATION Environmental effects: N/Av Important environmental characteristics: N/Av Aquatic toxicity: N/Av SECTION 13 - WASTE DISPOSAL Handling and storage conditions for disposal: Handle according to recommendations listed in Section 7. Methods of disposal: Dispose of in sealed containers in accordance with all applicable government regulations. Dispose in accordance with all applicable federal, provincial, state and local regulations. Contact your local, state or federal environmental agency for specific rules. RCRA: If this product, as supplied, becomes a waste, it may meet the criteria of a hazardous waste as defined under RCRA, Title 40 CFR 261. Waste classification should be determined by the end user of the product. For disposal of unused or waste material, check with local, state and federal environmental agencies. SECTION 14 - TRANSPORTATION INFORMATION Transportation of Dangerous Goods (TDG) Information: This product is not regulated according Canadian Regulations. US DOT 49 CFR information: This product is not regulated according to US Regulations. SECTION 15 - REGULATORY INFORMATION In Canada: WHMIS information: This product is controlled by WHMIS. It does meet the criteria for a controlled product provided in Part IV of the Controlled Products Regulations (CPR). This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and this MSDS contains all the information required by the CPR. CEPA information: Ingredient listed on the DSL/NDSL. Henry 314 Multipurpose Ceramic Tile Adhesive Page 5 of 5 SECTION 15 - REGULATORY INFORMATION continued In U.S.A.: TSCA information: Ingredient listed on the TSCA inventory. DOT/CERCLA Reportable Quantity (RQ): None Reportable SARA TITLE III: Sec. 313, Toxic Chemicals Notification, 40 CFR 372: This material is not subject to the TSCA notification requirements, since it does not contain any Toxic Chemical constituents above the minimum levels. California Proposition 65: This product does not contain chemicals known to the State of California to cause cancer or reproductive toxicity. New Jersey Hazardous Substance Lists: This product contains the following listed hazardous substances above threshold percentages: Chemical Name CAS # Stoddard solvent 8052-41-3 SECTION 16 - OTHER INFORMATION Prepared by: Telephone number: Preparation date: The W.W. Henry Company (724) 203-8499 December 7, 2004 References: 1. 2. 3. 4. 5. 6. ACGIH, Threshold Limit Values and Biological Exposure Indices for 2004. International Agency for Research on Cancer Monographs, 2004. Canadian Centre for Occupational Health and Safety, CCInfoWeb databases, 2004 (Chempendium and RTECs). Material Safety Data Sheet from manufacturer. US EPA Title III List of Lists – October 2001 version. California Proposition 65 List – December 7, 2004 version. Abbreviations: ACGIH = American Conference of Governmental Industrial Hygienists CAS = Chemical Abstract Service CERCLA = Comprehensive Environmental Response, Compensation, and Liability Act of 1980 CFR = Code of Federal Regulations (Transportation in U.S.A.) DOT = Department of Transport (U.S.A.) DSL = Domestic Substance List IARC = International Agency for Research on Cancer N/Av = Not available. N/Ap = Not applicable NIOSH = National Institute for Occupational Safety and Health NTP = National Toxicology Program (U.S.A.) OSHA = Occupational Safety and Health Administration (U.S.A.) PEL = Permissible Exposure Limit RCRA = Resource Conservation and Recovery Act SARA = Superfund Amendments & Reauthorization Act STEL = Short-term Exposure Limit TLV = Threshold Limit Value TSCA = Toxic Substances Control Act TWA = Time Weighted Average WHMIS = Workplace Hazardous Materials Information System The information presented herein is supplied as a guide to those who handle or use this product and has been prepared in good faith by technically knowledgeable personnel. It is not intended to be all - inclusive. The manner and conditions of use and handling may involve other and additional considerations. Safe work practices must be employed when working with any materials. It is important that the end user makes a determination regarding the adequacy of the safety procedures employed during the use of this product. No warranty of any kind is given or implied. W.W. Henry Company will not be liable for any damages, losses, injuries or consequential damages which may result from the use or reliance on any information contained herein. This Material Safety Data Sheet is valid for three (3) years. End of the MSDS MATERIAL SAFETY DATA SHEET PRODUCT NAME: Roberts 3200 White Cove Base Adhesive PRODUCT USES: For installing vinyl and rubber cove base W.H.M.I.S. CLASSIFICATION: NON-CONTOLLED V.O.C. CONTENT: 88g/L SECTION I - MANUFACTURER IDENTIFICATION MANUFACTURER'S NAME: ROBERTS COMPANY CANADA LTD. ADDRESS: 2070 Steeles Ave. Bramalea, Ontario L6T 1A7 24 HOUR (CANUTEC) PHONE: (613) 996-6666 DATE REVISED: 06/30/02 (Product was discontinued in 2002. Replaced by 7032) NAME OF PREPARER: Peter Sharko INFORMATION PHONE: (905) 791-4444 SOURCES USED: Raw material supplier M.S.D.S. SECTION II - HAZARDOUS INGREDIENTS INFORMATION COMPONENT APPROX. % MINERAL SPIRITS 5-10 UN# 1256 SECTION III – PHYSICAL DATA BOILING POINT: 100° CFREEZING POINT: N/A VAPOUR DENSITY (AIR=1): 4-5 VAPOUR PRESSURE (MM OF MERCURY): Min. spirits 2 @ 20ºC SOLUBILITY IN WATER: Miscible APPEARANCE AND ODOUR: White, soft buttery paste, mild solvent odour. CAS# 8052-41-3 LD50 LC50 1,400 PPM 8HR., RAT SPECIFIC GRAVITY (H20=1): 1.17 pH: 9.5 – 10.5 EVAPORATION RATE (BUTYL ACETATE=1): Slower EVAPORATION RATE (ETHYL ACETATE=1): Slower PERCENT VOLATILE: 46 ODOUR THRESHOLD (PPM): Not available SECTION IV - FIRE AND EXPLOSION DATA FLASHPOINT (specify method): Over 200ºF METHOD USED: P.M.C.C. IMPACT SENSITIVITY: Insensitive FLAMMABLE LIMITS (% BY VOLUME): LOWER: 0.8-0.9 UPPER: 7 SENSITIVITY TO STATIC DISCHARGE: Vapours may be FIRE EXTINGUISHING MEDIA: Foam, CO2, Dry Chemical AUTO IGNITION TEMP: N/A TDG FLAMMABILITY CLASSIFICATION: Not regulated. SPECIAL FIRE-FIGHTING PROCEDURES: Poses minimal fire hazard. Must be heated substantially. Self-contained breathing apparatus should be worn for fires involving this product. UNUSUAL FIRE AND EXPLOSION HAZARDS: Flammable vapours, heavier than air, may be able to collect in confined spaces and pose a hazard. SECTION V - REACTIVITY DATA STABILITY: Stable INCOMPATIBILITY (Materials to avoid): Strong oxidizing agents HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO2, and Hydrocarbons upon combustion. HAZARDOUS POLYMERIZATION: Will not occur SECTION VI – TOXICOLOGICAL PROPERTIES SKIN CONTACT X SKIN ABSORPTION CONDITIONS TO AVOID: Excessive Heat CONDITIONS TO AVOID: None ENTRY ROUTE TABLE EYE CONTACT X INHALATION ACUTE X INHALATION CHRONIC INGESTION X EFFECTS OF ACUTE EXPOSURE TO MATERIAL: Overexposure to vapours can cause eye, nose, throat irritation, dizziness, drowsiness, headache feelings of drunkenness, nausea, vomiting. Massive overexposure can cause respiratory failure. Ingestion causes similar symptoms. Aspiration causes severe pneumonitis. Product is eye and skin irritant. EFFECTS OF CHRONIC EXPOSURE TO MATERIAL: Prolonged or repeated contact with skin may cause drying and defatting of skin and dermatitis. Although unlikely to occur, overexposure to vapours may cause corneal damage, photophobia. In rare cases, severe overexposure may sensitize heart muscles causing heart arrhythmia. LD50 (SPECIFY SPECIES & ROUTE): Not available SENSITIZING CAPACITY: May sensitize heart muscles. See above. LC50 (SPECIFY SPECIES): Not available CARCINOGENICITY: None EXPOSURE LIMIT: TLV-TWA, PPM MINERAL SPIRITS, 100 REPRODUCTIVITY EFFECTS: None known IRRITANCY: Eye, nose, throat and skin irritant SYNERGISTIC MATERIALS: None known SECTION VII – PREVENTATIVE MEASURES RESPIRATORY PROTECTION (SPECIFY TYPE): Not required under normal conditions of use. If TLV is to be exceeded, employ an approved NIOSH/MSHA chemical cartridge respirator with organic vapour cartridge. Consult your safety equipment supplier for respirator requirements. VENTILATION: General dilution ventilation to keep vapours below TLV. PROTECTIVE GLOVES: Solvent resistant gloves should be worn. EYE PROTECTION: Goggles / glasses with side shields OTHER PROTECTIVE EQUIPMENT: None required. SPILL PROCEDURES: Provide adequate ventilation. Mechanically collect. Wash area with water. Prevent from entering sewers or waterways. Spilled material may cause slippery conditions. Promptly report significant spills to appropriate authorities. Consult local regulations. WASTE DISPOSAL METHOD: Destroy by incineration at an approved facility. Dried material only may be landfilled. Consult local regulations. STORAGE & HANDLING PRECAUTIONS: Store in ventilated area as close to 70ºF as possible. OTHER PRECAUTIONS: Keep containers closed when not in use. Keep out of reach of children. SECTION VIII – FIRST AID MEASURES INHALATION: EYES: SKIN: INGESTION: Remove to fresh air. If not breathing, trained personnel should administer artificial respiration. Obtain medical attention immediately. Flush with water for 20 minutes holding eyelids open. Obtain medical attention immediately. Wash with soap and water. Remove dried adhesive with mineral spirits followed by soap and water. Remove contaminated clothing and launder before re-use. Consult physician if irritation develops. Do not induce vomiting. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Contact physician immediately. Page 1 of 6 Material Safety Data Sheet 24 Hour Emergency Phone Numbers: Medical: 1-800-327 -3874 1-513-558-5111 Transportation: 1-800-535-5053 1-352-323-3500 NOTE: National Response Center emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals. IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16. Section 1 - Chemical Product / Company Information This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request. Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en español a su solicitud. Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere. Product Name: Product UPC Number: Product Use/Class: Manufacturer: DAP WELDWOOD Multi-Purpose Floor Covering Adhesive 7079800144, 7079800142, 7079800141, 7079800140, 7079872054, 7079872052, 7079872049 Latex Floor Covering Adhesive Revision Date: 03/07/2005 Supercedes: 02/17/1999 MSDS Number: 00030807001 DAP Inc. 2400 Boston Street Suite 200 Baltimore, MD 21224-4723 888-327 -8477 (non-emergency matters) Section 2 - Composition / Information On Ingredients Chemical Name CASRN Kaolin 1332-58-7 Petroleum hydrocarbon oil 64742-52-5 Urea 57-13 -6 Ethylene glycol 107-21-1 Titanium dioxide 13463-67-7 4-Vinylcyclohexene 100-40-3 WT% 15-40 10-30 1-5 1-5 0.1-1.0 <0.0006 ACGIH TWA 2 MGM3 N.E. N.E. N.E. 10 MGM3 0.1 PPM ACGIH STEL N.E. N.E. N.E. N.E. N.E. N.E. ACGIH CEIL N.E. N.E. N.E. 100 MGM3 N.E. N.E. OSHA TWA N.E. N.E. N.E. N.E. 15 MGM3 N.E. OSHA STEL N.E. N.E. N.E. N.E. N.E. N.E. OSHA CEIL N.E. N.E. N.E. N.E. N.E. N.E. Skin No No No No No No Exposure Notes: Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary between states. Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work practices Section 3 - Hazards Identification Emergency Overview: A white to off-white paste with a very slight ammonia odor. WARNING! May cause irritation to the Page 2 of 6 respiratory tract. Harmful or fatal if swallowed. May cause eye, skin, nose, throat and respiratory tract irritation. This product contains ethylene glycol. Refer to other MSDS sections for other detailed information. Effects Of Overexposure - Eye Contact: May cause eye irritation. Effects Of Overexposure - Skin Contact: May cause skin irritation. Effects Of Overexposure - Inhalation: Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes). Vapors may be irritating to eyes, nose, throat, and lungs. Prolonged, repeated, or high exposures may cause weakness and depression of the central nervous system. Effects Of Overexposure - Ingestion: If ingested, may cause vomiting, diarrhea, and depressed respiration. Aspiration of material into the lungs due to vomiting can cause chemical pneumonitis, which can be fatal. Effects Of Overexposure - Chronic Hazards: Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Studies have shown that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals. Ethylene glycol has been shown to cause birth defects in laboratory animals. Prolonged or repeated contact with skin results in irritation and dermatitis. Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation Medical Conditions which May be Aggravated by Exposure: None known. Section 4 - First Aid Measures First Aid - Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately. First Aid - Skin Contact: Wash off with soap and water. First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If continued breathing difficulty is experienced, get medical attention immediately. First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately. Note to Physician: None. COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arise from any of the above routes of entry. Section 5 - Fire Fighting Measures Flash Point, F: greater than 200 degrees Fahrenheit Method: (Seta Closed Cup) Lower Explosive Limit, %: Not Established Upper Explosive Limit, %: Not Established Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam Unusual Fire And Explosion Hazards: None known. Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent) and full protective gear. Use water spray to cool exposed surfaces. Page 3 of 6 Section 6 - Accidental Release Measures Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Wet dried material before scraping up and place into containers. Section 7 - Handling And Storage Handling: Do not breathe vapors. Provide fresh air such that chemical odors cannot be detected during use and while drying. Use in well ventilated area. Construction and repair activities can adversely affect indoor air quality. Consult with occupants or a representative (i.e. maintenance, building manager, industrial hygienist, or safety officer) to determine ways to minimize impact. Wash thoroughly after handling. Do not sand, dry sweep, dry scrape, drill, saw, beadblast, mechanically chip, pulverize or otherwise machine existing resilient flooring, backing, lining felt, or asphaltic "cut -back" adhesives. These products may contain either asbestos fibers or crystalline silica. Avoid creating dust. Inhalation of such dust is a cancer and respiratory tract hazard. See current edition of the Resilient Floor Covering Institute's publication "Recommended Work Practices for Removal of Resilient Floor Coverings", for detailed information and instructions addressed to the task of removing all resilient floor covering materials. Avoid contact with eyes, skin and clothing. Storage: Store containers away from excessive heat and freezing. Keep containers tightly closed. Store away from caustics and oxidizers. Section 8 - Exposure Controls / Personal Protection Precautionary Measures: Please refer to other sections and subsections of this MSDS. Engineering Controls: Provide sufficient general and/or local exhaust ventilation to maintain exposure below recommended exposure limit. Use only in well-ventilated areas. Respiratory Protection: A respiratory protection program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Respirator use is not expected to be necessary under normal conditions of handling. In emergency situations, use of a NIOSH -approved respirator may be required. Skin Protection: Wear rubber gloves. Eye Protection: Goggles or safety glasses with side shields. Other protective equipment: None. Hygienic Practices: Although this product is not considered an eye irritant, inhalation hazard, or a skin contact hazard under normal conditions, it is advisable that personnel minimize skin contact, inhalation of vapors and eye contact. Remove and wash contaminated clothing before re-use. Section 9 - Physical And Chemical Properties Boiling Range: Odor: Appearance: Solubility in H2O: Freeze Point: Vapor Pressure: Physical State: Not Established Very Slight Ammonia White to Off-White Not Established Not Established Not Established Paste Vapor Density: Odor Threshold: Evaporation Rate: Specific Gravity: pH: Viscosity: Not Established Not Established Not Established 1.202 Between 7.0 and 12.0 Not Established When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally. Page 4 of 6 (See section 16 for abbreviation legend) Section 10 - Stability And Reactivity Conditions To Avoid: Excessive heat and freezing. Incompatibility: Strong oxidizing agents. Strong bases. Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx. Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions. Stability: Stable under normal conditions. Section 11 - Toxicological Information Product LD50: Not Established CASRN 57-13-6 107-21-1 100-40-3 Chemical Name Product LC50: Not Established LD50 Urea Ethylene glycol 4-Vinylcyclohexene Rat:8471 mg/kg Rat:4700 mg/kg 16620 mg/kg LC50 WT% ------------Rat:10876 mg/kg 4000 ppm rat 1-5 1-5 <0.0006 Carcinogenicity: CAS No. Chemical Name 13463-67 -7 Titanium dioxide 100-40-3 4-Vinylcyclohexene 14808-60 -7 Silica, crystalline ACGIH OSHA IARC NTP WT% ----- ----- Classification not possible from current data. ----- 0.1-1.0 ----- Possible carcinogen. ----- <0.0006 ----- ----- Known carcinogen. <0.00001 Confirmed animal carcinogen with unknown relevance to humans. Suspected human carcinogen. Significant Data with Possible Relevance to Humans: None Section 12 - Ecological Information Ecological Information: Ecological injuries are not known or expected under normal use. Section 13 - Disposal Information Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA Waste Code if Discarded (40 CFR Section 261): none Section 14 - Transportation Information DOT Proper Shipping Name: DOT Technical Name: DOT Hazard Class: None Packing Group: N.A. None N.A. Hazard Subclass: DOT UN/NA Number: N.A. None Page 5 of 6 Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may apply if shipped via other modes of transportation and/or to non-domestic destinations. Section 15 - Regulatory Information CERCLA - SARA Hazard Category: This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: SARA Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Chemical Name Ethylene glycol CAS Number WT% 107-21-1 1-5 Toxic Substances Control Act: All ingredients in this product are either on TSCA inventory list, or otherwise exempt. This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: Chemical Name CAS Number 5-Chloro-2-methyl-4-isothazoli 2-Methyl-4-isothiazolin-3-one 26172-55 -4 2682-20-4 U.S. State Regulations: New Jersey Right-to-Know: The following materials are non-hazardous, but are among the top five components in this product: Chemical Name Water Hydrocarbon Petroleum Resin Butadiene-styrene copolymer CAS Number 7732-18 -5 Proprietary Proprietary WT% 30-60 3-7 3-7 Pennsylvania Right-to-Know: The following non-hazardous ingredients are present in the product at greater than 3%: Chemical Name Water Hydrocarbon Petroleum Resin Butadiene-styrene copolymer CAS Number 7732-18 -5 Proprietary Proprietary California Proposition 65: Warning: The following ingredients present in the product are known to the State of California to cause cancer: WT% 30-60 3-7 3-7 Page 6 of 6 Chemical Name CAS Number Definition Date Listed WT% 4-Vinylcyclohexene 100-40 -3 Carcinogenic. Listed: May 1, 1996 <0.0006 Silica, crystalline 14808-60-7 Carcinogenic. Listed: October 1, 1988 <0.00001 Warning: The following ingredients present in the product are known to the State of California to cause birth defects or other reproductive harm: None. Section 16 - Other Information HMIS Ratings: Health: 1 Flammability: 1 VOLATILE ORGANIC COMPOUNDS, GR/LTR: 34.3 Reactivity: 0 LB/GAL: 0.3 Personal Protection: X WT%: 1.557 REASON FOR REVISION: Periodic Update Legend: N.A. – Not Applicable ACGIH – American Conference of Governmental Industrial Hygienists N.E. – Not Established SARA – Superfund Amendments and Reauthorization Act of 1986 N.D. – Not Determined NJRTK – New Jersey Right-to-Know Law VOC – Volatile Organic Compound OSHA – Occupational Safety and Health Administration PEL – Permissible Exposure Limit HMIS – Hazardous Materials Identification System TLV – Threshold Limit Value NTP – National Toxicology Program STEL – Short Term Exposure Limit CEIL – Ceiling Exposure Limit LD50 – Lethal Dose 50 LC50 – Lethal Concentration 50 F – Degree Fahrenheit C – Degree Celcius MSDS – Material Safety Data Sheet CASRN – The Chemical Abstracts Service Registry Number DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context of the intended use and (ii) determine if they are appropriate. Page 1 of 7 Hoja de datos de la seguridad de los materiales Números telefónicos de emergencia las 24 horas: Emergencias médicas: 1-800-327-3874 1-513-558-5111 Transporte: 1-800-535-5053 1-352-323-3500 NOTA: Los números de emergencia del Centro de Respuesta Nacional s ólo se deben usar en caso de emergencias químicas que involucren un derramamiento, incendio, exposici ón o accidente que tengan que ver con químicos IMPORTANTE: Lea esta hoja de datos de la seguridad de los materiales antes de manipular o desechar este producto, y entregue esta información a los empleados, clientes y usuarios de este producto. Este producto está cubierto por la norma de comunicación de riesgos OSHA, y este documento fue preparado de acuerdo con los requisitos de dicha norma. Todos los términos abreviados utilizados en este documento se describen con más detalles en la sección 16. Sección 1 - Información del producto químico/ compañía Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en español a su solicitud. On peut demander cette MSDS a la langue Francaise Canadienne. Nombre de producto: Número de UPC del producto: Uso/ clase del producto: DAP WELDWOOD Multi-Purpose Floor Covering Adhesive 7079800144, 7079800142, 7079800141, 7079800140, 7079872054, 7079872052, 7079872049 Latex Floor Covering Adhesive Fabricante: DAP Inc. 2400 Boston Street Suite 200 Baltimore, MD 21224-4723 888-327-8477 (asuntos de no emergencia) Fecha de revisión: Reemplaza a: 03/07/2005 02/17/1999 Número de hoja 00030807001 de datos (MSDS): Sección 2 - Composición / Información sobre los Ingredientes Nombre Químico Caolín Destilados (Petróleo), Fracción Nafténica Pesada Tratada Con Hidrógeno Carbamida Etilen Glicol Dioxidodetitanio 4-Vinilciclohexeno CASRN 1332 -58-7 Peso% 15 -40 ACGIH TWA ACGIH STEL ACGIH CEIL 2 MGM3 N.E. N.E. 64742-52-5 10 -30 N.E. N.E. 57 -13-6 107-21-1 13463-67-7 100-40-3 1-5 1-5 0.1-1.0 <0.0006 N.E. N.E. 10 MGM3 0.1 PPM N.E. N.E. N.E. N.E. OSHA TWA N.E. OSHA STEL N.E. OSHA CEIL N.E. Piel No N.E. N.E. N.E. N.E. No N.E. 100 MGM3 N.E. N.E. N.E. N.E. 15 MGM3 N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. No No No No Notas sobre la exposición: Importante: Los niveles de exposición permitidos (PEL) señalados son suministrados por el Dept. del Trabajo de EE.UU., Límites de la norma final OSHA (CFR 29 1910.1000); Estos límites pueden variar de estado a estado. Nota: Se debe evitar o reducir al máximo la exposición de la piel de un empleado a substancias que tengan "S Í" en la columna "PIEL" en la tabla anterior, seg ún lo permitan las circunstancias mediante el uso de guantes, ropa de protecci ón, gafas de seguridad y otros equipos personales de protección, controles de ingeniería o prácticas de trabajo. Sección 3 - Identificación de riesgos Page 2 of 7 Generalidades sobre las emergencias: Un blanco a la pasta de-blanco con un olor muy leve del amoniaco. ¡ADVERTENCIA! Puede causar irritaci ón de las vías respiratorias. Dañino o fatal si se traga. Podría causar irritación de los ojos, piel, nariz, garganta y tracto respiratorio. Este producto contiene glicol de etileno. Consulte otras secciones de la hoja de datos de seguridad de los materiales para m ás información detallada. Efectos de la sobre exposición - Contacto visual: Podr ía causar irritación a los ojos. Efectos de la sobre exposición - Contacto de la piel: Podría causar irritación de la piel. Efectos de la sobre exposición - Inhalaci ón: La inhalaci ón puede causar irritación de las vías respiratorias (nariz, boca, membranas mucosas). Los vapores pueden irritar los ojos, la nariz, la garganta y los pulmones. Las exposiciones prolongadas, repetidas o elevadas pueden causar debilidad y depresi ón del sistema nervioso central. Efectos de la sobre exposición - Ingestión: Si se ingiere, podría causar vómito, diarrea y respiración deprimida. La aspiraci ón del material en los pulmones debido al vómito puede causar neumonitis química, lo que podría ser fatal. Efectos de la sobre exposición - Riesgos crónicos: El glicol de etileno puede causar daño al riñón e hígado con la sobre exposición prolongada y repetida. Los estudios han demostrado que la inhalación repetida al glicol de etileno ha producido cambios cardiovasculares adversos en los animales de laboratorio. Se ha demostrado que el glicol de etileno causa defectos de nacimiento en animales de laboratorio. El contacto prolongado o repetido con la piel resulta en irritación y dermatitis. Ruta(s) principal de entrada: Piel el Contacto, Pele la Absorción,Aspiración Condiciones m édicas que se pueden agravar a causa de la exposición: Ninguno conocido. Sección 4 - Medidas de primeros auxilios Primeros auxilios - Contacto visual: En caso de contacto, enjuague los ojos de inmediato con abundante agua por al menos 15 minutos. Obtenga atención médica de inmediato. Primeros auxilios - Contacto de la piel: Lavar con agua y jabón. Primeros auxilios - Inhalaci ón: Si se inhala, salga al aire fresco. Si se dificulta la respiración, abandone el área para obtener aire fresco. Si se experimenta dificultad continua para respirar, busque atenci ón médica de inmediato. Primeros auxilios - Ingestión: Si se traga, NO PROVOQUE EL VÓMITO. Obtenga atención médica de inmediato. Nota para el médico: Sin informaci ón COMENTARIOS: Llame para emergencias médicas al 1 -800-327-3874 si surgiera cualquier irritación o complicación de cualquiera de las rutas de entrada anteriores. Sección 5 - Medidas para combatir incendios Punto de inflamaci ón, F: Más que 200 grados Fahrenheit Método: ( Seta Cerró Copa) Límite explosivo menor, %: No Establecido Límite explosivo mayor, %: No Establecido Medios para extinguir: Bióxido de carbono, Seque Sustancia Química, Espuma Riesgos inusuales de incendio y explosi ón: Ninguno conocido. Procedimientos especiales para combatir incendios: Use un aparato para respiraci ón auto-contenida con demanda de Page 3 of 7 presi ón (aprobado por el Instituto NIOSH o equivalente) y equipo completo de protecci ón. Use rociador de agua para enfriar las superficies expuestas. Sección 6 - Medidas en caso de emisión accidental Pasos a seguir en el caso de emisión o derramamiento de materiales: Use el equipo de protección correcto según lo especifica la Secci ón 8. Moje el material seco antes de raspar y coloque en contenedores. Sección 7 - Manejo y almacenamiento Manejo: No respire los vapores. Suministre aire fresco de manera que los olores de los químicos no se puedan detectar durante el uso y mientras se seca. Usar en un área bien ventilada. Las actividades de construcci ón y de reparaciones pueden afectar de manera adversa la calidad del aire en interiores. Consulte con los ocupantes o un representante (es decir, mantenimiento, administrador de construcción, higienista industrial, u oficial de seguridad) para determinar las formas de reducir el impacto. Lave a fondo después de manipular. No lije, barra en seco, raspe en seco, perfore, asierre, pula, corte mecánicamente, pulverice o una acci ón similar los revestimientos elásticos existentes, refuerzos, fieltro de forro, o adhesivos asfálticos "cut back". Estos productos pueden contener ya sea fibras de asbestos o sílice cristalino. Evite crear polvo. La inhalación de este polvo es un riesgo de cáncer y de infección del tracto respiratorio. Consulte la edici ón actual de la publicaci ón del Instituto Resilient Floor Covering: “Pr ácticas de trabajo recomendadas para retirar los revestimientos elásticos", para informaci ón e instrucciones detalladas para la tarea de retirar todos los materiales de revestimiento elástico. Evite el contacto con los ojos, la piel y la ropa. Almacenamiento: Almacene los contenedores lejos del calor y congelamiento excesivos. Manténgase el recipiente bien cerrado. Almacene lejos de substancias cáusticas y oxidantes. Sección 8 - Controles de la exposición/ Protección personal Medidas de precaución: Refiérase por favor a otras secciones y subdivisiones de este MSDS. Controles de ingeniería: Ofrezca ventilación de escape general y/o local suficiente para mantener la exposición debajo del límite recomendado. Utilícese solo en zonas bien ventiladas. Protecci ón respiratoria: Se debe seguir un programa de protecci ón respiratoria que cumpla con los requisitos de OSHA 1910.134 y ANSI Z88.2 cada vez que las condiciones del lugar de trabajo exijan el uso de un respirador. No es de esperar que sea necesario usar un aparato de respiraci ón bajo condiciones normales de manejo. En situaciones de emergencia, puede que se requiera el uso de un aparato de respiraci ón aprobado por el NIOSH. Protecci ón de la piel: Usar guantes de goma. Protecci ón de la visión: Gafas de seguridad con protectores laterales. Otro equipo de protección: Ninguno. Prácticas higiénicas: No obstante este producto no se considera un irritante para los ojos, riesgo de inhalación o riesgo de contacto con la piel bajo condiciones normales, se recomienda que el personal reduzca el contacto con la piel, la inhalación de vapores y el contacto con los ojos. Quitar y lavar la ropa contaminada antes de reutilizar. Sección 9 - Propiedades físicas y químicas Rango de ebullición: No Establecido Densidad del vapor: No Establecido Page 4 of 7 Olor: Amoniaco muy Leve Umbral de olor: No Establecido Aspecto: Blanco a De-Blanco Índice de evaporación: No Establecido Solubilidad en H2O: No Establecido Gravedad específica: 1.202 Punto de congelamiento: No Establecido pH: Entre 7,0 y 12,0 Presi ón del vapor: No Establecido Viscosidad: No Establecido Estado físico: Pasta (Ver sección 16 para la leyenda de las abreviaturas) Sección 10 - Estabilidad y reactividad Condiciones a evitar: Calentamiento y congelamiento excesivos. Incompatibilidad: agentes oxidantes fuertes bases fuertes Productos de descomposición peligrosa: Productos de descomposición normal, es decir, COx, NOx. Polimerización peligrosa: No ocurrirá polimerización peligrosa bajo condiciones normales. Estabilidad: Estable en condiciones normales Sección 11 - Información toxicológica LD50 del producto: No Establecido CASRN Nombre Químico 57-13-6 107-21-1 100-40-3 LC50 del producto: No Establecido LD50 LC50 Carbamida Etilen Glicol 4-Vinilciclohexeno Rat:8471 mg/kg Rat:4700 mg/kg 16620 mg/kg ------------Rat:10876 mg/kg 4000 ppm rat Peso% 1-5 1-5 <0.0006 Carcinogenicidad: Número CAS Nombre Químico 13463-67 -7 Dioxidodetitanio 100-40-3 4-Vinilciclohexeno 14808-60 -7 Silicecristalina ACGIH OSHA IARC NTP Peso% ----- ----- Clasificación no posible de datos actuales. ----- 0.1-1.0 ----- Cancerígeno posible. ----- <0.0006 ----- ----- Cancerígeno conocido. <0.00001 Cancerígeno animal confirmado con la aplicabilidad desconocida a humanos. Cancerígeno humano sospechado. Datos significativos con posible relevancia para los humanos: Ninguno Sección 12 - Información ecológica Información ecológica: No se conocen ni esperan daños ecológicos bajo uso normal. Sección 13 - Información sobre desechos Información sobre desechos: Deseche los materiales de acuerdo con todas las normas federales, estatales y locales. Las normas/ restricciones estatales y locales son complejas y pueden diferir de las normas federales. La responsabilidad de eliminar los desechos correctamente recae en el propietario de los desechos. Page 5 of 7 Código de desechos de EPA en caso de desecho (CFR 40 Sección 261): Ninguno Sección 14 - Información sobre transporte Nombre correcto para envío a DOT: Nombre técnico para DOT: Clase de riesgo para DOT: Ninguno Grupo de empaque: No Aplicable Ninguno No Aplicable Sub-clase de riesgo: Número UN/NA para DOT: No Aplicable Ninguno Nota: La información del envío proporcionada es aplicable para el transporte doméstico del suelo sólo. Categorizaci ón diferente puede aplicar si enviado vía otros modos del transporte y/o a destino no-domésticos. Sección 15 - Información reglamentaria Categoría de riesgo CERCLA - SARA: Este producto ha sido revisado según las categorías de riesgo de EPA promulgadas según las secciones 311 y 312 de la Ley de enmienda y reautorización de fondos especiales de 1986 (SARA, por sus iniciales en inglés, Título III) y se considera, según las definiciones correspondientes, que cumple con las siguientes categorías: Sección 313 de la ley SARA: Este producto contiene las siguientes substancias sujeto a los requisitos de reporte de la sección 313 del título III de la ley SARA de 1986 y 40 CFR parte 372: Nombre Químico Etilen Glicol Número CAS Peso% 107-21-1 1-5 Ley para el control de substancias tóxicas: Todos ingredientes en este producto son o en lista de inventario de TSCA, o de otro modo exima. Este producto contiene las siguientes substancias químicas de acuerdo con los requisitos de reporte de la ley TSCA 12(B) si es exportado desde los Estados Unidos: Nombre Químico Número CAS 5-Chloro-2-Methyl-4-Isothazoli 2-Methyl-4-Isothiazolin-3-One 26172-55 -4 2682-20-4 Regulaciones estatales de EE.UU.: Ley del Derecho a saberde New Jersey: Los siguientes materiales no representan peligro, pero están entre los primeros cinco componentes de este producto: Nombre Químico Agua Hydrocarbon Petroleum Resin Copolymer De Estireno De Butadiene Número CAS 7732-18 -5 Propietario Propietario Peso% 30-60 3-7 3-7 Ley del Derecho a saber de Pennsylvania: Los siguientes ingredientes no peligrosos están presentes en el producto en una proporción mayor a 3%: Nombre Químico Número CAS Peso% Page 6 of 7 Agua Hydrocarbon Petroleum Resin Copolymer De Estireno De Butadiene 7732 -18-5 Propietario Propietario 30-60 3-7 3-7 Propuesta 65 de California: Advertencia: Los siguientes ingredientes presentes en el producto son conocidos para el Estado de California por causar cáncer: Nombre Químico 4-Vinilciclohexeno Ester Etilico Del Acido 2 -Propenoico Silicecristalina Número CAS 100-40 -3 140-88 -5 14808-60-7 Definición Fecha Listó Peso% Cancerígeno. Cancerígeno. Cancerígeno. Listed: May 1, 1996 Listed: July 1, 1989 Listed: October 1, 1988 <0.0006 <0.0001 <0.00001 Advertencia: Los siguientes ingredientes presentes en el producto son conocidos para el Estado de California por causar defectos de nacimiento u otros daños reproductivos: Ninguno. Sección 16 - Otra información Índices HMIS: Salud: 1 Inflamabilidad: 1 Reactividad: 0 COMPONENTES ORGÁNICOS VOLÁTILES, GR/LTR: 34.3 LB/GAL: 0.3 Protecci ón personal: X WT%: 1.557 RAZÓN DE LA REVISIÓN: Periódico Actualiza Leyenda: N.A. - No aplica ACGIH - Conferencia Americana de Higienistas Industriales gubernamentales N.E. - No establecido SARA - Ley Ley de enmienda y reautorizaci ón de fondos especiales de 1986 (SARA) N.D. - No determinado NJRTK - Ley del Derecho a saber de New Jersey VOC - Componente orgánico volátil OSHA - Administración de la seguridad y salud ocupacional PEL - Límites permitidos de exposición C - Grados centígrados TLV - Valor del límite umbral NTP - Programa nacional de toxicología STEL - Límite de exposición a corto plazo CEIL - Límite máximo de exposici ón LD50 - Dosis letal 50 LC50 - Concentración letal 50 HMIS - Sistema de identificación de materiales peligrosos MSDS - Hoja de datos de la seguridad de los materiales CASRN - Número de registro de servicios de abstractos químicos F - Grados Fahrenheit DAP cree que los datos y las declaraciones contenidos en el presente son exactos hasta la fecha. Se ofrecen de buena fe como valores típicos y no como las especificaciones del producto. NO SE OFRECE NINGUNA GARANT ÍA DE COMERCIABILIDAD, IDONEIDAD PARA UN PROPÓSITO EN PARTICULAR O CUALQUIER OTRA GARANTÍA, EXPRESA O IMPLÍCITA, CON RESPECTO A LA INFORMACIÓN SUMINISTRADA EN EL PRESENTE O DEL PRODUCTO AL CUAL LA INFORMACIÓN SE REFIERE. Dado que este documento tiene la intención de ser una guía únicamente para el uso correcto y el manejo preventivo del producto de la referencia por parte de personas correctamente entrenadas, es responsabilidad del usuario (i) revisar las recomendaciones con especial consideración al contexto específico del uso que se pretende y (ii) determinar si son correctas. Page 7 of 7 Page 1 of 7 Fiche signalétique 24 heures – Numéros de téléphone en cas d’urgence: Urgence médicale: 1-800-327 -3874 1-513-558 -5111 Urgence transport: 1-800-535 -5053 1-352-323 -3500 NOTE: Les numéros de téléphone en cas d’urgence doivent être utilisés uniquement lors de déversement, de fuite, d’incendie, d’exposition ou d’accident impliquant des produits chimiques. IMPORTANT: Lire attentivement cette fiche signalétique avant de manipuler ou de disposer de ce produit. Remettre ces informations aux employés, clients et utilisateurs de ce produit. Ce produit est régit sous la gouverne de l’OSHA, Communication de renseignements à l’égard de matières dangereuses, et ce document a été préparé pour répondre aux exigences de ces standards. Les significations pour toutes les abréviations utilisées dans cette fiche signalétique sont décrites à la Section 16. Section 1 – Identification du produit et de la compagnie This MSDS is offered in English upon request. Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere. Nom du produit: Numéro UPC: Utilisation du produit/Classe: Fabricant: DAP WELDWOOD Multi-Purpose Floor Covering Adhesive 7079800144, 7079800142, 7079800141, 7079800140, 7079872054, 7079872052, 7079872049 Latex Floor Covering Adhesive Date de r évision: 03/07/2005 Date 02/17/1999 d’abrogation: Numéro de fiche: 00030807001 DAP Inc. 2400 Boston Street Suite 200 Baltimore, MD 21224-4723 888-327 -8477 ( Pour toute information non urgente) Section 2 - Composition / Ingrédients dangereux Nom Chimique Kaolin Distillat naphténique lourd hydrotraité Urée Éthylène glycol Dioxyde de titane 4-Vinylcyclohexne CASRN 1332 -58-7 64742-52-5 57-13-6 107-21 -1 13463-67-7 100-40 -3 Poids% 15-40 10-30 1-5 1-5 0.1-1.0 <0.0006 ACGIH TWA ACGIH STEL ACGIH CEIL 2 MGM3 N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. N.E. 100 MGM3 10 MGM3 N.E. N.E. 0.1 PPM N.E. N.E. OSHA TWA N.E. N.E. N.E. N.E. 15 MGM3 N.E. OSHA STEL N.E. N.E. N.E. N.E. N.E. N.E. OSHA CEIL Peau N.E. Non N.E. Non N.E. Non N.E. Non N.E. Non N.E. Non Notes concernant l’exposition: Important: Les limites d’exposition permises (LEP) décrites proviennent du Department of Labor des États-Unis, règlement final concernant les valeurs d’exposition moyennes pondérées de l’OSHA (CFR 29 1910.1000); ces limites peuvent varier selon les états. Note: Prendre tous les moyens selon les circonstances afin de prévenir ou réduire toute exposition de la peau des employés aux substances portant la mention «OUI» dans la colonne «PEAU» du tableau ci-dessus. Utiliser des gants, une combinaison, des lunettes étanches, tout autre équipement de protection personnel adéquat, les contrôles techniques et les pratiques appropriées au type de travail. Section 3 – Identification des dangers Page 2 of 7 Urgences générales: Un blanc à la pâte de-blanc avec une odeur d'ammoniaque tr ès insignifiante. AVERTISSEMENT ! Peut provoquer une irritation des voies respiratoires. Nocif ou mortel si ingéré. Peut causer une irritation des yeux, de la peau, du nez, de la gorge et des voies respiratoires. Ce produit contient du glycol d'éthyl ène. Consulter les autres sections de cette fiche signalétique pour des informations plus détaillées. Effets de surexposition – Contact oculaire: Peut causer une irritation des yeux. Effets de surexposition – Contact cutané: Peut causer une irritation de la peau. Effets de surexposition – Inhalation: L'inhalation de ce produit peut provoquer l'irritation des voies respiratoires (nez, bouche, muqueuses). Les vapeurs peuvent être irritantes pour les yeux, le nez, la gorge et les poumons. L'exposition prolongée, ou répétée, ou à de fortes concentrations peut provoquer un affaiblissement et une dépression du système nerveux central. Effets de surexposition – Ingestion: En cas d’ingestion, peut causer des vomissements, de la diarrhée et une diminution de la capacité pulmonaire. L’aspiration de mat ériau dans les poumons lors de vomissements peut causer une pneumonie chimique qui peut être mortelle. Effets de surexposition – Dangers chroniques: Une exposition excessive et répétée à l’éthyl ène glycol peut causer des lésions aux reins et au foie. Les études en laboratoire menées sur des animaux ont démontré que l’inhalation r épétée d’éthyl ène glycol cause des changements néfastes du syst ème cardiovasculaire. Lors d’études en laboratoire sur les animaux, il a été démontré que l ’éthyl ène glycol cause des anomalies congénitales. Un contact excessif et répété avec la peau peut causer une irritation ou une dermatite. Voie(s) d’absorption: Peau le Contact, L'Absorption de peau, l'Inhalation Problèmes médicaux aggravés lors d’exposition au produit : Aucune connue. Section 4 – Premiers soins Premiers soins – Contact oculaire: En cas de contact avec les yeux, rincer abondamment avec de l ’eau pendant au moins 15 minutes. Obtenir des soins médicaux immédiatement. Premiers soins – Contact cutané: Laver avec de l'eau et du savon. Premiers soins – Inhalation: En cas d’inhalation, transporter la personne exposée à l’air frais. Si elle a de la difficulté à respirer, quitter les lieux afin d’obtenir de l’air frais. Si la difficulté à respirer persiste, obtenir des soins médicaux immédiatement. Premiers soins – Ingestion: En cas d’ingestion, NE PAS FAIRE VOMIR. Obtenir des soins m édicaux immédiatement. Note au médecin: Pas d'information. COMMENTAIRES: En cas d’apparition d’une irritation ou de complications suite à une exposition au produit, communiquer immédiatement avec l’urgence m édicale au 1-800-327-3874. Section 5 – Mesures de protection en cas d’incendie Point d’éclair, º F ( º C ): Plus grand que 200 degrés Fahrenheit Méthode: ( Seta A Fermé la Tasse) Limite d ’explosibilité inférieure, %: Pas Etabli Limite d ’explosibilité supérieure, %: Pas Etabli Moyens d’extinction: Dioxyde de carbone, Sécher Chimique, Mousse Page 3 of 7 Risques particuliers d’explosions ou d’ignition: Aucun connu. Procédures spéciales de lutte contre les incendies: Porter un respirateur autonome à pression d’air (approuvé NIOSH ou équivalent) et un équipement de protection personnel complet. Utiliser une lance-brouillard afin de refroidir les contenants expos és. Section 6 – Mesures en cas de déversement accidentel Procédures de nettoyage: Porter un équipement de protection personnel approprié tel que spécifié à la Section 8. Humidifier le matériau sec avant de le gratter puis disposer dans un contenant. Section 7 – Manutention et entreposage Manutention: Éviter de respirer les vapeurs. Assurer l’entrée d’air frais de façon à éliminer les odeurs des produits chimiques pendant l ’utilisation et le temps de séchage. Utilisez dans un espace bien aéré. Les activités de construction et de réparation peuvent affecter la qualité de l’air à l’intérieur. Vérifier avec les occupants ou un de leurs représentants (responsable de maintenance, gérant d’édifice, hygiéniste industriel ou responsable de sécurité) afin de déterminer les façons appropriées pour en diminuer l’impact. Laver vigoureusement après la manipulation. Ne pas poncer, balayer à sec, gratter à sec, percer, scier, utiliser un jet à billes, buriner et pulvériser mécaniquement ou à l’aide de tout autre outil les couvre-planchers élastiques, les supports, les blindages ou les adhésifs d’asphalte dilué existants. Ces produits peuvent contenir de l’amiante ou de la silice cristalline. Éviter de générer de la poussière. Éviter d’inhaler cette poussi ère, elle est canc érigène et dangereuse pour les voies respiratoires. Pour de plus amples informations concernant les pratiques d’enlèvement complet des couvre-planchers élastiques, consulter la r écente édition du bulletin du Resilient Floor Covering Institute; "Le Travail recommand é Pratique pour l'Enlèvement de Couvertures de Plancher Elastiques". Éviter tout contact avec les yeux, la peau et les vêtements. Entreposage: Entreposer les contenants loin de la chaleur excessive ou du froid excessif. Conserver le récipient bien fermé. Entreposer loin des produits caustiques et des agents oxydants. Section 8 – Contrôles d’exposition / Protection personnelle Mesures de précaution: S'il vous plaît se référer aux autres sections et aux autres sous -sections de ce MSDS. Contrôles d’ingénierie: Faire fonctionner au maximum le système de ventilation central et/ou le système d’évacuation local afin de maintenir le niveau des vapeurs organiques sous les limites d’exposition recommandées. Utiliser seulement dans des zones bien ventilées. Protection des voies respiratoires: Un programme de protection respiratoire défini selon les normes de l ’OSHA 1910.134 et de l’ANSI Z88.2 doit être appliqué à chaque fois que les conditions sur les lieux de travail exigent de porter un respirateur. On ne s'attend pas à ce qu'un masque soit nécessaire dans les conditions normales de manipulation. En cas de situation d'urgence, un masque de type agréé par NIOSH peut être nécessaire. Protection de la peau: Portez des gants en caoutchouc. Protection des yeux: Lunettes étanches ou lunettes de s écurité avec boucliers latéraux. Équipements de protection additionnels: Aucun. Pratiques hygiéniques: Dans des conditions normales d’utilisation, même si ce produit n’est pas considéré ni un irritant pour les yeux, ni un danger en cas d’inhalation ou de contact avec la peau, il est recommandé que le personnel minimise les risques de contact avec les yeux et la peau et évite d’inhaler les vapeurs. Enlever et laver les vêtements contaminés avant réutilisation. Page 4 of 7 Section 9 – Propriétés physiques et chimiques Point d’ébullition: Odeur: Pas Etabli L'Ammoniaque très Insignifiante Apparence: Blanc à De-Blanc Solubilité dans l’eau (H2O): Point de congélation: Pression de vapeur: État physique: Pas Etabli Pas Etabli Pas Etabli Pâte Densité de vapeur: Limite de détection olfactive: Taux d ’évaporation: Poids spécifique: Pas Etabli Pas Etabli Taux de pH: Viscosité: Entre 7,0 et 12,0 Pas Etabli Pas Etabli 1.202 (Consulter la Section 16 pour conna ître la signification des abréviations)) Section 10 – Stabilité et réactivité Conditions à éviter: Chaleur excessive ou froid excessif. Incompatibilité: des oxydants forts des bases fortes Produits de décomposition dangereux: Produits de d écomposition habituels : oxydes de carbone (COx) et oxydes d’azote (NOx). Risque de polym érisation: Aucune polymérisation dangereuse ne surviendra dans des conditions normales d’utilisation. Stabilité: Stable dans des conditions normales Section 11 – Propriétés toxicologiques Produit DL50: Pas Etabli CASRN 57-13-6 107-21-1 100-40-3 Nom Chimique Produit CL50: Pas Etabli LD50 Urée Éthylène glycol 4-Vinylcyclohexne Rat:8471 mg/kg Rat:4700 mg/kg 16620 mg/kg LC50 Poids% ------------Rat:10876 mg/kg 4000 ppm rat 1-5 1-5 <0.0006 Effets cancérig ènes: Numéro CAS Nom Chimique 13463-67 -7 Dioxyde de titane 100-40-3 4-Vinylcyclohexne 14808-60 -7 Silice cristalline ACGIH OSHA IARC NTP Poids% ----- ----- Classification pas possible des données actuelles. ----- 0.1-1.0 ----- Cancérog ène possible. ----- <0.0006 ----- ----- Cancérogène connue. <0.00001 Confirmée canc érog ène animale avec le pertinence inconnu aux humains. Présumée cancérogène humaine. Données significatives possiblement pertinentes à l’humain: Aucun Section 12 – Information écologique Information écologique: Aucune dégradation de l'environnement n'est connue ou prévisible dans les conditions normales d'utilisation. Page 5 of 7 Section 13 – Information sur la mise au rebut Information concernant la mise au rebut: Disposer de ce matériau en respectant les lois fédérales, provinciales et municipales. Les lois et restrictions provinciales et municipales sont complexes et peuvent différer des lois f édérales. La responsabilité de la disposition appropriée des déchets appartient au propriétaire des déchets. Code de mise au rebut de l ’Agence de protection de l’environnement (40 CFR Section 261): Aucun Section 14 – Étiquetage selon le Ministère des Transports Nom du produit expédié: Nom technique: Classe de danger: Aucun Aucun Pas Applicable Groupe d’emballage: Classe de transport: Numéro UN/NA: Pas Applicable Pas Applicable Aucun Note : L'information d'expédition fournie est applicable pour le transport de sol domestique seulement. La catégorisation différente peut s'appliquer si exp édié via les autres modes de et/ou de transport aux destinations non résidentielles. Section 15 – Information sur les règlements CERCLA - Catégories de dangers selon le SARA: Ce produit a été revu en conformité avec les «Catégories de dangers» établies par l’Agence de protection de l’environnement et promulguées aux Sections 311 et 312 du Superfund Amendment and Reauthorization Act de 1986 (SARA Titre III). Selon les définitions applicables, il est considéré répondre aux cat égories suivantes : SARA SECTION 313 : Ce produit contient les substances suivantes assujetties aux normes de déclaration de la Section 313, du Titre III de la Superfund Amendments and Reauthorization Act de 1986 et du 40 CFR partie 372 : Nom Chimique Éthylène glycol Numéro CAS 107-21-1 Poids% 1-5 LOI SUR LE CONTRÔLE DES SUBSTANCES TOXIQUES: Tous ingrédients dans ce produit sont ou sur la liste d'inventaire de TSCA, ou autrement exempter. Ce produit contient les substances chimiques suivantes à déclarer selon les normes TSCA 12(B) si export é à l’extérieur des États-Unis: Nom Chimique Numéro CAS 5-Chloro-2-Methyl-4-Isothazoli 2-Methyl-4-Isothiazolin-3-One 26172-55 -4 2682-20-4 Lois particulières selon les états aux États-Unis: NEW JERSEY RIGHT-TO-KNOW : Les substances suivantes sont non-dangereuses mais sont comptées parmi les 5 principaux ingrédients composant ce produit: Nom Chimique Eau Hydrocarbon Petroleum Resin Copolymère de styrène et de butadiène Numéro CAS 7732-18 -5 De propriété De propriété Poids% 30-60 3-7 3-7 Page 6 of 7 PENSYLVANIA RIGHT-TO-KNOW: Les substances suivantes sont non-dangereuses mais sont présentes à plus de 3% dans ce produit: Nom Chimique Numéro CAS Eau Hydrocarbon Petroleum Resin Copolymère de styrène et de butadiène Poids% 7732-18 -5 De propriété De propriété 30-60 3-7 3-7 PROPOSITION 65 DE CALIFORNIE: AVERTISSEMENT ! Les produits chimiques list és ci-dessous et contenus dans ce produit sont reconnus par l’État de la Californie pour causer le cancer: Nom Chimique Numéro CAS Définition Dater Enuméré Poids% 4-Vinylcyclohexne Silice cristalline 100-40 -3 14808-60-7 Cancérog ène. Cancérog ène. Listed: May 1, 1996 Listed: October 1, 1988 <0.0006 <0.00001 AVERTISSEMENT ! Les produits chimiques list és ci-dessous et contenus dans ce produit sont reconnus par l’État de la Californie pour causer le cancer, des anomalies congénitales ou d’autres problèmes reliés à la reproduction: Aucun. Section 16 – Autres informations Classification des dangers: Santé: 1 Inflammabilité: 1 COMPOSÉ ORGANIQUE VOLATIL, G/LITRE: 34.3 Réactivité: 0 LB/GALLON: 0.3 Protection personnelle: X POIDS %: 1.557 RAISONS DE RÉVISION: Mise à jour p ériodique Légende: N.A. – Non applicable ACGIH – American Conference of Governmental Industrial Hygienists N.É. – Non établi SARA – Superfund Amendments and Reauthorization Act de 1986 N.D. – Non déterminé NJRTK – New Jersey Right-to-Know Law VOC – Composé organique volatil OSHA – Occupational Safety and Health Administration PEL – Limite d’exposition permise HMIS – Hazardous Materials Identification System TLV – Limite tolérable d’exposition TWA – Valeur d’exposition moyenne pondérée NTP – National Toxicology Program F – Degré Fahrenheit STEL – Limite d’exposition à court terme C – Degré Celcius LD50 – Dose létale 50 LC50 – Concentration létale 50 CASRN – Numéro enregistré selon le Chemical Abstracts Service CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act DAP croit que les données et renseignements stipulés dans cette fiche signal étique sont précis à la date de rédaction de cette fiche. Ces données sont offertes en toute bonne foi et représente des valeurs standard sans toutefois être des sp écifications du produit. AUCUNE GARANTIE SUR LA QUALITÉ MARCHANDE, GARANTIE D’APTITUDE POUR AUCUN TYPE D’EMPLOI PARTICULIER OU TOUTE AUTRE FORME DE GARANTIE N’EST EXPRESSÉMENT OU IMPLICITEMENT OFFERTE EN REGARD DES INFORMATIONS FOURNIES DANS CETTE FICHE OU DES INFORMATIONS RELATIVES AU PRODUIT. Cette fiche est produite uniquement à titre de guide pour les personnes form ées à cet effet afin qu’elles puissent appliquer les procédures appropriées de manutention auxquelles le produit réfère. Toutefois, c’est la responsabilité chaque utilisateur de revoir les recommandations selon le contexte spécifique de l’utilisation prévue et de déterminer si ces proc édures sont appropriées. Page 7 of 7 MATERIAL SAFETY DATA SHEET C-98 01 00 =========================================================================== Section 1 -- PRODUCT AND COMPANY IDENTIFICATION --------------------------------------------------------------------------PRODUCT NUMBER HMIS CODES Health 1 C-98 Flammability 0 Reactivity 0 PRODUCT NAME Multi-Purpose Floor Adhesive MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. THE SHERWIN-WILLIAMS COMPANY (216) 566-2917 101 Prospect Avenue N.W. Cleveland, OH 44115 DATE OF PREPARATION INFORMATION TELEPHONE NO. 19-APR-07 (216) 566-2902 =========================================================================== Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE --------------------------------------------------------------------------28 1332-58-7 Kaolin ACGIH TLV 2 mg/m3 as Resp. Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction =========================================================================== Section 3 -- HAZARDS IDENTIFICATION --------------------------------------------------------------------------ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. SIGNS AND SYMPTOMS OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. =========================================================================== Section 4 -- FIRST AID MEASURES --------------------------------------------------------------------------EYES: SKIN: INHALATION: INGESTION: Flush eyes with large amounts of water for 15 minutes. Get medical attention. Wash affected area thoroughly with soap and water. If affected, remove from exposure. Restore breathing. Keep warm and quiet. Do not induce vomiting. Get medical attention immediately. Continued on page 2 C-98 page 2 =========================================================================== Section 5 -- FIRE FIGHTING MEASURES --------------------------------------------------------------------------FLASH POINT LEL UEL Not Applicable N.A. N.A. FLAMMABILITY CLASSIFICATION Not Applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. =========================================================================== Section 6 -- ACCIDENTAL RELEASE MEASURES --------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. =========================================================================== Section 7 -- HANDLING AND STORAGE --------------------------------------------------------------------------STORAGE CATEGORY Not Applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Continued on page 3 C-98 page 3 =========================================================================== Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION --------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Solvent resistant (B.F. Goodrich Holdfast No. 66 or equal) EYE PROTECTION Wear safety spectacles with unperforated sideshields. =========================================================================== Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES --------------------------------------------------------------------------PRODUCT WEIGHT 10.10 lb/gal 1210 g/l SPECIFIC GRAVITY 1.22 BOILING POINT 212 - 213 F 100 - 100 C MELTING POINT Not Available VOLATILE VOLUME 38 % EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 7.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 0.00 lb/gal 0 g/l Less Water and Federally Exempt Solvents 0.00 lb/gal 0 g/l Emitted VOC Continued on page 4 C-98 page 4 =========================================================================== Section 10 -- STABILITY AND REACTIVITY --------------------------------------------------------------------------STABILITY -- Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur =========================================================================== Section 11 -- TOXICOLOGICAL INFORMATION --------------------------------------------------------------------------CHRONIC HEALTH HAZARDS No ingredient in this product is an IARC, NTP or OSHA listed carcinogen. --------------------------------------------------------------------------TOXICOLOGY DATA CAS No. Ingredient Name --------------------------------------------------------------------------1332-58-7 Kaolin LC50 RAT 4HR Not Available LD50 RAT Not Available =========================================================================== Section 12 -- ECOLOGICAL INFORMATION --------------------------------------------------------------------------ECOTOXICOLOGICAL INFORMATION No data available. =========================================================================== Section 13 -- DISPOSAL CONSIDERATIONS --------------------------------------------------------------------------WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. =========================================================================== Section 14 -- TRANSPORT INFORMATION --------------------------------------------------------------------------US Ground (DOT) Information is not Available Canada (TDG) Information is not Available IMO Information is not Available Continued on page 5 C-98 page 5 =========================================================================== Section 15 -- REGULATORY INFORMATION --------------------------------------------------------------------------SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element --------------------------------------------------------------------------No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification. CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of California to cause cancer. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. =========================================================================== Section 16 -- OTHER INFORMATION --------------------------------------------------------------------------This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. MAPEI® Material Safety Data Sheet (MSDS) - North America Read complete MSDS prior to using product. ----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------Product Name: Ultrabond ECO™ 575 Product Description: Premium Cove Base Adhesive ----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------IN THE EVENT OF A CHEMICAL EMERGENCY INVOLVING A SPILL, LEAK, FIRE, EXPLOSION, EXPOSURE OR ACCIDENT CONTACT THE FOLLOWING NUMBERS: EMERGENCY 24 HOUR NUMBER (USA) CHEMTREC 1-800-424-9300 (Canada) CANUTEC 1-613-996-6666 CONSUMER STATEMENT: CAUTION - EYE IRRITANT. NON-TOXIC. WORK AND HYGIENE PRACTICE: Remove contaminated clothing immediately. Wash hands, after each use and before eating, drinking, or using toiletries. Minimize contact of product on skins. ________________________________________________________________________________________________________________________ I - GENERAL INFORMATION MANUFACTURER: USA and Puerto Rico Canada MAPEI CORPORATION MAPEI INC. II - PHYSICAL CHARACTERISTICS 0 g/L Calculated VOC (See below.) >212°F (>100°C) Boiling Point 1,0 Vapor Pressure (mmHg) 1144 East Newport Center Drive 2900 Francis-Hughes Avenue Deerfield Beach, FL 33442 Laval, QC H7L 3J5 Vapor Density (AIR=1) Specific Gravity (H20=1) Ph: (954) 246-8888 Ph: (450) 662-1212 Melting/Freezing Point (F) N/E Evaporation Rate (Butyl Acetate=1) Solubility in water pH (paste/liquid) Same as water. Soluble 8,0 - 10,0 Appearance and Odor Beige paste. Slight odor of latex. MSDS PREPARED BY: Regulatory Affairs Department - MAPEI North America REVISION DATE (YYYY/MM/DD): 2005/07/15 For most current MSDS, download document from: www.mapei.com 1,10 - 1,20 1,00 - 1,30 (VOC per CA South Coast Air Quality Management District, Rule 1168) ________________________________________________________________________________________________________________________ III - HAZARD ASSESSMENT Hazardous Components (specific chemical identity; common names): OSHA (PEL) ACGIH (TLVTWA) Other Limits Recommended % Percent (Optional) THIS PRODUCT CONTAINS NO HAZARDOUS INGREDIENTS AS DEFINED BY US OSHA HAZARD COMMUNICATION STANDARD - 29 CFR 1910.1200 OR SECTION 13 OF THE CANADIAN HAZARDOUS PRODUCTS ACT. For California (Proposition 65): This product contains no chemicals reportable under Proposition 65. All ingredients are listed within or exempted from US TSCA and Canadian DSL. (USA) - HMIS (Hazardous Materials Identification System) Rating: Health - 1 Fire - 0 Reactivity - 0 Protection - B "*" = chronic effect (Canada) - WHMIS (Workplace Hazardous Materials Information System) Classifications: Not regulated under WHMIS. ________________________________________________________________________________________________________________________ IV - TRANSPORTATION By GROUND - USA and Puerto Rico (DOT): Not Regulated By SEA (IMDG): Not Regulated By GROUND - Canada (TDG): Not Regulated By AIR (IATA): Not Regulated ________________________________________________________________________________________________________________________ V - FIRE AND EXPLOSION HAZARD DATA Lower Explosive Limit (%) - N/E Upper Explosive Limit (%) Flash Point: >212°F (>100°C) Unusual Fire and Explosion Hazards - Some decomposition products may be harmful. N/E Extinguishing Media: Will not burn except under extreme temperatures. Water spray, carbon dioxide, dry chemical or foam. Special Fire Fighting Procedures: Wear standard fire fighting gear with self-contained breathing apparatus. ________________________________________________________________________________________________________________________ VI - REACTIVITY DATA Stability: Stable Conditions to Avoid: None known. ----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------Page 2 of 7 English Version on pages 2 and 3. Ultrabond ECO™ 575 Version Française à la pages 4 et 5. La versión en Español en las páginas 6 y 7. MSDS Page 2 de 7 Páginas 2 de 7 Incompatibility (Materials to Avoid): Strong oxidizing agents, strong acids, and strong bases. Hazard Decomposition of By-products: Carbon monoxide, carbon dioxide, oxides of nitrogen, and other unidentified organic compounds. Polymerization: Will Not Occur Conditions to Avoid: None known. ________________________________________________________________________________________________________________________ VII - HEALTH HAZARD DATA Routes of entry during normal usage: Inhalation? YES Skin? YES Ingestion? NO Health Hazards: Acute: No effects are suspected under normal professional use. Chronic: None known. Carcinogenicity: NTP - NO IARC - NO OSHA - NO Signs and Symptoms of Overexposure: No effects are suspected under normal professional use. Medical Conditions That Can Be Aggravated by Exposure: Allergies, skin and respiratory disorders. Product sensitivity. ________________________________________________________________________________________________________________________ VIII - EMERGENCY AND FIRST AID PROCEDURE Eyes: Flush with cool water for 15 minutes while holding eyelid open. If irritation persists, seek medical attention immediately. Skin: Avoid contact with skin. Remove contaminated clothing. Wash affected area thoroughly with soap and water. If irritation persists, seek immediate medical attention. Inhalation: Remove to fresh air if allowable concentrations of any of the hazardous ingredients are exceeded. If not breathing, trained personnel should initiate artificial respirations and immediate medical attention should be obtained. Ingestion: Do not induce vomiting. Do not give anything by mouth to an unconscious person. Seek medical attention immediately. ________________________________________________________________________________________________________________________ IX - PRECAUTIONS FOR SAFE HANDLING AND USE Steps to be taken if Material is Leaked or Spilled: Wear protective equipment. Contain by diking with inert absorbent materials and put into an approved waste container. Waste Disposal Method: Dispose in accordance to local environmental regulation. Precautions to be taken during Handling and Storage: Keep container closed when not in use. Store at 60-95°F (15-35°C) and out of the sun. Use adequate ventilation to avoid breathing vapors when cover is removed. Avoid prolonged skins contact. Other Precautions: _______________________________________________________________________________________________________________________ X - CONTROL MEASURES Respiratory Protection: If workplace exposure limit of product is exceeded, a NIOSH/MSHA approved air supplied respirator is required in absence of proper environmental control. Engineering or administrative controls should be implemented to reduce exposure. Local Exhaust - Use in WELL VENTILATED areas only. Mechanical - Use only intrinsically safe devices. Ventilation: Special - N/A Other - N/A Eye Protection: Safety glasses or goggles as necessary to prevent eye contact. Protective Gloves: Impervious. (Nitrile, rubber, or better) As needed to minimize contact with skin. Other Protective Equipment: _______________________________________________________________________________________________________________________ N/A="Not Applicable" N/E="Not Established" The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof. MAPEI assumes no responsibility for personal injury or property damage to vendees, users, or third parties caused by the material. Such vendees or users assume all risks associated with the use of the material. ----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------Page 3 of 7 English Version on pages 2 and 3. Ultrabond ECO™ 575 Version Française à la pages 4 et 5. La versión en Español en las páginas 6 y 7. MSDS Page 3 de 7 Páginas 3 de 7 MATERIAL SAFETY DATA SHEET HAZARD RATINGS HMIS Health 1 Flammability 0 Reactivity 0 PPE X 1 CHEMICAL PRODUCT & COMPANY IDENTIFICATION Product DP60776 MSDS Name D-650 CLEAR VCT ADH (EX LE-5000) CAS # Mixture Product Use DURABOND Flooring Adhesive Generic Description Rubber Emulsion Manufacturer BOSTIK FINDLEY, INC. 211 Boston Street Middleton , MA 01949 USA 24 Hour Emergency Assistance Phone: 1-800-227-0332 General Assistance Phone: 1-978-777-0100 Phone: 1-978-777-0100 MSDS Assistance 2 COMPOSITION / INFORMATION ON INGREDIENTS No hazardous ingredients as per 29 CFR 1910.1200. 3 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Extended contact with this material may cause irritation to the skin, eyes, and mucous membranes. POTENTIAL HEALTH EFFECTS Skin Contact: Prolonged or repeated skin contact may cause irritation. Eye Contact: May cause irritation with temporary redness with stinging and tearing. Inhalation: This product is not expected to cause respiratory tract irritation under conditions of intended use. Ingestion: Exposure is unlikely. This product can cause gastrointestinal irritation, nausea, vomiting, and diarrhea. TARGET ORGANS None known for product as a whole. 4 FIRST AID MEASURES SKIN Remove contaminated clothing to prevent further skin exposure and dispose of properly. In situations involving considerable skin contact, place the contaminated person in a deluge shower for at least 15 minutes. For minor exposures, wash thoroughly with soap and clean water. Get medical attention if irritation persists. EYE Immediately flush with plenty of water for at least 15 minutes, holding eyelids open at all times. Get medical attention immediately. MSDS Number Label Number 24126 Product DP60776 24126 NA = Not Available ND = Not Determined 1/5 INHALATION Not normally required. Remove to fresh air. Get medical attention if cough or other symptoms develop. INGESTION No harmful effect is anticipated. If ingested, get immediate medical attention. Do not induce vomiting unless instructed to do so by medical personnel. Never give anything by mouth to a victim who is unconscious or is having convulsions. NOTES TO PHYSICIAN None 5 FIRE FIGHTING MEASURES HAZARDOUS COMBUSTION PRODUCTS Decomposition can produce hazardous chemicals. Carbon monoxide, carbon dioxide, and other unknown products may be produced during combustion. EXTINGUISHING MEDIA This product is a water dispersion and as such will not burn until all water has boiled away. Residual solid and container can support combustion. Use dry chemical, carbon dioxide, water spray, or foam. DUST EXPLOSION HAZARD None Known SENSITIVITY TO MECHANICAL IMPACT None Known SENSITIVITY TO STATIC DISCHARGE None Known UNUSUAL FIRE & EXPLOSION HAZARDS During a fire, irritating and highly toxic gases may be generated during combustion or decomposition. High temperatures can cause sealed containers to rupture due to a buildup of internal pressures. Cool with water. FIRE FIGHTING EQUIPMENT/INSTRUCTIONS Firefighters should wear full protective clothing including self contained breathing apparatus. Flash Point > 200 F (> 93 C) 6 ACCIDENTAL RELEASE MEASURES EMERGENCY ACTION Appropriate safety measures and protective equipment should be used. See Section 8. Do not discharge to lakes, streams, ponds, or sewers. Dispose of in compliance with local, state, and federal regulations. CLEAN-UP PROCEDURES Scrape up the spilled material. Put material in suitable, covered, labeled containers. Wash site of spill with strong soap solution. 7 HANDLING & STORAGE For Commercial Use Only - Not Packaged or Labeled for Home Use! MSDS Number Label Number 24126 Product DP60776 24126 NA = Not Available ND = Not Determined 2/5 HANDLING Wash hands thoroughly after handling, especially before eating, drinking, smoking, and using restroom facilities. Wash contaminated goggles, face shields, and gloves. Professionally launder contaminated clothing before re-use. STORAGE Keep material from freezing. Store under normal working temperatures in a well-ventilated area. Do not pressurize drums. Avoid contact with any copper or brass. EMPTY CONTAINER PRECAUTION Attention! Follow label warnings even after container is emptied since empty containers may retain product residues. Do not reuse empty container without professional cleaning for food, clothing, or products for human or animal consumption, or where skin contact can occur. 8 EXPOSURE CONTROLS / PERSONAL PROTECTION ENGINEERING CONTROLS Local exhaust ventilation is recommended when vapors, mists, or dusts can be released. EYE PROTECTION: PERSONAL PROTECTION EQUIPMENT (PPE) Wear goggles or safety glasses with side shields. SKIN PROTECTION: PERSONAL PROTECTION EQUIPMENT (PPE) Wear protective impervious gloves to minimize skin exposure. RESPIRATORY PROTECTION: PERSONAL PROTECTION EQUIPMENT (PPE) None required where adequate ventilation conditions exist. If airborne concentrations are above the applicable exposure limits, use NIOSH approved respiratory protection. GENERAL Eyewash fountains and emergency showers should be readily available. 9 PHYSICAL & CHEMICAL PROPERTIES Boiling Point 212 F (100 C) Solubility In Water Disperses in Water Freezing Point 32 F (0 C) Density 1.028 g/cc Odor Threshold NA Octanol/Water Coefficient NA Odor Mild Color Clear Physical State Paste Freeze Protect No MSDS Number Label Number 24126 Product DP60776 24126 NA = Not Available ND = Not Determined 3/5 10 STABILITY & REACTIVITY STABILITY/INCOMPATABILITY Stable under normal conditions. Coagulation may occur following freezing, thawing, or boiling. Avoid water, amines, strong bases, alcohols and metallics hydrides. HAZARDOUS REACTIONS/DECOMPOSITION PRODUCTS If product is burned carbon monoxide, carbon dioxide, and other unknown products may be produced. HAZARDOUS POLYMERIZATION Will not occur. CONDITIONS TO AVOID None. 11 TOXICOLOGICAL INFORMATION TOXICOLOGICAL DATA If any toxicological data is available, it will be listed below: CARCINOGENICITY No regulated ingredients. 12 ECOLOGICAL INFORMATION VOC (Volatile Organic Compounds) 0 g/l ECOTOXICOLOGICAL INFORMATION No data available for this product. 13 DISPOSAL CONSIDERATIONS We make no guarantee or warranty of any kind that the use or disposal of this product complies with all local, state, or federal laws. It is also the obligation of each user of the product mentioned herein to determine and comply with the requirements of all applicable statutes. WASTE DISPOSAL This product as supplied is not considered a hazardous waste under RCRA. Liquid adhesive should not be disposed of in a landfill. Do not discharge to streams, lakes, ponds, or sewers. Disposal of unused portions of this product and process waste containing this product should be done only after a careful evaluation and in compliance with all federal, local, and state laws. 14 TRANSPORT INFORMATION Proper Shipping Name Hazard Class Non-Regulated Not Applicable 15 REGULATORY INFORMATION All components are on the U.S. EPA TSCA Inventory List. This MSDS is prepared and distributed pursuant to the Federal Hazard Communication Standard, 29 CFR 1910.1200. MSDS Number Label Number 24126 Product DP60776 24126 NA = Not Available ND = Not Determined 4/5 STATE REGULATIONS If this product contains any ingredients listed under California Proposition 65, they will be noted below: California - Prop. 65 - Cancer list 1,3-BUTADIENE 1,4-DIOXANE SILICA, QUARTZ 106-99-0 carcinogen; initial date 4/1/88 123-91-1 carcinogen; initial date 1/1/88 14808-60-7 carcinogen (airborne particles of respirable size); initial date 10/1/88 INTERNATIONAL REGULATIONS This is not a controlled product under the Canadian Workplace Hazardous Materials Information System (WHMIS). This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and contains all the information required by the Controlled Products Regulations. SARA 302 EXTREMELY HAZARDOUS SUBSTANCES Not Regulated SARA 311/312 HAZARD CATEGORIES Immediate Hazard No Delayed Hazard No Fire Hazard No Pressure Hazard No Reactivity Hazard No SARA 313 TOXIC CHEMICALS Not Regulated 16 OTHER INFORMATION DISCLAIMER The data in this MSDS has been compiled from publicly available sources. This data relates only to the designated product and not to the use of said product in combination with other materials. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Responsibility for proper precautions and safe use of the product lies with the user. All data in this MSDS is typical of the product as a whole, and does not represent any individual lot or batch, therefore, Bostik Findley, Inc. makes no warranty about the accuracy of the data herein and assumes no liability for the use of such data. It is the responsibility of the user to comply with all applicable federal, state, and local laws and regulations. Issue Date 01-Jul-2002 Supercedes 11-Feb-2002 Prepared By Aurora Flores MSDS Sections Reviewed and/or Updated Chemical Product & Company Identification: Product & Company Identification MSDS Number Label Number 24126 Product DP60776 24126 NA = Not Available ND = Not Determined 5/5 Material Safety Data Sheet 456 TYPE I DUAL PURPOSE FLOOR AND WALL CERAMIC MASTIC I. PRODUCT IDENTIFICATION Number: 456 Name: APAC Type I Dual Purpose Floor and Wall Ceramic Mastic Class: Acrylic Emulsion Latex Adhesive Emergency Telephone CHEMTREC: 800-424-9300 II. HMIS (0=minimal hazard; 4= severe) Health = 1 Flammability = 0 Reactivity = 0 Pers. Prot. Equip: B III. HAZARDOUS INGREDIENTS Ingredient (CAS #) Percent: Occ. Exp. Lmt. PEL TLV Units Mineral Spirits <4% 100 100 ppm (8052-41-3) IV. PHYSICAL DATA BOILING RANGE: 212˚F. VAPOR PRESSURE: heavier than air. EVAPORATION RATE: slower than ether. WT/GAL.: 12.85 lbs. VOC: 56 gram/liter wet; 35 gram/liter dry coating solids. Percent Solids: 70.5% Non-Photochemically Reactive. V. FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION: Nonflammable. FLASH POINT: >140˚F. EXTINGUISHING MEDIA: Does not support combustion in wet state. EXTINGUISHING MEDIA: For dry adhesive – Foam, CO2, Dry Chemical, Water Fog. UNUSUAL FIRE AND EXPLOSION HAZARDS: none. SPECIAL FIRE FIGHTING PROCEDURES: Self contained positive pressure breathing apparatus. VI. HEALTH HAZARD DATA Product not considered carcinogenic by NPT, IARC, or OSHA. EFFECTS OF OVEREXPOSURE: May cause irritation to eyes, skin, and respiratory tract if inhaled. Ingestion: Ethylene Glycol can cause gastrointestinal distress, nausea, vomiting, diarrhea, and in sufficient quantities death. PRIMARY ROUTES OF ENTRY: inhalation and ingestion. MEDICAL CONDITIONS PRONE TO AGGRAVATION BY EXPOSURE: none know. EMERGENCY FIRST AID PROCEDURES: Eye Contact – flush eye with water for 15 minutes. Skin Contact – wash thoroughly with soap and water. Inhalation – remove to fresh air, give oxygen. Contact physician or poison control center immediately. Ingestion – if swallowed, DO NOT induce vomiting. VII. REACTIVITY DATA STABILITY: Stable. CONDITION TO AVOID: Excessive heat or freezing temperatures. INCOMPATIBILITY: (Materials to avoid) Strong oxidizers, acids, and alkalis. VIII. SPILL OR LEAK PROCEDURES SPILLS: Scrape up excess and place in DOT approved container. Remove to safe place where material can dry. WASTE DISPOSAL METHOD: Dispose of as per local, state and federal regulations. Do not flush adhesive down drains. IX. SPECIAL PROTECTION INFORMATION: VENTILATION: Use with adequate ventilation. Open doors and windows to create cross ventilation during use and until adhesive dries. PROTECTIVE GLOVES: Use chemical-resistant gloves if needed to avoid repeated or prolonged skin contact. EYE PROTECTION: Use splash goggles or face shield when eye contact may occur. OTHER PROTECTIVE CLOTHING OR EQUIPMENT: None required. WORK / HYGIENIC PRACTICES: Thorough washing of the skin with soap and water. IX. SPECIAL PRECAUTIONS: HANDLING AND STORING: Avoid extreme heat or cold. OTHER PRECAUTIONS: Keep out of reach of children. Use only as directed on label. Close container after each use. Do not reuse container. Avoid skin and eye contact. X. TRANSPORTATION DATA D.O.T.: unregulated SHIPPING NAME: Adhesive APAC believes that data set forth herein is accurate as of the date hereof, and makes no warranty with respect thereto and expressly disclaims all liability for reliance thereon. Such data are offered solely for your consideration, investigation and verification. N/A not applicable or not available N/K none known or not known 02-23-05 www.apacadhesives.com All Purpose Adhesive Company • 2424 Lakeland Road • Dalton, GA 30721 • 800-747-APAC • Fax: 706-277-4157 MATERIAL SAFETY DATA SHEET Date Prepared: September 29, 2005 1. PRODUCT/COMPANY IDENTIFICATION Product Name: Bonsal ® Superior Unsanded Tile Grout (Various Colors) Emergency Telephone: 800-424-9300 (Chemtrec) or 703-527-3887 (Outside USA) Manufacturer’s Name & Address: Bonsal American/ an Oldcastle Company 8201 Arrowridge Blvd. Charlotte, NC 28273 Telephone Number for Information: 704-525-1621 2. EMERGENCY AND FIRST AID EMERGENCY INFORMATION: Bonsal® Superior Unsanded Tile Grout is a cementitious powder blend. When in contact with moisture in eyes or on skin, or when mixed with water, it becomes highly caustic (pH > 12) and will damage or burn (as severely as third-degree) the eyes or skin. Inhalation may cause irritation to the moist mucous membranes of the nose, throat and upper respiratory system or may cause or may aggravate certain lung diseases or conditions. Use exposure controls or personal protection methods described in Section 12. EYES: Immediately flush eye thoroughly with water. Continue flushing eye for at least 15 minutes, including under lids, to remove all particles. Call physician immediately. SKIN: Wash skin with cool water and pH-neutral soap or a mild detergent. Seek medical treatment if irritation or inflammation develops or persists. Seek immediate medical treatment in the event of burns. INHALATION: Remove person to fresh air. If breathing is difficult, administer oxygen. If not breathing, give artificial respiration. Seek medical help if coughing and other symptoms do not subside. Inhalation of large amounts of Bonsal ® Superior Unsanded Tile Grout require immediate medical attention. INGESTION: Do not induce vomiting. If conscious, have the victim drink plenty of water and call a physician immediately. 10/5/2005 Bonsal® Superior Unsanded Tile Grout Page 1 of 6 3. COMPOSITION INFORMATION DESCRIPTION: This product consists of a heterogeneous mixture of hydraulic cement and sand. The major compounds are: 3CaO•SiO2 2CaO•SiO2 3CaO•Al2O3 4CaO•Al2O3•Fe2O3 CaSO4•2H2O SiO2 Tricalcium Silicate Dicalcium Silicate Tricalcium Aluminate Tetracalcium aluminoferrite Calcium Sulfate dihydrate (Gypsum) Silica Sand CAS #12168-85-3 CAS #10034-77-2 CAS #12042-78-3 CAS #12068-35-8 CAS #7778-18-9 (CAS #13397-24-5) CAS #14808-60-7 4. HAZARDOUS INGREDIENTS COMPONENT OSHA PEL ACGIH TLV-TWA NIOSH REL -------------------Hydraulic Cement ------------------------5 mg respirable dust/m3 15 mg total dust/m3 -----------------------10 mg total dust/m3 ------------------------ Calcium sulfate (CAS #7778-189) [Gypsum (CAS #13397-24-5)] 5 mg respirable dust/m3 15 mg total dust/m3 10 mg total dust/m3 _________ 0.5 mg/m3 Iron oxide , Mineral Oxides, and/or Carbon Black Calcium carbonate (CAS #131765-3) Magnesium oxide (CAS #130948-4) Calcium oxide (CAS #1306-78-8) Crystalline silica (CAS #1480860-7) 5 mg respirable dust/m3 15 mg total dust/m3 10 mg total dust/m3 15 mg total dust/m3 10 mg total dust/m3 5 mg/m3 2 mg/m3 10 mg of respirable dust/m3 % SiO2 + 2 0.5 mg respirable quartz/m3 0.05 mg respirable quartz dust/m3 TRACE INGREDIENTS: Due to the use of substances mined from the earth’s crust, trace amounts of naturally occurring, potentially harmful constituents may be detected during chemical analysis. 10/5/2005 Bonsal® Superior Unsanded Tile Grout Page 2 of 6 5. HAZARD IDENTIFICATION POTENTIAL HEALTH EFFECTS: NOTE: Potential health effects may vary depending upon the duration and degree of exposure. To reduce or eliminate health hazards associated with this product, use exposure controls or personal protection methods as described in Section 12. EYE CONTACT: (Acute/Chronic) Exposure to airborne dust may cause immediate or delayed irritation or inflammation of the cornea. Eye contact by larger amounts of dry powder or splashes of wet Unsanded Tile Grout may cause effects ranging from moderate eye irritation to chemical burns and blindness. SKIN CONTACT: (Acute) Exposure to dry Bonsal® Superior Unsanded Tile Grout may cause drying of the skin with consequent mild irritation or more significant effects attributable to aggravation of other conditions. Discomfort or pain cannot be relied upon to alert a person to a hazardous skin exposure. (Chronic) Dry Bonsal® Superior Unsanded Tile Grout coming in contact with wet skin or exposure to wet Unsanded Tile Grout may cause more severe skin effects, including thickening, cracking or fissuring of the skin. Prolonged exposure can cause severe skin damage in the form of chemical (caustic) burns. (Acute/Chronic) Some individuals may exhibit an allergic response upon exposure to Bonsal® Superior Unsanded Tile Grout . The response may appear in a variety of forms ranging from a mild rash to severe skin ulcers. INHALATION: (Acute) Exposure to Bonsal® Superior Unsanded Tile Grout may cause irritation to the moist mucous membranes of the nose, throat and upper respiratory system. Pre-existing upper respiratory and lung diseases may be aggravated by inhalation. (Chronic) Inhalation exposure to free crystalline silica may cause delayed lung injury including silicosis, a disabling and potentially fatal lung disease, and/or cause or aggravate other lung diseases or conditions. INGESTION: (Acute/Chronic) Internal discomfort or ill effects are possible if large quantities are swallowed. CARCINOGENIC POTENTIAL: Bonsal® Superior Unsanded Tile Grout is not recognized as a carcinogen by NTP, OSHA, or IARC. However, it may contain trace amounts of heavy metals recognized as carcinogens by these organizations. In addition, it also contains crystalline silica which IARC classifies as a known human carcinogen (Group I). The NTP, in it’s ninth Annual Report on Carcinogens, classified “silica, crystalline (respirable)” as a known carcinogen. (See also Sections 4 and 12.) 10/5/2005 Bonsal® Superior Unsanded Tile Grout Page 3 of 6 6. ACCIDENTAL RELEASE MEASURES Contain material to prevent contamination of soil, surface water or ground water. Use dry clean-up methods that do not disperse dust into the air or entry into surface water. Material can be used if not contaminated. Place in an appropriate labeled container for disposal or use. Avoid inhalation of dust and contact with skin and eyes. Use exposure control and personal protection methods as described in Section 12. 7. PHYSICAL/CHEMICAL DATA APPEARANCE/ODOR: Gray, odorless PHYSICAL STATE: Solid (Powder mixed with sand.) BOILING POINT: > 1000°C MELTING POINT: > 1000°C VAPOR PRESSURE: Not applicable VAPOR DENSITY: Not applicable pH (IN WATER) (ASTM D 1293-95) 12 to 13 SOLUBILITY IN WATER: Slightly soluble (0.1% to 1.0%) SPECIFIC GRAVITY (H2O = 1.0): 2.5 – 2.8 EVAPORATION RATE: None 8. FIRE AND EXPLOSION FLASH POINT: None LOWER EXPLOSIVE LIMIT: None AUTO IGNITION TEMPERATURE: Not combustible UPPER EXPLOSIVE LIMIT: None FLAMMABLE LIMITS Not applicable SPECIAL FIRE FIGHTING PROCEDURES: None EXTINGUISHING MEDIA: Not combustible UNUSUAL FIRE AND EXPLOSION HAZARDS: None HAZARDOUS COMBUSTION PRODUCTS: None 9. STABILITY AND REACTIVITY DATA STABILITY: Product is stable. Keep dry until used. CONDITIONS TO AVOID: Unintentional contact with water. Contact with water will result in hydration and produces (caustic) calcium hydroxide. INCOMPATIBILITY: Wet Unsanded Tile Grout is alkaline. As such, it is incompatible with acids, ammonium salts and aluminum metal. HAZARDOUS DECOMPOSITION: Will not occur. HAZARDOUS POLYMERIZATION: Will not occur. 10/5/2005 Bonsal® Superior Unsanded Tile Grout Page 4 of 6 10. PRECAUTIONS FOR HANDLING AND STORAGE Keep dry until used. Handle and store in a manner so that airborne dust does not exceed applicable exposure limits. Use adequate ventilation and dust collection. Use exposure control and personal protection methods as described in Section 12. HANDLING AND STORAGE 11. TOXICOLOGICAL INFORMATION See Section 5 for Hazard Identification. No recognized unusual toxicity to plants and animals. Conditions aggravated by exposure: Eye disease, Skin disorders and Chronic Respiratory conditions. 12. EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION: Use local exhaust or general dilution ventilation to control dust levels below applicable exposure limits. Minimize dispersal of dust into the air. If local or general ventilation is not adequate to control dust levels below applicable exposure limits or when dust causes irritation or discomfort, use MSHA/NIOSH approved respirators. EYE PROTECTION: Wear safety glasses with side shields or goggles to avoid contact with the eyes. In extremely dusty environments and unpredictable environments, wear tight-fitting unvented or indirectly vented goggles to avoid eye irritation or injury. Contact lenses should not be worn when handling cement or cement containing products. SKIN PROTECTION: Wear impervious abrasion- and alkali-resistant gloves, boots, long-sleeved shirt, long pants or other protective clothing to prevent skin contact. Promptly remove clothing dusty with dry Unsanded Tile Grout or clothing dampened with moisture mixed with Unsanded Tile Grout, and launder before re-use. If contact occurs, wash areas contacted by material with pH neutral soap and water. 13. DISPOSAL CONSIDERATIONS DISPOSAL: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal methods must be in compliance with all Federal, State/ Provincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. IF THIS MATERIAL AS PACKAGED, BECOMES A WASTE, IT DOES NOT MEET THE CRITERIA FOR A HAZARDOUS WASTE AS DEFINED BY THE ENVIRONMENTAL PROTECTION AGENCY UNDER THE AUTHORITY OF THE RESOURCE CONSERVATION AND RECOVER ACT (40CFR 261), DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. 10/5/2005 Bonsal® Superior Unsanded Tile Grout Page 5 of 6 Comply with all applicable local, state and federal regulations for disposal of unusable or contaminated materials. Dispose of packaging/containers according to local, state and federal regulations. 14. TRANSPORTATION DATA Bonsal® Superior Unsanded Tile Grout is not hazardous under U.S. DOT or TDG regulations. 15. OTHER REGULATORY INFORMATION Status under US OSHA Hazard Communication Rule 29 CFR 1910.1200: Bonsal® Superior Unsanded Tile Grout is considered a hazardous chemical under this regulation and should be included in the employer's hazard communication program. Status under CERCLA/Superfund, 40 CFR 117 and 302: Not listed. Hazard Category under SARA (Title III), Sections 311 and 312: Bonsal® Superior Unsanded Tile Grout qualifies as a hazardous substance with delayed health effects. Status under SARA (Title III), Section 313: Not subject to reporting requirements under Section 313. Status under TSCA (as of May 1997): Some substances in Bonsal® Superior Unsanded Tile Grout are on the TSCA inventory list. Status under the Federal Hazardous Substances Act: Bonsal® Superior Unsanded Tile Grout is a hazardous substance subject to statutes promulgated under the subject act. Status under California Proposition 65: This product contains crystalline silica, a substance known to the State of California to cause cancer. This product also may contain trace amounts of heavy metals known to the State of California to cause cancer, birth defects or other reproductive harm. Status under Canadian Environmental Protection Act: Not listed. Status under Canadian WHMIS: Bonsal® Superior Unsanded Tile Grout is considered to be a hazardous material under the Hazardous Products Act as defined by the Controlled Products Regulations (Class D2A, E Corrosive Material) and subject to the requirements of WHMIS. 16. OTHER INFORMATION The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, express or implied, is made with respect to the information contained herein. It is the user’s obligation to determine the conditions of safe use of this product. 10/5/2005 Bonsal® Superior Unsanded Tile Grout Page 6 of 6 Material Safety Data Sheet SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: SYNONYMS: PRODUCT CODES: Moldstat Peroxy Kling Cleaning Compound 100354 MANUFACTURER: ADDRESS: Theochem Laboratories Inc 7373 Rowlett Park Drive Tampa, FL 33610-1141 EMERGENCY PHONE: ChemTel: North America: 1-800-255-3924 International: +01-813-248-0585 CHEMICAL NAME: CHEMICAL FAMILY: CHEMICAL FORMULA: PRODUCT USE: PREPARED BY: REVISION NUMBER: MSDS REVISION DATE: Hydrogen Peroxide Mixture NA NA Cleaning TGD 1.2 10/07/2010 SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS The product contains non-hazardous or trade-secret components. INGREDIENT: Hydrogen Peroxide CAS NO. % WT 7722-84-1 <4 % VOL ppm mg/m3 OSHA PEL-TWA: OSHA PEL STEL: OSHA PEL CEILING: 1 ppm NA NA NA NA NA ACGIH TLV-TWA: ACGIH TLV STEL: ACGIH TLV CEILING: 1 ppm NA NA NA NA NA SARA 313 REPORTABLE NA No No Ingestion: Unlikely SECTION 3: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: ROUTE(S) OF ENTRY: POTENTIAL HEALTH EFFECTS SHORT TERM/ACUTE EXPOSURE: Eyes: Yes EYES: Inhalation: Unlikely Skin: Causes irritation, redness, and pain. SKIN: No adverse effects expected on intact skin. Contact on burn or open skin may cause stinging pain or irritation. INHALATION: Not expected to be a health hazard under normal conditions. INGESTION: Large oral doses may cause irritation and blistering to the mouth, throat, and abdomen. May also cause abdominal pain, vomiting, and diarrhea. CHRONIC HEALTH HAZARDS: CARCINOGENICITY: No further data known NTP: NO ARC Monographs: NO MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: None OSHA Regulated: NO known SECTION 4: FIRST AID MEASURES Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. EYES: SKIN: Not expected to require first aid measures. Wash exposed area with soap and water. Get medical advice if irritation develops. INGESTION: Give several glasses of water to drink to dilute. If large amounts were swallowed, get medical advice. INHALATION: Not expected to require first aid measures. NOTES TO PHYSICIANS OR FIRST AID PROVIDERS: No further data known SECTION 5: FIRE-FIGHTING MEASURES FIRE AND EXPLOSIVE PROPERTIES: Not considered to be a fire hazard. Concentrated hydrogen peroxide (30%) is a strong oxidizer, but this dilute product does not present that hazard. Not considered to be an explosion hazard. Drying of concentrated hydrogen peroxide on clothing or other combustible materials may cause fire or explosion. FLAMMABLE LIMITS IN AIR, UPPER: (% BY VOLUME) LOWER: None None FLASH POINT: (Closed FLAMMABLE LIMITS: None None Cup): AUTOIGNITION TEMPERATURE: None Known NFPA HAZARD CLASSIFICATION HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 1 HMIS HAZARD CLASSIFICATION FLAMMABILITY: HEALTH: 1 REACTIVITY: 1 EXTINGUISHING MEDIA: Use 0 OTHER: NA PROTECTION: NA any means suitable for extinguishing surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES: In the event of a fire, wear full protective clothing and NIOSH-approved selfcontained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. UNUSUAL FIRE AND EXPLOSION HAZARDS: None HAZARDOUS DECOMPOSITION PRODUCTS: None SECTION 6: ACCIDENTAL RELEASE MEASURES Stop spill or leak if it can be done safely. Contain spill to smallest possible area. Large spills should be recovered for disposal. Waste materials should be disposed of in accordance with all local, state and federal regulations. Transfer contaminated absorbent, soil and other materials to containers for disposal CLEAN-UP MEASURES: SECTION 7: HANDLING AND STORAGE HANDLING: As with any chemical, handle the product in a manner that minimizes exposure to practicable levels. Prior to handling, consult Section 8 of this MSDS to evaluate personal protective equipment needs. Open Page 2 of 5 Product Name: Moldstat Peroxy Kling containers slowly to relieve any pressure. Follow all other standard industrial hygiene practices. Empty containers may contain product residue. All safety precautions taken when handling this product should also be taken when handling empty drums and containers. Keep containers closed when not in use. STORAGE: Store in a cool, dry area away from combustibles and reactive chemicals. Store away from sources of ignition. Do not store at temperatures above 120 oF. OTHER PRECAUTIONS: For Industrial & Institutional use only. _________________________________________________________________________________________________________________ SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: Normal general ventilation is expected to be adequate. It is recommended that ventilation be designed in all instances to maintain airborne concentrations at lowest practicable levels. RESPIRATORY PROTECTION: Not expected to require personal respirator usage. EYE PROTECTION: Wear protective eyewear to prevent accidental exposure. SKIN PROTECTION: Gloves are for prolonged use. OTHER PERSONAL PROTECTIVE EQUIPMENT: Selection of personal protective equipment should be based upon the anticipated exposure and made in accordance with OSHA's Personal Protective Equipment Standard found in 29 CFR 1910 Subpart I. HYGIENIC PRACTICES: Wash hands after use. Keep containers closed when not in use. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear, Viscous Liquid ODOR: Citrus Odor PHYSICAL STATE: Liquid pH AS SUPPLIED: 6.0 – 7.0 BOILING POINT: 210 - 212 oF MELTING POINT: NA FREEZING POINT: NA VAPOR PRESSURE (mmHg): Same as water VAPOR DENSITY (AIR = 1): Same as water SPECIFIC GRAVITY): 1.01 – 1.02 EVAPORATION RATE: < 1 (BuAc = 1) SOLUBILITY IN WATER: Complete PERCENT SOLIDS BY WEIGHT: NA PERCENT VOLATILE: NA MOLECULAR WEIGHT: Mixture VISCOSITY: NA Page 3 of 5 Product Name: Moldstat Peroxy Kling SECTION 10: STABILITY AND REACTIVITY STABILITY: Product is Stable under normal conditions. CONDITIONS TO AVOID (STABILITY): Do not mix with any other chemicals. INCOMPATIBILITY (MATERIAL TO AVOID): Alkalis HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: On HAZARDOUS POLYMERIZATION: Will incineration, residue will produce oxygen. not occur CONDITIONS TO AVOID (POLYMERIZATION): Will not polymerize SECTION 11: TOXICOLOGICAL INFORMATION EYE EFFECTS: No further toxicological data known. SKIN EFFECTS: No ORAL EFFECTS: further toxicological data known. No further toxicological data known. INHALATION EFFECTS: OTHER: No further toxicological data known. No further data known. SECTION 12: ECOLOGICAL INFORMATION____________________________________________________________________________ ECOTOXICOLOGICAL INFORMATION: This product has not been evaluated for ecotoxicity. As with any industrial chemical, exposure to the environment should be prevented and minimized wherever possible. ENVIRONMENTAL FATE: Not Known SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: Ensure that collection, transport, treatment, and disposal of waste product, containers and rinsate complies with all applicable laws and regulations. Note that use, mixture, processing, or contamination of the product may cause the material to be classified as a hazardous waste. It is the responsibility of the product user or owner to determine at the time of disposal, whether the product is regulated as a hazardous waste. RCRA HAZARD CLASS: NA SECTION 14: TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION PROPER SHIPPING NAME: HAZARD CLASS: ID NUMBER: PACKING GROUP: LABEL STATEMENT: Cleaning Compound Liquid, Not Regulated None NA NA Caution WATER TRANSPORTATION Not regulated AIR TRANSPORTATION Not regulated OTHER AGENCIES: Not regulated Page 4 of 5 Product Name: Moldstat Peroxy Kling SECTION 15: REGULATORY INFORMATION U.S. FEDERAL REGULATIONS SARA 313: This product contains none of the substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. CLEAN WATER ACT / OIL POLLUTION ACT: This product contains none of the chemicals subject to regulation by Section 311 of the Clean Water Act and the Oil Pollution Act. Releases of the product into or leading to surface waters must be reported to the National Response Center at 1-800-424-8802. CERCLA REPORTABLE QUANTITY: Any components listed below have been assigned a reportable quantity (RQ) by the Federal EPA. Release of the product into the environment that exceed the RQ for a particular component must be reported to the National Response Center at 1-800-424-8802. COMPONENT: None TOXIC SUBSTANCES CONTROL ACT: The OZONE DEPLETING SUBSTANCES: This components of this product are listed on the TSCA Inventory. product contains no ozone depleting substances as defined by the Clean Air Act. HAZARDOUS AIR POLLUTANTS: Any components COMPONENT: air pollutants. STATE REGULATIONS: Check listed below are defined by the Federal EPA as hazardous None with the appropriate state agency to determine whether regulations exists. INTERNATIONAL REGULATIONS: NA SECTION 16: OTHER INFORMATION PREPARED BY: Department of Regulatory Compliance DATE OF ISSUE: 8/4/06 DATE OF LAST REVISION: 10/07/2010 We believe the information given is accurate. It is offered in good faith, but without guarantee. Since conditions are beyond our control, user assumes all responsibility and risk. Page 5 of 5 Product Name: Moldstat Peroxy Kling Material Safety Data Sheet SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: SYNONYMS: PRODUCT CODES: Moldstat Plus NA 100352 EPA REG. NUMBER: 10324-72-9367 MANUFACTURER: ADDRESS: Theochem Laboratories Inc 7373 Rowlett Park Drive Tampa, FL 33610-1141 EMERGENCY PHONE: ChemTel: North America: 1-800-255-3924 International: +01-813-248-0585 CHEMICAL NAME: CHEMICAL FAMILY: CHEMICAL FORMULA: PRODUCT USE: PREPARED BY: REVISION NUMBER: MSDS REVISION DATE: Mixture NA NA Disinfectant, Mildewstat and Fungicide TGD 1.3 10/03/2012 SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS The product may contain additional non-hazardous or trade-secret components. INGREDIENT: CAS NO. ALKYL (C12 , -C16) DIMETHLY BENZYL AMMONIUM CHLORIDE OCTYL DECYL DIMETHYL AMMONIUM CHLORIDE DIOCTYL DIMETHYL AMMONIUM CHLORIDE DIDECYL DIMETHYL AMMONIUM CHLORIDE SODIUM METASILICATE % WT % VOL 68424-85-1 8.68% NA No 32426-11-2 6.51% NA No 5538-94-3 3.26% NA No 7173-51-5 6834-92-0 3.25% 1.5% NA NA No No ALKYL (C12 , -C16) DIMETHYL BENZYL AMMONIUM CHLORIDE ppm mg/m3 OSHA PEL-TWA: OSHA PEL STEL: OSHA PEL CEILING: NA NA NA NA NA NA ACGIH TLV-TWA: ACGIH TLV STEL: ACGIH TLV CEILING: NA NA NA NA NA NA OCTYL DECYL DIMETHLY AMMONIUM CHLORIDE OSHA PEL-TWA: OSHA PEL STEL: OSHA PEL CEILING: ppm mg/m3 400 ppm NA NA NA NA NA SARA 313 REPORTABLE NA NA NA ACGIH TLV-TWA: ACGIH TLV STEL: ACGIH TLV CEILING: NA NA NA DIOCTYL DIMETHYL AMMONIUM CHLORIDE ppm mg/m3 OSHA PEL-TWA: OSHA PEL STEL: OSHA PEL CEILING: NA NA NA NA NA NA ACGIH TLV-TWA: ACGIH TLV STEL: ACGIH TLV CEILING: NA NA NA NA NA NA SODIUM METASILICATE ppm mg/m3 OSHA PEL-TWA: OSHA PEL STEL: OSHA PEL CEILING: NA NA NA 2 mg/M3 NA NA ACGIH TLV-TWA: ACGIH TLV STEL: ACGIH TLV CEILING: NA NA NA 2 mg/M3 NA NA SECTION 3: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: ROUTE(S) OF ENTRY: POTENTIAL HEALTH EFFECTS SHORT TERM/ACUTE EXPOSURE: Inhalation: Eyes: Yes EYES: Yes Skin: Yes Ingestion: Unlikely Causes burns and may result in permanent injury to eyes including blindness. SKIN: Causes corrosive burns. Brief exposures may cause irritation and defatting of the skin. Exposures not promptly washed off may lead to toxic effects similar to ingestion. Harmful if absorbed through skin. INHALATION: Mists and vapors can irritate the throat and respiratory tract. High vapor concentrations may cause central nervous system effects. Symptoms may include headaches, dizziness, and drowsiness. Harmful if inhaled. INGESTION: Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea and possibly death. Harmful if swallowed. CHRONIC HEALTH HAZARDS: CARCINOGENICITY: No further data known NTP: No ARC Monographs: No MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: OSHA Regulated: No Pre-existing eye, skin and respiratory disorders. SECTION 4: FIRST AID MEASURES Flush with large amounts of running water for at least 15 minutes while holding upper and lower lids open. Remove contact lenses of present after the first 5 minutes, then continue rinsing eye. Seek medical attention immediately. EYES: Page 2 of 6 Product Name:Moldstat Plus SKIN: Remove contaminated clothing immediately. launder before rewearing. Wash exposed area with soap & water. Seek medical attention. INGESTION: Drink promptly, a large quantity of water. Do not give anything by mouth to an unconscious person. Seek immediate medical attention or contact poision control center. INHALATION: If symptoms are experienced, move to fresh air. Get medical attention if irritation persists. If person is not breathing call 911 or an ambulance, then give artificial respiration (CPR). NOTES TO PHYSICIANS OR FIRST AID PROVIDERS: Probable mucosal damage may contraindicate the use of gastric lavage. SECTION 5: FIRE-FIGHTING MEASURES FIRE AND EXPLOSIVE PROPERTIES: . FLAMMABLE LIMITS IN AIR, UPPER: (% BY VOLUME) LOWER: Not Established Not Established FLASH POINT: (Closed FLAMMABLE LIMITS: Over 200 oF (over 94o C) Not Established Cup): AUTOIGNITION TEMPERATURE: None Known NFPA HAZARD CLASSIFICATION HEALTH: 2 FLAMMABILITY: 1 REACTIVITY: 0 HMIS HAZARD CLASSIFICATION FLAMMABILITY: 1 HEALTH: 2 REACTIVITY: 0 EXTINGUISHING MEDIA: Foam, OTHER: NA PROTECTION: NA CO2, Water Fog, Dry Chemical. Solid water streams may spread burning liquid. SPECIAL FIRE FIGHTING PROCEDURES: Liquid is soluable in water & easily diluted. UNUSUAL FIRE AND EXPLOSION HAZARDS: HAZARDOUS DECOMPOSITION PRODUCTS: Irritating and toxic gases or fumes may be released during a fire. SECTION 6: ACCIDENTAL RELEASE MEASURES CLEAN-UP MEASURES: Stop spill or leak if it can be done safely. Contain spill to smallest possible area. Large spills should be recovered for disposal. Waste materials should be disposed of in accordance with all local, state and federal regulations. Transfer contaminated absorbent, soil and other materials to containers for disposal SECTION 7: HANDLING AND STORAGE HANDLING: As with any chemical, handle the product in a manner that minimizes exposure to practicable levels. Prior to handling, consult Section 8 of this MSDS personal protective equipment needs. Open containers slowly to relieve any pressure. Follow all other standard industrial hygiene practices. Empty containers may contain product residue. All safety precautions taken when handling this product should also be taken when handling empty containers. STORAGE: Store in a cool, dry area away from combustibles and reactive chemicals. Store away from sources of ignition. OTHER PRECAUTIONS: For Industrial & Institutional use only. _________________________________________________________________________________________________________________ SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: Normal general ventilation is expected to be adequate. It is recommended that ventilation be designed in all instances to maintain airborne concentrations at lowest practicable levels. The user may wish to refer to 29 CFR 1910.1000(d)(2) and the ACGIH "Threshold Limit Values for Chemical Substances and Page 3 of 6 Product Name:Moldstat Plus Physical Agents Biological Exposure Indicies" (Appendix C) for the determination of exposure limits of mixtures. An industrial hygienist or similar professional may be consulted to confirm that the calculated exposure limits apply. RESPIRATORY PROTECTION: Provide adequate local exhaust ventilation. None needed unless TLV is exceeded. If irritation is experienced a NIOSH approved respirator maybe necessary. EYE PROTECTION: Wear appropriate protective eyewear to prevent accidental exposure. Safety glasses with side shields, chemical goggles or face shield. SKIN PROTECTION: Rubber or Neoprene Selection of personal protective equipment should be based upon the anticipated exposure and made in accordance with OSHA's Personal Protective Equipment Standard found in 29 CFR 1910 Subpart I OTHER PERSONAL PROTECTIVE EQUIPMENT: HYGIENIC PRACTICES: Wash hands after use. Keep containers closed when not in use. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Green Liquid ODOR: Floral Odor PHYSICAL STATE: Liquid pH AS SUPPLIED: 13.0 + 0.3 BOILING POINT: NA MELTING POINT: Liquid FREEZING POINT: Not established VAPOR PRESSURE (mmHg): Same as water VAPOR DENSITY (AIR = 1): 8.33 SPECIFIC GRAVITY): 1.04 EVAPORATION RATE: NA SOLUBILITY IN WATER: Complete PERCENT SOLIDS BY WEIGHT: Not established PERCENT VOLATILE BY WEIGHT: Not established MOLECULAR WEIGHT: Mixture VISCOSITY: Not Established SECTION 10: STABILITY AND REACTIVITY STABILITY: Product is Stable CONDITIONS TO AVOID (STABILITY): High Temperatures. INCOMPATIBILITY (MATERIAL TO AVOID): Strong Oxidizers. HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: Toxic hydrogen chloride, oxides of carbon & nitrogen. Page 4 of 6 Product Name:Moldstat Plus HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID (POLYMERIZATION): Will not polymerize. SECTION 11: TOXICOLOGICAL INFORMATION EYE EFFECTS: No further toxicological data known. SKIN EFFECTS:No ORAL EFFECTS: further toxicological data known. No further toxicological data known. INHALATION EFFECTS: OTHER: No further toxicological data known. No further data known. SECTION 12: ECOLOGICAL INFORMATION____________________________________________________________________________ This product has not been evaluated for ecotoxicity. As with any industrial chemical, exposure to the environment should be prevented and minimized wherever possible. ECOTOXICOLOGICAL INFORMATION: ENVIRONMENTAL FATE: Unknown SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: Ensure that collection, transport, treatment, and disposal of waste product, containers and rinsate complies with all applicable laws and regulations. Note that use, mixture, processing, or contamination of the product may cause the material to be classified as a hazardous waste. It is the responsibility of the product user or owner to determine at the time of disposal, whether the product is regulated as a hazardous waste. RCRA HAZARD CLASS: NA SECTION 14: TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION PROPER SHIPPING NAME: HAZARD CLASS: ID NUMBER: PACKING GROUP: EXCEPTIONS: 1 gallon LABEL STATEMENT: WATER TRANSPORTATION AIR TRANSPORTATION OTHER AGENCIES: and 1 quart bottles Disinfectant, Corrosive, Liquids, (Contains Quaternary Ammonium Compounds) Class 8 NA1903 PG III 173.154 Limited Quantity Danger Not applicable Not applicable Not regulated SECTION 15: REGULATORY INFORMATION U.S. FEDERAL REGULATIONS SARA 313: This product contains none of the substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. CLEAN WATER ACT / OIL POLLUTION ACT: This product contains none of the chemicals subject to regulation by Section 311 of the Clean Water Act and the Oil Pollution Act. Releases of the product into or leading to surface waters must be reported to the National Response Center at 1-800-424-8802. Page 5 of 6 Product Name:Moldstat Plus CERCLA REPORTABLE QUANTITY: Any components listed below have been assigned a reportable quantity (RQ) by the Federal EPA. Release of the product into the environment that exceed the RQ for a particular component must be reported to the National Response Center at 1-800-424-8802. COMPONENT: None TOXIC SUBSTANCES CONTROL ACT: The OZONE DEPLETING SUBSTANCES: This components of this product are listed on the TSCA Inventory. product contains no ozone depleting substances as defined by the Clean Air Act. HAZARDOUS AIR POLLUTANTS: Any components listed below are defined by the Federal EPA as hazardous air pollutants. None COMPONENT: STATE REGULATIONS: Check with the appropriate state agency to determine whether regulations exists. INTERNATIONAL REGULATIONS: NA SECTION 16: OTHER INFORMATION PREPARED BY: Department of Regulatory Compliance DATE OF ISSUE: 5/10/07 DATE OF LAST REVISION: 10/03/2012 We believe the information given is accurate. It is offered in good faith, but without guarantee. Since conditions are beyond our control, user assumes all responsibility and risk. Page 6 of 6 Product Name:Moldstat Plus Material Safety Data Sheet SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: SYNONYMS: PRODUCT CODES: MANUFACTURER: ADDRESS: Moldstat Coating (Clear) NA 100356 Theochem Laboratories Inc 7373 Rowlett Park Drive Tampa, FL 33610-1141 EMERGENCY PHONE: ChemTel: North America: 1-800-255-3924 International: +01-813-248-0585 CHEMICAL NAME: CHEMICAL FAMILY: CHEMICAL FORMULA: PRODUCT USE: PREPARED BY: REVISION NUMBER: MSDS REVISION DATE: Mixture NA NA Encapsulator TGD 1.0 10/04/2010 SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS Components listed in this section may contribute to the potential hazards associated with exposure to the concentrate. The product may contain additional non-hazardous or trade-secret components. INGREDIENT: None CAS NO. % WT % VOL SARA 313 REPORTABLE NA NA NA No ppm mg/m3 OSHA PEL-TWA: OSHA PEL STEL: OSHA PEL CEILING: NA NA NA NA NA NA ACGIH TLV-TWA: ACGIH TLV STEL: ACGIH TLV CEILING: NA NA NA NA NA NA SECTION 3: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: ROUTE(S) OF ENTRY: POTENTIAL HEALTH EFFECTS SHORT TERM/ACUTE EXPOSURE: Inhalation: Eyes: Yes EYES: Contact can cause irritation. SKIN: Contact may cause dryness. INHALATION: No Skin: No inhalation hazards. INGESTION: Ingesting large amounts may cause tissue damage. Yes Ingestion: Unlikely CHRONIC HEALTH HAZARDS: CARCINOGENICITY: No further data known NTP: NO ARC Monographs: NO MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: OSHA Regulated: NO None known SECTION 4: FIRST AID MEASURES Flush with large amounts of running water for at least 15 minutes while holding upper and lower lids open. If irritation persists get medical attention immediately. EYES: SKIN: Wash with water after exposure. INGESTION: Drink large amounts of water, Do not induce vomiting. Consult physician immediately for additional advice and treatment INHALATION: Move victim to fresh air. NOTES TO PHYSICIANS OR FIRST AID PROVIDERS: No further data known SECTION 5: FIRE-FIGHTING MEASURES FIRE AND EXPLOSIVE PROPERTIES: FLAMMABLE LIMITS IN AIR, UPPER: (% BY VOLUME) LOWER: None None FLASH POINT: (Closed FLAMMABLE LIMITS: None None Cup): AUTOIGNITION TEMPERATURE: None Known NFPA HAZARD CLASSIFICATION HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0 OTHER: NA HMIS HAZARD CLASSIFICATION FLAMMABILITY: HEALTH: 1 0 REACTIVITY: 0 PROTECTION: NA EXTINGUISHING MEDIA: Use appropriate methods for combating surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES: None UNUSUAL FIRE AND EXPLOSION HAZARDS: None HAZARDOUS DECOMPOSITION PRODUCTS: None SECTION 6: ACCIDENTAL RELEASE MEASURES CLEAN-UP MEASURES: Stop spill or leak if it can be done safely. Contain spill to smallest possible area. Large spills should be recovered for disposal. Waste materials should be disposed of in accordance with all local, state and federal regulations. Transfer contaminated absorbent, soil and other materials to containers for disposal. Page 2 of 5 Product Name: Moldstat Coating-Claer SECTION 7: HANDLING AND STORAGE HANDLING: As with any chemical, handle the product in a manner that minimizes exposure to practicable levels. Prior to handling, consult Section 8 of this MSDS to evaluate personal protective equipment needs. Open containers slowly to relieve any pressure. Follow all other standard industrial hygiene practices. Empty containers may contain product residue. All safety precautions taken when handling this product should also be taken when handling empty drums and containers. Keep containers closed when not in use. STORAGE: Store in a cool, dry area away from combustibles and reactive chemicals. Store away from sources of ignition. Do not store at temperatures above 120 oF. OTHER PRECAUTIONS: For Industrial & Institutional use only. _________________________________________________________________________________________________________________ SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: Normal general ventilation is expected to be adequate. It is recommended that ventilation be designed in all instances to maintain airborne concentrations at lowest practicable levels. The user may wish to refer to 29 CFR 1910.1000(d)(2) and the ACGIH "Threshold Limit Values for Chemical Substances and Physical Agents Biological Exposure Indicies" (Appendix C) for the determination of exposure limits of mixtures. An industrial hygienist or similar professional may be consulted to confirm that the calculated exposure limits apply. RESPIRATORY PROTECTION: When using in a confined area, provide adequate ventilation or exhaust otherwise none needed. EYE PROTECTION: Wear protective eyewear to prevent accidental exposure SKIN PROTECTION: Chemically resistant gloves are are recommended to prevent exposure. Selection of personal protective equipment should be based upon the anticipated exposure and made in accordance with OSHA's Personal Protective Equipment Standard found in 29 CFR 1910 Subpart I. OTHER PERSONAL PROTECTIVE EQUIPMENT: HYGIENIC PRACTICES: Wash hands after use. Keep containers closed when not in use. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: White Milky Liquid ODOR: Acrylic Odor PHYSICAL STATE: Liquid pH AS SUPPLIED: 7.0 – 8.0 BOILING POINT: NA MELTING POINT: NA FREEZING POINT: NA VAPOR PRESSURE (mmHg): NA VAPOR DENSITY (AIR = 1): NA SPECIFIC GRAVITY : 1.02 – 1.03 EVAPORATION RATE: Same as water Page 3 of 5 Product Name: Moldstat Coating-Claer SOLUBILITY IN WATER: Dispersible PERCENT SOLIDS BY WEIGHT: NA PERCENT VOLATILE: NA MOLECULAR WEIGHT: Mixture VISCOSITY: NA SECTION 10: STABILITY AND REACTIVITY STABILITY: Product is Stable CONDITIONS TO AVOID (STABILITY): Extreme Temperatures INCOMPATIBILITY (MATERIAL TO AVOID): Strong Oxidizers and Acids HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: None HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID (POLYMERIZATION): Will not polymerize SECTION 11: TOXICOLOGICAL INFORMATION EYE EFFECTS: No further toxicological data known. SKIN EFFECTS: No ORAL EFFECTS: further toxicological data known. No further toxicological data known. INHALATION EFFECTS: OTHER: No further toxicological data known. No further data known. SECTION 12: ECOLOGICAL INFORMATION____________________________________________________________________________ This product has not been evaluated for ecotoxicity. As with any industrial chemical, exposure to the environment should be prevented and minimized wherever possible. ECOTOXICOLOGICAL INFORMATION: ENVIRONMENTAL FATE: Not known. SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: Ensure that collection, transport, treatment, and disposal of waste product, containers and rinsate complies with all applicable laws and regulations. Note that use, mixture, processing, or contamination of the product may cause the material to be classified as a hazardous waste. It is the responsibility of the product user or owner to determine at the time of disposal, whether the product is regulated as a hazardous waste. RCRA HAZARD CLASS: NA SECTION 14: TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION PROPER SHIPPING NAME: Coating Compound, Not regulated Page 4 of 5 Product Name: Moldstat Coating-Claer Not regulated Not regulated Not regulated Caution HAZARD CLASS: ID NUMBER: PACKING GROUP: LABEL STATEMENT: WATER TRANSPORTATION Not regulated AIR TRANSPORTATION Not regulated OTHER AGENCIES: Not Regulated SECTION 15: REGULATORY INFORMATION U.S. FEDERAL REGULATIONS SARA 313: This product contains one of the substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. Diethylene Glycol Monomethyl Ether, CAS No.111-77-7 CLEAN WATER ACT / OIL POLLUTION ACT: This product contains none of the chemicals subject to regulation by Section 311 of the Clean Water Act and the Oil Pollution Act. Releases of the product into or leading to surface waters must be reported to the National Response Center at 1-800-424-8802. CERCLA REPORTABLE QUANTITY: Any components listed below have been assigned a reportable quantity (RQ) by the Federal EPA. Release of the product into the environment that exceed the RQ for a particular component must be reported to the National Response Center at 1-800-424-8802. COMPONENT: None TOXIC SUBSTANCES CONTROL ACT: The OZONE DEPLETING SUBSTANCES: This components of this product are listed on the TSCA Inventory. product contains no ozone depleting substances as defined by the Clean Air Act. HAZARDOUS AIR POLLUTANTS: Any components listed below are defined by the Federal EPA as hazardous air pollutants. None COMPONENT: STATE REGULATIONS: Check with the appropriate state agency to determine whether regulations exists. INTERNATIONAL REGULATIONS: NA SECTION 16: OTHER INFORMATION PREPARED BY: Department of Regulatory Compliance DATE OF ISSUE: 3/6/06 DATE: 10/04/2010 We believe the information given is accurate. It is offered in good faith, but without guarantee. Since conditions are beyond our control, user assumes all responsibility and risk. Page 5 of 5 Product Name: Moldstat Coating-Claer
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