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DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 1 of 7
Version: 1.3
Revision Date: 2006/01/23

DOW CORNING(R) HVAC/R SEALANT CLEAR
1. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY
24 Hour Emergency Telephone:
Customer Service:
Product Disposal Information:
CHEMTREC:

Dow Corning Corporation
South Saginaw Road
Midland, Michigan 48686

MSDS No.: 04045032

Revision Date: 2006/01/23

Generic Description:
Physical Form:
Color:
Odor:

Silicone elastomer
Paste
Colorless
Acetic acid odor

NFPA Profile: Health

2 Flammability

1 Instability/Reactivity

Note: NFPA = National Fire Protection Association

2. OSHA HAZARDOUS COMPONENTS
CAS Number

(989) 496-5900
(989) 496-6000
(989) 496-6315
(800) 424-9300

Wt %

Component Name

17689-77-9

1.0 - 5.0

Ethyltriacetoxysilane

4253-34-3

1.0 - 5.0

Methyltriacetoxysilane

The above components are hazardous as defined in 29 CFR 1910.1200.

3. HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
Acute Effects
Eye:

Direct contact may cause moderate irritation.

Skin:

May cause moderate irritation.

Inhalation:

Irritates respiratory passages very slightly.

Oral:

Low ingestion hazard in normal use.

Prolonged/Repeated Exposure Effects
Skin:

No known applicable information.

Inhalation:

No known applicable information.

Oral:

No known applicable information.

0

DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 2 of 7
Version: 1.3
Revision Date: 2006/01/23

DOW CORNING(R) HVAC/R SEALANT CLEAR
Signs and Symptoms of Overexposure
No known applicable information.
Medical Conditions Aggravated by Exposure
No known applicable information.
The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar compositions,
component data and/or expert review of the product. Please refer to Section 11 for the detailed toxicology information.

4. FIRST AID MEASURES
Eye:

Immediately flush with water for 15 minutes. Get medical attention.

Skin:

Remove from skin and wash thoroughly with soap and water or waterless cleanser. Get
medical attention if irritation or other ill effects develop or persist.

Inhalation:

No first aid should be needed.

Oral:

No first aid should be needed.

Comments:

Treat according to person's condition and specifics of exposure.

5. FIRE FIGHTING MEASURES
Flash Point:

Not applicable.

Autoignition Temperature:

Not determined.

Flammability Limits in Air:

Not determined.

Extinguishing Media:

On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide
(CO2), dry chemical or water spray. Water can be used to cool fire exposed containers.

Fire Fighting Measures:

Self-contained breathing apparatus and protective clothing should be worn in fighting large
fires involving chemicals. Determine the need to evacuate or isolate the area according to
your local emergency plan. Use water spray to keep fire exposed containers cool.

Unusual Fire Hazards:

None.

Hazardous Decomposition Products
Thermal breakdown of this product during fire or very high heat conditions may evolve the following hazardous
decomposition products: Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide.
Formaldehyde.

6. ACCIDENTAL RELEASE MEASURES

DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 3 of 7
Version: 1.3
Revision Date: 2006/01/23

DOW CORNING(R) HVAC/R SEALANT CLEAR
Containment/Clean up:

Observe all personal protection equipment recommendations described in Sections 5 and 8.
Wipe up or scrape up and contain for salvage or disposal. Clean area as appropriate since
spilled materials, even in small quantities, may present a slip hazard. Final cleaning may
require use of steam, solvents or detergents. Dispose of saturated absorbant or cleaning
materials appropriately, since spontaneous heating may occur. Local, state and federal laws
and regulations may apply to releases and disposal of this material, as well as those materials
and items employed in the cleanup of releases. You will need to determine which federal,
state and local laws and regulations are applicable. Sections 13 and 15 of this MSDS provide
information regarding certain federal and state requirements.

Note: See section 8 for Personal Protective Equipment for Spills. Call (989) 496-5900, if additional information is
required.

7. HANDLING AND STORAGE
Use with adequate ventilation. Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide
ventilation during use to control HOAc within exposure guidelines or use respiratory protection. Avoid eye contact.
Keep container closed and store away from water or moisture.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Component Exposure Limits
CAS Number

Component Name

Exposure Limits

17689-77-9

Ethyltriacetoxysilane

See acetic acid comments.

4253-34-3

Methyltriacetoxysilane

See acetic acid comments.

Acetic acid is formed upon contact with water or humid air. Provide adequate ventilation to control exposures within
guidelines of OSHA PEL: TWA 10 ppm and ACGIH TLV: TWA 10 ppm, STEL 15 ppm.
Engineering Controls
Local Ventilation:
General Ventilation:

None should be needed.
Recommended.

Personal Protective Equipment for Routine Handling
Eyes:

Use proper protection - safety glasses as a minimum.

Skin:

Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as
soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are
recommended.

Suitable Gloves:

Silver Shield(R). 4H(R).

DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 4 of 7
Version: 1.3
Revision Date: 2006/01/23

DOW CORNING(R) HVAC/R SEALANT CLEAR
Inhalation:

No respiratory protection should be needed.

Suitable Respirator:

None should be needed.

Personal Protective Equipment for Spills
Eyes:

Use proper protection - safety glasses as a minimum.

Skin:

Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as
soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are
recommended.

Inhalation/Suitable
Respirator:

No respiratory protection should be needed.

Precautionary Measures:

Avoid eye contact. Use reasonable care.

Comments:

Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide ventilation
during use to control HOAc within exposure guidelines or use respiratory protection.

Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require
added precautions.

9. PHYSICAL AND CHEMICAL PROPERTIES
Physical Form:
Color:
Odor:
Specific Gravity @ 25°C:
Viscosity:
Freezing/Melting Point:
Boiling Point:
Vapor Pressure @ 25°C:
Vapor Density:
Solubility in Water:
pH:
Volatile Content:

Paste
Colorless
Acetic acid odor
1.04
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.

Note: The above information is not intended for use in preparing product specifications. Contact Dow Corning before writing
specifications.

10. STABILITY AND REACTIVITY
Chemical Stability:

Stable.

Hazardous
Polymerization:
Conditions to Avoid:

Hazardous polymerization will not occur.
None.

DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 5 of 7
Version: 1.3
Revision Date: 2006/01/23

DOW CORNING(R) HVAC/R SEALANT CLEAR
Materials to Avoid:

Oxidizing material can cause a reaction. Water, moisture, or humid air can cause hazardous
vapors to form as described in Section 8.

11. TOXICOLOGICAL INFORMATION
Special Hazard Information on Components
No known applicable information.

12. ECOLOGICAL INFORMATION
Environmental Fate and Distribution
Complete information is not yet available.
Environmental Effects
Complete information is not yet available.
Fate and Effects in Waste Water Treatment Plants
Complete information is not yet available.

Hazard Parameters (LC50 or EC50)
Acute Aquatic Toxicity (mg/L)
Acute Terrestrial Toxicity

Ecotoxicity Classification Criteria
High
Medium
<=1
>1 and <=100
<=100
>100 and <= 2000

Low
>100
>2000

This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34, 1993.
This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information presented in the
section concerning the overall ecological safety of this material.

13. DISPOSAL CONSIDERATIONS
RCRA Hazard Class (40 CFR 261)
When a decision is made to discard this material, as received, is it classified as a hazardous waste? No
State or local laws may impose additional regulatory requirements regarding disposal.
Call (989) 496-6315, if additional information is required.
14. TRANSPORT INFORMATION
DOT Road Shipment Information (49 CFR 172.101)
Not subject to DOT.
Ocean Shipment (IMDG)

DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 6 of 7
Version: 1.3
Revision Date: 2006/01/23

DOW CORNING(R) HVAC/R SEALANT CLEAR
Not subject to IMDG code.
Air Shipment (IATA)
Not subject to IATA regulations.
Call Dow Corning Transportation, (989) 496-8577, if additional information is required.

15. REGULATORY INFORMATION
Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
TSCA Status:

All chemical substances in this material are included on or exempted from listing on the TSCA
Inventory of Chemical Substances.

EPA SARA Title III Chemical Listings
Section 302 Extremely Hazardous Substances (40 CFR 355):
None.

Section 304 CERCLA Hazardous Substances (40 CFR 302):
None.

Section 311/312 Hazard Class (40 CFR 370):
Acute: Yes
Chronic: No
Fire: No
Pressure: No
Reactive: No
Section 313 Toxic Chemicals (40 CFR 372):
None present or none present in regulated quantities.
Supplemental State Compliance Information
California
Warning: This product contains the following chemical(s) listed by the State of California under the Safe Drinking Water
and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer, birth defects or other
reproductive harm.
None known.
Massachusetts
CAS Number

Wt %

Component Name

DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 7 of 7
Version: 1.3
Revision Date: 2006/01/23

DOW CORNING(R) HVAC/R SEALANT CLEAR
7631-86-9

7.0 - 13.0

Silica, amorphous

CAS Number

Wt %

Component Name

70131-67-8

> 60.0

Dimethyl siloxane, hydroxy-terminated

7631-86-9

7.0 - 13.0

Silica, amorphous

17689-77-9

1.0 - 5.0

Ethyltriacetoxysilane

4253-34-3

1.0 - 5.0

Methyltriacetoxysilane

New Jersey

Pennsylvania
CAS Number

Wt %

Component Name

70131-67-8

> 60.0

Dimethyl siloxane, hydroxy-terminated

7631-86-9

7.0 - 13.0

Silica, amorphous

16. OTHER INFORMATION
Prepared by: Dow Corning Corporation
These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or
implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally
applicable. However, each user should review these recommendations in the specific context of the intended use and
determine whether they are appropriate.
(R) indicates Registered Trademark

MATERIAL SAFETY DATA SHEET
IDENTIFICATION
Name:
Chemical Family:
Formula:
Synonyms:
Hazard Class:
Other Identifying Data:

REFRIGERANT (R414b)
Halogenated Hydrocarbons
Mixture of CHClFCF3, CH3CClF2, CH(CH3)2-CH3, CHClF2
N/A
2.2
This product is a direct replacement for CFC-12 & HFC-134a,
without modification of the user's equipment.

CAS Name:
Chlorodifluoromethane
1-Chloro-1, 1-difluoroethane
Isobutane
2-Chloro-1,1,1,2-Tetrafluoroethane

CAS Registry No.
000075-45-6
000075-68-3
068476-85-7
002837-89-0

FIRE AND EXPLOSION DATA:
Flash point:
Flammability Classification:
Health Hazard Code:
Flammable Limits in Air
Extinguishing Media:

NA
will not burn
Nonhazardous
LEL: NA % UEL: NA %
Stop Flow of Gas, Use Class A Ext. Agent, Use Class B Ext. Agent,
Water may be used to blanket fire. EXPLODES ON HEATING
Unusual Fire/Explosion Hazards: Cylinders may vent or rupture in fire conditions, leading to
decomposition. Vapours may decompose if exposed to direct
flame conditions. The vapour may displace oxygen making
breathing difficult and causing light-headedness or suffocation.
Special Fire Fighting Procedures:The material is not flammable and does not support combustion.
The choice of fire extinguishing media depends on the
surrounding materials involved in the fire. Use self-contained
breathing apparatus and full protective gear. Use water spray to
cool fire-exposed containers.
HEALTH HAZARD INFORMATION:

Manufacturer / Distributor:
U.S.

Environment Specialty Products
10640 East 59th Street, PO Box 36626
841 Brock Rd. South,
Indianapolis IN 46236
Pickering ON LIW 3J2
EMER:1-800-457-4280 CHEMTREC, 24 Hrs
1-613-996-6666 CANUTEC, chemical emer. only
INFO: 1-800-497-6805 (weekdays 7:30am-4:00pm)1-800-495-4062 (weekdays 9:00am-5:00pm)

Immediate: The greatest hazard is contact with escaping gas which can cause frostbite and damage
to exposed tissue. The escaping gas may displace oxygen and cause light-headedness, eye irritation
and suffocation.
Long Term: Exposure to high concentrations may lead to cardiac irregularities, unconsciousness
or death.
Other Hazards: None listed

PHYSICAL DATA

FIRST AID

CANADA

ICOR International Inc

Boiling Point:
-29.8°F
Vapour Pressure:
NDA
Evaporation Rate:
NDA
( Butyl Acetate =1)
Vapour Density (Air =1) >1
very slight
Solubility in H2O:
Specific Gravity:
1.1

Pure or Mixture:
Melting Point (F):
pH:
Ignition Temperature:
Physical State:

Mixture
NDA
NA
1170°F
Gas

HAZARDOUS COMPONENTS:
Material(s):
Chlorodifluoromethane
1-Chloro-1, 1-difluoroethane
Isobutane
2-Chloro-1,1,1,2-Tetrafluoroethane

Approximate weight %
50
9.5
1.5
39

HAZARDOUS REACTIVITY: AVOID INTENSE HEAT AND OPEN FLAME
Stability: Material is normally stable. However, avoid open flames and high temperatures.
Incompatibility (materials to avoid): Strong oxidants, including oxygen, freshly scraped
aluminium, alkali metals, and alkali earth metals (sodium, magnesium, etc.) may cause exothermic
reaction. The aluminum in refrigeration systems contains an oxide/chloride coating to prevent
reaction with metal.
Hazardous decomposition products:
Hydrofluoric and hydrochloric acids, chlorine, fluorine, possibly phosgene, carbon dioxide, and
carbon monoxide.
Polymerization: Will not occur.
Other Reactivity Data: Cylinders of used product may contain oil as well as refrigerant. A liquid
leak or venting during a fire will produce a cloud of oil mist that is very flammable.

Inhalation: Remove to fresh air, call a physician. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do not give epinephrine or similar drugs.
Note to physicians: Because of possible increased risk or eliciting cardiac dysrythmias, catecholamine
drugs, such as epinephrine, should be considered only as a last resort in life threatening emergencies.

Eyes: Flush immediately with water for at least 15 minutes. Call a physician.
Skin: Warm the area gradually by flushing with plenty of water. Call a physician
Swallowed: DO NOT INDUCE VOMITTING, Call a physician
Medical Conditions Aggravated by Exposure: Persons subject to cardiac problems may be at
increased risk by exposure.
PRECAUTIONS / PROCEDURES:
Spill or leak: Remove or extinguish ignition or combustion sources. Evacuate enclosed spaces
until gas is dispersed. Keep upwind. Stop the release of gas, if possible without risk. Disperse the
gas with floor level forced-air ventilation. Exhaust vapours outdoors. Contain the spill by building
a dike using absorbent material. Collect the remainder of the spill with absorbent material and
place into a drum for waster disposal or recovery. Wash contaminated clothing before reuse.
Work/Hygiene Practices: Use insulated or lined butyl gloves, face shield or goggles, and
impervious clothing.
Special Measures: Good general ventilation is usually adequate, but local ventilation may be
needed if gas is vented to atmosphere. Use self-contained breathing apparatus if local ventilation is
not adequate.
SHIPPING INFORMATION:
DOT

Other information:

Proper shipping name: LIQUEFIED GAS, N.O.S.
Hazard Class: 2.2
DOT Identification: UN3163
Do not heat above 120°F
Date revised: 03-01-04

MATERIAL SAFETY DATA SHEET
NFPA SYMBOL
HMIS
SEVERE 4
SERIOUS
MODERATE
SLIGHT
MINIMAL

HMIS SYMBOL
HEALTH
1
FLAMMABILITY 1
REACTIVITY
0

NFPA
EXTREME
FIRE
3
HIGH
2
MODERATE
1
SLIGHT
TOXICITY
0
INSIGNIFICANT

1
1

REACTIVITY
0
SPECIAL

MAY BE USED TO COMPLY WITH OSHA’S HAZARD
COMMUNICATIONS STANDSRD (HSC) 29 CFR 1910.1200
==================================================================================
SECTION I - PRODUCT IDENTIFICATION
==================================================================================
Product name / Identity : ZOOM-SPOUT OILER DO-1
A-1 Components Product Code #:
6403
Product use : Oil
Chemical family : Petroleum Hydrocarbonate
Supplier name and address :
Manufacturer name and address:
A-1 COMPONENTS CORP.
625 West 18th St.
Hialeah, Florida 33010
Phone # : (305) 885-1911

Same as
Supplier

Emergency Telephone Numbers, 24-hour :

INFOTRAC 1-800-535-5053

WHMIS CLASS: D2B
==================================================================================
SECTION II - HAZARDOUS INGREDIENTS
==================================================================================
LC50 ppm
LD50 mg/kg
Ingredients
CAS #
wt.%
(Rat, ihl.)
(Rat, oral)
Oil mist

64742-65-0

95-99.99

n/av

n/av

==================================================================================
SECTION III - PHYSICAL DATA
==================================================================================
Physical State : Liquid
Odor and appearance : Clear, yellow characteristic odor.
Odor threshold : n/ap
Specific gravity : 0.866
Coefficient of water/oil distribution : n/av
Vapor pressure (mm Hg at 20oC) : n/av
Boiling point : above 555°F (291°C)
Freezing/Melting Point : n/av
pH : n/ap
Vapor density (Air = 1) : Heavier than air
Evaporation rate (BuAe = 1) : Slower than ether
Volatiles, wt.% : Negligible
Viscosity: 31.5 CST, @ 40°C
Solubility in water: Negligible

TELE-SPOUT OILER DO-1

==================================================================================
SECTION IV - FIRE AND EXPLOSION DATA
==================================================================================
Conditions of flammability :. This material will burn but will not ignite readily.
Means of extinction : Dry chemical, CO@, water spray, foam, sand or earth. Water or foam may cause frothing.
Sensitivity to mechanical impact/static discharge : n/av
Flash point (Method) : 365°F (202°C) (COC)
Upper flammable limit % : n/ap
Lower flammable limit % : n/ap
Auto-ignition temperature : n/ap
Special Fire Fighting Procedures: Water spray may be useful in minimizing vapors and cooling containers
exposed to heat and flame. Avoid spreading burning liquid with water used for cooling purposes. Move
undamaged containers from fire area if you can do so without risk.
Hazardous Combustion Products: Refer to "Hazardous Decomposition Products".
Unusual Fire and Explosion Hazards:
==================================================================================
SECTION V - REACTIVITY DATA
==================================================================================
Stability : Stable under ambient pressure and temperature. Hazardous polymerization will not occur.
Incompatible materials : Strong oxidizing agents. Avoid contact with any source of ignition. Extended exposure
to hugh temperatures may cause decomposition.
Conditions of reactivity: n/ap
Hazardous decomposition products : Thermal decomposition in the presence of air may yield major amounts
of oxides of carbon and minor amounts of oxides of sulphur and nitrogen.
==================================================================================
SECTION VI - TOXICOLOGICAL PROPERTIES
==================================================================================
*** Routes of exposure and acute/chronic effects ***
Exposure limit : TLV-TWA Oil mist 5 mg/m3
Irritancy of Product: Inhalation, ingestion, skin and eye contact.
Inhalation : Exposure of mists, or prolonged or repeated exposure to fumes or vapors that may be generated
when this material is heated, may cause irritation of nose and throat..
Skin :This material can cause skin irritation. Prolonged or repeated contact may cause redness, burning, or
dermatitis.
Eyes : This material may cause eye irritation. Direct contact may cause burning, tearing, and redness.
Ingestion : Accidental ingestion of this material may cause irritation of the digestive tract.
Chronic effects : None.
Carcinogenicity: Not listed by IARC and ACGIH as carcinogenic.
Reproductive effects, Teratogenicity, Mutagenicity: n/av.
Sensitization to Product: None known.
Name of Toxicologically Synergistic Products: n/av

TELE-SPOUT OILER DO-1

==================================================================================
SECTION VII FIRST AID
==================================================================================
Inhalation : Move victim from source of exposure if irritation of nose or throat develops. If symptoms of exposure
develop, seek medical attention. If victim is not breathing, artificial respiration should be administered. Seek
medical attention immediately.
Eyes : Immediately move victim away from exposure. For direct contact, flush the affected eye(s) with clean
water for at least 15 minutes. Seek medical attention immediately.
Skin : Do not use gasoline, thinners or solvents to remove product from skin. Wipe material from skin and
remove contaminated clothing. Cleanse affected area thoroughly with soap and water if necessarily a waterless
hand cleaner. . If irritation or redness develops and persists, seek medical attention immediately.
Ingestion : If victim is conscious and alert, give 2 to 3 cups of water or milk to drink. Seek medical attention
immediately.
NOTE TO PHYSICIAN: Emesis of lavage is not recommended for ingestions of minute quantities or
tastes of most hydrocarbons. Medical opinion is divided for large ingestions. Emesis of lavage has been
recommended for these petroleum products which have a high oral toxicity. Gastric lavage with a cuffed
endotracheal tube is recommended by some physicians to prevent aspiration.
==================================================================================
SECTION VIII - PREVENTIVE MEASURES
==================================================================================
Spill, leak or release : Collect leaking fluid in sealable containers. Absorb spilled liquid in sand or inert
absorbant. Contact fire authorities and appropriate local/provincial agencies.
Waste disposal : Review federal, provincial and local government requirements prior to disposal.
*** PROTECTIVE EQUIPMENT ***
Respiratory protection : If airborne concentrations exceed recommended exposure limits, a suitable filter-type
respirator should be worn.
Ventilation : If current ventilation practices are not adequate to maintain airborne concentration below
established exposure limits (see Section VI), additional ventilation or exhaust system may be required.
Protective gloves : Impermeable to the specific material handled is advised to prevent skin contact and possible
irritation.
Eye protection : Approved eye protection to safeguard against potential eye contact.
Other protective equipment : Eye wash and quick drench shower facilities should be available in the work area.
Barrier creams that are specific for oil-based materials are recommended when gloves are impractical.
*** STORAGE & HANDLING ***
Storage and handling conditions :
Handling: Avoid generating oil mists while handling. Avoid prolonged or repeated skin contact. wash thoroughly
after handling. Do not wear oil-soaked clothing or shoes.
Storage: Store in a cool, dry location. Store in original container. Keep container closed when not in use.
Special Shipping Information: TDG - Not Regulated
==================================================================================
Additional notes or references :
Abbreviations :
n/av : not available
n/ap : not applicable
IARC : International Agency for Research on Cancer
ACGIH : American Conference of Governmental Industrial Hygienists
TLV : Threshold Limit Values
NIOSH: National Institute of Occupational Safety and Health
STEL: Short Term Exposure Limit
TDG : Transportation of Dangerous Goods Act.
References :
1. ACGIH, Threshold Limit Values and Biological Exposure Indices for 1993-94.
2. International Agency for Research on Cancer Monographs, Supplement 7, 1988.
3. Canadian Centre for Occupational Health and Safety. Cheminfo Database.
4. N. Irving Sax. Dangerous Properties of Industrial Materials. Seventh Edition.
==================================================================================
SECTION IX PREPARATION INFORMATION
==================================================================================
Prepared by : A-1 COMPONENTS CORP.
Telephone # : (305) 885-1911
Preparation date : December 16, 2005

TELE-SPOUT OILER DO-1

CATALOG NO. PT-200, PT-236

MATERIAL SAFETY DATA SHEET
PRO-TREAT 200
SECTION I-IDENTIFICATION

HAZARD RATINGS
HMIS DATA
HEALTH 2
0=MINIMAL
FIRE
1
1=SLIGHT
REACTIVITY 1 2 =MODERATE
3=HIGH
4=EXTREME
Personal Protection Index B

MANUFACTURED BY: Diversitech, Inc
ADDRESS: 2530 Lantrac Court
Decatur, GA 30035
EMERGENCY Phone No. 800-255-3924 Chem-Tel (Chemical Emergencies Only)
PHONE NUMBER FOR INFORMATION: 800-995-2222
DATE REVISED: 3/29/2006
NAME OF PREPARER: ANTHONY E. JERNIGAN
INGREDIENT

SECTION II HAZARDOUS INGREDIENTS INFORMATION
CAS NO
OSHA
ACIGH
OTHER
PEL
TLV
STEL

Tetradecyl
Dimethylbenzyl ammonium chloride 139-08-2

LD50: 18 mg/kg (mouse)

% or
RNG
<25%

SECTION III – PHYSICAL/CHEMICAL CHARACTERISTICS
Boiling Point: >112°C
Specific gravity (H2O = 1): 1.-25-1.35
Vapor pressure (mm Hg): < 0.1
Melting Point (Pour Point): >40°C
Vapor Density (Air = 1): N/A
Evaporation Rate (Water = 1): N/A
Solubility in water: 100
Appearance and odor: Blue tablet with a characteristic cationic surfactant odor.
SECTION IV- FIRE AND EXPLOSION HAZARD DATA
Flash Point (Method Used): None

Flammable Limits: None

Extinguishing media: Not applicable
Special Fire Fighting Procedures: Keep containers cooled with a water spray if involved in a fire.
Unusual Fire and Explosion Hazards: This product may evolve toxic fumes (ammonia, hydrogen
chloride if heated to decomposition.
Stability-Stable

SECTION V – REACTIVITY DATA
Conditions to avoid: None

Incompatibility (Materials to avoid): Strong oxidizers, strong acids, formaldehyde, anionic surfactants &
soap
Hazardous Decomposition or Byproducts: May evolve carbon monoxide, carbon dioxide, hydrogen
chloride, ammonia gas and other unidentified fragments if this product is involved in a fire.
Hazardous Polymerization: Will not occur.

1

PRO-TREAT 200 MSDS
SECTION VI– HEALTH HAZARD DATA
Routes of Entry: Inhalation: no Skin: yes Ingestion: yes Eyes: yes
Health Hazards (acute and chronic): Pro-Treat 200 is moderately toxic if ingested. Eye contact causes
extreme irritation. May cause skin irritation in sensitive individuals.
Carcinogenicity: NTP? No IARC Monographs? No OSHA Regulated? No
Signs and symptoms of exposure:
Inhalation: Dust may cause chemical pnuemonitis. This product is not toxic by
inhalation.
Skin: Minimally irritating. Prolonged contact may cause dermatitis or drying of skin.
Ingestion: Do not take internally. If ingested, it may damage
throat and digestive tissue. Swallowing may cause diarrhea, nausea, vomiting, unconsciousness.
Eyes: May cause severe eye irritation, permanent damage or blindness.
Medical Conditions Aggravated by Exposure: Contact with skin or eyes, or breathing dust can cause eye
skin or tissue damage or affect individuals with respiratory disorders.
Emergency and First Aid Procedures:
Eyes: Flush with water for 15 minutes. Consult a physician if irritation persists
Skin: Remove contaminated clothing. Wash the affected area with soap and water. Launder or dry
clean clothes before reuse..
Inhalation: Evacuate to a safe area with plenty of fresh air. Allow the affected individual to rest in a well
ventilated area, then seek medical aid immediately.
Ingestion: DO NOT induce vomiting. Force fluids. Contact the nearest Poison Control Center
SECTION VII – PRECAUTIONS FOR SAFE HANDLING AND STORAGE
STEPS TO BE TAKEN IF MATERIAL IS SPILLED OR RELEASED:
Wear recommended protective clothing. Remove contaminated garments promptly. Sweep up tablets and
dispose of contaminated product in accordance with local, state, and federal regulations. Undamaged
product may be recovered and used according to label instructions.
DO NOT contaminate municipal sewers or other open bodies of water with runoff form cleanup.
WASTE DISPOSAL METHODS: Incinerate this material and all associated wastes, or bury in an approved
landfill in accordance with governmental regulations.
HANDLING AND STORAGE:
Avoid contact with skin and eyes. Avoid breathing dust. Keep containers closed when not in use. Store in a
dry, cool, area
Empty containers may retain residue. All containers should be disposed of in an environmentally safe
manner, and in accordance with all governmental regulations.
Keep this and all chemicals out of the reach of children.

2

PRO-TREAT 200 MSDS
SECTION VIII – CONTROL MEASURES
Respiratory Protection (Specify Type): Use in a well-ventilated area. If dust is being generated and
exceeds the TLV, a respiratory program meeting OSHA 1910.134 and ANSI Z88.2 requirements must be
followed.
Ventilation: Local exhaust is recommended when used in enclosed areas.
Protective Gloves: Neoprene, latex or other materials may be used if there is documented evidence of
compatibility.
Eye protection: Safety glasses (ANSI Z87.1) or approved equivalent as necessary to minimize eye contact
hazards.
Other Protective Clothing: Neoprene aprons, overshoes, oversleeves or other impervious clothing as
necessary to minimize exposure.
Work Hygienic Practices: Use proper industrial hygiene practices to minimize hazardous exposure. Wash
hands after handling this material, and before eating or smoking.

SECTION IX – ADDITIONAL INFORMATION
Transportation Information:
DOT HAZARD LABEL: None
DOT Description: Cleaning Compound, NOI, other than liquid
TSCA: All ingredients are TSCA listed
SARA TITLE III Reporting Requirements:
Section 302: EHS reporting not required
Section 304: Hazardous releases reporting not required
Section 311: Community Right To Know reporting is required if the inventory is above the Threshold
Planning Quantity.
Section 312: R-T-K Inventory data reporting is not required.
Section 313: Emissions and release reporting may be required for users of this product within the
manufacturing sector. This does not apply to service companies.
This information is, to the best of our knowledge and belief, accurate and reliable as of the date
completed. However no representation, warranty or guarantee is made as to its accuracy, reliability or
completeness. It is the user’s responsibility to satisfy himself as to the completeness and suitability of
such information for his own particular use. We do not accept liability for any loss or damage that may
occur from the use of this information, nor do we offer any warranty against patent infringement

3

MATERIAL SAFETY DATA SHEET
MSDS 0165
=============================================================================
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
----------------------------------------------------------------------------HMIS CODES
PRODUCT NAME
Health
1
Acid - Away
Flammability
2
Reactivity
0
PRODUCT CODES
PPI
B
45004,45010
CHEMICAL FAMILY:
Organic
USE
Compressor Burnout Acid Neutralizer
MANUFACTURER'S NAME
EMERGENCY TELEPHONE NO.
The RectorSeal Corporation
Chemtrec 24 Hours
2601 Spenwick Drive
(800) 424-9300
Houston, Texas 77055 USA
VALIDATION DATE
TECHNICAL SERVICE TELEPHONE NO.
June 14, 2006
(800) 231-3345
REVISION DATE
June 14, 2006
=============================================================================
Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
----------------------------------------------------------------------------% by WT
CAS No. INGREDIENT
UNITS
-64742-44-5 Petroleum Oil
ACGIH TLV
5 mg/m3
OSHA PEL
5 mg/m3
=============================================================================
Section 3 -- HAZARDS IDENTIFICATION
----------------------------------------------------------------------------SUMMARY OF ACUTE HAZARDS
Repeated inhalation may cause dizziness and nausea. Ingestion may cause
cramps and diarrhea.
ROUTE OF EXPOSURE, SIGNS AND SYMPTOMS
INHALATION
Upper respiratory tract irritation and dizziness.
EYE CONTACT
Irritation, watering may occur.
SKIN CONTACT
Frequent or prolonged contact may irritate and cause dermatitis.
INGESTION
May cause nausea, vomiting and gastro-intestinal irritation.
SUMMARY OF CHRONIC HAZARDS
Prolonged skin contact may result in irritation and dermatitis.
Prolonged eye contact may result in irritation or chemical burns.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Individuals with pre-existing or chronic diseases of the eyes, skin
or persons with chemical sensitivity may have increased susceptibility to
excessive exposures.
=============================================================================
Section 4 -- FIRST AID MEASURES
----------------------------------------------------------------------------If INHALED:
If overcome by exposure, remove victim to fresh air
immediately. Give oxygen or artificial respiration as
needed. Obtain emergency medical attention. Prompt action
is essential.

If on SKIN:

Wash with soap and water. Remove contaminated clothing.
If irritation occurs, seek medical attention.
If in EYES:
Flush with large amounts of water for at least 15 minutes.
Get medical attention if irritation persists.
If SWALLOWED:
If swallowed, call a physician immediately. Only induce
vomiting at the instruction of a physician. Never give
anything by mouth to an unconscious person.
=============================================================================
Section 5 -- FIRE FIGHTING MEASURES
----------------------------------------------------------------------------FLASH POINT
LEL
UEL
>148 F (64 C) SETA CC
N/D
N/D
EXTINGUSING MEDIA
Foam, dry chemical, carbon dioxide or water fog.
SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus
(SCBA) and other protective clothing. Hazardous decomposition products
possible (see Section 10).
UNUSUAL FIRE AND EXPLOSION HAZARDS: Combustible - moderate flash point.
Heat may build up pressure and rupture closed containers.
=============================================================================
Section 6 -- ACCIDENTAL RELEASE MEASURES
----------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove all sources
of ignition. Use absorbent materials to prevent footing hazard and to
contain. Ventilate area with natural or explosion-proof, forced air
ventilation. Avoid flushing into sewers, drains, waterways, and soil.
Wear protective clothing and respiratory protection during cleanup.
=============================================================================
Section 7 -- HANDLING AND STORAGE
----------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed and
upright when not in use. Do not store near heat, sparks, or open flames.
OTHER PRECAUTIONS: Avoid prolonged or repeated contact with skin or
clothing. Empty containers may contain residues; treat as if full and
observe all products precautions. Do not reuse empty containers.
KEEP OUT OF REACH OF CHILDREN.
=============================================================================
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
----------------------------------------------------------------------------RESPIRATORY PROTECTION (SPECIFY TYPE): In confined poorly ventilated areas,
use NIOSH/MSHA approved air purifying or supplied air purifying or supplied
air respirators.
VENTILATION - LOCAL EXHAUST: Acceptable
SPECIAL: Explosion-proof equipment
MECHANICAL (GENERAL): Preferable
OTHER: N/A
PROTECTIVE GLOVES: Rubber or neoprene
EYE PROTECTION: Chemical splash goggles (ANSI Z-87.1 or equivalent)
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Coveralls recommended.
WORK/HYGIENIC PRACTICES: Where use can result in skin contact, wash exposed
areas thoroughly before eating, drinking, smoking, or leaving work area.
Launder contaminated clothing before reuse.
=============================================================================
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
----------------------------------------------------------------------------BOILING POINT:
320 F (160 C) @ 760mm Hg
SPECIFIC GRAVITY (H20 = 1):
0.9
VAPOR PRESSURE (mm Hg):
<5 @ 68 F (20 C)
MELTING POINT:
N/A
VAPOR DENSITY (AIR = 1):
>5

EVAPORATION RATE (ETHYL ACETATE = 1): <1
APPEARANCE/ODOR:
Pale Yellow Oil/Petroleum Odor
SOLUBILITY IN WATER:
Insoluble
VOLATILE ORGANIC COMPOUNDS(VOC)Content
(Theoretical Percentage By Weight):
0% or (0 g/L)
=============================================================================
Section 10 -- STABILITY AND REACTIVITY
----------------------------------------------------------------------------STABILITY: Stable
CONDITIONS TO AVOID: Heat, sparks, open flames, and strong oxidizing
conditions.
INCOMPATIBILITY (MATERIALS TO AVOID): Gaseous oxygen and strong oxidizing
materials.
HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO2 and fragmented hydrocarbons.
HAZARDOUS POLYMERIZATION: Will not occur.
=============================================================================
Section 11 -- TOXICOLOGY INFORMATION
----------------------------------------------------------------------------CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
----------------------------------------------------------------------------TOXICOLOGY DATA
Ingredient Name
----------------------------------------------------------------------------Petroleum Oil
Oral-Rat
LD50: N/D
Inhalation-Rat
LC50: N/D
=============================================================================
Section 12 -- Ecological Information
----------------------------------------------------------------------------ECOLOGICAL DATA
Ingredient Name
----------------------------------------------------------------------------Petroleum Oil
Food Chain Concentration Potential
N/D
WATERFOWL TOXICITY
N/D
BOD
N/D
AQUATIC TOXICITY
N/D
=============================================================================
Section 13 -- DISPOSAL CONSIDERATIONS
----------------------------------------------------------------------------Waste Classification: Non-regulated waste oil
Disposal Method:
Used oil recycler
Waste from this product is not considered hazardous as defined under the
Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Dispose of in
accordance with Federal, State, and Local regulation regarding pollution.
=============================================================================
Section 14 -- TRANSPORTATION INFORMATION
----------------------------------------------------------------------------DOT:
Non-Regulated
OCEAN (IMDG):
Non-Regulated
AIR (IATA):
Non-Regulated
WHMIS (CANADA):
Non-Regulated
=============================================================================
Section 15 -- REGULATORY INFORMATION
----------------------------------------------------------------------------REGULATORY DATA
Ingredient Name
----------------------------------------------------------------------------Petroleum Oil

SARA 313
No
TSCA Inventory
Yes
CERCLA RQ
N/A
RCRA Code
N/A
=============================================================================
Section 16 -- OTHER INFORMATION
----------------------------------------------------------------------------This document is prepared pursuant to the OSHA Hazard Communication
Standard (29 CFR 1910.1200). The information herein is given in good faith,
but no warranty, expressed or implied is made. Consult RectorSeal for further
information: (713) 263-8001

Page 1 of 1

CHEMetrics, Inc.
4295 Catlett Rd., Calverton, VA 20138
(800) 356-3072 (540) 788-9026
Fax (540) 788-4856 E-mail technical@chemetrics.com

24 Hour Emergency Numbers:
Creation Date:
Revision Date:

(703) 590-9204
(540) 439-3860
04/22/86 (1072-17)
12/22/06

MATERIAL SAFETY DATA SHEET
I. CHEMICAL IDENTIFICATION

VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION

TRADE NAMES: DISSOLVED OXYGEN CHEMets® and ULR CHEMets®
CATALOG NOS.: R-7501, R-7501V, R-7511, R-7518, R-7540, R-7540G and
R-7540V

OSHA PEL & ACGIH TLV: N/A
PROTECTIVE EQUIPMENT: Safety glasses

IX. PHYSICAL AND CHEMICAL PROPERTIES
DESCRIPTION: Reagent ampoules for the determination of dissolved oxygen
in water. Each CHEMet™ contains approximately 0.50 mL of liquid reagent
sealed under vacuum. Each ULR CHEMet™ contains approximately 1 mL of
liquid reagent sealed under vacuum.
NFPA RATINGS: HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0

STATE: Liquid APPEARANCE: Colorless to pale yellow ODOR: None
SOLUBILITY IN WATER: Miscible pH: 11.5
BOILING POINT: 150EC MELTING POINT: -5.0EC
VAPOR PRESSURE: N/A SPECIFIC GRAVITY: 1.03
VAPOR DENSITY: N/A

II. COMPOSITION/INFORMATION ON INGREDIENTS

X. STABILITY AND REACTIVITY

COMPONENT:
CAS NO.:

Diethylene Glycol
111-46-6
PERCENT: < 28.5

COMPONENT:
CAS NO.:

Deionized Water
7732-18-5
PERCENT: > 70

INCOMPATIBILITIES: Acids
HAZARDOUS DECOMPOSITION PRODUCTS: When heated to decomposition, oxides of carbon may be emitted.
Stable under normal conditions.

COMPONENT:
CAS NO.:

Other components
N/A
PERCENT:

XI. TOXICOLOGICAL INFORMATION
< 1.0

Any component of this mixture not specifically listed (e.g. "other components")
is not considered to present a carcinogen hazard.

III. HAZARDS IDENTIFICATION
Harmful if swallowed.
ACUTE TOXICITY: Irritation, nausea, diarrhea, nerve depression
CHRONIC TOXICITY: Irritation, liver or kidney lesions
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye, skin, liver or
kidney disorders

CARCINOGEN STATUS: None
No other data available at this time.

XII. ECOLOGICAL INFORMATION
Diethylene glycol has a low bioconcentration potential and is practically nontoxic to aquatic organisms.
No other data available at this time.

XIII. DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with Federal, State and Local Regulations.

IV. FIRST AID MEASURES

XIV. TRANSPORT INFORMATION

EYE AND SKIN CONTACT: Immediately flush eyes and skin with water for
15 minutes.
INGESTION: If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Seek medical
attention.
INHALATION: Remove individual to fresh air.

Not regulated.

V. FIRE FIGHTING MEASURES
FLASH POINT: N/A AUTOIGNITION POINT: N/A
FLAMMABILITY LIMITS: UPPER: N/A LOWER: N/A
EXTINGUISHING MEDIA: Dry chemical, carbon dioxide, water spray or foam

XV. REGULATORY INFORMATION
EUROPEAN INFORMATION:
EU Symbols: Xn - HARMFUL
Risk Phrases: Harmful if swallowed.
Safety Phrases: If swallowed, seek medical advice immediately (show the
label where possible).
CANADIAN INFORMATION:
WHMIS Classification: D2A
All chemical components of this product are listed on Canada’s DSL.

VI. ACCIDENTAL RELEASE MEASURES
Take up with absorbent material. Place in small containers for disposal.

U.S. INFORMATION:
All chemical components of this product are listed on the TSCA Inventory.

VII. HANDLING AND STORAGE

XVI. OTHER INFORMATION

Always wear eye protection when working with these ampoules.
WARNING: Do not break the tip of the ampoule unless it is completely
immersed in your sample. Breaking the tip in the air may cause the glass
ampoule to shatter.
If this product is used as directed, the user will not come in contact with or be
exposed to any of its chemical components.
Wash thoroughly after handling. Avoid contact with eyes.
Fragile. Liquid in glass. Handle with care.
Exposure of this product to temperatures up to 120EF (49EC) or even below
32EF (0EC) will not create a safety hazard. For optimum analytical accuracy,
the product should be stored in the dark and at room temperature.

THE ABOVE INFORMATION IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST
INFORMATION CURRENTLY AVAILABLE TO US. ALL PRODUCTS ARE OFFERED IN
ACCORDANCE WITH THE MANUFACTURER'S CURRENT PRODUCTION SPECIFICATIONS
AND ARE INTENDED SOLELY FOR USE IN ANALYTICAL TESTING. THE MANUFACTURER
SHALL IN NO EVENT BE LIABLE FOR ANY INJURY, LOSS OR DAMAGE RESULTING FROM
THE HANDLING, USE OR MISUSE OF THESE PRODUCTS.
CHEMets® and ULR CHEMets® are registered trademarks of CHEMetrics, Inc.

MSDS #GGC-12, #GGC-6 SWOOSH CO2 Cartridge

SECTION 1: IDENTIFICATION

Product Name: Swoosh CO2 Cartridges

MANUFACTURED FOR: Diversitech, Inc
ADDRESS: 2530 Lantrac Court, Decatur, GA 30035
PHONE NUMBER: 800-255-3924 Chem-Tel (Chemical Emergencies Only)
PHONE NUMBER (For Information): 800-995-2222
DATE REVISED: 5/5/2004
PREPARED BY: Anthony Jernigan
SECTION 2: HAZARDOUS INGREDIENTS INFORMATION
INGREDIENT
CAS NO
OSHA PEL ACIGH TLV OTHER STEL
%
Carbon dioxide 124-38-9
5000 ppm
3000 ppm
~100
SECTION 3: HAZARD IDENTIFICATION
Emergency Overview: Colorless odorless gas. Contact with desublimed solid may cause
frostbite. This product is nonflammable. Breathing high concentrations of vapors may produce
drowsiness and a headache.
Potential Health Effects:
Eyes: Contact with desublimed solid may cause frostbite.
Skin: Contact with desublimed solid may cause frostbite
Ingestion: Unlikely. Contact with desublimed solid may cause frostbite.
Inhalation: High concentrations of vapors in immediate area can displace oxygen and can
cause dizziness and unconsciousness. Use with adequate ventilation.
Pre-Existing Medical Conditions Aggravated by Exposure: Heart, lung, skin, eye.
SECTION 4: FIRST AID MEASURES
Eyes: Treat for frostbite immediately. Have eyes examined and tested by medical personnel if
irritation develops or persists.
Skin: Treat for frostbite immediately. Get medical attention if irritation develops or persist.
Ingestion: Not a possible route of entry.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
Flash Point: None to boiling (TCC)
LEL/UEL: Nonflammable
Extinguishing Media: Use extinguishing media as suitable for the combustible materials
involved in the fire.
Fire Fighting Instructions: As in any fire, wear self-contained breathing apparatus (pressuredemand, MSHA/NIOSH approved or equivalent) and full protective gear.
Unusual Fire and Explosion Hazards: Contents under pressure. Do not store near heat
sources.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Large Spills: Shut off leak if possible and safe to do so. Wear self-contained breathing
apparatus and appropriate personal protective equipment. Allow condensed solid to sublime.
Small Spills: Allow condensed solid to sublime.

1

MSDS #GGC-12, #GGC-6 SWOOSH CO2 Cartridge

SECTION 7: HANDLING AND STORAGE
Avoid prolonged or repeated contact with eyes, skin, and clothing. Wash hands before eating.
Protect cartridges from abuse, and extreme temperatures. Keep this product out of the reach of
children. Do not puncture cartridge unless it is contained in an approved appliance. Do not
attempt to refill spent cartridges. Maintain a well-ventilated work area; use with adequate
ventilation. Avoid breathing product vapor or mist. Store in a cool dry place, away from heat,
sparks, flame and direct sunlight.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines:
CHEMICAL NAME ACGIH TWA OSHA PEL ACGIH STEL
Carbon Dioxide
5,000 ppm
5,000 ppm
30,000 ppm
Work/Hygienic Practices: Good general ventilation should be sufficient to control airborne
levels. Local exhaust ventilation may be necessary to control any air contaminants to within their
TLVs during the use of this product. Wear safety glasses with side shields (or goggles) and
rubber, neoprene or other chemically resistant gloves if there is documented evidence of
compatibility when handling this material.
NFPA and HMIS Codes:
NFPA
HMIS
Health
1
1
Flammability 0
0
Reactivity
0
0
Personal Protection - B
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Colorless gas
Solubility in Water: Very Soluble
Odor: Slight ethereal
Specific Gravity: (Water =1) 1.53
pH: NA
Evaporation Rate: >1 (Butyl acetate=1)
Vapor Pressure: 856 psia @ 70 F
Vapor Density: 1.65 @ 70°F (Air = 1)
Viscosity: NA
Percent Volatile: 100%
SECTION 10: STABILITY AND REACTIVITY
Stability: This product is stable. Conditions to Avoid: None known
Incompatibility: None known
Products of Decomposition: None known
Hazardous Polymerization: Will not occur Conditions to Avoid: NA
SECTION 11: TOXICOLOGICAL INFORMATION
Inhalation:
Carbon Dioxide: LCLo/human
9ppm/5 min
Cancer Information: No ingredients listed as human carcinogens by NTP or IARC
Reproductive effects: none
Teratogenic effects: none
Mutagenic effects: none

2

MSDS #GGC-12, #GGC-6 SWOOSH CO2 Cartridge

SECTION 12: ECOLOGICAL INFORMATION
Environmental Impact Information: No sufficient effect known from discharge of gas or
desublimed solid.
Environmental Impact Data
REPORTING (percent by weight):
CFC 0.0% VOC 0.0%; HFC 0.0% HFC 0.0%; Cl. Solv. 0.0% ODP 0.00
US regulations require reporting spills of this material that could reach any surface waters. The
toll free number for the US Coast Guard National Response Center is: 800-424-8802.
SECTION 13: DISPOSAL CONSIDERATIONS
Dispose of in accordance with all federal, state and local regulations.
SECTION 14: TRANSPORTATION INFORMATION
Proper
Sub. Pkg. Hazard
Pkg. Max.
Shipping Name UN Number Class Risk Group Label
Instr. Quantity
Air: Carbon Dioxide UN 1013
2.2 NA NA Non-flammable 200 75kg;150kg.
Gas
Ground: Consumer NA
ORM-D NA NA ORM-D
Pkg.
Commodity, ORM-D
Auth. 173.306
SECTION 15: REGULATORY INFORMATION
SECTION 313 SUPPLIER NOTIFICATION
This product contains the following toxic chemicals subject to the reporting requirements of
Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR
372): None
TOXIC SUBSTANCES CONTROL ACT (TSCA): All ingredients of this product are listed on the
TSCA Inventory.
WHMIS: Class A
This product is classified according to the hazard criteria of the CPR, and the MSDS contains all
of the information required by the CPR.
EEC:
Supply Classification: Not Listed
Hazard Pictogram: None
Risk Phrases: R-20 Harmful by Inhalation
Safety Phrases: S-2 Keep out of reach of children
S-47 Keep at temperatures not exceeding 49 degrees C
S-57 Refer to supplier for information on recycling
SECTION 16: OTHER INFORMATION
Do not puncture or incinerate containers. Normal ventilation for standard manufacturing
practices is usually adequate. Local exhaust should be used when large amounts are released.
REFERENCES: 29 CFR 1910.1200 40 CFR 300-700 ANSI Z400.1-1998; EEC Dangerous
Substances Classification, Packaging and Labeling List (Annexes 1, 2, 3 & 4)
This information is, to the best of our knowledge and belief, accurate and reliable as of the date completed. However no
representation, warranty or guarantee is made as to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy
himself as to the completeness and suitability of such information for his own particular use. We do not accept liability for any loss or
damage that may occur from the use of this information, nor do we offer any warranty against patent infringement.

3

J/B Industries Inc.
Section 1: Product And
Company Identification
COMPANY:
LOCATION:

J/B INDUSTRIES INC.
601 N. Farnsworth Ave.
Aurora, IL 60507

Emergency Telephone Number:

630/851-9444
PRODUCT NAME:

Vacuum Pump Oil
PRODUCT GRADES:
PRODUCT CODE:
DATE ISSUED:

December 28, 1992
DATE REVISED:

September 18, 2006
Sept. 1 , 2003

Section 2: Composition/
Information On Ingredients
CAS NAME:

Distillates, hydrotreated heavy paraffinic
CAS NUMBER:

64742-54-7
AMOUNT:

100% weight
This product is not approved for direct
food use [CFR 178.3620 (a) & (b)]

Section 3: Hazards Identification
EMERGENCY OVERVIEW

Clear colorless to pale yellow liquid.
IMMEDIATE HEALTH EFFECTS
EYE:

Not expected to cause prolonged or
significant eye irritation.
SKIN:

Contact with the skin is not expected to
cause prolonged or significant irritation.
Not expected to be harmful to internal
organs if absorbed through the skin.
Contact with the skin is not expected to
cause an allergic skin response.
INGESTION:

Not expected to be harmful if swallowed.
INHALATION:

Not expected to be harmful if inhaled.
Contains a petroleum-based mineral oil.
May cause respiratory irritation or other
pulmonary effects following prolonged
or repeated inhalation of oil mist at
airborne levels above the recomm
ended mineral oil mist exposure limit.
Symptoms of respiratory irritation
may include coughing and
difficulty breathing.

Material Safety Data Sheet
Section 4: First Aid Measures
EYE:

No specific first aid measures are
required because this material is not
expected to cause eye irritation. As a
precaution, remove contact lenses, if
worn, and flush eyes with water.
SKIN:

No specific first aid measures are
required because this material is not
expected to be harmful if it contacts the
skin. As a precaution, remove clothing
and shoes if contaminated. To remove
the material from skin, use soap and
water. Discard contaminated
clothing and shoes or thoroughly
clean before reuse.
No specific first aid measures are
required because this material is not
expected to be harmful if swallowed. Do
not induce vomiting. As a precaution,
give the person a glass of water or milk
to drink and get medical advice. Never
give anything by mouth to an
unconscious person.
INHALATION:

No specific first aid measures are
required because this material is not
expected to be harmful if inhaled. If
exposed to excessive levels of material
in the air, move the exposed person to
fresh air. Get medical attention
if coughing or respiratory
discomfort occurs.

Section 5: Fire Fighting Measures
FIRE CLASSIFICATION;

OSHA Classification (29 CFR
1910.1200): Not classified by OSHA as
flammable or combustible.
NFPA RATINGS:
HEALTH FLAMMABILITY

REACTIVITY

1

0

FLAMMABLE PROPERTIES:
FLASH POINT:

Cleveland Open Cup 378°F (190°C)
(Min)
AUTOIGNITION:

No data available
FLAMMABLE (EXPLOSIVE) LIMITS (% by
volume in air):

Lower N/A

Combustion Products:

Highly dependent on combustion
conditions. A complex mixture of
airborne solids, liquids, and gases
including carbon monoxide, carbon
dioxide, and unidentified organic
compounds will be evolved when this
material undergoes combustion.

Section 6. Accidental Release
Measures
PROTECTIVE MEASURES:

Eliminate all sources of ignition in
vicinity of spilled material.
SPILL MANAGEMENT:

INGESTION:

0

material, do not enter any enclosed or
confined fire space without proper
protective equipment, including selfcontained breathing apparatus.

Upper N/A

EXTINGUISHING MEDIA:

Use water fog, foam, dry chemical or
carbon dioxide (CO2) to extinguish
flames.
PROTECTION OF FIRE FIGHTERS:
Fire Fighting Instructions:

This material will burn although it is not
easily ignited. For fires involving this

Stop the source of the release if you can
do it without risk. Contain release to
prevent further contamination of soil,
surface water or groundwater. Clean up
spill as soon as possible, observing
precautions in Exposure Controls/
Personal Protection. Use appropriate
techniques such as applying noncombustible absorbent materials or
pumping. Where feasible and
appropriate, remove contaminated soil.
Place contaminated materials in
disposable containers and dispose of
in a manner consistent with
applicable regulations.
REPORTING:

Report spills to local authorities and/or
the U.S. Coast Guard's National
Response Center at (800) 424-8802 as
appropriate or required.

Section 7. Handling and Storage
GENERAL HANDLING INFORMATION:

Avoid contaminating soil or releasing this
material into sewage and drainage
systems and bodies of water.
STATIC HAZARD:

Electrostatic charge may accumulate and
create a hazardous condition when
handling this material. To minimize this
hazard, bonding and grounding may be
necessary but may not, by themselves,
be sufficient. Review all operations which
have the potential of generating an
accumulation of electrostatic charge and/
or a flammable atmosphere (including
tank and container filling, splash filling,
tank cleaning, sampling, gauging, switch
loading, filtering, mixing, agitation, and
vacuum truck operations) and use
appropriate mitigating procedures. For
more information, refer to OSHA
1

Standard 29 CFR 1910.106, 'Flammable
and Combustible Liquids', National Fire
Protection Association (NFPA 77,
'Recommended Practice on Static
Electricity; and /or the American
Petroleum Institute (API) Recommended
Practice 2003, 'Protection Against
Ignitions Arising Out of Static, Lightning
and Stray Currents'.
CONTAINER WARNING:

Container is not designed to contain
pressure. Do not use pressure to empty
container or it may rupture with
explosive force. Empty containers retain
product residue (solid, liquid, and/or
vapor) and can be dangerous. Do not
pressurize, cut, weld, braze, solder, drill,
grind, or expose such containers to heat,
flame, sparks, static electricity, or other
sources of ignition. They may explode
and cause injury or death. Empty
containers should be completely
drained, properly closed, and promptly
returned to a drum reconditioner or
disposed of properly.

RESPIRATORY PROTECTION:

No respiratory protection is normally
required.
If user operations generate an oil mist,
determine if airborne concentrations are
below the OSHA Permissible Exposure
Limit (PEL) of 5 mg/m3 for mineral oil
mist. If not, wear a NIOSH approved
respirator that provides adequate
protection from the measured
concentrations of this material. For
air-purifying respirators use a
particulate cartridge.
Use a positive pressure, air-supplying
respirator if there is potential for
uncontrolled release, exposure levels are
not known, or other circumstances
where air-purifying respirators may not
provide adequate protection.

Section 9: Physical And
Chemical Properties
APPEARANCE AND ODOR:

Clear colorless to pale yellow liquid.
PH:

Not Available

Section 8. Exposure Controls/
Personal Protection

VAPOR PRESSURE:

GENERAL CONSIDERATIONS:

VAPOR DENSITY (Air =1):

Consider the potential hazards of this
material (see Section 3), applicable
exposure limits, job activities, and other
substances in the work place when
designing engineering controls and
selecting personal protective equipment.
If engineering controls or work practices
are not adequate to prevent exposure to
harmful levels of this material, the
personal protective equipment listed
below is recommended. The user should
read and understand all instructions and
limitations supplied with the equipment
since protection is usually provided for a
limited time or under certain
circumstances.
ENGINEERING CONTROLS:

Use in a well-ventilated area.
PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:

No special eye protection is normally
required. Where splashing is possible,
wear safety glasses with side shields as
a good safety practice.
SKIN PROTECTION:

No special protective clothing is normally
required. Where splashing is possible,
select protective clothing depending on
operations conducted, physical
requirements and other substances.
Suggested materials for protective
gloves include: Nitrile Rubber, Silver
Shield, Viton.

<0.01 mmHg @ 100°F
>1
BOILING POINT:

>600°F (>315° C)
SOLUBILITY:

Soluble in hydrocarbons, insoluble in
water
FREEZING POINT

NA
MELTING POINT

NA
SPECIFIC GRAVITY:

0.85-0.87 @ 15.6 °C/15.6°C
VOLATILE ORGANIC COMPOUNDS (VOC):

2.9% weight (Approximate)
VISCOSITY:

18.7 cST - 105 cST @40°C

Section 11. Toxicological
Information
IMMEDIATE HEALTH EFFECTS
EYE IRRITATION:

The mean 24-hour Draize eye irritation
score in rabbits is 4.0/110.
SKIN IRRITATION:

For a 24-hour exposure, the
Primary Irritation Score (PIS) in
rabbits is: 0.2/8.0.
SKIN SENSITIZATION:

This material did not cause skin
sensitization reactions in a Buehler
guinea pig test.
ACUTE DERMAL TOXICITY:

The 24 hour(s) LD50 in the rabbit is
>5g/kg.
ACUTE ORAL TOXICITY:

The LD50 in the rat is >5 g/kg.
ACUTE INHALATION TOXICITY:

The acute inhalation toxicity hazard is
based on evaluation of data for similar
materials or product components.
GENETIC TOXICITY:

This product gave negative results in the
following mutagenicity assays:
Microbial/Microsome Reverse Mutation
Assay.
ADDITIONAL TOXICOLOGY INFORMATION:

This product contains petroleum base
oils which may be refined by various
processes including severe solvent
extraction, severe hydrocracking, or
severe hydrotreating. None of the oils
requires a cancer warning under the
OSHA Hazard Communication Standard
(29 CFR 1910.1200). These oils have not
been listed in the National Toxicology
Program (NTP) Annual Report nor have
they been classified by the International
Agency for Research on Cancer (IARC)
as; carcinogenic to humans (Group 1),
probably carcinogenic to humans
(Group 2A), or possibly carcinogenic to
humans (Group 2B).

Section 10. Stability And
Reactivity

Section 12. Ecological
Information:

CHEMICAL STABILITY:

EXOTOXICITY

This material is considered stable under
normal ambient and anticipated storage
and handling conditions of temperature
and pressure.
INCOMPATIBILITY WITH
OTHER MATERIALS:

May react with strong oxidizing agents,
such as chlorates, nitrates, peroxides,
etc.
HAZARDOUS DECOMPOSITION PRODUCTS:

None known (None expected)
HAZARDOUS POLYMERIZATION:

Hazardous polymerization will not occur.

Ten 96 hour(s) LC50 for rainbow trout
(Oncorhynchus mykiss) is >1000 mg/l.
ENVIRONMENTAL FATE
READY BIODEGRADABILITY:

This material is not expected to be
readily biodegradable.

Section 13. Disposal
Considerations
Oil collection services are available for
used oil recycling or disposal. Place
contaminated materials in containers
and dispose of in a manner consistent
2

with applicable regulations. Contact your
sales representative or local
environmental or health authorities for
approved disposal or recyling methods.

Section 14. Transportation
Information
The description shown may not apply to
all shipping situations. Consult 49CFR,
or appropriate Dangerous Goods
Regulations, for additional description
requirements (e.g., technical name) and
mode-specific or quantity-specific
shipping requirements.
DOT SHIPPING NAME:

Not regulated as a hazardous material for
transportation under 49 CFR
DOT HAZARD CLASS:

Not Applicable
DOT IDENTIFICATION NUMBER:

Not Applicable
DOT PACKING GROUP:

Not Applicable

Section 15. Regulatory
Information
SARA 311/312 CATEGORIES:

1.
2.
3.
4.

Immediate (Acute) Health Effects:
Delayed (Chronic) Health Effects:
Fire Hazard:
Sudden Release of
Pressure Hazard:
5. Reactivity Hazard:
REGULATORY LISTS SEARCHED:

4_I1=IARC Group 1
4_I2A=IARC Group 2A
4_I28B=IARC Group 2B
05=NTP Carcinogen
06-OSHA Carcinogen
09-TSCA 12(b)
10=TSCA Section 4
11=TSCA Section 8(a) CAIR
12=TSCA Section 8(a) PAIR
13=TSCA Section 8(d)
15=SARA Section 313
16=CA Proposition 65
17=MA RTK
18=NJ RTK
19=DOT Marine Pollutant
20=PA RTK
21=TSCA Section 5(a)
25=CAA Section 112 HAPs
26=CWA Section 311
28=CWA Section 307
30=RCRA Waste P-List
31-RCRA Waste U-List
32=RCRA Appendix VIII
No components of this material were
found on the regulatory lists above.

No
No
No
No
No

CHEMICAL INVENTORIES:

AUSTRALIA: All the components of this
material are listed on the Australian
Inventory of Chemical Substances
(AICS).
KOREA: All the components of this
product are on the Existing Chemicals
List (ECL) in Korea.
PHILIPPINES: All the components of this
product are listed on the Philippine
Inventory of Chemicals and Chemical
Substances (PICCS).
CANADA: All the components of this
material are on the Canadian Domestic
Substances List (DSL).
EUROPEAN UNION: All the components
of this material are in compliance with
the EU Seventh Amendment Directive
92/32/EEC.
UNITED STATES: All of the components
of this material are on the Toxic
Substances Control Act (TSCA) Chemical
Inventory.
NEW JERSEY RTK CLASSIFICATION:
Under the New Jersey Right-to-Know Act
L. 1983 Chapter 315 N.J.S.A.34:5A-1 et.
seq., the product is to be indentified as
follows: PETROLEUM OIL
WHMIS CLASSIFICATION:

This product is not considered a
controlled product according to the
criteria of the Canadian Controlled
Products Regulations.

Section 16. Other Information
NFPA RATINGS:

Health: Flammability:
0
1

Reactivity:
0

HMIS RATINGS:

Health: Flammability: Reactivity
1
1
0
(0-Least, 1-Slight, 2-Moderate, 3-High,
4-Extreme, PPE:-Personal Protection
Equipment Index recommendation, *Chronic Effect Indicator). These values
are obtained using the guidelines or
published evaluations prepared by the
National Fire Protection Association
(NFPA) or the National Paint and Coating
Association (for HMIS ratings).
Prepared according to the OSHA Hazard
Communication Standard (29 CFR
1910.1200) and the ANSI MSDS
Standard (Z400.1).
The above information is based on the
data of which we are aware and is
believed to be correct as of the date
hereof. Since this information may be
applied under conditions beyond our
control and with which we may be
unfamiliar and since data made available
subsequent to the date hereof may
suggest modifications of the information,
we do not assume any responsibility for
the results of it use. This information is
furnished upon condition that the person
receiving it shall make his own
determination of the suitability of the
material for his particular purpose.

3

Date Prepared: July 1, 1992
Date Reviewed: January 8, 2001

MATERIAL SAFETY DATA SHEET
Product Name:

Acetylene

January 8, 2001

1. Chemical, Product and Company Identification
Linweld, Inc
9911 Deer Park Road
Waverly, NE 68462

Telephone Number
Information: (402) 786-3330
Emergency: (402) 786-5277

Product Name: Acetylene
Chemical Name: Acetylene
Common Names: Acetylene; Ethyne

2. Hazard Ingredients and Identity Information
COMPONENT
Acetylene
Acetone

% VOLUME
95.0 to 99.6
Unavailable

OSHA-PEL
Not Available
1000 ppm TWA

ACGIH-TLV
Simple Asphyxiant
750 ppm TWA
1000 ppm STEL

CAS NUMBER
000074-86-2
000067-64-1

3. Physical and Chemical Characteristics
Boiling Point:
Melting Point:
Vapor Pressure:

-118.8o F
-116o F
635 psig

Specific Gravity:
Evaporation Rate:
Solubility (H2O):

0.906
N/A
Soluble

pH:
Physical State:

N/A
Gas

Appearance and Odor:
Pure acetylene is a colorless gas with an ethereal odor. Commercial (carbide) acetylene has a distinctive garlic-like odor.
How to Detect This Substance:
N/A
Other Physical and Chemical Data:
Liquid density at boiling point, 38.8 lb/ft3 (622 kg/m3)
Gas density at 70o F 1 atm, 0.0691 lb/ft3 (1.107 kg/m3)

4. Fire and Explosion Hazard Data
Flammability Classification:
Ignition Temperature:

Flammable
565o F

Flash Point (F):
Method:

N/A
N/A

LEL (%):
UEL (%):

2.2
82.5

Extinguishing Media:
Carbon dioxide; Dry chemical; Water spray
Fire Fighting Procedures:
Stop flow of gas before extinguishing fire. If flame is small and originating from fusible plug or valve stem, attempt to extinguish
flame. A glove, heavy cloth or any wet material slapped across the flame will frequently extinguish it. If flame is large and
originating from fusible plug, do not attempt to extinguish unless cylinder is outdoors or in a well-ventilated area away from sources
of ignition. Escaping gas may be easily re-ignited by adjacent ignition sources. Use water spray to keep fire-exposed containers
cool. Burning or heated cylinders may rupture violently. Approach fire from upwind to avoid hazardous vapors and toxic
decomposition products. Fight fire from protected location or maximum possible distance.
Fire & Explosion Hazard:
Gaseous acetylene is spontaneously combustible in air at pressure above 30 pi. Acetylene requires very low ignition energy;
therefore extinguished fires may easily re-ignite if the flow of gas is not stopped. Acetylene has a density very similar to that of air,
so leaking acetylene does not readily dissipate. Gas may travel to an ignition source and flash back.

5. Reactivity Data
Stability:

Unstable

Hazardous Polymerization:

May occur

Incompatibility:
Oxygen and oxidizers including halogens and halogen compounds. Forms explosive acetylide compounds with copper, mercury,
silver, brass (>66% copper), and brazing materials containing silver or copper.

Page 1 of 4

Product Name:

Acetylene

January 8, 2001

5. Reactivity Data (Continued)
Conditions to Avoid:
Do not allow free gas (outside of cylinder) to exceed 30 psi. Cylinders should not be exposed to sudden shock or sources of heat.
Hazardous Decomposition or Byproducts:
Under high pressure, acetylene decomposes to carbon and hydrogen. Carbon monoxide may be produced from burning.
Under certain conditions, acetylene forms acetylide compounds when in contact with copper, silver and mercury.

Other Reactivity Data:
Flammable over an extremely wide range in air. Explosive reactions may occur on ignition. Reacts explosively with halogens and
halogenated compounds.
Electrical classification: Class 1, Group A

6. Health Hazard Data
Route(s) of Entry:

Health Hazards:
Acute

Chronic

Eye contact
No

Skin Contact
No

Inhalation
Yes

Ingestion
No

Skin Absorption
No

Product is a simple asphyxiant. Effects of oxygen deficiency may include any, all or none of the
following: rapid breathing, diminished mental alertness, impaired muscle coordination, blurred speech,
and fatigue. As asphyxiation progresses, nausea, vomiting, and loss of consciousness may occur,
eventually leading to convulsions, coma and death.
N/A

Carcinogenicity:

NTP
No

IARC Monographs
No

OSHA
No

Signs and Symptoms of Exposure and Emergency First Aid Procedures:
Eye Contact
N/A
Skin Contact
Inhalation

N/A
Product is a simple asphyxiant. Effects of oxygen deficiency may include any, all or none of the
following: rapid breathing, diminished mental alertness, impaired muscle coordination, blurred speech,
and fatigue. As asphyxiation progresses, nausea, vomiting, and loss of consciousness may occur,
eventually leading to convulsions, coma and death.
Under normal operating conditions, acetone is not released from the cylinder. However, if the cylinder
is overcharged with acetone or acetylene, acetone may occasionally "spit" out. Acetone is primarily a
central nervous system toxin causing headache, nausea, dizziness, vomiting and fatigue. Moderate
concentrations may cause respiratory irritation.
Conscious victim should be assisted to an uncontaminated area and allowed to inhale fresh air.
Unconscious victim should be moved to an uncontaminated area and given assisted respiration with
supplemental oxygen. Further treatment should be symptomatic and supportive.

Ingestion

N/A

Medical Conditions Aggravated by Exposure:
Persons having health conditions that may be aggravated by exposure to acetylene should not be allowed to work with this
product.

7. Precautions for Safe Handling and Use
Actions if Released or Spilled:
Evacuate all personnel from affected area. Use appropriate personal protective equipment.
If possible to do so safely, shut off all ignition sources and close cylinder valve. For small leaks, the cylinder may be moved
outdoors and away from ignition sources. If leak is in the user's equipment, be certain to purge piping with inert gas prior to
attempting repairs. If leak is in cylinder or cylinder valve, contact the nearest distributor.

Page 2 of 4

Product Name:

Acetylene

January 8, 2001

7. Precautions for Safe Handling and Use (Continued)
Waste Disposal Method:
Do not attempt to dispose of waste or unused quantities. Return in properly labeled shipping container, with any valve outlet plugs
or caps secured and valve protection caps in place.
Handling and Storage Precautions:
Use only in well-ventilated areas. Valve protection caps must remain in place unless cylinder is secured with valve outlet piped to
point of use. Do not drag, slide or roll cylinders. Use a suitable hand truck for cylinder movement. Use a pressure-reducing
regulator when connecting cylinder to lower pressure piping or systems. Do not heat cylinder. Use a check valve or trap in the
discharge line to prevent hazardous backflow into the cylinder.
Protect cylinders from physical damage. Store in cool, dry, well-ventilated area away from heavy traffic areas and emergency exits.
Do not allow temperature of cylinder storage area to exceed 125o F. Cylinders should be stored upright and firmly secured to
prevent falling or being knocked over. Full and empty cylinders should be segregated. Acetylene cylinders should never be stored
on their sides. This makes the acetylene unstable and increases the likelihood of solvent release during use. Do not attempt to
repair or alter cylinders. Do not tamper with the valve, pressure relief devices or fusible plugs. If the fusible plug or valve begins to
leak, move the cylinder to an open area and contact the nearest distributor. A leaking cylinder should be properly marked to
prevent further use. Never allow a torch flame to come in contact with the cylinder or fusible plug.
Do not store acetylene within 20 feet of oxygen or combustible materials unless separated by a one-half hour rated 5 feet high
firewall. Post "NO SMOKING OR OPEN FLAMES" signs in the storage and use area.
Other Precautions:
To prevent solvent withdrawal from the cylinder during use, always follow supplier instructions for maximum withdrawal rate for
each size of cylinder.
Compressed gas cylinders should only be refilled by qualified personnel. Shipment of compressed gas cylinders, which have been
filled without the consent of the cylinder owner, is a violation of federal law (49 CFR).
Always secure cylinders in an upright position during transportation. Never transport cylinders in enclosed space such as a vehicle
truck or van.
For additional recommendations, see CGA Pamphlets P-1, G-1, SB-4; NFPA 51; OSHA 1910 Subpart H and Q.
Transportation Information:
Shipping Name
Hazard Class
ID Number
Shipping Label - 1
NFPA Rating:
Health: 0

Acetylene, dissolved
2.1
UN1001
Flammable Gas

Flammability:

4

Reactivity:

0

8. Control Measures
Eye Protection:
Safety goggles or glasses as appropriate.
Protective Gloves:
PVC or rubber gloves for laboratory use; as required for welding and cutting.
Respiratory Protection:
Positive pressure air line with mask or self-contained breathing apparatus should be available for emergency use.
Ventilation:
Local exhaust to prevent acetylene accumulation above the exposure limit and to maintain oxygen concentration above 19.5%.
Mechanical ventilation should be designed in accordance with electrical codes.
Other Protective Clothing or Equipment:
Safety shoes, safety shower.

Page 3 of 4

Product Name:

Acetylene

January 8, 2001

9. Regulatory Information
Acetone is regulated as a Hazardous Substance under CERCLA
Acetylene is listed under the Clean Air Act (CAA) Section 112(r) with a threshold quantity (TQ) of 10,000 pounds.
SARA TITLE III NOTIFICATIONS AND INFORMATION
Releases of acetone in quantities equal to or greater than the reportable quantity (RQ) of 5,000 pounds are subject to reporting to
the National Response Center under CERCLA, Section 304 SARA Title III.
Sara Title III – Section 313 Supplier Notification
This product does not contain toxic chemicals subject to reporting requirements of section 313 of the Emergency Planning and
Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372.
SARA Title III – Hazard Classes
Acute Health Hazard
Fire Hazard
Sudden Release of Pressure Hazard
Reactivity Hazard

Disclaimer of Expressed and Implied Warranties
Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no
representations as to the accuracy or completeness of the information contained herein, and assume no responsibility regarding
the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a
determination as to the suitability of the information for their particular purpose.

Page 4 of 4

Date Prepared: July 1, 1992
Date Reviewed: January 8, 2001

MATERIAL SAFETY DATA SHEET
Product Name:

Acetylene

January 8, 2001

1. Chemical, Product and Company Identification
Linweld, Inc
9911 Deer Park Road
Waverly, NE 68462

Telephone Number
Information: (402) 786-3330
Emergency: (402) 786-5277

Product Name: Acetylene
Chemical Name: Acetylene
Common Names: Acetylene; Ethyne

2. Hazard Ingredients and Identity Information
COMPONENT
Acetylene
Acetone

% VOLUME
95.0 to 99.6
Unavailable

OSHA-PEL
Not Available
1000 ppm TWA

ACGIH-TLV
Simple Asphyxiant
750 ppm TWA
1000 ppm STEL

CAS NUMBER
000074-86-2
000067-64-1

3. Physical and Chemical Characteristics
Boiling Point:
Melting Point:
Vapor Pressure:

-118.8o F
-116o F
635 psig

Specific Gravity:
Evaporation Rate:
Solubility (H2O):

0.906
N/A
Soluble

pH:
Physical State:

N/A
Gas

Appearance and Odor:
Pure acetylene is a colorless gas with an ethereal odor. Commercial (carbide) acetylene has a distinctive garlic-like odor.
How to Detect This Substance:
N/A
Other Physical and Chemical Data:
Liquid density at boiling point, 38.8 lb/ft3 (622 kg/m3)
Gas density at 70o F 1 atm, 0.0691 lb/ft3 (1.107 kg/m3)

4. Fire and Explosion Hazard Data
Flammability Classification:
Ignition Temperature:

Flammable
565o F

Flash Point (F):
Method:

N/A
N/A

LEL (%):
UEL (%):

2.2
82.5

Extinguishing Media:
Carbon dioxide; Dry chemical; Water spray
Fire Fighting Procedures:
Stop flow of gas before extinguishing fire. If flame is small and originating from fusible plug or valve stem, attempt to extinguish
flame. A glove, heavy cloth or any wet material slapped across the flame will frequently extinguish it. If flame is large and
originating from fusible plug, do not attempt to extinguish unless cylinder is outdoors or in a well-ventilated area away from sources
of ignition. Escaping gas may be easily re-ignited by adjacent ignition sources. Use water spray to keep fire-exposed containers
cool. Burning or heated cylinders may rupture violently. Approach fire from upwind to avoid hazardous vapors and toxic
decomposition products. Fight fire from protected location or maximum possible distance.
Fire & Explosion Hazard:
Gaseous acetylene is spontaneously combustible in air at pressure above 30 pi. Acetylene requires very low ignition energy;
therefore extinguished fires may easily re-ignite if the flow of gas is not stopped. Acetylene has a density very similar to that of air,
so leaking acetylene does not readily dissipate. Gas may travel to an ignition source and flash back.

5. Reactivity Data
Stability:

Unstable

Hazardous Polymerization:

May occur

Incompatibility:
Oxygen and oxidizers including halogens and halogen compounds. Forms explosive acetylide compounds with copper, mercury,
silver, brass (>66% copper), and brazing materials containing silver or copper.

Page 1 of 4

Product Name:

Acetylene

January 8, 2001

5. Reactivity Data (Continued)
Conditions to Avoid:
Do not allow free gas (outside of cylinder) to exceed 30 psi. Cylinders should not be exposed to sudden shock or sources of heat.
Hazardous Decomposition or Byproducts:
Under high pressure, acetylene decomposes to carbon and hydrogen. Carbon monoxide may be produced from burning.
Under certain conditions, acetylene forms acetylide compounds when in contact with copper, silver and mercury.

Other Reactivity Data:
Flammable over an extremely wide range in air. Explosive reactions may occur on ignition. Reacts explosively with halogens and
halogenated compounds.
Electrical classification: Class 1, Group A

6. Health Hazard Data
Route(s) of Entry:

Health Hazards:
Acute

Chronic

Eye contact
No

Skin Contact
No

Inhalation
Yes

Ingestion
No

Skin Absorption
No

Product is a simple asphyxiant. Effects of oxygen deficiency may include any, all or none of the
following: rapid breathing, diminished mental alertness, impaired muscle coordination, blurred speech,
and fatigue. As asphyxiation progresses, nausea, vomiting, and loss of consciousness may occur,
eventually leading to convulsions, coma and death.
N/A

Carcinogenicity:

NTP
No

IARC Monographs
No

OSHA
No

Signs and Symptoms of Exposure and Emergency First Aid Procedures:
Eye Contact
N/A
Skin Contact
Inhalation

N/A
Product is a simple asphyxiant. Effects of oxygen deficiency may include any, all or none of the
following: rapid breathing, diminished mental alertness, impaired muscle coordination, blurred speech,
and fatigue. As asphyxiation progresses, nausea, vomiting, and loss of consciousness may occur,
eventually leading to convulsions, coma and death.
Under normal operating conditions, acetone is not released from the cylinder. However, if the cylinder
is overcharged with acetone or acetylene, acetone may occasionally "spit" out. Acetone is primarily a
central nervous system toxin causing headache, nausea, dizziness, vomiting and fatigue. Moderate
concentrations may cause respiratory irritation.
Conscious victim should be assisted to an uncontaminated area and allowed to inhale fresh air.
Unconscious victim should be moved to an uncontaminated area and given assisted respiration with
supplemental oxygen. Further treatment should be symptomatic and supportive.

Ingestion

N/A

Medical Conditions Aggravated by Exposure:
Persons having health conditions that may be aggravated by exposure to acetylene should not be allowed to work with this
product.

7. Precautions for Safe Handling and Use
Actions if Released or Spilled:
Evacuate all personnel from affected area. Use appropriate personal protective equipment.
If possible to do so safely, shut off all ignition sources and close cylinder valve. For small leaks, the cylinder may be moved
outdoors and away from ignition sources. If leak is in the user's equipment, be certain to purge piping with inert gas prior to
attempting repairs. If leak is in cylinder or cylinder valve, contact the nearest distributor.

Page 2 of 4

Product Name:

Acetylene

January 8, 2001

7. Precautions for Safe Handling and Use (Continued)
Waste Disposal Method:
Do not attempt to dispose of waste or unused quantities. Return in properly labeled shipping container, with any valve outlet plugs
or caps secured and valve protection caps in place.
Handling and Storage Precautions:
Use only in well-ventilated areas. Valve protection caps must remain in place unless cylinder is secured with valve outlet piped to
point of use. Do not drag, slide or roll cylinders. Use a suitable hand truck for cylinder movement. Use a pressure-reducing
regulator when connecting cylinder to lower pressure piping or systems. Do not heat cylinder. Use a check valve or trap in the
discharge line to prevent hazardous backflow into the cylinder.
Protect cylinders from physical damage. Store in cool, dry, well-ventilated area away from heavy traffic areas and emergency exits.
Do not allow temperature of cylinder storage area to exceed 125o F. Cylinders should be stored upright and firmly secured to
prevent falling or being knocked over. Full and empty cylinders should be segregated. Acetylene cylinders should never be stored
on their sides. This makes the acetylene unstable and increases the likelihood of solvent release during use. Do not attempt to
repair or alter cylinders. Do not tamper with the valve, pressure relief devices or fusible plugs. If the fusible plug or valve begins to
leak, move the cylinder to an open area and contact the nearest distributor. A leaking cylinder should be properly marked to
prevent further use. Never allow a torch flame to come in contact with the cylinder or fusible plug.
Do not store acetylene within 20 feet of oxygen or combustible materials unless separated by a one-half hour rated 5 feet high
firewall. Post "NO SMOKING OR OPEN FLAMES" signs in the storage and use area.
Other Precautions:
To prevent solvent withdrawal from the cylinder during use, always follow supplier instructions for maximum withdrawal rate for
each size of cylinder.
Compressed gas cylinders should only be refilled by qualified personnel. Shipment of compressed gas cylinders, which have been
filled without the consent of the cylinder owner, is a violation of federal law (49 CFR).
Always secure cylinders in an upright position during transportation. Never transport cylinders in enclosed space such as a vehicle
truck or van.
For additional recommendations, see CGA Pamphlets P-1, G-1, SB-4; NFPA 51; OSHA 1910 Subpart H and Q.
Transportation Information:
Shipping Name
Hazard Class
ID Number
Shipping Label - 1
NFPA Rating:
Health: 0

Acetylene, dissolved
2.1
UN1001
Flammable Gas

Flammability:

4

Reactivity:

0

8. Control Measures
Eye Protection:
Safety goggles or glasses as appropriate.
Protective Gloves:
PVC or rubber gloves for laboratory use; as required for welding and cutting.
Respiratory Protection:
Positive pressure air line with mask or self-contained breathing apparatus should be available for emergency use.
Ventilation:
Local exhaust to prevent acetylene accumulation above the exposure limit and to maintain oxygen concentration above 19.5%.
Mechanical ventilation should be designed in accordance with electrical codes.
Other Protective Clothing or Equipment:
Safety shoes, safety shower.

Page 3 of 4

Product Name:

Acetylene

January 8, 2001

9. Regulatory Information
Acetone is regulated as a Hazardous Substance under CERCLA
Acetylene is listed under the Clean Air Act (CAA) Section 112(r) with a threshold quantity (TQ) of 10,000 pounds.
SARA TITLE III NOTIFICATIONS AND INFORMATION
Releases of acetone in quantities equal to or greater than the reportable quantity (RQ) of 5,000 pounds are subject to reporting to
the National Response Center under CERCLA, Section 304 SARA Title III.
Sara Title III – Section 313 Supplier Notification
This product does not contain toxic chemicals subject to reporting requirements of section 313 of the Emergency Planning and
Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372.
SARA Title III – Hazard Classes
Acute Health Hazard
Fire Hazard
Sudden Release of Pressure Hazard
Reactivity Hazard

Disclaimer of Expressed and Implied Warranties
Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no
representations as to the accuracy or completeness of the information contained herein, and assume no responsibility regarding
the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a
determination as to the suitability of the information for their particular purpose.

Page 4 of 4

Page 1 of 1

CHEMetrics, Inc.
4295 Catlett Rd., Calverton, VA 20138
(800) 356-3072 (540) 788-9026
Fax (540) 788-4856 E-mail technical@chemetrics.com

24 Hour Emergency Numbers:
Creation Date:
Revision Date:

(703) 590-9204
(540) 439-3860
04/22/86 (1072-14)
07/22/04

MATERIAL SAFETY DATA SHEET
I. CHEMICAL IDENTIFICATION

IX. PHYSICAL AND CHEMICAL PROPERTIES

TRADE NAMES: DISSOLVED OXYGEN CHEMets®, ULR CHEMets®, and
Vacu-vials®

STATE: Liquid APPEARANCE: Colorless to pale yellow ODOR: None
SOLUBILITY IN WATER: Miscible pH: 11.5
BOILING POINT: 150°C MELTING POINT: -5.0°C
VAPOR PRESSURE: N/A SPECIFIC GRAVITY: 1.03
VAPOR DENSITY: N/A

CATALOG NOS.: R-7501, R-7501V, R-7511, R-7518, R-7540, R-7540G,
R-7540V and R-7553
DESCRIPTION: Reagent ampoules for the determination of dissolved oxygen
in water. Each CHEMet™ contains approximately 0.50 mL of liquid reagent
sealed under vacuum. Each ULR CHEMet™ contains approximately 1 mL of
liquid reagent sealed under vacuum. Each Vacu-vial™ contains approximately 2 mL of liquid reagent sealed under vacuum.

X. STABILITY AND REACTIVITY
INCOMPATIBILITIES: Acids
HAZARDOUS DECOMPOSITION PRODUCTS: When heated to decomposition, oxides of carbon may be emitted.
Stable under normal conditions.

NFPA RATINGS: HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0

II. COMPOSITION/INFORMATION ON INGREDIENTS
COMPONENT: Diethylene Glycol
CAS NO.:
111-46-6
PERCENT:

XI. TOXICOLOGICAL INFORMATION
CARCINOGEN STATUS: None
No other data available at this time.

25.0

XII. ECOLOGICAL INFORMATION
COMPONENT: Deionized Water
CAS NO.:
7732-18-5
PERCENT: >74.0
COMPONENT: Other components
CAS NO.:
N/A
PERCENT: < 1.0

Diethylene Glycol has a low bioconcentration potential and is practically nontoxic to aquatic organisms.
No other data available at this time.

XIII. DISPOSAL CONSIDERATIONS
Any component of this mixture not specifically listed (e.g. "other components")
is not considered to present a carcinogen hazard.

Dispose of in a manner consistent with Federal, State and Local Regulations.

III. HAZARDS IDENTIFICATION

XIV. TRANSPORT INFORMATION

Harmful if swallowed.
ACUTE TOXICITY: Irritation, nausea, diarrhea, nerve depression
CHRONIC TOXICITY: Irritation, liver or kidney lesions
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye, skin, liver or
kidney disorders

Not regulated.

XV. REGULATORY INFORMATION

EYE AND SKIN CONTACT: Immediately flush eyes and skin with water for
15 minutes.
INGESTION: If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Seek medical
attention.
INHALATION: Remove individual to fresh air.

EUROPEAN INFORMATION:
EU Symbols: Xn - HARMFUL
Risk Phrases: Harmful if swallowed.
Safety Phrases: If swallowed, seek medical advice immediately (show the
label where possible).
CANADIAN INFORMATION:
WHMIS Classification: D2B
All chemical components of this product are listed on Canada’s DSL list.
U.S. INFORMATION:
All chemical components of this product are listed on the TSCA Inventory.

V. FIRE FIGHTING MEASURES

XVI. OTHER INFORMATION

FLASH POINT: N/A AUTOIGNITION POINT: N/A
FLAMMABILITY LIMITS: UPPER: N/A LOWER: N/A
EXTINGUISHING MEDIA: Dry chemical, carbon dioxide, water spray or foam

VI. ACCIDENTAL RELEASE MEASURES

THE ABOVE INFORMATION IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST
INFORMATION CURRENTLY AVAILABLE TO US. ALL PRODUCTS ARE OFFERED IN
ACCORDANCE WITH THE MANUFACTURER'S CURRENT PRODUCTION SPECIFICATIONS
AND ARE INTENDED SOLELY FOR USE IN ANALYTICAL TESTING. THE MANUFACTURER
SHALL IN NO EVENT BE LIABLE FOR ANY INJURY, LOSS OR DAMAGE RESULTING FROM
THE HANDLING, USE OR MISUSE OF THESE PRODUCTS.

Take up with absorbent material. Place in small containers for disposal.

CHEMets®, ULR CHEMets® and Vacu-vials® are registered trademarks of CHEMetrics, Inc.

IV. FIRST AID MEASURES

VII. HANDLING AND STORAGE
If this product is used as directed, the user will not come in contact with or be
exposed to any of its chemical components.
Wash thoroughly after handling. Avoid contact with eyes.
Fragile. Liquid in glass. Handle with care.
The reagent in these ampoules is light sensitive. Product should be stored in
the dark and at room temperature; however, temperatures up to 120°F or
even below freezing will not normally affect reagent performance.

VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION
OSHA PEL & ACGIH TLV: N/A
PROTECTIVE EQUIPMENT: Safety glasses

B
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SAFETY DATA SHEET

Revised edition no : 1
Date : 15/7/2005
Supersedes : 0/0/0

Nitrous oxide (refrigerated)

AL093B

nó
ó
t
Label 2.2 : Non
flammable, non toxic
gas.

ê
O

Label 5.1 : Oxidizing
substances.

O : Oxidizing

1 IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING
:
:
:
:

Nitrous oxide (refrigerated)
AL093B
N2O
AIR LIQUIDE SA
France
See paragraph 16 "OTHER INFORMATION"
: See paragraph 16 "OTHER INFORMATION"

Trade name
MSDS No
Chemical formula
Company identification

Emergency phone nr

2 COMPOSITION / INFORMATION ON INGREDIENTS
: Substance.

Substance / Preparation
Substance name
Nitrous oxide (refrigerated)

:

Contents
100 %

CAS No
10024-97-2

EC No
233-032-0

Index No
-----

Classification
O; R8

Contains no other components or impurities which will influence the classification of the product.

3 HAZARDS IDENTIFICATION
Hazards identification

: Refrigerated liquefied gas. Contact with product may cause cold burns or frostbite.
Oxidant. Strongly supports combustion. May react violently with combustible
materials.

4 FIRST AID MEASURES
First aid measures
- Inhalation

- Skin/eye contact

- Ingestion

: In high concentrations may cause asphyxiation. Symptoms may include loss of
mobility/consciousness. Victim may not be aware of asphyxiation.
In low concentrations may cause narcotic effects. Symptoms may include
dizziness, headache, nausea and loss of co-ordination.
Remove victim to uncontaminated area wearing self contained breathing
apparatus. Keep victim warm and rested. Call a doctor. Apply artificial respiration if
breathing stopped.
: Immediately flush eyes thoroughly with water for at least 15 minutes.
In case of frostbite spray with water for at least 15 minutes. Apply a sterile dressing.
Obtain medical assistance.
: Ingestion is not considered a potential route of exposure.

5 FIRE-FIGHTING MEASURES
Flammable class
Specific hazards
Hazardous combustion products

AIR LIQUIDE SA
France

: Non flammable.
: Exposure to fire may cause containers to rupture/explode.
Supports combustion.
: If involved in a fire the following toxic and/or corrosive fumes may be produced by
thermal decomposition :
Nitric oxide/nitrogen dioxide.

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SAFETY DATA SHEET

Revised edition no : 1
Date : 15/7/2005
Supersedes : 0/0/0

Nitrous oxide (refrigerated)

AL093B

5 FIRE-FIGHTING MEASURES (continued)
Extinguishing media
- Suitable extinguishing media
Specific methods

: All known extinguishants can be used.
: If possible, stop flow of product.
Move away from the container and cool with water from a protected position.
If leaking do not spray water onto container. Water surrounding area (from
protected position) to contain fire.
Special protective equipment for fire : Use self-contained breathing apparatus and chemically protective clothing.
fighters

6 ACCIDENTAL RELEASE MEASURES
Personal precautions

Environmental precautions

Clean up methods

: Evacuate area.
Ensure adequate air ventilation.
Eliminate ignition sources.
Wear self-contained breathing apparatus when entering area unless atmosphere is
proved to be safe.
Use protective clothing.
: Try to stop release.
Prevent from entering sewers, basements and workpits, or any place where its
accumulation can be dangerous.
: Ventilate area.
Keep area evacuated and free from ignition sources until any spilled liquid has
evaporated. (Ground free from frost).

7 HANDLING AND STORAGE
Storage
Handling

: Segregate from flammable gases and other flammable materials in store.
Keep container below 50°C in a well ventilated place.
: Use no oil or grease.
Open valve slowly to avoid pressure shock.
Suck back of water into the container must be prevented.
Do not allow backfeed into the container.
Use only properly specified equipment which is suitable for this product, its supply
pressure and temperature. Contact your gas supplier if in doubt.
Keep away from ignition sources (including static discharges).
Refer to supplier's container handling instructions.

8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection

Occupational Exposure Limits

: Do not smoke while handling product.
Ensure adequate ventilation.
Protect eyes, face and skin from liquid splashes.
: Nitrous oxide (refrigerated) : TLV© -TWA [ppm] : 50
Nitrous oxide (refrigerated) : OEL (UK)-LTEL [ppm] : 100
Nitrous oxide (refrigerated) : MAK - Germany [ppm] : 100

9 PHYSICAL AND CHEMICAL PROPERTIES
Physical state at 20 °C
Colour
Odo(u)r

AIR LIQUIDE SA
France

: Refrigerated liquefied gas.
: Colourless liquid.
: Sweetish.
Poor warning properties at high concentrations.

B
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SAFETY DATA SHEET

Revised edition no : 1
Date : 15/7/2005
Supersedes : 0/0/0

Nitrous oxide (refrigerated)

AL093B

9 PHYSICAL AND CHEMICAL PROPERTIES (continued)
Molecular weight
Melting point [°C]
Boiling point [°C]
Critical temperature [°C]
Vapour pressure, 20°C
Relative density, gas (air=1)
Relative density, liquid (water=1)
Solubility in water [mg/l]
Flammability range [vol% in air]
Auto-ignition temperature [°C]
Other data

:
:
:
:
:
:
:
:
:
:
:

44
-90.81
-88.5
36.4
50.8 bar
1.5
1.2
2.2
Oxidiser.
Not applicable.
Gas/vapour heavier than air. May accumulate in confined spaces, particularly at or
below ground level.

10 STABILITY AND REACTIVITY
Stability and reactivity

: May react violently with combustible materials.
May react violently with reducing agents.
Violently oxidises organic material.
Thermal decomposition yields toxic products which can be corrosive in the
presence of moisture. At temperatures over 575°C and at atmospheric pressure,
nitrous oxide decomposes into nitrogen and oxygen. Pressurized nitrous oxide can
also decompose at temperatures equal or greater than 300°C. In the presence of
catalysts (e.g. halogen products, mercury, nickel, platinum) the rate of
decomposition increases and decomposition can occur at even lower
temperatures. Nitrous oxide dissociation is irreversible and exothermic, leading to a
considerable rise in pressure.
Liquid spillages can cause embrittlement of structural materials.

11 TOXICOLOGICAL INFORMATION
Toxicity information

: No known toxicological effects from this product.

12 ECOLOGICAL INFORMATION
Ecological effects information
Global warming factor [CO2=1]

: Can cause frost damage to vegetation.
When discharged in large quantities may contribute to the greenhouse effect.
: 310

13 DISPOSAL CONSIDERATIONS
General

: To atmosphere in a well ventilated place.
Do not discharge into any place where its accumulation could be dangerous.
Contact supplier if guidance is required.
Discharge to atmosphere in large quantities should be avoided.

14 TRANSPORT INFORMATION
UN No.
H.I. nr
ADR/RID

AIR LIQUIDE SA
France

: 2201
: 225

B
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SAFETY DATA SHEET

Revised edition no : 1
Date : 15/7/2005
Supersedes : 0/0/0

Nitrous oxide (refrigerated)

AL093B

14 TRANSPORT INFORMATION (continued)
- Proper shipping name
- ADR Class
- ADR/RID Classification code
- Labelling ADR
Other transport information

:
:
:
:

NITROUS OXIDE, REFRIGERATED LIQUID
2
3O
Label 2.2 : Non flammable, non toxic gas.
Label 5.1 : Oxidizing substances.
: Avoid transport on vehicles where the load space is not separated from the driver's
compartment.
Ensure vehicle driver is aware of the potential hazards of the load and knows what
to do in the event of an accident or an emergency.
Before transporting product containers :
- Ensure that containers are firmly secured.
- Ensure cylinder valve is closed and not leaking.
- Ensure valve outlet cap nut or plug (where provided) is correctly fitted.
- Ensure valve protection device (where provided) is correctly fitted.
- Ensure there is adequate ventilation.
- Compliance with applicable regulations.

15 REGULATORY INFORMATION
EC Classification

EC Labelling
- Symbol(s)
- R Phrase(s)
- S Phrase(s)

: Not included in Annex I.
Proposed by the industry.
O; R8
: O : Oxidizing
: R8 : Contact with combustible material may cause fire.
: S9 : Keep container in a well-ventilated place.
S17 : Keep away from combustible material.
S36 : Wear suitable protective clothing.

16 OTHER INFORMATION
Asphyxiant in high concentrations.
May cause frostbite.
The hazard of asphyxiation is often overlooked and must be stressed during operator training.
Ensure all national/local regulations are observed.
This Safety Data Sheet has been established in accordance with the applicable European Directives and applies to all
countries that have translated the Directives in their national laws.
Before using this product in any new process or experiment, a thorough material compatibility and safety study should be
carried out.
Details given in this document are believed to be correct at the time of going to press. Whilst proper care has been taken in
the preparation of this document, no liability for injury or damage resulting from its use can be accepted.
Recommended uses and restrictions : This SDS is for information purposes only and is subject to change without notice. [
Prior to purchase of products, please contact your local AIR LIQUIDE office for a
complete SDS (with Manufacturer's name and emergency phone number).]
End of document

AIR LIQUIDE SA
France

Material Safety Data Sheet: Nitrogen

Product Name: Nitrogen

CAS: 7727-37-9

Nitrogen; Nitrogen, compressed (D.O.T.)

DOT I.D No.: UN 1066

Chemical Name and Synonyms:
Nitrogen

DOT Hazard Class: Division 2.2

Formula: N2

Chemical Family: Inert Gas

HEALTH HAZARD DATA
Time Weighted Average Exposure Limit:
Nitrogen is defined as a simple asphyxiant (ACGIH 1994-1995i; OSHA 1993 PEL (8 Hr.
TWA) = None listed.
Symptoms of Exposure:
Effects of exposure to high concentrations so as to displace the oxygen in air necessary
for life may include any, all or none of the following: • Loss of balance or dizziness •
Tightness in the frontal area of the forehead.
Toxicological Properties:
•

Nitrogen is nontoxic but the liberation of a large amount in a confined area could
displace the amount of oxygen in air necessary to support life.

•

Nitrogen is not listed in the LARC, NTP or by OSHA as a carcinogen or potential
carcinogen.

•

Persons in ill health where such illness would be aggravated by exposure to
nitrogen should not be allowed to work with or handle this product.

Recommended First Aid Treatment:
Prompt medical attention is mandatory in all cases of overexposure to nitrogen. Rescue
personnel should be equipped with self-contained breathing apparatus.

Inhalation: Conscious persons should be assisted to an uncontaminated area and inhale
fresh air. Quick removal from the contaminated area is most important. Unconscious
persons should be moved to an uncontaminated area, given assisted respiration and
supplemental oxygen. Further treatment should be symptomatic and supportive.

Hazardous Mixtures of other Liquids, Solids or Gases:
None.
PHYSICAL DATA
Boiling Point: -320.5°F (-195.8°C)

Liquid Density at Boiling Point:
4.43 lb/ft3 (70.96 kg/m3)

Vapor Pressure @ 70°F (21.1°C) = Above the
critical temperature of -232.6°F (-147°C)

Gas Density at 70°F. 1 atm .0725
lb/ft3 (1.161 kq/m3)

Solubility in Water: Very slightly

Freezing Point: -345.9°F (-209.9°C)

Evaporation Rate: N/A (Gas)

Specific Gravity (AIR=1) @ 70°F
(21.1°C) = 0.97

Appearance and Odor: Colorless, odorless gas

FIRE AND EXPLOSION HAZARD DATA
Flash Point (Method used):
N/A Gas

Auto Ignition Temperature:
N/A

Extinguishing Media: Carbon dioxide, dry chemical

Flammable Limits %
by Volume: LEL N/A
UEL N/A
Electrical
Classification:
Nonhazardous

Special Fire fighting Procedures: Nonflammable inert gas
Unusual Fire and Explosion Hazards: If cylinders are involved in a fire, safely relocate or
keep cool with water spray.

REACTIVITY DATA
Stability: Stable
Incompatibility (Materials to Avoid): None
Hazardous Decomposition Products: None
Hazardous Polymerization: Will not occur
Conditions to Avoid: None

SPILL OR LEAK PROCEDURES
Steps to be taken in case material is released or spilled:
Evacuate all personnel from affected area. Use appropriate protective equipment. If leak
is in container or container valve, contact your closest supplier location or call the
emergency telephone number listed herein.
Waste disposal methods:
Do not attempt to dispose of waste or unused quantities. Return in the shipping
container properly labeled, with any valve outlet plugs or caps secured and valve
protection cap in place to your supplier. For emergency disposal assistance, contact
your closest supplier location or call the emergency telephone number listed herein.

SPECIAL PROTECTION INFORMATION
Respiratory Protection (Specify type): Positive pressure air line with mask or selfcontained breathing apparatus should be available for emergency use.
Ventilation: See Local Exhaust
Protective Gloves: Any material
Eye Protection: Safety goggles or glasses
Other Protective Equipment: Safety shoes

SPECIAL PRECAUTIONS
Special Labeling Information:
DOT Shipping Name: Nitrogen, Compressed
DOT Hazard Class: Division 2.2
DOT Shipping Label: Nonflammable Gas
I.D. No.: UN 1066
Special Handling Recommendation:
Use only in well-ventilated areas. Valve protection caps must remain in place unless
cylinder is secured with valve outlet piped to use point. Do not drag, slide or roll
cylinders. Use a suitable hand truck for cylinder movement. Use a pressure reducing
regulator when connecting cylinder to lower pressure (<3,000 psig) piping or systems.
Do not heat cylinder by any means to increase the discharge rate of product from
cylinder. Use a check valve or trap in the discharge line to prevent hazardous back flow
into the cylinder. For additional handling recommendations, consult Compressed Gas
Association’s Pamphlets P-1, P-9, P-14, and Safety Bulletin SB-2.

Special Storage Recommendations:
Protect cylinders from physical damage. Store in cool, dry, well-ventilated area away
from heavily trafficked areas and emergency exits. Do not allow the temperature where
cylinders are stored to exceed 125F (52C). Cylinders should be stored upright and firmly
secured to prevent falling or being knocked over. Full and empty cylinders should be
segregated. Use a “first in -first out” inventory system to prevent full cylinders being
stored for excessive periods of time. For additional storage recommendations, consult
Compressed Gas Association’s Pamphlets P-1, P-9, P-14, and Safety Bulletin SB-2.
Other Recommendations or Precautions:
Compressed gas cylinders should not be refilled except by qualified producers of
compressed gases. Shipment of a compressed gas cylinder which has not been filled by
the owner or with his (written) consent is a violation of Federal Law (49CFR).
Special Packaging Recommendations:
Nitrogen is non-corrosive and may be used with any common structural materials.

www.isocinfo.com

Material Safety Data Sheet: Nitrogen

Product Name: Nitrogen

CAS: 7727-37-9

Nitrogen; Nitrogen, compressed (D.O.T.)

DOT I.D No.: UN 1066

Chemical Name and Synonyms:
Nitrogen

DOT Hazard Class: Division 2.2

Formula: N2

Chemical Family: Inert Gas

HEALTH HAZARD DATA
Time Weighted Average Exposure Limit:
Nitrogen is defined as a simple asphyxiant (ACGIH 1994-1995i; OSHA 1993 PEL (8 Hr.
TWA) = None listed.
Symptoms of Exposure:
Effects of exposure to high concentrations so as to displace the oxygen in air necessary
for life may include any, all or none of the following: • Loss of balance or dizziness •
Tightness in the frontal area of the forehead.
Toxicological Properties:
•

Nitrogen is nontoxic but the liberation of a large amount in a confined area could
displace the amount of oxygen in air necessary to support life.

•

Nitrogen is not listed in the LARC, NTP or by OSHA as a carcinogen or potential
carcinogen.

•

Persons in ill health where such illness would be aggravated by exposure to
nitrogen should not be allowed to work with or handle this product.

Recommended First Aid Treatment:
Prompt medical attention is mandatory in all cases of overexposure to nitrogen. Rescue
personnel should be equipped with self-contained breathing apparatus.

Inhalation: Conscious persons should be assisted to an uncontaminated area and inhale
fresh air. Quick removal from the contaminated area is most important. Unconscious
persons should be moved to an uncontaminated area, given assisted respiration and
supplemental oxygen. Further treatment should be symptomatic and supportive.

Hazardous Mixtures of other Liquids, Solids or Gases:
None.
PHYSICAL DATA
Boiling Point: -320.5°F (-195.8°C)

Liquid Density at Boiling Point:
4.43 lb/ft3 (70.96 kg/m3)

Vapor Pressure @ 70°F (21.1°C) = Above the
critical temperature of -232.6°F (-147°C)

Gas Density at 70°F. 1 atm .0725
lb/ft3 (1.161 kq/m3)

Solubility in Water: Very slightly

Freezing Point: -345.9°F (-209.9°C)

Evaporation Rate: N/A (Gas)

Specific Gravity (AIR=1) @ 70°F
(21.1°C) = 0.97

Appearance and Odor: Colorless, odorless gas

FIRE AND EXPLOSION HAZARD DATA
Flash Point (Method used):
N/A Gas

Auto Ignition Temperature:
N/A

Extinguishing Media: Carbon dioxide, dry chemical

Flammable Limits %
by Volume: LEL N/A
UEL N/A
Electrical
Classification:
Nonhazardous

Special Fire fighting Procedures: Nonflammable inert gas
Unusual Fire and Explosion Hazards: If cylinders are involved in a fire, safely relocate or
keep cool with water spray.

REACTIVITY DATA
Stability: Stable
Incompatibility (Materials to Avoid): None
Hazardous Decomposition Products: None
Hazardous Polymerization: Will not occur
Conditions to Avoid: None

SPILL OR LEAK PROCEDURES
Steps to be taken in case material is released or spilled:
Evacuate all personnel from affected area. Use appropriate protective equipment. If leak
is in container or container valve, contact your closest supplier location or call the
emergency telephone number listed herein.
Waste disposal methods:
Do not attempt to dispose of waste or unused quantities. Return in the shipping
container properly labeled, with any valve outlet plugs or caps secured and valve
protection cap in place to your supplier. For emergency disposal assistance, contact
your closest supplier location or call the emergency telephone number listed herein.

SPECIAL PROTECTION INFORMATION
Respiratory Protection (Specify type): Positive pressure air line with mask or selfcontained breathing apparatus should be available for emergency use.
Ventilation: See Local Exhaust
Protective Gloves: Any material
Eye Protection: Safety goggles or glasses
Other Protective Equipment: Safety shoes

SPECIAL PRECAUTIONS
Special Labeling Information:
DOT Shipping Name: Nitrogen, Compressed
DOT Hazard Class: Division 2.2
DOT Shipping Label: Nonflammable Gas
I.D. No.: UN 1066
Special Handling Recommendation:
Use only in well-ventilated areas. Valve protection caps must remain in place unless
cylinder is secured with valve outlet piped to use point. Do not drag, slide or roll
cylinders. Use a suitable hand truck for cylinder movement. Use a pressure reducing
regulator when connecting cylinder to lower pressure (<3,000 psig) piping or systems.
Do not heat cylinder by any means to increase the discharge rate of product from
cylinder. Use a check valve or trap in the discharge line to prevent hazardous back flow
into the cylinder. For additional handling recommendations, consult Compressed Gas
Association’s Pamphlets P-1, P-9, P-14, and Safety Bulletin SB-2.

Special Storage Recommendations:
Protect cylinders from physical damage. Store in cool, dry, well-ventilated area away
from heavily trafficked areas and emergency exits. Do not allow the temperature where
cylinders are stored to exceed 125F (52C). Cylinders should be stored upright and firmly
secured to prevent falling or being knocked over. Full and empty cylinders should be
segregated. Use a “first in -first out” inventory system to prevent full cylinders being
stored for excessive periods of time. For additional storage recommendations, consult
Compressed Gas Association’s Pamphlets P-1, P-9, P-14, and Safety Bulletin SB-2.
Other Recommendations or Precautions:
Compressed gas cylinders should not be refilled except by qualified producers of
compressed gases. Shipment of a compressed gas cylinder which has not been filled by
the owner or with his (written) consent is a violation of Federal Law (49CFR).
Special Packaging Recommendations:
Nitrogen is non-corrosive and may be used with any common structural materials.

www.isocinfo.com

MATERIAL SAFETY DATA SHEET
S O S PRODUCTS COMPANY INC
PO BOX 47
East Greenville, Pa.
18041
Phone (215)-679-6262
(215)-679-6263
PAGE 1
----------------------------------------------------------------------------SECTION I - GENERAL INFORMATION
----------------------------------------------------------------------------Product Code:
HS
Revision Date: 08/06/07
Identification:
HOT STOP LIQUID
----------------------------------------------------------------------------SECTION II - HAZARDOUS INGREDIENTS
----------------------------------------------------------------------------This product is not classified as hazardous in accordance with OSHA 1910.1200
----------------------------------------------------------------------------Carcinogenicity:
This product is NOT considered to be a carcinogen by the
National Toxicology Program, the International Agency for
Research on Cancer, or the Occupational Safety and Health
Administration.
----------------------------------------------------------------------------SECTION III - PHYSICAL CHARACTERISTICS
----------------------------------------------------------------------------Boiling Point:
230
Specific Gravity:
1.00
Vapor Pressure:
17.00
Melting Point:
NOT APPLICABLE
Vapor Density:
.06
Evaporation Rate:
GT 1
Solubility in Water:
SOLUBLE
Odor and Appearance:
----------------------------------------------------------------------------SECTION IV - FIRE AND EXPLOSION HAZARD DATA
----------------------------------------------------------------------------Flash Point:
NOT APPLICABLE
LEL:
N/A
Flammable Limits:
NONE
VEL:
N/A
Extinguishing Media:
NOT APPLICABLE
Special Fire Fighting Procedures: WATER FOG, DRY CHEMICAL. NONE.
Unusual Fire and Explosion Hazards:
NOT APPLICABLE
----------------------------------------------------------------------------SECTION V - REACTIVITY DATA
----------------------------------------------------------------------------This product is STABLE.
Conditions to avoid:
NONE
Incompatibility:
COMPATIBLE
Hazardous Decomposition:
NONE
Hazardous Polymerization:
WILL NOT OCCUR
----------------------------------------------------------------------------SECTION VI - HEALTH HAZARD DATA
----------------------------------------------------------------------------Routes of Entry:
Inhalation?
NO
Skin?
YES - PRIMARY
Ingestion?
YES - SECONDARY
Health Hazards (Acute and Chronic): NONE KNOWN
Carcinogenicity:

NTP?
NO
IARC Monographs?
NO
OSHA Regulated?
NO
Signs and Symptoms of Exposure:
NONE

Medical Conditions Generally Aggravated by Exposure:
NONE KNOWN
Emergency and First Aid Procedures:
EYE: FLUSH 15 MINUTES AND CALL PHYCIAN. SKIN WASH WITH SOAP
AND WATER.
INGESTION: DO NOT INDUCE VOMITING CALL PHYSICAN
----------------------------------------------------------------------------SECTION VII - HANDLING PRECAUTIONS
----------------------------------------------------------------------------Steps to be Taken if Material is Released or Spilled:
FLUSH WITH WATER INTO DRAIN; SOAK UP REMAINDER WITH
OBSORBENT FLOOR
COMPOUND & SWEEP UP.
Waste Disposal Method:
NON-HAZARDOUS LANDFILL.

COMPLY WITH LOCAL ORDINANCES

Precautions to be Taken in Handling and Storage: NONE
Other Precautions: NONE
----------------------------------------------------------------------------SECTION VIII - CONTROL MEASURES
----------------------------------------------------------------------------Respiratory Protection:
NONE REQUIRED
Ventilation Required:
LOCAL EXHAUST ADEQUATE
Protective Gloves:
NOT REQUIRED
Eye Protection:
SAFETY GOGGLES
Other Protective Equipment:
NONE REQUIRED FOR NORMAL USE
Work/Hygienic Practices:
WASH AFTER USING
----------------------------------------------------------------------------The above information pertains to the product as it is currently formulated
and is based upon the information available at this time. Additions of
reducers or other additives to this product may substantially alter the
composition and subsequent hazards of the product. Since conditions of use
are outside of our control, we make no warranties, either expressed or
implied, and assume no liability in connection with any use of this
information.

Kidde de México

Av. División del Golfo 3308
87019 Cd. Victoria, Tamaulipas, México
e-mail: kidde.mexico@kidde.com.mx

MATERIAL SAFETY DATA SHEET
ABC 90 DRY CHEMICAL POWDER – POLVO QUÍMICO SECO ABC 90

SECTION 1 – CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Trade Name / Label Name:

ABC 90% Made to Badger Formulation

CAS Number:

N/A

Chemical Name / Family

N/A
It is a mixture
ABC 90 fire extinguishing powder
Multipurpose Fire extinguishing agent
KIDDE DE MEXICO, S. A. de C. V.

Synonyms:
Manufacturer's Name:

Business phone / Fax:

Av. División del Golfo 3308 Nte.
87019 Cd. Victoria, Tamaulipas, MÉXICO
+52 (834) 318-75-00 / +52 (834) 318-75-29

Date of preparation:

October 13, 2005

Address:

SECTION 2 – COMPOSITION AND INFORMATION ON INGREDIENTS
CAS N°

% w/w

OSHA PEL
mg/m3

ACGIH TLV
mg/m3

TOXICITY
DATA

Monoammonium phosphate

7722-76-1

92 - 94

NONE

NONE

NONE

Mica

12001-26-2

1–3

3

3

NONE

Attapulgus clay

8031-18-3

2-4

NONE

NONE

NONE

Amorphous silica

7631-86-9

0.2 – 1.5

6

10

NONE

Methyl Hydrogen Polysiloxane

63148-57-2

0.4 – 1.0

NONE

NONE

NONE

CHEMICAL NAME

SECTION 3 – PHYSICAL AND CHEMICAL CHARACTERISTICS
Boiling point, °C:
Vapor pressure, mm
Hg:
Vapor density
(Air=1):
Reactivity in water:

Document: GT05310

N/A
N/A
N/A
Unreactive

Specific gravity
(H20=1)
Percent volatile by
volume:
Evaporation rate
(Butyl acetate=1)
Appearance and
odor:

ABOUT 1.9

Viscosity @ 20°C:

N/A

N/A

Melting point, °C:

NDA

N/A

Solubility in water:

22.7 g/100g

Odorless, pale yellow coloured fine powder

Issuing date: 13/10/05

Document: GT05310

Page 2 of 3

SECTION 4 – FIRE AND EXPLOSION HAZARD DATA
Flash point:

Flammable limits in
air, % by volume

N/A

N/A

Auto-ignition
temperature:

Extinguishing media:

N/A – The product is a fire extinguishing agent

Unusual fire and explosion
hazards:

NONE

Special fire fighting procedures:

N/A

The material is a fire extinguishing agent and will not burn. However, if other
materials are involved, use standard chemical fire fighting procedures and
consider the hazards of those materials. In enclosed areas, fire fighters must
wear self-contained breathing apparatus and full protective equipment.

SECTION 5 – REACTIVITY DATA
Stability:

Stable

Incompatibility (materials to
avoid):
Hazardous decomposition
products:

Conditions to avoid:

Extreme
heat

Hazardous
polymerization:

Will not
occur

Strong alkalis. Do not mix with BC type dry chemical extinguishing agents.
Ammonia, phosphorus oxides.

SECTION 6 – HEALTH HAZARD DATA
Threshold limit value:
Routes of entry:
Signs and symptoms of
overexposure:
Medical conditions generally
aggravated by exposure:
Chemical listed as carcinogen or
potential:

Emergency and first aid
procedures:

ACGIH TLV for particulates not otherwise classified: 10 mg/m3
OSHA PEL for nuisance dust limit total: 15 mg/m3
Inhalation: YES; may be irritant to the respiratory tract.
Eye contact: YES; mildly irritant for a short period.
Skin contact: YES; may be mildly irritating.
Ingestion: NOT an expected route of entry.
Acute: Transient cough, shortness of breath, irritation of airways.
Chronic: This product is not known to cause chronic illness.
Asthma, emphysema, bronchitis or other respiratory illness.
NTP program: No

IARC monographs: No

OSHA: No

Eye contact: Flush with large amounts of water for at least 15 minutes. If
irritation persists, seek medical attention.
Skin contact: Wash with soap and water. If irritation persists, seek medical
attention.
Inhalation: Move victim to fresh air. Seek medical attention if discomfort
continues.
Ingestion: Rinse mouth, drink large amounts of water and induce vomiting.
Seek medical help.

SECTION 7 – SPECIAL PRECAUTIONS AND SPILL / LEAK PROCEDURES
Precautions to be taken in
handling and storage:

Should be stored in original containers. Store in dry, cool, well-ventilated
place away from alkaline compounds. Wash after handling. Do not cut, grind,
weld or drill on or near product containers. Treat empty containers as if they
were full.

Other precautions:

Do not mix with alkaline materials.

Steps to be taken in case
materials is released or spilled:
Waste disposal method:

Direction of Operations

Sweep up or vacuum. Store in covered containers. Do not reuse. In case of
large spills, use rubber gloves, chemically resistant suit and boots, hard hat
and air purifying respirator.
Dispose of in compliance with local, state and federal regulations.
Components are non hazardous, sanitary landfill disposal may be acceptable
Issuing date: 13/10/05

Document: GT05310

Page 3 of 3

SECTION 8 – SPECIAL PROTECTION INFORMATION
Respiratory protection:

Dust mask where dustiness is prevalent or TLV exceeded. Mechanical filter
respirator if exposure is prolonged.

Ventilation:

Use adequate ventilation. Use fan or vent to outside.

Protective gloves:

Wear rubber gloves for routine industrial use.

Eye protection:

Recommended as mechanical barrier for prolonged exposure. Safety glasses
or chemical type goggles.

Other protective equipment:

If irritation occurs, long sleeves and impervious gloves should be worn.

Work / Hygienic practices:

Use good personal hygiene and good housekeeping practices. Avoid breathing
of dust. Wash with soap and water.

SECTION 9 – REGULATORY INFORMATION
U.S. OSHA HAZARD
COMMUNICATION STANDARD

RCRA INFORMATION

SARA Reporting Requirements

TSCA Inventory status

Product assessed in accordance with OSHA 20 CFR 1910.1200 and
determined not to be hazardous.
The unused product, in our opinion, is not specifically listed by the EPA as
hazardous waste (40 CFR, Part 261D), nor is it formulated to contain
materials which are listed hazardous wastes. It does not exhibit the hazardous
characteristics of ignitability, corrosivity or reactivity, and is not formulated
with contaminants as determined by the toxicity characteristics leaching
procedure (TCLP). However, used product may be regulated.
No component of this product is subject to the reporting requirements of
Sections 302, 304 and 313 of Title III of the Superfund Amendments and
Reauthorization Act.
Kidde de México certifies that the product described herein complies with all
applicable rules or orders under TSCA and no chemical substance for entry in
violation under TSCA or any applicable rule or order thereunder TSCA is being
offered.

HAZARDOUS MATERIAL IDENTIFICATION SYSTEM RATINGS
HEALTH:
1
HAZARD INDEX:
0 Minimal hazard
1 Slight hazard
2 Moderate hazard
3 Serious hazard
4 Sever hazard

FLAMMABILITY:

0

REACTIVITY:

0

GENERAL KEYS:
N/A: Not applicable.
NDA: No data available.

The information herein is given in good faith. It is based on available data and is believed to be true
and accurate, but no warranty, expressed or implied, is made. Therefore, KIDDE DE MEXICO.
assumes NO responsibility for damage or injury from the use of the product described herein.

Direction of Operations

Issuing date: 13/10/05

Kidde de México

Av. División del Golfo 3308
87019 Cd. Victoria, Tamaulipas, México
e-mail: kidde.mexico@kidde.com.mx

MATERIAL SAFETY DATA SHEET
ABC 90 DRY CHEMICAL POWDER – POLVO QUÍMICO SECO ABC 90

SECTION 1 – CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Trade Name / Label Name:

ABC 90% Made to Badger Formulation

CAS Number:

N/A

Chemical Name / Family

N/A
It is a mixture
ABC 90 fire extinguishing powder
Multipurpose Fire extinguishing agent
KIDDE DE MEXICO, S. A. de C. V.

Synonyms:
Manufacturer's Name:

Business phone / Fax:

Av. División del Golfo 3308 Nte.
87019 Cd. Victoria, Tamaulipas, MÉXICO
+52 (834) 318-75-00 / +52 (834) 318-75-29

Date of preparation:

October 13, 2005

Address:

SECTION 2 – COMPOSITION AND INFORMATION ON INGREDIENTS
CAS N°

% w/w

OSHA PEL
mg/m3

ACGIH TLV
mg/m3

TOXICITY
DATA

Monoammonium phosphate

7722-76-1

92 - 94

NONE

NONE

NONE

Mica

12001-26-2

1–3

3

3

NONE

Attapulgus clay

8031-18-3

2-4

NONE

NONE

NONE

Amorphous silica

7631-86-9

0.2 – 1.5

6

10

NONE

Methyl Hydrogen Polysiloxane

63148-57-2

0.4 – 1.0

NONE

NONE

NONE

CHEMICAL NAME

SECTION 3 – PHYSICAL AND CHEMICAL CHARACTERISTICS
Boiling point, °C:
Vapor pressure, mm
Hg:
Vapor density
(Air=1):
Reactivity in water:

Document: GT05310

N/A
N/A
N/A
Unreactive

Specific gravity
(H20=1)
Percent volatile by
volume:
Evaporation rate
(Butyl acetate=1)
Appearance and
odor:

ABOUT 1.9

Viscosity @ 20°C:

N/A

N/A

Melting point, °C:

NDA

N/A

Solubility in water:

22.7 g/100g

Odorless, pale yellow coloured fine powder

Issuing date: 13/10/05

Document: GT05310

Page 2 of 3

SECTION 4 – FIRE AND EXPLOSION HAZARD DATA
Flash point:

Flammable limits in
air, % by volume

N/A

N/A

Auto-ignition
temperature:

Extinguishing media:

N/A – The product is a fire extinguishing agent

Unusual fire and explosion
hazards:

NONE

Special fire fighting procedures:

N/A

The material is a fire extinguishing agent and will not burn. However, if other
materials are involved, use standard chemical fire fighting procedures and
consider the hazards of those materials. In enclosed areas, fire fighters must
wear self-contained breathing apparatus and full protective equipment.

SECTION 5 – REACTIVITY DATA
Stability:

Stable

Incompatibility (materials to
avoid):
Hazardous decomposition
products:

Conditions to avoid:

Extreme
heat

Hazardous
polymerization:

Will not
occur

Strong alkalis. Do not mix with BC type dry chemical extinguishing agents.
Ammonia, phosphorus oxides.

SECTION 6 – HEALTH HAZARD DATA
Threshold limit value:
Routes of entry:
Signs and symptoms of
overexposure:
Medical conditions generally
aggravated by exposure:
Chemical listed as carcinogen or
potential:

Emergency and first aid
procedures:

ACGIH TLV for particulates not otherwise classified: 10 mg/m3
OSHA PEL for nuisance dust limit total: 15 mg/m3
Inhalation: YES; may be irritant to the respiratory tract.
Eye contact: YES; mildly irritant for a short period.
Skin contact: YES; may be mildly irritating.
Ingestion: NOT an expected route of entry.
Acute: Transient cough, shortness of breath, irritation of airways.
Chronic: This product is not known to cause chronic illness.
Asthma, emphysema, bronchitis or other respiratory illness.
NTP program: No

IARC monographs: No

OSHA: No

Eye contact: Flush with large amounts of water for at least 15 minutes. If
irritation persists, seek medical attention.
Skin contact: Wash with soap and water. If irritation persists, seek medical
attention.
Inhalation: Move victim to fresh air. Seek medical attention if discomfort
continues.
Ingestion: Rinse mouth, drink large amounts of water and induce vomiting.
Seek medical help.

SECTION 7 – SPECIAL PRECAUTIONS AND SPILL / LEAK PROCEDURES
Precautions to be taken in
handling and storage:

Should be stored in original containers. Store in dry, cool, well-ventilated
place away from alkaline compounds. Wash after handling. Do not cut, grind,
weld or drill on or near product containers. Treat empty containers as if they
were full.

Other precautions:

Do not mix with alkaline materials.

Steps to be taken in case
materials is released or spilled:
Waste disposal method:

Direction of Operations

Sweep up or vacuum. Store in covered containers. Do not reuse. In case of
large spills, use rubber gloves, chemically resistant suit and boots, hard hat
and air purifying respirator.
Dispose of in compliance with local, state and federal regulations.
Components are non hazardous, sanitary landfill disposal may be acceptable
Issuing date: 13/10/05

Document: GT05310

Page 3 of 3

SECTION 8 – SPECIAL PROTECTION INFORMATION
Respiratory protection:

Dust mask where dustiness is prevalent or TLV exceeded. Mechanical filter
respirator if exposure is prolonged.

Ventilation:

Use adequate ventilation. Use fan or vent to outside.

Protective gloves:

Wear rubber gloves for routine industrial use.

Eye protection:

Recommended as mechanical barrier for prolonged exposure. Safety glasses
or chemical type goggles.

Other protective equipment:

If irritation occurs, long sleeves and impervious gloves should be worn.

Work / Hygienic practices:

Use good personal hygiene and good housekeeping practices. Avoid breathing
of dust. Wash with soap and water.

SECTION 9 – REGULATORY INFORMATION
U.S. OSHA HAZARD
COMMUNICATION STANDARD

RCRA INFORMATION

SARA Reporting Requirements

TSCA Inventory status

Product assessed in accordance with OSHA 20 CFR 1910.1200 and
determined not to be hazardous.
The unused product, in our opinion, is not specifically listed by the EPA as
hazardous waste (40 CFR, Part 261D), nor is it formulated to contain
materials which are listed hazardous wastes. It does not exhibit the hazardous
characteristics of ignitability, corrosivity or reactivity, and is not formulated
with contaminants as determined by the toxicity characteristics leaching
procedure (TCLP). However, used product may be regulated.
No component of this product is subject to the reporting requirements of
Sections 302, 304 and 313 of Title III of the Superfund Amendments and
Reauthorization Act.
Kidde de México certifies that the product described herein complies with all
applicable rules or orders under TSCA and no chemical substance for entry in
violation under TSCA or any applicable rule or order thereunder TSCA is being
offered.

HAZARDOUS MATERIAL IDENTIFICATION SYSTEM RATINGS
HEALTH:
1
HAZARD INDEX:
0 Minimal hazard
1 Slight hazard
2 Moderate hazard
3 Serious hazard
4 Sever hazard

FLAMMABILITY:

0

REACTIVITY:

0

GENERAL KEYS:
N/A: Not applicable.
NDA: No data available.

The information herein is given in good faith. It is based on available data and is believed to be true
and accurate, but no warranty, expressed or implied, is made. Therefore, KIDDE DE MEXICO.
assumes NO responsibility for damage or injury from the use of the product described herein.

Direction of Operations

Issuing date: 13/10/05

MATERIAL SAFETY DATA SHEET

Section 1. Chemical product and company identification
Product Name:
Synonym:
Manufacturer:
Internet Address:
Address:

Super D Dry Powder Extinguishant
Class D Powder
AMEREX CORPORATION
www.amerex-fire.com
7595 Gadsden Highway
P.O. Box 81
Trussville, AL 35173-0081
(205) 655-3271
Chemtrec 1(800) 424-9300 or
(703) 527–3887
December, 2003

Telephone:
Emergency Contacts:
Revised:

Section 2. Hazard identification and emergency overview
Emergency overview: Off-white, fine solid powder, odorless.
Adverse health effects and symptoms: Moderate irritant to the respiratory system and
eyes; mild irritant to the skin. Symptoms may include stinging of eyes and abraded
skin, coughing, shortness of breath, and irritation of the lungs, eyes, and skin.
Exposure guidelines:
Ingredients
Sodium chloride
Mica
Attapulgite clay
Mineralite (Zeolite)
Magnesium stearate

OSHA PEL

ACGIH TLV

DFG MAK *

PNOC**
Total dust, 15 mg/m3
Respirable fraction, 5 mg/m3

PNOC
Total dust, 10 mg/m3
Respirable fraction, 3 mg/m3

20 mppcf***
PNOC
Total dust, 15 mg/m3
Respirable fraction, 5 mg/m3

3 mg/m3 respirable fraction
PNOC
Total dust, 10 mg/m3
Respirable fraction, 3 mg/m3

PNOC
Total dust, 4 mg/m3
Respirable fraction,
1.5 mg/m3
------PNOC
Total dust, 4 mg/m3
Respirable fraction,
1.5 mg/m3
4 mg/m3

80 mg/m3
10 mg/m3
% SiO2
PNOC
PNOC
Total dust, 15 mg/m3
Total dust, 10 mg/m3
3
Respirable fraction, 5 mg/m Respirable fraction, 3 mg/m3
Page 1 of 7 Pages
SUPER – D

PNOC
Total dust, 4 mg/m3
Respirable fraction,

1.5 mg/m3
Silica, amorphous (fumed)

PNOC
Total dust, 15 mg/m3
Respirable fraction, 5 mg/m3

2 mg/m3

0.3 mg/m3

*German regulatory limits **PNOC = Particulates not otherwise classified (ACGIH) also known as Particulates not
otherwise regulated (OSHA) *** mppcf = million particles per cubic foot. All values are 8 hour time weighted average
concentrations.

Hazard symbols: WHMIS (Canadian workplace hazardous materials identification
system)
D2B

may irritate eyes, mucous membranes, or skin

Section 3. Composition/information on ingredients
Name/Compound

Weight %

CAS #

Sodium chloride
evaporated flour grade

87

7647-14-5

Attapulgite clay or Fullers earth
magnesium aluminum silicatecontains > 1% crystalline silica

4.2

12174-11-7

Mica
potassium aluminum silicate

4.2

12001-26-2

Zeolite, synthetic
amorphous precipitated silica

2.1

112926-00-8

Silica, amorphous, fumed

<2

69012-64-2

Magnesium stearate
octadecanoic acid, Mg salt

<1

557-04-0

14808-60-7

Section 4. First Aid Measures
Eye Exposure: Irrigate eyes at eye wash station and repeat until pain free. Seek
medical attention if irritation develops or persists, or if visual changes occur.
Skin Exposure: In case of contact, wash with plenty of soap and water. Seek medical
attention if irritation develops or persists.

Page 2 of 7 Pages
SUPER – D

Inhalation: If respiratory irritation or distress occurs remove victim to fresh air. Seek
medical attention if irritation develops or persists.
Ingestion: Not known to present an ingestion hazard.
Medical conditions possibly aggravated by exposure: Inhalation of product may
aggravate existing chronic respiratory problems such as asthma, emphysema, or
bronchitis. Skin contact may aggravate existing skin disease. Chronic overexposure
may cause pneumoconiosis (“dusty lung” disease).

Section 5. Fire fighting measures
Extinguishing media: non combustible and non flammable – product is an
extinguishing agent
Unusual fire/explosion hazards: none known
Insensitive to mechanical impact or static discharge.
HMIS Hazard Ranking:
health = 1, flammability = 0, reactivity = 0, personal protective equipment: use N-95
dust mask (see Section 8)
Section 6. Accidental release measures
Clean up released material using vacuum or wet sweep and shovel to minimize
generation of dust. Wear appropriate respiratory protection. Bag and drum for
disposal. If product is used and/or contaminated, use PPE and containment
appropriate to the nature of the mixture.

Section 7. Handling and storage
Avoid skin, eye, or respiratory exposure. Use appropriate PPE when handling or
maintaining equipment, and wash thoroughly after handling (see Section 8). Keep
product in original container or extinguisher. Contents may be under pressure –
inspect for extinguisher rust periodically to insure container integrity. Do not mix with
other extinguishing agents.
Page 3 of 7 Pages
SUPER – D

Section 8. Exposure controls/ personal protection
During the application of this product against fires, exhaust gases and the products of
incomplete combustion (PICs) are the principal respiratory hazards. In the
manufacture of extinguishers, automated systems and point source ventilation controls
sufficiently minimize respiratory exposure. Employers and employees must use their
collective judgment in determining occupational settings where the use of a dust mask
or air purifying respirator is prudent. The need for respiratory protection is not likely for
short-term use in well ventilated areas.
Respiratory protection: use N95 dust mask for limited exposure, use air-purifying
respirator (APR) with high efficiency particulate air (HEPA) filters for prolonged
exposure.
Eye protection: wear chemical goggles
Skin protection: use nitrile, latex, or similar gloves and coveralls. Good personal
hygiene practices essential, such as avoiding food, tobacco products, or other hand-tomouth contact when handling. Wash thoroughly after handling.

Section 9. Physical and chemical properties
Appearance: off-white powder, finely divided odorless solid.
Specific gravity: ~ 1.0
Solubility: product is coated, not immediately soluble in water
Non –flammable
Flash point: none
Vapor pressure: < 1 mm Hg
pH: approximately 7 for a 10% solution
Boiling point: not applicable
No explosive or oxidizing properties

Section 10. Stability and reactivity
Stability: stable
Incompatibles: strong acids and strong oxidizers like bleach.
Page 4 of 7 Pages
SUPER – D

Decomposition products: heat of fire may release chlorine compounds and oxides of
sodium.
Possibility of hazardous reactions: none

Section 11. Toxicological information
Acute toxicity:

Sodium chloride LD50 (rat): oral, 3000 mg/kg body weight,
LD50 (mouse): oral, 4000 mg/kg body weight, LDLo (lowest lethal
dose) (rat): subcutaneous, 3500 mg/kg body weight, LDLo (dog):
intraperitoneal, 364 mg/kg body weight.
Target organs in man: None. While an essential nutrient, sodium
chloride is a mild irritant to epithelial tissue, (eyes, mucous
membranes, skin) and may aggravate dermatitis. No information was
found indicating the product causes sensitization.

Chronic toxicity: This product’s ingredients are not considered as “probable” or
“suspected” carcinogens by OSHA, IARC, or ACGIH.
Pneumoconiosis, or “dusty lung” disease, may result from chronic
exposure to any dust.
Reproductive
toxicity:

This product’s ingredients are not known to have reproductive or
teratogenic effects.

Section 12. Ecological information
Ecotoxicity:

negative effects unknown.

Persistence/
Degradability:

degrades slowly in humid/wet environment

Bioaccummulation: extent unknown
Mobility in soil:

insoluble coating, poor mobility

Page 5 of 7 Pages
SUPER – D

Section 13. Disposal considerations
This product is not a RCRA characteristically hazardous or listed hazardous waste.
Dispose of according to state or local laws, which may be more restrictive than federal
laws or regulations. Used product may be altered or contaminated, creating different
disposal considerations.

Section 14. Transportation information
This product is not defined as a hazardous material under U.S. Department of
Transportation (DOT) 49 CFR 172, or by Transport Canada “Transportation of
Dangerous Goods” regulations.

Section 15. Regulatory information
International Inventory Status:
All ingredients are on the following inventories
Country(ies)
United States of America
Canada
Europe
Australia
Japan
South Korea

Agency
TSCA
DSL
EINECS/ELINCS
AICS
MITI
KECL

Status
Yes
Yes
Yes
Yes
Yes
Yes

European Risk and Safety phrases:
EU Classification:
R Phrases:
S Phrases:

Irritant
20
36/37
22
24/25
26

Harmful by inhalation.
Irritating to eyes, respiratory system.
Do not breathe dust.
Avoid contact with skin and eyes
In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice.

Page 6 of 7 Pages
SUPER – D

U.S. federal regulatory information:
None of the chemicals in this product are under SARA reporting requirements or have
SARA threshold planning quantities (TPQs) or CERCLA reportable quantities (RQs), or
are regulated under TSCA 8(d).
State regulatory information:
Chemicals in this product are covered under specific State regulations, as denoted
below:
Alaska - Designated Toxic and Hazardous Substances: None
California – Permissible Exposure Limits for Chemical Contaminants: None
Florida – Substance List: Mica Dust
Illinois – Toxic Substance List: None
Kansas – Section 302/303 List: None
Massachusetts – Substance List: Mica Dust
Minnesota – List of Hazardous Substances: None
Missouri – Employer Information/Toxic Substance List: None
New Jersey – Right to Know Hazardous Substance List: None
North Dakota – List of Hazardous Chemicals, Reportable Quantities: None
Pennsylvania – Hazardous Substance List: None
Rhode Island – Hazardous Substance List: Mica Dust
Texas – Hazardous Substance List: No
West Virginia – Hazardous Substance List: None
Wisconsin – Toxic and Hazardous Substances: None

California Proposition 65: No component is listed on the California Proposition 65 list.
_____________________________________________________________________
Section 16. Other information
This MSDS conforms to requirements under U.S., U.K., Canadian, Australian, and EU
regulations or standards, and conforms to the proposed 2003 ANSI Z400.1 format.
The information herein is given in good faith but no warranty, expressed or implied, is
made. Updated by Lindsay R. Hill, CIH

Page 7 of 7 Pages
SUPER – D

MATERIAL SAFETY DATA SHEET
Kidde 55 Multi-Purpose Dry Chemical
(Fire Extinguishing Agent)

1.

PRODUCT AND COMPANY IDENTIFICATION
Product Name
Other Trade Names
Manufacturer/Supplier
Address

Phone Number
Chemtrec Number
(for emergencies only)
Revision Date:
MSDS Date:

Kidde 55 Multi –Purpose Dry Chemical (Fire Extinguishing Agent)
ABC, Ammonium Phosphate, Monoammonium Phosphate
Kidde – Residential and Commercial
A United Technologies Company
1016 Corporate Park Drive
Mebane, NC 27302
USA
(919) 304-8200
(919) 563-5911
(800) 424-9300
(703) 527-3887 (International)
August 7, 2007
January 15, 2007

This MSDS has been compiled in accordance with - EC Directive 91/155/EC - OSHA's Hazcom Standard (29 CFR 1910.1200)

2.

3.

COMPOSITION/INFORMATION ON THE COMPONENTS
Component Name
Monoammonium Phosphate

CAS#/Codes Concentration R Phrases
7722-76-1
55 - 65%
None
EC#2317645

EU Classification
None

Ammonium Sulfate

7783-20-2
30 - 40%
EC#2319841

None

None

Mica
Clay

12001-26-2
8031-18-3

None
None

None
None

Amorphous Silica

7631-86-9
<2%
EC#2315454

None

None

Dye

NA

None

None

1 - 4%
<2%

<0.1%

HAZARD IDENTIFICATION
EU Main Hazards
Non Hazardous Powder
Routes of Entry
- Eye contact - Inhalation - Skin contact
Carcinogenic Status
See Section 11 - Toxicity
Target Organs
- Respiratory System - Skin - Eye
Health Effects - Eyes
Contact for short periods of time may cause irritation.
Health Effects - Skin
Contact may cause mild irritation.

Revision Date: August 7, 2007

Page 1 of 6

MATERIAL SAFETY DATA SHEET
Kidde 55 Multi-Purpose Dry Chemical
(Fire Extinguishing Agent)

3.

HAZARD IDENTIFICATION
Health Effects - Ingestion
Ingestion is not an expected route of exposure.
Health Effects - Inhalation
May irritate the respiratory tract. May cause transient cough and shortness of breath.

4.

FIRST AID MEASURES
Eyes
Immediately flood the eye with plenty of water of warm water for at least 15 minutes, holding the eye
open. Obtain medical attention if soreness or redness persists.
Skin
Wash affected area with soap and water. Obtain medical attention if irritation persists.
Ingestion
Dilute by drinking large quantities of water and obtain medical attention.
Inhalation
Move victim to fresh air. Obtain medical attention immediately for any breathing difficulty.
Advice to Physicians
Treat symptomatically.

5.

FIRE FIGHTING MEASURES
Extinguishing Media
This preparation is used as an extinguishing agent and therefore is not a problem when trying to
control a blaze. Use extinguishing agent appropriate to other materials involved. Keep pressurized
extinguishers and surroundings cool with water spray as they may rupture or burst in the heat of a fire.
Unusual Fire and Explosion Hazards
Pressurized containers may explode in heat of fire.
Protective Equipment for Fire-Fighting
Wear full protective clothing and self-contained breathing apparatus as appropriate for specific fire
conditions.

6.

ACCIDENTAL RELEASE MEASURES
Sweep up or vacuum. Prevent skin and eye contact. Wear appropriate protective equipment.

7.

HANDLING AND STORAGE
Pressurized extinguishers should be properly stored and secured to prevent falling or being knocked
over. Do not drag, slide or roll extinguishers. Do not drop extinguishers or permit them to strike
against each other. Never apply flame or localized heat directly to any part of the extinguisher or
plastic container. Store pressurized extinguishers and plastic containers away from high heat sources.
Storage area should be: - cool - dry - well ventilated - under cover - out of direct sunlight

Revision Date: August 7, 2007

Page 2 of 6

MATERIAL SAFETY DATA SHEET
Kidde 55 Multi-Purpose Dry Chemical
(Fire Extinguishing Agent)

8.

EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Standards
Occupational exposure limits are listed below, if they exist.
Mica
ACGIH TLV: 3 mg/m3 TWA, measured as respirable fraction of the aerosol.
OSHA PEL: 20 mppcf, <1% crystalline silica
Nuisance Dust Limit
OSHA PEL: 50 mppcf or 15 mg/m3 TWA, total dust
15 mppcf or 5 mg/m3 TWA, respirable fraction
Engineering Control Measures
Use with adequate ventilation. There should be local procedures for the selection, training, inspection
and maintenance of this equipment. When used in large volumes, use local exhaust ventilation.
Respiratory Protection
Not normally required. Use dust mask where dustiness is prevalent, or TLV is exceeded.
Hand Protection
Not normally needed when used as a portable fire extinguisher. Use gloves if irritation occurs.
Eye Protection
Chemical goggles or safety glasses with side shields.
Body Protection
Normal work wear.

9.

PHYSICAL AND CHEMICAL PROPERTIES
Physical State
Color
Odor
Specific Gravity
Boiling Range/Point (°C/F)
Flash Point (PMCC) (°C/F)
Solubility in Water
Vapor Density (Air = 1)
Vapor Pressure
Evaporation Rate

10.

Powder
Pale Yellow
Odorless
Not available
Not applicable
Not Flammable
Not applicable
Heavier than air.
Not applicable
Not applicable

STABILITY AND REACTIVITY
Stability
Stable under normal conditions.
Conditions to Avoid
- Heat - High temperatures - Exposure to direct sunlight
Materials to Avoid
- Strong oxidizing agents - strong acids - sodium hypochlorite

Revision Date: August 7, 2007

Page 3 of 6

MATERIAL SAFETY DATA SHEET
Kidde 55 Multi-Purpose Dry Chemical
(Fire Extinguishing Agent)

10.

STABILITY AND REACTIVITY
Hazardous Polymerization
Will not occur.
Hazardous Decomposition Products
- oxides of carbon - ammonia – oxides of phosphorus – nitrogen oxides

11.

TOXICOLOGICAL INFORMATION
Acute Toxicity
Low order of acute toxicity.
Chronic Toxicity/Carcinogenicity
This product is not expected to cause long term adverse health effects.
Mica and clay may contain small quantities of quartz (crystalline silica) as an impurity. Prolonged
exposure to respirable crystalline silica dust at concentrations exceeding the occupational exposure
limits may increase the risk of developing a disabling lung disease known as silicosis. IARC found
limited evidence for pulmonary carcinogenicity of crystalline silica in humans.
Genotoxicity
This product is not expected to cause any mutagenic effects.
Reproductive/Developmental Toxicity
This product is not expected to cause adverse reproductive effects.

12.

ECOLOGICAL INFORMATION
Mobility
No relevant studies identified.
Persistence/Degradability
No relevant studies identified.
Bio-accumulation
No relevant studies identified.
Ecotoxicity
No relevant studies identified.

13.

DISPOSAL
Dispose of container in accordance with all applicable local and national regulations. Do not cut,
puncture or weld on or near to the container. No harm to the environment is expected from this
preparation.

14.

TRANSPORT INFORMATION
DOT CFR 172.101 Data
UN Proper Shipping Name
UN Class
UN Number
UN Packaging Group

Revision Date: August 7, 2007

Not regulated
Not regulated
None
None
None
Page 4 of 6

MATERIAL SAFETY DATA SHEET
Kidde 55 Multi-Purpose Dry Chemical
(Fire Extinguishing Agent)

15.

REGULATORY INFORMATION
EU Label Information
Classification and labelling have been performed according to EU directives 67/548/EEC and 99/45/EC
including amendments.
EU Hazard Symbol and Indication of Danger.
This preparation is not classified as dangerous.
R phrases
None
S phrases
None.
US REGULATIONS (Federal, State) and INTERNATIONAL CHEMICAL REGISTRATION LAWS
TSCA Listing
This product contains ingredients that are listed on or exempt from listing on the EPA Toxic Substance
Control Act Chemical Substance Inventory.
EINECS Listing
All ingredients in this product have not been verified for listing on the European Inventory of Existing
Commercial Chemical Substances (EINECS) or the European List of New Chemical Substances
(ELINCS).
DSL/NDSL (Canadian) Listing
All ingredients in this product are listed on the Domestic Substance List (DSL) or the Non-Domestic
Substance List (NDSL) or are exempt from listing.
WHMIS Classification
D2B
This product was classified in accordance with the hazard criteria of the Canadian Controlled Products
Regulations and the MSDS contains all the information required by these regulations.
MA Right To Know Law
All components have been checked for inclusion on the Massachusetts Substance List (MSL). Those
components present at or above the de minimus concentration include: - Mica (12001-26-2) 1-4% Amorphous Silica (7631-86-9) <2% - Ammonium Sulfate (7783-20-2) 30 - 40%
PA Right To Know Law
This product contains the following chemicals found on the Pennsylvania Hazardous Substance List: Mica (12001-26-2) 1-4% - Amorphous Silica (7631-86-9) <2% - Ammonium Sulfate (7783-20-2)
30 - 40%
NJ Right To Know Law
This product contains the following chemicals found on the NJ Right To Know Hazardous Substance
List: - Mica (12001-26-2) 1-4% - Amorphous Silica (7631-86-9) <2%
California Proposition 65
This product does not contain materials which the State of California has found to cause cancer, birth
defects or other reproductive harm.
SARA Title III Sect. 302 (EHS)
This product does not contain any chemicals subject to SARA Title III Section 302.
SARA Title III Sect. 304
This product does not contain any chemicals subject to SARA Title III Section 304.

Revision Date: August 7, 2007

Page 5 of 6

MATERIAL SAFETY DATA SHEET
Kidde 55 Multi-Purpose Dry Chemical
(Fire Extinguishing Agent)

15.

REGULATORY INFORMATION
SARA Title III Sect. 311/312 Categorization
- Immediate (Acute) Health Hazard
SARA Title III Sect. 313
This product does not contain any chemicals that are listed in Section 313 at or above de minimis
concentrations.

16.

OTHER INFORMATION
NFPA Ratings
NFPA Code for Health - 1
NFPA Code for Flammability - 0
NFPA Code for Reactivity - 0
NFPA Code for Special Hazards - None
HMIS Ratings
HMIS Code for Health - 1
HMIS Code for Flammability - 0
HMIS Code for Reactivity - 0
HMIS Code for Personal Protection - See Section 8
Abbreviations
N/A: Denotes no applicable information found or available
CAS#: Chemical Abstracts Service Number
ACGIH: American Conference of Governmental Industrial Hygienists
OSHA: Occupational Safety and Health Administration
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
STEL: Short Term Exposure Limit
NTP: National Toxicology Program
IARC: International Agency for Research on Cancer
R: Risk
S: Safety
EnviroNet LLC.
Prepared By:
The information contained herein is based on data believed to be accurate. However, no
representation, warranty, or guarantee is made to its accuracy, reliability or completeness. It is the
user's responsibility to satisfy himself as to the suitability and completeness of such information for its
own particular use. Badger Fire Protection assumes no responsibility for personal injury or property
damage resulting from use, handling or from contact with this product.

Revision Date: August 7, 2007

Page 6 of 6

MATERIAL SAFETY DATA SHEET #KFFM010

ABC Multipurpose Dry Chemical
Fire Extinguisher

Section 1 – NAME & HAZARD SUMMARY
Material Name: DRY CHEMICAL Multipurpose Ammonium Phosphate
Supplier Name and Address: Kidde Fire Fighting
150 Gordon Drive · P.O. Box 695
Exton, PA 19341-0695 USA
Phone: (610) 363-1400 · Fax: (610) 524-9073
www.Kidde-Fire.com
Section 2 – INGREDIENTS
Material name: Siliceous Muscovite Mica, Mica
OSHA PEL: 20 MPPCF*
ACGIH TLV: 20 MPPCF*
Other Exposure Limits: None
CAS No.: 12001-26-2
*Million particles per cubic foot
Section 3 – PHYSICAL DATA
Boiling Point: NA
Specific Gravity (H2O = 1): 1.80
Vapor Pressure (mm Hq): NA
Vapor Density (Air -1): NA
Solubility In Water: Slightly water soluble
Appearance and Odor: Yellow powder, odorless
Melting Point: 374° Fahrenheit
Section 4 – FIRE & EXPLOSION HAZARD
Flash Point: Noncombustible
Method Used: NA
Flammable Limits in Air, % by Volume: LEL Lower: NA; UEL Upper: NA
Auto-Ignition Temperature: NA
Extinguisher Media: NA, This material is a fire extinguisher agent
KFFM010

Page 1 of 2

6/1/04

Special Fire Fighting Procedures: NA
Unusual Fire and Explosion Hazards: NA
Section 5 – REACTIVITY DATA
Stability: Stable
Conditions to Avoid: NA
Incompatibility (Materials to Avoid): Do not mix with different types of dry chemical
extinguishing agents
Hazardous Polymerization: Will Not Occur
Conditions to Avoid: NA
Section 6 – HEALTH HAZARD ASSESSMENT
Acute: Transient cough, Irritation of airways, and shortness of breath
Chronic: Pneumonconiosis
Signs and Symptoms of Exposure: Coughing and irritation of airways
Medical Conditions Generally Aggravated by Exposure: Asthma, Bronchitis, or other
respiratory illness
Chemical Listed as Carcinogen or Potential Carcinogen: N/A
Emergency and First Aid Procedures: Move victims to fresh air. Wash affected area with soap
and water. Flush from eyes with large amounts of water for at least 15 minutes. Seek medical
attention if necessary.
Routes of Entry: Inhalation, Eyes, Skin, Ingestion
Section 7 – SPILL OR LEAK PROCEDURES
Precautions to be Taken in Handling and Storage: Multipurpose (ABC) Dry Chemical should
be stored in original container or in sealed extinguishers.
Other Precautions: None
Steps to be Taken in Case Material is Released or Spilled: Sweep up. Store in covered
containers. Do not reuse.
Section 8 – SPECIAL PROTECTION INFORMATION
Respiratory Protection: Dust respirator approved by NIOSH/MSHA schedule TC-ZIC
Ventilation: NA
Local Exhaust: NA
Mechanical General: NA
Special: NA Other: NA
Protective Gloves: Sensitive individuals should wear gloves
Eye Protection: Safety glasses are recommended
Other Protective Clothing or Equipment: NA
Work/Hygienic Practices: Avoid breathing of dust. Wash off with soap and water.
The information herein is given in good faith but no warranty, expressed or implied, is made.

KFFM010

Page 2 of 2

6/1/04

MATERIAL SAFETY DATA SHEET
S O S PRODUCTS COMPANY INC
P. O. Box 47
East Greenville, Pa.
18041
Phone (215-679)-6262
(215)-679-6263

SECTION I
PAGE 1
Product Code:
Identification:

-

GENERAL

WG8 / WGP
WAX GASKET

INFORMATION
Revision Date:

08/06/07

SECTION II - HAZARDOUS INGREDIENTS
This product is not classified as hazardous in accordance with OSHA 1910.1200
Carcinogenicity:
This product is NOT considered to be a carcinogen by the
National Toxicology Program, the International Agency for Research on
Cancer, or the Occupational Safety and Health Administration.
SECTION III - PHYSICAL CHARACTERISTICS
Boiling Point: < 650o F
Specific Gravity: .85
Vapor Pressure: 0.01
Melting Point:
140o-170o F.
Vapor Density: N/A
Evaporation Rate: N/A
Solubility in Water:
NEGLIGIBLE
Odor and Appearance: AMBER WAXY SOLID WITH TYPICAL PETROLEUM WAX ODOR
SECTION IV - FIRE AND EXPLOSION HAZARD
Flash Point: 500o F. COC
LEL: N/A
Flammable Limits: NOT DETERMINED
UEL: N/A
Extinguishing Media:
DRY CHEMICAL, FOAM, FIRE EXTINGUISHER
Special Fire Fighting Procedures:
USE WATER SPRAY, DRY CHEMICAL FOAM, OR CARBON DIOXIDE. WATER OR FOAM
MAY CAUSE FROTHING. WATER MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS
COOL. USE PROTECTIVE CLOTHING WHEN ENTERING CONFINED AREAS WITH WAX
FIRES.
Unusual Fire and Explosion Hazards:
WHEN HEATED ABOVE FLASH POINT, FLAMMABLE VAPORS COULD BE RELEASED
WHICH COULD BURN IN CONFINED AREAS.
SECTION V
This product is STABLE.
Conditions to avoid:
Incompatibility:

-

REACTIVITY DATA

HIGH HEAT, TEMPERATURES OVER 160 DEG F.

STRONG OXIDIZING AGENTS

Hazardous Decomposition:

BY OPEN FLAME:

CARBON DIOXIDE & CARBON MONOXIDE

Hazardous Polymerization WILL NOT OCCUR.

Routes of Entry:

SECTION VI - HEALTH HAZARD DATA
Inhalation? NO
Skin?
YES - SECONDARY
Ingestion?
YES - SECONDARY

Health Hazards (Acute and Chronic):

NONE KNOWN

Carcinogenicity:

NTP?
IARC Monographs?
OSHA Regulated?

Signs and Symptoms of Exposure:

NO
NO
NO

NONE

Medical Conditions Generally Aggravated by Exposure:

NONE KNOWN

Emergency and First Aid Procedures:
SKIN: WASH WITH SOAP & WATER THOROUGHLY.
EYES: FLUSH 15 MINUTES WITH WATER.
INGESTION: MAY CAUSE IRRITATION OF DIGESTIVE TRACT.
QUANTITY, CALL PHYSICIAN.

IF LARGE

SECTION VII - HANDLING PRECAUTIONS
Steps to be Taken if Material is Released or Spilled:
REPLACE INTO CONTAINER AND PACKAGE APPROPRIATELY FOR DISPOSAL. FOR
MOLTEN MATERIAL, ABSORB WITH SAND OR INERT ABSORBENT AND NOTIFY STATE
AND LOCAL AGENCIES.
Waste Disposal Method:

WAX- COMPLY WITH FEDERAL, STATE AND LOCAL REGULATIONS.

Precautions to be Taken in Handling and Storage:
STORE IN A COOL, DRY LOCATION. TO PREVENT MELTING OR DEFORMING DO NOT
STORE OVER 110o F.
Other Precautions:

NONE

SECTION VIII - CONTROL MEASURES
Respiratory Protection: NONE REQUIRED FOR NORMAL USE.
Ventilation Required: ADEQUATE VENTILATION
Protective Gloves: NONE REQUIRED FOR NORMAL USE.
Eye Protection: WEAR SAFETY GLASSES
Other Protective Equipment: NONE
Work/Hygienic Practices: USE GOOD PERSONAL HYGIENE PRACTICES.

The above information pertains to the product as it is currently formulated and
is based upon the information available at this time. Additions of reducers or
other additives to this product may substantially alter the composition and
subsequent hazards of the product. Since conditions of use are outside of our
control, we make no warranties, either expressed or implied, and assume no
liability in connection with any use of this information.

MATERIAL SAFETY DATA SHEET
S O S PRODUCTS COMPANY INC
P. O. Box 47
East Greenville, Pa.
18041
Phone (215-679)-6262
(215)-679-6263

SECTION I
PAGE 1
Product Code:
Identification:

-

GENERAL

WG8 / WGP
WAX GASKET

INFORMATION
Revision Date:

08/06/07

SECTION II - HAZARDOUS INGREDIENTS
This product is not classified as hazardous in accordance with OSHA 1910.1200
Carcinogenicity:
This product is NOT considered to be a carcinogen by the
National Toxicology Program, the International Agency for Research on
Cancer, or the Occupational Safety and Health Administration.
SECTION III - PHYSICAL CHARACTERISTICS
Boiling Point: < 650o F
Specific Gravity: .85
Vapor Pressure: 0.01
Melting Point:
140o-170o F.
Vapor Density: N/A
Evaporation Rate: N/A
Solubility in Water:
NEGLIGIBLE
Odor and Appearance: AMBER WAXY SOLID WITH TYPICAL PETROLEUM WAX ODOR
SECTION IV - FIRE AND EXPLOSION HAZARD
Flash Point: 500o F. COC
LEL: N/A
Flammable Limits: NOT DETERMINED
UEL: N/A
Extinguishing Media:
DRY CHEMICAL, FOAM, FIRE EXTINGUISHER
Special Fire Fighting Procedures:
USE WATER SPRAY, DRY CHEMICAL FOAM, OR CARBON DIOXIDE. WATER OR FOAM
MAY CAUSE FROTHING. WATER MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS
COOL. USE PROTECTIVE CLOTHING WHEN ENTERING CONFINED AREAS WITH WAX
FIRES.
Unusual Fire and Explosion Hazards:
WHEN HEATED ABOVE FLASH POINT, FLAMMABLE VAPORS COULD BE RELEASED
WHICH COULD BURN IN CONFINED AREAS.
SECTION V
This product is STABLE.
Conditions to avoid:
Incompatibility:

-

REACTIVITY DATA

HIGH HEAT, TEMPERATURES OVER 160 DEG F.

STRONG OXIDIZING AGENTS

Hazardous Decomposition:

BY OPEN FLAME:

CARBON DIOXIDE & CARBON MONOXIDE

Hazardous Polymerization WILL NOT OCCUR.

Routes of Entry:

SECTION VI - HEALTH HAZARD DATA
Inhalation? NO
Skin?
YES - SECONDARY
Ingestion?
YES - SECONDARY

Health Hazards (Acute and Chronic):

NONE KNOWN

Carcinogenicity:

NTP?
IARC Monographs?
OSHA Regulated?

Signs and Symptoms of Exposure:

NO
NO
NO

NONE

Medical Conditions Generally Aggravated by Exposure:

NONE KNOWN

Emergency and First Aid Procedures:
SKIN: WASH WITH SOAP & WATER THOROUGHLY.
EYES: FLUSH 15 MINUTES WITH WATER.
INGESTION: MAY CAUSE IRRITATION OF DIGESTIVE TRACT.
QUANTITY, CALL PHYSICIAN.

IF LARGE

SECTION VII - HANDLING PRECAUTIONS
Steps to be Taken if Material is Released or Spilled:
REPLACE INTO CONTAINER AND PACKAGE APPROPRIATELY FOR DISPOSAL. FOR
MOLTEN MATERIAL, ABSORB WITH SAND OR INERT ABSORBENT AND NOTIFY STATE
AND LOCAL AGENCIES.
Waste Disposal Method:

WAX- COMPLY WITH FEDERAL, STATE AND LOCAL REGULATIONS.

Precautions to be Taken in Handling and Storage:
STORE IN A COOL, DRY LOCATION. TO PREVENT MELTING OR DEFORMING DO NOT
STORE OVER 110o F.
Other Precautions:

NONE

SECTION VIII - CONTROL MEASURES
Respiratory Protection: NONE REQUIRED FOR NORMAL USE.
Ventilation Required: ADEQUATE VENTILATION
Protective Gloves: NONE REQUIRED FOR NORMAL USE.
Eye Protection: WEAR SAFETY GLASSES
Other Protective Equipment: NONE
Work/Hygienic Practices: USE GOOD PERSONAL HYGIENE PRACTICES.

The above information pertains to the product as it is currently formulated and
is based upon the information available at this time. Additions of reducers or
other additives to this product may substantially alter the composition and
subsequent hazards of the product. Since conditions of use are outside of our
control, we make no warranties, either expressed or implied, and assume no
liability in connection with any use of this information.

Friday, April 21, 2006

Page 1 of 7

MSDS - Material Safety Data Sheet
Product Name: C-12 CPVC Cement
MSDS No.: 018750

Part Numbers Covered:
018750-24
018752-24
018760-24
018762-24
018770-12
018772-12
018780-12
018782-12
018790

1. Basic Information:
Manufacturer: WILLIAM H. HARVEY COMPANY

4

Address: 4334 SOUTH 67TH STREET
City, ST Zip: OMAHA, NE 68117-1019

2

1

Emergency Contact: CHEMTREC
Emergency Telephone Number: (800)424-9300
Contact: Information Telephone Number
Information Telephone Number: (800)228-9681
Last Update: 04/21/2006
Chemical State:
Chemical Type:

X

2
4

Expiration Date:

Liquid

Gas

Pure

X

1

Solid

G

Mixture

2. Ingredients:
Trade Secret
EHS

IARC
NTP

SARA
313
OSHA
SUB Z
PEL

ACGIH
TLV

Other
Limits

CAS No.

Chemical Name

% Range

68648-82-8

CPVC RESIN

10 - 20

NI

10 MG/M3 NI

108-94-1

CYCLOHEXANONE

5 - 15

25 PPM

25 PPM

NI

112945-52-5 FUMED SILICA

1-5

5 mg/m3

3 mg/m3

NI

78-93-3

METHYL ETHYL KETONE

20 - 30

200 PPM

200 PPM

NI

109-99-9

TETRAHYDROFURAN

40 - 48

200 PPM

50 PPM

NI

3. Hazardous Identification:
Hazard Category:

X Acute

X Chronic

X Fire

Pressure

Reactive

Hazardous Identification Information:

HAZARDS OVERVIEW:
Clear orange colored, moderately viscous liquid with a distinct and penetrating odor. Extremely flammable liquid and vapor.
Vapors may cause flash fire. May cause eye and skin irritation. Inhalation of vaors or mists may cause respiratory irritation and
central nervous system effects. Ingestion may cause irritation, nausea, vomiting, diarrhea and kidney and liver disorders. May
be fatal if swallowed. Aspiration hazard. Symptoms may be delayed.

Friday, April 21, 2006

Page 2 of 7

MSDS - Material Safety Data Sheet
Product Name: C-12 CPVC Cement
MSDS No.: 018750

4. First Aid Measures:
Route(s) of Entry:

EYES: Liquid causes severe irritation. Vapors cause slight to moderate irritation.
SKIN: Liquid or vapors may cause severe irritation.
INHALATION: May cause nose and throat irritation, headache, nausea, vomiting, drowsiness and incoordination.
INGESTION: Swallowing may cause irritation, nausea, vomiting, diarrhea and kidney and liver disorders. May be fatal if
swallowed.
TARGET ORGANS: Eyes, Skin, Lungs, Kidney, Liver, Central Nervous System.
Health Hazards (Acute and Chronic):

ACUTE:
Severe skin irritant. Fast skin penetrant. Not expected to be a sensitizer. Eye irritant. Inhalation hazard. Overexposure may
cause coughing, shortness of breath, dizziness, vomiting, central nervous system depression, intoxication, and collapse.
Ingestion hazard. May produce symptoms of nervous system depression including headache, dizziness, nausea, loss of sense
of balance, drowsiness, and visual disturbances.
CHRONIC:
Prolonged or repeated eye contact may cause conjunctivitis. Prolonged or repeated skin contact may cause defatting and
dermatitis. May cause liver and kidney damage. May cause reproductive and fetal effects May cause lung damage. Narcotic in
high concentrations.
Signs and Symptoms:

See HEALTH HAZARDS above.
Medical Conditions Generally Aggravated by Exposure:

AGGRAVATION OF EXISTING CONDITIONS:
Persons with pre-existing skin disorders or eye problems or impaired liver or kidney function may be more susceptible to the
effects of the substance.
Emergency and First Aid Procedures:

FOR EMERGENCY FIRST AID HELP CALL 1-303-623-5716 COLLECT.
SKIN CONTACT:
Immediately wash skin with soap and water while removing contaminated clothing and shoes. Remove dried cement with
HARVEY'S POWER SCRUB HAND CLEANER or baby oil. Launder clothing before reuse. Seek medical attention if irritation
persists.
EYES:
Liquid: Immediately flush with plenty of water for 5 minutes. Remove contacts if present and continue flushing with water while
holding eyelids open with thumb and index finger for 15 minutes. Seek medical attention if irritation develops or persists.
Vapors: If vapors cause irritation, move to fresh air and flush eyes as above. Seek medical attention if irritation develops or
persists.
INHALATION:
Move to fresh air. Give oxygen if breathing is difficult. Give artificial respiration if required. Call a physician or poison control
center (1-303-623-576 collect) immediately.
INGESTION:
DO NOT INDUCE VOMITING. Rinse mouth with water. Never give anything by mouth to a person who is unconscious or
drowsy. Get immediate medical attention by calling a Poison Control Center (1-303-623-5716 Collect), or hospital emergency
room. If medical advice cannot be obtained, then take the person and product to the nearest medical emergency treatment
center or hospital.
Other Health Warnings:

NI

Friday, April 21, 2006

Page 3 of 7

MSDS - Material Safety Data Sheet
Product Name: C-12 CPVC Cement
MSDS No.: 018750

5. Fire Fighting Measures:
Flash Point: 0 - 6 ºF

Lower Explosive Limit: 1.1 %by vol.

Upper Explosive Limit: 11.8 %by vol

F.P. Method: TCC
Fire Extinguishing Media: Use dry chemical, CO2, or foam to extinguish fire. Cool fire exposed container with water. Water may be ineffective
as an extinguishing agent.

Special Fire Fighting Procedures:

Firefighters should wear positive pressure self contained breathing apparatus and full protective clothing for fires in areas where
chemicals are used or stored.
Unusual Fire and Explosion:

Extremely flammable liquid. Keep away from heat and all sources of ignition including sparks, flames, lighted cigarettes and pilot
lights. containers may rupture or explode in the heat of a fire. Vapors are heavier than air and may travel to a remote ingition
source and flash back. This product contains Tetrahydrofuran that may form explosive organic peroxides when exposed to air or
light or with age. Combustion will produce toxic and irritating vapors including carbon monoxide and carbon dioxide.

6. Accidental Release Measures:
Steps to be Taken in Case Material is Released or Spilled:

Remove all sources of ignition and ventilate area. Stop leak if it can be done without risk. Prevent liquid from entering
watercourses, natural waterways, drainage collection areas or sewers.
Personnel cleaning up the spill should wear appropriate Ppersonal Protective Equipment, including respirators if vapor
concentrations are high. Soak up spill with an inert absorbent such as sand, earth or other non-combusting material. Put spent
absorbent material in covered, labeled metal containers. See Section XIII for disposal information.
Report releases to proper authorities as required.

7. Handling and Storage:
Precautions to be Taken:

HANDLING:
Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists. Use with adequate ventilation (equivalent to
outdoors). Wash thoroughly after handling. do not eat, drink or smoke in the work area. Keep product away from heat, sparks,
flames and all other sources of ignition. No smoking in use or storage areas. Keep containers closed when not in use.
STORAGE:
Store in a cool, dry, well ventilated area away from incompatable materials. Keep containers closed when not in use.
Other Precautions:

"Empty" containers can retain product residue and can be hazardous. Follow all MSDS precations in handling empty containers.
Do not cut or weld on or near empty or full containers.
Prevent prolonged or repeated breathing of vapors released during application process. Reports have associated repeated and
prolonged overexposure to solvents with permanent brain damage and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents may be harmful or fatal.

8. Exposure Controls/Personal Protection:
Ventilation Requirements:

GENERAL MECHANICAL: Exhaust ventilation capable of maintaining emissions at the point of use below OSHA PEL.
LOCAL EXHAUST: Open doors & windows. If used in an enclosed area, use exhaust fans.
Exhaust fans should be explosion-proof or set up in a way that flammable concentrations of vapors are not exposed to electrical
fixtures or hot surfaces.
Personal Protective Equipment:

Friday, April 21, 2006

Page 4 of 7

MSDS - Material Safety Data Sheet
Product Name: C-12 CPVC Cement
MSDS No.: 018750
RESPIRATORY PROTECTION:
For operations where the exposure limits may be exceeded, a NIOSH approved organic vapor respirator or supplied air respirator
is recommended. Equipment selection depends on the contaminant type and concentration. Select in accordance with 29 CFR
1910.134 and good industrial hygiene practice.
For firefighting, use self-contained breathing apparatus.
EYE PROTECTION:
Safety glasses with side shields or safety goggles.
SKIN PROTECTION:
Rubber gloves are adequate for normal use of the product. For long exposures to the substance, chemical resistant gloves may
be required to avoid prolonged exposure.
OTHER PROTECTION:
An eye wash and safety shower should be available in the work area.

9. Physical and Chemical Properties:
Boiling Point: 155 ºF

Melting Point: NA

Evaporation Rate (Butyl Acetate = 1): 3.7 - 8.0

Vapor Pressure (mm Hg.): ~ 157

Specific Gravity (H20 = 1): 0.95000

Vapor Density (AIR = 1): ~ 2.5

Solubility In Water: Negligible

Appearance and Odor: Clear orange colored, moderately viscous liquid with
Ether-like odor

Other Information: Specific Gravity = ~.95

10. Stability and Reactivity:
Stability:

Stable.
Incompatibility (Materials to Avoid):

Oxidizing agents, alkalis, amines, ammonia, acids, chlorine compounds, chlorinated inorganics (potassium, calcium and sodium
hypochlorite) and hydrogen peroxides. May attack plastic and rubber compounds.
Decomposition/By Products:

Burning can produce carbon monoxide, carbon dioxide, water, cyanide, hydrogen cyanide, and vapors of chemicals listed in
Section II.
Hazardous Polymerization:

Will not occur.

11. Toxicological Information:

Friday, April 21, 2006

Page 5 of 7

MSDS - Material Safety Data Sheet
Product Name: C-12 CPVC Cement
MSDS No.: 018750
THIS PRODUCT IS TOXIC BY INGESTION. MAY CAUSE NARCOSIS, GASTRIC INJURY OR DEATH.
CHRONIC TOXICITY: Prolonged or reapeated overexposure can cause dermatitis and damage to the kidney, liver, lungs and
central nervous system.
TOXICITY DATA:
Cyclohexanone:
Oral rat LD50: 1,620 mg/kg.
Inhalation rat LC50: 8,000 ppm/4 hours
Skin rabbit: 1 mL/kg
Methyl Ethyl Ketone:
Oral rat LD50: 2,737 mg/kg.
Inhalation rat LC50: 23,500 mg/m3/8 hours
Skin rabbit: 6480 mg/kg
Tetrahydrofuran:
Oral rat LD50: 1,650 mg/kg
Inhalation rat LC50: 21,000 ppm/ 3 hours
CPVC Resin:
No toxicity studies have been conducted on this product.
As with all chemicals for which test data are limited or do not exist, caution must be exercised through the prudent use of
protective equipment and handling procedures to minimize exposure.
SENSITIZATION:
None of the components are known to cause sensitization.
CARCINOGENICITY:
None of the components are listed as a carcinogen or suspect cacinogen by NTP, IARC or OSHA. The NTP has reported that
exposure of mice and rats to Tetrahydrofuran vapor levels up to 1800 ppm 6 hr/day, 5 days/week for their lifetime caused an
increased incidence of kidney tumors in male rats and liver tumors in female mice. The significance of these findings for human
health is unclear at this time, and may be related to "species specific" effects. Elevated incidences of tumors in humans have not
been reported for Tetrahydrofuran. ACGIH has classified Cyclohexanone and Tetrahydrofuran as "A3", Confirmed Animal
Carcinogen with Unknown Relevance to Humans.
MUTAGENICITY:
Cyclohexanone has been positive in bacterial and mammalian assays. Methyl Ethyl Ketone and Tetrahydrofuran are generally
thought not to be mutagenic.
REPRODUCTIVE TOXICITY:
Methyl Ethyl Ketone and Cyclohexanone have been shown to cause embryofetal toxicity and birth defects in laboratory animals.
Tetrahydrofuran have been found to cause adverse developmental effects only when exposure levels cause othe toxic effects to
the mother.

12. Ecological Information:
THIS PRODUCT IS NOT EXPECTED TO BE TOXIC TO AQUATIC ORGANISMS.
Cyclohexanone: 96 hour LC50 values for fish is over 100mg/L.
Methyl Ethyl Ketone: 96 hour LC50 values for fish is over 100mg/L.
Tetrahydrofuran: 96 hour LC50 for fathead minnow: 2160 mg/L.
VOC Information:
This product emits VOC's (Volatile Organic Compounds) in its use. Make sure that use of this product complies with local VOC
emission regulations, where they exist.
VOC Content (as manufactured): 776 grams/liter

13. Disposal Considerations:

Friday, April 21, 2006

Page 6 of 7

MSDS - Material Safety Data Sheet
Product Name: C-12 CPVC Cement
MSDS No.: 018750
DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS.
RCRA Hazardous Waste Number: U057, U159, U213
EPA Hazardous Waste ID Number: D001, D035, F003, F005
EPA Hazardous Waste Class: Ignitable Waste. Toxic Waste (Methyl Ethyl Ketone content)

14. Transport Information:
DOT (DEPARTMENT OF TRANSPORTATION) U.S.:
Proper Shipping Name: Less than 1 Liter = Consumer Commodity
1 Liter or Greater = Adhesives, Containing Flammable Liquid
Hazard Class/Packing Group: Less than 1 Liter = ORM-D
1 Liter or Greater = 3, PGII
UN/NA Number: Less than 1 Liter = None
1 Liter or Greater = UN1133
Hazard Labels: Less than 1 Liter = None
1 Liter or Greater = Flammable Liquid
INTERNATIONAL MARITIME DANGEROUS GOODS:
Proper Shipping Name: Flammable Liquid, N.O.S.

Limited Quantity

Hazard Class/Packing Group: 3, II
UN Number: UN1993
Label: None (Limited Quantities are excepted from labeling)
2004 NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER: 128

15. Regulatory Information:

Friday, April 21, 2006

Page 7 of 7

MSDS - Material Safety Data Sheet
Product Name: C-12 CPVC Cement
MSDS No.: 018750
SARA, Section 311 / 312, Hazard Category:
Acute Health
Chronic Health
Flammable
SARA, Section 302, Extremely Hazardous Substances:
This product does not contain chemical regulated under SARA Section 302.
SARA, Section 313, Toxic Chemical:
This product does not contains any chemical subject to SARA Title III, Section 313 reporting requirements:
CERCLA 103, Reportable Quantity:
Spills of this product over the RQ (reportable quantity) must be reported to the National Response Center; The RQ for the
product, based on the RQ for Methyl Ethyl Ketone (100% maximum) of 5,000 lbs. is 5,000 lbs. Many states have more stringent
release reporting requirements. Report spills required under federal, state and local regulations.
CALIFORNIA PROPOSITON 65:
This product contains trace amounts of chemicals known to the State of California to cause cancer. Under normal use
conditions, exposure to these chemicals at levels above the State of California "No Significant Risk Level" (NSRL) are unlikely.
The Willliam H. Harvey Company strongly recommends and encourages the proper selection and use of Personal Protective
Equipment and engineered ventilation noted in Section VIII of this MSDS.
TSCA INVENTORY:
All of the components of this product are listed on the TSCA inventory.
CANADIAN WHIMS CLASSIFICATION:
Class B, Division 2; Class D, Division 2, Subdivision A.
This product has been classified in accordance with the hazard criteria of the Conrtrolled Products Regulations (CPR) and the
MSDS contains all the information required by the CPR.

16. Other Information:
KEEP AWAY FROM HEAT SPARK AND FLAMES AT ALL TIMES.
STORE IN A COOL DRY PLACE.
ABBREVIATIONS:
~ = Approximately
< = Less Than
> = Greater Than
ACGIH = American Conference of Governmental Industrial Hygienists
AIHA
= American Industrial Hygiene Association
C = Degrees Celcius
CERCLA =
The Comprehensive Environmental Response, Compensation, and Liability Act
Deg = Degrees
EPA
= Environmental Protection Agency
F = Degrees Farenheit
HMIS
= Hazardous Materials Information System
IARC
= International Agency for Research on Cancer
NA = Not Applicable
NDA
= No Data Available
NE = Not Established
NFPA = National Fire Protection Association
NI = Not Indicated
NIOSH = National Institure of Occupational Safety and Health
NTP= National Toxicology Program
OSHA = Occupational Safety and Health Administration
SARA
=
Superfund Amendment and Reauthorization Act
DISCLAIMER: The information herein has been compiled from sources believed to be reliable, up-to-date, and is accurate to the
best of our knowledge. However, the William H. Harvey Company cannot give any guarantees regarding information from other
sources, and expressly does not make warranties, nor assumes any liability for its uses.

PIPE JOINT COMPOUND

80-067
HMIS RATING
Health	

2

Flammability	

3

Reactivity	

0

NFPA 704 RATING

MATERIAL
SAFETY DATA
SHEET

Kimball-Midwest
P.O. Box 2470
Columbus, OH 43216-2470
Corporate telephone: 614-219-6100
Emergency Telephone: 800-424-9300

Health	

2	

Flammability	

3

Reactivity	

0

NFPA 30B LEVEL
N/A

1. PRODUCT IDENTIFICATION
PART NUMBER............................. 80-067
PRODUCT NAME.......................... LOCTITE PIPE JOINT COMPOUND, 30556
CHEMICAL FAMILY....................... N/A
DOT SHIPPING.............................. Consumer Commodity ORM-D

2. HAZARDOUS INGREDIENTS
Specific Chemical Identity, Common Names	

OSHA PEL	 ACGIH TLV	

STEL	

Clay (1332-58-7)	
15mg/m3	 2mg/m3	None	
Vegetable Oil (68187-84-8)	None	None	None	
Rosin (8050-09-7)	None	None	None	
Isopropyl alcohol (67-63-0)	
200ppm	 200ppm	 400ppm	
Talc (14807-96-6)	
20mppcf	 2mg/m3	
3ppm	
Carbon, black (133-86-4)	
3.5mg/m3	 3.5mg/m3	None	
Silica, quartz (14808-60-7)	
0.1mg/m3	 .05mg/m3	None	

%

30-60
10-30
10-30
10-30
1-5
0.1-1
0.1-1

All chemical compounds marked with an asterisk (*) are toxic chemicals subject to the reporting of Section 313 of
Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372. You must
notify each person to whom this mixture of trade name product is sold. This statement must not be detached. Any
copy or redistribution of this Material Safety Data Sheet shall include this statement. **Ceiling

3. PHYSICAL DATA
BOILING POINT (RANGE)...................................>149°C to (300°F)
VAPOR PRESSURE PSIG @ 68°F...................... 33mmHg
VAPOR DENSITY (AIR = 1).................................. Heavier than air
SOLUBILITY IN WATER....................................... Partial
SPECIFIC GRAVITY (H2O = 1)............................ 1.37
MELTING/FREEZING POINT............................... N/A
EVAPORATION RATE (61%=1)........................... Not available
VOC content (by weight)....................................... 15.2%
APPEARANCE AND ODOR................................. Dark Brown Viscous liquid/
Alcoholic Odor

4. FIRE AND EXPLOSION DATA
FLASH POINT....................................................... 76°F TCC
UPPER EXPLOSIVE LIMIT (%)............................ 12.7
LOWER EXPLOSIVE LIMIT (%)........................... 2.3
EXTINGUISHING MEDIA...................................... Foam, dry chemical, CO2
SPECIAL FIREFIGHTING PROCEDURES........... As in any fire, wear self-contained
breathing apparatus pressure-demand (MSHA/
NIOSH approved or equivalent) and full protective
gear.
HAZARDOUS COMBUSTION PRODUCTS......... Alehydes. Oxides of carbon.
Carboxylic acids. Irritating organic carbon.

5. HEALTH EFFECTS DATA
SHORT TERM EFFECTS OF EXPOSURE
ROUTE OF ENTRY...............Skin absorption, Inhalation, Eye contact, Ingestion
HEALTH HAZARDS
(ACUTE AND CHRONIC)......May cause allergic skin reaction, may cause eye,
skin and respiratory tract irritation. May be harmful
if swallowed.
EYE CONTACT.....................May cause irritation. Redness. Swelling. Stinging.
INGESTION...........................Not expected to be harmful by ingestion.
INHALATION.........................May cause to nose and throat.
SKIN CONTACT....................May cause skin irritation. May cause allergic skin
reaction. Burning Sensation. Redness
MEDICAL CONDITIONS GENERALLY
AGGRAVATED BY EXPOSURE	 Eye, skin and respiratory disorders

5. HEALTH EFFECTS DATA CON’T.
FIRST AID PROCEDURES
EYE CONTACT.....................Flush with copious amounts of water, preferably,
lukewarm water for at least 15 minutes, holding eyelids
open at all times. Obtain medical attention.
SKIN CONTACT....................Wash with soap and water. Remove contaminated
clothing and shoes. Wash clothing before reuse.
Get medical attention if symptoms occur.
Ingestion...........................Do not induce vomiting. Keep individual calm. Obtain
medical attention.
INHALATION.........................Remove to fresh air. If symptoms develop and
persist, get medical attention.
SPECIAL HEALTH EFFECTS
CARCINOGEN (OSHA Guidelines) Silica, quartz, is a known carcinogen.
CALIFORNIA PROP 65	This product contains a chemical known to the
State of California to cause cancer.

6. REACTIVITY
STABILITY............................................................ Stable under normal
conditions.
INCOMPATIBILITIES............................................ Oxidizing and spontaneously
flammable products.
HAZARDOUS DECOMPOSITION
PRODUCTS.......................................................... Oxides of carbon. Aldehydes.
Carboxylic acid.
HAZARDOUS POLYMERIZATION....................... Will not occur under normal
conditions.
HAZARDOUS POLYMERIZATION CONDITIONS.....None known.

7. PRECAUTIONS FOR SAFE HANDLING & USE
PROTECTIVE EQUIPMENT
REQUIREMENTS..................Tightly sealed goggles with side shields, impermeable
gloves and protective clothing as necessary to
prevent skin contact. Local exhaust ventilation may
be necessary to control air contaminants to within
TLVs during the use of this product.
WASH REQUIREMENTS......Wash with soap and water.
SPILL OR LEAK PROCEDURES	Remove all sources of ignition. Ensure adequate
ventilation. Scrape up spilled material and place in
sealed container for disposal.
WASTE DISPOSAL METHODS	 Dispose of in accordance with local, state,
and federal regulations.
HANDLING & STORAGE......Avoid contact with eyes, skin and clothing. Avoid
breathing vapor and mist. Wash thoroughly after
handling. Use only adequate ventilation. Store below
100oF.
OTHER PRECAUTIONS.......Use NIOSH approved respirator with an organic
vapor cartridge; avoid prolonged breathing of
vapors; protection provided by air purifying
respirators is limited.

8. ADDITIONAL INFORMATION
Use self-contained breathing apparatus if TLV limits are exceeded. Do not eat
or smoke while using. Wash hands after use. Use positive pressure air supplied
respirator if there is potential for uncontrolled release, if exposure levels are
unknown, or in any circumstance where air purifying respirators may not provide
adequate protection.
The information GIVEN AND THE RECOMMENDATIONS MADE HEREIN
APPLY TO OUR PRODUCT(S) ALONE AND ARE NOT COMBINED WITH
OTHER PRODUCTS. SUCH INFORMATION IS BASED UPON OUR RESEARCH
AND ON DATA FROM OTHER RELIABLE SOURCES AND IS BELIEVED
TO BE ACCURATE. NO GUARANTEE OF ACCURACY IS MADE. IT IS
THE PURCHASER’S RESPONSIBILITY BEFORE USING ANY PRODUCT
TO VERIFY THIS DATA UNDER THEIR OWN OPERATING CONDITIONS
AND TO DETERMINE WHETHER THE PRODUCT IS SUITABLE FOR THEIR
PURPOSES.

COPYRIGHT© 1984 KIMBALL MIDWEST UPDATE 9/06

HEAT PRUF GREASE
Revision Date: 2007/05/15
Section 1: PRODUCT INFORMATION
Chemical family: Mixture.
Product uses: Industrial material.
Supplier: Radiator Specialty Co., of Canada
1711 Aimco Blvd.
Mississauga, Ontario
L4W 1H7.
Emergency Phone Number: 303−623−5716
Manufacturer: Refer to supplier.
TDG classification: Not regulated.
WHMIS classification: Not controlled.
DSL status: Not available.
Section 2: HAZARDOUS INGREDIENTS
C.A.S.

CONCENTRATION %

Ingredient Name

T.L.V.

LD/50

LC/50

60.0−100.0

MINERAL OIL

NOT AVAILABLE

NOT AVAILABLE

NOT AVAILABLE

Section 2A: ADDITIONAL INGREDIENT INFORMATION
Note: Mineral Oil − TLV 5 mg/m3.
Section 3: PHYSICAL DATA
Physical state: Semi−solid.
Appearance & odor: Gel
Petroleum odour.
Odor threshold (ppm): Not available.
Vapour pressure (mmHg): <0.1
Vapour density (air=1): >1.0
Volatiles (%)
By volume: Not available.
Evaporation rate
<0.01
(butyl acetate = 1):
Boiling point (°C): Not available.
Freezing point (°C): 284
pH: Not available.
Specific gravity @ 20 °C: (water = 1).
0.99500
Solubility in water (%): Negligible.

GR1, GR1V − HEAT PRUF GREASE

1/4

Coefficient of water\oil dist.: Not available.
VOC: Not available.
Section 4: FIRE & EXPLOSION DATA
Flammability: Not flammable.
Conditions of flammability: At temperatures at or above flash point.
Extinguishing media: Carbon dioxide, dry chemical, foam.
Water spray.
Special procedures: Positive pressure self−contained breathing apparatus required and full protection to
prevent skin contact.
Auto−ignition temperature: Not available.
Flash point (°C), method: Cleveland Open Cup.
450
Lower flammability
Not applicable.
limit (% vol):
Upper flammability
Not applicable.
limit (% vol):
Explosion Data
Sensitivity to static discharge: Not available.
Sensitivity to mechanical impact: Not available.
Hazardous combustion products: Oxides of carbon (CO, CO2).
Unidentified organic compounds.
Explosive power: Not available.
Section 5: REACTIVITY DATA
Chemical stability: Stable under normal conditions.
Conditions of instability: None known.
Hazardous polymerization: Will not occur.
Incompatible substances: Strong oxidizers.
Hazardous decomposition
See hazardous combustion products.
products:
Section 6: TOXICOLOGICAL PROPERTIES
Route of entry: Ingestion.
Skin and eye contact.
Effects of acute exposure
Eye contact: No adverse effects expected.
Skin contact: No adverse effects expected.
Inhalation: No adverse effects expected.
Ingestion: Aspiration of liquid into lungs may cause chemical pneumonitis which can be fatal.
Aspiration may result in pulmonary edema.

GR1, GR1V − HEAT PRUF GREASE

2/4

Effects of chronic exposure: None known.
LD50 of product, species & route: Not available.
LC50 of product, species & route: Not available.
Exposure limit of material: Not available for mixture, see section 2A.
Sensitization to product: Not available.
Carcinogenic effects: Not available.
Reproductive effects: Not available.
Teratogenicity: Not available.
Mutagenicity: Not available.
Synergistic materials: Not available.
Section 7: PREVENTATIVE MEASURES
Precautionary Measures
Gloves/Type:

Wear appropriate gloves.
Respiratory/Type:

Wear a NIOSH approved respirator if TLV is exceeded.
Eye/Type:

Safety glasses.
Do not wear contact lenses.
Footwear/Type: Safety shoes per local regulations.
Clothing/Type: Wear adequate protective clothes.
Other/Type: Eye wash facility should be in close proximity.
Emergency shower should be in close proximity.
Ventilation requirements: Maintain adequate ventilation.
Leak/Spill: Contain the spill.
Absorb with inert material.
Wear appropriate protective equipment.
Place in a chemical waste container for disposal.
Waste disposal: Recycle waste where applicable.
Dispose in accordance with local, provincial/state, and federal regulations.
Handling procedures and Keep away from heat, sparks, and open flame.
equipment: Use adequate ventilation.
Wash thoroughly after using, particularly before eating or smoking.
Wear personal protective equipment appropriate to task.
Keep out of reach of children.
Launder contaminated clothing prior to reuse.

GR1, GR1V − HEAT PRUF GREASE

3/4

Storage requirements: Store away from all sources of ignition.
Store away from incompatible materials.
Keep containers tightly closed.
TDG classification: Not regulated.
Special shipping information: See transportation information.
Section 8: FIRST AID MEASURES
Skin contact: Wash thoroughly with soap and water.
Seek medical attention if irritation persists.
Eye contact: Immediately flush eyes with large amounts of water for at least 15 minutes, lifting
upper and lower lids. Get prompt medical attention.
Inhalation: Remove victim to fresh air.
If breathing is difficult get medical attention.
Ingestion: Guard against aspiration of liquids into lungs.
Never give anything by mouth to an unconscious person.
Do not induce vomiting, seek immediate medical attention.
Additional information: The above information is believed to be correct but does not purport to be all
inclusive and shall be used only as a guide. This company shall not be held liable
for any inaccuracies.
Section 9: ADDITIONAL INFORMATION
General note: This material safety data sheet was prepared from information obtained from
various sources, including product suppliers and the Canadian Center for
Occupational Health and Safety.
This MSDS was generated by Conform−Plus Application Service. Visit us at www.netmsds.com.

GR1, GR1V − HEAT PRUF GREASE

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MATERIAL SAFETY DATA SHEET
PRODUCT NAME: WATER PUTTY
PRODUCT CODE: 8040
==================

HMIS CODES: H
0

SECTION I

-

MANUFACTURER IDENTIFICATION

F
0

R
0

P

=================

MANUFACTURER'S NAME: Custom Building Products, Inc.
ADDRESS: 6511 SALT LAKE AVE., BELL, CA.
90201
EMERGENCY PHONE: (323) 582-0846
INFORMATION PHONE: (323) 582-0846
DATE REVISED
: 10-11-04
NAME OF PREPARER : STEVE TAYLOR
REASON REVISED : NEW
==========

SECTION II

-

HAZARDOUS INGREDIENTS/SARA III INFORMATION

=========

OCCUPATIONAL EXPOSURE
VAPOR
LIMITS
PRESSURE
Wt.
HAZARDOUS COMPONENTS
CAS NUMBER OSHA PEL
ACGIH TLV mm Hg @ TEMP %
--------------------------------------------------------------------------------CALCIUM CARBONATE/
LIMESTONE
1317-65-3
10mg/M3
N/A
40
*** No toxic chemical(s) subject to the reporting requirements of section 313
of Title III and of 40 CFR 372 are present. ***

==============

SECTION III

-

PHYSICAL/CHEMICAL CHARACTERISTICS

=============

BOILING RANGE: N/A
SPECIFIC GRAVITY (H2O=1):
2.6
VAPOR DENSITY: HEAVIER THAN AIR
EVAPORATION RATE: SLOWER THAN ETHER
SOLUBILITY IN WATER: SLIGHT
APPEARANCE AND ODOR: YELLOW POWDER; NO ODOR
================

SECTION IV

-

FIRE AND EXPLOSION HAZARD DATA

FLASH POINT: N/A
FLAMMABLE LIMITS IN AIR BY VOLUME - LOWER:
EXTINGUISHING MEDIA: NONE KNOWN
SPECIAL FIREFIGHTING PROCEDURES

N/A

UPPER:

N/A

===============

NONE
UNUSUAL FIRE AND EXPLOSION HAZARDS
NONE

8040

MATERIAL SAFETY DATA SHEET

========================

SECTION V

-

REACTIVITY DATA

PAGE 2 OF 3
=======================

STABILITY: STABLE
CONDITIONS TO AVOID
NONE
INCOMPATIBILITY (MATERIALS TO AVOID)
POSSIBLE REACTIVITY WITH STRONG MINERAL ACIDS.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS
REACTION WITH ACIDS WILL EVOLVE CARBON DIOXIDE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
=====================

SECTION VI

-

HEALTH HAZARD DATA

======================

INHALATION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
REMOVE TO FRESH AIR.
SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE
MAY DEVELOP SUFFICIENT HEAT TO CAUSE BURNS TO SKIN IF A LARGE MASS IS KEPT
IN CONTACT WITH SKIN WHILE HARDENING. PARTICLES MAY CAUSE IRRITATION TO EYES.
SKIN ABSORPTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
NONE
INGESTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
PLASTER HARDENS WHEN WETTED AND IF INGESTED MAY RESULT IN OBSTRUCTION.
SEE PHYSICIAN.
HEALTH HAZARDS (ACUTE AND CHRONIC)
ACUTE: NONE
CHRONIC: NONE
CARCINOGENICITY:

NTP? NO

IARC MONOGRAPHS? NO

OSHA REGULATED? NO NONE

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
NONE
EMERGENCY AND FIRST AID PROCEDURES
EYE CONTACT: FLUSH WITH WATER TO REMOVE PARTICLES. IF IRRITATION PERSISTS,
SEE PHYSICIAN.
SKIN CONTACT: WASH WITH SOAP AND WATER.

INHALED: REMOVE TO FRESH AIR.
SWALLOWED: IF INGESTED, SEE PHYSICIAN BECAUSE OF POSSIBLE BLOCKAGE.

8040
===========

MATERIAL SAFETY DATA SHEET
SECTION VII

-

PAGE 3 OF 3

PRECAUTIONS FOR SAFE HANDLING AND USE

============

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
CLEAN UP USING DRY METHODS THAT DO NOT DISPERSE DUST INTO THE AIR.
AVOID BREATHING DUST. EMERGENCY PROCEDURES ARE NOT REQUIRED.
WASTE DISPOSAL METHOD
CAN BE TREATED AS COMMON WASTE.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
NONE
OTHER PRECAUTIONS
NONE
=====================

SECTION VIII

-

CONTROL MEASURES

======================

RESPIRATORY PROTECTION
NIOSH APPROVED RESPIRATOR FOR NUISANCE DUST.
VENTILATION
LOCAL EXHAUST.
PROTECTIVE GLOVES
NONE REQUIRED.
EYE PROTECTION
DUST GOGGLES OR SAFETY GLASSES.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT
NONE REQUIRED.
WORK/HYGIENIC PRACTICES
KEEP SPILLED MATERIALS CLEANED UP.
=========================

SECTION IX

-

DISCLAIMER

==========================

DISCLAIMER
THE INFORMATION PRESENTED HERE IS BELIEVED TO BE ACCURATE BUT IS NOT
WARRANTED TO BE, WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS ARE
ADVISED TO CONFIRM IN ADVANCE OF NEED, THAT THE INFORMATION IS CURRENT,
APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES.

Handy & Harman of Canada, Limited
MATERIAL SAFETY DATA SHEET
SECTION 1

MATERIAL IDENTIFICATION AND USE
SIL-FOS, FOS-FLO

MATERIAL NAME IDENTIFIER:

Manufacturer’s Name: HANDY & HARMAN OF CANADA, LIMITED
City: REXDALE

CODE BA-3 rev 10/06

Province/State/Country:

Street Address:

ONTARIO, CANADA M9W 5G1

Supplier’s Name:

290 CARLINGVIEW DRIVE

Emergency Phone No:

(416) 675-1860

Street Address:

City:

Province/State/Country:

Chemical Name:
Silver Brazing Filler Metal
Molecular Weight:
N/Avl.

SECTION 2

Emergency Phone No:
Chemical Family:
Ag/Cu/P; Cu/P; Cu/P/Sn; Cu/P/Sn/Ni Alloys
Trade Names, Synonyms:
Refer To Chart

Chemical Formula:
Refer To Chart
Material Use:
Filler Metals For Brazing

HAZARDOUS CHEMICAL COMPONENTS

Chemical Component

CAS Number

SILVER (Ag)

7440-22-4

COPPER (Cu)

7440-50-8

PHOSPHOROUS (P)
(red allotropic form)

7723-14-0

TIN (Sn)

7440-31-5

NICKEL (Ni)

7440-02-0

(Refer to filler metal chart below for nominal composition %)
ACGIH: TLVs (2000) 0.1 mg/m3 TWA (metal)
3
OSHA PEL: 0.01 mg/m TWA
LC 50 N/Avl.
LD 50 N/Avl.
ACGIH: TLVs (2000) 0.2 mg/m3 TWA (fume); 1.0 mg/m3 TWA (dusts & mists)
3
3
OSHA PELS: 0.1 mg/m TWA (fume); 1.0 mg/m TWA (dusts & mists)
LC 50 N/Avl.
LD 50 470 mg/kg oral-mouse
ACGIH: TLVs N/Avl.
OSHA PEL: N/Avl.
LC 50 N/Avl.
LD 50 N/Avl.
ACGIH: TLVs (2000) 2.0 mg/m3 TWA (metal, oxide, and inorganic compounds, as Sn)
3
OSHA PEL: 2.0 mg/m TWA
LC 50 15 mg/m3/10m inhal.-monkey
LD 50 72 mg/kg oral-mouse
3
ACGIH: TLVs (2000) 1.0 mg/m TWA (metal)(inhalable fraction)
0.2 mg/m3 TWA (insoluble compounds, as Ni)(inhalable fraction)
3
OSHA PEL: 1.0 mg/m TWA (metal & insoluble compounds, as Ni)
LC 50 N/Avl.
LD 50 N/Avl.

HANDY & HARMAN BRAZING FILLER METALS CHART
Solidus
FILLER METAL
NAME
SIL-FOS 18
SIL-FOS
SIL-FOS 6
SIL-FOS 6M
SIL-FOS 5
SIL-FOS 5F
SIL-FOS 2
SIL-FOS 2M
SIL-FOS 1
FOS-FLO 7
FOS-FLO 6
FOS-FLO 5
FOS-FLO 670
FOS-FLO 671

Nominal Composition, %

AWS / SFA
CLASS
BCuP5
BCuP-4
BCuP-3
BCuP-7
BCuP-6

BCuP-2
BCuP-1

Others

(Melt
Point)

Liquidus
(Flow Point)

Brazing Range

Specific

Ag

Cu

P

ºF ºC

ºF ºC

ºF

18
15
6
6
5
5
2
2
9

74.75
80
86.75
88
89
88.25
91
91.4
92.6

7.25
5
7.25
6
6
6.75
7
6.6
6.5

1190-645
1190-645

1190-645
1475-800

1190-1300
1300-1500

645-705
705-815

8.1
8.44

1190-645

1325-720

1275-1450

690-785

7.9

1190-645
1190-645
1190-645
1190-645
1190-645
1190-645

1460-795
1495-815
1420-770
1450-785
1495-815
1500-815

1300-1500
1325-1500
1300-1500
1325-1500
1350-1550
1350-1600

705-815
720-815
705-815
720-815
730-845
730-870

8.1
8.14
8.14
8.0
8.1
8.1

0
0
0

92.75
94
95

7.25
6
5

1310-710
1310-710
1310-710

1460-795
1570-855
1695-925

1350-1550
1375-1575
1450-1700

730-845
745-855
790-925

8.01
8.12
8.1

0
0

87
85.3

6
6.2

1215-657
1134-612

1270-687
1260-682

1270-1450
1260-1425

687-788
682-774

8.4
8.47

7 Sn
7 Sn, 1.5 Ni

ºC

Gravity

Handy & Harman of Canada, Limited
MATERIAL SAFETY DATA SHEET
SECTION 3

PHYSICAL DATA

Physical State: Gas
Liquid
Solid ■
Odour Threshold (ppm): N/Avl.
Evaporation Rate: Solid - N/Appl.
% Volatile (By Volume): N/Appl.
Specific Gravity: Refer To Chart

SECTION 4

CODE BA-3 rev 10/06

Odour & Appearance: No Odour; Solid Metal Wire, Strip, Powder, Paste
Vapour Pressure (mm.Hg): N/Avl.
Vapour Density (AIR=1):Solid-N/Appl.
Boiling Point (ºC): Solid - N/Appl.
Freezing Point (ºC): Solid - N/Appl.
Solubility In Water (20ºC): Insoluble
pH: N/Appl.
Coeff.-Water Oil Disp.: N/Appl.

FIRE AND EXPLOSION DATA

Flammability: Yes ■ No
If yes, under which conditions?
Dust, powder and fumes are flammable when exposed to flame or by chemical reaction with oxidizing agents (see Section 5 for incompatible
materials). Fires or explosions involving these alloys may release potentially toxic emissions of metal or metal oxide fumes (see Section 2 for
hazardous components).
Means Of Extinction: Dry powder for metal fires. Do not use water on dust, powder or fume fires.
Special Procedures: Use self-contained breathing apparatus with full face-piece operated in pressure demand or other positive pressure
mode.
Flashpoint(ºC) & Method: Solid Metal - Non-Flammable
Upper Explosion Limit (% By Volume): N/Appl.
Lower Explosion Limit (%By Volume): Solid Metal - N/Appl.
Auto Ignition Temperature (ºC): Solid Metal - N/Appl.
TDG Flammability Classification: None
Hazardous Combustion Products: Solid Metal - N/Appl.
Sensitivity To Impact Explosion Data: N/Appl.
Rate Of Burning: N/Appl.
Explosive Power: N/Appl.
Sensitivity To Static Discharge: N/Appl.

SECTION 5

REACTIVITY DATA
***AVOID DISPERSION OF FINELY DIVIDED PARTICLES IN AIR***

Chemical Stability: Yes ■ No
If yes, under which conditions? Normal Ambient Environment.
Incompatibility With Other Substances: Yes ■ No
If yes, which ones?
Ammonia; HNO3; Azides; Ethanol; Ethylenimine; Mg; Chlorates; Bromates; C12; CIF3; Chlorine Oxides; Inorganic Peroxides; Peroxyformic
Acid; Permonosulphuric Acid; Fluorine; CS2; SeOCI; SeOF; SeF4; Iodates.
Reactivity And Under What Conditions: Silver and copper can form explosive acetylides upon contact with uncombusted acetylene.
Hazardous Decomposition Products: Hazardous polymerization will not occur. Upon heating, danger is mostly from inhalation of metal
(oxide) fumes. Overexposure to elemental oxide fumes or dust can cause nausea and metal fume fever. Use hooded exhaust ventilation to
carry all fumes away from work area and, if necessary, use air supplied respirator (see Section 7). Thought should be given to the heating
methods, flux and base metals being joined which could emit fumes on heating depending on their particular chemistry.
Avoid overheating (see chart, Brazing Range).

SECTION 6

TOXICOLOGICAL PROPERTIES

Route Of Exposure:
Inhalation
Inhalation of the components of these products are not known to present a significant risk to health
when used according to instructions and with appropriate protective measures (see Section 7). Inhalation of the component/elements has
been reported to cause one or more of the following symptoms/effects upon excessively high and/or prolonged inhalation/exposure.
SILVER:
Acute
May cause grey discolouration of mucous membranes.
Chronic
May produce argyria, a permanent blue-grey discolouration of the skin, eyes, mucous membranes,
and the respiratory tract.
COPPER:
Acute
Acute exposure to dust or fume may cause respiratory tract irritation, fever, muscle ache, chills,
cough, weakness, and a metallic taste.
Chronic
Exposure may cause damage to the liver, kidney, spleen, pancreas, and brain.
PHOSPHOROUS:
Acute
When heated in air, fume is corrosive and irritating to eyes, nose, throat, and mucous membranes.
Chronic
Unlikely.
TIN
Acute
Dust or fume may cause respiratory tract irritation, nausea, joint/muscle pains.
Chronic
May cause stannosis, a benign pneumoconeosis, as well as possible dyspnea.
NICKEL:
Acute
Dust or fumes may produce headache, nausea, vertigo, asthma, and pulmonary edema.
Chronic
May increase the risk of cancer to the nasopharynx, lungs, prostate, and kidney.

Miscellaneous Toxicological Information
Nickel is classified as a potential human carcinogen by the following organizations (with respective sub-classifications):
1. IARC (Group 2B)
2. NTP (Group 2B)
Nickel has also produced fetotoxic and teratogenic effects in animal studies, and mutagenic responses in mammalian cell cultures.
Neither Silver, Copper, Tin, nor Phosphorous are classified as potential or demonstrated human carcinogens by IARC, NIOSH, NTP, OSHA,
or ACGIH.

Page 2

Handy & Harman of Canada, Limited
MATERIAL SAFETY DATA SHEET
SECTION 6 (cont’d)

TOXICOLOGICAL PROPERTIES

CODE BA-3 rev 10/06

Health Conditions Aggravated By Exposure: Pre-existing pulmonary diseases (e.g., bronchitis, emphysema) may be aggravated by
inhalation exposure to these materials, particularly as fume. Exposure to nickel by inhalation and/or ingestion may aggravate pre-existing
diseases of the liver, kidneys, central nervous system, and musculoskeletal system.
Route Of Exposure
Skin: In solid form, materials are not known to be hazardous. In finely divided form, skin contact may produce localized irritation, localized
argyria, skin discolouration, and contact or allergic dermatitis.
Eyes: Exposure of the eyes to finely divided form of these materials may produce localized argyria, irritation, conjunctivitis, and ulceration of
the cornea.
Ingestion: Finely divided form of these materials may produce gastric irritation, vomiting, abdominal pain, hemorrhage, and diarrhea. Longterm chronic ingestion may produce damage to the liver, kidney, spleen, pancreas, musculoskeletal system, blood-forming organs, and
central nervous system.
Exposure Limit Of Material:
Irritancy Of Material:
LD 50 Of Material - Specify
LC 50 Of Material
N/Avl.
N/Avl.
Species And Route: N/Avl.
Specify Species: N/Avl.
Sensitizing Capability Of
Carcinogenicity Of Material:
Reproductive Effects Of
Synergistic Materials:
N/Avl.
N/Avl.
Material: N/Avl.
Material: N/Avl.

SECTION 7

PREVENTATIVE MEASURES

Personal Protective Equipment: Personal protective equipment will be required when using these materials. The nature of the processing
activity will determine what form of equipment is necessary, i.e., safety glasses, respirator, protective clothing, etc. Personal protective
equipment should not be substituted for proper handling and engineering controls.
Gloves: Wear appropriate protective gloves to prevent injury from the hazards of brazing and/or repeated contact with finely divided material.
Avoid flammable fabrics.
Respiratory: Local exhaust, mechanical ventilation, and/or respiratory equipment may be required to maintain a protection factor appropriate
to the airborne concentrations of the contaminants generated and provide sufficient clean air for breathing. If exposure levels exceed OSHA
PELS, wear a NIOSH/MSHA-approved respirator (or other approving authority) for protection from the airborne contaminants. All adjacent
persons in the immediate vicinity of brazing or “soldering” operations shall be similarly protected as necessary by ventilation or approved
respirators.
Eyes: Wear eye protection (safety glasses, dust-proof goggles) adequate to prevent eye contact with this material in finely divided form and
to prevent eye injury from the hazards of brazing. Plastic-frame safety spectacles with side shields and filter lenses (shade #3 or #4) are
recommended.
Footwear: Refer to workplace safety regulations.
Clothing: Avoid flammable fabrics. Wear appropriate clothing to prevent skin injuries from the hazards of brazing.
Other Protection: Practice good housekeeping and personal hygiene procedures. To avoid ingestion of material, wash hands and face
before eating, drinking, or consumption of tobacco.
Brazing alloys may be used with a separately applied flux which, when heated, may emit irritating and/or toxic gases and fumes. Consult the
MSDS for the specific flux in use to determine its hazards and appropriate protective measures. For general guidance, refer to American
National Standards Institute (ANSI) Z49.1, “Safety in Welding and Cutting” (American Welding Society, Miami, FL 33135).
Engineering Controls: Adequate ventilation, sinks, showers, and eyewash stations should be provided. The best industrial control practice
is to maintain concentrations of all chemical fumes and dusts as low as is practical.
Leak And Spill Procedure: If metal is molten, allow to solidify and cool. Clean up any spilled material so as to minimize dispersion of dusts.
Wet sweeping or vacuuming using HEPA, or similarly approved filtration, are recommended methods.
Waste Disposal: Return to manufacturer for reclaim. Sara Title III - Hazard Classes: Acute Health Hazard; Chronic Health Hazard
Handling Procedure And Equipment: Avoid heating above brazing range (see chart, Section 2) as excessive fumes may result. When
applicable, use sufficient flux or atmosphere to protect the metals and minimize oxidation/vapourization during use.
Storage Requirements: Avoid storage near incompatible materials (see also Section 5). Also avoid conditions which create toxic fumes or
dusts. Wash exposed skin after handling material. Stable at room temperature.
Special Shipping Information: No special requirements.
WHMIS Classification: Class D, Division 2, Subdivision B.

Page 3

Handy & Harman of Canada, Limited
MATERIAL SAFETY DATA SHEET
SECTION 8

FIRST AID MEASURES

CODE BA-3 rev 10/06

Emergency And First Aid Procedures
Inhalation: Move victim to fresh air at once. Give oxygen if breathing is laboured, artificial respiration if victim is not breathing. Keep person
warm and quiet. Get medical attention immediately.
Skin: Contact in solid forms is not known to be hazardous. If clothing is contaminated with finely divided particles, remove. Wash affected
area with large quantities of water for at least 5 minutes. Get medical attention if necessary.
Eyes: Flush immediately with large amounts of water for at least 15 minutes while lifting the lower and upper eyelids. If irritation continues,
get medical attention.
Ingestion: If person is conscious, give large amounts of water and induce vomiting. Seek medical attention. If person is unconscious or
convulsive, get immediate medical attention.

***SEEK MEDICAL ATTENTION IN ALL CASES OF EXPOSURE***
SIGNS AND SYMPTOMS OF EXPOSURE:
Acute
Inhalation: Chills, fever, aching muscles, sneezing, dry throat, coughing, constriction of throat, nausea, irritation of nose and trachea,
discolouration of mucous membranes, difficulty in breathing, chest pain, headache.
Skin: Particles may cause irritation, pain, nausea, vomiting.
Eyes: Particles may cause irritation, redness, itching.
Ingestion: Nausea, vomiting, headache, diarrhea, fever, abdominal pain.
Chronic
Inhalation: Cough, difficulty in breathing, laryngitis, discolouration of mucous membranes, kidney and liver disorders.
Skin: May cause argaria, discolouration, contact dermatitis and/or allergic sensitization among hyper-susceptible individuals.
Eyes: Irritation
Ingestion: May cause damage to the liver, kidneys, musculoskeletal system and nervous system.
Medical Conditions Generally Aggravated By Exposure: (see Section 6).
Sources Used: Canadian Centre For Occupational Health And Safety, Hamilton, Ontario; American Welding Society, Miami, Florida;
ACGIH, Cincinnati, Ohio; Lucas-Milhaupt Inc., Cudahy, Wisconsin.
Additional Information: The information contained herein is only for the manufactured product. The composition and hazards of any
resultant fumes due to heating methods, filler metal alloy, flux and base metals employed may vary significantly.
Brazing fumes consist of various airborne substances which may create hazards to health when they are inhaled or swallowed. The degree
of hazard to the worker(s) in the work area depends upon the composition of the total fume, the concentration of contaminants in the
breathing air and the time-length of exposure to it. It is the responsibility of the user/employer to ensure the suitability of the material use and
that TLV, TWA, and STEL values are not exceeded.
Assessment of the possible exposure to the worker(s) to hazardous fumes, when required, should be carried out by a competent person and
may involve air concentration measurements

SECTION 9
PREPARED BY:
Marketing Department

PREPARATION DATE OF MSDS
PHONE NO:
(416) 675-1860

DATE:
Revised 10/06

Page 4

Handy & Harman of Canada, Limited
MATERIAL SAFETY DATA SHEET
SECTION 1

MATERIAL IDENTIFICATION AND USE
SIL-FOS, FOS-FLO

MATERIAL NAME IDENTIFIER:

Manufacturer’s Name: HANDY & HARMAN OF CANADA, LIMITED
City: REXDALE

CODE BA-3 rev 10/06

Province/State/Country:

Street Address:

ONTARIO, CANADA M9W 5G1

Supplier’s Name:

290 CARLINGVIEW DRIVE

Emergency Phone No:

(416) 675-1860

Street Address:

City:

Province/State/Country:

Chemical Name:
Silver Brazing Filler Metal
Molecular Weight:
N/Avl.

SECTION 2

Emergency Phone No:
Chemical Family:
Ag/Cu/P; Cu/P; Cu/P/Sn; Cu/P/Sn/Ni Alloys
Trade Names, Synonyms:
Refer To Chart

Chemical Formula:
Refer To Chart
Material Use:
Filler Metals For Brazing

HAZARDOUS CHEMICAL COMPONENTS

Chemical Component

CAS Number

SILVER (Ag)

7440-22-4

COPPER (Cu)

7440-50-8

PHOSPHOROUS (P)
(red allotropic form)

7723-14-0

TIN (Sn)

7440-31-5

NICKEL (Ni)

7440-02-0

(Refer to filler metal chart below for nominal composition %)
ACGIH: TLVs (2000) 0.1 mg/m3 TWA (metal)
3
OSHA PEL: 0.01 mg/m TWA
LC 50 N/Avl.
LD 50 N/Avl.
ACGIH: TLVs (2000) 0.2 mg/m3 TWA (fume); 1.0 mg/m3 TWA (dusts & mists)
3
3
OSHA PELS: 0.1 mg/m TWA (fume); 1.0 mg/m TWA (dusts & mists)
LC 50 N/Avl.
LD 50 470 mg/kg oral-mouse
ACGIH: TLVs N/Avl.
OSHA PEL: N/Avl.
LC 50 N/Avl.
LD 50 N/Avl.
ACGIH: TLVs (2000) 2.0 mg/m3 TWA (metal, oxide, and inorganic compounds, as Sn)
3
OSHA PEL: 2.0 mg/m TWA
LC 50 15 mg/m3/10m inhal.-monkey
LD 50 72 mg/kg oral-mouse
3
ACGIH: TLVs (2000) 1.0 mg/m TWA (metal)(inhalable fraction)
0.2 mg/m3 TWA (insoluble compounds, as Ni)(inhalable fraction)
3
OSHA PEL: 1.0 mg/m TWA (metal & insoluble compounds, as Ni)
LC 50 N/Avl.
LD 50 N/Avl.

HANDY & HARMAN BRAZING FILLER METALS CHART
Solidus
FILLER METAL
NAME
SIL-FOS 18
SIL-FOS
SIL-FOS 6
SIL-FOS 6M
SIL-FOS 5
SIL-FOS 5F
SIL-FOS 2
SIL-FOS 2M
SIL-FOS 1
FOS-FLO 7
FOS-FLO 6
FOS-FLO 5
FOS-FLO 670
FOS-FLO 671

Nominal Composition, %

AWS / SFA
CLASS
BCuP5
BCuP-4
BCuP-3
BCuP-7
BCuP-6

BCuP-2
BCuP-1

Others

(Melt
Point)

Liquidus
(Flow Point)

Brazing Range

Specific

Ag

Cu

P

ºF ºC

ºF ºC

ºF

18
15
6
6
5
5
2
2
9

74.75
80
86.75
88
89
88.25
91
91.4
92.6

7.25
5
7.25
6
6
6.75
7
6.6
6.5

1190-645
1190-645

1190-645
1475-800

1190-1300
1300-1500

645-705
705-815

8.1
8.44

1190-645

1325-720

1275-1450

690-785

7.9

1190-645
1190-645
1190-645
1190-645
1190-645
1190-645

1460-795
1495-815
1420-770
1450-785
1495-815
1500-815

1300-1500
1325-1500
1300-1500
1325-1500
1350-1550
1350-1600

705-815
720-815
705-815
720-815
730-845
730-870

8.1
8.14
8.14
8.0
8.1
8.1

0
0
0

92.75
94
95

7.25
6
5

1310-710
1310-710
1310-710

1460-795
1570-855
1695-925

1350-1550
1375-1575
1450-1700

730-845
745-855
790-925

8.01
8.12
8.1

0
0

87
85.3

6
6.2

1215-657
1134-612

1270-687
1260-682

1270-1450
1260-1425

687-788
682-774

8.4
8.47

7 Sn
7 Sn, 1.5 Ni

ºC

Gravity

Handy & Harman of Canada, Limited
MATERIAL SAFETY DATA SHEET
SECTION 3

PHYSICAL DATA

Physical State: Gas
Liquid
Solid ■
Odour Threshold (ppm): N/Avl.
Evaporation Rate: Solid - N/Appl.
% Volatile (By Volume): N/Appl.
Specific Gravity: Refer To Chart

SECTION 4

CODE BA-3 rev 10/06

Odour & Appearance: No Odour; Solid Metal Wire, Strip, Powder, Paste
Vapour Pressure (mm.Hg): N/Avl.
Vapour Density (AIR=1):Solid-N/Appl.
Boiling Point (ºC): Solid - N/Appl.
Freezing Point (ºC): Solid - N/Appl.
Solubility In Water (20ºC): Insoluble
pH: N/Appl.
Coeff.-Water Oil Disp.: N/Appl.

FIRE AND EXPLOSION DATA

Flammability: Yes ■ No
If yes, under which conditions?
Dust, powder and fumes are flammable when exposed to flame or by chemical reaction with oxidizing agents (see Section 5 for incompatible
materials). Fires or explosions involving these alloys may release potentially toxic emissions of metal or metal oxide fumes (see Section 2 for
hazardous components).
Means Of Extinction: Dry powder for metal fires. Do not use water on dust, powder or fume fires.
Special Procedures: Use self-contained breathing apparatus with full face-piece operated in pressure demand or other positive pressure
mode.
Flashpoint(ºC) & Method: Solid Metal - Non-Flammable
Upper Explosion Limit (% By Volume): N/Appl.
Lower Explosion Limit (%By Volume): Solid Metal - N/Appl.
Auto Ignition Temperature (ºC): Solid Metal - N/Appl.
TDG Flammability Classification: None
Hazardous Combustion Products: Solid Metal - N/Appl.
Sensitivity To Impact Explosion Data: N/Appl.
Rate Of Burning: N/Appl.
Explosive Power: N/Appl.
Sensitivity To Static Discharge: N/Appl.

SECTION 5

REACTIVITY DATA
***AVOID DISPERSION OF FINELY DIVIDED PARTICLES IN AIR***

Chemical Stability: Yes ■ No
If yes, under which conditions? Normal Ambient Environment.
Incompatibility With Other Substances: Yes ■ No
If yes, which ones?
Ammonia; HNO3; Azides; Ethanol; Ethylenimine; Mg; Chlorates; Bromates; C12; CIF3; Chlorine Oxides; Inorganic Peroxides; Peroxyformic
Acid; Permonosulphuric Acid; Fluorine; CS2; SeOCI; SeOF; SeF4; Iodates.
Reactivity And Under What Conditions: Silver and copper can form explosive acetylides upon contact with uncombusted acetylene.
Hazardous Decomposition Products: Hazardous polymerization will not occur. Upon heating, danger is mostly from inhalation of metal
(oxide) fumes. Overexposure to elemental oxide fumes or dust can cause nausea and metal fume fever. Use hooded exhaust ventilation to
carry all fumes away from work area and, if necessary, use air supplied respirator (see Section 7). Thought should be given to the heating
methods, flux and base metals being joined which could emit fumes on heating depending on their particular chemistry.
Avoid overheating (see chart, Brazing Range).

SECTION 6

TOXICOLOGICAL PROPERTIES

Route Of Exposure:
Inhalation
Inhalation of the components of these products are not known to present a significant risk to health
when used according to instructions and with appropriate protective measures (see Section 7). Inhalation of the component/elements has
been reported to cause one or more of the following symptoms/effects upon excessively high and/or prolonged inhalation/exposure.
SILVER:
Acute
May cause grey discolouration of mucous membranes.
Chronic
May produce argyria, a permanent blue-grey discolouration of the skin, eyes, mucous membranes,
and the respiratory tract.
COPPER:
Acute
Acute exposure to dust or fume may cause respiratory tract irritation, fever, muscle ache, chills,
cough, weakness, and a metallic taste.
Chronic
Exposure may cause damage to the liver, kidney, spleen, pancreas, and brain.
PHOSPHOROUS:
Acute
When heated in air, fume is corrosive and irritating to eyes, nose, throat, and mucous membranes.
Chronic
Unlikely.
TIN
Acute
Dust or fume may cause respiratory tract irritation, nausea, joint/muscle pains.
Chronic
May cause stannosis, a benign pneumoconeosis, as well as possible dyspnea.
NICKEL:
Acute
Dust or fumes may produce headache, nausea, vertigo, asthma, and pulmonary edema.
Chronic
May increase the risk of cancer to the nasopharynx, lungs, prostate, and kidney.

Miscellaneous Toxicological Information
Nickel is classified as a potential human carcinogen by the following organizations (with respective sub-classifications):
1. IARC (Group 2B)
2. NTP (Group 2B)
Nickel has also produced fetotoxic and teratogenic effects in animal studies, and mutagenic responses in mammalian cell cultures.
Neither Silver, Copper, Tin, nor Phosphorous are classified as potential or demonstrated human carcinogens by IARC, NIOSH, NTP, OSHA,
or ACGIH.

Page 2

Handy & Harman of Canada, Limited
MATERIAL SAFETY DATA SHEET
SECTION 6 (cont’d)

TOXICOLOGICAL PROPERTIES

CODE BA-3 rev 10/06

Health Conditions Aggravated By Exposure: Pre-existing pulmonary diseases (e.g., bronchitis, emphysema) may be aggravated by
inhalation exposure to these materials, particularly as fume. Exposure to nickel by inhalation and/or ingestion may aggravate pre-existing
diseases of the liver, kidneys, central nervous system, and musculoskeletal system.
Route Of Exposure
Skin: In solid form, materials are not known to be hazardous. In finely divided form, skin contact may produce localized irritation, localized
argyria, skin discolouration, and contact or allergic dermatitis.
Eyes: Exposure of the eyes to finely divided form of these materials may produce localized argyria, irritation, conjunctivitis, and ulceration of
the cornea.
Ingestion: Finely divided form of these materials may produce gastric irritation, vomiting, abdominal pain, hemorrhage, and diarrhea. Longterm chronic ingestion may produce damage to the liver, kidney, spleen, pancreas, musculoskeletal system, blood-forming organs, and
central nervous system.
Exposure Limit Of Material:
Irritancy Of Material:
LD 50 Of Material - Specify
LC 50 Of Material
N/Avl.
N/Avl.
Species And Route: N/Avl.
Specify Species: N/Avl.
Sensitizing Capability Of
Carcinogenicity Of Material:
Reproductive Effects Of
Synergistic Materials:
N/Avl.
N/Avl.
Material: N/Avl.
Material: N/Avl.

SECTION 7

PREVENTATIVE MEASURES

Personal Protective Equipment: Personal protective equipment will be required when using these materials. The nature of the processing
activity will determine what form of equipment is necessary, i.e., safety glasses, respirator, protective clothing, etc. Personal protective
equipment should not be substituted for proper handling and engineering controls.
Gloves: Wear appropriate protective gloves to prevent injury from the hazards of brazing and/or repeated contact with finely divided material.
Avoid flammable fabrics.
Respiratory: Local exhaust, mechanical ventilation, and/or respiratory equipment may be required to maintain a protection factor appropriate
to the airborne concentrations of the contaminants generated and provide sufficient clean air for breathing. If exposure levels exceed OSHA
PELS, wear a NIOSH/MSHA-approved respirator (or other approving authority) for protection from the airborne contaminants. All adjacent
persons in the immediate vicinity of brazing or “soldering” operations shall be similarly protected as necessary by ventilation or approved
respirators.
Eyes: Wear eye protection (safety glasses, dust-proof goggles) adequate to prevent eye contact with this material in finely divided form and
to prevent eye injury from the hazards of brazing. Plastic-frame safety spectacles with side shields and filter lenses (shade #3 or #4) are
recommended.
Footwear: Refer to workplace safety regulations.
Clothing: Avoid flammable fabrics. Wear appropriate clothing to prevent skin injuries from the hazards of brazing.
Other Protection: Practice good housekeeping and personal hygiene procedures. To avoid ingestion of material, wash hands and face
before eating, drinking, or consumption of tobacco.
Brazing alloys may be used with a separately applied flux which, when heated, may emit irritating and/or toxic gases and fumes. Consult the
MSDS for the specific flux in use to determine its hazards and appropriate protective measures. For general guidance, refer to American
National Standards Institute (ANSI) Z49.1, “Safety in Welding and Cutting” (American Welding Society, Miami, FL 33135).
Engineering Controls: Adequate ventilation, sinks, showers, and eyewash stations should be provided. The best industrial control practice
is to maintain concentrations of all chemical fumes and dusts as low as is practical.
Leak And Spill Procedure: If metal is molten, allow to solidify and cool. Clean up any spilled material so as to minimize dispersion of dusts.
Wet sweeping or vacuuming using HEPA, or similarly approved filtration, are recommended methods.
Waste Disposal: Return to manufacturer for reclaim. Sara Title III - Hazard Classes: Acute Health Hazard; Chronic Health Hazard
Handling Procedure And Equipment: Avoid heating above brazing range (see chart, Section 2) as excessive fumes may result. When
applicable, use sufficient flux or atmosphere to protect the metals and minimize oxidation/vapourization during use.
Storage Requirements: Avoid storage near incompatible materials (see also Section 5). Also avoid conditions which create toxic fumes or
dusts. Wash exposed skin after handling material. Stable at room temperature.
Special Shipping Information: No special requirements.
WHMIS Classification: Class D, Division 2, Subdivision B.

Page 3

Handy & Harman of Canada, Limited
MATERIAL SAFETY DATA SHEET
SECTION 8

FIRST AID MEASURES

CODE BA-3 rev 10/06

Emergency And First Aid Procedures
Inhalation: Move victim to fresh air at once. Give oxygen if breathing is laboured, artificial respiration if victim is not breathing. Keep person
warm and quiet. Get medical attention immediately.
Skin: Contact in solid forms is not known to be hazardous. If clothing is contaminated with finely divided particles, remove. Wash affected
area with large quantities of water for at least 5 minutes. Get medical attention if necessary.
Eyes: Flush immediately with large amounts of water for at least 15 minutes while lifting the lower and upper eyelids. If irritation continues,
get medical attention.
Ingestion: If person is conscious, give large amounts of water and induce vomiting. Seek medical attention. If person is unconscious or
convulsive, get immediate medical attention.

***SEEK MEDICAL ATTENTION IN ALL CASES OF EXPOSURE***
SIGNS AND SYMPTOMS OF EXPOSURE:
Acute
Inhalation: Chills, fever, aching muscles, sneezing, dry throat, coughing, constriction of throat, nausea, irritation of nose and trachea,
discolouration of mucous membranes, difficulty in breathing, chest pain, headache.
Skin: Particles may cause irritation, pain, nausea, vomiting.
Eyes: Particles may cause irritation, redness, itching.
Ingestion: Nausea, vomiting, headache, diarrhea, fever, abdominal pain.
Chronic
Inhalation: Cough, difficulty in breathing, laryngitis, discolouration of mucous membranes, kidney and liver disorders.
Skin: May cause argaria, discolouration, contact dermatitis and/or allergic sensitization among hyper-susceptible individuals.
Eyes: Irritation
Ingestion: May cause damage to the liver, kidneys, musculoskeletal system and nervous system.
Medical Conditions Generally Aggravated By Exposure: (see Section 6).
Sources Used: Canadian Centre For Occupational Health And Safety, Hamilton, Ontario; American Welding Society, Miami, Florida;
ACGIH, Cincinnati, Ohio; Lucas-Milhaupt Inc., Cudahy, Wisconsin.
Additional Information: The information contained herein is only for the manufactured product. The composition and hazards of any
resultant fumes due to heating methods, filler metal alloy, flux and base metals employed may vary significantly.
Brazing fumes consist of various airborne substances which may create hazards to health when they are inhaled or swallowed. The degree
of hazard to the worker(s) in the work area depends upon the composition of the total fume, the concentration of contaminants in the
breathing air and the time-length of exposure to it. It is the responsibility of the user/employer to ensure the suitability of the material use and
that TLV, TWA, and STEL values are not exceeded.
Assessment of the possible exposure to the worker(s) to hazardous fumes, when required, should be carried out by a competent person and
may involve air concentration measurements

SECTION 9
PREPARED BY:
Marketing Department

PREPARATION DATE OF MSDS
PHONE NO:
(416) 675-1860

DATE:
Revised 10/06

Page 4

Page 1/7

Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 07/25/2003

Reviewed on 07/14/2003

1 Identification of substance
Product details
Trade name: 256GS Sn55Pb45, Sn60Pb40, Sn62Pb38, Sn63Pb37, Sn65Pb35
Application of the substance / the preparation: Solder paste
Manufacturer/Supplier:
Kester
515 E. Touhy Ave.
Des Plaines, IL 60018
Information department:
MSDS Coordinator
Emergency information:
CHEMTREC 24-Hour Emergency Telephone Number:
CHEMTREC 24-Hour Emergency Telephone Number (Outside of the U.S. and Canada):

Tel.(847) 297-1600
Fax.(847) 390-9338

Tel. (847) 699-5755
(800)424-9300
(703)527-3887

2 Composition/Data on components
Chemical characterization
Description: Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
7440-31-5 tin
7439-92-1 lead
65997-05-9 Rosin, polymerized
8050-09-7 Rosin
143-24-8 bis(2-(2-methoxyethoxy)ethyl) ether

50-100%
25-50%
2.5-10%
≤ 2.5%
≤ 2.5%

3 Hazards identification
WHMIS Hazard Symbols

=

Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of international guidelines.
Harmful by inhalation and if swallowed.
Danger of cumulative effects.
May cause sensitisation by skin contact.
Possible risk of impaired fertility.
Contains lead. Should not be used on surfaces liable to be chewed or sucked by children.
Classification system:
NFPA ratings (scale 0 - 4)

2

1

0

Health = 2
Fire = 1
Reactivity = 0
(Contd. on page 2)
USA

DR

Page 2/7

Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 07/25/2003

Reviewed on 07/14/2003

Trade name: 256GS Sn55Pb45, Sn60Pb40, Sn62Pb38, Sn63Pb37, Sn65Pb35
(Contd. of page 1)

HMIS-ratings (scale 0 - 4)
HEALTH

*2

FIRE

1

REACTIVITY 0

Health = *2
Fire = 1
Reactivity = 0

4 First aid measures
General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
After inhalation: Supply fresh air; consult doctor in case of complaints.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact: Rinse opened eye for several minutes under running water.
After swallowing: Induce vomiting, if person is conscious. Seek medical help.

5 Fire fighting measures
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards caused by the material, its products of combustion or resulting gases:
In case of fire, the following can be released:
Carbon monoxide (CO)
Carbon dioxide (CO2)
Aliphatic aldehydes
Melted solder above 1000°F will liberate toxic lead and/or antimony fumes.
Protective equipment: Wear self-contained respiatory protective device.

6 Accidental release measures
Person-related safety precautions: Ensure adequate ventilation
Measures for environmental protection: Do not allow product to reach sewage system or any water course.
Measures for cleaning/collecting: Scoop up paste and deposit in appropriate containers.

7 Handling and storage
Handling:
Information for safe handling:
Wash hands after handling paste and before eating or smoking. Care should be taken to remove paste from
under fingernails.
Information about protection against explosions and fires: Keep respiratory protective device available.
Storage:
o
Requirements to be met by storerooms and receptacles: Store at or near 5 C in a dry location.
Information about storage in one common storage facility: Not required.
(Contd. on page 3)
USA

DR

Page 3/7

Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 07/25/2003

Reviewed on 07/14/2003

Trade name: 256GS Sn55Pb45, Sn60Pb40, Sn62Pb38, Sn63Pb37, Sn65Pb35
(Contd. of page 2)

Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles.

8 Exposure controls and personal protection
Additional information about design of technical systems: No further data; see item 7.
Components with limit values that require monitoring at the workplace:
7440-31-5 tin
PEL 2 mg/m³
Metal
REL 2 mg/m³
Tin, Metal
TLV 2 mg/m³
7439-92-1 lead
PEL 0.05* mg/m³
as Pb
REL <0.1* mg/m³
as Pb; *Blood Pb <0.06 mg/100 g whole blood
TLV 0.05 mg/m³
as Pb; BEI
8050-09-7 Rosin
PEL (Colophony)
TLV SEN; (L)
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Breathing equipment:
When ventilation is not sufficient to remove fumes from the breathing zone, a safety approved respirator or selfcontained breathing apparatus should be worn.
Protection of hands:

S

Protective gloves

Material of gloves:
Nitrile rubber, NBR
Natural rubber, NR
Penetration time of glove material:
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:

R

Tightly sealed goggles
(Contd. on page 4)
USA

DR

Page 4/7

Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 07/25/2003

Reviewed on 07/14/2003

Trade name: 256GS Sn55Pb45, Sn60Pb40, Sn62Pb38, Sn63Pb37, Sn65Pb35
(Contd. of page 3)

Safety glasses

9 Physical and chemical properties
General Information
Form:
Color:
Odor:

Pasty
Silver grey
Mild

Change in condition
Melting point/Melting range: > 100°C (> 212°F)
Boiling point/Boiling range: Undetermined.
Flash point:

> 93°C (> 199°F)

Danger of explosion:

Product does not present an explosion hazard.

Density at 20°C (68°F):

> 7 g/cm³

Solubility in / Miscibility with
Water:
Insoluble.

10 Stability and reactivity
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Materials to be avoided: Strong acids, strong oxidizers.
Dangerous reactions No dangerous reactions known.
Dangerous products of decomposition:
When heated to soldering temperatures, the solvents are evaporated and rosin may be thermally degraded to
liberate aliphatic aldehydes and acids.

11 Toxicological information
Acute toxicity:
Primary irritant effect:
on the skin: Possible local irritation by contact with flux or fumes.
on the eye: Smoke during soldering can cause eye irritation.
through inhalation:
Flux fumes during soldering may cause irritation and damage of mucous membranes and respiratory system.
through ingestion: May be harmful if swallowed.
Sensitization: Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Irritant
USA

(Contd. on page 5)

DR

Page 5/7

Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 07/25/2003

Reviewed on 07/14/2003

Trade name: 256GS Sn55Pb45, Sn60Pb40, Sn62Pb38, Sn63Pb37, Sn65Pb35
(Contd. of page 4)

12 Ecological information
General notes: Do not allow product to reach ground water, water course or sewage system.

13 Disposal considerations
Product:
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.

14 Transport information
DOT regulations:
Hazard class:
Not regulated.
Land transport ADR/RID (cross-border):
ADR/RID class: Not regulated.
Maritime transport IMDG:
IMDG Class:
Not regulated.
Air transport ICAO-TI and IATA-DGR:
ICAO/IATA Class: Not regulated.

15 Regulations
USA The following information relates to product regulation specific to the USA.
SARA (Superfund Amendments and Reauthorization Act)
Section 355 (extremely hazardous substances):
None of the ingredient is listed.
Section 313 (Specific toxic chemical listings):
7439-92-1 lead
TSCA (Toxic Substances Control Act):
All ingredients are listed.
California Proposition 65
Chemicals known to cause cancer:
WARNING: This product contains a chemical known to the State of California to cause cancer.
7439-92-1 lead
(Contd. on page 6)
USA
DR

Page 6/7

Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 07/25/2003

Reviewed on 07/14/2003

Trade name: 256GS Sn55Pb45, Sn60Pb40, Sn62Pb38, Sn63Pb37, Sn65Pb35
(Contd. of page 5)

25013-16-5 tert-butyl-4-methoxyphenol
7440-43-9 cadmium
7440-02-0 nickel
Chemicals known to cause reproductive toxicity:
WARNING: This product contains a chemical known to the State of California to cause birth defects and/or other
reproductive harm.
7439-92-1 lead
872-50-4 N-methyl-2-pyrrolidone
7440-43-9 cadmium
Carcinogenicity categories
EPA (Environmental Protection Agency)
7439-92-1 lead B2
IARC (International Agency for Research on Cancer)
7439-92-1 lead 2B
NTP (National Toxicology Program)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
CANADA: The following information relates to product regulation specific to Canada.
Workplace Hazardous Materials Identification (WHMIS):
This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products
Regulation (CPR) and the MSDS contains all of the information required by the CPR.
WHMIS Classification:
D2A
D2B
Components on Ingredient List for WHMIS:
Rosin, polymerized
lead
tin
EUROPEAN UNION
The following information relates to product regulation specific to the directives of the Euopean Union.
Risk phrases:
Harmful by inhalation and if swallowed.
Danger of cumulative effects.
May cause sensitisation by skin contact.
Possible risk of impaired fertility.
(Contd. on page 7)
USA

DR

Page 7/7

Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 07/25/2003

Reviewed on 07/14/2003

Trade name: 256GS Sn55Pb45, Sn60Pb40, Sn62Pb38, Sn63Pb37, Sn65Pb35
(Contd. of page 6)

Safety phrases:
Avoid exposure - obtain special instructions before use.
Keep locked up and out of the reach of children.
Avoid contact with skin.
Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point.
Wear suitable gloves.
In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
Special labeling of certain preparations:
Contains lead. Should not be used on surfaces liable to be chewed or sucked by children.

16 Other information
The information contained herein is based on data considered accurate and is offered solely for information,
consideration and investigation. Kester extends no warranties, makes no representations and
assumes no responsibilty as to the accuracy, completeness or suitability of this data for any purchaser's use. The
data on this Material Safety Data Sheet relates only to this product and does not relate to use with any other
material or in any process. All chemical products should be used only by, or under the direction of, technically
qualified personnel who are aware of the hazards involved and the necessity for reasonable care in handling.
Hazard communication regulations require that employees must be trained on how to use a Material Safety Data
Sheet as a source for hazard information.
Department issuing MSDS: Product Safety
Contact: Heather Holich, MSDS Coordinator

Tel. (847)699-5755
USA

DR

1 of 2

Quality Through People and Technology

Amerway Silver Solder Flux
Material Safety Data Sheet
Section 01
Information furnished by:

Date effective:
Emergency phone:
Chemtrec:
Product or trade name:
Product Use:
Person to contact:

Identification
Amerway, Inc.
3701 Beale Avenue
Altoona, PA 16601
1/01/08
1-814-944-0200
1-800-424-9300
Amerway Silver Solder Flux
Silver Soldering
Terry Buck

Section 02
Constituents
Chem
CAS
%Wt.
PEL/PPM
Zinc Chloride
7646-85-7
30-45
1 mg/m^3
Ammonium Chloride
12125-02-09
5-15
10.0 mg/m^3
Ammonium Biflouride 1341-49-7
2-7
2.5 mg/mg^3
Hydrochloric Acid
7647-01-0
3-6
5 ppm
All ingredients are reported in EPA and TSCA inventory.
Unlisted ingredients are considered non-toxic.
None of the materials in this product are listed in NTP, IARC, or OSHA as carcinogens.

TLV/PPM
1 mg/m^3
10.0 mg/m^3
2.5 mg/mg^3
5 ppm

Section 03
Melting Point
Boiling Point
Vapor Pressure
Vapor Density ( air is 1)
Solubility in Water
Appearance & Color
Specific Gravity
Odor
% Volatile
pH
Evaporation Rate :(nBuAc=1)

Physical Data
N/A
212 F
N/A
N/A
100 %
Clear Liquid
1.5
Acidic
65%
1.0
6

Section 04
Flash Point / Method Used
Flammable Limits
Extinguishing Media
Fire Fighting Equipment
Special Precautions

Fire and Explosion Hazard Data
None
None
N/A
Water or with non-flammable salts.
None

Section 05
Stability
Conditions to Avoid
Hazardous Polymerization
Incompatibility
Hazardous Decomposition Products

Reactivity Data
Stable
Inhalation of fumes.
Will not occur.
Alkalis
None known.

Section 06
Action to take for spills/leaks
Disposal method

Spill, Leak and Disposal Procedures
Dilute with water.
Dispose of per federal, state and local regulations.

2 of 2
Section 07
Eye
Skin Contact
Skin Absorption
Ingestion
Inhalation
Systemic & Other Effects
Section 08
Eyes
Skin
Ingestion
Inhalation
Note to Physician
Section 09
Ventilation
Respiratory Protection
Eye Protection
Skin Protection
Other
Section 10
Storage
Handling Information
Website by Precision Business Solutions

Health Hazard Data
Higher concentrations can cause eye irritations.
May cause skin irritation.
Will cause skin irritation.
Do not induce vomiting, give two glasses of milk or
water, contact a physician.
Remove to fresh air, contact a physician.
None known.
First Aid Procedures
Wash with water for 10 minutes, contact physician.
Wash with soap and water.
Do not induce vomiting, give two glasses of milk or water.
Contact a physician.
Remove to fresh air, contact a physician.
Salt solution of chlorine and fluorine.
Special Handling Information
Fume hood or mechanical ventilation must be provided to
maintain exposure levels below TLV’s.
Use NIOSH/OSHA approved respirator for dust and acid
fumes.
Wear safety goggles during use.
Wear rubber apron and gloves.
Follow NIOSH/OSHA health guidelines for chemical
hazards.
Special Precautions and Additional Information
Store in dry cool place.
When handling use proper safety procedures.
© Amerway.com

MATERIAL SAFETY DATA SHEET
PLEASE CAREFULLY READ AND UNDERSTAND THIS MATERIAL SAFETY DATA SHEET BEFORE USING THIS PRODUCT
May be used to comply with OSHA’s Hazards Communication Standard, 29 CFR 1910.1200. Standard must be consulted for specific requirements.

SECTION I (IDENTIFICATION)
Manufacturer/Supplier Name:

UNIWELD PRODUCTS, INC.
2850 Ravenswood Road
Fort Lauderdale, FL 33312

Emergency Phone No.:

Product Name(s):
Product Classification:

PROPANE ODORIZED
LIQUIFIED PETROLEUM GAS (PARAFFINIC HYDROCARBONS)

(954) 584-2000

SECTION II (HAZARDOUS INGREDIENTS/IDENTITY INFORMATION)
Important: Propane may contain various percentages of these hazardous components, depending on the source of supply.

EXPOSURE LIMIT (mg/m3)
INGREDIENT

% WEIGHT

CAS NO.

85-100

74-98-6

PROPYLENE

0-10

115-07-1

BUTANE & HEAVIER

0-2.5

106-97-8

ETHANE

0-5

74-84-0

ETHYL MERCAPTAN
(ODORANT)

<0.1

75-08-1

PROPANE

OSHA PEL/TWA

ACGIH TLV/TWA

1,000 PPM

800 PPM

800 PPM

SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS
Property

Value

Appearance and odor

Colorless gas, liquid under pressure. Mercaptan “rotten eggs” odor

Boiling point

-44 degrees F.

Evaporation rate (Butyl Acetate = 1)

<1 (diffuses readily)

Flash point

-156 degrees F.

Liquid to vapor expansion ratio

1:270

Molecular weight

44.096

Solubility in water

Slight

Specific gravity (liquid)

0.500 - 0.510 (Water = 1)

Specific gravity (vapor)

1.52 (Air = 1)

Vapor pressure (maximum)

208 PSIG @ 100 degrees F.

SECTION IV - FIRE AND EXPLOSION HAZARD DATA
Flammability limits

Ignition temperature
Extinguishing media

Special fire-fighting
procedures and precautions

Flammability limits by volume in air.
Lower 2.15 percent
Upper 9.6 percent
Auto ignition temperature is 940 degrees Fahrenheit.
Allow product to burn if source cannot be shut off safely.
Class B-C or A-B-C dry chemical or halon extinguishers can be used on small fires.
Apply water from a safe distance to cool containers, surrounding equipment, and structures.
Extremely flammable. Containers may explode if not sufficiently cooled with water spray.
Evacuate surrounding area of unprotected personnel and isolate. Do not enter confined fire space without full bunker gear
(helmet with face shield, bunker coats, gloves, and rubber boots) and a positive pressure NIOSH-approved self-contained
breathing apparatus.

SECTION V - REACTIVITY DATA
Stability and hazardous
polymerization
Conditions and materials
vapor accumulation.

This product is stable. Hazardous polymerization will not occur.
Avoid heat, sparks, flame, and contact with strong oxidizing agents. Avoid buildups of static electricity. Prevent to avoid

Hazardous
decomposition products

Carbon monoxide and unidentified organic products may be formed during combustion.

Purpose
Eye contact
Skin contact
Inhalation

The health effects are consistent with requirements of the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Direct contact with liquid propane can result in eye burns.
Direct contact with liquid propane can result in skin burns (frostbite).
This product is classified as a simple asphyxiant.
High vapor concentrations may produce a reversible central nervous system depression (anesthesia).
Higher concentrations may produce asphyxiation.
WARNING: DO NOT BREATHE FUMES!
Ingestion is not likely.
Eye or skin burns (frostbite) as noted previously.
Early to moderate central nervous system depression may be evidenced by giddiness, headache, dizziness, and nausea. In
extreme cases, unconsciousness may occur.
Asphyxiation may be noted by a sudden loss of consciousness. Death may quickly follow.
Caution is recommended for personnel with pre-existing central nervous system or chronic respiratory diseases.

SECTION VI - HEALTH HAZARD DATA

Ingestion
Signs and symptoms

Aggravated medical
conditions
Acute toxicity data
Carcinogenicity
Occupational exposure limits
Cardiac effects

Acute toxicity data is not applicable to this product.
This product is not classified as a carcinogen.
See the table in section 2
While there is no evidence that exposure to industrially acceptable levels of hydrocarbons have produced cardiac effects
in humans, animal studies have shown that inhalation of high vapor levels of the components of this product have produced
CONTINUED ON THE BACK

Effects of propylene

cardiac sensitization. Such sensitization may cause fatal changes in heart rhythms. This latter effect was shown to be
enhanced by hypoxia or the injection of adrenaline-like agents.
Laboratory animals exposed to high levels of propylene for prolonged periods of time showed evidence of effects in the liver,
kidneys, and nasal cavity.

SECTION VII - PRECAUTIONS FOR SAFE HANDLING & USE
Release, spill, or
leak procedures

Warning! Extremely flammable.

Eliminate sources of ignition.
Isolate hazard area and deny entry to unnecessary or unprotected personnel.
Stay upwind and keep out of low areas.
Notify local fire department.
Disperse vapor clouds with water spray.
Shut off source of leak only if it can be done safely.
Training
Train all personnel involved in handling propane in proper handling and operating procedures.
Document all training.
Handling and storing
Handle and store propane in accordance with NFPA 58 and local fire codes.
Keep containers away from heat sources or temperatures exceeding 130 degrees Fahrenheit.
Do not drop or roll any container.
Store and transport containers with relief valves in vapor space.
Keep all container valves closed when not in use.
Keep protective caps (if applicable) on containers when not in use.
DOT cylinders
Take these precautions when using DOT cylinders:
Periodically inspect and requalify DOT cylinders in accordance with DOT and NFPA 58 codes.
Store and use cylinders with valves off and the relief valves in the container vapor space.
Shut all valves and follow recommended procedures before exchanging cylinders.
Special precautions
Containers, even those that have been emptied, can contain explosive vapors.
Do not cut, drill, grind, weld or perform similar operations on or near containers.
Propane odorization
Warning! Any smell of odorant, even a faint one, may indicate a dangerous situation.
Ethyl mercaptan is the preferred warning agent for propane. Although ethyl mercaptan has excellent warning properties,
“It is recognized that no odorant will be completely effective as a warning agent in every circumstance” (NFPA 58 A-1-4.1,
1992 edition).
Instances in which odorants may lose their effectiveness include, but are not limited to the following:
Odor may fade due to chemical oxidation in improperly prepared new tanks and cylinders or from rust, air and water
in used containers that have been allowed to stand open to the atmosphere.
Odor may be absorbed and adsorbed by the walls of containers and distribution systems.
Odor in the gas escaping from underground leaks may be absorbed by certain types of soils.
Effectiveness of the odorant may be reduced by cold temperatures.
Other odors, such as from cooking or from a musty basement, may mask or cover up the mercaptan odor in propane.
Exposure to the mercaptan odor of propane for extended periods of time may affect a person’s ability to
detect the odorant.
Physical disabilities or the use of alcohol, tobacco, or drugs may decrease a person’s ability to detect the odorant.
WARNING: CALIFORNIA PROPOSITION 65: This product, when used for welding, soldering, brazing, cutting and other metal working or flame processes,
produces fumes, particulates, residues and/or other by-products which contain chemicals known to the State of California to cause cancer and birth defects
or other reproductive harm.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive
harm.

SECTION VIII - FIRE AND EXPLOSION HAZARDS
Flammability limits

Ignition temperature
Extinguishing media

Flammability limits by volume in air.
Lower 2.15 percent
Upper 9.6 percent
Auto ignition temperature is 940 degrees Fahrenheit.
Allow product to burn if source cannot be shut off safely.
Class B-C or A-B-C dry chemical or halon
extinguishers can be used on small fires.
Apply water from a safe distance to cool containers,
surrounding equipment, and structures.

Extremely flammable compressed gas.• Asphyxiant
in high concentrations. • Skin contact with liquid
causes burns similar to frostbite. • Ethyl mercaptan
used as a warning agent may not be entirely effective
in all situations. Read the warnings in section 7.
NFPA hazard Hazard ratings are in the following table
rating
Fire Hazard
Health hazard = 1
Health
Fire hazard = 4
Hazard
Reactivity = 0
Where:
0 = Least
3 = High
Reactivity
1 = Slight
4 = Extreme
2 = Moderate
Warning!

4

1

0

SECTION VIIII - EMERGENCY AND FIRST AID PROCEDURES
Purpose
Eye contact with liquid
Skin contact with liquid
Inhalation
Ingestion

Follow these procedures in case of personal injuries resulting from use of this product.
Flush eyes with water. Get medical attention.
Flush with water. If frostbite or burn occurs, get medical attention.
Remove victim to fresh air and provide oxygen if breathing is difficult.
Seek immediate medical attention if victim is not breathing. Give artificial respiration.
Not applicable to this product.

SECTION X - EMPLOYEE PROTECTION
Respiratory protection

Use a NIOSH-approved respirator as required when airborn exposure limits are exceeded.
In accord with 29 CFR 1910.134, use either an atmosphere supplying respirator or an air purifying respirator for
organic vapors.
WARNING: DO NOT BREATHE FUMES!
Protective clothing
Avoid liquid contact with eyes or skin.
Wear safety glasses or goggles as appropriate.
Wear protective clothing as appropriate.
Additional protective measures Use explosion-proof ventilation as required to control vapor concentrations.

SECTION XI - TRANSPORTATION REQUIREMENTS
DOT shipping name
DOT classification
Other DOT requirements

Liquefied Petroleum Gas
Division 2.1 (Flammable Gas)
UN 1075, Hazardous Materials Guide Number 115.

EPA/TSCA
EPA Hazard Classification

The components of this product are listed on the EPA/TSCA inventory of chemical substances.
This product is classified by 40 CFR 372 (SARA Section 313) as:

SECTION XII - OTHER REGULATORY CONTROLS

Acute Hazard

Chronic Hazard

XXX
Ozone-depleting substances
RCRA Information

State regulatory information

Fire Hazard

Pressure Hazard

XXX

XXX

Reactive Hazard

This product does not contain, nor was it directly manufactured with, any class I or class II ozone-depleting substances.
This product is not subject to 40CFR 268.30 ban on the disposal of hazardous wastes.
If this product becomes a waste material, it would be an ignitable hazardous waste, having a waste code number D0001.
Refer to latest EPA or state regulations regarding proper disposal. Under EPA-RCRA, containers are considered hazardous
unless depressurized to a pressure approaching atmospheric. Depressurize containers at a controlled rate to a flare.
The ingredients in this product are specifically listed by individual states; other product specific health and safety data in
other sections of the MSDS may also be applicable for state requirements.
Contact the appropriate agency in your state for details on your regulatory requirements.

Uniweld Products, Inc. believes this data to be accurate and to reflect qualified expert opinion regarding current research. Uniweld Products, Inc. cannot

make any expressed or implied warranty as to this information.

MSD50
Effective Date: January, 2008

Material Safety Data Sheet
Section 1
Product Name:
Revision #: 2.0

Product and Company Identification
BLOC-IT Heat Sink Paste
Date Prepared: May 23, 1991

Manufacturer:

Date Revised: June 14, 2004

Supplier/Importer:

LA-CO INDUSTRIES, Inc./Markal Co.
1201 Pratt Blvd.
Elk Grove Village, IL, USA 60007-5746
Information Telephone: 847-956-7600
Emergency Telephone: Call CHEMTREC
USA 800-424-9300
International (Call Collect) 1-703-527-3887
Chemical Formula: Mixture
CAS No.: Not Applicable. Derivation: Not Applicable.
Synonyms: Not Applicable.
General Use: Heat sink paste for protecting heat
sensitive areas when soldering, brazing or welding.

Section 2

Composition/Information on Ingredients

Ingredient

CAS No.

No Hazardous ingredients according to the U.S. OSHA Hazard Communication Standard 29
CFR 1910.1200, Canadian WHMIS regulations, British CHIP2 regulation 6, and Australian
Regulations for the Control of Workplace Hazardous Substances.
(For Section 2 footnotes: See Section 15)

Section 3

Hazards Identification

EMERGENCY OVERVIEW: None.
POTENTIAL HEALTH EFFECTS
Primary Exposure Routes: Not Applicable.
Acute Effects
Eyes: Not Applicable.
Skin: Not Applicable.
Ingestion: Not Applicable.
Inhalation: Not Applicable.
Chronic Effects
Eyes: Not Applicable.
Skin: Not Applicable.
Ingestion: Not Applicable.
Inhalation: Not Applicable.
Carcinogenicity: Not Applicable.
Target Organ Effects: Not Applicable.
Medical Conditions Aggravated by Long-Term Exposure: Not Determined.
Other Information: Not Applicable.

Page 1 of 5

%

Product Name:
Revision #: 2.0

BLOC-IT Heat Sink Paste
Date Prepared: May 23, 1991

Section 4

Date Revised: June 14, 2004

First Aid

Eye Contact: Flush with water.
Skin Contact: Rinse with water.
Ingestion: Not Applicable.
Inhalation: Not Applicable.
Other Information: Not Applicable.

Section 5

Fire Fighting Measures

Flash Point (method): Not Applicable.
Autoignition Temperature: Not Applicable.
LEL: Not Applicable. UEL: Not Applicable.
Flammability Classification: Not Applicable.
Extinguishing Media: Not Applicable.
Hazardous Combustion Products: Possibly carbon monoxide.
Unusual Fire or Explosion Hazards: Not Applicable.
Fire-Fighting Instructions/Equipment: Keep personnel removed and upwind of any fire. Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA).

Section 6

Accidental Release Measures

Use recommended personal protective equipment (see Section 8).
Spill: CAUTION: Spill area may be slippery. Scrape up bulk. Mop spill area with water.

Section 7

Handling and Storage

Handling Precautions: Use recommended personal protective equipment (see Section 8). Wash
thoroughly after handling.
Storage Requirements: Store away from incompatible chemicals (see Sec. 10). Store in a cool, dry
area.

Section 8

Exposure Controls/Personal Protection

Eye/Face Protection: Suitable for related activities where this product is used.
Skin/Hand Protection: Suitable for related activities where this product is used.
Respiratory Protection: Suitable for related activities where this product is used.
Other Equipment: Eye wash and safety shower. Suitable for related activities where this product is
used.
Engineering Controls: Suitable for related activities where this product is used.
Administrative Controls: Users of this product must be properly trained and qualified in its use.
Other Information: No food or beverage should be consumed in the work area. Wash thoroughly before
eating, drinking, or smoking.

Section 9

Physical and Chemical Properties

Appearance/Physical State: Light pink to beige paste.
Odor: Negligible.
Odor Threshold (ppm): Not Determined.
Specific Gravity (H2O = 1): 1.0 to 1.1
Page 2 of 5

Product Name:
Revision #: 2.0

BLOC-IT Heat Sink Paste
Date Prepared: May 23, 1991

Date Revised: June 14, 2004

Solubility - Water: Soluble
- Fat: Insoluble
Coefficient of Water/Oil Solubility: >>1
Partition Coefficient (n-octanol/water): <<1
pH: Neutral
Melting Point: Not Determined.
Boiling Point: 2120F/1000C
Vapor Pressure (mm Hg at 200C): Not Determined.
Vapor Density (Air = 1): Not Determined.
Evaporation Rate (n-BuAc=1): <1
V.O.C.: 0%(w/w), 0%(v/v), 0 lbs./gal.(U.S.), 0 kg/l
Flash Point (method): (see Section 5)
Autoignition Temperature: (see Section 5)
Flammability Classification: (see Section 5)
Unusual Fire or Explosion Hazards: (see Section 5)
Oxidizing Properties: Not Applicable.
Other Information: None.
Note: The physical data represented above are typical values and should not be construed as a
specification.

Section 10

Stability and Reactivity

Chemical Stability: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid: Not Applicable.
Chemicals to Avoid: Not Determined.
Hazardous Decomposition Products (non-thermal): Not Applicable.

Section 11

Toxicological Information

Sensitization to Product: Not Applicable.
Irritancy of Product: Not Applicable.
Reproductive Toxicity: Not Applicable.
Teratogenicity: Not Applicable.
Mutagenicity: Not Applicable.
Further hazard information, if applicable, may be found in Section 3. Toxicological information regarding
individual ingredients, if applicable, may be found in Section 2.

Section 12

Ecological Information

Mobility: Not Determined.
Degradability: Not Determined.
Accumulation: Not Determined.

Section 13

Ecotoxicity: Not Determined.
Other Adverse Effects: Not Determined.

Disposal Considerations

Dispose of in accordance with all applicable regulations.

Page 3 of 5

Product Name:
Revision #: 2.0

Section 14

BLOC-IT Heat Sink Paste
Date Prepared: May 23, 1991

Date Revised: June 14, 2004

Transport Information

D.O.T. (U.S.)
Proper Shipping Name: Not Regulated.
Hazard Class or Division: Not Regulated.
Hazard Label: Not Regulated.
I.D. Number: Not Regulated.
TDG (Canada): Not Regulated.
IATA: Not Regulated.
ICAO: Not Regulated.
IMO: Not Regulated.
Australian Code for the Transport of Dangerous Goods
Dangerous Goods Class and Subsidiary Risk: Not Regulated.

Section 15

Regulatory Information

Footnotes for Section 2:
1
2
3
4
5
6

Subject to the reporting requirements of SARA Title III, Section 313.
Appears on the California Safe Drinking Water and Toxic Enforcement Act (Prop. 65) Substances List.
Appears on the Massachusetts Substances List.
Appears on the New Jersey Right-To-Know Hazardous Substances List.
Appears on the Pennsylvania Hazardous Substances List.
Appears on the Canadian WHMIS Ingredient Disclosure List.

U.S.A.
OSHA Hazard Status: This product is not considered to be hazardous as defined by the U.S. OSHA
HCS (29 CFR 1910.1200).
EPA SARA sec. 311/312 Hazard Categories: Not Applicable.
Toxic Substances Control Act (TSCA): All ingredients contained in this product are listed on the U.S.
EPA TSCA Chemical Substance Inventory.
HMIS Rating: Health 0, Flammability 0, Reactivity 0
NFPA Rating: Health 0, Flammability 0, Reactivity 0
CANADA
WHMIS Status: This product is not considered to be hazardous as defined by Canadian WHMIS
Controlled Products Regulations.
WHMIS Rating: None.
WHMIS Risk Phrases: None.
WHMIS Precautionary Statements: None.
Domestic Substances List (DSL): All ingredients contained in this product are listed on the Canadian
EPA (CEPA) Domestic Substances List (DSL).
E.U.
European Inventory of Existing Chemical Substances (EINECS): All ingredients contained in this
product are listed on the European Inventory of Existing Chemical Substances (EINECS).
Categories of Danger (Labeling Information): None.
Risk (R) Phrases: None.
Safety (S) Phrases: Keep out of reach of children (S2
AUSTRALIA
Worksafe Australia Status: This product is not classified as hazardous according to criteria of
Worksafe Australia.
HAZCHEM Code: None allocated.
Poisons Schedule Number: None allocated.

Page 4 of 5

Product Name:
Revision #: 2.0

BLOC-IT Heat Sink Paste
Date Prepared: May 23, 1991

Date Revised: June 14, 2004

Further regulatory information regarding individual ingredients, if applicable, may be found in Section 2.
This product has been classified in accordance with the hazard criteria of the U.S. OSHA Hazard
Communication Standard, the Canadian WHMIS Controlled Products Regulations, the British CHIP2
regulation 6, and the Australian NMRCWHS. This MSDS contains the information required by the above
regulations and conforms to ANSI Z400.1-1993.

Section 16

Other Information

MSDS Prepared By: Director of Chemical Safety

The information contained herein is based on data available to us and is accurate and
reliable to the best of our knowledge and belief. However, LA-CO Industries, Inc. makes
no representations as to its completeness or accuracy. Information is supplied on
condition that persons receiving such information will make their own determination as
to its suitability for their purposes prior to use. In no event will LA-CO Industries, Inc. be
responsible for damages of any nature whatsoever resulting from the use of or reliance
upon the information contained herein.

Page 5 of 5

MATERIAL SAFETY DATA SHEET
S O S PRODUCTS COMPANY INC
4th and Railroad Streets
East Greenville, Pa.
18041
Phone (215-679-6262
(215)-679-6263
PAGE 1
----------------------------------------------------------------------------SECTION I - GENERAL INFORMATION
----------------------------------------------------------------------------Product Code:
PVCC
Revision Date:08/06/07
Identification:
PVC CEMENT MEDIUM BODY
----------------------------------------------------------------------------SECTION II - HAZARDOUS INGREDIENTS
----------------------------------------------------------------------------OSHA
ACG/H
RATING
INGREDIENT:
PEL
TLV
H-F-R
CAS. NO
----------------------------------------------------------------------------TETRAHYDROFURAN
200 PPM
200 PPM
2-3-1
109-99-9
*METHYL ETHYL KETONE
200 PPM
200 PPM
1-3-0
78-93-3
CYCLOHEXANONE
25 PPM
25 PPM
1-2-0
108-94-1
*ACETONE
750 PPM
750 PPM
1-3-0
67-64-1
----------------------------------------------------------------------------*SUBJECT TO REPORTING REQUIREMENTS OF SARA TITLE III SECTIION 313.
----------------------------------------------------------------------------Carcinogenicity:
This product is NOT considered to be a carcinogen by the
National Toxicology Program, the International Agency for
Research on Cancer, or the Occupational Safety and Health
Administration.
----------------------------------------------------------------------------SECTION III - PHYSICAL CHARACTERISTICS
----------------------------------------------------------------------------Boiling Point:
133 F
Specific Gravity: (Water = 1)
0.91
Vapor Pressure: (mm Hg) 182
Melting Point:
N/A
Vapor Density:
(Air = 1) 2.5
Evaporation Rate:
8
Solubility in Water: NIL
(Butyl Acetate = 1)
Odor and Appearance: COLORED LIQUID, ACETONE-LIKE ODOR
----------------------------------------------------------------------------SECTION IV - FIRE AND EXPLOSION HAZARD DATA
----------------------------------------------------------------------------Flash Point:
-4 F
LEL:
2%
Flammable Limits:
N/A
UEL:
13%
Extinguishing Media: DRY CHEMICAL OR CARBON DIOXIDE OR FOAM.
Special Fire Fighting Procedures: DIRECT EXTINGUISHER AT BASE OF FLAMES.
Unusual Fire and Explosion Hazards: VAPOR HEAVIER THAN AIR & MAY TRAVEL
ALONG FLOOR OR GROUND TO IGNITION SOURCES FROM USE AREA.
----------------------------------------------------------------------------SECTION V - REACTIVITY DATA
----------------------------------------------------------------------------This product is STABLE.
Conditions to avoid: KEEP IN CLOSED CONTAINERS, AWAY FROM SPARKS &/OR FLAME.
Incompatibility: STRONG OXIDIZERS.
Hazardous Decomposition: CARBON DIOXIDE, CARBON MONOXIDE, HYDROGEN CHLORIDE.
Hazardous Polymerization: WILL NOT OCCUR.

----------------------------------------------------------------------------SECTION VI - HEALTH HAZARD DATA
PAGE 2
----------------------------------------------------------------------------Routes of Entry:
Inhalation?
YES - PRIMARY
Skin?
YES - PRIMARY
Ingestion?
YES - SECONDARY
Health Hazards (Acute and Chronic):
BREATHING: EXCESSIVE INHALATION CAN CAUSE NASAL &
RESPIRATORY IRRITATION & CENTRAL NERVOUS SYSTEM DEFECTS.
SKIN: PROLONGED OR REPEATED CONTACT CAN CAUSE MODERATE
IRRITATION, BURNS IF NOT REMOVED. CHRONIC OVEREXPOSURE
HAS APPARANTLY BEEN FOUND TO CAUSE THE FOLLOWING EFFECTS
IN LAB ANIMALS: LIVER ABNORMALITIES, KIDNEY, LUNG, &
BRAIN DAMAGE.
Carcinogenicity:
NTP?
NO
IARC Monographs?
NO
OSHA Regulated?
NO
Signs and Symptoms of Exposure:
INHALATION: DIZZINESS, HEADACHE, NAUSEA.
SKIN: IRRITATION, DEFATTING.
EYES: IRRITATION, REDNESS.
Medical Conditions Generally Aggravated by Exposure: NO INFORMATION AVAILABLE.
Emergency and First Aid Procedures:
INHALATION: REMOVE TO FRESH AIR. SKIN: FLUSH WITH WATER
& REMOVE CONTAMINATED CLOTHING. EYES: FLUSH REPEATEDLY
WITH WATER.
----------------------------------------------------------------------------SECTION VII - HANDLING PRECAUTIONS
----------------------------------------------------------------------------Steps to be Taken if Material is Released or Spilled:
ELIMINATE IGNITION SOURCES, FLAMES, PILOT LIGHTS & TURN
OFF ELECTRIC MOTORS. ABSORB LIQUID ON RAGS OR PAPER
TOWELS & REMOVE TO OUTDOORS. VENTILATE AREA.
Waste Disposal Method: DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, LOCAL
REGULATIONS.
Precautions to be Taken in Handling and Storage:
STORE IN COOL AREA AWAY FROM PILOT LIGHTS &
IGNITION SOURCES.
Other Precautions: KEEP CONTAINER CLOSED WHEN NOT IN USE.
----------------------------------------------------------------------------SECTION VIII - CONTROL MEASURES
----------------------------------------------------------------------------Respiratory Protection:
USE NIOSH APPROVED RESPIRATOR IF TLV EZPOSUER LIMITS ARE
EXCEEDED.
Ventilation Required: LOCAL EXHAUST: OPEN DOORS & WINDOWS. USE ONLY IN
A WELL-VENTILATED AREA. USE MECHANICAL EXHAUST IF
NECESSARY TO MAINTAIN EXPOSURE BELOW TLV.
Protective Gloves: WEAR RUBBER GLOVES IF EXCESSIVE SKIN CONTACT MAY OCCUR.

Eye Protection:
WEAR EYE PROTECTION IF SPLASHING OF PRODUCT IS LIKELY.
Other Protective Equipment: NONE.
Work/Hygienic Practices: WASH THOROUGHLY AFTER HANDLING.
----------------------------------------------------------------------------The above information pertains to the product as it is currently formulated
and is based upon the information available at this time. Additions of
reducers or other additives to this product may substantially alter the
composition and subsequent hazards of the product. Since conditions of use
are outside of our control, we make no warranties, either expressed or
implied, and assume no liability in connection with any use of this
information.

Silicone Grease

IMS Company
Validation Date: January 13, 2012

Page 1 of 3

Material Safety Data Sheet

Section 1 - Manufacturer Information
Manufacturer/Distributor

IMS Company
10373 Stafford Road
Chagrin Falls, OH 44023-5296
WEB: http://www.imscompany.com

Emergency Phone #
800-424-9300
Prepared by
Safety Advisor
Prepared/Revised
February 28, 2007
Sales:
sales@imscompany.com

Trade Names ...........Silicone Grease
Part Numbers ...........100585
100586
100830

1 gallon can
5.3 ounce tube
2 ounce tube

Replaces AER1-G128-G
Replaces AER1-G053-T
Replaces STXX-SG2

Hazardous Material Information System
Health ................1
Flammability.............1
Reactivity ................. 0
Protection................. X
* Chronic (Accumulates)
0 Normal use Material
0 Will Not Burn
0 Stable
X = Consult the
1 Slight Hazard (temporary) 1 Possible to Burn
1 Unstable if Heated
MSDS and
2 Health Affected (lengthy) 2 Burns if Heated
2 Violent Chemical Change
your supervisor
3 Extreme Danger
3 Easily Burns
3 Shock and Heat Sensitive
for your special
4 Severe or Fatal
4 Very Easily Burns
4 May Explode
workplace need
NOTE The HMIS may not be enough hazard information for this chemical in all workplaces. The HMIS system
requires employee training about the system and about information in this MSDS.

Section 2 - Ingredients
Chemical/Common Name

CAS-Number

%

PEL-OSHA

Silica, Amorphous Fumed
Polydimethylsiloxane
Dimethyl Siloxane, hydro-terminated

7631-86-9
63148-62-9
70131-67-8

0.1 to 20
60 to 80
0.1 to 10

6 mg/m3

(1)
(2)

TLV-ACGIH
TWA 10 mg/m3 (2)

(1)

(1)

(1)

(1)

None Established
Total dust

Does this product contain carcinogens (NTP, IARC, or OSHA)? No

Section 3 - Health Data
HEALTH EFFECTS - (Acute and Chronic)
Ingestion

low ingestion hazard in normal use. Large amounts may cause digestive discomfort, but no known
injury.

Inhalation

No significant effects expected from a single short-term exposure.

Eye

Direct contact could cause temporary discomfort with mild redness and dryness similar to windburn.

Skin

No significant irritation expected from a single short-term exposure.

PRIMARY ROUTES OF ENTRY Inhalation, Skin
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
No known applicable information.
EMERGENCY FIRST AID PROCEDURES

IMS Company
Validation Date: January 13, 2012
Eye Contact

Silicone Grease

Page 2 of 3

Material Safety Data Sheet

Immediately flush thoroughly with water.

Skin Contact Wipe off and flush with water.
Inhalation

No first aid should be needed.

Ingestion

No first aid should be needed.

Section 4 - Chemical Data
Boiling Point (F)................................ > 95° F (35° C)
Vapor Pressure (PSIG) .................... NA
Vapor Density (Air=1) ....................... NA
Solubility in Water............................. NA

Specific Gravity (Water=1) ...................... 1.1
Percent Volatile by Weight (%)................NA
Evaporation Rate (Ether).........................NA
Viscosity ..................................................500,000 cSt

Appearance and Odor Information Viscous liquid (paste-like), translucent white, some odor

Section 5 - Physical Data
Flash Point (CC) ................................. > 214° F (101° C)

Flammable Limits ............... LEL = NA

UEL = NA

Extinguishing Media Water spray, water fog, carbon dioxide, dry chemical, foam.
Special Fire Fighting Procedures Self-contained breathing apparatus and protective clothing should be worn in
fighting fires involving chemicals. Determine the need to evacuate or isolate the area according to your local
emergency plan. Use water spray to keep exposed containers cool.
Unusual Fire and Explosion Hazards None known.
Incompatibility (Materials to Avoid) Oxidizing material can cause a reaction.
Hazardous Decomposition Products Silicon Dioxide, Carbon oxides, traces of incompletely burned carbon
products, formaldehyde.
NOTICE
This product contains methylpolysiloxanes, which when heated to temperatures above 300° F (150° C), in the
presence of air, can form formaldehyde vapors. Formaldehyde is a potential cancer hazard, a known skin and
respiratory sensitizer, eye and throat irritant, and an acute toxicant. Vapors irritate eyes, nose, and throat. Safe
handing conditions may be maintained by keeping vapor concentrations within the OSHA permissible exposure limit
for formaldehyde. (Note Product does not contain formaldehyde).
Will Hazardous Polymerization Occur? No
Conditions to Avoid for Polymerization NA
Is the Product Stable? Yes
Conditions to Avoid for Stability NA

Section 6 - Spill or Leak Procedures
Steps to be Taken in Case Material is Released or Spilled Small spill and general procedure; remove product
and use absorbent material to take care of any oil-like residues. Large and unusual conditions; determine whether to
evacuate or isolate the areas according to your local emergency plan. Observe all personal protective equipment
recommendations. For large spills, provide diking or other appropriate containment to keep material from spreading.
Clean up remaining materials as appropriate since silicone materials, even in small quantities, present a slip hazard.

IMS Company
Validation Date: January 13, 2012

Silicone Grease

Page 3 of 3

Material Safety Data Sheet

Final cleaning may require use of steam, solvents, or detergents. Dispose of saturated absorbent or cleaning
materials in a sealed container, or totally exposed to air, since spontaneous heating – combustion may occur.
Waste Disposal Methods Not classified as a hazardous waste. If uncontaminated, use as appropriate. If not
useable, mix with absorbent materials such dried clay or absorbent pads, or set out to harden in open air – may take
a long time, and send to landfill. Follow local, State and Federal disposal procedures.

Section 7 - Exposure Control Information
Ventilation No local exhaust should be needed. Mechanical (general) ventilation recommended.
Respiratory Protection None should be needed if not sprayed. If sprayed, use appropriated mist respirator.
Consult with your safety equipment supplier.
Protective Gloves Where prolonged or repeated contact with the spray mist or the deposited product is likely, the
use of impervious gloves (for example neoprene or nitrile) is indicated.
Other Protective Equipment If contact with the material in any manner is likely, eye protection is recommended.
Chemical Monogoggles or safety glasses with side shields and a face shield will provide protection in most
situations. Do not wear contact lenses.
Other Engineering Controls To determine exposure levels, monitoring should be performed
Work Practices Do not use in confined or closed space. Ventilation should maintain the concentration of the
product or its components below the TLV/PEL value.
Hygienic Practices Wash thoroughly before eating or smoking after using this or any chemical product. This
product transferred to a lighted cigarette will result in the hazardous decomposition products. It is good practice to
remove large amount of any chemical from the skin as soon as practical.

Section 8 - Special Precautions
Precautions to be Taken in Handling and Storage Avoid spreading onto red hot surfaces, which may cause
decomposition.
Maintenance Precautions Do not remove or deface label.
Additional Comments
CAUTION Intentional misuse of this chemical product, as with any industrial chemical, in contact with the
body can be harmful or fatal. This includes such things as deliberately breathing, placing in mouth,
swallowing, placing on skin, or any other body contact, or repeated, or continuous contact.
IMS provides this information in good faith, but makes no representation as to its comprehensiveness or its accuracy.
This document is offered as a guide to a trained person, for appropriate precautionary handling. Persons using the
product and receiving the information must exercise independent judgment in determining the appropriateness of the use
and the safety information for their particular purpose. IMS MAKES NO REPRESENTATIONS OR WARRANTIES,
EXPRESSED OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THIS INFORMATION OR TO THE PRODUCT.
ACCORDINGLY, IMS WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE ON
THIS INFORMATION.

MATERIAL SAFETY DATA SHEET
S O S PRODUCTS COMPANY INC
P. O. Box 47
East Greenville, Pa.
18041
Phone (215)-679-6262
(215)-679-6263

Product Code:

SECTION I
TFD

-

PAGE 1

GENERAL INFORMATION
Revision Date: 08/06/07

SECTION II - HAZARDOUS INGREDIENTS
This product is not classified as hazardous in accordance with OSHA 1910.1200
Carcinogenicity: This product is NOT considered to be a carcinogen by the
National Toxicology Program, the International Agency for Research on
Cancer, or the Occupational Safety and Health Administration.
SECTION III - PHYSICAL CHARACTERISTICS
Boiling Point: N/A
Specific Gravity: 1.55
Vapor Pressure: N/A
Melting Point:
N/A
Vapor Density: N/A
Evaporation Rate: N/A
N/A
Evaporation Rate:
N/A
Solubility in Water: NOT SOLUBLE
Odor and Appearance: WHITE PASTE WITH PLEASANT ODOR
SECTION IV
Flash Point: N/A
Flammable Limits:

N/A

Extinguishing Media:

-

FIRE AND EXPLOSION HAZARD DATA
LEL: N/A
UEL: N/A

DRY CHEMICAL, FOAM, CARBON DIOXIDE

Special Fire Fighting Procedures:
USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
Unusual Fire and Explosion Hazards:

TOXIC FUMES GIVEN OFF ABOVE 800 DEG F.

SECTION V - REACTIVITY DATA
This product is STABLE.
Conditions to avoid: DIRECT CONTACT WITH OPEN FLAME.
Incompatibility:
SODIUM POTASSIUM ALLOY
Hazardous Decomposition: FLUOROCARBON GASES PRESENT IN TEFLON DECOMPOSITION
Hazardous Polymerization WILL NOT OCCUR.

Routes of Entry:

SECTION VI - HEALTH HAZARD DATA
Inhalation?
NO
Skin?
YES - PRIMARY
Ingestion?
YES - SECONDARY

Health Hazards (Acute and Chronic):
Carcinogenicity:

NONE

NTP?
IARC Monographs?
OSHA Regulated?

Signs and Symptoms of Exposure:

NONE

NO
NO
NO

Medical Conditions Generally Aggravated by Exposure:

NONE KNOWN

Emergency and First Aid Procedures:
SKIN: WASH WITH SOAP & WATER THOROUGHLY.
EYES: FLUSH 15 MINUTES WITH WATER.
INGESTION: DO NOT INDUCE VOMITING. CALL PHYSICIAN.
SECTION VII - HANDLING PRECAUTIONS
Steps to be Taken if Material is Released or Spilled:
USE ABSORBENT MATERIAL & SWEEP UP.
Waste Disposal Method:
NON-HAZARDOUS LANDFILL.
REGULATIONS.

COMPLY WITH FEDERAL, STATE AND LOCAL

Precautions to be Taken in Handling and Storage:
Other Precautions:

NONE

KEEP AWAY FROM DIRECT CONTACT WITH SPARKS & OPEN FLAME.

SECTION VII - CONTROL MEASURES
Respiratory Protection: NONE REQUIRED FOR NORMAL USE.
Ventilation Required: NORMAL VENTILATION
Protective Gloves: WEAR RUBBER GLOVES
Eye Protection: WEAR SAFETY GOGGLES
Other Protective Equipment: NONE REQUIRED FOR NORMAL USE.
Work/Hygienic Practices: WASH THOROUGHLY WITH SOAP & WATER AFTER USING.

The above information pertains to the product as it is currently formulated
and is based upon the information available at this time. Additions of reducers
or other additives to this product may substantially alter the composition and
subsequent hazards of the product. Since conditions of use are outside of our
control, we make no warranties, either expressed or implied, and assume no
liability in connection with any use of this information.

MSDS No:
Issue Date:
Page:

OTH050E5
10 June 2005
1 of 4

MATERIAL SAFETY DATA SHEET
SECTION 1
PRODUCT AND COMPANY IDENTIFICATION
Trade Name:
OATEY PLUMBER’S PUTTY
Product Use:
Stainless fixture setting compound.
Formula:
See SECTION 2
Synonyms:
Putty.
Firm Name &
OATEY CO. 4700 West 160th Street P.O. Box 35906 Cleveland,
Mailing Address:
Ohio 44135, U.S.A.
http://www.oatey.com
Oatey Phone Number: (216) 267-7100 or (800) 321-9532
Emergency Phone
For Emergency First Aid call 1-303-623-5716 COLLECT. For
Numbers:
chemical transportation emergencies ONLY, call Chemtrec at
1-800-424-9300. Outside the US: 1-703-527-3887.
Prepared By:
Corporate Director – Safety and Environmental Compliance
Preparation Date:
June 10, 2005
SECTION 2
INGREDIENTS:
Limestone
Hydrocarbon oil
Talc
Clay

COMPOSITION/INFORMATION ON INGREDIENTS
%wt/wt:
CAS NUMBER: ACGIH TLV TWA: OSHA PEL TWA:
60 - 90% 1317-65-3
10 mg/M3
15 mg/M3
(Total dust)
10 - 30% 64742-52-5
5 mg/M3
5 mg/M3
1 - 5%
14807-96-6
2 mg/M3
2 mg/M3
1 – 5%
68953-58-2
10 mg/M3
10 mg/M3

OSHA Hazard Classification:

OTHER:
None
None
None
None

Not hazardous

SECTION 3
HAZARDS IDENTIFICATION
Emergency Overview:
White putty with a mild petroleum odor. May cause mechanical irritation of the eyes.
SECTION 4

FIRST AID MEASURES
CALL 1-303-623-5716 COLLECT
Skin:
Wash all exposed areas with soap and water.
Eyes:
As with most foreign materials, should eye contact occur, flush eyes
with water until foreign matter is removed. If irritation develops,
seek medical attention.
Inhalation: Not a likely route of entry.
Ingestion: DO NOT INDUCE VOMITING. Rinse mouth with water. Call a physician.
SECTION 5
FIRE FIGHTING MEASURES
Flashpoint / Method: Not applicable
Flammability:
LEL = Not determined, UEL = Not determined
Extinguishing
Use dry chemical, CO2, or foam to extinguish fire. Cool fire
Media:
exposed container with water. Water may be ineffective as an
extinguishing agent.
Special Fire
As appropriate for surrounding fire.
Fighting
Procedure:
Unusual Fire and
None
Explosion
Hazards:
Hazardous
Combustion will produce toxic and irritating vapors including
Decomposition
carbon monoxide and carbon dioxide.
Products:

MSDS No:
Issue Date:
Page:

OTH050E5
10 June 2005
2 of 4

SECTION 6
Spill or
Leak
Procedures:

ACCIDENTAL RELEASE MEASURES
Sweep up dried material and dispose of with ordinary trash.

SECTION 7
Handling:

HANDLING AND STORAGE
No special handling required.
Use good hygiene practices.
Store in a cool, dry area.
None.

Storage:
Other:
SECTION 8
Ventilation:
Respiratory
Protection:
Skin
Protection:
Eye
Protection:
Other:

Wash thoroughly after handling.

EXPOSURE CONTROLS/PERSONAL PROTECTION
Use with adequate ventilation.
If putty dries and becomes dusty, wear a dust respirator
during clean-up.
Gloves are not normally required.
Safety glasses with side shields are recommended.
Eye wash should be available.

SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point:
Not applicable
Melting Point:
Not applicable
Vapor Pressure:
Not determined
Vapor Density:
Not determined
Volatile Components: Not determined
Solubility In Water: Negligible.
pH:
Not applicable
Specific Gravity:
2.0 @ 20 Degrees C
Evaporation Rate:
Not applicable
Appearance:
White Putty
Odor:
Petroleum odor
Will Dissolve In:
Not determined
Material Is:
Putty
SECTION 10
STABILITY AND REACTIVITY
Stability:
Stable.
Conditions To Avoid: Avoid heat, flames and other sources of ignition.
Hazardous
Combustion will produce toxic and irritating vapors
Decomposition
including carbon monoxide and carbon dioxide.
Products:
Incompatibility/
Strong oxidizing agents.
Materials To Avoid:
Hazardous
Will not occur.
Polymerization:

MSDS No:
Issue Date:
Page:
SECTION 11
Inhalation:
Skin:
Eye:
Ingestion:
Chronic
Toxicity:
Toxicity Data:
Sensitization:
Carcinogenicity:
Mutagenicity:
Reproductive
Toxicity:
Medical
Conditions
Aggravated By
Exposure:
SECTION 12
VOC
Information:

OTH050E5
10 June 2005
3 of 4

TOXICOLOGICAL INFORMATION
Not a likely route of entry.
May cause mild irritation. Prolonged and repeated contact
may cause dermatitis.
Contact may cause irritation.
Swallowing may cause a laxative effect including cramps and
diarrhea.
Prolonged or repeated overexposure cause dermatitis.
Not available
None of the components are
None of the components are
carcinogen by NTP, IARC or
None of the components are
None of the components are

known to cause sensitization.
listed as a carcinogen or suspect
OSHA.
known to be mutagenic.
known to be toxic to reproduction.

None known.

ECOLOGICAL INFORMATION
No ecotoxicological information known.
This product has very low VOC level.

SECTION 13
DISPOSAL CONSIDERATIONS
Waste Disposal: Dispose in accordance with current local, state and federal
regulations.
RCRA Hazardous Waste Number:
Not a hazardous waste.
EPA Hazardous Waste ID Number: Not a hazardous waste.
EPA Hazard Waste Class: Not a hazardous waste.
SECTION 14
TRANSPORT INFORMATION
Less than 1 Liter (0.3 gal) Greater than 1 Liter (0.3 gal)
DOT
Proper Shipping Name:
Not regulated.
Not regulated.
Hazard Class/Packing Group: None
None
UN/NA Number:
None
None
Hazard Labels:
None
None
IMDG
Proper Shipping Name:
Not regulated
Hazard Class/Packing Group: None
UN Number:
None
Label:
None
2004 North American Emergency Response Guidebook Number: None

MSDS No:
Issue Date:
Page:

OTH050E5
10 June 2005
4 of 4

SECTION 15
REGULATORY INFORMATION
Hazard Category for Section
Not hazardous.
Section 302 Extremely
This product does not contain chemicals regulated
Hazardous Substances (TPQ):
under SARA Section 302.
Section 313 Toxic Chemicals: This product does not contain any chemicals regulated
under SARA Title III Section 313.
CERCLA 103 Reportable
This product does not contain any chemicals regulated
Quantity:
under CERCLA.
California Proposition 65:
This product does not contain any chemicals subject
To California Proposition 65 regulation.
TSCA Inventory:
All of the components of this product are listed on
the TSCA inventory.
Canadian WHIMS Classification:
Not a controlled product.
This product has been classified in accordance with
the hazard criteria of the Controlled Products
Regulations (CPR) and the MSDS contains all the
information required by the CPR.
SECTION 16
OTHER INFORMATION
NFPA and HMIS:
NFPA Hazard Signal: Health: 0
Flammability: 0
HMIS Hazard Signal: Health: 0
Flammability: 0

Reactivity: 0
Reactivity: 0

Special: None
PPE: A

Disclaimer:
The information herein has been compiled from sources believed to be reliable, upto-date, and is accurate to the best of our knowledge. However, Oatey cannot give
any guarantees regarding information from other sources, and expressly does not make
warranties, nor assumes any liability for its use.

MATERIAL SAFETY DATA SHEET
POWER O PRODUCTS
6 - HEALTH HAZARD DATA

1 - IDENTIFICATION
Manufacturer:
Address:
City, State, Zip:
Telephone:
24-Hour Emergency:
Date Prepared:

Ormco Corporation
1717 West Collins Avenue
Orange, CA 92867
1-800-854-1741
Chemtrec 1-800-424-9300
September 24, 2001

Routes of Entry:
Skin: None known
Eyes: May cause mechanical irritation and damage.
Inhalation: N/A
Ingestion: N/A
Carcinogenicity NTP: No
IARC Monographs: No
OSHA Regulated Carcinogen: No

2 - COMPOSITION INFORMATION
7 - EMERGENCY FIRST AID PROCEDURES
Hazardous Ingredients
This product contains no hazardous components as defined in the
OSHA Hazard Communication Standard ( 29 CFR 1910.1200 ).
Other Ingredients
Polyurethane elastomer

3 - PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point: N/D
Specific Gravity (H20 = 1): N/D
Vapor Pressure (mm Hg): N/D
Vapor Density (AIR = 1): N/D
Freezing/Melting Point: N/D
Solubility in Water: N/D
Appearance and Odor: Clear or colored elastomer material with no
odor

Skin: N/A
Eyes: N/A
Inhalation: N/A
Ingestion: N/A

8 - PRECAUTIONS FOR SAFE HANDLING & USE
Steps to be taken in case material is released or spilled: N/A
Waste Disposal Method: Dispose of properly in accordance with all
federal, state and local regulations.
Precautions to be taken in handling and storing: Store in a cool and
dry place away from heat and light.

9 - CONTROL MEASURES

Flash Point (Method Used): N/D
Flammable Limits: LEL: N/D UEL: N/D
Extinguishing Media: Chemical foam, CO2 or dry chemical
Special Fire Fighting Procedures: Wear a self-contained breathing
apparatus.
Unusual Fire and Explosion Hazards: N/A

Respiratory Protection: N/A
VENTILATION:
Local Exhaust: N/A
Mechanical (General): N/A
Protective Gloves: Not required
Eye Protection: Safety glasses recommended.
Work/Hygiene Practices: Handle in accordance with good personal
hygiene and safety practices. These practices include avoiding
unnecessary exposure to uncured material. Avoid contamination of
food.

5 - REACTIVITY DATA

10 - TRANSPORTATION INFORMATION

Stability: Stable if stored as directed.
Conditions to Avoid: Heat, light, aging and contamination
Incompatibility (Material to Avoid): N/A
Hazardous Decomposition Byproducts: Oxides of carbon
Hazardous Polymerization: Will not occur

Not DOT regulated.

4 - FIRE AND EXPLOSION HAZARD DATA

11 - SPECIAL INFORMATION
HMIS (Hazardous Material Identification System) Rating:
H0 F0 R0-Safety glasses
[HMIS Hazard Index: 4 – Severe Hazard; 3 – Serious Hazard;
2 – Moderate Hazard; 1 – Slight Hazard; 0 – Minimum Hazard]

Note: This MSDS was prepared in accordance with the requirements of the OSHA Hazard Communication Standard (29 CFR 1910.1200) and is
to be used only for this product. The information contained in this MSDS is, to the best of our knowledge, believed to be accurate.

NFPA Hazard Rating
Flammability

0
0

Health

MATERIAL SAFETY DATA SHEET
L-82E

0

Reactivity

0 = Minimum 1 = Light 2 = Moderate 3 = Serious 4 = Extreme

Section 1 - Product Identification
Bio-Chem Surface Technology

Trade name:

Gold Matrix All Purpose

5977 Transcanada Highway
Pointe-Claire, Quebec
H9R 1C1
Emergency: CANUTEC (613) 996-6666

Product name:
Order no.:
WHMIS Classification:
Controlled under WHMIS:

Industrial cleaner/degreaser
53-G 603, 53-G 607, 53-G608
Non-hazardous
No

Section 2 - Hazardous Ingredients
Ingredients

CAS Number

% by Weight

LD50RAT

LC50RAT

No hazardous substances to declare.

Section 3 - Physical / Chemical Characteristics
Physical state:
pH:
Specific gravity:
Evaporation rate:

Liquid
12
1.00 g/ml @ 20ºC
N/Av

Odour & appearance:Lavender, blue
Boiling point:
98ºC
Vapour pressure:
N/Av
VOC g/l:
N/Av

Odour threshold: None
Freezing point: 0ºC
Vapour density: N/Av
Water solubility: Soluble

Section 4 - Fire & Explosion Hazard
Flammability: No
Flashpoint: N/A

Conditions: None

Auto ignition temperature: N/A
Flammable limits (%): Upper: N/A Lower: N/A

Extinguishing media: None
Hazardous combustion products: None
Sensitivity to mechanical impact or static discharge: No

Section 5 - Reactivity Data
Chemical stability: Yes
Conditions: None
Incompatible substances: Do not mix with other chemicals.
Hazardous decomposition products: None
N/A - Not Applicable

Reactivity conditions: None

N/Av - Not Available
Page 1 of 2

MATERIAL SAFETY DATA SHEET
L-82E
Section 6 - Toxicological Data
Route of entry: Eye and skin contact, ingestion.
Acute exposure effects: None
Chronic exposure effects: None
Exposure limits (TLV/TWA): N/Av
Carcinogenicity
Mutagenicity
Reproductive toxicity
No
No
No
If yes to any of the above, specify:

Teratogenicity
No

Synergistic effects
No

Section 7 - Preventive Measures
Protective equipment:
Handling procedures:
Waste disposal methods:
Leak/spill procedures:
Storage requirements:
Engineering controls:
Handling equipment:
Special shipping information:

Gloves in case of prolonged contact.
Keep container tightly closed.
Dispose as per municipal, provincial and federal regulations.
Soak up with absorbent material. Rinse small amount with quantity of water. Neutralize.
Store below 50ºC and above 0ºC. Keep upright.
None
None

Section 8 - First Aid Measures
Skin contact:
Eye contact:
Inhalation:
Ingestion:
Other:

Wash off with water and soap. Apply cream.
Rinse eyes thoroughly with water. Consult a physician.
N/A
Do not induce vomitting. Rinse mouth with water and give plenty of water to drink.
Consult a physician.

Section 9 - Preparation of MSDS
Prepared by:
Telephone:
Date:

Division Manager WCB
(514) 733-3315
June 21th, 2007

This data is offered in good faith as typical values and not as a product specification. No warranty, either express or implied is hereby made. The
recommended industrial hygiene and safe handling procedures are believed to bee generally applicable. However, each user should review these
recommendations in the specific context of the intended use and determine whether they are appropriate.

N/A - Not Applicable

N/Av - Not Available
Page 2 of 2

Material Safety Data Sheet
Section 1. Product and Company Identification
Product Name

PROFESSIONAL LYSOL® BRAND
DISINFECTANT FOAM CLEANER
(AEROSOL)

Product Description

Aerosol disinfectant cleaner for multiple surfaces.

Manufacturer

Reckitt Benckiser North America, Inc.
Morris Corporate Center IV
399 Interpace Parkway (P.O. Box 225)
Parsippany, N.J. 07054-0225

Product Identifier

EPA Reg. No. 777-71-675

Item Number

36241-02775-09

MSDS#

Not available.

Validation Date

9/1/2005

Print Date

9/1/2005

In case of
Emergency:

Telephone: 800-677-9218
(Professional Products)

Transportation
Emergencies:

Chemtrec: 1-800-424-9300
(U.S. & Canada)
Outside the U.S & Canada
(North America), call:
703-527-3887

Formula Number

(794-103) F/F 376360

UPC Number

36241-02775 (24 oz.)

Section 2. Composition and Information on Ingredients
Name

CAS #

1) DIETHYLENE GLYCOL MONOBUTYL
ETHER
2) ISOBUTANE

% by Weight

Exposure Limits : TLV/PEL

112-34-5

5.6

Not available.

75-28-5

7.0

Not available.

Section 3. Hazards Identification
Emergency Overview

CAUTION: May cause eye irritation. Avoid contact with eyes and skin. Contents under pressure. Do not
use or store near heat or open flame. Do not puncture or incinerate container. Exposure to temperature
above 55º C (130ºF) or in sun or discarding can in fire or incinerator may cause bursting. KEEP OUT OF
REACH OF CHILDREN.

Section 4. First Aid Measures
Eye Contact

In case of eye contact, hold eyes open and IMMEDIATELY rinse eyes thoroughly with plenty of water.
Remove any contact lenses and continue rinsing for at least 15 minutes. If irritation persists, consult a
physician.

Skin Contact

In case of skin contact, wash skin thoroughly with soap and water. If irritation persists, consult a physician.

Inhalation

Remove to fresh air.

Ingestion

Rinse mouth with water. Contact a physician or poison control center if symptoms develop. NEVER give an
unconscious person anything to ingest.

Continued on Next Page

PROFESSIONAL LYSOL® BRAND
DISINFECTANT FOAM CLEANER
(AEROSOL)

Page Number: 2

Section 5. Fire and Explosion Data
Flammability

See Section 14 for any Shipping Classifications.

Flash Point

Not applicable. Flame extension less than 18 inches or 45 cm.

Explosive Limits in Air

Not available.

Products of Combustion

Not available.

Fire and Explosion Hazards

CONTENTS UNDER PRESSURE. Do not use or store near hear or open flame. Do not puncture or
incinerate. Do not expose to heat or store at temperatures above 55º C (130º F) as container may burst.

Fire Fighting Media
and Instructions

Use water spray, foam, dry chemical or carbon dioxide, as suitable for surrounding fire.

Special Fire Fighting
Instructions

Wear self-contained breathing apparatus and protective clothing appropriate for fighting a typical chemical
fire. Move containers away from fire if possible and safe to do so. Use water spray to cool fire exposed
containers. Provide shielding for venting, rupturing or bursting containers.

Section 6. Accidental Release Measures
Accidental Spill

Small spills of liquid can be wiped up with a wet paper towel and residue may be flushed to sink or sanitary
sewer with water.
Large spills of liquid from ruptured cans: Eliminate all sources of ignition and ventilate the area with
equipment rated for use in flammable environments. Spilled liquid should be diked, contained, collected and
stored in metal containers for later disposal according to local, state or federal regulations.

Section 7. Handling and Storage
Handling and Storage

CAUTION: May cause eye irritation. Avoid contact with eyes or skin. Contents under pressure. Do not
store near heat or open flame.
Store container in a cool, dry area inaccessible to small children. Do not reuse empty container. Replace
cap and discard in trash. Do not incinerate or puncture. KEEP OUT OF REACH OF CHILDREN.
It is a violation of federal law to use this product in a manner inconsistent with its labeling.

Section 8. Exposure Controls/Personal Protection
Ventilation Requirements

None required.

Eye Protection

None required when used as recommended. Appropriate eye protection should be worn if the possibility of
eye contact exists. Emergency responders should wear eye protection.

Skin Protection

For sensitive skin or prolonged use, wear rubber gloves. Emergency responders should wear impermeable
gloves.

Respiratory Protection

None required.

Other Protection

None required. Emergency responders should wear impermeable clothing and footwear when responding
to a situation where contact with the liquid is possible.

Work/Hygienic Practices

Washing with soap and water after use is recommended as good hygienic practice to prevent possible skin
irritation and / or eye irritation from the residue that may be left on the hands.

Continued on Next Page

Page Number: 3

PROFESSIONAL LYSOL® BRAND
DISINFECTANT FOAM CLEANER
(AEROSOL)
Section 9. Physical and Chemical Properties
Description

Aerosol container. White foam when sprayed.

Odor

Not available.

pH

12.35 [Basic.]

Color

White foam when sprayed as an aerosol.

Boiling/Condensation Point

Not available.

Specific Gravity

1.007-1.036

Vapor Pressure

34-40 PSIG @ 70°F.

Vapor Density

>1 (concentrate)

Viscosity

Not available.

Solubility

Miscible

Physical Chemical Comments Not available.

Section 10. Stability and Reactivity Data
Chemical Stability

The product is stable.

Conditions of Instability

Temperatures above 130° F (55° C) which may cause aerosol container to rupture.

Incompatibility with Various
Substances

Oxidizing agents and acids.

Hazardous Decomposition
Products

Oxides of nitrogen and/or carbon and other unidentified organic compounds may be formed during thermal
decomposition.

Hazardous Polymerization

Will not occur.

Section 11. Toxicological Information

Exposure effects
Eye Contact

May cause eye irritation. Avoid contact with eyes.

Skin Contact

May cause skin irritation. Avoid skin contact.

Inhalation

None expected.

Ingestion

None expected.

Carcinogenicity

Not listed as carcinogenic by OSHA, NTP or IARC.

Section 12. Ecological Information
Ecotoxicity

Not available.

Continued on Next Page

Page Number: 4

PROFESSIONAL LYSOL® BRAND
DISINFECTANT FOAM CLEANER
(AEROSOL)
Section 13. Disposal Considerations
Waste Disposal

Dispose of in accordance with local, state and federal regulations. Container Disposal: Do not reuse empty
container. Replace cap and discard in trash.

Section 14. Transport Information
DOT Classification

ORM-D

Proper Shipping Name

Consumer Commodity

DOT Identification Number

Not applicable

Packing Group

Not applicable

Maritime Transportation

Not applicable.

Hazardous Substances
Reportable Quantity

Not applicable.

Special Provisions for
Transport

ORM-D: For US Domestic Shipments Only

TDG Classification

Consumer Commodity - Transborder Consignment

ADR Classification

Not applicable.

IMDG Classification

UN1950 - Aerosols, class 2.2 - Limited Quantity

IATA Classification

Consumer Commodity, 9 ID8000

Section 15. Regulatory Information
Federal and State
Regulations

SARA Title III, Section 313 Toxic Chemical Notification & Release Reporting:
1) DIETHYLENE GLYCOL MONOBUTYL ETHER

CAS #: 112-34-5

5.6

%

California Proposition 65: This product contains the following ingredients which require a warning under the Safe
Drinking Water & Toxic Enforcement Act:
None

Other Classifications

New Jersey Right-To-Know
Regulation:

WHMIS (Canada)

Not a WHMIS controlled product.

NEW JERSEY WORKER AND COMMUNITY RIGHT TO KNOW ACT: This EPA Registered Product is exempt from the labeling
requirements of the above act. N.J.A.C. 8:59-5.5 #1.

Section 16. Other Information

HMIS (U.S.A.)

Health Hazard
Fire Hazard
Reactivity
Personal Protection

1
2
0
B

Continued on Next Page

1
Health

1

0

Reactivity
Specific hazard

NFPA Aerosol Level
Validated by Product Safety on 9/1/2005.

Fire Hazard

National Fire Protection
Association (U.S.A.)

Printed 9/1/2005.

1, per NFPA 30B

PROFESSIONAL LYSOL® BRAND
DISINFECTANT FOAM CLEANER
(AEROSOL)

Page Number: 5

Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee
that these are the only hazards that exist.

MATERIAL SAFETY DATA SHEET
Product Name: PINE CLEANER & DEODORANT

Product No. 094.00

SAVIN PRODUCTS COMPANY, INC.
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: PINE CLEANER & DEODORANT
Emergency phone: Chemtrec: 800-424-9300
Company:

Product Information: 781-961-2744

SAVIN PRODUCTS COMPANY, INC.
214 HIGH STREET
RANDOLPH, MA 02368

Date Prepared: 04-23-04

Supersedes: 01-15-02

Prepared by: KJS

2. COMPOSITION/INFORMATION ON INGREDIENTS
Component
1. Nonylphenol Ethoxylate

CAS No.
9016-45-9

Exposure Limits
N/A

Typical
% by Weight
1-5

3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
CAUTION: May causes eye irritation. May cause skin irritation with prolonged contact. Harmful if swallowed. Avoid contact with
eyes, skin and clothing. Wash thoroughly after handling. Do not take internally.
EFFECTS of OVEREXPOSURE
CARCINOGENICITY:
NTP: No
IARC: No
OSHA: No
EYES: May cause severe eye irritation.
SKIN: Repeated or prolonged contact may cause skin irritation.
INHALATION: Mist may cause irritation to mucous membranes and respiratory tract.
INGESTION: May result in gastric disturbances.
CHRONIC EFFECTS and MEDICAL CONDITIONS: The effects of long-term, low-level exposures to this product have not been
determined. Safe handling of this material on a long-term basis should emphasize the avoidance of all effects from repetitive acute
exposure. This product may aggravate existing eye, skin and respiratory conditions.
4. FIRST AID MEASURES
EYES: Flush with copious amounts of water for at least 15 minutes, lifting upper and lower lids occasionally. Get immediate medical
attention.
SKIN: Immediately flush with water. Remove contaminated clothing. Launder contaminated clothing before reuse.
INHALATION: Remove to fresh air. If breathing is difficult, oxygen may be given, preferably with a physician’s advice. Get medical
attention.
INGESTION: If swallowed, give several glasses of water. Do not induce vomiting. If vomiting does occur, give fluids again and keep
head below hips to help prevent aspiration. Do not give anything by mouth to an unconscious person. Get immediate medical
attention.
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES:
Flash Point: >200 F
Test: Tag Closed Cup (Method D-56)
Explosive Limits:
LEL: N/A
UEL: N/A
EXTINGUISHING MEDIA: Use water spray, dry chemical, CO2, or alcohol foam.
SPECIAL PROCEDURES AND UNUSUAL HAZARDS: Combustion may produce noxious and irritating gases which will require
fresh air source in fire fighting.
FIREFIGHTING INSTRUCTIONS: Firefighters should wear NIOSH approved, positive pressure, self-contained breathing apparatus
and full protective clothing when appropriate.

Page 1 of 3

MATERIAL SAFETY DATA SHEET
Product Name: PINE CLEANER & DEODORANT

Product No. 094.00

6. ACCIDENTAL RELEASE MEASURES
SMALL SPILLS: Soak up small spills with inert solids. Use suitable disposal container.
LARGE SPILLS: Limit access to area. Dike and contain spill with inert material (sand, earth, etc.) and transfer the liquid and solid
separately to containers for recovery or disposal. Keep spill out of sewers and open bodies of water. CAUTION: Floor may become
slippery.
7. HANDLING AND STORAGE
Handle according to good manufacturing and warehousing practices. Keep containers tightly closed when not in use. Use good
personal hygiene practices. Wash hand before eating, drinking, smoking or using toilet facilities. Promptly remove soiled clothing and
wash thoroughly before reuse. Store in tightly closed containers away from heat, sparks, open flame or strong oxidizing agents.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
EYE PROTECTION: Avoid splashing. Wear chemical-resistant safety goggles if necessary. Contact lenses must not be worn.
PROTECTIVE GLOVES: Depending on conditions of use, protective gloves, apron, boots, head and face protection should be worn.
This equipment should be cleaned thoroughly after each use.
RESPIRATORY PROTECTION: No occupational exposure standards have been developed for this material. Where exposure through
inhalation may occur from use, NIOSH/MSHA approved respiratory protection equipment is recommended.
VENTILATION: Either local exhaust or general room ventilation is usually adequate.
OTHER PROTECTIVE EQUIPMENT: Emergency eye wash fountains and safety showers should be available in the immediate
vicinity of any potential exposure.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Clear, green, thin, foamy liquid.
BOILING POINT: approx. >212F >100C @ 1ATM
FREEZE/MELT POINT: approx. 0C
VAPOR PRESSURE (mm): ca water
VAPOR DENSITY (air=1): ca water
EVAPORATION RATE: approx. water
VOLATILE CONTENT: 97%
SOLUBILITY IN WATER: Complete.
SPECIFIC GRAVITY: 1.01 @ 20C
DENSITY: 8.4 lb./gal. @ 20C
pH(as is): 7.0
ODOR: Pine
ODOR THRESHOLD (ppm): Not determined.
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY (CONDITIONS TO AVOID): Stable.
INCOMPATIBILITY: Strong acids, strong oxidizers and excessive heat.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, Carbon Dioxide, Ammonia, Nitrous oxides and other toxic
gases.
HAZARDOUS POLYMERIZATION: None
11. TOXICOLOGICAL INFORMATION
No LD50 or LC50 found for oral, dermal or inhalation routes of administration.
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL/CHEMICAL FATE INFORMATION: Not available.
13. DISPOSAL CONSIDERATIONS
RCRA: This product, if disposed as shipped, is not considered a hazardous waste as specified in 40 CFR 261.
Dispose in accordance with all applicable federal, state and local regulations.

Page 2 of 3

MATERIAL SAFETY DATA SHEET
Product Name: PINE CLEANER & DEODORANT

Product No. 094.00

14. TRANSPORT INFORMATION
SHIPPING NAME:
HAZARD CLASS:
ID #:
PACKING GROUP:
LABEL:

Compound, Cleaning, Liquid
Not regulated as HAZMAT.
N/A
N/A
N/A

15. REGULATORY INFORMATION
This material does not contain nor was it manufactured using ozone-depleting chemicals.
U.S. FEDERAL REGULATIONS:
TSCA STATUS: All ingredients on Toxic Substance Control Act Inventory.
CERCLA REPORTABLE QUANTITY:

N/A

SARA TITLE III:
Section 302 Extremely Hazardous Substances:
Section 311/312 Hazardous Categories:
Section 313 Toxic Chemicals:

None.
Immediate (Acute)
None.

RCRA STATUS: Based on chemical composition and pH (40 CFR Sec. 261.22), this material is not classified as a hazardous waste if
disposed as shipped.
16. OTHER INFORMATION
All label precautions must be observed when handling, storing and transporting empty containers due to product residues. Do not
reuse this container unless it is professionally cleaned and reconditioned.
REFERENCES:
•
U.S. Dept. of Health and Human Services, NIOSH: Registry of Toxic Effects of Chemical Substances, 1985-86 Editions.
•
Sax, N. Irving and Lewis, R.J.: Dangerous Properties of Industrial Materials, 7th Edition, Van Nostrand Reinhold Co., 1989.
•
Lewis, R.J.: Hawley’s Condensed Chemical Dictionary,12th Edition, Van Nostrand Reinhold Co., 1993.
•
U.S. Dept. of Transportation, U.S. Coast Guard: CHRIS Hazardous Chemical Data, 1982.
•
U.S. Dept. of Labor, OSHA: Air Contaminants - Permissible Exposure Limits, 1989.
•
National Fire Protection Association (NFPA): Fire Protection Guide on Hazardous Materials (NFPA 325M/49/491M/704), 9th
Edition, 1986.
•
National Fire Protection Association (NFPA): Hazardous Materials Response Handbook, Henry, M.F., Editor, 1989.
•
Merck & Co., Inc.: The Merck Index, 11th Edition, 1989.
Information herein is given in good faith as authoritative and valid; no warranty, express or implied can be made.

Page 3 of 3

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NuGenTec
Glass Cleaner - Windex(r) type
PRD Number: GPG202

Page 1 of 5
May 29, 2007

MATERIAL SAFETY DATA SHEET
1.

PRODUCT IDENTIFICATION AND USE
Product Identification
Product Name:
Glass and Window Cleaner - Windex(r) type
Product Number:
GPG202
Synonyms:
Window and Glass Cleaner
CAS Number:
Blend
Company Identification
NuGeneration Technologies, LLC
100 Professional Center Drive suite 101
Rohnert Park, CA
94928
USA
www.nugentec.com
(707) 820-4080
(For product information)
1-800-424-9300 or 1-202-483-7616 (For emergencies CHEMTREC)
SPECIAL NOTES:

2.

Non-streaking Fast drying window cleaner.

HAZARDOUS INGREDIENTS
Chemical Name
------------SEC-PROPYL ALCOHOL
BALANCE NON-HAZARDOUS INGREDIENTS

Amount
-------< 10.0 %
> 90.0 %

CAS Number
---------67-63-0
N/A

COMPOSITION COMMENT:
This Product Meets FDA/USDA requirements for cleaning in the food
processing industry. This product is formulated with NON-Hazardous
ingredients only.
EXPOSURE GUIDELINES:
Canadian Disclosure List

3.

No Information Available.
SEC-PROPYL ALCOHOL

(67-63-0)

PHYSICAL DATA
FORM ...............................:
COLOR ..............................:
ODOR ...............................:
BOILING POINT ......................:
SOLUBILITY IN WATER ................:
SPECIFIC GRAVITY ...................:
BULK DENSITY .......................:
MELTING/FREEZING POINT .............:
PH .................................:
% VOLATILES ........................:
VOLATILE ORGANIC COMPOUNDS (VOC) ...:

Liquid
Colorless
Faint ether-like odor
>212 F
Complete
0.996 (Water = 1)
8.31
32 F
10.5
6 %
<60 g/l

NuGenTec
Glass Cleaner - Windex(r) type
PRD Number: GPG202

Page 2 of 5
May 29, 2007

INHALATION:
No hazards expected in normal industrial use at room temperature.
INGESTION:
Ingestion is not considered a potential route of exposure.
CARCINOGENICITY INFORMATION:
No known cancer hazards.
MISCELLANEOUS:
Slippery, can cause falls if walked on.

4.

FIRE AND EXPLOSION DATA
FLAMMABLE PROPERTIES
COC Flash Point: N/A
Autoignition Temperature:
FLAMMABLE LIMITS IN AIR
EXTINGUISHING MEDIA:

N/A
LEL:

N/A

UEL:

N/A

Carbon dioxide, foam, or dry powder.

FIRE & EXPLOSION HAZARDS:
High concentrations of vapors may burn in a fire.
FIRE FIGHTING INSTRUCTIONS:
Contaminated extinguishing water must be disposed of in accordance with
applicable regulations.

5.

REACTIVITY DATA
STABILITY:
Stable.
POLYMERIZATION:
Hazardous polymerization will not occur.
INCOMPATIBILITY WITH OTHER MATERIALS:
None known.
DECOMPOSITION:
Decomposition will not occur if handled and stored properly.
CONDITIONS TO AVOID:
This material is safe under normal storage and handling conditions.

NuGenTec
Glass Cleaner - Windex(r) type
PRD Number: GPG202

6.

Page 3 of 5
May 29, 2007

TOXICOLOGICAL PROPERTIES
EYE:
Contact may cause eye irritation.
eye tissue.

Not known to cause permanent injury to

SKIN:
Prolonged or repeated contact may cause skin irritation.
INHALATION:
No hazards expected in normal industrial use at room temperature.
INGESTION:
Ingestion is not considered a potential route of exposure.
CARCINOGENICITY INFORMATION:
No known cancer hazards.
MISCELLANEOUS:
Slippery, can cause falls if walked on.
EYE EFFECTS:
Contact may cause eye irritation.
SKIN EFFECTS:
Contact may cause slight skin irritation.
ACUTE ORAL EFFECTS:
No know hazards in normal industrial use.
ACUTE INHALATION EFFECTS:
No know hazards in normal industrial use.

7.

PREVENTITIVE MEASURES
RECOMMENDED STORAGE TEMPERATURE
Minimum: 4.4 C
(39.9 F)
Maximum: 48.9 C
(120.0 F)
HANDLING (PERSONNEL):
Avoid contact with eyes, skin, and clothing.
HANDLING (PHYSICAL ASPECTS):
Keep container closed to avoid contamination.
STORAGE PRECAUTIONS:
Keep container closed when not in use.
pallets high.

Do not stack drums more than three

NuGenTec
Glass Cleaner - Windex(r) type
PRD Number: GPG202

Page 4 of 5
May 29, 2007

ENGINEERING CONTROLS:
Good general ventilation should be sufficient to control airborne levels.
EYE / FACE PROTECTION REQUIREMENTS:
When splashing of the material may occur, chemical goggles and a face
shield are recommended.
SKIN PROTECTION REQUIREMENTS:
For brief contact, normal work attire should be sufficient.
thoroughly after handling.

Wash hands

RESPIRATORY PROTECTION REQUIREMENTS:
Under normal use conditions, with adequate ventilation, no special
handling equipment is required.
SAFEGUARDS (PERSONNEL):
Protect skin and eyes from exposure.
INITIAL CONTAINMENT:
Floor may become slippery. Wash area to prevent slipping. Contain
spilled material. Treat or dispose of waste material in accordance with
all local, state/provincial, and national requirements.
LARGE SPILLS PROCEDURE:
Flush spill area with water to wastewater treatment system. Treat or
dispose of waste material in accordance with all local, state/provincial,
and national requirements.
SMALL SPILLS PROCEDURE:
Floor may become slippery. Wash with water. Treat or dispose of waste
material in accordance with all local, state/provincial, and national
requirements.
WASTE DISPOSAL:
Uncleaned empty containers should be disposed of in the same manner as the
contents. Treat or dispose of waste material in accordance with all
local, state/provincial, and national requirements.
CONTAINER DISPOSAL:

8.

Clean out containers prior to disposal.

FIRST AID MEASURES
EYE CONTACT FIRST AID:
Hold eyelids apart and flush eyes with plenty of water for at least 15
minutes. Get medical attention if irritation develops or persists.
SKIN CONTACT FIRST AID:
Flush skin with plenty of water.
develops or persists.

Get medical attention if irritation

NuGenTec
Glass Cleaner - Windex(r) type
PRD Number: GPG202

Page 5 of 5
May 29, 2007

INHALATION FIRST AID:
Not an expected route of exposure.
Remove from area of exposure. Seek immediate medical attention if
respiratory irritation or distress continues.
INGESTION FIRST AID:
Ingestion is not considered a potential route of exposure.
get medical attention immediately.

If ingested

NOTES TO PHYSICIAN:
Treat patient symptomatically.

9.

PREPARATION DATE OF MSDS
Prepared By.......:
Approval Date.....:
Supersedes Date...:
PRD Number........:

Donato Polignone
May 29, 2007
August 30, 2001
GPG202 (Official Copy)

**********************************************************************
This information is furnished without warranty, expressed or implied,
except that it is accurate to the best knowledge of NuGeneration
Technologies, LLC. The data on this sheet are related only to the
specific material designated herein. NuGeneration Technologies, LLC
assumes no legal responsibility for use or reliance upon these data.
**********************************************************************
END OF MSDS
**********************************************************************

PRODUCT DATA SHEET

Tile & Grout Cleaner
Ready to Use Cleaner For
■ Sanded Grout
■ Non-sanded Grout
■ Ceramic Tile
■ Quarry Tile
■ Glazed Ceramic
■ Honed Marble
■ Honed Limestone
■ Honed Travertine
Special Features
■ Non Acid
■ Removes Mildew
■ Environmentally Safe

■ Mortar
■ Porcelain Tile
■ Tumbled Marble
■ Granite

■ Non Bleach

■ Pleasant Odor

■ Fast Acting

■ User Friendly

PRODUCT DE SCRIPTION

KEEP OUT OF REACH OF CHILDREN. Tile & Grout Cleaner is a non abrasive, non acidic cleaner designed for use on all grout and ceramic tiles.
Strong enough to remove difficult stains, soap scum, dirt, water deposits,
mildew and mold, yet is gentle enough for regular use. Tile & Grout Cleaner
is easy to use and will not harm sanded and non sanded grout as many
household products can. Environmentally friendly Tile & Grout Cleaner will
not harm tile, chrome, glass, Formica or Corian (NOT FOR USE ON POLISHED MARBLE, LIMESTONE OR TRAVERTINE)
Sample Testing
Due to the differences of each substrate, several inconspicuous test patches should be completed to assure maximum performance. User must
determine suitability of the product for their intended use.
Protect Neighboring Surfaces
Always protect neighboring surfaces including wood, carpet, metal, landscaping and other non masonry surfaces.
APPLIC ATION INSTRUCTIONS

Read entire label and PDS/MSDS before using.
Spray Tile & Grout Cleaner onto soiled surface and allow to dwell for several minutes. Wipe clean with a clean scrub pad, brush, sponge or cloth. Do
not allow Tile & Grout Cleaner to dry on the surface. Rinse if necessary.
Heavy soiled surfaces and more porous surfaces may require scrubbing.
Use the appropriate brush for the surface being cleaned. Grout can be
cleaned with a small nylon brush. To remove heavy build up of mold or
mildew use H2O Strip as directed first. Not for use on polished, marble,
travertine or limestone.
Heavy Duty Cleaning: Use Phosphoric Acid Cleaner , GCFR or Liquid
Poultice as directed.
Light Cleaning: Use Mira Clean #1, Porcelain & Ceramic Tile Cleaner, Mira
Soap, Grout Cleaner, or Counter Kleen as directed.
Water, Stain & Slip Protection
To protect cleaned area from future soiling and staining and increase static
coefficient of friction, we recommend applying the appropriate Miracle
Penetrating Sealer/Impregnator.

6.11.2007

Color and Gloss Enhancement
For added color with “Textured and Non polished” surfaces, 511 Seal &
Enhance may be used. For porous type “Paver”, Stone Polish, MiraPolish,
Granite Brite, 511 Seal & Enhance, Mira Dust, Marble Conditioner or Tile
Brite may be used as directed.

www.miraclesealants.com

Mold, Mildew and Bacteria Sanitation
For best results in killing mold, mildew, bacteria and other micro organisms,
use Miracle Disinfectant or Miracle Wipes as directed.
Coverage
Coverage will vary depending on density, porosity, texture. surface absorption, weather, time solution left on surface and application methods. Used
as directed, Tile & Grout Cleaner will clean approximately 4,000 square feet
per gallon (363 s.m. per 3.785 liters) and 250 square feet per 8 ounce bottle (22 s.m. per .16 liters).
MAINTENANCE

For ongoing maintenance instructions please refer to Miracle Sealants Care
Guide. Refer to the Miracle Sealants Product Recommendation Chart for
specific product recommendations.
Storage
Store Tile & Grout Cleaner in the original upright container, properly sealed
and unmixed. Stored at 770 F (400 C), Tile & Grout Cleaner will have a shelf
life of 12 months. Do not allow to freeze.
Technical Support
For additional technical support, contact Miracle Sealants Company at
1-800-350-1901 or 626-814-8988 ext. 3013
Office Hours
Monday - Friday from 8:30 am - 5:00 pm PT.
1-626-443-6433 or 1-800-350-1901 • Fax: 1-626-443-1435
website: www.miraclesealants.com
Product Damaged During Transportation
If product is damaged during transportation contact
Info Trac @ 1-800-535-5053
Additional Products
Miracle Sealants Company offers a complete line of water & stain repellents, sealers, cleaner, polishing compounds, diamond abrasives, machinery and accessories for the tile, stone, concrete, metal, fabric and carpet
professional or do-it yourself specialist.
Caution
Store in cool area. Only use this product in well ventilated areas. Good ventilation means that fresh air is flowing in such a way to feel a slight breeze.
Continue to ventilate until odors are completely eliminated. Avoid contact
with skin. Chemical resistant gloves should be worn at all times. Keep small
children and pets out of area until product or surface has thoroughly dried.
Refer to the MSDS for additional information.
Warranty
Instructions are a condensed guide and should not be considered complete. In the event of failure, the only obligation of Miracle Sealants
Company shall be to replace such products proven to be defective. Before
using, user shall determine the suitability of the product for their intended
use. User assumes all risks and liability whatsoever in connection therein.
Neither seller nor manufacturer shall be liable for any injury or inability to
use this product.

MATERIAL SAFETY DATA SHEET

Tile & Grout Cleaner
Osha’s Hazard Communication Standard
U.S. Department Of Labor
29 CFR 1910.1200
OMB No. 1218-0072
Name: Tile & Grout Cleaner
Identity No:
Section 1
Manufacturers Name:
Address:
Emergency Phone:
City:
State:
Phone:
Date Prepared:

Miracle Sealants Company
12318 Lower Azusa Road
800-350-1901
Arcadia
CA
626-443-6433
June 2007

Section 2 - Hazardous Ingredient/Identity Information
Hazardous Components
CAS #
OSHA PEL
None
None
None
VOC: 6% by weight before dilution or 68 g/L

ACGIH TLV
None

Section 3 - Physical/Chemical Characteristics
Specific gravity: 1.066
Boiling point: 2100 F
Vapor pressure: Not tested
Melting point: Not tested
Vapor density: Not tested
Evaporation rate: Not tested
Solubility in water: 100%
Appearance and odor: Colorless liquid, citrus odor
Section 4 - Fire And Explosion Hazard Data
Flash Point: Not Available
Flammable limits: Not tested
LEL: Not tested
UEL: Not tested
pH: 8.5-10.0
NFPA hazard rating (o = Least, 4 = Extreme)
Health: 1
Fire: 0
Reactivity: 0
Other: 0
HMIS Hazard Rating:
Health: 1
Reactivity: 0

Fire: 0

Extinguishing media: CO2, dry foam
Special fire fighting procedures: None
Unusual fire and explosion hazards: None

www.miraclesealants.com

Emergency and First Aid Procedures:
Eyes: Flush with water for 15 minutes. If irritation persists, call physician.
Skin: Wash off with soap and water. If irritation persists, call physician.
Ingestion: Do not induce vomiting. Call physician or Poison Control Center
immediately..
Inhalation: Get person to fresh air if unconscious. Call physician.
Section 7 - Precautions For Safe Handling And Use
Steps to be taken in case material is released or spilled: Soak up with
inert, absorbent material. Scoop up and place in a proper waste
disposal container.
Waste disposal method: Dispose of in accordance with state and
local regulations.
Precautions to be taken in handling and storing: Store in a cool, dry place,
out of direct sunlight. Do not freeze less than or equal to 320 F or heat
above 1100 F.
Other precautions: KEEP OUT OF REACH OF CHILDREN. Follow directions on
the container for proper use of this product.
Section 8 - Control Measures
Respiratory protection: Ventilate by opening all doors and windows.
Ventilation:
Local exhaust - If available
Mechanical - If available

Protective gloves: Plastic or rubber, chemical resistant.
Eye protection: Tight fitting splash proof safety glasses or goggles.
Other protective clothing or equipment: None
Work hygienic practices: Wash hands thoroughly before handling food
stuffs, liquids or tobacco products. Use common sense and care around
chemicals. Never mix this product with other chemicals. Consult your supervisor for all other hygienic and safety practices. All practices depend on
your specific business. Directions for use normally found on label which will
dictate engineering and control measures.
Section 9 - Shipping & Regulatory Classification
DOT Shipping Name: Please refer to the Bill of Lading receiving/documents
for up-to-date information.
DOT#: Not Available

Section 5 - Reactivity Data
Stability: Stable
Conditions to avoid: None
Incompatible materials to avoid: Strong oxidizer
Hazardous decomposition byproducts: CO, CO2
Hazardous polymerization: Will not occur.
Section 6 - Health Hazard Data
Routes of Entry:
Eyes - Possible
Inhalation - Possible
Skin - Possible
Ingestion - Possible
Health Hazards - Same as signs and symptoms of exposure.

Special - None
Other - None

DOT Hazard Class: Not Available

Toxic Substances Control Act (TSCA): This product and/or all the
ingredients contained in this product have been registered under the
Toxic Substances Control Act.
SARA: No SARA 313 chemicals identified.
NOTE: Miracle Sealants believes the data set forth are accurate. Miracle
Sealants makes no warranty with respects thereto and disclaims all liability
or reliance thereon. Such data are offered solely for consideration, investigation and verification. Also, the data set forth is for the concentrated finished product. All lab samples are for experimental purposes only and used
at the customers discretion.

Carcinogenicity:
OSHA: None
NTP: None
IARC Monographs: None

6.11.2007

Signs and Symptoms of Over Exposure:
Eyes: Burning sensation.
Skin: Slight Irritation.
Ingestion: Nausea.
Inhalation: Slight Irritation.

MATERIAL SAFETY DATA SHEET

TEMP TILE, ENAMEL, METAL AND PORCELAIN CLEANER (SUMA)
HMIS
Health
Fire Hazard
Reactivity

2
0
0

NFPA
2
0
0

Personal protective equipment

None / Aucune / Ninguno

Version Number: 1

Preparation date: 2006-10-12

1. PRODUCT AND COMPANY IDENTIFICATION
Product name:

TEMP TILE, ENAMEL, METAL AND PORCELAIN CLEANER (SUMA)

MSDS #:
Product code:
Recommended use:

203201436001
04410279
Cleaning product.

Manufacturer, importer, supplier:
US Headquarters
JohnsonDiversey, Inc.
8310 16th St.
Sturtevant, Wisconsin 53177-0902
Phone: 1-888-352-2249
MSDS Internet Address:
www.johnsondiversey.com
Emergency telephone number:

Canadian Headquarters
JohnsonDiversey - Canada, Inc.
2401 Bristol Circle
Oakville, Ontario L6H 6P1
Phone: 1-800-668-3131

1-800-851-7145 (Prosar); 1-651-917-6133 (Int'l Prosar); 01-800-710-3400 (México)

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
CAUTION. CAUSES EYE IRRITATION. MAY BE MILDLY IRRITATING TO SKIN.
Principle routes of exposure:
Eye contact:
Skin contact:
Inhalation:
Ingestion:

Eye contact. Skin contact. Inhalation.
Moderately irritating to the eyes.
May be mildly irritating to skin.
None known.
May cause irritation to mouth, throat and stomach .

3. COMPOSITION/INFORMATION ON INGREDIENTS
HAZARDOUS COMPONENTS
Ingredient(s)
Ethylene glycol
Sodium carbonate
Quartz

CAS #

Weight %

LD50 Oral - Rat

107-21-1
497-19-8
14808-60-7

1 - 5%
1 - 5%
100

=4000 mg/kg
=4090 mg/kg
=500 mg/kg

LD50 Dermal Rabbit
=9530 µL/kg
Not available
Not available

LC50 Inhalation - Rat
200 mg/m3
Not available
Not available

4. FIRST AID MEASURES
Eye contact:
Skin contact:
Inhalation:
Ingestion:
Aggravated Medical Conditions:

Flush immediately with plenty of water. If irritation persists, get medical attention.
Flush immediately with plenty of water. If irritation develops get medical attention.
No specific first aid measures are required.
If swallowed, give a cupful of water or milk.
None known.

5. FIRE-FIGHTING MEASURES
Suitable extinguishing media:
Specific hazards:
Unusual hazards:
Specific methods:

The product is not flammable. Extinguish fire using agent suitable for surrounding fire.
Not applicable
None known
No special methods required

Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or
equivalent) and full protective gear
Extinguishing media which must not be used for safety reasons: No information available

TEMP TILE, ENAMEL, METAL AND PORCELAIN CLEANER (SUMA)

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6. ACCIDENTAL RELEASE MEASURES
Personal precautions:
Environmental precautions
and clean-up methods:

Use personal protective equipment
Clean-up methods - large spillage. Shovel into suitable container for disposal. Use a water rinse for final
clean-up.

7. HANDLING AND STORAGE
Handling:
Avoid contact with skin, eyes and clothing. Wash thoroughly after handling. FOR COMMERCIAL AND INDUSTRIAL USE ONLY.
Storage:
Protect from freezing. Keep tightly closed in a dry, cool and well-ventilated place. KEEP OUT OF THE REACH OF CHILDREN.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering measures to reduce exposure:
No special ventilation requirements. General room ventilation is adequate.
Personal Protective Equipment
Eye protection:
Hand protection:
Skin and body protection:
Respiratory protection:
Hygiene measures:

No special requirements under normal use conditions.
No special requirements under normal use conditions
No special requirements under normal use conditions.
No special requirements under normal use conditions.
Handle in accordance with good industrial hygiene and safety practice

Ingredient(s)
Ethylene glycol
Quartz

CAS #
107-21-1
14808-60-7

ACGIH
100 mg/m3 (Ceiling)
0.05 mg/m3 (TWA)

OSHA

Mexico
100 mg/m3 (Peak)
0.1 mg/m3 (TWA)

9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State:
pH:
Appearance:
Color:
Odor:
Specific gravity:
Density:
VOC:
Flash point:
Solubility:
Viscosity:

Solid
10.4
Paste
Yellow - Green
Lavender
1.5497
12.93 lbs/gal
0% *
>200 (°F) >93.3 (°C)
Soluble
No information available

No information available
Bulk density:
Dilution pH:
No information available.
Vapor density:
No information available
Evaporation Rate
No information available
Boiling point/range:
Not determined
Melting point/range:
Not determined
Decomposition temperature:
Not determined
Autoignition temperature:
No information available
Partition coefficient (n-octanol/water): No information available
Solubility in other solvents:
No information available
Elemental Phosphorus:
0 %P

* - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508

10. STABILITY AND REACTIVITY
Stability:
Polymerization:
Hazardous decomposition products:

The product is stable
Hazardous polymerization does not occur
None reasonably foreseeable.

11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information:

Oral LD50 estimated to be greater than 5000 mg/kg
See Section 3

Chronic toxicity:

This product contains Quartz (silica) which is listed as a carcinogen, however, the formulation is a heavy,
viscous liquid and therefore, chronic effects from exposure to respirable-size particles of this product are
minimal.

Specific effects
Carcinogenic effects:
Mutagenic effects:
Reproductive toxicity:
Target organ effects:

None known
None known
None known
None known

TEMP TILE, ENAMEL, METAL AND PORCELAIN CLEANER (SUMA)

2 of 4

11. TOXICOLOGICAL INFORMATION
HAZARDOUS COMPONENTS
Ingredient(s)
Quartz

CAS #
14808-60-7

NTP
X

IARC
1

OSHA
X

12. ECOLOGICAL INFORMATION
Environmental Information:

No data available

13. DISPOSAL CONSIDERATIONS
Waste from residues / unused products:
Dispose of according to all federal, state and local applicable regulations

14. TRANSPORT INFORMATION
DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information

15. REGULATORY INFORMATION
International Inventories
All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL).
U.S. Regulations
California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65
STATE RIGHT TO KNOW
Ingredient(s)
Ethylene glycol
Water
Sodium carbonate
Coconut Oil Based Soap
Tallow
Quartz
CERCLA/ SARA
Ingredient(s)
Ethylene glycol

CAS #
107-21-1
7732-18-5
497-19-8
TS*
61789-97-7
14808-60-7

CAS #
107-21-1

Ingredient(s)
Ethylene glycol
SARA 311/312 Hazard Categories
Immediate:
Delayed:
Fire:
Reactivity:
Sudden Release of Pressure:

MARTK:
X
X

Weight %
1 - 5%

NJRTK:
X
X

CERCLA/SARA RQ (lbs)
5000

CAA HAP
X

CAA ODS

PARTK:
X
X
X

RIRTK:
X
X
-

Section 302 TPQ (lbs)

Section 313
X

CWA Priority Pollutants

X
-

Canada
WHMIS hazard class: D2B Toxic materials .

Ingredient(s)
Ethylene glycol

CAS #
107-21-1

NPRI
X

16. OTHER INFORMATION
Reason for revision:
Prepared by:
Additional advice:

Not applicable
NAPRAC
None

TEMP TILE, ENAMEL, METAL AND PORCELAIN CLEANER (SUMA)

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16. OTHER INFORMATION
Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express
or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible
to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and
regulations.

TEMP TILE, ENAMEL, METAL AND PORCELAIN CLEANER (SUMA)

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Eli Lilly and Company
Material Safety Data Sheet
MSDS Index

Sodium Bicarbonate
Effective Date: 05-Aug-2004

Section 1 - Chemical Product and Company
Emergency Phone:
1-317-276-2000
CHEMTREC:
1-800-424-9300 (North America)
1-703-527-3887 (International)

Manufacturer:
Eli Lilly and Company
Lilly Corporate Center
Indianapolis, IN 46285
Common Name: Sodium Bicarbonate

CAS Number(s): 144-55-8
EINECS Number: 2056-33-8
Chemical Name: Carbonic acid monosodium salt
Chemical Family: Inorganic salt
Chemical Formula: C H O3 . Na
Molecular Weight: 84.01
Synonym(s): Sodium bicarbonate tablets; Soludal; Meylon; Soda; Monosodium carbonate; Sodium
hydrogen carbonate; Sodium acid carbonate; Bicarbonate of soda; Baking soda; Soda mint; NaHCO3;
Sodium bicarbonate - cell culture grade; Sodium bicarbonate tablet mix
Lilly Serial Number(s): 237728
Lilly Item Code(s): QA049K; QA116D; QA192M; QA241X; QA281L; QA384W; QA476V; QD400T;
QD472B; TA1260; TA1264; TA1265
See attached glossary for abbreviations.

Section 2 - Composition / Information on Ingredients
Ingredient
Sodium Bicarbonate

CAS
144-55-8

Exposure Guidelines:
Sodium bicarbonate - Exposure Guideline 1500 micrograms/m3 TWA for 12 hours, 2300
micrograms/m3 TWA for 8 hours. (Lilly-established guideline)
Dow Chemical Exposure Guideline 10 mg/m3 TWA.

Section 3 - Hazards Identification

Appearance: White crystalline powder or granules or compressed uncoated tablets
Physical State: Solid
Odor: Odorless

Emergency Overview
Emergency Overview Effective Date: 07-Aug-2002
Lilly Laboratory Labeling Codes:
Health 1
Fire 0

Reactivity 0

Primary Physical and Health Hazards: No Significant Health Hazards.
Caution Statement: No significant health hazards have been reported for Sodium Bicarbonate.

Routes of Entry: Inhalation and skin contact.
Effects of Overexposure: Material has low acute oral or inhalation toxicity. Material may be slightly
irritating to the eyes, skin, and respiratory tract. Inhalation of dust may cause coughing.
Medical Conditions Aggravated by Exposure: None known.
Carcinogenicity: No carcinogenicity data found. Not listed by IARC, NTP, ACGIH, or OSHA.

Section 4 - First Aid Measures
Eyes: Flush eyes with plenty of water. Get medical attention.
Skin: Remove contaminated clothing and clean before reuse. Wash all exposed areas of skin with
plenty of soap and water. Get medical attention if irritation develops.
Inhalation: Move individual to fresh air. Get medical attention if breathing difficulty occurs. If not
breathing, provide artificial respiration assistance (mouth-to-mouth) and call a physician immediately.
Ingestion: Call a physician or poison control center. No first aid procedures are normally required.

Section 5 - Fire Fighting Measures
Flash Point: Not applicable
UEL: Not applicable
LEL: Not applicable
Extinguishing Media: Use water, carbon dioxide, dry chemical, foam, or Halon.

Unusual Fire and Explosion Hazards: None known.
Hazardous Combustion Products: May emit toxic fumes when exposed to heat or fire.

Section 6 - Accidental Release Measures
Spills: Wear protective equipment, including eye protection, to avoid exposure (see Section 8 for
specific handling precautions). Vacuum material with appropriate dust collection filter in place. Be
aware of potential for dust explosion when using electrical equipment. If vacuum is not available,
lightly mist material and remove by sweeping or wet wiping.

Section 7 - Handling and Storage
Lilly Warehouse Storage Category: 140X
Storage Conditions: Warehouse: 10 to 40 C (45 to 104 F). For certain items, other storage conditions
may be required.

Section 8 - Exposure Controls / Personal Protection
See Section 2 for Exposure Guideline information.
Respiratory Protection: Use an approved respirator.
Eye Protection: Chemical goggles and/or face shield.
Ventilation: Laboratory fume hood or local exhaust ventilation.
Other Protective Equipment: Chemical-resistant gloves and body covering to minimize skin
contact. If handled in a ventilated enclosure, as in a laboratory setting, respirator and goggles or face
shield may not be required. Safety glasses are always required.

Section 9 - Physical and Chemical Properties
Boiling Point: Not applicable
Melting Point: Not applicable
Specific Gravity: 2.159
pH: 8.2 (1% solution)
Evaporation Rate: Not applicable
Water Solubility: 8.6 g/100 ml @ 20 C (68 F)
Vapor Density: Not applicable
Vapor Pressure: Not applicable

Section 10 - Stability and Reactivity

Stability: Stable at normal temperatures and pressures.
Incompatibility: May react with strong oxidizing agents (e.g., peroxides, permanganates, nitric acid,
etc.) and strong acids.
Hazardous Decomposition: May emit toxic fumes when heated to decomposition.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information
Acute Exposure
Oral:
Sodium bicarbonate - Rat, median lethal dose 4220 mg/kg.
Skin: No applicable information found.
Inhalation:
Sodium bicarbonate - Rat, median lethal concentration greater than 4740 mg/m3
(duration unspecified).
Skin Contact: No applicable information found.
Eye Contact:
Sodium bicarbonate - Rabbit, mild irritant

Chronic Exposure
Target Organ Effects: No applicable information found.
Reproduction:
Sodium bicarbonate - No teratogenic effects reported in rats or mice given large doses during
pregnancy.
Sensitization: No applicable information found.
Mutagenicity:
Sodium bicarbonate - Negative in Ames assay.

Section 12 - Ecological Information
Ecotoxicity Data:
Sodium bicarbonate
Daphnia magna 48-hour median lethal concentration: 11.7 mmol/L to 26.3 mmol/L
Western mosquitofish 96-hour median lethal concentration: 5.6 g/L
Bluegill 96-hour median lethal concentration: 8.25 g/L

Rainbow trout median lethal concentration (duration unspecified): 7.7 g/L
Environmental Fate: No applicable information found.
Environmental Summary:
Sodium bicarbonate - This material is practically non-toxic to aquatic organisms. Material is soluble in
water and may leach from soil into groundwater.

Section 13 - Disposal Considerations
Waste Disposal: Dispose of any cleanup materials and waste residue according to all applicable laws
and regulations.

Section 14 - Transport Information
Regulatory Organizations:
DOT: Not Regulated
ICAO/IATA: Not Regulated
IMO: Not Regulated

Section 15 - Regulatory Information
Below is selected regulatory information chosen primarily for possible Eli Lilly and Company
usage. This section is not a complete analysis or reference to all applicable regulatory
information. Please consider all applicable laws and regulations for your country/state.
U.S. Regulations
Sodium bicarbonate
TSCA - Yes
CERCLA - Not on this list
SARA 302 - Not on this list
SARA 313 - Not on this list
OSHA Substance Specific - No
EU Regulations
EC Classification
Not assigned an overall EC classification.

Section 16 - Other Information
MSDS Sections Revised: Section 7.

As of the date of issuance, we are providing available information relevant to the handling of this
material in the workplace. All information contained herein is offered with the good faith belief that it is
accurate. THIS MATERIAL SAFETY DATA SHEET SHALL NOT BE DEEMED TO CREATE ANY
WARRANTY OF ANY KIND (INCLUDING WARRANTY OF MERCHANTABILITY OR FITNESS
FOR A PARTICULAR PURPOSE). In the event of an adverse incident associated with this material,
this safety data sheet is not intended to be a substitute for consultation with appropriately trained
personnel. Nor is this safety data sheet intended to be a substitute for product literature which may
accompany the finished product.
For additional information contact:
Eli Lilly and Company
Hazard Communication
317-433-7171
GLOSSARY:
ACGIH = American Conference of Governmental Industrial Hygienists
AIHA = American Industrial Hygiene Association
BEI = Biological Exposure Index
CAS Number = Chemical Abstract Service Registry Number
CERCLA = Comprehensive Environmental Response Compensation and Liability Act (of 1980)
CHAN = Chemical Hazard Alert Notice
CHEMTREC = Chemical Transportation Emergency Center
DOT = Department of Transportation
EC = European Community
EINECS = European Inventory of Existing Chemical Substances
ELINCS = European List of New Chemical Substances
EPA = Environmental Protection Agency
HEPA = High Efficiency Particulate Air (Filter)
IARC = International Agency for Research on Cancer
ICAO/IATA = International Civil Aviation Organization/International Air Transport Association
IEG = Lilly Interim Exposure Guideline
IMO = International Maritime Organization
Kow = Octanol/Water Partition Coefficient
LEG = Lilly Exposure Guideline
LEL = Lower Explosive Limit
MSDS = Material Safety Data Sheet
MSHA = Mine Safety and Health Administration
NA = Not Applicable, except in Section 14 where NA = North America
NADA = New Animal Drug Application
NAIF = No Applicable Information Found
NCI = National Cancer Institute
NIOSH = National Institute for Occupational Safety and Health
NOS = Not Otherwise Specified
NTP = National Toxicology Program
OSHA = Occupational Safety and Health Administration
PEL = Permissible Exposure Limit (OSHA)
RCRA = Resource Conservation and Recovery Act
RQ = Reportable Quantity
RTECS = Registry of Toxic Effects of Chemical Substances

SARA = Superfund Amendments and Reauthorization Act
STEG = Lilly Short Term Exposure Guideline
STEL = Short Term Exposure Limit
TLV = Threshold Limit Value (ACGIH)
TPQ = Threshold Planning Quantity
TSCA = Toxic Substances Control Act
TWA = Time Weighted Average/8 Hours Unless Otherwise Noted
UEL = Upper Explosive Limit
UN = United Nations
WEEL = Workplace Environmental Exposure Level (AIHA)

Material Safety Data Sheet: Simple Green® Lime Scale Remover
Version No. 00004
Date of Issue: January 2007

Section 1:

ANSI-Z400.1-2003 Format

PRODUCT & COMPANY IDENTIFICATION

Product Name:
Additional Names:

Simple Green® Lime Scale Remover
AROMA CLEAN™ by Simple Green® Bath, Tub & Tile Cleaner

Manufacturer’s Product Code Numbers:
Lime Scale Remover
50022 – 22 oz trigger spray bottle
50032* – 32 oz trigger spray bottle
50005* – 5 gallon pail
Company:

Telephone:
Emergency Phone:
Use of Product:

Section 2:

Aroma Clean Bath, Tub & Tile
16201 – 24 oz Trigger Spray Bottle
50128* – 1 gallon bottle
50155* – 55 Gallon Drum

* GSA Available

Sunshine Makers, Inc.
15922 Pacific Coast Highway
Huntington Harbour, CA 92649 USA
800-228-0709 ● 562-795-6000
Fax: 562-592-3830
Chem-Tel 24-Hour Emergency Service: 800-225-3924
Ready to use liquid for removal of soap scum, mineral scale, hard-water spots, calcium and lime
deposits on hard, non-porous surfaces. Not for use on any natural stone surface.

HAZARDS IDENTIFICATION

Emergency Overview: CAUTION. Eye irritant.
This product contains no substances which at their given concentration, are considered to be hazardous to health.
0
0

1
0

NFPA/HMIS Rating:
Health = 1 = slight
Fire, Reactivity, and Special = 0 = minimal

Principal Routes of Exposure: Eye, Skin contact, Ingestion
Eye Contact: Eye Irritant.
Skin Contact: Substance may cause slight skin irritation.
May cause gastrointestinal irritation, nausea, vomiting and diarrhea.
Ingestion:
Carcinogens: No ingredients are listed by OSHA, IARC, or NTP as known or suspected carcinogens.
No medical conditions are known to be aggravated by exposure to Simple Green® Lime Scale
Medical Conditions:
Remover.

Section 3:

COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name
Urea monohydrochloride

CAS Number
506-89-8

Hazardous Substances Present:
SARA 313 Substances Present:
Clean Air Act Sec. 112 Substances Present:

Section 4:
Eye Contact:
Skin Contact:
Inhalation:
Ingestion:

% Weight
3-5%

ACGIH TWA
Not applicable

Acute Toxicity LD50
1121 mg/kg rat (oral)

None
None
None

FIRST AID MEASURES
In case of eye contact, remove contact lenses and rinse immediately with plenty of water, also under the
eyelids, for at least 15 minutes.
Flush with water. Wash off the soap and water. Obtain medical attention if irritation persists. Wsh
contaminated clothing well before reuse.
Not a normal route of exposure. If symptoms develop, move victim to fresh air. If symptoms persist,
call a physician.
Clean mouth with water and afterwards drink plenty of water. Never give anything by mouth to an
unconscious person. Consult a physician if necessary.

Material Safety Data Sheet: SIMPLE GREEN® LIME SCALE REMOER

Pg 1 of 3

Material Safety Data Sheet: Simple Green® Lime Scale Remover
Date of Issue: January 2007
Version No. 00004

Section 5:

FIRE FIGHTING MEASURES

Flash Point:
Hazardous Combustion Products:
Suitable extinguishing media:
Specific hazards:

Section 6:

ANSI-Z400.1-2003 Format

Not flammable
May include, but not limited to, oxides of carbon
Treat for surrounding material.
Fire fighters should wear self-contained breathing apparatus.

ACCIDENTAL RELEASE MEASURES

Method for cleaning up: Before initiating cleanup, refer to hazard data on this MSDS
• Retrieve any useable product and store in properly marked containers
• Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container
• Prevent large spills from entering sewers and waterways.

Section 7:

HANDLING AND STORAGE

Safe Handling:
Storage:
Incompatible Products:

Section 8:

Avoid contact with eyes. Wash hands immediately after contact to avoid hand-eye transfer.
Keep out of reach of children. Keep containers tightly closed in cool, well-ventilated place.
Bleach, mildew stain removers, caustics, oxidizers, reducers.

EXPOSURE CONTROLS/PERSONAL PROTECTION

Hand Protection
Eye Protection
Respiratory Protection
Other Protective Equipment
Engineering measures
General hygiene
conditions:

Section 9:

There are no known hazards associated with this material when used as recommended.
The following general hygiene considerations are recognized as common good industrial hygiene
practices:
- Avoid breathing vapor or mist.
- Avoid contact with eyes.
- Wash thoroughly after handling and before eating, drinking, or smoking.

PHYSICAL AND CHEMICAL PROPERTIES

Appearance:
Odor:
Vapor Density:
pH:
Boiling Point:
Freezing Point:
Water Content:
Specific Gravity:

Section 10:

Rubber
Safety Glasses
Not normally required
As required by employer code
None, under normal processing

Lime Scale Remover is a pale aqua liquid; AROMA CLEAN is a pale purple liquid.
Lime Scale Remover has a wintergreen fragrance; AROMA CLEAN has a lavender fragrance.
Not determined
Completely water soluble.
Water Solubility:
1.0 – 1.5
8.52 lbs/gallon
Bulk Density:
o
o
~ 100 C (~212 F)
None observed to boiling point.
Flash Point:
Ca. 0oC
< 0.01%
Insoluble matter:
> 70%
0 g/L per EPA Method 24
VOCs:
1.0230

STABILITY AND REACTIVITY

Stability:
Materials to Avoid:
Hazardous Decomposition Products:

Stable
None known
None expected

Material Safety Data Sheet: SIMPLE GREEN® LIME SCALE REMOER

Pg 2 of 3

Material Safety Data Sheet: Simple Green® Lime Scale Remover
Version No. 00004
Date of Issue: January 2007

Section 11:

ANSI-Z400.1-2003 Format

TOXICOLOGICAL INFORMATION

Acute Toxicity:

Oral LD50 (rat) - > 10 g/kg body weight
Toxicity extrapolated from ingredients. Animal testing not conducted.

Eye Irritation:

This product may cause irritation to the eyes.

Dermal Irritation:

Not expected under normal use conditions.

Repeat Exposure Via Skin Contact: No toxic effects are expected to be associated with normal daily exposure

Section 12: ECOLOGICAL INFORMATION
Hazard to wild mammals:
Hazard to avian species:
Hazard to aquatic organisms:
Chemical Fate Information:

Low, based on toxicology profile
Low, based on toxicology profile
> 100 mg/L (rainbow trout, 96 hours)
Biodegradable; Based on formula & biodegradability, the bioaccumulation potential is low.

Section 13: DISPOSAL CONSIDERATIONS
Waste from residues/unused product:
Empty Containers:

Dispose in accordance with all national and local regulations.
Triple-rinse with water and offer for recycling if available in your area.
Otherwise, dispose as non-hazardous waste.

Dispose of used or unused product, and empty containers in accordance with the local, State provincial, and Federal
regulations for your location. Never dispose into lakes, streams, and open bodies of water or storm drains.

Section 14: TRANSPORT INFORMATION
DOT:
Proper Shipping Name:

Not regulated for ground shipments
Cleaning Compound Class 55

UN No.:
Packing Group:

Not required.
Not applicable

Section 15: REGULATORY INFORMATION
All components are listed on Canadian DSL, EINECS and TSCA Chemical Substances Inventory.
RCRA Status:
Not a hazardous waste.
CERCLA Status:
Not Listed.
TSCA TIR Reporting:
Not required / Not Listed.
CA PROP. 65 Status:
Not Listed.

Section 16:

OTHER INFORMATION

Questions about the information found on this MSDS should be directed to:
SUNSHINE MAKERS, INC. – TECHNICAL DEPARTMENT
15922 Pacific Coast Hwy. Huntington Harbour, CA 92649
Phone: 800/228-0709 [8am-5pm Pacific time, Mon-Fri]
Fax: 562/592-3830

Email: infoweb@simplegreen.com

DISCLAIMER: The information provided with this MSDS is furnished in good faith and without warranty of any kind.
Personnel handling this material must make independent determinations of the suitability and completeness of information
from all sources to assure proper use and disposal of this material and the safety and health of employees and customers.
Sunshine Makers, Inc. assumes no additional liability or responsibility resulting from the use of, or reliance on this
information.

Material Safety Data Sheet: SIMPLE GREEN® LIME SCALE REMOER

Pg 3 of 3

Material Safety Data Sheet
Product Name:

Number:

DMN-308

Sparkle Floor Cleaner, #2473
Revised: 9/4/98

A liquid alkaline detergent.
Damon Industries, Inc.
Box 2120
Alliance, OH 44601

24 hour Emergency Only phone: 1-800-535-5053
Information phone: 1-800-362-9850 or 330-821-5310
fax: 330-821-6355

Section 2 - Composition / Information on Hazardous Ingredients
Ingredient
1-Butoxy-2-propanol
Potassium hydroxide

Cas No.
5131-66-8
1310-58-3

Percent
2 - 10%
2 - 5%

Carcinogen
No
No

Section 3 - Hazards Identification
Emergency Overview: Concentrate is corrosive to all body parts. Diluted solutions may be irritating or corrosive
depending on their strength. Excessive inhalation of vapors may cause irritation. Product is water based and
presents little or no hazard in a fire. Product has a high pH and large amounts should not be allowed into sewers
without neutralizing. A green liquid with a sharp odor.
Health Hazards: Corrosive, Irritant
Primary Routes of Entry: X Through Skin

Physical Hazards: None
X Inhalation

X Ingestion

Potential Health Effects:
Eyes - concentrate and strong solutions cause eye damage. Milder solutions cause irritation and redness.
Skin - prolonged contact with concentrate and strong solutions can cause skin damage and loss. There is little or
no effect if rinsed off thoroughly right away. Weaker solutions cause irritation.
Swallowing - may result in damage to mucous membranes and gastrointestinal irritation.
Breathing - excessive inhalation of mist or spray can cause coughing, irritation of nose and throat.
Section 4 - First Aid Measures
Eye Contact: Immediately flush eyes with water for at least 15 minutes, lifting upper and lower eyelids
occasionally. Get medical attention immediately.
Skin Contact: With concentrate and strong (1:10) solutions immediately flush exposed area with running water
for 15 minutes. Remove contaminated clothing and shoes. With weaker solutions wash exposed area with soap
and water. If irritation persists, call a physician. Wash contaminated clothing before reuse.
Inhalation: If affected, move exposed person to fresh air. If irritation persists get medical attention.
Ingestion: If the product is swallowed, do NOT induce vomiting. If the affected person is conscious, give a glass
of water or milk to drink. Get medical attention immediately.
Section 5 - Fire-Fighting Measures
Flash Point: None (ASTM D-56 closed cup)
Lower Explosive Limit: Not Applicable
Extinguishing Media: Any
Special Fire Fighting Procedures: None.
Unusual Fire And Explosion Hazards: None.

Upper Explosive Limit: Not Applicable

Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Small spills of a few gallons may be cleaned up with a
rag or mop. Larger spills should diked to prevent spreading and then collected into clean pails or drums.
Section 7 - Handling and Storage
Empty containers retain product residue and may be hazardous. Observe all precautions given in this data sheet.
Keep from freezing.

DMN-308 Sparkle Floor Cleaner

Page 1 of 2

9/4/98

Section 8 - Exposure Controls / Personal Protection
Ingredient
1-Butoxy-2-propanol
Potassium hydroxide

C.A.S. No.
5131-66-8
1310-58-3

(1)=OSHA (2)=NIOSH (3)=ACGIH (4)=CANADA

Percent
2 - 10%
2 - 5%

TWA(source)
STEL
Ceiling
no established limits are available
2 mg/m3(2)
2 mg/m3(3,4)

TWA=8 hr Time Weighted Average

STEL=15 minute TWA

Ceiling=Instantaneous

Ventilation: Good room ventilation.
Respiratory Protection: None, except when spraying overhead use an approved respirator with an organic
vapor cartridge.
Gloves: Use rubber or latex gloves when handling concentrate or strong dilutions. Persons with sensitive skin or
who use the product for prolonged periods may wish to use rubber or latex gloves when using any dilution.
Eye Protection: Most uses of diluted product do not require eye protection although the use of safety glasses
with side shields, especially for contact lens wearers, is always a good idea. Using concentrate or strong (1:10)
solutions requires safety glasses with side shields. Overhead spraying requires goggles or a face shield, or if
considerable spray will fall on the user, complete head and body protection.
Other Protective Equipment: An eyewash station should be located within 10 seconds travel time of the
concentrate use/mixing area.
Section 9 - Physical and Chemical Properties
Boiling Point: 215° F.
Specific Gravity: 1.05
Percent Volatiles: 85%
Solubility In Water: Complete
Appearance and Odor: Green liquid with sharp odor.

Vapor Pressure: Not Available
Vapor Density: Not Available
Evaporation Rate: Same as water.
pH: concentrate 13.5 ± 0.5

Section 10 - Stability and Reactivity
Incompatibility: None

Hazardous Decomposition Products: None
Section 11 - Toxicological Information

Target Organs: None.
Section 12 - Ecological Information
When scrubbing outdoors or where the solution will enter a storm sewer, flood the cleaned area with plenty of
water to dilute and reduce pH of run-off. Do not use more product than necessary. Do not dispose of unusable
product in the environment. Be sure to comply with any applicable regulations.
Section 13 - Disposal Considerations
Waste Disposal Method: Dispose of up to 2 gallons of concentrate in the sanitary sewer with a large amount of
water. Larger amounts must be neutralized to within the pH limits of your waste water treatment system.
Section 14 - Transport Information
D.O.T. Hazard Class: Not considered hazardous by D.O.T., I.M.C.O., I.A.T.A. or U.N.
Section 15 - Regulatory Information
The components of this product are on the TSCA inventory of chemical substances.
Section 16 - Other Information
NFPA / HMIS
Ratings:

Health:
Flammability:
Reactivity:

2
0
0

0 = Insignificant
3 = Serious

1 = Slight
2 = Moderate
4 = Severe

The information accumulated herein is believed to be accurate but is not warranted to be. Recipients are advised
to confirm in advance that the information is current, applicable, and suitable to their circumstances.

DMN-308 Sparkle Floor Cleaner

Page 2 of 2

9/4/98

MATERIAL SAFETY DATA SHEET

VANISH NON-ACID BOWL & BATHROOM CLEANER II
HMIS
Health
Fire Hazard
Reactivity

1
1
0

NFPA
1
1
0

Personal protective equipment

Preparation date: 2005-08-23

Version Number: 1

1. PRODUCT AND COMPANY IDENTIFICATION
Product name:

VANISH NON-ACID BOWL & BATHROOM CLEANER II

MSDS #:
Product code:
Recommended use:

126478001
126478001, 90158
Cleaning product.

Manufacturer, importer, supplier:
US Headquarters
JohnsonDiversey, Inc.
8310 16th St.
Sturtevant, Wisconsin 53177-0902
Phone: 1-888-352-2249
MSDS Internet Address:
www.johnsondiversey.com
Emergency telephone number:

Canadian Headquarters
JohnsonDiversey - Canada, Inc.
2401 Bristol Circle
Oakville, Ontario L6H 6P1
Phone: 1-800-668-3131

1-800-851-7145 (Prosar); 1-651-917-6133 (Int'l Prosar); 01-800-710-3400 (México)

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Moderately irritating to the eyes. Moderately irritating to the skin.
Principle routes of exposure:
Skin contact:
Eye contact:
Inhalation:
Ingestion:

Inhalation. Skin contact. Eye contact.
May be mildly irritating to skin.
Moderately irritating to the eyes.
None known.
None known.

3. COMPOSITION/INFORMATION ON INGREDIENTS
HAZARDOUS COMPONENTS
Ingredient
N-alkyl dimethyl benzyl ammonium
chlorides
N-alkyl dimethyl ethylbenzyl
ammonium chlorides
Isopropyl alcohol

CAS #
68391-01-5

Weight %
0.1 - 1.5%

LD50 Oral
Not available

LD50 Dermal
Not available

LC50 Inhalation
Not available

68956-79-6

0.1 - 1.5%

Not available

Not available

Not available

67-63-0

1 - 5%

5000 mg/kg (rat)

12800 mg/kg (rabbit)

16000 ppm/8H (rat)

4. FIRST AID MEASURES
Eye contact:
Skin contact:
Inhalation:
Ingestion:
Aggravated Medical Conditions:

Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if
present, after the first 5 minutes, then continue rinsing eyes. If irritation persists, get medical attention.
Flush immediately with plenty of water. Get medical attention if irritation occurs.
No specific first aid measures are required.
No specific first aid measures are required.
Persons with pre-existing skin disorders may be more susceptable to irritating effects

5. FIRE-FIGHTING MEASURES
Suitable extinguishing media:

Use dry chemical, CO2, water spray or "alcohol" foam.

VANISH NON-ACID BOWL & BATHROOM CLEANER II

1 of 3

Specific hazards:
Unusual hazards:
Specific methods:

Although this product has a flash point below 200 Deg. F, it is an aqueous solution containing an alcohol
and does not sustain combustion.
None known.
No special methods required.

Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or
equivalent) and full protective gear
Extinguishing media which must not be used for safety reasons: No information available

6. ACCIDENTAL RELEASE MEASURES
Personal precautions:
Environmental precautions
and clean-up methods:

Put on appropriate personal protective equipment (see Section 8.).
Use appropriate containment to avoid environmental contamination. Sweep up and shovel into suitable
containers for disposal. Keep in suitable and closed containers for disposal. Use a water rinse for final
clean-up.

7. HANDLING AND STORAGE
Handling:
Avoid contact with skin, eyes and clothing. Wash thoroughly after handling. FOR COMMERCIAL AND INDUSTRIAL USE ONLY
Storage:
Keep tightly closed in a dry, cool and well-ventilated place. Protect from freezing . Keep out of the reach of children.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering measures to reduce exposure:
None known
Personal Protective Equipment
Eye protection:
Hand protection:
Skin and body protection:
Respiratory protection:
Hygiene measures:
Ingredient
Isopropyl alcohol

No special requirements under normal use conditions
No special requirements under normal use conditions
No special requirements under normal use conditions
No special requirements under normal use conditions
Handle in accordance with good industrial hygiene and safety practice
CAS #
67-63-0

ACGIH
400 ppm (STEL)
200 ppm (TWA)

OSHA
980 mg/m3 400 ppm

Mexico
1225 mg/m3 (STEL)
980 mg/m3 (TWA)

9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State:
Liquid
Color:
Clear Blue
Odor:
No information available
Specific gravity:
No information available
Dilution pH:
No information available
Bulk density:
No information available
Vapor density:
No information available
Evaporation rate:
No information available
Solubility in other
No information available
solvents:
Viscosity: No information available
Partition coefficient (n-octanol/water): No information available

Appearance:
No information available
Boiling point/range: >199.4 (°F)
Melting point/range: <32 (°F)
pH:
7.5
Density:
No information available
Decomposition temperature:
Not determined
Autoignition temperature:
No information available
Solubility:
Soluble
VOC:
2%
Flash point: 141.8 (°F) 61 (°C)

10. STABILITY AND REACTIVITY
Stability:
Polymerization:
Hazardous decomposition products:
Materials to avoid:
Conditions to avoid:

The product is stable.
Not applicable.
None reasonably foreseeable
None known .
Keep away from heat.

11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information:

LD50 estimated to be greater than 5000 mg/kg.
See Section 3

Chronic toxicity:

None known

Specific effects
Carcinogenic effects:

None known

VANISH NON-ACID BOWL & BATHROOM CLEANER II

2 of 3

Mutagenic effects:
Reproductive toxicity:
Target organ effects:

None known
None known
None known

12. ECOLOGICAL INFORMATION
Environmental Information:

When used for its intended purpose this product should not cause adverse effects in the environment

13. DISPOSAL CONSIDERATIONS
Waste from residues / unused products:
PESTICIDAL WASTE - Observe all applicable Federal/Provincial/State regulations and Local/Municipal ordinances regarding disposal of pesticide
wastes .

14. TRANSPORT INFORMATION
DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information

15. REGULATORY INFORMATION
International Inventories
All components of this product are listed on the following inventories: Korea (ECL), Philippines (PICCS), China (IECSC).
U.S. Regulations
EPA Reg. No. : 70627-3
California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65
STATE RIGHT TO KNOW
Ingredient
Water
Isopropyl alcohol
Alcohol ethoxylates

CAS #
7732-18-5
67-63-0
68131-39-5

CERCLA / SARA
Ingredient
Isopropyl alcohol

CAS #
67-63-0

MARTK:
Listed
-

NJRTK:
Listed
-

Weight %
1 - 5%

PARTK:
Listed
-

CERCLA/SARA RQ (lbs)
100

RIRTK:
Listed
-

ILRTK:
Listed
-

Section 302 TPQ (lbs)

CTRTK:
Listed
-

Section 313
Listed.

Canada
WHMIS hazard class: Not for sale in Canada .
Ingredient
Isopropyl alcohol

CAS #
67-63-0

NPRI
Listed

16. OTHER INFORMATION
Reason for revision:
Prepared by:
Additional advice:

Not applicable
NAPRAC
None

Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express
or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible
to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and
regulations.

VANISH NON-ACID BOWL & BATHROOM CLEANER II

3 of 3

MATERIAL SAFETY DATA SHEET
24 HOUR EMERGENCY CHEMTREC TELEPHONE 1-(800)-424-9300
24 HOUR MEDICAL EMERGENCY TELEPHONE 1-(888)-324-7596
WD-40 COMPANY, 1061 Cudahy Place (92110), P.O. Box 80607, San Diego, CA 92138-0607
TELEPHONE (619)-275-1400
DATE PREPARED: December, 2004
I. GENERAL INFORMATION
PRODUCT NAME: Maximum Strength X-14 Instant Mildew Stain Remover
PRODUCT CATEGORY: Household Cleaner
II. INGREDIENTS
HAZARDOUS INGREDIENTS:
%
Sodium hypochlorite
3-6%
Sodium carbonate
0.5-2%

CAS #
7681-52-9
497-19-8

TLV/PEL
Not established
Not established

HAZARD DATA
Irritant/Corrosive
Irritant

III. HEALTH HAZARD DATA
EFFECTS OF OVEREXPOSURE:
SKIN: May cause skin irritation.
EYE: Causes eye irritation.
INHALATION: Mist may be irritating to the upper respiratory tract. Not recommended for use by persons with heart conditions or chronic respiratory problems.
INGESTION: May cause gastrointestinal irritation, nausea, vomiting and diarrhea.
FIRST AID PROCEDURE:
SKIN: Flush immediately and thoroughly with water.
EYE: Flush with large amounts of water for at least 15 minutes while holding eyelids open. Contact a physician.
INHALATION: Discontinue use. Remove to fresh air.
INGESTION: Do not induce vomiting. Drink several glasses of water. Call a poison control center or a physician immediately. Do not give anything by mouth to unconscious individuals.
IV. SPECIAL PROTECTION INFORMATION
EYE PROTECTION: Safety glasses should be worn in an industrial/institutional setting.
SKIN PROTECTION: For sensitive skin or prolonged use, wear rubber gloves.
RESPIRATORY PROTECTION: Not needed when product is used according to label directions. Appropriate cartridge
respirator may be needed in an institutional setting. Use in a well-ventilated area.
V. FIRE AND EXPLOSION HAZARD DATA
FLAMMABLE LIMITS: Non-flammable liquid.
EXTINGUISHING MEDIA: As applicable to type of fire.
SPECIAL FIRE FIGHTING PROCEDURES: Fire can be fought with standard procedures but hazards are present that
can be handled safely by wearing self contained breathing apparatus.
UNUSUAL FIRE/EXPLOSION HAZARDS: None
VI. ENVIRONMENTAL PROTECTION PROCEDURES
SPILL RESPONSE: Wipe up spill with absorbent material. Rinse spill area with water to remove residue.
WASTE DISPOSAL METHOD: Do not reuse container. Dispose of in accordance with federal, state and local
regulations.

VII. SPECIAL PRECAUTIONS
HANDLING: Avoid contact with eyes, contact lens or eyeglasses. Avoid contact with skin. Avoid breathing fumes.
STORAGE: Do not store next to acids or heat source. Keep container tightly closed.
TRANSPORTATION: In accordance with federal, state and local regulations.
VIII. REACTIVITY DATA
STABILITY: Stable.
INCOMPATIBILITY: Do not mix with acids, ammonia or other household chemicals.
HAZARDOUS DECOMPOSITION PRODUCTS: When heated can form carbon monoxide, carbon dioxide and chlorine.
IX. PHYSICAL DATA
BOILING POINT (°F): Not determined.
VAPOR PRESSURE (mm Hg): Not determined.
VAPOR DENSITY (AIR=1): Not determined.
APPEARANCE AND ODOR: Clear, yellow
liquid with chlorine odor.

SPECIFIC GRAVITY (H2O=1): 1.03-1.15
% VOLATILE BY VOLUME: Greater than 85%.
SOLUBILITY IN WATER: Soluble
pH: 11.5-12.0

The information provided in this Material Safety Data Sheet has been compiled from our experience and data with
similar commercially available materials and is believed to be accurate. No guarantee of accuracy is made. It is the
user's responsibility to determine the suitability of this information for the adoption of necessary safety precautions and
disposal procedures.
PLEASE BE ADVISED THAT THIS MATERIAL SAFETY DATA SHEET IS INTENDED FOR INDUSTRIAL PURCHASERS
WHICH MAY USE LARGE QUANTITIES OF THE PRODUCT. DEPENDING ON THE SCOPE OF TOXICOLOGICAL
TESTS CONDUCTED ON THE FORMULATION AND/OR THE RAW MATERIALS, THE LISTED HAZARD DATA MAY
REFLECT HAZARDS RELATED TO THE FORMULATION AS A WHOLE OR TO INDIVIDUAL COMPONENTS AT 100%
CONCENTRATION. THEREFORE, CERTAIN WARNINGS AND HAZARD STATEMENTS CONTAINED ON THIS MSDS
MAY NOT BE APPLICABLE TO OR INCLUDED IN THE PACKAGE LABELING AVAILABLE TO THE GENERAL PUBLIC.

SIGNATURE: Peter Fougner

TITLE:

REVISION DATE:

SUPERSEDES:

MSDS No.:X14MSR

December, 2004

Director - Global Quality Assurance
October, 2003

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name:
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

FORMULA 499185
ZENAGEL
ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Sodium Hydroxide
Butane
Triethylene Glycol
Propane
Ethanolamine

CAS No.:
1310-73-2
106-97-8
112-27-6
74-98-6
141-43-5

TLV:
2 mg/m3 ceiling
800ppm
N.A.
2500ppm
3ppm

______________________________________________________________________________

SECTION 3
Boiling Point:
Solubility in Water:
pH:

PHYSICAL DATA
<0 to 5670 F
Soluble
13.5 + 0.5

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.99 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flash Point(Propellant):
Flammable Limits(Propellant):
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

Non-Flammable
<0OF
LEL:
0.9
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5
Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

Acids
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.

First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________

SECTION 9

SPILL OR LEAK PROCEDURE

Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None

__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
499185

Friday, January 18, 2008

Page 1 of 4

MSDS - Material Safety Data Sheet
Product Name: CARPET AND UPHOLSTERY ALL PURPOSE FOAM
CLEANER
MSDS No.: MPC22

I. Basic Information:
Manufacturer: RADIATOR SPECIALTY COMPANY

2

Address: 600 RADIATOR ROAD
City, ST Zip: INDIAN TRAIL, NC 28079

1

Emergency Contact: Rocky Mountain Poision Control Center
Emergency Telephone Number: 303-623-5716
Contact: Robert Geer
Information Telephone Number: 704-684-1811
Last Update: 01/18/2008
Chemical State:

X

Chemical Type:

1
2

Expiration Date:

Liquid
Pure

Gas

X

0

Solid

B

Mixture

II. Ingredients:
Trade Secret
EHS

IARC
NTP

SARA
313
OSHA
SUB Z
PEL

ACGIH
TLV

X

25 ppm

25 ppm

CAS No.

Chemical Name

% Range

111-76-2

2-Butoxyethanol

1-5

106-97-8

Butane

1-4

N/E

800 ppm

74-98-6

Propane

1-4

N/E

1000 ppm

1310-73-2

Sodium hydroxide

0-3

2 mg/m3

2 mg/m3

Other
Limits

III. Hazardous Identification:
Hazard Category:

X Acute

Chronic

Fire

X Pressure

Hazardous Identification Information:

CAUTION: Eye Irritant, Contents Under Pressure.
Level 1 Aerosol

IV. First Aid Measures:
Route(s) of Entry:

Absorption, Eye, Inhalation, and Ingestion.
Health Hazards (Acute and Chronic):

See signs and symptoms below.
Signs and Symptoms:

Eye Contact: Direct spray of vapors may be irritating or harmful to eyes.
Skin Contact: Prolonged contact may cause irritation due to defatting of skin.
Inhalation: High concentration of vapors may irritate nose and throat and cause headaches and nausea.
Ingestion: Can cause irritation, gastric disturbances, and nausea..
Medical Conditions Generally Aggravated by Exposure:

Reactive

Friday, January 18, 2008

Page 2 of 4

MSDS - Material Safety Data Sheet
Product Name: CARPET AND UPHOLSTERY ALL PURPOSE FOAM
CLEANER
MSDS No.: MPC22
None known
Emergency and First Aid Procedures:

Eye Contact: Flush eyes with water for 15 minutes while lifting upper and lower eyelid. Get prompt medical attention.
Skin Contact: Wash with soap and water. If irritation persists, get prompt medical attention.
Inhalation: Move to fresh air. If breathing becomes difficult get prompt medical attention.
Ingestion: Drink water or milk. Call Poison Control Center, physician, or hospital emergency room immediately.

.

Other Health Warnings:

None known

V. Fire Fighting Measures:
Flash Point: None
F.P. Method:

Lower Explosive Limit: N/D

Upper Explosive Limit: N/D

TCC

Fire Extinguishing Media: Water Fog, Foam, Carbon Dioxide, Dry Chemical

Special Fire Fighting Procedures:

Wear self-contained , positive pressure breathing apparatus and protective clothes. Cool containers exposed to heat with water
fog.
Unusual Fire and Explosion:

Use shield to protect from venting, rupturing, or bursting cans.

VI. Accidental Release Measures:
Steps to be Taken in Case Material is Released or Spilled:

Use appropiate protective equipment. Contain spill and then absorb spill with inert material or rags and scoop into a chemical
waste container. Neutralize remaining traces of material and flush with water followed by liberal covering with sodium bicarbonate.
All clean-up material should be removed and placed in approved containers for disposal. Rinse water may be disposed of down a
sanitary sewer system if authorized by the local municipality.

VII. Handling and Storage:
Precautions to be Taken:

Use with adequate ventilation. Do not take internally. Do not expose to heat or store at temperatures above 120 F. Do no
puncture or incinerate container.
Other Precautions:

Avoid contact with strong oxidizing agents.

VIII. Exposure Controls/Personal Protection:
Ventilation Requirements:

See Section 2 for applicable exposure limits. Use with adequate ventilation. If TLV is exceeded, wear NIOSH approved respirator.
Personal Protective Equipment:

See Section 2 for applicable exposure limits. For prolonged exposure wear protective safety glasses, gloves, and apron.

Friday, January 18, 2008

Page 3 of 4

MSDS - Material Safety Data Sheet
Product Name: CARPET AND UPHOLSTERY ALL PURPOSE FOAM
CLEANER
MSDS No.: MPC22

IX. Physical and Chemical Properties:
Boiling Point: 212 F

Melting Point: N/A

Evaporation Rate (Butyl Acetate = 1): < 1

Vapor Pressure (mm Hg.): N/D

Specific Gravity (H20 = 1): 1.00000

Vapor Density (AIR = 1): N/D

Solubility In Water: Soluble

Appearance and Odor:

Other Information: pH: 11.5 - 12.5

White spray foam with light citrus floral scent

X. Stability and Reactivity:
Stability:

Stable
Incompatibility (Materials to Avoid):

Avoid contact with strong oxidizing agents
Decomposition/By Products:

Carbon Monoxide, Carbon Dioxide
Hazardous Polymerization:

Will not occur

XI. Toxicological Information:
N/D

XII. Ecological Information:
N/D

XIII. Disposal Considerations:
DISPOSAL: This container may be recycled in aerosol recycling centers when empty. Before offering for recycling, empty the can
by using the product according to the label. DO NOT PUNCTURE! If recycling is not available, wrap the container and discard in
the trash. Dispose of unused product in accordance with all local, state government and federal laws and regulations.

XIV. Transport Information:
DOT Hazard Class: ORM-D
Shipping Name: Consumer Commodity
The DOT description is provided to assist in the proper shipping classification of this product and may not be suitable for all shipping
purposes.

XV. Regulatory Information:
See Section 2 for SARA Reportable Chemicals.
USA TSCA: All components of this material are listed on the US TSCA Inventory.

Friday, January 18, 2008

Page 4 of 4

MSDS - Material Safety Data Sheet
Product Name: CARPET AND UPHOLSTERY ALL PURPOSE FOAM
CLEANER
MSDS No.: MPC22

XVI. Other Information:
Do not used in confined area without proper ventilation. Contact lenses may cause further damage in case of splash into eye.
KEEP AWAY FROM CHILDREN AND ANIMALS!
N/E: Not Established
N/D: Not Determined
N/A: Not Applicable
N/AV: Not Available
While Radiator Specialty Company believes this data is accurate as of the revision date, we make no warranty with respect to the
data and we expressly disclaim all liability for reliance thereon. The data is offered solely for information, investigation, and
verification. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or
disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance.

MATERIAL SAFETY DATA SHEET
Complies with OSHA hazard communication standard 29 CFR 1910.1200
Scot Laboratories
16841 Park Circle Drive
Chagrin Falls, OH 44023

Phone:
Fax:
Date:

(440) 543-3033
(440) 543-1825
September 26, 2000

SECTION I - Product Identification
Product Name:
Carpet Shampoo for Extraction Cleaners

HMIS Rating
Health1
Fire0
Reactivity-0
0= minimal, 1= slight, 2= moderate, 3= serious, 4= severe
Code:

237

SECTION II - Hazardous Ingredients/Identity Information - NONE
SECTION III - Physical/Chemical Characteristics
Physical State:
Liquid
Vapor Density (AIR = 1):
Color:
Clear, Lt. Amber
Vapor Pressure (mm Hg):
Odor:
Pleasant
Solubility in Water:
o
Boiling Point:
212 F
Specific Gravity (H2 O):
o
Melting Point:
32 F
Evaporation Rate:

Heavier than air
Unknown
Complete
1.055
< 1 (Butyl Acetate = 1)

SECTION IV - Fire and Explosion Hazard
Flash Point:
Flammability Limits in Air:
Extinguishing Media:

Data
None
N/A
N/A

SECTION V - Reactivity Data
Stability:
Material to Avoid:
Conditions to Avoid:
Hazardous Decomposition or Byproducts:

Stable
Do not mix with other chemicals. Follow instructions on label.
Unknown
Unknown (Hazardous Polymerization will not occur)

Fire Fighting Procedure:
Unusual Fire or Explosion Hazards:

None
None

SECTION VI - Health Hazard Data
Product hazard classification:
None
Carcinogenic ingredients:
Unknown
Effects of overexposure:
Ingestion may cause nausea or diarrhea. May be irritating to eyes.
Medical Conditions aggravated by use:
Unknown
First Aid Procedures:
INGESTION:
Do not induce vomiting, drink plenty of water, contact a physician immediately.
SKIN/EYE CONTACT: Flush with water for 15 minutes. If irritation persists, consult a physician.
SECTION VII - Pre cautions for Safe Handling and Use
In case of Release or Spill:
Recover liquid with absorbent. Mop up or wet vac. Rinse area with water to remove.
Waste Disposal Method:
Small amounts - down drain or sanitary landfill. Large amounts - obey local ordinances.
Handling and Storing:Do not store near heat. Do not freeze.
Other Precautions:
If frozen, thaw to room temperature and mix before using. Do not pour unused portion back into container - it
contaminate product.
SECTION VIII - Control Measures
Gloves:
None
Eye Protection:
None
Other Protection:
None

Respirator:
Ventilation:
Work/Hygienic Practices:

may

None
Local exhaust is normally adequate.
Follow good manufacturing and housekeeping rules.

SECTION IX - Special Precautions - None
SECTION X - Department of Transportation
Shipping Hazard Classification: None
DISCLAIMER
The information contained herein was obtained from current and reliable sources. However, the data is provided without any warranty, expressed or
implied, regarding its correctness or accuracy. Since the conditions for use, handling, storage and disposal of this product are beyond Scot Laboratories'
control, it is the user's responsibility both to determine safe conditions for use of this product and to assume liability for loss, injury, damage or expense
arising from the product's improper use. No warranty, expressed or implied, regarding the product described herein shall be created by or inferred from
any statement or omission in this MSDS. Various government agencies (e.g., DOT, EPA, FDA) may have specific regulations concerning the
transportation, handling, storage, use or disposal of this product which may not be reflected in this MSDS. The user should review these regulations to

ensure full compliance.

Manufactured By:

Product Name:

PRODUCTS CHEMICAL COMPANY

CARPET SPOT CLEANER

6400 Herman Av Cleveland OH 44102

216-281-1155

EMERGENCY: phone number involving spill, leak, fire or accident:
MATERIAL SAFETY DATA

INFOTRAC 800-535-5053

(Prepared According to 29CFR 1910,1200)

1611

SECTION 1 -- PRODUCT IDENTIFICATION

Product Code #

PRODUCT NAME:

HMIS Rating

Health
Fire
Reactivity
Personal Protection

PRODUCT TYPE: CARRPET SPOT CLEANER
COMPANY NAME:
COMPANY ADDRESS:
Proper Shipping Name: COMPOUND, CLEANING LIQUID, NOI

CAS NO.

SULFONIC ACID

27176-87-0

2 BUTOXYETHANOL

111-76-2

...
...
...
...

1
0
0
B

Formula Proprietary

SECTION 2 -- INGREDIENTS
CHEMICAL NAME

1611

PERCENT WT

Revision Date: 08/06

313 / CHEM

5 to 10

N

7.813

Y

PEL

TWA-TLV

CARCINOGEN
NO

25ppm

25ppm

Yes

NOTE: This product contains materials subject to the reporting requirements of SARA, Section 313 Emergency Planning & Right-to-Know Act.
The balance of the chemicals in this mixture are either considered nonhazardous or are below the listing limits for hazardous substances.
These chemicals are considered trade secrets. The specific identity of these chemicals is available to health professionals.

SECTION 3 -- PHYSICAL DATA

SECTION 4 -- FIRE AND EXPLOSION DATA

212
Boil Point
Specific Gravity
Volatile:
Vapor Press.(mmhg) 20@68f
VaporDensity (AIR=1) N/A
pH
Soluble in water Evap. Rate(H20=1) = 1
VOC = 82.9 (g/l) VOS of Concentrate = 7.9%
CLEAR LIQUID/CHARACTERISTIC
Appearance / Odor:

1.046
90
10

SECTION 5 -- REACTIVITY DATA

Flash Point:
N/A (TCP)
Flammable Limits:
N/A
Non-Flammable
Extinguishing Media:
N/A
Special Fire Fighting Procedures:
Fire, Explosion Hazards:
N/A
SECTION 6 -- STORAGE AND HANDLING

Stability: STABLE
Hazardous Polymerization: WILL NOT OCCUR
NONE KNOWN
Incompatibility:
NONE KNOWN
Hazardous Decomposition:

KEEP OUT OF THE REACH OF CHILDREN
For industrial use only

SECTION 7 -- HEALTH AND FIRST AID
EYES: May Cause eye irritation.

EYES: Flush eyes with large amounts of water. Consult
physician if irritation continues.

SKIN: May cause skin irritation.

SKIN: Flush with water.

INHALATION:

INHALATION: Move person to fresh air. Consult physician

INGESTION: May cause irritation to the intestine, mouth, throat,
& esophagus.

INGESTION: Do not induce vomiting or give anything by mouth
to an unconscious person. Consult Physician.

SECTION 8 -- SPECIAL PROTECTION DATA
Respiratory Protection: Adequate ventilation
Ventilation as required to maintain TLV
Protective Gloves: Rubber Gloves Recommended.
Eye Protection: Safety Glasses Recommended
N/A = Not Applicable

SECTION 9 -- SPILL OR LEAK PRECAUTIONS
Steps to be taken in case of spill or leak:
Mop or absorb for disposal
Waste disposal Method:
Sewer or incinerate with local approval.

CMP = Complete
END OF GENERATE

Spot Shot Carpet and Stain Remover
5/25/05

Material Safety Data Sheet (MSDS)
Section 1 - Chemical Product and Company Identification
MANUFACTURER/SUPPLIER:
US Office:
Spot Shot Products
A Division of WD-40 Company
1061 Cudahy Place
San Diego, CA 92110
Information Phone #: (619) 275-1400
Emergency Phone # 24 hr:
Chemtrec: (800) 424-9300 –
Designated for use only in the event of chemical
emergencies involving a spill, leak, fire exposure or
accident involving chemicals.

Canadian Office:
WD-40 Products [Canada] LTD.
P.O. Box 220
Toronto, Ontario M9C 4V3
Information Phone #: (416) 622-9881
Emergency Phone # 24 hr:
Canutec: (613) 996-6666 –
Designated for use only in the event of chemical
emergencies involving a spill, leak, fire exposure or
accident involving chemicals

PRODUCT NAME: SPOT SHOT CARPET STAIN REMOVER (14 oz.)
FORMULA: Mixture
GENERAL CLASS: Aerosol Cleaning Aid
MSDS DATE OF PREPARATION: May 25, 2005

HMIS Rating
Health: 2
Flammability: 2
Reactivity: 1

Section 2 - Composition/Information on Ingredients
Ingredient
2-Butoxyethanol
Liquefied Petroleum Gas
See Section 8 for Exposure Limits

CAS #
111-76-2
68476-85-7

Weight Percent
Less than 25%
Less than 10%

Section 3 – Hazards Identification
AEROSOL SPRAY. PLEASANT ODOR. CAUTION! CONTENTS UNDER PRESSURE. AVOID HEAT
AND FLAMES. MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. HARMFUL
IF INTENTIONALLY INHALED. HARMFUL IF ABSORBED THROUGH SKIN. MAY AFFECT
LIVER, KIDNEYS, BLOOD, LYMPHATIC SYSTEM OR CENTRAL NERVOUS SYSTEM.
Avoid breathing concentrated vapors. Use with adequate ventilation. Avoid getting on skin, in eyes, and on
clothing. Wash thoroughly after handling.
Potential Health Effects:
Primary Routes of Entry: Inhalation, skin and eye contact.
Acute Effects:
Inhalation: Excessive inhalation can cause headache, drowsiness, nausea and lack of coordination. Can
cause irritation of respiratory tract.
Skin Contact: Can cause skin irritation. Toxic amounts may be absorbed through the skin with symptoms
similar to those under inhalation and ingestion.
Eye Contact: Liquid sprayed into eyes causes corneal irritation and pain.
Ingestion: Symptoms are similar to those of inhalation including pain, diarrhea and vomiting. May cause
damage to the liver and kidneys.
Chronic Effects: 2-butoxyethanol has caused lymphatic system, blood, liver and kidney damage.
Medical Conditions Aggravated by Exposure: Pre-existing respiratory, skin, eye, liver, kidney and
lymphatic disorders.

Page 1 of 4

Spot Shot Carpet and Stain Remover
5/25/05
Section 4 – First Aid Measures
IF INHALED: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical attention.
IF SWALLOWED: Do not induce vomiting. Call a physician or poison control center. Give one eightounce glass of water to drink if the patient if conscious and responsive. Never give anything by mouth to an
unconscious person.
IF ON SKIN: Wash skin with soap and water. Remove contaminated clothing and wash before reuse. Get
medical attention if irritation persists or symptoms of exposure develop.
IF IN EYES: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Get medical attention if irritation persists.
Section 5 – Fire Fighting Measures
Flammability Properties: Not flammable per flame projection test.
Extinguishing Media: Carbon dioxide, dry chemical, water fog
Special Fire Fighting Instructions: Keep fire-exposed containers cool with water spray. In the event of a
fire, wear full protective clothing and a NIOSH approved self-contained breathing apparatus with full face
piece and operated in positive pressure mode.
Unusual Fire and Explosion Hazards: Exposure of containers to extreme heat and flames can cause them to
rupture often with violent force and subsequent fire.
Section 6 – Accidental Release Measures
Ventilate area of spill and remove all sources of ignition. Observe all hazards mentioned in Section 3. Wear
personal protective equipment specified in Section 8.
Spills: Wipe, scrape or soak up contents in an inert material. Pick up spill for recovery or disposal and place
in a closed container.
Section 7 – Handling and Storage
Handling: Use with adequate ventilation. Do not smoke or use around open flames or sources of extreme
heat. Intentional misuse by deliberately concentrating vapors and inhaling can be harmful or fatal. Avoid
getting in eyes or on skin and clothing. Do not breathe vapors. Wash thoroughly after handling, and wash
contaminated clothing before reuse.
Storage: Store in a cool, dry ventilated area. Protect from physical damage. Do not store in direct sunlight,
near open flames or above temperatures greater than 120 F. Do not place can in hot water or near radiators,
stoves or other sources of heat.
Section 8 – Exposure Controls/Personal Protection
Occupational Exposure Limits
2-Butoxyethanol
Liquefied Petroleum Gas

20 ppm TWA ACGIH-TLV
50 ppm TWA OSHA PEL skin
1000 ppm TWA ACGIH TLV
1000 ppm TWA OSHA PEL (as propane)

The Following Controls are Recommended for Normal Consumer Use of this Product
Engineering Controls: Good general ventilation is adequate for normal use. When using large amounts,
open windows or use a fan to ventilate the area.
Personal Protection:
Eye Protection: Avoid eye contact. Always spray product away from your face.
Skin Protection: Avoid prolonged or repeated skin contact. Wash hands with soap and water after use.
Respiratory Protection: None required. Use in a well-ventilated area.

Page 2 of 4

Spot Shot Carpet and Stain Remover
5/25/05

For Bulk Processing or Workplace Use the Following Controls are Recommended
Engineering Controls: A system of local and/or general exhaust is recommended to control airborne levels
below the occupational exposure limits.
Personal Protection:
Eye Protection: Safety glasses with side shields or chemical goggles are recommended.
Skin Protection: Wear appropriate protective clothing and chemical-resistant gloves to prevent skin contact.
Wash thoroughly after handling.
Respiratory Protection: Use in a well-ventilated area. Appropriate respiratory protection shall be worn
when applied engineering controls are not adequate to protect against inhalation exposure.
Work/Hygiene Practices: Eye wash facilities should be available. Wash hands before eating and smoking.
Section 9 – Physical and Chemical Properties
Vapor Pressure:
Specific Gravity (Water = 1):
Boiling Range: Solubility in water (20 C):
Appearance and Odor:

55 psig @ 70 F
(propellant)
N/D
43 F – 343F (propellant)
miscible
Aerosol spray. Pleasant
odor.

Vapor Density (air = 1):

>1

Evaporation Rate (Butyl
Acetate = 1):
% Volatiles by Volume:
VOC’s lbs/gal:
Coefficient of Water/Oil
Distribution:

Less than 1
N/D
N/D
N/D

Section 10 – Stability and Reactivity
Stability: Stable under normal storage conditions.
Hazardous Polymerization: Will not occur
Conditions to Avoid: Extreme heat, sources of ignition, physical damage to can.
Incompatibilities: Avoid strong oxidizers, strong bases, acids and chlorinated solvents.
Hazardous Decomposition Products: Burning can produce carbon monoxide and/or carbon dioxide and
trace amounts of phosgene gas.
Section 11 – Toxicological Information
2-Butoxyethanol
Inhalation LC50 (ppm) 4-HR: 450 (RAT) Acute oral LD50 (mg/kg): 1,480 (RAT)
Acute Dermal LD50 (kg/kg): 490 (RBT) Irritation, Skin, open, 500 mg: MILD (RBT)
Irritation, Eye, 18 mg: SEVERE (RBT)
Liquefied Petroleum Gas: No data is available
Section 12 – Ecological Information
This product is not expected to be harmful for the environment.
Section13 Disposal Considerations
Aerosol containers should not be punctured, compacted in home trash compactors or incinerated. Empty
containers may be disposed of through normal waste management options. Dispose of all waste product,
absorbents, and other materials in accordance with applicable Federal, state and local regulations.
Section 14 – Transportation Information_
DOT Classification: Consumer Commodity ORM-D

Page 3 of 4

Spot Shot Carpet and Stain Remover
5/25/05
Section 15 – Regulatory Information
SARA 302: None found
SARA 311/312 Hazard Categories: Immediate (acute), Chronic (delayed), Flammability
SARA 313: Toxic Chemicals: 2-butoxyethanol 17% by wt. (glycol ether compound)
OSHA: Hazardous under criteria of the OSHA Hazard Communication Standard (29 CFR 1910.1200)
California Proposition 65: No components listed.
Canadian Environmental Protection Act: All of the ingredients are listed on the Canadian Domestic
Substances List.
Canadian WHMIS Classification: Class D, Division 2, Subdivision B (Toxic material causing other chronic
effects)
This MSDS has been prepared according to the criteria of the Controlled Products Regulation (CPR) and
the MSDS contains all of the information required by the CPR.
Section 16 – Other Information__
HMIS Hazard Rating: Health – 2 (moderate hazard), Fire Hazard – 2 (moderate hazard),
Reactivity – 1 (low hazard)
Prepared By: Industrial Health & Safety Consultants, Inc.
Revision Date: 05/25/2005

Supercedes: 02/18/05

This MSDS complies with OSHA guidelines set by 29 CFR 1910.1200 and the Canadian WHMIS
regulations. The foregoing information has been compiled from sources believed to be accurate but is not
warranted to be. Recipients are advised to confirm in advance of need that data is correct. Standards change
without notice. It is the responsibility of the recipient to insure that their personnel have been notified of
any changes which may affect them. The data provided on this MSDS are not meant to be used as
specifications, only as guideline information as to the safe use of this product. User should refer to
applicable laws before use.
N/D = Not Determined N/E = Not Established N/A = Not Applicable

Page 4 of 4

Material Safety Data Sheet
DRAIN FLOW Inhibited Sulfuric Acid

Conforms with OSHA form OMB No. 1218-0072

Roebic Laboratories, Inc.
25 Connair Road, PO Box 927
Orange, CT 06477

Emergency Telephone NumbersROEBIC (203) 795-1283
CHEMTREC (800) 424-9300

(Note: Emergency numbers are to be used only in the event of chemical emergencies involving a spill,
leak, fire, exposure, or accident)
Date: 01/01/01
Preparer: Dave Lawler

Packaging Lot No.: Stamped on carton top

SECTION I – PRODUCT IDENTIFICATION
Product Name
Common Synonyms
Chemical Family
Formula
CAS No.
Precautionary Labeling

US Precautionary Labeling

International Labeling

DRAIN FLOW
Drain Opener, (Blended Sulfuric Acid)
Sulfuric Acid
H2S04 (Approx. 90%)
7664-93-9 (sulfuric acid)
Health 3
Flammability 0
Reactivity 0
Contact 2
Do not get in eyes, on skin, or on clothing. Do not take internally. Avoid
breathing mist or fumes. Keep separate from powdered metals,
organics, combustible materials, solvents, oxidizers, alkalis, and amines.
Keep out of reach of children.
Do not get in eyes, on skin, or on clothing. Do not take internally. Avoid
breathing mist or fumes. Keep separate from powdered metals,
organics, combustible materials, solvents, oxidizers, alkalis, and amines.
Keep out of reach of children.
SECTION II – COMPONENTS

Component
Diluted Sulfuric Acid
Fortifying Agents

CAS No.
Wt %
7664-93-9
80
N/A (none carcinogenic)

OSHA/PEL
N/A

ACGIH/TLV
1-mg/m3

SECTION III – PHYSICAL DATA
Boiling Point
Freezing Point
Specific Gravity
Water Solubility
pH
Viscosity
Odor
Appearance

221°F 105C
-20°F -10C
1.75
Complete
1.25
30 SSU @ 100F 32.7C
Sulfur (sulfur trioxide fumes)
Viscous Black Liquid (for safety identification)
SECTION IV – FIRE, REACTIVITY, & EXPLOSION DATA

Non-Flammable:
Extinguishing Media:
Fire Fighting Techniques:
Toxic Gas Produced:
Explosion Data:

But explosive hydrogen gas can accumulate if transferred into metal
containers.
Use extinguishing media appropriate for surrounding fire.
Wear full protective clothing including self-contained breathing apparatus
with full-face piece operated in a positive pressure mode.
Reaction with certain metals can produce flammable hydrogen gas.
Provide adequat e ventilation when applying.
No sensitivity to mechanical impact. No sensitivity to static discharge.

1

SECTION V – HEALTH HAZARD DATA
Toxicity of Components

Carcinogenic: None Identified
Reproductive effect: None identified
Effects of Overexposure
Inhalation: Irritation of upper respiratory tract
Skin Contact: Irritation
Eye Contact: Irritation
Ingestion: Internal irritation
Emergency and First Aid Procedures
Inhalation: Remove from contaminated atmosphere.
Apply artificial respiration if necessary. Call a physician.
Skin Contact: Flush with cool water, then baking soda solution. If
irritation persists get medical attention.
Ingestion: Give large quantities of water or milk. Do not induce
vomiting. Do not drink carbonated water. Call a physician.
Eye Contact: Immediately flush with large quantities of water. Call a
physician.
SECTION VI – REACTIVITY DATA
Stability
Conditions to Avoid

Decomposition

Stable
Do not allow product to come in contact with strong alkalis. May cause eruption
of hot acid when poured in drain. Do not mix with other household chemicals.
Never add water to acid while in container because of violent reaction. When
empty rinse thoroughly with water before discarding.
Sulfur fumes
SECTION VII – SPILLS AND DISPOSAL PROCEDURES

Small Spill
Large Spill

Neutralize with sodium bicarbonate or soda ash and flush with large amounts of
water.
Pump to a soda ash and slack lime solution, then dispose of with large amounts
of water.
SECTION VIII – INDUSTRIAL PROTECTIVE EQUIPMENT

Ventilation:
Respiratory Protection:

Eye and Skin Protection:

Use general or local exhaust ventilation to meet TVL
requirements and to minimize exposure.
Respiratory protection is required if airborne concentrations
exceed TLV. Above this level use NIOSH approved equipment
with full-face piece. Follow respirator manufacturer’s
recommendations.
Safety goggles, protective clothing and rubber or plastic gloves
are recommended.

SECTION IX – STORAGE AND HANDLING PRECAUTIONS
Storage

Store in high-density polyethylene, rubber lined, fiber glass, or 316 stainless steel
containers. Do not store in extreme heat or cold areas. Avoid contact with organic
matter. DRAIN FLOW is a strong chemical digester of dead organics.
SECTION X - TRANSPORTATION DATA AND ADDITIONAL INFORMATION

Domestic (D.O.T.)
Proper Shipping Name
Hazard Class
UN/NA
Labels
Frt. Classification

Sulfuric Acid 66 Be (blended with buffing agents)
Corrosive Material
UN1830/NA
Corrosive
Cleaning Compound – Class 55

2

International (I.M.O.)
Proper Shipping Name
Hazard Class
UN/NA
Labels
Marine Shipping
Air Shipping

Sulfuric Acid 66 Be (blended with buffing agents)
Corrosive Material
UN1830/NA
Corrosive
Non-pollutant
Not allowed on passenger flights
SECTION XI – OTHER COMMENTS

This document is intended only as a guide. The user is responsible for determining the precautions and
dangers of this chemical formulation for his/her particular application. Supplier cannot warn of all the
potential dangers of use or interaction with other chemicals or materials, therefore; disclaims any
warranties, expressed or implied with regard to its merchantability or its fitness for a particular purpose.
The user is responsible for reading all precautionary information and handling accordingly.

3

Institutional 80240

JSDYL

T

MATERIAL SAFETY
DATA SHEET
I - PRODUCT IDENTIFICATION AND USE

PRODUCT NAME:
USE:

MSDS ID: 80240

DISHWASHER ALL

Machine Warewashing Detergent

SUPPLIER:

EMERGENCY PHONE:

JohnsonDiversey Canada, Inc.
2401 Bristol Circle
Oakville Ontario, L6H 6P1, Canada

WHMIS CLASSIFICATION:
CHEMICAL FAMILY:

1-800-668-7171

D2B

TRADE NAME / SYNONYMS:

Chlorinated alkali

CHEMICAL NAME:

not applicable

not applicable

II - HAZARDOUS INGREDIENTS
HAZARDOUS INGREDIENT

% w/w

CAS #

LD50 / LC50

Route / Species

30-60

000497-19-8

LD50 4090 mg/kg

oral/rat

Sodium carbonate
Disodium dichlorosiocyanuratedihydrate
Sodium metasilicate

1-5

051580-86-0

LD50 620 mg/kg

oral/rat

7-13

006834-92-0

LD50 1153 mg/kg

oral/rat

1-5

069227-21-0

LD50 3400 mg/kg

oral/rat

Linear alcohol ethoxylate/propoxylate

III - HANDLING AND DISPOSAL PROCEDURES
PERSONAL PROTECTIVE EQUIPMENT:
Gloves:

Nitrile, Neoprene or Natural rubber

Respiratory:

Eye:

safety glasses

NIOSH approved dust mask as required.

SPECIAL HANDLING PROCEDURES AND EQUIPMENT:
VENTILATION REQUIREMENTS:

WASTE DISPOSAL:

not required

Other: not required
Avoid breathing dust. Avoid eye and skin contact.

General ventilation.

INCOMPATIBILITY (Material to Avoid):
SPILL PROCEDURES:

Footwear:

Strong acids

Sweep or scoop up material for disposal.

Dispose according to municipal, provincial, and federal regulations.

STORAGE / SHIPPING REQUIREMENT:

Store in a cool dry area in a closed container.

IV - PHYSICAL PROPERTIES
APPEARANCE / ODOUR:

White, free-flowing powder with blue speckles - floral odour

S.G. / BULK DENSITY(g/cc):

1.00 - 1.09

VAPOUR PRESSURE (mmHg):
ODOUR THRESHOLD:
FREEZING POINT:

pH:

not applicable

VAPOUR DENSITY (air=1):

0.2-0.4 ppm chlorine

BOILING POINT:

not applicable

SOLUBILITY IN WATER:

(0.1% solution) 11.0 ± 0.5

PERCENT VOLATILE:

soluble

not applicable

not applicable
not applicable

EVAPORATION RATE (water=1):

not applicable

V - TOXICOLOGICAL PROPERTIES
EFFECTS OF ACUTE EXPOSURE TO MATERIAL:
EYES:

May cause severe irritation. May cause permanent damage if not treated promptly.

SKIN:

Repeated or prolonged contact may result in irritation.

INGESTION:

May cause severe irritation of the digestive tract. May cause temporary or permanent damage if not treated promptly.

INHALATION: Breathing dust may cause respiratory irritation.

JohnsonDiversey Material Safety Data Sheet:

DISHWASHER ALL

Page

1 of 2

Institutional 80240

LD50 (calculated):

4462 mg/kg

OTHER TOXIC EFFECTS:

LC50 (calculated):

Not applicable

TLV (Sodium metalsilicate): 2 mg/m3

EFFECTS OF CHRONIC
EXPOSURE TO MATERIAL:

None known.

VI - FIRST AID MEASURES
EYES:

Flush eyes with plenty of water for at least 15 minutes. Hold eyelids open while rinsing. Contact a physician immediately.

SKIN:

Flush affected area thoroughly with water. If irritation develops, contact a physician.

INGESTION:

Drink large volumes of water . Never give anything by mouth to an unconscious patient. Do not induce vomiting. Contact a
physician immediately.

INHALATION: Remove patient to fresh air. Get medical attendion for any breathing difficulty.

VII - FIRE AND EXPLOSION DATA
FLAMMABLE:

No.

FLASH POINT, °C:

not applicable

EXTINGUISHING MEDIA:

Water [x]

AUTO IGNITION TEMPERATURE,°C:
Dry Chemical [x]

Carbon Dioxide [x]

SPECIAL FIRE FIGHTING PROCEDURES:

Wear self-contained breathing apparatus.

HAZARDOUS COMBUSTION PRODUCTS:

Chlorine gas. Oxides of carbon, nitrogen.

EXPLOSIVE SENSITIVITY TO:

Foam [x]

N/Ap

Other [ ]

not applicable

VIII - REACTIVITY DATA
STABILITY:

Stable [x]

CONDITIONS TO AVOID:

Unstable [ ]
not applicable

INCOMPATIBILITY (Material to Avoid) :
HAZARDOUS DECOMPOSITION PRODUCTS:
REACTIVITY:

Acids.
Contact with acids generates chlorine gas. Chloramines.

not dangerously reactive

IX - MSDS PREPARATION
SOURCES USED:

PREPARATION DATE:

RTECS, ChemInfo

PREPARED BY:

April 15, 2003

JohnsonDiversey Canada, Inc.
Regulatory Department
Institutional Division
Phone (905) 829-1200

Information on this form is furnished in compliance with the Regulations respecting Controlled Products under the Hazardous Products Act and is
not to be used for any other purpose, nor is it to be reproduced or published. JohnsonDiversey Canada assumes no responsibility for injury to any
person or property resulting from any use of the material if reasonable safety procedures are not adhered to. In addition, JohnsonDiversey Canada
assumes no responsibility for injury to any person or property resulting from any abnormal use or theft of the material, even if reasonable safety
procedures are followed. Each user assumes the risk in his use of the material and should review the data and recommendations in the specific
context of the intended use.

JohnsonDiversey Material Safety Data Sheet:

DISHWASHER ALL

Page

2 of 2

Industrial

______________________________________________________________________________
MATERIAL
__________________________
SAFETY DATA SHEET
Page
1 of 3
Revised
2/02/04
WHITE LOTION HAND SOAP
Replaces 8/12/03
Printed
2/03/04
MSDS
______________________________________________________________________________
ID: 04617
______________________________________________________________________________
______________________________________________________________________________
I. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name:
Product Discriptor:
MANUFACTURER: JOHNSONDIVERSEY, INC.
3630 E. KEMPER ROAD
CINCINNATI, OH. 45241

EMERGENCY PHONE NUMBER:(800)851-7145

______________________________________________________________________________
______________________________________________________________________________
II. HAZARDOUS COMPONENTS
Component Name
CAS Number
%
Exposure Limits Units
----------------------------- ----------- ---------- ---------------- ------WHITE LOTION HAND SOAP
>30%
None established
______________________________________________________________________________
______________________________________________________________________________
III. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
SIGNS AND SYMPTOMS OF OVEREXPOSURE
ACUTE:
MAY IRRITATE EYES
CHRONIC: SAME AS ACUTE
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Sensitive skin
______________________________________________________________________________
______________________________________________________________________________
IV. FIRST AID MEASURES
______________________________________________________________________________
______________________________________________________________________________
V. FIRE FIGHTING MEASURES
FLASH POINT (degrees F): NONE
FLAME EXTENSION: N/A
FLAMMABLE LIMITS IN AIR BY VOLUME:
LEL: N/A
UEL: N/A
EXTINGUISHING MEDIA: CO2, FOAM, DRY CHEMICALS
FIRE FIGHTING INSTRUCTIONS: Wear full protective gear and positive pressure
breathing apparatus (SCBA) in fire area.
______________________________________________________________________________
______________________________________________________________________________
VI. ACCIDENTAL RELEASE MEASURES
IF MATERIAL IS RELEASED OR SPILLED:
FLUSH TO DRAIN AND RINSE TO AVOID SLIPPERY CONDITIONS
This product does not contain a reportable quantity (RQ) under CERCLA.
______________________________________________________________________________
______________________________________________________________________________
VII. HANDLING AND STORAGE
HANDLING AND STORAGE PRECAUTIONS: DO NOT SPILL. WILL CAUSE A SLICK WORKING
SURFACE. KEEP FROM FREEZING. IF FROZEN, THAW AND MIX TO MAKE USABLE. DO NOT
PRESSURE CONTAINER TO EMPTY.

Industrial

______________________________________________________________________________
MATERIAL
__________________________
SAFETY DATA SHEET
Page
2 of 3
Revised
2/02/04
WHITE LOTION HAND SOAP
Replaces 8/12/03
Printed
2/03/04
MSDS
______________________________________________________________________________
ID: 04617
______________________________________________________________________________
______________________________________________________________________________
VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION
EYE/FACE PROTECTION: NONE
PROTECTIVE GLOVES: NONE
OTHER PROTECTIVE CLOTHING/EQUIPMENT: NONE
ENGINEERING CONTROLS:
MECHANICAL VENTILATION: PRODUCING NORMAL AIR DILUTION
LOCAL VENTILATION: NO
______________________________________________________________________________
______________________________________________________________________________
IX. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE AND ODOR:
BOILING POINT (DEG F): 212
FREEZING POINT: Not determined
SPECIFIC GRAVITY/BULK DENSITY:
pH:
pH 1% SOLUTION: Not Determined
VOLATILE BY VOLUME: 80
VAPOR PRESSURE(mmHg): 17.5
at 20 F
VAPOR DENSITY: N/A
______________________________________________________________________________
______________________________________________________________________________
X. STABILITY AND REACTIVITY
CHEMICAL STABILITY: STABLE
INCOMPATIBILITY WITH OTHER MATERIALS: CO WITH INCOMPLETE COMBUSTION
HAZARDOUS DECOMPOSITION PRODUCTS: None known.
HAZARDOUS POLYMERIZATION: NONE
______________________________________________________________________________
______________________________________________________________________________
XI. TOXICOLOGICAL INFORMATION
No data available.
TOXICITY TEST DATA:
No data available.
______________________________________________________________________________
______________________________________________________________________________
XII. ECOLOGICAL INFORMATION
ECOTOXICITY TEST DATA: No data available.
ENVIRONMENTAL FATE: No data available.
______________________________________________________________________________
______________________________________________________________________________
XIII. DISPOSAL CONSIDERATIONS
RCRA REGULATED: Not Regulated.
POUR OR FLUSH DOWN DRAIN OR LAND FILL. CONTAINS NO PHOSPHATES, 100%
BIODEGRADABLE. USE UNTIL LESS THAN 1 INCH REMAINS IN CONTAINER, EMPTY
CONTAINER TRIPLE RINSE WITH WATER, ADD TO OPERATION REMOVE OR DEFACE LABEL
BEFORE SELLING CONTAINER OR DISPOSAL
______________________________________________________________________________
______________________________________________________________________________
XIV. TRANSPORT INFORMATION
Please refer to the Bill of Lading/receiving documents for up to date shipping
information.

Industrial

______________________________________________________________________________
MATERIAL
__________________________
SAFETY DATA SHEET
Page
3 of 3
Revised
2/02/04
WHITE LOTION HAND SOAP
Replaces 8/12/03
Printed
2/03/04
MSDS
______________________________________________________________________________
ID: 04617
______________________________________________________________________________
______________________________________________________________________________
XV. REGULATORY INFORMATION
U.S. Federal Regulations:
TSCA: All ingredients in this product are on TSCA inventory.
HAPS: Contains no hazardous air pollutants.
VOC CONTENT (EPA Method 24A): % VOC:
Lb/Gal VOC:
CERCLA/EPCRA:
Section 313 Toxic Chemicals: None
SARA Section 311/312:
ACUTE:NO
CHRONIC:NO
FIRE:NO
REACTIVITY:NO
SUDDEN RELEASE OF PRESSURE:NO
LISTED CARCINOGEN: NONE
NTP: NO
IARC: NO
OSHA: NO
HMIS RATINGS: HEALTH:
FIRE:
REACTIVITY:
PERSONAL PROTECTIVE EQUIPMENT:
NFPA RATING: HEALTH:
FIRE:
REACTIVITY:
SPECIAL:
STATE RIGHT-TO-KNOW INFORMATION:
CALIFORNIA PROPOSITION 65:
None of the ingredients are on the California proposition 65 list.
______________________________________________________________________________
______________________________________________________________________________
XVI. OTHER INFORMATION
DISCLAIMER: The information contained in this material safety data sheet is
based on the knowledge of this specific product and current national legislation. It applies to the product as sold, use dilutions may be less hazardous.
It may not be valid for this material if used in combination with any other
materials or in a process. It is the user's responsibility to evaluate the
handling, and use.

MATERIAL SAFETY DATA SHEET
Effective Date: 08/06

(Prepared According To 29 CFR 1910.1200)

N/A = Not Applicable

SECTION 1 - PRODUCT IDENTIFICATION
Product Name: North Woods™ Natures Stuff
Chemical Family: N/A
Generic Name: Citrus Hand Cleaner
Formula: N/A
Suppliers Name: SUPERIOR CHEMICAL CORP.
Suppliers Address: 1331 Wisconsin Avenue, Sheboygan, WI 53081
Phone: 800-242-7694
EMERGENCY PHONE: 800-535-5053

NPCA Hazardous Materials
Identification System

Health

0

Flammability

1

Reactivity

0

Maximum Personal Protection

A

SECTION 2 - HAZARDOUS INGREDIENTS
CHEMICAL NAME

CAS NO.

WT.%

PEL

TWA-TLV

STEL-TLV

CARCINOGEN

No hazardous ingredients.

SECTION 3 - PHYSICAL DATA
Specific Gravity: 0.963
Boiling Range (˚F): 175°F
Vapor Density: <1.0
Vapor Pressure: N/D
pH: 6.8 - 7.4
% Volatile: N / A
Evaporation Rate: >1.0
Solubility in Water: Soluble
Physical Description: Yellow, opaque liquid; pleasant citrus fragrance.

SECTION 5 - REACTIVITY DATA

SECTION 4 - FIRE & EXPLOSION HAZARD DATA
Flash Point (method used): N / A
Upper Explosive Limit: N/A
Lower Explosive Limit: N/A
Extinguishing Media: Foam, carbon dioxide, dry chemical.
Special Fire Fighting Procedures: Self contained breathing apparatus.
Unusual Fire & Explosion Hazards: Cool fire exposed containers with
water spray.

SECTION 6 - STORAGE & HANDLING INFO

Hazardous Polymerization: Will not occur.
Stability: Stable
Precautions To Be Taken In Handling & Storage:
Incompatibility (materials to avoid): Strong acids and oxidizing agents. Keep out of reach of children. For institutional and industrial use only.
Store in a cool, dry place, away from heat or open flame. Keep continer
slightly closed when not in use.
Hazardous Decomposition Products: Thermal decomposition may
yield oxides of carbon.

SECTION 7 - HEALTH HAZARDS AND FIRST AID
Effects of Overexposure
Primary Route of Entry:
Skin: Irritation.

First Aid
Procedures:
Skin: Wash with soap and water. If irritation persists, obtain medical
attention.

Eyes: Severe irritation, redness and tearing.

Eyes: Flush eyes and under eyelids with plenty of cool water for at least 15
minutes. Obtain medical attention if irritation persists.

Inhalation: None under normal use.

Inhalation: Remove person to fresh air.

Ingestion: Gastrointestinal irritation, nausea, vomiting, diarrhea.

Ingestion: Contact physician or poison center immediately. DO NOT
INDUCE VOMITING. Never give anything by mouth to an
unconscious person.

SECTION 8 - SPECIAL PROTECTION INFORMATION
Respiratory Protection: Use adequate ventilation.

Ventilation: General ventilation should be sufficient for most conditions.
Local exhaust ventilation may be necessary for some operations.

Protective Gloves: Not required.
Other Protective Equipment: None.

Eyes: None.

SECTION 9 - SPILL OR LEAK PROCEDURES
Steps to be taken in case material is released or spilled:
Mop up or otherwise absorb and hold material for disposal.

Waste disposal method:
Any method in accordance with applicable laws.

Notice to reader: To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability
whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials
may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

MATERIAL SAFETY DATA SHEET
SECTION I – MATERIAL IDENTIFICATION AND USE
MATERIAL NAME: SUPER STRENGTH BOWL CLEANER

4521-253
4521-253

900mL

MANUFACTURERS NAME:
CP INDUSTRIES LTD.
225 BLACK STREET
FERGUS, ONTARIO N1M 1A5

SUPPLIERS NAME:
HOME HARDWARE
34 HENRY STREET WEST
ST JACOBS, ONTARIO N0B 2N0

EMERGENCY TELEPHONE NUMBER: (613) 996-6666

EMERGENCY TELEPHONE NUMBER: (613) 996-6666

Non-Office Hours, Weekends, or Holidays – (CANUTEC) Call Collect

Non-Office Hours, Weekends, or Holidays – (CANUTEC) Call Collect

CHEMICAL NAME
Not Applicable (mixture)
MOLECULAR WEIGHT
Not Applicable

CHEMICAL FAMILY
Mineral Acid
TRADE NAME AND SYNONYMS
Not Available

CHEMICAL FORMULA
Not Applicable
MATERIAL USE
WHMIS CLASS
Toilet Bowl Cleaner
E D1A

SECTION II – HAZARDOUS INGREDIENTS OF MATERIAL
HAZARDOUS INGREDIENTS

Hydrogen Chloride

APPROXIMATE
CONCENTRATION %

10 - 20

C.A.S.N.A.

“EXPOSURE LIMITS”

LD50 / LC50
SPECIFY SPECIES & ROUTE

007647-01-0

TLV (ACGIH) 5 ppm
Ceiling

Hydrochloric Acid:
LD50 Not Determined
LC50 3124 ppm for 1 hour
(inhalation/rat)

SECTION III – PHYSICAL DATA FOR MATERIAL
PHYSICAL STATE
GAS LIQUID X SOLID

ODOUR AND APPEARANCE
ODOUR THRESHOLD
Clear dark blue liquid, slight pungent odour Not Available

SPECIFIC GRAVITY
1.08

VAPOUR PRESSURE (mm)
Not Available

VAPOUR DENSITY (Air=1)
Not Available

BOILING POINT (°C)
Not Available

EVAPORATION RATE
Not Available

FREEZING POINT (°C)
SOLUBILITY IN WATER
-10°C approx.
Infinite
COEFFICIENT OF WATER/OIL DISTRIBUTION: Not Available

% VOLATILE (by volume)
99% (approx.)

pH
Strong acid less than 1

SECTION IV – FIRE AND EXPLOSION DATA
FLAMMABILITY
YES
NO X

IF YES, UNDER WHAT CONDITIONS

MEANS OF EXTINCTION:
None Required. Not Flammable.
SPECIAL PROCEDURES:
Hydrochloric acid itself is non-flammable. There is, however, a latent fire or explosion hazard due to
hydrogen gas generated when acid is in contact with metals. Wear full protective equipment including self contained breathing apparatus.
FLASH POINT (°C) AND METHOD: None
AUTO IGNITION TEMPERATURE (°C): Not Applicable
UPPER EXPLOSION LIMIT (% BY VOLUME): Not Applicable LOWER EXPLOSION LIMIT (% BY VOLUME): Not Applicable
HAZARDOUS COMBUSTION PRODUCTS: Toxic and Corrosive HCL Gas may be released.
EXPLOSION DATA SENSITIVITY TO MECHANICAL IMPACT: Not Applicable
RATE OF BURNING
Not Applicable

EXPLOSIVE POWER
Not Applicable

SENSITIVITY TO STATIC DISCHARGE
Not Applicable

SECTION V – REACTIVITY DATA
CHEMICAL STABILITY
IF NO, UNDER WHAT CONDITIONS?
YES X NO
INCOMPATIBILITY TO OTHER SUBSTANCES IF SO, WHICH ONES?
YES X NO
REACTIVITY AND UNDER WHAT CONDITIONS: Contact with alkalis will generate heat. Contact with most metals will generate
hydrogen gas. Contact with oxidizing chlorinated materials will generate toxic chlorine gas.
HAZARDOUS DECOMPOSITION PRODUCTS: See above

MATERIAL NAME: SUPER STRENGTH BOWL CLEANER
SECTION VI – TOXICOLOGICAL PROPERTIES OF PRODUCT
ROUTE OF ENTRY
SKIN CONTACT:
X
SKIN ABSORPTION:
EYE CONTACT: X
INHALATION ACUTE: X
INHALATION CHRONIC: X
INGESTION:
X
EFFECTS OF ACUTE EXPOSURE TO PRODUCT
EYE:
CORROSIVE. Contact may cause pain, lachrymation (tears), and severe irritation with corneal injury, may even cause
blindness.
SKIN:
CORROSIVE. Short single skin exposure may cause burns.
INHALATION: CORROSIVE. Excessive vapour concentrations inhaled may cause serious adverse effects, even death.
INGESTION: CORROSIVE. May cause burns of the mouth and throat and gastro intestinal irritation and ulceration.
EFFECTS OF CHRONIC EXPOSURE TO PRODUCT: Repeated excessive exposure may cause erosion of teeth and bleeding and
ulceration of nose, mouth and gums.
LD50 OF PRODUCT (SPECIFY SPECIES & ROUTE) IRRITANCY OF PRODUCT EXPOSURE LIMITS OF PRODUCT
Not Determined
High
ACGIH TLV 5 ppm Ceiling
LC50 OF PRODUCT (SPECIFY SPECIES)
Hydrochloric Acid: 3124 ppm for 1 hr (inhal/rat)
CARCINOGENICITY
Not Applicable

SENSITIZATION TO PRODUCT
Not Available

REPRODUCTIVE EFFECTS
Not Available

SYNERGISTIC MATERIALS
None Known

TERATOGENICITY
Not Available

MUTAGENICITY
Not Available

SECTION VII – PREVENTATIVE MEASURES
PERSONAL PROTECTIVE EQUIPMENT
GLOVES
RESPIRATORY (SPECIFY)
Neoprene, Rubber or PVC
Approved air purity respirator if exposure guidelines
or comfort levels may be exceeded.

EYE (SPECIFY)
Chemical Goggles

FOOTWEAR (SPECIFY)
Rubber Boots

OTHER (SPECIFY)
Not Applicable

CLOTHING (SPECIFY)
Apron

ENGINEERING CONTROLS (E.G. VENTILATION, ENCLOSED PROCESS, (SPECIFY): Local mechanical exhaust ventilation to
control airborne contamination below exposure levels.
LEAK AND SPILL PROCEDURE:
Ventilated area. Do not allow spilled material to go to drain. Contain leak or spill, soak
up with sand, ashes, or gravel. Dispose of into covered polyethylene containers.
WASTE DISPOSAL:

Dispose of according to local, provincial, and federal regulations.

HANDLING PROCEDURES & EQUIPMENT:

Use only with adequate ventilation. Avoid eye and skin contact. Avoid breathing
vapours.

STORAGE REQUIREMENTS:

Store in a cool, dry place in a closed container away from heat, metals and oxidizers.

SPECIAL SHIPPING INFORMATION:

Not Applicable.
SECTION VIII – FIRST AID PROCEDURES

SKIN: Immediate, continued and thorough washing in flowing water for 30 minutes, is imperative while removing contaminated clothing.
Seek medical attention immediately.
EYE: Immediate and continuous irrigation with flowing water for at least 30 minutes is imperative. Prompt medical attention is essential.
INHALATION: Remove patient to fresh air if effects occur. Seek medical attention immediately.
INGESTION: DO NOT induce vomiting. Give large amounts of water or milk if available and transport to medical facility immediately.
GENERAL ADVICE: Safety shower and eyewash must be readily available. CORROSIVE. May cause stricture. If lavage is performed,
suggest endotracheal and esophagoscopic control if burn is present, treat as any thermal burn after decontamination.
SECTION IX – PREPARATION DATE OF MSDS
ADDITIONAL INFORMATION/COMMENTS: None
SOURCES USED: Supplier MSDS
PREPARED BY:

CP INDUSTRIES LTD. PHONE NUMBER: (519) 843-6300
DEVELOPMENT DEPT.
INSTITUTIONAL DIVISION

DATE: MARCH 24, 2004

MATERIAL SAFETY DATA SHEET
SECTION I - PRODUCT IDENTIFICATION AND USE
Product Identifier:
CLING TYPE BOWL CLEANER
Product Use: HEAVY DUTY BOWL CLEANER FOR USE ON PORCELAIN, PLASTIC TILE,
FIBREGLASS, VITREOUS CHINA AND STAINLESS STEEL.
Supplier:
SHARE CANADA
Address:
1691 CHURCH AVENUE, WINNIPEG, MANITOBA R2X 2Y7
Telephone Number: (204) 633-8553
Fax: (204) 633-8453
CANUTEC: (613) 996-6666

SECTION II - HAZARDOUS INGREDIENTS
Hazardous
ingredients
PHOSPHORIC ACID

CAS Number

7664-38-2

Exposure
limits
1 mg / m

3

Weight %

10

30 %

LD 50

LC50

1530 mg /kg (rat/ oral)
2740 mg /kg (rabbit/
dermal)

SECTION III- PHYSICAL DATA
Physical State:
Specific Gravity (20oC):
Odour and appearance:

LIQUID
1.1
TRANSLUSCENT TO OPAQUE GREEN LIQUID, WINTERGREEN

ODOUR.

Odour threshold:
Not available.
pH:
1.2
Vapour pressure (mm Hg):
2.3 kPa @ 20oC.
Vapour density (air = 1):
1
Evaporation rate (water = 1): 1
% volatile by volume:
Not available.
Solubility in water:
EASILY SOLUBLE IN COLD WATER.
Boiling point (Co):
102 o C.
Freezing point (Co):
Not available.
Coefficient of oil/water distribution: Not available.

SECTION IV - FIRE AND EXPLOSION DATA
Flammable or combustible: Not flammable or combustible. Flash point (Co): NONE
Conditions of flammability: NONE
Upper flammable limit: Not applicable.
Lower flammable limit: Not applicable.
Autoignition temperature: Not applicable. Flammability classification: NONE
Special fire fighting procedures: SPRAY WATER TO COOL CONTAINERS AND CONTROL
VAPOURS. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID BREATHING FUMES.
Means of extinction: SMALL FIRE USE DRY CHEMICAL, CARBON DIOXIDE, WATER
SPRAY OR FOAM, LARGE FIRE USE WATER SPRAY, FOG OR FOAM. DO NOT USE
WATER JET.
Hazardous combustion products: PHOSPHATES AND CARBON OXIDES.
Sensitivity to mechanical impact:
Not sensitive.
Sensitivity to static discharge:
Not sensitive.

SECTION V - REACTIVITY DATA
Is the product stable? STABLE
Conditions of reactivity: DO NOT MIX WITH OTHER CLEANING PRODUCTS.
Incompatible substances: HIGHLY REACTIVE WITH ALKALIS. SLIGHTLY REACTIVE
WITH ORGANIC MATERIALS. NON-REACTIVE WITH OXIDIZING AGENTS, ACIDS.
Hazardous decomposition products: PHOSPHATES AND CARBON OXIDES.

Not found.
.

Product Identifier: CLING TYPE BOWL CLEANER

SECTION VI - TOXICOLOGICAL PROPERTIES
WHMIS CLASSIFICATION: CLASS D2B, E - CORROSIVE MATERIAL
Primary routes of exposure: SKIN AND EYE CONTACTAND INGESTION.
Exposure limits: SEE SECTION II FOR LIMITS FOR INGREDIENTS.
Acute effects of exposure: DANGEROUS IN CASE OF SKIN CONTACT (CORROSIVE,
IRRITANT), OF EYE CONTACT (IRRITANT), OF INGESTION, OF INHALATION. LIQUID OR
SPRAY MIST MAY PRODUCE TISSUE DAMAGE PARTICULARLY ON MUCOUS
MEMBRANES OF EYES, MOUTH AND RESPIRATORY TRACT. Chronic effects of
exposure: REPEATED EXPOSURE MAY CAUSE CHRONIC EYE, SKIN AND RESPIRATORY
TRACT IRRITATION.
Sensitizer: NOT KNOWN TO BE A SENSITIZER.
Carcinogen: NOT LISTED - IARC, NTP, OSHA Mutagen: NOT KNOWN AS A MUTAGEN.

SECTION VII - PREVENTION MEASURES
Gloves: IMPERVIOUS
GLOVES

Respirator: IF VENTILATION IS
INSUFFICIENT, WEAR SUITABLE
RESPIRATORY EQUIPMENT.

Eye protection: SPLASH
GOGGLES, FACE`SHIELD.

Footwear:
RUBBER BOOTS

Clothing: PROTECTIVE
CLOTHING TO PREVENT SKIN
CONTACT.

Other: EYE WASH
STATION AND SAFETY
SHOWER.

Engineering controls: PROVIDE EXHAUST VENTILATION TO KEEP AIRBORNE
CONCENTRATIONS OF VAPOURS BELOW TLV.
Leak and spill procedures: ABSORB WITH INERT DRY MATERIAL AND PLACE IN AN
APPROPRIATE WASTE DISPOSAL CONTAINER.
Waste disposal: DISPOSE ACCORDING TO FEDERAL, PROVINCIAL OR LOCAL
REGULATIONS. CONSULT LOCAL OR REGIONAL AUTHORITIES.
Handling and storage requirements: KEEP LOCKED UP, KEEP CONTAINER TIGHTLY
CLOSED AND DRY. KEEP AWAY FROM HEAT, METALS AND OXIDIZING MATERIALS AND
SOURCES OF IGNITION. STRONG ACIDS THAT ARE NOT STRONG OXIDANTS SHOULD
BE STORED IN A SEPARATE SAFETY STORAGE CABINET OR ROOM. KEEP LOCKED
UP AND OUT OF THE REACH OF CHILDREN. KEEP CONTAINER DRY. DO NOT
BREATHE GAS, FUMES, VAPOUR OR SPRAY. AVOID CONTACT WITH SKIN AND EYES.
KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. KEEP OUT OF THE REACH OF
CHILDREN.
Special shipping information: T.D.G CLASS 8 PHOSPHORIC ACID, LIQUID. UN 1805,
PACKING GROUP III. LIMITED QUANTITY IN CONTAINERS UP TO 5 LITRES.

SECTION VIII - FIRST AID MEASURES
Eye contact: IMMEDIATELY FLUSH EYES AND UNDER EYELIDS WITH PLENTY OF COOL
WATER FOR 15 MINUTES HOLDING THE EYELIDS OPEN. GET MEDICAL ATTENTION.
Skin contact: WASH SKIN WITH PLENTY OF COOL WATER AND NON-ABRASIVE SOAP
AND COVER WITH AN EMOLIENT. IF IRRITATION PERSISTS GET MEDICAL ATTENTION.
Ingestion: CONTACT PHYSICIAN OR POISON CONTROL CENTRE IMMEDIATELY. DO
NOT INDUCE VOMITING. RINSE MOUTH THOROUGHLY. GIVE CONSCIOUS PERSON
SEVERAL GLASSES OF WATER OR MILK. Inhalation: ALLOW THE VICTIM TO REST IN
A WELL-VENTILATED AREA. SEEK IMMEDIATE MEDICAL ATTENTION.

SECTION IX - PREPARATION DATA
Information sources:
Prepared by:
Telephone Number:
Preparation Date:

MANUFACTURER S MSDS, CCOHS CCINFO
SHARE CANADA
(204) 633-8553
September 2, 2005

Atlantic Chemical Equipment Co.
2190 DeFoor Hills Rd NW
Atlanta, GA 30318
404-355-5522

MATERIAL SAFETY DATA SHEET

PRODUCT NAME:

ODOR NEUTRALIZER (ON & ONjr)

EMERGENCY PHONE: 1-800-424-9300

VII - PRECAUTIONS FOR SAFE HANDLING AND USE

May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200.

Standard must be consulted for specific requirements. This product contains
no substances subject to SARA TITLE III and 40 CRF.

HMIS SYMBOLS
HEALTH

1

FLAMMABILITY

1

REACTIVITY

0

STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED:
SMALL SPILLS: Sweep up material and shovel into waste container.
LARGE SPILLS: Contain and collect for reuse.
WASTE DISPOSAL METHOD: Deposit in landfill in accordance with local, State, and Federal regulations.

1 - IDENTIFICATION

VIII - SPECIAL PROTECTION INFORMATION

PRODUCT NAME: (ON) Odor Neutralizer

PACKAGE TYPE: pint, quart, gallon

PREPARED DEPARTMENT OF HAZARDOUS COMMUNICATIONS

DATE PREPARED: June 2003

RESPIRATORY:

Needed in misty conditions. Use approved NIOSH organic vapor HEPA respirator.

EYE: Wear chemical splash goggles.

II - HAZARDOUS INGREDIENTS
PRINCIPLE HAZARDOUS COMPONENT(S)
(CHEMICAL NAMES)
2 - hydroxybenzoic acid methyl ester

CAS NO

ACGIH TLV

OSHA

119-36-8

N/E

PEL

% or RANGE

SKIN: Prevent all possible contact. Use impervious apron,
boots, goggles.

PROTECTIVE GLOVES: PVC or rubber

<37%
OTHER: DO not eat, drink, or smoke in work area. Wash hands before eating.
VENTILATION REQUIREMENTS: Local exhaust adequate

IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep containers closed when not in use.

III - PHYSICAL DATA
BOILING POINT ( 0F) : N/A
VAPOR PRESSURE (mm Hg) : N/A

SPECIFIC GRAVITY (H20= 1) : N/A

VAPOR DENSITY (Air = 1) : Heavier

EVAPORATION RATE (H20 = 1) : <1

pH : NA

APPEARANCE AND ODOR : Dark brown granules - wintergreen odor

MELTING POINT : N/E

SPECIAL PRECAUTIONARY STATEMENTS: Keep this and all chemicals out of reach of children.

SOLUBILITY IN WATER : Not Soluble

IV - FIRE AND EXPLOSION HAZARD DATA

NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on
experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be
confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of
merchantability fitness or otherwise is made.

FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Flash point 2140F
SARA Title III Reporting Requirements

SPECIAL FIRE FIGHTING PROCEDURES: Wear impervious clothing and SCBA; dike spills to prevent runoff
UNUSUAL FIRE AND EXPLOSION HAZARDS: Products of decomposition include carbon monoxide and low molecular weight hydro carbons

V - REACTIVITY DATA
CHEMICAL
STABILITY

UNSTABLE

302

(Extremely Hazardous Substances): Reporting not required.

304/CERCLA

(Spills Notification): Not required.

311

Community Right-To-Know, RTK): Reporting not required.

312

(RTK Inventory Data): Reporting required above TPQ.

CONDITIONS TO AVOID:

STABLE

X

INCOMPATIBILITY (Materials to avoid): Oxidizing agents, heat, sparks, open flame, bases
HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO2
HAZARDOUS
POLYMERIZATION

MAY OCCUR

CONDITIONS TO AVOID:

WILL NOT OCCUR

X

VI - HEALTH HAZARD AREA
ROUTE(S) OF ENTRY:

EYES Yes

SKIN Yes

INGESTION Yes

313

(Emissions and Releases): Reporting not required.

DOT

NOT HAZARDOUS

INHALATION Yes
References

EFFECTS OF OVER EXPOSURE: Irritant
INHALATION: May irritate sensitive persons

TOXIC SUBSTANCE CONTROL CT LIST (TSCA) - INGREDIENTS LISTED

SKIN CONTACT/ABSORPTION: Irritation

PERMISSIBLE EXPOSURE REFERENCES:
Registry of Toxic Effects of Chemical Substances.

INGESTION: Toxic if ingested

Title 29 Code of Federal Regulations.
National Toxicology Program (NTP) Report on Carcinogens.

EYES: Eye irritant
CARCINOGENICITY:

NTP? Not listed

IARC MONOGRAPHS? Not listed

OSHA REGULATED? Not listed

EMERGENCY AND FIRST AID PROCEDURES:
EYES AND SKIN: EYES - wash eyes with plenty of water. GET MEDICAL ATTENTION IMMEDIATELY. SKIN - Rinse skin with plenty of water
and soap. Get medical help if nauseated, treat as ingested products
INHALATION: Remove to fresh air. GET IMMEDIATE MEDICAL ATTENTION, if symptoms persist.
INGESTION: Immediately induce vomiting. GET IMMEDIATE MEDICAL ATTENTION. Call poison control center. Treat for salicylate poisons.

International Agency for Research on Cancer (IARC) Monographs.
Title 40 Code of Federal Regulations
REGULATORY STANDARDS:
DOT Title 49 Code of Federal Regulations 172.101
SARA Title III
Nuclear Regulatory Commission

1

MATERIAL SAFETY DATA SHEET
SECTION I - PRODUCT IDENTIFICATION AND USE
Product Identifier:

ODOUR NEUTRALIZER

Product Use:

WATER BASED DEODERANT FOR USE AS AN ODOUR NEUTRALIZER.

Supplier:
Address:

SHARE CANADA
1691 CHURCH AVENUE, WINNIPEG, MANITOBA R2X 2Y7

Telephone Number: (204) 633-8553

Fax: (204) 633-8453

CANUTEC: (613) 996-6666

SECTION II - HAZARDOUS INGREDIENTS
Ingredient

CAS Number

Weight %

LD 50

LC 50

Isopropanol

67-63-0

5

5840 mg/kg
oral /rat

16,000 ppm
rat, 2 hr

10 %

SECTION III - PHYSICAL DATA
Physical State:
LIQUID
Specific gravity:
0.995
pH:
Not available.
Odour and appearance: CLEAR, LIGHT YELLOW LIQUID. FLORAL FRAGRANCE.
Odour threshold:
Not available.
Vapour pressure (PSI): Not available.
Vapour density (air = 1): Not available.
Evaporation rate (water = 1): Not available.
% volatile by volume: 1-10
Solubility in water:
SOLUBLE.
0
0
Boiling Point ( C ):
Not available.
Freezing Point ( C ): Not available.
Coefficient of water/oil distribution: Not available.

SECTION IV - FIRE AND EXPLOSION DATA
Flammable or combustible:
COMBUSTIBLE
0
Flash point and method:
42 C CLOSED CUP
Upper flammable limit:
Not Available.
Lower flammable limit:
Not Available.
Autoignition temperature:
Not Available.
Flammability classification:
COMBUSTIBLE LIQUID.
Conditions of flammability:
EXPOSURE TO HEAT OR OPEN FLAME.
Means of extinction: WATER, FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Special fire fighting procedures: COOL FIRE-EXPOSED CONTAINERS WITH WATER FOG.
FIREFIGHTERS SHOULD BE EQUIPPED WITH FULL PROTECTIVE GEAR, INCLUDING SELFCONTAINED BREATHING APPARATUS.
Hazardous combustion products: OXIDES OF CARBON.
Sensitivity to mechanical impact: NOT SENSITIVE
Sensitivity to static discharge: NOT SENSITIVE

SECTION V - REACTIVITY DATA
Is the product stable:
Incompatible substances:
Conditions of Reactivity:
Hazardous decomposition products:
CARBON.

YES- STABLE.
OXIDIZERS
NONE
THERMAL DECOMPOSITION MAY PRODUCE OXIDES OF

Product identifier:

ODOUR NEUTRALIZER

SECTION VI - TOXICOLOGICAL PROPERTIES
Primary routes of exposure: SKIN AND EYE CONTACT, INHALATION, INGESTION.
Exposure Limits: ACGIH -TLV: ISOPROPANOL TLV-TWA 400 ppm TLV STEL 500 ppm
WHMIS CLASS: B- 3 COMBUSTIBLE LIQUID, D 2B OTHER TOXIC EFFECTS (EYE IRRITANT).
Irritant:
YES
Carcinogen: NO - IARC / OSHA / NTP
Sensitizer:
NO
Mutagen:
NO
Reproductive effects: NONE KNOWN
Synergistic products: NONE KNOWN
Effects of acute exposure: Eyes: MILD IRRITATION AND REDNESS.
Ingestion: GASTROINTESTINAL IRRITATION, NAUSEA, CRAMPS AND VOMITING. ASPIRATION MAY
BE A HAZARD. Skin: REDNESS, DRYNESS AND IRRITATION WITH PROLONGED AND REPEATED
EXPOSURE. Inhaled: MOVE TO FRESH AIR. IF IRRITATION PERSISTS OBTAIN MEDICAL
ATTENTION.

SECTION VII - PREVENTION MEASURES
Gloves: CHEMICAL
RESISTANT GLOVES

Respirator: USE WITH
ADEQUATE VENTILATION.

Eye protection: SAFETY GLASSES
OR CHEMICAL GOGGLES

Footwear: NO SPECIAL
REQUIREMENTS.

Clothing: NO SPECIAL
REQUIREMENTS.

Other requirements: EYE WASH
STATION

Engineering Controls: NO SPECIAL VENTILATION REQUIRED.
Respiratory protection: USE WITH ADEQUATE VENTILATION.
Leak or spill procedures: VENTILATE AREA AND EXTINGUISH ALL SOURCES OF IGNITION. SOAK
UP ON INERT ABSORBENT MATERIAL AND PLACE IN A PROPERLY MARKED CLOSED CONTAINER
FOR PROPER DISPOSAL.
Waste disposal: CONSULT LOCAL ENVIRONMENTAL AUTHORITIES.
Handling and storage requirements: STORE IN A COOL, DRY PLACE. KEEP CONTAINER TIGHTLY
CLOSED WHEN NOT IN USE. KEEP OUT OF THE REACH OF CHILDREN.
Special shipping information: NOT REGULATED BY TDG.

SECTION VIII - FIRST AID MEASURES
Eyes: FLUSH EYES AND UNDER EYELIDS FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS,
OBTAIN MEDICAL ATTENTION.
Skin: WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, OBTAIN MEDICAL ATTENTION.
Ingestion: CONTACT PHYSICIAN OR POISON CONTROL CENTRE IMMEDIATELY. RINSE MOUTH
WITH WATER ANG GIVE PERSON 1 OR 2 GLASSES OF WATER. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON.
Inhalation: MOVE TO FRESH AIR. IF IRRITATION PERSISTS, OBTAIN MEDICAL ATTENTION.

SECTION IX - PREPARATION DATA
Information Sources:
Prepared by:
Telephone:
Preparation date:

SUPPLIERS' MATERIAL SAFETY DATA SHEET, CCOSH - CHEMINFO
SHARE CANADA
1-204-633-8553
March 11, 2005

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name:
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

FORMULA 491705
MANGO
ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Acetone
Propane
Isobutane
n-Butane
Fragrance

CAS No.:
67-64-1
74-98-6
75-28-5
106-97-8
Not available

TLV:
500ppm
2500ppm
Not established
800ppm
Not available

______________________________________________________________________________

SECTION 3
Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA
<0 to 1330 F
Slightly
Clear/mango scent

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5
Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.

First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________

SECTION 9

SPILL OR LEAK PROCEDURE

Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None

__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491705

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name:
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

FORMULA 491655
TROPICAL NECTAR
ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Acetone
Propane
Isobutane
n-Butane
Fragrance

CAS No.:
67-64-1
74-98-6
75-28-5
106-97-8
Not available

TLV:
500ppm
2500ppm
Not established
800ppm
Not available

______________________________________________________________________________

SECTION 3
Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA
<0 to 1330 F
Slightly
Clear/tropical scent

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5
Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.

First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________

SECTION 9

SPILL OR LEAK PROCEDURE

Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None

__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491655

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name:
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

FORMULA 491805
PEACH KIWI
ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Acetone
Propane
Isobutane
n-Butane
Fragrance

CAS No.:
67-64-1
74-98-6
75-28-5
106-97-8
Not available

TLV:
500ppm
2500ppm
Not established
800ppm
Not available

______________________________________________________________________________

SECTION 3
Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA
<0 to 1330 F
Slightly
Clear/peach kiwi scent

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5
Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.

First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________

SECTION 9

SPILL OR LEAK PROCEDURE

Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None

__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491805

MATERIAL SAFETY DATA SHEET

GLASER MANUFACTURING
#27 - 547 MAIN STREET, E.
MILTON, ON L9T 3J2
(905) 876-4420

EMERGENCY CANUTEC #:

613-996-6666

SECTION I - PRODUCT IDENTIFICATION AND USE
PRODUCT NAME:
CHEMICAL FAMILY:
PRODUCT USE:

BIO-ZYME
BIOLOGICAL DRAIN OPENER
DRAIN CONTROL/STACK MAINTAINER

SECTION II - HAZARDOUS INGREDIENTS
HAZARDOUS INGREDIENT

APPROX. %

CAS#

LD50/RAT, ORAL

LC50

VIABLE BACTERIAL CULTURES

60-100

N/A

NOT KNOWN

NOT KNOWN

SECTION III - PHYSICAL DATA
PHYSICAL STATE:
LIQUID
ODOUR & APPEARANCE: SPICE ODOUR, WHITE
ODOUR THRESHOLD:
N/E
VAPOUR PRESSURE:
N/AP
EVAPORATION RATE:
N/E
BOILING POINT:
100ºC
COEFFICIENT OF WATER/OIL DISTRIBUTION:

SPECIFIC GRAVITY:
VAPOUR DENSITY (AIR=1):
SOLUBILITY IN WATER:
pH:

1.01
N/AP
MODERATE
8.0 – 8.5

N/E

SECTION IV - FIRE AND EXPLOSION DATA
CONDITIONS OF FLAMMABILITY:
EXTINGUISHING MEDIA:
HAZARDOUS COMBUSTION PRODUCTS:
UPPER FLAMMABILITY LIMIT:
AUTO IGNITION TEMP:
SENSITIVITY TO STATIC CHARGE:

NONE
N/AP
NONE KNOWN
N/AP
N/AP
N/AP

LOWER FLAMMABILITY LIMIT:
EXPLOSION DATA:

N/AP
N/AP

SECTION V - REACTIVITY DATA
CHEMICAL STABILITY:
CONDITIONS TO AVOID:
INCOMPATIBLE SUBSTANCES:
HAZARDOUS DECOMPOSITION:
HAZARDOUS POLYMERIZATION:

STABLE
NONE
STRONG ACIDS OR ALKALIS MAY INACTIVATE SOME BACTERIAL CULTURES.
NONE KNOWN
WILL NOT OCCUR.

SECTION VI - TOXICOLOGICAL PROPERTIES
ROUTE OF ENTRY:

SKIN CONTACT: YES
INHALATION:
YES

SKIN ABSORPTION: YES
INGESTION:
YES

EYE CONTACT: YES

EFFECTS OF ACUTE EXPOSURE TO MATERIAL:
THIS MATERIAL MAY CAUSE EYE OR SKIN IRRITATION. ORGANISMS USED ARE NON PATHOGENIC,
BUT CAN CAUSE INFECTION WHEN IN CONTACT WITH OPEN WOUNDS. THESE ORGANISMS ARE
SUSCEPTIBLE TO COMMONLY USED ANTIBIOTICS.
EFFECTS OF CHRONIC EXPOSURE:
NONE KNOWN. LIMITED TOXIC DATA ARE AVAILABLE ON THIS SPECIFIC PRODUCT. THIS HEALTH
HAZARD ASSESSMENT IS BASED ON THE RESULTS OF SCREENING TESTS.
EXPOSURE LIMITS:
N/E
SENSITIZATION OF MATERIAL: NONE KNOWN

IRRITANCY OF MATERIAL:
SLIGHT
CARCINOGENICITY:
NONE KNOWN

1

REPRODUCTIVE TOXICITY:
MUTAGENICITY:

PRODUCT NAME:

NONE KNOWN
NONE KNOWN

TERATOGENICITY:
SYNERGISTIC PRODUCTS:

NONE KNOWN
NONE KNOWN

BIO-ZYME

SECTION VII - PREVENTIVE MEASURES
HAND PROTECTION:
RUBBER OR VINYL GLOVES
EYE PROTECTION:
SAFETY GLASSES
DEPENDING ON SEVERITY OF EXPOSURE:
RESPIRATORY PROTECTION:
LOCAL EXHAUST ADEQUATE. USE NOISH APPROVED RESPIRATOR IF
MISTING PRODUCT.
FOOT WEAR:
RUBBER BOOTS IF CONTACT POSSIBLE
CLOTHING:
AVOID SKIN CONTACT. LONG SLEEVE CLOTHING.
ENGINEERING CONTROLS:
LOCAL EXHAUST ADEQUATE. USE NOISH APPROVED RESPIRATOR IF IN
CONFINED AREAS.
LEAKS AND SPILL PROCEDURES: SMALL SPILLS: FLUSH WITH LARGE AMOUNTS OF WATER.
LARGE SPILLS: COLLECT WITH ABSORBENT AND PLACE IN CONTAINERS
FOR DISPOSAL.
WASTE DISPOSAL: REVIEW LOCAL GOVERNMENT REGULATIONS AND DISPOSE THROUGH LICENSED
FACILITY.
HANDLING PROCEDURES & EQUIPMENT:
AVOID EYE CONTACT.
STORAGE REQUIREMENTS:
STORE IN A COOL, DRY AREA. DO NOT FREEZE.
SECTION VIII - FIRST AID MEASURES
PROCEDURES:
SKIN:
REMOVE CONTAMINATED CLOTHING, WASH AND FLUSH GENEROUSLY WITH SOAP AND
WATER. IF IRRITATION PERSISTS, SEEK MEDICAL ATTENTION.
EYES:
FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL
ATTENTION IF IRRITATION PERSISTS.
INGESTION: DO NOT INDUCE VOMITING. RINSE MOUTH WITH WATER. DRINK LARGE AMOUNTS OF MILK OR
WATER. SEEK MEDICAL ATTENTION IMMEDIATELY.
SECTION IX - TDG SHIPPING INFORMATION
WHMIS CLASSIFICATION: CLASS D, DIVISION 2B
TDG CLASSIFICATION:
NONE
PIN #:
NONE
PACKING GROUP:
N/AP
SECTION X - HMIS HAZARD RATING INFORMATION
HEALTH: 1

FIRE: 0

REACTIVITY: 0

SPECIAL: NONE

HAZARD RATING SCALE: 0=MINIMAL, 1=SLIGHT, 2=MODERATE, 3=SERIOUS, 4=SEVERE
SECTION XI - PREPARATION INFORMATION
PREPARED BY:
PREPARATION DATE:

GLASER MANUFACTURING
JAN 2006

DISCLAIMER
THE INFORMATION CONTAINED HEREIN IS COMPILED FROM SOURCES BELIEVED TO BE RELIABLE. THE MANNER AND
CONDITIONS OF USE AND HANDLING MAY INVOLVE OTHER AND ADDITIONAL CONSIDERATIONS. WE ACCEPT NO
RESPONSIBILITY FOR THE ACCURACY, SUFFICIENCY, RELIABILITY OR FOR ANY LOSS OR INJURY RESULTING FROM
THE USE OF THE INFORMATION.

2

MATERIAL SAFETY DATA SHEET

Page: 1 of 4

NATIONAL SANITARY SUPPLY CO.
13217 S. Figueroa Street
Los Angeles, California 90061
Emergency No. 1-800-535-5053 (INFOTRAC)
----------------------------------------------------------------------------SECTION 1. IDENTIFICATION OF PRODUCT
----------------------------------------------------------------------------Product Name: MINT O LINE MINT ODOR
Date Issued: 07/15/93
DEODORANT CLEANER
Supercedes: 06/01/90
National Item#: 1720XX
----------------------------------------------------------------------------SECTION 2. INGREDIENTS CAS NUMBER PERCENT EXPOSURE LIMITS IN AIR
OSHA PEL ACGIH TLV OTHER
----------------------------------------------------------------------------ISOPROPYL ALCOHOL
67-63-01 14-16
400 ppm TWA 400 ppm
COCONUT OIL SOAP
61788-47-4 8-10
NOT ESTABLISHED
METHYL SALICYLATE
119-36-8
<2
NOT ESTABLISHED
WATER
>50.00
N/A = Not Applicable; N/D = Not Determined
----------------------------------------------------------------------------SECTION 3. PHYSICAL DATA
----------------------------------------------------------------------------Boiling Point (F): <212
Specific Gravity (Water=1): .86
Vapor Pressure (mm Hg.): 16
Percent Volatile (By Volume): 88
Vapor Density (Air=1): ND
Evaporation Rate (Water =1): 1
Solubility in Water: SOLUBLE
pH Range: 10.5
Appearance and Odor: CLEAR COLORLESS/MINT SCENT
----------------------------------------------------------------------------Section 4. FIRE AND EXPLOSION HAZARD DATA
----------------------------------------------------------------------------Flash Point (Test Method): 108 F (TOC)
Extinguishing Media: CO2, DRY CHEMICAL, FOAM, WATER FOG
Special Fire Fighting Procedures: NORMAL FIRE FIGHTING PROCEDURES MAY BE
USED. COOL AND USE CAUTION WHEN APPROACHING OR HANDLING FIRE- EXPOSED
CONTAINERS.
Unusual Fire & Explosion Hazards: CONTAINERS MAY BURST IN HEAT.

MATERIAL SAFETY DATA SHEET
Page: 2 of 4
Product Name: MINT O LINE MINT ODOR DEODORANT CLEANER
Date Issued: 07/15/93
National Item#: 1720
----------------------------------------------------------------------------SECTION 5. REACTIVITY DATA
----------------------------------------------------------------------------Stability: STABLE
Incompatibility - Materials to Avoid: NONE KNOWN TO NSS
Hazardous Polymerization: WILL NOT OCCUR
Conditions to Avoid: NONE KNOWN TO NSS
Hazardous Decomposition Products: WHEN EXPOSED TO FIRE, PRODUCES NORMAL
PRODUCTS OF COMBUSTION.
----------------------------------------------------------------------------SECTION 6. SPILL, LEAK AND DISPOSAL PROCEDURES
----------------------------------------------------------------------------Spill Response: FOR SMALL SPILLS. DILUTE WITH WATER AND PICK UP WITH MOP
AND PAIL OR WET PICK UP VACUUM. FOR LARGE SPILLS, DIKE AREA TO CONTAIN
SPILL. CLEAN UP USING ABSORBENT MATERIAL. PLACE ALL CONTAMINATED
MATERIAL IN A CLOSED CONTAINER FOR DISPOSAL.
Product Disposal: WASTE FOR DILUTED PRODUCT MAY BE FLUSHED TO SEWER.
UNDILUTED PRODUCT RECOVERED FROM SPILLS MAY BE SENT TO A LICENSED
DISPOSAL FACILITY TO BE DISPOSED OF IN ACCORDANCE WITH FEDERAL/STATE
REGULATIONS AND LOCAL ORDINANCES.
Container Disposal: TRIPLE RINSE EMPTY CONTAINER THOROUGHLY WITH WATER
AND DISCARD IN REGULAR TRASH COLLECTION IF ALLOWED BY LOCAL, STATE AND
FEDERAL REGULATIONS.
----------------------------------------------------------------------------SECTION 7. HEALTH HAZARD DATA

MATERIAL SAFETY DATA SHEET
Page: 3 of 4
Product Name: MINT O LINE MINT ODOR DEODORANT CLEANER
Date Issued: 07/15/93
National Item#: 1720
----------------------------------------------------------------------------Symptoms of Overexposure:
Eye Contact: EYE IRRITANT. IF NOT PROMPTLY TREATED, EYE DAMAGE MAY
RESULT.
Skin Contact: SKIN IRRITANT. IRRITATION CAN OCCUR FROM CONTACT
WITH CONCENTRATED PRODUCT OR FROM PROLONGED CONTACT
WITH DILUTED PRODUCT. REPEATED OR PROLONGED EXPOSURE
TO DILUTED PRODUCT MAY LEAD TO DERMATITIS.
Inhalation: NO HEALTH EFFECTS ARE KNOWN TO OCCUR FROM INHALATION OF
THIS PRODUCT UNDER NORMAL USE IN A WELL VENTILATED
AREA. HIGH AIRBORNE CONCENTRATIONS OF MISTS OR SPRAYS
OF THIS PRODUCT MAY CA USE IRRITATION OF THE UPPER
RESPIRATORY TRACT.
Ingestion: INGESTION OF THIS PRODUCT MAY CAUSE DAMAGE TO THE
MEMBRANES OF THE MOUTH, THROAT, AND GASTROINTESTINAL
TRACT WHICH THE PRODUCT CONTACTS. BURNS OF THE MOUTH AND
THROAT, NAUSEA, VOMITING, CRAMPS, AND DIARRHEA MAY
OCCUR.
Primary Routes of Entry: EYES, SKIN
THE ISOPROYL ALCOHOL LISTED IN SECTION 2 IS NOT LISTED ON THE
OSHA, NTP OR IARC MONOGRAPH CARCINOGEN LISTS.
----------------------------------------------------------------------------SECTION 8. EMERGENCY AND FIRST AID PROCEDURES
----------------------------------------------------------------------------Eye Contact: IMMEDIATELY FLUSH THE EYE WITH LARGE QUANTITIES OF RUNNING
WATER FOR A MINIMUM OF 15 MINUTES. HOLD THE EYELIDS APART DURING THE
IRRIGATION TO ENSURE FLUSHING OF THE ENTIRE SURFACE OF THE EYE LID WITH
WATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS.
Skin Contact: FLUSH THE EFFECTED AREA WITH LARGE QUANTITIES OF RUNNING
WATER WHILE REMOVING CONTAMINATED CLOTHES AND SHOES. WASH CLOTHING
BEFORE REUSE. GET MEDICAL ATTENTION IF IRRITATION PERSISTS.
Inhalation: REMOVE FROM CONTAMINATED AREA. IF SYMPTOMS OF RESPIRATORY
DISCOMFORT PERSISTS, GET MEDICAL ATTENTION.
Ingestion: REQUIRES IMMEDIATE MEDICAL MANAGEMENT. DRINK MILK OR WATER AND
GET MEDICAL ADVICE. VOMITING SHOULD BE INDUCED ONLY ON RECOMMENDATION OF
MEDICAL PERSONNEL.
----------------------------------------------------------------------------SECTION 9. SPECIAL PROTECTION INFORMATION
----------------------------------------------------------------------------Respiratory Protection: NO SPECIAL REQUIREMENTS UNDER NORMAL USE
CONDITIONS.
Ventilation: ROOM VENTILATION IS ADEQUATE.
Protection Gloves: NO SPECIAL REQUIREMENTS UNDER NORMAL USE CONDITIONS.
Eye Protection: NO SPECIAL REQUIREMENTS UNDER NORMAL USE CONDITIONS.
Other Protective Clothing/Equipment: WHERE GROSS EYE OR SKIN CONTACT MAY
OCCUR, USE APPROPRIATE PROTECTIVE EQUIPMENT.

MATERIAL SAFETY DATA SHEET
Page: 4 of 4
Product Name: MINT O LINE MINT ODOR DEODORANT CLEANER
Date Issued: 07/15/93
National Item#: 1720
----------------------------------------------------------------------------SECTION 10. ADDITIONAL INFORMATION AND PRECAUTIONS
----------------------------------------------------------------------------Handling and Storage Precautions: STORE IN A COOL DRY PLACE. REPLACE
CAP AFTER USE. KEEP OUT OF REACH OF CHILDREN.
SARA TITLE III H&P RATINGS: Acute, YES; Chronic, NO; Fire, YES;
Press. Release, NO;
Reactive, NO;
NFPA RATINGS: HEALTH - 1

FIRE -3

REACTIVITY -0

SPECIFIC -1

----------------------------------------------------------------------------THE INFORMATION ON THIS MATERIAL SAFETY DATA SHEET REPRESENTS THE LATEST
DATA AND BEST OPINION AS TO THE PROPER USE AND HANDLING OF THIS PRODUCT
UNDER NORMAL CONDITIONS. ANY USE OF THIS PRODUCT OR METHOD OF
APPLICATION WHICH IS NOT IN CONFORMANCE WITH THIS DATA SHEET AND THE
PRODUCT LABEL DIRECTIONS, IS THE RESPONSIBILITY OF THE USER. THIS
MATERIAL SAFETY DATA SHEET WAS PREPARED TO COMPLY WITH THE OSHA HAZARD
COMMUNICATION REGULATION.
-----------------------------------------------------------------------------

Material Safety Data Sheet

U.S. DEPARTMENT OF LABOR

May be used to comply with
OSHA=S Hazard Communication Standard
29 CFR 2910.1200. Standard must be
consulted for specific requirements.

Occupational Safety and Health
(Non-Mandatory Form)
Form Approved
OMB No. 1218-0072

Identity (As Used on Label and List) #202
Big D Fire D One-Shot

Note: Blank spaces are not permitted. If any item is not applicable, or
no information is available, the space must be marked to indicate that.

Section I
Big D Industries, Inc.

Manufacturer=s Name

Emergency Telephone Number

(800) 535-5053

Address (number, Street, City, State, and ZIP Code)

Telephone Number for Information

5620 S. W. 29th Street (73179)

2541

P. O. Box 82219

Date Prepared

Oklahoma City, OK 73148

Signature of Preparer (optional)

(800) 654-4752

(800) 654-4752

(405) 682-

01/01/2007

Section II - HMIS Rating
Health

1

4

Flammability

1

Reactivity

Section III - Hazardous Ingredients/Identity Information
Hazardous Components (Specific Chemical Identity: Common Name(s))

OSHA PEL

ACGIH TLV

Other Limits

%(optional)
Rcmnd.

Acetone CAS #67-64-1

500 ppm

500 ppm

-

Amyl Acetate CAS #628-63-7

100 ppm

100 ppm

-

Ethyl Acetate CAS #141-78-6

400 ppm

400 ppm

Liq. Petrole\um Gas - CAS #68476-85-7

1000 ppm

1000 ppm

Section IV - Physical/Chemical Characteristics
Boiling Point

-44 - 1350F Conc.

Specific Gravity (H2O = 1) 0.5677

N/E

Vapor Pressure (mm Hg.)

N/E

Melting Point

N/A

Vapor Density (AIR = 1)

>1

Evaporation Rate

<1

Solubility in Water:

Slight

Appearance and Odor:

Produces fine mist with pleasant fragrance. Liquid is transparent.

Section V - Fire and Explosion Hazard Data
Flash Point (Method Used)

Extinguishing Media

Flammable Limits

Carbon dioxide, dry foam, water spray
Self contained air supply suggested.

Special Fire Fighting Procedures
Unusual Fire and Explosion Hazards
N/A - Not Applicable

N/A

Keep containers cool (below 1300F) to avoid bursting.

N/D - Not Determined

Page 1

N/E - Not Established

LEL

UEL

1.8%

12.8

#202

Section VI - Reactivity Data
Stability

Unstable

Conditions to Avoid:

Stable

X
Avoid contact with strong oxidizing agents such as nitric acid.

Incompatibility (Materials to Avoid):
Hazardous Decomposition or Byproducts:

Hazardous
Polymerization

None

None

May Occur

Conditions to Avoid:

Will Not Occur

None

X

Section VII - Health Hazard Data
Route(s) of Entry:

Inhalation?

Yes

Skin?

Yes

Ingestion?

Yes

Health Hazards (Acute and Chronic):

Acute - Propellant is an asphyxiant and may exhibit properties at high concentrate. Chronic - Unconsciousness
Carcinogenicity:

NTP?

No

Signs and Symptoms of Exposure:

IARC Monographs?

No

OSHA Regulated?

No

Skin - possible frostbite burn. Eyes - burning sensation. Inhalation - Headache, nausea, disorientation.

Medical Conditions
Generally Aggravated by Exposure:

Emphysema

Emergency and First Aid Procedures: Eye contact: flush with large amounts of water. May cause corneal damage on prolonged contact. Seek medical

attn.
Ingestion: Do not give anything by mouth to an unconscious person. Seek Medical attn. Inhalation: remove person to fresh air . Administer
artificial respiration if not breathing. Seek medical attn.

Section VIII - Precautions for Safe Handling and Use
Steps to be Taken in Case Material is Released or Spilled:

If container is ruptured and begins to leak, place in a well ventilated area and eliminate all ignition sources.
Waste Disposal Method: do not discard empty container in incinerator or fire. Dispose of in accordance with Local, State, and Federal regulations.
0

Precautions to be Taken in Handling and Storing: Store in cool area away from heat or open flame. Do not store above 130 F as containers may burst

releasing the highly flammable propellant. AStore as Level Aerosol (NFPA 30B)
Other precautions: In case of rupture, ventilate to prevent concentrations from reaching flammable levels. Note: any copies or redistribution of

this M.S.D. Sheet must not be modified in any way.

Section IX - Control Measures
Respiratory Protection (Specify Type):

Self contained breathing apparatus.

Ventilation

Protective Gloves: Rubber or plastic for prolonged contact
Other Protective Clothing or Equipment:
Work/Hygienic Practices:
N.A. = Not Applicable

Local Exhaust:: Doors & windows open

Special

N/A

Mechanical (General)

Other

N/A

Fan

Eye Protection: Safety goggles for splash protection

Eye wash/shower facility nearby

Good housekeeping practices. Avoid skin/eye contact.
N.D. - Not Determined

Page 2

N/E - Not Established

OSHA 174, Sept. 1985

MATERIAL SAFETY DATA SHEET
MSDS 0091
=============================================================================
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
----------------------------------------------------------------------------HMIS CODES
PRODUCT NAME
Health
2
RectorSeal Concentrated Evaporator Coil Cleaner
Flammability
0
Reactivity
0
PRODUCT CODES
PPI
B
82552, 82555, 82558
CHEMICAL FAMILY
Organic/Inorganic
USE
Coil Cleaner
MANUFACTURER'S NAME
EMERGENCY TELEPHONE NO.
The RectorSeal Corporation
Chemtrec 24 Hours
2601 Spenwick Drive
(800) 424-9300
Houston, Texas 77055 USA
DATE OF PREPARATION
TECHNICAL SERVICE TELEPHONE NO.
June 30, 2005
(800) 231-3345
=============================================================================
Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
----------------------------------------------------------------------------% by WT
CAS No. INGREDIENT
UNITS
1-5
111-76-2 Glycol Ether EB
ACGIH TLV
25 ppm
OSHA PEL
25 ppm
=============================================================================
Section 3 -- HAZARDS IDENTIFICATION
----------------------------------------------------------------------------SUMMARY OF ACUTE HAZARDS
Irritation to eyes, nose, and throat; drowsiness, narcosis, tremors, and
other CNS effects at high concentrations. Skin irritation, dermatitis, and
defatting.
ROUTE OF EXPOSURE, SIGNS AND SYMPTOMS
INHALATION
Nasal and respiratory irritation, dizziness, narcosis, headache, nausea,
CNS depression, and unconsciousness.
EYE CONTACT
Watering, blurred vision, inflammation, and irritation which can result in
corneal injury.
SKIN CONTACT
Irritation, dermatitis.
INGESTION
Nausea, vomiting; CNS depression; irritation of gastrointestinal tract,
liver and peritoneal wall; lung congestion.
SUMMARY OF CHRONIC HAZARDS
Skin irritation, contact dermatitis, and defatting.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Individuals with pre-existing or chronic diseases of the eyes, skin,
respiratory system, cardiovascular system, gastrointestinal system, liver,
or kidneys may have increased susceptibility to excessive exposure.
=============================================================================
Section 4 -- FIRST AID MEASURES
----------------------------------------------------------------------------If INHALED:
If overcome by exposure, remove victim to fresh air
immediately. Give oxygen or artificial respiration as
needed. Obtain emergency medical attention. Prompt

action is essential.
Immediately wash with soap and water. Remove and wash
any contaminated clothing.
If in EYES:
Flush eyes with large amounts of water for 15 minutes.
Get medical attention if irritation persists.
If SWALLOWED:
If swallowed, call a physician immediately. Only induce
vomiting at the instruction of a physician. Never give
anything by mouth to an unconscious person.
=============================================================================
Section 5 -- FIRE FIGHTING MEASURES
----------------------------------------------------------------------------FLASH POINT
LEL
UEL
None
N/D
N/D
EXTINGUSING MEDIA
Non-flammable. Use agents appropriate for surrounding fires.
SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained full face piece
breathing apparatus and other protective clothing. Hazardous decomposition
products possible (see Section 10).
UNUSUAL FIRE AND EXPLOSION HAZARDS: None
=============================================================================
Section 6 -- ACCIDENTAL RELEASE MEASURES
----------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove all sources
of ignition. Use absorbent materials to prevent footing hazard and to contain.
Ventilate area with natural or explosion-proof, forced air ventilation. Avoid
flushing into sewers, drains, waterways, and soil. Wear protective clothing
and respiratory protection during cleanup.
=============================================================================
Section 7 -- HANDLING AND STORAGE
----------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed and
upright when not in use. Do not store near heat, sparks, or open flames.
OTHER PRECAUTIONS: Avoid prolonged or repeated contact with skin or clothing.
Empty containers may contain residues; treat as if full and observe all
products precautions. Do not reuse empty containers.
=============================================================================
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
----------------------------------------------------------------------------RESPIRATORY PROTECTION (SPECIFY TYPE): In confined, poorly ventilated areas,
use NIOSH/MSHA approved air purifying or supplied air respirators during
soldering operations until fumes have dissipated.
VENTILATION - LOCAL EXHAUST: Acceptable
SPECIAL: Explosion proof
MECHANICAL (GENERAL): Acceptable
OTHER: N/A
PROTECTIVE GLOVES: Wear rubber gloves.
EYE PROTECTION: Safety glasses (ANSI Z-87.1 or equivalent)
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Chemical resistant coveralls
recommended.
WORK/HYGIENIC PRACTICES: Where use can result in skin contact, wash exposed
areas thoroughly before eating, drinking, smoking, or leaving work area.
Launder contaminated clothing before reuse.
=============================================================================
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
----------------------------------------------------------------------------BOILING POINT:
212 F (100 C) @ 760mm Hg
SPECIFIC GRAVITY (H20 = 1):
0.99
VAPOR PRESSURE (mm Hg):
17 @ 68 F (20 C)
MELTING POINT:
N/A
VAPOR DENSITY (AIR = 1):
<1
If on SKIN:

EVAPORATION RATE (ETHYL ACETATE = 1): >1
APPEARANCE/ODOR:
Green Liquid / Mild Odor
SOLUBILITY IN WATER:
Soluble
=============================================================================
Section 10 -- STABILITY AND REACTIVITY
----------------------------------------------------------------------------STABILITY: Stable
CONDITIONS TO AVOID: None
INCOMPATIBILITY (MATERIALS TO AVOID): Heat, sparks and open flames.
HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO, and fragmented hydrocarbons.
HAZARDOUS POLYMERIZATION: Will not occur.
=============================================================================
Section 11 -- TOXICOLOGY INFORMATION
----------------------------------------------------------------------------CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
----------------------------------------------------------------------------TOXICOLOGY DATA
Ingredient Name
----------------------------------------------------------------------------Glycol Ether EB
Oral-Rat LD50:470 mg/kg
Inhalation-Rat TCLo:200 ppm/6H
=============================================================================
Section 12 -- Ecological Information
----------------------------------------------------------------------------ECOLOGICAL DATA
Ingredient Name
----------------------------------------------------------------------------Glycol Ether EB
Food Chain Concentration Potential
None
WATERFOWL TOXICITY
N/A
BOD
26%
AQUATIC TOXICITY
1000 ppm/24 hr/brine shrimp/TLm
=============================================================================
Section 13 -- DISPOSAL CONSIDERATIONS
----------------------------------------------------------------------------Waste Classification: Non-regulated liquid waste.
Disposal Method: Dispose of in accordance with local, state and federal
regulations.
=============================================================================
Section 14 -- TRANSPORTATION INFORMATION
----------------------------------------------------------------------------DOT: Non-regulated
OCEAN (IMDG): Non-regulated
AIR (IATA): Non-regulated
WHMIS (CANADA): Non-regulated
=============================================================================
Section 15 -- REGULATORY INFORMATION
----------------------------------------------------------------------------REGULATORY DATA
Ingredient Name
----------------------------------------------------------------------------Glycol Ether EB
SARA 313
Yes
TSCA Inventory
Yes
CERCLA RQ
N/A
RCRA Code
N/A
=============================================================================
Section 16 -- OTHER INFORMATION

----------------------------------------------------------------------------This document is prepared pursuant to the OSHA Hazard Communication
Standard (29 CFR 1910.1200). The information herein is given in good faith,
but no warranty, expressed or implied is made. Consult RectorSeal for further
information: (713) 263-8001

MATERIAL SAFETY DATA SHEET
MSDS 0091
=============================================================================
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
----------------------------------------------------------------------------HMIS CODES
PRODUCT NAME
Health
2
RectorSeal Concentrated Evaporator Coil Cleaner
Flammability
0
Reactivity
0
PRODUCT CODES
PPI
B
82552, 82555, 82558
CHEMICAL FAMILY
Organic/Inorganic
USE
Coil Cleaner
MANUFACTURER'S NAME
EMERGENCY TELEPHONE NO.
The RectorSeal Corporation
Chemtrec 24 Hours
2601 Spenwick Drive
(800) 424-9300
Houston, Texas 77055 USA
DATE OF PREPARATION
TECHNICAL SERVICE TELEPHONE NO.
June 30, 2005
(800) 231-3345
=============================================================================
Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
----------------------------------------------------------------------------% by WT
CAS No. INGREDIENT
UNITS
1-5
111-76-2 Glycol Ether EB
ACGIH TLV
25 ppm
OSHA PEL
25 ppm
=============================================================================
Section 3 -- HAZARDS IDENTIFICATION
----------------------------------------------------------------------------SUMMARY OF ACUTE HAZARDS
Irritation to eyes, nose, and throat; drowsiness, narcosis, tremors, and
other CNS effects at high concentrations. Skin irritation, dermatitis, and
defatting.
ROUTE OF EXPOSURE, SIGNS AND SYMPTOMS
INHALATION
Nasal and respiratory irritation, dizziness, narcosis, headache, nausea,
CNS depression, and unconsciousness.
EYE CONTACT
Watering, blurred vision, inflammation, and irritation which can result in
corneal injury.
SKIN CONTACT
Irritation, dermatitis.
INGESTION
Nausea, vomiting; CNS depression; irritation of gastrointestinal tract,
liver and peritoneal wall; lung congestion.
SUMMARY OF CHRONIC HAZARDS
Skin irritation, contact dermatitis, and defatting.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Individuals with pre-existing or chronic diseases of the eyes, skin,
respiratory system, cardiovascular system, gastrointestinal system, liver,
or kidneys may have increased susceptibility to excessive exposure.
=============================================================================
Section 4 -- FIRST AID MEASURES
----------------------------------------------------------------------------If INHALED:
If overcome by exposure, remove victim to fresh air
immediately. Give oxygen or artificial respiration as
needed. Obtain emergency medical attention. Prompt

action is essential.
Immediately wash with soap and water. Remove and wash
any contaminated clothing.
If in EYES:
Flush eyes with large amounts of water for 15 minutes.
Get medical attention if irritation persists.
If SWALLOWED:
If swallowed, call a physician immediately. Only induce
vomiting at the instruction of a physician. Never give
anything by mouth to an unconscious person.
=============================================================================
Section 5 -- FIRE FIGHTING MEASURES
----------------------------------------------------------------------------FLASH POINT
LEL
UEL
None
N/D
N/D
EXTINGUSING MEDIA
Non-flammable. Use agents appropriate for surrounding fires.
SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained full face piece
breathing apparatus and other protective clothing. Hazardous decomposition
products possible (see Section 10).
UNUSUAL FIRE AND EXPLOSION HAZARDS: None
=============================================================================
Section 6 -- ACCIDENTAL RELEASE MEASURES
----------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove all sources
of ignition. Use absorbent materials to prevent footing hazard and to contain.
Ventilate area with natural or explosion-proof, forced air ventilation. Avoid
flushing into sewers, drains, waterways, and soil. Wear protective clothing
and respiratory protection during cleanup.
=============================================================================
Section 7 -- HANDLING AND STORAGE
----------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed and
upright when not in use. Do not store near heat, sparks, or open flames.
OTHER PRECAUTIONS: Avoid prolonged or repeated contact with skin or clothing.
Empty containers may contain residues; treat as if full and observe all
products precautions. Do not reuse empty containers.
=============================================================================
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
----------------------------------------------------------------------------RESPIRATORY PROTECTION (SPECIFY TYPE): In confined, poorly ventilated areas,
use NIOSH/MSHA approved air purifying or supplied air respirators during
soldering operations until fumes have dissipated.
VENTILATION - LOCAL EXHAUST: Acceptable
SPECIAL: Explosion proof
MECHANICAL (GENERAL): Acceptable
OTHER: N/A
PROTECTIVE GLOVES: Wear rubber gloves.
EYE PROTECTION: Safety glasses (ANSI Z-87.1 or equivalent)
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Chemical resistant coveralls
recommended.
WORK/HYGIENIC PRACTICES: Where use can result in skin contact, wash exposed
areas thoroughly before eating, drinking, smoking, or leaving work area.
Launder contaminated clothing before reuse.
=============================================================================
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
----------------------------------------------------------------------------BOILING POINT:
212 F (100 C) @ 760mm Hg
SPECIFIC GRAVITY (H20 = 1):
0.99
VAPOR PRESSURE (mm Hg):
17 @ 68 F (20 C)
MELTING POINT:
N/A
VAPOR DENSITY (AIR = 1):
<1
If on SKIN:

EVAPORATION RATE (ETHYL ACETATE = 1): >1
APPEARANCE/ODOR:
Green Liquid / Mild Odor
SOLUBILITY IN WATER:
Soluble
=============================================================================
Section 10 -- STABILITY AND REACTIVITY
----------------------------------------------------------------------------STABILITY: Stable
CONDITIONS TO AVOID: None
INCOMPATIBILITY (MATERIALS TO AVOID): Heat, sparks and open flames.
HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO, and fragmented hydrocarbons.
HAZARDOUS POLYMERIZATION: Will not occur.
=============================================================================
Section 11 -- TOXICOLOGY INFORMATION
----------------------------------------------------------------------------CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
----------------------------------------------------------------------------TOXICOLOGY DATA
Ingredient Name
----------------------------------------------------------------------------Glycol Ether EB
Oral-Rat LD50:470 mg/kg
Inhalation-Rat TCLo:200 ppm/6H
=============================================================================
Section 12 -- Ecological Information
----------------------------------------------------------------------------ECOLOGICAL DATA
Ingredient Name
----------------------------------------------------------------------------Glycol Ether EB
Food Chain Concentration Potential
None
WATERFOWL TOXICITY
N/A
BOD
26%
AQUATIC TOXICITY
1000 ppm/24 hr/brine shrimp/TLm
=============================================================================
Section 13 -- DISPOSAL CONSIDERATIONS
----------------------------------------------------------------------------Waste Classification: Non-regulated liquid waste.
Disposal Method: Dispose of in accordance with local, state and federal
regulations.
=============================================================================
Section 14 -- TRANSPORTATION INFORMATION
----------------------------------------------------------------------------DOT: Non-regulated
OCEAN (IMDG): Non-regulated
AIR (IATA): Non-regulated
WHMIS (CANADA): Non-regulated
=============================================================================
Section 15 -- REGULATORY INFORMATION
----------------------------------------------------------------------------REGULATORY DATA
Ingredient Name
----------------------------------------------------------------------------Glycol Ether EB
SARA 313
Yes
TSCA Inventory
Yes
CERCLA RQ
N/A
RCRA Code
N/A
=============================================================================
Section 16 -- OTHER INFORMATION

----------------------------------------------------------------------------This document is prepared pursuant to the OSHA Hazard Communication
Standard (29 CFR 1910.1200). The information herein is given in good faith,
but no warranty, expressed or implied is made. Consult RectorSeal for further
information: (713) 263-8001

MATERIAL SAFETY DATA SHEET
MSDS 0128
=============================================================================
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
----------------------------------------------------------------------------HMIS CODES
PRODUCT NAME
Health
2
Clean-N-Safe Aerosol Coil Cleaner
Flammability
2
Reactivity
0
PRODUCT CODES
PPI
B
83780
CHEMICAL FAMILY
Organic/Inorganic
USE
Coil Cleaner
MANUFACTURER'S NAME
EMERGENCY TELEPHONE NO.
The RectorSeal Corporation
Chemtrec 24 Hours
2601 Spenwick Drive
(800) 424-9300
Houston, Texas 77055 USA
DATE OF PREPARATION
TECHNICAL SERVICE TELEPHONE NO.
June 8, 2005
(800) 231-3345
=============================================================================
Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
----------------------------------------------------------------------------% by WT
CAS No. INGREDIENT
UNITS
-9036-19-5
Octylphenoxypolyethoxyethanol
ACGIH TLV
N/D
OSHA PEL
N/D
-57018-52-7
Polylene Glycol Butyl Ether
ACGIH TLV
N/D
OSHA PEL
N/D
-6834-92-0
Sodium Metasilicate
ACGIH TLV
N/D
OSHA PEL
N/D
=============================================================================
Section 3 -- HAZARDS IDENTIFICATION
----------------------------------------------------------------------------SUMMARY OF ACUTE HAZARDS
Irritation to eyes, nose, and throat; drowsiness, narcosis, tremors, and
other CNS effects at high concentrations. Skin irritation, dermatitis, and
defatting.
ROUTE OF EXPOSURE, SIGNS AND SYMPTOMS
INHALATION
Nasal and respiratory irritation, dizziness, narcosis, headache, nausea,
CNS depression, and unconsciousness.
EYE CONTACT
Watering, blurred vision, inflammation, and irritation which can result in
corneal injury.
SKIN CONTACT
Irritation, dermatitis.
INGESTION
Nausea, vomiting; CNS depression; irritation of gastrointestinal tract,
liver and peritoneal wall; lung congestion.
SUMMARY OF CHRONIC HAZARDS
Skin irritation, contact dermatitis, and defatting.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Individuals with pre-existing or chronic diseases of the eyes, skin,
respiratory system, cardiovascular system, gastrointestinal system, liver,
or kidneys may have increased susceptibility to excessive exposure.

=============================================================================
Section 4 -- FIRST AID MEASURES
----------------------------------------------------------------------------If INHALED:
If overcome by exposure, remove victim to fresh air
immediately. Give oxygen or artificial respiration as
needed. Obtain emergency medical attention. Prompt
action is essential.
If on SKIN:
Immediately wash with soap and water. Remove and wash
any contaminated clothing.
If in EYES:
Flush eyes with large amounts of water for 15 minutes.
Get medical attention if irritation persists.
If SWALLOWED:
If swallowed, call a physician immediately. Only induce
vomiting at the instruction of a physician. Never give
anything by mouth to an unconscious person.
=============================================================================
Section 5 -- FIRE FIGHTING MEASURES
----------------------------------------------------------------------------FLASH POINT
LEL
UEL
Not combustible, Negative Flame Extension
N/D
N/D
NFPA Level 1 Aerosol
EXTINGUSING MEDIA
Use extinguishing agents appropriate for surrounding fires.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Aerosol cans are under pressure exposure to temperatures above 120F can cause bursting or "rocketing" of cans.
=============================================================================
Section 6 -- ACCIDENTAL RELEASE MEASURES
----------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Depressurize
and dispose of empty cans
=============================================================================
Section 7 -- HANDLING AND STORAGE
----------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Shake well before using.
Keep away from heat, sparks and open flames. Prolonged exposure to direct
sunshine or storage above 120 F may cause can to burst. Do not puncture or
incinerate can.
OTHER PRECAUTIONS: Avoid prolonged or repeated contact with skin or clothing.
Empty containers may contain residues; treat as if full and observe all
products precautions.
=============================================================================
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
----------------------------------------------------------------------------RESPIRATORY PROTECTION (SPECIFY TYPE): None required.
VENTILATION - LOCAL EXHAUST: N/A
SPECIAL: N/A
MECHANICAL (GENERAL): N/A
OTHER: N/A
PROTECTIVE GLOVES: None required.
EYE PROTECTION: Safety glasses (ANSI Z-87.1 or equivalent)
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: None normally required.
WORK/HYGIENIC PRACTICES: Where use can result in skin contact, wash exposed
areas thoroughly before eating, drinking, smoking, or leaving work area.
Launder contaminated clothing before reuse.
=============================================================================
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
----------------------------------------------------------------------------BOILING POINT:
>230 F (110 C) @ 760mm Hg
SPECIFIC GRAVITY (H20 = 1):
1.0
VAPOR PRESSURE (mm Hg):
N/D
MELTING POINT:
N/A

VAPOR DENSITY (AIR = 1):
N/D
EVAPORATION RATE (ETHYL ACETATE = 1): Similar to water
APPEARANCE/ODOR:
Clear Liquid / Fresh Odor
SOLUBILITY IN WATER:
Soluble
=============================================================================
Section 10 -- STABILITY AND REACTIVITY
----------------------------------------------------------------------------STABILITY: Stable
CONDITIONS TO AVOID: Do not store in temperatures above 120 F.
INCOMPATIBILITY (MATERIALS TO AVOID): None known
HAZARDOUS DECOMPOSITION PRODUCTS: None known
HAZARDOUS POLYMERIZATION: Will not occur.
=============================================================================
Section 11 -- TOXICOLOGY INFORMATION
----------------------------------------------------------------------------CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
----------------------------------------------------------------------------TOXICOLOGY DATA
Ingredient Name
----------------------------------------------------------------------------Octylphenoxypolyethoxyethanol
Oral-Rat LD50:4190 mg/kg
Inhalation-Rat LC50:N/D
Polylene Glycol Butyl Ether
Oral-Rat LD50:N/D
Inhalation-Rat LC50:N/D
Sodium Metasilicate
Oral-Rat LD50:1153 mg/kg
Inhalation-Rat LC50:N/D
=============================================================================
Section 12 -- Ecological Information
----------------------------------------------------------------------------ECOLOGICAL DATA
Ingredient Name
----------------------------------------------------------------------------Octylphenoxypolyethoxyethanol
Food Chain Concentration Potential
N/D
WATERFOWL TOXICITY
N/D
BOD
N/D
AQUATIC TOXICITY
N/D
Polylene Glycol Butyl Ether
Food Chain Concentration Potential
N/D
WATERFOWL TOXICITY
N/D
BOD
N/D
AQUATIC TOXICITY
N/D
Sodium Metasilicate
Food Chain Concentration Potential
N/D
WATERFOWL TOXICITY
N/D
BOD
N/D
AQUATIC TOXICITY
N/D
=============================================================================
Section 13 -- DISPOSAL CONSIDERATIONS
----------------------------------------------------------------------------Waste Classification: Aerosols
Disposal Method: Empty containers can be disposed of in trash. Full
containers should be depressurized to separate liquid phase. The liquid
phase is considered a D001 ignitable waste and should be incinerated.
Dispose of all liquid waste in accordance with all local, state and federal
regulations.

=============================================================================
Section 14 -- TRANSPORTATION INFORMATION
----------------------------------------------------------------------------DOT: Consumer Commodity, ORM-D
OCEAN (IMDG): Aerosols, Class 2, UN 1950, IMDG#2102, EMS#2-13
AIR (IATA): Aerosols, 2.2, UN1950, ERG#126
WHMIS (CANADA): Class A
=============================================================================
Section 15 -- REGULATORY INFORMATION
----------------------------------------------------------------------------REGULATORY DATA
Ingredient Name
----------------------------------------------------------------------------Octylphenoxypolyethoxyethanol
SARA 313
No
TSCA Inventory
Yes
CERCLA RQ
N/A
RCRA Code
N/A
Polylene Glycol Butyl Ether
SARA 313
No
TSCA Inventory
Yes
CERCLA RQ
N/A
RCRA Code
N/A
Sodium Metasilicate
SARA 313
No
TSCA Inventory
Yes
CERCLA RQ
N/A
RCRA Code
N/A
=============================================================================
Section 16 -- OTHER INFORMATION
----------------------------------------------------------------------------This document is prepared pursuant to the OSHA Hazard Communication
Standard (29 CFR 1910.1200). The information herein is given in good faith,
but no warranty, expressed or implied is made. Consult RectorSeal for further
information: (713) 263-8001

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name:
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

FORMULA 496655
ZENASHEEN H20
ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Mineral Oil
Propane
Butane
Isoparaffinic Hydrocarbon
Silicone
Isobutane
Ester

CAS No.:
8042-47-5
74-98-6
106-97-8
64741-66-8
63148-62-9
75-28-5
9007-48-1

TLV:
5 mg/m3 as mist
2500ppm
800ppm
Not established
Not established
Not established
Not established

______________________________________________________________________________

SECTION 3
Boiling Point:
Solubility in Water:
Vapor Density(Air=1):

PHYSICAL DATA
<0 to 4510 F
Emulsion
Heavier than air

Specific Gravity(H2O=1):
Evaporation Rate:
pH:

0.89 + 0.05
Slower than Ether
10.75 + 0.5

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flash Point(Propellant):
Flammable Limits(Propellant):
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

150OF
<0OF
LEL:
1.9
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5
Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.

First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________

SECTION 9

SPILL OR LEAK PROCEDURE

Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None

__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
496655

MATERIAL SAFETY DATA SHEET
(SIMILAR TO OSHA FORM 174)

N.A. = Not Applicable
Not Est. = Not Established
Prop. = Proprietary

SECTION 1 - MANUFACTURER / DISTRIBUTOR INFORMATION
Product Name: FRESH START Concentrated Malodor Counteractant	
Supplier’s Name: National Chemical Laboratories of PA, Inc.
Supplier’s Address: 401 N. 10th Street · Philadelphia PA 19123	
HMIS Hazard Code: Health: 1 Flammability: 0 Reactivity: 0 Other: 0	
Chemical Family: Odor Control Agent	
D.O.T. Shipping Name: N/A	

Product #: 1415
Emergency Phone #: CHEM-TEL (800) 255-3924
Chemical Name: N.A. Proprietary Blend
Formula: N.A. Blended Product
Hazard Class: N/A	
D.O.T. ID#: N/A

SECTION 2 - HAZARDOUS INGREDIENTS
CHEMICAL NAME	
None

CAS NUMBER 	

% Concentration Range 	 Hazard Ratings (TLV/PEL)

SECTION 3 - PHYSICAL DATA
Boiling Point (°F): 212	
Vapor Pressure: = To Water	
Vapor Density: = To Water
Solubility in Water: Complete
Appearance: Clear Blue Liquid
Odor: Astra

Specific Gravity: 1.001
Evaporation Rate: = To Water

SECTION 4 - FIRE AND EXPLOSION DATA
Flash Point (°F): None to boiling (TOC)
Flammable Limits: Not Flammable
Extinguising Media: Foam, CO2, water fog, BC/ABC extinguisher may be used in area where material is stored.
Special Fire Fighting Procedures: None known
Unusual Fire & Explosion Hazards: None known.
SECTION 5 - HEALTH HAZARD DATA
Route(s) of Entry: Inhalation: No Skin: Yes Ingestion: Yes		
Threshold Limit Value: Not Est.
Effects of Overexposure: May cause skin and eye irritation. May be harmful if swallowed.
Emergency & First Aid Procedures: For Eyes: Flush eyes with water for at least fifteen minutes. If irritation persists seek medical attention. For
Skin: Flush skin thoroughly with water. If irritation persists seek medical attention. If ingested: Do not induce vomiting. Give large quantities of water.
Seek medical attention. Never give anything by mouth to an unconscious person.
Conditions Aggravated by Exposure: May aggravate pre-existing pulmonary conditions.
Listed Carcinogen, Mutagen, Teratogen (Ingredient, Source, Amount): None
SECTION 6 - REACTIVITY DATA
Stability: Stable
Conditions to Avoid: None
Incompatibility: Avoid contact with acids and oxidizers.
Hazardous Decomposition Products: None known
Hazardous Polymerization: Will not occur.
SECTION 7 - SPILL OR LEAK PROCEDURES
Steps to be taken if material is released or spilled: Ventilate area and recontainerize by mopping, wet vacuum, or the use of a suitable absorbent.
Waste disposal method: Follow local, state and federal regulations.
SECTION 8 - SPECIAL PROTECTION INFORMATION
Respiratory Protection: Not required
Ventilation: Local
Protective Gloves: Recommended for prolonged contact.
Eye Protection: Goggles or safety glasses with side shields.
Other Protective Equipment: None.
SECTION 9 – SPECIAL PRECAUTIONS
Precautions to be taken in handling and storage: Store between 40°F and 120°F. Avoid contact with skin and eyes. Do not ingest.
Other Precautions: Keep out of reach of children. For professional use only.
The information contained in this MSDS was obtained from current and reliable sources, however the data is provided without any warranty, expressed or implied, regarding
its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of this company, it is not responsible for loss, injury
and expense arising out of the product’s improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any
statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use or disposal of this product which
may be covered by this MSDS. The user is responsible for full compliance.

Date Prepared – 03/24/08

By: G.C.

MATERIAL SAFETY DATA SHEET
(SIMILAR TO OSHA FORM 174)

N.A. = Not Applicable
Not Est. = Not Established
Prop. = Proprietary

SECTION 1 - MANUFACTURER / DISTRIBUTOR INFORMATION
Product Name: FRESH START Concentrated Malodor Counteractant	
Supplier’s Name: National Chemical Laboratories of PA, Inc.
Supplier’s Address: 401 N. 10th Street · Philadelphia PA 19123	
HMIS Hazard Code: Health: 1 Flammability: 0 Reactivity: 0 Other: 0	
Chemical Family: Odor Control Agent	
D.O.T. Shipping Name: N/A	

Product #: 1415
Emergency Phone #: CHEM-TEL (800) 255-3924
Chemical Name: N.A. Proprietary Blend
Formula: N.A. Blended Product
Hazard Class: N/A	
D.O.T. ID#: N/A

SECTION 2 - HAZARDOUS INGREDIENTS
CHEMICAL NAME	
None

CAS NUMBER 	

% Concentration Range 	 Hazard Ratings (TLV/PEL)

SECTION 3 - PHYSICAL DATA
Boiling Point (°F): 212	
Vapor Pressure: = To Water	
Vapor Density: = To Water
Solubility in Water: Complete
Appearance: Clear Blue Liquid
Odor: Astra

Specific Gravity: 1.001
Evaporation Rate: = To Water

SECTION 4 - FIRE AND EXPLOSION DATA
Flash Point (°F): None to boiling (TOC)
Flammable Limits: Not Flammable
Extinguising Media: Foam, CO2, water fog, BC/ABC extinguisher may be used in area where material is stored.
Special Fire Fighting Procedures: None known
Unusual Fire & Explosion Hazards: None known.
SECTION 5 - HEALTH HAZARD DATA
Route(s) of Entry: Inhalation: No Skin: Yes Ingestion: Yes		
Threshold Limit Value: Not Est.
Effects of Overexposure: May cause skin and eye irritation. May be harmful if swallowed.
Emergency & First Aid Procedures: For Eyes: Flush eyes with water for at least fifteen minutes. If irritation persists seek medical attention. For
Skin: Flush skin thoroughly with water. If irritation persists seek medical attention. If ingested: Do not induce vomiting. Give large quantities of water.
Seek medical attention. Never give anything by mouth to an unconscious person.
Conditions Aggravated by Exposure: May aggravate pre-existing pulmonary conditions.
Listed Carcinogen, Mutagen, Teratogen (Ingredient, Source, Amount): None
SECTION 6 - REACTIVITY DATA
Stability: Stable
Conditions to Avoid: None
Incompatibility: Avoid contact with acids and oxidizers.
Hazardous Decomposition Products: None known
Hazardous Polymerization: Will not occur.
SECTION 7 - SPILL OR LEAK PROCEDURES
Steps to be taken if material is released or spilled: Ventilate area and recontainerize by mopping, wet vacuum, or the use of a suitable absorbent.
Waste disposal method: Follow local, state and federal regulations.
SECTION 8 - SPECIAL PROTECTION INFORMATION
Respiratory Protection: Not required
Ventilation: Local
Protective Gloves: Recommended for prolonged contact.
Eye Protection: Goggles or safety glasses with side shields.
Other Protective Equipment: None.
SECTION 9 – SPECIAL PRECAUTIONS
Precautions to be taken in handling and storage: Store between 40°F and 120°F. Avoid contact with skin and eyes. Do not ingest.
Other Precautions: Keep out of reach of children. For professional use only.
The information contained in this MSDS was obtained from current and reliable sources, however the data is provided without any warranty, expressed or implied, regarding
its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of this company, it is not responsible for loss, injury
and expense arising out of the product’s improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any
statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use or disposal of this product which
may be covered by this MSDS. The user is responsible for full compliance.

Date Prepared – 03/24/08

By: G.C.

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name:
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

FORMULA 491963
ZENEZE FOGGER
ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
5-31-02

______________________________________________________________________________

SECTION 2
Chemical Name:
Water
Surfactant
Surfactant
Methyl Ether
Perfume

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS
CAS No.:
7732-18-5
68298-20-4
68412-54-4
115-10-6
Proprietary

TLV:
Not applicable
Not established
Not established
Not established
Not available

Carcinogen:
No
No
No
No
No

This formula contains no ingredients subject to the reporting requirements of SARA title III, section 313.

______________________________________________________________________________

SECTION 3
Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA
<00 F
Complete
Clear liquid, unique scent

Specific Gravity :
Evaporation Rate(H2O=1):
pH (Concentrate):

1.01 + .01
1.0 + 0.2
10.0 + 0.5

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Propellant: <00 F
Flammable Limits:
LEL: 3.4
UEL: 27
Extinguishing Media:
Use water fog, dry chemical or carbon dioxide.
Special Fire Fighting Procedures:
Aerosol cans may rupture when heated
Unusual Fire and Explosion Hazards:
Heated cans may burst.
_______________________________________________________________________________________________________________________________________

SECTION 5
Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide and carbon monoxide.
Will not occur.

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved
respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination. Extreme overexposure may result in unconsciousness and
possibly death.
INGESTION: Aspiration hazard if swallowed.

First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION: DO NOT induce vomiting. Seek medical attention immediately. Note:
Never give anything by mouth to an unconscious or convulsing victim. Keep person
warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

None normally required.
Provide local exhaust.
None required if spraying.
ZENEX supports employee safety as priority #1. Therefore, we recommend the use of safety
glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________

SECTION 9

SPILL OR LEAK PROCEDURE

Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None

__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this time.
Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties,
express or implied, and assume no liability in connection with any use of this information.
491963

The Procter & Gamble Company
P&G Household Care
Fabric & Home Care Innovation Center
5299 Spring Grove Avenue
Cincinnati, OH 45217-1087

MATERIAL SAFETY DATA SHEET
MSDS #:FH/F/2007/RPRL-6YWNSS
FH/F/2006/NMNE-6SCML6
Supersedes: FH/F/2004/VBVV-63YQ5Y

Issue Date: 3/22/07
Issue Date: 8/30/04

SECTION I - PRODUCT IDENTIFICATION
Identity: Fabric Refresher

Finished Product

Brands: FEBREZE FABRIC REFRESHER (Allergen Reducer, Extra Strength, Pet Odor Eliminator,
Spring & Renewal, Meadows & Rain, Linen & Sky, Citrus & Light, Auto, and Lavender Vanilla &
Comfort)
P&G Telephone Number: 1-800-308-EASY (1-800-308-3279)
or call Local Poison Control Center or your physician.

SECTION II - HAZARDS IDENTIFICATION
Potential Health Hazards (Acute and Chronic): (See Section 11 for more information)
Ingestion: None known.
Eye Contact: Mild eye irritant.
Skin Contact: Prolonged skin contact may result in transient, superficial effects similar to those produced by mild
toilet soap
Inhalation: None known.
Signs and Symptoms of Exposure:
Ingestion: Possible mild gastrointestinal irritation with nausea, vomiting, and/or diarrhea.
Eye Contact: Instillation into the eye may result in transient, superficial effects similar to those produced by mild
toilet soap.
Skin Contact: Prolonged skin contact may result in transient, superficial effects similar to those produced by mild
toilet soap.
Inhalation: None known.
Medical Conditions Generally Known to be Aggravated by Exposure: None known.
Potential Environmental Effects: (See Section 12 for more information)
SECTION III - COMPOSITION AND INGREDIENTS
Ingredients listed on the product label are: Water, alcohol, odor eliminator derived from corn, and fragrance.
Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200. and/or WHMIS under the HPA:
LD50/LC50
CAS No.
Composition
Common Name
Chemical Name
Range
Ethyl Alcohol
Ethanol
64-17-5
1-5%
7.06 g/kg rat, oral
Febreze Fabric Refresher

Page 1 of 5

SECTION IV – FIRST AID INFORMATION
First Aid Procedures:
Ingestion: Dilute with fluids and treat symptomatically.
Eye Contact: Rinse well with water for at least 15 minutes.
Skin Contact: Rinse with water.
Inhalation: Remove to fresh air.
Note to Physician: Treat symptomatically.
Other: Consumer product package has the following precautionary statement: USE ONLY AS INTENDED.
KEEP OUT OF THE REACH OF CHILDREN. Do not spray directly toward face. If eye contact occurs,
rinse well with water.
SECTION V - FIRE FIGHTING INFORMATION
Flash Point (Method Used):
Allergen Reducer: 136 ºF / 58 ºC (Closed Cup)
Other scent variants: 156 – 159 ºF / 68 – 71 ºC (Closed Cup)
Products do not sustain combustion (ASTM D 4206)
Flammable Properties: Products are not considered flammable, and do not sustain combustion
Upper Flammable Limit: N/K
Lower Flammable Limit: N/K
Explosive Limits:

UEL: N/A

LEL: N/A

Auto-ignition Temperature: N/K
Hazardous Combustion Products: None known
Explosion Data (Sensitivity to Mechanical Impact): N/A
Explosion Data (Sensitivity to Static Discharge): N/A
Extinguishing Media:
Suitable: CO2, water, or dry chemical may be used.
Unsuitable: N/K
Protection of Firefighters:
Specific Hazards Arising from the Material: None known
Protective Equipment and Precautions for Firefighters: Normal fire-fighting gear.
SECTION VI - ACCIDENTAL RELEASE MEASURES
Personal Precautions: None
Environmental Precautions: Disposal is to be performed in compliance with federal, state/provincial and local
regulations. Slowly flush down sewer with excess water or dispose as liquid scrap. Discard empty container in
trash. Do not landfill liquids.
Methods for Containment: Dike or contain spill. Absorb with inert material and dispose. Flush area with water.
Prevent washings from entering waterways. Sorbents may be used.
Methods for Cleanup: Use water spray to dilute and/or wash away spills to avoid exposure and to protect persons
working to stop/repair leak. Any spills are to be prevented from entering waterways. Sorbents may be used.
Other Information: (if applicable)

Febreze Fabric Refresher

Page 2 of 5

SECTION VII – HANDLING AND STORAGE
Precautions To Be Taken in Handling: None.
Precautions To B e Taken in Storage: Store at room temperature.
SECTION VIII - EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines:
Ethanol (CAS# 64-17-5) ACGIH-TLV 1000 ppm
OSHA Z-1 PEL 1000 ppm
Engineering Controls: None required
Personal Protective Equipment (PPE):
Eye/Face Protection: None required for normal consumer use.
Industrial setting: If a splash of solution is likely, chemical goggles may be needed.
Skin Protection: None required for normal consumer use.
Industrial setting: Minimize skin contact with protective gloves (rubber or neoprene).
Respiratory Protection: None required with normal consumer use.
Industrial setting: Use ventilation to minimize exposure to vapor or mist (ethanol).
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Appearance (color, physical form, shape):

Flash Point (Method Used):

Clear liquid

Allergen Reducer: 136 ºF / 58 ºC (CC)
Other scent variants: 156 – 159 ºF / 68 – 71 ºC (CC)
Products do not sustain combustion (ASTM D 4206)

Odor: Products are perfumed.

Reserve Alkalinity: N/A

Odor Threshold: N/A

Solubility in Water: Soluble

Physical State: Liquid

Decomposition Temperature: N/A

Vapor Pressure (mm Hg): N/A

Evaporation Rate (nBuOAc=1):

Vapor Density (Air=1): N/A

Specific Gravity/Density: ~ 1.0

Boiling Point: ~ 212 ºF / ~ 100 ºC

Melting/Freezing Point: N/A

Partition Coefficient (n-octanol/water): N/A

pH (100% solution):

N/K

Allergen Reducer: pH = 6.5 -6.9
Other scent variants: pH = 7.8 – 8.0
Volatile Organic Compound (VOC): Product complies with State and Federal regulations for VOC content.
SECTION X - STABILITY AND REACTIVITY
Chemical Stability: Stable
Conditions to Avoid: N/K
Incompatible Materials: N/K
Hazardous Decomposition Products: N/K
Possibility of Hazardous Reactions: N/K

Febreze Fabric Refresher

Page 3 of 5

SECTION XI - TOXICOLOGICAL INFORMATION
Febreze is practically nontoxic. If ingested, it may be mildly irritating.
LD50 (oral): > 5000 mg/kg (estimated).
LD50 (dermal): > 5000 mg/kg (estimated).
Chronic Effects: No chronic health effects reported.
Target Organs: No target organs reported.
Carcinogenicity: NTP: No
IARC: No
OSHA: No
SECTION XII - ECOLOGICAL INFORMATION
There are no concerns at relevant environmental concentrations. Based on ecotoxicity and fate data for the
individual ingredients in this formulation and for similar consumer product formulations, this product is
anticipated to be non-hazardous to the environment following consumer usage.
SECTION XIII - DISPOSAL CONSIDERATIONS
Waste Disposal Method: Disposal is to be performed in compliance with federal, state/provincial and local
regulations.
Non-household Setting (US Federal): Products covered by this MSDS, in their original form, when disposed as
waste, are considered non hazardous waste according to Federal RCRA regulations (40 CFR 261). Disposal should
be in accordance with local, state and federal regulations.
Non-Household Setting (California): Not hazardous.
Household Use: Product used in household may be disposed of in refuse or in sewer.

SECTION XIV - TRANSPORT INFORMATION
Ground Transport (US DOT): Products covered by this MSDS, in their original form, are not
regulated for transportation.
Air Transport (IATA): – not regulated
Marine/Water Transport (IMDG): – not regulated

Febreze Fabric Refresher

Page 4 of 5

SECTION XV - REGULATORY INFORMATION
United States:
All intentionally-added components of this (these) product(s) are listed on the US TSCA Inventory.
EPA Registration Number: Not Applicable
SARA 313/302/304/311/312 chemicals: None
California: This product has been evaluated and does not require warning labeling under California Proposition
65.
California Registration Number: Not Applicable
State Right-to-Know and CERCLA:
The following ingredients present in the finished product are listed on state right-to-know lists or state worker
exposure lists
Ingredient
Ethanol

CAS #
64-17-5

Level
1-5%

CERCLA
RQ
100 lbs.

IL
X

MA
X

State
NJ
X

PA
X

RI
X

Canada:
All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified in
accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and this MSDS
contains all information required by the Controlled Products Regulations.
Other: Perfumes contained within the products covered by this MSDS comply with appropriate IFRA guidance.

P&G Hazard Rating:

*N/A. - Not Applicable

SECTION XVI - OTHER INFORMATION
Health:
1
4=EXTREME
Flammability: 2
3=HIGH
Reactivity:
0
2=MODERATE
1=SLIGHT
0=NOT SIGNIFICANT
*N/K. - Not Known

Data supplied is for use only in connection with occupational safety and health.
DISCLAIMER: This MSDS is intended to provide a brief summary of our knowledge and guidance regarding the
use of this material. The information contained here has been compiled from sources considered by Procter &
Gamble to be dependable and is accurate to the best of the Company’s knowledge. It is not meant to be an allinclusive document on worldwide hazard communication regulations.
This information is offered in good faith. Each user of this material needs to evaluate the conditions of use and
design the appropriate protective mechanisms to prevent employee exposures, property damage or release to the
environment. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, or for any
damage to any property resulting from misuse of the product.

Febreze Fabric Refresher

Page 5 of 5

Material Safety Data Sheet

GLADE ODOR COUNTERACTANT
Fire Hazard

National Fire
Protection
Association (NFPA)

Health

4

0 0

Hazardous Material
Information System
(HMIS)

Reactivity

Health
Fire Hazard

0
4

Reactivity

0

Specific Hazard
Protective None required.
Clothing

Emergency
Overview

Colorless. Aerosol. See Section 9.
CAUTION: CONTENTS UNDER PRESSURE. May be mildly
irritating to eyes.

Section 1. Chemical Product and Company Identification
94783

Product Name

GLADE ODOR COUNTERACTANT

Code

Product Use

Industrial/Institutional: Air care.

PMS#

433317

126232001

Validation Date

04/19/2000

Print Date
Supersedes

04/20/2000
04/13/2000.

In Case of
Emergency

(800) 851-7145

MSDS#

U.S. Headquarters
Drackett Professional
A Division of
S.C. Johnson Commercial Markets, Inc.
8310 16th Street
Sturtevant, Wisconsin 53177-0902
Phone: (888) 352-2249

Section 2. Composition and Information on Ingredients
Ingredients

CAS #

% by Weight

Exposure Limits

Isobutane

75-28-5

5-10

Not available.

Propane

74-98-6

5-10

Butane

106-97-8

10-30

Water

7732-18-5

60-100

TWA: 1800 (mg/m3) from
OSHA (PEL) [United States]
TWA: 4508 (mg/m3) from
ACGIH (TLV) [United States]
TWA: 1900 (mg/m3) from
OSHA (PEL) [United States]
TWA: 1900 (mg/m3) from
ACGIH (TLV) [United States]
Not available.

LC50/LD50

VAPOR (LC50): Acute: 0.0057
ppm 0.25 hours [Rat].
Not available.

Not available.

Not applicable.

Section 3. Hazards Identification
Inhalation. Skin contact. Eye contact.

Routes of Entry
Potential Acute Health Effects

Eyes May be mildly irritating to eyes.
Skin None known.
Inhalation None known.
Ingestion None known.
Medical Conditions
None known.
Aggravated by Overexposure:
See Toxicological Information (section 11)

Continued on Next Page
Page: 1/4

GLADE ODOR COUNTERACTANT

Material Safety Data Sheet

Section 4. First Aid Measures
Eye Contact

Flush immediately with plenty of water. Get medical attention if irritation occurs.

Skin Contact

Rinse with plenty of running water.

Inhalation

No specific first aid measures are required.

Ingestion

No specific first aid measures are required.

Section 5. Fire Fighting Measures
Flammability of the Product
Flash Points

NFPA 30B Level 1 Aerosol.
CLOSED CUP: <-7°C (19.4°F).

Products of Combustion

None known.

Fire Fighting Media
and Instructions
Special Remarks on Fire and
Explosion Hazards

Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire
fighting procedure may be used.
Aerosol product - Containers may rocket or explode in heat of fire.

Section 6. Accidental Release Measures
Personal Precautions

Put on appropriate personal protective equipment (see Section 8).

Environmental Precautions
and Clean-up Methods

In the event of major spillage: Use appropriate containment to avoid environmental contamination. Sweep
or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a
water rinse for final clean-up.

Section 7. Handling and Storage
Handling

Avoid contact with eyes. Do not puncture or incinerate. FOR INDUSTRIAL USE ONLY

Storage

Store in a dry, cool and well-ventilated area. Protect from freezing. Keep away from heat, sparks and
flame. Pressurized container: protect from sunlight and do not expose to temperature exceeding 50°C.
Do not pierce or burn, even after use. KEEP OUT OF REACH OF CHILDREN.

Section 8. Exposure Controls/Personal Protection
Engineering Controls

No special ventilation requirements. General room ventilation is adequate.

Personal Protection

Eyes No special protective clothing is required.
Hands No special protective clothing is required.
Respiratory No special protective clothing is required.
Feet No special protective clothing is required.
Body No special protective clothing is required.

Section 9. Physical and Chemical Properties
Physical State and
Appearance
Odor

Liquid. (Aerosol.)

Color

Colorless.

pH

Not applicable.

Solubility in water

Complete.

Fragrance like.

Continued on Next Page
Page: 2/4

GLADE ODOR COUNTERACTANT

Material Safety Data Sheet

Section 10. Stability and Reactivity
Stability and Reactivity

The product is stable.

Conditions of Instability

Excessive heat.

Incompatibility with Various
Substances

Not available.

Hazardous Decomposition
Products

Produces normal products of combustion.

Hazardous Polymerization

Will not occur.

Section 11. Toxicological Information
ORAL (LD50) Estimated to be greater than 5000 mg/kg (rat).

Acute toxicity

Effects of Chronic Exposure None known.

Not available.

Other Toxic Effects

Section 12. Ecological Information
Not available.

Section 13. Disposal Considerations
If possible, recycle empty aerosol cans to the nearest steel recycling center. Use up package or give to
someone who can. Dispose of according to all federal, state and local regulations.

Waste Information

Section 14. Transport Information
DOT Classification

Aerosols

DOT Proper
Shipping Name
DOT Class

CLASS 2.1: Flammable gas.

UN/NA

UN1950

DOT Special
Considerations

Limited Quantity

TDG Classification
TDG Proper
Shipping Name
TDG Class

Aerosols

PIN/NIP

UN1950

TDG Special
Considerations

Limited Quantity

CLASS 2.1: Flammable gas.

Section 15. Regulatory Information

Reporting in this section is based on ingredients disclosed in Section 2
US Regulations
Federal Clean air act (CAA) 112 accidental release prevention: Butane
Clean air act (CAA) 112 regulated flammable substances: Propane, Isobutane, Butane
CERCLA: Hazardous substances.: Propane, Isobutane
State New Jersey: Propane, Isobutane, Butane
Massachusetts spill list: Propane, Isobutane, Butane
Massachusetts RTK: Propane, Isobutane, Butane
Pennsylvania RTK: Propane, Isobutane, Butane

This product is not subject to the reporting requirements under California's Proposition 65.
Registered Product Not applicable.
Information
Canadian Regulations
WHMIS Classification CLASS A: Compressed gas.

Continued on Next Page
Page: 3/4

GLADE ODOR COUNTERACTANT

Material Safety Data Sheet

WHMIS Icon

Registered Product Not applicable.
Information
Chemical Inventory Status

All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control
Act (TSCA) Chemical Substance Inventory.

Section 16. Other Information
Other Special
Considerations
Version

Not available.
1

Notice to Reader
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied,
as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to
evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws
and regulations.

Material Safety Data Sheet
Section 1. Product and Company Identification
Product Name

Product Description
Manufacturer

LYSOL® BRAND II DISINFECTANT
SPRAY, ALL SCENTS (AEROSOL) CANADIAN

MSDS#

Validation Date
Antibacterial action. Kills viruses, bacteria, mold and mildew.
Eliminates odours.
Print Date
Reckitt Benckiser (Canada) Inc.
2 Wickman Road
Toronto, Ontario M8Z 5M5

Product Identifier

Reg. No. 25094, P.C.P. Act

Item Number

59631-50709-06

Not available.

2/28/2006
2/28/2006

In case of
Emergency:

Telephone: 800-888-0192

Transportation
Emergencies:

Chemtrec: 1-800-424-9300
(U.S. & Canada)
Outside the U.S & Canada
(North America), call:
703-527-3887

Formula Number

432-124A (359979) Original scent; 147-082 (356595) Country scentTM; 147-083 (356596) Mountain scent; 73-087
(356593) Fresh scent; 258-011 (356597) Linen®; 192-031 (364000) Soft Powder®; 550-095 (367851) Spring
WaterfallTM.

UPC Number

59631-33072, 59631-50706 (Original/Parfum Originale); 59631-34082, 59631-50709 (Country/Parfum Campagnard); 59631-50615 (Mountain Air/Parfum de Montagne); 59631-32102 (Fresh/Parfum
de Fraîcheur); 59631-26710, -34052 & -50710 (Linen/Linge); 59631-75571 (Spring Waterfall/Chute D'Eau Printainière) & 59631-75393 (364000) Soft Powder/Parfum Tendre de Poudre.

Section 2. Composition and Information on Ingredients
Name

CAS #

1) ETHANOL

64-17-5

79

124-38-9

4.0

2) CARBON DIOXIDE

% by Weight

Exposure Limits : TLV/PEL
TWA: 1880 (mg/m3) from ACGIH (TLV)
TWA: 1000 (ppm) from ACGIH (TLV)
TWA: 1900 (mg/m3) from OSHA (PEL)
TWA: 1000 (ppm) from OSHA (PEL)
TWA: 9000 (mg/m3) from ACGIH (TLV)
TWA: 5000 (ppm) from ACGIH (TLV)
TWA: 9000 STEL: 54 (mg/m3) from OSHA (PEL)
TWA: 5000 (ppm) from OSHA (PEL)

Section 3. Hazards Identification
Emergency Overview

DANGER: Extremely Flammable. Container may explode if heated. Keep away from heat, sparks and open
flame. Exposure to temperatures above 55º C (130º F) may cause bursting. Causes eye irritation. Do not
spray in eyes, on skin or on clothing. KEEP OUT OF REACH OF CHILDREN.

Section 4. First Aid Measures
Eye Contact

In case of eye contact, hold eyes open and IMMEDIATELY rinse eyes thoroughly with plenty of water.
Remove any contact lenses and continue rinsing for at least 15 minutes. If irritation persists, consult a
physician.

Skin Contact

In keeping with good hygienic practices, wash exposed areas thoroughly with soap and water.

Inhalation

None required under recommended use conditions. Remove to fresh air.

Ingestion

Call a physician or poison control center immediately. Contains denatured ethanol; ingestion may result in
ethanol poisoning. NEVER give an unconscious person anything to ingest.

Continued on Next Page

LYSOL® BRAND II DISINFECTANT SPRAY,
ALL SCENTS (AEROSOL) - CANADIAN

Page Number: 2

Section 5. Fire and Explosion Data
Flammability

Extremely flammable. See Section 14 for any Shipping Classifications.

Flash Point

Not applicable. Aerosol flame extension greater than 18 inches or 45 cm.

Explosive Limits in Air

LOWER: 3.3% UPPER: 19%

Products of Combustion

Carbon monoxide, carbon dioxide and other unknown organic compounds.

Fire and Explosion Hazards

Contents under pressure. Do not use in presence of open flame or sparks. Do not puncture or incinerate
container or store at temperatures over 50°C. Container may explode if heated.

Fire Fighting Media
and Instructions

Use DRY chemicals, CO2, water spray or foam. Use extinguishing media suitable for surrounding
materials.

Special Fire Fighting
Instructions

Product contents under pressure. Cool containers with water spray. Wear full protective equipment:
eye/face (shield), body (full bunker gear), respiratory (SCBA). Provide shielding for venting, rupturing or
bursting containers. Move containers away from fire, if possible and safe to do so.

Section 6. Accidental Release Measures
Accidental Spill

Small spills: Eliminate all sources of ignition. Absorb with an inert material and place in appropriate waste
disposal container.
Large spills: Eliminate all sources of ignition and ventilate the area with equipment rated for use in
flammable environments. Collect liquid and store in metal containers for later disposal according to local,
provincial or federal regulations.

Section 7. Handling and Storage
Handling and Storage

DANGER: Extremely flammable. Container may explode if heated. Contents under pressure. Do not use
in presence of open flame or sparks. Do not puncture or incinerate container or store at temperatures over
50°C. Causes eye irritation. Do not spray in eyes, on skin or on clothing. Avoid contact with eyes or food.
KEEP OUT REACH OF CHILDREN.
It is an offence under the PEST CONTROL PRODUCTS ACT to use a control product under unsafe
conditions.

Section 8. Exposure Controls/Personal Protection
Ventilation Requirements

None required. General ventilation should be sufficient to control airborne levels.

Eye Protection

Avoid contact with eyes. Emergency responders should wear full eye and face protection.

Skin Protection

May cause mild skin irritation after prolonged or repeated use. Emergency responders should wear
impermeable gloves.

Respiratory Protection

None required under normal use conditions. Emergency responders should wear suitable respiratory
protection where long term exposure to vapors from large areas of spilled liquid is possible such as a major
spill, a fire or a clean-up operation.

Other Protection

None required under normal use conditions.

Work/Hygienic Practices

Washing with soap and water after use is recommended as good hygienic practice to prevent possible skin
irritation and / or eye irritation from the residue that may be left on the hands.

Continued on Next Page

Page Number: 3

LYSOL® BRAND II DISINFECTANT SPRAY,
ALL SCENTS (AEROSOL) - CANADIAN
Section 9. Physical and Chemical Properties
Description

Aerosol spray.

Odor

Various scents.

pH

10 [Basic.]

Color

Clear (Spray mist).

Boiling/Condensation Point

Not available.

Specific Gravity

0.835 @ 25°C

Vapor Pressure

95-105 psig.

Vapor Density

The highest known value is 1.6 (Air = 1) (ETHANOL).

Viscosity

Not available.

Solubility

Complete.

Physical Chemical Comments Not available.

Section 10. Stability and Reactivity Data
Chemical Stability

The product is stable.

Conditions of Instability

Danger: Extremely flammable. Container may explode if heated. Contents under pressure. Do not use in
presence of open flame or sparks. Do not puncture or incinerate container or store at temperatures over
50°C.

Incompatibility with Various
Substances

Do not use on polished wood furniture, rayon fabrics or acrylic plastics. Avoid contact with food.

Hazardous Decomposition
Products

Toxic sulfur oxides can be released if heated to decomposition temperature.

Hazardous Polymerization

Will not occur.

Section 11. Toxicological Information

Exposure effects
Eye Contact

Avoid contact with eyes. Causes eye irritation.

Skin Contact

None expected under recommended use conditions. Prolonged or repeated skin contact may result in slight
to moderate skin irritation.

Inhalation

None expected.

Ingestion

Contains denatured alcohol; ingestion may result in ethanol poisoning.

Carcinogenicity

Not listed as carcinogenic by OSHA, NTP or IARC.

Section 12. Ecological Information
Ecotoxicity

Not available.

Continued on Next Page

Page Number: 4

LYSOL® BRAND II DISINFECTANT SPRAY,
ALL SCENTS (AEROSOL) - CANADIAN
Section 13. Disposal Considerations
Waste Disposal

This container may be recycled in communities where aerosol can recycling is available. Before offering for
recycling, empty the can by using product according to the label (DO NOT PUNCTURE OR INCINERATE).
If recycling is not available, contact your municipality or provincial Ministry of Environment for disposal
information.

Section 14. Transport Information
DOT Classification

ORM-D

Proper Shipping Name

Consumer Commodity

DOT Identification Number

Not applicable.

Packing Group

Not applicable

Maritime Transportation

Not applicable.

Hazardous Substances
Reportable Quantity

Not applicable.

Special Provisions for
Transport

Not applicable.

TDG Classification

Consumer Commodity - Transborder Consignment.

ADR Classification

Not applicable.

IMDG Classification

Aerosols, Class 2.1, UN1950 - Limited Quantity.

IATA Classification

Consumer Commoditity, 9 ID8000

Section 15. Regulatory Information
Federal and State
Regulations

SARA Title III, Section 313 Toxic Chemical Notification & Release Reporting:
None

California Proposition 65: This product contains the following ingredients which require a warning under the Safe
Drinking Water & Toxic Enforcement Act:
None

Other Classifications

WHMIS (Canada)

CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F).

Section 16. Other Information

HMIS (U.S.A.)

Health Hazard
Fire Hazard
Reactivity
Personal Protection

1
3
0
B

Continued on Next Page

1
Health

1

0

Reactivity
Specific hazard

NFPA Aerosol Level
Validated by Product Safety on 2/28/2006.

Fire Hazard

National Fire Protection
Association (U.S.A.)

Printed 2/28/2006.

1, per NFPA 30B

LYSOL® BRAND II DISINFECTANT SPRAY,
ALL SCENTS (AEROSOL) - CANADIAN

Page Number: 5

Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee
that these are the only hazards that exist.

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name:
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

FORMULA 494725
ZENABRITE LEMON
ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Isoparaffinic HC Solvent
Butane
Propane
Poly (dimethylsiloxane)

CAS No.:
64742-48-9
106-97-8
74-98-6
63148-62-9

TLV:
Not Established
800ppm
2500ppm
Not Established

______________________________________________________________________________

SECTION 3
Boiling Point:
Solubility in Water:
Vapor Density(Air=1):

PHYSICAL DATA
<0 to 3720 F
Nil
Heavier than air

Specific Gravity(H2O=1):
Evaporation Rate:
pH:

0.89 + 0.05
Slower than Ether
NA

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flash Point(Propellant):
Flammable Limits(Propellant):
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

Non-Flammable
7OF
LEL:
1.3
UEL: 9.8
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5
Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.

First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________

SECTION 9

SPILL OR LEAK PROCEDURE

Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None

__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
494725

MATERIAL SAFETY DATA SHEET
81410
02 00
===========================================================================
Section 1 −− PRODUCT AND COMPANY IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT NUMBER
HMIS CODES
Health
2
81410
Flammability
2
Reactivity
0
PRODUCT NAME
DURA SEAL* DURA FINISH* Liquid Floor Wax, Neutral
MANUFACTURER’S NAME
EMERGENCY TELEPHONE NO.
MINWAX Company
(216) 566−2917
10 Mountainview Road
Upper Saddle River, NJ 07458
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
31−MAR−07
(800) 364−1359
===========================================================================
Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
51
64742−88−7 Mineral Spirits
ACGIH TLV
100 ppm
2 mm
OSHA PEL
100 ppm
3
64741−65−7 Mineral Spirits (Odorless)
ACGIH TLV
100 ppm
1 mm
OSHA PEL
100 ppm
===========================================================================
Section 3 −− HAZARDS IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.

Continued on page 2

81410
page 2
===========================================================================
Section 4 −− FIRST AID MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
EYES:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re−use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 −− FIRE FIGHTING MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
FLASH POINT
LEL
UEL
103 F PMCC
1.0
7.0
FLAMMABILITY CLASSIFICATION
Combustible, Flash above 99 and below 200 F
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Alcohol Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers may explode (due to the build−up of pressure) when
exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self−contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build−up and possible autoignition or explosion when exposed to
extreme heat.
===========================================================================
Section 6 −− ACCIDENTAL RELEASE MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
===========================================================================
Section 7 −− HANDLING AND STORAGE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STORAGE CATEGORY
DOL Storage Class II

Continued on page 3

81410
page 3
===========================================================================
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Contents are COMBUSTIBLE. Keep away from heat and open flame.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Keep container closed when not in use. Transfer only to approved
containers with complete and appropriate labeling. Do not take internally.
Keep out of the reach of children.
To minimize the possibility of spontaneous combustion: control the
accumulation of overspray; soak wiping rags and waste immediately after use
in a water−filled, closed metal container; air dry filters outside, far
from any combustible material and separated by bricks or other
non−combustible spacers; dispose of all contaminated materials and waste
properly. Consult OSHA 29 CFR 1910.107(b)(5) and NFPA 33, Chapter 8 (8−9)
for the proper procedures.
===========================================================================
Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
Removal of old paint by sanding, scraping or other means may generate
dust or fumes that contain lead. Exposure to lead dust or fumes may cause
brain damage or other adverse health effects, especially in children or
pregnant women. Controlling exposure to lead or other hazardous substances
requires the use of proper protective equipment, such as a properly fitted
respirator (NIOSH approved) and proper containment and cleanup. For more
information, call the National Lead Information Center at 1−800−424−LEAD
(in US) or contact your local health authority.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
Wear gloves which are recommended by glove supplier for protection
against materials in Section 2.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.

Continued on page 4

81410
page 4
===========================================================================
Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT WEIGHT
7.28 lb/gal
872 g/l
SPECIFIC GRAVITY
0.88
BOILING POINT
212 − 412 F
100 − 211 C
MELTING POINT
Not Available
VOLATILE VOLUME
78 %
EVAPORATION RATE
Slower than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
7.2
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical − As Packaged)
4.73 lb/gal
566 g/l
Less Water and Federally Exempt Solvents
3.90 lb/gal
468 g/l
Emitted VOC
===========================================================================
Section 10 −− STABILITY AND REACTIVITY
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STABILITY −− Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
===========================================================================
Section 11 −− TOXICOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver and urinary systems.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
TOXICOLOGY DATA
CAS No.
Ingredient Name
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
64742−88−7
Mineral Spirits
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
64741−65−7
Mineral Spirits (Odorless)
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
===========================================================================
Section 12 −− ECOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ECOTOXICOLOGICAL INFORMATION
No data available.

Continued on page 5

81410
page 5
===========================================================================
Section 13 −− DISPOSAL CONSIDERATIONS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Incinerate in approved facility. Do not incinerate closed container.
Dispose of in accordance with Federal, State/Provincial, and Local
regulations regarding pollution.
===========================================================================
Section 14 −− TRANSPORT INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
US Ground (DOT)
May be Classed as a Combustible Liquid for U.S. Ground.
UN1263, PAINT, 3, PG III, (ERG#128)
Bulk Containers may be Shipped as:
UN1263, PAINT, COMBUSTIBLE LIQUID, PG III, (ERG#128)
Canada (TDG)
May be Classed as a Combustible Liquid for Canadian Ground.
UN1263, PAINT, CLASS 3, PG III, (ERG#128)
IMO
UN1263, PAINT, CLASS 3, PG III, (39 C c.c.), EmS F−E, S−E
===========================================================================
Section 15 −− REGULATORY INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
No ingredients in this product are subject to SARA 313 (40 CFR 372.65C)
Supplier Notification.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
===========================================================================
Section 16 −− OTHER INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

Material Safety Data Sheet

U. S. Department of Labor

May be used to comply with OSHA's
Hazard Communication Standard
29 CFR 1910.1200. Standard must be
consulted for specific requirements.

Occupational Safety and Health Administration
(Non-Mandatory Form)
Form Approved

IDENTITY (As Used on Label and List)

NOTE: Blank spaces are not permitted. If any item is not applicable, or
no information is available, the space must be marked to indicate that.

Bab-O Powdered Cleanser

OMB No. 1218-0072

SECTION I
Manufacturer's Name

Emergency Telephone Number

Fitzpatrick Bros., Inc.

(262) 947-3500 X 617

Address (Number, Street, City, State and ZIP Code)

Telephone Number for Information

(262) 947-3500 X 617
Date Prepared

625 North Sacramento Boulevard

07/25/2005
Signature of Preparer (optional)

Chicago, Illinois 60612

SECTION II - Hazardous Ingredients/Identity Information
Hazardous Components (Specify Chemical Identity: Common Name[s]) OSHA PEL

THIS PRODUCT CONTAINS:

ACGIH TLV

Other Limits Recommended

% (optional)

Calcium Carbonate (CAS# 1317-65-3)
Sodium Carbonate (CAS# 497-19-8)
Sodium Dodecylbenzene Sulfonate (CAS# 25155-30-0

These basic materials have been identified as eye, skin, mucous membrane irritants.

SECTION III - Physical/Chemical Characteristics
Boiling Point

Specific Gravity (H2O = 1)

N/A

N/A

Vapor Pressure (mm Hg.)

Melting Point

N/A

N/A

Vapor Density (AIR = 1)

Evaporation Rate (Butyl Acetate = 1)

N/A

N/A

Solubility in Water

Partially soluble in water
Appearance and Odor

White powder, no odor

SECTION IV - Fire and Explosion Hazard Data
Flash Point (Method Used)

Flammable Limits

N/A

N/A

Extinguishing Media

Not a fire or explosive hazard
Special Fire Fighting Procedures

None
Unusual Fire and Explosion Hazards

None
(Reproduce locally)

Page 1

LEL

UEL

N/A

N/A

SECTION V - Reactivity Data
Stability

Unstable

Stable

Conditions to Avoid

X

Do not mix with ammonia or other household chemicals

Incompatability (Materials to Avoid)

Hazardous Decomposition or Byproducts

Hazardous
Polymerization

May Occur

Will Not Occur

Conditions to Avoid

X

SECTION VI - Health Hazard Data
Routes of Entry:

Inhalation?

Skin?

Yes

Ingestion?

No

No

Health Hazards (Acute and Chronic)

This material is identified as an irritant to eyes and the respiratory tract.
Scouring powder is not irritating to the skin and is harmful if swallowed.

Carcinogenicity:

NTP?

IARC Monographs?

OSHA Regulated?

Non-carcinogen
Signs and Symptoms of Exposure

Eye and mucous membrane irritation
Medical Conditions Generally Aggravated by Exposure

Avoid contact with eyes. Avoid breathing dust.
Emergency and First Aid Procedures

In case of contact with eyes, wash with plenty of water for at least 15 minutes.
Get medical attention if excessive inhalation occurs. Remove victim to fresh air.

SECTION VII - Precautions for Safe Handling and Use
Steps to be Taken in Case Material is Released or Spilled

Normal clean-up procedures
Waste Disposal Method

Conform to state, federal and local regulations

Precautions to be Taken in Handling and Storing

Store in cool, dry, ventilated area
Other Precautions

SECTION VIII - Control Measures
Respiratory Protection (Specify Type)

If dusty, wear mask
Ventilation

Local Exhaust

Special

Natural
Mechanical (General)

Other

Protective Gloves

Eye Protection

If needed

Wear goggles, if needed

Other Protective Clothing or Equipment

Optional
Work/Hygienic Practices

Page 2

Material Safety Data Sheet

PROFESSIONAL VANISH MILDEW STAIN CLEANER
Fire Hazard

National Fire
Protection
Association (NFPA)

Health

1

2 0

Health

Hazardous Material
Information System
(HMIS)

Reactivity

Fire Hazard
Reactivity

2
1
0

Specific Hazard
Emergency Straw color. Liquid. See Section 9.
Overview
WARNING: CAUSES EYE IRRITATION. May be mildly
irritating to skin.

Protective
Clothing

Section 1. Chemical Product and Company Identification
Product Name

PROFESSIONAL VANISH MILDEW STAIN CLEANER Code

90156

Product Use

Industrial/Institutional: Washroom care.

PMS#

433230

MSDS#

126095001

Validation Date

6/26/2003

Print Date
Supersedes

6/26/2003
No Previous Validation

In Case of
Emergency

(800) 851-7145

U.S. Headquarters
Drackett Professional
A Division of
S.C. Johnson Commercial Markets, Inc.
8310 16th Street
Sturtevant, Wisconsin 53177-0902
Phone: (888) 352-2249

Section 2. Composition and Information on Ingredients
Ingredients

CAS #

% by Weight

Sodium Hydroxide

1310-73-2

1-5

Sodium Hypochlorite
Tert-butyl Alcohol

7681-52-9
75-65-0

1-5
1-5

Water

7732-18-5

60-100

Exposure Limits
OSHA (United States).
CEIL: 2 mg/m3
ACGIH (United States).
STEL: 2 mg/m3
Not available.
OSHA (United States).
TWA: 300 mg/m3
ACGIH (United States).
TWA: 303 mg/m3
Not available.

LC50/LD50
Not available.

Not available.
ORAL (LD50): Acute: 3500
mg/kg [Rat].

Not available.

Section 3. Hazards Identification
Inhalation. Skin contact. Eye contact.

Routes of Entry
Potential Acute Health Effects

Eyes May be moderately irritating to eyes.
Skin May be mildly irritating to skin.
Inhalation May be irritating to nose, throat, and respiratory tract.
Ingestion May cause abdominal discomfort, nausea, vomiting and diarrhea.
Medical Conditions
Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, emphysema, etc., may
Aggravated by Overexposure: be more susceptible to irritating effects.
See Toxicological Information (section 11)

Continued on Next Page
Page: 1/4

PROFESSIONAL VANISH MILDEW STAIN CLEANER

Material Safety Data Sheet

Section 4. First Aid Measures
Eye Contact

Flush immediately with plenty of water. If irritation persists, get medical attention.

Skin Contact

Flush immediately with plenty of water. Get medical attention if irritation occurs.

Inhalation

If breathing is difficult: Remove to fresh air. Get medical attention immediately.

Ingestion

Immediately drink plenty of water. If discomfort persists, get medical attention.

Section 5. Fire Fighting Measures
Flammability of the Product None known.
CLOSED CUP: >103°C (217.4°F).
Flash Points
None known.

Products of Combustion

Fire Fighting Media
Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire
and Instructions
fighting procedure may be used.
Special Remarks on Fire and None known.
Explosion Hazards

Section 6. Accidental Release Measures
Personal Precautions

Put on appropriate personal protective equipment (see Section 8).

Environmental Precautions
and Clean-up Methods

In the event of major spillage: Use appropriate containment to avoid environmental contamination. Sweep
or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a
water rinse for final clean-up.

Section 7. Handling and Storage
Handling

Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. FOR COMMERCIAL AND
INDUSTRIAL USE ONLY.

Storage

Store in a dry, cool and well-ventilated area. Protect from freezing. KEEP OUT OF REACH OF
CHILDREN.

Section 8. Exposure Controls/Personal Protection
Engineering Controls

Good general ventilation should be sufficient to control airborne levels. Respiratory protection is not
required if good ventilation is maintained.

Personal Protection
Eyes Safety glasses recommended.
Hands For prolonged or repeated contact with skin: Rubber gloves.
Respiratory No special requirements under normal use conditions.
Feet No special requirements under normal use conditions.
Body No special protective clothing is required.

Section 9. Physical and Chemical Properties
Physical State and
Appearance
Odor

Liquid.

Color

Straw color.

pH

12.8 [Basic.]

Specific Gravity

1

Evaporation Rate

<1

Solubility in water

Complete.

Bleach.

Continued on Next Page
Page: 2/4

PROFESSIONAL VANISH MILDEW STAIN CLEANER

Material Safety Data Sheet

Section 10. Stability and Reactivity
Stability and Reactivity

The product is stable.

Conditions of Instability

None known.

Incompatibility with Various Avoid mixing with: acids , Ammonia. Do not mix with any other chemicals or products unless specified by
Substances
label.
Hazardous Decomposition
Products

When exposed to fire: Produces normal products of combustion.

Hazardous Polymerization

Will not occur.

Section 11. Toxicological Information
ORAL (LD50) Estimated to be greater than 5000 mg/kg (rat).
DERMAL (LD50) Between 2000 - 20000 mg/kg (rat).

Acute toxicity

Effects of Chronic Exposure None known.
Not available.

Other Toxic Effects

Section 12. Ecological Information
Not available.

Section 13. Disposal Considerations
No special precautions. Dispose of according to all federal, state and local regulations.

Waste Information

Section 14. Transport Information
DOT Classification
Please refer to the Bill of Lading/receiving documents for up to date shipping information.

DOT Proper
Shipping Name
TDG Classification

Please refer to the Bill of Lading/receiving documents for up to date shipping information.

TDG Proper
Shipping Name

Section 15. Regulatory Information

Reporting in this section is based on ingredients disclosed in Section 2
US Regulations
Federal SARA 313 toxic chemical notification and release reporting: Tert-butyl Alcohol
Clean Water Act (CWA) 311: Sodium hydroxide, Sodium Hypochlorite
CERCLA: Hazardous substances.: Sodium hydroxide, Sodium Hypochlorite, Tert-butyl Alcohol
State New Jersey spill list: Sodium hydroxide, Sodium Hypochlorite, Tert-butyl Alcohol
New Jersey: Sodium hydroxide, Sodium Hypochlorite, Tert-butyl Alcohol
Massachusetts spill list: Sodium hydroxide, Sodium Hypochlorite, Tert-butyl Alcohol
Massachusetts RTK: Sodium hydroxide, Sodium Hypochlorite, Tert-butyl Alcohol
Pennsylvania RTK: Sodium hydroxide, Sodium Hypochlorite, Tert-butyl Alcohol
This product is not subject to the reporting requirements under California's Proposition 65.

Registered Product Not applicable.
Information
Canadian Regulations
WHMIS Classification Not applicable.
WHMIS Icon
Registered Product Not applicable.
Information
Chemical Inventory Status

All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control
Act (TSCA) Chemical Substance Inventory

Continued on Next Page
Page: 3/4

PROFESSIONAL VANISH MILDEW STAIN CLEANER

Material Safety Data Sheet

Section 16. Other Information
Other Special
Considerations
Version

Not available.
1.01

Notice to Reader
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied,
as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to
evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws
and regulations.

FICHE DE DONNÉES DE SÉCURITÉ

CARPET SCIENCE Détachant
HMIS
Santé
Risque d'incendie
Réactivité

NFPA
1
1
0

1
1
0

Protection individuelle

None / Aucune / Ninguno

None / Aucune / Ninguno

Numéro de révision: 1

Date de révision: 2007-06-08

1. IDENTIFICATION DE LA SUBSTANCE/PREPARATION ET DE LA SOCIETE/ENTREPRISE
Nom du produit:

CARPET SCIENCE Détachant

MSDS #:
Code du produit:
Utilisation recommandée:

126097001
94350
Industriel/Institutionnel. Soins des Moquettes .

Producteur, importateur, fournisseur:
US Headquarters
JohnsonDiversey, Inc.
8310 16th St.
Sturtevant, Wisconsin 53177-0902
Phone: 1-888-352-2249
MSDS Internet Address:
www.johnsondiversey.com
Téléphone en cas d'urgence:

Canadian Headquarters
JohnsonDiversey - Canada, Inc.
2401 Bristol Circle
Oakville, Ontario L6H 6P1
Phone: 1-800-668-3131

1-800-851-7145 (Prosar); 1-651-917-6133 (Int'l Prosar); 01-800-710-3400 (México)

2. IDENTIFICATION DES DANGERS
Aperçu des premiers secours
ATTENTION. PEUT IRRITER MODÉRÉMENT LES YEUX. PEUT IRRITER MODÉRÉMENT LA PEAU . LIQUIDE ET VAPEUR COMBUSTIBLES.
Principales voies entree:
Contact avec les yeux:
Contact avec la peau:
Inhalation:
Ingestion:

Contact avec les yeux. Contact avec la peau. Inhalation.
Peut irriter modérément les yeux.
Peut irriter modérément la peau.
Aucun à notre connaissance.
Aucun à notre connaissance.

3. COMPOSITION/INFORMATION SUR LES COMPOSANTS
Composants Dangereux
Composant(s)
Alcool isopropylique

CAS #
67-63-0

% en poids
1 - 5%

DL50 Orale
=4396 mg/kg

DL50 Cutanée
=12800 mg/kg

CL50 Inhalatoire
=72.6 mg/L (4 h)

4. PREMIERS SOINS
Contact avec les yeux:
Contact avec la peau:
Inhalation:
Ingestion:
Conditions médicales aggravées:

Rincer immédiatement à grande eau . Si une irritation apparaît, consulter un médecin.
Rincer immédiatement à grande eau . Si une irritation apparaît, consulter un médecin..
Les premiers secours ne sont pas nécessaires.
Les premiers secours ne sont pas nécessaires.
Aucun à notre connaissance.

5. MESURES DE LUTTE CONTRE L'INCENDIE
Moyen d'extinction approprié:
Dangers spécifiques:
Risques Inhabituels
Méthodes particulières d'intervention:

Poudre, eau pulvérisée, mousse, dioxide de carbone.
Alors que ce produit possede un point d'eclair inferieur a 200 Deg. F, il constitue une solution aqueuse a
base d'alcool qui ne soutient pas la combustion .
Aucun à notre connaissance
Aucune méthodes spéciale n'est requise .

Equipements spéciaux pour la protection des intervenants: Comme pour tout incendie, porter un respirateur à air comprimé, MSHA/NIOSH
(approuvé ou équivalent), ainsi qu'une combinaison complète de protection
Moyen d'extinction à ne pas utiliser pour des raisons de sécurité: Pas d'information disponible

6. MESURES A PRENDRE EN CAS DE DÉVERSEMENT ACCIDENTEL
Précautions individuelles:

CARPET SCIENCE Détachant

Revêtir un équipement de protection individuelle approprié (voir Section 8).

1 of 3

6. MESURES A PRENDRE EN CAS DE DÉVERSEMENT ACCIDENTEL
Méthodes de nettoyage:

Utiliser un récipient approprié pour éviter toute contamination du milieu ambiant. Absorber l'écoulement
avec un matériau inerte (p.e.sable sec ou terre), puis mettre dans un conteneur pour déchets chimiques.

7. MANIPULATION ET STOCKAGE
Manipulation:
Éviter le contact avec la peau et les yeux. LIQUIDE ET VAPEUR COMBUSTIBLES . Tenir à l'abri des flammes nues, des surfaces chaudes et des
sources d'inflammation. Utiliser seulement dans des zones bien ventilées. POUR UTILISATOIN COMMERCIALE ET INDUSTRIELLE SEULEMENT
Stockage:
Protéger du gel . Conserver hermétiquement fermé dans un endroit sec, frais et bien ventilé. GARDER HORS DE LA PORTÉE DES ENFANTS.

8. MESURES DE CONTRÔLE DE L'EXPOSITION/PROTECTION INDIVIDUELLE
Mesures d'ordre technique:
Aucune ventilation particulière requise. Ventilation adéquate du local.
Protection individuelle
Protection des yeux:
Protection des mains:
Protection de la peau et du corps:
Protection respiratoire:
Mesures d'hygiène:
Composant(s)
Alcool isopropylique

Aucune condition particulière dans les conditions normales d'utilisation.
Aucune condition particulière dans les conditions normales d'utilisation
Aucune condition particulière dans les conditions normales d'utilisation.
Aucune condition particulière dans les conditions normales d'utilisation .
A manipuler conformément aux normes d'hygiène industrielle et aux consignes de sécurité.
CAS #
67-63-0

ACGIH
400 ppm (STEL)
200 ppm (TWA)

OSHA
980 mg/m3 (TWA)
400 ppm (TWA)

Mexico
500 ppm (STEL)
1225 mg/m3 (STEL)
400 ppm (TWA)
980 mg/m3 (TWA)

9. PROPRIETES PHYSIQUES ET CHIMIQUES
État de la matière:
pH:
Aspect:
Couleur:
Odeur:
Densité:
Densité:
Teneur (%) en COV
(composés
organiques volatils):
Point d'éclair:
Solubilité:
Viscosité:

liquide
7.5
liquide
opaque blanc cassé
fruité
1
8.35 lbs/gal
2.75% *

Masse volumique apparente:
pH de la solution diluée
Densité gazeuse:
Vitesse d'évaporation
Point/intervalle d'ébullition:
Point/intervalle de fusion:
Température de décomposition:
Température d'auto-inflammation:

129°F 54°C
soluble
Pas d'information disponible

Coefficient de partage (n-octanol/eau): Pas d'information disponible
Solubilité dans d'autres solvants: Pas d'information disponible
phosphore élémental :
0 %P

Pas d'information disponible
Pas d'information disponible.
Pas d'information disponible
Pas d'information disponible
212°F 100°C
30.2 °F-1 °C
indéterminé
Pas d'information disponible

* - Titre 17, Code des règlements de la Californie, division 3, chapitre 1, sous-chapitre 8.5, article 2, Produits de consommation, sections 94508

10. STABILITÉ ET RÉACTIVITÉ
Stabilité:
polymérisation:
Produits de décomposition dangereux:
Conditions à éviter:

Le produit est stable.
Une polymérisation dangereuse ne se produit pas..
Aucun raisonnablement prévisible.
Ne pas congeler.

11. INFORMATIONS TOXICOLOGIQUES
Toxicité aiguë
Information sur les composants:

Oral(e) Estimée à un niveau supérieur à 5000 mg/kg; Cutanée Toxicité orale exprimée en DL50 > 2000
mg/kg
Voir la Section 3

Toxicité chronique:

Aucun à notre connaissance

Effets spécifiques
effets cancérogènes:
effets mutagènes:
Toxicité pour la reproduction:
Effets sur l'organe-cible:

Aucun à notre connaissance
Aucun à notre connaissance
Aucun à notre connaissance
Aucun à notre connaissance

CARPET SCIENCE Détachant

2 of 3

11. INFORMATIONS TOXICOLOGIQUES
Composants Dangereux

12. INFORMATIONS ÉCOLOGIQUES
Information environnementales

donnée non disponible

13. CONSIDERATIONS RELATIVES À L'ÉLIMINATION
Déchets des résidus / produits non utilisés:
Le produit non dilué est réglementée par les lois concernant l'environnement et le transport en tant que déchet allumable . Éliminer selon les dispositions
prévues par les différentes réglementations fédérales, provinciales, locales ou d'État .

14. INFORMATIONS RELATIVES AU TRANSPORT
DOT/TDG: S' il vous plait, consulter le document d'expédition pour les renseignements à jour sur le transport

15. INFORMATIONS RÉGLEMENTAIRES
Inventaires internationales
Tous les éléments de ce produit sont énumérés dans les inventaires suivants: États-Unis (TSCA), Canada (DSL/NDSL).
Réglementation des É.-U.
Proposition 65 de la Californie: Ils n'y a pas des ingrédients qui sont assujettis à la déclaration en suivant 'Proposition 65' de Californie
LOI DU DROIT DE SAVOIR DE L'ÉTAT
Composant(s)
Eau
Hexyloxyéthanol
Alcool isopropylique

CAS #
7732-18-5
112-25-4
67-63-0

CERCLA/ SARA
Composant(s)
Hexyloxyéthanol
Alcool isopropylique

CAS #
112-25-4
67-63-0

Composant(s)
Hexyloxyéthanol

MARTK:
X

% en poids
1 - 5%
1 - 5%

NJRTK:
X

CERCLA/SARA RQ (lbs)

CAA HAP
X

CAA ODS

PARTK:
X
X

RIRTK:
X

Section 302, TPQ kg)

Section 313
X
X

CWA Polluants en Priorité

Catégories de risque en vertu de la loi SARA, section 311/312
Immédiat
Différée
Feu:
X
Réactivité
Décompression soudaine
Canada
Catégories de risque du SIMDUT : B3

liquides combustibles.

Composant(s)
Alcool isopropylique

CAS #
67-63-0

NPRI
X

16. AUTRES INFORMATIONS
Cause de la révision:
Préparé par:
Conseils supplémentaires:

Sans objet
NAPRAC
aucune

Avis au lecteur: Ce document a etè prèparè de sources considèrèes techniquement sèrieuses. If ne constitue pas une garantie, ènoncèe ou tacite, de
l'exactitude des renseignements ci-incluses. Les conditions actuelles d'usage et de manutention sont hors du contrôle du vendeur. L'utilisateur doit
s'assurer qu'il posè'de toutes les donnèes en cours, en regard de son utilization particulière et qu'il respecte tous les règlements fèdèraux, des ètats,
provinciaux et municipaux.

CARPET SCIENCE Détachant

3 of 3

The Valspar Corporation
Material Safety Data Sheet
1. PRODUCT AND COMPANY IDENTIFICATION
Material Identification

Product ID:

011.0002400

Product Name:
Product Use:
Print date
Revision Date

GOOF OFF
Paint product.
31/Jan/2007
31/Aug/2005

Company Identification
The Valspar Corporation - Architectural Coatings Division
1191 Wheeling Road
Wheeling, IL 60090
Manufacturer's Phone:
1-847-520-8580
24-Hour Medical Emergency
Phone:

1-888-345-5732

2. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS
Common Name
CAS-No.
XYLENE
1330-20-7
ETHYLBENZENE
100-41-4
DIETHYLENE GLYCOL
MONOMETHYL ETHER
111-77-3
TOLUENE
108-88-3

Approx.
Chemical name
Weight %
75 - 80
Xylenes (o-, m-, p- isomers)
15 - 20

Ethyl benzene

1-5

Diethylene glycol monomethyl ether

1-5

Toluene

If this section is blank there are no hazardous components per OSHA guidelines.

3. HAZARDS IDENTIFICATION
Primary Routes of Exposure:
Inhalation
Ingestion
Skin absorption
Emergency Overview:
This section not in use.
This product contains ingredients that may contribute to the following potential acute health effects:
Inhalation Effects:
Harmful if inhaled. May affect the brain, nervous system, or respiratory system, causing dizziness, headache, nausea or
respiratory irritation.
Eye Contact:
Corneal Injury/eye damage.

Product ID: 011.0002400

Page 1 / 7

Skin Contact:
May cause moderate skin irritation.
Acute Ingestion:
None known
Other Effects:
May cause central nervous system depression. May cause liver damage. May cause kidney damage.
This product contains ingredients that may contribute to the following potential chronic health effects:
Notice: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain
and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful
or fatal. Possible birth defects hazard. Contains ingredients which may cause birth defects based on animal data. May
cause kidney damage. May cause liver damage.
See Section 11 for toxicological information about Mutagens, Teratogens and Carcinogens.
If this section is blank, no information is available.

4. FIRST AID MEASURES
Inhalation:
If affected by inhalation, move victim to fresh air. If symptoms persist, seek medical attention.
Eye Contact:
In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get
medical attention immediately after flushing.
Skin Contact:
In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. If irritation persists get
medical attention.
Ingestion:
If swallowed , do not induce vomiting. Give large quantities of water. If available, give several glasses of milk. Never give
anything by mouth to an unconscious person. Get medical attention immediately. If swallowed, get medical attention
immediately.
Medical conditions aggravated by exposure: Any respiratory or skin condition.

5. FIRE FIGHTING MEASURES
Flash point (Fahrenheit):
Lower explosive limit:
Upper explosive limit:
Autoignition temperature:
Sensitivity to impact:
Sensitivity to static discharge:
Hazardous combustion products:

80º F ( 27º C) TCC/PM
1%
7%
Not available. º F ( º C)
No.
Subject to static discharge hazards. Please see bonding and
grounding information in Section 7.
See Section 10.

Unusual fire and explosion hazards:
None known.
Extinguishing media:
Carbon dioxide, dry chemical, foam and/or water fog.
Fire fighting procedures:
Use water spray to cool nearby containers and structures exposed to fire.

Product ID: 011.0002400

Page 2 / 7

6. ACCIDENTAL RELEASE MEASURES
Action to be taken if material is released or spilled:
Ventilate area. Avoid breathing of vapors. Use self-containing breathing apparatus or airmask for large spills in a
confined area. Wipe, scrape or soak up in an inert material and put in a container for disposal. See section 5, "Unusual
Fire and Explosion Hazards", for proper container and storage procedures. Remove sources of ignition. Remove with
inert absorbent and non sparking tools. Avoid contact with eyes.

7. HANDLING AND STORAGE
Precautions to be taken in handling and storage:
Keep away from heat, sparks, and flames. Keep container closed when not in use. Do not store above 120 degrees F.
(49 degrees C). Based on flash point and vapor pressure, suitable storage should be provided in accordance with OSHA
regulation 1910.106, Ontario OH&S regulation 851 section 22. Empty containers may contain product residue, including
flammable or explosive vapors. Do not cut, puncture or weld on or near container. All label warnings must be observed
until the container has been commercially cleaned or reconditioned. If the product is used near or above the flashpoint,
an ignition hazard may be present. Activities, uses, or operations which liberate vapor (such as mixing or free fall of
liquids) may also present an ignition hazard. Please ensure containers and other interconnected equipment are properly
bonded and grounded at all times.

8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS
Personal Protective Equipment
Eye and face protection:
Avoid contact with eyes. Wear chemical goggles if there is the possibility of contact or splashing in the eye.
Skin protection:
Appropriate chemical resistant gloves should be worn.To prevent skin contact wear protective clothing covering all
exposed areas.
Respiratory protection:
If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator such as an air
purifying respirator with organic vapor cartridge and dust/mist filter. Consult the respirator manufacturer's literature to
ensure that the respirator will provide adequate protection. Read and follow all respirator manufacturer's instructions.
Ventilation
Required when spraying or applying in confined area. Ventilation equipment should be explosion proof. Eliminate
ignition sources.
Exposure Guidelines
OSHA Permissible Exposure Limits (PEL's)
Common Name
CAS-No.
XYLENE
1330-20-7
ETHYLBENZENE
100-41-4
TOLUENE
108-88-3

Approx.
TWA (final)
Weight %
75 - 80
435 mg/m³ 100 ppm
15 - 20

435 mg/m³ 100 ppm

1-5

200 ppm

Ceilings limits (final)

Skin designations

300 ppm

ACGIH Threshold Limit Value (TLV's)
Common Name
CAS-No.

Approx.
TWA
Weight %

STEL

Product ID: 011.0002400

Page 3 / 7

Ceiling limits

Skin designations

XYLENE
1330-20-7
ETHYLBENZENE
100-41-4
TOLUENE
108-88-3

75 - 80

100 ppm

150 ppm

15 - 20

100 ppm

125 ppm

1-5

50 ppm

Can be absorbed
through the skin.

If this section is blank, no information is available.

9. PHYSICAL PROPERTIES
Odor:
Physical State:
pH:
Vapor pressure:
Vapor density (air = 1.0):
Boiling point:
Solubility in water:
Coefficient of water/oil distribution:
Density (lbs per US gallon):
Specific Gravity
Evaporation rate (butyl acetate = 1.0):

Normal for this product type.
Liquid
Not determined.
28 mmHG @ 68º F ( 20º C)
4.1
230º F ( 110º C)
Insoluble.
Not determined.
7.29
.87
2

10. STABILITY AND REACTIVITY
Stability
Conditions to Avoid:
Incompatibility:
Hazardous Polymerization:
Hazardous Decomposition Products:

Stable
None known.
Strong oxidizers.
None anticipated.
Carbon monoxide and carbon dioxide.

Sensitivity to static discharge:

Subject to static discharge hazards. Please see bonding and
grounding information in Section 7.

11. TOXICOLOGICAL INFORMATION
Mutagens:
Common Name
CAS-No.
TOLUENE
108-88-3

Approx.
California Prop 65 - Developmental
Weight % Toxicity
1-5
Listed: January 1, 1991
Developmental toxin.

California Prop 65 - Reproductive
(Male)

Teratogens:
Carcinogens:
Contains ethylbenzene, which has been determined by NTP to be an animal carcinogen with no known relevance to
humans. IARC has classified ethylbenzene as possibly carcinogenic to humans (2b) on the basis of sufficient evidence of
carcinogenicity in laboratory animals but inadequate evidence of cancer in humans.
Common Name
CAS-No.
ETHYLBENZENE
100-41-4

Approx.
IARC Group 1 - Human
Weight % Evidence
15 - 20

Product ID: 011.0002400

Page 4 / 7

IARC Group 2A - Limited IARC Group 2B Human Data
Sufficient Animal Data
Monograph 77, 2000

Common Name
CAS-No.
ETHYLBENZENE
100-41-4

Approx.
NTP Known
Weight % Carcinogens
15 - 20

NTP Suspect
Carcinogens

NTP Evidence of
Carcinogenicity
male rat-clear evidence;
female rat-some
evidence; male micesome evidence; female
mice-some evidence

Common Name
CAS-No.
ETHYLBENZENE
100-41-4

Approx.
OSHA Select
Weight % Carcinogens
15 - 20

OSHA Possible Select
Carcinogens

ACGIH Carcinogens
Group A3 Confirmed
animal carcinogen with
unknown relevance to
humans.

If this section is blank, no information is available.

12. ECOLOGICAL DATA
Not available at this time.

13. DISPOSAL CONSIDERATIONS
Disposal should be made in accordance with federal, state and local regulations.

14. TRANSPORTATION INFORMATION
U.S. Department of Transportation
Proper Shipping Name:
PAINT RELATED MATERIAL
Hazard Class:
3
UN ID Number:
UN1263
Packing Group:
III
49 CFR Hazardous Material Regulations Parts 100-180
The supplier will apply the combustible liquid exception in 49 CFR 173.150(f), limited quantity or "does not sustain
combustion" exceptions and consumer commodity rules, when authorized. Please check 49 CFR Parts 100-180 to
determine if the use of these exceptions applies to your shipments when re-shipping our products.
International Air Transport Association:
Proper Shipping Name:
PAINT RELATED MATERIAL
Hazard Class:
3
UN ID Number:
UN1263
Packing Group:
III
International Maritime Organization:
Proper Shipping Name:
PAINT RELATED MATERIAL
Hazard Class:
3
Non-Bulk UN ID Number:
UN1263
Packing Group:
III

15. REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS:

Product ID: 011.0002400

Page 5 / 7

15. REGULATORY INFORMATION
Common Name
CAS-No.
XYLENE
1330-20-7

Approx.
SARA 302
Weight %
75 - 80

ETHYLBENZENE
100-41-4

15 - 20

DIETHYLENE GLYCOL
MONOMETHYL ETHER
111-77-3
TOLUENE
108-88-3

1-5

SARA 313

form R reporting required 100
for 1.0% de minimis
concentration
form R reporting required 1000
for 1.0% de minimis
concentration
YES

1-5

SARA 311/312 Hazard Class:
Acute:
Chronic:
Flammability:
Reactivity:
Sudden Pressure:

CERCLA RQ in lbs.

form R reporting required 1000
for 1.0% de minimis
concentration

Yes
Yes
Yes
No
No

U.S. STATE REGULATIONS:
Pennsylvania Right To Know:
ETHYLBENZENE
TOLUENE
DIETHYLENE GLYCOL MONOMETHYL ETHER
XYLENE

100-41-4
108-88-3
111-77-3
1330-20-7

California Proposition 65:
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
Rule 66 status of product

Photochemically reactive.

INTERNATIONAL REGULATIONS - Chemical Inventories
TSCA Inventory:

All components of this product are in compliance with U.S.
TSCA Chemical Substance Inventory Requirements.

Canada Domestic Substances List:

All components of this product are listed on the Domestic
Substances List.

16. OTHER INFORMATION
HMIS Codes
Health:
Flammability:
Reactivity:
PPE:

2
3
1
X - See Section 8 for Personal Protective Equipment (PPE).

Product ID: 011.0002400

Page 6 / 7

Abbreviations:
OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer, NIOSH National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH - American Conference
of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management District, TSCA - Toxic
Substances Control Act, IATA - International Air Transport Association, IMO - International Maritime Organization, DOT Department of Transportation, NA - Not applicable, NOT ESTAB - Not established, N.A.V. - Not available, RQ Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L - Grams per liter, MM - Millimeters,
MPPCF - Millions of particles per cubic foot, PPM - parts per million, PPT - parts per thousand, TCC/PM - Tag closed
cup / Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time Weighted Average, STEL - Short term
exposure limit, C - Celsius, F - Fahrenheit.
Disclaimer:
The data on this sheet represent typical values. Since application variables are a major factor in product performance, this
information should serve only as a general guide. Valspar assumes no obligation or liability for use of this information.
UNLESS VALSPAR AGREES OTHERWISE IN WRITING, VALSPAR MAKES NO WARRANTIES, EXPRESS OR
IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. VALSPAR WILL NOT BE
LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only remedy for any defect in this
product is the replacement of the defective product, or a refund of its purchase price, at our option. This MSDS contains
additional information required by the state of Pennsylvania.

Product ID: 011.0002400

Page 7 / 7

The Valspar Corporation
Material Safety Data Sheet
1. PRODUCT AND COMPANY IDENTIFICATION
Material Identification

Product ID:

011.0002417.004

Product Name:
Product Use:
Effective date:
Revision Date
UN ID Number:
WHMIS Classification:

CAN GOOF OFF 16 OZ 12P
Paint product.
12/Oct/2005
31/Aug/2005
UN1263
D2B Toxic Material D2A Very Toxic Material B2 Flammable Liquids

Company Identification
1191 Wheeling Road
Wheeling, IL 60090
Tech Info Phone:

847-520-8580

24-Hour Medical Emergency
Phone:

1-888-345-5732

2. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS
Common Name
CAS-No.
XYLENE
1330-20-7
ETHYLBENZENE
100-41-4
DIETHYLENE GLYCOL
MONOMETHYL ETHER
111-77-3
TOLUENE
108-88-3

Approx. Chemical Name
Weight %
75 - 80
Xylenes (o-, m-, pisomers)
15 - 20
Ethyl benzene

CAS Number

1-5

Diethylene glycol
monomethyl ether

111-77-3

1-5

Toluene

108-88-3

Trade Secret Number

1330-20-7
100-41-4

If this section is blank there are no hazardous components per OHSA guidelines.

3. HAZARDS IDENTIFICATION
Primary Routes of Exposure:
Inhalation
Ingestion
Skin absorption
Emergency Overview:
This section not in use.
This product contains ingredients that may contribute to the following potential acute health effects:
Inhalation Effects:
Harmful if inhaled. May affect the brain, nervous system, or respiratory system, causing dizziness, headache,
nausea or respiratory irritation.

Product ID: 011.0002417.004

Page 1 of 7

Eye Contact:
Corneal Injury/eye damage.
Skin Contact:
May cause moderate skin irritation.
Acute Ingestion:
None known
Other Effects:
May cause central nervous system depression. May cause liver damage. May cause kidney damage.
This product contains ingredients that may contribute to the following potential chronic health effects:
Notice: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain
and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be
harmful or fatal. Possible birth defects hazard. Contains ingredients which may cause birth defects based on animal
data. May cause kidney damage. May cause liver damage.
See Section 11 for toxicological information about Mutagens, Teratogens and Carcinogens.
If this section is blank, no information is available.

4. FIRST AID MEASURES
Inhalation:
If affected by inhalation, move victim to fresh air. If symptoms persist, seek medical attention.
Eye Contact:
In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get
medical attention immediately after flushing.
Skin Contact:
In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. If irritation persists get
medical attention.
Ingestion:
If swallowed , do not induce vomiting. Give large quantities of water. If available, give several glasses of milk. Never
give anything by mouth to an unconscious person. Get medical attention immediately. If swallowed, get medical
attention immediately.
Medical conditions aggravated by exposure: Any respiratory or skin condition.

5. FIRE FIGHTING MEASURES
Flash point (Fahrenheit):
Lower explosive limit:
Upper explosive limit:
Autoignition temperature:
Sensitivity to impact:
Sensitivity to static discharge:
Hazardous combustion products:

80º F ( 27º C) TCC/PM
1%
7%
Not available. º F ( º C)
No.
Subject to static discharge hazards. Please see bonding
and grounding information in Section 7.
See Section 10.

Unusual fire and explosion hazards:
None known.
Extinguishing media:
Carbon dioxide, dry chemical, foam and/or water fog.

Product ID: 011.0002417.004

Page 2 of 7

Fire fighting procedures:
Use water spray to cool nearby containers and structures exposed to fire.

6. ACCIDENTAL RELEASE MEASURES
Action to be taken if material is released or spilled:
Ventilate area. Avoid breathing of vapors. Use self-containing breathing apparatus or airmask for large spills in a
confined area. Wipe, scrape or soak up in an inert material and put in a container for disposal. See section 5,
"Unusual Fire and Explosion Hazards", for proper container and storage procedures. Remove sources of ignition.
Remove with inert absorbent and non sparking tools. Avoid contact with eyes.

7. HANDLING AND STORAGE
Precautions to be taken in handling and storage:
Keep away from heat, sparks, and flames. Keep container closed when not in use. Do not store above 120 degrees
F. (49 degrees C). Based on flash point and vapor pressure, suitable storage should be provided in accordance with
OSHA regulation 1910.106, Ontario OH&S regulation 851 section 22. Empty containers may contain product residue,
including flammable or explosive vapors. Do not cut, puncture or weld on or near container. All label warnings must
be observed until the container has been commercially cleaned or reconditioned. If the product is used near or above
the flashpoint, an ignition hazard may be present. Activities, uses, or operations which liberate vapor (such as mixing
or free fall of liquids) may also present an ignition hazard. Please ensure containers and other interconnected
equipment are properly bonded and grounded at all times.

8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS
Personal Protective Equipment
Eye and face protection:
Avoid contact with eyes. Wear chemical goggles if there is the possibility of contact or splashing in the eye.
Skin protection:
Appropriate chemical resistant gloves should be worn.To prevent skin contact wear protective clothing covering all
exposed areas.
Respiratory protection:
If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator such as an
air purifying respirator with organic vapor cartridge and dust/mist filter. Consult the respirator manufacturer's literature
to ensure that the respirator will provide adequate protection. Read and follow all respirator manufacturer's
instructions.
Ventilation
Required when spraying or applying in confined area. Ventilation equipment should be explosion proof. Eliminate
ignition sources.
Exposure Guidelines
OSHA Permissible Exposure Limits (PEL's)
Common Name
CAS-No.
XYLENE
1330-20-7
ETHYLBENZENE
100-41-4
TOLUENE
108-88-3

Approx. TWA (final)
Weight %
75 - 80
435 mg/m3 100 ppm
15 - 20

435 mg/m3 100 ppm

1-5

200 ppm

Ceilings limits (final)

300 ppm

ACGIH Threshold Limit Value (TLV's)

Product ID: 011.0002417.004

Page 3 of 7

Skin designations

Common Name
CAS-No.
XYLENE
1330-20-7
ETHYLBENZENE
100-41-4
TOLUENE
108-88-3

Approx. TWA
Weight %
75 - 80
100 ppm

STEL

15 - 20

100 ppm

125 ppm

1-5

50 ppm

Ceiling limits

Skin
designations

150 ppm

Can be absorbed
through the skin.

If this section is blank, no information is available.

9. PHYSICAL PROPERTIES
Odor:
Odor threshold:
Physical State:
pH:
Vapor pressure:
Vapor density (air = 1.0):
Boiling point:
Solubility in water:
Coefficient of water/oil distribution:
Density (lbs per US gallon):
Specific Gravity
Evaporation rate (butyl acetate = 1.0):

Normal for this product type.
Not available.
Liquid
Not determined.
28 mmHG @ 68º F ( Not Available. º C)
4.1
230º F ( 110º C)
Insoluble.
Not determined.
7.29
.87
2

10. STABILITY AND REACTIVITY
Stability
Conditions to Avoid:
Incompatibility:
Hazardous Polymerization:
Hazardous Decomposition Products:

Stable
None known.
Strong oxidizers.
None anticipated.
Carbon monoxide and carbon dioxide.

Sensitivity to static discharge:

Subject to static discharge hazards. Please see bonding
and grounding information in Section 7.

11. TOXICOLOGICAL INFORMATION
Common Name
CAS-No.
XYLENE
1330-20-7
ETHYLBENZENE
100-41-4
DIETHYLENE GLYCOL
MONOMETHYL ETHER
111-77-3
TOLUENE
108-88-3

Approx. NIOSH - Selected LD50s and LC50s
Weight %
75 - 80
Inhalation LC50 Rat : 5000 ppm/4H
Oral LD50 Rat : 4300 mg/kg
Dermal LD50 Rabbit : >1700 mg/kg
15 - 20
Oral LD50 Rat : 3500 mg/kg
Dermal LD50 Rabbit : 17800 uL/kg
1-5
Oral LD50 Rat : 4 mL/kg
Oral LD50 Mouse : 8222 mg/kg
Dermal LD50 Rabbit : 2500 uL/kg
1-5
Inhalation LC50 Rat : 49 gm/m3/4H
Inhalation LC50 Mouse : 400 ppm/24H
Oral LD50 Rat : 636 mg/kg
Dermal LD50 Rabbit : 14100 uL/kg

Mutagens:

Product ID: 011.0002417.004

Page 4 of 7

Common Name
CAS-No.
TOLUENE
108-88-3

Approx. Calif- Prop. 65. Developmental
Weight % Toxicity
1-5
Listed: January 1, 1991
Developmental toxin.

California Prop 65 - reproductive
male

Teratogens:
Carcinogens:
Contains ethylbenzene, which has been determined by NTP to be an animal carcinogen with no known relevance to
humans. IARC has classified ethylbenzene as possibly carcinogenic to humans (2b) on the basis of sufficient
evidence of carcinogenicity in laboratory animals but inadequate evidence of cancer in humans.
Common Name
CAS-No.
ETHYLBENZENE
100-41-4

Approx. IARC Group 1 - Human IARC Group 2A - limited IARC Group 2b Weight % Evidence
human data
sufficient animal data
15 - 20
Monograph 77, 2000

Common Name
CAS-No.
ETHYLBENZENE
100-41-4

Approx. NTP Known
Weight % carcinogens
15 - 20

NTP Suspect
carcinogens

NTP Evidence of
carcinogenicity
male rat-clear evidence;
female rat-some
evidence; male micesome evidence; female
mice-some evidence

Common Name
CAS-No.
ETHYLBENZENE
100-41-4

Approx. OSHA Select
Weight % carcinogens
15 - 20

OSHA Possible select
carcinogens

ACGIH Carcinogens

If this section is blank, no information is available.

12. ECOLOGICAL DATA
Not available at this time.

13. DISPOSAL CONSIDERATIONS
Disposal should be made in accordance with federal, state and local regulations.

14. TRANSPORTATION INFORMATION
Canadian Transport of Dangerous Goods
Proper Shipping Name:
PAINT
Hazard Class:
3
UN ID Number:
UN1263
Packing Group:
III
International Air Transport Association:
Proper Shipping Name:
PAINT
Hazard Class:
3
UN ID Number:
UN1263
Packing Group:
III
Product ID: 011.0002417.004

Page 5 of 7

Group A3 Confirmed
animal carcinogen with
unknown relevance to
humans.

International Maritime Organization:
Proper Shipping Name:
PAINT
Hazard Class:
3
UN ID Number:
UN1263
Packing Group:
III

15. REGULATORY INFORMATION
INTERNATIONAL REGULATIONS - Chemical Inventories
TSCA Inventory:

All components of this product are in compliance with U.S.
TSCA Chemical Substance Inventory Requirements.

Canada Domestic Substances List:

All components of this product are listed on the Domestic
Substances List.

Canada National Pollutant Release Inventory:
Common Name
CAS-No.
XYLENE
1330-20-7
ETHYLBENZENE
100-41-4
DIETHYLENE GLYCOL
MONOMETHYL ETHER
111-77-3
TOLUENE
108-88-3

Approx. NPRI Status
Weight %
75 - 80
[reporting required]
15 - 20

[reporting required]

1-5

YES

1-5

[reporting required]

This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations and the MSDS contains all of the information required by the Controlled Products Regulations.

16. OTHER INFORMATION
HMIS Codes
Health:
Flammability:
Reactivity:
PPE:

2
3
1
X - See Section 8 for Personal Protective Equipment (PPE).

Abbreviations:
OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer,
NIOSH - National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH American Conference of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management
District, TSCA - Toxic Substances Control Act, IATA - International Air Transport Association, IMO - International
Maritime Organization, DOT - Department of Transportation, NA - Not applicable, NOT ESTAB - Not established,
N.A.V. - Not available, RQ - Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L - Grams
per liter, MM - Millimeters, MPPCF - Millions of particles per cubic foot, PPM - parts per million, PPT - parts per
thousand, TCC/PM - Tag closed cup / Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time
Weighted Average, STEL - Short term exposure limit, C - Celsius, F - Fahrenheit.

Product ID: 011.0002417.004

Page 6 of 7

Disclaimer:
The data on this sheet represent typical values. Since application variables are a major factor in product performance,
this information should serve only as a general guide. Valspar assumes no obligation or liability for use of this
information. UNLESS VALSPAR AGREES OTHERWISE IN WRITING, VALSPAR MAKES NO WARRANTIES,
EXPRESS OR IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT.
VALSPAR WILL NOT BE LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only
remedy for any defect in this product is the replacement of the defective product, or a refund of its purchase price, at
our option. This MSDS contains additional information required by the state of Pennsylvania.
Preparation Information:
Prepared By:
Print date
Revision Date

Regulatory Affairs Department
12/Oct/2005
31/Aug/2005

Technical Information:
The Valspar Corporation - Architectural Coatings Division
1191 Wheeling Road
Wheeling, IL 60090
Tech Info Phone:
847-520-8580
24-Hour Medical Emergency
Phone:

1-888-345-5732

Product ID: 011.0002417.004

Page 7 of 7

The Valspar Corporation
Material Safety Data Sheet
1. PRODUCT AND COMPANY IDENTIFICATION
Material Identification

Product ID:

011.0002316.077

Product Name
Product Use:
Print date
Revision Date

GRAF RMVR 16OZ SPRAY
Paint product.
2005/04/14
2005/04/14

6U

Company Identification
The Valspar Corporation - Architectural Coatings Division
1000 Lake Road
Medina, OH 44256
Manufacturer's Phone:
1-330-725-4511
24-Hour Medical Emergency
Phone:

1-888-345-5732

2. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS
Common Name
CAS-No.
XYLENE
1330-20-7
TOLUENE
108-88-3
ETHYLBENZENE
100-41-4
PROPANE
74-98-6
DIETHYLENE GLYCOL
MONOMETHYL ETHER
111-77-3
BUTANE
106-97-8
METHYL ALCOHOL
67-56-1

approx.
Weight %
45 - 50

Chemical name
Xylenes (o-, m-, p- isomers)

15 - 20

Toluene

10 - 15

Ethyl benzene

10 - 15

Propane

5 - 10

Diethylene glycol monomethyl ether

1-5

Butane

1-5

Methyl alcohol

If this section is blank there are no hazardous components per OSHA guidelines.

3. HAZARDS IDENTIFICATION
Primary Routes of Exposure:
Inhalation
Ingestion
Skin absorption

Product ID:

011.0002316.077

Page 1 of 8

Emergency Overview:
This section not in use.
This product contains ingredients that may contribute to the following potential acute health effects:
Inhalation Effects:
Harmful if inhaled. May affect the brain, nervous system, or respiratory system, causing dizziness, headache, nausea or
respiratory irritation.
Eye Contact:
Corneal Injury/eye damage.
Skin Contact:
May cause moderate skin irritation. May be harmful if absorbed through skin.
Acute Ingestion:
May be fatal or cause blindness if swallowed.
Other Effects:
May cause central nervous system depression. May cause liver damage. Contains ingredient which is considered highly
toxic. May cause kidney damage.
This product contains ingredients that may contribute to the following potential chronic health effects:
Notice: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain
and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful
or fatal.Possible birth defects hazard. Contains ingredients which may cause birth defects based on animal data. May
cause kidney damage. May cause liver damage.
See Section 11 for toxicological information about Mutagens, Teratogens and Carcinogens.
If this section is blank, no information is available.

4. FIRST AID MEASURES
Inhalation:
If affected by inhalation, move victim to fresh air. If symptoms persist, seek medical attention.
Eye Contact:
In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get
medical attention immediately after flushing.
Skin Contact:
In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. If irritation persists get
medical attention.
Ingestion:
Poison! Get medical attention immediately. If swallowed, contact medical personnel immediately to determine best course
of action.
Medical conditions aggravated by exposure: Any respiratory or skin condition.

5. FIRE FIGHTING MEASURES
Product ID:

011.0002316.077

Page 2 of 8

Flash point (Fahrenheit):
Lower explosive limit:
Upper explosive limit:
Autoignition temperature:
Sensitivity to impact:
Sensitivity to static discharge:
information in Section 7.
Hazardous combustion products:

-31º F ( -35º C) TCC/PM
1%
23 %
Not available.º F ( º C)
No.
Subject to static discharge hazards. Please see bonding and grounding
See Section 10.

Unusual fire and explosion hazards:
None known.
Extinguishing media:
Carbon dioxide, dry chemical, foam and/or water fog.
Fire fighting procedures:
Use water spray to cool nearby containers and structures exposed to fire.

6. ACCIDENTAL RELEASE MEASURES
Action to be taken if material is released or spilled:
Ventilate area. Avoid breathing of vapors. Use self-containing breathing apparatus or airmask for large spills in a confined
area. Wipe, scrape or soak up in an inert material and put in a container for disposal. See section 5, "Unusual Fire and
Explosion Hazards", for proper container and storage procedures. Remove sources of ignition. Remove with inert
absorbent and non sparking tools. Avoid contact with eyes.

7. HANDLING AND STORAGE
Precautions to be taken in handling and storage:
Keep away from heat, sparks, and flames. Keep container closed when not in use. Do not store above 120 degrees F. (49
degrees C). Based on flash point and vapor pressure, suitable storage should be provided in accordance with OSHA
regulation 1910.106, Ontario OH&S regulation 851 section 22. Empty containers may contain product residue, including
flammable or explosive vapors. Do not cut, puncture or weld on or near container. All label warnings must be observed
until the container has been commercially cleaned or reconditioned. If the product is used near or above the flashpoint, an
ignition hazard may be present. Activities, uses, or operations which liberate vapor (such as mixing or free fall of liquids)
may also present an ignition hazard. Please ensure containers and other interconnected equipment are properly bonded
and grounded at all times.

8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS
Personal Protective Equipment
Eye and face protection:
Avoid contact with eyes. Wear chemical goggles if there is the possibility of contact or splashing in the eye.
Skin protection:
Appropriate chemical resistant gloves should be worn.To prevent skin contact wear protective clothing covering all
exposed areas.
Respiratory protection:
If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator such as an air
purifying respirator with organic vapor cartridge and dust/mist filter. Consult the respirator manufacturer's literature to
ensure that the respirator will provide adequate protection. Read and follow all respirator manufacturer's instructions.

Product ID:

011.0002316.077

Page 3 of 8

Ventilation
Required when spraying or applying in confined area. Ventilation equipment should be explosion proof. Eliminate ignition
sources.
Exposure Guidelines
OSHA Permissible Exposure Limits (PEL's)
Common Name
CAS-No.
XYLENE
1330-20-7
TOLUENE
108-88-3
ETHYLBENZENE
100-41-4
PROPANE
74-98-6
METHYL ALCOHOL
67-56-1

approx.
Weight %
45 - 50

TWA (final)

Ceilings limits (final)

Skin designations

435 MGM3 100 ppm

15 - 20

200 ppm

300 ppm

10 - 15

435 MGM3 100 ppm

10 - 15

1800 MGM3 1000 ppm

1-5

260 MGM3 200 ppm

ACGIH Threshold Limit Value (TLV's)
Common Name
CAS-No.
XYLENE
1330-20-7
TOLUENE
108-88-3
ETHYLBENZENE
100-41-4
PROPANE
74-98-6
BUTANE
106-97-8
METHYL ALCOHOL
67-56-1

approx.
Weight %
45 - 50

TWA

STEL

100 ppm

15 - 20

50 ppm

10 - 15

100 ppm

10 - 15

1000 ppm

1-5

1000 ppm

1-5

200 ppm

Ceiling limits

150 ppm
Can be absorbed
through the skin.
125 ppm

250 ppm

If this section is blank, no information is available.

9. PHYSICAL PROPERTIES
Odor:
Physical State:
pH:
Vapor pressure:
Vapor density (air = 1.0):
Boiling point:
Solubility in water:
Coefficient of water/oil distribution:
Density (lbs per US gallon):

Product ID:

Skin
designations

Normal for this product type.
Liquid
Not determined.
NOT DETERMINED mmHG @ 68º F ( 20º C)
4.1
-42º F ( -41º C)
Not determined.
Not determined.
6.7

011.0002316.077

Page 4 of 8

Can be absorbed
through the skin.

Specific Gravity
Evaporation rate (butyl acetate = 1.0):

.8
5.9

10. STABILITY AND REACTIVITY
Stability
Conditions to Avoid:
Incompatibility:
Hazardous Polymerization:
Hazardous Decomposition Products:

Stable
None known.
Strong oxidizers.
None anticipated.
Carbon monoxide and carbon dioxide.

Sensitivity to static discharge:

Subject to static discharge hazards. Please see bonding and grounding
information in Section 7.

11. TOXICOLOGICAL INFORMATION
Mutagens:
Common Name
CAS-No.
TOLUENE
108-88-3

approx.
Weight %
15 - 20

Calif- Prop. 65. Developmental
Toxicity
Listed: January 1, 1991
Developmental toxin.

California Prop 65 - reproductive
male

Teratogens:

Carcinogens:
Contains ethylbenzene, which has been determined by NTP to be an animal carcinogen with no known relevance to
humans. IARC has classified ethylbenzene as possibly carcinogenic to humans (2b) on the basis of sufficient evidence of
carcinogenicity in laboratory animals but inadequate evidence of cancer in humans.
Common Name
approx.
IARC Group 1 - Human IARC Group 2A IARC Group 2b CAS-No.
Weight %
Evidence
limited human data
sufficient animal data
ETHYLBENZENE
10 - 15
Monograph 77, 2000
100-41-4
Common Name
CAS-No.
ETHYLBENZENE
100-41-4

approx.
Weight %
10 - 15

NTP Known
carcinogens

NTP Suspect
carcinogens

Common Name
CAS-No.
ETHYLBENZENE
100-41-4

approx.
Weight %
10 - 15

OSHA Select
carcinogens

OSHA Possible select ACGIH Carcinogens
carcinogens
Group A3 Confirmed
animal carcinogen with
unknown relevance to
humans.

Product ID:

011.0002316.077

Page 5 of 8

NTP Evidence of
carcinogenicity
male rat-clear
evidence; female ratsome evidence; male
mice-some evidence;
female mice-some
evidence

If this section is blank, no information is available.

12. ECOLOGICAL DATA
Not available at this time.

13. DISPOSAL CONSIDERATIONS
Disposal should be made in accordance with federal, state and local regulations.

14. TRANSPORTATION INFORMATION
U.S. Department of Transportation
Proper Shipping Name:
CONSUMER COMMODITY ORM-D
UN ID Number:
CONCOM
49 CFR Hazardous Material Regulations Parts 100-180
The supplier will apply the combustible liquid exception in 49 CFR 173.150(f), limited quantity or "does not sustain
combustion" exceptions and consumer commodity rules, when authorized. Please check 49 CFR Parts 100-180 to
determine if the use of these exceptions applies to your shipments when re-shipping our products.
International Air Transport Association:
Proper Shipping Name:
AEROSOLS, FLAMMABLE
Hazard Class:
2.1
UN ID Number:
UN1950
International Maritime Organization:
Proper Shipping Name:
AEROSOLS
Hazard Class:
2
UN ID Number:
UN1950

15. REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS:
Common Name
approx.
CAS-No.
Weight %
XYLENE
45 - 50
1330-20-7
TOLUENE
108-88-3

15 - 20

ETHYLBENZENE
100-41-4

10 - 15

DIETHYLENE GLYCOL
MONOMETHYL ETHER
111-77-3
METHYL ALCOHOL
67-56-1

5 - 10

Product ID:

SARA 302

1-5

011.0002316.077

Page 6 of 8

SARA 313

CERCLA RQ IN LBS.

form R reporting
required for 1.0% de
minimis concentration
form R reporting
required for 1.0% de
minimis concentration
form R reporting
required for 1.0% de
minimis concentration
YES

100

form R reporting
required for 1.0% de
minimis concentration

5000

1000

1000

SARA 311/312 Hazard Class:
Acute:
Yes
Chronic:
Yes
Flammability:
Yes
Reactivity:
No
Sudden Pressure:
Yes
U.S. STATE REGULATIONS:

Pennsylvania Right To Know:
XYLENE
METHYL ALCOHOL
PROPANE
DIETHYLENE GLYCOL MONOMETHYL ETHER
ETHYLBENZENE
BUTANE
TOLUENE

1330-20-7
67-56-1
74-98-6
111-77-3
100-41-4
106-97-8
108-88-3

California Proposition 65:
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
Rule 66 status of product

Photochemically reactive.

INTERNATIONAL REGULATIONS - Chemical Inventories
TSCA Inventory:

All components of this product are in compliance with U.S. TSCA Chemical
Substance Inventory Requirements.

Canada Domestic Substances List:

All components of this product are listed on the Domestic Substances List.

16. OTHER INFORMATION
HMIS Codes
Health:
Flammability:
Reactivity:
PPE:

2
4
1
X - See Section 8 for Personal Protective Equipment (PPE).

Abbreviations:
OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer, NIOSH National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH - American Conference
of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management District, TSCA - Toxic
Substances Control Act, IATA - International Air Transport Association, IMO - International Maritime Organization, DOT Department of Transportation, NA - Not applicable, NOT ESTAB - Not established, N.A.V. - Not available, RQ Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L - Grams per liter, MM - Millimeters,

Product ID:

011.0002316.077

Page 7 of 8

MPPCF - Millions of particles per cubic foot, PPM - parts per million, PPT - parts per thousand, TCC/PM - Tag closed
cup / Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time Weighted Average, STEL - Short term
exposure limit, C - Celsius, F - Fahrenheit.
Disclaimer:
The data on this sheet represent typical values. Since application variables are a major factor in product performance, this
information should serve only as a general guide. Valspar assumes no obligation or liability for use of this information.
UNLESS VALSPAR AGREES OTHERWISE IN WRITING, VALSPAR MAKES NO WARRANTIES, EXPRESS OR
IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. VALSPAR WILL NOT BE
LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only remedy for any defect in this
product is the replacement of the defective product, or a refund of its purchase price, at our option. This MSDS contains
additional information required by the state of Pennsylvania.

Product ID:

011.0002316.077

Page 8 of 8

Material Safety Data Sheet
WHMIS (Pictograms)

WHMIS (Classification)

Personal protective equipment

WHMIS CLASS B-3: Combustible liquid with a flash point
between 37.8°C (100°F) and 93.3°C (200°F).

Section 1. Product and Company Identification
Product
name /
Trade name

Solvent Mineral Spirit

Paint Thinner

Associated
Product’s Item
Code

SOLV 1

83-326

Synonym

Petroleum Distillate

CAS #

Not available.

Chemical family

Aliphatic hydrocarbon (Solvent.)

Validation date

11/8/2007.
Nov. 08 2007

Chemical formula

Not available.

Print date

11/8/2007.
Nov. 08 2007

Manufacturer

Recochem Inc.
850 Montee de Liesse
Montreal, Quebec
514-341-3550

In case of
emergency

Material uses

Not available.

Recochem Inc.
Communications and Regulatory
Affairs Department
(905) 791-1788

Section 2. Hazardous Ingredients
Canada
Name
Petroleum Distillate

CAS number

%
100

There are no ingredients or additional ingredients present which, within the current knowledge of the
supplier and in the concentrations applicable, are classified as hazardous to health or the environment and
hence require reporting in this section.

Section 3. Hazard Identification
Emergency Overview

WARNING !
FLAMMABLE LIQUID AND VAPOR. COMBUSTIBLE.
Flammable liquid. Keep away from heat, sparks and flame. Avoid breathing vapor or mist. Avoid contact with skin
and clothing. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use.

Potential Acute Health
Effects

See Section #11: "Toxicological Information" for further human health effects.
This product may cause mild irritatation to eyes and skin upon contact.
Prolonged and repeated contact with skin can cause drying of the skin resulting in irritation and dermatitis.
Inflammation of the eye is characterized by mild redness, watering, and itching.
Skin inflammation is characterized by mild itching, scaling, reddening.
Ingestion can cause burning sensation, vomiting, drowsiness and in severe cases pulmonary edema.
Inhalation of excessive amounts may result in impairment, such as drowsiness, lack of coordination, headache and
nausea.

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Note to Physician

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Aspiration hazard if swallowed. Can enter lungs and cause damage. Small amounts of liquid aspirated into the
respiratory system during ingestion or from vomiting may cause mild to severe pulmonary injury and possible death.

Section 4. First aid measures
Eye contact

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.
Check for and remove any contact lenses. Get medical attention if irritation occurs.

Skin contact

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if
symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Inhalation

Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the
person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or
are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Ingestion

Wash out mouth with water. Remove dentures if any. Move exposed person to fresh air. Keep person warm and at
rest. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink.
Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so
by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get
medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.

Section 5. Fire fighting measures
Products of combustion

No specific data.

Fire-fighting media and
instructions

Use dry chemical, CO2, water spray (fog) or foam.

Fire Hazards

Container explosion may occur under fire conditions or when heated. Vapor may travel a considerable distance to
source of ignition and flash back. Vigorously supports combustion. Combustible when exposed to heat or flame.

Explosion Hazards

Vapours may travel along ground and flashback along vapour trail.

Section 6. Accidental release measures
Small spill and leak

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble or absorb
with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosionproof equipment. Dispose of via a licensed waste disposal contractor.

Large spill and leak

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows.
Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous
earth and place in container for disposal according to local regulations (see section 13). Use spark-proof tools and
explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material
may pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section
13 for waste disposal.

Section 7. Handling and Storage
Handling

Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited
in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Do not breathe vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Use
only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage
areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative
made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open
flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling)
equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or
explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before

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transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container.
See Section #10 for applicable incompatible materials.
Do not store above the following temperature: 42°C (107.6°F). Store in accordance with local regulations. Store in a
segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources.
Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have
been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.

Storage

Section 8. Exposure controls, personal protection
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to
keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls
also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation
equipment.

Engineering controls

Personal protection
Eyes Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is
necessary to avoid exposure to liquid splashes, mists, gases or dusts.
Recommended: splash goggles

Body Personal protective equipment for the body should be selected based on the task being performed and the risks
involved and should be approved by a specialist before handling this product.

Respiratory Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment

indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards
of the product and the safe working limits of the selected respirator.

Hands Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when
handling chemical products if a risk assessment indicates this is necessary.
>8 hours (breakthrough time): nitrile rubber

Product name

Exposure limits

Canada
Petroleum Distillate

ACGIH (Canada, 2003).
TWA: 100 ppm 8 hour(s).
TWA: 525 mg/m³ 8 hour(s).

United States
Petroleum Distillate

OSHA (United States, 2003).
TWA: 500 ppm 8 hour(s).
TWA: 2900 mg/m³ 8 hour(s).

Section 9. Physical and chemical properties
Physical State and
Appearance

Liquid.

Odour

Petroleum distillates

Molecular weight

Not applicable.

Taste

Not available.

pH

Not applicable.

Colour

Not available.

Boiling/condensation point

150 to 210°C (302 to 410°F)

Volatility

100% (v/v), 100% (w/w)

Melting/freezing point

-58°C (-72.4°F)

Evaporation 0.1 (Butyl acetate. = 1)
rate

Relative density

0.79

Odour
Threshold

Continued on next page

Not available.

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Vapour Pressure

0.29 kPa (2.2 mm Hg)

Viscosity

Kinematic: 0.0114 cm2/s (1.14 cSt)

Vapour Density

5 [Air = 1]

Solubility

Easily soluble in the following materials: diethyl ether, noctanol.
Insoluble in the following materials: water.

VOC Content

790 (g/l).

Other
Properties

Not available.

The product is:

Combustible.

Auto-ignition temperature 229°C (444.2°F)
Flash Point

Closed cup: 42°C (107.6°F) [Tagliabue. (ASTM D56)]

Flammable limits

Lower: 1%
Upper: 13.3%

Fire hazards in the
presence of various
substances

Flammable in the presence of open flames, sparks and static discharge. This product is combustible if exposed to
heat or when in involved in a fire and in contact with combustible materials which may act as a wick.

Section 10. Stability and reactivity
Stability

The product is stable. Under normal conditions of storage and use, hazardous polymerization will not occur.

Conditions of instability

No additional remark.

Incompatibility with
various substances

Reactive with oxidizing agents.

Section 11. Toxicological information
Routes of entry

Eye contact. Inhalation. Ingestion.

Environmental effects

No known significant effects or critical hazards.

Acute effects on humans
Eyes May cause mild eye irritation.
Skin May cause mild skin irritation.
Inhalation Slightly hazardous by the following route of exposure: of inhalation. Exposure to very high concentrations can cause
dizziness, lightheadness, headache, nausea, and blurrred vision. Higher levels may cause unconsciousness.

Ingestion This product is of very low acute toxicity. Aspiration hazard if swallowed. Can enter lungs and cause damage.
Chronic effects on humans

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Section 12. Ecological information
Ecotoxicity

For accidential discharges into environment, see Section #6: "Accidential Release Measures" for suggested
instructions.
No known significant effects or critical hazards.
Not available.

Section 13. Disposal considerations
Waste information

The generation of waste should be avoided or minimized wherever possible. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all
times comply with the requirements of environmental protection and waste disposal legislation and any regional local
authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.

Disposal should be in accordance with applicable regional, national and local laws and regulations.

Section 14. Transport information
Canada Transportation of Dangerous Goods (TDG) Information
Primary Class
Subsidiary Class (if
applicable)

Class 3: Flammable liquid.

Proper shipping name
Hazard identification
number
Packing group

PETROLEUM DISTILLATES, N.O.S.
UN 1268

Special Provisions

In containers of 450L or less this product is not classified as a
Dangerous Goods according to TDG exemption 1.33

-

III

International Maritime Dangerous Goods (IMDG) Transportation Information
Primary Class
Subsidiary Class (if
applicable)

Class 3: Flammable liquid.

Proper shipping name
Hazard identification
number
Packing group

PETROLEUM DISTILLATES, N.O.S.
UN 1268

Marine pollutant
Special Provisions

Not a pollutant.

-

III

In containers of 5 L (5Kg) capacity or less this product is
classified as a "Consumer Commodity" under IMDG regulations.

United States Department of Transportation (DOT) Information
Primary Class

Class 3: Flammable liquid.

Subsidiary class (if
applicable)

-

Proper shipping name

PETROLEUM DISTILLATES, N.O.S.

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PaintMineral
ThinnerSpirit
Solvent

Hazard identification
number
Packing group

UN 1268

Special Provisions

In containers of 454L or less this product is not classified as a
Gangerous Good according to exception 173.150 f(1-2)

International Air
Transport Association
(IATA)

For air shipment classification and associated regulations, please refer to the latest edition of
IATA Dangerous Goods Regulations.

III

Section 15. Other Regulatory Information and Pictograms
WHMIS Classification
(Canada)
Canada Domestic
Substances List (DSL)
Status

WHMIS CLASS B-3: Combustible liquid with a flash point between
37.8°C (100°F) and 93.3°C (200°F).

HCS Classification
(U.S.A.)

Combustible liquid

U.S.A. Regulatory Lists

This product and/ or all of its components are on the TSCA inventory list.

Hazardous Material
Information System
(U.S.A.)

This product and/ or all of its components are on the DSL.

Health
Flammability
Reactivity
Personal protection

1
2
0
G

National Fire
Protection
Association
(U.S.A.)

Flammability
Health

2

1 0

Reactivity

Specific hazard

Section 16. Other information
Validated and verified by Compliance and Technical Information Manager on 11/8/2007 ph.# Printed 11/8/2007.
905-791-1788.

Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for
the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain
hazards are described herein, we cannot guarantee that these are the only hazards that exist.

MSDS are available at www.recochem.com

Common Name: CRYSTAL SIMPLE GREEN
Manufacturer: SUNSHINE MAKERS
MSDS Revision Date: 8/1/2006

Grainger Item Number(s): 3UP37, 3UP38, 3UP39, 3UP40
Manufacturer Model Number(s):

MSDS Table of Contents
Click the desired link below to jump directly to that section in the MSDS.
I. PRODUCT & COMPANY INFORMATION
II. INGREDIENT INFORMATION
III. HAZARDS IDENTIFICATION
IV. FIRST AID MEASURES
V. FIRE FIGHTING MEASURES
VI. ACCIDENTAL RELEASE MEASURES
VII. HANDLING, STORAGE & TRANSPORT INFORMATION
VIII. EXPOSURE CONTROLS
IX. PERSONAL PROTECTION
X. PHYSICAL AND CHEMICAL PROPERTIES
XI. STABILITY AND REACTIVITY INFORMATION
XII. TOXICOLOGICAL INFORMATION
XIII. BIODEGRADABILITY AND ENVIRONMENTAL TOXICITY INFORMATION
XIV. DISPOSAL CONSIDERATIONS
XV. OTHER INFORMATION

MATERIAL SAFETY DATA SHEET: CRYSTAL SIMPLE GREEN(R*)
ALSO FOR: SIMPLE GREEN(R*) SAFETY TOWELS
VERSION NO.: 4013
ISSUE DATE: AUGUST 2006

I. PRODUCT & COMPANY INFORMATION

PRODUCT NAME: CRYSTAL SIMPLE GREEN(R*)
OTHER NAMES:
CRYSTAL SIMPLE GREEN(R*) - SPECIALIZED CLEANER / DEGREASER
SIMPLE GREEN(R*) SAFETY TOWELS (FLUID ONLY)
COMPANY NAME:
SUNSHINE MAKERS, INC.
15922 PACIFIC COAST HIGHWAY
HUNTINGTON HARBOUR, CA 92649
USA
TELEPHONE:
800-228-0709

562-795-6000
FAX: 562-592-3034
FOR 24-HOUR EMERGENCY, CALL CHEM-TEL, INC.: 800-255-3924
WEBSITE: WWW.SIMPLEGREEN.COM
USE OF PRODUCT:
A SPECIALIZED CLEANER AND DEGREASER FOR USE IN THE INDUSTRIAL AND
INSTITUTIONAL WORKPLACE. (SIMPLE GREEN(R*) SAFETY TOWELS CONTAIN DILUTED
CRYSTAL SIMPLE GREEN(R*).)

II. INGREDIENT INFORMATION

THE ONLY INGREDIENT OF CRYSTAL SIMPLE GREEN(R*) WITH ESTABLISHED EXPOSURE
LIMITS IS UNDILUTED 2-BUTOXYETHANOL (<6%) (BUTYL) CELLOSOLVE; CAS NO.
111-76-2: THE ACGIH TLV-TWA IS: 20 PPM (97 MG/M3.)
THE QUANTITY OF 2-BUTOXYETHANOL IN SIMPLE GREEN SAFETY TOWELS IS <1%.
BASED UPON CHEMICAL ANALYSIS, CRYSTAL SIMPLE GREEN(R*) CONTAINS NO KNOWN EPA
PRIORITY POLLUTANTS, HEAVY METALS, OR CHEMICALS LISTED UNDER RCRA, CERCLA,
OR CWA. ANALYSIS BY TCLP (TOXICITY CHARACTERISTIC LEACHING PROCEDURE)
ACCORDING TO RCRA REVEALED NO TOXIC ORGANIC OR INORGANIC CONSTITUENTS.
ALL COMPONENTS OF CRYSTAL SIMPLE GREEN(R*) ARE LISTED ON THE TSCA CHEMICAL
SUBSTANCE INVENTORY.

III. HAZARDS IDENTIFICATION

UN NUMBER: NOT REQUIRED
DANGEROUS GOODS CLASS: NONHAZARDOUS
NJ TRADE SECRET REGISTRATION NUMBERS:
80100235-5000P
80100235-5001P
80100235-5002P
80100235-5003P
80100235-5004P
80100235-5005P
80100235-5006P
80100235-5007P
80100235-5008P
80100235-5009P
HAZARD RATING (NFPA/HMIS):
HEALTH
1*
REACTIVITY 0
FIRE
0
SPECIAL
0
NFPA:
1
0
0
0
RATING SCALE:
0 = MINIMAL
1 = SLIGHT

2 = MODERATE
3 = SERIOUS
4 = SEVERE
*MILD EYE IRRITANT, NON-MUTAGENIC AND NON-CARCINOGENIC. NONE OF THE
INGREDIENTS IN CRYSTAL SIMPLE GREEN(R*) ARE REGULATED OR LISTED AS CANCER
AGENTS BY FEDERAL OSHA, NTP, OR IARC.

IV. FIRST AID MEASURES

SYMPTOMS OF OVEREXPOSURE AND FIRST AID TREATMENT:
EYE CONTACT:
REDDENING MAY DEVELOP. IMMEDIATELY RINSE THE EYE WITH LARGE QUANTITIES OF
COOL WATER; CONTINUE 10-15 MINUTES OR UNTIL THE MATERIAL HAS BEEN REMOVED;
BE SURE TO REMOVE CONTACT LENSES, IF PRESENT, AND TO LIFT UPPER AND LOWER
LIDS DURING RINSING. GET MEDICAL ATTENTION IF IRRITATION PERSISTS.
SKIN CONTACT:
MINIMAL EFFECTS, IF ANY; RINSE SKIN WITH WATER, RINSE SHOES AND LAUNDER
CLOTHING BEFORE REUSE. REVERSIBLE REDDENING MAY OCCUR IN SOME
DERMAL-SENSITIVE USERS; THOROUGHLY RINSE AREA AND GET MEDICAL ATTENTION IF
REACTION PERSISTS.
SWALLOWING:
ESSENTIALLY NON-TOXIC. GIVE SEVERAL GLASSES OF WATER TO DILUTE; DO NOT
INDUCE VOMITING. IF STOMACH UPSET OCCURS, CONSULT PHYSICIAN.
INHALATION:
NON-TOXIC. EXPOSURES TO CONCENTRATE-MIST MAY CAUSE MILD IRRITATION OF NASAL
PASSAGES OR THROAT; REMOVE TO FRESH AIR. GET MEDICAL ATTENTION IF IRRITATION
PERSISTS.

V. FIRE FIGHTING MEASURES

CRYSTAL SIMPLE GREEN(R*) IS STABLE, NOT FLAMMABLE, AND WILL NOT BURN.
FLASH POINT/AUTO-IGNITION: NOT FLAMMABLE.
FLAMMABILITY LIMITS: NOT FLAMMABLE.
EXTINGUISHING MEDIA:
NOT FLAMMABLE/NONEXPLOSIVE. NO SPECIAL PROCEDURES REQUIRED.
SPECIAL FIRE FIGHTING PROCEDURES: NONE REQUIRED.

VI. ACCIDENTAL RELEASE MEASURES

RECOVER USABLE MATERIAL BY CONVENIENT METHOD; RESIDUAL MAY BE REMOVED BY
WIPE OR WET MOP. IF NECESSARY, UNRECOVERABLE MATERIAL MAY BE WASHED TO DRAIN
WITH LARGE QUANTITIES OF WATER.

VII. HANDLING, STORAGE & TRANSPORT INFORMATION

NO SPECIAL PRECAUTIONS ARE REQUIRED. THIS PRODUCT IS NON-HAZARDOUS FOR
STORAGE AND TRANSPORT ACCORDING TO THE U.S. DEPARTMENT OF TRANSPORTATION
REGULATIONS. CRYSTAL SIMPLE GREEN(R*) REQUIRES NO SPECIAL LABELING OR

PLACARDING TO MEET U.S. DEPARTMENT OF TRANSPORTATION REQUIREMENTS.
UN NUMBER: NOT REQUIRED
DANGEROUS GOODS CLASS: NONHAZARDOUS

VIII. EXPOSURE CONTROLS

EXPOSURE LIMITS:
THE CRYSTAL SIMPLE GREEN(R*) FORMULATION PRESENTS NO HEALTH HAZARDS TO THE
USER WHEN USED ACCORDING TO LABEL DIRECTIONS FOR ITS INTENDED PURPOSES. MILD
SKIN AND EYE IRRITATION IS POSSIBLE (PLEASE SEE EYE CONTACT AND SKIN CONTACT
IN SECTION IV.).
VENTILATION:
NO SPECIAL VENTILATION IS REQUIRED DURING USE. LARGE-SCALE USES INDOORS
SHOULD PROVIDE AN INCREASED RATE OF AIR EXCHANGE.
HUMAN HEALTH EFFECTS OR RISKS FROM EXPOSURE:
ADVERSE EFFECTS ON HUMAN HEALTH ARE NOT EXPECTED FROM CRYSTAL SIMPLE
GREEN(R*), BASED UPON TWENTY YEARS OF USE OF SIMPLE GREEN WITHOUT REPORTED
ADVERSE HEALTH INCIDENCE IN DIVERSE POPULATION GROUPS, INCLUDING EXTENSIVE
USE BY INMATES OF U.S. FEDERAL PRISONS IN CLEANING OPERATIONS.
CRYSTAL SIMPLE GREEN(R*) IS A MILD EYE IRRITANT; MUCOUS MEMBRANES MAY BECOME
IRRITATED BY CONCENTRATE-MIST.
CRYSTAL SIMPLE GREEN(R*) IS NOT LIKELY TO IRRITATE THE SKIN IN THE MAJORITY
OF USERS. REPEATED DAILY APPLICATION TO THE SKIN WITHOUT RINSING, OR
CONTINUOUS CONTACT OF CRYSTAL SIMPLE GREEN(R*) ON THE SKIN MAY LEAD TO
TEMPORARY, BUT REVERSIBLE, IRRITATION.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
NO AGGRAVATION OF EXISTING MEDICAL CONDITIONS IS EXPECTED; DERMAL-SENSITIVE
USERS MAY REACT TO DERMAL CONTACT BY CRYSTAL SIMPLE GREEN(R*).

IX. PERSONAL PROTECTION

PRECAUTIONARY MEASURES: NO SPECIAL REQUIREMENTS UNDER NORMAL USE CONDITIONS.
EYE PROTECTION:
CAUTION, INCLUDING REASONABLE EYE PROTECTION, SHOULD ALWAYS BE USED TO AVOID
EYE CONTACT WHERE SPLASHING MAY OCCUR.
SKIN PROTECTION:
NO SPECIAL PRECAUTIONS REQUIRED; RINSE COMPLETELY FROM SKIN AFTER CONTACT.
RESPIRATORY PROTECTION:
NO SPECIAL PRECAUTIONS REQUIRED EXCEPT DURING LARGE-SCALE SPRAY APPLICATIONS
WHERE SPRAY MIST LEVELS ARE HIGH.
WORK AND HYGIENIC PRACTICES:
WASH OR RINSE HANDS BEFORE TOUCHING EYES OR CONTACT LENSES. FOLLOW STANDARD
HYGIENIC PRACTICES FOR HANDLING CLEANING AGENTS.

X. PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE/ODOR: CLEAR LIQUID
SPECIFIC GRAVITY: 1.020

pH OF CONCENTRATE: 9.35
EVAPORATION: >1 (BUTYL ACETATE = 1)
BOILING POINT: 100.6 DEG. C (212 DEG. F )
FREEZING POINT: -9 DEG. C (16 DEG. F)
IF PRODUCT FREEZES, IT WILL RECONSTITUTE WITHOUT LOSS OF EFFICACY WHEN
BROUGHT BACK TO ROOM TEMPERATURE AND AGITATED.
VAPOR PRESSURE:
18 MMHg @ 20 DEG. C
23.5 MMHg @ 26 DEG. C
VAPOR DENSITY: 1.3 (AIR = 1)
DENSITY: 8.5 LBS./GALLON
VOC COMPOSITE PARTIAL PRESSURE: 0 MMHg @ 20 DEG. C
VOLATILE ORGANIC COMPOUNDS (VOCS):
0 G/L PER ASTM METHOD 3960-90. PER EPA METHOD 24, VOCS ARE 5.9% AND PRODUCT
MUST BE DILUTED AT LEAST 1 PART OF WATER TO 1 PART SIMPLE GREEN(R*) IN ORDER
TO MEET CARB 2005 VOC REGULATIONS - OR 1 PART SIMPLE GREEN TO 3 PARTS WATER
TO MEET SCAQMD RULE 1171 & RULE 1122 AND BAAQMD REGULATION 8-16 VOC
REQUIREMENTS FOR SOLVENT CLEANING OPERATIONS.
SAFETY TOWEL VOCS: PER EPA METHOD 24, VOCS ARE 0.5%.
SAFETY TOWEL pH: 8.1 - 8.8
WATER SOLUBILITY: CRYSTAL SIMPLE GREEN(R*) IS COMPLETELY SOLUBLE IN WATER.
DETECTION:
CRYSTAL SIMPLE GREEN(R*) AND SIMPLE GREEN(R*) SAFETY TOWELS HAVE A
CHARACTERISTIC ODOR THAT IS NOT INDICATIVE OF ANY HAZARDOUS SITUATION.

XI. STABILITY AND REACTIVITY INFORMATION

NONREACTIVE. CRYSTAL SIMPLE GREEN(R*) IS STABLE, EVEN UNDER FIRE CONDITIONS,
AND WILL NOT REACT WITH WATER OR OXIDIZERS. HAZARDOUS POLYMERIZATION WILL
NOT OCCUR.

XII. TOXICOLOGICAL INFORMATION

THE INFORMATION AND CONCLUSIONS CITED IN THIS SECTION ARE BASED ON DATA AND
TESTING OF SIMPLE GREEN(R*). THE DATA ARE DIRECTLY APPLICABLE TO CRYSTAL
SIMPLE GREEN(R*) BECAUSE BOTH FORMULATIONS ARE VIRTUALLY IDENTICAL, EXCEPT
FOR FRAGRANCE AND COLOR.
NONHUMAN TOXICITY:
ACUTE MORTALITY STUDIES:
ORAL LD50 (RAT): >5.0 G/KG BODY WEIGHT
DERMAL LD50 (RABBIT): >2.0 G/KG BODY WEIGHT
DERMAL IRRITATION:
ONLY MILD, BUT REVERSIBLE, IRRITATION WAS FOUND IN A STANDARD 72-HR TEST ON
RABBITS. A VALUE OF 0.2 (NON-IRRITATING) WAS FOUND ON A SCALE OF 8.
EYE IRRITATION:

WITH OR WITHOUT RINSING WITH WATER, THE IRRITATION SCORES IN RABBITS AT 24
HOURS DID NOT EXCEED 15 (MILD IRRITANT) ON A SCALE OF 110.
SUBCHRONIC DERMAL EFFECTS:
NO ADVERSE EFFECTS, EXCEPT REVERSIBLE DERMAL IRRITATION, WERE FOUND IN
RABBITS EXPOSED TO SIMPLE GREEN(R*) (UP TO 2.0 G/KG/DAY FOR 13 WEEKS)
APPLIED TO THE SKIN OF 25 MALES AND 25 FEMALES. ONLY FEMALE BODY WEIGHT GAIN
WAS AFFECTED. DETAILED MICROSCOPIC EXAMINATION OF ALL MAJOR TISSUES SHOWED
NO ADVERSE CHANGES.
FERTILITY ASSESSMENT BY CONTINUOUS BREEDING:
THE SIMPLE GREEN(R*) FORMULATION HAD NO ADVERSE EFFECT ON FERTILITY AND
REPRODUCTION IN CD-1 MICE WITH CONTINUOUS ADMINISTRATION FOR 18 WEEKS, AND
HAD NO ADVERSE EFFECT ON THE REPRODUCTIVE PERFORMANCE OF THEIR OFFSPRING.

XIII. BIODEGRADABILITY AND ENVIRONMENTAL TOXICITY INFORMATION

BIODEGRADABILITY:
LIKE SIMPLE GREEN(R*), CRYSTAL SIMPLE GREEN(R*) IS READILY DECOMPOSED BY
NATURALLY OCCURRING MICROORGANISMS. THE BIOLOGICAL OXYGEN DEMAND (BOD), AS A
PERCENTAGE OF THE CHEMICAL OXYGEN DEMAND (COD), AFTER 4, 7, AND 11 DAYS WAS
56%, 60%, AND 70%, RESPECTIVELY. PER OECD CLOSED BOTTLE TEST, CRYSTAL SIMPLE
GREEN(R*) MEETS OECD AND EPA RECOMMENDATIONS FOR READY BIODEGRADABILITY.
IN A STANDARD BIODEGRADATION TEST WITH SOILS FROM THREE DIFFERENT COUNTRIES,
BUTYL CELLOSOLVE REACHED 50% DEGRADATION IN 6 TO 23 DAYS, DEPENDING UPON
SOIL TYPE, AND EXCEEDED THE RATE OF DEGRADATION FOR GLUCOSE, WHICH WAS USED
AS A CONTROL FOR COMPARISON.
ENVIRONMENTAL TOXICITY INFORMATION:
CRYSTAL SIMPLE GREEN(R*) IS CONSIDERED PRACTICALLY NON-TOXIC PER EPA'S
AQUATIC TOXICITY SCALE.

XIV. DISPOSAL CONSIDERATIONS

CRYSTAL SIMPLE GREEN(R*) IS FULLY WATER SOLUBLE AND BIODEGRADABLE AND WILL
NOT HARM SEWAGE-TREATMENT MICROORGANISMS IF DISPOSAL BY SEWER OR DRAIN IS
NECESSARY. DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE, AND
FEDERAL LAWS.

XV. OTHER INFORMATION

CONTAINERS:
CRYSTAL SIMPLE GREEN(R*) RESIDUES CAN BE COMPLETELY REMOVED BY RINSING WITH
WATER; THE CONTAINER MAY BE RECYCLED OR APPLIED TO OTHER USES.
CONTACT POINT:
SUNSHINE MAKERS, INC., RESEARCH AND DEVELOPMENT DIVISION: 562-795-6000.
NATIONAL STOCK NUMBERS:
PART#

NSN

SIZE

19024

7930-01-418-1151

24 OZ. SPRAY (12/CS)

19128

7930-01-418-1152

1 GAL. (6/CS)

19005

7930-01-418-1153

5 GAL.

19055

7930-01-418-1155

55 GAL.

SIMPLE GREEN SAFETY TOWEL PART NUMBERS:
PART #

SIZE

13353

5-COUNT POUCH (50/CS)

13351

75-COUNT CANISTER (6/CS)

NOTICE:
ALL INFORMATION APPEARING HEREIN IS BASED UPON DATA OBTAINED BY THE
MANUFACTURER AND RECOGNIZED TECHNICAL SOURCES. JUDGMENTS AS TO THE
SUITABILITY OF INFORMATION HEREIN FOR PURCHASER'S PURPOSES ARE NECESSARILY
PURCHASER'S RESPONSIBILITY. THEREFORE, ALTHOUGH REASONABLE CARE HAS BEEN
TAKEN IN THE PREPARATION OF THIS INFORMATION, SUNSHINE MAKERS, INC. OR ITS
DISTRIBUTORS EXTENDS NO WARRANTIES, MAKES NO REPRESENTATIONS AND ASSUMES NO
RESPONSIBILITY AS TO THE SUITABILITY OF SUCH INFORMATION FOR APPLICATION TO
PURCHASER'S INTENDED PURPOSES OR FOR CONSEQUENCES OF ITS USE.

Material Safety Data Sheet:
Version No. 10013c

Section 1:

Simple Green® All-Purpose Cleaner
Simple Green® Scrubbing Pad
Date of Issue: July 2007

PRODUCT & COMPANY IDENTIFICATION

Product Name:
Additional Name:

Simple Green® All-Purpose Cleaner
Simple Green® Scrubbing Pad
Simple Green® Concentrated Cleaner/Degreaser/Deodorizer

Manufacturer’s Product Code Numbers:
Company:
Telephone:
Emergency Phone:
Use of Product:

Section 2:

ANSI-Z400.1-2003 Format

*Please refer to page 4

Sunshine Makers, Inc.
15922 Pacific Coast Highway
Huntington Harbour, CA 92649 USA
800-228-0709 ● 562-795-6000
Fax: 562-592-3830
Chem-Tel 24-Hour Emergency Service: 800-255-3924
An all purpose cleaner and degreaser used diluted in water for direct, spray and dip tank procedures.
Scrubbing pad is used with water for manual scrubbing applications.

HAZARDS IDENTIFICATION

Emergency Overview: CAUTION. Mild eye irritant.
Simple Green@ is a dark green liquid with a sassafras odor. Scrubbing Pad is a green fibrous rectangle.
0
0

1
0

HMIS Rating:
Health = 1 = slight
Fire = 0
Reactivity, and Special = 0 = minimal

Eye Contact:

Mild Eye Irritant.

Skin Contact:

No adverse effects expected under typical use conditions. Prolonged exposure may cause dryness. Under
this condition, use of gloves or skin moisturizer after washing may be indicated.

Ingestion:

May cause stomach or intestinal upset if swallowed (due to detersive properties.)

Inhalation:

No adverse effects expected under typical use conditions. Adequate ventilation should be present when
using Simple Green® over a prolonged period of time. Open windows or ventilate via fan or other airmoving equipment if necessary.

Carcinogens:

No ingredients are listed by OSHA, IARC, or NTP as known or suspected carcinogens.

Medical Conditions:

Not Required

UN Number:

Section 3:

No medical conditions are known to be aggravated by exposure to Simple Green®. Dermalsensitive users may experience mild but reversible reactions.
Dangerous Goods Class:

Nonhazardous

COMPOSITION/INFORMATION ON INGREDIENTS

The only ingredient of Simple Green® with established exposure limits is undiluted 2-butoxyethanol (<6%) (Butyl
Cellosolve; CAS No. 111-76-2): the ACGIH TLV-TWA is 20 ppm (97 mg/m3). Based upon chemical analysis, Simple
Green® contains no known EPA priority pollutants, heavy metals or chemicals listed under RCRA, CERCLA, or CWA.
Analysis by TCLP (Toxicity Characteristic Leaching Procedure) according to RCRA revealed no toxic organic or
inorganic constituents.
All components of Simple Green® are listed on the TSCA Chemical Substance Inventory.
80100235-5000p
80100235-5001p

80100235-5002p
80100235-5003p

NJ Trade Secret Numbers
80100235-5004p
80100235-5006p
80100235-5005p
80100235-5007p

Material Safety Data Sheet: SIMPLE GREEN® ALL-PURPOSE CLEANER & SCRUBBING PAD

80100235-5008p
80100235-5009p
Pg 1 of 4

Material Safety Data Sheet:
Version No. 10013c

Simple Green® All-Purpose Cleaner
Simple Green® Scrubbing Pad
Date of Issue: July 2007

ANSI-Z400.1-2003 Format

Section 4:

FIRST AID MEASURES

Eye Contact:

Reddening may develop. Immediately rinse the eye with large quantities of cool water; continue 10-15
minutes or until the material has been removed; be sure to remove contact lenses, if present, and to lift upper
and lower lids during rinsing. Get medical attention if irritation persists.

Skin Contact:

Minimal effects, if any; rinse skin with water, rinse shoes and launder clothing before reuse. Reversible
reddening may occur in some dermal-sensitive users; thoroughly rinse area and get medical attention if
reaction persists.

Swallowing;

Essentially non-toxic. Give several glasses of water to dilute; do not induce vomiting. If stomach upset
occurs, consult physician.

Inhalation:

Non-toxic. Exposure to concentrate may cause mild irritation of nasal passages or throat; remove to fresh
air. Get medical attention if irritation persists.

Section 5:

FIRE FIGHTING MEASURES

Simple Green® is stable, not flammable, and will not burn. No special procedures required.
Flash Point/Auto-Ignition: Not flammable.
Flammability Limits: Not flammable.

Section 6:

Extinguishing Media: Not flammable/nonexplosive.
Special Fire Fighting Procedures: None required.

ACCIDENTAL RELEASE MEASURES

Personal Precautions: Avoid contact with eyes. Do not rub eyes with hands during cleanup. No special precautions for
dermal contact are needed. Wash hands thoroughly after cleaning up spill or leak.
Method for cleaning up: Recover usable material by convenient method, residual may be removed by wipe or wet mop.
If necessary, unrecoverable material may be washed to drain with large quantities of water.

Section 7:

HANDLING AND STORAGE

No Special precautions are required. This product is non-hazardous for storage and transport according to the U.S.
Department of Transportation Regulations. Simple Green® requires no special labeling or placarding to meet U.S.
Department of Transportation requirements.
Not Required

UN Number:

Section 8:

Dangerous Goods Class:

Nonhazardous

EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Limits:

The Simple Green® formulation presents no health hazards to the user when used according to label
directions for its intended purposes. Mild skin and eye irritation is possible (please see Eye contact
and Skin contact in section IV.) No special precautionary measures required under normal use
conditions.

Ventilation:

No special ventilation, precautions or respiratory protection is required during normal use. Largescale use indoors should provide an increased rate of air exchange.

Human Health
Effects or Risks
From Exposure:

Adverse effects on human health are not expected from Simple Green®, based on 20 years of use of
Simple Green® without reported adverse health incidence in diverse population groups, including
extensive use by inmates of U.S. Federal prisons in cleaning operations.

Eye protection:

Simple Green® is a mild eye irritant; mucous membranes may become irritated by concentrate. Eye
protection not generally required. Wash hands after using wipes.

Skin protection:

Simple Green® is not likely to irritate the skin in the majority of users. Repeated daily application to
the skin without rinsing, or continuous contact on the skin may lead to temporary, but reversible,
irritation. Rinse completely from skin after contact.

Material Safety Data Sheet: SIMPLE GREEN® ALL-PURPOSE CLEANER & SCRUBBING PAD

Pg 2 of 4

Material Safety Data Sheet:

Simple Green® All-Purpose Cleaner
Simple Green® Scrubbing Pad
Date of Issue: July 2007

Version No. 10013c

Section 8:

EXPOSURE CONTROLS/PERSONAL PROTECTION – continued –

General hygiene
conditions:

Section 9:

ANSI-Z400.1-2003 Format

There are no known hazards associated with this material when used as recommended.
The following general hygiene considerations are recognized as common good industrial hygiene
practices:
- Avoid breathing vapor or mist.
- Avoid contact with eyes.
- Wash thoroughly after handling and before eating, drinking, or smoking.

PHYSICAL AND CHEMICAL PROPERTIES

Appearance & Odor: Cleaner is a dark green liquid, pad is a fibrous green matrix; both exhibit a sassafras odor.
Specific Gravity:

1.020

Vapor Pressure:

18 mm Hg @ 20oC; 23.5 mmHg @ 26oC

Evaporation:

>1 (butyl acetate = 1)

Vapor Density:

1.3 (air = 1)

Water Solubility:

100%

Density:

8.5 lbs/gallon

pH:

9.35;

Boiling Point:
Ash Content:

o

o

100.6 C (212 F)

Safety Towel pH is 8.1 - 8.8

o

At 600 F: 1.86% by weight

Nutrient Content:
Phosphorus: 0.3% by formula
Approx -9 C (16 F)
Freezing Point:
Nitrogen <1.0% by weight (fusion and qualitative test for ammonia)
If product freezes, it will reconstitute without loss of efficacy
Sulfur: 0.6% by weight (barium chloride precipitation method)
when brought back to room temperature and agitated.
o
VOC Composite Partial Pressure: 0.006 mmHg @ 20 C
o

o

Volatile Organic Compounds (VOCs): Per EPA Method 24, VOC’s are 5.9%. Cleaner must be diluted at least 1 part
Simple Green to 2 parts water to meet CARB, and 1 part Simple Green to 3 parts water to meet SCAQMD Rule 1171 &
Rule 1122 and BAAQMD Regulation 8-16 VOC requirements for solvent cleaning operations. Towel VOCs are 1.2%.

Section 10: STABILITY AND REACTIVITY
Stability:
Materials to Avoid:
Hazardous Decomposition Products:

Stable
None known
None expected

Section 11: TOXICOLOGICAL INFORMATION
Nonhuman Toxicity (Data for Simple Green®)
Acute Toxicity:
Oral LD50 (rat): >5.0 g/kg body weight

Dermal LD50 (rabbit)

>2.0 g/kg body weight

Eye Irritation:

With or without rinsing with water, the irritation scores in rabbits at 24 hours did not exceed 15
(mild irritant) on a scale of 0-110.

Dermal Irritation:

Only mild, but reversible, irritation was found in a standard 72 hour test on rabbits. A value of 0.2
(non-irritating) was found on a scale of 0-8.

Subchronic Dermal
effects:

No adverse effects, except reversible dermal irritation, were found in rabbits exposed to Simple
Green (up to 2.0 g/kg/day for 13 weeks) applied to the skin of 25 males and 25 females. Only
female body weight gain was affected.

Fertility Assessment
by Continuous
Breeding:

The Simple Green® formulation had no adverse effect on fertility and reproduction in Cd-1 mice
with continuous administration for 18 weeks, and had no adverse effect on the reproductive
performance of their offspring.

Material Safety Data Sheet: SIMPLE GREEN® ALL-PURPOSE CLEANER & SCRUBBING PAD

Pg 3 of 4

Material Safety Data Sheet:
Version No. 10013c

Simple Green® All-Purpose Cleaner
Simple Green® Scrubbing Pad
Date of Issue: July 2007

ANSI-Z400.1-2003 Format

Section 12: ECOLOGICAL INFORMATION
Biodegradability: Simple Green® is readily decomposed by naturally occurring microorganisms. The biological oxygen
demand (BOD), as a percentage of the chemical oxygen demand (COD), after 4, 7, and 11 days was 56%, 60% and 70%,
respectively. Per OECD Closed Bottle Test, Simple Green® meets OECD and EPA recommendations for ready
biodegradability.
In a standard biodegradation test with soils from three different countries, Butyl Cellosolve reached 50% degradation in 6
to 23 days, depending upon soil type, and exceeded the rate of degradation for glucose which was used as a control for
comparison.
Environmental Toxicity Information: Simple Green® is considered practically non-toxic per EPA’s Aquatic toxicity
scale.

Section 13: DISPOSAL CONSIDERATIONS
Dispose of in accordance with all applicable local, state and federal laws. Dispose of used or unused product, and empty
containers in accordance with the local, State, Provincial, and Federal regulations for your location. Never dispose of used
degreasing rinsates into lakes, streams, and open bodies of water or storm drains.

Section 14: TRANSPORT INFORMATION
This product is non-hazardous for transport according to the U.S. Department of Transportation Services
UN Number: Not required
Dangerous Goods Class: Nonhazardous

Section 15: REGULATORY INFORMATION
All components are listed on:
*Reportable components:
RCRA Status:
TSCA TRI Reporting:

EINECS and TSCA Inventory
None.
No components listed under:
Not a hazardous waste.
CERCLA Status:
Not required / Not listed
CA PROP. 65 Status:

Clean Air Act Section 112
No components listed
No components listed

Section 16: OTHER INFORMATION
Questions about the information found on this MSDS should be directed to:
SUNSHINE MAKERS, INC. – TECHNICAL DEPARTMENT
15922 Pacific Coast Hwy. Huntington Harbour, CA 92649
Phone: 800/228-0709 [8am-5pm Pacific time, Mon-Fri]

Fax: 562/592-3830

National Stock Numbers & Industrial Numbers:
Simple Green

Scrubbing Pad

Part Number
13012
13005
13006
13016
13008
Part Number
10224

NSN
7930-01-342-5315
7930-01-306-8369
7930-01-342-5316
7930-01-342-5317
7930-01-342-4145
NSN
7930-01-346-9148

Email: infoweb@simplegreen.com
Retail Numbers:

Size
24 oz spray (12/case)
1 Gallon (6/case)
5 Gallon
15 Gallon
55 Gallon
Size
Each (24/case)

Part Number
13002
13005
13013
13014
13033

Size
16 oz Trigger (12/case)
1 Gallon (6/case)
24 oz Trigger (12/case)
67 oz / 2 L (6/case)
32 oz Trigger (12/case)

* part number is for both industrial and retail

**International Part Numbers May Differ.

DISCLAIMER: The information provided with this MSDS is furnished in good faith and without warranty of any kind. Personnel
handling this material must make independent determinations of the suitability and completeness of information from all sources to
assure proper use and disposal of this material and the safety and health of employees and customers. Sunshine Makers, Inc. assumes
no additional liability or responsibility resulting from the use of, or reliance on this information.

Material Safety Data Sheet: SIMPLE GREEN® ALL-PURPOSE CLEANER & SCRUBBING PAD

Pg 4 of 4

Material Safety Data Sheet:
Version No. 10013c

Section 1:

Simple Green® All-Purpose Cleaner
Simple Green® Scrubbing Pad
Date of Issue: July 2007

PRODUCT & COMPANY IDENTIFICATION

Product Name:
Additional Name:

Simple Green® All-Purpose Cleaner
Simple Green® Scrubbing Pad
Simple Green® Concentrated Cleaner/Degreaser/Deodorizer

Manufacturer’s Product Code Numbers:
Company:
Telephone:
Emergency Phone:
Use of Product:

Section 2:

ANSI-Z400.1-2003 Format

*Please refer to page 4

Sunshine Makers, Inc.
15922 Pacific Coast Highway
Huntington Harbour, CA 92649 USA
800-228-0709 ● 562-795-6000
Fax: 562-592-3830
Chem-Tel 24-Hour Emergency Service: 800-255-3924
An all purpose cleaner and degreaser used diluted in water for direct, spray and dip tank procedures.
Scrubbing pad is used with water for manual scrubbing applications.

HAZARDS IDENTIFICATION

Emergency Overview: CAUTION. Mild eye irritant.
Simple Green@ is a dark green liquid with a sassafras odor. Scrubbing Pad is a green fibrous rectangle.
0
0

1
0

HMIS Rating:
Health = 1 = slight
Fire = 0
Reactivity, and Special = 0 = minimal

Eye Contact:

Mild Eye Irritant.

Skin Contact:

No adverse effects expected under typical use conditions. Prolonged exposure may cause dryness. Under
this condition, use of gloves or skin moisturizer after washing may be indicated.

Ingestion:

May cause stomach or intestinal upset if swallowed (due to detersive properties.)

Inhalation:

No adverse effects expected under typical use conditions. Adequate ventilation should be present when
using Simple Green® over a prolonged period of time. Open windows or ventilate via fan or other airmoving equipment if necessary.

Carcinogens:

No ingredients are listed by OSHA, IARC, or NTP as known or suspected carcinogens.

Medical Conditions:

Not Required

UN Number:

Section 3:

No medical conditions are known to be aggravated by exposure to Simple Green®. Dermalsensitive users may experience mild but reversible reactions.
Dangerous Goods Class:

Nonhazardous

COMPOSITION/INFORMATION ON INGREDIENTS

The only ingredient of Simple Green® with established exposure limits is undiluted 2-butoxyethanol (<6%) (Butyl
Cellosolve; CAS No. 111-76-2): the ACGIH TLV-TWA is 20 ppm (97 mg/m3). Based upon chemical analysis, Simple
Green® contains no known EPA priority pollutants, heavy metals or chemicals listed under RCRA, CERCLA, or CWA.
Analysis by TCLP (Toxicity Characteristic Leaching Procedure) according to RCRA revealed no toxic organic or
inorganic constituents.
All components of Simple Green® are listed on the TSCA Chemical Substance Inventory.
80100235-5000p
80100235-5001p

80100235-5002p
80100235-5003p

NJ Trade Secret Numbers
80100235-5004p
80100235-5006p
80100235-5005p
80100235-5007p

Material Safety Data Sheet: SIMPLE GREEN® ALL-PURPOSE CLEANER & SCRUBBING PAD

80100235-5008p
80100235-5009p
Pg 1 of 4

Material Safety Data Sheet:
Version No. 10013c

Simple Green® All-Purpose Cleaner
Simple Green® Scrubbing Pad
Date of Issue: July 2007

ANSI-Z400.1-2003 Format

Section 4:

FIRST AID MEASURES

Eye Contact:

Reddening may develop. Immediately rinse the eye with large quantities of cool water; continue 10-15
minutes or until the material has been removed; be sure to remove contact lenses, if present, and to lift upper
and lower lids during rinsing. Get medical attention if irritation persists.

Skin Contact:

Minimal effects, if any; rinse skin with water, rinse shoes and launder clothing before reuse. Reversible
reddening may occur in some dermal-sensitive users; thoroughly rinse area and get medical attention if
reaction persists.

Swallowing;

Essentially non-toxic. Give several glasses of water to dilute; do not induce vomiting. If stomach upset
occurs, consult physician.

Inhalation:

Non-toxic. Exposure to concentrate may cause mild irritation of nasal passages or throat; remove to fresh
air. Get medical attention if irritation persists.

Section 5:

FIRE FIGHTING MEASURES

Simple Green® is stable, not flammable, and will not burn. No special procedures required.
Flash Point/Auto-Ignition: Not flammable.
Flammability Limits: Not flammable.

Section 6:

Extinguishing Media: Not flammable/nonexplosive.
Special Fire Fighting Procedures: None required.

ACCIDENTAL RELEASE MEASURES

Personal Precautions: Avoid contact with eyes. Do not rub eyes with hands during cleanup. No special precautions for
dermal contact are needed. Wash hands thoroughly after cleaning up spill or leak.
Method for cleaning up: Recover usable material by convenient method, residual may be removed by wipe or wet mop.
If necessary, unrecoverable material may be washed to drain with large quantities of water.

Section 7:

HANDLING AND STORAGE

No Special precautions are required. This product is non-hazardous for storage and transport according to the U.S.
Department of Transportation Regulations. Simple Green® requires no special labeling or placarding to meet U.S.
Department of Transportation requirements.
Not Required

UN Number:

Section 8:

Dangerous Goods Class:

Nonhazardous

EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Limits:

The Simple Green® formulation presents no health hazards to the user when used according to label
directions for its intended purposes. Mild skin and eye irritation is possible (please see Eye contact
and Skin contact in section IV.) No special precautionary measures required under normal use
conditions.

Ventilation:

No special ventilation, precautions or respiratory protection is required during normal use. Largescale use indoors should provide an increased rate of air exchange.

Human Health
Effects or Risks
From Exposure:

Adverse effects on human health are not expected from Simple Green®, based on 20 years of use of
Simple Green® without reported adverse health incidence in diverse population groups, including
extensive use by inmates of U.S. Federal prisons in cleaning operations.

Eye protection:

Simple Green® is a mild eye irritant; mucous membranes may become irritated by concentrate. Eye
protection not generally required. Wash hands after using wipes.

Skin protection:

Simple Green® is not likely to irritate the skin in the majority of users. Repeated daily application to
the skin without rinsing, or continuous contact on the skin may lead to temporary, but reversible,
irritation. Rinse completely from skin after contact.

Material Safety Data Sheet: SIMPLE GREEN® ALL-PURPOSE CLEANER & SCRUBBING PAD

Pg 2 of 4

Material Safety Data Sheet:

Simple Green® All-Purpose Cleaner
Simple Green® Scrubbing Pad
Date of Issue: July 2007

Version No. 10013c

Section 8:

EXPOSURE CONTROLS/PERSONAL PROTECTION – continued –

General hygiene
conditions:

Section 9:

ANSI-Z400.1-2003 Format

There are no known hazards associated with this material when used as recommended.
The following general hygiene considerations are recognized as common good industrial hygiene
practices:
- Avoid breathing vapor or mist.
- Avoid contact with eyes.
- Wash thoroughly after handling and before eating, drinking, or smoking.

PHYSICAL AND CHEMICAL PROPERTIES

Appearance & Odor: Cleaner is a dark green liquid, pad is a fibrous green matrix; both exhibit a sassafras odor.
Specific Gravity:

1.020

Vapor Pressure:

18 mm Hg @ 20oC; 23.5 mmHg @ 26oC

Evaporation:

>1 (butyl acetate = 1)

Vapor Density:

1.3 (air = 1)

Water Solubility:

100%

Density:

8.5 lbs/gallon

pH:

9.35;

Boiling Point:
Ash Content:

o

o

100.6 C (212 F)

Safety Towel pH is 8.1 - 8.8

o

At 600 F: 1.86% by weight

Nutrient Content:
Phosphorus: 0.3% by formula
Approx -9 C (16 F)
Freezing Point:
Nitrogen <1.0% by weight (fusion and qualitative test for ammonia)
If product freezes, it will reconstitute without loss of efficacy
Sulfur: 0.6% by weight (barium chloride precipitation method)
when brought back to room temperature and agitated.
o
VOC Composite Partial Pressure: 0.006 mmHg @ 20 C
o

o

Volatile Organic Compounds (VOCs): Per EPA Method 24, VOC’s are 5.9%. Cleaner must be diluted at least 1 part
Simple Green to 2 parts water to meet CARB, and 1 part Simple Green to 3 parts water to meet SCAQMD Rule 1171 &
Rule 1122 and BAAQMD Regulation 8-16 VOC requirements for solvent cleaning operations. Towel VOCs are 1.2%.

Section 10: STABILITY AND REACTIVITY
Stability:
Materials to Avoid:
Hazardous Decomposition Products:

Stable
None known
None expected

Section 11: TOXICOLOGICAL INFORMATION
Nonhuman Toxicity (Data for Simple Green®)
Acute Toxicity:
Oral LD50 (rat): >5.0 g/kg body weight

Dermal LD50 (rabbit)

>2.0 g/kg body weight

Eye Irritation:

With or without rinsing with water, the irritation scores in rabbits at 24 hours did not exceed 15
(mild irritant) on a scale of 0-110.

Dermal Irritation:

Only mild, but reversible, irritation was found in a standard 72 hour test on rabbits. A value of 0.2
(non-irritating) was found on a scale of 0-8.

Subchronic Dermal
effects:

No adverse effects, except reversible dermal irritation, were found in rabbits exposed to Simple
Green (up to 2.0 g/kg/day for 13 weeks) applied to the skin of 25 males and 25 females. Only
female body weight gain was affected.

Fertility Assessment
by Continuous
Breeding:

The Simple Green® formulation had no adverse effect on fertility and reproduction in Cd-1 mice
with continuous administration for 18 weeks, and had no adverse effect on the reproductive
performance of their offspring.

Material Safety Data Sheet: SIMPLE GREEN® ALL-PURPOSE CLEANER & SCRUBBING PAD

Pg 3 of 4

Material Safety Data Sheet:
Version No. 10013c

Simple Green® All-Purpose Cleaner
Simple Green® Scrubbing Pad
Date of Issue: July 2007

ANSI-Z400.1-2003 Format

Section 12: ECOLOGICAL INFORMATION
Biodegradability: Simple Green® is readily decomposed by naturally occurring microorganisms. The biological oxygen
demand (BOD), as a percentage of the chemical oxygen demand (COD), after 4, 7, and 11 days was 56%, 60% and 70%,
respectively. Per OECD Closed Bottle Test, Simple Green® meets OECD and EPA recommendations for ready
biodegradability.
In a standard biodegradation test with soils from three different countries, Butyl Cellosolve reached 50% degradation in 6
to 23 days, depending upon soil type, and exceeded the rate of degradation for glucose which was used as a control for
comparison.
Environmental Toxicity Information: Simple Green® is considered practically non-toxic per EPA’s Aquatic toxicity
scale.

Section 13: DISPOSAL CONSIDERATIONS
Dispose of in accordance with all applicable local, state and federal laws. Dispose of used or unused product, and empty
containers in accordance with the local, State, Provincial, and Federal regulations for your location. Never dispose of used
degreasing rinsates into lakes, streams, and open bodies of water or storm drains.

Section 14: TRANSPORT INFORMATION
This product is non-hazardous for transport according to the U.S. Department of Transportation Services
UN Number: Not required
Dangerous Goods Class: Nonhazardous

Section 15: REGULATORY INFORMATION
All components are listed on:
*Reportable components:
RCRA Status:
TSCA TRI Reporting:

EINECS and TSCA Inventory
None.
No components listed under:
Not a hazardous waste.
CERCLA Status:
Not required / Not listed
CA PROP. 65 Status:

Clean Air Act Section 112
No components listed
No components listed

Section 16: OTHER INFORMATION
Questions about the information found on this MSDS should be directed to:
SUNSHINE MAKERS, INC. – TECHNICAL DEPARTMENT
15922 Pacific Coast Hwy. Huntington Harbour, CA 92649
Phone: 800/228-0709 [8am-5pm Pacific time, Mon-Fri]

Fax: 562/592-3830

National Stock Numbers & Industrial Numbers:
Simple Green

Scrubbing Pad

Part Number
13012
13005
13006
13016
13008
Part Number
10224

NSN
7930-01-342-5315
7930-01-306-8369
7930-01-342-5316
7930-01-342-5317
7930-01-342-4145
NSN
7930-01-346-9148

Email: infoweb@simplegreen.com
Retail Numbers:

Size
24 oz spray (12/case)
1 Gallon (6/case)
5 Gallon
15 Gallon
55 Gallon
Size
Each (24/case)

Part Number
13002
13005
13013
13014
13033

Size
16 oz Trigger (12/case)
1 Gallon (6/case)
24 oz Trigger (12/case)
67 oz / 2 L (6/case)
32 oz Trigger (12/case)

* part number is for both industrial and retail

**International Part Numbers May Differ.

DISCLAIMER: The information provided with this MSDS is furnished in good faith and without warranty of any kind. Personnel
handling this material must make independent determinations of the suitability and completeness of information from all sources to
assure proper use and disposal of this material and the safety and health of employees and customers. Sunshine Makers, Inc. assumes
no additional liability or responsibility resulting from the use of, or reliance on this information.

Material Safety Data Sheet: SIMPLE GREEN® ALL-PURPOSE CLEANER & SCRUBBING PAD

Pg 4 of 4

Page 1 of 4
Procter & Gamble
CPG TN 6
2 Procter & Gamble Plaza
Cincinnati, OH 45202

MATERIAL SAFETY DATA SHEET
Issue Date: 12/2005
Issue Date: 8/01

Supersedes: N/A

SECTION I - CHEMICAL PRODUCT
Identity: Granular Cleaner with Bleach
Brands: SPIC and SPAN Floor Cleaner with BLEACH (non-phosphate & phosphate)
Hazard Rating: 1
Health: 1
4=EXTREME
Flammability: 0
3=HIGH
Reactivity: 0
2= MODERATE
1=SLIGHT
Emergency Telephone Number: - 1-800-332-7787 or call Local Poison Control Center

SECTION II - COMPOSITION AND INGREDIENTS
Ingredients/Chemical Name: Anionic surfactants, water softeners (sodium carbonate, complex sodium phosphates
[phosphate version]), dry chlorine bleach, processing aids (sodium sulfate), metal
protection agents (sodium silicates).
This product is a mild eye irritant within the meaning of the OSHA Hazard Communication Standard
Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200 and/or WHMIS under the Hazardous Product Act.
Common
CAS No.
Recommended Limits
Composition LD50/LC50
Chemical Name
Name
Range
Sodium carbonate
Soda Ash 497-19-8
N/A
15-40% (OP)
LD50=1.86
10-25% (P)
g/kg
LC50=N/A
Sodium
2893-78-9
AGCY
OSHA
10-15%
LD50=735
Sodium
DCC
TLV
PEL
mg/kg rat
dichloroisocynanurate
10
mg/m3
15
mg/m3
dihydrate
C12.3 LAS 68081-81-2
15-30%
LD50=0.65Linear alkyl benzene
1.26 g/kg
sulfonate
N/A
LC50=N/A

SECTION III - HAZARDS IDENTIFICATION
Health Hazards & Symptoms (Acute and Chronic):
Ingestion:
May cause transient gastrointestinal irritation with nausea, vomiting and/or diarrhea.
Eye Contact:
May cause mild, transient irritation with stinging, tearing, itching,swelling and redness.
Inhalation:
Heavy or prolonged exposure to dust may cause transient respiratory tract irritation with
coughing, sore throat, wheezing or transitiory shortness of breath.

SPIC and SPAN Floor Cleaner with BLEACH (non-phosphate & phosphate) MSDS (Continued)
Page 2 of 4

SECTION IV - FIRST AID INFORMATION
Emergency and First Aid Procedures:
Ingestion:
Drink 1 or 2 large glasses of water. If large amounts are ingested, call a physician.
Eye Contact:
Flush with large amounts of water for at 10-15 minutes.
Skin:
Rinse skin thoroughly with water. Discontinue use.
Inhalation:
Leave dusty area.
Other: Product package has a caution statement: CAUTION:. May cause eye/skin irritation. Eye irritant. Avoid eye
contact. Do not mix with other cleaning products as irritating fumes may be released. May be irritating to skin.
For sensitive skin or prolonged use, wear gloves. If eye or skin contact occurs, flush with water for 15 minutes.
If irritation persists, seek medical attention. KEEP OUT OF REACH OF CHILDREN

SECTION V - FIRE FIGHTING INFORMATION
Flash Point (Method Used): N/A

Explosive Limits: LEL: N/A

UEL: N/A

Extinguishing Media: CO2 , water, or dry chemical
Special Fire Fighting Procedures: None known.
Unusual Fire Hazards : N/A

SECTION VI - ACCIDENTAL RELEASE MEASURES
Personal Precautions: None
Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL, PROVINCIAL AND LOCAL REGULATIONS. Solutions may be disposed of in sewer. Dry product may be landfilled if
permitted by local regulations. Discard empty container in trash.
Steps To Be Taken in Case Material is Released or Spilled: Dispose as dry scrap or flush small quantities down
acceptable sewer (contains biodegradable surfactants). Dispose of according to local regulations. Prevent heavy
exposure to dust with NIOSH approved dust mask.

SECTION VII - HANDLING AND STORAGE
Precautions To Be Taken in Handling and Storing: Store in a cool, dry place. Keep product dry to maintain freeflowing granules.
Other Precautions: None

SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION
Respiratory Protection (Specify Type): None required with normal use.
Ventilation
Local Exhaust: None required with normal use.
Special: None
Mechanical (General): Acceptable.
Other: None
Eye Protection: None required with normal use.
Manufacturing Setting: With dusty conditions or if a splash is likely, chemical goggles may be needed.
Protective Gloves: None required with normal use.
Manufacturing Setting: Protective gloves (rubber, neoprene) should be used for any prolonged direct contact.
Other Protective Equipment: None required with normal use.

2

SPIC and SPAN Floor Cleaner with BLEACH (non-phosphate & phosphate) MSDS (Continued)
Page 3 of 4
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point ° F: N/A

Specific Gravity (H2 O=1): N/A

Vapor Pressure (mm Hg): N/A

Percent Volatile by Volume (%): N/A

Vapor Density (Air=1): N/A

Evaporation Rate (nBuOAc=1): N/A

Odor Threshold: N/A

Freezing Point: N/A

Coefficient of Water/Oil Distribution: N/A

pH (1% solution): ~10.9

Scooped Density: 0.4/cc (bulk density)

Solubility in Water: Mostly

Appearance and Odor: White granule with green specks
and bland odor

Reserve Alkalinity: 4.0 max

SECTION X - STABILITY AND REACTIVITY
Possible Hazardous Reactions/Conditions: None known
Conditions to Avoid: None
Materials to Avoid: Products which contain ammonia or are acidic
Hazardous Decomposition Products: Chlorine gas
Other Recommendations: None
Stability:

Stable

Hazardous Polymerization:

Will not occur

SECTION XI - TOXICOLOGICAL INFORMATION
LD50 (rats oral): 2.9g/kg

SECTION XII - ECOLOGICAL INFORMATION
None

SECTION XIII - DISPOSAL CONSIDERATIONS
Waste Disposal Method: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH FEDERAL, PROVINCIAL
AND LOCAL REGULATIONS. Small quantities may be disposed of in sewer. Dry product may be landfilled. Discard
empty container in trash.

SECTION XIV - TRANSPORT INFORMATION
DOT Classification: The finished product is not DOT hazardous.

3

SPIC and SPAN Floor Cleaner with BLEACH (non-phosphate & phosphate) MSDS (Continued)
Page 4 of 4
SECTION XV - ADDITIONAL REGULATORY INFORMATION
All components are listed on the US TSCA Inventory. No components are affected by Significant New Use Rules
(SNURs) under TSCA §5.
No components of Spic and Span with Bleach are subject to California Proposition 65.
All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified with
Hazard Criteria of the Canadian Control Products Regulation (CPR) and this MSDS contains all information required
by the Canadian Products Regulation.

*N/A. - Not Applicable

SECTION XVI - OTHER INFORMATION
*N/K. - Not Known

The submission of this MSDS may be required by law, but this is not an assertion that the substance is hazardous
when used in accordance with proper safety practices and normal handling procedures. Data supplied is for use
only in connection with occupational safety and health.
The information contained herein has been compiled from sources considered by Procter & Gamble to be
dependable and is accurate to the best of the Company’s knowledge. The information relates to the specific material
designated herein, and does not relate to the use in combination with any other material or any other process.
Procter & Gamble assumed no responsibility for injury to the recipient or third persons, for any damage to any
property resulting from misuse of the controlled product.

4

Page 1 de 4
Procter & Gamble
CPG TN 6
2, Procter & Gamble Plaza
Cincinnati (Ohio) 45202

FICHE SIGNALÉTIQUE

Date de publication : 12-2005
Date de publication : 8-01

Remplace : S.O.

SECTION 1 – IDENTIFICATION DU PRODUIT
Identification : Nettoyant granulaire avec javellisant
Marques : Nettoyant avec JAVELLISANT pour planchers SPIC and SPAN (sans phosphate et avec phosphate)
Évaluation du danger : 1
Santé : 1
4 = EXTRÊME
Inflammabilité : 0
3 = ÉLEVÉ
Réactivité : 0
2 = MODÉRÉ
1 = LÉGER
Numéro de téléphone en cas d’urgence : 1 800 332-7787 ou appelez le centre antipoison de votre localité.

SECTION II – COMPOSITION ET INGRÉDIENTS
Ingrédients/Nom chimique : Agents de surface anioniques, adoucisseurs d’eau (carbonate de sodium, complexe de
phosphates sodiques [version avec phosphate]), produit à blanchir au chlore en poudre,
agent technologique [sulfate de sodium], agent de protection contre les particules
métalliques [silicate de sodium])
Ce produit est un irritant oculaire léger en vertu de la norme de communication de la Occupational Safety and Health
Administration (OSHA).
Ingrédients dangereux tels que définis par la OSHA, 29 CFR 1910.1200 et/ou la SIMDUT en vertu de la Loi
sur les produits dangereux.
No de CAS
Limites recommandées
Écart de la
DL50/CL50
Nom chimique Nom commun
composition
chimique
Carbonate de
Bicarbonate de 497-19-8
S.O.
15 à 40 % DL50=1,86
g/kg
sodium
soude
(O.P.)
10 à 25 % CL50 = S.O.
(PHOSPHO
RE)

Dichloroisocyanur
ate de sodium
dihydraté

Sodium DCC

2893-78-9

AGCY VLE

10 à 15 %

DL50=735
mg/kg chez
le rat

15 à 30 %

DL50=0,651,26 g/kg
CL50 = S.O.

10 mg/m3
OSHA PEL
15mg/m3

Alkyl benzène
sulfonate
linéaire

alkylsulfonate
linéaire

68081-81-2

S.O.

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SECTION III – IDENTIFICATION DES DANGERS
Dangers pour la santé (aigus et chroniques) :
Ingestion : L’ingestion du produit peut causer une irritation gastro-intestinale passagère provoquant nausées,
vomissements et/ou diarrhée.
Contact avec les yeux : Peut causer une irritation passagère légère accompagnée d’une sensation de brûlure, des
larmoiements, un prurit, de l’œdème et des rougeurs.
Inhalation : L’exposition intense ou prolongée à la poussière du produit peut causer une irritation passagère des
voies respiratoires accompagnée de toux, de maux de gorge, de sifflement ou de dyspnée
passagère.

SECTION IV – PREMIERS SOINS
Procédures d’urgence et de premiers soins :
Ingestion : Boire un ou deux grands verres d’eau. Si une quantité importante de produit est ingérée,
consultez un médecin.
Contact avec les yeux : Rincer à grande eau pendant au moins 10 à 15 minutes.
Peau : Rincez abondamment avec de l’eau. Cesser l’emploi.
Inhalation : Quitter le lieu empoussiéré.
Autre : L’emballage du produit comporte un énoncé de risques : MISE EN GARDE : Peut causer une irritation des
yeux/de la peau. Irritant oculaire : Éviter le contact avec les yeux. Ne pas mélanger avec d’autres produits
nettoyants puisque des vapeurs irritantes pourraient être émises. Peut être irritant pour la peau. En cas de
peau sensible ou de contact prolongé, le port de gants est recommandé. Dans le cas d’un contact avec les
yeux ou la peau, rincer à grande eau pendant au moins 15 minutes. Si l’irritation persiste, consulter un
médecin. TENIR HORS DE LA PORTÉE DES ENFANTS.
SECTION – RENSEIGNEMENTS CONCERNANT LES MOYENS D’EXTINCTION
Point d’éclair (méthode utilisée) : S.O.

Limites d’explosion :

LIE : S.O.

LES : S.O.

Moyens d’extinction : CO2, eau ou poudre extinctrice
Procédures spéciales d’extinction : Aucune connue
Risques d’incendie inhabituels : S.O.

SECTION VI – MESURES À PRENDRE EN CAS DE DÉVERSEMENT ACCIDENTEL
Précautions personnelles : S.O.
Précautions environnementales : ÉLIMINER CONFORMÉMENT AUX RÈGLEMENTS FÉDÉRAUX,
PROVINCIAUX ET LOCAUX. Les solutions domestiques peuvent être évacuées dans l’égout. Le produit sec peut
être enfoui si les règlements locaux le permettent. Jeter les contenants vides dans la poubelle.
Mesures à prendre en cas de fuite ou de déversement : Les petites quantités peuvent être progressivement
évacuées dans les égouts appropriés (contient des surfactifs biodégradables). Éliminer conformément aux règlements
applicables. Prévenir l’exposition intense à la poussière au moyen d’un appareil respiratoire approuvé par le
NIOSH.

2

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SECTION VII – MANUTENTION ET ENTREPOSAGE
Précautions à prendre pour la manutention et l’entreposage : Entreposer dans un lieu frais et sec. Éviter
l’humidité pour éviter que les granules ne s’agglomèrent.
Autres précautions : Aucune
SECTION VIII – PROTECTION PERSONNELLE ET CONTRÔLE DE L’EXPOSITION AU PRODUIT
Protection des voies respiratoires (spécifier le type) : Aucune dans des conditions normales d’utilisation.
Ventilation :
Ventilation par aspiration à la source : Aucune dans des conditions normales d’utilisation..
Spéciale : Aucune
Mécanique (générale) : Acceptable.
Autre : Aucune
Protection des yeux : Non requise à l’usage normal.
Industrie manufacturière : Dans des conditions poussiéreuses ou si une éclaboussure est probable, des lunettes
protectrices contre les agents chimiques pourraient s’avérer nécessaires.
Gants de protection : Non requis à l’usage normal.
Industrie manufacturière : Des gants de protection (caoutchouc, néoprène) s’imposent dans le cas des contacts
directs prolongés.
Autre équipement de protection : Non requis à l’usage normal.

SECTION IX – PROPRIÉTÉS PHYSIQUES ET CHIMIQUES
Point d’ébullition (°°F) : S.O.

Densité (H2O=1) : S.O.

Tension de vapeur (mm Hg) : S.O.

Pourcentage volatile au volume (%) : S.O.

Densité de vapeur (Air=1) : S.O.

Taux d’évaporation (nBuOAc=1) : S.O.

Seuil de l’odeur : S.O.

Point de congélation : S.O.

Coefficient de répartition eau-huile : S.O.

pH (solution 1 %) : environ10,9

Densité volumique : 0,4/en vase fermé (densité
apparente)

Solubilité dans l’eau : Importante

Apparence et odeur : Poudre blanche avec granules
verts à la senteur neutre

Alcalinité : 4,0 max

SECTION X – STABILITÉ ET RÉACTIVITÉ
Réactions/conditions dangereuses possibles : Aucune connue
Conditions à éviter : Aucune
Matériaux à éviter : Produits contenant de l’ammoniaque et acides
Produits de décomposition dangereux : Chlore gazeux
Autres recommandations : Aucune
Stabilité chimique : Stable
Polymérisation dangereuse : Impossible

3

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SECTION XI – PROPRIÉTÉS TOXICOLOGIQUES
DL50 (ingestion chez le rat) : 2,9 g/kg

SECTION XII – INFORMATION ÉCOLOGIQUE
Aucune.

SECTION XIII – RÈGLEMENTS CONCERNANT L’ÉLIMINATION
Méthode d’élimination : ÉLIMINER CONFORMÉMENT AUX RÈGLEMENTS FÉDÉRAUX, PROVINCIAUX
ET LOCAUX. Les petites quantités peuvent être évacuées dans l’égout. Le produit sec peut être enfoui. Jeter les
contenants vides dans la poubelle.

SECTION XIV – INFORMATION CONCERNANT LE TRANSPORT
Classification DOT : Le produit fini est non-toxique selon le ministère des Transports (DOT).

SECTION XV – RENSEIGNEMENTS SUPPLÉMENTAIRES SUR LA RÈGLEMENTATION
Toutes les composantes figurent sur l’inventaire du TSCA. Les règles de la nouvelle utilisation importante ne
modifie en aucun cas les composantes conformément à l’inventaire du TSCA §5.
Aucune des composantes du nettoyant avec javellisant Spic and Span n’est assujettie à la proposition 65 de la
Californie.
Tous les ingrédients ont été approuvés par la LCPE et peuvent être importés au Canada par Procter & Gamble. Ce
produit a été classé sous la catégorie Critères de risque du règlement canadien régissant les produits contrôlés et
cette fiche signalétique contient toute l’information requise par ledit règlement.

*S.O. - Sans objet

SECTION XVI – AUTRES RENSEIGNEMENTS
*INC. - Inconnu

La présentation de cette fiche signalétique est requise par la loi, mais ce n’est pas une affirmation que la substance
est dangereuse lorsque celle-ci est utilisée en respectant les bonnes règles de sécurité et les méthodes de
manutention normales. Les données fournies ne peuvent être utilisées que dans le cadre de la sécurité et de la santé
au travail.
Les renseignements de la présente fiche ont été compilés à partir de sources considérées comme fiables par la
société Procter & Gamble, et sont exacts à sa connaissance. Ces renseignements ne concernent que la matière
désignée par la présente fiche et non son utilisation en combinaison avec toute autre matière ou tout autre procédé.
Procter & Gamble n’est pas responsable des blessures infligées au destinataire ou à une tierce personne, ni d’aucun
dommage à la propriété résultant d’une utilisation incorrecte de produit contrôlé.

4

MATERIAL SAFETY DATA SHEET
SECTION 1. PRODUCT/MANUFACTURER'S IDENTITY
PRODUCT NAME: OVEN & GRILL CLEANER

PRODUCT I.D. NUMBER (PIN): 1719

PRODUCT NUMBER: 02806FS
PRODUCT USE: Oven and grill cleaner

WHMIS CLASS:

3
0
1
C

DOT HAZARD CLASS: Corrosive Material

COMPANY:
Essential Industries, Inc.
P.O. Box 12
Merton, WI 53056-0012
EMERGENCY PHONE:

H.M.I.S.

E; D2B

DOT SHIPPING NAME:
Caustic Alkali Liquid, N.O.S.
(Potassium hydroxide, Sodium metasilicate)
8, UN1719, PGIII

800-843-6174

HEALTH

HAZARD RATING

FIRE

4 = Extreme
3 = High
2 = Moderate
1 = Slight
0 = Insignificant

REACTIVITY
MAXIMUM PERSONAL
PROTECTION

A = Goggles B = Goggles & Gloves C = Goggles, Gloves & Apron

ABBREVIATION KEY: N.A. - Not Applicable N.E. = Not Established N.D. = Not Determined

SECTION 2 - HAZARDOUS INGREDIENTS INFORMATION
%
60-100
5-10
1-5
10-30

CAS NO.
7732-18-5
1310-58-3
6834-92-0
N.A.

HAZARDOUS CHEMICAL IDENTITY
Water
Potassium hydroxide
Sodium metasilicate
Surfactants

PEL
N.E.
2mg/m3
2mg/m3
N.E.

TLV
N.E.
2mg/m3
2mg/m3
N.E.

LD50
N.D.
365mg/kg
847mg/kg
N.D.

LC50
N.D.
N.D.
N.D.
N.D.

This mixture does not contain components which are subject to the reporting requiements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of
1986 and 40 CFR, Part 372.

SECTION 3 - PHYSICAL DATA
Color:

Boiling Point:

Purple

Odor: Bland
Physical State:

Liquid

Solubility in Water:

Complete

pH: 13.0 - 14.0

Vapor Pressure: <30 mm of Hg

100°C (212°F)
Freezing Point: 0°C (32°F)
Water/Oil Distribution: N.E.

Vapor Density (Air=1): <1
Evaporation Rate (Water=1):

Odor Threshold:

VOC Content:

N.E.

1% pH: 11.8

N.E.

0.0%

Specific Gravity: 1.10 gm/ml
Weight per Gallon: 9.19 lbs./gal.

SECTION 4 - FIRE AND EXPLOSION HAZARD DATA
Flash Point and Method: N.A.

Autoignition Temperature: N.A.

Extinguishing Media:

Flammable Limits: N.A.

LEL: N.A.

Special Fire Fighting Procedures:

UEL: N.A.

Use dry chemical or CO2.
Use proper protective equipment.

Unusual Fire and Explosion Hazards:

Hazardous Combustion Products: N.A.

None.

SECTION 5 - REACTIVITY DATA
Chemical Stability:

Hazardous decomposition of By-Products: None known.

Stable.

Incompatibility (Materials to Avoid):

Acids, aluminum and other soft metals.

Hazardous Polymerization: Will not occur.

SECTION 6 - TOXICOLOGICAL PROPERTIES
Routes of Entry:
Sensitization:

Toxicologically Synergistic Products:

Ingestion. Inhalation. Skin contact. Eye contact.

None known.

Medical Conditions Aggravated by Exposure:

No.

None known.

EFFECTS OF OVEREXPOSURE (Acute and/or Chronic):
Eyes: May cause severe irritation, redness, burns and possible corneal injury.

Carcinogenic Effects:

NO carcinogenic effect.

Skin: May cause severe irritation, redness, burns.

Mutagenic Effects:

NO mutagenic effect.

Ingestion: May cause severe irritation or burning of gastrointestinal tract and possible mucosal Teratogenic Effects: NO teratogenic effect.
injury.

Reproductive Toxicity:

Inhalation: May irritate respiratory tract when used with inadequate ventilation.

NO reproductive toxicity effect.

SECTION 7 - PREVENTATIVE AND CONTROL MEASURES
Respiratory Protection:

None normally required with adequate ventilation.
Protective Gloves: Rubber/Neoprene.
Protective Clothing and Equipment:
Full cover clothing - rubber apron.
Storage Requirements: Store in cool, dry area. Follow good housekeeping
practices.
Steps to be Taken if Material
is Spilled or Released:
Waste Disposal:

Ventilation:

Local Exhaust: Acceptable Mechanical: Recommended

Eye Protection: Chemical splash goggles.
Work and Hygienic
Practices:

After handling, always wash hands thoroughly with soap
and water.

Other Requirements:

Keep out of reach of children.

Collect and reuse if possible. Dilute and flush to sewer with large quantities of water if permitted by regulatory authorities or absorb on inert
material (sand, clay, etc.) and place into container for proper disposal. Do not allow runoff into public waterways.

Dispose of as permitted by all federal, provincial, state and local regulatory authorities.

SECTION 8 - EMERGENCY FIRST AID PROCEDURES
FIRST AID - NOTES TO PHYSICIAN:
Eyes: Flush with a large amount of water for 30 minutes holding eyelids open. Seek medical attention.
Skin: Remove contaminated clothing and footwear. Flood/shower with water for 30 minutes.
Ingestion: Rinse mouth with water. Give 2-3 large glasses of water. Do not induce vomiting. Seek medical attention.
Inhalation:Remove to fresh air and rest. In all cases if symptoms persist, seek medical attention.
Note to Physician:

No additional information.

SECTION 9 - PREPARATION INFORMATION
Prepared By:

Regulatory Affairs Department

Phone:

262-538-1122

Date of Preparation:

1/1/2005.

MATERIAL SAFETY DATA SHEET
SECTION 1. PRODUCT/MANUFACTURER'S IDENTITY
PRODUCT NAME: OVEN & GRILL CLEANER

PRODUCT I.D. NUMBER (PIN): 1719

PRODUCT NUMBER: 02806FS
PRODUCT USE: Oven and grill cleaner

WHMIS CLASS:

3
0
1
C

DOT HAZARD CLASS: Corrosive Material

COMPANY:
Essential Industries, Inc.
P.O. Box 12
Merton, WI 53056-0012
EMERGENCY PHONE:

H.M.I.S.

E; D2B

DOT SHIPPING NAME:
Caustic Alkali Liquid, N.O.S.
(Potassium hydroxide, Sodium metasilicate)
8, UN1719, PGIII

800-843-6174

HEALTH

HAZARD RATING

FIRE

4 = Extreme
3 = High
2 = Moderate
1 = Slight
0 = Insignificant

REACTIVITY
MAXIMUM PERSONAL
PROTECTION

A = Goggles B = Goggles & Gloves C = Goggles, Gloves & Apron

ABBREVIATION KEY: N.A. - Not Applicable N.E. = Not Established N.D. = Not Determined

SECTION 2 - HAZARDOUS INGREDIENTS INFORMATION
%
60-100
5-10
1-5
10-30

CAS NO.
7732-18-5
1310-58-3
6834-92-0
N.A.

HAZARDOUS CHEMICAL IDENTITY
Water
Potassium hydroxide
Sodium metasilicate
Surfactants

PEL
N.E.
2mg/m3
2mg/m3
N.E.

TLV
N.E.
2mg/m3
2mg/m3
N.E.

LD50
N.D.
365mg/kg
847mg/kg
N.D.

LC50
N.D.
N.D.
N.D.
N.D.

This mixture does not contain components which are subject to the reporting requiements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of
1986 and 40 CFR, Part 372.

SECTION 3 - PHYSICAL DATA
Color:

Boiling Point:

Purple

Odor: Bland
Physical State:

Liquid

Solubility in Water:

Complete

pH: 13.0 - 14.0

Vapor Pressure: <30 mm of Hg

100°C (212°F)
Freezing Point: 0°C (32°F)
Water/Oil Distribution: N.E.

Vapor Density (Air=1): <1
Evaporation Rate (Water=1):

Odor Threshold:

VOC Content:

N.E.

1% pH: 11.8

N.E.

0.0%

Specific Gravity: 1.10 gm/ml
Weight per Gallon: 9.19 lbs./gal.

SECTION 4 - FIRE AND EXPLOSION HAZARD DATA
Flash Point and Method: N.A.

Autoignition Temperature: N.A.

Extinguishing Media:

Flammable Limits: N.A.

LEL: N.A.

Special Fire Fighting Procedures:

UEL: N.A.

Use dry chemical or CO2.
Use proper protective equipment.

Unusual Fire and Explosion Hazards:

Hazardous Combustion Products: N.A.

None.

SECTION 5 - REACTIVITY DATA
Chemical Stability:

Hazardous decomposition of By-Products: None known.

Stable.

Incompatibility (Materials to Avoid):

Acids, aluminum and other soft metals.

Hazardous Polymerization: Will not occur.

SECTION 6 - TOXICOLOGICAL PROPERTIES
Routes of Entry:
Sensitization:

Toxicologically Synergistic Products:

Ingestion. Inhalation. Skin contact. Eye contact.

None known.

Medical Conditions Aggravated by Exposure:

No.

None known.

EFFECTS OF OVEREXPOSURE (Acute and/or Chronic):
Eyes: May cause severe irritation, redness, burns and possible corneal injury.

Carcinogenic Effects:

NO carcinogenic effect.

Skin: May cause severe irritation, redness, burns.

Mutagenic Effects:

NO mutagenic effect.

Ingestion: May cause severe irritation or burning of gastrointestinal tract and possible mucosal Teratogenic Effects: NO teratogenic effect.
injury.

Reproductive Toxicity:

Inhalation: May irritate respiratory tract when used with inadequate ventilation.

NO reproductive toxicity effect.

SECTION 7 - PREVENTATIVE AND CONTROL MEASURES
Respiratory Protection:

None normally required with adequate ventilation.
Protective Gloves: Rubber/Neoprene.
Protective Clothing and Equipment:
Full cover clothing - rubber apron.
Storage Requirements: Store in cool, dry area. Follow good housekeeping
practices.
Steps to be Taken if Material
is Spilled or Released:
Waste Disposal:

Ventilation:

Local Exhaust: Acceptable Mechanical: Recommended

Eye Protection: Chemical splash goggles.
Work and Hygienic
Practices:

After handling, always wash hands thoroughly with soap
and water.

Other Requirements:

Keep out of reach of children.

Collect and reuse if possible. Dilute and flush to sewer with large quantities of water if permitted by regulatory authorities or absorb on inert
material (sand, clay, etc.) and place into container for proper disposal. Do not allow runoff into public waterways.

Dispose of as permitted by all federal, provincial, state and local regulatory authorities.

SECTION 8 - EMERGENCY FIRST AID PROCEDURES
FIRST AID - NOTES TO PHYSICIAN:
Eyes: Flush with a large amount of water for 30 minutes holding eyelids open. Seek medical attention.
Skin: Remove contaminated clothing and footwear. Flood/shower with water for 30 minutes.
Ingestion: Rinse mouth with water. Give 2-3 large glasses of water. Do not induce vomiting. Seek medical attention.
Inhalation:Remove to fresh air and rest. In all cases if symptoms persist, seek medical attention.
Note to Physician:

No additional information.

SECTION 9 - PREPARATION INFORMATION
Prepared By:

Regulatory Affairs Department

Phone:

262-538-1122

Date of Preparation:

1/1/2005.

MATERIAL SAFETY DATA SHEET
SECTION I - PRODUCT IDENTIFICATION AND USE
Product Name

Softsoap Liquid Hand Soap

Supplier’s Name

Colgate-Palmolive Canada Inc.

Telephone No.:

(416) 421-6000

Product Use
Address:

Liquid Hand Soap

NCP

Whmis Classification:

Two Morneau Sobeco Centre, 6th Floor
895 Don Mills Road, Toronto, Ontario M3C 1W3
Check your local Poison Control Centre in your
telephone white pages.

Emergency Contacts:

SECTION II - PREPARATION OF MSDS
PREPARED BY:

Technical Services

N/A = Not Applicable;

PHONE:

(416) 421-6000

DATE:

January 1, 2007

N/E = Not Established/Available

SECTION III - HAZARDOUS INGREDIENTS
Hazardous Ingredient

Concentration
Range %

C.A.S. or U.N.
Number

Exposure Limits

LD50/LC50 Specify Species and Route

N/A

SECTION IV - PHYSICAL DATA
Physical State
Liquid

Odour and Appearance
Various scents and colours

Vapour Density
N/E

Evaporation Rate
N/E

Odour Threshold
N/E

Boiling Point
N/E

Freezing Point
N/E

Specific Gravity
1.07(20°/20° C)

pH
6.0 - 6.5

Vapour Pressure
N/E

Coefficient of Water/Oil Distribution
N/E

SECTION V - FIRE OR EXPLOSION HAZARD
Flammable:

Yes

( )

No

(X)

If yes, under which conditions:

If involved in fire, use water, dry alcohol type or all purpose foam, dry chemical, carbon dioxide or other Class B extinguishing agents.

Means of Extinction:

Flashpoint and Method
N/E

Upper Flammable Limit
N/E

Hazardous Combustion Products:
Explosion Data Sensitivity
To Mechanical Impact

Lower Flammable Limit
N/E

Auto-ignition Temperature
N/E

Carbon Monoxide, Sulphur Dioxide, Oxides of Nitrogen

N/E

Explosion Data Sensitivity
To Static Charge

N/E

SECTION VI - REACTIVITY DATA
Chemical
Instability:

Yes

( )

No

(X)

If yes, under which conditions?

Incompatibility To
Other Substances:

Yes

( )

No

(X)

If yes, which ones?

Reactivity:

Yes

( )

No

(X)

If yes, under which conditions?

Hazardous Decomposition Products:

None known

SECTION VII - TOXICOLOGICAL PROPERTIES OF PRODUCT This product has not been tested as a whole.
Routes of Entry:

Skin Contact

X

Skin Absorption

Eye Contact

X

Inhalation

Effects of Acute Exposure To Product:
Skin Contact:

No evidence of dermal toxicity

Skin Absorption

N/A

Eye Contact:

Contact with eye can produce conjunctival irritation.

Inhalation:

N/A

Ingestion:

May cause vomiting with persistant, unpleasant aftertaste.

Ingestion

X

MATERIAL SAFETY DATA SHEET
Product Name

Softsoap Liquid Hand Soap

SECTION VII - TOXICOLOGICAL PROPERTIES OF PRODUCT This product has not been tested as a whole.
Effects of Chronic Exposure To Product:

N/E

LD50 of Product (Specify Species and Route)

N/E

Exposure Limits
N/E

LC50 of Product (Specify Species)

N/A

Irritancy of Product
N/E

Sensitization of Product
N/E

Carcinogenicity
N/E

Teratogenicity
N/E

Mutagenicity
N/E

Synergistic Materials
N/E

Reproductive Toxicity
N/E

SECTION VIII - PREVENTATIVE MEASURES
Personal Protective Equipment:

Rubber or Plastic Gloves, Goggles or Safety Glasses, Protective Clothing

Engineering Controls:

Safety Showers and Eyewash Fountains should be available. The product should be used in a well ventilated area.

Leak and Spill Procedures:

Rinse with water

Waste Disposal:

Dispose in accordance with Federal, Provincial and Local regulations.

Handling Procedures and
Equipment:

Follow routine safe handling procedures. Avoid contact when handling.

Storage Requirements:

Store in suitably labeled containers. Keep containers tightly closed. Protect from damage. Store in a cool, dry, well-ventilated area,
out of direct sunlight.

Special Shipping Instruction:

None

SECTION IX - TRANSPORTATION OF DANGEROUS GOODS
TDG Regulated Product:

PIN Number:

Yes

( )

No

N/A

(X)

Product TDG or CFR 49 Shipping Name
(If CFR so indicate)
Packaging Group

N/A

N/A

SECTION X - FIRST AID MEASURES
Skin:

Flush the contact area well with lukewarm running water for at least 15 minutes. If irritation persists, call a physician.

Eye:

Flush the contaminated eye(s) for at least 15 minutes with lukewarm water, holding the eyelid open. Take care not to rinse contaminated water into
the non-affected eye. Always seek medical attention for eye injuries.

Inhalation:

N/A

Ingestion:

If swallowed drink 3 - 4 glasses of water. DO NOT INDUCE VOMITING. Call a physician.

This product is labeled in accordance with the requirements of the Hazardous Products Act and/or the Pest Control Products Act in that the use pattern and exposure in
the workplace is generally consistent with that experienced by consumers. In certain respects, the requirements of the Workplace Hazardous Materials Information
System applicable to the drafting of this Material Safety Data Sheet may differ from the requirements of those acts and regulations and as a result, this MSDS may
contain additional information to that found on the label.
Because we cannot anticipate or control the many different conditions under which this information and our products may be used, we do not guarantee the applicability
of this information or the suitability of our products in any given situation. Users of our products should make their own tests to determine the safety and suitability of
each such product for their particular purposes.

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name:
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

FORMULA 491705
MANGO
ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Acetone
Propane
Isobutane
n-Butane
Fragrance

CAS No.:
67-64-1
74-98-6
75-28-5
106-97-8
Not available

TLV:
500ppm
2500ppm
Not established
800ppm
Not available

______________________________________________________________________________

SECTION 3
Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA
<0 to 1330 F
Slightly
Clear/mango scent

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5
Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.

First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________

SECTION 9

SPILL OR LEAK PROCEDURE

Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None

__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491705

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name:
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

FORMULA 491655
TROPICAL NECTAR
ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Acetone
Propane
Isobutane
n-Butane
Fragrance

CAS No.:
67-64-1
74-98-6
75-28-5
106-97-8
Not available

TLV:
500ppm
2500ppm
Not established
800ppm
Not available

______________________________________________________________________________

SECTION 3
Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA
<0 to 1330 F
Slightly
Clear/tropical scent

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5
Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.

First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________

SECTION 9

SPILL OR LEAK PROCEDURE

Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None

__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491655

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name:
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

FORMULA 491805
PEACH KIWI
ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Acetone
Propane
Isobutane
n-Butane
Fragrance

CAS No.:
67-64-1
74-98-6
75-28-5
106-97-8
Not available

TLV:
500ppm
2500ppm
Not established
800ppm
Not available

______________________________________________________________________________

SECTION 3
Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA
<0 to 1330 F
Slightly
Clear/peach kiwi scent

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5
Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.

First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________

SECTION 9

SPILL OR LEAK PROCEDURE

Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None

__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491805

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name: NEUTRAZEN Natural Scents
491153 Cinnamon
491105 Citrus Creme
491325 Citrus Peel
491235 Cranberry Spice
491123 Fresh Linen
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

(Hand Held Cans)
491075 Fruit Basket
491255 Green Apple
491455 Mango
491155 Orchard Spice
491405 Peach Kiwi

491355 Pina Colada
491305 Powder Fresh
491055 Tropical Nectar
491205 Vanilla Delight

ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Dimethyl Ketal
Isobutane
Propane
Butane
Fragrance

CAS No.:
67-64-1
75-28-5
74-98-6
106-97-8
Not available

TLV:
500ppm
Not established
2500ppm
800ppm
Not available

______________________________________________________________________________

SECTION 3

Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA

<0 to 1330 F
Slightly
Clear

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5

Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.
First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

SECTION 9

SPILL OR LEAK PROCEDURE

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________
Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None
__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491153,491105,491325,491235,491123,491075,491255,491455,491155,491405,491355,491305,491055, 491205

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name: NEUTRAZEN Natural Scents
491153 Cinnamon
491105 Citrus Creme
491325 Citrus Peel
491235 Cranberry Spice
491123 Fresh Linen
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

(Hand Held Cans)
491075 Fruit Basket
491255 Green Apple
491455 Mango
491155 Orchard Spice
491405 Peach Kiwi

491355 Pina Colada
491305 Powder Fresh
491055 Tropical Nectar
491205 Vanilla Delight

ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Dimethyl Ketal
Isobutane
Propane
Butane
Fragrance

CAS No.:
67-64-1
75-28-5
74-98-6
106-97-8
Not available

TLV:
500ppm
Not established
2500ppm
800ppm
Not available

______________________________________________________________________________

SECTION 3

Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA

<0 to 1330 F
Slightly
Clear

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5

Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.
First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

SECTION 9

SPILL OR LEAK PROCEDURE

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________
Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None
__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491153,491105,491325,491235,491123,491075,491255,491455,491155,491405,491355,491305,491055, 491205

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name: NEUTRAZEN Natural Scents
491153 Cinnamon
491105 Citrus Creme
491325 Citrus Peel
491235 Cranberry Spice
491123 Fresh Linen
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

(Hand Held Cans)
491075 Fruit Basket
491255 Green Apple
491455 Mango
491155 Orchard Spice
491405 Peach Kiwi

491355 Pina Colada
491305 Powder Fresh
491055 Tropical Nectar
491205 Vanilla Delight

ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Dimethyl Ketal
Isobutane
Propane
Butane
Fragrance

CAS No.:
67-64-1
75-28-5
74-98-6
106-97-8
Not available

TLV:
500ppm
Not established
2500ppm
800ppm
Not available

______________________________________________________________________________

SECTION 3

Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA

<0 to 1330 F
Slightly
Clear

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5

Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.
First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

SECTION 9

SPILL OR LEAK PROCEDURE

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________
Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None
__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491153,491105,491325,491235,491123,491075,491255,491455,491155,491405,491355,491305,491055, 491205

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name: NEUTRAZEN Natural Scents
491153 Cinnamon
491105 Citrus Creme
491325 Citrus Peel
491235 Cranberry Spice
491123 Fresh Linen
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

(Hand Held Cans)
491075 Fruit Basket
491255 Green Apple
491455 Mango
491155 Orchard Spice
491405 Peach Kiwi

491355 Pina Colada
491305 Powder Fresh
491055 Tropical Nectar
491205 Vanilla Delight

ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Dimethyl Ketal
Isobutane
Propane
Butane
Fragrance

CAS No.:
67-64-1
75-28-5
74-98-6
106-97-8
Not available

TLV:
500ppm
Not established
2500ppm
800ppm
Not available

______________________________________________________________________________

SECTION 3

Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA

<0 to 1330 F
Slightly
Clear

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5

Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.
First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

SECTION 9

SPILL OR LEAK PROCEDURE

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________
Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None
__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491153,491105,491325,491235,491123,491075,491255,491455,491155,491405,491355,491305,491055, 491205

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name: NEUTRAZEN Natural Scents
491153 Cinnamon
491105 Citrus Creme
491325 Citrus Peel
491235 Cranberry Spice
491123 Fresh Linen
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

(Hand Held Cans)
491075 Fruit Basket
491255 Green Apple
491455 Mango
491155 Orchard Spice
491405 Peach Kiwi

491355 Pina Colada
491305 Powder Fresh
491055 Tropical Nectar
491205 Vanilla Delight

ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Dimethyl Ketal
Isobutane
Propane
Butane
Fragrance

CAS No.:
67-64-1
75-28-5
74-98-6
106-97-8
Not available

TLV:
500ppm
Not established
2500ppm
800ppm
Not available

______________________________________________________________________________

SECTION 3

Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA

<0 to 1330 F
Slightly
Clear

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5

Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.
First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

SECTION 9

SPILL OR LEAK PROCEDURE

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________
Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None
__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491153,491105,491325,491235,491123,491075,491255,491455,491155,491405,491355,491305,491055, 491205

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name: NEUTRAZEN Natural Scents
491153 Cinnamon
491105 Citrus Creme
491325 Citrus Peel
491235 Cranberry Spice
491123 Fresh Linen
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

(Hand Held Cans)
491075 Fruit Basket
491255 Green Apple
491455 Mango
491155 Orchard Spice
491405 Peach Kiwi

491355 Pina Colada
491305 Powder Fresh
491055 Tropical Nectar
491205 Vanilla Delight

ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Dimethyl Ketal
Isobutane
Propane
Butane
Fragrance

CAS No.:
67-64-1
75-28-5
74-98-6
106-97-8
Not available

TLV:
500ppm
Not established
2500ppm
800ppm
Not available

______________________________________________________________________________

SECTION 3

Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA

<0 to 1330 F
Slightly
Clear

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5

Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.
First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

SECTION 9

SPILL OR LEAK PROCEDURE

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________
Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None
__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491153,491105,491325,491235,491123,491075,491255,491455,491155,491405,491355,491305,491055, 491205

NFPA Hazard Rating
Flammability

0
0

Health

MATERIAL SAFETY DATA SHEET
L-82E

0

Reactivity

0 = Minimum 1 = Light 2 = Moderate 3 = Serious 4 = Extreme

Section 1 - Product Identification
Bio-Chem Surface Technology

Trade name:

Gold Matrix All Purpose

5977 Transcanada Highway
Pointe-Claire, Quebec
H9R 1C1
Emergency: CANUTEC (613) 996-6666

Product name:
Order no.:
WHMIS Classification:
Controlled under WHMIS:

Industrial cleaner/degreaser
53-G 603, 53-G 607, 53-G608
Non-hazardous
No

Section 2 - Hazardous Ingredients
Ingredients

CAS Number

% by Weight

LD50RAT

LC50RAT

No hazardous substances to declare.

Section 3 - Physical / Chemical Characteristics
Physical state:
pH:
Specific gravity:
Evaporation rate:

Liquid
12
1.00 g/ml @ 20ºC
N/Av

Odour & appearance:Lavender, blue
Boiling point:
98ºC
Vapour pressure:
N/Av
VOC g/l:
N/Av

Odour threshold: None
Freezing point: 0ºC
Vapour density: N/Av
Water solubility: Soluble

Section 4 - Fire & Explosion Hazard
Flammability: No
Flashpoint: N/A

Conditions: None

Auto ignition temperature: N/A
Flammable limits (%): Upper: N/A Lower: N/A

Extinguishing media: None
Hazardous combustion products: None
Sensitivity to mechanical impact or static discharge: No

Section 5 - Reactivity Data
Chemical stability: Yes
Conditions: None
Incompatible substances: Do not mix with other chemicals.
Hazardous decomposition products: None
N/A - Not Applicable

Reactivity conditions: None

N/Av - Not Available
Page 1 of 2

MATERIAL SAFETY DATA SHEET
L-82E
Section 6 - Toxicological Data
Route of entry: Eye and skin contact, ingestion.
Acute exposure effects: None
Chronic exposure effects: None
Exposure limits (TLV/TWA): N/Av
Carcinogenicity
Mutagenicity
Reproductive toxicity
No
No
No
If yes to any of the above, specify:

Teratogenicity
No

Synergistic effects
No

Section 7 - Preventive Measures
Protective equipment:
Handling procedures:
Waste disposal methods:
Leak/spill procedures:
Storage requirements:
Engineering controls:
Handling equipment:
Special shipping information:

Gloves in case of prolonged contact.
Keep container tightly closed.
Dispose as per municipal, provincial and federal regulations.
Soak up with absorbent material. Rinse small amount with quantity of water. Neutralize.
Store below 50ºC and above 0ºC. Keep upright.
None
None

Section 8 - First Aid Measures
Skin contact:
Eye contact:
Inhalation:
Ingestion:
Other:

Wash off with water and soap. Apply cream.
Rinse eyes thoroughly with water. Consult a physician.
N/A
Do not induce vomitting. Rinse mouth with water and give plenty of water to drink.
Consult a physician.

Section 9 - Preparation of MSDS
Prepared by:
Telephone:
Date:

Division Manager WCB
(514) 733-3315
June 21th, 2007

This data is offered in good faith as typical values and not as a product specification. No warranty, either express or implied is hereby made. The
recommended industrial hygiene and safe handling procedures are believed to bee generally applicable. However, each user should review these
recommendations in the specific context of the intended use and determine whether they are appropriate.

N/A - Not Applicable

N/Av - Not Available
Page 2 of 2

MATERIAL SAFETY DATA SHEET

Atlantic Chemical Equipment Co.
3471 Atlanta Industrial Parkway
Suite 200
Atlanta, GA 30331
404-505-6626

PRODUCT NAME:

(CCL) NON-RINSE EVAPORATOR COIL CLEANER

EMERGENCY PHONE: 1-800-424-9300

VII - PRECAUTIONS FOR SAFE HANDLING AND USE

May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200.

Standard must be consulted for specific requirements. This product contains
no substances subject to SARA TITLE III and 40 CRF.

HMIS SYMBOLS
HEALTH

1

FLAMMABILITY

0

REACTIVITY

0

STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED:
SMALL SPILLS: Dilute and wash to drain.
LARGE SPILLS: Due to packaging, large spills cannot occur.
WASTE DISPOSAL METHOD: Deposit in approved hazardous waste landfill in accordance with local, state, and federal regulations.

1 - IDENTIFICATION

VIII - SPECIAL PROTECTION INFORMATION

PRODUCT NAME: CCL - EVAPORATOR COIL CLEANER

PACKAGE TYPE: 16oz, 1, 5, 55 gal

PREPARED DEPARTMENT OF HAZARDOUS COMMUNICATIONS

DATE PREPARED: January 2006

RESPIRATORY: Wear approved mist respirator for mist conditions or in enclosed areas.
EYE: Chemical goggles recommended.

II - HAZARDOUS INGREDIENTS
PRINCIPLE HAZARDOUS COMPONENT(S)
(CHEMICAL NAMES)
Sodium Silicate

CAS NO

ACGIH TLV

6824-92-0

ND

ND

2-Butoxyethanol*

111-76-2

25ppm

25ppm

OSHA

PEL

% or RANGE

SKIN: Wear impervious gloves, apron, boots.

PROTECTIVE GLOVES: Recommended Butyl/alkaline resistant

OTHER: do not eat, drink, or smoke in work area. Wash hands before eating.
VENTILATION REQUIREMENTS: Local exhaust adequate

*2-Butyloxyethanol is a TITLE III Section 313 Chemical subject to reporting; a listed air contaminate with skin designation.

IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed when not in use.

III - PHYSICAL DATA
BOILING POINT ( 0F) : ND
VAPOR PRESSURE (mm Hg) : ND

SPECIFIC GRAVITY (H20= 1) : 1.062

VAPOR DENSITY (Air = 1) : ND

EVAPORATION RATE (H20 = 1) : ND

pH : 13.0

APPEARANCE AND ODOR : Clear green liquid. Bland odor

MELTING POINT: N.A.

SPECIAL PRECAUTIONARY STATEMENTS: Keep this and all chemicals out of reach of children.
NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on
experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be
confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of
merchantability fitness or otherwise is made.

SOLUBILITY IN WATER : Complete

IV - FIRE AND EXPLOSION HAZARD DATA
FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Not Flammable

SARA Title III Reporting Requirements

SPECIAL FIRE FIGHTING PROCEDURES: None known
UNUSUAL FIRE AND EXPLOSION HAZARDS: None known

V - REACTIVITY DATA
CHEMICAL
STABILITY

UNSTABLE

302

(Extremely Hazardous Substances): Reporting not required.

304/CERCLA

(Spills Notification): Not required.

311

Community Right-To-Know, RTK): Reporting required. Acute health hazard.

312

(RTK Inventory Data): Reporting required for inventories above TPQ.

CONDITIONS TO AVOID:

STABLE

X

INCOMPATIBILITY (Materials to avoid): Oxidizers or acids
HAZARDOUS DECOMPOSITION PRODUCTS:
HAZARDOUS
POLYMERIZATION

MAY OCCUR

CONDITIONS TO AVOID:

WILL NOT OCCUR

X

VI - HEALTH HAZARD AREA
ROUTE(S) OF ENTRY:

EYES Yes

SKIN Yes

INGESTION Yes

313

(Emissions and Releases): Reporting required for 2-Butoxyethanol above RQ.

DOT

NOT HAZARDOUS

INHALATION Yes
References

EFFECTS OF OVER EXPOSURE: Corrosive to eyes, skin, and mucous membranes
INHALATION: Irritation of nasal passages. Possible light headedness.

TOXIC SUBSTANCE CONTROL CT LIST (TSCA) - INGREDIENTS LISTED

SKIN CONTACT/ABSORPTION: Causes burning and irritation. 2-butoxyethanol enters bloodstream through skin absorption.

PERMISSIBLE EXPOSURE REFERENCES:
Registry of Toxic Effects of Chemical Substances.
Title 29 Code of Federal Regulations.

INGESTION: causes nausea - gastric distress. Possible pulmonary edema if aspiration of material in lungs occurs while vomiting.

National Toxicology Program (NTP) Report on Carcinogens.

EYES: Will cause burning and severe irritation.
CARCINOGENICITY:

NTP? Not listed

IARC MONOGRAPHS?N/L

OSHA REGULATED? Not listed

Title 40 Code of Federal Regulations

EMERGENCY AND FIRST AID PROCEDURES:
EYES AND SKIN: EYES - Wash with plenty of water for 15 minutes. GET IMMEDIATE MEDICAL ATTENTION.
soap and water. Get medical help if irritation persists. If nausea occurs seek medical help.

International Agency for Research on Cancer (IARC) Monographs.

SKIN - Wash well with REGULATORY STANDARDS:

INHALATION: Move to fresh air. If breathing difficulty does not improve seek medical attention.
INGESTION: Drink water. Do not cause vomiting. GET IMMEDIATE MEDICAL ATTENTION. CALL POISON CONTROL CENTER.

DOT Title 49 Code of Federal Regulations 172.101
SARA Title III
Nuclear Regulatory Commission

1

MATERIAL SAFETY DATA SHEET

Atlantic Chemical Equipment Co.
3471 Atlanta Industrial Parkway
Suite 200
Atlanta, GA 30331
404-505-6626

PRODUCT NAME:

(CCL) NON-RINSE EVAPORATOR COIL CLEANER

EMERGENCY PHONE: 1-800-424-9300

VII - PRECAUTIONS FOR SAFE HANDLING AND USE

May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200.

Standard must be consulted for specific requirements. This product contains
no substances subject to SARA TITLE III and 40 CRF.

HMIS SYMBOLS
HEALTH

1

FLAMMABILITY

0

REACTIVITY

0

STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED:
SMALL SPILLS: Dilute and wash to drain.
LARGE SPILLS: Due to packaging, large spills cannot occur.
WASTE DISPOSAL METHOD: Deposit in approved hazardous waste landfill in accordance with local, state, and federal regulations.

1 - IDENTIFICATION

VIII - SPECIAL PROTECTION INFORMATION

PRODUCT NAME: CCL - EVAPORATOR COIL CLEANER

PACKAGE TYPE: 16oz, 1, 5, 55 gal

PREPARED DEPARTMENT OF HAZARDOUS COMMUNICATIONS

DATE PREPARED: January 2006

RESPIRATORY: Wear approved mist respirator for mist conditions or in enclosed areas.
EYE: Chemical goggles recommended.

II - HAZARDOUS INGREDIENTS
PRINCIPLE HAZARDOUS COMPONENT(S)
(CHEMICAL NAMES)
Sodium Silicate

CAS NO

ACGIH TLV

6824-92-0

ND

ND

2-Butoxyethanol*

111-76-2

25ppm

25ppm

OSHA

PEL

% or RANGE

SKIN: Wear impervious gloves, apron, boots.

PROTECTIVE GLOVES: Recommended Butyl/alkaline resistant

OTHER: do not eat, drink, or smoke in work area. Wash hands before eating.
VENTILATION REQUIREMENTS: Local exhaust adequate

*2-Butyloxyethanol is a TITLE III Section 313 Chemical subject to reporting; a listed air contaminate with skin designation.

IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed when not in use.

III - PHYSICAL DATA
BOILING POINT ( 0F) : ND
VAPOR PRESSURE (mm Hg) : ND

SPECIFIC GRAVITY (H20= 1) : 1.062

VAPOR DENSITY (Air = 1) : ND

EVAPORATION RATE (H20 = 1) : ND

pH : 13.0

APPEARANCE AND ODOR : Clear green liquid. Bland odor

MELTING POINT: N.A.

SPECIAL PRECAUTIONARY STATEMENTS: Keep this and all chemicals out of reach of children.
NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on
experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be
confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of
merchantability fitness or otherwise is made.

SOLUBILITY IN WATER : Complete

IV - FIRE AND EXPLOSION HAZARD DATA
FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Not Flammable

SARA Title III Reporting Requirements

SPECIAL FIRE FIGHTING PROCEDURES: None known
UNUSUAL FIRE AND EXPLOSION HAZARDS: None known

V - REACTIVITY DATA
CHEMICAL
STABILITY

UNSTABLE

302

(Extremely Hazardous Substances): Reporting not required.

304/CERCLA

(Spills Notification): Not required.

311

Community Right-To-Know, RTK): Reporting required. Acute health hazard.

312

(RTK Inventory Data): Reporting required for inventories above TPQ.

CONDITIONS TO AVOID:

STABLE

X

INCOMPATIBILITY (Materials to avoid): Oxidizers or acids
HAZARDOUS DECOMPOSITION PRODUCTS:
HAZARDOUS
POLYMERIZATION

MAY OCCUR

CONDITIONS TO AVOID:

WILL NOT OCCUR

X

VI - HEALTH HAZARD AREA
ROUTE(S) OF ENTRY:

EYES Yes

SKIN Yes

INGESTION Yes

313

(Emissions and Releases): Reporting required for 2-Butoxyethanol above RQ.

DOT

NOT HAZARDOUS

INHALATION Yes
References

EFFECTS OF OVER EXPOSURE: Corrosive to eyes, skin, and mucous membranes
INHALATION: Irritation of nasal passages. Possible light headedness.

TOXIC SUBSTANCE CONTROL CT LIST (TSCA) - INGREDIENTS LISTED

SKIN CONTACT/ABSORPTION: Causes burning and irritation. 2-butoxyethanol enters bloodstream through skin absorption.

PERMISSIBLE EXPOSURE REFERENCES:
Registry of Toxic Effects of Chemical Substances.
Title 29 Code of Federal Regulations.

INGESTION: causes nausea - gastric distress. Possible pulmonary edema if aspiration of material in lungs occurs while vomiting.

National Toxicology Program (NTP) Report on Carcinogens.

EYES: Will cause burning and severe irritation.
CARCINOGENICITY:

NTP? Not listed

IARC MONOGRAPHS?N/L

OSHA REGULATED? Not listed

Title 40 Code of Federal Regulations

EMERGENCY AND FIRST AID PROCEDURES:
EYES AND SKIN: EYES - Wash with plenty of water for 15 minutes. GET IMMEDIATE MEDICAL ATTENTION.
soap and water. Get medical help if irritation persists. If nausea occurs seek medical help.

International Agency for Research on Cancer (IARC) Monographs.

SKIN - Wash well with REGULATORY STANDARDS:

INHALATION: Move to fresh air. If breathing difficulty does not improve seek medical attention.
INGESTION: Drink water. Do not cause vomiting. GET IMMEDIATE MEDICAL ATTENTION. CALL POISON CONTROL CENTER.

DOT Title 49 Code of Federal Regulations 172.101
SARA Title III
Nuclear Regulatory Commission

1

Atlantic Chemical Equipment Co.
2190 DeFoor Hills Rd NW
Atlanta, GA 30318
404-355-5522

MATERIAL SAFETY DATA SHEET

PRODUCT NAME:

HEAVY DUTY COIL CLEANER (HDC)

EMERGENCY PHONE: 1-800-424-9300

VII - PRECAUTIONS FOR SAFE HANDLING AND USE

May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200.

Standard must be consulted for specific requirements. This product contains
no substances subject to SARA TITLE III and 40 CRF.

HMIS SYMBOLS
HEALTH

2

FLAMMABILITY

0

REACTIVITY

0

STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED:
SMALL SPILLS: Neutralize with vinegar and flush to sanitary sewer.
LARGE SPILLS: Due to packaging, large spills can not occur.
WASTE DISPOSAL METHOD: Deposit in landfill in accordance with Local, State, and Federal regulations.

1 - IDENTIFICATION

VIII - SPECIAL PROTECTION INFORMATION

PRODUCT NAME: (HDC) HEAVY DUTY COIL CLEANER

PACKAGE TYPE: 16oz, 1, 5, 55gallon

PREPARED DEPARTMENT OF HAZARDOUS COMMUNICATIONS

DATE PREPARED: June 2003

RESPIRATORY: Needed to keep exposure below TLV for mists. Use NIOSH approved cartridge type respirator for mists.
EYE: Chemical goggles recommended

II - HAZARDOUS INGREDIENTS
OSHA

PEL

PRINCIPLE HAZARDOUS COMPONENT(S)
(CHEMICAL NAMES)
Caustic Potash (Potassium Hydroxide)

CAS NO

ACGIH TLV

1310-58-3

2 mg/m3

Hexylene Glycol

107-41-5

26 ppm

Triethanolamine

102-71-6

N/E

N/E

>1

Sodium Metasilicate

6834-92-0

N/E

N/E

>2

% or RANGE

2 mg/m3

SKIN: Avoid contact with eyes, skin, and clothing. Wash hands PROTECTIVE GLOVES: Recommended. Chemical resistant rubber or
and face thoroughly after handling.
plastic gloves.

<2
>4

OTHER: Rubber of PVC footwear, apron in misty conditions.
VENTILATION REQUIREMENTS: Local exhaust adequate.

IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed when not in use. Do not store in aluminum
drums and separate from acids.

III - PHYSICAL DATA
BOILING POINT ( 0F) : 2120F
VAPOR PRESSURE (mm Hg) : 17

SPECIFIC GRAVITY (H20= 1) : 1.12

VAPOR DENSITY (Air = 1) : 1.0

EVAPORATION RATE (H20 = 1) :

pH : 13.5

APPEARANCE AND ODOR : Clear yellow liquid - Slight glycol odor

MELTING POINT: N/D

SPECIAL PRECAUTIONARY STATEMENTS: Keep this and all chemicals out of reach of children.

SOLUBILITY IN WATER : Complete

IV - FIRE AND EXPLOSION HAZARD DATA

NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on
experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be
confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of
merchantability fitness or otherwise is made.

FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Non-Flammable
SARA Title III Reporting Requirements

SPECIAL FIRE FIGHTING PROCEDURES: Wear impervious gear to prevent all contact
UNUSUAL FIRE AND EXPLOSION HAZARDS:

V - REACTIVITY DATA
CHEMICAL
STABILITY

UNSTABLE

302

(Extremely Hazardous Substances): Reporting not required.

304/CERCLA

(Spills Notification): Reporting required for spills above 1000 lbs.

311

Community Right-To-Know, RTK): Reporting required. Acute & chronic health hazard, corrosive & toxic

312

(RTK Inventory Data): Reporting required for above TPQ.

CONDITIONS TO AVOID:

STABLE

X

INCOMPATIBILITY (Materials to avoid): Acids, acid products, oxidizing agents
HAZARDOUS DECOMPOSITION PRODUCTS: Heat, Carbon Monoxide, Carbon Dioxide
HAZARDOUS
POLYMERIZATION

MAY OCCUR

CONDITIONS TO AVOID:

WILL NOT OCCUR

X

VI - HEALTH HAZARD AREA
ROUTE(S) OF ENTRY:

EYES Yes

SKIN Yes

INGESTION Yes

313

(Emissions and Releases): Reporting not required.

DOT

Corrosive liquid, basic, inorganic, N.O.S. (contains potassium hydroxide) 8, UN3264, PGIII

INHALATION Yes
References

EFFECTS OF OVER EXPOSURE: Corrosive to eyes and mucous membranes
INHALATION: Mists are irritating to nasal passages

TOXIC SUBSTANCE CONTROL CT LIST (TSCA) - INGREDIENTS LISTED

SKIN CONTACT/ABSORPTION: Irritation, redness
INGESTION: Gastric distress. Corrosive to digestive tract. May cause central nervous system depression

PERMISSIBLE EXPOSURE REFERENCES:
Registry of Toxic Effects of Chemical Substances.
Title 29 Code of Federal Regulations.
National Toxicology Program (NTP) Report on Carcinogens.

EYES: Burning, irritation, redness. Corrosive to eyes.
CARCINOGENICITY:

NTP? Not listed

IARC MONOGRAPHS? Not listed

OSHA REGULATED? Not listed

Title 40 Code of Federal Regulations

EMERGENCY AND FIRST AID PROCEDURES:
EYES AND SKIN: EYES - Wash eyes with plenty of water for 15 minutes. SEEK IMMEDIATE MEDICAL ATTENTION
soap and water. SEEK MEDICAL ATTENTION if irritation persists

International Agency for Research on Cancer (IARC) Monographs.

SKIN - Wash well with REGULATORY STANDARDS:

INHALATION: Remove to fresh air. If breathing is difficult SEEK IMMEDIATE MEDICAL ATTENTION
INGESTION: Drink water. DO NOT induce vomiting. SEEK IMMEDIATE MEDICAL ATTENTION. CALL POISON CONTROL CENTER

DOT Title 49 Code of Federal Regulations 172.101
SARA Title III
Nuclear Regulatory Commission

1

Atlantic Chemical Equipment Co.
2190 DeFoor Hills Rd NW
Atlanta, GA 30318
404-355-5522

MATERIAL SAFETY DATA SHEET

PRODUCT NAME:

ALKALINE COIL CLEANER (ACC)

EMERGENCY PHONE: 1-800-424-9300

VII - PRECAUTIONS FOR SAFE HANDLING AND USE

May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200.

Standard must be consulted for specific requirements. This product contains
no substances subject to SARA TITLE III and 40 CRF.

HMIS SYMBOLS
HEALTH

3

FLAMMABILITY

0

REACTIVITY

0

STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED:
SMALL SPILLS: Neutralize with diluted acid flush with water to drain.
LARGE SPILLS: Due to packaging, large spills can not occur.
WASTE DISPOSAL METHOD: Deposit in accordance to local, state, and federal regulations

1 - IDENTIFICATION

VIII - SPECIAL PROTECTION INFORMATION

PRODUCT NAME: Alkaline Coil Cleaner (ACC)

PACKAGE TYPE: Pint, Gallon, Pail, or Drum

PREPARED DEPARTMENT OF HAZARDOUS COMMUNICATIONS

DATE PREPARED: June 2003

RESPIRATORY: Vapor cartridge for mists and vapors/Not normally needed with local exhaust
EYE: Chemical goggles - Recommended

II - HAZARDOUS INGREDIENTS
PRINCIPLE HAZARDOUS COMPONENT(S)
(CHEMICAL NAMES)
Caustic Soda (Sodium Hydroxide)*

CAS NO

ACGIH TLV

1310-73-2

2mg/m

OSHA

3

PEL

2mg/m

% or RANGE

3

SKIN: Wear impervious clothing, boots, splash apron

PROTECTIVE GLOVES: Chemical resistant rubber or plastic gloves

< 17

* listed air contaminate (see 29 CFR per 1910.1000)

OTHER: Do not eat, drink, or smoke in work area. Wash hands before eating
VENTILATION REQUIREMENTS: Local exhaust adequate

III - PHYSICAL DATA
BOILING POINT ( 0F) : 2120F
VAPOR PRESSURE (mm Hg) : N/D

SPECIFIC GRAVITY (H20= 1) : 1.18

VAPOR DENSITY (Air = 1) : 1

EVAPORATION RATE (H20 = 1) : > 1

pH : 13.5

APPEARANCE AND ODOR : Clear liquid - slight ester odor

MELTING POINT: N/A

IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed when not in use

SOLUBILITY IN WATER : Complete

SPECIAL PRECAUTIONARY STATEMENTS: Keep this and all chemicals out of reach of children.

IV - FIRE AND EXPLOSION HAZARD DATA
FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Flash Point: None

NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on
experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be
confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of
merchantability fitness or otherwise is made.

SPECIAL FIRE FIGHTING PROCEDURES: Flood with water; compound is corrosive to exposed skin, wear protective clothing
UNUSUAL FIRE AND EXPLOSION HAZARDS: May react with oxidizers
CHEMICAL
STABILITY

UNSTABLE

SARA Title III Reporting Requirements

CONDITIONS TO AVOID:
X

STABLE

INCOMPATIBILITY (Materials to avoid): Acids and acids products. Soft metals. Oxidizers

302

(Extremely Hazardous Substances): Reporting not required.

304/CERCLA

(Spills Notification): Reporting required if release is above RQ for sodium hydroxide (1000 lbs)

311

Community Right-To-Know, RTK): Reporting required. Acute health hazard, corrosive, toxic.

312

(RTK Inventory Data): Reporting required for inventories above threshold planning quantity.

HAZARDOUS DECOMPOSITION PRODUCTS: Carbon dioxide, Heat, Carbon Monoxide
HAZARDOUS
POLYMERIZATION

MAY OCCUR

CONDITIONS TO AVOID:
X

WILL NOT OCCUR

VI - HEALTH HAZARD AREA
ROUTE(S) OF ENTRY:

EYES Yes

SKIN Yes

INGESTION Yes

INHALATION Yes

EFFECTS OF OVER EXPOSURE: Corrosive to skin, eyes, and mucous membranes, digestive tract

313

(Emissions and Releases): Reporting not required.

INHALATION: Irritation of respiratory system/mists can cause damage to respiratory passages.

DOT

Corrosive liquid, basic, inorganic, N.O.S. (contains sodium hydroxide) 8, UN3266, PGII

SKIN CONTACT/ABSORPTION: causes burning and possible deep ulceration
References

INGESTION: Gastric distress (severe damage to membranes and deep tissues)

TOXIC SUBSTANCE CONTROL CT LIST (TSCA) - INGREDIENTS LISTED
PERMISSIBLE EXPOSURE REFERENCES:

EYES: Will cause burning and severe damage even blindness rapidly
CARCINOGENICITY:

NTP? Notlisted

IARC MONOGRAPHS? Not listed

OSHA REGULATED? Not listed

EYES AND SKIN: EYES - Flush eyes with plenty of water for 15 minutes. GET IMMEDIATE MEDICAL ATTENTION
neutralize skin then wash well with soap and water. Get medical help if irritation persists
INHALATION: Move to fresh air, if breathing is difficult or stops then start artificial respiration. GET MEDICAL ATTENTION
INGESTION: Drink water. Do Not induce vomiting. GET IMMEDIATE MEDICAL ATTENTION. Call Poison Control Center.

Registry of Toxic Effects of Chemical Substances.
Title 29 Code of Federal Regulations.

EMERGENCY AND FIRST AID PROCEDURES:
SKIN - Use vinegar to

National Toxicology Program (NTP) Report on Carcinogens.
International Agency for Research on Cancer (IARC) Monographs.
Title 40 Code of Federal Regulations
REGULATORY STANDARDS:
DOT Title 49 Code of Federal Regulations 172.101
SARA Title III
Nuclear Regulatory Commission

1

PROTECH™ Super Concentrated Condenser Coil Cleaner

85-H4X32, 85-4X08

Page 1 of 2

MATERIAL SAFETY DATA SHEET
SECTION 1

CHEMICAL PRODUCT AND COMPANY INFORMATION

Product Name: PROTECH™ Super Concentrated Condenser Coil Cleaner
Product Number(s): 85-H4X32, 85-4X08
Product Use: Coil cleaner
Company Name: North American Research Corporation
P.O. Box 1318
Lewisville, TX 75067
Telephone Numbers: (972) 492-1800, (800) 527-7520, Fax (972) 394-6755
Emergencies: Infotrac (800) 535-5053 (24 hours, everyday)
SECTION 2

Date Prepared

Jan. 24, 2003

Replaces

Apr. 04, 2001

COMPOSITION / INFORMATION ON INGREDIENTS

OSHA Hazardous Components (29 CFR 1910.1200):

Potassium Hydroxide

SECTION 3

CAS
Registry No.
1310-58-3

OSHA PEL
3
2 mg/m Ceiling

ACGIH TLV
3
2 mg/m Ceiling

Other Limits
None known

%
(Optional)
< 70

HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
POISON! DANGER! CORROSIVE. CAUSES SEVERE BURNS TO SKIN, EYES, AND OTHER BODY TISSUE. HARMFUL
OR FATAL IF SWALLOWED.
POTENTIAL HEALTH EFFECTS
EYE CONTACT: Corrosive. May cause permanent damage including blindness.
SKIN CONTACT: Corrosive. May cause permanent damage.
INHALATION: May cause irritation and corrosive effects to the nose, throat, and respiratory tract. Severe injury is usually
avoided by self-limiting coughing and sneezing symptoms.
INGESTION: Corrosive. May cause burns to mouth, throat, and stomach.
CHRONIC EXPOSURE: No known chronic effects.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: None known other than existing skin disorders.
CARCINOGENICITY: NTP? No
IARC Monographs? No
OSHA Regulated? No
SECTION 4

FIRST-AID MEASURES

EYE CONTACT: Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Get medical attention
immediately.
SKIN CONTACT: Flush immediately with plenty of water for at least 15 minutes. Get medical attention immediately.
INHALATION: If breathing is difficult: Remove to fresh air. Get medical attention immediately.
INGESTION: Do not induce vomiting! Immediately drink large quantities of water. Never give anything by mouth to an
unconscious person. Get medical attention immediately.
SECTION 5

FIRE-FIGHTING MEASURES

FLASHPOINT: Not flammable
METHOD: Not applicable
FLAMMABLE LIMITS:
LEL: Not applicable
UEL: Not applicable AUTOIGNITION TEMP: Not applicable
GENERAL HAZARD: Not considered to be a fire hazard. Will react with some metals, eg. Aluminum, tin, zinc to form flammable
hydrogen gas.
FIRE EXTINGUISHING MEDIA: Use means suitable for extinguishing surrounding fire. Water spray may be used to keep fire-exposed
containers cool.
SPECIAL INFORMATION: Corrosive material. See sections 8 and 10.
SECTION 6

ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS: Put on appropriate personal protective equipment.
ENVIRONMENTAL PRECAUTIONS AND CLEAN-UP:
Small spills: Mop up or soak up with rags and flush with water.
In the event of major spillage: Use appropriate containment consistent with good industrial or environmental practice. Recover as
much as possible. Pump, sweep or scrape up the remaining material and place in suitable clean containers for disposal by
proper methods. Use a water rinse for final clean-up.

PROTECH™ Super Concentrated Condenser Coil Cleaner

SECTION 7

85-H4X32, 85-4X08

Page 2 of 2

STORAGE AND HANDLING

HANDLING: Avoid contact with eyes, skin, and clothing. Do not taste or swallow. Avoid breathing vapors or spray mists. Wash
thoroughly after handling. Remove and wash contaminated clothing and footwear before reuse. Product residue may remain on/in
empty containers. All precautions for handling the product must be used in handling the empty container and residue. FOR
INDUSTRIAL USE ONLY.
STORAGE: Keep tightly closed in original container. Store in a cool, dry, ventilated area. Protect against physical damage. Tip: For
transport on service truck, place container inside of plastic pail and immobilize pail.
SECTION 8

EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLS: Good general ventilation should be sufficient to control airborne levels. Respiratory protection is not required
if good ventilation is maintained.
PERSONAL PROTECTION:
EYES: Chemical splash goggles.
HANDS: Chemical resistant gloves; rubber, neoprene, or other impervious material.
RESPIRATORY: If mists/vapors are not adequately controlled by ventilation, use appropriate respiratory protection to avoid over
exposure. A respiratory protection program that meets OSHA’s 29 CFR 1910.134 and ANSI Z88.2
requirements must be followed whenever workplace conditions warrant a respirator’s use.
FEET: Chemical resistant boots; rubber, neoprene, or other impervious material.
BODY: If major exposure is possible, wear suitable, impervious protective clothing.
SECTION 9

PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE AND ODOR: Semi-viscous, amber to clear liquid. Bland odor.
VAPOR PRESSURE: Not determined
SOLUBILITY IN WATER: Complete
BOILING POINT: 212°F
EVAPORATION RATE (Butyl Acetate = 1): Not determined
SECTION 10

SPECIFIC GRAVITY: 1.42
VAPOR DENSITY: Not determined
pH: 13.5
FREEZING / MELTING POINT: Not determined

STABILITY AND REACTIVITY

STABILITY: Stable under ordinary conditions of use and storage. HAZARDOUS POLYMERIZATION: Will not occur.
INCOMPATIBILITY (Materials to Avoid): Reactive with oxidizing agents, acids, chlorinated hydrocarbons, acetone. Will react with some
metals, e.g., aluminum, tin, zinc, to form flammable hydrogen gas.
HAZARDOUS DECOMPOSITION PRODUCTS: When exposed to fire, produces normal products of combustion.
SECTION 11

TOXICOLOGICAL INFORMATION

For Potassium Hydroxide (1310-58-3): Oral LD50 (rat): 365 mg/kg. Primary skin irritation: (rabbit, 24hr) severe. Primary eye irritation:
(rabbit, 24hr) severe.
SECTION 12

ECOLOGICAL INFORMATION

For Potassium Hydroxide (1310-58-3): LC50 (96hr) Fathead minnow, 45% KOH solution = 179 mg/L.
SECTION 13

DISPOSAL CONSIDERATIONS

Disposal of unused product is regulated under environmental and transportation laws as a corrosive waste. Dispose of container and
unused contents in accordance with federal, state, and local requirements.
SECTION 14

TRANSPORT INFORMATION

U.S. Department of Transportation: Potassium Hydroxide Solution, 8, UN1814, PG II
SECTION 15

REGULATORY INFORMATION

TSCA: All ingredients of this product are listed or are excluded from listing on the U.S. TSCA chemical substances inventory.
CERCLA: Potassium Hydroxide (1310-58-3); RQ 1000 lbs.
SARA TITLE III: Section 311/312 Hazard Category: Acute: Yes Chronic: No Fire: No Pressure: No Reactive Hazard: Yes
Section 313 Reportable Ingredients: None
SECTION 16

OTHER INFORMATION

NFPA RATING: Health – 3, Flammability – 0, Reactivity – 1
®

HMIS RATING: Health – 3, Flammability – 0, Reactivity – 2
®

®

®

HMIS ratings are to be used with a fully implemented HMIS program. HMIS is a registered mark of the National Paint and
Coatings Association (NPCA).
NOTICE: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty,
express or implied, as to accuracy of the information contained within. Actual conditions of use and handling are beyond seller’s control.
User is responsible to evaluate all available information when using product for any particular use and to comply with all federal, state,
provincial, and local laws and regulations.

PROTECH™ Super Concentrated Condenser Coil Cleaner

85-4X08, 85-H4X32

Page 1 of 2

MATERIAL SAFETY DATA SHEET
SECTION 1

CHEMICAL PRODUCT AND COMPANY INFORMATION

Product Name: PROTECH™ Super Concentrated Condenser Coil Cleaner
Product Number(s): 85-4X08, 85-H4X32
Product Use: Coil cleaner
Company Name: North American Research Corporation
P.O. Box 1318
Lewisville, TX 75067
Telephone Numbers: (972) 492-1800, (800) 527-7520, Fax (972) 394-6755
Emergencies: Infotrac (800) 535-5053 (24 hours, everyday)
SECTION 2

Date Prepared

Jan. 14, 2004

Replaces

COMPOSITION / INFORMATION ON INGREDIENTS

OSHA Hazardous Components (29 CFR 1910.1200):

Potassium Hydroxide

SECTION 3

CAS
Registry No.
1310-58-3

OSHA PEL
3
2 mg/m Ceiling

ACGIH TLV
3
2 mg/m Ceiling

Other Limits
None known

%
(Optional)
< 70

HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
POISON! DANGER! CORROSIVE. CAUSES SEVERE BURNS TO SKIN, EYES, AND OTHER BODY TISSUE. HARMFUL
OR FATAL IF SWALLOWED.
POTENTIAL HEALTH EFFECTS
EYE CONTACT: Corrosive. May cause permanent damage including blindness.
SKIN CONTACT: Corrosive. May cause permanent damage.
INHALATION: May cause irritation and corrosive effects to the nose, throat, and respiratory tract. Severe injury is usually
avoided by self-limiting coughing and sneezing symptoms.
INGESTION: Corrosive. May cause burns to mouth, throat, and stomach.
CHRONIC EXPOSURE: No known chronic effects.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: None known other than existing skin disorders.
CARCINOGENICITY: NTP? No
IARC Monographs? No
OSHA Regulated? No
SECTION 4

FIRST-AID MEASURES

EYE CONTACT: Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Get medical attention
immediately.
SKIN CONTACT: Flush immediately with plenty of water for at least 15 minutes. Get medical attention immediately.
INHALATION: If breathing is difficult: Remove to fresh air. Get medical attention immediately.
INGESTION: Do not induce vomiting! Immediately drink large quantities of water. Never give anything by mouth to an
unconscious person. Get medical attention immediately.
SECTION 5

FIRE-FIGHTING MEASURES

FLASHPOINT: Not flammable
METHOD: Not applicable
FLAMMABLE LIMITS:
LEL: Not applicable
UEL: Not applicable AUTOIGNITION TEMP: Not applicable
GENERAL HAZARD: Not considered to be a fire hazard. Will react with some metals, eg. Aluminum, tin, zinc to form flammable
hydrogen gas.
FIRE EXTINGUISHING MEDIA: Use means suitable for extinguishing surrounding fire. Water spray may be used to keep fire-exposed
containers cool.
SPECIAL INFORMATION: Corrosive material. See sections 8 and 10.
SECTION 6

ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS: Put on appropriate personal protective equipment.
ENVIRONMENTAL PRECAUTIONS AND CLEAN-UP:
Small spills: Mop up or soak up with rags and flush with water.
In the event of major spillage: Use appropriate containment consistent with good industrial or environmental practice. Recover as
much as possible. Pump, sweep or scrape up the remaining material and place in suitable clean containers for disposal by
proper methods. Use a water rinse for final clean-up.

PROTECH™ Super Concentrated Condenser Coil Cleaner

SECTION 7

85-4X08, 85-H4X32

Page 2 of 2

STORAGE AND HANDLING

HANDLING: Avoid contact with eyes, skin, and clothing. Do not taste or swallow. Avoid breathing vapors or spray mists. Wash
thoroughly after handling. Remove and wash contaminated clothing and footwear before reuse. Product residue may remain on/in
empty containers. All precautions for handling the product must be used in handling the empty container and residue. FOR
INDUSTRIAL USE ONLY.
STORAGE: Keep tightly closed in original container. Store in a cool, dry, ventilated area. Protect against physical damage. Tip: For
transport on service truck, place container inside of plastic pail and immobilize pail.
SECTION 8

EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLS: Good general ventilation should be sufficient to control airborne levels. Respiratory protection is not required
if good ventilation is maintained.
PERSONAL PROTECTION:
EYES: Chemical splash goggles.
HANDS: Chemical resistant gloves; rubber, neoprene, or other impervious material.
RESPIRATORY: If mists/vapors are not adequately controlled by ventilation, use appropriate respiratory protection to avoid over
exposure. A respiratory protection program that meets OSHA’s 29 CFR 1910.134 and ANSI Z88.2
requirements must be followed whenever workplace conditions warrant a respirator’s use.
FEET: Chemical resistant boots; rubber, neoprene, or other impervious material.
BODY: If major exposure is possible, wear suitable, impervious protective clothing.
SECTION 9

PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE AND ODOR: Semi-viscous, amber to clear liquid. Bland odor.
VAPOR PRESSURE: Not determined
SOLUBILITY IN WATER: Complete
BOILING POINT: 212°F
EVAPORATION RATE (Butyl Acetate = 1): Not determined
SECTION 10

SPECIFIC GRAVITY: 1.42
VAPOR DENSITY: Not determined
pH: 13.5
FREEZING / MELTING POINT: Not determined

STABILITY AND REACTIVITY

STABILITY: Stable under ordinary conditions of use and storage. HAZARDOUS POLYMERIZATION: Will not occur.
INCOMPATIBILITY (Materials to Avoid): Reactive with oxidizing agents, acids, chlorinated hydrocarbons, acetone. Will react with some
metals, e.g., aluminum, tin, zinc, to form flammable hydrogen gas.
HAZARDOUS DECOMPOSITION PRODUCTS: When exposed to fire, produces normal products of combustion.
SECTION 11

TOXICOLOGICAL INFORMATION

For Potassium Hydroxide (1310-58-3): Oral LD50 (rat): 365 mg/kg. Primary skin irritation: (rabbit, 24hr) severe. Primary eye irritation:
(rabbit, 24hr) severe.
SECTION 12

ECOLOGICAL INFORMATION

For Potassium Hydroxide (1310-58-3): LC50 (96hr) Fathead minnow, 45% KOH solution = 179 mg/L.
SECTION 13

DISPOSAL CONSIDERATIONS

Disposal of unused product is regulated under environmental and transportation laws as a corrosive waste. Dispose of container and
unused contents in accordance with federal, state, and local requirements.
SECTION 14

TRANSPORT INFORMATION

U.S. Department of Transportation: Potassium Hydroxide Solution, 8, UN1814, PG II
SECTION 15

REGULATORY INFORMATION

TSCA: All ingredients of this product are listed or are excluded from listing on the U.S. TSCA chemical substances inventory.
CERCLA: Potassium Hydroxide (1310-58-3); RQ 1000 lbs.
SARA TITLE III: Section 311/312 Hazard Category: Acute: Yes Chronic: No Fire: No Pressure: No Reactive Hazard: Yes
Section 313 Reportable Ingredients: None
SECTION 16

OTHER INFORMATION

NFPA RATING: Health – 3, Flammability – 0, Reactivity – 1
®

HMIS RATING: Health – 3, Flammability – 0, Reactivity – 2
®

®

®

HMIS ratings are to be used with a fully implemented HMIS program. HMIS is a registered mark of the National Paint and
Coatings Association (NPCA).
NOTICE: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty,
express or implied, as to accuracy of the information contained within. Actual conditions of use and handling are beyond seller’s control.
User is responsible to evaluate all available information when using product for any particular use and to comply with all federal, state,
provincial, and local laws and regulations.

Atlantic Chemical Equipment Co.
2190 DeFoor Hills Rd NW
Atlanta, GA 30318
404-355-5522
Toll Free: 1-800-929-2436

MATERIAL SAFETY DATA SHEET

PRODUCT NAME: (FNC) FOAM N' CLEAN COIL CLEANER
EMERGENCY PHONE: 1-800-424-9300

VII - PRECAUTIONS FOR SAFE HANDLING AND USE

May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200.

Standard must be consulted for specific requirements. This product contains
no substances subject to SARA TITLE III and 40 CRF.

HMIS SYMBOLS
HEALTH

3

FLAMMABILITY

0

REACTIVITY

0

STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED:
SMALL SPILLS: Neutralize with water and vinegar. Wash to drain
LARGE SPILLS: Due to packaging, large spills cannot occur
WASTE DISPOSAL METHOD: Deposit in landfill in accordance with local, state, and federal regulations

1 - IDENTIFICATION

VIII - SPECIAL PROTECTION INFORMATION

PRODUCT NAME: Foam N' Clean Coil Cleaner (FNC)

PACKAGE TYPE: 32oz, 1, 2.5, 5, & 55 gallon units

PREPARED BY GENE HUNT/CHEMIST SUPERSCEEDES MAY 2002 MSDS

DATE PREPARED: Revised August 2003

RESPIRATORY:

Keep face away from spray mist. Do not breathe vapors.

EYE: Use tight fitting, splash proof safety goggles. Contact lenses should no be worn when handling this material.

II - HAZARDOUS INGREDIENTS
PRINCIPLE HAZARDOUS COMPONENT(S)
(CHEMICAL NAMES)
Sodium Metasilicate

CAS NO

ACGIH TLV

6834-92-0

N/E

N/E

< 1.5

Sodium Hydroxide 50%

1310-73-2

2mg/m2

< 38

Potassium Hydroxide 45%

1310-58-3

2mg/m3

2mg/m3
NE

OSHA

PEL

% or RANGE

PROTECTIVE GLOVES: Chemical resistant rubber/neoprene

OTHER: Avoid contact with eyes, skin, and clothing. Wash hands and face thoroughly after handling

<4
VENTILATION REQUIREMENTS: If vapors are detected, ventilate work area by opening windows and using exhaust fans. Always work
with wind from behind.

III - PHYSICAL DATA
BOILING POINT ( 0F) : 2120F
VAPOR PRESSURE (mm Hg) : 17

SPECIFIC GRAVITY (H20= 1) : 1.20

VAPOR DENSITY (Air = 1) : 2

EVAPORATION RATE (H20 = 1) : 1.0

pH : 11.6 - 13.0 @ 20 0C
SOLUBILITY IN WATER : Complete

APPEARANCE AND ODOR : Clear brown liquid, Herbal Odor

MELTING POINT:

SKIN: Wear impervious clothing and footwear to prevent all
skin contact. Use of face shield is recommended.

N/A

IX - SPECIAL PRECAUTIONS

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed when not in use
SPECIAL PRECAUTIONARY STATEMENTS: Keep this and all chemicals out of reach of children.

IV - FIRE AND EXPLOSION HAZARD DATA
FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Flash Point: Not Combustible
SPECIAL FIRE FIGHTING PROCEDURES: Standard fire fighting techniques / Wear impervious to strong Alkaline Products Clothing
UNUSUAL FIRE AND EXPLOSION HAZARDS: Avoid mixing with acids and soft metals
CHEMICAL
STABILITY

UNSTABLE

NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on
experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be
confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of
merchantability fitness or otherwise is made.
SARA Title III Reporting Requirements

CONDITIONS TO AVOID:
X

STABLE

INCOMPATIBILITY (Materials to avoid): Acids and acid products

302

(Extremely Hazardous Substances): Reporting not required.

304/CERCLA

(Spills Notification): Reporting required for spills above RQ. Sodium hydroxide and Potassium hydroxide are
listed by CERCLA. Spills in excess of 1000 lbs. Each must be reported.

311

Community Right-To-Know, RTK): Reporting required. Acute & chronic health hazard, corrosive, toxic.

312

(RTK Inventory Data): Reporting required for inventories above threshold planning quantity.

HAZARDOUS DECOMPOSITION PRODUCTS: Heat
HAZARDOUS
POLYMERIZATION

MAY OCCUR

CONDITIONS TO AVOID:
X

WILL NOT OCCUR

VI - HEALTH HAZARD AREA
ROUTE(S) OF ENTRY:

EYES Yes

SKIN Yes

INGESTION Yes

INHALATION Yes

EFFECTS OF OVER EXPOSURE: Very corrosive to skin, eyes, and mucous membranes; causes deep immediate burns, any cause blindness

313

(Emissions and Releases): Reporting not required.

INHALATION: Irritation to nasal passages

DOT

Corrosive liquids, basic, inorganic, N.O.S. (contains sodium hydroxide) 8, UN3266, PGII

SKIN CONTACT/ABSORPTION: Severe burns to exposed skin
INGESTION: Nausea, Corrosive to digestive tract
EYES: Corrosive to eyes/Blindness may occur
CARCINOGENICITY: No
NTP? Not listed

References
PERMISSIBLE EXPOSURE REFERENCES:
Registry of Toxic Effects of Chemical Substances.
IARC MONOGRAPHS? Not listed OSHA REGULATED? See ss II for exposure

EMERGENCY AND FIRST AID PROCEDURES:

Title 29 Code of Federal Regulations.

EYES AND SKIN: EYES - Wash with plenty of water for 15 minutes. GET IMMEDIATE MEDICAL ATTENTION SKIN - Neutralize with very diluted
vinegar solution, wash with soap and water, apply skin cream. For large burns - GET IMMEDIATE MEDICAL ATTENTION

National Toxicology Program (NTP) Report on Carcinogens.

INHALATION: Remove to fresh air. If breathing stops, start artificial respiration, GET IMMEDIATE MEDICAL ATTENTION

Title 40 Code of Federal Regulations

International Agency for Research on Cancer (IARC) Monographs.

INGESTION: Drink water. DO NOT induce vomiting. SEEK IMMEDIATE MEDICAL ATTENTION. NOTE: Vomiting may cause aspiration of material REGULATORY STANDARDS:
to lungs causing Pulmonary Edema
DOT Title 49 Code of Federal Regulations 172.101
SARA Title III
Nuclear Regulatory Commission

1

Atlantic Chemical Equipment Co.
2190 DeFoor Hills Rd NW
Atlanta, GA 30318
404-355-5522

MATERIAL SAFETY DATA SHEET

PRODUCT NAME: ENVIRO-SAFE COIL CLEANER (ECS)
EMERGENCY PHONE: 1-800-424-9300
May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200.

Standard must be consulted for specific requirements. This product contains
no substances subject to SARA TITLE III and 40 CRF.

VII - PRECAUTIONS FOR SAFE HANDLING AND USE
STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED:
Neutralize with diluted vinegar solution to pH of 7 the flush to sewer.

HMIS SYMBOLS
HEALTH

1

FLAMMABILITY

0

REACTIVITY

0

WASTE DISPOSAL METHOD: Flush to sanitary sewer or dispose with other sanitary waste.

1 - IDENTIFICATION

VIII - SPECIAL PROTECTION INFORMATION

PRODUCT NAME: (ECS) ENVIRO-SAFE COIL CLEANER

PACKAGE TYPE: 1, 5, 55 gal

PREPARED DEPARTMENT OF HAZARDOUS COMMUNICATIONS

DATE PREPARED: June 2003

RESPIRATORY: Required in misty conditions
EYE: Chemical goggles with side shields

II - HAZARDOUS INGREDIENTS
PRINCIPLE HAZARDOUS COMPONENT(S)
(CHEMICAL NAMES)
None known

CAS NO

ACGIH TLV

OSHA

PEL

% or RANGE

SKIN: Required to prevent skin contact

PROTECTIVE GLOVES: Required

OTHER: Follow good housekeeping practices/Empty container may contain hazardous residue. Do not reuse for food or drink.
VENTILATION REQUIREMENTS: Recommended for enclosed areas

IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed when not in use. Do not freeze. Follow label
instructions.

III - PHYSICAL DATA
BOILING POINT ( 0F) : 2140F
VAPOR PRESSURE (mm Hg) : NA

SPECIFIC GRAVITY (H20= 1) : 1.09

VAPOR DENSITY (Air = 1) : NA

EVAPORATION RATE (H20 = 1) : 14.0

pH : 8.5

APPEARANCE AND ODOR : Clear, no odor liquid

MELTING POINT: N/A

SPECIAL PRECAUTIONARY STATEMENTS: Keep this and all chemicals out of reach of children.
NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on
experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be
confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of
merchantability fitness or otherwise is made.

SOLUBILITY IN WATER : Complete

IV - FIRE AND EXPLOSION HAZARD DATA
FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Flash Point - Not Flammable

SARA Title III Reporting Requirements

SPECIAL FIRE FIGHTING PROCEDURES: Keep containers cool with water spray
UNUSUAL FIRE AND EXPLOSION HAZARDS: None known

V - REACTIVITY DATA
CHEMICAL
STABILITY

UNSTABLE

302

(Extremely Hazardous Substances): Reporting not required.

304/CERCLA

(Spills Notification): Not required.

311

Community Right-To-Know, RTK): Reporting not required.

312

(RTK Inventory Data): Not required.

CONDITIONS TO AVOID:

STABLE

X

INCOMPATIBILITY (Materials to avoid): Avoid oxidizers or acids
HAZARDOUS DECOMPOSITION PRODUCTS: Heat, carbon dioxide, carbon monoxide
HAZARDOUS
POLYMERIZATION

MAY OCCUR

CONDITIONS TO AVOID:

WILL NOT OCCUR

X

VI - HEALTH HAZARD AREA
ROUTE(S) OF ENTRY:

EYES Yes

SKIN Yes

INGESTION Yes

313

(Emissions and Releases): Reporting not required.

DOT

NOT HAZARDOUS

INHALATION Yes
References

EFFECTS OF OVER EXPOSURE:
INHALATION: Mists are corrosive to respiratory tract

TOXIC SUBSTANCE CONTROL CT LIST (TSCA) - INGREDIENTS LISTED

SKIN CONTACT/ABSORPTION: Irritating

PERMISSIBLE EXPOSURE REFERENCES:
Registry of Toxic Effects of Chemical Substances.

INGESTION: Corrosive to digestive system

Title 29 Code of Federal Regulations.
National Toxicology Program (NTP) Report on Carcinogens.

EYES: Corrosive to eyes
CARCINOGENICITY:

NTP? Not listed

IARC MONOGRAPHS? Not listed

OSHA REGULATED? Not listed

EMERGENCY AND FIRST AID PROCEDURES:

International Agency for Research on Cancer (IARC) Monographs.
Title 40 Code of Federal Regulations

EYES AND SKIN: EYES - Wash with plenty of water for 15 minutes, lifting upper and lower lids. GET IMMEDIATE MEDICAL ATTENTION. SKIN - REGULATORY STANDARDS:
Rinse skin with water. If irritation results apply skin cream and discontinue use.
DOT Title 49 Code of Federal Regulations 172.101
INHALATION: Move to fresh air. If breathing is difficult seek IMMEDIATE medical attention
INGESTION: Drink water or orange juice to dilute. DO NOT induce vomiting, GET IMMEDIATE MEDICAL ATTENTION, call Poison Control Center

SARA Title III
Nuclear Regulatory Commission

1

Atlantic Chemical Equipment Co.
2190 DeFoor Hills Rd NW
Atlanta, GA 30318
404-355-5522

MATERIAL SAFETY DATA SHEET

PRODUCT NAME:

ACESEAL MASTIC 181 (MAS)

EMERGENCY PHONE: 1-800-424-9300

VII - PRECAUTIONS FOR SAFE HANDLING AND USE

May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200.

Standard must be consulted for specific requirements. This product contains
no substances subject to SARA TITLE III and 40 CRF.

HMIS SYMBOLS
HEALTH

-

FLAMMABILITY

-

REACTIVITY

-

STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED:
SMALL SPILLS: Dilute and neutralize and wash to drain
LARGE SPILLS: Due to packaging, large spills cannot occur.
WASTE DISPOSAL METHOD: Deposit in landfill in accordance with local, state, and federal regulations.

1 - IDENTIFICATION

VIII - SPECIAL PROTECTION INFORMATION

PRODUCT NAME: (MAS) ACESEAL MASTIC 181

PACKAGE TYPE: 1, 2 gal

PREPARED DEPARTMENT OF HAZARDOUS COMMUNICATIONS

DATE PREPARED: June 2003

RESPIRATORY: None required in ventilated areas.
EYE: Follow good industrial practice by wearing safety glasses.

II - HAZARDOUS INGREDIENTS
PRINCIPLE HAZARDOUS COMPONENT(S)
(CHEMICAL NAMES)
Ammonium Hydroxide (29%)
Methyl Alcohol

OSHA

PEL

CAS NO

ACGIH TLV

1136-21-6

10 mg/cu. M

10 mg/cu. M

0.07

67-56-1

250 ppm

250 ppm

2.9

% or RANGE

SKIN: No significant concern.

PROTECTIVE GLOVES: Chemical resistant rubber or plastic.

OTHER: N/A
VENTILATION REQUIREMENTS: General good ventilation is recommended.

IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed when not in use. Store with adequate
ventilation.

III - PHYSICAL DATA
BOILING POINT ( 0F) : 1000F
VAPOR PRESSURE (mm Hg) : N/E

SPECIFIC GRAVITY (H20= 1) : 1.37

VAPOR DENSITY (Air = 1) : N/E

EVAPORATION RATE (H20 = 1) : Less than 1

pH : NA

APPEARANCE AND ODOR : White or gray with slight ammonia odor

MELTING POINT: N/A

SPECIAL PRECAUTIONARY STATEMENTS: Keep this and all chemicals out of reach of children.

SOLUBILITY IN WATER : Soluble

IV - FIRE AND EXPLOSION HAZARD DATA

NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on
experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be
confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of
merchantability fitness or otherwise is made.

FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Flash Point Non TCC
SARA Title III Reporting Requirements

SPECIAL FIRE FIGHTING PROCEDURES: None, however firefighters should always use self contained breathing apparatus as nitrogen oxides and
carbon monoxides may be involved.
UNUSUAL FIRE AND EXPLOSION HAZARDS: None

V - REACTIVITY DATA
CHEMICAL
STABILITY

UNSTABLE

302

(Extremely Hazardous Substances): Reporting not required.

304/CERCLA

(Spills Notification): Not required.

311

Community Right-To-Know, RTK): Reporting not required.

312

(RTK Inventory Data): Not required.

CONDITIONS TO AVOID:

STABLE

X

INCOMPATIBILITY (Materials to avoid): Materials that react with water
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, ammonia, nitrogen oxides
HAZARDOUS
POLYMERIZATION

MAY OCCUR

CONDITIONS TO AVOID:

WILL NOT OCCUR

X

VI - HEALTH HAZARD AREA
ROUTE(S) OF ENTRY:

EYES

SKIN

INGESTION

313

(Emissions and Releases): Reporting not required.

DOT

NOT HAZARDOUS

INHALATION
References

EFFECTS OF OVER EXPOSURE: No evidence
INHALATION: N/E

TOXIC SUBSTANCE CONTROL CT LIST (TSCA) - INGREDIENTS LISTED

SKIN CONTACT/ABSORPTION: N/E

PERMISSIBLE EXPOSURE REFERENCES:
Registry of Toxic Effects of Chemical Substances.

INGESTION: N/E

Title 29 Code of Federal Regulations.
National Toxicology Program (NTP) Report on Carcinogens.

EYES: N/E
CARCINOGENICITY:

NTP? Not listed

IARC MONOGRAPHS? N/L

OSHA REGULATED? II for exposure limits

EYES AND SKIN: EYES - Wash with plenty of water for 15 minutes. GET IMMEDIATE MEDICAL ATTENTION.
with running water and soap and water.
INHALATION: Move to fresh air. If breathing difficult seek IMMEDIATE medical attention

International Agency for Research on Cancer (IARC) Monographs.
Title 40 Code of Federal Regulations

EMERGENCY AND FIRST AID PROCEDURES:
SKIN - Wash well

REGULATORY STANDARDS:
DOT Title 49 Code of Federal Regulations 172.101
SARA Title III

INGESTION: DO NOT INDUCE VOMITING. Vomiting may cause pulmonary edema which may be fatal. GET IMMEDIATE MEDICAL ATTENTION. Nuclear Regulatory Commission
CALL POISON CONTROL CENTER - contains sulfite and caustic.

1

SAFETY DATA SHEET
LEAK DETECTOR SPRAY

Page 1
Issued: 08/06/2005
Revision No: 2

1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING
Product name: LEAK DETECTOR SPRAY
Product code: 32030
Company name: ROCOL Lubricants
ROCOL House
Swillington
Leeds
West Yorkshire
LS26 8BS
ENGLAND
Tel: +44 (0) 113 232 2700
Fax: +44 (0) 113 232 2740
Emergency tel: +44 (0) 113 232 2600

2. COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous ingredients: AMIDE DERIVATIVE 1-5%
[Xi] R36/38

3. HAZARDS IDENTIFICATION
Main hazards: None

4. FIRST AID MEASURES (SYMPTOMS)
Skin contact:
Eye contact:
Ingestion:
Inhalation:

There may be mild irritation at the site of contact.
There may be irritation and redness.
There may be irritation of the throat.
No symptoms.

4. FIRST AID MEASURES (ACTION)
Skin contact:
Eye contact:
Ingestion:
Inhalation:

Wash immediately with plenty of soap and water.
Bathe the eye with running water for 15 minutes. Consult a doctor.
Wash out mouth with water. Do not induce vomiting. Consult a doctor.
Remove casualty from exposure ensuring one's own safety whilst doing so.

5. FIRE-FIGHTING MEASURES
Extinguishing media: Use water spray to cool containers.
Protection of fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin
and eyes.

6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Refer to section 8 of SDS for personal protection details.
Environmental precautions: Do not discharge into drains or rivers.
Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by
an appropriate method.

7. HANDLING AND STORAGE
Handling requirements: Ensure there is sufficient ventilation of the area.
Storage conditions: Store in cool, well ventilated area. Keep away from sources of ignition. Keep away from direct
sunlight.
Suitable packaging: Must only be kept in original packaging.

[cont...]

Issued: 08/06/2005

SAFETY DATA SHEET
LEAK DETECTOR SPRAY

Page 2

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering measures:
Respiratory protection:
Hand protection:
Eye protection:
Skin protection:

Ensure there is sufficient ventilation of the area.
Respiratory protection not required.
Protective gloves.
Safety glasses with side-shields.
Protective clothing.

9. PHYSICAL AND CHEMICAL PROPERTIES
State:
Colour:
Odour:
Evaporation rate:
Oxidising:
Solubility in water:
Viscosity:
Boiling point/range°C:
Melting point/range°C:
Flash point°C:
Autoflammability°C:
Relative density:

Aerosol
Colourless
Odourless
Slow
Non-oxidising (by EC criteria)
Miscible in all proportions
Non-viscous
100
0
> 200
>200
1

10. STABILITY AND REACTIVITY
Stability:
Conditions to avoid:
Materials to avoid:
Haz. decomp. products:

Stable under normal conditions.
Direct sunlight. Heat. Sources of ignition.
Strong oxidising agents. Strong reducing agents.
In combustion emits toxic fumes of carbon dioxide / carbon monoxide.

11. TOXICOLOGICAL INFORMATION
Routes of exposure: Refer to section 4 of SDS for routes of exposure and corresponding symptoms.

12. ECOLOGICAL INFORMATION
Mobility: Volatile. Readily absorbed into soil.
Persistence and degradability: Biodegradable.
Bioaccumulative potential: No bioaccumulation potential.

13. DISPOSAL CONSIDERATIONS
Disposal of packaging: Dispose of in a regulated landfill site or other method for hazardous or toxic wastes.
NB: The user's attention is drawn to the possible existence of regional or national regulations
regarding disposal.

14. TRANSPORT INFORMATION
ADR / RID
UN no:
Classification code:
Shipping name:
Labelling:

1950
5A
AEROSOLS
2.2

ADR Class: 2

[cont...]

Issued: 08/06/2005

SAFETY DATA SHEET
LEAK DETECTOR SPRAY

Page 3

IMDG / IMO
UN no: 1950
EmS: F-D,S-U
Labelling: 2.2

Class: 2
Marine pollutant: .

IATA / ICAO
UN no: 1950
Labelling: 2.2

Class: 2

15. REGULATORY INFORMATION
Hazard symbols: No significant hazard.
Risk phrases: None
Safety phrases: S16: Keep away from sources of ignition - No smoking.
S23: Do not breathe spray.
S51: Use only in well-ventilated areas.
Precautionary phrases: Safety data sheet available for professional user on request.
Pressurized container: protect from sunlight and do not expose to temperatures exceeding
50°C. Do not pierce or burn, even after use.
Note: The regulatory information given above only indicates the principal regulations specifically
applicable to the product described in the safety data sheet. The user's attention is drawn to
the possible existence of additional provisions which complete these regulations. Refer to all
applicable national, international and local regulations or provisions.

16. OTHER INFORMATION
Other information: EC Directive 1999/45/EC relating to the classification, packaging and labelling of dangerous
preparations.
EC Directive 91/155/EEC defining the laying down and detailed arrangements for the system of
specific information relating to dangerous preparations.
EC Directive 94/1/EC adapting some technicalities of Council Directive 75/324/EEC on the
approximation of the laws of Member States relating to aerosol dispensers.
Risk phrases used in s.2: R36/38: Irritating to eyes and skin.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall
be used only as a guide. This company shall not be held liable for any damage resulting from
handling or from contact with the above product.

[final page]

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name: NEUTRAZEN Natural Scents (Metered Cans)
491143 Black Cherry
491120 Country Garden
491375 Gingerbread
491275 Candy Cane
491605 Cranberry Spice
491855 Green Apple
491113 Cinnamon
491250 Dutch Apple
491163 Hawaiian Kiss
491505 Citrus Creme
491333 Fresh Linen
491705 Mango
491125 Citrus Peel
491525 Fruit Basket
491755 Orchard Spice
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

491805 Peach Kiwi
491955 Pina Colada
491025 Pine Forest
491905 Powder Fresh
491655 Tropical Nectar
491555 Vanilla Delight

______________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Acetone
Propane
Isobutane
n-Butane
Fragrance

CAS No.:
67-64-1
74-98-6
75-28-5
106-97-8
Not available

TLV:
500ppm
2500ppm
Not established
800ppm
Not available

______________________________________________________________________________

SECTION 3

Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA

<0 to 1330 F
Slightly
Clear

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5

Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.
First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

SECTION 9

SPILL OR LEAK PROCEDURE

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________
Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None
__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491143,491275,491113,491505,491125,491120,491605,491250,491333,491525,491375, 491855,491163,
491705,491755,491805, 491955, 491025, 491905, 491655, 491555

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name: NEUTRAZEN Natural Scents (Metered Cans)
491143 Black Cherry
491120 Country Garden
491375 Gingerbread
491275 Candy Cane
491605 Cranberry Spice
491855 Green Apple
491113 Cinnamon
491250 Dutch Apple
491163 Hawaiian Kiss
491505 Citrus Creme
491333 Fresh Linen
491705 Mango
491125 Citrus Peel
491525 Fruit Basket
491755 Orchard Spice
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

491805 Peach Kiwi
491955 Pina Colada
491025 Pine Forest
491905 Powder Fresh
491655 Tropical Nectar
491555 Vanilla Delight

______________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Acetone
Propane
Isobutane
n-Butane
Fragrance

CAS No.:
67-64-1
74-98-6
75-28-5
106-97-8
Not available

TLV:
500ppm
2500ppm
Not established
800ppm
Not available

______________________________________________________________________________

SECTION 3

Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA

<0 to 1330 F
Slightly
Clear

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5

Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.
First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

SECTION 9

SPILL OR LEAK PROCEDURE

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________
Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None
__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491143,491275,491113,491505,491125,491120,491605,491250,491333,491525,491375, 491855,491163,
491705,491755,491805, 491955, 491025, 491905, 491655, 491555

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name: NEUTRAZEN Natural Scents
491153 Cinnamon
491105 Citrus Creme
491325 Citrus Peel
491235 Cranberry Spice
491123 Fresh Linen
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

(Hand Held Cans)
491075 Fruit Basket
491255 Green Apple
491455 Mango
491155 Orchard Spice
491405 Peach Kiwi

491355 Pina Colada
491305 Powder Fresh
491055 Tropical Nectar
491205 Vanilla Delight

ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Dimethyl Ketal
Isobutane
Propane
Butane
Fragrance

CAS No.:
67-64-1
75-28-5
74-98-6
106-97-8
Not available

TLV:
500ppm
Not established
2500ppm
800ppm
Not available

______________________________________________________________________________

SECTION 3

Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA

<0 to 1330 F
Slightly
Clear

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5

Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.
First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

SECTION 9

SPILL OR LEAK PROCEDURE

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________
Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None
__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491153,491105,491325,491235,491123,491075,491255,491455,491155,491405,491355,491305,491055, 491205

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name: NEUTRAZEN Natural Scents
491153 Cinnamon
491105 Citrus Creme
491325 Citrus Peel
491235 Cranberry Spice
491123 Fresh Linen
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

(Hand Held Cans)
491075 Fruit Basket
491255 Green Apple
491455 Mango
491155 Orchard Spice
491405 Peach Kiwi

491355 Pina Colada
491305 Powder Fresh
491055 Tropical Nectar
491205 Vanilla Delight

ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Dimethyl Ketal
Isobutane
Propane
Butane
Fragrance

CAS No.:
67-64-1
75-28-5
74-98-6
106-97-8
Not available

TLV:
500ppm
Not established
2500ppm
800ppm
Not available

______________________________________________________________________________

SECTION 3

Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA

<0 to 1330 F
Slightly
Clear

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5

Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.
First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

SECTION 9

SPILL OR LEAK PROCEDURE

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________
Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None
__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491153,491105,491325,491235,491123,491075,491255,491455,491155,491405,491355,491305,491055, 491205

Date:
Supercedes:

15 October 2007
15 November 2004

MATERIAL SAFETY DATA SHEET
IN CASE OF EMERGENCY CALL CHEMTREC AT 1-800-424-9300

1.

2.

PRODUCT IDENTIFICATION AND COMPANY IDENTIFICATION:
Product Name:

GOJO® PINK CONCENTRATE HAND SOAP

Company Name & Address:

GOJO Industries, Inc.
One GOJO Plaza, Suite 500
Akron, OH 44311

Emergency Phone:
Non-Emergency Phone:
MSDS Request Phone:

1-800-424-9300 CHEMTREC
(330) 255-6000
(330) 255-6000 x8804

INFORMATION ON INGREDIENTS:
HAZARDOUS INGREDIENTS
Ammonium Chloride as dust

CAS NUMBER
12125-02-9

Not established

Other ingredient(s) with notification requirements:
Sodium Lauryl Sulfate
Ammonium Chloride
3.

OSHA PEL

ACGIH TLV
TWA: 10 mg/m

CAS NUMBER

List

151-21-3

CN 1

12125-02-9

% RANGE
3

<3

MA 1; NJ 1;PA 1; CN 1

HAZARDS IDENTIFICATION:
EMERGENCY OVERVIEW
When used according to instructions, the product applicable to this MSDS is safe and presents no
immediate or long-term health hazard. However, abnormal entry routes, such as gross ingestion, may
require immediate medical attention.
Potential Health Effects:

4.

HMIS:

Health

1 Flammability

0 Reactivity

0 Personal Protection None

Eye Contact:
Skin Contact:
Inhalation:
Ingestion:
Carcinogenicity:

May cause eye irritation.
No irritation or reaction expected.
Not applicable.
May cause upset stomach, nausea (Abnormal entry route).
Not listed as a carcinogen by NTP, IARC, OSHA or ACGIH.

FIRST AID MEASURES:
Eye Contact:
Skin Contact:
Inhalation:
Ingestion:

Do not rub eyes. Flush eyes thoroughly with water for 15 minutes. If condition
worsens or irritation persists, contact physician.
Not applicable.
Not applicable.
Do not induce vomiting. Contact a physician or Poison Control Center.

GOJO® PINK CONCETRATE HAND SOAP
5.

Page 2 of 2

FIRE FIGHTING MEASURES:
NFPA:

Health

0 Fire

Flashpoint °F/°C (PMCC method):
Not determined.
Unusual Fire and Explosion Hazards: None known.
Special Fire Fighting Procedures:
None known.
Extinguishing Media: X Water Fog X Alcohol Foam
6.

0 Reactivity

X

CO2

X

0

Dry Chemical

Other

ACCIDENTAL RELEASE MEASURES:
No special requirements. Water clean up and rinse. CAUTION – WILL CAUSE SLIPPERY SURFACES.

7.

HANDLING AND STORAGE:
Store at normal room temperature away from reach of small children. Keep containers sealed. Use older
containers first. Avoid freezing conditions.

8.

EXPOSURE CONTROLS/PERSONAL PROTECTION:
Eye Protection:
Skin Protection:
Respiratory Protection:
Ventilation:
Protective Equipment or Clothing:

9.

PHYSICAL AND CHEMICAL PROPERTIES:
Appearance and Odor
pH (undiluted):
VOC , %:

10.

None required under normal conditions.
None required under normal conditions.
None required under normal conditions.
None required under normal conditions.
None required under normal conditions.

Pink pearlescent liquid, coconut fragrance
4.5 – 9.5
0

STABILITY AND REACTIVITY:
Stable/Non reactive product.

11.

TOXICOLOGICAL INFORMATION:
No acute or chronic toxic effects expected when used according to directions.

12.

ECOLOGICAL CONSIDERATIONS:
No ecological or special considerations when used according to directions. Not considered environmentally
harmful from normal dilution, expected usage and typical drainage to sewers, septic systems and treatment
plants.

13.

DISPOSAL CONSIDERATIONS:
No special considerations when disposed according to local, state and Federal regulations.

14.

TRANSPORT INFORMATION:
Not classified as a hazardous material.

15.

REGULATORY AND OTHER INFORMATION:
TSCA: All ingredients are listed or exempt per reference 15 USC 2602 (2)(B)(iv).
Complies with current FDA regulations for cosmetic and/or over-the-counter drug products.
Notice: The information herein is based on data considered to be accurate as of the date of preparation of this material safety data sheet.
However, no warranty or representation, expressed or implied, is made as to the accuracy or completeness of the foregoing data and
safety information. The user assumes all liability for any damage or injury resulting from abnormal use, from any failure to adhere to
recommended practices or from any hazards inherent in the nature of the product.

Document#: 9400-500

Page 1 of 4
The Procter & Gamble Company
P&G Household Care
Fabric & Home Care Innovation Center
5299 Spring Grove Avenue
Cincinnati, OH 45217-1087

MATERIAL SAFETY DATA SHEET
MSDS #:
Supersedes:

FH/H/2003/TWTA-5HRJZ8
MSDS issued March 4, 2004

Issue Date: May 9, 2006
Issue Date: Not Applicable

SECTION I - CHEMICAL PRODUCT
Identity: Mr Clean Magic Eraser Original, Duo, Extra Strength

Finished Product

Brands: MR CLEAN Magic Eraser
P&G Telephone Number: 1-800-248-1612 or call your Poison Control Center or your physician
SECTION II - COMPOSITION AND INGREDIENTS
Mr. Clean Magic Eraser is a melamine foam with cleaning agents.
Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200.
Common
CAS No.
Composition Range
Chemical Name
Name
(Wet Chemistry
None

LD50/LC50

SECTION III - HAZARDS IDENTIFICATION
Potential Health Hazards (Acute and Chronic): (See Section 11 for more information)
Ingestion: Blockage of the gastrointestinal tract may occur if swallowed. Do not ingest
Eye Contact: Irritating to eye
Skin Contact: Irritating to skin
Inhalation: Ensure adequate ventilation
Signs and Symptoms of Exposure:
Ingestion: May caust irritation and/or bloacage of the gastroinstestinal track.
Eye Contact: Dust from foam may cause mechanical irritation.
Skin Contact: Dust from foam may cause mechanical irritation.
Inhalation: Dust from foam may cause irritation of the respiratory track.
Medical Conditions Generally Known to be Aggravated by Exposure:
Potential Environmental Effects: (See Section 12 for more information)
SECTION IV – FIRST AID INFORMATION
First Aid Procedures:
Ingestion: If foam is ingested, contact a physician or veterinarian immediately. Intestinal blockage may be life
threatening to some household pets.
Eye Contact: In case of eye irritation, flush thoroughly with water for 15 minutes. If irritation persisits, seek
medical advice.
Skin Contact: In case of skin irritation, flush affected area thoroughly with water and apply a cold compress. If
irritation persists, seek medical advise. Remove any contaminated clothing.
Inhalation:If respiratioy irritation occurs, moving from the site of exposure to an area with fresh air. If irritation
perists, seek medical advise.
Note to Physician: (if applicable): Treat symptomatically.
Other: Consumer product package has the following precautionary statement: “Caution: keep out of reach of
children. Keep out of reach of toddlers and pets to avoid accidental ingestion. Do not use on skin or other parts of
the body. Using on skin will likely cause abrasions.”

Mr Clean Magic Eraser Plus Foaming Cleaner

Page 2 of 4

SECTION V - FIRE FIGHTING INFORMATION
Flammable Properties: 580 C/ 1076F
Extinguishing Media:
Suitable: Regular dry chemical, carbon dioxide, water, regular foam. For large fires: use regulary foam of flood
with fine water spray.
Unsuitable: NA
Protection of Firefighters:
Specific Hazards Arising from the Material:

Dust / air mixture may cause explosion.

Protective Equipment and Precautions for Firefighters:
SECTION VI - ACCIDENTAL RELEASE MEASURES
Personal Precautions: None Known
Environmental Precautions: Disposal is to be performed in compliance with all Federal, State, Provincial and
Local Regulations.
Methods for Containment: Collect spilled material in an approporate container for disposal.
Methods for Cleanup: Keep out of water supplies and sewers.
Other Information: (if applicable) Keep unnecessary people away, isolate hazard and deny entry to area.
SECTION VII – HANDLING AND STORAGE
Precautions To Be Taken in Handling: None known.
Precautions To Be Taken in Storage:: None known.
SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION
Exposure Guidelines:
Engineering Controls: Provide local ventilation
Personal Protective Equipment (PPE): Under conditions of frequent use or heavy exposure, respiratory
protection may be needed. (Any chemical cartridge respirator with an organic vapor cartridge(s), dust and mist
filter(s)).
Eye/Face Protection: Provide an emergenacy eye wash fountain and quick drench shower in the immediate work
area.
Skin Protection: Do not rub on skin, foam can cause abrasion to skin.
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Appearance (color, physical form, shape):

Flash Point (Method Used): NK

White and Yellow foam
Odor: None

Explosive Limits:

LEL:

Odor Threshold: Not applicable

Auto-Ignition Temperature: NK

Physical State: foam

Decomposition Temperature: NK

Vapor Pressure (mm Hg): NK

Evaporation Rate (nBuOAc=1): NK

Vapor Density (Air=1): NA

Specific Gravity/Density: NK

Boiling Point: NA

Melting/Freezing Point: NK

Partition Coefficient (n-octanol/water): NA

pH: Not applicable

Solubility in Water: Yes

Reserve Alkalinity: Not applicable

UEL:

2

Mr Clean Magic Eraser Plus Foaming Cleaner

Page 3 of 4

SECTION X - STABILITY AND REACTIVITY
Chemical Stability: Stable at normal temperatures and pressures
Conditions to Avoid: Avoid heat, flames, sparks, and other sources of ignition. Avoid contact with incompatable
materials.
Incompatible Materials: Oxizidizing materials
Hazardous Decomposition Products: Oxides of carbon, oxides of sulfur, aromatic compounds, formaldehyde,
hydrogen cyanide.
Possibility of Hazardous Reactions: None known

SECTION XI - TOXICOLOGICAL INFORMATION
Do not use on skin or other parts of the body. Using on skin will likely cause abrasions.

Chronic Effects: No chronic health effects reported.
Target Organs: No target organs reported.
Carcinogenicity: NTP: No IARC: No
OSHA: No

SECTION XII - ECOLOGICAL INFORMATION
Not available.
SECTION XIII - DISPOSAL CONSIDERATIONS
Waste Disposal Method:
Industrial Setting: Products covered by this MSDS, in their original form, when disposed as waste, are

considered non hazardous waste according to Federal RCRA regulations (40 CFR 261). Disposal should
be in accordance with local, state/provincial and federal regulations.
Household Use: Product used in household may be disposed of in refuse.

SECTION XIV - TRANSPORT INFORMATION
Ground Transport (US DOT): Not Regulated
Air Transport (IATA): Not Regulated
Marine/Water Transport (IMDG): Not Regulated

SECTION XV - ADDITIONAL REGULATORY INFORMATION

While this finished product is not considered hazardous as defined by OSHA in 29 CFR 1910.1200 (d),
this MSDS contains valuable information critical to the safe handling and proper use of the product.
All intentionally-added components of this product are listed on the US TSCA Inventory.

EPA Reg. No: Not applicable
This product is not subject to warning labeling under California Proposition 65.

Canada
All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been
classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR)
and this MSDS contains all information required by the Controlled Products Regulations.

3

Mr Clean Magic Eraser Plus Foaming Cleaner

P&G Hazard Rating:

*N/A. - Not Applicable

Page 4 of 4

SECTION XVI - OTHER INFORMATION
Health:
1
4=EXTREME
Flammability: 1
3=HIGH
Reactivity:
0
2=MODERATE
1=SLIGHT
0=NOT SIGNIFICANT
*N/K. - Not Known

Data supplied is for use only in connection with occupational safety and health.
The information contained herein has been compiled from sources considered by Procter & Gamble to be
dependable and is accurate to the best of the Company’s knowledge. The information relates to the specific
material designated herein, and does not relate to the use in combination with any other material or any other
process. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, for any damage to
any property resulting from misuse of the controlled product.

4

PRO-LINK
MATERIAL SAFETY DATA SHEET
PRO-LINK
510 CHAPMAN STREET
CANTON, MA 02021

Data Sheet No.
Issue Date 5/7/99
Issued By J. Irwin

PH: 781-828-9550
FX: 781-828-9551

SECTION 1
Trade Name/Synonyms

1401 Urinal Screen - Red/Cherry

Chemical Name/Synonyms
Chemical Family/Formula

SECTION 2 - Product/Component Data
Component(s) Chemical Name
Di (2-Ethylhexy 1) Phthalate

CAS Registry
117-81-7

% Approx. OSHA/PEL
<45.0

ACGIH TLV-TWA

5mg/m#
5mg/m3

SECTION 3 - Physical Data
Boiling Point (F)

Data Not Available
Data Not Available

Vapor Pressure (mm Hg)
Vapor Density (Air = 1)

N/A

Appearance and Odor

1.39

%, Volatile by Volume
Evaporation Rate (_ = 1)

N/A

Solubility in Water

Specific Gravity (H O = 1)

Melting Point

N/A
330 F

Pellet, slight odor

SECTION 4 - Fire & Explosion Hazard Data
Flash Point (Method Used)

Flammable Limits

N/A

LEL

UCL

N/A

N/A

Extinguishing Media

Water is most effective. ABC dry chemical, APPP and protein type air foam

Special Fire Fighting Procedures

self-contained breathing apparatus and turnout equipment should be worn

Unusual Fire & Explosion Hazards

NFPA Codes:

None under normal processing conditions
Flammability:
Health:

NE = Not Established
NA = Not Applicable

Reactivity:

SECTION 5 - Health Hazard Data
Route(s) of Entry

Inhalation: Yes (as fumes) Skin: No Ingestion: Yes
Effects of Overexposure
Health Hazards: Contains hazardous chemicals subject to the reporting requirements of Section
313 of the Emergency Planning and Community Right To Know Act of 1986. Fumes produced during normal hot melt processing may cause irritation to the eyes, respiratory tract or skin of employees who may be sensitive to these fumes.
Emergency/First Aid Procedures
Thoroughly wash skin with soap and water. If affected by fumes, remove to fresh air. If swallowed, induce vomiting by means of finger
in throat, salt water, or syrup of Ipecak. Call physician.

SECTION 6 - Reactivity Data
Stability

__Stable
__Unstable
X

Incompatibility (Materials to Avoid)

Conditions to Avoid Avoid prolonged/excessive heating; 1 hr. at 350 F 10 mins.; at 400 F
and 5 mins. at 450 F.

Oxidizing agents

Hazardous Decomposition Products
Hydrogen chloride, carbon monoxide and carbon dioxide
Conditions to Avoid

Hazardous Polymerization

___May Occur

___Will
Not Occur
X

None during normal use

SECTION 7 - Spill or Leak Procedures
Steps To Be Taken In Case Material is Released/Spilled

Normal housekeeping procedures
Waste Disposal Method

Do not incinerate. Dispose of waste in a licensed landfill in accordance with federal, state, and local regulations.

SECTION 8 - Special Protection Information
Respiratory Protection (Specify Type)
Ventilation

Not under normal processing conditions using adequate ventilation.
Special N/A
Local Exhaust As needed to remove fumes.
Mechanical (General) As needed to remove fumes. Other
N/A

Protective Gloves

Heat impervious gloves to handle hot melt

Eye Protection

Safety glasses in all industrial workplaces

Other Protective Equipment

Not normally required.

SECTION 9 - Special Precautions
Precautions To Be Taken In Handling and Storing

None - Always practice good housekeeping and hygienic measures.

This information is given in good faith but no warranty, expressed or implied, is made. Impact Products, Inc.
believes that it is accurate to the best of its knowledge and relates only to the specific material designated herein.

MATERIAL SAFETY DATA SHEET
HMIS HAZARD RATINGS

OSHA - Meets 29 CFR 1910.1200 Standards

HEALTH
FLAMMABILITY
REACTIVITY

3 = HIGH
4 = EXTREME

0 = INSIGNIFICANT
1 = SLIGHT
2 = MODERATE

2
2
0

TRANSPORTATION INFORMATION
PROPER SHIPPING NAME:

Environmentally hazardous substance, solid, n.o.s. (pdichlorobenzene)

HAZARD CLASS / PKG GRP:
IDENTIFICATION NUMBER:

9 / III
UN 3077

REF:
LABEL:

49 CFR 173.155, .213, .240
Miscellaneous

SECTION 1 - PRODUCT / COMPANY IDENTIFICATION
IDENTITY (AS USED ON LABEL AND LIST)

PARADICHLOROBENZENE BLOCKS
MANUFACTURER'S NAME
Hospital Specialty Company
ADDRESS (NUMBER, STREET, P.O. BOX)
670 Alpha Drive
(CITY, STATE AND ZIP CODE)
Highland Heights, OH 44143

( 08161, 08241, 08411, 06301, 06311, 06931, 06401,
Page 1 of 2
06411, 06901, 01931, 01991 )
EMERGENCY TELEPHONE NUMBER
CHEM • TEL (800) 255-3924 Outside USA (813) 248-0585
TELEPHONE NUMBER FOR INFORMATION
(440) 720-1800
DATE PREPARED:
April 21, 2005
SUPERSEDES:
December 15, 2001; March 18, 2002

SECTION 2 - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION
HAZARDOUS COMPONENTS
(SPECIFIC CHEMICAL IDENTITY; COMMON NAME(S))

CAS #

p-Dichlorobenzene (a,b,c,d,e,f)

106-46-7

%
(OPTIONAL)

60 - 100

OSHA PEL
PPM

75

MG/M

ACGIH TWA
3

PPM

450

10

MG/M

3

SARA

RQ

TITLE III

LBS

Yes

100

(a) Indicates a toxic chemical subject to annual reporting requirements of Section 313 of SARA Title III of the Emergency Planning and Community Right-ToKnow Act of 1986 and of 40 CFR 372.
(b) Indicates that the Resource Conservation and Recovery Act (RCRA) has determined the waste for this chemical is listed as hazardous and must be handled
according to regulations in 40 CFR 260-281.
(c) The Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) has notification requirements for releases or spills to the
environment of the Reportable Quantity (RQ for this mixture = 100 lbs) or greater amounts, according to 40 CFR 302.
(d) Indicates substance appears on National Toxicology Program (NTP) list of carcinogens, International Agency for Research on Cancer (IARC) list of
carcinogens or is regulated by the Occupational Safety and Health Administration (OSHA) as a possible carcinogen.
(e) California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986, chemicals known to the state to cause cancer or reproductive toxicity. A person
in the course of doing business must warn others who may consume, come into contact with, or otherwise be exposed to this chemical.
(f) Product is listed or defined as a marine pollutant in IMDG Code or 49 CFR 172.101 Appendix B, List of Marine Pollutants and must be classified as an
Environmentally Hazardous Substance, Class 9, in addition to any other defined hazards for this product.

SECTION 3 - HEALTH HAZARD DATA
ROUTES OF ENTRY - SIGNS AND SYMPTOMS OF EXPOSURE

EMERGENCY AND FIRST AID PROCEDURES

INHALATION: Inhalation of dust or vapors may irritate the respiratory tract; may
cause headache, dizziness, nausea, vomiting, weight loss and liver and kidney
damage. May also cause swelling around the eyes and runny nose.

Remove affected person to fresh air; provide oxygen if breathing is difficult; if
affected person is not breathing, administer CPR and seek emergency
medical attention.

SKIN: Causes skin irritation, with a slight burning sensation. Red blotching of
the skin due to allergic reactions may occur. May be absorbed through the skin;
symptoms may parallel inhalation.

Remove contaminated clothing; wash affected area with soap and water;
launder contaminated clothing before reuse; if irritation persists, seek medical
attention.

EYES: Contact causes severe irritation and pain associated with redness and
swelling of the conjunctiva.

Remove contact lenses. Flush eyes with clear running water for 15 minutes
while holding eyelids open; if irritation persists, seek medical attention.

INGESTION: Material is toxic; may cause headache, dizziness,; may cause
headache, dizziness, diarrhea and general weakness; swallowing can produce
adverse health effects paralleling inhalation.

Give two glasses of water for dilution; Induce vomiting by sticking fingers
down throat; never give anything by mouth to an unconscious person; seek
medical attention.

IARC MONOGRAPHS?
OSHA REGULATED?
CARCINOGENICITY
NTP?
Yes
Yes
p-Dichlorobenzene is listed as an anticipated carcinogen by NTP and 2B possibly carcinogenic to humans by IARC.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Preexisting skin, eye, or respiratory disorders may become aggravated through
prolonged exposure.

No

Form revised 09 / 01

MATERIAL SAFETY DATA SHEET
IDENTITY (AS USED ON LABEL AND LIST)
PARADICHLOROBENZENE BLOCKS

( 08161, 08241, 08411, 06301, 06311, 06931,
06401, 06411, 06901, 01931, 01991 )

Page 2 of 2
Date:
March 18, 2002

SECTION 4 - FIRE FIGHTING MEASURES
FLASH POINT (METHOD USED)
151º F (66º C) CC

NFPA RATING
IIA

FLAMMABLE LIMITS
LEL: 2.5%

UEL: 16.0%

EXTINGUISHING MEDIA
Carbon dioxide, water, water fog, dry chemical, chemical foam
SPECIAL FIRE FIGHTING PROCEDURES
Airborne dusts may form explosive mixtures if allowed to concentrate in confined area. Contact with strong oxidizers may cause fire.
UNUSUAL FIRE AND EXPLOSION HAZARDS
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand
or other positive pressure mode.

SECTION 5 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: COMBUSTIBLE. Evacuate and ventilate area; avoid breathing dust. Recover and
segregate product for reuse; shovel product into approved container for disposal.; for spills in excess of allowable limits (RQ) notify the National Response Center
(800) 424 - 8802; refer to CERCLA 40 CFR 302 and SARA Title III, Section 313 40 CFR 372 for detailed instructions concerning reporting requirements. Do not
discharge into lakes, ponds, streams or public waters. P-Dichlorobenzene is listed as a Marine Pollutant.

SECTION 6 - HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: This material is combustible. It should be stored in tightly closed containers in a cool, dry, well
ventilated area. Vapor may form explosive mixtures in air. All sources of ignition should be controlled. Keep this and other chemicals out of reach of children.
Avoid inhaling concentrated fumes or vapors.

SECTION 7 - EXPOSURE CONTROLS / PERSONAL PROTECTION
RESPIRATORY PROTECTION (SPECIFY TYPE): None required while threshold limits (Section 2) are kept below maximum allowable concentrations; if TWA
exceeds limits, NIOSH approved respirator must be worn. Refer to 29 CFR 1910.134 or European Standard EN 149 for complete regulations.
VENTILATION

LOCAL EXHAUST: Required
SPECIAL: To maintain minimum TWA and STEL levels.
MECHANICAL (GENERAL): Yes
OTHER: Engineering and work controls as required.
PROTECTIVE GLOVES: Neoprene or rubber gloves with cuffs.
EYE PROTECTION: Protective eyeglasses or chemical safety goggles.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Coveralls, apron, or other equipment should be worn to minimize skin contact.
WORK / HYGIENIC PRACTICES: Practice safe workplace habits. Minimize body contact with this, as well as all chemicals in general.

SECTION 8 - PHYSICAL / CHEMICAL PROPERTIES
BOILING POINT
345º F (174º C)
VAPOR PRESSURE (MM Hg)
0.6 mm Hg @ 20° C
VAPOR DENSITY (AIR = 1)
5.08
SOLUBILITY IN WATER
Practically insoluble in water.
APPEARANCE AND ODOR
White / pink solid blocks, penetrating mothball odor

SPECIFIC GRAVITY (WATER = 1)
1.500
pH
Not determined
EVAPORATION RATE (WATER = 1)
Not applicable
% VOLATILE (BY WEIGHT)
100% @ 70º F

SECTION 9 - STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Extreme temperatures, open flames, avoid
UNSTABLE:
generating airborne dust
STABLE: XXX
INCOMPATIBILITY (MATERIALS TO AVOID): Oxidizing agents, aluminum and its alloys

STABILITY

HAZARDOUS DECOMPOSITION OR BYPRODUCTS: May produce carbon monoxide, carbon dioxide, hydrogen chloride and phosgene when heated to
decomposition.
HAZARDOUS POLYMERIZATION

MAY OCCUR:
WILL NOT OCCUR: XXX

CONDITIONS TO AVOID:
None

SECTION 10 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: Dispose of in accordance with Local, State, and Federal Regulations. This product may produce concentrated hazardous vapors
or fumes in a disposal container creating a dangerous environment. Refer to "40 CFR Protection of Environment Parts 260 - 299" for complete waste disposal
regulations for ignitable materials. Consult your local, state, or Federal Environmental Protection Agency before disposing of any chemicals. Do not flush to
sanitary sewer or waterway.
The information contained herein is believed to be accurate but is not warranted to be so. Data and calculations are based on information furnished by the
manufacturer of the product and manufacturers of the components of the product. Users are advised to confirm in advance of need that information is current,
applicable and suited to the circumstances of use. Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if
reasonable safety procedures are not adhered to as stipulated in the data sheet. Furthermore, vendor assumes no responsibility for injury caused by abnormal use
of this material even if reasonable safety procedures are followed. Any questions regarding this product should be directed to the manufacturer of the product as
described in Section 1.

MSDS PREPARED BY: CDB, Inc., P.O. Box 5604, Lakeland, FL 33807 (863) 644 - 3298

www.compdatabase.com

Date:
Supercedes:

15 October 2007
15 November 2004

MATERIAL SAFETY DATA SHEET
IN CASE OF EMERGENCY CALL CHEMTREC AT 1-800-424-9300
1.

2.

PRODUCT IDENTIFICATION AND COMPANY IDENTIFICATION:
Product Name:

PURELL® HAND SANITIZER WITH ALOE

Company Name & Address:

GOJO Industries, Inc.
One GOJO Plaza, Suite 500
Akron, OH 44311

Emergency Phone:
Non-Emergency Phone:
MSDS Request Phone:

1-800-424-9300 CHEMTREC
(330) 255-6000
(330) 255-6000 x8804

INFORMATION ON INGREDIENTS:
HAZARDOUS INGREDIENTS

CAS NUMBER

OSHA PEL

ACGIH TLV

% RANGE

Ethyl Alcohol

64-17-5

1000 ppm

1000 ppm

62

Isopropanol

67-63-0

400 ppm

400 ppm

<5

Other ingredient(s) with notification requirements:

3.

CAS NUMBER

List

Ethyl Alcohol

64-17-5

MA 1; NJ 1S; PA 1; CN 2

Isopropanol

67-63-0

MA 1; NJ 1S; CN 1

HAZARDS IDENTIFICATION:
EMERGENCY OVERVIEW
When used according to instructions, the product applicable to this MSDS is safe and presents no
immediate or long-term health hazard. However, abnormal entry routes, such as gross ingestion, may
require immediate medical attention.
Potential Health Effects:

4.

HMIS:

Health

1 Flammability

3 Reactivity

0 Personal Protection None

Eye Contact:
Skin Contact:
Inhalation:
Ingestion:
Carcinogenicity:

May cause eye irritation.
No irritation or reaction expected.
Not applicable.
May cause upset stomach, nausea (Abnormal entry route).
Not listed as a carcinogen by NTP, IARC, OSHA or ACGIH.

FIRST AID MEASURES:
Eye Contact:
Skin Contact:
Inhalation:
Ingestion:

Do not rub eyes. Flush eyes thoroughly with water for 15 minutes. If condition
worsens or irritation persists, contact physician.
Not applicable.
Not applicable.
Do not induce vomiting. Contact a physician or Poison Control Center.

Purell is a trademark of Warner-Lambert Company LLC

PURELL® HAND SANITIZER WITH ALOE

5.

FIRE FIGHTING MEASURES:
NFPA:
Flashpoint °F/°C (PMCC method):
Unusual Fire and Explosion Hazards:
Special Fire Fighting Procedures:
Extinguishing Media: X Water Fog

6.

Page 2 of 2

Health
0 Fire 3 Reactivity 0
74°F/23°C
Product is flammable due to alcohol content.
None known.
X Alcohol Foam X CO2 X Dry Chemical

Other

ACCIDENTAL RELEASE MEASURES:
Avoid contact with ignition sources since product is flammable. Absorb onto inert material and dispose in
appropriate manner. Water clean up and rinse. CAUTION – WILL CAUSE SLIPPERY SURFACES.

7.

HANDLING AND STORAGE:
Keep away from fire or flame. Store at normal room temperature away from reach of small children. Keep
containers sealed. Use older containers first. Avoid freezing conditions.

8.

EXPOSURE CONTROLS/PERSONAL PROTECTION:
Eye Protection:
Skin Protection:
Respiratory Protection:
Ventilation:
Protective Equipment or Clothing:

9.

PHYSICAL AND CHEMICAL PROPERTIES:
Appearance and Odor
pH (undiluted):
VOC , %:

10.

None required under normal conditions.
None required under normal conditions.
None required under normal conditions.
None required under normal conditions.
None required under normal conditions.

Clear green liquid, floral fragrance
4.5 – 9.5
65

STABILITY AND REACTIVITY:
Stable/Non reactive product. Avoid ignition sources.

11.

TOXICOLOGICAL INFORMATION:
No acute or chronic toxic effects expected when used according to directions.

12.

ECOLOGICAL CONSIDERATIONS:
No ecological or special considerations when used according to directions. Not considered environmentally
harmful from normal dilution, expected usage and typical drainage to sewers, septic systems and treatment
plants.

13.

DISPOSAL CONSIDERATIONS:
Characteristic hazardous waste-flammable liquid. Dispose according to local, state and Federal regulations.

14.

TRANSPORT INFORMATION:
Hazardous by transport regulations. When transported by Ground and Rail, this product typically is shipped as
Consumer Commodity ORM-D. When transported by air, this product is typically shipped as Consumer
Commodity or Alcohols N.O.S. depending on package size. When transported by ocean, this product is
typically shipped as Limited Quantities. Refer to current regulations for exact requirements.

15.

REGULATORY AND OTHER INFORMATION:
TSCA: All ingredients are listed or exempt per reference 15 USC 2602 (2)(B)(iv).
Complies with current FDA regulations for cosmetic and/or over-the-counter drug products.
Notice: The information herein is based on data considered to be accurate as of the date of preparation of this material safety data sheet.
However, no warranty or representation, expressed or implied, is made as to the accuracy or completeness of the foregoing data and
safety information. The user assumes all liability for any damage or injury resulting from abnormal use, from any failure to adhere to
recommended practices or from any hazards inherent in the nature of the product.

Document#: 9650-506

MATERIAL SAFETY DATA SHEET
SECTION 1 – MATERIAL IDENTIFICATION AND USE
MATERIAL
NAME IDENTIFIER

EZE-FLO - Fumeless Alkaline Liquid Drain Opener and Cleaner

MANUFACTURERS NAME/ADDRESS

CONTACTS

Cantol Limited
199 Steelcase Road West
Markham, ON L3R 2M4

Canutec (24 hours)
(613) 996-6666
Web: www.cantol.com

SECTION 2 – HAZARDOUS INGREDIENTS
HAZARDOUS INGREDIENTS

Potassium Hydroxide

%

CAS
NUMBER

40-70

1310-58-3

LD50 OF MATERIAL
(SPECIFY SPECIES AND ROUTE)

365 mg/kg, ORAL, RAT

LC50 OF MATERIAL
(SPECIFY SPECIES)

NONE

SECTION 3 – PHYSICAL DATA
PHYSICAL STATE
GAS

LIQUID

ODOUR AND APPEARANCE

ODOUR THRESHOLD (PPM)

Clear red liquid with no odour

SOLID

Not Applicable

VAPOUR PRESSURE
(mm Hg.)

VAPOUR DENSITY
(AIR=1)

EVAPORATION
RATE

% VOLATILE
(BY VOLUME)

SOLUBILITY IN
WATER (20°C)

pH

Practically Zero
Not Available

Not Applicable
Complete

BOILING
POINT (°C)

Not Applicable

FREEZING
POINT (°C)

133 (271°F)
SPECIFIC GRAVITY

13.0 @ 1% Soln.

1.45

-29 (-20°F)
COEFF. WATER OIL DIST.

Not Available

SECTION 4 – FIRE AND EXPLOSION DATA
FLAMMABILITY
YES

IF YES, UNDER
WHICH CONDITIONS?

NO

MEANS OF EXTINCTION

Not Applicable

SPECIAL PROCEDURES

Wear protective clothing. Product is highly alkaline. Self-contained breathing apparatus should be worn in areas
where stored.

FLASHPOINT (C°) AND METHOD

UPPER EXPLOSION LIMIT (% BY VOLUME)

Not Applicable

Not Applicable

AUTO IGNITION TEMPERATURE (°C)

EXPLOSION
DATA

Not Applicable

TDG FLAMMABILITY CLASSIFICATION

Not Applicable

Not Applicable
SENSITIVITY TO IMPACT

RATE OF BURNING

Not Available

Not Available

LOWER EXPLOSION LIMIT (% BY VOLUME)

HAZARDOUS COMBUSTION PRODUCTS

None
EXPLOSIVE POWER

SENSITIVITY TO STATIC DISCHARGE

Not Available

Not Available

SECTION 5 – REACTIVITY DATA
CHEMICAL STABILITY
YES

✘

NO

IF NO, UNDER
WHICH CONDITIONS?

COMPATIBILITY WITH OTHER SUBSTANCES
YES

NO

IF NO,
WHICH ONES?

REACTIVITY, AND UNDER WHAT CONDITIONS
HAZARDOUS DECOMPOSITION PRODUCTS

Acids, aluminum, tin, zinc, combustible material, organohalogens, aldehydes.
Reacts with aluminum, tin, zinc to generate hydrogen gas. Contact with water may generate heat.
Reacts with food sugars to generate carbon monoxide.

NONE

EZE-FLO

SECTION 6 – TOXICOLOGICAL PROPERTIES
ROUTE OF ENTRY
SKIN CONTACT

✘

SKIN ABSORPTION

EYE CONTACT

✘

INHALATION ACUTE

INHALATION CHRONIC

INGESTION

✘

EFFECTS OF ACUTE EXPOSURE TO MATERIAL

Corrosive to skin and eyes. Harmful if swallowed.
EFFECTS OF CHRONIC EXPOSURE TO MATERIAL

None Known
LD 50 OF MATERIAL
SPECIFY SPECIES AND ROUTE

Not Available

LC50 OF MATERIAL
SPECIFY SPECIES

EXPOSURE LIMIT OF MATERIAL

Not Applicable

SENSITIZING CAPABILITY
OF MATERIAL

CARCINOGENICITY OF
MATERIAL

Not Available

IRRITANCY OF MATERIAL

Causes severe burns to
skin and eyes

ACGIH TLV for Potassium Hydroxide
2mg/m3
REPRODUCTIVE EFFECTS OF MATERIAL

None

SYNERGESTIC MATERIALS

None

None Known

SECTION 7 – PREVENTIVE MEASURES
PERSONAL PROTECTIVE EQUIPMENT

Gloves, eye protection
GLOVES (SPECIFY)

RESPIRATORY (SPECIFY)

EYE (SPECIFY)

Rubber, Neoprene, Plastic

None

Goggles

FOOTWEAR (SPECIFY)

CLOTHING (SPECIFY)

OTHER (SPECIFY)

None

None

None

ENGINEERING CONTROLS (SPECIFY E.G. VENTILATION ENCLOSED PROCESS)

None
LEAK AND SPILL PROCEDURE

Soak up spill with oil absorbant. Flush area with water.
WASTE DISPOSAL

Discard used absorbant in proper receptacle. Follow all government disposal regulations.
Never add water to the container. Violent reaction can occur. Always add product slowly to water
according to label directions. Wear gloves and goggles. Do not get in eyes, on skin or clothing.

HANDLING PROCEDURES AND EQUIPMENT

Keep container closed. Do not store near combustible materials.
KEEP OUT OF THE REACH OF CHILDREN.

STORAGE REQUIREMENTS

SPECIAL SHIPPING INFORMATION

LTD. QTY.

SECTION 8 – FIRST AID MEASURES
EYES: Immediately flush with plenty of water for at least 15 minutes. Seek prompt medical attention.
SKIN: Flush with water immediately. Seek prompt medical attention.
INGESTION: Do not induce vomiting. Drink large quantities of water. Call a physician.

SOURCES USED

Canadian Centre for Occupational Health and Safety, Vendor Material Safety Data Sheets
ADDITIONAL INFORMATION

For industrial and institutional use only. Read and follow all label directions and precautions. Do not mix with other
chemicals.
SECTION 9 – PREPARATION DATE OF THE MSDS
PREPARED BY

D1B, E

Cantol WHMIS Group

PHONE NUMBER

(905) 475-6141

DATE

February 1, 2007

Pumice Scouring Stick
Item Number:100714
U.S. Department Of Labor
Occupational Safety And Health Administration

MATERIAL SAFETY DATA SHEET
Required Under USDL Safety And Health Regulations
(29 CFP 1910.1200 "Hazards Communication Standard")

Section I
Manufactured For: Gabriel First Corp.
Emergency Telephone: 1-800-424-9300
Address: 233 W Commercial Street East Rochester, NY 14445
Chemical Name & Synonyms: Cleaning, Compound, Liquid
Trade Name & Synonyms: Pumice Scouring Stick
Prepared On: 6/30/2005

Section I - Hazardous Ingredients/Identity Information
Section II - Product & Component Data
Component(s)/ Chemical Names
TLV
PEL
Pumice (Volcanic Glass)
There is No Free Crystalline Silica Present

CAS Registry No

%

Section III - Physical Data
Boiling Point: N/A
Specific Gravity (H 2O=1): N/A
Melting Point: 2390° F
Vapor Pressure: N/A
Percent, Volatile By Volume (%): N/A
Vapor Density (Air=1): N/A
Evaporation Rate: N/A
Solubility In Water: Not Soluble
Appearance And Odor: Odorless Solid

Section IV - Fire And Explosion Hazard Data
Special Fire Fighting Procedures: None.
Unusual Fire and Explosion Hazards: None
Flash Point/Method Used: N/A
Flammable Limits: N/A
LEL: N/A UEL: N/A
Extinguishing Media: N/A

Section V - Health Hazard Data
Route(s) of Entry:
Inhalation? Yes
Skin? No
Ingestion: Yes
Health Hazards (Acute and Chronic): Dry sawing or grinding may result in the release of dust particles which, acute, may
cause irritation of eyes, nose or throat and chronic, may result in lung disease (Silicosis) if exposed for prolonged time.
Carcinogenicity:
NTP?
IARC Monographs?
OSHA Regulated?
No
No
No
Signs and Symptoms of Exposure: Irritation of eyes, nose and throat or shortness of breath.
Medical Conditions Generally Aggravated by Exposure: Pre -existing lung disease such as Emphysema
or Asthma.

Emergency First Aid Procedures: Irrigate eyes generously with clean water for 15 minutes. If irritation persists call a
physician.

Section VI - Reactivity Data
Stability Conditions To Avoid
Stable
None
Materials To Avoid: None
Hazardous Decomposition Products: None
Hazardous Polymerization
Conditions To Avoid
Will Not Occur
None

Section VII - Spill Or Leak Procedures
Steps To Be Taken In Case Material Is Released Or Spilled: Sweep up and properly dispose.
Waste Disposal Method: Dispose as common waste.
Precautions To Be Taken in Handling and Storing: None
Other Precautions: Wear NIOSH approved respirator and tight fitting goggles. When dry sawing or grinding, or saw and
grind when wet.

Section VIII - Special Protection Information
Control Measures (When Sawing or Grinding)
Respiratory Protection (Type): NIOSH Approved Particulate Respirator
Ventilation: Mechanical (General) in Confined Area
Protective Gloves: When Required
Eye Protection: Tight Fitting Goggles
Other Protective Equipment: None
Work/Hygienic Practices: N/A

Section IX - Special Precautions
Precautions To Be Taken In Handling And Storing: None

This information is given in good faith, but no warranty expressed or implied is made. Our company believes that it is accurate to the best of its knowledge
and relates only to the specific material designated herein.

ORTHO® Home Defense® MAX™ Perimeter & Indoor Insect Killer RTU Pull'N Spray

Page 1 of 4

MATERIAL SAFETY DATA SHEET
DATE PREPARED:07/08/2004
MSDS No:7202

1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ORTHO® Home Defense® MAX™ Perimeter & Indoor Insect Killer RTU Pull'N Spray
PRODUCT DESCRIPTION: Insecticide

MANUFACTURER
The ORTHO Group
P.O. Box 190
Marysville, OH 43040

24 HR. EMERGENCY TELEPHONE NUMBERS
CHEMTREC (U.S.):
Emergency Phone:

(800) 424-9300
1-800-225-2883

EPA REG. NO.: 239-2663D PN: 6061

2. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name
Bifenthrin
Other Ingredients

Wt.%
0.05
99.95

CAS#
82657-04-3

3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
IMMEDIATE CONCERNS:
CAUSES MODERATE EYE IRRITATION
AVOID CONTACT WITH EYES OR CLOTHING
KEEP OUT OF REACH OF CHILDREN
POTENTIAL HEALTH EFFECTS
EYES: This substance may cause moderate eye irritation. See Toxicological Information, section 11.
SKIN: This substance is not expected to cause skin irritation and is only slightly toxic if absorbed through the skin. See
Toxicological Information, section 11.
INGESTION: This substance is slightly toxic if swallowed. The degree of injury will depend on the amount absorbed from the gut.
See Toxicological Information, Section 11.
INHALATION: Overexposure to the spray mist may be irritating to the respiratory tract. If inhaled, this substance is considered
practically non-toxic to internal organs. See Toxicological Information, section 11.

4. FIRST AID MEASURES
EYES: Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5
minutes, then continue rinsing eyes. Call a poison control center or doctor for treatment advice.
SKIN: If on skin or clothing, take off contaminated clothing. Rinse skin immediately with plenty of water for 15 to 20 minutes. Call a
poison control center or doctor for treatment advice.
INGESTION: If swallowed, call a poison control center or doctor immediately for treatment advice. Have person sip glass of water if
able to swallow. Do not induce vomiting unless told to by a poison control center or doctor. Never give anything by mouth to an
unconscious person.
INHALATION: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration,
preferably by mouth-to-mouth, if possible. Call a poison control center or doctor for further treatment advice.

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COMMENTS: See product label for specific First Aid Measures. The above measures are the most conservative - Pesticide
Registration (PR) Notice 2001-1, January 2, 2001, and would apply in the event a product label is not immediately available.

5. FIRE FIGHTING MEASURES
FLASHPOINT AND METHOD: None
EXTINGUISHING MEDIA: Use CO2, Dry Chemical or Foam extinguishing media.
HAZARDOUS COMBUSTION PRODUCTS: Heating this material may generate carbon monoxide, carbon dioxide, hydrogen
chloride and hydrogen fluoride.
FIRE FIGHTING PROCEDURES: Products of combustion from fires involving this material may be toxic. Avoid breathing smoke
and mists. Avoid personnel and equipment contact with fallout and runoff. Minimize the amount of water used for fire fighting. Do
not enter any enclosed area without full protective equipment, including self-contained breathing equipment. Contain and isolate
runoff and debris for proper disposal. Decontaminate personal protective equipment and fire fighting equipment before reuse. Read
the entire document.

6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: While wearing rubber gloves, soak up spilled material with paper towels and discard in trash.
LARGE SPILL: Dike or contain release. Keep material out of lakes, streams, ponds, and sewer drains. Large spills should be covered
to prevent dispersal. Absorb with a non-combustible absorbent such as clay, sand or soil. Vacuum, shovel, or pump all waste
material, including absorbent, into drums and label contents for disposal. Clean spill area of residues and absorbent.
GENERAL PROCEDURES: Observe all protection and safety precautions when cleaning up spills -- see Section 8. "EXPOSURE
CONTROLS/PERSONAL PROTECTION".

7. HANDLING AND STORAGE
GENERAL PROCEDURES: Store this product only in its original container in a secured storage area. Protect container from
freezing.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS: No special ventilation is necessary under normal product use conditions. However, if workplace
operating conditions create high airborne concentrations of the material, special ventilation may be needed to reduce levels below
OSHA exposure limits.
PERSONAL PROTECTION
EYES AND FACE: For application of product in accordance with label instructions, no special eye protection is needed. Handling
of this product during manufacturing or in the event of an accidental discharge of the material which could cause eye contact,
workers should wear goggles or a face shield.
SKIN: Follow label precautions for skin protection. Avoid contact with skin and clothing. Wash thoroughly with soap and water
after handling. Remove contaminated clothing and wash before reuse.
RESPIRATORY: Avoid breathing vapor or mist. This product is not likely to pose an airborne exposure concern when handled
and used in accordance with label instructions.
OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200):
Chemical Name
Bifenthrin

OSHA PEL
None

EXPOSURE LIMITS
ACGIH TLV
ACGIH STEL
None
None

9. PHYSICAL AND CHEMICAL PROPERTIES

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PHYSICAL STATE: Liquid
APPEARANCE: Clear to cloudy white liquid
pH: ~7.0 to 7.3
SOLUBILITY IN WATER: Miscible with water.
DENSITY: 8.32 Lbs/gal at 20°C

10. STABILITY AND REACTIVITY
STABLE: YES
HAZARDOUS POLYMERIZATION: NO
CONDITIONS TO AVOID: DO NOT APPLY THIS PRODUCT IN OR ON ELECTRICAL EQUIPMENT DUE TO THE
POSSIBILITY OF SHOCK HAZARD.

11. TOXICOLOGICAL INFORMATION
ACUTE
EYES: Rabbit - moderately irritating, irritation cleared by 48 hours. EPA FIFRA toxicity category - lll.
DERMAL LD50: Rat = >10 g/kg. EPA FIFRA toxicity category - IV. SKIN IRRITATION: Rabbit - nonirritating, contact with
bifenthrin may produce reversible skin sensations such as numbness, burning and tingling. The skin sensations usually subside
within 12 hours. EPA FIFRA toxicity category - IV.
ORAL LD50: Rat = > 5 g/kg. EPA FIFRA toxicity Category - IV.
INHALATION LC50: Rat - 4 hour inhalation = > 5.0 mg/liter. EPA FIFRA toxicity category - IV.
SENSITIZATION: Guinea pig - no evidence of allergic skin reactions.
CHRONIC: CARCINOGENICITY : Mouse lifetime feeding study - high dose males - demonstrated an increase in urinary bladder
hemangiopericytomas. There was no evidence of increased tumors in the other male or female mice dose levels. The mouse no
observed effect level (NOEL) was male 75 mg/kg/dy, female 90 mg/kg/dy. Rat lifetime feeding study - no findings of tumors. The
rat NOEL was 10 mg/kg/dy. EPA classified bifenthrin - Group C carcinogen.
NEUROTOXICITY: Bifenthrin has not been associated with delayed peripheral neuropathy. Overexposure to pyrethroids results in a
transient disruption in the depolarization of nerve membranes by interfering with the closing of the sodium channels. Depending
upon the degree of overexposure, signs of overexposure may be displayed by tremors, muscle fasciculations, ataxia, spasms,
hyperexcitability, hyperactivity and convulsions. Localized skin contact with bifenthrin may result in temporay burning, tingling or
numbness sensations.
TERATOGENICITY: Bifenthrin is not considered to be a teratogen (a substance that causes birth defects). The rat and rabbit
developmental NOELs were 1 and 8 mg/kg/dy, respectively.
REPRODUCTIVE TOXIN: Bifenthrin is not considered to cause adverse reproductive effects. Results of a rat multigeneration
reproduction study indicated no developmental toxicity or reproductive effects at the highest dose level of approximately 15
mg/kg/dy. The maternal toxicity NOEL was approximately 5 mg/kg/dy.
MUTAGENICITY: The results of a series of mutation testing indicate that bifenthrin has a low order of mutagenic potential.

12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: In soil, bifenthrin is stable over a wide pH range and degrades at a slow rate which is governed by soil
characteristcs. Bifenthrin will also persist in aquatic sediments. Bifenthrin has a high Log Pow (>6.0), a high affinity for organic
matter, and is not mobile in soil. Therefore, there is little potential for movement into ground water. There is the potential for
bifenthrin to bioconcentrate (BCF = 11,750).
ECOTOXICOLOGICAL INFORMATION: This pesticide is extremely toxic to fish and aquatic invertebrates. Do not apply directly
to water. Drift and runoff from treated areas may be hazardous to aquatic organisms in neighboring areas. Care should be used when
spraying to avoid fish and reptile pets in/around ornamental ponds. This product is highly toxic to bees exposed to direct treatment
on residues on blooming plants. Do not apply this product or allow it to drift to blooming plants if bees are visiting the treatment
area.

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13. DISPOSAL CONSIDERATIONS
FOR LARGE SPILLS: Material collected that cannot be reprocessed should be disposed of in a landfill approved for pesticide
disposal or in accordance with applicable Federal, state, or local procedures.
PRODUCT DISPOSAL: Call local solid waste agency or 1-800-CLEANUP for disposal instructions. Never place unused product
down any drain.

14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: Not Regulated
U.S. SURFACE FREIGHT CLASS: Insecticides, Fungicides, Insect or animal repellents or vermin exterminators, NOI, Other
than poison
SPECIAL SHIPPING NOTES: The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate
Dangerous Goods Regulations, for additional description requirements (e.g., technical name) and mode-specific or quantity-specific
shipping requirements.

15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
PRODUCT CLASSIFICATION UNDER SECTION 311 OF SARA
ACUTE: YES

CHRONIC: NO

FIRE: NO

REACTIVITY: NO

PRESSURE GENERATING: NO

STATE REGULATIONS
CALIFORNIA PROPOSITION 65: No ingredients on list.
GENERAL COMMENTS: Contact local authorities for disposal of large quantities of unused product.

16. OTHER INFORMATION
HMIS CODES
FLAMMABILITY: 0
NFPA CODES
FIRE: 0 HEALTH: 1

HEALTH: 1

PHYSICAL HAZARD: 0

REACTIVITY: 0

APPROVAL DATE: 07/08/2004
REVISION SUMMARY New MSDS
ADDITIONAL MSDS INFORMATION: NFPA/HMIS Hazard Rating: 0=Least; 1=Slight; 2=Moderate; 3=High; 4=Severe.
COMMENTS: Use of this product is regulated by the U.S. Environmental Protection Agency (EPA) through the approved product
label. It is a violation of Federal law to use this product in a manner inconsistent with its labeling.
MANUFACTURER DISCLAIMER: The information contained herein is, to the best of the Manufacturer's (see Section 1)
knowledge and belief, accurate and reliable as of the date of preparation of this document. However, no warranty or guarantee,
express or implied, is made as to the accuracy or reliability, and the Manufacturer shall not be liable for any loss or damage arising
out of the use thereof. No authorization is given or implied to use any patented invention without a license. In addition, the
Manufacturer shall not be liable for any damage or injury resulting from abnormal use, from any failure to adhere to recommended
practices or from any hazards inherent in the nature of the product.

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MATERIAL SAFETY DATA SHEET
S00857
01 00
===========================================================================
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
--------------------------------------------------------------------------PRODUCT NUMBER
HMIS CODES
Health
2
S00857
Flammability
2
Reactivity
0
PRODUCT NAME
SPRAYON® BLAST'EM® Wasp & Hornet Killer
MANUFACTURER'S NAME
EMERGENCY TELEPHONE NO.
THE SHERWIN-WILLIAMS COMPANY
(216) 566-2917
Consumer Group - Industrial
Cleveland, OH 44115
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
21-MAY-07
(800) 251-2486
===========================================================================
Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
--------------------------------------------------------------------------91
64742-47-8 Heavy Aliphatic Solvent
ACGIH TLV Not Available
0.2 mm
OSHA PEL Not Available
5
67-63-0 2-Propanol
ACGIH TLV
400 ppm
33 mm
ACGIH TLV
500 ppm STEL
OSHA PEL
400 ppm
OSHA PEL
500 ppm STEL
0.5
51-03-6 Piperonyl Butoxide
ACGIH TLV Not Available
OSHA PEL Not Available
0.3
52645-53-1 Permethrin
ACGIH TLV Not Available
OSHA PEL Not Available
2
124-38-9 Carbon Dioxide
ACGIH TLV
5000 ppm
760 mm
OSHA PEL
5000 ppm
===========================================================================
Section 3 -- HAZARDS IDENTIFICATION
--------------------------------------------------------------------------ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.

Continued on page 2

S00857
page 2
===========================================================================
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Prolonged or frequent repeated skin contact may cause allergic reactions
in some individuals.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
===========================================================================
Section 4 -- FIRST AID MEASURES
--------------------------------------------------------------------------EYES:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 -- FIRE FIGHTING MEASURES
--------------------------------------------------------------------------FLASH POINT
LEL
UEL
165 °F PMCC
0.7
12.7
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.
===========================================================================
Section 6 -- ACCIDENTAL RELEASE MEASURES
--------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
===========================================================================
Section 7 -- HANDLING AND STORAGE
--------------------------------------------------------------------------This product is toxic to fish. Do not allow product to enter
groundwater, streams, lakes or ponds. Do not contaminate water by cleaning
of equipment or disposal of wastes.
STORAGE CATEGORY
Not Available

Continued on page 3

S00857
page 3
===========================================================================
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat and open flame.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
===========================================================================
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
--------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
Do not use in commercial food/feed handling establishments, restaurants
or other sites where food/feed is commercially prepared or processed. Do
not use in Federally Inspected meat and poultry plants.
Do not allow children or pets to contact treated surfaces until spray
has dried. Do not spray air in rooms or use on plants. Avoid spraying
vegetation directly. Apply as a surface spray only. Do not spray to
contact food, feedstuffs or water supplies. Thoroughly wash dishes and
food-handling utensils contaminated with this product. Remove pets and
cover fish bowls before spraying.
Do not contaminate water, food or feed by storage or disposal. Do not
store near heat or open flame. Store in cool area away from children.
It is a violation of Federal law to use this product in a manner
inconsistent with its labeling. Read entire label.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
PROTECTIVE GLOVES
Wear chemical-resistant gloves to prevent skin contact.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
===========================================================================
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
--------------------------------------------------------------------------PRODUCT WEIGHT
6.54 lb/gal
783 g/l
SPECIFIC GRAVITY
0.79
BOILING POINT
<0 - 500 F
<-18 - 260 C
MELTING POINT
Not Available
VOLATILE VOLUME
99 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical)
Volatile Weight 96.65 % Less Water and Federally Exempt Solvents

Continued on page 4

S00857
page 4
===========================================================================
Section 10 -- STABILITY AND REACTIVITY
--------------------------------------------------------------------------STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
===========================================================================
Section 11 -- TOXICOLOGICAL INFORMATION
--------------------------------------------------------------------------CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
--------------------------------------------------------------------------TOXICOLOGY DATA
CAS No.
Ingredient Name
--------------------------------------------------------------------------64742-47-8
Heavy Aliphatic Solvent
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
67-63-0
2-Propanol
LC50
RAT
4HR
Not Available
LD50
RAT
5045
mg/kg
51-03-6
Piperonyl Butoxide
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
52645-53-1
Permethrin
LC50
RAT
4HR
Not Available
LD50
RAT
410
mg/kg
124-38-9
Carbon Dioxide
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
===========================================================================
Section 12 -- ECOLOGICAL INFORMATION
--------------------------------------------------------------------------ENVIRONMENTAL HAZARDS
This product is toxic to fish and aquatic invertebrates. Do not apply
directly to water.
ECOTOXICOLOGICAL INFORMATION
No data available.
===========================================================================
Section 13 -- DISPOSAL CONSIDERATIONS
--------------------------------------------------------------------------WASTE DISPOSAL METHOD
Waste from this product is not hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.

Continued on page 5

S00857
page 5
===========================================================================
Section 14 -- TRANSPORT INFORMATION
--------------------------------------------------------------------------US Ground (DOT)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, 2.2, LIMITED QUANTITY, (ERG#126)
Canada (TDG)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, CLASS 2.2, LIMITED QUANTITY, (ERG#126)
IMO
May be shipped as Limited Quantity
UN1950, AEROSOLS, CLASS 2, LIMITED QUANTITY, EmS F-D, S-U
===========================================================================
Section 15 -- REGULATORY INFORMATION
--------------------------------------------------------------------------SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
No ingredients in this product are subject to SARA 313 (40 CFR 372.65C)
Supplier Notification.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
===========================================================================
Section 16 -- OTHER INFORMATION
--------------------------------------------------------------------------This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

MATERIAL SAFETY DATA SHEET
Date stamp:

MSDS Ref. No.:

01-Sep-2005

Revision Number: 5

011771025

1. PRODUCT AND COMPANY IDENTIFICATION
Product name:
Description:

ORTHO Indoor Insect Fogger
Insecticide
24-HOUR EMERGENCY TELEPHONE NUMBERS:
CHEMTREC (U.S.): 1-800-424-9300
CHEMTREC (International): 1-703-527-3887
Non-Emergency Calls: 1-937-644-0011

Company
The Scotts Company
14111 Scottslawn Road
Marysville, OH 43041
EPA Registration No.: 239-2626
Formula No.: S1112

2. HAZARDS IDENTIFICATION
Labelling
Signal word:
Precautionary Statement

CAUTION.
Causes substantial but temporary eye injury. Do not get in eyes. Wear safety glases. Wear goggles.
Harmful if absorbed through the skin. Avoid contact with eyes, skin, and clothing. Wash with soap and
water after handling. Keep out of reach of children.

Potential health effects
Eye contact:
Skin contact:
Ingestion:
Inhalation:

Irritating to eyes.
Irritation not expected.
Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea.
May cause irritation of respiratory tract.

Aggravated Medical Conditions:
Principle routes of exposure:
Target organ effects:

Inhalation may aggravate asthma.
Skin, Eyes, Inhalation
Irritation.

3. COMPOSITION/INFORMATION ON INGREDIENTS
Components
Natural Pyrethrine
Permethrin
MGK 264, N-octyl bicycloheptene dicarboximide
Inert Ingredients

CAS-No
8003-34-7
52645-53-1
113-48-4
PROPRIETARY

Weight %
0.05
0.4
0.4
99.115

4. FIRST AID MEASURES
Eye contact:

Hold eye open and rins slowly and gently with water for 15-20 minutes. Remove contact lenses, if present
after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment
advice

Skin contact:

Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a
poison control center or doctor for treatment advice

Ingestion:

Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if
able to swallow. Do not induce vomiting unless told to do so be a poison control center or doctor. Do not
give anything by mouth to an unconscious person

Inhalation:

Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial
respiration, preferabley by mouth-to-mouth, if possible. Call a poison control center or doctor for further
treatment advice

5. FIRE-FIGHTING MEASURES
Flammable properties:
Suitable extinguishing media:
Explosion potential:
Explosive properties:

Revision date: 10-May-2005

Flammable aerosol. N.F.P.A. (Code 30B) Level I Aerosol.
Water spray, carbon dioxide, dry chemical, chemical foam.
Closed containers may rupture violently under fire conditions.
Heating may cause an explosion..

Page 1 of 4

MSDS Ref. No.:

ORTHO Indoor Insect Fogger

011771025

_______________________________________________________________________________________________
Hazardous combustion products:
Fire fighting procedures:
Special protective equipment for
firefighters:
Flammability Limits in Air:

Toxic fumes may be produced.
Select appropriate method to surround and extinguish fire. Flood with water to cool containers.
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or
equivalent) and full protective gear.
No information available

6. ACCIDENTAL RELEASE MEASURES
Personal precautions:
Environmental precautions:
Methods for containment:
Methods for cleaning up:

Wear personal protective equipment
Prevent product from entering drains
Control spill with dykes and absorb with inert absorbant material
Detergent and water.

7. HANDLING AND STORAGE
Handling: Avoid container breakage. Avoid inhalation or contact with skin, eyes, or clothing. Do not use near heat. Do not use near an ignition source.
Do not puncture or incinerate.
Storage: Store in a cool, dry area away from incompatible materials and heat sources.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Components
Natural Pyrethrine
Permethrin
MGK 264, N-octyl bicycloheptene
dicarboximide
Engineering controls

ACGIH:
5 mg/m³ TWA
Not Listed
Not Listed

OSHA:
5 mg/m³ TWA
Not Listed
Not Listed

Use adequate ventilation to keep the airborne concentrations of this material below the recommended
exposure standard

Personal Protective Equipment
Eye/face protection:
Skin and body protection:
Respiratory protection:

General hygiene considerations:

Eye/face protection is not required, but is recommended in manufacturing situations where contact may
occur. Safety glasses with side shields or goggles. Face-shield.
No special protective clothing is required under normal workplace conditions. Wear suitable protective
clothing if contact is anticipated during manufacturing.
If airborne levels are high or product does not remain intact, use a combination of engineering controls
(e.g. ventilation) and personal protection (e.g. NIOSH/MSHA approved respirator for dusts, mists, and
fumes.
Remove and wash contaminated clothing before re-use. Wash hands before breaks and immediately after
handling the product..

9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State:
Color:
Solubility:
Density:
Method:

Appearance:
Odor:
Specific gravity:
Flash point:

Liquid
Light yellow
Miscible
8.13 lbs/gal
TAG CC

clear
solvent
0.975
165° F

10. STABILITY AND REACTIVITY
Chemically Stable:
Conditions to avoid:
Materials to avoid:
Hazardous decomposition products:
Possibility of hazardous reactions:

Yes
Temperatures above 130F.
Oxidising agents (strong).
Toxic fumes and gases may be generated.
Poses little or no immediate hazard.

11. TOXICOLOGICAL INFORMATION
Acute toxicity

Revision date: 10-May-2005

Page 2 of 4

MSDS Ref. No.:

ORTHO Indoor Insect Fogger

011771025

_______________________________________________________________________________________________
LD50/oral: >5 g/kg, rat
LD50/dermal: >5 g/kg, rabbit
LC50/inhalation: >5.98 mg/L, (vapor), rat
Eye effects: Mild eye irritation, rabbit
Skin effects: Mild skin irritation, rabbit
Sensitization: No sensitization, guinea pig
Chronic toxicity
Carcinogenic effects:

The table below indicates whether each agency has listed any indgredient as a carcinogen.

Components
Natural Pyrethrine
Permethrin
MGK 264, N-octyl bicycloheptene
dicarboximide
Ingestion:
Inhalation:
Target organ effects:

NTP:
Not listed
Not listed
Not listed

IARC:
Not listed
3
Not listed

OSHA:
Not listed
Not listed
Not listed

Ingestion may cause irritation to mucous membranes.
Possible irritation of the respiratory tract.
Irritation.

12. ECOLOGICAL INFORMATION
Ecotoxicity effects:
Persistence and degradability:
Bioaccumulative potential:
Mobility:
Aquatic toxicity:

Toxic to aquatic organisms.
Inherently biodegradable.
No information available.
Water contaminating.
No information available.

13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods:
Contaminated packaging:

If partially filled, call the local solid waste agency or 1-800-CLEANUP for disposal instructions. Do not
place product down any indoor or outdoor drain.
If empty, place in trash or offer for recycling if available.

14. TRANSPORT INFORMATION
The description shown may not apply to all situations. Consult 49 CFR, or appropriate dangerous goods regulations for additional description
requirements (e.g. technical name) and mode-specific or quantity-specific shipping requirements.
DOT
Proper shipping name:

Consumer Commodity, ORM-D

15. REGULATORY INFORMATION
Natural Pyrethrine

Components

CAS-No
8003-34-7

Permethrin
MGK 264, N-octyl bicycloheptene dicarboximide

52645-53-1
113-48-4

General Information

CERCLA/SARA 313
0.454 kg final RQ
1 lb final RQ
1 lb final RQ
Not Listed
Not Listed

CERCLA/SARA 302
Not Listed

Not Listed
Not Listed

Contact local authorities for disposal of large quantities of product

16. OTHER INFORMATION
NFPA:

Health: 1

Flammability: 4

Reactivity: 0

HMIS:

Health: 1

Flammability: 4

Reactivity: 1

Hazard Rating: 0=Least; 1-Slight; 2=Moderate; 3=High; 4=Severe

Revision date: 10-May-2005

Page 3 of 4

MSDS Ref. No.:

ORTHO Indoor Insect Fogger

011771025

_______________________________________________________________________________________________
EPA FIFRA Comment: Use of this product is regulated by the U.S. Environmental Protection Agency (EPA) through the approved product label. It is a
violation of Federal law to use this product in a manner inconsistent with its labeling.

General comment: This document contains health, safety, and environmental information useful to emergency response agencies, health care
providers, manufacturers, and workers/employees. It does not replace the precautionary language, use directions, or the storage and disposal
information found on the product label.
Revision date:

10-May-2005

Additional Information: This information contained herein is, to the best of Scott's knowledge and belief, accurate and reliable as of the date of
preparation of this document. However, no warranty or guarantee, express or implied, is made as to the accuracy or reliability, and Scotts shall not be
liable for any loss or damage arising out of the use thereof. No authorization is given or implied to use any patented invention without a license. In
addition, Scotts shall not be liable for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices or from
any hazards inherent in the nature of the product.

Revision date: 10-May-2005

Page 4 of 4

S00859
01 00

MATERIAL SAFETY DATA SHEET

===========================================================================
Section 1 −− PRODUCT AND COMPANY IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT NUMBER
HMIS CODES
Health
2
S00859
Flammability
2
Reactivity
0
PRODUCT NAME
HIT SQUAD Industrial Insecticide
MANUFACTURER’S NAME
EMERGENCY TELEPHONE NO.
THE SHERWIN−WILLIAMS COMPANY
(216) 566−2917
Consumer Group − Industrial
Cleveland, OH 44115
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
04−JUN−03
(800) 251−2486
===========================================================================
Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
5
64741−65−7 Mineral Spirits (Odorless)
ACGIH TLV
100 ppm
1 mm
OSHA PEL
100 ppm
92
64742−47−8 Heavy Aliphatic Solvent
ACGIH TLV Not Available
0.1 mm
OSHA PEL Not Available
0.3
Proprietary Fenvalerate
ACGIH TLV Not Available
OSHA PEL Not Available
3
124−38−9 Carbon Dioxide
ACGIH TLV
5000 ppm
OSHA PEL
5000 ppm
===========================================================================
Section 3 −− HAZARDS IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
Irritation of eyes, skin and upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.

Continued on page 2

S00859
page 2
===========================================================================
Section 4 −− FIRST AID MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
If INHALED:

If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
If on SKIN:
Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re−use.
If in EYES:
Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
If SWALLOWED: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 −− FIRE FIGHTING MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
FLASH POINT
LEL
UEL
175 F TCC
1.0
8.8
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self−contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build−up and possible autoignition or explosion when exposed to
extreme heat.
===========================================================================
Section 6 −− ACCIDENTAL RELEASE MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
===========================================================================
Section 7 −− HANDLING AND STORAGE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ENVIRONMENTAL HAZARDS
This product is toxic to fish and aquatic invertebrates. Do not apply
directly to water.
STORAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat and open flame.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Store container upright to prevent leakage. Avoid storage near feed or
food products.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
Continued on page 3

S00859
page 3
===========================================================================
Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Do not spray to contact food, feedstuffs or water supplies. Thoroughly
wash dishes and food−handling utensils contaminated with this product.
It is a violation of Federal law to use this product in a manner
inconsistent with its labeling. Read entire label.
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
===========================================================================
Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT WEIGHT
6.68 lb/gal
800 g/l
SPECIFIC GRAVITY
0.80
BOILING POINT
<0 − 484 F
<−18 − 251 C
MELTING POINT
Not Available
VOLATILE VOLUME
99 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical)
Volatile Weight 96.50 % Less Water and Federally Exempt Solvents
===========================================================================
Section 10 −− STABILITY AND REACTIVITY
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STABILITY −− Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur

Continued on page 4

S00859
page 4
===========================================================================
Section 11 −− TOXICOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
TOXICOLOGY DATA
CAS No.
Ingredient Name
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
64741−65−7
Mineral Spirits (Odorless)
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
64742−47−8
Heavy Aliphatic Solvent
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
Proprietary
Fenvalerate
LC50
RAT
4HR
Not Available
LD50
RAT
451
mg/kg
124−38−9
Carbon Dioxide
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
===========================================================================
Section 12 −− ECOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ECOTOXICOLOGICAL INFORMATION
No data available.
===========================================================================
Section 13 −− DISPOSAL CONSIDERATIONS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
WASTE DISPOSAL METHOD
Waste from this product is not hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.
===========================================================================
Section 14 −− TRANSPORT INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
No data available.
===========================================================================
Section 15 −− REGULATORY INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
No ingredients in this product are subject to SARA 313 (40 CFR 372.65C)
Supplier Notification.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
Continued on page 5

S00859
page 5
===========================================================================
Section 16 −− OTHER INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
This product has been classified in accordance with the hazard criteria
of the CPR and the MSDS contains all of the information required by the
CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

PAGE 1 OF 2
PRODUCT CODE: MG-2, 4
MATERIAL SAFETY DATA SHEET
I. GENERAL INFORMATION
ENFORCER PRODUCTS, INC.
P. O. BOX 1060
CARTERSVILLE, GA. 30120

PRODUCT NAME:

MANUFACTURER’S PHONE NUMBER: (770) 386-0801
24 HOUR EMERGENCY NUMBER: 1-800-255-3924

HAZARD RATINGS:
HEALTH_0_ REACTIVITY_0_
FLAMMABILITY_0_
PERSONAL PROTECTION_0_
EPA REG. NO.: N/A

MOUSE GLUE TRAP

PREPARED BY: TRESSIE DEMPSEY

DATE: NOVEMBER 22, 1999

II. INGREDIENTS
PRINCIPAL COMPONENTS

CAS NUMBER

PERCENT

OSHA PEL

ACGIH TLV

OTHER

HAZARD

NONE

III. PHYSICAL DATA
BOILING POINT: NOT DETERMINED

SPECIFIC GRAVITY:

0.95 TO 1.08

VAPOR PRESSURE (mm Hg.): N/A

PERCENT VOLATILE BY VOLUME: N/A

VAPOR DENSITY: N/A

SOLUBILITY IN WATER: NOT SOLUBLE

APPEARANCE & ODOR: OFF-WHITE TO TAN COLORED TACKY SOLID WITH REINOUS
ODOR

EVAPORATION RATE (Butyl Acetate = 1): N/A

IV. FIRE & EXPLOSION DATA
FLASHPOINT (Method used): > 400°F

AUTOIGNITION TEMPERATURE: N/A

LEL: N/A

EXTINGUISHING MEDIA: WATER SPRAY, FOAM, DRY CHEMICAL

UEL: N/A

FLAMMABLE LIMITS: NOT DETERMINED

SPECIAL FIRE FIGHTING PROCEDURES:

WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES.

UNUSUAL FIRE & EXPLOSION HAZARDS:

DECOMPOSITION MAY PRODUCE SMOKE, HAZARDOUS CHEMICALS SUCH AS COx, NOx
AND OTHER UNKNOWN HAZARDOUS.

V. REACTIVITY HAZARD DATA
STABILITY: |X| STABLE
| | UNSTABLE

CONDITIONS TO AVOID: OVER-HEATING

INCOMPATABILITY (Materials to
avoid):
HAZARDOUS POLYMERIZATION:

OXIDIZING MATERIALS MAY CAUSE REACTION.
| | WILL OCCUR

| X | WILL NOT OCCUR

HAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF CARBON AND SMOKE.

CONDITIONS TO AVOID: NONE KNOWN

PAGE 2 OF 2
PRODUCT CODE: MG-2, 4
VI. HEALTH HAZARD DATA
PRIMARY ROUTES OF ENTRY:

INHALATION | |

INGESTION | |

SKIN ABSORPTION | |

EYE | |

NOT HAZARDOUS | X |

ACUTE EFFECTS OF OVEREXPOSURE:
INGESTION:

NONE

SKIN CONTACT:

NONE

INHALATION:

NONE

EYE CONTACT:

NONE

CHRONIC EFFECTS OF OVEREXPOSURE:
CARCINOGENICITY:

NONE

NTP? N/A

IARC? N/A

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:

OSHA REGULATED? N/A

NONE KNOWN.

EMERGENCY FIRST AID PROCEDURES:
INGESTION:

FREE THROAT FROM BLOCKAGE.

SKIN CONTACT:

WASH WITH SOAP AND WATER.

INHALATION:

GET FRESH AIR.

EYE CONTACT:

FLUSH WITH WATER.

VII. CONTROL AND PROTECTIVE MEASURES
EYE PROTECTION:

NONE

RESPIRATORY PROTECTION (specify):

NONE

SKIN PROTECTION:

NONE

VENTILATION:

NONE

OTHER PROTECTION:

NONE

VIII. SPECIAL PRECAUTIONS
HANDLING AND STORING PROCEDURES:

NONE

RELEASE OR SPILL PROCEDURES:

SWEEP UP AND PLACE IN A CONTAINER FOR DISPOSAL.

WASTE DISPOSAL METHOD:

DISPOSE OF AS A SOLID WASTE.

OTHER PRECAUTIONS:

KEEP THIS AND ALL CHEMICALS OUT OF REACH OF CHILDREN AND PETS.

IX. ADDITIONAL INFORMATION
PROPER DOT SHIPPING NAME:

DEVICE, NOS (NOT DOT / IMO REGULATED)

BIODEGRADABILITY:

NOT BIODEGRADABLE

LEAK PROCEDURES:

NOT LIKELY, A RESINOUS SOLID.

THIS INFORMATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200.
********************** END OF REPORT **********************

PAGE 1 OF 2
PRODUCT CODE: RG-2
MATERIAL SAFETY DATA SHEET
I. GENERAL INFORMATION
ENFORCER PRODUCTS, INC.
P. O. BOX 1060
CARTERSVILLE, GA. 30120

PRODUCT NAME:

MANUFACTURER’S PHONE NUMBER: (770) 386-0801
24 HOUR EMERGENCY NUMBER: 1-800-255-3924

HAZARD RATINGS:
HEALTH_0_ REACTIVITY_0_
FLAMMABILITY_0_
PERSONAL PROTECTION_0_
EPA REG. NO.: N/A

ENFORCER RAT AND MOUSE GLUE TRAP

PREPARED BY: TRESSIE DEMPSEY

DATE: NOVEMBER 22,1999

II. INGREDIENTS
PRINCIPAL COMPONENTS

CAS NUMBER

PERCENT

OSHA PEL

ACGIH TLV

OTHER

HAZARD

NONE

III. PHYSICAL DATA
BOILING POINT: NOT DETERMINED

SPECIFIC GRAVITY:

0.95 TO 1.08

VAPOR PRESSURE (mm Hg.): N/A

PERCENT VOLATILE BY VOLUME: N/A

VAPOR DENSITY: N/A

SOLUBILITY IN WATER: NOT SOLUBLE

APPEARANCE & ODOR: OFF-WHITE TO TAN COLORED TACKY SOLID WITH RESINOUS
ODOR.

EVAPORATION RATE (Butyl Acetate = 1): N/A

IV. FIRE & EXPLOSION DATA
FLASHPOINT (Method used): > 400°F (COC)

AUTOIGNITION TEMPERATURE: N/A

LEL: N/A

EXTINGUISHING MEDIA: WATER SPRAY, FOAM, DRY CHEMICAL

UEL: N/A

FLAMMABLE LIMITS: NOT DETERMINED

SPECIAL FIRE FIGHTING PROCEDURES:

WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES.

UNUSUAL FIRE & EXPLOSION HAZARDS:

DECOMPOSITION MAY PRODUCE SMOKE, HAZARDOUS CHEMICALS SUCH AS COx, NOx
AND OTHER UNKNOWN HAZARDOUS SUBSTANCES.

V. REACTIVITY HAZARD DATA
STABILITY: |X| STABLE
| | UNSTABLE

CONDITIONS TO AVOID: OVER-HEATING

INCOMPATABILITY (Materials to avoid):

OXIDIZING MATERIALS MAY CAUSE REACTION.

| X | WILL NOT
OCCUR
HAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF CARBON AND SMOKE.
HAZARDOUS POLYMERIZATION:

| | WILL OCCUR

CONDITIONS TO AVOID: NONE KNOWN

PAGE 2 OF 2
PRODUCT CODE: RG-2
VI. HEALTH HAZARD DATA
PRIMARY ROUTES OF ENTRY:

INHALATION | |

INGESTION | |

SKIN ABSORPTION | |

EYE | |

NOT HAZARDOUS | X |

ACUTE EFFECTS OF OVEREXPOSURE:
INGESTION:

NONE

SKIN CONTACT:

NONE

INHALATION:

NONE

EYE CONTACT:

NONE

CHRONIC EFFECTS OF OVEREXPOSURE:
CARCINOGENICITY:

NONE

NTP? N/A

IARC? N/A

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:

OSHA REGULATED? N/A

NONE KNOWN.

EMERGENCY FIRST AID PROCEDURES:
INGESTION:

FREE THROAT FROM BLOCKAGE.

SKIN CONTACT:

WASH WITH SOAP AND WATER.

INHALATION:

GET FRESH AIR.

EYE CONTACT:

FLUSH WITH WATER.

VII. CONTROL AND PROTECTIVE MEASURES
EYE PROTECTION:

NONE

RESPIRATORY PROTECTION (specify):

NONE

SKIN PROTECTION:

NONE

VENTILATION:

NONE

OTHER PROTECTION:

NONE

VIII. SPECIAL PRECAUTIONS
HANDLING AND STORING PROCEDURES:

NONE

RELEASE OR SPILL PROCEDURES:

SWEEP UP AND PLACE IN A CONTAINER FOR DISPOSAL.

WASTE DISPOSAL METHOD:

DISPOSE OF AS A SOLID WASTE.

OTHER PRECAUTIONS:

KEEP THIS AND ALL CHEMICALS OUT OF REACH OF CHILDREN AND PETS.

IX. ADDITIONAL INFORMATION
PROPER DOT SHIPPING NAME:

DEVICE, NOS (NOT DOT / IMO REGULATED)

BIODEGRADABILITY:

NOT BIODEGRADABLE

LEAK PROCEDURES:

NOT LIKELY, A RESINOUS SOLID.

THIS INFORMATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200.
********************** END OF REPORT **********************

Material Safety Data Sheet
Calcium hypochlorite, available chlorine >65%
ACC# 03990

Section 1 - Chemical Product and Company Identification
MSDS Name: Calcium hypochlorite, available chlorine >65%
Catalog Numbers: AC199030010, AC199030200, AC300340000, AC300340010, AC300340050,
AC300341000, S79945, C100-250, C100-500
Synonyms: Calcium oxychloride; losantin; Hypochlorous acid; Calcium salt; Lime chloride
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887

Section 2 - Composition, Information on Ingredients
CAS#
7778-54-3

Chemical Name
Calcium hypochlorite

Percent

EINECS/ELINCS

100

231-908-7

Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Appearance: white crystalline powder.
Danger! Strong oxidizer. Contact with other material may cause a fire. Corrosive. Causes eye
and skin burns. Harmful if swallowed. Contact with acids liberates toxic gas. May cause severe
respiratory tract irritation with possible burns. May cause severe digestive tract irritation with
possible burns. Air sensitive.
Target Organs: Lungs, respiratory system, eyes, skin, mucous membranes.
Potential Health Effects
Eye: Causes eye burns. May result in corneal injury. May cause blindness. May cause blepharitis
(inflammation of the margins of the eyelids).
Skin: Causes severe burns with delayed tissue destruction.
Ingestion: Harmful if swallowed. May cause severe and permanent damage to the digestive tract.
May cause perforation of the digestive tract. Causes digestive tract burns with immediate pain,
swelling of the throat, convulsions, and possible coma. Ingestion of Calcium hypochlorite solutions
may cause death. As little as 1 ounce may be lethal if the available chlorine concentration exceeds
15%.
Inhalation: Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary
edema. May cause systemic effects. Causes corrosive action on the mucous membranes.
Chronic: Prolonged or repeated skin contact may cause dermatitis. Prolonged or repeated eye
contact may cause conjunctivitis. Effects may be delayed.

Section 4 - First Aid Measures
Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy
contaminated shoes.
Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or
water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air
immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If
breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in pressuredemand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact
with other material may cause fire. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Use water spray to keep fire-exposed
containers cool. Use water with caution and in flooding amounts. Contaminating or mixing with
foreign materials such as combustibles, grease, and fuels can cause fire. Containers may explode
when heated.
Extinguishing Media: Use water only! Do NOT use carbon dioxide or dry chemical. Contact
professional fire-fighters immediately. Cool containers with flooding quantities of water until well
after fire is out.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 3; Flammability: 0; Instability: 1; Special Hazard: OX

Section 6 - Accidental Release Measures
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up
spills immediately, observing precautions in the Protective Equipment section. Avoid generating
dusty conditions. Remove all sources of ignition. Provide ventilation. Do not get water inside
containers. Do not use combustible materials such as paper towels to clean up spill.

Section 7 - Handling and Storage
Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse.
Use only in a well-ventilated area. Minimize dust generation and accumulation. Do not get in eyes,

on skin, or on clothing. Keep container tightly closed. Keep away from heat, sparks and flame.
Avoid contact with clothing and other combustible materials. Do not ingest or inhale. Discard
contaminated shoes. Use only a clean, dry scoop made of metal or plastic each time product is
taken from container. Never use scoops containing remnants of other products as it may cause a
violent reaction leading to fire or an explosion.
Storage: Keep away from sources of ignition. Do not store near combustible materials. Do not
store in direct sunlight. Keep container closed when not in use. Store in a tightly closed container.
Keep away from acids.

Section 8 - Exposure Controls, Personal Protection
Engineering Controls: Facilities storing or utilizing this material should be equipped with an
eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations
low.
Exposure Limits
Chemical Name
Calcium hypochlorite

ACGIH
none listed

NIOSH

OSHA - Final PELs

none listed

none listed

OSHA Vacated PELs: Calcium hypochlorite: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's
eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI
Z88.2 requirements or European Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.

Section 9 - Physical and Chemical Properties
Physical State: Crystalline powder
Appearance: white
Odor: strong odor - chlorine-like
pH: 11.4 (1% aq. sol.)
Vapor Pressure: Not applicable.
Vapor Density: Not applicable.
Evaporation Rate:Not applicable.
Viscosity: Not available.
Boiling Point: Decomposes
Freezing/Melting Point:100 deg C
Decomposition Temperature:180 deg C
Solubility: Slightly soluble.
Specific Gravity/Density:2.350
Molecular Formula:CaCl2O2
Molecular Weight:142.9848

Section 10 - Stability and Reactivity

Chemical Stability: All hypochlorite solutions are unstable and slowly decompose on contact with
air. Calcium hypochlorite is corrosive to most metals and will evolve toxic chlorine and chlorine
monoxide gas when heated above 350°F. Sudden heating above 212°F may cause an explosion.
Pure, dry calcium hypochlorite is not sensitive to friction or impact. However, in the presence of
small amounts of water, it can decompose to form dangerously unstable dichlorine monoxide,
which is sensitive to friction, shock or static spark.
Conditions to Avoid: Ignition sources, dust generation, excess heat, moisture, high humidity.
Incompatibilities with Other Materials: Reducing agents, ammonia, iron oxide, phenols, sulfur,
aliphatic amines, acetylene, cyanides (e.g. potassium cyanide, sodium cyanide), sulfides
(inorganic, e.g. ferric sulfide, lead sulfide, sodium sulfide), carbontetrachloride, aromatic amines,
carbon, ammonium chloride, charcoal, glycerol, air, ethanol, menthol, rust, hydroxy compounds
(e.g. ethanol, ethylene glycol, gycerol, sugar), metal oxides, turpentine, diethylene glycol
monomethyl ether, acetic acid + potassium, N,N-dichloromethylamine + heat, 1-propanethiol,
isobutanethiol, sodium hydrogen sulfate + starch + sodium carbonate, combustible materials (e.g.
anthracene, grease, oil, mercaptans, methyl carbitol, nitromethane, organic matter, and
propylmercaptan).
Hazardous Decomposition Products: Hydrogen chloride, oxygen, chlorine, calcium hydroxide,
calcium carbonate, dichlorine monoxide, Calcium chlorate.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information
RTECS#:
CAS# 7778-54-3: NH3485000
LD50/LC50:
CAS# 7778-54-3:
Oral, rat: LD50 = 850 mg/kg;
.
Carcinogenicity:
CAS# 7778-54-3: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: Mutation in bacteria.
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information
Ecotoxicity: Fish: Striped bass: LC50 = 0.5 mg/L; 24 Hr; Static bioassay (70% hypochlorite)

Section 13 - Disposal Considerations
Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts
261.3. Additionally, waste generators must consult state and local hazardous waste regulations to

ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information
US DOT

Canada TDG

Shipping Name:

CALCIUM HYPOCHLORITE, DRY

CALCIUM HYPOCHLORITE, DRY

Hazard Class:

5.1

5.1

UN Number:

UN1748

UN1748

Packing Group:

II

II

Section 15 - Regulatory Information
US FEDERAL
TSCA
CAS# 7778-54-3 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 7778-54-3: 10 lb final RQ; 4.54 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 7778-54-3: immediate, fire.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7778-54-3 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7778-54-3 can be found on the following state right to know lists: California, New Jersey,
Pennsylvania, Massachusetts.
California Prop 65
California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
OCN
Risk Phrases:
R 22 Harmful if swallowed.
R 31 Contact with acids liberates toxic gas.
R 34 Causes burns.
R 8 Contact with combustible material may cause fire.
R 50 Very toxic to aquatic organisms.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
otection.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 61 Avoid release to the environment. Refer to special instructions
/safety data sheets.
WGK (Water Danger/Protection)
CAS# 7778-54-3: 2
Canada - DSL/NDSL
CAS# 7778-54-3 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of C, E.
This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List

Section 16 - Additional Information
MSDS Creation Date: 7/19/1999
Revision #7 Date: 5/16/2007
The information above is believed to be accurate and represents the best information currently available to us. However, we make
no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no
liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their
particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any
special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.

f

8RENNTAG~II_II.
BRENNTAG
MID-SOUTH,
INC.

MATERIAL SAFETY DATA SHEET

Effective

Date:

July 19, 2004

SODIUM
HYPOCHLORITE
SOLUTION
L

SECTIONI -MATERIAL mENTIFIC~TiON

MANUFACTURER'S

BRENNTAG

NAME & ADDRES~:

MID-SOUTH,

EMERGENCY

Inc.

TELEPHONE

.::J

NUMBER:

270-830-1222

1405 Highway 136 West / Geneva Road
Henderson, Kentucky 42420
CHEMICAL NAME AND SYNONYMS:
Sodium Hypochlorite Solution (10-14.2%); Hypochlorite Solution; Bleach Solution,
Hypochlorous acid, sodium salt, &/or AB Bleach; sodium hypochlorite/DIWater
CHEMICAL

FAMILY:

Hypochlorite

C'

FORMULA:

SECTION

n -HAZARDOUS

NaOCI

INGRED
THRESHOLD LIMIT VALUES (UNITS)
OSHA:
_1
ACGm:
PEL
J STEL I
TLV
1 STEL

CAS
NUMBER

CHEMICAL
NAME(S)

.WT
%

7681-52-9

Sodium hypochlorite**

10 -14.2

1310-73-2

Sodium hydroxide

0.3-1.0

7647-14-5

Sodium Chloride

9 -12.5

-NON

497-19-8

Sodium carbonate

::;0.5

-NONE

ESTABLISHED

-

7732-18-5

Water

Balance

-NONE

ESTABLISHED

-

-NON
2mgim3Ceiling

E EST

A B LIS

1

1

E EST

A B LIS

H ED -

2mgim3Ceiling
H ED

1

-

-

This product does not contain any chemical (5) subject to reporting requirements of Section 313, Title III of SARA, Part 372.
** %(w/w) as CI1 9.5 to 13.55% TL vrrw A (ACGIH) O.5ppm C11; TL V/STEL (ACGIH) Ippm CI1 & PEL (OSHA) Ippm CI1

CO
BOILING

SECTIONllI-PHYSICALDATA
POINT

of (OC): 110°Cfor15%NaOCI

I

SPECIFIC GRAVITY lH!O=l):

VAPOR DENSITY (AIR =1): n.a.

EVAPORATION

VAPOR PRESSURE (mmH2): Vapor pressure of
water plus decomposition products.

PERCENT VOLATILE

SOLU~ILITY

IN WATER:

Complete

APPEARANCE
...';'

l

SECTION

IV -FIRE

AND EXPLOSION

FLASH POINT (METHOD USED): Non -flammable
EXTINGUISHING

MEDIA:

.FLAMMABLE

RATE:

1.08-1.27

n.a.
BY VOLUME (%): Water vapor plus
decomposition products.

AND ODOR: Light, yellow-green liquid
with pungent-like chlorine odor.

HAZARD
LIMITS

D

(% BY VOLUME):

n.a.

Use water spray, fog, foam, dry chemicals, or carbon dioxide.

SPECIAL FIRE FIGHTING PROCEDURES: Firefighters'shouldwearprotectiveequipmentincluding self containedbreathingapparatus.
Avoid fumes. Dilute spill with copius amountsof water.ventilate. Be preparedto userespirator.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Possiblevigorous reactionupon contaminationwith organics or oxidizing agents.
Bleachdecomposeswhen heated,decompositionproductsmaycausecontainersto ruptureor explode. Many reactionscan causefire and explosion.
This material will reactwith somemetalswhich maycauseliberationof oxygen. Toxic fumescanbe liberated by contact with acid or heat.

C:\RDl\WORD\MSDS\MSSOHYPO.DOC

Page I of 5

FORMATREVISIONDATE: April 23. 2001

.';1:'

~j

BRENNTAG~II_I(~
BRENNTAG
MID-SOUTH,INC.

-

MATERIAL SAFETYDATA SHEET

Effective Date: July 19, 2004

SODIUM HYPOCHLORITE

SOLUTION

Vigorousreactionscanoccurwith oxidizablematerials
andorganics.Keepmaterialcool usinga watersprayfroma safedistance.Keepall
unnecessary
peopleaway. Stayup windandstayoutof low-lyingareas.

I

SECTION

V -HEAL

EFFECTS

TH HAZARD

DATA

I

OF OVEREXPOSURE:

PRECAUTIONARY STATEMENTS (Hazards
to humans
anddomesticanimals):Danger! Corrosive! May causesevereskin and eye
irritation or chemicalbums to brokenskin. Causeseyedamage.Exposureto skin may causesensitizationor other allergic responses.
INHALATION: Corrosive! Productmay causesevereirritation of the nose,throatand respiratorytract. Repeatedand/orprolonged
exposuresmay causeproductive cough, runny nose,bronchopneumonia,
pulmonaryedema(fluid build-up in lungs), and reductionof
pulmonaryfunction. Repeatedinhalationexposuremay causeimpairmentof lung functionand permanentlung damage.
EYE CONTACT: Extremelycorrosive! This productcausescornealscarringandclouding. Glaucoma,cataractsand permanent
blindnessmay occur.
SKIN CONTACT: Corrosive! Concentratedsolutionsmay causepain and deepandseverebums to the skin. Prolongedand
repeatedexposureto diluted solutions oftencausesirrita~ion,redness,pain anddrying andcracking of the skin. Human evidencehas
indicatedthat an ingredientin this productcancauseskin sensitization.
INGESTION: Corrosive! Will immediatelycauseseverecorrosionof and damageto the gastrointestinaltract. Exposure
characterizedby nausea,vomiting, diarrhea,abdominalpain, bleeding,and/ortissueulceration.
PRIMARY ROUTES OF ENTRY: Inhalationandcontact.
CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN: ~/No
* as Chlorine

~/No

OSHA/No ACGllI/A4*

EMERGENCY AND FIRST AID PROCEDURES:
INHALATION:

Removevictim to freshair. Give artificial respirationif not breathing. Get medicalattention.

EYE CONTACT: Washeyeswith plenty of waterfor at least15 minuteswhile holding eyelidsopen. Consultan eye specialist
immediately.
SKIN CONTACT: Flush skin with plenty of waterwhile removingcontaminatedclothing. Get medical attentionfor persistent
irritation. Cleanclothing before reuse.
INGESTION: If swallowed drink large quantitiesof water. Do NOT inducevomiting. Call a poison control centeror doctor
immediatelyfor treatmentadvice. If spontaneous
vomiting °£C.UfS,
have victim leanforward with head down to avoid breathing in of
vomitus,rinse mouthand administermore water.

I

SECTION

VI -TOXICOLOGICAL

INFO

TI

TOXICITY DATA:

Oral LD50: 8,910mgikg. (Rats)
Acute dermaltoxicity: III; LD50, > 3,000mgikg
Dermal LD 50: > 10,000mgikg.(Rabbits)
Primaryeye irritati9n: I; Corrosive
Inhalation 0.25-hourLC 50: >10.5 mg/l (Rats)
Primary skin irritation: I; Corrosive
Acute oral toxicity: IV; LD50, 192mgikg
SUMMARY: The concentratedsolution is corrosiveto skin, and a 5% solutionis a severeeye irritant. Solutionscontainingmore
than 5% availablechlorine are classified by DOT corrosive.Toxicity describedin animalsfrom single exposuresby ingestion
includesmuscularweakness,and hyperactivity. Repeatedingestionexposurein animalscausedan increasein the relative weight of
adrenalglands in one study,but no pathologicalchangewere observedin two otherstudies. Long-term administrationof compound
C:\RDI\WORD\MSDS\MSSOHYPO.DOC

Page2 of 5

FORMAT
REVISION
DATE:April23.2001

.BR~~NTA::

BRENNTAGMID-SOUTH, INC.

-

MATERIAL SAFETY DATA SHEET

Effective Date: July 19, 2004

SODIUM HYPOCHLORITE

SOLUTION

in drinking water of ratscauseddepressionof the immunesystem. No adversechangeswere observedin an eight-weekdermal study
of a 1% solution in guineapigs. Tests in animalsdemonstrateno carcinogenicactivity by eitherthe oral or dermalroutes. Tests in
bacterialand mammaliancell culturesdemonstratemutagenicactivity.
I

SECTION

VII

-ECOLOGICAL

INFORMATION

I

ENVIRONMENTAL HAZARDS: This pesticideis toxic to fish and aquaticorganisms.Do not dischargeeffluents containingthis
productinto lakes,streams,ponds,estuaries,oceansor otherwatersunlessin accordancewith the requirementsof a National
PollutantDischargeElimination System(NPDES)permit and the permitting authorityhas beennotified in writing prior to discharge.
Do not dischargeeffluent containingthis productto sewersystemswithout previouslynotifying the sewagetreatmentplant authority.
For guidance,contactyou State WaterBoard or RegionalOffice of the EPA.
Acute oral-bobwhitequail: LD50, > 2510mgikg
Acute dietary-mallardduck: LC50, > 5220 ppm
Acute dietary-bobwhitequail: LC50, > 5620ppm
Acute fish-rainbowtrout: LC50, 0.18-0.22mgil
Acute fish-bluegill sunfish: LC50, 0.44-0.79mgil
I

SECTION
STABILITY:

Acute invertebrate-daphnia:
LC50, 0.033-0.048mg/l
Fatheadminnows: 96-hourLC50, 5.9 mg/LO
RainbowTrout: 96-hourLC50, 0.2mg/liter
Bluegill sunfish: 96-hourLC50, 0.58mg/liter

vm

-REACTIVITY

Unstable (Contingent
upontemperature,

DATA

I

HAZARDOUS POLYMERIZATION:

Will not occur.

contamination(metals),and pH.)

CONDITIONS TO AVOW:
copperand iron.

Heat, light exposure,decreasein pH, and contaminationwith heavymetals, suchas nickel, cobalt,

INCOMPATffiILITY (MATERIALS TO AVOm): Heavy metals,reducingagents,organics,ether,ammonia, ammoniumacetate,
ammoniumcarbonate,ammoniumnitrate, ammoniumoxalate,ammoniumphosphate,ureaand acids.
HAZARDOUS DECOMPOSITION PRODUCTS: Hypochlorousacid, chlorine,hydrochloric acid, sodiumchloride, sodium
chlorate,and oxygen. Decompositionof sodiumhypochloritetakesplace within a few secondswith following salts: ammonium
acetate,ammoniumcarbonate,ammoniumnitrate,ammoniumoxalate,and ammoniumphosphate.Hypochlorites reactwith ureato
form nitrogentrichloride, which explodesspontaneouslyin air.
I

SECTION

IX -SPILL

OR

LEAK

PROCEDURES

I

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Personnelwith properprotective equipment
~houldcontainspill. Flush areawith large amountsofwater,.;t)se reducing agentssuchasbisulfites or ferrous salt solutionsto
neutralize.
WASTE DISPOSAL METHOD: Disposalis to be in accordancewith all Federal,State,and Local regulations.

SECTION

X -SPECIAL

PROTECTION

INFORMATION

RESPIRATORY PROTECTION: Whenfumespresent,useNIOSH approvedrespiratorwith acid type canister.
VENTILATION:

Local exhaustpreferableasrequiredto control fumes.

PROTECTIVE GLOVES: Rubberor plastic.

EYE PROTECTION: Chemicalgoggles.

OTHER PROTECTIVE EOUIPMENT: Clothing to protectskin. Safetyshowerandeye washfountain.
C:\RDl\WORD\MSDS\MSSOHYPO.DOC

1_'.-

Page3 of 5

FORMAT
REVISION
DATE:April23,2001

0_- Ow,",

"~;~."'m-

BRENNT
AGMID-SOUTH,
INC.

~II-

BRENNTAG~
1111.1

MATERIAL SAFETY DATA SHEET

Effective Date: July 19, 2004

SODIUM HYPOCHLORITE

I

SECTION

XI -SPECIAL

SOLUTION

PRECAUTIONS

-l

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Storethis productin a cool dry area; away form direct
sunlight and heatto avoid deterioration. In caseof spill, flood areaswith largequantitiesof water. Productor rinsatesthat cannotbe
usedshouldbe diluted with waterbefore disposalin a sanitarysewer. Do not reusecontainer. Do not contaminatefood or feed by
storage,disposalor cleaning of equipment. Mostmetalsand metalalloys are NOT suitablefor use in contactwith sodium
hypochlorite solutionsincluding aluminum, brass,bronze,copper,castiron, galvanizedsteel,mild steel,nickel, or stainlesssteel,
sincethesemetals act asa catalystwhich will causerapid decompositionof the sodiumhypochlorite solution through the releaseof

oxygen.
Sodiumhypochlorite solutionsare basically unstable,and on exposureto heatand/orlight, will slowly decompose,becomingless
concentratedwith time. Sodiumhypochloritesolutionsshould neverbe allowedto contactor mix with acids or other low pH
compounds,due to the releaseof chlorine gas. Do not allow sodiumhypochloriteto mix with ammonia,since chloroaminesmaybe
formed.
Decompositionof sodiumhypochlorite takesplacewithin a few secondswith following salts: ammoniumacetate,ammonium
carbonate,ammoniumnitrate, ammoniumoxalate,and ammoniumphosphate.
Hypochlorites reactwith ureato form nitrogentrichloride, which explodesspontaneouslyin air.
Solutions of sodiumhypochloriteare corrosiveto the skin,eyes,and mucousmembranes.Propersafety equipmentshouldbe used
whenworking with or in close proximity of sodiumhypochlorite.
OTHER PRECAUTIONS: Use with adequateventilation. Washthoroughly afterhandling. Do not get in eyes, on skin or clothing.
Do NOT breathefumes or mist. Mixing this productwith chemicals(e.g. commonhouseholdcleaners,ammonia, acids,detergents,
etc.) or organic matterwill releasechlorine gas,which is irritating to eyes,lungs,and mucousmembranes.
STRONGOXIDIZING AGENT: Mix only with wateraccordingto labeldirections. Mixing this product with chemicals(e.g.
commonhouseholdcleaners,ammonia,acids,detergents,etc.) or organic matter(e.g. urine,feces,etc.) will releasechlorine gas,
which is irritating to eyes,lungs and mucousmembranes.
HAZARD RATING:

Health 3

SECTION

Flammability 0

XII -D.O. Ti' .SHIPPING

Reactivity 2

INFORMATION

PROPER SHIPPING .NAME: Hypochlorite Solutions
HAZARD CLASS: 8 (Corrosive)
D.O.T. LABEL REQUffiED: Corrosive

C:\RD1\WORD\MSDS\MSSOHYPO.DOC

UN/NA: UN 1791

PACKING GROUP: III

~EPORTABLE OUANTITY OF PRODUCT: 800 to 2,000 lbs.

Page4 of 5

FORMAT
REVISION
DATE:April23.2001

"

.~'"

BRENNTAG ..8.1;
-

BRENNTAG MID-SOUTH, INC.
MATERIAL

SAFETY

Effective

Date:

DATA SHEET

July 19, 2004

SODIUM HYPOCHLORITE

I

SECTION
TSCA (Toxic
CERCLA

Substance Control Act}:

AND SARA

XIII

SARA Extremely

Discharge

AIR ACT':

OTHER REGULA
Know Laws.

"

= 100 pounds (100% NaOCl)

Acute:

yes

CERCLA

Hazardous Material:

SARA Toxic Chemical:
Chronic:

yes

Fire: no

This product does not contain nor is it manufactured

nONS/LEGISLA

INFORMATION

40 CFR §300-373:

Hazardous substance: No

Title III Hazard Classifications:
EPA " CLEAN

TORY

All components of this product are listed on the TSCA inventory.

REGULA nONS,

Super fund Reportable

-REGULA

SOLUTION

TION THAT APPLY

TO THIS PRODUCT:

Reactivity:

yes

yes

No
Pressure: No

with ozone depleting substances.
Massachusetts, Pennsylvania, and New Jersey Right-to

,,~~'.'

~i.E
BRENNTAd MI~O~~~~GEVEs
~T
THE ~Fo~rib~~6NT
AlNED HEREIN IS FACfUAL; rr IS NOT TO BE TAKEN AS A
WARRANTY OR REPRESENTATIONFOR WlDCH BRENNTAG MID-SOUTH, INC. ASSUMESLEGAL RESPONSffiILITY. rr IS OFFERED SOLELY FOR
YOUR CONSffiERA TION, INVESTIGATION AND VERIFICATION. ANY USE OF THIS INFORMATION AND DATA MUST BE DETERMINED BY THE
USERTO BE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
,
"""

:I:

~

A(iJJ~ 71

,::;(P
'f:~~~~~~~
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C:\RDI\WORD\MSDS\MSSOHYPO.DOC

"-_~_k!CJ,",

",'-

"!'::

~~~~-

:=

..

Page 5 of 5

FORMAT REVISION DATE: April 23, 2001

MATERIAL SAFETY DATA SHEET

1.

CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME:
Product ID:
SYNONYMS:
No. 0310
ISSUE DATE:
EDITION NO.:

Pittclor® Dry Chlorinating Granules
0310D
Calcium Hypochlorite Granular; Cal Hypo Granules; Ca(OCl) 2; MSDS
03/09/2007
11

PPG Industries, Inc.
One PPG Place, Pittsburgh, PA 15272, USA
24-hour Emergency Telephone Number: 1-412-434-4515
For Product Information (8am-5pm Eastern time):
1-800-245-2974 (Cal Hypo)

PREPARER:

Product Safety, Chemicals

2.

COMPOSITION/INFORMATION ON INGREDIENTS

Material/CAS Number

Percent

Calcium Hypochlorite
7778-54-3
Calcium Chlorate
10137-74-3
Calcium Carbonate
471-34-1
Calcium Hydroxide
1305-62-0

>65
<2
<2
<2

Note: Minimum 65% Available Chlorine. 35% inert ingredients (includes 5.5-8.5% water).

3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
DANGER! Corrosive - Causes severe and irreversible burns to eye and skin. Harmful if inhaled. May
cause irritation and inflammation to the respiratory tract. Harmful or fatal if swallowed. Strong
Oxidizing Agent! Mix only with water. Never add water to product. Always add the product to large
quantities of water. Do not mix with any other chemicals. Contamination with moisture, acids, organic
materials and other easily combustible materials such as petroleum, paint products, wood or paper
Page 1 of 7

PPG:

0310D Pittclor® Dry Chlorinating Granules

03/09/2007

may cause fire or explosion and the liberation of hazardous gases. Do not add this product to any
dispensing device containing remnants of any other product. Such use may cause violent reaction
leading to fire or explosion. Very toxic to aquatic organisms.
Precautions:
Do not get in eyes, on skin, or on clothing. Avoid breathing dust. Irritating to nose
and throat. Do not swallow. Do not eat, drink or smoke in work area. Wash hands after handling.
Remove and wash contaminated clothing before reuse. Keep out of reach of children.

4.

FIRST AID MEASURES

INHALATION: Remove from area to fresh air. If symptomatic, contact a poison control center,
emergency room or physician for treatment information.
EYE/SKIN CONTACT: EYE: Remove contact lens and pour a gentle stream of warm water
through the affected eye for at least 15 minutes. Contact a poison control center, emergency room or
physician right away as further treatment will be necessary. SKIN: Run a gentle stream of water over
the affected area for 15 minutes. A mild soap may be used if available. Contact a poison control
center, emergency room or physician right away as further treatment will be necessary.
INGESTION:
Gently wipe or rinse the inside of the mouth with water. Sips of water may be given
if person is fully conscious. Never give anything by mouth to an unconscious or convulsing person.
Do Not induce vomiting. Contact a poison control center, emergency room or physician right away as
further treatment will be necessary.

5. FIRE-FIGHTING MEASURES
FLASH POINT:

Not Applicable.

EXTINGUISHING MEDIA: Drench with large quantities of water only. Do not use dry chemicals or
foams. Product supplies own oxygen, therefore attempts to smother fire with a wet blanket, carbon
dioxide, dry chemical extinguisher or other means are not effective.
SPECIAL FIREFIGHTING PROCEDURES: Product decomposes at approximately 338-356°F (170180°C) releasing oxygen gas. Container may rupture. Fire-fighters must wear NIOSH approved,
pressure demand, self-contained breathing apparatus with full face piece for possible exposure to
hazardous gases. Emits toxic fumes under fire conditions.

6.

ACCIDENTAL RELEASE MEASURES

ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
Use extreme caution in handling spilled material. Do not mix with any other chemicals.
Contamination with moisture, acids, organics or other easily combustible materials such as
petroleum, paint products, wood or paper may cause fire or violent decomposition. If fire or
decomposition occurs in area of spill, immediately douse with plenty of water. Otherwise, sweep up
all visible material using a clean (new, if possible), dry shovel and broom and dissolve material in
water. Spilled material that has been swept up and dissolved in water should be used immediately in
the normal application for which this product is being consumed.

7. HANDLING AND STORAGE

Page 2 of 7

PPG:

0310D Pittclor® Dry Chlorinating Granules

03/09/2007

PRECAUTIONS TO BE TAKEN DURING HANDLING AND STORAGE:
Store in a cool, dry, well-ventilated place. Keep in original container. Keep container closed when not
in use. Keep away from heat, sparks, flames, direct sunlight, and other sources of heat, including
lighted tobacco products. Use only a clean (new, if possible), dry scoop made of metal or plastic each
time product is taken from the container. Do not add this product to any dispensing device containing
remnants of any other product. Such use may cause violent reaction leading to fire or explosion. Add
this product only to water. Never add water to product. Always add the product to large quantities of
water. May cause fire or explosion if mixed with other chemicals. Fire may result if contaminated with
acids, organic materials and other easily combustible materials such as oil, kerosene, gasoline, paint
products wood and paper. Do not reuse container. Residual material remaining in empty container
can react to cause fire. Thoroughly flush empty container with water then destroy by placing in trash
collection. Do not contaminate water, food, or feed by storage or disposal of this product.

8.

EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Limits:
8-hour Time Weighted Average (TWA); 15-minute Short-Term Exposure Limit (STEL)
OSHA: The OSHA exposure limit(s) for Calcium hydroxide: 5 mg/m3 TWA. Calcium carbonate: 15
mg/m3 (total dust) 5 mg/m3 (respirable dust)
ACGIH: The ACGIH exposure limit(s) for Calcium hydroxide: 5 mg/m3 TWA. Calcium carbonate: 10
mg/m3 (total dust) 3 mg/m3 (respirable nuisance particulate) TWA.
ONTARIO: The Ontario Exposure limit(s) for Calcium hydroxide: 5 mg/m3TWAEV Calcium
carbonate: 10 mg/m3TWAEV
PPG Internal Permissible Exposure Limit (IPEL):
TWA. 2 mg/m3 STEL.

Calcium hypochlorite: 1 mg/m3

RESPIRATORY PROTECTION:
Where the potential for exposure
to dust exists, use the appropriate regulatory compliant full facepiece air-purifying respirator with acid
gas cartridge and particulate prefilter. Carefully read and follow the respirator manufacturer's
instructions and information.
VENTILATION: Use local exhaust or general room/dilution ventilation sufficient to maintain
employee exposure below permissible exposure limits.
EYE AND FACE PROTECTION:

Splashproof goggles and faceshield.

PROTECTIVE GLOVES: Butyl rubber. Neoprene. Nitrile.
OTHER PROTECTIVE EQUIPMENT: Boots, aprons, or chemical suits should be used when
necessary to prevent skin contact.

9. PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point:
Vapor Density (Air=1):

Decomposes at approximately 338-356°F (170-180°C)
NA
Page 3 of 7

PPG:

0310D Pittclor® Dry Chlorinating Granules

Specific Gravity (Water=1):
pH:
FREEZING/MELTING POINT:
SOLUBILITY (wt.% in water):
Bulk Density (kg/M3):
VOLUME % VOLATILE:
VAPOR PRESSURE:
Evaporation Rate:
HEAT OF SOLUTION:
Physical State:
Odor:
COLOR:

03/09/2007

NA
Alkaline
NA
217 g/l @ 27°C
65-67 lbs./cu.ft.
NA
NA
NA
Slightly exothermic
Granules
slight chlorine
White

10. STABILITY AND REACTIVITY
Stability:

Unstable above 338°F (170°C).

HAZARDOUS POLYMERIZATION: Will not occur.
INCOMPATIBILITY (CONDITIONS/MATERIALS TO AVOID):
Contamination. Excessive heat above 338°F (170°C). Moisture. Acids. Reducing agents. Organics.
Combustible materials. Petroleum products. Paint products. Wood and paper.
HAZARDOUS THERMAL DECOMPOSITION/COMBUSTION PRODUCTS:
Acid or ammonia contamination will release toxic gases. Excessive heat will cause decomposition
resulting in the release of oxygen and chlorine gas.

11.
ACUTE INHALATION LC50:
toxicity.
ACUTE DERMAL LD50:
SKIN IRRITATION:
EYE IRRITATION:
ACUTE ORAL LD50:

TOXICOLOGICAL INFORMATION
No mortality at 3.5 mg/l (rat) (1 hour). Slight to very low
>1000 mg/kg. (rabbit) Slight to very low toxicity.
Corrosive.
Corrosive.
850 mg/kg. (rat) Moderate toxicity.

CARCINOGENICITY STATUS:
This product is NOT listed as a carcinogen or suspected
carcinogen by NTP, IARC, ACGIH, or OSHA.
MEDICAL CONDITIONS AGGRAVATED: None known.
EFFECTS OF OVEREXPOSURE:
ACUTE:
Inhalation: Inhalation of calcium hypochlorite dust and deposition of particles in the respiratory tract
can lead to irritation of the tissue and cause a variety of effects. These effects are dependent on
concentration and include: upper respiratory tract irritation, nasal congestion, coughing, sore throat,
laryngitis and shortness of breath. In operations where there are high concentrations of respirable
Page 4 of 7

PPG:

0310D Pittclor® Dry Chlorinating Granules

03/09/2007

particulates, pulmonary edema (fluid in the lung) may be produced. If not treated immediately,
pulmonary edema can be life threatening. Since this product is in granular or tablet form, particles of
respirable size are not generally encountered.
Eye/Skin: Calcium hypochlorite is corrosive to the eyes. Contact of calcium hypochlorite dust with
the eyes, even a minute amount for a short duration, can cause severe irritation and even blindness.
Contact with the skin may cause severe irritation, burns, or tissue destruction. In studies utilizing
rabbits, the skin irritation score was 8/8 and the eye irritation score was 98.5/110.
Ingestion: Calcium hypochlorite, if swallowed, causes severe burns to the digestive tract and can be
fatal.
CHRONIC:
Genotoxicity: Calcium hypochlorite produced positive responses in in-vitro assays using bacterial
systems (the Ames test) and chromosomal aberrations in Chinese hamster fibroblasts. In a whole
animal experiment (mouse micronucleus test), exposures ranging from 20 to 160 mg/kg produced no
compound related chromosomal abnormalities.
Carcinogenisis: Although no study has been conducted with calcium hypochlorite, the carcinogenic
potential of sodium hypochlorite was studied in F344 rats. After 104 weeks of drinking water
containing up to 2000 ppm sodium hypochlorite, there was no evidence that this chemical produced
any carcinogenic response. In addition, this exposure did not result in any adverse effects

12.

ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION:
0.088 mg/l (Bluegill) 96-hour LC50. Extreme toxicity.
ENVIRONMENTAL FATE:
No data at this time.

13.

DISPOSAL CONSIDERATIONS

DISPOSAL METHOD:
Spilled material that has been swept up and dissolved in water should be used immediately in the
normal application for which this product is being used. If this is not possible, dissolve material in
water and carefully neutralize dissolved material by adding hydrogen peroxide (one pint of 35%
hydrogen peroxide solution per pound of calcium hypochlorite to be neutralized) then dilute the
neutralized material with plenty of water and flush to sewer. Note: Only properly neutralized material
should be flushed to sewer. Unneutralized material can cause environmental damage to receiving
water or can interfere with treatment plant operation. Care must be taken when using or disposing of
chemical materials and/or their containers to prevent environmental contamination. It is your duty to
dispose of the chemical materials and/or their containers in accordance with the U.S. Clean Air Act,
the Clean Water Act, the Resource Conservation and Recovery Act, as well as any other relevant
Federal, State, or local laws/regulations regarding disposal.

14.
Proper Shipping Name:

TRANSPORT INFORMATION
Calcium Hypochlorite, Hydrated
Page 5 of 7

PPG:

0310D Pittclor® Dry Chlorinating Granules

03/09/2007

Hazard Class:
5.1 (Oxidizer)
UN Number:
UN2880
Packing Group:
II
10 lbs./4.5 kg. (calcium
USA-RQ, Hazardous Substance and Quantity:
hypochlorite)
Marine Pollutant:
None
Additional Information:
USA Shipments Only - Hazardous Substances are
regulated in the USA when shipped above their Reportable Quantity (RQ).

15.

REGULATORY INFORMATION

USA TSCA: All components of this product are listed on the TSCA Inventory.
EU EINECS: All components in this product are listed on EINECS.
CANADA DOMESTIC SUBSTANCES LIST (DSL): This product and/or all of its components are
listed on the Canadian DSL.
AUSTRALIA AICS: All components of this product are listed on AICS.
KOREA ECL: All components in this product are listed on the Korean Existing Chemicals Inventory
(KECI).
JAPAN MITI (ENCS):
All components in this product are listed on the
Japanese Existing and New Chemical Substances (ENCS) chemical inventory.
PHILIPPINES PICCS:
All of the components in this product are listed
on the Philippines Inventory of Chemicals and Chemical Substances (PICCS).
CHINA IECSC:
All components of this product are listed on the Inventory of Existing Chemical
Substances in China (IECSC) or otherwise exempt.
SARA TITLE III:
SARA (311, 312) Hazard Class:
Acute Health Hazard. Reactive Hazard. Fire Hazard.
SARA (313) Chemicals:
Not listed.
SARA Extremely Hazardous Substance:
Not listed.
CERCLA Hazardous Substance:
The following materials are listed as CERCLA Hazardous Substances in Table 302.4 of 40 CFR Part
302: Calcium Hypochlorite (7778-54-3) RQ = 10 lbs./4.54 kg.
CANADA REGULATIONS (WHMIS): Class C - Oxidizing material.
FIFRA:
This product is registered with EPA as a pesticide.

16.

OTHER INFORMATION

Other Information:
NSF Drinking Water Treatment Chemicals Listing - PPG calcium hypochlorite is certified for
maximum use at 15 mg/L under NSF/ANSI Standard 60.
The following has been revised since the last issue of this MSDS:
Page 6 of 7

PPG:

0310D Pittclor® Dry Chlorinating Granules

03/09/2007

Date. Edition. Section 1 has been updated. Section 8 has been updated. Section 12 has been
updated. Section 15 has been updated. Section 16 has been updated.
Previous revision date:
Previous edition number:

01/02/2004
010

NA = Not Available

Page 7 of 7

Material Safety Data Sheet
PO Box 24600
Houston, Tx 77229-4600
281-457-4888
888-647-7717
www.dxgroup.com

Provided by:
DPC Industries, Inc.
DX Distributors, Inc.
DPC Enterprises
DX Systems Company
DXI Industries, Inc.
DX Terminals

SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name

TRICHLOR TABLETS

Synonyms

1,3,5- TRIAZINE, TRICHLOR, CRYSTAL CARE TABLETS, HYDROTECH TABLETS

Chemical Name

TRICHLORISOCYANURIC ACID

Emergency phone:
Chemtrec:

281-457-4888
800-424-9300

Date of Issue:
Revised Date:

1/2/01
N/A

SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
COMPONENTS

PERCENT

TRICHLORISOCYANURIC ACID

99%

CAS NO.
87-90-1

SECTION 3 - HAZARDS IDENTIFICATION
Potential Health Effects
ACGIH - TLV:
Eye Contact

NOT ESTABLISHED.

Skin Contact

CAN CAUSE SKIN BURNS, IRRITATION AND POSSIBLE ALLERGIC REACTION.

Ingestion

CORROSIVE AND MAY CAUSE SEVERE AND PERMANENT DAMAGE TO MOUTH, THROAT AND
STOMACH.

Inhalation

CAUSES RESPIRATORY TRACT IRRITATION.

Carcinogenicity:

CAN CAUSE EYE BURNS AND PERMANENT TISSUE DAMAGE.

NTP NO

IARC NO
OSHA NO
SECTION 4 - FIRST AID PROCEDCURES

Eye Contact:

IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION.

Skin Contact:

IMMEDIATELY REMOVE CONTAMINATED CLOTHING OR SHOES, WIPE EXCESS FROM SKIN AND
FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. USE SOAP IF AVAILABLE OR
FOLLOW BY WASHING WITH SOAP AND WATER. DO NOT REUSE CLOTHING UNTIL THOROUGHLY
CLEANED. GET MEDICAL ATTENTION.

Inhalation:

REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS DIFFICULT. GIVE
ARTIFICIAL RESPIRATION IF NOT BREATHING. GET MEDICAL ATTENTION.

Ingestion:

DO NOT INDUCE VOMITING. RINSE MOUTH WITH WATER. IF CONSCIOUS, GIVE LARGE
QUANTITIES OF WATER OR MILK AND GET IMMEDIATE MEDICAL ATTENTION. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON!

SECTION 5 -FIRE FIGHTING MEASURES
Flash Point

NONFLAMMABLE.

Extinguishing Media

USE MEDIA APPROPRIATE FOR SURROUNDING AREA.

TRICHLOR TABLETS

Page 1 of 3

WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE
GEAR. STAY UPWIND AND KEEP OUT OF LOW AREAS.

Special Firefighting
Procedures/Precuations

SECTION 6 -ACCIDENTAL RELEASE MEASURES
For Spill:

SWEEP OR VACUUM MATERIAL AND PLACE IN CONTAINER FOR DISPOSAL. FLUSH REMAINING
MATERIAL WITH LARGE AMOUNTS OF WATER. PREVENT IT FROM ENTERING WATERWAYS OR SEWERS.

SECTION 7 - HANDLING AND STORAGE
Keep container tightly closed when not in use. Store in a cool, dry, well-ventilated area, away from heat and
incompatible materials. Protect containers from physical damage.
AVOID MOISTURE CONTAMINATION. KEEP OFF WET FLOORS.

SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
Respiratory Protection

USE A NIOSH/MSHA APPROVED RESPIRATOR FOLLOWING MANUFACTURER'S
RECOMMENDATIONS.

Ventilation

LOCAL AND MECHANICAL RECOMMENDED.

Protective Gloves

CHEMICAL IMPERVIOUS GLOVES.

Eye/Face Protection

CHEMICAL SAFETY GOGGLES AND/OR FULL-FACE SHIELD.

Other Protection

CHEMICAL RESISTANT CLOTHING SUCH AS COVERALLS/APRON, BOOTS, ETC.

Work Practices

USE GOOD PERSONAL HYGIENE PRACTICES. WASH HANDS BEFORE EATING, DRINKING,
SMOKING, OR USING TOILET FACILITIES. PROMPTLY REMOVE SOILED CLOTHING AND
WASH THOROUGHLY BEFORE REUSE. SHOWER AFTER WORK USING PLENTY OF SOAP
AND WATER.

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point (ºF):

Vapor Pressure (mmHg):

NOT APPLICABLE

Freezing Point (ºF): NOT APPLICABLE

Vapor Density (Air=1):

NOT APPLICABLE

Solubility (H2O):

SOLUBLE

Specific Gravity (H2O=1):

<1

pH

2.6

Evaporation Rate:

NOT DETERMINED

Appearance/Odor:

WHITE SOLID WITH CHLORINE-LIKE/BLEACH ODOR.

DECOMP AT 230

SECTION 10 - STABILITY AND REACTIVITY
Chemical Stability:

YES

Incompatible Materials

OXIDIZING AGENTS, REDUCING AGENTS, INORGANIC NITROGEN AND ORGANIC
MATERIALS.

Decomposition Products

MAY EVOLE CHLORINE CONTAINING GAS.

Hazardous Polymerization:

WILL NOT OCCUR.

TRICHLOR TABLETS

Page 2 of 3

SECTION 11 - TOXICITY INFORMATION
LD50 SKIN = 7600 mg/kg LD50 ORAL = 600 mg/kg

SECTION 12 - ECOLOGICAL INFORMATION
NO DATA AVAILABLE.

SECTION 13 - DISPOSAL CONSIDERATIONS
DISPOSE OF WASTE MATERIALS ACCORDING TO ALL FEDERAL, STATE AND LOCAL REGULATIONS.

SECTION 14 - TRANSPORT INFORMATION
USA DOT Shipping Name: TRICHLOROISOCYANURIC ACID, DRY
Hazard Class:

5.1

UN/NA Number:

UN2468

Packing Group:

II

Subsidiary Hazard
NO

Marine Pollutant:

SECTION 15 - REGULATORY INFORMATION
CERCLA RQ (lbs): NOT APPLICABLE
SARA Title III Section 312:
Acute

Chronic

Flammable

SARA Title III Section 313:

Sudden Release of Pressure

Reactive

No

SARA Extremely Hazardous Substance:

No

HMIS HAZARD RATING
Health:
0 - Least

Fire:

3

1 - Slight

Reactivity:

1

2 - Moderate

3 - High

2

4 - Extreme

SECTION 16 - OTHER INFORMATION
EPA Pesticide Registration Number:

NOT APPLICABLE

NSF Maximum Use Level for Potable Water (Standard 60):

NOT APPLICABLE

TSCA (Toxic Substance Control Act), 40 CFR 710:
Sources of the raw materials used in this mixture assure that all chemical ingredients present are in compliance
with Section 8(b) Chemical Substance Inventory, or are otherwise in compliance with TSCA.

DISCLAIMER
THE DATA PRESENTED IS TRUE AND CORRECT TO THE BEST OF OUR KNOWLEDGE AND BELIEF;
HOWEVER, NEITHER SELLER NOR PREPARER MAKES ANY WARRANTIES, EXPRESSED OR IMPLIED,
CONCERNING THE INFORMATION PRESENTED. THE USER IS CAUTIONED TO PERFOM HIS OWN HAZARD
EVALUATION AND TO RELY UPON HIS OWN DETERMINATIONS.

TRICHLOR TABLETS

Page 3 of 3

MATERIAL SAFETY DATA SHEET
Section 1 - Product Identification & Use
Product Name:
Bromine Tablets
WHMIS Classification: Class C: Oxidizing Material
TDG Classification:
Oxidizing solid, n.o.s. (bromo-chlorodimethylhydantoin) Class 5.1, UN 1479,
Packing Group II
Supplier:
Advance Chemicals Ltd.
2023 Kingsway Ave
Port Coquitlam, BC V3C 1S9
phone (604)945-9666
fax (604)945-9617
Emergency phone:
CANUTEC 24 hrs (613) 996-6666
Section 2 - Hazardous Ingredients
Hazardous Components
%(w/w) C.A.S. No. LD50 & LC50
1-bromo-3-chloro-5, 5-dimethylhydantoin
92.5
126-06-7
no data found
Section 3 - Physical Data
Physical state: solid
Boiling point: N/A
Specific Gravity: N/A
Freezing point:120-148°C%
Volatile(By volume): <0.5
Solubility in water: 0.54g/100g @ 25°C
Vapour pressure: N/A
Evaporation rate: no data found
Odour & Appearance: Pungent, off-white tablets.
Section 4 - Fire or Explosion Hazard
Flammability:
The product is considered to be flammable.
Contamination with organic chemicals, acids, or ammonia may
generate fumes leading to fire or explosion.
Flash Point: Decomposes at 165°C.
Extinguishing media: Use copious quantities of water.
Hazardous Combustion/Decomposition Products: Produces
noxious gases: Br2
Section 5 - Reactivity Data
Stability: Stable.
Incompatible substances: Strong acids and alkalis, high storage
temperatures, organic materials, ammonia bearing compounds,
strong reducing agents and moisture.
Polymerization: Will not occur.
Hazardous decomposition products: Thermal decomposition
releases unidentified noxious gases.
Section 6 - Toxicological Properties
Route of Entry: Skin, eye, ingestion and acute inhalation.
Inhalation: May cause damage to lungs (systemic absorption).
Severe to nose and throat.
Skin contact: Acute exposure may cause severe skin damage.
Eye contact: Acute exposure may cause severe eye damage.
Section 7 - Preventative Measures
Personal Protective Equipment: Avoid contact with skin and
eyes. Wear chemical protective gloves, goggles and face shield,
rubber apron and boots. Eye wash fountains and safety shower
facilities should be provided nearby for emergency use.
Respiratory protection: Use an NIOSH/MSHA approved air
purifying, dust, mist and particulate respirator.
Action to take for spills & leaks: Wear chemical protective
clothing, rubber gloves and suitable respiratory protection. Small
spills should be swept or vacuumed up and disposed of in
government approved waste containers. The spill area may then be
flushed with large quantities of water. Larger spills should be
contained by diking with sand, soil or other non-combustible
material, then transferred into approved waste containers for proper
disposal. Do not allow spilled, or waste product to flow into
waterways. Keep product out of sewers, storm drains, surface runoff water and soil. Restrict access to non-protected personnel.
Comply with all government regulations on spill reporting, and
handling and disposal of waste. Incinerate or dissolve in water and
neutralize halogen. Wet spills should be collected and neutralized.

Revision #: 03

Disposal methods: Dispose of contaminated product and materials
used in cleaning up spills or leaks in a manner approved for this
material. Consult appropriate federal, provincial and local regulatory
agencies to ascertain proper disposal procedures.
Note: Empty containers can have residues, gasses and mists, and
are subject to proper waste disposal as mentioned above.
Storage & Handling Precautions: Warning, harmful or fatal if
swallowed. Causes eye, skin and respiratory irritation. Avoid
contact with eyes and repeated contact with skin and clothing. Do
not ingest. Keep container tightly closed when not in use. Store
upright in a cool, dry, well-ventilated place away from incompatible
materials. Do not use pressure to empty container. Wash thoroughly
after handling. Use with adequate ventilation.
Repair and Maintenance Precautions: Do not cut, grind, weld or
drill in, on or near this container.
Section 8 - First Aid Measures
If inhaled: Remove victim to fresh air. Give artificial respiration if
not breathing. Get immediate emergency medical attention. Keep
patient warm and at rest. Give supplemental oxygen if victim is
having trouble breathing.
In case of eye contact: Immediately flush eyes with clean water for
at least twenty (20) minutes, lifting the upper and lower eyelids to
ensure complete flushing action of the eyeball. Get immediate
emergency medical attention. Do not transport victim until the
recommended flushing period has been completed, unless eye
flushing can be carried out during transport.
In case of skin contact: Wipe away excess material with a dry
cloth then immediately flush skin with plenty of clean running water
for at least twenty (20) minutes. Remove contaminated clothing and
shoes. If irritation persists, get emergency medical attention. Wash
and launder clothes before re-use.
In case of ingestion or swallowing: If victim is conscious, dilute
stomach contents by giving one or two glasses of water. DO NOT
INDUCE VOMITING. Never give anything by mouth to an unconscious
victim. GET IMMEDIATE EMERGENCY MEDICAL ATTENTION.
Section 9 - Preparation Information
Advance Chemicals Limited expressly disclaims all expressed or
implied warranties of merchantability and fitness for a particular
purpose with respect to the product provided. The information
contained herein is offered only as a guide to the handling of this
specific product, and has been prepared in good faith by technically
knowledgeable personnel. This M.S.D.S. is not intended to be allinclusive, and the manner and conditions of use may involve other
and additional considerations.
Revised:
5 July 2004; 27 October 2006; 15 December 2006

S:\MSDS\MSDS - Advance\Advance Updated MSDS\Bromine Tablets.DOC

Page 1 of 1

MATERIAL SAFETY DATA

SHEET

GLB Stabilizer

1. Product And Company Identification
Supplier
GLB
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Manufacturer
Advantis Technologies Inc.
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Telephone Number: (770)521-5999
FAX Number: (770)521-5959
Web Site: www.poolspacare.com

Telephone Number: (770) 521-5999
FAX Number: (770) 521-5959
Web Site: www.poolspacare.com

Supplier Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Manufacturer Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Issue Date: 04/18/2001
Product Name: GLB Stabilizer
CAS Number: Not Established
Chemical Family: Cyanurate
Chemical Formula: C3H3N3O3
MSDS Number: 57
Synonyms
CYA
2. Composition/Information On Ingredients
Ingredient
Name

CAS
Number

CYANURIC ACID

Percent Of
Total Weight

108-80-5

Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials
determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as
carcinogens are listed if they comprise 0.1% or more of the composition. Information on proprietary materials is
available in 29CFR 1910.1200(i)(1).
3. Hazards Identification
Primary Routes(s) Of Entry
Skin Contact
Eye Hazards
May cause eye irritation.
Skin Hazards
May cause skin irritation.
Ingestion Hazards
Harmful if swallowed.If ingested, get immediate medical attention
Inhalation Hazards
May cause respiratory tract irritation.
Signs And Symptoms
Low Toxicity irritating only as a dust

Page 1 of 4

MATERIAL SAFETY DATA

SHEET

GLB Stabilizer
3. Hazards Identification - Continued
Conditions Aggravated By Exposure
None Known
First Aid (Pictograms)

4. First Aid Measures
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes.
Consult Physician.
Skin
In case of contact, immediately flush skin with plenty of water for at least 15 minutes.
Ingestion
Call a physician or a poison control center immediately.
Inhalation
If inhaled, remove to fresh air.
Fire Fighting (Pictograms)

5. Fire Fighting Measures
Flash Point: N/A °F
Flammability Class: NOT FLAMMABLE
Extinguishing Media
Use the appropriate extinguishing media for the surrounding fire.
Fire Fighting Instructions
Firefighters should wear self-contained breathing apparatus and full protective gear.
6. Accidental Release Measures

Sweep up and remove immediately. Clean up on dry basis. Avoid release to the environment. Collect and dispose.
7. Handling And Storage
Handling And Storage Precautions
Keep out of reach of children. Do not store with acids. Keep containers tightly closed. Store material in a cool and
dry place. Away from food.
Handling Precautions
Avoid unnecessary contact with eyes skin and clothing.
Storage Precautions
Store in a cool dry place. Keep away from food
Work/Hygienic Practices
Use safe chemical handling procedures suitable for the hazards presended by this material.

Page 2 of 4

MATERIAL SAFETY DATA

SHEET

GLB Stabilizer
Protective Clothing (Pictograms)

8. Exposure Controls/Personal Protection
Engineering Controls
Local exhaust acceptable. Special exhaust not required unless dust accumulation is a problem.
Eye/Face Protection
Safety glasses with side shields or goggles recommended.
Skin Protection
Chemical-resistant gloves.
Respiratory Protection
None normally required. If dust accumulation is a problem a dust mask is suggested.
Full Cover clothing should be worn
9. Physical And Chemical Properties
Appearance
White to gray Crystalline powder
Odor
None
Chemical Type: Mixture
Physical State: Solid
Melting Point: DECOMPOSES °F
Boiling Point: DECOMPOSES @ 70C °C
Specific Gravity: 0.83-0.93
Percent Volitales: NOT APPLICABLE
Percent VOCs: NOT APPLICABLE
Vapor Pressure: NIL
Vapor Density: NOT VOLATILE
Solubility: 1% AT 25C IN WATER
Viscosity: NOT APPLICABLE
Evaporation Rate: NOT APPLICABLE
10. Stability And Reactivity
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatible Materials
NONE
Hazardous Decomposition Products
Oxides of Nitrogen and Carbon anc Cyanuric Acid
11. Toxicological Information
Acute Oral Effects
LD50 mg/kg Rat >5g/kg

Page 3 of 4

MATERIAL SAFETY DATA

SHEET

GLB Stabilizer
12. Ecological Information
No Data Available...
13. Disposal Considerations

Dispose in accordance with applicable federal, state and local government regulations.
14. Transport Information
Proper Shipping Name
NOT REGULATED
Hazard Class
NOT REGULATED
DOT Identification Number
NONE
DOT Shipping Label
NOT ASSIGNED
15. Regulatory Information
No Data Available...
NFPA

HMIS

0
1

0

HEALTH

1

FLAMMABILITY

0

REACTIVITY

0

PERSONAL PROTECTION

E

16. Other Information
Revision/Preparer Information
MSDS Preparer: JHW3
This MSDS Superceeds A Previous MSDS Dated: 07/26/2000
Disclaimer
Although reasonable care has been taken in the preparation of this document, we extend no warranties
and make no representations as to the accuracy or completeness of the information contained therein,
and assume no responsibility regarding the suitablility of this information for the user's intended
purposes or for the consequences of its use. Each individual should make a determination as to the
suitability of the information for their particular purposes(s).
GLB
Printed Using MSDS Generator™ 2000

Page 4 of 4

MATERIAL SAFETY DATA

SHEET

GLB Alkalinity Up

1. Product And Company Identification
Supplier
GLB
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Manufacturer
Advantis Technologies Inc.
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Telephone Number: (770)521-5999
FAX Number: (770)521-5959
Web Site: www.poolspacare.com

Telephone Number: (770) 521-5999
FAX Number: (770) 521-5959
Web Site: www.poolspacare.com

Supplier Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Manufacturer Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Issue Date: 01/19/05
Product Name: GLB Alkalinity Up
CAS Number: Not Established
Chemical Family: Alkali Salt
Chemical Formula: NaHCO3
MSDS Number: 48
2. Composition/Information On Ingredients
Ingredient
Name

CAS
Number

SODIUM BICARBONATE

Percent Of
Total Weight

144-55-8

Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials
determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as
carcinogens are listed if they comprise 0.1% of more of the composition. Information on proprietary materials is available
in 29CFR 1910.1200(i)(1).
3. Hazards Identification
Primary Routes(s) Of Entry
Skin Contact
Eye Hazards
Causes eye irritation.
Skin Hazards
Causes skin irritation.
Ingestion Hazards
Harmful if swallowed. If ingested, get immediate medical attention
Inhalation Hazards
May cause respiratory tract irritation.
Signs And Symptoms
none known

Page 1 of 5

MATERIAL SAFETY DATA

SHEET

GLB Alkalinity Up
First Aid (Pictograms)

4. First Aid Measures
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes.
Consult Physician.
Skin
Wash the affected area under tepid running water using a mild soap.
Ingestion
INDUCE VOMITING. Drink large amounts of water. Contact a physician or poison control.
Inhalation
If inhaled, remove to fresh air.
Fire Fighting (Pictograms)

5. Fire Fighting Measures
Flash Point: N/A °F
Flammability Class: NOT FLAMMABLE
Extinguishing Media
Use the appropriate extinguishing media for the surrounding fire.
Fire Fighting Instructions
Firefighters should wear self-contained breathing apparatus and full protective gear.
This material is used as a dry powder extinguishing agent for all classes of fires
6. Accidental Release Measures

Sweep up and remove immediately. Collect and dispose.
7. Handling And Storage
Handling And Storage Precautions
Keep out of reach of children. Do not store with acids. Keep containers tightly closed. Store material in a cool and
dry place.
Handling Precautions
Avoid contact with eyes.
Storage Precautions
Keep away from acids. Store in a cool dry place.
Work/Hygienic Practices
Use safe chemical handling procedures suitable for the hazards presended by this material.

Page 2 of 5

MATERIAL SAFETY DATA

SHEET

GLB Alkalinity Up
Protective Clothing (Pictograms)

8. Exposure Controls/Personal Protection
Engineering Controls
Use with adequate general and local exhaust ventilation.
Eye/Face Protection
Safety glasses with side shields or goggles recommended.
Skin Protection
Chemical-resistant gloves.
Respiratory Protection
None normally required. If dust accumulation is a problem a dust mask is suggested.
9. Physical And Chemical Properties
Appearance
White Granules
Odor
None
Chemical Type: Mixture
Physical State: Solid
Melting Point: DECOMPOSES °F
Boiling Point: DECOMPOSES °F
Percent Volitales: NOT APPLICABLE
Percent VOCs: NOT APPLICABLE
Vapor Pressure: NOT APPLICABLE
Vapor Density: NOT APPLICABLE
pH Factor: 8.5 At a Concentration Of 1% SOLUTION IN WATER
Solubility: 9.6G/100ML AT 20C IN WATER
Viscosity: NOT APPLICABLE
Evaporation Rate: NOT APPLICABLE
10. Stability And Reactivity
Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid (Stability)
High Humidity Causes Caking
Incompatible Materials
All Acids
Hazardous Decomposition Products
CO2
11. Toxicological Information
Acute Oral Effects
LD50 mg/kg Rat >4.22g/kg MAY CAUSE IRRITATION OF EYES AND RESPIATORY PASSAGES.
INGESTATION MAY CAUSE GASTROINTESTINAL IRRITATION

Page 3 of 5

MATERIAL SAFETY DATA

SHEET

GLB Alkalinity Up
12. Ecological Information
No Data Available...
13. Disposal Considerations

Dispose in accordance with applicable federal, state and local government regulations.
14. Transport Information
Proper Shipping Name
NOT REGULATED
Hazard Class
NOT REGULATED
Secondary Hazard Class
NOT REGULATED
DOT Identification Number
NONE
DOT Shipping Label
NOT ASSIGNED
Freight Class
NOT REGULATED
Packaging Requirements
NOT REGULATED
15. Regulatory Information
State Regulations
Sodium Bicarbonate is considered a hazardous waste in California
Canadian Regulatory Information
Class D, Div 2b - Poisonous or Infectious Material: other toxic effects
NFPA

HMIS

0
0

0

HEALTH

0

FLAMMABILITY

0

REACTIVITY

0

PERSONAL PROTECTION

E

16. Other Information
Revision/Preparer Information
MSDS Preparer: JHW3
This MSDS Superceeds A Previous MSDS Dated: 07/26/2000
Disclaimer
Although reasonable care has been taken in the preparation of this document, we extend no warranties
and make no representations as to the accuracy or completeness of the information contained therein,
and assume no responsibility regarding the suitablility of this information for the user's intended
purposes or for the consequences of its use. Each individual should make a determination as to the
suitability of the information for their particular purposes(s).

Page 4 of 5

MATERIAL SAFETY DATA
GLB Alkalinity Up
Disclaimer - Continued
GLB
Printed Using MSDS Generator™ 2000

Page 5 of 5

SHEET

MATERIAL SAFETY DATA

SHEET

GLB Clear Blue

1. Product And Company Identification
Supplier
GLB
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Manufacturer
Advantis Technologies, Inc.
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Telephone Number: (770)521-5999
FAX Number: (770)521-5959
Web Site: www.poolspacare.com

Telephone Number: (770) 521-5999
FAX Number: (770) 521-5959
Web Site: www.poolspacare.com

Supplier Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Manufacturer Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Issue Date: 02/08/2006
Product Name: GLB Clear Blue
Chemical Name: Catonic Polyamide in water
CAS Number: Not Established
Chemical Formula: Proprietery
MSDS Number: 36
2. Composition/Information On Ingredients
Ingredient
Name

CAS
Number

Polydimethyldiallyammonium
Chloride

Percent Of
Total Weight

26062-79-3

Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials
determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as
carcinogens are listed if they comprise 0.1% or more of the composition. Information on proprietary materials is available in
29CFR 1910.1200(i)(1).
3. Hazards Identification
Primary Routes(s) Of Entry
Skin Contact
Eye Hazards
May cause eye irritation.
Skin Hazards
May cause skin irritation. Non-sensitizer for skin.
Ingestion Hazards
Harmful if swallowed.
Inhalation Hazards
Slightly hazardous in case of inhalation.
Signs And Symptoms
Irritant to eyes and skin
4. First Aid Measures
No Data Available...

Page 1 of 4

MATERIAL SAFETY DATA

SHEET

GLB Clear Blue
4. First Aid Measures - Continued
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes.
Skin
Remove contaminated clothing and shoes.Rinse the affected area with tepid water for at least 15 minutes.
Ingestion
DO NOT INDUCE VOMITING. Drink large amounts of water or milk. Contact a physician or poison control. In cases
where individual is semi-comatose, comatose, or convulsing, DO NOT GIVE FLUIDS BY MOUTH.
Inhalation
If inhaled, remove to fresh air.
Fire Fighting (Pictograms)

5. Fire Fighting Measures
Flash Point: >100 °C
Flash Point Method: Closed Cup
Flammability Class: NOT FLAMMABLE
Fire And Explosion Hazards
In a fire situation, may liberate oxides of nitrogen or carbon, and hydrogen chloride.
Extinguishing Media
Use the appropriate extinguishing media for the surrounding fire.
Fire Fighting Instructions
CAUTION Surfaces wet with this product are slippery. Keep containers cool by spraying with water if exposed to
fire.
6. Accidental Release Measures
Clean up spill immediately. Contain and/or absorb spill with inert material (e.g. sand, vermiculite). Flush spill area with
water. Use appropriate containers to avoid environmental contamination.
CAUTION Surfaces wet with this product are slippery.
7. Handling And Storage
Handling And Storage Precautions
Keep out of reach of children. Store material in a cool and dry place. Wash thoroughly after handling.
Storage Precautions
Avoid contact with skin and clothing.
Work/Hygienic Practices
Wash thoroughly with soap and water after handling.

Page 2 of 4

MATERIAL SAFETY DATA

SHEET

GLB Clear Blue
7. Handling And Storage - Continued
Protective Clothing (Pictograms)

8. Exposure Controls/Personal Protection
Engineering Controls
Local exhaust acceptable. Special exhaust not required.
Eye/Face Protection
Safety glasses with side shields or goggles recommended.
Skin Protection
Chemical-resistant gloves.
Respiratory Protection
None normally required.
9. Physical And Chemical Properties
Appearance
Clear Blue
Odor
Mild amine
Chemical Type: Mixture
Physical State: Liquid
Melting Point: NOT APPLICABLE °F
Boiling Point: 212 °F
Specific Gravity: 1.0-1.1
Molecular Weight: Proprietary
Percent Volitales: NEGLIGIBLE
Packing Density: NOT DETERMINED
Vapor Pressure: NOT DETERMINED
Vapor Density: NOT DETERMINED
pH Factor: 2-3
Solubility: Soluble in Water
Viscosity: NOT DETERMINED
Evaporation Rate: <1
10. Stability And Reactivity
Sta bility: Stable
Hazardous Polymerization: will not occur
Conditions To Avoid (Stability)
Strong Oxidizers
Incompatible Materials
Avoid contact with strong oxidizers
Hazardous Decomposition Products
When heated toxic fumes such as Oxides of Carbon, Nitrogen and Hydrogen chloride may be present

Page 3 of 4

MATERIAL SAFETY DATA

SHEET

GLB Clear Blue
11. Toxicological Information
No Data Available...
12. Ecological Information
No Data Available...
13. Disposal Considerations
Refer to applicable federal, state, and local regulations prior to disposition of container and residual contents.
14. Transport Information
Proper Shipping Name
NOT REGULATED
Hazard Class
NONE ASSIGNED
DOT Identification Number
NONE
15. Regulatory Information
No Data Available...
NFPA

HMIS

0
1

0

HEALTH

1

FLAMMABILITY

0

REACTIVITY

0

PERSONAL

B

PROTECTION

16. Other Information
Revision/Preparer Information
MSDS Preparer: JHW
This MSDS Superceeds A Previous MSDS Dated: 07/24/2000
Disclaimer
Although reasonable care has been taken in the preparation of this document, we extend no warranties
and make no representations as to the accuracy or completeness of the information contained therein,
and assume no responsibility regarding the suitablility of this information for the user's intended purposes
or for the consequences of its use. Each individual should make a determination as to the suitability of
the information for their particular purposes(s).
GLB
Printed Using MSDS Generator™ 2000

Page 4 of 4

MATERIAL SAFETY DATA

SHEET
Page 1 of 5

GLB Filter Cleanse

1. Product And Company Identification
Supplier
GLB
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Manufacturer
Advantis Technologies, Inc.
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Telephone Number: (770)521-5999
FAX Number: (770)521-5959
Web Site: www.poolspacare.com

Telephone Number: (770) 521-5999
FAX Number: (770) 521-5959
Web Site: www.poolspacare.com

Supplier Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Manufacturer Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Issue Date: 05/05/2004
Product Name: GLB Filter Cleanse
Chemical Name: Acid surfactant cleaner
Chemical Family: Acid
Chemical Formula: Proprietary Mixture
MSDS Number: 116
2. Composition/Information On Ingredients
Ingredient
Name

CAS
Number

CITRICACID

Percent Of
Total Weight

77-92-9

SODIUMBISULFATE

7681-38-1

Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials
determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as
carcinogens are listed if they comprise 0.1% or more of the composition. Information on proprietary materials is available in
29CFR 1910.1200(i)(1).
EMERGENCY OVERVIEW
Corrosive to eyes skin and respiatory tract.
Hazards Identification (Pictograms)

3. Hazards Identification
Primary Routes(s) Of Entry
Skin Contact
Eye Hazards
Causes eye damage.
Skin Hazards
May cause skin irritation.
Ingestion Hazards
Harmful if swallowed.

MATERIAL SAFETY DATA

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Page 2 of 5

GLB Filter Cleanse
3. Hazards Identification - Continued
Inhalation Hazards
Causes respiratory tract irritation.
Signs And Symptoms
Irritation of Eyes, Skin and Respiratory Passages
First Aid (Pictograms)

4. First Aid Measures
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Call a
physician or a poison control center immediately.
Skin
In case of contact, immediately flush skin with soap and plenty of water. Remove contaminated clothing and shoes.
Ingestion
DO NOT INDUCE VOMITING. Call a physician or a poison control center immediately. If victim is fully conscious,
give one or two cups of water or milk to drink.
Inhalation
If breathing is difficult, give oxygen. If inhaled, remove to fresh air.
Fire Fighting (Pictograms)

5. Fire Fighting Measures
Flash Point: N/A °F
Fire And Explosion Hazards
At temperatures in excess of 570 F, hazardous fumes of sulfur dioxide and sulfur trioxide are evolved. Use forced
draft ventilation or gas mask.
Extinguishing Media
Use the appropriate extinguishing media for the surrounding fire.
Fire Fighting Instructions
Firefighters should wear self-contained breathing apparatus and full protective gear. Water can be used to cool and
protect exposed material.
6. Accidental Release Measures
Clean up spill immediately. Neutralize spill area with soda ash or lime. Flush spill area with water. Use appropriate
containers to avoid environmental contamination.

MATERIAL SAFETY DATA

SHEET

GLB Filter Cleanse
Handling & Storage (Pictograms)

7. Handling And Storage
Handling And Storage Precautions
Keep out of reach of children. Store material in a cool and dry place. Keep containers tightly closed.
Handling Precautions
Use only with adequate personal protection.
Storage Precautions
Store in a cool dry place.
Work/Hygienic Practices
Use safe chemical handling procedures suitable for the hazards presended by this material.
Avoid contact with eyes. Solutions of this material are acidic and strongly irritating. Will attack most metals.
Protective Clothing (Pictograms)

8. Exposure Controls/Personal Protection
Engineering Controls
Local exhaust acceptable. Special exhaust not required
Eye/Face Protection
Safety glasses with side shields or goggles recommended.
Skin Protection
Chemical-resistant gloves.
Respiratory Protection
None normally required.
9. Physical And Chemical Properties
Appearance
Purple to Red Granular
Odor
Slightly Acidic
Chemical Type: Mixture
Physical State: Solid
Melting Point: n/a °F
Boiling Point: 220 °F
Specific Gravity: 1.30
Molecular Weight: NOT DETERMINED
Percent Volitales: NOT DETERMINED
Vapor Pressure: NOT DETERMINED
pH Factor: <1 At a Concentration Of 1% solution in water
Solubility: <30%

Page 3 of 5

MATERIAL SAFETY DATA

SHEET

Page 4 of 5

GLB Filter Cleanse
10. Stability And Reactivity
Sta bility: Stable
Hazardous Polymerization: Will not occur.
Incompatible Materials
Oxidizers, Cyanides, Sulfides, Strong Alkaline or caustic material.
Hazardous Decomposition Products
At Temperatures in excess of 570F Hazardous fumes of Sulfur Dioxide and Sulfer Trioxide are evolved.
11. Toxicological Information
No Data Available...
12. Ecological Information
No Data Available...
13. Disposal Considerations
Dispose in accordance with applicable federal, state and local government regulations.
14. Transport Information
Proper Shipping Name
NOT REGULATED
Hazard Class
NOT REGULATED
DOT Identification Number
NONE
15. Regulatory Information
Ingredient(s) - State Regulations
SODIUM BISULFATE
New Jersey - Workplace Hazard
New Jersey - Special Hazard
New York City - Hazardous Substance
NFPA

HMIS

0
1

1

HEALTH

1

FLAMMABILITY

0

REACTIVITY

1

PERSONAL

F

PROTECTION

16. Other Information
Revision/Preparer Information
MSDS Preparer: JHW
This MSDS Superceeds A Previous MSDS Dated: 11/03/2000
Disclaimer
Although reasonable care has been taken in the preparation of this document, we extend no warranties
and make no representations as to the accuracy or completeness of the information contained therein,
and assume no responsibility regarding the suitablility of this information for the user's intended purposes
or for the consequences of its use. Each individual should make a determination as to the suitability of
the information for their particular purposes(s).

MATERIAL SAFETY DATA

SHEET

GLB Filter Cleanse
Disclaimer - Continued
GLB
Printed Using MSDS Generator™ 2000

Page 5 of 5

Product #SASH, SAL*

Page 1 of 7

MATERIAL SAFETY DATA SHEET

Sodium Carbonate
Section 01 - Chemical And Product And Company Information
Product Identifier ……………………... Sodium Carbonate (Soda Ash)
Product Use …………………………..... Glass manufacture, detergent manufacture, sodium chemical
manufacture, carbonate chemicals manufacture, pulp and paper, brine
treatment,water hardness removal, pH adjustment in water or waste
water, flue gas desulfurization, coal treatment, ion exchange resin
regeneration
Supplier Name……………………….…. ClearTech Industries Inc.
2302 Hanselman Avenue
Saskatoon, SK. Canada
S7L 5Z3
Prepared By................……………..….. ClearTech Industries Inc. Technical Department
Phone: (306)664-2522
Preparation Date.........…………….…... December 21, 2007
24-Hour Emergency Phone…………... 306-664-2522

Section 02 - Composition / Information on Ingredients
Hazardous Ingredients....………….... Sodium Carbonate

99.8%

CAS Number...................…….…….....Sodium Carbonate

497-19-8

Synonym (s)...................……………...Disodium carbonate, calcined soda, soda ash, lite soda ash, dense soda
ash, carbonic acid, disodium salt, sodium carbonate anhydrous

Product #SASH, SAL*

Page 2 of 7

Section 03 - Hazard Identification
Inhalation...................………….….... May cause upper respiratory tract irritation.
Skin Contact / Absorption…….…... May cause redness, swelling from prolonged contact, especially in hot
weather.
Eye Contact................………….….... Causes irritation, may burn eyes.
Ingestion.....................………………. Low acute oral toxicity. May cause nausea, vomiting, diarrhea, irritation,
and stomach ache.
Exposure Limits……………………... Treat as a nuisance particulate: TWA(OSHA)= 5mg/m3; TWA(Ontario
Ministry of Labour)= 10mg/m3

Section 04 - First Aid Measures
Inhalation....................……………….. Remove victim to fresh air. Give artificial respiration only if breathing has
stopped. If breathing is difficult, give oxygen. Seek immediate medical
attention.
Skin Contact / Absorption………….. Remove contaminated clothing. Wash affected area with soap and water.
Seek medical attention if irritation occurs or persists.
Eye Contact..................…………….... Flush immediately with water for at least 20 minutes. Forcibly hold eyelids
apart to ensure complete irrigation of eye tissue. Seek immediate medical
attention
Ingestion......................………………. Do not induce vomiting. If vomiting occurs, lean victim forward to prevent
breathing in vomitus. Give large amounts of water. Do not give anything
by mouth to an unconscious or convulsing person. Seek immediate
medical attention.
Additional Information.....…………... While internal toxicity is low, irritant effects of high concentrations may
produce corneal opacities, and vesicular skin reactions in humans with
abraded skin only. Treatment is symptomatic and supportive.

Section 05 - Fire Fighting
Conditions of Flammability……….... Non flammable
Means of Extinction........…………..... Product does not burn. Use appropriate extinguishing media for material
that is supplying the fuel to the fire.
Flash Point....………………………….. Not applicable

Product #SASH, SAL*

Page 3 of 7

Auto-ignition Temperature…………. Not applicable
Upper Flammable Limit …………….. Not applicable
Lower Flammable Limit...……….…... Not applicable
Hazardous Combustible Products... Heating sodium carbonate liberates CO2 and fumes of sodium oxide.
Special Fire Fighting Procedures..... Wear NIOSH-approved self-contained breathing apparatus and protective
clothing.
Explosion Hazards………………….... Not applicable

Section 06 - Accidental Release Measures
Leak / Spill................….……………... Wear appropriate personal protective equipment. Ventilate area. Stop or
reduce leak if safe to do so. Prevent material from entering sewers.
Deactivating Materials...……….…... Use an acid to neutralize after the soda ash has been made into a
solution.

Section 07 - Handling and Storage
Handling Procedures.......…………... Use proper equipment for lifting and transporting all containers. Use
sensible industrial hygiene and housekeeping practices. Wash thoroughly
after handling. Avoid all situations that could lead to harmful exposure.
Storage Requirements......……...….. Product is hygroscopic and tends to cake on s