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DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 1 of 7
Version: 1.3
Revision Date: 2006/01/23

DOW CORNING(R) HVAC/R SEALANT CLEAR
1. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY
24 Hour Emergency Telephone:
Customer Service:
Product Disposal Information:
CHEMTREC:

Dow Corning Corporation
South Saginaw Road
Midland, Michigan 48686

MSDS No.: 04045032

Revision Date: 2006/01/23

Generic Description:
Physical Form:
Color:
Odor:

Silicone elastomer
Paste
Colorless
Acetic acid odor

NFPA Profile: Health

2 Flammability

1 Instability/Reactivity

Note: NFPA = National Fire Protection Association

2. OSHA HAZARDOUS COMPONENTS
CAS Number

(989) 496-5900
(989) 496-6000
(989) 496-6315
(800) 424-9300

Wt %

Component Name

17689-77-9

1.0 - 5.0

Ethyltriacetoxysilane

4253-34-3

1.0 - 5.0

Methyltriacetoxysilane

The above components are hazardous as defined in 29 CFR 1910.1200.

3. HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
Acute Effects
Eye:

Direct contact may cause moderate irritation.

Skin:

May cause moderate irritation.

Inhalation:

Irritates respiratory passages very slightly.

Oral:

Low ingestion hazard in normal use.

Prolonged/Repeated Exposure Effects
Skin:

No known applicable information.

Inhalation:

No known applicable information.

Oral:

No known applicable information.

0

DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 2 of 7
Version: 1.3
Revision Date: 2006/01/23

DOW CORNING(R) HVAC/R SEALANT CLEAR
Signs and Symptoms of Overexposure
No known applicable information.
Medical Conditions Aggravated by Exposure
No known applicable information.
The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar compositions,
component data and/or expert review of the product. Please refer to Section 11 for the detailed toxicology information.

4. FIRST AID MEASURES
Eye:

Immediately flush with water for 15 minutes. Get medical attention.

Skin:

Remove from skin and wash thoroughly with soap and water or waterless cleanser. Get
medical attention if irritation or other ill effects develop or persist.

Inhalation:

No first aid should be needed.

Oral:

No first aid should be needed.

Comments:

Treat according to person's condition and specifics of exposure.

5. FIRE FIGHTING MEASURES
Flash Point:

Not applicable.

Autoignition Temperature:

Not determined.

Flammability Limits in Air:

Not determined.

Extinguishing Media:

On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide
(CO2), dry chemical or water spray. Water can be used to cool fire exposed containers.

Fire Fighting Measures:

Self-contained breathing apparatus and protective clothing should be worn in fighting large
fires involving chemicals. Determine the need to evacuate or isolate the area according to
your local emergency plan. Use water spray to keep fire exposed containers cool.

Unusual Fire Hazards:

None.

Hazardous Decomposition Products
Thermal breakdown of this product during fire or very high heat conditions may evolve the following hazardous
decomposition products: Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide.
Formaldehyde.

6. ACCIDENTAL RELEASE MEASURES

DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 3 of 7
Version: 1.3
Revision Date: 2006/01/23

DOW CORNING(R) HVAC/R SEALANT CLEAR
Containment/Clean up:

Observe all personal protection equipment recommendations described in Sections 5 and 8.
Wipe up or scrape up and contain for salvage or disposal. Clean area as appropriate since
spilled materials, even in small quantities, may present a slip hazard. Final cleaning may
require use of steam, solvents or detergents. Dispose of saturated absorbant or cleaning
materials appropriately, since spontaneous heating may occur. Local, state and federal laws
and regulations may apply to releases and disposal of this material, as well as those materials
and items employed in the cleanup of releases. You will need to determine which federal,
state and local laws and regulations are applicable. Sections 13 and 15 of this MSDS provide
information regarding certain federal and state requirements.

Note: See section 8 for Personal Protective Equipment for Spills. Call (989) 496-5900, if additional information is
required.

7. HANDLING AND STORAGE
Use with adequate ventilation. Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide
ventilation during use to control HOAc within exposure guidelines or use respiratory protection. Avoid eye contact.
Keep container closed and store away from water or moisture.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Component Exposure Limits
CAS Number

Component Name

Exposure Limits

17689-77-9

Ethyltriacetoxysilane

See acetic acid comments.

4253-34-3

Methyltriacetoxysilane

See acetic acid comments.

Acetic acid is formed upon contact with water or humid air. Provide adequate ventilation to control exposures within
guidelines of OSHA PEL: TWA 10 ppm and ACGIH TLV: TWA 10 ppm, STEL 15 ppm.
Engineering Controls
Local Ventilation:
General Ventilation:

None should be needed.
Recommended.

Personal Protective Equipment for Routine Handling
Eyes:

Use proper protection - safety glasses as a minimum.

Skin:

Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as
soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are
recommended.

Suitable Gloves:

Silver Shield(R). 4H(R).

DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 4 of 7
Version: 1.3
Revision Date: 2006/01/23

DOW CORNING(R) HVAC/R SEALANT CLEAR
Inhalation:

No respiratory protection should be needed.

Suitable Respirator:

None should be needed.

Personal Protective Equipment for Spills
Eyes:

Use proper protection - safety glasses as a minimum.

Skin:

Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as
soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are
recommended.

Inhalation/Suitable
Respirator:

No respiratory protection should be needed.

Precautionary Measures:

Avoid eye contact. Use reasonable care.

Comments:

Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide ventilation
during use to control HOAc within exposure guidelines or use respiratory protection.

Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require
added precautions.

9. PHYSICAL AND CHEMICAL PROPERTIES
Physical Form:
Color:
Odor:
Specific Gravity @ 25°C:
Viscosity:
Freezing/Melting Point:
Boiling Point:
Vapor Pressure @ 25°C:
Vapor Density:
Solubility in Water:
pH:
Volatile Content:

Paste
Colorless
Acetic acid odor
1.04
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.

Note: The above information is not intended for use in preparing product specifications. Contact Dow Corning before writing
specifications.

10. STABILITY AND REACTIVITY
Chemical Stability:

Stable.

Hazardous
Polymerization:
Conditions to Avoid:

Hazardous polymerization will not occur.
None.

DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 5 of 7
Version: 1.3
Revision Date: 2006/01/23

DOW CORNING(R) HVAC/R SEALANT CLEAR
Materials to Avoid:

Oxidizing material can cause a reaction. Water, moisture, or humid air can cause hazardous
vapors to form as described in Section 8.

11. TOXICOLOGICAL INFORMATION
Special Hazard Information on Components
No known applicable information.

12. ECOLOGICAL INFORMATION
Environmental Fate and Distribution
Complete information is not yet available.
Environmental Effects
Complete information is not yet available.
Fate and Effects in Waste Water Treatment Plants
Complete information is not yet available.

Hazard Parameters (LC50 or EC50)
Acute Aquatic Toxicity (mg/L)
Acute Terrestrial Toxicity

Ecotoxicity Classification Criteria
High
Medium
<=1
>1 and <=100
<=100
>100 and <= 2000

Low
>100
>2000

This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34, 1993.
This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information presented in the
section concerning the overall ecological safety of this material.

13. DISPOSAL CONSIDERATIONS
RCRA Hazard Class (40 CFR 261)
When a decision is made to discard this material, as received, is it classified as a hazardous waste? No
State or local laws may impose additional regulatory requirements regarding disposal.
Call (989) 496-6315, if additional information is required.
14. TRANSPORT INFORMATION
DOT Road Shipment Information (49 CFR 172.101)
Not subject to DOT.
Ocean Shipment (IMDG)

DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 6 of 7
Version: 1.3
Revision Date: 2006/01/23

DOW CORNING(R) HVAC/R SEALANT CLEAR
Not subject to IMDG code.
Air Shipment (IATA)
Not subject to IATA regulations.
Call Dow Corning Transportation, (989) 496-8577, if additional information is required.

15. REGULATORY INFORMATION
Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
TSCA Status:

All chemical substances in this material are included on or exempted from listing on the TSCA
Inventory of Chemical Substances.

EPA SARA Title III Chemical Listings
Section 302 Extremely Hazardous Substances (40 CFR 355):
None.

Section 304 CERCLA Hazardous Substances (40 CFR 302):
None.

Section 311/312 Hazard Class (40 CFR 370):
Acute: Yes
Chronic: No
Fire: No
Pressure: No
Reactive: No
Section 313 Toxic Chemicals (40 CFR 372):
None present or none present in regulated quantities.
Supplemental State Compliance Information
California
Warning: This product contains the following chemical(s) listed by the State of California under the Safe Drinking Water
and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer, birth defects or other
reproductive harm.
None known.
Massachusetts
CAS Number

Wt %

Component Name

DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 7 of 7
Version: 1.3
Revision Date: 2006/01/23

DOW CORNING(R) HVAC/R SEALANT CLEAR
7631-86-9

7.0 - 13.0

Silica, amorphous

CAS Number

Wt %

Component Name

70131-67-8

> 60.0

Dimethyl siloxane, hydroxy-terminated

7631-86-9

7.0 - 13.0

Silica, amorphous

17689-77-9

1.0 - 5.0

Ethyltriacetoxysilane

4253-34-3

1.0 - 5.0

Methyltriacetoxysilane

New Jersey

Pennsylvania
CAS Number

Wt %

Component Name

70131-67-8

> 60.0

Dimethyl siloxane, hydroxy-terminated

7631-86-9

7.0 - 13.0

Silica, amorphous

16. OTHER INFORMATION
Prepared by: Dow Corning Corporation
These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or
implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally
applicable. However, each user should review these recommendations in the specific context of the intended use and
determine whether they are appropriate.
(R) indicates Registered Trademark

MATERIAL SAFETY DATA SHEET
IDENTIFICATION
Name:
Chemical Family:
Formula:
Synonyms:
Hazard Class:
Other Identifying Data:

REFRIGERANT (R414b)
Halogenated Hydrocarbons
Mixture of CHClFCF3, CH3CClF2, CH(CH3)2-CH3, CHClF2
N/A
2.2
This product is a direct replacement for CFC-12 & HFC-134a,
without modification of the user's equipment.

CAS Name:
Chlorodifluoromethane
1-Chloro-1, 1-difluoroethane
Isobutane
2-Chloro-1,1,1,2-Tetrafluoroethane

CAS Registry No.
000075-45-6
000075-68-3
068476-85-7
002837-89-0

FIRE AND EXPLOSION DATA:
Flash point:
Flammability Classification:
Health Hazard Code:
Flammable Limits in Air
Extinguishing Media:

NA
will not burn
Nonhazardous
LEL: NA % UEL: NA %
Stop Flow of Gas, Use Class A Ext. Agent, Use Class B Ext. Agent,
Water may be used to blanket fire. EXPLODES ON HEATING
Unusual Fire/Explosion Hazards: Cylinders may vent or rupture in fire conditions, leading to
decomposition. Vapours may decompose if exposed to direct
flame conditions. The vapour may displace oxygen making
breathing difficult and causing light-headedness or suffocation.
Special Fire Fighting Procedures:The material is not flammable and does not support combustion.
The choice of fire extinguishing media depends on the
surrounding materials involved in the fire. Use self-contained
breathing apparatus and full protective gear. Use water spray to
cool fire-exposed containers.
HEALTH HAZARD INFORMATION:

Manufacturer / Distributor:
U.S.

Environment Specialty Products
10640 East 59th Street, PO Box 36626
841 Brock Rd. South,
Indianapolis IN 46236
Pickering ON LIW 3J2
EMER:1-800-457-4280 CHEMTREC, 24 Hrs
1-613-996-6666 CANUTEC, chemical emer. only
INFO: 1-800-497-6805 (weekdays 7:30am-4:00pm)1-800-495-4062 (weekdays 9:00am-5:00pm)

Immediate: The greatest hazard is contact with escaping gas which can cause frostbite and damage
to exposed tissue. The escaping gas may displace oxygen and cause light-headedness, eye irritation
and suffocation.
Long Term: Exposure to high concentrations may lead to cardiac irregularities, unconsciousness
or death.
Other Hazards: None listed

PHYSICAL DATA

FIRST AID

CANADA

ICOR International Inc

Boiling Point:
-29.8°F
Vapour Pressure:
NDA
Evaporation Rate:
NDA
( Butyl Acetate =1)
Vapour Density (Air =1) >1
very slight
Solubility in H2O:
Specific Gravity:
1.1

Pure or Mixture:
Melting Point (F):
pH:
Ignition Temperature:
Physical State:

Mixture
NDA
NA
1170°F
Gas

HAZARDOUS COMPONENTS:
Material(s):
Chlorodifluoromethane
1-Chloro-1, 1-difluoroethane
Isobutane
2-Chloro-1,1,1,2-Tetrafluoroethane

Approximate weight %
50
9.5
1.5
39

HAZARDOUS REACTIVITY: AVOID INTENSE HEAT AND OPEN FLAME
Stability: Material is normally stable. However, avoid open flames and high temperatures.
Incompatibility (materials to avoid): Strong oxidants, including oxygen, freshly scraped
aluminium, alkali metals, and alkali earth metals (sodium, magnesium, etc.) may cause exothermic
reaction. The aluminum in refrigeration systems contains an oxide/chloride coating to prevent
reaction with metal.
Hazardous decomposition products:
Hydrofluoric and hydrochloric acids, chlorine, fluorine, possibly phosgene, carbon dioxide, and
carbon monoxide.
Polymerization: Will not occur.
Other Reactivity Data: Cylinders of used product may contain oil as well as refrigerant. A liquid
leak or venting during a fire will produce a cloud of oil mist that is very flammable.

Inhalation: Remove to fresh air, call a physician. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do not give epinephrine or similar drugs.
Note to physicians: Because of possible increased risk or eliciting cardiac dysrythmias, catecholamine
drugs, such as epinephrine, should be considered only as a last resort in life threatening emergencies.

Eyes: Flush immediately with water for at least 15 minutes. Call a physician.
Skin: Warm the area gradually by flushing with plenty of water. Call a physician
Swallowed: DO NOT INDUCE VOMITTING, Call a physician
Medical Conditions Aggravated by Exposure: Persons subject to cardiac problems may be at
increased risk by exposure.
PRECAUTIONS / PROCEDURES:
Spill or leak: Remove or extinguish ignition or combustion sources. Evacuate enclosed spaces
until gas is dispersed. Keep upwind. Stop the release of gas, if possible without risk. Disperse the
gas with floor level forced-air ventilation. Exhaust vapours outdoors. Contain the spill by building
a dike using absorbent material. Collect the remainder of the spill with absorbent material and
place into a drum for waster disposal or recovery. Wash contaminated clothing before reuse.
Work/Hygiene Practices: Use insulated or lined butyl gloves, face shield or goggles, and
impervious clothing.
Special Measures: Good general ventilation is usually adequate, but local ventilation may be
needed if gas is vented to atmosphere. Use self-contained breathing apparatus if local ventilation is
not adequate.
SHIPPING INFORMATION:
DOT

Other information:

Proper shipping name: LIQUEFIED GAS, N.O.S.
Hazard Class: 2.2
DOT Identification: UN3163
Do not heat above 120°F
Date revised: 03-01-04

MATERIAL SAFETY DATA SHEET
NFPA SYMBOL
HMIS
SEVERE 4
SERIOUS
MODERATE
SLIGHT
MINIMAL

HMIS SYMBOL
HEALTH
1
FLAMMABILITY 1
REACTIVITY
0

NFPA
EXTREME
FIRE
3
HIGH
2
MODERATE
1
SLIGHT
TOXICITY
0
INSIGNIFICANT

1
1

REACTIVITY
0
SPECIAL

MAY BE USED TO COMPLY WITH OSHA’S HAZARD
COMMUNICATIONS STANDSRD (HSC) 29 CFR 1910.1200
==================================================================================
SECTION I - PRODUCT IDENTIFICATION
==================================================================================
Product name / Identity : ZOOM-SPOUT OILER DO-1
A-1 Components Product Code #:
6403
Product use : Oil
Chemical family : Petroleum Hydrocarbonate
Supplier name and address :
Manufacturer name and address:
A-1 COMPONENTS CORP.
625 West 18th St.
Hialeah, Florida 33010
Phone # : (305) 885-1911

Same as
Supplier

Emergency Telephone Numbers, 24-hour :

INFOTRAC 1-800-535-5053

WHMIS CLASS: D2B
==================================================================================
SECTION II - HAZARDOUS INGREDIENTS
==================================================================================
LC50 ppm
LD50 mg/kg
Ingredients
CAS #
wt.%
(Rat, ihl.)
(Rat, oral)
Oil mist

64742-65-0

95-99.99

n/av

n/av

==================================================================================
SECTION III - PHYSICAL DATA
==================================================================================
Physical State : Liquid
Odor and appearance : Clear, yellow characteristic odor.
Odor threshold : n/ap
Specific gravity : 0.866
Coefficient of water/oil distribution : n/av
Vapor pressure (mm Hg at 20oC) : n/av
Boiling point : above 555°F (291°C)
Freezing/Melting Point : n/av
pH : n/ap
Vapor density (Air = 1) : Heavier than air
Evaporation rate (BuAe = 1) : Slower than ether
Volatiles, wt.% : Negligible
Viscosity: 31.5 CST, @ 40°C
Solubility in water: Negligible

TELE-SPOUT OILER DO-1

==================================================================================
SECTION IV - FIRE AND EXPLOSION DATA
==================================================================================
Conditions of flammability :. This material will burn but will not ignite readily.
Means of extinction : Dry chemical, CO@, water spray, foam, sand or earth. Water or foam may cause frothing.
Sensitivity to mechanical impact/static discharge : n/av
Flash point (Method) : 365°F (202°C) (COC)
Upper flammable limit % : n/ap
Lower flammable limit % : n/ap
Auto-ignition temperature : n/ap
Special Fire Fighting Procedures: Water spray may be useful in minimizing vapors and cooling containers
exposed to heat and flame. Avoid spreading burning liquid with water used for cooling purposes. Move
undamaged containers from fire area if you can do so without risk.
Hazardous Combustion Products: Refer to "Hazardous Decomposition Products".
Unusual Fire and Explosion Hazards:
==================================================================================
SECTION V - REACTIVITY DATA
==================================================================================
Stability : Stable under ambient pressure and temperature. Hazardous polymerization will not occur.
Incompatible materials : Strong oxidizing agents. Avoid contact with any source of ignition. Extended exposure
to hugh temperatures may cause decomposition.
Conditions of reactivity: n/ap
Hazardous decomposition products : Thermal decomposition in the presence of air may yield major amounts
of oxides of carbon and minor amounts of oxides of sulphur and nitrogen.
==================================================================================
SECTION VI - TOXICOLOGICAL PROPERTIES
==================================================================================
*** Routes of exposure and acute/chronic effects ***
Exposure limit : TLV-TWA Oil mist 5 mg/m3
Irritancy of Product: Inhalation, ingestion, skin and eye contact.
Inhalation : Exposure of mists, or prolonged or repeated exposure to fumes or vapors that may be generated
when this material is heated, may cause irritation of nose and throat..
Skin :This material can cause skin irritation. Prolonged or repeated contact may cause redness, burning, or
dermatitis.
Eyes : This material may cause eye irritation. Direct contact may cause burning, tearing, and redness.
Ingestion : Accidental ingestion of this material may cause irritation of the digestive tract.
Chronic effects : None.
Carcinogenicity: Not listed by IARC and ACGIH as carcinogenic.
Reproductive effects, Teratogenicity, Mutagenicity: n/av.
Sensitization to Product: None known.
Name of Toxicologically Synergistic Products: n/av

TELE-SPOUT OILER DO-1

==================================================================================
SECTION VII FIRST AID
==================================================================================
Inhalation : Move victim from source of exposure if irritation of nose or throat develops. If symptoms of exposure
develop, seek medical attention. If victim is not breathing, artificial respiration should be administered. Seek
medical attention immediately.
Eyes : Immediately move victim away from exposure. For direct contact, flush the affected eye(s) with clean
water for at least 15 minutes. Seek medical attention immediately.
Skin : Do not use gasoline, thinners or solvents to remove product from skin. Wipe material from skin and
remove contaminated clothing. Cleanse affected area thoroughly with soap and water if necessarily a waterless
hand cleaner. . If irritation or redness develops and persists, seek medical attention immediately.
Ingestion : If victim is conscious and alert, give 2 to 3 cups of water or milk to drink. Seek medical attention
immediately.
NOTE TO PHYSICIAN: Emesis of lavage is not recommended for ingestions of minute quantities or
tastes of most hydrocarbons. Medical opinion is divided for large ingestions. Emesis of lavage has been
recommended for these petroleum products which have a high oral toxicity. Gastric lavage with a cuffed
endotracheal tube is recommended by some physicians to prevent aspiration.
==================================================================================
SECTION VIII - PREVENTIVE MEASURES
==================================================================================
Spill, leak or release : Collect leaking fluid in sealable containers. Absorb spilled liquid in sand or inert
absorbant. Contact fire authorities and appropriate local/provincial agencies.
Waste disposal : Review federal, provincial and local government requirements prior to disposal.
*** PROTECTIVE EQUIPMENT ***
Respiratory protection : If airborne concentrations exceed recommended exposure limits, a suitable filter-type
respirator should be worn.
Ventilation : If current ventilation practices are not adequate to maintain airborne concentration below
established exposure limits (see Section VI), additional ventilation or exhaust system may be required.
Protective gloves : Impermeable to the specific material handled is advised to prevent skin contact and possible
irritation.
Eye protection : Approved eye protection to safeguard against potential eye contact.
Other protective equipment : Eye wash and quick drench shower facilities should be available in the work area.
Barrier creams that are specific for oil-based materials are recommended when gloves are impractical.
*** STORAGE & HANDLING ***
Storage and handling conditions :
Handling: Avoid generating oil mists while handling. Avoid prolonged or repeated skin contact. wash thoroughly
after handling. Do not wear oil-soaked clothing or shoes.
Storage: Store in a cool, dry location. Store in original container. Keep container closed when not in use.
Special Shipping Information: TDG - Not Regulated
==================================================================================
Additional notes or references :
Abbreviations :
n/av : not available
n/ap : not applicable
IARC : International Agency for Research on Cancer
ACGIH : American Conference of Governmental Industrial Hygienists
TLV : Threshold Limit Values
NIOSH: National Institute of Occupational Safety and Health
STEL: Short Term Exposure Limit
TDG : Transportation of Dangerous Goods Act.
References :
1. ACGIH, Threshold Limit Values and Biological Exposure Indices for 1993-94.
2. International Agency for Research on Cancer Monographs, Supplement 7, 1988.
3. Canadian Centre for Occupational Health and Safety. Cheminfo Database.
4. N. Irving Sax. Dangerous Properties of Industrial Materials. Seventh Edition.
==================================================================================
SECTION IX PREPARATION INFORMATION
==================================================================================
Prepared by : A-1 COMPONENTS CORP.
Telephone # : (305) 885-1911
Preparation date : December 16, 2005

TELE-SPOUT OILER DO-1

CATALOG NO. PT-200, PT-236

MATERIAL SAFETY DATA SHEET
PRO-TREAT 200
SECTION I-IDENTIFICATION

HAZARD RATINGS
HMIS DATA
HEALTH 2
0=MINIMAL
FIRE
1
1=SLIGHT
REACTIVITY 1 2 =MODERATE
3=HIGH
4=EXTREME
Personal Protection Index B

MANUFACTURED BY: Diversitech, Inc
ADDRESS: 2530 Lantrac Court
Decatur, GA 30035
EMERGENCY Phone No. 800-255-3924 Chem-Tel (Chemical Emergencies Only)
PHONE NUMBER FOR INFORMATION: 800-995-2222
DATE REVISED: 3/29/2006
NAME OF PREPARER: ANTHONY E. JERNIGAN
INGREDIENT

SECTION II HAZARDOUS INGREDIENTS INFORMATION
CAS NO
OSHA
ACIGH
OTHER
PEL
TLV
STEL

Tetradecyl
Dimethylbenzyl ammonium chloride 139-08-2

LD50: 18 mg/kg (mouse)

% or
RNG
<25%

SECTION III – PHYSICAL/CHEMICAL CHARACTERISTICS
Boiling Point: >112°C
Specific gravity (H2O = 1): 1.-25-1.35
Vapor pressure (mm Hg): < 0.1
Melting Point (Pour Point): >40°C
Vapor Density (Air = 1): N/A
Evaporation Rate (Water = 1): N/A
Solubility in water: 100
Appearance and odor: Blue tablet with a characteristic cationic surfactant odor.
SECTION IV- FIRE AND EXPLOSION HAZARD DATA
Flash Point (Method Used): None

Flammable Limits: None

Extinguishing media: Not applicable
Special Fire Fighting Procedures: Keep containers cooled with a water spray if involved in a fire.
Unusual Fire and Explosion Hazards: This product may evolve toxic fumes (ammonia, hydrogen
chloride if heated to decomposition.
Stability-Stable

SECTION V – REACTIVITY DATA
Conditions to avoid: None

Incompatibility (Materials to avoid): Strong oxidizers, strong acids, formaldehyde, anionic surfactants &
soap
Hazardous Decomposition or Byproducts: May evolve carbon monoxide, carbon dioxide, hydrogen
chloride, ammonia gas and other unidentified fragments if this product is involved in a fire.
Hazardous Polymerization: Will not occur.

1

PRO-TREAT 200 MSDS
SECTION VI– HEALTH HAZARD DATA
Routes of Entry: Inhalation: no Skin: yes Ingestion: yes Eyes: yes
Health Hazards (acute and chronic): Pro-Treat 200 is moderately toxic if ingested. Eye contact causes
extreme irritation. May cause skin irritation in sensitive individuals.
Carcinogenicity: NTP? No IARC Monographs? No OSHA Regulated? No
Signs and symptoms of exposure:
Inhalation: Dust may cause chemical pnuemonitis. This product is not toxic by
inhalation.
Skin: Minimally irritating. Prolonged contact may cause dermatitis or drying of skin.
Ingestion: Do not take internally. If ingested, it may damage
throat and digestive tissue. Swallowing may cause diarrhea, nausea, vomiting, unconsciousness.
Eyes: May cause severe eye irritation, permanent damage or blindness.
Medical Conditions Aggravated by Exposure: Contact with skin or eyes, or breathing dust can cause eye
skin or tissue damage or affect individuals with respiratory disorders.
Emergency and First Aid Procedures:
Eyes: Flush with water for 15 minutes. Consult a physician if irritation persists
Skin: Remove contaminated clothing. Wash the affected area with soap and water. Launder or dry
clean clothes before reuse..
Inhalation: Evacuate to a safe area with plenty of fresh air. Allow the affected individual to rest in a well
ventilated area, then seek medical aid immediately.
Ingestion: DO NOT induce vomiting. Force fluids. Contact the nearest Poison Control Center
SECTION VII – PRECAUTIONS FOR SAFE HANDLING AND STORAGE
STEPS TO BE TAKEN IF MATERIAL IS SPILLED OR RELEASED:
Wear recommended protective clothing. Remove contaminated garments promptly. Sweep up tablets and
dispose of contaminated product in accordance with local, state, and federal regulations. Undamaged
product may be recovered and used according to label instructions.
DO NOT contaminate municipal sewers or other open bodies of water with runoff form cleanup.
WASTE DISPOSAL METHODS: Incinerate this material and all associated wastes, or bury in an approved
landfill in accordance with governmental regulations.
HANDLING AND STORAGE:
Avoid contact with skin and eyes. Avoid breathing dust. Keep containers closed when not in use. Store in a
dry, cool, area
Empty containers may retain residue. All containers should be disposed of in an environmentally safe
manner, and in accordance with all governmental regulations.
Keep this and all chemicals out of the reach of children.

2

PRO-TREAT 200 MSDS
SECTION VIII – CONTROL MEASURES
Respiratory Protection (Specify Type): Use in a well-ventilated area. If dust is being generated and
exceeds the TLV, a respiratory program meeting OSHA 1910.134 and ANSI Z88.2 requirements must be
followed.
Ventilation: Local exhaust is recommended when used in enclosed areas.
Protective Gloves: Neoprene, latex or other materials may be used if there is documented evidence of
compatibility.
Eye protection: Safety glasses (ANSI Z87.1) or approved equivalent as necessary to minimize eye contact
hazards.
Other Protective Clothing: Neoprene aprons, overshoes, oversleeves or other impervious clothing as
necessary to minimize exposure.
Work Hygienic Practices: Use proper industrial hygiene practices to minimize hazardous exposure. Wash
hands after handling this material, and before eating or smoking.

SECTION IX – ADDITIONAL INFORMATION
Transportation Information:
DOT HAZARD LABEL: None
DOT Description: Cleaning Compound, NOI, other than liquid
TSCA: All ingredients are TSCA listed
SARA TITLE III Reporting Requirements:
Section 302: EHS reporting not required
Section 304: Hazardous releases reporting not required
Section 311: Community Right To Know reporting is required if the inventory is above the Threshold
Planning Quantity.
Section 312: R-T-K Inventory data reporting is not required.
Section 313: Emissions and release reporting may be required for users of this product within the
manufacturing sector. This does not apply to service companies.
This information is, to the best of our knowledge and belief, accurate and reliable as of the date
completed. However no representation, warranty or guarantee is made as to its accuracy, reliability or
completeness. It is the user’s responsibility to satisfy himself as to the completeness and suitability of
such information for his own particular use. We do not accept liability for any loss or damage that may
occur from the use of this information, nor do we offer any warranty against patent infringement

3

MATERIAL SAFETY DATA SHEET
MSDS 0165
=============================================================================
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
----------------------------------------------------------------------------HMIS CODES
PRODUCT NAME
Health
1
Acid - Away
Flammability
2
Reactivity
0
PRODUCT CODES
PPI
B
45004,45010
CHEMICAL FAMILY:
Organic
USE
Compressor Burnout Acid Neutralizer
MANUFACTURER'S NAME
EMERGENCY TELEPHONE NO.
The RectorSeal Corporation
Chemtrec 24 Hours
2601 Spenwick Drive
(800) 424-9300
Houston, Texas 77055 USA
VALIDATION DATE
TECHNICAL SERVICE TELEPHONE NO.
June 14, 2006
(800) 231-3345
REVISION DATE
June 14, 2006
=============================================================================
Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
----------------------------------------------------------------------------% by WT
CAS No. INGREDIENT
UNITS
-64742-44-5 Petroleum Oil
ACGIH TLV
5 mg/m3
OSHA PEL
5 mg/m3
=============================================================================
Section 3 -- HAZARDS IDENTIFICATION
----------------------------------------------------------------------------SUMMARY OF ACUTE HAZARDS
Repeated inhalation may cause dizziness and nausea. Ingestion may cause
cramps and diarrhea.
ROUTE OF EXPOSURE, SIGNS AND SYMPTOMS
INHALATION
Upper respiratory tract irritation and dizziness.
EYE CONTACT
Irritation, watering may occur.
SKIN CONTACT
Frequent or prolonged contact may irritate and cause dermatitis.
INGESTION
May cause nausea, vomiting and gastro-intestinal irritation.
SUMMARY OF CHRONIC HAZARDS
Prolonged skin contact may result in irritation and dermatitis.
Prolonged eye contact may result in irritation or chemical burns.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Individuals with pre-existing or chronic diseases of the eyes, skin
or persons with chemical sensitivity may have increased susceptibility to
excessive exposures.
=============================================================================
Section 4 -- FIRST AID MEASURES
----------------------------------------------------------------------------If INHALED:
If overcome by exposure, remove victim to fresh air
immediately. Give oxygen or artificial respiration as
needed. Obtain emergency medical attention. Prompt action
is essential.

If on SKIN:

Wash with soap and water. Remove contaminated clothing.
If irritation occurs, seek medical attention.
If in EYES:
Flush with large amounts of water for at least 15 minutes.
Get medical attention if irritation persists.
If SWALLOWED:
If swallowed, call a physician immediately. Only induce
vomiting at the instruction of a physician. Never give
anything by mouth to an unconscious person.
=============================================================================
Section 5 -- FIRE FIGHTING MEASURES
----------------------------------------------------------------------------FLASH POINT
LEL
UEL
>148 F (64 C) SETA CC
N/D
N/D
EXTINGUSING MEDIA
Foam, dry chemical, carbon dioxide or water fog.
SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus
(SCBA) and other protective clothing. Hazardous decomposition products
possible (see Section 10).
UNUSUAL FIRE AND EXPLOSION HAZARDS: Combustible - moderate flash point.
Heat may build up pressure and rupture closed containers.
=============================================================================
Section 6 -- ACCIDENTAL RELEASE MEASURES
----------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove all sources
of ignition. Use absorbent materials to prevent footing hazard and to
contain. Ventilate area with natural or explosion-proof, forced air
ventilation. Avoid flushing into sewers, drains, waterways, and soil.
Wear protective clothing and respiratory protection during cleanup.
=============================================================================
Section 7 -- HANDLING AND STORAGE
----------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed and
upright when not in use. Do not store near heat, sparks, or open flames.
OTHER PRECAUTIONS: Avoid prolonged or repeated contact with skin or
clothing. Empty containers may contain residues; treat as if full and
observe all products precautions. Do not reuse empty containers.
KEEP OUT OF REACH OF CHILDREN.
=============================================================================
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
----------------------------------------------------------------------------RESPIRATORY PROTECTION (SPECIFY TYPE): In confined poorly ventilated areas,
use NIOSH/MSHA approved air purifying or supplied air purifying or supplied
air respirators.
VENTILATION - LOCAL EXHAUST: Acceptable
SPECIAL: Explosion-proof equipment
MECHANICAL (GENERAL): Preferable
OTHER: N/A
PROTECTIVE GLOVES: Rubber or neoprene
EYE PROTECTION: Chemical splash goggles (ANSI Z-87.1 or equivalent)
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Coveralls recommended.
WORK/HYGIENIC PRACTICES: Where use can result in skin contact, wash exposed
areas thoroughly before eating, drinking, smoking, or leaving work area.
Launder contaminated clothing before reuse.
=============================================================================
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
----------------------------------------------------------------------------BOILING POINT:
320 F (160 C) @ 760mm Hg
SPECIFIC GRAVITY (H20 = 1):
0.9
VAPOR PRESSURE (mm Hg):
<5 @ 68 F (20 C)
MELTING POINT:
N/A
VAPOR DENSITY (AIR = 1):
>5

EVAPORATION RATE (ETHYL ACETATE = 1): <1
APPEARANCE/ODOR:
Pale Yellow Oil/Petroleum Odor
SOLUBILITY IN WATER:
Insoluble
VOLATILE ORGANIC COMPOUNDS(VOC)Content
(Theoretical Percentage By Weight):
0% or (0 g/L)
=============================================================================
Section 10 -- STABILITY AND REACTIVITY
----------------------------------------------------------------------------STABILITY: Stable
CONDITIONS TO AVOID: Heat, sparks, open flames, and strong oxidizing
conditions.
INCOMPATIBILITY (MATERIALS TO AVOID): Gaseous oxygen and strong oxidizing
materials.
HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO2 and fragmented hydrocarbons.
HAZARDOUS POLYMERIZATION: Will not occur.
=============================================================================
Section 11 -- TOXICOLOGY INFORMATION
----------------------------------------------------------------------------CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
----------------------------------------------------------------------------TOXICOLOGY DATA
Ingredient Name
----------------------------------------------------------------------------Petroleum Oil
Oral-Rat
LD50: N/D
Inhalation-Rat
LC50: N/D
=============================================================================
Section 12 -- Ecological Information
----------------------------------------------------------------------------ECOLOGICAL DATA
Ingredient Name
----------------------------------------------------------------------------Petroleum Oil
Food Chain Concentration Potential
N/D
WATERFOWL TOXICITY
N/D
BOD
N/D
AQUATIC TOXICITY
N/D
=============================================================================
Section 13 -- DISPOSAL CONSIDERATIONS
----------------------------------------------------------------------------Waste Classification: Non-regulated waste oil
Disposal Method:
Used oil recycler
Waste from this product is not considered hazardous as defined under the
Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Dispose of in
accordance with Federal, State, and Local regulation regarding pollution.
=============================================================================
Section 14 -- TRANSPORTATION INFORMATION
----------------------------------------------------------------------------DOT:
Non-Regulated
OCEAN (IMDG):
Non-Regulated
AIR (IATA):
Non-Regulated
WHMIS (CANADA):
Non-Regulated
=============================================================================
Section 15 -- REGULATORY INFORMATION
----------------------------------------------------------------------------REGULATORY DATA
Ingredient Name
----------------------------------------------------------------------------Petroleum Oil

SARA 313
No
TSCA Inventory
Yes
CERCLA RQ
N/A
RCRA Code
N/A
=============================================================================
Section 16 -- OTHER INFORMATION
----------------------------------------------------------------------------This document is prepared pursuant to the OSHA Hazard Communication
Standard (29 CFR 1910.1200). The information herein is given in good faith,
but no warranty, expressed or implied is made. Consult RectorSeal for further
information: (713) 263-8001

Page 1 of 1

CHEMetrics, Inc.
4295 Catlett Rd., Calverton, VA 20138
(800) 356-3072 (540) 788-9026
Fax (540) 788-4856 E-mail technical@chemetrics.com

24 Hour Emergency Numbers:
Creation Date:
Revision Date:

(703) 590-9204
(540) 439-3860
04/22/86 (1072-17)
12/22/06

MATERIAL SAFETY DATA SHEET
I. CHEMICAL IDENTIFICATION

VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION

TRADE NAMES: DISSOLVED OXYGEN CHEMets® and ULR CHEMets®
CATALOG NOS.: R-7501, R-7501V, R-7511, R-7518, R-7540, R-7540G and
R-7540V

OSHA PEL & ACGIH TLV: N/A
PROTECTIVE EQUIPMENT: Safety glasses

IX. PHYSICAL AND CHEMICAL PROPERTIES
DESCRIPTION: Reagent ampoules for the determination of dissolved oxygen
in water. Each CHEMet™ contains approximately 0.50 mL of liquid reagent
sealed under vacuum. Each ULR CHEMet™ contains approximately 1 mL of
liquid reagent sealed under vacuum.
NFPA RATINGS: HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0

STATE: Liquid APPEARANCE: Colorless to pale yellow ODOR: None
SOLUBILITY IN WATER: Miscible pH: 11.5
BOILING POINT: 150EC MELTING POINT: -5.0EC
VAPOR PRESSURE: N/A SPECIFIC GRAVITY: 1.03
VAPOR DENSITY: N/A

II. COMPOSITION/INFORMATION ON INGREDIENTS

X. STABILITY AND REACTIVITY

COMPONENT:
CAS NO.:

Diethylene Glycol
111-46-6
PERCENT: < 28.5

COMPONENT:
CAS NO.:

Deionized Water
7732-18-5
PERCENT: > 70

INCOMPATIBILITIES: Acids
HAZARDOUS DECOMPOSITION PRODUCTS: When heated to decomposition, oxides of carbon may be emitted.
Stable under normal conditions.

COMPONENT:
CAS NO.:

Other components
N/A
PERCENT:

XI. TOXICOLOGICAL INFORMATION
< 1.0

Any component of this mixture not specifically listed (e.g. "other components")
is not considered to present a carcinogen hazard.

III. HAZARDS IDENTIFICATION
Harmful if swallowed.
ACUTE TOXICITY: Irritation, nausea, diarrhea, nerve depression
CHRONIC TOXICITY: Irritation, liver or kidney lesions
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye, skin, liver or
kidney disorders

CARCINOGEN STATUS: None
No other data available at this time.

XII. ECOLOGICAL INFORMATION
Diethylene glycol has a low bioconcentration potential and is practically nontoxic to aquatic organisms.
No other data available at this time.

XIII. DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with Federal, State and Local Regulations.

IV. FIRST AID MEASURES

XIV. TRANSPORT INFORMATION

EYE AND SKIN CONTACT: Immediately flush eyes and skin with water for
15 minutes.
INGESTION: If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Seek medical
attention.
INHALATION: Remove individual to fresh air.

Not regulated.

V. FIRE FIGHTING MEASURES
FLASH POINT: N/A AUTOIGNITION POINT: N/A
FLAMMABILITY LIMITS: UPPER: N/A LOWER: N/A
EXTINGUISHING MEDIA: Dry chemical, carbon dioxide, water spray or foam

XV. REGULATORY INFORMATION
EUROPEAN INFORMATION:
EU Symbols: Xn - HARMFUL
Risk Phrases: Harmful if swallowed.
Safety Phrases: If swallowed, seek medical advice immediately (show the
label where possible).
CANADIAN INFORMATION:
WHMIS Classification: D2A
All chemical components of this product are listed on Canada’s DSL.

VI. ACCIDENTAL RELEASE MEASURES
Take up with absorbent material. Place in small containers for disposal.

U.S. INFORMATION:
All chemical components of this product are listed on the TSCA Inventory.

VII. HANDLING AND STORAGE

XVI. OTHER INFORMATION

Always wear eye protection when working with these ampoules.
WARNING: Do not break the tip of the ampoule unless it is completely
immersed in your sample. Breaking the tip in the air may cause the glass
ampoule to shatter.
If this product is used as directed, the user will not come in contact with or be
exposed to any of its chemical components.
Wash thoroughly after handling. Avoid contact with eyes.
Fragile. Liquid in glass. Handle with care.
Exposure of this product to temperatures up to 120EF (49EC) or even below
32EF (0EC) will not create a safety hazard. For optimum analytical accuracy,
the product should be stored in the dark and at room temperature.

THE ABOVE INFORMATION IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST
INFORMATION CURRENTLY AVAILABLE TO US. ALL PRODUCTS ARE OFFERED IN
ACCORDANCE WITH THE MANUFACTURER'S CURRENT PRODUCTION SPECIFICATIONS
AND ARE INTENDED SOLELY FOR USE IN ANALYTICAL TESTING. THE MANUFACTURER
SHALL IN NO EVENT BE LIABLE FOR ANY INJURY, LOSS OR DAMAGE RESULTING FROM
THE HANDLING, USE OR MISUSE OF THESE PRODUCTS.
CHEMets® and ULR CHEMets® are registered trademarks of CHEMetrics, Inc.

MSDS #GGC-12, #GGC-6 SWOOSH CO2 Cartridge

SECTION 1: IDENTIFICATION

Product Name: Swoosh CO2 Cartridges

MANUFACTURED FOR: Diversitech, Inc
ADDRESS: 2530 Lantrac Court, Decatur, GA 30035
PHONE NUMBER: 800-255-3924 Chem-Tel (Chemical Emergencies Only)
PHONE NUMBER (For Information): 800-995-2222
DATE REVISED: 5/5/2004
PREPARED BY: Anthony Jernigan
SECTION 2: HAZARDOUS INGREDIENTS INFORMATION
INGREDIENT
CAS NO
OSHA PEL ACIGH TLV OTHER STEL
%
Carbon dioxide 124-38-9
5000 ppm
3000 ppm
~100
SECTION 3: HAZARD IDENTIFICATION
Emergency Overview: Colorless odorless gas. Contact with desublimed solid may cause
frostbite. This product is nonflammable. Breathing high concentrations of vapors may produce
drowsiness and a headache.
Potential Health Effects:
Eyes: Contact with desublimed solid may cause frostbite.
Skin: Contact with desublimed solid may cause frostbite
Ingestion: Unlikely. Contact with desublimed solid may cause frostbite.
Inhalation: High concentrations of vapors in immediate area can displace oxygen and can
cause dizziness and unconsciousness. Use with adequate ventilation.
Pre-Existing Medical Conditions Aggravated by Exposure: Heart, lung, skin, eye.
SECTION 4: FIRST AID MEASURES
Eyes: Treat for frostbite immediately. Have eyes examined and tested by medical personnel if
irritation develops or persists.
Skin: Treat for frostbite immediately. Get medical attention if irritation develops or persist.
Ingestion: Not a possible route of entry.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
Flash Point: None to boiling (TCC)
LEL/UEL: Nonflammable
Extinguishing Media: Use extinguishing media as suitable for the combustible materials
involved in the fire.
Fire Fighting Instructions: As in any fire, wear self-contained breathing apparatus (pressuredemand, MSHA/NIOSH approved or equivalent) and full protective gear.
Unusual Fire and Explosion Hazards: Contents under pressure. Do not store near heat
sources.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Large Spills: Shut off leak if possible and safe to do so. Wear self-contained breathing
apparatus and appropriate personal protective equipment. Allow condensed solid to sublime.
Small Spills: Allow condensed solid to sublime.

1

MSDS #GGC-12, #GGC-6 SWOOSH CO2 Cartridge

SECTION 7: HANDLING AND STORAGE
Avoid prolonged or repeated contact with eyes, skin, and clothing. Wash hands before eating.
Protect cartridges from abuse, and extreme temperatures. Keep this product out of the reach of
children. Do not puncture cartridge unless it is contained in an approved appliance. Do not
attempt to refill spent cartridges. Maintain a well-ventilated work area; use with adequate
ventilation. Avoid breathing product vapor or mist. Store in a cool dry place, away from heat,
sparks, flame and direct sunlight.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines:
CHEMICAL NAME ACGIH TWA OSHA PEL ACGIH STEL
Carbon Dioxide
5,000 ppm
5,000 ppm
30,000 ppm
Work/Hygienic Practices: Good general ventilation should be sufficient to control airborne
levels. Local exhaust ventilation may be necessary to control any air contaminants to within their
TLVs during the use of this product. Wear safety glasses with side shields (or goggles) and
rubber, neoprene or other chemically resistant gloves if there is documented evidence of
compatibility when handling this material.
NFPA and HMIS Codes:
NFPA
HMIS
Health
1
1
Flammability 0
0
Reactivity
0
0
Personal Protection - B
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Colorless gas
Solubility in Water: Very Soluble
Odor: Slight ethereal
Specific Gravity: (Water =1) 1.53
pH: NA
Evaporation Rate: >1 (Butyl acetate=1)
Vapor Pressure: 856 psia @ 70 F
Vapor Density: 1.65 @ 70°F (Air = 1)
Viscosity: NA
Percent Volatile: 100%
SECTION 10: STABILITY AND REACTIVITY
Stability: This product is stable. Conditions to Avoid: None known
Incompatibility: None known
Products of Decomposition: None known
Hazardous Polymerization: Will not occur Conditions to Avoid: NA
SECTION 11: TOXICOLOGICAL INFORMATION
Inhalation:
Carbon Dioxide: LCLo/human
9ppm/5 min
Cancer Information: No ingredients listed as human carcinogens by NTP or IARC
Reproductive effects: none
Teratogenic effects: none
Mutagenic effects: none

2

MSDS #GGC-12, #GGC-6 SWOOSH CO2 Cartridge

SECTION 12: ECOLOGICAL INFORMATION
Environmental Impact Information: No sufficient effect known from discharge of gas or
desublimed solid.
Environmental Impact Data
REPORTING (percent by weight):
CFC 0.0% VOC 0.0%; HFC 0.0% HFC 0.0%; Cl. Solv. 0.0% ODP 0.00
US regulations require reporting spills of this material that could reach any surface waters. The
toll free number for the US Coast Guard National Response Center is: 800-424-8802.
SECTION 13: DISPOSAL CONSIDERATIONS
Dispose of in accordance with all federal, state and local regulations.
SECTION 14: TRANSPORTATION INFORMATION
Proper
Sub. Pkg. Hazard
Pkg. Max.
Shipping Name UN Number Class Risk Group Label
Instr. Quantity
Air: Carbon Dioxide UN 1013
2.2 NA NA Non-flammable 200 75kg;150kg.
Gas
Ground: Consumer NA
ORM-D NA NA ORM-D
Pkg.
Commodity, ORM-D
Auth. 173.306
SECTION 15: REGULATORY INFORMATION
SECTION 313 SUPPLIER NOTIFICATION
This product contains the following toxic chemicals subject to the reporting requirements of
Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR
372): None
TOXIC SUBSTANCES CONTROL ACT (TSCA): All ingredients of this product are listed on the
TSCA Inventory.
WHMIS: Class A
This product is classified according to the hazard criteria of the CPR, and the MSDS contains all
of the information required by the CPR.
EEC:
Supply Classification: Not Listed
Hazard Pictogram: None
Risk Phrases: R-20 Harmful by Inhalation
Safety Phrases: S-2 Keep out of reach of children
S-47 Keep at temperatures not exceeding 49 degrees C
S-57 Refer to supplier for information on recycling
SECTION 16: OTHER INFORMATION
Do not puncture or incinerate containers. Normal ventilation for standard manufacturing
practices is usually adequate. Local exhaust should be used when large amounts are released.
REFERENCES: 29 CFR 1910.1200 40 CFR 300-700 ANSI Z400.1-1998; EEC Dangerous
Substances Classification, Packaging and Labeling List (Annexes 1, 2, 3 & 4)
This information is, to the best of our knowledge and belief, accurate and reliable as of the date completed. However no
representation, warranty or guarantee is made as to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy
himself as to the completeness and suitability of such information for his own particular use. We do not accept liability for any loss or
damage that may occur from the use of this information, nor do we offer any warranty against patent infringement.

3

J/B Industries Inc.
Section 1: Product And
Company Identification
COMPANY:
LOCATION:

J/B INDUSTRIES INC.
601 N. Farnsworth Ave.
Aurora, IL 60507

Emergency Telephone Number:

630/851-9444
PRODUCT NAME:

Vacuum Pump Oil
PRODUCT GRADES:
PRODUCT CODE:
DATE ISSUED:

December 28, 1992
DATE REVISED:

September 18, 2006
Sept. 1 , 2003

Section 2: Composition/
Information On Ingredients
CAS NAME:

Distillates, hydrotreated heavy paraffinic
CAS NUMBER:

64742-54-7
AMOUNT:

100% weight
This product is not approved for direct
food use [CFR 178.3620 (a) & (b)]

Section 3: Hazards Identification
EMERGENCY OVERVIEW

Clear colorless to pale yellow liquid.
IMMEDIATE HEALTH EFFECTS
EYE:

Not expected to cause prolonged or
significant eye irritation.
SKIN:

Contact with the skin is not expected to
cause prolonged or significant irritation.
Not expected to be harmful to internal
organs if absorbed through the skin.
Contact with the skin is not expected to
cause an allergic skin response.
INGESTION:

Not expected to be harmful if swallowed.
INHALATION:

Not expected to be harmful if inhaled.
Contains a petroleum-based mineral oil.
May cause respiratory irritation or other
pulmonary effects following prolonged
or repeated inhalation of oil mist at
airborne levels above the recomm
ended mineral oil mist exposure limit.
Symptoms of respiratory irritation
may include coughing and
difficulty breathing.

Material Safety Data Sheet
Section 4: First Aid Measures
EYE:

No specific first aid measures are
required because this material is not
expected to cause eye irritation. As a
precaution, remove contact lenses, if
worn, and flush eyes with water.
SKIN:

No specific first aid measures are
required because this material is not
expected to be harmful if it contacts the
skin. As a precaution, remove clothing
and shoes if contaminated. To remove
the material from skin, use soap and
water. Discard contaminated
clothing and shoes or thoroughly
clean before reuse.
No specific first aid measures are
required because this material is not
expected to be harmful if swallowed. Do
not induce vomiting. As a precaution,
give the person a glass of water or milk
to drink and get medical advice. Never
give anything by mouth to an
unconscious person.
INHALATION:

No specific first aid measures are
required because this material is not
expected to be harmful if inhaled. If
exposed to excessive levels of material
in the air, move the exposed person to
fresh air. Get medical attention
if coughing or respiratory
discomfort occurs.

Section 5: Fire Fighting Measures
FIRE CLASSIFICATION;

OSHA Classification (29 CFR
1910.1200): Not classified by OSHA as
flammable or combustible.
NFPA RATINGS:
HEALTH FLAMMABILITY

REACTIVITY

1

0

FLAMMABLE PROPERTIES:
FLASH POINT:

Cleveland Open Cup 378°F (190°C)
(Min)
AUTOIGNITION:

No data available
FLAMMABLE (EXPLOSIVE) LIMITS (% by
volume in air):

Lower N/A

Combustion Products:

Highly dependent on combustion
conditions. A complex mixture of
airborne solids, liquids, and gases
including carbon monoxide, carbon
dioxide, and unidentified organic
compounds will be evolved when this
material undergoes combustion.

Section 6. Accidental Release
Measures
PROTECTIVE MEASURES:

Eliminate all sources of ignition in
vicinity of spilled material.
SPILL MANAGEMENT:

INGESTION:

0

material, do not enter any enclosed or
confined fire space without proper
protective equipment, including selfcontained breathing apparatus.

Upper N/A

EXTINGUISHING MEDIA:

Use water fog, foam, dry chemical or
carbon dioxide (CO2) to extinguish
flames.
PROTECTION OF FIRE FIGHTERS:
Fire Fighting Instructions:

This material will burn although it is not
easily ignited. For fires involving this

Stop the source of the release if you can
do it without risk. Contain release to
prevent further contamination of soil,
surface water or groundwater. Clean up
spill as soon as possible, observing
precautions in Exposure Controls/
Personal Protection. Use appropriate
techniques such as applying noncombustible absorbent materials or
pumping. Where feasible and
appropriate, remove contaminated soil.
Place contaminated materials in
disposable containers and dispose of
in a manner consistent with
applicable regulations.
REPORTING:

Report spills to local authorities and/or
the U.S. Coast Guard's National
Response Center at (800) 424-8802 as
appropriate or required.

Section 7. Handling and Storage
GENERAL HANDLING INFORMATION:

Avoid contaminating soil or releasing this
material into sewage and drainage
systems and bodies of water.
STATIC HAZARD:

Electrostatic charge may accumulate and
create a hazardous condition when
handling this material. To minimize this
hazard, bonding and grounding may be
necessary but may not, by themselves,
be sufficient. Review all operations which
have the potential of generating an
accumulation of electrostatic charge and/
or a flammable atmosphere (including
tank and container filling, splash filling,
tank cleaning, sampling, gauging, switch
loading, filtering, mixing, agitation, and
vacuum truck operations) and use
appropriate mitigating procedures. For
more information, refer to OSHA
1

Standard 29 CFR 1910.106, 'Flammable
and Combustible Liquids', National Fire
Protection Association (NFPA 77,
'Recommended Practice on Static
Electricity; and /or the American
Petroleum Institute (API) Recommended
Practice 2003, 'Protection Against
Ignitions Arising Out of Static, Lightning
and Stray Currents'.
CONTAINER WARNING:

Container is not designed to contain
pressure. Do not use pressure to empty
container or it may rupture with
explosive force. Empty containers retain
product residue (solid, liquid, and/or
vapor) and can be dangerous. Do not
pressurize, cut, weld, braze, solder, drill,
grind, or expose such containers to heat,
flame, sparks, static electricity, or other
sources of ignition. They may explode
and cause injury or death. Empty
containers should be completely
drained, properly closed, and promptly
returned to a drum reconditioner or
disposed of properly.

RESPIRATORY PROTECTION:

No respiratory protection is normally
required.
If user operations generate an oil mist,
determine if airborne concentrations are
below the OSHA Permissible Exposure
Limit (PEL) of 5 mg/m3 for mineral oil
mist. If not, wear a NIOSH approved
respirator that provides adequate
protection from the measured
concentrations of this material. For
air-purifying respirators use a
particulate cartridge.
Use a positive pressure, air-supplying
respirator if there is potential for
uncontrolled release, exposure levels are
not known, or other circumstances
where air-purifying respirators may not
provide adequate protection.

Section 9: Physical And
Chemical Properties
APPEARANCE AND ODOR:

Clear colorless to pale yellow liquid.
PH:

Not Available

Section 8. Exposure Controls/
Personal Protection

VAPOR PRESSURE:

GENERAL CONSIDERATIONS:

VAPOR DENSITY (Air =1):

Consider the potential hazards of this
material (see Section 3), applicable
exposure limits, job activities, and other
substances in the work place when
designing engineering controls and
selecting personal protective equipment.
If engineering controls or work practices
are not adequate to prevent exposure to
harmful levels of this material, the
personal protective equipment listed
below is recommended. The user should
read and understand all instructions and
limitations supplied with the equipment
since protection is usually provided for a
limited time or under certain
circumstances.
ENGINEERING CONTROLS:

Use in a well-ventilated area.
PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:

No special eye protection is normally
required. Where splashing is possible,
wear safety glasses with side shields as
a good safety practice.
SKIN PROTECTION:

No special protective clothing is normally
required. Where splashing is possible,
select protective clothing depending on
operations conducted, physical
requirements and other substances.
Suggested materials for protective
gloves include: Nitrile Rubber, Silver
Shield, Viton.

<0.01 mmHg @ 100°F
>1
BOILING POINT:

>600°F (>315° C)
SOLUBILITY:

Soluble in hydrocarbons, insoluble in
water
FREEZING POINT

NA
MELTING POINT

NA
SPECIFIC GRAVITY:

0.85-0.87 @ 15.6 °C/15.6°C
VOLATILE ORGANIC COMPOUNDS (VOC):

2.9% weight (Approximate)
VISCOSITY:

18.7 cST - 105 cST @40°C

Section 11. Toxicological
Information
IMMEDIATE HEALTH EFFECTS
EYE IRRITATION:

The mean 24-hour Draize eye irritation
score in rabbits is 4.0/110.
SKIN IRRITATION:

For a 24-hour exposure, the
Primary Irritation Score (PIS) in
rabbits is: 0.2/8.0.
SKIN SENSITIZATION:

This material did not cause skin
sensitization reactions in a Buehler
guinea pig test.
ACUTE DERMAL TOXICITY:

The 24 hour(s) LD50 in the rabbit is
>5g/kg.
ACUTE ORAL TOXICITY:

The LD50 in the rat is >5 g/kg.
ACUTE INHALATION TOXICITY:

The acute inhalation toxicity hazard is
based on evaluation of data for similar
materials or product components.
GENETIC TOXICITY:

This product gave negative results in the
following mutagenicity assays:
Microbial/Microsome Reverse Mutation
Assay.
ADDITIONAL TOXICOLOGY INFORMATION:

This product contains petroleum base
oils which may be refined by various
processes including severe solvent
extraction, severe hydrocracking, or
severe hydrotreating. None of the oils
requires a cancer warning under the
OSHA Hazard Communication Standard
(29 CFR 1910.1200). These oils have not
been listed in the National Toxicology
Program (NTP) Annual Report nor have
they been classified by the International
Agency for Research on Cancer (IARC)
as; carcinogenic to humans (Group 1),
probably carcinogenic to humans
(Group 2A), or possibly carcinogenic to
humans (Group 2B).

Section 10. Stability And
Reactivity

Section 12. Ecological
Information:

CHEMICAL STABILITY:

EXOTOXICITY

This material is considered stable under
normal ambient and anticipated storage
and handling conditions of temperature
and pressure.
INCOMPATIBILITY WITH
OTHER MATERIALS:

May react with strong oxidizing agents,
such as chlorates, nitrates, peroxides,
etc.
HAZARDOUS DECOMPOSITION PRODUCTS:

None known (None expected)
HAZARDOUS POLYMERIZATION:

Hazardous polymerization will not occur.

Ten 96 hour(s) LC50 for rainbow trout
(Oncorhynchus mykiss) is >1000 mg/l.
ENVIRONMENTAL FATE
READY BIODEGRADABILITY:

This material is not expected to be
readily biodegradable.

Section 13. Disposal
Considerations
Oil collection services are available for
used oil recycling or disposal. Place
contaminated materials in containers
and dispose of in a manner consistent
2

with applicable regulations. Contact your
sales representative or local
environmental or health authorities for
approved disposal or recyling methods.

Section 14. Transportation
Information
The description shown may not apply to
all shipping situations. Consult 49CFR,
or appropriate Dangerous Goods
Regulations, for additional description
requirements (e.g., technical name) and
mode-specific or quantity-specific
shipping requirements.
DOT SHIPPING NAME:

Not regulated as a hazardous material for
transportation under 49 CFR
DOT HAZARD CLASS:

Not Applicable
DOT IDENTIFICATION NUMBER:

Not Applicable
DOT PACKING GROUP:

Not Applicable

Section 15. Regulatory
Information
SARA 311/312 CATEGORIES:

1.
2.
3.
4.

Immediate (Acute) Health Effects:
Delayed (Chronic) Health Effects:
Fire Hazard:
Sudden Release of
Pressure Hazard:
5. Reactivity Hazard:
REGULATORY LISTS SEARCHED:

4_I1=IARC Group 1
4_I2A=IARC Group 2A
4_I28B=IARC Group 2B
05=NTP Carcinogen
06-OSHA Carcinogen
09-TSCA 12(b)
10=TSCA Section 4
11=TSCA Section 8(a) CAIR
12=TSCA Section 8(a) PAIR
13=TSCA Section 8(d)
15=SARA Section 313
16=CA Proposition 65
17=MA RTK
18=NJ RTK
19=DOT Marine Pollutant
20=PA RTK
21=TSCA Section 5(a)
25=CAA Section 112 HAPs
26=CWA Section 311
28=CWA Section 307
30=RCRA Waste P-List
31-RCRA Waste U-List
32=RCRA Appendix VIII
No components of this material were
found on the regulatory lists above.

No
No
No
No
No

CHEMICAL INVENTORIES:

AUSTRALIA: All the components of this
material are listed on the Australian
Inventory of Chemical Substances
(AICS).
KOREA: All the components of this
product are on the Existing Chemicals
List (ECL) in Korea.
PHILIPPINES: All the components of this
product are listed on the Philippine
Inventory of Chemicals and Chemical
Substances (PICCS).
CANADA: All the components of this
material are on the Canadian Domestic
Substances List (DSL).
EUROPEAN UNION: All the components
of this material are in compliance with
the EU Seventh Amendment Directive
92/32/EEC.
UNITED STATES: All of the components
of this material are on the Toxic
Substances Control Act (TSCA) Chemical
Inventory.
NEW JERSEY RTK CLASSIFICATION:
Under the New Jersey Right-to-Know Act
L. 1983 Chapter 315 N.J.S.A.34:5A-1 et.
seq., the product is to be indentified as
follows: PETROLEUM OIL
WHMIS CLASSIFICATION:

This product is not considered a
controlled product according to the
criteria of the Canadian Controlled
Products Regulations.

Section 16. Other Information
NFPA RATINGS:

Health: Flammability:
0
1

Reactivity:
0

HMIS RATINGS:

Health: Flammability: Reactivity
1
1
0
(0-Least, 1-Slight, 2-Moderate, 3-High,
4-Extreme, PPE:-Personal Protection
Equipment Index recommendation, *Chronic Effect Indicator). These values
are obtained using the guidelines or
published evaluations prepared by the
National Fire Protection Association
(NFPA) or the National Paint and Coating
Association (for HMIS ratings).
Prepared according to the OSHA Hazard
Communication Standard (29 CFR
1910.1200) and the ANSI MSDS
Standard (Z400.1).
The above information is based on the
data of which we are aware and is
believed to be correct as of the date
hereof. Since this information may be
applied under conditions beyond our
control and with which we may be
unfamiliar and since data made available
subsequent to the date hereof may
suggest modifications of the information,
we do not assume any responsibility for
the results of it use. This information is
furnished upon condition that the person
receiving it shall make his own
determination of the suitability of the
material for his particular purpose.

3

Date Prepared: July 1, 1992
Date Reviewed: January 8, 2001

MATERIAL SAFETY DATA SHEET
Product Name:

Acetylene

January 8, 2001

1. Chemical, Product and Company Identification
Linweld, Inc
9911 Deer Park Road
Waverly, NE 68462

Telephone Number
Information: (402) 786-3330
Emergency: (402) 786-5277

Product Name: Acetylene
Chemical Name: Acetylene
Common Names: Acetylene; Ethyne

2. Hazard Ingredients and Identity Information
COMPONENT
Acetylene
Acetone

% VOLUME
95.0 to 99.6
Unavailable

OSHA-PEL
Not Available
1000 ppm TWA

ACGIH-TLV
Simple Asphyxiant
750 ppm TWA
1000 ppm STEL

CAS NUMBER
000074-86-2
000067-64-1

3. Physical and Chemical Characteristics
Boiling Point:
Melting Point:
Vapor Pressure:

-118.8o F
-116o F
635 psig

Specific Gravity:
Evaporation Rate:
Solubility (H2O):

0.906
N/A
Soluble

pH:
Physical State:

N/A
Gas

Appearance and Odor:
Pure acetylene is a colorless gas with an ethereal odor. Commercial (carbide) acetylene has a distinctive garlic-like odor.
How to Detect This Substance:
N/A
Other Physical and Chemical Data:
Liquid density at boiling point, 38.8 lb/ft3 (622 kg/m3)
Gas density at 70o F 1 atm, 0.0691 lb/ft3 (1.107 kg/m3)

4. Fire and Explosion Hazard Data
Flammability Classification:
Ignition Temperature:

Flammable
565o F

Flash Point (F):
Method:

N/A
N/A

LEL (%):
UEL (%):

2.2
82.5

Extinguishing Media:
Carbon dioxide; Dry chemical; Water spray
Fire Fighting Procedures:
Stop flow of gas before extinguishing fire. If flame is small and originating from fusible plug or valve stem, attempt to extinguish
flame. A glove, heavy cloth or any wet material slapped across the flame will frequently extinguish it. If flame is large and
originating from fusible plug, do not attempt to extinguish unless cylinder is outdoors or in a well-ventilated area away from sources
of ignition. Escaping gas may be easily re-ignited by adjacent ignition sources. Use water spray to keep fire-exposed containers
cool. Burning or heated cylinders may rupture violently. Approach fire from upwind to avoid hazardous vapors and toxic
decomposition products. Fight fire from protected location or maximum possible distance.
Fire & Explosion Hazard:
Gaseous acetylene is spontaneously combustible in air at pressure above 30 pi. Acetylene requires very low ignition energy;
therefore extinguished fires may easily re-ignite if the flow of gas is not stopped. Acetylene has a density very similar to that of air,
so leaking acetylene does not readily dissipate. Gas may travel to an ignition source and flash back.

5. Reactivity Data
Stability:

Unstable

Hazardous Polymerization:

May occur

Incompatibility:
Oxygen and oxidizers including halogens and halogen compounds. Forms explosive acetylide compounds with copper, mercury,
silver, brass (>66% copper), and brazing materials containing silver or copper.

Page 1 of 4

Product Name:

Acetylene

January 8, 2001

5. Reactivity Data (Continued)
Conditions to Avoid:
Do not allow free gas (outside of cylinder) to exceed 30 psi. Cylinders should not be exposed to sudden shock or sources of heat.
Hazardous Decomposition or Byproducts:
Under high pressure, acetylene decomposes to carbon and hydrogen. Carbon monoxide may be produced from burning.
Under certain conditions, acetylene forms acetylide compounds when in contact with copper, silver and mercury.

Other Reactivity Data:
Flammable over an extremely wide range in air. Explosive reactions may occur on ignition. Reacts explosively with halogens and
halogenated compounds.
Electrical classification: Class 1, Group A

6. Health Hazard Data
Route(s) of Entry:

Health Hazards:
Acute

Chronic

Eye contact
No

Skin Contact
No

Inhalation
Yes

Ingestion
No

Skin Absorption
No

Product is a simple asphyxiant. Effects of oxygen deficiency may include any, all or none of the
following: rapid breathing, diminished mental alertness, impaired muscle coordination, blurred speech,
and fatigue. As asphyxiation progresses, nausea, vomiting, and loss of consciousness may occur,
eventually leading to convulsions, coma and death.
N/A

Carcinogenicity:

NTP
No

IARC Monographs
No

OSHA
No

Signs and Symptoms of Exposure and Emergency First Aid Procedures:
Eye Contact
N/A
Skin Contact
Inhalation

N/A
Product is a simple asphyxiant. Effects of oxygen deficiency may include any, all or none of the
following: rapid breathing, diminished mental alertness, impaired muscle coordination, blurred speech,
and fatigue. As asphyxiation progresses, nausea, vomiting, and loss of consciousness may occur,
eventually leading to convulsions, coma and death.
Under normal operating conditions, acetone is not released from the cylinder. However, if the cylinder
is overcharged with acetone or acetylene, acetone may occasionally "spit" out. Acetone is primarily a
central nervous system toxin causing headache, nausea, dizziness, vomiting and fatigue. Moderate
concentrations may cause respiratory irritation.
Conscious victim should be assisted to an uncontaminated area and allowed to inhale fresh air.
Unconscious victim should be moved to an uncontaminated area and given assisted respiration with
supplemental oxygen. Further treatment should be symptomatic and supportive.

Ingestion

N/A

Medical Conditions Aggravated by Exposure:
Persons having health conditions that may be aggravated by exposure to acetylene should not be allowed to work with this
product.

7. Precautions for Safe Handling and Use
Actions if Released or Spilled:
Evacuate all personnel from affected area. Use appropriate personal protective equipment.
If possible to do so safely, shut off all ignition sources and close cylinder valve. For small leaks, the cylinder may be moved
outdoors and away from ignition sources. If leak is in the user's equipment, be certain to purge piping with inert gas prior to
attempting repairs. If leak is in cylinder or cylinder valve, contact the nearest distributor.

Page 2 of 4

Product Name:

Acetylene

January 8, 2001

7. Precautions for Safe Handling and Use (Continued)
Waste Disposal Method:
Do not attempt to dispose of waste or unused quantities. Return in properly labeled shipping container, with any valve outlet plugs
or caps secured and valve protection caps in place.
Handling and Storage Precautions:
Use only in well-ventilated areas. Valve protection caps must remain in place unless cylinder is secured with valve outlet piped to
point of use. Do not drag, slide or roll cylinders. Use a suitable hand truck for cylinder movement. Use a pressure-reducing
regulator when connecting cylinder to lower pressure piping or systems. Do not heat cylinder. Use a check valve or trap in the
discharge line to prevent hazardous backflow into the cylinder.
Protect cylinders from physical damage. Store in cool, dry, well-ventilated area away from heavy traffic areas and emergency exits.
Do not allow temperature of cylinder storage area to exceed 125o F. Cylinders should be stored upright and firmly secured to
prevent falling or being knocked over. Full and empty cylinders should be segregated. Acetylene cylinders should never be stored
on their sides. This makes the acetylene unstable and increases the likelihood of solvent release during use. Do not attempt to
repair or alter cylinders. Do not tamper with the valve, pressure relief devices or fusible plugs. If the fusible plug or valve begins to
leak, move the cylinder to an open area and contact the nearest distributor. A leaking cylinder should be properly marked to
prevent further use. Never allow a torch flame to come in contact with the cylinder or fusible plug.
Do not store acetylene within 20 feet of oxygen or combustible materials unless separated by a one-half hour rated 5 feet high
firewall. Post "NO SMOKING OR OPEN FLAMES" signs in the storage and use area.
Other Precautions:
To prevent solvent withdrawal from the cylinder during use, always follow supplier instructions for maximum withdrawal rate for
each size of cylinder.
Compressed gas cylinders should only be refilled by qualified personnel. Shipment of compressed gas cylinders, which have been
filled without the consent of the cylinder owner, is a violation of federal law (49 CFR).
Always secure cylinders in an upright position during transportation. Never transport cylinders in enclosed space such as a vehicle
truck or van.
For additional recommendations, see CGA Pamphlets P-1, G-1, SB-4; NFPA 51; OSHA 1910 Subpart H and Q.
Transportation Information:
Shipping Name
Hazard Class
ID Number
Shipping Label - 1
NFPA Rating:
Health: 0

Acetylene, dissolved
2.1
UN1001
Flammable Gas

Flammability:

4

Reactivity:

0

8. Control Measures
Eye Protection:
Safety goggles or glasses as appropriate.
Protective Gloves:
PVC or rubber gloves for laboratory use; as required for welding and cutting.
Respiratory Protection:
Positive pressure air line with mask or self-contained breathing apparatus should be available for emergency use.
Ventilation:
Local exhaust to prevent acetylene accumulation above the exposure limit and to maintain oxygen concentration above 19.5%.
Mechanical ventilation should be designed in accordance with electrical codes.
Other Protective Clothing or Equipment:
Safety shoes, safety shower.

Page 3 of 4

Product Name:

Acetylene

January 8, 2001

9. Regulatory Information
Acetone is regulated as a Hazardous Substance under CERCLA
Acetylene is listed under the Clean Air Act (CAA) Section 112(r) with a threshold quantity (TQ) of 10,000 pounds.
SARA TITLE III NOTIFICATIONS AND INFORMATION
Releases of acetone in quantities equal to or greater than the reportable quantity (RQ) of 5,000 pounds are subject to reporting to
the National Response Center under CERCLA, Section 304 SARA Title III.
Sara Title III – Section 313 Supplier Notification
This product does not contain toxic chemicals subject to reporting requirements of section 313 of the Emergency Planning and
Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372.
SARA Title III – Hazard Classes
Acute Health Hazard
Fire Hazard
Sudden Release of Pressure Hazard
Reactivity Hazard

Disclaimer of Expressed and Implied Warranties
Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no
representations as to the accuracy or completeness of the information contained herein, and assume no responsibility regarding
the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a
determination as to the suitability of the information for their particular purpose.

Page 4 of 4

Date Prepared: July 1, 1992
Date Reviewed: January 8, 2001

MATERIAL SAFETY DATA SHEET
Product Name:

Acetylene

January 8, 2001

1. Chemical, Product and Company Identification
Linweld, Inc
9911 Deer Park Road
Waverly, NE 68462

Telephone Number
Information: (402) 786-3330
Emergency: (402) 786-5277

Product Name: Acetylene
Chemical Name: Acetylene
Common Names: Acetylene; Ethyne

2. Hazard Ingredients and Identity Information
COMPONENT
Acetylene
Acetone

% VOLUME
95.0 to 99.6
Unavailable

OSHA-PEL
Not Available
1000 ppm TWA

ACGIH-TLV
Simple Asphyxiant
750 ppm TWA
1000 ppm STEL

CAS NUMBER
000074-86-2
000067-64-1

3. Physical and Chemical Characteristics
Boiling Point:
Melting Point:
Vapor Pressure:

-118.8o F
-116o F
635 psig

Specific Gravity:
Evaporation Rate:
Solubility (H2O):

0.906
N/A
Soluble

pH:
Physical State:

N/A
Gas

Appearance and Odor:
Pure acetylene is a colorless gas with an ethereal odor. Commercial (carbide) acetylene has a distinctive garlic-like odor.
How to Detect This Substance:
N/A
Other Physical and Chemical Data:
Liquid density at boiling point, 38.8 lb/ft3 (622 kg/m3)
Gas density at 70o F 1 atm, 0.0691 lb/ft3 (1.107 kg/m3)

4. Fire and Explosion Hazard Data
Flammability Classification:
Ignition Temperature:

Flammable
565o F

Flash Point (F):
Method:

N/A
N/A

LEL (%):
UEL (%):

2.2
82.5

Extinguishing Media:
Carbon dioxide; Dry chemical; Water spray
Fire Fighting Procedures:
Stop flow of gas before extinguishing fire. If flame is small and originating from fusible plug or valve stem, attempt to extinguish
flame. A glove, heavy cloth or any wet material slapped across the flame will frequently extinguish it. If flame is large and
originating from fusible plug, do not attempt to extinguish unless cylinder is outdoors or in a well-ventilated area away from sources
of ignition. Escaping gas may be easily re-ignited by adjacent ignition sources. Use water spray to keep fire-exposed containers
cool. Burning or heated cylinders may rupture violently. Approach fire from upwind to avoid hazardous vapors and toxic
decomposition products. Fight fire from protected location or maximum possible distance.
Fire & Explosion Hazard:
Gaseous acetylene is spontaneously combustible in air at pressure above 30 pi. Acetylene requires very low ignition energy;
therefore extinguished fires may easily re-ignite if the flow of gas is not stopped. Acetylene has a density very similar to that of air,
so leaking acetylene does not readily dissipate. Gas may travel to an ignition source and flash back.

5. Reactivity Data
Stability:

Unstable

Hazardous Polymerization:

May occur

Incompatibility:
Oxygen and oxidizers including halogens and halogen compounds. Forms explosive acetylide compounds with copper, mercury,
silver, brass (>66% copper), and brazing materials containing silver or copper.

Page 1 of 4

Product Name:

Acetylene

January 8, 2001

5. Reactivity Data (Continued)
Conditions to Avoid:
Do not allow free gas (outside of cylinder) to exceed 30 psi. Cylinders should not be exposed to sudden shock or sources of heat.
Hazardous Decomposition or Byproducts:
Under high pressure, acetylene decomposes to carbon and hydrogen. Carbon monoxide may be produced from burning.
Under certain conditions, acetylene forms acetylide compounds when in contact with copper, silver and mercury.

Other Reactivity Data:
Flammable over an extremely wide range in air. Explosive reactions may occur on ignition. Reacts explosively with halogens and
halogenated compounds.
Electrical classification: Class 1, Group A

6. Health Hazard Data
Route(s) of Entry:

Health Hazards:
Acute

Chronic

Eye contact
No

Skin Contact
No

Inhalation
Yes

Ingestion
No

Skin Absorption
No

Product is a simple asphyxiant. Effects of oxygen deficiency may include any, all or none of the
following: rapid breathing, diminished mental alertness, impaired muscle coordination, blurred speech,
and fatigue. As asphyxiation progresses, nausea, vomiting, and loss of consciousness may occur,
eventually leading to convulsions, coma and death.
N/A

Carcinogenicity:

NTP
No

IARC Monographs
No

OSHA
No

Signs and Symptoms of Exposure and Emergency First Aid Procedures:
Eye Contact
N/A
Skin Contact
Inhalation

N/A
Product is a simple asphyxiant. Effects of oxygen deficiency may include any, all or none of the
following: rapid breathing, diminished mental alertness, impaired muscle coordination, blurred speech,
and fatigue. As asphyxiation progresses, nausea, vomiting, and loss of consciousness may occur,
eventually leading to convulsions, coma and death.
Under normal operating conditions, acetone is not released from the cylinder. However, if the cylinder
is overcharged with acetone or acetylene, acetone may occasionally "spit" out. Acetone is primarily a
central nervous system toxin causing headache, nausea, dizziness, vomiting and fatigue. Moderate
concentrations may cause respiratory irritation.
Conscious victim should be assisted to an uncontaminated area and allowed to inhale fresh air.
Unconscious victim should be moved to an uncontaminated area and given assisted respiration with
supplemental oxygen. Further treatment should be symptomatic and supportive.

Ingestion

N/A

Medical Conditions Aggravated by Exposure:
Persons having health conditions that may be aggravated by exposure to acetylene should not be allowed to work with this
product.

7. Precautions for Safe Handling and Use
Actions if Released or Spilled:
Evacuate all personnel from affected area. Use appropriate personal protective equipment.
If possible to do so safely, shut off all ignition sources and close cylinder valve. For small leaks, the cylinder may be moved
outdoors and away from ignition sources. If leak is in the user's equipment, be certain to purge piping with inert gas prior to
attempting repairs. If leak is in cylinder or cylinder valve, contact the nearest distributor.

Page 2 of 4

Product Name:

Acetylene

January 8, 2001

7. Precautions for Safe Handling and Use (Continued)
Waste Disposal Method:
Do not attempt to dispose of waste or unused quantities. Return in properly labeled shipping container, with any valve outlet plugs
or caps secured and valve protection caps in place.
Handling and Storage Precautions:
Use only in well-ventilated areas. Valve protection caps must remain in place unless cylinder is secured with valve outlet piped to
point of use. Do not drag, slide or roll cylinders. Use a suitable hand truck for cylinder movement. Use a pressure-reducing
regulator when connecting cylinder to lower pressure piping or systems. Do not heat cylinder. Use a check valve or trap in the
discharge line to prevent hazardous backflow into the cylinder.
Protect cylinders from physical damage. Store in cool, dry, well-ventilated area away from heavy traffic areas and emergency exits.
Do not allow temperature of cylinder storage area to exceed 125o F. Cylinders should be stored upright and firmly secured to
prevent falling or being knocked over. Full and empty cylinders should be segregated. Acetylene cylinders should never be stored
on their sides. This makes the acetylene unstable and increases the likelihood of solvent release during use. Do not attempt to
repair or alter cylinders. Do not tamper with the valve, pressure relief devices or fusible plugs. If the fusible plug or valve begins to
leak, move the cylinder to an open area and contact the nearest distributor. A leaking cylinder should be properly marked to
prevent further use. Never allow a torch flame to come in contact with the cylinder or fusible plug.
Do not store acetylene within 20 feet of oxygen or combustible materials unless separated by a one-half hour rated 5 feet high
firewall. Post "NO SMOKING OR OPEN FLAMES" signs in the storage and use area.
Other Precautions:
To prevent solvent withdrawal from the cylinder during use, always follow supplier instructions for maximum withdrawal rate for
each size of cylinder.
Compressed gas cylinders should only be refilled by qualified personnel. Shipment of compressed gas cylinders, which have been
filled without the consent of the cylinder owner, is a violation of federal law (49 CFR).
Always secure cylinders in an upright position during transportation. Never transport cylinders in enclosed space such as a vehicle
truck or van.
For additional recommendations, see CGA Pamphlets P-1, G-1, SB-4; NFPA 51; OSHA 1910 Subpart H and Q.
Transportation Information:
Shipping Name
Hazard Class
ID Number
Shipping Label - 1
NFPA Rating:
Health: 0

Acetylene, dissolved
2.1
UN1001
Flammable Gas

Flammability:

4

Reactivity:

0

8. Control Measures
Eye Protection:
Safety goggles or glasses as appropriate.
Protective Gloves:
PVC or rubber gloves for laboratory use; as required for welding and cutting.
Respiratory Protection:
Positive pressure air line with mask or self-contained breathing apparatus should be available for emergency use.
Ventilation:
Local exhaust to prevent acetylene accumulation above the exposure limit and to maintain oxygen concentration above 19.5%.
Mechanical ventilation should be designed in accordance with electrical codes.
Other Protective Clothing or Equipment:
Safety shoes, safety shower.

Page 3 of 4

Product Name:

Acetylene

January 8, 2001

9. Regulatory Information
Acetone is regulated as a Hazardous Substance under CERCLA
Acetylene is listed under the Clean Air Act (CAA) Section 112(r) with a threshold quantity (TQ) of 10,000 pounds.
SARA TITLE III NOTIFICATIONS AND INFORMATION
Releases of acetone in quantities equal to or greater than the reportable quantity (RQ) of 5,000 pounds are subject to reporting to
the National Response Center under CERCLA, Section 304 SARA Title III.
Sara Title III – Section 313 Supplier Notification
This product does not contain toxic chemicals subject to reporting requirements of section 313 of the Emergency Planning and
Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372.
SARA Title III – Hazard Classes
Acute Health Hazard
Fire Hazard
Sudden Release of Pressure Hazard
Reactivity Hazard

Disclaimer of Expressed and Implied Warranties
Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no
representations as to the accuracy or completeness of the information contained herein, and assume no responsibility regarding
the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a
determination as to the suitability of the information for their particular purpose.

Page 4 of 4

Page 1 of 1

CHEMetrics, Inc.
4295 Catlett Rd., Calverton, VA 20138
(800) 356-3072 (540) 788-9026
Fax (540) 788-4856 E-mail technical@chemetrics.com

24 Hour Emergency Numbers:
Creation Date:
Revision Date:

(703) 590-9204
(540) 439-3860
04/22/86 (1072-14)
07/22/04

MATERIAL SAFETY DATA SHEET
I. CHEMICAL IDENTIFICATION

IX. PHYSICAL AND CHEMICAL PROPERTIES

TRADE NAMES: DISSOLVED OXYGEN CHEMets®, ULR CHEMets®, and
Vacu-vials®

STATE: Liquid APPEARANCE: Colorless to pale yellow ODOR: None
SOLUBILITY IN WATER: Miscible pH: 11.5
BOILING POINT: 150°C MELTING POINT: -5.0°C
VAPOR PRESSURE: N/A SPECIFIC GRAVITY: 1.03
VAPOR DENSITY: N/A

CATALOG NOS.: R-7501, R-7501V, R-7511, R-7518, R-7540, R-7540G,
R-7540V and R-7553
DESCRIPTION: Reagent ampoules for the determination of dissolved oxygen
in water. Each CHEMet™ contains approximately 0.50 mL of liquid reagent
sealed under vacuum. Each ULR CHEMet™ contains approximately 1 mL of
liquid reagent sealed under vacuum. Each Vacu-vial™ contains approximately 2 mL of liquid reagent sealed under vacuum.

X. STABILITY AND REACTIVITY
INCOMPATIBILITIES: Acids
HAZARDOUS DECOMPOSITION PRODUCTS: When heated to decomposition, oxides of carbon may be emitted.
Stable under normal conditions.

NFPA RATINGS: HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0

II. COMPOSITION/INFORMATION ON INGREDIENTS
COMPONENT: Diethylene Glycol
CAS NO.:
111-46-6
PERCENT:

XI. TOXICOLOGICAL INFORMATION
CARCINOGEN STATUS: None
No other data available at this time.

25.0

XII. ECOLOGICAL INFORMATION
COMPONENT: Deionized Water
CAS NO.:
7732-18-5
PERCENT: >74.0
COMPONENT: Other components
CAS NO.:
N/A
PERCENT: < 1.0

Diethylene Glycol has a low bioconcentration potential and is practically nontoxic to aquatic organisms.
No other data available at this time.

XIII. DISPOSAL CONSIDERATIONS
Any component of this mixture not specifically listed (e.g. "other components")
is not considered to present a carcinogen hazard.

Dispose of in a manner consistent with Federal, State and Local Regulations.

III. HAZARDS IDENTIFICATION

XIV. TRANSPORT INFORMATION

Harmful if swallowed.
ACUTE TOXICITY: Irritation, nausea, diarrhea, nerve depression
CHRONIC TOXICITY: Irritation, liver or kidney lesions
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye, skin, liver or
kidney disorders

Not regulated.

XV. REGULATORY INFORMATION

EYE AND SKIN CONTACT: Immediately flush eyes and skin with water for
15 minutes.
INGESTION: If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Seek medical
attention.
INHALATION: Remove individual to fresh air.

EUROPEAN INFORMATION:
EU Symbols: Xn - HARMFUL
Risk Phrases: Harmful if swallowed.
Safety Phrases: If swallowed, seek medical advice immediately (show the
label where possible).
CANADIAN INFORMATION:
WHMIS Classification: D2B
All chemical components of this product are listed on Canada’s DSL list.
U.S. INFORMATION:
All chemical components of this product are listed on the TSCA Inventory.

V. FIRE FIGHTING MEASURES

XVI. OTHER INFORMATION

FLASH POINT: N/A AUTOIGNITION POINT: N/A
FLAMMABILITY LIMITS: UPPER: N/A LOWER: N/A
EXTINGUISHING MEDIA: Dry chemical, carbon dioxide, water spray or foam

VI. ACCIDENTAL RELEASE MEASURES

THE ABOVE INFORMATION IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST
INFORMATION CURRENTLY AVAILABLE TO US. ALL PRODUCTS ARE OFFERED IN
ACCORDANCE WITH THE MANUFACTURER'S CURRENT PRODUCTION SPECIFICATIONS
AND ARE INTENDED SOLELY FOR USE IN ANALYTICAL TESTING. THE MANUFACTURER
SHALL IN NO EVENT BE LIABLE FOR ANY INJURY, LOSS OR DAMAGE RESULTING FROM
THE HANDLING, USE OR MISUSE OF THESE PRODUCTS.

Take up with absorbent material. Place in small containers for disposal.

CHEMets®, ULR CHEMets® and Vacu-vials® are registered trademarks of CHEMetrics, Inc.

IV. FIRST AID MEASURES

VII. HANDLING AND STORAGE
If this product is used as directed, the user will not come in contact with or be
exposed to any of its chemical components.
Wash thoroughly after handling. Avoid contact with eyes.
Fragile. Liquid in glass. Handle with care.
The reagent in these ampoules is light sensitive. Product should be stored in
the dark and at room temperature; however, temperatures up to 120°F or
even below freezing will not normally affect reagent performance.

VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION
OSHA PEL & ACGIH TLV: N/A
PROTECTIVE EQUIPMENT: Safety glasses

B
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SAFETY DATA SHEET

Revised edition no : 1
Date : 15/7/2005
Supersedes : 0/0/0

Nitrous oxide (refrigerated)

AL093B

nó
ó
t
Label 2.2 : Non
flammable, non toxic
gas.

ê
O

Label 5.1 : Oxidizing
substances.

O : Oxidizing

1 IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING
:
:
:
:

Nitrous oxide (refrigerated)
AL093B
N2O
AIR LIQUIDE SA
France
See paragraph 16 "OTHER INFORMATION"
: See paragraph 16 "OTHER INFORMATION"

Trade name
MSDS No
Chemical formula
Company identification

Emergency phone nr

2 COMPOSITION / INFORMATION ON INGREDIENTS
: Substance.

Substance / Preparation
Substance name
Nitrous oxide (refrigerated)

:

Contents
100 %

CAS No
10024-97-2

EC No
233-032-0

Index No
-----

Classification
O; R8

Contains no other components or impurities which will influence the classification of the product.

3 HAZARDS IDENTIFICATION
Hazards identification

: Refrigerated liquefied gas. Contact with product may cause cold burns or frostbite.
Oxidant. Strongly supports combustion. May react violently with combustible
materials.

4 FIRST AID MEASURES
First aid measures
- Inhalation

- Skin/eye contact

- Ingestion

: In high concentrations may cause asphyxiation. Symptoms may include loss of
mobility/consciousness. Victim may not be aware of asphyxiation.
In low concentrations may cause narcotic effects. Symptoms may include
dizziness, headache, nausea and loss of co-ordination.
Remove victim to uncontaminated area wearing self contained breathing
apparatus. Keep victim warm and rested. Call a doctor. Apply artificial respiration if
breathing stopped.
: Immediately flush eyes thoroughly with water for at least 15 minutes.
In case of frostbite spray with water for at least 15 minutes. Apply a sterile dressing.
Obtain medical assistance.
: Ingestion is not considered a potential route of exposure.

5 FIRE-FIGHTING MEASURES
Flammable class
Specific hazards
Hazardous combustion products

AIR LIQUIDE SA
France

: Non flammable.
: Exposure to fire may cause containers to rupture/explode.
Supports combustion.
: If involved in a fire the following toxic and/or corrosive fumes may be produced by
thermal decomposition :
Nitric oxide/nitrogen dioxide.

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SAFETY DATA SHEET

Revised edition no : 1
Date : 15/7/2005
Supersedes : 0/0/0

Nitrous oxide (refrigerated)

AL093B

5 FIRE-FIGHTING MEASURES (continued)
Extinguishing media
- Suitable extinguishing media
Specific methods

: All known extinguishants can be used.
: If possible, stop flow of product.
Move away from the container and cool with water from a protected position.
If leaking do not spray water onto container. Water surrounding area (from
protected position) to contain fire.
Special protective equipment for fire : Use self-contained breathing apparatus and chemically protective clothing.
fighters

6 ACCIDENTAL RELEASE MEASURES
Personal precautions

Environmental precautions

Clean up methods

: Evacuate area.
Ensure adequate air ventilation.
Eliminate ignition sources.
Wear self-contained breathing apparatus when entering area unless atmosphere is
proved to be safe.
Use protective clothing.
: Try to stop release.
Prevent from entering sewers, basements and workpits, or any place where its
accumulation can be dangerous.
: Ventilate area.
Keep area evacuated and free from ignition sources until any spilled liquid has
evaporated. (Ground free from frost).

7 HANDLING AND STORAGE
Storage
Handling

: Segregate from flammable gases and other flammable materials in store.
Keep container below 50°C in a well ventilated place.
: Use no oil or grease.
Open valve slowly to avoid pressure shock.
Suck back of water into the container must be prevented.
Do not allow backfeed into the container.
Use only properly specified equipment which is suitable for this product, its supply
pressure and temperature. Contact your gas supplier if in doubt.
Keep away from ignition sources (including static discharges).
Refer to supplier's container handling instructions.

8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection

Occupational Exposure Limits

: Do not smoke while handling product.
Ensure adequate ventilation.
Protect eyes, face and skin from liquid splashes.
: Nitrous oxide (refrigerated) : TLV© -TWA [ppm] : 50
Nitrous oxide (refrigerated) : OEL (UK)-LTEL [ppm] : 100
Nitrous oxide (refrigerated) : MAK - Germany [ppm] : 100

9 PHYSICAL AND CHEMICAL PROPERTIES
Physical state at 20 °C
Colour
Odo(u)r

AIR LIQUIDE SA
France

: Refrigerated liquefied gas.
: Colourless liquid.
: Sweetish.
Poor warning properties at high concentrations.

B
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SAFETY DATA SHEET

Revised edition no : 1
Date : 15/7/2005
Supersedes : 0/0/0

Nitrous oxide (refrigerated)

AL093B

9 PHYSICAL AND CHEMICAL PROPERTIES (continued)
Molecular weight
Melting point [°C]
Boiling point [°C]
Critical temperature [°C]
Vapour pressure, 20°C
Relative density, gas (air=1)
Relative density, liquid (water=1)
Solubility in water [mg/l]
Flammability range [vol% in air]
Auto-ignition temperature [°C]
Other data

:
:
:
:
:
:
:
:
:
:
:

44
-90.81
-88.5
36.4
50.8 bar
1.5
1.2
2.2
Oxidiser.
Not applicable.
Gas/vapour heavier than air. May accumulate in confined spaces, particularly at or
below ground level.

10 STABILITY AND REACTIVITY
Stability and reactivity

: May react violently with combustible materials.
May react violently with reducing agents.
Violently oxidises organic material.
Thermal decomposition yields toxic products which can be corrosive in the
presence of moisture. At temperatures over 575°C and at atmospheric pressure,
nitrous oxide decomposes into nitrogen and oxygen. Pressurized nitrous oxide can
also decompose at temperatures equal or greater than 300°C. In the presence of
catalysts (e.g. halogen products, mercury, nickel, platinum) the rate of
decomposition increases and decomposition can occur at even lower
temperatures. Nitrous oxide dissociation is irreversible and exothermic, leading to a
considerable rise in pressure.
Liquid spillages can cause embrittlement of structural materials.

11 TOXICOLOGICAL INFORMATION
Toxicity information

: No known toxicological effects from this product.

12 ECOLOGICAL INFORMATION
Ecological effects information
Global warming factor [CO2=1]

: Can cause frost damage to vegetation.
When discharged in large quantities may contribute to the greenhouse effect.
: 310

13 DISPOSAL CONSIDERATIONS
General

: To atmosphere in a well ventilated place.
Do not discharge into any place where its accumulation could be dangerous.
Contact supplier if guidance is required.
Discharge to atmosphere in large quantities should be avoided.

14 TRANSPORT INFORMATION
UN No.
H.I. nr
ADR/RID

AIR LIQUIDE SA
France

: 2201
: 225

B
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SAFETY DATA SHEET

Revised edition no : 1
Date : 15/7/2005
Supersedes : 0/0/0

Nitrous oxide (refrigerated)

AL093B

14 TRANSPORT INFORMATION (continued)
- Proper shipping name
- ADR Class
- ADR/RID Classification code
- Labelling ADR
Other transport information

:
:
:
:

NITROUS OXIDE, REFRIGERATED LIQUID
2
3O
Label 2.2 : Non flammable, non toxic gas.
Label 5.1 : Oxidizing substances.
: Avoid transport on vehicles where the load space is not separated from the driver's
compartment.
Ensure vehicle driver is aware of the potential hazards of the load and knows what
to do in the event of an accident or an emergency.
Before transporting product containers :
- Ensure that containers are firmly secured.
- Ensure cylinder valve is closed and not leaking.
- Ensure valve outlet cap nut or plug (where provided) is correctly fitted.
- Ensure valve protection device (where provided) is correctly fitted.
- Ensure there is adequate ventilation.
- Compliance with applicable regulations.

15 REGULATORY INFORMATION
EC Classification

EC Labelling
- Symbol(s)
- R Phrase(s)
- S Phrase(s)

: Not included in Annex I.
Proposed by the industry.
O; R8
: O : Oxidizing
: R8 : Contact with combustible material may cause fire.
: S9 : Keep container in a well-ventilated place.
S17 : Keep away from combustible material.
S36 : Wear suitable protective clothing.

16 OTHER INFORMATION
Asphyxiant in high concentrations.
May cause frostbite.
The hazard of asphyxiation is often overlooked and must be stressed during operator training.
Ensure all national/local regulations are observed.
This Safety Data Sheet has been established in accordance with the applicable European Directives and applies to all
countries that have translated the Directives in their national laws.
Before using this product in any new process or experiment, a thorough material compatibility and safety study should be
carried out.
Details given in this document are believed to be correct at the time of going to press. Whilst proper care has been taken in
the preparation of this document, no liability for injury or damage resulting from its use can be accepted.
Recommended uses and restrictions : This SDS is for information purposes only and is subject to change without notice. [
Prior to purchase of products, please contact your local AIR LIQUIDE office for a
complete SDS (with Manufacturer's name and emergency phone number).]
End of document

AIR LIQUIDE SA
France

Material Safety Data Sheet: Nitrogen

Product Name: Nitrogen

CAS: 7727-37-9

Nitrogen; Nitrogen, compressed (D.O.T.)

DOT I.D No.: UN 1066

Chemical Name and Synonyms:
Nitrogen

DOT Hazard Class: Division 2.2

Formula: N2

Chemical Family: Inert Gas

HEALTH HAZARD DATA
Time Weighted Average Exposure Limit:
Nitrogen is defined as a simple asphyxiant (ACGIH 1994-1995i; OSHA 1993 PEL (8 Hr.
TWA) = None listed.
Symptoms of Exposure:
Effects of exposure to high concentrations so as to displace the oxygen in air necessary
for life may include any, all or none of the following: • Loss of balance or dizziness •
Tightness in the frontal area of the forehead.
Toxicological Properties:
•

Nitrogen is nontoxic but the liberation of a large amount in a confined area could
displace the amount of oxygen in air necessary to support life.

•

Nitrogen is not listed in the LARC, NTP or by OSHA as a carcinogen or potential
carcinogen.

•

Persons in ill health where such illness would be aggravated by exposure to
nitrogen should not be allowed to work with or handle this product.

Recommended First Aid Treatment:
Prompt medical attention is mandatory in all cases of overexposure to nitrogen. Rescue
personnel should be equipped with self-contained breathing apparatus.

Inhalation: Conscious persons should be assisted to an uncontaminated area and inhale
fresh air. Quick removal from the contaminated area is most important. Unconscious
persons should be moved to an uncontaminated area, given assisted respiration and
supplemental oxygen. Further treatment should be symptomatic and supportive.

Hazardous Mixtures of other Liquids, Solids or Gases:
None.
PHYSICAL DATA
Boiling Point: -320.5°F (-195.8°C)

Liquid Density at Boiling Point:
4.43 lb/ft3 (70.96 kg/m3)

Vapor Pressure @ 70°F (21.1°C) = Above the
critical temperature of -232.6°F (-147°C)

Gas Density at 70°F. 1 atm .0725
lb/ft3 (1.161 kq/m3)

Solubility in Water: Very slightly

Freezing Point: -345.9°F (-209.9°C)

Evaporation Rate: N/A (Gas)

Specific Gravity (AIR=1) @ 70°F
(21.1°C) = 0.97

Appearance and Odor: Colorless, odorless gas

FIRE AND EXPLOSION HAZARD DATA
Flash Point (Method used):
N/A Gas

Auto Ignition Temperature:
N/A

Extinguishing Media: Carbon dioxide, dry chemical

Flammable Limits %
by Volume: LEL N/A
UEL N/A
Electrical
Classification:
Nonhazardous

Special Fire fighting Procedures: Nonflammable inert gas
Unusual Fire and Explosion Hazards: If cylinders are involved in a fire, safely relocate or
keep cool with water spray.

REACTIVITY DATA
Stability: Stable
Incompatibility (Materials to Avoid): None
Hazardous Decomposition Products: None
Hazardous Polymerization: Will not occur
Conditions to Avoid: None

SPILL OR LEAK PROCEDURES
Steps to be taken in case material is released or spilled:
Evacuate all personnel from affected area. Use appropriate protective equipment. If leak
is in container or container valve, contact your closest supplier location or call the
emergency telephone number listed herein.
Waste disposal methods:
Do not attempt to dispose of waste or unused quantities. Return in the shipping
container properly labeled, with any valve outlet plugs or caps secured and valve
protection cap in place to your supplier. For emergency disposal assistance, contact
your closest supplier location or call the emergency telephone number listed herein.

SPECIAL PROTECTION INFORMATION
Respiratory Protection (Specify type): Positive pressure air line with mask or selfcontained breathing apparatus should be available for emergency use.
Ventilation: See Local Exhaust
Protective Gloves: Any material
Eye Protection: Safety goggles or glasses
Other Protective Equipment: Safety shoes

SPECIAL PRECAUTIONS
Special Labeling Information:
DOT Shipping Name: Nitrogen, Compressed
DOT Hazard Class: Division 2.2
DOT Shipping Label: Nonflammable Gas
I.D. No.: UN 1066
Special Handling Recommendation:
Use only in well-ventilated areas. Valve protection caps must remain in place unless
cylinder is secured with valve outlet piped to use point. Do not drag, slide or roll
cylinders. Use a suitable hand truck for cylinder movement. Use a pressure reducing
regulator when connecting cylinder to lower pressure (<3,000 psig) piping or systems.
Do not heat cylinder by any means to increase the discharge rate of product from
cylinder. Use a check valve or trap in the discharge line to prevent hazardous back flow
into the cylinder. For additional handling recommendations, consult Compressed Gas
Association’s Pamphlets P-1, P-9, P-14, and Safety Bulletin SB-2.

Special Storage Recommendations:
Protect cylinders from physical damage. Store in cool, dry, well-ventilated area away
from heavily trafficked areas and emergency exits. Do not allow the temperature where
cylinders are stored to exceed 125F (52C). Cylinders should be stored upright and firmly
secured to prevent falling or being knocked over. Full and empty cylinders should be
segregated. Use a “first in -first out” inventory system to prevent full cylinders being
stored for excessive periods of time. For additional storage recommendations, consult
Compressed Gas Association’s Pamphlets P-1, P-9, P-14, and Safety Bulletin SB-2.
Other Recommendations or Precautions:
Compressed gas cylinders should not be refilled except by qualified producers of
compressed gases. Shipment of a compressed gas cylinder which has not been filled by
the owner or with his (written) consent is a violation of Federal Law (49CFR).
Special Packaging Recommendations:
Nitrogen is non-corrosive and may be used with any common structural materials.

www.isocinfo.com

Material Safety Data Sheet: Nitrogen

Product Name: Nitrogen

CAS: 7727-37-9

Nitrogen; Nitrogen, compressed (D.O.T.)

DOT I.D No.: UN 1066

Chemical Name and Synonyms:
Nitrogen

DOT Hazard Class: Division 2.2

Formula: N2

Chemical Family: Inert Gas

HEALTH HAZARD DATA
Time Weighted Average Exposure Limit:
Nitrogen is defined as a simple asphyxiant (ACGIH 1994-1995i; OSHA 1993 PEL (8 Hr.
TWA) = None listed.
Symptoms of Exposure:
Effects of exposure to high concentrations so as to displace the oxygen in air necessary
for life may include any, all or none of the following: • Loss of balance or dizziness •
Tightness in the frontal area of the forehead.
Toxicological Properties:
•

Nitrogen is nontoxic but the liberation of a large amount in a confined area could
displace the amount of oxygen in air necessary to support life.

•

Nitrogen is not listed in the LARC, NTP or by OSHA as a carcinogen or potential
carcinogen.

•

Persons in ill health where such illness would be aggravated by exposure to
nitrogen should not be allowed to work with or handle this product.

Recommended First Aid Treatment:
Prompt medical attention is mandatory in all cases of overexposure to nitrogen. Rescue
personnel should be equipped with self-contained breathing apparatus.

Inhalation: Conscious persons should be assisted to an uncontaminated area and inhale
fresh air. Quick removal from the contaminated area is most important. Unconscious
persons should be moved to an uncontaminated area, given assisted respiration and
supplemental oxygen. Further treatment should be symptomatic and supportive.

Hazardous Mixtures of other Liquids, Solids or Gases:
None.
PHYSICAL DATA
Boiling Point: -320.5°F (-195.8°C)

Liquid Density at Boiling Point:
4.43 lb/ft3 (70.96 kg/m3)

Vapor Pressure @ 70°F (21.1°C) = Above the
critical temperature of -232.6°F (-147°C)

Gas Density at 70°F. 1 atm .0725
lb/ft3 (1.161 kq/m3)

Solubility in Water: Very slightly

Freezing Point: -345.9°F (-209.9°C)

Evaporation Rate: N/A (Gas)

Specific Gravity (AIR=1) @ 70°F
(21.1°C) = 0.97

Appearance and Odor: Colorless, odorless gas

FIRE AND EXPLOSION HAZARD DATA
Flash Point (Method used):
N/A Gas

Auto Ignition Temperature:
N/A

Extinguishing Media: Carbon dioxide, dry chemical

Flammable Limits %
by Volume: LEL N/A
UEL N/A
Electrical
Classification:
Nonhazardous

Special Fire fighting Procedures: Nonflammable inert gas
Unusual Fire and Explosion Hazards: If cylinders are involved in a fire, safely relocate or
keep cool with water spray.

REACTIVITY DATA
Stability: Stable
Incompatibility (Materials to Avoid): None
Hazardous Decomposition Products: None
Hazardous Polymerization: Will not occur
Conditions to Avoid: None

SPILL OR LEAK PROCEDURES
Steps to be taken in case material is released or spilled:
Evacuate all personnel from affected area. Use appropriate protective equipment. If leak
is in container or container valve, contact your closest supplier location or call the
emergency telephone number listed herein.
Waste disposal methods:
Do not attempt to dispose of waste or unused quantities. Return in the shipping
container properly labeled, with any valve outlet plugs or caps secured and valve
protection cap in place to your supplier. For emergency disposal assistance, contact
your closest supplier location or call the emergency telephone number listed herein.

SPECIAL PROTECTION INFORMATION
Respiratory Protection (Specify type): Positive pressure air line with mask or selfcontained breathing apparatus should be available for emergency use.
Ventilation: See Local Exhaust
Protective Gloves: Any material
Eye Protection: Safety goggles or glasses
Other Protective Equipment: Safety shoes

SPECIAL PRECAUTIONS
Special Labeling Information:
DOT Shipping Name: Nitrogen, Compressed
DOT Hazard Class: Division 2.2
DOT Shipping Label: Nonflammable Gas
I.D. No.: UN 1066
Special Handling Recommendation:
Use only in well-ventilated areas. Valve protection caps must remain in place unless
cylinder is secured with valve outlet piped to use point. Do not drag, slide or roll
cylinders. Use a suitable hand truck for cylinder movement. Use a pressure reducing
regulator when connecting cylinder to lower pressure (<3,000 psig) piping or systems.
Do not heat cylinder by any means to increase the discharge rate of product from
cylinder. Use a check valve or trap in the discharge line to prevent hazardous back flow
into the cylinder. For additional handling recommendations, consult Compressed Gas
Association’s Pamphlets P-1, P-9, P-14, and Safety Bulletin SB-2.

Special Storage Recommendations:
Protect cylinders from physical damage. Store in cool, dry, well-ventilated area away
from heavily trafficked areas and emergency exits. Do not allow the temperature where
cylinders are stored to exceed 125F (52C). Cylinders should be stored upright and firmly
secured to prevent falling or being knocked over. Full and empty cylinders should be
segregated. Use a “first in -first out” inventory system to prevent full cylinders being
stored for excessive periods of time. For additional storage recommendations, consult
Compressed Gas Association’s Pamphlets P-1, P-9, P-14, and Safety Bulletin SB-2.
Other Recommendations or Precautions:
Compressed gas cylinders should not be refilled except by qualified producers of
compressed gases. Shipment of a compressed gas cylinder which has not been filled by
the owner or with his (written) consent is a violation of Federal Law (49CFR).
Special Packaging Recommendations:
Nitrogen is non-corrosive and may be used with any common structural materials.

www.isocinfo.com

MATERIAL SAFETY DATA SHEET
S O S PRODUCTS COMPANY INC
PO BOX 47
East Greenville, Pa.
18041
Phone (215)-679-6262
(215)-679-6263
PAGE 1
----------------------------------------------------------------------------SECTION I - GENERAL INFORMATION
----------------------------------------------------------------------------Product Code:
HS
Revision Date: 08/06/07
Identification:
HOT STOP LIQUID
----------------------------------------------------------------------------SECTION II - HAZARDOUS INGREDIENTS
----------------------------------------------------------------------------This product is not classified as hazardous in accordance with OSHA 1910.1200
----------------------------------------------------------------------------Carcinogenicity:
This product is NOT considered to be a carcinogen by the
National Toxicology Program, the International Agency for
Research on Cancer, or the Occupational Safety and Health
Administration.
----------------------------------------------------------------------------SECTION III - PHYSICAL CHARACTERISTICS
----------------------------------------------------------------------------Boiling Point:
230
Specific Gravity:
1.00
Vapor Pressure:
17.00
Melting Point:
NOT APPLICABLE
Vapor Density:
.06
Evaporation Rate:
GT 1
Solubility in Water:
SOLUBLE
Odor and Appearance:
----------------------------------------------------------------------------SECTION IV - FIRE AND EXPLOSION HAZARD DATA
----------------------------------------------------------------------------Flash Point:
NOT APPLICABLE
LEL:
N/A
Flammable Limits:
NONE
VEL:
N/A
Extinguishing Media:
NOT APPLICABLE
Special Fire Fighting Procedures: WATER FOG, DRY CHEMICAL. NONE.
Unusual Fire and Explosion Hazards:
NOT APPLICABLE
----------------------------------------------------------------------------SECTION V - REACTIVITY DATA
----------------------------------------------------------------------------This product is STABLE.
Conditions to avoid:
NONE
Incompatibility:
COMPATIBLE
Hazardous Decomposition:
NONE
Hazardous Polymerization:
WILL NOT OCCUR
----------------------------------------------------------------------------SECTION VI - HEALTH HAZARD DATA
----------------------------------------------------------------------------Routes of Entry:
Inhalation?
NO
Skin?
YES - PRIMARY
Ingestion?
YES - SECONDARY
Health Hazards (Acute and Chronic): NONE KNOWN
Carcinogenicity:

NTP?
NO
IARC Monographs?
NO
OSHA Regulated?
NO
Signs and Symptoms of Exposure:
NONE

Medical Conditions Generally Aggravated by Exposure:
NONE KNOWN
Emergency and First Aid Procedures:
EYE: FLUSH 15 MINUTES AND CALL PHYCIAN. SKIN WASH WITH SOAP
AND WATER.
INGESTION: DO NOT INDUCE VOMITING CALL PHYSICAN
----------------------------------------------------------------------------SECTION VII - HANDLING PRECAUTIONS
----------------------------------------------------------------------------Steps to be Taken if Material is Released or Spilled:
FLUSH WITH WATER INTO DRAIN; SOAK UP REMAINDER WITH
OBSORBENT FLOOR
COMPOUND & SWEEP UP.
Waste Disposal Method:
NON-HAZARDOUS LANDFILL.

COMPLY WITH LOCAL ORDINANCES

Precautions to be Taken in Handling and Storage: NONE
Other Precautions: NONE
----------------------------------------------------------------------------SECTION VIII - CONTROL MEASURES
----------------------------------------------------------------------------Respiratory Protection:
NONE REQUIRED
Ventilation Required:
LOCAL EXHAUST ADEQUATE
Protective Gloves:
NOT REQUIRED
Eye Protection:
SAFETY GOGGLES
Other Protective Equipment:
NONE REQUIRED FOR NORMAL USE
Work/Hygienic Practices:
WASH AFTER USING
----------------------------------------------------------------------------The above information pertains to the product as it is currently formulated
and is based upon the information available at this time. Additions of
reducers or other additives to this product may substantially alter the
composition and subsequent hazards of the product. Since conditions of use
are outside of our control, we make no warranties, either expressed or
implied, and assume no liability in connection with any use of this
information.

Kidde de México

Av. División del Golfo 3308
87019 Cd. Victoria, Tamaulipas, México
e-mail: kidde.mexico@kidde.com.mx

MATERIAL SAFETY DATA SHEET
ABC 90 DRY CHEMICAL POWDER – POLVO QUÍMICO SECO ABC 90

SECTION 1 – CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Trade Name / Label Name:

ABC 90% Made to Badger Formulation

CAS Number:

N/A

Chemical Name / Family

N/A
It is a mixture
ABC 90 fire extinguishing powder
Multipurpose Fire extinguishing agent
KIDDE DE MEXICO, S. A. de C. V.

Synonyms:
Manufacturer's Name:

Business phone / Fax:

Av. División del Golfo 3308 Nte.
87019 Cd. Victoria, Tamaulipas, MÉXICO
+52 (834) 318-75-00 / +52 (834) 318-75-29

Date of preparation:

October 13, 2005

Address:

SECTION 2 – COMPOSITION AND INFORMATION ON INGREDIENTS
CAS N°

% w/w

OSHA PEL
mg/m3

ACGIH TLV
mg/m3

TOXICITY
DATA

Monoammonium phosphate

7722-76-1

92 - 94

NONE

NONE

NONE

Mica

12001-26-2

1–3

3

3

NONE

Attapulgus clay

8031-18-3

2-4

NONE

NONE

NONE

Amorphous silica

7631-86-9

0.2 – 1.5

6

10

NONE

Methyl Hydrogen Polysiloxane

63148-57-2

0.4 – 1.0

NONE

NONE

NONE

CHEMICAL NAME

SECTION 3 – PHYSICAL AND CHEMICAL CHARACTERISTICS
Boiling point, °C:
Vapor pressure, mm
Hg:
Vapor density
(Air=1):
Reactivity in water:

Document: GT05310

N/A
N/A
N/A
Unreactive

Specific gravity
(H20=1)
Percent volatile by
volume:
Evaporation rate
(Butyl acetate=1)
Appearance and
odor:

ABOUT 1.9

Viscosity @ 20°C:

N/A

N/A

Melting point, °C:

NDA

N/A

Solubility in water:

22.7 g/100g

Odorless, pale yellow coloured fine powder

Issuing date: 13/10/05

Document: GT05310

Page 2 of 3

SECTION 4 – FIRE AND EXPLOSION HAZARD DATA
Flash point:

Flammable limits in
air, % by volume

N/A

N/A

Auto-ignition
temperature:

Extinguishing media:

N/A – The product is a fire extinguishing agent

Unusual fire and explosion
hazards:

NONE

Special fire fighting procedures:

N/A

The material is a fire extinguishing agent and will not burn. However, if other
materials are involved, use standard chemical fire fighting procedures and
consider the hazards of those materials. In enclosed areas, fire fighters must
wear self-contained breathing apparatus and full protective equipment.

SECTION 5 – REACTIVITY DATA
Stability:

Stable

Incompatibility (materials to
avoid):
Hazardous decomposition
products:

Conditions to avoid:

Extreme
heat

Hazardous
polymerization:

Will not
occur

Strong alkalis. Do not mix with BC type dry chemical extinguishing agents.
Ammonia, phosphorus oxides.

SECTION 6 – HEALTH HAZARD DATA
Threshold limit value:
Routes of entry:
Signs and symptoms of
overexposure:
Medical conditions generally
aggravated by exposure:
Chemical listed as carcinogen or
potential:

Emergency and first aid
procedures:

ACGIH TLV for particulates not otherwise classified: 10 mg/m3
OSHA PEL for nuisance dust limit total: 15 mg/m3
Inhalation: YES; may be irritant to the respiratory tract.
Eye contact: YES; mildly irritant for a short period.
Skin contact: YES; may be mildly irritating.
Ingestion: NOT an expected route of entry.
Acute: Transient cough, shortness of breath, irritation of airways.
Chronic: This product is not known to cause chronic illness.
Asthma, emphysema, bronchitis or other respiratory illness.
NTP program: No

IARC monographs: No

OSHA: No

Eye contact: Flush with large amounts of water for at least 15 minutes. If
irritation persists, seek medical attention.
Skin contact: Wash with soap and water. If irritation persists, seek medical
attention.
Inhalation: Move victim to fresh air. Seek medical attention if discomfort
continues.
Ingestion: Rinse mouth, drink large amounts of water and induce vomiting.
Seek medical help.

SECTION 7 – SPECIAL PRECAUTIONS AND SPILL / LEAK PROCEDURES
Precautions to be taken in
handling and storage:

Should be stored in original containers. Store in dry, cool, well-ventilated
place away from alkaline compounds. Wash after handling. Do not cut, grind,
weld or drill on or near product containers. Treat empty containers as if they
were full.

Other precautions:

Do not mix with alkaline materials.

Steps to be taken in case
materials is released or spilled:
Waste disposal method:

Direction of Operations

Sweep up or vacuum. Store in covered containers. Do not reuse. In case of
large spills, use rubber gloves, chemically resistant suit and boots, hard hat
and air purifying respirator.
Dispose of in compliance with local, state and federal regulations.
Components are non hazardous, sanitary landfill disposal may be acceptable
Issuing date: 13/10/05

Document: GT05310

Page 3 of 3

SECTION 8 – SPECIAL PROTECTION INFORMATION
Respiratory protection:

Dust mask where dustiness is prevalent or TLV exceeded. Mechanical filter
respirator if exposure is prolonged.

Ventilation:

Use adequate ventilation. Use fan or vent to outside.

Protective gloves:

Wear rubber gloves for routine industrial use.

Eye protection:

Recommended as mechanical barrier for prolonged exposure. Safety glasses
or chemical type goggles.

Other protective equipment:

If irritation occurs, long sleeves and impervious gloves should be worn.

Work / Hygienic practices:

Use good personal hygiene and good housekeeping practices. Avoid breathing
of dust. Wash with soap and water.

SECTION 9 – REGULATORY INFORMATION
U.S. OSHA HAZARD
COMMUNICATION STANDARD

RCRA INFORMATION

SARA Reporting Requirements

TSCA Inventory status

Product assessed in accordance with OSHA 20 CFR 1910.1200 and
determined not to be hazardous.
The unused product, in our opinion, is not specifically listed by the EPA as
hazardous waste (40 CFR, Part 261D), nor is it formulated to contain
materials which are listed hazardous wastes. It does not exhibit the hazardous
characteristics of ignitability, corrosivity or reactivity, and is not formulated
with contaminants as determined by the toxicity characteristics leaching
procedure (TCLP). However, used product may be regulated.
No component of this product is subject to the reporting requirements of
Sections 302, 304 and 313 of Title III of the Superfund Amendments and
Reauthorization Act.
Kidde de México certifies that the product described herein complies with all
applicable rules or orders under TSCA and no chemical substance for entry in
violation under TSCA or any applicable rule or order thereunder TSCA is being
offered.

HAZARDOUS MATERIAL IDENTIFICATION SYSTEM RATINGS
HEALTH:
1
HAZARD INDEX:
0 Minimal hazard
1 Slight hazard
2 Moderate hazard
3 Serious hazard
4 Sever hazard

FLAMMABILITY:

0

REACTIVITY:

0

GENERAL KEYS:
N/A: Not applicable.
NDA: No data available.

The information herein is given in good faith. It is based on available data and is believed to be true
and accurate, but no warranty, expressed or implied, is made. Therefore, KIDDE DE MEXICO.
assumes NO responsibility for damage or injury from the use of the product described herein.

Direction of Operations

Issuing date: 13/10/05

Kidde de México

Av. División del Golfo 3308
87019 Cd. Victoria, Tamaulipas, México
e-mail: kidde.mexico@kidde.com.mx

MATERIAL SAFETY DATA SHEET
ABC 90 DRY CHEMICAL POWDER – POLVO QUÍMICO SECO ABC 90

SECTION 1 – CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Trade Name / Label Name:

ABC 90% Made to Badger Formulation

CAS Number:

N/A

Chemical Name / Family

N/A
It is a mixture
ABC 90 fire extinguishing powder
Multipurpose Fire extinguishing agent
KIDDE DE MEXICO, S. A. de C. V.

Synonyms:
Manufacturer's Name:

Business phone / Fax:

Av. División del Golfo 3308 Nte.
87019 Cd. Victoria, Tamaulipas, MÉXICO
+52 (834) 318-75-00 / +52 (834) 318-75-29

Date of preparation:

October 13, 2005

Address:

SECTION 2 – COMPOSITION AND INFORMATION ON INGREDIENTS
CAS N°

% w/w

OSHA PEL
mg/m3

ACGIH TLV
mg/m3

TOXICITY
DATA

Monoammonium phosphate

7722-76-1

92 - 94

NONE

NONE

NONE

Mica

12001-26-2

1–3

3

3

NONE

Attapulgus clay

8031-18-3

2-4

NONE

NONE

NONE

Amorphous silica

7631-86-9

0.2 – 1.5

6

10

NONE

Methyl Hydrogen Polysiloxane

63148-57-2

0.4 – 1.0

NONE

NONE

NONE

CHEMICAL NAME

SECTION 3 – PHYSICAL AND CHEMICAL CHARACTERISTICS
Boiling point, °C:
Vapor pressure, mm
Hg:
Vapor density
(Air=1):
Reactivity in water:

Document: GT05310

N/A
N/A
N/A
Unreactive

Specific gravity
(H20=1)
Percent volatile by
volume:
Evaporation rate
(Butyl acetate=1)
Appearance and
odor:

ABOUT 1.9

Viscosity @ 20°C:

N/A

N/A

Melting point, °C:

NDA

N/A

Solubility in water:

22.7 g/100g

Odorless, pale yellow coloured fine powder

Issuing date: 13/10/05

Document: GT05310

Page 2 of 3

SECTION 4 – FIRE AND EXPLOSION HAZARD DATA
Flash point:

Flammable limits in
air, % by volume

N/A

N/A

Auto-ignition
temperature:

Extinguishing media:

N/A – The product is a fire extinguishing agent

Unusual fire and explosion
hazards:

NONE

Special fire fighting procedures:

N/A

The material is a fire extinguishing agent and will not burn. However, if other
materials are involved, use standard chemical fire fighting procedures and
consider the hazards of those materials. In enclosed areas, fire fighters must
wear self-contained breathing apparatus and full protective equipment.

SECTION 5 – REACTIVITY DATA
Stability:

Stable

Incompatibility (materials to
avoid):
Hazardous decomposition
products:

Conditions to avoid:

Extreme
heat

Hazardous
polymerization:

Will not
occur

Strong alkalis. Do not mix with BC type dry chemical extinguishing agents.
Ammonia, phosphorus oxides.

SECTION 6 – HEALTH HAZARD DATA
Threshold limit value:
Routes of entry:
Signs and symptoms of
overexposure:
Medical conditions generally
aggravated by exposure:
Chemical listed as carcinogen or
potential:

Emergency and first aid
procedures:

ACGIH TLV for particulates not otherwise classified: 10 mg/m3
OSHA PEL for nuisance dust limit total: 15 mg/m3
Inhalation: YES; may be irritant to the respiratory tract.
Eye contact: YES; mildly irritant for a short period.
Skin contact: YES; may be mildly irritating.
Ingestion: NOT an expected route of entry.
Acute: Transient cough, shortness of breath, irritation of airways.
Chronic: This product is not known to cause chronic illness.
Asthma, emphysema, bronchitis or other respiratory illness.
NTP program: No

IARC monographs: No

OSHA: No

Eye contact: Flush with large amounts of water for at least 15 minutes. If
irritation persists, seek medical attention.
Skin contact: Wash with soap and water. If irritation persists, seek medical
attention.
Inhalation: Move victim to fresh air. Seek medical attention if discomfort
continues.
Ingestion: Rinse mouth, drink large amounts of water and induce vomiting.
Seek medical help.

SECTION 7 – SPECIAL PRECAUTIONS AND SPILL / LEAK PROCEDURES
Precautions to be taken in
handling and storage:

Should be stored in original containers. Store in dry, cool, well-ventilated
place away from alkaline compounds. Wash after handling. Do not cut, grind,
weld or drill on or near product containers. Treat empty containers as if they
were full.

Other precautions:

Do not mix with alkaline materials.

Steps to be taken in case
materials is released or spilled:
Waste disposal method:

Direction of Operations

Sweep up or vacuum. Store in covered containers. Do not reuse. In case of
large spills, use rubber gloves, chemically resistant suit and boots, hard hat
and air purifying respirator.
Dispose of in compliance with local, state and federal regulations.
Components are non hazardous, sanitary landfill disposal may be acceptable
Issuing date: 13/10/05

Document: GT05310

Page 3 of 3

SECTION 8 – SPECIAL PROTECTION INFORMATION
Respiratory protection:

Dust mask where dustiness is prevalent or TLV exceeded. Mechanical filter
respirator if exposure is prolonged.

Ventilation:

Use adequate ventilation. Use fan or vent to outside.

Protective gloves:

Wear rubber gloves for routine industrial use.

Eye protection:

Recommended as mechanical barrier for prolonged exposure. Safety glasses
or chemical type goggles.

Other protective equipment:

If irritation occurs, long sleeves and impervious gloves should be worn.

Work / Hygienic practices:

Use good personal hygiene and good housekeeping practices. Avoid breathing
of dust. Wash with soap and water.

SECTION 9 – REGULATORY INFORMATION
U.S. OSHA HAZARD
COMMUNICATION STANDARD

RCRA INFORMATION

SARA Reporting Requirements

TSCA Inventory status

Product assessed in accordance with OSHA 20 CFR 1910.1200 and
determined not to be hazardous.
The unused product, in our opinion, is not specifically listed by the EPA as
hazardous waste (40 CFR, Part 261D), nor is it formulated to contain
materials which are listed hazardous wastes. It does not exhibit the hazardous
characteristics of ignitability, corrosivity or reactivity, and is not formulated
with contaminants as determined by the toxicity characteristics leaching
procedure (TCLP). However, used product may be regulated.
No component of this product is subject to the reporting requirements of
Sections 302, 304 and 313 of Title III of the Superfund Amendments and
Reauthorization Act.
Kidde de México certifies that the product described herein complies with all
applicable rules or orders under TSCA and no chemical substance for entry in
violation under TSCA or any applicable rule or order thereunder TSCA is being
offered.

HAZARDOUS MATERIAL IDENTIFICATION SYSTEM RATINGS
HEALTH:
1
HAZARD INDEX:
0 Minimal hazard
1 Slight hazard
2 Moderate hazard
3 Serious hazard
4 Sever hazard

FLAMMABILITY:

0

REACTIVITY:

0

GENERAL KEYS:
N/A: Not applicable.
NDA: No data available.

The information herein is given in good faith. It is based on available data and is believed to be true
and accurate, but no warranty, expressed or implied, is made. Therefore, KIDDE DE MEXICO.
assumes NO responsibility for damage or injury from the use of the product described herein.

Direction of Operations

Issuing date: 13/10/05

MATERIAL SAFETY DATA SHEET

Section 1. Chemical product and company identification
Product Name:
Synonym:
Manufacturer:
Internet Address:
Address:

Super D Dry Powder Extinguishant
Class D Powder
AMEREX CORPORATION
www.amerex-fire.com
7595 Gadsden Highway
P.O. Box 81
Trussville, AL 35173-0081
(205) 655-3271
Chemtrec 1(800) 424-9300 or
(703) 527–3887
December, 2003

Telephone:
Emergency Contacts:
Revised:

Section 2. Hazard identification and emergency overview
Emergency overview: Off-white, fine solid powder, odorless.
Adverse health effects and symptoms: Moderate irritant to the respiratory system and
eyes; mild irritant to the skin. Symptoms may include stinging of eyes and abraded
skin, coughing, shortness of breath, and irritation of the lungs, eyes, and skin.
Exposure guidelines:
Ingredients
Sodium chloride
Mica
Attapulgite clay
Mineralite (Zeolite)
Magnesium stearate

OSHA PEL

ACGIH TLV

DFG MAK *

PNOC**
Total dust, 15 mg/m3
Respirable fraction, 5 mg/m3

PNOC
Total dust, 10 mg/m3
Respirable fraction, 3 mg/m3

20 mppcf***
PNOC
Total dust, 15 mg/m3
Respirable fraction, 5 mg/m3

3 mg/m3 respirable fraction
PNOC
Total dust, 10 mg/m3
Respirable fraction, 3 mg/m3

PNOC
Total dust, 4 mg/m3
Respirable fraction,
1.5 mg/m3
------PNOC
Total dust, 4 mg/m3
Respirable fraction,
1.5 mg/m3
4 mg/m3

80 mg/m3
10 mg/m3
% SiO2
PNOC
PNOC
Total dust, 15 mg/m3
Total dust, 10 mg/m3
3
Respirable fraction, 5 mg/m Respirable fraction, 3 mg/m3
Page 1 of 7 Pages
SUPER – D

PNOC
Total dust, 4 mg/m3
Respirable fraction,

1.5 mg/m3
Silica, amorphous (fumed)

PNOC
Total dust, 15 mg/m3
Respirable fraction, 5 mg/m3

2 mg/m3

0.3 mg/m3

*German regulatory limits **PNOC = Particulates not otherwise classified (ACGIH) also known as Particulates not
otherwise regulated (OSHA) *** mppcf = million particles per cubic foot. All values are 8 hour time weighted average
concentrations.

Hazard symbols: WHMIS (Canadian workplace hazardous materials identification
system)
D2B

may irritate eyes, mucous membranes, or skin

Section 3. Composition/information on ingredients
Name/Compound

Weight %

CAS #

Sodium chloride
evaporated flour grade

87

7647-14-5

Attapulgite clay or Fullers earth
magnesium aluminum silicatecontains > 1% crystalline silica

4.2

12174-11-7

Mica
potassium aluminum silicate

4.2

12001-26-2

Zeolite, synthetic
amorphous precipitated silica

2.1

112926-00-8

Silica, amorphous, fumed

<2

69012-64-2

Magnesium stearate
octadecanoic acid, Mg salt

<1

557-04-0

14808-60-7

Section 4. First Aid Measures
Eye Exposure: Irrigate eyes at eye wash station and repeat until pain free. Seek
medical attention if irritation develops or persists, or if visual changes occur.
Skin Exposure: In case of contact, wash with plenty of soap and water. Seek medical
attention if irritation develops or persists.

Page 2 of 7 Pages
SUPER – D

Inhalation: If respiratory irritation or distress occurs remove victim to fresh air. Seek
medical attention if irritation develops or persists.
Ingestion: Not known to present an ingestion hazard.
Medical conditions possibly aggravated by exposure: Inhalation of product may
aggravate existing chronic respiratory problems such as asthma, emphysema, or
bronchitis. Skin contact may aggravate existing skin disease. Chronic overexposure
may cause pneumoconiosis (“dusty lung” disease).

Section 5. Fire fighting measures
Extinguishing media: non combustible and non flammable – product is an
extinguishing agent
Unusual fire/explosion hazards: none known
Insensitive to mechanical impact or static discharge.
HMIS Hazard Ranking:
health = 1, flammability = 0, reactivity = 0, personal protective equipment: use N-95
dust mask (see Section 8)
Section 6. Accidental release measures
Clean up released material using vacuum or wet sweep and shovel to minimize
generation of dust. Wear appropriate respiratory protection. Bag and drum for
disposal. If product is used and/or contaminated, use PPE and containment
appropriate to the nature of the mixture.

Section 7. Handling and storage
Avoid skin, eye, or respiratory exposure. Use appropriate PPE when handling or
maintaining equipment, and wash thoroughly after handling (see Section 8). Keep
product in original container or extinguisher. Contents may be under pressure –
inspect for extinguisher rust periodically to insure container integrity. Do not mix with
other extinguishing agents.
Page 3 of 7 Pages
SUPER – D

Section 8. Exposure controls/ personal protection
During the application of this product against fires, exhaust gases and the products of
incomplete combustion (PICs) are the principal respiratory hazards. In the
manufacture of extinguishers, automated systems and point source ventilation controls
sufficiently minimize respiratory exposure. Employers and employees must use their
collective judgment in determining occupational settings where the use of a dust mask
or air purifying respirator is prudent. The need for respiratory protection is not likely for
short-term use in well ventilated areas.
Respiratory protection: use N95 dust mask for limited exposure, use air-purifying
respirator (APR) with high efficiency particulate air (HEPA) filters for prolonged
exposure.
Eye protection: wear chemical goggles
Skin protection: use nitrile, latex, or similar gloves and coveralls. Good personal
hygiene practices essential, such as avoiding food, tobacco products, or other hand-tomouth contact when handling. Wash thoroughly after handling.

Section 9. Physical and chemical properties
Appearance: off-white powder, finely divided odorless solid.
Specific gravity: ~ 1.0
Solubility: product is coated, not immediately soluble in water
Non –flammable
Flash point: none
Vapor pressure: < 1 mm Hg
pH: approximately 7 for a 10% solution
Boiling point: not applicable
No explosive or oxidizing properties

Section 10. Stability and reactivity
Stability: stable
Incompatibles: strong acids and strong oxidizers like bleach.
Page 4 of 7 Pages
SUPER – D

Decomposition products: heat of fire may release chlorine compounds and oxides of
sodium.
Possibility of hazardous reactions: none

Section 11. Toxicological information
Acute toxicity:

Sodium chloride LD50 (rat): oral, 3000 mg/kg body weight,
LD50 (mouse): oral, 4000 mg/kg body weight, LDLo (lowest lethal
dose) (rat): subcutaneous, 3500 mg/kg body weight, LDLo (dog):
intraperitoneal, 364 mg/kg body weight.
Target organs in man: None. While an essential nutrient, sodium
chloride is a mild irritant to epithelial tissue, (eyes, mucous
membranes, skin) and may aggravate dermatitis. No information was
found indicating the product causes sensitization.

Chronic toxicity: This product’s ingredients are not considered as “probable” or
“suspected” carcinogens by OSHA, IARC, or ACGIH.
Pneumoconiosis, or “dusty lung” disease, may result from chronic
exposure to any dust.
Reproductive
toxicity:

This product’s ingredients are not known to have reproductive or
teratogenic effects.

Section 12. Ecological information
Ecotoxicity:

negative effects unknown.

Persistence/
Degradability:

degrades slowly in humid/wet environment

Bioaccummulation: extent unknown
Mobility in soil:

insoluble coating, poor mobility

Page 5 of 7 Pages
SUPER – D

Section 13. Disposal considerations
This product is not a RCRA characteristically hazardous or listed hazardous waste.
Dispose of according to state or local laws, which may be more restrictive than federal
laws or regulations. Used product may be altered or contaminated, creating different
disposal considerations.

Section 14. Transportation information
This product is not defined as a hazardous material under U.S. Department of
Transportation (DOT) 49 CFR 172, or by Transport Canada “Transportation of
Dangerous Goods” regulations.

Section 15. Regulatory information
International Inventory Status:
All ingredients are on the following inventories
Country(ies)
United States of America
Canada
Europe
Australia
Japan
South Korea

Agency
TSCA
DSL
EINECS/ELINCS
AICS
MITI
KECL

Status
Yes
Yes
Yes
Yes
Yes
Yes

European Risk and Safety phrases:
EU Classification:
R Phrases:
S Phrases:

Irritant
20
36/37
22
24/25
26

Harmful by inhalation.
Irritating to eyes, respiratory system.
Do not breathe dust.
Avoid contact with skin and eyes
In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice.

Page 6 of 7 Pages
SUPER – D

U.S. federal regulatory information:
None of the chemicals in this product are under SARA reporting requirements or have
SARA threshold planning quantities (TPQs) or CERCLA reportable quantities (RQs), or
are regulated under TSCA 8(d).
State regulatory information:
Chemicals in this product are covered under specific State regulations, as denoted
below:
Alaska - Designated Toxic and Hazardous Substances: None
California – Permissible Exposure Limits for Chemical Contaminants: None
Florida – Substance List: Mica Dust
Illinois – Toxic Substance List: None
Kansas – Section 302/303 List: None
Massachusetts – Substance List: Mica Dust
Minnesota – List of Hazardous Substances: None
Missouri – Employer Information/Toxic Substance List: None
New Jersey – Right to Know Hazardous Substance List: None
North Dakota – List of Hazardous Chemicals, Reportable Quantities: None
Pennsylvania – Hazardous Substance List: None
Rhode Island – Hazardous Substance List: Mica Dust
Texas – Hazardous Substance List: No
West Virginia – Hazardous Substance List: None
Wisconsin – Toxic and Hazardous Substances: None

California Proposition 65: No component is listed on the California Proposition 65 list.
_____________________________________________________________________
Section 16. Other information
This MSDS conforms to requirements under U.S., U.K., Canadian, Australian, and EU
regulations or standards, and conforms to the proposed 2003 ANSI Z400.1 format.
The information herein is given in good faith but no warranty, expressed or implied, is
made. Updated by Lindsay R. Hill, CIH

Page 7 of 7 Pages
SUPER – D

MATERIAL SAFETY DATA SHEET
Kidde 55 Multi-Purpose Dry Chemical
(Fire Extinguishing Agent)

1.

PRODUCT AND COMPANY IDENTIFICATION
Product Name
Other Trade Names
Manufacturer/Supplier
Address

Phone Number
Chemtrec Number
(for emergencies only)
Revision Date:
MSDS Date:

Kidde 55 Multi –Purpose Dry Chemical (Fire Extinguishing Agent)
ABC, Ammonium Phosphate, Monoammonium Phosphate
Kidde – Residential and Commercial
A United Technologies Company
1016 Corporate Park Drive
Mebane, NC 27302
USA
(919) 304-8200
(919) 563-5911
(800) 424-9300
(703) 527-3887 (International)
August 7, 2007
January 15, 2007

This MSDS has been compiled in accordance with - EC Directive 91/155/EC - OSHA's Hazcom Standard (29 CFR 1910.1200)

2.

3.

COMPOSITION/INFORMATION ON THE COMPONENTS
Component Name
Monoammonium Phosphate

CAS#/Codes Concentration R Phrases
7722-76-1
55 - 65%
None
EC#2317645

EU Classification
None

Ammonium Sulfate

7783-20-2
30 - 40%
EC#2319841

None

None

Mica
Clay

12001-26-2
8031-18-3

None
None

None
None

Amorphous Silica

7631-86-9
<2%
EC#2315454

None

None

Dye

NA

None

None

1 - 4%
<2%

<0.1%

HAZARD IDENTIFICATION
EU Main Hazards
Non Hazardous Powder
Routes of Entry
- Eye contact - Inhalation - Skin contact
Carcinogenic Status
See Section 11 - Toxicity
Target Organs
- Respiratory System - Skin - Eye
Health Effects - Eyes
Contact for short periods of time may cause irritation.
Health Effects - Skin
Contact may cause mild irritation.

Revision Date: August 7, 2007

Page 1 of 6

MATERIAL SAFETY DATA SHEET
Kidde 55 Multi-Purpose Dry Chemical
(Fire Extinguishing Agent)

3.

HAZARD IDENTIFICATION
Health Effects - Ingestion
Ingestion is not an expected route of exposure.
Health Effects - Inhalation
May irritate the respiratory tract. May cause transient cough and shortness of breath.

4.

FIRST AID MEASURES
Eyes
Immediately flood the eye with plenty of water of warm water for at least 15 minutes, holding the eye
open. Obtain medical attention if soreness or redness persists.
Skin
Wash affected area with soap and water. Obtain medical attention if irritation persists.
Ingestion
Dilute by drinking large quantities of water and obtain medical attention.
Inhalation
Move victim to fresh air. Obtain medical attention immediately for any breathing difficulty.
Advice to Physicians
Treat symptomatically.

5.

FIRE FIGHTING MEASURES
Extinguishing Media
This preparation is used as an extinguishing agent and therefore is not a problem when trying to
control a blaze. Use extinguishing agent appropriate to other materials involved. Keep pressurized
extinguishers and surroundings cool with water spray as they may rupture or burst in the heat of a fire.
Unusual Fire and Explosion Hazards
Pressurized containers may explode in heat of fire.
Protective Equipment for Fire-Fighting
Wear full protective clothing and self-contained breathing apparatus as appropriate for specific fire
conditions.

6.

ACCIDENTAL RELEASE MEASURES
Sweep up or vacuum. Prevent skin and eye contact. Wear appropriate protective equipment.

7.

HANDLING AND STORAGE
Pressurized extinguishers should be properly stored and secured to prevent falling or being knocked
over. Do not drag, slide or roll extinguishers. Do not drop extinguishers or permit them to strike
against each other. Never apply flame or localized heat directly to any part of the extinguisher or
plastic container. Store pressurized extinguishers and plastic containers away from high heat sources.
Storage area should be: - cool - dry - well ventilated - under cover - out of direct sunlight

Revision Date: August 7, 2007

Page 2 of 6

MATERIAL SAFETY DATA SHEET
Kidde 55 Multi-Purpose Dry Chemical
(Fire Extinguishing Agent)

8.

EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Standards
Occupational exposure limits are listed below, if they exist.
Mica
ACGIH TLV: 3 mg/m3 TWA, measured as respirable fraction of the aerosol.
OSHA PEL: 20 mppcf, <1% crystalline silica
Nuisance Dust Limit
OSHA PEL: 50 mppcf or 15 mg/m3 TWA, total dust
15 mppcf or 5 mg/m3 TWA, respirable fraction
Engineering Control Measures
Use with adequate ventilation. There should be local procedures for the selection, training, inspection
and maintenance of this equipment. When used in large volumes, use local exhaust ventilation.
Respiratory Protection
Not normally required. Use dust mask where dustiness is prevalent, or TLV is exceeded.
Hand Protection
Not normally needed when used as a portable fire extinguisher. Use gloves if irritation occurs.
Eye Protection
Chemical goggles or safety glasses with side shields.
Body Protection
Normal work wear.

9.

PHYSICAL AND CHEMICAL PROPERTIES
Physical State
Color
Odor
Specific Gravity
Boiling Range/Point (°C/F)
Flash Point (PMCC) (°C/F)
Solubility in Water
Vapor Density (Air = 1)
Vapor Pressure
Evaporation Rate

10.

Powder
Pale Yellow
Odorless
Not available
Not applicable
Not Flammable
Not applicable
Heavier than air.
Not applicable
Not applicable

STABILITY AND REACTIVITY
Stability
Stable under normal conditions.
Conditions to Avoid
- Heat - High temperatures - Exposure to direct sunlight
Materials to Avoid
- Strong oxidizing agents - strong acids - sodium hypochlorite

Revision Date: August 7, 2007

Page 3 of 6

MATERIAL SAFETY DATA SHEET
Kidde 55 Multi-Purpose Dry Chemical
(Fire Extinguishing Agent)

10.

STABILITY AND REACTIVITY
Hazardous Polymerization
Will not occur.
Hazardous Decomposition Products
- oxides of carbon - ammonia – oxides of phosphorus – nitrogen oxides

11.

TOXICOLOGICAL INFORMATION
Acute Toxicity
Low order of acute toxicity.
Chronic Toxicity/Carcinogenicity
This product is not expected to cause long term adverse health effects.
Mica and clay may contain small quantities of quartz (crystalline silica) as an impurity. Prolonged
exposure to respirable crystalline silica dust at concentrations exceeding the occupational exposure
limits may increase the risk of developing a disabling lung disease known as silicosis. IARC found
limited evidence for pulmonary carcinogenicity of crystalline silica in humans.
Genotoxicity
This product is not expected to cause any mutagenic effects.
Reproductive/Developmental Toxicity
This product is not expected to cause adverse reproductive effects.

12.

ECOLOGICAL INFORMATION
Mobility
No relevant studies identified.
Persistence/Degradability
No relevant studies identified.
Bio-accumulation
No relevant studies identified.
Ecotoxicity
No relevant studies identified.

13.

DISPOSAL
Dispose of container in accordance with all applicable local and national regulations. Do not cut,
puncture or weld on or near to the container. No harm to the environment is expected from this
preparation.

14.

TRANSPORT INFORMATION
DOT CFR 172.101 Data
UN Proper Shipping Name
UN Class
UN Number
UN Packaging Group

Revision Date: August 7, 2007

Not regulated
Not regulated
None
None
None
Page 4 of 6

MATERIAL SAFETY DATA SHEET
Kidde 55 Multi-Purpose Dry Chemical
(Fire Extinguishing Agent)

15.

REGULATORY INFORMATION
EU Label Information
Classification and labelling have been performed according to EU directives 67/548/EEC and 99/45/EC
including amendments.
EU Hazard Symbol and Indication of Danger.
This preparation is not classified as dangerous.
R phrases
None
S phrases
None.
US REGULATIONS (Federal, State) and INTERNATIONAL CHEMICAL REGISTRATION LAWS
TSCA Listing
This product contains ingredients that are listed on or exempt from listing on the EPA Toxic Substance
Control Act Chemical Substance Inventory.
EINECS Listing
All ingredients in this product have not been verified for listing on the European Inventory of Existing
Commercial Chemical Substances (EINECS) or the European List of New Chemical Substances
(ELINCS).
DSL/NDSL (Canadian) Listing
All ingredients in this product are listed on the Domestic Substance List (DSL) or the Non-Domestic
Substance List (NDSL) or are exempt from listing.
WHMIS Classification
D2B
This product was classified in accordance with the hazard criteria of the Canadian Controlled Products
Regulations and the MSDS contains all the information required by these regulations.
MA Right To Know Law
All components have been checked for inclusion on the Massachusetts Substance List (MSL). Those
components present at or above the de minimus concentration include: - Mica (12001-26-2) 1-4% Amorphous Silica (7631-86-9) <2% - Ammonium Sulfate (7783-20-2) 30 - 40%
PA Right To Know Law
This product contains the following chemicals found on the Pennsylvania Hazardous Substance List: Mica (12001-26-2) 1-4% - Amorphous Silica (7631-86-9) <2% - Ammonium Sulfate (7783-20-2)
30 - 40%
NJ Right To Know Law
This product contains the following chemicals found on the NJ Right To Know Hazardous Substance
List: - Mica (12001-26-2) 1-4% - Amorphous Silica (7631-86-9) <2%
California Proposition 65
This product does not contain materials which the State of California has found to cause cancer, birth
defects or other reproductive harm.
SARA Title III Sect. 302 (EHS)
This product does not contain any chemicals subject to SARA Title III Section 302.
SARA Title III Sect. 304
This product does not contain any chemicals subject to SARA Title III Section 304.

Revision Date: August 7, 2007

Page 5 of 6

MATERIAL SAFETY DATA SHEET
Kidde 55 Multi-Purpose Dry Chemical
(Fire Extinguishing Agent)

15.

REGULATORY INFORMATION
SARA Title III Sect. 311/312 Categorization
- Immediate (Acute) Health Hazard
SARA Title III Sect. 313
This product does not contain any chemicals that are listed in Section 313 at or above de minimis
concentrations.

16.

OTHER INFORMATION
NFPA Ratings
NFPA Code for Health - 1
NFPA Code for Flammability - 0
NFPA Code for Reactivity - 0
NFPA Code for Special Hazards - None
HMIS Ratings
HMIS Code for Health - 1
HMIS Code for Flammability - 0
HMIS Code for Reactivity - 0
HMIS Code for Personal Protection - See Section 8
Abbreviations
N/A: Denotes no applicable information found or available
CAS#: Chemical Abstracts Service Number
ACGIH: American Conference of Governmental Industrial Hygienists
OSHA: Occupational Safety and Health Administration
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
STEL: Short Term Exposure Limit
NTP: National Toxicology Program
IARC: International Agency for Research on Cancer
R: Risk
S: Safety
EnviroNet LLC.
Prepared By:
The information contained herein is based on data believed to be accurate. However, no
representation, warranty, or guarantee is made to its accuracy, reliability or completeness. It is the
user's responsibility to satisfy himself as to the suitability and completeness of such information for its
own particular use. Badger Fire Protection assumes no responsibility for personal injury or property
damage resulting from use, handling or from contact with this product.

Revision Date: August 7, 2007

Page 6 of 6

MATERIAL SAFETY DATA SHEET #KFFM010

ABC Multipurpose Dry Chemical
Fire Extinguisher

Section 1 – NAME & HAZARD SUMMARY
Material Name: DRY CHEMICAL Multipurpose Ammonium Phosphate
Supplier Name and Address: Kidde Fire Fighting
150 Gordon Drive · P.O. Box 695
Exton, PA 19341-0695 USA
Phone: (610) 363-1400 · Fax: (610) 524-9073
www.Kidde-Fire.com
Section 2 – INGREDIENTS
Material name: Siliceous Muscovite Mica, Mica
OSHA PEL: 20 MPPCF*
ACGIH TLV: 20 MPPCF*
Other Exposure Limits: None
CAS No.: 12001-26-2
*Million particles per cubic foot
Section 3 – PHYSICAL DATA
Boiling Point: NA
Specific Gravity (H2O = 1): 1.80
Vapor Pressure (mm Hq): NA
Vapor Density (Air -1): NA
Solubility In Water: Slightly water soluble
Appearance and Odor: Yellow powder, odorless
Melting Point: 374° Fahrenheit
Section 4 – FIRE & EXPLOSION HAZARD
Flash Point: Noncombustible
Method Used: NA
Flammable Limits in Air, % by Volume: LEL Lower: NA; UEL Upper: NA
Auto-Ignition Temperature: NA
Extinguisher Media: NA, This material is a fire extinguisher agent
KFFM010

Page 1 of 2

6/1/04

Special Fire Fighting Procedures: NA
Unusual Fire and Explosion Hazards: NA
Section 5 – REACTIVITY DATA
Stability: Stable
Conditions to Avoid: NA
Incompatibility (Materials to Avoid): Do not mix with different types of dry chemical
extinguishing agents
Hazardous Polymerization: Will Not Occur
Conditions to Avoid: NA
Section 6 – HEALTH HAZARD ASSESSMENT
Acute: Transient cough, Irritation of airways, and shortness of breath
Chronic: Pneumonconiosis
Signs and Symptoms of Exposure: Coughing and irritation of airways
Medical Conditions Generally Aggravated by Exposure: Asthma, Bronchitis, or other
respiratory illness
Chemical Listed as Carcinogen or Potential Carcinogen: N/A
Emergency and First Aid Procedures: Move victims to fresh air. Wash affected area with soap
and water. Flush from eyes with large amounts of water for at least 15 minutes. Seek medical
attention if necessary.
Routes of Entry: Inhalation, Eyes, Skin, Ingestion
Section 7 – SPILL OR LEAK PROCEDURES
Precautions to be Taken in Handling and Storage: Multipurpose (ABC) Dry Chemical should
be stored in original container or in sealed extinguishers.
Other Precautions: None
Steps to be Taken in Case Material is Released or Spilled: Sweep up. Store in covered
containers. Do not reuse.
Section 8 – SPECIAL PROTECTION INFORMATION
Respiratory Protection: Dust respirator approved by NIOSH/MSHA schedule TC-ZIC
Ventilation: NA
Local Exhaust: NA
Mechanical General: NA
Special: NA Other: NA
Protective Gloves: Sensitive individuals should wear gloves
Eye Protection: Safety glasses are recommended
Other Protective Clothing or Equipment: NA
Work/Hygienic Practices: Avoid breathing of dust. Wash off with soap and water.
The information herein is given in good faith but no warranty, expressed or implied, is made.

KFFM010

Page 2 of 2

6/1/04

MATERIAL SAFETY DATA SHEET
S O S PRODUCTS COMPANY INC
P. O. Box 47
East Greenville, Pa.
18041
Phone (215-679)-6262
(215)-679-6263

SECTION I
PAGE 1
Product Code:
Identification:

-

GENERAL

WG8 / WGP
WAX GASKET

INFORMATION
Revision Date:

08/06/07

SECTION II - HAZARDOUS INGREDIENTS
This product is not classified as hazardous in accordance with OSHA 1910.1200
Carcinogenicity:
This product is NOT considered to be a carcinogen by the
National Toxicology Program, the International Agency for Research on
Cancer, or the Occupational Safety and Health Administration.
SECTION III - PHYSICAL CHARACTERISTICS
Boiling Point: < 650o F
Specific Gravity: .85
Vapor Pressure: 0.01
Melting Point:
140o-170o F.
Vapor Density: N/A
Evaporation Rate: N/A
Solubility in Water:
NEGLIGIBLE
Odor and Appearance: AMBER WAXY SOLID WITH TYPICAL PETROLEUM WAX ODOR
SECTION IV - FIRE AND EXPLOSION HAZARD
Flash Point: 500o F. COC
LEL: N/A
Flammable Limits: NOT DETERMINED
UEL: N/A
Extinguishing Media:
DRY CHEMICAL, FOAM, FIRE EXTINGUISHER
Special Fire Fighting Procedures:
USE WATER SPRAY, DRY CHEMICAL FOAM, OR CARBON DIOXIDE. WATER OR FOAM
MAY CAUSE FROTHING. WATER MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS
COOL. USE PROTECTIVE CLOTHING WHEN ENTERING CONFINED AREAS WITH WAX
FIRES.
Unusual Fire and Explosion Hazards:
WHEN HEATED ABOVE FLASH POINT, FLAMMABLE VAPORS COULD BE RELEASED
WHICH COULD BURN IN CONFINED AREAS.
SECTION V
This product is STABLE.
Conditions to avoid:
Incompatibility:

-

REACTIVITY DATA

HIGH HEAT, TEMPERATURES OVER 160 DEG F.

STRONG OXIDIZING AGENTS

Hazardous Decomposition:

BY OPEN FLAME:

CARBON DIOXIDE & CARBON MONOXIDE

Hazardous Polymerization WILL NOT OCCUR.

Routes of Entry:

SECTION VI - HEALTH HAZARD DATA
Inhalation? NO
Skin?
YES - SECONDARY
Ingestion?
YES - SECONDARY

Health Hazards (Acute and Chronic):

NONE KNOWN

Carcinogenicity:

NTP?
IARC Monographs?
OSHA Regulated?

Signs and Symptoms of Exposure:

NO
NO
NO

NONE

Medical Conditions Generally Aggravated by Exposure:

NONE KNOWN

Emergency and First Aid Procedures:
SKIN: WASH WITH SOAP & WATER THOROUGHLY.
EYES: FLUSH 15 MINUTES WITH WATER.
INGESTION: MAY CAUSE IRRITATION OF DIGESTIVE TRACT.
QUANTITY, CALL PHYSICIAN.

IF LARGE

SECTION VII - HANDLING PRECAUTIONS
Steps to be Taken if Material is Released or Spilled:
REPLACE INTO CONTAINER AND PACKAGE APPROPRIATELY FOR DISPOSAL. FOR
MOLTEN MATERIAL, ABSORB WITH SAND OR INERT ABSORBENT AND NOTIFY STATE
AND LOCAL AGENCIES.
Waste Disposal Method:

WAX- COMPLY WITH FEDERAL, STATE AND LOCAL REGULATIONS.

Precautions to be Taken in Handling and Storage:
STORE IN A COOL, DRY LOCATION. TO PREVENT MELTING OR DEFORMING DO NOT
STORE OVER 110o F.
Other Precautions:

NONE

SECTION VIII - CONTROL MEASURES
Respiratory Protection: NONE REQUIRED FOR NORMAL USE.
Ventilation Required: ADEQUATE VENTILATION
Protective Gloves: NONE REQUIRED FOR NORMAL USE.
Eye Protection: WEAR SAFETY GLASSES
Other Protective Equipment: NONE
Work/Hygienic Practices: USE GOOD PERSONAL HYGIENE PRACTICES.

The above information pertains to the product as it is currently formulated and
is based upon the information available at this time. Additions of reducers or
other additives to this product may substantially alter the composition and
subsequent hazards of the product. Since conditions of use are outside of our
control, we make no warranties, either expressed or implied, and assume no
liability in connection with any use of this information.

MATERIAL SAFETY DATA SHEET
S O S PRODUCTS COMPANY INC
P. O. Box 47
East Greenville, Pa.
18041
Phone (215-679)-6262
(215)-679-6263

SECTION I
PAGE 1
Product Code:
Identification:

-

GENERAL

WG8 / WGP
WAX GASKET

INFORMATION
Revision Date:

08/06/07

SECTION II - HAZARDOUS INGREDIENTS
This product is not classified as hazardous in accordance with OSHA 1910.1200
Carcinogenicity:
This product is NOT considered to be a carcinogen by the
National Toxicology Program, the International Agency for Research on
Cancer, or the Occupational Safety and Health Administration.
SECTION III - PHYSICAL CHARACTERISTICS
Boiling Point: < 650o F
Specific Gravity: .85
Vapor Pressure: 0.01
Melting Point:
140o-170o F.
Vapor Density: N/A
Evaporation Rate: N/A
Solubility in Water:
NEGLIGIBLE
Odor and Appearance: AMBER WAXY SOLID WITH TYPICAL PETROLEUM WAX ODOR
SECTION IV - FIRE AND EXPLOSION HAZARD
Flash Point: 500o F. COC
LEL: N/A
Flammable Limits: NOT DETERMINED
UEL: N/A
Extinguishing Media:
DRY CHEMICAL, FOAM, FIRE EXTINGUISHER
Special Fire Fighting Procedures:
USE WATER SPRAY, DRY CHEMICAL FOAM, OR CARBON DIOXIDE. WATER OR FOAM
MAY CAUSE FROTHING. WATER MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS
COOL. USE PROTECTIVE CLOTHING WHEN ENTERING CONFINED AREAS WITH WAX
FIRES.
Unusual Fire and Explosion Hazards:
WHEN HEATED ABOVE FLASH POINT, FLAMMABLE VAPORS COULD BE RELEASED
WHICH COULD BURN IN CONFINED AREAS.
SECTION V
This product is STABLE.
Conditions to avoid:
Incompatibility:

-

REACTIVITY DATA

HIGH HEAT, TEMPERATURES OVER 160 DEG F.

STRONG OXIDIZING AGENTS

Hazardous Decomposition:

BY OPEN FLAME:

CARBON DIOXIDE & CARBON MONOXIDE

Hazardous Polymerization WILL NOT OCCUR.

Routes of Entry:

SECTION VI - HEALTH HAZARD DATA
Inhalation? NO
Skin?
YES - SECONDARY
Ingestion?
YES - SECONDARY

Health Hazards (Acute and Chronic):

NONE KNOWN

Carcinogenicity:

NTP?
IARC Monographs?
OSHA Regulated?

Signs and Symptoms of Exposure:

NO
NO
NO

NONE

Medical Conditions Generally Aggravated by Exposure:

NONE KNOWN

Emergency and First Aid Procedures:
SKIN: WASH WITH SOAP & WATER THOROUGHLY.
EYES: FLUSH 15 MINUTES WITH WATER.
INGESTION: MAY CAUSE IRRITATION OF DIGESTIVE TRACT.
QUANTITY, CALL PHYSICIAN.

IF LARGE

SECTION VII - HANDLING PRECAUTIONS
Steps to be Taken if Material is Released or Spilled:
REPLACE INTO CONTAINER AND PACKAGE APPROPRIATELY FOR DISPOSAL. FOR
MOLTEN MATERIAL, ABSORB WITH SAND OR INERT ABSORBENT AND NOTIFY STATE
AND LOCAL AGENCIES.
Waste Disposal Method:

WAX- COMPLY WITH FEDERAL, STATE AND LOCAL REGULATIONS.

Precautions to be Taken in Handling and Storage:
STORE IN A COOL, DRY LOCATION. TO PREVENT MELTING OR DEFORMING DO NOT
STORE OVER 110o F.
Other Precautions:

NONE

SECTION VIII - CONTROL MEASURES
Respiratory Protection: NONE REQUIRED FOR NORMAL USE.
Ventilation Required: ADEQUATE VENTILATION
Protective Gloves: NONE REQUIRED FOR NORMAL USE.
Eye Protection: WEAR SAFETY GLASSES
Other Protective Equipment: NONE
Work/Hygienic Practices: USE GOOD PERSONAL HYGIENE PRACTICES.

The above information pertains to the product as it is currently formulated and
is based upon the information available at this time. Additions of reducers or
other additives to this product may substantially alter the composition and
subsequent hazards of the product. Since conditions of use are outside of our
control, we make no warranties, either expressed or implied, and assume no
liability in connection with any use of this information.

Friday, April 21, 2006

Page 1 of 7

MSDS - Material Safety Data Sheet
Product Name: C-12 CPVC Cement
MSDS No.: 018750

Part Numbers Covered:
018750-24
018752-24
018760-24
018762-24
018770-12
018772-12
018780-12
018782-12
018790

1. Basic Information:
Manufacturer: WILLIAM H. HARVEY COMPANY

4

Address: 4334 SOUTH 67TH STREET
City, ST Zip: OMAHA, NE 68117-1019

2

1

Emergency Contact: CHEMTREC
Emergency Telephone Number: (800)424-9300
Contact: Information Telephone Number
Information Telephone Number: (800)228-9681
Last Update: 04/21/2006
Chemical State:
Chemical Type:

X

2
4

Expiration Date:

Liquid

Gas

Pure

X

1

Solid

G

Mixture

2. Ingredients:
Trade Secret
EHS

IARC
NTP

SARA
313
OSHA
SUB Z
PEL

ACGIH
TLV

Other
Limits

CAS No.

Chemical Name

% Range

68648-82-8

CPVC RESIN

10 - 20

NI

10 MG/M3 NI

108-94-1

CYCLOHEXANONE

5 - 15

25 PPM

25 PPM

NI

112945-52-5 FUMED SILICA

1-5

5 mg/m3

3 mg/m3

NI

78-93-3

METHYL ETHYL KETONE

20 - 30

200 PPM

200 PPM

NI

109-99-9

TETRAHYDROFURAN

40 - 48

200 PPM

50 PPM

NI

3. Hazardous Identification:
Hazard Category:

X Acute

X Chronic

X Fire

Pressure

Reactive

Hazardous Identification Information:

HAZARDS OVERVIEW:
Clear orange colored, moderately viscous liquid with a distinct and penetrating odor. Extremely flammable liquid and vapor.
Vapors may cause flash fire. May cause eye and skin irritation. Inhalation of vaors or mists may cause respiratory irritation and
central nervous system effects. Ingestion may cause irritation, nausea, vomiting, diarrhea and kidney and liver disorders. May
be fatal if swallowed. Aspiration hazard. Symptoms may be delayed.

Friday, April 21, 2006

Page 2 of 7

MSDS - Material Safety Data Sheet
Product Name: C-12 CPVC Cement
MSDS No.: 018750

4. First Aid Measures:
Route(s) of Entry:

EYES: Liquid causes severe irritation. Vapors cause slight to moderate irritation.
SKIN: Liquid or vapors may cause severe irritation.
INHALATION: May cause nose and throat irritation, headache, nausea, vomiting, drowsiness and incoordination.
INGESTION: Swallowing may cause irritation, nausea, vomiting, diarrhea and kidney and liver disorders. May be fatal if
swallowed.
TARGET ORGANS: Eyes, Skin, Lungs, Kidney, Liver, Central Nervous System.
Health Hazards (Acute and Chronic):

ACUTE:
Severe skin irritant. Fast skin penetrant. Not expected to be a sensitizer. Eye irritant. Inhalation hazard. Overexposure may
cause coughing, shortness of breath, dizziness, vomiting, central nervous system depression, intoxication, and collapse.
Ingestion hazard. May produce symptoms of nervous system depression including headache, dizziness, nausea, loss of sense
of balance, drowsiness, and visual disturbances.
CHRONIC:
Prolonged or repeated eye contact may cause conjunctivitis. Prolonged or repeated skin contact may cause defatting and
dermatitis. May cause liver and kidney damage. May cause reproductive and fetal effects May cause lung damage. Narcotic in
high concentrations.
Signs and Symptoms:

See HEALTH HAZARDS above.
Medical Conditions Generally Aggravated by Exposure:

AGGRAVATION OF EXISTING CONDITIONS:
Persons with pre-existing skin disorders or eye problems or impaired liver or kidney function may be more susceptible to the
effects of the substance.
Emergency and First Aid Procedures:

FOR EMERGENCY FIRST AID HELP CALL 1-303-623-5716 COLLECT.
SKIN CONTACT:
Immediately wash skin with soap and water while removing contaminated clothing and shoes. Remove dried cement with
HARVEY'S POWER SCRUB HAND CLEANER or baby oil. Launder clothing before reuse. Seek medical attention if irritation
persists.
EYES:
Liquid: Immediately flush with plenty of water for 5 minutes. Remove contacts if present and continue flushing with water while
holding eyelids open with thumb and index finger for 15 minutes. Seek medical attention if irritation develops or persists.
Vapors: If vapors cause irritation, move to fresh air and flush eyes as above. Seek medical attention if irritation develops or
persists.
INHALATION:
Move to fresh air. Give oxygen if breathing is difficult. Give artificial respiration if required. Call a physician or poison control
center (1-303-623-576 collect) immediately.
INGESTION:
DO NOT INDUCE VOMITING. Rinse mouth with water. Never give anything by mouth to a person who is unconscious or
drowsy. Get immediate medical attention by calling a Poison Control Center (1-303-623-5716 Collect), or hospital emergency
room. If medical advice cannot be obtained, then take the person and product to the nearest medical emergency treatment
center or hospital.
Other Health Warnings:

NI

Friday, April 21, 2006

Page 3 of 7

MSDS - Material Safety Data Sheet
Product Name: C-12 CPVC Cement
MSDS No.: 018750

5. Fire Fighting Measures:
Flash Point: 0 - 6 ºF

Lower Explosive Limit: 1.1 %by vol.

Upper Explosive Limit: 11.8 %by vol

F.P. Method: TCC
Fire Extinguishing Media: Use dry chemical, CO2, or foam to extinguish fire. Cool fire exposed container with water. Water may be ineffective
as an extinguishing agent.

Special Fire Fighting Procedures:

Firefighters should wear positive pressure self contained breathing apparatus and full protective clothing for fires in areas where
chemicals are used or stored.
Unusual Fire and Explosion:

Extremely flammable liquid. Keep away from heat and all sources of ignition including sparks, flames, lighted cigarettes and pilot
lights. containers may rupture or explode in the heat of a fire. Vapors are heavier than air and may travel to a remote ingition
source and flash back. This product contains Tetrahydrofuran that may form explosive organic peroxides when exposed to air or
light or with age. Combustion will produce toxic and irritating vapors including carbon monoxide and carbon dioxide.

6. Accidental Release Measures:
Steps to be Taken in Case Material is Released or Spilled:

Remove all sources of ignition and ventilate area. Stop leak if it can be done without risk. Prevent liquid from entering
watercourses, natural waterways, drainage collection areas or sewers.
Personnel cleaning up the spill should wear appropriate Ppersonal Protective Equipment, including respirators if vapor
concentrations are high. Soak up spill with an inert absorbent such as sand, earth or other non-combusting material. Put spent
absorbent material in covered, labeled metal containers. See Section XIII for disposal information.
Report releases to proper authorities as required.

7. Handling and Storage:
Precautions to be Taken:

HANDLING:
Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists. Use with adequate ventilation (equivalent to
outdoors). Wash thoroughly after handling. do not eat, drink or smoke in the work area. Keep product away from heat, sparks,
flames and all other sources of ignition. No smoking in use or storage areas. Keep containers closed when not in use.
STORAGE:
Store in a cool, dry, well ventilated area away from incompatable materials. Keep containers closed when not in use.
Other Precautions:

"Empty" containers can retain product residue and can be hazardous. Follow all MSDS precations in handling empty containers.
Do not cut or weld on or near empty or full containers.
Prevent prolonged or repeated breathing of vapors released during application process. Reports have associated repeated and
prolonged overexposure to solvents with permanent brain damage and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents may be harmful or fatal.

8. Exposure Controls/Personal Protection:
Ventilation Requirements:

GENERAL MECHANICAL: Exhaust ventilation capable of maintaining emissions at the point of use below OSHA PEL.
LOCAL EXHAUST: Open doors & windows. If used in an enclosed area, use exhaust fans.
Exhaust fans should be explosion-proof or set up in a way that flammable concentrations of vapors are not exposed to electrical
fixtures or hot surfaces.
Personal Protective Equipment:

Friday, April 21, 2006

Page 4 of 7

MSDS - Material Safety Data Sheet
Product Name: C-12 CPVC Cement
MSDS No.: 018750
RESPIRATORY PROTECTION:
For operations where the exposure limits may be exceeded, a NIOSH approved organic vapor respirator or supplied air respirator
is recommended. Equipment selection depends on the contaminant type and concentration. Select in accordance with 29 CFR
1910.134 and good industrial hygiene practice.
For firefighting, use self-contained breathing apparatus.
EYE PROTECTION:
Safety glasses with side shields or safety goggles.
SKIN PROTECTION:
Rubber gloves are adequate for normal use of the product. For long exposures to the substance, chemical resistant gloves may
be required to avoid prolonged exposure.
OTHER PROTECTION:
An eye wash and safety shower should be available in the work area.

9. Physical and Chemical Properties:
Boiling Point: 155 ºF

Melting Point: NA

Evaporation Rate (Butyl Acetate = 1): 3.7 - 8.0

Vapor Pressure (mm Hg.): ~ 157

Specific Gravity (H20 = 1): 0.95000

Vapor Density (AIR = 1): ~ 2.5

Solubility In Water: Negligible

Appearance and Odor: Clear orange colored, moderately viscous liquid with
Ether-like odor

Other Information: Specific Gravity = ~.95

10. Stability and Reactivity:
Stability:

Stable.
Incompatibility (Materials to Avoid):

Oxidizing agents, alkalis, amines, ammonia, acids, chlorine compounds, chlorinated inorganics (potassium, calcium and sodium
hypochlorite) and hydrogen peroxides. May attack plastic and rubber compounds.
Decomposition/By Products:

Burning can produce carbon monoxide, carbon dioxide, water, cyanide, hydrogen cyanide, and vapors of chemicals listed in
Section II.
Hazardous Polymerization:

Will not occur.

11. Toxicological Information:

Friday, April 21, 2006

Page 5 of 7

MSDS - Material Safety Data Sheet
Product Name: C-12 CPVC Cement
MSDS No.: 018750
THIS PRODUCT IS TOXIC BY INGESTION. MAY CAUSE NARCOSIS, GASTRIC INJURY OR DEATH.
CHRONIC TOXICITY: Prolonged or reapeated overexposure can cause dermatitis and damage to the kidney, liver, lungs and
central nervous system.
TOXICITY DATA:
Cyclohexanone:
Oral rat LD50: 1,620 mg/kg.
Inhalation rat LC50: 8,000 ppm/4 hours
Skin rabbit: 1 mL/kg
Methyl Ethyl Ketone:
Oral rat LD50: 2,737 mg/kg.
Inhalation rat LC50: 23,500 mg/m3/8 hours
Skin rabbit: 6480 mg/kg
Tetrahydrofuran:
Oral rat LD50: 1,650 mg/kg
Inhalation rat LC50: 21,000 ppm/ 3 hours
CPVC Resin:
No toxicity studies have been conducted on this product.
As with all chemicals for which test data are limited or do not exist, caution must be exercised through the prudent use of
protective equipment and handling procedures to minimize exposure.
SENSITIZATION:
None of the components are known to cause sensitization.
CARCINOGENICITY:
None of the components are listed as a carcinogen or suspect cacinogen by NTP, IARC or OSHA. The NTP has reported that
exposure of mice and rats to Tetrahydrofuran vapor levels up to 1800 ppm 6 hr/day, 5 days/week for their lifetime caused an
increased incidence of kidney tumors in male rats and liver tumors in female mice. The significance of these findings for human
health is unclear at this time, and may be related to "species specific" effects. Elevated incidences of tumors in humans have not
been reported for Tetrahydrofuran. ACGIH has classified Cyclohexanone and Tetrahydrofuran as "A3", Confirmed Animal
Carcinogen with Unknown Relevance to Humans.
MUTAGENICITY:
Cyclohexanone has been positive in bacterial and mammalian assays. Methyl Ethyl Ketone and Tetrahydrofuran are generally
thought not to be mutagenic.
REPRODUCTIVE TOXICITY:
Methyl Ethyl Ketone and Cyclohexanone have been shown to cause embryofetal toxicity and birth defects in laboratory animals.
Tetrahydrofuran have been found to cause adverse developmental effects only when exposure levels cause othe toxic effects to
the mother.

12. Ecological Information:
THIS PRODUCT IS NOT EXPECTED TO BE TOXIC TO AQUATIC ORGANISMS.
Cyclohexanone: 96 hour LC50 values for fish is over 100mg/L.
Methyl Ethyl Ketone: 96 hour LC50 values for fish is over 100mg/L.
Tetrahydrofuran: 96 hour LC50 for fathead minnow: 2160 mg/L.
VOC Information:
This product emits VOC's (Volatile Organic Compounds) in its use. Make sure that use of this product complies with local VOC
emission regulations, where they exist.
VOC Content (as manufactured): 776 grams/liter

13. Disposal Considerations:

Friday, April 21, 2006

Page 6 of 7

MSDS - Material Safety Data Sheet
Product Name: C-12 CPVC Cement
MSDS No.: 018750
DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS.
RCRA Hazardous Waste Number: U057, U159, U213
EPA Hazardous Waste ID Number: D001, D035, F003, F005
EPA Hazardous Waste Class: Ignitable Waste. Toxic Waste (Methyl Ethyl Ketone content)

14. Transport Information:
DOT (DEPARTMENT OF TRANSPORTATION) U.S.:
Proper Shipping Name: Less than 1 Liter = Consumer Commodity
1 Liter or Greater = Adhesives, Containing Flammable Liquid
Hazard Class/Packing Group: Less than 1 Liter = ORM-D
1 Liter or Greater = 3, PGII
UN/NA Number: Less than 1 Liter = None
1 Liter or Greater = UN1133
Hazard Labels: Less than 1 Liter = None
1 Liter or Greater = Flammable Liquid
INTERNATIONAL MARITIME DANGEROUS GOODS:
Proper Shipping Name: Flammable Liquid, N.O.S.

Limited Quantity

Hazard Class/Packing Group: 3, II
UN Number: UN1993
Label: None (Limited Quantities are excepted from labeling)
2004 NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER: 128

15. Regulatory Information:

Friday, April 21, 2006

Page 7 of 7

MSDS - Material Safety Data Sheet
Product Name: C-12 CPVC Cement
MSDS No.: 018750
SARA, Section 311 / 312, Hazard Category:
Acute Health
Chronic Health
Flammable
SARA, Section 302, Extremely Hazardous Substances:
This product does not contain chemical regulated under SARA Section 302.
SARA, Section 313, Toxic Chemical:
This product does not contains any chemical subject to SARA Title III, Section 313 reporting requirements:
CERCLA 103, Reportable Quantity:
Spills of this product over the RQ (reportable quantity) must be reported to the National Response Center; The RQ for the
product, based on the RQ for Methyl Ethyl Ketone (100% maximum) of 5,000 lbs. is 5,000 lbs. Many states have more stringent
release reporting requirements. Report spills required under federal, state and local regulations.
CALIFORNIA PROPOSITON 65:
This product contains trace amounts of chemicals known to the State of California to cause cancer. Under normal use
conditions, exposure to these chemicals at levels above the State of California "No Significant Risk Level" (NSRL) are unlikely.
The Willliam H. Harvey Company strongly recommends and encourages the proper selection and use of Personal Protective
Equipment and engineered ventilation noted in Section VIII of this MSDS.
TSCA INVENTORY:
All of the components of this product are listed on the TSCA inventory.
CANADIAN WHIMS CLASSIFICATION:
Class B, Division 2; Class D, Division 2, Subdivision A.
This product has been classified in accordance with the hazard criteria of the Conrtrolled Products Regulations (CPR) and the
MSDS contains all the information required by the CPR.

16. Other Information:
KEEP AWAY FROM HEAT SPARK AND FLAMES AT ALL TIMES.
STORE IN A COOL DRY PLACE.
ABBREVIATIONS:
~ = Approximately
< = Less Than
> = Greater Than
ACGIH = American Conference of Governmental Industrial Hygienists
AIHA
= American Industrial Hygiene Association
C = Degrees Celcius
CERCLA =
The Comprehensive Environmental Response, Compensation, and Liability Act
Deg = Degrees
EPA
= Environmental Protection Agency
F = Degrees Farenheit
HMIS
= Hazardous Materials Information System
IARC
= International Agency for Research on Cancer
NA = Not Applicable
NDA
= No Data Available
NE = Not Established
NFPA = National Fire Protection Association
NI = Not Indicated
NIOSH = National Institure of Occupational Safety and Health
NTP= National Toxicology Program
OSHA = Occupational Safety and Health Administration
SARA
=
Superfund Amendment and Reauthorization Act
DISCLAIMER: The information herein has been compiled from sources believed to be reliable, up-to-date, and is accurate to the
best of our knowledge. However, the William H. Harvey Company cannot give any guarantees regarding information from other
sources, and expressly does not make warranties, nor assumes any liability for its uses.

PIPE JOINT COMPOUND

80-067
HMIS RATING
Health	

2

Flammability	

3

Reactivity	

0

NFPA 704 RATING

MATERIAL
SAFETY DATA
SHEET

Kimball-Midwest
P.O. Box 2470
Columbus, OH 43216-2470
Corporate telephone: 614-219-6100
Emergency Telephone: 800-424-9300

Health	

2	

Flammability	

3

Reactivity	

0

NFPA 30B LEVEL
N/A

1. PRODUCT IDENTIFICATION
PART NUMBER............................. 80-067
PRODUCT NAME.......................... LOCTITE PIPE JOINT COMPOUND, 30556
CHEMICAL FAMILY....................... N/A
DOT SHIPPING.............................. Consumer Commodity ORM-D

2. HAZARDOUS INGREDIENTS
Specific Chemical Identity, Common Names	

OSHA PEL	 ACGIH TLV	

STEL	

Clay (1332-58-7)	
15mg/m3	 2mg/m3	None	
Vegetable Oil (68187-84-8)	None	None	None	
Rosin (8050-09-7)	None	None	None	
Isopropyl alcohol (67-63-0)	
200ppm	 200ppm	 400ppm	
Talc (14807-96-6)	
20mppcf	 2mg/m3	
3ppm	
Carbon, black (133-86-4)	
3.5mg/m3	 3.5mg/m3	None	
Silica, quartz (14808-60-7)	
0.1mg/m3	 .05mg/m3	None	

%

30-60
10-30
10-30
10-30
1-5
0.1-1
0.1-1

All chemical compounds marked with an asterisk (*) are toxic chemicals subject to the reporting of Section 313 of
Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372. You must
notify each person to whom this mixture of trade name product is sold. This statement must not be detached. Any
copy or redistribution of this Material Safety Data Sheet shall include this statement. **Ceiling

3. PHYSICAL DATA
BOILING POINT (RANGE)...................................>149°C to (300°F)
VAPOR PRESSURE PSIG @ 68°F...................... 33mmHg
VAPOR DENSITY (AIR = 1).................................. Heavier than air
SOLUBILITY IN WATER....................................... Partial
SPECIFIC GRAVITY (H2O = 1)............................ 1.37
MELTING/FREEZING POINT............................... N/A
EVAPORATION RATE (61%=1)........................... Not available
VOC content (by weight)....................................... 15.2%
APPEARANCE AND ODOR................................. Dark Brown Viscous liquid/
Alcoholic Odor

4. FIRE AND EXPLOSION DATA
FLASH POINT....................................................... 76°F TCC
UPPER EXPLOSIVE LIMIT (%)............................ 12.7
LOWER EXPLOSIVE LIMIT (%)........................... 2.3
EXTINGUISHING MEDIA...................................... Foam, dry chemical, CO2
SPECIAL FIREFIGHTING PROCEDURES........... As in any fire, wear self-contained
breathing apparatus pressure-demand (MSHA/
NIOSH approved or equivalent) and full protective
gear.
HAZARDOUS COMBUSTION PRODUCTS......... Alehydes. Oxides of carbon.
Carboxylic acids. Irritating organic carbon.

5. HEALTH EFFECTS DATA
SHORT TERM EFFECTS OF EXPOSURE
ROUTE OF ENTRY...............Skin absorption, Inhalation, Eye contact, Ingestion
HEALTH HAZARDS
(ACUTE AND CHRONIC)......May cause allergic skin reaction, may cause eye,
skin and respiratory tract irritation. May be harmful
if swallowed.
EYE CONTACT.....................May cause irritation. Redness. Swelling. Stinging.
INGESTION...........................Not expected to be harmful by ingestion.
INHALATION.........................May cause to nose and throat.
SKIN CONTACT....................May cause skin irritation. May cause allergic skin
reaction. Burning Sensation. Redness
MEDICAL CONDITIONS GENERALLY
AGGRAVATED BY EXPOSURE	 Eye, skin and respiratory disorders

5. HEALTH EFFECTS DATA CON’T.
FIRST AID PROCEDURES
EYE CONTACT.....................Flush with copious amounts of water, preferably,
lukewarm water for at least 15 minutes, holding eyelids
open at all times. Obtain medical attention.
SKIN CONTACT....................Wash with soap and water. Remove contaminated
clothing and shoes. Wash clothing before reuse.
Get medical attention if symptoms occur.
Ingestion...........................Do not induce vomiting. Keep individual calm. Obtain
medical attention.
INHALATION.........................Remove to fresh air. If symptoms develop and
persist, get medical attention.
SPECIAL HEALTH EFFECTS
CARCINOGEN (OSHA Guidelines) Silica, quartz, is a known carcinogen.
CALIFORNIA PROP 65	This product contains a chemical known to the
State of California to cause cancer.

6. REACTIVITY
STABILITY............................................................ Stable under normal
conditions.
INCOMPATIBILITIES............................................ Oxidizing and spontaneously
flammable products.
HAZARDOUS DECOMPOSITION
PRODUCTS.......................................................... Oxides of carbon. Aldehydes.
Carboxylic acid.
HAZARDOUS POLYMERIZATION....................... Will not occur under normal
conditions.
HAZARDOUS POLYMERIZATION CONDITIONS.....None known.

7. PRECAUTIONS FOR SAFE HANDLING & USE
PROTECTIVE EQUIPMENT
REQUIREMENTS..................Tightly sealed goggles with side shields, impermeable
gloves and protective clothing as necessary to
prevent skin contact. Local exhaust ventilation may
be necessary to control air contaminants to within
TLVs during the use of this product.
WASH REQUIREMENTS......Wash with soap and water.
SPILL OR LEAK PROCEDURES	Remove all sources of ignition. Ensure adequate
ventilation. Scrape up spilled material and place in
sealed container for disposal.
WASTE DISPOSAL METHODS	 Dispose of in accordance with local, state,
and federal regulations.
HANDLING & STORAGE......Avoid contact with eyes, skin and clothing. Avoid
breathing vapor and mist. Wash thoroughly after
handling. Use only adequate ventilation. Store below
100oF.
OTHER PRECAUTIONS.......Use NIOSH approved respirator with an organic
vapor cartridge; avoid prolonged breathing of
vapors; protection provided by air purifying
respirators is limited.

8. ADDITIONAL INFORMATION
Use self-contained breathing apparatus if TLV limits are exceeded. Do not eat
or smoke while using. Wash hands after use. Use positive pressure air supplied
respirator if there is potential for uncontrolled release, if exposure levels are
unknown, or in any circumstance where air purifying respirators may not provide
adequate protection.
The information GIVEN AND THE RECOMMENDATIONS MADE HEREIN
APPLY TO OUR PRODUCT(S) ALONE AND ARE NOT COMBINED WITH
OTHER PRODUCTS. SUCH INFORMATION IS BASED UPON OUR RESEARCH
AND ON DATA FROM OTHER RELIABLE SOURCES AND IS BELIEVED
TO BE ACCURATE. NO GUARANTEE OF ACCURACY IS MADE. IT IS
THE PURCHASER’S RESPONSIBILITY BEFORE USING ANY PRODUCT
TO VERIFY THIS DATA UNDER THEIR OWN OPERATING CONDITIONS
AND TO DETERMINE WHETHER THE PRODUCT IS SUITABLE FOR THEIR
PURPOSES.

COPYRIGHT© 1984 KIMBALL MIDWEST UPDATE 9/06

HEAT PRUF GREASE
Revision Date: 2007/05/15
Section 1: PRODUCT INFORMATION
Chemical family: Mixture.
Product uses: Industrial material.
Supplier: Radiator Specialty Co., of Canada
1711 Aimco Blvd.
Mississauga, Ontario
L4W 1H7.
Emergency Phone Number: 303−623−5716
Manufacturer: Refer to supplier.
TDG classification: Not regulated.
WHMIS classification: Not controlled.
DSL status: Not available.
Section 2: HAZARDOUS INGREDIENTS
C.A.S.

CONCENTRATION %

Ingredient Name

T.L.V.

LD/50

LC/50

60.0−100.0

MINERAL OIL

NOT AVAILABLE

NOT AVAILABLE

NOT AVAILABLE

Section 2A: ADDITIONAL INGREDIENT INFORMATION
Note: Mineral Oil − TLV 5 mg/m3.
Section 3: PHYSICAL DATA
Physical state: Semi−solid.
Appearance & odor: Gel
Petroleum odour.
Odor threshold (ppm): Not available.
Vapour pressure (mmHg): <0.1
Vapour density (air=1): >1.0
Volatiles (%)
By volume: Not available.
Evaporation rate
<0.01
(butyl acetate = 1):
Boiling point (°C): Not available.
Freezing point (°C): 284
pH: Not available.
Specific gravity @ 20 °C: (water = 1).
0.99500
Solubility in water (%): Negligible.

GR1, GR1V − HEAT PRUF GREASE

1/4

Coefficient of water\oil dist.: Not available.
VOC: Not available.
Section 4: FIRE & EXPLOSION DATA
Flammability: Not flammable.
Conditions of flammability: At temperatures at or above flash point.
Extinguishing media: Carbon dioxide, dry chemical, foam.
Water spray.
Special procedures: Positive pressure self−contained breathing apparatus required and full protection to
prevent skin contact.
Auto−ignition temperature: Not available.
Flash point (°C), method: Cleveland Open Cup.
450
Lower flammability
Not applicable.
limit (% vol):
Upper flammability
Not applicable.
limit (% vol):
Explosion Data
Sensitivity to static discharge: Not available.
Sensitivity to mechanical impact: Not available.
Hazardous combustion products: Oxides of carbon (CO, CO2).
Unidentified organic compounds.
Explosive power: Not available.
Section 5: REACTIVITY DATA
Chemical stability: Stable under normal conditions.
Conditions of instability: None known.
Hazardous polymerization: Will not occur.
Incompatible substances: Strong oxidizers.
Hazardous decomposition
See hazardous combustion products.
products:
Section 6: TOXICOLOGICAL PROPERTIES
Route of entry: Ingestion.
Skin and eye contact.
Effects of acute exposure
Eye contact: No adverse effects expected.
Skin contact: No adverse effects expected.
Inhalation: No adverse effects expected.
Ingestion: Aspiration of liquid into lungs may cause chemical pneumonitis which can be fatal.
Aspiration may result in pulmonary edema.

GR1, GR1V − HEAT PRUF GREASE

2/4

Effects of chronic exposure: None known.
LD50 of product, species & route: Not available.
LC50 of product, species & route: Not available.
Exposure limit of material: Not available for mixture, see section 2A.
Sensitization to product: Not available.
Carcinogenic effects: Not available.
Reproductive effects: Not available.
Teratogenicity: Not available.
Mutagenicity: Not available.
Synergistic materials: Not available.
Section 7: PREVENTATIVE MEASURES
Precautionary Measures
Gloves/Type:

Wear appropriate gloves.
Respiratory/Type:

Wear a NIOSH approved respirator if TLV is exceeded.
Eye/Type:

Safety glasses.
Do not wear contact lenses.
Footwear/Type: Safety shoes per local regulations.
Clothing/Type: Wear adequate protective clothes.
Other/Type: Eye wash facility should be in close proximity.
Emergency shower should be in close proximity.
Ventilation requirements: Maintain adequate ventilation.
Leak/Spill: Contain the spill.
Absorb with inert material.
Wear appropriate protective equipment.
Place in a chemical waste container for disposal.
Waste disposal: Recycle waste where applicable.
Dispose in accordance with local, provincial/state, and federal regulations.
Handling procedures and Keep away from heat, sparks, and open flame.
equipment: Use adequate ventilation.
Wash thoroughly after using, particularly before eating or smoking.
Wear personal protective equipment appropriate to task.
Keep out of reach of children.
Launder contaminated clothing prior to reuse.

GR1, GR1V − HEAT PRUF GREASE

3/4

Storage requirements: Store away from all sources of ignition.
Store away from incompatible materials.
Keep containers tightly closed.
TDG classification: Not regulated.
Special shipping information: See transportation information.
Section 8: FIRST AID MEASURES
Skin contact: Wash thoroughly with soap and water.
Seek medical attention if irritation persists.
Eye contact: Immediately flush eyes with large amounts of water for at least 15 minutes, lifting
upper and lower lids. Get prompt medical attention.
Inhalation: Remove victim to fresh air.
If breathing is difficult get medical attention.
Ingestion: Guard against aspiration of liquids into lungs.
Never give anything by mouth to an unconscious person.
Do not induce vomiting, seek immediate medical attention.
Additional information: The above information is believed to be correct but does not purport to be all
inclusive and shall be used only as a guide. This company shall not be held liable
for any inaccuracies.
Section 9: ADDITIONAL INFORMATION
General note: This material safety data sheet was prepared from information obtained from
various sources, including product suppliers and the Canadian Center for
Occupational Health and Safety.
This MSDS was generated by Conform−Plus Application Service. Visit us at www.netmsds.com.

GR1, GR1V − HEAT PRUF GREASE

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MATERIAL SAFETY DATA SHEET
PRODUCT NAME: WATER PUTTY
PRODUCT CODE: 8040
==================

HMIS CODES: H
0

SECTION I

-

MANUFACTURER IDENTIFICATION

F
0

R
0

P

=================

MANUFACTURER'S NAME: Custom Building Products, Inc.
ADDRESS: 6511 SALT LAKE AVE., BELL, CA.
90201
EMERGENCY PHONE: (323) 582-0846
INFORMATION PHONE: (323) 582-0846
DATE REVISED
: 10-11-04
NAME OF PREPARER : STEVE TAYLOR
REASON REVISED : NEW
==========

SECTION II

-

HAZARDOUS INGREDIENTS/SARA III INFORMATION

=========

OCCUPATIONAL EXPOSURE
VAPOR
LIMITS
PRESSURE
Wt.
HAZARDOUS COMPONENTS
CAS NUMBER OSHA PEL
ACGIH TLV mm Hg @ TEMP %
--------------------------------------------------------------------------------CALCIUM CARBONATE/
LIMESTONE
1317-65-3
10mg/M3
N/A
40
*** No toxic chemical(s) subject to the reporting requirements of section 313
of Title III and of 40 CFR 372 are present. ***

==============

SECTION III

-

PHYSICAL/CHEMICAL CHARACTERISTICS

=============

BOILING RANGE: N/A
SPECIFIC GRAVITY (H2O=1):
2.6
VAPOR DENSITY: HEAVIER THAN AIR
EVAPORATION RATE: SLOWER THAN ETHER
SOLUBILITY IN WATER: SLIGHT
APPEARANCE AND ODOR: YELLOW POWDER; NO ODOR
================

SECTION IV

-

FIRE AND EXPLOSION HAZARD DATA

FLASH POINT: N/A
FLAMMABLE LIMITS IN AIR BY VOLUME - LOWER:
EXTINGUISHING MEDIA: NONE KNOWN
SPECIAL FIREFIGHTING PROCEDURES

N/A

UPPER:

N/A

===============

NONE
UNUSUAL FIRE AND EXPLOSION HAZARDS
NONE

8040

MATERIAL SAFETY DATA SHEET

========================

SECTION V

-

REACTIVITY DATA

PAGE 2 OF 3
=======================

STABILITY: STABLE
CONDITIONS TO AVOID
NONE
INCOMPATIBILITY (MATERIALS TO AVOID)
POSSIBLE REACTIVITY WITH STRONG MINERAL ACIDS.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS
REACTION WITH ACIDS WILL EVOLVE CARBON DIOXIDE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
=====================

SECTION VI

-

HEALTH HAZARD DATA

======================

INHALATION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
REMOVE TO FRESH AIR.
SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE
MAY DEVELOP SUFFICIENT HEAT TO CAUSE BURNS TO SKIN IF A LARGE MASS IS KEPT
IN CONTACT WITH SKIN WHILE HARDENING. PARTICLES MAY CAUSE IRRITATION TO EYES.
SKIN ABSORPTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
NONE
INGESTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
PLASTER HARDENS WHEN WETTED AND IF INGESTED MAY RESULT IN OBSTRUCTION.
SEE PHYSICIAN.
HEALTH HAZARDS (ACUTE AND CHRONIC)
ACUTE: NONE
CHRONIC: NONE
CARCINOGENICITY:

NTP? NO

IARC MONOGRAPHS? NO

OSHA REGULATED? NO NONE

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
NONE
EMERGENCY AND FIRST AID PROCEDURES
EYE CONTACT: FLUSH WITH WATER TO REMOVE PARTICLES. IF IRRITATION PERSISTS,
SEE PHYSICIAN.
SKIN CONTACT: WASH WITH SOAP AND WATER.

INHALED: REMOVE TO FRESH AIR.
SWALLOWED: IF INGESTED, SEE PHYSICIAN BECAUSE OF POSSIBLE BLOCKAGE.

8040
===========

MATERIAL SAFETY DATA SHEET
SECTION VII

-

PAGE 3 OF 3

PRECAUTIONS FOR SAFE HANDLING AND USE

============

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
CLEAN UP USING DRY METHODS THAT DO NOT DISPERSE DUST INTO THE AIR.
AVOID BREATHING DUST. EMERGENCY PROCEDURES ARE NOT REQUIRED.
WASTE DISPOSAL METHOD
CAN BE TREATED AS COMMON WASTE.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
NONE
OTHER PRECAUTIONS
NONE
=====================

SECTION VIII

-

CONTROL MEASURES

======================

RESPIRATORY PROTECTION
NIOSH APPROVED RESPIRATOR FOR NUISANCE DUST.
VENTILATION
LOCAL EXHAUST.
PROTECTIVE GLOVES
NONE REQUIRED.
EYE PROTECTION
DUST GOGGLES OR SAFETY GLASSES.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT
NONE REQUIRED.
WORK/HYGIENIC PRACTICES
KEEP SPILLED MATERIALS CLEANED UP.
=========================

SECTION IX

-

DISCLAIMER

==========================

DISCLAIMER
THE INFORMATION PRESENTED HERE IS BELIEVED TO BE ACCURATE BUT IS NOT
WARRANTED TO BE, WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS ARE
ADVISED TO CONFIRM IN ADVANCE OF NEED, THAT THE INFORMATION IS CURRENT,
APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES.

Handy & Harman of Canada, Limited
MATERIAL SAFETY DATA SHEET
SECTION 1

MATERIAL IDENTIFICATION AND USE
SIL-FOS, FOS-FLO

MATERIAL NAME IDENTIFIER:

Manufacturer’s Name: HANDY & HARMAN OF CANADA, LIMITED
City: REXDALE

CODE BA-3 rev 10/06

Province/State/Country:

Street Address:

ONTARIO, CANADA M9W 5G1

Supplier’s Name:

290 CARLINGVIEW DRIVE

Emergency Phone No:

(416) 675-1860

Street Address:

City:

Province/State/Country:

Chemical Name:
Silver Brazing Filler Metal
Molecular Weight:
N/Avl.

SECTION 2

Emergency Phone No:
Chemical Family:
Ag/Cu/P; Cu/P; Cu/P/Sn; Cu/P/Sn/Ni Alloys
Trade Names, Synonyms:
Refer To Chart

Chemical Formula:
Refer To Chart
Material Use:
Filler Metals For Brazing

HAZARDOUS CHEMICAL COMPONENTS

Chemical Component

CAS Number

SILVER (Ag)

7440-22-4

COPPER (Cu)

7440-50-8

PHOSPHOROUS (P)
(red allotropic form)

7723-14-0

TIN (Sn)

7440-31-5

NICKEL (Ni)

7440-02-0

(Refer to filler metal chart below for nominal composition %)
ACGIH: TLVs (2000) 0.1 mg/m3 TWA (metal)
3
OSHA PEL: 0.01 mg/m TWA
LC 50 N/Avl.
LD 50 N/Avl.
ACGIH: TLVs (2000) 0.2 mg/m3 TWA (fume); 1.0 mg/m3 TWA (dusts & mists)
3
3
OSHA PELS: 0.1 mg/m TWA (fume); 1.0 mg/m TWA (dusts & mists)
LC 50 N/Avl.
LD 50 470 mg/kg oral-mouse
ACGIH: TLVs N/Avl.
OSHA PEL: N/Avl.
LC 50 N/Avl.
LD 50 N/Avl.
ACGIH: TLVs (2000) 2.0 mg/m3 TWA (metal, oxide, and inorganic compounds, as Sn)
3
OSHA PEL: 2.0 mg/m TWA
LC 50 15 mg/m3/10m inhal.-monkey
LD 50 72 mg/kg oral-mouse
3
ACGIH: TLVs (2000) 1.0 mg/m TWA (metal)(inhalable fraction)
0.2 mg/m3 TWA (insoluble compounds, as Ni)(inhalable fraction)
3
OSHA PEL: 1.0 mg/m TWA (metal & insoluble compounds, as Ni)
LC 50 N/Avl.
LD 50 N/Avl.

HANDY & HARMAN BRAZING FILLER METALS CHART
Solidus
FILLER METAL
NAME
SIL-FOS 18
SIL-FOS
SIL-FOS 6
SIL-FOS 6M
SIL-FOS 5
SIL-FOS 5F
SIL-FOS 2
SIL-FOS 2M
SIL-FOS 1
FOS-FLO 7
FOS-FLO 6
FOS-FLO 5
FOS-FLO 670
FOS-FLO 671

Nominal Composition, %

AWS / SFA
CLASS
BCuP5
BCuP-4
BCuP-3
BCuP-7
BCuP-6

BCuP-2
BCuP-1

Others

(Melt
Point)

Liquidus
(Flow Point)

Brazing Range

Specific

Ag

Cu

P

ºF ºC

ºF ºC

ºF

18
15
6
6
5
5
2
2
9

74.75
80
86.75
88
89
88.25
91
91.4
92.6

7.25
5
7.25
6
6
6.75
7
6.6
6.5

1190-645
1190-645

1190-645
1475-800

1190-1300
1300-1500

645-705
705-815

8.1
8.44

1190-645

1325-720

1275-1450

690-785

7.9

1190-645
1190-645
1190-645
1190-645
1190-645
1190-645

1460-795
1495-815
1420-770
1450-785
1495-815
1500-815

1300-1500
1325-1500
1300-1500
1325-1500
1350-1550
1350-1600

705-815
720-815
705-815
720-815
730-845
730-870

8.1
8.14
8.14
8.0
8.1
8.1

0
0
0

92.75
94
95

7.25
6
5

1310-710
1310-710
1310-710

1460-795
1570-855
1695-925

1350-1550
1375-1575
1450-1700

730-845
745-855
790-925

8.01
8.12
8.1

0
0

87
85.3

6
6.2

1215-657
1134-612

1270-687
1260-682

1270-1450
1260-1425

687-788
682-774

8.4
8.47

7 Sn
7 Sn, 1.5 Ni

ºC

Gravity

Handy & Harman of Canada, Limited
MATERIAL SAFETY DATA SHEET
SECTION 3

PHYSICAL DATA

Physical State: Gas
Liquid
Solid ■
Odour Threshold (ppm): N/Avl.
Evaporation Rate: Solid - N/Appl.
% Volatile (By Volume): N/Appl.
Specific Gravity: Refer To Chart

SECTION 4

CODE BA-3 rev 10/06

Odour & Appearance: No Odour; Solid Metal Wire, Strip, Powder, Paste
Vapour Pressure (mm.Hg): N/Avl.
Vapour Density (AIR=1):Solid-N/Appl.
Boiling Point (ºC): Solid - N/Appl.
Freezing Point (ºC): Solid - N/Appl.
Solubility In Water (20ºC): Insoluble
pH: N/Appl.
Coeff.-Water Oil Disp.: N/Appl.

FIRE AND EXPLOSION DATA

Flammability: Yes ■ No
If yes, under which conditions?
Dust, powder and fumes are flammable when exposed to flame or by chemical reaction with oxidizing agents (see Section 5 for incompatible
materials). Fires or explosions involving these alloys may release potentially toxic emissions of metal or metal oxide fumes (see Section 2 for
hazardous components).
Means Of Extinction: Dry powder for metal fires. Do not use water on dust, powder or fume fires.
Special Procedures: Use self-contained breathing apparatus with full face-piece operated in pressure demand or other positive pressure
mode.
Flashpoint(ºC) & Method: Solid Metal - Non-Flammable
Upper Explosion Limit (% By Volume): N/Appl.
Lower Explosion Limit (%By Volume): Solid Metal - N/Appl.
Auto Ignition Temperature (ºC): Solid Metal - N/Appl.
TDG Flammability Classification: None
Hazardous Combustion Products: Solid Metal - N/Appl.
Sensitivity To Impact Explosion Data: N/Appl.
Rate Of Burning: N/Appl.
Explosive Power: N/Appl.
Sensitivity To Static Discharge: N/Appl.

SECTION 5

REACTIVITY DATA
***AVOID DISPERSION OF FINELY DIVIDED PARTICLES IN AIR***

Chemical Stability: Yes ■ No
If yes, under which conditions? Normal Ambient Environment.
Incompatibility With Other Substances: Yes ■ No
If yes, which ones?
Ammonia; HNO3; Azides; Ethanol; Ethylenimine; Mg; Chlorates; Bromates; C12; CIF3; Chlorine Oxides; Inorganic Peroxides; Peroxyformic
Acid; Permonosulphuric Acid; Fluorine; CS2; SeOCI; SeOF; SeF4; Iodates.
Reactivity And Under What Conditions: Silver and copper can form explosive acetylides upon contact with uncombusted acetylene.
Hazardous Decomposition Products: Hazardous polymerization will not occur. Upon heating, danger is mostly from inhalation of metal
(oxide) fumes. Overexposure to elemental oxide fumes or dust can cause nausea and metal fume fever. Use hooded exhaust ventilation to
carry all fumes away from work area and, if necessary, use air supplied respirator (see Section 7). Thought should be given to the heating
methods, flux and base metals being joined which could emit fumes on heating depending on their particular chemistry.
Avoid overheating (see chart, Brazing Range).

SECTION 6

TOXICOLOGICAL PROPERTIES

Route Of Exposure:
Inhalation
Inhalation of the components of these products are not known to present a significant risk to health
when used according to instructions and with appropriate protective measures (see Section 7). Inhalation of the component/elements has
been reported to cause one or more of the following symptoms/effects upon excessively high and/or prolonged inhalation/exposure.
SILVER:
Acute
May cause grey discolouration of mucous membranes.
Chronic
May produce argyria, a permanent blue-grey discolouration of the skin, eyes, mucous membranes,
and the respiratory tract.
COPPER:
Acute
Acute exposure to dust or fume may cause respiratory tract irritation, fever, muscle ache, chills,
cough, weakness, and a metallic taste.
Chronic
Exposure may cause damage to the liver, kidney, spleen, pancreas, and brain.
PHOSPHOROUS:
Acute
When heated in air, fume is corrosive and irritating to eyes, nose, throat, and mucous membranes.
Chronic
Unlikely.
TIN
Acute
Dust or fume may cause respiratory tract irritation, nausea, joint/muscle pains.
Chronic
May cause stannosis, a benign pneumoconeosis, as well as possible dyspnea.
NICKEL:
Acute
Dust or fumes may produce headache, nausea, vertigo, asthma, and pulmonary edema.
Chronic
May increase the risk of cancer to the nasopharynx, lungs, prostate, and kidney.

Miscellaneous Toxicological Information
Nickel is classified as a potential human carcinogen by the following organizations (with respective sub-classifications):
1. IARC (Group 2B)
2. NTP (Group 2B)
Nickel has also produced fetotoxic and teratogenic effects in animal studies, and mutagenic responses in mammalian cell cultures.
Neither Silver, Copper, Tin, nor Phosphorous are classified as potential or demonstrated human carcinogens by IARC, NIOSH, NTP, OSHA,
or ACGIH.

Page 2

Handy & Harman of Canada, Limited
MATERIAL SAFETY DATA SHEET
SECTION 6 (cont’d)

TOXICOLOGICAL PROPERTIES

CODE BA-3 rev 10/06

Health Conditions Aggravated By Exposure: Pre-existing pulmonary diseases (e.g., bronchitis, emphysema) may be aggravated by
inhalation exposure to these materials, particularly as fume. Exposure to nickel by inhalation and/or ingestion may aggravate pre-existing
diseases of the liver, kidneys, central nervous system, and musculoskeletal system.
Route Of Exposure
Skin: In solid form, materials are not known to be hazardous. In finely divided form, skin contact may produce localized irritation, localized
argyria, skin discolouration, and contact or allergic dermatitis.
Eyes: Exposure of the eyes to finely divided form of these materials may produce localized argyria, irritation, conjunctivitis, and ulceration of
the cornea.
Ingestion: Finely divided form of these materials may produce gastric irritation, vomiting, abdominal pain, hemorrhage, and diarrhea. Longterm chronic ingestion may produce damage to the liver, kidney, spleen, pancreas, musculoskeletal system, blood-forming organs, and
central nervous system.
Exposure Limit Of Material:
Irritancy Of Material:
LD 50 Of Material - Specify
LC 50 Of Material
N/Avl.
N/Avl.
Species And Route: N/Avl.
Specify Species: N/Avl.
Sensitizing Capability Of
Carcinogenicity Of Material:
Reproductive Effects Of
Synergistic Materials:
N/Avl.
N/Avl.
Material: N/Avl.
Material: N/Avl.

SECTION 7

PREVENTATIVE MEASURES

Personal Protective Equipment: Personal protective equipment will be required when using these materials. The nature of the processing
activity will determine what form of equipment is necessary, i.e., safety glasses, respirator, protective clothing, etc. Personal protective
equipment should not be substituted for proper handling and engineering controls.
Gloves: Wear appropriate protective gloves to prevent injury from the hazards of brazing and/or repeated contact with finely divided material.
Avoid flammable fabrics.
Respiratory: Local exhaust, mechanical ventilation, and/or respiratory equipment may be required to maintain a protection factor appropriate
to the airborne concentrations of the contaminants generated and provide sufficient clean air for breathing. If exposure levels exceed OSHA
PELS, wear a NIOSH/MSHA-approved respirator (or other approving authority) for protection from the airborne contaminants. All adjacent
persons in the immediate vicinity of brazing or “soldering” operations shall be similarly protected as necessary by ventilation or approved
respirators.
Eyes: Wear eye protection (safety glasses, dust-proof goggles) adequate to prevent eye contact with this material in finely divided form and
to prevent eye injury from the hazards of brazing. Plastic-frame safety spectacles with side shields and filter lenses (shade #3 or #4) are
recommended.
Footwear: Refer to workplace safety regulations.
Clothing: Avoid flammable fabrics. Wear appropriate clothing to prevent skin injuries from the hazards of brazing.
Other Protection: Practice good housekeeping and personal hygiene procedures. To avoid ingestion of material, wash hands and face
before eating, drinking, or consumption of tobacco.
Brazing alloys may be used with a separately applied flux which, when heated, may emit irritating and/or toxic gases and fumes. Consult the
MSDS for the specific flux in use to determine its hazards and appropriate protective measures. For general guidance, refer to American
National Standards Institute (ANSI) Z49.1, “Safety in Welding and Cutting” (American Welding Society, Miami, FL 33135).
Engineering Controls: Adequate ventilation, sinks, showers, and eyewash stations should be provided. The best industrial control practice
is to maintain concentrations of all chemical fumes and dusts as low as is practical.
Leak And Spill Procedure: If metal is molten, allow to solidify and cool. Clean up any spilled material so as to minimize dispersion of dusts.
Wet sweeping or vacuuming using HEPA, or similarly approved filtration, are recommended methods.
Waste Disposal: Return to manufacturer for reclaim. Sara Title III - Hazard Classes: Acute Health Hazard; Chronic Health Hazard
Handling Procedure And Equipment: Avoid heating above brazing range (see chart, Section 2) as excessive fumes may result. When
applicable, use sufficient flux or atmosphere to protect the metals and minimize oxidation/vapourization during use.
Storage Requirements: Avoid storage near incompatible materials (see also Section 5). Also avoid conditions which create toxic fumes or
dusts. Wash exposed skin after handling material. Stable at room temperature.
Special Shipping Information: No special requirements.
WHMIS Classification: Class D, Division 2, Subdivision B.

Page 3

Handy & Harman of Canada, Limited
MATERIAL SAFETY DATA SHEET
SECTION 8

FIRST AID MEASURES

CODE BA-3 rev 10/06

Emergency And First Aid Procedures
Inhalation: Move victim to fresh air at once. Give oxygen if breathing is laboured, artificial respiration if victim is not breathing. Keep person
warm and quiet. Get medical attention immediately.
Skin: Contact in solid forms is not known to be hazardous. If clothing is contaminated with finely divided particles, remove. Wash affected
area with large quantities of water for at least 5 minutes. Get medical attention if necessary.
Eyes: Flush immediately with large amounts of water for at least 15 minutes while lifting the lower and upper eyelids. If irritation continues,
get medical attention.
Ingestion: If person is conscious, give large amounts of water and induce vomiting. Seek medical attention. If person is unconscious or
convulsive, get immediate medical attention.

***SEEK MEDICAL ATTENTION IN ALL CASES OF EXPOSURE***
SIGNS AND SYMPTOMS OF EXPOSURE:
Acute
Inhalation: Chills, fever, aching muscles, sneezing, dry throat, coughing, constriction of throat, nausea, irritation of nose and trachea,
discolouration of mucous membranes, difficulty in breathing, chest pain, headache.
Skin: Particles may cause irritation, pain, nausea, vomiting.
Eyes: Particles may cause irritation, redness, itching.
Ingestion: Nausea, vomiting, headache, diarrhea, fever, abdominal pain.
Chronic
Inhalation: Cough, difficulty in breathing, laryngitis, discolouration of mucous membranes, kidney and liver disorders.
Skin: May cause argaria, discolouration, contact dermatitis and/or allergic sensitization among hyper-susceptible individuals.
Eyes: Irritation
Ingestion: May cause damage to the liver, kidneys, musculoskeletal system and nervous system.
Medical Conditions Generally Aggravated By Exposure: (see Section 6).
Sources Used: Canadian Centre For Occupational Health And Safety, Hamilton, Ontario; American Welding Society, Miami, Florida;
ACGIH, Cincinnati, Ohio; Lucas-Milhaupt Inc., Cudahy, Wisconsin.
Additional Information: The information contained herein is only for the manufactured product. The composition and hazards of any
resultant fumes due to heating methods, filler metal alloy, flux and base metals employed may vary significantly.
Brazing fumes consist of various airborne substances which may create hazards to health when they are inhaled or swallowed. The degree
of hazard to the worker(s) in the work area depends upon the composition of the total fume, the concentration of contaminants in the
breathing air and the time-length of exposure to it. It is the responsibility of the user/employer to ensure the suitability of the material use and
that TLV, TWA, and STEL values are not exceeded.
Assessment of the possible exposure to the worker(s) to hazardous fumes, when required, should be carried out by a competent person and
may involve air concentration measurements

SECTION 9
PREPARED BY:
Marketing Department

PREPARATION DATE OF MSDS
PHONE NO:
(416) 675-1860

DATE:
Revised 10/06

Page 4

Handy & Harman of Canada, Limited
MATERIAL SAFETY DATA SHEET
SECTION 1

MATERIAL IDENTIFICATION AND USE
SIL-FOS, FOS-FLO

MATERIAL NAME IDENTIFIER:

Manufacturer’s Name: HANDY & HARMAN OF CANADA, LIMITED
City: REXDALE

CODE BA-3 rev 10/06

Province/State/Country:

Street Address:

ONTARIO, CANADA M9W 5G1

Supplier’s Name:

290 CARLINGVIEW DRIVE

Emergency Phone No:

(416) 675-1860

Street Address:

City:

Province/State/Country:

Chemical Name:
Silver Brazing Filler Metal
Molecular Weight:
N/Avl.

SECTION 2

Emergency Phone No:
Chemical Family:
Ag/Cu/P; Cu/P; Cu/P/Sn; Cu/P/Sn/Ni Alloys
Trade Names, Synonyms:
Refer To Chart

Chemical Formula:
Refer To Chart
Material Use:
Filler Metals For Brazing

HAZARDOUS CHEMICAL COMPONENTS

Chemical Component

CAS Number

SILVER (Ag)

7440-22-4

COPPER (Cu)

7440-50-8

PHOSPHOROUS (P)
(red allotropic form)

7723-14-0

TIN (Sn)

7440-31-5

NICKEL (Ni)

7440-02-0

(Refer to filler metal chart below for nominal composition %)
ACGIH: TLVs (2000) 0.1 mg/m3 TWA (metal)
3
OSHA PEL: 0.01 mg/m TWA
LC 50 N/Avl.
LD 50 N/Avl.
ACGIH: TLVs (2000) 0.2 mg/m3 TWA (fume); 1.0 mg/m3 TWA (dusts & mists)
3
3
OSHA PELS: 0.1 mg/m TWA (fume); 1.0 mg/m TWA (dusts & mists)
LC 50 N/Avl.
LD 50 470 mg/kg oral-mouse
ACGIH: TLVs N/Avl.
OSHA PEL: N/Avl.
LC 50 N/Avl.
LD 50 N/Avl.
ACGIH: TLVs (2000) 2.0 mg/m3 TWA (metal, oxide, and inorganic compounds, as Sn)
3
OSHA PEL: 2.0 mg/m TWA
LC 50 15 mg/m3/10m inhal.-monkey
LD 50 72 mg/kg oral-mouse
3
ACGIH: TLVs (2000) 1.0 mg/m TWA (metal)(inhalable fraction)
0.2 mg/m3 TWA (insoluble compounds, as Ni)(inhalable fraction)
3
OSHA PEL: 1.0 mg/m TWA (metal & insoluble compounds, as Ni)
LC 50 N/Avl.
LD 50 N/Avl.

HANDY & HARMAN BRAZING FILLER METALS CHART
Solidus
FILLER METAL
NAME
SIL-FOS 18
SIL-FOS
SIL-FOS 6
SIL-FOS 6M
SIL-FOS 5
SIL-FOS 5F
SIL-FOS 2
SIL-FOS 2M
SIL-FOS 1
FOS-FLO 7
FOS-FLO 6
FOS-FLO 5
FOS-FLO 670
FOS-FLO 671

Nominal Composition, %

AWS / SFA
CLASS
BCuP5
BCuP-4
BCuP-3
BCuP-7
BCuP-6

BCuP-2
BCuP-1

Others

(Melt
Point)

Liquidus
(Flow Point)

Brazing Range

Specific

Ag

Cu

P

ºF ºC

ºF ºC

ºF

18
15
6
6
5
5
2
2
9

74.75
80
86.75
88
89
88.25
91
91.4
92.6

7.25
5
7.25
6
6
6.75
7
6.6
6.5

1190-645
1190-645

1190-645
1475-800

1190-1300
1300-1500

645-705
705-815

8.1
8.44

1190-645

1325-720

1275-1450

690-785

7.9

1190-645
1190-645
1190-645
1190-645
1190-645
1190-645

1460-795
1495-815
1420-770
1450-785
1495-815
1500-815

1300-1500
1325-1500
1300-1500
1325-1500
1350-1550
1350-1600

705-815
720-815
705-815
720-815
730-845
730-870

8.1
8.14
8.14
8.0
8.1
8.1

0
0
0

92.75
94
95

7.25
6
5

1310-710
1310-710
1310-710

1460-795
1570-855
1695-925

1350-1550
1375-1575
1450-1700

730-845
745-855
790-925

8.01
8.12
8.1

0
0

87
85.3

6
6.2

1215-657
1134-612

1270-687
1260-682

1270-1450
1260-1425

687-788
682-774

8.4
8.47

7 Sn
7 Sn, 1.5 Ni

ºC

Gravity

Handy & Harman of Canada, Limited
MATERIAL SAFETY DATA SHEET
SECTION 3

PHYSICAL DATA

Physical State: Gas
Liquid
Solid ■
Odour Threshold (ppm): N/Avl.
Evaporation Rate: Solid - N/Appl.
% Volatile (By Volume): N/Appl.
Specific Gravity: Refer To Chart

SECTION 4

CODE BA-3 rev 10/06

Odour & Appearance: No Odour; Solid Metal Wire, Strip, Powder, Paste
Vapour Pressure (mm.Hg): N/Avl.
Vapour Density (AIR=1):Solid-N/Appl.
Boiling Point (ºC): Solid - N/Appl.
Freezing Point (ºC): Solid - N/Appl.
Solubility In Water (20ºC): Insoluble
pH: N/Appl.
Coeff.-Water Oil Disp.: N/Appl.

FIRE AND EXPLOSION DATA

Flammability: Yes ■ No
If yes, under which conditions?
Dust, powder and fumes are flammable when exposed to flame or by chemical reaction with oxidizing agents (see Section 5 for incompatible
materials). Fires or explosions involving these alloys may release potentially toxic emissions of metal or metal oxide fumes (see Section 2 for
hazardous components).
Means Of Extinction: Dry powder for metal fires. Do not use water on dust, powder or fume fires.
Special Procedures: Use self-contained breathing apparatus with full face-piece operated in pressure demand or other positive pressure
mode.
Flashpoint(ºC) & Method: Solid Metal - Non-Flammable
Upper Explosion Limit (% By Volume): N/Appl.
Lower Explosion Limit (%By Volume): Solid Metal - N/Appl.
Auto Ignition Temperature (ºC): Solid Metal - N/Appl.
TDG Flammability Classification: None
Hazardous Combustion Products: Solid Metal - N/Appl.
Sensitivity To Impact Explosion Data: N/Appl.
Rate Of Burning: N/Appl.
Explosive Power: N/Appl.
Sensitivity To Static Discharge: N/Appl.

SECTION 5

REACTIVITY DATA
***AVOID DISPERSION OF FINELY DIVIDED PARTICLES IN AIR***

Chemical Stability: Yes ■ No
If yes, under which conditions? Normal Ambient Environment.
Incompatibility With Other Substances: Yes ■ No
If yes, which ones?
Ammonia; HNO3; Azides; Ethanol; Ethylenimine; Mg; Chlorates; Bromates; C12; CIF3; Chlorine Oxides; Inorganic Peroxides; Peroxyformic
Acid; Permonosulphuric Acid; Fluorine; CS2; SeOCI; SeOF; SeF4; Iodates.
Reactivity And Under What Conditions: Silver and copper can form explosive acetylides upon contact with uncombusted acetylene.
Hazardous Decomposition Products: Hazardous polymerization will not occur. Upon heating, danger is mostly from inhalation of metal
(oxide) fumes. Overexposure to elemental oxide fumes or dust can cause nausea and metal fume fever. Use hooded exhaust ventilation to
carry all fumes away from work area and, if necessary, use air supplied respirator (see Section 7). Thought should be given to the heating
methods, flux and base metals being joined which could emit fumes on heating depending on their particular chemistry.
Avoid overheating (see chart, Brazing Range).

SECTION 6

TOXICOLOGICAL PROPERTIES

Route Of Exposure:
Inhalation
Inhalation of the components of these products are not known to present a significant risk to health
when used according to instructions and with appropriate protective measures (see Section 7). Inhalation of the component/elements has
been reported to cause one or more of the following symptoms/effects upon excessively high and/or prolonged inhalation/exposure.
SILVER:
Acute
May cause grey discolouration of mucous membranes.
Chronic
May produce argyria, a permanent blue-grey discolouration of the skin, eyes, mucous membranes,
and the respiratory tract.
COPPER:
Acute
Acute exposure to dust or fume may cause respiratory tract irritation, fever, muscle ache, chills,
cough, weakness, and a metallic taste.
Chronic
Exposure may cause damage to the liver, kidney, spleen, pancreas, and brain.
PHOSPHOROUS:
Acute
When heated in air, fume is corrosive and irritating to eyes, nose, throat, and mucous membranes.
Chronic
Unlikely.
TIN
Acute
Dust or fume may cause respiratory tract irritation, nausea, joint/muscle pains.
Chronic
May cause stannosis, a benign pneumoconeosis, as well as possible dyspnea.
NICKEL:
Acute
Dust or fumes may produce headache, nausea, vertigo, asthma, and pulmonary edema.
Chronic
May increase the risk of cancer to the nasopharynx, lungs, prostate, and kidney.

Miscellaneous Toxicological Information
Nickel is classified as a potential human carcinogen by the following organizations (with respective sub-classifications):
1. IARC (Group 2B)
2. NTP (Group 2B)
Nickel has also produced fetotoxic and teratogenic effects in animal studies, and mutagenic responses in mammalian cell cultures.
Neither Silver, Copper, Tin, nor Phosphorous are classified as potential or demonstrated human carcinogens by IARC, NIOSH, NTP, OSHA,
or ACGIH.

Page 2

Handy & Harman of Canada, Limited
MATERIAL SAFETY DATA SHEET
SECTION 6 (cont’d)

TOXICOLOGICAL PROPERTIES

CODE BA-3 rev 10/06

Health Conditions Aggravated By Exposure: Pre-existing pulmonary diseases (e.g., bronchitis, emphysema) may be aggravated by
inhalation exposure to these materials, particularly as fume. Exposure to nickel by inhalation and/or ingestion may aggravate pre-existing
diseases of the liver, kidneys, central nervous system, and musculoskeletal system.
Route Of Exposure
Skin: In solid form, materials are not known to be hazardous. In finely divided form, skin contact may produce localized irritation, localized
argyria, skin discolouration, and contact or allergic dermatitis.
Eyes: Exposure of the eyes to finely divided form of these materials may produce localized argyria, irritation, conjunctivitis, and ulceration of
the cornea.
Ingestion: Finely divided form of these materials may produce gastric irritation, vomiting, abdominal pain, hemorrhage, and diarrhea. Longterm chronic ingestion may produce damage to the liver, kidney, spleen, pancreas, musculoskeletal system, blood-forming organs, and
central nervous system.
Exposure Limit Of Material:
Irritancy Of Material:
LD 50 Of Material - Specify
LC 50 Of Material
N/Avl.
N/Avl.
Species And Route: N/Avl.
Specify Species: N/Avl.
Sensitizing Capability Of
Carcinogenicity Of Material:
Reproductive Effects Of
Synergistic Materials:
N/Avl.
N/Avl.
Material: N/Avl.
Material: N/Avl.

SECTION 7

PREVENTATIVE MEASURES

Personal Protective Equipment: Personal protective equipment will be required when using these materials. The nature of the processing
activity will determine what form of equipment is necessary, i.e., safety glasses, respirator, protective clothing, etc. Personal protective
equipment should not be substituted for proper handling and engineering controls.
Gloves: Wear appropriate protective gloves to prevent injury from the hazards of brazing and/or repeated contact with finely divided material.
Avoid flammable fabrics.
Respiratory: Local exhaust, mechanical ventilation, and/or respiratory equipment may be required to maintain a protection factor appropriate
to the airborne concentrations of the contaminants generated and provide sufficient clean air for breathing. If exposure levels exceed OSHA
PELS, wear a NIOSH/MSHA-approved respirator (or other approving authority) for protection from the airborne contaminants. All adjacent
persons in the immediate vicinity of brazing or “soldering” operations shall be similarly protected as necessary by ventilation or approved
respirators.
Eyes: Wear eye protection (safety glasses, dust-proof goggles) adequate to prevent eye contact with this material in finely divided form and
to prevent eye injury from the hazards of brazing. Plastic-frame safety spectacles with side shields and filter lenses (shade #3 or #4) are
recommended.
Footwear: Refer to workplace safety regulations.
Clothing: Avoid flammable fabrics. Wear appropriate clothing to prevent skin injuries from the hazards of brazing.
Other Protection: Practice good housekeeping and personal hygiene procedures. To avoid ingestion of material, wash hands and face
before eating, drinking, or consumption of tobacco.
Brazing alloys may be used with a separately applied flux which, when heated, may emit irritating and/or toxic gases and fumes. Consult the
MSDS for the specific flux in use to determine its hazards and appropriate protective measures. For general guidance, refer to American
National Standards Institute (ANSI) Z49.1, “Safety in Welding and Cutting” (American Welding Society, Miami, FL 33135).
Engineering Controls: Adequate ventilation, sinks, showers, and eyewash stations should be provided. The best industrial control practice
is to maintain concentrations of all chemical fumes and dusts as low as is practical.
Leak And Spill Procedure: If metal is molten, allow to solidify and cool. Clean up any spilled material so as to minimize dispersion of dusts.
Wet sweeping or vacuuming using HEPA, or similarly approved filtration, are recommended methods.
Waste Disposal: Return to manufacturer for reclaim. Sara Title III - Hazard Classes: Acute Health Hazard; Chronic Health Hazard
Handling Procedure And Equipment: Avoid heating above brazing range (see chart, Section 2) as excessive fumes may result. When
applicable, use sufficient flux or atmosphere to protect the metals and minimize oxidation/vapourization during use.
Storage Requirements: Avoid storage near incompatible materials (see also Section 5). Also avoid conditions which create toxic fumes or
dusts. Wash exposed skin after handling material. Stable at room temperature.
Special Shipping Information: No special requirements.
WHMIS Classification: Class D, Division 2, Subdivision B.

Page 3

Handy & Harman of Canada, Limited
MATERIAL SAFETY DATA SHEET
SECTION 8

FIRST AID MEASURES

CODE BA-3 rev 10/06

Emergency And First Aid Procedures
Inhalation: Move victim to fresh air at once. Give oxygen if breathing is laboured, artificial respiration if victim is not breathing. Keep person
warm and quiet. Get medical attention immediately.
Skin: Contact in solid forms is not known to be hazardous. If clothing is contaminated with finely divided particles, remove. Wash affected
area with large quantities of water for at least 5 minutes. Get medical attention if necessary.
Eyes: Flush immediately with large amounts of water for at least 15 minutes while lifting the lower and upper eyelids. If irritation continues,
get medical attention.
Ingestion: If person is conscious, give large amounts of water and induce vomiting. Seek medical attention. If person is unconscious or
convulsive, get immediate medical attention.

***SEEK MEDICAL ATTENTION IN ALL CASES OF EXPOSURE***
SIGNS AND SYMPTOMS OF EXPOSURE:
Acute
Inhalation: Chills, fever, aching muscles, sneezing, dry throat, coughing, constriction of throat, nausea, irritation of nose and trachea,
discolouration of mucous membranes, difficulty in breathing, chest pain, headache.
Skin: Particles may cause irritation, pain, nausea, vomiting.
Eyes: Particles may cause irritation, redness, itching.
Ingestion: Nausea, vomiting, headache, diarrhea, fever, abdominal pain.
Chronic
Inhalation: Cough, difficulty in breathing, laryngitis, discolouration of mucous membranes, kidney and liver disorders.
Skin: May cause argaria, discolouration, contact dermatitis and/or allergic sensitization among hyper-susceptible individuals.
Eyes: Irritation
Ingestion: May cause damage to the liver, kidneys, musculoskeletal system and nervous system.
Medical Conditions Generally Aggravated By Exposure: (see Section 6).
Sources Used: Canadian Centre For Occupational Health And Safety, Hamilton, Ontario; American Welding Society, Miami, Florida;
ACGIH, Cincinnati, Ohio; Lucas-Milhaupt Inc., Cudahy, Wisconsin.
Additional Information: The information contained herein is only for the manufactured product. The composition and hazards of any
resultant fumes due to heating methods, filler metal alloy, flux and base metals employed may vary significantly.
Brazing fumes consist of various airborne substances which may create hazards to health when they are inhaled or swallowed. The degree
of hazard to the worker(s) in the work area depends upon the composition of the total fume, the concentration of contaminants in the
breathing air and the time-length of exposure to it. It is the responsibility of the user/employer to ensure the suitability of the material use and
that TLV, TWA, and STEL values are not exceeded.
Assessment of the possible exposure to the worker(s) to hazardous fumes, when required, should be carried out by a competent person and
may involve air concentration measurements

SECTION 9
PREPARED BY:
Marketing Department

PREPARATION DATE OF MSDS
PHONE NO:
(416) 675-1860

DATE:
Revised 10/06

Page 4

Page 1/7

Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 07/25/2003

Reviewed on 07/14/2003

1 Identification of substance
Product details
Trade name: 256GS Sn55Pb45, Sn60Pb40, Sn62Pb38, Sn63Pb37, Sn65Pb35
Application of the substance / the preparation: Solder paste
Manufacturer/Supplier:
Kester
515 E. Touhy Ave.
Des Plaines, IL 60018
Information department:
MSDS Coordinator
Emergency information:
CHEMTREC 24-Hour Emergency Telephone Number:
CHEMTREC 24-Hour Emergency Telephone Number (Outside of the U.S. and Canada):

Tel.(847) 297-1600
Fax.(847) 390-9338

Tel. (847) 699-5755
(800)424-9300
(703)527-3887

2 Composition/Data on components
Chemical characterization
Description: Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
7440-31-5 tin
7439-92-1 lead
65997-05-9 Rosin, polymerized
8050-09-7 Rosin
143-24-8 bis(2-(2-methoxyethoxy)ethyl) ether

50-100%
25-50%
2.5-10%
≤ 2.5%
≤ 2.5%

3 Hazards identification
WHMIS Hazard Symbols

=

Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of international guidelines.
Harmful by inhalation and if swallowed.
Danger of cumulative effects.
May cause sensitisation by skin contact.
Possible risk of impaired fertility.
Contains lead. Should not be used on surfaces liable to be chewed or sucked by children.
Classification system:
NFPA ratings (scale 0 - 4)

2

1

0

Health = 2
Fire = 1
Reactivity = 0
(Contd. on page 2)
USA

DR

Page 2/7

Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 07/25/2003

Reviewed on 07/14/2003

Trade name: 256GS Sn55Pb45, Sn60Pb40, Sn62Pb38, Sn63Pb37, Sn65Pb35
(Contd. of page 1)

HMIS-ratings (scale 0 - 4)
HEALTH

*2

FIRE

1

REACTIVITY 0

Health = *2
Fire = 1
Reactivity = 0

4 First aid measures
General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
After inhalation: Supply fresh air; consult doctor in case of complaints.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact: Rinse opened eye for several minutes under running water.
After swallowing: Induce vomiting, if person is conscious. Seek medical help.

5 Fire fighting measures
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards caused by the material, its products of combustion or resulting gases:
In case of fire, the following can be released:
Carbon monoxide (CO)
Carbon dioxide (CO2)
Aliphatic aldehydes
Melted solder above 1000°F will liberate toxic lead and/or antimony fumes.
Protective equipment: Wear self-contained respiatory protective device.

6 Accidental release measures
Person-related safety precautions: Ensure adequate ventilation
Measures for environmental protection: Do not allow product to reach sewage system or any water course.
Measures for cleaning/collecting: Scoop up paste and deposit in appropriate containers.

7 Handling and storage
Handling:
Information for safe handling:
Wash hands after handling paste and before eating or smoking. Care should be taken to remove paste from
under fingernails.
Information about protection against explosions and fires: Keep respiratory protective device available.
Storage:
o
Requirements to be met by storerooms and receptacles: Store at or near 5 C in a dry location.
Information about storage in one common storage facility: Not required.
(Contd. on page 3)
USA

DR

Page 3/7

Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 07/25/2003

Reviewed on 07/14/2003

Trade name: 256GS Sn55Pb45, Sn60Pb40, Sn62Pb38, Sn63Pb37, Sn65Pb35
(Contd. of page 2)

Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles.

8 Exposure controls and personal protection
Additional information about design of technical systems: No further data; see item 7.
Components with limit values that require monitoring at the workplace:
7440-31-5 tin
PEL 2 mg/m³
Metal
REL 2 mg/m³
Tin, Metal
TLV 2 mg/m³
7439-92-1 lead
PEL 0.05* mg/m³
as Pb
REL <0.1* mg/m³
as Pb; *Blood Pb <0.06 mg/100 g whole blood
TLV 0.05 mg/m³
as Pb; BEI
8050-09-7 Rosin
PEL (Colophony)
TLV SEN; (L)
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Breathing equipment:
When ventilation is not sufficient to remove fumes from the breathing zone, a safety approved respirator or selfcontained breathing apparatus should be worn.
Protection of hands:

S

Protective gloves

Material of gloves:
Nitrile rubber, NBR
Natural rubber, NR
Penetration time of glove material:
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:

R

Tightly sealed goggles
(Contd. on page 4)
USA

DR

Page 4/7

Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 07/25/2003

Reviewed on 07/14/2003

Trade name: 256GS Sn55Pb45, Sn60Pb40, Sn62Pb38, Sn63Pb37, Sn65Pb35
(Contd. of page 3)

Safety glasses

9 Physical and chemical properties
General Information
Form:
Color:
Odor:

Pasty
Silver grey
Mild

Change in condition
Melting point/Melting range: > 100°C (> 212°F)
Boiling point/Boiling range: Undetermined.
Flash point:

> 93°C (> 199°F)

Danger of explosion:

Product does not present an explosion hazard.

Density at 20°C (68°F):

> 7 g/cm³

Solubility in / Miscibility with
Water:
Insoluble.

10 Stability and reactivity
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Materials to be avoided: Strong acids, strong oxidizers.
Dangerous reactions No dangerous reactions known.
Dangerous products of decomposition:
When heated to soldering temperatures, the solvents are evaporated and rosin may be thermally degraded to
liberate aliphatic aldehydes and acids.

11 Toxicological information
Acute toxicity:
Primary irritant effect:
on the skin: Possible local irritation by contact with flux or fumes.
on the eye: Smoke during soldering can cause eye irritation.
through inhalation:
Flux fumes during soldering may cause irritation and damage of mucous membranes and respiratory system.
through ingestion: May be harmful if swallowed.
Sensitization: Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Irritant
USA

(Contd. on page 5)

DR

Page 5/7

Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 07/25/2003

Reviewed on 07/14/2003

Trade name: 256GS Sn55Pb45, Sn60Pb40, Sn62Pb38, Sn63Pb37, Sn65Pb35
(Contd. of page 4)

12 Ecological information
General notes: Do not allow product to reach ground water, water course or sewage system.

13 Disposal considerations
Product:
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.

14 Transport information
DOT regulations:
Hazard class:
Not regulated.
Land transport ADR/RID (cross-border):
ADR/RID class: Not regulated.
Maritime transport IMDG:
IMDG Class:
Not regulated.
Air transport ICAO-TI and IATA-DGR:
ICAO/IATA Class: Not regulated.

15 Regulations
USA The following information relates to product regulation specific to the USA.
SARA (Superfund Amendments and Reauthorization Act)
Section 355 (extremely hazardous substances):
None of the ingredient is listed.
Section 313 (Specific toxic chemical listings):
7439-92-1 lead
TSCA (Toxic Substances Control Act):
All ingredients are listed.
California Proposition 65
Chemicals known to cause cancer:
WARNING: This product contains a chemical known to the State of California to cause cancer.
7439-92-1 lead
(Contd. on page 6)
USA
DR

Page 6/7

Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 07/25/2003

Reviewed on 07/14/2003

Trade name: 256GS Sn55Pb45, Sn60Pb40, Sn62Pb38, Sn63Pb37, Sn65Pb35
(Contd. of page 5)

25013-16-5 tert-butyl-4-methoxyphenol
7440-43-9 cadmium
7440-02-0 nickel
Chemicals known to cause reproductive toxicity:
WARNING: This product contains a chemical known to the State of California to cause birth defects and/or other
reproductive harm.
7439-92-1 lead
872-50-4 N-methyl-2-pyrrolidone
7440-43-9 cadmium
Carcinogenicity categories
EPA (Environmental Protection Agency)
7439-92-1 lead B2
IARC (International Agency for Research on Cancer)
7439-92-1 lead 2B
NTP (National Toxicology Program)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
CANADA: The following information relates to product regulation specific to Canada.
Workplace Hazardous Materials Identification (WHMIS):
This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products
Regulation (CPR) and the MSDS contains all of the information required by the CPR.
WHMIS Classification:
D2A
D2B
Components on Ingredient List for WHMIS:
Rosin, polymerized
lead
tin
EUROPEAN UNION
The following information relates to product regulation specific to the directives of the Euopean Union.
Risk phrases:
Harmful by inhalation and if swallowed.
Danger of cumulative effects.
May cause sensitisation by skin contact.
Possible risk of impaired fertility.
(Contd. on page 7)
USA

DR

Page 7/7

Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 07/25/2003

Reviewed on 07/14/2003

Trade name: 256GS Sn55Pb45, Sn60Pb40, Sn62Pb38, Sn63Pb37, Sn65Pb35
(Contd. of page 6)

Safety phrases:
Avoid exposure - obtain special instructions before use.
Keep locked up and out of the reach of children.
Avoid contact with skin.
Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point.
Wear suitable gloves.
In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
Special labeling of certain preparations:
Contains lead. Should not be used on surfaces liable to be chewed or sucked by children.

16 Other information
The information contained herein is based on data considered accurate and is offered solely for information,
consideration and investigation. Kester extends no warranties, makes no representations and
assumes no responsibilty as to the accuracy, completeness or suitability of this data for any purchaser's use. The
data on this Material Safety Data Sheet relates only to this product and does not relate to use with any other
material or in any process. All chemical products should be used only by, or under the direction of, technically
qualified personnel who are aware of the hazards involved and the necessity for reasonable care in handling.
Hazard communication regulations require that employees must be trained on how to use a Material Safety Data
Sheet as a source for hazard information.
Department issuing MSDS: Product Safety
Contact: Heather Holich, MSDS Coordinator

Tel. (847)699-5755
USA

DR

1 of 2

Quality Through People and Technology

Amerway Silver Solder Flux
Material Safety Data Sheet
Section 01
Information furnished by:

Date effective:
Emergency phone:
Chemtrec:
Product or trade name:
Product Use:
Person to contact:

Identification
Amerway, Inc.
3701 Beale Avenue
Altoona, PA 16601
1/01/08
1-814-944-0200
1-800-424-9300
Amerway Silver Solder Flux
Silver Soldering
Terry Buck

Section 02
Constituents
Chem
CAS
%Wt.
PEL/PPM
Zinc Chloride
7646-85-7
30-45
1 mg/m^3
Ammonium Chloride
12125-02-09
5-15
10.0 mg/m^3
Ammonium Biflouride 1341-49-7
2-7
2.5 mg/mg^3
Hydrochloric Acid
7647-01-0
3-6
5 ppm
All ingredients are reported in EPA and TSCA inventory.
Unlisted ingredients are considered non-toxic.
None of the materials in this product are listed in NTP, IARC, or OSHA as carcinogens.

TLV/PPM
1 mg/m^3
10.0 mg/m^3
2.5 mg/mg^3
5 ppm

Section 03
Melting Point
Boiling Point
Vapor Pressure
Vapor Density ( air is 1)
Solubility in Water
Appearance & Color
Specific Gravity
Odor
% Volatile
pH
Evaporation Rate :(nBuAc=1)

Physical Data
N/A
212 F
N/A
N/A
100 %
Clear Liquid
1.5
Acidic
65%
1.0
6

Section 04
Flash Point / Method Used
Flammable Limits
Extinguishing Media
Fire Fighting Equipment
Special Precautions

Fire and Explosion Hazard Data
None
None
N/A
Water or with non-flammable salts.
None

Section 05
Stability
Conditions to Avoid
Hazardous Polymerization
Incompatibility
Hazardous Decomposition Products

Reactivity Data
Stable
Inhalation of fumes.
Will not occur.
Alkalis
None known.

Section 06
Action to take for spills/leaks
Disposal method

Spill, Leak and Disposal Procedures
Dilute with water.
Dispose of per federal, state and local regulations.

2 of 2
Section 07
Eye
Skin Contact
Skin Absorption
Ingestion
Inhalation
Systemic & Other Effects
Section 08
Eyes
Skin
Ingestion
Inhalation
Note to Physician
Section 09
Ventilation
Respiratory Protection
Eye Protection
Skin Protection
Other
Section 10
Storage
Handling Information
Website by Precision Business Solutions

Health Hazard Data
Higher concentrations can cause eye irritations.
May cause skin irritation.
Will cause skin irritation.
Do not induce vomiting, give two glasses of milk or
water, contact a physician.
Remove to fresh air, contact a physician.
None known.
First Aid Procedures
Wash with water for 10 minutes, contact physician.
Wash with soap and water.
Do not induce vomiting, give two glasses of milk or water.
Contact a physician.
Remove to fresh air, contact a physician.
Salt solution of chlorine and fluorine.
Special Handling Information
Fume hood or mechanical ventilation must be provided to
maintain exposure levels below TLV’s.
Use NIOSH/OSHA approved respirator for dust and acid
fumes.
Wear safety goggles during use.
Wear rubber apron and gloves.
Follow NIOSH/OSHA health guidelines for chemical
hazards.
Special Precautions and Additional Information
Store in dry cool place.
When handling use proper safety procedures.
© Amerway.com

MATERIAL SAFETY DATA SHEET
PLEASE CAREFULLY READ AND UNDERSTAND THIS MATERIAL SAFETY DATA SHEET BEFORE USING THIS PRODUCT
May be used to comply with OSHA’s Hazards Communication Standard, 29 CFR 1910.1200. Standard must be consulted for specific requirements.

SECTION I (IDENTIFICATION)
Manufacturer/Supplier Name:

UNIWELD PRODUCTS, INC.
2850 Ravenswood Road
Fort Lauderdale, FL 33312

Emergency Phone No.:

Product Name(s):
Product Classification:

PROPANE ODORIZED
LIQUIFIED PETROLEUM GAS (PARAFFINIC HYDROCARBONS)

(954) 584-2000

SECTION II (HAZARDOUS INGREDIENTS/IDENTITY INFORMATION)
Important: Propane may contain various percentages of these hazardous components, depending on the source of supply.

EXPOSURE LIMIT (mg/m3)
INGREDIENT

% WEIGHT

CAS NO.

85-100

74-98-6

PROPYLENE

0-10

115-07-1

BUTANE & HEAVIER

0-2.5

106-97-8

ETHANE

0-5

74-84-0

ETHYL MERCAPTAN
(ODORANT)

<0.1

75-08-1

PROPANE

OSHA PEL/TWA

ACGIH TLV/TWA

1,000 PPM

800 PPM

800 PPM

SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS
Property

Value

Appearance and odor

Colorless gas, liquid under pressure. Mercaptan “rotten eggs” odor

Boiling point

-44 degrees F.

Evaporation rate (Butyl Acetate = 1)

<1 (diffuses readily)

Flash point

-156 degrees F.

Liquid to vapor expansion ratio

1:270

Molecular weight

44.096

Solubility in water

Slight

Specific gravity (liquid)

0.500 - 0.510 (Water = 1)

Specific gravity (vapor)

1.52 (Air = 1)

Vapor pressure (maximum)

208 PSIG @ 100 degrees F.

SECTION IV - FIRE AND EXPLOSION HAZARD DATA
Flammability limits

Ignition temperature
Extinguishing media

Special fire-fighting
procedures and precautions

Flammability limits by volume in air.
Lower 2.15 percent
Upper 9.6 percent
Auto ignition temperature is 940 degrees Fahrenheit.
Allow product to burn if source cannot be shut off safely.
Class B-C or A-B-C dry chemical or halon extinguishers can be used on small fires.
Apply water from a safe distance to cool containers, surrounding equipment, and structures.
Extremely flammable. Containers may explode if not sufficiently cooled with water spray.
Evacuate surrounding area of unprotected personnel and isolate. Do not enter confined fire space without full bunker gear
(helmet with face shield, bunker coats, gloves, and rubber boots) and a positive pressure NIOSH-approved self-contained
breathing apparatus.

SECTION V - REACTIVITY DATA
Stability and hazardous
polymerization
Conditions and materials
vapor accumulation.

This product is stable. Hazardous polymerization will not occur.
Avoid heat, sparks, flame, and contact with strong oxidizing agents. Avoid buildups of static electricity. Prevent to avoid

Hazardous
decomposition products

Carbon monoxide and unidentified organic products may be formed during combustion.

Purpose
Eye contact
Skin contact
Inhalation

The health effects are consistent with requirements of the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Direct contact with liquid propane can result in eye burns.
Direct contact with liquid propane can result in skin burns (frostbite).
This product is classified as a simple asphyxiant.
High vapor concentrations may produce a reversible central nervous system depression (anesthesia).
Higher concentrations may produce asphyxiation.
WARNING: DO NOT BREATHE FUMES!
Ingestion is not likely.
Eye or skin burns (frostbite) as noted previously.
Early to moderate central nervous system depression may be evidenced by giddiness, headache, dizziness, and nausea. In
extreme cases, unconsciousness may occur.
Asphyxiation may be noted by a sudden loss of consciousness. Death may quickly follow.
Caution is recommended for personnel with pre-existing central nervous system or chronic respiratory diseases.

SECTION VI - HEALTH HAZARD DATA

Ingestion
Signs and symptoms

Aggravated medical
conditions
Acute toxicity data
Carcinogenicity
Occupational exposure limits
Cardiac effects

Acute toxicity data is not applicable to this product.
This product is not classified as a carcinogen.
See the table in section 2
While there is no evidence that exposure to industrially acceptable levels of hydrocarbons have produced cardiac effects
in humans, animal studies have shown that inhalation of high vapor levels of the components of this product have produced
CONTINUED ON THE BACK

Effects of propylene

cardiac sensitization. Such sensitization may cause fatal changes in heart rhythms. This latter effect was shown to be
enhanced by hypoxia or the injection of adrenaline-like agents.
Laboratory animals exposed to high levels of propylene for prolonged periods of time showed evidence of effects in the liver,
kidneys, and nasal cavity.

SECTION VII - PRECAUTIONS FOR SAFE HANDLING & USE
Release, spill, or
leak procedures

Warning! Extremely flammable.

Eliminate sources of ignition.
Isolate hazard area and deny entry to unnecessary or unprotected personnel.
Stay upwind and keep out of low areas.
Notify local fire department.
Disperse vapor clouds with water spray.
Shut off source of leak only if it can be done safely.
Training
Train all personnel involved in handling propane in proper handling and operating procedures.
Document all training.
Handling and storing
Handle and store propane in accordance with NFPA 58 and local fire codes.
Keep containers away from heat sources or temperatures exceeding 130 degrees Fahrenheit.
Do not drop or roll any container.
Store and transport containers with relief valves in vapor space.
Keep all container valves closed when not in use.
Keep protective caps (if applicable) on containers when not in use.
DOT cylinders
Take these precautions when using DOT cylinders:
Periodically inspect and requalify DOT cylinders in accordance with DOT and NFPA 58 codes.
Store and use cylinders with valves off and the relief valves in the container vapor space.
Shut all valves and follow recommended procedures before exchanging cylinders.
Special precautions
Containers, even those that have been emptied, can contain explosive vapors.
Do not cut, drill, grind, weld or perform similar operations on or near containers.
Propane odorization
Warning! Any smell of odorant, even a faint one, may indicate a dangerous situation.
Ethyl mercaptan is the preferred warning agent for propane. Although ethyl mercaptan has excellent warning properties,
“It is recognized that no odorant will be completely effective as a warning agent in every circumstance” (NFPA 58 A-1-4.1,
1992 edition).
Instances in which odorants may lose their effectiveness include, but are not limited to the following:
Odor may fade due to chemical oxidation in improperly prepared new tanks and cylinders or from rust, air and water
in used containers that have been allowed to stand open to the atmosphere.
Odor may be absorbed and adsorbed by the walls of containers and distribution systems.
Odor in the gas escaping from underground leaks may be absorbed by certain types of soils.
Effectiveness of the odorant may be reduced by cold temperatures.
Other odors, such as from cooking or from a musty basement, may mask or cover up the mercaptan odor in propane.
Exposure to the mercaptan odor of propane for extended periods of time may affect a person’s ability to
detect the odorant.
Physical disabilities or the use of alcohol, tobacco, or drugs may decrease a person’s ability to detect the odorant.
WARNING: CALIFORNIA PROPOSITION 65: This product, when used for welding, soldering, brazing, cutting and other metal working or flame processes,
produces fumes, particulates, residues and/or other by-products which contain chemicals known to the State of California to cause cancer and birth defects
or other reproductive harm.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive
harm.

SECTION VIII - FIRE AND EXPLOSION HAZARDS
Flammability limits

Ignition temperature
Extinguishing media

Flammability limits by volume in air.
Lower 2.15 percent
Upper 9.6 percent
Auto ignition temperature is 940 degrees Fahrenheit.
Allow product to burn if source cannot be shut off safely.
Class B-C or A-B-C dry chemical or halon
extinguishers can be used on small fires.
Apply water from a safe distance to cool containers,
surrounding equipment, and structures.

Extremely flammable compressed gas.• Asphyxiant
in high concentrations. • Skin contact with liquid
causes burns similar to frostbite. • Ethyl mercaptan
used as a warning agent may not be entirely effective
in all situations. Read the warnings in section 7.
NFPA hazard Hazard ratings are in the following table
rating
Fire Hazard
Health hazard = 1
Health
Fire hazard = 4
Hazard
Reactivity = 0
Where:
0 = Least
3 = High
Reactivity
1 = Slight
4 = Extreme
2 = Moderate
Warning!

4

1

0

SECTION VIIII - EMERGENCY AND FIRST AID PROCEDURES
Purpose
Eye contact with liquid
Skin contact with liquid
Inhalation
Ingestion

Follow these procedures in case of personal injuries resulting from use of this product.
Flush eyes with water. Get medical attention.
Flush with water. If frostbite or burn occurs, get medical attention.
Remove victim to fresh air and provide oxygen if breathing is difficult.
Seek immediate medical attention if victim is not breathing. Give artificial respiration.
Not applicable to this product.

SECTION X - EMPLOYEE PROTECTION
Respiratory protection

Use a NIOSH-approved respirator as required when airborn exposure limits are exceeded.
In accord with 29 CFR 1910.134, use either an atmosphere supplying respirator or an air purifying respirator for
organic vapors.
WARNING: DO NOT BREATHE FUMES!
Protective clothing
Avoid liquid contact with eyes or skin.
Wear safety glasses or goggles as appropriate.
Wear protective clothing as appropriate.
Additional protective measures Use explosion-proof ventilation as required to control vapor concentrations.

SECTION XI - TRANSPORTATION REQUIREMENTS
DOT shipping name
DOT classification
Other DOT requirements

Liquefied Petroleum Gas
Division 2.1 (Flammable Gas)
UN 1075, Hazardous Materials Guide Number 115.

EPA/TSCA
EPA Hazard Classification

The components of this product are listed on the EPA/TSCA inventory of chemical substances.
This product is classified by 40 CFR 372 (SARA Section 313) as:

SECTION XII - OTHER REGULATORY CONTROLS

Acute Hazard

Chronic Hazard

XXX
Ozone-depleting substances
RCRA Information

State regulatory information

Fire Hazard

Pressure Hazard

XXX

XXX

Reactive Hazard

This product does not contain, nor was it directly manufactured with, any class I or class II ozone-depleting substances.
This product is not subject to 40CFR 268.30 ban on the disposal of hazardous wastes.
If this product becomes a waste material, it would be an ignitable hazardous waste, having a waste code number D0001.
Refer to latest EPA or state regulations regarding proper disposal. Under EPA-RCRA, containers are considered hazardous
unless depressurized to a pressure approaching atmospheric. Depressurize containers at a controlled rate to a flare.
The ingredients in this product are specifically listed by individual states; other product specific health and safety data in
other sections of the MSDS may also be applicable for state requirements.
Contact the appropriate agency in your state for details on your regulatory requirements.

Uniweld Products, Inc. believes this data to be accurate and to reflect qualified expert opinion regarding current research. Uniweld Products, Inc. cannot

make any expressed or implied warranty as to this information.

MSD50
Effective Date: January, 2008

Material Safety Data Sheet
Section 1
Product Name:
Revision #: 2.0

Product and Company Identification
BLOC-IT Heat Sink Paste
Date Prepared: May 23, 1991

Manufacturer:

Date Revised: June 14, 2004

Supplier/Importer:

LA-CO INDUSTRIES, Inc./Markal Co.
1201 Pratt Blvd.
Elk Grove Village, IL, USA 60007-5746
Information Telephone: 847-956-7600
Emergency Telephone: Call CHEMTREC
USA 800-424-9300
International (Call Collect) 1-703-527-3887
Chemical Formula: Mixture
CAS No.: Not Applicable. Derivation: Not Applicable.
Synonyms: Not Applicable.
General Use: Heat sink paste for protecting heat
sensitive areas when soldering, brazing or welding.

Section 2

Composition/Information on Ingredients

Ingredient

CAS No.

No Hazardous ingredients according to the U.S. OSHA Hazard Communication Standard 29
CFR 1910.1200, Canadian WHMIS regulations, British CHIP2 regulation 6, and Australian
Regulations for the Control of Workplace Hazardous Substances.
(For Section 2 footnotes: See Section 15)

Section 3

Hazards Identification

EMERGENCY OVERVIEW: None.
POTENTIAL HEALTH EFFECTS
Primary Exposure Routes: Not Applicable.
Acute Effects
Eyes: Not Applicable.
Skin: Not Applicable.
Ingestion: Not Applicable.
Inhalation: Not Applicable.
Chronic Effects
Eyes: Not Applicable.
Skin: Not Applicable.
Ingestion: Not Applicable.
Inhalation: Not Applicable.
Carcinogenicity: Not Applicable.
Target Organ Effects: Not Applicable.
Medical Conditions Aggravated by Long-Term Exposure: Not Determined.
Other Information: Not Applicable.

Page 1 of 5

%

Product Name:
Revision #: 2.0

BLOC-IT Heat Sink Paste
Date Prepared: May 23, 1991

Section 4

Date Revised: June 14, 2004

First Aid

Eye Contact: Flush with water.
Skin Contact: Rinse with water.
Ingestion: Not Applicable.
Inhalation: Not Applicable.
Other Information: Not Applicable.

Section 5

Fire Fighting Measures

Flash Point (method): Not Applicable.
Autoignition Temperature: Not Applicable.
LEL: Not Applicable. UEL: Not Applicable.
Flammability Classification: Not Applicable.
Extinguishing Media: Not Applicable.
Hazardous Combustion Products: Possibly carbon monoxide.
Unusual Fire or Explosion Hazards: Not Applicable.
Fire-Fighting Instructions/Equipment: Keep personnel removed and upwind of any fire. Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA).

Section 6

Accidental Release Measures

Use recommended personal protective equipment (see Section 8).
Spill: CAUTION: Spill area may be slippery. Scrape up bulk. Mop spill area with water.

Section 7

Handling and Storage

Handling Precautions: Use recommended personal protective equipment (see Section 8). Wash
thoroughly after handling.
Storage Requirements: Store away from incompatible chemicals (see Sec. 10). Store in a cool, dry
area.

Section 8

Exposure Controls/Personal Protection

Eye/Face Protection: Suitable for related activities where this product is used.
Skin/Hand Protection: Suitable for related activities where this product is used.
Respiratory Protection: Suitable for related activities where this product is used.
Other Equipment: Eye wash and safety shower. Suitable for related activities where this product is
used.
Engineering Controls: Suitable for related activities where this product is used.
Administrative Controls: Users of this product must be properly trained and qualified in its use.
Other Information: No food or beverage should be consumed in the work area. Wash thoroughly before
eating, drinking, or smoking.

Section 9

Physical and Chemical Properties

Appearance/Physical State: Light pink to beige paste.
Odor: Negligible.
Odor Threshold (ppm): Not Determined.
Specific Gravity (H2O = 1): 1.0 to 1.1
Page 2 of 5

Product Name:
Revision #: 2.0

BLOC-IT Heat Sink Paste
Date Prepared: May 23, 1991

Date Revised: June 14, 2004

Solubility - Water: Soluble
- Fat: Insoluble
Coefficient of Water/Oil Solubility: >>1
Partition Coefficient (n-octanol/water): <<1
pH: Neutral
Melting Point: Not Determined.
Boiling Point: 2120F/1000C
Vapor Pressure (mm Hg at 200C): Not Determined.
Vapor Density (Air = 1): Not Determined.
Evaporation Rate (n-BuAc=1): <1
V.O.C.: 0%(w/w), 0%(v/v), 0 lbs./gal.(U.S.), 0 kg/l
Flash Point (method): (see Section 5)
Autoignition Temperature: (see Section 5)
Flammability Classification: (see Section 5)
Unusual Fire or Explosion Hazards: (see Section 5)
Oxidizing Properties: Not Applicable.
Other Information: None.
Note: The physical data represented above are typical values and should not be construed as a
specification.

Section 10

Stability and Reactivity

Chemical Stability: Stable
Hazardous Polymerization: Will Not Occur
Conditions to Avoid: Not Applicable.
Chemicals to Avoid: Not Determined.
Hazardous Decomposition Products (non-thermal): Not Applicable.

Section 11

Toxicological Information

Sensitization to Product: Not Applicable.
Irritancy of Product: Not Applicable.
Reproductive Toxicity: Not Applicable.
Teratogenicity: Not Applicable.
Mutagenicity: Not Applicable.
Further hazard information, if applicable, may be found in Section 3. Toxicological information regarding
individual ingredients, if applicable, may be found in Section 2.

Section 12

Ecological Information

Mobility: Not Determined.
Degradability: Not Determined.
Accumulation: Not Determined.

Section 13

Ecotoxicity: Not Determined.
Other Adverse Effects: Not Determined.

Disposal Considerations

Dispose of in accordance with all applicable regulations.

Page 3 of 5

Product Name:
Revision #: 2.0

Section 14

BLOC-IT Heat Sink Paste
Date Prepared: May 23, 1991

Date Revised: June 14, 2004

Transport Information

D.O.T. (U.S.)
Proper Shipping Name: Not Regulated.
Hazard Class or Division: Not Regulated.
Hazard Label: Not Regulated.
I.D. Number: Not Regulated.
TDG (Canada): Not Regulated.
IATA: Not Regulated.
ICAO: Not Regulated.
IMO: Not Regulated.
Australian Code for the Transport of Dangerous Goods
Dangerous Goods Class and Subsidiary Risk: Not Regulated.

Section 15

Regulatory Information

Footnotes for Section 2:
1
2
3
4
5
6

Subject to the reporting requirements of SARA Title III, Section 313.
Appears on the California Safe Drinking Water and Toxic Enforcement Act (Prop. 65) Substances List.
Appears on the Massachusetts Substances List.
Appears on the New Jersey Right-To-Know Hazardous Substances List.
Appears on the Pennsylvania Hazardous Substances List.
Appears on the Canadian WHMIS Ingredient Disclosure List.

U.S.A.
OSHA Hazard Status: This product is not considered to be hazardous as defined by the U.S. OSHA
HCS (29 CFR 1910.1200).
EPA SARA sec. 311/312 Hazard Categories: Not Applicable.
Toxic Substances Control Act (TSCA): All ingredients contained in this product are listed on the U.S.
EPA TSCA Chemical Substance Inventory.
HMIS Rating: Health 0, Flammability 0, Reactivity 0
NFPA Rating: Health 0, Flammability 0, Reactivity 0
CANADA
WHMIS Status: This product is not considered to be hazardous as defined by Canadian WHMIS
Controlled Products Regulations.
WHMIS Rating: None.
WHMIS Risk Phrases: None.
WHMIS Precautionary Statements: None.
Domestic Substances List (DSL): All ingredients contained in this product are listed on the Canadian
EPA (CEPA) Domestic Substances List (DSL).
E.U.
European Inventory of Existing Chemical Substances (EINECS): All ingredients contained in this
product are listed on the European Inventory of Existing Chemical Substances (EINECS).
Categories of Danger (Labeling Information): None.
Risk (R) Phrases: None.
Safety (S) Phrases: Keep out of reach of children (S2
AUSTRALIA
Worksafe Australia Status: This product is not classified as hazardous according to criteria of
Worksafe Australia.
HAZCHEM Code: None allocated.
Poisons Schedule Number: None allocated.

Page 4 of 5

Product Name:
Revision #: 2.0

BLOC-IT Heat Sink Paste
Date Prepared: May 23, 1991

Date Revised: June 14, 2004

Further regulatory information regarding individual ingredients, if applicable, may be found in Section 2.
This product has been classified in accordance with the hazard criteria of the U.S. OSHA Hazard
Communication Standard, the Canadian WHMIS Controlled Products Regulations, the British CHIP2
regulation 6, and the Australian NMRCWHS. This MSDS contains the information required by the above
regulations and conforms to ANSI Z400.1-1993.

Section 16

Other Information

MSDS Prepared By: Director of Chemical Safety

The information contained herein is based on data available to us and is accurate and
reliable to the best of our knowledge and belief. However, LA-CO Industries, Inc. makes
no representations as to its completeness or accuracy. Information is supplied on
condition that persons receiving such information will make their own determination as
to its suitability for their purposes prior to use. In no event will LA-CO Industries, Inc. be
responsible for damages of any nature whatsoever resulting from the use of or reliance
upon the information contained herein.

Page 5 of 5

MATERIAL SAFETY DATA SHEET
S O S PRODUCTS COMPANY INC
4th and Railroad Streets
East Greenville, Pa.
18041
Phone (215-679-6262
(215)-679-6263
PAGE 1
----------------------------------------------------------------------------SECTION I - GENERAL INFORMATION
----------------------------------------------------------------------------Product Code:
PVCC
Revision Date:08/06/07
Identification:
PVC CEMENT MEDIUM BODY
----------------------------------------------------------------------------SECTION II - HAZARDOUS INGREDIENTS
----------------------------------------------------------------------------OSHA
ACG/H
RATING
INGREDIENT:
PEL
TLV
H-F-R
CAS. NO
----------------------------------------------------------------------------TETRAHYDROFURAN
200 PPM
200 PPM
2-3-1
109-99-9
*METHYL ETHYL KETONE
200 PPM
200 PPM
1-3-0
78-93-3
CYCLOHEXANONE
25 PPM
25 PPM
1-2-0
108-94-1
*ACETONE
750 PPM
750 PPM
1-3-0
67-64-1
----------------------------------------------------------------------------*SUBJECT TO REPORTING REQUIREMENTS OF SARA TITLE III SECTIION 313.
----------------------------------------------------------------------------Carcinogenicity:
This product is NOT considered to be a carcinogen by the
National Toxicology Program, the International Agency for
Research on Cancer, or the Occupational Safety and Health
Administration.
----------------------------------------------------------------------------SECTION III - PHYSICAL CHARACTERISTICS
----------------------------------------------------------------------------Boiling Point:
133 F
Specific Gravity: (Water = 1)
0.91
Vapor Pressure: (mm Hg) 182
Melting Point:
N/A
Vapor Density:
(Air = 1) 2.5
Evaporation Rate:
8
Solubility in Water: NIL
(Butyl Acetate = 1)
Odor and Appearance: COLORED LIQUID, ACETONE-LIKE ODOR
----------------------------------------------------------------------------SECTION IV - FIRE AND EXPLOSION HAZARD DATA
----------------------------------------------------------------------------Flash Point:
-4 F
LEL:
2%
Flammable Limits:
N/A
UEL:
13%
Extinguishing Media: DRY CHEMICAL OR CARBON DIOXIDE OR FOAM.
Special Fire Fighting Procedures: DIRECT EXTINGUISHER AT BASE OF FLAMES.
Unusual Fire and Explosion Hazards: VAPOR HEAVIER THAN AIR & MAY TRAVEL
ALONG FLOOR OR GROUND TO IGNITION SOURCES FROM USE AREA.
----------------------------------------------------------------------------SECTION V - REACTIVITY DATA
----------------------------------------------------------------------------This product is STABLE.
Conditions to avoid: KEEP IN CLOSED CONTAINERS, AWAY FROM SPARKS &/OR FLAME.
Incompatibility: STRONG OXIDIZERS.
Hazardous Decomposition: CARBON DIOXIDE, CARBON MONOXIDE, HYDROGEN CHLORIDE.
Hazardous Polymerization: WILL NOT OCCUR.

----------------------------------------------------------------------------SECTION VI - HEALTH HAZARD DATA
PAGE 2
----------------------------------------------------------------------------Routes of Entry:
Inhalation?
YES - PRIMARY
Skin?
YES - PRIMARY
Ingestion?
YES - SECONDARY
Health Hazards (Acute and Chronic):
BREATHING: EXCESSIVE INHALATION CAN CAUSE NASAL &
RESPIRATORY IRRITATION & CENTRAL NERVOUS SYSTEM DEFECTS.
SKIN: PROLONGED OR REPEATED CONTACT CAN CAUSE MODERATE
IRRITATION, BURNS IF NOT REMOVED. CHRONIC OVEREXPOSURE
HAS APPARANTLY BEEN FOUND TO CAUSE THE FOLLOWING EFFECTS
IN LAB ANIMALS: LIVER ABNORMALITIES, KIDNEY, LUNG, &
BRAIN DAMAGE.
Carcinogenicity:
NTP?
NO
IARC Monographs?
NO
OSHA Regulated?
NO
Signs and Symptoms of Exposure:
INHALATION: DIZZINESS, HEADACHE, NAUSEA.
SKIN: IRRITATION, DEFATTING.
EYES: IRRITATION, REDNESS.
Medical Conditions Generally Aggravated by Exposure: NO INFORMATION AVAILABLE.
Emergency and First Aid Procedures:
INHALATION: REMOVE TO FRESH AIR. SKIN: FLUSH WITH WATER
& REMOVE CONTAMINATED CLOTHING. EYES: FLUSH REPEATEDLY
WITH WATER.
----------------------------------------------------------------------------SECTION VII - HANDLING PRECAUTIONS
----------------------------------------------------------------------------Steps to be Taken if Material is Released or Spilled:
ELIMINATE IGNITION SOURCES, FLAMES, PILOT LIGHTS & TURN
OFF ELECTRIC MOTORS. ABSORB LIQUID ON RAGS OR PAPER
TOWELS & REMOVE TO OUTDOORS. VENTILATE AREA.
Waste Disposal Method: DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, LOCAL
REGULATIONS.
Precautions to be Taken in Handling and Storage:
STORE IN COOL AREA AWAY FROM PILOT LIGHTS &
IGNITION SOURCES.
Other Precautions: KEEP CONTAINER CLOSED WHEN NOT IN USE.
----------------------------------------------------------------------------SECTION VIII - CONTROL MEASURES
----------------------------------------------------------------------------Respiratory Protection:
USE NIOSH APPROVED RESPIRATOR IF TLV EZPOSUER LIMITS ARE
EXCEEDED.
Ventilation Required: LOCAL EXHAUST: OPEN DOORS & WINDOWS. USE ONLY IN
A WELL-VENTILATED AREA. USE MECHANICAL EXHAUST IF
NECESSARY TO MAINTAIN EXPOSURE BELOW TLV.
Protective Gloves: WEAR RUBBER GLOVES IF EXCESSIVE SKIN CONTACT MAY OCCUR.

Eye Protection:
WEAR EYE PROTECTION IF SPLASHING OF PRODUCT IS LIKELY.
Other Protective Equipment: NONE.
Work/Hygienic Practices: WASH THOROUGHLY AFTER HANDLING.
----------------------------------------------------------------------------The above information pertains to the product as it is currently formulated
and is based upon the information available at this time. Additions of
reducers or other additives to this product may substantially alter the
composition and subsequent hazards of the product. Since conditions of use
are outside of our control, we make no warranties, either expressed or
implied, and assume no liability in connection with any use of this
information.

Silicone Grease

IMS Company
Validation Date: January 13, 2012

Page 1 of 3

Material Safety Data Sheet

Section 1 - Manufacturer Information
Manufacturer/Distributor

IMS Company
10373 Stafford Road
Chagrin Falls, OH 44023-5296
WEB: http://www.imscompany.com

Emergency Phone #
800-424-9300
Prepared by
Safety Advisor
Prepared/Revised
February 28, 2007
Sales:
sales@imscompany.com

Trade Names ...........Silicone Grease
Part Numbers ...........100585
100586
100830

1 gallon can
5.3 ounce tube
2 ounce tube

Replaces AER1-G128-G
Replaces AER1-G053-T
Replaces STXX-SG2

Hazardous Material Information System
Health ................1
Flammability.............1
Reactivity ................. 0
Protection................. X
* Chronic (Accumulates)
0 Normal use Material
0 Will Not Burn
0 Stable
X = Consult the
1 Slight Hazard (temporary) 1 Possible to Burn
1 Unstable if Heated
MSDS and
2 Health Affected (lengthy) 2 Burns if Heated
2 Violent Chemical Change
your supervisor
3 Extreme Danger
3 Easily Burns
3 Shock and Heat Sensitive
for your special
4 Severe or Fatal
4 Very Easily Burns
4 May Explode
workplace need
NOTE The HMIS may not be enough hazard information for this chemical in all workplaces. The HMIS system
requires employee training about the system and about information in this MSDS.

Section 2 - Ingredients
Chemical/Common Name

CAS-Number

%

PEL-OSHA

Silica, Amorphous Fumed
Polydimethylsiloxane
Dimethyl Siloxane, hydro-terminated

7631-86-9
63148-62-9
70131-67-8

0.1 to 20
60 to 80
0.1 to 10

6 mg/m3

(1)
(2)

TLV-ACGIH
TWA 10 mg/m3 (2)

(1)

(1)

(1)

(1)

None Established
Total dust

Does this product contain carcinogens (NTP, IARC, or OSHA)? No

Section 3 - Health Data
HEALTH EFFECTS - (Acute and Chronic)
Ingestion

low ingestion hazard in normal use. Large amounts may cause digestive discomfort, but no known
injury.

Inhalation

No significant effects expected from a single short-term exposure.

Eye

Direct contact could cause temporary discomfort with mild redness and dryness similar to windburn.

Skin

No significant irritation expected from a single short-term exposure.

PRIMARY ROUTES OF ENTRY Inhalation, Skin
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
No known applicable information.
EMERGENCY FIRST AID PROCEDURES

IMS Company
Validation Date: January 13, 2012
Eye Contact

Silicone Grease

Page 2 of 3

Material Safety Data Sheet

Immediately flush thoroughly with water.

Skin Contact Wipe off and flush with water.
Inhalation

No first aid should be needed.

Ingestion

No first aid should be needed.

Section 4 - Chemical Data
Boiling Point (F)................................ > 95° F (35° C)
Vapor Pressure (PSIG) .................... NA
Vapor Density (Air=1) ....................... NA
Solubility in Water............................. NA

Specific Gravity (Water=1) ...................... 1.1
Percent Volatile by Weight (%)................NA
Evaporation Rate (Ether).........................NA
Viscosity ..................................................500,000 cSt

Appearance and Odor Information Viscous liquid (paste-like), translucent white, some odor

Section 5 - Physical Data
Flash Point (CC) ................................. > 214° F (101° C)

Flammable Limits ............... LEL = NA

UEL = NA

Extinguishing Media Water spray, water fog, carbon dioxide, dry chemical, foam.
Special Fire Fighting Procedures Self-contained breathing apparatus and protective clothing should be worn in
fighting fires involving chemicals. Determine the need to evacuate or isolate the area according to your local
emergency plan. Use water spray to keep exposed containers cool.
Unusual Fire and Explosion Hazards None known.
Incompatibility (Materials to Avoid) Oxidizing material can cause a reaction.
Hazardous Decomposition Products Silicon Dioxide, Carbon oxides, traces of incompletely burned carbon
products, formaldehyde.
NOTICE
This product contains methylpolysiloxanes, which when heated to temperatures above 300° F (150° C), in the
presence of air, can form formaldehyde vapors. Formaldehyde is a potential cancer hazard, a known skin and
respiratory sensitizer, eye and throat irritant, and an acute toxicant. Vapors irritate eyes, nose, and throat. Safe
handing conditions may be maintained by keeping vapor concentrations within the OSHA permissible exposure limit
for formaldehyde. (Note Product does not contain formaldehyde).
Will Hazardous Polymerization Occur? No
Conditions to Avoid for Polymerization NA
Is the Product Stable? Yes
Conditions to Avoid for Stability NA

Section 6 - Spill or Leak Procedures
Steps to be Taken in Case Material is Released or Spilled Small spill and general procedure; remove product
and use absorbent material to take care of any oil-like residues. Large and unusual conditions; determine whether to
evacuate or isolate the areas according to your local emergency plan. Observe all personal protective equipment
recommendations. For large spills, provide diking or other appropriate containment to keep material from spreading.
Clean up remaining materials as appropriate since silicone materials, even in small quantities, present a slip hazard.

IMS Company
Validation Date: January 13, 2012

Silicone Grease

Page 3 of 3

Material Safety Data Sheet

Final cleaning may require use of steam, solvents, or detergents. Dispose of saturated absorbent or cleaning
materials in a sealed container, or totally exposed to air, since spontaneous heating – combustion may occur.
Waste Disposal Methods Not classified as a hazardous waste. If uncontaminated, use as appropriate. If not
useable, mix with absorbent materials such dried clay or absorbent pads, or set out to harden in open air – may take
a long time, and send to landfill. Follow local, State and Federal disposal procedures.

Section 7 - Exposure Control Information
Ventilation No local exhaust should be needed. Mechanical (general) ventilation recommended.
Respiratory Protection None should be needed if not sprayed. If sprayed, use appropriated mist respirator.
Consult with your safety equipment supplier.
Protective Gloves Where prolonged or repeated contact with the spray mist or the deposited product is likely, the
use of impervious gloves (for example neoprene or nitrile) is indicated.
Other Protective Equipment If contact with the material in any manner is likely, eye protection is recommended.
Chemical Monogoggles or safety glasses with side shields and a face shield will provide protection in most
situations. Do not wear contact lenses.
Other Engineering Controls To determine exposure levels, monitoring should be performed
Work Practices Do not use in confined or closed space. Ventilation should maintain the concentration of the
product or its components below the TLV/PEL value.
Hygienic Practices Wash thoroughly before eating or smoking after using this or any chemical product. This
product transferred to a lighted cigarette will result in the hazardous decomposition products. It is good practice to
remove large amount of any chemical from the skin as soon as practical.

Section 8 - Special Precautions
Precautions to be Taken in Handling and Storage Avoid spreading onto red hot surfaces, which may cause
decomposition.
Maintenance Precautions Do not remove or deface label.
Additional Comments
CAUTION Intentional misuse of this chemical product, as with any industrial chemical, in contact with the
body can be harmful or fatal. This includes such things as deliberately breathing, placing in mouth,
swallowing, placing on skin, or any other body contact, or repeated, or continuous contact.
IMS provides this information in good faith, but makes no representation as to its comprehensiveness or its accuracy.
This document is offered as a guide to a trained person, for appropriate precautionary handling. Persons using the
product and receiving the information must exercise independent judgment in determining the appropriateness of the use
and the safety information for their particular purpose. IMS MAKES NO REPRESENTATIONS OR WARRANTIES,
EXPRESSED OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THIS INFORMATION OR TO THE PRODUCT.
ACCORDINGLY, IMS WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE ON
THIS INFORMATION.

MATERIAL SAFETY DATA SHEET
S O S PRODUCTS COMPANY INC
P. O. Box 47
East Greenville, Pa.
18041
Phone (215)-679-6262
(215)-679-6263

Product Code:

SECTION I
TFD

-

PAGE 1

GENERAL INFORMATION
Revision Date: 08/06/07

SECTION II - HAZARDOUS INGREDIENTS
This product is not classified as hazardous in accordance with OSHA 1910.1200
Carcinogenicity: This product is NOT considered to be a carcinogen by the
National Toxicology Program, the International Agency for Research on
Cancer, or the Occupational Safety and Health Administration.
SECTION III - PHYSICAL CHARACTERISTICS
Boiling Point: N/A
Specific Gravity: 1.55
Vapor Pressure: N/A
Melting Point:
N/A
Vapor Density: N/A
Evaporation Rate: N/A
N/A
Evaporation Rate:
N/A
Solubility in Water: NOT SOLUBLE
Odor and Appearance: WHITE PASTE WITH PLEASANT ODOR
SECTION IV
Flash Point: N/A
Flammable Limits:

N/A

Extinguishing Media:

-

FIRE AND EXPLOSION HAZARD DATA
LEL: N/A
UEL: N/A

DRY CHEMICAL, FOAM, CARBON DIOXIDE

Special Fire Fighting Procedures:
USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
Unusual Fire and Explosion Hazards:

TOXIC FUMES GIVEN OFF ABOVE 800 DEG F.

SECTION V - REACTIVITY DATA
This product is STABLE.
Conditions to avoid: DIRECT CONTACT WITH OPEN FLAME.
Incompatibility:
SODIUM POTASSIUM ALLOY
Hazardous Decomposition: FLUOROCARBON GASES PRESENT IN TEFLON DECOMPOSITION
Hazardous Polymerization WILL NOT OCCUR.

Routes of Entry:

SECTION VI - HEALTH HAZARD DATA
Inhalation?
NO
Skin?
YES - PRIMARY
Ingestion?
YES - SECONDARY

Health Hazards (Acute and Chronic):
Carcinogenicity:

NONE

NTP?
IARC Monographs?
OSHA Regulated?

Signs and Symptoms of Exposure:

NONE

NO
NO
NO

Medical Conditions Generally Aggravated by Exposure:

NONE KNOWN

Emergency and First Aid Procedures:
SKIN: WASH WITH SOAP & WATER THOROUGHLY.
EYES: FLUSH 15 MINUTES WITH WATER.
INGESTION: DO NOT INDUCE VOMITING. CALL PHYSICIAN.
SECTION VII - HANDLING PRECAUTIONS
Steps to be Taken if Material is Released or Spilled:
USE ABSORBENT MATERIAL & SWEEP UP.
Waste Disposal Method:
NON-HAZARDOUS LANDFILL.
REGULATIONS.

COMPLY WITH FEDERAL, STATE AND LOCAL

Precautions to be Taken in Handling and Storage:
Other Precautions:

NONE

KEEP AWAY FROM DIRECT CONTACT WITH SPARKS & OPEN FLAME.

SECTION VII - CONTROL MEASURES
Respiratory Protection: NONE REQUIRED FOR NORMAL USE.
Ventilation Required: NORMAL VENTILATION
Protective Gloves: WEAR RUBBER GLOVES
Eye Protection: WEAR SAFETY GOGGLES
Other Protective Equipment: NONE REQUIRED FOR NORMAL USE.
Work/Hygienic Practices: WASH THOROUGHLY WITH SOAP & WATER AFTER USING.

The above information pertains to the product as it is currently formulated
and is based upon the information available at this time. Additions of reducers
or other additives to this product may substantially alter the composition and
subsequent hazards of the product. Since conditions of use are outside of our
control, we make no warranties, either expressed or implied, and assume no
liability in connection with any use of this information.

MSDS No:
Issue Date:
Page:

OTH050E5
10 June 2005
1 of 4

MATERIAL SAFETY DATA SHEET
SECTION 1
PRODUCT AND COMPANY IDENTIFICATION
Trade Name:
OATEY PLUMBER’S PUTTY
Product Use:
Stainless fixture setting compound.
Formula:
See SECTION 2
Synonyms:
Putty.
Firm Name &
OATEY CO. 4700 West 160th Street P.O. Box 35906 Cleveland,
Mailing Address:
Ohio 44135, U.S.A.
http://www.oatey.com
Oatey Phone Number: (216) 267-7100 or (800) 321-9532
Emergency Phone
For Emergency First Aid call 1-303-623-5716 COLLECT. For
Numbers:
chemical transportation emergencies ONLY, call Chemtrec at
1-800-424-9300. Outside the US: 1-703-527-3887.
Prepared By:
Corporate Director – Safety and Environmental Compliance
Preparation Date:
June 10, 2005
SECTION 2
INGREDIENTS:
Limestone
Hydrocarbon oil
Talc
Clay

COMPOSITION/INFORMATION ON INGREDIENTS
%wt/wt:
CAS NUMBER: ACGIH TLV TWA: OSHA PEL TWA:
60 - 90% 1317-65-3
10 mg/M3
15 mg/M3
(Total dust)
10 - 30% 64742-52-5
5 mg/M3
5 mg/M3
1 - 5%
14807-96-6
2 mg/M3
2 mg/M3
1 – 5%
68953-58-2
10 mg/M3
10 mg/M3

OSHA Hazard Classification:

OTHER:
None
None
None
None

Not hazardous

SECTION 3
HAZARDS IDENTIFICATION
Emergency Overview:
White putty with a mild petroleum odor. May cause mechanical irritation of the eyes.
SECTION 4

FIRST AID MEASURES
CALL 1-303-623-5716 COLLECT
Skin:
Wash all exposed areas with soap and water.
Eyes:
As with most foreign materials, should eye contact occur, flush eyes
with water until foreign matter is removed. If irritation develops,
seek medical attention.
Inhalation: Not a likely route of entry.
Ingestion: DO NOT INDUCE VOMITING. Rinse mouth with water. Call a physician.
SECTION 5
FIRE FIGHTING MEASURES
Flashpoint / Method: Not applicable
Flammability:
LEL = Not determined, UEL = Not determined
Extinguishing
Use dry chemical, CO2, or foam to extinguish fire. Cool fire
Media:
exposed container with water. Water may be ineffective as an
extinguishing agent.
Special Fire
As appropriate for surrounding fire.
Fighting
Procedure:
Unusual Fire and
None
Explosion
Hazards:
Hazardous
Combustion will produce toxic and irritating vapors including
Decomposition
carbon monoxide and carbon dioxide.
Products:

MSDS No:
Issue Date:
Page:

OTH050E5
10 June 2005
2 of 4

SECTION 6
Spill or
Leak
Procedures:

ACCIDENTAL RELEASE MEASURES
Sweep up dried material and dispose of with ordinary trash.

SECTION 7
Handling:

HANDLING AND STORAGE
No special handling required.
Use good hygiene practices.
Store in a cool, dry area.
None.

Storage:
Other:
SECTION 8
Ventilation:
Respiratory
Protection:
Skin
Protection:
Eye
Protection:
Other:

Wash thoroughly after handling.

EXPOSURE CONTROLS/PERSONAL PROTECTION
Use with adequate ventilation.
If putty dries and becomes dusty, wear a dust respirator
during clean-up.
Gloves are not normally required.
Safety glasses with side shields are recommended.
Eye wash should be available.

SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point:
Not applicable
Melting Point:
Not applicable
Vapor Pressure:
Not determined
Vapor Density:
Not determined
Volatile Components: Not determined
Solubility In Water: Negligible.
pH:
Not applicable
Specific Gravity:
2.0 @ 20 Degrees C
Evaporation Rate:
Not applicable
Appearance:
White Putty
Odor:
Petroleum odor
Will Dissolve In:
Not determined
Material Is:
Putty
SECTION 10
STABILITY AND REACTIVITY
Stability:
Stable.
Conditions To Avoid: Avoid heat, flames and other sources of ignition.
Hazardous
Combustion will produce toxic and irritating vapors
Decomposition
including carbon monoxide and carbon dioxide.
Products:
Incompatibility/
Strong oxidizing agents.
Materials To Avoid:
Hazardous
Will not occur.
Polymerization:

MSDS No:
Issue Date:
Page:
SECTION 11
Inhalation:
Skin:
Eye:
Ingestion:
Chronic
Toxicity:
Toxicity Data:
Sensitization:
Carcinogenicity:
Mutagenicity:
Reproductive
Toxicity:
Medical
Conditions
Aggravated By
Exposure:
SECTION 12
VOC
Information:

OTH050E5
10 June 2005
3 of 4

TOXICOLOGICAL INFORMATION
Not a likely route of entry.
May cause mild irritation. Prolonged and repeated contact
may cause dermatitis.
Contact may cause irritation.
Swallowing may cause a laxative effect including cramps and
diarrhea.
Prolonged or repeated overexposure cause dermatitis.
Not available
None of the components are
None of the components are
carcinogen by NTP, IARC or
None of the components are
None of the components are

known to cause sensitization.
listed as a carcinogen or suspect
OSHA.
known to be mutagenic.
known to be toxic to reproduction.

None known.

ECOLOGICAL INFORMATION
No ecotoxicological information known.
This product has very low VOC level.

SECTION 13
DISPOSAL CONSIDERATIONS
Waste Disposal: Dispose in accordance with current local, state and federal
regulations.
RCRA Hazardous Waste Number:
Not a hazardous waste.
EPA Hazardous Waste ID Number: Not a hazardous waste.
EPA Hazard Waste Class: Not a hazardous waste.
SECTION 14
TRANSPORT INFORMATION
Less than 1 Liter (0.3 gal) Greater than 1 Liter (0.3 gal)
DOT
Proper Shipping Name:
Not regulated.
Not regulated.
Hazard Class/Packing Group: None
None
UN/NA Number:
None
None
Hazard Labels:
None
None
IMDG
Proper Shipping Name:
Not regulated
Hazard Class/Packing Group: None
UN Number:
None
Label:
None
2004 North American Emergency Response Guidebook Number: None

MSDS No:
Issue Date:
Page:

OTH050E5
10 June 2005
4 of 4

SECTION 15
REGULATORY INFORMATION
Hazard Category for Section
Not hazardous.
Section 302 Extremely
This product does not contain chemicals regulated
Hazardous Substances (TPQ):
under SARA Section 302.
Section 313 Toxic Chemicals: This product does not contain any chemicals regulated
under SARA Title III Section 313.
CERCLA 103 Reportable
This product does not contain any chemicals regulated
Quantity:
under CERCLA.
California Proposition 65:
This product does not contain any chemicals subject
To California Proposition 65 regulation.
TSCA Inventory:
All of the components of this product are listed on
the TSCA inventory.
Canadian WHIMS Classification:
Not a controlled product.
This product has been classified in accordance with
the hazard criteria of the Controlled Products
Regulations (CPR) and the MSDS contains all the
information required by the CPR.
SECTION 16
OTHER INFORMATION
NFPA and HMIS:
NFPA Hazard Signal: Health: 0
Flammability: 0
HMIS Hazard Signal: Health: 0
Flammability: 0

Reactivity: 0
Reactivity: 0

Special: None
PPE: A

Disclaimer:
The information herein has been compiled from sources believed to be reliable, upto-date, and is accurate to the best of our knowledge. However, Oatey cannot give
any guarantees regarding information from other sources, and expressly does not make
warranties, nor assumes any liability for its use.

MATERIAL SAFETY DATA SHEET
POWER O PRODUCTS
6 - HEALTH HAZARD DATA

1 - IDENTIFICATION
Manufacturer:
Address:
City, State, Zip:
Telephone:
24-Hour Emergency:
Date Prepared:

Ormco Corporation
1717 West Collins Avenue
Orange, CA 92867
1-800-854-1741
Chemtrec 1-800-424-9300
September 24, 2001

Routes of Entry:
Skin: None known
Eyes: May cause mechanical irritation and damage.
Inhalation: N/A
Ingestion: N/A
Carcinogenicity NTP: No
IARC Monographs: No
OSHA Regulated Carcinogen: No

2 - COMPOSITION INFORMATION
7 - EMERGENCY FIRST AID PROCEDURES
Hazardous Ingredients
This product contains no hazardous components as defined in the
OSHA Hazard Communication Standard ( 29 CFR 1910.1200 ).
Other Ingredients
Polyurethane elastomer

3 - PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point: N/D
Specific Gravity (H20 = 1): N/D
Vapor Pressure (mm Hg): N/D
Vapor Density (AIR = 1): N/D
Freezing/Melting Point: N/D
Solubility in Water: N/D
Appearance and Odor: Clear or colored elastomer material with no
odor

Skin: N/A
Eyes: N/A
Inhalation: N/A
Ingestion: N/A

8 - PRECAUTIONS FOR SAFE HANDLING & USE
Steps to be taken in case material is released or spilled: N/A
Waste Disposal Method: Dispose of properly in accordance with all
federal, state and local regulations.
Precautions to be taken in handling and storing: Store in a cool and
dry place away from heat and light.

9 - CONTROL MEASURES

Flash Point (Method Used): N/D
Flammable Limits: LEL: N/D UEL: N/D
Extinguishing Media: Chemical foam, CO2 or dry chemical
Special Fire Fighting Procedures: Wear a self-contained breathing
apparatus.
Unusual Fire and Explosion Hazards: N/A

Respiratory Protection: N/A
VENTILATION:
Local Exhaust: N/A
Mechanical (General): N/A
Protective Gloves: Not required
Eye Protection: Safety glasses recommended.
Work/Hygiene Practices: Handle in accordance with good personal
hygiene and safety practices. These practices include avoiding
unnecessary exposure to uncured material. Avoid contamination of
food.

5 - REACTIVITY DATA

10 - TRANSPORTATION INFORMATION

Stability: Stable if stored as directed.
Conditions to Avoid: Heat, light, aging and contamination
Incompatibility (Material to Avoid): N/A
Hazardous Decomposition Byproducts: Oxides of carbon
Hazardous Polymerization: Will not occur

Not DOT regulated.

4 - FIRE AND EXPLOSION HAZARD DATA

11 - SPECIAL INFORMATION
HMIS (Hazardous Material Identification System) Rating:
H0 F0 R0-Safety glasses
[HMIS Hazard Index: 4 – Severe Hazard; 3 – Serious Hazard;
2 – Moderate Hazard; 1 – Slight Hazard; 0 – Minimum Hazard]

Note: This MSDS was prepared in accordance with the requirements of the OSHA Hazard Communication Standard (29 CFR 1910.1200) and is
to be used only for this product. The information contained in this MSDS is, to the best of our knowledge, believed to be accurate.

NFPA Hazard Rating
Flammability

0
0

Health

MATERIAL SAFETY DATA SHEET
L-82E

0

Reactivity

0 = Minimum 1 = Light 2 = Moderate 3 = Serious 4 = Extreme

Section 1 - Product Identification
Bio-Chem Surface Technology

Trade name:

Gold Matrix All Purpose

5977 Transcanada Highway
Pointe-Claire, Quebec
H9R 1C1
Emergency: CANUTEC (613) 996-6666

Product name:
Order no.:
WHMIS Classification:
Controlled under WHMIS:

Industrial cleaner/degreaser
53-G 603, 53-G 607, 53-G608
Non-hazardous
No

Section 2 - Hazardous Ingredients
Ingredients

CAS Number

% by Weight

LD50RAT

LC50RAT

No hazardous substances to declare.

Section 3 - Physical / Chemical Characteristics
Physical state:
pH:
Specific gravity:
Evaporation rate:

Liquid
12
1.00 g/ml @ 20ºC
N/Av

Odour & appearance:Lavender, blue
Boiling point:
98ºC
Vapour pressure:
N/Av
VOC g/l:
N/Av

Odour threshold: None
Freezing point: 0ºC
Vapour density: N/Av
Water solubility: Soluble

Section 4 - Fire & Explosion Hazard
Flammability: No
Flashpoint: N/A

Conditions: None

Auto ignition temperature: N/A
Flammable limits (%): Upper: N/A Lower: N/A

Extinguishing media: None
Hazardous combustion products: None
Sensitivity to mechanical impact or static discharge: No

Section 5 - Reactivity Data
Chemical stability: Yes
Conditions: None
Incompatible substances: Do not mix with other chemicals.
Hazardous decomposition products: None
N/A - Not Applicable

Reactivity conditions: None

N/Av - Not Available
Page 1 of 2

MATERIAL SAFETY DATA SHEET
L-82E
Section 6 - Toxicological Data
Route of entry: Eye and skin contact, ingestion.
Acute exposure effects: None
Chronic exposure effects: None
Exposure limits (TLV/TWA): N/Av
Carcinogenicity
Mutagenicity
Reproductive toxicity
No
No
No
If yes to any of the above, specify:

Teratogenicity
No

Synergistic effects
No

Section 7 - Preventive Measures
Protective equipment:
Handling procedures:
Waste disposal methods:
Leak/spill procedures:
Storage requirements:
Engineering controls:
Handling equipment:
Special shipping information:

Gloves in case of prolonged contact.
Keep container tightly closed.
Dispose as per municipal, provincial and federal regulations.
Soak up with absorbent material. Rinse small amount with quantity of water. Neutralize.
Store below 50ºC and above 0ºC. Keep upright.
None
None

Section 8 - First Aid Measures
Skin contact:
Eye contact:
Inhalation:
Ingestion:
Other:

Wash off with water and soap. Apply cream.
Rinse eyes thoroughly with water. Consult a physician.
N/A
Do not induce vomitting. Rinse mouth with water and give plenty of water to drink.
Consult a physician.

Section 9 - Preparation of MSDS
Prepared by:
Telephone:
Date:

Division Manager WCB
(514) 733-3315
June 21th, 2007

This data is offered in good faith as typical values and not as a product specification. No warranty, either express or implied is hereby made. The
recommended industrial hygiene and safe handling procedures are believed to bee generally applicable. However, each user should review these
recommendations in the specific context of the intended use and determine whether they are appropriate.

N/A - Not Applicable

N/Av - Not Available
Page 2 of 2

Material Safety Data Sheet
Section 1. Product and Company Identification
Product Name

PROFESSIONAL LYSOL® BRAND
DISINFECTANT FOAM CLEANER
(AEROSOL)

Product Description

Aerosol disinfectant cleaner for multiple surfaces.

Manufacturer

Reckitt Benckiser North America, Inc.
Morris Corporate Center IV
399 Interpace Parkway (P.O. Box 225)
Parsippany, N.J. 07054-0225

Product Identifier

EPA Reg. No. 777-71-675

Item Number

36241-02775-09

MSDS#

Not available.

Validation Date

9/1/2005

Print Date

9/1/2005

In case of
Emergency:

Telephone: 800-677-9218
(Professional Products)

Transportation
Emergencies:

Chemtrec: 1-800-424-9300
(U.S. & Canada)
Outside the U.S & Canada
(North America), call:
703-527-3887

Formula Number

(794-103) F/F 376360

UPC Number

36241-02775 (24 oz.)

Section 2. Composition and Information on Ingredients
Name

CAS #

1) DIETHYLENE GLYCOL MONOBUTYL
ETHER
2) ISOBUTANE

% by Weight

Exposure Limits : TLV/PEL

112-34-5

5.6

Not available.

75-28-5

7.0

Not available.

Section 3. Hazards Identification
Emergency Overview

CAUTION: May cause eye irritation. Avoid contact with eyes and skin. Contents under pressure. Do not
use or store near heat or open flame. Do not puncture or incinerate container. Exposure to temperature
above 55º C (130ºF) or in sun or discarding can in fire or incinerator may cause bursting. KEEP OUT OF
REACH OF CHILDREN.

Section 4. First Aid Measures
Eye Contact

In case of eye contact, hold eyes open and IMMEDIATELY rinse eyes thoroughly with plenty of water.
Remove any contact lenses and continue rinsing for at least 15 minutes. If irritation persists, consult a
physician.

Skin Contact

In case of skin contact, wash skin thoroughly with soap and water. If irritation persists, consult a physician.

Inhalation

Remove to fresh air.

Ingestion

Rinse mouth with water. Contact a physician or poison control center if symptoms develop. NEVER give an
unconscious person anything to ingest.

Continued on Next Page

PROFESSIONAL LYSOL® BRAND
DISINFECTANT FOAM CLEANER
(AEROSOL)

Page Number: 2

Section 5. Fire and Explosion Data
Flammability

See Section 14 for any Shipping Classifications.

Flash Point

Not applicable. Flame extension less than 18 inches or 45 cm.

Explosive Limits in Air

Not available.

Products of Combustion

Not available.

Fire and Explosion Hazards

CONTENTS UNDER PRESSURE. Do not use or store near hear or open flame. Do not puncture or
incinerate. Do not expose to heat or store at temperatures above 55º C (130º F) as container may burst.

Fire Fighting Media
and Instructions

Use water spray, foam, dry chemical or carbon dioxide, as suitable for surrounding fire.

Special Fire Fighting
Instructions

Wear self-contained breathing apparatus and protective clothing appropriate for fighting a typical chemical
fire. Move containers away from fire if possible and safe to do so. Use water spray to cool fire exposed
containers. Provide shielding for venting, rupturing or bursting containers.

Section 6. Accidental Release Measures
Accidental Spill

Small spills of liquid can be wiped up with a wet paper towel and residue may be flushed to sink or sanitary
sewer with water.
Large spills of liquid from ruptured cans: Eliminate all sources of ignition and ventilate the area with
equipment rated for use in flammable environments. Spilled liquid should be diked, contained, collected and
stored in metal containers for later disposal according to local, state or federal regulations.

Section 7. Handling and Storage
Handling and Storage

CAUTION: May cause eye irritation. Avoid contact with eyes or skin. Contents under pressure. Do not
store near heat or open flame.
Store container in a cool, dry area inaccessible to small children. Do not reuse empty container. Replace
cap and discard in trash. Do not incinerate or puncture. KEEP OUT OF REACH OF CHILDREN.
It is a violation of federal law to use this product in a manner inconsistent with its labeling.

Section 8. Exposure Controls/Personal Protection
Ventilation Requirements

None required.

Eye Protection

None required when used as recommended. Appropriate eye protection should be worn if the possibility of
eye contact exists. Emergency responders should wear eye protection.

Skin Protection

For sensitive skin or prolonged use, wear rubber gloves. Emergency responders should wear impermeable
gloves.

Respiratory Protection

None required.

Other Protection

None required. Emergency responders should wear impermeable clothing and footwear when responding
to a situation where contact with the liquid is possible.

Work/Hygienic Practices

Washing with soap and water after use is recommended as good hygienic practice to prevent possible skin
irritation and / or eye irritation from the residue that may be left on the hands.

Continued on Next Page

Page Number: 3

PROFESSIONAL LYSOL® BRAND
DISINFECTANT FOAM CLEANER
(AEROSOL)
Section 9. Physical and Chemical Properties
Description

Aerosol container. White foam when sprayed.

Odor

Not available.

pH

12.35 [Basic.]

Color

White foam when sprayed as an aerosol.

Boiling/Condensation Point

Not available.

Specific Gravity

1.007-1.036

Vapor Pressure

34-40 PSIG @ 70°F.

Vapor Density

>1 (concentrate)

Viscosity

Not available.

Solubility

Miscible

Physical Chemical Comments Not available.

Section 10. Stability and Reactivity Data
Chemical Stability

The product is stable.

Conditions of Instability

Temperatures above 130° F (55° C) which may cause aerosol container to rupture.

Incompatibility with Various
Substances

Oxidizing agents and acids.

Hazardous Decomposition
Products

Oxides of nitrogen and/or carbon and other unidentified organic compounds may be formed during thermal
decomposition.

Hazardous Polymerization

Will not occur.

Section 11. Toxicological Information

Exposure effects
Eye Contact

May cause eye irritation. Avoid contact with eyes.

Skin Contact

May cause skin irritation. Avoid skin contact.

Inhalation

None expected.

Ingestion

None expected.

Carcinogenicity

Not listed as carcinogenic by OSHA, NTP or IARC.

Section 12. Ecological Information
Ecotoxicity

Not available.

Continued on Next Page

Page Number: 4

PROFESSIONAL LYSOL® BRAND
DISINFECTANT FOAM CLEANER
(AEROSOL)
Section 13. Disposal Considerations
Waste Disposal

Dispose of in accordance with local, state and federal regulations. Container Disposal: Do not reuse empty
container. Replace cap and discard in trash.

Section 14. Transport Information
DOT Classification

ORM-D

Proper Shipping Name

Consumer Commodity

DOT Identification Number

Not applicable

Packing Group

Not applicable

Maritime Transportation

Not applicable.

Hazardous Substances
Reportable Quantity

Not applicable.

Special Provisions for
Transport

ORM-D: For US Domestic Shipments Only

TDG Classification

Consumer Commodity - Transborder Consignment

ADR Classification

Not applicable.

IMDG Classification

UN1950 - Aerosols, class 2.2 - Limited Quantity

IATA Classification

Consumer Commodity, 9 ID8000

Section 15. Regulatory Information
Federal and State
Regulations

SARA Title III, Section 313 Toxic Chemical Notification & Release Reporting:
1) DIETHYLENE GLYCOL MONOBUTYL ETHER

CAS #: 112-34-5

5.6

%

California Proposition 65: This product contains the following ingredients which require a warning under the Safe
Drinking Water & Toxic Enforcement Act:
None

Other Classifications

New Jersey Right-To-Know
Regulation:

WHMIS (Canada)

Not a WHMIS controlled product.

NEW JERSEY WORKER AND COMMUNITY RIGHT TO KNOW ACT: This EPA Registered Product is exempt from the labeling
requirements of the above act. N.J.A.C. 8:59-5.5 #1.

Section 16. Other Information

HMIS (U.S.A.)

Health Hazard
Fire Hazard
Reactivity
Personal Protection

1
2
0
B

Continued on Next Page

1
Health

1

0

Reactivity
Specific hazard

NFPA Aerosol Level
Validated by Product Safety on 9/1/2005.

Fire Hazard

National Fire Protection
Association (U.S.A.)

Printed 9/1/2005.

1, per NFPA 30B

PROFESSIONAL LYSOL® BRAND
DISINFECTANT FOAM CLEANER
(AEROSOL)

Page Number: 5

Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee
that these are the only hazards that exist.

MATERIAL SAFETY DATA SHEET
Product Name: PINE CLEANER & DEODORANT

Product No. 094.00

SAVIN PRODUCTS COMPANY, INC.
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: PINE CLEANER & DEODORANT
Emergency phone: Chemtrec: 800-424-9300
Company:

Product Information: 781-961-2744

SAVIN PRODUCTS COMPANY, INC.
214 HIGH STREET
RANDOLPH, MA 02368

Date Prepared: 04-23-04

Supersedes: 01-15-02

Prepared by: KJS

2. COMPOSITION/INFORMATION ON INGREDIENTS
Component
1. Nonylphenol Ethoxylate

CAS No.
9016-45-9

Exposure Limits
N/A

Typical
% by Weight
1-5

3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
CAUTION: May causes eye irritation. May cause skin irritation with prolonged contact. Harmful if swallowed. Avoid contact with
eyes, skin and clothing. Wash thoroughly after handling. Do not take internally.
EFFECTS of OVEREXPOSURE
CARCINOGENICITY:
NTP: No
IARC: No
OSHA: No
EYES: May cause severe eye irritation.
SKIN: Repeated or prolonged contact may cause skin irritation.
INHALATION: Mist may cause irritation to mucous membranes and respiratory tract.
INGESTION: May result in gastric disturbances.
CHRONIC EFFECTS and MEDICAL CONDITIONS: The effects of long-term, low-level exposures to this product have not been
determined. Safe handling of this material on a long-term basis should emphasize the avoidance of all effects from repetitive acute
exposure. This product may aggravate existing eye, skin and respiratory conditions.
4. FIRST AID MEASURES
EYES: Flush with copious amounts of water for at least 15 minutes, lifting upper and lower lids occasionally. Get immediate medical
attention.
SKIN: Immediately flush with water. Remove contaminated clothing. Launder contaminated clothing before reuse.
INHALATION: Remove to fresh air. If breathing is difficult, oxygen may be given, preferably with a physician’s advice. Get medical
attention.
INGESTION: If swallowed, give several glasses of water. Do not induce vomiting. If vomiting does occur, give fluids again and keep
head below hips to help prevent aspiration. Do not give anything by mouth to an unconscious person. Get immediate medical
attention.
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES:
Flash Point: >200 F
Test: Tag Closed Cup (Method D-56)
Explosive Limits:
LEL: N/A
UEL: N/A
EXTINGUISHING MEDIA: Use water spray, dry chemical, CO2, or alcohol foam.
SPECIAL PROCEDURES AND UNUSUAL HAZARDS: Combustion may produce noxious and irritating gases which will require
fresh air source in fire fighting.
FIREFIGHTING INSTRUCTIONS: Firefighters should wear NIOSH approved, positive pressure, self-contained breathing apparatus
and full protective clothing when appropriate.

Page 1 of 3

MATERIAL SAFETY DATA SHEET
Product Name: PINE CLEANER & DEODORANT

Product No. 094.00

6. ACCIDENTAL RELEASE MEASURES
SMALL SPILLS: Soak up small spills with inert solids. Use suitable disposal container.
LARGE SPILLS: Limit access to area. Dike and contain spill with inert material (sand, earth, etc.) and transfer the liquid and solid
separately to containers for recovery or disposal. Keep spill out of sewers and open bodies of water. CAUTION: Floor may become
slippery.
7. HANDLING AND STORAGE
Handle according to good manufacturing and warehousing practices. Keep containers tightly closed when not in use. Use good
personal hygiene practices. Wash hand before eating, drinking, smoking or using toilet facilities. Promptly remove soiled clothing and
wash thoroughly before reuse. Store in tightly closed containers away from heat, sparks, open flame or strong oxidizing agents.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
EYE PROTECTION: Avoid splashing. Wear chemical-resistant safety goggles if necessary. Contact lenses must not be worn.
PROTECTIVE GLOVES: Depending on conditions of use, protective gloves, apron, boots, head and face protection should be worn.
This equipment should be cleaned thoroughly after each use.
RESPIRATORY PROTECTION: No occupational exposure standards have been developed for this material. Where exposure through
inhalation may occur from use, NIOSH/MSHA approved respiratory protection equipment is recommended.
VENTILATION: Either local exhaust or general room ventilation is usually adequate.
OTHER PROTECTIVE EQUIPMENT: Emergency eye wash fountains and safety showers should be available in the immediate
vicinity of any potential exposure.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Clear, green, thin, foamy liquid.
BOILING POINT: approx. >212F >100C @ 1ATM
FREEZE/MELT POINT: approx. 0C
VAPOR PRESSURE (mm): ca water
VAPOR DENSITY (air=1): ca water
EVAPORATION RATE: approx. water
VOLATILE CONTENT: 97%
SOLUBILITY IN WATER: Complete.
SPECIFIC GRAVITY: 1.01 @ 20C
DENSITY: 8.4 lb./gal. @ 20C
pH(as is): 7.0
ODOR: Pine
ODOR THRESHOLD (ppm): Not determined.
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY (CONDITIONS TO AVOID): Stable.
INCOMPATIBILITY: Strong acids, strong oxidizers and excessive heat.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, Carbon Dioxide, Ammonia, Nitrous oxides and other toxic
gases.
HAZARDOUS POLYMERIZATION: None
11. TOXICOLOGICAL INFORMATION
No LD50 or LC50 found for oral, dermal or inhalation routes of administration.
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL/CHEMICAL FATE INFORMATION: Not available.
13. DISPOSAL CONSIDERATIONS
RCRA: This product, if disposed as shipped, is not considered a hazardous waste as specified in 40 CFR 261.
Dispose in accordance with all applicable federal, state and local regulations.

Page 2 of 3

MATERIAL SAFETY DATA SHEET
Product Name: PINE CLEANER & DEODORANT

Product No. 094.00

14. TRANSPORT INFORMATION
SHIPPING NAME:
HAZARD CLASS:
ID #:
PACKING GROUP:
LABEL:

Compound, Cleaning, Liquid
Not regulated as HAZMAT.
N/A
N/A
N/A

15. REGULATORY INFORMATION
This material does not contain nor was it manufactured using ozone-depleting chemicals.
U.S. FEDERAL REGULATIONS:
TSCA STATUS: All ingredients on Toxic Substance Control Act Inventory.
CERCLA REPORTABLE QUANTITY:

N/A

SARA TITLE III:
Section 302 Extremely Hazardous Substances:
Section 311/312 Hazardous Categories:
Section 313 Toxic Chemicals:

None.
Immediate (Acute)
None.

RCRA STATUS: Based on chemical composition and pH (40 CFR Sec. 261.22), this material is not classified as a hazardous waste if
disposed as shipped.
16. OTHER INFORMATION
All label precautions must be observed when handling, storing and transporting empty containers due to product residues. Do not
reuse this container unless it is professionally cleaned and reconditioned.
REFERENCES:
•
U.S. Dept. of Health and Human Services, NIOSH: Registry of Toxic Effects of Chemical Substances, 1985-86 Editions.
•
Sax, N. Irving and Lewis, R.J.: Dangerous Properties of Industrial Materials, 7th Edition, Van Nostrand Reinhold Co., 1989.
•
Lewis, R.J.: Hawley’s Condensed Chemical Dictionary,12th Edition, Van Nostrand Reinhold Co., 1993.
•
U.S. Dept. of Transportation, U.S. Coast Guard: CHRIS Hazardous Chemical Data, 1982.
•
U.S. Dept. of Labor, OSHA: Air Contaminants - Permissible Exposure Limits, 1989.
•
National Fire Protection Association (NFPA): Fire Protection Guide on Hazardous Materials (NFPA 325M/49/491M/704), 9th
Edition, 1986.
•
National Fire Protection Association (NFPA): Hazardous Materials Response Handbook, Henry, M.F., Editor, 1989.
•
Merck & Co., Inc.: The Merck Index, 11th Edition, 1989.
Information herein is given in good faith as authoritative and valid; no warranty, express or implied can be made.

Page 3 of 3

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NuGenTec
Glass Cleaner - Windex(r) type
PRD Number: GPG202

Page 1 of 5
May 29, 2007

MATERIAL SAFETY DATA SHEET
1.

PRODUCT IDENTIFICATION AND USE
Product Identification
Product Name:
Glass and Window Cleaner - Windex(r) type
Product Number:
GPG202
Synonyms:
Window and Glass Cleaner
CAS Number:
Blend
Company Identification
NuGeneration Technologies, LLC
100 Professional Center Drive suite 101
Rohnert Park, CA
94928
USA
www.nugentec.com
(707) 820-4080
(For product information)
1-800-424-9300 or 1-202-483-7616 (For emergencies CHEMTREC)
SPECIAL NOTES:

2.

Non-streaking Fast drying window cleaner.

HAZARDOUS INGREDIENTS
Chemical Name
------------SEC-PROPYL ALCOHOL
BALANCE NON-HAZARDOUS INGREDIENTS

Amount
-------< 10.0 %
> 90.0 %

CAS Number
---------67-63-0
N/A

COMPOSITION COMMENT:
This Product Meets FDA/USDA requirements for cleaning in the food
processing industry. This product is formulated with NON-Hazardous
ingredients only.
EXPOSURE GUIDELINES:
Canadian Disclosure List

3.

No Information Available.
SEC-PROPYL ALCOHOL

(67-63-0)

PHYSICAL DATA
FORM ...............................:
COLOR ..............................:
ODOR ...............................:
BOILING POINT ......................:
SOLUBILITY IN WATER ................:
SPECIFIC GRAVITY ...................:
BULK DENSITY .......................:
MELTING/FREEZING POINT .............:
PH .................................:
% VOLATILES ........................:
VOLATILE ORGANIC COMPOUNDS (VOC) ...:

Liquid
Colorless
Faint ether-like odor
>212 F
Complete
0.996 (Water = 1)
8.31
32 F
10.5
6 %
<60 g/l

NuGenTec
Glass Cleaner - Windex(r) type
PRD Number: GPG202

Page 2 of 5
May 29, 2007

INHALATION:
No hazards expected in normal industrial use at room temperature.
INGESTION:
Ingestion is not considered a potential route of exposure.
CARCINOGENICITY INFORMATION:
No known cancer hazards.
MISCELLANEOUS:
Slippery, can cause falls if walked on.

4.

FIRE AND EXPLOSION DATA
FLAMMABLE PROPERTIES
COC Flash Point: N/A
Autoignition Temperature:
FLAMMABLE LIMITS IN AIR
EXTINGUISHING MEDIA:

N/A
LEL:

N/A

UEL:

N/A

Carbon dioxide, foam, or dry powder.

FIRE & EXPLOSION HAZARDS:
High concentrations of vapors may burn in a fire.
FIRE FIGHTING INSTRUCTIONS:
Contaminated extinguishing water must be disposed of in accordance with
applicable regulations.

5.

REACTIVITY DATA
STABILITY:
Stable.
POLYMERIZATION:
Hazardous polymerization will not occur.
INCOMPATIBILITY WITH OTHER MATERIALS:
None known.
DECOMPOSITION:
Decomposition will not occur if handled and stored properly.
CONDITIONS TO AVOID:
This material is safe under normal storage and handling conditions.

NuGenTec
Glass Cleaner - Windex(r) type
PRD Number: GPG202

6.

Page 3 of 5
May 29, 2007

TOXICOLOGICAL PROPERTIES
EYE:
Contact may cause eye irritation.
eye tissue.

Not known to cause permanent injury to

SKIN:
Prolonged or repeated contact may cause skin irritation.
INHALATION:
No hazards expected in normal industrial use at room temperature.
INGESTION:
Ingestion is not considered a potential route of exposure.
CARCINOGENICITY INFORMATION:
No known cancer hazards.
MISCELLANEOUS:
Slippery, can cause falls if walked on.
EYE EFFECTS:
Contact may cause eye irritation.
SKIN EFFECTS:
Contact may cause slight skin irritation.
ACUTE ORAL EFFECTS:
No know hazards in normal industrial use.
ACUTE INHALATION EFFECTS:
No know hazards in normal industrial use.

7.

PREVENTITIVE MEASURES
RECOMMENDED STORAGE TEMPERATURE
Minimum: 4.4 C
(39.9 F)
Maximum: 48.9 C
(120.0 F)
HANDLING (PERSONNEL):
Avoid contact with eyes, skin, and clothing.
HANDLING (PHYSICAL ASPECTS):
Keep container closed to avoid contamination.
STORAGE PRECAUTIONS:
Keep container closed when not in use.
pallets high.

Do not stack drums more than three

NuGenTec
Glass Cleaner - Windex(r) type
PRD Number: GPG202

Page 4 of 5
May 29, 2007

ENGINEERING CONTROLS:
Good general ventilation should be sufficient to control airborne levels.
EYE / FACE PROTECTION REQUIREMENTS:
When splashing of the material may occur, chemical goggles and a face
shield are recommended.
SKIN PROTECTION REQUIREMENTS:
For brief contact, normal work attire should be sufficient.
thoroughly after handling.

Wash hands

RESPIRATORY PROTECTION REQUIREMENTS:
Under normal use conditions, with adequate ventilation, no special
handling equipment is required.
SAFEGUARDS (PERSONNEL):
Protect skin and eyes from exposure.
INITIAL CONTAINMENT:
Floor may become slippery. Wash area to prevent slipping. Contain
spilled material. Treat or dispose of waste material in accordance with
all local, state/provincial, and national requirements.
LARGE SPILLS PROCEDURE:
Flush spill area with water to wastewater treatment system. Treat or
dispose of waste material in accordance with all local, state/provincial,
and national requirements.
SMALL SPILLS PROCEDURE:
Floor may become slippery. Wash with water. Treat or dispose of waste
material in accordance with all local, state/provincial, and national
requirements.
WASTE DISPOSAL:
Uncleaned empty containers should be disposed of in the same manner as the
contents. Treat or dispose of waste material in accordance with all
local, state/provincial, and national requirements.
CONTAINER DISPOSAL:

8.

Clean out containers prior to disposal.

FIRST AID MEASURES
EYE CONTACT FIRST AID:
Hold eyelids apart and flush eyes with plenty of water for at least 15
minutes. Get medical attention if irritation develops or persists.
SKIN CONTACT FIRST AID:
Flush skin with plenty of water.
develops or persists.

Get medical attention if irritation

NuGenTec
Glass Cleaner - Windex(r) type
PRD Number: GPG202

Page 5 of 5
May 29, 2007

INHALATION FIRST AID:
Not an expected route of exposure.
Remove from area of exposure. Seek immediate medical attention if
respiratory irritation or distress continues.
INGESTION FIRST AID:
Ingestion is not considered a potential route of exposure.
get medical attention immediately.

If ingested

NOTES TO PHYSICIAN:
Treat patient symptomatically.

9.

PREPARATION DATE OF MSDS
Prepared By.......:
Approval Date.....:
Supersedes Date...:
PRD Number........:

Donato Polignone
May 29, 2007
August 30, 2001
GPG202 (Official Copy)

**********************************************************************
This information is furnished without warranty, expressed or implied,
except that it is accurate to the best knowledge of NuGeneration
Technologies, LLC. The data on this sheet are related only to the
specific material designated herein. NuGeneration Technologies, LLC
assumes no legal responsibility for use or reliance upon these data.
**********************************************************************
END OF MSDS
**********************************************************************

PRODUCT DATA SHEET

Tile & Grout Cleaner
Ready to Use Cleaner For
■ Sanded Grout
■ Non-sanded Grout
■ Ceramic Tile
■ Quarry Tile
■ Glazed Ceramic
■ Honed Marble
■ Honed Limestone
■ Honed Travertine
Special Features
■ Non Acid
■ Removes Mildew
■ Environmentally Safe

■ Mortar
■ Porcelain Tile
■ Tumbled Marble
■ Granite

■ Non Bleach

■ Pleasant Odor

■ Fast Acting

■ User Friendly

PRODUCT DE SCRIPTION

KEEP OUT OF REACH OF CHILDREN. Tile & Grout Cleaner is a non abrasive, non acidic cleaner designed for use on all grout and ceramic tiles.
Strong enough to remove difficult stains, soap scum, dirt, water deposits,
mildew and mold, yet is gentle enough for regular use. Tile & Grout Cleaner
is easy to use and will not harm sanded and non sanded grout as many
household products can. Environmentally friendly Tile & Grout Cleaner will
not harm tile, chrome, glass, Formica or Corian (NOT FOR USE ON POLISHED MARBLE, LIMESTONE OR TRAVERTINE)
Sample Testing
Due to the differences of each substrate, several inconspicuous test patches should be completed to assure maximum performance. User must
determine suitability of the product for their intended use.
Protect Neighboring Surfaces
Always protect neighboring surfaces including wood, carpet, metal, landscaping and other non masonry surfaces.
APPLIC ATION INSTRUCTIONS

Read entire label and PDS/MSDS before using.
Spray Tile & Grout Cleaner onto soiled surface and allow to dwell for several minutes. Wipe clean with a clean scrub pad, brush, sponge or cloth. Do
not allow Tile & Grout Cleaner to dry on the surface. Rinse if necessary.
Heavy soiled surfaces and more porous surfaces may require scrubbing.
Use the appropriate brush for the surface being cleaned. Grout can be
cleaned with a small nylon brush. To remove heavy build up of mold or
mildew use H2O Strip as directed first. Not for use on polished, marble,
travertine or limestone.
Heavy Duty Cleaning: Use Phosphoric Acid Cleaner , GCFR or Liquid
Poultice as directed.
Light Cleaning: Use Mira Clean #1, Porcelain & Ceramic Tile Cleaner, Mira
Soap, Grout Cleaner, or Counter Kleen as directed.
Water, Stain & Slip Protection
To protect cleaned area from future soiling and staining and increase static
coefficient of friction, we recommend applying the appropriate Miracle
Penetrating Sealer/Impregnator.

6.11.2007

Color and Gloss Enhancement
For added color with “Textured and Non polished” surfaces, 511 Seal &
Enhance may be used. For porous type “Paver”, Stone Polish, MiraPolish,
Granite Brite, 511 Seal & Enhance, Mira Dust, Marble Conditioner or Tile
Brite may be used as directed.

www.miraclesealants.com

Mold, Mildew and Bacteria Sanitation
For best results in killing mold, mildew, bacteria and other micro organisms,
use Miracle Disinfectant or Miracle Wipes as directed.
Coverage
Coverage will vary depending on density, porosity, texture. surface absorption, weather, time solution left on surface and application methods. Used
as directed, Tile & Grout Cleaner will clean approximately 4,000 square feet
per gallon (363 s.m. per 3.785 liters) and 250 square feet per 8 ounce bottle (22 s.m. per .16 liters).
MAINTENANCE

For ongoing maintenance instructions please refer to Miracle Sealants Care
Guide. Refer to the Miracle Sealants Product Recommendation Chart for
specific product recommendations.
Storage
Store Tile & Grout Cleaner in the original upright container, properly sealed
and unmixed. Stored at 770 F (400 C), Tile & Grout Cleaner will have a shelf
life of 12 months. Do not allow to freeze.
Technical Support
For additional technical support, contact Miracle Sealants Company at
1-800-350-1901 or 626-814-8988 ext. 3013
Office Hours
Monday - Friday from 8:30 am - 5:00 pm PT.
1-626-443-6433 or 1-800-350-1901 • Fax: 1-626-443-1435
website: www.miraclesealants.com
Product Damaged During Transportation
If product is damaged during transportation contact
Info Trac @ 1-800-535-5053
Additional Products
Miracle Sealants Company offers a complete line of water & stain repellents, sealers, cleaner, polishing compounds, diamond abrasives, machinery and accessories for the tile, stone, concrete, metal, fabric and carpet
professional or do-it yourself specialist.
Caution
Store in cool area. Only use this product in well ventilated areas. Good ventilation means that fresh air is flowing in such a way to feel a slight breeze.
Continue to ventilate until odors are completely eliminated. Avoid contact
with skin. Chemical resistant gloves should be worn at all times. Keep small
children and pets out of area until product or surface has thoroughly dried.
Refer to the MSDS for additional information.
Warranty
Instructions are a condensed guide and should not be considered complete. In the event of failure, the only obligation of Miracle Sealants
Company shall be to replace such products proven to be defective. Before
using, user shall determine the suitability of the product for their intended
use. User assumes all risks and liability whatsoever in connection therein.
Neither seller nor manufacturer shall be liable for any injury or inability to
use this product.

MATERIAL SAFETY DATA SHEET

Tile & Grout Cleaner
Osha’s Hazard Communication Standard
U.S. Department Of Labor
29 CFR 1910.1200
OMB No. 1218-0072
Name: Tile & Grout Cleaner
Identity No:
Section 1
Manufacturers Name:
Address:
Emergency Phone:
City:
State:
Phone:
Date Prepared:

Miracle Sealants Company
12318 Lower Azusa Road
800-350-1901
Arcadia
CA
626-443-6433
June 2007

Section 2 - Hazardous Ingredient/Identity Information
Hazardous Components
CAS #
OSHA PEL
None
None
None
VOC: 6% by weight before dilution or 68 g/L

ACGIH TLV
None

Section 3 - Physical/Chemical Characteristics
Specific gravity: 1.066
Boiling point: 2100 F
Vapor pressure: Not tested
Melting point: Not tested
Vapor density: Not tested
Evaporation rate: Not tested
Solubility in water: 100%
Appearance and odor: Colorless liquid, citrus odor
Section 4 - Fire And Explosion Hazard Data
Flash Point: Not Available
Flammable limits: Not tested
LEL: Not tested
UEL: Not tested
pH: 8.5-10.0
NFPA hazard rating (o = Least, 4 = Extreme)
Health: 1
Fire: 0
Reactivity: 0
Other: 0
HMIS Hazard Rating:
Health: 1
Reactivity: 0

Fire: 0

Extinguishing media: CO2, dry foam
Special fire fighting procedures: None
Unusual fire and explosion hazards: None

www.miraclesealants.com

Emergency and First Aid Procedures:
Eyes: Flush with water for 15 minutes. If irritation persists, call physician.
Skin: Wash off with soap and water. If irritation persists, call physician.
Ingestion: Do not induce vomiting. Call physician or Poison Control Center
immediately..
Inhalation: Get person to fresh air if unconscious. Call physician.
Section 7 - Precautions For Safe Handling And Use
Steps to be taken in case material is released or spilled: Soak up with
inert, absorbent material. Scoop up and place in a proper waste
disposal container.
Waste disposal method: Dispose of in accordance with state and
local regulations.
Precautions to be taken in handling and storing: Store in a cool, dry place,
out of direct sunlight. Do not freeze less than or equal to 320 F or heat
above 1100 F.
Other precautions: KEEP OUT OF REACH OF CHILDREN. Follow directions on
the container for proper use of this product.
Section 8 - Control Measures
Respiratory protection: Ventilate by opening all doors and windows.
Ventilation:
Local exhaust - If available
Mechanical - If available

Protective gloves: Plastic or rubber, chemical resistant.
Eye protection: Tight fitting splash proof safety glasses or goggles.
Other protective clothing or equipment: None
Work hygienic practices: Wash hands thoroughly before handling food
stuffs, liquids or tobacco products. Use common sense and care around
chemicals. Never mix this product with other chemicals. Consult your supervisor for all other hygienic and safety practices. All practices depend on
your specific business. Directions for use normally found on label which will
dictate engineering and control measures.
Section 9 - Shipping & Regulatory Classification
DOT Shipping Name: Please refer to the Bill of Lading receiving/documents
for up-to-date information.
DOT#: Not Available

Section 5 - Reactivity Data
Stability: Stable
Conditions to avoid: None
Incompatible materials to avoid: Strong oxidizer
Hazardous decomposition byproducts: CO, CO2
Hazardous polymerization: Will not occur.
Section 6 - Health Hazard Data
Routes of Entry:
Eyes - Possible
Inhalation - Possible
Skin - Possible
Ingestion - Possible
Health Hazards - Same as signs and symptoms of exposure.

Special - None
Other - None

DOT Hazard Class: Not Available

Toxic Substances Control Act (TSCA): This product and/or all the
ingredients contained in this product have been registered under the
Toxic Substances Control Act.
SARA: No SARA 313 chemicals identified.
NOTE: Miracle Sealants believes the data set forth are accurate. Miracle
Sealants makes no warranty with respects thereto and disclaims all liability
or reliance thereon. Such data are offered solely for consideration, investigation and verification. Also, the data set forth is for the concentrated finished product. All lab samples are for experimental purposes only and used
at the customers discretion.

Carcinogenicity:
OSHA: None
NTP: None
IARC Monographs: None

6.11.2007

Signs and Symptoms of Over Exposure:
Eyes: Burning sensation.
Skin: Slight Irritation.
Ingestion: Nausea.
Inhalation: Slight Irritation.

MATERIAL SAFETY DATA SHEET

TEMP TILE, ENAMEL, METAL AND PORCELAIN CLEANER (SUMA)
HMIS
Health
Fire Hazard
Reactivity

2
0
0

NFPA
2
0
0

Personal protective equipment

None / Aucune / Ninguno

Version Number: 1

Preparation date: 2006-10-12

1. PRODUCT AND COMPANY IDENTIFICATION
Product name:

TEMP TILE, ENAMEL, METAL AND PORCELAIN CLEANER (SUMA)

MSDS #:
Product code:
Recommended use:

203201436001
04410279
Cleaning product.

Manufacturer, importer, supplier:
US Headquarters
JohnsonDiversey, Inc.
8310 16th St.
Sturtevant, Wisconsin 53177-0902
Phone: 1-888-352-2249
MSDS Internet Address:
www.johnsondiversey.com
Emergency telephone number:

Canadian Headquarters
JohnsonDiversey - Canada, Inc.
2401 Bristol Circle
Oakville, Ontario L6H 6P1
Phone: 1-800-668-3131

1-800-851-7145 (Prosar); 1-651-917-6133 (Int'l Prosar); 01-800-710-3400 (México)

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
CAUTION. CAUSES EYE IRRITATION. MAY BE MILDLY IRRITATING TO SKIN.
Principle routes of exposure:
Eye contact:
Skin contact:
Inhalation:
Ingestion:

Eye contact. Skin contact. Inhalation.
Moderately irritating to the eyes.
May be mildly irritating to skin.
None known.
May cause irritation to mouth, throat and stomach .

3. COMPOSITION/INFORMATION ON INGREDIENTS
HAZARDOUS COMPONENTS
Ingredient(s)
Ethylene glycol
Sodium carbonate
Quartz

CAS #

Weight %

LD50 Oral - Rat

107-21-1
497-19-8
14808-60-7

1 - 5%
1 - 5%
100

=4000 mg/kg
=4090 mg/kg
=500 mg/kg

LD50 Dermal Rabbit
=9530 µL/kg
Not available
Not available

LC50 Inhalation - Rat
200 mg/m3
Not available
Not available

4. FIRST AID MEASURES
Eye contact:
Skin contact:
Inhalation:
Ingestion:
Aggravated Medical Conditions:

Flush immediately with plenty of water. If irritation persists, get medical attention.
Flush immediately with plenty of water. If irritation develops get medical attention.
No specific first aid measures are required.
If swallowed, give a cupful of water or milk.
None known.

5. FIRE-FIGHTING MEASURES
Suitable extinguishing media:
Specific hazards:
Unusual hazards:
Specific methods:

The product is not flammable. Extinguish fire using agent suitable for surrounding fire.
Not applicable
None known
No special methods required

Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or
equivalent) and full protective gear
Extinguishing media which must not be used for safety reasons: No information available

TEMP TILE, ENAMEL, METAL AND PORCELAIN CLEANER (SUMA)

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6. ACCIDENTAL RELEASE MEASURES
Personal precautions:
Environmental precautions
and clean-up methods:

Use personal protective equipment
Clean-up methods - large spillage. Shovel into suitable container for disposal. Use a water rinse for final
clean-up.

7. HANDLING AND STORAGE
Handling:
Avoid contact with skin, eyes and clothing. Wash thoroughly after handling. FOR COMMERCIAL AND INDUSTRIAL USE ONLY.
Storage:
Protect from freezing. Keep tightly closed in a dry, cool and well-ventilated place. KEEP OUT OF THE REACH OF CHILDREN.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering measures to reduce exposure:
No special ventilation requirements. General room ventilation is adequate.
Personal Protective Equipment
Eye protection:
Hand protection:
Skin and body protection:
Respiratory protection:
Hygiene measures:

No special requirements under normal use conditions.
No special requirements under normal use conditions
No special requirements under normal use conditions.
No special requirements under normal use conditions.
Handle in accordance with good industrial hygiene and safety practice

Ingredient(s)
Ethylene glycol
Quartz

CAS #
107-21-1
14808-60-7

ACGIH
100 mg/m3 (Ceiling)
0.05 mg/m3 (TWA)

OSHA

Mexico
100 mg/m3 (Peak)
0.1 mg/m3 (TWA)

9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State:
pH:
Appearance:
Color:
Odor:
Specific gravity:
Density:
VOC:
Flash point:
Solubility:
Viscosity:

Solid
10.4
Paste
Yellow - Green
Lavender
1.5497
12.93 lbs/gal
0% *
>200 (°F) >93.3 (°C)
Soluble
No information available

No information available
Bulk density:
Dilution pH:
No information available.
Vapor density:
No information available
Evaporation Rate
No information available
Boiling point/range:
Not determined
Melting point/range:
Not determined
Decomposition temperature:
Not determined
Autoignition temperature:
No information available
Partition coefficient (n-octanol/water): No information available
Solubility in other solvents:
No information available
Elemental Phosphorus:
0 %P

* - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508

10. STABILITY AND REACTIVITY
Stability:
Polymerization:
Hazardous decomposition products:

The product is stable
Hazardous polymerization does not occur
None reasonably foreseeable.

11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information:

Oral LD50 estimated to be greater than 5000 mg/kg
See Section 3

Chronic toxicity:

This product contains Quartz (silica) which is listed as a carcinogen, however, the formulation is a heavy,
viscous liquid and therefore, chronic effects from exposure to respirable-size particles of this product are
minimal.

Specific effects
Carcinogenic effects:
Mutagenic effects:
Reproductive toxicity:
Target organ effects:

None known
None known
None known
None known

TEMP TILE, ENAMEL, METAL AND PORCELAIN CLEANER (SUMA)

2 of 4

11. TOXICOLOGICAL INFORMATION
HAZARDOUS COMPONENTS
Ingredient(s)
Quartz

CAS #
14808-60-7

NTP
X

IARC
1

OSHA
X

12. ECOLOGICAL INFORMATION
Environmental Information:

No data available

13. DISPOSAL CONSIDERATIONS
Waste from residues / unused products:
Dispose of according to all federal, state and local applicable regulations

14. TRANSPORT INFORMATION
DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information

15. REGULATORY INFORMATION
International Inventories
All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL).
U.S. Regulations
California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65
STATE RIGHT TO KNOW
Ingredient(s)
Ethylene glycol
Water
Sodium carbonate
Coconut Oil Based Soap
Tallow
Quartz
CERCLA/ SARA
Ingredient(s)
Ethylene glycol

CAS #
107-21-1
7732-18-5
497-19-8
TS*
61789-97-7
14808-60-7

CAS #
107-21-1

Ingredient(s)
Ethylene glycol
SARA 311/312 Hazard Categories
Immediate:
Delayed:
Fire:
Reactivity:
Sudden Release of Pressure:

MARTK:
X
X

Weight %
1 - 5%

NJRTK:
X
X

CERCLA/SARA RQ (lbs)
5000

CAA HAP
X

CAA ODS

PARTK:
X
X
X

RIRTK:
X
X
-

Section 302 TPQ (lbs)

Section 313
X

CWA Priority Pollutants

X
-

Canada
WHMIS hazard class: D2B Toxic materials .

Ingredient(s)
Ethylene glycol

CAS #
107-21-1

NPRI
X

16. OTHER INFORMATION
Reason for revision:
Prepared by:
Additional advice:

Not applicable
NAPRAC
None

TEMP TILE, ENAMEL, METAL AND PORCELAIN CLEANER (SUMA)

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16. OTHER INFORMATION
Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express
or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible
to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and
regulations.

TEMP TILE, ENAMEL, METAL AND PORCELAIN CLEANER (SUMA)

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Eli Lilly and Company
Material Safety Data Sheet
MSDS Index

Sodium Bicarbonate
Effective Date: 05-Aug-2004

Section 1 - Chemical Product and Company
Emergency Phone:
1-317-276-2000
CHEMTREC:
1-800-424-9300 (North America)
1-703-527-3887 (International)

Manufacturer:
Eli Lilly and Company
Lilly Corporate Center
Indianapolis, IN 46285
Common Name: Sodium Bicarbonate

CAS Number(s): 144-55-8
EINECS Number: 2056-33-8
Chemical Name: Carbonic acid monosodium salt
Chemical Family: Inorganic salt
Chemical Formula: C H O3 . Na
Molecular Weight: 84.01
Synonym(s): Sodium bicarbonate tablets; Soludal; Meylon; Soda; Monosodium carbonate; Sodium
hydrogen carbonate; Sodium acid carbonate; Bicarbonate of soda; Baking soda; Soda mint; NaHCO3;
Sodium bicarbonate - cell culture grade; Sodium bicarbonate tablet mix
Lilly Serial Number(s): 237728
Lilly Item Code(s): QA049K; QA116D; QA192M; QA241X; QA281L; QA384W; QA476V; QD400T;
QD472B; TA1260; TA1264; TA1265
See attached glossary for abbreviations.

Section 2 - Composition / Information on Ingredients
Ingredient
Sodium Bicarbonate

CAS
144-55-8

Exposure Guidelines:
Sodium bicarbonate - Exposure Guideline 1500 micrograms/m3 TWA for 12 hours, 2300
micrograms/m3 TWA for 8 hours. (Lilly-established guideline)
Dow Chemical Exposure Guideline 10 mg/m3 TWA.

Section 3 - Hazards Identification

Appearance: White crystalline powder or granules or compressed uncoated tablets
Physical State: Solid
Odor: Odorless

Emergency Overview
Emergency Overview Effective Date: 07-Aug-2002
Lilly Laboratory Labeling Codes:
Health 1
Fire 0

Reactivity 0

Primary Physical and Health Hazards: No Significant Health Hazards.
Caution Statement: No significant health hazards have been reported for Sodium Bicarbonate.

Routes of Entry: Inhalation and skin contact.
Effects of Overexposure: Material has low acute oral or inhalation toxicity. Material may be slightly
irritating to the eyes, skin, and respiratory tract. Inhalation of dust may cause coughing.
Medical Conditions Aggravated by Exposure: None known.
Carcinogenicity: No carcinogenicity data found. Not listed by IARC, NTP, ACGIH, or OSHA.

Section 4 - First Aid Measures
Eyes: Flush eyes with plenty of water. Get medical attention.
Skin: Remove contaminated clothing and clean before reuse. Wash all exposed areas of skin with
plenty of soap and water. Get medical attention if irritation develops.
Inhalation: Move individual to fresh air. Get medical attention if breathing difficulty occurs. If not
breathing, provide artificial respiration assistance (mouth-to-mouth) and call a physician immediately.
Ingestion: Call a physician or poison control center. No first aid procedures are normally required.

Section 5 - Fire Fighting Measures
Flash Point: Not applicable
UEL: Not applicable
LEL: Not applicable
Extinguishing Media: Use water, carbon dioxide, dry chemical, foam, or Halon.

Unusual Fire and Explosion Hazards: None known.
Hazardous Combustion Products: May emit toxic fumes when exposed to heat or fire.

Section 6 - Accidental Release Measures
Spills: Wear protective equipment, including eye protection, to avoid exposure (see Section 8 for
specific handling precautions). Vacuum material with appropriate dust collection filter in place. Be
aware of potential for dust explosion when using electrical equipment. If vacuum is not available,
lightly mist material and remove by sweeping or wet wiping.

Section 7 - Handling and Storage
Lilly Warehouse Storage Category: 140X
Storage Conditions: Warehouse: 10 to 40 C (45 to 104 F). For certain items, other storage conditions
may be required.

Section 8 - Exposure Controls / Personal Protection
See Section 2 for Exposure Guideline information.
Respiratory Protection: Use an approved respirator.
Eye Protection: Chemical goggles and/or face shield.
Ventilation: Laboratory fume hood or local exhaust ventilation.
Other Protective Equipment: Chemical-resistant gloves and body covering to minimize skin
contact. If handled in a ventilated enclosure, as in a laboratory setting, respirator and goggles or face
shield may not be required. Safety glasses are always required.

Section 9 - Physical and Chemical Properties
Boiling Point: Not applicable
Melting Point: Not applicable
Specific Gravity: 2.159
pH: 8.2 (1% solution)
Evaporation Rate: Not applicable
Water Solubility: 8.6 g/100 ml @ 20 C (68 F)
Vapor Density: Not applicable
Vapor Pressure: Not applicable

Section 10 - Stability and Reactivity

Stability: Stable at normal temperatures and pressures.
Incompatibility: May react with strong oxidizing agents (e.g., peroxides, permanganates, nitric acid,
etc.) and strong acids.
Hazardous Decomposition: May emit toxic fumes when heated to decomposition.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information
Acute Exposure
Oral:
Sodium bicarbonate - Rat, median lethal dose 4220 mg/kg.
Skin: No applicable information found.
Inhalation:
Sodium bicarbonate - Rat, median lethal concentration greater than 4740 mg/m3
(duration unspecified).
Skin Contact: No applicable information found.
Eye Contact:
Sodium bicarbonate - Rabbit, mild irritant

Chronic Exposure
Target Organ Effects: No applicable information found.
Reproduction:
Sodium bicarbonate - No teratogenic effects reported in rats or mice given large doses during
pregnancy.
Sensitization: No applicable information found.
Mutagenicity:
Sodium bicarbonate - Negative in Ames assay.

Section 12 - Ecological Information
Ecotoxicity Data:
Sodium bicarbonate
Daphnia magna 48-hour median lethal concentration: 11.7 mmol/L to 26.3 mmol/L
Western mosquitofish 96-hour median lethal concentration: 5.6 g/L
Bluegill 96-hour median lethal concentration: 8.25 g/L

Rainbow trout median lethal concentration (duration unspecified): 7.7 g/L
Environmental Fate: No applicable information found.
Environmental Summary:
Sodium bicarbonate - This material is practically non-toxic to aquatic organisms. Material is soluble in
water and may leach from soil into groundwater.

Section 13 - Disposal Considerations
Waste Disposal: Dispose of any cleanup materials and waste residue according to all applicable laws
and regulations.

Section 14 - Transport Information
Regulatory Organizations:
DOT: Not Regulated
ICAO/IATA: Not Regulated
IMO: Not Regulated

Section 15 - Regulatory Information
Below is selected regulatory information chosen primarily for possible Eli Lilly and Company
usage. This section is not a complete analysis or reference to all applicable regulatory
information. Please consider all applicable laws and regulations for your country/state.
U.S. Regulations
Sodium bicarbonate
TSCA - Yes
CERCLA - Not on this list
SARA 302 - Not on this list
SARA 313 - Not on this list
OSHA Substance Specific - No
EU Regulations
EC Classification
Not assigned an overall EC classification.

Section 16 - Other Information
MSDS Sections Revised: Section 7.

As of the date of issuance, we are providing available information relevant to the handling of this
material in the workplace. All information contained herein is offered with the good faith belief that it is
accurate. THIS MATERIAL SAFETY DATA SHEET SHALL NOT BE DEEMED TO CREATE ANY
WARRANTY OF ANY KIND (INCLUDING WARRANTY OF MERCHANTABILITY OR FITNESS
FOR A PARTICULAR PURPOSE). In the event of an adverse incident associated with this material,
this safety data sheet is not intended to be a substitute for consultation with appropriately trained
personnel. Nor is this safety data sheet intended to be a substitute for product literature which may
accompany the finished product.
For additional information contact:
Eli Lilly and Company
Hazard Communication
317-433-7171
GLOSSARY:
ACGIH = American Conference of Governmental Industrial Hygienists
AIHA = American Industrial Hygiene Association
BEI = Biological Exposure Index
CAS Number = Chemical Abstract Service Registry Number
CERCLA = Comprehensive Environmental Response Compensation and Liability Act (of 1980)
CHAN = Chemical Hazard Alert Notice
CHEMTREC = Chemical Transportation Emergency Center
DOT = Department of Transportation
EC = European Community
EINECS = European Inventory of Existing Chemical Substances
ELINCS = European List of New Chemical Substances
EPA = Environmental Protection Agency
HEPA = High Efficiency Particulate Air (Filter)
IARC = International Agency for Research on Cancer
ICAO/IATA = International Civil Aviation Organization/International Air Transport Association
IEG = Lilly Interim Exposure Guideline
IMO = International Maritime Organization
Kow = Octanol/Water Partition Coefficient
LEG = Lilly Exposure Guideline
LEL = Lower Explosive Limit
MSDS = Material Safety Data Sheet
MSHA = Mine Safety and Health Administration
NA = Not Applicable, except in Section 14 where NA = North America
NADA = New Animal Drug Application
NAIF = No Applicable Information Found
NCI = National Cancer Institute
NIOSH = National Institute for Occupational Safety and Health
NOS = Not Otherwise Specified
NTP = National Toxicology Program
OSHA = Occupational Safety and Health Administration
PEL = Permissible Exposure Limit (OSHA)
RCRA = Resource Conservation and Recovery Act
RQ = Reportable Quantity
RTECS = Registry of Toxic Effects of Chemical Substances

SARA = Superfund Amendments and Reauthorization Act
STEG = Lilly Short Term Exposure Guideline
STEL = Short Term Exposure Limit
TLV = Threshold Limit Value (ACGIH)
TPQ = Threshold Planning Quantity
TSCA = Toxic Substances Control Act
TWA = Time Weighted Average/8 Hours Unless Otherwise Noted
UEL = Upper Explosive Limit
UN = United Nations
WEEL = Workplace Environmental Exposure Level (AIHA)

Material Safety Data Sheet: Simple Green® Lime Scale Remover
Version No. 00004
Date of Issue: January 2007

Section 1:

ANSI-Z400.1-2003 Format

PRODUCT & COMPANY IDENTIFICATION

Product Name:
Additional Names:

Simple Green® Lime Scale Remover
AROMA CLEAN™ by Simple Green® Bath, Tub & Tile Cleaner

Manufacturer’s Product Code Numbers:
Lime Scale Remover
50022 – 22 oz trigger spray bottle
50032* – 32 oz trigger spray bottle
50005* – 5 gallon pail
Company:

Telephone:
Emergency Phone:
Use of Product:

Section 2:

Aroma Clean Bath, Tub & Tile
16201 – 24 oz Trigger Spray Bottle
50128* – 1 gallon bottle
50155* – 55 Gallon Drum

* GSA Available

Sunshine Makers, Inc.
15922 Pacific Coast Highway
Huntington Harbour, CA 92649 USA
800-228-0709 ● 562-795-6000
Fax: 562-592-3830
Chem-Tel 24-Hour Emergency Service: 800-225-3924
Ready to use liquid for removal of soap scum, mineral scale, hard-water spots, calcium and lime
deposits on hard, non-porous surfaces. Not for use on any natural stone surface.

HAZARDS IDENTIFICATION

Emergency Overview: CAUTION. Eye irritant.
This product contains no substances which at their given concentration, are considered to be hazardous to health.
0
0

1
0

NFPA/HMIS Rating:
Health = 1 = slight
Fire, Reactivity, and Special = 0 = minimal

Principal Routes of Exposure: Eye, Skin contact, Ingestion
Eye Contact: Eye Irritant.
Skin Contact: Substance may cause slight skin irritation.
May cause gastrointestinal irritation, nausea, vomiting and diarrhea.
Ingestion:
Carcinogens: No ingredients are listed by OSHA, IARC, or NTP as known or suspected carcinogens.
No medical conditions are known to be aggravated by exposure to Simple Green® Lime Scale
Medical Conditions:
Remover.

Section 3:

COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name
Urea monohydrochloride

CAS Number
506-89-8

Hazardous Substances Present:
SARA 313 Substances Present:
Clean Air Act Sec. 112 Substances Present:

Section 4:
Eye Contact:
Skin Contact:
Inhalation:
Ingestion:

% Weight
3-5%

ACGIH TWA
Not applicable

Acute Toxicity LD50
1121 mg/kg rat (oral)

None
None
None

FIRST AID MEASURES
In case of eye contact, remove contact lenses and rinse immediately with plenty of water, also under the
eyelids, for at least 15 minutes.
Flush with water. Wash off the soap and water. Obtain medical attention if irritation persists. Wsh
contaminated clothing well before reuse.
Not a normal route of exposure. If symptoms develop, move victim to fresh air. If symptoms persist,
call a physician.
Clean mouth with water and afterwards drink plenty of water. Never give anything by mouth to an
unconscious person. Consult a physician if necessary.

Material Safety Data Sheet: SIMPLE GREEN® LIME SCALE REMOER

Pg 1 of 3

Material Safety Data Sheet: Simple Green® Lime Scale Remover
Date of Issue: January 2007
Version No. 00004

Section 5:

FIRE FIGHTING MEASURES

Flash Point:
Hazardous Combustion Products:
Suitable extinguishing media:
Specific hazards:

Section 6:

ANSI-Z400.1-2003 Format

Not flammable
May include, but not limited to, oxides of carbon
Treat for surrounding material.
Fire fighters should wear self-contained breathing apparatus.

ACCIDENTAL RELEASE MEASURES

Method for cleaning up: Before initiating cleanup, refer to hazard data on this MSDS
• Retrieve any useable product and store in properly marked containers
• Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container
• Prevent large spills from entering sewers and waterways.

Section 7:

HANDLING AND STORAGE

Safe Handling:
Storage:
Incompatible Products:

Section 8:

Avoid contact with eyes. Wash hands immediately after contact to avoid hand-eye transfer.
Keep out of reach of children. Keep containers tightly closed in cool, well-ventilated place.
Bleach, mildew stain removers, caustics, oxidizers, reducers.

EXPOSURE CONTROLS/PERSONAL PROTECTION

Hand Protection
Eye Protection
Respiratory Protection
Other Protective Equipment
Engineering measures
General hygiene
conditions:

Section 9:

There are no known hazards associated with this material when used as recommended.
The following general hygiene considerations are recognized as common good industrial hygiene
practices:
- Avoid breathing vapor or mist.
- Avoid contact with eyes.
- Wash thoroughly after handling and before eating, drinking, or smoking.

PHYSICAL AND CHEMICAL PROPERTIES

Appearance:
Odor:
Vapor Density:
pH:
Boiling Point:
Freezing Point:
Water Content:
Specific Gravity:

Section 10:

Rubber
Safety Glasses
Not normally required
As required by employer code
None, under normal processing

Lime Scale Remover is a pale aqua liquid; AROMA CLEAN is a pale purple liquid.
Lime Scale Remover has a wintergreen fragrance; AROMA CLEAN has a lavender fragrance.
Not determined
Completely water soluble.
Water Solubility:
1.0 – 1.5
8.52 lbs/gallon
Bulk Density:
o
o
~ 100 C (~212 F)
None observed to boiling point.
Flash Point:
Ca. 0oC
< 0.01%
Insoluble matter:
> 70%
0 g/L per EPA Method 24
VOCs:
1.0230

STABILITY AND REACTIVITY

Stability:
Materials to Avoid:
Hazardous Decomposition Products:

Stable
None known
None expected

Material Safety Data Sheet: SIMPLE GREEN® LIME SCALE REMOER

Pg 2 of 3

Material Safety Data Sheet: Simple Green® Lime Scale Remover
Version No. 00004
Date of Issue: January 2007

Section 11:

ANSI-Z400.1-2003 Format

TOXICOLOGICAL INFORMATION

Acute Toxicity:

Oral LD50 (rat) - > 10 g/kg body weight
Toxicity extrapolated from ingredients. Animal testing not conducted.

Eye Irritation:

This product may cause irritation to the eyes.

Dermal Irritation:

Not expected under normal use conditions.

Repeat Exposure Via Skin Contact: No toxic effects are expected to be associated with normal daily exposure

Section 12: ECOLOGICAL INFORMATION
Hazard to wild mammals:
Hazard to avian species:
Hazard to aquatic organisms:
Chemical Fate Information:

Low, based on toxicology profile
Low, based on toxicology profile
> 100 mg/L (rainbow trout, 96 hours)
Biodegradable; Based on formula & biodegradability, the bioaccumulation potential is low.

Section 13: DISPOSAL CONSIDERATIONS
Waste from residues/unused product:
Empty Containers:

Dispose in accordance with all national and local regulations.
Triple-rinse with water and offer for recycling if available in your area.
Otherwise, dispose as non-hazardous waste.

Dispose of used or unused product, and empty containers in accordance with the local, State provincial, and Federal
regulations for your location. Never dispose into lakes, streams, and open bodies of water or storm drains.

Section 14: TRANSPORT INFORMATION
DOT:
Proper Shipping Name:

Not regulated for ground shipments
Cleaning Compound Class 55

UN No.:
Packing Group:

Not required.
Not applicable

Section 15: REGULATORY INFORMATION
All components are listed on Canadian DSL, EINECS and TSCA Chemical Substances Inventory.
RCRA Status:
Not a hazardous waste.
CERCLA Status:
Not Listed.
TSCA TIR Reporting:
Not required / Not Listed.
CA PROP. 65 Status:
Not Listed.

Section 16:

OTHER INFORMATION

Questions about the information found on this MSDS should be directed to:
SUNSHINE MAKERS, INC. – TECHNICAL DEPARTMENT
15922 Pacific Coast Hwy. Huntington Harbour, CA 92649
Phone: 800/228-0709 [8am-5pm Pacific time, Mon-Fri]
Fax: 562/592-3830

Email: infoweb@simplegreen.com

DISCLAIMER: The information provided with this MSDS is furnished in good faith and without warranty of any kind.
Personnel handling this material must make independent determinations of the suitability and completeness of information
from all sources to assure proper use and disposal of this material and the safety and health of employees and customers.
Sunshine Makers, Inc. assumes no additional liability or responsibility resulting from the use of, or reliance on this
information.

Material Safety Data Sheet: SIMPLE GREEN® LIME SCALE REMOER

Pg 3 of 3

Material Safety Data Sheet
Product Name:

Number:

DMN-308

Sparkle Floor Cleaner, #2473
Revised: 9/4/98

A liquid alkaline detergent.
Damon Industries, Inc.
Box 2120
Alliance, OH 44601

24 hour Emergency Only phone: 1-800-535-5053
Information phone: 1-800-362-9850 or 330-821-5310
fax: 330-821-6355

Section 2 - Composition / Information on Hazardous Ingredients
Ingredient
1-Butoxy-2-propanol
Potassium hydroxide

Cas No.
5131-66-8
1310-58-3

Percent
2 - 10%
2 - 5%

Carcinogen
No
No

Section 3 - Hazards Identification
Emergency Overview: Concentrate is corrosive to all body parts. Diluted solutions may be irritating or corrosive
depending on their strength. Excessive inhalation of vapors may cause irritation. Product is water based and
presents little or no hazard in a fire. Product has a high pH and large amounts should not be allowed into sewers
without neutralizing. A green liquid with a sharp odor.
Health Hazards: Corrosive, Irritant
Primary Routes of Entry: X Through Skin

Physical Hazards: None
X Inhalation

X Ingestion

Potential Health Effects:
Eyes - concentrate and strong solutions cause eye damage. Milder solutions cause irritation and redness.
Skin - prolonged contact with concentrate and strong solutions can cause skin damage and loss. There is little or
no effect if rinsed off thoroughly right away. Weaker solutions cause irritation.
Swallowing - may result in damage to mucous membranes and gastrointestinal irritation.
Breathing - excessive inhalation of mist or spray can cause coughing, irritation of nose and throat.
Section 4 - First Aid Measures
Eye Contact: Immediately flush eyes with water for at least 15 minutes, lifting upper and lower eyelids
occasionally. Get medical attention immediately.
Skin Contact: With concentrate and strong (1:10) solutions immediately flush exposed area with running water
for 15 minutes. Remove contaminated clothing and shoes. With weaker solutions wash exposed area with soap
and water. If irritation persists, call a physician. Wash contaminated clothing before reuse.
Inhalation: If affected, move exposed person to fresh air. If irritation persists get medical attention.
Ingestion: If the product is swallowed, do NOT induce vomiting. If the affected person is conscious, give a glass
of water or milk to drink. Get medical attention immediately.
Section 5 - Fire-Fighting Measures
Flash Point: None (ASTM D-56 closed cup)
Lower Explosive Limit: Not Applicable
Extinguishing Media: Any
Special Fire Fighting Procedures: None.
Unusual Fire And Explosion Hazards: None.

Upper Explosive Limit: Not Applicable

Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Small spills of a few gallons may be cleaned up with a
rag or mop. Larger spills should diked to prevent spreading and then collected into clean pails or drums.
Section 7 - Handling and Storage
Empty containers retain product residue and may be hazardous. Observe all precautions given in this data sheet.
Keep from freezing.

DMN-308 Sparkle Floor Cleaner

Page 1 of 2

9/4/98

Section 8 - Exposure Controls / Personal Protection
Ingredient
1-Butoxy-2-propanol
Potassium hydroxide

C.A.S. No.
5131-66-8
1310-58-3

(1)=OSHA (2)=NIOSH (3)=ACGIH (4)=CANADA

Percent
2 - 10%
2 - 5%

TWA(source)
STEL
Ceiling
no established limits are available
2 mg/m3(2)
2 mg/m3(3,4)

TWA=8 hr Time Weighted Average

STEL=15 minute TWA

Ceiling=Instantaneous

Ventilation: Good room ventilation.
Respiratory Protection: None, except when spraying overhead use an approved respirator with an organic
vapor cartridge.
Gloves: Use rubber or latex gloves when handling concentrate or strong dilutions. Persons with sensitive skin or
who use the product for prolonged periods may wish to use rubber or latex gloves when using any dilution.
Eye Protection: Most uses of diluted product do not require eye protection although the use of safety glasses
with side shields, especially for contact lens wearers, is always a good idea. Using concentrate or strong (1:10)
solutions requires safety glasses with side shields. Overhead spraying requires goggles or a face shield, or if
considerable spray will fall on the user, complete head and body protection.
Other Protective Equipment: An eyewash station should be located within 10 seconds travel time of the
concentrate use/mixing area.
Section 9 - Physical and Chemical Properties
Boiling Point: 215° F.
Specific Gravity: 1.05
Percent Volatiles: 85%
Solubility In Water: Complete
Appearance and Odor: Green liquid with sharp odor.

Vapor Pressure: Not Available
Vapor Density: Not Available
Evaporation Rate: Same as water.
pH: concentrate 13.5 ± 0.5

Section 10 - Stability and Reactivity
Incompatibility: None

Hazardous Decomposition Products: None
Section 11 - Toxicological Information

Target Organs: None.
Section 12 - Ecological Information
When scrubbing outdoors or where the solution will enter a storm sewer, flood the cleaned area with plenty of
water to dilute and reduce pH of run-off. Do not use more product than necessary. Do not dispose of unusable
product in the environment. Be sure to comply with any applicable regulations.
Section 13 - Disposal Considerations
Waste Disposal Method: Dispose of up to 2 gallons of concentrate in the sanitary sewer with a large amount of
water. Larger amounts must be neutralized to within the pH limits of your waste water treatment system.
Section 14 - Transport Information
D.O.T. Hazard Class: Not considered hazardous by D.O.T., I.M.C.O., I.A.T.A. or U.N.
Section 15 - Regulatory Information
The components of this product are on the TSCA inventory of chemical substances.
Section 16 - Other Information
NFPA / HMIS
Ratings:

Health:
Flammability:
Reactivity:

2
0
0

0 = Insignificant
3 = Serious

1 = Slight
2 = Moderate
4 = Severe

The information accumulated herein is believed to be accurate but is not warranted to be. Recipients are advised
to confirm in advance that the information is current, applicable, and suitable to their circumstances.

DMN-308 Sparkle Floor Cleaner

Page 2 of 2

9/4/98

MATERIAL SAFETY DATA SHEET

VANISH NON-ACID BOWL & BATHROOM CLEANER II
HMIS
Health
Fire Hazard
Reactivity

1
1
0

NFPA
1
1
0

Personal protective equipment

Preparation date: 2005-08-23

Version Number: 1

1. PRODUCT AND COMPANY IDENTIFICATION
Product name:

VANISH NON-ACID BOWL & BATHROOM CLEANER II

MSDS #:
Product code:
Recommended use:

126478001
126478001, 90158
Cleaning product.

Manufacturer, importer, supplier:
US Headquarters
JohnsonDiversey, Inc.
8310 16th St.
Sturtevant, Wisconsin 53177-0902
Phone: 1-888-352-2249
MSDS Internet Address:
www.johnsondiversey.com
Emergency telephone number:

Canadian Headquarters
JohnsonDiversey - Canada, Inc.
2401 Bristol Circle
Oakville, Ontario L6H 6P1
Phone: 1-800-668-3131

1-800-851-7145 (Prosar); 1-651-917-6133 (Int'l Prosar); 01-800-710-3400 (México)

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Moderately irritating to the eyes. Moderately irritating to the skin.
Principle routes of exposure:
Skin contact:
Eye contact:
Inhalation:
Ingestion:

Inhalation. Skin contact. Eye contact.
May be mildly irritating to skin.
Moderately irritating to the eyes.
None known.
None known.

3. COMPOSITION/INFORMATION ON INGREDIENTS
HAZARDOUS COMPONENTS
Ingredient
N-alkyl dimethyl benzyl ammonium
chlorides
N-alkyl dimethyl ethylbenzyl
ammonium chlorides
Isopropyl alcohol

CAS #
68391-01-5

Weight %
0.1 - 1.5%

LD50 Oral
Not available

LD50 Dermal
Not available

LC50 Inhalation
Not available

68956-79-6

0.1 - 1.5%

Not available

Not available

Not available

67-63-0

1 - 5%

5000 mg/kg (rat)

12800 mg/kg (rabbit)

16000 ppm/8H (rat)

4. FIRST AID MEASURES
Eye contact:
Skin contact:
Inhalation:
Ingestion:
Aggravated Medical Conditions:

Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if
present, after the first 5 minutes, then continue rinsing eyes. If irritation persists, get medical attention.
Flush immediately with plenty of water. Get medical attention if irritation occurs.
No specific first aid measures are required.
No specific first aid measures are required.
Persons with pre-existing skin disorders may be more susceptable to irritating effects

5. FIRE-FIGHTING MEASURES
Suitable extinguishing media:

Use dry chemical, CO2, water spray or "alcohol" foam.

VANISH NON-ACID BOWL & BATHROOM CLEANER II

1 of 3

Specific hazards:
Unusual hazards:
Specific methods:

Although this product has a flash point below 200 Deg. F, it is an aqueous solution containing an alcohol
and does not sustain combustion.
None known.
No special methods required.

Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or
equivalent) and full protective gear
Extinguishing media which must not be used for safety reasons: No information available

6. ACCIDENTAL RELEASE MEASURES
Personal precautions:
Environmental precautions
and clean-up methods:

Put on appropriate personal protective equipment (see Section 8.).
Use appropriate containment to avoid environmental contamination. Sweep up and shovel into suitable
containers for disposal. Keep in suitable and closed containers for disposal. Use a water rinse for final
clean-up.

7. HANDLING AND STORAGE
Handling:
Avoid contact with skin, eyes and clothing. Wash thoroughly after handling. FOR COMMERCIAL AND INDUSTRIAL USE ONLY
Storage:
Keep tightly closed in a dry, cool and well-ventilated place. Protect from freezing . Keep out of the reach of children.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering measures to reduce exposure:
None known
Personal Protective Equipment
Eye protection:
Hand protection:
Skin and body protection:
Respiratory protection:
Hygiene measures:
Ingredient
Isopropyl alcohol

No special requirements under normal use conditions
No special requirements under normal use conditions
No special requirements under normal use conditions
No special requirements under normal use conditions
Handle in accordance with good industrial hygiene and safety practice
CAS #
67-63-0

ACGIH
400 ppm (STEL)
200 ppm (TWA)

OSHA
980 mg/m3 400 ppm

Mexico
1225 mg/m3 (STEL)
980 mg/m3 (TWA)

9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State:
Liquid
Color:
Clear Blue
Odor:
No information available
Specific gravity:
No information available
Dilution pH:
No information available
Bulk density:
No information available
Vapor density:
No information available
Evaporation rate:
No information available
Solubility in other
No information available
solvents:
Viscosity: No information available
Partition coefficient (n-octanol/water): No information available

Appearance:
No information available
Boiling point/range: >199.4 (°F)
Melting point/range: <32 (°F)
pH:
7.5
Density:
No information available
Decomposition temperature:
Not determined
Autoignition temperature:
No information available
Solubility:
Soluble
VOC:
2%
Flash point: 141.8 (°F) 61 (°C)

10. STABILITY AND REACTIVITY
Stability:
Polymerization:
Hazardous decomposition products:
Materials to avoid:
Conditions to avoid:

The product is stable.
Not applicable.
None reasonably foreseeable
None known .
Keep away from heat.

11. TOXICOLOGICAL INFORMATION
Acute toxicity
Component Information:

LD50 estimated to be greater than 5000 mg/kg.
See Section 3

Chronic toxicity:

None known

Specific effects
Carcinogenic effects:

None known

VANISH NON-ACID BOWL & BATHROOM CLEANER II

2 of 3

Mutagenic effects:
Reproductive toxicity:
Target organ effects:

None known
None known
None known

12. ECOLOGICAL INFORMATION
Environmental Information:

When used for its intended purpose this product should not cause adverse effects in the environment

13. DISPOSAL CONSIDERATIONS
Waste from residues / unused products:
PESTICIDAL WASTE - Observe all applicable Federal/Provincial/State regulations and Local/Municipal ordinances regarding disposal of pesticide
wastes .

14. TRANSPORT INFORMATION
DOT/TDG: Please refer to the Bill of Lading/receiving documents for up to date shipping information

15. REGULATORY INFORMATION
International Inventories
All components of this product are listed on the following inventories: Korea (ECL), Philippines (PICCS), China (IECSC).
U.S. Regulations
EPA Reg. No. : 70627-3
California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65
STATE RIGHT TO KNOW
Ingredient
Water
Isopropyl alcohol
Alcohol ethoxylates

CAS #
7732-18-5
67-63-0
68131-39-5

CERCLA / SARA
Ingredient
Isopropyl alcohol

CAS #
67-63-0

MARTK:
Listed
-

NJRTK:
Listed
-

Weight %
1 - 5%

PARTK:
Listed
-

CERCLA/SARA RQ (lbs)
100

RIRTK:
Listed
-

ILRTK:
Listed
-

Section 302 TPQ (lbs)

CTRTK:
Listed
-

Section 313
Listed.

Canada
WHMIS hazard class: Not for sale in Canada .
Ingredient
Isopropyl alcohol

CAS #
67-63-0

NPRI
Listed

16. OTHER INFORMATION
Reason for revision:
Prepared by:
Additional advice:

Not applicable
NAPRAC
None

Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express
or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible
to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and
regulations.

VANISH NON-ACID BOWL & BATHROOM CLEANER II

3 of 3

MATERIAL SAFETY DATA SHEET
24 HOUR EMERGENCY CHEMTREC TELEPHONE 1-(800)-424-9300
24 HOUR MEDICAL EMERGENCY TELEPHONE 1-(888)-324-7596
WD-40 COMPANY, 1061 Cudahy Place (92110), P.O. Box 80607, San Diego, CA 92138-0607
TELEPHONE (619)-275-1400
DATE PREPARED: December, 2004
I. GENERAL INFORMATION
PRODUCT NAME: Maximum Strength X-14 Instant Mildew Stain Remover
PRODUCT CATEGORY: Household Cleaner
II. INGREDIENTS
HAZARDOUS INGREDIENTS:
%
Sodium hypochlorite
3-6%
Sodium carbonate
0.5-2%

CAS #
7681-52-9
497-19-8

TLV/PEL
Not established
Not established

HAZARD DATA
Irritant/Corrosive
Irritant

III. HEALTH HAZARD DATA
EFFECTS OF OVEREXPOSURE:
SKIN: May cause skin irritation.
EYE: Causes eye irritation.
INHALATION: Mist may be irritating to the upper respiratory tract. Not recommended for use by persons with heart conditions or chronic respiratory problems.
INGESTION: May cause gastrointestinal irritation, nausea, vomiting and diarrhea.
FIRST AID PROCEDURE:
SKIN: Flush immediately and thoroughly with water.
EYE: Flush with large amounts of water for at least 15 minutes while holding eyelids open. Contact a physician.
INHALATION: Discontinue use. Remove to fresh air.
INGESTION: Do not induce vomiting. Drink several glasses of water. Call a poison control center or a physician immediately. Do not give anything by mouth to unconscious individuals.
IV. SPECIAL PROTECTION INFORMATION
EYE PROTECTION: Safety glasses should be worn in an industrial/institutional setting.
SKIN PROTECTION: For sensitive skin or prolonged use, wear rubber gloves.
RESPIRATORY PROTECTION: Not needed when product is used according to label directions. Appropriate cartridge
respirator may be needed in an institutional setting. Use in a well-ventilated area.
V. FIRE AND EXPLOSION HAZARD DATA
FLAMMABLE LIMITS: Non-flammable liquid.
EXTINGUISHING MEDIA: As applicable to type of fire.
SPECIAL FIRE FIGHTING PROCEDURES: Fire can be fought with standard procedures but hazards are present that
can be handled safely by wearing self contained breathing apparatus.
UNUSUAL FIRE/EXPLOSION HAZARDS: None
VI. ENVIRONMENTAL PROTECTION PROCEDURES
SPILL RESPONSE: Wipe up spill with absorbent material. Rinse spill area with water to remove residue.
WASTE DISPOSAL METHOD: Do not reuse container. Dispose of in accordance with federal, state and local
regulations.

VII. SPECIAL PRECAUTIONS
HANDLING: Avoid contact with eyes, contact lens or eyeglasses. Avoid contact with skin. Avoid breathing fumes.
STORAGE: Do not store next to acids or heat source. Keep container tightly closed.
TRANSPORTATION: In accordance with federal, state and local regulations.
VIII. REACTIVITY DATA
STABILITY: Stable.
INCOMPATIBILITY: Do not mix with acids, ammonia or other household chemicals.
HAZARDOUS DECOMPOSITION PRODUCTS: When heated can form carbon monoxide, carbon dioxide and chlorine.
IX. PHYSICAL DATA
BOILING POINT (°F): Not determined.
VAPOR PRESSURE (mm Hg): Not determined.
VAPOR DENSITY (AIR=1): Not determined.
APPEARANCE AND ODOR: Clear, yellow
liquid with chlorine odor.

SPECIFIC GRAVITY (H2O=1): 1.03-1.15
% VOLATILE BY VOLUME: Greater than 85%.
SOLUBILITY IN WATER: Soluble
pH: 11.5-12.0

The information provided in this Material Safety Data Sheet has been compiled from our experience and data with
similar commercially available materials and is believed to be accurate. No guarantee of accuracy is made. It is the
user's responsibility to determine the suitability of this information for the adoption of necessary safety precautions and
disposal procedures.
PLEASE BE ADVISED THAT THIS MATERIAL SAFETY DATA SHEET IS INTENDED FOR INDUSTRIAL PURCHASERS
WHICH MAY USE LARGE QUANTITIES OF THE PRODUCT. DEPENDING ON THE SCOPE OF TOXICOLOGICAL
TESTS CONDUCTED ON THE FORMULATION AND/OR THE RAW MATERIALS, THE LISTED HAZARD DATA MAY
REFLECT HAZARDS RELATED TO THE FORMULATION AS A WHOLE OR TO INDIVIDUAL COMPONENTS AT 100%
CONCENTRATION. THEREFORE, CERTAIN WARNINGS AND HAZARD STATEMENTS CONTAINED ON THIS MSDS
MAY NOT BE APPLICABLE TO OR INCLUDED IN THE PACKAGE LABELING AVAILABLE TO THE GENERAL PUBLIC.

SIGNATURE: Peter Fougner

TITLE:

REVISION DATE:

SUPERSEDES:

MSDS No.:X14MSR

December, 2004

Director - Global Quality Assurance
October, 2003

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name:
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

FORMULA 499185
ZENAGEL
ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Sodium Hydroxide
Butane
Triethylene Glycol
Propane
Ethanolamine

CAS No.:
1310-73-2
106-97-8
112-27-6
74-98-6
141-43-5

TLV:
2 mg/m3 ceiling
800ppm
N.A.
2500ppm
3ppm

______________________________________________________________________________

SECTION 3
Boiling Point:
Solubility in Water:
pH:

PHYSICAL DATA
<0 to 5670 F
Soluble
13.5 + 0.5

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.99 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flash Point(Propellant):
Flammable Limits(Propellant):
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

Non-Flammable
<0OF
LEL:
0.9
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5
Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

Acids
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.

First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________

SECTION 9

SPILL OR LEAK PROCEDURE

Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None

__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
499185

Friday, January 18, 2008

Page 1 of 4

MSDS - Material Safety Data Sheet
Product Name: CARPET AND UPHOLSTERY ALL PURPOSE FOAM
CLEANER
MSDS No.: MPC22

I. Basic Information:
Manufacturer: RADIATOR SPECIALTY COMPANY

2

Address: 600 RADIATOR ROAD
City, ST Zip: INDIAN TRAIL, NC 28079

1

Emergency Contact: Rocky Mountain Poision Control Center
Emergency Telephone Number: 303-623-5716
Contact: Robert Geer
Information Telephone Number: 704-684-1811
Last Update: 01/18/2008
Chemical State:

X

Chemical Type:

1
2

Expiration Date:

Liquid
Pure

Gas

X

0

Solid

B

Mixture

II. Ingredients:
Trade Secret
EHS

IARC
NTP

SARA
313
OSHA
SUB Z
PEL

ACGIH
TLV

X

25 ppm

25 ppm

CAS No.

Chemical Name

% Range

111-76-2

2-Butoxyethanol

1-5

106-97-8

Butane

1-4

N/E

800 ppm

74-98-6

Propane

1-4

N/E

1000 ppm

1310-73-2

Sodium hydroxide

0-3

2 mg/m3

2 mg/m3

Other
Limits

III. Hazardous Identification:
Hazard Category:

X Acute

Chronic

Fire

X Pressure

Hazardous Identification Information:

CAUTION: Eye Irritant, Contents Under Pressure.
Level 1 Aerosol

IV. First Aid Measures:
Route(s) of Entry:

Absorption, Eye, Inhalation, and Ingestion.
Health Hazards (Acute and Chronic):

See signs and symptoms below.
Signs and Symptoms:

Eye Contact: Direct spray of vapors may be irritating or harmful to eyes.
Skin Contact: Prolonged contact may cause irritation due to defatting of skin.
Inhalation: High concentration of vapors may irritate nose and throat and cause headaches and nausea.
Ingestion: Can cause irritation, gastric disturbances, and nausea..
Medical Conditions Generally Aggravated by Exposure:

Reactive

Friday, January 18, 2008

Page 2 of 4

MSDS - Material Safety Data Sheet
Product Name: CARPET AND UPHOLSTERY ALL PURPOSE FOAM
CLEANER
MSDS No.: MPC22
None known
Emergency and First Aid Procedures:

Eye Contact: Flush eyes with water for 15 minutes while lifting upper and lower eyelid. Get prompt medical attention.
Skin Contact: Wash with soap and water. If irritation persists, get prompt medical attention.
Inhalation: Move to fresh air. If breathing becomes difficult get prompt medical attention.
Ingestion: Drink water or milk. Call Poison Control Center, physician, or hospital emergency room immediately.

.

Other Health Warnings:

None known

V. Fire Fighting Measures:
Flash Point: None
F.P. Method:

Lower Explosive Limit: N/D

Upper Explosive Limit: N/D

TCC

Fire Extinguishing Media: Water Fog, Foam, Carbon Dioxide, Dry Chemical

Special Fire Fighting Procedures:

Wear self-contained , positive pressure breathing apparatus and protective clothes. Cool containers exposed to heat with water
fog.
Unusual Fire and Explosion:

Use shield to protect from venting, rupturing, or bursting cans.

VI. Accidental Release Measures:
Steps to be Taken in Case Material is Released or Spilled:

Use appropiate protective equipment. Contain spill and then absorb spill with inert material or rags and scoop into a chemical
waste container. Neutralize remaining traces of material and flush with water followed by liberal covering with sodium bicarbonate.
All clean-up material should be removed and placed in approved containers for disposal. Rinse water may be disposed of down a
sanitary sewer system if authorized by the local municipality.

VII. Handling and Storage:
Precautions to be Taken:

Use with adequate ventilation. Do not take internally. Do not expose to heat or store at temperatures above 120 F. Do no
puncture or incinerate container.
Other Precautions:

Avoid contact with strong oxidizing agents.

VIII. Exposure Controls/Personal Protection:
Ventilation Requirements:

See Section 2 for applicable exposure limits. Use with adequate ventilation. If TLV is exceeded, wear NIOSH approved respirator.
Personal Protective Equipment:

See Section 2 for applicable exposure limits. For prolonged exposure wear protective safety glasses, gloves, and apron.

Friday, January 18, 2008

Page 3 of 4

MSDS - Material Safety Data Sheet
Product Name: CARPET AND UPHOLSTERY ALL PURPOSE FOAM
CLEANER
MSDS No.: MPC22

IX. Physical and Chemical Properties:
Boiling Point: 212 F

Melting Point: N/A

Evaporation Rate (Butyl Acetate = 1): < 1

Vapor Pressure (mm Hg.): N/D

Specific Gravity (H20 = 1): 1.00000

Vapor Density (AIR = 1): N/D

Solubility In Water: Soluble

Appearance and Odor:

Other Information: pH: 11.5 - 12.5

White spray foam with light citrus floral scent

X. Stability and Reactivity:
Stability:

Stable
Incompatibility (Materials to Avoid):

Avoid contact with strong oxidizing agents
Decomposition/By Products:

Carbon Monoxide, Carbon Dioxide
Hazardous Polymerization:

Will not occur

XI. Toxicological Information:
N/D

XII. Ecological Information:
N/D

XIII. Disposal Considerations:
DISPOSAL: This container may be recycled in aerosol recycling centers when empty. Before offering for recycling, empty the can
by using the product according to the label. DO NOT PUNCTURE! If recycling is not available, wrap the container and discard in
the trash. Dispose of unused product in accordance with all local, state government and federal laws and regulations.

XIV. Transport Information:
DOT Hazard Class: ORM-D
Shipping Name: Consumer Commodity
The DOT description is provided to assist in the proper shipping classification of this product and may not be suitable for all shipping
purposes.

XV. Regulatory Information:
See Section 2 for SARA Reportable Chemicals.
USA TSCA: All components of this material are listed on the US TSCA Inventory.

Friday, January 18, 2008

Page 4 of 4

MSDS - Material Safety Data Sheet
Product Name: CARPET AND UPHOLSTERY ALL PURPOSE FOAM
CLEANER
MSDS No.: MPC22

XVI. Other Information:
Do not used in confined area without proper ventilation. Contact lenses may cause further damage in case of splash into eye.
KEEP AWAY FROM CHILDREN AND ANIMALS!
N/E: Not Established
N/D: Not Determined
N/A: Not Applicable
N/AV: Not Available
While Radiator Specialty Company believes this data is accurate as of the revision date, we make no warranty with respect to the
data and we expressly disclaim all liability for reliance thereon. The data is offered solely for information, investigation, and
verification. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or
disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance.

MATERIAL SAFETY DATA SHEET
Complies with OSHA hazard communication standard 29 CFR 1910.1200
Scot Laboratories
16841 Park Circle Drive
Chagrin Falls, OH 44023

Phone:
Fax:
Date:

(440) 543-3033
(440) 543-1825
September 26, 2000

SECTION I - Product Identification
Product Name:
Carpet Shampoo for Extraction Cleaners

HMIS Rating
Health1
Fire0
Reactivity-0
0= minimal, 1= slight, 2= moderate, 3= serious, 4= severe
Code:

237

SECTION II - Hazardous Ingredients/Identity Information - NONE
SECTION III - Physical/Chemical Characteristics
Physical State:
Liquid
Vapor Density (AIR = 1):
Color:
Clear, Lt. Amber
Vapor Pressure (mm Hg):
Odor:
Pleasant
Solubility in Water:
o
Boiling Point:
212 F
Specific Gravity (H2 O):
o
Melting Point:
32 F
Evaporation Rate:

Heavier than air
Unknown
Complete
1.055
< 1 (Butyl Acetate = 1)

SECTION IV - Fire and Explosion Hazard
Flash Point:
Flammability Limits in Air:
Extinguishing Media:

Data
None
N/A
N/A

SECTION V - Reactivity Data
Stability:
Material to Avoid:
Conditions to Avoid:
Hazardous Decomposition or Byproducts:

Stable
Do not mix with other chemicals. Follow instructions on label.
Unknown
Unknown (Hazardous Polymerization will not occur)

Fire Fighting Procedure:
Unusual Fire or Explosion Hazards:

None
None

SECTION VI - Health Hazard Data
Product hazard classification:
None
Carcinogenic ingredients:
Unknown
Effects of overexposure:
Ingestion may cause nausea or diarrhea. May be irritating to eyes.
Medical Conditions aggravated by use:
Unknown
First Aid Procedures:
INGESTION:
Do not induce vomiting, drink plenty of water, contact a physician immediately.
SKIN/EYE CONTACT: Flush with water for 15 minutes. If irritation persists, consult a physician.
SECTION VII - Pre cautions for Safe Handling and Use
In case of Release or Spill:
Recover liquid with absorbent. Mop up or wet vac. Rinse area with water to remove.
Waste Disposal Method:
Small amounts - down drain or sanitary landfill. Large amounts - obey local ordinances.
Handling and Storing:Do not store near heat. Do not freeze.
Other Precautions:
If frozen, thaw to room temperature and mix before using. Do not pour unused portion back into container - it
contaminate product.
SECTION VIII - Control Measures
Gloves:
None
Eye Protection:
None
Other Protection:
None

Respirator:
Ventilation:
Work/Hygienic Practices:

may

None
Local exhaust is normally adequate.
Follow good manufacturing and housekeeping rules.

SECTION IX - Special Precautions - None
SECTION X - Department of Transportation
Shipping Hazard Classification: None
DISCLAIMER
The information contained herein was obtained from current and reliable sources. However, the data is provided without any warranty, expressed or
implied, regarding its correctness or accuracy. Since the conditions for use, handling, storage and disposal of this product are beyond Scot Laboratories'
control, it is the user's responsibility both to determine safe conditions for use of this product and to assume liability for loss, injury, damage or expense
arising from the product's improper use. No warranty, expressed or implied, regarding the product described herein shall be created by or inferred from
any statement or omission in this MSDS. Various government agencies (e.g., DOT, EPA, FDA) may have specific regulations concerning the
transportation, handling, storage, use or disposal of this product which may not be reflected in this MSDS. The user should review these regulations to

ensure full compliance.

Manufactured By:

Product Name:

PRODUCTS CHEMICAL COMPANY

CARPET SPOT CLEANER

6400 Herman Av Cleveland OH 44102

216-281-1155

EMERGENCY: phone number involving spill, leak, fire or accident:
MATERIAL SAFETY DATA

INFOTRAC 800-535-5053

(Prepared According to 29CFR 1910,1200)

1611

SECTION 1 -- PRODUCT IDENTIFICATION

Product Code #

PRODUCT NAME:

HMIS Rating

Health
Fire
Reactivity
Personal Protection

PRODUCT TYPE: CARRPET SPOT CLEANER
COMPANY NAME:
COMPANY ADDRESS:
Proper Shipping Name: COMPOUND, CLEANING LIQUID, NOI

CAS NO.

SULFONIC ACID

27176-87-0

2 BUTOXYETHANOL

111-76-2

...
...
...
...

1
0
0
B

Formula Proprietary

SECTION 2 -- INGREDIENTS
CHEMICAL NAME

1611

PERCENT WT

Revision Date: 08/06

313 / CHEM

5 to 10

N

7.813

Y

PEL

TWA-TLV

CARCINOGEN
NO

25ppm

25ppm

Yes

NOTE: This product contains materials subject to the reporting requirements of SARA, Section 313 Emergency Planning & Right-to-Know Act.
The balance of the chemicals in this mixture are either considered nonhazardous or are below the listing limits for hazardous substances.
These chemicals are considered trade secrets. The specific identity of these chemicals is available to health professionals.

SECTION 3 -- PHYSICAL DATA

SECTION 4 -- FIRE AND EXPLOSION DATA

212
Boil Point
Specific Gravity
Volatile:
Vapor Press.(mmhg) 20@68f
VaporDensity (AIR=1) N/A
pH
Soluble in water Evap. Rate(H20=1) = 1
VOC = 82.9 (g/l) VOS of Concentrate = 7.9%
CLEAR LIQUID/CHARACTERISTIC
Appearance / Odor:

1.046
90
10

SECTION 5 -- REACTIVITY DATA

Flash Point:
N/A (TCP)
Flammable Limits:
N/A
Non-Flammable
Extinguishing Media:
N/A
Special Fire Fighting Procedures:
Fire, Explosion Hazards:
N/A
SECTION 6 -- STORAGE AND HANDLING

Stability: STABLE
Hazardous Polymerization: WILL NOT OCCUR
NONE KNOWN
Incompatibility:
NONE KNOWN
Hazardous Decomposition:

KEEP OUT OF THE REACH OF CHILDREN
For industrial use only

SECTION 7 -- HEALTH AND FIRST AID
EYES: May Cause eye irritation.

EYES: Flush eyes with large amounts of water. Consult
physician if irritation continues.

SKIN: May cause skin irritation.

SKIN: Flush with water.

INHALATION:

INHALATION: Move person to fresh air. Consult physician

INGESTION: May cause irritation to the intestine, mouth, throat,
& esophagus.

INGESTION: Do not induce vomiting or give anything by mouth
to an unconscious person. Consult Physician.

SECTION 8 -- SPECIAL PROTECTION DATA
Respiratory Protection: Adequate ventilation
Ventilation as required to maintain TLV
Protective Gloves: Rubber Gloves Recommended.
Eye Protection: Safety Glasses Recommended
N/A = Not Applicable

SECTION 9 -- SPILL OR LEAK PRECAUTIONS
Steps to be taken in case of spill or leak:
Mop or absorb for disposal
Waste disposal Method:
Sewer or incinerate with local approval.

CMP = Complete
END OF GENERATE

Spot Shot Carpet and Stain Remover
5/25/05

Material Safety Data Sheet (MSDS)
Section 1 - Chemical Product and Company Identification
MANUFACTURER/SUPPLIER:
US Office:
Spot Shot Products
A Division of WD-40 Company
1061 Cudahy Place
San Diego, CA 92110
Information Phone #: (619) 275-1400
Emergency Phone # 24 hr:
Chemtrec: (800) 424-9300 –
Designated for use only in the event of chemical
emergencies involving a spill, leak, fire exposure or
accident involving chemicals.

Canadian Office:
WD-40 Products [Canada] LTD.
P.O. Box 220
Toronto, Ontario M9C 4V3
Information Phone #: (416) 622-9881
Emergency Phone # 24 hr:
Canutec: (613) 996-6666 –
Designated for use only in the event of chemical
emergencies involving a spill, leak, fire exposure or
accident involving chemicals

PRODUCT NAME: SPOT SHOT CARPET STAIN REMOVER (14 oz.)
FORMULA: Mixture
GENERAL CLASS: Aerosol Cleaning Aid
MSDS DATE OF PREPARATION: May 25, 2005

HMIS Rating
Health: 2
Flammability: 2
Reactivity: 1

Section 2 - Composition/Information on Ingredients
Ingredient
2-Butoxyethanol
Liquefied Petroleum Gas
See Section 8 for Exposure Limits

CAS #
111-76-2
68476-85-7

Weight Percent
Less than 25%
Less than 10%

Section 3 – Hazards Identification
AEROSOL SPRAY. PLEASANT ODOR. CAUTION! CONTENTS UNDER PRESSURE. AVOID HEAT
AND FLAMES. MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. HARMFUL
IF INTENTIONALLY INHALED. HARMFUL IF ABSORBED THROUGH SKIN. MAY AFFECT
LIVER, KIDNEYS, BLOOD, LYMPHATIC SYSTEM OR CENTRAL NERVOUS SYSTEM.
Avoid breathing concentrated vapors. Use with adequate ventilation. Avoid getting on skin, in eyes, and on
clothing. Wash thoroughly after handling.
Potential Health Effects:
Primary Routes of Entry: Inhalation, skin and eye contact.
Acute Effects:
Inhalation: Excessive inhalation can cause headache, drowsiness, nausea and lack of coordination. Can
cause irritation of respiratory tract.
Skin Contact: Can cause skin irritation. Toxic amounts may be absorbed through the skin with symptoms
similar to those under inhalation and ingestion.
Eye Contact: Liquid sprayed into eyes causes corneal irritation and pain.
Ingestion: Symptoms are similar to those of inhalation including pain, diarrhea and vomiting. May cause
damage to the liver and kidneys.
Chronic Effects: 2-butoxyethanol has caused lymphatic system, blood, liver and kidney damage.
Medical Conditions Aggravated by Exposure: Pre-existing respiratory, skin, eye, liver, kidney and
lymphatic disorders.

Page 1 of 4

Spot Shot Carpet and Stain Remover
5/25/05
Section 4 – First Aid Measures
IF INHALED: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical attention.
IF SWALLOWED: Do not induce vomiting. Call a physician or poison control center. Give one eightounce glass of water to drink if the patient if conscious and responsive. Never give anything by mouth to an
unconscious person.
IF ON SKIN: Wash skin with soap and water. Remove contaminated clothing and wash before reuse. Get
medical attention if irritation persists or symptoms of exposure develop.
IF IN EYES: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Get medical attention if irritation persists.
Section 5 – Fire Fighting Measures
Flammability Properties: Not flammable per flame projection test.
Extinguishing Media: Carbon dioxide, dry chemical, water fog
Special Fire Fighting Instructions: Keep fire-exposed containers cool with water spray. In the event of a
fire, wear full protective clothing and a NIOSH approved self-contained breathing apparatus with full face
piece and operated in positive pressure mode.
Unusual Fire and Explosion Hazards: Exposure of containers to extreme heat and flames can cause them to
rupture often with violent force and subsequent fire.
Section 6 – Accidental Release Measures
Ventilate area of spill and remove all sources of ignition. Observe all hazards mentioned in Section 3. Wear
personal protective equipment specified in Section 8.
Spills: Wipe, scrape or soak up contents in an inert material. Pick up spill for recovery or disposal and place
in a closed container.
Section 7 – Handling and Storage
Handling: Use with adequate ventilation. Do not smoke or use around open flames or sources of extreme
heat. Intentional misuse by deliberately concentrating vapors and inhaling can be harmful or fatal. Avoid
getting in eyes or on skin and clothing. Do not breathe vapors. Wash thoroughly after handling, and wash
contaminated clothing before reuse.
Storage: Store in a cool, dry ventilated area. Protect from physical damage. Do not store in direct sunlight,
near open flames or above temperatures greater than 120 F. Do not place can in hot water or near radiators,
stoves or other sources of heat.
Section 8 – Exposure Controls/Personal Protection
Occupational Exposure Limits
2-Butoxyethanol
Liquefied Petroleum Gas

20 ppm TWA ACGIH-TLV
50 ppm TWA OSHA PEL skin
1000 ppm TWA ACGIH TLV
1000 ppm TWA OSHA PEL (as propane)

The Following Controls are Recommended for Normal Consumer Use of this Product
Engineering Controls: Good general ventilation is adequate for normal use. When using large amounts,
open windows or use a fan to ventilate the area.
Personal Protection:
Eye Protection: Avoid eye contact. Always spray product away from your face.
Skin Protection: Avoid prolonged or repeated skin contact. Wash hands with soap and water after use.
Respiratory Protection: None required. Use in a well-ventilated area.

Page 2 of 4

Spot Shot Carpet and Stain Remover
5/25/05

For Bulk Processing or Workplace Use the Following Controls are Recommended
Engineering Controls: A system of local and/or general exhaust is recommended to control airborne levels
below the occupational exposure limits.
Personal Protection:
Eye Protection: Safety glasses with side shields or chemical goggles are recommended.
Skin Protection: Wear appropriate protective clothing and chemical-resistant gloves to prevent skin contact.
Wash thoroughly after handling.
Respiratory Protection: Use in a well-ventilated area. Appropriate respiratory protection shall be worn
when applied engineering controls are not adequate to protect against inhalation exposure.
Work/Hygiene Practices: Eye wash facilities should be available. Wash hands before eating and smoking.
Section 9 – Physical and Chemical Properties
Vapor Pressure:
Specific Gravity (Water = 1):
Boiling Range: Solubility in water (20 C):
Appearance and Odor:

55 psig @ 70 F
(propellant)
N/D
43 F – 343F (propellant)
miscible
Aerosol spray. Pleasant
odor.

Vapor Density (air = 1):

>1

Evaporation Rate (Butyl
Acetate = 1):
% Volatiles by Volume:
VOC’s lbs/gal:
Coefficient of Water/Oil
Distribution:

Less than 1
N/D
N/D
N/D

Section 10 – Stability and Reactivity
Stability: Stable under normal storage conditions.
Hazardous Polymerization: Will not occur
Conditions to Avoid: Extreme heat, sources of ignition, physical damage to can.
Incompatibilities: Avoid strong oxidizers, strong bases, acids and chlorinated solvents.
Hazardous Decomposition Products: Burning can produce carbon monoxide and/or carbon dioxide and
trace amounts of phosgene gas.
Section 11 – Toxicological Information
2-Butoxyethanol
Inhalation LC50 (ppm) 4-HR: 450 (RAT) Acute oral LD50 (mg/kg): 1,480 (RAT)
Acute Dermal LD50 (kg/kg): 490 (RBT) Irritation, Skin, open, 500 mg: MILD (RBT)
Irritation, Eye, 18 mg: SEVERE (RBT)
Liquefied Petroleum Gas: No data is available
Section 12 – Ecological Information
This product is not expected to be harmful for the environment.
Section13 Disposal Considerations
Aerosol containers should not be punctured, compacted in home trash compactors or incinerated. Empty
containers may be disposed of through normal waste management options. Dispose of all waste product,
absorbents, and other materials in accordance with applicable Federal, state and local regulations.
Section 14 – Transportation Information_
DOT Classification: Consumer Commodity ORM-D

Page 3 of 4

Spot Shot Carpet and Stain Remover
5/25/05
Section 15 – Regulatory Information
SARA 302: None found
SARA 311/312 Hazard Categories: Immediate (acute), Chronic (delayed), Flammability
SARA 313: Toxic Chemicals: 2-butoxyethanol 17% by wt. (glycol ether compound)
OSHA: Hazardous under criteria of the OSHA Hazard Communication Standard (29 CFR 1910.1200)
California Proposition 65: No components listed.
Canadian Environmental Protection Act: All of the ingredients are listed on the Canadian Domestic
Substances List.
Canadian WHMIS Classification: Class D, Division 2, Subdivision B (Toxic material causing other chronic
effects)
This MSDS has been prepared according to the criteria of the Controlled Products Regulation (CPR) and
the MSDS contains all of the information required by the CPR.
Section 16 – Other Information__
HMIS Hazard Rating: Health – 2 (moderate hazard), Fire Hazard – 2 (moderate hazard),
Reactivity – 1 (low hazard)
Prepared By: Industrial Health & Safety Consultants, Inc.
Revision Date: 05/25/2005

Supercedes: 02/18/05

This MSDS complies with OSHA guidelines set by 29 CFR 1910.1200 and the Canadian WHMIS
regulations. The foregoing information has been compiled from sources believed to be accurate but is not
warranted to be. Recipients are advised to confirm in advance of need that data is correct. Standards change
without notice. It is the responsibility of the recipient to insure that their personnel have been notified of
any changes which may affect them. The data provided on this MSDS are not meant to be used as
specifications, only as guideline information as to the safe use of this product. User should refer to
applicable laws before use.
N/D = Not Determined N/E = Not Established N/A = Not Applicable

Page 4 of 4

Material Safety Data Sheet
DRAIN FLOW Inhibited Sulfuric Acid

Conforms with OSHA form OMB No. 1218-0072

Roebic Laboratories, Inc.
25 Connair Road, PO Box 927
Orange, CT 06477

Emergency Telephone NumbersROEBIC (203) 795-1283
CHEMTREC (800) 424-9300

(Note: Emergency numbers are to be used only in the event of chemical emergencies involving a spill,
leak, fire, exposure, or accident)
Date: 01/01/01
Preparer: Dave Lawler

Packaging Lot No.: Stamped on carton top

SECTION I – PRODUCT IDENTIFICATION
Product Name
Common Synonyms
Chemical Family
Formula
CAS No.
Precautionary Labeling

US Precautionary Labeling

International Labeling

DRAIN FLOW
Drain Opener, (Blended Sulfuric Acid)
Sulfuric Acid
H2S04 (Approx. 90%)
7664-93-9 (sulfuric acid)
Health 3
Flammability 0
Reactivity 0
Contact 2
Do not get in eyes, on skin, or on clothing. Do not take internally. Avoid
breathing mist or fumes. Keep separate from powdered metals,
organics, combustible materials, solvents, oxidizers, alkalis, and amines.
Keep out of reach of children.
Do not get in eyes, on skin, or on clothing. Do not take internally. Avoid
breathing mist or fumes. Keep separate from powdered metals,
organics, combustible materials, solvents, oxidizers, alkalis, and amines.
Keep out of reach of children.
SECTION II – COMPONENTS

Component
Diluted Sulfuric Acid
Fortifying Agents

CAS No.
Wt %
7664-93-9
80
N/A (none carcinogenic)

OSHA/PEL
N/A

ACGIH/TLV
1-mg/m3

SECTION III – PHYSICAL DATA
Boiling Point
Freezing Point
Specific Gravity
Water Solubility
pH
Viscosity
Odor
Appearance

221°F 105C
-20°F -10C
1.75
Complete
1.25
30 SSU @ 100F 32.7C
Sulfur (sulfur trioxide fumes)
Viscous Black Liquid (for safety identification)
SECTION IV – FIRE, REACTIVITY, & EXPLOSION DATA

Non-Flammable:
Extinguishing Media:
Fire Fighting Techniques:
Toxic Gas Produced:
Explosion Data:

But explosive hydrogen gas can accumulate if transferred into metal
containers.
Use extinguishing media appropriate for surrounding fire.
Wear full protective clothing including self-contained breathing apparatus
with full-face piece operated in a positive pressure mode.
Reaction with certain metals can produce flammable hydrogen gas.
Provide adequat e ventilation when applying.
No sensitivity to mechanical impact. No sensitivity to static discharge.

1

SECTION V – HEALTH HAZARD DATA
Toxicity of Components

Carcinogenic: None Identified
Reproductive effect: None identified
Effects of Overexposure
Inhalation: Irritation of upper respiratory tract
Skin Contact: Irritation
Eye Contact: Irritation
Ingestion: Internal irritation
Emergency and First Aid Procedures
Inhalation: Remove from contaminated atmosphere.
Apply artificial respiration if necessary. Call a physician.
Skin Contact: Flush with cool water, then baking soda solution. If
irritation persists get medical attention.
Ingestion: Give large quantities of water or milk. Do not induce
vomiting. Do not drink carbonated water. Call a physician.
Eye Contact: Immediately flush with large quantities of water. Call a
physician.
SECTION VI – REACTIVITY DATA
Stability
Conditions to Avoid

Decomposition

Stable
Do not allow product to come in contact with strong alkalis. May cause eruption
of hot acid when poured in drain. Do not mix with other household chemicals.
Never add water to acid while in container because of violent reaction. When
empty rinse thoroughly with water before discarding.
Sulfur fumes
SECTION VII – SPILLS AND DISPOSAL PROCEDURES

Small Spill
Large Spill

Neutralize with sodium bicarbonate or soda ash and flush with large amounts of
water.
Pump to a soda ash and slack lime solution, then dispose of with large amounts
of water.
SECTION VIII – INDUSTRIAL PROTECTIVE EQUIPMENT

Ventilation:
Respiratory Protection:

Eye and Skin Protection:

Use general or local exhaust ventilation to meet TVL
requirements and to minimize exposure.
Respiratory protection is required if airborne concentrations
exceed TLV. Above this level use NIOSH approved equipment
with full-face piece. Follow respirator manufacturer’s
recommendations.
Safety goggles, protective clothing and rubber or plastic gloves
are recommended.

SECTION IX – STORAGE AND HANDLING PRECAUTIONS
Storage

Store in high-density polyethylene, rubber lined, fiber glass, or 316 stainless steel
containers. Do not store in extreme heat or cold areas. Avoid contact with organic
matter. DRAIN FLOW is a strong chemical digester of dead organics.
SECTION X - TRANSPORTATION DATA AND ADDITIONAL INFORMATION

Domestic (D.O.T.)
Proper Shipping Name
Hazard Class
UN/NA
Labels
Frt. Classification

Sulfuric Acid 66 Be (blended with buffing agents)
Corrosive Material
UN1830/NA
Corrosive
Cleaning Compound – Class 55

2

International (I.M.O.)
Proper Shipping Name
Hazard Class
UN/NA
Labels
Marine Shipping
Air Shipping

Sulfuric Acid 66 Be (blended with buffing agents)
Corrosive Material
UN1830/NA
Corrosive
Non-pollutant
Not allowed on passenger flights
SECTION XI – OTHER COMMENTS

This document is intended only as a guide. The user is responsible for determining the precautions and
dangers of this chemical formulation for his/her particular application. Supplier cannot warn of all the
potential dangers of use or interaction with other chemicals or materials, therefore; disclaims any
warranties, expressed or implied with regard to its merchantability or its fitness for a particular purpose.
The user is responsible for reading all precautionary information and handling accordingly.

3

Institutional 80240

JSDYL

T

MATERIAL SAFETY
DATA SHEET
I - PRODUCT IDENTIFICATION AND USE

PRODUCT NAME:
USE:

MSDS ID: 80240

DISHWASHER ALL

Machine Warewashing Detergent

SUPPLIER:

EMERGENCY PHONE:

JohnsonDiversey Canada, Inc.
2401 Bristol Circle
Oakville Ontario, L6H 6P1, Canada

WHMIS CLASSIFICATION:
CHEMICAL FAMILY:

1-800-668-7171

D2B

TRADE NAME / SYNONYMS:

Chlorinated alkali

CHEMICAL NAME:

not applicable

not applicable

II - HAZARDOUS INGREDIENTS
HAZARDOUS INGREDIENT

% w/w

CAS #

LD50 / LC50

Route / Species

30-60

000497-19-8

LD50 4090 mg/kg

oral/rat

Sodium carbonate
Disodium dichlorosiocyanuratedihydrate
Sodium metasilicate

1-5

051580-86-0

LD50 620 mg/kg

oral/rat

7-13

006834-92-0

LD50 1153 mg/kg

oral/rat

1-5

069227-21-0

LD50 3400 mg/kg

oral/rat

Linear alcohol ethoxylate/propoxylate

III - HANDLING AND DISPOSAL PROCEDURES
PERSONAL PROTECTIVE EQUIPMENT:
Gloves:

Nitrile, Neoprene or Natural rubber

Respiratory:

Eye:

safety glasses

NIOSH approved dust mask as required.

SPECIAL HANDLING PROCEDURES AND EQUIPMENT:
VENTILATION REQUIREMENTS:

WASTE DISPOSAL:

not required

Other: not required
Avoid breathing dust. Avoid eye and skin contact.

General ventilation.

INCOMPATIBILITY (Material to Avoid):
SPILL PROCEDURES:

Footwear:

Strong acids

Sweep or scoop up material for disposal.

Dispose according to municipal, provincial, and federal regulations.

STORAGE / SHIPPING REQUIREMENT:

Store in a cool dry area in a closed container.

IV - PHYSICAL PROPERTIES
APPEARANCE / ODOUR:

White, free-flowing powder with blue speckles - floral odour

S.G. / BULK DENSITY(g/cc):

1.00 - 1.09

VAPOUR PRESSURE (mmHg):
ODOUR THRESHOLD:
FREEZING POINT:

pH:

not applicable

VAPOUR DENSITY (air=1):

0.2-0.4 ppm chlorine

BOILING POINT:

not applicable

SOLUBILITY IN WATER:

(0.1% solution) 11.0 ± 0.5

PERCENT VOLATILE:

soluble

not applicable

not applicable
not applicable

EVAPORATION RATE (water=1):

not applicable

V - TOXICOLOGICAL PROPERTIES
EFFECTS OF ACUTE EXPOSURE TO MATERIAL:
EYES:

May cause severe irritation. May cause permanent damage if not treated promptly.

SKIN:

Repeated or prolonged contact may result in irritation.

INGESTION:

May cause severe irritation of the digestive tract. May cause temporary or permanent damage if not treated promptly.

INHALATION: Breathing dust may cause respiratory irritation.

JohnsonDiversey Material Safety Data Sheet:

DISHWASHER ALL

Page

1 of 2

Institutional 80240

LD50 (calculated):

4462 mg/kg

OTHER TOXIC EFFECTS:

LC50 (calculated):

Not applicable

TLV (Sodium metalsilicate): 2 mg/m3

EFFECTS OF CHRONIC
EXPOSURE TO MATERIAL:

None known.

VI - FIRST AID MEASURES
EYES:

Flush eyes with plenty of water for at least 15 minutes. Hold eyelids open while rinsing. Contact a physician immediately.

SKIN:

Flush affected area thoroughly with water. If irritation develops, contact a physician.

INGESTION:

Drink large volumes of water . Never give anything by mouth to an unconscious patient. Do not induce vomiting. Contact a
physician immediately.

INHALATION: Remove patient to fresh air. Get medical attendion for any breathing difficulty.

VII - FIRE AND EXPLOSION DATA
FLAMMABLE:

No.

FLASH POINT, °C:

not applicable

EXTINGUISHING MEDIA:

Water [x]

AUTO IGNITION TEMPERATURE,°C:
Dry Chemical [x]

Carbon Dioxide [x]

SPECIAL FIRE FIGHTING PROCEDURES:

Wear self-contained breathing apparatus.

HAZARDOUS COMBUSTION PRODUCTS:

Chlorine gas. Oxides of carbon, nitrogen.

EXPLOSIVE SENSITIVITY TO:

Foam [x]

N/Ap

Other [ ]

not applicable

VIII - REACTIVITY DATA
STABILITY:

Stable [x]

CONDITIONS TO AVOID:

Unstable [ ]
not applicable

INCOMPATIBILITY (Material to Avoid) :
HAZARDOUS DECOMPOSITION PRODUCTS:
REACTIVITY:

Acids.
Contact with acids generates chlorine gas. Chloramines.

not dangerously reactive

IX - MSDS PREPARATION
SOURCES USED:

PREPARATION DATE:

RTECS, ChemInfo

PREPARED BY:

April 15, 2003

JohnsonDiversey Canada, Inc.
Regulatory Department
Institutional Division
Phone (905) 829-1200

Information on this form is furnished in compliance with the Regulations respecting Controlled Products under the Hazardous Products Act and is
not to be used for any other purpose, nor is it to be reproduced or published. JohnsonDiversey Canada assumes no responsibility for injury to any
person or property resulting from any use of the material if reasonable safety procedures are not adhered to. In addition, JohnsonDiversey Canada
assumes no responsibility for injury to any person or property resulting from any abnormal use or theft of the material, even if reasonable safety
procedures are followed. Each user assumes the risk in his use of the material and should review the data and recommendations in the specific
context of the intended use.

JohnsonDiversey Material Safety Data Sheet:

DISHWASHER ALL

Page

2 of 2

Industrial

______________________________________________________________________________
MATERIAL
__________________________
SAFETY DATA SHEET
Page
1 of 3
Revised
2/02/04
WHITE LOTION HAND SOAP
Replaces 8/12/03
Printed
2/03/04
MSDS
______________________________________________________________________________
ID: 04617
______________________________________________________________________________
______________________________________________________________________________
I. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name:
Product Discriptor:
MANUFACTURER: JOHNSONDIVERSEY, INC.
3630 E. KEMPER ROAD
CINCINNATI, OH. 45241

EMERGENCY PHONE NUMBER:(800)851-7145

______________________________________________________________________________
______________________________________________________________________________
II. HAZARDOUS COMPONENTS
Component Name
CAS Number
%
Exposure Limits Units
----------------------------- ----------- ---------- ---------------- ------WHITE LOTION HAND SOAP
>30%
None established
______________________________________________________________________________
______________________________________________________________________________
III. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
SIGNS AND SYMPTOMS OF OVEREXPOSURE
ACUTE:
MAY IRRITATE EYES
CHRONIC: SAME AS ACUTE
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Sensitive skin
______________________________________________________________________________
______________________________________________________________________________
IV. FIRST AID MEASURES
______________________________________________________________________________
______________________________________________________________________________
V. FIRE FIGHTING MEASURES
FLASH POINT (degrees F): NONE
FLAME EXTENSION: N/A
FLAMMABLE LIMITS IN AIR BY VOLUME:
LEL: N/A
UEL: N/A
EXTINGUISHING MEDIA: CO2, FOAM, DRY CHEMICALS
FIRE FIGHTING INSTRUCTIONS: Wear full protective gear and positive pressure
breathing apparatus (SCBA) in fire area.
______________________________________________________________________________
______________________________________________________________________________
VI. ACCIDENTAL RELEASE MEASURES
IF MATERIAL IS RELEASED OR SPILLED:
FLUSH TO DRAIN AND RINSE TO AVOID SLIPPERY CONDITIONS
This product does not contain a reportable quantity (RQ) under CERCLA.
______________________________________________________________________________
______________________________________________________________________________
VII. HANDLING AND STORAGE
HANDLING AND STORAGE PRECAUTIONS: DO NOT SPILL. WILL CAUSE A SLICK WORKING
SURFACE. KEEP FROM FREEZING. IF FROZEN, THAW AND MIX TO MAKE USABLE. DO NOT
PRESSURE CONTAINER TO EMPTY.

Industrial

______________________________________________________________________________
MATERIAL
__________________________
SAFETY DATA SHEET
Page
2 of 3
Revised
2/02/04
WHITE LOTION HAND SOAP
Replaces 8/12/03
Printed
2/03/04
MSDS
______________________________________________________________________________
ID: 04617
______________________________________________________________________________
______________________________________________________________________________
VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION
EYE/FACE PROTECTION: NONE
PROTECTIVE GLOVES: NONE
OTHER PROTECTIVE CLOTHING/EQUIPMENT: NONE
ENGINEERING CONTROLS:
MECHANICAL VENTILATION: PRODUCING NORMAL AIR DILUTION
LOCAL VENTILATION: NO
______________________________________________________________________________
______________________________________________________________________________
IX. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE AND ODOR:
BOILING POINT (DEG F): 212
FREEZING POINT: Not determined
SPECIFIC GRAVITY/BULK DENSITY:
pH:
pH 1% SOLUTION: Not Determined
VOLATILE BY VOLUME: 80
VAPOR PRESSURE(mmHg): 17.5
at 20 F
VAPOR DENSITY: N/A
______________________________________________________________________________
______________________________________________________________________________
X. STABILITY AND REACTIVITY
CHEMICAL STABILITY: STABLE
INCOMPATIBILITY WITH OTHER MATERIALS: CO WITH INCOMPLETE COMBUSTION
HAZARDOUS DECOMPOSITION PRODUCTS: None known.
HAZARDOUS POLYMERIZATION: NONE
______________________________________________________________________________
______________________________________________________________________________
XI. TOXICOLOGICAL INFORMATION
No data available.
TOXICITY TEST DATA:
No data available.
______________________________________________________________________________
______________________________________________________________________________
XII. ECOLOGICAL INFORMATION
ECOTOXICITY TEST DATA: No data available.
ENVIRONMENTAL FATE: No data available.
______________________________________________________________________________
______________________________________________________________________________
XIII. DISPOSAL CONSIDERATIONS
RCRA REGULATED: Not Regulated.
POUR OR FLUSH DOWN DRAIN OR LAND FILL. CONTAINS NO PHOSPHATES, 100%
BIODEGRADABLE. USE UNTIL LESS THAN 1 INCH REMAINS IN CONTAINER, EMPTY
CONTAINER TRIPLE RINSE WITH WATER, ADD TO OPERATION REMOVE OR DEFACE LABEL
BEFORE SELLING CONTAINER OR DISPOSAL
______________________________________________________________________________
______________________________________________________________________________
XIV. TRANSPORT INFORMATION
Please refer to the Bill of Lading/receiving documents for up to date shipping
information.

Industrial

______________________________________________________________________________
MATERIAL
__________________________
SAFETY DATA SHEET
Page
3 of 3
Revised
2/02/04
WHITE LOTION HAND SOAP
Replaces 8/12/03
Printed
2/03/04
MSDS
______________________________________________________________________________
ID: 04617
______________________________________________________________________________
______________________________________________________________________________
XV. REGULATORY INFORMATION
U.S. Federal Regulations:
TSCA: All ingredients in this product are on TSCA inventory.
HAPS: Contains no hazardous air pollutants.
VOC CONTENT (EPA Method 24A): % VOC:
Lb/Gal VOC:
CERCLA/EPCRA:
Section 313 Toxic Chemicals: None
SARA Section 311/312:
ACUTE:NO
CHRONIC:NO
FIRE:NO
REACTIVITY:NO
SUDDEN RELEASE OF PRESSURE:NO
LISTED CARCINOGEN: NONE
NTP: NO
IARC: NO
OSHA: NO
HMIS RATINGS: HEALTH:
FIRE:
REACTIVITY:
PERSONAL PROTECTIVE EQUIPMENT:
NFPA RATING: HEALTH:
FIRE:
REACTIVITY:
SPECIAL:
STATE RIGHT-TO-KNOW INFORMATION:
CALIFORNIA PROPOSITION 65:
None of the ingredients are on the California proposition 65 list.
______________________________________________________________________________
______________________________________________________________________________
XVI. OTHER INFORMATION
DISCLAIMER: The information contained in this material safety data sheet is
based on the knowledge of this specific product and current national legislation. It applies to the product as sold, use dilutions may be less hazardous.
It may not be valid for this material if used in combination with any other
materials or in a process. It is the user's responsibility to evaluate the
handling, and use.

MATERIAL SAFETY DATA SHEET
Effective Date: 08/06

(Prepared According To 29 CFR 1910.1200)

N/A = Not Applicable

SECTION 1 - PRODUCT IDENTIFICATION
Product Name: North Woods™ Natures Stuff
Chemical Family: N/A
Generic Name: Citrus Hand Cleaner
Formula: N/A
Suppliers Name: SUPERIOR CHEMICAL CORP.
Suppliers Address: 1331 Wisconsin Avenue, Sheboygan, WI 53081
Phone: 800-242-7694
EMERGENCY PHONE: 800-535-5053

NPCA Hazardous Materials
Identification System

Health

0

Flammability

1

Reactivity

0

Maximum Personal Protection

A

SECTION 2 - HAZARDOUS INGREDIENTS
CHEMICAL NAME

CAS NO.

WT.%

PEL

TWA-TLV

STEL-TLV

CARCINOGEN

No hazardous ingredients.

SECTION 3 - PHYSICAL DATA
Specific Gravity: 0.963
Boiling Range (˚F): 175°F
Vapor Density: <1.0
Vapor Pressure: N/D
pH: 6.8 - 7.4
% Volatile: N / A
Evaporation Rate: >1.0
Solubility in Water: Soluble
Physical Description: Yellow, opaque liquid; pleasant citrus fragrance.

SECTION 5 - REACTIVITY DATA

SECTION 4 - FIRE & EXPLOSION HAZARD DATA
Flash Point (method used): N / A
Upper Explosive Limit: N/A
Lower Explosive Limit: N/A
Extinguishing Media: Foam, carbon dioxide, dry chemical.
Special Fire Fighting Procedures: Self contained breathing apparatus.
Unusual Fire & Explosion Hazards: Cool fire exposed containers with
water spray.

SECTION 6 - STORAGE & HANDLING INFO

Hazardous Polymerization: Will not occur.
Stability: Stable
Precautions To Be Taken In Handling & Storage:
Incompatibility (materials to avoid): Strong acids and oxidizing agents. Keep out of reach of children. For institutional and industrial use only.
Store in a cool, dry place, away from heat or open flame. Keep continer
slightly closed when not in use.
Hazardous Decomposition Products: Thermal decomposition may
yield oxides of carbon.

SECTION 7 - HEALTH HAZARDS AND FIRST AID
Effects of Overexposure
Primary Route of Entry:
Skin: Irritation.

First Aid
Procedures:
Skin: Wash with soap and water. If irritation persists, obtain medical
attention.

Eyes: Severe irritation, redness and tearing.

Eyes: Flush eyes and under eyelids with plenty of cool water for at least 15
minutes. Obtain medical attention if irritation persists.

Inhalation: None under normal use.

Inhalation: Remove person to fresh air.

Ingestion: Gastrointestinal irritation, nausea, vomiting, diarrhea.

Ingestion: Contact physician or poison center immediately. DO NOT
INDUCE VOMITING. Never give anything by mouth to an
unconscious person.

SECTION 8 - SPECIAL PROTECTION INFORMATION
Respiratory Protection: Use adequate ventilation.

Ventilation: General ventilation should be sufficient for most conditions.
Local exhaust ventilation may be necessary for some operations.

Protective Gloves: Not required.
Other Protective Equipment: None.

Eyes: None.

SECTION 9 - SPILL OR LEAK PROCEDURES
Steps to be taken in case material is released or spilled:
Mop up or otherwise absorb and hold material for disposal.

Waste disposal method:
Any method in accordance with applicable laws.

Notice to reader: To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability
whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials
may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

MATERIAL SAFETY DATA SHEET
SECTION I – MATERIAL IDENTIFICATION AND USE
MATERIAL NAME: SUPER STRENGTH BOWL CLEANER

4521-253
4521-253

900mL

MANUFACTURERS NAME:
CP INDUSTRIES LTD.
225 BLACK STREET
FERGUS, ONTARIO N1M 1A5

SUPPLIERS NAME:
HOME HARDWARE
34 HENRY STREET WEST
ST JACOBS, ONTARIO N0B 2N0

EMERGENCY TELEPHONE NUMBER: (613) 996-6666

EMERGENCY TELEPHONE NUMBER: (613) 996-6666

Non-Office Hours, Weekends, or Holidays – (CANUTEC) Call Collect

Non-Office Hours, Weekends, or Holidays – (CANUTEC) Call Collect

CHEMICAL NAME
Not Applicable (mixture)
MOLECULAR WEIGHT
Not Applicable

CHEMICAL FAMILY
Mineral Acid
TRADE NAME AND SYNONYMS
Not Available

CHEMICAL FORMULA
Not Applicable
MATERIAL USE
WHMIS CLASS
Toilet Bowl Cleaner
E D1A

SECTION II – HAZARDOUS INGREDIENTS OF MATERIAL
HAZARDOUS INGREDIENTS

Hydrogen Chloride

APPROXIMATE
CONCENTRATION %

10 - 20

C.A.S.N.A.

“EXPOSURE LIMITS”

LD50 / LC50
SPECIFY SPECIES & ROUTE

007647-01-0

TLV (ACGIH) 5 ppm
Ceiling

Hydrochloric Acid:
LD50 Not Determined
LC50 3124 ppm for 1 hour
(inhalation/rat)

SECTION III – PHYSICAL DATA FOR MATERIAL
PHYSICAL STATE
GAS LIQUID X SOLID

ODOUR AND APPEARANCE
ODOUR THRESHOLD
Clear dark blue liquid, slight pungent odour Not Available

SPECIFIC GRAVITY
1.08

VAPOUR PRESSURE (mm)
Not Available

VAPOUR DENSITY (Air=1)
Not Available

BOILING POINT (°C)
Not Available

EVAPORATION RATE
Not Available

FREEZING POINT (°C)
SOLUBILITY IN WATER
-10°C approx.
Infinite
COEFFICIENT OF WATER/OIL DISTRIBUTION: Not Available

% VOLATILE (by volume)
99% (approx.)

pH
Strong acid less than 1

SECTION IV – FIRE AND EXPLOSION DATA
FLAMMABILITY
YES
NO X

IF YES, UNDER WHAT CONDITIONS

MEANS OF EXTINCTION:
None Required. Not Flammable.
SPECIAL PROCEDURES:
Hydrochloric acid itself is non-flammable. There is, however, a latent fire or explosion hazard due to
hydrogen gas generated when acid is in contact with metals. Wear full protective equipment including self contained breathing apparatus.
FLASH POINT (°C) AND METHOD: None
AUTO IGNITION TEMPERATURE (°C): Not Applicable
UPPER EXPLOSION LIMIT (% BY VOLUME): Not Applicable LOWER EXPLOSION LIMIT (% BY VOLUME): Not Applicable
HAZARDOUS COMBUSTION PRODUCTS: Toxic and Corrosive HCL Gas may be released.
EXPLOSION DATA SENSITIVITY TO MECHANICAL IMPACT: Not Applicable
RATE OF BURNING
Not Applicable

EXPLOSIVE POWER
Not Applicable

SENSITIVITY TO STATIC DISCHARGE
Not Applicable

SECTION V – REACTIVITY DATA
CHEMICAL STABILITY
IF NO, UNDER WHAT CONDITIONS?
YES X NO
INCOMPATIBILITY TO OTHER SUBSTANCES IF SO, WHICH ONES?
YES X NO
REACTIVITY AND UNDER WHAT CONDITIONS: Contact with alkalis will generate heat. Contact with most metals will generate
hydrogen gas. Contact with oxidizing chlorinated materials will generate toxic chlorine gas.
HAZARDOUS DECOMPOSITION PRODUCTS: See above

MATERIAL NAME: SUPER STRENGTH BOWL CLEANER
SECTION VI – TOXICOLOGICAL PROPERTIES OF PRODUCT
ROUTE OF ENTRY
SKIN CONTACT:
X
SKIN ABSORPTION:
EYE CONTACT: X
INHALATION ACUTE: X
INHALATION CHRONIC: X
INGESTION:
X
EFFECTS OF ACUTE EXPOSURE TO PRODUCT
EYE:
CORROSIVE. Contact may cause pain, lachrymation (tears), and severe irritation with corneal injury, may even cause
blindness.
SKIN:
CORROSIVE. Short single skin exposure may cause burns.
INHALATION: CORROSIVE. Excessive vapour concentrations inhaled may cause serious adverse effects, even death.
INGESTION: CORROSIVE. May cause burns of the mouth and throat and gastro intestinal irritation and ulceration.
EFFECTS OF CHRONIC EXPOSURE TO PRODUCT: Repeated excessive exposure may cause erosion of teeth and bleeding and
ulceration of nose, mouth and gums.
LD50 OF PRODUCT (SPECIFY SPECIES & ROUTE) IRRITANCY OF PRODUCT EXPOSURE LIMITS OF PRODUCT
Not Determined
High
ACGIH TLV 5 ppm Ceiling
LC50 OF PRODUCT (SPECIFY SPECIES)
Hydrochloric Acid: 3124 ppm for 1 hr (inhal/rat)
CARCINOGENICITY
Not Applicable

SENSITIZATION TO PRODUCT
Not Available

REPRODUCTIVE EFFECTS
Not Available

SYNERGISTIC MATERIALS
None Known

TERATOGENICITY
Not Available

MUTAGENICITY
Not Available

SECTION VII – PREVENTATIVE MEASURES
PERSONAL PROTECTIVE EQUIPMENT
GLOVES
RESPIRATORY (SPECIFY)
Neoprene, Rubber or PVC
Approved air purity respirator if exposure guidelines
or comfort levels may be exceeded.

EYE (SPECIFY)
Chemical Goggles

FOOTWEAR (SPECIFY)
Rubber Boots

OTHER (SPECIFY)
Not Applicable

CLOTHING (SPECIFY)
Apron

ENGINEERING CONTROLS (E.G. VENTILATION, ENCLOSED PROCESS, (SPECIFY): Local mechanical exhaust ventilation to
control airborne contamination below exposure levels.
LEAK AND SPILL PROCEDURE:
Ventilated area. Do not allow spilled material to go to drain. Contain leak or spill, soak
up with sand, ashes, or gravel. Dispose of into covered polyethylene containers.
WASTE DISPOSAL:

Dispose of according to local, provincial, and federal regulations.

HANDLING PROCEDURES & EQUIPMENT:

Use only with adequate ventilation. Avoid eye and skin contact. Avoid breathing
vapours.

STORAGE REQUIREMENTS:

Store in a cool, dry place in a closed container away from heat, metals and oxidizers.

SPECIAL SHIPPING INFORMATION:

Not Applicable.
SECTION VIII – FIRST AID PROCEDURES

SKIN: Immediate, continued and thorough washing in flowing water for 30 minutes, is imperative while removing contaminated clothing.
Seek medical attention immediately.
EYE: Immediate and continuous irrigation with flowing water for at least 30 minutes is imperative. Prompt medical attention is essential.
INHALATION: Remove patient to fresh air if effects occur. Seek medical attention immediately.
INGESTION: DO NOT induce vomiting. Give large amounts of water or milk if available and transport to medical facility immediately.
GENERAL ADVICE: Safety shower and eyewash must be readily available. CORROSIVE. May cause stricture. If lavage is performed,
suggest endotracheal and esophagoscopic control if burn is present, treat as any thermal burn after decontamination.
SECTION IX – PREPARATION DATE OF MSDS
ADDITIONAL INFORMATION/COMMENTS: None
SOURCES USED: Supplier MSDS
PREPARED BY:

CP INDUSTRIES LTD. PHONE NUMBER: (519) 843-6300
DEVELOPMENT DEPT.
INSTITUTIONAL DIVISION

DATE: MARCH 24, 2004

MATERIAL SAFETY DATA SHEET
SECTION I - PRODUCT IDENTIFICATION AND USE
Product Identifier:
CLING TYPE BOWL CLEANER
Product Use: HEAVY DUTY BOWL CLEANER FOR USE ON PORCELAIN, PLASTIC TILE,
FIBREGLASS, VITREOUS CHINA AND STAINLESS STEEL.
Supplier:
SHARE CANADA
Address:
1691 CHURCH AVENUE, WINNIPEG, MANITOBA R2X 2Y7
Telephone Number: (204) 633-8553
Fax: (204) 633-8453
CANUTEC: (613) 996-6666

SECTION II - HAZARDOUS INGREDIENTS
Hazardous
ingredients
PHOSPHORIC ACID

CAS Number

7664-38-2

Exposure
limits
1 mg / m

3

Weight %

10

30 %

LD 50

LC50

1530 mg /kg (rat/ oral)
2740 mg /kg (rabbit/
dermal)

SECTION III- PHYSICAL DATA
Physical State:
Specific Gravity (20oC):
Odour and appearance:

LIQUID
1.1
TRANSLUSCENT TO OPAQUE GREEN LIQUID, WINTERGREEN

ODOUR.

Odour threshold:
Not available.
pH:
1.2
Vapour pressure (mm Hg):
2.3 kPa @ 20oC.
Vapour density (air = 1):
1
Evaporation rate (water = 1): 1
% volatile by volume:
Not available.
Solubility in water:
EASILY SOLUBLE IN COLD WATER.
Boiling point (Co):
102 o C.
Freezing point (Co):
Not available.
Coefficient of oil/water distribution: Not available.

SECTION IV - FIRE AND EXPLOSION DATA
Flammable or combustible: Not flammable or combustible. Flash point (Co): NONE
Conditions of flammability: NONE
Upper flammable limit: Not applicable.
Lower flammable limit: Not applicable.
Autoignition temperature: Not applicable. Flammability classification: NONE
Special fire fighting procedures: SPRAY WATER TO COOL CONTAINERS AND CONTROL
VAPOURS. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID BREATHING FUMES.
Means of extinction: SMALL FIRE USE DRY CHEMICAL, CARBON DIOXIDE, WATER
SPRAY OR FOAM, LARGE FIRE USE WATER SPRAY, FOG OR FOAM. DO NOT USE
WATER JET.
Hazardous combustion products: PHOSPHATES AND CARBON OXIDES.
Sensitivity to mechanical impact:
Not sensitive.
Sensitivity to static discharge:
Not sensitive.

SECTION V - REACTIVITY DATA
Is the product stable? STABLE
Conditions of reactivity: DO NOT MIX WITH OTHER CLEANING PRODUCTS.
Incompatible substances: HIGHLY REACTIVE WITH ALKALIS. SLIGHTLY REACTIVE
WITH ORGANIC MATERIALS. NON-REACTIVE WITH OXIDIZING AGENTS, ACIDS.
Hazardous decomposition products: PHOSPHATES AND CARBON OXIDES.

Not found.
.

Product Identifier: CLING TYPE BOWL CLEANER

SECTION VI - TOXICOLOGICAL PROPERTIES
WHMIS CLASSIFICATION: CLASS D2B, E - CORROSIVE MATERIAL
Primary routes of exposure: SKIN AND EYE CONTACTAND INGESTION.
Exposure limits: SEE SECTION II FOR LIMITS FOR INGREDIENTS.
Acute effects of exposure: DANGEROUS IN CASE OF SKIN CONTACT (CORROSIVE,
IRRITANT), OF EYE CONTACT (IRRITANT), OF INGESTION, OF INHALATION. LIQUID OR
SPRAY MIST MAY PRODUCE TISSUE DAMAGE PARTICULARLY ON MUCOUS
MEMBRANES OF EYES, MOUTH AND RESPIRATORY TRACT. Chronic effects of
exposure: REPEATED EXPOSURE MAY CAUSE CHRONIC EYE, SKIN AND RESPIRATORY
TRACT IRRITATION.
Sensitizer: NOT KNOWN TO BE A SENSITIZER.
Carcinogen: NOT LISTED - IARC, NTP, OSHA Mutagen: NOT KNOWN AS A MUTAGEN.

SECTION VII - PREVENTION MEASURES
Gloves: IMPERVIOUS
GLOVES

Respirator: IF VENTILATION IS
INSUFFICIENT, WEAR SUITABLE
RESPIRATORY EQUIPMENT.

Eye protection: SPLASH
GOGGLES, FACE`SHIELD.

Footwear:
RUBBER BOOTS

Clothing: PROTECTIVE
CLOTHING TO PREVENT SKIN
CONTACT.

Other: EYE WASH
STATION AND SAFETY
SHOWER.

Engineering controls: PROVIDE EXHAUST VENTILATION TO KEEP AIRBORNE
CONCENTRATIONS OF VAPOURS BELOW TLV.
Leak and spill procedures: ABSORB WITH INERT DRY MATERIAL AND PLACE IN AN
APPROPRIATE WASTE DISPOSAL CONTAINER.
Waste disposal: DISPOSE ACCORDING TO FEDERAL, PROVINCIAL OR LOCAL
REGULATIONS. CONSULT LOCAL OR REGIONAL AUTHORITIES.
Handling and storage requirements: KEEP LOCKED UP, KEEP CONTAINER TIGHTLY
CLOSED AND DRY. KEEP AWAY FROM HEAT, METALS AND OXIDIZING MATERIALS AND
SOURCES OF IGNITION. STRONG ACIDS THAT ARE NOT STRONG OXIDANTS SHOULD
BE STORED IN A SEPARATE SAFETY STORAGE CABINET OR ROOM. KEEP LOCKED
UP AND OUT OF THE REACH OF CHILDREN. KEEP CONTAINER DRY. DO NOT
BREATHE GAS, FUMES, VAPOUR OR SPRAY. AVOID CONTACT WITH SKIN AND EYES.
KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. KEEP OUT OF THE REACH OF
CHILDREN.
Special shipping information: T.D.G CLASS 8 PHOSPHORIC ACID, LIQUID. UN 1805,
PACKING GROUP III. LIMITED QUANTITY IN CONTAINERS UP TO 5 LITRES.

SECTION VIII - FIRST AID MEASURES
Eye contact: IMMEDIATELY FLUSH EYES AND UNDER EYELIDS WITH PLENTY OF COOL
WATER FOR 15 MINUTES HOLDING THE EYELIDS OPEN. GET MEDICAL ATTENTION.
Skin contact: WASH SKIN WITH PLENTY OF COOL WATER AND NON-ABRASIVE SOAP
AND COVER WITH AN EMOLIENT. IF IRRITATION PERSISTS GET MEDICAL ATTENTION.
Ingestion: CONTACT PHYSICIAN OR POISON CONTROL CENTRE IMMEDIATELY. DO
NOT INDUCE VOMITING. RINSE MOUTH THOROUGHLY. GIVE CONSCIOUS PERSON
SEVERAL GLASSES OF WATER OR MILK. Inhalation: ALLOW THE VICTIM TO REST IN
A WELL-VENTILATED AREA. SEEK IMMEDIATE MEDICAL ATTENTION.

SECTION IX - PREPARATION DATA
Information sources:
Prepared by:
Telephone Number:
Preparation Date:

MANUFACTURER S MSDS, CCOHS CCINFO
SHARE CANADA
(204) 633-8553
September 2, 2005

Atlantic Chemical Equipment Co.
2190 DeFoor Hills Rd NW
Atlanta, GA 30318
404-355-5522

MATERIAL SAFETY DATA SHEET

PRODUCT NAME:

ODOR NEUTRALIZER (ON & ONjr)

EMERGENCY PHONE: 1-800-424-9300

VII - PRECAUTIONS FOR SAFE HANDLING AND USE

May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200.

Standard must be consulted for specific requirements. This product contains
no substances subject to SARA TITLE III and 40 CRF.

HMIS SYMBOLS
HEALTH

1

FLAMMABILITY

1

REACTIVITY

0

STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED:
SMALL SPILLS: Sweep up material and shovel into waste container.
LARGE SPILLS: Contain and collect for reuse.
WASTE DISPOSAL METHOD: Deposit in landfill in accordance with local, State, and Federal regulations.

1 - IDENTIFICATION

VIII - SPECIAL PROTECTION INFORMATION

PRODUCT NAME: (ON) Odor Neutralizer

PACKAGE TYPE: pint, quart, gallon

PREPARED DEPARTMENT OF HAZARDOUS COMMUNICATIONS

DATE PREPARED: June 2003

RESPIRATORY:

Needed in misty conditions. Use approved NIOSH organic vapor HEPA respirator.

EYE: Wear chemical splash goggles.

II - HAZARDOUS INGREDIENTS
PRINCIPLE HAZARDOUS COMPONENT(S)
(CHEMICAL NAMES)
2 - hydroxybenzoic acid methyl ester

CAS NO

ACGIH TLV

OSHA

119-36-8

N/E

PEL

% or RANGE

SKIN: Prevent all possible contact. Use impervious apron,
boots, goggles.

PROTECTIVE GLOVES: PVC or rubber

<37%
OTHER: DO not eat, drink, or smoke in work area. Wash hands before eating.
VENTILATION REQUIREMENTS: Local exhaust adequate

IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep containers closed when not in use.

III - PHYSICAL DATA
BOILING POINT ( 0F) : N/A
VAPOR PRESSURE (mm Hg) : N/A

SPECIFIC GRAVITY (H20= 1) : N/A

VAPOR DENSITY (Air = 1) : Heavier

EVAPORATION RATE (H20 = 1) : <1

pH : NA

APPEARANCE AND ODOR : Dark brown granules - wintergreen odor

MELTING POINT : N/E

SPECIAL PRECAUTIONARY STATEMENTS: Keep this and all chemicals out of reach of children.

SOLUBILITY IN WATER : Not Soluble

IV - FIRE AND EXPLOSION HAZARD DATA

NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on
experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be
confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of
merchantability fitness or otherwise is made.

FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Flash point 2140F
SARA Title III Reporting Requirements

SPECIAL FIRE FIGHTING PROCEDURES: Wear impervious clothing and SCBA; dike spills to prevent runoff
UNUSUAL FIRE AND EXPLOSION HAZARDS: Products of decomposition include carbon monoxide and low molecular weight hydro carbons

V - REACTIVITY DATA
CHEMICAL
STABILITY

UNSTABLE

302

(Extremely Hazardous Substances): Reporting not required.

304/CERCLA

(Spills Notification): Not required.

311

Community Right-To-Know, RTK): Reporting not required.

312

(RTK Inventory Data): Reporting required above TPQ.

CONDITIONS TO AVOID:

STABLE

X

INCOMPATIBILITY (Materials to avoid): Oxidizing agents, heat, sparks, open flame, bases
HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO2
HAZARDOUS
POLYMERIZATION

MAY OCCUR

CONDITIONS TO AVOID:

WILL NOT OCCUR

X

VI - HEALTH HAZARD AREA
ROUTE(S) OF ENTRY:

EYES Yes

SKIN Yes

INGESTION Yes

313

(Emissions and Releases): Reporting not required.

DOT

NOT HAZARDOUS

INHALATION Yes
References

EFFECTS OF OVER EXPOSURE: Irritant
INHALATION: May irritate sensitive persons

TOXIC SUBSTANCE CONTROL CT LIST (TSCA) - INGREDIENTS LISTED

SKIN CONTACT/ABSORPTION: Irritation

PERMISSIBLE EXPOSURE REFERENCES:
Registry of Toxic Effects of Chemical Substances.

INGESTION: Toxic if ingested

Title 29 Code of Federal Regulations.
National Toxicology Program (NTP) Report on Carcinogens.

EYES: Eye irritant
CARCINOGENICITY:

NTP? Not listed

IARC MONOGRAPHS? Not listed

OSHA REGULATED? Not listed

EMERGENCY AND FIRST AID PROCEDURES:
EYES AND SKIN: EYES - wash eyes with plenty of water. GET MEDICAL ATTENTION IMMEDIATELY. SKIN - Rinse skin with plenty of water
and soap. Get medical help if nauseated, treat as ingested products
INHALATION: Remove to fresh air. GET IMMEDIATE MEDICAL ATTENTION, if symptoms persist.
INGESTION: Immediately induce vomiting. GET IMMEDIATE MEDICAL ATTENTION. Call poison control center. Treat for salicylate poisons.

International Agency for Research on Cancer (IARC) Monographs.
Title 40 Code of Federal Regulations
REGULATORY STANDARDS:
DOT Title 49 Code of Federal Regulations 172.101
SARA Title III
Nuclear Regulatory Commission

1

MATERIAL SAFETY DATA SHEET
SECTION I - PRODUCT IDENTIFICATION AND USE
Product Identifier:

ODOUR NEUTRALIZER

Product Use:

WATER BASED DEODERANT FOR USE AS AN ODOUR NEUTRALIZER.

Supplier:
Address:

SHARE CANADA
1691 CHURCH AVENUE, WINNIPEG, MANITOBA R2X 2Y7

Telephone Number: (204) 633-8553

Fax: (204) 633-8453

CANUTEC: (613) 996-6666

SECTION II - HAZARDOUS INGREDIENTS
Ingredient

CAS Number

Weight %

LD 50

LC 50

Isopropanol

67-63-0

5

5840 mg/kg
oral /rat

16,000 ppm
rat, 2 hr

10 %

SECTION III - PHYSICAL DATA
Physical State:
LIQUID
Specific gravity:
0.995
pH:
Not available.
Odour and appearance: CLEAR, LIGHT YELLOW LIQUID. FLORAL FRAGRANCE.
Odour threshold:
Not available.
Vapour pressure (PSI): Not available.
Vapour density (air = 1): Not available.
Evaporation rate (water = 1): Not available.
% volatile by volume: 1-10
Solubility in water:
SOLUBLE.
0
0
Boiling Point ( C ):
Not available.
Freezing Point ( C ): Not available.
Coefficient of water/oil distribution: Not available.

SECTION IV - FIRE AND EXPLOSION DATA
Flammable or combustible:
COMBUSTIBLE
0
Flash point and method:
42 C CLOSED CUP
Upper flammable limit:
Not Available.
Lower flammable limit:
Not Available.
Autoignition temperature:
Not Available.
Flammability classification:
COMBUSTIBLE LIQUID.
Conditions of flammability:
EXPOSURE TO HEAT OR OPEN FLAME.
Means of extinction: WATER, FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Special fire fighting procedures: COOL FIRE-EXPOSED CONTAINERS WITH WATER FOG.
FIREFIGHTERS SHOULD BE EQUIPPED WITH FULL PROTECTIVE GEAR, INCLUDING SELFCONTAINED BREATHING APPARATUS.
Hazardous combustion products: OXIDES OF CARBON.
Sensitivity to mechanical impact: NOT SENSITIVE
Sensitivity to static discharge: NOT SENSITIVE

SECTION V - REACTIVITY DATA
Is the product stable:
Incompatible substances:
Conditions of Reactivity:
Hazardous decomposition products:
CARBON.

YES- STABLE.
OXIDIZERS
NONE
THERMAL DECOMPOSITION MAY PRODUCE OXIDES OF

Product identifier:

ODOUR NEUTRALIZER

SECTION VI - TOXICOLOGICAL PROPERTIES
Primary routes of exposure: SKIN AND EYE CONTACT, INHALATION, INGESTION.
Exposure Limits: ACGIH -TLV: ISOPROPANOL TLV-TWA 400 ppm TLV STEL 500 ppm
WHMIS CLASS: B- 3 COMBUSTIBLE LIQUID, D 2B OTHER TOXIC EFFECTS (EYE IRRITANT).
Irritant:
YES
Carcinogen: NO - IARC / OSHA / NTP
Sensitizer:
NO
Mutagen:
NO
Reproductive effects: NONE KNOWN
Synergistic products: NONE KNOWN
Effects of acute exposure: Eyes: MILD IRRITATION AND REDNESS.
Ingestion: GASTROINTESTINAL IRRITATION, NAUSEA, CRAMPS AND VOMITING. ASPIRATION MAY
BE A HAZARD. Skin: REDNESS, DRYNESS AND IRRITATION WITH PROLONGED AND REPEATED
EXPOSURE. Inhaled: MOVE TO FRESH AIR. IF IRRITATION PERSISTS OBTAIN MEDICAL
ATTENTION.

SECTION VII - PREVENTION MEASURES
Gloves: CHEMICAL
RESISTANT GLOVES

Respirator: USE WITH
ADEQUATE VENTILATION.

Eye protection: SAFETY GLASSES
OR CHEMICAL GOGGLES

Footwear: NO SPECIAL
REQUIREMENTS.

Clothing: NO SPECIAL
REQUIREMENTS.

Other requirements: EYE WASH
STATION

Engineering Controls: NO SPECIAL VENTILATION REQUIRED.
Respiratory protection: USE WITH ADEQUATE VENTILATION.
Leak or spill procedures: VENTILATE AREA AND EXTINGUISH ALL SOURCES OF IGNITION. SOAK
UP ON INERT ABSORBENT MATERIAL AND PLACE IN A PROPERLY MARKED CLOSED CONTAINER
FOR PROPER DISPOSAL.
Waste disposal: CONSULT LOCAL ENVIRONMENTAL AUTHORITIES.
Handling and storage requirements: STORE IN A COOL, DRY PLACE. KEEP CONTAINER TIGHTLY
CLOSED WHEN NOT IN USE. KEEP OUT OF THE REACH OF CHILDREN.
Special shipping information: NOT REGULATED BY TDG.

SECTION VIII - FIRST AID MEASURES
Eyes: FLUSH EYES AND UNDER EYELIDS FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS,
OBTAIN MEDICAL ATTENTION.
Skin: WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, OBTAIN MEDICAL ATTENTION.
Ingestion: CONTACT PHYSICIAN OR POISON CONTROL CENTRE IMMEDIATELY. RINSE MOUTH
WITH WATER ANG GIVE PERSON 1 OR 2 GLASSES OF WATER. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON.
Inhalation: MOVE TO FRESH AIR. IF IRRITATION PERSISTS, OBTAIN MEDICAL ATTENTION.

SECTION IX - PREPARATION DATA
Information Sources:
Prepared by:
Telephone:
Preparation date:

SUPPLIERS' MATERIAL SAFETY DATA SHEET, CCOSH - CHEMINFO
SHARE CANADA
1-204-633-8553
March 11, 2005

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name:
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

FORMULA 491705
MANGO
ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Acetone
Propane
Isobutane
n-Butane
Fragrance

CAS No.:
67-64-1
74-98-6
75-28-5
106-97-8
Not available

TLV:
500ppm
2500ppm
Not established
800ppm
Not available

______________________________________________________________________________

SECTION 3
Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA
<0 to 1330 F
Slightly
Clear/mango scent

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5
Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.

First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________

SECTION 9

SPILL OR LEAK PROCEDURE

Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None

__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491705

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name:
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

FORMULA 491655
TROPICAL NECTAR
ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Acetone
Propane
Isobutane
n-Butane
Fragrance

CAS No.:
67-64-1
74-98-6
75-28-5
106-97-8
Not available

TLV:
500ppm
2500ppm
Not established
800ppm
Not available

______________________________________________________________________________

SECTION 3
Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA
<0 to 1330 F
Slightly
Clear/tropical scent

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5
Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.

First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________

SECTION 9

SPILL OR LEAK PROCEDURE

Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None

__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491655

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name:
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

FORMULA 491805
PEACH KIWI
ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Acetone
Propane
Isobutane
n-Butane
Fragrance

CAS No.:
67-64-1
74-98-6
75-28-5
106-97-8
Not available

TLV:
500ppm
2500ppm
Not established
800ppm
Not available

______________________________________________________________________________

SECTION 3
Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA
<0 to 1330 F
Slightly
Clear/peach kiwi scent

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5
Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.

First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________

SECTION 9

SPILL OR LEAK PROCEDURE

Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None

__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491805

MATERIAL SAFETY DATA SHEET

GLASER MANUFACTURING
#27 - 547 MAIN STREET, E.
MILTON, ON L9T 3J2
(905) 876-4420

EMERGENCY CANUTEC #:

613-996-6666

SECTION I - PRODUCT IDENTIFICATION AND USE
PRODUCT NAME:
CHEMICAL FAMILY:
PRODUCT USE:

BIO-ZYME
BIOLOGICAL DRAIN OPENER
DRAIN CONTROL/STACK MAINTAINER

SECTION II - HAZARDOUS INGREDIENTS
HAZARDOUS INGREDIENT

APPROX. %

CAS#

LD50/RAT, ORAL

LC50

VIABLE BACTERIAL CULTURES

60-100

N/A

NOT KNOWN

NOT KNOWN

SECTION III - PHYSICAL DATA
PHYSICAL STATE:
LIQUID
ODOUR & APPEARANCE: SPICE ODOUR, WHITE
ODOUR THRESHOLD:
N/E
VAPOUR PRESSURE:
N/AP
EVAPORATION RATE:
N/E
BOILING POINT:
100ºC
COEFFICIENT OF WATER/OIL DISTRIBUTION:

SPECIFIC GRAVITY:
VAPOUR DENSITY (AIR=1):
SOLUBILITY IN WATER:
pH:

1.01
N/AP
MODERATE
8.0 – 8.5

N/E

SECTION IV - FIRE AND EXPLOSION DATA
CONDITIONS OF FLAMMABILITY:
EXTINGUISHING MEDIA:
HAZARDOUS COMBUSTION PRODUCTS:
UPPER FLAMMABILITY LIMIT:
AUTO IGNITION TEMP:
SENSITIVITY TO STATIC CHARGE:

NONE
N/AP
NONE KNOWN
N/AP
N/AP
N/AP

LOWER FLAMMABILITY LIMIT:
EXPLOSION DATA:

N/AP
N/AP

SECTION V - REACTIVITY DATA
CHEMICAL STABILITY:
CONDITIONS TO AVOID:
INCOMPATIBLE SUBSTANCES:
HAZARDOUS DECOMPOSITION:
HAZARDOUS POLYMERIZATION:

STABLE
NONE
STRONG ACIDS OR ALKALIS MAY INACTIVATE SOME BACTERIAL CULTURES.
NONE KNOWN
WILL NOT OCCUR.

SECTION VI - TOXICOLOGICAL PROPERTIES
ROUTE OF ENTRY:

SKIN CONTACT: YES
INHALATION:
YES

SKIN ABSORPTION: YES
INGESTION:
YES

EYE CONTACT: YES

EFFECTS OF ACUTE EXPOSURE TO MATERIAL:
THIS MATERIAL MAY CAUSE EYE OR SKIN IRRITATION. ORGANISMS USED ARE NON PATHOGENIC,
BUT CAN CAUSE INFECTION WHEN IN CONTACT WITH OPEN WOUNDS. THESE ORGANISMS ARE
SUSCEPTIBLE TO COMMONLY USED ANTIBIOTICS.
EFFECTS OF CHRONIC EXPOSURE:
NONE KNOWN. LIMITED TOXIC DATA ARE AVAILABLE ON THIS SPECIFIC PRODUCT. THIS HEALTH
HAZARD ASSESSMENT IS BASED ON THE RESULTS OF SCREENING TESTS.
EXPOSURE LIMITS:
N/E
SENSITIZATION OF MATERIAL: NONE KNOWN

IRRITANCY OF MATERIAL:
SLIGHT
CARCINOGENICITY:
NONE KNOWN

1

REPRODUCTIVE TOXICITY:
MUTAGENICITY:

PRODUCT NAME:

NONE KNOWN
NONE KNOWN

TERATOGENICITY:
SYNERGISTIC PRODUCTS:

NONE KNOWN
NONE KNOWN

BIO-ZYME

SECTION VII - PREVENTIVE MEASURES
HAND PROTECTION:
RUBBER OR VINYL GLOVES
EYE PROTECTION:
SAFETY GLASSES
DEPENDING ON SEVERITY OF EXPOSURE:
RESPIRATORY PROTECTION:
LOCAL EXHAUST ADEQUATE. USE NOISH APPROVED RESPIRATOR IF
MISTING PRODUCT.
FOOT WEAR:
RUBBER BOOTS IF CONTACT POSSIBLE
CLOTHING:
AVOID SKIN CONTACT. LONG SLEEVE CLOTHING.
ENGINEERING CONTROLS:
LOCAL EXHAUST ADEQUATE. USE NOISH APPROVED RESPIRATOR IF IN
CONFINED AREAS.
LEAKS AND SPILL PROCEDURES: SMALL SPILLS: FLUSH WITH LARGE AMOUNTS OF WATER.
LARGE SPILLS: COLLECT WITH ABSORBENT AND PLACE IN CONTAINERS
FOR DISPOSAL.
WASTE DISPOSAL: REVIEW LOCAL GOVERNMENT REGULATIONS AND DISPOSE THROUGH LICENSED
FACILITY.
HANDLING PROCEDURES & EQUIPMENT:
AVOID EYE CONTACT.
STORAGE REQUIREMENTS:
STORE IN A COOL, DRY AREA. DO NOT FREEZE.
SECTION VIII - FIRST AID MEASURES
PROCEDURES:
SKIN:
REMOVE CONTAMINATED CLOTHING, WASH AND FLUSH GENEROUSLY WITH SOAP AND
WATER. IF IRRITATION PERSISTS, SEEK MEDICAL ATTENTION.
EYES:
FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL
ATTENTION IF IRRITATION PERSISTS.
INGESTION: DO NOT INDUCE VOMITING. RINSE MOUTH WITH WATER. DRINK LARGE AMOUNTS OF MILK OR
WATER. SEEK MEDICAL ATTENTION IMMEDIATELY.
SECTION IX - TDG SHIPPING INFORMATION
WHMIS CLASSIFICATION: CLASS D, DIVISION 2B
TDG CLASSIFICATION:
NONE
PIN #:
NONE
PACKING GROUP:
N/AP
SECTION X - HMIS HAZARD RATING INFORMATION
HEALTH: 1

FIRE: 0

REACTIVITY: 0

SPECIAL: NONE

HAZARD RATING SCALE: 0=MINIMAL, 1=SLIGHT, 2=MODERATE, 3=SERIOUS, 4=SEVERE
SECTION XI - PREPARATION INFORMATION
PREPARED BY:
PREPARATION DATE:

GLASER MANUFACTURING
JAN 2006

DISCLAIMER
THE INFORMATION CONTAINED HEREIN IS COMPILED FROM SOURCES BELIEVED TO BE RELIABLE. THE MANNER AND
CONDITIONS OF USE AND HANDLING MAY INVOLVE OTHER AND ADDITIONAL CONSIDERATIONS. WE ACCEPT NO
RESPONSIBILITY FOR THE ACCURACY, SUFFICIENCY, RELIABILITY OR FOR ANY LOSS OR INJURY RESULTING FROM
THE USE OF THE INFORMATION.

2

MATERIAL SAFETY DATA SHEET

Page: 1 of 4

NATIONAL SANITARY SUPPLY CO.
13217 S. Figueroa Street
Los Angeles, California 90061
Emergency No. 1-800-535-5053 (INFOTRAC)
----------------------------------------------------------------------------SECTION 1. IDENTIFICATION OF PRODUCT
----------------------------------------------------------------------------Product Name: MINT O LINE MINT ODOR
Date Issued: 07/15/93
DEODORANT CLEANER
Supercedes: 06/01/90
National Item#: 1720XX
----------------------------------------------------------------------------SECTION 2. INGREDIENTS CAS NUMBER PERCENT EXPOSURE LIMITS IN AIR
OSHA PEL ACGIH TLV OTHER
----------------------------------------------------------------------------ISOPROPYL ALCOHOL
67-63-01 14-16
400 ppm TWA 400 ppm
COCONUT OIL SOAP
61788-47-4 8-10
NOT ESTABLISHED
METHYL SALICYLATE
119-36-8
<2
NOT ESTABLISHED
WATER
>50.00
N/A = Not Applicable; N/D = Not Determined
----------------------------------------------------------------------------SECTION 3. PHYSICAL DATA
----------------------------------------------------------------------------Boiling Point (F): <212
Specific Gravity (Water=1): .86
Vapor Pressure (mm Hg.): 16
Percent Volatile (By Volume): 88
Vapor Density (Air=1): ND
Evaporation Rate (Water =1): 1
Solubility in Water: SOLUBLE
pH Range: 10.5
Appearance and Odor: CLEAR COLORLESS/MINT SCENT
----------------------------------------------------------------------------Section 4. FIRE AND EXPLOSION HAZARD DATA
----------------------------------------------------------------------------Flash Point (Test Method): 108 F (TOC)
Extinguishing Media: CO2, DRY CHEMICAL, FOAM, WATER FOG
Special Fire Fighting Procedures: NORMAL FIRE FIGHTING PROCEDURES MAY BE
USED. COOL AND USE CAUTION WHEN APPROACHING OR HANDLING FIRE- EXPOSED
CONTAINERS.
Unusual Fire & Explosion Hazards: CONTAINERS MAY BURST IN HEAT.

MATERIAL SAFETY DATA SHEET
Page: 2 of 4
Product Name: MINT O LINE MINT ODOR DEODORANT CLEANER
Date Issued: 07/15/93
National Item#: 1720
----------------------------------------------------------------------------SECTION 5. REACTIVITY DATA
----------------------------------------------------------------------------Stability: STABLE
Incompatibility - Materials to Avoid: NONE KNOWN TO NSS
Hazardous Polymerization: WILL NOT OCCUR
Conditions to Avoid: NONE KNOWN TO NSS
Hazardous Decomposition Products: WHEN EXPOSED TO FIRE, PRODUCES NORMAL
PRODUCTS OF COMBUSTION.
----------------------------------------------------------------------------SECTION 6. SPILL, LEAK AND DISPOSAL PROCEDURES
----------------------------------------------------------------------------Spill Response: FOR SMALL SPILLS. DILUTE WITH WATER AND PICK UP WITH MOP
AND PAIL OR WET PICK UP VACUUM. FOR LARGE SPILLS, DIKE AREA TO CONTAIN
SPILL. CLEAN UP USING ABSORBENT MATERIAL. PLACE ALL CONTAMINATED
MATERIAL IN A CLOSED CONTAINER FOR DISPOSAL.
Product Disposal: WASTE FOR DILUTED PRODUCT MAY BE FLUSHED TO SEWER.
UNDILUTED PRODUCT RECOVERED FROM SPILLS MAY BE SENT TO A LICENSED
DISPOSAL FACILITY TO BE DISPOSED OF IN ACCORDANCE WITH FEDERAL/STATE
REGULATIONS AND LOCAL ORDINANCES.
Container Disposal: TRIPLE RINSE EMPTY CONTAINER THOROUGHLY WITH WATER
AND DISCARD IN REGULAR TRASH COLLECTION IF ALLOWED BY LOCAL, STATE AND
FEDERAL REGULATIONS.
----------------------------------------------------------------------------SECTION 7. HEALTH HAZARD DATA

MATERIAL SAFETY DATA SHEET
Page: 3 of 4
Product Name: MINT O LINE MINT ODOR DEODORANT CLEANER
Date Issued: 07/15/93
National Item#: 1720
----------------------------------------------------------------------------Symptoms of Overexposure:
Eye Contact: EYE IRRITANT. IF NOT PROMPTLY TREATED, EYE DAMAGE MAY
RESULT.
Skin Contact: SKIN IRRITANT. IRRITATION CAN OCCUR FROM CONTACT
WITH CONCENTRATED PRODUCT OR FROM PROLONGED CONTACT
WITH DILUTED PRODUCT. REPEATED OR PROLONGED EXPOSURE
TO DILUTED PRODUCT MAY LEAD TO DERMATITIS.
Inhalation: NO HEALTH EFFECTS ARE KNOWN TO OCCUR FROM INHALATION OF
THIS PRODUCT UNDER NORMAL USE IN A WELL VENTILATED
AREA. HIGH AIRBORNE CONCENTRATIONS OF MISTS OR SPRAYS
OF THIS PRODUCT MAY CA USE IRRITATION OF THE UPPER
RESPIRATORY TRACT.
Ingestion: INGESTION OF THIS PRODUCT MAY CAUSE DAMAGE TO THE
MEMBRANES OF THE MOUTH, THROAT, AND GASTROINTESTINAL
TRACT WHICH THE PRODUCT CONTACTS. BURNS OF THE MOUTH AND
THROAT, NAUSEA, VOMITING, CRAMPS, AND DIARRHEA MAY
OCCUR.
Primary Routes of Entry: EYES, SKIN
THE ISOPROYL ALCOHOL LISTED IN SECTION 2 IS NOT LISTED ON THE
OSHA, NTP OR IARC MONOGRAPH CARCINOGEN LISTS.
----------------------------------------------------------------------------SECTION 8. EMERGENCY AND FIRST AID PROCEDURES
----------------------------------------------------------------------------Eye Contact: IMMEDIATELY FLUSH THE EYE WITH LARGE QUANTITIES OF RUNNING
WATER FOR A MINIMUM OF 15 MINUTES. HOLD THE EYELIDS APART DURING THE
IRRIGATION TO ENSURE FLUSHING OF THE ENTIRE SURFACE OF THE EYE LID WITH
WATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS.
Skin Contact: FLUSH THE EFFECTED AREA WITH LARGE QUANTITIES OF RUNNING
WATER WHILE REMOVING CONTAMINATED CLOTHES AND SHOES. WASH CLOTHING
BEFORE REUSE. GET MEDICAL ATTENTION IF IRRITATION PERSISTS.
Inhalation: REMOVE FROM CONTAMINATED AREA. IF SYMPTOMS OF RESPIRATORY
DISCOMFORT PERSISTS, GET MEDICAL ATTENTION.
Ingestion: REQUIRES IMMEDIATE MEDICAL MANAGEMENT. DRINK MILK OR WATER AND
GET MEDICAL ADVICE. VOMITING SHOULD BE INDUCED ONLY ON RECOMMENDATION OF
MEDICAL PERSONNEL.
----------------------------------------------------------------------------SECTION 9. SPECIAL PROTECTION INFORMATION
----------------------------------------------------------------------------Respiratory Protection: NO SPECIAL REQUIREMENTS UNDER NORMAL USE
CONDITIONS.
Ventilation: ROOM VENTILATION IS ADEQUATE.
Protection Gloves: NO SPECIAL REQUIREMENTS UNDER NORMAL USE CONDITIONS.
Eye Protection: NO SPECIAL REQUIREMENTS UNDER NORMAL USE CONDITIONS.
Other Protective Clothing/Equipment: WHERE GROSS EYE OR SKIN CONTACT MAY
OCCUR, USE APPROPRIATE PROTECTIVE EQUIPMENT.

MATERIAL SAFETY DATA SHEET
Page: 4 of 4
Product Name: MINT O LINE MINT ODOR DEODORANT CLEANER
Date Issued: 07/15/93
National Item#: 1720
----------------------------------------------------------------------------SECTION 10. ADDITIONAL INFORMATION AND PRECAUTIONS
----------------------------------------------------------------------------Handling and Storage Precautions: STORE IN A COOL DRY PLACE. REPLACE
CAP AFTER USE. KEEP OUT OF REACH OF CHILDREN.
SARA TITLE III H&P RATINGS: Acute, YES; Chronic, NO; Fire, YES;
Press. Release, NO;
Reactive, NO;
NFPA RATINGS: HEALTH - 1

FIRE -3

REACTIVITY -0

SPECIFIC -1

----------------------------------------------------------------------------THE INFORMATION ON THIS MATERIAL SAFETY DATA SHEET REPRESENTS THE LATEST
DATA AND BEST OPINION AS TO THE PROPER USE AND HANDLING OF THIS PRODUCT
UNDER NORMAL CONDITIONS. ANY USE OF THIS PRODUCT OR METHOD OF
APPLICATION WHICH IS NOT IN CONFORMANCE WITH THIS DATA SHEET AND THE
PRODUCT LABEL DIRECTIONS, IS THE RESPONSIBILITY OF THE USER. THIS
MATERIAL SAFETY DATA SHEET WAS PREPARED TO COMPLY WITH THE OSHA HAZARD
COMMUNICATION REGULATION.
-----------------------------------------------------------------------------

Material Safety Data Sheet

U.S. DEPARTMENT OF LABOR

May be used to comply with
OSHA=S Hazard Communication Standard
29 CFR 2910.1200. Standard must be
consulted for specific requirements.

Occupational Safety and Health
(Non-Mandatory Form)
Form Approved
OMB No. 1218-0072

Identity (As Used on Label and List) #202
Big D Fire D One-Shot

Note: Blank spaces are not permitted. If any item is not applicable, or
no information is available, the space must be marked to indicate that.

Section I
Big D Industries, Inc.

Manufacturer=s Name

Emergency Telephone Number

(800) 535-5053

Address (number, Street, City, State, and ZIP Code)

Telephone Number for Information

5620 S. W. 29th Street (73179)

2541

P. O. Box 82219

Date Prepared

Oklahoma City, OK 73148

Signature of Preparer (optional)

(800) 654-4752

(800) 654-4752

(405) 682-

01/01/2007

Section II - HMIS Rating
Health

1

4

Flammability

1

Reactivity

Section III - Hazardous Ingredients/Identity Information
Hazardous Components (Specific Chemical Identity: Common Name(s))

OSHA PEL

ACGIH TLV

Other Limits

%(optional)
Rcmnd.

Acetone CAS #67-64-1

500 ppm

500 ppm

-

Amyl Acetate CAS #628-63-7

100 ppm

100 ppm

-

Ethyl Acetate CAS #141-78-6

400 ppm

400 ppm

Liq. Petrole\um Gas - CAS #68476-85-7

1000 ppm

1000 ppm

Section IV - Physical/Chemical Characteristics
Boiling Point

-44 - 1350F Conc.

Specific Gravity (H2O = 1) 0.5677

N/E

Vapor Pressure (mm Hg.)

N/E

Melting Point

N/A

Vapor Density (AIR = 1)

>1

Evaporation Rate

<1

Solubility in Water:

Slight

Appearance and Odor:

Produces fine mist with pleasant fragrance. Liquid is transparent.

Section V - Fire and Explosion Hazard Data
Flash Point (Method Used)

Extinguishing Media

Flammable Limits

Carbon dioxide, dry foam, water spray
Self contained air supply suggested.

Special Fire Fighting Procedures
Unusual Fire and Explosion Hazards
N/A - Not Applicable

N/A

Keep containers cool (below 1300F) to avoid bursting.

N/D - Not Determined

Page 1

N/E - Not Established

LEL

UEL

1.8%

12.8

#202

Section VI - Reactivity Data
Stability

Unstable

Conditions to Avoid:

Stable

X
Avoid contact with strong oxidizing agents such as nitric acid.

Incompatibility (Materials to Avoid):
Hazardous Decomposition or Byproducts:

Hazardous
Polymerization

None

None

May Occur

Conditions to Avoid:

Will Not Occur

None

X

Section VII - Health Hazard Data
Route(s) of Entry:

Inhalation?

Yes

Skin?

Yes

Ingestion?

Yes

Health Hazards (Acute and Chronic):

Acute - Propellant is an asphyxiant and may exhibit properties at high concentrate. Chronic - Unconsciousness
Carcinogenicity:

NTP?

No

Signs and Symptoms of Exposure:

IARC Monographs?

No

OSHA Regulated?

No

Skin - possible frostbite burn. Eyes - burning sensation. Inhalation - Headache, nausea, disorientation.

Medical Conditions
Generally Aggravated by Exposure:

Emphysema

Emergency and First Aid Procedures: Eye contact: flush with large amounts of water. May cause corneal damage on prolonged contact. Seek medical

attn.
Ingestion: Do not give anything by mouth to an unconscious person. Seek Medical attn. Inhalation: remove person to fresh air . Administer
artificial respiration if not breathing. Seek medical attn.

Section VIII - Precautions for Safe Handling and Use
Steps to be Taken in Case Material is Released or Spilled:

If container is ruptured and begins to leak, place in a well ventilated area and eliminate all ignition sources.
Waste Disposal Method: do not discard empty container in incinerator or fire. Dispose of in accordance with Local, State, and Federal regulations.
0

Precautions to be Taken in Handling and Storing: Store in cool area away from heat or open flame. Do not store above 130 F as containers may burst

releasing the highly flammable propellant. AStore as Level Aerosol (NFPA 30B)
Other precautions: In case of rupture, ventilate to prevent concentrations from reaching flammable levels. Note: any copies or redistribution of

this M.S.D. Sheet must not be modified in any way.

Section IX - Control Measures
Respiratory Protection (Specify Type):

Self contained breathing apparatus.

Ventilation

Protective Gloves: Rubber or plastic for prolonged contact
Other Protective Clothing or Equipment:
Work/Hygienic Practices:
N.A. = Not Applicable

Local Exhaust:: Doors & windows open

Special

N/A

Mechanical (General)

Other

N/A

Fan

Eye Protection: Safety goggles for splash protection

Eye wash/shower facility nearby

Good housekeeping practices. Avoid skin/eye contact.
N.D. - Not Determined

Page 2

N/E - Not Established

OSHA 174, Sept. 1985

MATERIAL SAFETY DATA SHEET
MSDS 0091
=============================================================================
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
----------------------------------------------------------------------------HMIS CODES
PRODUCT NAME
Health
2
RectorSeal Concentrated Evaporator Coil Cleaner
Flammability
0
Reactivity
0
PRODUCT CODES
PPI
B
82552, 82555, 82558
CHEMICAL FAMILY
Organic/Inorganic
USE
Coil Cleaner
MANUFACTURER'S NAME
EMERGENCY TELEPHONE NO.
The RectorSeal Corporation
Chemtrec 24 Hours
2601 Spenwick Drive
(800) 424-9300
Houston, Texas 77055 USA
DATE OF PREPARATION
TECHNICAL SERVICE TELEPHONE NO.
June 30, 2005
(800) 231-3345
=============================================================================
Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
----------------------------------------------------------------------------% by WT
CAS No. INGREDIENT
UNITS
1-5
111-76-2 Glycol Ether EB
ACGIH TLV
25 ppm
OSHA PEL
25 ppm
=============================================================================
Section 3 -- HAZARDS IDENTIFICATION
----------------------------------------------------------------------------SUMMARY OF ACUTE HAZARDS
Irritation to eyes, nose, and throat; drowsiness, narcosis, tremors, and
other CNS effects at high concentrations. Skin irritation, dermatitis, and
defatting.
ROUTE OF EXPOSURE, SIGNS AND SYMPTOMS
INHALATION
Nasal and respiratory irritation, dizziness, narcosis, headache, nausea,
CNS depression, and unconsciousness.
EYE CONTACT
Watering, blurred vision, inflammation, and irritation which can result in
corneal injury.
SKIN CONTACT
Irritation, dermatitis.
INGESTION
Nausea, vomiting; CNS depression; irritation of gastrointestinal tract,
liver and peritoneal wall; lung congestion.
SUMMARY OF CHRONIC HAZARDS
Skin irritation, contact dermatitis, and defatting.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Individuals with pre-existing or chronic diseases of the eyes, skin,
respiratory system, cardiovascular system, gastrointestinal system, liver,
or kidneys may have increased susceptibility to excessive exposure.
=============================================================================
Section 4 -- FIRST AID MEASURES
----------------------------------------------------------------------------If INHALED:
If overcome by exposure, remove victim to fresh air
immediately. Give oxygen or artificial respiration as
needed. Obtain emergency medical attention. Prompt

action is essential.
Immediately wash with soap and water. Remove and wash
any contaminated clothing.
If in EYES:
Flush eyes with large amounts of water for 15 minutes.
Get medical attention if irritation persists.
If SWALLOWED:
If swallowed, call a physician immediately. Only induce
vomiting at the instruction of a physician. Never give
anything by mouth to an unconscious person.
=============================================================================
Section 5 -- FIRE FIGHTING MEASURES
----------------------------------------------------------------------------FLASH POINT
LEL
UEL
None
N/D
N/D
EXTINGUSING MEDIA
Non-flammable. Use agents appropriate for surrounding fires.
SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained full face piece
breathing apparatus and other protective clothing. Hazardous decomposition
products possible (see Section 10).
UNUSUAL FIRE AND EXPLOSION HAZARDS: None
=============================================================================
Section 6 -- ACCIDENTAL RELEASE MEASURES
----------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove all sources
of ignition. Use absorbent materials to prevent footing hazard and to contain.
Ventilate area with natural or explosion-proof, forced air ventilation. Avoid
flushing into sewers, drains, waterways, and soil. Wear protective clothing
and respiratory protection during cleanup.
=============================================================================
Section 7 -- HANDLING AND STORAGE
----------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed and
upright when not in use. Do not store near heat, sparks, or open flames.
OTHER PRECAUTIONS: Avoid prolonged or repeated contact with skin or clothing.
Empty containers may contain residues; treat as if full and observe all
products precautions. Do not reuse empty containers.
=============================================================================
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
----------------------------------------------------------------------------RESPIRATORY PROTECTION (SPECIFY TYPE): In confined, poorly ventilated areas,
use NIOSH/MSHA approved air purifying or supplied air respirators during
soldering operations until fumes have dissipated.
VENTILATION - LOCAL EXHAUST: Acceptable
SPECIAL: Explosion proof
MECHANICAL (GENERAL): Acceptable
OTHER: N/A
PROTECTIVE GLOVES: Wear rubber gloves.
EYE PROTECTION: Safety glasses (ANSI Z-87.1 or equivalent)
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Chemical resistant coveralls
recommended.
WORK/HYGIENIC PRACTICES: Where use can result in skin contact, wash exposed
areas thoroughly before eating, drinking, smoking, or leaving work area.
Launder contaminated clothing before reuse.
=============================================================================
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
----------------------------------------------------------------------------BOILING POINT:
212 F (100 C) @ 760mm Hg
SPECIFIC GRAVITY (H20 = 1):
0.99
VAPOR PRESSURE (mm Hg):
17 @ 68 F (20 C)
MELTING POINT:
N/A
VAPOR DENSITY (AIR = 1):
<1
If on SKIN:

EVAPORATION RATE (ETHYL ACETATE = 1): >1
APPEARANCE/ODOR:
Green Liquid / Mild Odor
SOLUBILITY IN WATER:
Soluble
=============================================================================
Section 10 -- STABILITY AND REACTIVITY
----------------------------------------------------------------------------STABILITY: Stable
CONDITIONS TO AVOID: None
INCOMPATIBILITY (MATERIALS TO AVOID): Heat, sparks and open flames.
HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO, and fragmented hydrocarbons.
HAZARDOUS POLYMERIZATION: Will not occur.
=============================================================================
Section 11 -- TOXICOLOGY INFORMATION
----------------------------------------------------------------------------CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
----------------------------------------------------------------------------TOXICOLOGY DATA
Ingredient Name
----------------------------------------------------------------------------Glycol Ether EB
Oral-Rat LD50:470 mg/kg
Inhalation-Rat TCLo:200 ppm/6H
=============================================================================
Section 12 -- Ecological Information
----------------------------------------------------------------------------ECOLOGICAL DATA
Ingredient Name
----------------------------------------------------------------------------Glycol Ether EB
Food Chain Concentration Potential
None
WATERFOWL TOXICITY
N/A
BOD
26%
AQUATIC TOXICITY
1000 ppm/24 hr/brine shrimp/TLm
=============================================================================
Section 13 -- DISPOSAL CONSIDERATIONS
----------------------------------------------------------------------------Waste Classification: Non-regulated liquid waste.
Disposal Method: Dispose of in accordance with local, state and federal
regulations.
=============================================================================
Section 14 -- TRANSPORTATION INFORMATION
----------------------------------------------------------------------------DOT: Non-regulated
OCEAN (IMDG): Non-regulated
AIR (IATA): Non-regulated
WHMIS (CANADA): Non-regulated
=============================================================================
Section 15 -- REGULATORY INFORMATION
----------------------------------------------------------------------------REGULATORY DATA
Ingredient Name
----------------------------------------------------------------------------Glycol Ether EB
SARA 313
Yes
TSCA Inventory
Yes
CERCLA RQ
N/A
RCRA Code
N/A
=============================================================================
Section 16 -- OTHER INFORMATION

----------------------------------------------------------------------------This document is prepared pursuant to the OSHA Hazard Communication
Standard (29 CFR 1910.1200). The information herein is given in good faith,
but no warranty, expressed or implied is made. Consult RectorSeal for further
information: (713) 263-8001

MATERIAL SAFETY DATA SHEET
MSDS 0091
=============================================================================
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
----------------------------------------------------------------------------HMIS CODES
PRODUCT NAME
Health
2
RectorSeal Concentrated Evaporator Coil Cleaner
Flammability
0
Reactivity
0
PRODUCT CODES
PPI
B
82552, 82555, 82558
CHEMICAL FAMILY
Organic/Inorganic
USE
Coil Cleaner
MANUFACTURER'S NAME
EMERGENCY TELEPHONE NO.
The RectorSeal Corporation
Chemtrec 24 Hours
2601 Spenwick Drive
(800) 424-9300
Houston, Texas 77055 USA
DATE OF PREPARATION
TECHNICAL SERVICE TELEPHONE NO.
June 30, 2005
(800) 231-3345
=============================================================================
Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
----------------------------------------------------------------------------% by WT
CAS No. INGREDIENT
UNITS
1-5
111-76-2 Glycol Ether EB
ACGIH TLV
25 ppm
OSHA PEL
25 ppm
=============================================================================
Section 3 -- HAZARDS IDENTIFICATION
----------------------------------------------------------------------------SUMMARY OF ACUTE HAZARDS
Irritation to eyes, nose, and throat; drowsiness, narcosis, tremors, and
other CNS effects at high concentrations. Skin irritation, dermatitis, and
defatting.
ROUTE OF EXPOSURE, SIGNS AND SYMPTOMS
INHALATION
Nasal and respiratory irritation, dizziness, narcosis, headache, nausea,
CNS depression, and unconsciousness.
EYE CONTACT
Watering, blurred vision, inflammation, and irritation which can result in
corneal injury.
SKIN CONTACT
Irritation, dermatitis.
INGESTION
Nausea, vomiting; CNS depression; irritation of gastrointestinal tract,
liver and peritoneal wall; lung congestion.
SUMMARY OF CHRONIC HAZARDS
Skin irritation, contact dermatitis, and defatting.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Individuals with pre-existing or chronic diseases of the eyes, skin,
respiratory system, cardiovascular system, gastrointestinal system, liver,
or kidneys may have increased susceptibility to excessive exposure.
=============================================================================
Section 4 -- FIRST AID MEASURES
----------------------------------------------------------------------------If INHALED:
If overcome by exposure, remove victim to fresh air
immediately. Give oxygen or artificial respiration as
needed. Obtain emergency medical attention. Prompt

action is essential.
Immediately wash with soap and water. Remove and wash
any contaminated clothing.
If in EYES:
Flush eyes with large amounts of water for 15 minutes.
Get medical attention if irritation persists.
If SWALLOWED:
If swallowed, call a physician immediately. Only induce
vomiting at the instruction of a physician. Never give
anything by mouth to an unconscious person.
=============================================================================
Section 5 -- FIRE FIGHTING MEASURES
----------------------------------------------------------------------------FLASH POINT
LEL
UEL
None
N/D
N/D
EXTINGUSING MEDIA
Non-flammable. Use agents appropriate for surrounding fires.
SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained full face piece
breathing apparatus and other protective clothing. Hazardous decomposition
products possible (see Section 10).
UNUSUAL FIRE AND EXPLOSION HAZARDS: None
=============================================================================
Section 6 -- ACCIDENTAL RELEASE MEASURES
----------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove all sources
of ignition. Use absorbent materials to prevent footing hazard and to contain.
Ventilate area with natural or explosion-proof, forced air ventilation. Avoid
flushing into sewers, drains, waterways, and soil. Wear protective clothing
and respiratory protection during cleanup.
=============================================================================
Section 7 -- HANDLING AND STORAGE
----------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed and
upright when not in use. Do not store near heat, sparks, or open flames.
OTHER PRECAUTIONS: Avoid prolonged or repeated contact with skin or clothing.
Empty containers may contain residues; treat as if full and observe all
products precautions. Do not reuse empty containers.
=============================================================================
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
----------------------------------------------------------------------------RESPIRATORY PROTECTION (SPECIFY TYPE): In confined, poorly ventilated areas,
use NIOSH/MSHA approved air purifying or supplied air respirators during
soldering operations until fumes have dissipated.
VENTILATION - LOCAL EXHAUST: Acceptable
SPECIAL: Explosion proof
MECHANICAL (GENERAL): Acceptable
OTHER: N/A
PROTECTIVE GLOVES: Wear rubber gloves.
EYE PROTECTION: Safety glasses (ANSI Z-87.1 or equivalent)
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Chemical resistant coveralls
recommended.
WORK/HYGIENIC PRACTICES: Where use can result in skin contact, wash exposed
areas thoroughly before eating, drinking, smoking, or leaving work area.
Launder contaminated clothing before reuse.
=============================================================================
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
----------------------------------------------------------------------------BOILING POINT:
212 F (100 C) @ 760mm Hg
SPECIFIC GRAVITY (H20 = 1):
0.99
VAPOR PRESSURE (mm Hg):
17 @ 68 F (20 C)
MELTING POINT:
N/A
VAPOR DENSITY (AIR = 1):
<1
If on SKIN:

EVAPORATION RATE (ETHYL ACETATE = 1): >1
APPEARANCE/ODOR:
Green Liquid / Mild Odor
SOLUBILITY IN WATER:
Soluble
=============================================================================
Section 10 -- STABILITY AND REACTIVITY
----------------------------------------------------------------------------STABILITY: Stable
CONDITIONS TO AVOID: None
INCOMPATIBILITY (MATERIALS TO AVOID): Heat, sparks and open flames.
HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO, and fragmented hydrocarbons.
HAZARDOUS POLYMERIZATION: Will not occur.
=============================================================================
Section 11 -- TOXICOLOGY INFORMATION
----------------------------------------------------------------------------CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
----------------------------------------------------------------------------TOXICOLOGY DATA
Ingredient Name
----------------------------------------------------------------------------Glycol Ether EB
Oral-Rat LD50:470 mg/kg
Inhalation-Rat TCLo:200 ppm/6H
=============================================================================
Section 12 -- Ecological Information
----------------------------------------------------------------------------ECOLOGICAL DATA
Ingredient Name
----------------------------------------------------------------------------Glycol Ether EB
Food Chain Concentration Potential
None
WATERFOWL TOXICITY
N/A
BOD
26%
AQUATIC TOXICITY
1000 ppm/24 hr/brine shrimp/TLm
=============================================================================
Section 13 -- DISPOSAL CONSIDERATIONS
----------------------------------------------------------------------------Waste Classification: Non-regulated liquid waste.
Disposal Method: Dispose of in accordance with local, state and federal
regulations.
=============================================================================
Section 14 -- TRANSPORTATION INFORMATION
----------------------------------------------------------------------------DOT: Non-regulated
OCEAN (IMDG): Non-regulated
AIR (IATA): Non-regulated
WHMIS (CANADA): Non-regulated
=============================================================================
Section 15 -- REGULATORY INFORMATION
----------------------------------------------------------------------------REGULATORY DATA
Ingredient Name
----------------------------------------------------------------------------Glycol Ether EB
SARA 313
Yes
TSCA Inventory
Yes
CERCLA RQ
N/A
RCRA Code
N/A
=============================================================================
Section 16 -- OTHER INFORMATION

----------------------------------------------------------------------------This document is prepared pursuant to the OSHA Hazard Communication
Standard (29 CFR 1910.1200). The information herein is given in good faith,
but no warranty, expressed or implied is made. Consult RectorSeal for further
information: (713) 263-8001

MATERIAL SAFETY DATA SHEET
MSDS 0128
=============================================================================
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
----------------------------------------------------------------------------HMIS CODES
PRODUCT NAME
Health
2
Clean-N-Safe Aerosol Coil Cleaner
Flammability
2
Reactivity
0
PRODUCT CODES
PPI
B
83780
CHEMICAL FAMILY
Organic/Inorganic
USE
Coil Cleaner
MANUFACTURER'S NAME
EMERGENCY TELEPHONE NO.
The RectorSeal Corporation
Chemtrec 24 Hours
2601 Spenwick Drive
(800) 424-9300
Houston, Texas 77055 USA
DATE OF PREPARATION
TECHNICAL SERVICE TELEPHONE NO.
June 8, 2005
(800) 231-3345
=============================================================================
Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
----------------------------------------------------------------------------% by WT
CAS No. INGREDIENT
UNITS
-9036-19-5
Octylphenoxypolyethoxyethanol
ACGIH TLV
N/D
OSHA PEL
N/D
-57018-52-7
Polylene Glycol Butyl Ether
ACGIH TLV
N/D
OSHA PEL
N/D
-6834-92-0
Sodium Metasilicate
ACGIH TLV
N/D
OSHA PEL
N/D
=============================================================================
Section 3 -- HAZARDS IDENTIFICATION
----------------------------------------------------------------------------SUMMARY OF ACUTE HAZARDS
Irritation to eyes, nose, and throat; drowsiness, narcosis, tremors, and
other CNS effects at high concentrations. Skin irritation, dermatitis, and
defatting.
ROUTE OF EXPOSURE, SIGNS AND SYMPTOMS
INHALATION
Nasal and respiratory irritation, dizziness, narcosis, headache, nausea,
CNS depression, and unconsciousness.
EYE CONTACT
Watering, blurred vision, inflammation, and irritation which can result in
corneal injury.
SKIN CONTACT
Irritation, dermatitis.
INGESTION
Nausea, vomiting; CNS depression; irritation of gastrointestinal tract,
liver and peritoneal wall; lung congestion.
SUMMARY OF CHRONIC HAZARDS
Skin irritation, contact dermatitis, and defatting.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Individuals with pre-existing or chronic diseases of the eyes, skin,
respiratory system, cardiovascular system, gastrointestinal system, liver,
or kidneys may have increased susceptibility to excessive exposure.

=============================================================================
Section 4 -- FIRST AID MEASURES
----------------------------------------------------------------------------If INHALED:
If overcome by exposure, remove victim to fresh air
immediately. Give oxygen or artificial respiration as
needed. Obtain emergency medical attention. Prompt
action is essential.
If on SKIN:
Immediately wash with soap and water. Remove and wash
any contaminated clothing.
If in EYES:
Flush eyes with large amounts of water for 15 minutes.
Get medical attention if irritation persists.
If SWALLOWED:
If swallowed, call a physician immediately. Only induce
vomiting at the instruction of a physician. Never give
anything by mouth to an unconscious person.
=============================================================================
Section 5 -- FIRE FIGHTING MEASURES
----------------------------------------------------------------------------FLASH POINT
LEL
UEL
Not combustible, Negative Flame Extension
N/D
N/D
NFPA Level 1 Aerosol
EXTINGUSING MEDIA
Use extinguishing agents appropriate for surrounding fires.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Aerosol cans are under pressure exposure to temperatures above 120F can cause bursting or "rocketing" of cans.
=============================================================================
Section 6 -- ACCIDENTAL RELEASE MEASURES
----------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Depressurize
and dispose of empty cans
=============================================================================
Section 7 -- HANDLING AND STORAGE
----------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Shake well before using.
Keep away from heat, sparks and open flames. Prolonged exposure to direct
sunshine or storage above 120 F may cause can to burst. Do not puncture or
incinerate can.
OTHER PRECAUTIONS: Avoid prolonged or repeated contact with skin or clothing.
Empty containers may contain residues; treat as if full and observe all
products precautions.
=============================================================================
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
----------------------------------------------------------------------------RESPIRATORY PROTECTION (SPECIFY TYPE): None required.
VENTILATION - LOCAL EXHAUST: N/A
SPECIAL: N/A
MECHANICAL (GENERAL): N/A
OTHER: N/A
PROTECTIVE GLOVES: None required.
EYE PROTECTION: Safety glasses (ANSI Z-87.1 or equivalent)
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: None normally required.
WORK/HYGIENIC PRACTICES: Where use can result in skin contact, wash exposed
areas thoroughly before eating, drinking, smoking, or leaving work area.
Launder contaminated clothing before reuse.
=============================================================================
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
----------------------------------------------------------------------------BOILING POINT:
>230 F (110 C) @ 760mm Hg
SPECIFIC GRAVITY (H20 = 1):
1.0
VAPOR PRESSURE (mm Hg):
N/D
MELTING POINT:
N/A

VAPOR DENSITY (AIR = 1):
N/D
EVAPORATION RATE (ETHYL ACETATE = 1): Similar to water
APPEARANCE/ODOR:
Clear Liquid / Fresh Odor
SOLUBILITY IN WATER:
Soluble
=============================================================================
Section 10 -- STABILITY AND REACTIVITY
----------------------------------------------------------------------------STABILITY: Stable
CONDITIONS TO AVOID: Do not store in temperatures above 120 F.
INCOMPATIBILITY (MATERIALS TO AVOID): None known
HAZARDOUS DECOMPOSITION PRODUCTS: None known
HAZARDOUS POLYMERIZATION: Will not occur.
=============================================================================
Section 11 -- TOXICOLOGY INFORMATION
----------------------------------------------------------------------------CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
----------------------------------------------------------------------------TOXICOLOGY DATA
Ingredient Name
----------------------------------------------------------------------------Octylphenoxypolyethoxyethanol
Oral-Rat LD50:4190 mg/kg
Inhalation-Rat LC50:N/D
Polylene Glycol Butyl Ether
Oral-Rat LD50:N/D
Inhalation-Rat LC50:N/D
Sodium Metasilicate
Oral-Rat LD50:1153 mg/kg
Inhalation-Rat LC50:N/D
=============================================================================
Section 12 -- Ecological Information
----------------------------------------------------------------------------ECOLOGICAL DATA
Ingredient Name
----------------------------------------------------------------------------Octylphenoxypolyethoxyethanol
Food Chain Concentration Potential
N/D
WATERFOWL TOXICITY
N/D
BOD
N/D
AQUATIC TOXICITY
N/D
Polylene Glycol Butyl Ether
Food Chain Concentration Potential
N/D
WATERFOWL TOXICITY
N/D
BOD
N/D
AQUATIC TOXICITY
N/D
Sodium Metasilicate
Food Chain Concentration Potential
N/D
WATERFOWL TOXICITY
N/D
BOD
N/D
AQUATIC TOXICITY
N/D
=============================================================================
Section 13 -- DISPOSAL CONSIDERATIONS
----------------------------------------------------------------------------Waste Classification: Aerosols
Disposal Method: Empty containers can be disposed of in trash. Full
containers should be depressurized to separate liquid phase. The liquid
phase is considered a D001 ignitable waste and should be incinerated.
Dispose of all liquid waste in accordance with all local, state and federal
regulations.

=============================================================================
Section 14 -- TRANSPORTATION INFORMATION
----------------------------------------------------------------------------DOT: Consumer Commodity, ORM-D
OCEAN (IMDG): Aerosols, Class 2, UN 1950, IMDG#2102, EMS#2-13
AIR (IATA): Aerosols, 2.2, UN1950, ERG#126
WHMIS (CANADA): Class A
=============================================================================
Section 15 -- REGULATORY INFORMATION
----------------------------------------------------------------------------REGULATORY DATA
Ingredient Name
----------------------------------------------------------------------------Octylphenoxypolyethoxyethanol
SARA 313
No
TSCA Inventory
Yes
CERCLA RQ
N/A
RCRA Code
N/A
Polylene Glycol Butyl Ether
SARA 313
No
TSCA Inventory
Yes
CERCLA RQ
N/A
RCRA Code
N/A
Sodium Metasilicate
SARA 313
No
TSCA Inventory
Yes
CERCLA RQ
N/A
RCRA Code
N/A
=============================================================================
Section 16 -- OTHER INFORMATION
----------------------------------------------------------------------------This document is prepared pursuant to the OSHA Hazard Communication
Standard (29 CFR 1910.1200). The information herein is given in good faith,
but no warranty, expressed or implied is made. Consult RectorSeal for further
information: (713) 263-8001

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name:
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

FORMULA 496655
ZENASHEEN H20
ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Mineral Oil
Propane
Butane
Isoparaffinic Hydrocarbon
Silicone
Isobutane
Ester

CAS No.:
8042-47-5
74-98-6
106-97-8
64741-66-8
63148-62-9
75-28-5
9007-48-1

TLV:
5 mg/m3 as mist
2500ppm
800ppm
Not established
Not established
Not established
Not established

______________________________________________________________________________

SECTION 3
Boiling Point:
Solubility in Water:
Vapor Density(Air=1):

PHYSICAL DATA
<0 to 4510 F
Emulsion
Heavier than air

Specific Gravity(H2O=1):
Evaporation Rate:
pH:

0.89 + 0.05
Slower than Ether
10.75 + 0.5

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flash Point(Propellant):
Flammable Limits(Propellant):
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

150OF
<0OF
LEL:
1.9
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5
Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.

First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________

SECTION 9

SPILL OR LEAK PROCEDURE

Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None

__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
496655

MATERIAL SAFETY DATA SHEET
(SIMILAR TO OSHA FORM 174)

N.A. = Not Applicable
Not Est. = Not Established
Prop. = Proprietary

SECTION 1 - MANUFACTURER / DISTRIBUTOR INFORMATION
Product Name: FRESH START Concentrated Malodor Counteractant	
Supplier’s Name: National Chemical Laboratories of PA, Inc.
Supplier’s Address: 401 N. 10th Street · Philadelphia PA 19123	
HMIS Hazard Code: Health: 1 Flammability: 0 Reactivity: 0 Other: 0	
Chemical Family: Odor Control Agent	
D.O.T. Shipping Name: N/A	

Product #: 1415
Emergency Phone #: CHEM-TEL (800) 255-3924
Chemical Name: N.A. Proprietary Blend
Formula: N.A. Blended Product
Hazard Class: N/A	
D.O.T. ID#: N/A

SECTION 2 - HAZARDOUS INGREDIENTS
CHEMICAL NAME	
None

CAS NUMBER 	

% Concentration Range 	 Hazard Ratings (TLV/PEL)

SECTION 3 - PHYSICAL DATA
Boiling Point (°F): 212	
Vapor Pressure: = To Water	
Vapor Density: = To Water
Solubility in Water: Complete
Appearance: Clear Blue Liquid
Odor: Astra

Specific Gravity: 1.001
Evaporation Rate: = To Water

SECTION 4 - FIRE AND EXPLOSION DATA
Flash Point (°F): None to boiling (TOC)
Flammable Limits: Not Flammable
Extinguising Media: Foam, CO2, water fog, BC/ABC extinguisher may be used in area where material is stored.
Special Fire Fighting Procedures: None known
Unusual Fire & Explosion Hazards: None known.
SECTION 5 - HEALTH HAZARD DATA
Route(s) of Entry: Inhalation: No Skin: Yes Ingestion: Yes		
Threshold Limit Value: Not Est.
Effects of Overexposure: May cause skin and eye irritation. May be harmful if swallowed.
Emergency & First Aid Procedures: For Eyes: Flush eyes with water for at least fifteen minutes. If irritation persists seek medical attention. For
Skin: Flush skin thoroughly with water. If irritation persists seek medical attention. If ingested: Do not induce vomiting. Give large quantities of water.
Seek medical attention. Never give anything by mouth to an unconscious person.
Conditions Aggravated by Exposure: May aggravate pre-existing pulmonary conditions.
Listed Carcinogen, Mutagen, Teratogen (Ingredient, Source, Amount): None
SECTION 6 - REACTIVITY DATA
Stability: Stable
Conditions to Avoid: None
Incompatibility: Avoid contact with acids and oxidizers.
Hazardous Decomposition Products: None known
Hazardous Polymerization: Will not occur.
SECTION 7 - SPILL OR LEAK PROCEDURES
Steps to be taken if material is released or spilled: Ventilate area and recontainerize by mopping, wet vacuum, or the use of a suitable absorbent.
Waste disposal method: Follow local, state and federal regulations.
SECTION 8 - SPECIAL PROTECTION INFORMATION
Respiratory Protection: Not required
Ventilation: Local
Protective Gloves: Recommended for prolonged contact.
Eye Protection: Goggles or safety glasses with side shields.
Other Protective Equipment: None.
SECTION 9 – SPECIAL PRECAUTIONS
Precautions to be taken in handling and storage: Store between 40°F and 120°F. Avoid contact with skin and eyes. Do not ingest.
Other Precautions: Keep out of reach of children. For professional use only.
The information contained in this MSDS was obtained from current and reliable sources, however the data is provided without any warranty, expressed or implied, regarding
its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of this company, it is not responsible for loss, injury
and expense arising out of the product’s improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any
statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use or disposal of this product which
may be covered by this MSDS. The user is responsible for full compliance.

Date Prepared – 03/24/08

By: G.C.

MATERIAL SAFETY DATA SHEET
(SIMILAR TO OSHA FORM 174)

N.A. = Not Applicable
Not Est. = Not Established
Prop. = Proprietary

SECTION 1 - MANUFACTURER / DISTRIBUTOR INFORMATION
Product Name: FRESH START Concentrated Malodor Counteractant	
Supplier’s Name: National Chemical Laboratories of PA, Inc.
Supplier’s Address: 401 N. 10th Street · Philadelphia PA 19123	
HMIS Hazard Code: Health: 1 Flammability: 0 Reactivity: 0 Other: 0	
Chemical Family: Odor Control Agent	
D.O.T. Shipping Name: N/A	

Product #: 1415
Emergency Phone #: CHEM-TEL (800) 255-3924
Chemical Name: N.A. Proprietary Blend
Formula: N.A. Blended Product
Hazard Class: N/A	
D.O.T. ID#: N/A

SECTION 2 - HAZARDOUS INGREDIENTS
CHEMICAL NAME	
None

CAS NUMBER 	

% Concentration Range 	 Hazard Ratings (TLV/PEL)

SECTION 3 - PHYSICAL DATA
Boiling Point (°F): 212	
Vapor Pressure: = To Water	
Vapor Density: = To Water
Solubility in Water: Complete
Appearance: Clear Blue Liquid
Odor: Astra

Specific Gravity: 1.001
Evaporation Rate: = To Water

SECTION 4 - FIRE AND EXPLOSION DATA
Flash Point (°F): None to boiling (TOC)
Flammable Limits: Not Flammable
Extinguising Media: Foam, CO2, water fog, BC/ABC extinguisher may be used in area where material is stored.
Special Fire Fighting Procedures: None known
Unusual Fire & Explosion Hazards: None known.
SECTION 5 - HEALTH HAZARD DATA
Route(s) of Entry: Inhalation: No Skin: Yes Ingestion: Yes		
Threshold Limit Value: Not Est.
Effects of Overexposure: May cause skin and eye irritation. May be harmful if swallowed.
Emergency & First Aid Procedures: For Eyes: Flush eyes with water for at least fifteen minutes. If irritation persists seek medical attention. For
Skin: Flush skin thoroughly with water. If irritation persists seek medical attention. If ingested: Do not induce vomiting. Give large quantities of water.
Seek medical attention. Never give anything by mouth to an unconscious person.
Conditions Aggravated by Exposure: May aggravate pre-existing pulmonary conditions.
Listed Carcinogen, Mutagen, Teratogen (Ingredient, Source, Amount): None
SECTION 6 - REACTIVITY DATA
Stability: Stable
Conditions to Avoid: None
Incompatibility: Avoid contact with acids and oxidizers.
Hazardous Decomposition Products: None known
Hazardous Polymerization: Will not occur.
SECTION 7 - SPILL OR LEAK PROCEDURES
Steps to be taken if material is released or spilled: Ventilate area and recontainerize by mopping, wet vacuum, or the use of a suitable absorbent.
Waste disposal method: Follow local, state and federal regulations.
SECTION 8 - SPECIAL PROTECTION INFORMATION
Respiratory Protection: Not required
Ventilation: Local
Protective Gloves: Recommended for prolonged contact.
Eye Protection: Goggles or safety glasses with side shields.
Other Protective Equipment: None.
SECTION 9 – SPECIAL PRECAUTIONS
Precautions to be taken in handling and storage: Store between 40°F and 120°F. Avoid contact with skin and eyes. Do not ingest.
Other Precautions: Keep out of reach of children. For professional use only.
The information contained in this MSDS was obtained from current and reliable sources, however the data is provided without any warranty, expressed or implied, regarding
its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of this company, it is not responsible for loss, injury
and expense arising out of the product’s improper use. No warranty, expressed or inferred, regarding the product described in this MSDS shall be created or inferred by any
statement in this MSDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use or disposal of this product which
may be covered by this MSDS. The user is responsible for full compliance.

Date Prepared – 03/24/08

By: G.C.

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name:
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

FORMULA 491963
ZENEZE FOGGER
ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
5-31-02

______________________________________________________________________________

SECTION 2
Chemical Name:
Water
Surfactant
Surfactant
Methyl Ether
Perfume

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS
CAS No.:
7732-18-5
68298-20-4
68412-54-4
115-10-6
Proprietary

TLV:
Not applicable
Not established
Not established
Not established
Not available

Carcinogen:
No
No
No
No
No

This formula contains no ingredients subject to the reporting requirements of SARA title III, section 313.

______________________________________________________________________________

SECTION 3
Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA
<00 F
Complete
Clear liquid, unique scent

Specific Gravity :
Evaporation Rate(H2O=1):
pH (Concentrate):

1.01 + .01
1.0 + 0.2
10.0 + 0.5

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Propellant: <00 F
Flammable Limits:
LEL: 3.4
UEL: 27
Extinguishing Media:
Use water fog, dry chemical or carbon dioxide.
Special Fire Fighting Procedures:
Aerosol cans may rupture when heated
Unusual Fire and Explosion Hazards:
Heated cans may burst.
_______________________________________________________________________________________________________________________________________

SECTION 5
Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide and carbon monoxide.
Will not occur.

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved
respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination. Extreme overexposure may result in unconsciousness and
possibly death.
INGESTION: Aspiration hazard if swallowed.

First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION: DO NOT induce vomiting. Seek medical attention immediately. Note:
Never give anything by mouth to an unconscious or convulsing victim. Keep person
warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

None normally required.
Provide local exhaust.
None required if spraying.
ZENEX supports employee safety as priority #1. Therefore, we recommend the use of safety
glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________

SECTION 9

SPILL OR LEAK PROCEDURE

Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None

__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this time.
Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties,
express or implied, and assume no liability in connection with any use of this information.
491963

The Procter & Gamble Company
P&G Household Care
Fabric & Home Care Innovation Center
5299 Spring Grove Avenue
Cincinnati, OH 45217-1087

MATERIAL SAFETY DATA SHEET
MSDS #:FH/F/2007/RPRL-6YWNSS
FH/F/2006/NMNE-6SCML6
Supersedes: FH/F/2004/VBVV-63YQ5Y

Issue Date: 3/22/07
Issue Date: 8/30/04

SECTION I - PRODUCT IDENTIFICATION
Identity: Fabric Refresher

Finished Product

Brands: FEBREZE FABRIC REFRESHER (Allergen Reducer, Extra Strength, Pet Odor Eliminator,
Spring & Renewal, Meadows & Rain, Linen & Sky, Citrus & Light, Auto, and Lavender Vanilla &
Comfort)
P&G Telephone Number: 1-800-308-EASY (1-800-308-3279)
or call Local Poison Control Center or your physician.

SECTION II - HAZARDS IDENTIFICATION
Potential Health Hazards (Acute and Chronic): (See Section 11 for more information)
Ingestion: None known.
Eye Contact: Mild eye irritant.
Skin Contact: Prolonged skin contact may result in transient, superficial effects similar to those produced by mild
toilet soap
Inhalation: None known.
Signs and Symptoms of Exposure:
Ingestion: Possible mild gastrointestinal irritation with nausea, vomiting, and/or diarrhea.
Eye Contact: Instillation into the eye may result in transient, superficial effects similar to those produced by mild
toilet soap.
Skin Contact: Prolonged skin contact may result in transient, superficial effects similar to those produced by mild
toilet soap.
Inhalation: None known.
Medical Conditions Generally Known to be Aggravated by Exposure: None known.
Potential Environmental Effects: (See Section 12 for more information)
SECTION III - COMPOSITION AND INGREDIENTS
Ingredients listed on the product label are: Water, alcohol, odor eliminator derived from corn, and fragrance.
Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200. and/or WHMIS under the HPA:
LD50/LC50
CAS No.
Composition
Common Name
Chemical Name
Range
Ethyl Alcohol
Ethanol
64-17-5
1-5%
7.06 g/kg rat, oral
Febreze Fabric Refresher

Page 1 of 5

SECTION IV – FIRST AID INFORMATION
First Aid Procedures:
Ingestion: Dilute with fluids and treat symptomatically.
Eye Contact: Rinse well with water for at least 15 minutes.
Skin Contact: Rinse with water.
Inhalation: Remove to fresh air.
Note to Physician: Treat symptomatically.
Other: Consumer product package has the following precautionary statement: USE ONLY AS INTENDED.
KEEP OUT OF THE REACH OF CHILDREN. Do not spray directly toward face. If eye contact occurs,
rinse well with water.
SECTION V - FIRE FIGHTING INFORMATION
Flash Point (Method Used):
Allergen Reducer: 136 ºF / 58 ºC (Closed Cup)
Other scent variants: 156 – 159 ºF / 68 – 71 ºC (Closed Cup)
Products do not sustain combustion (ASTM D 4206)
Flammable Properties: Products are not considered flammable, and do not sustain combustion
Upper Flammable Limit: N/K
Lower Flammable Limit: N/K
Explosive Limits:

UEL: N/A

LEL: N/A

Auto-ignition Temperature: N/K
Hazardous Combustion Products: None known
Explosion Data (Sensitivity to Mechanical Impact): N/A
Explosion Data (Sensitivity to Static Discharge): N/A
Extinguishing Media:
Suitable: CO2, water, or dry chemical may be used.
Unsuitable: N/K
Protection of Firefighters:
Specific Hazards Arising from the Material: None known
Protective Equipment and Precautions for Firefighters: Normal fire-fighting gear.
SECTION VI - ACCIDENTAL RELEASE MEASURES
Personal Precautions: None
Environmental Precautions: Disposal is to be performed in compliance with federal, state/provincial and local
regulations. Slowly flush down sewer with excess water or dispose as liquid scrap. Discard empty container in
trash. Do not landfill liquids.
Methods for Containment: Dike or contain spill. Absorb with inert material and dispose. Flush area with water.
Prevent washings from entering waterways. Sorbents may be used.
Methods for Cleanup: Use water spray to dilute and/or wash away spills to avoid exposure and to protect persons
working to stop/repair leak. Any spills are to be prevented from entering waterways. Sorbents may be used.
Other Information: (if applicable)

Febreze Fabric Refresher

Page 2 of 5

SECTION VII – HANDLING AND STORAGE
Precautions To Be Taken in Handling: None.
Precautions To B e Taken in Storage: Store at room temperature.
SECTION VIII - EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines:
Ethanol (CAS# 64-17-5) ACGIH-TLV 1000 ppm
OSHA Z-1 PEL 1000 ppm
Engineering Controls: None required
Personal Protective Equipment (PPE):
Eye/Face Protection: None required for normal consumer use.
Industrial setting: If a splash of solution is likely, chemical goggles may be needed.
Skin Protection: None required for normal consumer use.
Industrial setting: Minimize skin contact with protective gloves (rubber or neoprene).
Respiratory Protection: None required with normal consumer use.
Industrial setting: Use ventilation to minimize exposure to vapor or mist (ethanol).
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Appearance (color, physical form, shape):

Flash Point (Method Used):

Clear liquid

Allergen Reducer: 136 ºF / 58 ºC (CC)
Other scent variants: 156 – 159 ºF / 68 – 71 ºC (CC)
Products do not sustain combustion (ASTM D 4206)

Odor: Products are perfumed.

Reserve Alkalinity: N/A

Odor Threshold: N/A

Solubility in Water: Soluble

Physical State: Liquid

Decomposition Temperature: N/A

Vapor Pressure (mm Hg): N/A

Evaporation Rate (nBuOAc=1):

Vapor Density (Air=1): N/A

Specific Gravity/Density: ~ 1.0

Boiling Point: ~ 212 ºF / ~ 100 ºC

Melting/Freezing Point: N/A

Partition Coefficient (n-octanol/water): N/A

pH (100% solution):

N/K

Allergen Reducer: pH = 6.5 -6.9
Other scent variants: pH = 7.8 – 8.0
Volatile Organic Compound (VOC): Product complies with State and Federal regulations for VOC content.
SECTION X - STABILITY AND REACTIVITY
Chemical Stability: Stable
Conditions to Avoid: N/K
Incompatible Materials: N/K
Hazardous Decomposition Products: N/K
Possibility of Hazardous Reactions: N/K

Febreze Fabric Refresher

Page 3 of 5

SECTION XI - TOXICOLOGICAL INFORMATION
Febreze is practically nontoxic. If ingested, it may be mildly irritating.
LD50 (oral): > 5000 mg/kg (estimated).
LD50 (dermal): > 5000 mg/kg (estimated).
Chronic Effects: No chronic health effects reported.
Target Organs: No target organs reported.
Carcinogenicity: NTP: No
IARC: No
OSHA: No
SECTION XII - ECOLOGICAL INFORMATION
There are no concerns at relevant environmental concentrations. Based on ecotoxicity and fate data for the
individual ingredients in this formulation and for similar consumer product formulations, this product is
anticipated to be non-hazardous to the environment following consumer usage.
SECTION XIII - DISPOSAL CONSIDERATIONS
Waste Disposal Method: Disposal is to be performed in compliance with federal, state/provincial and local
regulations.
Non-household Setting (US Federal): Products covered by this MSDS, in their original form, when disposed as
waste, are considered non hazardous waste according to Federal RCRA regulations (40 CFR 261). Disposal should
be in accordance with local, state and federal regulations.
Non-Household Setting (California): Not hazardous.
Household Use: Product used in household may be disposed of in refuse or in sewer.

SECTION XIV - TRANSPORT INFORMATION
Ground Transport (US DOT): Products covered by this MSDS, in their original form, are not
regulated for transportation.
Air Transport (IATA): – not regulated
Marine/Water Transport (IMDG): – not regulated

Febreze Fabric Refresher

Page 4 of 5

SECTION XV - REGULATORY INFORMATION
United States:
All intentionally-added components of this (these) product(s) are listed on the US TSCA Inventory.
EPA Registration Number: Not Applicable
SARA 313/302/304/311/312 chemicals: None
California: This product has been evaluated and does not require warning labeling under California Proposition
65.
California Registration Number: Not Applicable
State Right-to-Know and CERCLA:
The following ingredients present in the finished product are listed on state right-to-know lists or state worker
exposure lists
Ingredient
Ethanol

CAS #
64-17-5

Level
1-5%

CERCLA
RQ
100 lbs.

IL
X

MA
X

State
NJ
X

PA
X

RI
X

Canada:
All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified in
accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and this MSDS
contains all information required by the Controlled Products Regulations.
Other: Perfumes contained within the products covered by this MSDS comply with appropriate IFRA guidance.

P&G Hazard Rating:

*N/A. - Not Applicable

SECTION XVI - OTHER INFORMATION
Health:
1
4=EXTREME
Flammability: 2
3=HIGH
Reactivity:
0
2=MODERATE
1=SLIGHT
0=NOT SIGNIFICANT
*N/K. - Not Known

Data supplied is for use only in connection with occupational safety and health.
DISCLAIMER: This MSDS is intended to provide a brief summary of our knowledge and guidance regarding the
use of this material. The information contained here has been compiled from sources considered by Procter &
Gamble to be dependable and is accurate to the best of the Company’s knowledge. It is not meant to be an allinclusive document on worldwide hazard communication regulations.
This information is offered in good faith. Each user of this material needs to evaluate the conditions of use and
design the appropriate protective mechanisms to prevent employee exposures, property damage or release to the
environment. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, or for any
damage to any property resulting from misuse of the product.

Febreze Fabric Refresher

Page 5 of 5

Material Safety Data Sheet

GLADE ODOR COUNTERACTANT
Fire Hazard

National Fire
Protection
Association (NFPA)

Health

4

0 0

Hazardous Material
Information System
(HMIS)

Reactivity

Health
Fire Hazard

0
4

Reactivity

0

Specific Hazard
Protective None required.
Clothing

Emergency
Overview

Colorless. Aerosol. See Section 9.
CAUTION: CONTENTS UNDER PRESSURE. May be mildly
irritating to eyes.

Section 1. Chemical Product and Company Identification
94783

Product Name

GLADE ODOR COUNTERACTANT

Code

Product Use

Industrial/Institutional: Air care.

PMS#

433317

126232001

Validation Date

04/19/2000

Print Date
Supersedes

04/20/2000
04/13/2000.

In Case of
Emergency

(800) 851-7145

MSDS#

U.S. Headquarters
Drackett Professional
A Division of
S.C. Johnson Commercial Markets, Inc.
8310 16th Street
Sturtevant, Wisconsin 53177-0902
Phone: (888) 352-2249

Section 2. Composition and Information on Ingredients
Ingredients

CAS #

% by Weight

Exposure Limits

Isobutane

75-28-5

5-10

Not available.

Propane

74-98-6

5-10

Butane

106-97-8

10-30

Water

7732-18-5

60-100

TWA: 1800 (mg/m3) from
OSHA (PEL) [United States]
TWA: 4508 (mg/m3) from
ACGIH (TLV) [United States]
TWA: 1900 (mg/m3) from
OSHA (PEL) [United States]
TWA: 1900 (mg/m3) from
ACGIH (TLV) [United States]
Not available.

LC50/LD50

VAPOR (LC50): Acute: 0.0057
ppm 0.25 hours [Rat].
Not available.

Not available.

Not applicable.

Section 3. Hazards Identification
Inhalation. Skin contact. Eye contact.

Routes of Entry
Potential Acute Health Effects

Eyes May be mildly irritating to eyes.
Skin None known.
Inhalation None known.
Ingestion None known.
Medical Conditions
None known.
Aggravated by Overexposure:
See Toxicological Information (section 11)

Continued on Next Page
Page: 1/4

GLADE ODOR COUNTERACTANT

Material Safety Data Sheet

Section 4. First Aid Measures
Eye Contact

Flush immediately with plenty of water. Get medical attention if irritation occurs.

Skin Contact

Rinse with plenty of running water.

Inhalation

No specific first aid measures are required.

Ingestion

No specific first aid measures are required.

Section 5. Fire Fighting Measures
Flammability of the Product
Flash Points

NFPA 30B Level 1 Aerosol.
CLOSED CUP: <-7°C (19.4°F).

Products of Combustion

None known.

Fire Fighting Media
and Instructions
Special Remarks on Fire and
Explosion Hazards

Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire
fighting procedure may be used.
Aerosol product - Containers may rocket or explode in heat of fire.

Section 6. Accidental Release Measures
Personal Precautions

Put on appropriate personal protective equipment (see Section 8).

Environmental Precautions
and Clean-up Methods

In the event of major spillage: Use appropriate containment to avoid environmental contamination. Sweep
or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a
water rinse for final clean-up.

Section 7. Handling and Storage
Handling

Avoid contact with eyes. Do not puncture or incinerate. FOR INDUSTRIAL USE ONLY

Storage

Store in a dry, cool and well-ventilated area. Protect from freezing. Keep away from heat, sparks and
flame. Pressurized container: protect from sunlight and do not expose to temperature exceeding 50°C.
Do not pierce or burn, even after use. KEEP OUT OF REACH OF CHILDREN.

Section 8. Exposure Controls/Personal Protection
Engineering Controls

No special ventilation requirements. General room ventilation is adequate.

Personal Protection

Eyes No special protective clothing is required.
Hands No special protective clothing is required.
Respiratory No special protective clothing is required.
Feet No special protective clothing is required.
Body No special protective clothing is required.

Section 9. Physical and Chemical Properties
Physical State and
Appearance
Odor

Liquid. (Aerosol.)

Color

Colorless.

pH

Not applicable.

Solubility in water

Complete.

Fragrance like.

Continued on Next Page
Page: 2/4

GLADE ODOR COUNTERACTANT

Material Safety Data Sheet

Section 10. Stability and Reactivity
Stability and Reactivity

The product is stable.

Conditions of Instability

Excessive heat.

Incompatibility with Various
Substances

Not available.

Hazardous Decomposition
Products

Produces normal products of combustion.

Hazardous Polymerization

Will not occur.

Section 11. Toxicological Information
ORAL (LD50) Estimated to be greater than 5000 mg/kg (rat).

Acute toxicity

Effects of Chronic Exposure None known.

Not available.

Other Toxic Effects

Section 12. Ecological Information
Not available.

Section 13. Disposal Considerations
If possible, recycle empty aerosol cans to the nearest steel recycling center. Use up package or give to
someone who can. Dispose of according to all federal, state and local regulations.

Waste Information

Section 14. Transport Information
DOT Classification

Aerosols

DOT Proper
Shipping Name
DOT Class

CLASS 2.1: Flammable gas.

UN/NA

UN1950

DOT Special
Considerations

Limited Quantity

TDG Classification
TDG Proper
Shipping Name
TDG Class

Aerosols

PIN/NIP

UN1950

TDG Special
Considerations

Limited Quantity

CLASS 2.1: Flammable gas.

Section 15. Regulatory Information

Reporting in this section is based on ingredients disclosed in Section 2
US Regulations
Federal Clean air act (CAA) 112 accidental release prevention: Butane
Clean air act (CAA) 112 regulated flammable substances: Propane, Isobutane, Butane
CERCLA: Hazardous substances.: Propane, Isobutane
State New Jersey: Propane, Isobutane, Butane
Massachusetts spill list: Propane, Isobutane, Butane
Massachusetts RTK: Propane, Isobutane, Butane
Pennsylvania RTK: Propane, Isobutane, Butane

This product is not subject to the reporting requirements under California's Proposition 65.
Registered Product Not applicable.
Information
Canadian Regulations
WHMIS Classification CLASS A: Compressed gas.

Continued on Next Page
Page: 3/4

GLADE ODOR COUNTERACTANT

Material Safety Data Sheet

WHMIS Icon

Registered Product Not applicable.
Information
Chemical Inventory Status

All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control
Act (TSCA) Chemical Substance Inventory.

Section 16. Other Information
Other Special
Considerations
Version

Not available.
1

Notice to Reader
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied,
as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to
evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws
and regulations.

Material Safety Data Sheet
Section 1. Product and Company Identification
Product Name

Product Description
Manufacturer

LYSOL® BRAND II DISINFECTANT
SPRAY, ALL SCENTS (AEROSOL) CANADIAN

MSDS#

Validation Date
Antibacterial action. Kills viruses, bacteria, mold and mildew.
Eliminates odours.
Print Date
Reckitt Benckiser (Canada) Inc.
2 Wickman Road
Toronto, Ontario M8Z 5M5

Product Identifier

Reg. No. 25094, P.C.P. Act

Item Number

59631-50709-06

Not available.

2/28/2006
2/28/2006

In case of
Emergency:

Telephone: 800-888-0192

Transportation
Emergencies:

Chemtrec: 1-800-424-9300
(U.S. & Canada)
Outside the U.S & Canada
(North America), call:
703-527-3887

Formula Number

432-124A (359979) Original scent; 147-082 (356595) Country scentTM; 147-083 (356596) Mountain scent; 73-087
(356593) Fresh scent; 258-011 (356597) Linen®; 192-031 (364000) Soft Powder®; 550-095 (367851) Spring
WaterfallTM.

UPC Number

59631-33072, 59631-50706 (Original/Parfum Originale); 59631-34082, 59631-50709 (Country/Parfum Campagnard); 59631-50615 (Mountain Air/Parfum de Montagne); 59631-32102 (Fresh/Parfum
de Fraîcheur); 59631-26710, -34052 & -50710 (Linen/Linge); 59631-75571 (Spring Waterfall/Chute D'Eau Printainière) & 59631-75393 (364000) Soft Powder/Parfum Tendre de Poudre.

Section 2. Composition and Information on Ingredients
Name

CAS #

1) ETHANOL

64-17-5

79

124-38-9

4.0

2) CARBON DIOXIDE

% by Weight

Exposure Limits : TLV/PEL
TWA: 1880 (mg/m3) from ACGIH (TLV)
TWA: 1000 (ppm) from ACGIH (TLV)
TWA: 1900 (mg/m3) from OSHA (PEL)
TWA: 1000 (ppm) from OSHA (PEL)
TWA: 9000 (mg/m3) from ACGIH (TLV)
TWA: 5000 (ppm) from ACGIH (TLV)
TWA: 9000 STEL: 54 (mg/m3) from OSHA (PEL)
TWA: 5000 (ppm) from OSHA (PEL)

Section 3. Hazards Identification
Emergency Overview

DANGER: Extremely Flammable. Container may explode if heated. Keep away from heat, sparks and open
flame. Exposure to temperatures above 55º C (130º F) may cause bursting. Causes eye irritation. Do not
spray in eyes, on skin or on clothing. KEEP OUT OF REACH OF CHILDREN.

Section 4. First Aid Measures
Eye Contact

In case of eye contact, hold eyes open and IMMEDIATELY rinse eyes thoroughly with plenty of water.
Remove any contact lenses and continue rinsing for at least 15 minutes. If irritation persists, consult a
physician.

Skin Contact

In keeping with good hygienic practices, wash exposed areas thoroughly with soap and water.

Inhalation

None required under recommended use conditions. Remove to fresh air.

Ingestion

Call a physician or poison control center immediately. Contains denatured ethanol; ingestion may result in
ethanol poisoning. NEVER give an unconscious person anything to ingest.

Continued on Next Page

LYSOL® BRAND II DISINFECTANT SPRAY,
ALL SCENTS (AEROSOL) - CANADIAN

Page Number: 2

Section 5. Fire and Explosion Data
Flammability

Extremely flammable. See Section 14 for any Shipping Classifications.

Flash Point

Not applicable. Aerosol flame extension greater than 18 inches or 45 cm.

Explosive Limits in Air

LOWER: 3.3% UPPER: 19%

Products of Combustion

Carbon monoxide, carbon dioxide and other unknown organic compounds.

Fire and Explosion Hazards

Contents under pressure. Do not use in presence of open flame or sparks. Do not puncture or incinerate
container or store at temperatures over 50°C. Container may explode if heated.

Fire Fighting Media
and Instructions

Use DRY chemicals, CO2, water spray or foam. Use extinguishing media suitable for surrounding
materials.

Special Fire Fighting
Instructions

Product contents under pressure. Cool containers with water spray. Wear full protective equipment:
eye/face (shield), body (full bunker gear), respiratory (SCBA). Provide shielding for venting, rupturing or
bursting containers. Move containers away from fire, if possible and safe to do so.

Section 6. Accidental Release Measures
Accidental Spill

Small spills: Eliminate all sources of ignition. Absorb with an inert material and place in appropriate waste
disposal container.
Large spills: Eliminate all sources of ignition and ventilate the area with equipment rated for use in
flammable environments. Collect liquid and store in metal containers for later disposal according to local,
provincial or federal regulations.

Section 7. Handling and Storage
Handling and Storage

DANGER: Extremely flammable. Container may explode if heated. Contents under pressure. Do not use
in presence of open flame or sparks. Do not puncture or incinerate container or store at temperatures over
50°C. Causes eye irritation. Do not spray in eyes, on skin or on clothing. Avoid contact with eyes or food.
KEEP OUT REACH OF CHILDREN.
It is an offence under the PEST CONTROL PRODUCTS ACT to use a control product under unsafe
conditions.

Section 8. Exposure Controls/Personal Protection
Ventilation Requirements

None required. General ventilation should be sufficient to control airborne levels.

Eye Protection

Avoid contact with eyes. Emergency responders should wear full eye and face protection.

Skin Protection

May cause mild skin irritation after prolonged or repeated use. Emergency responders should wear
impermeable gloves.

Respiratory Protection

None required under normal use conditions. Emergency responders should wear suitable respiratory
protection where long term exposure to vapors from large areas of spilled liquid is possible such as a major
spill, a fire or a clean-up operation.

Other Protection

None required under normal use conditions.

Work/Hygienic Practices

Washing with soap and water after use is recommended as good hygienic practice to prevent possible skin
irritation and / or eye irritation from the residue that may be left on the hands.

Continued on Next Page

Page Number: 3

LYSOL® BRAND II DISINFECTANT SPRAY,
ALL SCENTS (AEROSOL) - CANADIAN
Section 9. Physical and Chemical Properties
Description

Aerosol spray.

Odor

Various scents.

pH

10 [Basic.]

Color

Clear (Spray mist).

Boiling/Condensation Point

Not available.

Specific Gravity

0.835 @ 25°C

Vapor Pressure

95-105 psig.

Vapor Density

The highest known value is 1.6 (Air = 1) (ETHANOL).

Viscosity

Not available.

Solubility

Complete.

Physical Chemical Comments Not available.

Section 10. Stability and Reactivity Data
Chemical Stability

The product is stable.

Conditions of Instability

Danger: Extremely flammable. Container may explode if heated. Contents under pressure. Do not use in
presence of open flame or sparks. Do not puncture or incinerate container or store at temperatures over
50°C.

Incompatibility with Various
Substances

Do not use on polished wood furniture, rayon fabrics or acrylic plastics. Avoid contact with food.

Hazardous Decomposition
Products

Toxic sulfur oxides can be released if heated to decomposition temperature.

Hazardous Polymerization

Will not occur.

Section 11. Toxicological Information

Exposure effects
Eye Contact

Avoid contact with eyes. Causes eye irritation.

Skin Contact

None expected under recommended use conditions. Prolonged or repeated skin contact may result in slight
to moderate skin irritation.

Inhalation

None expected.

Ingestion

Contains denatured alcohol; ingestion may result in ethanol poisoning.

Carcinogenicity

Not listed as carcinogenic by OSHA, NTP or IARC.

Section 12. Ecological Information
Ecotoxicity

Not available.

Continued on Next Page

Page Number: 4

LYSOL® BRAND II DISINFECTANT SPRAY,
ALL SCENTS (AEROSOL) - CANADIAN
Section 13. Disposal Considerations
Waste Disposal

This container may be recycled in communities where aerosol can recycling is available. Before offering for
recycling, empty the can by using product according to the label (DO NOT PUNCTURE OR INCINERATE).
If recycling is not available, contact your municipality or provincial Ministry of Environment for disposal
information.

Section 14. Transport Information
DOT Classification

ORM-D

Proper Shipping Name

Consumer Commodity

DOT Identification Number

Not applicable.

Packing Group

Not applicable

Maritime Transportation

Not applicable.

Hazardous Substances
Reportable Quantity

Not applicable.

Special Provisions for
Transport

Not applicable.

TDG Classification

Consumer Commodity - Transborder Consignment.

ADR Classification

Not applicable.

IMDG Classification

Aerosols, Class 2.1, UN1950 - Limited Quantity.

IATA Classification

Consumer Commoditity, 9 ID8000

Section 15. Regulatory Information
Federal and State
Regulations

SARA Title III, Section 313 Toxic Chemical Notification & Release Reporting:
None

California Proposition 65: This product contains the following ingredients which require a warning under the Safe
Drinking Water & Toxic Enforcement Act:
None

Other Classifications

WHMIS (Canada)

CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F).

Section 16. Other Information

HMIS (U.S.A.)

Health Hazard
Fire Hazard
Reactivity
Personal Protection

1
3
0
B

Continued on Next Page

1
Health

1

0

Reactivity
Specific hazard

NFPA Aerosol Level
Validated by Product Safety on 2/28/2006.

Fire Hazard

National Fire Protection
Association (U.S.A.)

Printed 2/28/2006.

1, per NFPA 30B

LYSOL® BRAND II DISINFECTANT SPRAY,
ALL SCENTS (AEROSOL) - CANADIAN

Page Number: 5

Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee
that these are the only hazards that exist.

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name:
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

FORMULA 494725
ZENABRITE LEMON
ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Isoparaffinic HC Solvent
Butane
Propane
Poly (dimethylsiloxane)

CAS No.:
64742-48-9
106-97-8
74-98-6
63148-62-9

TLV:
Not Established
800ppm
2500ppm
Not Established

______________________________________________________________________________

SECTION 3
Boiling Point:
Solubility in Water:
Vapor Density(Air=1):

PHYSICAL DATA
<0 to 3720 F
Nil
Heavier than air

Specific Gravity(H2O=1):
Evaporation Rate:
pH:

0.89 + 0.05
Slower than Ether
NA

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flash Point(Propellant):
Flammable Limits(Propellant):
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

Non-Flammable
7OF
LEL:
1.3
UEL: 9.8
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5
Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.

First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________

SECTION 9

SPILL OR LEAK PROCEDURE

Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None

__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
494725

MATERIAL SAFETY DATA SHEET
81410
02 00
===========================================================================
Section 1 −− PRODUCT AND COMPANY IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT NUMBER
HMIS CODES
Health
2
81410
Flammability
2
Reactivity
0
PRODUCT NAME
DURA SEAL* DURA FINISH* Liquid Floor Wax, Neutral
MANUFACTURER’S NAME
EMERGENCY TELEPHONE NO.
MINWAX Company
(216) 566−2917
10 Mountainview Road
Upper Saddle River, NJ 07458
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
31−MAR−07
(800) 364−1359
===========================================================================
Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
51
64742−88−7 Mineral Spirits
ACGIH TLV
100 ppm
2 mm
OSHA PEL
100 ppm
3
64741−65−7 Mineral Spirits (Odorless)
ACGIH TLV
100 ppm
1 mm
OSHA PEL
100 ppm
===========================================================================
Section 3 −− HAZARDS IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.

Continued on page 2

81410
page 2
===========================================================================
Section 4 −− FIRST AID MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
EYES:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re−use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 −− FIRE FIGHTING MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
FLASH POINT
LEL
UEL
103 F PMCC
1.0
7.0
FLAMMABILITY CLASSIFICATION
Combustible, Flash above 99 and below 200 F
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Alcohol Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers may explode (due to the build−up of pressure) when
exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self−contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build−up and possible autoignition or explosion when exposed to
extreme heat.
===========================================================================
Section 6 −− ACCIDENTAL RELEASE MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
===========================================================================
Section 7 −− HANDLING AND STORAGE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STORAGE CATEGORY
DOL Storage Class II

Continued on page 3

81410
page 3
===========================================================================
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Contents are COMBUSTIBLE. Keep away from heat and open flame.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Keep container closed when not in use. Transfer only to approved
containers with complete and appropriate labeling. Do not take internally.
Keep out of the reach of children.
To minimize the possibility of spontaneous combustion: control the
accumulation of overspray; soak wiping rags and waste immediately after use
in a water−filled, closed metal container; air dry filters outside, far
from any combustible material and separated by bricks or other
non−combustible spacers; dispose of all contaminated materials and waste
properly. Consult OSHA 29 CFR 1910.107(b)(5) and NFPA 33, Chapter 8 (8−9)
for the proper procedures.
===========================================================================
Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
Removal of old paint by sanding, scraping or other means may generate
dust or fumes that contain lead. Exposure to lead dust or fumes may cause
brain damage or other adverse health effects, especially in children or
pregnant women. Controlling exposure to lead or other hazardous substances
requires the use of proper protective equipment, such as a properly fitted
respirator (NIOSH approved) and proper containment and cleanup. For more
information, call the National Lead Information Center at 1−800−424−LEAD
(in US) or contact your local health authority.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
Wear gloves which are recommended by glove supplier for protection
against materials in Section 2.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.

Continued on page 4

81410
page 4
===========================================================================
Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT WEIGHT
7.28 lb/gal
872 g/l
SPECIFIC GRAVITY
0.88
BOILING POINT
212 − 412 F
100 − 211 C
MELTING POINT
Not Available
VOLATILE VOLUME
78 %
EVAPORATION RATE
Slower than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
7.2
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical − As Packaged)
4.73 lb/gal
566 g/l
Less Water and Federally Exempt Solvents
3.90 lb/gal
468 g/l
Emitted VOC
===========================================================================
Section 10 −− STABILITY AND REACTIVITY
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STABILITY −− Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
===========================================================================
Section 11 −− TOXICOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver and urinary systems.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
TOXICOLOGY DATA
CAS No.
Ingredient Name
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
64742−88−7
Mineral Spirits
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
64741−65−7
Mineral Spirits (Odorless)
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
===========================================================================
Section 12 −− ECOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ECOTOXICOLOGICAL INFORMATION
No data available.

Continued on page 5

81410
page 5
===========================================================================
Section 13 −− DISPOSAL CONSIDERATIONS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Incinerate in approved facility. Do not incinerate closed container.
Dispose of in accordance with Federal, State/Provincial, and Local
regulations regarding pollution.
===========================================================================
Section 14 −− TRANSPORT INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
US Ground (DOT)
May be Classed as a Combustible Liquid for U.S. Ground.
UN1263, PAINT, 3, PG III, (ERG#128)
Bulk Containers may be Shipped as:
UN1263, PAINT, COMBUSTIBLE LIQUID, PG III, (ERG#128)
Canada (TDG)
May be Classed as a Combustible Liquid for Canadian Ground.
UN1263, PAINT, CLASS 3, PG III, (ERG#128)
IMO
UN1263, PAINT, CLASS 3, PG III, (39 C c.c.), EmS F−E, S−E
===========================================================================
Section 15 −− REGULATORY INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
No ingredients in this product are subject to SARA 313 (40 CFR 372.65C)
Supplier Notification.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
===========================================================================
Section 16 −− OTHER INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

Material Safety Data Sheet

U. S. Department of Labor

May be used to comply with OSHA's
Hazard Communication Standard
29 CFR 1910.1200. Standard must be
consulted for specific requirements.

Occupational Safety and Health Administration
(Non-Mandatory Form)
Form Approved

IDENTITY (As Used on Label and List)

NOTE: Blank spaces are not permitted. If any item is not applicable, or
no information is available, the space must be marked to indicate that.

Bab-O Powdered Cleanser

OMB No. 1218-0072

SECTION I
Manufacturer's Name

Emergency Telephone Number

Fitzpatrick Bros., Inc.

(262) 947-3500 X 617

Address (Number, Street, City, State and ZIP Code)

Telephone Number for Information

(262) 947-3500 X 617
Date Prepared

625 North Sacramento Boulevard

07/25/2005
Signature of Preparer (optional)

Chicago, Illinois 60612

SECTION II - Hazardous Ingredients/Identity Information
Hazardous Components (Specify Chemical Identity: Common Name[s]) OSHA PEL

THIS PRODUCT CONTAINS:

ACGIH TLV

Other Limits Recommended

% (optional)

Calcium Carbonate (CAS# 1317-65-3)
Sodium Carbonate (CAS# 497-19-8)
Sodium Dodecylbenzene Sulfonate (CAS# 25155-30-0

These basic materials have been identified as eye, skin, mucous membrane irritants.

SECTION III - Physical/Chemical Characteristics
Boiling Point

Specific Gravity (H2O = 1)

N/A

N/A

Vapor Pressure (mm Hg.)

Melting Point

N/A

N/A

Vapor Density (AIR = 1)

Evaporation Rate (Butyl Acetate = 1)

N/A

N/A

Solubility in Water

Partially soluble in water
Appearance and Odor

White powder, no odor

SECTION IV - Fire and Explosion Hazard Data
Flash Point (Method Used)

Flammable Limits

N/A

N/A

Extinguishing Media

Not a fire or explosive hazard
Special Fire Fighting Procedures

None
Unusual Fire and Explosion Hazards

None
(Reproduce locally)

Page 1

LEL

UEL

N/A

N/A

SECTION V - Reactivity Data
Stability

Unstable

Stable

Conditions to Avoid

X

Do not mix with ammonia or other household chemicals

Incompatability (Materials to Avoid)

Hazardous Decomposition or Byproducts

Hazardous
Polymerization

May Occur

Will Not Occur

Conditions to Avoid

X

SECTION VI - Health Hazard Data
Routes of Entry:

Inhalation?

Skin?

Yes

Ingestion?

No

No

Health Hazards (Acute and Chronic)

This material is identified as an irritant to eyes and the respiratory tract.
Scouring powder is not irritating to the skin and is harmful if swallowed.

Carcinogenicity:

NTP?

IARC Monographs?

OSHA Regulated?

Non-carcinogen
Signs and Symptoms of Exposure

Eye and mucous membrane irritation
Medical Conditions Generally Aggravated by Exposure

Avoid contact with eyes. Avoid breathing dust.
Emergency and First Aid Procedures

In case of contact with eyes, wash with plenty of water for at least 15 minutes.
Get medical attention if excessive inhalation occurs. Remove victim to fresh air.

SECTION VII - Precautions for Safe Handling and Use
Steps to be Taken in Case Material is Released or Spilled

Normal clean-up procedures
Waste Disposal Method

Conform to state, federal and local regulations

Precautions to be Taken in Handling and Storing

Store in cool, dry, ventilated area
Other Precautions

SECTION VIII - Control Measures
Respiratory Protection (Specify Type)

If dusty, wear mask
Ventilation

Local Exhaust

Special

Natural
Mechanical (General)

Other

Protective Gloves

Eye Protection

If needed

Wear goggles, if needed

Other Protective Clothing or Equipment

Optional
Work/Hygienic Practices

Page 2

Material Safety Data Sheet

PROFESSIONAL VANISH MILDEW STAIN CLEANER
Fire Hazard

National Fire
Protection
Association (NFPA)

Health

1

2 0

Health

Hazardous Material
Information System
(HMIS)

Reactivity

Fire Hazard
Reactivity

2
1
0

Specific Hazard
Emergency Straw color. Liquid. See Section 9.
Overview
WARNING: CAUSES EYE IRRITATION. May be mildly
irritating to skin.

Protective
Clothing

Section 1. Chemical Product and Company Identification
Product Name

PROFESSIONAL VANISH MILDEW STAIN CLEANER Code

90156

Product Use

Industrial/Institutional: Washroom care.

PMS#

433230

MSDS#

126095001

Validation Date

6/26/2003

Print Date
Supersedes

6/26/2003
No Previous Validation

In Case of
Emergency

(800) 851-7145

U.S. Headquarters
Drackett Professional
A Division of
S.C. Johnson Commercial Markets, Inc.
8310 16th Street
Sturtevant, Wisconsin 53177-0902
Phone: (888) 352-2249

Section 2. Composition and Information on Ingredients
Ingredients

CAS #

% by Weight

Sodium Hydroxide

1310-73-2

1-5

Sodium Hypochlorite
Tert-butyl Alcohol

7681-52-9
75-65-0

1-5
1-5

Water

7732-18-5

60-100

Exposure Limits
OSHA (United States).
CEIL: 2 mg/m3
ACGIH (United States).
STEL: 2 mg/m3
Not available.
OSHA (United States).
TWA: 300 mg/m3
ACGIH (United States).
TWA: 303 mg/m3
Not available.

LC50/LD50
Not available.

Not available.
ORAL (LD50): Acute: 3500
mg/kg [Rat].

Not available.

Section 3. Hazards Identification
Inhalation. Skin contact. Eye contact.

Routes of Entry
Potential Acute Health Effects

Eyes May be moderately irritating to eyes.
Skin May be mildly irritating to skin.
Inhalation May be irritating to nose, throat, and respiratory tract.
Ingestion May cause abdominal discomfort, nausea, vomiting and diarrhea.
Medical Conditions
Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, emphysema, etc., may
Aggravated by Overexposure: be more susceptible to irritating effects.
See Toxicological Information (section 11)

Continued on Next Page
Page: 1/4

PROFESSIONAL VANISH MILDEW STAIN CLEANER

Material Safety Data Sheet

Section 4. First Aid Measures
Eye Contact

Flush immediately with plenty of water. If irritation persists, get medical attention.

Skin Contact

Flush immediately with plenty of water. Get medical attention if irritation occurs.

Inhalation

If breathing is difficult: Remove to fresh air. Get medical attention immediately.

Ingestion

Immediately drink plenty of water. If discomfort persists, get medical attention.

Section 5. Fire Fighting Measures
Flammability of the Product None known.
CLOSED CUP: >103°C (217.4°F).
Flash Points
None known.

Products of Combustion

Fire Fighting Media
Extinguish with water spray or carbon dioxide, dry chemical powder or appropriate foam. Normal fire
and Instructions
fighting procedure may be used.
Special Remarks on Fire and None known.
Explosion Hazards

Section 6. Accidental Release Measures
Personal Precautions

Put on appropriate personal protective equipment (see Section 8).

Environmental Precautions
and Clean-up Methods

In the event of major spillage: Use appropriate containment to avoid environmental contamination. Sweep
or scrape up material. Place in suitable clean, dry containers for disposal by approved methods. Use a
water rinse for final clean-up.

Section 7. Handling and Storage
Handling

Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. FOR COMMERCIAL AND
INDUSTRIAL USE ONLY.

Storage

Store in a dry, cool and well-ventilated area. Protect from freezing. KEEP OUT OF REACH OF
CHILDREN.

Section 8. Exposure Controls/Personal Protection
Engineering Controls

Good general ventilation should be sufficient to control airborne levels. Respiratory protection is not
required if good ventilation is maintained.

Personal Protection
Eyes Safety glasses recommended.
Hands For prolonged or repeated contact with skin: Rubber gloves.
Respiratory No special requirements under normal use conditions.
Feet No special requirements under normal use conditions.
Body No special protective clothing is required.

Section 9. Physical and Chemical Properties
Physical State and
Appearance
Odor

Liquid.

Color

Straw color.

pH

12.8 [Basic.]

Specific Gravity

1

Evaporation Rate

<1

Solubility in water

Complete.

Bleach.

Continued on Next Page
Page: 2/4

PROFESSIONAL VANISH MILDEW STAIN CLEANER

Material Safety Data Sheet

Section 10. Stability and Reactivity
Stability and Reactivity

The product is stable.

Conditions of Instability

None known.

Incompatibility with Various Avoid mixing with: acids , Ammonia. Do not mix with any other chemicals or products unless specified by
Substances
label.
Hazardous Decomposition
Products

When exposed to fire: Produces normal products of combustion.

Hazardous Polymerization

Will not occur.

Section 11. Toxicological Information
ORAL (LD50) Estimated to be greater than 5000 mg/kg (rat).
DERMAL (LD50) Between 2000 - 20000 mg/kg (rat).

Acute toxicity

Effects of Chronic Exposure None known.
Not available.

Other Toxic Effects

Section 12. Ecological Information
Not available.

Section 13. Disposal Considerations
No special precautions. Dispose of according to all federal, state and local regulations.

Waste Information

Section 14. Transport Information
DOT Classification
Please refer to the Bill of Lading/receiving documents for up to date shipping information.

DOT Proper
Shipping Name
TDG Classification

Please refer to the Bill of Lading/receiving documents for up to date shipping information.

TDG Proper
Shipping Name

Section 15. Regulatory Information

Reporting in this section is based on ingredients disclosed in Section 2
US Regulations
Federal SARA 313 toxic chemical notification and release reporting: Tert-butyl Alcohol
Clean Water Act (CWA) 311: Sodium hydroxide, Sodium Hypochlorite
CERCLA: Hazardous substances.: Sodium hydroxide, Sodium Hypochlorite, Tert-butyl Alcohol
State New Jersey spill list: Sodium hydroxide, Sodium Hypochlorite, Tert-butyl Alcohol
New Jersey: Sodium hydroxide, Sodium Hypochlorite, Tert-butyl Alcohol
Massachusetts spill list: Sodium hydroxide, Sodium Hypochlorite, Tert-butyl Alcohol
Massachusetts RTK: Sodium hydroxide, Sodium Hypochlorite, Tert-butyl Alcohol
Pennsylvania RTK: Sodium hydroxide, Sodium Hypochlorite, Tert-butyl Alcohol
This product is not subject to the reporting requirements under California's Proposition 65.

Registered Product Not applicable.
Information
Canadian Regulations
WHMIS Classification Not applicable.
WHMIS Icon
Registered Product Not applicable.
Information
Chemical Inventory Status

All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control
Act (TSCA) Chemical Substance Inventory

Continued on Next Page
Page: 3/4

PROFESSIONAL VANISH MILDEW STAIN CLEANER

Material Safety Data Sheet

Section 16. Other Information
Other Special
Considerations
Version

Not available.
1.01

Notice to Reader
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied,
as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to
evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws
and regulations.

FICHE DE DONNÉES DE SÉCURITÉ

CARPET SCIENCE Détachant
HMIS
Santé
Risque d'incendie
Réactivité

NFPA
1
1
0

1
1
0

Protection individuelle

None / Aucune / Ninguno

None / Aucune / Ninguno

Numéro de révision: 1

Date de révision: 2007-06-08

1. IDENTIFICATION DE LA SUBSTANCE/PREPARATION ET DE LA SOCIETE/ENTREPRISE
Nom du produit:

CARPET SCIENCE Détachant

MSDS #:
Code du produit:
Utilisation recommandée:

126097001
94350
Industriel/Institutionnel. Soins des Moquettes .

Producteur, importateur, fournisseur:
US Headquarters
JohnsonDiversey, Inc.
8310 16th St.
Sturtevant, Wisconsin 53177-0902
Phone: 1-888-352-2249
MSDS Internet Address:
www.johnsondiversey.com
Téléphone en cas d'urgence:

Canadian Headquarters
JohnsonDiversey - Canada, Inc.
2401 Bristol Circle
Oakville, Ontario L6H 6P1
Phone: 1-800-668-3131

1-800-851-7145 (Prosar); 1-651-917-6133 (Int'l Prosar); 01-800-710-3400 (México)

2. IDENTIFICATION DES DANGERS
Aperçu des premiers secours
ATTENTION. PEUT IRRITER MODÉRÉMENT LES YEUX. PEUT IRRITER MODÉRÉMENT LA PEAU . LIQUIDE ET VAPEUR COMBUSTIBLES.
Principales voies entree:
Contact avec les yeux:
Contact avec la peau:
Inhalation:
Ingestion:

Contact avec les yeux. Contact avec la peau. Inhalation.
Peut irriter modérément les yeux.
Peut irriter modérément la peau.
Aucun à notre connaissance.
Aucun à notre connaissance.

3. COMPOSITION/INFORMATION SUR LES COMPOSANTS
Composants Dangereux
Composant(s)
Alcool isopropylique

CAS #
67-63-0

% en poids
1 - 5%

DL50 Orale
=4396 mg/kg

DL50 Cutanée
=12800 mg/kg

CL50 Inhalatoire
=72.6 mg/L (4 h)

4. PREMIERS SOINS
Contact avec les yeux:
Contact avec la peau:
Inhalation:
Ingestion:
Conditions médicales aggravées:

Rincer immédiatement à grande eau . Si une irritation apparaît, consulter un médecin.
Rincer immédiatement à grande eau . Si une irritation apparaît, consulter un médecin..
Les premiers secours ne sont pas nécessaires.
Les premiers secours ne sont pas nécessaires.
Aucun à notre connaissance.

5. MESURES DE LUTTE CONTRE L'INCENDIE
Moyen d'extinction approprié:
Dangers spécifiques:
Risques Inhabituels
Méthodes particulières d'intervention:

Poudre, eau pulvérisée, mousse, dioxide de carbone.
Alors que ce produit possede un point d'eclair inferieur a 200 Deg. F, il constitue une solution aqueuse a
base d'alcool qui ne soutient pas la combustion .
Aucun à notre connaissance
Aucune méthodes spéciale n'est requise .

Equipements spéciaux pour la protection des intervenants: Comme pour tout incendie, porter un respirateur à air comprimé, MSHA/NIOSH
(approuvé ou équivalent), ainsi qu'une combinaison complète de protection
Moyen d'extinction à ne pas utiliser pour des raisons de sécurité: Pas d'information disponible

6. MESURES A PRENDRE EN CAS DE DÉVERSEMENT ACCIDENTEL
Précautions individuelles:

CARPET SCIENCE Détachant

Revêtir un équipement de protection individuelle approprié (voir Section 8).

1 of 3

6. MESURES A PRENDRE EN CAS DE DÉVERSEMENT ACCIDENTEL
Méthodes de nettoyage:

Utiliser un récipient approprié pour éviter toute contamination du milieu ambiant. Absorber l'écoulement
avec un matériau inerte (p.e.sable sec ou terre), puis mettre dans un conteneur pour déchets chimiques.

7. MANIPULATION ET STOCKAGE
Manipulation:
Éviter le contact avec la peau et les yeux. LIQUIDE ET VAPEUR COMBUSTIBLES . Tenir à l'abri des flammes nues, des surfaces chaudes et des
sources d'inflammation. Utiliser seulement dans des zones bien ventilées. POUR UTILISATOIN COMMERCIALE ET INDUSTRIELLE SEULEMENT
Stockage:
Protéger du gel . Conserver hermétiquement fermé dans un endroit sec, frais et bien ventilé. GARDER HORS DE LA PORTÉE DES ENFANTS.

8. MESURES DE CONTRÔLE DE L'EXPOSITION/PROTECTION INDIVIDUELLE
Mesures d'ordre technique:
Aucune ventilation particulière requise. Ventilation adéquate du local.
Protection individuelle
Protection des yeux:
Protection des mains:
Protection de la peau et du corps:
Protection respiratoire:
Mesures d'hygiène:
Composant(s)
Alcool isopropylique

Aucune condition particulière dans les conditions normales d'utilisation.
Aucune condition particulière dans les conditions normales d'utilisation
Aucune condition particulière dans les conditions normales d'utilisation.
Aucune condition particulière dans les conditions normales d'utilisation .
A manipuler conformément aux normes d'hygiène industrielle et aux consignes de sécurité.
CAS #
67-63-0

ACGIH
400 ppm (STEL)
200 ppm (TWA)

OSHA
980 mg/m3 (TWA)
400 ppm (TWA)

Mexico
500 ppm (STEL)
1225 mg/m3 (STEL)
400 ppm (TWA)
980 mg/m3 (TWA)

9. PROPRIETES PHYSIQUES ET CHIMIQUES
État de la matière:
pH:
Aspect:
Couleur:
Odeur:
Densité:
Densité:
Teneur (%) en COV
(composés
organiques volatils):
Point d'éclair:
Solubilité:
Viscosité:

liquide
7.5
liquide
opaque blanc cassé
fruité
1
8.35 lbs/gal
2.75% *

Masse volumique apparente:
pH de la solution diluée
Densité gazeuse:
Vitesse d'évaporation
Point/intervalle d'ébullition:
Point/intervalle de fusion:
Température de décomposition:
Température d'auto-inflammation:

129°F 54°C
soluble
Pas d'information disponible

Coefficient de partage (n-octanol/eau): Pas d'information disponible
Solubilité dans d'autres solvants: Pas d'information disponible
phosphore élémental :
0 %P

Pas d'information disponible
Pas d'information disponible.
Pas d'information disponible
Pas d'information disponible
212°F 100°C
30.2 °F-1 °C
indéterminé
Pas d'information disponible

* - Titre 17, Code des règlements de la Californie, division 3, chapitre 1, sous-chapitre 8.5, article 2, Produits de consommation, sections 94508

10. STABILITÉ ET RÉACTIVITÉ
Stabilité:
polymérisation:
Produits de décomposition dangereux:
Conditions à éviter:

Le produit est stable.
Une polymérisation dangereuse ne se produit pas..
Aucun raisonnablement prévisible.
Ne pas congeler.

11. INFORMATIONS TOXICOLOGIQUES
Toxicité aiguë
Information sur les composants:

Oral(e) Estimée à un niveau supérieur à 5000 mg/kg; Cutanée Toxicité orale exprimée en DL50 > 2000
mg/kg
Voir la Section 3

Toxicité chronique:

Aucun à notre connaissance

Effets spécifiques
effets cancérogènes:
effets mutagènes:
Toxicité pour la reproduction:
Effets sur l'organe-cible:

Aucun à notre connaissance
Aucun à notre connaissance
Aucun à notre connaissance
Aucun à notre connaissance

CARPET SCIENCE Détachant

2 of 3

11. INFORMATIONS TOXICOLOGIQUES
Composants Dangereux

12. INFORMATIONS ÉCOLOGIQUES
Information environnementales

donnée non disponible

13. CONSIDERATIONS RELATIVES À L'ÉLIMINATION
Déchets des résidus / produits non utilisés:
Le produit non dilué est réglementée par les lois concernant l'environnement et le transport en tant que déchet allumable . Éliminer selon les dispositions
prévues par les différentes réglementations fédérales, provinciales, locales ou d'État .

14. INFORMATIONS RELATIVES AU TRANSPORT
DOT/TDG: S' il vous plait, consulter le document d'expédition pour les renseignements à jour sur le transport

15. INFORMATIONS RÉGLEMENTAIRES
Inventaires internationales
Tous les éléments de ce produit sont énumérés dans les inventaires suivants: États-Unis (TSCA), Canada (DSL/NDSL).
Réglementation des É.-U.
Proposition 65 de la Californie: Ils n'y a pas des ingrédients qui sont assujettis à la déclaration en suivant 'Proposition 65' de Californie
LOI DU DROIT DE SAVOIR DE L'ÉTAT
Composant(s)
Eau
Hexyloxyéthanol
Alcool isopropylique

CAS #
7732-18-5
112-25-4
67-63-0

CERCLA/ SARA
Composant(s)
Hexyloxyéthanol
Alcool isopropylique

CAS #
112-25-4
67-63-0

Composant(s)
Hexyloxyéthanol

MARTK:
X

% en poids
1 - 5%
1 - 5%

NJRTK:
X

CERCLA/SARA RQ (lbs)

CAA HAP
X

CAA ODS

PARTK:
X
X

RIRTK:
X

Section 302, TPQ kg)

Section 313
X
X

CWA Polluants en Priorité

Catégories de risque en vertu de la loi SARA, section 311/312
Immédiat
Différée
Feu:
X
Réactivité
Décompression soudaine
Canada
Catégories de risque du SIMDUT : B3

liquides combustibles.

Composant(s)
Alcool isopropylique

CAS #
67-63-0

NPRI
X

16. AUTRES INFORMATIONS
Cause de la révision:
Préparé par:
Conseils supplémentaires:

Sans objet
NAPRAC
aucune

Avis au lecteur: Ce document a etè prèparè de sources considèrèes techniquement sèrieuses. If ne constitue pas une garantie, ènoncèe ou tacite, de
l'exactitude des renseignements ci-incluses. Les conditions actuelles d'usage et de manutention sont hors du contrôle du vendeur. L'utilisateur doit
s'assurer qu'il posè'de toutes les donnèes en cours, en regard de son utilization particulière et qu'il respecte tous les règlements fèdèraux, des ètats,
provinciaux et municipaux.

CARPET SCIENCE Détachant

3 of 3

The Valspar Corporation
Material Safety Data Sheet
1. PRODUCT AND COMPANY IDENTIFICATION
Material Identification

Product ID:

011.0002400

Product Name:
Product Use:
Print date
Revision Date

GOOF OFF
Paint product.
31/Jan/2007
31/Aug/2005

Company Identification
The Valspar Corporation - Architectural Coatings Division
1191 Wheeling Road
Wheeling, IL 60090
Manufacturer's Phone:
1-847-520-8580
24-Hour Medical Emergency
Phone:

1-888-345-5732

2. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS
Common Name
CAS-No.
XYLENE
1330-20-7
ETHYLBENZENE
100-41-4
DIETHYLENE GLYCOL
MONOMETHYL ETHER
111-77-3
TOLUENE
108-88-3

Approx.
Chemical name
Weight %
75 - 80
Xylenes (o-, m-, p- isomers)
15 - 20

Ethyl benzene

1-5

Diethylene glycol monomethyl ether

1-5

Toluene

If this section is blank there are no hazardous components per OSHA guidelines.

3. HAZARDS IDENTIFICATION
Primary Routes of Exposure:
Inhalation
Ingestion
Skin absorption
Emergency Overview:
This section not in use.
This product contains ingredients that may contribute to the following potential acute health effects:
Inhalation Effects:
Harmful if inhaled. May affect the brain, nervous system, or respiratory system, causing dizziness, headache, nausea or
respiratory irritation.
Eye Contact:
Corneal Injury/eye damage.

Product ID: 011.0002400

Page 1 / 7

Skin Contact:
May cause moderate skin irritation.
Acute Ingestion:
None known
Other Effects:
May cause central nervous system depression. May cause liver damage. May cause kidney damage.
This product contains ingredients that may contribute to the following potential chronic health effects:
Notice: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain
and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful
or fatal. Possible birth defects hazard. Contains ingredients which may cause birth defects based on animal data. May
cause kidney damage. May cause liver damage.
See Section 11 for toxicological information about Mutagens, Teratogens and Carcinogens.
If this section is blank, no information is available.

4. FIRST AID MEASURES
Inhalation:
If affected by inhalation, move victim to fresh air. If symptoms persist, seek medical attention.
Eye Contact:
In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get
medical attention immediately after flushing.
Skin Contact:
In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. If irritation persists get
medical attention.
Ingestion:
If swallowed , do not induce vomiting. Give large quantities of water. If available, give several glasses of milk. Never give
anything by mouth to an unconscious person. Get medical attention immediately. If swallowed, get medical attention
immediately.
Medical conditions aggravated by exposure: Any respiratory or skin condition.

5. FIRE FIGHTING MEASURES
Flash point (Fahrenheit):
Lower explosive limit:
Upper explosive limit:
Autoignition temperature:
Sensitivity to impact:
Sensitivity to static discharge:
Hazardous combustion products:

80º F ( 27º C) TCC/PM
1%
7%
Not available. º F ( º C)
No.
Subject to static discharge hazards. Please see bonding and
grounding information in Section 7.
See Section 10.

Unusual fire and explosion hazards:
None known.
Extinguishing media:
Carbon dioxide, dry chemical, foam and/or water fog.
Fire fighting procedures:
Use water spray to cool nearby containers and structures exposed to fire.

Product ID: 011.0002400

Page 2 / 7

6. ACCIDENTAL RELEASE MEASURES
Action to be taken if material is released or spilled:
Ventilate area. Avoid breathing of vapors. Use self-containing breathing apparatus or airmask for large spills in a
confined area. Wipe, scrape or soak up in an inert material and put in a container for disposal. See section 5, "Unusual
Fire and Explosion Hazards", for proper container and storage procedures. Remove sources of ignition. Remove with
inert absorbent and non sparking tools. Avoid contact with eyes.

7. HANDLING AND STORAGE
Precautions to be taken in handling and storage:
Keep away from heat, sparks, and flames. Keep container closed when not in use. Do not store above 120 degrees F.
(49 degrees C). Based on flash point and vapor pressure, suitable storage should be provided in accordance with OSHA
regulation 1910.106, Ontario OH&S regulation 851 section 22. Empty containers may contain product residue, including
flammable or explosive vapors. Do not cut, puncture or weld on or near container. All label warnings must be observed
until the container has been commercially cleaned or reconditioned. If the product is used near or above the flashpoint,
an ignition hazard may be present. Activities, uses, or operations which liberate vapor (such as mixing or free fall of
liquids) may also present an ignition hazard. Please ensure containers and other interconnected equipment are properly
bonded and grounded at all times.

8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS
Personal Protective Equipment
Eye and face protection:
Avoid contact with eyes. Wear chemical goggles if there is the possibility of contact or splashing in the eye.
Skin protection:
Appropriate chemical resistant gloves should be worn.To prevent skin contact wear protective clothing covering all
exposed areas.
Respiratory protection:
If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator such as an air
purifying respirator with organic vapor cartridge and dust/mist filter. Consult the respirator manufacturer's literature to
ensure that the respirator will provide adequate protection. Read and follow all respirator manufacturer's instructions.
Ventilation
Required when spraying or applying in confined area. Ventilation equipment should be explosion proof. Eliminate
ignition sources.
Exposure Guidelines
OSHA Permissible Exposure Limits (PEL's)
Common Name
CAS-No.
XYLENE
1330-20-7
ETHYLBENZENE
100-41-4
TOLUENE
108-88-3

Approx.
TWA (final)
Weight %
75 - 80
435 mg/m³ 100 ppm
15 - 20

435 mg/m³ 100 ppm

1-5

200 ppm

Ceilings limits (final)

Skin designations

300 ppm

ACGIH Threshold Limit Value (TLV's)
Common Name
CAS-No.

Approx.
TWA
Weight %

STEL

Product ID: 011.0002400

Page 3 / 7

Ceiling limits

Skin designations

XYLENE
1330-20-7
ETHYLBENZENE
100-41-4
TOLUENE
108-88-3

75 - 80

100 ppm

150 ppm

15 - 20

100 ppm

125 ppm

1-5

50 ppm

Can be absorbed
through the skin.

If this section is blank, no information is available.

9. PHYSICAL PROPERTIES
Odor:
Physical State:
pH:
Vapor pressure:
Vapor density (air = 1.0):
Boiling point:
Solubility in water:
Coefficient of water/oil distribution:
Density (lbs per US gallon):
Specific Gravity
Evaporation rate (butyl acetate = 1.0):

Normal for this product type.
Liquid
Not determined.
28 mmHG @ 68º F ( 20º C)
4.1
230º F ( 110º C)
Insoluble.
Not determined.
7.29
.87
2

10. STABILITY AND REACTIVITY
Stability
Conditions to Avoid:
Incompatibility:
Hazardous Polymerization:
Hazardous Decomposition Products:

Stable
None known.
Strong oxidizers.
None anticipated.
Carbon monoxide and carbon dioxide.

Sensitivity to static discharge:

Subject to static discharge hazards. Please see bonding and
grounding information in Section 7.

11. TOXICOLOGICAL INFORMATION
Mutagens:
Common Name
CAS-No.
TOLUENE
108-88-3

Approx.
California Prop 65 - Developmental
Weight % Toxicity
1-5
Listed: January 1, 1991
Developmental toxin.

California Prop 65 - Reproductive
(Male)

Teratogens:
Carcinogens:
Contains ethylbenzene, which has been determined by NTP to be an animal carcinogen with no known relevance to
humans. IARC has classified ethylbenzene as possibly carcinogenic to humans (2b) on the basis of sufficient evidence of
carcinogenicity in laboratory animals but inadequate evidence of cancer in humans.
Common Name
CAS-No.
ETHYLBENZENE
100-41-4

Approx.
IARC Group 1 - Human
Weight % Evidence
15 - 20

Product ID: 011.0002400

Page 4 / 7

IARC Group 2A - Limited IARC Group 2B Human Data
Sufficient Animal Data
Monograph 77, 2000

Common Name
CAS-No.
ETHYLBENZENE
100-41-4

Approx.
NTP Known
Weight % Carcinogens
15 - 20

NTP Suspect
Carcinogens

NTP Evidence of
Carcinogenicity
male rat-clear evidence;
female rat-some
evidence; male micesome evidence; female
mice-some evidence

Common Name
CAS-No.
ETHYLBENZENE
100-41-4

Approx.
OSHA Select
Weight % Carcinogens
15 - 20

OSHA Possible Select
Carcinogens

ACGIH Carcinogens
Group A3 Confirmed
animal carcinogen with
unknown relevance to
humans.

If this section is blank, no information is available.

12. ECOLOGICAL DATA
Not available at this time.

13. DISPOSAL CONSIDERATIONS
Disposal should be made in accordance with federal, state and local regulations.

14. TRANSPORTATION INFORMATION
U.S. Department of Transportation
Proper Shipping Name:
PAINT RELATED MATERIAL
Hazard Class:
3
UN ID Number:
UN1263
Packing Group:
III
49 CFR Hazardous Material Regulations Parts 100-180
The supplier will apply the combustible liquid exception in 49 CFR 173.150(f), limited quantity or "does not sustain
combustion" exceptions and consumer commodity rules, when authorized. Please check 49 CFR Parts 100-180 to
determine if the use of these exceptions applies to your shipments when re-shipping our products.
International Air Transport Association:
Proper Shipping Name:
PAINT RELATED MATERIAL
Hazard Class:
3
UN ID Number:
UN1263
Packing Group:
III
International Maritime Organization:
Proper Shipping Name:
PAINT RELATED MATERIAL
Hazard Class:
3
Non-Bulk UN ID Number:
UN1263
Packing Group:
III

15. REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS:

Product ID: 011.0002400

Page 5 / 7

15. REGULATORY INFORMATION
Common Name
CAS-No.
XYLENE
1330-20-7

Approx.
SARA 302
Weight %
75 - 80

ETHYLBENZENE
100-41-4

15 - 20

DIETHYLENE GLYCOL
MONOMETHYL ETHER
111-77-3
TOLUENE
108-88-3

1-5

SARA 313

form R reporting required 100
for 1.0% de minimis
concentration
form R reporting required 1000
for 1.0% de minimis
concentration
YES

1-5

SARA 311/312 Hazard Class:
Acute:
Chronic:
Flammability:
Reactivity:
Sudden Pressure:

CERCLA RQ in lbs.

form R reporting required 1000
for 1.0% de minimis
concentration

Yes
Yes
Yes
No
No

U.S. STATE REGULATIONS:
Pennsylvania Right To Know:
ETHYLBENZENE
TOLUENE
DIETHYLENE GLYCOL MONOMETHYL ETHER
XYLENE

100-41-4
108-88-3
111-77-3
1330-20-7

California Proposition 65:
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
Rule 66 status of product

Photochemically reactive.

INTERNATIONAL REGULATIONS - Chemical Inventories
TSCA Inventory:

All components of this product are in compliance with U.S.
TSCA Chemical Substance Inventory Requirements.

Canada Domestic Substances List:

All components of this product are listed on the Domestic
Substances List.

16. OTHER INFORMATION
HMIS Codes
Health:
Flammability:
Reactivity:
PPE:

2
3
1
X - See Section 8 for Personal Protective Equipment (PPE).

Product ID: 011.0002400

Page 6 / 7

Abbreviations:
OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer, NIOSH National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH - American Conference
of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management District, TSCA - Toxic
Substances Control Act, IATA - International Air Transport Association, IMO - International Maritime Organization, DOT Department of Transportation, NA - Not applicable, NOT ESTAB - Not established, N.A.V. - Not available, RQ Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L - Grams per liter, MM - Millimeters,
MPPCF - Millions of particles per cubic foot, PPM - parts per million, PPT - parts per thousand, TCC/PM - Tag closed
cup / Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time Weighted Average, STEL - Short term
exposure limit, C - Celsius, F - Fahrenheit.
Disclaimer:
The data on this sheet represent typical values. Since application variables are a major factor in product performance, this
information should serve only as a general guide. Valspar assumes no obligation or liability for use of this information.
UNLESS VALSPAR AGREES OTHERWISE IN WRITING, VALSPAR MAKES NO WARRANTIES, EXPRESS OR
IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. VALSPAR WILL NOT BE
LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only remedy for any defect in this
product is the replacement of the defective product, or a refund of its purchase price, at our option. This MSDS contains
additional information required by the state of Pennsylvania.

Product ID: 011.0002400

Page 7 / 7

The Valspar Corporation
Material Safety Data Sheet
1. PRODUCT AND COMPANY IDENTIFICATION
Material Identification

Product ID:

011.0002417.004

Product Name:
Product Use:
Effective date:
Revision Date
UN ID Number:
WHMIS Classification:

CAN GOOF OFF 16 OZ 12P
Paint product.
12/Oct/2005
31/Aug/2005
UN1263
D2B Toxic Material D2A Very Toxic Material B2 Flammable Liquids

Company Identification
1191 Wheeling Road
Wheeling, IL 60090
Tech Info Phone:

847-520-8580

24-Hour Medical Emergency
Phone:

1-888-345-5732

2. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS
Common Name
CAS-No.
XYLENE
1330-20-7
ETHYLBENZENE
100-41-4
DIETHYLENE GLYCOL
MONOMETHYL ETHER
111-77-3
TOLUENE
108-88-3

Approx. Chemical Name
Weight %
75 - 80
Xylenes (o-, m-, pisomers)
15 - 20
Ethyl benzene

CAS Number

1-5

Diethylene glycol
monomethyl ether

111-77-3

1-5

Toluene

108-88-3

Trade Secret Number

1330-20-7
100-41-4

If this section is blank there are no hazardous components per OHSA guidelines.

3. HAZARDS IDENTIFICATION
Primary Routes of Exposure:
Inhalation
Ingestion
Skin absorption
Emergency Overview:
This section not in use.
This product contains ingredients that may contribute to the following potential acute health effects:
Inhalation Effects:
Harmful if inhaled. May affect the brain, nervous system, or respiratory system, causing dizziness, headache,
nausea or respiratory irritation.

Product ID: 011.0002417.004

Page 1 of 7

Eye Contact:
Corneal Injury/eye damage.
Skin Contact:
May cause moderate skin irritation.
Acute Ingestion:
None known
Other Effects:
May cause central nervous system depression. May cause liver damage. May cause kidney damage.
This product contains ingredients that may contribute to the following potential chronic health effects:
Notice: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain
and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be
harmful or fatal. Possible birth defects hazard. Contains ingredients which may cause birth defects based on animal
data. May cause kidney damage. May cause liver damage.
See Section 11 for toxicological information about Mutagens, Teratogens and Carcinogens.
If this section is blank, no information is available.

4. FIRST AID MEASURES
Inhalation:
If affected by inhalation, move victim to fresh air. If symptoms persist, seek medical attention.
Eye Contact:
In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get
medical attention immediately after flushing.
Skin Contact:
In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. If irritation persists get
medical attention.
Ingestion:
If swallowed , do not induce vomiting. Give large quantities of water. If available, give several glasses of milk. Never
give anything by mouth to an unconscious person. Get medical attention immediately. If swallowed, get medical
attention immediately.
Medical conditions aggravated by exposure: Any respiratory or skin condition.

5. FIRE FIGHTING MEASURES
Flash point (Fahrenheit):
Lower explosive limit:
Upper explosive limit:
Autoignition temperature:
Sensitivity to impact:
Sensitivity to static discharge:
Hazardous combustion products:

80º F ( 27º C) TCC/PM
1%
7%
Not available. º F ( º C)
No.
Subject to static discharge hazards. Please see bonding
and grounding information in Section 7.
See Section 10.

Unusual fire and explosion hazards:
None known.
Extinguishing media:
Carbon dioxide, dry chemical, foam and/or water fog.

Product ID: 011.0002417.004

Page 2 of 7

Fire fighting procedures:
Use water spray to cool nearby containers and structures exposed to fire.

6. ACCIDENTAL RELEASE MEASURES
Action to be taken if material is released or spilled:
Ventilate area. Avoid breathing of vapors. Use self-containing breathing apparatus or airmask for large spills in a
confined area. Wipe, scrape or soak up in an inert material and put in a container for disposal. See section 5,
"Unusual Fire and Explosion Hazards", for proper container and storage procedures. Remove sources of ignition.
Remove with inert absorbent and non sparking tools. Avoid contact with eyes.

7. HANDLING AND STORAGE
Precautions to be taken in handling and storage:
Keep away from heat, sparks, and flames. Keep container closed when not in use. Do not store above 120 degrees
F. (49 degrees C). Based on flash point and vapor pressure, suitable storage should be provided in accordance with
OSHA regulation 1910.106, Ontario OH&S regulation 851 section 22. Empty containers may contain product residue,
including flammable or explosive vapors. Do not cut, puncture or weld on or near container. All label warnings must
be observed until the container has been commercially cleaned or reconditioned. If the product is used near or above
the flashpoint, an ignition hazard may be present. Activities, uses, or operations which liberate vapor (such as mixing
or free fall of liquids) may also present an ignition hazard. Please ensure containers and other interconnected
equipment are properly bonded and grounded at all times.

8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS
Personal Protective Equipment
Eye and face protection:
Avoid contact with eyes. Wear chemical goggles if there is the possibility of contact or splashing in the eye.
Skin protection:
Appropriate chemical resistant gloves should be worn.To prevent skin contact wear protective clothing covering all
exposed areas.
Respiratory protection:
If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator such as an
air purifying respirator with organic vapor cartridge and dust/mist filter. Consult the respirator manufacturer's literature
to ensure that the respirator will provide adequate protection. Read and follow all respirator manufacturer's
instructions.
Ventilation
Required when spraying or applying in confined area. Ventilation equipment should be explosion proof. Eliminate
ignition sources.
Exposure Guidelines
OSHA Permissible Exposure Limits (PEL's)
Common Name
CAS-No.
XYLENE
1330-20-7
ETHYLBENZENE
100-41-4
TOLUENE
108-88-3

Approx. TWA (final)
Weight %
75 - 80
435 mg/m3 100 ppm
15 - 20

435 mg/m3 100 ppm

1-5

200 ppm

Ceilings limits (final)

300 ppm

ACGIH Threshold Limit Value (TLV's)

Product ID: 011.0002417.004

Page 3 of 7

Skin designations

Common Name
CAS-No.
XYLENE
1330-20-7
ETHYLBENZENE
100-41-4
TOLUENE
108-88-3

Approx. TWA
Weight %
75 - 80
100 ppm

STEL

15 - 20

100 ppm

125 ppm

1-5

50 ppm

Ceiling limits

Skin
designations

150 ppm

Can be absorbed
through the skin.

If this section is blank, no information is available.

9. PHYSICAL PROPERTIES
Odor:
Odor threshold:
Physical State:
pH:
Vapor pressure:
Vapor density (air = 1.0):
Boiling point:
Solubility in water:
Coefficient of water/oil distribution:
Density (lbs per US gallon):
Specific Gravity
Evaporation rate (butyl acetate = 1.0):

Normal for this product type.
Not available.
Liquid
Not determined.
28 mmHG @ 68º F ( Not Available. º C)
4.1
230º F ( 110º C)
Insoluble.
Not determined.
7.29
.87
2

10. STABILITY AND REACTIVITY
Stability
Conditions to Avoid:
Incompatibility:
Hazardous Polymerization:
Hazardous Decomposition Products:

Stable
None known.
Strong oxidizers.
None anticipated.
Carbon monoxide and carbon dioxide.

Sensitivity to static discharge:

Subject to static discharge hazards. Please see bonding
and grounding information in Section 7.

11. TOXICOLOGICAL INFORMATION
Common Name
CAS-No.
XYLENE
1330-20-7
ETHYLBENZENE
100-41-4
DIETHYLENE GLYCOL
MONOMETHYL ETHER
111-77-3
TOLUENE
108-88-3

Approx. NIOSH - Selected LD50s and LC50s
Weight %
75 - 80
Inhalation LC50 Rat : 5000 ppm/4H
Oral LD50 Rat : 4300 mg/kg
Dermal LD50 Rabbit : >1700 mg/kg
15 - 20
Oral LD50 Rat : 3500 mg/kg
Dermal LD50 Rabbit : 17800 uL/kg
1-5
Oral LD50 Rat : 4 mL/kg
Oral LD50 Mouse : 8222 mg/kg
Dermal LD50 Rabbit : 2500 uL/kg
1-5
Inhalation LC50 Rat : 49 gm/m3/4H
Inhalation LC50 Mouse : 400 ppm/24H
Oral LD50 Rat : 636 mg/kg
Dermal LD50 Rabbit : 14100 uL/kg

Mutagens:

Product ID: 011.0002417.004

Page 4 of 7

Common Name
CAS-No.
TOLUENE
108-88-3

Approx. Calif- Prop. 65. Developmental
Weight % Toxicity
1-5
Listed: January 1, 1991
Developmental toxin.

California Prop 65 - reproductive
male

Teratogens:
Carcinogens:
Contains ethylbenzene, which has been determined by NTP to be an animal carcinogen with no known relevance to
humans. IARC has classified ethylbenzene as possibly carcinogenic to humans (2b) on the basis of sufficient
evidence of carcinogenicity in laboratory animals but inadequate evidence of cancer in humans.
Common Name
CAS-No.
ETHYLBENZENE
100-41-4

Approx. IARC Group 1 - Human IARC Group 2A - limited IARC Group 2b Weight % Evidence
human data
sufficient animal data
15 - 20
Monograph 77, 2000

Common Name
CAS-No.
ETHYLBENZENE
100-41-4

Approx. NTP Known
Weight % carcinogens
15 - 20

NTP Suspect
carcinogens

NTP Evidence of
carcinogenicity
male rat-clear evidence;
female rat-some
evidence; male micesome evidence; female
mice-some evidence

Common Name
CAS-No.
ETHYLBENZENE
100-41-4

Approx. OSHA Select
Weight % carcinogens
15 - 20

OSHA Possible select
carcinogens

ACGIH Carcinogens

If this section is blank, no information is available.

12. ECOLOGICAL DATA
Not available at this time.

13. DISPOSAL CONSIDERATIONS
Disposal should be made in accordance with federal, state and local regulations.

14. TRANSPORTATION INFORMATION
Canadian Transport of Dangerous Goods
Proper Shipping Name:
PAINT
Hazard Class:
3
UN ID Number:
UN1263
Packing Group:
III
International Air Transport Association:
Proper Shipping Name:
PAINT
Hazard Class:
3
UN ID Number:
UN1263
Packing Group:
III
Product ID: 011.0002417.004

Page 5 of 7

Group A3 Confirmed
animal carcinogen with
unknown relevance to
humans.

International Maritime Organization:
Proper Shipping Name:
PAINT
Hazard Class:
3
UN ID Number:
UN1263
Packing Group:
III

15. REGULATORY INFORMATION
INTERNATIONAL REGULATIONS - Chemical Inventories
TSCA Inventory:

All components of this product are in compliance with U.S.
TSCA Chemical Substance Inventory Requirements.

Canada Domestic Substances List:

All components of this product are listed on the Domestic
Substances List.

Canada National Pollutant Release Inventory:
Common Name
CAS-No.
XYLENE
1330-20-7
ETHYLBENZENE
100-41-4
DIETHYLENE GLYCOL
MONOMETHYL ETHER
111-77-3
TOLUENE
108-88-3

Approx. NPRI Status
Weight %
75 - 80
[reporting required]
15 - 20

[reporting required]

1-5

YES

1-5

[reporting required]

This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations and the MSDS contains all of the information required by the Controlled Products Regulations.

16. OTHER INFORMATION
HMIS Codes
Health:
Flammability:
Reactivity:
PPE:

2
3
1
X - See Section 8 for Personal Protective Equipment (PPE).

Abbreviations:
OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer,
NIOSH - National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH American Conference of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management
District, TSCA - Toxic Substances Control Act, IATA - International Air Transport Association, IMO - International
Maritime Organization, DOT - Department of Transportation, NA - Not applicable, NOT ESTAB - Not established,
N.A.V. - Not available, RQ - Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L - Grams
per liter, MM - Millimeters, MPPCF - Millions of particles per cubic foot, PPM - parts per million, PPT - parts per
thousand, TCC/PM - Tag closed cup / Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time
Weighted Average, STEL - Short term exposure limit, C - Celsius, F - Fahrenheit.

Product ID: 011.0002417.004

Page 6 of 7

Disclaimer:
The data on this sheet represent typical values. Since application variables are a major factor in product performance,
this information should serve only as a general guide. Valspar assumes no obligation or liability for use of this
information. UNLESS VALSPAR AGREES OTHERWISE IN WRITING, VALSPAR MAKES NO WARRANTIES,
EXPRESS OR IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT.
VALSPAR WILL NOT BE LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only
remedy for any defect in this product is the replacement of the defective product, or a refund of its purchase price, at
our option. This MSDS contains additional information required by the state of Pennsylvania.
Preparation Information:
Prepared By:
Print date
Revision Date

Regulatory Affairs Department
12/Oct/2005
31/Aug/2005

Technical Information:
The Valspar Corporation - Architectural Coatings Division
1191 Wheeling Road
Wheeling, IL 60090
Tech Info Phone:
847-520-8580
24-Hour Medical Emergency
Phone:

1-888-345-5732

Product ID: 011.0002417.004

Page 7 of 7

The Valspar Corporation
Material Safety Data Sheet
1. PRODUCT AND COMPANY IDENTIFICATION
Material Identification

Product ID:

011.0002316.077

Product Name
Product Use:
Print date
Revision Date

GRAF RMVR 16OZ SPRAY
Paint product.
2005/04/14
2005/04/14

6U

Company Identification
The Valspar Corporation - Architectural Coatings Division
1000 Lake Road
Medina, OH 44256
Manufacturer's Phone:
1-330-725-4511
24-Hour Medical Emergency
Phone:

1-888-345-5732

2. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS
Common Name
CAS-No.
XYLENE
1330-20-7
TOLUENE
108-88-3
ETHYLBENZENE
100-41-4
PROPANE
74-98-6
DIETHYLENE GLYCOL
MONOMETHYL ETHER
111-77-3
BUTANE
106-97-8
METHYL ALCOHOL
67-56-1

approx.
Weight %
45 - 50

Chemical name
Xylenes (o-, m-, p- isomers)

15 - 20

Toluene

10 - 15

Ethyl benzene

10 - 15

Propane

5 - 10

Diethylene glycol monomethyl ether

1-5

Butane

1-5

Methyl alcohol

If this section is blank there are no hazardous components per OSHA guidelines.

3. HAZARDS IDENTIFICATION
Primary Routes of Exposure:
Inhalation
Ingestion
Skin absorption

Product ID:

011.0002316.077

Page 1 of 8

Emergency Overview:
This section not in use.
This product contains ingredients that may contribute to the following potential acute health effects:
Inhalation Effects:
Harmful if inhaled. May affect the brain, nervous system, or respiratory system, causing dizziness, headache, nausea or
respiratory irritation.
Eye Contact:
Corneal Injury/eye damage.
Skin Contact:
May cause moderate skin irritation. May be harmful if absorbed through skin.
Acute Ingestion:
May be fatal or cause blindness if swallowed.
Other Effects:
May cause central nervous system depression. May cause liver damage. Contains ingredient which is considered highly
toxic. May cause kidney damage.
This product contains ingredients that may contribute to the following potential chronic health effects:
Notice: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain
and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful
or fatal.Possible birth defects hazard. Contains ingredients which may cause birth defects based on animal data. May
cause kidney damage. May cause liver damage.
See Section 11 for toxicological information about Mutagens, Teratogens and Carcinogens.
If this section is blank, no information is available.

4. FIRST AID MEASURES
Inhalation:
If affected by inhalation, move victim to fresh air. If symptoms persist, seek medical attention.
Eye Contact:
In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get
medical attention immediately after flushing.
Skin Contact:
In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. If irritation persists get
medical attention.
Ingestion:
Poison! Get medical attention immediately. If swallowed, contact medical personnel immediately to determine best course
of action.
Medical conditions aggravated by exposure: Any respiratory or skin condition.

5. FIRE FIGHTING MEASURES
Product ID:

011.0002316.077

Page 2 of 8

Flash point (Fahrenheit):
Lower explosive limit:
Upper explosive limit:
Autoignition temperature:
Sensitivity to impact:
Sensitivity to static discharge:
information in Section 7.
Hazardous combustion products:

-31º F ( -35º C) TCC/PM
1%
23 %
Not available.º F ( º C)
No.
Subject to static discharge hazards. Please see bonding and grounding
See Section 10.

Unusual fire and explosion hazards:
None known.
Extinguishing media:
Carbon dioxide, dry chemical, foam and/or water fog.
Fire fighting procedures:
Use water spray to cool nearby containers and structures exposed to fire.

6. ACCIDENTAL RELEASE MEASURES
Action to be taken if material is released or spilled:
Ventilate area. Avoid breathing of vapors. Use self-containing breathing apparatus or airmask for large spills in a confined
area. Wipe, scrape or soak up in an inert material and put in a container for disposal. See section 5, "Unusual Fire and
Explosion Hazards", for proper container and storage procedures. Remove sources of ignition. Remove with inert
absorbent and non sparking tools. Avoid contact with eyes.

7. HANDLING AND STORAGE
Precautions to be taken in handling and storage:
Keep away from heat, sparks, and flames. Keep container closed when not in use. Do not store above 120 degrees F. (49
degrees C). Based on flash point and vapor pressure, suitable storage should be provided in accordance with OSHA
regulation 1910.106, Ontario OH&S regulation 851 section 22. Empty containers may contain product residue, including
flammable or explosive vapors. Do not cut, puncture or weld on or near container. All label warnings must be observed
until the container has been commercially cleaned or reconditioned. If the product is used near or above the flashpoint, an
ignition hazard may be present. Activities, uses, or operations which liberate vapor (such as mixing or free fall of liquids)
may also present an ignition hazard. Please ensure containers and other interconnected equipment are properly bonded
and grounded at all times.

8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS
Personal Protective Equipment
Eye and face protection:
Avoid contact with eyes. Wear chemical goggles if there is the possibility of contact or splashing in the eye.
Skin protection:
Appropriate chemical resistant gloves should be worn.To prevent skin contact wear protective clothing covering all
exposed areas.
Respiratory protection:
If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator such as an air
purifying respirator with organic vapor cartridge and dust/mist filter. Consult the respirator manufacturer's literature to
ensure that the respirator will provide adequate protection. Read and follow all respirator manufacturer's instructions.

Product ID:

011.0002316.077

Page 3 of 8

Ventilation
Required when spraying or applying in confined area. Ventilation equipment should be explosion proof. Eliminate ignition
sources.
Exposure Guidelines
OSHA Permissible Exposure Limits (PEL's)
Common Name
CAS-No.
XYLENE
1330-20-7
TOLUENE
108-88-3
ETHYLBENZENE
100-41-4
PROPANE
74-98-6
METHYL ALCOHOL
67-56-1

approx.
Weight %
45 - 50

TWA (final)

Ceilings limits (final)

Skin designations

435 MGM3 100 ppm

15 - 20

200 ppm

300 ppm

10 - 15

435 MGM3 100 ppm

10 - 15

1800 MGM3 1000 ppm

1-5

260 MGM3 200 ppm

ACGIH Threshold Limit Value (TLV's)
Common Name
CAS-No.
XYLENE
1330-20-7
TOLUENE
108-88-3
ETHYLBENZENE
100-41-4
PROPANE
74-98-6
BUTANE
106-97-8
METHYL ALCOHOL
67-56-1

approx.
Weight %
45 - 50

TWA

STEL

100 ppm

15 - 20

50 ppm

10 - 15

100 ppm

10 - 15

1000 ppm

1-5

1000 ppm

1-5

200 ppm

Ceiling limits

150 ppm
Can be absorbed
through the skin.
125 ppm

250 ppm

If this section is blank, no information is available.

9. PHYSICAL PROPERTIES
Odor:
Physical State:
pH:
Vapor pressure:
Vapor density (air = 1.0):
Boiling point:
Solubility in water:
Coefficient of water/oil distribution:
Density (lbs per US gallon):

Product ID:

Skin
designations

Normal for this product type.
Liquid
Not determined.
NOT DETERMINED mmHG @ 68º F ( 20º C)
4.1
-42º F ( -41º C)
Not determined.
Not determined.
6.7

011.0002316.077

Page 4 of 8

Can be absorbed
through the skin.

Specific Gravity
Evaporation rate (butyl acetate = 1.0):

.8
5.9

10. STABILITY AND REACTIVITY
Stability
Conditions to Avoid:
Incompatibility:
Hazardous Polymerization:
Hazardous Decomposition Products:

Stable
None known.
Strong oxidizers.
None anticipated.
Carbon monoxide and carbon dioxide.

Sensitivity to static discharge:

Subject to static discharge hazards. Please see bonding and grounding
information in Section 7.

11. TOXICOLOGICAL INFORMATION
Mutagens:
Common Name
CAS-No.
TOLUENE
108-88-3

approx.
Weight %
15 - 20

Calif- Prop. 65. Developmental
Toxicity
Listed: January 1, 1991
Developmental toxin.

California Prop 65 - reproductive
male

Teratogens:

Carcinogens:
Contains ethylbenzene, which has been determined by NTP to be an animal carcinogen with no known relevance to
humans. IARC has classified ethylbenzene as possibly carcinogenic to humans (2b) on the basis of sufficient evidence of
carcinogenicity in laboratory animals but inadequate evidence of cancer in humans.
Common Name
approx.
IARC Group 1 - Human IARC Group 2A IARC Group 2b CAS-No.
Weight %
Evidence
limited human data
sufficient animal data
ETHYLBENZENE
10 - 15
Monograph 77, 2000
100-41-4
Common Name
CAS-No.
ETHYLBENZENE
100-41-4

approx.
Weight %
10 - 15

NTP Known
carcinogens

NTP Suspect
carcinogens

Common Name
CAS-No.
ETHYLBENZENE
100-41-4

approx.
Weight %
10 - 15

OSHA Select
carcinogens

OSHA Possible select ACGIH Carcinogens
carcinogens
Group A3 Confirmed
animal carcinogen with
unknown relevance to
humans.

Product ID:

011.0002316.077

Page 5 of 8

NTP Evidence of
carcinogenicity
male rat-clear
evidence; female ratsome evidence; male
mice-some evidence;
female mice-some
evidence

If this section is blank, no information is available.

12. ECOLOGICAL DATA
Not available at this time.

13. DISPOSAL CONSIDERATIONS
Disposal should be made in accordance with federal, state and local regulations.

14. TRANSPORTATION INFORMATION
U.S. Department of Transportation
Proper Shipping Name:
CONSUMER COMMODITY ORM-D
UN ID Number:
CONCOM
49 CFR Hazardous Material Regulations Parts 100-180
The supplier will apply the combustible liquid exception in 49 CFR 173.150(f), limited quantity or "does not sustain
combustion" exceptions and consumer commodity rules, when authorized. Please check 49 CFR Parts 100-180 to
determine if the use of these exceptions applies to your shipments when re-shipping our products.
International Air Transport Association:
Proper Shipping Name:
AEROSOLS, FLAMMABLE
Hazard Class:
2.1
UN ID Number:
UN1950
International Maritime Organization:
Proper Shipping Name:
AEROSOLS
Hazard Class:
2
UN ID Number:
UN1950

15. REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS:
Common Name
approx.
CAS-No.
Weight %
XYLENE
45 - 50
1330-20-7
TOLUENE
108-88-3

15 - 20

ETHYLBENZENE
100-41-4

10 - 15

DIETHYLENE GLYCOL
MONOMETHYL ETHER
111-77-3
METHYL ALCOHOL
67-56-1

5 - 10

Product ID:

SARA 302

1-5

011.0002316.077

Page 6 of 8

SARA 313

CERCLA RQ IN LBS.

form R reporting
required for 1.0% de
minimis concentration
form R reporting
required for 1.0% de
minimis concentration
form R reporting
required for 1.0% de
minimis concentration
YES

100

form R reporting
required for 1.0% de
minimis concentration

5000

1000

1000

SARA 311/312 Hazard Class:
Acute:
Yes
Chronic:
Yes
Flammability:
Yes
Reactivity:
No
Sudden Pressure:
Yes
U.S. STATE REGULATIONS:

Pennsylvania Right To Know:
XYLENE
METHYL ALCOHOL
PROPANE
DIETHYLENE GLYCOL MONOMETHYL ETHER
ETHYLBENZENE
BUTANE
TOLUENE

1330-20-7
67-56-1
74-98-6
111-77-3
100-41-4
106-97-8
108-88-3

California Proposition 65:
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
Rule 66 status of product

Photochemically reactive.

INTERNATIONAL REGULATIONS - Chemical Inventories
TSCA Inventory:

All components of this product are in compliance with U.S. TSCA Chemical
Substance Inventory Requirements.

Canada Domestic Substances List:

All components of this product are listed on the Domestic Substances List.

16. OTHER INFORMATION
HMIS Codes
Health:
Flammability:
Reactivity:
PPE:

2
4
1
X - See Section 8 for Personal Protective Equipment (PPE).

Abbreviations:
OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer, NIOSH National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH - American Conference
of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management District, TSCA - Toxic
Substances Control Act, IATA - International Air Transport Association, IMO - International Maritime Organization, DOT Department of Transportation, NA - Not applicable, NOT ESTAB - Not established, N.A.V. - Not available, RQ Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L - Grams per liter, MM - Millimeters,

Product ID:

011.0002316.077

Page 7 of 8

MPPCF - Millions of particles per cubic foot, PPM - parts per million, PPT - parts per thousand, TCC/PM - Tag closed
cup / Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time Weighted Average, STEL - Short term
exposure limit, C - Celsius, F - Fahrenheit.
Disclaimer:
The data on this sheet represent typical values. Since application variables are a major factor in product performance, this
information should serve only as a general guide. Valspar assumes no obligation or liability for use of this information.
UNLESS VALSPAR AGREES OTHERWISE IN WRITING, VALSPAR MAKES NO WARRANTIES, EXPRESS OR
IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. VALSPAR WILL NOT BE
LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only remedy for any defect in this
product is the replacement of the defective product, or a refund of its purchase price, at our option. This MSDS contains
additional information required by the state of Pennsylvania.

Product ID:

011.0002316.077

Page 8 of 8

Material Safety Data Sheet
WHMIS (Pictograms)

WHMIS (Classification)

Personal protective equipment

WHMIS CLASS B-3: Combustible liquid with a flash point
between 37.8°C (100°F) and 93.3°C (200°F).

Section 1. Product and Company Identification
Product
name /
Trade name

Solvent Mineral Spirit

Paint Thinner

Associated
Product’s Item
Code

SOLV 1

83-326

Synonym

Petroleum Distillate

CAS #

Not available.

Chemical family

Aliphatic hydrocarbon (Solvent.)

Validation date

11/8/2007.
Nov. 08 2007

Chemical formula

Not available.

Print date

11/8/2007.
Nov. 08 2007

Manufacturer

Recochem Inc.
850 Montee de Liesse
Montreal, Quebec
514-341-3550

In case of
emergency

Material uses

Not available.

Recochem Inc.
Communications and Regulatory
Affairs Department
(905) 791-1788

Section 2. Hazardous Ingredients
Canada
Name
Petroleum Distillate

CAS number

%
100

There are no ingredients or additional ingredients present which, within the current knowledge of the
supplier and in the concentrations applicable, are classified as hazardous to health or the environment and
hence require reporting in this section.

Section 3. Hazard Identification
Emergency Overview

WARNING !
FLAMMABLE LIQUID AND VAPOR. COMBUSTIBLE.
Flammable liquid. Keep away from heat, sparks and flame. Avoid breathing vapor or mist. Avoid contact with skin
and clothing. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use.

Potential Acute Health
Effects

See Section #11: "Toxicological Information" for further human health effects.
This product may cause mild irritatation to eyes and skin upon contact.
Prolonged and repeated contact with skin can cause drying of the skin resulting in irritation and dermatitis.
Inflammation of the eye is characterized by mild redness, watering, and itching.
Skin inflammation is characterized by mild itching, scaling, reddening.
Ingestion can cause burning sensation, vomiting, drowsiness and in severe cases pulmonary edema.
Inhalation of excessive amounts may result in impairment, such as drowsiness, lack of coordination, headache and
nausea.

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Note to Physician

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Aspiration hazard if swallowed. Can enter lungs and cause damage. Small amounts of liquid aspirated into the
respiratory system during ingestion or from vomiting may cause mild to severe pulmonary injury and possible death.

Section 4. First aid measures
Eye contact

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.
Check for and remove any contact lenses. Get medical attention if irritation occurs.

Skin contact

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if
symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Inhalation

Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the
person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or
are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Ingestion

Wash out mouth with water. Remove dentures if any. Move exposed person to fresh air. Keep person warm and at
rest. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink.
Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so
by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get
medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.

Section 5. Fire fighting measures
Products of combustion

No specific data.

Fire-fighting media and
instructions

Use dry chemical, CO2, water spray (fog) or foam.

Fire Hazards

Container explosion may occur under fire conditions or when heated. Vapor may travel a considerable distance to
source of ignition and flash back. Vigorously supports combustion. Combustible when exposed to heat or flame.

Explosion Hazards

Vapours may travel along ground and flashback along vapour trail.

Section 6. Accidental release measures
Small spill and leak

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble or absorb
with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosionproof equipment. Dispose of via a licensed waste disposal contractor.

Large spill and leak

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows.
Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous
earth and place in container for disposal according to local regulations (see section 13). Use spark-proof tools and
explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material
may pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section
13 for waste disposal.

Section 7. Handling and Storage
Handling

Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited
in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Do not breathe vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Use
only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage
areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative
made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open
flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling)
equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or
explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before

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transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container.
See Section #10 for applicable incompatible materials.
Do not store above the following temperature: 42°C (107.6°F). Store in accordance with local regulations. Store in a
segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources.
Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have
been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.

Storage

Section 8. Exposure controls, personal protection
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to
keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls
also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation
equipment.

Engineering controls

Personal protection
Eyes Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is
necessary to avoid exposure to liquid splashes, mists, gases or dusts.
Recommended: splash goggles

Body Personal protective equipment for the body should be selected based on the task being performed and the risks
involved and should be approved by a specialist before handling this product.

Respiratory Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment

indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards
of the product and the safe working limits of the selected respirator.

Hands Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when
handling chemical products if a risk assessment indicates this is necessary.
>8 hours (breakthrough time): nitrile rubber

Product name

Exposure limits

Canada
Petroleum Distillate

ACGIH (Canada, 2003).
TWA: 100 ppm 8 hour(s).
TWA: 525 mg/m³ 8 hour(s).

United States
Petroleum Distillate

OSHA (United States, 2003).
TWA: 500 ppm 8 hour(s).
TWA: 2900 mg/m³ 8 hour(s).

Section 9. Physical and chemical properties
Physical State and
Appearance

Liquid.

Odour

Petroleum distillates

Molecular weight

Not applicable.

Taste

Not available.

pH

Not applicable.

Colour

Not available.

Boiling/condensation point

150 to 210°C (302 to 410°F)

Volatility

100% (v/v), 100% (w/w)

Melting/freezing point

-58°C (-72.4°F)

Evaporation 0.1 (Butyl acetate. = 1)
rate

Relative density

0.79

Odour
Threshold

Continued on next page

Not available.

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Vapour Pressure

0.29 kPa (2.2 mm Hg)

Viscosity

Kinematic: 0.0114 cm2/s (1.14 cSt)

Vapour Density

5 [Air = 1]

Solubility

Easily soluble in the following materials: diethyl ether, noctanol.
Insoluble in the following materials: water.

VOC Content

790 (g/l).

Other
Properties

Not available.

The product is:

Combustible.

Auto-ignition temperature 229°C (444.2°F)
Flash Point

Closed cup: 42°C (107.6°F) [Tagliabue. (ASTM D56)]

Flammable limits

Lower: 1%
Upper: 13.3%

Fire hazards in the
presence of various
substances

Flammable in the presence of open flames, sparks and static discharge. This product is combustible if exposed to
heat or when in involved in a fire and in contact with combustible materials which may act as a wick.

Section 10. Stability and reactivity
Stability

The product is stable. Under normal conditions of storage and use, hazardous polymerization will not occur.

Conditions of instability

No additional remark.

Incompatibility with
various substances

Reactive with oxidizing agents.

Section 11. Toxicological information
Routes of entry

Eye contact. Inhalation. Ingestion.

Environmental effects

No known significant effects or critical hazards.

Acute effects on humans
Eyes May cause mild eye irritation.
Skin May cause mild skin irritation.
Inhalation Slightly hazardous by the following route of exposure: of inhalation. Exposure to very high concentrations can cause
dizziness, lightheadness, headache, nausea, and blurrred vision. Higher levels may cause unconsciousness.

Ingestion This product is of very low acute toxicity. Aspiration hazard if swallowed. Can enter lungs and cause damage.
Chronic effects on humans

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Section 12. Ecological information
Ecotoxicity

For accidential discharges into environment, see Section #6: "Accidential Release Measures" for suggested
instructions.
No known significant effects or critical hazards.
Not available.

Section 13. Disposal considerations
Waste information

The generation of waste should be avoided or minimized wherever possible. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all
times comply with the requirements of environmental protection and waste disposal legislation and any regional local
authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.

Disposal should be in accordance with applicable regional, national and local laws and regulations.

Section 14. Transport information
Canada Transportation of Dangerous Goods (TDG) Information
Primary Class
Subsidiary Class (if
applicable)

Class 3: Flammable liquid.

Proper shipping name
Hazard identification
number
Packing group

PETROLEUM DISTILLATES, N.O.S.
UN 1268

Special Provisions

In containers of 450L or less this product is not classified as a
Dangerous Goods according to TDG exemption 1.33

-

III

International Maritime Dangerous Goods (IMDG) Transportation Information
Primary Class
Subsidiary Class (if
applicable)

Class 3: Flammable liquid.

Proper shipping name
Hazard identification
number
Packing group

PETROLEUM DISTILLATES, N.O.S.
UN 1268

Marine pollutant
Special Provisions

Not a pollutant.

-

III

In containers of 5 L (5Kg) capacity or less this product is
classified as a "Consumer Commodity" under IMDG regulations.

United States Department of Transportation (DOT) Information
Primary Class

Class 3: Flammable liquid.

Subsidiary class (if
applicable)

-

Proper shipping name

PETROLEUM DISTILLATES, N.O.S.

Continued on next page

Nov. 08 2007
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PaintMineral
ThinnerSpirit
Solvent

Hazard identification
number
Packing group

UN 1268

Special Provisions

In containers of 454L or less this product is not classified as a
Gangerous Good according to exception 173.150 f(1-2)

International Air
Transport Association
(IATA)

For air shipment classification and associated regulations, please refer to the latest edition of
IATA Dangerous Goods Regulations.

III

Section 15. Other Regulatory Information and Pictograms
WHMIS Classification
(Canada)
Canada Domestic
Substances List (DSL)
Status

WHMIS CLASS B-3: Combustible liquid with a flash point between
37.8°C (100°F) and 93.3°C (200°F).

HCS Classification
(U.S.A.)

Combustible liquid

U.S.A. Regulatory Lists

This product and/ or all of its components are on the TSCA inventory list.

Hazardous Material
Information System
(U.S.A.)

This product and/ or all of its components are on the DSL.

Health
Flammability
Reactivity
Personal protection

1
2
0
G

National Fire
Protection
Association
(U.S.A.)

Flammability
Health

2

1 0

Reactivity

Specific hazard

Section 16. Other information
Validated and verified by Compliance and Technical Information Manager on 11/8/2007 ph.# Printed 11/8/2007.
905-791-1788.

Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for
the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain
hazards are described herein, we cannot guarantee that these are the only hazards that exist.

MSDS are available at www.recochem.com

Common Name: CRYSTAL SIMPLE GREEN
Manufacturer: SUNSHINE MAKERS
MSDS Revision Date: 8/1/2006

Grainger Item Number(s): 3UP37, 3UP38, 3UP39, 3UP40
Manufacturer Model Number(s):

MSDS Table of Contents
Click the desired link below to jump directly to that section in the MSDS.
I. PRODUCT & COMPANY INFORMATION
II. INGREDIENT INFORMATION
III. HAZARDS IDENTIFICATION
IV. FIRST AID MEASURES
V. FIRE FIGHTING MEASURES
VI. ACCIDENTAL RELEASE MEASURES
VII. HANDLING, STORAGE & TRANSPORT INFORMATION
VIII. EXPOSURE CONTROLS
IX. PERSONAL PROTECTION
X. PHYSICAL AND CHEMICAL PROPERTIES
XI. STABILITY AND REACTIVITY INFORMATION
XII. TOXICOLOGICAL INFORMATION
XIII. BIODEGRADABILITY AND ENVIRONMENTAL TOXICITY INFORMATION
XIV. DISPOSAL CONSIDERATIONS
XV. OTHER INFORMATION

MATERIAL SAFETY DATA SHEET: CRYSTAL SIMPLE GREEN(R*)
ALSO FOR: SIMPLE GREEN(R*) SAFETY TOWELS
VERSION NO.: 4013
ISSUE DATE: AUGUST 2006

I. PRODUCT & COMPANY INFORMATION

PRODUCT NAME: CRYSTAL SIMPLE GREEN(R*)
OTHER NAMES:
CRYSTAL SIMPLE GREEN(R*) - SPECIALIZED CLEANER / DEGREASER
SIMPLE GREEN(R*) SAFETY TOWELS (FLUID ONLY)
COMPANY NAME:
SUNSHINE MAKERS, INC.
15922 PACIFIC COAST HIGHWAY
HUNTINGTON HARBOUR, CA 92649
USA
TELEPHONE:
800-228-0709

562-795-6000
FAX: 562-592-3034
FOR 24-HOUR EMERGENCY, CALL CHEM-TEL, INC.: 800-255-3924
WEBSITE: WWW.SIMPLEGREEN.COM
USE OF PRODUCT:
A SPECIALIZED CLEANER AND DEGREASER FOR USE IN THE INDUSTRIAL AND
INSTITUTIONAL WORKPLACE. (SIMPLE GREEN(R*) SAFETY TOWELS CONTAIN DILUTED
CRYSTAL SIMPLE GREEN(R*).)

II. INGREDIENT INFORMATION

THE ONLY INGREDIENT OF CRYSTAL SIMPLE GREEN(R*) WITH ESTABLISHED EXPOSURE
LIMITS IS UNDILUTED 2-BUTOXYETHANOL (<6%) (BUTYL) CELLOSOLVE; CAS NO.
111-76-2: THE ACGIH TLV-TWA IS: 20 PPM (97 MG/M3.)
THE QUANTITY OF 2-BUTOXYETHANOL IN SIMPLE GREEN SAFETY TOWELS IS <1%.
BASED UPON CHEMICAL ANALYSIS, CRYSTAL SIMPLE GREEN(R*) CONTAINS NO KNOWN EPA
PRIORITY POLLUTANTS, HEAVY METALS, OR CHEMICALS LISTED UNDER RCRA, CERCLA,
OR CWA. ANALYSIS BY TCLP (TOXICITY CHARACTERISTIC LEACHING PROCEDURE)
ACCORDING TO RCRA REVEALED NO TOXIC ORGANIC OR INORGANIC CONSTITUENTS.
ALL COMPONENTS OF CRYSTAL SIMPLE GREEN(R*) ARE LISTED ON THE TSCA CHEMICAL
SUBSTANCE INVENTORY.

III. HAZARDS IDENTIFICATION

UN NUMBER: NOT REQUIRED
DANGEROUS GOODS CLASS: NONHAZARDOUS
NJ TRADE SECRET REGISTRATION NUMBERS:
80100235-5000P
80100235-5001P
80100235-5002P
80100235-5003P
80100235-5004P
80100235-5005P
80100235-5006P
80100235-5007P
80100235-5008P
80100235-5009P
HAZARD RATING (NFPA/HMIS):
HEALTH
1*
REACTIVITY 0
FIRE
0
SPECIAL
0
NFPA:
1
0
0
0
RATING SCALE:
0 = MINIMAL
1 = SLIGHT

2 = MODERATE
3 = SERIOUS
4 = SEVERE
*MILD EYE IRRITANT, NON-MUTAGENIC AND NON-CARCINOGENIC. NONE OF THE
INGREDIENTS IN CRYSTAL SIMPLE GREEN(R*) ARE REGULATED OR LISTED AS CANCER
AGENTS BY FEDERAL OSHA, NTP, OR IARC.

IV. FIRST AID MEASURES

SYMPTOMS OF OVEREXPOSURE AND FIRST AID TREATMENT:
EYE CONTACT:
REDDENING MAY DEVELOP. IMMEDIATELY RINSE THE EYE WITH LARGE QUANTITIES OF
COOL WATER; CONTINUE 10-15 MINUTES OR UNTIL THE MATERIAL HAS BEEN REMOVED;
BE SURE TO REMOVE CONTACT LENSES, IF PRESENT, AND TO LIFT UPPER AND LOWER
LIDS DURING RINSING. GET MEDICAL ATTENTION IF IRRITATION PERSISTS.
SKIN CONTACT:
MINIMAL EFFECTS, IF ANY; RINSE SKIN WITH WATER, RINSE SHOES AND LAUNDER
CLOTHING BEFORE REUSE. REVERSIBLE REDDENING MAY OCCUR IN SOME
DERMAL-SENSITIVE USERS; THOROUGHLY RINSE AREA AND GET MEDICAL ATTENTION IF
REACTION PERSISTS.
SWALLOWING:
ESSENTIALLY NON-TOXIC. GIVE SEVERAL GLASSES OF WATER TO DILUTE; DO NOT
INDUCE VOMITING. IF STOMACH UPSET OCCURS, CONSULT PHYSICIAN.
INHALATION:
NON-TOXIC. EXPOSURES TO CONCENTRATE-MIST MAY CAUSE MILD IRRITATION OF NASAL
PASSAGES OR THROAT; REMOVE TO FRESH AIR. GET MEDICAL ATTENTION IF IRRITATION
PERSISTS.

V. FIRE FIGHTING MEASURES

CRYSTAL SIMPLE GREEN(R*) IS STABLE, NOT FLAMMABLE, AND WILL NOT BURN.
FLASH POINT/AUTO-IGNITION: NOT FLAMMABLE.
FLAMMABILITY LIMITS: NOT FLAMMABLE.
EXTINGUISHING MEDIA:
NOT FLAMMABLE/NONEXPLOSIVE. NO SPECIAL PROCEDURES REQUIRED.
SPECIAL FIRE FIGHTING PROCEDURES: NONE REQUIRED.

VI. ACCIDENTAL RELEASE MEASURES

RECOVER USABLE MATERIAL BY CONVENIENT METHOD; RESIDUAL MAY BE REMOVED BY
WIPE OR WET MOP. IF NECESSARY, UNRECOVERABLE MATERIAL MAY BE WASHED TO DRAIN
WITH LARGE QUANTITIES OF WATER.

VII. HANDLING, STORAGE & TRANSPORT INFORMATION

NO SPECIAL PRECAUTIONS ARE REQUIRED. THIS PRODUCT IS NON-HAZARDOUS FOR
STORAGE AND TRANSPORT ACCORDING TO THE U.S. DEPARTMENT OF TRANSPORTATION
REGULATIONS. CRYSTAL SIMPLE GREEN(R*) REQUIRES NO SPECIAL LABELING OR

PLACARDING TO MEET U.S. DEPARTMENT OF TRANSPORTATION REQUIREMENTS.
UN NUMBER: NOT REQUIRED
DANGEROUS GOODS CLASS: NONHAZARDOUS

VIII. EXPOSURE CONTROLS

EXPOSURE LIMITS:
THE CRYSTAL SIMPLE GREEN(R*) FORMULATION PRESENTS NO HEALTH HAZARDS TO THE
USER WHEN USED ACCORDING TO LABEL DIRECTIONS FOR ITS INTENDED PURPOSES. MILD
SKIN AND EYE IRRITATION IS POSSIBLE (PLEASE SEE EYE CONTACT AND SKIN CONTACT
IN SECTION IV.).
VENTILATION:
NO SPECIAL VENTILATION IS REQUIRED DURING USE. LARGE-SCALE USES INDOORS
SHOULD PROVIDE AN INCREASED RATE OF AIR EXCHANGE.
HUMAN HEALTH EFFECTS OR RISKS FROM EXPOSURE:
ADVERSE EFFECTS ON HUMAN HEALTH ARE NOT EXPECTED FROM CRYSTAL SIMPLE
GREEN(R*), BASED UPON TWENTY YEARS OF USE OF SIMPLE GREEN WITHOUT REPORTED
ADVERSE HEALTH INCIDENCE IN DIVERSE POPULATION GROUPS, INCLUDING EXTENSIVE
USE BY INMATES OF U.S. FEDERAL PRISONS IN CLEANING OPERATIONS.
CRYSTAL SIMPLE GREEN(R*) IS A MILD EYE IRRITANT; MUCOUS MEMBRANES MAY BECOME
IRRITATED BY CONCENTRATE-MIST.
CRYSTAL SIMPLE GREEN(R*) IS NOT LIKELY TO IRRITATE THE SKIN IN THE MAJORITY
OF USERS. REPEATED DAILY APPLICATION TO THE SKIN WITHOUT RINSING, OR
CONTINUOUS CONTACT OF CRYSTAL SIMPLE GREEN(R*) ON THE SKIN MAY LEAD TO
TEMPORARY, BUT REVERSIBLE, IRRITATION.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
NO AGGRAVATION OF EXISTING MEDICAL CONDITIONS IS EXPECTED; DERMAL-SENSITIVE
USERS MAY REACT TO DERMAL CONTACT BY CRYSTAL SIMPLE GREEN(R*).

IX. PERSONAL PROTECTION

PRECAUTIONARY MEASURES: NO SPECIAL REQUIREMENTS UNDER NORMAL USE CONDITIONS.
EYE PROTECTION:
CAUTION, INCLUDING REASONABLE EYE PROTECTION, SHOULD ALWAYS BE USED TO AVOID
EYE CONTACT WHERE SPLASHING MAY OCCUR.
SKIN PROTECTION:
NO SPECIAL PRECAUTIONS REQUIRED; RINSE COMPLETELY FROM SKIN AFTER CONTACT.
RESPIRATORY PROTECTION:
NO SPECIAL PRECAUTIONS REQUIRED EXCEPT DURING LARGE-SCALE SPRAY APPLICATIONS
WHERE SPRAY MIST LEVELS ARE HIGH.
WORK AND HYGIENIC PRACTICES:
WASH OR RINSE HANDS BEFORE TOUCHING EYES OR CONTACT LENSES. FOLLOW STANDARD
HYGIENIC PRACTICES FOR HANDLING CLEANING AGENTS.

X. PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE/ODOR: CLEAR LIQUID
SPECIFIC GRAVITY: 1.020

pH OF CONCENTRATE: 9.35
EVAPORATION: >1 (BUTYL ACETATE = 1)
BOILING POINT: 100.6 DEG. C (212 DEG. F )
FREEZING POINT: -9 DEG. C (16 DEG. F)
IF PRODUCT FREEZES, IT WILL RECONSTITUTE WITHOUT LOSS OF EFFICACY WHEN
BROUGHT BACK TO ROOM TEMPERATURE AND AGITATED.
VAPOR PRESSURE:
18 MMHg @ 20 DEG. C
23.5 MMHg @ 26 DEG. C
VAPOR DENSITY: 1.3 (AIR = 1)
DENSITY: 8.5 LBS./GALLON
VOC COMPOSITE PARTIAL PRESSURE: 0 MMHg @ 20 DEG. C
VOLATILE ORGANIC COMPOUNDS (VOCS):
0 G/L PER ASTM METHOD 3960-90. PER EPA METHOD 24, VOCS ARE 5.9% AND PRODUCT
MUST BE DILUTED AT LEAST 1 PART OF WATER TO 1 PART SIMPLE GREEN(R*) IN ORDER
TO MEET CARB 2005 VOC REGULATIONS - OR 1 PART SIMPLE GREEN TO 3 PARTS WATER
TO MEET SCAQMD RULE 1171 & RULE 1122 AND BAAQMD REGULATION 8-16 VOC
REQUIREMENTS FOR SOLVENT CLEANING OPERATIONS.
SAFETY TOWEL VOCS: PER EPA METHOD 24, VOCS ARE 0.5%.
SAFETY TOWEL pH: 8.1 - 8.8
WATER SOLUBILITY: CRYSTAL SIMPLE GREEN(R*) IS COMPLETELY SOLUBLE IN WATER.
DETECTION:
CRYSTAL SIMPLE GREEN(R*) AND SIMPLE GREEN(R*) SAFETY TOWELS HAVE A
CHARACTERISTIC ODOR THAT IS NOT INDICATIVE OF ANY HAZARDOUS SITUATION.

XI. STABILITY AND REACTIVITY INFORMATION

NONREACTIVE. CRYSTAL SIMPLE GREEN(R*) IS STABLE, EVEN UNDER FIRE CONDITIONS,
AND WILL NOT REACT WITH WATER OR OXIDIZERS. HAZARDOUS POLYMERIZATION WILL
NOT OCCUR.

XII. TOXICOLOGICAL INFORMATION

THE INFORMATION AND CONCLUSIONS CITED IN THIS SECTION ARE BASED ON DATA AND
TESTING OF SIMPLE GREEN(R*). THE DATA ARE DIRECTLY APPLICABLE TO CRYSTAL
SIMPLE GREEN(R*) BECAUSE BOTH FORMULATIONS ARE VIRTUALLY IDENTICAL, EXCEPT
FOR FRAGRANCE AND COLOR.
NONHUMAN TOXICITY:
ACUTE MORTALITY STUDIES:
ORAL LD50 (RAT): >5.0 G/KG BODY WEIGHT
DERMAL LD50 (RABBIT): >2.0 G/KG BODY WEIGHT
DERMAL IRRITATION:
ONLY MILD, BUT REVERSIBLE, IRRITATION WAS FOUND IN A STANDARD 72-HR TEST ON
RABBITS. A VALUE OF 0.2 (NON-IRRITATING) WAS FOUND ON A SCALE OF 8.
EYE IRRITATION:

WITH OR WITHOUT RINSING WITH WATER, THE IRRITATION SCORES IN RABBITS AT 24
HOURS DID NOT EXCEED 15 (MILD IRRITANT) ON A SCALE OF 110.
SUBCHRONIC DERMAL EFFECTS:
NO ADVERSE EFFECTS, EXCEPT REVERSIBLE DERMAL IRRITATION, WERE FOUND IN
RABBITS EXPOSED TO SIMPLE GREEN(R*) (UP TO 2.0 G/KG/DAY FOR 13 WEEKS)
APPLIED TO THE SKIN OF 25 MALES AND 25 FEMALES. ONLY FEMALE BODY WEIGHT GAIN
WAS AFFECTED. DETAILED MICROSCOPIC EXAMINATION OF ALL MAJOR TISSUES SHOWED
NO ADVERSE CHANGES.
FERTILITY ASSESSMENT BY CONTINUOUS BREEDING:
THE SIMPLE GREEN(R*) FORMULATION HAD NO ADVERSE EFFECT ON FERTILITY AND
REPRODUCTION IN CD-1 MICE WITH CONTINUOUS ADMINISTRATION FOR 18 WEEKS, AND
HAD NO ADVERSE EFFECT ON THE REPRODUCTIVE PERFORMANCE OF THEIR OFFSPRING.

XIII. BIODEGRADABILITY AND ENVIRONMENTAL TOXICITY INFORMATION

BIODEGRADABILITY:
LIKE SIMPLE GREEN(R*), CRYSTAL SIMPLE GREEN(R*) IS READILY DECOMPOSED BY
NATURALLY OCCURRING MICROORGANISMS. THE BIOLOGICAL OXYGEN DEMAND (BOD), AS A
PERCENTAGE OF THE CHEMICAL OXYGEN DEMAND (COD), AFTER 4, 7, AND 11 DAYS WAS
56%, 60%, AND 70%, RESPECTIVELY. PER OECD CLOSED BOTTLE TEST, CRYSTAL SIMPLE
GREEN(R*) MEETS OECD AND EPA RECOMMENDATIONS FOR READY BIODEGRADABILITY.
IN A STANDARD BIODEGRADATION TEST WITH SOILS FROM THREE DIFFERENT COUNTRIES,
BUTYL CELLOSOLVE REACHED 50% DEGRADATION IN 6 TO 23 DAYS, DEPENDING UPON
SOIL TYPE, AND EXCEEDED THE RATE OF DEGRADATION FOR GLUCOSE, WHICH WAS USED
AS A CONTROL FOR COMPARISON.
ENVIRONMENTAL TOXICITY INFORMATION:
CRYSTAL SIMPLE GREEN(R*) IS CONSIDERED PRACTICALLY NON-TOXIC PER EPA'S
AQUATIC TOXICITY SCALE.

XIV. DISPOSAL CONSIDERATIONS

CRYSTAL SIMPLE GREEN(R*) IS FULLY WATER SOLUBLE AND BIODEGRADABLE AND WILL
NOT HARM SEWAGE-TREATMENT MICROORGANISMS IF DISPOSAL BY SEWER OR DRAIN IS
NECESSARY. DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE, AND
FEDERAL LAWS.

XV. OTHER INFORMATION

CONTAINERS:
CRYSTAL SIMPLE GREEN(R*) RESIDUES CAN BE COMPLETELY REMOVED BY RINSING WITH
WATER; THE CONTAINER MAY BE RECYCLED OR APPLIED TO OTHER USES.
CONTACT POINT:
SUNSHINE MAKERS, INC., RESEARCH AND DEVELOPMENT DIVISION: 562-795-6000.
NATIONAL STOCK NUMBERS:
PART#

NSN

SIZE

19024

7930-01-418-1151

24 OZ. SPRAY (12/CS)

19128

7930-01-418-1152

1 GAL. (6/CS)

19005

7930-01-418-1153

5 GAL.

19055

7930-01-418-1155

55 GAL.

SIMPLE GREEN SAFETY TOWEL PART NUMBERS:
PART #

SIZE

13353

5-COUNT POUCH (50/CS)

13351

75-COUNT CANISTER (6/CS)

NOTICE:
ALL INFORMATION APPEARING HEREIN IS BASED UPON DATA OBTAINED BY THE
MANUFACTURER AND RECOGNIZED TECHNICAL SOURCES. JUDGMENTS AS TO THE
SUITABILITY OF INFORMATION HEREIN FOR PURCHASER'S PURPOSES ARE NECESSARILY
PURCHASER'S RESPONSIBILITY. THEREFORE, ALTHOUGH REASONABLE CARE HAS BEEN
TAKEN IN THE PREPARATION OF THIS INFORMATION, SUNSHINE MAKERS, INC. OR ITS
DISTRIBUTORS EXTENDS NO WARRANTIES, MAKES NO REPRESENTATIONS AND ASSUMES NO
RESPONSIBILITY AS TO THE SUITABILITY OF SUCH INFORMATION FOR APPLICATION TO
PURCHASER'S INTENDED PURPOSES OR FOR CONSEQUENCES OF ITS USE.

Material Safety Data Sheet:
Version No. 10013c

Section 1:

Simple Green® All-Purpose Cleaner
Simple Green® Scrubbing Pad
Date of Issue: July 2007

PRODUCT & COMPANY IDENTIFICATION

Product Name:
Additional Name:

Simple Green® All-Purpose Cleaner
Simple Green® Scrubbing Pad
Simple Green® Concentrated Cleaner/Degreaser/Deodorizer

Manufacturer’s Product Code Numbers:
Company:
Telephone:
Emergency Phone:
Use of Product:

Section 2:

ANSI-Z400.1-2003 Format

*Please refer to page 4

Sunshine Makers, Inc.
15922 Pacific Coast Highway
Huntington Harbour, CA 92649 USA
800-228-0709 ● 562-795-6000
Fax: 562-592-3830
Chem-Tel 24-Hour Emergency Service: 800-255-3924
An all purpose cleaner and degreaser used diluted in water for direct, spray and dip tank procedures.
Scrubbing pad is used with water for manual scrubbing applications.

HAZARDS IDENTIFICATION

Emergency Overview: CAUTION. Mild eye irritant.
Simple Green@ is a dark green liquid with a sassafras odor. Scrubbing Pad is a green fibrous rectangle.
0
0

1
0

HMIS Rating:
Health = 1 = slight
Fire = 0
Reactivity, and Special = 0 = minimal

Eye Contact:

Mild Eye Irritant.

Skin Contact:

No adverse effects expected under typical use conditions. Prolonged exposure may cause dryness. Under
this condition, use of gloves or skin moisturizer after washing may be indicated.

Ingestion:

May cause stomach or intestinal upset if swallowed (due to detersive properties.)

Inhalation:

No adverse effects expected under typical use conditions. Adequate ventilation should be present when
using Simple Green® over a prolonged period of time. Open windows or ventilate via fan or other airmoving equipment if necessary.

Carcinogens:

No ingredients are listed by OSHA, IARC, or NTP as known or suspected carcinogens.

Medical Conditions:

Not Required

UN Number:

Section 3:

No medical conditions are known to be aggravated by exposure to Simple Green®. Dermalsensitive users may experience mild but reversible reactions.
Dangerous Goods Class:

Nonhazardous

COMPOSITION/INFORMATION ON INGREDIENTS

The only ingredient of Simple Green® with established exposure limits is undiluted 2-butoxyethanol (<6%) (Butyl
Cellosolve; CAS No. 111-76-2): the ACGIH TLV-TWA is 20 ppm (97 mg/m3). Based upon chemical analysis, Simple
Green® contains no known EPA priority pollutants, heavy metals or chemicals listed under RCRA, CERCLA, or CWA.
Analysis by TCLP (Toxicity Characteristic Leaching Procedure) according to RCRA revealed no toxic organic or
inorganic constituents.
All components of Simple Green® are listed on the TSCA Chemical Substance Inventory.
80100235-5000p
80100235-5001p

80100235-5002p
80100235-5003p

NJ Trade Secret Numbers
80100235-5004p
80100235-5006p
80100235-5005p
80100235-5007p

Material Safety Data Sheet: SIMPLE GREEN® ALL-PURPOSE CLEANER & SCRUBBING PAD

80100235-5008p
80100235-5009p
Pg 1 of 4

Material Safety Data Sheet:
Version No. 10013c

Simple Green® All-Purpose Cleaner
Simple Green® Scrubbing Pad
Date of Issue: July 2007

ANSI-Z400.1-2003 Format

Section 4:

FIRST AID MEASURES

Eye Contact:

Reddening may develop. Immediately rinse the eye with large quantities of cool water; continue 10-15
minutes or until the material has been removed; be sure to remove contact lenses, if present, and to lift upper
and lower lids during rinsing. Get medical attention if irritation persists.

Skin Contact:

Minimal effects, if any; rinse skin with water, rinse shoes and launder clothing before reuse. Reversible
reddening may occur in some dermal-sensitive users; thoroughly rinse area and get medical attention if
reaction persists.

Swallowing;

Essentially non-toxic. Give several glasses of water to dilute; do not induce vomiting. If stomach upset
occurs, consult physician.

Inhalation:

Non-toxic. Exposure to concentrate may cause mild irritation of nasal passages or throat; remove to fresh
air. Get medical attention if irritation persists.

Section 5:

FIRE FIGHTING MEASURES

Simple Green® is stable, not flammable, and will not burn. No special procedures required.
Flash Point/Auto-Ignition: Not flammable.
Flammability Limits: Not flammable.

Section 6:

Extinguishing Media: Not flammable/nonexplosive.
Special Fire Fighting Procedures: None required.

ACCIDENTAL RELEASE MEASURES

Personal Precautions: Avoid contact with eyes. Do not rub eyes with hands during cleanup. No special precautions for
dermal contact are needed. Wash hands thoroughly after cleaning up spill or leak.
Method for cleaning up: Recover usable material by convenient method, residual may be removed by wipe or wet mop.
If necessary, unrecoverable material may be washed to drain with large quantities of water.

Section 7:

HANDLING AND STORAGE

No Special precautions are required. This product is non-hazardous for storage and transport according to the U.S.
Department of Transportation Regulations. Simple Green® requires no special labeling or placarding to meet U.S.
Department of Transportation requirements.
Not Required

UN Number:

Section 8:

Dangerous Goods Class:

Nonhazardous

EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Limits:

The Simple Green® formulation presents no health hazards to the user when used according to label
directions for its intended purposes. Mild skin and eye irritation is possible (please see Eye contact
and Skin contact in section IV.) No special precautionary measures required under normal use
conditions.

Ventilation:

No special ventilation, precautions or respiratory protection is required during normal use. Largescale use indoors should provide an increased rate of air exchange.

Human Health
Effects or Risks
From Exposure:

Adverse effects on human health are not expected from Simple Green®, based on 20 years of use of
Simple Green® without reported adverse health incidence in diverse population groups, including
extensive use by inmates of U.S. Federal prisons in cleaning operations.

Eye protection:

Simple Green® is a mild eye irritant; mucous membranes may become irritated by concentrate. Eye
protection not generally required. Wash hands after using wipes.

Skin protection:

Simple Green® is not likely to irritate the skin in the majority of users. Repeated daily application to
the skin without rinsing, or continuous contact on the skin may lead to temporary, but reversible,
irritation. Rinse completely from skin after contact.

Material Safety Data Sheet: SIMPLE GREEN® ALL-PURPOSE CLEANER & SCRUBBING PAD

Pg 2 of 4

Material Safety Data Sheet:

Simple Green® All-Purpose Cleaner
Simple Green® Scrubbing Pad
Date of Issue: July 2007

Version No. 10013c

Section 8:

EXPOSURE CONTROLS/PERSONAL PROTECTION – continued –

General hygiene
conditions:

Section 9:

ANSI-Z400.1-2003 Format

There are no known hazards associated with this material when used as recommended.
The following general hygiene considerations are recognized as common good industrial hygiene
practices:
- Avoid breathing vapor or mist.
- Avoid contact with eyes.
- Wash thoroughly after handling and before eating, drinking, or smoking.

PHYSICAL AND CHEMICAL PROPERTIES

Appearance & Odor: Cleaner is a dark green liquid, pad is a fibrous green matrix; both exhibit a sassafras odor.
Specific Gravity:

1.020

Vapor Pressure:

18 mm Hg @ 20oC; 23.5 mmHg @ 26oC

Evaporation:

>1 (butyl acetate = 1)

Vapor Density:

1.3 (air = 1)

Water Solubility:

100%

Density:

8.5 lbs/gallon

pH:

9.35;

Boiling Point:
Ash Content:

o

o

100.6 C (212 F)

Safety Towel pH is 8.1 - 8.8

o

At 600 F: 1.86% by weight

Nutrient Content:
Phosphorus: 0.3% by formula
Approx -9 C (16 F)
Freezing Point:
Nitrogen <1.0% by weight (fusion and qualitative test for ammonia)
If product freezes, it will reconstitute without loss of efficacy
Sulfur: 0.6% by weight (barium chloride precipitation method)
when brought back to room temperature and agitated.
o
VOC Composite Partial Pressure: 0.006 mmHg @ 20 C
o

o

Volatile Organic Compounds (VOCs): Per EPA Method 24, VOC’s are 5.9%. Cleaner must be diluted at least 1 part
Simple Green to 2 parts water to meet CARB, and 1 part Simple Green to 3 parts water to meet SCAQMD Rule 1171 &
Rule 1122 and BAAQMD Regulation 8-16 VOC requirements for solvent cleaning operations. Towel VOCs are 1.2%.

Section 10: STABILITY AND REACTIVITY
Stability:
Materials to Avoid:
Hazardous Decomposition Products:

Stable
None known
None expected

Section 11: TOXICOLOGICAL INFORMATION
Nonhuman Toxicity (Data for Simple Green®)
Acute Toxicity:
Oral LD50 (rat): >5.0 g/kg body weight

Dermal LD50 (rabbit)

>2.0 g/kg body weight

Eye Irritation:

With or without rinsing with water, the irritation scores in rabbits at 24 hours did not exceed 15
(mild irritant) on a scale of 0-110.

Dermal Irritation:

Only mild, but reversible, irritation was found in a standard 72 hour test on rabbits. A value of 0.2
(non-irritating) was found on a scale of 0-8.

Subchronic Dermal
effects:

No adverse effects, except reversible dermal irritation, were found in rabbits exposed to Simple
Green (up to 2.0 g/kg/day for 13 weeks) applied to the skin of 25 males and 25 females. Only
female body weight gain was affected.

Fertility Assessment
by Continuous
Breeding:

The Simple Green® formulation had no adverse effect on fertility and reproduction in Cd-1 mice
with continuous administration for 18 weeks, and had no adverse effect on the reproductive
performance of their offspring.

Material Safety Data Sheet: SIMPLE GREEN® ALL-PURPOSE CLEANER & SCRUBBING PAD

Pg 3 of 4

Material Safety Data Sheet:
Version No. 10013c

Simple Green® All-Purpose Cleaner
Simple Green® Scrubbing Pad
Date of Issue: July 2007

ANSI-Z400.1-2003 Format

Section 12: ECOLOGICAL INFORMATION
Biodegradability: Simple Green® is readily decomposed by naturally occurring microorganisms. The biological oxygen
demand (BOD), as a percentage of the chemical oxygen demand (COD), after 4, 7, and 11 days was 56%, 60% and 70%,
respectively. Per OECD Closed Bottle Test, Simple Green® meets OECD and EPA recommendations for ready
biodegradability.
In a standard biodegradation test with soils from three different countries, Butyl Cellosolve reached 50% degradation in 6
to 23 days, depending upon soil type, and exceeded the rate of degradation for glucose which was used as a control for
comparison.
Environmental Toxicity Information: Simple Green® is considered practically non-toxic per EPA’s Aquatic toxicity
scale.

Section 13: DISPOSAL CONSIDERATIONS
Dispose of in accordance with all applicable local, state and federal laws. Dispose of used or unused product, and empty
containers in accordance with the local, State, Provincial, and Federal regulations for your location. Never dispose of used
degreasing rinsates into lakes, streams, and open bodies of water or storm drains.

Section 14: TRANSPORT INFORMATION
This product is non-hazardous for transport according to the U.S. Department of Transportation Services
UN Number: Not required
Dangerous Goods Class: Nonhazardous

Section 15: REGULATORY INFORMATION
All components are listed on:
*Reportable components:
RCRA Status:
TSCA TRI Reporting:

EINECS and TSCA Inventory
None.
No components listed under:
Not a hazardous waste.
CERCLA Status:
Not required / Not listed
CA PROP. 65 Status:

Clean Air Act Section 112
No components listed
No components listed

Section 16: OTHER INFORMATION
Questions about the information found on this MSDS should be directed to:
SUNSHINE MAKERS, INC. – TECHNICAL DEPARTMENT
15922 Pacific Coast Hwy. Huntington Harbour, CA 92649
Phone: 800/228-0709 [8am-5pm Pacific time, Mon-Fri]

Fax: 562/592-3830

National Stock Numbers & Industrial Numbers:
Simple Green

Scrubbing Pad

Part Number
13012
13005
13006
13016
13008
Part Number
10224

NSN
7930-01-342-5315
7930-01-306-8369
7930-01-342-5316
7930-01-342-5317
7930-01-342-4145
NSN
7930-01-346-9148

Email: infoweb@simplegreen.com
Retail Numbers:

Size
24 oz spray (12/case)
1 Gallon (6/case)
5 Gallon
15 Gallon
55 Gallon
Size
Each (24/case)

Part Number
13002
13005
13013
13014
13033

Size
16 oz Trigger (12/case)
1 Gallon (6/case)
24 oz Trigger (12/case)
67 oz / 2 L (6/case)
32 oz Trigger (12/case)

* part number is for both industrial and retail

**International Part Numbers May Differ.

DISCLAIMER: The information provided with this MSDS is furnished in good faith and without warranty of any kind. Personnel
handling this material must make independent determinations of the suitability and completeness of information from all sources to
assure proper use and disposal of this material and the safety and health of employees and customers. Sunshine Makers, Inc. assumes
no additional liability or responsibility resulting from the use of, or reliance on this information.

Material Safety Data Sheet: SIMPLE GREEN® ALL-PURPOSE CLEANER & SCRUBBING PAD

Pg 4 of 4

Material Safety Data Sheet:
Version No. 10013c

Section 1:

Simple Green® All-Purpose Cleaner
Simple Green® Scrubbing Pad
Date of Issue: July 2007

PRODUCT & COMPANY IDENTIFICATION

Product Name:
Additional Name:

Simple Green® All-Purpose Cleaner
Simple Green® Scrubbing Pad
Simple Green® Concentrated Cleaner/Degreaser/Deodorizer

Manufacturer’s Product Code Numbers:
Company:
Telephone:
Emergency Phone:
Use of Product:

Section 2:

ANSI-Z400.1-2003 Format

*Please refer to page 4

Sunshine Makers, Inc.
15922 Pacific Coast Highway
Huntington Harbour, CA 92649 USA
800-228-0709 ● 562-795-6000
Fax: 562-592-3830
Chem-Tel 24-Hour Emergency Service: 800-255-3924
An all purpose cleaner and degreaser used diluted in water for direct, spray and dip tank procedures.
Scrubbing pad is used with water for manual scrubbing applications.

HAZARDS IDENTIFICATION

Emergency Overview: CAUTION. Mild eye irritant.
Simple Green@ is a dark green liquid with a sassafras odor. Scrubbing Pad is a green fibrous rectangle.
0
0

1
0

HMIS Rating:
Health = 1 = slight
Fire = 0
Reactivity, and Special = 0 = minimal

Eye Contact:

Mild Eye Irritant.

Skin Contact:

No adverse effects expected under typical use conditions. Prolonged exposure may cause dryness. Under
this condition, use of gloves or skin moisturizer after washing may be indicated.

Ingestion:

May cause stomach or intestinal upset if swallowed (due to detersive properties.)

Inhalation:

No adverse effects expected under typical use conditions. Adequate ventilation should be present when
using Simple Green® over a prolonged period of time. Open windows or ventilate via fan or other airmoving equipment if necessary.

Carcinogens:

No ingredients are listed by OSHA, IARC, or NTP as known or suspected carcinogens.

Medical Conditions:

Not Required

UN Number:

Section 3:

No medical conditions are known to be aggravated by exposure to Simple Green®. Dermalsensitive users may experience mild but reversible reactions.
Dangerous Goods Class:

Nonhazardous

COMPOSITION/INFORMATION ON INGREDIENTS

The only ingredient of Simple Green® with established exposure limits is undiluted 2-butoxyethanol (<6%) (Butyl
Cellosolve; CAS No. 111-76-2): the ACGIH TLV-TWA is 20 ppm (97 mg/m3). Based upon chemical analysis, Simple
Green® contains no known EPA priority pollutants, heavy metals or chemicals listed under RCRA, CERCLA, or CWA.
Analysis by TCLP (Toxicity Characteristic Leaching Procedure) according to RCRA revealed no toxic organic or
inorganic constituents.
All components of Simple Green® are listed on the TSCA Chemical Substance Inventory.
80100235-5000p
80100235-5001p

80100235-5002p
80100235-5003p

NJ Trade Secret Numbers
80100235-5004p
80100235-5006p
80100235-5005p
80100235-5007p

Material Safety Data Sheet: SIMPLE GREEN® ALL-PURPOSE CLEANER & SCRUBBING PAD

80100235-5008p
80100235-5009p
Pg 1 of 4

Material Safety Data Sheet:
Version No. 10013c

Simple Green® All-Purpose Cleaner
Simple Green® Scrubbing Pad
Date of Issue: July 2007

ANSI-Z400.1-2003 Format

Section 4:

FIRST AID MEASURES

Eye Contact:

Reddening may develop. Immediately rinse the eye with large quantities of cool water; continue 10-15
minutes or until the material has been removed; be sure to remove contact lenses, if present, and to lift upper
and lower lids during rinsing. Get medical attention if irritation persists.

Skin Contact:

Minimal effects, if any; rinse skin with water, rinse shoes and launder clothing before reuse. Reversible
reddening may occur in some dermal-sensitive users; thoroughly rinse area and get medical attention if
reaction persists.

Swallowing;

Essentially non-toxic. Give several glasses of water to dilute; do not induce vomiting. If stomach upset
occurs, consult physician.

Inhalation:

Non-toxic. Exposure to concentrate may cause mild irritation of nasal passages or throat; remove to fresh
air. Get medical attention if irritation persists.

Section 5:

FIRE FIGHTING MEASURES

Simple Green® is stable, not flammable, and will not burn. No special procedures required.
Flash Point/Auto-Ignition: Not flammable.
Flammability Limits: Not flammable.

Section 6:

Extinguishing Media: Not flammable/nonexplosive.
Special Fire Fighting Procedures: None required.

ACCIDENTAL RELEASE MEASURES

Personal Precautions: Avoid contact with eyes. Do not rub eyes with hands during cleanup. No special precautions for
dermal contact are needed. Wash hands thoroughly after cleaning up spill or leak.
Method for cleaning up: Recover usable material by convenient method, residual may be removed by wipe or wet mop.
If necessary, unrecoverable material may be washed to drain with large quantities of water.

Section 7:

HANDLING AND STORAGE

No Special precautions are required. This product is non-hazardous for storage and transport according to the U.S.
Department of Transportation Regulations. Simple Green® requires no special labeling or placarding to meet U.S.
Department of Transportation requirements.
Not Required

UN Number:

Section 8:

Dangerous Goods Class:

Nonhazardous

EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Limits:

The Simple Green® formulation presents no health hazards to the user when used according to label
directions for its intended purposes. Mild skin and eye irritation is possible (please see Eye contact
and Skin contact in section IV.) No special precautionary measures required under normal use
conditions.

Ventilation:

No special ventilation, precautions or respiratory protection is required during normal use. Largescale use indoors should provide an increased rate of air exchange.

Human Health
Effects or Risks
From Exposure:

Adverse effects on human health are not expected from Simple Green®, based on 20 years of use of
Simple Green® without reported adverse health incidence in diverse population groups, including
extensive use by inmates of U.S. Federal prisons in cleaning operations.

Eye protection:

Simple Green® is a mild eye irritant; mucous membranes may become irritated by concentrate. Eye
protection not generally required. Wash hands after using wipes.

Skin protection:

Simple Green® is not likely to irritate the skin in the majority of users. Repeated daily application to
the skin without rinsing, or continuous contact on the skin may lead to temporary, but reversible,
irritation. Rinse completely from skin after contact.

Material Safety Data Sheet: SIMPLE GREEN® ALL-PURPOSE CLEANER & SCRUBBING PAD

Pg 2 of 4

Material Safety Data Sheet:

Simple Green® All-Purpose Cleaner
Simple Green® Scrubbing Pad
Date of Issue: July 2007

Version No. 10013c

Section 8:

EXPOSURE CONTROLS/PERSONAL PROTECTION – continued –

General hygiene
conditions:

Section 9:

ANSI-Z400.1-2003 Format

There are no known hazards associated with this material when used as recommended.
The following general hygiene considerations are recognized as common good industrial hygiene
practices:
- Avoid breathing vapor or mist.
- Avoid contact with eyes.
- Wash thoroughly after handling and before eating, drinking, or smoking.

PHYSICAL AND CHEMICAL PROPERTIES

Appearance & Odor: Cleaner is a dark green liquid, pad is a fibrous green matrix; both exhibit a sassafras odor.
Specific Gravity:

1.020

Vapor Pressure:

18 mm Hg @ 20oC; 23.5 mmHg @ 26oC

Evaporation:

>1 (butyl acetate = 1)

Vapor Density:

1.3 (air = 1)

Water Solubility:

100%

Density:

8.5 lbs/gallon

pH:

9.35;

Boiling Point:
Ash Content:

o

o

100.6 C (212 F)

Safety Towel pH is 8.1 - 8.8

o

At 600 F: 1.86% by weight

Nutrient Content:
Phosphorus: 0.3% by formula
Approx -9 C (16 F)
Freezing Point:
Nitrogen <1.0% by weight (fusion and qualitative test for ammonia)
If product freezes, it will reconstitute without loss of efficacy
Sulfur: 0.6% by weight (barium chloride precipitation method)
when brought back to room temperature and agitated.
o
VOC Composite Partial Pressure: 0.006 mmHg @ 20 C
o

o

Volatile Organic Compounds (VOCs): Per EPA Method 24, VOC’s are 5.9%. Cleaner must be diluted at least 1 part
Simple Green to 2 parts water to meet CARB, and 1 part Simple Green to 3 parts water to meet SCAQMD Rule 1171 &
Rule 1122 and BAAQMD Regulation 8-16 VOC requirements for solvent cleaning operations. Towel VOCs are 1.2%.

Section 10: STABILITY AND REACTIVITY
Stability:
Materials to Avoid:
Hazardous Decomposition Products:

Stable
None known
None expected

Section 11: TOXICOLOGICAL INFORMATION
Nonhuman Toxicity (Data for Simple Green®)
Acute Toxicity:
Oral LD50 (rat): >5.0 g/kg body weight

Dermal LD50 (rabbit)

>2.0 g/kg body weight

Eye Irritation:

With or without rinsing with water, the irritation scores in rabbits at 24 hours did not exceed 15
(mild irritant) on a scale of 0-110.

Dermal Irritation:

Only mild, but reversible, irritation was found in a standard 72 hour test on rabbits. A value of 0.2
(non-irritating) was found on a scale of 0-8.

Subchronic Dermal
effects:

No adverse effects, except reversible dermal irritation, were found in rabbits exposed to Simple
Green (up to 2.0 g/kg/day for 13 weeks) applied to the skin of 25 males and 25 females. Only
female body weight gain was affected.

Fertility Assessment
by Continuous
Breeding:

The Simple Green® formulation had no adverse effect on fertility and reproduction in Cd-1 mice
with continuous administration for 18 weeks, and had no adverse effect on the reproductive
performance of their offspring.

Material Safety Data Sheet: SIMPLE GREEN® ALL-PURPOSE CLEANER & SCRUBBING PAD

Pg 3 of 4

Material Safety Data Sheet:
Version No. 10013c

Simple Green® All-Purpose Cleaner
Simple Green® Scrubbing Pad
Date of Issue: July 2007

ANSI-Z400.1-2003 Format

Section 12: ECOLOGICAL INFORMATION
Biodegradability: Simple Green® is readily decomposed by naturally occurring microorganisms. The biological oxygen
demand (BOD), as a percentage of the chemical oxygen demand (COD), after 4, 7, and 11 days was 56%, 60% and 70%,
respectively. Per OECD Closed Bottle Test, Simple Green® meets OECD and EPA recommendations for ready
biodegradability.
In a standard biodegradation test with soils from three different countries, Butyl Cellosolve reached 50% degradation in 6
to 23 days, depending upon soil type, and exceeded the rate of degradation for glucose which was used as a control for
comparison.
Environmental Toxicity Information: Simple Green® is considered practically non-toxic per EPA’s Aquatic toxicity
scale.

Section 13: DISPOSAL CONSIDERATIONS
Dispose of in accordance with all applicable local, state and federal laws. Dispose of used or unused product, and empty
containers in accordance with the local, State, Provincial, and Federal regulations for your location. Never dispose of used
degreasing rinsates into lakes, streams, and open bodies of water or storm drains.

Section 14: TRANSPORT INFORMATION
This product is non-hazardous for transport according to the U.S. Department of Transportation Services
UN Number: Not required
Dangerous Goods Class: Nonhazardous

Section 15: REGULATORY INFORMATION
All components are listed on:
*Reportable components:
RCRA Status:
TSCA TRI Reporting:

EINECS and TSCA Inventory
None.
No components listed under:
Not a hazardous waste.
CERCLA Status:
Not required / Not listed
CA PROP. 65 Status:

Clean Air Act Section 112
No components listed
No components listed

Section 16: OTHER INFORMATION
Questions about the information found on this MSDS should be directed to:
SUNSHINE MAKERS, INC. – TECHNICAL DEPARTMENT
15922 Pacific Coast Hwy. Huntington Harbour, CA 92649
Phone: 800/228-0709 [8am-5pm Pacific time, Mon-Fri]

Fax: 562/592-3830

National Stock Numbers & Industrial Numbers:
Simple Green

Scrubbing Pad

Part Number
13012
13005
13006
13016
13008
Part Number
10224

NSN
7930-01-342-5315
7930-01-306-8369
7930-01-342-5316
7930-01-342-5317
7930-01-342-4145
NSN
7930-01-346-9148

Email: infoweb@simplegreen.com
Retail Numbers:

Size
24 oz spray (12/case)
1 Gallon (6/case)
5 Gallon
15 Gallon
55 Gallon
Size
Each (24/case)

Part Number
13002
13005
13013
13014
13033

Size
16 oz Trigger (12/case)
1 Gallon (6/case)
24 oz Trigger (12/case)
67 oz / 2 L (6/case)
32 oz Trigger (12/case)

* part number is for both industrial and retail

**International Part Numbers May Differ.

DISCLAIMER: The information provided with this MSDS is furnished in good faith and without warranty of any kind. Personnel
handling this material must make independent determinations of the suitability and completeness of information from all sources to
assure proper use and disposal of this material and the safety and health of employees and customers. Sunshine Makers, Inc. assumes
no additional liability or responsibility resulting from the use of, or reliance on this information.

Material Safety Data Sheet: SIMPLE GREEN® ALL-PURPOSE CLEANER & SCRUBBING PAD

Pg 4 of 4

Page 1 of 4
Procter & Gamble
CPG TN 6
2 Procter & Gamble Plaza
Cincinnati, OH 45202

MATERIAL SAFETY DATA SHEET
Issue Date: 12/2005
Issue Date: 8/01

Supersedes: N/A

SECTION I - CHEMICAL PRODUCT
Identity: Granular Cleaner with Bleach
Brands: SPIC and SPAN Floor Cleaner with BLEACH (non-phosphate & phosphate)
Hazard Rating: 1
Health: 1
4=EXTREME
Flammability: 0
3=HIGH
Reactivity: 0
2= MODERATE
1=SLIGHT
Emergency Telephone Number: - 1-800-332-7787 or call Local Poison Control Center

SECTION II - COMPOSITION AND INGREDIENTS
Ingredients/Chemical Name: Anionic surfactants, water softeners (sodium carbonate, complex sodium phosphates
[phosphate version]), dry chlorine bleach, processing aids (sodium sulfate), metal
protection agents (sodium silicates).
This product is a mild eye irritant within the meaning of the OSHA Hazard Communication Standard
Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200 and/or WHMIS under the Hazardous Product Act.
Common
CAS No.
Recommended Limits
Composition LD50/LC50
Chemical Name
Name
Range
Sodium carbonate
Soda Ash 497-19-8
N/A
15-40% (OP)
LD50=1.86
10-25% (P)
g/kg
LC50=N/A
Sodium
2893-78-9
AGCY
OSHA
10-15%
LD50=735
Sodium
DCC
TLV
PEL
mg/kg rat
dichloroisocynanurate
10
mg/m3
15
mg/m3
dihydrate
C12.3 LAS 68081-81-2
15-30%
LD50=0.65Linear alkyl benzene
1.26 g/kg
sulfonate
N/A
LC50=N/A

SECTION III - HAZARDS IDENTIFICATION
Health Hazards & Symptoms (Acute and Chronic):
Ingestion:
May cause transient gastrointestinal irritation with nausea, vomiting and/or diarrhea.
Eye Contact:
May cause mild, transient irritation with stinging, tearing, itching,swelling and redness.
Inhalation:
Heavy or prolonged exposure to dust may cause transient respiratory tract irritation with
coughing, sore throat, wheezing or transitiory shortness of breath.

SPIC and SPAN Floor Cleaner with BLEACH (non-phosphate & phosphate) MSDS (Continued)
Page 2 of 4

SECTION IV - FIRST AID INFORMATION
Emergency and First Aid Procedures:
Ingestion:
Drink 1 or 2 large glasses of water. If large amounts are ingested, call a physician.
Eye Contact:
Flush with large amounts of water for at 10-15 minutes.
Skin:
Rinse skin thoroughly with water. Discontinue use.
Inhalation:
Leave dusty area.
Other: Product package has a caution statement: CAUTION:. May cause eye/skin irritation. Eye irritant. Avoid eye
contact. Do not mix with other cleaning products as irritating fumes may be released. May be irritating to skin.
For sensitive skin or prolonged use, wear gloves. If eye or skin contact occurs, flush with water for 15 minutes.
If irritation persists, seek medical attention. KEEP OUT OF REACH OF CHILDREN

SECTION V - FIRE FIGHTING INFORMATION
Flash Point (Method Used): N/A

Explosive Limits: LEL: N/A

UEL: N/A

Extinguishing Media: CO2 , water, or dry chemical
Special Fire Fighting Procedures: None known.
Unusual Fire Hazards : N/A

SECTION VI - ACCIDENTAL RELEASE MEASURES
Personal Precautions: None
Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL, PROVINCIAL AND LOCAL REGULATIONS. Solutions may be disposed of in sewer. Dry product may be landfilled if
permitted by local regulations. Discard empty container in trash.
Steps To Be Taken in Case Material is Released or Spilled: Dispose as dry scrap or flush small quantities down
acceptable sewer (contains biodegradable surfactants). Dispose of according to local regulations. Prevent heavy
exposure to dust with NIOSH approved dust mask.

SECTION VII - HANDLING AND STORAGE
Precautions To Be Taken in Handling and Storing: Store in a cool, dry place. Keep product dry to maintain freeflowing granules.
Other Precautions: None

SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION
Respiratory Protection (Specify Type): None required with normal use.
Ventilation
Local Exhaust: None required with normal use.
Special: None
Mechanical (General): Acceptable.
Other: None
Eye Protection: None required with normal use.
Manufacturing Setting: With dusty conditions or if a splash is likely, chemical goggles may be needed.
Protective Gloves: None required with normal use.
Manufacturing Setting: Protective gloves (rubber, neoprene) should be used for any prolonged direct contact.
Other Protective Equipment: None required with normal use.

2

SPIC and SPAN Floor Cleaner with BLEACH (non-phosphate & phosphate) MSDS (Continued)
Page 3 of 4
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point ° F: N/A

Specific Gravity (H2 O=1): N/A

Vapor Pressure (mm Hg): N/A

Percent Volatile by Volume (%): N/A

Vapor Density (Air=1): N/A

Evaporation Rate (nBuOAc=1): N/A

Odor Threshold: N/A

Freezing Point: N/A

Coefficient of Water/Oil Distribution: N/A

pH (1% solution): ~10.9

Scooped Density: 0.4/cc (bulk density)

Solubility in Water: Mostly

Appearance and Odor: White granule with green specks
and bland odor

Reserve Alkalinity: 4.0 max

SECTION X - STABILITY AND REACTIVITY
Possible Hazardous Reactions/Conditions: None known
Conditions to Avoid: None
Materials to Avoid: Products which contain ammonia or are acidic
Hazardous Decomposition Products: Chlorine gas
Other Recommendations: None
Stability:

Stable

Hazardous Polymerization:

Will not occur

SECTION XI - TOXICOLOGICAL INFORMATION
LD50 (rats oral): 2.9g/kg

SECTION XII - ECOLOGICAL INFORMATION
None

SECTION XIII - DISPOSAL CONSIDERATIONS
Waste Disposal Method: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH FEDERAL, PROVINCIAL
AND LOCAL REGULATIONS. Small quantities may be disposed of in sewer. Dry product may be landfilled. Discard
empty container in trash.

SECTION XIV - TRANSPORT INFORMATION
DOT Classification: The finished product is not DOT hazardous.

3

SPIC and SPAN Floor Cleaner with BLEACH (non-phosphate & phosphate) MSDS (Continued)
Page 4 of 4
SECTION XV - ADDITIONAL REGULATORY INFORMATION
All components are listed on the US TSCA Inventory. No components are affected by Significant New Use Rules
(SNURs) under TSCA §5.
No components of Spic and Span with Bleach are subject to California Proposition 65.
All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified with
Hazard Criteria of the Canadian Control Products Regulation (CPR) and this MSDS contains all information required
by the Canadian Products Regulation.

*N/A. - Not Applicable

SECTION XVI - OTHER INFORMATION
*N/K. - Not Known

The submission of this MSDS may be required by law, but this is not an assertion that the substance is hazardous
when used in accordance with proper safety practices and normal handling procedures. Data supplied is for use
only in connection with occupational safety and health.
The information contained herein has been compiled from sources considered by Procter & Gamble to be
dependable and is accurate to the best of the Company’s knowledge. The information relates to the specific material
designated herein, and does not relate to the use in combination with any other material or any other process.
Procter & Gamble assumed no responsibility for injury to the recipient or third persons, for any damage to any
property resulting from misuse of the controlled product.

4

Page 1 de 4
Procter & Gamble
CPG TN 6
2, Procter & Gamble Plaza
Cincinnati (Ohio) 45202

FICHE SIGNALÉTIQUE

Date de publication : 12-2005
Date de publication : 8-01

Remplace : S.O.

SECTION 1 – IDENTIFICATION DU PRODUIT
Identification : Nettoyant granulaire avec javellisant
Marques : Nettoyant avec JAVELLISANT pour planchers SPIC and SPAN (sans phosphate et avec phosphate)
Évaluation du danger : 1
Santé : 1
4 = EXTRÊME
Inflammabilité : 0
3 = ÉLEVÉ
Réactivité : 0
2 = MODÉRÉ
1 = LÉGER
Numéro de téléphone en cas d’urgence : 1 800 332-7787 ou appelez le centre antipoison de votre localité.

SECTION II – COMPOSITION ET INGRÉDIENTS
Ingrédients/Nom chimique : Agents de surface anioniques, adoucisseurs d’eau (carbonate de sodium, complexe de
phosphates sodiques [version avec phosphate]), produit à blanchir au chlore en poudre,
agent technologique [sulfate de sodium], agent de protection contre les particules
métalliques [silicate de sodium])
Ce produit est un irritant oculaire léger en vertu de la norme de communication de la Occupational Safety and Health
Administration (OSHA).
Ingrédients dangereux tels que définis par la OSHA, 29 CFR 1910.1200 et/ou la SIMDUT en vertu de la Loi
sur les produits dangereux.
No de CAS
Limites recommandées
Écart de la
DL50/CL50
Nom chimique Nom commun
composition
chimique
Carbonate de
Bicarbonate de 497-19-8
S.O.
15 à 40 % DL50=1,86
g/kg
sodium
soude
(O.P.)
10 à 25 % CL50 = S.O.
(PHOSPHO
RE)

Dichloroisocyanur
ate de sodium
dihydraté

Sodium DCC

2893-78-9

AGCY VLE

10 à 15 %

DL50=735
mg/kg chez
le rat

15 à 30 %

DL50=0,651,26 g/kg
CL50 = S.O.

10 mg/m3
OSHA PEL
15mg/m3

Alkyl benzène
sulfonate
linéaire

alkylsulfonate
linéaire

68081-81-2

S.O.

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SECTION III – IDENTIFICATION DES DANGERS
Dangers pour la santé (aigus et chroniques) :
Ingestion : L’ingestion du produit peut causer une irritation gastro-intestinale passagère provoquant nausées,
vomissements et/ou diarrhée.
Contact avec les yeux : Peut causer une irritation passagère légère accompagnée d’une sensation de brûlure, des
larmoiements, un prurit, de l’œdème et des rougeurs.
Inhalation : L’exposition intense ou prolongée à la poussière du produit peut causer une irritation passagère des
voies respiratoires accompagnée de toux, de maux de gorge, de sifflement ou de dyspnée
passagère.

SECTION IV – PREMIERS SOINS
Procédures d’urgence et de premiers soins :
Ingestion : Boire un ou deux grands verres d’eau. Si une quantité importante de produit est ingérée,
consultez un médecin.
Contact avec les yeux : Rincer à grande eau pendant au moins 10 à 15 minutes.
Peau : Rincez abondamment avec de l’eau. Cesser l’emploi.
Inhalation : Quitter le lieu empoussiéré.
Autre : L’emballage du produit comporte un énoncé de risques : MISE EN GARDE : Peut causer une irritation des
yeux/de la peau. Irritant oculaire : Éviter le contact avec les yeux. Ne pas mélanger avec d’autres produits
nettoyants puisque des vapeurs irritantes pourraient être émises. Peut être irritant pour la peau. En cas de
peau sensible ou de contact prolongé, le port de gants est recommandé. Dans le cas d’un contact avec les
yeux ou la peau, rincer à grande eau pendant au moins 15 minutes. Si l’irritation persiste, consulter un
médecin. TENIR HORS DE LA PORTÉE DES ENFANTS.
SECTION – RENSEIGNEMENTS CONCERNANT LES MOYENS D’EXTINCTION
Point d’éclair (méthode utilisée) : S.O.

Limites d’explosion :

LIE : S.O.

LES : S.O.

Moyens d’extinction : CO2, eau ou poudre extinctrice
Procédures spéciales d’extinction : Aucune connue
Risques d’incendie inhabituels : S.O.

SECTION VI – MESURES À PRENDRE EN CAS DE DÉVERSEMENT ACCIDENTEL
Précautions personnelles : S.O.
Précautions environnementales : ÉLIMINER CONFORMÉMENT AUX RÈGLEMENTS FÉDÉRAUX,
PROVINCIAUX ET LOCAUX. Les solutions domestiques peuvent être évacuées dans l’égout. Le produit sec peut
être enfoui si les règlements locaux le permettent. Jeter les contenants vides dans la poubelle.
Mesures à prendre en cas de fuite ou de déversement : Les petites quantités peuvent être progressivement
évacuées dans les égouts appropriés (contient des surfactifs biodégradables). Éliminer conformément aux règlements
applicables. Prévenir l’exposition intense à la poussière au moyen d’un appareil respiratoire approuvé par le
NIOSH.

2

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SECTION VII – MANUTENTION ET ENTREPOSAGE
Précautions à prendre pour la manutention et l’entreposage : Entreposer dans un lieu frais et sec. Éviter
l’humidité pour éviter que les granules ne s’agglomèrent.
Autres précautions : Aucune
SECTION VIII – PROTECTION PERSONNELLE ET CONTRÔLE DE L’EXPOSITION AU PRODUIT
Protection des voies respiratoires (spécifier le type) : Aucune dans des conditions normales d’utilisation.
Ventilation :
Ventilation par aspiration à la source : Aucune dans des conditions normales d’utilisation..
Spéciale : Aucune
Mécanique (générale) : Acceptable.
Autre : Aucune
Protection des yeux : Non requise à l’usage normal.
Industrie manufacturière : Dans des conditions poussiéreuses ou si une éclaboussure est probable, des lunettes
protectrices contre les agents chimiques pourraient s’avérer nécessaires.
Gants de protection : Non requis à l’usage normal.
Industrie manufacturière : Des gants de protection (caoutchouc, néoprène) s’imposent dans le cas des contacts
directs prolongés.
Autre équipement de protection : Non requis à l’usage normal.

SECTION IX – PROPRIÉTÉS PHYSIQUES ET CHIMIQUES
Point d’ébullition (°°F) : S.O.

Densité (H2O=1) : S.O.

Tension de vapeur (mm Hg) : S.O.

Pourcentage volatile au volume (%) : S.O.

Densité de vapeur (Air=1) : S.O.

Taux d’évaporation (nBuOAc=1) : S.O.

Seuil de l’odeur : S.O.

Point de congélation : S.O.

Coefficient de répartition eau-huile : S.O.

pH (solution 1 %) : environ10,9

Densité volumique : 0,4/en vase fermé (densité
apparente)

Solubilité dans l’eau : Importante

Apparence et odeur : Poudre blanche avec granules
verts à la senteur neutre

Alcalinité : 4,0 max

SECTION X – STABILITÉ ET RÉACTIVITÉ
Réactions/conditions dangereuses possibles : Aucune connue
Conditions à éviter : Aucune
Matériaux à éviter : Produits contenant de l’ammoniaque et acides
Produits de décomposition dangereux : Chlore gazeux
Autres recommandations : Aucune
Stabilité chimique : Stable
Polymérisation dangereuse : Impossible

3

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SECTION XI – PROPRIÉTÉS TOXICOLOGIQUES
DL50 (ingestion chez le rat) : 2,9 g/kg

SECTION XII – INFORMATION ÉCOLOGIQUE
Aucune.

SECTION XIII – RÈGLEMENTS CONCERNANT L’ÉLIMINATION
Méthode d’élimination : ÉLIMINER CONFORMÉMENT AUX RÈGLEMENTS FÉDÉRAUX, PROVINCIAUX
ET LOCAUX. Les petites quantités peuvent être évacuées dans l’égout. Le produit sec peut être enfoui. Jeter les
contenants vides dans la poubelle.

SECTION XIV – INFORMATION CONCERNANT LE TRANSPORT
Classification DOT : Le produit fini est non-toxique selon le ministère des Transports (DOT).

SECTION XV – RENSEIGNEMENTS SUPPLÉMENTAIRES SUR LA RÈGLEMENTATION
Toutes les composantes figurent sur l’inventaire du TSCA. Les règles de la nouvelle utilisation importante ne
modifie en aucun cas les composantes conformément à l’inventaire du TSCA §5.
Aucune des composantes du nettoyant avec javellisant Spic and Span n’est assujettie à la proposition 65 de la
Californie.
Tous les ingrédients ont été approuvés par la LCPE et peuvent être importés au Canada par Procter & Gamble. Ce
produit a été classé sous la catégorie Critères de risque du règlement canadien régissant les produits contrôlés et
cette fiche signalétique contient toute l’information requise par ledit règlement.

*S.O. - Sans objet

SECTION XVI – AUTRES RENSEIGNEMENTS
*INC. - Inconnu

La présentation de cette fiche signalétique est requise par la loi, mais ce n’est pas une affirmation que la substance
est dangereuse lorsque celle-ci est utilisée en respectant les bonnes règles de sécurité et les méthodes de
manutention normales. Les données fournies ne peuvent être utilisées que dans le cadre de la sécurité et de la santé
au travail.
Les renseignements de la présente fiche ont été compilés à partir de sources considérées comme fiables par la
société Procter & Gamble, et sont exacts à sa connaissance. Ces renseignements ne concernent que la matière
désignée par la présente fiche et non son utilisation en combinaison avec toute autre matière ou tout autre procédé.
Procter & Gamble n’est pas responsable des blessures infligées au destinataire ou à une tierce personne, ni d’aucun
dommage à la propriété résultant d’une utilisation incorrecte de produit contrôlé.

4

MATERIAL SAFETY DATA SHEET
SECTION 1. PRODUCT/MANUFACTURER'S IDENTITY
PRODUCT NAME: OVEN & GRILL CLEANER

PRODUCT I.D. NUMBER (PIN): 1719

PRODUCT NUMBER: 02806FS
PRODUCT USE: Oven and grill cleaner

WHMIS CLASS:

3
0
1
C

DOT HAZARD CLASS: Corrosive Material

COMPANY:
Essential Industries, Inc.
P.O. Box 12
Merton, WI 53056-0012
EMERGENCY PHONE:

H.M.I.S.

E; D2B

DOT SHIPPING NAME:
Caustic Alkali Liquid, N.O.S.
(Potassium hydroxide, Sodium metasilicate)
8, UN1719, PGIII

800-843-6174

HEALTH

HAZARD RATING

FIRE

4 = Extreme
3 = High
2 = Moderate
1 = Slight
0 = Insignificant

REACTIVITY
MAXIMUM PERSONAL
PROTECTION

A = Goggles B = Goggles & Gloves C = Goggles, Gloves & Apron

ABBREVIATION KEY: N.A. - Not Applicable N.E. = Not Established N.D. = Not Determined

SECTION 2 - HAZARDOUS INGREDIENTS INFORMATION
%
60-100
5-10
1-5
10-30

CAS NO.
7732-18-5
1310-58-3
6834-92-0
N.A.

HAZARDOUS CHEMICAL IDENTITY
Water
Potassium hydroxide
Sodium metasilicate
Surfactants

PEL
N.E.
2mg/m3
2mg/m3
N.E.

TLV
N.E.
2mg/m3
2mg/m3
N.E.

LD50
N.D.
365mg/kg
847mg/kg
N.D.

LC50
N.D.
N.D.
N.D.
N.D.

This mixture does not contain components which are subject to the reporting requiements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of
1986 and 40 CFR, Part 372.

SECTION 3 - PHYSICAL DATA
Color:

Boiling Point:

Purple

Odor: Bland
Physical State:

Liquid

Solubility in Water:

Complete

pH: 13.0 - 14.0

Vapor Pressure: <30 mm of Hg

100°C (212°F)
Freezing Point: 0°C (32°F)
Water/Oil Distribution: N.E.

Vapor Density (Air=1): <1
Evaporation Rate (Water=1):

Odor Threshold:

VOC Content:

N.E.

1% pH: 11.8

N.E.

0.0%

Specific Gravity: 1.10 gm/ml
Weight per Gallon: 9.19 lbs./gal.

SECTION 4 - FIRE AND EXPLOSION HAZARD DATA
Flash Point and Method: N.A.

Autoignition Temperature: N.A.

Extinguishing Media:

Flammable Limits: N.A.

LEL: N.A.

Special Fire Fighting Procedures:

UEL: N.A.

Use dry chemical or CO2.
Use proper protective equipment.

Unusual Fire and Explosion Hazards:

Hazardous Combustion Products: N.A.

None.

SECTION 5 - REACTIVITY DATA
Chemical Stability:

Hazardous decomposition of By-Products: None known.

Stable.

Incompatibility (Materials to Avoid):

Acids, aluminum and other soft metals.

Hazardous Polymerization: Will not occur.

SECTION 6 - TOXICOLOGICAL PROPERTIES
Routes of Entry:
Sensitization:

Toxicologically Synergistic Products:

Ingestion. Inhalation. Skin contact. Eye contact.

None known.

Medical Conditions Aggravated by Exposure:

No.

None known.

EFFECTS OF OVEREXPOSURE (Acute and/or Chronic):
Eyes: May cause severe irritation, redness, burns and possible corneal injury.

Carcinogenic Effects:

NO carcinogenic effect.

Skin: May cause severe irritation, redness, burns.

Mutagenic Effects:

NO mutagenic effect.

Ingestion: May cause severe irritation or burning of gastrointestinal tract and possible mucosal Teratogenic Effects: NO teratogenic effect.
injury.

Reproductive Toxicity:

Inhalation: May irritate respiratory tract when used with inadequate ventilation.

NO reproductive toxicity effect.

SECTION 7 - PREVENTATIVE AND CONTROL MEASURES
Respiratory Protection:

None normally required with adequate ventilation.
Protective Gloves: Rubber/Neoprene.
Protective Clothing and Equipment:
Full cover clothing - rubber apron.
Storage Requirements: Store in cool, dry area. Follow good housekeeping
practices.
Steps to be Taken if Material
is Spilled or Released:
Waste Disposal:

Ventilation:

Local Exhaust: Acceptable Mechanical: Recommended

Eye Protection: Chemical splash goggles.
Work and Hygienic
Practices:

After handling, always wash hands thoroughly with soap
and water.

Other Requirements:

Keep out of reach of children.

Collect and reuse if possible. Dilute and flush to sewer with large quantities of water if permitted by regulatory authorities or absorb on inert
material (sand, clay, etc.) and place into container for proper disposal. Do not allow runoff into public waterways.

Dispose of as permitted by all federal, provincial, state and local regulatory authorities.

SECTION 8 - EMERGENCY FIRST AID PROCEDURES
FIRST AID - NOTES TO PHYSICIAN:
Eyes: Flush with a large amount of water for 30 minutes holding eyelids open. Seek medical attention.
Skin: Remove contaminated clothing and footwear. Flood/shower with water for 30 minutes.
Ingestion: Rinse mouth with water. Give 2-3 large glasses of water. Do not induce vomiting. Seek medical attention.
Inhalation:Remove to fresh air and rest. In all cases if symptoms persist, seek medical attention.
Note to Physician:

No additional information.

SECTION 9 - PREPARATION INFORMATION
Prepared By:

Regulatory Affairs Department

Phone:

262-538-1122

Date of Preparation:

1/1/2005.

MATERIAL SAFETY DATA SHEET
SECTION 1. PRODUCT/MANUFACTURER'S IDENTITY
PRODUCT NAME: OVEN & GRILL CLEANER

PRODUCT I.D. NUMBER (PIN): 1719

PRODUCT NUMBER: 02806FS
PRODUCT USE: Oven and grill cleaner

WHMIS CLASS:

3
0
1
C

DOT HAZARD CLASS: Corrosive Material

COMPANY:
Essential Industries, Inc.
P.O. Box 12
Merton, WI 53056-0012
EMERGENCY PHONE:

H.M.I.S.

E; D2B

DOT SHIPPING NAME:
Caustic Alkali Liquid, N.O.S.
(Potassium hydroxide, Sodium metasilicate)
8, UN1719, PGIII

800-843-6174

HEALTH

HAZARD RATING

FIRE

4 = Extreme
3 = High
2 = Moderate
1 = Slight
0 = Insignificant

REACTIVITY
MAXIMUM PERSONAL
PROTECTION

A = Goggles B = Goggles & Gloves C = Goggles, Gloves & Apron

ABBREVIATION KEY: N.A. - Not Applicable N.E. = Not Established N.D. = Not Determined

SECTION 2 - HAZARDOUS INGREDIENTS INFORMATION
%
60-100
5-10
1-5
10-30

CAS NO.
7732-18-5
1310-58-3
6834-92-0
N.A.

HAZARDOUS CHEMICAL IDENTITY
Water
Potassium hydroxide
Sodium metasilicate
Surfactants

PEL
N.E.
2mg/m3
2mg/m3
N.E.

TLV
N.E.
2mg/m3
2mg/m3
N.E.

LD50
N.D.
365mg/kg
847mg/kg
N.D.

LC50
N.D.
N.D.
N.D.
N.D.

This mixture does not contain components which are subject to the reporting requiements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of
1986 and 40 CFR, Part 372.

SECTION 3 - PHYSICAL DATA
Color:

Boiling Point:

Purple

Odor: Bland
Physical State:

Liquid

Solubility in Water:

Complete

pH: 13.0 - 14.0

Vapor Pressure: <30 mm of Hg

100°C (212°F)
Freezing Point: 0°C (32°F)
Water/Oil Distribution: N.E.

Vapor Density (Air=1): <1
Evaporation Rate (Water=1):

Odor Threshold:

VOC Content:

N.E.

1% pH: 11.8

N.E.

0.0%

Specific Gravity: 1.10 gm/ml
Weight per Gallon: 9.19 lbs./gal.

SECTION 4 - FIRE AND EXPLOSION HAZARD DATA
Flash Point and Method: N.A.

Autoignition Temperature: N.A.

Extinguishing Media:

Flammable Limits: N.A.

LEL: N.A.

Special Fire Fighting Procedures:

UEL: N.A.

Use dry chemical or CO2.
Use proper protective equipment.

Unusual Fire and Explosion Hazards:

Hazardous Combustion Products: N.A.

None.

SECTION 5 - REACTIVITY DATA
Chemical Stability:

Hazardous decomposition of By-Products: None known.

Stable.

Incompatibility (Materials to Avoid):

Acids, aluminum and other soft metals.

Hazardous Polymerization: Will not occur.

SECTION 6 - TOXICOLOGICAL PROPERTIES
Routes of Entry:
Sensitization:

Toxicologically Synergistic Products:

Ingestion. Inhalation. Skin contact. Eye contact.

None known.

Medical Conditions Aggravated by Exposure:

No.

None known.

EFFECTS OF OVEREXPOSURE (Acute and/or Chronic):
Eyes: May cause severe irritation, redness, burns and possible corneal injury.

Carcinogenic Effects:

NO carcinogenic effect.

Skin: May cause severe irritation, redness, burns.

Mutagenic Effects:

NO mutagenic effect.

Ingestion: May cause severe irritation or burning of gastrointestinal tract and possible mucosal Teratogenic Effects: NO teratogenic effect.
injury.

Reproductive Toxicity:

Inhalation: May irritate respiratory tract when used with inadequate ventilation.

NO reproductive toxicity effect.

SECTION 7 - PREVENTATIVE AND CONTROL MEASURES
Respiratory Protection:

None normally required with adequate ventilation.
Protective Gloves: Rubber/Neoprene.
Protective Clothing and Equipment:
Full cover clothing - rubber apron.
Storage Requirements: Store in cool, dry area. Follow good housekeeping
practices.
Steps to be Taken if Material
is Spilled or Released:
Waste Disposal:

Ventilation:

Local Exhaust: Acceptable Mechanical: Recommended

Eye Protection: Chemical splash goggles.
Work and Hygienic
Practices:

After handling, always wash hands thoroughly with soap
and water.

Other Requirements:

Keep out of reach of children.

Collect and reuse if possible. Dilute and flush to sewer with large quantities of water if permitted by regulatory authorities or absorb on inert
material (sand, clay, etc.) and place into container for proper disposal. Do not allow runoff into public waterways.

Dispose of as permitted by all federal, provincial, state and local regulatory authorities.

SECTION 8 - EMERGENCY FIRST AID PROCEDURES
FIRST AID - NOTES TO PHYSICIAN:
Eyes: Flush with a large amount of water for 30 minutes holding eyelids open. Seek medical attention.
Skin: Remove contaminated clothing and footwear. Flood/shower with water for 30 minutes.
Ingestion: Rinse mouth with water. Give 2-3 large glasses of water. Do not induce vomiting. Seek medical attention.
Inhalation:Remove to fresh air and rest. In all cases if symptoms persist, seek medical attention.
Note to Physician:

No additional information.

SECTION 9 - PREPARATION INFORMATION
Prepared By:

Regulatory Affairs Department

Phone:

262-538-1122

Date of Preparation:

1/1/2005.

MATERIAL SAFETY DATA SHEET
SECTION I - PRODUCT IDENTIFICATION AND USE
Product Name

Softsoap Liquid Hand Soap

Supplier’s Name

Colgate-Palmolive Canada Inc.

Telephone No.:

(416) 421-6000

Product Use
Address:

Liquid Hand Soap

NCP

Whmis Classification:

Two Morneau Sobeco Centre, 6th Floor
895 Don Mills Road, Toronto, Ontario M3C 1W3
Check your local Poison Control Centre in your
telephone white pages.

Emergency Contacts:

SECTION II - PREPARATION OF MSDS
PREPARED BY:

Technical Services

N/A = Not Applicable;

PHONE:

(416) 421-6000

DATE:

January 1, 2007

N/E = Not Established/Available

SECTION III - HAZARDOUS INGREDIENTS
Hazardous Ingredient

Concentration
Range %

C.A.S. or U.N.
Number

Exposure Limits

LD50/LC50 Specify Species and Route

N/A

SECTION IV - PHYSICAL DATA
Physical State
Liquid

Odour and Appearance
Various scents and colours

Vapour Density
N/E

Evaporation Rate
N/E

Odour Threshold
N/E

Boiling Point
N/E

Freezing Point
N/E

Specific Gravity
1.07(20°/20° C)

pH
6.0 - 6.5

Vapour Pressure
N/E

Coefficient of Water/Oil Distribution
N/E

SECTION V - FIRE OR EXPLOSION HAZARD
Flammable:

Yes

( )

No

(X)

If yes, under which conditions:

If involved in fire, use water, dry alcohol type or all purpose foam, dry chemical, carbon dioxide or other Class B extinguishing agents.

Means of Extinction:

Flashpoint and Method
N/E

Upper Flammable Limit
N/E

Hazardous Combustion Products:
Explosion Data Sensitivity
To Mechanical Impact

Lower Flammable Limit
N/E

Auto-ignition Temperature
N/E

Carbon Monoxide, Sulphur Dioxide, Oxides of Nitrogen

N/E

Explosion Data Sensitivity
To Static Charge

N/E

SECTION VI - REACTIVITY DATA
Chemical
Instability:

Yes

( )

No

(X)

If yes, under which conditions?

Incompatibility To
Other Substances:

Yes

( )

No

(X)

If yes, which ones?

Reactivity:

Yes

( )

No

(X)

If yes, under which conditions?

Hazardous Decomposition Products:

None known

SECTION VII - TOXICOLOGICAL PROPERTIES OF PRODUCT This product has not been tested as a whole.
Routes of Entry:

Skin Contact

X

Skin Absorption

Eye Contact

X

Inhalation

Effects of Acute Exposure To Product:
Skin Contact:

No evidence of dermal toxicity

Skin Absorption

N/A

Eye Contact:

Contact with eye can produce conjunctival irritation.

Inhalation:

N/A

Ingestion:

May cause vomiting with persistant, unpleasant aftertaste.

Ingestion

X

MATERIAL SAFETY DATA SHEET
Product Name

Softsoap Liquid Hand Soap

SECTION VII - TOXICOLOGICAL PROPERTIES OF PRODUCT This product has not been tested as a whole.
Effects of Chronic Exposure To Product:

N/E

LD50 of Product (Specify Species and Route)

N/E

Exposure Limits
N/E

LC50 of Product (Specify Species)

N/A

Irritancy of Product
N/E

Sensitization of Product
N/E

Carcinogenicity
N/E

Teratogenicity
N/E

Mutagenicity
N/E

Synergistic Materials
N/E

Reproductive Toxicity
N/E

SECTION VIII - PREVENTATIVE MEASURES
Personal Protective Equipment:

Rubber or Plastic Gloves, Goggles or Safety Glasses, Protective Clothing

Engineering Controls:

Safety Showers and Eyewash Fountains should be available. The product should be used in a well ventilated area.

Leak and Spill Procedures:

Rinse with water

Waste Disposal:

Dispose in accordance with Federal, Provincial and Local regulations.

Handling Procedures and
Equipment:

Follow routine safe handling procedures. Avoid contact when handling.

Storage Requirements:

Store in suitably labeled containers. Keep containers tightly closed. Protect from damage. Store in a cool, dry, well-ventilated area,
out of direct sunlight.

Special Shipping Instruction:

None

SECTION IX - TRANSPORTATION OF DANGEROUS GOODS
TDG Regulated Product:

PIN Number:

Yes

( )

No

N/A

(X)

Product TDG or CFR 49 Shipping Name
(If CFR so indicate)
Packaging Group

N/A

N/A

SECTION X - FIRST AID MEASURES
Skin:

Flush the contact area well with lukewarm running water for at least 15 minutes. If irritation persists, call a physician.

Eye:

Flush the contaminated eye(s) for at least 15 minutes with lukewarm water, holding the eyelid open. Take care not to rinse contaminated water into
the non-affected eye. Always seek medical attention for eye injuries.

Inhalation:

N/A

Ingestion:

If swallowed drink 3 - 4 glasses of water. DO NOT INDUCE VOMITING. Call a physician.

This product is labeled in accordance with the requirements of the Hazardous Products Act and/or the Pest Control Products Act in that the use pattern and exposure in
the workplace is generally consistent with that experienced by consumers. In certain respects, the requirements of the Workplace Hazardous Materials Information
System applicable to the drafting of this Material Safety Data Sheet may differ from the requirements of those acts and regulations and as a result, this MSDS may
contain additional information to that found on the label.
Because we cannot anticipate or control the many different conditions under which this information and our products may be used, we do not guarantee the applicability
of this information or the suitability of our products in any given situation. Users of our products should make their own tests to determine the safety and suitability of
each such product for their particular purposes.

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name:
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

FORMULA 491705
MANGO
ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Acetone
Propane
Isobutane
n-Butane
Fragrance

CAS No.:
67-64-1
74-98-6
75-28-5
106-97-8
Not available

TLV:
500ppm
2500ppm
Not established
800ppm
Not available

______________________________________________________________________________

SECTION 3
Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA
<0 to 1330 F
Slightly
Clear/mango scent

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5
Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.

First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________

SECTION 9

SPILL OR LEAK PROCEDURE

Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None

__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491705

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name:
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

FORMULA 491655
TROPICAL NECTAR
ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Acetone
Propane
Isobutane
n-Butane
Fragrance

CAS No.:
67-64-1
74-98-6
75-28-5
106-97-8
Not available

TLV:
500ppm
2500ppm
Not established
800ppm
Not available

______________________________________________________________________________

SECTION 3
Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA
<0 to 1330 F
Slightly
Clear/tropical scent

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5
Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.

First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________

SECTION 9

SPILL OR LEAK PROCEDURE

Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None

__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491655

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name:
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

FORMULA 491805
PEACH KIWI
ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Acetone
Propane
Isobutane
n-Butane
Fragrance

CAS No.:
67-64-1
74-98-6
75-28-5
106-97-8
Not available

TLV:
500ppm
2500ppm
Not established
800ppm
Not available

______________________________________________________________________________

SECTION 3
Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA
<0 to 1330 F
Slightly
Clear/peach kiwi scent

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5
Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.

First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________

SECTION 9

SPILL OR LEAK PROCEDURE

Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None

__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491805

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name: NEUTRAZEN Natural Scents
491153 Cinnamon
491105 Citrus Creme
491325 Citrus Peel
491235 Cranberry Spice
491123 Fresh Linen
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

(Hand Held Cans)
491075 Fruit Basket
491255 Green Apple
491455 Mango
491155 Orchard Spice
491405 Peach Kiwi

491355 Pina Colada
491305 Powder Fresh
491055 Tropical Nectar
491205 Vanilla Delight

ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Dimethyl Ketal
Isobutane
Propane
Butane
Fragrance

CAS No.:
67-64-1
75-28-5
74-98-6
106-97-8
Not available

TLV:
500ppm
Not established
2500ppm
800ppm
Not available

______________________________________________________________________________

SECTION 3

Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA

<0 to 1330 F
Slightly
Clear

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5

Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.
First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

SECTION 9

SPILL OR LEAK PROCEDURE

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________
Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None
__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491153,491105,491325,491235,491123,491075,491255,491455,491155,491405,491355,491305,491055, 491205

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name: NEUTRAZEN Natural Scents
491153 Cinnamon
491105 Citrus Creme
491325 Citrus Peel
491235 Cranberry Spice
491123 Fresh Linen
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

(Hand Held Cans)
491075 Fruit Basket
491255 Green Apple
491455 Mango
491155 Orchard Spice
491405 Peach Kiwi

491355 Pina Colada
491305 Powder Fresh
491055 Tropical Nectar
491205 Vanilla Delight

ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Dimethyl Ketal
Isobutane
Propane
Butane
Fragrance

CAS No.:
67-64-1
75-28-5
74-98-6
106-97-8
Not available

TLV:
500ppm
Not established
2500ppm
800ppm
Not available

______________________________________________________________________________

SECTION 3

Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA

<0 to 1330 F
Slightly
Clear

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5

Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.
First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

SECTION 9

SPILL OR LEAK PROCEDURE

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________
Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None
__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491153,491105,491325,491235,491123,491075,491255,491455,491155,491405,491355,491305,491055, 491205

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name: NEUTRAZEN Natural Scents
491153 Cinnamon
491105 Citrus Creme
491325 Citrus Peel
491235 Cranberry Spice
491123 Fresh Linen
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

(Hand Held Cans)
491075 Fruit Basket
491255 Green Apple
491455 Mango
491155 Orchard Spice
491405 Peach Kiwi

491355 Pina Colada
491305 Powder Fresh
491055 Tropical Nectar
491205 Vanilla Delight

ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Dimethyl Ketal
Isobutane
Propane
Butane
Fragrance

CAS No.:
67-64-1
75-28-5
74-98-6
106-97-8
Not available

TLV:
500ppm
Not established
2500ppm
800ppm
Not available

______________________________________________________________________________

SECTION 3

Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA

<0 to 1330 F
Slightly
Clear

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5

Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.
First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

SECTION 9

SPILL OR LEAK PROCEDURE

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________
Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None
__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491153,491105,491325,491235,491123,491075,491255,491455,491155,491405,491355,491305,491055, 491205

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name: NEUTRAZEN Natural Scents
491153 Cinnamon
491105 Citrus Creme
491325 Citrus Peel
491235 Cranberry Spice
491123 Fresh Linen
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

(Hand Held Cans)
491075 Fruit Basket
491255 Green Apple
491455 Mango
491155 Orchard Spice
491405 Peach Kiwi

491355 Pina Colada
491305 Powder Fresh
491055 Tropical Nectar
491205 Vanilla Delight

ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Dimethyl Ketal
Isobutane
Propane
Butane
Fragrance

CAS No.:
67-64-1
75-28-5
74-98-6
106-97-8
Not available

TLV:
500ppm
Not established
2500ppm
800ppm
Not available

______________________________________________________________________________

SECTION 3

Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA

<0 to 1330 F
Slightly
Clear

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5

Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.
First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

SECTION 9

SPILL OR LEAK PROCEDURE

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________
Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None
__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491153,491105,491325,491235,491123,491075,491255,491455,491155,491405,491355,491305,491055, 491205

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name: NEUTRAZEN Natural Scents
491153 Cinnamon
491105 Citrus Creme
491325 Citrus Peel
491235 Cranberry Spice
491123 Fresh Linen
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

(Hand Held Cans)
491075 Fruit Basket
491255 Green Apple
491455 Mango
491155 Orchard Spice
491405 Peach Kiwi

491355 Pina Colada
491305 Powder Fresh
491055 Tropical Nectar
491205 Vanilla Delight

ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Dimethyl Ketal
Isobutane
Propane
Butane
Fragrance

CAS No.:
67-64-1
75-28-5
74-98-6
106-97-8
Not available

TLV:
500ppm
Not established
2500ppm
800ppm
Not available

______________________________________________________________________________

SECTION 3

Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA

<0 to 1330 F
Slightly
Clear

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5

Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.
First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

SECTION 9

SPILL OR LEAK PROCEDURE

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________
Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None
__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491153,491105,491325,491235,491123,491075,491255,491455,491155,491405,491355,491305,491055, 491205

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name: NEUTRAZEN Natural Scents
491153 Cinnamon
491105 Citrus Creme
491325 Citrus Peel
491235 Cranberry Spice
491123 Fresh Linen
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

(Hand Held Cans)
491075 Fruit Basket
491255 Green Apple
491455 Mango
491155 Orchard Spice
491405 Peach Kiwi

491355 Pina Colada
491305 Powder Fresh
491055 Tropical Nectar
491205 Vanilla Delight

ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Dimethyl Ketal
Isobutane
Propane
Butane
Fragrance

CAS No.:
67-64-1
75-28-5
74-98-6
106-97-8
Not available

TLV:
500ppm
Not established
2500ppm
800ppm
Not available

______________________________________________________________________________

SECTION 3

Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA

<0 to 1330 F
Slightly
Clear

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5

Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.
First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

SECTION 9

SPILL OR LEAK PROCEDURE

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________
Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None
__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491153,491105,491325,491235,491123,491075,491255,491455,491155,491405,491355,491305,491055, 491205

NFPA Hazard Rating
Flammability

0
0

Health

MATERIAL SAFETY DATA SHEET
L-82E

0

Reactivity

0 = Minimum 1 = Light 2 = Moderate 3 = Serious 4 = Extreme

Section 1 - Product Identification
Bio-Chem Surface Technology

Trade name:

Gold Matrix All Purpose

5977 Transcanada Highway
Pointe-Claire, Quebec
H9R 1C1
Emergency: CANUTEC (613) 996-6666

Product name:
Order no.:
WHMIS Classification:
Controlled under WHMIS:

Industrial cleaner/degreaser
53-G 603, 53-G 607, 53-G608
Non-hazardous
No

Section 2 - Hazardous Ingredients
Ingredients

CAS Number

% by Weight

LD50RAT

LC50RAT

No hazardous substances to declare.

Section 3 - Physical / Chemical Characteristics
Physical state:
pH:
Specific gravity:
Evaporation rate:

Liquid
12
1.00 g/ml @ 20ºC
N/Av

Odour & appearance:Lavender, blue
Boiling point:
98ºC
Vapour pressure:
N/Av
VOC g/l:
N/Av

Odour threshold: None
Freezing point: 0ºC
Vapour density: N/Av
Water solubility: Soluble

Section 4 - Fire & Explosion Hazard
Flammability: No
Flashpoint: N/A

Conditions: None

Auto ignition temperature: N/A
Flammable limits (%): Upper: N/A Lower: N/A

Extinguishing media: None
Hazardous combustion products: None
Sensitivity to mechanical impact or static discharge: No

Section 5 - Reactivity Data
Chemical stability: Yes
Conditions: None
Incompatible substances: Do not mix with other chemicals.
Hazardous decomposition products: None
N/A - Not Applicable

Reactivity conditions: None

N/Av - Not Available
Page 1 of 2

MATERIAL SAFETY DATA SHEET
L-82E
Section 6 - Toxicological Data
Route of entry: Eye and skin contact, ingestion.
Acute exposure effects: None
Chronic exposure effects: None
Exposure limits (TLV/TWA): N/Av
Carcinogenicity
Mutagenicity
Reproductive toxicity
No
No
No
If yes to any of the above, specify:

Teratogenicity
No

Synergistic effects
No

Section 7 - Preventive Measures
Protective equipment:
Handling procedures:
Waste disposal methods:
Leak/spill procedures:
Storage requirements:
Engineering controls:
Handling equipment:
Special shipping information:

Gloves in case of prolonged contact.
Keep container tightly closed.
Dispose as per municipal, provincial and federal regulations.
Soak up with absorbent material. Rinse small amount with quantity of water. Neutralize.
Store below 50ºC and above 0ºC. Keep upright.
None
None

Section 8 - First Aid Measures
Skin contact:
Eye contact:
Inhalation:
Ingestion:
Other:

Wash off with water and soap. Apply cream.
Rinse eyes thoroughly with water. Consult a physician.
N/A
Do not induce vomitting. Rinse mouth with water and give plenty of water to drink.
Consult a physician.

Section 9 - Preparation of MSDS
Prepared by:
Telephone:
Date:

Division Manager WCB
(514) 733-3315
June 21th, 2007

This data is offered in good faith as typical values and not as a product specification. No warranty, either express or implied is hereby made. The
recommended industrial hygiene and safe handling procedures are believed to bee generally applicable. However, each user should review these
recommendations in the specific context of the intended use and determine whether they are appropriate.

N/A - Not Applicable

N/Av - Not Available
Page 2 of 2

MATERIAL SAFETY DATA SHEET

Atlantic Chemical Equipment Co.
3471 Atlanta Industrial Parkway
Suite 200
Atlanta, GA 30331
404-505-6626

PRODUCT NAME:

(CCL) NON-RINSE EVAPORATOR COIL CLEANER

EMERGENCY PHONE: 1-800-424-9300

VII - PRECAUTIONS FOR SAFE HANDLING AND USE

May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200.

Standard must be consulted for specific requirements. This product contains
no substances subject to SARA TITLE III and 40 CRF.

HMIS SYMBOLS
HEALTH

1

FLAMMABILITY

0

REACTIVITY

0

STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED:
SMALL SPILLS: Dilute and wash to drain.
LARGE SPILLS: Due to packaging, large spills cannot occur.
WASTE DISPOSAL METHOD: Deposit in approved hazardous waste landfill in accordance with local, state, and federal regulations.

1 - IDENTIFICATION

VIII - SPECIAL PROTECTION INFORMATION

PRODUCT NAME: CCL - EVAPORATOR COIL CLEANER

PACKAGE TYPE: 16oz, 1, 5, 55 gal

PREPARED DEPARTMENT OF HAZARDOUS COMMUNICATIONS

DATE PREPARED: January 2006

RESPIRATORY: Wear approved mist respirator for mist conditions or in enclosed areas.
EYE: Chemical goggles recommended.

II - HAZARDOUS INGREDIENTS
PRINCIPLE HAZARDOUS COMPONENT(S)
(CHEMICAL NAMES)
Sodium Silicate

CAS NO

ACGIH TLV

6824-92-0

ND

ND

2-Butoxyethanol*

111-76-2

25ppm

25ppm

OSHA

PEL

% or RANGE

SKIN: Wear impervious gloves, apron, boots.

PROTECTIVE GLOVES: Recommended Butyl/alkaline resistant

OTHER: do not eat, drink, or smoke in work area. Wash hands before eating.
VENTILATION REQUIREMENTS: Local exhaust adequate

*2-Butyloxyethanol is a TITLE III Section 313 Chemical subject to reporting; a listed air contaminate with skin designation.

IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed when not in use.

III - PHYSICAL DATA
BOILING POINT ( 0F) : ND
VAPOR PRESSURE (mm Hg) : ND

SPECIFIC GRAVITY (H20= 1) : 1.062

VAPOR DENSITY (Air = 1) : ND

EVAPORATION RATE (H20 = 1) : ND

pH : 13.0

APPEARANCE AND ODOR : Clear green liquid. Bland odor

MELTING POINT: N.A.

SPECIAL PRECAUTIONARY STATEMENTS: Keep this and all chemicals out of reach of children.
NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on
experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be
confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of
merchantability fitness or otherwise is made.

SOLUBILITY IN WATER : Complete

IV - FIRE AND EXPLOSION HAZARD DATA
FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Not Flammable

SARA Title III Reporting Requirements

SPECIAL FIRE FIGHTING PROCEDURES: None known
UNUSUAL FIRE AND EXPLOSION HAZARDS: None known

V - REACTIVITY DATA
CHEMICAL
STABILITY

UNSTABLE

302

(Extremely Hazardous Substances): Reporting not required.

304/CERCLA

(Spills Notification): Not required.

311

Community Right-To-Know, RTK): Reporting required. Acute health hazard.

312

(RTK Inventory Data): Reporting required for inventories above TPQ.

CONDITIONS TO AVOID:

STABLE

X

INCOMPATIBILITY (Materials to avoid): Oxidizers or acids
HAZARDOUS DECOMPOSITION PRODUCTS:
HAZARDOUS
POLYMERIZATION

MAY OCCUR

CONDITIONS TO AVOID:

WILL NOT OCCUR

X

VI - HEALTH HAZARD AREA
ROUTE(S) OF ENTRY:

EYES Yes

SKIN Yes

INGESTION Yes

313

(Emissions and Releases): Reporting required for 2-Butoxyethanol above RQ.

DOT

NOT HAZARDOUS

INHALATION Yes
References

EFFECTS OF OVER EXPOSURE: Corrosive to eyes, skin, and mucous membranes
INHALATION: Irritation of nasal passages. Possible light headedness.

TOXIC SUBSTANCE CONTROL CT LIST (TSCA) - INGREDIENTS LISTED

SKIN CONTACT/ABSORPTION: Causes burning and irritation. 2-butoxyethanol enters bloodstream through skin absorption.

PERMISSIBLE EXPOSURE REFERENCES:
Registry of Toxic Effects of Chemical Substances.
Title 29 Code of Federal Regulations.

INGESTION: causes nausea - gastric distress. Possible pulmonary edema if aspiration of material in lungs occurs while vomiting.

National Toxicology Program (NTP) Report on Carcinogens.

EYES: Will cause burning and severe irritation.
CARCINOGENICITY:

NTP? Not listed

IARC MONOGRAPHS?N/L

OSHA REGULATED? Not listed

Title 40 Code of Federal Regulations

EMERGENCY AND FIRST AID PROCEDURES:
EYES AND SKIN: EYES - Wash with plenty of water for 15 minutes. GET IMMEDIATE MEDICAL ATTENTION.
soap and water. Get medical help if irritation persists. If nausea occurs seek medical help.

International Agency for Research on Cancer (IARC) Monographs.

SKIN - Wash well with REGULATORY STANDARDS:

INHALATION: Move to fresh air. If breathing difficulty does not improve seek medical attention.
INGESTION: Drink water. Do not cause vomiting. GET IMMEDIATE MEDICAL ATTENTION. CALL POISON CONTROL CENTER.

DOT Title 49 Code of Federal Regulations 172.101
SARA Title III
Nuclear Regulatory Commission

1

MATERIAL SAFETY DATA SHEET

Atlantic Chemical Equipment Co.
3471 Atlanta Industrial Parkway
Suite 200
Atlanta, GA 30331
404-505-6626

PRODUCT NAME:

(CCL) NON-RINSE EVAPORATOR COIL CLEANER

EMERGENCY PHONE: 1-800-424-9300

VII - PRECAUTIONS FOR SAFE HANDLING AND USE

May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200.

Standard must be consulted for specific requirements. This product contains
no substances subject to SARA TITLE III and 40 CRF.

HMIS SYMBOLS
HEALTH

1

FLAMMABILITY

0

REACTIVITY

0

STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED:
SMALL SPILLS: Dilute and wash to drain.
LARGE SPILLS: Due to packaging, large spills cannot occur.
WASTE DISPOSAL METHOD: Deposit in approved hazardous waste landfill in accordance with local, state, and federal regulations.

1 - IDENTIFICATION

VIII - SPECIAL PROTECTION INFORMATION

PRODUCT NAME: CCL - EVAPORATOR COIL CLEANER

PACKAGE TYPE: 16oz, 1, 5, 55 gal

PREPARED DEPARTMENT OF HAZARDOUS COMMUNICATIONS

DATE PREPARED: January 2006

RESPIRATORY: Wear approved mist respirator for mist conditions or in enclosed areas.
EYE: Chemical goggles recommended.

II - HAZARDOUS INGREDIENTS
PRINCIPLE HAZARDOUS COMPONENT(S)
(CHEMICAL NAMES)
Sodium Silicate

CAS NO

ACGIH TLV

6824-92-0

ND

ND

2-Butoxyethanol*

111-76-2

25ppm

25ppm

OSHA

PEL

% or RANGE

SKIN: Wear impervious gloves, apron, boots.

PROTECTIVE GLOVES: Recommended Butyl/alkaline resistant

OTHER: do not eat, drink, or smoke in work area. Wash hands before eating.
VENTILATION REQUIREMENTS: Local exhaust adequate

*2-Butyloxyethanol is a TITLE III Section 313 Chemical subject to reporting; a listed air contaminate with skin designation.

IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed when not in use.

III - PHYSICAL DATA
BOILING POINT ( 0F) : ND
VAPOR PRESSURE (mm Hg) : ND

SPECIFIC GRAVITY (H20= 1) : 1.062

VAPOR DENSITY (Air = 1) : ND

EVAPORATION RATE (H20 = 1) : ND

pH : 13.0

APPEARANCE AND ODOR : Clear green liquid. Bland odor

MELTING POINT: N.A.

SPECIAL PRECAUTIONARY STATEMENTS: Keep this and all chemicals out of reach of children.
NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on
experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be
confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of
merchantability fitness or otherwise is made.

SOLUBILITY IN WATER : Complete

IV - FIRE AND EXPLOSION HAZARD DATA
FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Not Flammable

SARA Title III Reporting Requirements

SPECIAL FIRE FIGHTING PROCEDURES: None known
UNUSUAL FIRE AND EXPLOSION HAZARDS: None known

V - REACTIVITY DATA
CHEMICAL
STABILITY

UNSTABLE

302

(Extremely Hazardous Substances): Reporting not required.

304/CERCLA

(Spills Notification): Not required.

311

Community Right-To-Know, RTK): Reporting required. Acute health hazard.

312

(RTK Inventory Data): Reporting required for inventories above TPQ.

CONDITIONS TO AVOID:

STABLE

X

INCOMPATIBILITY (Materials to avoid): Oxidizers or acids
HAZARDOUS DECOMPOSITION PRODUCTS:
HAZARDOUS
POLYMERIZATION

MAY OCCUR

CONDITIONS TO AVOID:

WILL NOT OCCUR

X

VI - HEALTH HAZARD AREA
ROUTE(S) OF ENTRY:

EYES Yes

SKIN Yes

INGESTION Yes

313

(Emissions and Releases): Reporting required for 2-Butoxyethanol above RQ.

DOT

NOT HAZARDOUS

INHALATION Yes
References

EFFECTS OF OVER EXPOSURE: Corrosive to eyes, skin, and mucous membranes
INHALATION: Irritation of nasal passages. Possible light headedness.

TOXIC SUBSTANCE CONTROL CT LIST (TSCA) - INGREDIENTS LISTED

SKIN CONTACT/ABSORPTION: Causes burning and irritation. 2-butoxyethanol enters bloodstream through skin absorption.

PERMISSIBLE EXPOSURE REFERENCES:
Registry of Toxic Effects of Chemical Substances.
Title 29 Code of Federal Regulations.

INGESTION: causes nausea - gastric distress. Possible pulmonary edema if aspiration of material in lungs occurs while vomiting.

National Toxicology Program (NTP) Report on Carcinogens.

EYES: Will cause burning and severe irritation.
CARCINOGENICITY:

NTP? Not listed

IARC MONOGRAPHS?N/L

OSHA REGULATED? Not listed

Title 40 Code of Federal Regulations

EMERGENCY AND FIRST AID PROCEDURES:
EYES AND SKIN: EYES - Wash with plenty of water for 15 minutes. GET IMMEDIATE MEDICAL ATTENTION.
soap and water. Get medical help if irritation persists. If nausea occurs seek medical help.

International Agency for Research on Cancer (IARC) Monographs.

SKIN - Wash well with REGULATORY STANDARDS:

INHALATION: Move to fresh air. If breathing difficulty does not improve seek medical attention.
INGESTION: Drink water. Do not cause vomiting. GET IMMEDIATE MEDICAL ATTENTION. CALL POISON CONTROL CENTER.

DOT Title 49 Code of Federal Regulations 172.101
SARA Title III
Nuclear Regulatory Commission

1

Atlantic Chemical Equipment Co.
2190 DeFoor Hills Rd NW
Atlanta, GA 30318
404-355-5522

MATERIAL SAFETY DATA SHEET

PRODUCT NAME:

HEAVY DUTY COIL CLEANER (HDC)

EMERGENCY PHONE: 1-800-424-9300

VII - PRECAUTIONS FOR SAFE HANDLING AND USE

May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200.

Standard must be consulted for specific requirements. This product contains
no substances subject to SARA TITLE III and 40 CRF.

HMIS SYMBOLS
HEALTH

2

FLAMMABILITY

0

REACTIVITY

0

STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED:
SMALL SPILLS: Neutralize with vinegar and flush to sanitary sewer.
LARGE SPILLS: Due to packaging, large spills can not occur.
WASTE DISPOSAL METHOD: Deposit in landfill in accordance with Local, State, and Federal regulations.

1 - IDENTIFICATION

VIII - SPECIAL PROTECTION INFORMATION

PRODUCT NAME: (HDC) HEAVY DUTY COIL CLEANER

PACKAGE TYPE: 16oz, 1, 5, 55gallon

PREPARED DEPARTMENT OF HAZARDOUS COMMUNICATIONS

DATE PREPARED: June 2003

RESPIRATORY: Needed to keep exposure below TLV for mists. Use NIOSH approved cartridge type respirator for mists.
EYE: Chemical goggles recommended

II - HAZARDOUS INGREDIENTS
OSHA

PEL

PRINCIPLE HAZARDOUS COMPONENT(S)
(CHEMICAL NAMES)
Caustic Potash (Potassium Hydroxide)

CAS NO

ACGIH TLV

1310-58-3

2 mg/m3

Hexylene Glycol

107-41-5

26 ppm

Triethanolamine

102-71-6

N/E

N/E

>1

Sodium Metasilicate

6834-92-0

N/E

N/E

>2

% or RANGE

2 mg/m3

SKIN: Avoid contact with eyes, skin, and clothing. Wash hands PROTECTIVE GLOVES: Recommended. Chemical resistant rubber or
and face thoroughly after handling.
plastic gloves.

<2
>4

OTHER: Rubber of PVC footwear, apron in misty conditions.
VENTILATION REQUIREMENTS: Local exhaust adequate.

IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed when not in use. Do not store in aluminum
drums and separate from acids.

III - PHYSICAL DATA
BOILING POINT ( 0F) : 2120F
VAPOR PRESSURE (mm Hg) : 17

SPECIFIC GRAVITY (H20= 1) : 1.12

VAPOR DENSITY (Air = 1) : 1.0

EVAPORATION RATE (H20 = 1) :

pH : 13.5

APPEARANCE AND ODOR : Clear yellow liquid - Slight glycol odor

MELTING POINT: N/D

SPECIAL PRECAUTIONARY STATEMENTS: Keep this and all chemicals out of reach of children.

SOLUBILITY IN WATER : Complete

IV - FIRE AND EXPLOSION HAZARD DATA

NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on
experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be
confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of
merchantability fitness or otherwise is made.

FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Non-Flammable
SARA Title III Reporting Requirements

SPECIAL FIRE FIGHTING PROCEDURES: Wear impervious gear to prevent all contact
UNUSUAL FIRE AND EXPLOSION HAZARDS:

V - REACTIVITY DATA
CHEMICAL
STABILITY

UNSTABLE

302

(Extremely Hazardous Substances): Reporting not required.

304/CERCLA

(Spills Notification): Reporting required for spills above 1000 lbs.

311

Community Right-To-Know, RTK): Reporting required. Acute & chronic health hazard, corrosive & toxic

312

(RTK Inventory Data): Reporting required for above TPQ.

CONDITIONS TO AVOID:

STABLE

X

INCOMPATIBILITY (Materials to avoid): Acids, acid products, oxidizing agents
HAZARDOUS DECOMPOSITION PRODUCTS: Heat, Carbon Monoxide, Carbon Dioxide
HAZARDOUS
POLYMERIZATION

MAY OCCUR

CONDITIONS TO AVOID:

WILL NOT OCCUR

X

VI - HEALTH HAZARD AREA
ROUTE(S) OF ENTRY:

EYES Yes

SKIN Yes

INGESTION Yes

313

(Emissions and Releases): Reporting not required.

DOT

Corrosive liquid, basic, inorganic, N.O.S. (contains potassium hydroxide) 8, UN3264, PGIII

INHALATION Yes
References

EFFECTS OF OVER EXPOSURE: Corrosive to eyes and mucous membranes
INHALATION: Mists are irritating to nasal passages

TOXIC SUBSTANCE CONTROL CT LIST (TSCA) - INGREDIENTS LISTED

SKIN CONTACT/ABSORPTION: Irritation, redness
INGESTION: Gastric distress. Corrosive to digestive tract. May cause central nervous system depression

PERMISSIBLE EXPOSURE REFERENCES:
Registry of Toxic Effects of Chemical Substances.
Title 29 Code of Federal Regulations.
National Toxicology Program (NTP) Report on Carcinogens.

EYES: Burning, irritation, redness. Corrosive to eyes.
CARCINOGENICITY:

NTP? Not listed

IARC MONOGRAPHS? Not listed

OSHA REGULATED? Not listed

Title 40 Code of Federal Regulations

EMERGENCY AND FIRST AID PROCEDURES:
EYES AND SKIN: EYES - Wash eyes with plenty of water for 15 minutes. SEEK IMMEDIATE MEDICAL ATTENTION
soap and water. SEEK MEDICAL ATTENTION if irritation persists

International Agency for Research on Cancer (IARC) Monographs.

SKIN - Wash well with REGULATORY STANDARDS:

INHALATION: Remove to fresh air. If breathing is difficult SEEK IMMEDIATE MEDICAL ATTENTION
INGESTION: Drink water. DO NOT induce vomiting. SEEK IMMEDIATE MEDICAL ATTENTION. CALL POISON CONTROL CENTER

DOT Title 49 Code of Federal Regulations 172.101
SARA Title III
Nuclear Regulatory Commission

1

Atlantic Chemical Equipment Co.
2190 DeFoor Hills Rd NW
Atlanta, GA 30318
404-355-5522

MATERIAL SAFETY DATA SHEET

PRODUCT NAME:

ALKALINE COIL CLEANER (ACC)

EMERGENCY PHONE: 1-800-424-9300

VII - PRECAUTIONS FOR SAFE HANDLING AND USE

May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200.

Standard must be consulted for specific requirements. This product contains
no substances subject to SARA TITLE III and 40 CRF.

HMIS SYMBOLS
HEALTH

3

FLAMMABILITY

0

REACTIVITY

0

STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED:
SMALL SPILLS: Neutralize with diluted acid flush with water to drain.
LARGE SPILLS: Due to packaging, large spills can not occur.
WASTE DISPOSAL METHOD: Deposit in accordance to local, state, and federal regulations

1 - IDENTIFICATION

VIII - SPECIAL PROTECTION INFORMATION

PRODUCT NAME: Alkaline Coil Cleaner (ACC)

PACKAGE TYPE: Pint, Gallon, Pail, or Drum

PREPARED DEPARTMENT OF HAZARDOUS COMMUNICATIONS

DATE PREPARED: June 2003

RESPIRATORY: Vapor cartridge for mists and vapors/Not normally needed with local exhaust
EYE: Chemical goggles - Recommended

II - HAZARDOUS INGREDIENTS
PRINCIPLE HAZARDOUS COMPONENT(S)
(CHEMICAL NAMES)
Caustic Soda (Sodium Hydroxide)*

CAS NO

ACGIH TLV

1310-73-2

2mg/m

OSHA

3

PEL

2mg/m

% or RANGE

3

SKIN: Wear impervious clothing, boots, splash apron

PROTECTIVE GLOVES: Chemical resistant rubber or plastic gloves

< 17

* listed air contaminate (see 29 CFR per 1910.1000)

OTHER: Do not eat, drink, or smoke in work area. Wash hands before eating
VENTILATION REQUIREMENTS: Local exhaust adequate

III - PHYSICAL DATA
BOILING POINT ( 0F) : 2120F
VAPOR PRESSURE (mm Hg) : N/D

SPECIFIC GRAVITY (H20= 1) : 1.18

VAPOR DENSITY (Air = 1) : 1

EVAPORATION RATE (H20 = 1) : > 1

pH : 13.5

APPEARANCE AND ODOR : Clear liquid - slight ester odor

MELTING POINT: N/A

IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed when not in use

SOLUBILITY IN WATER : Complete

SPECIAL PRECAUTIONARY STATEMENTS: Keep this and all chemicals out of reach of children.

IV - FIRE AND EXPLOSION HAZARD DATA
FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Flash Point: None

NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on
experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be
confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of
merchantability fitness or otherwise is made.

SPECIAL FIRE FIGHTING PROCEDURES: Flood with water; compound is corrosive to exposed skin, wear protective clothing
UNUSUAL FIRE AND EXPLOSION HAZARDS: May react with oxidizers
CHEMICAL
STABILITY

UNSTABLE

SARA Title III Reporting Requirements

CONDITIONS TO AVOID:
X

STABLE

INCOMPATIBILITY (Materials to avoid): Acids and acids products. Soft metals. Oxidizers

302

(Extremely Hazardous Substances): Reporting not required.

304/CERCLA

(Spills Notification): Reporting required if release is above RQ for sodium hydroxide (1000 lbs)

311

Community Right-To-Know, RTK): Reporting required. Acute health hazard, corrosive, toxic.

312

(RTK Inventory Data): Reporting required for inventories above threshold planning quantity.

HAZARDOUS DECOMPOSITION PRODUCTS: Carbon dioxide, Heat, Carbon Monoxide
HAZARDOUS
POLYMERIZATION

MAY OCCUR

CONDITIONS TO AVOID:
X

WILL NOT OCCUR

VI - HEALTH HAZARD AREA
ROUTE(S) OF ENTRY:

EYES Yes

SKIN Yes

INGESTION Yes

INHALATION Yes

EFFECTS OF OVER EXPOSURE: Corrosive to skin, eyes, and mucous membranes, digestive tract

313

(Emissions and Releases): Reporting not required.

INHALATION: Irritation of respiratory system/mists can cause damage to respiratory passages.

DOT

Corrosive liquid, basic, inorganic, N.O.S. (contains sodium hydroxide) 8, UN3266, PGII

SKIN CONTACT/ABSORPTION: causes burning and possible deep ulceration
References

INGESTION: Gastric distress (severe damage to membranes and deep tissues)

TOXIC SUBSTANCE CONTROL CT LIST (TSCA) - INGREDIENTS LISTED
PERMISSIBLE EXPOSURE REFERENCES:

EYES: Will cause burning and severe damage even blindness rapidly
CARCINOGENICITY:

NTP? Notlisted

IARC MONOGRAPHS? Not listed

OSHA REGULATED? Not listed

EYES AND SKIN: EYES - Flush eyes with plenty of water for 15 minutes. GET IMMEDIATE MEDICAL ATTENTION
neutralize skin then wash well with soap and water. Get medical help if irritation persists
INHALATION: Move to fresh air, if breathing is difficult or stops then start artificial respiration. GET MEDICAL ATTENTION
INGESTION: Drink water. Do Not induce vomiting. GET IMMEDIATE MEDICAL ATTENTION. Call Poison Control Center.

Registry of Toxic Effects of Chemical Substances.
Title 29 Code of Federal Regulations.

EMERGENCY AND FIRST AID PROCEDURES:
SKIN - Use vinegar to

National Toxicology Program (NTP) Report on Carcinogens.
International Agency for Research on Cancer (IARC) Monographs.
Title 40 Code of Federal Regulations
REGULATORY STANDARDS:
DOT Title 49 Code of Federal Regulations 172.101
SARA Title III
Nuclear Regulatory Commission

1

PROTECH™ Super Concentrated Condenser Coil Cleaner

85-H4X32, 85-4X08

Page 1 of 2

MATERIAL SAFETY DATA SHEET
SECTION 1

CHEMICAL PRODUCT AND COMPANY INFORMATION

Product Name: PROTECH™ Super Concentrated Condenser Coil Cleaner
Product Number(s): 85-H4X32, 85-4X08
Product Use: Coil cleaner
Company Name: North American Research Corporation
P.O. Box 1318
Lewisville, TX 75067
Telephone Numbers: (972) 492-1800, (800) 527-7520, Fax (972) 394-6755
Emergencies: Infotrac (800) 535-5053 (24 hours, everyday)
SECTION 2

Date Prepared

Jan. 24, 2003

Replaces

Apr. 04, 2001

COMPOSITION / INFORMATION ON INGREDIENTS

OSHA Hazardous Components (29 CFR 1910.1200):

Potassium Hydroxide

SECTION 3

CAS
Registry No.
1310-58-3

OSHA PEL
3
2 mg/m Ceiling

ACGIH TLV
3
2 mg/m Ceiling

Other Limits
None known

%
(Optional)
< 70

HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
POISON! DANGER! CORROSIVE. CAUSES SEVERE BURNS TO SKIN, EYES, AND OTHER BODY TISSUE. HARMFUL
OR FATAL IF SWALLOWED.
POTENTIAL HEALTH EFFECTS
EYE CONTACT: Corrosive. May cause permanent damage including blindness.
SKIN CONTACT: Corrosive. May cause permanent damage.
INHALATION: May cause irritation and corrosive effects to the nose, throat, and respiratory tract. Severe injury is usually
avoided by self-limiting coughing and sneezing symptoms.
INGESTION: Corrosive. May cause burns to mouth, throat, and stomach.
CHRONIC EXPOSURE: No known chronic effects.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: None known other than existing skin disorders.
CARCINOGENICITY: NTP? No
IARC Monographs? No
OSHA Regulated? No
SECTION 4

FIRST-AID MEASURES

EYE CONTACT: Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Get medical attention
immediately.
SKIN CONTACT: Flush immediately with plenty of water for at least 15 minutes. Get medical attention immediately.
INHALATION: If breathing is difficult: Remove to fresh air. Get medical attention immediately.
INGESTION: Do not induce vomiting! Immediately drink large quantities of water. Never give anything by mouth to an
unconscious person. Get medical attention immediately.
SECTION 5

FIRE-FIGHTING MEASURES

FLASHPOINT: Not flammable
METHOD: Not applicable
FLAMMABLE LIMITS:
LEL: Not applicable
UEL: Not applicable AUTOIGNITION TEMP: Not applicable
GENERAL HAZARD: Not considered to be a fire hazard. Will react with some metals, eg. Aluminum, tin, zinc to form flammable
hydrogen gas.
FIRE EXTINGUISHING MEDIA: Use means suitable for extinguishing surrounding fire. Water spray may be used to keep fire-exposed
containers cool.
SPECIAL INFORMATION: Corrosive material. See sections 8 and 10.
SECTION 6

ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS: Put on appropriate personal protective equipment.
ENVIRONMENTAL PRECAUTIONS AND CLEAN-UP:
Small spills: Mop up or soak up with rags and flush with water.
In the event of major spillage: Use appropriate containment consistent with good industrial or environmental practice. Recover as
much as possible. Pump, sweep or scrape up the remaining material and place in suitable clean containers for disposal by
proper methods. Use a water rinse for final clean-up.

PROTECH™ Super Concentrated Condenser Coil Cleaner

SECTION 7

85-H4X32, 85-4X08

Page 2 of 2

STORAGE AND HANDLING

HANDLING: Avoid contact with eyes, skin, and clothing. Do not taste or swallow. Avoid breathing vapors or spray mists. Wash
thoroughly after handling. Remove and wash contaminated clothing and footwear before reuse. Product residue may remain on/in
empty containers. All precautions for handling the product must be used in handling the empty container and residue. FOR
INDUSTRIAL USE ONLY.
STORAGE: Keep tightly closed in original container. Store in a cool, dry, ventilated area. Protect against physical damage. Tip: For
transport on service truck, place container inside of plastic pail and immobilize pail.
SECTION 8

EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLS: Good general ventilation should be sufficient to control airborne levels. Respiratory protection is not required
if good ventilation is maintained.
PERSONAL PROTECTION:
EYES: Chemical splash goggles.
HANDS: Chemical resistant gloves; rubber, neoprene, or other impervious material.
RESPIRATORY: If mists/vapors are not adequately controlled by ventilation, use appropriate respiratory protection to avoid over
exposure. A respiratory protection program that meets OSHA’s 29 CFR 1910.134 and ANSI Z88.2
requirements must be followed whenever workplace conditions warrant a respirator’s use.
FEET: Chemical resistant boots; rubber, neoprene, or other impervious material.
BODY: If major exposure is possible, wear suitable, impervious protective clothing.
SECTION 9

PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE AND ODOR: Semi-viscous, amber to clear liquid. Bland odor.
VAPOR PRESSURE: Not determined
SOLUBILITY IN WATER: Complete
BOILING POINT: 212°F
EVAPORATION RATE (Butyl Acetate = 1): Not determined
SECTION 10

SPECIFIC GRAVITY: 1.42
VAPOR DENSITY: Not determined
pH: 13.5
FREEZING / MELTING POINT: Not determined

STABILITY AND REACTIVITY

STABILITY: Stable under ordinary conditions of use and storage. HAZARDOUS POLYMERIZATION: Will not occur.
INCOMPATIBILITY (Materials to Avoid): Reactive with oxidizing agents, acids, chlorinated hydrocarbons, acetone. Will react with some
metals, e.g., aluminum, tin, zinc, to form flammable hydrogen gas.
HAZARDOUS DECOMPOSITION PRODUCTS: When exposed to fire, produces normal products of combustion.
SECTION 11

TOXICOLOGICAL INFORMATION

For Potassium Hydroxide (1310-58-3): Oral LD50 (rat): 365 mg/kg. Primary skin irritation: (rabbit, 24hr) severe. Primary eye irritation:
(rabbit, 24hr) severe.
SECTION 12

ECOLOGICAL INFORMATION

For Potassium Hydroxide (1310-58-3): LC50 (96hr) Fathead minnow, 45% KOH solution = 179 mg/L.
SECTION 13

DISPOSAL CONSIDERATIONS

Disposal of unused product is regulated under environmental and transportation laws as a corrosive waste. Dispose of container and
unused contents in accordance with federal, state, and local requirements.
SECTION 14

TRANSPORT INFORMATION

U.S. Department of Transportation: Potassium Hydroxide Solution, 8, UN1814, PG II
SECTION 15

REGULATORY INFORMATION

TSCA: All ingredients of this product are listed or are excluded from listing on the U.S. TSCA chemical substances inventory.
CERCLA: Potassium Hydroxide (1310-58-3); RQ 1000 lbs.
SARA TITLE III: Section 311/312 Hazard Category: Acute: Yes Chronic: No Fire: No Pressure: No Reactive Hazard: Yes
Section 313 Reportable Ingredients: None
SECTION 16

OTHER INFORMATION

NFPA RATING: Health – 3, Flammability – 0, Reactivity – 1
®

HMIS RATING: Health – 3, Flammability – 0, Reactivity – 2
®

®

®

HMIS ratings are to be used with a fully implemented HMIS program. HMIS is a registered mark of the National Paint and
Coatings Association (NPCA).
NOTICE: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty,
express or implied, as to accuracy of the information contained within. Actual conditions of use and handling are beyond seller’s control.
User is responsible to evaluate all available information when using product for any particular use and to comply with all federal, state,
provincial, and local laws and regulations.

PROTECH™ Super Concentrated Condenser Coil Cleaner

85-4X08, 85-H4X32

Page 1 of 2

MATERIAL SAFETY DATA SHEET
SECTION 1

CHEMICAL PRODUCT AND COMPANY INFORMATION

Product Name: PROTECH™ Super Concentrated Condenser Coil Cleaner
Product Number(s): 85-4X08, 85-H4X32
Product Use: Coil cleaner
Company Name: North American Research Corporation
P.O. Box 1318
Lewisville, TX 75067
Telephone Numbers: (972) 492-1800, (800) 527-7520, Fax (972) 394-6755
Emergencies: Infotrac (800) 535-5053 (24 hours, everyday)
SECTION 2

Date Prepared

Jan. 14, 2004

Replaces

COMPOSITION / INFORMATION ON INGREDIENTS

OSHA Hazardous Components (29 CFR 1910.1200):

Potassium Hydroxide

SECTION 3

CAS
Registry No.
1310-58-3

OSHA PEL
3
2 mg/m Ceiling

ACGIH TLV
3
2 mg/m Ceiling

Other Limits
None known

%
(Optional)
< 70

HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
POISON! DANGER! CORROSIVE. CAUSES SEVERE BURNS TO SKIN, EYES, AND OTHER BODY TISSUE. HARMFUL
OR FATAL IF SWALLOWED.
POTENTIAL HEALTH EFFECTS
EYE CONTACT: Corrosive. May cause permanent damage including blindness.
SKIN CONTACT: Corrosive. May cause permanent damage.
INHALATION: May cause irritation and corrosive effects to the nose, throat, and respiratory tract. Severe injury is usually
avoided by self-limiting coughing and sneezing symptoms.
INGESTION: Corrosive. May cause burns to mouth, throat, and stomach.
CHRONIC EXPOSURE: No known chronic effects.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: None known other than existing skin disorders.
CARCINOGENICITY: NTP? No
IARC Monographs? No
OSHA Regulated? No
SECTION 4

FIRST-AID MEASURES

EYE CONTACT: Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Get medical attention
immediately.
SKIN CONTACT: Flush immediately with plenty of water for at least 15 minutes. Get medical attention immediately.
INHALATION: If breathing is difficult: Remove to fresh air. Get medical attention immediately.
INGESTION: Do not induce vomiting! Immediately drink large quantities of water. Never give anything by mouth to an
unconscious person. Get medical attention immediately.
SECTION 5

FIRE-FIGHTING MEASURES

FLASHPOINT: Not flammable
METHOD: Not applicable
FLAMMABLE LIMITS:
LEL: Not applicable
UEL: Not applicable AUTOIGNITION TEMP: Not applicable
GENERAL HAZARD: Not considered to be a fire hazard. Will react with some metals, eg. Aluminum, tin, zinc to form flammable
hydrogen gas.
FIRE EXTINGUISHING MEDIA: Use means suitable for extinguishing surrounding fire. Water spray may be used to keep fire-exposed
containers cool.
SPECIAL INFORMATION: Corrosive material. See sections 8 and 10.
SECTION 6

ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS: Put on appropriate personal protective equipment.
ENVIRONMENTAL PRECAUTIONS AND CLEAN-UP:
Small spills: Mop up or soak up with rags and flush with water.
In the event of major spillage: Use appropriate containment consistent with good industrial or environmental practice. Recover as
much as possible. Pump, sweep or scrape up the remaining material and place in suitable clean containers for disposal by
proper methods. Use a water rinse for final clean-up.

PROTECH™ Super Concentrated Condenser Coil Cleaner

SECTION 7

85-4X08, 85-H4X32

Page 2 of 2

STORAGE AND HANDLING

HANDLING: Avoid contact with eyes, skin, and clothing. Do not taste or swallow. Avoid breathing vapors or spray mists. Wash
thoroughly after handling. Remove and wash contaminated clothing and footwear before reuse. Product residue may remain on/in
empty containers. All precautions for handling the product must be used in handling the empty container and residue. FOR
INDUSTRIAL USE ONLY.
STORAGE: Keep tightly closed in original container. Store in a cool, dry, ventilated area. Protect against physical damage. Tip: For
transport on service truck, place container inside of plastic pail and immobilize pail.
SECTION 8

EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLS: Good general ventilation should be sufficient to control airborne levels. Respiratory protection is not required
if good ventilation is maintained.
PERSONAL PROTECTION:
EYES: Chemical splash goggles.
HANDS: Chemical resistant gloves; rubber, neoprene, or other impervious material.
RESPIRATORY: If mists/vapors are not adequately controlled by ventilation, use appropriate respiratory protection to avoid over
exposure. A respiratory protection program that meets OSHA’s 29 CFR 1910.134 and ANSI Z88.2
requirements must be followed whenever workplace conditions warrant a respirator’s use.
FEET: Chemical resistant boots; rubber, neoprene, or other impervious material.
BODY: If major exposure is possible, wear suitable, impervious protective clothing.
SECTION 9

PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE AND ODOR: Semi-viscous, amber to clear liquid. Bland odor.
VAPOR PRESSURE: Not determined
SOLUBILITY IN WATER: Complete
BOILING POINT: 212°F
EVAPORATION RATE (Butyl Acetate = 1): Not determined
SECTION 10

SPECIFIC GRAVITY: 1.42
VAPOR DENSITY: Not determined
pH: 13.5
FREEZING / MELTING POINT: Not determined

STABILITY AND REACTIVITY

STABILITY: Stable under ordinary conditions of use and storage. HAZARDOUS POLYMERIZATION: Will not occur.
INCOMPATIBILITY (Materials to Avoid): Reactive with oxidizing agents, acids, chlorinated hydrocarbons, acetone. Will react with some
metals, e.g., aluminum, tin, zinc, to form flammable hydrogen gas.
HAZARDOUS DECOMPOSITION PRODUCTS: When exposed to fire, produces normal products of combustion.
SECTION 11

TOXICOLOGICAL INFORMATION

For Potassium Hydroxide (1310-58-3): Oral LD50 (rat): 365 mg/kg. Primary skin irritation: (rabbit, 24hr) severe. Primary eye irritation:
(rabbit, 24hr) severe.
SECTION 12

ECOLOGICAL INFORMATION

For Potassium Hydroxide (1310-58-3): LC50 (96hr) Fathead minnow, 45% KOH solution = 179 mg/L.
SECTION 13

DISPOSAL CONSIDERATIONS

Disposal of unused product is regulated under environmental and transportation laws as a corrosive waste. Dispose of container and
unused contents in accordance with federal, state, and local requirements.
SECTION 14

TRANSPORT INFORMATION

U.S. Department of Transportation: Potassium Hydroxide Solution, 8, UN1814, PG II
SECTION 15

REGULATORY INFORMATION

TSCA: All ingredients of this product are listed or are excluded from listing on the U.S. TSCA chemical substances inventory.
CERCLA: Potassium Hydroxide (1310-58-3); RQ 1000 lbs.
SARA TITLE III: Section 311/312 Hazard Category: Acute: Yes Chronic: No Fire: No Pressure: No Reactive Hazard: Yes
Section 313 Reportable Ingredients: None
SECTION 16

OTHER INFORMATION

NFPA RATING: Health – 3, Flammability – 0, Reactivity – 1
®

HMIS RATING: Health – 3, Flammability – 0, Reactivity – 2
®

®

®

HMIS ratings are to be used with a fully implemented HMIS program. HMIS is a registered mark of the National Paint and
Coatings Association (NPCA).
NOTICE: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty,
express or implied, as to accuracy of the information contained within. Actual conditions of use and handling are beyond seller’s control.
User is responsible to evaluate all available information when using product for any particular use and to comply with all federal, state,
provincial, and local laws and regulations.

Atlantic Chemical Equipment Co.
2190 DeFoor Hills Rd NW
Atlanta, GA 30318
404-355-5522
Toll Free: 1-800-929-2436

MATERIAL SAFETY DATA SHEET

PRODUCT NAME: (FNC) FOAM N' CLEAN COIL CLEANER
EMERGENCY PHONE: 1-800-424-9300

VII - PRECAUTIONS FOR SAFE HANDLING AND USE

May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200.

Standard must be consulted for specific requirements. This product contains
no substances subject to SARA TITLE III and 40 CRF.

HMIS SYMBOLS
HEALTH

3

FLAMMABILITY

0

REACTIVITY

0

STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED:
SMALL SPILLS: Neutralize with water and vinegar. Wash to drain
LARGE SPILLS: Due to packaging, large spills cannot occur
WASTE DISPOSAL METHOD: Deposit in landfill in accordance with local, state, and federal regulations

1 - IDENTIFICATION

VIII - SPECIAL PROTECTION INFORMATION

PRODUCT NAME: Foam N' Clean Coil Cleaner (FNC)

PACKAGE TYPE: 32oz, 1, 2.5, 5, & 55 gallon units

PREPARED BY GENE HUNT/CHEMIST SUPERSCEEDES MAY 2002 MSDS

DATE PREPARED: Revised August 2003

RESPIRATORY:

Keep face away from spray mist. Do not breathe vapors.

EYE: Use tight fitting, splash proof safety goggles. Contact lenses should no be worn when handling this material.

II - HAZARDOUS INGREDIENTS
PRINCIPLE HAZARDOUS COMPONENT(S)
(CHEMICAL NAMES)
Sodium Metasilicate

CAS NO

ACGIH TLV

6834-92-0

N/E

N/E

< 1.5

Sodium Hydroxide 50%

1310-73-2

2mg/m2

< 38

Potassium Hydroxide 45%

1310-58-3

2mg/m3

2mg/m3
NE

OSHA

PEL

% or RANGE

PROTECTIVE GLOVES: Chemical resistant rubber/neoprene

OTHER: Avoid contact with eyes, skin, and clothing. Wash hands and face thoroughly after handling

<4
VENTILATION REQUIREMENTS: If vapors are detected, ventilate work area by opening windows and using exhaust fans. Always work
with wind from behind.

III - PHYSICAL DATA
BOILING POINT ( 0F) : 2120F
VAPOR PRESSURE (mm Hg) : 17

SPECIFIC GRAVITY (H20= 1) : 1.20

VAPOR DENSITY (Air = 1) : 2

EVAPORATION RATE (H20 = 1) : 1.0

pH : 11.6 - 13.0 @ 20 0C
SOLUBILITY IN WATER : Complete

APPEARANCE AND ODOR : Clear brown liquid, Herbal Odor

MELTING POINT:

SKIN: Wear impervious clothing and footwear to prevent all
skin contact. Use of face shield is recommended.

N/A

IX - SPECIAL PRECAUTIONS

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed when not in use
SPECIAL PRECAUTIONARY STATEMENTS: Keep this and all chemicals out of reach of children.

IV - FIRE AND EXPLOSION HAZARD DATA
FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Flash Point: Not Combustible
SPECIAL FIRE FIGHTING PROCEDURES: Standard fire fighting techniques / Wear impervious to strong Alkaline Products Clothing
UNUSUAL FIRE AND EXPLOSION HAZARDS: Avoid mixing with acids and soft metals
CHEMICAL
STABILITY

UNSTABLE

NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on
experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be
confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of
merchantability fitness or otherwise is made.
SARA Title III Reporting Requirements

CONDITIONS TO AVOID:
X

STABLE

INCOMPATIBILITY (Materials to avoid): Acids and acid products

302

(Extremely Hazardous Substances): Reporting not required.

304/CERCLA

(Spills Notification): Reporting required for spills above RQ. Sodium hydroxide and Potassium hydroxide are
listed by CERCLA. Spills in excess of 1000 lbs. Each must be reported.

311

Community Right-To-Know, RTK): Reporting required. Acute & chronic health hazard, corrosive, toxic.

312

(RTK Inventory Data): Reporting required for inventories above threshold planning quantity.

HAZARDOUS DECOMPOSITION PRODUCTS: Heat
HAZARDOUS
POLYMERIZATION

MAY OCCUR

CONDITIONS TO AVOID:
X

WILL NOT OCCUR

VI - HEALTH HAZARD AREA
ROUTE(S) OF ENTRY:

EYES Yes

SKIN Yes

INGESTION Yes

INHALATION Yes

EFFECTS OF OVER EXPOSURE: Very corrosive to skin, eyes, and mucous membranes; causes deep immediate burns, any cause blindness

313

(Emissions and Releases): Reporting not required.

INHALATION: Irritation to nasal passages

DOT

Corrosive liquids, basic, inorganic, N.O.S. (contains sodium hydroxide) 8, UN3266, PGII

SKIN CONTACT/ABSORPTION: Severe burns to exposed skin
INGESTION: Nausea, Corrosive to digestive tract
EYES: Corrosive to eyes/Blindness may occur
CARCINOGENICITY: No
NTP? Not listed

References
PERMISSIBLE EXPOSURE REFERENCES:
Registry of Toxic Effects of Chemical Substances.
IARC MONOGRAPHS? Not listed OSHA REGULATED? See ss II for exposure

EMERGENCY AND FIRST AID PROCEDURES:

Title 29 Code of Federal Regulations.

EYES AND SKIN: EYES - Wash with plenty of water for 15 minutes. GET IMMEDIATE MEDICAL ATTENTION SKIN - Neutralize with very diluted
vinegar solution, wash with soap and water, apply skin cream. For large burns - GET IMMEDIATE MEDICAL ATTENTION

National Toxicology Program (NTP) Report on Carcinogens.

INHALATION: Remove to fresh air. If breathing stops, start artificial respiration, GET IMMEDIATE MEDICAL ATTENTION

Title 40 Code of Federal Regulations

International Agency for Research on Cancer (IARC) Monographs.

INGESTION: Drink water. DO NOT induce vomiting. SEEK IMMEDIATE MEDICAL ATTENTION. NOTE: Vomiting may cause aspiration of material REGULATORY STANDARDS:
to lungs causing Pulmonary Edema
DOT Title 49 Code of Federal Regulations 172.101
SARA Title III
Nuclear Regulatory Commission

1

Atlantic Chemical Equipment Co.
2190 DeFoor Hills Rd NW
Atlanta, GA 30318
404-355-5522

MATERIAL SAFETY DATA SHEET

PRODUCT NAME: ENVIRO-SAFE COIL CLEANER (ECS)
EMERGENCY PHONE: 1-800-424-9300
May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200.

Standard must be consulted for specific requirements. This product contains
no substances subject to SARA TITLE III and 40 CRF.

VII - PRECAUTIONS FOR SAFE HANDLING AND USE
STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED:
Neutralize with diluted vinegar solution to pH of 7 the flush to sewer.

HMIS SYMBOLS
HEALTH

1

FLAMMABILITY

0

REACTIVITY

0

WASTE DISPOSAL METHOD: Flush to sanitary sewer or dispose with other sanitary waste.

1 - IDENTIFICATION

VIII - SPECIAL PROTECTION INFORMATION

PRODUCT NAME: (ECS) ENVIRO-SAFE COIL CLEANER

PACKAGE TYPE: 1, 5, 55 gal

PREPARED DEPARTMENT OF HAZARDOUS COMMUNICATIONS

DATE PREPARED: June 2003

RESPIRATORY: Required in misty conditions
EYE: Chemical goggles with side shields

II - HAZARDOUS INGREDIENTS
PRINCIPLE HAZARDOUS COMPONENT(S)
(CHEMICAL NAMES)
None known

CAS NO

ACGIH TLV

OSHA

PEL

% or RANGE

SKIN: Required to prevent skin contact

PROTECTIVE GLOVES: Required

OTHER: Follow good housekeeping practices/Empty container may contain hazardous residue. Do not reuse for food or drink.
VENTILATION REQUIREMENTS: Recommended for enclosed areas

IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed when not in use. Do not freeze. Follow label
instructions.

III - PHYSICAL DATA
BOILING POINT ( 0F) : 2140F
VAPOR PRESSURE (mm Hg) : NA

SPECIFIC GRAVITY (H20= 1) : 1.09

VAPOR DENSITY (Air = 1) : NA

EVAPORATION RATE (H20 = 1) : 14.0

pH : 8.5

APPEARANCE AND ODOR : Clear, no odor liquid

MELTING POINT: N/A

SPECIAL PRECAUTIONARY STATEMENTS: Keep this and all chemicals out of reach of children.
NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on
experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be
confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of
merchantability fitness or otherwise is made.

SOLUBILITY IN WATER : Complete

IV - FIRE AND EXPLOSION HAZARD DATA
FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Flash Point - Not Flammable

SARA Title III Reporting Requirements

SPECIAL FIRE FIGHTING PROCEDURES: Keep containers cool with water spray
UNUSUAL FIRE AND EXPLOSION HAZARDS: None known

V - REACTIVITY DATA
CHEMICAL
STABILITY

UNSTABLE

302

(Extremely Hazardous Substances): Reporting not required.

304/CERCLA

(Spills Notification): Not required.

311

Community Right-To-Know, RTK): Reporting not required.

312

(RTK Inventory Data): Not required.

CONDITIONS TO AVOID:

STABLE

X

INCOMPATIBILITY (Materials to avoid): Avoid oxidizers or acids
HAZARDOUS DECOMPOSITION PRODUCTS: Heat, carbon dioxide, carbon monoxide
HAZARDOUS
POLYMERIZATION

MAY OCCUR

CONDITIONS TO AVOID:

WILL NOT OCCUR

X

VI - HEALTH HAZARD AREA
ROUTE(S) OF ENTRY:

EYES Yes

SKIN Yes

INGESTION Yes

313

(Emissions and Releases): Reporting not required.

DOT

NOT HAZARDOUS

INHALATION Yes
References

EFFECTS OF OVER EXPOSURE:
INHALATION: Mists are corrosive to respiratory tract

TOXIC SUBSTANCE CONTROL CT LIST (TSCA) - INGREDIENTS LISTED

SKIN CONTACT/ABSORPTION: Irritating

PERMISSIBLE EXPOSURE REFERENCES:
Registry of Toxic Effects of Chemical Substances.

INGESTION: Corrosive to digestive system

Title 29 Code of Federal Regulations.
National Toxicology Program (NTP) Report on Carcinogens.

EYES: Corrosive to eyes
CARCINOGENICITY:

NTP? Not listed

IARC MONOGRAPHS? Not listed

OSHA REGULATED? Not listed

EMERGENCY AND FIRST AID PROCEDURES:

International Agency for Research on Cancer (IARC) Monographs.
Title 40 Code of Federal Regulations

EYES AND SKIN: EYES - Wash with plenty of water for 15 minutes, lifting upper and lower lids. GET IMMEDIATE MEDICAL ATTENTION. SKIN - REGULATORY STANDARDS:
Rinse skin with water. If irritation results apply skin cream and discontinue use.
DOT Title 49 Code of Federal Regulations 172.101
INHALATION: Move to fresh air. If breathing is difficult seek IMMEDIATE medical attention
INGESTION: Drink water or orange juice to dilute. DO NOT induce vomiting, GET IMMEDIATE MEDICAL ATTENTION, call Poison Control Center

SARA Title III
Nuclear Regulatory Commission

1

Atlantic Chemical Equipment Co.
2190 DeFoor Hills Rd NW
Atlanta, GA 30318
404-355-5522

MATERIAL SAFETY DATA SHEET

PRODUCT NAME:

ACESEAL MASTIC 181 (MAS)

EMERGENCY PHONE: 1-800-424-9300

VII - PRECAUTIONS FOR SAFE HANDLING AND USE

May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200.

Standard must be consulted for specific requirements. This product contains
no substances subject to SARA TITLE III and 40 CRF.

HMIS SYMBOLS
HEALTH

-

FLAMMABILITY

-

REACTIVITY

-

STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED:
SMALL SPILLS: Dilute and neutralize and wash to drain
LARGE SPILLS: Due to packaging, large spills cannot occur.
WASTE DISPOSAL METHOD: Deposit in landfill in accordance with local, state, and federal regulations.

1 - IDENTIFICATION

VIII - SPECIAL PROTECTION INFORMATION

PRODUCT NAME: (MAS) ACESEAL MASTIC 181

PACKAGE TYPE: 1, 2 gal

PREPARED DEPARTMENT OF HAZARDOUS COMMUNICATIONS

DATE PREPARED: June 2003

RESPIRATORY: None required in ventilated areas.
EYE: Follow good industrial practice by wearing safety glasses.

II - HAZARDOUS INGREDIENTS
PRINCIPLE HAZARDOUS COMPONENT(S)
(CHEMICAL NAMES)
Ammonium Hydroxide (29%)
Methyl Alcohol

OSHA

PEL

CAS NO

ACGIH TLV

1136-21-6

10 mg/cu. M

10 mg/cu. M

0.07

67-56-1

250 ppm

250 ppm

2.9

% or RANGE

SKIN: No significant concern.

PROTECTIVE GLOVES: Chemical resistant rubber or plastic.

OTHER: N/A
VENTILATION REQUIREMENTS: General good ventilation is recommended.

IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed when not in use. Store with adequate
ventilation.

III - PHYSICAL DATA
BOILING POINT ( 0F) : 1000F
VAPOR PRESSURE (mm Hg) : N/E

SPECIFIC GRAVITY (H20= 1) : 1.37

VAPOR DENSITY (Air = 1) : N/E

EVAPORATION RATE (H20 = 1) : Less than 1

pH : NA

APPEARANCE AND ODOR : White or gray with slight ammonia odor

MELTING POINT: N/A

SPECIAL PRECAUTIONARY STATEMENTS: Keep this and all chemicals out of reach of children.

SOLUBILITY IN WATER : Soluble

IV - FIRE AND EXPLOSION HAZARD DATA

NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on
experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be
confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of
merchantability fitness or otherwise is made.

FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Flash Point Non TCC
SARA Title III Reporting Requirements

SPECIAL FIRE FIGHTING PROCEDURES: None, however firefighters should always use self contained breathing apparatus as nitrogen oxides and
carbon monoxides may be involved.
UNUSUAL FIRE AND EXPLOSION HAZARDS: None

V - REACTIVITY DATA
CHEMICAL
STABILITY

UNSTABLE

302

(Extremely Hazardous Substances): Reporting not required.

304/CERCLA

(Spills Notification): Not required.

311

Community Right-To-Know, RTK): Reporting not required.

312

(RTK Inventory Data): Not required.

CONDITIONS TO AVOID:

STABLE

X

INCOMPATIBILITY (Materials to avoid): Materials that react with water
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, ammonia, nitrogen oxides
HAZARDOUS
POLYMERIZATION

MAY OCCUR

CONDITIONS TO AVOID:

WILL NOT OCCUR

X

VI - HEALTH HAZARD AREA
ROUTE(S) OF ENTRY:

EYES

SKIN

INGESTION

313

(Emissions and Releases): Reporting not required.

DOT

NOT HAZARDOUS

INHALATION
References

EFFECTS OF OVER EXPOSURE: No evidence
INHALATION: N/E

TOXIC SUBSTANCE CONTROL CT LIST (TSCA) - INGREDIENTS LISTED

SKIN CONTACT/ABSORPTION: N/E

PERMISSIBLE EXPOSURE REFERENCES:
Registry of Toxic Effects of Chemical Substances.

INGESTION: N/E

Title 29 Code of Federal Regulations.
National Toxicology Program (NTP) Report on Carcinogens.

EYES: N/E
CARCINOGENICITY:

NTP? Not listed

IARC MONOGRAPHS? N/L

OSHA REGULATED? II for exposure limits

EYES AND SKIN: EYES - Wash with plenty of water for 15 minutes. GET IMMEDIATE MEDICAL ATTENTION.
with running water and soap and water.
INHALATION: Move to fresh air. If breathing difficult seek IMMEDIATE medical attention

International Agency for Research on Cancer (IARC) Monographs.
Title 40 Code of Federal Regulations

EMERGENCY AND FIRST AID PROCEDURES:
SKIN - Wash well

REGULATORY STANDARDS:
DOT Title 49 Code of Federal Regulations 172.101
SARA Title III

INGESTION: DO NOT INDUCE VOMITING. Vomiting may cause pulmonary edema which may be fatal. GET IMMEDIATE MEDICAL ATTENTION. Nuclear Regulatory Commission
CALL POISON CONTROL CENTER - contains sulfite and caustic.

1

SAFETY DATA SHEET
LEAK DETECTOR SPRAY

Page 1
Issued: 08/06/2005
Revision No: 2

1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING
Product name: LEAK DETECTOR SPRAY
Product code: 32030
Company name: ROCOL Lubricants
ROCOL House
Swillington
Leeds
West Yorkshire
LS26 8BS
ENGLAND
Tel: +44 (0) 113 232 2700
Fax: +44 (0) 113 232 2740
Emergency tel: +44 (0) 113 232 2600

2. COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous ingredients: AMIDE DERIVATIVE 1-5%
[Xi] R36/38

3. HAZARDS IDENTIFICATION
Main hazards: None

4. FIRST AID MEASURES (SYMPTOMS)
Skin contact:
Eye contact:
Ingestion:
Inhalation:

There may be mild irritation at the site of contact.
There may be irritation and redness.
There may be irritation of the throat.
No symptoms.

4. FIRST AID MEASURES (ACTION)
Skin contact:
Eye contact:
Ingestion:
Inhalation:

Wash immediately with plenty of soap and water.
Bathe the eye with running water for 15 minutes. Consult a doctor.
Wash out mouth with water. Do not induce vomiting. Consult a doctor.
Remove casualty from exposure ensuring one's own safety whilst doing so.

5. FIRE-FIGHTING MEASURES
Extinguishing media: Use water spray to cool containers.
Protection of fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin
and eyes.

6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Refer to section 8 of SDS for personal protection details.
Environmental precautions: Do not discharge into drains or rivers.
Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by
an appropriate method.

7. HANDLING AND STORAGE
Handling requirements: Ensure there is sufficient ventilation of the area.
Storage conditions: Store in cool, well ventilated area. Keep away from sources of ignition. Keep away from direct
sunlight.
Suitable packaging: Must only be kept in original packaging.

[cont...]

Issued: 08/06/2005

SAFETY DATA SHEET
LEAK DETECTOR SPRAY

Page 2

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering measures:
Respiratory protection:
Hand protection:
Eye protection:
Skin protection:

Ensure there is sufficient ventilation of the area.
Respiratory protection not required.
Protective gloves.
Safety glasses with side-shields.
Protective clothing.

9. PHYSICAL AND CHEMICAL PROPERTIES
State:
Colour:
Odour:
Evaporation rate:
Oxidising:
Solubility in water:
Viscosity:
Boiling point/range°C:
Melting point/range°C:
Flash point°C:
Autoflammability°C:
Relative density:

Aerosol
Colourless
Odourless
Slow
Non-oxidising (by EC criteria)
Miscible in all proportions
Non-viscous
100
0
> 200
>200
1

10. STABILITY AND REACTIVITY
Stability:
Conditions to avoid:
Materials to avoid:
Haz. decomp. products:

Stable under normal conditions.
Direct sunlight. Heat. Sources of ignition.
Strong oxidising agents. Strong reducing agents.
In combustion emits toxic fumes of carbon dioxide / carbon monoxide.

11. TOXICOLOGICAL INFORMATION
Routes of exposure: Refer to section 4 of SDS for routes of exposure and corresponding symptoms.

12. ECOLOGICAL INFORMATION
Mobility: Volatile. Readily absorbed into soil.
Persistence and degradability: Biodegradable.
Bioaccumulative potential: No bioaccumulation potential.

13. DISPOSAL CONSIDERATIONS
Disposal of packaging: Dispose of in a regulated landfill site or other method for hazardous or toxic wastes.
NB: The user's attention is drawn to the possible existence of regional or national regulations
regarding disposal.

14. TRANSPORT INFORMATION
ADR / RID
UN no:
Classification code:
Shipping name:
Labelling:

1950
5A
AEROSOLS
2.2

ADR Class: 2

[cont...]

Issued: 08/06/2005

SAFETY DATA SHEET
LEAK DETECTOR SPRAY

Page 3

IMDG / IMO
UN no: 1950
EmS: F-D,S-U
Labelling: 2.2

Class: 2
Marine pollutant: .

IATA / ICAO
UN no: 1950
Labelling: 2.2

Class: 2

15. REGULATORY INFORMATION
Hazard symbols: No significant hazard.
Risk phrases: None
Safety phrases: S16: Keep away from sources of ignition - No smoking.
S23: Do not breathe spray.
S51: Use only in well-ventilated areas.
Precautionary phrases: Safety data sheet available for professional user on request.
Pressurized container: protect from sunlight and do not expose to temperatures exceeding
50°C. Do not pierce or burn, even after use.
Note: The regulatory information given above only indicates the principal regulations specifically
applicable to the product described in the safety data sheet. The user's attention is drawn to
the possible existence of additional provisions which complete these regulations. Refer to all
applicable national, international and local regulations or provisions.

16. OTHER INFORMATION
Other information: EC Directive 1999/45/EC relating to the classification, packaging and labelling of dangerous
preparations.
EC Directive 91/155/EEC defining the laying down and detailed arrangements for the system of
specific information relating to dangerous preparations.
EC Directive 94/1/EC adapting some technicalities of Council Directive 75/324/EEC on the
approximation of the laws of Member States relating to aerosol dispensers.
Risk phrases used in s.2: R36/38: Irritating to eyes and skin.
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall
be used only as a guide. This company shall not be held liable for any damage resulting from
handling or from contact with the above product.

[final page]

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name: NEUTRAZEN Natural Scents (Metered Cans)
491143 Black Cherry
491120 Country Garden
491375 Gingerbread
491275 Candy Cane
491605 Cranberry Spice
491855 Green Apple
491113 Cinnamon
491250 Dutch Apple
491163 Hawaiian Kiss
491505 Citrus Creme
491333 Fresh Linen
491705 Mango
491125 Citrus Peel
491525 Fruit Basket
491755 Orchard Spice
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

491805 Peach Kiwi
491955 Pina Colada
491025 Pine Forest
491905 Powder Fresh
491655 Tropical Nectar
491555 Vanilla Delight

______________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Acetone
Propane
Isobutane
n-Butane
Fragrance

CAS No.:
67-64-1
74-98-6
75-28-5
106-97-8
Not available

TLV:
500ppm
2500ppm
Not established
800ppm
Not available

______________________________________________________________________________

SECTION 3

Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA

<0 to 1330 F
Slightly
Clear

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5

Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.
First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

SECTION 9

SPILL OR LEAK PROCEDURE

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________
Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None
__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491143,491275,491113,491505,491125,491120,491605,491250,491333,491525,491375, 491855,491163,
491705,491755,491805, 491955, 491025, 491905, 491655, 491555

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name: NEUTRAZEN Natural Scents (Metered Cans)
491143 Black Cherry
491120 Country Garden
491375 Gingerbread
491275 Candy Cane
491605 Cranberry Spice
491855 Green Apple
491113 Cinnamon
491250 Dutch Apple
491163 Hawaiian Kiss
491505 Citrus Creme
491333 Fresh Linen
491705 Mango
491125 Citrus Peel
491525 Fruit Basket
491755 Orchard Spice
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

491805 Peach Kiwi
491955 Pina Colada
491025 Pine Forest
491905 Powder Fresh
491655 Tropical Nectar
491555 Vanilla Delight

______________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Acetone
Propane
Isobutane
n-Butane
Fragrance

CAS No.:
67-64-1
74-98-6
75-28-5
106-97-8
Not available

TLV:
500ppm
2500ppm
Not established
800ppm
Not available

______________________________________________________________________________

SECTION 3

Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA

<0 to 1330 F
Slightly
Clear

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5

Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.
First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

SECTION 9

SPILL OR LEAK PROCEDURE

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________
Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None
__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491143,491275,491113,491505,491125,491120,491605,491250,491333,491525,491375, 491855,491163,
491705,491755,491805, 491955, 491025, 491905, 491655, 491555

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name: NEUTRAZEN Natural Scents
491153 Cinnamon
491105 Citrus Creme
491325 Citrus Peel
491235 Cranberry Spice
491123 Fresh Linen
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

(Hand Held Cans)
491075 Fruit Basket
491255 Green Apple
491455 Mango
491155 Orchard Spice
491405 Peach Kiwi

491355 Pina Colada
491305 Powder Fresh
491055 Tropical Nectar
491205 Vanilla Delight

ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Dimethyl Ketal
Isobutane
Propane
Butane
Fragrance

CAS No.:
67-64-1
75-28-5
74-98-6
106-97-8
Not available

TLV:
500ppm
Not established
2500ppm
800ppm
Not available

______________________________________________________________________________

SECTION 3

Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA

<0 to 1330 F
Slightly
Clear

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5

Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.
First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

SECTION 9

SPILL OR LEAK PROCEDURE

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________
Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None
__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491153,491105,491325,491235,491123,491075,491255,491455,491155,491405,491355,491305,491055, 491205

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name: NEUTRAZEN Natural Scents
491153 Cinnamon
491105 Citrus Creme
491325 Citrus Peel
491235 Cranberry Spice
491123 Fresh Linen
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

(Hand Held Cans)
491075 Fruit Basket
491255 Green Apple
491455 Mango
491155 Orchard Spice
491405 Peach Kiwi

491355 Pina Colada
491305 Powder Fresh
491055 Tropical Nectar
491205 Vanilla Delight

ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Dimethyl Ketal
Isobutane
Propane
Butane
Fragrance

CAS No.:
67-64-1
75-28-5
74-98-6
106-97-8
Not available

TLV:
500ppm
Not established
2500ppm
800ppm
Not available

______________________________________________________________________________

SECTION 3

Boiling Point:
Solubility in Water:
Physical Description:

PHYSICAL DATA

<0 to 1330 F
Slightly
Clear

Specific Gravity(H2O=1):
Evaporation Rate:
Vapor Density(Air=1):

0.80 + 0.05
Slower than Ether
Heavier than air

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.8
UEL: 9.5
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5

Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.
First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

SECTION 9

SPILL OR LEAK PROCEDURE

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________
Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None
__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
491153,491105,491325,491235,491123,491075,491255,491455,491155,491405,491355,491305,491055, 491205

Date:
Supercedes:

15 October 2007
15 November 2004

MATERIAL SAFETY DATA SHEET
IN CASE OF EMERGENCY CALL CHEMTREC AT 1-800-424-9300

1.

2.

PRODUCT IDENTIFICATION AND COMPANY IDENTIFICATION:
Product Name:

GOJO® PINK CONCENTRATE HAND SOAP

Company Name & Address:

GOJO Industries, Inc.
One GOJO Plaza, Suite 500
Akron, OH 44311

Emergency Phone:
Non-Emergency Phone:
MSDS Request Phone:

1-800-424-9300 CHEMTREC
(330) 255-6000
(330) 255-6000 x8804

INFORMATION ON INGREDIENTS:
HAZARDOUS INGREDIENTS
Ammonium Chloride as dust

CAS NUMBER
12125-02-9

Not established

Other ingredient(s) with notification requirements:
Sodium Lauryl Sulfate
Ammonium Chloride
3.

OSHA PEL

ACGIH TLV
TWA: 10 mg/m

CAS NUMBER

List

151-21-3

CN 1

12125-02-9

% RANGE
3

<3

MA 1; NJ 1;PA 1; CN 1

HAZARDS IDENTIFICATION:
EMERGENCY OVERVIEW
When used according to instructions, the product applicable to this MSDS is safe and presents no
immediate or long-term health hazard. However, abnormal entry routes, such as gross ingestion, may
require immediate medical attention.
Potential Health Effects:

4.

HMIS:

Health

1 Flammability

0 Reactivity

0 Personal Protection None

Eye Contact:
Skin Contact:
Inhalation:
Ingestion:
Carcinogenicity:

May cause eye irritation.
No irritation or reaction expected.
Not applicable.
May cause upset stomach, nausea (Abnormal entry route).
Not listed as a carcinogen by NTP, IARC, OSHA or ACGIH.

FIRST AID MEASURES:
Eye Contact:
Skin Contact:
Inhalation:
Ingestion:

Do not rub eyes. Flush eyes thoroughly with water for 15 minutes. If condition
worsens or irritation persists, contact physician.
Not applicable.
Not applicable.
Do not induce vomiting. Contact a physician or Poison Control Center.

GOJO® PINK CONCETRATE HAND SOAP
5.

Page 2 of 2

FIRE FIGHTING MEASURES:
NFPA:

Health

0 Fire

Flashpoint °F/°C (PMCC method):
Not determined.
Unusual Fire and Explosion Hazards: None known.
Special Fire Fighting Procedures:
None known.
Extinguishing Media: X Water Fog X Alcohol Foam
6.

0 Reactivity

X

CO2

X

0

Dry Chemical

Other

ACCIDENTAL RELEASE MEASURES:
No special requirements. Water clean up and rinse. CAUTION – WILL CAUSE SLIPPERY SURFACES.

7.

HANDLING AND STORAGE:
Store at normal room temperature away from reach of small children. Keep containers sealed. Use older
containers first. Avoid freezing conditions.

8.

EXPOSURE CONTROLS/PERSONAL PROTECTION:
Eye Protection:
Skin Protection:
Respiratory Protection:
Ventilation:
Protective Equipment or Clothing:

9.

PHYSICAL AND CHEMICAL PROPERTIES:
Appearance and Odor
pH (undiluted):
VOC , %:

10.

None required under normal conditions.
None required under normal conditions.
None required under normal conditions.
None required under normal conditions.
None required under normal conditions.

Pink pearlescent liquid, coconut fragrance
4.5 – 9.5
0

STABILITY AND REACTIVITY:
Stable/Non reactive product.

11.

TOXICOLOGICAL INFORMATION:
No acute or chronic toxic effects expected when used according to directions.

12.

ECOLOGICAL CONSIDERATIONS:
No ecological or special considerations when used according to directions. Not considered environmentally
harmful from normal dilution, expected usage and typical drainage to sewers, septic systems and treatment
plants.

13.

DISPOSAL CONSIDERATIONS:
No special considerations when disposed according to local, state and Federal regulations.

14.

TRANSPORT INFORMATION:
Not classified as a hazardous material.

15.

REGULATORY AND OTHER INFORMATION:
TSCA: All ingredients are listed or exempt per reference 15 USC 2602 (2)(B)(iv).
Complies with current FDA regulations for cosmetic and/or over-the-counter drug products.
Notice: The information herein is based on data considered to be accurate as of the date of preparation of this material safety data sheet.
However, no warranty or representation, expressed or implied, is made as to the accuracy or completeness of the foregoing data and
safety information. The user assumes all liability for any damage or injury resulting from abnormal use, from any failure to adhere to
recommended practices or from any hazards inherent in the nature of the product.

Document#: 9400-500

Page 1 of 4
The Procter & Gamble Company
P&G Household Care
Fabric & Home Care Innovation Center
5299 Spring Grove Avenue
Cincinnati, OH 45217-1087

MATERIAL SAFETY DATA SHEET
MSDS #:
Supersedes:

FH/H/2003/TWTA-5HRJZ8
MSDS issued March 4, 2004

Issue Date: May 9, 2006
Issue Date: Not Applicable

SECTION I - CHEMICAL PRODUCT
Identity: Mr Clean Magic Eraser Original, Duo, Extra Strength

Finished Product

Brands: MR CLEAN Magic Eraser
P&G Telephone Number: 1-800-248-1612 or call your Poison Control Center or your physician
SECTION II - COMPOSITION AND INGREDIENTS
Mr. Clean Magic Eraser is a melamine foam with cleaning agents.
Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200.
Common
CAS No.
Composition Range
Chemical Name
Name
(Wet Chemistry
None

LD50/LC50

SECTION III - HAZARDS IDENTIFICATION
Potential Health Hazards (Acute and Chronic): (See Section 11 for more information)
Ingestion: Blockage of the gastrointestinal tract may occur if swallowed. Do not ingest
Eye Contact: Irritating to eye
Skin Contact: Irritating to skin
Inhalation: Ensure adequate ventilation
Signs and Symptoms of Exposure:
Ingestion: May caust irritation and/or bloacage of the gastroinstestinal track.
Eye Contact: Dust from foam may cause mechanical irritation.
Skin Contact: Dust from foam may cause mechanical irritation.
Inhalation: Dust from foam may cause irritation of the respiratory track.
Medical Conditions Generally Known to be Aggravated by Exposure:
Potential Environmental Effects: (See Section 12 for more information)
SECTION IV – FIRST AID INFORMATION
First Aid Procedures:
Ingestion: If foam is ingested, contact a physician or veterinarian immediately. Intestinal blockage may be life
threatening to some household pets.
Eye Contact: In case of eye irritation, flush thoroughly with water for 15 minutes. If irritation persisits, seek
medical advice.
Skin Contact: In case of skin irritation, flush affected area thoroughly with water and apply a cold compress. If
irritation persists, seek medical advise. Remove any contaminated clothing.
Inhalation:If respiratioy irritation occurs, moving from the site of exposure to an area with fresh air. If irritation
perists, seek medical advise.
Note to Physician: (if applicable): Treat symptomatically.
Other: Consumer product package has the following precautionary statement: “Caution: keep out of reach of
children. Keep out of reach of toddlers and pets to avoid accidental ingestion. Do not use on skin or other parts of
the body. Using on skin will likely cause abrasions.”

Mr Clean Magic Eraser Plus Foaming Cleaner

Page 2 of 4

SECTION V - FIRE FIGHTING INFORMATION
Flammable Properties: 580 C/ 1076F
Extinguishing Media:
Suitable: Regular dry chemical, carbon dioxide, water, regular foam. For large fires: use regulary foam of flood
with fine water spray.
Unsuitable: NA
Protection of Firefighters:
Specific Hazards Arising from the Material:

Dust / air mixture may cause explosion.

Protective Equipment and Precautions for Firefighters:
SECTION VI - ACCIDENTAL RELEASE MEASURES
Personal Precautions: None Known
Environmental Precautions: Disposal is to be performed in compliance with all Federal, State, Provincial and
Local Regulations.
Methods for Containment: Collect spilled material in an approporate container for disposal.
Methods for Cleanup: Keep out of water supplies and sewers.
Other Information: (if applicable) Keep unnecessary people away, isolate hazard and deny entry to area.
SECTION VII – HANDLING AND STORAGE
Precautions To Be Taken in Handling: None known.
Precautions To Be Taken in Storage:: None known.
SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION
Exposure Guidelines:
Engineering Controls: Provide local ventilation
Personal Protective Equipment (PPE): Under conditions of frequent use or heavy exposure, respiratory
protection may be needed. (Any chemical cartridge respirator with an organic vapor cartridge(s), dust and mist
filter(s)).
Eye/Face Protection: Provide an emergenacy eye wash fountain and quick drench shower in the immediate work
area.
Skin Protection: Do not rub on skin, foam can cause abrasion to skin.
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Appearance (color, physical form, shape):

Flash Point (Method Used): NK

White and Yellow foam
Odor: None

Explosive Limits:

LEL:

Odor Threshold: Not applicable

Auto-Ignition Temperature: NK

Physical State: foam

Decomposition Temperature: NK

Vapor Pressure (mm Hg): NK

Evaporation Rate (nBuOAc=1): NK

Vapor Density (Air=1): NA

Specific Gravity/Density: NK

Boiling Point: NA

Melting/Freezing Point: NK

Partition Coefficient (n-octanol/water): NA

pH: Not applicable

Solubility in Water: Yes

Reserve Alkalinity: Not applicable

UEL:

2

Mr Clean Magic Eraser Plus Foaming Cleaner

Page 3 of 4

SECTION X - STABILITY AND REACTIVITY
Chemical Stability: Stable at normal temperatures and pressures
Conditions to Avoid: Avoid heat, flames, sparks, and other sources of ignition. Avoid contact with incompatable
materials.
Incompatible Materials: Oxizidizing materials
Hazardous Decomposition Products: Oxides of carbon, oxides of sulfur, aromatic compounds, formaldehyde,
hydrogen cyanide.
Possibility of Hazardous Reactions: None known

SECTION XI - TOXICOLOGICAL INFORMATION
Do not use on skin or other parts of the body. Using on skin will likely cause abrasions.

Chronic Effects: No chronic health effects reported.
Target Organs: No target organs reported.
Carcinogenicity: NTP: No IARC: No
OSHA: No

SECTION XII - ECOLOGICAL INFORMATION
Not available.
SECTION XIII - DISPOSAL CONSIDERATIONS
Waste Disposal Method:
Industrial Setting: Products covered by this MSDS, in their original form, when disposed as waste, are

considered non hazardous waste according to Federal RCRA regulations (40 CFR 261). Disposal should
be in accordance with local, state/provincial and federal regulations.
Household Use: Product used in household may be disposed of in refuse.

SECTION XIV - TRANSPORT INFORMATION
Ground Transport (US DOT): Not Regulated
Air Transport (IATA): Not Regulated
Marine/Water Transport (IMDG): Not Regulated

SECTION XV - ADDITIONAL REGULATORY INFORMATION

While this finished product is not considered hazardous as defined by OSHA in 29 CFR 1910.1200 (d),
this MSDS contains valuable information critical to the safe handling and proper use of the product.
All intentionally-added components of this product are listed on the US TSCA Inventory.

EPA Reg. No: Not applicable
This product is not subject to warning labeling under California Proposition 65.

Canada
All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been
classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR)
and this MSDS contains all information required by the Controlled Products Regulations.

3

Mr Clean Magic Eraser Plus Foaming Cleaner

P&G Hazard Rating:

*N/A. - Not Applicable

Page 4 of 4

SECTION XVI - OTHER INFORMATION
Health:
1
4=EXTREME
Flammability: 1
3=HIGH
Reactivity:
0
2=MODERATE
1=SLIGHT
0=NOT SIGNIFICANT
*N/K. - Not Known

Data supplied is for use only in connection with occupational safety and health.
The information contained herein has been compiled from sources considered by Procter & Gamble to be
dependable and is accurate to the best of the Company’s knowledge. The information relates to the specific
material designated herein, and does not relate to the use in combination with any other material or any other
process. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, for any damage to
any property resulting from misuse of the controlled product.

4

PRO-LINK
MATERIAL SAFETY DATA SHEET
PRO-LINK
510 CHAPMAN STREET
CANTON, MA 02021

Data Sheet No.
Issue Date 5/7/99
Issued By J. Irwin

PH: 781-828-9550
FX: 781-828-9551

SECTION 1
Trade Name/Synonyms

1401 Urinal Screen - Red/Cherry

Chemical Name/Synonyms
Chemical Family/Formula

SECTION 2 - Product/Component Data
Component(s) Chemical Name
Di (2-Ethylhexy 1) Phthalate

CAS Registry
117-81-7

% Approx. OSHA/PEL
<45.0

ACGIH TLV-TWA

5mg/m#
5mg/m3

SECTION 3 - Physical Data
Boiling Point (F)

Data Not Available
Data Not Available

Vapor Pressure (mm Hg)
Vapor Density (Air = 1)

N/A

Appearance and Odor

1.39

%, Volatile by Volume
Evaporation Rate (_ = 1)

N/A

Solubility in Water

Specific Gravity (H O = 1)

Melting Point

N/A
330 F

Pellet, slight odor

SECTION 4 - Fire & Explosion Hazard Data
Flash Point (Method Used)

Flammable Limits

N/A

LEL

UCL

N/A

N/A

Extinguishing Media

Water is most effective. ABC dry chemical, APPP and protein type air foam

Special Fire Fighting Procedures

self-contained breathing apparatus and turnout equipment should be worn

Unusual Fire & Explosion Hazards

NFPA Codes:

None under normal processing conditions
Flammability:
Health:

NE = Not Established
NA = Not Applicable

Reactivity:

SECTION 5 - Health Hazard Data
Route(s) of Entry

Inhalation: Yes (as fumes) Skin: No Ingestion: Yes
Effects of Overexposure
Health Hazards: Contains hazardous chemicals subject to the reporting requirements of Section
313 of the Emergency Planning and Community Right To Know Act of 1986. Fumes produced during normal hot melt processing may cause irritation to the eyes, respiratory tract or skin of employees who may be sensitive to these fumes.
Emergency/First Aid Procedures
Thoroughly wash skin with soap and water. If affected by fumes, remove to fresh air. If swallowed, induce vomiting by means of finger
in throat, salt water, or syrup of Ipecak. Call physician.

SECTION 6 - Reactivity Data
Stability

__Stable
__Unstable
X

Incompatibility (Materials to Avoid)

Conditions to Avoid Avoid prolonged/excessive heating; 1 hr. at 350 F 10 mins.; at 400 F
and 5 mins. at 450 F.

Oxidizing agents

Hazardous Decomposition Products
Hydrogen chloride, carbon monoxide and carbon dioxide
Conditions to Avoid

Hazardous Polymerization

___May Occur

___Will
Not Occur
X

None during normal use

SECTION 7 - Spill or Leak Procedures
Steps To Be Taken In Case Material is Released/Spilled

Normal housekeeping procedures
Waste Disposal Method

Do not incinerate. Dispose of waste in a licensed landfill in accordance with federal, state, and local regulations.

SECTION 8 - Special Protection Information
Respiratory Protection (Specify Type)
Ventilation

Not under normal processing conditions using adequate ventilation.
Special N/A
Local Exhaust As needed to remove fumes.
Mechanical (General) As needed to remove fumes. Other
N/A

Protective Gloves

Heat impervious gloves to handle hot melt

Eye Protection

Safety glasses in all industrial workplaces

Other Protective Equipment

Not normally required.

SECTION 9 - Special Precautions
Precautions To Be Taken In Handling and Storing

None - Always practice good housekeeping and hygienic measures.

This information is given in good faith but no warranty, expressed or implied, is made. Impact Products, Inc.
believes that it is accurate to the best of its knowledge and relates only to the specific material designated herein.

MATERIAL SAFETY DATA SHEET
HMIS HAZARD RATINGS

OSHA - Meets 29 CFR 1910.1200 Standards

HEALTH
FLAMMABILITY
REACTIVITY

3 = HIGH
4 = EXTREME

0 = INSIGNIFICANT
1 = SLIGHT
2 = MODERATE

2
2
0

TRANSPORTATION INFORMATION
PROPER SHIPPING NAME:

Environmentally hazardous substance, solid, n.o.s. (pdichlorobenzene)

HAZARD CLASS / PKG GRP:
IDENTIFICATION NUMBER:

9 / III
UN 3077

REF:
LABEL:

49 CFR 173.155, .213, .240
Miscellaneous

SECTION 1 - PRODUCT / COMPANY IDENTIFICATION
IDENTITY (AS USED ON LABEL AND LIST)

PARADICHLOROBENZENE BLOCKS
MANUFACTURER'S NAME
Hospital Specialty Company
ADDRESS (NUMBER, STREET, P.O. BOX)
670 Alpha Drive
(CITY, STATE AND ZIP CODE)
Highland Heights, OH 44143

( 08161, 08241, 08411, 06301, 06311, 06931, 06401,
Page 1 of 2
06411, 06901, 01931, 01991 )
EMERGENCY TELEPHONE NUMBER
CHEM • TEL (800) 255-3924 Outside USA (813) 248-0585
TELEPHONE NUMBER FOR INFORMATION
(440) 720-1800
DATE PREPARED:
April 21, 2005
SUPERSEDES:
December 15, 2001; March 18, 2002

SECTION 2 - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION
HAZARDOUS COMPONENTS
(SPECIFIC CHEMICAL IDENTITY; COMMON NAME(S))

CAS #

p-Dichlorobenzene (a,b,c,d,e,f)

106-46-7

%
(OPTIONAL)

60 - 100

OSHA PEL
PPM

75

MG/M

ACGIH TWA
3

PPM

450

10

MG/M

3

SARA

RQ

TITLE III

LBS

Yes

100

(a) Indicates a toxic chemical subject to annual reporting requirements of Section 313 of SARA Title III of the Emergency Planning and Community Right-ToKnow Act of 1986 and of 40 CFR 372.
(b) Indicates that the Resource Conservation and Recovery Act (RCRA) has determined the waste for this chemical is listed as hazardous and must be handled
according to regulations in 40 CFR 260-281.
(c) The Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) has notification requirements for releases or spills to the
environment of the Reportable Quantity (RQ for this mixture = 100 lbs) or greater amounts, according to 40 CFR 302.
(d) Indicates substance appears on National Toxicology Program (NTP) list of carcinogens, International Agency for Research on Cancer (IARC) list of
carcinogens or is regulated by the Occupational Safety and Health Administration (OSHA) as a possible carcinogen.
(e) California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986, chemicals known to the state to cause cancer or reproductive toxicity. A person
in the course of doing business must warn others who may consume, come into contact with, or otherwise be exposed to this chemical.
(f) Product is listed or defined as a marine pollutant in IMDG Code or 49 CFR 172.101 Appendix B, List of Marine Pollutants and must be classified as an
Environmentally Hazardous Substance, Class 9, in addition to any other defined hazards for this product.

SECTION 3 - HEALTH HAZARD DATA
ROUTES OF ENTRY - SIGNS AND SYMPTOMS OF EXPOSURE

EMERGENCY AND FIRST AID PROCEDURES

INHALATION: Inhalation of dust or vapors may irritate the respiratory tract; may
cause headache, dizziness, nausea, vomiting, weight loss and liver and kidney
damage. May also cause swelling around the eyes and runny nose.

Remove affected person to fresh air; provide oxygen if breathing is difficult; if
affected person is not breathing, administer CPR and seek emergency
medical attention.

SKIN: Causes skin irritation, with a slight burning sensation. Red blotching of
the skin due to allergic reactions may occur. May be absorbed through the skin;
symptoms may parallel inhalation.

Remove contaminated clothing; wash affected area with soap and water;
launder contaminated clothing before reuse; if irritation persists, seek medical
attention.

EYES: Contact causes severe irritation and pain associated with redness and
swelling of the conjunctiva.

Remove contact lenses. Flush eyes with clear running water for 15 minutes
while holding eyelids open; if irritation persists, seek medical attention.

INGESTION: Material is toxic; may cause headache, dizziness,; may cause
headache, dizziness, diarrhea and general weakness; swallowing can produce
adverse health effects paralleling inhalation.

Give two glasses of water for dilution; Induce vomiting by sticking fingers
down throat; never give anything by mouth to an unconscious person; seek
medical attention.

IARC MONOGRAPHS?
OSHA REGULATED?
CARCINOGENICITY
NTP?
Yes
Yes
p-Dichlorobenzene is listed as an anticipated carcinogen by NTP and 2B possibly carcinogenic to humans by IARC.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Preexisting skin, eye, or respiratory disorders may become aggravated through
prolonged exposure.

No

Form revised 09 / 01

MATERIAL SAFETY DATA SHEET
IDENTITY (AS USED ON LABEL AND LIST)
PARADICHLOROBENZENE BLOCKS

( 08161, 08241, 08411, 06301, 06311, 06931,
06401, 06411, 06901, 01931, 01991 )

Page 2 of 2
Date:
March 18, 2002

SECTION 4 - FIRE FIGHTING MEASURES
FLASH POINT (METHOD USED)
151º F (66º C) CC

NFPA RATING
IIA

FLAMMABLE LIMITS
LEL: 2.5%

UEL: 16.0%

EXTINGUISHING MEDIA
Carbon dioxide, water, water fog, dry chemical, chemical foam
SPECIAL FIRE FIGHTING PROCEDURES
Airborne dusts may form explosive mixtures if allowed to concentrate in confined area. Contact with strong oxidizers may cause fire.
UNUSUAL FIRE AND EXPLOSION HAZARDS
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand
or other positive pressure mode.

SECTION 5 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: COMBUSTIBLE. Evacuate and ventilate area; avoid breathing dust. Recover and
segregate product for reuse; shovel product into approved container for disposal.; for spills in excess of allowable limits (RQ) notify the National Response Center
(800) 424 - 8802; refer to CERCLA 40 CFR 302 and SARA Title III, Section 313 40 CFR 372 for detailed instructions concerning reporting requirements. Do not
discharge into lakes, ponds, streams or public waters. P-Dichlorobenzene is listed as a Marine Pollutant.

SECTION 6 - HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: This material is combustible. It should be stored in tightly closed containers in a cool, dry, well
ventilated area. Vapor may form explosive mixtures in air. All sources of ignition should be controlled. Keep this and other chemicals out of reach of children.
Avoid inhaling concentrated fumes or vapors.

SECTION 7 - EXPOSURE CONTROLS / PERSONAL PROTECTION
RESPIRATORY PROTECTION (SPECIFY TYPE): None required while threshold limits (Section 2) are kept below maximum allowable concentrations; if TWA
exceeds limits, NIOSH approved respirator must be worn. Refer to 29 CFR 1910.134 or European Standard EN 149 for complete regulations.
VENTILATION

LOCAL EXHAUST: Required
SPECIAL: To maintain minimum TWA and STEL levels.
MECHANICAL (GENERAL): Yes
OTHER: Engineering and work controls as required.
PROTECTIVE GLOVES: Neoprene or rubber gloves with cuffs.
EYE PROTECTION: Protective eyeglasses or chemical safety goggles.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Coveralls, apron, or other equipment should be worn to minimize skin contact.
WORK / HYGIENIC PRACTICES: Practice safe workplace habits. Minimize body contact with this, as well as all chemicals in general.

SECTION 8 - PHYSICAL / CHEMICAL PROPERTIES
BOILING POINT
345º F (174º C)
VAPOR PRESSURE (MM Hg)
0.6 mm Hg @ 20° C
VAPOR DENSITY (AIR = 1)
5.08
SOLUBILITY IN WATER
Practically insoluble in water.
APPEARANCE AND ODOR
White / pink solid blocks, penetrating mothball odor

SPECIFIC GRAVITY (WATER = 1)
1.500
pH
Not determined
EVAPORATION RATE (WATER = 1)
Not applicable
% VOLATILE (BY WEIGHT)
100% @ 70º F

SECTION 9 - STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Extreme temperatures, open flames, avoid
UNSTABLE:
generating airborne dust
STABLE: XXX
INCOMPATIBILITY (MATERIALS TO AVOID): Oxidizing agents, aluminum and its alloys

STABILITY

HAZARDOUS DECOMPOSITION OR BYPRODUCTS: May produce carbon monoxide, carbon dioxide, hydrogen chloride and phosgene when heated to
decomposition.
HAZARDOUS POLYMERIZATION

MAY OCCUR:
WILL NOT OCCUR: XXX

CONDITIONS TO AVOID:
None

SECTION 10 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: Dispose of in accordance with Local, State, and Federal Regulations. This product may produce concentrated hazardous vapors
or fumes in a disposal container creating a dangerous environment. Refer to "40 CFR Protection of Environment Parts 260 - 299" for complete waste disposal
regulations for ignitable materials. Consult your local, state, or Federal Environmental Protection Agency before disposing of any chemicals. Do not flush to
sanitary sewer or waterway.
The information contained herein is believed to be accurate but is not warranted to be so. Data and calculations are based on information furnished by the
manufacturer of the product and manufacturers of the components of the product. Users are advised to confirm in advance of need that information is current,
applicable and suited to the circumstances of use. Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if
reasonable safety procedures are not adhered to as stipulated in the data sheet. Furthermore, vendor assumes no responsibility for injury caused by abnormal use
of this material even if reasonable safety procedures are followed. Any questions regarding this product should be directed to the manufacturer of the product as
described in Section 1.

MSDS PREPARED BY: CDB, Inc., P.O. Box 5604, Lakeland, FL 33807 (863) 644 - 3298

www.compdatabase.com

Date:
Supercedes:

15 October 2007
15 November 2004

MATERIAL SAFETY DATA SHEET
IN CASE OF EMERGENCY CALL CHEMTREC AT 1-800-424-9300
1.

2.

PRODUCT IDENTIFICATION AND COMPANY IDENTIFICATION:
Product Name:

PURELL® HAND SANITIZER WITH ALOE

Company Name & Address:

GOJO Industries, Inc.
One GOJO Plaza, Suite 500
Akron, OH 44311

Emergency Phone:
Non-Emergency Phone:
MSDS Request Phone:

1-800-424-9300 CHEMTREC
(330) 255-6000
(330) 255-6000 x8804

INFORMATION ON INGREDIENTS:
HAZARDOUS INGREDIENTS

CAS NUMBER

OSHA PEL

ACGIH TLV

% RANGE

Ethyl Alcohol

64-17-5

1000 ppm

1000 ppm

62

Isopropanol

67-63-0

400 ppm

400 ppm

<5

Other ingredient(s) with notification requirements:

3.

CAS NUMBER

List

Ethyl Alcohol

64-17-5

MA 1; NJ 1S; PA 1; CN 2

Isopropanol

67-63-0

MA 1; NJ 1S; CN 1

HAZARDS IDENTIFICATION:
EMERGENCY OVERVIEW
When used according to instructions, the product applicable to this MSDS is safe and presents no
immediate or long-term health hazard. However, abnormal entry routes, such as gross ingestion, may
require immediate medical attention.
Potential Health Effects:

4.

HMIS:

Health

1 Flammability

3 Reactivity

0 Personal Protection None

Eye Contact:
Skin Contact:
Inhalation:
Ingestion:
Carcinogenicity:

May cause eye irritation.
No irritation or reaction expected.
Not applicable.
May cause upset stomach, nausea (Abnormal entry route).
Not listed as a carcinogen by NTP, IARC, OSHA or ACGIH.

FIRST AID MEASURES:
Eye Contact:
Skin Contact:
Inhalation:
Ingestion:

Do not rub eyes. Flush eyes thoroughly with water for 15 minutes. If condition
worsens or irritation persists, contact physician.
Not applicable.
Not applicable.
Do not induce vomiting. Contact a physician or Poison Control Center.

Purell is a trademark of Warner-Lambert Company LLC

PURELL® HAND SANITIZER WITH ALOE

5.

FIRE FIGHTING MEASURES:
NFPA:
Flashpoint °F/°C (PMCC method):
Unusual Fire and Explosion Hazards:
Special Fire Fighting Procedures:
Extinguishing Media: X Water Fog

6.

Page 2 of 2

Health
0 Fire 3 Reactivity 0
74°F/23°C
Product is flammable due to alcohol content.
None known.
X Alcohol Foam X CO2 X Dry Chemical

Other

ACCIDENTAL RELEASE MEASURES:
Avoid contact with ignition sources since product is flammable. Absorb onto inert material and dispose in
appropriate manner. Water clean up and rinse. CAUTION – WILL CAUSE SLIPPERY SURFACES.

7.

HANDLING AND STORAGE:
Keep away from fire or flame. Store at normal room temperature away from reach of small children. Keep
containers sealed. Use older containers first. Avoid freezing conditions.

8.

EXPOSURE CONTROLS/PERSONAL PROTECTION:
Eye Protection:
Skin Protection:
Respiratory Protection:
Ventilation:
Protective Equipment or Clothing:

9.

PHYSICAL AND CHEMICAL PROPERTIES:
Appearance and Odor
pH (undiluted):
VOC , %:

10.

None required under normal conditions.
None required under normal conditions.
None required under normal conditions.
None required under normal conditions.
None required under normal conditions.

Clear green liquid, floral fragrance
4.5 – 9.5
65

STABILITY AND REACTIVITY:
Stable/Non reactive product. Avoid ignition sources.

11.

TOXICOLOGICAL INFORMATION:
No acute or chronic toxic effects expected when used according to directions.

12.

ECOLOGICAL CONSIDERATIONS:
No ecological or special considerations when used according to directions. Not considered environmentally
harmful from normal dilution, expected usage and typical drainage to sewers, septic systems and treatment
plants.

13.

DISPOSAL CONSIDERATIONS:
Characteristic hazardous waste-flammable liquid. Dispose according to local, state and Federal regulations.

14.

TRANSPORT INFORMATION:
Hazardous by transport regulations. When transported by Ground and Rail, this product typically is shipped as
Consumer Commodity ORM-D. When transported by air, this product is typically shipped as Consumer
Commodity or Alcohols N.O.S. depending on package size. When transported by ocean, this product is
typically shipped as Limited Quantities. Refer to current regulations for exact requirements.

15.

REGULATORY AND OTHER INFORMATION:
TSCA: All ingredients are listed or exempt per reference 15 USC 2602 (2)(B)(iv).
Complies with current FDA regulations for cosmetic and/or over-the-counter drug products.
Notice: The information herein is based on data considered to be accurate as of the date of preparation of this material safety data sheet.
However, no warranty or representation, expressed or implied, is made as to the accuracy or completeness of the foregoing data and
safety information. The user assumes all liability for any damage or injury resulting from abnormal use, from any failure to adhere to
recommended practices or from any hazards inherent in the nature of the product.

Document#: 9650-506

MATERIAL SAFETY DATA SHEET
SECTION 1 – MATERIAL IDENTIFICATION AND USE
MATERIAL
NAME IDENTIFIER

EZE-FLO - Fumeless Alkaline Liquid Drain Opener and Cleaner

MANUFACTURERS NAME/ADDRESS

CONTACTS

Cantol Limited
199 Steelcase Road West
Markham, ON L3R 2M4

Canutec (24 hours)
(613) 996-6666
Web: www.cantol.com

SECTION 2 – HAZARDOUS INGREDIENTS
HAZARDOUS INGREDIENTS

Potassium Hydroxide

%

CAS
NUMBER

40-70

1310-58-3

LD50 OF MATERIAL
(SPECIFY SPECIES AND ROUTE)

365 mg/kg, ORAL, RAT

LC50 OF MATERIAL
(SPECIFY SPECIES)

NONE

SECTION 3 – PHYSICAL DATA
PHYSICAL STATE
GAS

LIQUID

ODOUR AND APPEARANCE

ODOUR THRESHOLD (PPM)

Clear red liquid with no odour

SOLID

Not Applicable

VAPOUR PRESSURE
(mm Hg.)

VAPOUR DENSITY
(AIR=1)

EVAPORATION
RATE

% VOLATILE
(BY VOLUME)

SOLUBILITY IN
WATER (20°C)

pH

Practically Zero
Not Available

Not Applicable
Complete

BOILING
POINT (°C)

Not Applicable

FREEZING
POINT (°C)

133 (271°F)
SPECIFIC GRAVITY

13.0 @ 1% Soln.

1.45

-29 (-20°F)
COEFF. WATER OIL DIST.

Not Available

SECTION 4 – FIRE AND EXPLOSION DATA
FLAMMABILITY
YES

IF YES, UNDER
WHICH CONDITIONS?

NO

MEANS OF EXTINCTION

Not Applicable

SPECIAL PROCEDURES

Wear protective clothing. Product is highly alkaline. Self-contained breathing apparatus should be worn in areas
where stored.

FLASHPOINT (C°) AND METHOD

UPPER EXPLOSION LIMIT (% BY VOLUME)

Not Applicable

Not Applicable

AUTO IGNITION TEMPERATURE (°C)

EXPLOSION
DATA

Not Applicable

TDG FLAMMABILITY CLASSIFICATION

Not Applicable

Not Applicable
SENSITIVITY TO IMPACT

RATE OF BURNING

Not Available

Not Available

LOWER EXPLOSION LIMIT (% BY VOLUME)

HAZARDOUS COMBUSTION PRODUCTS

None
EXPLOSIVE POWER

SENSITIVITY TO STATIC DISCHARGE

Not Available

Not Available

SECTION 5 – REACTIVITY DATA
CHEMICAL STABILITY
YES

✘

NO

IF NO, UNDER
WHICH CONDITIONS?

COMPATIBILITY WITH OTHER SUBSTANCES
YES

NO

IF NO,
WHICH ONES?

REACTIVITY, AND UNDER WHAT CONDITIONS
HAZARDOUS DECOMPOSITION PRODUCTS

Acids, aluminum, tin, zinc, combustible material, organohalogens, aldehydes.
Reacts with aluminum, tin, zinc to generate hydrogen gas. Contact with water may generate heat.
Reacts with food sugars to generate carbon monoxide.

NONE

EZE-FLO

SECTION 6 – TOXICOLOGICAL PROPERTIES
ROUTE OF ENTRY
SKIN CONTACT

✘

SKIN ABSORPTION

EYE CONTACT

✘

INHALATION ACUTE

INHALATION CHRONIC

INGESTION

✘

EFFECTS OF ACUTE EXPOSURE TO MATERIAL

Corrosive to skin and eyes. Harmful if swallowed.
EFFECTS OF CHRONIC EXPOSURE TO MATERIAL

None Known
LD 50 OF MATERIAL
SPECIFY SPECIES AND ROUTE

Not Available

LC50 OF MATERIAL
SPECIFY SPECIES

EXPOSURE LIMIT OF MATERIAL

Not Applicable

SENSITIZING CAPABILITY
OF MATERIAL

CARCINOGENICITY OF
MATERIAL

Not Available

IRRITANCY OF MATERIAL

Causes severe burns to
skin and eyes

ACGIH TLV for Potassium Hydroxide
2mg/m3
REPRODUCTIVE EFFECTS OF MATERIAL

None

SYNERGESTIC MATERIALS

None

None Known

SECTION 7 – PREVENTIVE MEASURES
PERSONAL PROTECTIVE EQUIPMENT

Gloves, eye protection
GLOVES (SPECIFY)

RESPIRATORY (SPECIFY)

EYE (SPECIFY)

Rubber, Neoprene, Plastic

None

Goggles

FOOTWEAR (SPECIFY)

CLOTHING (SPECIFY)

OTHER (SPECIFY)

None

None

None

ENGINEERING CONTROLS (SPECIFY E.G. VENTILATION ENCLOSED PROCESS)

None
LEAK AND SPILL PROCEDURE

Soak up spill with oil absorbant. Flush area with water.
WASTE DISPOSAL

Discard used absorbant in proper receptacle. Follow all government disposal regulations.
Never add water to the container. Violent reaction can occur. Always add product slowly to water
according to label directions. Wear gloves and goggles. Do not get in eyes, on skin or clothing.

HANDLING PROCEDURES AND EQUIPMENT

Keep container closed. Do not store near combustible materials.
KEEP OUT OF THE REACH OF CHILDREN.

STORAGE REQUIREMENTS

SPECIAL SHIPPING INFORMATION

LTD. QTY.

SECTION 8 – FIRST AID MEASURES
EYES: Immediately flush with plenty of water for at least 15 minutes. Seek prompt medical attention.
SKIN: Flush with water immediately. Seek prompt medical attention.
INGESTION: Do not induce vomiting. Drink large quantities of water. Call a physician.

SOURCES USED

Canadian Centre for Occupational Health and Safety, Vendor Material Safety Data Sheets
ADDITIONAL INFORMATION

For industrial and institutional use only. Read and follow all label directions and precautions. Do not mix with other
chemicals.
SECTION 9 – PREPARATION DATE OF THE MSDS
PREPARED BY

D1B, E

Cantol WHMIS Group

PHONE NUMBER

(905) 475-6141

DATE

February 1, 2007

Pumice Scouring Stick
Item Number:100714
U.S. Department Of Labor
Occupational Safety And Health Administration

MATERIAL SAFETY DATA SHEET
Required Under USDL Safety And Health Regulations
(29 CFP 1910.1200 "Hazards Communication Standard")

Section I
Manufactured For: Gabriel First Corp.
Emergency Telephone: 1-800-424-9300
Address: 233 W Commercial Street East Rochester, NY 14445
Chemical Name & Synonyms: Cleaning, Compound, Liquid
Trade Name & Synonyms: Pumice Scouring Stick
Prepared On: 6/30/2005

Section I - Hazardous Ingredients/Identity Information
Section II - Product & Component Data
Component(s)/ Chemical Names
TLV
PEL
Pumice (Volcanic Glass)
There is No Free Crystalline Silica Present

CAS Registry No

%

Section III - Physical Data
Boiling Point: N/A
Specific Gravity (H 2O=1): N/A
Melting Point: 2390° F
Vapor Pressure: N/A
Percent, Volatile By Volume (%): N/A
Vapor Density (Air=1): N/A
Evaporation Rate: N/A
Solubility In Water: Not Soluble
Appearance And Odor: Odorless Solid

Section IV - Fire And Explosion Hazard Data
Special Fire Fighting Procedures: None.
Unusual Fire and Explosion Hazards: None
Flash Point/Method Used: N/A
Flammable Limits: N/A
LEL: N/A UEL: N/A
Extinguishing Media: N/A

Section V - Health Hazard Data
Route(s) of Entry:
Inhalation? Yes
Skin? No
Ingestion: Yes
Health Hazards (Acute and Chronic): Dry sawing or grinding may result in the release of dust particles which, acute, may
cause irritation of eyes, nose or throat and chronic, may result in lung disease (Silicosis) if exposed for prolonged time.
Carcinogenicity:
NTP?
IARC Monographs?
OSHA Regulated?
No
No
No
Signs and Symptoms of Exposure: Irritation of eyes, nose and throat or shortness of breath.
Medical Conditions Generally Aggravated by Exposure: Pre -existing lung disease such as Emphysema
or Asthma.

Emergency First Aid Procedures: Irrigate eyes generously with clean water for 15 minutes. If irritation persists call a
physician.

Section VI - Reactivity Data
Stability Conditions To Avoid
Stable
None
Materials To Avoid: None
Hazardous Decomposition Products: None
Hazardous Polymerization
Conditions To Avoid
Will Not Occur
None

Section VII - Spill Or Leak Procedures
Steps To Be Taken In Case Material Is Released Or Spilled: Sweep up and properly dispose.
Waste Disposal Method: Dispose as common waste.
Precautions To Be Taken in Handling and Storing: None
Other Precautions: Wear NIOSH approved respirator and tight fitting goggles. When dry sawing or grinding, or saw and
grind when wet.

Section VIII - Special Protection Information
Control Measures (When Sawing or Grinding)
Respiratory Protection (Type): NIOSH Approved Particulate Respirator
Ventilation: Mechanical (General) in Confined Area
Protective Gloves: When Required
Eye Protection: Tight Fitting Goggles
Other Protective Equipment: None
Work/Hygienic Practices: N/A

Section IX - Special Precautions
Precautions To Be Taken In Handling And Storing: None

This information is given in good faith, but no warranty expressed or implied is made. Our company believes that it is accurate to the best of its knowledge
and relates only to the specific material designated herein.

ORTHO® Home Defense® MAX™ Perimeter & Indoor Insect Killer RTU Pull'N Spray

Page 1 of 4

MATERIAL SAFETY DATA SHEET
DATE PREPARED:07/08/2004
MSDS No:7202

1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ORTHO® Home Defense® MAX™ Perimeter & Indoor Insect Killer RTU Pull'N Spray
PRODUCT DESCRIPTION: Insecticide

MANUFACTURER
The ORTHO Group
P.O. Box 190
Marysville, OH 43040

24 HR. EMERGENCY TELEPHONE NUMBERS
CHEMTREC (U.S.):
Emergency Phone:

(800) 424-9300
1-800-225-2883

EPA REG. NO.: 239-2663D PN: 6061

2. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name
Bifenthrin
Other Ingredients

Wt.%
0.05
99.95

CAS#
82657-04-3

3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
IMMEDIATE CONCERNS:
CAUSES MODERATE EYE IRRITATION
AVOID CONTACT WITH EYES OR CLOTHING
KEEP OUT OF REACH OF CHILDREN
POTENTIAL HEALTH EFFECTS
EYES: This substance may cause moderate eye irritation. See Toxicological Information, section 11.
SKIN: This substance is not expected to cause skin irritation and is only slightly toxic if absorbed through the skin. See
Toxicological Information, section 11.
INGESTION: This substance is slightly toxic if swallowed. The degree of injury will depend on the amount absorbed from the gut.
See Toxicological Information, Section 11.
INHALATION: Overexposure to the spray mist may be irritating to the respiratory tract. If inhaled, this substance is considered
practically non-toxic to internal organs. See Toxicological Information, section 11.

4. FIRST AID MEASURES
EYES: Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5
minutes, then continue rinsing eyes. Call a poison control center or doctor for treatment advice.
SKIN: If on skin or clothing, take off contaminated clothing. Rinse skin immediately with plenty of water for 15 to 20 minutes. Call a
poison control center or doctor for treatment advice.
INGESTION: If swallowed, call a poison control center or doctor immediately for treatment advice. Have person sip glass of water if
able to swallow. Do not induce vomiting unless told to by a poison control center or doctor. Never give anything by mouth to an
unconscious person.
INHALATION: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration,
preferably by mouth-to-mouth, if possible. Call a poison control center or doctor for further treatment advice.

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COMMENTS: See product label for specific First Aid Measures. The above measures are the most conservative - Pesticide
Registration (PR) Notice 2001-1, January 2, 2001, and would apply in the event a product label is not immediately available.

5. FIRE FIGHTING MEASURES
FLASHPOINT AND METHOD: None
EXTINGUISHING MEDIA: Use CO2, Dry Chemical or Foam extinguishing media.
HAZARDOUS COMBUSTION PRODUCTS: Heating this material may generate carbon monoxide, carbon dioxide, hydrogen
chloride and hydrogen fluoride.
FIRE FIGHTING PROCEDURES: Products of combustion from fires involving this material may be toxic. Avoid breathing smoke
and mists. Avoid personnel and equipment contact with fallout and runoff. Minimize the amount of water used for fire fighting. Do
not enter any enclosed area without full protective equipment, including self-contained breathing equipment. Contain and isolate
runoff and debris for proper disposal. Decontaminate personal protective equipment and fire fighting equipment before reuse. Read
the entire document.

6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: While wearing rubber gloves, soak up spilled material with paper towels and discard in trash.
LARGE SPILL: Dike or contain release. Keep material out of lakes, streams, ponds, and sewer drains. Large spills should be covered
to prevent dispersal. Absorb with a non-combustible absorbent such as clay, sand or soil. Vacuum, shovel, or pump all waste
material, including absorbent, into drums and label contents for disposal. Clean spill area of residues and absorbent.
GENERAL PROCEDURES: Observe all protection and safety precautions when cleaning up spills -- see Section 8. "EXPOSURE
CONTROLS/PERSONAL PROTECTION".

7. HANDLING AND STORAGE
GENERAL PROCEDURES: Store this product only in its original container in a secured storage area. Protect container from
freezing.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS: No special ventilation is necessary under normal product use conditions. However, if workplace
operating conditions create high airborne concentrations of the material, special ventilation may be needed to reduce levels below
OSHA exposure limits.
PERSONAL PROTECTION
EYES AND FACE: For application of product in accordance with label instructions, no special eye protection is needed. Handling
of this product during manufacturing or in the event of an accidental discharge of the material which could cause eye contact,
workers should wear goggles or a face shield.
SKIN: Follow label precautions for skin protection. Avoid contact with skin and clothing. Wash thoroughly with soap and water
after handling. Remove contaminated clothing and wash before reuse.
RESPIRATORY: Avoid breathing vapor or mist. This product is not likely to pose an airborne exposure concern when handled
and used in accordance with label instructions.
OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200):
Chemical Name
Bifenthrin

OSHA PEL
None

EXPOSURE LIMITS
ACGIH TLV
ACGIH STEL
None
None

9. PHYSICAL AND CHEMICAL PROPERTIES

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PHYSICAL STATE: Liquid
APPEARANCE: Clear to cloudy white liquid
pH: ~7.0 to 7.3
SOLUBILITY IN WATER: Miscible with water.
DENSITY: 8.32 Lbs/gal at 20°C

10. STABILITY AND REACTIVITY
STABLE: YES
HAZARDOUS POLYMERIZATION: NO
CONDITIONS TO AVOID: DO NOT APPLY THIS PRODUCT IN OR ON ELECTRICAL EQUIPMENT DUE TO THE
POSSIBILITY OF SHOCK HAZARD.

11. TOXICOLOGICAL INFORMATION
ACUTE
EYES: Rabbit - moderately irritating, irritation cleared by 48 hours. EPA FIFRA toxicity category - lll.
DERMAL LD50: Rat = >10 g/kg. EPA FIFRA toxicity category - IV. SKIN IRRITATION: Rabbit - nonirritating, contact with
bifenthrin may produce reversible skin sensations such as numbness, burning and tingling. The skin sensations usually subside
within 12 hours. EPA FIFRA toxicity category - IV.
ORAL LD50: Rat = > 5 g/kg. EPA FIFRA toxicity Category - IV.
INHALATION LC50: Rat - 4 hour inhalation = > 5.0 mg/liter. EPA FIFRA toxicity category - IV.
SENSITIZATION: Guinea pig - no evidence of allergic skin reactions.
CHRONIC: CARCINOGENICITY : Mouse lifetime feeding study - high dose males - demonstrated an increase in urinary bladder
hemangiopericytomas. There was no evidence of increased tumors in the other male or female mice dose levels. The mouse no
observed effect level (NOEL) was male 75 mg/kg/dy, female 90 mg/kg/dy. Rat lifetime feeding study - no findings of tumors. The
rat NOEL was 10 mg/kg/dy. EPA classified bifenthrin - Group C carcinogen.
NEUROTOXICITY: Bifenthrin has not been associated with delayed peripheral neuropathy. Overexposure to pyrethroids results in a
transient disruption in the depolarization of nerve membranes by interfering with the closing of the sodium channels. Depending
upon the degree of overexposure, signs of overexposure may be displayed by tremors, muscle fasciculations, ataxia, spasms,
hyperexcitability, hyperactivity and convulsions. Localized skin contact with bifenthrin may result in temporay burning, tingling or
numbness sensations.
TERATOGENICITY: Bifenthrin is not considered to be a teratogen (a substance that causes birth defects). The rat and rabbit
developmental NOELs were 1 and 8 mg/kg/dy, respectively.
REPRODUCTIVE TOXIN: Bifenthrin is not considered to cause adverse reproductive effects. Results of a rat multigeneration
reproduction study indicated no developmental toxicity or reproductive effects at the highest dose level of approximately 15
mg/kg/dy. The maternal toxicity NOEL was approximately 5 mg/kg/dy.
MUTAGENICITY: The results of a series of mutation testing indicate that bifenthrin has a low order of mutagenic potential.

12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: In soil, bifenthrin is stable over a wide pH range and degrades at a slow rate which is governed by soil
characteristcs. Bifenthrin will also persist in aquatic sediments. Bifenthrin has a high Log Pow (>6.0), a high affinity for organic
matter, and is not mobile in soil. Therefore, there is little potential for movement into ground water. There is the potential for
bifenthrin to bioconcentrate (BCF = 11,750).
ECOTOXICOLOGICAL INFORMATION: This pesticide is extremely toxic to fish and aquatic invertebrates. Do not apply directly
to water. Drift and runoff from treated areas may be hazardous to aquatic organisms in neighboring areas. Care should be used when
spraying to avoid fish and reptile pets in/around ornamental ponds. This product is highly toxic to bees exposed to direct treatment
on residues on blooming plants. Do not apply this product or allow it to drift to blooming plants if bees are visiting the treatment
area.

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13. DISPOSAL CONSIDERATIONS
FOR LARGE SPILLS: Material collected that cannot be reprocessed should be disposed of in a landfill approved for pesticide
disposal or in accordance with applicable Federal, state, or local procedures.
PRODUCT DISPOSAL: Call local solid waste agency or 1-800-CLEANUP for disposal instructions. Never place unused product
down any drain.

14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: Not Regulated
U.S. SURFACE FREIGHT CLASS: Insecticides, Fungicides, Insect or animal repellents or vermin exterminators, NOI, Other
than poison
SPECIAL SHIPPING NOTES: The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate
Dangerous Goods Regulations, for additional description requirements (e.g., technical name) and mode-specific or quantity-specific
shipping requirements.

15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
PRODUCT CLASSIFICATION UNDER SECTION 311 OF SARA
ACUTE: YES

CHRONIC: NO

FIRE: NO

REACTIVITY: NO

PRESSURE GENERATING: NO

STATE REGULATIONS
CALIFORNIA PROPOSITION 65: No ingredients on list.
GENERAL COMMENTS: Contact local authorities for disposal of large quantities of unused product.

16. OTHER INFORMATION
HMIS CODES
FLAMMABILITY: 0
NFPA CODES
FIRE: 0 HEALTH: 1

HEALTH: 1

PHYSICAL HAZARD: 0

REACTIVITY: 0

APPROVAL DATE: 07/08/2004
REVISION SUMMARY New MSDS
ADDITIONAL MSDS INFORMATION: NFPA/HMIS Hazard Rating: 0=Least; 1=Slight; 2=Moderate; 3=High; 4=Severe.
COMMENTS: Use of this product is regulated by the U.S. Environmental Protection Agency (EPA) through the approved product
label. It is a violation of Federal law to use this product in a manner inconsistent with its labeling.
MANUFACTURER DISCLAIMER: The information contained herein is, to the best of the Manufacturer's (see Section 1)
knowledge and belief, accurate and reliable as of the date of preparation of this document. However, no warranty or guarantee,
express or implied, is made as to the accuracy or reliability, and the Manufacturer shall not be liable for any loss or damage arising
out of the use thereof. No authorization is given or implied to use any patented invention without a license. In addition, the
Manufacturer shall not be liable for any damage or injury resulting from abnormal use, from any failure to adhere to recommended
practices or from any hazards inherent in the nature of the product.

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MATERIAL SAFETY DATA SHEET
S00857
01 00
===========================================================================
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
--------------------------------------------------------------------------PRODUCT NUMBER
HMIS CODES
Health
2
S00857
Flammability
2
Reactivity
0
PRODUCT NAME
SPRAYON® BLAST'EM® Wasp & Hornet Killer
MANUFACTURER'S NAME
EMERGENCY TELEPHONE NO.
THE SHERWIN-WILLIAMS COMPANY
(216) 566-2917
Consumer Group - Industrial
Cleveland, OH 44115
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
21-MAY-07
(800) 251-2486
===========================================================================
Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
--------------------------------------------------------------------------91
64742-47-8 Heavy Aliphatic Solvent
ACGIH TLV Not Available
0.2 mm
OSHA PEL Not Available
5
67-63-0 2-Propanol
ACGIH TLV
400 ppm
33 mm
ACGIH TLV
500 ppm STEL
OSHA PEL
400 ppm
OSHA PEL
500 ppm STEL
0.5
51-03-6 Piperonyl Butoxide
ACGIH TLV Not Available
OSHA PEL Not Available
0.3
52645-53-1 Permethrin
ACGIH TLV Not Available
OSHA PEL Not Available
2
124-38-9 Carbon Dioxide
ACGIH TLV
5000 ppm
760 mm
OSHA PEL
5000 ppm
===========================================================================
Section 3 -- HAZARDS IDENTIFICATION
--------------------------------------------------------------------------ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.

Continued on page 2

S00857
page 2
===========================================================================
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Prolonged or frequent repeated skin contact may cause allergic reactions
in some individuals.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
===========================================================================
Section 4 -- FIRST AID MEASURES
--------------------------------------------------------------------------EYES:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 -- FIRE FIGHTING MEASURES
--------------------------------------------------------------------------FLASH POINT
LEL
UEL
165 °F PMCC
0.7
12.7
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.
===========================================================================
Section 6 -- ACCIDENTAL RELEASE MEASURES
--------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
===========================================================================
Section 7 -- HANDLING AND STORAGE
--------------------------------------------------------------------------This product is toxic to fish. Do not allow product to enter
groundwater, streams, lakes or ponds. Do not contaminate water by cleaning
of equipment or disposal of wastes.
STORAGE CATEGORY
Not Available

Continued on page 3

S00857
page 3
===========================================================================
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat and open flame.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
===========================================================================
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
--------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
Do not use in commercial food/feed handling establishments, restaurants
or other sites where food/feed is commercially prepared or processed. Do
not use in Federally Inspected meat and poultry plants.
Do not allow children or pets to contact treated surfaces until spray
has dried. Do not spray air in rooms or use on plants. Avoid spraying
vegetation directly. Apply as a surface spray only. Do not spray to
contact food, feedstuffs or water supplies. Thoroughly wash dishes and
food-handling utensils contaminated with this product. Remove pets and
cover fish bowls before spraying.
Do not contaminate water, food or feed by storage or disposal. Do not
store near heat or open flame. Store in cool area away from children.
It is a violation of Federal law to use this product in a manner
inconsistent with its labeling. Read entire label.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
PROTECTIVE GLOVES
Wear chemical-resistant gloves to prevent skin contact.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
===========================================================================
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
--------------------------------------------------------------------------PRODUCT WEIGHT
6.54 lb/gal
783 g/l
SPECIFIC GRAVITY
0.79
BOILING POINT
<0 - 500 F
<-18 - 260 C
MELTING POINT
Not Available
VOLATILE VOLUME
99 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical)
Volatile Weight 96.65 % Less Water and Federally Exempt Solvents

Continued on page 4

S00857
page 4
===========================================================================
Section 10 -- STABILITY AND REACTIVITY
--------------------------------------------------------------------------STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
===========================================================================
Section 11 -- TOXICOLOGICAL INFORMATION
--------------------------------------------------------------------------CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
--------------------------------------------------------------------------TOXICOLOGY DATA
CAS No.
Ingredient Name
--------------------------------------------------------------------------64742-47-8
Heavy Aliphatic Solvent
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
67-63-0
2-Propanol
LC50
RAT
4HR
Not Available
LD50
RAT
5045
mg/kg
51-03-6
Piperonyl Butoxide
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
52645-53-1
Permethrin
LC50
RAT
4HR
Not Available
LD50
RAT
410
mg/kg
124-38-9
Carbon Dioxide
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
===========================================================================
Section 12 -- ECOLOGICAL INFORMATION
--------------------------------------------------------------------------ENVIRONMENTAL HAZARDS
This product is toxic to fish and aquatic invertebrates. Do not apply
directly to water.
ECOTOXICOLOGICAL INFORMATION
No data available.
===========================================================================
Section 13 -- DISPOSAL CONSIDERATIONS
--------------------------------------------------------------------------WASTE DISPOSAL METHOD
Waste from this product is not hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.

Continued on page 5

S00857
page 5
===========================================================================
Section 14 -- TRANSPORT INFORMATION
--------------------------------------------------------------------------US Ground (DOT)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, 2.2, LIMITED QUANTITY, (ERG#126)
Canada (TDG)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, CLASS 2.2, LIMITED QUANTITY, (ERG#126)
IMO
May be shipped as Limited Quantity
UN1950, AEROSOLS, CLASS 2, LIMITED QUANTITY, EmS F-D, S-U
===========================================================================
Section 15 -- REGULATORY INFORMATION
--------------------------------------------------------------------------SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
No ingredients in this product are subject to SARA 313 (40 CFR 372.65C)
Supplier Notification.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
===========================================================================
Section 16 -- OTHER INFORMATION
--------------------------------------------------------------------------This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

MATERIAL SAFETY DATA SHEET
Date stamp:

MSDS Ref. No.:

01-Sep-2005

Revision Number: 5

011771025

1. PRODUCT AND COMPANY IDENTIFICATION
Product name:
Description:

ORTHO Indoor Insect Fogger
Insecticide
24-HOUR EMERGENCY TELEPHONE NUMBERS:
CHEMTREC (U.S.): 1-800-424-9300
CHEMTREC (International): 1-703-527-3887
Non-Emergency Calls: 1-937-644-0011

Company
The Scotts Company
14111 Scottslawn Road
Marysville, OH 43041
EPA Registration No.: 239-2626
Formula No.: S1112

2. HAZARDS IDENTIFICATION
Labelling
Signal word:
Precautionary Statement

CAUTION.
Causes substantial but temporary eye injury. Do not get in eyes. Wear safety glases. Wear goggles.
Harmful if absorbed through the skin. Avoid contact with eyes, skin, and clothing. Wash with soap and
water after handling. Keep out of reach of children.

Potential health effects
Eye contact:
Skin contact:
Ingestion:
Inhalation:

Irritating to eyes.
Irritation not expected.
Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea.
May cause irritation of respiratory tract.

Aggravated Medical Conditions:
Principle routes of exposure:
Target organ effects:

Inhalation may aggravate asthma.
Skin, Eyes, Inhalation
Irritation.

3. COMPOSITION/INFORMATION ON INGREDIENTS
Components
Natural Pyrethrine
Permethrin
MGK 264, N-octyl bicycloheptene dicarboximide
Inert Ingredients

CAS-No
8003-34-7
52645-53-1
113-48-4
PROPRIETARY

Weight %
0.05
0.4
0.4
99.115

4. FIRST AID MEASURES
Eye contact:

Hold eye open and rins slowly and gently with water for 15-20 minutes. Remove contact lenses, if present
after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment
advice

Skin contact:

Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a
poison control center or doctor for treatment advice

Ingestion:

Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if
able to swallow. Do not induce vomiting unless told to do so be a poison control center or doctor. Do not
give anything by mouth to an unconscious person

Inhalation:

Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial
respiration, preferabley by mouth-to-mouth, if possible. Call a poison control center or doctor for further
treatment advice

5. FIRE-FIGHTING MEASURES
Flammable properties:
Suitable extinguishing media:
Explosion potential:
Explosive properties:

Revision date: 10-May-2005

Flammable aerosol. N.F.P.A. (Code 30B) Level I Aerosol.
Water spray, carbon dioxide, dry chemical, chemical foam.
Closed containers may rupture violently under fire conditions.
Heating may cause an explosion..

Page 1 of 4

MSDS Ref. No.:

ORTHO Indoor Insect Fogger

011771025

_______________________________________________________________________________________________
Hazardous combustion products:
Fire fighting procedures:
Special protective equipment for
firefighters:
Flammability Limits in Air:

Toxic fumes may be produced.
Select appropriate method to surround and extinguish fire. Flood with water to cool containers.
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or
equivalent) and full protective gear.
No information available

6. ACCIDENTAL RELEASE MEASURES
Personal precautions:
Environmental precautions:
Methods for containment:
Methods for cleaning up:

Wear personal protective equipment
Prevent product from entering drains
Control spill with dykes and absorb with inert absorbant material
Detergent and water.

7. HANDLING AND STORAGE
Handling: Avoid container breakage. Avoid inhalation or contact with skin, eyes, or clothing. Do not use near heat. Do not use near an ignition source.
Do not puncture or incinerate.
Storage: Store in a cool, dry area away from incompatible materials and heat sources.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Components
Natural Pyrethrine
Permethrin
MGK 264, N-octyl bicycloheptene
dicarboximide
Engineering controls

ACGIH:
5 mg/m³ TWA
Not Listed
Not Listed

OSHA:
5 mg/m³ TWA
Not Listed
Not Listed

Use adequate ventilation to keep the airborne concentrations of this material below the recommended
exposure standard

Personal Protective Equipment
Eye/face protection:
Skin and body protection:
Respiratory protection:

General hygiene considerations:

Eye/face protection is not required, but is recommended in manufacturing situations where contact may
occur. Safety glasses with side shields or goggles. Face-shield.
No special protective clothing is required under normal workplace conditions. Wear suitable protective
clothing if contact is anticipated during manufacturing.
If airborne levels are high or product does not remain intact, use a combination of engineering controls
(e.g. ventilation) and personal protection (e.g. NIOSH/MSHA approved respirator for dusts, mists, and
fumes.
Remove and wash contaminated clothing before re-use. Wash hands before breaks and immediately after
handling the product..

9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State:
Color:
Solubility:
Density:
Method:

Appearance:
Odor:
Specific gravity:
Flash point:

Liquid
Light yellow
Miscible
8.13 lbs/gal
TAG CC

clear
solvent
0.975
165° F

10. STABILITY AND REACTIVITY
Chemically Stable:
Conditions to avoid:
Materials to avoid:
Hazardous decomposition products:
Possibility of hazardous reactions:

Yes
Temperatures above 130F.
Oxidising agents (strong).
Toxic fumes and gases may be generated.
Poses little or no immediate hazard.

11. TOXICOLOGICAL INFORMATION
Acute toxicity

Revision date: 10-May-2005

Page 2 of 4

MSDS Ref. No.:

ORTHO Indoor Insect Fogger

011771025

_______________________________________________________________________________________________
LD50/oral: >5 g/kg, rat
LD50/dermal: >5 g/kg, rabbit
LC50/inhalation: >5.98 mg/L, (vapor), rat
Eye effects: Mild eye irritation, rabbit
Skin effects: Mild skin irritation, rabbit
Sensitization: No sensitization, guinea pig
Chronic toxicity
Carcinogenic effects:

The table below indicates whether each agency has listed any indgredient as a carcinogen.

Components
Natural Pyrethrine
Permethrin
MGK 264, N-octyl bicycloheptene
dicarboximide
Ingestion:
Inhalation:
Target organ effects:

NTP:
Not listed
Not listed
Not listed

IARC:
Not listed
3
Not listed

OSHA:
Not listed
Not listed
Not listed

Ingestion may cause irritation to mucous membranes.
Possible irritation of the respiratory tract.
Irritation.

12. ECOLOGICAL INFORMATION
Ecotoxicity effects:
Persistence and degradability:
Bioaccumulative potential:
Mobility:
Aquatic toxicity:

Toxic to aquatic organisms.
Inherently biodegradable.
No information available.
Water contaminating.
No information available.

13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods:
Contaminated packaging:

If partially filled, call the local solid waste agency or 1-800-CLEANUP for disposal instructions. Do not
place product down any indoor or outdoor drain.
If empty, place in trash or offer for recycling if available.

14. TRANSPORT INFORMATION
The description shown may not apply to all situations. Consult 49 CFR, or appropriate dangerous goods regulations for additional description
requirements (e.g. technical name) and mode-specific or quantity-specific shipping requirements.
DOT
Proper shipping name:

Consumer Commodity, ORM-D

15. REGULATORY INFORMATION
Natural Pyrethrine

Components

CAS-No
8003-34-7

Permethrin
MGK 264, N-octyl bicycloheptene dicarboximide

52645-53-1
113-48-4

General Information

CERCLA/SARA 313
0.454 kg final RQ
1 lb final RQ
1 lb final RQ
Not Listed
Not Listed

CERCLA/SARA 302
Not Listed

Not Listed
Not Listed

Contact local authorities for disposal of large quantities of product

16. OTHER INFORMATION
NFPA:

Health: 1

Flammability: 4

Reactivity: 0

HMIS:

Health: 1

Flammability: 4

Reactivity: 1

Hazard Rating: 0=Least; 1-Slight; 2=Moderate; 3=High; 4=Severe

Revision date: 10-May-2005

Page 3 of 4

MSDS Ref. No.:

ORTHO Indoor Insect Fogger

011771025

_______________________________________________________________________________________________
EPA FIFRA Comment: Use of this product is regulated by the U.S. Environmental Protection Agency (EPA) through the approved product label. It is a
violation of Federal law to use this product in a manner inconsistent with its labeling.

General comment: This document contains health, safety, and environmental information useful to emergency response agencies, health care
providers, manufacturers, and workers/employees. It does not replace the precautionary language, use directions, or the storage and disposal
information found on the product label.
Revision date:

10-May-2005

Additional Information: This information contained herein is, to the best of Scott's knowledge and belief, accurate and reliable as of the date of
preparation of this document. However, no warranty or guarantee, express or implied, is made as to the accuracy or reliability, and Scotts shall not be
liable for any loss or damage arising out of the use thereof. No authorization is given or implied to use any patented invention without a license. In
addition, Scotts shall not be liable for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices or from
any hazards inherent in the nature of the product.

Revision date: 10-May-2005

Page 4 of 4

S00859
01 00

MATERIAL SAFETY DATA SHEET

===========================================================================
Section 1 −− PRODUCT AND COMPANY IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT NUMBER
HMIS CODES
Health
2
S00859
Flammability
2
Reactivity
0
PRODUCT NAME
HIT SQUAD Industrial Insecticide
MANUFACTURER’S NAME
EMERGENCY TELEPHONE NO.
THE SHERWIN−WILLIAMS COMPANY
(216) 566−2917
Consumer Group − Industrial
Cleveland, OH 44115
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
04−JUN−03
(800) 251−2486
===========================================================================
Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
5
64741−65−7 Mineral Spirits (Odorless)
ACGIH TLV
100 ppm
1 mm
OSHA PEL
100 ppm
92
64742−47−8 Heavy Aliphatic Solvent
ACGIH TLV Not Available
0.1 mm
OSHA PEL Not Available
0.3
Proprietary Fenvalerate
ACGIH TLV Not Available
OSHA PEL Not Available
3
124−38−9 Carbon Dioxide
ACGIH TLV
5000 ppm
OSHA PEL
5000 ppm
===========================================================================
Section 3 −− HAZARDS IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
Irritation of eyes, skin and upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.

Continued on page 2

S00859
page 2
===========================================================================
Section 4 −− FIRST AID MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
If INHALED:

If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
If on SKIN:
Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re−use.
If in EYES:
Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
If SWALLOWED: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 −− FIRE FIGHTING MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
FLASH POINT
LEL
UEL
175 F TCC
1.0
8.8
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self−contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build−up and possible autoignition or explosion when exposed to
extreme heat.
===========================================================================
Section 6 −− ACCIDENTAL RELEASE MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
===========================================================================
Section 7 −− HANDLING AND STORAGE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ENVIRONMENTAL HAZARDS
This product is toxic to fish and aquatic invertebrates. Do not apply
directly to water.
STORAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat and open flame.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Store container upright to prevent leakage. Avoid storage near feed or
food products.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
Continued on page 3

S00859
page 3
===========================================================================
Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Do not spray to contact food, feedstuffs or water supplies. Thoroughly
wash dishes and food−handling utensils contaminated with this product.
It is a violation of Federal law to use this product in a manner
inconsistent with its labeling. Read entire label.
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
===========================================================================
Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT WEIGHT
6.68 lb/gal
800 g/l
SPECIFIC GRAVITY
0.80
BOILING POINT
<0 − 484 F
<−18 − 251 C
MELTING POINT
Not Available
VOLATILE VOLUME
99 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical)
Volatile Weight 96.50 % Less Water and Federally Exempt Solvents
===========================================================================
Section 10 −− STABILITY AND REACTIVITY
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STABILITY −− Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur

Continued on page 4

S00859
page 4
===========================================================================
Section 11 −− TOXICOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
TOXICOLOGY DATA
CAS No.
Ingredient Name
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
64741−65−7
Mineral Spirits (Odorless)
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
64742−47−8
Heavy Aliphatic Solvent
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
Proprietary
Fenvalerate
LC50
RAT
4HR
Not Available
LD50
RAT
451
mg/kg
124−38−9
Carbon Dioxide
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
===========================================================================
Section 12 −− ECOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ECOTOXICOLOGICAL INFORMATION
No data available.
===========================================================================
Section 13 −− DISPOSAL CONSIDERATIONS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
WASTE DISPOSAL METHOD
Waste from this product is not hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.
===========================================================================
Section 14 −− TRANSPORT INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
No data available.
===========================================================================
Section 15 −− REGULATORY INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
No ingredients in this product are subject to SARA 313 (40 CFR 372.65C)
Supplier Notification.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
Continued on page 5

S00859
page 5
===========================================================================
Section 16 −− OTHER INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
This product has been classified in accordance with the hazard criteria
of the CPR and the MSDS contains all of the information required by the
CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

PAGE 1 OF 2
PRODUCT CODE: MG-2, 4
MATERIAL SAFETY DATA SHEET
I. GENERAL INFORMATION
ENFORCER PRODUCTS, INC.
P. O. BOX 1060
CARTERSVILLE, GA. 30120

PRODUCT NAME:

MANUFACTURER’S PHONE NUMBER: (770) 386-0801
24 HOUR EMERGENCY NUMBER: 1-800-255-3924

HAZARD RATINGS:
HEALTH_0_ REACTIVITY_0_
FLAMMABILITY_0_
PERSONAL PROTECTION_0_
EPA REG. NO.: N/A

MOUSE GLUE TRAP

PREPARED BY: TRESSIE DEMPSEY

DATE: NOVEMBER 22, 1999

II. INGREDIENTS
PRINCIPAL COMPONENTS

CAS NUMBER

PERCENT

OSHA PEL

ACGIH TLV

OTHER

HAZARD

NONE

III. PHYSICAL DATA
BOILING POINT: NOT DETERMINED

SPECIFIC GRAVITY:

0.95 TO 1.08

VAPOR PRESSURE (mm Hg.): N/A

PERCENT VOLATILE BY VOLUME: N/A

VAPOR DENSITY: N/A

SOLUBILITY IN WATER: NOT SOLUBLE

APPEARANCE & ODOR: OFF-WHITE TO TAN COLORED TACKY SOLID WITH REINOUS
ODOR

EVAPORATION RATE (Butyl Acetate = 1): N/A

IV. FIRE & EXPLOSION DATA
FLASHPOINT (Method used): > 400°F

AUTOIGNITION TEMPERATURE: N/A

LEL: N/A

EXTINGUISHING MEDIA: WATER SPRAY, FOAM, DRY CHEMICAL

UEL: N/A

FLAMMABLE LIMITS: NOT DETERMINED

SPECIAL FIRE FIGHTING PROCEDURES:

WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES.

UNUSUAL FIRE & EXPLOSION HAZARDS:

DECOMPOSITION MAY PRODUCE SMOKE, HAZARDOUS CHEMICALS SUCH AS COx, NOx
AND OTHER UNKNOWN HAZARDOUS.

V. REACTIVITY HAZARD DATA
STABILITY: |X| STABLE
| | UNSTABLE

CONDITIONS TO AVOID: OVER-HEATING

INCOMPATABILITY (Materials to
avoid):
HAZARDOUS POLYMERIZATION:

OXIDIZING MATERIALS MAY CAUSE REACTION.
| | WILL OCCUR

| X | WILL NOT OCCUR

HAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF CARBON AND SMOKE.

CONDITIONS TO AVOID: NONE KNOWN

PAGE 2 OF 2
PRODUCT CODE: MG-2, 4
VI. HEALTH HAZARD DATA
PRIMARY ROUTES OF ENTRY:

INHALATION | |

INGESTION | |

SKIN ABSORPTION | |

EYE | |

NOT HAZARDOUS | X |

ACUTE EFFECTS OF OVEREXPOSURE:
INGESTION:

NONE

SKIN CONTACT:

NONE

INHALATION:

NONE

EYE CONTACT:

NONE

CHRONIC EFFECTS OF OVEREXPOSURE:
CARCINOGENICITY:

NONE

NTP? N/A

IARC? N/A

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:

OSHA REGULATED? N/A

NONE KNOWN.

EMERGENCY FIRST AID PROCEDURES:
INGESTION:

FREE THROAT FROM BLOCKAGE.

SKIN CONTACT:

WASH WITH SOAP AND WATER.

INHALATION:

GET FRESH AIR.

EYE CONTACT:

FLUSH WITH WATER.

VII. CONTROL AND PROTECTIVE MEASURES
EYE PROTECTION:

NONE

RESPIRATORY PROTECTION (specify):

NONE

SKIN PROTECTION:

NONE

VENTILATION:

NONE

OTHER PROTECTION:

NONE

VIII. SPECIAL PRECAUTIONS
HANDLING AND STORING PROCEDURES:

NONE

RELEASE OR SPILL PROCEDURES:

SWEEP UP AND PLACE IN A CONTAINER FOR DISPOSAL.

WASTE DISPOSAL METHOD:

DISPOSE OF AS A SOLID WASTE.

OTHER PRECAUTIONS:

KEEP THIS AND ALL CHEMICALS OUT OF REACH OF CHILDREN AND PETS.

IX. ADDITIONAL INFORMATION
PROPER DOT SHIPPING NAME:

DEVICE, NOS (NOT DOT / IMO REGULATED)

BIODEGRADABILITY:

NOT BIODEGRADABLE

LEAK PROCEDURES:

NOT LIKELY, A RESINOUS SOLID.

THIS INFORMATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200.
********************** END OF REPORT **********************

PAGE 1 OF 2
PRODUCT CODE: RG-2
MATERIAL SAFETY DATA SHEET
I. GENERAL INFORMATION
ENFORCER PRODUCTS, INC.
P. O. BOX 1060
CARTERSVILLE, GA. 30120

PRODUCT NAME:

MANUFACTURER’S PHONE NUMBER: (770) 386-0801
24 HOUR EMERGENCY NUMBER: 1-800-255-3924

HAZARD RATINGS:
HEALTH_0_ REACTIVITY_0_
FLAMMABILITY_0_
PERSONAL PROTECTION_0_
EPA REG. NO.: N/A

ENFORCER RAT AND MOUSE GLUE TRAP

PREPARED BY: TRESSIE DEMPSEY

DATE: NOVEMBER 22,1999

II. INGREDIENTS
PRINCIPAL COMPONENTS

CAS NUMBER

PERCENT

OSHA PEL

ACGIH TLV

OTHER

HAZARD

NONE

III. PHYSICAL DATA
BOILING POINT: NOT DETERMINED

SPECIFIC GRAVITY:

0.95 TO 1.08

VAPOR PRESSURE (mm Hg.): N/A

PERCENT VOLATILE BY VOLUME: N/A

VAPOR DENSITY: N/A

SOLUBILITY IN WATER: NOT SOLUBLE

APPEARANCE & ODOR: OFF-WHITE TO TAN COLORED TACKY SOLID WITH RESINOUS
ODOR.

EVAPORATION RATE (Butyl Acetate = 1): N/A

IV. FIRE & EXPLOSION DATA
FLASHPOINT (Method used): > 400°F (COC)

AUTOIGNITION TEMPERATURE: N/A

LEL: N/A

EXTINGUISHING MEDIA: WATER SPRAY, FOAM, DRY CHEMICAL

UEL: N/A

FLAMMABLE LIMITS: NOT DETERMINED

SPECIAL FIRE FIGHTING PROCEDURES:

WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES.

UNUSUAL FIRE & EXPLOSION HAZARDS:

DECOMPOSITION MAY PRODUCE SMOKE, HAZARDOUS CHEMICALS SUCH AS COx, NOx
AND OTHER UNKNOWN HAZARDOUS SUBSTANCES.

V. REACTIVITY HAZARD DATA
STABILITY: |X| STABLE
| | UNSTABLE

CONDITIONS TO AVOID: OVER-HEATING

INCOMPATABILITY (Materials to avoid):

OXIDIZING MATERIALS MAY CAUSE REACTION.

| X | WILL NOT
OCCUR
HAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF CARBON AND SMOKE.
HAZARDOUS POLYMERIZATION:

| | WILL OCCUR

CONDITIONS TO AVOID: NONE KNOWN

PAGE 2 OF 2
PRODUCT CODE: RG-2
VI. HEALTH HAZARD DATA
PRIMARY ROUTES OF ENTRY:

INHALATION | |

INGESTION | |

SKIN ABSORPTION | |

EYE | |

NOT HAZARDOUS | X |

ACUTE EFFECTS OF OVEREXPOSURE:
INGESTION:

NONE

SKIN CONTACT:

NONE

INHALATION:

NONE

EYE CONTACT:

NONE

CHRONIC EFFECTS OF OVEREXPOSURE:
CARCINOGENICITY:

NONE

NTP? N/A

IARC? N/A

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:

OSHA REGULATED? N/A

NONE KNOWN.

EMERGENCY FIRST AID PROCEDURES:
INGESTION:

FREE THROAT FROM BLOCKAGE.

SKIN CONTACT:

WASH WITH SOAP AND WATER.

INHALATION:

GET FRESH AIR.

EYE CONTACT:

FLUSH WITH WATER.

VII. CONTROL AND PROTECTIVE MEASURES
EYE PROTECTION:

NONE

RESPIRATORY PROTECTION (specify):

NONE

SKIN PROTECTION:

NONE

VENTILATION:

NONE

OTHER PROTECTION:

NONE

VIII. SPECIAL PRECAUTIONS
HANDLING AND STORING PROCEDURES:

NONE

RELEASE OR SPILL PROCEDURES:

SWEEP UP AND PLACE IN A CONTAINER FOR DISPOSAL.

WASTE DISPOSAL METHOD:

DISPOSE OF AS A SOLID WASTE.

OTHER PRECAUTIONS:

KEEP THIS AND ALL CHEMICALS OUT OF REACH OF CHILDREN AND PETS.

IX. ADDITIONAL INFORMATION
PROPER DOT SHIPPING NAME:

DEVICE, NOS (NOT DOT / IMO REGULATED)

BIODEGRADABILITY:

NOT BIODEGRADABLE

LEAK PROCEDURES:

NOT LIKELY, A RESINOUS SOLID.

THIS INFORMATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200.
********************** END OF REPORT **********************

Material Safety Data Sheet
Calcium hypochlorite, available chlorine >65%
ACC# 03990

Section 1 - Chemical Product and Company Identification
MSDS Name: Calcium hypochlorite, available chlorine >65%
Catalog Numbers: AC199030010, AC199030200, AC300340000, AC300340010, AC300340050,
AC300341000, S79945, C100-250, C100-500
Synonyms: Calcium oxychloride; losantin; Hypochlorous acid; Calcium salt; Lime chloride
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887

Section 2 - Composition, Information on Ingredients
CAS#
7778-54-3

Chemical Name
Calcium hypochlorite

Percent

EINECS/ELINCS

100

231-908-7

Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Appearance: white crystalline powder.
Danger! Strong oxidizer. Contact with other material may cause a fire. Corrosive. Causes eye
and skin burns. Harmful if swallowed. Contact with acids liberates toxic gas. May cause severe
respiratory tract irritation with possible burns. May cause severe digestive tract irritation with
possible burns. Air sensitive.
Target Organs: Lungs, respiratory system, eyes, skin, mucous membranes.
Potential Health Effects
Eye: Causes eye burns. May result in corneal injury. May cause blindness. May cause blepharitis
(inflammation of the margins of the eyelids).
Skin: Causes severe burns with delayed tissue destruction.
Ingestion: Harmful if swallowed. May cause severe and permanent damage to the digestive tract.
May cause perforation of the digestive tract. Causes digestive tract burns with immediate pain,
swelling of the throat, convulsions, and possible coma. Ingestion of Calcium hypochlorite solutions
may cause death. As little as 1 ounce may be lethal if the available chlorine concentration exceeds
15%.
Inhalation: Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary
edema. May cause systemic effects. Causes corrosive action on the mucous membranes.
Chronic: Prolonged or repeated skin contact may cause dermatitis. Prolonged or repeated eye
contact may cause conjunctivitis. Effects may be delayed.

Section 4 - First Aid Measures
Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy
contaminated shoes.
Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or
water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air
immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If
breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in pressuredemand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact
with other material may cause fire. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Use water spray to keep fire-exposed
containers cool. Use water with caution and in flooding amounts. Contaminating or mixing with
foreign materials such as combustibles, grease, and fuels can cause fire. Containers may explode
when heated.
Extinguishing Media: Use water only! Do NOT use carbon dioxide or dry chemical. Contact
professional fire-fighters immediately. Cool containers with flooding quantities of water until well
after fire is out.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 3; Flammability: 0; Instability: 1; Special Hazard: OX

Section 6 - Accidental Release Measures
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up
spills immediately, observing precautions in the Protective Equipment section. Avoid generating
dusty conditions. Remove all sources of ignition. Provide ventilation. Do not get water inside
containers. Do not use combustible materials such as paper towels to clean up spill.

Section 7 - Handling and Storage
Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse.
Use only in a well-ventilated area. Minimize dust generation and accumulation. Do not get in eyes,

on skin, or on clothing. Keep container tightly closed. Keep away from heat, sparks and flame.
Avoid contact with clothing and other combustible materials. Do not ingest or inhale. Discard
contaminated shoes. Use only a clean, dry scoop made of metal or plastic each time product is
taken from container. Never use scoops containing remnants of other products as it may cause a
violent reaction leading to fire or an explosion.
Storage: Keep away from sources of ignition. Do not store near combustible materials. Do not
store in direct sunlight. Keep container closed when not in use. Store in a tightly closed container.
Keep away from acids.

Section 8 - Exposure Controls, Personal Protection
Engineering Controls: Facilities storing or utilizing this material should be equipped with an
eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations
low.
Exposure Limits
Chemical Name
Calcium hypochlorite

ACGIH
none listed

NIOSH

OSHA - Final PELs

none listed

none listed

OSHA Vacated PELs: Calcium hypochlorite: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's
eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI
Z88.2 requirements or European Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.

Section 9 - Physical and Chemical Properties
Physical State: Crystalline powder
Appearance: white
Odor: strong odor - chlorine-like
pH: 11.4 (1% aq. sol.)
Vapor Pressure: Not applicable.
Vapor Density: Not applicable.
Evaporation Rate:Not applicable.
Viscosity: Not available.
Boiling Point: Decomposes
Freezing/Melting Point:100 deg C
Decomposition Temperature:180 deg C
Solubility: Slightly soluble.
Specific Gravity/Density:2.350
Molecular Formula:CaCl2O2
Molecular Weight:142.9848

Section 10 - Stability and Reactivity

Chemical Stability: All hypochlorite solutions are unstable and slowly decompose on contact with
air. Calcium hypochlorite is corrosive to most metals and will evolve toxic chlorine and chlorine
monoxide gas when heated above 350°F. Sudden heating above 212°F may cause an explosion.
Pure, dry calcium hypochlorite is not sensitive to friction or impact. However, in the presence of
small amounts of water, it can decompose to form dangerously unstable dichlorine monoxide,
which is sensitive to friction, shock or static spark.
Conditions to Avoid: Ignition sources, dust generation, excess heat, moisture, high humidity.
Incompatibilities with Other Materials: Reducing agents, ammonia, iron oxide, phenols, sulfur,
aliphatic amines, acetylene, cyanides (e.g. potassium cyanide, sodium cyanide), sulfides
(inorganic, e.g. ferric sulfide, lead sulfide, sodium sulfide), carbontetrachloride, aromatic amines,
carbon, ammonium chloride, charcoal, glycerol, air, ethanol, menthol, rust, hydroxy compounds
(e.g. ethanol, ethylene glycol, gycerol, sugar), metal oxides, turpentine, diethylene glycol
monomethyl ether, acetic acid + potassium, N,N-dichloromethylamine + heat, 1-propanethiol,
isobutanethiol, sodium hydrogen sulfate + starch + sodium carbonate, combustible materials (e.g.
anthracene, grease, oil, mercaptans, methyl carbitol, nitromethane, organic matter, and
propylmercaptan).
Hazardous Decomposition Products: Hydrogen chloride, oxygen, chlorine, calcium hydroxide,
calcium carbonate, dichlorine monoxide, Calcium chlorate.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information
RTECS#:
CAS# 7778-54-3: NH3485000
LD50/LC50:
CAS# 7778-54-3:
Oral, rat: LD50 = 850 mg/kg;
.
Carcinogenicity:
CAS# 7778-54-3: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: Mutation in bacteria.
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information
Ecotoxicity: Fish: Striped bass: LC50 = 0.5 mg/L; 24 Hr; Static bioassay (70% hypochlorite)

Section 13 - Disposal Considerations
Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts
261.3. Additionally, waste generators must consult state and local hazardous waste regulations to

ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information
US DOT

Canada TDG

Shipping Name:

CALCIUM HYPOCHLORITE, DRY

CALCIUM HYPOCHLORITE, DRY

Hazard Class:

5.1

5.1

UN Number:

UN1748

UN1748

Packing Group:

II

II

Section 15 - Regulatory Information
US FEDERAL
TSCA
CAS# 7778-54-3 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 7778-54-3: 10 lb final RQ; 4.54 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 7778-54-3: immediate, fire.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7778-54-3 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7778-54-3 can be found on the following state right to know lists: California, New Jersey,
Pennsylvania, Massachusetts.
California Prop 65
California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
OCN
Risk Phrases:
R 22 Harmful if swallowed.
R 31 Contact with acids liberates toxic gas.
R 34 Causes burns.
R 8 Contact with combustible material may cause fire.
R 50 Very toxic to aquatic organisms.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
otection.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 61 Avoid release to the environment. Refer to special instructions
/safety data sheets.
WGK (Water Danger/Protection)
CAS# 7778-54-3: 2
Canada - DSL/NDSL
CAS# 7778-54-3 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of C, E.
This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List

Section 16 - Additional Information
MSDS Creation Date: 7/19/1999
Revision #7 Date: 5/16/2007
The information above is believed to be accurate and represents the best information currently available to us. However, we make
no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no
liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their
particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any
special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.

f

8RENNTAG~II_II.
BRENNTAG
MID-SOUTH,
INC.

MATERIAL SAFETY DATA SHEET

Effective

Date:

July 19, 2004

SODIUM
HYPOCHLORITE
SOLUTION
L

SECTIONI -MATERIAL mENTIFIC~TiON

MANUFACTURER'S

BRENNTAG

NAME & ADDRES~:

MID-SOUTH,

EMERGENCY

Inc.

TELEPHONE

.::J

NUMBER:

270-830-1222

1405 Highway 136 West / Geneva Road
Henderson, Kentucky 42420
CHEMICAL NAME AND SYNONYMS:
Sodium Hypochlorite Solution (10-14.2%); Hypochlorite Solution; Bleach Solution,
Hypochlorous acid, sodium salt, &/or AB Bleach; sodium hypochlorite/DIWater
CHEMICAL

FAMILY:

Hypochlorite

C'

FORMULA:

SECTION

n -HAZARDOUS

NaOCI

INGRED
THRESHOLD LIMIT VALUES (UNITS)
OSHA:
_1
ACGm:
PEL
J STEL I
TLV
1 STEL

CAS
NUMBER

CHEMICAL
NAME(S)

.WT
%

7681-52-9

Sodium hypochlorite**

10 -14.2

1310-73-2

Sodium hydroxide

0.3-1.0

7647-14-5

Sodium Chloride

9 -12.5

-NON

497-19-8

Sodium carbonate

::;0.5

-NONE

ESTABLISHED

-

7732-18-5

Water

Balance

-NONE

ESTABLISHED

-

-NON
2mgim3Ceiling

E EST

A B LIS

1

1

E EST

A B LIS

H ED -

2mgim3Ceiling
H ED

1

-

-

This product does not contain any chemical (5) subject to reporting requirements of Section 313, Title III of SARA, Part 372.
** %(w/w) as CI1 9.5 to 13.55% TL vrrw A (ACGIH) O.5ppm C11; TL V/STEL (ACGIH) Ippm CI1 & PEL (OSHA) Ippm CI1

CO
BOILING

SECTIONllI-PHYSICALDATA
POINT

of (OC): 110°Cfor15%NaOCI

I

SPECIFIC GRAVITY lH!O=l):

VAPOR DENSITY (AIR =1): n.a.

EVAPORATION

VAPOR PRESSURE (mmH2): Vapor pressure of
water plus decomposition products.

PERCENT VOLATILE

SOLU~ILITY

IN WATER:

Complete

APPEARANCE
...';'

l

SECTION

IV -FIRE

AND EXPLOSION

FLASH POINT (METHOD USED): Non -flammable
EXTINGUISHING

MEDIA:

.FLAMMABLE

RATE:

1.08-1.27

n.a.
BY VOLUME (%): Water vapor plus
decomposition products.

AND ODOR: Light, yellow-green liquid
with pungent-like chlorine odor.

HAZARD
LIMITS

D

(% BY VOLUME):

n.a.

Use water spray, fog, foam, dry chemicals, or carbon dioxide.

SPECIAL FIRE FIGHTING PROCEDURES: Firefighters'shouldwearprotectiveequipmentincluding self containedbreathingapparatus.
Avoid fumes. Dilute spill with copius amountsof water.ventilate. Be preparedto userespirator.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Possiblevigorous reactionupon contaminationwith organics or oxidizing agents.
Bleachdecomposeswhen heated,decompositionproductsmaycausecontainersto ruptureor explode. Many reactionscan causefire and explosion.
This material will reactwith somemetalswhich maycauseliberationof oxygen. Toxic fumescanbe liberated by contact with acid or heat.

C:\RDl\WORD\MSDS\MSSOHYPO.DOC

Page I of 5

FORMATREVISIONDATE: April 23. 2001

.';1:'

~j

BRENNTAG~II_I(~
BRENNTAG
MID-SOUTH,INC.

-

MATERIAL SAFETYDATA SHEET

Effective Date: July 19, 2004

SODIUM HYPOCHLORITE

SOLUTION

Vigorousreactionscanoccurwith oxidizablematerials
andorganics.Keepmaterialcool usinga watersprayfroma safedistance.Keepall
unnecessary
peopleaway. Stayup windandstayoutof low-lyingareas.

I

SECTION

V -HEAL

EFFECTS

TH HAZARD

DATA

I

OF OVEREXPOSURE:

PRECAUTIONARY STATEMENTS (Hazards
to humans
anddomesticanimals):Danger! Corrosive! May causesevereskin and eye
irritation or chemicalbums to brokenskin. Causeseyedamage.Exposureto skin may causesensitizationor other allergic responses.
INHALATION: Corrosive! Productmay causesevereirritation of the nose,throatand respiratorytract. Repeatedand/orprolonged
exposuresmay causeproductive cough, runny nose,bronchopneumonia,
pulmonaryedema(fluid build-up in lungs), and reductionof
pulmonaryfunction. Repeatedinhalationexposuremay causeimpairmentof lung functionand permanentlung damage.
EYE CONTACT: Extremelycorrosive! This productcausescornealscarringandclouding. Glaucoma,cataractsand permanent
blindnessmay occur.
SKIN CONTACT: Corrosive! Concentratedsolutionsmay causepain and deepandseverebums to the skin. Prolongedand
repeatedexposureto diluted solutions oftencausesirrita~ion,redness,pain anddrying andcracking of the skin. Human evidencehas
indicatedthat an ingredientin this productcancauseskin sensitization.
INGESTION: Corrosive! Will immediatelycauseseverecorrosionof and damageto the gastrointestinaltract. Exposure
characterizedby nausea,vomiting, diarrhea,abdominalpain, bleeding,and/ortissueulceration.
PRIMARY ROUTES OF ENTRY: Inhalationandcontact.
CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN: ~/No
* as Chlorine

~/No

OSHA/No ACGllI/A4*

EMERGENCY AND FIRST AID PROCEDURES:
INHALATION:

Removevictim to freshair. Give artificial respirationif not breathing. Get medicalattention.

EYE CONTACT: Washeyeswith plenty of waterfor at least15 minuteswhile holding eyelidsopen. Consultan eye specialist
immediately.
SKIN CONTACT: Flush skin with plenty of waterwhile removingcontaminatedclothing. Get medical attentionfor persistent
irritation. Cleanclothing before reuse.
INGESTION: If swallowed drink large quantitiesof water. Do NOT inducevomiting. Call a poison control centeror doctor
immediatelyfor treatmentadvice. If spontaneous
vomiting °£C.UfS,
have victim leanforward with head down to avoid breathing in of
vomitus,rinse mouthand administermore water.

I

SECTION

VI -TOXICOLOGICAL

INFO

TI

TOXICITY DATA:

Oral LD50: 8,910mgikg. (Rats)
Acute dermaltoxicity: III; LD50, > 3,000mgikg
Dermal LD 50: > 10,000mgikg.(Rabbits)
Primaryeye irritati9n: I; Corrosive
Inhalation 0.25-hourLC 50: >10.5 mg/l (Rats)
Primary skin irritation: I; Corrosive
Acute oral toxicity: IV; LD50, 192mgikg
SUMMARY: The concentratedsolution is corrosiveto skin, and a 5% solutionis a severeeye irritant. Solutionscontainingmore
than 5% availablechlorine are classified by DOT corrosive.Toxicity describedin animalsfrom single exposuresby ingestion
includesmuscularweakness,and hyperactivity. Repeatedingestionexposurein animalscausedan increasein the relative weight of
adrenalglands in one study,but no pathologicalchangewere observedin two otherstudies. Long-term administrationof compound
C:\RDI\WORD\MSDS\MSSOHYPO.DOC

Page2 of 5

FORMAT
REVISION
DATE:April23.2001

.BR~~NTA::

BRENNTAGMID-SOUTH, INC.

-

MATERIAL SAFETY DATA SHEET

Effective Date: July 19, 2004

SODIUM HYPOCHLORITE

SOLUTION

in drinking water of ratscauseddepressionof the immunesystem. No adversechangeswere observedin an eight-weekdermal study
of a 1% solution in guineapigs. Tests in animalsdemonstrateno carcinogenicactivity by eitherthe oral or dermalroutes. Tests in
bacterialand mammaliancell culturesdemonstratemutagenicactivity.
I

SECTION

VII

-ECOLOGICAL

INFORMATION

I

ENVIRONMENTAL HAZARDS: This pesticideis toxic to fish and aquaticorganisms.Do not dischargeeffluents containingthis
productinto lakes,streams,ponds,estuaries,oceansor otherwatersunlessin accordancewith the requirementsof a National
PollutantDischargeElimination System(NPDES)permit and the permitting authorityhas beennotified in writing prior to discharge.
Do not dischargeeffluent containingthis productto sewersystemswithout previouslynotifying the sewagetreatmentplant authority.
For guidance,contactyou State WaterBoard or RegionalOffice of the EPA.
Acute oral-bobwhitequail: LD50, > 2510mgikg
Acute dietary-mallardduck: LC50, > 5220 ppm
Acute dietary-bobwhitequail: LC50, > 5620ppm
Acute fish-rainbowtrout: LC50, 0.18-0.22mgil
Acute fish-bluegill sunfish: LC50, 0.44-0.79mgil
I

SECTION
STABILITY:

Acute invertebrate-daphnia:
LC50, 0.033-0.048mg/l
Fatheadminnows: 96-hourLC50, 5.9 mg/LO
RainbowTrout: 96-hourLC50, 0.2mg/liter
Bluegill sunfish: 96-hourLC50, 0.58mg/liter

vm

-REACTIVITY

Unstable (Contingent
upontemperature,

DATA

I

HAZARDOUS POLYMERIZATION:

Will not occur.

contamination(metals),and pH.)

CONDITIONS TO AVOW:
copperand iron.

Heat, light exposure,decreasein pH, and contaminationwith heavymetals, suchas nickel, cobalt,

INCOMPATffiILITY (MATERIALS TO AVOm): Heavy metals,reducingagents,organics,ether,ammonia, ammoniumacetate,
ammoniumcarbonate,ammoniumnitrate, ammoniumoxalate,ammoniumphosphate,ureaand acids.
HAZARDOUS DECOMPOSITION PRODUCTS: Hypochlorousacid, chlorine,hydrochloric acid, sodiumchloride, sodium
chlorate,and oxygen. Decompositionof sodiumhypochloritetakesplace within a few secondswith following salts: ammonium
acetate,ammoniumcarbonate,ammoniumnitrate,ammoniumoxalate,and ammoniumphosphate.Hypochlorites reactwith ureato
form nitrogentrichloride, which explodesspontaneouslyin air.
I

SECTION

IX -SPILL

OR

LEAK

PROCEDURES

I

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Personnelwith properprotective equipment
~houldcontainspill. Flush areawith large amountsofwater,.;t)se reducing agentssuchasbisulfites or ferrous salt solutionsto
neutralize.
WASTE DISPOSAL METHOD: Disposalis to be in accordancewith all Federal,State,and Local regulations.

SECTION

X -SPECIAL

PROTECTION

INFORMATION

RESPIRATORY PROTECTION: Whenfumespresent,useNIOSH approvedrespiratorwith acid type canister.
VENTILATION:

Local exhaustpreferableasrequiredto control fumes.

PROTECTIVE GLOVES: Rubberor plastic.

EYE PROTECTION: Chemicalgoggles.

OTHER PROTECTIVE EOUIPMENT: Clothing to protectskin. Safetyshowerandeye washfountain.
C:\RDl\WORD\MSDS\MSSOHYPO.DOC

1_'.-

Page3 of 5

FORMAT
REVISION
DATE:April23,2001

0_- Ow,",

"~;~."'m-

BRENNT
AGMID-SOUTH,
INC.

~II-

BRENNTAG~
1111.1

MATERIAL SAFETY DATA SHEET

Effective Date: July 19, 2004

SODIUM HYPOCHLORITE

I

SECTION

XI -SPECIAL

SOLUTION

PRECAUTIONS

-l

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Storethis productin a cool dry area; away form direct
sunlight and heatto avoid deterioration. In caseof spill, flood areaswith largequantitiesof water. Productor rinsatesthat cannotbe
usedshouldbe diluted with waterbefore disposalin a sanitarysewer. Do not reusecontainer. Do not contaminatefood or feed by
storage,disposalor cleaning of equipment. Mostmetalsand metalalloys are NOT suitablefor use in contactwith sodium
hypochlorite solutionsincluding aluminum, brass,bronze,copper,castiron, galvanizedsteel,mild steel,nickel, or stainlesssteel,
sincethesemetals act asa catalystwhich will causerapid decompositionof the sodiumhypochlorite solution through the releaseof

oxygen.
Sodiumhypochlorite solutionsare basically unstable,and on exposureto heatand/orlight, will slowly decompose,becomingless
concentratedwith time. Sodiumhypochloritesolutionsshould neverbe allowedto contactor mix with acids or other low pH
compounds,due to the releaseof chlorine gas. Do not allow sodiumhypochloriteto mix with ammonia,since chloroaminesmaybe
formed.
Decompositionof sodiumhypochlorite takesplacewithin a few secondswith following salts: ammoniumacetate,ammonium
carbonate,ammoniumnitrate, ammoniumoxalate,and ammoniumphosphate.
Hypochlorites reactwith ureato form nitrogentrichloride, which explodesspontaneouslyin air.
Solutions of sodiumhypochloriteare corrosiveto the skin,eyes,and mucousmembranes.Propersafety equipmentshouldbe used
whenworking with or in close proximity of sodiumhypochlorite.
OTHER PRECAUTIONS: Use with adequateventilation. Washthoroughly afterhandling. Do not get in eyes, on skin or clothing.
Do NOT breathefumes or mist. Mixing this productwith chemicals(e.g. commonhouseholdcleaners,ammonia, acids,detergents,
etc.) or organic matterwill releasechlorine gas,which is irritating to eyes,lungs,and mucousmembranes.
STRONGOXIDIZING AGENT: Mix only with wateraccordingto labeldirections. Mixing this product with chemicals(e.g.
commonhouseholdcleaners,ammonia,acids,detergents,etc.) or organic matter(e.g. urine,feces,etc.) will releasechlorine gas,
which is irritating to eyes,lungs and mucousmembranes.
HAZARD RATING:

Health 3

SECTION

Flammability 0

XII -D.O. Ti' .SHIPPING

Reactivity 2

INFORMATION

PROPER SHIPPING .NAME: Hypochlorite Solutions
HAZARD CLASS: 8 (Corrosive)
D.O.T. LABEL REQUffiED: Corrosive

C:\RD1\WORD\MSDS\MSSOHYPO.DOC

UN/NA: UN 1791

PACKING GROUP: III

~EPORTABLE OUANTITY OF PRODUCT: 800 to 2,000 lbs.

Page4 of 5

FORMAT
REVISION
DATE:April23.2001

"

.~'"

BRENNTAG ..8.1;
-

BRENNTAG MID-SOUTH, INC.
MATERIAL

SAFETY

Effective

Date:

DATA SHEET

July 19, 2004

SODIUM HYPOCHLORITE

I

SECTION
TSCA (Toxic
CERCLA

Substance Control Act}:

AND SARA

XIII

SARA Extremely

Discharge

AIR ACT':

OTHER REGULA
Know Laws.

"

= 100 pounds (100% NaOCl)

Acute:

yes

CERCLA

Hazardous Material:

SARA Toxic Chemical:
Chronic:

yes

Fire: no

This product does not contain nor is it manufactured

nONS/LEGISLA

INFORMATION

40 CFR §300-373:

Hazardous substance: No

Title III Hazard Classifications:
EPA " CLEAN

TORY

All components of this product are listed on the TSCA inventory.

REGULA nONS,

Super fund Reportable

-REGULA

SOLUTION

TION THAT APPLY

TO THIS PRODUCT:

Reactivity:

yes

yes

No
Pressure: No

with ozone depleting substances.
Massachusetts, Pennsylvania, and New Jersey Right-to

,,~~'.'

~i.E
BRENNTAd MI~O~~~~GEVEs
~T
THE ~Fo~rib~~6NT
AlNED HEREIN IS FACfUAL; rr IS NOT TO BE TAKEN AS A
WARRANTY OR REPRESENTATIONFOR WlDCH BRENNTAG MID-SOUTH, INC. ASSUMESLEGAL RESPONSffiILITY. rr IS OFFERED SOLELY FOR
YOUR CONSffiERA TION, INVESTIGATION AND VERIFICATION. ANY USE OF THIS INFORMATION AND DATA MUST BE DETERMINED BY THE
USERTO BE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
,
"""

:I:

~

A(iJJ~ 71

,::;(P
'f:~~~~~~~
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C:\RDI\WORD\MSDS\MSSOHYPO.DOC

"-_~_k!CJ,",

",'-

"!'::

~~~~-

:=

..

Page 5 of 5

FORMAT REVISION DATE: April 23, 2001

MATERIAL SAFETY DATA SHEET

1.

CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME:
Product ID:
SYNONYMS:
No. 0310
ISSUE DATE:
EDITION NO.:

Pittclor® Dry Chlorinating Granules
0310D
Calcium Hypochlorite Granular; Cal Hypo Granules; Ca(OCl) 2; MSDS
03/09/2007
11

PPG Industries, Inc.
One PPG Place, Pittsburgh, PA 15272, USA
24-hour Emergency Telephone Number: 1-412-434-4515
For Product Information (8am-5pm Eastern time):
1-800-245-2974 (Cal Hypo)

PREPARER:

Product Safety, Chemicals

2.

COMPOSITION/INFORMATION ON INGREDIENTS

Material/CAS Number

Percent

Calcium Hypochlorite
7778-54-3
Calcium Chlorate
10137-74-3
Calcium Carbonate
471-34-1
Calcium Hydroxide
1305-62-0

>65
<2
<2
<2

Note: Minimum 65% Available Chlorine. 35% inert ingredients (includes 5.5-8.5% water).

3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
DANGER! Corrosive - Causes severe and irreversible burns to eye and skin. Harmful if inhaled. May
cause irritation and inflammation to the respiratory tract. Harmful or fatal if swallowed. Strong
Oxidizing Agent! Mix only with water. Never add water to product. Always add the product to large
quantities of water. Do not mix with any other chemicals. Contamination with moisture, acids, organic
materials and other easily combustible materials such as petroleum, paint products, wood or paper
Page 1 of 7

PPG:

0310D Pittclor® Dry Chlorinating Granules

03/09/2007

may cause fire or explosion and the liberation of hazardous gases. Do not add this product to any
dispensing device containing remnants of any other product. Such use may cause violent reaction
leading to fire or explosion. Very toxic to aquatic organisms.
Precautions:
Do not get in eyes, on skin, or on clothing. Avoid breathing dust. Irritating to nose
and throat. Do not swallow. Do not eat, drink or smoke in work area. Wash hands after handling.
Remove and wash contaminated clothing before reuse. Keep out of reach of children.

4.

FIRST AID MEASURES

INHALATION: Remove from area to fresh air. If symptomatic, contact a poison control center,
emergency room or physician for treatment information.
EYE/SKIN CONTACT: EYE: Remove contact lens and pour a gentle stream of warm water
through the affected eye for at least 15 minutes. Contact a poison control center, emergency room or
physician right away as further treatment will be necessary. SKIN: Run a gentle stream of water over
the affected area for 15 minutes. A mild soap may be used if available. Contact a poison control
center, emergency room or physician right away as further treatment will be necessary.
INGESTION:
Gently wipe or rinse the inside of the mouth with water. Sips of water may be given
if person is fully conscious. Never give anything by mouth to an unconscious or convulsing person.
Do Not induce vomiting. Contact a poison control center, emergency room or physician right away as
further treatment will be necessary.

5. FIRE-FIGHTING MEASURES
FLASH POINT:

Not Applicable.

EXTINGUISHING MEDIA: Drench with large quantities of water only. Do not use dry chemicals or
foams. Product supplies own oxygen, therefore attempts to smother fire with a wet blanket, carbon
dioxide, dry chemical extinguisher or other means are not effective.
SPECIAL FIREFIGHTING PROCEDURES: Product decomposes at approximately 338-356°F (170180°C) releasing oxygen gas. Container may rupture. Fire-fighters must wear NIOSH approved,
pressure demand, self-contained breathing apparatus with full face piece for possible exposure to
hazardous gases. Emits toxic fumes under fire conditions.

6.

ACCIDENTAL RELEASE MEASURES

ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
Use extreme caution in handling spilled material. Do not mix with any other chemicals.
Contamination with moisture, acids, organics or other easily combustible materials such as
petroleum, paint products, wood or paper may cause fire or violent decomposition. If fire or
decomposition occurs in area of spill, immediately douse with plenty of water. Otherwise, sweep up
all visible material using a clean (new, if possible), dry shovel and broom and dissolve material in
water. Spilled material that has been swept up and dissolved in water should be used immediately in
the normal application for which this product is being consumed.

7. HANDLING AND STORAGE

Page 2 of 7

PPG:

0310D Pittclor® Dry Chlorinating Granules

03/09/2007

PRECAUTIONS TO BE TAKEN DURING HANDLING AND STORAGE:
Store in a cool, dry, well-ventilated place. Keep in original container. Keep container closed when not
in use. Keep away from heat, sparks, flames, direct sunlight, and other sources of heat, including
lighted tobacco products. Use only a clean (new, if possible), dry scoop made of metal or plastic each
time product is taken from the container. Do not add this product to any dispensing device containing
remnants of any other product. Such use may cause violent reaction leading to fire or explosion. Add
this product only to water. Never add water to product. Always add the product to large quantities of
water. May cause fire or explosion if mixed with other chemicals. Fire may result if contaminated with
acids, organic materials and other easily combustible materials such as oil, kerosene, gasoline, paint
products wood and paper. Do not reuse container. Residual material remaining in empty container
can react to cause fire. Thoroughly flush empty container with water then destroy by placing in trash
collection. Do not contaminate water, food, or feed by storage or disposal of this product.

8.

EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Limits:
8-hour Time Weighted Average (TWA); 15-minute Short-Term Exposure Limit (STEL)
OSHA: The OSHA exposure limit(s) for Calcium hydroxide: 5 mg/m3 TWA. Calcium carbonate: 15
mg/m3 (total dust) 5 mg/m3 (respirable dust)
ACGIH: The ACGIH exposure limit(s) for Calcium hydroxide: 5 mg/m3 TWA. Calcium carbonate: 10
mg/m3 (total dust) 3 mg/m3 (respirable nuisance particulate) TWA.
ONTARIO: The Ontario Exposure limit(s) for Calcium hydroxide: 5 mg/m3TWAEV Calcium
carbonate: 10 mg/m3TWAEV
PPG Internal Permissible Exposure Limit (IPEL):
TWA. 2 mg/m3 STEL.

Calcium hypochlorite: 1 mg/m3

RESPIRATORY PROTECTION:
Where the potential for exposure
to dust exists, use the appropriate regulatory compliant full facepiece air-purifying respirator with acid
gas cartridge and particulate prefilter. Carefully read and follow the respirator manufacturer's
instructions and information.
VENTILATION: Use local exhaust or general room/dilution ventilation sufficient to maintain
employee exposure below permissible exposure limits.
EYE AND FACE PROTECTION:

Splashproof goggles and faceshield.

PROTECTIVE GLOVES: Butyl rubber. Neoprene. Nitrile.
OTHER PROTECTIVE EQUIPMENT: Boots, aprons, or chemical suits should be used when
necessary to prevent skin contact.

9. PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point:
Vapor Density (Air=1):

Decomposes at approximately 338-356°F (170-180°C)
NA
Page 3 of 7

PPG:

0310D Pittclor® Dry Chlorinating Granules

Specific Gravity (Water=1):
pH:
FREEZING/MELTING POINT:
SOLUBILITY (wt.% in water):
Bulk Density (kg/M3):
VOLUME % VOLATILE:
VAPOR PRESSURE:
Evaporation Rate:
HEAT OF SOLUTION:
Physical State:
Odor:
COLOR:

03/09/2007

NA
Alkaline
NA
217 g/l @ 27°C
65-67 lbs./cu.ft.
NA
NA
NA
Slightly exothermic
Granules
slight chlorine
White

10. STABILITY AND REACTIVITY
Stability:

Unstable above 338°F (170°C).

HAZARDOUS POLYMERIZATION: Will not occur.
INCOMPATIBILITY (CONDITIONS/MATERIALS TO AVOID):
Contamination. Excessive heat above 338°F (170°C). Moisture. Acids. Reducing agents. Organics.
Combustible materials. Petroleum products. Paint products. Wood and paper.
HAZARDOUS THERMAL DECOMPOSITION/COMBUSTION PRODUCTS:
Acid or ammonia contamination will release toxic gases. Excessive heat will cause decomposition
resulting in the release of oxygen and chlorine gas.

11.
ACUTE INHALATION LC50:
toxicity.
ACUTE DERMAL LD50:
SKIN IRRITATION:
EYE IRRITATION:
ACUTE ORAL LD50:

TOXICOLOGICAL INFORMATION
No mortality at 3.5 mg/l (rat) (1 hour). Slight to very low
>1000 mg/kg. (rabbit) Slight to very low toxicity.
Corrosive.
Corrosive.
850 mg/kg. (rat) Moderate toxicity.

CARCINOGENICITY STATUS:
This product is NOT listed as a carcinogen or suspected
carcinogen by NTP, IARC, ACGIH, or OSHA.
MEDICAL CONDITIONS AGGRAVATED: None known.
EFFECTS OF OVEREXPOSURE:
ACUTE:
Inhalation: Inhalation of calcium hypochlorite dust and deposition of particles in the respiratory tract
can lead to irritation of the tissue and cause a variety of effects. These effects are dependent on
concentration and include: upper respiratory tract irritation, nasal congestion, coughing, sore throat,
laryngitis and shortness of breath. In operations where there are high concentrations of respirable
Page 4 of 7

PPG:

0310D Pittclor® Dry Chlorinating Granules

03/09/2007

particulates, pulmonary edema (fluid in the lung) may be produced. If not treated immediately,
pulmonary edema can be life threatening. Since this product is in granular or tablet form, particles of
respirable size are not generally encountered.
Eye/Skin: Calcium hypochlorite is corrosive to the eyes. Contact of calcium hypochlorite dust with
the eyes, even a minute amount for a short duration, can cause severe irritation and even blindness.
Contact with the skin may cause severe irritation, burns, or tissue destruction. In studies utilizing
rabbits, the skin irritation score was 8/8 and the eye irritation score was 98.5/110.
Ingestion: Calcium hypochlorite, if swallowed, causes severe burns to the digestive tract and can be
fatal.
CHRONIC:
Genotoxicity: Calcium hypochlorite produced positive responses in in-vitro assays using bacterial
systems (the Ames test) and chromosomal aberrations in Chinese hamster fibroblasts. In a whole
animal experiment (mouse micronucleus test), exposures ranging from 20 to 160 mg/kg produced no
compound related chromosomal abnormalities.
Carcinogenisis: Although no study has been conducted with calcium hypochlorite, the carcinogenic
potential of sodium hypochlorite was studied in F344 rats. After 104 weeks of drinking water
containing up to 2000 ppm sodium hypochlorite, there was no evidence that this chemical produced
any carcinogenic response. In addition, this exposure did not result in any adverse effects

12.

ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION:
0.088 mg/l (Bluegill) 96-hour LC50. Extreme toxicity.
ENVIRONMENTAL FATE:
No data at this time.

13.

DISPOSAL CONSIDERATIONS

DISPOSAL METHOD:
Spilled material that has been swept up and dissolved in water should be used immediately in the
normal application for which this product is being used. If this is not possible, dissolve material in
water and carefully neutralize dissolved material by adding hydrogen peroxide (one pint of 35%
hydrogen peroxide solution per pound of calcium hypochlorite to be neutralized) then dilute the
neutralized material with plenty of water and flush to sewer. Note: Only properly neutralized material
should be flushed to sewer. Unneutralized material can cause environmental damage to receiving
water or can interfere with treatment plant operation. Care must be taken when using or disposing of
chemical materials and/or their containers to prevent environmental contamination. It is your duty to
dispose of the chemical materials and/or their containers in accordance with the U.S. Clean Air Act,
the Clean Water Act, the Resource Conservation and Recovery Act, as well as any other relevant
Federal, State, or local laws/regulations regarding disposal.

14.
Proper Shipping Name:

TRANSPORT INFORMATION
Calcium Hypochlorite, Hydrated
Page 5 of 7

PPG:

0310D Pittclor® Dry Chlorinating Granules

03/09/2007

Hazard Class:
5.1 (Oxidizer)
UN Number:
UN2880
Packing Group:
II
10 lbs./4.5 kg. (calcium
USA-RQ, Hazardous Substance and Quantity:
hypochlorite)
Marine Pollutant:
None
Additional Information:
USA Shipments Only - Hazardous Substances are
regulated in the USA when shipped above their Reportable Quantity (RQ).

15.

REGULATORY INFORMATION

USA TSCA: All components of this product are listed on the TSCA Inventory.
EU EINECS: All components in this product are listed on EINECS.
CANADA DOMESTIC SUBSTANCES LIST (DSL): This product and/or all of its components are
listed on the Canadian DSL.
AUSTRALIA AICS: All components of this product are listed on AICS.
KOREA ECL: All components in this product are listed on the Korean Existing Chemicals Inventory
(KECI).
JAPAN MITI (ENCS):
All components in this product are listed on the
Japanese Existing and New Chemical Substances (ENCS) chemical inventory.
PHILIPPINES PICCS:
All of the components in this product are listed
on the Philippines Inventory of Chemicals and Chemical Substances (PICCS).
CHINA IECSC:
All components of this product are listed on the Inventory of Existing Chemical
Substances in China (IECSC) or otherwise exempt.
SARA TITLE III:
SARA (311, 312) Hazard Class:
Acute Health Hazard. Reactive Hazard. Fire Hazard.
SARA (313) Chemicals:
Not listed.
SARA Extremely Hazardous Substance:
Not listed.
CERCLA Hazardous Substance:
The following materials are listed as CERCLA Hazardous Substances in Table 302.4 of 40 CFR Part
302: Calcium Hypochlorite (7778-54-3) RQ = 10 lbs./4.54 kg.
CANADA REGULATIONS (WHMIS): Class C - Oxidizing material.
FIFRA:
This product is registered with EPA as a pesticide.

16.

OTHER INFORMATION

Other Information:
NSF Drinking Water Treatment Chemicals Listing - PPG calcium hypochlorite is certified for
maximum use at 15 mg/L under NSF/ANSI Standard 60.
The following has been revised since the last issue of this MSDS:
Page 6 of 7

PPG:

0310D Pittclor® Dry Chlorinating Granules

03/09/2007

Date. Edition. Section 1 has been updated. Section 8 has been updated. Section 12 has been
updated. Section 15 has been updated. Section 16 has been updated.
Previous revision date:
Previous edition number:

01/02/2004
010

NA = Not Available

Page 7 of 7

Material Safety Data Sheet
PO Box 24600
Houston, Tx 77229-4600
281-457-4888
888-647-7717
www.dxgroup.com

Provided by:
DPC Industries, Inc.
DX Distributors, Inc.
DPC Enterprises
DX Systems Company
DXI Industries, Inc.
DX Terminals

SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name

TRICHLOR TABLETS

Synonyms

1,3,5- TRIAZINE, TRICHLOR, CRYSTAL CARE TABLETS, HYDROTECH TABLETS

Chemical Name

TRICHLORISOCYANURIC ACID

Emergency phone:
Chemtrec:

281-457-4888
800-424-9300

Date of Issue:
Revised Date:

1/2/01
N/A

SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
COMPONENTS

PERCENT

TRICHLORISOCYANURIC ACID

99%

CAS NO.
87-90-1

SECTION 3 - HAZARDS IDENTIFICATION
Potential Health Effects
ACGIH - TLV:
Eye Contact

NOT ESTABLISHED.

Skin Contact

CAN CAUSE SKIN BURNS, IRRITATION AND POSSIBLE ALLERGIC REACTION.

Ingestion

CORROSIVE AND MAY CAUSE SEVERE AND PERMANENT DAMAGE TO MOUTH, THROAT AND
STOMACH.

Inhalation

CAUSES RESPIRATORY TRACT IRRITATION.

Carcinogenicity:

CAN CAUSE EYE BURNS AND PERMANENT TISSUE DAMAGE.

NTP NO

IARC NO
OSHA NO
SECTION 4 - FIRST AID PROCEDCURES

Eye Contact:

IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION.

Skin Contact:

IMMEDIATELY REMOVE CONTAMINATED CLOTHING OR SHOES, WIPE EXCESS FROM SKIN AND
FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. USE SOAP IF AVAILABLE OR
FOLLOW BY WASHING WITH SOAP AND WATER. DO NOT REUSE CLOTHING UNTIL THOROUGHLY
CLEANED. GET MEDICAL ATTENTION.

Inhalation:

REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS DIFFICULT. GIVE
ARTIFICIAL RESPIRATION IF NOT BREATHING. GET MEDICAL ATTENTION.

Ingestion:

DO NOT INDUCE VOMITING. RINSE MOUTH WITH WATER. IF CONSCIOUS, GIVE LARGE
QUANTITIES OF WATER OR MILK AND GET IMMEDIATE MEDICAL ATTENTION. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON!

SECTION 5 -FIRE FIGHTING MEASURES
Flash Point

NONFLAMMABLE.

Extinguishing Media

USE MEDIA APPROPRIATE FOR SURROUNDING AREA.

TRICHLOR TABLETS

Page 1 of 3

WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE
GEAR. STAY UPWIND AND KEEP OUT OF LOW AREAS.

Special Firefighting
Procedures/Precuations

SECTION 6 -ACCIDENTAL RELEASE MEASURES
For Spill:

SWEEP OR VACUUM MATERIAL AND PLACE IN CONTAINER FOR DISPOSAL. FLUSH REMAINING
MATERIAL WITH LARGE AMOUNTS OF WATER. PREVENT IT FROM ENTERING WATERWAYS OR SEWERS.

SECTION 7 - HANDLING AND STORAGE
Keep container tightly closed when not in use. Store in a cool, dry, well-ventilated area, away from heat and
incompatible materials. Protect containers from physical damage.
AVOID MOISTURE CONTAMINATION. KEEP OFF WET FLOORS.

SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
Respiratory Protection

USE A NIOSH/MSHA APPROVED RESPIRATOR FOLLOWING MANUFACTURER'S
RECOMMENDATIONS.

Ventilation

LOCAL AND MECHANICAL RECOMMENDED.

Protective Gloves

CHEMICAL IMPERVIOUS GLOVES.

Eye/Face Protection

CHEMICAL SAFETY GOGGLES AND/OR FULL-FACE SHIELD.

Other Protection

CHEMICAL RESISTANT CLOTHING SUCH AS COVERALLS/APRON, BOOTS, ETC.

Work Practices

USE GOOD PERSONAL HYGIENE PRACTICES. WASH HANDS BEFORE EATING, DRINKING,
SMOKING, OR USING TOILET FACILITIES. PROMPTLY REMOVE SOILED CLOTHING AND
WASH THOROUGHLY BEFORE REUSE. SHOWER AFTER WORK USING PLENTY OF SOAP
AND WATER.

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point (ºF):

Vapor Pressure (mmHg):

NOT APPLICABLE

Freezing Point (ºF): NOT APPLICABLE

Vapor Density (Air=1):

NOT APPLICABLE

Solubility (H2O):

SOLUBLE

Specific Gravity (H2O=1):

<1

pH

2.6

Evaporation Rate:

NOT DETERMINED

Appearance/Odor:

WHITE SOLID WITH CHLORINE-LIKE/BLEACH ODOR.

DECOMP AT 230

SECTION 10 - STABILITY AND REACTIVITY
Chemical Stability:

YES

Incompatible Materials

OXIDIZING AGENTS, REDUCING AGENTS, INORGANIC NITROGEN AND ORGANIC
MATERIALS.

Decomposition Products

MAY EVOLE CHLORINE CONTAINING GAS.

Hazardous Polymerization:

WILL NOT OCCUR.

TRICHLOR TABLETS

Page 2 of 3

SECTION 11 - TOXICITY INFORMATION
LD50 SKIN = 7600 mg/kg LD50 ORAL = 600 mg/kg

SECTION 12 - ECOLOGICAL INFORMATION
NO DATA AVAILABLE.

SECTION 13 - DISPOSAL CONSIDERATIONS
DISPOSE OF WASTE MATERIALS ACCORDING TO ALL FEDERAL, STATE AND LOCAL REGULATIONS.

SECTION 14 - TRANSPORT INFORMATION
USA DOT Shipping Name: TRICHLOROISOCYANURIC ACID, DRY
Hazard Class:

5.1

UN/NA Number:

UN2468

Packing Group:

II

Subsidiary Hazard
NO

Marine Pollutant:

SECTION 15 - REGULATORY INFORMATION
CERCLA RQ (lbs): NOT APPLICABLE
SARA Title III Section 312:
Acute

Chronic

Flammable

SARA Title III Section 313:

Sudden Release of Pressure

Reactive

No

SARA Extremely Hazardous Substance:

No

HMIS HAZARD RATING
Health:
0 - Least

Fire:

3

1 - Slight

Reactivity:

1

2 - Moderate

3 - High

2

4 - Extreme

SECTION 16 - OTHER INFORMATION
EPA Pesticide Registration Number:

NOT APPLICABLE

NSF Maximum Use Level for Potable Water (Standard 60):

NOT APPLICABLE

TSCA (Toxic Substance Control Act), 40 CFR 710:
Sources of the raw materials used in this mixture assure that all chemical ingredients present are in compliance
with Section 8(b) Chemical Substance Inventory, or are otherwise in compliance with TSCA.

DISCLAIMER
THE DATA PRESENTED IS TRUE AND CORRECT TO THE BEST OF OUR KNOWLEDGE AND BELIEF;
HOWEVER, NEITHER SELLER NOR PREPARER MAKES ANY WARRANTIES, EXPRESSED OR IMPLIED,
CONCERNING THE INFORMATION PRESENTED. THE USER IS CAUTIONED TO PERFOM HIS OWN HAZARD
EVALUATION AND TO RELY UPON HIS OWN DETERMINATIONS.

TRICHLOR TABLETS

Page 3 of 3

MATERIAL SAFETY DATA SHEET
Section 1 - Product Identification & Use
Product Name:
Bromine Tablets
WHMIS Classification: Class C: Oxidizing Material
TDG Classification:
Oxidizing solid, n.o.s. (bromo-chlorodimethylhydantoin) Class 5.1, UN 1479,
Packing Group II
Supplier:
Advance Chemicals Ltd.
2023 Kingsway Ave
Port Coquitlam, BC V3C 1S9
phone (604)945-9666
fax (604)945-9617
Emergency phone:
CANUTEC 24 hrs (613) 996-6666
Section 2 - Hazardous Ingredients
Hazardous Components
%(w/w) C.A.S. No. LD50 & LC50
1-bromo-3-chloro-5, 5-dimethylhydantoin
92.5
126-06-7
no data found
Section 3 - Physical Data
Physical state: solid
Boiling point: N/A
Specific Gravity: N/A
Freezing point:120-148°C%
Volatile(By volume): <0.5
Solubility in water: 0.54g/100g @ 25°C
Vapour pressure: N/A
Evaporation rate: no data found
Odour & Appearance: Pungent, off-white tablets.
Section 4 - Fire or Explosion Hazard
Flammability:
The product is considered to be flammable.
Contamination with organic chemicals, acids, or ammonia may
generate fumes leading to fire or explosion.
Flash Point: Decomposes at 165°C.
Extinguishing media: Use copious quantities of water.
Hazardous Combustion/Decomposition Products: Produces
noxious gases: Br2
Section 5 - Reactivity Data
Stability: Stable.
Incompatible substances: Strong acids and alkalis, high storage
temperatures, organic materials, ammonia bearing compounds,
strong reducing agents and moisture.
Polymerization: Will not occur.
Hazardous decomposition products: Thermal decomposition
releases unidentified noxious gases.
Section 6 - Toxicological Properties
Route of Entry: Skin, eye, ingestion and acute inhalation.
Inhalation: May cause damage to lungs (systemic absorption).
Severe to nose and throat.
Skin contact: Acute exposure may cause severe skin damage.
Eye contact: Acute exposure may cause severe eye damage.
Section 7 - Preventative Measures
Personal Protective Equipment: Avoid contact with skin and
eyes. Wear chemical protective gloves, goggles and face shield,
rubber apron and boots. Eye wash fountains and safety shower
facilities should be provided nearby for emergency use.
Respiratory protection: Use an NIOSH/MSHA approved air
purifying, dust, mist and particulate respirator.
Action to take for spills & leaks: Wear chemical protective
clothing, rubber gloves and suitable respiratory protection. Small
spills should be swept or vacuumed up and disposed of in
government approved waste containers. The spill area may then be
flushed with large quantities of water. Larger spills should be
contained by diking with sand, soil or other non-combustible
material, then transferred into approved waste containers for proper
disposal. Do not allow spilled, or waste product to flow into
waterways. Keep product out of sewers, storm drains, surface runoff water and soil. Restrict access to non-protected personnel.
Comply with all government regulations on spill reporting, and
handling and disposal of waste. Incinerate or dissolve in water and
neutralize halogen. Wet spills should be collected and neutralized.

Revision #: 03

Disposal methods: Dispose of contaminated product and materials
used in cleaning up spills or leaks in a manner approved for this
material. Consult appropriate federal, provincial and local regulatory
agencies to ascertain proper disposal procedures.
Note: Empty containers can have residues, gasses and mists, and
are subject to proper waste disposal as mentioned above.
Storage & Handling Precautions: Warning, harmful or fatal if
swallowed. Causes eye, skin and respiratory irritation. Avoid
contact with eyes and repeated contact with skin and clothing. Do
not ingest. Keep container tightly closed when not in use. Store
upright in a cool, dry, well-ventilated place away from incompatible
materials. Do not use pressure to empty container. Wash thoroughly
after handling. Use with adequate ventilation.
Repair and Maintenance Precautions: Do not cut, grind, weld or
drill in, on or near this container.
Section 8 - First Aid Measures
If inhaled: Remove victim to fresh air. Give artificial respiration if
not breathing. Get immediate emergency medical attention. Keep
patient warm and at rest. Give supplemental oxygen if victim is
having trouble breathing.
In case of eye contact: Immediately flush eyes with clean water for
at least twenty (20) minutes, lifting the upper and lower eyelids to
ensure complete flushing action of the eyeball. Get immediate
emergency medical attention. Do not transport victim until the
recommended flushing period has been completed, unless eye
flushing can be carried out during transport.
In case of skin contact: Wipe away excess material with a dry
cloth then immediately flush skin with plenty of clean running water
for at least twenty (20) minutes. Remove contaminated clothing and
shoes. If irritation persists, get emergency medical attention. Wash
and launder clothes before re-use.
In case of ingestion or swallowing: If victim is conscious, dilute
stomach contents by giving one or two glasses of water. DO NOT
INDUCE VOMITING. Never give anything by mouth to an unconscious
victim. GET IMMEDIATE EMERGENCY MEDICAL ATTENTION.
Section 9 - Preparation Information
Advance Chemicals Limited expressly disclaims all expressed or
implied warranties of merchantability and fitness for a particular
purpose with respect to the product provided. The information
contained herein is offered only as a guide to the handling of this
specific product, and has been prepared in good faith by technically
knowledgeable personnel. This M.S.D.S. is not intended to be allinclusive, and the manner and conditions of use may involve other
and additional considerations.
Revised:
5 July 2004; 27 October 2006; 15 December 2006

S:\MSDS\MSDS - Advance\Advance Updated MSDS\Bromine Tablets.DOC

Page 1 of 1

MATERIAL SAFETY DATA

SHEET

GLB Stabilizer

1. Product And Company Identification
Supplier
GLB
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Manufacturer
Advantis Technologies Inc.
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Telephone Number: (770)521-5999
FAX Number: (770)521-5959
Web Site: www.poolspacare.com

Telephone Number: (770) 521-5999
FAX Number: (770) 521-5959
Web Site: www.poolspacare.com

Supplier Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Manufacturer Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Issue Date: 04/18/2001
Product Name: GLB Stabilizer
CAS Number: Not Established
Chemical Family: Cyanurate
Chemical Formula: C3H3N3O3
MSDS Number: 57
Synonyms
CYA
2. Composition/Information On Ingredients
Ingredient
Name

CAS
Number

CYANURIC ACID

Percent Of
Total Weight

108-80-5

Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials
determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as
carcinogens are listed if they comprise 0.1% or more of the composition. Information on proprietary materials is
available in 29CFR 1910.1200(i)(1).
3. Hazards Identification
Primary Routes(s) Of Entry
Skin Contact
Eye Hazards
May cause eye irritation.
Skin Hazards
May cause skin irritation.
Ingestion Hazards
Harmful if swallowed.If ingested, get immediate medical attention
Inhalation Hazards
May cause respiratory tract irritation.
Signs And Symptoms
Low Toxicity irritating only as a dust

Page 1 of 4

MATERIAL SAFETY DATA

SHEET

GLB Stabilizer
3. Hazards Identification - Continued
Conditions Aggravated By Exposure
None Known
First Aid (Pictograms)

4. First Aid Measures
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes.
Consult Physician.
Skin
In case of contact, immediately flush skin with plenty of water for at least 15 minutes.
Ingestion
Call a physician or a poison control center immediately.
Inhalation
If inhaled, remove to fresh air.
Fire Fighting (Pictograms)

5. Fire Fighting Measures
Flash Point: N/A °F
Flammability Class: NOT FLAMMABLE
Extinguishing Media
Use the appropriate extinguishing media for the surrounding fire.
Fire Fighting Instructions
Firefighters should wear self-contained breathing apparatus and full protective gear.
6. Accidental Release Measures

Sweep up and remove immediately. Clean up on dry basis. Avoid release to the environment. Collect and dispose.
7. Handling And Storage
Handling And Storage Precautions
Keep out of reach of children. Do not store with acids. Keep containers tightly closed. Store material in a cool and
dry place. Away from food.
Handling Precautions
Avoid unnecessary contact with eyes skin and clothing.
Storage Precautions
Store in a cool dry place. Keep away from food
Work/Hygienic Practices
Use safe chemical handling procedures suitable for the hazards presended by this material.

Page 2 of 4

MATERIAL SAFETY DATA

SHEET

GLB Stabilizer
Protective Clothing (Pictograms)

8. Exposure Controls/Personal Protection
Engineering Controls
Local exhaust acceptable. Special exhaust not required unless dust accumulation is a problem.
Eye/Face Protection
Safety glasses with side shields or goggles recommended.
Skin Protection
Chemical-resistant gloves.
Respiratory Protection
None normally required. If dust accumulation is a problem a dust mask is suggested.
Full Cover clothing should be worn
9. Physical And Chemical Properties
Appearance
White to gray Crystalline powder
Odor
None
Chemical Type: Mixture
Physical State: Solid
Melting Point: DECOMPOSES °F
Boiling Point: DECOMPOSES @ 70C °C
Specific Gravity: 0.83-0.93
Percent Volitales: NOT APPLICABLE
Percent VOCs: NOT APPLICABLE
Vapor Pressure: NIL
Vapor Density: NOT VOLATILE
Solubility: 1% AT 25C IN WATER
Viscosity: NOT APPLICABLE
Evaporation Rate: NOT APPLICABLE
10. Stability And Reactivity
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatible Materials
NONE
Hazardous Decomposition Products
Oxides of Nitrogen and Carbon anc Cyanuric Acid
11. Toxicological Information
Acute Oral Effects
LD50 mg/kg Rat >5g/kg

Page 3 of 4

MATERIAL SAFETY DATA

SHEET

GLB Stabilizer
12. Ecological Information
No Data Available...
13. Disposal Considerations

Dispose in accordance with applicable federal, state and local government regulations.
14. Transport Information
Proper Shipping Name
NOT REGULATED
Hazard Class
NOT REGULATED
DOT Identification Number
NONE
DOT Shipping Label
NOT ASSIGNED
15. Regulatory Information
No Data Available...
NFPA

HMIS

0
1

0

HEALTH

1

FLAMMABILITY

0

REACTIVITY

0

PERSONAL PROTECTION

E

16. Other Information
Revision/Preparer Information
MSDS Preparer: JHW3
This MSDS Superceeds A Previous MSDS Dated: 07/26/2000
Disclaimer
Although reasonable care has been taken in the preparation of this document, we extend no warranties
and make no representations as to the accuracy or completeness of the information contained therein,
and assume no responsibility regarding the suitablility of this information for the user's intended
purposes or for the consequences of its use. Each individual should make a determination as to the
suitability of the information for their particular purposes(s).
GLB
Printed Using MSDS Generator™ 2000

Page 4 of 4

MATERIAL SAFETY DATA

SHEET

GLB Alkalinity Up

1. Product And Company Identification
Supplier
GLB
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Manufacturer
Advantis Technologies Inc.
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Telephone Number: (770)521-5999
FAX Number: (770)521-5959
Web Site: www.poolspacare.com

Telephone Number: (770) 521-5999
FAX Number: (770) 521-5959
Web Site: www.poolspacare.com

Supplier Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Manufacturer Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Issue Date: 01/19/05
Product Name: GLB Alkalinity Up
CAS Number: Not Established
Chemical Family: Alkali Salt
Chemical Formula: NaHCO3
MSDS Number: 48
2. Composition/Information On Ingredients
Ingredient
Name

CAS
Number

SODIUM BICARBONATE

Percent Of
Total Weight

144-55-8

Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials
determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as
carcinogens are listed if they comprise 0.1% of more of the composition. Information on proprietary materials is available
in 29CFR 1910.1200(i)(1).
3. Hazards Identification
Primary Routes(s) Of Entry
Skin Contact
Eye Hazards
Causes eye irritation.
Skin Hazards
Causes skin irritation.
Ingestion Hazards
Harmful if swallowed. If ingested, get immediate medical attention
Inhalation Hazards
May cause respiratory tract irritation.
Signs And Symptoms
none known

Page 1 of 5

MATERIAL SAFETY DATA

SHEET

GLB Alkalinity Up
First Aid (Pictograms)

4. First Aid Measures
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes.
Consult Physician.
Skin
Wash the affected area under tepid running water using a mild soap.
Ingestion
INDUCE VOMITING. Drink large amounts of water. Contact a physician or poison control.
Inhalation
If inhaled, remove to fresh air.
Fire Fighting (Pictograms)

5. Fire Fighting Measures
Flash Point: N/A °F
Flammability Class: NOT FLAMMABLE
Extinguishing Media
Use the appropriate extinguishing media for the surrounding fire.
Fire Fighting Instructions
Firefighters should wear self-contained breathing apparatus and full protective gear.
This material is used as a dry powder extinguishing agent for all classes of fires
6. Accidental Release Measures

Sweep up and remove immediately. Collect and dispose.
7. Handling And Storage
Handling And Storage Precautions
Keep out of reach of children. Do not store with acids. Keep containers tightly closed. Store material in a cool and
dry place.
Handling Precautions
Avoid contact with eyes.
Storage Precautions
Keep away from acids. Store in a cool dry place.
Work/Hygienic Practices
Use safe chemical handling procedures suitable for the hazards presended by this material.

Page 2 of 5

MATERIAL SAFETY DATA

SHEET

GLB Alkalinity Up
Protective Clothing (Pictograms)

8. Exposure Controls/Personal Protection
Engineering Controls
Use with adequate general and local exhaust ventilation.
Eye/Face Protection
Safety glasses with side shields or goggles recommended.
Skin Protection
Chemical-resistant gloves.
Respiratory Protection
None normally required. If dust accumulation is a problem a dust mask is suggested.
9. Physical And Chemical Properties
Appearance
White Granules
Odor
None
Chemical Type: Mixture
Physical State: Solid
Melting Point: DECOMPOSES °F
Boiling Point: DECOMPOSES °F
Percent Volitales: NOT APPLICABLE
Percent VOCs: NOT APPLICABLE
Vapor Pressure: NOT APPLICABLE
Vapor Density: NOT APPLICABLE
pH Factor: 8.5 At a Concentration Of 1% SOLUTION IN WATER
Solubility: 9.6G/100ML AT 20C IN WATER
Viscosity: NOT APPLICABLE
Evaporation Rate: NOT APPLICABLE
10. Stability And Reactivity
Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid (Stability)
High Humidity Causes Caking
Incompatible Materials
All Acids
Hazardous Decomposition Products
CO2
11. Toxicological Information
Acute Oral Effects
LD50 mg/kg Rat >4.22g/kg MAY CAUSE IRRITATION OF EYES AND RESPIATORY PASSAGES.
INGESTATION MAY CAUSE GASTROINTESTINAL IRRITATION

Page 3 of 5

MATERIAL SAFETY DATA

SHEET

GLB Alkalinity Up
12. Ecological Information
No Data Available...
13. Disposal Considerations

Dispose in accordance with applicable federal, state and local government regulations.
14. Transport Information
Proper Shipping Name
NOT REGULATED
Hazard Class
NOT REGULATED
Secondary Hazard Class
NOT REGULATED
DOT Identification Number
NONE
DOT Shipping Label
NOT ASSIGNED
Freight Class
NOT REGULATED
Packaging Requirements
NOT REGULATED
15. Regulatory Information
State Regulations
Sodium Bicarbonate is considered a hazardous waste in California
Canadian Regulatory Information
Class D, Div 2b - Poisonous or Infectious Material: other toxic effects
NFPA

HMIS

0
0

0

HEALTH

0

FLAMMABILITY

0

REACTIVITY

0

PERSONAL PROTECTION

E

16. Other Information
Revision/Preparer Information
MSDS Preparer: JHW3
This MSDS Superceeds A Previous MSDS Dated: 07/26/2000
Disclaimer
Although reasonable care has been taken in the preparation of this document, we extend no warranties
and make no representations as to the accuracy or completeness of the information contained therein,
and assume no responsibility regarding the suitablility of this information for the user's intended
purposes or for the consequences of its use. Each individual should make a determination as to the
suitability of the information for their particular purposes(s).

Page 4 of 5

MATERIAL SAFETY DATA
GLB Alkalinity Up
Disclaimer - Continued
GLB
Printed Using MSDS Generator™ 2000

Page 5 of 5

SHEET

MATERIAL SAFETY DATA

SHEET

GLB Clear Blue

1. Product And Company Identification
Supplier
GLB
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Manufacturer
Advantis Technologies, Inc.
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Telephone Number: (770)521-5999
FAX Number: (770)521-5959
Web Site: www.poolspacare.com

Telephone Number: (770) 521-5999
FAX Number: (770) 521-5959
Web Site: www.poolspacare.com

Supplier Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Manufacturer Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Issue Date: 02/08/2006
Product Name: GLB Clear Blue
Chemical Name: Catonic Polyamide in water
CAS Number: Not Established
Chemical Formula: Proprietery
MSDS Number: 36
2. Composition/Information On Ingredients
Ingredient
Name

CAS
Number

Polydimethyldiallyammonium
Chloride

Percent Of
Total Weight

26062-79-3

Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials
determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as
carcinogens are listed if they comprise 0.1% or more of the composition. Information on proprietary materials is available in
29CFR 1910.1200(i)(1).
3. Hazards Identification
Primary Routes(s) Of Entry
Skin Contact
Eye Hazards
May cause eye irritation.
Skin Hazards
May cause skin irritation. Non-sensitizer for skin.
Ingestion Hazards
Harmful if swallowed.
Inhalation Hazards
Slightly hazardous in case of inhalation.
Signs And Symptoms
Irritant to eyes and skin
4. First Aid Measures
No Data Available...

Page 1 of 4

MATERIAL SAFETY DATA

SHEET

GLB Clear Blue
4. First Aid Measures - Continued
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes.
Skin
Remove contaminated clothing and shoes.Rinse the affected area with tepid water for at least 15 minutes.
Ingestion
DO NOT INDUCE VOMITING. Drink large amounts of water or milk. Contact a physician or poison control. In cases
where individual is semi-comatose, comatose, or convulsing, DO NOT GIVE FLUIDS BY MOUTH.
Inhalation
If inhaled, remove to fresh air.
Fire Fighting (Pictograms)

5. Fire Fighting Measures
Flash Point: >100 °C
Flash Point Method: Closed Cup
Flammability Class: NOT FLAMMABLE
Fire And Explosion Hazards
In a fire situation, may liberate oxides of nitrogen or carbon, and hydrogen chloride.
Extinguishing Media
Use the appropriate extinguishing media for the surrounding fire.
Fire Fighting Instructions
CAUTION Surfaces wet with this product are slippery. Keep containers cool by spraying with water if exposed to
fire.
6. Accidental Release Measures
Clean up spill immediately. Contain and/or absorb spill with inert material (e.g. sand, vermiculite). Flush spill area with
water. Use appropriate containers to avoid environmental contamination.
CAUTION Surfaces wet with this product are slippery.
7. Handling And Storage
Handling And Storage Precautions
Keep out of reach of children. Store material in a cool and dry place. Wash thoroughly after handling.
Storage Precautions
Avoid contact with skin and clothing.
Work/Hygienic Practices
Wash thoroughly with soap and water after handling.

Page 2 of 4

MATERIAL SAFETY DATA

SHEET

GLB Clear Blue
7. Handling And Storage - Continued
Protective Clothing (Pictograms)

8. Exposure Controls/Personal Protection
Engineering Controls
Local exhaust acceptable. Special exhaust not required.
Eye/Face Protection
Safety glasses with side shields or goggles recommended.
Skin Protection
Chemical-resistant gloves.
Respiratory Protection
None normally required.
9. Physical And Chemical Properties
Appearance
Clear Blue
Odor
Mild amine
Chemical Type: Mixture
Physical State: Liquid
Melting Point: NOT APPLICABLE °F
Boiling Point: 212 °F
Specific Gravity: 1.0-1.1
Molecular Weight: Proprietary
Percent Volitales: NEGLIGIBLE
Packing Density: NOT DETERMINED
Vapor Pressure: NOT DETERMINED
Vapor Density: NOT DETERMINED
pH Factor: 2-3
Solubility: Soluble in Water
Viscosity: NOT DETERMINED
Evaporation Rate: <1
10. Stability And Reactivity
Sta bility: Stable
Hazardous Polymerization: will not occur
Conditions To Avoid (Stability)
Strong Oxidizers
Incompatible Materials
Avoid contact with strong oxidizers
Hazardous Decomposition Products
When heated toxic fumes such as Oxides of Carbon, Nitrogen and Hydrogen chloride may be present

Page 3 of 4

MATERIAL SAFETY DATA

SHEET

GLB Clear Blue
11. Toxicological Information
No Data Available...
12. Ecological Information
No Data Available...
13. Disposal Considerations
Refer to applicable federal, state, and local regulations prior to disposition of container and residual contents.
14. Transport Information
Proper Shipping Name
NOT REGULATED
Hazard Class
NONE ASSIGNED
DOT Identification Number
NONE
15. Regulatory Information
No Data Available...
NFPA

HMIS

0
1

0

HEALTH

1

FLAMMABILITY

0

REACTIVITY

0

PERSONAL

B

PROTECTION

16. Other Information
Revision/Preparer Information
MSDS Preparer: JHW
This MSDS Superceeds A Previous MSDS Dated: 07/24/2000
Disclaimer
Although reasonable care has been taken in the preparation of this document, we extend no warranties
and make no representations as to the accuracy or completeness of the information contained therein,
and assume no responsibility regarding the suitablility of this information for the user's intended purposes
or for the consequences of its use. Each individual should make a determination as to the suitability of
the information for their particular purposes(s).
GLB
Printed Using MSDS Generator™ 2000

Page 4 of 4

MATERIAL SAFETY DATA

SHEET
Page 1 of 5

GLB Filter Cleanse

1. Product And Company Identification
Supplier
GLB
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Manufacturer
Advantis Technologies, Inc.
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Telephone Number: (770)521-5999
FAX Number: (770)521-5959
Web Site: www.poolspacare.com

Telephone Number: (770) 521-5999
FAX Number: (770) 521-5959
Web Site: www.poolspacare.com

Supplier Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Manufacturer Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Issue Date: 05/05/2004
Product Name: GLB Filter Cleanse
Chemical Name: Acid surfactant cleaner
Chemical Family: Acid
Chemical Formula: Proprietary Mixture
MSDS Number: 116
2. Composition/Information On Ingredients
Ingredient
Name

CAS
Number

CITRICACID

Percent Of
Total Weight

77-92-9

SODIUMBISULFATE

7681-38-1

Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials
determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as
carcinogens are listed if they comprise 0.1% or more of the composition. Information on proprietary materials is available in
29CFR 1910.1200(i)(1).
EMERGENCY OVERVIEW
Corrosive to eyes skin and respiatory tract.
Hazards Identification (Pictograms)

3. Hazards Identification
Primary Routes(s) Of Entry
Skin Contact
Eye Hazards
Causes eye damage.
Skin Hazards
May cause skin irritation.
Ingestion Hazards
Harmful if swallowed.

MATERIAL SAFETY DATA

SHEET

Page 2 of 5

GLB Filter Cleanse
3. Hazards Identification - Continued
Inhalation Hazards
Causes respiratory tract irritation.
Signs And Symptoms
Irritation of Eyes, Skin and Respiratory Passages
First Aid (Pictograms)

4. First Aid Measures
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Call a
physician or a poison control center immediately.
Skin
In case of contact, immediately flush skin with soap and plenty of water. Remove contaminated clothing and shoes.
Ingestion
DO NOT INDUCE VOMITING. Call a physician or a poison control center immediately. If victim is fully conscious,
give one or two cups of water or milk to drink.
Inhalation
If breathing is difficult, give oxygen. If inhaled, remove to fresh air.
Fire Fighting (Pictograms)

5. Fire Fighting Measures
Flash Point: N/A °F
Fire And Explosion Hazards
At temperatures in excess of 570 F, hazardous fumes of sulfur dioxide and sulfur trioxide are evolved. Use forced
draft ventilation or gas mask.
Extinguishing Media
Use the appropriate extinguishing media for the surrounding fire.
Fire Fighting Instructions
Firefighters should wear self-contained breathing apparatus and full protective gear. Water can be used to cool and
protect exposed material.
6. Accidental Release Measures
Clean up spill immediately. Neutralize spill area with soda ash or lime. Flush spill area with water. Use appropriate
containers to avoid environmental contamination.

MATERIAL SAFETY DATA

SHEET

GLB Filter Cleanse
Handling & Storage (Pictograms)

7. Handling And Storage
Handling And Storage Precautions
Keep out of reach of children. Store material in a cool and dry place. Keep containers tightly closed.
Handling Precautions
Use only with adequate personal protection.
Storage Precautions
Store in a cool dry place.
Work/Hygienic Practices
Use safe chemical handling procedures suitable for the hazards presended by this material.
Avoid contact with eyes. Solutions of this material are acidic and strongly irritating. Will attack most metals.
Protective Clothing (Pictograms)

8. Exposure Controls/Personal Protection
Engineering Controls
Local exhaust acceptable. Special exhaust not required
Eye/Face Protection
Safety glasses with side shields or goggles recommended.
Skin Protection
Chemical-resistant gloves.
Respiratory Protection
None normally required.
9. Physical And Chemical Properties
Appearance
Purple to Red Granular
Odor
Slightly Acidic
Chemical Type: Mixture
Physical State: Solid
Melting Point: n/a °F
Boiling Point: 220 °F
Specific Gravity: 1.30
Molecular Weight: NOT DETERMINED
Percent Volitales: NOT DETERMINED
Vapor Pressure: NOT DETERMINED
pH Factor: <1 At a Concentration Of 1% solution in water
Solubility: <30%

Page 3 of 5

MATERIAL SAFETY DATA

SHEET

Page 4 of 5

GLB Filter Cleanse
10. Stability And Reactivity
Sta bility: Stable
Hazardous Polymerization: Will not occur.
Incompatible Materials
Oxidizers, Cyanides, Sulfides, Strong Alkaline or caustic material.
Hazardous Decomposition Products
At Temperatures in excess of 570F Hazardous fumes of Sulfur Dioxide and Sulfer Trioxide are evolved.
11. Toxicological Information
No Data Available...
12. Ecological Information
No Data Available...
13. Disposal Considerations
Dispose in accordance with applicable federal, state and local government regulations.
14. Transport Information
Proper Shipping Name
NOT REGULATED
Hazard Class
NOT REGULATED
DOT Identification Number
NONE
15. Regulatory Information
Ingredient(s) - State Regulations
SODIUM BISULFATE
New Jersey - Workplace Hazard
New Jersey - Special Hazard
New York City - Hazardous Substance
NFPA

HMIS

0
1

1

HEALTH

1

FLAMMABILITY

0

REACTIVITY

1

PERSONAL

F

PROTECTION

16. Other Information
Revision/Preparer Information
MSDS Preparer: JHW
This MSDS Superceeds A Previous MSDS Dated: 11/03/2000
Disclaimer
Although reasonable care has been taken in the preparation of this document, we extend no warranties
and make no representations as to the accuracy or completeness of the information contained therein,
and assume no responsibility regarding the suitablility of this information for the user's intended purposes
or for the consequences of its use. Each individual should make a determination as to the suitability of
the information for their particular purposes(s).

MATERIAL SAFETY DATA

SHEET

GLB Filter Cleanse
Disclaimer - Continued
GLB
Printed Using MSDS Generator™ 2000

Page 5 of 5

Product #SASH, SAL*

Page 1 of 7

MATERIAL SAFETY DATA SHEET

Sodium Carbonate
Section 01 - Chemical And Product And Company Information
Product Identifier ……………………... Sodium Carbonate (Soda Ash)
Product Use …………………………..... Glass manufacture, detergent manufacture, sodium chemical
manufacture, carbonate chemicals manufacture, pulp and paper, brine
treatment,water hardness removal, pH adjustment in water or waste
water, flue gas desulfurization, coal treatment, ion exchange resin
regeneration
Supplier Name……………………….…. ClearTech Industries Inc.
2302 Hanselman Avenue
Saskatoon, SK. Canada
S7L 5Z3
Prepared By................……………..….. ClearTech Industries Inc. Technical Department
Phone: (306)664-2522
Preparation Date.........…………….…... December 21, 2007
24-Hour Emergency Phone…………... 306-664-2522

Section 02 - Composition / Information on Ingredients
Hazardous Ingredients....………….... Sodium Carbonate

99.8%

CAS Number...................…….…….....Sodium Carbonate

497-19-8

Synonym (s)...................……………...Disodium carbonate, calcined soda, soda ash, lite soda ash, dense soda
ash, carbonic acid, disodium salt, sodium carbonate anhydrous

Product #SASH, SAL*

Page 2 of 7

Section 03 - Hazard Identification
Inhalation...................………….….... May cause upper respiratory tract irritation.
Skin Contact / Absorption…….…... May cause redness, swelling from prolonged contact, especially in hot
weather.
Eye Contact................………….….... Causes irritation, may burn eyes.
Ingestion.....................………………. Low acute oral toxicity. May cause nausea, vomiting, diarrhea, irritation,
and stomach ache.
Exposure Limits……………………... Treat as a nuisance particulate: TWA(OSHA)= 5mg/m3; TWA(Ontario
Ministry of Labour)= 10mg/m3

Section 04 - First Aid Measures
Inhalation....................……………….. Remove victim to fresh air. Give artificial respiration only if breathing has
stopped. If breathing is difficult, give oxygen. Seek immediate medical
attention.
Skin Contact / Absorption………….. Remove contaminated clothing. Wash affected area with soap and water.
Seek medical attention if irritation occurs or persists.
Eye Contact..................…………….... Flush immediately with water for at least 20 minutes. Forcibly hold eyelids
apart to ensure complete irrigation of eye tissue. Seek immediate medical
attention
Ingestion......................………………. Do not induce vomiting. If vomiting occurs, lean victim forward to prevent
breathing in vomitus. Give large amounts of water. Do not give anything
by mouth to an unconscious or convulsing person. Seek immediate
medical attention.
Additional Information.....…………... While internal toxicity is low, irritant effects of high concentrations may
produce corneal opacities, and vesicular skin reactions in humans with
abraded skin only. Treatment is symptomatic and supportive.

Section 05 - Fire Fighting
Conditions of Flammability……….... Non flammable
Means of Extinction........…………..... Product does not burn. Use appropriate extinguishing media for material
that is supplying the fuel to the fire.
Flash Point....………………………….. Not applicable

Product #SASH, SAL*

Page 3 of 7

Auto-ignition Temperature…………. Not applicable
Upper Flammable Limit …………….. Not applicable
Lower Flammable Limit...……….…... Not applicable
Hazardous Combustible Products... Heating sodium carbonate liberates CO2 and fumes of sodium oxide.
Special Fire Fighting Procedures..... Wear NIOSH-approved self-contained breathing apparatus and protective
clothing.
Explosion Hazards………………….... Not applicable

Section 06 - Accidental Release Measures
Leak / Spill................….……………... Wear appropriate personal protective equipment. Ventilate area. Stop or
reduce leak if safe to do so. Prevent material from entering sewers.
Deactivating Materials...……….…... Use an acid to neutralize after the soda ash has been made into a
solution.

Section 07 - Handling and Storage
Handling Procedures.......…………... Use proper equipment for lifting and transporting all containers. Use
sensible industrial hygiene and housekeeping practices. Wash thoroughly
after handling. Avoid all situations that could lead to harmful exposure.
Storage Requirements......……...….. Product is hygroscopic and tends to cake on storage. Store in a cool, dry,
well ventilated place. Keep container tightly closed, and away from acids.

Section 08 - Personal Protection and Exposure Controls
Protective Equipment
Eyes.………………………….………... Chemical goggles, full-face shield, or a full-face respirator is to be worn at
all times when product is handled. Contact lenses should not be worn;
they may contribute to severe eye injury.
Respiratory………………………….... Respiratory protection is not normally required. If use creates dust
formations, then a NIOSH approved respirator with a dust cartridge is
recommended.

Product #SASH, SAL*

Page 4 of 7

Gloves………………………………..... Impervious gloves of chemically resistant material (rubber or PVC) should
be worn at all times. Wash contaminated clothing and dry thoroughly
before reuse.
Clothing………………………..…….... Body suits, aprons, and/or coveralls of chemical resistant material should
be worn at all times. Wash contaminated clothing and dry thoroughly
before reuse.
Footwear……………………………..... No special footwear is required other than what is mandated at place of
work.

Engineering Controls
Ventilation Requirements………...... Mechanical ventilation (dilution or local exhaust), process or personnel
enclosure and control of process conditions should be provided. Supply
sufficient replacement air to make up for air removed by exhaust systems.
Other………………………………….... Emergency shower and eyewash should be in close proximity.

Section 09 - Physical and Chemical Properties
Physical State.......……....………….... Solid
Odor and Appearance…..…………... White granular solid, no odour
Odor Threshold....……………............ Not applicable
Specific Gravity (Water=1)………….. ~2.53 @ 20oC
Vapor Pressure (mm Hg, 20C)….….. Not applicable
Vapor Density (Air=1)..…………….... Not applicable
Evaporation Rate........……..…….….. Not applicable
Boiling Point...............………….…..... Not available
Freeze/Melting Point....…………….... 851oC
pH............................……………….….. 11.3 (1% solution)
Water/Oil Distribution Coefficient.... Not available
Bulk Density..............…………….…... 0.70-1.12g/cm3
% Volatiles by Volume………..……... Not applicable

Product #SASH, SAL*

Page 5 of 7

Solubility in Water...………………..... 33.2%(w/w)
Molecular Formula......………….….... Na2CO3
Molecular Weight........……………..... 105.99

Section 10 - Stability and Reactivity
Stability.................…………....……………. Stable under normal conditions. Avoid conditions of extreme heat
(i.e.:temperatures greater than 400oC). Heating liberates fumes of
sodium oxide.
Incompatibility..............…………..……….. Aluminium, fluorine, humid air, moisture, acids, sulfuric acid,
magnesium, phosphorus pentaoxide, molten lithium.
Hazardous Products of Decomposition.. Carbon dioxide and heat form from reaction with acids.
Polymerization...........…………….…….…. Will not occur

Section 11 - Toxicological Information
Irritancy.................……..………….…. Mild irritant. Skin and eye irritant.
Sensitization........…….......………….. Non-sensitizing (humans, 0.25% Sodium carbonate)
Chronic/Acute Effects……...……….. May cause severe irritation of the eyes, including corneal opacities. Dusts
and mists may be irritating to the skin, mucous membranes and upper
respiratory tract. No significant acute toxicological effects expected.
Synergistic Materials...……....……... Not available
Animal Toxicity Data......…..………... LD50(Rat, Oral)= 4090mg/kg
LC50(Rat, Inhalation, 2hr)= 2.3mg/L
Carcinogenicity......……......……….... Not considered to be carcinogenic by IARC, NTP, ACGIH, and OSHA
Reproductive Toxicity..…...………... Not available
Teratogenicity..........….....…………... Not available
Mutagenicity...........…….....…………. Not available

Product #SASH, SAL*

Page 6 of 7

Section 12 - Ecological Information
Fish Toxicity..................……………... TLm(48hr, Mosquito Fish)= 840mg/L
TLm(96hr, Mosquito Fish)= 1200mg/L
LC50(Daphina magna, 96hr)= 265-565mg/L
LC50(Bluegill sunfish, 96hr)= 300-320mg/L
Biodegradability.............……….….... Not applicable
Environmental Effects………………. Not available

Section 13 - Disposal Consideration
Waste Disposal...........…...…………...Dispose in accordance with all federal, provincial, and/or local regulations
including the Canadian Environmental Protection Act.

Section 14 - Transportation Information
TDG Classification
Class……………..………………..….... Not regulated
Group...............…………….......……... Not regulated
PIN Number.................……..……….... Not regulated
Other…………………………………..... Secure containers (full and/or empty) with suitable hold down devises
during shipment.

Section 15 - Regulatory Information
WHMIS Classification.......…………....D2, E
NOTE: THE PRODUCT LISTED ON THIS MSDS HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE
HAZARD CRITERIA OF THE CANADIAN CONTROLLED PRODUCTS REGULATIONS. THIS MSDS
CONTAINS ALL INFORMATION REQUIRED BY THOSE REGULATIONS.
NSF Certification................................Product is certified under ANSI/NSF Standard 60 for corrosion control,
scale control and pH adjustment at a maximum dosage of 150mg/L.

Section 16 - Other Information
Note: The responsibility to provide a safe workplace remains with the user. The user should consider the health
hazards and safety information contained herein as a guide and should take those precautions required in an
individual operation to instruct employees and develop work practice procedures for a safe work environment. The
information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions
of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages

Product #SASH, SAL*

Page 7 of 7

incurred by the use of this material. It is the responsibility of the user to comply with all applicable laws and
regulations.
Attention: Receiver of the chemical goods / MSDS coordinator
As part of our commitment to the Canadian Association of Chemical Distributors (CACD) Responsible
Distribution® initiative, ClearTech Industries Inc. and its associated companies require, as a condition of sale, that
you forward the attached Material Safety Data Sheet(s) to all affected employees, customers, and end-users.
ClearTech will send any available supplementary handling, health, and safety information to you at your request.
If you have any questions or concerns please call our customer service or technical service department.

ClearTech Industries Inc. - Locations
Corporate Head Office: 2302 Hanselman Avenue, Saskatoon, SK, S7L 5Z3
Phone: 306-664-2522
Fax: 306-665-6216
Location
Richmond, B.C.
Calgary, AB.
Edmonton, AB.
Saskatoon, SK.
Regina, SK.
Winnipeg, MB.
Mississauga, ON.

www.ClearTech.ca
Address
Postal Code
12431 Horseshoe Way
V7A 4X6
5516E - 40th St. S.E.
T2C 2A1
11750 - 180th Street
T5S 1N7
2302 Hanselman Avenue
S7L 5Z3
555 Henderson Drive
S42 5X2
340 Saulteaux Crescent
R3J 3T2
7480 Bath Road
L4T 1L2

Phone Number
604-272-4000
403-279-1096
780-452-6000
306-933-0177
306-721-7737
204-987-9777
905-612-0566

Fax Number
604-272-4596
403-236-0989
780-452-4600
306-933-3282
306-721-8611
204-987-9770
905-612-0575

24 Hour Emergency Number - All Locations - 306-664-2522

Material Safety Data Sheet
WHMIS (Pictograms)

WHMIS (Classification)

Personal Protective Equipment

Class D-1A: Material causing immediate and serious toxic effects
(VERY TOXIC).
Class E: Corrosive liquid.

Section 1. Product and Company Identification
Associated
Product’s Item
Code

WIP-12280
12-284EXP

Hydrochloric acid

CAS #

7647-01-0

Chemical Family

Inorganic acid.

July 08 2004
Validation Date 7/8/2004.

Chemical Formula

HCl (aq)

Print Date

Manufacturer

Recochem Inc.
850 Montee de Liesse
Montreal, Quebec
514-341-3550

In Case of Recochem Inc.
Emergency C o m m u n i c a t i o n s a n d R e g u l a t o r y
Affairs Department
(905) 791-1788

Material Uses

Consumer products: Cleaning solution.

Product Name /
Trade name

Muriatic Acid

Synonym

Muriatic Acid

July 08 2004
7/8/2004.

Section 2. Hazardous Ingredients
Name
Hydrochloric acid

CAS #

% by
Weight

7647-01-0

31-32%
/ 20º
Baume

Exposure Limits
Canadian Values (ACGIH)
U.S. Values (OSHA)
Muriatic
Acid

Not available.

Section 3. Hazard Identification
Emergency Overview

DANGER!
CAUSES SEVERE EYE AND SKIN BURNS. MAY BE FATAL IF SWALLOWED.
Do not get in eyes, on skin or on clothing. Do not ingest. Do not breathe vapor or mist. Keep container closed. Use
only with adequate ventilation. Wash thoroughly after handling.

Potential Acute Health
Effects

See Section #11: "Toxicological Information" for further human health effects.
Very dangerous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant), of inhalation.
Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory
tract.
Skin contact may produce burns.
Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or
shortness of breath.
Inflammation of the eye is characterized by redness, watering, and itching.
Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.

Note to Physician

Not available.

Continued on Next Page

July 08 2004
Validated on 7/8/2004.

Muriatic
Muriatic
Acid Acid

Page: 2/5

Section 4. First Aid Measures
Eye Contact

IMMEDIATELY flush eyes with running water for at least 15 minutes, keeping eyelids open. SEEK IMMEDIATE
MEDICAL ATTENTION.

Skin Contact

If the chemical got onto the clothed portion of the body, remove the contaminated clothes as quickly as possible.
Place the victim under a deluge shower. Gently and thoroughly wash the contaminated skin with running water and
non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Seek medical attention. Wash
contaminated clothing before reusing.

Inhalation

Allow the victim to rest in a well ventilated area. Seek medical attention.

Ingestion

DO NOT induce vomiting. Have conscious person drink several glasses of water or milk. Seek medical attention.

Section 5. Fire Fighting Measures
Products of Combustion

Not applicable.

Fire Fighting Media
and Instructions

Use DRY chemicals, CO2, water spray or foam.

Fire Hazards

Flammable hydrogen gas may be produced on prolonged contact with metals.

Explosion Hazards

Flammable hydrogen gas may be produced on prolonged contact with metals.

Section 6. Accidental Release Measures
Small Spill and Leak

Dilute with water and mop up, or absorb with an inert DRY material and place in an appropriate waste disposal
container. If necessary: Neutralize the residue with a dilute solution of sodium carbonate.

Large Spill and Leak

Corrosive liquid.
Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Place in appropriate
container and dispose of in accordance with regional regulations. Neutralize the residue with a dilute solution of
sodium carbonate.

Section 7. Handling and Storage
Handling

Not available.

Storage

See Section #10 for applicable incompatible materials.
May corrode metallic surfaces. Store in a polyethylene container. Keep away from incompatibles. Keep container
tighltly closed in a cool, well-ventilated place.

Section 8. Exposure Controls, Personal Protection
Engineering Controls

Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station
location.

Personal Protection
Eyes Face shield.
Body Synthetic apron.
Respiratory Wear appropriate respirator when ventilation is inadequate.
Hands Impervious gloves.

Continued on Next Page

July 08 2004
Validated on 7/8/2004.

Page: 3/5

Muriatic
Muriatic
Acid Acid

Section 9. Physical and Chemical Properties
Physical State and
Appearance

Liquid.

Odour

Irritant.

Molecular Weight

Not applicable.

Taste

Not available.

pH (1% Soln/Water)

1 [Acidic.]

Colour

Clear colorless to light yellow.

Boiling/Condensation
Point

>81°C (177.8°F)

Volatility

Not available.

Melting/Freezing Point

Not available.

Evaporation Not available.
Rate

Specific Gravity

1.16 (Water = 1)

Odour
Threshold

Not available.

Vapour Pressure

25 mm of Hg (@ 20°C)

Viscosity

Not available.

Vapour Density

Not available.

Solubility

Soluble in water, methanol.

VOC Content

Not available.

Other
Properties

Not available.

The Product is:

Non-flammable.

Auto-ignition
Temperature

Not applicable.

Flash Point

Not applicable.

Flammable Limits

Not applicable.

Fire Hazards in Presence Not applicable.
of Various Substances

Section 10. Stability and Reactivity
Stability

The product is stable.

Conditions of Instability

No additional remark.

Incompatibility with
Various Substances

Reactive with oxidizing agents, metals, alkalis.

Section 11. Toxicological Information
Routes of Entry

Skin contact. Eye contact. Inhalation. Ingestion.

Toxicity to Animals

Acute oral toxicity (LD50): 900 mg/kg [Rabbit.]. (Hydrochloric acid).

Acute Effects on Humans
Eyes Very hazardous in case of eye contact (irritant). Corrosive to eyes. Inflammation of the eye is characterized by
redness, watering, and itching.

Skin Very hazardous in case of skin contact (corrosive, irritant). Skin contact may produce burns. Severe over-exposure
can result in death. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.

Inhalation Very hazardous in case of inhalation. Inhalation of the spray mist may produce severe irritation of respiratory tract,
characterized by coughing, choking, or shortness of breath. Over-exposure by inhalation may cause respiratory
irritation. May be fatal if inhaled.

Continued on Next Page

July 08 2004
Validated on 7/8/2004.

Page: 4/5

Muriatic
Muriatic
Acid Acid

Ingestion May be fatal if swallowed. May cause burns to mouth, throat and stomach.
Chronic Effects on
Humans

CARCINOGENIC EFFECTS: Classified NONE.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.
Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated
or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial
infection. Repeated exposure to a highly toxic material may produce general deterioration of health by an
accumulation in one or many human organs.

Section 12. Ecological Information
Ecotoxicity

For accidential discharges into environment, see Section #6: "Accidential Release Measures" for suggested
instructions.
Not available.

Section 13. Disposal Considerations
Waste Information

Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14. Transport Information
Canada Transportation of Dangerous Goods (TDG) Information
Primary Class
Subsidiary Class (if
applicable)

Class 8: Corrosive material

Proper shipping name
Hazard Identification
Number
Packing Group

hydrochloric acid
1789

Special Provisions

In containers of 1 L (1Kg) capacity or less this product is
classified as a "Limited Quantities""Consumer Commodity" under
TDG regulations.

8

II

International Maritime Dangerous Goods (IMDG) Transportation Information
Primary Class
Subsidiary Class (if
applicable)

Class 8: Corrosive material

Proper shipping name
Hazard Identification
Number
Packing Group

Hydrochloric acid
1789

Marine Pollutant
Special Provisions

Not pollutant.

-

II

-

United States Department of Transportation (DOT) Information

Continued on Next Page

8

No placard (handling and hazard label) required.

July 08 2004
Validated on 7/8/2004.

Page: 5/5

Muriatic
Muriatic
Acid Acid

Primary Class

Class 8: Corrosive material

Subsidiary class (if
applicable)

-

Proper shipping name
Hazard Identification
Number
Packing Group

hydrochloric acid

Special Provisions

In containers of 1 L (1Kg) this product is qualified as a "consumer
commodity" ORM-D under DOT

International Air
Transport Association
(IATA)

For air shipment classification and associated regulations, please refer to the latest edition of
IATA Dangerous Goods Regulations.

CORROSIVE

8

1789
II

Section 15. Other Regulatory Information and Pictograms
WHMIS Classification
(Canada)
Canada Domestic
Substances List (DSL)
Status

Class D-1A: Material causing immediate and serious toxic effects
(VERY TOXIC).
Class E: Corrosive liquid.
This product and/ or all of its components are on the DSL.

HCS Classification
(U.S.A.)

Corrosive Material

U.S.A. Regulatory Lists

This product and/ or all of its components are on the TSCA inventory list.

Hazardous Material
Information System
(U.S.A.)

Health
Flammability
Reactivity
Personal Protection

3
0
2
D

National Fire
Protection
Association
(U.S.A.)

Flammability

Health

0
3 2

Reactivity

Specific Hazard

Section 16. Other Information
Validated and verified by Compliance and Technical Information Manager on 7/8/2004.
July 08 2004

Printed 7/8/2004.
July 08 2004

Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for
the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain
hazards are described herein, we cannot guarantee that these are the only hazards that exist.

MSDS are available at www.recochem.com

MATERIAL SAFETY DATA

SHEET
Page 1 of 5

GLB Stain Magnet

1. Product And Company Identification
Supplier
GLB
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Manufacturer
Advantis Technologies, Inc.
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Telephone Number: (770)521-5999
FAX Number: (770)521-5959
Web Site: www.poolspacare.com

Telephone Number: (770) 521-5999
FAX Number: (770) 521-5959
Web Site: www.poolspacare.com

Supplier Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Manufacturer Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Issue Date: 03/05/2004
Product Name: GLB Stain Magnet
Chemical Family: Formulated Stain Remover
Chemical Formula: Proprietary Mixture
MSDS Number: 32
2. Composition/Information On Ingredients
Ingredient
Name

CAS
Number

SODIUMERYTHROBATE

6381-77-7

SODIUMSULFITE

7757-83-7

Percent Of
Total Weight

Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials
determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as
carcinogens are listed if they comprise 0.1% or more of the composition. Information on proprietary materials is available in
29CFR 1910.1200(i)(1).
3. Hazards Identification
Primary Routes(s) Of Entry
Skin Contact
Eye Hazards
Causes eye irritation.
Skin Hazards
Causes skin irritation.
Ingestion Hazards
Harmful if swallowed. May cause colic and diarrhea, circulatory disturbances, CNS depression and Death. If
ingested, get immediate medical attention
Inhalation Hazards
May cause respiratory tract irritation. May cause Central Nervous System effects. May cause delayed lung injury.
Signs And Symptoms
Irritation of Eyes, Skin and Respiratory Passages

MATERIAL SAFETY DATA

SHEET

Page 2 of 5

GLB Stain Magnet
First Aid (Pictograms)

4. First Aid Measures
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Call a
physician or a poison control center immediately.
Skin
Wash the affected area under tepid running water using a mild soap. Get medical attention immediately if irritation
(redness, rash, blistering) develops and persists.
Ingestion
If swallowed, induce vomiting immediately. Call a physician or a poison control center immediately.
Inhalation
If inhaled, remove to fresh air.If breathing is difficult, give oxygen. Consult Physician

Fire Fighting (Pictograms)

5. Fire Fighting Measures
Flash Point: N/A °F
Flammability Class: NOT FLAMMABLE
Extinguishing Media
Use CO2 (Carbon Dioxide), dry chemical, or foam.
Fire Fighting Instructions
Firefighters should wear self-contained breathing apparatus and full protective gear. Water can be used to cool,
protect exposed material and knock down fumes.
6. Accidental Release Measures
Sweep up and remove immediately.Flood with water in accordance with applicable regulations.
Handling & Storage (Pictograms)

7. Handling And Storage
Handling And Storage Precautions
Keep out of reach of children.
Wear necessary protective equipment. If substantial dust in in the air take measures to remove sources of ignition
to prevent possible dust combustion or explosion. Promptly ventilate area. Keep containers tightly closed. Keep
away from Acids and Oxiders
Handling Precautions
Avoid creating dust. Avoid contact with eyes. Use NIOSH/MSHA approved mist respirator.

MATERIAL SAFETY DATA

SHEET

GLB Stain Magnet
7. Handling And Storage - Continued
Work/Hygienic Practices
Use safe chemical handling procedures suitable for the hazards presented by this material.

Protective Clothing (Pictograms)

8. Exposure Controls/Personal Protection
Engineering Controls
Use with adequate ventilation if dusty conditions prevail or sulfur dioxide gas is released.
Eye/Face Protection
Safety glasses with side shields or goggles recommended.
Skin Protection
Chemical-resistant gloves.
Respiratory Protection
Use NIOSH/MSHA approved dust and mist respirator
Ingredient(s) - Exposure Limits
SODIUM SULFITE
PEL
TLV
5ppm
2ppm
Full Work Clothing, including long sleeved shirt and trousers required.
9. Physical And Chemical Properties
Appearance
White Granules
Odor
None
Chemical Type: Mixture
Physical State: Solid
Melting Point: NOT DETERMINED °F
Specific Gravity: 1.2-2.7
Molecular Weight: NOT DETERMINED
Percent Volitales: NOT DETERMINED
Vapor Pressure: NOT APPLICABLE
Vapor Density: NOT APPLICABLE
pH Factor: 8-10 At a Concentration Of 1% SOLUTION IN WATER
Solubility: SOLUBLE IN WATER
Evaporation Rate: NOT APPLICABLE
10. Stability And Reactivity
Sta bility: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid (Stability)
High temperatures. Before melting may yield sulfur dioxide with a hazardous residue
Incompatible Materials
Avoid contact with strong acids and oxidizers

Page 3 of 5

MATERIAL SAFETY DATA

SHEET

Page 4 of 5

GLB Stain Magnet
10. Stability And Reactivity - Continued
Hazardous Decomposition Products
Sulfur dioxide gas and sodium sulfide residue
11. Toxicological Information
No Data Available...
12. Ecological Information
No Data Available...
13. Disposal Considerations
Dissolve in water, using caution as solution may increase in temperature. Neutralize with acid and flush to sewer if in
accordance with applicable federal, state and local government regulations. Good ventilation is required during
neutralization due to the release of SO2 gas. Oxidation to sodium sulfate solution may be required, as for example by
adding a slight excess hydrogen peroxide carefully and stirring. Neutralized waste may have to be disposed of by a
contractor.
14. Transport Information
Proper Shipping Name
NOT REGULATED
Hazard Class
NOT REGULATED
DOT Identification Number
NONE
15. Regulatory Information
Canadian Regulatory Information
Class D, Div 2b - Poisonous or Infectious Material: other toxic effects
Class C - Oxidizing Material
WHMIS - Canada (Pictograms)

NFPA

HMIS

0
1

0

HEALTH

2

FLAMMABILITY

0

REACTIVITY

0

PERSONAL

B

PROTECTION

16. Other Information
Revision/Preparer Information
MSDS Preparer: JHW3
This MSDS Superceeds A Previous MSDS Dated: 07/21/2000
Disclaimer
Although reasonable care has been taken in the preparation of this document, we extend no warranties
and make no representations as to the accuracy or completeness of the information contained therein,
and assume no responsibility regarding the suitablility of this information for the user's intended purposes

MATERIAL SAFETY DATA

SHEET

Page 5 of 5

GLB Stain Magnet
Disclaimer - Continued
or for the consequences of its use. Each individual should make a determination as to the suitability of
the information for their particular purposes(s).
GLB
Printed Using MSDS Generator™ 2000

MATERIAL SAFETY DATA

SHEET

GLB Natural Clear

1. Product And Company Identification
Supplier
GLB
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Manufacturer
Advantis Technologies, Inc.
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Telephone Number: (770)521-5999
FAX Number: (770)521-5959
Web Site: www.poolspacare.com

Telephone Number: (770) 521-5999
FAX Number: (770) 521-5959
Web Site: www.poolspacare.com

Supplier Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Manufacturer Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Issue Date: 04/16/2007
Product Name: GLB Natural Clear
Chemical Name: Enzymatic Cleaner
CAS Number: Not Established
Chemical Family: Enzyme
Chemical Formula: Proprietary
MSDS Number: 21
2. Composition/Information On Ingredients
Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials
determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as
carcinogens are listed if they comprise 0.1% or more of the composition. Information on proprietary materials is available in
29CFR 1910.1200(i)(1).
3. Hazards Identification
Primary Routes(s) Of Entry
Eye Contact, Skin Contact
Eye Hazards
May cause eye irritation.
Skin Hazards
May cause skin irritation.
Ingestion Hazards
If ingested, get immediate medical attention
Inhalation Hazards
None known
First Aid (Pictograms)

4. First Aid Measures
No Data Available...

Page 1 of 4

MATERIAL SAFETY DATA

SHEET

GLB Natural Clear
4. First Aid Measures - Continued
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes.
Skin
Remove contaminated clothing and shoes. Wash affected areas with soap and water.
Ingestion
DO NOT INDUCE VOMITING. Drink large amounts of water. Contact a physician or poison control.
Inhalation
No known hazard
Fire Fighting (Pictograms)

5. Fire Fighting Measures
Flash Point: n/a °F
Extinguishing Media
Use the appropriate extinguishing media for the surrounding fire.
Fire Fighting Instructions
Firefighters should wear self-contained breathing apparatus and full protective gear.
6. Accidental Release Measures
Clean up spill immediately. Contain and/or absorb spill with inert material (e.g. sand, vermiculite).
7. Handling And Storage
Handling And Storage Precautions
Keep out of reach of children. Store material in a cool and dry place.
Storage Precautions
Keep out of reach of children. Store in a cool dry place.
Work/Hygienic Practices
Use safe chemical handling procedures suitable for the hazards presented by this material.
Protective Clothing (Pictograms)

8. Exposure Controls/Personal Protection
Engineering Controls
Local exhaust acceptable. Special exhaust not required
Eye/Face Protection
Safety glasses with side shields or goggles.
Skin Protection
Chemical-resistant gloves.

Page 2 of 4

MATERIAL SAFETY DATA
GLB Natural Clear
8. Exposure Controls/Personal Protection - Continued
Respiratory Protection
None normally required.
9. Physical And Chemical Properties
Appearance
Clear yellow liquid
Odor
Floral
Chemical Type: Mixture
Physical State: Liquid
Melting Point: NOT DETERMINED °F
Boiling Point: 212 °F
Specific Gravity: 0.99-1.1
Percent Volitales: Nil
Packing Density: NOT DETERMINED
Vapor Pressure: NOT DETERMINED
Vapor Density: >AIR
pH Factor: 6-8
Solubility: SOLUBLE IN WATER
10. Stability And Reactivity
Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid (Stability)
None Known
Incompatible Materials
None known
11. Toxicological Information
No Data Available...
12. Ecological Information
No Data Available...
13. Disposal Considerations
Dispose in accordance with applicable federal, state and local government regulations.
14. Transport Information
Proper Shipping Name
NON REGULATED
Hazard Class
NON REGULATED
DOT Identification Number
NONE
DOT Shipping Label
NOT ASSIGNED

Page 3 of 4

SHEET

MATERIAL SAFETY DATA

SHEET

GLB Natural Clear
15. Regulatory Information
Canadian Regulatory Information
Class D, Div 2b - Poisonous or Infectious Material: other toxic effects
WHMIS - Canada (Pictograms)

NFPA

HMIS

0
1

0

HEALTH

1

FLAMMABILITY

0

REACTIVITY

0

PERSONAL

B

PROTECTION

16. Other Information
Revision/Preparer Information
MSDS Preparer: JHW
Disclaimer
Although reasonable care has been taken in the preparation of this document, we extend no warranties
and make no representations as to the accuracy or completeness of the information contained therein,
and assume no responsibility regarding the suitablility of this information for the user's intended purposes
or for the consequences of its use. Each individual should make a determination as to the suitability of
the information for their particular purposes(s).
GLB
Printed Using MSDS Generator™ 2000

Page 4 of 4

MATERIAL SAFETY DATA

SHEET
Page 1 of 4

Leisure Time Foam Down

1. Product And Company Identification
Supplier
Leisure Time
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Manufacturer
Advantis Technologies, Inc.
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Telephone Number: (770) 521-5999
FAX Number: (770) 521-5959
Web Site: www.poolspacare.com

Telephone Number: (770) 521-5999
FAX Number: (770) 521-5959
Web Site: www.poolspacare.com

Supplier Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Manufacturer Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Issue Date: 09/01/2004
Product Name: Leisure Time Foam Down
Chemical Family: Silicone Emulsion
Chemical Formula: Proprietary
MSDS Number: 25
2. Composition/Information On Ingredients
Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials
determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as
carcinogens are listed if they comprise 0.1% or more of the composition. Information on proprietary materials is available in
29CFR 1910.1200(i)(1).
3. Hazards Identification
Primary Routes(s) Of Entry
Skin Contact
Eye Hazards
Causes eye irritation.
Skin Hazards
May cause skin irritation.
Ingestion Hazards
May be harmful if swallowed.
Inhalation Hazards
None normally associated with this product
First Aid (Pictograms)

4. First Aid Measures
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes.
Skin
In case of contact, immediately flush skin with soap and plenty of water.

MATERIAL SAFETY DATA

SHEET

Page 2 of 4

Leisure Time Foam Down
4. First Aid Measures - Continued
Ingestion
If swallowed, induce vomiting immediately. Call a physician or a poison control center immediately.
Inhalation
If inhaled, remove to fresh air. If breathing is difficult, give oxygen.
Fire Fighting (Pictograms)

5. Fire Fighting Measures
Flash Point: n/a °F
Fire And Explosion Hazards
Burning causes oxides of carbon and silicone
Extinguishing Media
Use the appropriate extinguishing media for the surrounding fire.
Fire Fighting Instructions
Firefighters should wear self-contained breathing apparatus and full protective gear.
6. Accidental Release Measures
Contain and/or absorb spill with inert material (e.g. sand, vermiculite). Collect and dispose. Flush spill area with water.
7. Handling And Storage
Handling And Storage Precautions
Keep out of reach of children. Store material in a cool and dry place.
Work/Hygienic Practices
Use safe chemical handling procedures suitable for the hazards presended by this material.
Protective Clothing (Pictograms)

8. Exposure Controls/Personal Protection
Engineering Controls
Local exhaust acceptable. Special exhaust not required
Eye/Face Protection
Safety glasses with side shields or goggles.
Skin Protection
Chemical-resistant gloves.
Respiratory Protection
None normally required.
9. Physical And Chemical Properties
Appearance
Creamy white liquid

MATERIAL SAFETY DATA

SHEET

Leisure Time Foam Down
9. Physical And Chemical Properties - Continued
Odor
Mild
Chemical Type: Mixture
Physical State: Liquid
Melting Point: n/a °F
Boiling Point: 212 °F
Specific Gravity: 1.0
Percent Volitales: NOT ESTABLISHED
Vapor Pressure: NOT ESTABLISHED
Vapor Density: NOT ESTABLISHED
pH Factor: 6-7
Solubility: SOLUBLE IN WATER
Viscosity: NOT ESTABLISHED
Evaporation Rate: NOT ESTABLISHED
10. Stability And Reactivity
Sta bility: Stable
Hazardous Polymerization: Will not occur
Incompatible Materials
Strong Oxidants
Hazardous Decomposition Products
Burning causes oxides of carbon and silicone
11. Toxicological Information
No Data Available...
12. Ecological Information
No Data Available...
13. Disposal Considerations
Dispose in accordance with applicable federal, state and local government regulations.
14. Transport Information
Proper Shipping Name
NOT REGULATED
Hazard Class
NOT REGULATED
DOT Identification Number
NONE
15. Regulatory Information
No Data Available...

Page 3 of 4

MATERIAL SAFETY DATA

SHEET

Page 4 of 4

Leisure Time Foam Down
NFPA

HMIS

0
1

0

HEALTH

1

FLAMMABILITY

0

REACTIVITY

0

PERSONAL

B

PROTECTION

16. Other Information
Revision/Preparer Information
MSDS Preparer: JHW3
Disclaimer
Although reasonable care has been taken in the preparation of this document, we extend no warranties
and make no representations as to the accuracy or completeness of the information contained therein,
and assume no responsibility regarding the suitablility of this information for the user's intended purposes
or for the consequences of its use. Each individual should make a determination as to the suitability of
the information for their particular purposes(s).
Leisure Time
Printed Using MSDS Generator™ 2000

Vanson HaloSource, Inc
Material Safety Data Sheet
Material Name: SeaKlear® Natural Clarifier for Pools
Telephone No: 425-881-6464

VHI-MSDS-02.13 Rev 03
Date Prepared: 04-28-05

24-HOUR EMERGENCY PHONE: CHEMTREC 800-424-9300
SECTION I – CHEMICAL PRODUCT & COMPANY IDENTIFICATION
Manufacturer's Name:
Corporate Address:
Emergency Phone:
Manufacturer's Phone:
Material Name:
Chemical Name:

Vanson HaloSource, Inc.
14716 NE 87th Street, Redmond, WA 98052
800-424-9300 Chemtrec
(425) 881-6464
SeaKlear Natural Clarifier
Chitosan acetate

SECTION II – COMPOSITION, INFORMATION ON INGREDIENTS

CAS NO.
9012-76-4
64-19-7

INGREDIENT

EXPOSURE LIMITS

Chitosan
Acetic Acid
Water

NA

SECTION III – HAZARDS IDENTIFICATION
PRINCIPAL HEALTH HAZARDS, INCLUDING SIGNIFICANT ROUTES, EFFECTS, AND SYMPTOMS OF
OVEREXPOSURE AND MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE MAY BE:
EYE: May be mildly irritating to eyes.
SKIN: Not hazardous to skin.
INHALATION: See first aid section below.
INGESTION: Not likely to be hazardous by ingestion.
CARCINOGENICITY: Not listed by National Toxicology Program (NTP) OSHA, or International Agency for Research on
Cancer (IARC)

SECTION IV - FIRST AID

EYES: Remove contact lenses (if applicable), flush with water for 15 minutes. Call a physician.
SKIN: Cleansing the skin after exposure is advisable.
INHALATION: If large amounts of fumes are inhaled, remove to fresh air and consult a physician.
INGESTION: Consult a physician if necessary.

Page 1 of 5

Vanson HaloSource, Inc
Material Safety Data Sheet
Material Name: SeaKlear® Natural Clarifier for Pools
Telephone No: 425-881-6464

VHI-MSDS-02.13 Rev 03
Date Prepared: 04-28-05

SECTION V - FIRE FIGHTING MEASURES

HAZARDOUS COMBUSTION PRODUCTS: NA
EXTINGUISHING MEDIA: Does not burn. Use water, dry chemicals, carbon dioxide, sand or foam. Use extinguishing
media appropriate for surrounding fire.
FIREFIGHTING INSTRUCTIONS: Do not enter confined fire space without full bunker gear (helmet with face shield,
bunker coat, gloves and rubber boots), including a positive pressure NIOSH approved self-contained breathing
apparatus. Water may be used to keep fire-exposed containers cool until fire is out.
FLASH POINT: NA

SECTION VI – ACCIDENTAL RELEASE MEASURES

SPILL: Wear suitable protective clothing. Dilute with water and hose down.
DISPOSAL INFORMATION: Material is 100% biodegradable, is nontoxic and can be disposed of in any approved
manner. Treatment, storage, transportation and disposal must be in accordance with applicable Federal
State/Provincial and local regulations.
DISPOSAL METHODS: Dilute with water and hose down.

SECTION VII - HANDLING & STORAGE

HANDLING & STORAGE PRECAUTIONS: 10-50°C recommended (will freeze @ ~3°C). Shelf life is indefinite but
viscosity will decrease over time. The container should be kept covered to prevent contamination.

SECTION VIII - EXPOSURE CONTROLS/ PERSONAL PROTECTION

PERSONAL PROTECTIVE EQUIPMENT (PPE): Good hygiene practices should be strictly followed. Before eating,
drinking or smoking, wash face and hands thoroughly. Emergency showers and eyewash facilities should be
accessible.
EYE PROTECTION: Safety glasses recommended.
SKIN PROTECTION: Rubber gloves recommended.
PROTECTIVE CLOTHING: NA

Page 2 of 5

Vanson HaloSource, Inc
Material Safety Data Sheet
Material Name: SeaKlear® Natural Clarifier for Pools
Telephone No: 425-881-6464

VHI-MSDS-02.13 Rev 03
Date Prepared: 04-28-05

PROTECTIVE FOOTWEAR: NA
RESPIRATORY PROTECTION: NA
.
VENTILATION REQUIREMENTS: Generally adequate

SECTION IX - PHYSICAL & CHEMICAL PROPERTIES

PHYSICAL FORM: Clear to pale yellow viscous liquid with a pungent vinegar odor.
BOILING POINT: 211°F
MELTING POINT: NA
pH: 3.0-4.5
SOLUBILITY IN WATER: Soluble.
SPECIFIC GRAVITY: 1.0-1.1 g/mL

SECTION X - STABILITY & REACTIVITY DATA

CHEMICAL STABILITY: Stable.
HAZARDOUS POLYMERIZATION: Will not occur.
INCOMPATIBLES: Strong oxidizing material and strong bases.
DECOMPOSITION PRODUCTS: Decomposition will not occur.
Material is bio-degradable.

SECTION XI - TOXICOLOGICAL INFORMATION

ORAL Rat LD50 (MG/KG): NA
NA
Ipr Rat, LD50(MG/KG):
SCU Mouse, LD50(MG/KG): NA

IV-Mouse, LD50(MG/KG): NA
DERMAL LD50 (rabbit): NA
EYE IRRITATION (rabbit): NA
SKIN IRRITATION (rabbit): NA

Page 3 of 5

Vanson HaloSource, Inc
Material Safety Data Sheet
Material Name: SeaKlear® Natural Clarifier for Pools
Telephone No: 425-881-6464

VHI-MSDS-02.13 Rev 03
Date Prepared: 04-28-05

SECTION XII - ECOLOGICAL INFORMATION
Fish 96-hour LC50
Daphnia 48-hour LC50
Green algae 96-hour EC50
Fish Chronic Value (ChV)
Daphnia ChV
Algae ChV

=
=
=
=
=
=

NA
NA
NA
NA
NA
NA

SECTION XIII - DISPOSAL CONSIDERATION

WASTE DISPOSAL METHOD: Dispose of in accordance with all applicable federal, local and State environmental
regulations. Material is 100% biodegradable, is nontoxic and can be disposed of in any approved manner.

SECTION XIV - TRANSPORTATION INFORMATION

DOT Proper Shipping Name:
DOT Hazard Class:
Packing Group:
UN Number:
Product RQ (lbs.):
DOT Label:
DOT Placard:

Chemicals, N.O.S. (non-regulated) (Domestic & International)

Not regulated as a hazardous material
NA
NA
NA
NA
NA

SECTION XV - REGULATORY INFORMATION

MATERIAL IS REPORTED IN EPA TSCA INVENTORY LIST?: No
MATERIAL IS LISTED AS A CARCINOGEN/POTENTIAL CARCINOGEN IN FOLLOWING?: No
NTP ANNUAL REPORT: No

IARC GROUP I OR II: No

OSHA 29CFR PART 1910 SUBPART Z: No

DOES PRODUCT CONTAIN A TOXIC CHEMICAL SUBJECT TO SARA TITLE III SECTION 313 REPORTING: No
SARA TITLE III SECTION 311/312 CLASSIFICATIONS: None

Page 4 of 5

Vanson HaloSource, Inc
Material Safety Data Sheet
Material Name: SeaKlear® Natural Clarifier for Pools
Telephone No: 425-881-6464

VHI-MSDS-02.13 Rev 03
Date Prepared: 04-28-05

SECTION XVI – OTHER INFORMATION
The above information is based upon information Vanson-HaloSource, Inc. believes to be reliable and is supplied for
informational purposes only. Vanson-HaloSource, Inc. disclaims any liability for damage which results from the use of
the above information and nothing contained therein shall constitute a guarantee, warranty (including fitness for a
particular purpose) or representation with respect to the accuracy or completeness of the data, the product described or
their use for any specific purpose even if that purpose is known to Vanson-HaloSource, Inc. The final determination of
the suitability of the information, the manner of use of the information or product and potential infringement is the sole
responsibility of the user.

Page 5 of 5

MATERIAL SAFETY DATA

SHEET

GLB TLC

1. Product And Company Identification
Supplier
GLB
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Manufacturer
Advantis Technologies Inc.
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Telephone Number: (770)521-5999
FAX Number: (770)521-5959
Web Site: www.poolspacare.com

Telephone Number: (770) 521-5999
FAX Number: (770) 521-5959
Web Site: www.poolspacare.com

Supplier Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Manufacturer Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Issue Date: 04/01/2005
Product Name: GLB TLC
CAS Number: Not Established
Chemical Family: Acid Mixture
Chemical Formula: Proprietary
MSDS Number: 19
Product Code: Proprietary
2. Composition/Information On Ingredients
Ingredient
Name

CAS
Number

Bis(2-hydroxyethyl)tallowammonium ethanoate

Percent Of
Total Weight

70750-46-8

HYDROCHLORIC ACID

7647-01-0

PHOSPHORICACID

7664-38-2

SULFURIC ACID

7664-93-9

Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials
determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as
carcinogens are listed if they comprise 0.1% or more of the composition. Information on proprietary materials is available in
29CFR 1910.1200(i)(1).
Hazards Identification (Pictograms)

3. Hazards Identification
Primary Routes(s) Of Entry
Eye Contact, Skin Contact
Eye Hazards
Causes severe eye burns.
Skin Hazards
Causes severe skin burns.

Page 1 of 6

MATERIAL SAFETY DATA

SHEET

GLB TLC
3. Hazards Identification - Continued
Ingestion Hazards
Corrosive to living tissue.
Inhalation Hazards
May cause severe allergic respiratory reaction.
Signs And Symptoms
Irritation of Eyes, Skin and Respiratory Passages
First Aid (Pictograms)

4. First Aid Measures
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes.Call a
physician or a poison control center immediately.
Skin
Rinse the affected area with tepid water for at least 15 minutes.Get medical attention immediately if irritation
(redness, rash, blistering) develops and persists.
Ingestion
DO NOT INDUCE VOMITING. Drink large amounts of water. Contact a physician or poison control.
Inhalation
If inhaled, remove to fresh air. If breathing is difficult, give oxygen. Call a physician or a poison control center
immediately.
Fire Fighting (Pictograms)

5. Fire Fighting Measures
Flash Point: N/A °F
Extinguishing Media
Use the appropriate extinguishing media for the surrounding fire.
Fire Fighting Instructions
Water can be used to cool and protect exposed material. Firefighters should wear self-contained breathing apparatus
and full protective gear.
6. Accidental Release Measures
Neutralize spill area with soda ash or lime. Flood with water. Use appropriate containers to avoid environmental
contamination. Use appropriate personal protective equipment (PPE).
7. Handling And Storage
Handling And Storage Precautions
Keep out of reach of children. Do not store with alkalis.

Page 2 of 6

MATERIAL SAFETY DATA

SHEET

GLB TLC
7. Handling And Storage - Continued
Handling Precautions
Avoid contact with eyes. Avoid contact with skin and clothing. Wash thoroughly after handling.
Storage Precautions
Avoid contact with Alkalis, Amines, and Metals. Keep out of reach of children.
Work/Hygienic Practices
Use safe chemical handling procedures suitable for the hazards presended by this material.
Protective Clothing (Pictograms)

8. Exposure Controls/Personal Protection
Engineering Controls
Local exhaust acceptable. Special exhaust not required
Eye/Face Protection
Safety glasses with side shields or goggles recommended.
Skin Protection
Chemical-resistant gloves.
Respiratory Protection
None normally required.
Ingredient(s) - Exposure Limits
Bis(2-hydroxyethyl)tallowammonium ethanoate
NOT ESTABLISHED
HYDROCHLORIC ACID
ACGIH TLV-CEILING 5 ppm
OSHA PEL-CEILING 5 ppm
PHOSPHORIC ACID
ACGIH TLV-STEL 3 mg/m3
ACGIH TLV-TWA 1 mg/m3
OSHA PEL-TWA 1 mg/m3
SULFURIC ACID
ACGIH TLV-STEL 3 mg/m3
ACGIH TLV-TWA 1 mg/m3
OSHA PEL-TWA 1 mg/m3
9. Physical And Chemical Properties
Appearance
Pale amber liquid
Odor
Mild
Chemical Type: Mixture
Physical State: Liquid
Melting Point: n/a °F
Boiling Point: 212 °F
Specific Gravity: 1.1-1.2
Percent Volitales: NOT DETERMINED
Page 3 of 6

MATERIAL SAFETY DATA

SHEET

GLB TLC
9. Physical And Chemical Properties - Continued
Odor - Continued
Packing Density: NOT DETERMINED
Vapor Pressure: NOT DETERMINED
Vapor Density: >1
pH Factor: 0-2
Solubility: Soluble in Water
Viscosity: NOT DETERMINED
Evaporation Rate: <1
10. Stability And Reactivity
Sta bility: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid (Stability)
Avoid contact with strong Amines, Alkalis, and Metals. Heat can cause hydrogen chloride.
Incompatible Materials
Alkalis, Amines and Metals
Hazardous Decomposition Products
Hydrogen Chloride
11. Toxicological Information
Ingredient(s) - Carginogenicity
SULFURIC ACID
NTP - Listed On The National Toxicology Program
Listed In The IARC Monographs
12. Ecological Information
No Data Available...
13. Disposal Considerations
Refer to applicable federal, state, and local regulations prior to disposition of container and residual contents.
14. Transport Information
Proper Shipping Name
Corrosive Liquid, Acidic, Inorganic, N.O.S. (Hydrochloric and Sulfuric Acids)
Hazard Class
8, PGII (<1L Consumer Commodity ORM-D)
DOT Identification Number
UN3264
DOT (Pictograms)

15. Regulatory Information
Ingredient(s) - U.S. Regulatory Information
HYDROCHLORIC ACID
SARA Title III - Section 313 Form "R"/TRI Reportable Chemical
SARA - Acute Health Hazard
Page 4 of 6

MATERIAL SAFETY DATA

SHEET

GLB TLC
15. Regulatory Information - Continued
Ingredient(s) - U.S. Regulatory Information - Continued
SULFURIC ACID
SARA Title III - EPA Part 355 Extremely Hazardous Substance
SARA Title III - Section 313 Form "R"/TRI Reportable Chemical
SARA - Acute Health Hazard
SARA - Chronic Health Hazard
SARA - Fire Hazard
SARA - Reactivity Hazard
Ingredient(s) - State Regulations
HYDROCHLORIC ACID
New Jersey - Workplace Hazard
New Jersey - Environmental Hazard
New Jersey - Special Hazard
New Jersey - TCPA Extraordinarily Hazardous Substance
Pennsylvania - Workplace Hazard
Pennsylvania - Environmental Hazard
Massachusetts - Hazardous Substance
New York City - Hazardous Substance
SULFURIC ACID
New Jersey - Workplace Hazard
New Jersey - Environmental Hazard
New Jersey - Special Hazard
Pennsylvania - Workplace Hazard
Pennsylvania - Environmental Hazard
California - CalARP Table 3 Regulated Substance
Massachusetts - Hazardous Substance
New York City - Hazardous Substance
Canadian Regulatory Information
Class D, Div 1a - Poisonous or Infectious Material: immediate and serious toxic effects
Class D, Div 2a - Poisonous or Infectious Material: other toxic effects
Class D, Div 2b - Poisonous or Infectious Material: other toxic effects
Class E - Corrosive Material
WHMIS - Canada (Pictograms)

NFPA

HMIS

1
2

2

HEALTH

3

FLAMMABILITY

0

REACTIVITY

1

PERSONAL

C

PROTECTION

16. Other Information
Revision/Preparer Information
MSDS Preparer: JHW

Page 5 of 6

MATERIAL SAFETY DATA

SHEET

GLB TLC
Disclaimer
Although reasonable care has been taken in the preparation of this document, we extend no warranties
and make no representations as to the accuracy or completeness of the information contained therein,
and assume no responsibility regarding the suitablility of this information for the user's intended purposes
or for the consequences of its use. Each individual should make a determination as to the suitability of
the information for their particular purposes(s).
GLB
Printed Using MSDS Generator™ 2000

Page 6 of 6

Product #DESP

Page 1 of 7

MATERIAL SAFETY DATA SHEET

Diatomaceous Earth
Section 01 - Chemical And Product And Company Information
Product Identifier ……………………... Diatomaceous earth; Celatom FP-4, FW-10, FW-12, FW-14, FW-18,
FW-20, FW-40, FW-50, FW-60, FW-70, FW-80, or SP
Product Use …………………………..... Filter aid
Supplier Name……………………….…. ClearTech Industries Inc.
2303 Hanselman Avenue
Saskatoon, SK. Canada
S7L 5Z3
Prepared By................……………..….. ClearTech Industries Inc. Technical Department
Phone: (306)664-2522
Preparation Date.........…………….…... August 18, 2005
24-Hour Emergency Phone…………... 306-664-2522

Section 02 - Composition / Information on Ingredients
Hazardous Ingredients....………….... Diatomaceous Earth, Flux-Calcined(Diatomite) 100%
Crystalline silica(Cristobalite)
35-50%
CAS Number...................…….…….....Diatomaceous Earth, Flux-Calcined(Diatomite) 68855-54-9
Crystalline silica(Cristobalite)
14464-46-1
Synonym (s)...................……………...Aqua-cel; flux calcined diatomaceous earth

Section 03 - Hazard Identification
Inhalation...................………….….... Upper respiratory irritant. May cause coughing or throat irritation.
Breathing dust containing crystalline silica over a long period may cause
lung damage.

Product #DESP

Page 2 of 7

Skin Contact / Absorption…….….... May cause slight irritation.

Eye Contact................………….….... May cause slight irritation.
Ingestion.....................………………. May cause slight irritation. Not hazardous when digested.
Exposure Limits……………………... ACGIH/TLV: 0.05 mg/m3 (cristobalite)
ACGIH/TLV: 0.10 mg/m3 (silica, crystalline quartz), local regulated limits
may vary.

Section 04 - First Aid Measures
Inhalation....................……………….. Remove victim to fresh air. Give artificial respiration only if breathing has
stopped. If breathing is difficult, give oxygen. Seek immediate medical
attention.
Skin Contact / Absorption………….. Remove contaminated clothing. Wash affected area with soap and
water. Seek medical attention if irritation occurs or persists.
Eye Contact..................…………….... Flush immediately with water for at least 20 minutes. Forcibly hold
eyelids apart to ensure complete irrigation of eye tissue. Seek immediate
medical attention
Ingestion......................………………. No known health effects with short-term exposure. Drink water to reduce
bulk and drying effects. Seek immediate medical attention if there is
irritation.
Additional Information.....…………... Not available

Section 05 - Fire Fighting
Conditions of Flammability……….... Non-flammable
Means of Extinction........…………..... Product does not burn. Use appropriate extinguishing media for material
that is supplying the fuel to the fire.
Flash Point....………………………….. Not applicable
Auto-ignition Temperature…………. Not applicable
Upper Flammable Limit …………….. Not applicable

Product #DESP

Page 3 of 7

Lower Flammable Limit...……….…... Not applicable
Hazardous Combustible Products... Not applicable
Special Fire Fighting Procedures..... Wear NIOSH-approved
protective clothing.

self-contained

breathing

apparatus

and

Explosion Hazards………………….... Not applicable

Section 06 - Accidental Release Measures
Leak / Spill................….……………... Diatomaceous earth is a non-toxic, non-biodegradable mineral. Waste
generated from this product would only be considered hazardous when
mixed with a substance that would be considered hazardous. Flush area
with water to remove any residue.
Deactivating Materials...……….…... None

Section 07 - Handling and Storage
Handling Procedures.......…………... Use proper equipment for lifting and transporting all containers. Use
sensible industrial hygiene and housekeeping practices. Wash thoroughly
after handling. Avoid all situations that could lead to harmful exposure.
Storage Requirements......……...….. Store in a cool, dry, well-ventilated place. Keep container tightly closed,
and away from incompatible materials.

Section 08 - Personal Protection and Exposure Controls
Protective Equipment
Eyes.………………………….………... Chemical goggles, full-face shield, or a full-face respirator is to be worn at
all times when product is handled. Contact lenses should not be worn;
they may contribute to severe eye injury.
Respiratory………………………….... NIOSH approved respirators (standard 42CFR84, series N95) for
protection against pneumoconiosis producing dusts recommended when
dust is present.
Gloves………………………………..... Impervious gloves of chemically resistant material (rubber or PVC) should
be worn at all times. Wash contaminated clothing with soap and water,
dry thoroughly before reuse.

Product #DESP

Page 4 of 7

Clothing………………………..…….... Body suits, aprons, and/or coveralls of chemical resistant material should
be worn at all times. Wash contaminated clothing with soap and water, dry
thoroughly before reuse.

Footwear……………………………..... Impervious boots of chemically resistant material should be worn at all
times

Engineering Controls
Ventilation Requirements………...... Mechanical ventilation (dilution or local exhaust), process or personnel
enclosure, and control of process conditions. Supply sufficient
replacement air to make up for air removed by exhaust systems.
Other………………………………….... Emergency shower and eyewash should be in close proximity.

Section 09 - Physical and Chemical Properties
Physical State.......……....………….... Solid
Odor and Appearance…..………….... Fine odourless white, buff, or pink powder
Odor Threshold....……………............ Not available
Specific Gravity (Water=1)………….. 2.33
Vapor Pressure (mm Hg, 20C)….….. Not available
Vapor Density (Air=1)..…………….... Not available
Evaporation Rate........……..…….….. Not available
Boiling Point...............………….…..... Not available
Freeze/Melting Point....…………….... Not available
pH............................……………….….. 9-10 (10% slurry)
Water/Oil Distribution Coefficient.... Not available
Bulk Density..............…………….…... Varies with grade
% Volatiles by Volume………..……... 0%
Solubility in Water...………………..... <2%
Molecular Formula......………….….... Not applicable

Product #DESP

Page 5 of 7

Molecular Weight........……………..... Not applicable

Section 10 - Stability and Reactivity
Stability.................…………....……………. Stable under normal conditions.
Incompatibility..............…………..……….. Incompatible with hydrofluoric acid. Reaction with hydrofluoric acid
will evolve silicon tetrafluoride.
Hazardous Products of Decomposition.. Not available
Polymerization...........…………….…….…. Will not occur

Section 11 - Toxicological Information
Irritancy.................……..………….…. May cause dryness to mucous membranes.
Sensitization........…….......…………. Not available
Chronic/Acute Effects……...……….. Inhalation of dust in excess of OSHA/PEL over an extended number of
years may cause silicosis, a progressive and sometimes fatal lung
disease. Although silicosis is a non-cancerous lung disease, crystalline
silica has been determined by the International Agency for Research on
Cancer to be 'probably carcinogenic to humans.'
Synergistic Materials...……....……... Not available
Animal Toxicity Data......…..………... Not available
Carcinogenicity......……......………... IARC: crystalline silica classed as 2A; probably a human carcinogen.
Reproductive Toxicity..…...………... Not available
Teratogenicity..........….....…………... Not available
Mutagenicity...........…….....…………. Not available

Section 12 - Ecological Information
Fish Toxicity..................……………... Not available
Biodegradability.............……….….... Not available
Environmental Effects………………. Insoluble mineral product, will not have an adverse affect on waterways.

Product #DESP

Page 6 of 7

Section 13 - Disposal Consideration
Waste Disposal...........…...…………...Dispose in accordance with all federal, provincial, and/or local regulations
including the Canadian Environmental Protection Act.

Section 14 - Transportation Information
TDG Classification
Class……………..………………..….... Not regulated
Group...............…………….......……... Not regulated
PIN Number.................……..……….... Not regulated
Other…………………………………..... Secure containers (full and/or empty) with suitable hold down devises
during shipment.

Section 15 - Regulatory Information
WHMIS Classification.......…………....D2
NOTE: THE PRODUCT LISTED ON THIS MSDS HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE
HAZARD CRITERIA OF THE CANADIAN CONTROLLED PRODUCTS REGULATIONS.
THIS MSDS
CONTAINS ALL INFORMATION REQUIRED BY THOSE REGULATIONS

Section 16 - Other Information
Note: The responsibility to provide a safe workplace remains with the user. The user should consider the
health hazards and safety information contained herein as a guide and should take those precautions
required in an individual operation to instruct employees and develop work practice procedures for a safe
work environment. The information contained herein is, to the best of our knowledge and belief, accurate.
However, since the conditions of handling and use are beyond our control, we make no guarantee of
results, and assume no liability for damages incurred by the use of this material. It is the responsibility of
the user to comply with all applicable laws and regulations.

ClearTech Industries Inc. - Locations
Corporate Head Office: 2302 Hanselman Avenue, Saskatoon, SK, S7L 5Z3
Phone: 306-664-2522
Fax: 306-665-6216
www.ClearTech.ca
Location
Richmond BC
Calgary AB
Edmonton AB
Saskatoon SK

Address
12431 Horseshoe way
5516E - 40th St. S.E.
11750 - 180th Street
2302 Hanselman Avenue

Postal Code
V7A 4X6
T2C 2A1
T5S 1N7
S7L 5Z3

Phone Number
604-272-4000
403-279-1096
780-452-6000
306-933-0177

Fax Number
604-272-4596
403-236-0989
780-452-4600
306-933-3282

Product #DESP

Regina SK
Winnipeg MB
Mississauga ON

Page 7 of 7

555 Henderson Drive
340 Saulteaux Crescent
7480 Bath Road

S42 5X2
R3J 3T2
L4T 1L2

306-721-7737
204-987-9777
905-612-0566

306-721-8611
204-987-9770
905-612-0575

24 Hour Emergency Number - All Locations - 306-664-2522

Eli Lilly and Company
Material Safety Data Sheet
MSDS Index

Sodium Bicarbonate
Effective Date: 05-Aug-2004

Section 1 - Chemical Product and Company
Emergency Phone:
1-317-276-2000
CHEMTREC:
1-800-424-9300 (North America)
1-703-527-3887 (International)

Manufacturer:
Eli Lilly and Company
Lilly Corporate Center
Indianapolis, IN 46285
Common Name: Sodium Bicarbonate

CAS Number(s): 144-55-8
EINECS Number: 2056-33-8
Chemical Name: Carbonic acid monosodium salt
Chemical Family: Inorganic salt
Chemical Formula: C H O3 . Na
Molecular Weight: 84.01
Synonym(s): Sodium bicarbonate tablets; Soludal; Meylon; Soda; Monosodium carbonate; Sodium
hydrogen carbonate; Sodium acid carbonate; Bicarbonate of soda; Baking soda; Soda mint; NaHCO3;
Sodium bicarbonate - cell culture grade; Sodium bicarbonate tablet mix
Lilly Serial Number(s): 237728
Lilly Item Code(s): QA049K; QA116D; QA192M; QA241X; QA281L; QA384W; QA476V; QD400T;
QD472B; TA1260; TA1264; TA1265
See attached glossary for abbreviations.

Section 2 - Composition / Information on Ingredients
Ingredient
Sodium Bicarbonate

CAS
144-55-8

Exposure Guidelines:
Sodium bicarbonate - Exposure Guideline 1500 micrograms/m3 TWA for 12 hours, 2300
micrograms/m3 TWA for 8 hours. (Lilly-established guideline)
Dow Chemical Exposure Guideline 10 mg/m3 TWA.

Section 3 - Hazards Identification

Appearance: White crystalline powder or granules or compressed uncoated tablets
Physical State: Solid
Odor: Odorless

Emergency Overview
Emergency Overview Effective Date: 07-Aug-2002
Lilly Laboratory Labeling Codes:
Health 1
Fire 0

Reactivity 0

Primary Physical and Health Hazards: No Significant Health Hazards.
Caution Statement: No significant health hazards have been reported for Sodium Bicarbonate.

Routes of Entry: Inhalation and skin contact.
Effects of Overexposure: Material has low acute oral or inhalation toxicity. Material may be slightly
irritating to the eyes, skin, and respiratory tract. Inhalation of dust may cause coughing.
Medical Conditions Aggravated by Exposure: None known.
Carcinogenicity: No carcinogenicity data found. Not listed by IARC, NTP, ACGIH, or OSHA.

Section 4 - First Aid Measures
Eyes: Flush eyes with plenty of water. Get medical attention.
Skin: Remove contaminated clothing and clean before reuse. Wash all exposed areas of skin with
plenty of soap and water. Get medical attention if irritation develops.
Inhalation: Move individual to fresh air. Get medical attention if breathing difficulty occurs. If not
breathing, provide artificial respiration assistance (mouth-to-mouth) and call a physician immediately.
Ingestion: Call a physician or poison control center. No first aid procedures are normally required.

Section 5 - Fire Fighting Measures
Flash Point: Not applicable
UEL: Not applicable
LEL: Not applicable
Extinguishing Media: Use water, carbon dioxide, dry chemical, foam, or Halon.

Unusual Fire and Explosion Hazards: None known.
Hazardous Combustion Products: May emit toxic fumes when exposed to heat or fire.

Section 6 - Accidental Release Measures
Spills: Wear protective equipment, including eye protection, to avoid exposure (see Section 8 for
specific handling precautions). Vacuum material with appropriate dust collection filter in place. Be
aware of potential for dust explosion when using electrical equipment. If vacuum is not available,
lightly mist material and remove by sweeping or wet wiping.

Section 7 - Handling and Storage
Lilly Warehouse Storage Category: 140X
Storage Conditions: Warehouse: 10 to 40 C (45 to 104 F). For certain items, other storage conditions
may be required.

Section 8 - Exposure Controls / Personal Protection
See Section 2 for Exposure Guideline information.
Respiratory Protection: Use an approved respirator.
Eye Protection: Chemical goggles and/or face shield.
Ventilation: Laboratory fume hood or local exhaust ventilation.
Other Protective Equipment: Chemical-resistant gloves and body covering to minimize skin
contact. If handled in a ventilated enclosure, as in a laboratory setting, respirator and goggles or face
shield may not be required. Safety glasses are always required.

Section 9 - Physical and Chemical Properties
Boiling Point: Not applicable
Melting Point: Not applicable
Specific Gravity: 2.159
pH: 8.2 (1% solution)
Evaporation Rate: Not applicable
Water Solubility: 8.6 g/100 ml @ 20 C (68 F)
Vapor Density: Not applicable
Vapor Pressure: Not applicable

Section 10 - Stability and Reactivity

Stability: Stable at normal temperatures and pressures.
Incompatibility: May react with strong oxidizing agents (e.g., peroxides, permanganates, nitric acid,
etc.) and strong acids.
Hazardous Decomposition: May emit toxic fumes when heated to decomposition.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information
Acute Exposure
Oral:
Sodium bicarbonate - Rat, median lethal dose 4220 mg/kg.
Skin: No applicable information found.
Inhalation:
Sodium bicarbonate - Rat, median lethal concentration greater than 4740 mg/m3
(duration unspecified).
Skin Contact: No applicable information found.
Eye Contact:
Sodium bicarbonate - Rabbit, mild irritant

Chronic Exposure
Target Organ Effects: No applicable information found.
Reproduction:
Sodium bicarbonate - No teratogenic effects reported in rats or mice given large doses during
pregnancy.
Sensitization: No applicable information found.
Mutagenicity:
Sodium bicarbonate - Negative in Ames assay.

Section 12 - Ecological Information
Ecotoxicity Data:
Sodium bicarbonate
Daphnia magna 48-hour median lethal concentration: 11.7 mmol/L to 26.3 mmol/L
Western mosquitofish 96-hour median lethal concentration: 5.6 g/L
Bluegill 96-hour median lethal concentration: 8.25 g/L

Rainbow trout median lethal concentration (duration unspecified): 7.7 g/L
Environmental Fate: No applicable information found.
Environmental Summary:
Sodium bicarbonate - This material is practically non-toxic to aquatic organisms. Material is soluble in
water and may leach from soil into groundwater.

Section 13 - Disposal Considerations
Waste Disposal: Dispose of any cleanup materials and waste residue according to all applicable laws
and regulations.

Section 14 - Transport Information
Regulatory Organizations:
DOT: Not Regulated
ICAO/IATA: Not Regulated
IMO: Not Regulated

Section 15 - Regulatory Information
Below is selected regulatory information chosen primarily for possible Eli Lilly and Company
usage. This section is not a complete analysis or reference to all applicable regulatory
information. Please consider all applicable laws and regulations for your country/state.
U.S. Regulations
Sodium bicarbonate
TSCA - Yes
CERCLA - Not on this list
SARA 302 - Not on this list
SARA 313 - Not on this list
OSHA Substance Specific - No
EU Regulations
EC Classification
Not assigned an overall EC classification.

Section 16 - Other Information
MSDS Sections Revised: Section 7.

As of the date of issuance, we are providing available information relevant to the handling of this
material in the workplace. All information contained herein is offered with the good faith belief that it is
accurate. THIS MATERIAL SAFETY DATA SHEET SHALL NOT BE DEEMED TO CREATE ANY
WARRANTY OF ANY KIND (INCLUDING WARRANTY OF MERCHANTABILITY OR FITNESS
FOR A PARTICULAR PURPOSE). In the event of an adverse incident associated with this material,
this safety data sheet is not intended to be a substitute for consultation with appropriately trained
personnel. Nor is this safety data sheet intended to be a substitute for product literature which may
accompany the finished product.
For additional information contact:
Eli Lilly and Company
Hazard Communication
317-433-7171
GLOSSARY:
ACGIH = American Conference of Governmental Industrial Hygienists
AIHA = American Industrial Hygiene Association
BEI = Biological Exposure Index
CAS Number = Chemical Abstract Service Registry Number
CERCLA = Comprehensive Environmental Response Compensation and Liability Act (of 1980)
CHAN = Chemical Hazard Alert Notice
CHEMTREC = Chemical Transportation Emergency Center
DOT = Department of Transportation
EC = European Community
EINECS = European Inventory of Existing Chemical Substances
ELINCS = European List of New Chemical Substances
EPA = Environmental Protection Agency
HEPA = High Efficiency Particulate Air (Filter)
IARC = International Agency for Research on Cancer
ICAO/IATA = International Civil Aviation Organization/International Air Transport Association
IEG = Lilly Interim Exposure Guideline
IMO = International Maritime Organization
Kow = Octanol/Water Partition Coefficient
LEG = Lilly Exposure Guideline
LEL = Lower Explosive Limit
MSDS = Material Safety Data Sheet
MSHA = Mine Safety and Health Administration
NA = Not Applicable, except in Section 14 where NA = North America
NADA = New Animal Drug Application
NAIF = No Applicable Information Found
NCI = National Cancer Institute
NIOSH = National Institute for Occupational Safety and Health
NOS = Not Otherwise Specified
NTP = National Toxicology Program
OSHA = Occupational Safety and Health Administration
PEL = Permissible Exposure Limit (OSHA)
RCRA = Resource Conservation and Recovery Act
RQ = Reportable Quantity
RTECS = Registry of Toxic Effects of Chemical Substances

SARA = Superfund Amendments and Reauthorization Act
STEG = Lilly Short Term Exposure Guideline
STEL = Short Term Exposure Limit
TLV = Threshold Limit Value (ACGIH)
TPQ = Threshold Planning Quantity
TSCA = Toxic Substances Control Act
TWA = Time Weighted Average/8 Hours Unless Otherwise Noted
UEL = Upper Explosive Limit
UN = United Nations
WEEL = Workplace Environmental Exposure Level (AIHA)

R B F INTERNATIONAL LTEE / LTD
780, Nobel street,
St-Jérôme, Québec, J7Z 7A3
Tel.: (450) 438-4416, 1-800-433-0590
Fax: (450) 438-0827

Material Safety Data Sheet
Section I - Identification
2009048 – 2009085 – 2009086 - RONA

3” TABLETS STABILIZED CHLORINE
MANUFACTURER / SUPPLIER:

R B F INTERNATIONAL
780, Nobel street
St-Jerome, Quebec, J7Z 7A3
Tel.: (450) 438-4416, 1-800-433-0590

EMERGENCY LINES: (CANUTEC): 613 - 996 - 6666
1 - 800 - 463 - 5060

Chemical Name: Trichloro-s-triazine-trione
Product Use: Destroys bacteria and algae in swimming pool water.

Hazard Rating
4 Extreme
3 High
2 Moderate
1 Slight
0 None

Designation
Health
Fire
Reactivity
Personal Protection

2
0
1
D

Section II - Hazardous Ingredients
Material

Trichloro-s-triazine-trione

% By Weight

99-100

CAS Nr

Exposure Limits

LD50 (Oral-Rat)

87-90-1

6375 ppm

10.000 mg/Kg

MSDS

Page 1 of 4

RONA

3" TABLETS STABILIZED CHLORINE
Section III - Physical Data

Appearance
Boiling Point
Freezing Point
Odor
pH (1%)
Specific Gravity ( Water = 1)
Vapor Density ( Air = 1)
Vapor Pressure (mm Hg)
Evaporation Rate
Water Solubility
% Volatile
Coefficient water/oil distribution
Odor Threshold

White tablets.
Decompose at 2250C
N/A
N/A
2,3
2.09
N/A
N/A
N/A
Soluble (1g / 100 ml)
N/A
N/A
N/A

Section IV - Fire And Explosion Data
Flash Point (oC , Test Method):
Auto-Ignition Temperature:
Flammable Limits In Air: ( g/l ):
Extinguishing Media:
Special Fire Fighting Procedure:

Personal Protective Equipment:

Conditions of flammability:
Hazardous combustion products:
Explosion Data:
Sensitivity Impact:
Sensitivity to static discharge:
Mechanical Impact:

None
None
LFL: None
UFL: None
Dry Chemical (Sodium Bicarbonate), Foam, CO2, Water
Fight fires from a safe distance. DO NOT approach container
because of danger of rupturing. Use water spray to cool
containers exposed to fire.
Wear self-contained breathing apparatus (pressure-demand
MSHA/NIOSH approved or equivalent) and full protective
gear.
N/A
N/A
N/A
N/A
N/A
N/A

Section V - Health Hazard Information Of Product
Routes of Exposure and Acute Effects.
Inhalation:
Skin Contact:
Skin Absorption:
Eye Contact:
Ingestion:

May cause irritations.
May cause irritations.
May cause irritations.
May cause stinging or burning.
Poison. See a physician immediately.
MSDS

Page 2 of 4

RONA

3" TABLETS STABILIZED CHLORINE

Chronic Exposure.
Irritancy of product:
Sensitizing Capacity:
Mutagenic effect:
Teratogenic effect:
Carcinogenic effect:
Reproductive toxicity:
Synergistic products:

Irritating
N/A
N/A
N/A
N/A
N/A
N/A

Emergency and First Aid Procedure.
In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Call a physician immediately.
In case of contact, remove contaminated clothing and flush skin thoroughly with
Skin:
soap and water. Wash clothing before reusing.
Inhalation: If inhaled, remove to area of fresh air. If irritation persists, call a physician.
Ingestion: If swallowed, call a physician immediately.
Eyes:

Section VI - Reactivity Data
Conditions Contributing to Instability: This product is stable under normal conditions.
Avoid especially contact with oxidizing agents,
Incompatibility:
excessive heat, strong alkaline products.
Carbon Oxides ( CO2, CO ), Nitrogene, Trichloroamine
Decomposition Products:
In contact with oxidizing agents, open flame, sparks
Reactivity:
or ignition sources, strong alkaline products, sodium and
calcium hypochlorite, oil and grease.

Section VII - Spill Or Leak Procedures
Steps To Be Taken If Material Is Released Or Spilled
Cleanup personnel must wear proper protective equipment.
That is rubber gloves, face shield, safety goggles, safety shoes and protective clothing.
Never collect the spilled product in containers to be reused.
Neutralize with sodium thiosulfate and thoroughly wash area with water.
Waste Disposal Method.
Dispose according to Local, Provincial and Federal by-laws.

Section VIII - Special Protection Information.
Ventilation requirements
Local ventilation absolutely necessary.

MSDS

Page 3 of 4

RONA

3" TABLETS STABILIZED CHLORINE

Specific Personal Protective Information.
Chemical resistant gloves and other body protection (rubber apron,
boots, body covering clothes) to minimize skin contact.
Chemical splash goggles and/or face shield.
Eye Protection:
Respiratory protection: Use an approved self-contained breathing apparatus (MSHA/NIOSH
or equivalent).
Eye wash station and safety shower in area.
Other:
Do not wear contact lenses when working with this compound.
Skin Protection:

Section IX - Special Precaution.
Precaution To Be Taken In Handling.
Avoid inhalation of dust.
Avoid eye or skin contact. Do not take internally. Wash clothing before reuse.
Practice good personal hygiene.
Proper Storage, Handling and Disposal Requirements.
Store in tightly closed containers in a cool, dry, well-ventilated area.
Keep away from incompatible materials (oxidizing agents).
NO SMOKING in areas of storage, handling or use.

Section X - Transport And Regulatory Information.
TDG DESIGNATION:
UN NUMBER:
TDG CLASSIFICATION:
WHIMS CLASSIFICATION:
PACKING GROUP

Trichloroisocyanuric acid dry
2468
5.1
Schedule under the Pest Control
Product Act
II

Material Safety Data Sheet:
Prepared By:
Verified By:
Date Issued:

R. Ioanin
G. Radu
April 01, 2005

The information herein is given in good faith but no warranty, expressed or
implied is made. The persons receiving this information are urged to make
their own determination as to the information’s suitability and completeness
for their particular application.

MSDS

Page

4 of 4

Vanson HaloSource, Inc.
Material Safety Data Sheet
Material Name: SeaKlear® Phosphate Remover
Telephone No: 425-881-6464

VHI-MSDS-02.36 REV 05
Date Prepared: 12-19-05

24-HOUR EMERGENCY PHONE: CHEMTREC 800-424-9300
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
Manufacturer's Name:
Corporate Address:
Manufacturer's Telephone:
Emergency Telephone:
Material/Trade/Product Name:
Synonyms:
Chemical Name:
CAS No.:
Product Use:

Vanson HaloSource, Inc.
14716 NE 87th Street, Redmond, WA 98052
(425) 881-6464 (Monday-Friday, 8AM-5PM PDT)
800-424-9300 Chemtrec (24 Hours)
Phosphate Remover
None
Lanthanum Chloride, 7 hydrate (99.9%)
Not Applicable
Removes phosphates from water

SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS

CAS NO.

20211-76-1

HAZARDOUS INGREDIENT (S)

Lanthanum Chloride Hydrate

%

OSHA
HAZARDOUS
?

99.99

YES

NOTE: See Section 8 for permissible exposure limits.

SECTION 3: HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
Clear to slightly yellow liquid.
Can cause irritation to exposed areas of body. Severity of injury depends largely on duration of exposure.
Immediate action is necessary to limit severity of injury.
Hydrogen chloride will be produced from decomposition.
POTENTIAL HEALTH EFFECTS
EYE: May cause irritation.
SKIN: Possible skin irritant.
INHALATION: Should not be harmful if inhaled.
INGESTION: Possible irritant if swallowed.
Page 1 of 7

Vanson HaloSource, Inc.
Material Safety Data Sheet
Material Name: SeaKlear® Phosphate Remover
Telephone No: 425-881-6464

VHI-MSDS-02.36 REV 05
Date Prepared: 12-19-05

CHRONIC EXPOSURE/CARCINOGENICITY: This substance not listed as a potential carcinogen by IARC.
SIGNS AND SYMPTOMS OF OVEREXPOSURE: Eye and/or skin irritation.
AGGRAVATION OF PRE-EXISTING CONDITIONS: None known.

POTENTIAL ENVIRONMENTAL EFFECTS: None known.

SECTION 4: FIRST AID MEASURES

FIRST AID PROCEDURES
EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes, lifting eyelids occasionally.
Get medical attention at once.
SKIN CONTACT: Remove contaminated clothing and immediately wash exposed area for 15 minutes. Get
medical attention if necessary.
INHALATION: Move to fresh air. If breathing has stopped administer artificial respiration. Get medical
attention immediately.
INGESTION: Give large amounts of water. Do not induce vomiting. Get medical attention immediately.
NOTE TO PHYSICIANS: None

SECTION 5: FIRE FIGHTING MEASURES

FLASH POINT: Not applicable
UPPER FLAMMABLE LIMIT: Not applicable
FLAMMABLITY CLASS (OSHA): Not applicable

AUTOIGNITION TEMPERATURE: Not applicable
LOWER FLAMMABLE LIMIT: Not applicable
FLAME PROPAGATION/BURNING RATE: Not applicable

UNIQUE FIRE PROPERTIES: HCI is produced.
HAZARDOUS COMBUSTION PRODUCTS: HCI is produced.
EXTINGUISHING MEDIA: Use water, dry chemicals, carbon dioxide, sand or foam. Use extinguishing media
appropriate for surrounding fire.
PROTECTION OF FIREFIGHTERS: Do not enter confined fire space without full bunker gear (helmet with face shield,
bunker coat, gloves and rubber boots), including a positive pressure NIOSH approved self-contained breathing
apparatus. Water may be used to keep fire-exposed containers cool until fire is out.

Page 2 of 7

Vanson HaloSource, Inc.
Material Safety Data Sheet
Material Name: SeaKlear® Phosphate Remover
Telephone No: 425-881-6464

VHI-MSDS-02.36 REV 05
Date Prepared: 12-19-05

SECTION 6: ACCIDENTAL RELEASE MEASURES

PERSONAL PROTECTIVE EQUIPMENT: See Section 8 (Personal Protective Equipment).
ENVIRONMENTAL PRECAUTIONS: None
METHODS FOR CLEANING UP: Contain large spills and pump to recover. Small spills can be mopped up and
recovered.

SECTION 7: HANDLING AND STORAGE

SAFE HANDLING RECOMMENDATIONS
VENTILATION: Use general ventilation
FIRE PREVENTION: Not flammable
SPECIAL HANDLING REQUIREMENTS: Use appropriate PPE
SAFE STORAGE RECOMMENDATIONS
CONTAINMENT: Secondary containment is recommended.
STORAGE ROOM RECOMMENDATIONS: Store in cool, dry place. Keep container closed when not in use;
keep out of the reach of children.
INCOMPATIBLE MATERIALS: None known.
STORAGE CONDITIONS: Store in cool, dry place. Keep container closed when not in use; keep out of the
reach of children.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS: General ventilation
PERSONAL PROTECTIVE EQUIPMENT (PPE)
EYE/FACE PROTECTION: Safety glasses are recommended under normal conditions.
SKIN PROTECTION: Avoid contact with skin.

Page 3 of 7

Vanson HaloSource, Inc.
Material Safety Data Sheet
Material Name: SeaKlear® Phosphate Remover
Telephone No: 425-881-6464

VHI-MSDS-02.36 REV 05
Date Prepared: 12-19-05

HAND PROTECTION: Chemical resistant gloves are recommended to minimize potential irritation from
handling.
RESPIRATORY PROTECTION: None required where adequate ventilation conditions exist.
GOOD HYGEIENE/WORK PRACTICES: Always follow good hygiene/work practices by avoiding vapors or
mists and contact with eyes and skin. Thoroughly wash hands after handling and before eating or drinking.
Always wear the appropriate PPE when repairing or performing maintenance on contaminated equipment.
EXPOSURE GUIDELINES

INGREDIENT
CAS NO.
Not applicable

OSHA
TWA
Not
applicable

PERMISSIBLE EXPOSURE LIMITS
WISHA

STEL
Not
applicable

TWA
Not
applicable

STEL
Not
applicable

ACGIH (TLV)
TWA
Not
applicable

STEL
Not
applicable

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

COLOR: Clear to slightly yellow
PHYSICAL FORM: Liquid
pH: Not applicable
VAPOR DENSITY: 4.10
MELTING POINT: Not known
SOLUBILITY IN WATER: Appreciable (more than 10%)

SHAPE: Liquid
ODOR: None
VAPOR PRESSURE: Not known
BOILING POINT: Not known
FREEZING POINT: Not known
SPECIFIC GRAVITY OR DENSITY: Not known

SECTION 10: STABILITY AND REACTIVITY

CHEMICAL STABILITY: Stable
CONDITIONS TO AVOID: None known
MATERIALS TO AVOID (INCOMPATIBILITY): None known
HAZARDOUS DECOMPOSITION PRODUCTS: Hydrogen Chloride
HAZARDOUS POLYMERIZATION: Will not occur

SECTION 11: TOXICOLOGICAL INFORMATION

ORAL LD50 (rat): 4200
DERMAL LD50 (rat): 106
Page 4 of 7

Vanson HaloSource, Inc.
Material Safety Data Sheet
Material Name: SeaKlear® Phosphate Remover
Telephone No: 425-881-6464

VHI-MSDS-02.36 REV 05
Date Prepared: 12-19-05

SCU, LD50(MG/KG) (mouse): 2424

IV LD50 (MG/KG) (mouse): 18
SKIN IRRITATION (rabbit): Not available
SKIN SENSITIZATION (guinea pig): Not available
EYE IRRITATION (rabbit): Not available

SECTION 12: ECOLOGICAL INFORMATION
Fish 96-hour LC50
Daphnia 48-hour LC50
Green algae 96-hour EC50
Fish Chronic Value (ChV)
Daphnia ChV
Algae ChV

=Not available
=Not available
=Not available
=Not available
=Not available
=Not available

SECTION 13: DISPOSAL CONSIDERATIONS
If this product as supplied becomes a waste, it does meet the criteria of a hazardous waste as defined under the
Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Please be advised that state and local requirements
for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local
regulations regarding the proper disposal of this material.
NOTE: Chemical additions, processing or otherwise altering this material may make the waste management information
presented in this MSDS incomplete, inaccurate or otherwise inappropriate.

SECTION 14: TRANSPORT INFORMATION

U.S. DEPARTMENT OF TRANSPORTATION (DOT):
DOT Proper Shipping Name:
DOT Hazard Class:
Packing Group:
UN Number:

Not regulated
Not regulated
Not regulated
Not regulated

SECTION 15: REGULATORY INFORMATION

TSCA STATUS: Not listed
Page 5 of 7

Vanson HaloSource, Inc.
Material Safety Data Sheet
Material Name: SeaKlear® Phosphate Remover
Telephone No: 425-881-6464

VHI-MSDS-02.36 REV 05
Date Prepared: 12-19-05

CERCLA REPORTABLE QUANTITY (RQ):
CHEMICAL NAME

RQ

Not applicable

Not applicable

SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (EHS):
CHEMICAL NAME
None

TPQ

RQ

Not applicable

Not applicable

SARA TITLE III SECTION 311/312 HAZARD CATEGORIES: Does this product/material meet the definition of the
following hazard classes according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of SARA
Title III?
ACUTE HEALTH
HAZARD
Yes

CHRONIC HEALTH
HAZARD
No

FIRE HAZARD

REACTIVE HAZARD

No

No

SUDDEN RELEASE
OF PRESSURE
No

SARA TITLE III SECTION 313 TOXIC CHEMICALS INFORMATION:
CHEMICAL NAME
None

CAS NO.

CONCENTRATION (%)

Not applicable

Not applicable

CALIFORNIA PROPOSITION 65: The following chemical(s) is/are known to the state of California to cause cancer or
reproductive toxicity:
CHEMICAL NAME
None

CAS NO.

CONCENTRATION (%)

Not applicable

Not applicable

SECTION 16: OTHER INFORMATION

REVISION INFORMATION:
MSDS sections(s) changed since last revision of document: In an attempt to make Vanson-HaloSource’s MSDSs more
user friendly, as well as to keep current with all applicable regulations, all of the sections in this MSDS have had slight to
significant changes since the last revision.

DISCLAIMER:
****************************************************************************************************************************************
**
The above information is based upon information Vanson-HaloSource Inc. believes to be reliable and is supplied for
informational purposes only. Vanson-HaloSource Inc. disclaims any liability for damage which results from the use of
Page 6 of 7

Vanson HaloSource, Inc.
Material Safety Data Sheet
Material Name: SeaKlear® Phosphate Remover
Telephone No: 425-881-6464

VHI-MSDS-02.36 REV 05
Date Prepared: 12-19-05

the above information and nothing contained therein shall constitute a guarantee, warranty (including fitness for a
particular purpose) or representation with respect to the accuracy or completeness of the data, the product described or
their use for any specific purpose even if that purpose is known to Vanson-HaloSource Inc. The final determination of
the suitability of the information, the manner of use of the information or product and potential infringement is the sole
responsibility of the user.
****************************************************************************************************************************************
**
MSDS PREPARED BY: Jeremy Heath, EH&S Specialist

Page 7 of 7

MATERIAL SAFETY DATA

SHEET

GLB Oxy-Brite

1. Product And Company Identification
Supplier
GLB
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Manufacturer
Advantis Technologies, Inc.
1400 Bluegrass Lakes Parkway
Alpharetta, GA 30004 United States

Telephone Number: (770)521-5999
FAX Number: (770)521-5959
Web Site: www.poolspacare.com

Telephone Number: (770) 521-5999
FAX Number: (770) 521-5959
Web Site: www.poolspacare.com

Supplier Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Manufacturer Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300

Issue Date: 04/16/2007
Product Name: GLB Oxy-Brite
Chemical Name: Potassium Monopersulfate
CAS Number: Not Established
Chemical Family: Peroxygen Salt
Chemical Formula: Proprietary
MSDS Number: 314
2. Composition/Information On Ingredients
Ingredient
Name

CAS
Number

MAGNESIUM CARBONATE

Percent Of
Total Weight

546-93-0

POTASSIUMBISULFATE

7646-93-7

POTASSIUMPEROXYDISULFATE

7727-21-1

POTASSIUMPEROXYMONOSULFATE

10058-23-8

POTASSIUMSULFATE

7778-80-5

SODIUMTETRABORATEPENTAHYDRATE

12179-04-3

Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials
determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as
carcinogens are listed if they comprise 0.1% or more of the composition. Information on proprietary materials is available in
29CFR 1910.1200(i)(1).
EMERGENCY OVERVIEW
This product is a skin and eye corrosive, and a nose and throat irritant.
Hazards Identification (Pictograms)

3. Hazards Identification
Primary Routes(s) Of Entry
Skin Contact

Page 1 of 5

MATERIAL SAFETY DATA

SHEET

GLB Oxy-Brite
3. Hazards Identification - Continued
Eye Hazards
Corrosive to eyes. Eye contact may cause corrosion or ulceration. Severe eye damage may result if not
immediately treated.
Skin Hazards
Corrosive to skin. Skin contact with aqueous solutions or the dry powder upon contact with moisture or perspiration
may cause skin burns or ulceration; temporary body hair loss may occur in contacted areas. Skin contact with the
product may cause allergic skin reactions in sensitive individuals.
Ingestion Hazards
May cause irritation of the throat. Ingestion may cause inflammation and damage to the lining of the stomach,
resulting in bleeding. Ingestion may cause gastritis possibly progressing to necrosis or hemorrhage.
Inhalation Hazards
Inhalation may cause nose bleeds and irritation of the upper respiratory passages with coughing and discomfort.
Signs And Symptoms
Irritant to eyes and skin due to oxidizing properties
First Aid (Pictograms)

4. First Aid Measures
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Call a
physician or a poison control center immediately.
Skin
Wash affected areas with soap and water. Call a physician. Wash clothing before reuse.
Ingestion
DO NOT INDUCE VOMITING. Drink large amounts of water. Call a physician or a poison control center immediately.
Inhalation
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Consult
Physician
Fire Fighting (Pictograms)

5. Fire Fighting Measures
Flash Point: N/A °F
Fire And Explosion Hazards
Improper storage of large masses of this product can trap heat and lead to ignition of combustibles. Grinding or
intensive mixing may cause decomposition with liberation of heat and oxygen; ignition of oxidizable material if
present may occur.
Extinguishing Media
In case of fire, soak (flood) with water.

Page 2 of 5

MATERIAL SAFETY DATA

SHEET

GLB Oxy-Brite
5. Fire Fighting Measures - Continued
Fire Fighting Instructions
Will release oxygen when heated, intensifying a fire. Firefighters should wear self-contained breathing apparatus and
full protective gear.
GRINDING OR INTENSIVE MIXING MAY GENERATE SUFFICIENT HEAT TO FUSE PRODUCT AND CAUSE IGNITION
OF OXIDIZABLE MATERIAL PRESENT.
6. Accidental Release Measures
Clean up spill immediately. Flush spill area with water in compliance with State and Federal Regulations.
Handling & Storage (Pictograms)

7. Handling And Storage
Handling And Storage Precautions
Keep out of reach of children. Store material in a cool and dry place.
Handling Precautions
Avoid breathing dust or vapor. Avoid contact with skin and clothing. Avoid contact with eyes. Wash thoroughly after
handling. Wash clothing after use.
Storage Precautions
Store in a cool dry place. Keep away from heat, sparks, flame, and other sources of ignition (i.e., pilot lights,
electric motors and static electricity).
Work/Hygienic Practices
Use safe chemical handling procedures suitable for the hazards presended by this material.
Protective Clothing (Pictograms)

8. Exposure Controls/Personal Protection
Engineering Controls
Local exhaust acceptable. Special exhaust not required
Eye/Face Protection
Safety glasses with side shields or goggles recommended.
Skin Protection
Chemical-resistant gloves.
Respiratory Protection
The level of respiratory protection needed should be based on the required protection factor after evaluating chemical
exposures using appropriate industrial hygiene monitoring and/or OSHA guidance.
9. Physical And Chemical Properties
Appearance
Blue granules or powder

Page 3 of 5

MATERIAL SAFETY DATA

SHEET

GLB Oxy-Brite
9. Physical And Chemical Properties - Continued
Odor
None
Chemical Type: Mixture
Physical State: Solid
Melting Point: DECOMPOSES °F
Boiling Point: DECOMPOSES °F
Specific Gravity: 1.2
Molecular Weight: PROPRIETARY
Percent Volitales: NIL
Vapor Pressure: NIL
Vapor Density: NOT VOLATILE
Solubility: >25% AT 20C (68F)
Evaporation Rate: NOT VOLATILE
Corrosive, Oxidizer
10. Stability And Reactivity
Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid (Stability)
The mixture of this product with compounds containing halides or active halogens (bromine, chlorine, iodine) can
cause the release of the respective halogen gas, if moisture is present. Avoid these gases (bromine and chlorine)
because they are very irritating to eyes and lungs even at low concentrations. Never mix concentrated product with
dry or concentrated bromine containing chemicals, such as bromates, bromides, or any concentrated bromine pool
chemicals. Mixing this prodcut with dry or concentrated chlorine containing chemicals, such as hypochlorites,
sodium dichloroisocyanurate, sodium triisocyanurate or with sodium chloride, may cause the release of chlorine gas.

Mixing with cyanides can cause release of hydrogen cyanide gas. Mixing with heavy metal salts such as those of
cobalt, nickel, copper, or manganese can cause decomposition with release of oxygen and heat.
Incompatible Materials
Alkalis, Heavy Metals cause evolution of Oxygen gas. Halogens and cyanides can cause release of gases of these
compounds.
Hazardous Decomposition Products
Oxygen
11. Toxicological Information
Acute Studies
This product is a severe skin and eye irritant, but is not a skin sensitizer in animals.
12. Ecological Information
No Data Available...
13. Disposal Considerations
Dispose in accordance with applicable federal, state and local government regulations.
14. Transport Information
Proper Shipping Name
CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.
(Monopersulfate Compound)

Page 4 of 5

MATERIAL SAFETY DATA

SHEET

GLB Oxy-Brite
14. Transport Information - Continued
Proper Shipping Name - Continued
Hazard Class
8, PGII (<=1kg Consumer Commodity ORM-D)
DOT Identification Number
UN3260
DOT (Pictograms)

15. Regulatory Information
SARA Hazard Classes
Acute Health Hazard
Canadian Regulatory Information
Class D, Div 2b - Toxic Material. Skin or Eye Irritant
Class E - Corrosive Material
Class C - Oxidizing Material
WHMIS - Canada (Pictograms)

NFPA

HMIS

0
3

1

HEALTH

3

FLAMMABILITY

0

REACTIVITY

1

PERSONAL

E

PROTECTION

16. Other Information
Revision/Preparer Information
MSDS Preparer: JHW
This MSDS Superceeds A Previous MSDS Dated: 10/13/2003
Disclaimer
Although reasonable care has been taken in the preparation of this document, we extend no warranties
and make no representations as to the accuracy or completeness of the information contained therein,
and assume no responsibility regarding the suitablility of this information for the user's intended purposes
or for the consequences of its use. Each individual should make a determination as to the suitability of
the information for their particular purposes(s).
GLB
Printed Using MSDS Generator™ 2000

Page 5 of 5

Vanson HaloSource, Inc
Material Safety Data Sheet
Material Name: SEA-KLEAR 3-Month Algaecide
Telephone No: 425-881-6464

VHI-MSDS-02-16-REV-2
Date Prepared: 12-23-02

24-HOUR EMERGENCY PHONE: CHEMTREC 800-424-9300
SECTION I – CHEMICAL PRODUCT & COMPANY IDENTIFICATION
Manufacturer's Name:
Corporate Address:
Emergency Phone:
Manufacturer's Phone:
Material Name:
Chemical Name:

Vanson HaloSource, Inc.
th
14716 NE 87 Street, Redmond, WA 98052
800-424-9300 Chemtrec
(425) 881-6464
SEA-KLEAR 3-Month Algaecide
Copper (11) Triethanolamine

SECTION II – COMPOSITION, INFORMATION ON INGREDIENTS

CAS NO.

INGREDIENT

EXPOSURE LIMITS

Copper (11) Triethanolamine

OSHA PEL: N/A OSHA STEL: N/A ACGIH TLV: N/A

SECTION III – HAZARDS IDENTIFICATION

PRINCIPAL HEALTH HAZARDS, INCLUDING SIGNIFICANT ROUTES, EFFECTS, AND SYMPTOMS OF
OVEREXPOSURE AND MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE MAY BE:
EYE: Possible eye irritant.
SKIN: Not known to be a skin irritant.
INHALATION: NA
INGESTION: Low degree of toxicity by ingestion.
CARCINOGENICITY: Not listed by National Toxicology Program (NTP) OSHA, or International Agency for Research on
Cancer (IARC)

SECTION IV - FIRST AID

EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Contact a physician.
SKIN: If skin contact occurs, wash thoroughly with soap and water.
INHALATION: Use approved respirator for mists.
INGESTION: Contact a physician.

SECTION V - FIRE FIGHTING MEASURES

Page 1 of 6

Vanson HaloSource, Inc
Material Safety Data Sheet
Material Name: SEA-KLEAR 3-Month Algaecide
Telephone No: 425-881-6464

VHI-MSDS-02-16-REV-2
Date Prepared: 12-23-02

HAZARDOUS COMBUSTION PRODUCTS: NA
EXTINGUISHING MEDIA: Use water, dry chemicals, carbon dioxide, sand or foam. Use extinguishing media appropriate
for surrounding fire.
FIREFIGHTING INSTRUCTIONS: Do not enter confined fire space without full bunker gear (helmet with face shield,
bunker coat, gloves and rubber boots), including a positive pressure NIOSH approved self-contained breathing
apparatus. Water may be used to keep fire-exposed containers cool until fire is out.
FLASH POINT: Not applicable.

SECTION VI – ACCIDENTAL RELEASE MEASURES

SPILL: Vacuum collect in containers for disposal. Flush area with water.
DISPOSAL INFORMATION: Contaminated material or waste should be placed in suitable receptacles and removed to
chemical waste storage area for disposal in accordance with relevant federal, state, and local regulations.
DISPOSAL METHODS: In accordance with local, State and federal regulations. Flush residue with water.

SECTION VII - HANDLING & STORAGE

HANDLING & STORAGE PRECAUTIONS: Store below 40 °C/104° F in cool dry area in well closed containers.
Exercise normal handling precautions for liquids. Protect from freezing. Keep away from metals.

SECTION VIII - EXPOSURE CONTROLS/ PERSONAL PROTECTION

PERSONAL PROTECTIVE EQUIPMENT (PPE): Good hygiene practices should be strictly followed. Before eating,
drinking or smoking, wash face and hands thoroughly. For operations where eye or face contact may occur, wear
chemical goggles or face shield. Showers and eyewash facilities should be accessible.
EYE PROTECTION: eye protection recommended.
SKIN PROTECTION: gloves.
PROTECTIVE CLOTHING: NA
PROTECTIVE FOOTWEAR: NA
RESPIRATORY PROTECTION: NA
.
VENTILATION REQUIREMENTS: Generally adequate

Page 2 of 6

Vanson HaloSource, Inc
Material Safety Data Sheet
Material Name: SEA-KLEAR 3-Month Algaecide
Telephone No: 425-881-6464

VHI-MSDS-02-16-REV-2
Date Prepared: 12-23-02

SECTION IX - PHYSICAL & CHEMICAL PROPERTIES

PHYSICAL FORM: Odorless Blue liquid.
BOILING POINT: Same as water.
MELTING POINT: NA
pH: unknown
SOLUBILITY IN WATER: Miscible in water
SPECIFIC GRAVITY: 1.18-1.21
.

SECTION X - STABILITY & REACTIVITY DATA

CHEMICAL STABILITY: Stable.
HAZARDOUS POLYMERIZATION: Will not occur.
INCOMPATIBLES: NA
DECOMPOSITION PRODUCTS: NA

SECTION XI - TOXICOLOGICAL INFORMATION

ORAL Rat LD50 (MG/KG): 4,500 mg/kg

IV-Mouse, LD50(MG/KG): NA
DERMAL LD50 (rabbit): 8,000 mg/kg
EYE IRRITATION (rabbit): NA
SKIN IRRITATION (rabbit): NA

SECTION XII - ECOLOGICAL INFORMATION
Fish 96-hour LC50
Daphnia 48-hour LC50
Green algae 96-hour EC50

=
=
=

5.4 ppm @ 96 hours
NA
NA
Page 3 of 6

Vanson HaloSource, Inc
Material Safety Data Sheet
Material Name: SEA-KLEAR 3-Month Algaecide
Telephone No: 425-881-6464
Fish Chronic Value (ChV)
Daphnia ChV
Algae ChV

=
=
=

VHI-MSDS-02-16-REV-2
Date Prepared: 12-23-02

NA
NA
NA

GENERAL:

SECTION XIII - DISPOSAL CONSIDERATION

WASTE DISPOSAL METHOD: Dispose of in accordance with all applicable federal, local and State environmental
regulations.

SECTION XIV - TRANSPORTATION INFORMATION

DOT Proper Shipping Name:
DOT Hazard Class:
Packing Group:
UN Number:
Product RQ (lbs.):
DOT Label:
DOT Placard:
Freight Class (package):

None

Not regulated as a hazardous material
Not determined
Not determined
No limit
Miscellaneous
Not required
Not determined

SECTION XV - REGULATORY INFORMATION

MATERIAL IS REPORTED IN EPA TSCA INVENTORY LIST?: No
MATERIAL IS LISTED AS A CARCINOGEN/POTENTIAL CARCINOGEN IN FOLLOWING?: No
NTP ANNUAL REPORT: No

IARC GROUP I OR II: No

OSHA 29CFR PART 1910 SUBPART Z: No

DOES PRODUCT CONTAIN A TOXIC CHEMICAL SUBJECT TO SARA TITLE III SECTION 313 REPORTING: No
SARA TITLE III SECTION 311/312 CLASSIFICATIONS: None

SECTION XVI – OTHER INFORMATION
The above information is based upon information Vanson-HaloSource, Inc. believes to be reliable and is supplied for
informational purposes only. Vanson-HaloSource, Inc. disclaims any liability for damage which results from the use of the
above information and nothing contained therein shall constitute a guarantee, warranty (including fitness for a particular
purpose) or representation with respect to the accuracy or completeness of the data, the product described or their use
Page 4 of 6

Vanson HaloSource, Inc
Material Safety Data Sheet
Material Name: SEA-KLEAR 3-Month Algaecide
Telephone No: 425-881-6464

VHI-MSDS-02-16-REV-2
Date Prepared: 12-23-02

for any specific purpose even if that purpose is known to Vanson-HaloSource, Inc. The final determination of the
suitability of the information, the manner of use of the information or product and potential infringement is the sole
responsibility of the user.

Page 5 of 6

Vanson HaloSource, Inc.
Material Safety Data Sheet
Material Name: SeaKlear® Phosphate Remover
Telephone No: 425-881-6464

VHI-MSDS-02.36 REV 05
Date Prepared: 12-19-05

24-HOUR EMERGENCY PHONE: CHEMTREC 800-424-9300
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
Manufacturer's Name:
Corporate Address:
Manufacturer's Telephone:
Emergency Telephone:
Material/Trade/Product Name:
Synonyms:
Chemical Name:
CAS No.:
Product Use:

Vanson HaloSource, Inc.
14716 NE 87th Street, Redmond, WA 98052
(425) 881-6464 (Monday-Friday, 8AM-5PM PDT)
800-424-9300 Chemtrec (24 Hours)
Phosphate Remover
None
Lanthanum Chloride, 7 hydrate (99.9%)
Not Applicable
Removes phosphates from water

SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS

CAS NO.

20211-76-1

HAZARDOUS INGREDIENT (S)

Lanthanum Chloride Hydrate

%

OSHA
HAZARDOUS
?

99.99

YES

NOTE: See Section 8 for permissible exposure limits.

SECTION 3: HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
Clear to slightly yellow liquid.
Can cause irritation to exposed areas of body. Severity of injury depends largely on duration of exposure.
Immediate action is necessary to limit severity of injury.
Hydrogen chloride will be produced from decomposition.
POTENTIAL HEALTH EFFECTS
EYE: May cause irritation.
SKIN: Possible skin irritant.
INHALATION: Should not be harmful if inhaled.
INGESTION: Possible irritant if swallowed.
Page 1 of 7

Vanson HaloSource, Inc.
Material Safety Data Sheet
Material Name: SeaKlear® Phosphate Remover
Telephone No: 425-881-6464

VHI-MSDS-02.36 REV 05
Date Prepared: 12-19-05

CHRONIC EXPOSURE/CARCINOGENICITY: This substance not listed as a potential carcinogen by IARC.
SIGNS AND SYMPTOMS OF OVEREXPOSURE: Eye and/or skin irritation.
AGGRAVATION OF PRE-EXISTING CONDITIONS: None known.

POTENTIAL ENVIRONMENTAL EFFECTS: None known.

SECTION 4: FIRST AID MEASURES

FIRST AID PROCEDURES
EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes, lifting eyelids occasionally.
Get medical attention at once.
SKIN CONTACT: Remove contaminated clothing and immediately wash exposed area for 15 minutes. Get
medical attention if necessary.
INHALATION: Move to fresh air. If breathing has stopped administer artificial respiration. Get medical
attention immediately.
INGESTION: Give large amounts of water. Do not induce vomiting. Get medical attention immediately.
NOTE TO PHYSICIANS: None

SECTION 5: FIRE FIGHTING MEASURES

FLASH POINT: Not applicable
UPPER FLAMMABLE LIMIT: Not applicable
FLAMMABLITY CLASS (OSHA): Not applicable

AUTOIGNITION TEMPERATURE: Not applicable
LOWER FLAMMABLE LIMIT: Not applicable
FLAME PROPAGATION/BURNING RATE: Not applicable

UNIQUE FIRE PROPERTIES: HCI is produced.
HAZARDOUS COMBUSTION PRODUCTS: HCI is produced.
EXTINGUISHING MEDIA: Use water, dry chemicals, carbon dioxide, sand or foam. Use extinguishing media
appropriate for surrounding fire.
PROTECTION OF FIREFIGHTERS: Do not enter confined fire space without full bunker gear (helmet with face shield,
bunker coat, gloves and rubber boots), including a positive pressure NIOSH approved self-contained breathing
apparatus. Water may be used to keep fire-exposed containers cool until fire is out.

Page 2 of 7

Vanson HaloSource, Inc.
Material Safety Data Sheet
Material Name: SeaKlear® Phosphate Remover
Telephone No: 425-881-6464

VHI-MSDS-02.36 REV 05
Date Prepared: 12-19-05

SECTION 6: ACCIDENTAL RELEASE MEASURES

PERSONAL PROTECTIVE EQUIPMENT: See Section 8 (Personal Protective Equipment).
ENVIRONMENTAL PRECAUTIONS: None
METHODS FOR CLEANING UP: Contain large spills and pump to recover. Small spills can be mopped up and
recovered.

SECTION 7: HANDLING AND STORAGE

SAFE HANDLING RECOMMENDATIONS
VENTILATION: Use general ventilation
FIRE PREVENTION: Not flammable
SPECIAL HANDLING REQUIREMENTS: Use appropriate PPE
SAFE STORAGE RECOMMENDATIONS
CONTAINMENT: Secondary containment is recommended.
STORAGE ROOM RECOMMENDATIONS: Store in cool, dry place. Keep container closed when not in use;
keep out of the reach of children.
INCOMPATIBLE MATERIALS: None known.
STORAGE CONDITIONS: Store in cool, dry place. Keep container closed when not in use; keep out of the
reach of children.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS: General ventilation
PERSONAL PROTECTIVE EQUIPMENT (PPE)
EYE/FACE PROTECTION: Safety glasses are recommended under normal conditions.
SKIN PROTECTION: Avoid contact with skin.

Page 3 of 7

Vanson HaloSource, Inc.
Material Safety Data Sheet
Material Name: SeaKlear® Phosphate Remover
Telephone No: 425-881-6464

VHI-MSDS-02.36 REV 05
Date Prepared: 12-19-05

HAND PROTECTION: Chemical resistant gloves are recommended to minimize potential irritation from
handling.
RESPIRATORY PROTECTION: None required where adequate ventilation conditions exist.
GOOD HYGEIENE/WORK PRACTICES: Always follow good hygiene/work practices by avoiding vapors or
mists and contact with eyes and skin. Thoroughly wash hands after handling and before eating or drinking.
Always wear the appropriate PPE when repairing or performing maintenance on contaminated equipment.
EXPOSURE GUIDELINES

INGREDIENT
CAS NO.
Not applicable

OSHA
TWA
Not
applicable

PERMISSIBLE EXPOSURE LIMITS
WISHA

STEL
Not
applicable

TWA
Not
applicable

STEL
Not
applicable

ACGIH (TLV)
TWA
Not
applicable

STEL
Not
applicable

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

COLOR: Clear to slightly yellow
PHYSICAL FORM: Liquid
pH: Not applicable
VAPOR DENSITY: 4.10
MELTING POINT: Not known
SOLUBILITY IN WATER: Appreciable (more than 10%)

SHAPE: Liquid
ODOR: None
VAPOR PRESSURE: Not known
BOILING POINT: Not known
FREEZING POINT: Not known
SPECIFIC GRAVITY OR DENSITY: Not known

SECTION 10: STABILITY AND REACTIVITY

CHEMICAL STABILITY: Stable
CONDITIONS TO AVOID: None known
MATERIALS TO AVOID (INCOMPATIBILITY): None known
HAZARDOUS DECOMPOSITION PRODUCTS: Hydrogen Chloride
HAZARDOUS POLYMERIZATION: Will not occur

SECTION 11: TOXICOLOGICAL INFORMATION

ORAL LD50 (rat): 4200
DERMAL LD50 (rat): 106
Page 4 of 7

Vanson HaloSource, Inc.
Material Safety Data Sheet
Material Name: SeaKlear® Phosphate Remover
Telephone No: 425-881-6464

VHI-MSDS-02.36 REV 05
Date Prepared: 12-19-05

SCU, LD50(MG/KG) (mouse): 2424

IV LD50 (MG/KG) (mouse): 18
SKIN IRRITATION (rabbit): Not available
SKIN SENSITIZATION (guinea pig): Not available
EYE IRRITATION (rabbit): Not available

SECTION 12: ECOLOGICAL INFORMATION
Fish 96-hour LC50
Daphnia 48-hour LC50
Green algae 96-hour EC50
Fish Chronic Value (ChV)
Daphnia ChV
Algae ChV

=Not available
=Not available
=Not available
=Not available
=Not available
=Not available

SECTION 13: DISPOSAL CONSIDERATIONS
If this product as supplied becomes a waste, it does meet the criteria of a hazardous waste as defined under the
Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Please be advised that state and local requirements
for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local
regulations regarding the proper disposal of this material.
NOTE: Chemical additions, processing or otherwise altering this material may make the waste management information
presented in this MSDS incomplete, inaccurate or otherwise inappropriate.

SECTION 14: TRANSPORT INFORMATION

U.S. DEPARTMENT OF TRANSPORTATION (DOT):
DOT Proper Shipping Name:
DOT Hazard Class:
Packing Group:
UN Number:

Not regulated
Not regulated
Not regulated
Not regulated

SECTION 15: REGULATORY INFORMATION

TSCA STATUS: Not listed
Page 5 of 7

Vanson HaloSource, Inc.
Material Safety Data Sheet
Material Name: SeaKlear® Phosphate Remover
Telephone No: 425-881-6464

VHI-MSDS-02.36 REV 05
Date Prepared: 12-19-05

CERCLA REPORTABLE QUANTITY (RQ):
CHEMICAL NAME

RQ

Not applicable

Not applicable

SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (EHS):
CHEMICAL NAME
None

TPQ

RQ

Not applicable

Not applicable

SARA TITLE III SECTION 311/312 HAZARD CATEGORIES: Does this product/material meet the definition of the
following hazard classes according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of SARA
Title III?
ACUTE HEALTH
HAZARD
Yes

CHRONIC HEALTH
HAZARD
No

FIRE HAZARD

REACTIVE HAZARD

No

No

SUDDEN RELEASE
OF PRESSURE
No

SARA TITLE III SECTION 313 TOXIC CHEMICALS INFORMATION:
CHEMICAL NAME
None

CAS NO.

CONCENTRATION (%)

Not applicable

Not applicable

CALIFORNIA PROPOSITION 65: The following chemical(s) is/are known to the state of California to cause cancer or
reproductive toxicity:
CHEMICAL NAME
None

CAS NO.

CONCENTRATION (%)

Not applicable

Not applicable

SECTION 16: OTHER INFORMATION

REVISION INFORMATION:
MSDS sections(s) changed since last revision of document: In an attempt to make Vanson-HaloSource’s MSDSs more
user friendly, as well as to keep current with all applicable regulations, all of the sections in this MSDS have had slight to
significant changes since the last revision.

DISCLAIMER:
****************************************************************************************************************************************
**
The above information is based upon information Vanson-HaloSource Inc. believes to be reliable and is supplied for
informational purposes only. Vanson-HaloSource Inc. disclaims any liability for damage which results from the use of
Page 6 of 7

Vanson HaloSource, Inc.
Material Safety Data Sheet
Material Name: SeaKlear® Phosphate Remover
Telephone No: 425-881-6464

VHI-MSDS-02.36 REV 05
Date Prepared: 12-19-05

the above information and nothing contained therein shall constitute a guarantee, warranty (including fitness for a
particular purpose) or representation with respect to the accuracy or completeness of the data, the product described or
their use for any specific purpose even if that purpose is known to Vanson-HaloSource Inc. The final determination of
the suitability of the information, the manner of use of the information or product and potential infringement is the sole
responsibility of the user.
****************************************************************************************************************************************
**
MSDS PREPARED BY: Jeremy Heath, EH&S Specialist

Page 7 of 7

Vanson HaloSource, Inc
Material Safety Data Sheet
Material Name: SeaKlear® Natural Clarifier for Pools
Telephone No: 425-881-6464

VHI-MSDS-02.13 Rev 03
Date Prepared: 04-28-05

24-HOUR EMERGENCY PHONE: CHEMTREC 800-424-9300
SECTION I – CHEMICAL PRODUCT & COMPANY IDENTIFICATION
Manufacturer's Name:
Corporate Address:
Emergency Phone:
Manufacturer's Phone:
Material Name:
Chemical Name:

Vanson HaloSource, Inc.
14716 NE 87th Street, Redmond, WA 98052
800-424-9300 Chemtrec
(425) 881-6464
SeaKlear Natural Clarifier
Chitosan acetate

SECTION II – COMPOSITION, INFORMATION ON INGREDIENTS

CAS NO.
9012-76-4
64-19-7

INGREDIENT

EXPOSURE LIMITS

Chitosan
Acetic Acid
Water

NA

SECTION III – HAZARDS IDENTIFICATION
PRINCIPAL HEALTH HAZARDS, INCLUDING SIGNIFICANT ROUTES, EFFECTS, AND SYMPTOMS OF
OVEREXPOSURE AND MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE MAY BE:
EYE: May be mildly irritating to eyes.
SKIN: Not hazardous to skin.
INHALATION: See first aid section below.
INGESTION: Not likely to be hazardous by ingestion.
CARCINOGENICITY: Not listed by National Toxicology Program (NTP) OSHA, or International Agency for Research on
Cancer (IARC)

SECTION IV - FIRST AID

EYES: Remove contact lenses (if applicable), flush with water for 15 minutes. Call a physician.
SKIN: Cleansing the skin after exposure is advisable.
INHALATION: If large amounts of fumes are inhaled, remove to fresh air and consult a physician.
INGESTION: Consult a physician if necessary.

Page 1 of 5

Vanson HaloSource, Inc
Material Safety Data Sheet
Material Name: SeaKlear® Natural Clarifier for Pools
Telephone No: 425-881-6464

VHI-MSDS-02.13 Rev 03
Date Prepared: 04-28-05

SECTION V - FIRE FIGHTING MEASURES

HAZARDOUS COMBUSTION PRODUCTS: NA
EXTINGUISHING MEDIA: Does not burn. Use water, dry chemicals, carbon dioxide, sand or foam. Use extinguishing
media appropriate for surrounding fire.
FIREFIGHTING INSTRUCTIONS: Do not enter confined fire space without full bunker gear (helmet with face shield,
bunker coat, gloves and rubber boots), including a positive pressure NIOSH approved self-contained breathing
apparatus. Water may be used to keep fire-exposed containers cool until fire is out.
FLASH POINT: NA

SECTION VI – ACCIDENTAL RELEASE MEASURES

SPILL: Wear suitable protective clothing. Dilute with water and hose down.
DISPOSAL INFORMATION: Material is 100% biodegradable, is nontoxic and can be disposed of in any approved
manner. Treatment, storage, transportation and disposal must be in accordance with applicable Federal
State/Provincial and local regulations.
DISPOSAL METHODS: Dilute with water and hose down.

SECTION VII - HANDLING & STORAGE

HANDLING & STORAGE PRECAUTIONS: 10-50°C recommended (will freeze @ ~3°C). Shelf life is indefinite but
viscosity will decrease over time. The container should be kept covered to prevent contamination.

SECTION VIII - EXPOSURE CONTROLS/ PERSONAL PROTECTION

PERSONAL PROTECTIVE EQUIPMENT (PPE): Good hygiene practices should be strictly followed. Before eating,
drinking or smoking, wash face and hands thoroughly. Emergency showers and eyewash facilities should be
accessible.
EYE PROTECTION: Safety glasses recommended.
SKIN PROTECTION: Rubber gloves recommended.
PROTECTIVE CLOTHING: NA

Page 2 of 5

Vanson HaloSource, Inc
Material Safety Data Sheet
Material Name: SeaKlear® Natural Clarifier for Pools
Telephone No: 425-881-6464

VHI-MSDS-02.13 Rev 03
Date Prepared: 04-28-05

PROTECTIVE FOOTWEAR: NA
RESPIRATORY PROTECTION: NA
.
VENTILATION REQUIREMENTS: Generally adequate

SECTION IX - PHYSICAL & CHEMICAL PROPERTIES

PHYSICAL FORM: Clear to pale yellow viscous liquid with a pungent vinegar odor.
BOILING POINT: 211°F
MELTING POINT: NA
pH: 3.0-4.5
SOLUBILITY IN WATER: Soluble.
SPECIFIC GRAVITY: 1.0-1.1 g/mL

SECTION X - STABILITY & REACTIVITY DATA

CHEMICAL STABILITY: Stable.
HAZARDOUS POLYMERIZATION: Will not occur.
INCOMPATIBLES: Strong oxidizing material and strong bases.
DECOMPOSITION PRODUCTS: Decomposition will not occur.
Material is bio-degradable.

SECTION XI - TOXICOLOGICAL INFORMATION

ORAL Rat LD50 (MG/KG): NA
NA
Ipr Rat, LD50(MG/KG):
SCU Mouse, LD50(MG/KG): NA

IV-Mouse, LD50(MG/KG): NA
DERMAL LD50 (rabbit): NA
EYE IRRITATION (rabbit): NA
SKIN IRRITATION (rabbit): NA

Page 3 of 5

Vanson HaloSource, Inc
Material Safety Data Sheet
Material Name: SeaKlear® Natural Clarifier for Pools
Telephone No: 425-881-6464

VHI-MSDS-02.13 Rev 03
Date Prepared: 04-28-05

SECTION XII - ECOLOGICAL INFORMATION
Fish 96-hour LC50
Daphnia 48-hour LC50
Green algae 96-hour EC50
Fish Chronic Value (ChV)
Daphnia ChV
Algae ChV

=
=
=
=
=
=

NA
NA
NA
NA
NA
NA

SECTION XIII - DISPOSAL CONSIDERATION

WASTE DISPOSAL METHOD: Dispose of in accordance with all applicable federal, local and State environmental
regulations. Material is 100% biodegradable, is nontoxic and can be disposed of in any approved manner.

SECTION XIV - TRANSPORTATION INFORMATION

DOT Proper Shipping Name:
DOT Hazard Class:
Packing Group:
UN Number:
Product RQ (lbs.):
DOT Label:
DOT Placard:

Chemicals, N.O.S. (non-regulated) (Domestic & International)

Not regulated as a hazardous material
NA
NA
NA
NA
NA

SECTION XV - REGULATORY INFORMATION

MATERIAL IS REPORTED IN EPA TSCA INVENTORY LIST?: No
MATERIAL IS LISTED AS A CARCINOGEN/POTENTIAL CARCINOGEN IN FOLLOWING?: No
NTP ANNUAL REPORT: No

IARC GROUP I OR II: No

OSHA 29CFR PART 1910 SUBPART Z: No

DOES PRODUCT CONTAIN A TOXIC CHEMICAL SUBJECT TO SARA TITLE III SECTION 313 REPORTING: No
SARA TITLE III SECTION 311/312 CLASSIFICATIONS: None

Page 4 of 5

Vanson HaloSource, Inc
Material Safety Data Sheet
Material Name: SeaKlear® Natural Clarifier for Pools
Telephone No: 425-881-6464

VHI-MSDS-02.13 Rev 03
Date Prepared: 04-28-05

SECTION XVI – OTHER INFORMATION
The above information is based upon information Vanson-HaloSource, Inc. believes to be reliable and is supplied for
informational purposes only. Vanson-HaloSource, Inc. disclaims any liability for damage which results from the use of
the above information and nothing contained therein shall constitute a guarantee, warranty (including fitness for a
particular purpose) or representation with respect to the accuracy or completeness of the data, the product described or
their use for any specific purpose even if that purpose is known to Vanson-HaloSource, Inc. The final determination of
the suitability of the information, the manner of use of the information or product and potential infringement is the sole
responsibility of the user.

Page 5 of 5

The MSDS format adheres to the standards and regulatory requirements
of the United States and may not meet regulatory requirements
in other countries.
DuPont
Material Safety Data Sheet

Page

1

---------------------------------------------------------------------DuPont(tm) Pool Care Metal Remover
6503CR
Revised 8-DEC-2005
------------------------------------------------------------------------------------------------------------------------------------------CHEMICAL PRODUCT/COMPANY IDENTIFICATION
---------------------------------------------------------------------Company Identification
MANUFACTURER/DISTRIBUTOR
DuPont Chemical Solutions Enterprise
1007 Market Street
Wilmington, DE 19898
PHONE NUMBERS
Product Information
Transport Emergency
Medical Emergency

: 1-800-441-7515 (outside the U.S.
302-774-1000)
: CHEMTREC 1-800-424-9300(outside U.S.
703-527-3887)
: 1-800-441-3637 (outside the U.S.
302-774-1000)

---------------------------------------------------------------------COMPOSITION/INFORMATION ON INGREDIENTS
---------------------------------------------------------------------Components
Material
Sodium Citrate

CAS Number
68-04-2

%

---------------------------------------------------------------------HAZARDS IDENTIFICATION
---------------------------------------------------------------------Potential Health Effects
Eye Contact:
May cause eye irritation.
Skin Contact:
May cause skin irritation.
Ingestion:
May cause irritation of the gastrointestinal tract, nausea,
vomiting and diarrhea.
Inhalation:
May be harmful if inhaled.

6503CR

DuPont
Material Safety Data Sheet

Page

2

(HAZARDS IDENTIFICATION - Continued)
Carcinogenicity Information
None of the components present in this material at concentrations
equal to or greater than 0.1% are listed by IARC, NTP, OSHA or ACGIH
as a carcinogen.
---------------------------------------------------------------------FIRST AID MEASURES
---------------------------------------------------------------------First Aid
INHALATION
If inhaled, remove to fresh air. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen.
Call a physician.
SKIN CONTACT
Flush skin with water after contact.
before reuse.

Wash contaminated clothing

EYE CONTACT
In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes. Call a physician.
INGESTION
If swallowed, do not induce vomiting. Immediately give 2 glasses
of water. Never give anything by mouth to an unconscious person.
Call a physician.
---------------------------------------------------------------------FIRE FIGHTING MEASURES
---------------------------------------------------------------------Flammable Properties
Not a fire or explosion hazard.
Extinguishing Media
Use media appropriate for surrounding material.
Fire Fighting Instructions
Evacuate personnel to a safe area. Wear self-contained breathing
apparatus (SCBA) and full protective equipment.

6503CR

DuPont
Material Safety Data Sheet

Page

3

---------------------------------------------------------------------ACCIDENTAL RELEASE MEASURES
---------------------------------------------------------------------Safeguards (Personnel)
NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL)
sections before proceeding with clean-up. Use appropriate
PERSONAL PROTECTIVE EQUIPMENT during clean-up.
Wear self-contained breathing apparatus (SCBA) and full protective
gear.
Spill Clean Up
Flush to sewer.
---------------------------------------------------------------------HANDLING AND STORAGE
---------------------------------------------------------------------Handling (Personnel)
Avoid inhalation. Avoid contact with eyes, skin or clothing.
Wash thoroughly after handling. Wash clothing after use.
Handling (Physical Aspects)
Keep container tightly closed.
Storage
Store in a cool, dry place.
---------------------------------------------------------------------EXPOSURE CONTROLS/PERSONAL PROTECTION
---------------------------------------------------------------------Engineering Controls
Use only with adequate ventilation.
Personal Protective Equipment
EYE/FACE PROTECTION
Wear coverall chemical splash goggles. Additionally, wear a face
shield where the possibility exists for face contact due to
splashing or spraying of material.
RESPIRATORS Wear NIOSH approved respiratory protection as
appropriate.
PROTECTIVE CLOTHING
Where there is potential for skin contact have available and wear
as appropriate impervious gloves, apron, pants, jacket, hood and
boots.

6503CR

DuPont
Material Safety Data Sheet

Page

4

(EXPOSURE CONTROLS/PERSONAL PROTECTION - Continued)
Exposure Guidelines
Exposure Limits
DuPont(tm) Pool Care Metal Remover
PEL
(OSHA)
: None Established
TLV
(ACGIH)
: None Established
---------------------------------------------------------------------PHYSICAL AND CHEMICAL PROPERTIES
---------------------------------------------------------------------Physical Data
Boiling Point
Solubility in Water
Odor
Color
Specific Gravity
Form

:
:
:
:
:
:

>1500 C (>2732 F)
Soluble
None.
Clear.
1 g/mL
Liquid.

---------------------------------------------------------------------STABILITY AND REACTIVITY
---------------------------------------------------------------------Chemical Stability
Stable.
Incompatibility with Other Materials
None reasonably foreseeable.
Decomposition
Hazardous decomposition products:
POx.

toxic fumes of Na2O and

Polymerization
Polymerization will not occur.
---------------------------------------------------------------------TOXICOLOGICAL INFORMATION
---------------------------------------------------------------------Animal Data
Sodium Citrate:
Oral LD50 mg/kg (rat):

1546 mg/kg

6503CR

DuPont
Material Safety Data Sheet

Page

5

---------------------------------------------------------------------DISPOSAL CONSIDERATIONS
---------------------------------------------------------------------Waste Disposal
Treatment, storage, transportation, and disposal must be in
accordance with applicable Federal, State/Provincial, and Local
regulations.
---------------------------------------------------------------------TRANSPORTATION INFORMATION
---------------------------------------------------------------------Shipping Information
Not Regulated as a hazardous material by DOT, IMO, or IATA.
---------------------------------------------------------------------REGULATORY INFORMATION
---------------------------------------------------------------------U.S. Federal Regulations
TITLE III HAZARD CLASSIFICATIONS SECTIONS 311, 312
Acute
Chronic
Fire
Reactivity
Pressure

:
:
:
:
:

Yes
No
No
No
No

---------------------------------------------------------------------OTHER INFORMATION
---------------------------------------------------------------------NFPA, NPCA-HMIS
NPCA-HMIS Rating
Health
Flammability
Reactivity

: 1
: 0
: 0

Personal Protection rating to be supplied by user depending on use
conditions.
---------------------------------------------------------------------The data in this Material Safety Data Sheet relates only to the
specific material designated herein and does not relate to use in
combination with any other material or in any process.
Responsible for MSDS : MSDS Coordinator
>
: DuPont Chemical Solutions Enterprise
Address
: Wilmington, DE 19898
Telephone
: (800) 441-7515
This information is based upon technical information believed to be
reliable. It is subject to revision as additional knowledge and
experience is gained.
End of MSDS

Material Safety Data Sheet
POLY-BRITE

Section 1. Chemical product and company identification
: POLY-BRITE
: Bottle wash additive
: Ecolab Food and Beverage
5105 Tomken Road
Mississauga ON L4W 2X5
1-800-352-5326
990283-01
:
: 25-January-2006
EMERGENCY HEALTH INFORMATION: 1-800-328-0026
Outside United States and Canada CALL 1-651-222-5352 (in USA)

Trade name
Product use
Supplier

Code
Date of issue

Section 2. Composition, information on ingredients
Name
polyphosphoric acids, sodium salts
triphosphoric acid, pentasodium salt
disodium metasilicate
sodium phosphate, tribasic

CAS number% by weight
68915-31-1
5- 10
7758-29-4
3-7
6834-92-0
3-7
7601-54-9
1-5

Section 3. Hazards identification
Physical state
Emergency overview

: Liquid. (Liquid.)
: DANGER!
CAUSES EYE AND SKIN BURNS.
CAUSES SEVERE RESPIRATORY TRACT IRRITATION.
HARMFUL IF SWALLOWED.
Do not ingest. Do not get in eyes, on skin or clothing. Avoid breathing vapour or
mist. Keep container closed. Use only with adequate ventilation. Wash thoroughly
after handling.
: Skin contact, Eye contact, Inhalation, Ingestion

Routes of entry
Potential acute health effects
Eyes
:
Skin
:
Inhalation
:
:
Ingestion

Corrosive to eyes.
Corrosive to the skin.

Severely irritating to the respiratory system.
Harmful if swallowed. Causes burns to mouth, throat and stomach.
See toxicological information (section 11)

Section 4. First-aid measures
Eye contact
Skin Contact
Inhalation
Ingestion

: In case of contact, immediately flush eyes with cool running water. Remove contact lenses and
continue flushing with plenty of water for at least 15 minutes. Get medical attention
immediately.
: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes
thoroughly before reuse. Get medical attention immediately.
: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention immediately.
: Rinse mouth; then drink one or two large glasses of water. Do not induce vomiting. Never give
anything by mouth to an unconscious person. Obtain medical attention immediately.

Page: 2/4

POLY-BRITE

Section 5. Fire-fighting measures
Auto-ignition temperature
Flash point
Flammable limits
Upper:
Lower:
Products of combustion
Fire-fighting media and
instructions

: Not available.
: > 100°C
Not available.
Not available.
: Not available.
: Use an extinguishing agent suitable for the surrounding fire.

Dyke liquid for later disposal.
No specific hazard.
Special protective equipment
: Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
for fire-fighters
mode.
Risk of explosion of the product in the presence of mechanical impact: Not available.
Risk of explosion of the product in the presence of static discharge: Not available.

Section 6. Accidental release measures
Personal
Precautions
Environmental
precautions
Methods for
cleaning up

: Ventilate area of leak or spill. Do not touch damaged containers or spilled material unless
wearing appropriate protective equipment (Section 8). Stop leak if without risk. Do not allow to
enter drains or watercourses.
: Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
: If emergency personnel are unavailable, contain spilt material. For small spills, add absorbent
(soil may be used in the absence of other suitable materials), scoop up material and place in a
sealable, liquid-proof container for disposal. For large spills, dyke spilt material or otherwise
contain material to ensure runoff does not reach a waterway. Place spilt material in an
appropriate container for disposal.

Section 7. Handling and storage
Handling
Storage

: Do not ingest. Do not get in eyes, on skin or on clothing. Keep container closed. Use only with
adequate ventilation. Avoid breathing vapour or mist. Wash thoroughly after handling.
: Keep out of the reach of children. Keep container tightly closed. Keep container in a cool, wellventilated area.
Store between 40 and 0°C

Section 8. Exposure controls, personal protection
: Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of
vapours below their respective occupational exposure limits. Provide eyewash and safety
shower in area if contact or splash hazard exists.
Personal protection
Eyes
: Use chemical splash goggles. For continued or severe exposure wear a face shield over the
goggles.
Use
chemical-resistant, impervious gloves.
Hands
:
Skin
: Use synthetic apron, other protective equipment as necessary to prevent skin contact.
Respiratory
: Wear appropriate respirator when ventilation is inadequate and occupational exposure limits
are exceeded.
Consult local authorities for acceptable exposure limits.
Engineering
controls

Page: 3/4

POLY-BRITE

Section 9. Physical and chemical properties
Physical state
Colour
Odour
pH
Boiling/condensation point
Melting/freezing point
Specific gravity
Vapour pressure
Vapour density
Odour threshold
Evaporation rate
LogKow

:
:
:
:
:
:
:
:
:
:
:
:

Liquid. (Liquid.)
Clear.
Faint odour.
12.98 (100%)
Not available.
Not available.
1.18 (Water = 1)
Not applicable.
Not available.
Not available.
Not available.
Not available.

Section 10. Stability and reactivity
: The product is stable.
: Not available.
: Highly reactive with acids.
Slightly reactive to reactive with metals.
Incompatibility with various : Not available.
substances
Hazardous Decomposition : Not available.
Products
Stability
Conditions of instability
Reactivity

Section 11. Toxicological information
Potential acute health effects
: Corrosive to eyes.
Eyes
Skin
: Corrosive to the skin.
: Severely irritating to the respiratory system.
Inhalation
: Harmful if swallowed. Causes burns to mouth, throat and stomach.
Ingestion
Irritancy of Product
: Hazardous by WHMIS criteria.
Potential chronic health effects
: No known significant effects or critical hazards.
Carcinogenic effects
Mutagenic effects
: No known significant effects or critical hazards.
Teratogenic effects
: No known significant effects or critical hazards.
Reproductive effects
: No known significant effects or critical hazards.
Sensitization to Product
: No known significant effects or critical hazards.
Synergistic products
: Not available.
(toxicologically)
Toxicity data
Ingredient name
Test
Result
Route
Species
polyphosphoric acids, sodium
LD50
3053 mg/kg
Oral
Rat
salts
LD50
7572 mg/kg
Oral
Mouse
Rat
Oral
3120 mg/kg
triphosphoric acid, pentasodium LD50
Mouse
Oral
3100 mg/kg
salt
LD50
Rabbit
Dermal
>4640 mg/kg
LD50
1153 mg/kg
disodium metasilicate
LD50
Rat
Oral
770 mg/kg
LD50
Mouse
Oral
250 mg/kg
LDLo
Dog
Oral
250 mg/kg
LDLo
Oral
pig
: Not available.
Target organs

Page: 4/4

POLY-BRITE

Section 12. Ecological information
Products of degradation

: These products are phosphates. Some metallic oxides.

Section 13. Disposal considerations
Waste disposal

: The generation of waste should be avoided or minimised wherever possible. Avoid dispersal of
spilt material and runoff and contact with soil, waterways, drains and sewers. Disposal of this
product, solutions and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority
requirements.
Consult your local or regional authorities.

Section 14. Transport information
Regulatory
information

TDG
Classification

UN number Proper shipping name Class

Packing
group

Additional information

UN3253

III

Explosive Limit and Limited Quantity
Index
5

DISODIUM
TRIOXOSILICATE

8

Passenger Carrying Road or Rail
Index
25
APPLIES ONLY DURING ROAD TRANSPORT
Any variation of the shipping description based on the packaging is not addressed.

Section 15. Regulatory information
WHMIS
: Class E: Corrosive material.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the
MSDS contains all the information required by the Controlled Products Regulations.

Section 16. Other information
Date of issue
: 25-January-2006.
Responsible name
: Regulatory Affairs
Date of previous issue
: 25-January-2006.
Notice to reader
The above information is believed to be correct with respect to the formula used to manufacture the product
in the country of origin. As data, standards, and regulations change, and conditions of use and handling are
beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR
CONTINUING ACCURACY OF THIS INFORMATION.

SAFETY DATA SHEET

Date of issue: 18/08/94

1. Identification of the substance/preparation and of the company/undertaking
Identification of the product
Catalogue No: 16612

ID No.: 1661200

Product name: Aquamerck® Simple pH of swimming pool water test kit- Reagent 1
Manufacturer/supplier identification
Company:

VWR International Ltd., Merck House, Poole, Dorset, BH15 1TD, England
Telephone : + 44 (0) 1202 669700
Telefax : + 44 (0) 1202 665599

Emergency telephone No.: + 44 (0) 1202 669700
2. Composition/information on ingredients
Chemical characterization
Solution in water
Product name: Aquamerck® simple pH of swimming pool water test - Reagent 1
3. Hazards identification

4. First aid measures
- Eye contact: Irrigate thoroughly with water. If discomfort persists obtain medical attention.
- Inhalation: Remove from exposure.
- Skin contact: Wash off thoroughly with soap and water.
- Ingestion: Wash out mouth thoroughly with water. In severe cases obtain medical attention.
5. Fire-fighting measures
Special risks:
Not applicable.
Suitable extinguishing media:
Not applicable
6. Accidental release measures
Wear appropriate protective clothing.
If local regulations permit, mop up with plenty of water and run to waste, diluting greatly with running water. Otherwise transfer
to container and arrange removal by disposal company. Wash site of spillage thoroughly with detergent and water.
For large spillages liquids should be contained with sand or earth and both liquids and solids transferred to salvage containers.

Any residues should be treated as for small spillages.
7. Handling and storage
Handling:
Storage:
Store at room temperature (15 to 25°C recommended). Keep well closed and protected from direct sunlight and moisture.
8. Exposure controls/personal protection
UK Exposure Limits:
None assigned
Personal protective equipment:
As appropriate to the situation and the quantity handled.
- Respirator: Not applicable
- Ventilation: Not applicable
- Gloves: Rubber or plastic
- Eye Protection: Goggles or face-shield
- Other Precautions: Plastic apron, sleeves, boots - if handling large quantities

9. Physical and chemical properties
General information:
Product description

Red solution

Health, safety and environmental information:
Melting temperature
Boiling temperature
Density(g/ml)
Vapour pressure
Relative vapour density:
Solubility in water
Flash point
Explosion limits:
lower:
Auto-ignition temperature

n/a
n/a
n/a
n/a
n/a
Miscible in all proportions
n/a
n/a
n/a

10. Stability and reactivity
Stable.
No data
11. Toxicological information
May be harmful if ingested in quantity. May irritate eyes. Stains.
Further data

No data
We have no evidence of carcinogenic effects. We have no evidence of mutagenic or teratogenic effects.

12. Ecological information
No environmental hazard is anticipated provided that the material is handled and disposed of with due care and attention.

13. Disposal considerations
Chemical residues are generally classified as special waste, and as such are covered by regulations which vary according to
location. Contact your local waste disposal authority for advice, or pass to a chemical disposal company. Rinse out empty
containers thoroughly before returning for recycling.
14. Transport information
Not subject to transport regulations.
15. Regulatory information
Labelling according to EC directives

Local Regulations

16. Other information
Date of issue:
Date of print:

18/08/94
13/07/05

HACH LANGE GmbH

Safety Data Sheet
according to Regulation (EU) No. 1907/2006

28262-53 APA 6000 Alkalinity Standard 2
Print date : 17.01.2008

Product code : 2826253

Page 1 of 4

1. Identification of the substance/preparation and of the company/undertaking
Identification of the substance or preparation

28262-53 APA 6000 Alkalinity Standard 2
Use of the substance/preparation

Water analysis
Company/undertaking identification

Company name :
Street :
Place :
Telephone :
e-mail :
Internet :

HACH LANGE GmbH
Willstätterstr. 11
D-40549 Düsseldorf
+49 (0)211 5288-383
marion.ives@hach-lange.de
www.hach-lange.com

Inquiry office :

HACH LANGE Ltd.
Pacific Way
Salford Manchester M50 1DL - United Kingdom
Tel. +44 (0) 161 872 1487
e-Mail: martin.butterfield@hach-lange.co.uk
HACH LANGE Ltd.
Unit 1, Chestnut Road Western Industrial Estate
Dublin 12 - Ireland
Tel. +353 (0)1 4602522
e-Mail: joseph.diver@hach-lange.ie

2. Hazards identification
Classification
The product does not need to be labelled in accordance with EC directives or respective national
laws.

3. Composition/information on ingredients
Chemical characterization ( preparation )

Hazardous components
EC-No.
213-791-2
207-838-8

CAS-No.

Chemical name

Quantity Classification

7732-18-5 Water

> 99 %

497-19-8 Sodium carbonate

0,1 - 1,0 % Xi R36

Full text of each relevant R phrase can be found in heading 16.

4. First aid measures
After inhalation
Move to fresh air.
After contact with skin
Wash off immediately with plenty of water.
After contact with eyes
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
After ingestion
Clean mouth with water and drink afterwards plenty of water.
Revision no. : 1.00

GB - EN

Revision date : 01.06.2007

HACH LANGE GmbH

Safety Data Sheet
according to Regulation (EU) No. 1907/2006

28262-53 APA 6000 Alkalinity Standard 2
Print date : 17.01.2008

Product code : 2826253

Page 2 of 4

Advice to doctor
Treat symptomatically.

5. Fire-fighting measures
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. The product itself does not burn.
Special exposure hazards arriving from substance or preparation itself, combustion products, resulting
gases
Fire may liberate hazardous vapours.
Special protective equipment for fire-fighters
In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.
Additional information
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local
regulations.

6. Accidental release measures
Personal precautions
Use personal protective equipment.
Environmental precautions
Do not flush into surface water or sanitary sewer system.
Methods for cleaning up/taking up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).

7. Handling and storage
Handling
Advice on safe handling
Use only in well-ventilated areas.
Storage
Requirements for storage rooms and vessels
Keep in a dry, cool place.

8. Exposure controls/personal protection
Exposure limit values
Exposure controls
Protective and hygiene measures
The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Hand protection
Use barrier skin cream.
Wash hands before breaks and after work.
Chemical resistant protective gloves
The protective gloves to be used must comply with the specifications of EC directive 89/686/EEC and
the resultant standard EN374.
Eye protection
Safety glasses with side-shields

Revision no. : 1.00

GB - EN

Revision date : 01.06.2007

HACH LANGE GmbH

Safety Data Sheet
according to Regulation (EU) No. 1907/2006

28262-53 APA 6000 Alkalinity Standard 2
Print date : 17.01.2008

Product code : 2826253

Page 3 of 4

Skin protection
Remove and wash contaminated clothing before re-use.

9. Physical and chemical properties
General information

Physical state :
Colour :
Odour :

liquid
colourless
odourless

Important health, safety and environmental information

Test method
Changes in the physical state
Boiling point :

100 °C

Flash point :

not applicable

Lower explosion limits :
Upper explosion limits :
Density (at 20 °C) :
Water solubility :

not applicable
not applicable
1 g/cm³
miscible

10. Stability and reactivity
Conditions to avoid
No dangerous reaction known under conditions of normal use.
Materials to avoid
No dangerous reaction known under conditions of normal use.
Hazardous decomposition products
No decomposition if stored and applied as directed.

11. Toxicological information
Acute toxicity
No data is available on the product itself.
Specific effects in experiment on an animal
No data is available on the product itself.

12. Ecological information
Ecotoxicity

No data is available on the product itself.
Do not flush into surface water or sanitary sewer system.

13. Disposal considerations
Advice on disposal
In accordance with local and national regulations.
Waste disposal number of waste from residues/unused products
160506
WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.

Revision no. : 1.00

GB - EN

Revision date : 01.06.2007

HACH LANGE GmbH

Safety Data Sheet
according to Regulation (EU) No. 1907/2006

28262-53 APA 6000 Alkalinity Standard 2
Print date : 17.01.2008

Product code : 2826253

Page 4 of 4

Waste disposal number of used product
160506
WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of contaminated packaging
160506
WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.

14. Transport information
Land transport (ADR/RID)
Remarks (land transport)
Not subject to transport regulations.
Inland waterways transport
Remarks (inland waterways transport)
Not tested
Marine transport
Remarks (marine transport)
Not subject to transport regulations.
Air transport
Remarks (air transport)
Not subject to transport regulations.

15. Regulatory information
Labelling
Additional advice on labelling
Classification according to European directive on classification of hazardous preparations
1999/45/EC.
EU regulatory information
Additional information
The product does not need to be labelled in accordance with EC directives or respective national
laws.
National regulatory information
Water contaminating class :

- - not water contaminating

16. Other information
Full text of R-phrases referred to under sections 2 and 3
36
Irritating to eyes.
Other data

The information is based on present level of our knowledge. It does not, however, give assurances of
product properties and establishes no contract legal rights.
(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's
safety data sheet.)

Revision no. : 1.00

GB - EN

Revision date : 01.06.2007

SIGMA-ALDRICH
MATERIAL SAFETY DATA SHEET
Date Printed: 03/10/2007
Date Updated: 02/01/2006
Version 1.3
Section 1 - Product and Company Information
Product Name

1,3,5-TRIS(2-HYDROXYETHYL)CYANURIC
ACID, 97%
309001
ALDRICH

Product Number
Brand
Company
Address

Sigma-Aldrich
3050 Spruce Street
SAINT LOUIS MO 63103 US
800-325-5832
800-325-5052
314-776-6555

Technical Phone:
Fax:
Emergency Phone:

Section 2 - Composition/Information on Ingredient
Substance Name
1,3,5-TRIS(2-HYDROXYETHYL)CYANURIC
ACID,97%
Formula

CAS #
839-90-7

SARA 313
No

C9H15N3O6

Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Irritant.
Irritating to eyes, respiratory system and skin.
For additional information on toxicity, please refer to Section 11.
Section 4 - First Aid Measures
ORAL EXPOSURE
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.
INHALATION EXPOSURE
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
DERMAL EXPOSURE
In case of contact, immediately wash skin with soap and copious
amounts of water.
EYE EXPOSURE
In case of contact, immediately flush eyes with copious amounts
of water for at least 15 minutes.
Section 5 - Fire Fighting Measures
FLASH POINT
N/A

AUTOIGNITION TEMP
N/A
FLAMMABILITY
N/A
EXTINGUISHING MEDIA
Suitable: Water spray. Carbon dioxide, dry chemical powder, or
appropriate foam.
FIREFIGHTING
Protective Equipment: Wear self-contained breathing apparatus
and protective clothing to prevent contact with skin and eyes.
Specific Hazard(s): Emits toxic fumes under fire conditions.
EXPOSURE HAZARD(S)
Material: Irritant.
Section 6 - Accidental Release Measures
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal. Avoid
raising dust. Ventilate area and wash spill site after material
pickup is complete.
Section 7 - Handling and Storage
HANDLING
User Exposure: Avoid contact and inhalation. Do not get in eyes,
on skin, on clothing.
STORAGE
Suitable: Keep tightly closed. Store in a cool dry place.
Section 8 - Exposure Controls / PPE
ENGINEERING CONTROLS
Safety shower and eye bath. Mechanical exhaust required.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory: Use respirators and components tested and approved
under appropriate government standards such as NIOSH (US) or CEN
(EU). Where risk assessment shows air-purifying respirators are
appropriate use a dust mask type N95 (US) or type P1 (EN 143)
respirator.
Hand: Rubber gloves.
Eye: Chemical safety goggles.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling. Wash contaminated clothing before
reuse.
Section 9 - Physical/Chemical Properties
Molecular Weight
pH
BP/BP Range
ALDRICH - 309001

261.24 AMU
N/A
N/A
www.sigma-aldrich.com

Page

2

MP/MP Range
Freezing Point
Vapor Pressure
Vapor Density
Saturated Vapor Conc.
SG/Density
Bulk Density
Odor Threshold
Volatile%
VOC Content
Water Content
Solvent Content
Evaporation Rate
Viscosity
Surface Tension
Partition Coefficient
Decomposition Temp.
Flash Point
Explosion Limits
Flammability
Autoignition Temp
Refractive Index
Optical Rotation
Miscellaneous Data
Solubility

136.0 - 140.0 °C
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A

N/A = not available
Section 10 - Stability and Reactivity
STABILITY
Materials to Avoid: Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
Nitrogen oxides.
Section 11 - Toxicological Information
ROUTE OF EXPOSURE
Inhalation: Material is irritating to mucous membranes and upper
respiratory tract.
Multiple Routes: Causes eye and skin irritation. May be harmful
by inhalation, ingestion, or skin absorption.
SIGNS AND SYMPTOMS OF EXPOSURE
To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
Section 12 - Ecological Information
No data available.
Section 13 - Disposal Considerations
APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION
Dissolve or mix the material with a combustible solvent and burn
in a chemical incinerator equipped with an afterburner and
scrubber. Observe all federal, state, and local environmental
regulations.
Section 14 - Transport Information
ALDRICH - 309001

www.sigma-aldrich.com

Page

3

DOT
Proper Shipping Name: None
Non-Hazardous for Transport: This substance is
considered to be non-hazardous for transport.
IATA
Non-Hazardous for Air Transport: Non-hazardous for air
transport.
Section 15 - Regulatory Information
EU ADDITIONAL CLASSIFICATION
Symbol of Danger: Xi
Indication of Danger: Irritant.
R: 36/37/38
Risk Statements: Irritating to eyes, respiratory system and skin.
S: 26-37/39
Safety Statements: In case of contact with eyes, rinse
immediately with plenty of water and seek medical advice. Wear
suitable gloves and eye/face protection.
US CLASSIFICATION AND LABEL TEXT
Indication of Danger: Irritant.
Risk Statements: Irritating to eyes, respiratory system and skin.
Safety Statements: In case of contact with eyes, rinse
immediately with plenty of water and seek medical advice. Wear
suitable gloves and eye/face protection.
UNITED STATES REGULATORY INFORMATION
SARA LISTED: No
CANADA REGULATORY INFORMATION
WHMIS Classification: This product has been classified in
accordance with the hazard criteria of the CPR, and the MSDS
contains all the information required by the CPR.
DSL: Yes
NDSL: No
Section 16 - Other Information
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2007 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.

ALDRICH - 309001

www.sigma-aldrich.com

Page

4

SIGMA-ALDRICH
MATERIAL SAFETY DATA SHEET
Date Printed: 03/10/2007
Date Updated: 02/01/2006
Version 1.3
Section 1 - Product and Company Information
Product Name

1,3,5-TRIS(2-HYDROXYETHYL)CYANURIC
ACID, 97%
309001
ALDRICH

Product Number
Brand
Company
Address

Sigma-Aldrich
3050 Spruce Street
SAINT LOUIS MO 63103 US
800-325-5832
800-325-5052
314-776-6555

Technical Phone:
Fax:
Emergency Phone:

Section 2 - Composition/Information on Ingredient
Substance Name
1,3,5-TRIS(2-HYDROXYETHYL)CYANURIC
ACID,97%
Formula

CAS #
839-90-7

SARA 313
No

C9H15N3O6

Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Irritant.
Irritating to eyes, respiratory system and skin.
For additional information on toxicity, please refer to Section 11.
Section 4 - First Aid Measures
ORAL EXPOSURE
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.
INHALATION EXPOSURE
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
DERMAL EXPOSURE
In case of contact, immediately wash skin with soap and copious
amounts of water.
EYE EXPOSURE
In case of contact, immediately flush eyes with copious amounts
of water for at least 15 minutes.
Section 5 - Fire Fighting Measures
FLASH POINT
N/A

AUTOIGNITION TEMP
N/A
FLAMMABILITY
N/A
EXTINGUISHING MEDIA
Suitable: Water spray. Carbon dioxide, dry chemical powder, or
appropriate foam.
FIREFIGHTING
Protective Equipment: Wear self-contained breathing apparatus
and protective clothing to prevent contact with skin and eyes.
Specific Hazard(s): Emits toxic fumes under fire conditions.
EXPOSURE HAZARD(S)
Material: Irritant.
Section 6 - Accidental Release Measures
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal. Avoid
raising dust. Ventilate area and wash spill site after material
pickup is complete.
Section 7 - Handling and Storage
HANDLING
User Exposure: Avoid contact and inhalation. Do not get in eyes,
on skin, on clothing.
STORAGE
Suitable: Keep tightly closed. Store in a cool dry place.
Section 8 - Exposure Controls / PPE
ENGINEERING CONTROLS
Safety shower and eye bath. Mechanical exhaust required.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory: Use respirators and components tested and approved
under appropriate government standards such as NIOSH (US) or CEN
(EU). Where risk assessment shows air-purifying respirators are
appropriate use a dust mask type N95 (US) or type P1 (EN 143)
respirator.
Hand: Rubber gloves.
Eye: Chemical safety goggles.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling. Wash contaminated clothing before
reuse.
Section 9 - Physical/Chemical Properties
Molecular Weight
pH
BP/BP Range
ALDRICH - 309001

261.24 AMU
N/A
N/A
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Page

2

MP/MP Range
Freezing Point
Vapor Pressure
Vapor Density
Saturated Vapor Conc.
SG/Density
Bulk Density
Odor Threshold
Volatile%
VOC Content
Water Content
Solvent Content
Evaporation Rate
Viscosity
Surface Tension
Partition Coefficient
Decomposition Temp.
Flash Point
Explosion Limits
Flammability
Autoignition Temp
Refractive Index
Optical Rotation
Miscellaneous Data
Solubility

136.0 - 140.0 °C
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A

N/A = not available
Section 10 - Stability and Reactivity
STABILITY
Materials to Avoid: Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
Nitrogen oxides.
Section 11 - Toxicological Information
ROUTE OF EXPOSURE
Inhalation: Material is irritating to mucous membranes and upper
respiratory tract.
Multiple Routes: Causes eye and skin irritation. May be harmful
by inhalation, ingestion, or skin absorption.
SIGNS AND SYMPTOMS OF EXPOSURE
To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
Section 12 - Ecological Information
No data available.
Section 13 - Disposal Considerations
APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION
Dissolve or mix the material with a combustible solvent and burn
in a chemical incinerator equipped with an afterburner and
scrubber. Observe all federal, state, and local environmental
regulations.
Section 14 - Transport Information
ALDRICH - 309001

www.sigma-aldrich.com

Page

3

DOT
Proper Shipping Name: None
Non-Hazardous for Transport: This substance is
considered to be non-hazardous for transport.
IATA
Non-Hazardous for Air Transport: Non-hazardous for air
transport.
Section 15 - Regulatory Information
EU ADDITIONAL CLASSIFICATION
Symbol of Danger: Xi
Indication of Danger: Irritant.
R: 36/37/38
Risk Statements: Irritating to eyes, respiratory system and skin.
S: 26-37/39
Safety Statements: In case of contact with eyes, rinse
immediately with plenty of water and seek medical advice. Wear
suitable gloves and eye/face protection.
US CLASSIFICATION AND LABEL TEXT
Indication of Danger: Irritant.
Risk Statements: Irritating to eyes, respiratory system and skin.
Safety Statements: In case of contact with eyes, rinse
immediately with plenty of water and seek medical advice. Wear
suitable gloves and eye/face protection.
UNITED STATES REGULATORY INFORMATION
SARA LISTED: No
CANADA REGULATORY INFORMATION
WHMIS Classification: This product has been classified in
accordance with the hazard criteria of the CPR, and the MSDS
contains all the information required by the CPR.
DSL: Yes
NDSL: No
Section 16 - Other Information
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2007 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.

ALDRICH - 309001

www.sigma-aldrich.com

Page

4

R-0001
MATERIAL SAFETY DATA SHEET
MANUFACTURER: TAYLOR TECHNOLOGIES, INC
31 LOVETON CIRCLE
SPARKS, MD 21152
TELEPHONE: 410-472-4340
1.PRODUCT IDENTIFICATION
CATALOG NO.: R-0001
PRODUCT NAME: DPD Reagent #1
CHEMICAL FAMILY: Inorganic salt solution
2.INGREDIENTS
INGREDIENT
Potassium phosphate
Sodium phosphate
Nonhazardous ingredients
Deionized water

CAS NO.
7778-77-0
7558-79-4
NA
7732-18-5

%
<10
<10
<1
to 100

NATURE OF HAZARD
Irritant
Irritant
None
None

3.PHYSICAL/CHEMICAL CHARACTERISTICS
STATE: Liquid
APPEARANCE: Clear, colorless
ODOR: None
BOILING PT (F): 212
pH: 10
SPECIFIC GRAVITY: 1.24
VAPOR PRESSURE (mm Hg): 17
VAPOR DENSITY (AIR=1): .64
PERCENT VOLATILE BY VOLUME: 68
SOLUBILITY IN WATER: Soluble
4.FIRE, EXPLOSION HAZARD AND REACTIVITY DATA
FLASH PT: NA
METHOD: NA
FLAMMABLE LIMITS: LEL: NA
UEL: NA
EXTINGUISHING MEDIA: Dry chemical, carbon dioxide, water spray or foam
SPECIAL PROCEDURES: Wear self-contained (positive pressure if available)
breathing apparatus and full-protective clothing
FIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May emit
toxic fumes of phosphorus oxides
NFPA CODE: Health: 0
Flammability: 0
Reactivity: 0
Specific: NA
CONDITIONS TO AVOID: Extreme heat, temperatures.
5.HEALTH HAZARD DATA
INGREDIENT: NA
TOXICITY: NA
PEL: NA
STEL: NA

TLV:

NA

ROUTE(S) OF ENTRY: Inhalation
Ingestion X
Skin X
TARGET ORGAN(S): Eyes, skin
CARCINOGENICITY: NTP No
IARC No
OSHA No
HEALTH HAZARDS AND SYMPTOMS OF EXPOSURE:
EYES: Irritant.
SKIN: Contact may cause irritation.
INGESTION: Irritant. Large quantities may cause gastrointestinal
irritation, nausea, and diarrhea.
INHALATION: NA
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions

R-0001
Page 2
6.PRECAUTIONARY MEASURES
PROTECTIVE EQUIPMENT: General purpose gloves, safety glasses, lab coat
HANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing
chemical. Wash thoroughly after handling.
STORAGE: Cool, dry area. Avoid direct sunlight.
7.EMERGENCY AND FIRST AID PROCEDURES
EYE AND SKIN CONTACT: Immediately flush eyes with water for 20 minutes or
until chemical is removed. Call physician. Wash skin thoroughly with soap
and water.
INGESTION: Give large amounts of water. Call physician. Treat symptoms
as needed. DO NOT give anything by mouth to a person who is unconscious,
rapidly losing consciousness, or convulsing.
INHALATION: NA
8.SPILL AND DISPOSAL PROCEDURES
SPILL OR RELEASE: Absorb with vermiculite or other inert material.
Containerize for later disposal.
DISPOSAL: Incineration or other method to comply with all local, state, and
federal regulations.
NA = Not applicable
ND = Not determined
NE = Not established
This Material Safety Data Sheet has been prepared in accordance with 29 CFR
Part 1910.1200 and contains information believed to be accurate and complete at
the date of preparation. However, no warranty is expressed or implied. Advice
given under "Spill and Disposal Procedures" assumes compliance with federal,
state, and local regulations regarding the disposal of hazardous waste.
DATE PREPARED: March 2006

R-0002
MATERIAL SAFETY DATA SHEET
MANUFACTURER: TAYLOR TECHNOLOGIES, INC
31 LOVETON CIRCLE
SPARKS, MD 21152
TELEPHONE: 410-472-4340
1.PRODUCT IDENTIFICATION
CATALOG NO.: R-0002
PRODUCT NAME: DPD Reagent #2
CHEMICAL FAMILY: Acidic organic amine solution
2.INGREDIENTS
INGREDIENT
N,N-Diethyl-p-phenylenediamine sulfate
Organic acid
(trade secret)
Nonhazardous ingredients
Deionized water

CAS NO.
6283-63-2

%
<1

NATURE OF HAZARD
Irritant, toxic

Confidential <10

Irritant acid

NA
7732-18-5

None
None

<1
to 100

3.PHYSICAL/CHEMICAL CHARACTERISTICS
STATE: Liquid
APPEARANCE: Clear, colorless
ODOR: None
BOILING PT (F): 212
pH: 1.3
SPECIFIC GRAVITY: 1.01
VAPOR PRESSURE (mm Hg): 17
VAPOR DENSITY (AIR=1): .65
PERCENT VOLATILE BY VOLUME: 99
SOLUBILITY IN WATER: Soluble
4.FIRE, EXPLOSION HAZARD AND REACTIVITY DATA
FLASH PT: NA
METHOD: NA
FLAMMABLE LIMITS: LEL: NA
UEL: NA
EXTINGUISHING MEDIA: NA
SPECIAL PROCEDURES: Wear self-contained (positive pressure if available)
breathing apparatus and special protective clothing
FIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May emit
toxic fumes of carbon dioxide, carbon monoxide, nitrogen oxides,
phosphine, phosphorus oxides, sulfur oxides. Contact with metals may
produce hydrogen gas.
NFPA CODE: Health: 1
Flammability: 0
Reactivity: 0
Specific: NA
CONDITIONS TO AVOID: Extreme heat, temperatures. Contact with metals,
oxidizers, strong caustic.
5.HEALTH HAZARD DATA
INGREDIENT: Organic acid
TOXICITY: LD50(orl-rat): 2400 mg/kg
PEL: NE
STEL: NE

LD50(skn-rbt): >7940 mg/kg
TLV: NE

INGREDIENT: N,N-Diethyl-p-phenylenediamine sulfate
TOXICITY: LD50(unr-rat): 450 mg/kg
PEL: NE
TLV: NE
STEL: NE

R-0002
Page 2
5.HEALTH HAZARD DATA - continued
ROUTE(S) OF ENTRY: Inhalation
Ingestion X
Skin X
TARGET ORGAN(S): Eyes, skin, gastrointestinal tract
CARCINOGENICITY: NTP No IARC No
OSHA No
HEALTH HAZARDS AND SYMPTOMS OF EXPOSURE:
EYES: Irritant
SKIN: Irritant. Contact may cause dermatitis.
INGESTION: Irritant, toxic. May cause gastrointestinal irritation, nausea,
cramps, diarrhea.
INHALATION: NA
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions
6.PRECAUTIONARY MEASURES
PROTECTIVE EQUIPMENT: General purpose gloves, safety glasses, lab coat
HANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing
chemical. Wash thoroughly after handling.
STORAGE: Cool, dry area. Avoid direct sunlight.
7.EMERGENCY AND FIRST AID PROCEDURES
EYE AND SKIN CONTACT: Immediately flush eyes with water for 20 minutes
or until chemical is removed. Call physician. Wash skin thoroughly
with soap and water.
INGESTION: Give large amounts of water or large amounts of water with milk
of magnesia. Call physician. DO NOT INDUCE VOMITING. DO NOT give anything
by mouth to a person who is unconscious, rapidly losing consciousness,
or convulsing.
INHALATION: NA
8.SPILL AND DISPOSAL PROCEDURES
SPILL OR RELEASE: Neutralize with soda ash. Absorb with vermiculite or
other inert material. Containerize for later disposal.
DISPOSAL: Incineration or other method to comply with all local, state, and
federal regulations.
NA = Not applicable
ND = Not determined
NE = Not established
This Material Safety Data Sheet has been prepared in accordance with 29 CFR
Part 1910.1200 and contains information believed to be accurate and complete at
the date of preparation. However, no warranty is expressed or implied. Advice
given under "Spill and Disposal Procedures" assumes compliance with federal,
state, and local regulations regarding the disposal of hazardous waste.
DATE PREPARED: July 2005

R-0003
MATERIAL SAFETY DATA SHEET
MANUFACTURER: TAYLOR TECHNOLOGIES, INC
31 LOVETON CIRCLE
SPARKS, MD 21152
TELEPHONE: 410-472-4340
1.PRODUCT IDENTIFICATION
CATALOG NO.: R-0003
PRODUCT NAME: DPD Reagent #3
CHEMICAL FAMILY: Inorganic salt solution
2.INGREDIENTS
INGREDIENT
Potassium iodide
Nonhazardous ingredients
Deionized water

CAS NO.
7681-11-0
NA
7732-18-5

%
<20
<1
to 100

NATURE OF HAZARD
Irritant
None
None

3.PHYSICAL/CHEMICAL CHARACTERISTICS
STATE: Liquid
APPEARANCE: Clear, colorless
ODOR: None
BOILING PT (F): 212
pH: 7.6
SPECIFIC GRAVITY: 1.07
VAPOR PRESSURE (mm Hg): 17
VAPOR DENSITY (AIR=1): .6
PERCENT VOLATILE BY VOLUME: 80
SOLUBILITY IN WATER: Soluble
4.FIRE, EXPLOSION HAZARD AND REACTIVITY DATA
FLASH PT: NA
METHOD: NA
FLAMMABLE LIMITS: LEL: NA
UEL: NA
EXTINGUISHING MEDIA: NA
SPECIAL PROCEDURES: Wear self-contained (positive pressure if available)
breathing apparatus and full-protective clothing
FIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May emit
toxic fumes of iodine.
NFPA CODE: Health: 0
Flammability: 0
Reactivity: 0
Specific: NA
CONDITIONS TO AVOID: Extreme heat, temperatures. Contact with oxidizers,
acids.
5.HEALTH HAZARD DATA
INGREDIENT: Potassium iodide
TOXICITY: LD50(orl-mus): 1862 mg/kg
PEL: NE
STEL: NE

TLV:

NE

ROUTE(S) OF ENTRY: Inhalation
Ingestion X
Skin X
TARGET ORGAN(S): Eyes, skin
CARCINOGENICITY: NTP No IARC No
OSHA No
HEALTH HAZARDS AND SYMPTOMS OF EXPOSURE:
EYES: Contact may cause irritation.
SKIN: Contact may cause irritation.
INGESTION: Irritant. May cause gastrointestinal irritation.
INHALATION: NA
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions

R-0003
Page 2
6.PRECAUTIONARY MEASURES
PROTECTIVE EQUIPMENT: General purpose gloves, safety glasses, lab coat
HANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing
chemical. Wash thoroughly after handling.
STORAGE: Cool, dry area. Avoid direct sunlight.
7.EMERGENCY AND FIRST AID PROCEDURES
EYE AND SKIN CONTACT: Immediately flush eyes with water for 20 minutes or
until chemical is removed. Call physician. Wash skin thoroughly with soap
and water.
INGESTION: Give large amounts of water. Call physician. Treat symptoms
as needed. DO NOT give anything by mouth to a person who is unconscious,
rapidly losing consciousness, or convulsing.
INHALATION: NA
8.SPILL AND DISPOSAL PROCEDURES
SPILL OR RELEASE: Absorb with vermiculite or other inert material.
Containerize for later disposal.
DISPOSAL: Incineration or other method to comply with all local, state, and
federal regulations.
NA = Not applicable
ND = Not determined
NE = Not established
This Material Safety Data Sheet has been prepared in accordance with 29 CFR
Part 1910.1200 and contains information believed to be accurate and complete at
the date of preparation. However, no warranty is expressed or implied. Advice
given under "Spill and Disposal Procedures" assumes compliance with federal,
state, and local regulations regarding the disposal of hazardous waste.
DATE PREPARED: February 2007

R-0004
MATERIAL SAFETY DATA SHEET
MANUFACTURER: TAYLOR TECHNOLOGIES, INC
31 LOVETON CIRCLE
SPARKS, MD 21152
TELEPHONE: 410-472-4340
1.PRODUCT IDENTIFICATION
CATALOG NO.: R-0004
PRODUCT NAME: pH Indicator Solution (Phenol Red)
CHEMICAL FAMILY: Sulfonphthalein dye solution
2.INGREDIENTS
INGREDIENT
CAS NO.
Nonhazardous ingredients, NA
each
Deionized water
7732-18-5

%
<1

NATURE OF HAZARD
None

to 100

None

3.PHYSICAL/CHEMICAL CHARACTERISTICS
STATE: Liquid
APPEARANCE: Clear, red
ODOR: Phenolic
BOILING PT (F): 212
pH: 7.7
SPECIFIC GRAVITY: 1
VAPOR PRESSURE (mm Hg): 17
VAPOR DENSITY (AIR=1): .6
PERCENT VOLATILE BY VOLUME: 98
SOLUBILITY IN WATER: Soluble
4.FIRE, EXPLOSION HAZARD AND REACTIVITY DATA
FLASH PT: NA
METHOD: NA
FLAMMABLE LIMITS: LEL: NA
UEL: NA
EXTINGUISHING MEDIA: NA
SPECIAL PROCEDURES: Wear self-contained (positive pressure if available)
breathing apparatus and full-protective clothing
FIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May emit toxic
fumes of carbon oxides, nitrogen oxides, ammonia.
NFPA CODE: Health: 0
Flammability: 0
Reactivity: 0
Specific: NA
CONDITIONS TO AVOID: Extreme heat, temperatures.
5.HEALTH HAZARD DATA
INGREDIENT: NA
TOXICITY: NA
PEL: NA
STEL: NA

TLV:

NA

ROUTE(S) OF ENTRY: Inhalation
Ingestion X
Skin X
TARGET ORGAN(S): Eyes, skin
CARCINOGENICITY: NTP No
IARC No
OSHA No
HEALTH HAZARDS AND SYMPTOMS OF EXPOSURE:
EYES: Contact may cause irritation.
SKIN: Contact may cause staining.
INGESTION: Large quantities may cause gastrointestinal irritation.
INHALATION: NA
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions

R-0004
Page 2
6.PRECAUTIONARY MEASURES
PROTECTIVE EQUIPMENT: General purpose gloves, safety glasses, lab coat
HANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing
chemical. Wash thoroughly after handling.
STORAGE: Cool, dry area. Avoid direct sunlight.
7.EMERGENCY AND FIRST AID PROCEDURES
EYE AND SKIN CONTACT: Immediately flush eyes with water for 20 minutes or
until chemical is removed. Call physician. Wash skin thoroughly with soap
and water.
INGESTION: Give large amounts of water. Call physician. Treat symptoms
as needed. DO NOT give anything by mouth to a person who is unconscious,
rapidly losing consciousness, or convulsing.
INHALATION: NA
8.SPILL AND DISPOSAL PROCEDURES
SPILL OR RELEASE: Absorb with vermiculite or other inert material.
Containerize for later disposal.
DISPOSAL: Incineration or other method to comply with all local, state, and
federal regulations.
NA = Not applicable
ND = Not determined
NE = Not established
This Material Safety Data Sheet has been prepared in accordance with 29 CFR
Part 1910.1200 and contains information believed to be accurate and complete at
the date of preparation. However, no warranty is expressed or implied. Advice
given under "Spill and Disposal Procedures" assumes compliance with federal,
state, and local regulations regarding the disposal of hazardous waste.
DATE PREPARED: February 2007

R-0005
MATERIAL SAFETY DATA SHEET
MANUFACTURER: TAYLOR TECHNOLOGIES, INC
31 LOVETON CIRCLE
SPARKS, MD 21152
TELEPHONE: 410-472-4340
1.PRODUCT IDENTIFICATION
CATALOG NO.: R-0005
PRODUCT NAME: Acid Demand Reagent (ADR)
CHEMICAL FAMILY: Inorganic acid solution
2.INGREDIENTS
INGREDIENT
Sulfuric acid
Deionized water

CAS NO.
7664-93-9
7732-18-5

%
<1
to 100

NATURE OF HAZARD
Irritant acid
None

3.PHYSICAL/CHEMICAL CHARACTERISTICS
STATE: Liquid
APPEARANCE: Clear, colorless
ODOR: None
BOILING PT (F): 212
pH: 1.3
SPECIFIC GRAVITY: 1
VAPOR PRESSURE (mm Hg): 17
VAPOR DENSITY (AIR=1): .6
PERCENT VOLATILE BY VOLUME: 100
SOLUBILITY IN WATER: Soluble
4.FIRE, EXPLOSION HAZARD AND REACTIVITY DATA
FLASH PT: NA
METHOD: NA
FLAMMABLE LIMITS: LEL: NA
UEL: NA
EXTINGUISHING MEDIA: Dry chemical, carbon dioxide
SPECIAL PROCEDURES: Wear self-contained (positive pressure if available)
breathing apparatus and special protective clothing
FIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May react
violently with water. May react with metals to produce hydrogen gas. May
ignite combustible materials. May emit toxic fumes of sulfur oxides.
NFPA CODE: Health: 1
Flammability: 0
Reactivity: 0
Specific: NA
CONDITIONS TO AVOID: Extreme heat, temperatures. Contact with strong
alkali, metals.
5.HEALTH HAZARD DATA
INGREDIENT: Sulfuric acid
TOXICITY: LD50(orl-rat): 2140 mg/kg
PEL: 1 mg/m3
STEL: 3 mg/m3

TLV:

1 mg/m3

ROUTE(S) OF ENTRY: Inhalation
Ingestion X
Skin X
TARGET ORGAN(S): Eyes, skin
CARCINOGENICITY: NTP No
IARC No
OSHA No
HEALTH HAZARDS AND SYMPTOMS OF EXPOSURE:
EYES: Irritant. Contact may cause burns.
SKIN: Irritant. Contact may cause burns.
INGESTION: Irritant. May cause gastrointestinal irritation.
INHALATION: NA
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions

R-0005
Page 2
6.PRECAUTIONARY MEASURES
PROTECTIVE EQUIPMENT: General purpose gloves, safety glasses, lab coat
HANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing
chemical. Wash thoroughly after handling.
STORAGE: Cool, dry area. Avoid direct sunlight.
7.EMERGENCY AND FIRST AID PROCEDURES
EYE AND SKIN CONTACT: Immediately flush eyes with water for 20 minutes or
until chemical is removed. Call physician. Wash skin thoroughly
with soap and water.
INGESTION: Give large amounts of water or large amounts of water with milk
of magnesia. Call physician. DO NOT INDUCE VOMITING. DO NOT give anything
by mouth to a person who is unconscious, rapidly losing consciousness, or
convulsing.
INHALATION: NA
8.SPILL AND DISPOSAL PROCEDURES
SPILL OR RELEASE: Neutralize with soda ash. Absorb with vermiculite or
other inert material. Containerize for later disposal.
DISPOSAL: Incineration or other method to comply with all local, state, and
federal regulations.
NA = Not applicable
ND = Not determined
NE = Not established
This Material Safety Data Sheet has been prepared in accordance with 29 CFR
Part 1910.1200 and contains information believed to be accurate and complete at
the date of preparation. However, no warranty is expressed or implied. Advice
given under "Spill and Disposal Procedures" assumes compliance with federal,
state, and local regulations regarding the disposal of hazardous waste.
DATE PREPARED: October 2005

R-0006
MATERIAL SAFETY DATA SHEET
MANUFACTURER: TAYLOR TECHNOLOGIES, INC
31 LOVETON CIRCLE
SPARKS, MD 21152
TELEPHONE: 410-472-4340
1.PRODUCT IDENTIFICATION
CATALOG NO.: R-0006
PRODUCT NAME: Base Demand Reagent (BDR)
CHEMICAL FAMILY: Inorganic alkali solution
2.INGREDIENTS
INGREDIENT
Sodium carbonate
Deionized water

CAS NO.
497-19-8
7732-18-5

%
<1
to 100

NATURE OF HAZARD
Irritant alkali
None

3.PHYSICAL/CHEMICAL CHARACTERISTICS
STATE: Liquid
APPEARANCE: Clear, colorless
ODOR: None
BOILING PT (F): 212
pH: 11.2
SPECIFIC GRAVITY: 1
VAPOR PRESSURE (mm Hg): 17
VAPOR DENSITY (AIR=1): .6
PERCENT VOLATILE BY VOLUME: 99
SOLUBILITY IN WATER: Soluble
4.FIRE, EXPLOSION HAZARD AND REACTIVITY DATA
FLASH PT: NA
METHOD: NA
FLAMMABLE LIMITS: LEL: NA
UEL: NA
EXTINGUISHING MEDIA: NA
SPECIAL PROCEDURES: Wear self-contained (positive pressure if available)
breathing apparatus and full-protective clothing
FIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May react
violently with strong acids, fluorine, aluminum and lithium metals, and
phosphorus pentoxide. May emit toxic fumes of sodium oxide and carbon
dioxide.
NFPA CODE: Health: 1
Flammability: 0
Reactivity: 0
Specific: NA
CONDITIONS TO AVOID: Extreme heat, temperatures. Contact with strong
acids, fluorine, metals, phosphorus pentoxide.
5.HEALTH HAZARD DATA
INGREDIENT: Sodium carbonate
TOXICITY: LD50(orl-rat): 4090 mg/kg
PEL: NE
STEL: NE

TLV:

NE

ROUTE(S) OF ENTRY: Inhalation
Ingestion X
Skin X
TARGET ORGAN(S): Eyes, skin
CARCINOGENICITY: NTP No
IARC No
OSHA No
HEALTH HAZARDS AND SYMPTOMS OF EXPOSURE:
EYES: Irritant.
SKIN: Irritant. Contact may cause irritation.
INGESTION: Irritant. May cause gastrointestinal irritation.
INHALATION: NA
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions

R-0006
Page 2
6.PRECAUTIONARY MEASURES
PROTECTIVE EQUIPMENT: General purpose gloves, safety glasses, lab coat
HANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing
chemical. Wash thoroughly after handling.
STORAGE: Cool, dry area. Avoid direct sunlight.
7.EMERGENCY AND FIRST AID PROCEDURES
EYE AND SKIN CONTACT: Immediately flush eyes with water for 20 minutes or
until chemical is removed. Call physician. Wash skin thoroughly with soap
and water.
INGESTION: Give large amounts of water. Call physician. DO NOT INDUCE
VOMITING. DO NOT give anything by mouth to a person who is unconscious,
rapidly losing consciousness, or convulsing.
INHALATION: NA
8.SPILL AND DISPOSAL PROCEDURES
SPILL OR RELEASE: Neutralize with dilute acid. Absorb with vermiculite or
other inert material. Containerize for later disposal.
DISPOSAL: Incineration or other method to comply with all local, state, and
federal regulations.
NA = Not applicable
ND = Not determined
NE = Not established
This Material Safety Data Sheet has been prepared in accordance with 29 CFR
Part 1910.1200 and contains information believed to be accurate and complete at
the date of preparation. However, no warranty is expressed or implied. Advice
given under "Spill and Disposal Procedures" assumes compliance with federal,
state, and local regulations regarding the disposal of hazardous waste.
DATE PREPARED: July 2005

MSDS
P.O. Box 329 - 802 Washington Avenue Chestertown, MD 21620 - USA
TELEPHONE # FOR INFORMATION 410 778-3100

MATERIAL SAFETY DATA SHEET

24 HOUR EMERGENCY NUMBER (CHEM-TEL): USA, Canada, Puerto Rico 800-255-3924;
Outside North American Continent 813-248-0585 (call Collect)

1. Product Identification

Manufactured By: LaMotte Company
802 Washington Avenue
Chestertown, MD 21620

Product Code: 2976
Product Description: 3-Way Instatest Pool & Spa
Test Strips

2. Composition/Information On Ingredients
Hazard CAS#/Name

%

N/A
Dyes

<1

N/A
Buffers

<1

N/A
Polymers, binders

<1

N/A
Surfactant

<1

N/A
Organic acid

<1

PEL

NO HAZARDOUS INGREDIENTS in amounts >0.l%

All other ingredients are proprietary

Strips measure alkalinity, pH, and free chlorine in water.

1

TLV

Product Code: 2976

Product Description: 3-Way Instatest Pool & Spa
Test Strips

3. Hazards Overview
Primary Route Of Entry:

HMIS Hazard
Scale: 4 = Extreme, 3 = High, 2 = Moderate, 1= Slight, 0 = Least
Health: 0
Flammability: 0
Reactivity: 0
Carcinogenicity: None:

Other Health Related Comments:
Strips are non-toxic.

4. First Aid Measures
Eye Contact: Flush with water.
Skin Contact: Flush with water. Wash with soap and water.
Ingestion: Consult a physician.
Inhalation: N/A

5. Fire Fighting Measures
Flash Point (Method Used):

LEL: N/A

N/A

Extinguishing Media:

Water spray

Special Fire Fighting Procedures:

N/A

Unusual Fire & Explosion Hazard:

N/A

6. Accidental Release Measures
Sweep up and discard to trash.

2

UEL: N/A

Product Code: 2976

Product Description: 3-Way Instatest Pool & Spa
Test Strips

7. Handling & Storage
Store in cool, dry, storage area.

8. Exposure Controls/Personal Protection
Ventilation
Normal

Protection When Handling
N/A

Work/Hygenic Practices:

N/A

9. Physical & Chemical Properties
Appearance:
Solubility In Water:
Odor:
pH:

White Plastic Strip with colored paper pads
Insoluble
None
N/A

Vapor Density:
Vapor Pressure:
Boiling Point:
Melting Point:

10. Stability & Reactivity
Stable:

Yes

Conditions To Avoid:

Heat, Light, Moisture, air.

Incompatibility (Materials To Avoid):

N/A

Hazardous Decomposition Products:

N/A

3

N/A
N/A
N/A
N/A

Product Code: 2976

Product Description: 3-Way Instatest Pool & Spa
Test Strips

11. Toxicological Information
non-toxic

Target Organs:

N/A

12. Ecological Information
Information Not Yet Available

13. Disposal Considerations
Discard to trash. Dispose according to federal, state and local regulations.

14.QRLabel53
Transportation Information
Not Regulated For Transport

15. Regulatory Information
Chemical Inventory Status
Hazard

Ingredient

USA
TSCA

Europe
EC

--- Canada --DSL
NDSL

4

Australia

Japan

Product Code: 2976

Product Description: 3-Way Instatest Pool & Spa
Test Strips

Federal, State, & International Regulations
--- SARA 302 --Ingredient

Ingredient

product 2976
as a whole

RQ

--------- SARA 313 --------Listed

TPQ

Chemical Category

--- SARA 311/312 --Hazard Categories
Acute Chronic Fire Pressure Reactivity

-------- Australia ------Hazchem
Poison
Code
Schedule

No

None Allocated

No

No

No

No

16. Other Information
Store in cool, dry place out of direct sunlight.

Prepared By: IP, Regulatory Affairs Department
Revised: 11/2/2005

5

RCRA
261.33

CERCLA

TSCA
8(D)

This MSDS Is
WHMIS Compliant

None Allocated

Atlantic Chemical Equipment Co.
2190 DeFoor Hills Rd NW
Atlanta, GA 30318
404-355-5522

MATERIAL SAFETY DATA SHEET

PRODUCT NAME:

DETERGENT TABLETS BLISTER PACK (DPT)

EMERGENCY PHONE: 1-800-424-9300
May be used to comply with OSHA'S Hazard Communications Standard (HSC) 29 CRF 1910, 1200.

Standard must be consulted for specific requirements. This product contains
no substances subject to SARA TITLE III and 40 CRF.

VII - PRECAUTIONS FOR SAFE HANDLING AND USE
STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED:
Wash off with soap and water. Do not get in eyes or on mucous membrane

HMIS SYMBOLS
HEALTH

1

FLAMMABILITY

0

REACTIVITY

0

WASTE DISPOSAL METHOD: Incinerate with adequate ventilation

1 - IDENTIFICATION

VIII - SPECIAL PROTECTION INFORMATION

PRODUCT NAME: (DPT) DETERGENT TABLETS BLISTER PACK

PACKAGE TYPE: 12 Cards/8 tablets per card

PREPARED DEPARTMENT OF HAZARDOUS COMMUNICATIONS

DATE PREPARED: June 2003

RESPIRATORY: Use approved NIOSH respirator in dusty conditions
EYE: Chemical goggles recommended

II - HAZARDOUS INGREDIENTS
PRINCIPLE HAZARDOUS COMPONENT(S)
(CHEMICAL NAMES)
N-Alkydimethyl Benzyl Ammonium Chloride

CAS NO

ACGIH TLV

OSHA

PEL

1733-96-6

% or RANGE

SKIN: Wear impervious gloves

PROTECTIVE GLOVES: Impervious rubber or neoprene

20
OTHER: Do not eat, drink, or smoke in work area. Wash hands before eating
VENTILATION REQUIREMENTS: None needed

IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Do not remove tablets from pouch.

III - PHYSICAL DATA
BOILING POINT ( 0F) : N.A.
VAPOR PRESSURE (mm Hg) : N.A.

SPECIFIC GRAVITY (H20= 1) : N.A.

VAPOR DENSITY (Air = 1) : N.A.

EVAPORATION RATE (H20 = 1) : 0.0001

pH :

APPEARANCE AND ODOR : White tablets, no odor

MELTING POINT: 0

SPECIAL PRECAUTIONARY STATEMENTS: Do not get in eyes. Do not take internally. Keep this and all chemicals out of reach of
children.
NOTICE: We believe that the information contained on this material safety data sheet is accurate. The suggested procedures are based on
experience as of the date of publication. They are not necessarily nor fully adequate in every circumstance. Also, the suggestions should not be
confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements. No warranty, expressed or implied, of
merchantability fitness or otherwise is made.

SOLUBILITY IN WATER : 80%

IV - FIRE AND EXPLOSION HAZARD DATA
FLAMMABILITY as per CPSC FLAME EXTENTION TEST: Flash Point

NONE
SARA Title III Reporting Requirements

SPECIAL FIRE FIGHTING PROCEDURES: None
UNUSUAL FIRE AND EXPLOSION HAZARDS: None

V - REACTIVITY DATA
CHEMICAL
STABILITY

UNSTABLE

302

(Extremely Hazardous Substances): Reporting not required.

304/CERCLA

(Spills Notification): Not required.

311

Community Right-To-Know, RTK): Reporting not required. Acute health hazard, irritating, toxic.

312

(RTK Inventory Data): Reporting required for inventory above TPQ.

CONDITIONS TO AVOID:
X

STABLE

INCOMPATIBILITY (Materials to avoid): None
HAZARDOUS DECOMPOSITION PRODUCTS: None
HAZARDOUS
POLYMERIZATION

MAY OCCUR

CONDITIONS TO AVOID:

WILL NOT OCCUR

X

VI - HEALTH HAZARD AREA
ROUTE(S) OF ENTRY:

EYES Yes

SKIN Yes

INGESTION Yes

313

(Emissions and Releases): Reporting not required.

DOT

NOT HAZARDOUS

INHALATION Yes
References

EFFECTS OF OVER EXPOSURE:
INHALATION: If crushed or powdered, dusts are toxic

TOXIC SUBSTANCE CONTROL CT LIST (TSCA) - INGREDIENTS LISTED

SKIN CONTACT/ABSORPTION: Irritating to skin

PERMISSIBLE EXPOSURE REFERENCES:
Registry of Toxic Effects of Chemical Substances.

INGESTION: Toxic by ingestion

Title 29 Code of Federal Regulations.
National Toxicology Program (NTP) Report on Carcinogens.

EYES: Irritating on eye contact
CARCINOGENICITY:

NTP? Not listed

IARC MONOGRAPHS? Not listed

OSHA REGULATED? Not listed

Title 40 Code of Federal Regulations

EMERGENCY AND FIRST AID PROCEDURES:
EYES AND SKIN: EYES - Wash eyes with large quantities of water for 15 minutes. If irritation persists, call physician.
soap and water

International Agency for Research on Cancer (IARC) Monographs.

SKIN - Wash skin with

INHALATION: Remove to fresh air. If breathing remains difficult GET IMMEDIATE MEDICAL ATTENTION
INGESTION: If swallowed, drink large quantities of milk, egg white, gelatin. Do not induce vomiting. Avoid alcohol. GET IMMEDIATE MEDICAL
ATTENTION.

REGULATORY STANDARDS:
DOT Title 49 Code of Federal Regulations 172.101
SARA Title III
Nuclear Regulatory Commission

1

Pumice Scouring Stick
Item Number:100714
U.S. Department Of Labor
Occupational Safety And Health Administration

MATERIAL SAFETY DATA SHEET
Required Under USDL Safety And Health Regulations
(29 CFP 1910.1200 "Hazards Communication Standard")

Section I
Manufactured For: Gabriel First Corp.
Emergency Telephone: 1-800-424-9300
Address: 233 W Commercial Street East Rochester, NY 14445
Chemical Name & Synonyms: Cleaning, Compound, Liquid
Trade Name & Synonyms: Pumice Scouring Stick
Prepared On: 6/30/2005

Section I - Hazardous Ingredients/Identity Information
Section II - Product & Component Data
Component(s)/ Chemical Names
TLV
PEL
Pumice (Volcanic Glass)
There is No Free Crystalline Silica Present

CAS Registry No

%

Section III - Physical Data
Boiling Point: N/A
Specific Gravity (H 2O=1): N/A
Melting Point: 2390° F
Vapor Pressure: N/A
Percent, Volatile By Volume (%): N/A
Vapor Density (Air=1): N/A
Evaporation Rate: N/A
Solubility In Water: Not Soluble
Appearance And Odor: Odorless Solid

Section IV - Fire And Explosion Hazard Data
Special Fire Fighting Procedures: None.
Unusual Fire and Explosion Hazards: None
Flash Point/Method Used: N/A
Flammable Limits: N/A
LEL: N/A UEL: N/A
Extinguishing Media: N/A

Section V - Health Hazard Data
Route(s) of Entry:
Inhalation? Yes
Skin? No
Ingestion: Yes
Health Hazards (Acute and Chronic): Dry sawing or grinding may result in the release of dust particles which, acute, may
cause irritation of eyes, nose or throat and chronic, may result in lung disease (Silicosis) if exposed for prolonged time.
Carcinogenicity:
NTP?
IARC Monographs?
OSHA Regulated?
No
No
No
Signs and Symptoms of Exposure: Irritation of eyes, nose and throat or shortness of breath.
Medical Conditions Generally Aggravated by Exposure: Pre -existing lung disease such as Emphysema
or Asthma.

Emergency First Aid Procedures: Irrigate eyes generously with clean water for 15 minutes. If irritation persists call a
physician.

Section VI - Reactivity Data
Stability Conditions To Avoid
Stable
None
Materials To Avoid: None
Hazardous Decomposition Products: None
Hazardous Polymerization
Conditions To Avoid
Will Not Occur
None

Section VII - Spill Or Leak Procedures
Steps To Be Taken In Case Material Is Released Or Spilled: Sweep up and properly dispose.
Waste Disposal Method: Dispose as common waste.
Precautions To Be Taken in Handling and Storing: None
Other Precautions: Wear NIOSH approved respirator and tight fitting goggles. When dry sawing or grinding, or saw and
grind when wet.

Section VIII - Special Protection Information
Control Measures (When Sawing or Grinding)
Respiratory Protection (Type): NIOSH Approved Particulate Respirator
Ventilation: Mechanical (General) in Confined Area
Protective Gloves: When Required
Eye Protection: Tight Fitting Goggles
Other Protective Equipment: None
Work/Hygienic Practices: N/A

Section IX - Special Precautions
Precautions To Be Taken In Handling And Storing: None

This information is given in good faith, but no warranty expressed or implied is made. Our company believes that it is accurate to the best of its knowledge
and relates only to the specific material designated herein.

For RICCA, SpectroPure, Red Bird, and Solutions Plus Brands
Emergency Contact(24 hr) -- CHEMTREC®
Domestic: 800-424-9300
International: 703-527-3887
BUFFER, REFERENCE STANDARD, pH 7.00; BUFFER, PRECISION REFERENCE STANDARD pH 7.000 (Color Coded Yellow)

MSDS

Material Safety Data Sheet
Section 1: Chemical Product and Company Identification
Catalog Number:
1551, 1552, B-285, B017740, R1551300, S1551, SB017740

Product Identity:
BUFFER, REFERENCE STANDARD, pH 7.00; BUFFER, PRECISION REFERENCE STANDARD pH 7.000 (Color Coded Yellow)

Emergency Contact(24 hr) -- CHEMTREC®

Manufacturer's Name:
RICCA CHEMICAL COMPANY LLC

Domestic: 800-424-9300
International: 703-527-3887

CAGE Code: 0V553
Address:
448 West Fork Dr
Arlington, TX 76012

Telephone Number For Information:
817-461-5601

Date Prepared:

Revision: 7

6/16/98

Last Revised: 01/13/2006
Date Printed: 03/07/2006 9:31:07 pm

Section 2. Composition/Information on Ingredients
Component
Sodium Phosphate, Dibasic

CAS Registry #
7558-79-4

Concentration

ACGIH TLV

<1

Not Available
Not Available

Water, Deionized

7732-18-5

Balance

Not Available

<1

Not Available

< 0.1

Not Available

< 0.1

Not Available

Not Available
Potassium Phosphate, Monobasic

7778-77-0

Not Available
Inert Dye

proprietary

Not Available
Preservative (No Mercury compounds or
Formaldehyde)

pROPRIETARY

Not Available

OSHA PEL
Not Available
Not Available
Not Available
Not Available
Not Available
Not Available
Not Available
Not Available
Not Available
Not Available

Section 3: Hazard Identification
Emergency Overview: Non-flammable, non-toxic, non-corrosive. Does not present any significant health hazards. May cause irritation. Wash areas of contact

with water
Target Organs: eyes, skin
Eye Contact: May cause slight irritation.
Inhalation: May cause allergic respiratory reaction to those allergic to phosphates.

Page 1 of 4

For RICCA, SpectroPure, Red Bird, and Solutions Plus Brands
Emergency Contact(24 hr) -- CHEMTREC®
Domestic: 800-424-9300
International: 703-527-3887

MSDS

BUFFER, REFERENCE STANDARD, pH 7.00; BUFFER, PRECISION REFERENCE STANDARD pH 7.000 (Color Coded Yellow)

Skin Contact: May cause slight irritation to those allergic to phosphates.
Ingestion: Large doses may cause stomach upset.
Chronic Effects/Carcinogenicity: None
IARC - No.
NTP - No.
OSHA - No.
Reproductive Information: Not Applicable.
Teratology (Birth Defect) Information: Not Applicable.

Section 4: First Aid Measures - In all cases, seek qualified evaluation.
Eye Contact: Irrigate immediately with large quantity of water for at least 15 minutes. Call a physician if irritation develops.
Inhalation: Remove to fresh air. Give artificial respiration if necessary. If breathing is difficult, give oxygen.
Skin Contact: Flush with plenty of water for at least 15 minutes. Call a physician if irritation develops.
Ingestion: Dilute with water or milk. Call a physician if necessary.

Section 5: Fire Fighting Measures
Flash Point: Not Available.

Method Used: Not Available.

LFL: Not Available.

UFL: Not Available.

Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Fire & Explosion Hazards: Not considered to be a fire or explosion hazard.
Fire Fighting Instructions: Use normal procedures/instructions.
Fire Fighting Equipment: Use protective clothing and breathing equipment appropriate for the surrounding fire.

Section 6: Accidental Release Measures
Absorb with suitable material (vermiculite, clay, etc.) and dispose of in accordance with local regulations.
Check with local agencies for the proper disposal of phosphate containing solutions.

Section 7. Handling and Storage
As with all chemicals, wash hands thoroughly after handling. Avoid contact with eyes and skin. Protect from freezing and physical damage.
Safety Storage Code: General

Section 8: Exposure Control/Personal Protection
Engineering Controls: No specific controls are needed. Normal room ventilation is adequate.
Respiratory Protection: Normal room ventilation is adequate.
Skin Protection: Chemical resistant gloves.
Eye Protection: Safety glasses or goggles.

Section 9: Physical and Chemical Properties
Appearance: Clear, Yellow Liquid
Odor: Odorless
Solubility in Water: Inifinite
Specific Gravity: Approximately 1

pH: 7
Boiling Point(°C): Approximately 100
Melting Point(°C): Approximately 0
Vapor Pressure: Not Applicable.

Section 10: Stability and Reactivity
Chemical Stability: Stable under normal conditions of use and storage.
Incompatibility: None identified.

Page 2 of 4

For RICCA, SpectroPure, Red Bird, and Solutions Plus Brands
Emergency Contact(24 hr) -- CHEMTREC®
Domestic: 800-424-9300
International: 703-527-3887

MSDS

BUFFER, REFERENCE STANDARD, pH 7.00; BUFFER, PRECISION REFERENCE STANDARD pH 7.000 (Color Coded Yellow)

Hazardous Decomposition Products: Phosphorus oxides may form when heated to decomposition
Hazardous Polymerization: Will not occur.

Section 11. Toxicological Information
LD50, Oral, Rat: (Sodium Phosphate Dibasic) 17 gm/kg; LD50, Dermal, Rabbit: (Potassium Phosphate Monobasic) >4640 mg/kg; details of toxic effects not
reported other than lethal dose value.

Section 12. Ecological Information
Ecotoxicological Information: No information found
Chemical Fate Information: No information found

Section 13. Disposal Considerations
Dilute with water, then flush to sewer if local regulations allow for the flushing of phosphate containing solutions. If not allowed, save for recovery or recycling
in an approved waste disposal facility. Always dispose of in accordance with local, state and federal regulations.

Section 14. Transport Information
Part Numbers:

This product is not regulated.

Section 15. Regulatory Information (Not meant to be all inclusive - selected regulation represented)
OSHA Status:The above items either do not contain any specifically hazardous material or the potentially hazardous material is present in such low

concentration that the items do not present any immediate threat to health and safety. These items do not meet the OSHA Hazard Communication Standard (29
CFR 1910.1200) definition of a hazardous material.
TSCA Status:All components of this solution are listed on the TSCA Inventory or are mixtures (hydrates) of items listed on the TSCA Inventory.

Sara Title III:
Section 302 Extremely Hazardous Substances:Not Applicable.
Section 311/312 Hazardous Catagories:No
Section 313 Toxic Chemicals:Not Applicable.
California: None Reported.
Pennsylvania: Sodium Phosphate, Dibasic is listed as an Environmental Hazard on the state's Hazardous Substances List.
RCRA Status: Not Applicable.
CERCLA Reportable Quantity: Sodium Phosphate, Dibasic - 5,000 pounds.

WHMIS: Not Applicable.

Page 3 of 4

For RICCA, SpectroPure, Red Bird, and Solutions Plus Brands
Emergency Contact(24 hr) -- CHEMTREC®
Domestic: 800-424-9300
International: 703-527-3887

MSDS

BUFFER, REFERENCE STANDARD, pH 7.00; BUFFER, PRECISION REFERENCE STANDARD pH 7.000 (Color Coded Yellow)

Section 16. Other Information
NFPA Ratings:
Health: 1

Flammability: 0

Reactivity: 0

Special Notice Key:None

Flammability: 0

Reactivity: 0

Protective Equipment:B (Protective Eyewear, Gloves)

HMIS Ratings:
Health: 1

Rev 1, 10-19-98: (Section 16) Removed periods from NFPA and HMIS, Added® to HMIS;
Rev 2, 3-8-2000: Reformatted from WordPerfect® to Microsoft Word®, (Section 1) Revised emergency telephone number to CHEMTREC® 800-424-9300,
(Section 3) Added “May cause…water.” in emergency overview, (Section 7) added storage code, (Section 10) added decomposition products, (Section 11)
added toxicological data, (Section 15) added Pennsylvania listing.
Rev 3, 8-25-2000: (Section 2) corrected concentration of preservative from 1 - 2 to < 0.1%.
Rev 4, 10-09-2001: Reformatted to electronic data format.
Rev 5, 04-25-2003: (Section 1) added Solutions Plus catalog number B017740.
Rev 6, 04-01-2004: (Section 1) added catalog number S1551.
Rev 7, 01-13-2006: (Section 1) added catalog number R1551300.

When handled properly by qualified personnel, the product described herein does not present a significant health or safety hazard. Alteration of
its characteristics by concentration, evaporation, addition of other substances, or other means may present hazards not specifically addressed
herein and which must be evaluated by the user. The information furnished herein is believed to be accurate and represents the best data
currently available to us. No warranty, expressed or implied, is made and RICCA CHEMICAL COMPANY assumes no legal responsibility or
liability whatsoever resulting from its use.

Page 4 of 4

00006472

MATERIAL SAFETY DATA SHEET

Page 1

OSBORN INTERNATIONAL
5401 HAMILTON AVE.
CLEVELAND; 44114
USA

PRODUCT: 1515-01-002 76210 DRY GRAPHITE LUBRICANT 290G(10.25OZ)

Section 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
MANUFACTURER .................................................

PRODUCT NAME...................................................
CHEMICAL FAMILY................................................
MOLECULAR WEIGHT...........................................
CHEMICAL FORMULA...........................................
TRADE NAMES & SYNONYMS..............................
PRODUCT USES....................................................
FORMULA/LAB BOOK #.........................................

MANUFACTURED FOR:
OSBORN INTERNATIONAL
5401 HAMILTON AVE.
CLEVELAND
USA
44114
216-361-1900
1515-01-002 76210 DRY GRAPHITE LUBRICANT 290G(10.25OZ)
GRAPHITE.
NOT APPLICABLE.
MIXTURE.
1515-01-002 76210 DRY GRAPHITE LUBRICANT 290G(10.25OZ)
COATING.
F 01-040.

Section 02: COMPOSITION/INFORMATION INGREDIENTS
Hazardous Ingredients

%

Exposure Limit

C.A.S.#

LD/50, Route,Species

ACETONE

30-60

750 ppm

67-64-1

>9750 mg/kg ORAL - RAT

HEXANE

10-30

50 ppm

110-54-3

17,300 mg/kg ORAL-RAT

ISOPROPANOL

5-10

400 ppm

67-63-0

>4720 mg/kg ORAL - RAT

GRAPHITE POWDER
ISOBUTANE

1-5
5 -10

2.5mg/m3
1000 ppm

7782-42-5
75-28-5

NOT AVAILABLE
NOT APPLICABLE

PROPANE

10-30

1000 ppm

74-98-6

NOT APPLICABLE

LC/50 Route,Species
>16,000 ppm (4 hr) INHAL RAT
48,000 mg/kg
INHAL-MOUSE
12000 ppm (8hr) INHAL RAT
NOT AVAILABLE
142,500 ppm (4h) INHAL RAT
NOT AVAILABLE

Section 03: HAZARDS IDENTIFICATION
ROUTE OF ENTRY:
INGESTION............................................................. MAY CAUSE HEADACHE, NAUSEA, VOMITING AND WEAKNESS.
INHALATION........................................................... INHALATION OF SOLVENTS MAY CAUSE IRRITATION. PROPELLANT IS A SIMPLE
ASPHYXIANT.
EYE CONTACT....................................................... MAY CAUSE IRRITATION.
SKIN ABSORPTION................................................ NO DATA AVAILABLE FOR THIS PRODUCT MIXTURE.
SKIN CONTACT...................................................... MAY CAUSE IRRITATION.
EFFECTS OF ACUTE EXPOSURE........................ DIZZINESS, NAUSEA. IRRITATION TO SKIN & EYES.
EFFECTS OF CHRONIC EXPOSURE................... SOLVENTS MAY CAUSE DEFATTING DERMATITIS
EXPOSURE LIMIT OF MATERIAL......................... SEE SECTION 2.

.

Section 04: FIRST AID MEASURES
EMERGENCY FIRST AID PROCEDURE .............. IN CASE OF EYE CONTACT, FLUSH IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES AND GET MEDICAL ATTENTION. FOR SKIN, WASH THOROUGHLY WITH SOAP AND
WATER. IF AFFECTED BY INHALATION OF VAPOUR OR SPRAY MIST, REMOVE TO FRESH AIR.
IF SWALLOWED; DO NOT INDUCE VOMITING, GET MEDICAL ATTENTION.

Section 05: FIRE FIGHTING MEASURES
AUTO IGNITION TEMPERATURE (°C).................. 225-465.
SPECIAL PROCEDURES....................................... WATER FROM FOGGING NOZZLES MAY BE USED TO COOL CLOSED CONTAINERS TO
PREVENT BUILD-UP IF EXPOSED TO EXTREME TEMPERATURES. FULL PROTECTIVE
EQUIPMENT INCLUDING SELF CONTAINED BREATHING APPARTATUS SHOULD BE WORN IN A
FIRE INVOLVING THIS MATERIAL.
FLAMMABILITY....................................................... EXTREMELY FLAMMABLE.
IF YES, UNDER WHICH CONDITIONS?................ EXCESSIVE HEAT, SPARKS AND OPEN FLAME.
EXTINGUISHING MEDIA........................................ WATER, CARBON DIOXIDE, DRY CHEMICAL, FOAM.
UPPER FLAMMABLE LIMIT................................... 12.8.
(% BY VOLUME)
LOWER FLAMMABLE LIMIT.................................. 1.2.
(% BY VOLUME)
FLASH POINT (C), TAG CLOSED CUP................. LOWEST KNOWN VALUE IS ACETONE @ -18C.
EXPLOSION DATA
SENSITIVITY TO STATIC DISCHARGE........... NOT APPLICABLE.
SENSITIVITY TO IMPACT................................. NOT APPLICABLE.

00006472

MATERIAL SAFETY DATA SHEET

Page 2

PRODUCT: 1515-01-002 76210 DRY GRAPHITE LUBRICANT 290G(10.25OZ)
Section 05: FIRE FIGHTING MEASURES
HAZARDOUS COMBUSTION
PRODUCTS............................................................

HYDROCARBON FUMES AND SMOKE. CARBON MONOXIDE WHERE COMBUSTION IS
INCOMPLETE.

AEROSOL FLAME PROJECTION
CLASSIFIED AS:..................................................... >15cm BUT <100cm.
FLASHBACK........................................................... NONE.

Section 06: ACCIDENTAL RELEASE MEASURES
LEAK/SPILL............................................................. REMOVE ALL SOURCES OF IGNITION. USE AN INERT ABSORBENT MATERIAL, AND
NON-SPARKING TOOLS. VENTILATE AREA. PREVENT FROM ENTERING A WATERCOURSE.

Section 07: HANDLING AND STORAGE
STORAGE NEEDS..................................................
ENGINEERING CONTROLS..................................
HANDLING PROCEDURES AND EQUIPMENT.....
SYNERGISTIC MATERIALS...................................

KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAMES.
VENTILATION - LOCAL (MECHANICAL IF USED INDOORS ON A CONTINUOUS BASIS).
STORE IN A COOL, WELL VENTILATED AREA NOT TO EXCEED 50 DEG C.
NONE KNOWN.

Section 08: EXPOSURE CONTROLS/PERSONAL PROTECTION
GLOVES/ TYPE......................................................
RESPIRATORY/TYPE............................................

WEAR CHEMICAL RESISTANT GLOVES.
IF USED INDOORS ON A CONTINUOUS BASIS, USE OF A CARTRIDGE TYPE RESPIRATOR
(NIOSH/MSHATC 23C OR EQUIVALENT) IS RECOMMENDED.
EYE/TYPE............................................................... SAFETY GLASSES.
FOOTWEAR/TYPE................................................. NOT NORMALLY REQUIRED.
OTHER/TYPE.......................................................... NOT REQUIRED.

Section 09: PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE..................................................
APPEARANCE........................................................
ODOR......................................................................
ODOR THRESHOLD...............................................
VAPOUR PRESSURE(PSIG)-AEROSOL...............
@ 20 C
BOILING POINT (°C)(CONC)..................................
EVAPORATION RATE............................................
n-BUTYL ACETATE = 1
VAPOUR DENSITY (AIR=1)...................................
(BY WEIGHT)
SOLUBILITY IN WATER g/L (20°C)........................
pH............................................................................
SPECIFIC GRAVITY (LIQUID)................................
COEFFICIENT OF WATER\OIL DIST.....................
FREEZING POINT: (°C)..........................................
AEROSOL PERCENT VOLATILE...........................
(BY WEIGHT).
SPECIFIC GRAVITY (AEROSOL)..........................

AEROSOL.
BLACK/GREY.
KETONE.
NOT AVAILABLE.
50-60.
57-69.
GREATER THAN 1.
GREATER THAN 1.
NOT AVAILABLE.
NOT APPLICABLE.
0.75-0.82.
NOT AVAILABLE.
NOT AVAILABLE.
97-98.
0.66-0.70.

Section 10: STABILITY AND REACTIVITY
HAZARDOUS PRODUCTS OF
DECOMPOSITION.................................................. HYDROCARBON FUMES AND SMOKE. CARBON MONOXIDE WHERE COMBUSTION IS
INCOMPLETE.
CHEMICAL STABILITY:
YES......................................................................... UNDER NORMAL CONDITIONS.
NO, WHICH CONDITIONS?................................... NOT APPLICABLE.
COMPATIBILITY WITH OTHER SUBSTANCES:
NO, WHICH ONES?................................................ STRONG OXIDIZING AGENTS.
REACTIVITY CONDITIONS?.................................. NOT APPLICABLE.
HAZARDOUS POLYMERIZATION......................... WILL NOT OCCUR.

Section 11: TOXICOLOGICAL INFORMATION
REPRODUCTIVE EFFECTS................................... NO INFORMATION IS AVAILABLE AND NO ADVERSE REPRODUCTIVE EFFECTS ARE
ANTICIPATED.
IRRITANCY OF MATERIAL.................................... SKIN/EYE IRRITANT. N-HEXANE MAY DAMAGE PERIPHERAL NERVE TISSUE.
SENSITIZING CAPABILITY OF MATERIAL........... UNKNOWN.
CARCINOGENICITY OF MATERIAL...................... THE INGREDIENTS OF THIS PRODUCT ARE NOT LISTED AS CARCINOGENS BY NTP,
(NATIONAL TOXICOLOGY PROGRAM), NOT REGULATED AS CARCINOGENS BY OSHA,
(OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION), AND HAVE NOT BEEN EVALUATED
BY IARC,(INTERNATIONAL AGENCY FOR RESEARCH ON CANCER), NOR BY ACGIH
(AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS).
TERATOGENICITY................................................. NO INFORMATION IS AVAILABLE AND NO ADVERSE TERATOGENIC EFFECTS ARE
ANTICIPATED.
MUTAGENICITY..................................................... NO INFORMATION IS AVAILABLE AND NO ADVERSE MUTAGENIC EFFECTS ARE
ANTICIPATED.

00006472

MATERIAL SAFETY DATA SHEET

Page 3

PRODUCT: 1515-01-002 76210 DRY GRAPHITE LUBRICANT 290G(10.25OZ)
Section 12: ECOLOGICAL CONSIDERATIONS
ENVIRONMENTAL.................................................. NOT AVAILABLE.

Section 13: DISPOSAL CONSIDERATIONS
WASTE DISPOSAL................................................. DO NOT PUNCTURE OR INCINERATE CONTAINERS, EVEN WHEN EMPTY. DISPOSE OF IN
ACCORDANCE WITH LOCAL, PROVINCIAL AND FEDERAL REGULATIONS.

Section 14: TRANSPORTATION INFORMATION
T.D.G. CLASSIFICATION.......................................
D.O.T. CLASSIFICATION.......................................

CONSUMER COMMODITY (AEROSOLS, UN1950, CLASS 2.1) .
CONSUMER COMMODITY, ORM-D.

Section 15: REGULATORY INFORMATION
CANADIAN REGULATIONS:
-------------------------------------WHMIS CLASSIFICATION...................................... A,B5,D2B.
CNFC SECTION 3.3.5............................................. LEVEL 3.
CEPA (Canadian Enviromental Protection Act)
ALL SUBSTANCES IN THIS PRODUCT ARE LISTED ON THE CANADIAN DOMESTIC
SUBSTANCES LIST (DSL) OR ARE NOT REQUIRED TO BE LISTED.
U.S. REGULATIONS:
-----------------------------HMIS RATING HEALTH.......................................... 2 MODERATE HAZARD.
HMIS RATING FLAMMABILITY.............................. 4 SEVERE HAZARD.
HMIS RATING REACTIVITY................................... 0 MINIMAL HAZARD.
HMIS RATING PERSONAL PROTECTION............ B.
NFPA CODE 30B.................................................... LEVEL 3.
SARA 313 INFORMATION:..................................... THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
.
CAS #:
CHEMICAL NAME:
.
*110-54-3
N-HEXANE.
CALIFORNIA PROPOSITION 65:........................... THE FOLLOWING STATEMENT IS MADE IN ORDER TO COMPLY WITH THE CALIFORNIA SAFE
DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986:
.
WARNING: THIS PRODUCT DOES NOT INTENTIONALLY CONTAIN ANY CHEMICALS KNOWN
TO THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
. CAS #:
CHEMICAL NAME:
. N/A.
TSCA (Toxic Substances Control Act).................... ALL COMPONENT OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY. ANY
IMPURITIES PRESENT IN THIS PRODUCT ARE EXEMPT FROM LISTING.
VOC (w/w%)............................................................ 58-59.

Section 16: OTHER INFORMATION
NOTICE FROM KG PACKAGING INC ................... THE INFORMATION ON THIS MATERIAL SAFETY DATA SHEET IS PROVIDED BY K-G
PACKAGING INC. FREE OF CHARGE. WHILE BELIEVED TO BE RELIABLE, IT IS INTENDED FOR
USE BY SKILLED PERSONS AT THEIR OWN RISK. K-G PACKAGING INC. ASSUMES NO
RESPONSIBILITY FOR EVENTS RESULTING OR DAMAGES INCURRED FROM ITS USE. THE
INFORMATION ON THIS MATERIAL SAFETY DATA SHEET RELATES ONLY TO THE SPECIFIC
MATERIAL DESIGNATED HEREIN AND DOES NOT RELATE TO USE IN COMBINATION WITH
ANY OTHER MATERIAL OR IN ANY PROCESS.
PREPARED BY....................................................... TECHNICAL SERVICES
PREPARATION DATE ........................................... Jun11/07

MATERIAL SAFETY DATA
PRODUCT NAME: 4” & 10” Glue Sticks
PRODUCT CODE: 10-701 & 10-801

HMIS CODES: H F R P
000B

SECTION 1 - MANUFACTURER IDENTIFICATION
MANUFACTURER'S NAME:
ROBERTS CONSOLIDATED INDUSTRIES, INC.
ADDRESS: 2501 Lakeview Drive, Mexico, MO 65265
EMERGENCY PHONE:
(800)424-9300 (Chemtrec)
DATE REVISED:
09/01/01

INFORMATION PHONE: (905) 791-4444
NAME OF PREPARER: Peter Sharko

SECTION 11 - HAZARDOUS INGREDIENTS/SARA 111 INFORMATION
No reportable quantities of hazardous ingredients are present per OSHA regulation: 29 CFR 1910-1200.
No toxic chemical(s) subject to the reporting requirements of Section 313 of Title 111 and of 40 CFR 372 are present.
SECTION 111 - PHYSICAL/CHEMICAL CHARACTERISTICS
BOILING POINT:
N/A
VAPOR DENSITY:
N/A
COATING V.O.C.:
N/A
SOLUBILITY IN WATER:
Insoluble
APPEARANCE AND ODOR:
Transparent Solid
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
FLASH POINT:
N/A
FLAMMABLE LIMITS IN AIR BY VOLUME EXTINGUISHING MEDIA:
Foam, CO2, Dry Chemical
SPECIFIC FIREFIGHTING PROCEDURES: None
UNUSUAL FIRE AND EXPLOSION HAZARDS: None

SPECIFIC GRAVITY (H20=1): .9
EVAPORATION RATE: Slower than ether
pH: Neutral

METHOD USED: N/A
LOWER: N/A UPPER: N/A

SECTION V - REACTIVITY DATA
STABILITY:
Stable
INCOMPATIBILITY:
(Materials to avoid): Strong oxidizers.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Combustion products.
HAZARDOUS POLYMERIZATION: Will not occur.

CONDITIONS TO AVOID: Excessive Heat

SECTION VI - HEALTH HAZARD DATA
INHALATION HEALTH RISKS AND SYMPTOMS OF EXPOSURE: None
SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE: Molten material will cause skin burns.
SKIN ABSORPTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE: None
INGESTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE: Not likely to occur. Should it occur potential G.I. Blockage.
HEALTH HAZARDS (Acute and Chronic):
ACUTE: None
CHRONIC: None
CARCINOGENICITY: NTP? No
IARC MONOGRAPHS? No
OSHA REGULATED? No
This product contains no carcinogens as listed by NTP, IARC and OSHA
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: None known.
EMERGENCY AND FIRST AID PROCEDURES:
EYES:
N/A
SKIN:
N/A
INGESTION:
N/A
SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Contain for salvage or disposal.
WASTE DISPOSAL METHOD: Discarded material may be incinerated. Dispose according to Federal, State and local regulations.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep package from excessive heat. Keep out of reach of children.
OTHER PRECAUTIONS: None
SECTION VIII - CONTROL MEASURES
RESPIRATORY PROTECTION: None should be required.
PROTECTIVE GLOVES: General purpose gloves to protect against burns.
VENTILATION: None should be required.
EYE PROTECTION: None
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: None
WORK/HYGIENE PRACTICES: Standard hygiene and safe handling procedures are believed to be generally applicable.
SECTION IX - DISCLAIMER
DISCLAIMER: The information accumulated herein is believed to be accurate, but is not warranted to be whether originating with the company or not. Each user should review and determine for
themselves, the applicability of the information in the specific context of the intended use.

KEEP OUT OF REACH OF CHILDREN
Manufactured by:

ROBERTS CONSOLIDATED INDUSTRIES INC.

American Lubricating Co
5OO SOUTH FRONT STREET * PO BOX 258
MEMPHIS, TN 38101 USA
www.americanlubricating.com
phone: 901 527 4707 fax: 901 525 7670

MATERIAL SAFETY DATA SHEET
MANUFACTURER'S NAME:
American Lubricating Company
ADDRESS:
PO Box 258, Memphis, TN 38101

PRODUCT NAME: No Smoke Two Stroke
2 Cycle Engine Oil
/Fuel Stabilizer
HAZARD MATERIAL ID SYSTEM: H-1 F-1 R-0 PP-B

SECTION 1 - DESCRIPTION
PRODUCT NAME: No Smoke Two Stroke Two Cycle Engine Oil w/Fuel Stabilizer
DOT SHIPPING NAME: N/A
DOT HAZARD CLASS: Non-Hazardous
CAS REGISTRY NUMBER: 64742-54-7 or 64742-65-0
CHEMICAL NAME: Petroleum lubricating oil and fuel additive containing a
polyamine condensation product based dispersant and other component
judged not to affect the potential health or environmental impact of the
product, and <1% proprietary fuel stabilizer.
PREPARER: Chip Armstrong, October 2005
SECTION 2 - HAZARDOUS INGREDIENTS
COMPONENTS: Blend of mineral oil, light distillate solvent, and
proprietary additives.

BOILING POINT, DEG F: N/A
MELTING POINT, DEG F: N/A
SPECIFIC GRAVITY: 0.88
APPEARANCE: Dyed blue

SECTION 3 - PHYSICAL DATA
VAPOR PRESSURE: negligible
VAPOR DENSITY: above 1
SOLUBILITY IN WATER: negligible
ODOR: mineral oil

SECTION 4 - FIRE AND EXPLOSION DATA
FLASH POINT, DEG F: 178
EXTINGUISHING MEDIUM: water fog, foam, dry chemical, carbon dioxide
SPECIAL FIRE FIGHTING PROCEDURES: Use water spray to cool exposed containers
Fire fighting personnel should use respiratory protection.
UNUSUAL FIRE EXPLOSION HAZARDS: product of combustion includes fumes & CO2
SECTION 5 - REACTIVITY HAZARDS
STABILITY: stable
MATERIAL TO AVOID: strong oxidizers
HAZARDOUS POLYMERIZATION: will not
CONDITION TO AVOID: flame, extreme heat
HAZARDOUS DECOMPOSITION PRODUCTS: carbon monoxide upon combustion, fumes, smoke

SECTION 6 - HEALTH HAZARD INFORMATION
ROUTE OF ENTRY: X INHALATION X SKIN X INGESTION
ACUTE OVEREXPOSURE: may cause reversible eye and skin irritation; prolonged
skin exposure may cause dermatitis; ingestion may cause cramps & diarrhea;
breathing mists may cause dizziness
CHRONIC OVEREXPOSURE: defined by IARC as Class I mineral oil
CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN:
NATIONAL TOXICOLOGY PROGRAM IARC MONOGRAPHS
OSHA
YES
X NO
YES X NO
YES X NO
THRESHOLD LIMIT VALUE: 5-mg/cubic meter as mist
EMERGENCY AND FIRST AID: in all cases remove source of exposure
1. INHALATION: unlikely to occur except as mist
2. EYES: flush with water for at least 15 minutes or until irritation
subsides
3. SKIN: wash well with soap and water; remove oil soaked clothing;
wash clothes before reuse; if irritation develops, consult
physician
4. INGESTION: DO NOT induce vomiting; consult physician; contains solvent
SECTION 7 - SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION: normally not required with adequate ventilation;
if exposure exceeds limits, use NIOSH/MSHA approved air respirator
VENTILATION: if mists are present, provide adequate ventilation to control
level below the Permissible Exposure Limit
PROTECTIVE GLOVES: impermeable gloves EYE PROTECTION: goggles
OTHER: none usually required
SECTION 8 - SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES
HANDLING & STORAGE PRECAUTIONS: Keep away from fire, flame & sparks
OTHER PRECAUTIONS: never wear oil soaked clothing; discard oil soaked shoes;
affix proper warning labels on containers according to 29 CFR 1010.1200
IN CASE OF SPILLS: no unusual hazard; use pump and/or oil absorbent; keep
from entering waterways and sewers
WASTE DISPOSAL METHODS: dispose according to current local, state and
federal regulations; consider recycling; NOTE: material may become a
hazardous waste through use
NOTE: The above information is based on data of which we are aware and
is believed to be correct. However, no warranty is expressed or implied
regarding the accuracy of this data or the results to be obtained from the
use thereof. American Lubricating Company, Inc. assumes no responsibility
for injury to vendee or third persons proximately caused by the material if
reasonable safety procedures are not adhered to as stipulated in the data
sheet. Additionally, we assume no responsibility for injury to vendee or
third persons proximately caused by abnormal use of the material even if
reasonable safety procedures are followed. Furthermore, vendee assumes the
risk in his use of the material.

J/B Industries Inc.
Section 1: Product And
Company Identification
COMPANY:
LOCATION:

J/B INDUSTRIES INC.
601 N. Farnsworth Ave.
Aurora, IL 60507

Emergency Telephone Number:

630/851-9444
PRODUCT NAME:

Vacuum Pump Oil
PRODUCT GRADES:
PRODUCT CODE:
DATE ISSUED:

December 28, 1992
DATE REVISED:

September 18, 2006
Sept. 1 , 2003

Section 2: Composition/
Information On Ingredients
CAS NAME:

Distillates, hydrotreated heavy paraffinic
CAS NUMBER:

64742-54-7
AMOUNT:

100% weight
This product is not approved for direct
food use [CFR 178.3620 (a) & (b)]

Section 3: Hazards Identification
EMERGENCY OVERVIEW

Clear colorless to pale yellow liquid.
IMMEDIATE HEALTH EFFECTS
EYE:

Not expected to cause prolonged or
significant eye irritation.
SKIN:

Contact with the skin is not expected to
cause prolonged or significant irritation.
Not expected to be harmful to internal
organs if absorbed through the skin.
Contact with the skin is not expected to
cause an allergic skin response.
INGESTION:

Not expected to be harmful if swallowed.
INHALATION:

Not expected to be harmful if inhaled.
Contains a petroleum-based mineral oil.
May cause respiratory irritation or other
pulmonary effects following prolonged
or repeated inhalation of oil mist at
airborne levels above the recomm
ended mineral oil mist exposure limit.
Symptoms of respiratory irritation
may include coughing and
difficulty breathing.

Material Safety Data Sheet
Section 4: First Aid Measures
EYE:

No specific first aid measures are
required because this material is not
expected to cause eye irritation. As a
precaution, remove contact lenses, if
worn, and flush eyes with water.
SKIN:

No specific first aid measures are
required because this material is not
expected to be harmful if it contacts the
skin. As a precaution, remove clothing
and shoes if contaminated. To remove
the material from skin, use soap and
water. Discard contaminated
clothing and shoes or thoroughly
clean before reuse.
No specific first aid measures are
required because this material is not
expected to be harmful if swallowed. Do
not induce vomiting. As a precaution,
give the person a glass of water or milk
to drink and get medical advice. Never
give anything by mouth to an
unconscious person.
INHALATION:

No specific first aid measures are
required because this material is not
expected to be harmful if inhaled. If
exposed to excessive levels of material
in the air, move the exposed person to
fresh air. Get medical attention
if coughing or respiratory
discomfort occurs.

Section 5: Fire Fighting Measures
FIRE CLASSIFICATION;

OSHA Classification (29 CFR
1910.1200): Not classified by OSHA as
flammable or combustible.
NFPA RATINGS:
HEALTH FLAMMABILITY

REACTIVITY

1

0

FLAMMABLE PROPERTIES:
FLASH POINT:

Cleveland Open Cup 378°F (190°C)
(Min)
AUTOIGNITION:

No data available
FLAMMABLE (EXPLOSIVE) LIMITS (% by
volume in air):

Lower N/A

Combustion Products:

Highly dependent on combustion
conditions. A complex mixture of
airborne solids, liquids, and gases
including carbon monoxide, carbon
dioxide, and unidentified organic
compounds will be evolved when this
material undergoes combustion.

Section 6. Accidental Release
Measures
PROTECTIVE MEASURES:

Eliminate all sources of ignition in
vicinity of spilled material.
SPILL MANAGEMENT:

INGESTION:

0

material, do not enter any enclosed or
confined fire space without proper
protective equipment, including selfcontained breathing apparatus.

Upper N/A

EXTINGUISHING MEDIA:

Use water fog, foam, dry chemical or
carbon dioxide (CO2) to extinguish
flames.
PROTECTION OF FIRE FIGHTERS:
Fire Fighting Instructions:

This material will burn although it is not
easily ignited. For fires involving this

Stop the source of the release if you can
do it without risk. Contain release to
prevent further contamination of soil,
surface water or groundwater. Clean up
spill as soon as possible, observing
precautions in Exposure Controls/
Personal Protection. Use appropriate
techniques such as applying noncombustible absorbent materials or
pumping. Where feasible and
appropriate, remove contaminated soil.
Place contaminated materials in
disposable containers and dispose of
in a manner consistent with
applicable regulations.
REPORTING:

Report spills to local authorities and/or
the U.S. Coast Guard's National
Response Center at (800) 424-8802 as
appropriate or required.

Section 7. Handling and Storage
GENERAL HANDLING INFORMATION:

Avoid contaminating soil or releasing this
material into sewage and drainage
systems and bodies of water.
STATIC HAZARD:

Electrostatic charge may accumulate and
create a hazardous condition when
handling this material. To minimize this
hazard, bonding and grounding may be
necessary but may not, by themselves,
be sufficient. Review all operations which
have the potential of generating an
accumulation of electrostatic charge and/
or a flammable atmosphere (including
tank and container filling, splash filling,
tank cleaning, sampling, gauging, switch
loading, filtering, mixing, agitation, and
vacuum truck operations) and use
appropriate mitigating procedures. For
more information, refer to OSHA
1

Standard 29 CFR 1910.106, 'Flammable
and Combustible Liquids', National Fire
Protection Association (NFPA 77,
'Recommended Practice on Static
Electricity; and /or the American
Petroleum Institute (API) Recommended
Practice 2003, 'Protection Against
Ignitions Arising Out of Static, Lightning
and Stray Currents'.
CONTAINER WARNING:

Container is not designed to contain
pressure. Do not use pressure to empty
container or it may rupture with
explosive force. Empty containers retain
product residue (solid, liquid, and/or
vapor) and can be dangerous. Do not
pressurize, cut, weld, braze, solder, drill,
grind, or expose such containers to heat,
flame, sparks, static electricity, or other
sources of ignition. They may explode
and cause injury or death. Empty
containers should be completely
drained, properly closed, and promptly
returned to a drum reconditioner or
disposed of properly.

RESPIRATORY PROTECTION:

No respiratory protection is normally
required.
If user operations generate an oil mist,
determine if airborne concentrations are
below the OSHA Permissible Exposure
Limit (PEL) of 5 mg/m3 for mineral oil
mist. If not, wear a NIOSH approved
respirator that provides adequate
protection from the measured
concentrations of this material. For
air-purifying respirators use a
particulate cartridge.
Use a positive pressure, air-supplying
respirator if there is potential for
uncontrolled release, exposure levels are
not known, or other circumstances
where air-purifying respirators may not
provide adequate protection.

Section 9: Physical And
Chemical Properties
APPEARANCE AND ODOR:

Clear colorless to pale yellow liquid.
PH:

Not Available

Section 8. Exposure Controls/
Personal Protection

VAPOR PRESSURE:

GENERAL CONSIDERATIONS:

VAPOR DENSITY (Air =1):

Consider the potential hazards of this
material (see Section 3), applicable
exposure limits, job activities, and other
substances in the work place when
designing engineering controls and
selecting personal protective equipment.
If engineering controls or work practices
are not adequate to prevent exposure to
harmful levels of this material, the
personal protective equipment listed
below is recommended. The user should
read and understand all instructions and
limitations supplied with the equipment
since protection is usually provided for a
limited time or under certain
circumstances.
ENGINEERING CONTROLS:

Use in a well-ventilated area.
PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:

No special eye protection is normally
required. Where splashing is possible,
wear safety glasses with side shields as
a good safety practice.
SKIN PROTECTION:

No special protective clothing is normally
required. Where splashing is possible,
select protective clothing depending on
operations conducted, physical
requirements and other substances.
Suggested materials for protective
gloves include: Nitrile Rubber, Silver
Shield, Viton.

<0.01 mmHg @ 100°F
>1
BOILING POINT:

>600°F (>315° C)
SOLUBILITY:

Soluble in hydrocarbons, insoluble in
water
FREEZING POINT

NA
MELTING POINT

NA
SPECIFIC GRAVITY:

0.85-0.87 @ 15.6 °C/15.6°C
VOLATILE ORGANIC COMPOUNDS (VOC):

2.9% weight (Approximate)
VISCOSITY:

18.7 cST - 105 cST @40°C

Section 11. Toxicological
Information
IMMEDIATE HEALTH EFFECTS
EYE IRRITATION:

The mean 24-hour Draize eye irritation
score in rabbits is 4.0/110.
SKIN IRRITATION:

For a 24-hour exposure, the
Primary Irritation Score (PIS) in
rabbits is: 0.2/8.0.
SKIN SENSITIZATION:

This material did not cause skin
sensitization reactions in a Buehler
guinea pig test.
ACUTE DERMAL TOXICITY:

The 24 hour(s) LD50 in the rabbit is
>5g/kg.
ACUTE ORAL TOXICITY:

The LD50 in the rat is >5 g/kg.
ACUTE INHALATION TOXICITY:

The acute inhalation toxicity hazard is
based on evaluation of data for similar
materials or product components.
GENETIC TOXICITY:

This product gave negative results in the
following mutagenicity assays:
Microbial/Microsome Reverse Mutation
Assay.
ADDITIONAL TOXICOLOGY INFORMATION:

This product contains petroleum base
oils which may be refined by various
processes including severe solvent
extraction, severe hydrocracking, or
severe hydrotreating. None of the oils
requires a cancer warning under the
OSHA Hazard Communication Standard
(29 CFR 1910.1200). These oils have not
been listed in the National Toxicology
Program (NTP) Annual Report nor have
they been classified by the International
Agency for Research on Cancer (IARC)
as; carcinogenic to humans (Group 1),
probably carcinogenic to humans
(Group 2A), or possibly carcinogenic to
humans (Group 2B).

Section 10. Stability And
Reactivity

Section 12. Ecological
Information:

CHEMICAL STABILITY:

EXOTOXICITY

This material is considered stable under
normal ambient and anticipated storage
and handling conditions of temperature
and pressure.
INCOMPATIBILITY WITH
OTHER MATERIALS:

May react with strong oxidizing agents,
such as chlorates, nitrates, peroxides,
etc.
HAZARDOUS DECOMPOSITION PRODUCTS:

None known (None expected)
HAZARDOUS POLYMERIZATION:

Hazardous polymerization will not occur.

Ten 96 hour(s) LC50 for rainbow trout
(Oncorhynchus mykiss) is >1000 mg/l.
ENVIRONMENTAL FATE
READY BIODEGRADABILITY:

This material is not expected to be
readily biodegradable.

Section 13. Disposal
Considerations
Oil collection services are available for
used oil recycling or disposal. Place
contaminated materials in containers
and dispose of in a manner consistent
2

with applicable regulations. Contact your
sales representative or local
environmental or health authorities for
approved disposal or recyling methods.

Section 14. Transportation
Information
The description shown may not apply to
all shipping situations. Consult 49CFR,
or appropriate Dangerous Goods
Regulations, for additional description
requirements (e.g., technical name) and
mode-specific or quantity-specific
shipping requirements.
DOT SHIPPING NAME:

Not regulated as a hazardous material for
transportation under 49 CFR
DOT HAZARD CLASS:

Not Applicable
DOT IDENTIFICATION NUMBER:

Not Applicable
DOT PACKING GROUP:

Not Applicable

Section 15. Regulatory
Information
SARA 311/312 CATEGORIES:

1.
2.
3.
4.

Immediate (Acute) Health Effects:
Delayed (Chronic) Health Effects:
Fire Hazard:
Sudden Release of
Pressure Hazard:
5. Reactivity Hazard:
REGULATORY LISTS SEARCHED:

4_I1=IARC Group 1
4_I2A=IARC Group 2A
4_I28B=IARC Group 2B
05=NTP Carcinogen
06-OSHA Carcinogen
09-TSCA 12(b)
10=TSCA Section 4
11=TSCA Section 8(a) CAIR
12=TSCA Section 8(a) PAIR
13=TSCA Section 8(d)
15=SARA Section 313
16=CA Proposition 65
17=MA RTK
18=NJ RTK
19=DOT Marine Pollutant
20=PA RTK
21=TSCA Section 5(a)
25=CAA Section 112 HAPs
26=CWA Section 311
28=CWA Section 307
30=RCRA Waste P-List
31-RCRA Waste U-List
32=RCRA Appendix VIII
No components of this material were
found on the regulatory lists above.

No
No
No
No
No

CHEMICAL INVENTORIES:

AUSTRALIA: All the components of this
material are listed on the Australian
Inventory of Chemical Substances
(AICS).
KOREA: All the components of this
product are on the Existing Chemicals
List (ECL) in Korea.
PHILIPPINES: All the components of this
product are listed on the Philippine
Inventory of Chemicals and Chemical
Substances (PICCS).
CANADA: All the components of this
material are on the Canadian Domestic
Substances List (DSL).
EUROPEAN UNION: All the components
of this material are in compliance with
the EU Seventh Amendment Directive
92/32/EEC.
UNITED STATES: All of the components
of this material are on the Toxic
Substances Control Act (TSCA) Chemical
Inventory.
NEW JERSEY RTK CLASSIFICATION:
Under the New Jersey Right-to-Know Act
L. 1983 Chapter 315 N.J.S.A.34:5A-1 et.
seq., the product is to be indentified as
follows: PETROLEUM OIL
WHMIS CLASSIFICATION:

This product is not considered a
controlled product according to the
criteria of the Canadian Controlled
Products Regulations.

Section 16. Other Information
NFPA RATINGS:

Health: Flammability:
0
1

Reactivity:
0

HMIS RATINGS:

Health: Flammability: Reactivity
1
1
0
(0-Least, 1-Slight, 2-Moderate, 3-High,
4-Extreme, PPE:-Personal Protection
Equipment Index recommendation, *Chronic Effect Indicator). These values
are obtained using the guidelines or
published evaluations prepared by the
National Fire Protection Association
(NFPA) or the National Paint and Coating
Association (for HMIS ratings).
Prepared according to the OSHA Hazard
Communication Standard (29 CFR
1910.1200) and the ANSI MSDS
Standard (Z400.1).
The above information is based on the
data of which we are aware and is
believed to be correct as of the date
hereof. Since this information may be
applied under conditions beyond our
control and with which we may be
unfamiliar and since data made available
subsequent to the date hereof may
suggest modifications of the information,
we do not assume any responsibility for
the results of it use. This information is
furnished upon condition that the person
receiving it shall make his own
determination of the suitability of the
material for his particular purpose.

3

Material Safety Data Sheet
1 - Chemical Product and Company Identification
Manufacturer: WD-40 Company
Chemical Name: Organic Mixture
Address:

1061 Cudahy Place (92110)
P.O. Box 80607
San Diego, California, USA
92138 –0607
Telephone:
1-800-448-9340
Emergency only: 1-888-324-7596 (PROZAR)
Information:
1-888-324-7596

Trade Name: WD-40 Aerosol
Product Use: Cleaner, Lubricant, Penetrant
MSDS Date Of Preparation: 5/16/07

2 – Hazards Identification
Emergency Overview:
DANGER! Harmful of fatal if swallowed. Flammable aerosol. Contents under pressure. Avoid eye
contact. Use with adequate ventilation. Keep away from heat, sparks and all other sources of
ignition.
Symptoms of Overexposure:
Inhalation: High concentrations may cause nasal and respiratory irritation and central nervous
system effects such as headache, dizziness and nausea. Intentional abuse may be harmful or
fatal.
Skin Contact: Prolonged and/or repeated contact may produce mild irritation and defatting with
possible dermatitis.
Eye Contact: Contact may be mildly irritating to eyes. May cause redness and tearing.
Ingestion: This product has low oral toxicity. Swallowing may cause gastrointestinal irritation,
nausea, vomiting and diarrhea. The liquid contents are an aspiration hazard. If swallowed, can
enter the lungs and may cause chemical pneumonitis.
Chronic Effects: None expected.
Medical Conditions Aggravated by Exposure: Preexisting eye, skin and respiratory conditions
may be aggravated by exposure.
Suspected Cancer Agent:
Yes
No X
3 - Composition/Information on Ingredients
Ingredient
Aliphatic Hydrocarbon

Petroleum Base Oil
LVP Aliphatic Hydrocarbon
Carbon Dioxide
Non-Hazardous Ingredients

CAS #
64742-47-8
64742-48-9
64742-88-7
64742-65-0
64742-47-8
124-38-9
Mixture

Weight Percent
45-50

15-25
12-18
2-3
<10

4 – First Aid Measures
Ingestion (Swallowed): Aspiration Hazard. DO NOT induce vomiting. Call physician, poison
control center or the WD-40 Safety Hotline at 1-888-324-7596 immediately.
Eye Contact: Flush thoroughly with water. Get medical attention if irritation persists.
Skin Contact: Wash with soap and water. If irritation develops and persists, get medical
attention.

Page 1 of 4

Inhalation (Breathing): If irritation is experienced, move to fresh air. Get medical attention if
irritation or other symptoms develop and persist.
5 – Fire Fighting Measures
Extinguishing Media: Use water fog, dry chemical, carbon dioxide or foam. Do not use water jet
or flooding amounts of water. Burning product will float on the surface and spread fire.
Special Fire Fighting Procedures: Firefighters should always wear positive pressure selfcontained breathing apparatus and full protective clothing. Cool fire-exposed containers with
water. Use shielding to protect against bursting containers.
Unusual Fire and Explosion Hazards: Contents under pressure. Aerosol containers may burst
under fire conditions. Vapors are heavier than air and may travel along surfaces to remote ignition
sources and flash back.
6 – Accidental Release Measures
Wear appropriate protective clothing (see Section 8). Eliminate all sources of ignition and
ventilate area. Leaking cans should be placed in a plastic bag or open pail until the pressure has
dissipated. Contain and collect liquid with an inert absorbent and place in a container for disposal.
Clean spill area thoroughly. Report spills to authorities as required.
7 – Handling and Storage
Handling: Avoid contact with eyes. Avoid prolonged contact with skin. Avoid breathing vapors or
aerosols. Use with adequate ventilation. Keep away from heat, sparks, hot surfaces and open
flames. Wash thoroughly with soap and water after handling. Do not puncture or incinerate
containers. Keep can away from electrical current or battery terminals. Electrical arcing can cause
burn-through (puncture) which may result in flash fire, causing serious injury. Keep out of the
reach of children.
Storage: Do not store above 120°F or in direct sunlight. U.F.C (NFPA 30B) Level 3 Aerosol.
8 – Exposure Controls/Personal Protection
Occupational Exposure Limits
Chemical
Aliphatic Hydrocarbon
100 ppm TWA (ACGIH)
1200 mg/m3 TWA (manufacturer recommended)
Petroleum Base Oil
5 mg/m3 TWA (OSHA/ACGIH)
LVP Aliphatic Hydrocarbon
1200 mg/m3 TWA (manufacturer recommended)
Carbon Dioxide
5000 ppm TWA (OSHA/ACGIH), 30,000 ppm STEL (ACGIH)
Non-Hazardous Ingredients
None Established
The Following Controls are Recommended for Normal Consumer Use of this Product
Engineering Controls: Use in a well-ventilated area.
Personal Protection:
Eye Protection: Avoid eye contact. Safety glasses or goggles recommended.
Skin Protection: Avoid prolonged skin contact. Chemical resistant gloves recommended for
operations where skin contact is likely.
Respiratory Protection: None needed for normal use with adequate ventilation.
For Bulk Processing or Workplace Use the Following Controls are Recommended
Engineering Controls: Use adequate general and local exhaust ventilation to maintain exposure
levels below that occupational exposure limits.
Personal Protection:
Eye Protection: Safety goggles recommended where eye contact is possible.
Skin Protection: Wear chemical resistant gloves.
Respiratory Protection: None required if ventilation is adequate. If the occupational exposure
limits are exceeded, wear a NIOSH approved respirator. Respirator selection and use should be

Page 2 of 4

based on contaminant type, form and concentration. Follow OSHA 1910.134, ANSI Z88.2 and
good Industrial Hygiene practice.
Work/Hygiene Practices: Wash with soap and water after handling.
9 – Physical and Chemical Properties
Boiling Point:
323°F (minimum)
Solubility in Water:
Insoluble
Vapor Pressure:
110 PSI @ 70°F
Percent Volatile:
74%
Coefficient of
Not Determined
Water/Oil Distribution:
Flash Point:
131°F (concentrate) Tag
Closed Cup

Specific Gravity:
pH:
Vapor Density:
VOC:
Appearance/Odor
Flammable
Limits: (Solvent
Portion)

0.817 @ 72°F
Not Applicable
Greater than 1
412 grams/liter (49.5%)
Light amber liquid/mild
odor
LEL: 1.1% UE:: 8.9%

10 – Stability and Reactivity
Stability: Stable
Hazardous Polymerization: Will not occur.
Conditions to Avoid: Avoid heat, sparks, flames and other sources of ignition. Do not puncture
or incinerate containers.
Incompatibilities: Strong oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide and carbon dioxide.
11 – Toxicological Information
The oral toxicity of this product is estimated to be greater than 5,000 mg/kg based on an
assessment of the ingredients. This product is not classified as toxic by established criteria. It is
an aspiration hazard.
None of the components of this product is listed as a carcinogen or suspected carcinogen or is
considered a reproductive hazard.
12 – Ecological Information
No data is currently available.
13 - Disposal Considerations
If this product becomes a waste, it would be expected to meet the criteria of a RCRA ignitable
hazardous waste (D001). However, it is the responsibility of the generator to determine at the
time of disposal the proper classification and method of disposal. Dispose in accordance with
federal, state, and local regulations.
14 – Transportation Information_
DOT Surface Shipping Description: Consumer Commodity, ORM-D
IMDG Shipping Description: Aerosols, 2, UN1950
15 – Regulatory Information
U.S. Federal Regulations:
CERCLA 103 Reportable Quantity: This product is not subject to CERCLA reporting
requirements, however, oil spills are reportable to the National Response Center under the Clean
Water Act and many states have more stringent release reporting requirements. Report spills
required under federal, state and local regulations.
SARA TITLE III:
Hazard Category For Section 311/312: Acute Health, Fire Hazard, Sudden Release of
Pressure

Page 3 of 4

Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA
Title III Section 313 Reporting requirements: None
Section 302 Extremely Hazardous Substances (TPQ): None
EPA Toxic Substances Control Act (TSCA) Status: All of the components of this product are
listed on the TSCA inventory
Canadian Environmental Protection Act: All of the ingredients are listed on the Canadian
Domestic Substances List or exempt from notification
Canadian WHMIS Classification: Class B-5 (Flammable Aerosol)
This MSDS has been prepared according to the criteria of the Controlled Products Regulation
(CPR) and the MSDS contains all of the information required by the CPR.
16 – Other Information:
HMIS Hazard Rating:
Health – 1 (slight hazard), Fire Hazard – 4 (severe hazard), Reactivity – 0 (minimal hazard)

SIGNATURE:

TITLE:

REVISION DATE: Revision Date: May 2007

Page 4 of 4

Director of Global Quality Assurance
SUPERSEDES: December 2004

3M MATERIAL SAFETY DATA SHEET 3M 16-102 QUICK DRYING CONTACT CLEANER

12/05/2005

Material Safety Data Sheet
Copyright, 2005, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M 16-102 QUICK DRYING CONTACT CLEANER
MANUFACTURER: 3M
DIVISION: Electrical Markets Division
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 12/05/2005
Supercedes Date: 08/15/2002
Document Group: 08-0837-8
Product Use:
Intended Use:
Limitations on Use:
Specific Use:

ELECTRICAL CONTACT CLEANER, QUICK DRYING AEROSOL
AVOID HEAT,FLAME, SPARKS AND LIVE ELECTRICAL POWER.
QUICK DRYING CONTACT CLEANER

SECTION 2: INGREDIENTS
Ingredient

C.A.S. No.

HEPTANE
ETHYL ALCOHOL
ISOPROPYL ALCOHOL
CYCLOHEXANE
PROPANE

142-82-5
64-17-5
67-63-0
110-82-7
74-98-6

% by Wt
45 - 55
3 - 12
6 - 12
2 - 10
20

Minute quantities of the substances listed below may be emitted during Normal Use:
Substance
Hydrocarbons

Condition
Normal Use

SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Compressed Gas
Odor, Color, Grade: hydrocarbon odor, clear.
_________________________________________________________________________________________________
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3M MATERIAL SAFETY DATA SHEET 3M 16-102 QUICK DRYING CONTACT CLEANER

12/05/2005

General Physical Form: Liquid
Immediate health, physical, and environmental hazards: Flammable liquefied gas. Aerosol container contains flammable gas
under pressure. Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor.
Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol container contains
flammable material under pressure.
May cause target organ effects. Contains a chemical or chemicals which can cause
birth defects or other reproductive harm.

3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.

Skin Contact:
Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
May be absorbed through skin and cause target organ effects.

Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Intentional concentration and inhalation may be harmful or fatal.
May be absorbed following inhalation and cause target organ effects.

Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May be absorbed following ingestion and cause target organ effects.

Target Organ Effects:
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.

Prolonged or repeated exposure may cause:
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
jaundice.
Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased
protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination.

Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
Carcinogenicity:
NOTE: This product contains ethanol. In IARC published Monograph No. 44, entitled, "Alcohol Drinking", the carcinogenicity of
ethanol was determined based on chronic exposure to ethanol through human consumption of alcoholic beverages. This is not an
expected effect during the foreseeable use of this product.

_________________________________________________________________________________________________
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3M MATERIAL SAFETY DATA SHEET 3M 16-102 QUICK DRYING CONTACT CLEANER

Ingredient
ETHYL ALCOHOL

3.3

C.A.S. No.
64-17-5

Class Description
Group 1

12/05/2005

Regulation
International Agency for Research on Cancer

POTENTIAL ENVIRONMENTAL EFFECTS

The KOWWIN program estimates Log Pow, the logarithm of the octanol-water partition coefficient, Pow. Log Pow is a physical
property used to describe a substance's lipophilic or hydrophobic properties. Syracuse Research Corporation developed the KOWWIN
program. The components labeled "Highly volatile" are expected to be rapidly removed from the aquatic and terrestrial compartments
by vaporization. The high potential of this substance to move from water to the atmosphere means its toxicity is likely to disappear
rapidly from aerobic environments. The components labeled "readily biodegradable" are expected to fully degrade in wastewater
treatment and in most aerobic water or soil environments. Tests that strongly promote biodegradation show that the components
labeled "inherently biodegradable" underwent >20% biodegradation but may not fully biodegrade. There is insufficient component
information to calculate the ecotoxicity of this product. The components labeled "Log Kow <3" have measured or calculated log Kow
values <3 indicating they are unlikely to bioconcentrate to high concentrations in aquatic organisms by partitioning into lipid tissues.
The components labeled "Log Kow > or = 3" have measured or calculated log Kow values of > or = 3 indicating they have a potential
to bioconcentrate to high concentrations in aquatic organisms by partitioning into lipid tissues. Labelled Components: Readily
Biodegradable - Heptane (110-54-3), Ethyl Alcohol (64-17-5);
Highly Volatile - Isopropyl Alcohol (67-63-0);
Inherently biodegradable - Cyclohexane (110-82-7)
Log Kow < 3: Isopropyl Alcohol (67-63-0); Ethyl Alcohol (64-17-5); Propane (74-98-6)
Log Kow > 3: Heptane (110-54-3); Cyclohexane (110-82-7)

SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact:

Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.

Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air.

If signs/symptoms develop, get medical attention.

If Swallowed:
Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.

SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Autoignition temperature
Flash Point
Flammable Limits - LEL
Flammable Limits - UEL
OSHA Flammability Classification:

No Data Available
<=0 ºF
1.1 % volume
19.0 % volume
Class IB Flammable Liquid

5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). If water is used, fog nozzles are
preferred. Water may be used to cool containers to prevent pressure build-up and possible autoignition or explosion when exposed to
_________________________________________________________________________________________________
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3M MATERIAL SAFETY DATA SHEET 3M 16-102 QUICK DRYING CONTACT CLEANER

12/05/2005

extreme heat.

5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed
containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained
breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Flammable liquefied gas. Closed containers exposed to heat from fire may build pressure
and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source
and flash back. Aerosol container contains flammable material under pressure.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.

SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards,
respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information
on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up
by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only nonsparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to
disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and
could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. If possible, seal leaking container. Place
leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface
until appropriate packaging for the leaking container or its contents is available. Cover spill area with a fire-extinguishing foam
designed for use on solvents, such as alcohols and acetone, that can dissolve in water. An AR - AFFF type foam is recommended.
Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent
material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic,
corrosivity or flammability hazard. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue
with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety
precautions on the solvent label and MSDS. Place in a metal container approved for transportation by appropriate authorities.
Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.

SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Contents may be under
pressure, open carefully. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Ground containers
securely when transferring contents. Wear low static or properly grounded shoes. Do not pierce or burn container, even after use. Do
not spray near flames or sources of ignition. Aerosol container contains flammable gas under pressure. Avoid breathing of airborne
material. Avoid static discharge. Avoid eye contact with vapors, mists, or spray. For industrial or professional use only. Avoid
contact with oxidizing agents.

7.2 STORAGE
Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Keep container
tightly closed. Store away from oxidizing agents.

_________________________________________________________________________________________________
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3M MATERIAL SAFETY DATA SHEET 3M 16-102 QUICK DRYING CONTACT CLEANER

12/05/2005

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Do not use in a confined area or areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilation
to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not
adequate, use respiratory protection equipment.

8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray.
The following eye protection(s) are recommended: Indirect Vented Goggles.
8.2.2 Skin Protection
Avoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Fluoroelastomer (Viton).
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray.
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Half facepiece or fullface pressure demand self-contained breathing apparatus. Consult the current 3M
Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.

8.3 EXPOSURE GUIDELINES
Ingredient

Authority

Type

Limit

CYCLOHEXANE
CYCLOHEXANE
ETHYL ALCOHOL
ETHYL ALCOHOL
HEPTANE
HEPTANE
HEPTANE
HEPTANE
HEPTANE
ISOPROPYL ALCOHOL
ISOPROPYL ALCOHOL
ISOPROPYL ALCOHOL
ISOPROPYL ALCOHOL
PROPANE
PROPANE

ACGIH
OSHA
ACGIH
OSHA
ACGIH
ACGIH
OSHA
OSHA
OSHA
ACGIH
ACGIH
OSHA
OSHA
ACGIH
OSHA

TWA
TWA
TWA
TWA
TWA
STEL
TWA, Vacated
TWA
STEL, Vacated
TWA
STEL
TWA
STEL
TWA
TWA

100 ppm
300 ppm
1000 ppm
1000 ppm
400 ppm
500 ppm
400 ppm
500 ppm
500 ppm
200 ppm
400 ppm
400 ppm
500 ppm
1000 ppm
1000 ppm

Additional Information
Table Z-1
Table A4
Table Z-1

Table Z-1
Table A4
Table A4
Table Z-1A
Table Z-1A
Table Z-1

VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local
regulatory agency.
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)

_________________________________________________________________________________________________
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3M MATERIAL SAFETY DATA SHEET 3M 16-102 QUICK DRYING CONTACT CLEANER

12/05/2005

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Specific Physical Form:
Odor, Color, Grade:
General Physical Form:
Autoignition temperature
Flash Point
Flammable Limits - LEL
Flammable Limits - UEL
Boiling point

Compressed Gas
hydrocarbon odor, clear.
Liquid
No Data Available
<=0 ºF
1.1 % volume
19.0 % volume
0 - 212 ºF

Vapor Density

>=1 [Ref Std: AIR=1]

Vapor Pressure

33 - 760 mmHg

Specific Gravity
pH
Melting point
Solubility In Water

0.67 [Ref Std: WATER=1]
No Data Available
Not Applicable
Approximately 20 % weight

Evaporation rate
Volatile Organic Compounds
Percent volatile
VOC Less H2O & Exempt Solvents
Viscosity

>=1 [Ref Std: ETHER=1]
100 % weight
100 % volume
670 g/l
No Data Available

SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Sparks and/or flames; Heat; Strong oxidizing agents; ***Missing Data -Materials/Condition to
Avoid***

Hazardous Polymerization: Hazardous polymerization will not occur.

Hazardous Decomposition or By-Products
Substance

Condition

Acetic Acid
Aldehydes
Carbon monoxide
Carbon dioxide

Oxidative Degradation
Heat
During Combustion
During Combustion

SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.

_________________________________________________________________________________________________
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3M MATERIAL SAFETY DATA SHEET 3M 16-102 QUICK DRYING CONTACT CLEANER

12/05/2005

SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
See Section 3.3

CHEMICAL FATE INFORMATION
See Section 3.3

SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. Facility must be capable of handling aerosol cans.
Dispose of empty product containers in a sanitary landfill.
As a disposal alternative, dispose of waste product in a permitted hazardous waste facility.

EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
Since regulations vary, consult applicable regulations or authorities before disposal.

SECTION 14:TRANSPORT INFORMATION
ID Number(s):
80-6109-2788-3

Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.

SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.

311/312 Hazard Categories:
Fire Hazard - Yes Pressure Hazard - Yes

Reactivity Hazard - No

Immediate Hazard - Yes

Delayed Hazard - Yes

Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient

C.A.S. No

CYCLOHEXANE

110-82-7

% by Wt
2 - 10

This material contains a chemical which requires export notification under TSCA Section 12[b]:
Ingredient (Category if applicable)

C.A.S. No

Regulation

Status

_________________________________________________________________________________________________
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3M MATERIAL SAFETY DATA SHEET 3M 16-102 QUICK DRYING CONTACT CLEANER

CYCLOHEXANE

110-82-7

HEPTANE

142-82-5

12/05/2005

Toxic Substances Control Act (TSCA) 4 Test
Rule Chemicals
Toxic Substances Control Act (TSCA) 4 Test
Rule Chemicals

Applicable
Applicable

STATE REGULATIONS
Contact 3M for more information.

CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.
Contact 3M for more information.

INTERNATIONAL REGULATIONS
Contact 3M for more information.

WHMIS: Hazardous

This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 4 Reactivity: 0 Special Hazards: None
Aerosol Storage Code: 3
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.

HMIS Hazard Classification
Health: 2 Flammability: 4

Reactivity: 0

Protection: A

Hazardous Material Identification System (HMIS(r)) hazard ratings are designed to inform employees of chemical hazards in the workplace. These
ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency
situations. HMIS(r) ratings are to be used with a fully implemented HMIS(r) program. HMIS(r) is a registered mark of the National Paint and
Coatings Association (NPCA).

_________________________________________________________________________________________________
Page 8 of 10

3M MATERIAL SAFETY DATA SHEET 3M 16-102 QUICK DRYING CONTACT CLEANER

Reason for Reissue:

12/05/2005

Update to new format.

Revision Changes:
Section 16: NFPA hazard classification heading was modified.
Section 16: HMIS hazard classification heading was modified.
Section 16: NFPA hazard classification for health was modified.
Section 3: Carcinogenicity heading was modified.
Section 3: Potential environmental effects heading was modified.
Section 3: Other potential health effects heading was modified.
Section 1: Division name was modified.
Section 2: Normal use heading was modified.
Copyright was modified.
Section 8: Exposure guidelines data source legend was modified.
Section 3: Immediate physical hazard(s) was modified.
Section 3: Potential effects from eye contact was modified.
Section 3: Potential effects from skin contact information was modified.
Section 3: Potential effects from inhalation information was modified.
Section 3: Potential effects from ingestion information was modified.
Section 3: Potential environmental effects information was modified.
Section 5: Fire fighting procedures information was modified.
Section 5: Unusual fire and explosion hazard information was modified.
Section 7: Handling information was modified.
Section 7: Storage information was modified.
Section 8: Engineering controls information was modified.
Section 8: Eye/face protection phrase was modified.
Section 8: Respiratory protection - recommended respirators information was modified.
Section 15: 311/312 hazard categories heading was modified.
Section 15: International regulations information was modified.
Section 15: State regulations information was modified.
Section 15: US federal regulations information was modified.
Section 4: First aid for skin contact - decontamination - was modified.
Section 4: First aid for skin contact - medical assistance - was modified.
Section 4: First aid for ingestion (swallowing) - decontamination - was modified.
Section 4: First aid for ingestion (swallowing) - medical assistance - was modified.
Section 10: Hazardous polymerization heading was modified.
Section 3: Carcinogenicity phrase was modified.
Section 3: Immediate other hazard(s) was modified.
Section 2: Ingredient table was modified.
Section 15: TSCA section 12[b] text was modified.
Section 3: Other health effects information was modified.
Section 16: HMIS explanation was modified.
Section 16: NFPA explanation was modified.
Section 15: Inventories information was modified.
Section 15: EPCRA 313 text was modified.
Section 12: Ecotoxicological information heading was modified.
Section 12: Chemical fate information heading was modified.
Section 8: Exposure guidelines ingredient information was modified.
Section 8: Exposure guidelines legend was modified.
Section 9: Property description for optional properties was modified.
Section 16: NFPA hazard classification for special hazards was modified.
Section 16: NFPA hazard classification for aerosol storage was modified.
Section 15: TSCA section 12[b] information was modified.
Section 16: Reason for reissue comment was added.
Section 15: WHMIS regulations heading was added.
Section 15: WHMIS regulations information was added.
_________________________________________________________________________________________________
Page 9 of 10

3M MATERIAL SAFETY DATA SHEET 3M 16-102 QUICK DRYING CONTACT CLEANER

12/05/2005

Section 4: First aid for skin contact - termination of exposure - was added.
Section 4: First aid for skin contact - handling - was added.
Section 2: Ingredient phrase was added.
Section 3: Other health effects information (reproductive hazards) was added.
Section 16: Reason for reissue heading was added.
Section 12: Ecotoxicological information comment was added.
Section 12: Chemical Fate information comment was added.
Section 12: Ecotoxicological ecotox article information was deleted.
Section 12: Ecotoxicological ecofate information was deleted.

DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.

3M MSDSs are available at www.3M.com

_________________________________________________________________________________________________
Page 10 of 10

Faultless® Rust Buster
MSDS Number: 16800

Page 1
June 29, 2007

________________________________________
MATERIAL SAFETY DATA SHEET
1.

MANUFACTURER / PRODUCT IDENTIFICATION
______________________
Product Identification
Product Name:
Faultless® Rust Buster
Product Number:
16800
______________________
Company Identification
Faultless Starch / Bon Ami Co.
1025 W 8th Street
Kansas City, MO
64101
1-816-842-1230 (For product information)
1-800-424-9300 or 1-703-527-3887 (For emergencies)
Reason For Issue...:
Prepared By........:
Approved By........:
Title..............:
Approval Date......:
Supercedes Date....:
MSDS Number........:
RTN Number.........:

Update emergency contact
Bill Wood
Bill Wood
Technical Director
June 29, 2007
October 14, 2004
16800
00016800 (Official Copy)

*****************
EMERGENCY OVERVIEW
*****************
*
*
* May Cause Chemical Burns.
*
*
*
**********************************************************

NFPA Rating:
Health - 3, Flammability - 0, Reactivity - 0

2.

HAZARDOUS INGREDIENTS
_____________
Chemical Name
INGREDIENTS ARE PROPRIETARY

________
Amount
Confidential

COMPOSITION COMMENT:
The ingredients in this product are considered proprietary.
emergency, contact Info Trac. 1-800-535-5053.
EXPOSURE GUIDELINES:
No Information Available.

__________
CAS Number

In case of

Faultless® Rust Buster
Page 2
MSDS Number: 16800
June 29, 2007
____________________________________________________________________________________________________

3.

PHYSICAL / CHEMICAL CHARACTERISTICS
FORM ..................:
COLOR .................:
ODOR ..................:
BOILING POINT .........:
VAPOR PRESSURE ........:
SOLUBILITY IN WATER ...:
SPECIFIC GRAVITY ......:
BULK DENSITY ..........:
PH ....................:

4.

Liquid
Clear
acid
>200 F
<0.01 mm Hg
Complete
1.038 (Water = 1)
8.659 lb/gl
4.5 (1% solution in water)

FIRE AND EXPLOSION HAZARD DATA
FLAMMABLE PROPERTIES
COC Flash Point: N/A
Autoignition Temperature:

N/A

FLAMMABLE LIMITS IN AIR
LEL: N/A
UEL: N/A
FLAMMABLE PROPERTIES:
Active ingredient is not flammable, but packaging material will burn.
EXTINGUISHING MEDIA:
BC/ABC extinguisher may be used in area where material is stored.
SPECIAL FIRE FIGHTING PROCEDURES:
As in any fire, wear self-contained breathing apparatus pressure-demand
MSHA/NIOSH (approved or equivalent) and full protective gear.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
In case of fire, highly corrosive gasses may be emitted.

5.

REACTIVITY DATA
STABILITY:
Stable.
INCOMPATIBILITY (MATERIALS TO AVOID):
Glass, silicon compounds; alkali.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS:
Highly corrosive fumes.
HAZARDOUS POLYMERIZATION:
Will not occur.

Faultless® Rust Buster
Page 3
MSDS Number: 16800
June 29, 2007
____________________________________________________________________________________________________

6.

HEALTH HAZARD DATA
INHALATION RISKS AND SYMPTOMS OF EXPOSURE:
May cause respiratory irritation, osteofluorosis, and respiratory
impairment.
SKIN / EYE CONTACT RISKS AND SYMPTOMS OF EXPOSURE:
Corrosive to the skin and eyes.
SKIN ABSORPTION RISKS AND SYMPTOMS OF EXPOSURE:
Skin contact can cause a burning sensation and dermatitis.
INGESTION RISKS AND SYMPTOMS OF EXPOSURE:
May be fatal if swallowed.
HEALTH HAZARDS (ACUTE AND CHRONIC):
Material may cause severe chemical burns upon prolonged contact, poisoning
if injested.
EYE CONTACT FIRST AID:
Remove any contact lenses and flush with water for at least 15 minutes.
Get immediate medical attention.
SKIN CONTACT FIRST AID:
Immediately flush skin with plenty of water. Remove contaminated
clothing. Thoroughly wash (or discard) clothing and shoes before reuse.
INHALATION FIRST AID:
Remove to fresh air. Seek immediate medical attention.
INGESTION FIRST AID:
Rinse mouth at once, then drink 1 or 2 glasses of water or milk. DO NOT
induce vomiting. NEVER give anything by mouth to an unconscious person.
Get medical attention.

7.

PRECAUTIONS FOR SAFE HANDLING AND USE
ACTIONS IF MATERIAL IS RELEASED OR SPILLED:
Stop leak. Contain spill. Absorb with an inert material and place in a
suitable container. Flush spill area with large amounts of water.
WASTE DISPOSAL METHOD:
Dispose of in accordance with federal, state and local regulations.
MISCELLANEOUS:
Dispose of wash water and spill byproducts according to State and Federal
regulations.

Faultless® Rust Buster
Page 4
MSDS Number: 16800
June 29, 2007
____________________________________________________________________________________________________

(section 7 continued)
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
Store in a cool, dry area. Do not allow product to freeze.
eyes, on skin or clothing. Do not take internally.

8.

Do not get in

CONTROL MEASURES
RESPIRATORY PROTECTION:
Not required.
VENTILATION:
Local exhaust to take vapor away from user.
PROTECTIVE GLOVES:
Rubber gloves recommended.
EYE PROTECTION:
Wear approved safety glasses/goggles.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT:
To prevent skin contact, wear impervious clothing and boots.
WORK / HYGIENIC PRACTICES:
Observe reasonable care, cleanliness, and caution.

9.

TRANSPORTATION INFORMATION
PRODUCT LABEL..........:
D.O.T. SHIPPING NAME...:
D.O.T. HAZARD CLASS....:
UN NUMBER..............:
PACKAGE CLASS..........:

10.

Faultless® Rust Buster
Consumer Commodity
ORM-D
N/A
III

REGULATORY INFORMATION
CHEMICAL INVENTORY INFORMATION:
This material or all of its components are listed on the Inventory of
Existing Chemical Substances under the Toxic Substance Control Act (TSCA).

11.

DISCLAIMER

Faultless® Rust Buster
Page 5
MSDS Number: 16800
June 29, 2007
____________________________________________________________________________________________________

**********************************************************************
The information accumulated herein is believed to be accurate but is not
warranted to be whether originating with the company or not. Recipients
are advised to confirm in advance of need that the information is
current, applicable and suitable to their circumstances.
**********************************************************************
END OF MSDS
**********************************************************************

Wednesday, February 27, 2008

Page 1 of 5

MSDS - Material Safety Data Sheet
Product Name: LIQUID WRENCH PENETRATING OIL
MSDS No.: L106

I. Basic Information:
Manufacturer: RADIATOR SPECIALTY COMPANY

Contact: Robert Geer

Address: 600 RADIATOR ROAD

Information Telephone Number: 704-684-1811

City, ST Zip: INDIAN TRAIL, NC 28079

Emergency Contact: Rocky Mountain Poision Control Center

Country:

Emergency Telephone Number: 303-623-5716
Emergency Restrictions:

Product Name: LIQUID WRENCH PENETRATING OIL
MSDS No.: L106

Issue Date: 02/19/2008
Supersedes Date: 10/12/2006

II. Hazards Identification:
EMERGENCY OVERVIEW
Danger: Flammable. Harmful or fatal if swallowed. Eye and skin irritant. Contents under pressure.
Level 3 Aerosol
OSHA Regulatory Status
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Potential Health Effects

Route(s) of Entry:
Absorption, Inhalation, and Ingestion.

Health Hazards (Acute and Chronic):
N/D

Signs and Symptoms:
Eye Contact: Irritant. Prolonged contact may cause conjunctivitis.
Skin Contact: Irritant. Defatting of tissue, dermatitis may occur.
Inhalation: Irritant to mucous membranes. Repeated exposure may cause narcosis, dizziness, respiratory or lung irritation.
Ingestion: HARMFUL OR FATAL IF SWALLOWED. May cause burns to mouth, throat & stomach.
Medical Conditions Generally Aggravated by Exposure:
N/D

Other Health Warnings:
Vomiting and subsequent aspiration into the lungs may lead to chemical pneumonia and pulmonary edema which is a potentially fatal condition.
Potential Environmental Effects
Not Available

III. Composition/Information on Ingredients:
Chemical Name

CAS No.

% Range

Carbon dioxide

124-38-9

1.0 - 5.0

Fragrance

Proprietary

0.1 - 1.0

Kerosene

8008-20-6

40.0 - 70.0

Naphthenic Petroleum Distillate

64742-52-5

15.0 - 40.0

Solvent-Refined Heavy Paraffinic

64741-88-4

0.1 - 1.0

IV. First Aid Measures:
Emergency and First Aid Procedures:

Trade Secret

Wednesday, February 27, 2008

Page 2 of 5

MSDS - Material Safety Data Sheet
Product Name: LIQUID WRENCH PENETRATING OIL
MSDS No.: L106
Eye Contact: Flush eyes with clean water for 15 minutes while lifting eyelids. Get prompt medical attention.
Skin Contact: Wash with soap and water thoroughly. If adverse effects persist, get prompt medical attention. Launder contaminated clothing
before reuse.
Inhalation: Remove to fresh air. If breathing becomes difficult give oxygen and get prompt medical attention. If breathing stops, give artificial
respiration and get prompt medical attention.
Ingestion: DO NOT INDUCE VOMITING! Call Poison Control Center, physician, or hospital emergency room immediately. Aspiration of vomitus
into the lungs can cause pneumonitis, which can be fatal.
Note to Physicians:
N/E

V. Fire Fighting Measures:
Suitable Extinguishing Media:
Water Fog, Foam, Carbon Dioxide, Dry Chemical
Unsuitable Extinguishing Media:
Do not use forced water stream as this could cause the fire to spread.
Products of Combustion:
Normal products of combustion, smoke, carbon dioxide, carbon monoxide, and sulfur trioxides.
Protection of Firefighters:
Wear self-contained positive pressure breathing apparatus and protective clothes. Use shield to protect from rupturing and venting containers. At
elevated temperatures containers may vent, rupture or burst, even violently

VI. Accidental Release Measures:
Personal Precautions:
Eliminate all ignition sources. Persons not wearing protective equipment should be excluded from area of spill until clean up has been completed.
Environmental Precautions:
Prevent run-off to sewers, streams, or other bodies of water. If run-off occurs, notify proper authorities as required that a spill has occurred. Run off
to sewer may create fire or explosion hazard.
Methods for Containment:
Dike or contain spill and absorb with inert materials (sand, sawdust, absorbent sweeping compounds, rags, etc).
Methods for Cleanup:
Using a non-metalic scoop, place contaminated material into an approved chemical waste container. Where possible, vacuum spilled liquid using
an explosion proof vacuum to recover material.
Other Information:
All equipment used with handling the concentrate must be grounded. If run-off occurs, notify proper authorities as required that a spill has occurred.

VII. Handling and Storage:
Handling Precautions:
Use with adequate ventilation and proper protective equipment.
Do not use or store near fire, sparks, or open flame. Do not puncture or incinerate container. Exposure to sunlight and temperatures above 120°
may cause container to vent, rupture, or burst.
Storage Precautions:
Do not used in confined area without proper ventilation. Contact lenses may cause further damage in case of splash into eye. KEEP AWAY FROM
CHILDREN AND ANIMALS! Danger: Flammable.

VIII. Exposure Controls/Personal Protection:

Wednesday, February 27, 2008

Page 3 of 5

MSDS - Material Safety Data Sheet
Product Name: LIQUID WRENCH PENETRATING OIL
MSDS No.: L106
Chemical Name

OSHA PEL

ACGIH TLV

Other Limits

Kerosene

N/AV

100 ppm

Not Available

Naphthenic Petroleum Distillate

5 mg/m3

5 mg/m3

Not Available

Solvent-Refined Heavy Paraffinic

5 mg/m3

5 mg/m3

Not Available

Fragrance

N/D

N/D

Not Available

Carbon dioxide

N/AV

5000 ppm

Not Available

Engineering Controls:
Use with adequate ventilation. If TLV is exceeded, wear NIOSH approved respirator.

Personal Protective Equipment:
See Section 2 for applicable exposure limits. For prolonged exposure wear protective safety glasses, gloves, and apron.

IX. Physical and Chemical Properties:
Boiling Point: 320 F

Melting Point: N/A

Boiling Range: Not Available

Freezing Point: Not Available

Solubility In Water: Insoluble

Evaporation Rate (Butyl Acetate = 1): N/A

Flash Point: 132F

Flash Point Method: TCC

Odor Threshold: Not Available

Appearance and Odor: Dark Liquid with petroleum odor

Vapor Density (AIR = 1): N/A

Vapor Pressure (mm Hg.): N/A

pH Range: Not Available
Decomposition Temp:

Not Available

Lower Explosive Limit: 0.7%

Partition Coefficient:

Upper Explosive Limit: 5%

Specific Gravity (H20 = 1): 0.85
Other Information: VOC Content: 36.938

X. Stability and Reactivity:
Stability:
Product is stable
Conditions to Avoid:
See Incompatible Materials below
Incompatible Materials:
Avoid contact with strong oxidizers
Hazardous Decomposition Products:
Normal products of combustion, smoke, carbon dioxide, carbon monoxide, and sulfur trioxides.
Possibility of Hazardous Reactions:
Will not occur

XI. Toxicological Information:
N/D

XII. Ecological Information:
N/D

Not Available

Auto-Ignition Temp: Not Available

Wednesday, February 27, 2008

Page 4 of 5

MSDS - Material Safety Data Sheet
Product Name: LIQUID WRENCH PENETRATING OIL
MSDS No.: L106

XIII. Disposal Considerations:
DISPOSAL: This container may be recycled in aerosol recycling centers when empty. Before offering for recycling, empty the can by using the
product according to the label. DO NOT PUNCTURE! If recycling is not available, wrap the container and discard in the trash. Dispose of unused
product in accordance with all local, state government and federal laws and regulations.

XIV. Transport Information:
Shipping Name: Not Available
DOT Hazard Class: Not Available

DOT Subsidiary Hazard Class: Not Available

UN/NA#: Not Available

Packing Group:

Not Available

Transportation Information:
DOT Hazard Class: ORM-D
Shipping Name: Consumer Commodity

The DOT description is provided to assist in the proper shipping classification of this product and may not be suitable for international and air
shipping purposes.
ICAO/IATA (US)
Shipping Name: Aerosols
Class: 2.1
UN number: UN1950
International:
ICAO/IATA
UN number: UN1950
Shipping Name: Aerosols
Class: 2.1

IMDG
UN number: UN1950
Shipping Name: Aerosols
Class: 2.
EmS: F-D, S-U

XV. Regulatory Information:
See Section 2 for SARA Reportable Chemicals.
USA TSCA: All components of this material are listed on the US TSCA Inventory.
Warning: This product contains a chemical(s) known to the State of California to cause cancer or birth defects or other reproductive harm.

XVI. Other Information:
Chemical State:

X

Chemical Type:

Liquid

Gas

Pure

X

Mixture

Chronic

X

Fire

Solid

2

Hazard Category:

X

2

Acute

X

Pressure

Reactive

Additional Manufacturer Warnings:

Do not used in confined area without proper ventilation. Contact lenses
may cause further damage in case of splash into eye. KEEP AWAY FROM
CHILDREN AND ANIMALS!

2

N/E: Not Established
N/D: Not Determined
N/A: Not Applicable
N/AV: Not Available

0

2

C

0

Wednesday, February 27, 2008

Page 5 of 5

MSDS - Material Safety Data Sheet
Product Name: LIQUID WRENCH PENETRATING OIL
MSDS No.: L106
Additional Product Information:

While Radiator Specialty Company believes this data is accurate as of the revision date, we make no warranty with respect to the
data and we expressly disclaim all liability for reliance thereon. The data is offered solely for information, investigation, and
verification. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or
disposal of this product which may not be covered by this MSDS. The user is responsible for full compliance.

DOW CORNING CORPORATION
Fiche Signalétique
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Version: 1.4
Date de révision: 2007/06/27

MOLYKOTE(R) 557 SILICONE DRY FILM LUBRICANT
1. IDENTIFICATION DU PRODUIT ET DE LA SOCIETE
No. de la F.S.: 02410885
Préparé par Product Safety: (800) 248-2481
NEWALTA: (800) 567-7455
Date de révision: 2007/06/27

NOM DU FOURNISSEUR:
Dow Corning Canada Inc.
15-6400 Millcreek Drive, Suite 416
Mississauga, ON, Canada L5N 3E7

Téléphone d'urgence 24 heures: (989) 496-5900

NOM DU FABRICANT:
Dow Corning Corporation
South Saginaw Road
Midland, Michigan 48686

CLASSIFICATION SIMDUT: Catégorie B, Division 3.
Catégorie D, Division 2B.
Utilisation du Produit: Lubrifiant

2. IDENTIFICATION DES DANGERS
MESURES D'URGENCE GENERALES
Description Générique:
Etat Physique:
Couleur:
Odeur:

Silicone dans solvant.
Liquide.
Incolore.
Solvant.

++++++++++++++++++++++++++++++++++++++++++++
EFFETS SUR LA SANTE POTENTIELS
Effets aigus
Yeux:

Le contact direct peut causer une légère irritation. Les vapeurs peuvent entraîner l'irritation
des yeux.

Peau:

Aucune irritation significative n'est prévue à la suite d'une seule exposition à court terme.

Inhalation:

Les vapeurs peuvent irriter le nez et la gorge. La surexposition par inhalation peut causer la
somnolence, des étourdissements, de la confusion ou une perte de coordination.

Ingestion:

L'aspiration de liquide au moment de vomir peut causer de graves lésions aux poumons.

Effets suite a une exposition répétée/prolongée

DOW CORNING CORPORATION
Fiche Signalétique
Page: 2 de 8
Version: 1.4
Date de révision: 2007/06/27

MOLYKOTE(R) 557 SILICONE DRY FILM LUBRICANT
Peau:

Le contact répété ou prolongé peut causer le dégraissage ou l'assèchemenent de la peau, ce
qui peut entraîner une irritation cutanée et une dermatite.

Inhalation:

Aucun renseignement applicable connu.

Ingestion:

L'ingestion ou la déglutition répétée de grandes quantités peut causer des lésions internes.

Signes et Symptômes d'une surexposition
Aucun renseignement applicable connu.
Certains Malaises et Maladies sont aggravés par suite d'une exposition
Aucun renseignement applicable connu.
Les effets potentiels d'une surexposition énumérés ci-dessus sont fondés sur des données et des résultats d'études menées sur des
compositions similaires, des données portant sur les composants et/ou des études d'experts menées sur le produit. Veuillez vous
référer à la section 11 pour connaître le détail des renseignements d'ordre toxicologique.

3. COMPOSITION/INFORMATION SUR LES INGRÉDIENTS
Numéro de CAS

Pds (%)

Nom du composant

8052-41-3

> 60.0

Solvant Stoddard

108-11-2

3.0 - 7.0

4-Méthylpentane-2-ol

Les ingrédients énumérés ci-dessus sont des produits contrôlés selon le Règlement sur les produits contrôlés (RPC)
modifié. SOR/88-555.

4. PREMIERS SECOURS
Yeux:

Rincer immédiatement à grande eau pendant 15 minutes.

Peau:

Retirer de la peau et bien laver à l'eau et au savon ou à l'aide de détergent à sec. Consulter
un médecin si l'irritation ou d'autres malaises se développent ou persistent.

Inhalation:

Amener la personne à l'air frais. Consulter un médecin si les malaises persistent.

Ingestion:

Consulter un médecin immédiatement. Ne provoquer le vomissement que sur instruction
d'un médecin. Ne jamais donner quoi que ce soit par voie orale à une personne inconsciente.

Notes au médecin:

Traiter selon l'état de la personne et les conditions d'exposition.

5. MESURES DE LUTTE CONTRE L'INCENDIE
Point d'éclair:

103.1 °F / 39.5 °C (Coupelle fermée)

DOW CORNING CORPORATION
Fiche Signalétique
Page: 3 de 8
Version: 1.4
Date de révision: 2007/06/27

MOLYKOTE(R) 557 SILICONE DRY FILM LUBRICANT
Auto-Inflammation:

Pas disponible.

Limites D'inflammabilité
dans l'air:

Pas disponible.

Moyens d'extinction:

Pour les gros incendies, utiliser de la poudre extinctrice, de la mousse ou de l'eau pulvérisée.
Pour les petits incendies, utiliser du dioxyde de carbone (CO2), de la poudre extinctrice ou de
l'eau pulvérisée. L'eau peut être utilisée pour refroidir les récipients exposés au feu.

Mesures de lutte contre
l'incendie:

Il convient de porter un appareil respiratoire autonome et des vêtements de protection pour
combattre de gros incendies de produits chimiques. Pulvériser avec de l'eau les conteneurs
exposés au feu afin de les maintenir froids. Déterminer la nécessité d'évacuer ou d'isoler la
zone en accord avec le plan d'urgence en vigueur.

Risques d'incendie
inhabituels:

L'électricité statique s'accumulera et peut enflammer les vapeurs. Prévenir les risques
d'incendie en procédant à la métallisation et à la mise à la terre ou à la purge des gaz inertes.

6. MESURES À PRENDRE EN CAS DE DISPERSION ACCIDENTELLE
Retenue/Nettoyage:

Eliminer toutes les sources possibles d'ignition. Procéder à l'évacuation ou à l'isolation de la
zone conformément à la procédure d'urgence locale. Respecter toutes les recommandations
liées au matériel de protection personnelle (décrites aux sections 5 et 8). Pour les
déversements importants, installer des digues au d'autres méthodes de confinement pour
empêcher la propagation du produit. Si le produit confiné par des digues peut être pompé,
entreposer le produit récupéré dans un contenant approprié. Nettoyez les substances
restantes du déversement à l'aide d'un absorbant approprié. Nettoyer la zone de façon
appropriée puisque certains produits de silicone, méme en petites quantités, peuvent
présenter un risque de dérapage. Le nettoyage final peut exiger l'utilisation de vapeur, de
solvants ou de détergents. Éliminer l'absorbant ou les produits de nettoyage saturés de façon
appropriée, puisqu'une combustion spontanée peut se produire. Des lois et des règlements
locaux, provinciaux et fédéraux peuvent s'appliquer aux déversements et à l'élimination de ce
produit et des produits et des articles utilisés pour le nettoyage des déversements.

Note: Voir la section 8 sur l'équipement de protection personnelle sur les déversements. Appelez au (989) 496-5900,
pour de plus amples renseignements.
7. MANIPULATION ET STOCKAGE
Employer en présence d'un système de ventilation adéquate. Éviter le contact avec les yeux. Eviter tout contact avec la
peau. Ne pas inhaler les vapeurs, le brouillard, les poussières ou les fumées. Maintenir le contenant fermé. Ne pas
ingerer.
L'électricité statique s'accumulera et peut enflammer les vapeurs. Prévenir les risques d'incendie en procédant à la
métallisation et à la mise à la terre des contenants ou à la purge des gaz inertes. Maintenir le contenant fermé et le tenir
à l'abri de la chaleur, des étincelles et des flammes.

8. CONTROLE DE L'EXPOSITION / PROTECTION INDIVIDUELLE

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MOLYKOTE(R) 557 SILICONE DRY FILM LUBRICANT
Limite d'exposition du composant
Consultez les autorités locales afin d'obtenir les normes provinciales acceptables.
Numéro de CAS Nom du composant

Limites d'exposition

8052-41-3

Solvant Stoddard

OSHA PEL (final rule): TWA 500 ppm and ACGIH TLV:
TWA 100 ppm.
LD50: > 5,000 mg/kg - Ingestion Rat

108-11-2

4-Méthylpentane-2-ol

OSHA PEL (final rule)-skin: TWA 25 ppm and ACGIH
TLV-skin: TWA 25 ppm, STEL 40 ppm.
LD50:

Contrôles D'ngénierie
Ventilation du poste de
travail:
Ventilation générale:

Recommandé.
Recommandé.

Equipements de Protection Individuelle pour les Manipulations de Routine
Yeux:

Utiliser des lunettes à coques pour travailleur de l'industrie chimique.

Peau:

Se laver au moment des repas et à la fin des quarts de travail. Les vêtements et les souliers
contaminés doivent être retirés dès que possible et bien lavés avant d'être réutilisés. Le port
de gants de protection contre les produits chimiques est recommandé.

Gants convenables:

Évitez tout contact avec la peau en mettant en vigueur de bonnes procédures et pratiques
d'hygiène industrielle. Choisissez et utilisez des gants et/ou des vêtements protecteurs pour
réduire encore plus la possibilité de contact avec la peau. Consultez le fabricant de vos gants
et/ou de votre équipement de protection personnelle pour le choix de matériaux compatibles
appropriés.

Inhalation:

Utilisez une protection respiratoire à moins d'avoir une ventilation d'aspiration locale
adéquate ou que l'évaluation de l'exposition indique que les expositions se situent dans les
limites des directives d'exposition recommandées. Le personnel IH peut aider à juger la
suffisance des contrôles techniques actuels.

Respirateur Convenable:

Une ventilation aspirante générale et locale est conseillée pour garder le niveau d'exposition
aux vapeurs en dessous des seuils recommandés. Lorsque l'échantillonnage de l'air révèle
des concentrations dépassant les seuils recommandés ou que ces concentrations sont
inconnues, il faut porter une protection adéquate des voies respiratoires. Respectez la norme
ACNOR Z94.4-93 et utilisez des respirateurs homologués NIOSH / ACNOR.

Equipements de Protection Individuelle en Cas de Déversements

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MOLYKOTE(R) 557 SILICONE DRY FILM LUBRICANT
Yeux:

Utiliser un respirateur à masque complet.

Peau:

Se laver au moment des repas et à la fin des quarts de travail. Les vêtements et les souliers
contaminés doivent être retirés dès que possible et bien lavés avant d'être réutilisés. Le port
de gants de protection contre les produits chimiques est recommandé.

Inhalation/Respirateur
Convenable:

Protection des voies respiratoires conseillée. Respectez la norme ACNOR Z94.4-93 et
utilisez les respirateurs homologués NIOSH / ACNOR. La protection assurée par les
respirateurs à adduction d'air filtré contre l'exposition à tout produit chimique dangereux est
limitéeUtilisez un respirateur à adduction d'air à pression positive en cas de possibilité
d'émission incontrôlée, si les niveaux d'exposition sont inconnus ou dans toute autre situation
où la protection assurée par les respirateurs à adduction d'air filtré peut être insuffisante.

Mesures de Précaution:

Éviter le contact avec les yeux. Eviter tout contact avec la peau. Ne pas inhaler les vapeurs,
le brouillard, les poussières ou les fumées. Maintenir le contenant fermé. Ne pas ingerer.
Veuillez apporter de soin raisonnable

Note: Ces précautions concernent une manipulation à la température de la pièce. L'utilisation a des températures élevées ou les
applications en aérosol peut nécessiter des précautions supplémentaires.

9. PROPRIETES PHYSIQUES ET CHIMIQUES
Etat Physique:
Couleur:
Odeur:
Seuil olfactif:
Densité @ 25°C:
Viscosité:
Point de Congélation:
Point Ebullition:
Tension de Vapeur @
25°C:
Densité de la vapeur:
Taux d'évaporation:
Solubilité dans l'eau:
Coefficient de répartition
eau / huile:
pH:
Contenu Volatile:

Liquide.
Incolore.
Solvant.
Non disponible.
0.77
1 cSt
Pas disponible.
> 65 °C
Pas disponible.
Pas disponible.
Non disponible.
Pas disponible.
Non disponible.
Pas disponible.
95 %

Point d'éclair: 103.1 °F / 39.5 °C (Coupelle fermée)
Auto-Inflammation: Pas disponible.
Limites D'inflammabilité Pas disponible.
dans l'air:
Note: Ces informations ne sont pas destinées à la redaction de specification de produits. Veuillez contacter Dow Corning avant de
rédiger vos spécifications.

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MOLYKOTE(R) 557 SILICONE DRY FILM LUBRICANT
10. STABILITE ET REACTIVITE
stabilité chimique:

Stable.

Polymérisation
dangereuse:
Conditions à Eviter:

La polymérisation dangereuse ne se produira pas.

Materiaux à Eviter:

Les comburants peuvent entraîner une réaction.

Aucun(e).

Produits de décomposition dangereux
Le claquage thermique de ce produit durant un incendie ou sous des conditions de chaleur intense pourrait mener aux
produits de décomposition suivants: Oxydes de carbone et traces de résidus de combustion de composés carbonés.
Dioxyde de silicium. Formaldéhyde.

11. INFORMATIONS TOXICOLOGIQUES
Renseignements sur les dangers particuliers des Composants
Aucun renseignement applicable n'est connu.

12. INFORMATIONS ECOLOGIQUES
Distribution et Evolution dans l'environnement
Les renseignements complets ne sont pas encore disponibles.
Les effets sur l'environnement
Les renseignements complets ne sont pas encore disponibles.
Evolution et les effets dans les stations d'épuration des eaux usée
Les renseignements complets ne sont pas encore disponibles.

Parametres De Danger (LC50 OR EC50)
Toxicité Aigue en milieu Aquatique (MG/L)
Toxicité Aigue en milieu terrestre (MG/L)

Critère de classification de l'écotoxicité
Elevé
Moyen
<=1
>1 and <=100
<=100
>100 and <= 2000

Faible
>100
>2000

Ce Tableau est Adapté de "ENVIRONMENTAL TOXICOLOGY AND RISK ASSESSMENT", ASTM STP 1179, P. 34, 1993.
Ce Tableau peut être utilisé pour classifier l'écotoxicité du produit quand des données ecotoxiques sont inscritent au dessus. Veuillez lire l'autre
information sur la sécurité écologique de cette matière dans son ensemble.

13. CONSIDÉRATIONS RELATIVES À L'ÉLIMINATION

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MOLYKOTE(R) 557 SILICONE DRY FILM LUBRICANT
Peut être incinéré conformément aux réglementations locales.
Appelez la société locale d'élimination des déchets dangereux ou les autorités provinciales en matière de déchets pour
plus de renseignements.

14. INFORMATIONS RELATIVES AU TRANSPORT
Route du Canada (selon les règlements du code IMDG)
Nom D'expedition:

PETROLEUM DISTILLATES, N.O.S.

Classe des dangers:

3

Numero UN/NA:

UN 1268

Groupe D'emballage:

III

Étiquette(s) de risque:

flammable liquid

IMDG Maritime
Nom D'expedition:

PETROLEUM DISTILLATES, N.O.S.

Classe des dangers:

3

Numero UN/NA:

UN 1268

Groupe D'emballage:

III

Étiquette(s) de risque:

flammable liquid

ICAO Aérien
Nom D'expedition:

Petroleum distillates, n.o.s.

Classe des dangers:

3

Numero UN/NA:

UN 1268

Groupe D'emballage:

III

Classe des dangers:

Flammable Liquid

Appelez Dow Corning Transportation au (989) 496-8577 si vous avez besoin de renseignements supplémentaires.

15. INFORMATIONS REGLEMENTAIRES

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MOLYKOTE(R) 557 SILICONE DRY FILM LUBRICANT
Ce produit a été classé conformément aux critères de danger énoncés dans le RPC, et la fiche signalétique contient tous
les renseignements exigés par le RPC.
CLASSIFICATION
SIMDUT:

Catégorie B, Division 3.
Catégorie D, Division 2B.

DSL STATUS:

Toutes les substances chimiques dans ce produit figurent sur la LIS ou sont exemptées.

16. AUTRES INFORMATIONS
Redigé par: Dow Corning Corporation
Ces Données sont proposées de bonne foi comme valeurs typiques et non comme une spécification du produit. Aucune
garantie, expresse ou tacite, n'est établie par la présente. Les méthodes recommandées pour l'hygiène industrielle et une
manipulation sans risques sont considérées comme étant généralement applicables. Cependant, chaque utilisateur/trice
devrait revoir ces recommandations dans le contexte spécifique de l'utilisation prévue et déterminer si celles-ci sont
appropriées.
(R) indique une Marque Déposée

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name:
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

FORMULA 494965
PENTRAZEN
ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Kerosene
Mineral Spirits
Propane
Isobutane
n-Butane
Naphthenic Oil

CAS No.:
8008-20-6
8052-41-3
74-98-6
75-28-5
106-97-8
64742-52-5

TLV:
Not established
100ppm
2500ppm
Not established
800ppm
5mg/m3 as mist

______________________________________________________________________________

SECTION 3
Boiling Point:
Solubility in Water:
Vapor Density(Air=1):

PHYSICAL DATA
<0 to >5500 F
Nil
Heavier than air

Specific Gravity(H2O=1):
Evaporation Rate:
pH:

0.60 + 0.1
Slower than Ether
NA

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flash Point(Propellant):
Flammable Limits(Propellant):
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

140OF
<0OF
LEL:
1.8
UEL: 12.0
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst.

_______________________________________________________________________________________________________________________________________

SECTION 5
Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include irritation of respiratory tract, headache, dizziness,
nausea, and loss of coordination.Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.

First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________

SECTION 9

SPILL OR LEAK PROCEDURE

Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
Mineral Spirits may contain 3.5% 1,2,4, Trimethylbenzene (CAS#95-63-6) which is subject to the reporting
requirements of Section 313 of SARA Title III. Kerosene contains 0.5-1.5% xylene mix (CAS#1330-20-7),
0.5-1.5% naphthalene (CAS#91-20-3) and 0.4-1.2% biphenyl (CAS#92-52-4) which are subject to the
reporting requirements of Section 313 of SARA Title III.

__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this time.
Addition of reducers or other additives to this product may substantially alter the composition. We make no warranties,
express or implied, and assume no liability in connection with any use of this information.
494965

MATERIAL SAFETY DATA SHEET
NAME OF PRODUCT

MSDS DATE: 08/31/06

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME:
MANUFACTURED FOR:
ADDRESS:
EMERGENCY PHONE:
CHEMTREC PHONE:

73491 Eye Wash Solution - 16 oz.
Impact Products, LLC
2840 Centennial Road, Toledo, OH 43617
800-793-8740

CHEMICAL NAME:
CHEMICAL FAMILY:
CHEMICAL FORMULA:
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENT:
CAS NO.
% WT
TLV/PEL
This eye wash solution is a sterile, isotonic-preserved saline solution which complies with FDA regulations 21 CFR, parts 349 and
369. There are no ingredients in this eye wash solution which appeared on the OSHA standard 29 CFR 1910, subpart z.
SECTION 3: HAZARDS IDENTIFICATION
ROUTES OF ENTRY:

Inhalation: No

Skin: Yes

Ingestion: Yes

POTENTIAL HEALTH EFFECTS
EYES:
n/a
SKIN:
n/a
INGESTION:
n/a
INHALATION:
n/a
ACUTE/CHRONIC HEALTH HAZARDS: Non-toxic to the skin and if accidentally ingested is non-hazardous, but might exert a mil
emetic reaction accompanied by possible slight nausea.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: n/a

CARCINOGENICITY
OSHA:
No

NTP:

No

IARC:

No

OTHER:

SECTION 4: FIRST AID MEASURES
EYES:
SKIN:
INGESTION:
INHALATION:

n/a
n/a
Drink water if accidentally ingested to dilute the concentration
n/a

SECTION 5: FIRE-FIGHTING MEASURES
FLAMMABLE LIMITS:
non-flammable
FLASH POINT:
n/a
METHOD USED:
n/a
HMIS HAZARD CLASSIFICATION:
HEALTH:
EXTINGUISHING MEDIA:
n/a
SPECIAL FIRE FIGHTING PROCEDURES:
n/a
UNUSUAL FIRE AND EXPLOSION HAZARDS: none

LEL: n/a

FLAMMABILITY:

SECTION 6: ACCIDENTAL RELEASE MEASURES
ACCIDENTAL RELEASE MEASURES:
SECTION 7: HANDLING AND STORAGE
HANDLING AND STORAGE:
OTHER PRECAUTIONS:

None
None

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS:
VENTILATION :

Local Exhaust:

n/a

Special: n/a
PAGE 1 OF 3

UEL: n/a

REACTIVITY:

MATERIAL SAFETY DATA SHEET
NAME OF PRODUCT

MSDS DATE: 08/31/06

Mechanical:
n/a
Other:
n/a
RESPIRATORY PROTECTION:
Not required
EYE PROTECTION:
Not required
SKIN PROTECTION:
Not required
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Not required
WORK HYGIENIC PRACTICES:
No special practices required
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE/ODOR:
Clear, colorless, odorless liquid
BOILING POINT:
n/a
MELTING POINT:
n/a
VAPOR PRESSURE (mmHg):
n/a
VAPOR DENSITY (AIR = 1):
n/a
SPECIAL GRAVITY (H2O = 1):
n/a
EVAPORATION RATE:
n/a
SOLUBILITY IN WATER:
Complete
PERCENT VOLATILE:
VISCOSITY:

SECTION 10: STABILITY AND REACTIVITY
STABILITY:

STABLE
X

UNSTABLE

CONDITIONS TO AVOID (STABILITY):
INCOMPATIBILITY (MATERIAL TO AVOID):
HAZARDOUS DECOMPOSITION:
HAZARDOUS POLYMERIZATION:
CONDITIONS TO AVOID (POLYMERIZATION):

None
None
None
Will not occur
None

SECTION 11: TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION:

SECTION 12: ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION:

SECTION 13: DISPOSAL CONSIDERATIONS/PROCEDURES FOR SPILL OR LEAK CLEANUP
WASTE DISPOSAL METHOD: Standard
PROCEDURE FOR SPILL OR LEAK CLEANUP: Consistent with local, state and federal regulations regarding disposal of nonhazardous materials.
SECTION 14: TRANSPORT INFORMATION

SECTION 15: REGULATORY INFORMATION

SECTION 16: OTHER INFORMATION
OTHER INFORMATION:
DISCLAIMER:

The information furished herein is believed to be accurate and represents the best data currently available to us.
No warranty, expressed or implied is made and Impact Products LLC assumes no legal responsibility or liability
resulting from its use.

Additional Information:
PAGE 2 OF 3

MATERIAL SAFETY DATA SHEET
NAME OF PRODUCT
MSDS DATE: 08/31/06
Effects of Freezing on Eye Saline Concentrate
Freezing Point: 10 degrees F is the point where this product freezes solid, based on tests conducted by
the manufacturer of the liquid.
Sample bottles of Eye Wash Solution have been exposed to freezing conditions a number of times and
allowed to thaw in order to test for degradation or breakdown of the product. No degradation or
breakdown of eye wash has occurred under these circumstances.
While liquid product is not harmed by freezing and sub-freezing temperatures, consideration should be
given to the examination of the container/closure system (bottling) of the product to ensure that the
bottle/cap has not been compromised. The bottle/cap and seal must be intact for assurance of continued
sterility.
Neutralizing Effects
Eye Wash Solution is a buffered, isotonic, sterile saline solution, balanced to neutral pH 7. Being a neutral
pH solution, acids or caustic liquid, thus lowering or raising the pH of the combination of fluids.

PAGE 3 OF 3

MATERIAL SAFETY DATA SHEET
A26W51
13 00
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER
DATE OF PREPARATION
HMIS CODES
Health
A26W51
30-SEP-07
Flammability
Reactivity
PRODUCT NAME
CLASSIC 99® Interior Semi-Gloss Latex Enamel, Extra White

2*
0
0

MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS COMPANY
101 Prospect Avenue N.W.
Cleveland, OH 44115
TELEPHONE NUMBERS and WEBSITES
Product Information
www.sherwin-williams.com
Regulatory Information
(216) 566-2902
www.paintdocs.com
Medical Emergency
(216) 566-2917
Transportation Emergency
for Chemical Emergency ONLY (spill, leak,
(800) 424-9300
fire, exposure, or accident)
% by WT
2
1
0.1
5

12

Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
112-34-5 2-(2-Butoxyethoxy)-ethanol
ACGIH TLV Not Available
0.06 mm
OSHA PEL Not Available
107-21-1 Ethylene Glycol
ACGIH TLV
100 mg/m3 CEILI (aerosol) 0.12 mm
OSHA PEL
50 ppm CEILING
14464-46-1 Cristobalite
ACGIH TLV
0.05 mg/m3 as Resp. Dust
OSHA PEL
0.05 mg/m3 as Resp. Dust
471-34-1 Calcium Carbonate
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
15 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction
13463-67-7 Titanium Dioxide
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction

Section 3 -- HAZARDS IDENTIFICATION
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.

Continued on page 2

A26W51

page 2

EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
In a confined area vapors in high concentration may cause headache,
nausea or dizziness.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver and urinary systems.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
Section 4 -- FIRST AID MEASURES
EYES:
SKIN:
INHALATION:
INGESTION:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
Do not induce vomiting.
Get medical attention immediately.

Section 5 -- FIRE FIGHTING MEASURES
FLASH POINT
LEL
UEL
Not Applicable
N.A.
N.A.
FLAMMABILITY CLASSIFICATION
Not Applicable
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Alcohol Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers may explode (due to the build-up of pressure) when
exposed to extreme heat.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.
Section 6 -- ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
Continued on page 3

A26W51

page 3

Section 7 -- HANDLING AND STORAGE
STORAGE CATEGORY
Not Applicable
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep container closed when not in use. Transfer only to approved
containers with complete and appropriate labeling. Do not take internally.
Keep out of the reach of children.
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
Removal of old paint by sanding, scraping or other means may generate
dust or fumes that contain lead. Exposure to lead dust or fumes may cause
brain damage or other adverse health effects, especially in children or
pregnant women. Controlling exposure to lead or other hazardous substances
requires the use of proper protective equipment, such as a properly fitted
respirator (NIOSH approved) and proper containment and cleanup. For more
information, call the National Lead Information Center at 1-800-424-LEAD
(in US) or contact your local health authority.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
Wear gloves which are recommended by glove supplier for protection
against materials in Section 2.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.

Continued on page 4

A26W51

page 4

Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT WEIGHT
9.93 lb/gal
1189 g/l
SPECIFIC GRAVITY
1.19
BOILING POINT
212 - 448 F
100 - 231 C
MELTING POINT
Not Available
VOLATILE VOLUME
62 %
EVAPORATION RATE
Slower than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
9.5
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
0.72 lb/gal
86 g/l
Less Water and Federally Exempt Solvents
0.30 lb/gal
36 g/l
Emitted VOC
Section 10 -- STABILITY AND REACTIVITY
STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
Section 11 -- TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
Crystalline Silica (Quartz, Cristobalite) is listed by IARC and NTP.
Long term exposure to high levels of silica dust, which can occur only when
sanding or abrading the dry film, may cause lung damage (silicosis) and
possibly cancer.
IARC's Monograph No. 93 reports there is sufficient evidence of
carcinogenicity in experimental rats exposed to titanium dioxide but
inadequate evidence for carcinogenicity in humans and has assigned a Group
2B rating. In addition, the IARC summary concludes, "No significant
exposure to titanium dioxide is thought to occur during the use of products
in which titanium is bound to other materials, such as paint."
Ethylene Glycol is considered an animal teratogen. It has been shown to
cause birth defects in rats and mice at high doses when given in drinking
water or by gavage. There is no evidence to indicate it causes birth
defects in humans.
TOXICOLOGY DATA

Continued on page 5

A26W51
CAS No.
112-34-5
107-21-1
14464-46-1
471-34-1
13463-67-7

page 5
Ingredient Name
2-(2-Butoxyethoxy)-ethanol
LC50
RAT
LD50
RAT
Ethylene Glycol
LC50
RAT
LD50
RAT
Cristobalite
LC50
RAT
LD50
RAT
Calcium Carbonate
LC50
RAT
LD50
RAT
Titanium Dioxide
LC50
RAT
LD50
RAT

4HR

Not Available
5660
mg/kg

4HR

Not Available
4700
mg/kg

4HR

Not Available
Not Available

4HR

Not Available
Not Available

4HR

Not Available
Not Available

Section 12 -- ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
No data available.
Section 13 -- DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
Waste from this product is not hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Incinerate in approved facility. Do not incinerate closed container.
Dispose of in accordance with Federal, State/Provincial, and Local
regulations regarding pollution.
Section 14 -- TRANSPORT INFORMATION
US Ground (DOT)
Not Regulated for Transportation.
Canada (TDG)
Not Regulated for Transportation.
IMO
Not Regulated for Transportation.
Section 15 -- REGULATORY INFORMATION
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
107-21-1 Ethylene Glycol
Glycol Ethers

Continued on page 6

% by WT
1
2

% Element

A26W51

page 6

CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
Section 16 -- OTHER INFORMATION
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

MATERIAL SAFETY DATA SHEET
A26WQ8015
21 00
===========================================================================
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
--------------------------------------------------------------------------PRODUCT NUMBER
HMIS CODES
Health
2*
A26WQ8015
Flammability
0
Reactivity
0
PRODUCT NAME
CLASSIC 99® Interior Latex Semi-Gloss Wall Paint, Antique White
MANUFACTURER'S NAME
EMERGENCY TELEPHONE NO.
THE SHERWIN-WILLIAMS COMPANY
(216) 566-2917
170 Brunel Rd
Mississauga, ON L4Z 1T5
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
20-APR-07
(905) 507-0166
===========================================================================
Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
--------------------------------------------------------------------------2
112-34-5 2-(2-Butoxyethoxy)-ethanol
ACGIH TLV Not Available
0.06 mm
OSHA PEL Not Available
1
107-21-1 Ethylene Glycol
ACGIH TLV
100 mg/m3 CEILI (aerosol) 0.12 mm
OSHA PEL
50 ppm CEILING
0.1
14464-46-1 Cristobalite
ACGIH TLV
0.05 mg/m3 as Resp. Dust
OSHA PEL
0.05 mg/m3 as Resp. Dust
3
471-34-1 Calcium Carbonate
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
15 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction
15
13463-67-7 Titanium Dioxide
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction
===========================================================================
Section 3 -- HAZARDS IDENTIFICATION
--------------------------------------------------------------------------ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
In a confined area vapors in high concentration may cause headache,
nausea or dizziness.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.

Continued on page 2

A26WQ8015
page 2
===========================================================================
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
===========================================================================
Section 4 -- FIRST AID MEASURES
--------------------------------------------------------------------------EYES:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 -- FIRE FIGHTING MEASURES
--------------------------------------------------------------------------FLASH POINT
LEL
UEL
Not Applicable
N.A.
N.A.
FLAMMABILITY CLASSIFICATION
Not Applicable
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Alcohol Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers may explode (due to the build-up of pressure) when
exposed to extreme heat.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.
===========================================================================
Section 6 -- ACCIDENTAL RELEASE MEASURES
--------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
===========================================================================
Section 7 -- HANDLING AND STORAGE
--------------------------------------------------------------------------STORAGE CATEGORY
Not Applicable
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep container closed when not in use. Transfer only to approved
containers with complete and appropriate labeling. Do not take internally.
Keep out of the reach of children.

Continued on page 3

A26WQ8015
page 3
===========================================================================
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
--------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
Removal of old paint by sanding, scraping or other means may generate
dust or fumes that contain lead. Exposure to lead dust or fumes may cause
brain damage or other adverse health effects, especially in children or
pregnant women. Controlling exposure to lead or other hazardous substances
requires the use of proper protective equipment, such as a properly fitted
respirator (NIOSH approved) and proper containment and cleanup. For more
information, call the National Lead Information Center at 1-800-424-LEAD
(in US) or contact your local health authority.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
Wear gloves which are recommended by glove supplier for protection
against materials in Section 2.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
===========================================================================
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
--------------------------------------------------------------------------PRODUCT WEIGHT
10.07 lb/gal
1207 g/l
SPECIFIC GRAVITY
1.21
BOILING POINT
212 - 448 F
100 - 231 C
MELTING POINT
Not Available
VOLATILE VOLUME
61 %
EVAPORATION RATE
Slower than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
9.5
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
0.73 lb/gal
87 g/l
Less Water and Federally Exempt Solvents
0.31 lb/gal
37 g/l
Emitted VOC

Continued on page 4

A26WQ8015
page 4
===========================================================================
Section 10 -- STABILITY AND REACTIVITY
--------------------------------------------------------------------------STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
===========================================================================
Section 11 -- TOXICOLOGICAL INFORMATION
--------------------------------------------------------------------------CHRONIC HEALTH HAZARDS
Crystalline Silica (Quartz, Cristobalite) is listed by IARC and NTP.
Long term exposure to high levels of silica dust, which can occur only when
sanding or abrading the dry film, may cause lung damage (silicosis) and
possibly cancer.
Ethylene Glycol is considered an animal teratogen. It has been shown to
cause birth defects in rats and mice at high doses when given in drinking
water or by gavage. There is no evidence to indicate it causes birth
defects in humans.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver and urinary systems.
Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung
cancer, however, such exposure levels are not attainable in the workplace.
--------------------------------------------------------------------------TOXICOLOGY DATA
CAS No.
Ingredient Name
--------------------------------------------------------------------------112-34-5
2-(2-Butoxyethoxy)-ethanol
LC50
RAT
4HR
Not Available
LD50
RAT
5660
mg/kg
107-21-1
Ethylene Glycol
LC50
RAT
4HR
Not Available
LD50
RAT
4700
mg/kg
14464-46-1
Cristobalite
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
471-34-1
Calcium Carbonate
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
13463-67-7
Titanium Dioxide
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
===========================================================================
Section 12 -- ECOLOGICAL INFORMATION
--------------------------------------------------------------------------ECOTOXICOLOGICAL INFORMATION
No data available.

Continued on page 5

A26WQ8015
page 5
===========================================================================
Section 13 -- DISPOSAL CONSIDERATIONS
--------------------------------------------------------------------------WASTE DISPOSAL METHOD
Waste from this product is not hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Incinerate in approved facility. Do not incinerate closed container.
Dispose of in accordance with Federal, State/Provincial, and Local
regulations regarding pollution.
===========================================================================
Section 14 -- TRANSPORT INFORMATION
--------------------------------------------------------------------------US Ground (DOT)
Not Regulated for Transportation.
Canada (TDG)
Not Regulated for Transportation.
IMO
Not Regulated for Transportation.
===========================================================================
Section 15 -- REGULATORY INFORMATION
--------------------------------------------------------------------------SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
--------------------------------------------------------------------------107-21-1 Ethylene Glycol
1
Glycol Ethers
2
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
===========================================================================
Section 16 -- OTHER INFORMATION
--------------------------------------------------------------------------This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

Page 1 of 6

24 Hour Emergency:
CHEMTREC: 1-800-424-9300

Material Safety Data
Sheet

National Response in Canada
CANUTEC: 613-996-6666
Outside U.S. and Canada
Chemtrec: 202-483-7616
NOTE: CHEMTREC, CANUTEC and National Response Center
emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving
chemicals

Section 1 - Chemical Product / Company Information

Product Name:

KILZ Casual Colors Int/Ext
Stainblocking Primer-Sealer

Identification Number:

125

Product Use/Class:
Supplier:

Preparer:

Revision
Date:

Masterchem Industries, Inc.
3135 Old Highway M
Imperial, MO 63052-7834
Div of Masco, Inc
Crouse, Steve

02/13/2003

Manufacturer: Masterchem Industries, Inc.
3135 Old Highway M
Imperial, MO 63052-7834
Div of Masco, Inc

Section 2 - Composition / Information On Ingredients
Chemical Name

Ethylene Glycol
Ammonium
Hydroxide

CAS
Weight ACGIH
Number % Less TLV-TWA
Than
107-21-1 5.0
50 ppm
7664-41- 1.0
25 ppm
7

ACGIH
TLVSTEL
20mg/m3
35 ppm

OSHA
OSHA
PEL-TWA PELCEILING
50 ppm
N.E.
50 ppm

Section 3 - Hazards Identification
*** Emergency Overview ***: Contains a material which may cause embryo/fetotoxicity based on
animal data. Contains a material which can cause liver and kidney damage based on animal
data. Irritant.
Effects Of Overexposure - Eye Contact: Direct eye contact may cause irritation.
Effects Of Overexposure - Skin Contact: Direct skin contact may cause irritation.
Effects Of Overexposure - Inhalation: Inhalation may cause irritation to the respiratory tract
(nose, mouth, mucous membranes).

KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer 125

Page 2 of 6
Effects Of Overexposure - Ingestion: May cause severe gastrointestinal disturbance with
headache, nausea, vomiting and diarrhea. Harmful if swallowed. Gross overexposure may cause
severe kidney damage. Under normal use conditions, this product is not expected to cause
adverse health effects.
Effects Of Overexposure - Chronic Hazards: A component(s) of this product has been shown to
cause adverse liver and kidney effects in laboratory animals.
Primary Route(s) Of Entry: Unknown

Section 4 - First Aid Measures
First Aid - Eye Contact: If material gets into eyes, flush with water immediately for 15 minutes.
Consult a physician.
First Aid - Skin Contact: Wash skin thoroughly with soap and water.
First Aid - Inhalation: No Information.
First Aid - Ingestion: If swallowed do not induce vomiting. Seek immediate medical attention.

Section 5 - Fire Fighting Measures
Flash Point: Not applicable

LOWER EXPLOSIVE LIMIT:
UPPER EXPLOSIVE LIMIT :

Extinguishing Media: Unknown
Unusual Fire And Explosion Hazards: None known.
Special Firefighting Procedures: No Information.

Section 6 – Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Absorb residue with suitable chemical
absorbent. Dike to prevent entering any sewer or waterway. Transfer liquid to a holding container.
Dispose of material in accordance with all federal, state and local regulations. Spilled material
becomes very slippery when wet.

Section 7 - Handling And Storage
Handling: Hazardous residue may remain in emptied container. Do not reuse empty containers
without commercial cleaning or reconditioning. Use in well ventilated area.
Storage: Keep container closed when not in use.

KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer 125

Page 3 of 6

Section 8 - Exposure Controls / Personal Protection
Engineering Controls: General ventilation should be provided to maintain ambient concentrations
below nuisance levels.
Respiratory Protection: Respirator use is not expected to be necessary under normal conditions
of handling. In emergency situations, use of a NIOSH-approved respirator may be required.
When concentrations exceed nuisance levels, use appropriate NIOSH-approved respirator. In
extreme cases a Self Contained Breathing Apparatus (SCBA) may be necessary.
Skin Protection: Chemical-resistant gloves may be required for individuals with sensitive skin.
Sensitive individuals should wear gloves to prevent repeated contact.
Eye Protection: No Information.
Other protective equipment: No Information.
Hygienic Practices: No Information.

Section 9 - Physical And Chemical Properties
Boiling Range:
Odor:
Appearance:
Solubility in H2O:
Freeze Point:
Vapor Pressure:
Physical State:

212 - 340
slight ammoniacal
infinite
32F
Liquid

(See section 16 for abbreviation legend)

Section 10 - Stability And Reactivity
Conditions To Avoid: No Information.
Incompatibility: No Information.
Hazardous Decomposition: No Information.
Hazardous Polymerization: No Information.
Stability: No Information.

Section 11 - Toxicological Information
Product LD50:

Product LC50:

KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer 125

Vapor Density:
Odor Threshold:
Evaporation Rate:

>air

Specific Gravity:
PH:
Viscosity:

1.301
8.8 to 9.3
97 to 103KU

Equal To Water

Page 4 of 6
Chemical Name
Ethylene Glycol

LD50
Oral, rat: 4700
mg/kg

Ammonium Hydroxide

LC50
Inhalation: 10876
mg/m3
Inhalation-mouse
4230ppm/1H

Section 12 - Ecological Information
Ecological Information: No Information.

Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with applicable federal, state and local
regulations.

Section 14 - Transportation Information
DOT Proper Shipping
Name:
DOT Technical Name:
DOT Hazard Class:
DOT UN/NA Number:

Packing Group:
Hazard Subclass:
Resp. Guide Page:
ORM-D

Section 15 - Regulatory Information
CERCLA – SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under
Sections 311and 312 of the Superfund Amendment and
Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
None Known.
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendment and
Reauthorization Act of 1986 and 40 CFR part 372:

Chemical Name
Ethylene Glycol
Toxic Substances Control Act:

KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer 125

CAS Number
107-21-1

Page 5 of 6
This product contains the following chemical substances subject to the reporting requirements of
TSCA 12(B) if exported from the United States:

Chemical Name
Ethylene Glycol

CAS Number
107-21-1

U.S. State Regulations: As follows –
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this
product.

Chemical Name
Inert non-hazardous material
Water
Talc, containing no asbestos fibers
Titanium Dioxide
Calcium Carbonate

CAS Number
MIXTURE
7732-18-5
14807-96-6
13463-67-7
1317-65-3

Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%.

Chemical Name
Inert non-hazardous material
Water
Talc, containing no asbestos fibers
Titanium Dioxide
Calcium Carbonate
Nepheline syenite

CAS Number
MIXTURE
7732-18-5
14807-96-6
13463-67-7
1317-65-3
37244-96-5

California Proposition 65:
Warning: The following ingredients present in the product are known to the state of California to
cause Cancer:
No Proposition 65 Carcinogenic materials exist in this product
Warning: The following ingredients present in the product are known to the state of California to
cause birth defects, or other reproductive hazards.

Chemical Name
Ethylene Glycol
International Regulations: As follows –
CANADIAN WHMIS:

KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer 125

CAS Number
107-21-1

Page 6 of 6
This MSDS has been prepared in compliance with Controlled Product Regulations except for the
use of the 16 headings.
CANADIAN WHMIS CLASS:

Section 16 - Other Information
HMIS Ratings:
Health: 1- Minor Hazard

Flammability: 0 - No Hazard

Reactivity: 0

Personal Protection: B

VOLATILE ORGANIC COMPOUNDS, GR/LTR: 157
REASON FOR REVISION:
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

DISCLAIMER
The information accumulated herein is believed to be accurate, but is not warranted to be, whether
orginated
with the company or not. Since the use of this information and the conditions of use are not within
the control
of the manufacturer, it is the user's obligation to determine for safe use of this product.
All ingredients
used in the manufacture of this product are, if required, listed on the TSCA inventory.

KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer 125

Page 1 of 6

24 Hour Emergency:
CHEMTREC: 1-800-424-9300

Material Safety Data
Sheet

National Response in Canada
CANUTEC: 613-996-6666
Outside U.S. and Canada
Chemtrec: 202-483-7616
NOTE: CHEMTREC, CANUTEC and National Response Center
emergency numbers to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving
chemicals

Section 1 - Chemical Product / Company Information

Product Name:

KILZ Casual Colors Int/Ext
Stainblocking Primer-Sealer

Identification Number:

125

Product Use/Class:
Supplier:

Preparer:

Revision
Date:

Masterchem Industries, Inc.
3135 Old Highway M
Imperial, MO 63052-7834
Div of Masco, Inc
Crouse, Steve

02/13/2003

Manufacturer: Masterchem Industries, Inc.
3135 Old Highway M
Imperial, MO 63052-7834
Div of Masco, Inc

Section 2 - Composition / Information On Ingredients
Chemical Name

Ethylene Glycol
Ammonium
Hydroxide

CAS
Weight ACGIH
Number % Less TLV-TWA
Than
107-21-1 5.0
50 ppm
7664-41- 1.0
25 ppm
7

ACGIH
TLVSTEL
20mg/m3
35 ppm

OSHA
OSHA
PEL-TWA PELCEILING
50 ppm
N.E.
50 ppm

Section 3 - Hazards Identification
*** Emergency Overview ***: Contains a material which may cause embryo/fetotoxicity based on
animal data. Contains a material which can cause liver and kidney damage based on animal
data. Irritant.
Effects Of Overexposure - Eye Contact: Direct eye contact may cause irritation.
Effects Of Overexposure - Skin Contact: Direct skin contact may cause irritation.
Effects Of Overexposure - Inhalation: Inhalation may cause irritation to the respiratory tract
(nose, mouth, mucous membranes).

KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer 125

Page 2 of 6
Effects Of Overexposure - Ingestion: May cause severe gastrointestinal disturbance with
headache, nausea, vomiting and diarrhea. Harmful if swallowed. Gross overexposure may cause
severe kidney damage. Under normal use conditions, this product is not expected to cause
adverse health effects.
Effects Of Overexposure - Chronic Hazards: A component(s) of this product has been shown to
cause adverse liver and kidney effects in laboratory animals.
Primary Route(s) Of Entry: Unknown

Section 4 - First Aid Measures
First Aid - Eye Contact: If material gets into eyes, flush with water immediately for 15 minutes.
Consult a physician.
First Aid - Skin Contact: Wash skin thoroughly with soap and water.
First Aid - Inhalation: No Information.
First Aid - Ingestion: If swallowed do not induce vomiting. Seek immediate medical attention.

Section 5 - Fire Fighting Measures
Flash Point: Not applicable

LOWER EXPLOSIVE LIMIT:
UPPER EXPLOSIVE LIMIT :

Extinguishing Media: Unknown
Unusual Fire And Explosion Hazards: None known.
Special Firefighting Procedures: No Information.

Section 6 – Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Absorb residue with suitable chemical
absorbent. Dike to prevent entering any sewer or waterway. Transfer liquid to a holding container.
Dispose of material in accordance with all federal, state and local regulations. Spilled material
becomes very slippery when wet.

Section 7 - Handling And Storage
Handling: Hazardous residue may remain in emptied container. Do not reuse empty containers
without commercial cleaning or reconditioning. Use in well ventilated area.
Storage: Keep container closed when not in use.

KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer 125

Page 3 of 6

Section 8 - Exposure Controls / Personal Protection
Engineering Controls: General ventilation should be provided to maintain ambient concentrations
below nuisance levels.
Respiratory Protection: Respirator use is not expected to be necessary under normal conditions
of handling. In emergency situations, use of a NIOSH-approved respirator may be required.
When concentrations exceed nuisance levels, use appropriate NIOSH-approved respirator. In
extreme cases a Self Contained Breathing Apparatus (SCBA) may be necessary.
Skin Protection: Chemical-resistant gloves may be required for individuals with sensitive skin.
Sensitive individuals should wear gloves to prevent repeated contact.
Eye Protection: No Information.
Other protective equipment: No Information.
Hygienic Practices: No Information.

Section 9 - Physical And Chemical Properties
Boiling Range:
Odor:
Appearance:
Solubility in H2O:
Freeze Point:
Vapor Pressure:
Physical State:

212 - 340
slight ammoniacal
infinite
32F
Liquid

(See section 16 for abbreviation legend)

Section 10 - Stability And Reactivity
Conditions To Avoid: No Information.
Incompatibility: No Information.
Hazardous Decomposition: No Information.
Hazardous Polymerization: No Information.
Stability: No Information.

Section 11 - Toxicological Information
Product LD50:

Product LC50:

KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer 125

Vapor Density:
Odor Threshold:
Evaporation Rate:

>air

Specific Gravity:
PH:
Viscosity:

1.301
8.8 to 9.3
97 to 103KU

Equal To Water

Page 4 of 6
Chemical Name
Ethylene Glycol

LD50
Oral, rat: 4700
mg/kg

Ammonium Hydroxide

LC50
Inhalation: 10876
mg/m3
Inhalation-mouse
4230ppm/1H

Section 12 - Ecological Information
Ecological Information: No Information.

Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with applicable federal, state and local
regulations.

Section 14 - Transportation Information
DOT Proper Shipping
Name:
DOT Technical Name:
DOT Hazard Class:
DOT UN/NA Number:

Packing Group:
Hazard Subclass:
Resp. Guide Page:
ORM-D

Section 15 - Regulatory Information
CERCLA – SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under
Sections 311and 312 of the Superfund Amendment and
Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
None Known.
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendment and
Reauthorization Act of 1986 and 40 CFR part 372:

Chemical Name
Ethylene Glycol
Toxic Substances Control Act:

KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer 125

CAS Number
107-21-1

Page 5 of 6
This product contains the following chemical substances subject to the reporting requirements of
TSCA 12(B) if exported from the United States:

Chemical Name
Ethylene Glycol

CAS Number
107-21-1

U.S. State Regulations: As follows –
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this
product.

Chemical Name
Inert non-hazardous material
Water
Talc, containing no asbestos fibers
Titanium Dioxide
Calcium Carbonate

CAS Number
MIXTURE
7732-18-5
14807-96-6
13463-67-7
1317-65-3

Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%.

Chemical Name
Inert non-hazardous material
Water
Talc, containing no asbestos fibers
Titanium Dioxide
Calcium Carbonate
Nepheline syenite

CAS Number
MIXTURE
7732-18-5
14807-96-6
13463-67-7
1317-65-3
37244-96-5

California Proposition 65:
Warning: The following ingredients present in the product are known to the state of California to
cause Cancer:
No Proposition 65 Carcinogenic materials exist in this product
Warning: The following ingredients present in the product are known to the state of California to
cause birth defects, or other reproductive hazards.

Chemical Name
Ethylene Glycol
International Regulations: As follows –
CANADIAN WHMIS:

KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer 125

CAS Number
107-21-1

Page 6 of 6
This MSDS has been prepared in compliance with Controlled Product Regulations except for the
use of the 16 headings.
CANADIAN WHMIS CLASS:

Section 16 - Other Information
HMIS Ratings:
Health: 1- Minor Hazard

Flammability: 0 - No Hazard

Reactivity: 0

Personal Protection: B

VOLATILE ORGANIC COMPOUNDS, GR/LTR: 157
REASON FOR REVISION:
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

DISCLAIMER
The information accumulated herein is believed to be accurate, but is not warranted to be, whether
orginated
with the company or not. Since the use of this information and the conditions of use are not within
the control
of the manufacturer, it is the user's obligation to determine for safe use of this product.
All ingredients
used in the manufacture of this product are, if required, listed on the TSCA inventory.

KILZ Casual Colors Int/Ext Stainblocking Primer-Sealer 125

U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET
(Prepared According to 29 CFR 1910.1200)

______________________________________________________________________________

SECTION 1

IDENTIFICATION

Product Name:
Manufacturer's Name:
Manufacturer's Address:
Manufacturer's Phone Number:
Emergency Phone Number:
Proper Shipping Name:
Effective Date:

FORMULA 496905
ZENASTICK RP
ZENEX International
7777 First Place, Cleveland Ohio 44146
(440) 232-4155
1-800-535-5053
Consumer Commodity, ORM-D
10-15-01

______________________________________________________________________________

SECTION 2

IDENTITY INFORMATION AND HAZARDOUS INGREDIENTS

Chemical Name:
Heptane
Butane
Acetone
Styrene-Butadiene Polymer
Propane

CAS No.:
142-82-5
106-97-8
67-64-1
9003-55-3
74-98-6

TLV:
400ppm
800ppm
500ppm
Not established
2500ppm

______________________________________________________________________________

SECTION 3
Boiling Point:
Solubility in Water:
Vapor Density(Air=1):

PHYSICAL DATA
<0 to 2120 F
Nil
Heavier than air

Specific Gravity(H2O=1):
Evaporation Rate:
pH:

0.7 + 0.1
Slower than Ether
NA

_______________________________________________________________________________________________________________________________________

SECTION 4

FIRE AND EXPLOSION HAZARD DATA

Flash Point:
Flammable Limits:
Extinguishing Media:
Special Fire Fighting Procedures:
Unusual Fire and Explosion Hazards:

<0OF
LEL:
1.1
UEL: 12.8
Use water fog, dry chemical or carbon dioxide.
Aerosol cans may rupture when heated.
Heated cans may burst

_______________________________________________________________________________________________________________________________________

SECTION 5
Unstable______
Stable __X___
Incompatability (Materials to Avoid):
Conditions to Avoid:
Hazardous Decomposition or Byproducts:
Hazardous Polymerization:

REACTIVITY DATA

Stability:

None known.
High temperatures.
In fire, will decompose to carbon dioxide, carbon monoxide.
Will not occur

__________________________________________________________________________________________________________________________________________

SECTION 6

STORAGE AND HANDLING INFORMATION

Precautions to be Taken in Handling and Storing:
When spraying more than one half can continuously or more than one can consecutively,
use NIOSH approved respirator.
STORE AT TEMPERATURES BELOW 120oF
KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME
KEEP AWAY FROM CHILDREN
FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY
FOR USE BY TRAINED PERSONNEL ONLY
KEEP CONTAINER CLOSED DURING STORAGE
__________________________________________________________________________________________________________________________________________

SECTION 7

HEALTH HAZARDS AND FIRST AID

Effects of Overexposure:
SKIN: Skin irritant. Will cause defatting of skin. Effects are reversible.
EYES: Eye irritant. Will cause redness and burning sensation.
INHALATION: Effects of overexposure include headache, dizziness, nausea, loss of coordination,
nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
INGESTION:
Aspiration hazard if swallowed.
First Aid Procedures:
SKIN: Immediately flush exposed area with water for at least 15 minutes. If irritation persists, get
medical attention. Remove contaminated clothing and launder before reuse.
EYES: Immediately flush with large quantities of water for at least 15 minutes, lifting upper and lower
eyelids occasionally. Seek medical attention.
INHALATION: Remove person to fresh air. If irritation persists, give oxygen, get medical attention.
INGESTION:
DO NOT induce vomiting. Seek medical attention immediately.
Note: Never give anything by mouth to an unconscious or convulsing victim.
Keep person warm and quiet.
__________________________________________________________________________________________________________________________________________

SECTION 8

SPECIAL PROTECTION INFORMATION

Respiratory Protection:
Ventilation:
Protective Gloves:
Eye Protection:

Self-contained breathing apparatus if above TLV limit.
Provide local exhaust to keep TLV of Section 2 ingredients below acceptable limit.
None required if spraying.
As with all cleaners, ZENEX supports employee safety as priority #1. Therefore, we
recommend the use of safety glasses or chemical splash goggles.
Other Protective Equipment:
Long sleeves and long pants.
Work/Hygienic Practices:
Do not smoke while using. Wash hands after use.
__________________________________________________________________________________________________________________________________________

SECTION 9

SPILL OR LEAK PROCEDURE

Steps To Be Taken In Case Material Is Released or Spilled:
Use absorbent sweeping compound to soak up material. Put into container. Dispose as
hazardous waste.
Waste Disposal Method:
Dispose as hazardous waste in accordance with EPA RCRA.
_________________________________________________________________________________________________________________________________________

SECTION 10

REGULATORY INFORMATION

SARA Title III, Section 313 Components:
None
__________________________________________________________________________________________________________________________________________
This information pertains to this product as currently formulated, and is based on the information available at this
time. Addition of reducers or other additives to this product may substantially alter the composition. We make no
warranties, express or implied, and assume no liability in connection with any use of this information.
496905

|-------------------------------------------------------|
| M A T E R I A L
S A F E T Y
D A T A
S H E E T |
|-------------------------------------------------------|
|-------------------------------------------------------------------------|
|
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
|
|-------------------------------------------------------------------------|
THIS MSDS IS OFFERED IN CANADIAN-FRENCH UPON REQUEST.
ON PEUT DEMANDER CETTE MSDS A LA LANGUE FRANCAISE-CANADIENNE.
PRODUCT NAME
UPC NUMBER
PRODUCT USE/CLASS

: DAP 2000 HEAVY DUTY ADHESIVE
: 7079870555, 7079870565
: Construction Adhesive

SUPPLED BY:
24 HOUR EMERGENCY:
DAP INC.
TRANSPORTATION: 1-800-535-5053 (352-323-3500)
475 FINCHDENE SQUARE
MEDICAL
: 1-800-327-3874 (513-558-5111)
UNITE 5
SCARBOROUGH ONTARIO M1X 1B7
PREPARE DATE : 02/03/1999
GENERAL INFORMATION:
REVISION NO. : 8
DAP INC. : 1-888-DAP-TIPS (1-888-327-8477)
REVISION DATE: 07/08/2003
REVIEWED:
01/15/2005
|-------------------------------------------------------------------------|
|
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
|
|-------------------------------------------------------------------------|
WT/WT %
ITEM
------------ CHEMICAL NAME ------------CAS NUMBER
RANGE
--------------------------------------------------------------------------01
N-Hexane
110-54-3
5.0-10.0 %
02
Aliphatic Petroleum Distillate
64742-89-8
15.0-20.0 %
03
2-Methyl Pentane
107-83-5
5.0-10.0 %
04
3-Methyl Pentane
96-14-0
5.0-10.0 %
---------------------- EXPOSURE LIMITS -------------------ACGIH
OSHA
COMPANY
ITEM TLV-TWA
TLV-STEL
PEL-TWA
PEL-CEILING TLV-TWA
SKIN
--------------------------------------------------------------------------01
50 ppm
N.E.
50 ppm
N.E.
N.E.
NO
02
400 ppm
N.E.
400 ppm
N.E.
N.E.
NO
03
N.E.
N.E.
N.E.
N.E.
N.E.
NO
04
N.E.
N.E.
N.E.
N.E.
N.E.
NO
(See Section 16 for abbreviation legend)
Remaining ingredients are not considered hazardous per the OSHA Hazard
Communication Standard.
Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor
OSHA Final Rule Limits (CFR 29 1910.1000); limits may vary between states.

(Continued on Page 2)
---------------------------------------------------------------------------

Product Name: DAP 2000 HEAVY DUTY ADHESIVE
Revision Date: 07/08/2003
Reviewed:
01/15/2005
Page 2
|-------------------------------------------------------------------------|
|
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
|
|-------------------------------------------------------------------------|

|-------------------------------------------------------------------------|
|
SECTION 3 - HAZARDS IDENTIFICATION
|
|-------------------------------------------------------------------------|
EMERGENCY OVERVIEW: DANGER! Extremely flammable liquid and vapor. Vapor
harmful. Harmful or fatal if swallowed. Vapors may cause flash fire or
explosion. Aspiration hazard if swallowed - can enter lungs and cause
damage. Harmful if inhaled.
POTENTIAL HEALTH EFFECTS:
EFFECTS OF OVEREXPOSURE - EYE CONTACT:

May cause eye irritation.

EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May irritate skin. Prolonged
or repeated contact can result in defatting and drying of the skin which
may result in skin irritation and dermatitis (rash).
EFFECTS OF OVEREXPOSURE - INHALATION: Vapor harmful if inhaled. Vapor
may irritate nose and upper respiratory tract. Vapor inhalation may affect
the brain or nervous system causing dizziness, headache or nausea.
EFFECTS OF OVEREXPOSURE - INGESTION: This material may be harmful or fatal
if swallowed. Aspiration of material into the lungs due to vomiting can
cause chemical pneumonitis which can be fatal. If ingested, this product
may cause vomiting, diarrhea, and depressed respiration.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated
permanent brain and nervous system damage with prolonged and repeated
occupational overexposure to solvents. Hexane exposure may cause damage to
the arms and legs which may be permanent. Symptoms include: loss of
memory, loss of intellectual ability, and loss of coordination.
MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY CONTACT:
PRIMARY ROUTE(S) OF ENTRY:

SKIN CONTACT

None known.

INHALATION

|-------------------------------------------------------------------------|
|
SECTION 4 - FIRST AID MEASURES
|
|-------------------------------------------------------------------------|
EYE CONTACT: Flush with large quantities of water until irritation
subsides. Contact a physician.
SKIN CONTACT:

Wash with soap and water.

INHALATION: Remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Contact a physician
immediately. Note: Only trained personnel should give artificial
respiration or administer oxygen.

(Continued on Page 3)
---------------------------------------------------------------------------

Product Name: DAP 2000 HEAVY DUTY ADHESIVE
Revision Date: 07/08/2003
Reviewed:
01/15/2005
Page 3
|-------------------------------------------------------------------------|
|
SECTION 4 - FIRST AID MEASURES
|
|-------------------------------------------------------------------------|
INGESTION: DO NOT INDUCE VOMITING. If irritation or complications arise,
contact a physician or Regional Poison Control Center immediately.
COMMENTS:

None.

|-------------------------------------------------------------------------|
|
SECTION 5 - FIRE FIGHTING MEASURES
|
|-------------------------------------------------------------------------|
FLASH POINT: -34 C
(SETAFLASH CLOSED CUP)

LOWER EXPLOSIVE LIMIT: N.A.
UPPER EXPLOSIVE LIMIT: N.A.

AUTOIGNITION TEMPERATURE: N.E.
EXTINGUISHING MEDIA:

CO2

DRY CHEMICAL

FOAM

UNUSUAL FIRE AND EXPLOSION HAZARDS: Extremely flammable. Material will
readily ignite at room temperature. Vapors may form an explosive mixture
with air. Vapors can travel long distances to a source of ignition and
flashback. Containers may explode if exposed to extreme heat. Eliminate
sources of ignition: heat, electrical equipment, sparks, and flames. Do
not put in contact with
oxidizing or caustic materials.
SPECIAL FIREFIGHTING PROCEDURES: Full protective equipment, including
self-contained breathing apparatus, is recommended to protect from
combustion products. Cool exposed containers with water.
|-------------------------------------------------------------------------|
|
SECTION 6 - ACCIDENTAL RELEASE MEASURES
|
|-------------------------------------------------------------------------|
SPILL OR LEAK PROCEDURES: Dike spill area. Immediately eliminate sources
of ignition. Use absorbent material or scrape up dried material and place
into containers.
|-------------------------------------------------------------------------|
|
SECTION 7 - HANDLING AND STORAGE
|
|-------------------------------------------------------------------------|
HANDLING INFORMATION: KEEP OUT OF REACH OF CHILDREN. Avoid skin and eye
contact. Avoid breathing vapors. Use only in a well ventilated area.
STORAGE INFORMATION: Store away from caustics and oxidizers. Keep away
from heat, spark, and flame. Keep containers tightly closed when not in
use. Keep containers from excessive heat and freezing. Do not store at
temperatures above 49 degrees C.
OTHER PRECAUTIONS: Intentional misuse by deliberately concentrating and
inhaling vapors may be harmful or fatal. Do not take internally.
Construction and repair activities can adversely affect indoor air quality.
Consult with the occupants or a representative (i.e. maintenance, building
(Continued on Page 4)
---------------------------------------------------------------------------

Product Name: DAP 2000 HEAVY DUTY ADHESIVE
Revision Date: 07/08/2003
Reviewed:
01/15/2005
Page 4
|-------------------------------------------------------------------------|
|
SECTION 7 - HANDLING AND STORAGE
|
|-------------------------------------------------------------------------|
manager, industrial hygienist, or safety officer) to determine ways to
minimize any impact.
|-------------------------------------------------------------------------|
|
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
|
|-------------------------------------------------------------------------|
ENGINEERING CONTROLS: Provide sufficient mechanical ventilation (local or
general exhaust) to maintain exposure below PEL and TLV. Vapors are
heavier than air and will collect in low areas. Check all low areas
(basements, sumps, etc.) for vapors before entering.
RESPIRATORY PROTECTION: If 8 hour exposure limit or value is exceeded for
any component, use an approved NIOSH/OSHA respirator. Consult your safety
equipment supplier and the OSHA regulation, 29 CFR 1910.134 for respirator
requirements. A respiratory protection program that meets OSHA 1910.134 and
ANSI Z88.2 requirements must be followed whenever workplace conditions
warrant a respirator's use.
EYE PROTECTION:

Goggles or safety glasses with side shields.

SKIN PROTECTION:

Solvent impervious gloves.

OTHER PROTECTIVE EQUIPMENT:
if body contact may occur.
HYGIENIC PRACTICES:

Provide eyewash and solvent impervious apron

Remove contaminated clothing and wash before reuse.

|-------------------------------------------------------------------------|
|
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
|
|-------------------------------------------------------------------------|
BOILING RANGE
ODOR
APPEARANCE
SOLUBILITY IN H2O
SPECIFIC GRAVITY
VAPOR PRESSURE
PHYSICAL STATE

:
:
:
:
:
:
:

66 - 71 C
VAPOR DENSITY
: Is heavier than air
Gasoline-like
Gray color paste EVAPORATION RATE: Is faster than Butyl
Negligible
Acetate
1.3058
125 mm Hg @ 20 C
Paste

See Section 16 for abbreviation legend)
|-------------------------------------------------------------------------|
|
SECTION 10 - STABILITY AND REACTIVITY
|
|-------------------------------------------------------------------------|
CONDITIONS TO AVOID:
INCOMPATIBILITY:

Excessive heat and freezing.

Strong oxidizers and caustics.

HAZARDOUS DECOMPOSITION PRODUCTS:
NOx

Normal decomposition products, i.e. COx,

(Continued on Page 5)
---------------------------------------------------------------------------

Product Name: DAP 2000 HEAVY DUTY ADHESIVE
Revision Date: 07/08/2003
Reviewed:
01/15/2005
Page 5
|-------------------------------------------------------------------------|
|
SECTION 10 - STABILITY AND REACTIVITY
|
|-------------------------------------------------------------------------|
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
|-------------------------------------------------------------------------|
|
SECTION 11 - TOXICOLOGICAL PROPERTIES
|
|-------------------------------------------------------------------------|
---------------------- TOXICITY DATA -------------------ITEM ORAL-LD50
SKIN-LD50
INHALATION-LC50
--------------------------------------------------------------------------01

28710 mg/kg(rat)

N.A.

N.A.

n-Hexane has shown experimental teratogenic and reproductive affects.
(See Section 16 for abbreviation legend)
|-------------------------------------------------------------------------|
|
SECTION 12 - ECOLOGICAL INFORMATION
|
|-------------------------------------------------------------------------|
No Information.
|-------------------------------------------------------------------------|
|
SECTION 13 - DISPOSAL CONSIDERATIONS
|
|-------------------------------------------------------------------------|
WASTE MANAGEMENT/DISPOSAL: Dispose of according to Federal, State, and
Local Standards. Discarded material should be incinerated at a permitted
facility. Liquids cannot be disposed of in a landfill. Do not reuse empty
container. State and Local regulations/restrictions are complex and may
differ from Federal regulations. Responsibility for proper waste disposal
is with the owner of the waste.
EPA WASTE CODE - If discarded (40 CFR 261): None, yields no liquid
component when evaluated by EPA method 1311 (TCLP)
|-------------------------------------------------------------------------|
|
SECTION 14 - TRANSPORTATION INFORMATION
|
|-------------------------------------------------------------------------|
DOT PROPER SHIPPING NAME: Consumer Commodity
DOT HAZARD CLASS: ORM-D
DOT UN/NA NUMBER: NONE

PACKING GROUP: NONE

Note: The shipping information provided is applicable for domestic ground
transport only. Different categorization may apply if shipped via other
(Continued on Page 6)
---------------------------------------------------------------------------

Product Name: DAP 2000 HEAVY DUTY ADHESIVE
Revision Date: 07/08/2003
Reviewed:
01/15/2005
Page 6
|-------------------------------------------------------------------------|
|
SECTION 14 - TRANSPORTATION INFORMATION
|
|-------------------------------------------------------------------------|
modes of transportation and/or to non-domestic destinations.
Shipped in accordance with 49 CFR as part of a transborder shipment.
|-------------------------------------------------------------------------|
|
SECTION 15 - REGULATORY INFORMATION
|
|-------------------------------------------------------------------------|
U.S. FEDERAL REGULATIONS: AS FOLLOWS OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
----------- CHEMICAL NAME ----------N-Hexane

CAS NUMBER
110-54-3

WT/WT % RANGE
5.0-10.0%

TOXIC SUBSTANCES CONTROL ACT:
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:
----------- CHEMICAL NAME ----------None.

CAS NUMBER

All ingredients are listed on the TSCA inventory
INTERNATIONAL REGULATIONS: AS FOLLOWS CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: Class B2, Class D2B.
|-------------------------------------------------------------------------|
|
SECTION 16 - OTHER INFORMATION
|
|-------------------------------------------------------------------------|
HMIS RATINGS - HEALTH: 2

FLAMMABILITY: 4

REACTIVITY: 0

PREVIOUS MSDS REVISION DATE: 04/17/2000
VOC less water, less exempt solvent: 330-340 g/L (25-26 weight%)
VOC material
: 330-340 g/L

(Continued on Page 7)
---------------------------------------------------------------------------

Product Name: DAP 2000 HEAVY DUTY ADHESIVE
Revision Date: 07/08/2003
Reviewed:
01/15/2005
Page 7
|-------------------------------------------------------------------------|
|
SECTION 16 - OTHER INFORMATION
|
|-------------------------------------------------------------------------|
LEGEND:

ACGIH
N.A.
N.E.
PEL
NTP
SARA
STEL
TLV
VOC
NJRTK
N.D.

-

AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
NOT APPLICABLE
NOT ESTABLISHED
PERMISSIBLE EXPOSURE LIMIT
NATIONAL TOXICOLOGY PROGRAM
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986
SHORT TERM EXPOSURE LIMIT
THRESHOLD LIMIT VALUE(8 HR. TIME WEIGHTED AVERAGE OR TWA)
VOLATILE ORGANIC COMPOUND
NEW JERSEY RIGHT TO KNOW LAW
NOT DETERMINED

MSDS 17008
---------------------------------------------------------------------------

This data is offered in good faith as typical values and not as a product
specification. No warranty either expressed or implied, is hereby made.
The recommended industrial hygiene and safe handling procedures are
believed to be generally applicable. However, each user should review the
recommendations in specific context of the intended use and determine if
they are appropriate.
--------------------------------------------------------------------------< End OF MSDS >

|-------------------------------------------------------|
| M A T E R I A L
S A F E T Y
D A T A
S H E E T |
|-------------------------------------------------------|
|-------------------------------------------------------------------------|
|
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
|
|-------------------------------------------------------------------------|
PRODUCT NAME
UPC NUMBER

: BEATS THE NAIL ENVIROLINE - SQUEEZE TUBE
: 05960

PRODUCT USE/CLASS

: Latex Adhesive

MANUFACTURER:
DAP INC.
2400 BOSTON STREET
BALTIMORE, MD 21224

24 HOUR EMERGENCY:
TRANSPORTATION: 1-800-535-5053 (352-323-3500)
MEDICAL
: 1-800-327-3874 (513-558-5111)

PREPARE DATE : 09/13/1996
GENERAL INFORMATION:
REVISION NO. : 4
DAP INC. : 1-888-DAP-TIPS (1-888-327-8477)
REVISION DATE: 01/04/2000
|-------------------------------------------------------------------------|
|
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
|
|-------------------------------------------------------------------------|
WT/WT %
ITEM
------------ CHEMICAL NAME ------------CAS NUMBER
RANGE
--------------------------------------------------------------------------01

Ethanol

64-17-5

1.0-5.0 %

---------------------- EXPOSURE LIMITS -------------------ACGIH
OSHA
COMPANY
ITEM TLV-TWA
TLV-STEL
PEL-TWA
PEL-CEILING TLV-TWA
SKIN
--------------------------------------------------------------------------01

1000 ppm

N.E.

1000 ppm

N.E.

N.E.

NO

(See Section 16 for abbreviation legend)
Remaining ingredients are not considered hazardous per the OSHA Hazard
Communication Standard.
Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor
OSHA Final Rule Limits (CFR 29 1910.1000); limits may vary between states.
|-------------------------------------------------------------------------|
|
SECTION 3 - HAZARDS IDENTIFICATION
|
|-------------------------------------------------------------------------|
EMERGENCY OVERVIEW: CAUTION! May irritate eyes, skin, nose, and respiratory
tract.

(Continued on Page 2)
---------------------------------------------------------------------------

Product Name: BEATS THE NAIL ENVIROLINE - SQUEEZE TUBE
Revision Date: 01/04/2000
Page 2
|-------------------------------------------------------------------------|
|
SECTION 3 - HAZARDS IDENTIFICATION
|
|-------------------------------------------------------------------------|
POTENTIAL HEALTH EFFECTS:
EFFECTS OF OVEREXPOSURE - EYE CONTACT:
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:

May cause eye irritation.
May cause skin irritation.

EFFECTS OF OVEREXPOSURE - INHALATION: Vapor harmful if inhaled. Vapor
may irritate nose and upper respiratory tract. Vapor inhalation may affect
the brain or nervous system causing dizziness, headache or nausea.
EFFECTS OF OVEREXPOSURE - INGESTION: This material may be harmful or
fatal if swallowed. If ingested this product may cause vomiting, diarrhea,
and depressed respiration.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated
permanent brain and nervous system damage with prolonged and repeated
occupational overexposure to solvents.
MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY CONTACT:
PRIMARY ROUTE(S) OF ENTRY:

None known.

SKIN CONTACT

|-------------------------------------------------------------------------|
|
SECTION 4 - FIRST AID MEASURES
|
|-------------------------------------------------------------------------|
EYE CONTACT: Flush with large quantities of water until irritation
subsides. Contact a physician.
SKIN CONTACT:
INHALATION:

Wash with soap and water.
Remove to fresh air.

INGESTION: DO NOT INDUCE VOMITING.
Control Center immediately.
COMMENTS:

Contact a physician immediately.
Contact a physician or Regional Poison

None.

|-------------------------------------------------------------------------|
|
SECTION 5 - FIRE FIGHTING MEASURES
|
|-------------------------------------------------------------------------|
FLASH POINT: >200 F
(SETAFLASH CLOSED CUP)

LOWER EXPLOSIVE LIMIT: N.A.
UPPER EXPLOSIVE LIMIT: N.A.

|-------------------------------------------------------------------------|
AUTOIGNITION TEMPERATURE: N.E.
EXTINGUISHING MEDIA:

CO2

DRY CHEMICAL

UNUSUAL FIRE AND EXPLOSION HAZARDS:

FOAM

None known.

(Continued on Page 3)
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Product Name: BEATS THE NAIL ENVIROLINE - SQUEEZE TUBE
Revision Date: 01/04/2000

Page

3

|-------------------------------------------------------------------------|
|
SECTION 5 - FIRE FIGHTING MEASURES
|
|-------------------------------------------------------------------------|
SPECIAL FIREFIGHTING PROCEDURES: As in any fire, wear self-contained
breathing apparatus pressure-demand (MSHA/NIOSH approved or equivalent) and
full protective gear. Use water spray to cool exposed surfaces.
|-------------------------------------------------------------------------|
|
SECTION 6 - ACCIDENTAL RELEASE MEASURES
|
|-------------------------------------------------------------------------|
SPILL OR LEAK PROCEDURES:
containers.

Scrape up dried material and place into

|-------------------------------------------------------------------------|
|
SECTION 7 - HANDLING AND STORAGE
|
|-------------------------------------------------------------------------|
HANDLING INFORMATION: KEEP OUT OF REACH OF CHILDREN. Avoid skin and eye
contact. Avoid breathing vapors. Use only in a well ventilated area.
STORAGE INFORMATION: Store away from caustics and oxidizers. Keep
containers tightly closed when not in use. Keep containers from excessive
heat and freezing. Do not store at temperatures above 120 degrees F.
OTHER PRECAUTIONS: Intentional misuse by deliberately concentrating and
inhaling vapors may be harmful or fatal. Do not take internally. Use in a
well ventilated area. Provide fresh air such that chemical odors cannot be
detected during use and while drying. Construction and repair activities
can adversely affect indoor air quality. Consult with the occupants or a
representative(i.e. maintenance, building manager, industrial hygienist, or
safety officer) to determine ways to minimize any impact.
|-------------------------------------------------------------------------|
|
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
|
|-------------------------------------------------------------------------|
ENGINEERING CONTROLS: Provide sufficient mechanical ventilation (local or
general exhaust) to maintain exposure below PEL and TLV. Vapors are heavier
than air and will collect in low areas. Check all low areas (basements,
sumps, etc.) for vapor before entering.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA
1910.134 and ANSI Z88.2 requirements must be followed whenever workplace
conditions warrant a respirator's use. Not required under normal usage and
adequate ventilation.
EYE PROTECTION:
SKIN PROTECTION:
skin.

Goggles or safety glasses with side shields.
Gloves recommended for repeated or prolonged contact with

OTHER PROTECTIVE EQUIPMENT:

None.

(Continued on Page 4)
---------------------------------------------------------------------------

Product Name: BEATS THE NAIL ENVIROLINE - SQUEEZE TUBE
Revision Date: 01/04/2000

Page

4

|-------------------------------------------------------------------------|
|
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
|
|-------------------------------------------------------------------------|
HYGIENIC PRACTICES:

Wash contaminated clothing before reuse.

|-------------------------------------------------------------------------|
|
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
|
|-------------------------------------------------------------------------|
BOILING RANGE
ODOR
APPEARANCE
SOLUBILITY IN H2O
SPECIFIC GRAVITY
VAPOR PRESSURE
PHYSICAL STATE

:
:
:
:
:
:
:

210 - 220 F
VAPOR DENSITY
: Is heavier than air
Mild Odor
White Paste
EVAPORATION RATE: Is slower than Butyl
Miscible
Acetate
1.4115
17.5 mm Hg @ 68F.
Paste

(See Section 16 for abbreviation legend)
|-------------------------------------------------------------------------|
|
SECTION 10 - STABILITY AND REACTIVITY
|
|-------------------------------------------------------------------------|
CONDITIONS TO AVOID:
INCOMPATIBILITY:

Excessive heat and freezing.

Strong oxidizers and caustics.

HAZARDOUS DECOMPOSITION PRODUCTS:
NOx

Normal decomposition products, i.e. COx,

HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
|-------------------------------------------------------------------------|
|
SECTION 11 - TOXICOLOGICAL PROPERTIES
|
|-------------------------------------------------------------------------|
No product or component toxicological information is available.
|-------------------------------------------------------------------------|
|
SECTION 12 - ECOLOGICAL INFORMATION
|
|-------------------------------------------------------------------------|
No Information.

(Continued on Page 5)
---------------------------------------------------------------------------

Product Name: BEATS THE NAIL ENVIROLINE - SQUEEZE TUBE
Revision Date: 01/04/2000

Page

5

|-------------------------------------------------------------------------|
|
SECTION 13 - DISPOSAL CONSIDERATIONS
|
|-------------------------------------------------------------------------|
WASTE MANAGEMENT/DISPOSAL: Dispose of according to Federal, State, and
Local Standards. Do not reuse empty containers. State and Local
regulations/restrictions are complex and may differ from Federal
regulations. Responsibility for proper waste disposal is with the owner of
the waste.
EPA WASTE CODE - If discarded (40 CFR 261):

None.

|-------------------------------------------------------------------------|
|
SECTION 14 - TRANSPORTATION INFORMATION
|
|-------------------------------------------------------------------------|
DOT PROPER SHIPPING NAME: Not Regulated by D.O.T.
DOT HAZARD CLASS: NONE
DOT UN/NA NUMBER: NONE

PACKING GROUP: NONE

|-------------------------------------------------------------------------|
|
SECTION 15 - REGULATORY INFORMATION
|
|-------------------------------------------------------------------------|
U.S. FEDERAL REGULATIONS: AS FOLLOWS OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:

----------- CHEMICAL NAME ----------CAS NUMBER
No SARA Section 313 components exist in this product.

WT/WT % RANGE

TOXIC SUBSTANCES CONTROL ACT:
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:
----------- CHEMICAL NAME ----------No information is available.

CAS NUMBER

NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:

(Continued on Page 6)
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Product Name: BEATS THE NAIL ENVIROLINE - SQUEEZE TUBE
Revision Date: 01/04/2000
Page 6
|-------------------------------------------------------------------------|
|
SECTION 15 - REGULATORY INFORMATION
|
|-------------------------------------------------------------------------|
----------- CHEMICAL NAME ----------Water
Vinyl acetate copolymer
Plasticizer
Calcium Carbonate

CAS NUMBER
7732-18-5
TSRN-618608-5056P
TSRN-618608-5064P
1317-65-3

PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------Water
Vinyl acetate copolymer
Plasticizer
Calcium carbonate

CAS NUMBER
7732-18-5
proprietary
proprietary
1317-65-3

CALIFORNIA PROPOSITION 65:
WARNING: The chemical(s) noted below and contained in this product, are
known to the state of California to cause cancer, birth defects or other
reproductive harm:
----------- CHEMICAL NAME ----------CAS NUMBER
No Proposition 65 chemicals exist in this product.
INTERNATIONAL REGULATIONS: AS FOLLOWS CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: No information available.

(Continued on Page 7)
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Product Name: BEATS THE NAIL ENVIROLINE - SQUEEZE TUBE
Revision Date: 01/04/2000

Page

7

|-------------------------------------------------------------------------|
|
SECTION 16 - OTHER INFORMATION
|
|-------------------------------------------------------------------------|
HMIS RATINGS - HEALTH: 1
FLAMMABILITY: 1
REACTIVITY: 0
PREVIOUS MSDS REVISION DATE: 02/01/1997

REASON FOR REVISION:
SECTION 1: Address change and new emergency contact phone numbers.
VOC less water, less exempt solvent: 80-85 gm/l(6%)
VOC material: 50-55 gm/l(5-6%)
LEGEND:

ACGIH
N.A.
N.E.
PEL
NTP
SARA
STEL
TLV
VOC
NJRTK
N.D.

-

AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
NOT APPLICABLE
NOT ESTABLISHED
PERMISSIBLE EXPOSURE LIMIT
NATIONAL TOXICOLOGY PROGRAM
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986
SHORT TERM EXPOSURE LIMIT
THRESHOLD LIMIT VALUE(8 HR. TIME WEIGHTED AVERAGE OR TWA)
VOLATILE ORGANIC COMPOUND
NEW JERSEY RIGHT TO KNOW LAW
NOT DETERMINED

MSDS# 77086
---------------------------------------------------------------------------

This data is offered in good faith as typical values and not as a product
specification. No warranty either expressed or implied, is hereby made.
The recommended industrial hygiene and safe handling procedures are
believed to be generally applicable. However, each user should review the
recommendations in specific context of the intended use and determine if
they are appropriate.
--------------------------------------------------------------------------< End OF MSDS >

00010009605 English

Page 1 of 7

Material
Safety
Data
Sheet

24 Hour Emergency Phone Numbers:
Medical/Poison Control:
In U.S.: Call 1-800-222-1222
Outside U.S.: Call your local poison
control center
Transportation/National Response
Center:
1-800-535-5053
1-352-323-3500

NOTE: The National Response Center emergency numbers to
be used only in the event of chemical emergencies involving a
spill, leak, fire, exposure or accident involving chemicals.

IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of
this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16.

Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
On peut demader cette fiche signalétique (MSDS) a la langue francaise-canadienne.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.

Product Name:
Product UPC
Number:
Product Use/Class:
Manufacturer:

Kwik Seal Tub & Tile Adhesive Caulk - All
Colors
070798710504, 070798710207,
070798710238
Latex Caulk

Revision
Date:
Supercedes:

05/21/2008

MSDS
Number:

00010009605

04/27/2005

DAP Canada
475 Finchdene Square Unit 5
Scarborough, Ontario M1X 1B7
888-327 -8477 (non-emergency)

Section 2 - Hazards Identification
Emergency Overview: A colored paste product with a very slight ammonia odor. WARNING! May cause eye, skin, nose,
throat and respiratory tract irritation. May cause eye or skin irritation. Harmful if swallowed or absorbed through the skin.
This product contains ethylene glycol.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: May cause eye irritation.
Effects Of Overexposure - Skin Contact: May cause skin irritation. Harmful if absorbed through the skin.
Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation of high concentrations may cause headache,
nausea, and dizziness. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes).
Inhalation may cause mild irritation to the respiratory tract (nose, mouth, mucous membranes).
Effects Of Overexposure - Ingestion: Ingestion of ethylene glycol can cause gastrointestinal irritation, nausea,
vomiting, diarrhea and if ingested in sufficient quantities, death. Harmful or fatal if swallowed. Ingestion may cause
gastrointestinal irritation, nausea, vomiting and diarrhea. If ingested, may cause vomiting, diarrhea, and depressed
respiration. Ingestion may result in obstruction when material hardens.
Effects Of Overexposure - Chronic Hazards: Repeated or prolonged exposure may cause skin, respiratory, kidney and

00010009605 English

Page 2 of 7

liver damage. Prolonged and repeated skin contact may cause irritation and possibly dermatitis.
The International Agency for Research on Cancer (IARC) has determined that crystalline silica in the form of quartz or
cristobalite that is inhaled from occupational sources is carcinogenic to humans (Group 1- carcinogenic to humans). Refer
to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (published in June 1997) in conjunction with the use of
these materials. The National Toxicology Program (NTP) classifies respirable crystalline silica as "known to be a human
carcinogen". Refer to the 9th Report on Carcinogens (2000). The American Conference of Governmental Industrial
Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (Group A2).
Breathing dust containing respirable crystalline silica may not cause noticeable injury or illness even though permanent
lung damage may be occurring. Inhalation of dust may have the following serious chronic health effects: Excessive
inhalation of respirable dust can cause pneumoconiosis, a respiratory disease, which can result in delayed, progressive,
disabling and sometimes fatal lung injury. Symptoms include cough, shortness of breath, wheezing, non-specific chest
illness and reduced pulmonary function. Smoking exacerbates this disease. Individuals with pneumoconiosis are
predisposed to develop tuberculosis. There is some evidence that breathing respirable crystalline silica or the disease
silicosis is associated with an increased incidence of significant disease endpoints such as scleroderma (an immune
system disorder manifested by fibrosis of the lungs, skin and other internal organs) and kidney disease. Prolonged,
repeated, or high exposures may cause weakness and depression of the central nervous system.
Formaldehyde vapor is a known animal carcinogen according to OSHA and NTP and is considered possibly carcinogenic
to humans by inhalation. The International Agency for Research on Cancer considers formaldehyde to be a human
carcinogen.
A mixture of diisodecyl phthalate and diisononyl phthalate has been tested in a two-generation toxicity study in laboratory
animals. No effects on reproductive parameters were seen. However, a small but statistically significant increase in early
offspring mortality was seen at high oral doses. The significance of this to humans is uncertain.
The mixture of phthalate esters contained within this product has been shown to cause developmental effects at high
doses in laboratory animals when administered orally by gavage in a developmental study and developmental and fertility
effects when administered at high doses by feed in a two-generation reproduction study. The potential risk from
occupational and consumer exposure is considered to be very low, based on limited relevance of the rodent findings to
humans and the large safety margins between exposure and the effect levels.
Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Studies have shown
that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals. Ethylene
glycol has been shown to cause birth defects in laboratory animals.
Primary Route(s) Of Entry: Skin Contact, Inhalation, Eye Contact
Medical Conditions which May be Aggravated by Exposure: None known.
Carcinogenicity:
CAS No.

Chemical Name

13463-67-7

Titanium dioxide

14808-60-7

Silica, crystalline

50-00-0

Formaldehyde

ACGIH

OSHA

IARC

NTP

Not Listed.
Suspected human
carcinogen.
Suspected human
carcinogen.

Not Listed.

Possible carcinogen.

Not Listed.

Not Listed.

Human carcinogen.

Known carcinogen.

Potential cancer hazard.

Human carcinogen.

Anticipated carcinogen.

Section 3 - Composition / Information On Ingredients
Chemical Name
Limestone
Branched and linear phthalates
Titanium dioxide
n-Butyl acetate
Silica, crystalline
Ethylene glycol
Formaldehyde

CASRN
1317-65-3
Proprietary
13463-67 -7
123-86-4
14808-60 -7
107-21-1
50-00 -0

Wt%
30 -60
1-5
0.1-1.0
0.1-1.0
0.1-1.0
0.1-1.0
<0.02

00010009605 English

Page 3 of 7

Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes
until irritation subsides. Get medical attention immediately.
First Aid - Skin Contact: Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical aid if
symptoms persist. If skin irritation persists, call a physician. Remove and wash contaminated clothing. In case of contact,
immediately flush skin with plenty of water while removing contaminated clothing and shoes.
First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If
continued breathing difficulty is experienced, get medical attention immediately.
First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately. If ingested, drink 2
glasses of water. Immediately see a physician. Never give anything by mouth to an unconscious person.
Note to Physician: None.
COMMENTS: If over-exposure occurs, call your local poison control center.

Section 5 - Fire Fighting Measures
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: No special protective measures against fire required.
Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or
equivalent) and full protective gear. Use water spray to cool exposed surfaces.

Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use
absorbent material or scrape up dried material and place in container.

Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Avoid breathing vapor and contact
with eyes, skin and clothing. Use only with adequate ventilation. Open all windows and doors or use other means to
ensure cross-ventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous
conditions. Wash thoroughly after handling.
Storage: Do not store at temperatures above 120 degrees F. Store containers away from excessive heat and freezing.
Close container after each use. Store away from caustics and oxidizers.

Section 8 - Exposure Controls / Personal Protection
Chemical Name

CASRN

ACGIH TWA

ACGIH STEL

ACGIH CEIL

Limestone

1317-65-3

10 MGM3

N.E.

N.E.

Branched and linear phthalates
Titanium dioxide
n-Butyl acetate

Proprietary
13463-67-7
123-86-4

N.E.
10 MGM3
150 PPM

N.E.
N.E.
200 PPM

N.E.
N.E.
N.E.

Silica, crystalline

14808-60-7

0.025 MGM.

N.E.

N.E.

Ethylene glycol
Formaldehyde

107-21-1
50-00-0

N.E.
N.E.

N.E.
N.E.

100 MGM3
0.3 PPM

OSHA TWA
5 MGM3
(respirable
fraction)
N.E.
15 MGM3
150 PPM
10/(%SiO2 + 2)
MGM3
N.E.
0.75 PPM

OSHA STEL

OSHA CEIL

Skin

N.E.

N.E.

No

N.E.
N.E.
N.E.

N.E.
N.E.
N.E.

No
No
No

N.E.

N.E.

No

N.E.
2 PPM

N.E.
N.E.

No
No

00010009605 English

Page 4 of 7

Exposure Notes:
14808-60-7 The 2002 ACGIH Threshold Limit Values for Chemical Substances and Physical Agents lists the median
Respirable Particulate Mass (RPM) point for crystalline silica at 4.0 microns in terms of the particle's aerodynamic
diameter.
The TLVs for crystalline silica represent the respirable fraction.
OSHA PEL TWA for Quartz is calculated using the following formula: 10 mg/m3/(% SiO2 + 2). Both concentration and
percent quartz for the application of this limit are to be determined from the fraction passing a size selector with the
following characteristics.
|------------------------------------------------------------------------------------ |-----------------------------------------|
| ....... Aerodynamic diameter ( unit density sphere ) .....| Percent passing selector |
| 2 ................................................................................|.................90....................|
| 2.5 .............................................................................|..................75...................|
| 3.5 .............................................................................|..................50...................|
| 5.0 .............................................................................|..................25...................|
| 10 ..............................................................................|...................0....................|
50-00-0 Formaldehyde is a specially regulated substance for which an OSHA chemical-specific exposure standard exits.
Detailed information regarding this substance may be found in 29 CFR 1910.1048. Medical surveillance information
regarding this substance may be found in Appendix C to 29 CFR 1910.1048.
Precautionary Measures: Contact lenses pose a special hazard; soft lenses may absorb and all lenses concentrate
irritants.
Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Ensure adequate
ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient
concentrations below recommended exposure limits.
Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSH-approved air
purifying respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where
airborne concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA
1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.
National Institute for Occupational Safety and Health (NIOSH) has recommended that the permissible exposure limit be
changed to 50 micrograms respirable free silica per cubic meter of air (0.05 mg/m3) as determined by a full shift sample
up to 10-hour work shift.
Skin Protection: Rubber gloves. Natural rubber, butyl rubber and polyvinyl chloride gloves are not suitable protection
against the phthalates contained within this product; neoprene is recommended.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: Not required under normal use.
Hygienic Practices: Wash hands before breaks and at the end of workday. Remove and wash contaminated clothing
before re-use.
Important:

Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary
between states.

Note:

An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent
necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work
practices.

Section 9 - Physical And Chemical Properties
Boiling Range:
Odor:

210 - 220 F
Very Slight Ammonia

Vapor Density:
Odor Threshold:

Heavier Than Air
Not Established

00010009605 English
Color:
Solubility in H2O:
Freeze Point:
Vapor Pressure:
Physical State:
Flash Point, F:
Lower Explosive Limit, %:

Page 5 of 7
Colored
Not Established
Not Established
Not Established
Paste
> 200 F
Not Established

Evaporation Rate:
Slower Than n-Butyl Acetate
Specific Gravity:
1.6
pH:
Between 7.0 and 12.0
Viscosity:
Not Established
Flammability:
Non-Flammable
Method:
(Seta Closed Cup)
Upper Explosive Limit, %:Not Established

When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally.
(See section 16 for abbreviation legend)

Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Incompatible with strong bases and oxidizing agents.
Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under recommended storage conditions.

Section 11 - Toxicological Information
Product LD50: Not Established
CASRN
123-86-4
107-21-1
50-00-0

Chemical Name

n-Butyl acetate
Ethylene glycol
Formaldehyde

Product LC50: Not Established
LD50
Rat:10768 MG/KG
Rat:4700 mg/kg
-------------

LC50
Rat:2000 P
Rat:10876 mg/kg
Rat:203 mg/m3

Significant Data with Possible Relevance to Humans: This product contains trace amounts of free formaldehyde.
OSHA and NTP identify formaldehyde as a potential carcinogen. IARC identifies formaldehyde as a human carcinogen.
Formaldehyde has been shown to cause mutations in a variety of in-vitro test systems, the significance of which to
humans is unknown. There should be minimal risk when used with ventilation adequate to keep the atmospheric
concentration of formaldehyde below the recommended exposure limits.
Maintain adequate ventilation to prevent exposure above current OSHA / ACGIH exposure limits. Workplace monitoring of
the air to define formaldehyde exposure levels may be necessary.
In a two-year inhalation study, rats showed carcinogenic effects in the respiratory system at 15 ppm of formaldehyde.

Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.

Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local
regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is
with the owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): This product does not meet the definition of a hazardous waste
according to U.S. EPA Hazardous Waste Management Regulation, 40 CFR Section 261.

Section 14 - Transportation Information

00010009605 English
DOT Proper Shipping
Name:
DOT Technical Name:
DOT Hazard Class:

Page 6 of 7
Not Regulated

Packing Group:

N.A.

N.A.
N.A.

Hazard Subclass:
DOT UN/NA Number:

N.A.
None

Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may
apply if shipped via other modes of transportation and/or to non-domestic destinations.

Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of
the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable
definitions, to meet the following categories:
Immediate Health Hazard, Chronic Health Hazard
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
None
Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported
from the United States:
Chemical Name

CAS Number

Mercury & compounds

7439-97-6

Canadian WHMIS:
This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings.
Canadian WHMIS Class: Not Controlled.

Section 16 - Other Information
HMIS Ratings:
Health: 1

Flammability: 1

Reactivity: 0

Volatile Organic Compounds (VOC), less water less exempts: g/L:

Personal Protection: X
25.4

Volatile Organic Compounds (VOC), less water less exempts, less LVP -VOCs:

lb/gal: 0.2

wt:wt%: 1.1

wt:wt%: 0.6

REASON FOR REVISION: Periodic Update
Legend:

N.A. – Not Applicable

ACGIH – American Conference of Governmental Industrial Hygienists

00010009605 English

Page 7 of 7

N.E. – Not Established

SARA – Superfund Amendments and Reauthorization Act of 1986

N.D. – Not Determined

NJRTK – New Jersey Right-to-Know Law

VOC – Volatile Organic Compound

OSHA – Occupational Safety and Health Administration

PEL – Permissible Exposure Limit

HMIS – Hazardous Materials Identification System

TLV – Threshold Limit Value

NTP – National Toxicology Program

CEIL – Ceiling Exposure Limit

STEL – Short Term Exposure Limit

LD50 – Lethal Dose 50

LC50 – Lethal Concentration 50

F – Degree Fahrenheit

MSDS – Material Safety Data Sheet

C – Degree Celsius

CASRN – The Chemical Abstracts Service Registry Number

DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this
document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained
person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context
of the intended use and (ii) determine if they are appropriate.


MATERIAL SAFETY DATA SHEET

PRODUCT: HANDI FOAM®
MSDS No: 01009

ISSUE:

2

DATE OF ISSUE

7/7/03

Page 1 of 4

- Classified as Hazardous according to the criteria of NOHSC Ramset Fasteners (Aust) Pty Limited ACN 004 297 009
A Division of ITW Construction Products
Maroondah Highway,
Mooroolbark. Victoria. Australia. 3136
Telephone: 03 9726 6222
Emergency Telephone Number: 03 9726 6222 (Monday to Friday. 8 am to 5 pm EST)
PRODUCT IDENTIFICATION
Product Name:
Manufacturer’s Product Code:
Other Names:
UN Number:
Dangerous Goods Code:
Hazchem Code:
Poisons Schedule:

Handi Foam®
HDFM105, HDFM205, HDFM605
None
UN1956
2.2
2T
S6

Primary Use:
A two component expanding foam for filling large cavities. The two components are under
pressure. The operator releases a trigger, which causes the components to mix together
through a static mixing nozzle. The components react rapidly to form a solid foam mass.
Physical Description / Properties
Appearance:

Specific Gravity:
Flammability Limit:
Form:
Boiling Point:
Vapour Pressure:
Flashpoint:
Solubility in Water:
Other Properties:

Part A (Isocyanate): Amber to dark brown liquid. Froths when
released from container.
Part B (Resin): Light yellow to amber coloured liquid. Froths
when released from container.
1.2 (Both components)
Not Flammable
Liquid
-26°C: 1,1,1,2 – Tetrafluoroethane
Contents under pressure 345 Kpa.
Not flammable
Part A: Insoluble. Reacts to form a solid and CO2. Part B:
Partially soluble.
None

Ingredients
Chemical Name
Part A
1,1,1,2 – Tetrafluoroethane
4,4’ – Diphenylmethane Diisocyanate (MDI)
Higher Oligomers of MDI (Polymeric MDI)
Part B
1,1,1,2 – Tetrafluoroethane
Components not classified as hazardous

CAS Number

Proportion

811-97-2
101-68-8
9016-87-9

10 - 30%
30 – 60%
30 – 60%

811-97-2

10 - <30%
To 100%

MATERIAL SAFETY DATA SHEET

PRODUCT: HANDI FOAM®
MSDS No: 01009

ISSUE:

2

DATE OF ISSUE

7/7/03

Page 1 of 4

HEALTH HAZARD INFORMATION
Health Effects
Acute:
Eye – May cause irritation. May damage eyes due to adhesion.
Skin – Will adhere to skin. May cause localised irritation, reddening or swelling. Prolonged or
repeated exposure may lead to sensitisation and /or contact dermatitis.
Inhaled – May irritate mucus membranes with tightness in chest, coughing or allergic
asthma-like sensitivity. Extensive overexposure can lead to respiratory symptoms like
bronchitis and pulmonary oedema. These effects are usually reversible.
Ingestion: May cause irritation to mucus membranes in the mouth and digestive tract.
Chronic:
Overexposure to 1,1,1,2 – Tetrafluoroethane may cause light-headedness, headaches or
lethargy. Persons with cardiac arrhythmia may be at increased risk in severe overexposure.
Overexposure to MDI may cause sensitisation by inhalation.
First Aid
****Take a copy of this MSDS to the Doctor****
Eyes – Flush with water for at least 15 minutes with eyelids held open. Seek immediate
medical attention.
Skin – Remove contaminated clothing. Acetone or nail polish remover will assist removal of
the residue. DO NOT apply acetone or solvents to eyes or other sensitive skin areas.
Acetone will defat skin and may cause dermatitis in some individuals. Wash skin thoroughly
with soap and water and apply moisturiser. Alternatively, allow foam to harden and remove
mechanically. Foam residue will come off skin gradually over a period of a few days. If
irritation persists seek medical attention.
Inhaled – If breathing difficulty experienced, remove to fresh air. If symptoms persist seek
medical attention.
Swallowed – Rinse out with plenty of water. If poisoning occurs, contact doctor or Poisons
Information Centre. If swallowed do not induce vomiting. Give a glass of water.
First Aid Facilities – Eye wash stations
Advice to Doctor:
Treat symptomatically.

MATERIAL SAFETY DATA SHEET

PRODUCT: HANDI FOAM®
MSDS No: 01009

ISSUE:

2

DATE OF ISSUE

7/7/03

Page 1 of 4

PRECAUTIONS FOR USE
Exposure Limits:
None assigned by NOHSC
Exposure Guidelines
MDI
Higher oligomers of MDI
1,1,1,2 – Tetrafluoroethane

OSHA
0.020 ppm ceiling
None Established
None Established

ACGIH
0.005 ppm TWA
None Established
None Established

Engineering Controls:
Dilution ventilation to keep concentration below recommended limits
Personal Protection:
Eyes – Safety glasses with side shields, chemical goggles. Contact lenses pose a hazard.
Hands – Barrier cream and PVC gloves should be worn.
Feet – Rubber boots.
Respiratory system – Respirator in accordance with AS1716 Respiratory Protective Devices,
where ventilation is not adequate.
Clothing – Wear long sleeved overalls. Eyewash unit should be present to flush eyes in the
event of contamination.
Flammability:
Non flammable.
SAFE HANDLING INFORMATION
Storage and Transport.
Contents under pressure. Store in a cool, dry place. Ideal storage temperature is 16°C to
27°C. Storage above 32°C will shorten shelf life. Protect containers from physical abuse.
Storage below 13°C will affect properties of dispensed foam. Protect product from freezing.
UN 1956 Class 2.2 Non Flammable Compressed Gas
Spills and Disposal
If either Part A or Part B are spilled on their own. Wear skin, eye and respiratory protection.
Soak up material with absorbent and shovel into chemical waste container. Loosely cover
container and remove from work area. Decontaminate waste and spill area with a solution of
0.2- 0.5% liquid detergent and 3 – 8 % concentrated ammonium hydroxide in water (5 – 10%
sodium bicarbonate may be substituted for ammonium hydroxide). Use 10 parts of solution
for each part of spill and allow to react for at least 10 minutes. Allow loosely covered

MATERIAL SAFETY DATA SHEET

PRODUCT: HANDI FOAM®
MSDS No: 01009

ISSUE:

2

DATE OF ISSUE

7/7/03

Page 1 of 4

container to stand for several days before disposing of in accordance with directions from
local authorities.
Cured foam can be removed from surfaces mechanically.
Fire / Explosion Hazard
Not flammable. Contents under pressure. High temperatures will raise the pressures in the
containers, which may lead to rupturing. Extinguishing media include: dry chemical, carbon
dioxide, halon 1211, chemical foam or water spray if used in large quantities. (water
contamination will produce carbon dioxide. Fire fighters to wear self-contained breathing
apparatus. Combustion of components or cured foam will result in decomposition to produce
CO, CO2, NO and other oxides of nitrogen and carbon and traces of HCN or HCl.
Reactivity: Stable under recommended storage conditions.
Incompatibilities: Alcohols, strong bases, amines, metal compounds (such as small particle
metal catalysts) and water.
OTHER INFORMATION
No data
CONTACT POINT

Product Manager – Construction Chemicals
03 9726 6222

MATERIAL SAFETY DATA SHEET
MSDS Name: SA-167 SILICONIZED ACRYLIC LATEX CAULK
MSDS Number: 16711-001
Version Number
2
MSDS Date:
SEP-09-2002
Page Number:
1
-----------------------------------------------------------------------------

SECTION I - PRODUCT AND COMPANY INFORMATION

Product Name:
HMIS Hazard Rating:

SA-167 SILICONIZED ACRYLIC LATEX CAULK
Health: 1 Fire: 0 Reactivity: 0 PPE: B

Company Identification:

OSI SEALANTS, INC.a Subsidiary
of Sovereign Specialty Chems.
7405 PRODUCTION DRIVE
MENTOR OH 44060

Information phone/Fax:
Emergency Phone (24 hour)
Chemtrec (outside-USA)

(440) 255-8900 (440) 974-8358
CHEMTREC
(800) 424-9300
(703) 527-3887

Product Class
Trade Name
Product Code

CAULK
PRO-SERIES
16711-XXX

SECTION II - INGREDIENT AND HAZARD INFORMATION
Hazardous Ingredient Name
CAS Number

Percent

Titanium Dioxide **

13463-67-7

< 5.0

Y

ETHYLENE GLYCOL

107-21-1

< 2.0

Y

MINERAL SPIRITS

64742-48-9

< 2.0

Y

TSCA

Ingredient Notes:
Remaining ingredients are not considered OSHA hazardous.
**The main hazard for Titanium Dioxide is dust inhalation. Because of
its incorporation into the caulk, exposure by inhalation is unlikely.
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION III - PHYSICAL AND CHEMICAL PROPERTIES
Form:
High viscosity caulk
Appearance/Color:
various colors
Solubility (in water):
yes
pH Value, +/-.3:
7.5
--------------------------------------------------------------------------------

MATERIAL SAFETY DATA SHEET
MSDS Name: SA-167 SILICONIZED ACRYLIC LATEX CAULK
MSDS Number: 16711-001
Version Number
2
MSDS Date:
SEP-09-2002
Page Number:
2
----------------------------------------------------------------------------Boiling Range:
Vapor Pressure (mmHg):
Evaporation Rate:

212.øF (100.øC)
15.@ 68.øF (20.øC)
0.5 times Slower than n-Butyl Acetate

Vapor Density:

Heavier than air

% Volatile, Weight
% Volatile, Volume
Specific Gravity:
VOC (less H2O or exempt)

approx. 20.%
approx. 30.%
1.556
41 Gr/L (2%)

NOTE:
Odor : Mild acrylic odor.

Freeze Point : 32 Deg F

- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION IV - FIRE FIGHTING MEASURES (Flash,UEL,LEL for solvent only)
Flammability Class
N/A
Flash Range:
Not Available
Explosive Range (LEL/UEL):
Not Applicable

EXTINGUISHING MEDIA:
Dry chemical -- Carbon Dioxide -- Foam -- Water Fog
Will not burn in wet state.
SPECIAL FIRE-FIGHTING PROCEDURES:
Water may be used to cool and protect exposed containers.
Caution should be taken because uncured material is water soluble.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Any closed container may burst when exposed to extreme
heat or fire.
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION V - HEALTH HAZARD DATA
ROUTES OF ENTRY:
ENTRY THROUGH...Inhalation and skin most likely
CARCINOGENICITY...
NTP? N/E
|
IARC Monographs? N/E
|
OHSA? NO
EFFECTS OF OVEREXPOSURE
Inhalation:
May irritate respiratory tract.
Skin/Eye Contact: May cause irritation.
Ingestion:
Swallowing large amounts may cause nausea,
vomiting. ( an unlikely route of entry )
--------------------------------------------------------------------------------

MATERIAL SAFETY DATA SHEET
MSDS Name: SA-167 SILICONIZED ACRYLIC LATEX CAULK
MSDS Number: 16711-001
Version Number
2
MSDS Date:
SEP-09-2002
Page Number:
3
----------------------------------------------------------------------------FIRST AID MEASURES
Inhalation:
If affected by inhalation, remove to fresh air.
Eye Contact: Flush with water for at least 15 minutes, and
get prompt medical attention.
Skin Contact: Wash skin thoroughly with soap and water.
Ingestion:
Drink water, and get medical attention.
------------------------------------------------------------------N/A= Not applicable N/AV=Not available N/E, N/est=Not established
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION VI - STABILITY AND REACTIVITY
Stability:
This product is stable
Hazardous Polymerization:
Hazardous polymerization will not occur
INCOMPATABILITY:
None
CONDITIONS TO AVOID:
None
HAZARDOUS DECOMPOSITION PRODUCTS:
May produce oxides of carbon and oxides of nitrogen when burned.
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION VII - ACCIDENTAL RELEASE AND DISPOSAL MEASURES:
STEPS TO BE TAKEN IN CASE OF SPILL:
Wear appropriate protective clothing. Add dry absorbent and
shovel or sweep up. Place in an appropriate container and seal.
WASTE DISPOSAL METHOD:
Dispose of in accordance with Federal, State, and Local regulations.
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
ACGIH TLV
ACGIH TLV-C

ACGIH STEL

OSHA STEL

OSHA PEL

Titanium Dioxide **
10.00 mg/F3

N/est

N/est

N/est

15.00 mg/F3

ETHYLENE GLYCOL
50.00 PPM

N/est

N/est

N/est

50.00 PPM

MINERAL SPIRITS
100.00 PPM

N/est

N/est

N/est

100.00 PPM

--------------------------------------------------------------------------------

MATERIAL SAFETY DATA SHEET
MSDS Name: SA-167 SILICONIZED ACRYLIC LATEX CAULK
MSDS Number: 16711-001
Version Number
2
MSDS Date:
SEP-09-2002
Page Number:
4
-----------------------------------------------------------------------------

RESPIRATORY PROTECTION:
NIOSH respirators recommended if vapors and mists are generated.
VENTILATION:
Local exhaust is recommended for safe practice.
PROTECTIVE CLOTHING:
Gloves and clothing should be worn to prevent repeated skin contact.
EYE PROTECTION:
Splashproof goggles or safety glasses should be worn.
HANDLING AND STORAGE PRECAUTIONS:
Keep from freezing.
Keep away from heat.
Keep containers closed when not in use.
Avoid prolonged or repeated contact with skin.
Keep out of the reach of children.
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION IX - TRANSPORT INFORMATION:
DOT

CLASSIFICATIONS FOR ONE GALLON AND UNDER CONTAINERS

DESCRIPTION:
Non-hazardous
DOT CLASSIFICATIONS for OVER 1 GALLON size CONTAINERS
DESCRIPTION:

Non-hazardous,

Caulking product

- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION X - REGULATORY INFORMATION:
SARA TITLE III SECTION 313:
This product contains the following toxic chemicals subject to the
reporting requirements of Section 313 of the Emergency Planning and
Community Right to Know Act of 1986 and of 40 CFR 372:
Ingredient Name

CAS Number

Percent

ETHYLENE GLYCOL

107-21-1

< 2.0

The following ingredients are registered for TSCA 12B
Ingredient Name
CAS Number

Percent

ETHYLENE GLYCOL

< 2.0

107-21-1

Ethylene Glycol fits the EPA Hazard Category definition of Immediate
(Acute) and Delayed (Chronic) Health Hazards under SARA Sect.311,312.
--------------------------------------------------------------------------------

MATERIAL SAFETY DATA SHEET
MSDS Name: SA-167 SILICONIZED ACRYLIC LATEX CAULK
MSDS Number: 16711-001
Version Number
2
MSDS Date:
SEP-09-2002
Page Number:
5
----------------------------------------------------------------------------All chemical substances are TSCA listed.
California PROP.65 Chemicals:
none known
DISCLAIMER:
The information contained herein is based on data available as of
the date of preparation of this MSDS and which we believe to be
reliable. However, no warranty is expressed or implied regarding
the accuracy of the data. We shall not be responsible for the use
of this information, or of any product, method, or apparatus mentioned, and the user must make his own investigation to determine
the suitability of the information or products for his particular
purpose, for the protection of the environment, and the health and
safety of the users of this material.

--------------------------------------------------------------------------------

Last Page

00010011605 English

Page 1 of 7

Material
Safety
Data
Sheet

24 Hour Emergency Phone Numbers:
Medical/Poison Control:
In U.S.: Call 1-800-222-1222
Outside U.S.: Call your local poison
control center
Transportation/National Response
Center:
1-800-535-5053
1-352-323-3500

NOTE: The National Response Center emergency numbers to
be used only in the event of chemical emergencies involving a
spill, leak, fire, exposure or accident involving chemicals.

IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of
this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16.

Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
On peut demader cette fiche signalétique (MSDS) a la langue francaise-canadienne.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.

Product Name:
Product UPC
Number:
Product Use/Class:
Manufacturer:

DAP Alex Painters Acrylic Latex Caulk - All
Colors
070798736313, 070798736351

Revision
Date:
Supercedes:

04/01/2008

Latex Caulk

MSDS
Number:

00010011605

10/29/2004

DAP Canada
475 Finchdene Square Unit 5
Scarborough, Ontario M1X 1B7
888-327 -8477 (non-emergency)

Section 2 - Hazards Identification
Emergency Overview: A colored paste product with a very slight ammonia odor. WARNING! May cause eye, skin, nose,
throat and respiratory tract irritation. May cause eye or skin irritation. Harmful if swallowed or absorbed through the skin.
This product contains ethylene glycol.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: May cause eye irritation.
Effects Of Overexposure - Skin Contact: May cause skin irritation. Harmful if absorbed through the skin.
Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation of high concentrations may cause headache,
nausea, and dizziness. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes).
Inhalation may cause mild irritation to the respiratory tract (nose, mouth, mucous membranes).
Effects Of Overexposure - Ingestion: Ingestion of ethylene glycol can cause gastrointestinal irritation, nausea,
vomiting, diarrhea and if ingested in sufficient quantities, death. Harmful or fatal if swallowed. Ingestion may cause
gastrointestinal irritation, nausea, vomiting and diarrhea. If ingested, may cause vomiting, diarrhea, and depressed
respiration. Ingestion may result in obstruction when material hardens.
Effects Of Overexposure - Chronic Hazards: Repeated or prolonged exposure may cause respiratory system damage.

00010011605 English

Page 2 of 7

Prolonged and repeated skin contact may cause irritation and possibly dermatitis.
The International Agency for Research on Cancer (IARC) has determined that crystalline silica in the form of quartz or
cristobalite that is inhaled from occupational sources is carcinogenic to humans (Group 1- carcinogenic to humans). Refer
to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (published in June 1997) in conjunction with the use of
these materials. The National Toxicology Program (NTP) classifies respirable crystalline silica as "known to be a human
carcinogen". Refer to the 9th Report on Carcinogens (2000). The American Conference of Governmental Industrial
Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (Group A2).
Breathing dust containing respirable crystalline silica may not cause noticeable injury or illness even though permanent
lung damage may be occurring. Inhalation of dust may have the following serious chronic health effects: Excessive
inhalation of respirable dust can cause pneumoconiosis, a respiratory disease, which can result in delayed, progressive,
disabling and sometimes fatal lung injury. Symptoms include cough, shortness of breath, wheezing, non-specific chest
illness and reduced pulmonary function. Smoking exacerbates this disease. Individuals with pneumoconiosis are
predisposed to develop tuberculosis. There is some evidence that breathing respirable crystalline silica or the disease
silicosis is associated with an increased incidence of significant disease endpoints such as scleroderma (an immune
system disorder manifested by fibrosis of the lungs, skin and other internal organs) and kidney disease. Prolonged,
repeated, or high exposures may cause weakness and depression of the central nervous system. Overexposure may
cause kidney, cardiovascular, skin and liver damage.
Formaldehyde vapor is a known animal carcinogen according to OSHA and NTP and is considered possibly carcinogenic
to humans by inhalation. The International Agency for Research on Cancer considers formaldehyde to be a human
carcinogen.
A mixture of diisodecyl phthalate and diisononyl phthalate has been tested in a two-generation toxicity study in laboratory
animals. No effects on reproductive parameters were seen. However, a small but statistically significant increase in early
offspring mortality was seen at high oral doses. The significance of this to humans is uncertain.
The mixture of phthalate esters contained within this product has been shown to cause developmental effects at high
doses in laboratory animals when administered orally by gavage in a developmental study and developmental and fertility
effects when administered at high doses by feed in a two-generation reproduction study. The potential risk from
occupational and consumer exposure is considered to be very low, based on limited relevance of the rodent findings to
humans and the large safety margins between exposure and the effect levels.
Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Studies have shown
that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals. Ethylene
glycol has been shown to cause birth defects in laboratory animals.
Primary Route(s) Of Entry: Skin Contact, Inhalation, Eye Contact
Medical Conditions which May be Aggravated by Exposure: None known.
Carcinogenicity:
CAS No.

Chemical Name

14808-60-7

Silica, crystalline

13463-67-7

Titanium dioxide

50-00-0

Formaldehyde

ACGIH

OSHA

Suspected human
carcinogen.
Not Listed.
Suspected human
carcinogen.

IARC

NTP

Not Listed.

Human carcinogen.

Known carcinogen.

Not Listed.

Possible carcinogen.

Not Listed.

Potential cancer hazard.

Human carcinogen.

Anticipated carcinogen.

Section 3 - Composition / Information On Ingredients
Chemical Name
Limestone
Branched and linear phthalates
Stoddard solvent
Ethylene glycol
Silica, crystalline
Titanium dioxide

CASRN
1317-65-3
Proprietary
8052-41-3
107-21-1
14808-60 -7
13463-67 -7

Wt%
40 -70
1-5
0.5-1.5
0.1-1.0
0.1-1.0
0.1-1.0

00010011605 English

Page 3 of 7

Ammonia
Formaldehyde

7664-41-7
50-00 -0

0.1-1.0
<0.009

Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes
until irritation subsides. Get medical attention immediately.
First Aid - Skin Contact: Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical aid if
symptoms persist. If skin irritation persists, call a physician. Remove and wash contaminated clothing. In case of contact,
immediately flush skin with plenty of water while removing contaminated clothing and shoes.
First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If
continued breathing difficulty is experienced, get medical attention immediately.
First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately. If ingested, drink 2
glasses of water. Immediately see a physician. Never give anything by mouth to an unconscious person.
Note to Physician: None.
COMMENTS: If over-exposure occurs, call your local poison control center.

Section 5 - Fire Fighting Measures
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: No special protective measures against fire required.
Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or
equivalent) and full protective gear. Use water spray to cool exposed surfaces.

Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use
absorbent material or scrape up dried material and place in container.

Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Avoid breathing vapor and contact
with eyes, skin and clothing. Use only with adequate ventilation. Open all windows and doors or use other means to
ensure cross-ventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous
conditions. Wash thoroughly after handling.
Storage: Do not store at temperatures above 120 degrees F. Store containers away from excessive heat and freezing.
Close container after each use. Store away from caustics and oxidizers.

Section 8 - Exposure Controls / Personal Protection
Chemical Name

CASRN

ACGIH TWA

ACGIH STEL

ACGIH CEIL

Limestone

1317-65-3

10 MGM3

N.E.

N.E.

Branched and linear phthalates
Stoddard solvent
Ethylene glycol

Proprietary
8052-41-3
107-21-1

N.E.
100 PPM
N.E.

N.E.
N.E.
N.E.

N.E.
N.E.
100 MGM3

OSHA TWA
5 MGM3
(respirable
fraction)
N.E.
500 PPM
N.E.

OSHA STEL

OSHA CEIL

Skin

N.E.

N.E.

No

N.E.
N.E.
N.E.

N.E.
N.E.
N.E.

No
No
No

00010011605 English

Page 4 of 7

Silica, crystalline

14808-60-7

0.05 MGM3

N.E.

N.E.

Titanium dioxide
Ammonia
Formaldehyde

13463-67-7
7664-41-7
50-00-0

10 MGM3
25 PPM
N.E.

N.E.
35 PPM
N.E.

N.E.
N.E.
0.3 PPM

10/(%SiO2 + 2)
MGM3
15 MGM3
50 PPM
0.75 PPM

N.E.

N.E.

No

N.E.
N.E.
2 PPM

N.E.
N.E.
N.E.

No
No
No

Exposure Notes:
14808-60-7 The 2002 ACGIH Threshold Limit Values for Chemical Substances and Physical Agents lists the median
Respirable Particulate Mass (RPM) point for crystalline silica at 4.0 microns in terms of the particle's aerodynamic
diameter.
The TLVs for crystalline silica represent the respirable fraction.
OSHA PEL TWA for Quartz is calculated using the following formula: 10 mg/m3/(% SiO2 + 2). Both concentration and
percent quartz for the application of this limit are to be determined from the fraction passing a size selector with the
following characteristics.
|------------------------------------------------------------------------------------ |-----------------------------------------|
| ....... Aerodynamic diameter ( unit density sphere ) .....| Percent passing selector |
| 2 ................................................................................|.................90....................|
| 2.5 .............................................................................|..................75...................|
| 3.5 .............................................................................|..................50...................|
| 5.0 .............................................................................|..................25...................|
| 10 ..............................................................................|...................0....................|
50-00-0 Formaldehyde is a specially regulated substance for which an OSHA chemical-specific exposure standard exits.
Detailed information regarding this substance may be found in 29 CFR 1910.1048. Medical surveillance information
regarding this substance may be found in Appendix C to 29 CFR 1910.1048.
Precautionary Measures: Contact lenses pose a special hazard; soft lenses may absorb and all lenses concentrate
irritants.
Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Ensure adequate
ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient
concentrations below recommended exposure limits.
Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSH-approved air
purifying respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where
airborne concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA
1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.
National Institute for Occupational Safety and Health (NIOSH) has recommended that the permissible exposure limit be
changed to 50 micrograms respirable free silica per cubic meter of air (0.05 mg/m3) as determined by a full shift sample
up to 10-hour work shift.
Skin Protection: Rubber gloves. Natural rubber, butyl rubber and polyvinyl chloride gloves are not suitable protection
against the phthalates contained within this product; neoprene is recommended.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: Not required under normal use.
Hygienic Practices: Wash hands before breaks and at the end of workday. Remove and wash contaminated clothing
before re-use.
Important:

Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary
between states.

Note:

An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent
necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work
practices.

00010011605 English

Page 5 of 7

Section 9 - Physical And Chemical Properties
Boiling Range:
Odor:
Color:
Solubility in H2O:
Freeze Point:
Vapor Pressure:
Physical State:
Flash Point, F:

Not Established
Very Slight Ammonia
Colored
Not Established
Not Established
Not Established
Paste
Greater than 200 degrees
Fahrenheit
Lower Explosive Limit, %: Not Established

Vapor Density:
Odor Threshold:
Evaporation Rate:
Specific Gravity:
pH:
Viscosity:
Flammability:
Method:

Heavier Than Air
Not Established
Slower Than n-Butyl Acetate
1.6
Between 7.0 and 12.0
Not Established
Non-Flammable
(Seta Closed Cup)

Upper Explosive Limit, %:Not Established

When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally.
(See section 16 for abbreviation legend)

Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Incompatible with strong bases and oxidizing agents.
Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under recommended storage conditions.

Section 11 - Toxicological Information
Product LD50: Not Established
CASRN
107-21-1
7664-41-7
50-00-0

Chemical Name

Ethylene glycol
Ammonia
Formaldehyde

Product LC50: Not Established
LD50
Rat:4700 mg/kg
-------------------------

LC50
Rat:10876 mg/kg
Rat:2000 ppm/4H
Rat:203 mg/m3

Significant Data with Possible Relevance to Humans: This product contains trace amounts of free formaldehyde.
OSHA and NTP identify formaldehyde as a potential carcinogen. IARC identifies formaldehyde as a human carcinogen.
Formaldehyde has been shown to cause mutations in a variety of in-vitro test systems, the significance of which to
humans is unknown. There should be minimal risk when used with ventilation adequate to keep the atmospheric
concentration of formaldehyde below the recommended exposure limits.
Maintain adequate ventilation to prevent exposure above current OSHA / ACGIH exposure limits. Workplace monitoring of
the air to define formaldehyde exposure levels may be necessary.
In a two-year inhalation study, rats showed carcinogenic effects in the respiratory system at 15 ppm of formaldehyde.

Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.

Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local
regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is
with the owner of the waste.

00010011605 English

Page 6 of 7

EPA Waste Code if Discarded (40 CFR Section 261): None

Section 14 - Transportation Information
DOT Proper Shipping
Name:
DOT Technical Name:
DOT Hazard Class:

Not Regulated

Packing Group:

N.A.

N.A.
N.A.

Hazard Subclass:
DOT UN/NA Number:

N.A.
N.A.

Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may
apply if shipped via other modes of transportation and/or to non-domestic destinations.

Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of
the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable
definitions, to meet the following categories:
Immediate Health Hazard, Chronic Health Hazard
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
None
Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported
from the United States:
None
Canadian WHMIS:
This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings.
Canadian WHMIS Class: Not Controlled.

Section 16 - Other Information
HMIS Ratings:
Health: 1

Flammability: 1

Reactivity: 0

Volatile Organic Compounds (VOC), less water less exempts: g/L:

Personal Protection: X
56.0

Volatile Organic Compounds (VOC), less water less exempts, less LVP -VOCs:

lb/gal: 0.5

wt:wt%: 2.5

wt:wt%: 0.9

00010011605 English

Page 7 of 7

REASON FOR REVISION: Periodic Update
Legend:

N.A. – Not Applicable

ACGIH – American Conference of Governmental Industrial Hygienists

N.E. – Not Established

SARA – Superfund Amendments and Reauthorization Act of 1986

N.D. – Not Determined

NJRTK – New Jersey Right-to-Know Law

VOC – Volatile Organic Compound

OSHA – Occupational Safety and Health Administration

PEL – Permissible Exposure Limit

HMIS – Hazardous Materials Identification System

TLV – Threshold Limit Value

NTP – National Toxicology Program

CEIL – Ceiling Exposure Limit

STEL – Short Term Exposure Limit

LD50 – Lethal Dose 50

LC50 – Lethal Concentration 50

F – Degree Fahrenheit

MSDS – Material Safety Data Sheet

C – Degree Celsius

CASRN – The Chemical Abstracts Service Registry Number

DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this
document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained
person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context
of the intended use and (ii) determine if they are appropriate.


Page 1 of 6

Material
Safety
Data
Sheet

24 Hour Emergency Phone Numbers:
Medical: 1-800-327-3874
1-513-558-5111
Transportation:
1-800-535-5053
1-352-323-3500

NOTE: National Response Center emergency numbers to be used
only in the event of chemical emergencies involving a spill, leak,
fire, exposure or accident involving chemicals.

IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or
disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been
prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section
16.

Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en español a su solicitud.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.

Product Name:
Product UPC
Number:
Product Use/Class:
Manufacturer:

CAULK BE GONE
7079818025 7079818026 7079818045
7079871000
Latex Caulk
DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327 -8477 (non-emergency matters)

Revision Date: 12/21/2005
Supercedes:
12/09/1999
MSDS Number: 00077182001

Section 2 - Composition / Information On Ingredients
Chemical Name
Dimethyl glutarate
Dimethyl succinate
Dimethyl adipate
Ethylene glycol
Diethanolamine

CASRN
1119 -40-0
106-65-0
627-93-0
107-21-1
111-42-2

WT%

ACGIH TWA

10-30
5-10
3-7
0.5-1.5
0.1-1.0

N.E.
N.E.
N.E.
N.E.
2 MGM3

ACGIH
STEL
N.E.
N.E.
N.E.
N.E.
N.E.

ACGIH CEIL OSHA TWA OSHA STEL OSHA CEIL Skin
N.E.
N.E.
N.E.
100 MGM3
N.E.

N.E.
N.E.
N.E.
N.E.
N.E.

N.E.
N.E.
N.E.
N.E.
N.E.

N.E.
N.E.
N.E.
N.E.
N.E.

No
No
No
No
Yes

Exposure Notes:
Important:

Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits
may vary between states.

Note:

An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the
extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment,
engineering controls or work practices

Section 3 - Hazards Identification
Emergency Overview: A light green gel with a fruity odor. WARNING! Harmful if swallowed or absorbed through

Page 2 of 6
the skin. May cause eye, skin, nose, throat and respiratory tract irritation. This product contains ethylene glycol.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: Causes eye irritation. Signs and symptoms may include: pain, tears,
swelling, redness and blurred vision.
Effects Of Overexposure - Skin Contact: Harmful if absorbed through the skin. Prolonged or repeated contact
with skin may cause irritation.
Effects Of Overexposure - Inhalation: Vapor harmful. May affect the brain or nervous system causing
dizziness, headache or nausea. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous
membranes). May cause blurred vision.
Effects Of Overexposure - Ingestion: Harmful or fatal if swallowed. Ingestion of dibasic esters can cause
gastrointestinal irritation, nausea, vomiting, and diarrhea.
Effects Of Overexposure - Chronic Hazards: NOTICE: Reports have associated repeated and prolonged
occupational overexposure to solvents with permanent brain and nervous system damage. Symptoms include:
loss of memory, loss of intellectual ability and loss of coordination. Intentional misuse by deliberately
concentrating and inhaling the contents may be harmful or fatal. Prolonged and repeated skin contact may cause
irritation and possibly dermatitis. Repeated or prolonged exposure may cause respiratory system damage.
Overexposure may cause kidney, cardiovascular, skin and liver damage.
Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Studies have
shown that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory
animals. Ethylene glycol has been shown to cause birth defects in laboratory animals. Prolonged, repeated, or
high exposures may cause weakness and depression of the central nervous system. Dimethyladipate may
increase the incidence of abnormal embryo development, based on a single suboptimally analyzed rat study.
There are no human data.
Primary Route(s) Of Entry: Skin Contact, Inhalation, Ingestion, Eye Contact
Medical Conditions which May be Aggravated by Exposure: None known.

Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15
minutes until irritation subsides. Get medical attention immediately.
First Aid - Skin Contact: Wash off immediately with soap and plenty of water for at least 15 minutes. Get
medical aid if symptoms persist. Remove and wash contaminated clothing.
First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If
continued breathing difficulty is experienced, get medical attention immediately.
First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
Note to Physician: None.
COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arises from any of the
above routes of entry.

Section 5 - Fire Fighting Measures

Page 3 of 6

Flash Point, F: Greater than 200
Method: ( Seta Closed Cup)

Lower Explosive Limit, %: Not Established
Upper Explosive Limit, %: Not Established

Extinguishing Media: Alcohol, Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: No special protective measures against fire required.
Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved
or equivalent) and full protective gear. Use water spray to cool exposed surfaces.

Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in
Section 8. Use absorbent material or scrape up dried material and place in container.

Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Use only with adequate
ventilation. Avoid breathing vapor and contact with eyes, skin and clothing. Wash thoroughly after handling. Avoid
prolonged or repeated contact with skin. Open all windows and doors or use other means to ensure crossventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous
conditions.
Storage: Close container after each use. Store containers away from excessive heat and freezing. Do not store
at temperatures above 120 degrees F. Store away from caustics and oxidizers.

Section 8 - Exposure Controls / Personal Protection
Precautionary Measures: Please refer to other sections and subsections of this MSDS.
Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Ensure adequate
ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain
ambient concentrations below recommended exposure limits.
Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSHapproved air purifying respirator with an organic vapor cartridge or canister may be necessary under certain
circumstances where airborne concentrations are expected to exceed exposure limits. A respiratory protection
program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace
conditions warrant a respirator's use.
Skin Protection: Rubber gloves.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: Not required under normal use.
Hygienic Practices: Remove and wash contaminated clothing before re-use. Wash hands before breaks and at
the end of workday.

Section 9 - Physical And Chemical Properties

Page 4 of 6
Boiling Range:
Odor:
Appearance:
Solubility in H2O:
Freeze Point:
Vapor Pressure:
Physical State:

212 - 417 F
Fruity
Light green
Not Established
Not Established
Not Established
Gel

Vapor Density:
Odor Threshold:
Evaporation Rate:
Specific Gravity:
pH:
Viscosity:

Not Established
Not Established
Slower Than n-Butyl Acetate
1.037
Not Established
Not Established

When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined
experimentally.
(See section 16 for abbreviation legend)

Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Incompatible with strong bases and oxidizing agents.
Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under recommended storage conditions.

Section 11 - Toxicological Information
Product LD50: Not Established
CASRN
Chemical Name
106-65-0
107-21-1
111-42-2

Product LC50: Not Established
LD50
LC50

Dimethyl succinate
Ethylene glycol
Diethanolamine

Oral Rat:>5 gm/kg
Rat:4700 mg/kg
Oral Rat:620 uL/kg

------------Rat:10876 mg/kg
-------------

WT%
5-10
0.5-1.5
0.1-1.0

Carcinogenicity:
CAS No.
111-42-2

Chemical Name
Diethanolamine

ACGIH
-----

OSHA

IARC

NTP

WT%

-----

Classification not
possible from current
data.

-----

0.1-1.0

Significant Data with Possible Relevance to Humans: None

Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.

Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and
Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste
disposal is with the owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): None

Page 5 of 6

Section 14 - Transportation Information
DOT Proper Shipping
Name:
DOT Technical Name:
DOT Hazard Class:

Not Regulated

Packing Group:

N.A.

N.A.
N.A.

Hazard Subclass:
DOT UN/NA Number:

N.A.
N.A.

Note: The shipping information provided is applicable for domestic ground transport only. Different categorization
may apply if shipped via other modes of transportation and/or to non-domestic destinations.

Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and
312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
Immediate Health Hazard, Chronic Health Hazard
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
None
Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if
exported from the United States:
None

U.S. State Regulations
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product:
Chemical Name
Water

CAS Number
7732 -18-5

WT%
40-70

Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%:
Chemical Name
Water

CAS Number
7732 -18-5

WT%
40-70

Page 6 of 6
California Proposition 65:
Warning: The following ingredients present in the product are known to the State of California to cause cancer:
None.
Warning: The following ingredients present in the product are known to the State of California to cause birth
defects or other reproductive harm:
None.

Section 16 - Other Information
HMIS Ratings:
Health: 2

Flammability: 1

Reactivity: 0

VOLATILE ORGANIC COMPOUNDS, GR/LTR: 999.8

LB/GAL: 8.3

Personal Protection: X
WT%: 34.525

REASON FOR REVISION: Periodic Update
Legend:

N.A. – Not Applicable

ACGIH – American Conference of Governmental Industrial Hygienists

N.E. – Not Established

SARA – Superfund Amendments and Reauthorization Act of 1986

N.D. – Not Determined

NJRTK – New Jersey Right-to-Know Law

VOC – Volatile Organic Compound

OSHA – Occupational Safety and Health Administration

PEL – Permissible Exposure Limit

HMIS – Hazardous Materials Identification System

TLV – Threshold Limit Value

NTP – National Toxicology Program

STEL – Short Term Exposure Limit

CEIL – Ceiling Exposure Limit

LD50 – Lethal Dose 50

LC50 – Lethal Concentration 50

F – Degree Fahrenheit

C – Degree Celsius

MSDS – Material Safety Data Sheet

CASRN – The Chemical Abstracts Service Registry Number

DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as
typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF
FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS
MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE
INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary
handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the
recommendations with due consideration for the specific context of the intended use and (ii) determine if they are
appropriate.


[Du-Lite Home] | [Product Profiles] | [MSDS] | [Product Info Request]

Du-Lite® Quick Response Email
MATERIAL SAFETY DATA SHEET
KWIKSEAL
====================================================================================
SECTION I - IDENTIFICATION
====================================================================================
NFPA PROTECTION ........ X
TRANSPORTATION EMERGENCY:
NFPA HEALTH ............ 0
CHEM-TEL 1-800-255-3924
NFPA FLAMMABILITY ...... 2
INFORMATION: 860-347-2505
NFPA REACTIVITY ........ 0
DU-LITE CORPORATION
171 RIVER ROAD
MIDDLETOWN, CT 06457

PREPARED BY: WALTER J. SMITH
DATE: 4/01/04

PRODUCT NAME .........KWIKSEAL
DESCRIPTION ..........Rust Preventative Oil
DOT DESCRIP.: COMBUSTIBLE LIQUID, N.O.S., (CONTAINS MINERAL SPIRITS)
NA-1993, PG-III
DOT LABEL: (No DOT label required) DOT PLACARD: Combustible or Flammable
====================================================================================
SECTION II - HAZARDOUS INGREDIENTS
====================================================================================
HAZARDOUS COMPONENT
CAS NUMBER
TLV(MG/M3)
PEL(MG/M3)
PERCENT
LOW AROMATIC
HYDROCARBON SOLVENT
8032-32-4
100 PPM REC.
<77-87
NON-HAZARDOUS
N/A
N/A
N/A
<13-23
__________________________________________________________________________
N/E = NOT ESTABLISHED
N/A = NOT APPLICABLE
N/D = NOT DETERMINED
====================================================================================
SECTION III - PHYSICAL DATA
====================================================================================
BOILING POINT(°F).........300°F
SPECIFIC GRAVITY (H20=1)... 0.815
VAPOR PRESSURE (mm Hg)....1 @ 100°F MELTING POINT.............. N/A
VAPOR DENSITY (Air=1)....5.1
EVAPORATION RATE........... <0.1
SOLUBILITY IN H20.........Negligible
PH.................Neutral
APPEARANCE/ODOR....Clear, dark, low viscosity liquid - slight hydrocarbon odor.
====================================================================================
SECTION IV - REACTIVITY DATA
====================================================================================
CHEMICAL STABILITY: Stable
CONDITIONS TO AVOID: Open flame or excessive heat.
INCOMPATIBLE MATERIALS: Strong oxidizers.
DECOMPOSITION PRODUCTS: Fumes, smoke, carbon monoxide, carbon dioxide and
organic compounds.
HAZARDOUS POLYMERIZATION: Will not occur.
====================================================================================
SECTION V - FIRE AND EXPLOSION HAZARD DATA
====================================================================================
FLASH POINT................112°F PMCC FLAMMABLE LIMITS..LEL-0.9% VEL-7%
AUTOIGNITION TEMP..........490°F
IN CASE OF FIRE: Material is flammable petroleum liquid.
Use extinguishing carbon dioxide, foam or dry chemical media.
SPECIAL FIREFIGHTING PROCEDURES: Wear protective clothing with self-contained
breathing apparatus.
UNUSUAL FIRE HAZARDS: Petroleum liquid. Product will float and spread on water.

====================================================================================
SECTION VI - HEALTH HAZARD DATA
====================================================================================
ROUTES OF ENTRY: Eye contact, skin contact, inhalation, ingestion.
HEALTH HAZARDS (ACUTE, CHRONIC):
Skin - repeated or prolonged contact may cause dermatitis or loss of skin oils.
Eyes - Contact may cause mild irritation.
Inhalation - Mildly irritating in high concentrations.
Ingestion - Low oral toxicity.
CARCINOGENICITY: None. NTP?: No. IARC?: No. OSHA REGULATED?: No.
FIRST AID:
INHALATION:
Move victim to fresh air.
If not breathing, use artificial respiration.
If breathing is difficult, give oxygen.
Seek medical attention.
EYES:
Flush well with water.
SKIN:
Wash well with soap and water.
Remove contaminated clothing and launder.
Seek medical attention if irritation occurs.
INGESTION:
Low oral toxicity. Do notinduce vomiting.
====================================================================================
SECTION VII - PRECAUTIONS/PROCEDURES
====================================================================================
IN CASE OF SPILL: Contain and collect free liquid.
Contain spills with absorbent such as sand or clay.
WASTE DISPOSAL METHOD: Dispose of in accordance with local, state and federal EPA
regulations. Treat waste as an oil product.
PRECAUTIONS: Wear proper protective clothing when using this product.
Use with adequate ventilation.
Wash thoroughly after handling. Store away from excessive heat or open flame.
This is an oil product. Do not allow spills to enter waterways or drainage system.
If spill enters waterway and causes sheen, report to
National Response Center at 800-424-8602.
OTHER PRECAUTIONS: Emptied containers of this product may contain hazardous vapors and
residue. Clean thoroughly before reusing or discarding.
Do not use a welding torch to cut container.
Do not use for water or food storage.
====================================================================================
SECTION VIII - SPECIAL PROTECTION
====================================================================================
RESPIRATORY PROTECTION:
Use NIOSH approved respirator if vapors are excessive.
VENTILATION: Maintain below TLV. MECHANICAL EXHAUST...X
PROTECTIVE GLOVES: Rubber. LOCAL EXHAUST........X
EYE PROTECTION: Safety goggles, face shield.
OTHER PROTECTIVE EQUIPMENT... Apron, boots, full cover work clothes.
WORK/HYGIENIC PRACTICES...... Wash thoroughly after handling, launder clothes.
====================================================================================
SECTION IX - SARA TITLE III INFORMATION
====================================================================================
HAZARDOUS
CERCLA
SECT 302
SECT 313
SECT 311/312
COMPONENT
RQ LBS.
TPQ LBS.
TOXIC
HAZARDS
Low Aromatic
N/A
N/A
N/A
A,C
Hydrocarbon Solvent
A=IMMEDIATE (ACUTE HEALTH HAZARD) B=DELAYED (CHRONIC) HEALTH HAZARD
C=FIRE HAZARD
D= SUDDEN RELEASE OF PRESSURE HAZARD E=REACTIVE HAZARD

00010009605 English

Page 1 of 7

Material
Safety
Data
Sheet

24 Hour Emergency Phone Numbers:
Medical/Poison Control:
In U.S.: Call 1-800-222-1222
Outside U.S.: Call your local poison
control center
Transportation/National Response
Center:
1-800-535-5053
1-352-323-3500

NOTE: The National Response Center emergency numbers to
be used only in the event of chemical emergencies involving a
spill, leak, fire, exposure or accident involving chemicals.

IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of
this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16.

Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
On peut demader cette fiche signalétique (MSDS) a la langue francaise-canadienne.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.

Product Name:
Product UPC
Number:
Product Use/Class:
Manufacturer:

Kwik Seal Tub & Tile Adhesive Caulk - All
Colors
070798710504, 070798710207,
070798710238
Latex Caulk

Revision
Date:
Supercedes:

05/21/2008

MSDS
Number:

00010009605

04/27/2005

DAP Canada
475 Finchdene Square Unit 5
Scarborough, Ontario M1X 1B7
888-327 -8477 (non-emergency)

Section 2 - Hazards Identification
Emergency Overview: A colored paste product with a very slight ammonia odor. WARNING! May cause eye, skin, nose,
throat and respiratory tract irritation. May cause eye or skin irritation. Harmful if swallowed or absorbed through the skin.
This product contains ethylene glycol.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: May cause eye irritation.
Effects Of Overexposure - Skin Contact: May cause skin irritation. Harmful if absorbed through the skin.
Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation of high concentrations may cause headache,
nausea, and dizziness. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes).
Inhalation may cause mild irritation to the respiratory tract (nose, mouth, mucous membranes).
Effects Of Overexposure - Ingestion: Ingestion of ethylene glycol can cause gastrointestinal irritation, nausea,
vomiting, diarrhea and if ingested in sufficient quantities, death. Harmful or fatal if swallowed. Ingestion may cause
gastrointestinal irritation, nausea, vomiting and diarrhea. If ingested, may cause vomiting, diarrhea, and depressed
respiration. Ingestion may result in obstruction when material hardens.
Effects Of Overexposure - Chronic Hazards: Repeated or prolonged exposure may cause skin, respiratory, kidney and

00010009605 English

Page 2 of 7

liver damage. Prolonged and repeated skin contact may cause irritation and possibly dermatitis.
The International Agency for Research on Cancer (IARC) has determined that crystalline silica in the form of quartz or
cristobalite that is inhaled from occupational sources is carcinogenic to humans (Group 1- carcinogenic to humans). Refer
to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (published in June 1997) in conjunction with the use of
these materials. The National Toxicology Program (NTP) classifies respirable crystalline silica as "known to be a human
carcinogen". Refer to the 9th Report on Carcinogens (2000). The American Conference of Governmental Industrial
Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (Group A2).
Breathing dust containing respirable crystalline silica may not cause noticeable injury or illness even though permanent
lung damage may be occurring. Inhalation of dust may have the following serious chronic health effects: Excessive
inhalation of respirable dust can cause pneumoconiosis, a respiratory disease, which can result in delayed, progressive,
disabling and sometimes fatal lung injury. Symptoms include cough, shortness of breath, wheezing, non-specific chest
illness and reduced pulmonary function. Smoking exacerbates this disease. Individuals with pneumoconiosis are
predisposed to develop tuberculosis. There is some evidence that breathing respirable crystalline silica or the disease
silicosis is associated with an increased incidence of significant disease endpoints such as scleroderma (an immune
system disorder manifested by fibrosis of the lungs, skin and other internal organs) and kidney disease. Prolonged,
repeated, or high exposures may cause weakness and depression of the central nervous system.
Formaldehyde vapor is a known animal carcinogen according to OSHA and NTP and is considered possibly carcinogenic
to humans by inhalation. The International Agency for Research on Cancer considers formaldehyde to be a human
carcinogen.
A mixture of diisodecyl phthalate and diisononyl phthalate has been tested in a two-generation toxicity study in laboratory
animals. No effects on reproductive parameters were seen. However, a small but statistically significant increase in early
offspring mortality was seen at high oral doses. The significance of this to humans is uncertain.
The mixture of phthalate esters contained within this product has been shown to cause developmental effects at high
doses in laboratory animals when administered orally by gavage in a developmental study and developmental and fertility
effects when administered at high doses by feed in a two-generation reproduction study. The potential risk from
occupational and consumer exposure is considered to be very low, based on limited relevance of the rodent findings to
humans and the large safety margins between exposure and the effect levels.
Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Studies have shown
that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals. Ethylene
glycol has been shown to cause birth defects in laboratory animals.
Primary Route(s) Of Entry: Skin Contact, Inhalation, Eye Contact
Medical Conditions which May be Aggravated by Exposure: None known.
Carcinogenicity:
CAS No.

Chemical Name

13463-67-7

Titanium dioxide

14808-60-7

Silica, crystalline

50-00-0

Formaldehyde

ACGIH

OSHA

IARC

NTP

Not Listed.
Suspected human
carcinogen.
Suspected human
carcinogen.

Not Listed.

Possible carcinogen.

Not Listed.

Not Listed.

Human carcinogen.

Known carcinogen.

Potential cancer hazard.

Human carcinogen.

Anticipated carcinogen.

Section 3 - Composition / Information On Ingredients
Chemical Name
Limestone
Branched and linear phthalates
Titanium dioxide
n-Butyl acetate
Silica, crystalline
Ethylene glycol
Formaldehyde

CASRN
1317-65-3
Proprietary
13463-67 -7
123-86-4
14808-60 -7
107-21-1
50-00 -0

Wt%
30 -60
1-5
0.1-1.0
0.1-1.0
0.1-1.0
0.1-1.0
<0.02

00010009605 English

Page 3 of 7

Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes
until irritation subsides. Get medical attention immediately.
First Aid - Skin Contact: Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical aid if
symptoms persist. If skin irritation persists, call a physician. Remove and wash contaminated clothing. In case of contact,
immediately flush skin with plenty of water while removing contaminated clothing and shoes.
First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If
continued breathing difficulty is experienced, get medical attention immediately.
First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately. If ingested, drink 2
glasses of water. Immediately see a physician. Never give anything by mouth to an unconscious person.
Note to Physician: None.
COMMENTS: If over-exposure occurs, call your local poison control center.

Section 5 - Fire Fighting Measures
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: No special protective measures against fire required.
Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or
equivalent) and full protective gear. Use water spray to cool exposed surfaces.

Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use
absorbent material or scrape up dried material and place in container.

Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Avoid breathing vapor and contact
with eyes, skin and clothing. Use only with adequate ventilation. Open all windows and doors or use other means to
ensure cross-ventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous
conditions. Wash thoroughly after handling.
Storage: Do not store at temperatures above 120 degrees F. Store containers away from excessive heat and freezing.
Close container after each use. Store away from caustics and oxidizers.

Section 8 - Exposure Controls / Personal Protection
Chemical Name

CASRN

ACGIH TWA

ACGIH STEL

ACGIH CEIL

Limestone

1317-65-3

10 MGM3

N.E.

N.E.

Branched and linear phthalates
Titanium dioxide
n-Butyl acetate

Proprietary
13463-67-7
123-86-4

N.E.
10 MGM3
150 PPM

N.E.
N.E.
200 PPM

N.E.
N.E.
N.E.

Silica, crystalline

14808-60-7

0.025 MGM.

N.E.

N.E.

Ethylene glycol
Formaldehyde

107-21-1
50-00-0

N.E.
N.E.

N.E.
N.E.

100 MGM3
0.3 PPM

OSHA TWA
5 MGM3
(respirable
fraction)
N.E.
15 MGM3
150 PPM
10/(%SiO2 + 2)
MGM3
N.E.
0.75 PPM

OSHA STEL

OSHA CEIL

Skin

N.E.

N.E.

No

N.E.
N.E.
N.E.

N.E.
N.E.
N.E.

No
No
No

N.E.

N.E.

No

N.E.
2 PPM

N.E.
N.E.

No
No

00010009605 English

Page 4 of 7

Exposure Notes:
14808-60-7 The 2002 ACGIH Threshold Limit Values for Chemical Substances and Physical Agents lists the median
Respirable Particulate Mass (RPM) point for crystalline silica at 4.0 microns in terms of the particle's aerodynamic
diameter.
The TLVs for crystalline silica represent the respirable fraction.
OSHA PEL TWA for Quartz is calculated using the following formula: 10 mg/m3/(% SiO2 + 2). Both concentration and
percent quartz for the application of this limit are to be determined from the fraction passing a size selector with the
following characteristics.
|------------------------------------------------------------------------------------ |-----------------------------------------|
| ....... Aerodynamic diameter ( unit density sphere ) .....| Percent passing selector |
| 2 ................................................................................|.................90....................|
| 2.5 .............................................................................|..................75...................|
| 3.5 .............................................................................|..................50...................|
| 5.0 .............................................................................|..................25...................|
| 10 ..............................................................................|...................0....................|
50-00-0 Formaldehyde is a specially regulated substance for which an OSHA chemical-specific exposure standard exits.
Detailed information regarding this substance may be found in 29 CFR 1910.1048. Medical surveillance information
regarding this substance may be found in Appendix C to 29 CFR 1910.1048.
Precautionary Measures: Contact lenses pose a special hazard; soft lenses may absorb and all lenses concentrate
irritants.
Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Ensure adequate
ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient
concentrations below recommended exposure limits.
Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSH-approved air
purifying respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where
airborne concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA
1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.
National Institute for Occupational Safety and Health (NIOSH) has recommended that the permissible exposure limit be
changed to 50 micrograms respirable free silica per cubic meter of air (0.05 mg/m3) as determined by a full shift sample
up to 10-hour work shift.
Skin Protection: Rubber gloves. Natural rubber, butyl rubber and polyvinyl chloride gloves are not suitable protection
against the phthalates contained within this product; neoprene is recommended.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: Not required under normal use.
Hygienic Practices: Wash hands before breaks and at the end of workday. Remove and wash contaminated clothing
before re-use.
Important:

Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary
between states.

Note:

An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent
necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work
practices.

Section 9 - Physical And Chemical Properties
Boiling Range:
Odor:

210 - 220 F
Very Slight Ammonia

Vapor Density:
Odor Threshold:

Heavier Than Air
Not Established

00010009605 English
Color:
Solubility in H2O:
Freeze Point:
Vapor Pressure:
Physical State:
Flash Point, F:
Lower Explosive Limit, %:

Page 5 of 7
Colored
Not Established
Not Established
Not Established
Paste
> 200 F
Not Established

Evaporation Rate:
Slower Than n-Butyl Acetate
Specific Gravity:
1.6
pH:
Between 7.0 and 12.0
Viscosity:
Not Established
Flammability:
Non-Flammable
Method:
(Seta Closed Cup)
Upper Explosive Limit, %:Not Established

When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally.
(See section 16 for abbreviation legend)

Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Incompatible with strong bases and oxidizing agents.
Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under recommended storage conditions.

Section 11 - Toxicological Information
Product LD50: Not Established
CASRN
123-86-4
107-21-1
50-00-0

Chemical Name

n-Butyl acetate
Ethylene glycol
Formaldehyde

Product LC50: Not Established
LD50
Rat:10768 MG/KG
Rat:4700 mg/kg
-------------

LC50
Rat:2000 P
Rat:10876 mg/kg
Rat:203 mg/m3

Significant Data with Possible Relevance to Humans: This product contains trace amounts of free formaldehyde.
OSHA and NTP identify formaldehyde as a potential carcinogen. IARC identifies formaldehyde as a human carcinogen.
Formaldehyde has been shown to cause mutations in a variety of in-vitro test systems, the significance of which to
humans is unknown. There should be minimal risk when used with ventilation adequate to keep the atmospheric
concentration of formaldehyde below the recommended exposure limits.
Maintain adequate ventilation to prevent exposure above current OSHA / ACGIH exposure limits. Workplace monitoring of
the air to define formaldehyde exposure levels may be necessary.
In a two-year inhalation study, rats showed carcinogenic effects in the respiratory system at 15 ppm of formaldehyde.

Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.

Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local
regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is
with the owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): This product does not meet the definition of a hazardous waste
according to U.S. EPA Hazardous Waste Management Regulation, 40 CFR Section 261.

Section 14 - Transportation Information

00010009605 English
DOT Proper Shipping
Name:
DOT Technical Name:
DOT Hazard Class:

Page 6 of 7
Not Regulated

Packing Group:

N.A.

N.A.
N.A.

Hazard Subclass:
DOT UN/NA Number:

N.A.
None

Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may
apply if shipped via other modes of transportation and/or to non-domestic destinations.

Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of
the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable
definitions, to meet the following categories:
Immediate Health Hazard, Chronic Health Hazard
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
None
Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported
from the United States:
Chemical Name

CAS Number

Mercury & compounds

7439-97-6

Canadian WHMIS:
This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings.
Canadian WHMIS Class: Not Controlled.

Section 16 - Other Information
HMIS Ratings:
Health: 1

Flammability: 1

Reactivity: 0

Volatile Organic Compounds (VOC), less water less exempts: g/L:

Personal Protection: X
25.4

Volatile Organic Compounds (VOC), less water less exempts, less LVP -VOCs:

lb/gal: 0.2

wt:wt%: 1.1

wt:wt%: 0.6

REASON FOR REVISION: Periodic Update
Legend:

N.A. – Not Applicable

ACGIH – American Conference of Governmental Industrial Hygienists

00010009605 English

Page 7 of 7

N.E. – Not Established

SARA – Superfund Amendments and Reauthorization Act of 1986

N.D. – Not Determined

NJRTK – New Jersey Right-to-Know Law

VOC – Volatile Organic Compound

OSHA – Occupational Safety and Health Administration

PEL – Permissible Exposure Limit

HMIS – Hazardous Materials Identification System

TLV – Threshold Limit Value

NTP – National Toxicology Program

CEIL – Ceiling Exposure Limit

STEL – Short Term Exposure Limit

LD50 – Lethal Dose 50

LC50 – Lethal Concentration 50

F – Degree Fahrenheit

MSDS – Material Safety Data Sheet

C – Degree Celsius

CASRN – The Chemical Abstracts Service Registry Number

DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this
document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained
person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context
of the intended use and (ii) determine if they are appropriate.


00010009605 English

Page 1 of 7

Material
Safety
Data
Sheet

24 Hour Emergency Phone Numbers:
Medical/Poison Control:
In U.S.: Call 1-800-222-1222
Outside U.S.: Call your local poison
control center
Transportation/National Response
Center:
1-800-535-5053
1-352-323-3500

NOTE: The National Response Center emergency numbers to
be used only in the event of chemical emergencies involving a
spill, leak, fire, exposure or accident involving chemicals.

IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of
this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16.

Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
On peut demader cette fiche signalétique (MSDS) a la langue francaise-canadienne.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.

Product Name:
Product UPC
Number:
Product Use/Class:
Manufacturer:

Kwik Seal Tub & Tile Adhesive Caulk - All
Colors
070798710504, 070798710207,
070798710238
Latex Caulk

Revision
Date:
Supercedes:

05/21/2008

MSDS
Number:

00010009605

04/27/2005

DAP Canada
475 Finchdene Square Unit 5
Scarborough, Ontario M1X 1B7
888-327 -8477 (non-emergency)

Section 2 - Hazards Identification
Emergency Overview: A colored paste product with a very slight ammonia odor. WARNING! May cause eye, skin, nose,
throat and respiratory tract irritation. May cause eye or skin irritation. Harmful if swallowed or absorbed through the skin.
This product contains ethylene glycol.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: May cause eye irritation.
Effects Of Overexposure - Skin Contact: May cause skin irritation. Harmful if absorbed through the skin.
Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation of high concentrations may cause headache,
nausea, and dizziness. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes).
Inhalation may cause mild irritation to the respiratory tract (nose, mouth, mucous membranes).
Effects Of Overexposure - Ingestion: Ingestion of ethylene glycol can cause gastrointestinal irritation, nausea,
vomiting, diarrhea and if ingested in sufficient quantities, death. Harmful or fatal if swallowed. Ingestion may cause
gastrointestinal irritation, nausea, vomiting and diarrhea. If ingested, may cause vomiting, diarrhea, and depressed
respiration. Ingestion may result in obstruction when material hardens.
Effects Of Overexposure - Chronic Hazards: Repeated or prolonged exposure may cause skin, respiratory, kidney and

00010009605 English

Page 2 of 7

liver damage. Prolonged and repeated skin contact may cause irritation and possibly dermatitis.
The International Agency for Research on Cancer (IARC) has determined that crystalline silica in the form of quartz or
cristobalite that is inhaled from occupational sources is carcinogenic to humans (Group 1- carcinogenic to humans). Refer
to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (published in June 1997) in conjunction with the use of
these materials. The National Toxicology Program (NTP) classifies respirable crystalline silica as "known to be a human
carcinogen". Refer to the 9th Report on Carcinogens (2000). The American Conference of Governmental Industrial
Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (Group A2).
Breathing dust containing respirable crystalline silica may not cause noticeable injury or illness even though permanent
lung damage may be occurring. Inhalation of dust may have the following serious chronic health effects: Excessive
inhalation of respirable dust can cause pneumoconiosis, a respiratory disease, which can result in delayed, progressive,
disabling and sometimes fatal lung injury. Symptoms include cough, shortness of breath, wheezing, non-specific chest
illness and reduced pulmonary function. Smoking exacerbates this disease. Individuals with pneumoconiosis are
predisposed to develop tuberculosis. There is some evidence that breathing respirable crystalline silica or the disease
silicosis is associated with an increased incidence of significant disease endpoints such as scleroderma (an immune
system disorder manifested by fibrosis of the lungs, skin and other internal organs) and kidney disease. Prolonged,
repeated, or high exposures may cause weakness and depression of the central nervous system.
Formaldehyde vapor is a known animal carcinogen according to OSHA and NTP and is considered possibly carcinogenic
to humans by inhalation. The International Agency for Research on Cancer considers formaldehyde to be a human
carcinogen.
A mixture of diisodecyl phthalate and diisononyl phthalate has been tested in a two-generation toxicity study in laboratory
animals. No effects on reproductive parameters were seen. However, a small but statistically significant increase in early
offspring mortality was seen at high oral doses. The significance of this to humans is uncertain.
The mixture of phthalate esters contained within this product has been shown to cause developmental effects at high
doses in laboratory animals when administered orally by gavage in a developmental study and developmental and fertility
effects when administered at high doses by feed in a two-generation reproduction study. The potential risk from
occupational and consumer exposure is considered to be very low, based on limited relevance of the rodent findings to
humans and the large safety margins between exposure and the effect levels.
Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Studies have shown
that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals. Ethylene
glycol has been shown to cause birth defects in laboratory animals.
Primary Route(s) Of Entry: Skin Contact, Inhalation, Eye Contact
Medical Conditions which May be Aggravated by Exposure: None known.
Carcinogenicity:
CAS No.

Chemical Name

13463-67-7

Titanium dioxide

14808-60-7

Silica, crystalline

50-00-0

Formaldehyde

ACGIH

OSHA

IARC

NTP

Not Listed.
Suspected human
carcinogen.
Suspected human
carcinogen.

Not Listed.

Possible carcinogen.

Not Listed.

Not Listed.

Human carcinogen.

Known carcinogen.

Potential cancer hazard.

Human carcinogen.

Anticipated carcinogen.

Section 3 - Composition / Information On Ingredients
Chemical Name
Limestone
Branched and linear phthalates
Titanium dioxide
n-Butyl acetate
Silica, crystalline
Ethylene glycol
Formaldehyde

CASRN
1317-65-3
Proprietary
13463-67 -7
123-86-4
14808-60 -7
107-21-1
50-00 -0

Wt%
30 -60
1-5
0.1-1.0
0.1-1.0
0.1-1.0
0.1-1.0
<0.02

00010009605 English

Page 3 of 7

Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes
until irritation subsides. Get medical attention immediately.
First Aid - Skin Contact: Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical aid if
symptoms persist. If skin irritation persists, call a physician. Remove and wash contaminated clothing. In case of contact,
immediately flush skin with plenty of water while removing contaminated clothing and shoes.
First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If
continued breathing difficulty is experienced, get medical attention immediately.
First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately. If ingested, drink 2
glasses of water. Immediately see a physician. Never give anything by mouth to an unconscious person.
Note to Physician: None.
COMMENTS: If over-exposure occurs, call your local poison control center.

Section 5 - Fire Fighting Measures
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: No special protective measures against fire required.
Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or
equivalent) and full protective gear. Use water spray to cool exposed surfaces.

Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use
absorbent material or scrape up dried material and place in container.

Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Avoid breathing vapor and contact
with eyes, skin and clothing. Use only with adequate ventilation. Open all windows and doors or use other means to
ensure cross-ventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous
conditions. Wash thoroughly after handling.
Storage: Do not store at temperatures above 120 degrees F. Store containers away from excessive heat and freezing.
Close container after each use. Store away from caustics and oxidizers.

Section 8 - Exposure Controls / Personal Protection
Chemical Name

CASRN

ACGIH TWA

ACGIH STEL

ACGIH CEIL

Limestone

1317-65-3

10 MGM3

N.E.

N.E.

Branched and linear phthalates
Titanium dioxide
n-Butyl acetate

Proprietary
13463-67-7
123-86-4

N.E.
10 MGM3
150 PPM

N.E.
N.E.
200 PPM

N.E.
N.E.
N.E.

Silica, crystalline

14808-60-7

0.025 MGM.

N.E.

N.E.

Ethylene glycol
Formaldehyde

107-21-1
50-00-0

N.E.
N.E.

N.E.
N.E.

100 MGM3
0.3 PPM

OSHA TWA
5 MGM3
(respirable
fraction)
N.E.
15 MGM3
150 PPM
10/(%SiO2 + 2)
MGM3
N.E.
0.75 PPM

OSHA STEL

OSHA CEIL

Skin

N.E.

N.E.

No

N.E.
N.E.
N.E.

N.E.
N.E.
N.E.

No
No
No

N.E.

N.E.

No

N.E.
2 PPM

N.E.
N.E.

No
No

00010009605 English

Page 4 of 7

Exposure Notes:
14808-60-7 The 2002 ACGIH Threshold Limit Values for Chemical Substances and Physical Agents lists the median
Respirable Particulate Mass (RPM) point for crystalline silica at 4.0 microns in terms of the particle's aerodynamic
diameter.
The TLVs for crystalline silica represent the respirable fraction.
OSHA PEL TWA for Quartz is calculated using the following formula: 10 mg/m3/(% SiO2 + 2). Both concentration and
percent quartz for the application of this limit are to be determined from the fraction passing a size selector with the
following characteristics.
|------------------------------------------------------------------------------------ |-----------------------------------------|
| ....... Aerodynamic diameter ( unit density sphere ) .....| Percent passing selector |
| 2 ................................................................................|.................90....................|
| 2.5 .............................................................................|..................75...................|
| 3.5 .............................................................................|..................50...................|
| 5.0 .............................................................................|..................25...................|
| 10 ..............................................................................|...................0....................|
50-00-0 Formaldehyde is a specially regulated substance for which an OSHA chemical-specific exposure standard exits.
Detailed information regarding this substance may be found in 29 CFR 1910.1048. Medical surveillance information
regarding this substance may be found in Appendix C to 29 CFR 1910.1048.
Precautionary Measures: Contact lenses pose a special hazard; soft lenses may absorb and all lenses concentrate
irritants.
Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Ensure adequate
ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient
concentrations below recommended exposure limits.
Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSH-approved air
purifying respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where
airborne concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA
1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.
National Institute for Occupational Safety and Health (NIOSH) has recommended that the permissible exposure limit be
changed to 50 micrograms respirable free silica per cubic meter of air (0.05 mg/m3) as determined by a full shift sample
up to 10-hour work shift.
Skin Protection: Rubber gloves. Natural rubber, butyl rubber and polyvinyl chloride gloves are not suitable protection
against the phthalates contained within this product; neoprene is recommended.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: Not required under normal use.
Hygienic Practices: Wash hands before breaks and at the end of workday. Remove and wash contaminated clothing
before re-use.
Important:

Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary
between states.

Note:

An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent
necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work
practices.

Section 9 - Physical And Chemical Properties
Boiling Range:
Odor:

210 - 220 F
Very Slight Ammonia

Vapor Density:
Odor Threshold:

Heavier Than Air
Not Established

00010009605 English
Color:
Solubility in H2O:
Freeze Point:
Vapor Pressure:
Physical State:
Flash Point, F:
Lower Explosive Limit, %:

Page 5 of 7
Colored
Not Established
Not Established
Not Established
Paste
> 200 F
Not Established

Evaporation Rate:
Slower Than n-Butyl Acetate
Specific Gravity:
1.6
pH:
Between 7.0 and 12.0
Viscosity:
Not Established
Flammability:
Non-Flammable
Method:
(Seta Closed Cup)
Upper Explosive Limit, %:Not Established

When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally.
(See section 16 for abbreviation legend)

Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Incompatible with strong bases and oxidizing agents.
Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under recommended storage conditions.

Section 11 - Toxicological Information
Product LD50: Not Established
CASRN
123-86-4
107-21-1
50-00-0

Chemical Name

n-Butyl acetate
Ethylene glycol
Formaldehyde

Product LC50: Not Established
LD50
Rat:10768 MG/KG
Rat:4700 mg/kg
-------------

LC50
Rat:2000 P
Rat:10876 mg/kg
Rat:203 mg/m3

Significant Data with Possible Relevance to Humans: This product contains trace amounts of free formaldehyde.
OSHA and NTP identify formaldehyde as a potential carcinogen. IARC identifies formaldehyde as a human carcinogen.
Formaldehyde has been shown to cause mutations in a variety of in-vitro test systems, the significance of which to
humans is unknown. There should be minimal risk when used with ventilation adequate to keep the atmospheric
concentration of formaldehyde below the recommended exposure limits.
Maintain adequate ventilation to prevent exposure above current OSHA / ACGIH exposure limits. Workplace monitoring of
the air to define formaldehyde exposure levels may be necessary.
In a two-year inhalation study, rats showed carcinogenic effects in the respiratory system at 15 ppm of formaldehyde.

Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.

Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local
regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is
with the owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): This product does not meet the definition of a hazardous waste
according to U.S. EPA Hazardous Waste Management Regulation, 40 CFR Section 261.

Section 14 - Transportation Information

00010009605 English
DOT Proper Shipping
Name:
DOT Technical Name:
DOT Hazard Class:

Page 6 of 7
Not Regulated

Packing Group:

N.A.

N.A.
N.A.

Hazard Subclass:
DOT UN/NA Number:

N.A.
None

Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may
apply if shipped via other modes of transportation and/or to non-domestic destinations.

Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of
the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable
definitions, to meet the following categories:
Immediate Health Hazard, Chronic Health Hazard
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
None
Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported
from the United States:
Chemical Name

CAS Number

Mercury & compounds

7439-97-6

Canadian WHMIS:
This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings.
Canadian WHMIS Class: Not Controlled.

Section 16 - Other Information
HMIS Ratings:
Health: 1

Flammability: 1

Reactivity: 0

Volatile Organic Compounds (VOC), less water less exempts: g/L:

Personal Protection: X
25.4

Volatile Organic Compounds (VOC), less water less exempts, less LVP -VOCs:

lb/gal: 0.2

wt:wt%: 1.1

wt:wt%: 0.6

REASON FOR REVISION: Periodic Update
Legend:

N.A. – Not Applicable

ACGIH – American Conference of Governmental Industrial Hygienists

00010009605 English

Page 7 of 7

N.E. – Not Established

SARA – Superfund Amendments and Reauthorization Act of 1986

N.D. – Not Determined

NJRTK – New Jersey Right-to-Know Law

VOC – Volatile Organic Compound

OSHA – Occupational Safety and Health Administration

PEL – Permissible Exposure Limit

HMIS – Hazardous Materials Identification System

TLV – Threshold Limit Value

NTP – National Toxicology Program

CEIL – Ceiling Exposure Limit

STEL – Short Term Exposure Limit

LD50 – Lethal Dose 50

LC50 – Lethal Concentration 50

F – Degree Fahrenheit

MSDS – Material Safety Data Sheet

C – Degree Celsius

CASRN – The Chemical Abstracts Service Registry Number

DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this
document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained
person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context
of the intended use and (ii) determine if they are appropriate.


00010002605 English

Page 1 of 7

Material
Safety
Data
Sheet

24 Hour Emergency Phone Numbers:
Medical/Poison Control:
In U.S.: Call 1-800-222-1222
Outside U.S.: Call your local poison
control center
Transportation/National Response
Center:
1-800-535-5053
1-352-323-3500

NOTE: The National Response Center emergency numbers to
be used only in the event of chemical emergencies involving a
spill, leak, fire, exposure or accident involving chemicals.

IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of
this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16.

Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
On peut demader cette fiche signalétique (MSDS) a la langue francaise-canadienne.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.

Product Name:
Product UPC
Number:

Product Use/Class:
Manufacturer:

Alex Plus Acrylic Latex Caulk Plus Silicone - Revision
All Colors
Date:
070798742253, 070798742338,
Supercedes:
070798742437, 070798742376,
070798742390, 070798742451,
07098742475
Latex Caulk
MSDS
Number:
DAP Canada
475 Finchdene Square Unit 5
Scarborough, Ontario M1X 1B7
888-327 -8477 (non-emergency)

05/21/2008
04/21/2005

00010002605

Section 2 - Hazards Identification
Emergency Overview: A colored paste product with a very slight ammonia odor. WARNING! May cause eye, skin, nose,
throat and respiratory tract irritation. May cause eye or skin irritation. Harmful if swallowed or absorbed through the skin.
This product contains ethylene glycol.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: May cause eye irritation.
Effects Of Overexposure - Skin Contact: May cause skin irritation. Harmful if absorbed through the skin.
Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation of high concentrations may cause headache,
nausea, and dizziness. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes).
Inhalation may cause mild irritation to the respiratory tract (nose, mouth, mucous membranes).
Effects Of Overexposure - Ingestion: Ingestion of ethylene glycol can cause gastrointestinal irritation, nausea,
vomiting, diarrhea and if ingested in sufficient quantities, death. Harmful or fatal if swallowed. Ingestion may cause
gastrointestinal irritation, nausea, vomiting and diarrhea. If ingested, may cause vomiting, diarrhea, and depressed
respiration. Ingestion may result in obstruction when material hardens.

00010002605 English

Page 2 of 7

Effects Of Overexposure - Chronic Hazards: Repeated or prolonged exposure may cause skin, respiratory, kidney and
liver damage. Prolonged and repeated skin contact may cause irritation and possibly dermatitis.
The International Agency for Research on Cancer (IARC) has determined that crystalline silica in the form of quartz or
cristobalite that is inhaled from occupational sources is carcinogenic to humans (Group 1- carcinogenic to humans). Refer
to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (published in June 1997) in conjunction with the use of
these materials. The National Toxicology Program (NTP) classifies respirable crystalline silica as "known to be a human
carcinogen". Refer to the 9th Report on Carcinogens (2000). The American Conference of Governmental Industrial
Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (Group A2).
Breathing dust containing respirable crystalline silica may not cause noticeable injury or illness even though permanent
lung damage may be occurring. Inhalation of dust may have the following serious chronic health effects: Excessive
inhalation of respirable dust can cause pneumoconiosis, a respiratory disease, which can result in delayed, progressive,
disabling and sometimes fatal lung injury. Symptoms include cough, shortness of breath, wheezing, non-specific chest
illness and reduced pulmonary function. Smoking exacerbates this disease. Individuals with pneumoconiosis are
predisposed to develop tuberculosis. There is some evidence that breathing respirable crystalline silica or the disease
silicosis is associated with an increased incidence of significant disease endpoints such as scleroderma (an immune
system disorder manifested by fibrosis of the lungs, skin and other internal organs) and kidney disease. Prolonged,
repeated, or high exposures may cause weakness and depression of the central nervous system.
A mixture of diisodecyl phthalate and diisononyl phthalate has been tested in a two-generation toxicity study in laboratory
animals. No effects on reproductive parameters were seen. However, a small but statistically significant increase in early
offspring mortality was seen at high oral doses. The significance of this to humans is uncertain.
The mixture of phthalate esters contained within this product has been shown to cause developmental effects at high
doses in laboratory animals when administered orally by gavage in a developmental study and developmental and fertility
effects when administered at high doses by feed in a two-generation reproduction study. The potential risk from
occupational and consumer exposure is considered to be very low, based on limited relevance of the rodent findings to
humans and the large safety margins between exposure and the effect levels.
Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Studies have shown
that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals. Ethylene
glycol has been shown to cause birth defects in laboratory animals.
Primary Route(s) Of Entry: Skin Contact, Inhalation, Eye Contact
Medical Conditions which May be Aggravated by Exposure: None known.
Carcinogenicity:
CAS No.

Chemical Name

13463-67-7

Titanium dioxide

14808-60-7

Silica, crystalline

50-00-0

Formaldehyde

ACGIH

OSHA

IARC

NTP

Not Listed.
Suspected human
carcinogen.
Suspected human
carcinogen.

Not Listed.

Possible carcinogen.

Not Listed.

Not Listed.

Human carcinogen.

Known carcinogen.

Potential cancer hazard.

Human carcinogen.

Anticipated carcinogen.

Section 3 - Composition / Information On Ingredients
Chemical Name
Limestone
Branched and linear phthalates
Titanium dioxide
Silica, crystalline
Ethylene glycol
Ammonia
Formaldehyde

Section 4 - First Aid Measures

CASRN
1317-65-3
Proprietary
13463-67 -7
14808-60 -7
107-21-1
7664-41-7
50-00 -0

Wt%
40 -70
1-5
0.1-1.0
0.1-1.0
0.1-1.0
<0.08
<0.0010

00010002605 English

Page 3 of 7

First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes
until irritation subsides. Get medical attention immediately.
First Aid - Skin Contact: Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical aid if
symptoms persist. If skin irritation persists, call a physician. Remove and wash contaminated clothing. In case of contact,
immediately flush skin with plenty of water while removing contaminated clothing and shoes.
First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If
continued breathing difficulty is experienced, get medical attention immediately. First Aid: If you experience difficulty in
breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical attention immediately.
First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately. If ingested, drink 2
glasses of water. Immediately see a physician. Never give anything by mouth to an unconscious person.
Note to Physician: None.
COMMENTS: If over-exposure occurs, call your local poison control center.

Section 5 - Fire Fighting Measures
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: No special protective measures against fire required.
Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or
equivalent) and full protective gear. Use water spray to cool exposed surfaces.

Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use
absorbent material or scrape up dried material and place in container.

Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Avoid breathing vapor and contact
with eyes, skin and clothing. Use only with adequate ventilation. Open all windows and doors or use other means to
ensure cross-ventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous
conditions. Wash thoroughly after handling.
Storage: Do not store at temperatures above 120 degrees F. Store containers away from excessive heat and freezing.
Close container after each use. Store away from caustics and oxidizers.

Section 8 - Exposure Controls / Personal Protection
Chemical Name

CASRN

ACGIH TWA

ACGIH STEL

ACGIH CEIL

Limestone

1317-65-3

10 MGM3

N.E.

N.E.

Branched and linear phthalates
Titanium dioxide

Proprietary
13463-67-7

N.E.
10 MGM3

N.E.
N.E.

N.E.
N.E.

Silica, crystalline

14808-60-7

0.025 MGM.

N.E.

N.E.

Ethylene glycol
Ammonia
Formaldehyde

107-21-1
7664-41-7
50-00-0

N.E.
25 PPM
N.E.

N.E.
35 PPM
N.E.

100 MGM3
N.E.
0.3 PPM

OSHA TWA
5 MGM3
(respirable
fraction)
N.E.
15 MGM3
10/(%SiO2 + 2)
MGM3
N.E.
50 PPM
0.75 PPM

OSHA STEL

OSHA CEIL

Skin

N.E.

N.E.

No

N.E.
N.E.

N.E.
N.E.

No
No

N.E.

N.E.

No

N.E.
N.E.
2 PPM

N.E.
N.E.
N.E.

No
No
No

Exposure Notes:
14808-60-7 The 2002 ACGIH Threshold Limit Values for Chemical Substances and Physical Agents lists the median

00010002605 English

Page 4 of 7

Respirable Particulate Mass (RPM) point for crystalline silica at 4.0 microns in terms of the particle's aerodynamic
diameter.
The TLVs for crystalline silica represent the respirable fraction.
OSHA PEL TWA for Quartz is calculated using the following formula: 10 mg/m3/(% SiO2 + 2). Both concentration and
percent quartz for the application of this limit are to be determined from the fraction passing a size selector with the
following characteristics.
|------------------------------------------------------------------------------------ |-----------------------------------------|
| ....... Aerodynamic diameter ( unit density sphere ) .....| Percent passing selector |
| 2 ................................................................................|.................90....................|
| 2.5 .............................................................................|..................75...................|
| 3.5 .............................................................................|..................50...................|
| 5.0 .............................................................................|..................25...................|
| 10 ..............................................................................|...................0....................|
Precautionary Measures: Contact lenses pose a special hazard; soft lenses may absorb and all lenses concentrate
irritants.
Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Ensure adequate
ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient
concentrations below recommended exposure limits.
Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSH-approved air
purifying respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where
airborne concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA
1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.
National Institute for Occupational Safety and Health (NIOSH) has recommended that the permissible exposure limit be
changed to 50 micrograms respirable free silica per cubic meter of air (0.05 mg/m3) as determined by a full shift sample
up to 10-hour work shift.
Skin Protection: Rubber gloves. Natural rubber, butyl rubber and polyvinyl chloride gloves are not suitable protection
against the phthalates contained within this product; neoprene is recommended.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: Not required under normal use.
Hygienic Practices: Wash hands before breaks and at the end of workday. Remove and wash contaminated clothing
before re-use.
Important:

Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary
between states.

Note:

An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent
necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work
practices.

Section 9 - Physical And Chemical Properties
Boiling Range:
Odor:
Color:
Solubility in H2O:
Freeze Point:
Vapor Pressure:
Physical State:
Flash Point, F:

210 - 220 F
Very Slight Ammonia
Colored
Not Established
Not Established
Not Established
Paste
Greater than 200 degrees
Fahrenheit
Lower Explosive Limit, %: Not Established

Vapor Density:
Odor Threshold:
Evaporation Rate:
Specific Gravity:
pH:
Viscosity:
Flammability:
Method:

Heavier Than Air
Not Established
Slower Than n-Butyl Acetate
1.5
Between 7.0 and 12.0
Not Established
Non-Flammable
(Seta Closed Cup)

Upper Explosive Limit, %:Not Established

00010002605 English

Page 5 of 7

When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally.
(See section 16 for abbreviation legend)

Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Incompatible with strong bases and oxidizing agents.
Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under recommended storage conditions.

Section 11 - Toxicological Information
Product LD50: Not Established
CASRN
107-21-1
7664-41-7
50-00-0

Chemical Name

Product LC50: Not Established
LD50

Ethylene glycol
Ammonia
Formaldehyde

Rat:4700 mg/kg
-------------------------

LC50
Rat:10876 mg/kg
Rat:2000 ppm/4H
Rat:203 mg/m3

Significant Data with Possible Relevance to Humans: None.

Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.

Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local
regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is
with the owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): None

Section 14 - Transportation Information
DOT Proper Shipping
Name:
DOT Technical Name:
DOT Hazard Class:

Not Regulated

Packing Group:

N.A.

N.A.
N.A.

Hazard Subclass:
DOT UN/NA Number:

N.A.
N.A.

Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may
apply if shipped via other modes of transportation and/or to non-domestic destinations.

Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of

00010002605 English

Page 6 of 7

the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable
definitions, to meet the following categories:
Immediate Health Hazard, Chronic Health Hazard
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
None
Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported
from the United States:
Chemical Name

CAS Number

Mercury & compounds

7439-97-6

Canadian WHMIS:
This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings.
Canadian WHMIS Class: Not Controlled.

Section 16 - Other Information
HMIS Ratings:
Health: 1

Flammability: 1

Reactivity: 0

Volatile Organic Compounds (VOC), less water less exempts: g/L:

Personal Protection: B
30.5

lb/gal: 0.3

Volatile Organic Compounds (VOC), less water less exempts, less LVP -VOCs:

wt:wt%: 1.5

wt:wt%: 0.6

REASON FOR REVISION: Periodic Update
Legend:

N.A. – Not Applicable

ACGIH – American Conference of Governmental Industrial Hygienists

N.E. – Not Established

SARA – Superfund Amendments and Reauthorization Act of 1986

N.D. – Not Determined

NJRTK – New Jersey Right-to-Know Law

VOC – Volatile Organic Compound

OSHA – Occupational Safety and Health Administration

PEL – Permissible Exposure Limit

HMIS – Hazardous Materials Identification System

TLV – Threshold Limit Value

NTP – National Toxicology Program

CEIL – Ceiling Exposure Limit

STEL – Short Term Exposure Limit

LD50 – Lethal Dose 50

LC50 – Lethal Concentration 50

F – Degree Fahrenheit

MSDS – Material Safety Data Sheet

00010002605 English
C – Degree Celsius

Page 7 of 7
CASRN – The Chemical Abstracts Service Registry Number

DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this
document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained
person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context
of the intended use and (ii) determine if they are appropriate.


MATERIAL SAFETY DATA SHEET
MSDS Name: QUAD ADVANCED FORMULA SEALANT
MSDS Number: 24011-001-4
Version Number
2
MSDS Date:
SEP-09-2002
Page Number:
1
-----------------------------------------------------------------------------

SECTION I - PRODUCT AND COMPANY INFORMATION

Product Name:
HMIS Hazard Rating:

QUAD ADVANCED FORMULA SEALANT
Health: 1 Fire: 3 Reactivity: 0

Company Identification:

OSI SEALANTS, INC.a Subsidiary
of Sovereign Specialty Chems.
7405 PRODUCTION DRIVE
MENTOR OH 44060

Information phone/Fax:
Emergency Phone (24 hour)
Chemtrec (outside-USA)

(440) 255-8900 (440) 974-8358
CHEMTREC
(800) 424-9300
(703) 527-3887

Product Class
Trade Name
Product Code

SEALANT
PRO-SERIES
24011-001,-xxx

PPE: B

SECTION II - INGREDIENT AND HAZARD INFORMATION
Hazardous Ingredient Name
CAS Number

Percent

STODDARD SOLVENT

8052-41-3

10 - 15

Y

XYLENE

1330-20-7

10 - 15

Y

Titanium Dioxide **

13463-67-7

5 - 10

ETHYL BENZENE

100-41-4

< 5.0

TSCA

Y

Ingredient Notes:
Remaining ingredients are not considered OSHA hazardous.
*TITANIUM DIOXIDE IN WHITE ONLY!
**The main hazard for Titanium Dioxide is in inhalation. Because
of its incorporation into the polymer matrix, exposure by
inhalation is unlikely.
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION III - PHYSICAL AND CHEMICAL PROPERTIES
Form:
High viscosity caulk (various colors)
--------------------------------------------------------------------------------

MATERIAL SAFETY DATA SHEET
MSDS Name: QUAD ADVANCED FORMULA SEALANT
MSDS Number: 24011-001-4
Version Number
2
MSDS Date:
SEP-09-2002
Page Number:
2
----------------------------------------------------------------------------Solubility (in water):
pH Value, +/-.3:
Boiling Range:
Vapor Pressure (mmHg):
Evaporation Rate:

insol.
Not Applicable
280.øF - 380.øF (137.78øC - 193.33øC)
23.@ 68.øF (20.øC)
0.9 times Slower than n-Butyl Acetate

Vapor Density:

Heavier than air

% Volatile, Weight
% Volatile, Volume
Specific Gravity:
VOC (less H2O or exempt)

approx. 25.%
40.%
1.18
340 gr/l.(25%)

NOTE:
*BOIL RANGE, EVAP RATE, VAPOR DENSITY AND PRESSURE

FOR SOLVENT ONLY!

- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION IV - FIRE FIGHTING MEASURES (Flash,UEL,LEL for solvent only)
Flammability Class
IC
Flash Range:
80.øF (26.67øC)
Tag Closed Cup
Explosive Range (LEL/UEL):
1.%
7.%
EXTINGUISHING MEDIA:
Carbon Dioxide---Dry Chemical---Foam
Use water fog to cool material in vicinity of fire.
SPECIAL FIRE-FIGHTING PROCEDURES:
Use self-contained breathing apparatus with full facepiece
operated in pressure demand with full protective equipment.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Any closed container may rupture when exposed to extreme heat.
Solvent vapors are heavier than air and travel along the ground.
Vapors given off are flammable and may be ignited in air explosively.
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION V - HEALTH HAZARD DATA
ROUTES OF ENTRY:
ENTRY THROUGH... Inhalation and skin most likely
CARCINOGENICITY...
NTP? N/E
|
IARC Monographs? N/E
|
OHSA? NO
This product contains Ethylbenzene. The International Agency for
--------------------------------------------------------------------------------

MATERIAL SAFETY DATA SHEET
MSDS Name: QUAD ADVANCED FORMULA SEALANT
MSDS Number: 24011-001-4
Version Number
2
MSDS Date:
SEP-09-2002
Page Number:
3
----------------------------------------------------------------------------Research on Cancer has evaluated ethylbenzene and classified it as
a possible human carcinogen (Group 2B) based on sufficient evidence
for carcinogenicity in experimental animals, but inadequate evidence
for cancer in exposed humans.
EFFECTS OF OVEREXPOSURE
Eyes: Can cause irritation, redness, tearing and blurred vision.
Skin: Prolonged or repeated contact can cause moderate
irritation, drying of the skin, and dermatitis.
Inhalation: Excessive inhalation of vapors can cause respiratory
irritation, headache, drowsiness and fatigue. High
concentrations of vapors are anesthetic and may cause
central nervous system effects such as dizziness.
Ingestion: Can cause gastrointestinal irritation, nausea,
vomiting and diarrhea.
FIRST AID MEASURES
Eyes: Flush eyes gently with water for at least 15 minutes
lifting eyelids occasionally; get prompt medical attention
Skin: Wash thoroughly with soap and water; apply a mild skin cream.
Remove contaminated clothing.
Inhalation: Move affected person to fresh air; if breathing is
difficult, administer oxygen; if breathing has stopped,
give artificial respiration. Get medical attention.
Ingestion: DO NOT INDUCE VOMITING! Get immediate medical attention.
CHRONIC HAZARDS
NOTICE: Reports have associated repeated and prolonged
occupational overexposure to solvents with permanent brain,
nervous system, liver or kidney damage or may cause cardiac
arrhythmia.
INTENTIONAL misuse of this product by
deliberately inhaling its vapors may be harmful or fatal.
Overexposure to Xylene may cause injury to Liver, Kidney and blood.
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION VI - STABILITY AND REACTIVITY
Stability:
This product is stable
Hazardous Polymerization:
Hazardous polymerization will not occur
INCOMPATABILITY:
Keep away from strong oxidizing agents.
CONDITIONS TO AVOID:
Keep away from heat, spark, open flames and any ignition source.
HAZARDOUS DECOMPOSITION PRODUCTS:
Will produce fumes and smoke containing carbon monoxide and
dioxide under fire conditions.

--------------------------------------------------------------------------------

MATERIAL SAFETY DATA SHEET
MSDS Name: QUAD ADVANCED FORMULA SEALANT
MSDS Number: 24011-001-4
Version Number
2
MSDS Date:
SEP-09-2002
Page Number:
4
----------------------------------------------------------------------------- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION VII - ACCIDENTAL RELEASE AND DISPOSAL MEASURES:
STEPS TO BE TAKEN IN CASE OF SPILL:
Eliminate all ignition sources. Ventilate confined areas.
(Open windows and doors). Wear appropriate protective clothing.
Cover with absorbent. Scoop into sealable safety container.
WASTE DISPOSAL METHOD:
Dispose of following local, state, and federal regulations.
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
ACGIH TLV
ACGIH TLV-C
STODDARD SOLVENT
100.00 PPM

N/est

ACGIH STEL

N/est

OSHA STEL

N/est

OSHA PEL

100.00 PPM

XYLENE
100.00 PPM

N/est

150.00 PPM

Titanium Dioxide **
10.00 mg/F3

N/est

N/est

ETHYL BENZENE
100.00 PPM

N/est

N/est

150.00 PPM

N/est

150.00 PPM

100.00 PPM

15.00 N/est

100.00 PPM

RESPIRATORY PROTECTION:
If TLV of the product is exceeded, a NIOSH/MSHA jointly approved
air supply respirator is advised in the absence of proper
ventilation. OSHA regulations also permit the use of other
types of NIOSH/MSHA respirators under specified conditions.
(See your safety equipment supplier for more information)
VENTILATION:
Provide sufficient mechanical (general and/or local exhaust)
ventilation to maintain exposure below TLV.
Ventilate during application and curing of this product.
PROTECTIVE CLOTHING:
Rubber gloves should be worn where skin contact is likely.
Wear impervious clothing and shoes.
EYE PROTECTION:
Chemical goggles or safety glasses should be worn.
HANDLING AND STORAGE PRECAUTIONS:
--------------------------------------------------------------------------------

MATERIAL SAFETY DATA SHEET
MSDS Name: QUAD ADVANCED FORMULA SEALANT
MSDS Number: 24011-001-4
Version Number
2
MSDS Date:
SEP-09-2002
Page Number:
5
----------------------------------------------------------------------------Keep away from heat, spark and flame.
Keep out of reach of children.
Keep container closed while not in use.
Do not cut or burn recepticals that have contained a
solvent based product. Do not reuse this container.
Use only in a well ventilated area.
-------------------------------------------------------------------N/A=NOT APPLICABLE
N/AV=NOT AVAILABLE
N/E, N/est=NOT ESTABLISHED
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION IX - TRANSPORT INFORMATION:
DOT

CLASSIFICATIONS FOR ONE GALLON AND UNDER CONTAINERS

DESCRIPTION:
CLASS/ UN NO.:
DOT LABEL:
IMDG class:
IMDG BOL:

ORM-D, Consumer commodity
none
ORM-D (Caulking)
3.3
Flammable Liquid nos.,3,UN1993,PG III,LTD QTY

DOT CLASSIFICATIONS for OVER 1 GALLON size CONTAINERS
DESCRIPTION:
CLASS:
DOT LABEL:
IMDG CLASS:
IMDG BOL:

Flammable
Class 3,
Flammable
3.3
Flammable

Liquid n.o.s.
Pack group III
Liquid, UN 1993
liquid n.o.s.,3,UN1993,PG III

- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION X - REGULATORY INFORMATION:
SARA TITLE III SECTION 313:
This product contains the following toxic chemicals subject to the
reporting requirements of Section 313 of the Emergency Planning and
Community Right to Know Act of 1986 and of 40 CFR 372:
Ingredient Name

CAS Number

Percent

XYLENE

1330-20-7

10 - 15

ETHYL BENZENE

100-41-4

< 5.0

--------------------------------------------------------------------------------

MATERIAL SAFETY DATA SHEET
MSDS Name: QUAD ADVANCED FORMULA SEALANT
MSDS Number: 24011-001-4
Version Number
2
MSDS Date:
SEP-09-2002
Page Number:
6
----------------------------------------------------------------------------This material fits the EPA Hazard Category definition
of Immediate (Acute) and Delayed (Chronic) Health Hazards
under SARA Sections 311, 312.
Chemical substances are TSCA listed.
California PROP.65 Chemicals:

none known

DISCLAIMER:
The information contained herein is based on data available as of
the date of preparation of this MSDS and which we believe to be
reliable. However, no warranty is expressed or implied regarding
the accuracy of the data. We shall not be responsible for the use
of this information, or of any product, method, or apparatus mentioned, and the user must make his own investigation to determine
the suitability of the information or products for his particular
purpose, for the protection of the environment, and the health and
safety of the users of this material.

--------------------------------------------------------------------------------

Last Page

MSDS 3504
3504: Dap White Silicone
MSDS Last updated: 10/02/2006
XIAMETER®
MATERIAL SAFETY DATA SHEET
Version: 1.4
Revision Date: 2005/06/01
DAP® 100% SILICONE RUBBER SEALANT WHITE, 8646
1. PRODUCT AND COMPANY IDENTIFICATION
-------------------------------------------------------------------------------Dow Corning Corporation
24 Hour Emergency Telephone: (989) 496-5900
South Saginaw Road
Customer Service: (989) 496-6000
Midland, Michigan 48686
Product Disposal Information: (989) 496-6315
CHEMTREC: (800) 424-9300
MSDS No.: 04061404

Revision date: 2005/06/01

Generic Description: Silicone elastomer
Physical Form: Paste
Color: See product name
Odor: Acetic acid odor
NFPA Profile: Health 2

Flammability 1

Instability/Reactivity

0

Note: NFPA = National Fire Protection Association
2. OSHA HAZARDOUS COMPONENTS
-------------------------------------------------------------------------------CAS Number
Wt %
Component Name
17689-77-9
4253-34-3

1.0 - 5.0
1.0 - 5.0

Ethyltriacetoxysilane
Methyltriacetoxysilane

The above components are hazardous as defined in 29 CFR 1910.1200.
3. HAZARDS IDENTIFICATION
-------------------------------------------------------------------------------POTENTIAL HEALTH EFFECTS
Acute Effects
Eye:
Direct contact may cause moderate irritation.
Skin:
May cause moderate irritation.
Inhalation: Material is not likely to present an inhalation hazard at
ambient conditions. However, if material is heated or high
vapor/aerosol concentrations are attained, central nervous system
depression may occur, which is characterized by drowsiness,
dizziness, confusion or loss of coordination.
Oral:
Low ingestion hazard in normal use.
Prolonged/Repeated Exposure Effects
Skin:
Inhalation:
Oral:

No known applicable information.
No known applicable information.
Repeated ingestion or swallowing large amounts may injure
internally.

Signs and Symptoms of Overexposure
No known applicable information.
Medical Conditions Aggravated by Exposure
No known applicable information.
The above listed potential effects of overexposure are based on actual data,
results of studies performed upon similar composition, component data and/or
expert review of the product. Please refer to Section 11 for the detailed
toxicology information.
4. FIRST AID MEASURES

-------------------------------------------------------------------------------Eye:
Immediately flush with water for 15 minutes. Get medical attention.
Skin:

Remove from skin and wash thoroughly with soap and water or waterless
cleanser. Get medical attention if irritation or other ill effects
develop or persist.

Inhalation; Material is not likely to present an inhalation hazard at ambient
conditions.
If material is heated or vapor/mist/dust/fumes are generated, care
should be taken to prevent inhalation.
In case of exposure to vapor/mist/dust/fumes, move to fresh air.
Oral:

Get medical attention.

Comments: Treat according to person's condition and specifics of exposure.
5. FIRE FIGHTING MEASURES
-------------------------------------------------------------------------------Flash Point:
> 212 F / > 100 C (Closed Cup)
Auto ignition Temperature:

Not determined.

Flammability Limits in Air:

Not determined.

Extinguishing Media: On large fires use dry chemical, foam or water spray.
On small fires use carbon dioxide (CO2), dry chemical
or water spray. Water can be used to cool fire exposed
containers.
Fire Fighting Measures:

Self-contained breathing apparatus and protective

clothing should be worn in fighting large fires involving
chemicals. Determine the need to evacuate or isolate the area
according to your local emergency plan. Use water spray to
keep fire exposed containers cool.
Unusual Fire Hazards: None.
Hazardous Decomposition Products
Thermal breakdown of this product during fire or very high heat conditions may
evolve the following hazardous decomposition products: Carbon oxides and traces
of incompletely burned carbon compounds. Silicon dioxide. Formaldehyde. Metal
oxides.
Nitrogen oxides. Sulfur oxides. Chlorine compounds.
6. ACCIDENTAL RELEASE MEASURES
-------------------------------------------------------------------------------Containment/Clean up: Observe all personal protection equipment recommendations
Described in Sections 5 and 8. Wipe up or scrape up and contain
for salvage or disposal. Clean area as appropriate since spilled
materials, even in small quantities, may present a slip hazard.
Final cleaning may require use of steam, solvents or
detergents. Dispose of saturated absorbent or cleaning materials
appropriately, since spontaneous heating may occur.
Local, state and federal laws and regulations may apply to
releases and disposal of this material, as well as those materials
and items employed in the cleanup of releases.
You will need to determine which federal, state and local laws
and regulations are applicable.
Sections 13 and 15 of this MSDS provide information regarding
certain federal and state requirements.
Note: See section 8 for Personal Protective Equipment for Spills.
Call (989) 496-5900, if additional information is required.
7. HANDLING AND STORAGE
-------------------------------------------------------------------------------Use with adequate ventilation. Product evolves acetic acid (HOAc) when exposed
to water or humid air. Provide ventilation during use to control HOAc within
exposure guidelines or use respiratory protection. Avoid eye contact. Avoid skin
contact.
Do not take internally. Avoid breathing vapor. Keep container closed.
Use reasonable care and store away from oxidizing materials. Keep container
closed and store away from water or moisture.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
-------------------------------------------------------------------------------Component Exposure Limits
CAS Number

Component Name

Exposure Limits

17689-77-9

Ethyltriacetoxysilane

See acetic acid comments

4253-34-3

Methyltriacetoxysilane

See acetic acid comments

Acetic acid is formed upon contact with water or humid air.
Provide adequate ventilation to control exposures within guidelines of
OSHA PEL: TWA 10 ppm and ACGIH TLV: TWA 10 ppm, STEL 15 ppm.
Engineering Controls
Local Ventilation:
General Ventilation:

Recommended.
Recommended.

Personal Protective Equipment for Routine Handling
Eyes:

Use proper protection - safety glasses as a minimum.

Skin:

Wash at mealtime and end of shift. Contaminated clothing and shoes
should be removed as soon as practical and thoroughly cleaned before
reuse. Chemical protective gloves are recommended.

Suitable Gloves:

Butyl Rubber. Nitrile Rubber.

Inhalation: Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates that
exposures are within recommended exposure guidelines. IH personnel can
assist in judging the adequacy of existing engineering controls.
Suitable Respirator: Respiratory protection is not needed under ambient
conditions. if vapor/mist/dust/fumes are generated when material is
heated or handled, the following is advised. General and local exhaust
ventilation is recommended to maintain vapor exposures below
recommended limits. Where concentrations are above recommended
limits or are unknown, appropriate respiratory protection should be
worn. Follow OSHA respirator regulations (29 CFR 1910.134)
and use NIOSH/MSHA approved respirators.
Personal Protective Equipment for Spills
Eyes:

Use full face respirator.

Skin:

Wash at mealtime and end of shift. Contaminated clothing and shoes
should be removed as soon as practical and thoroughly cleaned before
reuse. Chemical protective gloves are recommended.

Inhalation/Suitable
Respiratory protection recommended. Follow OSHA Respirator
Regulations (29 CFR 1910.134) and use NIOSH/MSHA approved
respirators. Protection provided by air purifying respirators against
exposure to any hazardous chemical is limited. Use a positive pressure
air supplied respirator if there is any potential for uncontrolled
release, exposure levels are unknown, or any other circumstance where
air purifying respirators may not provide adequate protection.
Precautionary Measures: Avoid eye contact. Avoid skin contact. Do not take
internally. Avoid breathing vapor. Keep container closed. Use reasonable
care.
Comments: Product evolves acetic acid (HOAc) when exposed to water or humid air.
Provide ventilation during use to control HOAc within exposure
guidelines or use respiratory protection.
When heated to temperatures above 150 C (300 F) in the presence of air,
product may form formaldehyde vapors. Physical and health hazard
information is readily available from Dow Corning corporation and the
Material Safety Data Sheet.
Note: These precautions are for room temperature handling. Use at elevated
temperature or aerosol/spray applications may require added precautions.
9.

PHYSICAL AND CHEMICAL PROPERTIES

--------------------------------------------------------------------------------

Physical Form;
Color:
Odor:
Specific Gravity @ 25C:
Viscosity:
Freezing/Melting Point:
Boiling Point:
Vapor Pressure @ 25 C:
Vapor Density:
Solubility In Water:
pH:
Volatile Content:

Paste
See product name
Acetic acid odor
1.007
Not Determined.
Not Determined.
Not Determined.
Not Determined.
Not Determined.
Not Determined.
Not Determined.
Not Determined.

Note: The above information is not intended for use in preparing product
specifications.
10. STABILITY AND REACTIVITY
-------------------------------------------------------------------------------Chemical Stability:
Stable
Hazardous
Polymerization:

Hazardous polymerization will not occur.

Conditions to Avoid:

None

Materials to Avoid:
Oxidizing material can cause a reaction. Water, moisture,
Or humid air can cause hazardous vapors to form as
described in Section 8.
11. TOXICOLOGICAL INFORMATION
-------------------------------------------------------------------------------Component Toxicology Information
Inhalation of fumes may result in metal fume fever, a flu-like illness with
symptoms of metallic taste, fever and chills, aches, chest tightness, and cough.
Special Hazard Information on Components
No known applicable information.
12. ECOLOGICAL INFORMATION
-------------------------------------------------------------------------------Environmental Fate and Distribution
Complete information is not yet available.
Environmental Effects
Complete information is not yet available.
Fate and Effects in Waste Water Treatment Plants
Complete information is not yet available.
Ecotoxicity Classification Criteria
Hazard Parameters (LC50 or EC50)
High
Medium
Low
Acute Aquatic Toxicity (mg/L)
<=1
>1 and <=100
>100
Acute Terrestrial Toxicity
<=100
>100 and <=2000
>2000
This table is adapted from "Environmental Toxicology and Risk Assessment"
ASTM STP 1179, p.34, 1993
This table can be used to classify the ecotoxicity of this product when
ecotoxicity data is listed above. Please read the other information presented in
the section concerning the overall ecological safety of this material.
13. DISPOSAL CONSIDERATIONS
-------------------------------------------------------------------------------RCRA Hazard Class (40 CFR 261)
When a decision is made to discard this material, as received, is it classified
as a hazardous waste? No
State or local laws may impose additional regulatory requirements regarding
disposal.

Call (989) 496-6315, if additional information is required.
14. TRANSPORT INFORMATION
-------------------------------------------------------------------------------DOT Road Shipment Information (49 CFR 172.101)
Not subject to DOT.
Ocean Shipment (IMDG)
Not subject to IMDG code.
Air Shipment (IATA)
Not subject to IATA regulations.
15. REGULATORY INFORMATION
-------------------------------------------------------------------------------Contents of this MSDS comply with the OSHA Hazard Communication Standard
29 CFR 1910.1200.
TSCA Status:
All chemical substances in this material are included on or
exempted from listing on the TSCA Inventory of Chemical Substances.
EPA SARA Title III Chemical Listings
Section 302 Extremely Hazardous Substances (40 CFR 355):
None
Section 304 CERCLA Hazardous Substances (40CFR 302):
None
Section 311/312 Hazard Class (40 CFR 370):
Acute:
Yes
Chronic:
No
Fire:
No
Pressure:
No
Reactive:
No
Section 313 Toxic Chemicals (40 CFR 372):
None present or none present in regulated quantities.
Supplemental State Compliance Information
California
Warning: This product contains the following chemical(s) listed by the State of
California under the Safe Drinking Water and Toxic Enforcement Act of 1986
(Proposition 65) as
being known to cause cancer, birth defects or other reproductive harm.
None known.
Massachusetts
CAS Number

Wt %

Component Name

7631-86-9

7.0 - 13.0

Silica, amorphous

1333-86-4

<=2.0

Carbon black

13463-67-7

<=1.8

Titanium dioxide

1309-37-1

<=1.0

Iron oxide

New Jersey
CAS Number

Wt %

Component Name

70131-67-8

>60.0

Dimethyl siloxane, hydroxyl-terminated

7631-86-9

7.0 - 13.0

Silica, amorphous

64742-46-7
distillates

<=6.9

Hydro treated middle petroleum

1333-86-4

<=2.0

Carbon black

1332-37-2

<=2.0

Iron oxide

147-14-8

<=2.0

Tetrabenzo-5,10,15,20Diazaporphyrinephthalocyanine (Pigment

blue 15)
63148-62-9

1.0 - 5.0

Polydimethylsiloxane

17689-77-9

1.0 - 5.0

Ethyltriacetoxysilane

13463-67-7

<=1.8

Titanium dioxide

4253-34-3

1.0 - 5.0

Methyltriacetoxysilane

1309-37-1

<=1.0

Iron oxide

Pennsylvania
CAS Number

Wt %

Component Name

70131-67-8

> 60.0

Dimethyl siloxane, hydroxyl-terminated

7631-86-9

7.0 - 13.0

Silica, amorphous

64742-46-7
distillates

<=6.9

Hydro treated middle petroleum

1333-86-4

<=2.0

Carbon black

13463-67-7

<=1.8

1309-37-1

<=1.0

Titanium dioxide
Iron oxide

16. OTHER INFORMATION
-------------------------------------------------------------------------------Prepared by: Dow Corning Corporation
These data are offered in good faith as typical values and not as product
specifications. No warranty, either expressed or implied, is hereby made. The
recommended industrial hygiene and safe handling procedures are believed to be
generally applicable. However, each user should review these recommendations in
the specific context of the intended use and determine whether they are
appropriate.
XIAMETER® is a trademark of Dow Corning Corporation
http://www.xiameter.com

The information contained in this MSDS was obtained from current and reliable sources, however, the
data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy.
Since the conditions or handling, storage and disposal of this product are beyond the control of
Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the
products improper use. No warranty, expressed or inferred, regarding the product described in this
MSDS shall be created or inferred by any statement in this MSDS. Various government agencies may
have specific regulations regarding the transportation, handling, storage, use, or disposal of this
product which may not be covered by this MSDS. The user is responsible for full compliance.

XIAMETER(R)
Material Safety Data Sheet
Page: 1 of 8
Version: 1.5
Revision Date: 2005/06/01

DAP(R) 73473 SILICONE SEALANT CLEAR CDN
1. PRODUCT AND COMPANY IDENTIFICATION
24 Hour Emergency Telephone:
Customer Service:
Product Disposal Information:
CHEMTREC:

Dow Corning Corporation
South Saginaw Road
Midland, Michigan 48686

MSDS No.: 04061396

(989) 496-5900
(989) 496-6000
(989) 496-6315
(800) 424-9300

Revision Date: 2005/06/01

Generic Description:
Physical Form:
Color:
Odor:

Silicone elastomer
Paste
Colorless
Acetic acid odor

NFPA Profile: Health

2 Flammability

1 Instability/Reactivity

0

Note: NFPA = National Fire Protection Association

2. OSHA HAZARDOUS COMPONENTS
CAS Number

Wt %

Component Name

17689-77-9

1.0 - 5.0

Ethyltriacetoxysilane

4253-34-3

1.0 - 5.0

Methyltriacetoxysilane

The above components are hazardous as defined in 29 CFR 1910.1200.

3. HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
Acute Effects
Eye:

Direct contact may cause moderate irritation.

Skin:

May cause moderate irritation.

Inhalation:

Material is not likely to present an inhalation hazard at ambient conditions. However, if
material is heated or high vapor/aerosol concentrations are attained, central nervous system
depression may occur, which is characterized by drowsiness, dizziness, confusion or loss of
coordination.

Oral:

Low ingestion hazard in normal use.

Prolonged/Repeated Exposure Effects
Skin:

No known applicable information.

XIAMETER(R)
Material Safety Data Sheet
Page: 2 of 8
Version: 1.5
Revision Date: 2005/06/01

DAP(R) 73473 SILICONE SEALANT CLEAR CDN
Inhalation:

No known applicable information.

Oral:

No known applicable information.

Signs and Symptoms of Overexposure
No known applicable information.
Medical Conditions Aggravated by Exposure
No known applicable information.
The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar compositions,
component data and/or expert review of the product. Please refer to Section 11 for the detailed toxicology information.

4. FIRST AID MEASURES
Eye:

Immediately flush with water for 15 minutes. Get medical attention.

Skin:

Remove from skin and wash thoroughly with soap and water or waterless cleanser. Get
medical attention if irritation or other ill effects develop or persist.

Inhalation:

Material is not likely to present an inhalation hazard at ambient conditions. If material is
heated or vapor/mist/dust/fumes are generated, care should be taken to prevent inhalation.
In case of exposure to vapor/mist/dust/fumes, move to fresh air.

Oral:

No first aid should be needed.

Comments:

Treat according to person's condition and specifics of exposure.

5. FIRE FIGHTING MEASURES
Flash Point:

> 212 °F / > 100 °C (Closed Cup)

Autoignition Temperature:

Not determined.

Flammability Limits in Air:

Not determined.

Extinguishing Media:

On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide
(CO2), dry chemical or water spray. Water can be used to cool fire exposed containers.

Fire Fighting Measures:

Self-contained breathing apparatus and protective clothing should be worn in fighting large
fires involving chemicals. Determine the need to evacuate or isolate the area according to
your local emergency plan. Use water spray to keep fire exposed containers cool.

Unusual Fire Hazards:

None.

Hazardous Decomposition Products
Thermal breakdown of this product during fire or very high heat conditions may evolve the following hazardous

XIAMETER(R)
Material Safety Data Sheet
Page: 3 of 8
Version: 1.5
Revision Date: 2005/06/01

DAP(R) 73473 SILICONE SEALANT CLEAR CDN
decomposition products: Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide.
Formaldehyde.

6. ACCIDENTAL RELEASE MEASURES
Containment/Clean up:

Observe all personal protection equipment recommendations described in Sections 5 and 8.
Wipe up or scrape up and contain for salvage or disposal. Clean area as appropriate since
spilled materials, even in small quantities, may present a slip hazard. Final cleaning may
require use of steam, solvents or detergents. Dispose of saturated absorbant or cleaning
materials appropriately, since spontaneous heating may occur. Local, state and federal laws
and regulations may apply to releases and disposal of this material, as well as those materials
and items employed in the cleanup of releases. You will need to determine which federal,
state and local laws and regulations are applicable. Sections 13 and 15 of this MSDS provide
information regarding certain federal and state requirements.

Note: See section 8 for Personal Protective Equipment for Spills. Call (989) 496-5900, if additional information is
required.

7. HANDLING AND STORAGE
Use with adequate ventilation. Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide
ventilation during use to control HOAc within exposure guidelines or use respiratory protection. Avoid eye contact. Avoid
skin contact. Do not take internally. Avoid breathing vapor. Keep container closed.
Use reasonable care and store away from oxidizing materials. Keep container closed and store away from water or
moisture.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Component Exposure Limits
CAS Number

Component Name

Exposure Limits

17689-77-9

Ethyltriacetoxysilane

See acetic acid comments.

4253-34-3

Methyltriacetoxysilane

See acetic acid comments.

Acetic acid is formed upon contact with water or humid air. Provide adequate ventilation to control exposures within
guidelines of OSHA PEL: TWA 10 ppm and ACGIH TLV: TWA 10 ppm, STEL 15 ppm.
Engineering Controls
Local Ventilation:
General Ventilation:

Recommended.
Recommended.

Personal Protective Equipment for Routine Handling

XIAMETER(R)
Material Safety Data Sheet
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Revision Date: 2005/06/01

DAP(R) 73473 SILICONE SEALANT CLEAR CDN
Eyes:

Use proper protection - safety glasses as a minimum.

Skin:

Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as
soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are
recommended.

Suitable Gloves:

Nitrile Rubber. Butyl Rubber.

Inhalation:

Use respiratory protection unless adequate local exhaust ventilation is provided or exposure
assessment demonstrates that exposures are within recommended exposure guidelines. IH
personnel can assist in judging the adequacy of existing engineering controls.

Suitable Respirator:

Respiratory protection is not needed under ambient conditions. If vapor/mist/dust/fumes are
generated when material is heated or handled, the following is advised. General and local
exhaust ventilation is recommended to maintain vapor exposures below recommended limits.
Where concentrations are above recommended limits or are unknown, appropriate
respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR
1910.134) and use NIOSH/MSHA approved respirators.

Personal Protective Equipment for Spills
Eyes:

Use full face respirator.

Skin:

Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as
soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are
recommended.

Inhalation/Suitable
Respirator:

Respiratory protection recommended. Follow OSHA Respirator Regulations (29 CFR
1910.134) and use NIOSH/MHSA approved respirators. Protection provided by air purifying
respirators against exposure to any hazardous chemical is limited. Use a positive pressure air
supplied respirator if there is any potential for uncontrolled release, exposure levels are
unknown, or any other circumstance where air purifying respirators may not provide adequate
protection.

Precautionary Measures:

Avoid eye contact. Avoid skin contact. Do not take internally. Avoid breathing vapor. Keep
container closed. Use reasonable care.

Comments:

Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide ventilation
during use to control HOAc within exposure guidelines or use respiratory protection.
When heated to temperatures above 150 C (300 F) in the presence of air, product may form
formaldehyde vapors. Physical and health hazard information is readily available from Dow
Corning Corporation and the Material Safety Data Sheet.

Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require
added precautions.

9. PHYSICAL AND CHEMICAL PROPERTIES
Physical Form: Paste

XIAMETER(R)
Material Safety Data Sheet
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DAP(R) 73473 SILICONE SEALANT CLEAR CDN
Color:
Odor:
Specific Gravity @ 25°C:
Viscosity:
Freezing/Melting Point:
Boiling Point:
Vapor Pressure @ 25°C:
Vapor Density:
Solubility in Water:
pH:
Volatile Content:

Colorless
Acetic acid odor
1.007
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.

Note: The above information is not intended for use in preparing product specifications.

10. STABILITY AND REACTIVITY
Chemical Stability:

Stable.

Hazardous
Polymerization:
Conditions to Avoid:

Hazardous polymerization will not occur.

Materials to Avoid:

Oxidizing material can cause a reaction. Water, moisture, or humid air can cause hazardous
vapors to form as described in Section 8.

None.

11. TOXICOLOGICAL INFORMATION
Special Hazard Information on Components
No known applicable information.

12. ECOLOGICAL INFORMATION
Environmental Fate and Distribution
Complete information is not yet available.
Environmental Effects
Complete information is not yet available.
Fate and Effects in Waste Water Treatment Plants
Complete information is not yet available.

Hazard Parameters (LC50 or EC50)
Acute Aquatic Toxicity (mg/L)
Acute Terrestrial Toxicity

Ecotoxicity Classification Criteria
High
Medium
<=1
>1 and <=100
<=100
>100 and <= 2000

Low
>100
>2000

XIAMETER(R)
Material Safety Data Sheet
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Version: 1.5
Revision Date: 2005/06/01

DAP(R) 73473 SILICONE SEALANT CLEAR CDN
This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34, 1993.
This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information presented in the
section concerning the overall ecological safety of this material.

13. DISPOSAL CONSIDERATIONS
RCRA Hazard Class (40 CFR 261)
When a decision is made to discard this material, as received, is it classified as a hazardous waste? No
State or local laws may impose additional regulatory requirements regarding disposal.
Call (989) 496-6315, if additional information is required.
14. TRANSPORT INFORMATION
DOT Road Shipment Information (49 CFR 172.101)
Not subject to DOT.
Ocean Shipment (IMDG)
Not subject to IMDG code.
Air Shipment (IATA)
Not subject to IATA regulations.

15. REGULATORY INFORMATION
Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
TSCA Status:

All chemical substances in this material are included on or exempted from listing on the TSCA
Inventory of Chemical Substances.

EPA SARA Title III Chemical Listings
Section 302 Extremely Hazardous Substances (40 CFR 355):
None.

Section 304 CERCLA Hazardous Substances (40 CFR 302):
None.

Section 311/312 Hazard Class (40 CFR 370):
Acute: Yes
Chronic: No
Fire: No

XIAMETER(R)
Material Safety Data Sheet
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DAP(R) 73473 SILICONE SEALANT CLEAR CDN
Pressure: No
Reactive: No
Section 313 Toxic Chemicals (40 CFR 372):
None present or none present in regulated quantities.
Supplemental State Compliance Information
California
Warning: This product contains the following chemical(s) listed by the State of California under the Safe Drinking Water
and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer, birth defects or other
reproductive harm.
None known.
Massachusetts
CAS Number

Wt %

Component Name

7.0 - 13.0

Silica, amorphous

CAS Number

Wt %

Component Name

70131-67-8

> 60.0

Dimethyl siloxane, hydroxy-terminated

7631-86-9

7.0 - 13.0

64742-46-7

<=7.0

17689-77-9

1.0 - 5.0

Ethyltriacetoxysilane

4253-34-3

1.0 - 5.0

Methyltriacetoxysilane

7631-86-9

New Jersey

Silica, amorphous
Hydrotreated middle petroleum distillates

Pennsylvania
CAS Number

Wt %

Component Name

70131-67-8

> 60.0

Dimethyl siloxane, hydroxy-terminated

7631-86-9

7.0 - 13.0

64742-46-7

<=7.0

Silica, amorphous
Hydrotreated middle petroleum distillates

XIAMETER(R)
Material Safety Data Sheet
Page: 8 of 8
Version: 1.5
Revision Date: 2005/06/01

DAP(R) 73473 SILICONE SEALANT CLEAR CDN
16. OTHER INFORMATION
Prepared by: Dow Corning Corporation
These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or
implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally
applicable. However, each user should review these recommendations in the specific context of the intended use and
determine whether they are appropriate.
XIAMETER(R) is a trademark of Dow Corning Corporation
http://www.xiameter.com

0150 T ub & Wall Caulk Strip
0151 T ub & Wall Caulk Strip

Material Safety Data Sheet
(MSDS)
MSDS # 0003
R ev is ion 1

E ME RGE N CY TE LE PH O N E
NO.

SECTION I
TRADE NAME
(IF NONE, PUT CHEMICAL)

Tub & Wall Caulk Strip

MANUFACTURER'S NAME
AND TELEPHONE NO.

Red Devil, Incorporated

ADDRESS (Number, Street,

4175 Webb Street, Pryor, Oklahoma 74361

City, State, Zip Code

)

1-2-0
1-2-0-B

NFPA Rating:
HMIS Rating:

(918) 825-5744 (24 Hrs.)
(918) 825-5744

%

SECTION II - HAZARDOUS INGREDIENTS

TLV

PEL

U N ITS

PRODUCT CONSISTS OF:

Proprietary Butyl Mastic (Mixture)

<20%

NE

NE

NA

Calcium carbonate** [1317-65-3]
(as nuisance particulate, total)

>70%

10

15

mg/m3

Non-hazardous ingredients*

>10%

NA

NA

NA

*Unlisted ingredients are not considered hazardous under the OSHA
Hazard Communication Standard (29 CFR 1910.1200).
**Inhalation of particulates unlikely due to product's physical state
VOC: 12.4%/wt. CARB Compliance: YES. Prop 65 Ingredients: NONE

SECTION III - PHYSICAL DATA
BOILING POINT (°F)

NA

SPECIFIC GRAVITY (H 2 0=1)

NA

VAPOR PRESSURE (MM Hg.)

NA

PERCENT VOLATILES
BY VOLUME (%)

NA

VAPOR DENSITY (AIR=1)

NA

pH

NA

SOLUBILITY IN WATER

Insoluble

EVAPORATION RATE

NA

White Caulk Strip, Slight Organic Odor

APPEARANCE AND ODOR

SECTION IV - FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (Method used)

NA

FLAMMABLE LIMITS

EXTINGUISHING MEDIA

Water, foam, dry chemical, carbon dioxide

SPECIAL FIRE
FIGHTING PROCEDURES

None Known

UNUSUAL FIRE AND
EXPLOSION HAZARDS

None Known
NA - Not Applicable

NE - Not Established

NA

LEL

UN - Unavailable

UEL

SECTION V - HEALTH HAZARD INFORMATION
SYMPTOM/EFFECTS OR OVEREXPOSURE

FIRS T AID
EYES

SKIN

Solid or dust may cause mechanical irritation. In case of eye contact, immediately flush eye with running
water for 15 minutes. Consult a physician if necessary.
No adverse effects anticipated, as the product is not likely to be hazardous by skin contact. Consult a
physician if necessary.

INHALATION

No adverse effects anticipated, as the product is not likely to be hazardous by inhalation. Consult a
physician if necessary.

INGESTION

No adverse effects anticipated, as the product is not likely to be hazardous by ingestion. Consult a
physician if necessary.

SECTION VI - REACTIVITY DATA
STABILITY

Normally stable. Avoid heat, open flame.

INCOMPATIBLE MATERIALS

None Known

HAZARDOUS DECOMPOSITION PRODUCTS

Flammable hydrocarbons, oxides of carbon

SECTION VII - SPILL OR LEAK PROCEDURES
PROCEDURES

NA

WASTE DISPOSAL METHOD

Comply with Federal, State & Local Regulations for disposal.

SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY

Not required

EYEWEAR

Not required

CLOTHING/GLOVES

Not required

VENTILATION

Use local ventilation

SECTION IX - SPECIAL PRECAUTIONS
Store in a closed container in cool area. Avoid heat & open flame.
Reviewed By:
2004

Larry G. Brandon
NAME

VP Technology & General Manager
TITLE

June 24,
DATE

The information contained herein has been developed based upon current available scientific data. New information may be developed from time to time which may render
the conclusions of this report obsolete. Therefore, no warranty is extended as to the applicability of this information to the user's intended purpose or for the consequences of
its use or misuse.

Material
Safety
Data
Sheet

24 Hour Emergency Phone Numbers:
Medical: 1-800 -327-3874
1-513-558 -5111
Transportation:
1-800-535 -5053
1-352-323 -3500

NOTE: National Response Center emergency numbers to be used only in the
event of chemical emergencies involving a spill, leak, fire, exposure or accident
involving chemicals

IMPORTANT: Read this MSDS before handling or disposing of this product, and provide this information to the employees, customers, and users of this
product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with requirements of
this standard. All abbreviated terms used in this MSDS are further described in Section 16.

Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Spanish upon request.
Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en español a su solicitud.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.

Product Name:
LTX WINDOW GLAZING - 12049
Product UPC Number: 7079812108 7079812049 7079870980
Product Use/Class:
Latex Caulk
Manufacturer:
DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888 -327-5477 ( non-emergency matters )

Revision Date:
Supercedes:
MSDS Number:

11/17/2003
11/17/2003
00010404001

Section 2 - Composition / Information On Ingredients
Chemical Name
Di(C9) ester branched & linear
Di(c7) ester branch & linear
Ester Branched & Linear(C7&C9)
Ethylene glycol
Silica, crystalline
Formaldehyde
Acetaldehyde
Acrylonitrile

CASRN
Proprietary
Proprietary
Proprietary
107-21-1
14808-60-7
50 -00-0
75 -07-0
107-13-1

WT%
1-5
1-5
1-5
0.5-1.5
0.1-1.0
<0.02
<0.002
<0.0002

ACGIH TWA
N.E.
N.E.
N.E.
N.E.
0.05 MGM3
N.E.
N.E.
2 PPM

ACGIH STEL
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.

ACGIH CEIL
N.E.
N.E.
N.E.
100 MGM3
N.E.
0.3 PPM
25 PPM
N.E.

OSHA TWA
N.E.
N.E.
N.E.
N.E.
N.E.
0.75 PPM
200 PPM
2 PPM

OSHA STEL
N.E.
N.E.
N.E.
N.E.
N.E.
2 PPM
N.E.
10 PPM

OSHA CEIL
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.

SKIN
No
No
No
No
No
No
No
Yes

Exposure Notes:
CASRN

Exposure Note

14808-60 -7

The 2002 ACGIH Threshold Limit Values for Chemical Substances and Physical Agents lists the median Respirable Particulate Mass (RPM)
point for crystalline silica at 4.0 microns in terms of the particle's aerodynamic diameter.
The TLVs for crystalline silica represent the respirable fraction.
OSHA PEL TLV for Quartz is calculated using the following formula: 10 mg/m3/(% SiO2 + 2). Both concentration and percent quartz for the
application of this limit are to be determined from the fraction passing a size selector with the following characteristics.
|--------------------------------------------------------------------------------------------------------------------------- |-----------------------------------|
| .................................... Aerodynamic diameter ( unit density sphere ) .....................................| Percent passing selector |
| 2 ................................................................................................................................................|.................90....................|
| 2.5 .............................................................................................................................................|..................75...................|

50-00-0

107-13-1

Important:

| 3.5 .............................................................................................................................................|..................50...................|
| 5.0 .............................................................................................................................................|..................25...................|
| 10 ..............................................................................................................................................|...................0....................|
Formaldehyde is a specially regulated substance for which an OSHA chemical-specific exposure standard exits. Detailed information
regarding this substance may be found in 29 CFR 1910.1048. Medical surveillance information regarding this substance may be found in
Appendix C to 29 CFR 1910.1048.
Acrylonitrile is a specially regulated substance for which an OSHA chemical -specific exposure standard exits. Detailed information regarding
this substance may be found in 29 CFR 1910.1045. Medical surveillance information regarding this substance may be found in Appendix C to
29 CFR 1910.1045.

Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary between

states.

Note:

An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent necessary under
the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work practices

Section 3 - Hazards Identification
Emergency Overview: A(n) White to Off-White Paste product. WARNING! Harmful if swallowed or absorbed through the skin.
This product contains ethylene glycol. May cause eye, skin, nose, throat and respiratory tract irritation.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: Causes eye irritation.
Effects Of Overexposure - Skin Contact: Causes skin irritation. Prolonged or repeated contact with skin may cause irritation.
May cause allergic skin reaction or sensitization. Harmful if absorbed through the skin.
Effects Of Overexposure - Inhalation: Harmful if inhaled. Causes nose and throat irritation. Causes lung irritation. Vapor
harmful. May affect the brain or nervous system causing dizziness, headache or nausea. Inhalation may cause irritation to the
respiratory tract (nose, mouth, mucous membranes).
Effects Of Overexposure - Ingestion: Harmful or fatal if swallowed. Ingestion of ethylene glycol can cause gastrointestinal
irritation, nausea, vomiting, diarrhea and if ingested in sufficient quantities, death.
Effects Of Overexposure - Chronic Hazards: Studies have shown that repeated inhalation of ethylene glycol has produced
adverse cardiovascular changes in laboratory animals. Ethylene Glycol may cause kidney and liver damage upon prolonged and
repeated overexposures. Repeated or prolonged exposure may cause respiratory system damage. Prolonged and repeated skin
contact may cause irritation and possibly dermatitis. Formaldehyde vapor is a known animal carcinogen IARC and NTP and is
considered possibly carcinogenic to humans by inhalation. Ethylene glycol has been shown to cause birth defects in laboratory
animals. Overexposure may cause kidney, cardiovascular, skin and liver damage.
Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation
Medical Conditions which May be Aggravated by Exposure: None known.

Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes until
irritation subsides. Get medical attention immediately.
First Aid - Skin Contact: Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing.
First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If continued
breathing difficulty is experienced, get medical attention immediately.

First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
Note to Physician: No Information.
COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arise from any of the above routes of
entry.

Section 5 - Fire Fighting Measures
Flash Point, F: > 200 Fahrenheit
Method: (Seta Closed Cup)

Lower Explosive Limit, %: Not Established
Upper Explosive Limit, %: Not Established

Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: No special protective measures against fire required.
Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent)
and full protective gear. Use water spray to cool exposed surfaces.

Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use
absorbent material or scrape up dried material and place in container.

Section 7 - Handling And Storage
Handling: DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN! Use only with adequate ventilation. Ensure
fresh air entry during application and drying. Avoid breathing vapor and contact with eyes, skin and clothing. Wash thoroughly
after handling.
Storage: Close container after each use. Store containers away from excessive heat and freezing. Store away from caustics and
oxidizers. Do not store at temperatures above 120 degrees F.

Section 8 - Exposure Controls / Personal Protection
Precautionary Measures: No Information.
Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Ensure adequate ventilation,
especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient concentrations below
recommended exposure limits.
Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSH-approved air purifying
respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where airborne
concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA 1910.134 and
ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.
Skin Protection: Rubber gloves.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: Not required under normal use.

Hygienic Practices: Remove and wash contaminated clothing before re-use. Wash hands before breaks and at the end of
workday.

Section 9 - Physical And Chemical Properties
Boiling Range:
Odor:
Appearance:
Solubility in H2O:
Freeze Point:
Vapor Pressure:
Physical State:

Not Established
Not Established
A white to off white paste product
Not Established
Not Established
Not Established
Paste

Vapor Density:
Odor Threshold:
Evaporation Rate:
Specific Gravity:
pH:
Viscosity:

Not Established
Not Established
Not Established
1.826
Between 7.0 and 12.0
Not Established

(See section 16 for abbreviation legend)

Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Incompatible with strong bases and oxidizing agents.
Hazardous Decomposition Products: Normal decomposition products, i.e. COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under recommended storage conditions.

Section 11 - Toxicological Information
Product LD50: Not Established

Product LC50: Not Established

CASRN

Chemical Name

LD50

LC50

107-21-1
50-00-0
107-13-1

Ethylene glycol
Formaldehyde
Acrylonitrile

Rat:4700 mg/kg
------------Oral Rat:78 mg/kg

Rat:10876 mg/kg
Rat:203 mg/m3
Rat:425 ppm/4H

Carcinogenity:
CAS No.

Chemical Name

ACGIH

OSHA

IARC

NTP

14808-60 -7
50-00-0

Silica, crystalline
Formaldehyde

----Potential cancer hazard.

----Probable carcinogen.

Known carcinogen.
Anticipated carcinogen.

107-13-1

Acrylonitrile

Cancer hazard.

Possible carcinogen.

Anticipated carcinogen.

75-07-0

Acetaldehyde

Suspected human carcinogen.
Suspected human carcinogen.
Confirmed animal carcinogen with
unknown relevance to humans.
Confirmed animal carcinogen with
unknown relevance to humans.

-----

Possible carcinogen.

Anticipated carcinogen.

Significant Data with Possible Relevance to Humans: This product contains trace amounts of free formaldehyde. OSHA, NTP
and IARC identify formaldehyde as a potential carcinogen. Formaldehyde has been shown to cause mutations in a variety of invitro test systems, the significance of which to humans is unknown. In a two-year inhalation study, rats showed carcinogenic
effects in the respiratory system at 15 ppm of formaldehyde. There should be minimal risk when used with ventilation adequate to
keep the atmospheric concentration of formaldehyde below the recommended exposure limits. Maintain adequate ventilation to
prevent exposure above current OSHA / ACGIH exposure limits. Workplace monitoring of the air to define formaldehyde exposure
levels may be necessary.

Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.

Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local
regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the
owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): This product does not meet the definition of a hazardous waste according
to U.S. EPA Hazardous Waste Management Regulation, 40 CFR Section 261.

Section 14 - Transportation Information
DOT Proper Shipping Name: Not Regulated
DOT Technical Name:
N.A.
DOT Hazard Class:
N.A.

Packing Group:
Hazard Subclass:
DOT UN/NA Number:

N.A.
N.A.
N.A.

Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet
the following categories:
Immediate Health Hazard, Chronic Health Hazard
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund
Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name

CAS Number

Ethylene glycol

107-21-1

Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the
United States:
None
U.S. State Regulations:
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product:

Chemical Name

CAS Number

Non-Hazardous Polymer
Water

Proprietary
7732-18-5

Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%:
Chemical Name

CAS Number

Non-Hazardous Polymer
Water

Proprietary
7732-18-5

California Proposition 65:
Warning: The following ingredients present in the product are known to the State of California to cause cancer:
Chemical Name

CAS Number

Definition

Date Listed

Silica, crystalline
Formaldehyde
Acrylonitrile
Acetaldehyde

14808-60 -7
50-00-0
107-13-1
75-07-0

Carcinogenic.
Carcinogenic.
Carcinogenic.
Carcinogenic.

Listed: October 1, 1988
Listed: January 1, 1988
Listed: July 1, 1987
Listed: April 1, 1988

Warning: The following ingredients present in the product are known to the State of California to cause birth defects or other
reproductive harm.
None

Section 16 - Other Information
HMIS Ratings:
Health:

Flammability:

VOLATILE ORGANIC COMPOUNDS, GR/LTR: 48.7

Reactivity:
LB/GAL: 0.4

Personal Protection:
WT%: 2.2

REASON FOR REVISION:
Legend:

N.A. – Not Applicable

ACGIH – American Conference of Governmental Industrial Hygienists

N.E. – Not Established

SARA – Superfund Amendments and Reauthorization Act of 1986

N.D. – Not Determined

NJRTK – New Jersey Right-to-Know Law

VOC – Volatile Organic Compound

OSHA – Occupational Safety and Health Administration

PEL – Permissible Exposure Limit

HMIS – Hazardous Materials Identification System

TLV – Threshold Limit Value

NTP – National Toxicology Program

STEL – Short Term Exposure Limit

CEIL – Ceiling Exposure Limit

LD50 – Lethal Dose 50

LC50 – Lethal Concentration 50

F – Degree Fahrenheit

C – Degree Celcius

CASRN – The Chemical Abstracts Service Registry Number

MSDS – Material Safety Data Sheet

DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical values and
not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY PARTICULAR
PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE INFORMATION
HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this document is intended only as a
guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is therefore the responsibility
of the user to (i) review the recommendations with due consideration for the specific context of the intended use and (ii) determine if they are
appropriate.


Page 1 of 7

Material
Safety
Data
Sheet

24 Hour Emergency Phone Numbers:
Medical: 1-800-327-3874
1-513-558-5111
Transportation:
1-800-535-5053
1-352-323-3500

NOTE: National Response Center emergency numbers to be used
only in the event of chemical emergencies involving a spill, leak,
fire, exposure or accident involving chemicals.

IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or
disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been
prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section
16.

Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en español a su solicitud.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.

Product Name:
Product UPC
Number:
Product Use/Class:

DAPTEX® LATEX FOAM MP SEALANT
7079818826 7079818833 7079818834
7079871060
Pressurized Latex Foam

Manufacturer:

DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327-8477 (non-emergency matters)

Revision Date: 02/23/2004
Supercedes:
01/19/2004
MSDS Number: 00077346001

Section 2 - Composition / Information On Ingredients
Chemical Name
Isopropyl alcohol
Ethylene glycol
Dimethyl ether
Propane
n-Butane
Vinyl acetate
Aliphatic amines

CASRN
67-63 -0
107-21-1
115-10-6
74-98 -6
106-97-8
108-05-4
Proprietary

WT%
1-5
1-5
1-5
1-5
1-5
0.1-1.0
0.1-1.0.

ACGIH TWA ACGIH STEL ACGIH CEIL OSHA TWA
200 PPM
400 PPM
N.E.
400 PPM
N.E.
N.E.
100 MGM3 N.E.
N.E.
N.E.
N.E.
N.E.
2500 PPM N.E.
N.E.
1000 PPM
800 PPM
N.E.
N.E.
N.E.
10 PPM
15 PPM
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.

OSHA STEL
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.

OSHA CEIL
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.

Skin
No
No
No
No
No
No
N.E.

Exposure Notes:
Important:

Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits
may vary between states.

Note:

An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the
extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment,
engineering controls or work practices

Section 3 - Hazards Identification

Page 2 of 7
Emergency Overview: A white to off-white liquid with a slight alcoholic odor. DANGER! Contents under
pressure. Harmful if swallowed or absorbed through the skin. Exposure to temperatures above 120 'F may cause
can to rupture. May cause eye, skin, nose, throat and respiratory tract irritation. Vapors harmful if inhaled. Do not
puncture can. This product contains ethylene glycol.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: May cause eye irritation.
Effects Of Overexposure - Skin Contact: May causes skin irritation. Prolonged or repeated contact with skin
may cause irritation. Harmful if absorbed through the skin.
Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation may cause irritation to the respiratory tract
(nose, mouth, mucous membranes). Vapor harmful. May affect the brain or nervous system causing dizziness,
headache or nausea. Causes nose and throat irritation.
Effects Of Overexposure - Ingestion: Harmful or fatal if swallowed. Ingestion of ethylene glycol can cause
gastrointestinal irritation, nausea, vomiting, diarrhea and if ingested in sufficient quantities, death.
Effects Of Overexposure - Chronic Hazards: This product contains vinyl acetate which is classified as a class
2B carcinogen by IARC. Vinyl acetate was found to cause cancer in the respiratory tract of laboratory animals.
There is no evidence that vinyl acetate causes cancer in humans. The IARC published a monograph on vinyl
acetate (1995). In this monograph, IARC indicates "there is inadequate evidence in humans for carcinogenicity of
vinyl acetate. There is limited evidence in experimental animals for the carcinogenicity of vinyl acetate." Normally,
this lack of conclusive evidence would place a substance in the IARC 3 classification (not classified as a human
carcinogen). However, because vinyl acetate is metabolized to acetaldehyde, which has an IARC 2B (possibly
carcinogenic to humans) classification, it also has been listed under Category 2B.
Studies have shown that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in
laboratory animals. Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated
overexposures. Ethylene glycol has been shown to cause birth defects in laboratory animals.
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with
permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the
contents may be harmful or fatal. Repeated or prolonged exposure may cause respiratory system damage.
Prolonged and repeated skin contact may cause irritation and possibly dermatitis.
Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation, Eye Contact
Medical Conditions which May be Aggravated by Exposure: None known.

Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15
minutes until irritation subsides. Get medical attention immediately.
First Aid - Skin Contact: Wash off immediately with soap and plenty of water. Remove and wash contaminated
clothing.
First Aid - Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention immediately.
First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
Note to Physician: No Information.

Page 3 of 7
COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arise from any of the
above routes of entry.

Section 5 - Fire Fighting Measures
Flash Point, F: Aerosol (Extremely
Flammable)
Method: ( Not Applicable)

Lower Explosive Limit, %: Not Established
Upper Explosive Limit, %: Not Established

Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: Do not smoke. Extinguish all flames and pilot lights, and turn off stoves,
heaters, electric motors and other sources of ignition during use and until all vapors are gone. Store away from
caustics and oxidizers. Containers may explode if exposed to extreme heat.
Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved
or equivalent) and full protective gear. Use water spray to cool exposed surfaces.

Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in
Section 8. Use absorbent material or scrape up dried material and place in container.

Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Provide fresh air such that
chemical odors cannot be detected during use and while drying. Use only with adequate ventilation. Ensure fresh
air entry during application and drying. Avoid breathing vapor and contact with eyes, skin and clothing. Make sure
nozzle is directed away from yourself prior to discharge. Intentional misuse by deliberately concentrating and
inhaling vapors may be harmful or fatal. Open all windows and doors or use other means to ensure crossventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous
conditions. Construction and repair activities can adversely affect indoor air quality. Consult with occupants or a
representative (i.e. maintenance, building manager, industrial hygienist, or safety officer) to determine ways to
minimize impact. Wash thoroughly after handling.
Storage: Store containers away from excessive heat and freezing. Do not store at temperatures above 120
degrees F. Keep away from heat and sources of ignition. Protect material from direct sunlight. Store away from
caustics and oxidizers.

Section 8 - Exposure Controls / Personal Protection
Precautionary Measures: Please refer to other sections and subsections of this MSDS.
Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Vapors are
heavier than air and may spread along floors. Check all low areas for presence of vapor. Ensure adequate
ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain
ambient concentrations below recommended exposure limits. Provide sufficient general and/or local exhaust
ventilation to maintain exposure below recommended exposure limit.
Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSHapproved air purifying respirator with an organic vapor cartridge or canister may be necessary under certain
circumstances where airborne concentrations are expected to exceed exposure limits. A respiratory protection
program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace
conditions warrant a respirator's use. If concentrations exceed the exposure limits specified, use of a NIOSH-

Page 4 of 7
approved supplied air respirator is recommended. Where the protection factor is exceeded, use of a Self
Contained Breathing Apparatus (SCBA) may be necessary. No personal respiratory protective equipment
normally required.
Skin Protection: Rubber gloves.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: Not required under normal use.
Hygienic Practices: Remove and wash contaminated clothing before re-use. Wash hands before breaks and at
the end of workday.

Section 9 - Physical And Chemical Properties
Boiling Range:
Odor:
Appearance:

Not Established
Slight Alcoholic
White foaming liquid

Vapor Density:
Odor Threshold:
Evaporation Rate:

Heavier than air
Not Established

Solubility in H2O:
Freeze Point:
Vapor Pressure:
Physical State:

Not Established
Not Established
Not Established
Liquid

Specific Gravity:
pH:
Viscosity:

0.996
Between 7.0 and 12.0
Not Established

Slower than n-butyl
acetate

When reported, the vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined
experimentally.
(See section 16 for abbreviation legend)

Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Incompatible with strong bases and oxidizing agents.
Hazardous Decomposition Products: Normal decomposition products, i.e. COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under recommended storage conditions.

Section 11 - Toxicological Information
Product LD50: Not Established
CASRN
Chemical Name

LD50

67-63-0

Isopropyl alcohol

Rat:5045 mg/kg

Rat:16000 ppm/8H

107-21-1

Ethylene glycol

Rat:4700 mg/kg

-------------

106-97-8

n-Butane

-------------

Rat:658 gm/m3/4H

108-05-4

Vinyl acetate

-------------

Rat:11400 mg/m3/4H

Carcinogenicity:

Product LC50: Not Established
LC50

Page 5 of 7
CAS No.
108-05-4

Chemical Name

ACGIH

OSHA

IARC

NTP

Vinyl acetate

Confirmed animal carcinogen
with unknown relevance to
humans.

-----

Possible carcinogen.

-----

Significant Data with Possible Relevance to Humans: None

Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.

Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and
Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste
disposal is with the owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): D001 if residue remains

Section 14 - Transportation Information
DOT Proper Shipping
Name:
DOT Technical Name:
DOT Hazard Class:

Consumer Commodity

Packing Group:

N.A.
Hazard Subclass:
ORM-D Other regulated materialDOT UN/NA Number:

N.A.
N.A.
N.A.

Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and
312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
Immediate Health Hazard, Chronic Health Hazard
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name

CAS Number

Isopropyl alcohol
Ethylene glycol
Vinyl acetate

67-63-0
107-21-1
108-05-4

Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if
exported from the United States:

Page 6 of 7
None
U.S. State Regulations:
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product:
Chemical Name

CAS Number

Non-Hazardous Polymer
Water

Proprietary
7732-18-5

Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%:
Chemical Name

CAS Number

Non-Hazardous Polymer
Water

Proprietary
7732-18-5

California Proposition 65:
Warning: The following ingredients present in the product are known to the State of California to cause cancer:

None
Warning: The following ingredients present in the product are known to the State of California to cause birth
defects or other reproductive harm.
None

Section 16 - Other Information
HMIS Ratings:
Health: 0

Flammability: 3

Reactivity: 0

VOLATILE ORGANIC COMPOUNDS, GR/LTR: 170.3

LB/GAL: 1.4

WT%: 11.3

REASON FOR REVISION:
Legend:

N.A. – Not Applicable

ACGIH – American Conference of Governmental Industrial Hygienists

N.E. – Not Established

SARA – Superfund Amendments and Reauthorization Act of 1986

N.D. – Not Determined

NJRTK – New Jersey Right-to-Know Law

VOC – Volatile Organic Compound

OSHA – Occupational Safety and Health Administration

PEL – Permissible Exposure Limit

HMIS – Hazardous Materials Identification System

TLV – Threshold Limit Value

NTP – National Toxicology Program

STEL – Short Term Exposure Limit

CEIL – Ceiling Exposure Limit

Page 7 of 7
LD50 – Lethal Dose 50

LC50 – Lethal Concentration 50

F – Degree Fahrenheit

C – Degree Celcius

MSDS – Material Safety Data Sheet

CASRN – The Chemical Abstracts Service Registry Number

DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as
typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF
FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS
MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE
INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary
handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the
recommendations with due consideration for the specific context of the intended use and (ii) determine if they are
appropriate.


Page 1 of 7

Material
Safety
Data
Sheet

24 Hour Emergency Phone Numbers:
Medical: 1-800-327-3874
1-513-558-5111
Transportation:
1-800-535-5053
1-352-323-3500

NOTE: National Response Center emergency numbers to be used
only in the event of chemical emergencies involving a spill, leak,
fire, exposure or accident involving chemicals.

IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or
disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been
prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section
16.

Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en español a su solicitud.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.

Product Name:
Product UPC
Number:
Product Use/Class:

DAPTEX® LATEX FOAM MP SEALANT
7079818826 7079818833 7079818834
7079871060
Pressurized Latex Foam

Manufacturer:

DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327-8477 (non-emergency matters)

Revision Date: 02/23/2004
Supercedes:
01/19/2004
MSDS Number: 00077346001

Section 2 - Composition / Information On Ingredients
Chemical Name
Isopropyl alcohol
Ethylene glycol
Dimethyl ether
Propane
n-Butane
Vinyl acetate
Aliphatic amines

CASRN
67-63 -0
107-21-1
115-10-6
74-98 -6
106-97-8
108-05-4
Proprietary

WT%
1-5
1-5
1-5
1-5
1-5
0.1-1.0
0.1-1.0.

ACGIH TWA ACGIH STEL ACGIH CEIL OSHA TWA
200 PPM
400 PPM
N.E.
400 PPM
N.E.
N.E.
100 MGM3 N.E.
N.E.
N.E.
N.E.
N.E.
2500 PPM N.E.
N.E.
1000 PPM
800 PPM
N.E.
N.E.
N.E.
10 PPM
15 PPM
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.

OSHA STEL
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.

OSHA CEIL
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.

Skin
No
No
No
No
No
No
N.E.

Exposure Notes:
Important:

Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits
may vary between states.

Note:

An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the
extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment,
engineering controls or work practices

Section 3 - Hazards Identification

Page 2 of 7
Emergency Overview: A white to off-white liquid with a slight alcoholic odor. DANGER! Contents under
pressure. Harmful if swallowed or absorbed through the skin. Exposure to temperatures above 120 'F may cause
can to rupture. May cause eye, skin, nose, throat and respiratory tract irritation. Vapors harmful if inhaled. Do not
puncture can. This product contains ethylene glycol.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: May cause eye irritation.
Effects Of Overexposure - Skin Contact: May causes skin irritation. Prolonged or repeated contact with skin
may cause irritation. Harmful if absorbed through the skin.
Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation may cause irritation to the respiratory tract
(nose, mouth, mucous membranes). Vapor harmful. May affect the brain or nervous system causing dizziness,
headache or nausea. Causes nose and throat irritation.
Effects Of Overexposure - Ingestion: Harmful or fatal if swallowed. Ingestion of ethylene glycol can cause
gastrointestinal irritation, nausea, vomiting, diarrhea and if ingested in sufficient quantities, death.
Effects Of Overexposure - Chronic Hazards: This product contains vinyl acetate which is classified as a class
2B carcinogen by IARC. Vinyl acetate was found to cause cancer in the respiratory tract of laboratory animals.
There is no evidence that vinyl acetate causes cancer in humans. The IARC published a monograph on vinyl
acetate (1995). In this monograph, IARC indicates "there is inadequate evidence in humans for carcinogenicity of
vinyl acetate. There is limited evidence in experimental animals for the carcinogenicity of vinyl acetate." Normally,
this lack of conclusive evidence would place a substance in the IARC 3 classification (not classified as a human
carcinogen). However, because vinyl acetate is metabolized to acetaldehyde, which has an IARC 2B (possibly
carcinogenic to humans) classification, it also has been listed under Category 2B.
Studies have shown that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in
laboratory animals. Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated
overexposures. Ethylene glycol has been shown to cause birth defects in laboratory animals.
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with
permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the
contents may be harmful or fatal. Repeated or prolonged exposure may cause respiratory system damage.
Prolonged and repeated skin contact may cause irritation and possibly dermatitis.
Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation, Eye Contact
Medical Conditions which May be Aggravated by Exposure: None known.

Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15
minutes until irritation subsides. Get medical attention immediately.
First Aid - Skin Contact: Wash off immediately with soap and plenty of water. Remove and wash contaminated
clothing.
First Aid - Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention immediately.
First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
Note to Physician: No Information.

Page 3 of 7
COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arise from any of the
above routes of entry.

Section 5 - Fire Fighting Measures
Flash Point, F: Aerosol (Extremely
Flammable)
Method: ( Not Applicable)

Lower Explosive Limit, %: Not Established
Upper Explosive Limit, %: Not Established

Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: Do not smoke. Extinguish all flames and pilot lights, and turn off stoves,
heaters, electric motors and other sources of ignition during use and until all vapors are gone. Store away from
caustics and oxidizers. Containers may explode if exposed to extreme heat.
Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved
or equivalent) and full protective gear. Use water spray to cool exposed surfaces.

Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in
Section 8. Use absorbent material or scrape up dried material and place in container.

Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Provide fresh air such that
chemical odors cannot be detected during use and while drying. Use only with adequate ventilation. Ensure fresh
air entry during application and drying. Avoid breathing vapor and contact with eyes, skin and clothing. Make sure
nozzle is directed away from yourself prior to discharge. Intentional misuse by deliberately concentrating and
inhaling vapors may be harmful or fatal. Open all windows and doors or use other means to ensure crossventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous
conditions. Construction and repair activities can adversely affect indoor air quality. Consult with occupants or a
representative (i.e. maintenance, building manager, industrial hygienist, or safety officer) to determine ways to
minimize impact. Wash thoroughly after handling.
Storage: Store containers away from excessive heat and freezing. Do not store at temperatures above 120
degrees F. Keep away from heat and sources of ignition. Protect material from direct sunlight. Store away from
caustics and oxidizers.

Section 8 - Exposure Controls / Personal Protection
Precautionary Measures: Please refer to other sections and subsections of this MSDS.
Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Vapors are
heavier than air and may spread along floors. Check all low areas for presence of vapor. Ensure adequate
ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain
ambient concentrations below recommended exposure limits. Provide sufficient general and/or local exhaust
ventilation to maintain exposure below recommended exposure limit.
Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSHapproved air purifying respirator with an organic vapor cartridge or canister may be necessary under certain
circumstances where airborne concentrations are expected to exceed exposure limits. A respiratory protection
program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace
conditions warrant a respirator's use. If concentrations exceed the exposure limits specified, use of a NIOSH-

Page 4 of 7
approved supplied air respirator is recommended. Where the protection factor is exceeded, use of a Self
Contained Breathing Apparatus (SCBA) may be necessary. No personal respiratory protective equipment
normally required.
Skin Protection: Rubber gloves.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: Not required under normal use.
Hygienic Practices: Remove and wash contaminated clothing before re-use. Wash hands before breaks and at
the end of workday.

Section 9 - Physical And Chemical Properties
Boiling Range:
Odor:
Appearance:

Not Established
Slight Alcoholic
White foaming liquid

Vapor Density:
Odor Threshold:
Evaporation Rate:

Heavier than air
Not Established

Solubility in H2O:
Freeze Point:
Vapor Pressure:
Physical State:

Not Established
Not Established
Not Established
Liquid

Specific Gravity:
pH:
Viscosity:

0.996
Between 7.0 and 12.0
Not Established

Slower than n-butyl
acetate

When reported, the vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined
experimentally.
(See section 16 for abbreviation legend)

Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Incompatible with strong bases and oxidizing agents.
Hazardous Decomposition Products: Normal decomposition products, i.e. COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under recommended storage conditions.

Section 11 - Toxicological Information
Product LD50: Not Established
CASRN
Chemical Name

LD50

67-63-0

Isopropyl alcohol

Rat:5045 mg/kg

Rat:16000 ppm/8H

107-21-1

Ethylene glycol

Rat:4700 mg/kg

-------------

106-97-8

n-Butane

-------------

Rat:658 gm/m3/4H

108-05-4

Vinyl acetate

-------------

Rat:11400 mg/m3/4H

Carcinogenicity:

Product LC50: Not Established
LC50

Page 5 of 7
CAS No.
108-05-4

Chemical Name

ACGIH

OSHA

IARC

NTP

Vinyl acetate

Confirmed animal carcinogen
with unknown relevance to
humans.

-----

Possible carcinogen.

-----

Significant Data with Possible Relevance to Humans: None

Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.

Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and
Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste
disposal is with the owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): D001 if residue remains

Section 14 - Transportation Information
DOT Proper Shipping
Name:
DOT Technical Name:
DOT Hazard Class:

Consumer Commodity

Packing Group:

N.A.
Hazard Subclass:
ORM-D Other regulated materialDOT UN/NA Number:

N.A.
N.A.
N.A.

Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and
312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
Immediate Health Hazard, Chronic Health Hazard
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name

CAS Number

Isopropyl alcohol
Ethylene glycol
Vinyl acetate

67-63-0
107-21-1
108-05-4

Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if
exported from the United States:

Page 6 of 7
None
U.S. State Regulations:
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product:
Chemical Name

CAS Number

Non-Hazardous Polymer
Water

Proprietary
7732-18-5

Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%:
Chemical Name

CAS Number

Non-Hazardous Polymer
Water

Proprietary
7732-18-5

California Proposition 65:
Warning: The following ingredients present in the product are known to the State of California to cause cancer:

None
Warning: The following ingredients present in the product are known to the State of California to cause birth
defects or other reproductive harm.
None

Section 16 - Other Information
HMIS Ratings:
Health: 0

Flammability: 3

Reactivity: 0

VOLATILE ORGANIC COMPOUNDS, GR/LTR: 170.3

LB/GAL: 1.4

WT%: 11.3

REASON FOR REVISION:
Legend:

N.A. – Not Applicable

ACGIH – American Conference of Governmental Industrial Hygienists

N.E. – Not Established

SARA – Superfund Amendments and Reauthorization Act of 1986

N.D. – Not Determined

NJRTK – New Jersey Right-to-Know Law

VOC – Volatile Organic Compound

OSHA – Occupational Safety and Health Administration

PEL – Permissible Exposure Limit

HMIS – Hazardous Materials Identification System

TLV – Threshold Limit Value

NTP – National Toxicology Program

STEL – Short Term Exposure Limit

CEIL – Ceiling Exposure Limit

Page 7 of 7
LD50 – Lethal Dose 50

LC50 – Lethal Concentration 50

F – Degree Fahrenheit

C – Degree Celcius

MSDS – Material Safety Data Sheet

CASRN – The Chemical Abstracts Service Registry Number

DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as
typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF
FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS
MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE
INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary
handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the
recommendations with due consideration for the specific context of the intended use and (ii) determine if they are
appropriate.


Page 1 of 7

Material
Safety
Data
Sheet

24 Hour Emergency Phone Numbers:
Medical: 1-800-327-3874
1-513-558-5111
Transportation:
1-800-535-5053
1-352-323-3500

NOTE: National Response Center emergency numbers to be used
only in the event of chemical emergencies involving a spill, leak,
fire, exposure or accident involving chemicals.

IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or
disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been
prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section
16.

Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en español a su solicitud.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.

Product Name:
Product UPC
Number:
Product Use/Class:

DAPTEX® LATEX FOAM MP SEALANT
7079818826 7079818833 7079818834
7079871060
Pressurized Latex Foam

Manufacturer:

DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327-8477 (non-emergency matters)

Revision Date: 02/23/2004
Supercedes:
01/19/2004
MSDS Number: 00077346001

Section 2 - Composition / Information On Ingredients
Chemical Name
Isopropyl alcohol
Ethylene glycol
Dimethyl ether
Propane
n-Butane
Vinyl acetate
Aliphatic amines

CASRN
67-63 -0
107-21-1
115-10-6
74-98 -6
106-97-8
108-05-4
Proprietary

WT%
1-5
1-5
1-5
1-5
1-5
0.1-1.0
0.1-1.0.

ACGIH TWA ACGIH STEL ACGIH CEIL OSHA TWA
200 PPM
400 PPM
N.E.
400 PPM
N.E.
N.E.
100 MGM3 N.E.
N.E.
N.E.
N.E.
N.E.
2500 PPM N.E.
N.E.
1000 PPM
800 PPM
N.E.
N.E.
N.E.
10 PPM
15 PPM
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.

OSHA STEL
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.

OSHA CEIL
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.

Skin
No
No
No
No
No
No
N.E.

Exposure Notes:
Important:

Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits
may vary between states.

Note:

An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the
extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment,
engineering controls or work practices

Section 3 - Hazards Identification

Page 2 of 7
Emergency Overview: A white to off-white liquid with a slight alcoholic odor. DANGER! Contents under
pressure. Harmful if swallowed or absorbed through the skin. Exposure to temperatures above 120 'F may cause
can to rupture. May cause eye, skin, nose, throat and respiratory tract irritation. Vapors harmful if inhaled. Do not
puncture can. This product contains ethylene glycol.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: May cause eye irritation.
Effects Of Overexposure - Skin Contact: May causes skin irritation. Prolonged or repeated contact with skin
may cause irritation. Harmful if absorbed through the skin.
Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation may cause irritation to the respiratory tract
(nose, mouth, mucous membranes). Vapor harmful. May affect the brain or nervous system causing dizziness,
headache or nausea. Causes nose and throat irritation.
Effects Of Overexposure - Ingestion: Harmful or fatal if swallowed. Ingestion of ethylene glycol can cause
gastrointestinal irritation, nausea, vomiting, diarrhea and if ingested in sufficient quantities, death.
Effects Of Overexposure - Chronic Hazards: This product contains vinyl acetate which is classified as a class
2B carcinogen by IARC. Vinyl acetate was found to cause cancer in the respiratory tract of laboratory animals.
There is no evidence that vinyl acetate causes cancer in humans. The IARC published a monograph on vinyl
acetate (1995). In this monograph, IARC indicates "there is inadequate evidence in humans for carcinogenicity of
vinyl acetate. There is limited evidence in experimental animals for the carcinogenicity of vinyl acetate." Normally,
this lack of conclusive evidence would place a substance in the IARC 3 classification (not classified as a human
carcinogen). However, because vinyl acetate is metabolized to acetaldehyde, which has an IARC 2B (possibly
carcinogenic to humans) classification, it also has been listed under Category 2B.
Studies have shown that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in
laboratory animals. Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated
overexposures. Ethylene glycol has been shown to cause birth defects in laboratory animals.
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with
permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the
contents may be harmful or fatal. Repeated or prolonged exposure may cause respiratory system damage.
Prolonged and repeated skin contact may cause irritation and possibly dermatitis.
Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation, Eye Contact
Medical Conditions which May be Aggravated by Exposure: None known.

Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15
minutes until irritation subsides. Get medical attention immediately.
First Aid - Skin Contact: Wash off immediately with soap and plenty of water. Remove and wash contaminated
clothing.
First Aid - Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention immediately.
First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
Note to Physician: No Information.

Page 3 of 7
COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arise from any of the
above routes of entry.

Section 5 - Fire Fighting Measures
Flash Point, F: Aerosol (Extremely
Flammable)
Method: ( Not Applicable)

Lower Explosive Limit, %: Not Established
Upper Explosive Limit, %: Not Established

Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: Do not smoke. Extinguish all flames and pilot lights, and turn off stoves,
heaters, electric motors and other sources of ignition during use and until all vapors are gone. Store away from
caustics and oxidizers. Containers may explode if exposed to extreme heat.
Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved
or equivalent) and full protective gear. Use water spray to cool exposed surfaces.

Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in
Section 8. Use absorbent material or scrape up dried material and place in container.

Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Provide fresh air such that
chemical odors cannot be detected during use and while drying. Use only with adequate ventilation. Ensure fresh
air entry during application and drying. Avoid breathing vapor and contact with eyes, skin and clothing. Make sure
nozzle is directed away from yourself prior to discharge. Intentional misuse by deliberately concentrating and
inhaling vapors may be harmful or fatal. Open all windows and doors or use other means to ensure crossventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous
conditions. Construction and repair activities can adversely affect indoor air quality. Consult with occupants or a
representative (i.e. maintenance, building manager, industrial hygienist, or safety officer) to determine ways to
minimize impact. Wash thoroughly after handling.
Storage: Store containers away from excessive heat and freezing. Do not store at temperatures above 120
degrees F. Keep away from heat and sources of ignition. Protect material from direct sunlight. Store away from
caustics and oxidizers.

Section 8 - Exposure Controls / Personal Protection
Precautionary Measures: Please refer to other sections and subsections of this MSDS.
Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Vapors are
heavier than air and may spread along floors. Check all low areas for presence of vapor. Ensure adequate
ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain
ambient concentrations below recommended exposure limits. Provide sufficient general and/or local exhaust
ventilation to maintain exposure below recommended exposure limit.
Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSHapproved air purifying respirator with an organic vapor cartridge or canister may be necessary under certain
circumstances where airborne concentrations are expected to exceed exposure limits. A respiratory protection
program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace
conditions warrant a respirator's use. If concentrations exceed the exposure limits specified, use of a NIOSH-

Page 4 of 7
approved supplied air respirator is recommended. Where the protection factor is exceeded, use of a Self
Contained Breathing Apparatus (SCBA) may be necessary. No personal respiratory protective equipment
normally required.
Skin Protection: Rubber gloves.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: Not required under normal use.
Hygienic Practices: Remove and wash contaminated clothing before re-use. Wash hands before breaks and at
the end of workday.

Section 9 - Physical And Chemical Properties
Boiling Range:
Odor:
Appearance:

Not Established
Slight Alcoholic
White foaming liquid

Vapor Density:
Odor Threshold:
Evaporation Rate:

Heavier than air
Not Established

Solubility in H2O:
Freeze Point:
Vapor Pressure:
Physical State:

Not Established
Not Established
Not Established
Liquid

Specific Gravity:
pH:
Viscosity:

0.996
Between 7.0 and 12.0
Not Established

Slower than n-butyl
acetate

When reported, the vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined
experimentally.
(See section 16 for abbreviation legend)

Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Incompatible with strong bases and oxidizing agents.
Hazardous Decomposition Products: Normal decomposition products, i.e. COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under recommended storage conditions.

Section 11 - Toxicological Information
Product LD50: Not Established
CASRN
Chemical Name

LD50

67-63-0

Isopropyl alcohol

Rat:5045 mg/kg

Rat:16000 ppm/8H

107-21-1

Ethylene glycol

Rat:4700 mg/kg

-------------

106-97-8

n-Butane

-------------

Rat:658 gm/m3/4H

108-05-4

Vinyl acetate

-------------

Rat:11400 mg/m3/4H

Carcinogenicity:

Product LC50: Not Established
LC50

Page 5 of 7
CAS No.
108-05-4

Chemical Name

ACGIH

OSHA

IARC

NTP

Vinyl acetate

Confirmed animal carcinogen
with unknown relevance to
humans.

-----

Possible carcinogen.

-----

Significant Data with Possible Relevance to Humans: None

Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.

Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and
Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste
disposal is with the owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): D001 if residue remains

Section 14 - Transportation Information
DOT Proper Shipping
Name:
DOT Technical Name:
DOT Hazard Class:

Consumer Commodity

Packing Group:

N.A.
Hazard Subclass:
ORM-D Other regulated materialDOT UN/NA Number:

N.A.
N.A.
N.A.

Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and
312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
Immediate Health Hazard, Chronic Health Hazard
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name

CAS Number

Isopropyl alcohol
Ethylene glycol
Vinyl acetate

67-63-0
107-21-1
108-05-4

Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if
exported from the United States:

Page 6 of 7
None
U.S. State Regulations:
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product:
Chemical Name

CAS Number

Non-Hazardous Polymer
Water

Proprietary
7732-18-5

Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%:
Chemical Name

CAS Number

Non-Hazardous Polymer
Water

Proprietary
7732-18-5

California Proposition 65:
Warning: The following ingredients present in the product are known to the State of California to cause cancer:

None
Warning: The following ingredients present in the product are known to the State of California to cause birth
defects or other reproductive harm.
None

Section 16 - Other Information
HMIS Ratings:
Health: 0

Flammability: 3

Reactivity: 0

VOLATILE ORGANIC COMPOUNDS, GR/LTR: 170.3

LB/GAL: 1.4

WT%: 11.3

REASON FOR REVISION:
Legend:

N.A. – Not Applicable

ACGIH – American Conference of Governmental Industrial Hygienists

N.E. – Not Established

SARA – Superfund Amendments and Reauthorization Act of 1986

N.D. – Not Determined

NJRTK – New Jersey Right-to-Know Law

VOC – Volatile Organic Compound

OSHA – Occupational Safety and Health Administration

PEL – Permissible Exposure Limit

HMIS – Hazardous Materials Identification System

TLV – Threshold Limit Value

NTP – National Toxicology Program

STEL – Short Term Exposure Limit

CEIL – Ceiling Exposure Limit

Page 7 of 7
LD50 – Lethal Dose 50

LC50 – Lethal Concentration 50

F – Degree Fahrenheit

C – Degree Celcius

MSDS – Material Safety Data Sheet

CASRN – The Chemical Abstracts Service Registry Number

DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as
typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF
FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS
MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE
INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary
handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the
recommendations with due consideration for the specific context of the intended use and (ii) determine if they are
appropriate.


MATERIAL SAFETY DATA SHEET
MSDS Name: SA-167 SILICONIZED ACRYLIC LATEX CAULK
MSDS Number: 16711-001
Version Number
2
MSDS Date:
SEP-09-2002
Page Number:
1
-----------------------------------------------------------------------------

SECTION I - PRODUCT AND COMPANY INFORMATION

Product Name:
HMIS Hazard Rating:

SA-167 SILICONIZED ACRYLIC LATEX CAULK
Health: 1 Fire: 0 Reactivity: 0 PPE: B

Company Identification:

OSI SEALANTS, INC.a Subsidiary
of Sovereign Specialty Chems.
7405 PRODUCTION DRIVE
MENTOR OH 44060

Information phone/Fax:
Emergency Phone (24 hour)
Chemtrec (outside-USA)

(440) 255-8900 (440) 974-8358
CHEMTREC
(800) 424-9300
(703) 527-3887

Product Class
Trade Name
Product Code

CAULK
PRO-SERIES
16711-XXX

SECTION II - INGREDIENT AND HAZARD INFORMATION
Hazardous Ingredient Name
CAS Number

Percent

Titanium Dioxide **

13463-67-7

< 5.0

Y

ETHYLENE GLYCOL

107-21-1

< 2.0

Y

MINERAL SPIRITS

64742-48-9

< 2.0

Y

TSCA

Ingredient Notes:
Remaining ingredients are not considered OSHA hazardous.
**The main hazard for Titanium Dioxide is dust inhalation. Because of
its incorporation into the caulk, exposure by inhalation is unlikely.
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION III - PHYSICAL AND CHEMICAL PROPERTIES
Form:
High viscosity caulk
Appearance/Color:
various colors
Solubility (in water):
yes
pH Value, +/-.3:
7.5
--------------------------------------------------------------------------------

MATERIAL SAFETY DATA SHEET
MSDS Name: SA-167 SILICONIZED ACRYLIC LATEX CAULK
MSDS Number: 16711-001
Version Number
2
MSDS Date:
SEP-09-2002
Page Number:
2
----------------------------------------------------------------------------Boiling Range:
Vapor Pressure (mmHg):
Evaporation Rate:

212.øF (100.øC)
15.@ 68.øF (20.øC)
0.5 times Slower than n-Butyl Acetate

Vapor Density:

Heavier than air

% Volatile, Weight
% Volatile, Volume
Specific Gravity:
VOC (less H2O or exempt)

approx. 20.%
approx. 30.%
1.556
41 Gr/L (2%)

NOTE:
Odor : Mild acrylic odor.

Freeze Point : 32 Deg F

- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION IV - FIRE FIGHTING MEASURES (Flash,UEL,LEL for solvent only)
Flammability Class
N/A
Flash Range:
Not Available
Explosive Range (LEL/UEL):
Not Applicable

EXTINGUISHING MEDIA:
Dry chemical -- Carbon Dioxide -- Foam -- Water Fog
Will not burn in wet state.
SPECIAL FIRE-FIGHTING PROCEDURES:
Water may be used to cool and protect exposed containers.
Caution should be taken because uncured material is water soluble.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Any closed container may burst when exposed to extreme
heat or fire.
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION V - HEALTH HAZARD DATA
ROUTES OF ENTRY:
ENTRY THROUGH...Inhalation and skin most likely
CARCINOGENICITY...
NTP? N/E
|
IARC Monographs? N/E
|
OHSA? NO
EFFECTS OF OVEREXPOSURE
Inhalation:
May irritate respiratory tract.
Skin/Eye Contact: May cause irritation.
Ingestion:
Swallowing large amounts may cause nausea,
vomiting. ( an unlikely route of entry )
--------------------------------------------------------------------------------

MATERIAL SAFETY DATA SHEET
MSDS Name: SA-167 SILICONIZED ACRYLIC LATEX CAULK
MSDS Number: 16711-001
Version Number
2
MSDS Date:
SEP-09-2002
Page Number:
3
----------------------------------------------------------------------------FIRST AID MEASURES
Inhalation:
If affected by inhalation, remove to fresh air.
Eye Contact: Flush with water for at least 15 minutes, and
get prompt medical attention.
Skin Contact: Wash skin thoroughly with soap and water.
Ingestion:
Drink water, and get medical attention.
------------------------------------------------------------------N/A= Not applicable N/AV=Not available N/E, N/est=Not established
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION VI - STABILITY AND REACTIVITY
Stability:
This product is stable
Hazardous Polymerization:
Hazardous polymerization will not occur
INCOMPATABILITY:
None
CONDITIONS TO AVOID:
None
HAZARDOUS DECOMPOSITION PRODUCTS:
May produce oxides of carbon and oxides of nitrogen when burned.
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION VII - ACCIDENTAL RELEASE AND DISPOSAL MEASURES:
STEPS TO BE TAKEN IN CASE OF SPILL:
Wear appropriate protective clothing. Add dry absorbent and
shovel or sweep up. Place in an appropriate container and seal.
WASTE DISPOSAL METHOD:
Dispose of in accordance with Federal, State, and Local regulations.
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
ACGIH TLV
ACGIH TLV-C

ACGIH STEL

OSHA STEL

OSHA PEL

Titanium Dioxide **
10.00 mg/F3

N/est

N/est

N/est

15.00 mg/F3

ETHYLENE GLYCOL
50.00 PPM

N/est

N/est

N/est

50.00 PPM

MINERAL SPIRITS
100.00 PPM

N/est

N/est

N/est

100.00 PPM

--------------------------------------------------------------------------------

MATERIAL SAFETY DATA SHEET
MSDS Name: SA-167 SILICONIZED ACRYLIC LATEX CAULK
MSDS Number: 16711-001
Version Number
2
MSDS Date:
SEP-09-2002
Page Number:
4
-----------------------------------------------------------------------------

RESPIRATORY PROTECTION:
NIOSH respirators recommended if vapors and mists are generated.
VENTILATION:
Local exhaust is recommended for safe practice.
PROTECTIVE CLOTHING:
Gloves and clothing should be worn to prevent repeated skin contact.
EYE PROTECTION:
Splashproof goggles or safety glasses should be worn.
HANDLING AND STORAGE PRECAUTIONS:
Keep from freezing.
Keep away from heat.
Keep containers closed when not in use.
Avoid prolonged or repeated contact with skin.
Keep out of the reach of children.
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION IX - TRANSPORT INFORMATION:
DOT

CLASSIFICATIONS FOR ONE GALLON AND UNDER CONTAINERS

DESCRIPTION:
Non-hazardous
DOT CLASSIFICATIONS for OVER 1 GALLON size CONTAINERS
DESCRIPTION:

Non-hazardous,

Caulking product

- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - SECTION X - REGULATORY INFORMATION:
SARA TITLE III SECTION 313:
This product contains the following toxic chemicals subject to the
reporting requirements of Section 313 of the Emergency Planning and
Community Right to Know Act of 1986 and of 40 CFR 372:
Ingredient Name

CAS Number

Percent

ETHYLENE GLYCOL

107-21-1

< 2.0

The following ingredients are registered for TSCA 12B
Ingredient Name
CAS Number

Percent

ETHYLENE GLYCOL

< 2.0

107-21-1

Ethylene Glycol fits the EPA Hazard Category definition of Immediate
(Acute) and Delayed (Chronic) Health Hazards under SARA Sect.311,312.
--------------------------------------------------------------------------------

MATERIAL SAFETY DATA SHEET
MSDS Name: SA-167 SILICONIZED ACRYLIC LATEX CAULK
MSDS Number: 16711-001
Version Number
2
MSDS Date:
SEP-09-2002
Page Number:
5
----------------------------------------------------------------------------All chemical substances are TSCA listed.
California PROP.65 Chemicals:
none known
DISCLAIMER:
The information contained herein is based on data available as of
the date of preparation of this MSDS and which we believe to be
reliable. However, no warranty is expressed or implied regarding
the accuracy of the data. We shall not be responsible for the use
of this information, or of any product, method, or apparatus mentioned, and the user must make his own investigation to determine
the suitability of the information or products for his particular
purpose, for the protection of the environment, and the health and
safety of the users of this material.

--------------------------------------------------------------------------------

Last Page

00010011605 English

Page 1 of 7

Material
Safety
Data
Sheet

24 Hour Emergency Phone Numbers:
Medical/Poison Control:
In U.S.: Call 1-800-222-1222
Outside U.S.: Call your local poison
control center
Transportation/National Response
Center:
1-800-535-5053
1-352-323-3500

NOTE: The National Response Center emergency numbers to
be used only in the event of chemical emergencies involving a
spill, leak, fire, exposure or accident involving chemicals.

IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of
this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16.

Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
On peut demader cette fiche signalétique (MSDS) a la langue francaise-canadienne.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.

Product Name:
Product UPC
Number:
Product Use/Class:
Manufacturer:

DAP Alex Painters Acrylic Latex Caulk - All
Colors
070798736313, 070798736351

Revision
Date:
Supercedes:

04/01/2008

Latex Caulk

MSDS
Number:

00010011605

10/29/2004

DAP Canada
475 Finchdene Square Unit 5
Scarborough, Ontario M1X 1B7
888-327 -8477 (non-emergency)

Section 2 - Hazards Identification
Emergency Overview: A colored paste product with a very slight ammonia odor. WARNING! May cause eye, skin, nose,
throat and respiratory tract irritation. May cause eye or skin irritation. Harmful if swallowed or absorbed through the skin.
This product contains ethylene glycol.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: May cause eye irritation.
Effects Of Overexposure - Skin Contact: May cause skin irritation. Harmful if absorbed through the skin.
Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation of high concentrations may cause headache,
nausea, and dizziness. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes).
Inhalation may cause mild irritation to the respiratory tract (nose, mouth, mucous membranes).
Effects Of Overexposure - Ingestion: Ingestion of ethylene glycol can cause gastrointestinal irritation, nausea,
vomiting, diarrhea and if ingested in sufficient quantities, death. Harmful or fatal if swallowed. Ingestion may cause
gastrointestinal irritation, nausea, vomiting and diarrhea. If ingested, may cause vomiting, diarrhea, and depressed
respiration. Ingestion may result in obstruction when material hardens.
Effects Of Overexposure - Chronic Hazards: Repeated or prolonged exposure may cause respiratory system damage.

00010011605 English

Page 2 of 7

Prolonged and repeated skin contact may cause irritation and possibly dermatitis.
The International Agency for Research on Cancer (IARC) has determined that crystalline silica in the form of quartz or
cristobalite that is inhaled from occupational sources is carcinogenic to humans (Group 1- carcinogenic to humans). Refer
to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (published in June 1997) in conjunction with the use of
these materials. The National Toxicology Program (NTP) classifies respirable crystalline silica as "known to be a human
carcinogen". Refer to the 9th Report on Carcinogens (2000). The American Conference of Governmental Industrial
Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (Group A2).
Breathing dust containing respirable crystalline silica may not cause noticeable injury or illness even though permanent
lung damage may be occurring. Inhalation of dust may have the following serious chronic health effects: Excessive
inhalation of respirable dust can cause pneumoconiosis, a respiratory disease, which can result in delayed, progressive,
disabling and sometimes fatal lung injury. Symptoms include cough, shortness of breath, wheezing, non-specific chest
illness and reduced pulmonary function. Smoking exacerbates this disease. Individuals with pneumoconiosis are
predisposed to develop tuberculosis. There is some evidence that breathing respirable crystalline silica or the disease
silicosis is associated with an increased incidence of significant disease endpoints such as scleroderma (an immune
system disorder manifested by fibrosis of the lungs, skin and other internal organs) and kidney disease. Prolonged,
repeated, or high exposures may cause weakness and depression of the central nervous system. Overexposure may
cause kidney, cardiovascular, skin and liver damage.
Formaldehyde vapor is a known animal carcinogen according to OSHA and NTP and is considered possibly carcinogenic
to humans by inhalation. The International Agency for Research on Cancer considers formaldehyde to be a human
carcinogen.
A mixture of diisodecyl phthalate and diisononyl phthalate has been tested in a two-generation toxicity study in laboratory
animals. No effects on reproductive parameters were seen. However, a small but statistically significant increase in early
offspring mortality was seen at high oral doses. The significance of this to humans is uncertain.
The mixture of phthalate esters contained within this product has been shown to cause developmental effects at high
doses in laboratory animals when administered orally by gavage in a developmental study and developmental and fertility
effects when administered at high doses by feed in a two-generation reproduction study. The potential risk from
occupational and consumer exposure is considered to be very low, based on limited relevance of the rodent findings to
humans and the large safety margins between exposure and the effect levels.
Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Studies have shown
that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals. Ethylene
glycol has been shown to cause birth defects in laboratory animals.
Primary Route(s) Of Entry: Skin Contact, Inhalation, Eye Contact
Medical Conditions which May be Aggravated by Exposure: None known.
Carcinogenicity:
CAS No.

Chemical Name

14808-60-7

Silica, crystalline

13463-67-7

Titanium dioxide

50-00-0

Formaldehyde

ACGIH

OSHA

Suspected human
carcinogen.
Not Listed.
Suspected human
carcinogen.

IARC

NTP

Not Listed.

Human carcinogen.

Known carcinogen.

Not Listed.

Possible carcinogen.

Not Listed.

Potential cancer hazard.

Human carcinogen.

Anticipated carcinogen.

Section 3 - Composition / Information On Ingredients
Chemical Name
Limestone
Branched and linear phthalates
Stoddard solvent
Ethylene glycol
Silica, crystalline
Titanium dioxide

CASRN
1317-65-3
Proprietary
8052-41-3
107-21-1
14808-60 -7
13463-67 -7

Wt%
40 -70
1-5
0.5-1.5
0.1-1.0
0.1-1.0
0.1-1.0

00010011605 English

Page 3 of 7

Ammonia
Formaldehyde

7664-41-7
50-00 -0

0.1-1.0
<0.009

Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes
until irritation subsides. Get medical attention immediately.
First Aid - Skin Contact: Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical aid if
symptoms persist. If skin irritation persists, call a physician. Remove and wash contaminated clothing. In case of contact,
immediately flush skin with plenty of water while removing contaminated clothing and shoes.
First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If
continued breathing difficulty is experienced, get medical attention immediately.
First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately. If ingested, drink 2
glasses of water. Immediately see a physician. Never give anything by mouth to an unconscious person.
Note to Physician: None.
COMMENTS: If over-exposure occurs, call your local poison control center.

Section 5 - Fire Fighting Measures
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: No special protective measures against fire required.
Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or
equivalent) and full protective gear. Use water spray to cool exposed surfaces.

Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use
absorbent material or scrape up dried material and place in container.

Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Avoid breathing vapor and contact
with eyes, skin and clothing. Use only with adequate ventilation. Open all windows and doors or use other means to
ensure cross-ventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous
conditions. Wash thoroughly after handling.
Storage: Do not store at temperatures above 120 degrees F. Store containers away from excessive heat and freezing.
Close container after each use. Store away from caustics and oxidizers.

Section 8 - Exposure Controls / Personal Protection
Chemical Name

CASRN

ACGIH TWA

ACGIH STEL

ACGIH CEIL

Limestone

1317-65-3

10 MGM3

N.E.

N.E.

Branched and linear phthalates
Stoddard solvent
Ethylene glycol

Proprietary
8052-41-3
107-21-1

N.E.
100 PPM
N.E.

N.E.
N.E.
N.E.

N.E.
N.E.
100 MGM3

OSHA TWA
5 MGM3
(respirable
fraction)
N.E.
500 PPM
N.E.

OSHA STEL

OSHA CEIL

Skin

N.E.

N.E.

No

N.E.
N.E.
N.E.

N.E.
N.E.
N.E.

No
No
No

00010011605 English

Page 4 of 7

Silica, crystalline

14808-60-7

0.05 MGM3

N.E.

N.E.

Titanium dioxide
Ammonia
Formaldehyde

13463-67-7
7664-41-7
50-00-0

10 MGM3
25 PPM
N.E.

N.E.
35 PPM
N.E.

N.E.
N.E.
0.3 PPM

10/(%SiO2 + 2)
MGM3
15 MGM3
50 PPM
0.75 PPM

N.E.

N.E.

No

N.E.
N.E.
2 PPM

N.E.
N.E.
N.E.

No
No
No

Exposure Notes:
14808-60-7 The 2002 ACGIH Threshold Limit Values for Chemical Substances and Physical Agents lists the median
Respirable Particulate Mass (RPM) point for crystalline silica at 4.0 microns in terms of the particle's aerodynamic
diameter.
The TLVs for crystalline silica represent the respirable fraction.
OSHA PEL TWA for Quartz is calculated using the following formula: 10 mg/m3/(% SiO2 + 2). Both concentration and
percent quartz for the application of this limit are to be determined from the fraction passing a size selector with the
following characteristics.
|------------------------------------------------------------------------------------ |-----------------------------------------|
| ....... Aerodynamic diameter ( unit density sphere ) .....| Percent passing selector |
| 2 ................................................................................|.................90....................|
| 2.5 .............................................................................|..................75...................|
| 3.5 .............................................................................|..................50...................|
| 5.0 .............................................................................|..................25...................|
| 10 ..............................................................................|...................0....................|
50-00-0 Formaldehyde is a specially regulated substance for which an OSHA chemical-specific exposure standard exits.
Detailed information regarding this substance may be found in 29 CFR 1910.1048. Medical surveillance information
regarding this substance may be found in Appendix C to 29 CFR 1910.1048.
Precautionary Measures: Contact lenses pose a special hazard; soft lenses may absorb and all lenses concentrate
irritants.
Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Ensure adequate
ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient
concentrations below recommended exposure limits.
Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSH-approved air
purifying respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where
airborne concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA
1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.
National Institute for Occupational Safety and Health (NIOSH) has recommended that the permissible exposure limit be
changed to 50 micrograms respirable free silica per cubic meter of air (0.05 mg/m3) as determined by a full shift sample
up to 10-hour work shift.
Skin Protection: Rubber gloves. Natural rubber, butyl rubber and polyvinyl chloride gloves are not suitable protection
against the phthalates contained within this product; neoprene is recommended.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: Not required under normal use.
Hygienic Practices: Wash hands before breaks and at the end of workday. Remove and wash contaminated clothing
before re-use.
Important:

Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary
between states.

Note:

An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent
necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work
practices.

00010011605 English

Page 5 of 7

Section 9 - Physical And Chemical Properties
Boiling Range:
Odor:
Color:
Solubility in H2O:
Freeze Point:
Vapor Pressure:
Physical State:
Flash Point, F:

Not Established
Very Slight Ammonia
Colored
Not Established
Not Established
Not Established
Paste
Greater than 200 degrees
Fahrenheit
Lower Explosive Limit, %: Not Established

Vapor Density:
Odor Threshold:
Evaporation Rate:
Specific Gravity:
pH:
Viscosity:
Flammability:
Method:

Heavier Than Air
Not Established
Slower Than n-Butyl Acetate
1.6
Between 7.0 and 12.0
Not Established
Non-Flammable
(Seta Closed Cup)

Upper Explosive Limit, %:Not Established

When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally.
(See section 16 for abbreviation legend)

Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Incompatible with strong bases and oxidizing agents.
Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under recommended storage conditions.

Section 11 - Toxicological Information
Product LD50: Not Established
CASRN
107-21-1
7664-41-7
50-00-0

Chemical Name

Ethylene glycol
Ammonia
Formaldehyde

Product LC50: Not Established
LD50
Rat:4700 mg/kg
-------------------------

LC50
Rat:10876 mg/kg
Rat:2000 ppm/4H
Rat:203 mg/m3

Significant Data with Possible Relevance to Humans: This product contains trace amounts of free formaldehyde.
OSHA and NTP identify formaldehyde as a potential carcinogen. IARC identifies formaldehyde as a human carcinogen.
Formaldehyde has been shown to cause mutations in a variety of in-vitro test systems, the significance of which to
humans is unknown. There should be minimal risk when used with ventilation adequate to keep the atmospheric
concentration of formaldehyde below the recommended exposure limits.
Maintain adequate ventilation to prevent exposure above current OSHA / ACGIH exposure limits. Workplace monitoring of
the air to define formaldehyde exposure levels may be necessary.
In a two-year inhalation study, rats showed carcinogenic effects in the respiratory system at 15 ppm of formaldehyde.

Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.

Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local
regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is
with the owner of the waste.

00010011605 English

Page 6 of 7

EPA Waste Code if Discarded (40 CFR Section 261): None

Section 14 - Transportation Information
DOT Proper Shipping
Name:
DOT Technical Name:
DOT Hazard Class:

Not Regulated

Packing Group:

N.A.

N.A.
N.A.

Hazard Subclass:
DOT UN/NA Number:

N.A.
N.A.

Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may
apply if shipped via other modes of transportation and/or to non-domestic destinations.

Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of
the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable
definitions, to meet the following categories:
Immediate Health Hazard, Chronic Health Hazard
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
None
Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported
from the United States:
None
Canadian WHMIS:
This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings.
Canadian WHMIS Class: Not Controlled.

Section 16 - Other Information
HMIS Ratings:
Health: 1

Flammability: 1

Reactivity: 0

Volatile Organic Compounds (VOC), less water less exempts: g/L:

Personal Protection: X
56.0

Volatile Organic Compounds (VOC), less water less exempts, less LVP -VOCs:

lb/gal: 0.5

wt:wt%: 2.5

wt:wt%: 0.9

00010011605 English

Page 7 of 7

REASON FOR REVISION: Periodic Update
Legend:

N.A. – Not Applicable

ACGIH – American Conference of Governmental Industrial Hygienists

N.E. – Not Established

SARA – Superfund Amendments and Reauthorization Act of 1986

N.D. – Not Determined

NJRTK – New Jersey Right-to-Know Law

VOC – Volatile Organic Compound

OSHA – Occupational Safety and Health Administration

PEL – Permissible Exposure Limit

HMIS – Hazardous Materials Identification System

TLV – Threshold Limit Value

NTP – National Toxicology Program

CEIL – Ceiling Exposure Limit

STEL – Short Term Exposure Limit

LD50 – Lethal Dose 50

LC50 – Lethal Concentration 50

F – Degree Fahrenheit

MSDS – Material Safety Data Sheet

C – Degree Celsius

CASRN – The Chemical Abstracts Service Registry Number

DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this
document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained
person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context
of the intended use and (ii) determine if they are appropriate.


MATERIAL SAFETY DATA SHEET
WL30067
04 00
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER
DATE OF PREPARATION
HMIS CODES
Health
WL30067
15-MAY-08
Flammability
Reactivity
PRODUCT NAME
WHITE LIGHTNING® 3006™ Original Formula All Purpose Adhesive Caulk,
Clear

1
0
0

MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS CO.
Consumer Group - Industrial
Cleveland, OH 44115
TELEPHONE NUMBERS and WEBSITES
Regulatory Information
(216) 566-2902
www.paintdocs.com
Medical Emergency
(216) 566-2917
Transportation Emergency
for Chemical Emergency ONLY (spill, leak,
(800) 424-9300
fire, exposure, or accident)
Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
No ingredients in this product are hazardous as defined by the
Department of Labor.
Section 3 -- HAZARDS IDENTIFICATION
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
In a confined area vapors in high concentration may cause headache,
nausea or dizziness.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.

Continued on page 2

WL30067

page 2

Section 4 -- FIRST AID MEASURES
EYES:
SKIN:
INHALATION:
INGESTION:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
Do not induce vomiting.
Get medical attention immediately.

Section 5 -- FIRE FIGHTING MEASURES
FLASH POINT
LEL
UEL
Not Applicable
N.A.
N.A.
FLAMMABILITY CLASSIFICATION
Not Applicable
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Alcohol Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers may explode (due to the build-up of pressure) when
exposed to extreme heat.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.
Section 6 -- ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
Section 7 -- HANDLING AND STORAGE
STORAGE CATEGORY
Not Applicable
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep container closed when not in use. Transfer only to approved
containers with complete and appropriate labeling. Do not take internally.
Keep out of the reach of children.

Continued on page 3

WL30067

page 3

Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
Removal of old paint by sanding, scraping or other means may generate
dust or fumes that contain lead. Exposure to lead dust or fumes may cause
brain damage or other adverse health effects, especially in children or
pregnant women. Controlling exposure to lead or other hazardous substances
requires the use of proper protective equipment, such as a properly fitted
respirator (NIOSH approved) and proper containment and cleanup. For more
information, call the National Lead Information Center at 1-800-424-LEAD
(in US) or contact your local health authority.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
Wear gloves which are recommended by glove supplier for protection
against materials in Section 2.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT WEIGHT
8.77 lb/gal
1050 g/l
SPECIFIC GRAVITY
1.06
BOILING POINT
212 - 213 F
100 - 100 C
MELTING POINT
Not Available
VOLATILE VOLUME
51 %
EVAPORATION RATE
Slower than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
8.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
0.26 lb/gal
31 g/l
Less Water and Federally Exempt Solvents
0.13 lb/gal
15 g/l
Emitted VOC

Continued on page 4

WL30067

page 4

Section 10 -- STABILITY AND REACTIVITY
STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
Section 11 -- TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
TOXICOLOGY DATA
CAS No.
Ingredient Name
No LC50 or LD50 data available.
Section 12 -- ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
No data available.
Section 13 -- DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
Waste from this product is not hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Incinerate in approved facility. Do not incinerate closed container.
Dispose of in accordance with Federal, State/Provincial, and Local
regulations regarding pollution.
Section 14 -- TRANSPORT INFORMATION
US Ground (DOT)
Not Regulated for Transportation.
Canada (TDG)
Not Regulated for Transportation.
IMO
Not Regulated for Transportation.
Section 15 -- REGULATORY INFORMATION
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION

Continued on page 5

WL30067

page 5

CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
No ingredients in this product are subject to SARA 313 (40 CFR 372.65C)
Supplier Notification.
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
Section 16 -- OTHER INFORMATION
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

MATERIAL SAFETY DATA SHEET
WL01010
05 00
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER
DATE OF PREPARATION
HMIS CODES
Health
WL01010
19-JUN-08
Flammability
Reactivity
PRODUCT NAME
WHITE LIGHTNING® 3006™ Original Formula All Purpose Adhesive Caulk,
Almond

2*
0
0

MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS CO.
Consumer Group - Industrial
Cleveland, OH 44115
TELEPHONE NUMBERS and WEBSITES
Regulatory Information
(216) 566-2902
www.paintdocs.com
Medical Emergency
(216) 566-2917
Transportation Emergency
for Chemical Emergency ONLY (spill, leak,
(800) 424-9300
fire, exposure, or accident)
% by WT
1
59

0.8

Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
64742-88-7 Mineral Spirits
ACGIH TLV
100 ppm
2 mm
OSHA PEL
100 ppm
471-34-1 Calcium Carbonate
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
15 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction
13463-67-7 Titanium Dioxide
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction

Section 3 -- HAZARDS IDENTIFICATION
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
In a confined area vapors in high concentration may cause headache,
nausea or dizziness.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver and urinary systems.
Continued on page 2

WL01010

page 2

SIGNS AND SYMPTOMS OF OVEREXPOSURE
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
Section 4 -- FIRST AID MEASURES
EYES:
SKIN:
INHALATION:
INGESTION:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
Do not induce vomiting.
Get medical attention immediately.

Section 5 -- FIRE FIGHTING MEASURES
FLASH POINT
LEL
UEL
Not Applicable
N.A.
N.A.
FLAMMABILITY CLASSIFICATION
Not Applicable
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Alcohol Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers may explode (due to the build-up of pressure) when
exposed to extreme heat.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.
Section 6 -- ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
Section 7 -- HANDLING AND STORAGE
STORAGE CATEGORY
Not Applicable

Continued on page 3

WL01010

page 3

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep container closed when not in use. Transfer only to approved
containers with complete and appropriate labeling. Do not take internally.
Keep out of the reach of children.
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
Removal of old paint by sanding, scraping or other means may generate
dust or fumes that contain lead. Exposure to lead dust or fumes may cause
brain damage or other adverse health effects, especially in children or
pregnant women. Controlling exposure to lead or other hazardous substances
requires the use of proper protective equipment, such as a properly fitted
respirator (NIOSH approved) and proper containment and cleanup. For more
information, call the National Lead Information Center at 1-800-424-LEAD
(in US) or contact your local health authority.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
Wear gloves which are recommended by glove supplier for protection
against materials in Section 2.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT WEIGHT
SPECIFIC GRAVITY
BOILING POINT
MELTING POINT
VOLATILE VOLUME
EVAPORATION RATE
VAPOR DENSITY
SOLUBILITY IN WATER
pH

Continued on page 4

13.70 lb/gal
1641 g/l
1.65
212 - 395 F
100 - 201 C
Not Available
27 %
Slower than ether
Heavier than air
N.A.
8.0

WL01010

page 4

VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
0.38 lb/gal
46 g/l
Less Water and Federally Exempt Solvents
0.29 lb/gal
35 g/l
Emitted VOC
Section 10 -- STABILITY AND REACTIVITY
STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
Section 11 -- TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
TOXICOLOGY DATA
CAS No.
Ingredient Name
64742-88-7
Mineral Spirits
LC50
RAT
4HR
LD50
RAT
471-34-1
Calcium Carbonate
LC50
RAT
4HR
LD50
RAT
13463-67-7
Titanium Dioxide
LC50
RAT
4HR
LD50
RAT

Not Available
Not Available
Not Available
Not Available
Not Available
Not Available

Section 12 -- ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
No data available.
Section 13 -- DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
Waste from this product is not hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Incinerate in approved facility. Do not incinerate closed container.
Dispose of in accordance with Federal, State/Provincial, and Local
regulations regarding pollution.

Continued on page 5

WL01010

page 5

Section 14 -- TRANSPORT INFORMATION
US Ground (DOT)
Not Regulated for Transportation.
Canada (TDG)
Not Regulated for Transportation.
IMO
Not Regulated for Transportation.
Section 15 -- REGULATORY INFORMATION
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
No ingredients in this product are subject to SARA 313 (40 CFR 372.65C)
Supplier Notification.
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
Section 16 -- OTHER INFORMATION
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

Material Safety Data Sheet
Section 1

General Information

Manufacturer:
Zinsser Company, Inc.
173 Belmont Drive
Somerset, NJ 08875
(732) 469-8100
Emergency Telephone:
Product Name:
Codes:

Chemtrec (800) 424-9300

Date: December 1, 2006

Cover Stain Spray

03608 03610 03615 03616 03620 03624 03640

Section 2

Hazardous Ingredients

Hazardous Component

CAS#

Acetone
Aliphatic Petroleum Distillates
Kaolin
Limestone
Propane
Talc
Titanium dioxide
VM&P Naphtha

67-64-1
64742-89-8
1332-58-7
1317-65-3
74-98-6
14807-96-6
13463-67-7
8032-32-4

OSHA
PEL

ACGIH
TLV

1000 ppm
500 ppm
15 mg/m3 (5 mg/m3 *)
15 mg/m3 (5 mg/m3 *)
1000 ppm
20 mppcf
15 mg/m3
500 ppm

500 ppm
N/E
2 mg/m3*
3
10 mg/m (3 mg/m3 *)
1000 ppm
10 mg/m3 = (3 mg/m3)
10 mg/m3
300 ppm

* Respirable Dust Fraction

Section 3

Hazard Identification

Emergency Overview:
This material is an aerosol spray coating used as a primer/sealer.
The aerosol container is pressurized and extremely flammable. As packaged, this material has a
flashpoint of less than 32° F.
Primary Routes of Exposure:
Inhalation
Skin Contact
Eye Contact
Potential Acute Health Effects:
Eye:

May cause eye irritation.

Skin: Prolonged contact may cause skin irritation.
N/A: Not Applicable

N/D: Not Determined

N/E: Not Established

MSDS Code: Cover Stain Spray MSDS (12-1-06)

N/R: Not Required
Page 1 of 6 pages.

Est.: Estimated

Ingestion:
Although ingestion is not anticipated route of exposure, this material can be
harmful if swallowed. It may cause depression of the central nervous system, nausea, and
vomiting.
Inhalation:
irritation.

May cause headache, drowsiness, dizziness, nausea, and respiratory tract

Potential Chronic Health Effects: None known.
(See also Sections 4, 8, and 11 for related information)

Section 4

First Aid Measures

Eye contact: Flush eyes with water for 15 minutes.
Skin contact: Wash affected area with soap and water.
Ingestion:

Call a physician or poison control center.

Inhalation: Remove person to fresh air. Contact physician or poison control center if
symptoms persist.

Section 5

Fire Fighting Measures

Flash Point (method):

< 32° F (< 0° C)

Extinguishing Media:

Foam, CO2, dry chemical, water fog.

Protection of Firefighters: As in any fire, wear NIOSH approved self-contained breathing
apparatus in pressure-demand mode and full protective gear.
Fire and Explosion Hazards:
if exposed to heat (fire).

Section 6

Contents under pressure. Containers can build up pressure

Accidental Release Measures

Personal Precautions:
Use with adequate ventilation. Avoid breathing vapors. Avoid
contact with eyes and skin. Do not eat, drink or smoke in areas of use or storage.
Clean Up Methods: Dispose of in accordance with federal, state, local, regulations.
(See also Section 8 for information on Exposure Controls and Personal Protective Equipment)

N/A: Not Applicable

N/D: Not Determined

N/E: Not Established

MSDS Code: Cover Stain Spray MSDS (12-1-06)

N/R: Not Required
Page 2 of 6 pages.

Est.: Estimated

Section 7

Handling and Storage

Handling:
Keep away from heat, spark, and flame. Keep operating temperatures below
ignition temperatures at all times. Use only in a well-ventilated area.
Storage:
Store at ambient or lower temperature. Keep containers tightly closed and upright
when not in use. Protect against physical damage. Contents under pressure. Do not expose to
heat.

Section 8

Exposure Controls / Personal Protection

Engineering Controls:
Local exhaust ventilation may be necessary to control vapors
within applicable exposure limits.

Personal Protective Equipment (PPE):
Eye Protection:
contact.

Wear safety glasses, splash goggles, or full face shield to prevent eye

Skin Protection:

Wear rubber gloves to prevent skin contact.

Respiratory Protection:
Use NIOSH approved respirator with organic vapor cartridges if
vapor levels exceed allowable workplace exposure limits.
General Hygiene Practices: Wash thoroughly after handling. Prevent Eye contact. Avoid
prolonged skin or inhalation contact.

Section 9

Physical Data

Appearance:

White aerosol mist.

Odor: Hydrocarbon type odor.

Physical State:

Spray mist

pH:

Boiling Point:

N/D

Melting Point:

N/D

Vapor Pressure:

N/D

Vapor Density:

Greater than air

Odor Threshold:

N/D

Viscosity:

N/D

Solubility in Water: N/D

Section 10
Stability:

N/A

Specific Gravity (water = 1):

0.9

Stability and Reactivity

Stable, non-reactive.

N/A: Not Applicable

N/D: Not Determined

N/E: Not Established

MSDS Code: Cover Stain Spray MSDS (12-1-06)

N/R: Not Required
Page 3 of 6 pages.

Est.: Estimated

Hazardous Polymerization:

Will not occur.

Hazardous Decomposition Products:
Conditions to Avoid:

None known.

Heat, sparks, and open flames.

Section 11

Toxicological Information

Carcinocenicity:
This material is not considered a carcinogen by IARC or NTP and is not
regulated as a carcinogen by OSHA.
(See also Section 15 for related information)

Section 12

Ecological Information

Chemical Fate and Effects: No data available.

Section 13

Disposal Considerations

RCRA Hazardous Waste: This material, when discarded or disposed of, could be a hazardous
waste according to federal regulations (40 CFR 261) due to the characteristic of ignitability
(D001). The transportation, storage, treatment, and disposal of this waste must be conducted in
compliance with 40 CFR 262, 263, 264, 268, and 270. Disposal can only occur in properly
permitted facilities. Check state and local regulations for any additional requirements as these
may be more restrictive than federal laws and regulations. Chemical additions, processing or
otherwise altering this material may make the waste management information presented in this
MSDS incomplete, inaccurate, or otherwise inappropriate.

Section 14
Regulated by the DOT:

Transportation Information
Yes

DOT Proper Shipping Name:
UN / NA Number:

Paint

UN 1950

Section 15

Regulatory Information

CERCLA:
The Comprehensive Environmental Response Compensation and Liability Act of 1980 (CERCLA)
requires notification to the National Response Center for releases of quantities of Hazardous Substances
equal to or greater than the reportable quantities (RQs) in 40 CFR 302.4 (for CERCLA 102).

N/A: Not Applicable

N/D: Not Determined

N/E: Not Established

MSDS Code: Cover Stain Spray MSDS (12-1-06)

N/R: Not Required
Page 4 of 6 pages.

Est.: Estimated

Components present in this product at a level which could require reporting under the statute are:
Chemical Name
None

CAS#
N/A

Maximum Concentration (Wt. %)
N/A

SARA Title III, section 311/312:
The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires emergency
planning based on Threshold Planning Quantities (TPQs) and release reporting based on Reportable
Quantities (RQs) in 40 CFR 355 (used for SARA 302, 304, 311 and 312).
Components present in this product at a level which could require reporting under the statute are:
Chemical Name
None

CAS#
N/A

Maximum Concentration (Wt. %)
N/A

SARA Title III, section 313:
The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires submission of
annual reports of release of toxic chemicals that appear in 40 CFR 372 (for SARA 313).
Components present in this product at a level which could require reporting under the statute are:
Chemical Name
None

CAS#
N/A

Maximum Concentration (Wt. %)
N/A

TSCA:
The components of this mixture are listed in the Toxic Substance Control Act Inventory of
Chemical Substances.
This product contains the following chemicals which require export notification under section
12(b) of the TSCA regulation:
Chemical Name
Acetone
Methyl ethyl ketoxime

Section 16

CAS#
67-64-1
96-29-7

TSCA Section
Sec. 4
Sec. 4

Other Information

Legend: N/A: Not Applicable

N/D: Not Determined
N/E: Not Established
N/R: Not Required
STEL: Short Term Exposure Limit
C: OSHA Ceiling Value
cps: Centipoise
mg/m3: milligrams per cubic meter
mppcf: million particles per cubic foot of air. PPM: Parts Per Million
PPB: Parts Per Billion
PEL: Permissible Exposure Limit
TLV: Threshold Limit Value
TWA: Time Weighted Average
ACGIH: American Conference of Governmental Industrial Hygienists

N/A: Not Applicable

N/D: Not Determined

N/E: Not Established

MSDS Code: Cover Stain Spray MSDS (12-1-06)

N/R: Not Required
Page 5 of 6 pages.

Est.: Estimated

CPSC: Consumer Product Safety Commission
DOT: US Department of Transportation
FHSA: Federal Hazardous Substance Act
OSHA: Occupational Safety and Health Administration (US Dept. of Labor)
RCRA: Resource Conservation and Recovery Act
SARA: Superfund Amendment and Reauthorization Act
Skin: This substance has the potential to be absorbed systemically through the skin.
TSCA: Toxic Substance Control Act
Prepared By: Zinsser Health and Safety Manager, Regulatory Compliance Dept.
173 Belmont Drive Somerset, NJ 08875
(732) 469-8100
Disclaimer: Zinsser Company, Inc. believes, to the best of its knowledge, information and
belief, the information contained herein to be accurate and reliable as of the date of this material
safety data sheet. However, because the conditions of handling, use, and storage of these
materials are beyond our control, we assume no responsibility or liability for personal injury or
property damage incurred by the use of these materials and make no warranty, expressed or
implied, regarding the accuracy or reliability of the data or results obtained from their use. All
materials may present unknown hazards and should be used with caution. The information and
recommendations in this material safety data sheet are offered for the users’ consideration and
examination. It is the responsibility of the user to determine the final suitability of this
information and data and to comply with all applicable international, federal, state, and local
laws and regulations.

N/A: Not Applicable

N/D: Not Determined

N/E: Not Established

MSDS Code: Cover Stain Spray MSDS (12-1-06)

N/R: Not Required
Page 6 of 6 pages.

Est.: Estimated

Material Safety Data Sheet
Section 1

General Information

Manufacturer:
Zinsser Company, Inc.
173 Belmont Drive
Somerset, NJ 08875
(732) 469-8100
Emergency Telephone: Chemtrec (800) 424-9300
Product Name:
Codes:

Zinsser Magic Strip

42072

Section 2

42074

Hazardous Ingredients

Hazardous Component
Clay
Talc
Quartz
N-Methyl-2-Pyrrolidone

Section 3

Date: February 5, 2007

CAS#
1332-58-7
14807-96-6
14808-60-7
872-50-4

OSHA
PEL

ACGIH
TLV

2mg/m3
2mg/m3
5 mg/m3

10mg/m3
2mg/cm
10 mg/m3

NE

NE

Hazard Identification

Emergency Overview:
This material may cause eye, skin, nose, and throat irritation and may be
harmful if inhaled. This material is a paint stripper. It is a green colored liquid with a mild amine type
odor and flash pint greater than 200° F.
Primary Routes of Exposure:
Skin Contact
Eye Contact
Inhalation
Potential Acute Health Effects:
Eye:
May cause eye irritation. Direct contact with the liquid or exposure to vapors or mists may
cause stinging, tearing, redness, swelling, and eye damage.

N/A: Not Applicable

N/D: Not Determined

Zinsser Magic Strip (2-05-07)

N/E: Not Established

N/R: Not Required

Est.: Estimated

Page 1 of 7 pages.

Skin:
May cause skin irritation. Prolonged or repeated contact may cause skin to become
reddened, rough and dry due to the removal of natural oils and may result in dermatitis. May be
harmful if absorbed through the skin.
Ingestion: This material may be harmful if swallowed. Ingestion may cause gastrointestinal
irritation, nausea, vomiting and diarrhea.
Inhalation: Do not breathe vapor or spray mist Inhalation may cause respiratory tract irritation.
Breathing high concentrations of vapors or mists may affect the brain or central nervous system causing
dizziness, headaches, nausea, and drowsiness. Respiratory symptoms associated with preexisting lung
disorders (e.g. asthma-like conditions) may be aggravated by exposure to this material.
Potential Chronic Health Effects:
Signs and Symptoms:
Prolonged or repeated skin contact may cause dermatitis. Persons
with pre-existing skin disorders or impaired liver, kidney, and pulmonary function may be more
susceptible to the effects of this material.
(See also Sections 4, 8, and 11for related information)

Section 4

First Aid Measures

Eye contact: In case of eye contact, immediately flush eyes with plenty of water for at least 15
minutes. Get medical attention immediately.
Skin contact: In case of skin contact, wash thoroughly with soap and water for at least 15 minutes. Get
medical attention immediately. Remove contaminated clothing and shoes.
Ingestion:
If swallowed, contact a physician or poison control center immediately. DO NOT
induce vomiting unless directed to do so by medical personnel. May cause irritation of the
gastrointestinal tract with vomiting.
Inhalation: If you experience difficulty in breathing, leave the area to obtain fresh air. If
continued difficulty is experienced, get medical attention immediately.

Section 5

Fire Fighting Measures

Flash Point (method):

N/D (estimated greater than 200° F)

Extinguishing Media:

Water, CO2, foam, dry chemical or water supply.

Protection of Firefighters: As in any fire, wear self-contained breathing apparatus in pressure demand
mode and full protective gear.
Unusual Fire and Explosion Hazards:

N/A: Not Applicable

N/D: Not Determined

Zinsser Magic Strip (2-05-07)

None known.

N/E: Not Established

N/R: Not Required

Est.: Estimated

Page 2 of 7 pages.

Section 6

Accidental Release Measures

Clean Up Methods:
Keep unnecessary people away. Dike and contain spill with inert
material (sand, earth, etc.). Transfer liquid to containers for recovery or disposal, or absorb with
absorbent materials and place into containers for disposal. Keep spill out of sewer and open
bodies of water. Prevent runoff to sewers, streams or other bodies of water. Floors may be
slippery; care should be exercised to avoid falls during clean up operations.
Spillage:
If spilled, contain spilled material and remove with inert absorbent. Dispose of
contaminated absorbent, container and unused contents in accordance with local, state and federal
regulations. Clean up rags, papers and waste promptly. Allow solvent to evaporate then dispose of in
metal container. Call your local sanitation department for aid in disposing of unwanted product in your
area or call the Environmental Protection Agency Solvent and Hazardous Waste Hotline at 1-800-4249345. Do not dump on the ground or in local sewer of discharge system.
(See also Section 8 for information on Exposure Controls and Personal Protective Equipment and Section 13 for Disposal
information.)

Section 7

Handling and Storage

Handling:
Open containers carefully and close after each use. Do not get in eyes, on skin or on
clothing. Do not breathe vapors or spray mist. Wash thoroughly after handling. Wash clothing before
reuse. Thoroughly clean contaminated shoes. Do not use pressure to empty containers. Containers, even
those that have been emptied; will retain product residue and vapors. Always obey hazard warnings and
handle empty containers as if they were full. Use this product outdoors, if possible. If you must use it
indoors, open all windows and doors or use other means to ensure fresh air movement during application
and drying. Ensure fresh air entry during application and drying. Prevent the build-up of vapors by
opening windows and doors to achieve cross-ventilation.
Storage:
Store in a cool, dry, well-ventilated place away from incompatible materials.
Keep containers tightly closed when not in use. Vapors of this product are heavier than air and
will collect in low places, such as pits or degreasers or other poorly ventilated areas. Do not
enter places where vapors are suspected unless special respirator protection is worn and an
observer is present. Do not store near oxidizers, strong acids or bases. KEEP OUT OF REACH
OF CHILDREN.
(See also Section 8 for information on Exposure Controls and Personal Protective Equipment)

Section 8

Exposure Controls / Personal Protection

Engineering Controls:
Use in well-ventilated are and ensure good cross ventilation during use
and while drying. If necessary, use mechanical local exhaust ventilation or general room dilution
ventilation to reduce vapor concentrations.
WARNING! If you scrape, sand, or remove old paint, you may release lead dust. LEAD IS TOXIC.
EXPOSURE TO LEAD DUST CAN CAUSE SERIOUS ILLNESS, SUCH AS BRAIN DAMAGE,
N/A: Not Applicable

N/D: Not Determined

Zinsser Magic Strip (2-05-07)

N/E: Not Established

N/R: Not Required

Est.: Estimated

Page 3 of 7 pages.

ESPECIALLY IN CHILDREN. PREGNANT WOMEN SHOULD ALSO AVOID EXPOSURE. Wear a
NIOSH-approved respirator to control lead exposure. Clean up carefully with a HEPA vacuum and a
wet mop. Before you start, find out how to protect yourself and your family by contacting the National
Lead Information Hotline at 1-800-424-LEAD or log on to www.epa.gov/lead.
Personal Protective Equipment (PPE)
Eye Protection:
Do not get in eyes. Wear chemical splash goggles or similar eye protection if the
potential exists for eye contact
Skin Protection:
Prevent skin contact. It is recommended that PVA, rubber or other impermeable,
chemically resistant gloves be worn to prevent skin contact. Depending on conditions of use additional
protective equipment may be necessary such as face-shield, apron or coveralls.
Respiratory Protection:
If you experience eye watering, headache or dizziness or if air monitoring
demonstrates vapor/mist levels exceed applicable occupational exposure limits, wear an appropriate,
properly fitted respirator (NIOSH approved) during and after application. Follow respirator
manufacturer’s directions for respirator use. For emergency or non-routine operations involving high
vapor concentrations (such as enclosed areas) supplied air breathing apparatus (such as an airline
respirator or SCBA) may be required.
Protective Clothing:

Wear chemical-resistant gloves, boots, and aprons to prevent skin contact.

General Hygiene Practices:
Wash after handling material. Prevent eye and skin contact. Wash
thoroughly before handling food, cosmetics, or before smoking.

Section 9

Physical Data

Appearance: Green

Odor: Mild amine type

Physical State: liquid

pH:

Boiling Point: 212oF

Melting Point: N/A

Vapor Pressure: 0.2 mmHg @ 20°C

Vapor Density: Heavier than air.

Viscosity:

Solubility in Water: Miscible

N/D

N/A

Specific Gravity (water = 1): 1.31

Section 10
Stability:

Stability and Reactivity

Stable

Hazardous Polymerization:

N/A

Hazardous Decomposition Products:
N/A: Not Applicable

N/D: Not Determined

Zinsser Magic Strip (2-05-07)

CO2, CO, release when heated.
N/E: Not Established

N/R: Not Required

Est.: Estimated

Page 4 of 7 pages.

Incompatibility:

Avoid contact with oxidizing agents, strong acids or bases.

Section 11

Toxicological Information

Carcinogenicity:
Ingredients listed below are present at or greater than 0.1% and are classified by
either IARC, NTP, or OSHA as carcinogenic:
Ingredient

CAS #

Quartz

14808-60-7

Target Organs Effected:
upon human reproduction.

IARTC

NTP

OSHA

Yes

Yes

No

Animal tests indicate that N-Methyl-2-Pyrrolidone may cause toxic effects

NOTICE: Reports have associated repeated and prolonged occupational overexposure to
solvents with permanent brain and nervous system damage. Intentional misuse by deliberately
concentrating and inhaling the contents may be harmful or fatal.

Section 12

Ecological Information

Chemical Fate and Effects:

Section 13

None known.

Disposal Considerations

Recommended Waste Disposal Method: This material, when discarded or disposed of, could be a
hazardous waste according to federal regulations (40 CFR 261) due to the characteristic of ignitability
(D001). The transportation, storage, treatment, and disposal of this waste must be conducted in
compliance with 40 CFR 262, 263, 264, 268, and 270. Disposal can only occur in properly permitted
facilities. Check state and local regulations for any additional requirements as these may be more
restrictive than federal laws and regulations. Chemical additions, processing or otherwise altering this
material may make the waste management information presented in this MSDS incomplete, inaccurate,
or otherwise inappropriate

Section 14

Transportation Information

Regulated by the DOT:

No

DOT Proper Shipping Name:
UN / NA Number:

Not Applicable

DOT Hazard Class:
DOT Packing Group:

N/A: Not Applicable

Not Applicable

Not Applicable
Not Applicable

N/D: Not Determined

Zinsser Magic Strip (2-05-07)

N/E: Not Established

N/R: Not Required

Est.: Estimated

Page 5 of 7 pages.

Section 15

Regulatory Information

CERCLA:
The Comprehensive Environmental Response Compensation and Liability Act of 1980 (CERCLA) requires
notification to the National Response Center for releases of quantities of Hazardous Substances equal to or greater
than the reportable quantities (RQs) in 40 CFR 302.4 (for CERCLA 102).
Components present in this product at a level which could require reporting under the statute are:
Chemical Name
None

CAS#
N/A

Maximum Concentration (Wt. %)
N/A

SARA Title III, section 311/312:
The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires emergency planning
based on Threshold Planning Quantities (TPQs) and release reporting based on Reportable Quantities (RQs) in 40
CFR 355 (used for SARA 302, 304, 311 and 312).
Components present in this product at a level which could require reporting under the statute are:
Chemical Name

CAS#

Maximum Concentration (Wt. %)

None

N/A

N/A

SARA Title III, section 313:
The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires submission of annual
reports of release of toxic chemicals that appear in 40 CFR 372 (for SARA 313).
Components present in this product at a level which could require reporting under the statute are:
Chemical Name
N-Methyl-2-Pyrrolidone

CAS#
872-50-4

Maximum Concentration (Wt. %)
9%

TSCA:
The components of this mixture are listed in the Toxic Substance Control Act Inventory of Chemical
Substances.
This product does not contain any chemicals that require export notification under Section 12(b) of the
TSCA regulation.

Section 16

Other Information

Legend: N/A: Not Applicable
N/E: Not Established
cps: Centipoise
STEL: Short Term Exposure Limit
PPM: Parts Per Million
N/A: Not Applicable

N/D: Not Determined

Zinsser Magic Strip (2-05-07)

N/D: Not Determined
N/R: Not Required
KU: Krebs Units
C: OSHA Ceiling Value
PPB: Parts Per Billion

N/E: Not Established

N/R: Not Required

Est.: Estimated

Page 6 of 7 pages.

PEL: Permissible Exposure Limit
TLV: Threshold Limit Value
TWA: Time Weighted Average
mg/m3: Milligrams per cubic Meter
mppcf: Million particles per cubic foot of air.
ACGIH: American Conference of Governmental Industrial Hygienists
OSHA: Occupational Safety and Health Administration (US Dept. of Labor)
RCRA: Resource Conservation and recovery Act
SARA: Superfund Amendment and Reauthorization Act
TSCA: Toxic Substance Control Act
FHSA: Federal Hazardous Substance Act
Prepared By:

Zinsser Health and Safety Manager, Regulatory Compliance Dept.
173 Belmont Drive
Somerset, NJ 08875
(732) 469-8100

Disclaimer:
Zinsser Co., Inc. believes, to the best of its knowledge, information and belief, the information
contained herein to be accurate and reliable as of the date of this material safety data sheet. However, because the
conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or
liability for personal injury or property damage incurred by the use of these materials and make no warranty,
expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All
materials may present unknown hazards and should be used with caution. The information and recommendations
in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of
the user to determine the final suitability of this information and data and to comply with all applicable
international, federal, state, and local laws and regulations.

N/A: Not Applicable

N/D: Not Determined

Zinsser Magic Strip (2-05-07)

N/E: Not Established

N/R: Not Required

Est.: Estimated

Page 7 of 7 pages.

MSDS

Page 1 of 7

View MSDS :

1

2

3

4

5

6

7

8

9

10 11 12 13 14 15 16

SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
NFPA
Product Name:

3

KILZ® Original Aerosol

0

1

MSDS Manufacturer Number: 1024

NA

Manufacturer Name:

Masterchem Industries LLC

Address:

3135 Old Highway M
Imperial, MO 63052-2834

General Phone Number:

(636) 942-2510

General Fax Number:

(636) 942-3663

Health Hazard 1

Customer Service Phone
Number:

(800) 325-3552

Fire Hazard

CHEMTREC:

For emergencies in the US, call CHEMTREC: 800-424-9300

REACTIVITY 0

Canutec:

In Canada, call CANUTEC: (613) 996-6666 (call collect)

MSDS Creation Date:

06/26/2006

Personal
Protection

MSDS Revision Date:

05/09/2007

*

HMIS

3

x

Chronic Health
Effects:

SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name

CAS#

Ingredient Percent

Silicate, mica

12001-26-2

10 - 30 by Weight

Rutile

1317-80-2

5 - 10 by Weight

Octanes, all isomers

No data

5 - 10 by Weight

Octanes, all isomers

Mixture

5-10 by Weight

Non-hazardous ingredients

N/A

1 - 5 by Weight

1-Nitropropane

108-03-2

1-5 by Weight
10-30 by Weight

Non-hazardous ingredients
Acetone

67-64-1

10-30 by Weight

Titanium dioxide

13463-67-7

10 - 30 by Weight

Carbonic acid calcium salt

471-34-1

10 - 30 by Weight

Propane

74-98-6

10-30 by Weight

Isobutane

75-28-5

10-30 by Weight

VM&P Naphtha/Aliphatic Hydrocarbon

8032-32-4

10 - 30 by Weight

Nonane, all isomers

Mixture

10-30 by Weight

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MSDS

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Nonanes

No data

10 - 30 by Weight

Talc, Magnesium silicate hydrate

14807-96-6

1 - 5 by Weight

Xylene

1330-20-7

0.1 - 1 by Weight

Palygorskite

12174-11-7

0.1 - 1 by Weight

SECTION 3 - HAZARDS IDENTIFICATION
Emergency Overview:

Flammable. Irritant.

Potential Health Effects:
Eye:

May cause irritation.

Skin:

May cause irritation.

Inhalation:

Prolonged or excessive inhalation may cause respiratory tract irritation.

Ingestion:

Harmful if swallowed. Ingestion can cause nausea, vomiting, diarrhea and
gastrointestinal irritation.

Chronic Health Effects:

Prolonged or repeated contact can result in defatting and drying of the skin,
which may result in skin irritation and dermatitis (rash).
Repeated or prolonged inhalation may cause toxic effects.

Signs/Symptoms:

Overexposure can cause headaches, dizziness, nausea, and vomiting.

Target Organs:

Eyes. Skin. Respiratory system. Digestive system. Central nervous system.
Kidney.

Aggravation of Pre-Existing
Conditions:

May aggravate pre-existing respiratory disorders, allergy, eczema, or skin
conditions.

SECTION 4 - FIRST AID MEASURES
Eye Contact:

Immediately flush eyes with plenty of water for 15 to 20 minutes. Get medical
attention, if irritation or symptoms of overexposure persists.

Skin Contact:

Immediately wash skin with soap and plenty of water. Get medical attention if
irritation develops or persists.

Inhalation:

If inhaled, remove to fresh air. If not breathing, give artificial respiration or give
oxygen by trained personnel. Seek immediate medical attention.

Ingestion:

If swallowed, do NOT induce vomiting. Call a physician or poison control center
immediately. Never give anything by mouth to an unconscious person.

Other First Aid:

Due to possible aspiration into the lungs, DO NOT induce vomiting if ingested.
Provide a glass of water to dilute the material in the stomach. If vomiting occurs
naturally, have the person lean forward to reduce the risk of aspiration.

SECTION 5 - FIRE FIGHTING MEASURES
Flammable Properties:

Flammable liquid.

Flash Point:

<32°F (<0°C)

Flash Point Method:
Lower Flammable/Explosive Limit: 1%
Upper Flammable/Explosive Limit: 7%
Fire Fighting Instructions:

Flammable. Cool fire-exposed containers using water spray.

Extinguishing Media:

Use alcohol foam, carbon dioxide, dry chemical, or water fog or spray when
fighting fires involving this material.

Protective Equipment:

As in any fire, wear self-contained breathing apparatus pressure-demand,
MSHA/NIOSH (approved or equivalent) and full protective gear.

Unusual Fire Hazards:

Flammable liquid. Vapors can form an ignitable mixture with air. Vapors can flow
along surfaces to a distant ignition source and flash back.

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NFPA Ratings:
NFPA Flammability:

3

NFPA Health:

1

NFPA Reactivity:

0

NFPA Other:

NA

SECTION 6 - ACCIDENTAL RELEASE MEASURES
Spill Cleanup Measures:

Remove all sources of ignition. Absorb spill with inert material (e.g., dry sand or
earth), then place in a chemical waste container. Provide ventilation. Collect spi
with a non-sparking tool. Place into a suitable container for disposal.

Personnel Precautions:

Use proper personal protective equipment as listed in section 8.

Environmental Precautions:

Avoid runoff into storm sewers, ditches, and waterways.

SECTION 7 - HANDLING and STORAGE
Handling:

Use with adequate ventilation. Avoid breathing vapor and contact with eyes, ski
and clothing. Material will accumulate static charges which may cause an
electrical spark (ignition source). Use proper grounding procedures.

Storage:

Store in a cool, dry, well ventilated area away from sources of heat, combustible
materials, and incompatible substances. Keep container tightly closed when not
in use.

Work Practices:

To reduce potential for static discharge, bond and ground containers when
transferring material.

Special Handling Procedures:

Do not reuse containers without proper cleaning or reconditioning.

Hygiene Practices:

Wash thoroughly after handling. Avoid contact with eyes and skin. Avoid inhalin
vapor or mist.

SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION - EXPOSURE GUIDELINES
Engineering Controls:

Use appropriate engineering control such as process enclosures, local exhaust
ventilation, or other engineering controls to control airborne levels below
recommended exposure limits. Good general ventilation should be sufficient to
control airborne levels. Where such systems are not effective wear suitable
personal protective equipment, which performs satisfactorily and meets OSHA o
other recognized standards. Consult with local procedures for selection, training
inspection and maintenance of the personal protective equipment.

Eye/Face Protection:

Wear appropriate protective glasses or splash goggles as described by 29 CFR
1910.133, OSHA eye and face protection regulation, or the European standard
EN 166.

Skin Protection Description:

Chemical-resistant gloves and chemical goggles, face-shield and synthetic apron
or coveralls should be used to prevent contact with eyes, skin or clothing.

Respiratory Protection:

A NIOSH approved air-purifying respirator with an organic vapor cartridge or
canister may be permissible under certain circumstances where airborne
concentrations are expected to exceed exposure limits. Protection provided by
air purifying respirators is limited. Use a positive pressure air supplied respirato
if there is any potential for an uncontrolled release, exposure levels are not
known, or any other circumstances where air purifying respirators may not
provide adequate protection.

Other Protective:

Facilities storing or utilizing this material should be equipped with an eyewash
facility and a safety shower.

EXPOSURE GUIDELINES

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Silicate, mica :
Guideline ACGIH:

TLV-TWA: 3 mg/m3 (Respirable)

Guideline OSHA:

OSHA-TWA: 20 mg/m3

1-Nitropropane :
Guideline ACGIH:

TLV-TWA: 25 ppm

Guideline OSHA:

OSHA-TWA: ppm

Acetone :
Guideline ACGIH:

TLV-TWA: 500 ppm
TLV-STEL: 750 ppm

Guideline OSHA:

OSHA-TWA: 1000 ppm

Titanium dioxide :
Guideline ACGIH:

TLV-TWA: 10 mg/m3

Guideline OSHA:

OSHA-TWA: 15 mg/m3

Carbonic acid calcium salt :
Guideline ACGIH:

TLV-TWA: 5 mg/m3 (Respirable)

Guideline OSHA:

OSHA-TWA: 5 mg/m3 Respirable

Propane :
Guideline ACGIH:

TLV-TWA: 1000 ppm

Guideline OSHA:

OSHA-TWA: 1000 ppm

Isobutane :
Guideline ACGIH:

TLV-TWA: 1000 ppm

VM&P Naphtha/Aliphatic Hydrocarbon :
Guideline ACGIH:

TLV-TWA: 300 ppm

Talc, Magnesium silicate hydrate :
Guideline ACGIH:

TLV-TWA: 2 mg/m3 (Respirable)

Guideline OSHA:

OSHA-TWA: 20 mg/m3

Xylene :
Guideline ACGIH:

TLV-TWA: 100 ppm
TLV-STEL: 150 ppm

Guideline OSHA:

OSHA-TWA: 100 ppm

SECTION 9 - PHYSICAL and CHEMICAL PROPERTIES
Physical State Appearance:

Liquid

Boiling Point:

No Data

Melting Point:

No Data

Density:

10 - 12 Lbs./gal.

Vapor Density:

Greater than 1 (Air = 1)

pH:

No Data

Molecular Formula:

Mixture

Molecular Weight:

Mixture

Flash Point:

<32°F (<0°C)

Flash Point Method:

SECTION 10 - STABILITY and REACTIVITY
Chemical Stability:

Stable under normal temperatures and pressures.

Hazardous Polymerization:

Not reported.

Conditions to Avoid:

Heat, flames, ignition sources, and sparks. Incompatible materials. Freezing or
temperatures below 32 deg. F.

Incompatible Materials:

Oxidizing agents. Strong acids and alkalis.

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MSDS

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SECTION 11 - TOXICOLOGICAL INFORMATION
RTECS Number:

VV8760000

RTECS Number:

VM2940000

Acetone :
Eye:

Eye - Rabbit; Standard Draize Test : 10 uL - mild (RTECS)

Skin:

Skin - Guinea pig; LD50: >9400 uL/kg - Details of toxic effects not reported
other than lethal dose value. (RTECS)

Inhalation:

Inhalation - Rat LC50: 50100 mg/m3/8H - [Details of toxic effects not reported
other than lethal dose value
Inhalation - Mouse LC50: 44 gm/m3/4H - Details of toxic effects not reported
other than lethal dose value. (RTECS)

Ingestion:

Ingestion - Rat LD50: 5800 mg/kg - Behavioral - altered sleep time (including
change in righting reflex) Behavioral - tremor
Ingestion - Mouse LD50: 3 gm/kg - [Details of toxic effects not reported other
than lethal dose value. (RTECS)

Titanium dioxide :
RTECS Number:

XR2275000

Skin:

Skin - Rabbit; Standard Draize Test : 300 ug/3D; (Intermittent) mild. (RTECS)

Ingestion:

Ingestion - Rat TDLo: 60 gm/kg; Gastrointestinal - hypermotility, diarrhea
Gastrointestinal - other changes. (RTECS)

Carcinogenicity:

IARC: Group 2B: Possibly carcinogenic to humans

RTECS Number:

FF9335000

Isobutane :
Inhalation:

Inhalation - Rat LC50: 570,000 ppm/15M - [Behavioral - tremor Behavioral convulsions or effect on seizure threshold Lungs, Thorax, or Respiration respiratory depression] (RTECS)

VM&P Naphtha/Aliphatic Hydrocarbon :
RTECS Number:

OI6180000

Eye:

Eye's - Human: 880 ppm/15M; No effects reported. (RTECS)

Talc, Magnesium silicate hydrate :
RTECS Number:

WW2710000

Carcinogenicity:

IARC: Group 3: Unclassifiable as to carcinogenicity to humans

Xylene :
RTECS Number:

ZE2100000

Eye:

Eye - Rabbit; Standard Draize Test : 87 mg; mild.
Eye - Rabbit; Standard Draize Test : 5 mg/24H; severe. (RTECS)

Skin:

Skin - Rabbit; Standard Draize Test : 100%; Moderate.
Skin - Rabbit; Standard Draize Test : 500 mg/24H; Moderate. (RTECS)

Inhalation:

Inhalation - Rat LC50: 5000 ppm/4H; Details of toxic effects not reported other
than lethal dose value (RTECS)

Ingestion:

Ingestion - Rat LD50: 4300 mg/kg; Liver - other changes Kidney, Ureter,
Bladder - other changes
Ingestion - Mouse LD50: 2119 mg/kg; Details of toxic effects not reported othe
than lethal dose value (RTECS)

Carcinogenicity:

IARC: Group 3: Unclassifiable as to carcinogenicity to humans

Palygorskite :
RTECS Number:

RT6400000

Carcinogenicity:

IARC: Group 2B: Possibly carcinogenic to humans

SECTION 12 - ECOLOGICAL INFORMATION
Ecotoxicity:

No ecotoxicity data was found for the product.

Environmental Fate:

No environmental information found for this product.

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MSDS

Page 6 of 7

SECTION 13 - DISPOSAL CONSIDERATIONS
Waste Disposal:

Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the
classifications of hazardous waste prior to disposal. Furthermore, consult with
your state and local waste requirements or guidelines, if applicable, to ensure
compliance. Arrange disposal in accordance to the EPA and/or state and local
guidelines.

Important Disposal Information:

DANGER! Rags, steel wool and waste soaked with this product may
spontaneously catch fire if improperly discarded or stored. To avoid a
spontaneous combustion fire, immediately after use, place rags, steel wool or
waste in a sealed, water-filled, metal container. Do not store unused product
inside the home. For disposal guidance, contact your household refuse collection
service, fire department, county or state government environmental control
agency.

SECTION 14 - TRANSPORT INFORMATION
DOT Shipping Name:

Aerosol flammable

DOT Hazard Class:

2.1

DOT Packing Group:

III

SECTION 15 - REGULATORY INFORMATION
Silicate, mica :
TSCA Inventory Status:

Not listed

State Regulations:

Listed in the New Jersey State Right to Know List.
Listed in the Pennsylvania State Hazardous Substances List.

Canada DSL:

Listed

Rutile :
TSCA Inventory Status:

Listed

State Regulations:

Listed in the Pennsylvania State Hazardous Substances List.

Canada DSL:

Listed

1-Nitropropane :
State Regulations:

Listed in the Pennsylvania State Hazardous Substances List..

Canada DSL:

Listed

Non-hazardous ingredients :
TSCA Inventory Status:

Contains calcium carbonate (CAS:1317-65-3), which is listed in the TSCA
inventory.

Acetone :
TSCA Inventory Status:

Listed

State Regulations:

Listed in the Pennsylvania State Hazardous Substances List.

Canada DSL:

Listed

Titanium dioxide :
TSCA Inventory Status:

Listed

State Regulations:

Listed in the New Jersey State Right to Know List.
Listed in the Pennsylvania State Hazardous Substances List.

Canada DSL:

Listed

Carbonic acid calcium salt :
Canada DSL:

Listed

Propane :
TSCA Inventory Status:

Listed

State Regulations:

Listed in the Pennsylvania State Hazardous Substances List.
Listed in the New Jersey State Right to Know List.

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Canada DSL:

Listed

Isobutane :
TSCA Inventory Status:

Listed

State Regulations:

Listed in the Pennsylvania State Hazardous Substances List.
Listed in the New Jersey State Right to Know List..

Canada DSL:

Listed

VM&P Naphtha/Aliphatic Hydrocarbon :
TSCA Inventory Status:

Listed

State Regulations:

Listed in the New Jersey State Right to Know List.
Listed in the Pennsylvania State Hazardous Substances List.

Canada DSL:

Listed

Talc, Magnesium silicate hydrate :
TSCA Inventory Status:

Listed

State Regulations:

Listed in the New Jersey State Right to Know List.
Listed in the Pennsylvania State Hazardous Substances List.

Canada DSL:

Listed

Xylene :
TSCA Inventory Status:

Listed

State Regulations:

Listed in the New Jersey State Right to Know List.
Listed in the Pennsylvania State Hazardous Substances List.

Canada DSL:

Listed

Palygorskite :
TSCA Inventory Status:

Not listed

Canada DSL:

Not listed

SECTION 16 - ADDITIONAL INFORMATION
HMIS Fire Hazard:

3

HMIS Health Hazard:

1

HMIS Reactivity:

0

HMIS Personal Protection:

x

MSDS Creation Date:

06/26/2006

MSDS Revision Date:

05/09/2007

MSDS Revision Notes:

Quarterly and format update

MSDS Author:

Actio Corporation

Disclaimer:

This Health and Safety Information is correct to the best of our knowledge and
belief at the date of its publication but we cannot accept liability for any loss,
injury or damage which may result from its use. We shall ensure, so far as is
reasonably practicable, that any revision of this Data Sheet is sent to all
customers to whom we have directly supplied this substance, but must point ou
that it is the responsibility of any intermediate supplier to ensure that such
revision is passed to the ultimate user. The information given in the Data Sheet
is designed only as a guidance for safe handling, storage and the use of the
substance. It is not a specification nor does it guarantee any specific properties.
All chemicals should be handled only by competent personnel, within a
controlled environment. Should further information be required, this can be
obtained through the sales office whose address is at the top of this data sheet.

Trademark:

The trademarks, service marks, graphics and logos used on this MSDS are
registered or unregistered trademarks of BEHR Process Corporation. All Rights
Reserved.
Copyright© 1996-2006 Actio Software Corporation. All Rights Reserved.

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MSDS

Page 1 of 8

View MSDS :

1

2

3

4

5

6

7

8

9

10 11 12 13 14 15 16

SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
NFPA
Product Name:

3

KILZ® Upshot

0

1

MSDS Manufacturer Number: 10007

NA

Manufacturer Name:

Masterchem Industries LLC

Address:

3135 Old Highway M
Imperial, MO 63052-2834

General Phone Number:

(636) 942-2510

General Fax Number:

(636) 942-3663

Health Hazard 1

Customer Service Phone
Number:

(800) 325-3552

Fire Hazard

CHEMTREC:

For emergencies in the US, call CHEMTREC: 800-424-9300

REACTIVITY 0

Canutec:

In Canada, call CANUTEC: (613) 996-6666 (call collect)

MSDS Creation Date:

07/15/2006

Personal
Protection

MSDS Revision Date:

05/09/2007

*

HMIS

3

x

Chronic Health
Effects:

SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name

CAS#

Ingredient Percent

Silicate, mica

12001-26-2

10 - 30 by Weight

Limestone (calcium carbonate)

1317-65-3

1-10 by Weight

Rutile

1317-80-2

5 - 10 by Weight

Octanes, all isomers

No data

5 - 10 by Weight

Nonanes

Mixture

1-10 by Weight

Non-hazardous ingredients

N/A

1 - 5 by Weight

Octanes, all isomers

Mixture

1-5 by Weight

1-Nitropropane

108-03-2

1-5 by Weight

Acetone

67-64-1

10-30 by Weight

Titanium dioxide

13463-67-7

10 - 30 by Weight

Carbonic acid calcium salt

471-34-1

10 - 30 by Weight

Propane

74-98-6

10-30 by Weight

Isobutane

75-28-5

10-30 by Weight

VM&P Naphtha/Aliphatic Hydrocarbon

8032-32-4

10 - 30 by Weight

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Nonanes

No data

10 - 30 by Weight

Talc, Magnesium silicate hydrate

14807-96-6

1 - 5 by Weight

Talc (powder), containing no asbestos fibers

14807-96-6

1-5 by Weight

Xylene

1330-20-7

0.1 - 1 by Weight

Palygorskite

12174-11-7

0.1 - 1 by Weight

SECTION 3 - HAZARDS IDENTIFICATION
Emergency Overview:

Flammable aerosol. Irritant. Contents under pressure.

Potential Health Effects:
Eye:

May cause irritation.

Skin:

May cause irritation.

Inhalation:

Prolonged or excessive inhalation may cause respiratory tract irritation.

Ingestion:

Harmful if swallowed. Ingestion can cause nausea, vomiting, diarrhea and
gastrointestinal irritation.

Chronic Health Effects:

Prolonged or repeated contact can result in defatting and drying of the skin,
which may result in skin irritation and dermatitis (rash).
Repeated or prolonged inhalation may cause toxic effects.

Signs/Symptoms:

Overexposure can cause headaches, dizziness, nausea, and vomiting.

Target Organs:

Eyes. Skin. Respiratory system. Digestive system. Central nervous system.
Kidney.

Aggravation of Pre-Existing
Conditions:

May aggravate pre-existing respiratory disorders, allergy, eczema, or skin
conditions.

SECTION 4 - FIRST AID MEASURES
Eye Contact:

Immediately flush eyes with plenty of water for 15 to 20 minutes. Get medical
attention, if irritation or symptoms of overexposure persists.

Skin Contact:

Immediately wash skin with soap and plenty of water. Get medical attention if
irritation develops or persists.

Inhalation:

If inhaled, remove to fresh air. If not breathing, give artificial respiration or give
oxygen by trained personnel. Seek immediate medical attention.

Ingestion:

If swallowed, do NOT induce vomiting. Call a physician or poison control center
immediately. Never give anything by mouth to an unconscious person.

Other First Aid:

Due to possible aspiration into the lungs, DO NOT induce vomiting if ingested.
Provide a glass of water to dilute the material in the stomach. If vomiting occurs
naturally, have the person lean forward to reduce the risk of aspiration.

SECTION 5 - FIRE FIGHTING MEASURES
Flammable Properties:

Flammable aerosol. Contents are under pressure. Will release flammable vapors
at well below ambient temperatures and readily form flammable mixtures with
air. It will burn in the open and may be explosive in confined spaces.

Flash Point:

<32°F (0°C)

Flash Point Method:

TOC

Fire Fighting Instructions:

Flammable. Cool fire-exposed containers using water spray.

Extinguishing Media:

Use alcohol foam, carbon dioxide, dry chemical, or water fog or spray when
fighting fires involving this material.

Protective Equipment:

As in any fire, wear self-contained breathing apparatus pressure-demand,
MSHA/NIOSH (approved or equivalent) and full protective gear.

Unusual Fire Hazards:

Flammable liquid. Vapors can form an ignitable mixture with air. Vapors can flow

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Page 3 of 8

along surfaces to a distant ignition source and flash back.

NFPA Ratings:
NFPA Flammability:

3

NFPA Health:

1

NFPA Reactivity:

0

NFPA Other:

NA

SECTION 6 - ACCIDENTAL RELEASE MEASURES
Spill Cleanup Measures:

Remove all sources of ignition. Absorb spill with inert material (e.g., dry sand or
earth), then place in a chemical waste container. Provide ventilation. Collect spi
with a non-sparking tool. Place into a suitable container for disposal.

Personnel Precautions:

Use proper personal protective equipment as listed in section 8.

Environmental Precautions:

Avoid runoff into storm sewers, ditches, and waterways.

SECTION 7 - HANDLING and STORAGE
Handling:

Use with adequate ventilation. Avoid breathing vapor and contact with eyes, ski
and clothing. Material will accumulate static charges which may cause an
electrical spark (ignition source). Use proper grounding procedures.

Storage:

Store in a cool, dry, well ventilated area away from sources of heat, combustible
materials, and incompatible substances. Keep container tightly closed when not
in use. Do not store in temperatures above 120 °F.

Work Practices:

To reduce potential for static discharge, bond and ground containers when
transferring material.

Special Handling Procedures:

Handle with care. Contents are under pressure. Excessive pressure and
temperature will cause over pressurization and result in container bursting or
exploding.

Hygiene Practices:

Wash thoroughly after handling. Avoid contact with eyes and skin. Avoid inhalin
vapor or mist.

SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION - EXPOSURE GUIDELINES
Engineering Controls:

Use appropriate engineering control such as process enclosures, local exhaust
ventilation, or other engineering controls to control airborne levels below
recommended exposure limits. Good general ventilation should be sufficient to
control airborne levels. Where such systems are not effective wear suitable
personal protective equipment, which performs satisfactorily and meets OSHA o
other recognized standards. Consult with local procedures for selection, training
inspection and maintenance of the personal protective equipment.

Eye/Face Protection:

Wear appropriate protective glasses or splash goggles as described by 29 CFR
1910.133, OSHA eye and face protection regulation, or the European standard
EN 166.

Skin Protection Description:

Chemical-resistant gloves and chemical goggles, face-shield and synthetic apron
or coveralls should be used to prevent contact with eyes, skin or clothing.

Respiratory Protection:

A NIOSH approved air-purifying respirator with an organic vapor cartridge or
canister may be permissible under certain circumstances where airborne
concentrations are expected to exceed exposure limits. Protection provided by
air purifying respirators is limited. Use a positive pressure air supplied respirato
if there is any potential for an uncontrolled release, exposure levels are not
known, or any other circumstances where air purifying respirators may not
provide adequate protection.

Other Protective:

Facilities storing or utilizing this material should be equipped with an eyewash
facility and a safety shower.

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EXPOSURE GUIDELINES
Silicate, mica :
Guideline ACGIH:

TLV-TWA: 3 mg/m3 (Respirable)

Guideline OSHA:

OSHA-TWA: 20 mg/m3

1-Nitropropane :
Guideline ACGIH:

TLV-TWA: 25 ppm

Guideline OSHA:

OSHA-TWA: ppm

Acetone :
Guideline ACGIH:

TLV-TWA: 500 ppm
TLV-STEL: 750 ppm

Guideline OSHA:

OSHA-TWA: 1000 ppm

Titanium dioxide :
Guideline ACGIH:

TLV-TWA: 10 mg/m3

Guideline OSHA:

OSHA-TWA: 15 mg/m3

Carbonic acid calcium salt :
Guideline ACGIH:

TLV-TWA: 5 mg/m3 (Respirable)

Guideline OSHA:

OSHA-TWA: 5 mg/m3 Respirable

Propane :
Guideline ACGIH:

TLV-TWA: 1000 ppm

Guideline OSHA:

OSHA-TWA: 1000 ppm

Isobutane :
Guideline ACGIH:

TLV-TWA: 1000 ppm

VM&P Naphtha/Aliphatic Hydrocarbon :
Guideline ACGIH:

TLV-TWA: 300 ppm

Talc, Magnesium silicate hydrate :
Guideline ACGIH:

TLV-TWA: 2 mg/m3 (Respirable)

Guideline OSHA:

OSHA-TWA: 20 mg/m3

Talc (powder), containing no asbestos fibers :
Guideline ACGIH:

TLV-TWA: 2 mg/m3 (Respirable)

Guideline OSHA:

OSHA-TWA: 20 mg/m3

Xylene :
Guideline ACGIH:

TLV-TWA: 100 ppm
TLV-STEL: 150 ppm

Guideline OSHA:

OSHA-TWA: 100 ppm

SECTION 9 - PHYSICAL and CHEMICAL PROPERTIES
Physical State Appearance:

Liquid

Boiling Point:

No Data

Melting Point:

No Data

Density:

10 - 12 Lbs./gal.

Vapor Density:

Greater than 1 (Air = 1)

pH:

No Data

Molecular Formula:

Mixture

Molecular Weight:

Mixture

Flash Point:

<32°F (0°C)

Flash Point Method:

TOC

SECTION 10 - STABILITY and REACTIVITY

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Chemical Stability:

Stable under normal temperatures and pressures.

Hazardous Polymerization:

Not reported.

Conditions to Avoid:

Heat, flames, ignition sources, and sparks. Incompatible materials. Freezing or
temperatures below 32 deg. F. Temperatures above 120 °F.

Incompatible Materials:

Oxidizing agents. Strong acids and alkalis.

SECTION 11 - TOXICOLOGICAL INFORMATION
RTECS Number:

VV8760000

RTECS Number:

VM2940000

Acetone :
Eye:

Eye - Rabbit; Standard Draize Test : 10 uL - mild (RTECS)

Skin:

Skin - Guinea pig; LD50: >9400 uL/kg - Details of toxic effects not reported
other than lethal dose value. (RTECS)

Inhalation:

Inhalation - Rat LC50: 50100 mg/m3/8H - [Details of toxic effects not reported
other than lethal dose value
Inhalation - Mouse LC50: 44 gm/m3/4H - Details of toxic effects not reported
other than lethal dose value. (RTECS)

Ingestion:

Ingestion - Rat LD50: 5800 mg/kg - Behavioral - altered sleep time (including
change in righting reflex) Behavioral - tremor
Ingestion - Mouse LD50: 3 gm/kg - [Details of toxic effects not reported other
than lethal dose value. (RTECS)

Titanium dioxide :
RTECS Number:

XR2275000

Skin:

Skin - Rabbit; Standard Draize Test : 300 ug/3D; (Intermittent) mild. (RTECS)

Ingestion:

Ingestion - Rat TDLo: 60 gm/kg; Gastrointestinal - hypermotility, diarrhea
Gastrointestinal - other changes. (RTECS)

Carcinogenicity:

IARC: Group 2B: Possibly carcinogenic to humans

RTECS Number:

FF9335000

Isobutane :
Inhalation:

Inhalation - Rat LC50: 570,000 ppm/15M - [Behavioral - tremor Behavioral convulsions or effect on seizure threshold Lungs, Thorax, or Respiration respiratory depression] (RTECS)

VM&P Naphtha/Aliphatic Hydrocarbon :
RTECS Number:

OI6180000

Eye:

Eye's - Human: 880 ppm/15M; No effects reported. (RTECS)

Talc, Magnesium silicate hydrate :
RTECS Number:

WW2710000

Carcinogenicity:

IARC: Group 3: Unclassifiable as to carcinogenicity to humans

Talc (powder), containing no asbestos fibers :
Carcinogenicity:

IARC: Group 3: Unclassifiable as to carcinogenicity to humans

Xylene :
RTECS Number:

ZE2100000

Eye:

Eye - Rabbit; Standard Draize Test : 87 mg; mild.
Eye - Rabbit; Standard Draize Test : 5 mg/24H; severe. (RTECS)

Skin:

Skin - Rabbit; Standard Draize Test : 100%; Moderate.
Skin - Rabbit; Standard Draize Test : 500 mg/24H; Moderate. (RTECS)

Inhalation:

Inhalation - Rat LC50: 5000 ppm/4H; Details of toxic effects not reported other
than lethal dose value (RTECS)

Ingestion:

Ingestion - Rat LD50: 4300 mg/kg; Liver - other changes Kidney, Ureter,
Bladder - other changes
Ingestion - Mouse LD50: 2119 mg/kg; Details of toxic effects not reported othe
than lethal dose value (RTECS)

Carcinogenicity:

IARC: Group 3: Unclassifiable as to carcinogenicity to humans

Palygorskite :
RTECS Number:

RT6400000

Carcinogenicity:

IARC: Group 2B: Possibly carcinogenic to humans

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SECTION 12 - ECOLOGICAL INFORMATION
Ecotoxicity:

No ecotoxicity data was found for the product.

Environmental Fate:

No environmental information found for this product.

SECTION 13 - DISPOSAL CONSIDERATIONS
Waste Disposal:

Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the
classifications of hazardous waste prior to disposal. Furthermore, consult with
your state and local waste requirements or guidelines, if applicable, to ensure
compliance. Arrange disposal in accordance to the EPA and/or state and local
guidelines.

Important Disposal Information:

DANGER! Rags, steel wool and waste soaked with this product may
spontaneously catch fire if improperly discarded or stored. To avoid a
spontaneous combustion fire, immediately after use, place rags, steel wool or
waste in a sealed, water-filled, metal container. Do not store unused product
inside the home. For disposal guidance, contact your household refuse collection
service, fire department, county or state government environmental control
agency.

SECTION 14 - TRANSPORT INFORMATION
DOT Shipping Name:

Aerosol flammable

DOT Hazard Class:

2.1

DOT Packing Group:

III

SECTION 15 - REGULATORY INFORMATION
Silicate, mica :
TSCA Inventory Status:

Not listed

State Regulations:

Listed in the New Jersey State Right to Know List.
Listed in the Pennsylvania State Hazardous Substances List.

Canada DSL:

Listed

Limestone (calcium carbonate) :
TSCA Inventory Status:

Contains calcium carbonate (CAS:1317-65-3), which is listed in the TSCA
inventory.

State Regulations:

Listed in the Pennsylvania State Hazardous Substances List..

Rutile :
TSCA Inventory Status:

Listed

State Regulations:

Listed in the Pennsylvania State Hazardous Substances List.

Canada DSL:

Listed

1-Nitropropane :
State Regulations:

Listed in the Pennsylvania State Hazardous Substances List..

Canada DSL:

Listed

Acetone :
TSCA Inventory Status:

Listed

State Regulations:

Listed in the Pennsylvania State Hazardous Substances List.

Canada DSL:

Listed

Titanium dioxide :

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TSCA Inventory Status:

Listed

State Regulations:

Listed in the New Jersey State Right to Know List.
Listed in the Pennsylvania State Hazardous Substances List.

Canada DSL:

Listed

Carbonic acid calcium salt :
Canada DSL:

Listed

Propane :
TSCA Inventory Status:

Listed

State Regulations:

Listed in the Pennsylvania State Hazardous Substances List.
Listed in the New Jersey State Right to Know List.

Canada DSL:

Listed

Isobutane :
TSCA Inventory Status:

Listed

State Regulations:

Listed in the Pennsylvania State Hazardous Substances List.
Listed in the New Jersey State Right to Know List..

Canada DSL:

Listed

VM&P Naphtha/Aliphatic Hydrocarbon :
TSCA Inventory Status:

Listed

State Regulations:

Listed in the New Jersey State Right to Know List.
Listed in the Pennsylvania State Hazardous Substances List.

Canada DSL:

Listed

Talc, Magnesium silicate hydrate :
TSCA Inventory Status:

Listed

State Regulations:

Listed in the New Jersey State Right to Know List.
Listed in the Pennsylvania State Hazardous Substances List.

Canada DSL:

Listed

Talc (powder), containing no asbestos fibers :
TSCA Inventory Status:

Listed

State Regulations:

Listed in the New Jersey State Right to Know List.
Listed in the Pennsylvania State Hazardous Substances List.

Canada DSL:

Listed

Xylene :
TSCA Inventory Status:

Listed

State Regulations:

Listed in the New Jersey State Right to Know List.
Listed in the Pennsylvania State Hazardous Substances List.

Canada DSL:

Listed

Palygorskite :
TSCA Inventory Status:
Canada DSL:

Not listed
Not listed
WARNING: This product contains a chemical known to the state of California to
cause cancer and birth defects or other reproductive harm.

SECTION 16 - ADDITIONAL INFORMATION
HMIS Fire Hazard:

3

HMIS Health Hazard:

1

HMIS Reactivity:

0

HMIS Personal Protection:

x

MSDS Creation Date:

07/15/2006

MSDS Revision Date:

05/09/2007

MSDS Revision Notes:

Quarterly and format update

MSDS Author:

Actio Corporation

Disclaimer:

This Health and Safety Information is correct to the best of our knowledge and
belief at the date of its publication but we cannot accept liability for any loss,
injury or damage which may result from its use. We shall ensure, so far as is
reasonably practicable, that any revision of this Data Sheet is sent to all

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customers to whom we have directly supplied this substance, but must point ou
that it is the responsibility of any intermediate supplier to ensure that such
revision is passed to the ultimate user. The information given in the Data Sheet
is designed only as a guidance for safe handling, storage and the use of the
substance. It is not a specification nor does it guarantee any specific properties.
All chemicals should be handled only by competent personnel, within a
controlled environment. Should further information be required, this can be
obtained through the sales office whose address is at the top of this data sheet.
Trademark:

The trademarks, service marks, graphics and logos used on this MSDS are
registered or unregistered trademarks of BEHR Process Corporation. All Rights
Reserved.
Copyright© 1996-2006 Actio Software Corporation. All Rights Reserved.

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FICHE SIGNALÉTIQUE SANTÉ−SÉCURITÉ
DH1606
02 00
===========================================================================
Section 1 −− IDENTIFICATION DU PRODUIT ET DE LA SOCIÉTÉ
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
NUMÉRO DU PRODUIT
Santé
2*
DH1606
Inflammabilité
3
Réactivité
1
NOM DU PRODUIT
DUPLI−COLOR* High Heat with Ceramic, Aluminum
NOM DU FABRICANT
NO. DE TÉLÉPHONE EN CAS D’URGENCE
SHERWIN−WILLIAMS CANADA, INC.
(216) 566−2917
DUPLI−COLOR Products Group
Vaughan, ON L4K 4T8
DATE DE PRÉPARATION
NO. DE TÉLÉPHONE ORDINAIRE
06−JAN−07
(905) 761−9185
===========================================================================
Section 2 −− COMPOSITION/INFORMATION SUR LES INGRÉDIENTS
% EN POIDS
CAS No. INGREDIENT
UNITÉS
PRESSION VAPEUR
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
14
74−98−6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
13
106−97−8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
2
64742−88−7 Solvant Naphta Aliphatique Moyen
ACGIH TLV
100 ppm
2 mm
OSHA PEL
100 ppm
8
108−88−3 Toluène
ACGIH TLV
50 ppm (Peau)
22 mm
OSHA PEL
100 ppm (Peau)
OSHA PEL
150 ppm (Peau) STEL
1.0
100−41−4 Éthylbenzène
ACGIH TLV
100 ppm
7.1 mm
ACGIH TLV
125 ppm STEL
OSHA PEL
100 ppm
OSHA PEL
125 ppm STEL
5
1330−20−7 Xylène
ACGIH TLV
100 ppm
5.9 mm
ACGIH TLV
150 ppm STEL
OSHA PEL
100 ppm
OSHA PEL
150 ppm STEL
26
67−64−1 Acetone
ACGIH TLV
500 ppm
180 mm
ACGIH TLV
750 ppm STEL
OSHA PEL
1000 ppm
12
108−10−1 Méthylisobutylcétone
ACGIH TLV
50 ppm
16 mm
ACGIH TLV
75 ppm STEL
OSHA PEL
50 ppm
OSHA PEL
75 ppm STEL

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DH1606
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===========================================================================
2
763−69−9 3−Éthoxypropionate d’éthyle
ACGIH TLV Pas Disponible
1.11 mm
OSHA PEL Pas Disponible
===========================================================================
Section 3 −− IDENTIFICATION DES RISQUES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SOURCES D’EXPOSITION
L’exposition peut se produire par l’INHALATION des vapeurs ou du
brouillard de pulvérisation.
La PEAU et les YEUX peuvent entrer en contact avec le produit, les
vapeurs ou le brouillard de pulvérisation.
EFFET DE LA SUREXPOSITION
YEUX: Irritation des YEUX.
PEAU: L’exposition prolongée ou répétée risque de provoquer
l’irritation des peau.
INHALATION: Irritation des voies respiratoires supérieures.
Peut causer la dépression nerveuse. Une sur−exposition excessive à ce
produit peut entrainer la perte de conscience, voire même la mort.
SYMPTÔMES DE SUREXPOSITION
Les maux de tête, l’étourdissement, la nausée et la perte de
coordination des mouvements sont tous des symptômes d’exposition excessive
aux vapeurs ou à la brume de pulvérisation.
La rougeur et les démangeaisons ou la sensation de brûlure peuvent
indiquer une exposition excessive des yeux ou de la peau.
ETAT DE SANTÉ AGGRAVÉ PAR EXPOSITION
En général, aucun exposition n’est reconnue.
CANCÉROGÉNICITÉ
Voir la Section 11.
===========================================================================
Section 4 −− PREMIERS SOINS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
YEUX:

Rincer les yeux à grande eau pendant 15 minutes.
Aller voir un médecin.
PEAU: Laver à fond les parties affectées avec de l’eau et
du savon.
Enlever les habits contaminés et les laver avant de les
porter de nouveau.
INHALATION: Si une personne en est affectée, l’aider à sortir
des lieux. Rétablir la respiration. Aider la
personne á rester calme et au chaud.
INGESTION: N’incitez pas la personne á vomir.
Aller voir un médecin immédiatement.
===========================================================================
Section 5 −− MESURES EN CAS D’INCENDIE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
POINT D’ÉCLAIR
LIE
LSE
Propellant < 0 F
1.0
12.8
MOYENS D’EXTINCTION
Dioxyde de carbone, produit chimique sec, mousse

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DH1606
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===========================================================================
DANGERS D’INCENDIE OU D’EXPLOSION EXCEPTIONNELS
Les contenants peuvent exploser s’ils sont exposés à une très grande
chaleur.
L’application aux surfaces chaudes exige qu’on prenne des précautions
spéciales.
En cas d’urgence, une exposition excessive aux produits de décomposition
peut constituer un danger pour la santé. Les symptômes peuvent ne pas se
manifester immédiatement. Voir le médecin.
MESURES PARTICULIÉRES DI PROTECTION CONTRE L’INCENDIE
On doit utiliser l’équipement de protection complète y compris un
appareil de respiration auto−alimenté.
La pulvérisation avec de l’eau peut être inefficace. Si on se sert de
l’eau, l’ajutage pour brume est préférable. On peut se servir de l’eau
pour refroidir les contenants fermés afin d’empêcher l’augmentation de la
pression et la possibilité d’une combustion automatique ou l’explosion en
cas d’exposition à une chaleur extrêmement grande.
===========================================================================
Section 6 −− MARCHE Á SUIVRE EN CAS DE DÉVERSEMENT ACCIDENTEL
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
MESURES À PRENDRE LORSQUE DES MATIÉRES SONT RENVERSÉES OU ÉVAPORÉES
Enlever toute source de combustion. Bien aérer.
Nettoyer avec un absorbant non réactif.
===========================================================================
Section 7 −− MANUTENTION ET ENTREPOSAGE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
CATÉGORIE D’ENTREPOSAGE
Pas Disponible
PRÉCAUTIONS Á PRENDRE LORS DE L’ENTREPOSAGE DI LA MANIPULATION
Tenir loin de la chaleur, étincelles et de flamme nue. Les vapeurs
peuvent s’accumuler rapidement et s’enflammer et causer une explosion.
Aucours de l’utilisation de ce produit jusqu’à la disparution de toutes
les vapeurs: Garder l’endroit bien aéré. Eviter de fumer. Eteindre toute
flamme, veilleuse d’appareils et réchauds. Couper la courant des poêles,
des outils et appareils éléctriques ainsi que de toute autre source de
combustion.
Suivre les procédures approuvées pour attacher solidement et pour
permettre l’écoulement de l’éléctricité dans le sol.
Contenu sous pression. Ne pas ouvrir, incinérer ou exposer à des
températures au dessus de 120 Fahrenheit. La chaleur des rayons du soleil,
des radiateurs, des réchauds, de l’eau chaude, ou provenant de toute autre
source, peut provoquer l’explosion du contenant. Ne pas avaler. Garder
hors de la portée des enfants.

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DH1606
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===========================================================================
Section 8 −− CONTRÔLE DE L’EXPOSITION ET PROTECTION INDIVIDUELLE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRÉCAUTIONS À PRENDRE AUCOURS DE L’UTILISATION
N’utiliser ce produit que dans un endroit bien aéré.
Éviter tout contact avec la peau et les yeux. Eviter d’aspirer les
vapeurs et la brume de vaporisation.
Bien se laver les mains après l’utilisation.
Ce produit peut contenir des matières classifiées comme petites
particules irritantes, telles que le dioxyde de titane ou le carbonate de
calcium (voir la liste ACGIH TLV, la préface et l’annexe D). On peut avoir
ces particules dans des proportions dangereuses uniquement au moment du
grattement et de l’éraflement de la couche séchée. Si la liste dans la 2e
section ne fait aucune mention spécifique de la présence des poussières de
particules, les limites applicables sont: pour ACGIH TLV 10 mg/m3
(concentration totale de poussière), 3 mg/m3 (fractionée de respiratoire).
VENTILATION
Un système permettant l’échappement local des produits est préférable.
Si l’exposition aux produits de la 2e section est maintenue au−dessous des
limites d’exposition applicables, le système d’échappement global est
acceptable.
PROTECTION DES VOIES RESPIRATOIRES
Si on ne peut pas maintenir, par simple ventilation, le niveau auquel on
s’expos personnellement en dessous des limites applicables, porter un
respirateur à filtre de vapeur organique et particules approprié et bien
ajusté approuvé par NIOSH/MSHA pour se protéger contre les produits de la
2e section.
Pendant que vous frottez ou poncez la couche sechée, porter un
respirateur à filtre de poussière et de brume, approuvé par NIOSH/MSHA pour
vous protéger contre la poussière qui peut éventuellement se dégager de ce
produit, de la peinture ou de l’abrasif.
GANTS PROTECTEURS
Aucun n’est exigé pour l’application normale des produits aérosol,
lorsqu’on n’attend qu’un minimum de contact avec la peau. Pour un contact
prolongé et repété, portez des gants resistants aux produits chimiques.
LUNETTES DE SÉCURITÉ
Porter les lunetttes de sécurité avec des protecteurs latéraux non
perforés.
AUTRES PRÉCAUTIONS
L’utilisation inappropriée de ce produit en le concentrant et en
l’aspirant intentionnellement peut être dangereuse ou peut même causer la
mort.
===========================================================================
Section 9 −− PROPRIÉTÉS PHYSIQUES ET CHIMIQUES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
POIDS DU PRODUIT
6.29 lb/gal
753 g/l
DENSITÉ
0.76
COURBE D’ÉBULLITION
<0 − 395 F
<−18 − 201 C
POINT DE FUSION
P.D.
VOLUME VOLATIL
91 %
VITESSE D’ÉVAPORATION
Plus vite que l’Éther
DENSITÉ DE LA VAPEUR
Plus lourd que l’Air
SOLUBILITÉ DANS L’EAU
P.D.
COMPOSÉS ORGANIQUES VOLATILS (Théorique)
Volatil Poids 58.28% Moins d’eau et de solvants exemptés
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===========================================================================
Section 10 −− STABILITÉ ET RÉACTIVITÉ
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STABILITÉ −− Stable
CONDITIONS À ÉVITER
Aucun connu.
INCOMPATIBILITÉ
Aucun connu.
PRODUITS DANGEREUX DÛ À LA DÉCOMPOSITION
Par combustion: Dioxyde de carbone, monoxyde de carbone
POLYMÉRISATION DANGEREUSE
Ne Peut Pas De Produire
===========================================================================
Section 11 −− DONNÉES TOXICOLOGIQUES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
RISQUES DE SANTÉ CHRONIQUES
À partir de données expérimentales provenant d’études suffisantes
mendées chez les animaux et d’études insuffisantes menées chez humains,
l’éthylbenzène est classifié par le CIRC comme étant possiblement
carcinogène chez les humains (group 2B). On a constaté une augmentation de
certains types de cancer, y compris des tumeurs du rein chez les rats et
des tumeurs du poumon et du foie chez les souris, lorsque ces animaux ont
été exposés à l’inhalation de concentrations élevées d’éthylbenzène à long
terme. Toutefois, ces effets n’ont pas étéobservés chez les animaux
exposés à de plus faibles concentrations d’éthylbenzène. Jusqu’à présent
il n’y a aucune preuve suggérant que l’éthylbenzène provoque le cancer chez
les humains.
L’exposition, excessive et prolongée, aux solvants de la 2 section peut
entrainer demauvaises conséquences aux systèmesdu
fois,urinaire,cardio−vasculaire etreproductif.
Il existe des rapports de recherches qui associent des troubles
permanentes du cerveau et du système nerveux à l’exposition excessive,
répétée et prolongée aux solvants.
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
INFORMATION TOXICOLOGIQUE

Suite à la page 6

DH1606
page 6
===========================================================================
CAS No.
Ingredient
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
74−98−6
Propane
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
106−97−8
Butane
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
64742−88−7
Solvant Naphta Aliphatique Moyen
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
108−88−3
Toluène
LC50
RAT
4HR
4000
ppm
LD50
RAT
5000
mg/kg
100−41−4
Éthylbenzène
LC50
RAT
4HR
Pas Disponible
LD50
RAT
3500
mg/kg
1330−20−7
Xylène
LC50
RAT
4HR
5000
ppm
LD50
RAT
4300
mg/kg
67−64−1
Acetone
LC50
RAT
4HR
Pas Disponible
LD50
RAT
5800
mg/kg
108−10−1
Méthylisobutylcétone
LC50
RAT
4HR
Pas Disponible
LD50
RAT
2080
mg/kg
763−69−9
3−Éthoxypropionate d’éthyle
LC50
RAT
4HR
Pas Disponible
LD50
RAT
5000
mg/kg
===========================================================================
Section 12 −− DONNÉES ÉCOLOGIQUES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Aucunes donnies disponibles.
===========================================================================
Section 13 −− DONNÉES SUR L’ÉLIMINATION DU PRODUIT
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
MÉTHODE D’ÉLIMINATION DES DÉCHETS
Les déchets provenant de ce produit peuvent être dangereux, selon la
définition donnée dans la "U.S. Resource Conservation and Recovery Act"
(RCRA) 40 CFR 261.
On doit soumettre les déchets au test de combustion afin de déterminer
les numéros de l’EPA applicables.
Ne pas incinérer. Eliminer la pression dans le contenant. Se
débarrasser du contenu confermément aux lois anti−pollution fédérales,
provinciales et municipales.
===========================================================================
Section 14 −− DONNÉES SUR LE TRANSPORT
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Aucunes donnies disponibles.

Suite à la page 7

DH1606
page 7
===========================================================================
Section 15 −− DONNÉES SUR LA RÉGLEMENTATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SARA 313 (40 CFR 372.65C) AVIS DE FOURNISSEUR
CAS No.
CHIMIQUE/COMPOSÉ
% by WT
% Element
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
108−88−3 Toluène
8
100−41−4 Éthylbenzène
0.9
1330−20−7 Xylène
5
108−10−1 Méthylisobutylcétone
12
DONNÉES SUR LA TSCA
Tous les produits chimiques dans ce produit sont énumérés, ou exemptez
de l’énumération, sur le inventaire de TSCA.
===========================================================================
Section 16 −− AUTRES DONNÉES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Cette FTSS a été préparée conformént aux exigences du SIMDUT; les
données sont toutefois présentées sous 16 rubriques.

Les renseignements donnés ci−haut se rapportent à ce produit suivant sa
formule actuelle et s’appuient sur les données disponibles en ce moment.
L’addition de diluant et autres additifs peut changer considérablement les
risques associés à ce produit et sa composition. Etant donné que nous
n’avons pas de contrôle sur les conditions d’utilisation, nous ne donnons
aucune guarantie, explicite ou implicite et nous n’assumons aucune
responsabilité concernant l’usage, quel qu’il soit, de ces renseignements.

MATERIAL SAFETY DATA SHEET
H101
01 00
===========================================================================
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
--------------------------------------------------------------------------PRODUCT NUMBER
HMIS CODES
Health
2*
H101
Flammability
4
Reactivity
0
PRODUCT NAME
Hi-Heat Spray Paint, Hibachi Black
MANUFACTURER’S NAME
EMERGENCY TELEPHONE NO.
SHERWIN-WILLIAMS CANADA, INC.
(216) 566-2917
DUPLI-COLOR Products Group
Vaughan, ON L4K 4T8
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
22-MAR-04
(905) 761-9185
===========================================================================
Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
--------------------------------------------------------------------------15
74-98-6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
14
106-97-8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
10
108-88-3 Toluene
ACGIH TLV
50 ppm (skin)
22 mm
OSHA PEL
100 ppm (skin)
OSHA PEL
150 ppm (skin) STEL
2
100-41-4 Ethylbenzene
ACGIH TLV
100 ppm
7.1 mm
ACGIH TLV
125 ppm STEL
OSHA PEL
100 ppm
OSHA PEL
125 ppm STEL
11
1330-20-7 Xylene
ACGIH TLV
100 ppm
5.9 mm
ACGIH TLV
150 ppm STEL
OSHA PEL
100 ppm
OSHA PEL
150 ppm STEL
2
64742-94-5 Medium Aromatic Hydrocarbons
ACGIH TLV Not Available
0.12 mm
OSHA PEL Not Available
23
67-64-1 Acetone
ACGIH TLV
500 ppm
180 mm
ACGIH TLV
750 ppm STEL
OSHA PEL
1000 ppm
6
14807-96-6 Talc
ACGIH TLV
2 mg/m3 as Resp. Dust
OSHA PEL
2 mg/m3 as Resp. Dust

Continued on page 2

H101
page 2
===========================================================================
Section 3 -- HAZARDS IDENTIFICATION
--------------------------------------------------------------------------ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
===========================================================================
Section 4 -- FIRST AID MEASURES
--------------------------------------------------------------------------EYES:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 -- FIRE FIGHTING MEASURES
--------------------------------------------------------------------------FLASH POINT
LEL
UEL
Propellant < 0 F
0.8
12.8
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.

Continued on page 3

H101
page 3
===========================================================================
Section 6 -- ACCIDENTAL RELEASE MEASURES
--------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
===========================================================================
Section 7 -- HANDLING AND STORAGE
--------------------------------------------------------------------------STORAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated - Do not
smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
===========================================================================
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
--------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.

Continued on page 4

H101
page 4
===========================================================================
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
--------------------------------------------------------------------------PRODUCT WEIGHT
6.56 lb/gal
785 g/l
SPECIFIC GRAVITY
0.79
BOILING POINT
<0 - 415 F
<-18 - 212 C
MELTING POINT
Not Available
VOLATILE VOLUME
90 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical)
Volatile Weight 55.71 % Less Water and Federally Exempt Solvents
===========================================================================
Section 10 -- STABILITY AND REACTIVITY
--------------------------------------------------------------------------STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
===========================================================================
Section 11 -- TOXICOLOGICAL INFORMATION
--------------------------------------------------------------------------CHRONIC HEALTH HAZARDS
Ethylbenzene is classified by IARC as possibly carcinogenic to humans
(2B) based on inadequate evidence in humans and sufficient evidence in
laboratory animals.
Lifetime inhalation exposure of rats and mice to high
ethylbenzene concentrations resulted in increases in certain types of
cancer, including kidney tumors in rats and lung and liver tumors in mice.
These effects were not observed in animals exposed to lower concentrations.
There is no evidence that ethylbenzene causes cancer in humans.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, cardiovascular and reproductive
systems.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
--------------------------------------------------------------------------TOXICOLOGY DATA

Continued on page 5

H101
page 5
===========================================================================
CAS No.
Ingredient Name
--------------------------------------------------------------------------74-98-6
Propane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
106-97-8
Butane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
108-88-3
Toluene
LC50
RAT
4HR
4000
ppm
LD50
RAT
5000
mg/kg
100-41-4
Ethylbenzene
LC50
RAT
4HR
Not Available
LD50
RAT
3500
mg/kg
1330-20-7
Xylene
LC50
RAT
4HR
5000
ppm
LD50
RAT
4300
mg/kg
64742-94-5
Medium Aromatic Hydrocarbons
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
67-64-1
Acetone
LC50
RAT
4HR
Not Available
LD50
RAT
5800
mg/kg
14807-96-6
Talc
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
===========================================================================
Section 12 -- ECOLOGICAL INFORMATION
--------------------------------------------------------------------------ECOTOXICOLOGICAL INFORMATION
No data available.
===========================================================================
Section 13 -- DISPOSAL CONSIDERATIONS
--------------------------------------------------------------------------WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.
===========================================================================
Section 14 -- TRANSPORT INFORMATION
--------------------------------------------------------------------------No data available.
===========================================================================
Section 15 -- REGULATORY INFORMATION
--------------------------------------------------------------------------SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION

Continued on page 6

H101
page 6
===========================================================================
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
--------------------------------------------------------------------------108-88-3 Toluene
10
100-41-4 Ethylbenzene
2
1330-20-7 Xylene
11
Manganese Compound
5
0.9
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
===========================================================================
Section 16 -- OTHER INFORMATION
--------------------------------------------------------------------------This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

MATERIAL SAFETY DATA SHEET
1712
01 00
===========================================================================
Section 1 −− PRODUCT AND COMPANY IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT NUMBER
HMIS CODES
Health
2*
1712
Flammability
3
Reactivity
0
PRODUCT NAME
KRYLON* Industrial TOUGH COAT* I.D. Fluorescent Paint, Fluorescent Red
MANUFACTURER’S NAME
EMERGENCY TELEPHONE NO.
THE SHERWIN−WILLIAMS COMPANY
(216) 566−2917
Diversified Brands
Cleveland, OH 44115
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
04−MAY−07
(800) 247−3266
===========================================================================
Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
14
74−98−6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
6
106−97−8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
9
110−54−3 Hexane
ACGIH TLV
50 ppm
127 mm
OSHA PEL
50 ppm
4
107−83−5 Isohexane Isomers
ACGIH TLV Not Available
211 mm
OSHA PEL Not Available
1
96−14−0 3−Methylpentane
ACGIH TLV
500 ppm
211 mm
OSHA PEL Not Available
1
79−29−8 2,3−Dimethylbutane
ACGIH TLV Not Available
230 mm
OSHA PEL Not Available
7
64742−89−8 V. M. & P. Naphtha
ACGIH TLV
300 ppm
12 mm
OSHA PEL
300 ppm
OSHA PEL
400 ppm STEL
2
108−88−3 Toluene
ACGIH TLV
20 ppm
22 mm
OSHA PEL
100 ppm (Skin)
OSHA PEL
150 ppm (Skin) STEL
9
67−64−1 Acetone
ACGIH TLV
500 ppm
180 mm
ACGIH TLV
750 ppm STEL
OSHA PEL
1000 ppm
21
14808−60−7 Quartz
ACGIH TLV
0.05 mg/m3 as Resp. Dust
OSHA PEL
0.1 mg/m3 as Resp. Dust
Continued on page 2

1712
page 2
===========================================================================
8
7727−43−7 Barium Sulfate
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction
===========================================================================
Section 3 −− HAZARDS IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
===========================================================================
Section 4 −− FIRST AID MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
EYES:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re−use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 −− FIRE FIGHTING MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
FLASH POINT
LEL
UEL
Propellant < 0 F
0.9
12.8
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.

Continued on page 3

1712
page 3
===========================================================================
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self−contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build−up and possible autoignition or explosion when exposed to
extreme heat.
===========================================================================
Section 6 −− ACCIDENTAL RELEASE MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
===========================================================================
Section 7 −− HANDLING AND STORAGE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STORAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated − Do not
smoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
===========================================================================
Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.

Continued on page 4

1712
page 4
===========================================================================
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
===========================================================================
Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT WEIGHT
7.54 lb/gal
903 g/l
SPECIFIC GRAVITY
0.91
BOILING POINT
<0 − 325 F
<−18 − 162 C
MELTING POINT
Not Available
VOLATILE VOLUME
79 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical − As Packaged)
Volatile Weight 47.18% Less Water and Federally Exempt Solvents
===========================================================================
Section 10 −− STABILITY AND REACTIVITY
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STABILITY −− Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
===========================================================================
Section 11 −− TOXICOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
CHRONIC HEALTH HAZARDS
Crystalline Silica (Quartz, Cristobalite) is listed by IARC and NTP.
Long term exposure to high levels of silica dust, which can occur only when
sanding or abrading the dry film, may cause lung damage (silicosis) and
possibly cancer.
Prolonged and repeated exposure to Hexane may cause damage to nerve
tissue of the arms and legs (peripheral neuropathy), resulting in muscular
weakness and loss of sensation. This effect may be increased by the
presence of Methyl Ethyl Ketone.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, cardiovascular and reproductive
systems.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
TOXICOLOGY DATA
Continued on page 5

1712
page 5
===========================================================================
CAS No.
Ingredient Name
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
74−98−6
Propane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
106−97−8
Butane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
110−54−3
Hexane
LC50
RAT
4HR
Not Available
LD50
RAT
28700
mg/kg
107−83−5
Isohexane Isomers
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
96−14−0
3−Methylpentane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
79−29−8
2,3−Dimethylbutane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
64742−89−8
V. M. & P. Naphtha
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
108−88−3
Toluene
LC50
RAT
4HR
4000
ppm
LD50
RAT
5000
mg/kg
67−64−1
Acetone
LC50
RAT
4HR
Not Available
LD50
RAT
5800
mg/kg
14808−60−7
Quartz
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
7727−43−7
Barium Sulfate
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
===========================================================================
Section 12 −− ECOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ECOTOXICOLOGICAL INFORMATION
No data available.
===========================================================================
Section 13 −− DISPOSAL CONSIDERATIONS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.

Continued on page 6

1712
page 6
===========================================================================
Section 14 −− TRANSPORT INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
US Ground (DOT)
May be classed as Consumer Commodity, ORM−D
UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126)
Canada (TDG)
May be classed as Consumer Commodity, ORM−D
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126)
IMO
May be shipped as Limited Quantity
UN1950, AEROSOLS, CLASS 2, LIMITED QUANTITY, EmS F−D, S−U
===========================================================================
Section 15 −− REGULATORY INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
110−54−3 Hexane
9
108−88−3 Toluene
2
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
===========================================================================
Section 16 −− OTHER INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

MATERIAL SAFETY DATA SHEET
49211
02 00
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER
DATE OF PREPARATION
HMIS CODES
Health
49211
06-SEP-07
Flammability
Reactivity
PRODUCT NAME
KRYLON® RUST TOUGH® Rust Preventive Enamel (aerosol), Sun Yellow

2*
3
0

MANUFACTURER'S NAME
SHERWIN-WILLIAMS CANADA INC.
KRYLON Products Group
Vaughan, ON L4K 4T8
TELEPHONE NUMBERS and WEBSITES
Product Information
(800) 832-2541
Regulatory Information
(216) 566-2902
www.paintdocs.com
Medical Emergency
(216) 566-2917
Transportation Emergency
for Chemical Emergency ONLY (spill, leak,
(800) 424-9300
fire, exposure, or accident)
% by WT
14
7
5

11

0.5

3

Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
74-98-6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
106-97-8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
64742-89-8 V. M. & P. Naphtha
ACGIH TLV
300 ppm
12 mm
OSHA PEL
300 ppm
OSHA PEL
400 ppm STEL
108-88-3 Toluene
ACGIH TLV
20 ppm
22 mm
OSHA PEL
100 ppm (Skin)
OSHA PEL
150 ppm (Skin) STEL
100-41-4 Ethylbenzene
ACGIH TLV
100 ppm
7.1 mm
ACGIH TLV
125 ppm STEL
OSHA PEL
100 ppm
OSHA PEL
125 ppm STEL
1330-20-7 Xylene
ACGIH TLV
100 ppm
5.9 mm
ACGIH TLV
150 ppm STEL
OSHA PEL
100 ppm
OSHA PEL
150 ppm STEL

Continued on page 2

49211

page 2

34

5

2

67-64-1

108-10-1

13463-67-7

Acetone
ACGIH TLV
500
ACGIH TLV
750
OSHA PEL
1000
Methyl Isobutyl Ketone
ACGIH TLV
50
ACGIH TLV
75
OSHA PEL
50
OSHA PEL
75
Titanium Dioxide
ACGIH TLV
10
OSHA PEL
10
OSHA PEL
5

ppm
ppm STEL
ppm

180 mm

ppm
ppm STEL
ppm
ppm STEL

16 mm

mg/m3 as Dust
mg/m3 Total Dust
mg/m3 Respirable Fraction

Section 3 -- HAZARDS IDENTIFICATION
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
Section 4 -- FIRST AID MEASURES
EYES:
SKIN:
INHALATION:
INGESTION:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
Do not induce vomiting.
Get medical attention immediately.

Section 5 -- FIRE FIGHTING MEASURES
FLASH POINT
LEL
UEL
Propellant < 0 F
0.9
12.8
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam

Continued on page 3

49211

page 3

UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.
Section 6 -- ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
Section 7 -- HANDLING AND STORAGE
STORAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated - Do not
smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.

Continued on page 4

49211

page 4

Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
Removal of old paint by sanding, scraping or other means may generate
dust or fumes that contain lead. Exposure to lead dust or fumes may cause
brain damage or other adverse health effects, especially in children or
pregnant women. Controlling exposure to lead or other hazardous substances
requires the use of proper protective equipment, such as a properly fitted
respirator (NIOSH approved) and proper containment and cleanup. For more
information, call the National Lead Information Center at 1-800-424-LEAD
(in US) or contact your local health authority.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT WEIGHT
6.44 lb/gal
771 g/l
SPECIFIC GRAVITY
0.78
BOILING POINT
<0 - 325 F
<-18 - 162 C
MELTING POINT
Not Available
VOLATILE VOLUME
87 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
Volatile Weight 46.19% Less Water and Federally Exempt Solvents
Continued on page 5

49211

page 5

Section 10 -- STABILITY AND REACTIVITY
STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
Section 11 -- TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
Ethylbenzene is classified by IARC as possibly carcinogenic to humans
(2B) based on inadequate evidence in humans and sufficient evidence in
laboratory animals.
Lifetime inhalation exposure of rats and mice to high
ethylbenzene concentrations resulted in increases in certain types of
cancer, including kidney tumors in rats and lung and liver tumors in mice.
These effects were not observed in animals exposed to lower concentrations.
There is no evidence that ethylbenzene causes cancer in humans.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, cardiovascular and reproductive
systems.
IARC's Monograph No. 93 reports there is sufficient evidence of
carcinogenicity in experimental rats exposed to titanium dioxide but
inadequate evidence for carcinogenicity in humans and has assigned a Group
2B rating. In addition, the IARC summary concludes, "No significant
exposure to titanium dioxide is thought to occur during the use of products
in which titanium is bound to other materials, such as paint."
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
TOXICOLOGY DATA

Continued on page 6

49211
CAS No.
74-98-6
106-97-8
64742-89-8
108-88-3
100-41-4
1330-20-7
67-64-1
108-10-1
13463-67-7

page 6
Ingredient Name
Propane
LC50
RAT
LD50
RAT
Butane
LC50
RAT
LD50
RAT
V. M. & P. Naphtha
LC50
RAT
LD50
RAT
Toluene
LC50
RAT
LD50
RAT
Ethylbenzene
LC50
RAT
LD50
RAT
Xylene
LC50
RAT
LD50
RAT
Acetone
LC50
RAT
LD50
RAT
Methyl Isobutyl Ketone
LC50
RAT
LD50
RAT
Titanium Dioxide
LC50
RAT
LD50
RAT

4HR

Not Available
Not Available

4HR

Not Available
Not Available

4HR

Not Available
Not Available

4HR
4HR
4HR

4000
5000

ppm
mg/kg

Not Available
3500
mg/kg
5000
4300

ppm
mg/kg

4HR

Not Available
5800
mg/kg

4HR

Not Available
2080
mg/kg

4HR

Not Available
Not Available

Section 12 -- ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
No data available.
Section 13 -- DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.

Continued on page 7

49211

page 7

Section 14 -- TRANSPORT INFORMATION
US Ground (DOT)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126)
Canada (TDG)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126)
IMO
May be shipped as Limited Quantity
UN1950, AEROSOLS, CLASS 2, LIMITED QUANTITY, EmS F-D, S-U
Section 15 -- REGULATORY INFORMATION
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
108-88-3
100-41-4
1330-20-7
108-10-1

CHEMICAL/COMPOUND
Toluene
Ethylbenzene
Xylene
Methyl Isobutyl Ketone

% by WT
11
0.4
3
5

% Element

TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
Section 16 -- OTHER INFORMATION
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

MATERIAL SAFETY DATA SHEET
1715
01 00
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER
DATE OF PREPARATION
HMIS CODES
Health
2*
1715
22-DEC-07
Flammability
3
Reactivity
0
PRODUCT NAME
KRYLON® Industrial TOUGH COAT™ I.D. Fluorescent Paint, Fluorescent Green
MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS COMPANY
Diversified Brands
Cleveland, OH 44115
TELEPHONE NUMBERS and WEBSITES
Product Information
(800) 247-3266
Regulatory Information
(216) 566-2902
www.paintdocs.com
Medical Emergency
(216) 566-2917
Transportation Emergency
for Chemical Emergency ONLY (spill, leak,
(800) 424-9300
fire, exposure, or accident)
% by WT
14
6
8
4
1
1
7

Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
74-98-6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
106-97-8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
110-54-3 Hexane
ACGIH TLV
50 ppm
127 mm
OSHA PEL
50 ppm
107-83-5 Isohexane Isomers
ACGIH TLV Not Available
211 mm
OSHA PEL Not Available
96-14-0 3-Methylpentane
ACGIH TLV
500 ppm
211 mm
OSHA PEL Not Available
79-29-8 2,3-Dimethylbutane
ACGIH TLV Not Available
230 mm
OSHA PEL Not Available
64742-89-8 V. M. & P. Naphtha
ACGIH TLV
300 ppm
12 mm
OSHA PEL
300 ppm
OSHA PEL
400 ppm STEL

Continued on page 2

1715
3

page 2
108-88-3

9

21
8

67-64-1

14808-60-7
7727-43-7

Toluene
ACGIH TLV
OSHA PEL
OSHA PEL
Acetone
ACGIH TLV
ACGIH TLV
OSHA PEL
Quartz
ACGIH TLV
OSHA PEL
Barium Sulfate
ACGIH TLV
OSHA PEL
OSHA PEL

20
100
150

ppm
ppm (Skin)
ppm (Skin) STEL

500
750
1000

ppm
ppm STEL
ppm

0.05
0.1

mg/m3 as Resp. Dust
mg/m3 as Resp. Dust

10
10
5

22 mm

180 mm

mg/m3 as Dust
mg/m3 Total Dust
mg/m3 Respirable Fraction

Section 3 -- HAZARDS IDENTIFICATION
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, cardiovascular and reproductive
systems.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
Section 4 -- FIRST AID MEASURES
EYES:
SKIN:
INHALATION:
INGESTION:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
Do not induce vomiting.
Get medical attention immediately.

Continued on page 3

1715

page 3

Section 5 -- FIRE FIGHTING MEASURES
FLASH POINT
LEL
UEL
Propellant < 0 F
0.9
12.8
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.
Section 6 -- ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
Section 7 -- HANDLING AND STORAGE
STORAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated - Do not
smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).

Continued on page 4

1715

page 4

VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT WEIGHT
7.56 lb/gal
905 g/l
SPECIFIC GRAVITY
0.91
BOILING POINT
<0 - 325 F
<-18 - 162 C
MELTING POINT
Not Available
VOLATILE VOLUME
79 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
Volatile Weight 47.01% Less Water and Federally Exempt Solvents
Section 10 -- STABILITY AND REACTIVITY
STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur

Continued on page 5

1715

page 5

Section 11 -- TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
Prolonged and repeated exposure to Hexane may cause damage to nerve
tissue of the arms and legs (peripheral neuropathy), resulting in muscular
weakness and loss of sensation. This effect may be increased by the
presence of Methyl Ethyl Ketone.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
Crystalline Silica (Quartz, Cristobalite) is listed by IARC and NTP.
Long term exposure to high levels of silica dust, which can occur only when
sanding or abrading the dry film, may cause lung damage (silicosis) and
possibly cancer.
TOXICOLOGY DATA
CAS No.
Ingredient Name
74-98-6
Propane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
106-97-8
Butane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
110-54-3
Hexane
LC50
RAT
4HR
Not Available
LD50
RAT
28700
mg/kg
107-83-5
Isohexane Isomers
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
96-14-0
3-Methylpentane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
79-29-8
2,3-Dimethylbutane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
64742-89-8
V. M. & P. Naphtha
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
108-88-3
Toluene
LC50
RAT
4HR
4000
ppm
LD50
RAT
5000
mg/kg
67-64-1
Acetone
LC50
RAT
4HR
Not Available
LD50
RAT
5800
mg/kg
14808-60-7
Quartz
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
7727-43-7
Barium Sulfate
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available

Continued on page 6

1715

page 6

Section 12 -- ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
No data available.
Section 13 -- DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.
Section 14 -- TRANSPORT INFORMATION
US Ground (DOT)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126)
Canada (TDG)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126)
IMO
May be shipped as Limited Quantity
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U
Section 15 -- REGULATORY INFORMATION
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
110-54-3 Hexane
108-88-3 Toluene

% by WT
8
3

% Element

CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
Section 16 -- OTHER INFORMATION
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

Continued on page 7

1715

page 7

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

MATERIAL SAFETY DATA SHEET
C20758
01 00
===========================================================================
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
--------------------------------------------------------------------------PRODUCT NUMBER
HMIS CODES
Health
2
C20758
Flammability
4
Reactivity
0
PRODUCT NAME
15100 OSHA BLUE
MANUFACTURER'S NAME
EMERGENCY TELEPHONE NO.
THE SHERWIN-WILLIAMS COMPANY
(216) 566-2917
101 Prospect Avenue N.W.
Cleveland, OH 44115
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
02-JUN-05
(216) 566-2902
===========================================================================
Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
--------------------------------------------------------------------------14
74-98-6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
13
106-97-8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
22
108-88-3 Toluene
ACGIH TLV
50 ppm (Skin)
22 mm
OSHA PEL
100 ppm (Skin)
OSHA PEL
150 ppm (Skin) STEL
33
67-64-1 Acetone
ACGIH TLV
500 ppm
180 mm
ACGIH TLV
750 ppm STEL
OSHA PEL
1000 ppm
2
763-69-9 Ethyl 3-Ethoxypropionate
ACGIH TLV Not Available
1.11 mm
OSHA PEL Not Available
1
1332-58-7 Kaolin
ACGIH TLV
2 mg/m3 as Resp. Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction
1
13463-67-7 Titanium Dioxide
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction
===========================================================================
Section 3 -- HAZARDS IDENTIFICATION
--------------------------------------------------------------------------ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.

Continued on page 2

C20758
page 2
===========================================================================
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
===========================================================================
Section 4 -- FIRST AID MEASURES
--------------------------------------------------------------------------EYES:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 -- FIRE FIGHTING MEASURES
--------------------------------------------------------------------------FLASH POINT
LEL
UEL
Propellant < 0 F
1.0
12.8
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.
===========================================================================
Section 6 -- ACCIDENTAL RELEASE MEASURES
--------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.

Continued on page 3

C20758
page 3
===========================================================================
Section 7 -- HANDLING AND STORAGE
--------------------------------------------------------------------------STORAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated - Do not
smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
===========================================================================
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
--------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.

Continued on page 4

C20758
page 4
===========================================================================
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
--------------------------------------------------------------------------PRODUCT WEIGHT
6.29 lb/gal
753 g/l
SPECIFIC GRAVITY
0.76
BOILING POINT
<0 - 342 F
<-18 - 172 C
MELTING POINT
Not Available
VOLATILE VOLUME
91 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical)
Volatile Weight 51.59 % Less Water and Federally Exempt Solvents
===========================================================================
Section 10 -- STABILITY AND REACTIVITY
--------------------------------------------------------------------------STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
===========================================================================
Section 11 -- TOXICOLOGICAL INFORMATION
--------------------------------------------------------------------------CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, cardiovascular and reproductive
systems.
Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung
cancer, however, such exposure levels are not attainable in the workplace.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
--------------------------------------------------------------------------TOXICOLOGY DATA

Continued on page 5

C20758
page 5
===========================================================================
CAS No.
Ingredient Name
--------------------------------------------------------------------------74-98-6
Propane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
106-97-8
Butane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
108-88-3
Toluene
LC50
RAT
4HR
4000
ppm
LD50
RAT
5000
mg/kg
67-64-1
Acetone
LC50
RAT
4HR
Not Available
LD50
RAT
5800
mg/kg
763-69-9
Ethyl 3-Ethoxypropionate
LC50
RAT
4HR
Not Available
LD50
RAT
5000
mg/kg
1332-58-7
Kaolin
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
13463-67-7
Titanium Dioxide
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
===========================================================================
Section 12 -- ECOLOGICAL INFORMATION
--------------------------------------------------------------------------ECOTOXICOLOGICAL INFORMATION
No data available.
===========================================================================
Section 13 -- DISPOSAL CONSIDERATIONS
--------------------------------------------------------------------------WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.
===========================================================================
Section 14 -- TRANSPORT INFORMATION
--------------------------------------------------------------------------No data available.
===========================================================================
Section 15 -- REGULATORY INFORMATION
--------------------------------------------------------------------------SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
--------------------------------------------------------------------------108-88-3 Toluene
22

Continued on page 6

C20758
page 6
===========================================================================
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
===========================================================================
Section 16 -- OTHER INFORMATION
--------------------------------------------------------------------------This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

368
01 00

MATERIAL SAFETY DATA SHEET

===========================================================================
Section 1 −− PRODUCT AND COMPANY IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT NUMBER
HMIS CODES
Health
2
368
Flammability
4
Reactivity
0
PRODUCT NAME
KRYLON* WEEKEND* Spray Paint, Almond
MANUFACTURER’S NAME
EMERGENCY TELEPHONE NO.
THE SHERWIN−WILLIAMS COMPANY
(216) 566−2917
Diversified Brands
Cleveland, OH 44115
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
01−JUL−06
(800) 247−3266
===========================================================================
Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
14
74−98−6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
13
106−97−8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
19
108−88−3 Toluene
ACGIH TLV
50 ppm (Skin)
22 mm
OSHA PEL
100 ppm (Skin)
OSHA PEL
150 ppm (Skin) STEL
39
67−64−1 Acetone
ACGIH TLV
500 ppm
180 mm
ACGIH TLV
750 ppm STEL
OSHA PEL
1000 ppm
2
763−69−9 Ethyl 3−Ethoxypropionate
ACGIH TLV Not Available
1.11 mm
OSHA PEL Not Available
2
13463−67−7 Titanium Dioxide
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction
===========================================================================
Section 3 −− HAZARDS IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
Continued on page 2

368
page 2
===========================================================================
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
===========================================================================
Section 4 −− FIRST AID MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
EYES:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re−use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 −− FIRE FIGHTING MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
FLASH POINT
LEL
UEL
Propellant < 0 F
1.0
12.8
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self−contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build−up and possible autoignition or explosion when exposed to
extreme heat.
===========================================================================
Section 6 −− ACCIDENTAL RELEASE MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
===========================================================================
Section 7 −− HANDLING AND STORAGE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STORAGE CATEGORY
Not Available

Continued on page 3

368
page 3
===========================================================================
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated − Do not
smoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
===========================================================================
Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.

Continued on page 4

368
page 4
===========================================================================
Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT WEIGHT
6.22 lb/gal
745 g/l
SPECIFIC GRAVITY
0.75
BOILING POINT
<0 − 342 F
<−18 − 172 C
MELTING POINT
Not Available
VOLATILE VOLUME
93 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical − As Packaged)
Volatile Weight 48.54% Less Water and Federally Exempt Solvents
===========================================================================
Section 10 −− STABILITY AND REACTIVITY
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STABILITY −− Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
===========================================================================
Section 11 −− TOXICOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, cardiovascular and reproductive
systems.
Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung
cancer, however, such exposure levels are not attainable in the workplace.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
TOXICOLOGY DATA

Continued on page 5

368
page 5
===========================================================================
CAS No.
Ingredient Name
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
74−98−6
Propane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
106−97−8
Butane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
108−88−3
Toluene
LC50
RAT
4HR
4000
ppm
LD50
RAT
5000
mg/kg
67−64−1
Acetone
LC50
RAT
4HR
Not Available
LD50
RAT
5800
mg/kg
763−69−9
Ethyl 3−Ethoxypropionate
LC50
RAT
4HR
Not Available
LD50
RAT
5000
mg/kg
13463−67−7
Titanium Dioxide
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
===========================================================================
Section 12 −− ECOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ECOTOXICOLOGICAL INFORMATION
No data available.
===========================================================================
Section 13 −− DISPOSAL CONSIDERATIONS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.
===========================================================================
Section 14 −− TRANSPORT INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
No data available.
===========================================================================
Section 15 −− REGULATORY INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
108−88−3 Toluene
19
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.

Continued on page 6

368
page 6
===========================================================================
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
===========================================================================
Section 16 −− OTHER INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

M107
01 00

MATERIAL SAFETY DATA SHEET

===========================================================================
Section 1 −− PRODUCT AND COMPANY IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT NUMBER
HMIS CODES
Health
2*
M107
Flammability
4
Reactivity
1
PRODUCT NAME
Spray Paint, Silver
MANUFACTURER’S NAME
EMERGENCY TELEPHONE NO.
CONSUMER BRANDS CANADA
(216) 566−2917
200 Confederation Parkway
Vaughan, ON L4K 4T8
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
08−OCT−05
(905) 761−8866
===========================================================================
Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
16
74−98−6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
16
106−97−8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
1
64742−88−7 Mineral Spirits
ACGIH TLV
100 ppm
2 mm
OSHA PEL
100 ppm
34
108−88−3 Toluene
ACGIH TLV
50 ppm (Skin)
22 mm
OSHA PEL
100 ppm (Skin)
OSHA PEL
150 ppm (Skin) STEL
0.4
100−41−4 Ethylbenzene
ACGIH TLV
100 ppm
7.1 mm
ACGIH TLV
125 ppm STEL
OSHA PEL
100 ppm
OSHA PEL
125 ppm STEL
2
1330−20−7 Xylene
ACGIH TLV
100 ppm
5.9 mm
ACGIH TLV
150 ppm STEL
OSHA PEL
100 ppm
OSHA PEL
150 ppm STEL
10
67−64−1 Acetone
ACGIH TLV
500 ppm
180 mm
ACGIH TLV
750 ppm STEL
OSHA PEL
1000 ppm

Continued on page 2

M107
page 2
===========================================================================
Section 3 −− HAZARDS IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
===========================================================================
Section 4 −− FIRST AID MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
EYES:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re−use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 −− FIRE FIGHTING MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
FLASH POINT
LEL
UEL
Propellant < 0 F
1.0
12.8
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self−contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build−up and possible autoignition or explosion when exposed to
extreme heat.

Continued on page 3

M107
page 3
===========================================================================
Section 6 −− ACCIDENTAL RELEASE MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
===========================================================================
Section 7 −− HANDLING AND STORAGE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STORAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated − Do not
smoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
===========================================================================
Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
Removal of old paint by sanding, scraping or other means may generate
dust or fumes that contain lead. Exposure to lead dust or fumes may cause
brain damage or other adverse health effects, especially in children or
pregnant women. Controlling exposure to lead or other hazardous substances
requires the use of proper protective equipment, such as a properly fitted
respirator (NIOSH approved) and proper containment and cleanup. For more
information, call the National Lead Information Center at 1−800−424−LEAD
(in US) or contact your local health authority.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.

Continued on page 4

M107
page 4
===========================================================================
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
===========================================================================
Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT WEIGHT
6.23 lb/gal
746 g/l
SPECIFIC GRAVITY
0.75
BOILING POINT
<0 − 395 F
<−18 − 201 C
MELTING POINT
Not Available
VOLATILE VOLUME
87 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical)
Volatile Weight 70.31 % Less Water and Federally Exempt Solvents
===========================================================================
Section 10 −− STABILITY AND REACTIVITY
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STABILITY −− Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
===========================================================================
Section 11 −− TOXICOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
CHRONIC HEALTH HAZARDS
Ethylbenzene is classified by IARC as possibly carcinogenic to humans
(2B) based on inadequate evidence in humans and sufficient evidence in
laboratory animals.
Lifetime inhalation exposure of rats and mice to high
ethylbenzene concentrations resulted in increases in certain types of
cancer, including kidney tumors in rats and lung and liver tumors in mice.
These effects were not observed in animals exposed to lower concentrations.
There is no evidence that ethylbenzene causes cancer in humans.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, cardiovascular and reproductive
systems.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
TOXICOLOGY DATA

Continued on page 5

M107
page 5
===========================================================================
CAS No.
Ingredient Name
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
74−98−6
Propane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
106−97−8
Butane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
64742−88−7
Mineral Spirits
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
108−88−3
Toluene
LC50
RAT
4HR
4000
ppm
LD50
RAT
5000
mg/kg
100−41−4
Ethylbenzene
LC50
RAT
4HR
Not Available
LD50
RAT
3500
mg/kg
1330−20−7
Xylene
LC50
RAT
4HR
5000
ppm
LD50
RAT
4300
mg/kg
67−64−1
Acetone
LC50
RAT
4HR
Not Available
LD50
RAT
5800
mg/kg
===========================================================================
Section 12 −− ECOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ECOTOXICOLOGICAL INFORMATION
No data available.
===========================================================================
Section 13 −− DISPOSAL CONSIDERATIONS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.
===========================================================================
Section 14 −− TRANSPORT INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
No data available.
===========================================================================
Section 15 −− REGULATORY INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
108−88−3 Toluene
34
100−41−4 Ethylbenzene
0.3
1330−20−7 Xylene
2
Continued on page 6

M107
page 6
===========================================================================
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
===========================================================================
Section 16 −− OTHER INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

3202
01 00

MATERIAL SAFETY DATA SHEET

===========================================================================
Section 1 −− PRODUCT AND COMPANY IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT NUMBER
HMIS CODES
Health
2
3202
Flammability
4
Reactivity
0
PRODUCT NAME
KRYLON* Appliance Epoxy Paint, Almond
MANUFACTURER’S NAME
EMERGENCY TELEPHONE NO.
THE SHERWIN−WILLIAMS COMPANY
(216) 566−2917
KRYLON Products Group
Cleveland, OH 44115
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
24−JAN−06
(800) 832−2541
===========================================================================
Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
14
74−98−6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
13
106−97−8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
19
108−88−3 Toluene
ACGIH TLV
50 ppm (Skin)
22 mm
OSHA PEL
100 ppm (Skin)
OSHA PEL
150 ppm (Skin) STEL
23
67−64−1 Acetone
ACGIH TLV
500 ppm
180 mm
ACGIH TLV
750 ppm STEL
OSHA PEL
1000 ppm
12
123−86−4 n−Butyl Acetate
ACGIH TLV
150 ppm
10 mm
ACGIH TLV
200 ppm STEL
OSHA PEL
150 ppm
OSHA PEL
200 ppm STEL
8
13463−67−7 Titanium Dioxide
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction
===========================================================================
Section 3 −− HAZARDS IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.

Continued on page 2

3202
page 2
===========================================================================
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
===========================================================================
Section 4 −− FIRST AID MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
EYES:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re−use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 −− FIRE FIGHTING MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
FLASH POINT
LEL
UEL
Propellant < 0 F
1.0
12.8
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self−contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build−up and possible autoignition or explosion when exposed to
extreme heat.
===========================================================================
Section 6 −− ACCIDENTAL RELEASE MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.

Continued on page 3

3202
page 3
===========================================================================
Section 7 −− HANDLING AND STORAGE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STORAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated − Do not
smoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
===========================================================================
Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
Removal of old paint by sanding, scraping or other means may generate
dust or fumes that contain lead. Exposure to lead dust or fumes may cause
brain damage or other adverse health effects, especially in children or
pregnant women. Controlling exposure to lead or other hazardous substances
requires the use of proper protective equipment, such as a properly fitted
respirator (NIOSH approved) and proper containment and cleanup. For more
information, call the National Lead Information Center at 1−800−424−LEAD
(in US) or contact your local health authority.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.

Continued on page 4

3202
page 4
===========================================================================
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
===========================================================================
Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT WEIGHT
6.54 lb/gal
783 g/l
SPECIFIC GRAVITY
0.79
BOILING POINT
<0 − 264 F
<−18 − 128 C
MELTING POINT
Not Available
VOLATILE VOLUME
90 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical)
Volatile Weight 57.89 % Less Water and Federally Exempt Solvents
===========================================================================
Section 10 −− STABILITY AND REACTIVITY
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STABILITY −− Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
===========================================================================
Section 11 −− TOXICOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, blood forming, cardiovascular and
reproductive systems.
Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung
cancer, however, such exposure levels are not attainable in the workplace.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
TOXICOLOGY DATA

Continued on page 5

3202
page 5
===========================================================================
CAS No.
Ingredient Name
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
74−98−6
Propane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
106−97−8
Butane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
108−88−3
Toluene
LC50
RAT
4HR
4000
ppm
LD50
RAT
5000
mg/kg
67−64−1
Acetone
LC50
RAT
4HR
Not Available
LD50
RAT
5800
mg/kg
123−86−4
n−Butyl Acetate
LC50
RAT
4HR
2000
ppm
LD50
RAT
13100
mg/kg
13463−67−7
Titanium Dioxide
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
===========================================================================
Section 12 −− ECOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ECOTOXICOLOGICAL INFORMATION
No data available.
===========================================================================
Section 13 −− DISPOSAL CONSIDERATIONS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.
===========================================================================
Section 14 −− TRANSPORT INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
No data available.
===========================================================================
Section 15 −− REGULATORY INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
108−88−3 Toluene
19
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.

Continued on page 6

3202
page 6
===========================================================================
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
===========================================================================
Section 16 −− OTHER INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

FICHE SIGNALÉTIQUE SANTÉ-SÉCURITÉ
460505
02 00
Section 1 -- IDENTIFICATION DU PRODUIT ET DE LA SOCIÉTÉ
NUMÉRO DU PRODUIT
DATE DE PRÉPARATION
Santé
460505
29-SEP-07
Inflammabilité
Réactivité
NOM DU PRODUIT
COLOUR ALL Spray Paint, Gloss Black

2*
3
0

NOM DU FABRICANT
SHERWIN-WILLIAMS CANADA, INC.
DUPLI-COLOR Products Group
Vaughan, ON L4K 4T8
NUMÉROS DE TÉLÉPHONES ET SITES WEB
Renseignements sur le produit
(905) 761-9185
Renseignements réglementaires
(216) 566-2902
www.paintdocs.com
Urgence médicale
(216) 566-2917
Urgence de transport
pour une urgence chimique SEULEMENT
(800) 424-9300
(déversement, fuite, incendie, exposition
ou accident)
Section 2 -- COMPOSITION/INFORMATION SUR LES INGRÉDIENTS
CAS No. INGREDIENT
UNITÉS
PRESSION VAPEUR
74-98-6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
106-97-8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
108-88-3 Toluène
ACGIH TLV
20 ppm
22 mm
OSHA PEL
100 ppm (Peau)
OSHA PEL
150 ppm (Peau) STEL
67-64-1 Acetone
ACGIH TLV
500 ppm
180 mm
ACGIH TLV
750 ppm STEL
OSHA PEL
1000 ppm
763-69-9 3-Éthoxypropionate d'éthyle
ACGIH TLV Pas Disponible
1.11 mm
OSHA PEL Pas Disponible
1333-86-4 Noir de Carbone
ACGIH TLV
3.5 mg/m3
OSHA PEL
3.5 mg/m3

% EN POIDS
14
13
21

40

3
0.4

Suite à la page 2

460505

page 2

Section 3 -- IDENTIFICATION DES RISQUES
SOURCES D'EXPOSITION
L'exposition peut se produire par l'INHALATION des vapeurs ou du
brouillard de pulvérisation.
La PEAU et les YEUX peuvent entrer en contact avec le produit, les
vapeurs ou le brouillard de pulvérisation.
EFFET DE LA SUREXPOSITION
YEUX: Irritation des YEUX.
PEAU: L'exposition prolongée ou répétée risque de provoquer
l'irritation des peau.
INHALATION: Irritation des voies respiratoires supérieures.
Peut causer la dépression nerveuse. Une sur-exposition excessive à ce
produit peut entrainer la perte de conscience, voire même la mort.
L'exposition, excessive et prolongée, aux solvants de la 2 section peut
entrainer de mauvaises conséquences aux systèmes du fois, urinaire,
cardio-vasculaire et reproductif.
SYMPTÔMES DE SUREXPOSITION
Les maux de tête, l'étourdissement, la nausée et la perte de
coordination des mouvements sont tous des symptômes d'exposition excessive
aux vapeurs ou à la brume de pulvérisation.
La rougeur et les démangeaisons ou la sensation de brûlure peuvent
indiquer une exposition excessive des yeux ou de la peau.
ETAT DE SANTÉ AGGRAVÉ PAR EXPOSITION
En général, aucun exposition n'est reconnue.
CANCÉROGÉNICITÉ
Voir la Section 11.
Section 4 -- PREMIERS SOINS
YEUX:
PEAU:

INHALATION:
INGESTION:

Rincer les yeux à grande eau pendant 15 minutes.
Aller voir un médecin.
Laver à fond les parties affectées avec de l'eau et
du savon.
Enlever les habits contaminés et les laver avant de les
porter de nouveau.
Si une personne en est affectée, l'aider à sortir
des lieux. Rétablir la respiration. Aider la
personne á rester calme et au chaud.
N'incitez pas la personne á vomir.
Aller voir un médecin immédiatement.

Section 5 -- MESURES EN CAS D'INCENDIE
POINT D'ÉCLAIR
LIE
LSE
Propellant < 0 F
1.0
12.8
MOYENS D'EXTINCTION
Dioxyde de carbone, produit chimique sec, mousse

Suite à la page 3

460505

page 3

DANGERS D'INCENDIE OU D'EXPLOSION EXCEPTIONNELS
Les contenants peuvent exploser s'ils sont exposés à une très grande
chaleur.
L'application aux surfaces chaudes exige qu'on prenne des précautions
spéciales.
En cas d'urgence, une exposition excessive aux produits de décomposition
peut constituer un danger pour la santé. Les symptômes peuvent ne pas se
manifester immédiatement. Voir le médecin.
MESURES PARTICULIÉRES DI PROTECTION CONTRE L'INCENDIE
On doit utiliser l'équipement de protection complète y compris un
appareil de respiration auto-alimenté.
La pulvérisation avec de l'eau peut être inefficace. Si on se sert de
l'eau, l'ajutage pour brume est préférable. On peut se servir de l'eau
pour refroidir les contenants fermés afin d'empêcher l'augmentation de la
pression et la possibilité d'une combustion automatique ou l'explosion en
cas d'exposition à une chaleur extrêmement grande.
Section 6 -- MARCHE Á SUIVRE EN CAS DE DÉVERSEMENT ACCIDENTEL
MESURES À PRENDRE LORSQUE DES MATIÉRES SONT RENVERSÉES OU ÉVAPORÉES
Enlever toute source de combustion. Bien aérer.
Nettoyer avec un absorbant non réactif.
Section 7 -- MANUTENTION ET ENTREPOSAGE
CATÉGORIE D'ENTREPOSAGE
Pas Disponible
PRÉCAUTIONS Á PRENDRE LORS DE L'ENTREPOSAGE DI LA MANIPULATION
Tenir loin de la chaleur, étincelles et de flamme nue. Les vapeurs
peuvent s'accumuler rapidement et s'enflammer et causer une explosion.
Aucours de l'utilisation de ce produit jusqu'à la disparution de toutes
les vapeurs: Garder l'endroit bien aéré. Eviter de fumer. Eteindre toute
flamme, veilleuse d'appareils et réchauds. Couper la courant des poêles,
des outils et appareils éléctriques ainsi que de toute autre source de
combustion.
Suivre les procédures approuvées pour attacher solidement et pour
permettre l'écoulement de l'éléctricité dans le sol.
Contenu sous pression. Ne pas ouvrir, incinérer ou exposer à des
températures au dessus de 120 Fahrenheit. La chaleur des rayons du soleil,
des radiateurs, des réchauds, de l'eau chaude, ou provenant de toute autre
source, peut provoquer l'explosion du contenant. Ne pas avaler. Garder
hors de la portée des enfants.

Suite à la page 4

460505

page 4

Section 8 -- CONTRÔLE DE L'EXPOSITION ET PROTECTION INDIVIDUELLE
PRÉCAUTIONS À PRENDRE AUCOURS DE L'UTILISATION
N'utiliser ce produit que dans un endroit bien aéré.
Éviter tout contact avec la peau et les yeux. Eviter d'aspirer les
vapeurs et la brume de vaporisation.
Bien se laver les mains après l'utilisation.
Ce produit peut contenir des matières classifiées comme petites
particules irritantes, telles que le dioxyde de titane ou le carbonate de
calcium (voir la liste ACGIH TLV, la préface et l'annexe D). On peut avoir
ces particules dans des proportions dangereuses uniquement au moment du
grattement et de l'éraflement de la couche séchée. Si la liste dans la 2e
section ne fait aucune mention spécifique de la présence des poussières de
particules, les limites applicables sont: pour ACGIH TLV 10 mg/m3
(concentration totale de poussière), 3 mg/m3 (fractionée de respiratoire).
VENTILATION
Un système permettant l'échappement local des produits est préférable.
Si l'exposition aux produits de la 2e section est maintenue au-dessous des
limites d'exposition applicables, le système d'échappement global est
acceptable.
PROTECTION DES VOIES RESPIRATOIRES
Si on ne peut pas maintenir, par simple ventilation, le niveau auquel on
s'expos personnellement en dessous des limites applicables, porter un
respirateur à filtre de vapeur organique et particules approprié et bien
ajusté approuvé par NIOSH/MSHA pour se protéger contre les produits de la
2e section.
Pendant que vous frottez ou poncez la couche sechée, porter un
respirateur à filtre de poussière et de brume, approuvé par NIOSH/MSHA pour
vous protéger contre la poussière qui peut éventuellement se dégager de ce
produit, de la peinture ou de l'abrasif.
GANTS PROTECTEURS
Aucun n'est exigé pour l'application normale des produits aérosol,
lorsqu'on n'attend qu'un minimum de contact avec la peau. Pour un contact
prolongé et repété, portez des gants resistants aux produits chimiques.
LUNETTES DE SÉCURITÉ
Porter les lunetttes de sécurité avec des protecteurs latéraux non
perforés.
AUTRES PRÉCAUTIONS
L'utilisation inappropriée de ce produit en le concentrant et en
l'aspirant intentionnellement peut être dangereuse ou peut même causer la
mort.
Section 9 -- PROPRIÉTÉS PHYSIQUES ET CHIMIQUES
POIDS DU PRODUIT
DENSITÉ
COURBE D'ÉBULLITION
POINT DE FUSION
VOLUME VOLATIL
VITESSE D'ÉVAPORATION
DENSITÉ DE LA VAPEUR
SOLUBILITÉ DANS L'EAU
pH

Suite à la page 5

6.08 lb/gal
728 g/l
0.73
<0 - 342 F
<-18 - 172 C
P.D.
94 %
Plus vite que l'Éther
Plus lourd que l'Air
P.D.
7.0

460505

page 5

COMPOSÉS ORGANIQUES VOLATILS (Théorique)
Volatil Poids 51.59% Moins d'eau et de solvants exemptés
Section 10 -- STABILITÉ ET RÉACTIVITÉ
STABILITÉ -- Stable
CONDITIONS À ÉVITER
Aucun connu.
INCOMPATIBILITÉ
Aucun connu.
PRODUITS DANGEREUX DÛ À LA DÉCOMPOSITION
Par combustion: Dioxyde de carbone, monoxyde de carbone
POLYMÉRISATION DANGEREUSE
Ne Peut Pas De Produire
Section 11 -- DONNÉES TOXICOLOGIQUES
RISQUES DE SANTÉ CHRONIQUES
Il existe des rapports de recherches qui associent des troubles
permanentes du cerveau et du système nerveux à l'exposition excessive,
répétée et prolongée aux solvants.
Le carbone noir est classifié par l'IARC comme étant possiblement
carcinogène aux humains (groupe 2B) basé sur des données animales
expérimentales. Cependant, dans les humains, l'évidence de carcinogénéité
est insuffisante.
INFORMATION TOXICOLOGIQUE
CAS No.
Ingredient
74-98-6
Propane
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
106-97-8
Butane
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
108-88-3
Toluène
LC50
RAT
4HR
4000
ppm
LD50
RAT
5000
mg/kg
67-64-1
Acetone
LC50
RAT
4HR
Pas Disponible
LD50
RAT
5800
mg/kg
763-69-9
3-Éthoxypropionate d'éthyle
LC50
RAT
4HR
Pas Disponible
LD50
RAT
5000
mg/kg
1333-86-4
Noir de Carbone
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
Section 12 -- DONNÉES ÉCOLOGIQUES
Aucunes donnies disponibles.

Suite à la page 6

460505

page 6

Section 13 -- DONNÉES SUR L'ÉLIMINATION DU PRODUIT
MÉTHODE D'ÉLIMINATION DES DÉCHETS
Les déchets provenant de ce produit peuvent être dangereux, selon la
définition donnée dans la "U.S. Resource Conservation and Recovery Act"
(RCRA) 40 CFR 261.
On doit soumettre les déchets au test de combustion afin de déterminer
les numéros de l'EPA applicables.
Ne pas incinérer. Eliminer la pression dans le contenant. Se
débarrasser du contenu confermément aux lois anti-pollution fédérales,
provinciales et municipales.
Section 14 -- DONNÉES SUR LE TRANSPORT
US Ground (DOT)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126)
Canada (TDG)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126)
IMO
May be shipped as Limited Quantity
UN1950, AEROSOLS, CLASS 2, LIMITED QUANTITY, EmS F-D, S-U
Section 15 -- DONNÉES SUR LA RÉGLEMENTATION
SARA 313 (40 CFR 372.65C) AVIS DE FOURNISSEUR
CAS No.
CHIMIQUE/COMPOSÉ
108-88-3 Toluène

% by WT
21

% Element

DONNÉES SUR LA TSCA
Tous les produits chimiques dans ce produit sont énumérés, ou exemptez
de l'énumération, sur le inventaire de TSCA.
Section 16 -- AUTRES DONNÉES
Cette FTSS a été préparée conformént aux exigences du SIMDUT; les
données sont toutefois présentées sous 16 rubriques.

Les renseignements donnés ci-haut se rapportent à ce produit suivant sa
formule actuelle et s'appuient sur les données disponibles en ce moment.
L'addition de diluant et autres additifs peut changer considérablement les
risques associés à ce produit et sa composition. Etant donné que nous
n'avons pas de contrôle sur les conditions d'utilisation, nous ne donnons
aucune guarantie, explicite ou implicite et nous n'assumons aucune
responsabilité concernant l'usage, quel qu'il soit, de ces renseignements.

368
01 00

MATERIAL SAFETY DATA SHEET

===========================================================================
Section 1 −− PRODUCT AND COMPANY IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT NUMBER
HMIS CODES
Health
2
368
Flammability
4
Reactivity
0
PRODUCT NAME
KRYLON* WEEKEND* Spray Paint, Almond
MANUFACTURER’S NAME
EMERGENCY TELEPHONE NO.
THE SHERWIN−WILLIAMS COMPANY
(216) 566−2917
Diversified Brands
Cleveland, OH 44115
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
01−JUL−06
(800) 247−3266
===========================================================================
Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
14
74−98−6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
13
106−97−8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
19
108−88−3 Toluene
ACGIH TLV
50 ppm (Skin)
22 mm
OSHA PEL
100 ppm (Skin)
OSHA PEL
150 ppm (Skin) STEL
39
67−64−1 Acetone
ACGIH TLV
500 ppm
180 mm
ACGIH TLV
750 ppm STEL
OSHA PEL
1000 ppm
2
763−69−9 Ethyl 3−Ethoxypropionate
ACGIH TLV Not Available
1.11 mm
OSHA PEL Not Available
2
13463−67−7 Titanium Dioxide
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction
===========================================================================
Section 3 −− HAZARDS IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
Continued on page 2

368
page 2
===========================================================================
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
===========================================================================
Section 4 −− FIRST AID MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
EYES:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re−use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 −− FIRE FIGHTING MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
FLASH POINT
LEL
UEL
Propellant < 0 F
1.0
12.8
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self−contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build−up and possible autoignition or explosion when exposed to
extreme heat.
===========================================================================
Section 6 −− ACCIDENTAL RELEASE MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
===========================================================================
Section 7 −− HANDLING AND STORAGE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STORAGE CATEGORY
Not Available

Continued on page 3

368
page 3
===========================================================================
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated − Do not
smoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
===========================================================================
Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.

Continued on page 4

368
page 4
===========================================================================
Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT WEIGHT
6.22 lb/gal
745 g/l
SPECIFIC GRAVITY
0.75
BOILING POINT
<0 − 342 F
<−18 − 172 C
MELTING POINT
Not Available
VOLATILE VOLUME
93 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical − As Packaged)
Volatile Weight 48.54% Less Water and Federally Exempt Solvents
===========================================================================
Section 10 −− STABILITY AND REACTIVITY
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STABILITY −− Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
===========================================================================
Section 11 −− TOXICOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, cardiovascular and reproductive
systems.
Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung
cancer, however, such exposure levels are not attainable in the workplace.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
TOXICOLOGY DATA

Continued on page 5

368
page 5
===========================================================================
CAS No.
Ingredient Name
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
74−98−6
Propane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
106−97−8
Butane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
108−88−3
Toluene
LC50
RAT
4HR
4000
ppm
LD50
RAT
5000
mg/kg
67−64−1
Acetone
LC50
RAT
4HR
Not Available
LD50
RAT
5800
mg/kg
763−69−9
Ethyl 3−Ethoxypropionate
LC50
RAT
4HR
Not Available
LD50
RAT
5000
mg/kg
13463−67−7
Titanium Dioxide
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
===========================================================================
Section 12 −− ECOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ECOTOXICOLOGICAL INFORMATION
No data available.
===========================================================================
Section 13 −− DISPOSAL CONSIDERATIONS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.
===========================================================================
Section 14 −− TRANSPORT INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
No data available.
===========================================================================
Section 15 −− REGULATORY INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
108−88−3 Toluene
19
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.

Continued on page 6

368
page 6
===========================================================================
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
===========================================================================
Section 16 −− OTHER INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

368
01 00

MATERIAL SAFETY DATA SHEET

===========================================================================
Section 1 −− PRODUCT AND COMPANY IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT NUMBER
HMIS CODES
Health
2
368
Flammability
4
Reactivity
0
PRODUCT NAME
KRYLON* WEEKEND* Spray Paint, Almond
MANUFACTURER’S NAME
EMERGENCY TELEPHONE NO.
THE SHERWIN−WILLIAMS COMPANY
(216) 566−2917
Diversified Brands
Cleveland, OH 44115
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
01−JUL−06
(800) 247−3266
===========================================================================
Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
14
74−98−6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
13
106−97−8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
19
108−88−3 Toluene
ACGIH TLV
50 ppm (Skin)
22 mm
OSHA PEL
100 ppm (Skin)
OSHA PEL
150 ppm (Skin) STEL
39
67−64−1 Acetone
ACGIH TLV
500 ppm
180 mm
ACGIH TLV
750 ppm STEL
OSHA PEL
1000 ppm
2
763−69−9 Ethyl 3−Ethoxypropionate
ACGIH TLV Not Available
1.11 mm
OSHA PEL Not Available
2
13463−67−7 Titanium Dioxide
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction
===========================================================================
Section 3 −− HAZARDS IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
Continued on page 2

368
page 2
===========================================================================
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
===========================================================================
Section 4 −− FIRST AID MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
EYES:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re−use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 −− FIRE FIGHTING MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
FLASH POINT
LEL
UEL
Propellant < 0 F
1.0
12.8
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self−contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build−up and possible autoignition or explosion when exposed to
extreme heat.
===========================================================================
Section 6 −− ACCIDENTAL RELEASE MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
===========================================================================
Section 7 −− HANDLING AND STORAGE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STORAGE CATEGORY
Not Available

Continued on page 3

368
page 3
===========================================================================
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated − Do not
smoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
===========================================================================
Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.

Continued on page 4

368
page 4
===========================================================================
Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT WEIGHT
6.22 lb/gal
745 g/l
SPECIFIC GRAVITY
0.75
BOILING POINT
<0 − 342 F
<−18 − 172 C
MELTING POINT
Not Available
VOLATILE VOLUME
93 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical − As Packaged)
Volatile Weight 48.54% Less Water and Federally Exempt Solvents
===========================================================================
Section 10 −− STABILITY AND REACTIVITY
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STABILITY −− Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
===========================================================================
Section 11 −− TOXICOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, cardiovascular and reproductive
systems.
Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung
cancer, however, such exposure levels are not attainable in the workplace.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
TOXICOLOGY DATA

Continued on page 5

368
page 5
===========================================================================
CAS No.
Ingredient Name
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
74−98−6
Propane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
106−97−8
Butane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
108−88−3
Toluene
LC50
RAT
4HR
4000
ppm
LD50
RAT
5000
mg/kg
67−64−1
Acetone
LC50
RAT
4HR
Not Available
LD50
RAT
5800
mg/kg
763−69−9
Ethyl 3−Ethoxypropionate
LC50
RAT
4HR
Not Available
LD50
RAT
5000
mg/kg
13463−67−7
Titanium Dioxide
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
===========================================================================
Section 12 −− ECOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ECOTOXICOLOGICAL INFORMATION
No data available.
===========================================================================
Section 13 −− DISPOSAL CONSIDERATIONS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.
===========================================================================
Section 14 −− TRANSPORT INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
No data available.
===========================================================================
Section 15 −− REGULATORY INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
108−88−3 Toluene
19
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.

Continued on page 6

368
page 6
===========================================================================
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
===========================================================================
Section 16 −− OTHER INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

368
01 00

MATERIAL SAFETY DATA SHEET

===========================================================================
Section 1 −− PRODUCT AND COMPANY IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT NUMBER
HMIS CODES
Health
2
368
Flammability
4
Reactivity
0
PRODUCT NAME
KRYLON* WEEKEND* Spray Paint, Almond
MANUFACTURER’S NAME
EMERGENCY TELEPHONE NO.
THE SHERWIN−WILLIAMS COMPANY
(216) 566−2917
Diversified Brands
Cleveland, OH 44115
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
01−JUL−06
(800) 247−3266
===========================================================================
Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
14
74−98−6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
13
106−97−8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
19
108−88−3 Toluene
ACGIH TLV
50 ppm (Skin)
22 mm
OSHA PEL
100 ppm (Skin)
OSHA PEL
150 ppm (Skin) STEL
39
67−64−1 Acetone
ACGIH TLV
500 ppm
180 mm
ACGIH TLV
750 ppm STEL
OSHA PEL
1000 ppm
2
763−69−9 Ethyl 3−Ethoxypropionate
ACGIH TLV Not Available
1.11 mm
OSHA PEL Not Available
2
13463−67−7 Titanium Dioxide
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction
===========================================================================
Section 3 −− HAZARDS IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
Continued on page 2

368
page 2
===========================================================================
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
===========================================================================
Section 4 −− FIRST AID MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
EYES:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re−use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 −− FIRE FIGHTING MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
FLASH POINT
LEL
UEL
Propellant < 0 F
1.0
12.8
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self−contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build−up and possible autoignition or explosion when exposed to
extreme heat.
===========================================================================
Section 6 −− ACCIDENTAL RELEASE MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
===========================================================================
Section 7 −− HANDLING AND STORAGE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STORAGE CATEGORY
Not Available

Continued on page 3

368
page 3
===========================================================================
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated − Do not
smoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
===========================================================================
Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.

Continued on page 4

368
page 4
===========================================================================
Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT WEIGHT
6.22 lb/gal
745 g/l
SPECIFIC GRAVITY
0.75
BOILING POINT
<0 − 342 F
<−18 − 172 C
MELTING POINT
Not Available
VOLATILE VOLUME
93 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical − As Packaged)
Volatile Weight 48.54% Less Water and Federally Exempt Solvents
===========================================================================
Section 10 −− STABILITY AND REACTIVITY
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STABILITY −− Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
===========================================================================
Section 11 −− TOXICOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, cardiovascular and reproductive
systems.
Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung
cancer, however, such exposure levels are not attainable in the workplace.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
TOXICOLOGY DATA

Continued on page 5

368
page 5
===========================================================================
CAS No.
Ingredient Name
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
74−98−6
Propane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
106−97−8
Butane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
108−88−3
Toluene
LC50
RAT
4HR
4000
ppm
LD50
RAT
5000
mg/kg
67−64−1
Acetone
LC50
RAT
4HR
Not Available
LD50
RAT
5800
mg/kg
763−69−9
Ethyl 3−Ethoxypropionate
LC50
RAT
4HR
Not Available
LD50
RAT
5000
mg/kg
13463−67−7
Titanium Dioxide
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
===========================================================================
Section 12 −− ECOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ECOTOXICOLOGICAL INFORMATION
No data available.
===========================================================================
Section 13 −− DISPOSAL CONSIDERATIONS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.
===========================================================================
Section 14 −− TRANSPORT INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
No data available.
===========================================================================
Section 15 −− REGULATORY INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
108−88−3 Toluene
19
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.

Continued on page 6

368
page 6
===========================================================================
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
===========================================================================
Section 16 −− OTHER INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

CW01024
01 00

MATERIAL SAFETY DATA SHEET

===========================================================================
Section 1 −− PRODUCT AND COMPANY IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT NUMBER
HMIS CODES
Health
2*
CW01024
Flammability
4
Reactivity
0
PRODUCT NAME
COLORWORKS* from KRYLON* Interior/Exterior Spray Paint, Flat Black
MANUFACTURER’S NAME
EMERGENCY TELEPHONE NO.
THE SHERWIN−WILLIAMS COMPANY
(216) 566−2917
KRYLON Products Group
Cleveland, OH 44115
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
30−JUL−05
(800) 832−2541
===========================================================================
Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
18
74−98−6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
17
106−97−8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
3
64742−89−8 Lt. Aliphatic Hydrocarbon Solvent
ACGIH TLV
100 ppm
53 mm
OSHA PEL
100 ppm
5
64742−89−8 V. M. & P. Naphtha
ACGIH TLV
300 ppm
12 mm
OSHA PEL
300 ppm
OSHA PEL
400 ppm STEL
11
108−88−3 Toluene
ACGIH TLV
50 ppm (Skin)
22 mm
OSHA PEL
100 ppm (Skin)
OSHA PEL
150 ppm (Skin) STEL
0.1
100−41−4 Ethylbenzene
ACGIH TLV
100 ppm
7.1 mm
ACGIH TLV
125 ppm STEL
OSHA PEL
100 ppm
OSHA PEL
125 ppm STEL
1
111−76−2 2−Butoxyethanol
ACGIH TLV
20 ppm
0.88 mm
OSHA PEL
25 ppm
23
67−64−1 Acetone
ACGIH TLV
500 ppm
180 mm
ACGIH TLV
750 ppm STEL
OSHA PEL
1000 ppm
11
14807−96−6 Talc
ACGIH TLV
2 mg/m3 as Resp. Dust
OSHA PEL
2 mg/m3 as Resp. Dust
Continued on page 2

CW01024
page 2
===========================================================================
0.4
1333−86−4 Carbon Black
ACGIH TLV
3.5 mg/m3
OSHA PEL
3.5 mg/m3
===========================================================================
Section 3 −− HAZARDS IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
===========================================================================
Section 4 −− FIRST AID MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
EYES:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re−use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 −− FIRE FIGHTING MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
FLASH POINT
LEL
UEL
Propellant < 0 F
0.9
12.8
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.

Continued on page 3

CW01024
page 3
===========================================================================
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self−contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build−up and possible autoignition or explosion when exposed to
extreme heat.
===========================================================================
Section 6 −− ACCIDENTAL RELEASE MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
===========================================================================
Section 7 −− HANDLING AND STORAGE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STORAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated − Do not
smoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
===========================================================================
Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
Removal of old paint by sanding, scraping or other means may generate
dust or fumes that contain lead. Exposure to lead dust or fumes may cause
brain damage or other adverse health effects, especially in children or
pregnant women. Controlling exposure to lead or other hazardous substances
requires the use of proper protective equipment, such as a properly fitted
respirator (NIOSH approved) and proper containment and cleanup. For more
information, call the National Lead Information Center at 1−800−424−LEAD
(in US) or contact your local health authority.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
Continued on page 4

CW01024
page 4
===========================================================================
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
===========================================================================
Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT WEIGHT
6.22 lb/gal
745 g/l
SPECIFIC GRAVITY
0.75
BOILING POINT
<0 − 343 F
<−18 − 172 C
MELTING POINT
Not Available
VOLATILE VOLUME
90 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical)
Volatile Weight 57.23 % Less Water and Federally Exempt Solvents
===========================================================================
Section 10 −− STABILITY AND REACTIVITY
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STABILITY −− Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur

Continued on page 5

CW01024
page 5
===========================================================================
Section 11 −− TOXICOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
CHRONIC HEALTH HAZARDS
Ethylbenzene is classified by IARC as possibly carcinogenic to humans
(2B) based on inadequate evidence in humans and sufficient evidence in
laboratory animals.
Lifetime inhalation exposure of rats and mice to high
ethylbenzene concentrations resulted in increases in certain types of
cancer, including kidney tumors in rats and lung and liver tumors in mice.
These effects were not observed in animals exposed to lower concentrations.
There is no evidence that ethylbenzene causes cancer in humans.
Carbon Black is classified by IARC as possibly carcinogenic to humans
(group 2B) based on experimental animal data, however, there is
insufficient evidence in humans for its carcinogenicity.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, blood forming, cardiovascular and
reproductive systems.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
TOXICOLOGY DATA
CAS No.
Ingredient Name
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
74−98−6
Propane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
106−97−8
Butane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
64742−89−8
Lt. Aliphatic Hydrocarbon Solvent
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
64742−89−8
V. M. & P. Naphtha
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
108−88−3
Toluene
LC50
RAT
4HR
4000
ppm
LD50
RAT
5000
mg/kg
100−41−4
Ethylbenzene
LC50
RAT
4HR
Not Available
LD50
RAT
3500
mg/kg
111−76−2
2−Butoxyethanol
LC50
RAT
4HR
Not Available
LD50
RAT
470
mg/kg
67−64−1
Acetone
LC50
RAT
4HR
Not Available
LD50
RAT
5800
mg/kg
14807−96−6
Talc
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
1333−86−4
Carbon Black
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available

Continued on page 6

CW01024
page 6
===========================================================================
Section 12 −− ECOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ECOTOXICOLOGICAL INFORMATION
No data available.
===========================================================================
Section 13 −− DISPOSAL CONSIDERATIONS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.
===========================================================================
Section 14 −− TRANSPORT INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
No data available.
===========================================================================
Section 15 −− REGULATORY INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
108−88−3 Toluene
11
100−41−4 Ethylbenzene
0.1
Glycol Ethers
1
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
===========================================================================
Section 16 −− OTHER INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

MATERIAL SAFETY DATA SHEET
M103
03 00
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER
DATE OF PREPARATION
HMIS CODES
Health
M103
30-SEP-07
Flammability
Reactivity
PRODUCT NAME
Spray Paint, Aluminum

2*
3
1

MANUFACTURER'S NAME
SHERWIN-WILLIAMS CANADA, INC.
200 Confederation Pkwy
Vaughan, ON L4K 4T8
TELEPHONE NUMBERS and WEBSITES
Product Information
(905) 761-9185
Regulatory Information
(216) 566-2902
www.paintdocs.com
Medical Emergency
(216) 566-2917
Transportation Emergency
for Chemical Emergency ONLY (spill, leak,
(800) 424-9300
fire, exposure, or accident)
% by WT
16
16
1
34

0.4

2

Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
74-98-6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
106-97-8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
64742-88-7 Mineral Spirits
ACGIH TLV
100 ppm
2 mm
OSHA PEL
100 ppm
108-88-3 Toluene
ACGIH TLV
20 ppm
22 mm
OSHA PEL
100 ppm (Skin)
OSHA PEL
150 ppm (Skin) STEL
100-41-4 Ethylbenzene
ACGIH TLV
100 ppm
7.1 mm
ACGIH TLV
125 ppm STEL
OSHA PEL
100 ppm
OSHA PEL
125 ppm STEL
1330-20-7 Xylene
ACGIH TLV
100 ppm
5.9 mm
ACGIH TLV
150 ppm STEL
OSHA PEL
100 ppm
OSHA PEL
150 ppm STEL

Continued on page 2

M103
10

page 2
67-64-1

Acetone
ACGIH TLV
ACGIH TLV
OSHA PEL

500
750
1000

ppm
ppm STEL
ppm

180 mm

Section 3 -- HAZARDS IDENTIFICATION
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, cardiovascular and reproductive
systems.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
Section 4 -- FIRST AID MEASURES
EYES:
SKIN:
INHALATION:
INGESTION:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
Do not induce vomiting.
Get medical attention immediately.

Section 5 -- FIRE FIGHTING MEASURES
FLASH POINT
LEL
UEL
Propellant < 0 F
1.0
12.8
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.

Continued on page 3

M103

page 3

SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.
Section 6 -- ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
Section 7 -- HANDLING AND STORAGE
STORAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated - Do not
smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
Removal of old paint by sanding, scraping or other means may generate
dust or fumes that contain lead. Exposure to lead dust or fumes may cause
brain damage or other adverse health effects, especially in children or
pregnant women. Controlling exposure to lead or other hazardous substances
requires the use of proper protective equipment, such as a properly fitted
respirator (NIOSH approved) and proper containment and cleanup. For more
information, call the National Lead Information Center at 1-800-424-LEAD
(in US) or contact your local health authority.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.

Continued on page 4

M103

page 4

RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT WEIGHT
6.24 lb/gal
747 g/l
SPECIFIC GRAVITY
0.75
BOILING POINT
<0 - 395 F
<-18 - 201 C
MELTING POINT
Not Available
VOLATILE VOLUME
87 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
Volatile Weight 69.51% Less Water and Federally Exempt Solvents
Section 10 -- STABILITY AND REACTIVITY
STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur

Continued on page 5

M103

page 5

Section 11 -- TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
Ethylbenzene is classified by IARC as possibly carcinogenic to humans
(2B) based on inadequate evidence in humans and sufficient evidence in
laboratory animals. Lifetime inhalation exposure of rats and mice to high
ethylbenzene concentrations resulted in increases in certain types of
cancer, including kidney tumors in rats and lung and liver tumors in mice.
These effects were not observed in animals exposed to lower concentrations.
There is no evidence that ethylbenzene causes cancer in humans.
TOXICOLOGY DATA
CAS No.
Ingredient Name
74-98-6
Propane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
106-97-8
Butane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
64742-88-7
Mineral Spirits
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
108-88-3
Toluene
LC50
RAT
4HR
4000
ppm
LD50
RAT
5000
mg/kg
100-41-4
Ethylbenzene
LC50
RAT
4HR
Not Available
LD50
RAT
3500
mg/kg
1330-20-7
Xylene
LC50
RAT
4HR
5000
ppm
LD50
RAT
4300
mg/kg
67-64-1
Acetone
LC50
RAT
4HR
Not Available
LD50
RAT
5800
mg/kg
Section 12 -- ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
No data available.
Section 13 -- DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.

Continued on page 6

M103

page 6

Section 14 -- TRANSPORT INFORMATION
US Ground (DOT)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126)
Canada (TDG)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126)
IMO
May be shipped as Limited Quantity
UN1950, AEROSOLS, CLASS 2, LIMITED QUANTITY, EmS F-D, S-U
Section 15 -- REGULATORY INFORMATION
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
108-88-3 Toluene
100-41-4 Ethylbenzene
1330-20-7 Xylene

% by WT
34
0.3
2

% Element

TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
Section 16 -- OTHER INFORMATION
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

MATERIAL SAFETY DATA SHEET
DSCC362
02 00
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER
DATE OF PREPARATION
HMIS CODES
Health
DSCC362
29-SEP-07
Flammability
Reactivity
PRODUCT NAME
AUTO SPRAY® Paint, Bright White

2*
3
0

MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS CO.
DUPLI-COLOR Products Group
Cleveland, OH 44115
TELEPHONE NUMBERS and WEBSITES
Product Information
(800) 247-3270
www.duplicolor.com
Regulatory Information
(216) 566-2902
www.paintdocs.com
Medical Emergency
(216) 566-2917
Transportation Emergency
for Chemical Emergency ONLY (spill, leak,
(800) 424-9300
fire, exposure, or accident)
% by WT
10
10
9

1
40

7

8

Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
74-98-6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
106-97-8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
108-88-3 Toluene
ACGIH TLV
20 ppm
22 mm
OSHA PEL
100 ppm (Skin)
OSHA PEL
150 ppm (Skin) STEL
64-17-5 Ethanol
ACGIH TLV
1000 ppm
44 mm
OSHA PEL
1000 ppm
67-64-1 Acetone
ACGIH TLV
500 ppm
180 mm
ACGIH TLV
750 ppm STEL
OSHA PEL
1000 ppm
78-93-3 Methyl Ethyl Ketone
ACGIH TLV
200 ppm
70 mm
ACGIH TLV
300 ppm STEL
OSHA PEL
200 ppm
OSHA PEL
300 ppm STEL
763-69-9 Ethyl 3-Ethoxypropionate
ACGIH TLV Not Available
1.11 mm
OSHA PEL Not Available

Continued on page 2

DSCC362
4

page 2

13463-67-7

Titanium Dioxide
ACGIH TLV
OSHA PEL
OSHA PEL

10
10
5

mg/m3 as Dust
mg/m3 Total Dust
mg/m3 Respirable Fraction

Section 3 -- HAZARDS IDENTIFICATION
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, cardiovascular and reproductive
systems.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
Section 4 -- FIRST AID MEASURES
EYES:
SKIN:
INHALATION:
INGESTION:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
Do not induce vomiting.
Get medical attention immediately.

Section 5 -- FIRE FIGHTING MEASURES
FLASH POINT
LEL
UEL
Propellant < 0 F
1.0
19.0
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.

Continued on page 3

DSCC362

page 3

SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.
Section 6 -- ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
Section 7 -- HANDLING AND STORAGE
STORAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated - Do not
smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.

Continued on page 4

DSCC362

page 4

PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT WEIGHT
6.48 lb/gal
776 g/l
SPECIFIC GRAVITY
0.78
BOILING POINT
<0 - 342 F
<-18 - 172 C
MELTING POINT
Not Available
VOLATILE VOLUME
92 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
Volatile Weight 46.44% Less Water and Federally Exempt Solvents
Section 10 -- STABILITY AND REACTIVITY
STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
Section 11 -- TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
Methyl Ethyl Ketone may increase the nervous system effects of other
solvents.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
IARC's Monograph No. 93 reports there is sufficient evidence of
carcinogenicity in experimental rats exposed to titanium dioxide but
inadequate evidence for carcinogenicity in humans and has assigned a Group
2B rating. In addition, the IARC summary concludes, "No significant
exposure to titanium dioxide is thought to occur during the use of products
in which titanium is bound to other materials, such as paint."
TOXICOLOGY DATA

Continued on page 5

DSCC362
CAS No.
74-98-6
106-97-8
108-88-3
64-17-5
67-64-1
78-93-3
763-69-9
13463-67-7

page 5
Ingredient Name
Propane
LC50
RAT
LD50
RAT
Butane
LC50
RAT
LD50
RAT
Toluene
LC50
RAT
LD50
RAT
Ethanol
LC50
RAT
LD50
RAT
Acetone
LC50
RAT
LD50
RAT
Methyl Ethyl Ketone
LC50
RAT
LD50
RAT
Ethyl 3-Ethoxypropionate
LC50
RAT
LD50
RAT
Titanium Dioxide
LC50
RAT
LD50
RAT

4HR

Not Available
Not Available

4HR

Not Available
Not Available

4HR

4000
5000

ppm
mg/kg

4HR

Not Available
7060
mg/kg

4HR

Not Available
5800
mg/kg

4HR

Not Available
2740
mg/kg

4HR

Not Available
5000
mg/kg

4HR

Not Available
Not Available

Section 12 -- ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
No data available.
Section 13 -- DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.

Continued on page 6

DSCC362

page 6

Section 14 -- TRANSPORT INFORMATION
US Ground (DOT)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126)
Canada (TDG)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126)
IMO
May be shipped as Limited Quantity
UN1950, AEROSOLS, CLASS 2, LIMITED QUANTITY, EmS F-D, S-U
Section 15 -- REGULATORY INFORMATION
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
108-88-3 Toluene

% by WT
9

% Element

CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
Section 16 -- OTHER INFORMATION
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

00861
04 00

FICHE SIGNALÉTIQUE SANTÉ−SÉCURITÉ

===========================================================================
Section 1 −− IDENTIFICATION DU PRODUIT ET DE LA SOCIÉTÉ
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
NUMÉRO DU PRODUIT
Santé
2*
00861
Inflammabilité
3
Réactivité
0
NOM DU PRODUIT
RUST TOUGH* Rust Preventive Primer, Quick Dry Gray Primer
NOM DU FABRICANT
NO. DE TÉLÉPHONE EN CAS D’URGENCE
THE SHERWIN−WILLIAMS COMPANY
(216) 566−2917
Diversified Brands
Cleveland, OH 44115
DATE DE PRÉPARATION
NO. DE TÉLÉPHONE ORDINAIRE
30−JUL−05
(800) 247−3266
===========================================================================
Section 2 −− COMPOSITION/INFORMATION SUR LES INGRÉDIENTS
% EN POIDS
CAS No. INGREDIENT
UNITÉS
PRESSION VAPEUR
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
3
100−41−4 Éthylbenzène
ACGIH TLV
100 ppm
7.1 mm
ACGIH TLV
125 ppm STEL
OSHA PEL
100 ppm
OSHA PEL
125 ppm STEL
19
1330−20−7 Xylène
ACGIH TLV
100 ppm
5.9 mm
ACGIH TLV
150 ppm STEL
OSHA PEL
100 ppm
OSHA PEL
150 ppm STEL
3
64742−95−6 Solvant Naphta Aliphatique Léger
ACGIH TLV Pas Disponible
3.8 mm
OSHA PEL Pas Disponible
3
108−67−8 1,3,5−Triméthylbenzène
ACGIH TLV
25 ppm
2 mm
OSHA PEL
25 ppm
5
95−63−6 1,2,4−Triméthylbenzène
ACGIH TLV
25 ppm
2.03 mm
OSHA PEL
25 ppm
10
14807−96−6 Talc
ACGIH TLV
2 mg/m3 de resp. poussiére
OSHA PEL
2 mg/m3 de resp. poussiére
10
471−34−1 Carbonate de Calcium
ACGIH TLV
10 mg/m3 de poussiére
OSHA PEL
15 mg/m3 total de polva
OSHA PEL
5 mg/m3 fracción respirable
8
7727−43−7 Sulfate de Baryum
ACGIH TLV
10 mg/m3 de poussiére
OSHA PEL
10 mg/m3 total de polva
OSHA PEL
5 mg/m3 fracción respirable
9
13463−67−7 Dioxyde de Titane
ACGIH TLV
10 mg/m3 de poussiére
OSHA PEL
10 mg/m3 total de polva
OSHA PEL
5 mg/m3 fracción respirable
Suite à la page 2

00861
page 2
===========================================================================
0.6
1333−86−4 Noir de Carbone
ACGIH TLV
3.5 mg/m3
OSHA PEL
3.5 mg/m3
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
3.09
Baryum (Ba; total)
===========================================================================
Section 3 −− IDENTIFICATION DES RISQUES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SOURCES D’EXPOSITION
L’exposition peut se produire par l’INHALATION des vapeurs ou du
brouillard de pulvérisation.
La PEAU et les YEUX peuvent entrer en contact avec le produit, les
vapeurs ou le brouillard de pulvérisation.
EFFET DE LA SUREXPOSITION
YEUX: Irritation des YEUX.
PEAU: L’exposition prolongée ou répétée risque de provoquer
l’irritation des peau.
INHALATION: Irritation des voies respiratoires supérieures.
Peut causer la dépression nerveuse. Une sur−exposition excessive à ce
produit peut entrainer la perte de conscience, voire même la mort.
SYMPTÔMES DE SUREXPOSITION
Les maux de tête, l’étourdissement, la nausée et la perte de
coordination des mouvements sont tous des symptômes d’exposition excessive
aux vapeurs ou à la brume de pulvérisation.
La rougeur et les démangeaisons ou la sensation de brûlure peuvent
indiquer une exposition excessive des yeux ou de la peau.
ETAT DE SANTÉ AGGRAVÉ PAR EXPOSITION
En général, aucun exposition n’est reconnue.
CANCÉROGÉNICITÉ
Voir la Section 11.
===========================================================================
Section 4 −− PREMIERS SOINS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
YEUX:

Rincer les yeux à grande eau pendant 15 minutes.
Aller voir un médecin.
PEAU: Laver à fond les parties affectées avec de l’eau et
du savon.
Enlever les habits contaminés et les laver avant de les
porter de nouveau.
INHALATION: Si une personne en est affectée, l’aider à sortir
des lieux. Rétablir la respiration. Aider la
personne á rester calme et au chaud.
INGESTION: N’incitez pas la personne á vomir.
Aller voir un médecin immédiatement.
===========================================================================
Section 5 −− MESURES EN CAS D’INCENDIE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
POINT D’ÉCLAIR
LIE
LSE
87 F PMCC
0.7
7.0
CLASSIFICATION D’INFLAMMABILITÉ
ETIQUETTE ROUGE −− Inflammable, point critique en dessous de 38 C (100
degré F)
MOYENS D’EXTINCTION
Dioxyde de carbone, produit chimique sec, mousse
Suite à la page 3

00861
page 3
===========================================================================
DANGERS D’INCENDIE OU D’EXPLOSION EXCEPTIONNELS
Les contenants fermés peuvent exploser s’ils sont exposés à une très
grande chaleur.
L’application aux surfaces chaudes exige qu’on prenne des précautions
spéciales.
En cas d’urgence, une exposition excessive aux produits de décomposition
peut constituer un danger pour la santé. Les symptômes peuvent ne pas se
manifester immédiatement. Voir le médecin.
MESURES PARTICULIÉRES DI PROTECTION CONTRE L’INCENDIE
On doit utiliser l’équipement de protection complète y compris un
appareil de respiration auto−alimenté.
La pulvérisation avec de l’eau peut être inefficace. Si on se sert de
l’eau, l’ajutage pour brume est préférable. On peut se servir de l’eau
pour refroidir les contenants fermés afin d’empêcher l’augmentation de la
pression et la possibilité d’une combustion automatique ou l’explosion en
cas d’exposition à une chaleur extrêmement grande.
===========================================================================
Section 6 −− MARCHE Á SUIVRE EN CAS DE DÉVERSEMENT ACCIDENTEL
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
MESURES À PRENDRE LORSQUE DES MATIÉRES SONT RENVERSÉES OU ÉVAPORÉES
Enlever toute source de combustion. Bien aérer.
Nettoyer avec un absorbant non réactif.
===========================================================================
Section 7 −− MANUTENTION ET ENTREPOSAGE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
CATÉGORIE D’ENTREPOSAGE
U.S. DOL Storage Class IC
PRÉCAUTIONS Á PRENDRE LORS DE L’ENTREPOSAGE DI LA MANIPULATION
CONTENU INFLAMMABLE. Tenir loin de la chaleur, des étincelles et de la
flamme nue.
Aucours de l’utilisation de ce produit jusqu’à la disparution de toutes
les vapeurs: Garder l’endroit bien aéré. Eviter de fumer. Eteindre toute
flamme, veilleuse d’appareils et réchauds. Couper la courant des poêles,
des outils et appareils éléctriques ainsi que de toute autre source de
combustion.
Suivre les procédures approuvées pour attacher solidement et pour
permettre l’écoulement de l’éléctricité dans le sol.
Garder le contenant fermé lorsqu’il n’est pas en usage. Transvaser
seulement dans des contenants approuvés et ayant des étiquettes complètes
et convenables. Ne pas avaler. Garder hors de la portée des enfants.

Suite à la page 4

00861
page 4
===========================================================================
Section 8 −− CONTRÔLE DE L’EXPOSITION ET PROTECTION INDIVIDUELLE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRÉCAUTIONS À PRENDRE AUCOURS DE L’UTILISATION
N’utiliser ce produit que dans un endroit bien aéré.
Éviter tout contact avec la peau et les yeux. Eviter d’aspirer les
vapeurs et la brume de vaporisation.
Bien se laver les mains après l’utilisation.
Ce produit peut contenir des matières classifiées comme petites
particules irritantes, telles que le dioxyde de titane ou le carbonate de
calcium (voir la liste ACGIH TLV, la préface et l’annexe D). On peut avoir
ces particules dans des proportions dangereuses uniquement au moment du
grattement et de l’éraflement de la couche séchée. Si la liste dans la 2e
section ne fait aucune mention spécifique de la présence des poussières de
particules, les limites applicables sont: pour ACGIH TLV 10 mg/m3
(concentration totale de poussière), 3 mg/m3 (fractionée de respiratoire).
VENTILATION
Un système permettant l’échappement local des produits est préférable.
Si l’exposition aux produits de la 2e section est maintenue au−dessous des
limites d’exposition applicables, le système d’échappement global est
acceptable.
PROTECTION DES VOIES RESPIRATOIRES
Si on ne peut pas maintenir, par simple ventilation, le niveau auquel on
s’expos personnellement en dessous des limites applicables, porter un
respirateur à filtre de vapeur organique et particules approprié et bien
ajusté approuvé par NIOSH/MSHA pour se protéger contre les produits de la
2e section.
Aucours du ponçage, du nettoyage à la brosse métallique, de même qu’en
frottant, en brulant, en brasant ou en soudant la couche sèche, il est
recommandé de porter un respirateur à filtre de particules, approuvé par
NIOSH/MSHA afin de se protéger contre les produits non volatils de la 2e
section.
GANTS PROTECTEURS
Porter les gants recommandés par le fournisseur de gants pour se
protéger contre les produits de la 2e section.
LUNETTES DE SÉCURITÉ
Porter les lunetttes de sécurité avec des protecteurs latéraux non
perforés.
AUTRES PRÉCAUTIONS
L’utilisation inappropriée de ce produit en le concentrant et en
l’aspirant intentionnellement peut être dangereuse ou peut même causer la
mort.

Suite à la page 5

00861
page 5
===========================================================================
Section 9 −− PROPRIÉTÉS PHYSIQUES ET CHIMIQUES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
POIDS DU PRODUIT
11.44 lb/gal
1370 g/l
DENSITÉ
1.38
COURBE D’ÉBULLITION
277 − 360 F
136 − 182 C
POINT DE FUSION
P.D.
VOLUME VOLATIL
57 %
VITESSE D’ÉVAPORATION
Plus lent que l’Éther
DENSITÉ DE LA VAPEUR
Plus lourd que l’Air
SOLUBILITÉ DANS L’EAU
P.D.
COMPOSÉS ORGANIQUES VOLATILS (Théorique)
4.12 lb/gal
494 g/l
Moins d’eau et de Solvants Exemptés
4.12 lb/gal
494 g/l
Émis COV
===========================================================================
Section 10 −− STABILITÉ ET RÉACTIVITÉ
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STABILITÉ −− Stable
CONDITIONS À ÉVITER
Aucun connu.
INCOMPATIBILITÉ
Aucun connu.
PRODUITS DANGEREUX DÛ À LA DÉCOMPOSITION
Par combustion: Dioxyde de carbone, monoxyde de carbone, oxydes des
métaux de la 2e section
POLYMÉRISATION DANGEREUSE
Ne Peut Pas De Produire
===========================================================================
Section 11 −− DONNÉES TOXICOLOGIQUES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
RISQUES DE SANTÉ CHRONIQUES
À partir de données expérimentales provenant d’études suffisantes
mendées chez les animaux et d’études insuffisantes menées chez humains,
l’éthylbenzène est classifié par le CIRC comme étant possiblement
carcinogène chez les humains (group 2B). On a constaté une augmentation de
certains types de cancer, y compris des tumeurs du rein chez les rats et
des tumeurs du poumon et du foie chez les souris, lorsque ces animaux ont
été exposés à l’inhalation de concentrations élevées d’éthylbenzène à long
terme. Toutefois, ces effets n’ont pas étéobservés chez les animaux
exposés à de plus faibles concentrations d’éthylbenzène. Jusqu’à présent
il n’y a aucune preuve suggérant que l’éthylbenzène provoque le cancer chez
les humains.
Le carbone noir est classifié par l’IARC comme étant possiblement
carcinogène aux humains (groupe 2B) basé sur des données animales
expérimentales. Cependant, dans les humains, l’évidence de carcinogénéité
est insuffisante.
L’exposition, excessive et prolongée, aux solvants de la 2 section peut
entrainer demauvaises conséquences aux systèmesdu fois,urinaire
etreproductif.
Les rats exposés à la poussière de dioxyde de titanium à une
concentrations de 250mg/m3 ont développé le cancer des poumons. Toutefois,
on ne peut pas atteindre une telle concentration en milieu du travail.
Il existe des rapports de recherches qui associent des troubles
permanentes du cerveau et du système nerveux à l’exposition excessive,
répétée et prolongée aux solvants.
Suite à la page 6

00861
page 6
===========================================================================
INFORMATION TOXICOLOGIQUE
CAS No.
Ingredient
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
100−41−4
Éthylbenzène
LC50
RAT
4HR
Pas Disponible
LD50
RAT
3500
mg/kg
1330−20−7
Xylène
LC50
RAT
4HR
5000
ppm
LD50
RAT
4300
mg/kg
64742−95−6
Solvant Naphta Aliphatique Léger
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
108−67−8
1,3,5−Triméthylbenzène
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
95−63−6
1,2,4−Triméthylbenzène
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
14807−96−6
Talc
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
471−34−1
Carbonate de Calcium
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
7727−43−7
Sulfate de Baryum
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
13463−67−7
Dioxyde de Titane
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
1333−86−4
Noir de Carbone
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
===========================================================================
Section 12 −− DONNÉES ÉCOLOGIQUES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Aucunes donnies disponibles.
===========================================================================
Section 13 −− DONNÉES SUR L’ÉLIMINATION DU PRODUIT
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
MÉTHODE D’ÉLIMINATION DES DÉCHETS
Les déchets provenant de ce produit peuvent être dangereux, selon la
définition donnée dans la "U.S. Resource Conservation and Recovery Act"
(RCRA) 40 CFR 261.
On doit soumettre les déchets au test de combustion et d’extraction pour
déterminer les numéros de l’EPA applicables.
Incinérer dans un endroit approuvé. Ne pas incinérer les contenants
fermés. Respecter les lois anti−pollution fédérales, provinciales et
municipales.
===========================================================================
Section 14 −− DONNÉES SUR LE TRANSPORT
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Aucunes donnies disponibles.
Suite à la page 7

00861
page 7
===========================================================================
Section 15 −− DONNÉES SUR LA RÉGLEMENTATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SARA 313 (40 CFR 372.65C) AVIS DE FOURNISSEUR
CAS No.
CHIMIQUE/COMPOSÉ
% by WT
% Element
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
100−41−4 Éthylbenzène
3
1330−20−7 Xylène
19
95−63−6 1,2,4−Triméthylbenzène
5
Barium Compound
5
3.0
CALIFORNIA PROPOSITION 65
AVERTISSEMENT: Ce produit des matières chimiques connue de l’État de la
Californie qui peut causer le cancer, dommages à la naissance ou autre
malformation congénitale.
DONNÉES SUR LA TSCA
Tous les produits chimiques dans ce produit sont énumérés, ou exemptez
de l’énumération, sur le inventaire de TSCA.
===========================================================================
Section 16 −− AUTRES DONNÉES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Cette FTSS a été préparée conformént aux exigences du SIMDUT; les
données sont toutefois présentées sous 16 rubriques.

Les renseignements donnés ci−haut se rapportent à ce produit suivant sa
formule actuelle et s’appuient sur les données disponibles en ce moment.
L’addition de diluant et autres additifs peut changer considérablement les
risques associés à ce produit et sa composition. Etant donné que nous
n’avons pas de contrôle sur les conditions d’utilisation, nous ne donnons
aucune guarantie, explicite ou implicite et nous n’assumons aucune
responsabilité concernant l’usage, quel qu’il soit, de ces renseignements.

FICHE SIGNALÉTIQUE SANTÉ−SÉCURITÉ
49200
02 00
===========================================================================
Section 1 −− IDENTIFICATION DU PRODUIT ET DE LA SOCIÉTÉ
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
NUMÉRO DU PRODUIT
Santé
2*
49200
Inflammabilité
3
Réactivité
0
NOM DU PRODUIT
KRYLON* TOUGH COAT* Acrylic Aerosol Paint, Gloss White
NOM DU FABRICANT
NO. DE TÉLÉPHONE EN CAS D’URGENCE
THE SHERWIN−WILLIAMS COMPANY
(216) 566−2917
KRYLON Products Group
Cleveland, OH 44115
DATE DE PRÉPARATION
NO. DE TÉLÉPHONE ORDINAIRE
24−FEB−07
(800) 832−2541
===========================================================================
Section 2 −− COMPOSITION/INFORMATION SUR LES INGRÉDIENTS
% EN POIDS
CAS No. INGREDIENT
UNITÉS
PRESSION VAPEUR
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
15
74−98−6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
7
106−97−8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
4
64742−89−8 Solvant Naphta Aliphatique Léger
ACGIH TLV
300 ppm
12 mm
OSHA PEL
300 ppm
OSHA PEL
400 ppm STEL
10
108−88−3 Toluène
ACGIH TLV
50 ppm (Peau)
22 mm
OSHA PEL
100 ppm (Peau)
OSHA PEL
150 ppm (Peau) STEL
0.4
100−41−4 Éthylbenzène
ACGIH TLV
100 ppm
7.1 mm
ACGIH TLV
125 ppm STEL
OSHA PEL
100 ppm
OSHA PEL
125 ppm STEL
2
1330−20−7 Xylène
ACGIH TLV
100 ppm
5.9 mm
ACGIH TLV
150 ppm STEL
OSHA PEL
100 ppm
OSHA PEL
150 ppm STEL
32
67−64−1 Acetone
ACGIH TLV
500 ppm
180 mm
ACGIH TLV
750 ppm STEL
OSHA PEL
1000 ppm
4
108−10−1 Méthylisobutylcétone
ACGIH TLV
50 ppm
16 mm
ACGIH TLV
75 ppm STEL
OSHA PEL
50 ppm
OSHA PEL
75 ppm STEL
Suite à la page 2

49200
page 2
===========================================================================
7
13463−67−7 Dioxyde de Titane
ACGIH TLV
10 mg/m3 de poussiére
OSHA PEL
10 mg/m3 total de polva
OSHA PEL
5 mg/m3 fracción respirable
===========================================================================
Section 3 −− IDENTIFICATION DES RISQUES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SOURCES D’EXPOSITION
L’exposition peut se produire par l’INHALATION des vapeurs ou du
brouillard de pulvérisation.
La PEAU et les YEUX peuvent entrer en contact avec le produit, les
vapeurs ou le brouillard de pulvérisation.
EFFET DE LA SUREXPOSITION
YEUX: Irritation des YEUX.
PEAU: L’exposition prolongée ou répétée risque de provoquer
l’irritation des peau.
INHALATION: Irritation des voies respiratoires supérieures.
Peut causer la dépression nerveuse. Une sur−exposition excessive à ce
produit peut entrainer la perte de conscience, voire même la mort.
SYMPTÔMES DE SUREXPOSITION
Les maux de tête, l’étourdissement, la nausée et la perte de
coordination des mouvements sont tous des symptômes d’exposition excessive
aux vapeurs ou à la brume de pulvérisation.
La rougeur et les démangeaisons ou la sensation de brûlure peuvent
indiquer une exposition excessive des yeux ou de la peau.
ETAT DE SANTÉ AGGRAVÉ PAR EXPOSITION
En général, aucun exposition n’est reconnue.
CANCÉROGÉNICITÉ
Voir la Section 11.
===========================================================================
Section 4 −− PREMIERS SOINS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
YEUX:

Rincer les yeux à grande eau pendant 15 minutes.
Aller voir un médecin.
PEAU: Laver à fond les parties affectées avec de l’eau et
du savon.
Enlever les habits contaminés et les laver avant de les
porter de nouveau.
INHALATION: Si une personne en est affectée, l’aider à sortir
des lieux. Rétablir la respiration. Aider la
personne á rester calme et au chaud.
INGESTION: N’incitez pas la personne á vomir.
Aller voir un médecin immédiatement.
===========================================================================
Section 5 −− MESURES EN CAS D’INCENDIE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
POINT D’ÉCLAIR
LIE
LSE
Propellant < 0 F
0.9
12.8
MOYENS D’EXTINCTION
Dioxyde de carbone, produit chimique sec, mousse

Suite à la page 3

49200
page 3
===========================================================================
DANGERS D’INCENDIE OU D’EXPLOSION EXCEPTIONNELS
Les contenants peuvent exploser s’ils sont exposés à une très grande
chaleur.
L’application aux surfaces chaudes exige qu’on prenne des précautions
spéciales.
En cas d’urgence, une exposition excessive aux produits de décomposition
peut constituer un danger pour la santé. Les symptômes peuvent ne pas se
manifester immédiatement. Voir le médecin.
MESURES PARTICULIÉRES DI PROTECTION CONTRE L’INCENDIE
On doit utiliser l’équipement de protection complète y compris un
appareil de respiration auto−alimenté.
La pulvérisation avec de l’eau peut être inefficace. Si on se sert de
l’eau, l’ajutage pour brume est préférable. On peut se servir de l’eau
pour refroidir les contenants fermés afin d’empêcher l’augmentation de la
pression et la possibilité d’une combustion automatique ou l’explosion en
cas d’exposition à une chaleur extrêmement grande.
===========================================================================
Section 6 −− MARCHE Á SUIVRE EN CAS DE DÉVERSEMENT ACCIDENTEL
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
MESURES À PRENDRE LORSQUE DES MATIÉRES SONT RENVERSÉES OU ÉVAPORÉES
Enlever toute source de combustion. Bien aérer.
Nettoyer avec un absorbant non réactif.
===========================================================================
Section 7 −− MANUTENTION ET ENTREPOSAGE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
CATÉGORIE D’ENTREPOSAGE
Pas Disponible
PRÉCAUTIONS Á PRENDRE LORS DE L’ENTREPOSAGE DI LA MANIPULATION
Tenir loin de la chaleur, étincelles et de flamme nue. Les vapeurs
peuvent s’accumuler rapidement et s’enflammer et causer une explosion.
Aucours de l’utilisation de ce produit jusqu’à la disparution de toutes
les vapeurs: Garder l’endroit bien aéré. Eviter de fumer. Eteindre toute
flamme, veilleuse d’appareils et réchauds. Couper la courant des poêles,
des outils et appareils éléctriques ainsi que de toute autre source de
combustion.
Suivre les procédures approuvées pour attacher solidement et pour
permettre l’écoulement de l’éléctricité dans le sol.
Contenu sous pression. Ne pas ouvrir, incinérer ou exposer à des
températures au dessus de 120 Fahrenheit. La chaleur des rayons du soleil,
des radiateurs, des réchauds, de l’eau chaude, ou provenant de toute autre
source, peut provoquer l’explosion du contenant. Ne pas avaler. Garder
hors de la portée des enfants.

Suite à la page 4

49200
page 4
===========================================================================
Section 8 −− CONTRÔLE DE L’EXPOSITION ET PROTECTION INDIVIDUELLE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRÉCAUTIONS À PRENDRE AUCOURS DE L’UTILISATION
N’utiliser ce produit que dans un endroit bien aéré.
Éviter tout contact avec la peau et les yeux. Eviter d’aspirer les
vapeurs et la brume de vaporisation.
Bien se laver les mains après l’utilisation.
Ce produit peut contenir des matières classifiées comme petites
particules irritantes, telles que le dioxyde de titane ou le carbonate de
calcium (voir la liste ACGIH TLV, la préface et l’annexe D). On peut avoir
ces particules dans des proportions dangereuses uniquement au moment du
grattement et de l’éraflement de la couche séchée. Si la liste dans la 2e
section ne fait aucune mention spécifique de la présence des poussières de
particules, les limites applicables sont: pour ACGIH TLV 10 mg/m3
(concentration totale de poussière), 3 mg/m3 (fractionée de respiratoire).
VENTILATION
Un système permettant l’échappement local des produits est préférable.
Si l’exposition aux produits de la 2e section est maintenue au−dessous des
limites d’exposition applicables, le système d’échappement global est
acceptable.
PROTECTION DES VOIES RESPIRATOIRES
Si on ne peut pas maintenir, par simple ventilation, le niveau auquel on
s’expos personnellement en dessous des limites applicables, porter un
respirateur à filtre de vapeur organique et particules approprié et bien
ajusté approuvé par NIOSH/MSHA pour se protéger contre les produits de la
2e section.
Pendant que vous frottez ou poncez la couche sechée, porter un
respirateur à filtre de poussière et de brume, approuvé par NIOSH/MSHA pour
vous protéger contre la poussière qui peut éventuellement se dégager de ce
produit, de la peinture ou de l’abrasif.
GANTS PROTECTEURS
Aucun n’est exigé pour l’application normale des produits aérosol,
lorsqu’on n’attend qu’un minimum de contact avec la peau. Pour un contact
prolongé et repété, portez des gants resistants aux produits chimiques.
LUNETTES DE SÉCURITÉ
Porter les lunetttes de sécurité avec des protecteurs latéraux non
perforés.
AUTRES PRÉCAUTIONS
L’utilisation inappropriée de ce produit en le concentrant et en
l’aspirant intentionnellement peut être dangereuse ou peut même causer la
mort.
===========================================================================
Section 9 −− PROPRIÉTÉS PHYSIQUES ET CHIMIQUES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
POIDS DU PRODUIT
DENSITÉ
COURBE D’ÉBULLITION
POINT DE FUSION
VOLUME VOLATIL
VITESSE D’ÉVAPORATION
DENSITÉ DE LA VAPEUR
SOLUBILITÉ DANS L’EAU
pH

Suite à la page 5

6.68 lb/gal
800 g/l
0.80
<0 − 325 F
<−18 − 162 C
P.D.
87 %
Plus vite que l’Éther
Plus lourd que l’Air
P.D.
7.0

49200
page 5
===========================================================================
COMPOSÉS ORGANIQUES VOLATILS (Théorique)
Volatil Poids 44.90% Moins d’eau et de solvants exemptés
===========================================================================
Section 10 −− STABILITÉ ET RÉACTIVITÉ
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STABILITÉ −− Stable
CONDITIONS À ÉVITER
Aucun connu.
INCOMPATIBILITÉ
Aucun connu.
PRODUITS DANGEREUX DÛ À LA DÉCOMPOSITION
Par combustion: Dioxyde de carbone, monoxyde de carbone
POLYMÉRISATION DANGEREUSE
Ne Peut Pas De Produire
===========================================================================
Section 11 −− DONNÉES TOXICOLOGIQUES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
RISQUES DE SANTÉ CHRONIQUES
À partir de données expérimentales provenant d’études suffisantes
mendées chez les animaux et d’études insuffisantes menées chez humains,
l’éthylbenzène est classifié par le CIRC comme étant possiblement
carcinogène chez les humains (group 2B). On a constaté une augmentation de
certains types de cancer, y compris des tumeurs du rein chez les rats et
des tumeurs du poumon et du foie chez les souris, lorsque ces animaux ont
été exposés à l’inhalation de concentrations élevées d’éthylbenzène à long
terme. Toutefois, ces effets n’ont pas étéobservés chez les animaux
exposés à de plus faibles concentrations d’éthylbenzène. Jusqu’à présent
il n’y a aucune preuve suggérant que l’éthylbenzène provoque le cancer chez
les humains.
L’exposition, excessive et prolongée, aux solvants de la 2 section peut
entrainer demauvaises conséquences aux systèmesdu
fois,urinaire,cardio−vasculaire etreproductif.
Les rats exposés à la poussière de dioxyde de titanium à une
concentrations de 250mg/m3 ont développé le cancer des poumons. Toutefois,
on ne peut pas atteindre une telle concentration en milieu du travail.
Il existe des rapports de recherches qui associent des troubles
permanentes du cerveau et du système nerveux à l’exposition excessive,
répétée et prolongée aux solvants.
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
INFORMATION TOXICOLOGIQUE

Suite à la page 6

49200
page 6
===========================================================================
CAS No.
Ingredient
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
74−98−6
Propane
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
106−97−8
Butane
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
64742−89−8
Solvant Naphta Aliphatique Léger
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
108−88−3
Toluène
LC50
RAT
4HR
4000
ppm
LD50
RAT
5000
mg/kg
100−41−4
Éthylbenzène
LC50
RAT
4HR
Pas Disponible
LD50
RAT
3500
mg/kg
1330−20−7
Xylène
LC50
RAT
4HR
5000
ppm
LD50
RAT
4300
mg/kg
67−64−1
Acetone
LC50
RAT
4HR
Pas Disponible
LD50
RAT
5800
mg/kg
108−10−1
Méthylisobutylcétone
LC50
RAT
4HR
Pas Disponible
LD50
RAT
2080
mg/kg
13463−67−7
Dioxyde de Titane
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
===========================================================================
Section 12 −− DONNÉES ÉCOLOGIQUES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Aucunes donnies disponibles.
===========================================================================
Section 13 −− DONNÉES SUR L’ÉLIMINATION DU PRODUIT
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
MÉTHODE D’ÉLIMINATION DES DÉCHETS
Les déchets provenant de ce produit peuvent être dangereux, selon la
définition donnée dans la "U.S. Resource Conservation and Recovery Act"
(RCRA) 40 CFR 261.
On doit soumettre les déchets au test de combustion afin de déterminer
les numéros de l’EPA applicables.
Ne pas incinérer. Eliminer la pression dans le contenant. Se
débarrasser du contenu confermément aux lois anti−pollution fédérales,
provinciales et municipales.
===========================================================================
Section 14 −− DONNÉES SUR LE TRANSPORT
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Aucunes donnies disponibles.

Suite à la page 7

49200
page 7
===========================================================================
Section 15 −− DONNÉES SUR LA RÉGLEMENTATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SARA 313 (40 CFR 372.65C) AVIS DE FOURNISSEUR
CAS No.
CHIMIQUE/COMPOSÉ
% by WT
% Element
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
108−88−3 Toluène
10
100−41−4 Éthylbenzène
0.3
1330−20−7 Xylène
2
108−10−1 Méthylisobutylcétone
4
DONNÉES SUR LA TSCA
Tous les produits chimiques dans ce produit sont énumérés, ou exemptez
de l’énumération, sur le inventaire de TSCA.
===========================================================================
Section 16 −− AUTRES DONNÉES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Cette FTSS a été préparée conformént aux exigences du SIMDUT; les
données sont toutefois présentées sous 16 rubriques.

Les renseignements donnés ci−haut se rapportent à ce produit suivant sa
formule actuelle et s’appuient sur les données disponibles en ce moment.
L’addition de diluant et autres additifs peut changer considérablement les
risques associés à ce produit et sa composition. Etant donné que nous
n’avons pas de contrôle sur les conditions d’utilisation, nous ne donnons
aucune guarantie, explicite ou implicite et nous n’assumons aucune
responsabilité concernant l’usage, quel qu’il soit, de ces renseignements.

MATERIAL SAFETY DATA SHEET
49219
03 00
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER
DATE OF PREPARATION
HMIS CODES
Health
49219
06-SEP-07
Flammability
Reactivity
PRODUCT NAME
KRYLON® RUST TOUGH® Rust Preventive Enamel (aerosol), Flat White

2*
3
0

MANUFACTURER'S NAME
SHERWIN-WILLIAMS CANADA INC.
KRYLON Products Group
Vaughan, ON L4K 4T8
TELEPHONE NUMBERS and WEBSITES
Product Information
(800) 832-2541
Regulatory Information
(216) 566-2902
www.paintdocs.com
Medical Emergency
(216) 566-2917
Transportation Emergency
for Chemical Emergency ONLY (spill, leak,
(800) 424-9300
fire, exposure, or accident)
% by WT
15
7
4

11

0.2

32

Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
74-98-6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
106-97-8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
64742-89-8 V. M. & P. Naphtha
ACGIH TLV
300 ppm
12 mm
OSHA PEL
300 ppm
OSHA PEL
400 ppm STEL
108-88-3 Toluene
ACGIH TLV
20 ppm
22 mm
OSHA PEL
100 ppm (Skin)
OSHA PEL
150 ppm (Skin) STEL
100-41-4 Ethylbenzene
ACGIH TLV
100 ppm
7.1 mm
ACGIH TLV
125 ppm STEL
OSHA PEL
100 ppm
OSHA PEL
125 ppm STEL
67-64-1 Acetone
ACGIH TLV
500 ppm
180 mm
ACGIH TLV
750 ppm STEL
OSHA PEL
1000 ppm

Continued on page 2

49219
4

page 2
108-10-1

2

112926-00-8

7

13463-67-7

Methyl Isobutyl Ketone
ACGIH TLV
50
ACGIH TLV
75
OSHA PEL
50
OSHA PEL
75
Amorphous Precipitated
ACGIH TLV
10
OSHA PEL
6
Titanium Dioxide
ACGIH TLV
10
OSHA PEL
10
OSHA PEL
5

ppm
ppm STEL
ppm
ppm STEL
Silica
mg/m3 as Dust
mg/m3 as Dust

16 mm

mg/m3 as Dust
mg/m3 Total Dust
mg/m3 Respirable Fraction

Section 3 -- HAZARDS IDENTIFICATION
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
Section 4 -- FIRST AID MEASURES
EYES:
SKIN:
INHALATION:
INGESTION:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
Do not induce vomiting.
Get medical attention immediately.

Section 5 -- FIRE FIGHTING MEASURES
FLASH POINT
LEL
UEL
Propellant < 0 F
0.9
12.8
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam

Continued on page 3

49219

page 3

UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.
Section 6 -- ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
Section 7 -- HANDLING AND STORAGE
STORAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated - Do not
smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.

Continued on page 4

49219

page 4

Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
Removal of old paint by sanding, scraping or other means may generate
dust or fumes that contain lead. Exposure to lead dust or fumes may cause
brain damage or other adverse health effects, especially in children or
pregnant women. Controlling exposure to lead or other hazardous substances
requires the use of proper protective equipment, such as a properly fitted
respirator (NIOSH approved) and proper containment and cleanup. For more
information, call the National Lead Information Center at 1-800-424-LEAD
(in US) or contact your local health authority.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT WEIGHT
6.72 lb/gal
804 g/l
SPECIFIC GRAVITY
0.81
BOILING POINT
<0 - 325 F
<-18 - 162 C
MELTING POINT
Not Available
VOLATILE VOLUME
87 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
Volatile Weight 44.07% Less Water and Federally Exempt Solvents
Continued on page 5

49219

page 5

Section 10 -- STABILITY AND REACTIVITY
STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
Section 11 -- TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
Ethylbenzene is classified by IARC as possibly carcinogenic to humans
(2B) based on inadequate evidence in humans and sufficient evidence in
laboratory animals.
Lifetime inhalation exposure of rats and mice to high
ethylbenzene concentrations resulted in increases in certain types of
cancer, including kidney tumors in rats and lung and liver tumors in mice.
These effects were not observed in animals exposed to lower concentrations.
There is no evidence that ethylbenzene causes cancer in humans.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, cardiovascular and reproductive
systems.
IARC's Monograph No. 93 reports there is sufficient evidence of
carcinogenicity in experimental rats exposed to titanium dioxide but
inadequate evidence for carcinogenicity in humans and has assigned a Group
2B rating. In addition, the IARC summary concludes, "No significant
exposure to titanium dioxide is thought to occur during the use of products
in which titanium is bound to other materials, such as paint."
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
TOXICOLOGY DATA

Continued on page 6

49219
CAS No.
74-98-6
106-97-8
64742-89-8
108-88-3
100-41-4
67-64-1
108-10-1
112926-00-8
13463-67-7

page 6
Ingredient Name
Propane
LC50
RAT
4HR
LD50
RAT
Butane
LC50
RAT
4HR
LD50
RAT
V. M. & P. Naphtha
LC50
RAT
4HR
LD50
RAT
Toluene
LC50
RAT
4HR
LD50
RAT
Ethylbenzene
LC50
RAT
4HR
LD50
RAT
Acetone
LC50
RAT
4HR
LD50
RAT
Methyl Isobutyl Ketone
LC50
RAT
4HR
LD50
RAT
Amorphous Precipitated Silica
LC50
RAT
4HR
LD50
RAT
Titanium Dioxide
LC50
RAT
4HR
LD50
RAT

Not Available
Not Available
Not Available
Not Available
Not Available
Not Available
4000
5000

ppm
mg/kg

Not Available
3500
mg/kg
Not Available
5800
mg/kg
Not Available
2080
mg/kg
Not Available
Not Available
Not Available
Not Available

Section 12 -- ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
No data available.
Section 13 -- DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.

Continued on page 7

49219

page 7

Section 14 -- TRANSPORT INFORMATION
US Ground (DOT)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126)
Canada (TDG)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126)
IMO
May be shipped as Limited Quantity
UN1950, AEROSOLS, CLASS 2, LIMITED QUANTITY, EmS F-D, S-U
Section 15 -- REGULATORY INFORMATION
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
108-88-3 Toluene
100-41-4 Ethylbenzene
108-10-1 Methyl Isobutyl Ketone

% by WT
11
0.1
4

% Element

TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
Section 16 -- OTHER INFORMATION
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

FICHE SIGNALÉTIQUE SANTÉ-SÉCURITÉ
460505
02 00
Section 1 -- IDENTIFICATION DU PRODUIT ET DE LA SOCIÉTÉ
NUMÉRO DU PRODUIT
DATE DE PRÉPARATION
Santé
460505
29-SEP-07
Inflammabilité
Réactivité
NOM DU PRODUIT
COLOUR ALL Spray Paint, Gloss Black

2*
3
0

NOM DU FABRICANT
SHERWIN-WILLIAMS CANADA, INC.
DUPLI-COLOR Products Group
Vaughan, ON L4K 4T8
NUMÉROS DE TÉLÉPHONES ET SITES WEB
Renseignements sur le produit
(905) 761-9185
Renseignements réglementaires
(216) 566-2902
www.paintdocs.com
Urgence médicale
(216) 566-2917
Urgence de transport
pour une urgence chimique SEULEMENT
(800) 424-9300
(déversement, fuite, incendie, exposition
ou accident)
Section 2 -- COMPOSITION/INFORMATION SUR LES INGRÉDIENTS
CAS No. INGREDIENT
UNITÉS
PRESSION VAPEUR
74-98-6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
106-97-8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
108-88-3 Toluène
ACGIH TLV
20 ppm
22 mm
OSHA PEL
100 ppm (Peau)
OSHA PEL
150 ppm (Peau) STEL
67-64-1 Acetone
ACGIH TLV
500 ppm
180 mm
ACGIH TLV
750 ppm STEL
OSHA PEL
1000 ppm
763-69-9 3-Éthoxypropionate d'éthyle
ACGIH TLV Pas Disponible
1.11 mm
OSHA PEL Pas Disponible
1333-86-4 Noir de Carbone
ACGIH TLV
3.5 mg/m3
OSHA PEL
3.5 mg/m3

% EN POIDS
14
13
21

40

3
0.4

Suite à la page 2

460505

page 2

Section 3 -- IDENTIFICATION DES RISQUES
SOURCES D'EXPOSITION
L'exposition peut se produire par l'INHALATION des vapeurs ou du
brouillard de pulvérisation.
La PEAU et les YEUX peuvent entrer en contact avec le produit, les
vapeurs ou le brouillard de pulvérisation.
EFFET DE LA SUREXPOSITION
YEUX: Irritation des YEUX.
PEAU: L'exposition prolongée ou répétée risque de provoquer
l'irritation des peau.
INHALATION: Irritation des voies respiratoires supérieures.
Peut causer la dépression nerveuse. Une sur-exposition excessive à ce
produit peut entrainer la perte de conscience, voire même la mort.
L'exposition, excessive et prolongée, aux solvants de la 2 section peut
entrainer de mauvaises conséquences aux systèmes du fois, urinaire,
cardio-vasculaire et reproductif.
SYMPTÔMES DE SUREXPOSITION
Les maux de tête, l'étourdissement, la nausée et la perte de
coordination des mouvements sont tous des symptômes d'exposition excessive
aux vapeurs ou à la brume de pulvérisation.
La rougeur et les démangeaisons ou la sensation de brûlure peuvent
indiquer une exposition excessive des yeux ou de la peau.
ETAT DE SANTÉ AGGRAVÉ PAR EXPOSITION
En général, aucun exposition n'est reconnue.
CANCÉROGÉNICITÉ
Voir la Section 11.
Section 4 -- PREMIERS SOINS
YEUX:
PEAU:

INHALATION:
INGESTION:

Rincer les yeux à grande eau pendant 15 minutes.
Aller voir un médecin.
Laver à fond les parties affectées avec de l'eau et
du savon.
Enlever les habits contaminés et les laver avant de les
porter de nouveau.
Si une personne en est affectée, l'aider à sortir
des lieux. Rétablir la respiration. Aider la
personne á rester calme et au chaud.
N'incitez pas la personne á vomir.
Aller voir un médecin immédiatement.

Section 5 -- MESURES EN CAS D'INCENDIE
POINT D'ÉCLAIR
LIE
LSE
Propellant < 0 F
1.0
12.8
MOYENS D'EXTINCTION
Dioxyde de carbone, produit chimique sec, mousse

Suite à la page 3

460505

page 3

DANGERS D'INCENDIE OU D'EXPLOSION EXCEPTIONNELS
Les contenants peuvent exploser s'ils sont exposés à une très grande
chaleur.
L'application aux surfaces chaudes exige qu'on prenne des précautions
spéciales.
En cas d'urgence, une exposition excessive aux produits de décomposition
peut constituer un danger pour la santé. Les symptômes peuvent ne pas se
manifester immédiatement. Voir le médecin.
MESURES PARTICULIÉRES DI PROTECTION CONTRE L'INCENDIE
On doit utiliser l'équipement de protection complète y compris un
appareil de respiration auto-alimenté.
La pulvérisation avec de l'eau peut être inefficace. Si on se sert de
l'eau, l'ajutage pour brume est préférable. On peut se servir de l'eau
pour refroidir les contenants fermés afin d'empêcher l'augmentation de la
pression et la possibilité d'une combustion automatique ou l'explosion en
cas d'exposition à une chaleur extrêmement grande.
Section 6 -- MARCHE Á SUIVRE EN CAS DE DÉVERSEMENT ACCIDENTEL
MESURES À PRENDRE LORSQUE DES MATIÉRES SONT RENVERSÉES OU ÉVAPORÉES
Enlever toute source de combustion. Bien aérer.
Nettoyer avec un absorbant non réactif.
Section 7 -- MANUTENTION ET ENTREPOSAGE
CATÉGORIE D'ENTREPOSAGE
Pas Disponible
PRÉCAUTIONS Á PRENDRE LORS DE L'ENTREPOSAGE DI LA MANIPULATION
Tenir loin de la chaleur, étincelles et de flamme nue. Les vapeurs
peuvent s'accumuler rapidement et s'enflammer et causer une explosion.
Aucours de l'utilisation de ce produit jusqu'à la disparution de toutes
les vapeurs: Garder l'endroit bien aéré. Eviter de fumer. Eteindre toute
flamme, veilleuse d'appareils et réchauds. Couper la courant des poêles,
des outils et appareils éléctriques ainsi que de toute autre source de
combustion.
Suivre les procédures approuvées pour attacher solidement et pour
permettre l'écoulement de l'éléctricité dans le sol.
Contenu sous pression. Ne pas ouvrir, incinérer ou exposer à des
températures au dessus de 120 Fahrenheit. La chaleur des rayons du soleil,
des radiateurs, des réchauds, de l'eau chaude, ou provenant de toute autre
source, peut provoquer l'explosion du contenant. Ne pas avaler. Garder
hors de la portée des enfants.

Suite à la page 4

460505

page 4

Section 8 -- CONTRÔLE DE L'EXPOSITION ET PROTECTION INDIVIDUELLE
PRÉCAUTIONS À PRENDRE AUCOURS DE L'UTILISATION
N'utiliser ce produit que dans un endroit bien aéré.
Éviter tout contact avec la peau et les yeux. Eviter d'aspirer les
vapeurs et la brume de vaporisation.
Bien se laver les mains après l'utilisation.
Ce produit peut contenir des matières classifiées comme petites
particules irritantes, telles que le dioxyde de titane ou le carbonate de
calcium (voir la liste ACGIH TLV, la préface et l'annexe D). On peut avoir
ces particules dans des proportions dangereuses uniquement au moment du
grattement et de l'éraflement de la couche séchée. Si la liste dans la 2e
section ne fait aucune mention spécifique de la présence des poussières de
particules, les limites applicables sont: pour ACGIH TLV 10 mg/m3
(concentration totale de poussière), 3 mg/m3 (fractionée de respiratoire).
VENTILATION
Un système permettant l'échappement local des produits est préférable.
Si l'exposition aux produits de la 2e section est maintenue au-dessous des
limites d'exposition applicables, le système d'échappement global est
acceptable.
PROTECTION DES VOIES RESPIRATOIRES
Si on ne peut pas maintenir, par simple ventilation, le niveau auquel on
s'expos personnellement en dessous des limites applicables, porter un
respirateur à filtre de vapeur organique et particules approprié et bien
ajusté approuvé par NIOSH/MSHA pour se protéger contre les produits de la
2e section.
Pendant que vous frottez ou poncez la couche sechée, porter un
respirateur à filtre de poussière et de brume, approuvé par NIOSH/MSHA pour
vous protéger contre la poussière qui peut éventuellement se dégager de ce
produit, de la peinture ou de l'abrasif.
GANTS PROTECTEURS
Aucun n'est exigé pour l'application normale des produits aérosol,
lorsqu'on n'attend qu'un minimum de contact avec la peau. Pour un contact
prolongé et repété, portez des gants resistants aux produits chimiques.
LUNETTES DE SÉCURITÉ
Porter les lunetttes de sécurité avec des protecteurs latéraux non
perforés.
AUTRES PRÉCAUTIONS
L'utilisation inappropriée de ce produit en le concentrant et en
l'aspirant intentionnellement peut être dangereuse ou peut même causer la
mort.
Section 9 -- PROPRIÉTÉS PHYSIQUES ET CHIMIQUES
POIDS DU PRODUIT
DENSITÉ
COURBE D'ÉBULLITION
POINT DE FUSION
VOLUME VOLATIL
VITESSE D'ÉVAPORATION
DENSITÉ DE LA VAPEUR
SOLUBILITÉ DANS L'EAU
pH

Suite à la page 5

6.08 lb/gal
728 g/l
0.73
<0 - 342 F
<-18 - 172 C
P.D.
94 %
Plus vite que l'Éther
Plus lourd que l'Air
P.D.
7.0

460505

page 5

COMPOSÉS ORGANIQUES VOLATILS (Théorique)
Volatil Poids 51.59% Moins d'eau et de solvants exemptés
Section 10 -- STABILITÉ ET RÉACTIVITÉ
STABILITÉ -- Stable
CONDITIONS À ÉVITER
Aucun connu.
INCOMPATIBILITÉ
Aucun connu.
PRODUITS DANGEREUX DÛ À LA DÉCOMPOSITION
Par combustion: Dioxyde de carbone, monoxyde de carbone
POLYMÉRISATION DANGEREUSE
Ne Peut Pas De Produire
Section 11 -- DONNÉES TOXICOLOGIQUES
RISQUES DE SANTÉ CHRONIQUES
Il existe des rapports de recherches qui associent des troubles
permanentes du cerveau et du système nerveux à l'exposition excessive,
répétée et prolongée aux solvants.
Le carbone noir est classifié par l'IARC comme étant possiblement
carcinogène aux humains (groupe 2B) basé sur des données animales
expérimentales. Cependant, dans les humains, l'évidence de carcinogénéité
est insuffisante.
INFORMATION TOXICOLOGIQUE
CAS No.
Ingredient
74-98-6
Propane
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
106-97-8
Butane
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
108-88-3
Toluène
LC50
RAT
4HR
4000
ppm
LD50
RAT
5000
mg/kg
67-64-1
Acetone
LC50
RAT
4HR
Pas Disponible
LD50
RAT
5800
mg/kg
763-69-9
3-Éthoxypropionate d'éthyle
LC50
RAT
4HR
Pas Disponible
LD50
RAT
5000
mg/kg
1333-86-4
Noir de Carbone
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
Section 12 -- DONNÉES ÉCOLOGIQUES
Aucunes donnies disponibles.

Suite à la page 6

460505

page 6

Section 13 -- DONNÉES SUR L'ÉLIMINATION DU PRODUIT
MÉTHODE D'ÉLIMINATION DES DÉCHETS
Les déchets provenant de ce produit peuvent être dangereux, selon la
définition donnée dans la "U.S. Resource Conservation and Recovery Act"
(RCRA) 40 CFR 261.
On doit soumettre les déchets au test de combustion afin de déterminer
les numéros de l'EPA applicables.
Ne pas incinérer. Eliminer la pression dans le contenant. Se
débarrasser du contenu confermément aux lois anti-pollution fédérales,
provinciales et municipales.
Section 14 -- DONNÉES SUR LE TRANSPORT
US Ground (DOT)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126)
Canada (TDG)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126)
IMO
May be shipped as Limited Quantity
UN1950, AEROSOLS, CLASS 2, LIMITED QUANTITY, EmS F-D, S-U
Section 15 -- DONNÉES SUR LA RÉGLEMENTATION
SARA 313 (40 CFR 372.65C) AVIS DE FOURNISSEUR
CAS No.
CHIMIQUE/COMPOSÉ
108-88-3 Toluène

% by WT
21

% Element

DONNÉES SUR LA TSCA
Tous les produits chimiques dans ce produit sont énumérés, ou exemptez
de l'énumération, sur le inventaire de TSCA.
Section 16 -- AUTRES DONNÉES
Cette FTSS a été préparée conformént aux exigences du SIMDUT; les
données sont toutefois présentées sous 16 rubriques.

Les renseignements donnés ci-haut se rapportent à ce produit suivant sa
formule actuelle et s'appuient sur les données disponibles en ce moment.
L'addition de diluant et autres additifs peut changer considérablement les
risques associés à ce produit et sa composition. Etant donné que nous
n'avons pas de contrôle sur les conditions d'utilisation, nous ne donnons
aucune guarantie, explicite ou implicite et nous n'assumons aucune
responsabilité concernant l'usage, quel qu'il soit, de ces renseignements.

3201
01 00

MATERIAL SAFETY DATA SHEET

===========================================================================
Section 1 −− PRODUCT AND COMPANY IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT NUMBER
HMIS CODES
Health
2
3201
Flammability
4
Reactivity
0
PRODUCT NAME
KRYLON* Appliance Epoxy Paint, White
MANUFACTURER’S NAME
EMERGENCY TELEPHONE NO.
THE SHERWIN−WILLIAMS COMPANY
(216) 566−2917
KRYLON Products Group
Cleveland, OH 44115
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
24−JAN−06
(800) 832−2541
===========================================================================
Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
14
74−98−6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
13
106−97−8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
18
108−88−3 Toluene
ACGIH TLV
50 ppm (Skin)
22 mm
OSHA PEL
100 ppm (Skin)
OSHA PEL
150 ppm (Skin) STEL
23
67−64−1 Acetone
ACGIH TLV
500 ppm
180 mm
ACGIH TLV
750 ppm STEL
OSHA PEL
1000 ppm
12
123−86−4 n−Butyl Acetate
ACGIH TLV
150 ppm
10 mm
ACGIH TLV
200 ppm STEL
OSHA PEL
150 ppm
OSHA PEL
200 ppm STEL
7
13463−67−7 Titanium Dioxide
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction
===========================================================================
Section 3 −− HAZARDS IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.

Continued on page 2

3201
page 2
===========================================================================
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
===========================================================================
Section 4 −− FIRST AID MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
EYES:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re−use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 −− FIRE FIGHTING MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
FLASH POINT
LEL
UEL
Propellant < 0 F
1.0
12.8
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self−contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build−up and possible autoignition or explosion when exposed to
extreme heat.
===========================================================================
Section 6 −− ACCIDENTAL RELEASE MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.

Continued on page 3

3201
page 3
===========================================================================
Section 7 −− HANDLING AND STORAGE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STORAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated − Do not
smoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
===========================================================================
Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
Removal of old paint by sanding, scraping or other means may generate
dust or fumes that contain lead. Exposure to lead dust or fumes may cause
brain damage or other adverse health effects, especially in children or
pregnant women. Controlling exposure to lead or other hazardous substances
requires the use of proper protective equipment, such as a properly fitted
respirator (NIOSH approved) and proper containment and cleanup. For more
information, call the National Lead Information Center at 1−800−424−LEAD
(in US) or contact your local health authority.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.

Continued on page 4

3201
page 4
===========================================================================
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
===========================================================================
Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT WEIGHT
6.55 lb/gal
784 g/l
SPECIFIC GRAVITY
0.79
BOILING POINT
<0 − 264 F
<−18 − 128 C
MELTING POINT
Not Available
VOLATILE VOLUME
89 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical)
Volatile Weight 57.20 % Less Water and Federally Exempt Solvents
===========================================================================
Section 10 −− STABILITY AND REACTIVITY
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STABILITY −− Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
===========================================================================
Section 11 −− TOXICOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, blood forming, cardiovascular and
reproductive systems.
Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung
cancer, however, such exposure levels are not attainable in the workplace.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
TOXICOLOGY DATA

Continued on page 5

3201
page 5
===========================================================================
CAS No.
Ingredient Name
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
74−98−6
Propane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
106−97−8
Butane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
108−88−3
Toluene
LC50
RAT
4HR
4000
ppm
LD50
RAT
5000
mg/kg
67−64−1
Acetone
LC50
RAT
4HR
Not Available
LD50
RAT
5800
mg/kg
123−86−4
n−Butyl Acetate
LC50
RAT
4HR
2000
ppm
LD50
RAT
13100
mg/kg
13463−67−7
Titanium Dioxide
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
===========================================================================
Section 12 −− ECOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ECOTOXICOLOGICAL INFORMATION
No data available.
===========================================================================
Section 13 −− DISPOSAL CONSIDERATIONS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.
===========================================================================
Section 14 −− TRANSPORT INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
No data available.
===========================================================================
Section 15 −− REGULATORY INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
108−88−3 Toluene
18
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.

Continued on page 6

3201
page 6
===========================================================================
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
===========================================================================
Section 16 −− OTHER INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

MATERIAL SAFETY DATA SHEET
SF31
03 00
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER
DATE OF PREPARATION
HMIS CODES
Health
SF31
29-SEP-07
Flammability
Reactivity
PRODUCT NAME
Scratch Filler & Primer, Gray

3*
3
0

MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS CO.
DUPLI-COLOR Products Group
Cleveland, OH 44115
TELEPHONE NUMBERS and WEBSITES
Product Information
(800) 247-3270
www.duplicolor.com
Regulatory Information
(216) 566-2902
www.paintdocs.com
Medical Emergency
(216) 566-2917
Transportation Emergency
for Chemical Emergency ONLY (spill, leak,
(800) 424-9300
fire, exposure, or accident)
% by WT
6

2

2

31

5

Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
108-88-3 Toluene
ACGIH TLV
20 ppm
22 mm
OSHA PEL
100 ppm (Skin)
OSHA PEL
150 ppm (Skin) STEL
67-56-1 Methanol
ACGIH TLV
200 ppm (Skin)
92 mm
ACGIH TLV
250 ppm (Skin) STEL
OSHA PEL
200 ppm (Skin)
OSHA PEL
250 ppm (Skin) STEL
67-63-0 2-Propanol
ACGIH TLV
400 ppm
33 mm
ACGIH TLV
500 ppm STEL
OSHA PEL
400 ppm
OSHA PEL
500 ppm STEL
78-93-3 Methyl Ethyl Ketone
ACGIH TLV
200 ppm
70 mm
ACGIH TLV
300 ppm STEL
OSHA PEL
200 ppm
OSHA PEL
300 ppm STEL
108-10-1 Methyl Isobutyl Ketone
ACGIH TLV
50 ppm
16 mm
ACGIH TLV
75 ppm STEL
OSHA PEL
50 ppm
OSHA PEL
75 ppm STEL

Continued on page 2

SF31

page 2

16

763-69-9

10

14807-96-6

4

471-34-1

6

13463-67-7

Ethyl 3-Ethoxypropionate
ACGIH TLV Not Available
1.11 mm
OSHA PEL Not Available
Talc
ACGIH TLV
2 mg/m3 as Resp. Dust
OSHA PEL
2 mg/m3 as Resp. Dust
Calcium Carbonate
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
15 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction
Titanium Dioxide
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction

Section 3 -- HAZARDS IDENTIFICATION
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, cardiovascular and reproductive
systems.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
Section 4 -- FIRST AID MEASURES
EYES:
SKIN:
INHALATION:
INGESTION:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
Do not induce vomiting.
Get medical attention immediately.

Continued on page 3

SF31

page 3

Section 5 -- FIRE FIGHTING MEASURES
FLASH POINT
LEL
UEL
36 F PMCC
1.0
36.5
FLAMMABILITY CLASSIFICATION
RED LABEL -- Flammable, Flash below 100 F (38 C)
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.
Section 6 -- ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
Section 7 -- HANDLING AND STORAGE
STORAGE CATEGORY
DOL Storage Class IB
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Contents are FLAMMABLE. Keep away from heat, sparks, and open flame.
During use and until all vapors are gone: Keep area ventilated - Do not
smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Keep container closed when not in use. Transfer only to approved
containers with complete and appropriate labeling. Do not take internally.
Keep out of the reach of children.
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).

Continued on page 4

SF31

page 4

VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
Wear gloves which are recommended by glove supplier for protection
against materials in Section 2.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT WEIGHT
8.89 lb/gal
1065 g/l
SPECIFIC GRAVITY
1.07
BOILING POINT
148 - 342 F
64 - 172 C
MELTING POINT
Not Available
VOLATILE VOLUME
78 %
EVAPORATION RATE
Slower than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
5.52 lb/gal
661 g/l
Less Water and Federally Exempt Solvents
5.52 lb/gal
661 g/l
Emitted VOC
Section 10 -- STABILITY AND REACTIVITY
STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur

Continued on page 5

SF31

page 5

Section 11 -- TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
Methyl Ethyl Ketone may increase the nervous system effects of other
solvents.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
IARC's Monograph No. 93 reports there is sufficient evidence of
carcinogenicity in experimental rats exposed to titanium dioxide but
inadequate evidence for carcinogenicity in humans and has assigned a Group
2B rating. In addition, the IARC summary concludes, "No significant
exposure to titanium dioxide is thought to occur during the use of products
in which titanium is bound to other materials, such as paint."
TOXICOLOGY DATA
CAS No.
Ingredient Name
108-88-3
Toluene
LC50
RAT
4HR
4000
ppm
LD50
RAT
5000
mg/kg
67-56-1
Methanol
LC50
RAT
4HR
64000
ppm
LD50
RAT
5630
mg/kg
67-63-0
2-Propanol
LC50
RAT
4HR
Not Available
LD50
RAT
5045
mg/kg
78-93-3
Methyl Ethyl Ketone
LC50
RAT
4HR
Not Available
LD50
RAT
2740
mg/kg
108-10-1
Methyl Isobutyl Ketone
LC50
RAT
4HR
Not Available
LD50
RAT
2080
mg/kg
763-69-9
Ethyl 3-Ethoxypropionate
LC50
RAT
4HR
Not Available
LD50
RAT
5000
mg/kg
14807-96-6
Talc
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
471-34-1
Calcium Carbonate
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
13463-67-7
Titanium Dioxide
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
Section 12 -- ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
No data available.

Continued on page 6

SF31

page 6

Section 13 -- DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Incinerate in approved facility. Do not incinerate closed container.
Dispose of in accordance with Federal, State/Provincial, and Local
regulations regarding pollution.
Section 14 -- TRANSPORT INFORMATION
US Ground (DOT)
1 Gallon and Less may be Classed as CONSUMER COMMODITY, ORM-D
Larger Containers are Regulated as:
UN1263, PAINT, 3, PG II, (ERG#128)
DOT (Dept of Transportation) Hazardous Substances & Reportable Quantities
Ethyl methyl ketone 5000 lb RQ
Toluene 1000 lb RQ
Xylenes (isomers and mixture) 100 lb RQ
Bulk Containers may be Shipped as (check reportable quantities):
UN1263, PAINT, 3, PG II, (ERG#128)
Canada (TDG)
UN1263, PAINT, CLASS 3, PG II, (ERG#128)
IMO
UN1263, PAINT, CLASS 3, PG II, MARINE POLLUTANT, (2 C c.c.), (TRICRESYL
PHOSPHATE), EmS F-E, S-E
Section 15 -- REGULATORY INFORMATION
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
108-88-3 Toluene
67-56-1 Methanol
108-10-1 Methyl Isobutyl Ketone
Zinc Compound

% by WT
6
2
5
2

% Element

0.6

CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.

Continued on page 7

SF31

page 7

Section 16 -- OTHER INFORMATION
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

MATERIAL SAFETY DATA SHEET
SF31
03 00
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER
DATE OF PREPARATION
HMIS CODES
Health
SF31
29-SEP-07
Flammability
Reactivity
PRODUCT NAME
Scratch Filler & Primer, Gray

3*
3
0

MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS CO.
DUPLI-COLOR Products Group
Cleveland, OH 44115
TELEPHONE NUMBERS and WEBSITES
Product Information
(800) 247-3270
www.duplicolor.com
Regulatory Information
(216) 566-2902
www.paintdocs.com
Medical Emergency
(216) 566-2917
Transportation Emergency
for Chemical Emergency ONLY (spill, leak,
(800) 424-9300
fire, exposure, or accident)
% by WT
6

2

2

31

5

Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
108-88-3 Toluene
ACGIH TLV
20 ppm
22 mm
OSHA PEL
100 ppm (Skin)
OSHA PEL
150 ppm (Skin) STEL
67-56-1 Methanol
ACGIH TLV
200 ppm (Skin)
92 mm
ACGIH TLV
250 ppm (Skin) STEL
OSHA PEL
200 ppm (Skin)
OSHA PEL
250 ppm (Skin) STEL
67-63-0 2-Propanol
ACGIH TLV
400 ppm
33 mm
ACGIH TLV
500 ppm STEL
OSHA PEL
400 ppm
OSHA PEL
500 ppm STEL
78-93-3 Methyl Ethyl Ketone
ACGIH TLV
200 ppm
70 mm
ACGIH TLV
300 ppm STEL
OSHA PEL
200 ppm
OSHA PEL
300 ppm STEL
108-10-1 Methyl Isobutyl Ketone
ACGIH TLV
50 ppm
16 mm
ACGIH TLV
75 ppm STEL
OSHA PEL
50 ppm
OSHA PEL
75 ppm STEL

Continued on page 2

SF31

page 2

16

763-69-9

10

14807-96-6

4

471-34-1

6

13463-67-7

Ethyl 3-Ethoxypropionate
ACGIH TLV Not Available
1.11 mm
OSHA PEL Not Available
Talc
ACGIH TLV
2 mg/m3 as Resp. Dust
OSHA PEL
2 mg/m3 as Resp. Dust
Calcium Carbonate
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
15 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction
Titanium Dioxide
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction

Section 3 -- HAZARDS IDENTIFICATION
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, cardiovascular and reproductive
systems.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
Section 4 -- FIRST AID MEASURES
EYES:
SKIN:
INHALATION:
INGESTION:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
Do not induce vomiting.
Get medical attention immediately.

Continued on page 3

SF31

page 3

Section 5 -- FIRE FIGHTING MEASURES
FLASH POINT
LEL
UEL
36 F PMCC
1.0
36.5
FLAMMABILITY CLASSIFICATION
RED LABEL -- Flammable, Flash below 100 F (38 C)
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.
Section 6 -- ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
Section 7 -- HANDLING AND STORAGE
STORAGE CATEGORY
DOL Storage Class IB
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Contents are FLAMMABLE. Keep away from heat, sparks, and open flame.
During use and until all vapors are gone: Keep area ventilated - Do not
smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Keep container closed when not in use. Transfer only to approved
containers with complete and appropriate labeling. Do not take internally.
Keep out of the reach of children.
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).

Continued on page 4

SF31

page 4

VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
Wear gloves which are recommended by glove supplier for protection
against materials in Section 2.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT WEIGHT
8.89 lb/gal
1065 g/l
SPECIFIC GRAVITY
1.07
BOILING POINT
148 - 342 F
64 - 172 C
MELTING POINT
Not Available
VOLATILE VOLUME
78 %
EVAPORATION RATE
Slower than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
5.52 lb/gal
661 g/l
Less Water and Federally Exempt Solvents
5.52 lb/gal
661 g/l
Emitted VOC
Section 10 -- STABILITY AND REACTIVITY
STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur

Continued on page 5

SF31

page 5

Section 11 -- TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
Methyl Ethyl Ketone may increase the nervous system effects of other
solvents.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
IARC's Monograph No. 93 reports there is sufficient evidence of
carcinogenicity in experimental rats exposed to titanium dioxide but
inadequate evidence for carcinogenicity in humans and has assigned a Group
2B rating. In addition, the IARC summary concludes, "No significant
exposure to titanium dioxide is thought to occur during the use of products
in which titanium is bound to other materials, such as paint."
TOXICOLOGY DATA
CAS No.
Ingredient Name
108-88-3
Toluene
LC50
RAT
4HR
4000
ppm
LD50
RAT
5000
mg/kg
67-56-1
Methanol
LC50
RAT
4HR
64000
ppm
LD50
RAT
5630
mg/kg
67-63-0
2-Propanol
LC50
RAT
4HR
Not Available
LD50
RAT
5045
mg/kg
78-93-3
Methyl Ethyl Ketone
LC50
RAT
4HR
Not Available
LD50
RAT
2740
mg/kg
108-10-1
Methyl Isobutyl Ketone
LC50
RAT
4HR
Not Available
LD50
RAT
2080
mg/kg
763-69-9
Ethyl 3-Ethoxypropionate
LC50
RAT
4HR
Not Available
LD50
RAT
5000
mg/kg
14807-96-6
Talc
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
471-34-1
Calcium Carbonate
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
13463-67-7
Titanium Dioxide
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
Section 12 -- ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
No data available.

Continued on page 6

SF31

page 6

Section 13 -- DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Incinerate in approved facility. Do not incinerate closed container.
Dispose of in accordance with Federal, State/Provincial, and Local
regulations regarding pollution.
Section 14 -- TRANSPORT INFORMATION
US Ground (DOT)
1 Gallon and Less may be Classed as CONSUMER COMMODITY, ORM-D
Larger Containers are Regulated as:
UN1263, PAINT, 3, PG II, (ERG#128)
DOT (Dept of Transportation) Hazardous Substances & Reportable Quantities
Ethyl methyl ketone 5000 lb RQ
Toluene 1000 lb RQ
Xylenes (isomers and mixture) 100 lb RQ
Bulk Containers may be Shipped as (check reportable quantities):
UN1263, PAINT, 3, PG II, (ERG#128)
Canada (TDG)
UN1263, PAINT, CLASS 3, PG II, (ERG#128)
IMO
UN1263, PAINT, CLASS 3, PG II, MARINE POLLUTANT, (2 C c.c.), (TRICRESYL
PHOSPHATE), EmS F-E, S-E
Section 15 -- REGULATORY INFORMATION
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
108-88-3 Toluene
67-56-1 Methanol
108-10-1 Methyl Isobutyl Ketone
Zinc Compound

% by WT
6
2
5
2

% Element

0.6

CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.

Continued on page 7

SF31

page 7

Section 16 -- OTHER INFORMATION
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

MATERIAL SAFETY DATA SHEET
SF31
03 00
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER
DATE OF PREPARATION
HMIS CODES
Health
SF31
29-SEP-07
Flammability
Reactivity
PRODUCT NAME
Scratch Filler & Primer, Gray

3*
3
0

MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS CO.
DUPLI-COLOR Products Group
Cleveland, OH 44115
TELEPHONE NUMBERS and WEBSITES
Product Information
(800) 247-3270
www.duplicolor.com
Regulatory Information
(216) 566-2902
www.paintdocs.com
Medical Emergency
(216) 566-2917
Transportation Emergency
for Chemical Emergency ONLY (spill, leak,
(800) 424-9300
fire, exposure, or accident)
% by WT
6

2

2

31

5

Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
108-88-3 Toluene
ACGIH TLV
20 ppm
22 mm
OSHA PEL
100 ppm (Skin)
OSHA PEL
150 ppm (Skin) STEL
67-56-1 Methanol
ACGIH TLV
200 ppm (Skin)
92 mm
ACGIH TLV
250 ppm (Skin) STEL
OSHA PEL
200 ppm (Skin)
OSHA PEL
250 ppm (Skin) STEL
67-63-0 2-Propanol
ACGIH TLV
400 ppm
33 mm
ACGIH TLV
500 ppm STEL
OSHA PEL
400 ppm
OSHA PEL
500 ppm STEL
78-93-3 Methyl Ethyl Ketone
ACGIH TLV
200 ppm
70 mm
ACGIH TLV
300 ppm STEL
OSHA PEL
200 ppm
OSHA PEL
300 ppm STEL
108-10-1 Methyl Isobutyl Ketone
ACGIH TLV
50 ppm
16 mm
ACGIH TLV
75 ppm STEL
OSHA PEL
50 ppm
OSHA PEL
75 ppm STEL

Continued on page 2

SF31

page 2

16

763-69-9

10

14807-96-6

4

471-34-1

6

13463-67-7

Ethyl 3-Ethoxypropionate
ACGIH TLV Not Available
1.11 mm
OSHA PEL Not Available
Talc
ACGIH TLV
2 mg/m3 as Resp. Dust
OSHA PEL
2 mg/m3 as Resp. Dust
Calcium Carbonate
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
15 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction
Titanium Dioxide
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction

Section 3 -- HAZARDS IDENTIFICATION
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, cardiovascular and reproductive
systems.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
Section 4 -- FIRST AID MEASURES
EYES:
SKIN:
INHALATION:
INGESTION:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
Do not induce vomiting.
Get medical attention immediately.

Continued on page 3

SF31

page 3

Section 5 -- FIRE FIGHTING MEASURES
FLASH POINT
LEL
UEL
36 F PMCC
1.0
36.5
FLAMMABILITY CLASSIFICATION
RED LABEL -- Flammable, Flash below 100 F (38 C)
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.
Section 6 -- ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
Section 7 -- HANDLING AND STORAGE
STORAGE CATEGORY
DOL Storage Class IB
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Contents are FLAMMABLE. Keep away from heat, sparks, and open flame.
During use and until all vapors are gone: Keep area ventilated - Do not
smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Keep container closed when not in use. Transfer only to approved
containers with complete and appropriate labeling. Do not take internally.
Keep out of the reach of children.
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).

Continued on page 4

SF31

page 4

VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
Wear gloves which are recommended by glove supplier for protection
against materials in Section 2.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT WEIGHT
8.89 lb/gal
1065 g/l
SPECIFIC GRAVITY
1.07
BOILING POINT
148 - 342 F
64 - 172 C
MELTING POINT
Not Available
VOLATILE VOLUME
78 %
EVAPORATION RATE
Slower than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
5.52 lb/gal
661 g/l
Less Water and Federally Exempt Solvents
5.52 lb/gal
661 g/l
Emitted VOC
Section 10 -- STABILITY AND REACTIVITY
STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur

Continued on page 5

SF31

page 5

Section 11 -- TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
Methyl Ethyl Ketone may increase the nervous system effects of other
solvents.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
IARC's Monograph No. 93 reports there is sufficient evidence of
carcinogenicity in experimental rats exposed to titanium dioxide but
inadequate evidence for carcinogenicity in humans and has assigned a Group
2B rating. In addition, the IARC summary concludes, "No significant
exposure to titanium dioxide is thought to occur during the use of products
in which titanium is bound to other materials, such as paint."
TOXICOLOGY DATA
CAS No.
Ingredient Name
108-88-3
Toluene
LC50
RAT
4HR
4000
ppm
LD50
RAT
5000
mg/kg
67-56-1
Methanol
LC50
RAT
4HR
64000
ppm
LD50
RAT
5630
mg/kg
67-63-0
2-Propanol
LC50
RAT
4HR
Not Available
LD50
RAT
5045
mg/kg
78-93-3
Methyl Ethyl Ketone
LC50
RAT
4HR
Not Available
LD50
RAT
2740
mg/kg
108-10-1
Methyl Isobutyl Ketone
LC50
RAT
4HR
Not Available
LD50
RAT
2080
mg/kg
763-69-9
Ethyl 3-Ethoxypropionate
LC50
RAT
4HR
Not Available
LD50
RAT
5000
mg/kg
14807-96-6
Talc
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
471-34-1
Calcium Carbonate
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
13463-67-7
Titanium Dioxide
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
Section 12 -- ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
No data available.

Continued on page 6

SF31

page 6

Section 13 -- DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Incinerate in approved facility. Do not incinerate closed container.
Dispose of in accordance with Federal, State/Provincial, and Local
regulations regarding pollution.
Section 14 -- TRANSPORT INFORMATION
US Ground (DOT)
1 Gallon and Less may be Classed as CONSUMER COMMODITY, ORM-D
Larger Containers are Regulated as:
UN1263, PAINT, 3, PG II, (ERG#128)
DOT (Dept of Transportation) Hazardous Substances & Reportable Quantities
Ethyl methyl ketone 5000 lb RQ
Toluene 1000 lb RQ
Xylenes (isomers and mixture) 100 lb RQ
Bulk Containers may be Shipped as (check reportable quantities):
UN1263, PAINT, 3, PG II, (ERG#128)
Canada (TDG)
UN1263, PAINT, CLASS 3, PG II, (ERG#128)
IMO
UN1263, PAINT, CLASS 3, PG II, MARINE POLLUTANT, (2 C c.c.), (TRICRESYL
PHOSPHATE), EmS F-E, S-E
Section 15 -- REGULATORY INFORMATION
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
108-88-3 Toluene
67-56-1 Methanol
108-10-1 Methyl Isobutyl Ketone
Zinc Compound

% by WT
6
2
5
2

% Element

0.6

CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.

Continued on page 7

SF31

page 7

Section 16 -- OTHER INFORMATION
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

FICHE SIGNALÉTIQUE SANTÉ-SÉCURITÉ
B5WV1014
01 00
===========================================================================
Section 1 -- IDENTIFICATION DU PRODUIT ET DE LA SOCIÉTÉ
--------------------------------------------------------------------------NUMÉRO DU PRODUIT
Santé
1*
B5WV1014
Inflammabilité
0
Réactivité
0
NOM DU PRODUIT
Interior Latex Flat Paint, Antique White
NOM DU FABRICANT
NO. DE TÉLÉPHONE EN CAS D'URGENCE
THE SHERWIN-WILLIAMS COMPANY
(216) 566-2917
101 Prospect Avenue N.W.
Cleveland, OH 44115
DATE DE PRÉPARATION
NO. DE TÉLÉPHONE ORDINAIRE
18-APR-07
(216) 566-2902
===========================================================================
Section 2 -- COMPOSITION/INFORMATION SUR LES INGRÉDIENTS
% EN POIDS
CAS No. INGREDIENT
UNITÉS
PRESSION VAPEUR
--------------------------------------------------------------------------0.3
14808-60-7 Quartz
ACGIH TLV
0.05 mg/m3 de resp. poussiére
OSHA PEL
0.1 mg/m3 de resp. poussiére
3
14464-46-1 Cristobalite
ACGIH TLV
0.05 mg/m3 de resp. poussiére
OSHA PEL
0.05 mg/m3 de resp. poussiére
7
1332-58-7 Kaolin
ACGIH TLV
2 mg/m3 de resp. poussiére
OSHA PEL
10 mg/m3 total de polva
OSHA PEL
5 mg/m3 fracción respirable
4
14807-96-6 Talc
ACGIH TLV
2 mg/m3 de resp. poussiére
OSHA PEL
2 mg/m3 de resp. poussiére
6
471-34-1 Carbonate de Calcium
ACGIH TLV
10 mg/m3 de poussiére
OSHA PEL
15 mg/m3 total de polva
OSHA PEL
5 mg/m3 fracción respirable
7
13463-67-7 Dioxyde de Titane
ACGIH TLV
10 mg/m3 de poussiére
OSHA PEL
10 mg/m3 total de polva
OSHA PEL
5 mg/m3 fracción respirable
===========================================================================
Section 3 -- IDENTIFICATION DES RISQUES
--------------------------------------------------------------------------SOURCES D'EXPOSITION
L'exposition peut se produire par l'INHALATION des vapeurs ou du
brouillard de pulvérisation.
La PEAU et les YEUX peuvent entrer en contact avec le produit, les
vapeurs ou le brouillard de pulvérisation.

Suite à la page 2

B5WV1014
page 2
===========================================================================
EFFET DE LA SUREXPOSITION
YEUX: Irritation des YEUX.
PEAU: L'exposition prolongée ou répétée risque de provoquer
l'irritation des peau.
INHALATION: Irritation des voies respiratoires supérieures.
Dans un espace restreint, les vapeurs en grande concentration peuvent
causer des maux de tête, des nausées ou l'étourdissement.
SYMPTÔMES DE SUREXPOSITION
La rougeur et les démangeaisons ou la sensation de brûlure peuvent
indiquer une exposition excessive des yeux ou de la peau.
ETAT DE SANTÉ AGGRAVÉ PAR EXPOSITION
En général, aucun exposition n'est reconnue.
CANCÉROGÉNICITÉ
Voir la Section 11.
===========================================================================
Section 4 -- PREMIERS SOINS
--------------------------------------------------------------------------YEUX:

Rincer les yeux à grande eau pendant 15 minutes.
Aller voir un médecin.
PEAU: Laver à fond les parties affectées avec de l'eau et
du savon.
Enlever les habits contaminés et les laver avant de les
porter de nouveau.
INHALATION: Si une personne en est affectée, l'aider à sortir
des lieux. Rétablir la respiration. Aider la
personne á rester calme et au chaud.
INGESTION: N'incitez pas la personne á vomir.
Aller voir un médecin immédiatement.
===========================================================================
Section 5 -- MESURES EN CAS D'INCENDIE
--------------------------------------------------------------------------POINT D'ÉCLAIR
LIE
LSE
Non applicable
P.D.
P.D.
CLASSIFICATION D'INFLAMMABILITÉ
Non applicable
MOYENS D'EXTINCTION
Dioxyde de carbone, produit chimique sec, mousse d'alcool
DANGERS D'INCENDIE OU D'EXPLOSION EXCEPTIONNELS
Les contenants fermés peuvent exploser (à cause de l'augmentation de la
pression) s'ils sont exposés à une chaleur extrême.
En cas d'urgence, une exposition excessive aux produits de décomposition
peut constituer un danger pour la santé. Les symptômes peuvent ne pas se
manifester immédiatement. Voir le médecin.
MESURES PARTICULIÉRES DI PROTECTION CONTRE L'INCENDIE
On doit utiliser l'équipement de protection complète y compris un
appareil de respiration auto-alimenté.
La pulvérisation avec de l'eau peut être inefficace. Si on se sert de
l'eau, l'ajutage pour brume est préférable. On peut se servir de l'eau
pour refroidir les contenants fermés afin d'empêcher l'augmentation de la
pression et la possibilité d'une combustion automatique ou l'explosion en
cas d'exposition à une chaleur extrêmement grande.

Suite à la page 3

B5WV1014
page 3
===========================================================================
Section 6 -- MARCHE Á SUIVRE EN CAS DE DÉVERSEMENT ACCIDENTEL
--------------------------------------------------------------------------MESURES À PRENDRE LORSQUE DES MATIÉRES SONT RENVERSÉES OU ÉVAPORÉES
Enlever toute source de combustion. Bien aérer.
Nettoyer avec un absorbant non réactif.
===========================================================================
Section 7 -- MANUTENTION ET ENTREPOSAGE
--------------------------------------------------------------------------CATÉGORIE D'ENTREPOSAGE
Non applicable
PRÉCAUTIONS Á PRENDRE LORS DE L'ENTREPOSAGE DI LA MANIPULATION
Garder le contenant fermé lorsqu'il n'est pas en usage. Transvaser
seulement dans des contenants approuvés et ayant des étiquettes complètes
et convenables. Ne pas avaler. Garder hors de la portée des enfants.
===========================================================================
Section 8 -- CONTRÔLE DE L'EXPOSITION ET PROTECTION INDIVIDUELLE
--------------------------------------------------------------------------PRÉCAUTIONS À PRENDRE AUCOURS DE L'UTILISATION
N'utiliser ce produit que dans un endroit bien aéré.
Éviter tout contact avec la peau et les yeux. Eviter d'aspirer les
vapeurs et la brume de vaporisation.
Bien se laver les mains après l'utilisation.
Ce produit peut contenir des matières classifiées comme petites
particules irritantes, telles que le dioxyde de titane ou le carbonate de
calcium (voir la liste ACGIH TLV, la préface et l'annexe D). On peut avoir
ces particules dans des proportions dangereuses uniquement au moment du
grattement et de l'éraflement de la couche séchée. Si la liste dans la 2e
section ne fait aucune mention spécifique de la présence des poussières de
particules, les limites applicables sont: pour ACGIH TLV 10 mg/m3
(concentration totale de poussière), 3 mg/m3 (fractionée de respiratoire).
L'enlèvement des anciennes peintures par ponçage, décapage ou toute
autre méthode risque de dégager des poussières ou des vapeurs contaminées
par le plomb. L'exposition à ces poussières ou vapeurs peut entraîner un
dysfonctionnement du cerveau ou d'autres effets néfastes sur la santé,
surtout chez les femmes enceintes et les enfants. L'utilisation
d'équipement de protection approprié, tel qu'un appareil respiratoire bien
ajusté et homologué par le NIOSH, ainsi que des moyens de confinement
adéquats et un nettoyage convenable de ces substances sont nécessaires afin
de contrôler l'exposition au plomb ou à d'autres substances dangereuses.
Pour obtenir plus de renseignements, communiquer avec le National Lead
Information Center au 1-800-424-5323 (aux É-U) ou avec le service local de
santé publique.
VENTILATION
Un système permettant l'échappement local des produits est préférable.
Si l'exposition aux produits de la 2e section est maintenue au-dessous des
limites d'exposition applicables, le système d'échappement global est
acceptable.

Suite à la page 4

B5WV1014
page 4
===========================================================================
PROTECTION DES VOIES RESPIRATOIRES
Si on ne peut pas maintenir, par simple ventilation, le niveau auquel on
s'expos personnellement en dessous des limites applicables, porter un
respirateur à filtre de vapeur organique et particules approprié et bien
ajusté approuvé par NIOSH/MSHA pour se protéger contre les produits de la
2e section.
Pendant que vous frottez ou poncez la couche sechée, porter un
respirateur à filtre de poussière et de brume, approuvé par NIOSH/MSHA pour
vous protéger contre la poussière qui peut éventuellement se dégager de ce
produit, de la peinture ou de l'abrasif.
GANTS PROTECTEURS
Porter les gants recommandés par le fournisseur de gants pour se
protéger contre les produits de la 2e section.
LUNETTES DE SÉCURITÉ
Porter les lunetttes de sécurité avec des protecteurs latéraux non
perforés.
===========================================================================
Section 9 -- PROPRIÉTÉS PHYSIQUES ET CHIMIQUES
--------------------------------------------------------------------------POIDS DU PRODUIT
11.39 lb/gal
1364 g/l
DENSITÉ
1.37
COURBE D'ÉBULLITION
212 - 213 F
100 - 100 C
POINT DE FUSION
P.D.
VOLUME VOLATIL
65 %
VITESSE D'ÉVAPORATION
Plus lent que l'Éther
DENSITÉ DE LA VAPEUR
Plus lourd que l'Air
SOLUBILITÉ DANS L'EAU
P.D.
pH
9.0
COMPOSÉS ORGANIQUES VOLATILS (Théorique)
0.37 lb/gal
44 g/l
Moins d'eau et de Solvants Exemptés
0.13 lb/gal
16 g/l
Émis COV
===========================================================================
Section 10 -- STABILITÉ ET RÉACTIVITÉ
--------------------------------------------------------------------------STABILITÉ -- Stable
CONDITIONS À ÉVITER
Aucun connu.
INCOMPATIBILITÉ
Aucun connu.
PRODUITS DANGEREUX DÛ À LA DÉCOMPOSITION
Par combustion: Dioxyde de carbone, monoxyde de carbone
POLYMÉRISATION DANGEREUSE
Ne Peut Pas De Produire

Suite à la page 5

B5WV1014
page 5
===========================================================================
Section 11 -- DONNÉES TOXICOLOGIQUES
--------------------------------------------------------------------------RISQUES DE SANTÉ CHRONIQUES
La silice crystalline (tel que le quartz ou le cristobalite) figure sur
la liste de l'IARC. L'exposition prolongée à de hautes concentrations de la
poussière de silice (situation pouvant se développer seulement au moment du
ponçage ou de l'éraflement de la couche sèche), peut provoquer des troubles
des poumons(appelés silicosis) et même le cancer.
Les rats exposés à la poussière de dioxyde de titanium à une
concentrations de 250mg/m3 ont développé le cancer des poumons. Toutefois,
on ne peut pas atteindre une telle concentration en milieu du travail.
--------------------------------------------------------------------------INFORMATION TOXICOLOGIQUE
CAS No.
Ingredient
--------------------------------------------------------------------------14808-60-7
Quartz
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
14464-46-1
Cristobalite
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
1332-58-7
Kaolin
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
14807-96-6
Talc
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
471-34-1
Carbonate de Calcium
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
13463-67-7
Dioxyde de Titane
LC50
RAT
4HR
Pas Disponible
LD50
RAT
Pas Disponible
===========================================================================
Section 12 -- DONNÉES ÉCOLOGIQUES
--------------------------------------------------------------------------Aucunes donnies disponibles.
===========================================================================
Section 13 -- DONNÉES SUR L'ÉLIMINATION DU PRODUIT
--------------------------------------------------------------------------MÉTHODE D'ÉLIMINATION DES DÉCHETS
Les déchets de ce produit ne présentent aucun danger, selon la
définition donnée dans la "U.S. Resource Conservation and Recovery Act"
(RCRA) 40 CFR 261.
Incinérer dans un endroit approuvé. Ne pas incinérer les contenants
fermés. Respecter les lois anti-pollution fédérales, provinciales et
municipales.

Suite à la page 6

B5WV1014
page 6
===========================================================================
Section 14 -- DONNÉES SUR LE TRANSPORT
--------------------------------------------------------------------------US Ground (DOT)
Not Regulated for Transportation.
Canada (TDG)
Not Regulated for Transportation.
IMO
Not Regulated for Transportation.
===========================================================================
Section 15 -- DONNÉES SUR LA RÉGLEMENTATION
--------------------------------------------------------------------------SARA 313 (40 CFR 372.65C) AVIS DE FOURNISSEUR
CAS No.
CHIMIQUE/COMPOSÉ
% by WT
% Element
--------------------------------------------------------------------------No ingredients in this product are subject to SARA 313 (40 CFR 372.65C)
Supplier Notification
CALIFORNIA PROPOSITION 65
AVERTISSEMENT: Ce produit des matières chimiques connue de l'État de la
Californie qui peut causer le cancer, dommages à la naissance ou autre
malformation congénitale.
DONNÉES SUR LA TSCA
Tous les produits chimiques dans ce produit sont énumérés, ou exemptez
de l'énumération, sur le inventaire de TSCA.
===========================================================================
Section 16 -- AUTRES DONNÉES
--------------------------------------------------------------------------Cette FTSS a été préparée conformént aux exigences du SIMDUT; les
données sont toutefois présentées sous 16 rubriques.

Les renseignements donnés ci-haut se rapportent à ce produit suivant sa
formule actuelle et s'appuient sur les données disponibles en ce moment.
L'addition de diluant et autres additifs peut changer considérablement les
risques associés à ce produit et sa composition. Etant donné que nous
n'avons pas de contrôle sur les conditions d'utilisation, nous ne donnons
aucune guarantie, explicite ou implicite et nous n'assumons aucune
responsabilité concernant l'usage, quel qu'il soit, de ces renseignements.

MATERIAL SAFETY DATA SHEET
B30HV8003
04 00
===========================================================================
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
--------------------------------------------------------------------------PRODUCT NUMBER
HMIS CODES
Health
1*
B30HV8003
Flammability
0
Reactivity
0
PRODUCT NAME
Interior Latex Flat Paint, Dover White
MANUFACTURER'S NAME
EMERGENCY TELEPHONE NO.
THE SHERWIN-WILLIAMS COMPANY
(216) 566-2917
101 Prospect Avenue N.W.
Cleveland, OH 44115
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
18-APR-07
(216) 566-2902
===========================================================================
Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
--------------------------------------------------------------------------1
64742-54-7 Heavy Paraffinic Oil
ACGIH TLV
5 mg/m3 as Mist
OSHA PEL
5 mg/m3 as Mist
0.2
14808-60-7 Quartz
ACGIH TLV
0.05 mg/m3 as Resp. Dust
OSHA PEL
0.1 mg/m3 as Resp. Dust
2
14464-46-1 Cristobalite
ACGIH TLV
0.05 mg/m3 as Resp. Dust
OSHA PEL
0.05 mg/m3 as Resp. Dust
21
471-34-1 Calcium Carbonate
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
15 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction
12
13463-67-7 Titanium Dioxide
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction
===========================================================================
Section 3 -- HAZARDS IDENTIFICATION
--------------------------------------------------------------------------ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
Continued on page 2

B30HV8003
page 2
===========================================================================
For complete discussion of toxicology data refer to Section 11.
===========================================================================
Section 4 -- FIRST AID MEASURES
--------------------------------------------------------------------------EYES:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 -- FIRE FIGHTING MEASURES
--------------------------------------------------------------------------FLASH POINT
LEL
UEL
Not Applicable
N.A.
N.A.
FLAMMABILITY CLASSIFICATION
Not Applicable
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Alcohol Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers may explode (due to the build-up of pressure) when
exposed to extreme heat.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.
===========================================================================
Section 6 -- ACCIDENTAL RELEASE MEASURES
--------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
===========================================================================
Section 7 -- HANDLING AND STORAGE
--------------------------------------------------------------------------STORAGE CATEGORY
Not Applicable
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep container closed when not in use. Transfer only to approved
containers with complete and appropriate labeling. Do not take internally.
Keep out of the reach of children.

Continued on page 3

B30HV8003
page 3
===========================================================================
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
--------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
Removal of old paint by sanding, scraping or other means may generate
dust or fumes that contain lead. Exposure to lead dust or fumes may cause
brain damage or other adverse health effects, especially in children or
pregnant women. Controlling exposure to lead or other hazardous substances
requires the use of proper protective equipment, such as a properly fitted
respirator (NIOSH approved) and proper containment and cleanup. For more
information, call the National Lead Information Center at 1-800-424-LEAD
(in US) or contact your local health authority.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
Required for long or repeated contact.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
===========================================================================
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
--------------------------------------------------------------------------PRODUCT WEIGHT
11.10 lb/gal
1329 g/l
SPECIFIC GRAVITY
1.34
BOILING POINT
212 - 213 F
100 - 100 C
MELTING POINT
Not Available
VOLATILE VOLUME
71 %
EVAPORATION RATE
Slower than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
9.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
0.15 lb/gal
18 g/l
Less Water and Federally Exempt Solvents
0.04 lb/gal
5 g/l
Emitted VOC

Continued on page 4

B30HV8003
page 4
===========================================================================
Section 10 -- STABILITY AND REACTIVITY
--------------------------------------------------------------------------STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
===========================================================================
Section 11 -- TOXICOLOGICAL INFORMATION
--------------------------------------------------------------------------CHRONIC HEALTH HAZARDS
Crystalline Silica (Quartz, Cristobalite) is listed by IARC and NTP.
Long term exposure to high levels of silica dust, which can occur only when
sanding or abrading the dry film, may cause lung damage (silicosis) and
possibly cancer.
Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung
cancer, however, such exposure levels are not attainable in the workplace.
--------------------------------------------------------------------------TOXICOLOGY DATA
CAS No.
Ingredient Name
--------------------------------------------------------------------------64742-54-7
Heavy Paraffinic Oil
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
14808-60-7
Quartz
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
14464-46-1
Cristobalite
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
471-34-1
Calcium Carbonate
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
13463-67-7
Titanium Dioxide
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
===========================================================================
Section 12 -- ECOLOGICAL INFORMATION
--------------------------------------------------------------------------ECOTOXICOLOGICAL INFORMATION
No data available.
===========================================================================
Section 13 -- DISPOSAL CONSIDERATIONS
--------------------------------------------------------------------------WASTE DISPOSAL METHOD
Waste from this product is not hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Incinerate in approved facility. Do not incinerate closed container.
Dispose of in accordance with Federal, State/Provincial, and Local
regulations regarding pollution.
Continued on page 5

B30HV8003
page 5
===========================================================================
Section 14 -- TRANSPORT INFORMATION
--------------------------------------------------------------------------US Ground (DOT)
Not Regulated for Transportation.
Canada (TDG)
Not Regulated for Transportation.
IMO
Not Regulated for Transportation.
===========================================================================
Section 15 -- REGULATORY INFORMATION
--------------------------------------------------------------------------SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
--------------------------------------------------------------------------No ingredients in this product are subject to SARA 313 (40 CFR 372.65C)
Supplier Notification.
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
===========================================================================
Section 16 -- OTHER INFORMATION
--------------------------------------------------------------------------This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

MATERIAL SAFETY DATA SHEET
7915
01 00
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER
DATE OF PREPARATION
HMIS CODES
Health
7915
29-SEP-07
Flammability
Reactivity
PRODUCT NAME
KRYLON® Industrial ECO-GUARD™ Latex Enamel, Gray Primer

2*
2
0

MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS COMPANY
Diversified Brands
Cleveland, OH 44115
TELEPHONE NUMBERS and WEBSITES
Product Information
(800) 247-3266
Regulatory Information
(216) 566-2902
www.paintdocs.com
Medical Emergency
(216) 566-2917
Transportation Emergency
for Chemical Emergency ONLY (spill, leak,
(800) 424-9300
fire, exposure, or accident)
% by WT
1
6
7

38
0.1
10
2

Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
71-36-3 1-Butanol
ACGIH TLV
20 ppm (Skin)
5.5 mm
OSHA PEL
50 ppm (Skin) CEILING
111-76-2 2-Butoxyethanol
ACGIH TLV
20 ppm
0.88 mm
OSHA PEL
25 ppm
67-64-1 Acetone
ACGIH TLV
500 ppm
180 mm
ACGIH TLV
750 ppm STEL
OSHA PEL
1000 ppm
115-10-6 Dimethyl Ether
ACGIH TLV Not Available
760 mm
OSHA PEL Not Available
14808-60-7 Quartz
ACGIH TLV
0.05 mg/m3 as Resp. Dust
OSHA PEL
0.1 mg/m3 as Resp. Dust
14807-96-6 Talc
ACGIH TLV
2 mg/m3 as Resp. Dust
OSHA PEL
2 mg/m3 as Resp. Dust
13463-67-7 Titanium Dioxide
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction

Continued on page 2

7915

page 2

Section 3 -- HAZARDS IDENTIFICATION
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary and blood forming systems.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
Section 4 -- FIRST AID MEASURES
EYES:
SKIN:
INHALATION:
INGESTION:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
Do not induce vomiting.
Get medical attention immediately.

Section 5 -- FIRE FIGHTING MEASURES
FLASH POINT
LEL
UEL
Propellant < 0 F
1.1
27.0
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Alcohol Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers may explode (due to the build-up of pressure) when
exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.
Continued on page 3

7915

page 3

Section 6 -- ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
Section 7 -- HANDLING AND STORAGE
STORAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated - Do not
smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.

Continued on page 4

7915

page 4

Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT WEIGHT
7.40 lb/gal
886 g/l
SPECIFIC GRAVITY
0.89
BOILING POINT
<0 - 343 F
<-18 - 172 C
MELTING POINT
Not Available
VOLATILE VOLUME
88 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
Volatile Weight 46.70% Less Water and Federally Exempt Solvents
Section 10 -- STABILITY AND REACTIVITY
STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
Section 11 -- TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
Crystalline Silica (Quartz, Cristobalite) is listed by IARC and NTP.
Long term exposure to high levels of silica dust, which can occur only when
sanding or abrading the dry film, may cause lung damage (silicosis) and
possibly cancer.
IARC's Monograph No. 93 reports there is sufficient evidence of
carcinogenicity in experimental rats exposed to titanium dioxide but
inadequate evidence for carcinogenicity in humans and has assigned a Group
2B rating. In addition, the IARC summary concludes, "No significant
exposure to titanium dioxide is thought to occur during the use of products
in which titanium is bound to other materials, such as paint."
TOXICOLOGY DATA

Continued on page 5

7915
CAS No.
71-36-3
111-76-2
67-64-1
115-10-6
14808-60-7
14807-96-6
13463-67-7

page 5
Ingredient Name
1-Butanol
LC50
LD50
2-Butoxyethanol
LC50
LD50
Acetone
LC50
LD50
Dimethyl Ether
LC50
LD50
Quartz
LC50
LD50
Talc
LC50
LD50
Titanium Dioxide
LC50
LD50

RAT
RAT

4HR

8000
790

ppm
mg/kg

RAT
RAT

4HR

Not Available
470
mg/kg

RAT
RAT

4HR

Not Available
5800
mg/kg

RAT
RAT

4HR

Not Available
Not Available

RAT
RAT

4HR

Not Available
Not Available

RAT
RAT

4HR

Not Available
Not Available

RAT
RAT

4HR

Not Available
Not Available

Section 12 -- ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
No data available.
Section 13 -- DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.
Section 14 -- TRANSPORT INFORMATION
US Ground (DOT)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126)
Canada (TDG)
May be classed as Consumer Commodity, ORM-D
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126)
IMO
May be shipped as Limited Quantity
UN1950, AEROSOLS, CLASS 2, LIMITED QUANTITY, EmS F-D, S-U

Continued on page 6

7915

page 6

Section 15 -- REGULATORY INFORMATION
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
71-36-3 1-Butanol
Zinc Compound
Glycol Ethers

% by WT
1
2
6

% Element
0.6

CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
Section 16 -- OTHER INFORMATION
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

MATERIAL SAFETY DATA SHEET
.

1. Product and Company Identification
space

Product Name

Porcelain Repair: White - PA40FP88, Almond - PA40FP89, Grey - PA40FP90
Mixture

space

CAS #
space

Coating

Product Use
space

Mumby & Associates Limited
7040 Financial Drive
Mississauga, ON L5N 7H5 CA
Phone 905-812-9319
Emergency Phone: 1-613-996-666 (CANUTEC)

Manufacturer

space

LEGEND
HMIS/NFPA
Severe
Serious
Moderate
Slight
Minimal

Health
4
3
2
1
0

*

2

Flammability

3

Physical Hazard

0

Personal Protection

3
2

0

B

.

2. Hazards Identification
space

DANGER
Flammable liquid - may release vapours that form flammable mixtures at or above the
flash point. Containers may explode when heated.
MAY CAUSE EYE AND SKIN IRRITATION.
Contains a potential teratogen.

Emergency Overview

space

Potential short term health effects
Routes of exposure

Eye, Skin contact, Skin absorption, Inhalation, Ingestion.

space

Eyes

May cause irritation.

Skin

May cause irritation.

Inhalation

May cause respiratory tract irritation.

Ingestion

May cause stomach distress, nausea or vomiting.

space

space

space

space

Target organs

Blood. Eyes. Kidney. Liver. Respiratory system. Skin.

space

Chronic effects

Prolonged or repeated exposure can cause drying, defatting and dermatitis.

space

Signs and symptoms

Symptoms may include redness, oedema, drying, defatting and cracking of the skin.
Symptoms of overexposure may be headache, dizziness, tiredness, nausea and
vomiting.

.

3. Composition/Information on Ingredients
space

Ingredient(s)

CAS #

Percent

Xylene

1330-20-7

1-5

Solvent naphtha (petroleum), light aromatic

64742-95-6

10 - 30

1,2,4-Trimethylbenzene

95-63-6

10 - 30

Toluene

108-88-3

5 - 10

.

4. First Aid Measures
space

First aid procedures
Eye contact
space

Skin contact
space

Inhalation
space

Ingestion

#13802

Flush with cool water. Remove contact lenses, if applicable, and continue flushing.
Obtain medical attention if irritation persists.
Flush with cool water. Wash with soap and water. Obtain medical attention if irritation
persists.
If symptoms develop move victim to fresh air. If symptoms persist, obtain medical
attention.
Do not induce vomiting. Rinse mouth with water, then drink one or two glasses of water.
Obtain medical attention. Never give anything by mouth if victim is unconscious, or is
convulsing.
Page 1 of 5

Issue date

08-Aug-2006

space

Symptoms may be delayed.

Notes to physician
space

If you feel unwell, seek medical advice (show the label where possible). Ensure that
medical personnel are aware of the material(s) involved, and take precautions to protect
themselves. Show this safety data sheet to the doctor in attendance.

General advice

.

5. Fire-fighting Measures
space

Flammable by WHMIS criteria. Vapours may travel to a source of ignition and flash
back. Containers may explode when heated.

Flammable properties
space

Extinguishing media
Suitable extinguishing media

Dry chemical. Foam. Carbon dioxide.

space

Unsuitable extinguishing media Not available
space

Protection of firefighters
Specific hazards arising from
the chemical

Not available

space

Protective equipment for
firefighers

Firefighters should wear full protective clothing including self contained breathing
apparatus.

space

Hazardous combustion products

May include and are not limited to: Oxides of carbon.

space

Explosion data
Sensitivity to mechanical
impact

Not available

space

Sensitivity to static discharge

Not available

.

6. Accidental Release Measures
space

Keep unnecessary personnel away. Do not touch damaged containers or spilled material
unless wearing appropriate protective clothing. Keep people away from and upwind of
spill/leak.
Stop leak if you can do so without risk. Prevent entry into waterways, sewers,
basements or confined areas.
Before attempting clean up, refer to hazard data given above. Small spills may be
absorbed with non-reactive absorbent and placed in suitable, covered, labelled
containers. Prevent large spills from entering sewers or waterways. Contact emergency
services and supplier for advice. Remove sources of ignition.

Personal precautions
space

Methods for containment
space

Methods for cleaning up

.

7. Handling and Storage
space

Use according to package label instructions.

Handling
space

Keep out of reach of children.Store in a closed container away from incompatible
materials. Keep away from heat, open flames or other sources of ignition.

Storage
.

8. Exposure Controls / Personal Protection
space

Exposure limits
Ingredient(s)

Exposure limits

1,2,4-Trimethylbenzene

ACGIH-TLV
TWA: 25 ppm

Solvent naphtha (petroleum), light aromatic

ACGIH-TLV
Not established

Toluene

ACGIH-TLV
TWA: 50 ppm
Skin: 50 ppm

Xylene

ACGIH-TLV
TWA: 100 ppm
STEL: 150 ppm

space

Engineering controls

General ventilation normally adequate.

space

Personal protective equipment
Eye/Face protection
#13802

Safety glasses
Page 2 of 5

Issue date

08-Aug-2006

space

Rubber gloves. Confirm with a reputable supplier first.

Hand protection
space

Skin and body protection

As required by employer code.

Respiratory protection

Not normally required if good ventilation is maintained.

space

space

General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. When using do
not eat or drink. Wash hands before breaks and immediately after handling the product.
.

9. Physical & Chemical Properties
space

Opaque.

Appearance
space

Varies

Colour
space

Liquid

Form
space

Strong Hydrocarbon

Odour
space

Not available

Odour threshold
space

Liquid

Physical state
space

Not available

pH
space

Not available

Freezing point
space

110 °C (230.00 °F)

Boiling point
space

7.2 °C (44.96 °F) TCC

Flash point
space

> 1 (Ether = 1)

Evaporation Rate
space

Flammability limits in air, lower, %
by volume

1

space

Flammability Limits in Air, Upper, % 12.6
by Volume
Not available
Vapour pressure
space

space

> 1 (Air = 1)

Vapour density
space

1.15 (H2O = 1)

Specific gravity
space

Not available

Octanol/water coefficient
space

Insoluble

Solubility (H2O)
space

Auto-ignition temperature

Not available

space

45 - 55

VOC (Weight %)
space

Slightly viscous

Viscosity
.

10. Chemical Stability & Reactivity Information
space

Chemical stability

Stable under recommended storage conditions.

space

Conditions to avoid

Avoid high temperatures. Do not mix with other chemicals.

space

Incompatible materials

Strong oxidizing agents. Acids.

space

Hazardous decomposition products May include and are not limited to: Oxides of carbon.
Hazardous polymerisation does not occur.
Possibility of hazardous reactions
space

.

11. Toxicological Information
space

Component analysis - LC50
Ingredient(s)

LC50

1,2,4-Trimethylbenzene

3661 ppm rat

Solvent naphtha (petroleum), light aromatic

> 10.2 mg/L rat

Toluene

5100 ppm rat; 19 mg/l/4h rat

Xylene

6350 ppm rat

space

Component analysis - Oral LD50
Ingredient(s)

LD50

1,2,4-Trimethylbenzene

3280 mg/kg rat

Solvent naphtha (petroleum), light aromatic

4700 mg/kg rat

Toluene

636 mg/kg rat

Xylene

3523 mg/kg rat

#13802

Page 3 of 5

Issue date

08-Aug-2006

space

Effects of acute exposure
Eye

May cause irritation.

space

Skin

May cause irritation.

Inhalation

May cause respiratory tract irritation.

Ingestion

May cause stomach distress, nausea or vomiting.

space

space

space

Non-hazardous by WHMIS criteria.

Sensitisation
space

Contains a potential teratogen.

Chronic effects
space

Non-hazardous by WHMIS criteria.

Carcinogenicity

ACGIH - Threshold Limits Values - Carcinogens
Toluene
Xylene

108-88-3
1330-20-7

A4 - Not Classifiable as a Human Carcinogen
A4 - Not Classifiable as a Human Carcinogen

space

Mutagenicity

Non-hazardous by WHMIS criteria.

space

Reproductive effects

Non-hazardous by WHMIS criteria.

space

Teratogenicity

Contains potential teratogens.

.

12. Ecological Information
space

Ecotoxicity effects
space

Environmental effects

Components of this product have been identified as having potential environmental
concerns.
Harmful to aquatic life.

space

Aquatic toxicity

Not available

space

Persistence and degradability

Not available

space

Bioaccumulation/accumulation

Not available

space

Partition coefficient

Not available

space

Mobility in environmental media

Not available

space

Chemical fate information

Not available

.

13. Disposal Considerations
space

Waste codes

Not available

space

Disposal instructions

Review federal, provincial, and local government requirements prior to disposal.

space

Waste from residues / unused
products

Not available

space

Contaminated packaging

Not available

.

14. Transport Information
space

Transportation of Dangerous Goods (TDG)
Basic shipping requirements:
Proper shipping name

PAINT

Hazard class

3

UN number

1263

Packing group

II

Additional information:
Special provisions

59

.

15. Regulatory Information
space

Canadian federal regulations
space

WHMIS classification

#13802

This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulations and the MSDS contains all the information required by the
Controlled Products Regulations.
Exempt - Consumer product

Page 4 of 5

Issue date

08-Aug-2006

space

Inventory Status
Country(s) or region
Canada
Canada

Inventory Name
Domestic Substances List (DSL)
Non-Domestic Substances List (NDSL)

On Inventory (Yes/No)*
Yes
No

.

16. Other Information
space

Disclaimer

space

Issue date

Information contained herein was obtained from sources considered technically accurate
and reliable. While every effort has been made to ensure full disclosure of product
hazards, in some cases data is not available and is so stated. Since conditions of actual
product use are beyond control of the supplier, it is assumed that users of this material
have been fully trained according to the requirements of all applicable legislation and
regulatory instruments. No warranty, expressed or implied, is made and supplier will not
be liable for any losses, injuries or consequential damages which may result from the
use of or reliance on any information contained in this document.
08-Aug-2006

space

Effective Date

15-Aug-2006

space

Expiry Date

15-Aug-2009

space

Prepared by

#13802

Dell Tech Laboratories Ltd. (519) 858-5021

Page 5 of 5

Issue date

08-Aug-2006

MATERIAL SAFETY DATA SHEET

SPRAYTEX, Inc.
28430 West Witherspoon Parkway
Valencia, CA 91355

Emergency (800) 234-5979
Information (661) 257-8787

SPRAYTEX WHITE CEILING TEXTURE
Latest Revision Date 6/21/94

Print Date 1/1/01

SECTION 1

PRODUCT IDENTIFICATION

PRODUCT NAME OR NUMBER ................................................ SPRC004 [4044-W]
TRADE NAME OR CHEMICAL NAME ....................................... SPRAYTEX WHITE CEILING TEXTURE
SYNONYMS................................................................................ NA
FORMULA................................................................................... TSP0401 (L29326)
CHEMICAL FAMILY.................................................................... NA
MOLECULAR WEIGHT .............................................................. NA
NFPA........................................................................................... NA
HMIS RATING............................................................................. HEALTH=1; FLAMMABILITY=0; REACTIVITY=0
SECTION 2
CHEMICAL NAMES

HAZARDOUS INGREDIENTS / HAZARD DATA
CAS NUMBER

% WT

TLV-TWA

CALCIUM CARBONATE

471-34-1

47

0.1mg/m3

NOT ESTABLISHED

NO

DIMETHYL ETHER

115-10-6

9

NONE ESTABLISHED

NONE ESTABLISHED

NO

068476-86-8

1

1000ppm

NOT ESTABLISHED

NO

MIXTURE OF:
PROPANE/ISOBUTANE

PEL

SEC.313

*Information for mixtures is based on constituent MSDS which are available upon request. (Minus Proprietary Trade Names)
SECTION 3
PHYSICAL DATA
BOILING/MELTING POINT @760 mm Hg ................................. NOT ESTABLISHED
pH................................................................................................ NOT ESTABLISHED
VAPOR PRESSURE mm Hg @ 20° C........................................ 90 psig @ 70° F
VAPOR DENSITY (Air = 1) ......................................................... >1
PERCENT VOLATILE BY WEIGHT(%) ...................................... NA
SPECIFIC GRAVITY OR BULK DENSITY ................................. 1.25
SOLUBILITY IN WATER ............................................................. MISCIBLE
EVAPORATION RATE (BuAc = 1).............................................. 1
APPEARANCE............................................................................ OFF WHITE, TAN & GRAY THICK PASTE
ODOR.......................................................................................... CHARACTERISTIC FRAGRANCE
INTENSITY.................................................................................. NA
SECTION 4
FIRE AND EXPLOSION HAZARD DATA
FLASH POINT °f (Test Method) .................................................. NON-FLAMMABLE
AUTOIGNITION TEMPERATURE .............................................. NOT ESTABLISHED
FLAMMABILITY LIMITS IN AIR (% V) ........................................ NA
EXTINGUISHING MEDIA . . . . . . . . . . . ANY MEDIA CAPABLE OF EXTINGUISHING THE SUPPORTING FIRE.
SPECIAL FIRE FIGHTING PROCEDURES . . KEEP TEMPERATURES OF CONTAINERS BELOW 120° f BY SPRAYING
WITH WATER UNTIL FIRE HAS BEEN EXTINGUISHED.
UNUSUAL FIRE & EXPLOSION HAZARDS . . CONTAINERS MAY RUPTURE AND RELEASE A SMALL AMOUNT OF
FLAMMABLE GAS IF EXPOSED TO HEAT OF FIRE.
SECTION 5
HEALTH HAZARDS DATA * EFFECTS OF OVEREXPOSURE
SKIN CONTACT................WASH EXCESS MATERIAL FROM SKIN WITH SOAP & WATER.
EYE CONTACT.................FLUSH EYES WITH WARM WATER FOR 10 MINUTES.
CONSULT A PHYSICIAN IF IRRITATION OCCURS OR WORSENS.
INHALATION.....................IF INHALED EXCESSIVELY, REMOVE TO FRESH AIR.
INGESTION.......................PRODUCT IS NOT LIKELY TO BE INGESTED. IF THIS OCCURS TREAT SYMPTOMATICALLY.
CHRONIC EFFECTS OF OVEREXPOSURE..........NONE WHEN USED AS DIRECTED.
TOXICOLOGICAL TEST DATA ...............................NO RESULTS AVAILABLE.
note: ALL CHEMICALS ARE LISTED ON THE TSCA INVENTORY.

SPRAYTEX WHITE CEILING TEXTURE
SECTION 6
EMERGENCY AND FIRST AID PROCEDURES
SKIN .................. Wash affected area with water while removing contaminated clothing.
GET IMMEDIATE MEDICAL ATTENTION. Launder contaminated clothing before reuse.
EYES.................. Flush eyes with generous amounts of water for at least 15 minutes.
GET IMMEDIATE MEDICAL ATTENTION.
INGESTION........ If swallowed, DO NOT INDUCE VOMITING. Dilute with water or milk. CALL A PHYSICIAN IMMEDIATELY.
Never give fluids or induce vomiting if the victim is unconscious or having convulsions.
INHALATION...... Move to fresh air. Aid in breathing, if necessary and get immediate medical attention.
SECTION 7
REACTIVITY DATA
PRODUCT STABILITY ....................................... STABLE
CONDITIONS TO AVOID ............................... NONE KNOWN. CONTENTS ARE STABLE BUT UNDER PRESSURE.
DO NOT PUNCTURE OR INCINERATE CONTAINERS, EVEN WHEN EMPTY.
CHEMICAL INCOMPATIBILITY.......................... KEEP AWAY FROM ACIDS.
HAZARDOUS DECOMPOSITION PRODUCTS. CALCIUM OXIDE MAY BE PRODUCED ON DECOMPOSITION.
HAZARDOUS POLYMERIZATION..................... WILL NOT OCCUR.
CONDITIONS TO AVOID ............................... NONE KNOWN.
CORROSIVE TO METAL.................................... NO.
OXIDIZER ........................................................... NA
SECTION 8
SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION............. NIOSH/MSHA - Approved organic vapor respirator when vapors are generated above
............................................................... the permissible limit
VENTILATION........................................ Local exhaust to control to recommended P.E.L.
PROTECTIVE CLOTHING..................... Gloves, coveralls, aprons, boots, - as necessary to prevent skin contact.
EYE PROTECTION ............................... Chemical Goggles
OTHER PRECAUTIONS........................ Avoid excessive inhalations. Read and follow all label directions and cautions.
Eyewash fountains should be easily accessible.
SECTION 9
ENVIRONMENTAL DATA
ENVIRONMENTAL TOXICITY DATA ..............NA
SPILL OR LEAK PROCEDURES ....................LEAKING CONTAINERS SHOULD BE PLACED IN AN OPENED CONTAINER,
OUTDOORS, AWAY FROM SOURCES OF IGNITION, UNTIL ALL PRESSURE IS RELEASED.
HAZARDOUS SUBSTANCE SUPERFUND ....NA
WASTE DISPOSAL METHOD..... BURY OR INCINERATE IN APPROVED DISPOSAL FACILITIES IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REGULATION.
CONTAINER DISPOSAL ............. EMPTY CONTAINERS & DRIED PRODUCT MAY BE DISPOSED OF AS NORMAL
REFUSE.
SECTION 10
SHIPPING DATA
D.O.T. PROPER SHIPPING NAME......................................CONSUMER COMMODITY
HAZARDOUS SUBSTANCE 49CFR CERCLA.....................NA
D.O.T. HAZARD CLASS .......................................................ORM-D
D.O.T. LABELS REQUIRED .................................................NONE
D.O.T. PLACARDS REQUIRED ...........................................NONE
POISON CONSTITUENT......................................................NONE
BILL OF LADING DESCRIPTION.........................................CONSUMER COMMODITY ORM-D
CC NO...................................................................................NA
UN/NA CODE........................................................................NONE

SECTION 11
SUPPLIER INFORMATION
The information contained herein is, to the best of our knowledge and belief, accurate and reliable as of the
date of issued. We do not however, warrant or guarantee the accuracy or reliability, nor shall we be liable
for any loss or damage arising out of the use thereof. The information is offered for the user's
consideration and examination, and it is the user's responsibility to satisfy himself that it is suitable and
complete for his particular use.
PREPARED BY: J. STATEN, TECHNICAL SPECIALIST 6/21/94 / REFORMATTED: S. THOMAS 3/1/96

712828.txt

MATERIAL SAFETY DATA SHEET
SPRAYTEX, INC.
28430 WEST WITHERSPOON PARKWAY
VALENCIA, CA 91355
EMERGENCY: (800) 234-5979
INFORMATION: (661) 257-8787

SPRAYTEX CONTRACTOR SIZE ORANGEPEEL DRYWALL SPRAY TEXTURE
LATEST REVISION DATE: 6/21/94
PRINT DATE: 1/1/01
------SECTION 1 PRODUCT IDENTIFICATION -----PRODUCT NAME OR NUMBER: SPRC003 (5055)
TRADE NAME OR CHEMICAL NAME: SPRAYTEX CONTRACTOR SIZE ORANGEPEEL
SYNONYMS: NA
FORMULA: TSP0301 (L29145)
CHEMICAL FAMILY: NA
MOLECULAR WEIGHT: NA
NFPA:
HEALTH
1
FLAMMABILITY 4
REACTIVITY
0
HMIS RATING:
HEALTH
1
FLAMMABILITY 4
REACTIVITY
0
------SECTION 2 HAZARDOUS INGREDIENTS / HAZARD DATA -----CHEMICAL NAMES

CAS NUMBER

% WT

TLV - TWA

PEL

SEC. 313

CALCIUM CARBONATE

471-34-1

47

0.1 MG/M3

NOT
ESTABLISHED

NO

ISOPROPYL ALCOHOL

67-63-0

6

400 PPM

400 PPM

NO

10

NONE
ESTABLISHED

NONE
ESTABLISHED

NO

DIMETHYL ETHER

115-10-6

*INFORMATION FOR MIXTURES IS BASED ON CONSTITUENT MSDS WHICH ARE AVAILABLE
UPON REQUEST. (MINUS PROPRIETARY TRADE NAMES)
------SECTION 3 PHYSICAL DATA -----BOILING/MELTING POINT @ 760 MMHg: NOT ESTABLISHED
pH: NOT ESTABLISHED
VAPOR PRESSURE MMHg @ 20 DEG. C: 60 PSIG @ 70 DEG. F
Page 1

VAPOR DENSITY (AIR = 1): >1

712828.txt

PERCENT VOLATILE BY WEIGHT (%): NA
SPECIFIC GRAVITY OR BULK DENSITY: 1.25
SOLUBILITY IN WATER: MISCIBLE
EVAPORATION RATE (BuAc = 1): 1
APPEARANCE: OFF WHITE THICK PASTE
ODOR: CITRUS
INTENSITY: NA
------SECTION 4 FIRE AND EXPLOSION HAZARD DATA -----FLASH POINT DEG. F (TEST METHOD): -42 DEG. F TOC
AUTOIGNITION TEMPERATURE: 622 DEG. F
FLAMMABILITY LIMITS IN AIR (% V):
LEL: 3.4 %
UEL: 18.0 %
EXTINGUISHING MEDIA: ANY MEDIA CAPABLE OF EXTINGUISHING THE SUPPORTING FIRE.
SPECIAL FIRE FIGHTING PROCEDURES:
KEEP TEMPERATURES OF CONTAINERS BELOW 120 DEG. F BY SPRAYING WITH WATER UNTIL
FIRE HAS BEEN EXTINGUISHED.
UNUSUAL FIRE & EXPLOSION HAZARDS:
CONTAINERS MAY RUPTURE AND RELEASE A SMALL AMOUNT OF FLAMMABLE GAS IF EXPOSED
TO HEAT OF FIRE.
------SECTION 5 HEALTH HAZARDS DATA * EFFECTS OF OVEREXPOSURE -----SKIN CONTACT: WASH EXCESS MATERIAL FROM SKIN WITH SOAP & WATER.
EYE CONTACT:
FLUSH EYES WITH WARM WATER FOR 10 MINUTES.
CONSULT A PHYSICIAN IF IRRITATION OCCURS OR WORSENS.
INHALATION: IF INHALED EXCESSIVELY, REMOVE TO FRESH AIR.
INGESTION:
PRODUCT IS NOT LIKELY TO BE INGESTED. IF THIS OCCURS TREAT SYMPTOMATICALLY.
CHRONIC EFFECTS OF OVEREXPOSURE: NONE WHEN USED AS DIRECTED.
TOXICOLOGICAL TEST DATA: NO RESULTS AVAILABLE.
NOTE: ALL CHEMICALS ARE LISTED ON THE TSCA INVENTORY.
------SECTION 6 EMERGENCY AND FIRST AID PROCEDURES -----SKIN:
WASH AFFECTED AREA WITH WATER WHILE REMOVING CONTAMINATED CLOTHING. GET
IMMEDIATE MEDICAL ATTENTION. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
EYES:
FLUSH EYES WITH GENEROUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
Page 2

GET IMMEDIATE MEDICAL ATTENTION.

712828.txt

INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. DILUTE WITH WATER OR MILK. CALL A
PHYSICIAN IMMEDIATELY. NEVER GIVE FLUIDS OR INDUCE VOMITING IF THE VICTIM
IS UNCONSCIOUS OR HAVING CONVULSIONS.
INHALATION:
MOVE TO FRESH AIR. AID IN BREATHING, IF NECESSARY AND GET IMMEDIATE MEDICAL
ATTENTION.
------SECTION 7 REACTIVITY DATA -----PRODUCT STABILITY: STABLE
CONDITIONS TO AVOID:
NONE KNOWN. CONTENTS ARE STABLE BUT UNDER PRESSURE. DO NOT PUNCTURE OR
INCINERATE CONTAINERS, EVEN WHEN EMPTY.
CHEMICAL INCOMPATIBILITY: KEEP AWAY FROM ACIDS.
HAZARDOUS DECOMPOSITION PRODUCTS:
CALCIUM OXIDE MAY BE PRODUCED ON DECOMPOSITION.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
CONDITIONS TO AVOID: NONE KNOWN.
CORROSIVE TO METAL: NO.
OXIDIZER: NA
------SECTION 8 SPECIAL PROTECTION INFORMATION -----RESPIRATORY PROTECTION:
NIOSH/MSHA - APPROVED ORGANIC VAPOR RESPIRATOR WHEN VAPORS ARE GENERATED
ABOVE THE PERMISSIBLE LIMIT.
VENTILATION: LOCAL EXHAUST TO CONTROL TO RECOMMENDED P.E.L.
PROTECTIVE CLOTHING:
GLOVES, COVERALLS, APRONS, BOOTS, - AS NECESSARY TO PREVENT SKIN CONTACT.
EYE PROTECTION: CHEMICAL GOGGLES
OTHER PRECAUTIONS:
AVOID EXCESSIVE INHALATIONS. READ AND FOLLOW ALL LABEL DIRECTIONS AND
CAUTIONS. EYEWASH FOUNTAINS SHOULD BE EASILY ACCESSIBLE.
------SECTION 9 ENVIRONMENTAL DATA -----ENVIRONMENTAL TOXICITY DATA: NA
SPILL OR LEAK PROCEDURES:
LEAKING CONTAINERS SHOULD BE PLACED IN AN OPENED CONTAINER, OUTDOORS, AWAY
FROM SOURCES OF IGNITION, UNTIL ALL PRESSURE IS RELEASED.
HAZARDOUS SUBSTANCE SUPERFUND: NA
WASTE DISPOSAL METHOD:
BURY OR INCINERATE IN APPROVED DISPOSAL FACILITIES IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REGULATION.
Page 3

712828.txt
CONTAINER DISPOSAL:
EMPTY CONTAINERS & DRIED PRODUCT MAY BE DISPOSED OF AS NORMAL REFUSE.
------SECTION 10 SHIPPING DATA -----D.O.T. PROPER SHIPPING NAME: CONSUMER COMMODITY
HAZARDOUS SUBSTANCE 49 CFR CERCLA: NA
D.O.T. HAZARD CLASS: ORM-D
D.O.T. LABELS REQUIRED: NONE
D.O.T. PLACARDS REQUIRED: NONE
POISON CONSTITUENT: NONE
BILL OF LADING DESCRIPTION: CONSUMER COMMODITY ORM-D
CC NO: NA
UN/NA CODE: NONE
------SECTION 11 SUPPLIER INFORMATION -----THE INFORMATION CONTAINED HEREIN IS, TO THE BEST OF OUR KNOWLEDGE AND
BELIEF, ACCURATE AND RELIABLE AS OF THE DATE OF ISSUED. WE DO NOT HOWEVER,
WARRANT OR GUARANTEE THE ACCURACY OR RELIABILITY, NOR SHALL WE BE LIABLE
FOR ANY LOSS OR DAMAGE ARISING OUT OF THE USE THEREOF. THE INFORMATION IS
OFFERED FOR THE USER'S CONSIDERATION AND EXAMINATION, AND IT IS THE USER'S
RESPONSIBILITY TO SATISFY HIMSELF THAT IT IS SUITABLE AND COMPLETE FOR HIS
PARTICULAR USE.
PREPARED BY:
J. STATEN, TECHNICAL, SPECIALIST 6/21/94 / REFORMATTED: S. THOMAS 3/1/96

Page 4

PART I

What is the material and what do I need to know in an emergency?

1. PRODUCT IDENTIFICATION
TRADE NAME (AS LABELED):
PRODUCT CODES:
PRODUCT USE:
SUPPLIER/MANUFACTURER'S NAME:
ADDRESS:
CHEMTREC EMERGENCY NO.:
BUSINESS PHONE:
DATE OF PREPARATION:

HOMAX Waterbased ORANGEPEEL & SPLATTER Spray Texture

4091, 4092, 4192, 4091-06,4092-06, 4091-10-06
Patching Interior Texture
HOMAX PRODUCTS, INC.
200 Westerly Rd.
Bellingham, WA 98226
1-800-424-9300 (United States)
1-703-527-3887 (International Collect)
1-800-729-9029
Nov. 16, 2006

2. COMPOSITION and INFORMATION ON INGREDIENTS
CHEMICAL
NAME

CAS #

% w/w

EXPOSURE LIMITS IN AIR
ACGIH-TLV

OSHA-PEL

NIOSH-REL

TWA
mg/m3

STEL
mg/m3

TWA
mg/m3

STEL
mg/m3

TWA
mg/m3

STEL
mg/m3

IDLH/OTHER
mg/m3

Calcium
Carbonate

1317-65-3

30 - 60

10

NE

15 *
5 **

NE

10 *
5 **

NE

NE

Dimethyl Ether
(Propellant)

115-10-6

7 - 13

NE

NE

NE

NE

NE

NE

DFG MAK:
IDLH: 1900
Peak: II (8)

14807-96-6

1-5

NA

20

NA

2*

NE

1000

67-63-0

3-7

492

984

980

NE

980

1225

2,000
(10% LEL)

14808-60-7

0.1-1

10 mg/m3 **
NE
0.05 *
NE
50
% SiO2+2
The ingredients in the balance of this product do not contribute significant hazards
beyond those described in this document. All pertinent health, safety and
environmental information have been presented, per the requirements of the US
Federal OSHA Hazard Communication Standard (29 CFR 1910.1200) and Canadian
WHMIS.

Talc
Isopropyl alcohol
Silica Quartz

Water and ingredients present in
concentrations of less than 1% (or
less than 0.1% if carcinogens)

2 **

0.05 R

Balance

NE

NE = Not Established. See Section 16 for Definitions of Terms Used.
NOTE (1): ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format. This product has been classified in accordance
with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
NOTE (2):* Total dust; ** Respirable fraction; R = Measured as respirable fraction of the aerosol.
NOTE (3): The component Nicron 403, is free of crystalline silica and asbestos; therefore, carcinogenicity does not apply.

3. HAZARD IDENTIFICATION
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EMERGENCY OVERVIEW:
PHYISCAL DESCRIPTION: This product is a white colored aerosol with a slight ethereal odor.
HEALTH HAZARD: This product is harmful if it is inhaled or swallowed. This product may cause severe irritation to the eyes or skin.
If particulates of this product are inhaled, severe irritation of the respiratory system (i.e. lungs, nose, and throat), central nervous
system, and gastrointestinal tract could occur.
FIRE HAZARD: This product is a flammable liquid and vapor (aerosol), with its contents under pressure. HOMAX EASY TEXTURE
ORANGEPEEL & SPLATTER propellant has a flash point of - 42oF / -41oC.
REACTIVITY HAZARD: Minimal Hazard; the product is normally stable under ordinary conditions of use and storage.
ENVIRONMENTAL HAZARD: This product is does not normally present a significant hazard to aquatic or terrestrial life.
SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE:
The most significant route of occupational overexposure is contact with skin, eyes, and inhalation. The symptoms of overexposure to this
product are as follows:
INHALATION: If inhalation of product s mists or vapors occurs, severe respiratory system irritation or nervous system depression
may develop. Nervous system depression is characterized by headache, dizziness, nausea, or possible unconsciousness. CONTACT
WITH SKIN or EYES: Contact can cause severe eye or skin irritation. Symptoms of eye exposure may include redness, pain, burning
sensation, and tearing. Prolonged skin contact may result in redness, irritation, and dermatitis.
SKIN ABSORPTION: May cause irritation or burning sensation.
INGESTION: Ingestion is not anticipated to be a significant route of occupational exposure. If the product is swallowed, severe
irritation of the mouth, throat, and other tissues of the gastro-intestinal system may occur. Ingestion of large amounts may cause
irritation, pain, vomiting, and diarrhea.
INJECTION: Accidental injection of this product may cause mild irritation and swelling, in addition to the wound.

Hazardous Materials Identification System (HMIS)
Health

1*

Flammability

4

Physical Hazard

1

Protective Equipment

A

See Section 16 for Definition of Ratings
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms.
ACUTE: Depending on the duration of contact, overexposures can severely irritate the eyes, skin, lungs, respiratory tract and nervous
system. Symptoms of exposure generally alleviated when overexposure ends.
CHRONIC: Long-term skin contact may result in dermatitis.
TARGET ORGANS: Acute: Eyes, Skin, Lungs, CNS, and Respiratory tract. Chronic: Skin

PART II

What should I do if a hazardous situation occurs?

4. FIRST-AID MEASURES
Victims of chemical exposure must be taken for medical attention if any adverse effects occur. Take a copy of label and MSDS to
physician or health professional with victim.
SKIN EXPOSURE: If this product contaminates the skin, immediately begin decontamination with running water. Remove exposed or
contaminated clothing, taking care not to contaminate eyes. Victim must seek immediate medical attention if any adverse exposure
symptoms develop.
EYE EXPOSURE: If this product enters the eyes, open victim's eyes while under gently running water. Use sufficient force to open
eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. Victim must seek medical attention.
INHALATION: If this product is inhaled, blow nose and remove victim to fresh air. INGESTION: If this product is swallowed, CALL
PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION. DO NOT INDUCE VOMITING, unless
directed by medical personnel. Have victim rinse mouth with water, if conscious. Never induce vomiting or give

4. FIRST-AID MEASURES - Continued
a diluent (e.g., water) to someone who is unconscious, having convulsions, or unable to swallow. If contaminated individual is
convulsing, maintain an open airway and obtain immediate medical attention.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing conditions of pulmonary, dermatitis, and conjunctivitis
disorders.
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RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure.

5. FIRE-FIGHTING MEASURES
0

FLASH POINT: 30 F (-1.10C)
0

NFPA RATING

0

AUTOIGNITION TEMPERATURE: 662 F (350 C) (Dimethyl ether propellant)

FLAMMABILITY

FLAMMABLE LIMITS (in air by volume, %):
4

Lower: 3.4% (Dimethyl ether propellant)
Upper: 27% (Dimethyl ether propellant)
FIRE EXTINGUISHING MATERIALS: Use extinguishing material suitable to the
surrounding fire.
Water Fog: OK
Foam: OK
Halon: OK

HEALTH

1
2

Carbon Dioxide: OK
Dry Chemical: OK

0
1

REACTIVITY

OTHER

UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode due
to build up of pressure from extreme heat or fire.
Explosion Sensitivity to Mechanical Impact: Do not puncture.
Explosion Sensitivity to Static Discharge: Primarily vapors.
SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection. Structural firefighters must wear
Self-Contained Breathing Apparatus and full protective equipment. Move containers from
See Section 16 for
fire area if it can be done without risk to personnel. Exercise caution; contaminated floors
Definition of Ratings
and surfaces can be sticky. If possible, prevent runoff water from entering storm drains,
bodies of water, or other environmentally sensitive areas.

6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by trained personnel using pre-planned procedures.
Proper protective equipment should be used. In case of a spill, clear the affected area and protect people. Releases of this material may be
sticky. If the product is dried, and dusts may be generated during clean-up, dampen material prior to clean-up to avoid airborne
particulates.
RESPONSE TO INCIDENTAL RELEASES: Small scale releases, such as 1 container of this product, can generally be handled by
personnel who have received basic chemical safety training. Respond to incidental chemical releases by wearing gloves, goggles, and
appropriate body protection and by following the instructions for use presented above.
RESPONSE TO NON-INCIDENTAL RELEASES: Respond to non-incidental chemical releases of this product, such as the
simultaneous puncturing of several containers, by clearing the impacted area and contacting appropriate emergency personnel. Clean
up should only be done by qualified personnel. Responders should wear the level of protection appropriate to the type of chemical
released, the volume of the material spilled, and the location where the incident has occurred. Minimum Personal Protective
Equipment should be Level C: triple-gloves, chemical resistant apron, boots, and splash goggles and an Air-Purifying respirator with
high-efficiency particulate filter.
RESPONSE EQUIPMENT AND PROCEDURES: Wipe-away spilled paste with damp polypads or other suitable absorbent materials,
or scrape carefully with plastic tools. Decontaminate the area thoroughly. Place all spill residues in a suitable container and seal. Dispose
of in accordance with applicable U.S. Federal, State, or local procedures or appropriate standards of Canada (see Section 13, Disposal
Considerations).

PART III

How can I prevent hazardous situations from occurring?

7. HANDLING and STORAGE
WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash
thoroughly after using this product. Do not eat or drink while using this material. Avoid generating dusts and particulates of this product.
If sanding, use with adequate ventilation. Remove contaminated clothing immediately.
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Deleted: 

STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to use it safely. Open containers
carefully on a stable surface. Empty containers may contain residual material; therefore, empty containers should be handled with care.
Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store away
from incompatible materials (see Section 10, Stability and Reactivity). Keep container tightly closed when not in use. Inspect all
incoming containers before storage, to ensure containers are properly labeled and not damaged.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in Section
6 (Accidental Release Measures). Make certain that application equipment is locked and tagged-out safely if necessary. Collect all
rinsates and dispose of according to applicable U.S. Federal, State, or local procedures or appropriate Canadian standards.

8. EXPOSURE CONTROLS - PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained below the
limits provided in Section 2 (Composition and Information on Ingredients). Ensure adequate ventilation is available when sanding.
Ensure eyewash/safety shower stations are available near areas where this product is used.
RESPIRATORY PROTECTION: None needed under normal conditions of use. Use a dust respirator for large jobs if dusts cannot
otherwise be eliminated.
EYE PROTECTION: For consumer use, wearing eye protection (such as splash goggles) is advisable. However, for specific industrial
applications, enhanced eye protection may be necessary. Use approved safety goggles or safety glasses, as described in OSHA 29 CFR
1910.133. If necessary, refer to U.S. OSHA 29 CFR 1910.133, or appropriate Canadian standards.
HAND PROTECTION: For consumer use, wearing protective gloves is recommended. For specific industrial applications, wear
chemical impervious gloves (e.g., Neoprene, nitrile). If necessary, refer to U.S. OSHA 29 CFR 1910.138 or the appropriate standards of
Canada.
BODY PROTECTION: For consumer use, no specific body protection is normally needed. For specific industrial applications, body
protection is not routinely necessary, but may be warranted if excessive dusts may be generated. Use body protection appropriate for
task (e.g., Tyvek suit, rubber apron). If a hazard of injury to the feet exists due to falling objects, rolling objects, where objects may
pierce the soles of the feet or where employee s feet may be exposed to electrical hazards, use foot protection, as described in U.S. OSHA
29 CFR 1910.136.
HMIS PERSONAL PROTECTIVE EQUIPMENT RATING: Industrial Use situations: (A) Eye Protection.

9. PHYSICAL and CHEMICAL PROPERTIES
RELATIVE VAPOR DENSITY (air = 1): Heavier than air

EVAPORATION RATE (BuAc =1): Faster than n-butyl acetate

SPECIFIC GRAVITY: 0.9

MELTING POINT: 32oF (0oC)

SOLUBILITY IN WATER: Soluble in water

BOILING POINT: -13 oF (10.5 oC)

VAPOR PRESSURE, mm Hg @ 24°C:

pH: NA

ODOR THRESHOLD: NA
COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): NA
V.O.C.: < 60%

MIR: < 1.20

APPEARANCE, ODOR AND COLOR: This product is a white colored aerosol with a slight ethereal odor
HOW TO DETECT THIS SUBSTANCE (warning properties): The appearance and odor of this product may act as warning properties
in the event of an accidental release.

10. STABILITY and REACTIVITY
STABILITY: Stable under normal circumstances of use and handling.
DECOMPOSITION PRODUCTS: Thermal decomposition of this product may generate dusts, irritating fumes, and toxic gases (e.g.,
carbon monoxide, carbon dioxide).
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: This product is not compatible strong oxidizing agents.
HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06

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HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Avoid contact with incompatible chemicals and high temperatures.

PART IV

Is there any other useful information about this material?

11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: The following toxicology information is available for components greater than 1% in concentration.
The following data are available for Dimethyl ether:
Inhalation-Rat LC50: 308 g/m3
Inhalation-Mouse LC50: 386,000 ppm/30M
Inhalation-Rat TCLo: 2 pph/6H/30W-I
The following data are available for Isopropyl alcohol:
Skin-Rabbit, adult 500 mg Mild irritation effects
Eye effects-Rabbit, adult 16 mg
Eye effects-Rabbit, adult 10 mg Moderate irritation effects
Cytogenetic Analysis System-Saccharomyces cerevisiae 200 mmol/tube
Cytogenetic Analysis System-Rat-Inhalation 1030 mg/m3/16W-I
Oral-Rat TDLo:6480 mg/kg (male 26W pre):Reproductive effects
Inhalation-Rat TCLo:10,000 ppm/7H (female 1-19D post):Teratogenic effects
Oral-Man TDLo:14,432 mg/kg: Central nervous system effects, Cardiovascular effects, Pulmonary system effects
Oral-Human TDLo:223 mg/kg: Central nervous system effects, Cardiovascular effects
Oral-Man LDLo:5272 mg/kg
AJCPAI 38,144,62
Oral-Human LDLo:3570 mg/kg: Central nervous system effects, Pulmonary system effects, Gastrointestinal tract effects
Unreported-Man LDLo:2770 mg/kg
Oral-Rat LD50:5045 mg/kg
Inhalation-Rat LCLo:16,000 ppm/4H
Intraperitoneal-Rat LD50:2735 mg/kg
Intravenous-Rat LD50:1099 mg/kg
Oral-Mouse LD50:3600 mg/kg
Inhalation-Mouse LCLo:12,800 ppm/3H
Intraperitoneal-Mouse LD50:4477 mg/kg
Subcutaneous-Mouse LDLo:6000 mg/kg
Intravenous-Mouse LD50:1509 mg/kg
Oral-Dog, adult LD50:4797 mg/kg
Intravenous-Dog, adult LDLo:5120 mg/kg
Intravenous-Cat, adult LDLo:1963 mg/kg
Oral-Rabbit, adult LD50:6410 mg/kg
Skin-Rabbit, adult LD50:12,800 mg/kg
The following data are available for Talc:
Skin-Human 300 mg/3D-I Mild irritation effects
Inhalation-Rat TCLo:11 mg/m3/1Y-I:Equivocal tumorigenic agent
The following data are available for Calcium Carbonate, Vinyl Acrylic Copolymer, and Silica Quartz:
None available
SUSPECTED CANCER AGENT: The following table summarizes the carcinogenicity listing for the components of this product.
NO indicates that the substance is not considered to be, or suspected to be, a carcinogen by the listed agency.
IARC

NTP

ACGIH

NIOSH

OSHA

CA PROP 65

Calcium Carbonate

CHEMICAL

NO

NO

NO

NO

NO

NO

Dimethyl Ether

NO

NO

NO

NO

NO

NO

3

NO

A4

NO

NO

NO
NO

Talc
Vinyl Acrylic Copolymer

NO

NO

NO

NO

NO

Isopropyl alcohol

3

NO

NO

NO

NO

NO

Silica Quartz

1

Known

Ca

NO

A2

YES

Note: See section 16 for definition of ratings

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11. TOXICOLOGICAL INFORMATION - Continued
IRRITANCY OF PRODUCT: This product can be severely irritating to contaminated tissue.
SENSITIZATION TO THE PRODUCT: The components of this product are not reported to be sensitizers.
TOXICOLOGICAL SYNERGISTIC PRODUCTS: None known.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product and its components
on the human reproductive system.
Mutagenicity: This product is not expected to produce mutagenic effects in humans when used as instructed.
Embryotoxicity: This product is not expected to produce embryotoxic effects in humans when used as instructed.
Teratogenicity: This product is not reported to cause teratogenic effects in humans when used as instructed.
Reproductive Toxicity: This product is not reported to cause reproductive effects in humans when used as instructed.
A mutagen is a chemical that causes permanent changes to genetic material (DNA) such that the changes will propagate through
generational lines. An embryotoxin is a chemical that causes damage to a developing embryo (i.e. within the first eight weeks of
pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical that causes damage to a
developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is any substance that interferes in
any way with the reproductive process.
BIOLOGICAL EXPOSURES INDICES (BEIs): There is no BEI currently established for this substance.

12. ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ENVIRONMENTAL STABILITY: The following environmental data is available for components of this product: The mineral
components of this product are stable in the environment.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: This product is not anticipated to cause significant effects on terrestrial plants or
animals if released in small, consumer-sized volumes. This product may be harmful to animal life if large volumes of it are released into
the environment. Refer to Section 11 (Toxicological Information) for specific animal data.
EFFECT OF CHEMICAL ON AQUATIC LIFE: This product is not anticipated to cause significant effects on aquatic plants or animals
if released in small, consumer-sized volumes. This product may be harmful to contaminated aquatic life (especially if large volumes of it
are released into an aquatic environment). The following aquatic toxicity data is available for components of this product: NONE

13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Consumer Waste: Dispose of according to pertinent state and local household waste and
requirements. Industrial Use: Waste disposal must be in accordance with appropriate U.S. Federal, State, and local regulations or with
regulations of Canada.
EPA WASTE NUMBER: Not applicable to wastes consisting only of this product; however, the specific RCRA codes depend on the
exact nature of the discarded material.

14. TRANSPORTATION INFORMATION
THIS PRODUCT IS HAZARDOUS PER 49 CFR 172.101, THE U.S. DEPARTMENT OF TRANSPORTATION.
PROPER SHIPPING NAME:
Aerosols
HAZARD CLASS NUMBER and DESCRIPTION: 2.1(Flammable Gas)
UN IDENTIFICATION NUMBER:
UN1950
DOT LABEL(S) REQUIRED:
Flammable Gas
PACKAGING GROUP:
N/A
NORTH AMERICAN RESPONSE GUIDEBOOK NUMBER (2000): 126
MARINE POLLUTANT: No component is designated as a DOT Marine Pollutant.
Consumer commodities (per 173.306 (h)): A limited quantity that conforms to the provisions of paragraph (a) (1), (a) (3), or (b) of
this section and is a "consumer commodity" (per 49 CFR 171.8) can be renamed Consumer commodity and reclassified as an ORMD Material. Each package may not exceed 30 kg (66 pounds)gross weight. Reference 173.306 (a) (3): Limited quantities of
compressed gases may be shipped when in a metal container for the sole purpose of expelling a nonpoisonous liquid, paste, or powder.

14. TRANSPORTATION INFORMATION - Continued
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS:
description applies to this product under the regulations of Transport Canada.
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The above-listed DOT basic

15. REGULATORY INFORMATION
ADDITIONAL U.S. REGULATIONS:
EPA REPORTING REQUIREMENTS: The following reporting requirements are applicable to components of this product:
CHEMICAL

SECTION 302

SECTION 304

SECTION 313

(40 CFR 355, Appendix
A)

(40 CFR Table 302.4)

(40 CFR 372.65)

Calcium Carbonate

NO

NO

NO

Dimethyl Ether

NO

NO

NO

Talc

NO
NO

NO
NO

NO
NO

NO
NO

NO
NO

NO
NO

Isopropyl alcohol
Vinyl Acrylic Copolymer
Silica Quartz

U.S. SARA SECTION 311/312 FOR PRODUCT: Acute health effects; chronic health effects.
U.S. TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
OTHER U.S. FEDERAL REGULATIONS: Not applicable.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): WARNING: This product
contains a chemical known to the State of California to cause cancer.
ANSI LABELING (Z129.1):
DANGER! HARMFUL OR FATAL IF SWALLOWED. EXTREMELY FLAMMABLE LIQUID AND VAPOR.
VAPOR HARMFUL. CONTENTS UNDER PRESSURE. MAY EXPLODE IF HEATED. AFFECTS CENTRAL NERVOUS
SYSTEM. CAUSES SEVERE EYE IRRITATION. CAUSES IRRITATION TO SKIN AND RESPIRATORY TRACT. MAY BE
HARMFUL IF ABSORBED THROUGH SKIN. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND
INHALING THE CONTENTS MAY BE HARMFUL OR FATAL.
ANSI LABEL PRECAUTIONS:
Keep away from heat, sparks and flame. Do not expose to heat or store at temperatures above 120oF. Close container after use. Avoid
breathing dust, vapors or mist. Do not take internally. Avoid contact with skin and clothing. Wash thoroughly after handling. Avoid
contact with eyes.
ENVIRONMENTAL HAZARDS: Do not discharge effluent containing this product into streams, ponds, estuaries, oceans or other
waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the
permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems
without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office
of the EPA.

15. REGULATORY INFORMATION - Continued
ADDITIONAL CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are listed on the DSL Inventory.
CANADIAN WHMIS SYMBOLS: A - Compressed gas
B1 - Flammable and combustible material - Flammable gas
B2 - Flammable and combustible material - Flammable liquid
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D2A - Poisonous and infectious material - Other effects - Very toxic
D2B - Poisonous and infectious material - Other effects - Toxic

This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the
MSDS contains all the information required by the CPR.

16. OTHER INFORMATION
PREPARED BY:

DATE OF PRINTING

John R. Kordosh
Homax Products, Inc.
4505 E. Industrial St., Ste. 1B
Simi Valley, CA 93063
(805) 581-3555
December 5, 2006

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DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these, which are commonly used, include the following:
CAS #: This is the Chemical Abstract Service Number that uniquely identifies each compound.
ACGIH - American Conference of Governmental Industrial Hygienists, a
professional association which establishes exposure limits.
TLV - Threshold Limit Value - an airborne concentration of a substance that
represents conditions under which it is generally believed that nearly all workers
may be repeatedly exposed without adverse effect. The duration must be
considered, including the 8-hour Time Weighted Average (TWA), the 15minute Short Term Exposure Limit, and the instantaneous Ceiling Level (C).
Skin absorption effects must also be considered.
OSHA - U.S. Occupational Safety and Health Administration.
PEL - Permissible Exposure Limit - This exposure value means exactly the
same as a TLV, except that it is enforceable by OSHA. The OSHA Permissible
Exposure Limits are based in the 1989 PELs and the June, 1993 Air
Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 40191). Both
the current PELs and the vacated PELs are indicated. The phrase, Vacated
1989 PEL, is placed next to the PEL that was vacated by Court Order.
IDLH - Immediately Dangerous to Life and Health - This level represents a
concentration from which one can escape within 30-minutes without suffering
escape-preventing or permanent injury. The DFG - MAK is the Republic of
Germany s Maximum Exposure Level, similar to the U.S. PEL. NIOSH is the
National Institute of Occupational Safety and Health, which is the research arm
of the U.S. Occupational Safety and Health Administration (OSHA). NIOSH
issues exposure guidelines called Recommended Exposure Levels (RELs).
When no exposure guidelines are established, an entry of NE is made for
reference.
HAZARD RATINGS:
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM:
Health
Hazard: 0 (minimal acute or chronic exposure hazard); 1 (slight acute or chronic
exposure hazard); 2 (moderate acute or significant chronic exposure hazard); 3
(severe acute exposure hazard; onetime overexposure can cause permanent
injury and may be fatal); 4 (extreme acute exposure hazard; onetime
overexposure can be fatal). Flammability Hazard: 0 (minimal hazard); 1
(materials that require substantial pre-heating before burning); 2 (combustible
liquid or solids; liquids with a flash point of 38-93 C [100-200 F]); 3 (Class IB
and IC flammable liquids with flash points below 38 C [100 F]); 4 (Class IA
flammable liquids with flash points below 23 C [73 F] and boiling points below
38 C [100 F]. Reactivity Hazard: 0 (normally stable); 1 (material that can
become unstable at elevated temperatures or which can react slightly with
water); 2 (materials that are unstable but do not detonate or which can react
violently with water); 3 (materials that can detonate when initiated or which can
react explosively with water); 4 (materials that can detonate at normal
temperatures or pressures).
NATIONAL FIRE PROTECTION ASSOCIATION: Health Hazard: 0
(material that on exposure under fire conditions would offer no hazard beyond
that of ordinary combustible materials); 1 (materials that on exposure under fire
conditions could cause irritation or minor residual injury); 2 (materials that on
intense or continued exposure under fire conditions could cause temporary
incapacitation or possible residual injury); 3 (materials that can on short
exposure could cause serious temporary or residual injury); 4 (materials that
under very short exposure could cause death or major residual injury).
Flammability Hazard and Reactivity Hazard: Refer to definitions for
Hazardous Materials Identification System .

FLAMMABILITY LIMITS IN AIR:
Much of the information related to fire and explosion is derived from the
National Fire Protection Association (NFPA). Flash Point - Minimum
temperature at which a liquid gives off sufficient vapors to form an ignitable
mixture with air. Autoignition Temperature: The minimum temperature
required to initiate combustion in air with no other source of ignition. LEL - the
lowest percent of vapor in air, by volume, that will explode or ignite in the
presence of an ignition source. UEL - the highest percent of vapor in air, by
volume, that will explode or ignite in the presence of an ignition source.
TOXICOLOGICAL INFORMATION:
Possible health hazards as derived from human data, animal studies, or from the
results of studies with similar compounds are presented. Definitions of some
terms used in this section are: LD50 - Lethal Dose (solids & liquids) which kills
50% of the exposed animals; LC50 - Lethal Concentration (gases) which kills
50% of the exposed animals; ppm concentration expressed in parts of material
per million parts of air or water; mg/m3 concentration expressed in weight of
substance per volume of air; mg/kg quantity of material, by weight,
administered to a test subject, based on their body weight in kg. Other measures
of toxicity include TDLo, the lowest dose to cause a symptom and TCLo the
lowest concentration to cause a symptom; TDo, LDLo, LDo, TC, TCo, LCLo,
and LCo, the lowest dose (or concentration) to cause lethal or toxic effects. BEI
- Biological Exposure Indices, represent the levels of determinants which are
most likely to be observed in specimens collected from a healthy worker who
has been exposed to chemicals to the same extent as a worker with inhalation
exposure to the TLV. Ecological Information: EC is the effect concentration in
water.
Data from several sources are used to evaluate the cancer-causing potential of
the material. The sources and ratings are: IARC - the International Agency for
Research on Cancer; 1 = Carcinogenic to humans, 2A, 2B = Probably
carcinogenic to humans, 3 = Unclassifiable as to carcinogenicity in humans, and
4 = Probably not carcinogenic to humans. NTP - the National Toxicology
Program; K =Known to be a human carcinogen, and R = Reasonably anticipated
to be a human carcinogen. RTECS - the Registry of Toxic Effects of Chemical
Substances. OSHA - Occupational Safety and Health Administration and
CAL/OSHA - California s subunit of the Occupational Safety and Health
Administration; Ca = Carcinogen defined with no further categorization.
ACGIH American Conference of Governmental Industrial Hygienists; A1 =
Confirmed human carcinogen, A2 = Suspected human carcinogen, A3 =
Confirmed animal carcinogen with unknown relevance to humans, A4 = Not
classifiable as a human carcinogen, and A5 = Not suspected as a human
carcinogen. NIOSH
U.S. National Institute for Occupational Safety and
Health; Ca = Potential occupational carcinogen, with no further categorization.
EPA U.S. Environmental Protection; A = Human carcinogen, B = Probable
human carcinogen, C = Possible human carcinogen, D = Not classifiable as to
human carcinogenicity, E = Evidence of Non-carcinogenicity for humans, K =
Known human carcinogen, L = Likely to produce cancer in humans, CBD =
Cannot be determined, NL = Not likely to be carcinogenic in humans, and I =
Data are inadequate for an assessment of human carcinogenic potential.
REGULATORY INFORMATION:
This section explains the impact of various laws and regulations on the material.
EPA is the U.S. Environmental Protection Agency. WHMIS is the Canadian
Workplace Hazardous Materials Information System. DOT and TC are the U.S.
Department of Transportation and the Transport Canada, respectively.
Superfund Amendments and Reauthorization Act (SARA); the Canadian
Domestic/Non-Domestic Substances List (DSL/NDSL); the U.S. Toxic
Substance Control Act (TSCA); Marine Pollutant status according to the DOT;
the Comprehensive Environmental Response, Compensation, and Liability Act
(CERCLA or Superfund); and various state regulations. This section also
includes information on the precautionary warnings that appear on a material s
industrial package label.

HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06

page 9 of 9

This document was created with Win2PDF available at http://www.daneprairie.com.
The unregistered version of Win2PDF is for evaluation or non-commercial use only.

PART I

What is the material and what do I need to know in an emergency?

TRADE NAME (AS LABELED):
PRODUCT CODES:
PRODUCT USE:
SUPPLIER/MANUFACTURER'S NAME:
ADDRESS:
BUSINESS PHONE:
CHEMTREC EMERGENCY NO.:
BUSINESS PHONE:
DATE OF PREPARATION:

1. PRODUCT IDENTIFICATION
HOMAX EASY TOUCH COARSE ACOUSTIC TEXTURE
4070
Texture Patch
HOMAX PRODUCTS, INC.
468 W. Horton Road
Bellingham, WA 98226
1 800 729 9029
1-800-424-9300 (United States)
1-703-527-3887 (International Collect)
1-800-729-9029
April 20, 2004

This product is sold to consumers for household use in containers of relatively small volume (i.e. 5 gallon or less in size). This MSDS
has been developed to address safety concerns affecting those individuals working in warehouses and other places where large
numbers of these containers are stored, as well as those affecting potential users of this product in industrial /occupational settings.
All pertinent health, safety and environmental information have been presented in this document, per the requirements of the US Federal
OSHA Hazard Communication Standard (29 CFR 1910.1200) and Canadian WHMIS.

2. COMPOSITION and INFORMATION ON INGREDIENTS
CHEMICAL
NAME

CAS #

% w/w

EXPOSURE LIMITS IN AIR
ACGIH-TLV

OSHA-PEL

NIOSH-REL

TWA
mg/m3

STEL
mg/m3

TWA
mg/m3

STEL
mg/m3

TWA
mg/m3

STEL
mg/m3

IDLH
mg/m3

Calcium
carbonate

1317-65-3

15 40

10

NE

15 *
5 **

NE

10 *
5 **

NE

NE

Aluminum silicate

1322-58-7

7 13

2 **

NE

15 *
5 **

NE

NE

3000

Silica, crystalline

14808-60-7

1 5

0.05 **

NE

NE

50

Starch

9005-84-9

1 5

10

NE

10 mg/m3
% SiO2+2
15 *
NE
5 **

10 *
5 **
0.05 **
10 *
5 **

NE

NE

Attapulgite

12174-11-7

1-5

NE

NE

NE

NE

NE

Water and ingredients present in
concentrations of less than 1% (or less than
0.1% if carcinogens)

Balance

NE

NE

The ingredients in the balance of this product do not contribute significant hazards beyond those described
in this document. All pertinent health, safety and environmental information has been presented, per the
requirements of the US Federal OSHA Hazard Communication Standard (29 CFR 1910.1200) and
Canadian WHMIS.

NE = Not Established; * Total dust; ** Respirable fraction. See Section 16 for Definitions of Terms Used.
NOTE (1): ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format. This product has been classified in accordance
with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.

HOMAX EASY TOUCH COARSE ACOUSTIC TEXTURE Product ID#:4070, Revision Date: April 20, 2004
page 1 of 8

3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW:
PHYISCAL DESCRIPTION: This product is an odorless white aerosol texture.
HEALTH HAZARD: This product can cause irritation to the eyes or skin. This product is harmful if swallowed or inhaled. If vapors,
mists or particulates of this product are inhaled, irritation of the nose or throat could occur.
FIRE HAZARD: This product is non-combustible.
REACTIVITY HAZARD: This product is stable under ordinary conditions of use and storage.
ENVIRONMENTAL HAZARD: This product does not normally present a significant hazard to aquatic or terrestrial life in consumer
quantities.
SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE:
The most significant route of occupational overexposure is contact with skin and eyes. The symptoms of overexposure to this product are
as follows:
INHALATION: Vapors, mists, sprays, or dusts of this product can cause irritation to the respiratory tract. Dusts from this product can
contain small amounts of crystalline Silica, a recognized carcinogen. Exposure to high concentrations of crystalline Silica can also cause
silicosis.
CONTACT WITH SKIN or EYES: Contact can cause eye or skin irritation. Prolonged skin contact can result in dermatitis. Prolonged
eye exposure may include redness, pain, and tearing.
SKIN ABSORPTION: No component of this product is reported to be absorbed through intact skin.
INGESTION: If the product is swallowed, irritation of the mouth, throat, and other tissues of the gastro-intestinal system can occur.
Ingestion of large amounts can cause irritation, pain, vomiting, and diarrhea.
INJECTION: Accidental injection of this product can cause burning, reddening, and swelling in addition to the wound. Symptoms of
such exposure can include those described under Inhalation , Contact with Skin or Eyes, and Ingestion .

Hazardous Materials Identification System (HMIS)
Health

2*

Flammability

0

Physical Hazard

1

Protective Equipment

B

See Section 16 for Definition of Ratings
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms.
ACUTE: Depending on the duration of contact, overexposures can irritate the eyes, skin, mucous membranes, and other exposed tissue.
CHRONIC: Long-term skin or eye contact can result in dermatitis or eye irritation.
TARGET ORGANS: Acute: Eyes, respiratory system and skin. Chronic: Eyes and skin.

PART II

What should I do if a hazardous situation occurs?

4. FIRST-AID MEASURES
Victims of chemical exposure must be taken for medical attention if any adverse effects occur. Take a copy of label and MSDS to
physician or health professional with victim.
SKIN EXPOSURE: If this product contaminates the skin, immediately begin decontamination with running water. Remove exposed or
contaminated clothing, taking care not to contaminate eyes. Victim must seek immediate medical attention if any adverse exposure
symptoms develop.
EYE EXPOSURE: If this product enters the eyes, open victim's eyes while under gently running water. Use sufficient force to open
eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. Victim must seek medical attention.

4. FIRST-AID MEASURES - Continued
INHALATION: If vapors, mists, or sprays of this product are inhaled, remove victim to fresh air. Victim must seek immediate medical
attention if any adverse exposure symptoms develop. If necessary, use artificial respiration to support vital functions.
HOMAX EASY TOUCH COARSE ACOUSTIC TEXTURE Product ID#:4070, Revision Date: April 20, 2004
page 2 of 8

INGESTION: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT
INFORMATION. DO NOT INDUCE VOMITING, unless directed by medical personnel. Have victim rinse mouth with water, if
conscious. Never induce vomiting or give a diluent (e.g., water) to someone who is unconscious, having convulsions, or unable to
swallow. If contaminated individual is convulsing, maintain an open airway and obtain immediate medical attention.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Persons with pre-existing skin disorders, eye problems, impaired liver,
kidney, respiratory or lymphoid system function can be more susceptible to health effects associated with overexposures to this product.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure.

5. FIRE-FIGHTING MEASURES
FLASH POINT: Not applicable.
AUTOIGNITION TEMPERATURE: Not applicable.
FLAMMABLE LIMITS (in air by volume, %):

NFPA RATING

Lower: Not applicable.
Upper: Not applicable.

FLAMMABILITY

FIRE EXTINGUISHING MATERIALS:
surrounding fire.
Water Spray: OK.
Foam: OK
Halon: OK

Use extinguishing material suitable to the

Carbon Dioxide: OK
Dry Chemical: OK
Other: Any ABC Class.

UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode due to
build up of pressure from extreme heat or fire. When involved in a fire, this material may
decompose and, generating dusts, irritating fumes and toxic gases (e.g., Carbon monoxide
and Carbon dioxide).

0
HEALT
H

2

0
REACTIVIT
Y

OTHER
See Section 16 for
definitions of ratings

Explosion Sensitivity to Mechanical Impact: Not sensitive under normal conditions.
Explosion Sensitivity to Static Discharge: Not sensitive under normal conditions.
SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection. Structural firefighters must wear
Self-Contained Breathing Apparatus and full protective equipment. Move containers from fire area if it can be done without risk to
personnel. If possible, prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive areas.

6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK RESPONSE: Trained personnel using pre-planned procedures should respond to uncontrolled releases. Proper
protective equipment should be used. In case of a spill, clear the affected area and protect people.
RESPONSE TO INCIDENTAL RELEASES: Personnel who have received basic chemical safety training can generally handle smallscale releases, such as 1 container of this product. Respond to incidental chemical releases by wearing gloves, goggles, and
appropriate body protection.
RESPONSE TO NON-INCIDENTAL RELEASES: Respond to non-incidental chemical releases of this product, such as the
simultaneous puncturing of several containers, by clearing the impacted area and contacting appropriate emergency personnel. Clean
up should only be done by qualified personnel. Responders should wear the level of protection appropriate to the type of chemical
released, the volume of the material spilled, and the location where the incident has occurred. Minimum Personal Protective
Equipment should be Level B: triple-gloves, chemical resistant apron, boots, and splash goggles and Self-Contained Breathing
Apparatus. Level B should also be used when oxygen levels are below 19.5% or are unknown.
RESPONSE EQUIPMENT AND PROCEDURES: Absorb spilled liquid with polypads or other suitable absorbent materials.
Decontaminate the area thoroughly. Prevent spill rinsate from contamination of storm drains, sewers, soil or groundwater. Place all
spill residues in a suitable container and seal. Dispose of in accordance with applicable U.S. Federal, State, or local procedures or
appropriate standards of Canada (see Section 13, Disposal Considerations).

HOMAX EASY TOUCH COARSE ACOUSTIC TEXTURE Product ID#:4070, Revision Date: April 20, 2004
page 3 of 8

PART III

How can I prevent hazardous situations from occurring?

7. HANDLING and STORAGE
WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash
thoroughly after using this product. Do not eat or drink while using this material. Avoid generating dusts, mists or sprays of this product.
Remove contaminated clothing immediately.
STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to use it safely. Open containers
carefully on a stable surface. Empty containers can contain residual material; therefore, empty containers should be handled with care.
Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store away
from incompatible materials (see Section 10, Stability and Reactivity). Keep container tightly closed when not in use. Inspect all
incoming containers before storage, to ensure containers are properly labeled and not damaged.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in Section
6 (Accidental Release Measures). Make certain that application equipment is locked and tagged-out safely if necessary. Collect all
rinsates and dispose of according to applicable U.S. Federal, State, or local procedures or appropriate Canadian standards.

8. EXPOSURE CONTROLS - PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained below the
limits provided in Section 2 (Composition and Information on Ingredients).
RESPIRATORY PROTECTION: None needed under normal conditions of use. Use NIOSH approved respirators if ventilation is
inadequate to control dusts, mists, fumes or vapors. Maintain airborne contaminate concentrations below guidelines listed in Section 2
(Composition and Information on Ingredients). Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres use of
a full-face-piece pressure/demand SCBA or a full face-piece, supplied air respirator with auxiliary self-contained air supply is required
under OSHA s Respiratory Protection Standard (29 CFR 1910.134).
EYE PROTECTION: For consumer use, wearing eye protection (such as splash goggles) is advisable. However, for specific industrial
applications, enhanced eye protection can be necessary. Use approved safety goggles or safety glasses, as described in OSHA 29 CFR
1910.133. If necessary, refer to U.S. OSHA 29 CFR 1910.133, or appropriate Canadian standards.
HAND PROTECTION: For consumer use, wearing protective gloves is recommended. For specific industrial applications, wear
chemical impervious gloves (e.g., Neoprene or Nitrile). If necessary, refer to U.S. OSHA 29 CFR 1910.138 or the appropriate standards
of Canada.
BODY PROTECTION: For consumer use, no specific body protection is normally needed. For specific industrial applications, body
protection is not normally needed. Use body protection appropriate for task (e.g., Tyvek suit, rubber apron). If a hazard of injury to the
feet exists due to falling objects, rolling objects, where objects can pierce the soles of the feet or where employee s feet can be exposed to
electrical hazards, use foot protection, as described in U.S. OSHA 29 CFR 1910.136.
HMIS PERSONAL PROTECTIVE EQUIPMENT RATING: Industrial Use situations: B; Safety glasses and gloves.

9. PHYSICAL and CHEMICAL PROPERTIES
RELATIVE VAPOR DENSITY (air = 1): Heavier than air.

EVAPORATION RATE (BuAc =1): Not applicable.

SPECIFIC GRAVITY: Not applicable.

MELTING/FREEZING POINT: Not applicable.

SOLUBILITY IN WATER: Appreciable.

BOILING POINT: Not applicable.

VAPOR PRESSURE, mm Hg @ 24°C: Not applicable. pH: Not applicable.
ODOR THRESHOLD: Not applicable.
COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not applicable.
Weight % V.O.C.: 0.2%
APPEARANCE, ODOR AND COLOR: This product is an odorless white aerosol texture.
HOW TO DETECT THIS SUBSTANCE (warning properties): The appearance of this product may act as warning properties in the
event of an accidental release.

HOMAX EASY TOUCH COARSE ACOUSTIC TEXTURE Product ID#:4070, Revision Date: April 20, 2004
page 4 of 8

10. STABILITY and REACTIVITY
STABILITY: Stable under normal circumstances of use and handling.
DECOMPOSITION PRODUCTS: Thermal decomposition of this product may generate dusts, irritating fumes, and toxic gases (e.g.,
Carbon monoxide and Carbon dioxide).
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: This product is not compatible with acids, strong oxidizing agents
and ammonia.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Avoid contact with incompatible chemicals, high temperature/humidity, ignition sources, and vapor buildup.

PART IV

Is there any other useful information about this material?

11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: There are currently no toxicity data available for this product; the following toxicology information is available for
components greater than 1% in concentration.
The following data are available for Attapulgite:
Inhalation-Rat TCLo:10 mg/m3/6H/13W-I:Equivocal tumorigenic agent
Intraperitoneal-Rat TDLo:338 mg/kg/2W-I:Neoplastic effects
Implant-Rat TDLo:200 mg/kg:Equivocal tumorigenic agent
The following data are available for Limestone:
Oral - Rat: LD50: 6450 mg/kg
The following data are available for Starch:
Skin-Human 300 mg/3D-I Mild irritation effects
Intraperitoneal-Mouse LD50:6600 mg/kg
SUSPECTED CANCER AGENT: The following table summarizes the carcinogenicity listing for the components of this product.
NO indicates that the substance is not considered to be, or suspected to be, a carcinogen by the listed agency.
CHEMICAL

IARC

NTP

NIOSH

OSHA

ACGIH

PROP 65

Starch

NO

NO

NO

NO

NO

NO

Calcium carbonate

NO

NO

NO

NO

NO

NO

Aluminum silicate

3

NO

NO

NO

A4

NO

Silica, crystalline

1

K

Ca

NO

A2

YES

2B (>5 m)

NO

NO

NO

NO

YES (>5 m)

Attapulgite

3 (< 5 m)
IRRITANCY OF PRODUCT: This product can be irritating to contaminated tissue. Prolonged exposure can lead to tissue
damage.SENSITIZATION TO THE PRODUCT: Starch dust, a component of this product, may be an allergen.
TOXICOLOGICAL SYNERGISTIC PRODUCTS: None.

HOMAX EASY TOUCH COARSE ACOUSTIC TEXTURE Product ID#:4070, Revision Date: April 20, 2004
page 5 of 8

11. TOXICOLOGICAL INFORMATION Continued
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product and its components
on the human reproductive system.
Mutagenicity: When used as directed, this product is not expected to produce mutagenic effects in humans.
Embryotoxicity: When used as directed, this product is not expected to produce embryotoxic effects in humans.
Teratogenicity: When used as directed, this product is not expected to produce teratogenic effects in humans.
Reproductive Toxicity: When used as directed, this product is not expected to produce reproductive toxicity in humans.
A mutagen is a chemical that causes permanent changes to genetic material (DNA) such that the changes will propagate through
generational lines. An embryotoxin is a chemical that causes damage to a developing embryo (i.e. within the first eight weeks of
pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical that causes damage to a
developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is any substance that interferes in
any way with the reproductive process.
BIOLOGICAL EXPOSURES INDICES (BEIs): There are no BEI s established for any component of this product at this time.

12. ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ENVIRONMENTAL STABILITY: There is no environmental data for any component of this product at this time.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: This product can be harmful to terrestrial plant and animal life if large volumes
of it are released into the environment. Refer to Section 11, Toxicological Information , for specific animal data.
EFFECT OF CHEMICAL ON AQUATIC LIFE: This product can be harmful to animal life if large volumes of it are released into an
aquatic environment. There is no aquatic toxicity for any component of this product at this time.

13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Consumer Waste: Dispose of according to pertinent state and local household waste and
requirements. Industrial Use: Waste disposal must be in accordance with appropriate U.S. Federal, State, and local regulations or with
regulations of Canada.
EPA WASTE NUMBER: Not applicable to wastes consisting only of this product; however, the specific RCRA codes depend on the
exact nature of the discarded material.

14. TRANSPORTATION INFORMATION
THIS PRODUCT IS HAZARDOUS PER 49 CFR 172.101, THE U.S. DEPARTMENT OF TRANSPORTATION.
PROPER SHIPPING NAME:
Aerosols
HAZARD CLASS NUMBER and DESCRIPTION: 2.2 (Non-Flammable)
UN IDENTIFICATION NUMBER:
UN 1950
DOT LABEL(S) REQUIRED:
Non-Flammable Gas
PACKAGING GROUP:
Not applicable.
NORTH AMERICAN RESPONSE GUIDEBOOK NUMBER (2000): 126
MARINE POLLUTANT: No component is designated as a DOT Marine Pollutant.
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS:
description applies to this product under the regulations of Transport Canada.

The above-listed DOT basic

HOMAX EASY TOUCH COARSE ACOUSTIC TEXTURE Product ID#:4070, Revision Date: April 20, 2004
page 6 of 8

15. REGULATORY INFORMATION
ADDITIONAL U.S. REGULATIONS:
EPA REPORTING REQUIREMENTS: The following reporting requirements are applicable to components of this product:
CHEMICAL

SECTION 302

SECTION 304

SECTION 313

(40 CFR 355, Appendix A)

(40 CFR Table 302.4)

(40 CFR 372.65)

Starch

NO

NO

NO

Calcium carbonate

NO

NO

NO

Aluminum silicate

NO

NO

NO

Silica, crystalline

NO

NO

NO

Attapulgite

NO

NO

NO

U.S. SARA SECTION 311/312 FOR PRODUCT: Acute health effects; chronic health effects.
U.S. TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
OTHER U.S. FEDERAL REGULATIONS: Not applicable.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65):
WARNING: This product contains a chemical known to the State of California to cause cancer.
ANSI LABELING (Z129.1):
CAUTION! DUST AND VAPOR HARMFUL IF INHALED. MAY CAUSE SKIN, EYE AND LUNG IRRITATION. WARNING CONTENTS UNDER PRESSURE.
ANSI LABEL PRECAUTIONS:
Use with adequate ventilation, open windows and doors if using inside. Avoid breathing dust or vapors. Avoid contact with skin, eyes
and clothing. Use safety glasses and gloves. Wash thoroughly after handling. Do not puncture or incinerate container. Do not expose
to heat or store at temperatures above 120 F.
ENVIRONMENTAL HAZARDS: Do not discharge effluent containing this product into streams, ponds, estuaries, oceans or other
waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the
permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems
without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office
of the EPA.
ADDITIONAL CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are listed on the DSL Inventory.
CANADIAN WHMIS SYMBOLS: A - Compressed gas
D2B - Poisonous and infectious material - Other effects - Toxic

This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the
MSDS contains all the information required by the CPR.

16. OTHER INFORMATION
PREPARED BY:

DATE OF PRINTING

ADVANCED CHEMICAL SAFETY, Inc.
7563 Convoy Court
San Diego, CA 92111
(858)-874-5577
September 8, 2004

HOMAX EASY TOUCH COARSE ACOUSTIC TEXTURE Product ID#:4070, Revision Date: April 20, 2004
page 7 of 8

DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these, which are commonly used, include the following:
CAS #: This is the Chemical Abstract Service Number that uniquely identifies each compound.
ACGIH - American Conference of Governmental Industrial Hygienists, a
professional association which establishes exposure limits.
TLV - Threshold Limit Value - an airborne concentration of a substance that
represents conditions under which it is generally believed that nearly all workers
may be repeatedly exposed without adverse effect. The duration must be
considered, including the 8-hour Time Weighted Average (TWA), the 15minute Short Term Exposure Limit, and the instantaneous Ceiling Level (C).
Skin absorption effects must also be considered.
OSHA - U.S. Occupational Safety and Health Administration.
PEL - Permissible Exposure Limit - This exposure value means exactly the
same as a TLV, except that it is enforceable by OSHA. The OSHA Permissible
Exposure Limits are based in the 1989 PELs and the June, 1993 Air
Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 40191). Both
the current PELs and the vacated PELs are indicated. The phrase, Vacated
1989 PEL, is placed next to the PEL that was vacated by Court Order.
IDLH - Immediately Dangerous to Life and Health - This level represents a
concentration from which one can escape within 30-minutes without suffering
escape-preventing or permanent injury. The DFG - MAK is the Republic of
Germany s Maximum Exposure Level, similar to the U.S. PEL. NIOSH is the
National Institute of Occupational Safety and Health, which is the research arm
of the U.S. Occupational Safety and Health Administration (OSHA). NIOSH
issues exposure guidelines called Recommended Exposure Levels (RELs).
When no exposure guidelines are established, an entry of NE is made for
reference.
HAZARD RATINGS:
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM:
Health
Hazard: 0 (minimal acute or chronic exposure hazard); 1 (slight acute or chronic
exposure hazard); 2 (moderate acute or significant chronic exposure hazard); 3
(severe acute exposure hazard; onetime overexposure can cause permanent
injury and may be fatal); 4 (extreme acute exposure hazard; onetime
overexposure can be fatal). Flammability Hazard: 0 (minimal hazard); 1
(materials that require substantial pre-heating before burning); 2 (combustible
liquid or solids; liquids with a flash point of 38-93 C [100-200 F]); 3 (Class IB
and IC flammable liquids with flash points below 38 C [100 F]); 4 (Class IA
flammable liquids with flash points below 23 C [73 F] and boiling points below
38 C [100 F]. Reactivity Hazard: 0 (normally stable); 1 (material that can
become unstable at elevated temperatures or which can react slightly with
water); 2 (materials that are unstable but do not detonate or which can react
violently with water); 3 (materials that can detonate when initiated or which can
react explosively with water); 4 (materials that can detonate at normal
temperatures or pressures).
NATIONAL FIRE PROTECTION ASSOCIATION: Health Hazard: 0
(material that on exposure under fire conditions would offer no hazard beyond
that of ordinary combustible materials); 1 (materials that on exposure under fire
conditions could cause irritation or minor residual injury); 2 (materials that on
intense or continued exposure under fire conditions could cause temporary
incapacitation or possible residual injury); 3 (materials that can on short
exposure could cause serious temporary or residual injury); 4 (materials that
under very short exposure could cause death or major residual injury).
Flammability Hazard and Reactivity Hazard:
Refer to definitions for
Hazardous Materials Identification System .

FLAMMABILITY LIMITS IN AIR:
Much of the information related to fire and explosion is derived from the
National Fire Protection Association (NFPA). Flash Point - Minimum
temperature at which a liquid gives off sufficient vapors to form an ignitable
mixture with air. Autoignition Temperature: The minimum temperature
required to initiate combustion in air with no other source of ignition. LEL - the
lowest percent of vapor in air, by volume, that will explode or ignite in the
presence of an ignition source. UEL - the highest percent of vapor in air, by
volume, that will explode or ignite in the presence of an ignition source.
TOXICOLOGICAL INFORMATION:
Possible health hazards as derived from human data, animal studies, or from the
results of studies with similar compounds are presented. Definitions of some
terms used in this section are: LD50 - Lethal Dose (solids & liquids) which kills
50% of the exposed animals; LC50 - Lethal Concentration (gases) which kills
50% of the exposed animals; ppm concentration expressed in parts of material
per million parts of air or water; mg/m3 concentration expressed in weight of
substance per volume of air; mg/kg quantity of material, by weight,
administered to a test subject, based on their body weight in kg. Other measures
of toxicity include TDLo, the lowest dose to cause a symptom and TCLo the
lowest concentration to cause a symptom; TDo, LDLo, LDo, TC, TCo, LCLo,
and LCo, the lowest dose (or concentration) to cause lethal or toxic effects. BEI
- Biological Exposure Indices, represent the levels of determinants which are
most likely to be observed in specimens collected from a healthy worker who
has been exposed to chemicals to the same extent as a worker with inhalation
exposure to the TLV. Ecological Information: EC is the effect concentration in
water.
Data from several sources are used to evaluate the cancer-causing potential of
the material. The sources and ratings are: IARC - the International Agency for
Research on Cancer; 1 = Carcinogenic to humans, 2A, 2B = Probably
carcinogenic to humans, 3 = Unclassifiable as to carcinogenicity in humans, and
4 = Probably not carcinogenic to humans. NTP - the National Toxicology
Program; K =Known to be a human carcinogen, and R = Reasonably anticipated
to be a human carcinogen. RTECS - the Registry of Toxic Effects of Chemical
Substances. OSHA - Occupational Safety and Health Administration and
CAL/OSHA - California s subunit of the Occupational Safety and Health
Administration; Ca = Carcinogen defined with no further categorization.
ACGIH American Conference of Governmental Industrial Hygienists; A1 =
Confirmed human carcinogen, A2 = Suspected human carcinogen, A3 =
Confirmed animal carcinogen with unknown relevance to humans, A4 = Not
classifiable as a human carcinogen, and A5 = Not suspected as a human
carcinogen. NIOSH
U.S. National Institute for Occupational Safety and
Health; Ca = Potential occupational carcinogen, with no further categorization.
EPA U.S. Environmental Protection; A = Human carcinogen, B = Probable
human carcinogen, C = Possible human carcinogen, D = Not classifiable as to
human carcinogenicity, E = Evidence of Non-carcinogenicity for humans, K =
Known human carcinogen, L = Likely to produce cancer in humans, CBD =
Cannot be determined, NL = Not likely to be carcinogenic in humans, and I =
Data are inadequate for an assessment of human carcinogenic potential.
REGULATORY INFORMATION:
This section explains the impact of various laws and regulations on the material.
EPA is the U.S. Environmental Protection Agency. WHMIS is the Canadian
Workplace Hazardous Materials Information System. DOT and TC are the U.S.
Department of Transportation and the Transport Canada, respectively.
Superfund Amendments and Reauthorization Act (SARA); the Canadian
Domestic/Non-Domestic Substances List (DSL/NDSL); the U.S. Toxic
Substance Control Act (TSCA); Marine Pollutant status according to the DOT;
the Comprehensive Environmental Response, Compensation, and Liability Act
(CERCLA or Superfund); and various state regulations. This section also
includes information on the precautionary warnings that appear on a material s
industrial package label.

HOMAX EASY TOUCH COARSE ACOUSTIC TEXTURE Product ID#:4070, Revision Date: April 20, 2004
page 8 of 8

This document was created with Win2PDF available at http://www.daneprairie.com.
The unregistered version of Win2PDF is for evaluation or non-commercial use only.

1

PRODUCT TRADE NAME:

HAZARDOUS MATERIAL INFORMATION
SYSTEM

HOMAX PRODUCTS, INC.

EASY TOUCH KNOCKDOWN
ITEM #4060, 4065,4165

(HAZARD RATING: 0=LEAST, 1=SLIGHT, 2=MODERATE, 3=HIGH,
4=EXTREME) (A=SAFETY GLASSES)
SECTION I

MANUFACTURER'S NAME:
HOMAX PRODUCTS, INC.
840 WEST HORTON ROAD
BELLINGHAM WA 98226

HEALTH

2

FLAMMABILITY

0

REACTIVITY

0

PROTECTIVE EQUIPMENT

A

24 HOUR EMERGENCY PHONE NUMBER:
CHEMTREC 1-800-424-9300
FORMATION PHONE NUMBER: 1-800-729-9029
DATE OF PREPARATION:

SECTION II - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION
CAS
NUMBER
DESCRIPTION
PEL
TLV

04/22/03

%

14807-96-6
107-21-1

TALC
ETHYLENE GLYCOL

20 MPPCH\F
50PPM

2MG/M
50PPM

5-10%
1-5%

115-10-6
14807-96-6

DIMETHYL ETHER PROPELLA
TALC

N/A
20 MPPCH/F

N/A
2MG/M

500PPM
5-10%

THE DRIED FILM OF THIS PRODUCT MAY BECOME A DUST NUISANCE WHEN REMOVED BY SANDING OR
GRINDING. OSHA RECOMMENDS A PEL/TWA OF 15 mg/m3 FOR TOTAL DUST AND 5mg/m3 FOR THE RESPIRABLE
FRACTION. ACGIH RECOMMENDS A TLV/TWA OF 10mg/m3 FOR TOTAL DUST.
SKIN ABSORPTION MAY CONTRIBUTE TO THE OVERALL EXPOSURE TO THIS MATERIAL. TAKE APPROPRIATE
MEASURES TO PREVENT SKIN CONTACT.
SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS
APPEARANCE AND ODOR:
GRAYISH-WHITE LIQUID WITH TYPICAL LATEX ODOR.
BOILING POINT:
N/E
VAPOR PRESSURE:
>1
WATER SOLUBILITY %:
N/E
VAPOR DENSITY (AIR = 1):
>1
EVAPORATION RATE:
<1
SPECIFIC GRAVITY (WATER = 1):
0.939
% VOLATILITY BY VOLUME:
59.74
N/E = NOT ESTABLISHED
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (METHOD USED):
N/E

2
LEL:
FLAMMABLE LIMITS:
UEL:
EXTINGUISHING MEDIA:

N/A
N/E
N/A
USE WATER FOG, FOAM, DRY CHEMICAL OR CARBON DIOXIDE,
ALCOHOL FOAM.
LEVEL ONE AEROSOL

UNIFORM FIRE CODE STANDARD 88-1

SPECIAL FIREFIGHTING PROCEDURES:
FIREFIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS IF DUSTY CONDITIONS ARE
PRESENT. USE WATER SPRAY TO COOL EXPOSED CONTAINTERS. IF POSSIBLE, LET BURN UNTIL
SOURCE OF GAS IS SHUT OFF. SEVERE HAZARD WHEN EXPOSED TO HEAT OR FLAME.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CLOSED CONTAINERS MAY EXPLOSE DUE TO BUILD UP OF PRESSURE FROM EXTREME HEAT OF FIRE.
MIXTURES WITH AIR ARE HIGHLY FLAMMABLE.
SECTION V - REACTIVITY DATA
STABILITY:
MATERIAL IS STABLE. HAZARDOUS PLOYMERIZATION WILL NOT OCCUR.
INCOMPATIBILITY (MATERIALS TO AVOID):
BASED ON THE PRESENCE OF COMPONENET 2 AVOID OXIDIZING MATERIALS, AVOID ALKALIES, HIGH
TEMPERATURE, KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. STRONG OXIDIZING AGENTS,
OXYGEN, AVETIC ACID, ORGANIC ACID ANHYDRIDES.
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON DIOXIDE, CARBON MONOXIDE AND UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED
BURING COMBUSTION.
CONDITIONS TO AVOID:
TEMPERATURES ABOVE 1500F. HYDROFLUORIC ACID. AVOID HIGH TEMPERATURE, IGNITION SOURCES.
SECTION VI - HEALTH HAZARD DATA
ROUTES OF ENTRY:
INHALATION: YES

SKIN: YES

INGESTION: YES

HEALTH HAZARDS (ACUTE AND CHRONIC):
BASED ON THE PRESENCE OF COMPONENT 1 CHRONIC OVER EXPOSURE TO TALC DUST MAY CAUSE
SCARRING OF THE LUNGS. BASED ON THE PRESENCE OF COMPONENT 2 PRODUCT IS PRESUMED TO
BE AN ANIMAL TERATOGEN. EXPOSURE TO HIGH VAPOR CONCENTRATIONS MAY PRODUCE
ANESTHETIC EFFECTS. EYE OR SKIN CONTACT WITH LIQUID MAY PRODUCE BURNS DUE TO THE
FREEZING EFFECT.
INHALATION:
EXPOSURE MAY PRODUCE IRRITATION TO THE NOSE, THROAT, RESPIRATORY TRACT, AND OTHER
MUCOUS MEMBRANES. BASED ON THE PRESENCE OF COMPONENT 2 EXPOSURE TO HIGH
CONCENTRATIONS OF VAPOR MAY PRODUCE CENTRAL NERVOUS SYSTEM DEPRESSION. REPORTS
HAVE ASSOCIATED REPEATED AND PROLONGED INTENTIONAL MISUSE BY DELIBERATELY
CONCENTRATING AND INHALING THE CONTENET MAY BE HARMFUL OR FATAL. EXPOSURE TO HIGH
VAPOR CONCENTRATION MAY PRODUCE ANESTHETIC EFFECTS.
INGESTION:
BASED ON THE PRESENCE OF COMPONENT 2 PRODUCT IS PRESUMED TO BE MODERATELY TOXIC.
BASED ON THE PRESENCE OF COMPONENT 2 INGESTION MAY CAUSE KIDNEY DAMAGE. BASED ON THE
PRESENCE OF COMPONENT 2 INGESTION MAY CAUSE LUMBAR PAIN, OLIGURIA OR UREMIA. BASED ON
THE PRESENCE OF COMPONENT 2 INGESTION MAY CAUSE CENTRAL NERVOUS SYSTEM DAMAGE.
CARCINOGENICITY:

NTP - NO

IARC MONOGRAPHS - NO

SIGNS AND SYMPTOMSOF EXPOSURE:

OSHA REGULATED - NO

3
SYMPTOMS OR EYE IRRITATION INCLUDE PAIN, TEARING, REDDENING AND SWELLING. SYMPTOMS OF
SKIN IRRITATION INCLUDE REDDENING, SWELLING, RASH AND REDNESS. SYMPTOMS OF RESPIRATORY
IRRITATION INCLUDE RUNNY NOSE, SORE THROAT, COUGHING, CHEST DISCOMFORT, SHORTNESS OF
BREATH, AND REDUCED LUNG FUNCTION. SYMPTOMS OF GASTROINTESTINAL IRRITATION INCLUDE
SORE THROAT, ABDOMINAL PAIN, NAUSEA, VOMITING AND DIARRHEA. BASED ON THE PRESENCE OF
COMPONENT 2 CENTRAL NERVOUS SYSTEM DEPRESSION MAY BE EVIDENCED BY HEADACHE,
DIZZINESS, NAUSEA AND SYMPTOMS OF INTOXICATION; IN EXTREME CASES, UNCONSCIOUSNESS AND
DEATH MAY OCCUR. SYMPTOMS OF CHRONIC OVEREXPOSURE INCLUDE LOSS OF MEMORY, LOSS OF
INTELLECTUAL ABILITY AND LOSS OF COORDINATION. CONTACT WITH LIQUID MAY PRODUCE FREEZING
EFFECTS.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:
PREEXISTING EYE, SKIN OR REISPIRATORY DISORDERS MAY BE AGGREAVATED. IMPAIRED CENTRAL
NERVOUS SYSTEM FUNCTIONS FROM PREEXISTING DISORDERS MAY BE AGGRAVATED BY EXPOSURE
TO THIS PRODUCT.
EMERGENCY AND FIRST AID PROCEDURES:
IF INHALED:
REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. GET IMMEDIATE MEDICAL
ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH LOTS OF RUNNING WATER FOR 15 MINUTES, LIFTING UPPER AND
LOWER LIDS OCCASIONALLY. GET IMMEDIATE MEDICAL ATTENTION IF SYMPTOMS PERSIST.
SKIN CONTACT:
IMMEDIATELY WASH SKIN WITH LOTS OF SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
SHOES; WASH BEFORE REUSE. GET MEDICAL ATTENTION IF IRRITATION PERSISTS AFTER WASHING.
INGESTION:
DILUTE WITH TWO GLASSES OF WATER UNLESS THE VICTIM IS UNCONSCIOUS OR VERY DROWSY.
INDUCE VOMITING BY GIVING TWO TABLESPOONS IPECAC OR BY TOUCHING A FINGER TO THE BACK OF
THE VICTIM’S THROAT. KEEP THE VICTIM’S HEAD BELOW THE HIPS TO PREVENT ASPIRATION INTO THE
LUNGS. CONSULT A PHYSICIAN, HOSPITAL OR POISON CONTROL CENTER AND / OR TRANSPORT TO AN
EMERGENCY FACILITY IMMEDIATELY.
NOTES TO PHYSICIAN:
COMPONENT 2 ETHYLENE GLYCOL MAY CAUSE KIDNEY DAMAGE AND METABOLIC ACIDOSIS. ETHANOL
IS ANTIDOTAL, AND ITS EARLY ADMINISTRATION MAY BLOCK THE FORMATION OF NEPHROTOXIC
METABOLITES OF ETHYLENE GLYCOL IN THE LIVER. ETHANOL SHOULD BE GIVEN INTRAVENOUSLY, AS A
5% SOLUTION IN SODIUM BICARBONATE, AT A RATE OF ABOUT 10ml ETHANOL PER HOUR. A DESIRED
THERAPEUTIC LEVEL OF ETHANOL IN BLOOD IS 100mg/dl. HEMODIALYSIS MAYBE REQUIRED.
PULMONARY EDEMA WITH HYPOXEMIA HAS BEEN DESCRIBED IN A NUMBER OF PATIENTS FOLLOWING
POISONING WITH ETHYLENE GLYCOL. THE MECHANISM OF PRODUCTION HAS NOT BEEN ELUCIDATED,
BUT IT APPEARS TO BE NONCARDIOGENIC IN ORIGIN IN SEVERAL CASES. RESPIRATORY SUPPORT WITH
MECHANICAL VENTILATION AND POSITIVE END-EXPIRATORY PRESSURE MAY BE REQUIRED.
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER.
SECTION VII – PRECAUTIONS FOR SAFE HANDLING AND USE
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
FOR LARGE SPILLS EVACUATE THE HAZARD AREA OF UNPROTECTED PERSONNEL. WEAR
APPROPRIATE RESPIRATOR AND PROTECTIVE CLOTHING. SHUT OFF SOURCE OF LEAK ONLY IF SAFE
TO DO SO. DIKE AND CONTAIN. IF VAPOR CLOUD FORMS, WATER FOG MAY BE USED TO SUPPRESS;
CONTAIN RUN-OFF. REMOVE WITH VACUUM TRUCKS OR PUMP TO STORAGE/SALVAGE VESSELS. SOAK
UP RESIDUE WITH AN ABSORBENT SUCH AS CLAY, SAND OR OTHER SUITABLE MATERIAL; PLACE IN
NONLEAKING CONTAINERS FOR PROPER DISPOSAL. FLUSH AREA WITH WATER TO REMOVE TRACE
RESIDUE; DISPOSE OF FLUSH SOLUTIONS AS ABOVE. REMOVE ALL SOURCES OF IGNITION: SPARKS,

4
STATIC ELECTRICITY & ELECTRICAL. VENTILATE AREA. DISPERSE WITH WATER SPRAY. KEEP
PERSONNEL UP-WIND.
FOR SMALL SPILLS TAKE UP WITH AN ABSORBENT MATERIAL AND PLACE IN NONLEAKING CONTAINERS;
SEAL TIGHTLY FOR PROPER DISPOSAL.
WASTE DISPOSAL:
DISPOSE OF CONTAMINATED PRODUCT AND MATERIALS USED IN CLEANING UP SPILLS AND LEAKS IN A
MANNER APPROVED FOR THIS MATERIAL. CONSULT APPROPRIATE FEDERAL, STATE AND LOCAL
REGULATORY AGENCIES TO ASCERTAIN PROPER PROCEDURES. BURN UNDER CONTROLLED
CONDITIONS. DO NOT INCINERATE CLOSED CONTAINERS.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
STORE IN COOL, DRY PLACE. KEEP BAGS AND CONTAINERS DRY AT ALL TIMES. WASH THOROUGHLY
AFTER HANDLING. DO NOT GET IN EYES, ON SKIN OR CLOTHING. DO NOT STORE ABOVE 120 DEG. F. DO
NOT STORE NEAR HEAT, SPARKS OR FLAME. PROTECT FROM ALL SOURCES OF IGNITION.
OTHER PRECAUTIONS:
CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED, WILL RETAIN PRODUCT RESIDUE. ALWAYS
OBEY HAZARD WARNINGS AND HANDLE EMPTY CONTAINERS AS IF THEY WERE FULL. DO NOT GET IN
EYES, BREATHE VAPORS. AVOID SKIN CONTACT. DO NOT TAKE INTERNALLY. SMOKING WHEN USING
THIS PRODUCT MUST BE STRICTLY PROHIBITED.
SECTION VIII –CONTROL MEASURES
RESPIRATORY PROTECTION:
USE VENTILATION AS REQUIRED TO CONTROL VAPOR CONCENTRATIONS AT LEAST 10 AIR CHANGES
PER HOUR AREA RECOMMENDED FOR GOOD GENERAL ROOM VENTILATION. IF EXPOSURE EXCEEDS
THE PEL/TLV, USE A NIOSH-APPROVED DUST RESPIRATOR OR MASK PER REQUIREMENTS OF 29 CFR
1910.134.
VENTILATION:
USE LOCAL EXHAUST CAPABLE OF MINIMIZING VAPOR CONCENTRATIONS AT POINT OF USE. ALL
APPLICATION AREAS SHOULD BE ADEQUATELY VENTILATED IN ORDER NOT TO EXCEED SECTION II
COMPONENT TLV.
PROTECTIVE GLOVES:
USE NEOPRENE OR OTHER SOLVENT RESISTANT GLOVES TOPREVENT SKIN CONTACT.
EYE PROTECTIONS:
NIOSH-APPROVED DUST GOGGLES OR A SPLASH SHIELD SHOULD BE USED TO PREVENT SKIN
CONTACT. CONTACT LENSES SHOULD NOT BE WORN.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT:
LONG-SLEEVED SHIRT, TROUSERS AND SAFETY SHOES. FREEZING RESISTANT GLOVES ARE
RECOMMENDED.
WORK/HYGIENIC PRACTICES:
AVOID SKIN OR EYE CONTACT. DO NOT BREATH VAPORS. WASH THOROUGHLY AFTER HANDLING AND
BEFORE EATING, DRINKING OR SMOKING. AN EYEWASH AND SAFETY SHOWER SHOULD BE NEARBY
AND READY FOR USE.

SECTION IX- DISCLAIMER
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE, OBTAINED FROM
SOURCES BELIEVED BY HOMAX PRODUCTS, INC. TO BE ACCURATE. SINCE THE CONDITIONS AND METHODS OF
USE OF OUR PRODUCTS ARE BEYOND OUR CONTROL, WE DISCLAIM ANY AND ALL LIABILITY ARISING OUT OF
THE IMPROPER USE OF THESE PRODUCTS OR THE INFORMATION PROVIDED HEREWITH.
SHIPPING CLASSIFICATION: ORM-D HAZARDOUS MATERIAL DEFINED BY THE DOT.
PROPER SHIPPING NAME: CONSUMER COMMODITY

1

PRODUCT TRADE NAME:
HAZARDOUS MATERIAL INFORMATION
SYSTEM

HOMAX PRODUCTS, INC.

EASY TOUCH SPRAY TEXTURE

(R)

HEALTH

2

FLAMMABILITY

4

REACTIVITY

0

PROTECTIVE EQUIPMENT

J

ITEM #4050, 4055, 4101, 4155

(HAZARD RATING: 0=LEAST, 1=SLIGHT, 2=MODERATE, 3=HIGH,
4=EXTREME) (J=SPLASH GOGGLES, GLOVES, SYNTHETIC APRON,
DUST & VAPOR RESPIRATOR)
SECTION I
MANUFACTURER'S NAME:
HOMAX PRODUCTS, INC.
468 W. HORTON RD.
BELLINGHAM WA 98226

24 HOUR EMERGENCY PHONE NUMBER:
CHEMTREC 1-800-424-9300
NFORMATION PHONE NUMBER:

1-800-729-9029

DATE OF PREPARATION:

03/05/03

SECTION IIA - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION
CAS
WEIGHT
-OCCUPATIONAL EXPOSURE LIMITSVAPOR PRESS.
NUMBER
DESCRIPTION
PERCENT OSHA PEL** AOGIH TLV
OTHER
mm HG TEMP
01330-20-7
00100-41-4
00071-13-2
64742-89-8
00074-98-6
00075-28-5
01330-20-7
13463-67-7
00067-64-1

XYLENE
ETHYL BENZENE
BENZENE
PETROLEUM NAPTHA, ALKANES &
NAPHTHENES
PROPANE
ISOBUTANE
XYLENE
TITANIUM DIOXIDE
ACETONE

12
2.2
*Trace
8

100PPM
100PPM

100PPM
100PPM

434 mg/m3
434 mg/m3

NOT EST

300PPM

6
2
9
2
9

SIMPLE
NOT EST
100PPM
10 mg/m3
750PPM

ASPHIXIANT
800PPM
100PPM
10 mg/m3
750PPM

1000PPM
(ESTIMATE)
434MG/M3
(DUST)
1780 mg/m3

25
10

77
77

80

70

3619

70

25

77

181

68

* Trace quantities less than 0.1% and greater than 0.005%
**PELs represent lowered 1989 limits and may not be enforceable by Federal OSH

SECTION IIB - OTHER REGULATORY INFORMATION
CAS
NUMBER
01330-20-7
00100-41-4
00071-13-2
64742-89-8
00074-98-6
00075-28-5
00108-88-3

DESCRIPTION
XYLENE
ETHYL BENZENE
BENZENE
PETROLEUM NAPTHA, ALKANES &
NAPHTHENES
PROPANE
ISOBUTANE
TOLUENE

CARCINOGEN
NTP IARC OSHA

X

SARA TITLE III
302 313
X
X
X

X

CALIFORNIA
P65
I
II
X
X

X

X

X

2
13463-67-7
00087-84-1

TITANIUM DIOXIDE
ACETONE

SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS
BOILING RANGE:
-13 TO 2500 DEG F
VAPOR DENSITY:
HEAVIER THAN AIR
CALCULATED V.O.C.:
3.95LB/GL(474GR/LT)
SOLUBILITY IN WATER:
NON-SOLUABLE
APPEARANCE AND ODOR:
OPAQUE LIQUID, PETROLEUM ODOR
WT/GAL:
11.71 (WITH PROP: 8.85)
EVAPORATION RATE:
SAME AS (n-Butyl acetate=MEDIAN)
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
OSHA FLAMMABILITY CLASS:
FLAMMABLE LIQUID CLASS 1A
UNIFORM FIRE CODE STANDARD 88-1
LEVEL 1 AEROSOL
BULK FLASH POINT:
-4 DEG F
METHOD USED: P-MARTEN
BULK PROPELLANT FLASH POINT:
-158 DEG F
PACKAGED PRODUCT FLAME EXTENSION:
28
FLAMMABLE LIMITS IN AIR BY VOLUME:
LOWER: 1.0%
UPPER: 12.8%
EXTINGUISHING MEDIA:
FOAM, CO2, DRY CHEMICAL, WATER FOG
DOT/CERCLA:
THE DOT/CERCLA REPORTABLE QUANTITY (RQ) FOR THIS PRODUCT IS 1004 GALLONS BASED ON
XYLENE RQ 1000 LBS.
SPECIAL FIREFIGHTING PROCEDURES:
EVACUATE ALL UNNECESSARY PERSONNEL. USE FULL PROTECTIVE EQUIPMENT, INCLUDING SELFCONTAINED BREATHING APPARATUS. USE WATER SPRAY, PREFERABLY FOG, TO COOL CLOSED
CONTAINERS TO PREVENT PRESSURE BUILD-UP AND POSSIBLE EXPLOSION. DO NOT ALLOW PRODUCT
OR RUNOFF FROM FIRE CONTROL TO ENTER STORM OR SANITARY SEWERS, LAKES, RIVERS, STREAMS,
OR WATERWAYS.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
EXPLOSIVE AIR-VAPOR MIXTURES MAY FORM WHICH ARE DANGEROUS WHEN EXPOSED TO HEAT OR
FLAME. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL ALONG THE GROUND, OR BE MOVED BY
VENTILATION, AND IGNITED BY PILOT LIGHTS, STOVES, HEATERS, ELECTRIC MOTORS, SPARKS, FLAME,
SMOKING, STATIC DISCHARGE OR OTHER IGNITION SOURCES EVEN AT LOCATIONS DISTANT FROM
MATERIAL HANDLING SITE. CONTENTS UNDER PRESSURE. EXPOSURE TO HEAT OR PROLONGED
EXPOSURE TO SUN MAY CAUSE BURSTING.
SECTION V - REACTIVITY DATA
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE, IRRITATING FUMES,
HYDROCARBONS, NITROGEN OXIDES, WATER VAPORS, TOXIC MATERIALS, AMMONIA FUMES.
INCOMPATIBILITY (MATERIALS TO AVOID):
STRONG OXIDIZING AGENTS, ACIDS, ALKALIS, WATER,
CHLORINATED COMPOUNDS, COPPER, BASES.
STABILITY: STABLE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
CONDITIONS TO AVOID: HIGH TEMPERATURE AND HUMIDITY, IGNITION SOURCE, VAPOR BUILD-UP.
SECTION VI - HEALTH HAZARD DATA
PRIMARY ROUTE(S) OF EXPOSURE:

INHALATION, SKIN CONTACT

ACUTE EFFECTS FORM SHORT TERM EXPOSURE:
INHALATION:
VAPORS AND MISTS IRRITATE NOSE, THROAT AND LUNGS (BURNING, STINGING, COUGHING). MAY
CAUSE HEADACHE, DIZZINESS, NAUSEA, WEAKNESS, SHORTNESS OF BREATH AND LOSS OF
COORDINATION. EXPOSURE TO EXTREMELY HIGH VAPOR CONCENTRATIONS MAY CAUSE

3
UNCONSCIOUSNESS AND ASPHYXIATION. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING
AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL.
EYES: CONTACT WITH LIQUID OR VAPORS CAUSES SEVERE IRRITATION (REDNESS, WATERING, ITCHING,
STINGING, BLURRED VISION).
SKIN:

CONTACT CAUSES SEVERE IRRITATION (DRYNESS, ITCHING, CRACKING, RASH, SWELLING) AND
POSSIBLE BURNS.

SKIN ABSORPTION: NONE KNOWN
SWALLOWING: CAUSES NAUSEA, VOMITING, DIARRHEA AND CENTRAL NERVOUS SYSTEM DEPRESSION
(HEADACHE, DIZZINESS, GIDDINESS, NAUSEA, LOSS OF COORDINATION).
CHRONIC EFFECTS FROM LONG TERM/REPEATED EXPOSURE:
LONG-TERM OR REPEATED OVER EXPOSURE, WITHOUT PROPER VENTILATION OR PERSONAL
PROTECTION, MAY CAUSE DAMAGE TO: KIDNEYS, LIVER, HEART, BRAIN AND NERVOUS SYSTEM.
OTHER: N/A
CARCINOGEN DATA: N/A
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:
RESPIRATORY TRACT IRRITATION, NAUSEA, SKIN AND EYE DISORDERS, SENSITIZATION TO CHEMICAL
SUBSTANCES.
SECTION VII - EMERGENCY AND FIRST AID PROCEDURES
SWALLOWING:
IN CASE OF ACCIDENTAL INGESTION, CALL POISON CENTER, EMERGENCY ROOM OR PHYSICIAN
IMMEDIATELY.
INHALATION:
IF AFFECTED BY BREATHING ODORS OR VAPORS, REMOVE TO FRESH AIR. GET MEDICAL ATTENTION IF
SYMPTOMS PERSIST.
EYE:

IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES, WHILE LIFTING UPPER AND LOWER
EYELIDS. GET MEDICAL ATTENTION.

SKIN:

WASH WITH SOAP AND WATER. REMOVE AND CLEAN CONTAMINATED CLOTHING AND SHOES. GET
MEDICAL ATTENTION IF IRRITATION PERSISTS.

OTHER: N/A

SECTION VIII - PERSONAL PROTECTION
RESPIRATORY PROTECTION:
IF AFFECTED BY BREATHING VAPORS OR ODORS, WEAR A PROPERLY FITTED RESPIRATOR
(NIOSH/MSHA TC23C OR EQUIVALENT) DURING USE. IF PRODUCT GIVES OFF SPRAY MIST, AVOID
BREATHING BY WEARING RESPIRATOR PREFILTER OR PARTICLE MASK.
VENTILATION:
OPEN DOORS AND WINDOWS TO PROVIDE FRESH AIR VENTILATION, IN WORK AND IN SURROUNDING
AREAS, DURING AND AFTER APPLICATION UNTIL ALL VAPOR (FUMES) ARE GONE.
HAND PROTECTION:
WEAR GLOVES TO AVOID SKIN CONTACT.
EYE PROTECTION:
WEAR SAFETY GLASSES OR GOGGLES TO PROTECT EYES FROM SPLASH AND SPRAY MIST. NOTE:
CONTACT LENSES MAY CONTRIBUTE TO THE SEVERITY OF AN EYE INJURY AND SHOULD NOT BE WORN
WHEN WORKING WITH CHEMICAL PRODUCTS.

4
OTHER PROTECTIVE EQUIPMENT:
WHEN NECESSARY, WEAR PROTECTIVE CLOTHING TO AVOID SKIN CONTACT WITH LIQUID AND
OVERSPRAY.
WORK/HYGIENIC PRACTICES:
WASH HANDS AFTER USING AND BEFORE EATING, DRINKING, OR USING TOBACCO PRODUCTS.
THOROUGHLY CLEAN CONTAMINATED CLOTHING AND SHOES BEFORE REUSE.
SPILL OR LEAK PROCEDURES:
ELIMINATE IGNITION SOURCES AND VENTILATE AREA. EVACUATE ALL UNNECESSARY PERSONNEL.
WEAR PROTECTIVE EQUIPMENT. DIKE DRAINS TO PREVENT ENTERING STORM OR SANITARY SEWERS,
LAKES, RIVERS, STREAMS, OR WATERWAYS. CONTAIN SPILL AND COVER WITH INERT ABSORBENT
MATERIAL. TAKE UP USING NON-SPARKING TOOLS (ALUMINUM, BRASS, OR COPPER) AND PLACE
MIXTURE INTO CONTAINERS FOR DISPOSAL. NOTE: SOME SPILLS OR RELEASES MAY REQUIRE SPECIAL
REPORTING TO LOCAL, STATE, OR FEDERAL AGENCIES.
WASTE DISPOSAL:
WASTE MATERIAL AND EMPTY CONTAINERS MUST BE DISPOSED OF IN ACCORDANCE WITH ALL LOCAL,
STATE, AND FEDERAL ENVIRONMENTAL CONTROL REGULATIONS. USE ONLY APPROVED WASTE
MANAGEMENT FACILITIES.
SPECIAL PRECAUTIONS:
HANDLING PRECAUTIONS:
KEEP LIQUID AND VAPORS AWAY FROM HEAT, SPARKS AND FLAME. TURN OFF OR REMOVE ALL
SOURCES OF IGNITION. USE PROPER METHODS OF VENTILATION TO PREVENT VAPOR BUILD-UP. AVOID
SPRAYING HOT SURFACES. AVOID BREATHING VAPORS AND SPRAY MISTS. AVOID CONTACT WITH
EYES AND SKIN. DO NOT TAKE INTERNALLY. USE ADEQUATE METHODS OF VENTILATION, RESPIRATORY
AND PERSONAL PROTECTION EQUIPMENT. DO NOT HEAT, PUNCTURE OR INCINERATE CONTAINERS.
CONTENTS ARE UNDER PRESSURE AND MAY CONTAIN EXPLOSIVE VAPORS, EVEN WHEN EMPTY. DO
NOT REMOVE OR DEFACE LABEL.
SHIPPING AND STORAGE PRECAUTIONS:
CONTENTS UNDER PRESSURE. DO NOT STORE ABOVE 120 DEGREES F. OR PERMIT PROLONGED
EXPOSURE TO SUNLIGHT. PROTECT CONTAINERS FROM DAMAGE. STORE IN BUILDINGS OR AREAS
DESIGNED AND PROTECTED FOR STORAGE OR AEROSOLS. KEEP OUT OF REACH OF CHILDREN.
SECTION IX- DISCLAIMER
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE, OBTAINED FROM
SOURCES BELIEVED BY HOMAX PRODUCTS, INC. TO BE ACCURATE. SINCE THE CONDITIONS AND METHODS OF
USE OF OUR PRODUCTS ARE BEYOND OUR CONTROL, WE DISCLAIM ANY AND ALL LIABILITY ARISING OUT OF
THE IMPROPER USE OF THESE PRODUCTS OR THE INFORMATION PROVIDED HEREWITH.
SHIPPING INFORMATION:
PRODUCT CLASSIFICATION: ORM-D
HAZARD CLASS: CONSUMER COMMODITY
UN IDENTIFICATION NUMBER: N/A
DOT LABEL (S) REQUIRED: N/A
PACKAGING GROUP: N/A

PART I

What is the material and what do I need to know in an emergency?

1. PRODUCT IDENTIFICATION
TRADE NAME (AS LABELED):
PRODUCT CODES:
PRODUCT USE:
SUPPLIER/MANUFACTURER'S NAME:
ADDRESS:
CHEMTREC EMERGENCY NO.:
BUSINESS PHONE:
DATE OF PREPARATION:

HOMAX Waterbased ORANGEPEEL & SPLATTER Spray Texture

4091, 4092, 4192, 4091-06,4092-06, 4091-10-06
Patching Interior Texture
HOMAX PRODUCTS, INC.
200 Westerly Rd.
Bellingham, WA 98226
1-800-424-9300 (United States)
1-703-527-3887 (International Collect)
1-800-729-9029
Nov. 16, 2006

2. COMPOSITION and INFORMATION ON INGREDIENTS
CHEMICAL
NAME

CAS #

% w/w

EXPOSURE LIMITS IN AIR
ACGIH-TLV

OSHA-PEL

NIOSH-REL

TWA
mg/m3

STEL
mg/m3

TWA
mg/m3

STEL
mg/m3

TWA
mg/m3

STEL
mg/m3

IDLH/OTHER
mg/m3

Calcium
Carbonate

1317-65-3

30 - 60

10

NE

15 *
5 **

NE

10 *
5 **

NE

NE

Dimethyl Ether
(Propellant)

115-10-6

7 - 13

NE

NE

NE

NE

NE

NE

DFG MAK:
IDLH: 1900
Peak: II (8)

14807-96-6

1-5

NA

20

NA

2*

NE

1000

67-63-0

3-7

492

984

980

NE

980

1225

2,000
(10% LEL)

14808-60-7

0.1-1

10 mg/m3 **
NE
0.05 *
NE
50
% SiO2+2
The ingredients in the balance of this product do not contribute significant hazards
beyond those described in this document. All pertinent health, safety and
environmental information have been presented, per the requirements of the US
Federal OSHA Hazard Communication Standard (29 CFR 1910.1200) and Canadian
WHMIS.

Talc
Isopropyl alcohol
Silica Quartz

Water and ingredients present in
concentrations of less than 1% (or
less than 0.1% if carcinogens)

2 **

0.05 R

Balance

NE

NE = Not Established. See Section 16 for Definitions of Terms Used.
NOTE (1): ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format. This product has been classified in accordance
with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
NOTE (2):* Total dust; ** Respirable fraction; R = Measured as respirable fraction of the aerosol.
NOTE (3): The component Nicron 403, is free of crystalline silica and asbestos; therefore, carcinogenicity does not apply.

3. HAZARD IDENTIFICATION
HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06

page 1 of 9

EMERGENCY OVERVIEW:
PHYISCAL DESCRIPTION: This product is a white colored aerosol with a slight ethereal odor.
HEALTH HAZARD: This product is harmful if it is inhaled or swallowed. This product may cause severe irritation to the eyes or skin.
If particulates of this product are inhaled, severe irritation of the respiratory system (i.e. lungs, nose, and throat), central nervous
system, and gastrointestinal tract could occur.
FIRE HAZARD: This product is a flammable liquid and vapor (aerosol), with its contents under pressure. HOMAX EASY TEXTURE
ORANGEPEEL & SPLATTER propellant has a flash point of - 42oF / -41oC.
REACTIVITY HAZARD: Minimal Hazard; the product is normally stable under ordinary conditions of use and storage.
ENVIRONMENTAL HAZARD: This product is does not normally present a significant hazard to aquatic or terrestrial life.
SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE:
The most significant route of occupational overexposure is contact with skin, eyes, and inhalation. The symptoms of overexposure to this
product are as follows:
INHALATION: If inhalation of product s mists or vapors occurs, severe respiratory system irritation or nervous system depression
may develop. Nervous system depression is characterized by headache, dizziness, nausea, or possible unconsciousness. CONTACT
WITH SKIN or EYES: Contact can cause severe eye or skin irritation. Symptoms of eye exposure may include redness, pain, burning
sensation, and tearing. Prolonged skin contact may result in redness, irritation, and dermatitis.
SKIN ABSORPTION: May cause irritation or burning sensation.
INGESTION: Ingestion is not anticipated to be a significant route of occupational exposure. If the product is swallowed, severe
irritation of the mouth, throat, and other tissues of the gastro-intestinal system may occur. Ingestion of large amounts may cause
irritation, pain, vomiting, and diarrhea.
INJECTION: Accidental injection of this product may cause mild irritation and swelling, in addition to the wound.

Hazardous Materials Identification System (HMIS)
Health

1*

Flammability

4

Physical Hazard

1

Protective Equipment

A

See Section 16 for Definition of Ratings
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms.
ACUTE: Depending on the duration of contact, overexposures can severely irritate the eyes, skin, lungs, respiratory tract and nervous
system. Symptoms of exposure generally alleviated when overexposure ends.
CHRONIC: Long-term skin contact may result in dermatitis.
TARGET ORGANS: Acute: Eyes, Skin, Lungs, CNS, and Respiratory tract. Chronic: Skin

PART II

What should I do if a hazardous situation occurs?

4. FIRST-AID MEASURES
Victims of chemical exposure must be taken for medical attention if any adverse effects occur. Take a copy of label and MSDS to
physician or health professional with victim.
SKIN EXPOSURE: If this product contaminates the skin, immediately begin decontamination with running water. Remove exposed or
contaminated clothing, taking care not to contaminate eyes. Victim must seek immediate medical attention if any adverse exposure
symptoms develop.
EYE EXPOSURE: If this product enters the eyes, open victim's eyes while under gently running water. Use sufficient force to open
eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. Victim must seek medical attention.
INHALATION: If this product is inhaled, blow nose and remove victim to fresh air. INGESTION: If this product is swallowed, CALL
PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION. DO NOT INDUCE VOMITING, unless
directed by medical personnel. Have victim rinse mouth with water, if conscious. Never induce vomiting or give

4. FIRST-AID MEASURES - Continued
a diluent (e.g., water) to someone who is unconscious, having convulsions, or unable to swallow. If contaminated individual is
convulsing, maintain an open airway and obtain immediate medical attention.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing conditions of pulmonary, dermatitis, and conjunctivitis
disorders.
HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06

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RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure.

5. FIRE-FIGHTING MEASURES
0

FLASH POINT: 30 F (-1.10C)
0

NFPA RATING

0

AUTOIGNITION TEMPERATURE: 662 F (350 C) (Dimethyl ether propellant)

FLAMMABILITY

FLAMMABLE LIMITS (in air by volume, %):
4

Lower: 3.4% (Dimethyl ether propellant)
Upper: 27% (Dimethyl ether propellant)
FIRE EXTINGUISHING MATERIALS: Use extinguishing material suitable to the
surrounding fire.
Water Fog: OK
Foam: OK
Halon: OK

HEALTH

1
2

Carbon Dioxide: OK
Dry Chemical: OK

0
1

REACTIVITY

OTHER

UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode due
to build up of pressure from extreme heat or fire.
Explosion Sensitivity to Mechanical Impact: Do not puncture.
Explosion Sensitivity to Static Discharge: Primarily vapors.
SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection. Structural firefighters must wear
Self-Contained Breathing Apparatus and full protective equipment. Move containers from
See Section 16 for
fire area if it can be done without risk to personnel. Exercise caution; contaminated floors
Definition of Ratings
and surfaces can be sticky. If possible, prevent runoff water from entering storm drains,
bodies of water, or other environmentally sensitive areas.

6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by trained personnel using pre-planned procedures.
Proper protective equipment should be used. In case of a spill, clear the affected area and protect people. Releases of this material may be
sticky. If the product is dried, and dusts may be generated during clean-up, dampen material prior to clean-up to avoid airborne
particulates.
RESPONSE TO INCIDENTAL RELEASES: Small scale releases, such as 1 container of this product, can generally be handled by
personnel who have received basic chemical safety training. Respond to incidental chemical releases by wearing gloves, goggles, and
appropriate body protection and by following the instructions for use presented above.
RESPONSE TO NON-INCIDENTAL RELEASES: Respond to non-incidental chemical releases of this product, such as the
simultaneous puncturing of several containers, by clearing the impacted area and contacting appropriate emergency personnel. Clean
up should only be done by qualified personnel. Responders should wear the level of protection appropriate to the type of chemical
released, the volume of the material spilled, and the location where the incident has occurred. Minimum Personal Protective
Equipment should be Level C: triple-gloves, chemical resistant apron, boots, and splash goggles and an Air-Purifying respirator with
high-efficiency particulate filter.
RESPONSE EQUIPMENT AND PROCEDURES: Wipe-away spilled paste with damp polypads or other suitable absorbent materials,
or scrape carefully with plastic tools. Decontaminate the area thoroughly. Place all spill residues in a suitable container and seal. Dispose
of in accordance with applicable U.S. Federal, State, or local procedures or appropriate standards of Canada (see Section 13, Disposal
Considerations).

PART III

How can I prevent hazardous situations from occurring?

7. HANDLING and STORAGE
WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash
thoroughly after using this product. Do not eat or drink while using this material. Avoid generating dusts and particulates of this product.
If sanding, use with adequate ventilation. Remove contaminated clothing immediately.
HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06

page 3 of 9

Deleted: 

STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to use it safely. Open containers
carefully on a stable surface. Empty containers may contain residual material; therefore, empty containers should be handled with care.
Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store away
from incompatible materials (see Section 10, Stability and Reactivity). Keep container tightly closed when not in use. Inspect all
incoming containers before storage, to ensure containers are properly labeled and not damaged.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in Section
6 (Accidental Release Measures). Make certain that application equipment is locked and tagged-out safely if necessary. Collect all
rinsates and dispose of according to applicable U.S. Federal, State, or local procedures or appropriate Canadian standards.

8. EXPOSURE CONTROLS - PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained below the
limits provided in Section 2 (Composition and Information on Ingredients). Ensure adequate ventilation is available when sanding.
Ensure eyewash/safety shower stations are available near areas where this product is used.
RESPIRATORY PROTECTION: None needed under normal conditions of use. Use a dust respirator for large jobs if dusts cannot
otherwise be eliminated.
EYE PROTECTION: For consumer use, wearing eye protection (such as splash goggles) is advisable. However, for specific industrial
applications, enhanced eye protection may be necessary. Use approved safety goggles or safety glasses, as described in OSHA 29 CFR
1910.133. If necessary, refer to U.S. OSHA 29 CFR 1910.133, or appropriate Canadian standards.
HAND PROTECTION: For consumer use, wearing protective gloves is recommended. For specific industrial applications, wear
chemical impervious gloves (e.g., Neoprene, nitrile). If necessary, refer to U.S. OSHA 29 CFR 1910.138 or the appropriate standards of
Canada.
BODY PROTECTION: For consumer use, no specific body protection is normally needed. For specific industrial applications, body
protection is not routinely necessary, but may be warranted if excessive dusts may be generated. Use body protection appropriate for
task (e.g., Tyvek suit, rubber apron). If a hazard of injury to the feet exists due to falling objects, rolling objects, where objects may
pierce the soles of the feet or where employee s feet may be exposed to electrical hazards, use foot protection, as described in U.S. OSHA
29 CFR 1910.136.
HMIS PERSONAL PROTECTIVE EQUIPMENT RATING: Industrial Use situations: (A) Eye Protection.

9. PHYSICAL and CHEMICAL PROPERTIES
RELATIVE VAPOR DENSITY (air = 1): Heavier than air

EVAPORATION RATE (BuAc =1): Faster than n-butyl acetate

SPECIFIC GRAVITY: 0.9

MELTING POINT: 32oF (0oC)

SOLUBILITY IN WATER: Soluble in water

BOILING POINT: -13 oF (10.5 oC)

VAPOR PRESSURE, mm Hg @ 24°C:

pH: NA

ODOR THRESHOLD: NA
COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): NA
V.O.C.: < 60%

MIR: < 1.20

APPEARANCE, ODOR AND COLOR: This product is a white colored aerosol with a slight ethereal odor
HOW TO DETECT THIS SUBSTANCE (warning properties): The appearance and odor of this product may act as warning properties
in the event of an accidental release.

10. STABILITY and REACTIVITY
STABILITY: Stable under normal circumstances of use and handling.
DECOMPOSITION PRODUCTS: Thermal decomposition of this product may generate dusts, irritating fumes, and toxic gases (e.g.,
carbon monoxide, carbon dioxide).
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: This product is not compatible strong oxidizing agents.
HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06

page 4 of 9

HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Avoid contact with incompatible chemicals and high temperatures.

PART IV

Is there any other useful information about this material?

11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: The following toxicology information is available for components greater than 1% in concentration.
The following data are available for Dimethyl ether:
Inhalation-Rat LC50: 308 g/m3
Inhalation-Mouse LC50: 386,000 ppm/30M
Inhalation-Rat TCLo: 2 pph/6H/30W-I
The following data are available for Isopropyl alcohol:
Skin-Rabbit, adult 500 mg Mild irritation effects
Eye effects-Rabbit, adult 16 mg
Eye effects-Rabbit, adult 10 mg Moderate irritation effects
Cytogenetic Analysis System-Saccharomyces cerevisiae 200 mmol/tube
Cytogenetic Analysis System-Rat-Inhalation 1030 mg/m3/16W-I
Oral-Rat TDLo:6480 mg/kg (male 26W pre):Reproductive effects
Inhalation-Rat TCLo:10,000 ppm/7H (female 1-19D post):Teratogenic effects
Oral-Man TDLo:14,432 mg/kg: Central nervous system effects, Cardiovascular effects, Pulmonary system effects
Oral-Human TDLo:223 mg/kg: Central nervous system effects, Cardiovascular effects
Oral-Man LDLo:5272 mg/kg
AJCPAI 38,144,62
Oral-Human LDLo:3570 mg/kg: Central nervous system effects, Pulmonary system effects, Gastrointestinal tract effects
Unreported-Man LDLo:2770 mg/kg
Oral-Rat LD50:5045 mg/kg
Inhalation-Rat LCLo:16,000 ppm/4H
Intraperitoneal-Rat LD50:2735 mg/kg
Intravenous-Rat LD50:1099 mg/kg
Oral-Mouse LD50:3600 mg/kg
Inhalation-Mouse LCLo:12,800 ppm/3H
Intraperitoneal-Mouse LD50:4477 mg/kg
Subcutaneous-Mouse LDLo:6000 mg/kg
Intravenous-Mouse LD50:1509 mg/kg
Oral-Dog, adult LD50:4797 mg/kg
Intravenous-Dog, adult LDLo:5120 mg/kg
Intravenous-Cat, adult LDLo:1963 mg/kg
Oral-Rabbit, adult LD50:6410 mg/kg
Skin-Rabbit, adult LD50:12,800 mg/kg
The following data are available for Talc:
Skin-Human 300 mg/3D-I Mild irritation effects
Inhalation-Rat TCLo:11 mg/m3/1Y-I:Equivocal tumorigenic agent
The following data are available for Calcium Carbonate, Vinyl Acrylic Copolymer, and Silica Quartz:
None available
SUSPECTED CANCER AGENT: The following table summarizes the carcinogenicity listing for the components of this product.
NO indicates that the substance is not considered to be, or suspected to be, a carcinogen by the listed agency.
IARC

NTP

ACGIH

NIOSH

OSHA

CA PROP 65

Calcium Carbonate

CHEMICAL

NO

NO

NO

NO

NO

NO

Dimethyl Ether

NO

NO

NO

NO

NO

NO

3

NO

A4

NO

NO

NO
NO

Talc
Vinyl Acrylic Copolymer

NO

NO

NO

NO

NO

Isopropyl alcohol

3

NO

NO

NO

NO

NO

Silica Quartz

1

Known

Ca

NO

A2

YES

Note: See section 16 for definition of ratings

HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06

page 5 of 9

11. TOXICOLOGICAL INFORMATION - Continued
IRRITANCY OF PRODUCT: This product can be severely irritating to contaminated tissue.
SENSITIZATION TO THE PRODUCT: The components of this product are not reported to be sensitizers.
TOXICOLOGICAL SYNERGISTIC PRODUCTS: None known.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product and its components
on the human reproductive system.
Mutagenicity: This product is not expected to produce mutagenic effects in humans when used as instructed.
Embryotoxicity: This product is not expected to produce embryotoxic effects in humans when used as instructed.
Teratogenicity: This product is not reported to cause teratogenic effects in humans when used as instructed.
Reproductive Toxicity: This product is not reported to cause reproductive effects in humans when used as instructed.
A mutagen is a chemical that causes permanent changes to genetic material (DNA) such that the changes will propagate through
generational lines. An embryotoxin is a chemical that causes damage to a developing embryo (i.e. within the first eight weeks of
pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical that causes damage to a
developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is any substance that interferes in
any way with the reproductive process.
BIOLOGICAL EXPOSURES INDICES (BEIs): There is no BEI currently established for this substance.

12. ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ENVIRONMENTAL STABILITY: The following environmental data is available for components of this product: The mineral
components of this product are stable in the environment.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: This product is not anticipated to cause significant effects on terrestrial plants or
animals if released in small, consumer-sized volumes. This product may be harmful to animal life if large volumes of it are released into
the environment. Refer to Section 11 (Toxicological Information) for specific animal data.
EFFECT OF CHEMICAL ON AQUATIC LIFE: This product is not anticipated to cause significant effects on aquatic plants or animals
if released in small, consumer-sized volumes. This product may be harmful to contaminated aquatic life (especially if large volumes of it
are released into an aquatic environment). The following aquatic toxicity data is available for components of this product: NONE

13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Consumer Waste: Dispose of according to pertinent state and local household waste and
requirements. Industrial Use: Waste disposal must be in accordance with appropriate U.S. Federal, State, and local regulations or with
regulations of Canada.
EPA WASTE NUMBER: Not applicable to wastes consisting only of this product; however, the specific RCRA codes depend on the
exact nature of the discarded material.

14. TRANSPORTATION INFORMATION
THIS PRODUCT IS HAZARDOUS PER 49 CFR 172.101, THE U.S. DEPARTMENT OF TRANSPORTATION.
PROPER SHIPPING NAME:
Aerosols
HAZARD CLASS NUMBER and DESCRIPTION: 2.1(Flammable Gas)
UN IDENTIFICATION NUMBER:
UN1950
DOT LABEL(S) REQUIRED:
Flammable Gas
PACKAGING GROUP:
N/A
NORTH AMERICAN RESPONSE GUIDEBOOK NUMBER (2000): 126
MARINE POLLUTANT: No component is designated as a DOT Marine Pollutant.
Consumer commodities (per 173.306 (h)): A limited quantity that conforms to the provisions of paragraph (a) (1), (a) (3), or (b) of
this section and is a "consumer commodity" (per 49 CFR 171.8) can be renamed Consumer commodity and reclassified as an ORMD Material. Each package may not exceed 30 kg (66 pounds)gross weight. Reference 173.306 (a) (3): Limited quantities of
compressed gases may be shipped when in a metal container for the sole purpose of expelling a nonpoisonous liquid, paste, or powder.

14. TRANSPORTATION INFORMATION - Continued
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS:
description applies to this product under the regulations of Transport Canada.
HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06

page 6 of 9

The above-listed DOT basic

15. REGULATORY INFORMATION
ADDITIONAL U.S. REGULATIONS:
EPA REPORTING REQUIREMENTS: The following reporting requirements are applicable to components of this product:
CHEMICAL

SECTION 302

SECTION 304

SECTION 313

(40 CFR 355, Appendix
A)

(40 CFR Table 302.4)

(40 CFR 372.65)

Calcium Carbonate

NO

NO

NO

Dimethyl Ether

NO

NO

NO

Talc

NO
NO

NO
NO

NO
NO

NO
NO

NO
NO

NO
NO

Isopropyl alcohol
Vinyl Acrylic Copolymer
Silica Quartz

U.S. SARA SECTION 311/312 FOR PRODUCT: Acute health effects; chronic health effects.
U.S. TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
OTHER U.S. FEDERAL REGULATIONS: Not applicable.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): WARNING: This product
contains a chemical known to the State of California to cause cancer.
ANSI LABELING (Z129.1):
DANGER! HARMFUL OR FATAL IF SWALLOWED. EXTREMELY FLAMMABLE LIQUID AND VAPOR.
VAPOR HARMFUL. CONTENTS UNDER PRESSURE. MAY EXPLODE IF HEATED. AFFECTS CENTRAL NERVOUS
SYSTEM. CAUSES SEVERE EYE IRRITATION. CAUSES IRRITATION TO SKIN AND RESPIRATORY TRACT. MAY BE
HARMFUL IF ABSORBED THROUGH SKIN. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND
INHALING THE CONTENTS MAY BE HARMFUL OR FATAL.
ANSI LABEL PRECAUTIONS:
Keep away from heat, sparks and flame. Do not expose to heat or store at temperatures above 120oF. Close container after use. Avoid
breathing dust, vapors or mist. Do not take internally. Avoid contact with skin and clothing. Wash thoroughly after handling. Avoid
contact with eyes.
ENVIRONMENTAL HAZARDS: Do not discharge effluent containing this product into streams, ponds, estuaries, oceans or other
waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the
permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems
without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office
of the EPA.

15. REGULATORY INFORMATION - Continued
ADDITIONAL CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are listed on the DSL Inventory.
CANADIAN WHMIS SYMBOLS: A - Compressed gas
B1 - Flammable and combustible material - Flammable gas
B2 - Flammable and combustible material - Flammable liquid
HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06

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D2A - Poisonous and infectious material - Other effects - Very toxic
D2B - Poisonous and infectious material - Other effects - Toxic

This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the
MSDS contains all the information required by the CPR.

16. OTHER INFORMATION
PREPARED BY:

DATE OF PRINTING

John R. Kordosh
Homax Products, Inc.
4505 E. Industrial St., Ste. 1B
Simi Valley, CA 93063
(805) 581-3555
December 5, 2006

HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06

page 8 of 9

DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these, which are commonly used, include the following:
CAS #: This is the Chemical Abstract Service Number that uniquely identifies each compound.
ACGIH - American Conference of Governmental Industrial Hygienists, a
professional association which establishes exposure limits.
TLV - Threshold Limit Value - an airborne concentration of a substance that
represents conditions under which it is generally believed that nearly all workers
may be repeatedly exposed without adverse effect. The duration must be
considered, including the 8-hour Time Weighted Average (TWA), the 15minute Short Term Exposure Limit, and the instantaneous Ceiling Level (C).
Skin absorption effects must also be considered.
OSHA - U.S. Occupational Safety and Health Administration.
PEL - Permissible Exposure Limit - This exposure value means exactly the
same as a TLV, except that it is enforceable by OSHA. The OSHA Permissible
Exposure Limits are based in the 1989 PELs and the June, 1993 Air
Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 40191). Both
the current PELs and the vacated PELs are indicated. The phrase, Vacated
1989 PEL, is placed next to the PEL that was vacated by Court Order.
IDLH - Immediately Dangerous to Life and Health - This level represents a
concentration from which one can escape within 30-minutes without suffering
escape-preventing or permanent injury. The DFG - MAK is the Republic of
Germany s Maximum Exposure Level, similar to the U.S. PEL. NIOSH is the
National Institute of Occupational Safety and Health, which is the research arm
of the U.S. Occupational Safety and Health Administration (OSHA). NIOSH
issues exposure guidelines called Recommended Exposure Levels (RELs).
When no exposure guidelines are established, an entry of NE is made for
reference.
HAZARD RATINGS:
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM:
Health
Hazard: 0 (minimal acute or chronic exposure hazard); 1 (slight acute or chronic
exposure hazard); 2 (moderate acute or significant chronic exposure hazard); 3
(severe acute exposure hazard; onetime overexposure can cause permanent
injury and may be fatal); 4 (extreme acute exposure hazard; onetime
overexposure can be fatal). Flammability Hazard: 0 (minimal hazard); 1
(materials that require substantial pre-heating before burning); 2 (combustible
liquid or solids; liquids with a flash point of 38-93 C [100-200 F]); 3 (Class IB
and IC flammable liquids with flash points below 38 C [100 F]); 4 (Class IA
flammable liquids with flash points below 23 C [73 F] and boiling points below
38 C [100 F]. Reactivity Hazard: 0 (normally stable); 1 (material that can
become unstable at elevated temperatures or which can react slightly with
water); 2 (materials that are unstable but do not detonate or which can react
violently with water); 3 (materials that can detonate when initiated or which can
react explosively with water); 4 (materials that can detonate at normal
temperatures or pressures).
NATIONAL FIRE PROTECTION ASSOCIATION: Health Hazard: 0
(material that on exposure under fire conditions would offer no hazard beyond
that of ordinary combustible materials); 1 (materials that on exposure under fire
conditions could cause irritation or minor residual injury); 2 (materials that on
intense or continued exposure under fire conditions could cause temporary
incapacitation or possible residual injury); 3 (materials that can on short
exposure could cause serious temporary or residual injury); 4 (materials that
under very short exposure could cause death or major residual injury).
Flammability Hazard and Reactivity Hazard: Refer to definitions for
Hazardous Materials Identification System .

FLAMMABILITY LIMITS IN AIR:
Much of the information related to fire and explosion is derived from the
National Fire Protection Association (NFPA). Flash Point - Minimum
temperature at which a liquid gives off sufficient vapors to form an ignitable
mixture with air. Autoignition Temperature: The minimum temperature
required to initiate combustion in air with no other source of ignition. LEL - the
lowest percent of vapor in air, by volume, that will explode or ignite in the
presence of an ignition source. UEL - the highest percent of vapor in air, by
volume, that will explode or ignite in the presence of an ignition source.
TOXICOLOGICAL INFORMATION:
Possible health hazards as derived from human data, animal studies, or from the
results of studies with similar compounds are presented. Definitions of some
terms used in this section are: LD50 - Lethal Dose (solids & liquids) which kills
50% of the exposed animals; LC50 - Lethal Concentration (gases) which kills
50% of the exposed animals; ppm concentration expressed in parts of material
per million parts of air or water; mg/m3 concentration expressed in weight of
substance per volume of air; mg/kg quantity of material, by weight,
administered to a test subject, based on their body weight in kg. Other measures
of toxicity include TDLo, the lowest dose to cause a symptom and TCLo the
lowest concentration to cause a symptom; TDo, LDLo, LDo, TC, TCo, LCLo,
and LCo, the lowest dose (or concentration) to cause lethal or toxic effects. BEI
- Biological Exposure Indices, represent the levels of determinants which are
most likely to be observed in specimens collected from a healthy worker who
has been exposed to chemicals to the same extent as a worker with inhalation
exposure to the TLV. Ecological Information: EC is the effect concentration in
water.
Data from several sources are used to evaluate the cancer-causing potential of
the material. The sources and ratings are: IARC - the International Agency for
Research on Cancer; 1 = Carcinogenic to humans, 2A, 2B = Probably
carcinogenic to humans, 3 = Unclassifiable as to carcinogenicity in humans, and
4 = Probably not carcinogenic to humans. NTP - the National Toxicology
Program; K =Known to be a human carcinogen, and R = Reasonably anticipated
to be a human carcinogen. RTECS - the Registry of Toxic Effects of Chemical
Substances. OSHA - Occupational Safety and Health Administration and
CAL/OSHA - California s subunit of the Occupational Safety and Health
Administration; Ca = Carcinogen defined with no further categorization.
ACGIH American Conference of Governmental Industrial Hygienists; A1 =
Confirmed human carcinogen, A2 = Suspected human carcinogen, A3 =
Confirmed animal carcinogen with unknown relevance to humans, A4 = Not
classifiable as a human carcinogen, and A5 = Not suspected as a human
carcinogen. NIOSH
U.S. National Institute for Occupational Safety and
Health; Ca = Potential occupational carcinogen, with no further categorization.
EPA U.S. Environmental Protection; A = Human carcinogen, B = Probable
human carcinogen, C = Possible human carcinogen, D = Not classifiable as to
human carcinogenicity, E = Evidence of Non-carcinogenicity for humans, K =
Known human carcinogen, L = Likely to produce cancer in humans, CBD =
Cannot be determined, NL = Not likely to be carcinogenic in humans, and I =
Data are inadequate for an assessment of human carcinogenic potential.
REGULATORY INFORMATION:
This section explains the impact of various laws and regulations on the material.
EPA is the U.S. Environmental Protection Agency. WHMIS is the Canadian
Workplace Hazardous Materials Information System. DOT and TC are the U.S.
Department of Transportation and the Transport Canada, respectively.
Superfund Amendments and Reauthorization Act (SARA); the Canadian
Domestic/Non-Domestic Substances List (DSL/NDSL); the U.S. Toxic
Substance Control Act (TSCA); Marine Pollutant status according to the DOT;
the Comprehensive Environmental Response, Compensation, and Liability Act
(CERCLA or Superfund); and various state regulations. This section also
includes information on the precautionary warnings that appear on a material s
industrial package label.

HOMAX EASY TEXTURE ORANGEPEEL & SPLATTER Product ID#:4091, 4092, 4191, Revision Date: 11/16/06

page 9 of 9

This document was created with Win2PDF available at http://www.daneprairie.com.
The unregistered version of Win2PDF is for evaluation or non-commercial use only.

1

HAZARDOUS MATERIAL INFORMATION
SYSTEM

PRODUCT TRADE NAME:
HOMAX PRODUCTS, INC.

ACOUSTIC TEXTURE II
ITEM #4070

(HAZARD RATING: 0=LEAST, 1=SLIGHT, 2=MODERATE, 3=HIGH,
4=EXTREME) (I=SAFETY GLASSES, GLOVES, & VAPOR RESPIRATOR)

HEALTH

1

FLAMMABILITY

0

REACTIVITY

0

PROTECTIVE EQUIPMENT

J

SECTION I - MANUFACTURER IDENTIFICATION

MANUFACTURER'S NAME:
HOMAX PRODUCTS, INC.
468 W. HORTON ROAD
BELLINGHAM WA 98226

24 HOUR EMERGENCY PHONE NUMBER:
CHEMTREC 1-800-424-9300
NFORMATION PHONE NUMBER:

1-800-729-9029

DATE OF PREPARATION:

5/27/03

SECTION II A - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION
CAS NUMBER DESCRIPTION
PEL
TLV
07727-37-9
14808-60-7

NITROGEN
SILICA, CRYSTALLINE-QUARTZ

%
1

0.1 MG/M3

0.1 MG/M2

TRACE

TRACE QUANTITIES LESS THAN 1.0% AND GREATER THAN 0.009%
PEL REPRESENTS LOWERED 1989 LIMITS AND MAY NOT BE ENFORCEABLE BY FEDERAL OSHA.

SECTION IIB - OTHER REGULATORY INFORMATION
CAS NUMBER
DESCRIPTION
CARCINOGEN SARA TITLE III CALIFORNIA
07727-37-9
NITROGEN
NTP
IARC OSHA 302 313 P65 I II
14808-60-7
SILICA CRYSTALLINE-QUARTZ
X
X

2

SECTION III- PHYSICAL/CHEMICAL CHARACTERISTICS
APPEARANCE AND ODOR:
VISCIOUS LUMPY LIQUID
BOILING POINT:
0 TO 0 DEG. F
WATER SOLUBILITY:
APPRECIABLE
VAPOR DENSITY:
HEAVIER THAN AIR
EVAPORATION RATE:
SLOWER THAN N-BUTYL ACETATE= MEDIAN
CALCULATED V.O.C. .08 LB/GL (10GR/LT)
WT/GAL: 9.83 WITH PROP .89
SECTION IV-FIRE AND EXPLOSION DATA
FLASH POINT (METHOD USED):
N/A
UNIFORM FIRE CODE STANDARD 88-1
LEVEL ONE AEROSOL
BULK PRODUCT FLASH POINT:
N/A
BULK PROPELLANT FLASH POINT:
N/A
PACKAGED PRODUCT FLAME EXTENSION: 00
EXTINGUISHING MEDIA:
USE FOAM, CO2, DRY CHEMICAL, WATER FOG
SPECIAL FIREFIGHTING PROCEDURES:
EVACUATE ALL UNNECESSARY PERSONNEL. USE FULL PROTECTIVE EQUIPMENT, INCLUDING SELFCONTAINED BREATHING APPARATUS. USE WATER SPRAY, PREFERABLY FOG, TO COOL CLOSED
CONTAINERS TO PREVENT PRESSURE BUILD UP AND POSSIBLE EXPLOSION. DO NOT ALLOW PRODUCT
OR RUNOFF FROM FIRE CONTROL TO ENTER STORM OR SANITARY SEWERS, LAKES, RIVERS, STEAMS,
OR WATERWAYS.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CONTENTS UNDER PRESSURE. EXPOSURE TO HEAT OR PROLONGED EXPOSURE TO SUN MAY CAUSE
BURSTING.

SECTION V – REACTIVITY DATA
STABILITY: MATERIAL IS STABLE
INCOMPATIBILTY (MATERIALS TO AVOID): STRONG OXIDIZING AGENTS, ACIDS, AMMONIA.
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE, NITROGEN OXIDES.
CONDITIONS TO AVOID: HIGH TEMPERATURE AND HUMIDITY, IGNITION SOURCE, VAPOR BUILD UP.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.

SECTION VI – HEATLTH HAZARD DATA
ROUTES OF ENTRY: INHALATION: YES

SKIN: YES

ACUTE EFFECTS FROM SHORT TERM EXPOSURE:
INHALATION: DUST FROM PARTICLES CAUSE IRRITATION TO NOSE, THROAT AND LUNGS (POSSIBLE BURNING,
STINGING, COUGHING)
EYES:
NONE KNOWN
SKIN:
NONE KNOWN
SKIN ABSORPTION: NONE KNOWN
CHRONIC EFFECTS FROM LONG TERM /REPEATED EXPOSURE:
LONG TERM OR REPEATED OVEREXPOSURE, WITHOUT PROPER VENTILATION OR PERSONAL
PROTECTION, MAY CAUSE DAMAGE TO LIVER.
OTHER:
THIS PRODUCT CONTAINS A FORM OF CRYSTALLINE SILICA. LONG TERM EXPOSURE TO HIGH LEVELS
OF CHRYSTALLINE SILICA DUSTS MAY RESULT IN SILICOSIS, A DISABLING LUNG DISEASE. ALWAYS
WEAR APPROPRIATE RESPIRATORY PROTECTION WHEN EXPOSED TO SANDING OR GRINDING DUSTS.
CARCINOGEN DATA:
CRYSTALLINE SILICAS ARE CLASSIFIED BY IARC AS POTENTIAL HUMAN CARCINOGENS, INHALATION OF
CRYSTALLINE DUSTS MAY CAUSE LUNG TUMORS. RISK OF CANCER DEPENDS ON LEVEL AND DURATION

3
OF EXPOSURE. THE FOLLOWING STATEMENT IS REQUIRED BY CALIFORNIA PROPOSITION 65
(SAFE DRINKING WATER AND TOXIC REFORM ACT OF 1986)
WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:
RESPIRATORY TRACT IRRITATION, NAUSEA, SKIN AND EYE DISORDERS; SENSITIZATION TO CHEMICAL
SUBSTANCES.
EMERGENCY AND FIRST AID PROCEDURES:
SWALLOWING: IN CASE OF ACCIDENTAL INGESTION, CALL POISON CENTER, EMERGENCY ROOM OR PHYSICIAN
IMMEDIATELY.
INHALATION: IF AFFECTED BY BREATHING ODORS OR VAPORS, REMOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS PERSISTS.
EYE: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES, WHILE LIFTING THE UPPER AND LOWER
EYELIDS. GET MEDICAL ATTENTION.
SKIN: WASH WITH SOAP AND WATER. REMOVE AND CLEAN CONTAMINATED CLOTHING AND SHOES. GET
MEDICAL ATTENTION IF IRRITATION PERSISTS.
OTHER: N/A
SECTION VIII – PERSONAL PROTECTION
RESPIRATORY PROTECTION:
IF AFFECTED BY BREATHING VAPORS OR ODORS, WEAR A PROPERLY FITTED RESPIRATOR
(NIOSH/MSHA TC23C OR EQUILVALENT) DURING USE. IF PRODUCT GIVES OFF SPRAY MIST, AVOID
BREATHING BY WEARING RESPIRATOR PREFILTER OR PARTICLE MASK.
VENTILATION:
OPEN DOORS AND WINDOWS TO PROVIDE FRESH VENTILATION. IN WORK AND SURROUNDING AREAS
DURING AND AFTER APPLICATION UNTIL ALL VAPOR (FUMES) ARE GONE.
HAND PROTECTION
WEAR GLOVES TO AVOID SKIN CONTACT.
EYE PROTECTION:
SAFETY GLASSES OR GOGGLES TO PROTECT EYES FROM SPLASH AND SPRAY MISTS.
NOTE: CONTACT LENS MAY CONTRIBUTE TO THE SEVERITY OF AND EYE INJURY AND SHOULD NOT BE
WORN WHEN WORKING WITH CHEMICALS.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT:
EYES - WASH FOUNTAIN AND SAFETY SHOWER.
REMOVE AND WASH CONTAMINATED CLOTHING BEFORE RE-USE.
WORK/HYGIENIC PRACTICES:
WASH HANDS AFTER USING AND BEFORE EATING, DRINKING OR USING TOBACCO PRODUCTS.
THROUGHLY CLEAN CONTAMINATED CLOTHING AND SHOES BEFORE REUSE.
SPILL OR LEAKAGE PROCEDURES:
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
ELIMINATE IGNITION SOURCES AND VENTILATE AREA. EVACUATE UNNECESSARY PERSONNEL. WEAR
PROTECTIVE EQUIPMENT. DIKE AND CONAIN SPILL WITH INERT MATERIAL. TRANSFER LIQUID TO
CONTAINERS FOR DISPOSAL OR RECOVERY. PREVENT MATERIAL FROM ENTERING STORM OR
SANITARY SEWERS AND OPEN BODIES OF WATER.
WASTE DISPOSAL:
WASTE MATERIAL AND EMPTY CONTAINERS MUST BE DISPOSED OF IN ACCORDANCE WITH ALL LOCAL,
STATE, AND FEDERAL ENVIRONMENTAL CONTROL REGULATIONS. USE ONLY APPROVED WASTE
MANAGEMENT FACILITIES.
SPECIAL PRECAUTIONS:
HANDLING PRECAUTIONS:
USE PROPER METHODS OF VENTILATION TO PREVENT VAPOR BUILD-UP. AVOID SPRAYING HOT
SURFACES. DO NOT HEAT, PUNCTURE OR INCINERATE CONTAINERS. CONTENTS ARE UNDER
PRESSURE AND MAY CONTAIN VAPORS, EVEN WHEN EMPTY. DO NOT REMOVE OR DEFACE LABEL.

4

SHIPPING AND STORAGE PRECAUTIONS:
CONTENTS UNDER PRESSURE. DO NOT STORE ABOVE 120 DEGREES F OR PERMIT PROLONGED
EXPOSURE TO SUNLIGHT. PROTECT CONTAINERS FROM DAMAGE. STORE IN BUILDINGS OR AREAS
DESIGNED AND PROTECTED FROM STORAGE OF AEROSOLS. KEEP OUT OF REACH CHILDREN.

SECTION IX - DISCLAIMER
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE, OBTAINED FROM
SOURCES BELIEVED BY HOMAX PRODUCTS, INC. TO BE ACCURATE. SINCE THE CONDITIONS AND METHODS OF
USE OF OUR PRODUCTS ARE BEYOND OUR CONTROL, WE DISCLAIM ANY AND ALL LIABILITY ARISING OUT OF
THE IMPROPER USE OF THESE PRODUCTS OR THE INFORMATION PROVIDED HEREWITH.
PROPER SHIPPING NAME: CONSUMER COMMODITY
HAZARD CLASS NUMBER: ORM-D

3202
01 00

MATERIAL SAFETY DATA SHEET

===========================================================================
Section 1 −− PRODUCT AND COMPANY IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT NUMBER
HMIS CODES
Health
2
3202
Flammability
4
Reactivity
0
PRODUCT NAME
KRYLON* Appliance Epoxy Paint, Almond
MANUFACTURER’S NAME
EMERGENCY TELEPHONE NO.
THE SHERWIN−WILLIAMS COMPANY
(216) 566−2917
KRYLON Products Group
Cleveland, OH 44115
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
24−JAN−06
(800) 832−2541
===========================================================================
Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
14
74−98−6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
13
106−97−8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
19
108−88−3 Toluene
ACGIH TLV
50 ppm (Skin)
22 mm
OSHA PEL
100 ppm (Skin)
OSHA PEL
150 ppm (Skin) STEL
23
67−64−1 Acetone
ACGIH TLV
500 ppm
180 mm
ACGIH TLV
750 ppm STEL
OSHA PEL
1000 ppm
12
123−86−4 n−Butyl Acetate
ACGIH TLV
150 ppm
10 mm
ACGIH TLV
200 ppm STEL
OSHA PEL
150 ppm
OSHA PEL
200 ppm STEL
8
13463−67−7 Titanium Dioxide
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction
===========================================================================
Section 3 −− HAZARDS IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.

Continued on page 2

3202
page 2
===========================================================================
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
===========================================================================
Section 4 −− FIRST AID MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
EYES:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re−use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 −− FIRE FIGHTING MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
FLASH POINT
LEL
UEL
Propellant < 0 F
1.0
12.8
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self−contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build−up and possible autoignition or explosion when exposed to
extreme heat.
===========================================================================
Section 6 −− ACCIDENTAL RELEASE MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.

Continued on page 3

3202
page 3
===========================================================================
Section 7 −− HANDLING AND STORAGE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STORAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated − Do not
smoke − Extinguish all flames, pilot lights, and heaters − Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
===========================================================================
Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
Removal of old paint by sanding, scraping or other means may generate
dust or fumes that contain lead. Exposure to lead dust or fumes may cause
brain damage or other adverse health effects, especially in children or
pregnant women. Controlling exposure to lead or other hazardous substances
requires the use of proper protective equipment, such as a properly fitted
respirator (NIOSH approved) and proper containment and cleanup. For more
information, call the National Lead Information Center at 1−800−424−LEAD
(in US) or contact your local health authority.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.

Continued on page 4

3202
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===========================================================================
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
===========================================================================
Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT WEIGHT
6.54 lb/gal
783 g/l
SPECIFIC GRAVITY
0.79
BOILING POINT
<0 − 264 F
<−18 − 128 C
MELTING POINT
Not Available
VOLATILE VOLUME
90 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical)
Volatile Weight 57.89 % Less Water and Federally Exempt Solvents
===========================================================================
Section 10 −− STABILITY AND REACTIVITY
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STABILITY −− Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
===========================================================================
Section 11 −− TOXICOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, blood forming, cardiovascular and
reproductive systems.
Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung
cancer, however, such exposure levels are not attainable in the workplace.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
TOXICOLOGY DATA

Continued on page 5

3202
page 5
===========================================================================
CAS No.
Ingredient Name
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
74−98−6
Propane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
106−97−8
Butane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
108−88−3
Toluene
LC50
RAT
4HR
4000
ppm
LD50
RAT
5000
mg/kg
67−64−1
Acetone
LC50
RAT
4HR
Not Available
LD50
RAT
5800
mg/kg
123−86−4
n−Butyl Acetate
LC50
RAT
4HR
2000
ppm
LD50
RAT
13100
mg/kg
13463−67−7
Titanium Dioxide
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
===========================================================================
Section 12 −− ECOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ECOTOXICOLOGICAL INFORMATION
No data available.
===========================================================================
Section 13 −− DISPOSAL CONSIDERATIONS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.
===========================================================================
Section 14 −− TRANSPORT INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
No data available.
===========================================================================
Section 15 −− REGULATORY INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
108−88−3 Toluene
19
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.

Continued on page 6

3202
page 6
===========================================================================
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
===========================================================================
Section 16 −− OTHER INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

Common Name: KRYLON APPLIANCE EPOXY PAINT, WHITE
Manufacturer: SHERWIN-WILLIAMS
MSDS Revision Date: 1/6/2007

Grainger Item Number(s): 2X986, 4X590
Manufacturer Model
Number(s):

MSDS Table of Contents
Click the desired link below to jump directly to that section in the MSDS.
SECTION
SECTION
SECTION
SECTION
SECTION
SECTION
SECTION
SECTION
SECTION
SECTION
SECTION
SECTION
SECTION
SECTION
SECTION
SECTION

1 - PRODUCT AND COMPANY IDENTIFICATION
2 - COMPOSITION/INFORMATION ON INGREDIENTS
3 - HAZARDS IDENTIFICATION
4 - FIRST AID MEASURES
5 - FIRE FIGHTING MEASURES
6 - ACCIDENTAL RELEASE MEASURES
7 - HANDLING AND STORAGE
8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
9 - PHYSICAL AND CHEMICAL PROPERTIES
10 - STABILITY AND REACTIVITY
11 - TOXICOLOGICAL INFORMATION
12 - ECOLOGICAL INFORMATION
13 - DISPOSAL CONSIDERATIONS
14 - TRANSPORT INFORMATION
15 - REGULATORY INFORMATION
16 - OTHER INFORMATION

MATERIAL, SAFETY DATA SHEET
3201
01 00

SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NUMBER: 3201
PRODUCT NAME: KRYLON* APPLIANCE EPOXY PAINT, WHITE

HMIS CODES:
HEALTH
2
FLAMMABILITY 3
REACTIVITY
0
MANUFACTURER'S NAME:
THE SHERWIN-WILLIAMS COMPANY
KRYLON PRODUCTS GROUP
CLEVELAND, OH 44115
EMERGENCY TELEPHONE NO.: (216) 566-2917
INFORMATION TELEPHONE NO.: (800) 832-2541
DATE OF PREPARATION: 06-JAN-07

SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS

% BY WT

CAS NO.

INGREDIENT

UNITS

VAPOR
PRESSURE

14

74-98-6

PROPANE
ACGIH TLV: 2500 PPM
OSHA PEL: 1000 PPM

760 MM

13

106-97-8

BUTANE
ACGIH TLV: 800 PPM
OSHA PEL: 800 PPM

760 MM

18

108-88-3

TOLUENE
ACGIH TLV: 50 PPM (SKIN)
OSHA PEL: 100 PPM (SKIN)
OSHA PEL: 150 PPM (SKIN) STEL

22 MM

23

67-64-1

ACETONE
ACGIH TLV: 500 PPM
ACGIH TLV: 750 PPM STEL
OSHA PEL: 1000 PPM

180 MM

12

123-86-4

n-BUTYL ACETATE
ACGIH TLV: 150
ACGIH TLV: 200
OSHA PEL: 150
OSHA PEL: 200

10 MM

7

13463-67-7

PPM
PPM STEL
PPM
PPM STEL

TITANIUM DIOXIDE
ACGIH TLV: 10 MG/M3 AS DUST
OSHA PEL: 10 MG/M3 TOTAL DUST
OSHA PEL: 5 MG/M3 RESPIRABLE FRACTION

SECTION 3 - HAZARDS IDENTIFICATION

ROUTES OF EXPOSURE:
INHALATION OF VAPOR OR SPRAY MIST.
EYE OR SKIN CONTACT WITH THE PRODUCT, VAPOR OR SPRAY MIST.
EFFECTS OF OVEREXPOSURE:
EYES: IRRITATION.
SKIN: PROLONGED OR REPEATED EXPOSURE MAY CAUSE IRRITATION.
INHALATION: IRRITATION OF THE UPPER RESPIRATORY SYSTEM.
MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME OVEREXPOSURE MAY RESULT IN
UNCONSCIOUSNESS AND POSSIBLY DEATH.
SIGNS AND SYMPTOMS OF OVEREXPOSURE:
HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF COORDINATION ARE INDICATIONS OF
EXCESSIVE EXPOSURE TO VAPORS OR SPRAY MISTS.
REDNESS AND ITCHING OR BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE
SKIN EXPOSURE.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: NONE GENERALLY RECOGNIZED.
CANCER INFORMATION:
FOR COMPLETE DISCUSSION OF TOXICOLOGY DATA REFER TO SECTION 11.

SECTION 4 - FIRST AID MEASURES

EYES:
FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES.
GET MEDICAL ATTENTION.
SKIN:
WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER.
REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE.
INHALATION:
IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING.
KEEP WARM AND QUIET.
INGESTION:
DO NOT INDUCE VOMITING.
GET MEDICAL ATTENTION IMMEDIATELY.

SECTION 5 - FIRE FIGHTING MEASURES

FLASH POINT: PROPELLANT <0 F

LEL: 1.0
UEL: 12.8
EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, FOAM
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.
APPLICATION TO HOT SURFACES REQUIRES SPECIAL PRECAUTIONS.
DURING EMERGENCY CONDITIONS OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY
CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. OBTAIN
MEDICAL ATTENTION.
SPECIAL FIRE FIGHTING PROCEDURES:
FULL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS
SHOULD BE USED.
WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE
PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE
BUILD-UP AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME
HEAT.

SECTION 6 - ACCIDENTAL RELEASE MEASURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
REMOVE ALL SOURCES OF IGNITION. VENTILATE THE AREA.
REMOVE WITH INERT ABSORBENT.

SECTION 7 - HANDLING AND STORAGE

STORAGE CATEGORY: NOT AVAILABLE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME. VAPORS WILL ACCUMULATE READILY
AND MAY IGNITE EXPLOSIVELY.
DURING USE AND UNTIL ALL VAPORS ARE GONE:
KEEP AREA VENTILATED - DO NOT SMOKE - EXTINGUISH ALL FLAMES, PILOT LIGHTS,
AND HEATERS - TURN OFF STOVES, ELECTRIC TOOLS AND APPLIANCES, AND ANY OTHER
SOURCES OF IGNITION.
CONSULT NFPA CODE. USE APPROVED BONDING AND GROUNDING PROCEDURES.
CONTENTS UNDER PRESSURE. DO NOT PUNCTURE, INCINERATE, OR EXPOSE TO
TEMPERATURE ABOVE 120F. HEAT FROM SUNLIGHT, RADIATORS, STOVES, HOT WATER,
AND OTHER HEAT SOURCES COULD CAUSE CONTAINER TO BURST. DO NOT TAKE
INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN.

SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION

PRECAUTIONS TO BE TAKEN IN USE:
USE ONLY WITH ADEQUATE VENTILATION.
AVOID CONTACT WITH SKIN AND EYES. AVOID BREATHING VAPOR AND SPRAY MIST.
WASH HANDS AFTER USING.
THIS COATING MAY CONTAIN MATERIALS CLASSIFIED AS NUISANCE PARTICULATES
(LISTED "AS DUST" IN SECTION 2) WHICH MAY BE PRESENT AT HAZARDOUS LEVELS
ONLY DURING SANDING OR ABRADING OF THE DRIED FILM. IF NO SPECIFIC DUSTS
ARE LISTED IN SECTION 2, THE APPLICABLE LIMITS FOR NUISANCE DUSTS ARE
ACGIH TLV 10 MG/M3 (TOTAL DUST), 3 MG/M3 (RESPIRABLE FRACTION)
OSHA PEL 15 MG/M3 (TOTAL DUST), 5 MG/M3 (RESPIRABLE FRACTION).
REMOVAL OF OLD PAINT BY SANDING, SCRAPING OR OTHER MEANS MAY GENERATE DUST
OR FUMES THAT CONTAIN LEAD. EXPOSURE TO LEAD DUST OR FUMES MAY CAUSE BRAIN
DAMAGE OR OTHER ADVERSE HEALTH EFFECTS, ESPECIALLY IN CHILDREN OR PREGNANT
WOMEN. CONTROLLING EXPOSURE TO LEAD OR OTHER HAZARDOUS SUBSTANCES REQUIRES
THE USE OF PROPER PROTECTIVE EQUIPMENT, SUCH AS A PROPERLY FITTED
RESPIRATOR (NIOSH APPROVED) AND PROPER CONTAINMENT AND CLEANUP. FOR MORE
INFORMATION, CALL THE NATIONAL LEAD INFORMATION CENTER AT 1-800-424-LEAD
(IN US) OR CONTACT YOUR LOCAL HEALTH AUTHORITY.
VENTILATION:
LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE EXPOSURE TO
MATERIALS IN SECTION 2 IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS.
REFER TO OSHA STANDARDS 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION:
IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW APPLICABLE LIMITS BY
VENTILATION, WEAR A PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR
APPROVED BY NIOSH/MSHA FOR PROTECTION AGAINST MATERIALS IN SECTION 2.
WHEN SANDING OR ABRADING THE DRIED FILM, WEAR A DUST/MIST RESPIRATOR
APPROVED BY NIOSH/MSHA FOR DUST WHICH MAY BE GENERATED FROM THIS PRODUCT,
UNDERLYING PAINT, OR THE ABRASIVE.
PROTECTIVE GLOVES:
NONE REQUIRED FOR NORMAL APPLICATION OF AEROSOL PRODUCTS WHERE MINIMAL
SKIN CONTACT IS EXPECTED. FOR LONG OR REPEATED CONTACT, WEAR CHEMICAL
RESISTANT GLOVES.
EYE PROTECTION: WEAR SAFETY SPECTACLES WITH UNPERFORATED SIDESHIELDS.
OTHER PRECAUTIONS:
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS
CAN BE HARMFUL OR FATAL.

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

PRODUCT WEIGHT:
6.55 LB/GAL
784 G/L
SPECIFIC GRAVITY: 0.79

BOILING POINT:
<0 - 264 F
<-18 - 128 C
MELTING POINT: NOT AVAILABLE
VOLATILE VOLUME: 89 %
EVAPORATION RATE: FASTER THAN ETHER
VAPOR DENSITY: HEAVIER THAN AIR
SOLUBILITY IN WATER: N.A.
pH: 7.0
VOLATILE ORGANIC COMPOUNDS (VOC THEORETICAL - AS PACKAGED):
VOLATILE WEIGHT 57.20% LESS WATER AND FEDERALLY EXEMPT SOLVENTS

SECTION 10 - STABILITY AND REACTIVITY

STABILITY: STABLE
CONDITIONS TO AVOID: NONE KNOWN.
INCOMPATIBILITY: NONE KNOWN.
HAZARDOUS DECOMPOSITION PRODUCTS:
BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR

SECTION 11 - TOXICOLOGICAL INFORMATION

CHRONIC HEALTH HAZARDS:
NO INGREDIENT IN THIS PRODUCT IS AN IARC, NTP OR OSHA LISTED CARCINOGEN.
PROLONGED OVEREXPOSURE TO SOLVENT INGREDIENTS IN SECTION 2 MAY CAUSE
ADVERSE EFFECTS TO THE LIVER, URINARY, BLOOD FORMING, CARDIOVASCULAR AND
REPRODUCTIVE SYSTEMS.
RATS EXPOSED TO TITANIUM DIOXIDE DUST AT 250 MG./M3 DEVELOPED LUNG CANCER,
HOWEVER, SUCH EXPOSURE LEVELS ARE NOT ATTAINABLE IN THE WORKPLACE.
REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS
WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE.
TOXICOLOGY DATA:
CAS NO.

INGREDIENT NAME

74-98-6

PROPANE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE

106-97-8

BUTANE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE

108-88-3

TOLUENE
LC50 RAT 4HR: 4000 PPM
LD50 RAT: 5000 MG/KG

67-64-1

ACETONE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: 5800 MG/KG

123-86-4

n-BUTYL ACETATE
LC50 RAT 4HR: 2000 PPM
LD50 RAT: 13100 MG/KG

13463-67-7

TITANIUM DIOXIDE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE

SECTION 12 - ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION: NO DATA AVAILABLE.

SECTION 13 - DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD:
WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS DEFINED UNDER THE RESOURCE
CONSERVATION AND RECOVERY ACT (RCRA) 40 CFR 261.
WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE THE APPLICABLE EPA
HAZARDOUS WASTE NUMBERS.
DO NOT INCINERATE. DEPRESSURIZE CONTAINER. DISPOSE OF IN ACCORDANCE WITH
FEDERAL, STATE/PROVINCIAL, AND LOCAL REGULATIONS REGARDING POLLUTION.

SECTION 14 - TRANSPORT INFORMATION

NO DATA AVAILABLE.

SECTION 15 - REGULATORY INFORMATION

SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION:
CAS NO.

CHEMICAL/COMPOUND

% BY WT

108-88-3

TOLUENE

18

% ELEMENT

CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
TSCA CERTIFICATION:
ALL CHEMICALS IN THIS PRODUCT ARE LISTED, OR ARE EXEMPT FROM LISTING, ON
THE TSCA INVENTORY.

SECTION 16 - OTHER INFORMATION

THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CANADIAN CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE MSDS CONTAINS
ALL OF THE INFORMATION REQUIRED BY THE CPR.
THE ABOVE INFORMATION PERTAINS TO THIS PRODUCT AS CURRENTLY FORMULATED, AND
IS BASED ON THE INFORMATION AVAILABLE AT THIS TIME. ADDITION OF REDUCERS OR
OTHER ADDITIVES TO THIS PRODUCT MAY SUBSTANTIALLY ALTER THE COMPOSITION AND
HAZARDS OF THE PRODUCT. SINCE CONDITIONS OF USE ARE OUTSIDE OUR CONTROL, WE
MAKE NO WARRANTIES, EXPRESS OR IMPLIED, AND ASSUME NO LIABILITY IN
CONNECTION WITH ANY USE OF THIS INFORMATION.

HENKEL CONSUMER ADHESIVES

08/08/00
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET

Page 01 of 04

1.5 OZ PORCELAIN REPAIR-WHITE
01-80234
1.

CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name:
Item No.:
Part No.:
Product Type:
2.

1.5 OZ PORCELAIN REPAIR-WHITE
01-80234
PP-1
COATING

COMPOSITION, INFORMATION ON INGREDIENTS

Ingredients

CAS No.

Additives
aromatic petroleum solvents MB
XYLENES*
Acrylic resin

Proprietary
Proprietary
1330-20-7
Proprietary

%
55-60
35-40
5-10
trace

* This component is listed as a SARA Section 313 Toxic Chemical.
Ingredients which have

exposure limits

Exposure Limits (TWA)
Ingredients

ACGIH
(TLV)

OSHA
(PEL)

OTHER

XYLENES

100 ppm TWA
434 mg/m3

100 ppm TWA
435 mg/m3

None

Exposure Limits (STEL)
Ingredients

ACGIH
(TLV)

OSHA
(PEL)

XYLENES

150 ppm
651 mg/m3

150 ppm
655 mg/m3

3.

HAZARDS IDENTIFICATION

Toxicity:
Primary Routes of Entry:
Signs and Symptoms
of Exposure:

Existing Conditions
Aggravated by Exposure:

IRRITANT
TOXIC BY INGESTION AND INHALATION
SKIN, INGESTION, INHALATION
ANESTHETIC IRRITATION OF RESPIRATORY TRACT OR
CENTRAL NERVOUS SYSTEM CHARACTERIZED BY HEADACHE
DIZZINESS, OF NARCOSIS. PRIMARY IRRITATION
OF SKIN OR EYES
None known

HENKEL CONSUMER ADHESIVES

08/08/00
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET

Product Name:
Item No.:
3.

Page 02 of 04

1.5 OZ PORCELAIN REPAIR-WHITE
01-80234

HAZARDS IDENTIFICATION

Ingredients

(continued)

Literature Referenced
Target Organ and Other Health Effects

Carcinogen
NTP IARC OSHA

Additives
No Data
NO NO
NO
aromatic petroleum solvents MB No Data
NO NO
NO
XYLENES
CAR CNS IRR KID LIV
NO NO
NO
Acrylic resin
No Data
NO NO
NO
------------------------------------------------------------------------------Abbreviations
CAR Cardiac
IRR Irritant
LIV Liver
4.

CNS Central nervous system
KID Kidney

FIRST AID MEASURES

Ingestion:
Inhalation:
Skin Contact:
Eye Contact:

DO NOT INDUCE VOMITING. CALL A PHYSICIAN
IMMEDIATELY
REMOVE TO FRESH AIR. CALL A PHYSICIAN
WASH WITH LARGE AMOUNTS OF WATER.
FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES
SEEK MEDICAL HELP

5.

FIRE FIGHTING MEASURES

Flash Point:
Recommended
Extinguishing Agents:
Special Firefighting
Procedures:
Hazardous Products formed
by Fire or Thermal Decomp
Unusual Fire or
Explosion Hazards:
Explosive Limits:
(% by volume in air)Lower
(% by volume in air)Upper
6.

<100 DEG F
CO2, DRY CHEMICAL ,FOAM
Not available
OXIDES OF CARBON AND NITROGEN
WATER SPRAY MAY BE INEFFECTIVE.
TO COOL CONTAINERS.

WATER MAY BE USED

Not available
Not available

ACCIDENTAL RELEASE MEASURES

Steps to be taken in case
of spill or leak:

REMOVE ALL SOURCES OF IGNITION. AVOID BREATHING
VAPORS. REMOVE WITH ABSORBENT AND NONSPARKING
TOOLS

HENKEL CONSUMER ADHESIVES

08/08/00
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET

Product Name:
Item No.:
7.

1.5 OZ PORCELAIN REPAIR-WHITE
01-80234

HANDLING AND STORAGE

Safe Storage:
(Contact Loctite Customer
Handling:
8.

DO NOT STORE ABOVE 120 DEG F
Service 1-800-243-4874 for shelf life information)
OBSERVE NORMAL SAFETY PRECAUTIONS FOR FLAMMABLE
MATERIALS. AVOID BREATHING VAPORS.

EXPOSURE CONTROLS, PERSONAL PROTECTION

Eyes:
Skin:
Ventilation:

Safety glasses or goggles.
Rubber or plastic gloves.
SUFFICIENT TO MAINTAIN VAPOR CONCENTRATION BELOW
TLV
Not available

Respiratory

See Section 2 for Exposure Limits.
9.

PHYSICAL AND CHEMICAL PROPERTIES

Appearance:
Odor:
Boiling Point:
pH:
Solubility in Water:
Specific Gravity
Volatile Organic Compound
(EPA Method 24)
Vapor Pressure:
Vapor Density:
Evaporation Rate
(Ether = 1)
10.

WHITE LIQUID
SOLVENT
280-344 DEG F
Does not apply
INSOLUBLE
1.1
47.7%
<10 MM
>1
Not available

STABILITY AND REACTIVITY

Stability:
Hazardous Polymerization:
Incompatibility:
Conditions to Avoid:
Hazardous Decomposition
Products (non-thermal):
11.

Stable
Will not occur
NONE KNOWN
Not available
NONE KNOWN

TOXICOLOGICAL INFORMATION
See Section 3.

12.

Page 03 of 04

ECOLOGICAL INFORMATION
No data available

HENKEL CONSUMER ADHESIVES

08/08/00
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET

Product Name:
Item No.:
13.

1.5 OZ PORCELAIN REPAIR-WHITE
01-80234

DISPOSAL CONSIDERATIONS

Recommended methods of
disposal:

INCINERATE FOLLOWING FEDERAL, STATE, AND LOCAL
REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS

EPA Hazardous Waste
Number
14.

D001 - Hazardous waste per 40CFR 261.21

TRANSPORTATION INFORMATION

DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name:
Hazard Class or
Division:
Identification Number:
Marine Pollutant:
IATA
Proper Shipping Name:
Class or Division:
UN or ID Number:
15.

CONSUMER COMMODITY
ORM-D
None
None
FLAMMABLE LIQUIDS NOS XYLENES
FLAMMABLE, UN 1993 PG III
UN 1993

REGULATORY INFORMATION

CA Proposition 65:

16.

Page 04 of 04

WARNING: This product contains a chemical known to
the State of California to cause cancer
and birth defects or other reproductive
harm.

OTHER INFORMATION

Estimated NFPA(R) Code:
Health Hazard:
Fire Hazard:
Reactivity Hazard:
Specific Hazard:

3
3
0
Does not apply

Estimated HMIS(R) Code:
Health Hazard:
Flammability Hazard:
Reactivity Hazards:
Personal Protection:

3
3
0
See Section 8.

NFPA is a registered
HMIS is a registered
Prepared by:
Company:
(24hr.) Phone:

trademark of the National Fire Protection Assn.
trademark of the National Paint and Coatings Assn.

Safety, Health and Regulatory Affairs - North America,
Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(860) 571-5100

MATERIAL SAFETY DATA SHEET
DATE PRINTED: MAY 12, 2005
MSDS NO. SANDBLOCK
Sanding Block

SECTION

OUTBOUND

1. CHEMICAL PRODUCT AND COMPANY INFORMATION

PRODUCT NAME
Sanding Block
TRADE NAME
MANUFACTURER(4)
Saint-Gobain Abrasives, Inc.
1 New Bond St
Worcester, MA. 01615
(800) 543-4335
REVISION DATE
1/20/2005
MSDS PRINT FORMAT
NUSA

SECTION

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE DESCRIPTION
PERCENT
CAS#
-------------------------------------------------------------------------------Aluminum Oxide, Non-fibrous
20.000- 30.000 1344-28-1
Polyurethane polymer
5.000- 10.000 68400-67-9
Unvulcanized rubber
10.000- 20.000
Silicon Carbide
35.000- 45.000 409-21-2
OTHER
Not Applicable

SECTION

3. HAZARDS IDENTIFICATION

INHALATION ACUTE EXPOSURE EFFECTS
Dust may be slightly irritating to eyes and respiratory tract at
high concentrations.
INHALATION CHRONIC EXPOSURE EFFECTS
May affect breathing capacity.
EYE CONTACT ACUTE EXPOSURE EFFECTS
Dust may irritate eyes.
SKIN CONTACT ACUTE EXPOSURE EFFECTS
Some may experience skin irritation from dust.
INGESTION ACUTE EXPOSURE EFFECTS
No known adverse effects, but ingestion not recommended.

SECTION

4. FIRST AID MEASURES

INHALATION
Remove to fresh air. If breathing has stopped, give artificial
respiration. Get medical attention immediately.
SKIN CONTACT
Wash affected areas with soap and water. Obtain medical assistance.
EYE CONTACT
Wash with large amounts of water. Obtain first aid and medical

assistance, if needed.
INGESTION
Call poison control center, hospital emergency room or physician
immediately.

SECTION

5. FIRE FIGHTING MEASURES

FIRE FIGHTING PROCEDURES
Not Applicable
HAZARDOUS PRODUCTS/COMBUSTION
None.
HAZARD RATING SOURCE
NFPA
HEALTH
1
FLAMMABILITY
0
REACTIVITY
0
OTHER

SECTION

6. ACCIDENTAL RELEASE MEASURES

CLEAN-UP
Follow normal clean up procedures.

SECTION

7. HANDLING AND STORAGE

HANDLING
Handle with adequate ventilation for nuisance dust.

SECTION

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

VENTILATION PROTECTION
Recommend using local exhaust ventilation when general ventilation is
not keeping the airborne concentration below the TLV.
RESPIRATORY PROTECTION
Respirators are required when airborne contaminant levels exceed the
TLV(s).
EYE PROTECTION
Always WEAR SAFETY GLASSES or some type of eye protection while
sanding.
OTHER PROTECTION
Use of this product may create elevated sound levels. Hearing
protection should be worn where required (see OSHA 29 CFR 1910.134
and other applicable regulations).

SECTION

9. PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE & ODOR
Solid article. Odorless.

SECTION

10. STABILITY AND REACTIVITY

INCOMPATIBILITIES
Avoid acids of all types with a pH < 4.0.
DECOMPOSITION
In use, dust and decomposing odors may be generated. In most cases,

the material removed from the workplace will be significantly
greater than the sandpaper components.

SECTION

11. TOXICOLOGICAL INFORMATION

CARCINOGENICITY
Not Applicable
LD50/LC50
Values are not appropriate or available.

SECTION

12. ECOLOGICAL INFORMATION

CHEMICAL FATE
Not Applicable

SECTION

13. DISPOSAL CONSIDERATIONS

WASTE DISPOSAL
Use standard landfill methods consistent with applicable Federal,
State, Provincial and local laws.

SECTION

14. TRANSPORT INFORMATION

HAZARD CLASS
This product is not hazardous as defined by the Department of
Transportation.(USA)
This product is "Not Regulated" under the Transportation of Dangerous
Goods Act. (CAN)

SECTION

15. REGULATORY INFORMATION

--------------------------------------------------------------------------------

EXPOSURE LIMITS/REGULATORY INFORMATION
SUBSTANCE DESCRIPTION
UNITS
OSHA
ACGIH
MOL
________________________________________________________________________________
Aluminum Oxide, Non-fibrous
MG/M3

15.0000

10.0000

10.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

10.0000

10.0000

10.0000

Polyurethane polymer
PPM
Unvulcanized rubber
Silicon Carbide
MG/M3
LEGEND:
EXPOSURE LIMIT DESCRIPTIONS
CA PROP 65
Not Applicable
TSCA
Section 8(b) - Inventory Status
All components of this product are registered under the regulations
of the Toxic Substance Control Act.

DOMESTIC SUBSTANCE LIST
All components of this product are found on the Domestic Substance
List.

SECTION

16. OTHER INFORMATION

DISCLAIMER
___________________________________________________________________________
KEY TO ABBREVIATIONS:
EQ=EQual
AP=APproximately
=

LT=Less Than
TR=TRace

GT=Greater Than
ND=No Data available

Click here to go back to MSDS

1301 E. 9th Street, #700
Cleveland OH 44114
(800) 726-9626
Barnes Distribution

Material Safety Data
Sheet

MSDS Form No. : MSDS22034
Item No. : 22034, 22034
**** MATERIAL SAFETY DATA SHEET ****
FEL-PRO ALUMINUM PUTTY EPOXY (HARDENER)
Part # MSDS22034

**** SECTION 1 - CHEMICAL PRODUCT AND COMPANY
IDENTIFICATION ****
MSDS Name: FEL-PRO ALUMINUM PUTTY EPOXY (HARDENER)
Product CAS: (none)
Product Code:
Synonyms: 22034; FEL-PRO ALUMINUM PUTTY EPOXY (HARDENER)
Company Identification:
Name: BOWMAN DISTRIBUTION
Address: 1301 E. 9TH ST., ST. 700
Address:
City: CLEVELAND State: OH Zip: 44114
For information, call: HEALTH ISSUES AND TECHNICAL INFORMATION (8AM-5PM
ET): 1-216-416-7200 X 5
60
Emergency Number:
Emergency Agency: CHEMTREC (24 HOURS EVERYDAY) / ROCKY MOUNTAIN POISON
CONTROL CENTER (24 HOURS
EVERYDAY)
Number: 800-424-9300 / 303-623-5716
MSDS Creation Date: 1/5/2005
Supersedes Date: 1/1/2003
**** SECTION 2 - COMPOSITION, INFORMATION ON
INGREDIENTS ****

Chemical Name
ALUMINUM
NONYL PHENOL
POLYOXYALKLENEAMINE
AMINOETHYLPIPERAZINE

CAS
7429-90-5
25154-52-3
9046-10-0
140-31-8

MIN
15
5
10
10

MAX
15
5
10
10

BENZYL ALCOHOL
BISPHENOL-A
DIMER/TOFA, REACTION PRODUCTS W/TETA
TRIETHYLENETETRAMINE
AMORPHOUS SILICON DIOXIDE
Miscellaneous:
INGREDIENTS

100-51-6
80-05-7
68082-29-1
112-24-3
112945-52-5

5
10
40
25
3

5
10
40
25
3

% WT/WT
LESS THAN

ALUMINUM
15
NONYL PHENOL
5
POLYOXYALKLENEAMINE
10
AMINOETHYLPIPERAZINE 10
BENZYL ALCOHOL
5
BISPHENOL-A
10
DIMER/TOFA, REACTION PRODUCTS W/
TETA
40
TRIETHYLENETETRAMINE 25
NOTE:

SEE BELOW FOR EXPOSURE LIMIT DATA FOR THESE INGREDIENTS

INGREDIENT

OSHA PEL

ACGIH TLV

OTHER LIMITS

ALUMINUM
NONYL PHENOL
POLYOXYALKLENEAMINE
AMINOETHYLPIPERAZINE
BENZYL ALCOHOL
BISPHENOL-A
DIMER/TOFA, REACTION
PRODUCTS W/ TETA
TRIETHYLENETETRAMINE

10 MG/M3-TD
N.E.
N.E.
N.E.
N.E.
N.E.

10 MG/M3-TD
N.E.
N.E.
N.E.
N.E.
N.E.

N.E.
N.E.
N.E.
N.E.
N.E.
N.E.

N.E.
N.E.

N.E.
N.E.

N.E.
N.E.

Lbs of VOC per Gallon Coating (minus water): 0
Coating Density (lbs/gal): 0
Solvent Density (lbs/gal): 0
Percent Solvent (volume): 0
Percent Solids (volume): 0
Percent Water (volume): 0
**** SECTION 3 - HAZARDS IDENTIFICATION ****
NFPA: Health: Fire: Reactivity: Other:
HMIS: Health: 3 Fire: 1 Reactivity: 0 Special Protection:
Miscellaneous:
EMERGENCY OVERVIEW
APPEARANCE AND ODOR:

SILVERY;

HMIS AND NFPA HAZARD RATINGS:
CATEGORY

NFPA

MILD AMMONIA-LIKE ODOR.

ACUTE HEALTH
N.D.
FLAMMABILITY
N.D.
REACTIVITY
N.D.
PERSONAL PROT./SPECIFIC HAZ.:

* / N.D.

*REFER TO SECTION 8.
POTENTIAL HEALTH EFFECTS
Target Organs:
PRIMARY ROUTES OF EXPOSURE: INHALATION, INGESTION, SKIN CONTACT, EYE
CONTACT, SKIN ABSORPTION.
Eye:
HEALTH HAZARDS - ACUTE EFFECTS: CORROSIVE TO THE EYES AND MAY CAUSE
SEVERE DAMAGE INCLUDING BLINDNESS. PRODUCT VAPOR CAN CAUSE LACRIMATION,
CONJUNCTIVITIS, AND CORNEAL EDEMA WHEN ABSORBED INTO THE TISSUE OF THE
EYE. CORNEAL EDEMA MAY GIVE RISE TO A PERCEPTION OF "BLUE HAZE" OR
"FOG"
AROUND LIGHTS. THE EFFECT IS TRANSIENT AND HAS NO KNOW RESIDUAL EFFECT.
Skin:
HEALTH HAZARDS - ACUTE EFFECTS: SUBSTANCE CAN BE ABSORBED THROUGH THE
SKIN IN HARMFUL AMOUNTS. STRONG SKIN SENSITIZER. PROLONGED CONTACT MAY
CAUSE CHEMICAL BURNS AND BLISTERING.
Ingestion:
HEALTH HAZARDS - ACUTE EFFECTS: MODERATELY TOXIC. CAN BURN MOUTH,
THROAT
AND STOMACH, WITH NAUSEA, SEVERE PAIN, AND VOMITING.
Inhalation:
HEALTH HAZARDS - ACUTE EFFECTS: LIQUID ASPIRATED INTO LUNGS MAY CAUSE
SERIOUS INJURY OR DEATH.
POTENTIAL RESPIRATORY SENSITIZER. PROLONGED OR REPEATED INHALATION
MAY CAUSE LUNG DAMAGE.
PROLONGED INHALATION CAUSES INFLAMMATION AND ULCERATION OF THE
RESPIRATORY TRACT.
Miscellaneous:
CONDITIONS TO AVOID: DO NOT GET IN EYES, ON SKIN OR CLOTHING.
BREATHING DUST, VAPOR,
MIST OR GAS. DO NOT TAKE INTERNALLY.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:

AVOID

NO DATA.

CHRONIC HAZARDS: PREEXISTING PULMONARY AND DERMATOLOGICAL DISORDERS
MAY BE AGGRAVATED BY
EXPOSURE TO HAZARDOUS COMPONENTS. PROLONGED OR REPEATED OVEREXPOSURE
MAY CAUSE LUNG DAMAGE.

**** SECTION 4 - FIRST AID MEASURES ****
Eye:

IMMEDIATELY FLUSH WITH PLENTY OF WATER. AFTER INITIAL FLUSHING, REMOVE
ANY CONTACT LENSES AND CONTINUE FLUSHING FOR AT LEAST 15 MINUTES. HAVE
EYES IMMEDIATELY EXAMINED AND TESTED BY MEDICAL PERSONNEL.
Skin:
IMMEDIATELY FLUSH AFFECTED AREA (S) THOROUGHLY WITH WATER AT LEAST 15
MINUTES. REMOVE AND
0WASH CONTAMINATED CLOTHING. CONTAMINATED LEATHER ARTICLES SHOULD BE
DISPOSED OF. OBTAIN
1MEDICAL ATTENTION.
Ingestion:
IF SWALLOWED, DO NOT INDUCE VOMITING.
MILK. CALL A PHYSICIAN
OR POISON CONTROL CENTER IMMEDIATELY.
AN UNCONSCIOUS PERSON.

GIVE VICTIM A GLASS OF WATER OR
NEVER GIVE ANYTHING BY MOUTH TO

Inhalation:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION.
IF BREATHING IS
DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
Notes to Physician:

**** SECTION 5 - FIRE FIGHTING MEASURES ****
Unusual Fire and Explosion Hazards:
FINELY DIVIDED DUST IN AIR MAY PRESENT EXPLOSION HAZARD. PREVENT DUST
BUILD-UP. CLOSED
CONTAINERS MAY RUPTURE OR EXPLODE (DUE TO PRESSURE BUILD-UP) WHEN
EXPOSED TO EXTREME HEAT.
IRRITATING AND/OR TOXIC GASES OR FUMES MAY BE GENERATED BY THERMAL
DECOMPOSITION OR COMBUSTION.
Special Fire Fighting Procedures:
USE NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS AND FULL
PROTECTIVE CLOTHING. USE WATER
0TO COOL EXPOSED CONTAINERS. WATER STREAM DIRECTED INTO FIRE MAY CAUSE
FROTHING WITH SUBSEQUENT
1SPREAD OF FLAME.
Extinguishing Media:
ALCOHOL FOAM, CO2, WATER FOG, DRY CHEMICAL, FOAM.
Flash Point:
AND METHOD:

200 F (SETAFLASH CLOSED CUP).

Flammable Limits:
Lower Limit:
LEL(%): N.A.
Upper Limit:
UEL(%): N.A.

AutoIgnition Temperature:
(O F): NO DATA.
General Information:
FLAMMABILITY LIMITS (%):

N.A.

HAZARDOUS COMBUSTION PRODUCTS:

NO DATA.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES
****
Disposal:
DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS.
DECONTAMINATE OR DISPOSE
OF CONTAMINATED CLOTHING AND ARTICLES. WASH SPILL AREA WITH SOAP AND
WATER.
RCRA HAZARDOUS WASTE NUMBER:

NOT REGULATED.

Spills/Leaks:
WEAR APPROPRIATE PROTECTIVE EQUIPMENT DURING CLEANUP. ABSORB WITH
INERT MATERIAL, SUCH AS
CLAY. SWEEP OR SHOVEL INTO LOOSELY-COVERED WASTE CONTAINER AND REMOVE
TO APPROPRIATE WASTE
AREA.

**** SECTION 7 - HANDLING and STORAGE ****
Handling:
WASH THOROUGHLY AFTER HANDLING. USE WITH ADEQUATE VENTILATION. AVOID
BREATHING DUST, VAPOR,
MIST OR GAS. DO NOT GET IN EYES, ON SKIN OR CLOTHING. DO NOT TAKE
INTERNALLY. FOR INDUSTRIAL
USE ONLY. STORING: KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP OUT
OF REACH OF CHILDREN.
Storage:

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL
PROTECTION ****
Engineering Controls:
LOCAL EXHAUST NEEDED TO CONTROL VAPOR OR DUST LEVELS TO BELOW LOWEST
COMPONENT TLV.
Eyes:
CHEMICAL SPLASH GOGGLES.

FACE SHIELD.

Skin:
CLEAN CLOTHING TO COVER SKIN
NITRILE GLOVES. TEFLON
GLOVES. VITON GLOVES.
Clothing:
OTHER PROTECTIVE EQUIPMENT:

BUTYL RUBBER GLOVES.

NEOPRENE GLOVES.

ACCESSIBLE EYE WASH AND SAFETY SHOWER.

Respirators:
NONE NORMALLY REQUIRED UNDER GENERAL VENTILATION. IF TLV/PEL IS
EXCEEDED, IF USE IS PERFORMED
IN A POORLY VENTILATED SPACE, OR IF INHALATION EFFECTS OCCUR, USE
NIOSH-APPROVED VAPOR
CARTRIDGE RESPIRATOR IN ACCORDANCE WITH APPLICABLE HEALTH AND SAFETY
REGULATIONS AND
MANUFACTURER'S RECOMMENDATIONS.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
****
Appearance/Odor:

pH: ALK.
Vapor Pressure: NO DATA
Vapor Density: (AIR = 1): GT 1 HEAVIER THAN AIR
Evaporation Rate: (N-BUTYL ACETATE=1): LT 1. HEAVIER THAN AIR
Viscosity: HIGH
Boiling Point: 278-560 F
Freezing/Melting Point: FREEZING POINT: NO DATA.
Decomposition Temperature: NA
Solubility: IN WATER: SLIGHT
Specific Gravity: 1.07
Molecular Formula: NA
Molecular Weight: NA
Miscellaneous:
VOC (G/LITER): 0
MAX. % VOC BY WEIGHT: 0%.; METHOD USED: CALCULATED.
COEFF. OF WATER/OIL DISTRIBUTION: NO DATA.

**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
Conditions to Avoid:
NO INFORMATION.
Incompatibilities with Other Materials:
STRONG LEWIS OR MINERAL ACIDS. STRONG BASES OR OXIDANTS. REACTION WITH
EPOXY RESINS AND ISOCYANATES IN LARGE AMOUNTS OR UNDER UNCONTROLLED

CONDITIONS RELEASES CONSIDERABLE HEAT AND MAY RELEASE ACRID FUMES.
ALDEHYDES, KETONES, ACRYLATES, AND ORGANIC HALIDES. CLEANING SOLUTION
SUCH AS CHROMERGE (SULFURIC ACID/ DICHROMATE) AND AQUA REGIA. REACTION
WITH SOME NITRATES OR NITRITES CAN CAUSE THE FORMATION OF CANCERCAUSING
NITROSOAMINES. EPOXIDES. SULFURIC ACID, HBR + IRON WHEN IT HEATS ABOVE
100 DEGREES C.
Hazardous Decomposition Products:
OXIDES OF CARBON. OXIDES OF NITROGEN, AMMONIA. IRRITATION ALDEHYDES AND
KETONES.
Hazardous Polymerization:
WILL NOT OCCUR UNDER NORMAL CONDITIONS.

**** SECTION 11 - TOXICOLOGICAL INFORMATION
****
Toxicological Information:
CARCINOGENICITY: NONE.
INGREDIENT

NTP

OSHA

IARC

ALUMINUM
NONYL PHENOL
POLYOXYALKLENEAMINE
BENZYL ALCOHOL
BISPHENOL-A
DIMER/TOFA, REACTION
PRODUCTS W/ TETA
TRIETHYLENETETRAMINE

NO
NO
NO
NO
NO

NO
NO
NO
NO
NO

NO
NO
NO
NO
NO

NO
NO

NO
NO

NO
NO

COMPONENT TOXICOLOGICAL INFORMATION:
INGREDIENT LD 50 / LC50
ALUMINUM: NO INFORMATION / NO INFORMATION
NONYL PHENOL: SKIN (RBT ) 2140 MG/KG / NO INFORMATION.
POLYOXYALKLENEAMINE: DERM (RBT) 800 MG/KG / NO INFORMATION
BENZYL ALCOHOL: ORAL (RAT) 1230 MG/KG / NO INFORMATION
BISPHENOL-A: DERM (RBT) 3000 MG/KG / 200 MG/I/H
DIMER/TOFA, REACTION PRODUCTS W/ TETA: NO INFORMATION / NO INFORMATION
TRIETHYLENETETRAMINE: DERM (RBT) 805 MG/KG / NO INFORMATION.

**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecological Information:
NO DATA AVAILABLE.

**** SECTION 13 - OTHER PRECAUTIONS ****
Other Precautions:

Work/Hygienic Practices:
FOLLOW GENERAL INDUSTRIAL SAFETY PRACTICES DURING USE. DO
NOT SMOKE OR EAT DURING USE. WASH AFTER HANDLING. DO NOT REUSE EMPTY
CONTAINERS. FOLLOW ALL
MSDS/LABEL PRECAUTIONS EVEN AFTER CONTAINER IS EMPTIED.

**** SECTION 14 - TRANSPORT INFORMATION ****
Transportation Information:
DOT SHIPPING NAME: N.A.
HAZARD CLASS OR DIVISION:
CARTON MARKINGS:

N.A.

IDENTIFICATION NUMBER:
PACKING GROUP:
LABELS:

N.A.

N.A.

N.A.

N.A.

Label Information:

**** SECTION 15 - REGULATORY INFORMATION ****
Regulatory Information:
COMPONENT RCRA CLASSIFICATIONS:

NOT REGULATED.

TSCA: THE CHEMICAL SUBSTANCES IN THIS PRODUCT ARE ON THE TSCA SECTION
8
INVENTORY. THIS PRODUCT CONTAINS THE FOLLOWING CHEMICALS SUBJECT TO
REPORTING
REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE U.S.: NONYL PHENOL
(25154-52-3),
BISPHENOL-A (80-05-7).
PENNSYLVANIA RIGHT TO KNOW: THE FOLLOWING ARE NON-HAZARDOUS, BUT ARE
PRESENT
IN THE PRODUCT AT GREATER THAN 3 %: AMORPHOUS SILICON DIOXIDE (CAS
NUMBER 112945-52-5).

NJ RIGHT TO KNOW: THE FOLLOWING MATERIALS ARE NON-HAZARDOUS, BUT ARE
AMONG
THE TOP FIVE COMPONENTS IN THIS PRODUCT: AMORPHOUS SILICON DIOXIDE (CAS
NUMBER 112945-52-5).
CANADIAN WHMIS CLASS:

E, D2B.

CHIP SUPPLY LABEL SAFETY PHRASES:
CHIP SUPPLY LABEL RISK PHRASES:
CHIP SUPPLY LABEL SYMBOLS:

36/37/39

34

43

26

21

CORROSIVE, C

SARA TITLE III:
HAZARD CATEGORIES:
ACUTE HEALTH: YES
CHRONIC HEALTH: YES
FIRE HAZARD: YES
PRESSURE HAZARD: YES
REPORTABLE INGREDIENTS:
SECTION 302/303: NONE.
SECTION 313: NONE.
CERCLA RQ:

NONE KNOWN.

**** SECTION 16 - ADDITIONAL INFORMATION ****
Additional Information:
N.A. NOT APPLICABLE
N.D. NOT DETERMINED
N.E. NOT ESTABLISHED

**** MATERIAL SAFETY DATA SHEET ****
FEL-PRO ALUMINUM PUTTY EPOXY (RESIN)
Part # MSDS22034

**** SECTION 1 - CHEMICAL PRODUCT AND COMPANY
IDENTIFICATION ****
MSDS Name: FEL-PRO ALUMINUM PUTTY EPOXY (RESIN)

MATERIAL SAFETY DATA SHEET
S O S PRODUCTS COMPANY INC
P. O. Box 47
East Greenville, Pa.
18041
Phone (215)-679-6262
(215)-679-6263
PAGE 1
-------------------------------------------------------------------------------SECTION I - GENERAL INFORMATION
-------------------------------------------------------------------------------Product Code:
EP
Revision Date: July 26, 2005
Identification: EPOXY PUTTY
-------------------------------------------------------------------------------SECTION II - HAZARDOUS INGREDIENTS
-------------------------------------------------------------------------------PEL
TLV
TLV
INGREDIENT:
%
PPM
PPM
MG/M3
LEL
CAS. NO
-------------------------------------------------------------------------------TRI(DIMETHYLAMINOMETHYL) PH
00090-72-2
EPOXY RESIN
250-68-386
-------------------------------------------------------------------------------2,4,6, TRI (DIMETHYLAMINOMETHYL) PHENOL ACGIH-5PPM
EPOXY RESIN (DIGLYCIDYL ETHER OF BISPHENOL A)
ACGIH - 19.8G/KG (ORAL LD50 RABBIT)
ACGIH - 20G/KG (DERMAL LD50 RABBIT)
-------------------------------------------------------------------------------Carcinogenicity: This product is NOT considered to be a carcinogen by the
National Toxicology Program, the International Agency for
Research on Cancer, or the Occupational Safety and Health
Administration.
-------------------------------------------------------------------------------SECTION III - PHYSICAL CHARACTERISTIC
-------------------------------------------------------------------------------Boiling Point:
N/A
Specific Gravity:
1.9
Vapor Pressure:
N/A
Melting Point:
N/A
Vapor Density:
N/A
Evaporation Rate:
NONE
Solubility in Water:
NOT SOLUBLE
Odor and Appearance:
2 COMPONENTS IN MASTIC FORM. ODOR: MERCAPTAN
-------------------------------------------------------------------------------SECTION IV - FIRE AND EXPLOSION HAZARD DATA
-------------------------------------------------------------------------------Flash Point:
NONE
LEL: N/A
Flammable Limits:
N/A
UEL: N/A
Extinguishing Media:
WATER SPRAY, FOAM, CO2 AND DRY CHEMICAL
Special Fire Fighting Procedures: CONVENTIONAL METHODS
Unusual Fire and Explosion Hazards:
N/A
-------------------------------------------------------------------------------SECTION V - REACTIVITY DATA
-------------------------------------------------------------------------------This product is STABLE
Conditions to avoid: NONE
Incompatibility:
NONE
Hazardous Decomposition: CO, ALDEHYDES, ACIDS, SO2 AND N2 MAY BE FORMED.
Hazardous Polymerization: WILL NOT OCCUR.
-------------------------------------------------------------------------------SECTION VI - HEALTH HAZARD DATA
-------------------------------------------------------------------------------Routes of Entry:
Inhalation?
NO
Skin?
YES - SECONDARY
Ingestion?
YES - SECONDARY
Health Hazards (Acute and Chronic):
NONE KNOWN OR ESTABLISHED
Carcinogenicity:
NTP?
NO
IARC Monographs?
NO

OSHA Regulated?
Signs and Symptoms of Exposure:

NO

NONE

Medical Conditions Generally Aggravated by Exposure:

NONE

Emergency and First Aid Procedures:
SKIN: WASH WITH SOAP AND WATER. EYES: FLUSH 15 MINUTES; GET MEDICAL
ATTENTION. INHALATION: REMOVE TO FRESH AIR, INGESTION: INDUCE VOMITING.
CALL PHYSICIAN IMMEDIATELY.
-------------------------------------------------------------------------------SECTION VII - HANDLING PRECAUTIONS
-------------------------------------------------------------------------------Steps to be Taken if Material is Released or Spilled:
SWEEP UP IN NORMAL MANNER
Waste Disposal Method: NON-HAZARDOUS LANDFILL
Precautions to be Taken in Handling and Storage:

NONE

Other Precautions:
NONE
-------------------------------------------------------------------------------SECTION VIII - CONTROL MEASURES
-------------------------------------------------------------------------------Respiratory Protection:
NONE REQUIRED FOR NORMAL USE
Ventilation Required:

ADEQUATE

Protective Gloves:

WEAR POLYETHYLENE GLOVES FOR PROLONGED USE.

Eye Protection:

WEAR SAFETY GOGGLES

Other Protective Equipment:

NONE REQUIRED

Work/Hygienic Practices:

WASH THOROUGHLY AFTER USING.

-----------------------------------------------------------------------------The above information pertains to the product as it is currently formulated and
is based upon the information available at this time. Additions of reducers or
other additives to this product may substantially alter the composition and
subsequent hazards of the product. Since conditions of use are outside of our
control, we make no warranties, either expressed or implied, and assume no
liability in connection with any use of this information.

|-------------------------------------------------------|
| M A T E R I A L
S A F E T Y
D A T A
S H E E T |
|-------------------------------------------------------|
|-------------------------------------------------------------------------|
|
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
|
|-------------------------------------------------------------------------|
PRODUCT NAME
UPC NUMBER
PRODUCT USE/CLASS

: EASY SOLUTIONS - Tile Grout Repair
: 7079810726, 7079810731
: Tile Grout Repair

MANUFACTURER:
DAP INC.
2400 BOSTON STREET
BALTIMORE, MD 21224

24 HOUR EMERGENCY:
TRANSPORTATION: 1-800-535-5053 (352-323-3500)
MEDICAL
: 1-800-327-3874 (513-636-5118)

PREPARE DATE : 10/16/2000
REVISION NO. : 1
REVISION DATE: 06/11/2001

GENERAL INFORMATION:
DAP INC. : 1-888-DAP-TIPS (1-888-327-8477)

|-------------------------------------------------------------------------|
|
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
|
|-------------------------------------------------------------------------|
WT/WT %
ITEM
------------ CHEMICAL NAME ------------CAS NUMBER
RANGE
--------------------------------------------------------------------------01
02
03

Ethylene glycol
Calcium Carbonate
Mineral spirits

107-21-1
1317-65-3
8052-41-3

1.0-5.0 %
70.0-75.0 %
1.0-5.0 %

---------------------- EXPOSURE LIMITS -------------------ACGIH
OSHA
COMPANY
ITEM TLV-TWA
TLV-STEL
PEL-TWA
PEL-CEILING TLV-TWA
SKIN
--------------------------------------------------------------------------01
02
03

N.E.
10 mg/m3
100 ppm

50 ppm*
N.E.
N.E.

N.E.
15 mg/m3
100 ppm

50 ppm
N.E.
N.E.

N.E.
N.E.
N.E.

NO
NO
NO

(See Section 16 for abbreviation legend), * - TLV-Ceiling Value
Remaining ingredients are not considered hazardous per the OSHA Hazard
Communication Standard.
Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor
OSHA Final Rule Limits (CFR 29 1910.1000); limits may vary between states.

(Continued on Page 2)
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Product Name: EASY SOLUTIONS - Tile Grout Repair
Revision Date: 06/11/2001

Page

2

|-------------------------------------------------------------------------|
|
SECTION 3 - HAZARDS IDENTIFICATION
|
|-------------------------------------------------------------------------|
EMERGENCY OVERVIEW: CAUTION! May irritate eyes, skin, nose, and
respiratory tract. Harmful if inhaled or swallowed.
POTENTIAL HEALTH EFFECTS:
EFFECTS OF OVEREXPOSURE - EYE CONTACT:

May cause eye irritation.

EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation.
Prolonged or repeated contact can result in defatting and
drying of the skin which may result in skin irritation and dermatitis
(rash).
EFFECTS OF OVEREXPOSURE - INHALATION: Vapor harmful if inhaled. Vapor
may irritate nose and upper respiratory tract. Vapor inhalation may affect
the brain or nervous system causing dizziness, headache or nausea.
EFFECTS OF OVEREXPOSURE - INGESTION: This
fatal if swallowed. Ingestion of ethylene
respiratory and/or cardiac failure as well
ingested, this product may cause vomiting,
respiration.

material may be harmful or
glycol in excess may lead to
as kidney and liver damage. If
diarrhea, and depressed

EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated
permanent brain and nervous system damage with prolonged and repeated
occupational overexposure to solvents. Ingestion of Ethylene Glycol in
excess may lead to respiratory and cardiac failure, and kidney and liver
damage.
MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY CONTACT:
PRIMARY ROUTE(S) OF ENTRY:

SKIN CONTACT

None known.

INHALATION

|-------------------------------------------------------------------------|
|
SECTION 4 - FIRST AID MEASURES
|
|-------------------------------------------------------------------------|
EYE CONTACT: Flush with large quantities of water until irritation
subsides. If irritation persists, call Medical in Section I.
SKIN CONTACT: Wash with soap and water. If irritation persists, call
Medical in Section I.
INHALATION:
INGESTION:
COMMENTS:

Remove to fresh air.

Call Medical in Section I immediately.

DO NOT INDUCE VOMITING. Call Medical in Section I immediately.
None.

(Continued on Page 3)
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Product Name: EASY SOLUTIONS - Tile Grout Repair
Revision Date: 06/11/2001

Page

3

|-------------------------------------------------------------------------|
|
SECTION 5 - FIRE FIGHTING MEASURES
|
|-------------------------------------------------------------------------|
FLASH POINT: >200 F
(SETAFLASH CLOSED CUP)

LOWER EXPLOSIVE LIMIT: N.A.
UPPER EXPLOSIVE LIMIT: N.A.

AUTOIGNITION TEMPERATURE: N.E.
EXTINGUISHING MEDIA:

CO2

DRY CHEMICAL

FOAM

UNUSUAL FIRE AND EXPLOSION HAZARDS: Containers may burst if exposed to
extreme heat. Eliminate sources of ignition: heat, electrical equipment,
sparks, and flames. Do not put in contact with oxidizing or caustic
materials.
SPECIAL FIREFIGHTING PROCEDURES: Full protective equipment, including
self-contained breathing apparatus, is recommended to protect from
combustion products. Cool exposed containers with water.
|-------------------------------------------------------------------------|
|
SECTION 6 - ACCIDENTAL RELEASE MEASURES
|
|-------------------------------------------------------------------------|
SPILL OR LEAK PROCEDURES: Dike spill area. Absorb remaining liquid with
absorbent material and place into containers.
|-------------------------------------------------------------------------|
|
SECTION 7 - HANDLING AND STORAGE
|
|-------------------------------------------------------------------------|
HANDLING INFORMATION: KEEP OUT OF REACH OF CHILDREN. Avoid skin and eye
contact. Avoid breathing vapors. Use only in a well ventilated area.
STORAGE INFORMATION: Store away from caustics and oxidizers. Keep away
from heat, spark, and flame. Keep containers tightly closed when not in
use. Keep containers from excessive heat and freezing. Do not store at
temperatures above 120 degrees F.
OTHER PRECAUTIONS: Intentional misuse by deliberately concentrating and
inhaling vapors may be harmful or fatal. Do not take internally.
|-------------------------------------------------------------------------|
|
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
|
|-------------------------------------------------------------------------|
ENGINEERING CONTROLS: Provide sufficient mechanical ventilation (local or
general exhaust) to maintain exposure below PEL and TLV. Vapors are heavier
than air and will collect in low areas. Check all low areas (basements,
sumps, etc.) for vapor before entering.

(Continued on Page 4)
---------------------------------------------------------------------------

Product Name: EASY SOLUTIONS - Tile Grout Repair
Revision Date: 06/11/2001

Page

4

|-------------------------------------------------------------------------|
|
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
|
|-------------------------------------------------------------------------|
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA
1910.134 and ANSI Z88.2 requirements must be followed whenever workplace
conditions warrant a respirator's use. If 8 hour exposure limit or value
is exceeded for any component, use an approved NIOSH/OSHA respirator.
Consult your safety equipment supplier and the OSHA regulation, 29 CFR
1910.134 for respirator requirements. A respiratory protection program that
meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever
workplace conditions warrant a respirator's use.
EYE PROTECTION:
SKIN PROTECTION:

Goggles or safety glasses with side shields.
Solvent impervious gloves.

OTHER PROTECTIVE EQUIPMENT:
if body contact may occur.
HYGIENIC PRACTICES:

Provide eyewash and solvent impervious apron

Remove contaminated clothing and wash before reuse.

|-------------------------------------------------------------------------|
|
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
|
|-------------------------------------------------------------------------|
BOILING RANGE
ODOR
APPEARANCE
SOLUBILITY IN H2O
SPECIFIC GRAVITY
VAPOR PRESSURE
PHYSICAL STATE

:
:
:
:
:
:
:

210 - 220 F
Sl. amine odor
White paste
Negligible
1.9388
17.5 mm Hg@68F.
Paste

VAPOR DENSITY

: Is heavier than air

EVAPORATION RATE: Is slower than Butyl
Acetate

(See Section 16 for abbreviation legend)
|-------------------------------------------------------------------------|
|
SECTION 10 - STABILITY AND REACTIVITY
|
|-------------------------------------------------------------------------|
CONDITIONS TO AVOID:
INCOMPATIBILITY:

Excessive heat and freezing.

Strong oxidizers and caustics.

HAZARDOUS DECOMPOSITION PRODUCTS:
NOx

Normal decomposition products, i.e. COx,

HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
|-------------------------------------------------------------------------|
|
SECTION 11 - TOXICOLOGICAL PROPERTIES
|
|-------------------------------------------------------------------------|
No product or component toxicological information is available.
(Continued on Page 5)
---------------------------------------------------------------------------

Product Name: EASY SOLUTIONS - Tile Grout Repair
Revision Date: 06/11/2001

Page

5

|-------------------------------------------------------------------------|
|
SECTION 12 - ECOLOGICAL INFORMATION
|
|-------------------------------------------------------------------------|
No Information.
|-------------------------------------------------------------------------|
|
SECTION 13 - DISPOSAL CONSIDERATIONS
|
|-------------------------------------------------------------------------|
WASTE MANAGEMENT/DISPOSAL: Dispose of according to Federal, State, and
Local Standards. This product does not meet the definition of a hazardous
waste according to U.S. EPA Hazardous Waste Management Regulations, 40 CFR
Section 261. However, it is recommended that discarded material be
incinerated at a permitted facility. State and Local regulations/
restrictions are complex and may differ from Federal regulations.
Responsibility for proper waste disposal is with the owner of the waste.
EPA WASTE CODE - If discarded (40 CFR 261):

None.

|-------------------------------------------------------------------------|
|
SECTION 14 - TRANSPORTATION INFORMATION
|
|-------------------------------------------------------------------------|
DOT PROPER SHIPPING NAME: Not Regulated by D.O.T.
DOT HAZARD CLASS: NONE
DOT UN/NA NUMBER: NONE

PACKING GROUP: NONE

Note: The shipping information provided is applicable for domestic ground
transport only. Different categorization may apply if shipped via other
modes of transportation and/or non-domestic destinations.
|-------------------------------------------------------------------------|
|
SECTION 15 - REGULATORY INFORMATION
|
|-------------------------------------------------------------------------|
U.S. FEDERAL REGULATIONS: AS FOLLOWS OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
----------- CHEMICAL NAME ----------Ethylene glycol

CAS NUMBER
107-21-1

WT/WT % RANGE
1.0-5.0 %

TOXIC SUBSTANCES CONTROL ACT:
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:
----------- CHEMICAL NAME ----------OLEIC ACID
1,2,4-TRIMETHYLBENZENE

CAS NUMBER
112-80-1
95-63-6

(Continued on Page 6)
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Product Name: EASY SOLUTIONS - Tile Grout Repair
Revision Date: 06/11/2001

Page

6

|-------------------------------------------------------------------------|
|
SECTION 15 - REGULATORY INFORMATION
|
|-------------------------------------------------------------------------|
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------Water
Acrylic Polymer

CAS NUMBER
7732-18-5
TSRN-51-0344944-1943

PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------Water
Acrylic Polymer

CAS NUMBER
7732-18-5
Proprietary

CALIFORNIA PROPOSITION 65:
WARNING: The chemical(s) noted below and contained in this product, are
known to the state of California to cause cancer:
----------- CHEMICAL NAME ----------Chlorothalonil

CAS NUMBER
1897-45-6

INTERNATIONAL REGULATIONS: AS FOLLOWS CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: No information available.

(Continued on Page 7)
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Product Name: EASY SOLUTIONS - Tile Grout Repair
Revision Date: 06/11/2001

Page

7

|-------------------------------------------------------------------------|
|
SECTION 16 - OTHER INFORMATION
|
|-------------------------------------------------------------------------|
HMIS RATINGS - HEALTH: 1

FLAMMABILITY: 1

REACTIVITY: 0

PREVIOUS MSDS REVISION DATE: 10/16/2000
VOC less water, less exempt solvent: 95-100 gm/L (0.5-1 lb/gal) (4-5
wt%VOC)
VOC material
: 50-60 gm/L
LEGEND:

ACGIH
N.A.
N.E.
PEL
NTP
SARA
STEL
TLV
VOC
NJRTK
N.D.

-

AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
NOT APPLICABLE
NOT ESTABLISHED
PERMISSIBLE EXPOSURE LIMIT
NATIONAL TOXICOLOGY PROGRAM
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986
SHORT TERM EXPOSURE LIMIT
THRESHOLD LIMIT VALUE(8 HR. TIME WEIGHTED AVERAGE OR TWA)
VOLATILE ORGANIC COMPOUND
NEW JERSEY RIGHT TO KNOW LAW
NOT DETERMINED

MSDS# 71031
---------------------------------------------------------------------------

This data is offered in good faith as typical values and not as a product
specification. No warranty either expressed or implied, is hereby made.
The recommended industrial hygiene and safe handling procedures are
believed to be generally applicable. However, each user should review the
recommendations in specific context of the intended use and determine if
they are appropriate.
--------------------------------------------------------------------------< End OF MSDS >

MATERIAL SAFETY DATA

SHEET

Pre-Mixed Tile Grout
HMIS
HEALTH

1

FLAMMABILITY

0

REACTIVITY

0

PERSONAL

B

PROTECTION

1. Product And Company Identification
Supplier
CUSTOM BUILDING PRODUCTS
10400 Pioneer Blvd., Unit #3
Santa Fe Springs, CA 90670 UNITED STATES

Manufacturer
CUSTOM BUILDING PRODUCTS
10400 Pioneer Blvd., Unit #3
Santa Fe Springs, CA 90670 UNITED STATES

Company Contact: GEORGE MARCINA
Telephone Number: (562) 968-2980 Ext 103
FAX Number:
(562) 903-2697
E-Ma il: georgem@cbpmail.net
Web Site: www.custombuildingproducts.com

Company Contact: GEORGE MARCINA
Telephone Number: (562) 968-2980 Ext 103
FAX Number:
(562) 903-2697
E-Ma il: georgem@cbpmail.net
Web Site: www.custombuildingproducts.com

Supplier Emergency Contacts & Phone Number
GEORGE MARCINA: (562) 968-2980

Manufacturer Emergency Contacts & Phone Number
GEORGE MARCINA: (562) 968-2980

Issue Date: 04/24/2006
Product Name: Pre-Mixed Tile Grout
CAS Number: Not Established
Chemical Formula: Mixture
MSDS Number: 645
Product Code: 1022
2. Composition/Information On Ingredients
Ingredient
Name

CAS
Number

Percent Of
Total Weight

Acrylic Copolymer

Proprietary

5 - 15

Calcium Carbonate

1317-65-3

65 - 75

3. Hazards Identification
Primary Routes(s) Of Entry
Eye and Skin Contact. Inhalation. Ingestion.
Eye Hazards
Causes eye irritation.
Skin Hazards
May cause skin irritation.
Ingestion Hazards
Harmful if swallowed. May cause gastrointestinal irritation, nausea and vomiting.
Inhalation Hazards
May cause nose, throat, and lung irritation.
Chronic/Carcinogenicity Effects
May contain trace amounts of chemicals that IARC classifies as possible carcinogens.
Page 1 of 5

MATERIAL SAFETY DATA

SHEET

Pre-Mixed Tile Grout
3. Hazards Identification - Continued
Teratogenicity (Birth Defects)
May contain trace amounts of chemicals that caused birth defects in animal studies. It did not cause harm to the
animal or fetus when applied on skin.
Reproductive Effects
May contain trace amounts of chemicals that caused birth defects in animal studies. It did not cause harm to the
animal or fetus when applied on skin.
Mutagenicity (Genetic Effect)
May contain trace amounts of chemicals that caused birth defects in animal studies. It did not cause harm to the
animal or fetus when applied on skin.
Conditions Aggravated By Overexposure
May cause eye and skin irritation. May cause nose, throat and lung irritation. May cause gastronomic disturbances.
4. First Aid Measures
Eye
Gently blot or wipe any residue remaining on the face, being careful not to get it in the victim's eyes or skin. Hold
eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention
immediately.
Skin
Remove excess from the skin. Wash skin with plenty of water for at least 15 minutes. Remove contaminated
clothing and shoes. Thoroughly clean before reuse. Get medical attention immediately if irritation (redness, rash,
blistering) develops and persists.
Ingestion
If victim is fully conscious, give one or two cups of water or milk to drink. If swallowed, do not induce vomiting unless
directed to do so by medical personnel. Get medical attention immediately. If there is any discomfort from ingestion,
consult a physician.
Inhalation
If inhaled, remove to fresh air. Get medical attention immediately.
5. Fire Fighting Measures
Flash Point: NONE °F
Flash Point Method: NONE
Lower Explosive Limit: N/A
Upper Explosive Limit: N/A
Fire And Explosion Hazards
Material will not burn until all water has evaporated. Cans may burst open and splatter material if temperatures reach
212 deg F and above.
Extinguishing Media
Foam, CO2, Dry chemical, Water fog.
Fire Fighting Instructions
Firefighters should wear self-contained breathing apparatus and full protective gear.
6. Accidental Release Measures
Clean up spill immediately. Cover with absorbent to contain. Collect and dispose. Use appropriate containers to avoid
environmental contamination. Avoid runoff to waterways and sewers. Avoid release to the environment.
Use appropriate personal protective equipment (PPE).

Page 2 of 5

MATERIAL SAFETY DATA

SHEET

Pre-Mixed Tile Grout
7. Handling And Storage
Handling And Storage Precautions
Store in cool, dry areas away from sunlight, heat and heat sources. Protect from freezing.
Work/Hygienic Practices
Wash thoroughly with soap and water after handling. Use good personal hygiene. Observe good housekeeping
practices.
8. Exposure Controls/Personal Protection
Eye/Face Protection
Safety glasses with side shields or goggles recommended.
Skin Protection
Chemical-resistant gloves.
Respiratory Protection
General room ventilation is normally adequate. .In case of inadequate ventilation, use NIOSH-approved respirator.
Other/General Protection
General ventilation is usually sufficient. Fan or other device maybe needed if used in small and enclosed areas.
Ingredient(s) - Exposure Limits
Calcium Carbonate
OSHA - PEL - TWA - 15mg/m3
Niosh - REL 10 mg/m3
ACGIH- TLV - 10 mg/m3
OSHA - PEL - TWA - 5 mg/m3
Adequate clothing to prevent skin contact.
9. Physical And Chemical Properties
Appearance
White paste
Odor
Mild acrylic odor.
Chemical Type: Mixture
Physical State: Liquid
Boiling Point: 212 °F
Specific Gravity: 1.9
Percent Volatiles: 25
Vapor Density: HEAVIER THAN AIR
Solubility: Dilutable in water
Evaporation Rate: Slower than ether
10. Stability And Reactivity
Sta bility: Stable
Hazardous Polymerization: Will not occur
Incompatible Materials
Avoid contact with strong oxidizers.
Hazardous Decomposition Products
Thermal decomposition in air may result in carbon monoxide and / or carbon dioxide.
Conditions To Avoid (Polymerization)
Hazardous polymerization will not occur. Heat may cause pressure build-up in closed containers

Page 3 of 5

MATERIAL SAFETY DATA

SHEET

Pre-Mixed Tile Grout
11. Toxicological Information
Chronic/Carcinogenicity
May contain trace amounts of chemicals that IARC classifies as possible carcinogens.
Teratogenicity (Birth Defects)
May contain trace amounts of chemicals that caused birth defects in animal studies. It did not cause harm to the
animal or fetus when applied on skin.
Reproductive Effects
May contain trace amounts of chemicals that caused birth defects in animal studies. It did not cause harm to the
animal or fetus when applied on skin.
Mutagenicity (Genetic Effects)
May contain trace amounts of chemicals that caused birth defects in animal studies. It did not cause harm to the
animal or fetus when applied on skin.
Ingredient(s) - Toxicological Data
Acrylic Copolymer
Oral >5000mg / kg - rat
12. Ecological Information
No Data Available...
13. Disposal Considerations
Dispose in accordance with applicable federal, state and local government regulations and industry standards.
RCRA Information
Not considered RCRA waste
14. Transport Information
DOT Shipping Label
Not Regulated
15. Regulatory Information
Ingredient(s) - State Regulations
Acrylic Copolymer
California - Proposition 65
Calcium Carbonate
New Jersey - Workplace Hazard
Pennsylvania - Workplace Hazard
Massachusetts - Hazardous Substance
16. Other Information
HMIS Rating
He a lth: 1
Fire : 0
Re a ctivity: 0
Personal Protection: B
Revision/Preparer Information
MSDS Preparer: GEORGE MARCINA
MSDS Preparer Phone Number: (562) 968-2980 ext 103
This MSDS Supersedes A Previous MSDS Dated: 04/20/2006

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MATERIAL SAFETY DATA

SHEET

Pre-Mixed Tile Grout
Disclaimer
THE INFORMATION PRESENTED HERE IS BELIEVED TO BE ACCURATE BUT IS NOT WARRANTED TO BE,
WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN
ADVANCE OF NEED, THAT THE INFORMATION IS CURRENT, APPLICABLE, AND SUITABLE TO THEIR
CIRCUMSTANCES.
CUSTOM BUILDING PRODUCTS
Printed Using MSDS Generator™ 2000

Page 5 of 5

MATERIAL SAFETY DATA

SHEET

White Dry Non-Sanded Grout
HMIS
HEALTH

1

FLAMMABILITY

0

REACTIVITY

0

PERSONAL

E

PROTECTION

1. Product And Company Identification
Supplier
CUSTOM BUILDING PRODUCTS
10400 Pioneer Blvd., Unit #3
Santa Fe Springs, CA 90670 UNITED STATES

Manufacturer
CUSTOM BUILDING PRODUCTS
10400 Pioneer Blvd., Unit #3
Santa Fe Springs, CA 90670 UNITED STATES

Company Contact: GEORGE MARCINA
Telephone Number: (562) 968-2980 Ext 103
FAX Number:
(562) 903-2697
E-Ma il: georgem@cbpmail.net
Web Site: www.custombuildingproducts.com

Company Contact: GEORGE MARCINA
Telephone Number: (562) 968-2980 Ext 103
FAX Number:
(562) 903-2697
E-Ma il: georgem@cbpmail.net
Web Site: www.custombuildingproducts.com

Supplier Emergency Contacts & Phone Number
GEORGE MARCINA: (562) 968-2980

Manufacturer Emergency Contacts & Phone Number
GEORGE MARCINA: (562) 968-2980

Issue Date: 04/20/2006
Product Name: White Dry Non-Sanded Grout
CAS Number: Not Established
Chemical Family: Mixture
Chemical Formula: Mixture
MSDS Number: 637
Product Code: 8012
2. Composition/Information On Ingredients
Ingredient
Name

CAS
Number

Calcium Carbonate
Portland Cement

Percent Of
Total Weight

1317-65-3

20 - 30

65997-15-1

70 - 80

3. Hazards Identification
Primary Routes(s) Of Entry
Inhalation, Skin Contac, Eye Contact, Ingestion
Eye Hazards
Irritant, severe eye irritation. May cause eye injury. Effects may be delayed.
Skin Hazards
Contains Portland cement and exposure to dry Portland cement may cause drying of skin with consequent mild
irritation. Prolonged contact with wet Portland cement may cause severe, potentially irreversible damage to the skin
in the form of chemical (caustic) burns.
Ingestion Hazards
Ingestion is not known to be harmful, however the product contains Portland cement which is caustic to mucus
tissue and should not be consumed.

Page 1 of 4

MATERIAL SAFETY DATA

SHEET

White Dry Non-Sanded Grout
3. Hazards Identification - Continued
Inhalation Hazards
Causes respiratory tract irritation. May cause nose, throat, and lung irritation. May cause delayed lung injury.
Chronic/Carcinogenicity Effects
May contain trace amounts of Silica sand, known Human Carcinogen (Category 1)
4. First Aid Measures
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Get
medical attention immediately if irritation develops and persists.
Skin
In case of contact, immediately flush skin with plenty of water for at least 15 minutes. Get medical attention
immediately if irritation (redness, rash, blistering) develops and persists.
Ingestion
DO NOT INDUCE VOMITING. If victim is fully conscious, give one or two cups of water or milk to drink. Get medical
attention immediately.
Inhalation
If inhaled, remove to fresh air. Consult a physician immediately if irritation persists. Do not give an unconscious
person anything to drink.
5. Fire Fighting Measures
Flash Point: N/A °F
Flash Point Method: N/A
Lower Explosive Limit: N/A
Upper Explosive Limit: N/A
6. Accidental Release Measures
Avoid generating dust. Sweep up and remove immediately.U se appropriate personal protective equipment (PPE).
OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS REGARDING NOTIFICATIONS OF ACCIDENTAL
RELEASES.
7. Handling And Storage
Handling And Storage Precautions
Use only with adequate ventilation.
Handling Precautions
Avoid creating dust. Avoid breathing dust. Avoid contact with skin and clothing. Avoid contact with eyes.
Storage Precautions
Keep dry until ready to use.
Work/Hygienic Practices
Use good personal hygiene. Wash thoroughly with soap and water after handling.
8. Exposure Controls/Personal Protection
Engineering Controls
Use with adequate ventilation.
Eye/Face Protection
Safety glasses with side shields or goggles recommended.

Page 2 of 4

MATERIAL SAFETY DATA

SHEET

White Dry Non-Sanded Grout
8. Exposure Controls/Personal Protection - Continued
Skin Protection
If hands or feet will be exposed, wear impervious gloves and/or boots.
Respiratory Protection
In case of inadequate ventilation and when exposed to dust above the recommended limits, wear a suitable
NIOSH-approved respirator.
Ingredient(s) - Exposure Limits
Calcium Carbonate
OSHA - PEL - TWA - 15mg/m3
Niosh - REL 10 mg/m3
ACGIH- TLV - 10 mg/m3
OSHA - PEL - TWA - 5 mg/m3
Portland Cement
OSHA - PEL - 5mg/m3
OSHA - PEL - TWA - 50mppcf
ACGIH - TLV - 10mg/m3
9. Physical And Chemical Properties
Appearance
Free flowing white powder.
Chemical Type: Mixture
Physical State: Solid
Boiling Point: N/A °F
Specific Gravity: 2.7
Vapor Density: N/A
Solubility: SLIGHT
Evaporation Rate: N/A
10. Stability And Reactivity
Sta bility: STABLE
Hazardous Polymerization: WILL NOT OCCUR.
Conditions To Avoid (Stability)
Avoid unintentional contact with water.
Incompatible Materials
Contains portland cement which, when wet, is highly alkali. As a result, it is incompatible with acids, ammonium
salts, aluminum and other alkali and alkaline earth metals.
11. Toxicological Information
Chronic/Carcinogenicity
May contain traces of Silica sand, known human carcinogen.
12. Ecological Information
No Data Available...
13. Disposal Considerations
Dispose in accordance with applicable federal, state and local government regulations.
RCRA Information
Not considered RCRA Hazardous Waste.

Page 3 of 4

MATERIAL SAFETY DATA

SHEET

White Dry Non-Sanded Grout
14. Transport Information
DOT Shipping Label
NOT REGULATED
15. Regulatory Information
SARA Hazard Classes
Chronic Health Hazard
SARA Section 313 Notification
This product does not contains toxic chemicals subject to the reporting requirements of Section 313 of the
Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372.
State Regulations
Cal EPA -Toxic Hot Spots - OEHHA - REL - 3 micrograms /m3
Ingredient(s) - State Regulations
Calcium Carbonate
Pennsylvania - Workplace Hazard
Portland Cement
New Jersey - Workplace Hazard
Pennsylvania - Workplace Hazard
16. Other Information
HMIS Rating
He a lth: 1
Fire : 0
Re a ctivity: 0
Personal Protection: E
Revision/Preparer Information
MSDS Preparer: GEORGE MARCINA
MSDS Preparer Phone Number: (562) 968-2980 ext 103
This MSDS Supersedes A Previous MSDS Dated: 04/10/2006
Disclaimer
Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no
representations as to the accuracy or completeness of the information contained therein, and assume no
responsibility regarding the suitablility of this information for the user's intended purposes or for the consequences of
its use. Each individual should make a determination as to the suitability of the information for their particular
purposes(s).
CUSTOM BUILDING PRODUCTS
Printed Using MSDS Generator™ 2000

Page 4 of 4

Material Safety Data Sheet
F
S

1. Chemical Product and Company Identification
DESCRIPTION:
PRODUCT TYPE:
APPLICATION:

•

ELMER'S CARPENTERS WOOD GLUE
PVAC BASED ADHESIVE
FOR PRODUCT CODES SEE SECTION 16

Manufacturer/Supplier Information
MSDS Prepared by:
Elmer's Products, Inc.
Emergency Phone Number
1 Easton Oval
Poison Control Center
Columbus, OH 43219
888-516-2502
For additional health, safety or regulatory information, call 888-435-6377
Call 1-800-848-9400 to place an order or request additional MSDSs.

2. Composition, Information on Ingredients
No hazardous ingredients known to company.

3. Hazards Identification

3.1 Emergency Overview
Appearance
Odor
Not an immediate health hazard.

•

HMIS Rating

Light yellow liquid
Mild acetic aroma

HEALTH = 0 (minimal)
FLAMMABILITY = 0 (minimal)
REACTIVITY = 0 (minimal)

3.2 Potential Health Effects

•

Immediate Hazards
INGESTION:
INHALATION:
SKIN:
EYES:

•

No
No
No
No

hazards
hazards
hazards
hazards

known
known
known
known

to
to
to
to

company.
company.
company.
company.

Delayed Hazards
None of the components present in this product at concentrations equal
to or greater than 0.1% have been listed by NTP, classified by IARC,
nor regulated by OSHA as a carcinogen.

4. First Aid Measures
INGESTION:

EYES:

If accidentally swallowed, dilute by drinking large
quantities of water. Immediately contact poison control
center or hospital emergency room for any other
additional treatment directions.
Immediately flush eyes with plenty of water. Call a
physician if irritation persists.

5. Fire Fighting Measures
Autoignition Temperature
Not available
Upper/Lower Flammable Limits
Not applicable
Up/Lower Explosive Limits, % by Vol Not applicable
Flash Point
Not applicable
Will not burn unless water has evaporated. Dried material may
burn.
In case of fire, water should be used to keep fire-exposed
containers cool.

6. Accidental Release Measures

Soak up with absorbent material and remove to a chemical disposal
area. Prevent entry into natural bodies of water.

7. Handling and Storage

7.1 Handling
Handle in accordance with good industrial hygiene and safety
practices.

7.2 Storage
Keep from freezing.
Store in a cool, dry place.
Keep containers tightly closed.

8. Exposure Controls/Personal Protection

8.1 Exposure Controls
No special control measures necessary under normal conditions of use.

8.2 Personal Protection
No special protection necessary.

8.3 Exposure Guidelines
None established

9. Physical and Chemical Properties
Percent Volatiles
pH @ 25 C
Specific Gravity
Appearance

54.5
5.0
1.08
Light yellow liquid

Autoignition Temperature
Boiling Point
Vapor Density (Air=1)
Vapor Pressure, mm Hg @ 20 C
Evaporation Rate (Butyl Acetate=1)
Upper/Lower Flammable Limits
Up/Lower Explosive Limits, % by Vol
Flash Point
Freezing Point
Odor
Odor Threshold, ppm
Solubility in Water
Coefficient of Water/Oil Distrib.

Not available
100°C (212°F)
<1
17.5
<1
Not applicable
Not applicable
Not applicable
0°C (32°F)
Mild acetic aroma
Not available
Dispersible
Not available

10. Stability and Reactivity
Normally stable as defined in NFPA 704-12(4-3.1).

•

Incompatibilities:
Strong acids and alkaline materials.

•

Decomposition products may include:
CO, CO2.

•

Hazardous polymerization:
Will not occur.

•

Other Hazards:
None known to company.

11. Toxicological Information
INGESTION:
INHALATION:

SKIN
ABSORPTION:

A similar product was found to be non-toxic orally when
tested as described in 16 CFR Part 1500.3(c)(1) and (2).
A similar product was found to be non-toxic by
inhalation when tested as described in 16 CFR Part
1500.3 (c)(1) and (2).
A similar product was found to be non-toxic dermally
when tested as described in 16 CFR Part 1500.3 (c)(1)

SKIN:
EYES:

and (2).
A similar
described
A similar
described

product was not an irritant when tested as
in 16 CFR Part 1500.41.
product was not an irritant when tested as
in 16 CFR Part 1500.42.

12. Ecological Information
Not determined.

13. Disposal Considerations
Recover free liquid. Absorb residue and dispose of according to
local, state/provincial, and federal requirements.

14. Transport Information

14.1 U.S. Department of Transportation (DOT)
The data provided in this section is for information only and may not
be specific to your package size. You will need to apply the
appropriate regulations to properly classify your shipment for
transportation.
Non-Regulated.

14.2 Canadian Transportation of Dangerous Goods (TDG)
Non-Regulated.

15. Regulatory Information (Selected Regulations)

15.1 U.S. Federal Regulations

•

OSHA Hazard Communication Standard 29CFR1910.1200

This material is not a "health hazard" or a "physical hazard" as
determined when reviewed according to the requirements of the
Occupational Safety and Health Administration 29 CFR Part 1910.1200
"Hazard Communication" Standard.

•

SARA Title III: Section 311/312
Does not meet any hazard category

•

SARA Title III Section 313 and 40 CFR Part 372
This product contains the following toxic chemical(s) subject to the
reporting requirements of Section 313 of Title III of the Superfund
Amendments and Reauthorization Act of 1986, and Subpart C-Supplier
Notification Requirement of 40 CFR Part 372.
None required per SARA TITLE III SECTION 313.

•

TSCA Section 8(b) Inventory
All reportable chemical substances are listed on the TSCA Inventory.
We rely on certifications of compliance from our suppliers for
chemical substances not manufactured by us.

15.2 Canadian Regulations

•

Workplace Hazardous Materials Information System (WHMIS)
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulation (CPR) and the MSDS
contains all the information required by the CPR.
Not a controlled product

•

Canadian Environmental Protection Act (CEPA)
All reportable chemical substances are listed on the Domestic
Substances List (DSL) or otherwise comply with CEPA new substance
notification requirements.

•

National Pollutant Release Inventory (NPRI)

This product contains the following chemical(s) subject to the
reporting requirements of the Canadian Environmental Protection Act
(CEPA) subsection 16(1), National Pollutant Release Inventory.
None required.

16. Other Information
AP (Non-Toxic): Products bearing the AP (Non-Toxic) Product Seal of
The Art & Creative Materials Institute, Inc. (ACMI) are certified in a
program of toxicological evaluation by a medical expert to contain no
materials in sufficient quantities to be toxic or injurious to humans
or to cause acute or chronic health problems. This program is
reviewed by ACMI's Toxicological Advisory Board. These products are
certified by ACMI to be labeled in accordance with the chronic hazard
labeling standard, ASTM D-4236 and Federal Law, P.L. 100-695. In
addition, there is no physical hazard as defined within 29 CFR Part
1910.1200(c).
MSDS covers items:
U.S.:
E614, E700, E701, E702, E704, E705, E706, E970, E980,
E1367, E1825, E1850
Canada:
60613, 60614, 60615, 60616, 60617, 60618, 60619

•

User's Responsibility
The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace
Hazardous Materials Information System (WHMIS) require that the information
contained on these sheets be made available to your workers. Educate and
train your workers regarding OSHA and WHMIS precautions. Instruct your
workers to handle this product properly. Consult with appropriate experts
to guard against hazards associated with use of this product and its
ingredients.

•

Disclaimer
SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE
MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product
shall conform to contracted specifications, and that the product does not
infringe any valid United States or Canadian patent. No claim of any kind
shall be greater in amount than the purchase price of the quantity of
product in respect of which damages are claimed. In no event shall Seller
be liable for incidental or consequential damages, whether Buyer's claim is
based on contract, breach of warranty, negligence or otherwise.

CURRENT ISSUE: 27-JUN-06
PREVIOUS ISSUE: 13-JAN-05

Page 1 of 7

Material
Safety
Data
Sheet

24 Hour Emergency Phone Numbers:
Medical: 1-800-327-3874
1-513-558-5111
Transportation:
1-800-535-5053
1-352-323-3500

NOTE: National Response Center emergency numbers to be used
only in the event of chemical emergencies involving a spill, leak,
fire, exposure or accident involving chemicals.

IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or
disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been
prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section
16.

Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en español a su solicitud.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.

Product Name:
Product UPC
Number:

FAST N FINAL PREMIUM
7079812140, 7079812141, 7079812142,
7079812143, 7079812145, 7079812146,
7079812147, 7079812148, 7079812149,
7079823030, 7079823050, 7079823090,
7079871354
Product Use/Class: RTU Spackle/Wallboard Repair
Manufacturer:
DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888 -327-8477 (non-emergency matters)

Revision Date: 01/31/2006
Supercedes:
07/08/2003

MSDS Number: 00010410001

Section 2 - Composition / Information On Ingredients
Chemical Name
Sodium silicate glass
Ethylene glycol
Vinyl acetate
Formaldehyde
Acetaldehyde

CASRN
1344 -09-8
107-21-1
108-05-4
50-00-0
75-07-0

WT%

ACGIH TWA

10-30
0.5-1.5
0.1-1.0
<0.004
<0.002

10 MGM3
N.E.
10 PPM
N.E.
N.E.

ACGIH
STEL
N.E.
N.E.
15 PPM
N.E.
N.E.

ACGIH CEIL OSHA TWA OSHA STEL OSHA CEIL Skin
N.E.
100 MGM3
N.E.
0.3 PPM
25 PPM

5 MGM3
N.E.
N.E.
0.75 PPM
200 PPM

N.E.
N.E.
N.E.
2 PPM
N.E.

N.E.
N.E.
N.E.
N.E.
N.E.

No
No
No
No
No

Exposure Notes:

50-00-0 Formaldehyde is a specially regulated substance for which an OSHA chemical-specific
exposure standard exits. Detailed information regarding this substance may be found in 29 CFR
1910.1048. Medical surveillance information regarding this substance may be found in Appendix C to
29 CFR 1910.1048.
Important:

Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits
may vary between states.

Page 2 of 7
Note:

An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the
extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment,
engineering controls or work practices

Section 3 - Hazards Identification
Emergency Overview: A white to off-white paste with a slight sweet odor. CAUTION! May cause eye, skin,
nose, throat and respiratory tract irritation. This product contains ethylene glycol.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: May cause eye irritation.
Effects Of Overexposure - Skin Contact: May cause skin irritation. May cause dry skin.
Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation may cause irritation to the respiratory tract
(nose, mouth, mucous membranes). Inhalation of dust may cause lung damage or other adverse pulmonary and
respiratory effects.
Effects Of Overexposure - Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and
diarrhea.
Effects Of Overexposure - Chronic Hazards:
Formaldehyde vapor is a known animal carcinogen according to OSHA and NTP and is considered possibly
carcinogenic to humans by inhalation. The International Agency for Research on Cancer considers formaldehyde
to be a human carcinogen.

Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Studies have
shown that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory
animals. Ethylene glycol has been shown to cause birth defects in laboratory animals. This product contains vinyl
acetate which is classified as a class 2B carcinogen by IARC. Vinyl acetate was found to cause cancer in the
respiratory tract of laboratory animals. There is no evidence that vinyl acetate causes cancer in humans. The
IARC published a monograph on vinyl acetate (1995). In this monograph, IARC indicates "there is inadequate
evidence in humans for carcinogenicity of vinyl acetate. There is limited evidence in experimental animals for the
carcinogenicity of vinyl acetate." Normally, this lack of conclusive evidence would place a substance in the IARC 3
classification (not classified as a human carcinogen). However, because vinyl acetate is metabolized to
acetaldehyde, which has an IARC 2B (possibly carcinogenic to humans) classification, it also has been listed
under Category 2B. Prolonged, repeated, or high exposures may cause weakness and depression of the central
nervous system.
Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation
Medical Conditions which May be Aggravated by Exposure: If dry sanded, asthma and asthma-like conditions
may worsen from prolonged or repeated exposure to dust.

Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
Get medical attention immediately.
First Aid - Skin Contact: Wash off immediately with soap and plenty of water.
First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If
continued breathing difficulty is experienced, get medical attention immediately.

Page 3 of 7
First Aid - Ingestion: Call a physician or Poison Control Center immediately. Do not induce vomiting.
Note to Physician: None.
COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arises from any of the
above routes of entry.

Section 5 - Fire Fighting Measures
Flash Point, F: Greater than 200 degrees
Method: (Seta Closed Cup)

Lower Explosive Limit, %: Not Established
Upper Explosive Limit, %: Not Established

Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam
Unusual Fire And Explosion Hazards: None known.
Special Firefighting Procedures: Cool fire -exposed containers using water spray.

Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in
Section 8. Scrape up dried material and place into containers.

Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! Do not breathe vapors. Wash thoroughly after handling. Avoid
excessive heat and handling. Do not breathe dust. While dry sanding, use of a NIOSH-approved dust mask is
recommended. Avoid contact with eyes, skin and clothing. Removal of this product after use will result in the
generation of Dust. If dry-sanded, exposure to dust may result in the build -up of material in eyes, ears, nose, and
mouth which may cause irritation.
Storage: Store away from caustics and oxidizers. Do not store at temperatures above 120 degrees F. Keep
tightly closed. Avoid excessive heat and freezing.

Section 8 - Exposure Controls / Personal Protection
Precautionary Measures: Please refer to other sections and subsections of this MSDS.
Engineering Controls: Local ventilation of emission sources may be necessary to maintain ambient
concentrations below recommended exposure limits. Wet sanding is recommended to avoid generation of dust.
Prevent build-up of dust and vapors by opening windows and doors or use other means to ensure fresh air entry
during application, drying and sanding.
Respiratory Protection: A respiratory protection program that meets the OSHA 1910.134 and ANSI Z88.2
requirements must be followed whenever workplace conditions warrant a respirator's use. If concentrations
exceed the exposure limits specified, use of a NIOSH-approved supplied air respirator is recommended. Where
the protection factor is exceeded, use of a Self Contained Breathing Apparatus (SCBA) may be necessary. Use
an approved NIOSH/OSHA respirator if dry sanded.
Skin Protection: Wear gloves with repeated or prolonged use.
Eye Protection: Safety glasses with side-shields.

Page 4 of 7
Other protective equipment: Not required under normal use.
Hygienic Practices: Remove and wash contaminated clothing before re-use.

Section 9 - Physical And Chemical Properties
Boiling Range:
Odor:
Appearance:
Solubility in H2O:
Freeze Point:
Vapor Pressure:
Physical State:

Not Established
Slight Sweet
White to Off-White
Not Established
Not Established
Not Established
Paste

Vapor Density:
Odor Threshold:
Evaporation Rate:
Specific Gravity:
pH:
Viscosity:

Not Established
Not Established
Not Established
0.478
Between 7.0 and 12.0
Not Established

When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined
experimentally.
(See section 16 for abbreviation legend)

Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Strong oxidizing agents. Strong bases.
Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under normal conditions.

Section 11 - Toxicological Information
Product LD50: Not Established
CASRN
Chemical Name
107-21-1
108-05-4
50-00-0
75-07-0

Product LC50: Not Established
LD50
LC50

Ethylene glycol
Vinyl acetate
Formaldehyde
Acetaldehyde

Rat:4700 mg/kg
-------------------------------------

Rat:10876 mg/kg
Rat:11400 mg/m3/4H
Rat:203 mg/m3
Rat:13300 ppm/4H

WT%
0.5-1.5
0.1-1.0
<0.004
<0.002

Carcinogenicity:
CAS No.

Chemical Name

108-05-4

Vinyl acetate

50-00-0

Formaldehyde

75-07-0

Acetaldehyde

ACGIH
Confirmed animal
carcinogen with
unknown relevance to
humans.
Suspected human
carcinogen.
Confirmed animal
carcinogen with
unknown relevance to
humans.

OSHA

IARC

NTP

WT%

Not Listed.

Possible carcinogen.

Not Listed.

0.1-1.0

Potential cancer
hazard.

Human carcinogen.

Anticipated
carcinogen.

<0.004

Not Listed.

Possible carcinogen.

Anticipated
carcinogen.

<0.002

Significant Data with Possible Relevance to Humans: This product contains trace amounts of free
formaldehyde. OSHA and NTP identify formaldehyde as a potential carcinogen. IARC identifies formaldehyde as
a human carcinogen. Formaldehyde has been shown to cause mutations in a variety of in-vitro test systems, the

Page 5 of 7
significance of which to humans is unknown. In a two-year inhalation study, rats showed carcinogenic effects in
the respiratory system at 15 ppm of formaldehyde. There should be minimal risk when used with ventilation
adequate to keep the atmospheric concentration of formaldehyde below the recommended exposure limits.
Maintain adequate ventilation to prevent exposure above current OSHA / ACGIH exposure limits. Workplace
monitoring of the air to define formaldehyde exposure levels may be necessary.

Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.

Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and
Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste
disposal is with the owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): None

Section 14 - Transportation Information
DOT Proper Shipping
Name:
DOT Technical Name:
DOT Hazard Class:

Not Regulated

Packing Group:

N.A.

N.A.
N.A.

Hazard Subclass:
DOT UN/NA Number:

N.A.
None

Note: The shipping information provided is applicable for domestic ground transport only. Different categorization
may apply if shipped via other modes of transportation and/or to non-domestic destinations.

Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and
312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name
Ethylene glycol
Vinyl acetate

CAS Number
107-21-1
108-05-4

WT%
0.5-1.5
0.1-1.0

Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if

Page 6 of 7
exported from the United States:
None.

U.S. State Regulations
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product:
Chemical Name

CAS Number

Water
Acetic acid, vinyl ester, polymer
Sodium Borate; Boric Acid, Sodium Salt

7732 -18-5
Proprietary
7775 -19-1

WT%
30-60
10-30
1-5

Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%:
Chemical Name

CAS Number

Water
Acetic acid, vinyl ester, polymer
Sodium Borate; Boric Acid, Sodium Salt

7732 -18-5
Proprietary
7775 -19-1

WT%
30-60
10-30
1-5

California Proposition 65:
Warning: The following ingredients present in the product are known to the State of California to cause cancer:
Chemical Name
Formaldehyde
Acetaldehyde

CAS Number
50-00-0
75-07-0

Definition

Date Listed

WT%

Carcinogenic.
Carcinogenic.

Listed: January 1, 1988
Listed: April 1, 1988

<0.004
<0.002

Warning: The following ingredients present in the product are known to the State of California to cause birth
defects or other reproductive harm:
None.

Section 16 - Other Information
HMIS Ratings:
Health: 1

Flammability: 1

Reactivity: 0

VOLATILE ORGANIC COMPOUNDS, GR/LTR: 9.5

LB/GAL: 0.1

Personal Protection: X
WT%: 1.485

REASON FOR REVISION: Periodic Update
Legend:

N.A. – Not Applicable

ACGIH – American Conference of Governmental Industrial Hygienists

N.E. – Not Established

SARA – Superfund Amendments and Reauthorization Act of 1986

N.D. – Not Determined

NJRTK – New Jersey Right-to-Know Law

VOC – Volatile Organic Compound

OSHA – Occupational Safety and Health Administration

Page 7 of 7
PEL – Permissible Exposure Limit

HMIS – Hazardous Materials Identification System

TLV – Threshold Limit Value

NTP – National Toxicology Program

STEL – Short Term Exposure Limit

CEIL – Ceiling Exposure Limit

LD50 – Lethal Dose 50

LC50 – Lethal Concentration 50

F – Degree Fahrenheit

C – Degree Celsius

MSDS – Material Safety Data Sheet

CASRN – The Chemical Abstracts Service Registry Number

DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as
typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF
FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS
MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE
INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary
handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the
recommendations with due consideration for the specific context of the intended use and (ii) determine if they are
appropriate.


Page 1 of 7

Material
Safety
Data
Sheet

24 Hour Emergency Phone Numbers:
Medical: 1-800-327-3874
1-513-558-5111
Transportation:
1-800-535-5053
1-352-323-3500

NOTE: National Response Center emergency numbers to be used
only in the event of chemical emergencies involving a spill, leak,
fire, exposure or accident involving chemicals.

IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or
disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been
prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section
16.

Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en español a su solicitud.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.

Product Name:
Product UPC
Number:

FAST N FINAL PREMIUM
7079812140, 7079812141, 7079812142,
7079812143, 7079812145, 7079812146,
7079812147, 7079812148, 7079812149,
7079823030, 7079823050, 7079823090,
7079871354
Product Use/Class: RTU Spackle/Wallboard Repair
Manufacturer:
DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888 -327-8477 (non-emergency matters)

Revision Date: 01/31/2006
Supercedes:
07/08/2003

MSDS Number: 00010410001

Section 2 - Composition / Information On Ingredients
Chemical Name
Sodium silicate glass
Ethylene glycol
Vinyl acetate
Formaldehyde
Acetaldehyde

CASRN
1344 -09-8
107-21-1
108-05-4
50-00-0
75-07-0

WT%

ACGIH TWA

10-30
0.5-1.5
0.1-1.0
<0.004
<0.002

10 MGM3
N.E.
10 PPM
N.E.
N.E.

ACGIH
STEL
N.E.
N.E.
15 PPM
N.E.
N.E.

ACGIH CEIL OSHA TWA OSHA STEL OSHA CEIL Skin
N.E.
100 MGM3
N.E.
0.3 PPM
25 PPM

5 MGM3
N.E.
N.E.
0.75 PPM
200 PPM

N.E.
N.E.
N.E.
2 PPM
N.E.

N.E.
N.E.
N.E.
N.E.
N.E.

No
No
No
No
No

Exposure Notes:

50-00-0 Formaldehyde is a specially regulated substance for which an OSHA chemical-specific
exposure standard exits. Detailed information regarding this substance may be found in 29 CFR
1910.1048. Medical surveillance information regarding this substance may be found in Appendix C to
29 CFR 1910.1048.
Important:

Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits
may vary between states.

Page 2 of 7
Note:

An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the
extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment,
engineering controls or work practices

Section 3 - Hazards Identification
Emergency Overview: A white to off-white paste with a slight sweet odor. CAUTION! May cause eye, skin,
nose, throat and respiratory tract irritation. This product contains ethylene glycol.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: May cause eye irritation.
Effects Of Overexposure - Skin Contact: May cause skin irritation. May cause dry skin.
Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation may cause irritation to the respiratory tract
(nose, mouth, mucous membranes). Inhalation of dust may cause lung damage or other adverse pulmonary and
respiratory effects.
Effects Of Overexposure - Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and
diarrhea.
Effects Of Overexposure - Chronic Hazards:
Formaldehyde vapor is a known animal carcinogen according to OSHA and NTP and is considered possibly
carcinogenic to humans by inhalation. The International Agency for Research on Cancer considers formaldehyde
to be a human carcinogen.

Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Studies have
shown that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory
animals. Ethylene glycol has been shown to cause birth defects in laboratory animals. This product contains vinyl
acetate which is classified as a class 2B carcinogen by IARC. Vinyl acetate was found to cause cancer in the
respiratory tract of laboratory animals. There is no evidence that vinyl acetate causes cancer in humans. The
IARC published a monograph on vinyl acetate (1995). In this monograph, IARC indicates "there is inadequate
evidence in humans for carcinogenicity of vinyl acetate. There is limited evidence in experimental animals for the
carcinogenicity of vinyl acetate." Normally, this lack of conclusive evidence would place a substance in the IARC 3
classification (not classified as a human carcinogen). However, because vinyl acetate is metabolized to
acetaldehyde, which has an IARC 2B (possibly carcinogenic to humans) classification, it also has been listed
under Category 2B. Prolonged, repeated, or high exposures may cause weakness and depression of the central
nervous system.
Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation
Medical Conditions which May be Aggravated by Exposure: If dry sanded, asthma and asthma-like conditions
may worsen from prolonged or repeated exposure to dust.

Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
Get medical attention immediately.
First Aid - Skin Contact: Wash off immediately with soap and plenty of water.
First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If
continued breathing difficulty is experienced, get medical attention immediately.

Page 3 of 7
First Aid - Ingestion: Call a physician or Poison Control Center immediately. Do not induce vomiting.
Note to Physician: None.
COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arises from any of the
above routes of entry.

Section 5 - Fire Fighting Measures
Flash Point, F: Greater than 200 degrees
Method: (Seta Closed Cup)

Lower Explosive Limit, %: Not Established
Upper Explosive Limit, %: Not Established

Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam
Unusual Fire And Explosion Hazards: None known.
Special Firefighting Procedures: Cool fire -exposed containers using water spray.

Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in
Section 8. Scrape up dried material and place into containers.

Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! Do not breathe vapors. Wash thoroughly after handling. Avoid
excessive heat and handling. Do not breathe dust. While dry sanding, use of a NIOSH-approved dust mask is
recommended. Avoid contact with eyes, skin and clothing. Removal of this product after use will result in the
generation of Dust. If dry-sanded, exposure to dust may result in the build -up of material in eyes, ears, nose, and
mouth which may cause irritation.
Storage: Store away from caustics and oxidizers. Do not store at temperatures above 120 degrees F. Keep
tightly closed. Avoid excessive heat and freezing.

Section 8 - Exposure Controls / Personal Protection
Precautionary Measures: Please refer to other sections and subsections of this MSDS.
Engineering Controls: Local ventilation of emission sources may be necessary to maintain ambient
concentrations below recommended exposure limits. Wet sanding is recommended to avoid generation of dust.
Prevent build-up of dust and vapors by opening windows and doors or use other means to ensure fresh air entry
during application, drying and sanding.
Respiratory Protection: A respiratory protection program that meets the OSHA 1910.134 and ANSI Z88.2
requirements must be followed whenever workplace conditions warrant a respirator's use. If concentrations
exceed the exposure limits specified, use of a NIOSH-approved supplied air respirator is recommended. Where
the protection factor is exceeded, use of a Self Contained Breathing Apparatus (SCBA) may be necessary. Use
an approved NIOSH/OSHA respirator if dry sanded.
Skin Protection: Wear gloves with repeated or prolonged use.
Eye Protection: Safety glasses with side-shields.

Page 4 of 7
Other protective equipment: Not required under normal use.
Hygienic Practices: Remove and wash contaminated clothing before re-use.

Section 9 - Physical And Chemical Properties
Boiling Range:
Odor:
Appearance:
Solubility in H2O:
Freeze Point:
Vapor Pressure:
Physical State:

Not Established
Slight Sweet
White to Off-White
Not Established
Not Established
Not Established
Paste

Vapor Density:
Odor Threshold:
Evaporation Rate:
Specific Gravity:
pH:
Viscosity:

Not Established
Not Established
Not Established
0.478
Between 7.0 and 12.0
Not Established

When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined
experimentally.
(See section 16 for abbreviation legend)

Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Strong oxidizing agents. Strong bases.
Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under normal conditions.

Section 11 - Toxicological Information
Product LD50: Not Established
CASRN
Chemical Name
107-21-1
108-05-4
50-00-0
75-07-0

Product LC50: Not Established
LD50
LC50

Ethylene glycol
Vinyl acetate
Formaldehyde
Acetaldehyde

Rat:4700 mg/kg
-------------------------------------

Rat:10876 mg/kg
Rat:11400 mg/m3/4H
Rat:203 mg/m3
Rat:13300 ppm/4H

WT%
0.5-1.5
0.1-1.0
<0.004
<0.002

Carcinogenicity:
CAS No.

Chemical Name

108-05-4

Vinyl acetate

50-00-0

Formaldehyde

75-07-0

Acetaldehyde

ACGIH
Confirmed animal
carcinogen with
unknown relevance to
humans.
Suspected human
carcinogen.
Confirmed animal
carcinogen with
unknown relevance to
humans.

OSHA

IARC

NTP

WT%

Not Listed.

Possible carcinogen.

Not Listed.

0.1-1.0

Potential cancer
hazard.

Human carcinogen.

Anticipated
carcinogen.

<0.004

Not Listed.

Possible carcinogen.

Anticipated
carcinogen.

<0.002

Significant Data with Possible Relevance to Humans: This product contains trace amounts of free
formaldehyde. OSHA and NTP identify formaldehyde as a potential carcinogen. IARC identifies formaldehyde as
a human carcinogen. Formaldehyde has been shown to cause mutations in a variety of in-vitro test systems, the

Page 5 of 7
significance of which to humans is unknown. In a two-year inhalation study, rats showed carcinogenic effects in
the respiratory system at 15 ppm of formaldehyde. There should be minimal risk when used with ventilation
adequate to keep the atmospheric concentration of formaldehyde below the recommended exposure limits.
Maintain adequate ventilation to prevent exposure above current OSHA / ACGIH exposure limits. Workplace
monitoring of the air to define formaldehyde exposure levels may be necessary.

Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.

Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and
Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste
disposal is with the owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): None

Section 14 - Transportation Information
DOT Proper Shipping
Name:
DOT Technical Name:
DOT Hazard Class:

Not Regulated

Packing Group:

N.A.

N.A.
N.A.

Hazard Subclass:
DOT UN/NA Number:

N.A.
None

Note: The shipping information provided is applicable for domestic ground transport only. Different categorization
may apply if shipped via other modes of transportation and/or to non-domestic destinations.

Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and
312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name
Ethylene glycol
Vinyl acetate

CAS Number
107-21-1
108-05-4

WT%
0.5-1.5
0.1-1.0

Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if

Page 6 of 7
exported from the United States:
None.

U.S. State Regulations
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product:
Chemical Name

CAS Number

Water
Acetic acid, vinyl ester, polymer
Sodium Borate; Boric Acid, Sodium Salt

7732 -18-5
Proprietary
7775 -19-1

WT%
30-60
10-30
1-5

Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%:
Chemical Name

CAS Number

Water
Acetic acid, vinyl ester, polymer
Sodium Borate; Boric Acid, Sodium Salt

7732 -18-5
Proprietary
7775 -19-1

WT%
30-60
10-30
1-5

California Proposition 65:
Warning: The following ingredients present in the product are known to the State of California to cause cancer:
Chemical Name
Formaldehyde
Acetaldehyde

CAS Number
50-00-0
75-07-0

Definition

Date Listed

WT%

Carcinogenic.
Carcinogenic.

Listed: January 1, 1988
Listed: April 1, 1988

<0.004
<0.002

Warning: The following ingredients present in the product are known to the State of California to cause birth
defects or other reproductive harm:
None.

Section 16 - Other Information
HMIS Ratings:
Health: 1

Flammability: 1

Reactivity: 0

VOLATILE ORGANIC COMPOUNDS, GR/LTR: 9.5

LB/GAL: 0.1

Personal Protection: X
WT%: 1.485

REASON FOR REVISION: Periodic Update
Legend:

N.A. – Not Applicable

ACGIH – American Conference of Governmental Industrial Hygienists

N.E. – Not Established

SARA – Superfund Amendments and Reauthorization Act of 1986

N.D. – Not Determined

NJRTK – New Jersey Right-to-Know Law

VOC – Volatile Organic Compound

OSHA – Occupational Safety and Health Administration

Page 7 of 7
PEL – Permissible Exposure Limit

HMIS – Hazardous Materials Identification System

TLV – Threshold Limit Value

NTP – National Toxicology Program

STEL – Short Term Exposure Limit

CEIL – Ceiling Exposure Limit

LD50 – Lethal Dose 50

LC50 – Lethal Concentration 50

F – Degree Fahrenheit

C – Degree Celsius

MSDS – Material Safety Data Sheet

CASRN – The Chemical Abstracts Service Registry Number

DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as
typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF
FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS
MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE
INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary
handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the
recommendations with due consideration for the specific context of the intended use and (ii) determine if they are
appropriate.


|-------------------------------------------------------|
| M A T E R I A L
S A F E T Y
D A T A
S H E E T |
|-------------------------------------------------------|
|-------------------------------------------------------------------------|
|
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
|
|-------------------------------------------------------------------------|
PRODUCT NAME
: WALLBOARD JOINT COMPOUND RTU
UPC NUMBER
: 7079810100, 7079810102
PRODUCT USE/CLASS
: Joint Compound
MANUFACTURER:
DAP INC.
2400 BOSTON STREET
BALTIMORE, MD 21224

24 HOUR EMERGENCY:
TRANSPORTATION: 1-800-535-5053 (352-323-3500)
MEDICAL
: 1-800-327-3874 (513-558-5111)

PREPARE DATE: 12/23/1999
GENERAL INFORMATION:
REVISION NO.: 9
DAP INC. : 1-888-DAP-TIPS (1-888-327-8477)
REVISION DATE: 07/28/2003
|-------------------------------------------------------------------------|
|
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
|
|-------------------------------------------------------------------------|
ITEM
------------ CHEMICAL NAME ------------- CAS NUMBER
RANGE WT/WT %
--------------------------------------------------------------------------01
Mica
12001-26-2
1.0-5.0 %
02
Calcium Carbonate
1317-65-3
60.0-65.0 %
03
Crystalline Silica
14808-60-7
0.1-0.5 %
04
Attapulgite(polygorskite)
12174-11-7
0.1-5.0 %
---------------------- EXPOSURE LIMITS -------------------ACGIH
OSHA
COMPANY
ITEM TLV-TWA
TLV-STEL
PEL-TWA
PEL-CEILING TLV-TWA
SKIN
--------------------------------------------------------------------------01
3 mg/m3-dust N.E.
3 mg/m3-dust N.E.
N.E.
NO
02
10 mg/m3
N.E.
**
N.E.
N.E.
NO
03
0.05 mg/m3* N.E.
10 mg/m3dust N.E.
N.E.
NO
04
N.E.
N.E.
N.E.
N.E.
N.E.
NO
(See Section 16 for abbreviation legend)
* The 2001 ACGIH Threshold Limit Values for Chemical Substances and
Physical Agents lists the median Respirable Particulate Mass (RPM) point
for crystalline silica at 4.0 microns in terms of the particle’s
aerodynamic diameter.
** 10 mg/m3 / (% SiO2 + 2): Both concentration and percent quartz for the
application of this limit are to be determined from the fraction passing a
size selector with the following characteristics
|-------------------------------------------------------------------------|
| Aerodynamic diameter (unit density sphere) | Percent passing selector |
|-------------------------------------------------------------------------|
|2
|90
|
|2.5
|75
|
|3.5
|50
|
|5.0
|25
|
|10
|0
|
|-------------------------------------------------------------------------|
Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor
OSHA Final Rule Limits (CFR 29 1910.1000); limits may vary between states.
Remaining ingredients are not considered hazardous per the OSHA Hazard
Communication Standard.
(Continued on Page 2)
---------------------------------------------------------------------------

Product Name: WALLBOARD JOINT COMPOUND RTU
Revision Date: 07/28/2003
Page 2
|-------------------------------------------------------------------------|
|
SECTION 3 - HAZARDS IDENTIFICATION
|
|-------------------------------------------------------------------------|
POTENTIAL HEALTH EFFECTS:
EFFECTS OF OVEREXPOSURE - EYE CONTACT:

May cause eye irritation.

EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
EFFECTS OF OVEREXPOSURE - INHALATION:
respiratory tract.
EFFECTS OF OVEREXPOSURE - INGESTION:

May dry skin.

Vapor may irritate nose and upper
None known.

EFFECTS OF OVER EXPOSURE – CHRONIC HAZARDS
The International Agency for Research on Cancer (IARC)has determined that
crystalline silica in the form of quartz or cristobalite that is inhaled
from occupational sources is carcinogenic to humans (Group 1– carcinogenic
to humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic
Fibres (published in June 1997) in conjunction with the use of these
materials. The National Toxicology Program (NTP) classifies respirable
crystalline silica as known to be a human carcinogen. Refer to the 9th
Report on Carcinogens (2000). The American Conference of Governmental
Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a
suspected human carcinogen (A2).
Breathing dust containing respirable crystalline silica may not cause
noticeable injury or illness even though permanent lung damage may be
occurring. Inhalation of dust may have the following serious chronic health
effects: Excessive inhalation of respirable dust can cause pneumoconiosis,
a respiratory disease, which can result in delayed, progressive, disabling
and sometimes fatal lung injury. Symptoms include cough, shortness of
breath, wheezing, non-specific chest illness and reduced pulmonary
function. Smoking exacerbates this disease. Individuals with pneumoconiosis
are predisposed to develop tuberculosis. There is some evidence that
breathing respirable crystalline silica or the disease silicosis is
associated with an increased incidence of significant disease endpoints
such as scleroderma (an immune system disorder manifested by fibrosis of
the lungs, skin and other internal organs) and kidney disease.
MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY CONTACT: Asthma and
asthma-like conditions may worsen from prolonged and repeated exposure.
PRIMARY ROUTE(S) OF ENTRY:

SKIN CONTACT

INHALATION

|-------------------------------------------------------------------------|
|
SECTION 4 - FIRST AID MEASURES
|
|-------------------------------------------------------------------------|
EYE CONTACT: Flush with large quantities of water until irritation
subsides. Contact a physician.
SKIN CONTACT:

Wash with soap and water.

(Continued on Page 3)
---------------------------------------------------------------------------

Product Name: WALLBOARD JOINT COMPOUND RTU
Revision Date: 07/28/2003
Page 3
|-------------------------------------------------------------------------|
|
SECTION 4 - FIRST AID MEASURES
|
|-------------------------------------------------------------------------|
INHALATION:

Remove to fresh air.

Contact a physician immediately.

INGESTION: DO NOT INDUCE VOMITING.
Control Center immediately.
COMMENTS:

Contact a physician or Regional Poison

In case of a medical emergency call: 1-800-327-3874.

|-------------------------------------------------------------------------|
|
SECTION 5 - FIRE FIGHTING MEASURES
|
|-------------------------------------------------------------------------|
FLASH POINT: >200 F
(SETAFLASH CLOSED CUP)

LOWER EXPLOSIVE LIMIT: N.A.
UPPER EXPLOSIVE LIMIT: N.A.

AUTOIGNITION TEMPERATURE: N.E.
EXTINGUISHING MEDIA:

CO2

DRY CHEMICAL

UNUSUAL FIRE AND EXPLOSION HAZARDS:
SPECIAL FIREFIGHTING PROCEDURES:

FOAM

None known.

Use water spray to cool exposed surfaces.

|-------------------------------------------------------------------------|
|
SECTION 6 - ACCIDENTAL RELEASE MEASURES
|
|-------------------------------------------------------------------------|
SPILL OR LEAK PROCEDURES:
containers.

Scrape up dried material and place into

|-------------------------------------------------------------------------|
|
SECTION 7 - HANDLING AND STORAGE
|
|-------------------------------------------------------------------------|
CAUTION! Removal of this product after use will result in the generation of
dust. If dry-sanded, exposure to dust may result in build-up of material
in eyes, ears, nose, and mouth which may cause irritation.
HANDLING INFORMATION: KEEP OUT OF REACH OF CHILDREN. Keep containers away
from excessive heating and freezing. Avoid skin and eye contact. Do not
inhale dusts of this product.
STORAGE INFORMATION: Store away from caustics and oxidizers. Keep
containers tightly closed when not in use. Keep containers from excessive
heat and freezing. Do not store at temperatures above 120 degrees F.
OTHER PRECAUTIONS:

None.

|-------------------------------------------------------------------------|
|
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
|
|-------------------------------------------------------------------------|
(Continued on Page 4)
---------------------------------------------------------------------------

Product Name: WALLBOARD JOINT COMPOUND RTU
Revision Date: 07/28/2003
Page 4
|-------------------------------------------------------------------------|
|
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
|
|-------------------------------------------------------------------------|
ENGINEERING CONTROLS: If dry-sanding, provide sufficient mechanical
ventilation to maintain exposure below PEL and TLV. Wet sanding is
recommended to avoid generation of dust.
RESPIRATORY PROTECTION:
Dry sanding of dried product results in the generation of dust which
contains crystalline silica. Avoid exposure to dust by wearing an
appropriate, properly fitted, dust respirator during dry sanding. Follow
respiratory manufacturer’s directions for respirator use.
If the 8 hour exposure limit or value is exceeded for any component, use an
approved NIOSH/OSHA respirator. Consult your safety equipment supplier and
the OSHA regulation, 29 CFR 1910.134 for respirator requirements. A
respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2
requirements must be followed whenever workplace conditions warrant a
respirator's use.
The National Institute for Occupational Safety and Health (NIOSH)
recommended permissible exposure limit of 50 micrograms respirable free
silica per cubic meter of air (0.05 mg/m3) as determined by a full shift
sample up to 10 hour working day, 40 hours per week.
EYE PROTECTION:
SKIN PROTECTION:
skin.

Safety glasses with side shields.
Gloves recommended for repeated or prolonged contact with

OTHER PROTECTIVE EQUIPMENT:
HYGIENIC PRACTICES:

None.

Remove contaminated clothing and wash before reuse.

|-------------------------------------------------------------------------|
|
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
|
|-------------------------------------------------------------------------|
BOILING RANGE
: 210 - 220 F
VAPOR DENSITY
: Is heavier than air
ODOR
: Musty Odor
APPEARANCE
: Gray Color Paste EVAPORATION RATE: Is slower than Butyl
SOLUBILITY IN H2O : Miscible
Acetate
SPECIFIC GRAVITY : 1.7157
VAPOR PRESSURE
: 17.5 mm Hg@68F.
PHYSICAL STATE
: Paste
(See Section 16 for abbreviation legend)
|-------------------------------------------------------------------------|
|
SECTION 10 - STABILITY AND REACTIVITY
|
|-------------------------------------------------------------------------|
CONDITIONS TO AVOID:
INCOMPATIBILITY:

Excessive heat and freezing.

Strong oxidizers and caustics.

(Continued on Page 5)
---------------------------------------------------------------------------

Product Name: WALLBOARD JOINT COMPOUND RTU
Revision Date: 07/28/2003
Page 5
|-------------------------------------------------------------------------|
|
SECTION 10 - STABILITY AND REACTIVITY
|
|-------------------------------------------------------------------------|
HAZARDOUS DECOMPOSITION PRODUCTS:
NOx

Normal decomposition products, i.e. COx,

HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
|-------------------------------------------------------------------------|
|
SECTION 11 - TOXICOLOGICAL PROPERTIES
|
|-------------------------------------------------------------------------|
No product or component toxicological information is available.
|-------------------------------------------------------------------------|
|
SECTION 12 - ECOLOGICAL INFORMATION
|
|-------------------------------------------------------------------------|
No Information.
|-------------------------------------------------------------------------|
|
SECTION 13 - DISPOSAL CONSIDERATIONS
|
|-------------------------------------------------------------------------|
WASTE MANAGEMENT/DISPOSAL: This product does not meet the definition of a
hazardous waste according to U.S. EPA Hazardous Waste Management
Regulations, 40 CFR Section 261. State and Local regulations/restrictions
are complex and may differ from Federal regulations. Responsibility for
proper waste disposal is with the owner of the waste.
EPA WASTE CODE - If discarded (40 CFR 261):

None.

|-------------------------------------------------------------------------|
|
SECTION 14 - TRANSPORTATION INFORMATION
|
|-------------------------------------------------------------------------|
DOT PROPER SHIPPING NAME: Not Regulated by D.O.T.
DOT HAZARD CLASS: NONE
DOT UN/NA NUMBER: NONE

PACKING GROUP: NONE

|-------------------------------------------------------------------------|
|
SECTION 15 - REGULATORY INFORMATION
|
|-------------------------------------------------------------------------|
U.S. FEDERAL REGULATIONS: AS FOLLOWS OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)

(Continued on Page 6)
---------------------------------------------------------------------------

Product Name: WALLBOARD JOINT COMPOUND RTU
Revision Date: 07/28/2003
Page 6
|-------------------------------------------------------------------------|
|
SECTION 15 - REGULATORY INFORMATION
|
|-------------------------------------------------------------------------|
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
----------- CHEMICAL NAME ----------CAS NUMBER
No SARA Section 313 components exist in this product.

WT/WT % RANGE

TOXIC SUBSTANCES CONTROL ACT:
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:
----------- CHEMICAL NAME ----------CAS NUMBER
No TSCA 12(B) chemicals are known to exist in this product.
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------Water
Magnesium aluminum silicate
Vinyl Acetate Polymer

CAS NUMBER
7732-18-5
12174-11-7
TSRN-618608-5185P

PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------Water

CAS NUMBER
7732-18-5

CALIFORNIA PROPOSITION 65:
WARNING: The chemical(s) noted below and contained in this product, are
known to the state of California to cause cancer:
----------- CHEMICAL NAME ----------Crystalline Silica

CAS NUMBER
14808-60-7

INTERNATIONAL REGULATIONS: AS FOLLOWS CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: No information available.

(Continued on Page 7)
---------------------------------------------------------------------------

Product Name: WALLBOARD JOINT COMPOUND RTU
Revision Date: 07/28/2003
Page 7
|-------------------------------------------------------------------------|
|
SECTION 15 - REGULATORY INFORMATION
|
|-------------------------------------------------------------------------|
|-------------------------------------------------------------------------|
|
SECTION 16 - OTHER INFORMATION
|
|-------------------------------------------------------------------------|
HMIS RATINGS - HEALTH: 1

FLAMMABILITY: 0

REACTIVITY: 0

PREVIOUS MSDS REVISION DATE: 09/10/2002
REASON FOR REVISION:
Section 2. Update exposure limits for crystalline silica.

VOC less water, less exempt solvent: 15-20 g/L
VOC material
: 5-10 g/L
LEGEND:

ACGIH
N.A.
N.E.
PEL
NTP
SARA
STEL
TLV
VOC
NJRTK
N.D.

-

AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
NOT APPLICABLE
NOT ESTABLISHED
PERMISSIBLE EXPOSURE LIMIT
NATIONAL TOXICOLOGY PROGRAM
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986
SHORT TERM EXPOSURE LIMIT
THRESHOLD LIMIT VALUE(8 HR. TIME WEIGHTED AVERAGE OR TWA)
VOLATILE ORGANIC COMPOUND
NEW JERSEY RIGHT TO KNOW LAW
NOT DETERMINED

MSDS# 70288
---------------------------------------------------------------------------

This data is offered in good faith as typical values and not as a product
specification. No warranty either expressed or implied, is hereby made.
The recommended industrial hygiene and safe handling procedures are
believed to be generally applicable. However, each user should review the
recommendations in specific context of the intended use and determine if
they are appropriate.
--------------------------------------------------------------------------< End OF MSDS >

|-------------------------------------------------------|
| M A T E R I A L
S A F E T Y
D A T A
S H E E T |
|-------------------------------------------------------|
|-------------------------------------------------------------------------|
|
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
|
|-------------------------------------------------------------------------|
PRODUCT NAME
: WALLBOARD JOINT COMPOUND RTU
UPC NUMBER
: 7079810100, 7079810102
PRODUCT USE/CLASS
: Joint Compound
MANUFACTURER:
DAP INC.
2400 BOSTON STREET
BALTIMORE, MD 21224

24 HOUR EMERGENCY:
TRANSPORTATION: 1-800-535-5053 (352-323-3500)
MEDICAL
: 1-800-327-3874 (513-558-5111)

PREPARE DATE: 12/23/1999
GENERAL INFORMATION:
REVISION NO.: 9
DAP INC. : 1-888-DAP-TIPS (1-888-327-8477)
REVISION DATE: 07/28/2003
|-------------------------------------------------------------------------|
|
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
|
|-------------------------------------------------------------------------|
ITEM
------------ CHEMICAL NAME ------------- CAS NUMBER
RANGE WT/WT %
--------------------------------------------------------------------------01
Mica
12001-26-2
1.0-5.0 %
02
Calcium Carbonate
1317-65-3
60.0-65.0 %
03
Crystalline Silica
14808-60-7
0.1-0.5 %
04
Attapulgite(polygorskite)
12174-11-7
0.1-5.0 %
---------------------- EXPOSURE LIMITS -------------------ACGIH
OSHA
COMPANY
ITEM TLV-TWA
TLV-STEL
PEL-TWA
PEL-CEILING TLV-TWA
SKIN
--------------------------------------------------------------------------01
3 mg/m3-dust N.E.
3 mg/m3-dust N.E.
N.E.
NO
02
10 mg/m3
N.E.
**
N.E.
N.E.
NO
03
0.05 mg/m3* N.E.
10 mg/m3dust N.E.
N.E.
NO
04
N.E.
N.E.
N.E.
N.E.
N.E.
NO
(See Section 16 for abbreviation legend)
* The 2001 ACGIH Threshold Limit Values for Chemical Substances and
Physical Agents lists the median Respirable Particulate Mass (RPM) point
for crystalline silica at 4.0 microns in terms of the particle’s
aerodynamic diameter.
** 10 mg/m3 / (% SiO2 + 2): Both concentration and percent quartz for the
application of this limit are to be determined from the fraction passing a
size selector with the following characteristics
|-------------------------------------------------------------------------|
| Aerodynamic diameter (unit density sphere) | Percent passing selector |
|-------------------------------------------------------------------------|
|2
|90
|
|2.5
|75
|
|3.5
|50
|
|5.0
|25
|
|10
|0
|
|-------------------------------------------------------------------------|
Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor
OSHA Final Rule Limits (CFR 29 1910.1000); limits may vary between states.
Remaining ingredients are not considered hazardous per the OSHA Hazard
Communication Standard.
(Continued on Page 2)
---------------------------------------------------------------------------

Product Name: WALLBOARD JOINT COMPOUND RTU
Revision Date: 07/28/2003
Page 2
|-------------------------------------------------------------------------|
|
SECTION 3 - HAZARDS IDENTIFICATION
|
|-------------------------------------------------------------------------|
POTENTIAL HEALTH EFFECTS:
EFFECTS OF OVEREXPOSURE - EYE CONTACT:

May cause eye irritation.

EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
EFFECTS OF OVEREXPOSURE - INHALATION:
respiratory tract.
EFFECTS OF OVEREXPOSURE - INGESTION:

May dry skin.

Vapor may irritate nose and upper
None known.

EFFECTS OF OVER EXPOSURE – CHRONIC HAZARDS
The International Agency for Research on Cancer (IARC)has determined that
crystalline silica in the form of quartz or cristobalite that is inhaled
from occupational sources is carcinogenic to humans (Group 1– carcinogenic
to humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic
Fibres (published in June 1997) in conjunction with the use of these
materials. The National Toxicology Program (NTP) classifies respirable
crystalline silica as known to be a human carcinogen. Refer to the 9th
Report on Carcinogens (2000). The American Conference of Governmental
Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a
suspected human carcinogen (A2).
Breathing dust containing respirable crystalline silica may not cause
noticeable injury or illness even though permanent lung damage may be
occurring. Inhalation of dust may have the following serious chronic health
effects: Excessive inhalation of respirable dust can cause pneumoconiosis,
a respiratory disease, which can result in delayed, progressive, disabling
and sometimes fatal lung injury. Symptoms include cough, shortness of
breath, wheezing, non-specific chest illness and reduced pulmonary
function. Smoking exacerbates this disease. Individuals with pneumoconiosis
are predisposed to develop tuberculosis. There is some evidence that
breathing respirable crystalline silica or the disease silicosis is
associated with an increased incidence of significant disease endpoints
such as scleroderma (an immune system disorder manifested by fibrosis of
the lungs, skin and other internal organs) and kidney disease.
MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY CONTACT: Asthma and
asthma-like conditions may worsen from prolonged and repeated exposure.
PRIMARY ROUTE(S) OF ENTRY:

SKIN CONTACT

INHALATION

|-------------------------------------------------------------------------|
|
SECTION 4 - FIRST AID MEASURES
|
|-------------------------------------------------------------------------|
EYE CONTACT: Flush with large quantities of water until irritation
subsides. Contact a physician.
SKIN CONTACT:

Wash with soap and water.

(Continued on Page 3)
---------------------------------------------------------------------------

Product Name: WALLBOARD JOINT COMPOUND RTU
Revision Date: 07/28/2003
Page 3
|-------------------------------------------------------------------------|
|
SECTION 4 - FIRST AID MEASURES
|
|-------------------------------------------------------------------------|
INHALATION:

Remove to fresh air.

Contact a physician immediately.

INGESTION: DO NOT INDUCE VOMITING.
Control Center immediately.
COMMENTS:

Contact a physician or Regional Poison

In case of a medical emergency call: 1-800-327-3874.

|-------------------------------------------------------------------------|
|
SECTION 5 - FIRE FIGHTING MEASURES
|
|-------------------------------------------------------------------------|
FLASH POINT: >200 F
(SETAFLASH CLOSED CUP)

LOWER EXPLOSIVE LIMIT: N.A.
UPPER EXPLOSIVE LIMIT: N.A.

AUTOIGNITION TEMPERATURE: N.E.
EXTINGUISHING MEDIA:

CO2

DRY CHEMICAL

UNUSUAL FIRE AND EXPLOSION HAZARDS:
SPECIAL FIREFIGHTING PROCEDURES:

FOAM

None known.

Use water spray to cool exposed surfaces.

|-------------------------------------------------------------------------|
|
SECTION 6 - ACCIDENTAL RELEASE MEASURES
|
|-------------------------------------------------------------------------|
SPILL OR LEAK PROCEDURES:
containers.

Scrape up dried material and place into

|-------------------------------------------------------------------------|
|
SECTION 7 - HANDLING AND STORAGE
|
|-------------------------------------------------------------------------|
CAUTION! Removal of this product after use will result in the generation of
dust. If dry-sanded, exposure to dust may result in build-up of material
in eyes, ears, nose, and mouth which may cause irritation.
HANDLING INFORMATION: KEEP OUT OF REACH OF CHILDREN. Keep containers away
from excessive heating and freezing. Avoid skin and eye contact. Do not
inhale dusts of this product.
STORAGE INFORMATION: Store away from caustics and oxidizers. Keep
containers tightly closed when not in use. Keep containers from excessive
heat and freezing. Do not store at temperatures above 120 degrees F.
OTHER PRECAUTIONS:

None.

|-------------------------------------------------------------------------|
|
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
|
|-------------------------------------------------------------------------|
(Continued on Page 4)
---------------------------------------------------------------------------

Product Name: WALLBOARD JOINT COMPOUND RTU
Revision Date: 07/28/2003
Page 4
|-------------------------------------------------------------------------|
|
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
|
|-------------------------------------------------------------------------|
ENGINEERING CONTROLS: If dry-sanding, provide sufficient mechanical
ventilation to maintain exposure below PEL and TLV. Wet sanding is
recommended to avoid generation of dust.
RESPIRATORY PROTECTION:
Dry sanding of dried product results in the generation of dust which
contains crystalline silica. Avoid exposure to dust by wearing an
appropriate, properly fitted, dust respirator during dry sanding. Follow
respiratory manufacturer’s directions for respirator use.
If the 8 hour exposure limit or value is exceeded for any component, use an
approved NIOSH/OSHA respirator. Consult your safety equipment supplier and
the OSHA regulation, 29 CFR 1910.134 for respirator requirements. A
respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2
requirements must be followed whenever workplace conditions warrant a
respirator's use.
The National Institute for Occupational Safety and Health (NIOSH)
recommended permissible exposure limit of 50 micrograms respirable free
silica per cubic meter of air (0.05 mg/m3) as determined by a full shift
sample up to 10 hour working day, 40 hours per week.
EYE PROTECTION:
SKIN PROTECTION:
skin.

Safety glasses with side shields.
Gloves recommended for repeated or prolonged contact with

OTHER PROTECTIVE EQUIPMENT:
HYGIENIC PRACTICES:

None.

Remove contaminated clothing and wash before reuse.

|-------------------------------------------------------------------------|
|
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
|
|-------------------------------------------------------------------------|
BOILING RANGE
: 210 - 220 F
VAPOR DENSITY
: Is heavier than air
ODOR
: Musty Odor
APPEARANCE
: Gray Color Paste EVAPORATION RATE: Is slower than Butyl
SOLUBILITY IN H2O : Miscible
Acetate
SPECIFIC GRAVITY : 1.7157
VAPOR PRESSURE
: 17.5 mm Hg@68F.
PHYSICAL STATE
: Paste
(See Section 16 for abbreviation legend)
|-------------------------------------------------------------------------|
|
SECTION 10 - STABILITY AND REACTIVITY
|
|-------------------------------------------------------------------------|
CONDITIONS TO AVOID:
INCOMPATIBILITY:

Excessive heat and freezing.

Strong oxidizers and caustics.

(Continued on Page 5)
---------------------------------------------------------------------------

Product Name: WALLBOARD JOINT COMPOUND RTU
Revision Date: 07/28/2003
Page 5
|-------------------------------------------------------------------------|
|
SECTION 10 - STABILITY AND REACTIVITY
|
|-------------------------------------------------------------------------|
HAZARDOUS DECOMPOSITION PRODUCTS:
NOx

Normal decomposition products, i.e. COx,

HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
|-------------------------------------------------------------------------|
|
SECTION 11 - TOXICOLOGICAL PROPERTIES
|
|-------------------------------------------------------------------------|
No product or component toxicological information is available.
|-------------------------------------------------------------------------|
|
SECTION 12 - ECOLOGICAL INFORMATION
|
|-------------------------------------------------------------------------|
No Information.
|-------------------------------------------------------------------------|
|
SECTION 13 - DISPOSAL CONSIDERATIONS
|
|-------------------------------------------------------------------------|
WASTE MANAGEMENT/DISPOSAL: This product does not meet the definition of a
hazardous waste according to U.S. EPA Hazardous Waste Management
Regulations, 40 CFR Section 261. State and Local regulations/restrictions
are complex and may differ from Federal regulations. Responsibility for
proper waste disposal is with the owner of the waste.
EPA WASTE CODE - If discarded (40 CFR 261):

None.

|-------------------------------------------------------------------------|
|
SECTION 14 - TRANSPORTATION INFORMATION
|
|-------------------------------------------------------------------------|
DOT PROPER SHIPPING NAME: Not Regulated by D.O.T.
DOT HAZARD CLASS: NONE
DOT UN/NA NUMBER: NONE

PACKING GROUP: NONE

|-------------------------------------------------------------------------|
|
SECTION 15 - REGULATORY INFORMATION
|
|-------------------------------------------------------------------------|
U.S. FEDERAL REGULATIONS: AS FOLLOWS OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)

(Continued on Page 6)
---------------------------------------------------------------------------

Product Name: WALLBOARD JOINT COMPOUND RTU
Revision Date: 07/28/2003
Page 6
|-------------------------------------------------------------------------|
|
SECTION 15 - REGULATORY INFORMATION
|
|-------------------------------------------------------------------------|
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
----------- CHEMICAL NAME ----------CAS NUMBER
No SARA Section 313 components exist in this product.

WT/WT % RANGE

TOXIC SUBSTANCES CONTROL ACT:
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:
----------- CHEMICAL NAME ----------CAS NUMBER
No TSCA 12(B) chemicals are known to exist in this product.
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------Water
Magnesium aluminum silicate
Vinyl Acetate Polymer

CAS NUMBER
7732-18-5
12174-11-7
TSRN-618608-5185P

PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------Water

CAS NUMBER
7732-18-5

CALIFORNIA PROPOSITION 65:
WARNING: The chemical(s) noted below and contained in this product, are
known to the state of California to cause cancer:
----------- CHEMICAL NAME ----------Crystalline Silica

CAS NUMBER
14808-60-7

INTERNATIONAL REGULATIONS: AS FOLLOWS CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: No information available.

(Continued on Page 7)
---------------------------------------------------------------------------

Product Name: WALLBOARD JOINT COMPOUND RTU
Revision Date: 07/28/2003
Page 7
|-------------------------------------------------------------------------|
|
SECTION 15 - REGULATORY INFORMATION
|
|-------------------------------------------------------------------------|
|-------------------------------------------------------------------------|
|
SECTION 16 - OTHER INFORMATION
|
|-------------------------------------------------------------------------|
HMIS RATINGS - HEALTH: 1

FLAMMABILITY: 0

REACTIVITY: 0

PREVIOUS MSDS REVISION DATE: 09/10/2002
REASON FOR REVISION:
Section 2. Update exposure limits for crystalline silica.

VOC less water, less exempt solvent: 15-20 g/L
VOC material
: 5-10 g/L
LEGEND:

ACGIH
N.A.
N.E.
PEL
NTP
SARA
STEL
TLV
VOC
NJRTK
N.D.

-

AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
NOT APPLICABLE
NOT ESTABLISHED
PERMISSIBLE EXPOSURE LIMIT
NATIONAL TOXICOLOGY PROGRAM
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986
SHORT TERM EXPOSURE LIMIT
THRESHOLD LIMIT VALUE(8 HR. TIME WEIGHTED AVERAGE OR TWA)
VOLATILE ORGANIC COMPOUND
NEW JERSEY RIGHT TO KNOW LAW
NOT DETERMINED

MSDS# 70288
---------------------------------------------------------------------------

This data is offered in good faith as typical values and not as a product
specification. No warranty either expressed or implied, is hereby made.
The recommended industrial hygiene and safe handling procedures are
believed to be generally applicable. However, each user should review the
recommendations in specific context of the intended use and determine if
they are appropriate.
--------------------------------------------------------------------------< End OF MSDS >

MATERIAL SAFETY DATA SHEET
-------------------------7677

PAGE 1

MATERIAL SAFETY DATA SHEET PAGE 1
-------------------------ABBREVIATIONS:
NA=NOT APPLICABLE
ND=NOT DETERMINED
NE=NOT ESTABLISHED

HEALTH= 0
FLAMMABILITY= 0
REACTIVITY= 0
PERSONAL PROTECTION= +
WHMIS CLASSIFICATION: D2
+ SEE SECTION VII
========================================================SECTION I PRODUCT IDENTIFICATION AND USE
MATERIAL NAME/IDENTIFIER: 7677 - WALL PATCH / SHUR PATCH - LIGHTWEIGHT PATCHING COMPOUND
MANUFACTURER/SUPPLIER: GH INTERNATIONAL
a division of IKO Industries Ltd.
2540 RENA ROAD
MISSISSAUGA, ONTARIO L4T3C9
PHONE: 1-905-677-5522
EMERGENCY: 1-613-996-6666 CANUTEC(24 hr. emergency information only)
CHEMICAL FAMILY: Mixture
CHEMICAL FORMULA/MOLECULAR WT: NA
TRADE NAME AND SYNONYMS: NA
MATERIAL USE: Spackling/patching compound
========================================================
SECTION II HAZARDOUS INGREDIENTS
-----------------------------------------------------------------------------CHEMICAL NAME
OSHA-PEL
ACGIH-TLV
Amorphous Silica

6 mg/m3
-

10 mg/m3
(Total Dust)

CAS #63231-67-4
CARCINOGEN: NO
========================================================
SECTION III PHYSICAL DATA
APPEARANCE, PHYSICAL STATE AND ODOR:
ODOR THRESHOLD (PPM): ND
SPECIFIC GRAVITY/DENSITY (G/ML): 0.43-0.47
VAPOR PRESSURE (MM): 25 Deg. C 18 mm
VAPOR DENSITY (AIR=1): >1
EVAPORATION RATE (BUAC=1): <1
BOILING POINT: 200-215 Deg. F/93-101 Deg. C
MELTING/FREEZING POINT: 0’C
PH: 7.0-9.0
COEFFICIENT OF WATER/OIL DISTRIBUTION: ND
SOLUBILITY IN WATER: Soluble
% VOLATILE BY VOLUME: 20-30

White paste, latex odor.

LD50/LC50

%WT/WT

ND
-

15-25

MATERIAL SAFETY DATA SHEET
--------------------------

PAGE 2

========================================================SECTION IV FIRE OR EXPLOSION DATA
FLASH POINT: NA - Water based
AUTO IGNITION TEMPERATURE: NA
SENSITIVITY TO MECHANICAL IMPACT: NA
EXPLOSIVE POWER: NA
UPPER EXPLOSION LIMIT: NA
LOWER EXPLOSION LIMIT: NA
RATE OF BURNING: NA
SENSITIVITY TO STATIC DISCHARGE: NA
EXTINGUISHING MEDIA: NA
SPECIAL FIRE FIGHTING PROCEDURES:
NA
UNUSUAL FIRE AND EXPLOSION HAZARDS:
NA
FLAMMABILITY: NO
UNDER WHAT CONDITIONS: NA
========================================================SECTION V REACTIVITY DATA
STABILITY - MATERIAL IS: Stable
CONDITIONS TO AVOID:
NA
HAZARDOUS DECOMPOSITION/COMBUSTION PRODUCTS:
Carbon dioxide, carbon monoxide
INCOMPATIBILITY (MATERIALS TO AVOID):
Strong oxidizers
HAZARDOUS POLYMERIZATION:
Will not occur
CONDITIONS TO AVOID:
NA
========================================================SECTION VI TOXICOLOGICAL PROPERTIES
PRIMARY ROUTES OF ENTRY:
Skin - Ingestion
EFFECTS OF OVEREXPOSURE, CHRONIC:
None known
EFFECTS OF OVEREXPOSURE, ACUTE:
Skin: Prolonged/repeated contact may cause slight irritation to sensitive skin. Eyes: Contact may cause irritation. Ingestion:
Can cause gastrointestinal upset.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:
None known
CARCINOGENICITY: NO
LD50 OF PRODUCT: ND
IRRITANT?: NO
SYNERGISTIC MATERIALS: NA
REPRODUCTIVE EFFECTS: NO
WHMIS CLASSIFICATION: D2

LC50 OF PRODUCT: ND
SENSITIZER?: NO
TERATOGENIC: NO

MUTAGENIC: NO

MATERIAL SAFETY DATA SHEET
--------------------------

PAGE 3

========================================================SECTION VII PREVENTIVE MEASURES, SAFE
HANDLING AND USE,
REGULATORY INFORMATION
LEAK AND SPILL PROCEDURES:
Dike spill area, recover free liquid. Return to container. Add absorbent to spill area.
WASTE DISPOSAL METHOD:
Dispose of according to Federal, State and Local regulations.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
Store in cool, dry area. Protect from freezing.
OTHER:
Keep out of the reach of children!
VENTILATION:
NA
RESPIRATORY PROTECTION:
NA
PROTECTIVE GLOVES: NA
EYE PROTECTION: NA
OTHER PROTECTIVE EQUIPMENT: NA
WORK/HYGIENIC PRACTICES:
Remove contaminated clothing, launder before reuse.
REPORTABLE QUANTITY (MIN. UNDER ANY ACT): None
RCRA HAZARDOUS WASTE NO: None
DOT PROPER SHIPPING NAME: Calking and glaziers compound
DOT HAZARD CLASS: Not regulated
IDENTIFICATION NO: NMFC Item No. 149610
VOLATILE ORGANIC COMPOUNDS (VOC): <30 G/L
TDG CLASSIFICATION (CAN): Not regulated
========================================================SECTION VIII FIRST AID MEASURES
EMERGENCY AND FIRST AID PROCEDURES:
Skin: Wash with soap and water. Eyes: Flush with copious amounts of water. Contact a physician. Ingestion: Contact a
physician immediately.
========================================================SECTION IX PREPARATION INFORMATION
Prepared by: Technical Services Dept.
Date: November 2007
The information accumulated herein is believed to be accurate but is not warranted to be, whether originating with the Company or not.
Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances.
7677

MATERIAL SAFETY DATA SHEET
-------------------------7677

PAGE 1

MATERIAL SAFETY DATA SHEET PAGE 1
-------------------------ABBREVIATIONS:
NA=NOT APPLICABLE
ND=NOT DETERMINED
NE=NOT ESTABLISHED

HEALTH= 0
FLAMMABILITY= 0
REACTIVITY= 0
PERSONAL PROTECTION= +
WHMIS CLASSIFICATION: D2
+ SEE SECTION VII
========================================================SECTION I PRODUCT IDENTIFICATION AND USE
MATERIAL NAME/IDENTIFIER: 7677 - WALL PATCH / SHUR PATCH - LIGHTWEIGHT PATCHING COMPOUND
MANUFACTURER/SUPPLIER: GH INTERNATIONAL
a division of IKO Industries Ltd.
2540 RENA ROAD
MISSISSAUGA, ONTARIO L4T3C9
PHONE: 1-905-677-5522
EMERGENCY: 1-613-996-6666 CANUTEC(24 hr. emergency information only)
CHEMICAL FAMILY: Mixture
CHEMICAL FORMULA/MOLECULAR WT: NA
TRADE NAME AND SYNONYMS: NA
MATERIAL USE: Spackling/patching compound
========================================================
SECTION II HAZARDOUS INGREDIENTS
-----------------------------------------------------------------------------CHEMICAL NAME
OSHA-PEL
ACGIH-TLV
Amorphous Silica

6 mg/m3
-

10 mg/m3
(Total Dust)

CAS #63231-67-4
CARCINOGEN: NO
========================================================
SECTION III PHYSICAL DATA
APPEARANCE, PHYSICAL STATE AND ODOR:
ODOR THRESHOLD (PPM): ND
SPECIFIC GRAVITY/DENSITY (G/ML): 0.43-0.47
VAPOR PRESSURE (MM): 25 Deg. C 18 mm
VAPOR DENSITY (AIR=1): >1
EVAPORATION RATE (BUAC=1): <1
BOILING POINT: 200-215 Deg. F/93-101 Deg. C
MELTING/FREEZING POINT: 0’C
PH: 7.0-9.0
COEFFICIENT OF WATER/OIL DISTRIBUTION: ND
SOLUBILITY IN WATER: Soluble
% VOLATILE BY VOLUME: 20-30

White paste, latex odor.

LD50/LC50

%WT/WT

ND
-

15-25

MATERIAL SAFETY DATA SHEET
--------------------------

PAGE 2

========================================================SECTION IV FIRE OR EXPLOSION DATA
FLASH POINT: NA - Water based
AUTO IGNITION TEMPERATURE: NA
SENSITIVITY TO MECHANICAL IMPACT: NA
EXPLOSIVE POWER: NA
UPPER EXPLOSION LIMIT: NA
LOWER EXPLOSION LIMIT: NA
RATE OF BURNING: NA
SENSITIVITY TO STATIC DISCHARGE: NA
EXTINGUISHING MEDIA: NA
SPECIAL FIRE FIGHTING PROCEDURES:
NA
UNUSUAL FIRE AND EXPLOSION HAZARDS:
NA
FLAMMABILITY: NO
UNDER WHAT CONDITIONS: NA
========================================================SECTION V REACTIVITY DATA
STABILITY - MATERIAL IS: Stable
CONDITIONS TO AVOID:
NA
HAZARDOUS DECOMPOSITION/COMBUSTION PRODUCTS:
Carbon dioxide, carbon monoxide
INCOMPATIBILITY (MATERIALS TO AVOID):
Strong oxidizers
HAZARDOUS POLYMERIZATION:
Will not occur
CONDITIONS TO AVOID:
NA
========================================================SECTION VI TOXICOLOGICAL PROPERTIES
PRIMARY ROUTES OF ENTRY:
Skin - Ingestion
EFFECTS OF OVEREXPOSURE, CHRONIC:
None known
EFFECTS OF OVEREXPOSURE, ACUTE:
Skin: Prolonged/repeated contact may cause slight irritation to sensitive skin. Eyes: Contact may cause irritation. Ingestion:
Can cause gastrointestinal upset.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:
None known
CARCINOGENICITY: NO
LD50 OF PRODUCT: ND
IRRITANT?: NO
SYNERGISTIC MATERIALS: NA
REPRODUCTIVE EFFECTS: NO
WHMIS CLASSIFICATION: D2

LC50 OF PRODUCT: ND
SENSITIZER?: NO
TERATOGENIC: NO

MUTAGENIC: NO

MATERIAL SAFETY DATA SHEET
--------------------------

PAGE 3

========================================================SECTION VII PREVENTIVE MEASURES, SAFE
HANDLING AND USE,
REGULATORY INFORMATION
LEAK AND SPILL PROCEDURES:
Dike spill area, recover free liquid. Return to container. Add absorbent to spill area.
WASTE DISPOSAL METHOD:
Dispose of according to Federal, State and Local regulations.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
Store in cool, dry area. Protect from freezing.
OTHER:
Keep out of the reach of children!
VENTILATION:
NA
RESPIRATORY PROTECTION:
NA
PROTECTIVE GLOVES: NA
EYE PROTECTION: NA
OTHER PROTECTIVE EQUIPMENT: NA
WORK/HYGIENIC PRACTICES:
Remove contaminated clothing, launder before reuse.
REPORTABLE QUANTITY (MIN. UNDER ANY ACT): None
RCRA HAZARDOUS WASTE NO: None
DOT PROPER SHIPPING NAME: Calking and glaziers compound
DOT HAZARD CLASS: Not regulated
IDENTIFICATION NO: NMFC Item No. 149610
VOLATILE ORGANIC COMPOUNDS (VOC): <30 G/L
TDG CLASSIFICATION (CAN): Not regulated
========================================================SECTION VIII FIRST AID MEASURES
EMERGENCY AND FIRST AID PROCEDURES:
Skin: Wash with soap and water. Eyes: Flush with copious amounts of water. Contact a physician. Ingestion: Contact a
physician immediately.
========================================================SECTION IX PREPARATION INFORMATION
Prepared by: Technical Services Dept.
Date: November 2007
The information accumulated herein is believed to be accurate but is not warranted to be, whether originating with the Company or not.
Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances.
7677

Material Safety Data Sheet

Series:
#0511
(All Labels)

MSDS # 0033
1-0-0
1-0-0-A

NFPA Rating:
HMIS Rating:

SECTION I
TRADE NAME
(IF NONE, PUT CHEMICAL)

EMERGENCY TELEPHONE NO.

Wood Putty Powder

(918) 825-5744 (24 Hrs.)

CHEMICAL NAME
AND SYNONYMS
MANUFACTURER'S NAME
AND TELEPHONE NO.

Red Devil, Incorporated

ADDRESS (Number, Street,

4175 Webb Street, Pryor, Oklahoma 74361

)

City, State, Zip Code

(918) 825-5744

SECTION II - HAZARDOUS INGREDIENTS

%

TLV

PEL

UNITS

10

15

Mg/m3

NE

Mg/m3

PRODUCT CONSISTS OF:

Gypsum & Aluminum Silicate (8031-18-3) (as nuisance particulate)
Wood Flour (as wood dust)

>85.0
6.5

Non-Hazardous Ingredients*

<10.0

1.0
NA

NA

* Unlisted ingredients are not considered hazardous under the OSHA
Hazardous Communication Standard (29 CFR 1910.1200)
VOC: 0%/wt. CARB Compliance: YES. Prop 65 Ingredients: NONE

SECTION III - PHYSICAL DATA
BOILING POINT (°F)

NA

SPECIFIC GRAVITY (H20=1)

VAPOR PRESSURE (MM Hg.)

NA

PERCENT VOLATILES
BY VOLUME (%)

NA

VAPOR DENSITY (AIR=1)

NA

pH

NE

EVAPORATION RATE

NA

SOLUBILITY IN WATER
APPEARANCE AND ODOR

Slight

>2.0

Powder, odorless

SECTION IV - FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (Method used)

NA

FLAMMABLE LIMITS

EXTINGUISHING MEDIA

Use media suitable for adjacent materials

SPECIAL FIRE
FIGHTING PROCEDURES

No special procedures required

UNUSUAL FIRE AND
EXPLOSION HAZARDS

None known
NA - Not Applicable

NE - Not Established

1

LEL

UN - Unavailable

NA

UEL

NA

SECTION V - HEALTH HAZARD INFORMATION
SYMPTOM/EFFECTS OR OVEREXPOSURE

Inhalation of dust may cause respiratory irritation. Possible skin irritation. Eye contact causes irritation. Chronic
overexposure may result in lung damage.
FIRST AID
EYES

Flush eyes with large amounts of water. Get medical attention if irritation persists.
SKIN

Wash thoroughly with soap & water. Get medical attention if irritation persists.
INHALATION

Move victim to fresh air. Get medical help if irritation persists.
INGESTION

Contact local poison control center or physician immediately.

SECTION VI - REACTIVITY DATA
STABILITY

Stable
INCOMPATIBLE MATERIALS

None Known
HAZARDOUS DECOMPOSITION PRODUCTS

Carbon monoxide, carbon dioxide, sulfur dioxide

SECTION VII - SPILL OR LEAK PROCEDURES
PROCEDURES

Carefully clean up spilled material & place in dry containers for disposal. Avoid dust generation.
WASTE DISPOSAL METHOD

Dispose of in accordance with Local, State and Federal regulations.

SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY

For symptoms of overexposure, wear a NIOSH-approved respirator for dusts & mists.
EYEWEAR

If potential for eye contact exists, wear chemical goggles.
CLOTHING/GLOVES

Not normally required; in situations of extended skin contact, protective gloves are recommended.
VENTILATION

Local exhaust may be necessary under some handling/use conditions.

SECTION IX - SPECIAL PRECAUTIONS
Store in a closed container in dry area. This product does not contain ingredients listed in Section 313 of SARA Title III.
Reviewed By:
NAME

Larry G. Brandon

VP Technology & General Manager
TITLE

January 31, 2006
DATE

The information contained herein has been developed based upon current available scientific data. New information may be developed from time to time which may render the conclusions of
this report obsolete. Therefore, no warranty is extended as to the applicability of this information to the user's intended purpose or for the consequences of its use or misuse.

0511

2

MATERIAL SAFETY DATA

SHEET

WALLBOARD JOINT COMPOUND
HMIS
HEALTH

1

FLAMMABILITY

0

REACTIVITY

0

PERSONAL

B

PROTECTION

1. Product And Company Identification
Supplier
CUSTOM BUILDING PRODUCTS
13001 SEAL BEACH BLVD.
SEAL BEACH, CA 90740 UNITED STATES

Manufacturer
CUSTOM BUILDING PRODUCTS
13001 SEAL BEACH BLVD.
SEAL BEACH, CA 90740 UNITED STATES

Company Contact: GEORGE MARCINA
Telephone Number: (323) 582-0846

Company Contact: GEORGE MARCINA
Telephone Number: (323) 582-0846

Supplier Emergency Contacts & Phone Number
GEORGE MARCINA: (323) 582-0846

Manufacturer Emergency Contacts & Phone Number
GEORGE MARCINA: (323) 582-0846

Issue Date: 08/05/2005
Product Name: WALLBOARD JOINT COMPOUND
CAS Number: Not Established
MSDS Number: 315
Product Code: 2017
Product Identification Text
THIS MSDS IS APPLICABLE TO THE FOLLOWING PRODUCTS:
WALLBOARD JOINT COMPOUND
2. Composition/Information On Ingredients
Ingredient
Name

CAS
Number

CALCIUM CARBONATE
BENTONITECLAY

Percent Of
Total Weight

471-34-1

60 - 70

1302-78-9

1 -5

3. Hazards Identification
Primary Routes(s) Of Entry
NUSANCE DUST CAN BE RELEASED DURING DRY SANDING.
EYES, SKIN, NOSE
Eye Hazards
SLIGHT EYE IRRITATION. CORNEAL INJURY IS UNLIKELY.
Skin Hazards
PROLONGED EXPOSURE MAY IRRITATE SKIN.
Ingestion Hazards
INGESTION UNLIKELY
Inhalation Hazards
PROLONGED EXPOSURE TO NUSANCE DUST ABOVE THE THRESHOLD LIMIT VALUE MAY CAUSE
IRRITATION TO THE NESE THROAT LUNGS AND UPPER RESPIRATORY TRACT. SHORTNESS OF BREATH
Page 1 of 4

MATERIAL SAFETY DATA

SHEET

WALLBOARD JOINT COMPOUND
3. Hazards Identification - Continued
Inhalation Hazards - Continued
MAY ALSO OCCUR AFTER EXCESSIVE INHALATION.
Chronic/Carcinogenicity Effects
Contains Bentonite clay which may contain small amounts of Silica, Crystaline Quartz, Class 2A carcinogen
Conditions Aggravated By Exposure
NONE KNOWN.
4. First Aid Measures
Eye
IMMEDIATELY FLUSH WITH WATER. IF IRRITATION DEVELOPS, GET MEDICAL ATTENTION
Skin
WASH WITH SOAP AND WATER. IF IRRITATION DEVELOPS, GET MEDICAL ATTENTION.
Ingestion
NO KNOWN EFFECTS
Inhalation
REMOVE TO FRESH AIR. IF NECESSARY, SEEK MEDICAL ATTENTION.
5. Fire Fighting Measures
Flash Point: NONE °F
Flash Point Method: NONE
Lower Explosive Limit: N/A
Upper Explosive Limit: N/A
Fire And Explosion Hazards
MATERIAL IS NON FLAMMABLE
6. Accidental Release Measures
IN CASE MATERIAL IS RELEASED OR SPILLED, AVOID ENTRY INTO SEWERS OR NATURAL WAER WAYS. SOAK
UP SMALL SPILLS WITH ABSORBANT MATERIAL. FOR LARGE SPILLS, DIKE AND PUMP INTO SUITABLE
CONTAINERS FOR DISPOSAL.
7. Handling And Storage
Handling And Storage Precautions
STORE IN COOL, DRY AREA OUT OF SUNLIGHT. STORE AWAY FROM HEAT OR ANY HEAT SOURCES.
PROTECT FROM FREEZING.
Work/Hygienic Practices
HYGEINE AND GOOD HOUSEKEEPING PRACTICES SHOULD BE OBSERVED.
8. Exposure Controls/Personal Protection
Eye/Face Protection
SAFETY GLASSES ARE RECOMMENDED TO SAFEGUARD AGAINST POTENTIAL CONTACT.
Skin Protection
THE USE OF PLASTIC OR RUBBER GLOVES WILL PREVENT SKIN IRRITATION OF SENSITIVE INDIVIDUALS.
Other/General Protection

Page 2 of 4

MATERIAL SAFETY DATA

SHEET

WALLBOARD JOINT COMPOUND
8. Exposure Controls/Personal Protection - Continued
Ingredient(s) - Exposure Limits
CALCIUM CARBONATE
ACGIH TLV-TWA 10 mg/m3
OSHA PEL-TWA 15 mg/m3
OSHA PEL-TWA 5 mg/m3
BENTONITE CLAY
Classified as niusance dust but respirable dust may contain Silica, Crystali
ne Quartz, If more than 1% of Silica is present then:
OSHA PEL - 500 mg / m3
ACGIH - TLV - 10 mg / m3

9. Physical And Chemical Properties
Appearance
WHITE, CREAMY PASTE
Odor
MILD
Chemical Type: Mixture
Physical State: Liquid
Boiling Point: 212 °F
Specific Gravity: 1.6
Vapor Density: HEAVIER THAN AIR
Solubility: MISSIBLE IN WATER UNTIL DRIED
Evaporation Rate: SLOWER THAN ETHER
10. Stability And Reactivity
Sta bility: STABLE
Hazardous Polymerization: WILL NOT OCCUR.
Conditions To Avoid (Stability)
NONE KNOWN.
Incompatible Materials
AVOID CONTACT WITH STRONG STRONG ACIDS.
Conditions To Avoid (Polymerization)
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
11. Toxicological Information
No Data Available...
12. Ecological Information
No Data Available...
13. Disposal Considerations
DISPOSE OF PRODUCT IN ACCORDANCE WITH APPLICABLE LOCAL, COUNTY, STATE AND FEDERAL
REGULATIONS.
RCRA Information
Not considered RCRA waste

Page 3 of 4

MATERIAL SAFETY DATA

SHEET

WALLBOARD JOINT COMPOUND
14. Transport Information
No Data Available...
15. Regulatory Information
Ingredient(s) - State Regulations
CALCIUM CARBONATE
Pennsylvania - Workplace Hazard
BENTONITE CLAY
California - Proposition 65
16. Other Information
HMIS Rating
He a lth: 1
Fire : 0
Re a ctivity: 0
Personal Protection: B
Revision/Preparer Information
MSDS Preparer: GEORGE MARCINA
MSDS Preparer Phone Number: (323) 582-0846
This MSDS Supercedes A Previous MSDS Dated: 12/14/2003
Disclaimer
THE INFORMATION PRESENTED HERE IS BELIEVED TO BE ACCURATE BUT IS NOT WARRANTED TO BE,
WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN
ADVANCE OF NEED, THAT THE INFORMATION IS CURRENT, APPLICABLE, AND SUITABLE TO THEIR
CIRCUMSTANCES.
CUSTOM BUILDING PRODUCTS
Printed Using MSDS Generator™ 2000

Page 4 of 4

MATERIAL SAFETY DATA SHEET

MSDS #88-910-005E
Page 1 of 1

CGC Brand Fiberglass Tape
CGC Inc.
350 Burnhamthorpe Rd. W., 5th Floor
Mississauga, Ontario L5B 3J1
(905) 803-5600 Fax (905) 803-5688
A Subsidiary of USG Corporation

Product Safety: 1 (800) 507-8899
www.cgcinc.com
Version Date: April 2, 2004
Version: 3

SECTION 1
CHEMICAL PRODUCT AND IDENTIFICATION
PRODUCT: CGC Brand Fiberglass Tape
CHEMICAL FAMILY: Fiberglass with adhesive tape

SECTION 2
COMPOSITION, INFORMATION ON INGREDIENTS
MATERIAL
Fibrous Glass (Continuous Filament)

WT%
65-70

TLV (mg/m3)
1 f/cc(R)

PEL( mg/m3)
15(T)/5(R)

CAS NUMBER
65997-17-3

(T) – Total (R) – Respirable (NE) – Not Established mmpfc - million particles per cubic foot of air
All ingredients of this product are included in the U.S. Environmental Protection Agency’s Toxic Substances Control Act
Chemical Substance Inventory. All components of this product are included in the Canadian Domestic Substances List
(DSL).

SECTION 3
HAZARD IDENTIFICATION
INFORMATION FOR HANDLING AND IDENTIFICATION OF CHEMICAL HAZARDS
0 = Minimal Hazard
0
HEALTH
0
NFPA Ratings:
HIMS Ratings:
1 = Slight Hazard
0
FLAMMABILITY
Health:
0
Health:
0
2 = Moderate Hazard
0
0
0
PHYSICAL
HAZARD
Fire:
0
Fire:
0
3 = Serious Hazard
PERSONAL PROTECTION
Reactivity:
0
Reactivity:
0
4 = Severe Hazard
EMERGENCY OVERVIEW: This product is not expected to produce any unusual hazards during normal use. However,
it may be possible to create and release nuisance dust if tape is sanded when sanding joints. Eye, nose and upper
respiratory irritation may occur with prolonged exposure to high dust.
POTENTIAL HEALTH EFFECTS
ACUTE:
Eyes: Direct contact of fibers may cause irritation. Direct contact of particulate may cause mechanical irritation of the
eyes. If burning, redness, itching, pain or other symptoms persist or develop, consult a physician.
Skin: Direct contact with the skin may cause irritation.
Inhalation: Overexposure to glass fibers may produce irritation of the nose, throat, and upper respiratory system.
Persons subjected to overexposure to large amounts of dust will be forced to leave area because of nuisance conditions
such as coughing, sneezing and nasal irritation from dust. Labored breathing may occur after excessive inhalation. If
respiratory symptoms persist, consult physician.
Ingestion: There are no known health effects due to ingestion. Due to the physical nature of this product, ingestion is
unlikely. Wash hands before eating.
CHRONIC: Direct, prolonged or repeated contact with the skin may cause irritation.

MATERIAL SAFETY DATA SHEET

MSDS #88-910-005E
Page 2 of 2

CGC Brand Fiberglass Tape
SECTION 4
FIRST AID MEASURES
FIRST AID PROCEDURES
Eyes: In case of contact, do not rub or scratch your eyes. Flush thoroughly with water for 15 minutes to remove
particulates. If irritation persists, consult physician.
Skin: Wash with mild soap and water. If irritation persists, consult physician.
Inhalation: Remove to fresh air. Leave the area of high dust exposure until coughing and other symptoms subside.
Ingestion: Not likely to occur. If ingested, call physician.
TARGT ORGANS: Eyes, Skin, and Respiratory System.
PRIMARY ROUTES OF ENTRY: Eyes, Skin, and Respiratory System.

SECTION 5
FIRE FIGHTING MEASURES
None known.
General Fire Hazards:
Water or use extinguishing media appropriate for surrounding fire.
Extinguishing Media:
Fire fighters should wear protective gear appropriate for surrounding fire.
Special Fire Fighting Procedures:
None known.
Unusual Fire & Explosion Hazards:
None known.
Hazardous Combustion Products:
None Known
Not Applicable
Flash Point:
Auto Ignition:
Not Applicable
Method Used:
Flammability
Not Applicable
Classification:
Upper Flammable Limit (UFL): Not Applicable
Not Applicable
Lower Flammable Limit (LFL): Not Applicable
Rate of Burning:

SECTION 6
ACCIDENTAL RELEASE MEASURES
CONTAINMENT/ CLEAN-UP:
No special precautions. Dust or loose fibers may be vacuumed or swept up with the aid of a dust suppressant.
DISPOSAL:
In most cases, woven fiberglass scrap can be disposed of in a sanitary landfill.

SECTION 7
HANDLING AND STORAGE
HANDLING:
Avoid contact with skin and eyes.
STORAGE:
Keep dry

MATERIAL SAFETY DATA SHEET

MSDS #88-910-005E
Page 3 of 3

CGC Brand Fiberglass Tape
SECTION 8
EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS:
Selection of engineering controls will depend on environmental working conditions and operations.
RESPIRATORY PROTECTION:
Special ventilation typically is not necessary, but may be desirable in specific work conditions. Use mechanical or local
exhaust ventilation to keep levels below TLV.
OTHER PERSONAL PROTECTIVE EQUIPMENT:
Eye/Face: Wear eye protection (safety glasses or goggles) to avoid particulate irritation of the eye.
Skin: Gloves or protective clothing are usually not necessary, but may be desirable in specific work conditions.
General: Selection of Personal Protective Equipment will depend on environmental working conditions and operations.

SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Physical State
Odor
pH @ 25 º C
Particle Size
Molecular Weight
Bulk Density
Specific Gravity (H20 = 1)
Percent Volatile
VOC Content

White woven scrim type fabric.
Solid
Viscosity
Low to no odor
Solubility (H2O)
Not Applicable
Boiling Point
Not Applicable
Melting Point
Not Applicable
Softening Point
Not Applicable
Freezing Point
Not Applicable
Vapor Density (Air = 1)
Zero
Vapor Pressure (mm Hg)
Zero
Evaporation Rate (BuAc = 1)

SECTION 10
CHEMICAL STABILITY AND REACTIVITY
STABILITY:
CONDITIONS TO AVOID:
INCOMPATIBILITY:
HAZARDOUS POLYMERIZATION:
HAZARDOUS DECOMPOSITION:

Stable.
Contact with incompatibles.
Hydroflouric acid.
Will not occur.
None known.

SECTION 11
TOXICOLOGICAL INFORMATION
ACUTE EFFECTS:
Direct contact may cause eye, skin and/or respiratory irritation.
LD50: Not Available for product.
LC50: Not Available for product.
CHRONIC EFFECTS / CARCINOGENICITY:
Direct, prolonged or repeated contact with the skin may cause irritation.

Not Applicable
Not Applicable
Not Applicable
Not Applicable
Not Applicable
Not Applicable
Not Applicable
Not Applicable
Not Applicable

MSDS #88-910-005E
Page 4 of 4

MATERIAL SAFETY DATA SHEET
CGC Brand Fiberglass Tape
SECTION 12
ECOLOGICAL INFORMATION
ENVIRONMENTAL TOXICITY: This product has no known adverse effect on the ecology.
Ecotoxicity value: Not determined.

SECTION 13
DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD:
In most cases, woven fiberglass scrap can be disposed of in a sanitary landfill. Dispose of material in accordance with
Federal, State, Provincial, and Local regulations

SECTION 14
TRANSPORT INFORMATION
U.S. DOT INFORMATION: Not a hazardous material per DOT shipping requirements. Not classified or regulated.
Same as product name.
Shipping Name
Not classified
Hazard Class:
None. Not classified.
UN/NA #:
None.
Packing Group:
Not applicable.
Label (s) Required:
Not classified.
GGVSec/MDG-Code:
Not applicable.
ICAO/IATA-DGR:
None
RID/ADR:
None
ADNR:

SECTION 15
REGULATORY INFORMATION
UNITED STATES REGULATIONS

WT%

302

304

313

CAA Sec.
112

Fibrous Glass (Continuous Filament)

65-70

NL

NL

NL

NL

NL

Key :

RCRA
Code

MATERIAL

CERCLA

All ingredients of this product are included in the U.S. Environmental Protection Agency’s Toxic Substances Control Act
Chemical Substance Inventory.

NL = Not Listed
SARA Title III Section 302 (EPCRA) Extremely Hazardous Substances: Threshold Planning Quantity (TPQ)
SARA Title III Section 304 (EPCRA) Extremely Hazardous Substances: Reportable Quantity (RQ)
SARA Title III Section 313 (EPCRA) Toxic Chemicals: X= Subject to reporting under section 313
CERCLA Hazardous Substances: Reportable Quantity (RQ)
CAA Section 112 (r) Regulated Chemicals for Accidental Release Prevention: Threshold Quantities(TQ)
RCRA Hazardous Waste: RCRA hazardous waste code

NL

MSDS #88-910-005E
Page 5 of 5

MATERIAL SAFETY DATA SHEET
CGC Brand Fiberglass Tape
SECTION 15 REGULATORY INFORMATION (continued)
CANADIAN REGULATIONS

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the
MSDS contains all the information required by the Controlled Products Regulations. All components of this product are
included in the Canadian Domestic Substances List (DSL).
MATERIAL
Fibrous Glass (Continuous Filament)

WT%
65-70

IDL Item #
Not Listed

WHMIS Classification:
Not Listed

IDL Item # : Canadian Hazardous Products Act – Ingredient Disclosure List Item #
WHMIS Classification: Workplace Hazardous Material Information System
CARCINOGENICITY CLASSIFICATION OF INGREDIENT(S): None

SECTION 16
OTHER INFORMATION
∆WARNING!
Avoid exposure to dust. Dust may cause eye, skin, nose, throat or respiratory irritation. Avoid eye contact or inhalation
of dust. Wear eye protection. If eye contact occurs, flush thoroughly with water. If dusty conditions exist, wear a
NIOSH/MSHA-approved respirator to prevent coughing, sneezing and respiratory irritation. Do not ingest. If ingested,
call physician. Product safety information: (800) 507-8899 or www.cgcinc.com
KEEP OUT OF REACH OF CHILDREN.
Key/Legend
TLV
PEL
CAS
NIOSH
MSHA
OSHA
ACGIH
IARC
DOT
EPA
NFPA
HMIS
PPE
TSCA
DSL
NDSL
SARA
RCRA
CERCLA
UN/NA#
CFR
WHMIS

Threshold Limit Value
Permissible Exposure Limit
Chemical Abstracts Service (Registry Number)
National Institute for Occupational Safety and Health
Mine Safety and Health Administration
Occupational Health and Safety Administration
American Conference of Governmental Industrial Hygienists
International Agency for Research on Cancer
United States Department of Transportation
United States Environmental Protection Agency
National Fire Protection Association
Hazardous Materials Identification System
Personal Protection Equipment
Toxic Substances Control Act
Canadian Domestic Substances List
Canadian Non-Domestic Substances List
Superfund Amendments and Reauthorization Act of 1986
Resource Conservation and Recovery Act
Comprehensive Environmental Response, Compensation and Liability Act of 1980
United Nations/North America number
Code of Federal Regulations
Workplace Hazardous Material Information System

MATERIAL SAFETY DATA SHEET
CGC Brand Fiberglass Tape
SECTION 16 OTHER INFORMATION (continued)
Prepared by:
Product Safety
USG Corporation
125 South Franklin St.
Chicago, Illinois 60606

MSDS #88-910-005E
Page 6 of 6

Material Safety Data Sheet

U.S. Department of Labor

May be used to comply with OSHA’s Hazard
Communication Standard, 29 CFR 1910 1200. Standard
must be consulted for specific requirements.

Occupational Safety and Health Administration
(Non-Mandatory Form)
Form Approved
OMB No. 1218-0072
Note: Blank spaces are not permitted. If any item is not
applicable or no information is available, the space
must be marked to indicate that.

IDENTITY (as Used on Label and List)
Silicon Carbide Sanding Screen
Section I
Manufacturer’s name

Superior Abrasives, Inc.

Emergency Telephone Number

1-937-278-9123

Address (Number, Street, City, State and ZIP Code)

Telephone Number for Information 1-937-278-9123

4800 Wadsworth Road

Date Prepared January 1, 2006

Dayton, OH 45413

Signature of Preparer (optional)

Section II—Hazardous Ingredients/Identity Information
Hazardous Components (Specific Chemical Identity, Common Name(s))
OSHA PEL
3

Abrasive Grain: Silicon Carbide
15mg/m
Binding Resin: Epoxy and Phenol Formaldehyde Resin (Cured)
N/A
Flexible Backing: Cloth
N/A

Other Limits
Recommended

ACGIH TLV
3

10mg/m
N/A
N/A

% (optional)

55-65
5-15
20-30

Section III—Physical/Chemical Characteristics
Boiling Point

Specific Gravity (H20 = 1) N/A

N/A

Vapor Pressure (mm Hg) N/A

Melting Point N/A

Vapor Density (AIR = 1)N/A

Evaporation Rate (Butyl Acetate = 1) N/A

Solubility in Water N/A
Appearance and Odor Cones of cloth coated with abrasive grain and resin binder

Section IV—Fire and Explosion Hazard Data
Flash Point (Method Used)N/A

Flammable Limits

LEL N/A

UEL N/A

Extinguishing Media Carbon Dioxide, Foam, Water, Dry Chemical
Special Fire Fighting Procedures None

Unusual Fire and Explosion Hazards

(Reproduce locally)

None
OSHA 174 Sept. 1985

Section V—Reactivity Data
Stability

Unstable

Conditions to Avoid None

Stable XX
Incompatibility (Materials to Avoid) None
Hazardous Decomposition or Byproducts None
May Occur

Hazardous
Polymerization

Conditions to Avoid None

Will Not Occur XX

Section VI—Health Hazard Data
Route(s) of Entry

Inhalation? Airborne Dust

Health Hazards (Acute and Chronic)

Ingestion? N/A

Acute: Breathing difficulty: skin, eye, nasal, and respiratory irritation.

Carcinogenicity N/A

NTP? N/A

Signs and Symptoms of Exposure

Skin? N/A

IARC Monographs? N/A

OSHA Regulated? no

Deposits of Material on the skin, in the eyes and/or nasal passages. Coughing and/or difficulty

Breathing may be present.
Medical Conditions
Generally Aggravated by Exposure

Pulmonary Disorders

Emergency and First Aid Procedures

Provide fresh air. Flush eyes with approved eye wash.

Section VII—Precautions for Safe Handling and Use
Steps to Be Taken in Case Material Is Released or Spilled

Waste Disposal Method

By any conventional means

Precautions to Be Taken in Handling and Storing

Other Precautions

No special procedures

No special procedures

Observe recommended running speeds

Section VII—Control Measures
Respiratory Protection (Specify Type)
Ventilation

Local Exhaust

utilize approved respiratory protection for nuisance dust.

Utilize to keep airborne concentration

Special N/A

below limits
Mechanical (General)

Appropriate hoods and dust
collection recommended

Protective Gloves

Recommended to protect skin from abrasion

Other Protective Clothing or Equipment
Work/Hygienic Practices

None

Ordinary personal cleanliness practices

Other N/A

Eye Protection

Face shield or goggles when grinding

MATERIAL SAFETY DATA SHEET
NPCA

FOR COATINGS, RESINS AND RELATED MATERIALS
(Approved by US Department of Labor Essentially Similar to Form OSHA 20)
Date Issued 11/30/05
SECTION I
MANUFACTURER’S NAME

GARDNER ASPHALT CORPORATION.
STREET ADDRESS
4161 E 7TH AVENUE

CITY, STATE, AND ZIP CODE
TAMPA, FL 33605

EMERGENCY TELEPHONE NUMBER

1-800-424-9300
PRODUCT CLASS
ROOF CEMENT MASTIC A/F (WET/DRY) AKA
PLASTIC RF CEMENT/FLASHING CEMENT
TRADE NAME

MANUFACTURER’S CODE
IDENTIFICATION
0370-GA, 0375-GA

GARDNER, WEATHERSEAL, STA-KOOL, BLACKJACK

SECTION II- HAZARDOUS INGREDIENTS
INGREDIENT

PERCENT

PETROLEUM ASPHALT
CAS # - 8052-42-4
STODDARD SOLVENT
CAS #- 8052-41-3
CELLULOSE FIBER
CAS #- 9004-34-6
SILICATE MINERAL
CAS #- 7631-86-9

TLV
PPM

<40%

TLV
Mg/M3

LEL

VAPOR
PRESSURE

0.5
Fume

<20%

100

<10%

10*

<20%

10*

ADDITIONAL INFORMATION- * AS RESPIRABLE FRACTION OF DUST
Hazardous Materials Identification System (HMIS)
Health
1

Flammability
2

Reactivity

Personal Protection
C

1

SECTION III – PHYSICAL DATA
BOILING RANGE: 300 ºF - 390ºF
EVAPORATION RATE

FASTER

VAPOR DENSITY
SLOWER, THAN
ETHER

HEAVIER

LIGHTER, THAN AIR

PERCENT VOTILE BY
VOLUME 60 %

WEIGHT PER GALLON
BY VOLUME 8.4 LBS

SECTION IV – FIRE AND EXPLOSION HAZARD DATA
DOT CATEGORY - NA

FLASH POINT-

105ºF Minimum

EXTINGUISHING MEDIA- CO2, FOAM, & DRY CHEMICAL . DO NOT USE HALOGENATED EXTINGUISHING AGENTS.
UNUSUAL FIRE AND EXPLOSION HAZARDS- CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME
HEAT. PRODUCTS OF COMBUSTION MAY BE TOXIC.
SPECIAL FIRE FIGHTING PROCEDURES- WEAR MSHA/NIOSH APPROVED POSITIVE BREATHING APPARATUS IS
RECOMMENDED FOR FIREFIGHTERS. WATER MAY BE USED TO COOL CLOSED CONTAINERS, BUT MAY CAUSE
FROTHING, APPLY CAUTIOUSLY. HIGH PRESSURE STREAM WILL SPREAD FIRE. DO NOT USE HALOGENATED
EXTINGUISHING AGENTS!.

SECTION V – REACTIVITY DATA
STABILITY:

UNSTABLE

STABLE

CONDITIONS TO AVOID: SPARK, FLAMES,
ELECTRICAL AND STATIC DISCHARGE.

INCOMPATIBILTY (MATERIALS TO AVOID): STRONG OXIDIZERS, ACIDS, AND HALOGENATED CHEMICALS
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON DIOXIDE, CARBON MONOXIDE, NOX, SOX, H2S AND
REACTIVE HYDROCARBONS
HAZARDOUS POLYMERIZATION:

MAY OCCUR

WILL NOT OCCUR

CONDITIONS TO AVOID: NONE

SECTION VI-HEALTH HAZARD DATA
EFFECTS OF OVEREXPOSURE- ACUTE: SKIN: PROLONGED REPEATED CONTACT MAY CAUSE IRRITATION. EYES:

CONTACT MAY CAUSE IRRITATION, BLURRED VISION, REDNESS. INHALATION: EXCESSIVE BREATHING OF HIGH
VAPOR CONCENTRATION CAN CAUSE POSSIBLE UNCONSCIOUSNESS AND EVEN ASPHYXIATION. INGESTION: CAN
CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING AND DIARRHEA. CARCINOGENICITY: MATERIAL
CONTAINS PETROLEUM ASPHALT. IARC HAS DETERMINED THAT THERE IS ANADEQUATE EVIDENCE THAT ASPHALT
ALONE IS CARCINOGENIC TO HUMANS, IN SOLUTION; SOLVENT EXTRACTS CAN PRODUCE SKIN CANCER IN ANIMALS
FOLLOWING PROLONGED AND REPEATED CONTACT. IARC HAS CONCLUDED THAT THERE IS SUFFICIENT EVIDENCE
OF THE CARCINOGENICITY OF ASPHALT EXTRACTS. THEREFORE, CUTBACKS LIKE THIS PRODUCT MAY ALSO BE
IMPLICATED AS POTENTIALLY CARCINOGENIC. PLEASE FOLLOW MSDS PRECAUTIONARY MEASURES. SYNERGISTIC
MATERIALS: N/A. REPRODUCTIVE EFFECTS: ND. TERATOGENIC: NO. MUTAGENIC: NO.

CALIF. PROP. 65 • CHEMICAL WARNING (CALIFORNIA HEALTH AND SAFETY CODE #25249.5 ET SEQ).
WARNING: This product contains chemicals known to the State of California to cause cancer, birth defects or reproductive harm.
Read and follow label directions and information given on Material Safety Data Sheets and use care when handling or using all
petroleum products.
EMERGENCY FIRST AID PROCEDURE- SKIN: WASH EXPOSED AREAS WITH SOAP AND WATER. EYES: FLUSH EYES
WITH COPIOUS AMOUNTS OF WATER , IF SYMPTOMS PERSIST, CONSULT A PHYSICIAN. INHALATION: REMOVE PERSON
TO FRESH AIR. IF BREATHING IS DIFFICULT ADMINISTER OXIGEN. IF BREATHING STOPS, GIVE ARTIFICIAL
RESPIRATION. SEEK MEDICAL ATTENTION IMMEDIATELY. INGESTION: DO NOT INDUCE VOMITING.

SECTION VII – SPILL OR LEAK PROCEDURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: SOAK UP SPILL WITH SAND OR OTHER
ABSORBENT. REMOVE SOURCES OF IGNITION. PLACE IN CONTAINERS. WASH AREA.
WASTE DISPOSAL METHOD: DISPOSE IN ACCORDANCE WITH LOCAL, STATE OR FEDERAL REGULATIONS.

SECTION VIII – SPECIAL PROTECTION INFORMATION

RESPIRATORY PROTECTION: NOT NORMALLY REQUIRED IN WELL-VENTILATED AREA. IF TLV IS EXCEEDED, A

NIOSH/MSHA APPROVED BREATHING APPARATUS IS RECOMMENDED.

VENTILATION: USE WITH ADEQUATE VENTILATION. MAINTAIN EXPOSURE BELOW TLV LEVEL.
PROTECTIVE GLOVES: NITRILE RUBBER GLOVES SHOULD BE USED, AS WELL AS LONG SLEEVES.
EYE PROTECTION: FACE SHIELD AND SAFETY GOGGLES SHOULD BE USED.
OTHER PROTECTIVE EQUIPMENT: SOLVENT RESISTANT APRON AND BOOTS

SECTION IX – REGULATORY INFORMATION
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: STORE IN COOL DRY AREA.
OTHER PRECAUTIONS: KEEP OUT OF REACH OF CHILDREN AND AWAY FROM SOURCES OF IGNITION. AVOID
CONTACT WITH SKIN OR CLOTHING. KEEP CONTAINER CLOSED. WASH THOROUGHLY AFTER USING.

MATERIAL SAFETY DATA SHEET
MSDS Number: TP004997

Revision Date: May 2007

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
TRADE NAME: 808 Cold Application Cement, 829 Fibered Roof Coating
LABEL: TAM-PRO
USE & DESCRIPTION: Roofing Coatings
CHEMICAL FAMILY: Asphalt Mixture
MANUFACTURED FOR:
TAMKO Building Products, Inc.
P.O. Box 1404
Joplin, MO 64802-1404

EMERGENCY TELEPHONE NUMBERS;
General Information: 1-904-284-7571 (8 a.m. - 5 p.m. EST)
1-620-429-1800 (8 a.m. - 5 p.m. CST)
1-417-624-6644 (8 a.m. - 5 p .m. CST)
Chemtrec: 1-800-424-9300

2. COMPOSITION/INFORMATION ON INGREDIENTS
Exposure Limits*
Components

Cas No.

% by Wt.

OSHA
TWA

ACGIH
STEL

TWA

STEL

Unit

Petroleum asphalt

8052-42-4

<70

5 fume

NE

.5 fume

NE

mg/m³

Mineral spirits

8052-41-3

<30

200

NE

100

NE

ppm

Clay**

1332-58-7

<15

10 total dust
5 resp. dust

NE

mg/m³
mg/m³

Cellulose fibers

65996-61-4

<6

NE

NE

Calcium carbonate**

1317-65-3

<5

10 total dust
5 resp. dust

NE

mg/m³
mg/m³

0.1
0.05

NE
NE

mg/m³
mg/m³

**contains:
crystalline silica >0.1%
quartz
14808-60-7
crystobalite
14464-46-1

15 total dust NE
5 resp. dust
NE

15 total dust NE
5 resp. dust

>0.1
0.1
0.05

*See Section 8 for additional relevant exposure limits
NE = Not established

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NE

MSDS Number: TP004997

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3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
WARNING!
COMBUSTIBLE
VAPORS, MISTS OR FUMES MAY IRRITATE THE EYES AND RESPIRATORY TRACT
MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION
DIRECT CONTACT MAY CAUSE EYE AND SKIN IRRITATION
HEATING MAY RELEASE TOXIC HYDROGEN SULFIDE GAS (H2S) WHICH MAY ACCUMULATE IN
CONFINED SPACES
ASPIRATION HAZARD IF SWALLOWED
ASPHALT MAY CONTAIN COMPONENTS THAT ARE SKIN CANCER HAZARDS

HMIS Rating:
Health - 1
Flammability - 2
Reactivity - 0

NFPA Rating:
Health - 2
Flammability - 2
Reactivity - 0

Potential Health Effects:
EYE CONTACT: May cause eye irritation resulting in tearing, stinging, redness or swelling. Vapors,
mists, or fumes may be irritating.
SKIN CONTACT: Contact may cause skin irritation. Redness, drying and cracking of the skin
(dermatitis), may occur following prolonged and repeated contact. In addition, prolonged and
repeated exposure to asphalt fumes has been reported to cause an acne-like skin condition, skin
discoloration, and may increase sensitivity to the sun (photosensitization).
SKIN ABSORPTION: Not expected to be significant with short-term skin contact. However,
prolonged or repeated skin contact may result in absorption of hazardous components.
INGESTION: In general, asphalt products have low toxicity when swallowed. However, this
product may cause irritation of the digestive tract followed by vomiting and central nervous system
depression (see “Inhalation” for symptoms). If vomiting occurs, small amounts of material can be
aspirated into the lung and cause inflammation or damage with chemical pneumonia.
INHALATION: Exposure to fumes, vapors, or mists may cause irritation of the nose and throat, and
possible signs of central nervous system depression (symptoms may include headache, excitation,
dizziness, a loss of coordination, and drowsiness). Loss of consciousness can occur in poorly
ventilated or confined spaces. Additional signs and symptoms of exposure may include reduced
appetite and abnormal fatigue. Use of this product in well-ventilated working conditions is not
expected to cause adverse effects.

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NOTE: Hydrogen sulfide (H2S), an extremely toxic gas, may be emitted from heated asphalt and
may accumulate in storage tanks and other confined spaces. At low concentrations, H2S is irritating
to the eyes, nose and throat, and at high concentrations (>500 ppm) can cause rapid
unconsciousness and death. The odor of H2S cannot be used as an indicator of exposure, because
the gas causes rapid olfactory fatigue which deadens the sense of smell. Use this product only
under well-ventilated working conditions.
CHRONIC EFFECT/CARCINOGENICITY/SPECIAL TOXIC EFFECTS: This product contains
petroleum asphalt. Petroleum asphalt is not listed as a carcinogen by OSHA or NTP. The
International Agency for Research on Cancer (IARC) has determined there is inadequate evidence
that asphalt alone is carcinogenic to humans, and that there is inadequate evidence for the
carcinogenicity of undiluted air-refined asphalts in experimental animals. The National Institute of
Occupational Safety and Health (NIOSH) has, concluded that at higher temperatures roofing
asphalt fumes are a potential occupational carcinogen. If this product is heated or comes in contact
with heated material, avoid breathing fumes.
This material contains a hydrocarbon solvent. When dissolved in hydrocarbon solvents, asphalt
has produced skin tumors in animals following prolonged and repeated contact. Consequently,
IARC has determined that there is sufficient evidence that extracts or cutbacks (asphalts dissolved
in hydrocarbon solvents) are carcinogenic to experimental animals. This product may contain small
amounts of polyaromatic hydrocarbons which are recognized carcinogens in humans and
experimental animals.
This material contains a hydrocarbon solvent. Reports have associated prolonged or repeated
occupational overexposure to solvents with permanent brain and nervous system damage
(sometimes referred to as “Solvent or Painters Syndrome”. Intentional misuse by deliberately
inhaling vapors of this product may be harmful or fatal.
This product contains small amounts of respirable crystalline silica (quartz and crystobalite). IARC
and NTP have determined that there is sufficient evidence for the carcinogenicity of respirable
crystalline silica in experimental animals and limited evidence for its carcinogenicity in humans.
The presence of crystalline silica in this product is not expected to present an inhalation hazard
since the material is not a dust and is typically troweled onto a surface and allowed to harden. In
addition, the hardened product is not anticipated to present a health hazard unless is subjected to
mechanical forces including grinding, drilling, or other demolition work. In such cases, the silica
may be liberated in dust form. Prolonged and repeated exposure to respirable silica-containing dust
may have serious lung effects, including silicosis, bronchitis, and lung cancer.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing medical conditions that
may be aggravated by exposure include disorders of the skin and respiratory tract including
asthma.

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4. FIRST AID MEASURES
EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the eye lids to ensure thorough rinsing. Get medical attention if irritation persists. Get
immediate medical attention if there is direct eye contact with hot material.
SKIN CONTACT: Clean any exposed skin with warm soapy water. Use a waterless hand cleaner
to help remove the asphalt. Do not use solvents or thinners to remove material from skin. Get
medical attention if irritation persists or develops.
INGESTION: If swallowed, do not induce vomiting because of danger of aspirating material into
lungs, resulting in damage and chemical pneumonia. Never give anything by mouth to an
unconscious person. If vomiting occurs, keep head lower than hips to prevent aspiration. Get
immediate medical attention.
INHALATION: If inhalation overexposure to vapors, mists, or fumes occurs, remove person to
fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Get
immediate medical attention.
NOTES TO PHYSICIAN: Medical personnel can soften and remove asphalt with petroleum jelly or
white mineral oil.
In general, emesis induction is unnecessary in high viscosity products. Also contains mineral spirits
that, when aspirated into the lung, may result in chemical pneumonia. If large volumes have been
swallowed, gastric lavage should be considered. Patients may be predisposed to pneumonia
during convalescence, and should be kept under observation. Inhalation exposure of hydrogen
sulfide may also result in pulmonary congestion. Contact a Poison Center for additional treatment
information.

5. FIRE FIGHTING MEASURES
FLASH POINT (METHOD): 112 ºF (COC)
FLAMMABLE LIMITS (% VOLUME IN AIR - SOLVENT COMPONENT):
Lower= 0.8
Upper = 7.0
AUTOIGNITION TEMPERATURE: 460 ºF
EXTINGUISHING MEDIA: Dry chemical and carbon dioxide or foam, are preferred. Avoid use of
straight-stream water.
SPECIAL FIRE FIGHTING PROCEDURES: Combustible. Avoid breathing irritating and
potentially toxic fumes, including hydrogen sulfide gas. Firefighters should not enter confined
spaces without wearing NIOSH approved positive pressure breathing apparatus (SCBA) with full
face mask and full protective equipment. Water may be used to cool containers in a fire-exposed
area.
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UNUSUAL FIRE OR EXPLOSION HAZARDS: When heated above the flashpoint of the mineral
spirit component (100oF), fumes may burn if ignition source is provided. Petroleum asphalt fumes
can explode if emitted in an enclosed environment and supplied with an ignition source. Containers
exposed to intense heat from fires should be cooled with water to prevent vapor pressure buildup
which could result in container rupture.

6. ACCIDENTAL RELEASE MEASURES
PRECAUTIONS IF MATERIAL IS SPILLED OR RELEASED: Combustible. Handling equipment
must be grounded to prevent sparking. Remove ignition sources, ventilate area, and avoid
inhalation or skin contact by using appropriate precautions outlined in this MSDS (see Section 8).
Stop leak and contain spilled material with absorbent material. Collect adsorbed product and clean
up materials in appropriate container for proper disposal. Move containers from spill area. For
larger spills, keep unnecessary people away. Stay upwind of and away from spill. Notify proper
authorities. Prevent materials from entering drains, sewers, or waterways. Spills entering surface
waters or sewers (entering/leading to surface waters), that cause a sheen, must be reported to the
National Response Center (1-800-424-8802).
WASTE DISPOSAL METHODS: Dispose in accordance with applicable Federal, State and Local
regulations.

7. HANDLING AND STORAGE
STORAGE TEMPERATURE: Store away from heat and all ignition sources and open flames in
accordance with applicable laws and regulations.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Follow protective controls
outlined in this MSDS (see Section 8). Avoid all ignition sources. Storage areas should be
ventilated to reduce fire and explosion hazards, and possible overexposure of personnel to fumes
and vapors. Keep containers closed when not in use. Do not store near food and beverages or
smoking materials.
NOTE: Hydrogen sulfide (H2S), an extremely toxic gas, may be emitted from heated asphalt and
may accumulate in storage tanks and other confined spaces.
Empty containers retain residue (liquid and/or vapor) and can be dangerous. DO NOT
PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH
CONTAINERS TO HEAT, FLAME, SPARKS, OR OTHER SOURCES OF IGNITION. THEY MAY
EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to clean since residue is difficult to
remove. For work on tanks, refer to OSHA regulations, ANSI Z49.1, and other governmental and
industrial references pertaining to cleaning, repairing, welding or other contemplated operations.
To prevent fire or explosion risk from static accumulation and discharge, effectively ground product
transfer system in accordance with NFPA standard for petroleum products.

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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
RESPIRATORY PROTECTION: Normally not needed in well-ventilated areas. If applicable
standards are exceeded or are likely to be exceeded, use a NIOSH/MSHA approved, contaminantspecific, air-purifying respirator. If such concentrations are sufficiently high that this respirator is
inadequate, or high enough to cause oxygen deficiency, use a positive pressure self-contained
breathing apparatus (SCBA). Follow all applicable respirator use, fitting, and training standards and
regulations.
EYE PROTECTION: Chemical safety goggles or face shield needed if spraying or eye contact is
possible.
SKIN: Chemical resistant gloves, apron, or other protective clothing needed to prevent skin
contact.
VENTILATION: Use only with adequate ventilation to maintain exposures below appropriate
exposure limits. Local exhaust ventilation and/or enclosure of the process may be required. All
equipment must be explosion proof.
EXPOSURE GUIDELINES: See section 2 for component materials.
Additional potentially relevant exposure limits are listed below:

Components

Xylene

CAS No.

1330-20-7

Exposure Limits
OSHA
ACGIH
TWA
STEL
TWA
STEL

100

150

100

150

Unit

ppm

Other Information:
Avoid prolonged or repeated skin contact. Remove contaminated clothing; launder or dry clean
before reuse. Workers should wash their hands before breaks, meals, smoking and using toilet
facilities. Product is readily removed from skin by waterless hand cleaners followed by washing
with soap and water. Do not use solvents or thinners to remove material from skin.
A fresh water supply, including an eye wash for emergency first aid, and washing facilities should
be readily available. An oil-dissolving skin cleaner should be available.

9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE AND ODOR: Black liquid solvent odor.
BOILING POINT: 315 ºF
Ph: Not applicable
MELTING POINT: Not applicable

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SPECIFIC GRAVITY: 0.98 – 1.0
VAPOR PRESSURE: 2mm @ 70 ºF
VAPOR DENSITY (AIR = 1): 5
% VOLATILE, BY VOLUME: <30
SOLUBILITY IN WATER: Negligible
EVAPORATION RATE (BUTYL ACETAT = 1): <0.1
OTHER PHYSICAL AND CHEMICAL DATA: None

10. STABILITY AND REACTIVITY
STABILITY: Stable
CONDITIONS TO AVOID: Keep from heat, sparks, open flame, and other sources of ignition.
Avoid contact with strong oxidizing agents. Prevent vapor accumulation.
HAZARDOUS POLYMERIZATION: Will not occur.
INCOMPATIBILTY (MATERIALS TO AVOID): Strong acids or bases, oxidizing agents and
selected amines.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, ozone,
hydrogen sulfide, oxides of sulfur and various hydrocarbons.

11. TOXICOLOGICAL INFORMATION: According to NIOSH, research has identified low
levels of Polycyclic Aromatic Hydrocarbons (PAHs) in laboratory generated asphalt fumes.
Benzo(a)pyrenes, known carcinogens, have been identified in field-generated asphalt fumes.
Asphalt roofing fume condensates and fractions have been shown to contain chemicals known as
PAC’s, which have a chemical structure similar to known carcinogens and genotoxins. Laboratorygenerated asphalt fumes have been shown to be genotoxic. Laboratory-derived roofing asphalt
fume condensates have been shown to be mutagenic, clastogenic, and inhibit intracellular
communication in mammalian cells.
Laboratory studies have shown chemical extracts of asphalt fumes to be carcinogenic to the skin of
experimental animals following lifetime exposures, and to show positive mutagenicity in screening
bioassays. The relevance of these studies to human exposures is not known at this time.
Inhalation studies have not been conclusive regarding asphalt’s carcinogenic potential; however,
adverse lung effects were seen in several species of laboratory animals.
Skin application of undiluted air-refined (oxidized) asphalt to experimental animals has not resulted
in skin tumors. The results were weakly positive when the samples were applied in a solvent
vehicle.

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12. ECOLOGICAL INFORMATION: No specific data on this product. Product may cause
mechanical damage to aquatic organisms. The mineral spirit component is expected to volatilize in
the environment and to be moderately toxic to both freshwater and marine organisms. The
bioaccumulation potential is unknown.

13. DISPOSAL CONSIDERATIONS: Dispose in accordance with Federal, State and Local
regulations. Prevent materials from entering drains, sewers, or waterways. Do not dump on the
ground.

14. TRANSPORT INFORMATION:
DOT PROPER SHIPPING NAME: TARS, LIQUID
DOT HAZARD CLASSIFICATION: Combustible Liquid. Non-regulated in non-bulk quantities (less
than 119 gallons each). This exception to 49 CFR is cited at 173.150(f).
DOT LABELING REQUIREMENTS: Combustible Liquid
UN/NA NUMBER: NA1999
PLACARDS: Combustible Liquid
IMDG CODE: Hazardous for vessel transport under the IMDG Code
IMDG SHIPPING NAME: Tars, Liquid
IMDG HAZARD CLASS: 3
UN/ID NUMBER: UN 1999
PACKING GROUP NUMBER: PG III

15. REGULATORY INFORMATION
TOXIC SUBSTANCES CONTROL ACT (TSCA): The components in this product are listed on the
TSCA Inventory.
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT
(CERCLA): The material contains xylene. The reportable quantities for xylene are 1000 lb. Any
release of this product that results in a release of xylene equal to or exceeding the reportable
quantity must be reported to the National Response Center (800-424-8802) and appropriate state
and local regulatory agencies as described in 40 CFR 117,302.

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SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA), TITLE III:
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES: None
SECTION 311/312 HAZARD CATEGORIES:
Immediate Health
Delayed Health
Fire Hazard
SECTION 313 REPORTABLE INGREDIENTS:
Chemical Name
Xylene

CAS Number
1330-20-7

Concentration (% by Wt.)
<1

CALIFORNIA PROPOSITION 65
WARNING: This product contains a chemical known to the State of California to cause cancer and
birth defects or other reproductive harm.

16. OTHER INFORMATION
•
•

•

Preparation Date: March 1997
Revised:
o August 2004 (DOT Transport information and Prop 65 language)
o August 2005 (Changes in emergency contact information)
o June 2006 (Company name change)
o May 2007 (Formatting Issues)
Replaces: None

Disclaimer of Liability
The information and recommendations contained herein are to the best of TAMKO Building Products, Inc.’s
knowledge and belief, accurate and reliable as of the date issued. TAMKO Building Products, Inc. does not warrant
or guarantee their accuracy or reliability, and TAMKO Building Products, Inc. shall not be liable for any loss or
damage arising out of the use thereof.
The information and recommendations are offered for the user’s consideration and examination, and it is the user’s
responsibility to satisfy itself that they are suitable and complete for its particular use.

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Material Safety Data Sheet - MSDS
ExpertSeal Asphalt Repair
ExpertSeal Pot Hole Patch
Section 1. Chemical Product and Company Identification
Trade name
Material Uses
Supplier

: ExpertSeal Asphalt Repair
ExpertSeal Pot Hole Patch
: Asphalt repair and maintenance.

Validation Date

: ExpertSeal
1483, Sainte-Marguerite
Mercier, QC J6R 2L1
Tel: 1-800-573-7325
Tel: 1-450-698-0264
Fax: 1-450-698-0265

Manufacturer

: 2/25/2004.

In Case of Emergency : 1-800-573-7325
: ExpertSeal
1483, Sainte-Marguerite
Mercier, QC J6R 2L1
Tel: 1-800-573-7325
Tel: 1-450-698-0264
Fax: 1-450-698-0265
Copeland Coatings Co. Inc.
P.O. Box 595, 3600 Route 20
Nassau, NY, 12123
Tel: 1-800-303-4219

Section 2. Composition, Information on Ingredients
CAS #

Name

% by Weight

UN number

Limestone
1317-65-3
70-100
Not regulated.
Liquid Petroleum Asphalt
8052-42-4
3-5
Not regulated.
Fuels, diesel
68334-30-5
1-3
UN1202
This product is a manufactured product under the Canadian WHMIS. Therefore it is EXEMPTED from the regulatory
requirements under WHMIS. This MSDS has been written for workers using this product.

Section 3. Hazards Identification
Physical State and
Appearance
Emergency Overview

: Solid. (Granular solid.)

Potential Chronic Health
Effects

: CARCINOGENIC EFFECTS: Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
: Repeated or prolonged exposure is not known to aggravate any medical condition. This product
contains substances that may be hazardous to human health but the risk of exposure to such
substances is found negligeable. This is why it is not classified under WHMIS.
: Not available.

: WARNING!
MAY CAUSE RESPIRATORY TRACT IRRITATION.
Keep container closed. Use with adequate ventilation.
Routes of Entry
: Skin contact. Eye contact. Inhalation. Ingestion.
Potential Acute Health Effects
Eyes : Slightly hazardous in case of eye contact (irritant).
Skin : Slightly hazardous in case of skin contact (irritant). Non-sensitizer for skin.
Inhalation : Hazardous in case of inhalation (lung irritant).
Ingestion : Slightly hazardous in case of ingestion.

Medical Conditions
Aggravated by
Overexposure:
Over-exposure
signs/symptoms
See Toxicological Information (section 11) for a partial list of welding fumes ingredients.

Continued on Next Page

ExpertSeal Asphalt Repair
ExpertSeal Pot Hole Patch

Page: 2/5

Section 4. First Aid Measures
Eye Contact
Skin Contact

Inhalation
Ingestion
Notes to Physician

: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of
water for at least 15 minutes. Get medical attention if irritation occurs.
: Wash with soap and water. Get medical attention if irritation develops. Do not attempt to remove cold
asphalt. Do not use solvents to clean skin covered with asphalt. Vegetable oil may be used to remove
asphalt residue on skin surface.
: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical attention.
: Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to
an unconscious person. Get medical attention if symptoms appear.
: No specific antidot, medical staff contact Poisons Information Centre.

Section 5. Fire Fighting Measures
Flammability of the Product
Auto-ignition Temperature
Flash Points
Flammable Limits
Products of Combustion
Fire Hazards in Presence of
Various Substances
Explosion Hazards in
Presence of Various
Substances
Fire Fighting Media
and Instructions
Protective Clothing (Fire)

:
:
:
:
:
:

Non-flammable.
Not applicable.
Not applicable.
Not applicable.
Not applicable.
Not applicable.

: Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
: Use extinguishing media suitable for surrounding materials.
: Not applicable.

Section 6. Accidental Release Measures
Small Spill and Leak

Large Spill and Leak

: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and dispose of according to local and regional authority
requirements.
: Use a shovel to put the material into a convenient waste disposal container.

Section 7. Handling and Storage
: Keep container closed. Use with adequate ventilation.
: Keep container tightly closed. Keep container in a cool, well-ventilated area.

Handling
Storage

Section 8. Exposure Controls, Personal Protection
Engineering Controls
Personal Protection
Eyes
Body
Respiratory
Hands
Feet
Protective Clothing
(Pictograms)

: Keep in a cool, well-ventilated place.
:
:
:
:
:

Safety glasses.
Chemical resistant protective suit.
Vapor respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Boots.

:

Continued on Next Page

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ExpertSeal Asphalt Repair
ExpertSeal Pot Hole Patch
Personal Protection in Case
of a Large Spill

: Splash goggles. Full suit. Boots. Gloves. Vapor respirator. A self-contained breathing apparatus
should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient;
consult a specialist before handling this product.

Exposure Limits
Liquid Petroleum Asphalt

ACGIH TLV (Canada, 2001). : TWA: 0.5 mg/m3 8 hour(s). Form: Fume

Consult local authorities for acceptable exposure limits.

Section 9. Physical and Chemical Properties
Physical State and
Appearance
Color
Odor
Molecular Weight
Molecular Formula
pH (1% Soln/Water)
Boiling/Condensation Point
Melting/Freezing Point
Specific Gravity
Vapor Pressure
Vapor Density
Volatility
Odor Threshold
Evaporation Rate
VOC
Viscosity
LogKow
Solubility

: Solid. (Granular solid.)
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:

Black.
Petroleum.
Not applicable.
Not applicable.
Not applicable.
295 to 705°C (563 to 1301°F)
Not available.
2.6 to 2.8 (Water = 1)
Not available.
Not available.
1% (v/v).
Not available.
Not available.
1 (%)
Not available.
Not available.
Insoluble in cold water, hot water.

Section 10. Stability and Reactivity
Stability and Reactivity
Conditions of Instability
Incompatibility with
Various Substances
Hazardous Decomposition
Products
Hazardous Polymerization

: The product is stable.
: None known.
: Reactive with oxidizing agents, acids.
: Not available.
: Will not occur.

Section 11. Toxicological Information
Fuels, diesel

LD50

7500 mg/kg

Oral

Rat

: CARCINOGENIC EFFECTS: Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.
: Hazardous in case of inhalation (lung irritant).
Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion.
Non-sensitizer for skin.
Special Remarks on Toxicity : Not available.
to Animals
Special Remarks on Chronic : This product contains substances that may be hazardous to human health, but the risk of exposure to
Effects on Humans
such substances is found to be negligeable, in the normal conditions of use.
Chronic Effects on Humans
Other Toxic Effects on
Humans

Continued on Next Page

Page: 4/5

ExpertSeal Asphalt Repair
ExpertSeal Pot Hole Patch

Section 12. Ecological Information
BOD and COD
Biodegradable/OECD
Mobility
Products of Degradation
Toxicity of the Products of
Biodegradation
Special Remarks on the
Products of Biodegradation

:
:
:
:
:

Not available.
Not available.
Not available.
These products are carbon oxides (CO, CO2). Some metallic oxides.
Not available.

: Not available.

Section 13. Disposal Considerations
Waste Information

: Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Consult your local or regional authorities.

Section 14. Transport Information
Regulatory Information

UN number

Proper shipping name

Class

Packing
Group

Canada (TDG)

Not
regulated.

Not controlled under TDG.

-

-

NAERG

Label

Additional
information
-

: Not applicable.

Section 15. Regulatory Information
WHMIS (Canada)

: Not controlled under WHMIS (Canada).
CEPA DSL: Liquid Petroleum Asphalt; Fuels, diesel
CEPA NDSL: Limestone
This product is a manufactured product under the Canadian WHMIS. Therefore it is EXEMPTED
from the regulatory requirements under WHMIS. This MSDS has been written for workers using
this product.

Section 16. Other Information
Hazardous Material
Information System
(U.S.A.)

Health
Fire Hazard
Reactivity
Personal Protection

References

Responsible Name
Date of Previous Issue
Version
Notice to Reader

1
1
0
C

National Fire
Protection
Association
(U.S.A.)

1
Health

1

Fire Hazard

0

Reactivity
Specific Hazard

: -Canada Gazette Part II, Vol. 122, No. 2 Registration SOR/88-64 31 December, 1987 Hazardous
Products Act "Ingredient Disclosure List". - Canadian Transport of Dangerous Goods, Regulations and
Schedules, Clear Language version 2002. -Manufacturer's Material Safety Data Sheet.
: Kemika XXI inc. +1-450-435-7475
: No Previous Validation.
: 1

Continued on Next Page

ExpertSeal Asphalt Repair
ExpertSeal Pot Hole Patch

Page: 5/5

To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its
subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should
be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Home > Products > MSDS Sheets > MSDS 3503 -- [Back]
WELCOME -Please Login

Last Updated: 10/25/2003
Local Time, Green Bay, WI 9:22:01 AM CST

3503: GUTTER & LAP SEALANT
MSDS Last updated: 03/29/1999
MSDS SHEET FOR DAP GUTTER & LAP SEALANT #3503
*** SECTION 1 PRODUCT IDENTIFICATION ***
MANUFACTURER'S NAME:
MANUFACTURER'S ADDRESS:
EMERGENCY TELEPHONE:

DISTRIBUTOR'S NAME:
DISTRIBUTOR'S ADDRESS:

DAP INC.
P.O. BOX 277
DAYTON, OH 45401-0277
1-800-535-5053 (TRANSPORTATION)
1-800-327-3874 (MEDICAL)

INFORMATION TELEPHONE:

IMPERIAL SUPPLIES LLC
789 PACKER DRIVE
GREEN BAY, WI 54304
1-800-558-2808

PRODUCT NAME:
PRODUCT NO.:
IMPERIAL NO.:

DAP GUTTER & LAP SEALANT WH
18182
3503

*** SECTION 2 HAZARDOUS INGREDIENTS ***
ITEM

CHEMICAL NAME

CAS #

01

MINERAL SPIRITS

ITEM

EXPOSURE LIMITS
ACGIH
OSHA
TLV-TWA
TLV-STEL
PEL-TWA
PEL-CEILING

01

100PPM

N.E.

8052-41-3

%

100 PPM

10-15

COMPANY
TLV-TWA

N.E.

N.E.

SKIN
NO

*** SECTION 3 HAZARDS IDENTIFICATION ***
EMERGENCY OVERVIEW: DANGER! COMBUSTIBLE LIQUID AND VAPOR.
HARMFUL OR FATAL IF SWALLOWED. HARMFUL IF INHALED.

VAPOR HARMFUL.

POTENTIAL HEALTH EFFECTS:
EFFECTS OF OVEREXPOSURE: EYE CONTACT: MAY CAUSE EYE IRRITATION.
EFFECTS OF OVEREXPOSURE: SKIN CONTACT: MAY CAUSE SKIN IRRITATION. MAY
IRRITATE SKIN. PROLONGED OR REPEATED CONTACT CAN RESULT IN DEFATTING AND DRYING
OF THE SKIN WHICH MAY RESULT IN SKIN IRRITATION AND DERMATITIS (RASH).
EFFECTS OF OVEREXPOSURE: INHALATION: VAPOR HARMFUL IF INHALED. VAPOR MAY
IRRITATE NOSE AND UPPER RESPIRATORY TRACT. VAPOR INHALATION MAY AFFECT THE
BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE, OR NAUSEA.
EFFECTS OF OVEREXPOSURE: INGESTION: THIS MATERIAL MAY BE HARMFUL OR FATAL IF
SWALLOWED. IF INGESTED, THIS PRODUCT MAY CAUSE VOMITING, DIARRHEA, AND
DEPRESSED RESPIRATION.
EFFECTS OF OVEREXPOSURE: CHRONIC HAZARDS: REPORTS HAVE ASSOCIATED PERMANENT
BRAIN AND NERVOUS SYSTEM DAMAGE WITH PROLONGED AND REPEATED OCCUPATIONAL
OVEREXPOSURE TO SOLVENTS.
MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY CONTACT:
PRIMARY ROUTES OF ENTRY:

SKIN CONTACT AND INHALATION

NONE KNOWN.

*** SECTION 4 FIRST AID MEASURES ***
EYE CONTACT: FLUSH WITH LARGE QUANTITIES OF WATER UNTIL IRRITATION SUBSIDES.
SKIN CONTACT: WASH WITH SOAP AND WATER.
INHALATION: REMOVE TO FRESH AIR.
INGESTION: DO NOT INDUCE VOMITING.
COMMENTS: CALL MEDICAL IN SECTION 1 IF IRRITATION OR COMPLICATIONS ARISE FROM
ANY OF THE ABOVE ROUTES OF ENTRY.
*** SECTION 5 FIRE FIGHTING MEASURES ***
FLASH POINT: 120 F
SETAFLASH CLOSED CUP
LEL: N.A.
UEL: N.A.
AUTOIGNITION TEMPERATURE: N.A.
EXTINGUISHING MEDIA: CO2, DRY CHEMICAL, FOAM,
UNUSUAL FIRE AND EXPLOSION HAZARDS: CONTAINERS MAY EXPLODE IF EXPOSED TO
EXTREME HEAT. ELIMINATE SOURCES OF IGNITION: HEAT, ELECTRICAL EQUIPMENT,
SPARKS, AND FLAMES. DO NOT PUT IN CONTACT WITH OXIDIZING OR CAUSTIC MATERIALS.
SPECIAL FIREFIGHTING PROCEDURES: AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING
APPARATUS PRESSURE-DEMAND (MSHA/NIOSH APPROVED OR EQUIVALENT) AND
FULL PROTECTIVE GEAR TO PROTECT FROM COMBUSTION PRODUCTS. USE WATER
SPRAY TO COOL EXPOSED SURFACES.
*** SECTION 6 ACCIDENTAL RELEASE MEASURES ***
SPILL OR LEAK PROCEDURES:

DIKE SPILL AREA. USE ABSORBENT MATERIAL OR SCRAPE UP
DRIED MATERIAL AND PLACE INTO CONTAINERS.

*** SECTION 7 HANDLING & STORAGE ***
HANDLING INFORMATION:

KEEP OUT OF REACH OF CHILDREN. AVOID PROLONGED OR
REPEATED CONTACT WITH SKIN. AVOID CONTACT WITH EYES.
AVOID BREATHING VAPORS. USE ONLY IN A WELL VENTILATED
AREA.
STORAGE INFORMATION: STORE AWAY FROM CASUTICS AND OXIDIZERS. KEEP AWAY
FROM HEAT, SPARK, AND FLAME. KEEP CONTAINERS
TIGHTLY CLOSED WHEN NOT IN USE. KEEP CONTAINERS FROM
EXCESSIVE HEAT AND FREEZING. DO NOT STORE AT TEMPERATURES
ABOVE 120 DEGREES F.
OTHER PRECAUTIONS: INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND
INHALING VAPORS MAY BE HARMFUL OR FATAL. DO NOT TAKE
INTERNALLY.
*** SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION ***
ENGINEERING CONTROLS: PROVIDE SUFFICIENT MECHANICAL VENTILATION (LOCAL OR
GENERAL EXHAUST) TO MAINTAIN EXPOSURE BELOW PEL AND TLV.
VAPORS ARE HEAVIER THAN AIR AND WILL COLLECT IN LOW
AREAS. CHECK ALL LOW AREAS (BASEMENTS, SUMPS, ETC.) FOR
VAPOR BEFORE ENTERING.
RESPIRATORY PROTECTION: A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA
1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED
WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S
USE. IF 8 HOUR EXPOSURE LIMIT OR VALUE IS EXCEEDED
FOR ANY COMPONENT, USE AN APPROVEDNIOSH RESPIRATOR.
CONSULT YOU SAFETY EQUIPMENT SUPPLIER AND THE OSHA
REGULATION, 29 CFR 1910.134 FOR RESPIRATOR
REQUIREMENTS.
EYE PROTECTION: GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS RECOMMENDED.
SKIN PROTECTION: SOLVENT IMPERVIOUS GLOVES.
OTHER PROTECTIVE EQUIPMENT: PROVIDE EYEWASH AND SOLVENT IMPERVIOUS APRON IF
BODY CONTACT MAY OCCUR.
HYGIENIC PRACTICES: REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE.

*** SECTION 9 PHYSICAL & CHEMICAL PROPERTIES ***
BOILING RANGE: 310-320 F
ODOR: PETROLEUM ODOR
APPEARANCE: COLORED PASTE
SOLUBILITY IN H20: NEGLIGIBLE
SPECIFIC GRAVITY: 1.4511
VAPOR PRESSURE: 2.0 MM HG @ 68 F
PHYSICAL STATE: PASTE
VAPOR DENSITY: IS HEAVIER THAN AIR
EVAPORATION RATE: IS SLOWER THAN BUTYL ACETATE
*** SECTION 10 STABILITY & REACTIVITY ***
CONDITIONS TO AVOID: EXCESSIVE HEAT AND FREEZING.
INCOMPATIBILITY: STRONG OXIDIZERS AND CAUSTICS.
HAZARDOUS DECOMPOSITION PRODUCTS: NORMAL DECOMPOSITION PRODUCTS, I.E. COx, NOx
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
*** SECTION 11 TOXICOLOGICAL PROPERTIES ***
NO PRODUCT OR COMPONENT TOXICOLOGICAL INFORMATION IS AVAILABLE.
*** SECTION 12 ECOLOGICAL INFORMATION ***
NO INFORMATION
*** SECTION 13 DISPOSAL CONSIDERATIONS ***
WASTE MANAGEMENT/DISPOSAL: DISPOSE OF ACCORDING TO FEDERAL, STATE, AND LOCAL
STANDARDS. THIS PRODUCT DOES NOT MEET THE DEFINITION OF A HAZARDOUS WASTE
ACCORDING TO U.S. EPA HAZARDOUS WASTE MANAGEMENT REGULATIONS, 40 CFR SECTION
261. STATE AND LOCAL REGULATIONS/RESTRICTIONS ARE COMPLESX AND MAY DIFFER
FROM FEDERAL REGULATIONS. RESPONSIBILITY FOR PROPER WASTE DISPOSAL IS WITH
THE OWNER OF THE WASTE.
EPA WASTE CODE:

IF DISCARDED (40 CFR 261):

D001-IGNITABLE

*** SECTION 14 TRANSPORTATION INFORMATION ***
DOT PROPER SHIPPING NAME:
DOT HAZARD CLASS: NONE
DOT UN/NA NUMBER: NONE
PACKING GROUP: NONE

NOT REGULATED BY D.0.T.

*** SECTION 15 REGULATORY INFORMATION ***
U.S. FEDERAL REGULATIONS:

AS FOLLOWS -

OSHA: HAZARDOUS BY DEFINITION OF HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200)
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
NONE.
TOXIC SUBSTANCES CONTROL ACT:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
NONE.
NEW JERSEY RIGHT-TO-KNOW:

THE FOLLOWING MATERIALS ARE NON-HAZARDOUS, BUT ARE AMONG THE TOP FIVE COMPONENTS
IN THIS PRODUCT:
BUTYL RUBBER, SOYBEAN OIL, POLYMER, CALCIUM CARBONATE
PENNSYLVANIA RIGHT-TO-KNOW:
THE FOLLOWING NON-HAZARDOUS INGREDIENTS ARE PRESENT IN THE PRODUCT AT GREATER
THAN 3%:
BUTYL RUBBER, CALCIUM CARBONATE
CALIFORNIA PROPOSITION 65:
WARNING: THE CHEMCICAL NOTED BELOW AND CONTAINED IN THIS PRODUCT, ARE KNOWN TO
THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE
HARM:
NONE.
INTERNATIONAL REGULATIONS:

AS FOLLOWS -

CANADIAN WHMIS: THIS MSDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED
PRODUCT REGULATIONS EXCEPT FOR USE OF THE 16 HEADINGS.
CANADIAN WHMIS CLASS:

B3 COMBUSTIBLE LIQUID.

SOLD ON RETAIL MARKET.

*** SECTION 16 OTHER INFORMATION ***
HMIS RATINGS - HEALTH: 1
FLAMMABILITY: 2
REACTIVITY:
VOC LESS WATER, LESS EXEMPT SOLVENTS: 175-185 GMS/1(12-13%)
VOC MATERIAL: 175-185 GM/1

0

The information contained in this MSDS was obtained from current and reliable sources, however, the data is
provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions
or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will
not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed
or inferred, regarding the product described in this MSDS shall be created or inferred by any statement in this
MSDS. Various government agencies may have specific regulations regarding the transportation, handling,
storage, use, or disposal of this product which may not be covered by this MSDS. The user is responsible for full
compliance.

For more product information by email, click here
.
Imperial Supplies LLC does not provide services and products outside the United
States
Home | Site Search | Company Info | Catalog | New Products | Programs
Your Account | Career Opportunities | Info Request | Downloads | Privacy Policy | Links | Site Map
Copyright © Imperial, 2001
Questions or comments on these pages? Contact us.

Spartan Chemical Company, Inc.
Material Safety Data Sheet
SECTION I: PRODUCT INFORMATION
Product Name or Number (as it appears on label):

Product Division:
Janitorial

CONCRETE SEAL
Product Number: 2977
Spartan Chemical Company,
Inc.
1110 Spartan Drive

Product/Technical
1-(800)-537-8990
Information:
Medical Emergency: 1-(888)-314-6171 (24 hours)
Chemical Leak/Spil CHEMTREC 1-(800) 424-9300 (24
Emergency: hours)

Maumee OH 43537

Shipping Description: Buffing, polishing compounds, liquid, n.o.s.
NFPA Ratings:

HMIS Ratings:
Health: *2 - Moderate; Chronic
Hazard

Health: 2 - Moderate

Fire: 2 - Moderate

Fire: 2 - Moderate

Reactivity: 0 - Minimal

Reactivity: 0 - Minimal

Pers. Prot. Equip.: See Section VIII

SECTION II: HAZARDOUS INGREDIENTS
(Listed when present at 1% or greater, carcinogens at 0.1% or greater) All component chemicals are listed
or exempted from listing on the "TSCA Inventory" of chemical substances maintained by the U.S.
Environmental Protection Agency.
Table Z- 1 - A
Chemical Name(s)

CAS
% W Registry No.

*1,2,4Trimethylbenzene

25-30

Acrylic polymer

15-20

95-63-6

STEL mg/m

NTP, IARC
or OSHA
Carcinogen

TWA mg/m3

3

CELING
mg/m3

125

Not
Established

Not
Established

No

Not
Established

Not
Established

No

Proprietary Not Established

*Xylene

1-5

1330-20-7

435

655

Not
Established

No

Cumene

1-5

98-82-8

245

Not
Established

Not
Established

No

100
(ExxonMobile)

Not
Established

Not
Established

No

Aromatic hydrocarbon

45-55 64742-95-6

Comment: *This substance is subject to the reporting requirements of Section 313 of the Emergency
Planning and Community Right-To-Know Act of 1986 (SARA) and of 40 CFR 372.
SECTION III: PHYSICAL DATA
Boiling Point: 311 °F

Vapor Pressure: 2.7 mm Hg @ 20°F

Vapor Density (AIR = 1): >1
pH: N/A
Evaporation Rate 0.19
(but.ace.=1):

Solubility in Water: Nil
Specific Gravity 0.90
(H2O=1):
Percent Solid by 15-20
Weight:

Physical State: Liquid
Appearance & Odor: Water clear, slightly viscous, aromatic

SECTION IV: FIRE & EXPLOSIVE HAZARD DATA
Flash Point: 107°F
Flammable Limits: LEL - 1.0 UEL - 6.5

Method Used: ASTM-D56
Flame Extension: N/A

Extinguishing Media: Small Fires: extinguish with dry chemical, CO2, or foam. Large Fires: The
use of dry chemical or foam is recommended. Water may be an ineffective
extinguishing agent.
Special Fire Fighting The use of a SCBA is recommended for fire fighters. Water may be useful in
Procedures: minimizing vapors and cooling containers exposed to heat and flame. Avoid
spreading burning liquid with water used for cooling purposes.
Unusual Fire & Explosive This material is combustible and may be ignited by heat or flame. This
Hazards: material will burn, but not ignite readily.
SECTION V: HEALTH HAZARD DATA
Threshold Limit Value: Not established

Primary Routes of Inhalation, Skin Contact,
Entry: Eyes

Effects of Overexposure- Causes Eye irritation: Direct contact with the liquid or exposure to its
Conditions to Avoid: vapors or mists may cause burning, tearing, redness and swelling.
May Cause Skin Irritation: Prolonged or repeated exposure to this material
may cause redness and burning, drying and cracking of the skin. Persons
with pre-existing skin disorders may be more susceptible to the effects of this
material.
Inhalation: Breathing high concentrations of vapors or mists may cause
irritation of the nose and throat, signs of nervous system depression (e.g.,
drowsiness, dizziness, loss of coordination, and fatigue). Prolonged or
repeated exposure to vapors or mists may cause liver and kidney damage.
Persons with impaired lung function or asthma-like conditions may
experience additional breathing difficulties due to the irritant properties of
this material.
Harmful if Swallowed: Ingestion may cause irritation of the digestive tract
and signs of nervous system depression (e.g. drowsiness, dizziness, loss of
coordination, and fatigue).
Aspiration hazard - this material can enter lungs during swallowing or
vomiting and cause lung inflammation and damage.
Conditions Aggravated by Use of this product may aggravate preexisting skin; eye and respiratory
Use: disorders including asthma and dermatitis.
Emergency & First Aid Procedures:
Eyes: Move victim away from exposure to vapors and into fresh air. Remove
contact lenses. If irritation or redness develops; seek medical attention. For
direct contact; flush the affected eye(s) with clean water for at least 15
minutes. Seek medical attention.
Skin: Removed contaminated clothing. Cleanse affected area(s) thoroughly by
washing with mild soap and water. If irritation or redness develops and
persists; seek medical attention.
Ingestion: Call physician immediately. Do not induce vomiting. Keep person at rest.
Small amounts of this product aspirated into the respiratory system during

ingestion or vomiting may cause mild to severe pulmonary injury.
Inhalation: If symptoms of exposure develop; move victim away from source of
exposure and into fresh air. If symptoms persist; seek immediate medical
attention. If victim is not breathing; artificial respiration should be
administered. If breathing difficulties develop; oxygen should be
administered by qualified personnel.

SECTION VI: REACTIVITY DATA
Stability: Stable

Incompatible Materials: This product is
incompatible with strong
acids or bases; oxidizing
agents and selected
amines.

Hazardous Decomposition CO, CO2
Products:

Hazardous Will Not Occur
Polymerization:

SECTION VII: SPILL OR LEAK PROCEDURES
Steps to be Taken in Case Pick up with absorbent material and dispose of in accordance with state and
Material is Released or local regulations.
Spilled:
Waste Disposal Method: Use qualified disposal service.

SECTION VIII: SPECIAL PROTECTION INFORMATION
Respiratory Protection: The use of respiratory protection is advised when concentrations exceed the
established exposure limits (see Section II), additional ventilation or exhaust
systems may be required. Where explosive mixtures may be present,
systems safe for such locations should be used.
Ventilation: Good general ventilation should be sufficient for most conditions. Local
exhaust ventilation may be necessary for some operations.
Protective Gloves(Specify Wear neoprene, nitrile or other solvent resistant gloves.
Type):
Eye Protection(Specify Splash Goggles
Type):
Other Protective Equipment: Use of other protective equipment such as an impermeable apron should be
considered in order to prevent or minimize contact with this product. See 29
CFR 1910.132-138 for further guidance.

SECTION IX: SPECIAL PRECAUTIONS
Precautions; Handling & Keep containers tightly closed. Keep containers cool; dry and away from
Storing: sources of ignition. Use and store this product with adequate ventilation.
Avoid inhalation of vapors and personal contact with the product. Use good
personal hygiene practice. "Empty" containers retain residue (liquid and/or
vapor) and can be dangerous. Do not pressurize; cut; weld; braze; solder;
drill; grind or expose such containers to heat; flame; sparks or other sources
of ignition; they may explode and cause injury or death. "Empty" drums
should be completely drained; properly bunged and promptly shipped to the
supplier or a drum reconditioner. All other containers should be disposed on
in an environmentally safe manner and in accordance with governmental
regulations. Before working on or in tanks which contain or have contained
this product; refer to Occupational Safety and Health Administration
regulations; ANSI Z49.1; and other governmental and industrial references
pertaining to cleaning; repairing; welding or other contemplated operations.
Other Precautions: During use; eliminate any source of ignition. Remove all foodstuffs and
packaging materials from area to be coated.
© SCC 12/14/2005

Name:

Ronald T. Cook

CONCRETE SEAL

Effective
Date:
Changes:

12/14/2005

Title:

Manager, Regulatory
Affairs
Supercedes: 01/05/2000

Ref: 29 CFR 1910.1200
Update Sections I, II, V, VIII
(OSHA)
This document has been prepared using data from sources considered technically reliable. It does not
constitute a warranty, express or implied, as to the accuracy of the information contained herein. Actual
conditions of use and handling are beyond sellers control. User is responsible to evaluate all available
information when using product for any particular use and to comply with all Federal, State and Local laws
and regulations.

'ttL}

MATERIALSAFETYDATASHEET
PortlandCement
SECTION1 . ]DENTIFICATION
Pt9.d!.ct_Nane: Types l, l/lllA, l/ll, lllLA, Red Bag, White Portland
Manufacturer'sName and Address: ALAMO CEMENTCOMPANY
P.O. Box 34807
San Antonio, Texas 78265
TelephoneNumbers: In Texas: 1(800)292-5510 - Other: 1(210)208-1880
Chemical Name and Synonyms: Portland Cement.Portland Cement is also know as hydraulic cement.
PreparationDate: July 9, 2007. Replacesany prior versions.
CneEic3l-Fjtrily: Calcium compounds. Calcium silicate compounds and other calcium compounds
containing iron and aluminum make up the majority of this product,
Maior Compounds: 3CaO-Si02
2CaO-SiO2

TricalciumSilicate
DicalciumSilicate
3CaO-AlzOr TricalciumAluminate
4CaO-A12O3-Fe2O3 TetracalciumAluminoferrite
CaSOr-2HzO CalciumSulfateDihydrateor Gypsum
CaCO3
CalciumCarbonateor Limestone

EAIOUA: This productconsistsof finely ground Portlandcementclinkermixedwith a small amountof
calciumsulfatedihydrate(Gypsum).

SECTION
2 - COMPONENTS
HazardousInoredients:Portlandcementclinker(CAS#65997-5-1)apploximately95%by weight
ACGIHTLV-TWA(1995-1996)=10m9
total dusum'
OSHAPEL(8-hourTWA)=50millionparticles/ft3
- approximately
Gypsum(CAS#7778-18-9)
5% !y weight
ACGIHTLV-TWA(1995-1996)=10m9
total dusum'
OSHAPEL(8-hourTWA)=1Omg
totll dusUm3
OSHAPEL(8-hourTWA)=Smg
respirabledusUm3

Quartz(CAS#14808-60-7)-less
than 0.1%by weightor volumeACGIHTLV-TWA(1995-1996)=0.10m9
respirablequartzdusUm"
OSHAPEL(8-hourTWA)=(10m9
of respirabledusum')/(Percent
silica+ 2)
NIOSHREL(8-hourTWA)=O.05mg
respirablequartzdusUm"
Trace Constituents: Portlandcementis made from materialsmined from the earth and is processed
using energy provided by fossil fuels. Trace amounts of naturally occurring, potentiallyharmful
chemicalsmight be detectedduringchemicalanalysis.For example,Portlandcementmay containup to
2.0% insoluableresidue,some of which may be free crystallinesilica. Other trace constituentsmay
include calciumoxide (also known as free lime or quick lime),free magnesiumoxide, potassiumand
sodiumsulfatecompounds,chromiumcompounds,and nickelcompounds,

SECTION3 - HAZARDSIDENTIFICATION
EmergencyOverview:PortlandCementis a light gray powderthat poseslittleimmediatehazard.A single
short term exposureto the dry powder is not likely to cause serious harm. However,exposureof
sufficientdurationto wet Portlandcementcan causeserious,potentiallyirreversibletissue (skinor eye)
destructionin the form ot chemical(caustic)burns,includingthird degreeburns.The sametype of tissue
destructioncan occur if wet or moistareasofthe bodyareexposedfor sufficientdurationto dry Portland
Cement.

Pgle$bl-HeallLEfferlt:
RelevantRoutesof Exposure:EyeContact,skin contact,inhalation,and ingestion.
@:Exposuretoairbornedustmaycauseimmediateorde|ayedirritation
or inflammation.
Eye contact by largeramountsof dry powderor splashesof wet Portlandcementmay cause etfects
rangingfrom moderateeye irritationto chemicalburnsand blindness.Suchexposuresrequireimmediate
first aid (seesection4) and medicalattentionto preventsignificantdamageto the eye.
@:Discomfortorpaincannotbere|iedupontoa|ertapersontoa
hazardousskin exposure.Consequently,the only effectivemeans of avoiding skin injury or illness
involvesminimizingskin contact,particularlycontactwith wet cement.Exposedpersonsmay not feel
discomfortuntil ours afterthe exposurehas endedand significantinjuryhas occurred.
Exposureto dry Portlandcementmay causedrying of the skin with consequentmild irritationor more
significanteffectsattributableto aggravationor other conditions,Dry Portlandcementcontactingwet
skin or exposureto moist or wet Portlandcement may cause more severe skin effects including
thickening,cracking,fissuringof the skin. Prolongedexposurecan causesevereskin bdamagein the
form of (caustic)chemicalburns.
Some individualsmay exhibitan allergicresponseupon exposureto Portlandcement,possiblydue to
trace amountsot chromium.The responsemay appearin a varietyof forms rangingfrom a mild rashto
severeskin ulcers.Personsalreadysensitizedmay react to their first contactwith the product.Other
personsmayfirst experience
this effectafteryearsof contactwith Portlandcementproducts.
Portland cement may contain trace amounts of free crystalline silica.
EtfeglllllliliDCja0-hhalAtiQ!:
respirable
free
crystallinesilica may aggravateother lung conditions.lt also may
Prolongedexposureto
cause delayed injury including silicosis, a disabling and potentiallyfatal lung disease. (Also see
potential"below).
"Carcinogenic

Exposureto Portlandcementmay causeirritationto the moist mucousmembranesof the nose,throat,
and upperrespiratorysystem.lt may also leaveunpleasantdepositsin the nose.
Eftectr.IeilfilCl[I9m-inCa$iC!: Although small quantitiesof dust are not known to be harmful,ill effects
are possibleif largerquantitiesareconsumed.Portlandcementshouldnot be eaten.
C3lgingCanic.-Aeleltial:Portland cement is not listed as a carcinogen by NTP, OSHA,or IARC. lt may
however,containtraceamountsof substanceslistedas carcinogensby theseorganizations.
Crystallinesilica,a potentialtrace levelcontaminantin Portlandcement,is now classifiedby IARCas a
respirablesilica as "reasonablyanticipated
known humancarcinogen(Group1). NTPhas characterized
to be a carcinogen".
Medicalconditionswhich mav be aooravatedbv inhalationor dermal exposure: Pre-existingupper
respiratoryand lung diseases.
salts.
chromium(chromium*6)
Unusual(hyper)sensitivityto hexavalent

SECTION4-FIRSTAID

EygS: lmmediatelyflush eyes thoroughlywith water. Continueflushing eye for at least 15 minutes,
includingunderlids,to removeall particles.Callphysicianimmediately.
Sf,itr: Washskin with cool water and pH-neutralsoap or a mild detergent.Seekmedicaltreatmentin all
cases of prolongedexposureto wet cement,cementmixtures,liquidsfrom fresh cementproducts'or
prolongedwet skin exposureto dry cement.
Removeto fresh air. Seek medicalhelp if coughing and other symptoms do
hhalatiq!-el@l$t:
("lnhalation"
gross
amountsof Portlandcementrequireimmediatemedicalattention.)
of
not subside.
bgeEtieo: Do not inducevomiting.lf conscious,havethe victimdrink plentyofwater and call a physician
immediately.

DATA
SECTION5 - FIRE& EXPLOSION
F l a s hp o i n t . . . . . . . . . . . . . . . . . . . n o n e
Limit.,,..............none
LowerExplosive
Limit.................none
UpperExplosive
combustible
Autoignitiontemperature.............,not
not combustible
media.,...................
Extinguishing
Specialfirefightingprocedures...............none
(AlthoughPortlandcementposesno fire relatedhazards,a self containedbreathingapparatusis
to limitexposureto combustionproductswhenfightingany fire.)
recommended
products..............none
Hazardous
combustion
Unusualfireandexplosionhazards.............none

SECTION6 _ ACCIDENTAL
RELEASEMEASURES

Collectdry materialusinga scoop.Avoid actionsthat causedust to becomeairborne.Avoid inhalationof
dust and contactwith skin.Wearappropriatepersonalprotectiveequipmentas describedin Section8.
Scrapeup wet materialand placein appropriatecontainer.Allow the materialto dry beforedisposal.Do
not attemptto wash Portlandcementdown drains,
Disposeof wastematerialaccordingto local,state,and federalregulations.

SECTION7 - HANDLING
AND STORAGE

KeepPortlandcementdry until used.Normaltemperatures
and pressuresdo not affectthe material
Promptlyremovedusty clothingor clothingwhich is wet with cementfluidsand launderbeforereuse.
Washthoroughlyafterexposureto dust or wet cementmixturesor fluids.

PROTECTION
SECTION8 - EXPOSURE
CONTROLS/PERSONAL

Ski[PIOleCliA!: Preventionis essentialto avoiding potentiallysevereskin injury. Avoid contactwith
unhardenedPortlandcement.lf contactoccurs,promptlywashaffectedareawith soapand water.Where
prolongedexposureto unhardenedPortlandcementproductsmightoccur,wear imperviousclothingand
glovesto eliminateskin contact.Whererequired,wearsturdybootsthat are imperviousto waterto
eliminatefoot and ankleexposure.
Do not relyon barriercreams:Barriercreamsshouldnot be usedin placeof gloves.
Periodically
washareascontactedby dry Portlandcementor by wet cementor concretefluidswith a pH
neutralsoap.Washagainat the end of the work. lf irritationoccurs,immediately
wash the affectedarea
and seektreatment.lf clothingbecomessaturatedwith wet concrete,it shouldbe removedand replaced
with cleandry clothing.
RespiratorvProtection:Avoidactionsthat causedust to becomeairborne.Uselocalor general
ventilationto controlexposuresbelowapplicableexposurelimits.
(under30 CFR11) or N|OSH-approved
(under42 CFR84)respiratorsin
UseNIOSHAJMSHA-approved
poorlyventilatedareas,if an applicableexposureIimit is exceeded,or when dust causesdiscomfortor
irritation.(Advisory:Respiratorsand filterspurchasedafterJuly 10,1998must be certifiedunder42 CFR
84).
Venlilalig!: Uselocalexhaustor generaldilutionventilationto controlexposurewithinapplicablelimits.
Eyeggteglig!: Wherepotentiallysubject to splashesor puffs of cement,wear safety glasseswith side
and unpredictable
environments,
wearunventedor
shieldsor goggles.In extremelydusty environments
indirectlyventedgogglesto avoideye irritationor injury.Contactlensesshouldnot be worn when
workingwith Po(land cementor fresh cementproducts.

SECTION9 - PHYS]CALAND CHEMICALPROPERTIES
Appearance....,...,.Gray
Powder
Odor.....................No
distinctodor
(powder)
Physical
state........Solid
pH (inwater)..........12
to 13
Solubilityin water..Slightly
soluble(0.1to 1.0%)
Vaporpressure......Not
applicable
Vapordensity.........Not
applicable
Boilingpoint..........Not
applicable
MeltingPoint..........Not
applicable
Specificgravity(HrO=1.0)
3.15
Evaporationrate.....Not
Applicable

SECTION1O- STABILITYAND REACTIVITY
$lahilily: Stable
Conditionsto Avoid: Unintentional
contactwith water.
with acids,ammoniumsalts
lncqEpatihility:Wet Portlandcementis alkaline.As such it is incompatible
and phosphorous.
Hazardousdecomnosition:Will not spontaneously
occur.Addingwaterproduces(caustic)calcium
hydroxide.
Hazardousoolvmerization:Will not occur,

SECTION11 - TOXILOGICAL
INFORMATION
For a description of available,more detailedtoxicological information, contact the supplier or
manufacturer.

12- ECOLOGICAL
INFORMATION
SECTION
Ecoloricily: No recognizedunusualtoxicityto plantsor animals.
Relevantnhvsicaland chemicalproperties:SeeSections9 and 10

sEciloN 13- DTSPOSAL
Disposeof wastematerialaccordingto local,stateand federalregulations,(SincePortlandcementis
table,uncontaminated
materialmay be savedor futureuse.)
Disposeof bagsin an approvedlandfillor incinerator.

SECTION14- TRANSPORTATION
DATA
@ip!ilC-0g0e:
(DOT)regulations.
Department
of Transportation

Portlandcementis not hazardousunderU.S.

HaZard-chss:NotApplicable
ldentificaiion Number: Not Applicable

BecsledlabgIerl: NotApplicable
Hazardoussubstances/renortableouantities (RQl - Not applicable

INFORMATION
SECTION15 - OTHERREGULATORY
HazardCommunication
Rule.29 CFR1910.'1200:Portlandcementis
StatusLjnderIJSDOL-OSHA
considereda "hazardouschemical"underthis regulationand shouldbe part of any hazard
program.
communication
(total)TWA 5MG/M3
(RESPI.
StatusunderMSHACFR30 Part47: NIOSHREL:TWA10mg/m3
: Not listed
: Portlandcementqualifiesas a "hazardous
substance"with delayedhealtheffects.
StatusunderSARA(Titlelll).Section3'l3: Not subjectto reportingrequirements
undersection313.
@):somesubstancesinPort|andcementareontheTScAinventory
list.
Statusunderthe FederalHazardousSubstancesAct: Portlandcementis "a hazardoussubstance"
subjectto statutespromulgatedunderthe subjectact.
@:Thisproductcontainschemica|s(tracemeta|s)knowntothe
Stateof Californiato causecancer,birth defectsor otherreproductiveharm.Californialaw requiresthe
manufacturer
to givethe abovewarningin the absenceof definitivetestingto provethat the definedrisks
do not exist.
Status under CanadianEnvironmentalProtectionAct: Not listed.
Portland cement is considered to be a hazardous material under the Hazardous
SlaUfJldeLI{HM[i:
Products Act as defined by the Controlled Products Regulations(Class E - Corrosive Metal) and is
therefore subject to the labeling and MSDS requirementsof the Workplace HazardousMaterials
InformationSystem (WHMIS).

SECTION16 - OTHERINFORMATION
Beyidq!-dale: July 9, 2007

Ele-ef-preyiels-UjiDs:

December30, 2006

a$efJ0pqtantlOlC@aliC!: Portlandcementshould only be used by knowledgeablepersons.A key to
using the product safely requiresthe user to recognizethat Portlandcementchemicallyreactswith
water,and that some of the intermediateproductsof this reaction(that is, those presentwhile a Portland
cementproduct is "setting" pose a far more severehazardthan does Portlandcement itself,
While the informationprovidedin this materialsafetydata sheet is believedto provide a useful summary
of the hazardsof Portlandcementas it is commonlyused,the sheetcannotanticipateand provideall of
productusersshouldobtain
the intormationthat might be neededin everysituation.Inexperienced
proper training before using this product.
SELLERMAKESNOWARRANTY,EXPRESS
OR IMPLIED,
CONCERNING
THEPRODUCT
OR THE
MERCHANTABILITY
OR FITNESS
THEREOF
FORANY PURPOSE
OR CONCERNING
THEACCURACY
OF
ANY INFORMATION
PROVIDED
BY AlamoCementCo.,exceptthat the productshall performto
contractedspecification.The informationprovidedhereinwas believedby Alamo CementCo. to be
accurateat the time of preparationor preparedfrom the sources to believedto be reliable,but it is the
responsibilityof the user to investigateand understandother pertinentsources of informationto comply
with all lawsand proceduresapplicableto the safehandlingand useof productand to determinethe
suitabilityof the productfor its intendeduse.Buyer'sexclusiveremedyshall be for damagesand no
claimof any kind,whetheras to productdeliveredor for non-delivery
or product,and whetherbasedon
contract,breachof warranty , negligence,or otherwiseshall be greaterin amount than the purchaseprice
of the quantityof productin respectof whlchdamagesareclaimed.In no eventshallSellerbe liablefor
incidentalor consequentialdamages,whether Buyer's claim is basedon contract,breachof warranty,
negligenceor otherwise,
In particular,the datafurnishedin this do not addresshazardsthat may be posedby othermaterials
mixed with Portlandcementto produce Portlandcementproducts.Usersshould reviewother relevant
materialsafety data sheets beforeworking with this Portlandcementor working on Portlandcement
products,for example,Portlandcementconcrete.

Material
Safety
Data
Sheet

24 Hour Emergency Phone Numbers:
Medical: 1-800-327 -3874
1-513-558-5111
Transportation:
1-800-535-5053
1-352-323-3500

NOTE: National Response Center emergency numbers to be used only
in the event of chemical emergencies involving a spill, leak, fire,
exposure or accident involving chemicals.

IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of
this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16.

Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en espa ñol a su solicitud.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere .

Product Name:

DAP® Wallboard Joint Compound

Product UPC
Number:
Product
Use/Class:
Manufacturer:

070798300705 070798301207
RTU Spackle/Wallboard Repair

Revision
Date:
Supercedes:

04/27/2007

MSDS
Number:

00070288605

07/28/2003

DAP Canada Corporation
475 Finchdene Square Unit 5
Scarborough, Ontario M1X 1B7
888-327-8477 (non-emergency
matters)

Section 2 - Composition / Information On Ingredients
Chemical Name

CASRN

WT%

Calcium carbonate

1317-65-3

40-70

Mica
Magnesium aluminum silicate

12001-26-2
12174-11-7

1-5
1-5

Silica, crystalline

14808-60-7

0.1-1.0

Ethylene glycol

107-21-1

0.1-1.0

ACGIH TWA ACGIH STELACGIH CEIL OSHA TWA OSHA STEL OSHA CEIL
5 MGM3
10 MGM3
N.E.
N.E.
(respirable
N.E.
N.E.
fraction)
3 MGM3
N.E.
N.E.
5 MGM3
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
10/(%SiO2 +
0.05 MGM3
N.E.
N.E.
N.E.
N.E.
2) MGM3
N.E.
N.E.
100 MGM3
N.E.
N.E.
N.E.

Skin
No
No
No
No
No

Exposure Notes:

14808-60-7 The 2002 ACGIH Threshold Limit Values for Chemical Substances and Physical Agents lists the
median Respirable Particulate Mass (RPM) point for crystalline silica at 4.0 microns in terms of the particle's
aerodynamic diameter.
The TLVs for crystalline silica represent the respirable fraction.
OSHA PEL TWA for Quartz is calculated using the following formula: 10 mg/m3/(% SiO2 + 2). Both
concentration and percent quartz for the application of this limit are to be determined from the fraction passing a
size selector with the following characteristics.
|------------------------------------------------------------------------------------|-----------------------------------------|

| ....... Aerodynamic diameter ( unit density sphere ) .....| Percent passing selector |
| 2 ................................................................................|.................90....................|
| 2.5 .............................................................................|..................75...................|
| 3.5 .............................................................................|..................50...................|
| 5.0 .............................................................................|..................25...................|
| 10 ..............................................................................|...................0....................|
Important:

Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary
between states.

Note:

An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent
necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work
practices

Section 3 - Hazards Identification
Emergency Overview: A white to off-white paste product with a musty odor. CAUTION! This product contains ethylene
glycol.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: Direct eye contact may cause irritation.
Effects Of Overexposure - Skin Contact: May cause skin irritation. May cause dry skin.
Effects Of Overexposure - Inhalation: Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous
membranes). Inhalation of dust may cause lung damage or other adverse pulmonary and respiratory effects.
Effects Of Overexposure - Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.
Effects Of Overexposure - Chronic Hazards:
Ethylene Glycol may cause kidney and liver damage upon prolonged and repeated overexposures. Studies have shown
that repeated inhalation of ethylene glycol has produced adverse cardiovascular changes in laboratory animals. Ethylene
glycol has been shown to cause birth defects in laboratory animals.
The International Agency for Research on Cancer (IARC) has determined that crystalline silica in the form of quartz or
cristobalite that is inhaled from occupational sources is carcinogenic to humans (Group 1- carcinogenic to humans). Refer
to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (published in June 1997) in conjunction with the use of
these materials. The National Toxicology Program (NTP) classifies respirable crystalline silica as "known to be a human
carcinogen". Refer to the 9th Report on Carcinogens (2000). The American Conference of Governmental Industrial
Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (Group A2).
Breathing dust containing respirable crystalline silica may not cause noticeable injury or illness even though permanent
lung damage may be occurring. Inhalation of dust may have the following serious chronic health effects: Excessive
inhalation of respirable dust can cause pneumoconiosis, a respiratory disease, which can result in delayed, progressive,
disabling and sometimes fatal lung injury. Symptoms include cough, shortness of breath, wheezing, non-specific chest
illness and reduced pulmonary function. Smoking exacerbates this disease. Individuals with pneumoconiosis are
predisposed to develop tuberculosis. There is some evidence that breathing respirable crystalline silica or the disease
silicosis is associated with an increased incidence of significant disease endpoints such as scleroderma (an immune
system disorder manifested by fibrosis of the lungs, skin and other internal organs) and kidney disease.
Primary Route(s) Of Entry: Skin Contact, Inhalation
Medical Conditions which May be Aggravated by Exposure: If dry sanded, asthma and asthma-like conditions may
worsen from prolonged or repeated exposure to dust.

Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get
medical attention immediately.
First Aid - Skin Contact: Wash off immediately with soap and plenty of water.
First Aid - Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention immediately.
First Aid - Ingestion: Do not induce vomiting. Call a physician or Poison Control Center immediately.
Note to Physician: None.
COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arises from any of the above
routes of entry.

Section 5 - Fire Fighting
Measures
Flash Point, F: Greater than 200 degrees
Method: ( Seta Closed Cup)

Lower Explosive Limit, %: Not Established
Upper Explosive Limit, %: Not Established

Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: None known.
Special Firefighting Procedures: Cool fire -exposed containers using water spray.

Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8.
Scrape up dried material and place into containers.

Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! Avoid contact with skin and eyes. Wash thoroughly after handling. Do
not breathe dust. While dry sanding, use of a NIOSH -approved dust mask is recommended. Removal of this product after
use will result in the generation of Dust. If dry-sanded, exposure to dust may result in the build-up of material in eyes,
ears, nose, and mouth which may cause irritation. Avoid excessive heat and handling.
Storage: Store away from caustics and oxidizers. Do not store at temperatures above 120 degrees F. Keep tightly closed.
Avoid excessive heat and freezing.

Section 8 - Exposure Controls / Personal Protection
Precautionary Measures: Please refer to other sections and subsections of this MSDS.
Engineering Controls: Local ventilation of emission sources may be necessary to maintain ambient concentrations
below recommended exposure limits. Wet sanding is recommended to avoid generation of dust. Prevent build-up of dust
and vapors by opening windows and doors or use other means to ensure fresh air entry during application, drying and
sanding.

Respiratory Protection: A respiratory protection program that meets the OSHA 1910.134 and ANSI Z88.2 requirements
must be followed whenever workplace conditions warrant a respirator's use. If concentrations exceed the exposure limits
specified, use of a NIOSH-approved supplied air respirator is recommended. Where the protection factor is exceeded, use
of a Self Contained Breathing Apparatus (SCBA) may be necessary. Use an approved NIOSH/OSHA respirator if dry
sanded.
National Institute for Occupational Safety and Health (NIOSH) has recommended that the permissible exposure limit be
changed to 50 micrograms respirable free silica per cubic meter of air (0.05 mg/m3) as determined by a full shift sample
up to 10-hour work shift.
Skin Protection: Wear gloves with repeated or prolonged use.
Eye Protection: Safety glasses with side-shields.
Other protective equipment: Not required under normal use.
Hygienic Practices: Remove and wash contaminated clothing before re-use.

Section 9 - Physical And Chemical Properties
Boiling Range:
Odor:
Appearance:
Solubility in H2O:
Freeze Point:
Vapor Pressure:
Physical State:

210 - 220 F
Musty
White to Off-White
Not Established
Not Established
17.5 mm Hg @ 68F
Paste

Vapor Density:
Odor Threshold:
Evaporation Rate:
Specific Gravity:
pH:
Viscosity:

Heavier Than Air
Not Established
Slower Than n-Butyl Acetate
1.8
Between 7.0 and 12.0
Not Established

When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally.
(See section 16 for abbreviation legend)

Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Strong bases. Strong oxidizing agents.
Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under normal conditions.

Section 11 - Toxicological Information
Product LD50: Not Established
CASRN
Chemical Name
107-21-1

Product LC50: Not Established
LD50

Ethylene glycol

Rat:4700 mg/kg

LC50

WT%

Rat:10876 mg/kg

0.1-1.0

Carcinogenicity:
CAS No.
14808-60-7

Chemical Name
Silica, crystalline

ACGIH

OSHA

IARC

NTP

WT%

Suspected human carcinogen.

Not Listed.

Human carcinogen.

Known carcinogen.

0.1-1.0

Significant Data with Possible Relevance to Humans: None.

Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.

Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local
regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is
with the owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): none

Section 14 - Transportation Information
DOT Proper Shipping
Name:
DOT Technical Name:
DOT Hazard Class:

Not Regulated

Packing Group:

N.A.

N.A.
N.A.

Hazard Subclass:
DOT UN/NA Number:

N.A.
None

Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may
apply if shipped via other modes of transportation and/or to non-domestic destinations.

Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of
the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable
definitions, to meet the following categories:
Immediate Health Hazard, Chronic Health Hazard
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
None
Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported
from the United States:
None

U.S. State Regulations
New Jersey Right-to-Know:

The following materials are non-hazardous, but are among the top five components in this product:
Chemical Name

CAS Number

Water

7732-18-5

WT%
15-40

Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%:
Chemical Name

CAS Number

Water

7732-18-5

WT%
15-40

California Proposition 65:
WARNING: This product contains chemicals known to the State of California to cause cancer, birth defects or other
reproductive harm.

Section 16 - Other Information
HMIS Ratings:
Health: 1

Flammability: 0

VOLATILE ORGANIC COMPOUNDS, GR/LTR: 15.3

Reactivity: 0
LB/GAL: 0.1

Personal Protection: X
WT%: 0.4

REASON FOR REVISION: Periodic Update
Legend:

N.A. – Not Applicable

ACGIH – American Conference of Governmental Industrial Hygienists

N.E. – Not Established

SARA – Superfund Amendments and Reauthorization Act of 1986

N.D. – Not Determined

NJRTK – New Jersey Right-to-Know Law

VOC – Volatile Organic Compound

OSHA – Occupational Safety and Health Administration

PEL – Permissible Exposure Limit

HMIS – Hazardous Materials Identification System

TLV – Threshold Limit Value

NTP – National Toxicology Program

STEL – Short Term Exposure Limit

CEIL – Ceiling Exposure Limit

LD50 – Lethal Dose 50

LC50 – Lethal Concentration 50

F – Degree Fahrenheit

C – Degree Celsius

MSDS – Material Safety Data Sheet

CASRN – The Chemical Abstracts Service Registry Number

DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this
document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained
person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context
of the intended use and (ii) determine if they are appropriate.


00010421001 French

Page 1 of 7

Fiche
signalétique

24 heures – Numéros de téléphone en cas
d’urgence:
Urgence m édicale/ Empoisonner le Contrôle:
1-800-327-3874
1-513-558-5111
Urgence transport/Centre national de R éponse:
1-800-535-5053
1-352-323-3500

NOTE: Les numéros de t éléphone en cas d’urgence doivent
être utilisés uniquement lors de déversement, de fuite,
d’incendie, d’exposition ou d’accident impliquant des
produits chimiques.

IMPORTANT: Lire attentivement cette fiche signalétique avant de manipuler ou de disposer de ce produit. Remettre ces informations aux
employés, clients et utilisateurs de ce produit. Ce produit est régit sous la gouverne de l’OSHA, Communication de renseignements à l’égard de
matières dangereuses, et ce document a été préparé pour répondre aux exigences de ces standards. Les significations pour toutes les abréviations
utilisées dans cette fiche signal étique sont décrites à la Section 16.

Section 1 – Identification du produit et de la compagnie
This MSDS is offered in English upon request.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.

Nom du produit:
Numéro UPC:
Utilisation du
produit/Classe:
Fabricant:





DAP DRYDEX SPACKLING (RTU) SERRE LE
TUBE
070798123342, 070798123366, 070798123410,
070798123465
Pr êt à Utiliser la Réparation de Spackle/Panneau
MURAL
DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888 -327-8477 (Pour toute information non
urgente)

Date de r évision: 10/09/2007
Date
05/17/2007
d’abrogation:
Numéro de fiche: 00010421001

Section 2 - Identification des dangers
Urgences générales: Un produit rose de pâte avec une odeur insignifiante. AVERTISSEMENT ! Peut causer une
irritation des yeux, de la peau, du nez, de la gorge et des voies respiratoires. L’enlèvement de ce produit après usage ou
lors de ponçage à sec générera de la poussière. L’exposition à cette poussière peut causer une irritation des yeux, des
oreilles, du nez et de la bouche. Nocif par inhalation et par ingestion. Lors de ponçage à sec, une exposition à la
poussière peut causer une accumulation de matériau dans les yeux, les oreilles, le nez et la bouche. Ce produit contient
du glycol d'éthylène.
Consulter les autres sections de cette fiche signalétique pour des informations plus détaillées.
Effets de surexposition – Contact oculaire: Le contact direct avec les yeux peut provoquer une irritation.
Effets de surexposition – Contact cutané: Peut causer une irritation de la peau. Peut causer un assèchement de la
peau.
Effets de surexposition – Inhalation: L'inhalation de ce produit peut provoquer l'irritation des voies respiratoires (nez,
bouche, muqueuses). L'inhalation de poussi ère peut causer des dommages du poumon ou les effets autres,
défavorables, pulmonaires et respiratoires.
Effets de surexposition – Ingestion: L'ingestion peut provoquer une irritation de l'appareil digestif, des nausées, des
vomissements et des diarrhées.
Effets de surexposition – Dangers chroniques:

00010421001 French

Page 2 of 7

L'Agence Internationale pour la Recherche sur le Cancer (IARC) a déterminé cette silice cristalline sous forme de quartz
ou cristobalite qui est inhalé des sources de métier est cancérog ène aux humains (Groupe 1- cancérogène aux humains).
Se référer à la Monographie de IARC 68, la Silice, Quelques Silicates et Quelques Fibres Organiques (a publié en juin
1997) conjointement avec l'usage de ces matériels. Le Programme National de Toxicologie (NTP) classifie respirable la
silice cristalline comme " connu pour être une substance cancérogène humaine ". Se référer au neuvième Rapport sur les
Substances Canc érogènes (2000). La Conférence Am éricaine d'Hygiénistes Industriels Gouvernementaux (ACGIH)
classifie la silice cristalline, le quartz, comme une substance cancérogène humaine pr ésumée (le Groupe A2).
Respirer de la poussière contenant de la silice cristalline peut ne pas causer de lésions ni de maladies apparentes m ême
si des lésions permanentes aux poumons sont survenues. L’inhalation de poussi ère peut avoir des conséquences
chroniques très sérieuses pour la santé : L’inhalation excessive de poussière respirable peut causer une pneumoconiose,
une maladie respiratoire qui peut dégénérer sur un certain temps en incapacité progressive et quelques fois en lésions
des poumons qui peut être mortelle. Les symptômes incluent : toux, respiration courte, sifflements, maladie de poitrine
indéterminée et une réduction de la capacité pulmonaire. Fumer peut causer une accélération brutale de cette maladie.
Les personnes atteintes de pneumoconiose sont prédisposées pour développer la tuberculose. Il y a plusieurs évidences
démontrant que respirer de la silice cristalline ou la silicose est associ ée à une incidence accrue de maladies extrêmes
significatives tel que le syndrome d’Erasmus (un désordre du système immunitaire manifeste caus é par une fibrose des
poumons, de la peau et de d’autres organes internes) et une maladie des reins.
Une exposition excessive et répétée à l’éthyl ène glycol peut causer des l ésions aux reins et au foie. Les études en
laboratoire menées sur des animaux ont démontré que l ’inhalation répétée d’éthyl ène glycol cause des changements
néfastes du système cardiovasculaire. Lors d’études en laboratoire sur les animaux, il a été démontré que l ’éthyl ène
glycol cause des anomalies congénitales.
Voie(s) d’absorption: Peau le Contact, Inhalation, Oeil le Contact
Problèmes médicaux aggravés lors d’exposition au produit: Lors de pon çage à sec, la condition des personnes
atteintes d’asthme ou de symptômes semblables à l’asthme peut s’aggraver en cas d’exposition excessive et répétée à la
poussière.
Effets cancérig ènes:
CAS No.
14808-60-7

Chemical Name
Silice cristalline

ACGIH

OSHA

IARC

NTP

Présumée canc érogène
humaine.

Pas Enuméré.

Cancérogène humaine.

Cancérogène connue.

Section 3 - Composition / Ingrédients dangereux
Chemical Name
Pierre à chaux
Éthylène glycol
Magnesium aluminum silicate
Silice cristalline

CASRN
1317-65-3
107-21-1
12174-11 -7
14808-60 -7

Wt%
60-100
0.5-1.5
0.5-1.5
0.1-1.0

Section 4 - Premiers soins
Premiers soins – Contact oculaire: En cas de contact avec les yeux, rincer abondamment avec de l ’eau pendant au
moins 15 minutes. Obtenir des soins médicaux immédiatement.
Premiers soins – Contact cutané: Laver immédiatement et abondamment avec de l'eau et du savon.
Premiers soins – Inhalation: En cas d’inhalation, amener la personne à l’air frais. Si la personne ne respire plus,
appliquer la respiration artificielle. Si la personne a de la difficulté à respirer, donner de l’oxyg ène. Obtenir des soins
médicaux immédiatement.

00010421001 French

Page 3 of 7

Premiers soins – Ingestion: Appeler immédiatement un m édecin ou un Centre AntiPoison. Ne pas faire vomir.
Note au médecin: Aucun.
COMMENTAIRES: En cas d’apparition d’une irritation ou de complications suite à une exposition au produit,
communiquer immédiatement avec l’urgence m édicale au 1-800-327 -3874.

Section 5 - Mesures de protection en cas d’incendie
Moyens d’extinction: Dioxyde de carbone, Sécher Chimique, Mousse, Arroser le Brouillard
Risques particuliers d’explosions ou d’ignition: Aucune connue.
Procédures spéciales de lutte contre les incendies: Utiliser une lance-brouillard afin de refroidir les contenants
expos és au feu.

Section 6 - Mesures en cas de déversement accidentel
Procédures de nettoyage: Porter un équipement de protection personnel approprié tel que spécifié à la Section 8.
Gratter le mat ériau sec puis déposer dans un contenant.

Section 7 - Manutention et entreposage
Manutention: TENIR HORS DE LA PORTÉE DES ENFANTS! Eviter le contact avec la peau et les yeux. Ne pas respirer
la poussi ère. Pendant que sécher sanding, of a d'usage masque de poussière NIOSH-APPROUVE est recommandé.
L’enlèvement de ce produit générera de la poussière. Lors de ponçage à sec, l’exposition à cette poussière produit une
accumulation de matériau dans les yeux, les oreilles, le nez et la bouche et peut causer une irritation. Éviter la chaleur et
la manipulation excessive. Laver vigoureusement après la manipulation.
Entreposage: Éviter la chaleur excessive ou le froid excessif. Ne pas entreposer à des températures supérieures à 120º
F (48,8º C). Conserver hermétiquement fermé. Entreposer loin des produits caustiques et des agents oxydants.

Section 8 - Contrôles d’exposition / Protection personnelle
Chemical Name

CASRN

ACGIH TWA

ACGIH STEL

ACGIH CEIL

Pierre à chaux

1317-65-3

10 MGM3

N.E.

N.E.

Éthylène glycol
Magnesium aluminum silicate

107-21-1
12174-11-7

N.E.
N.E.

N.E.
N.E.

100 MGM3
N.E.

Silice cristalline

14808-60-7

0.05 MGM3

N.E.

N.E.

OSHA TWA
5 MGM3
(respirable
fraction)
N.E.
N.E.
10/(%SiO2 + 2)
MGM3

OSHA STEL

OSHA CEIL

Skin

N.E.

N.E.

Non

N.E.
N.E.

N.E.
N.E.

Non
Non

N.E.

N.E.

Non

Notes concernant l’exposition:
14808-60-7 La liste des valeurs d'exposition moyennes pondérées (VEMP) 2001 émise par l'ACGIH, section «Threshold
Limit Values for Chemical Substances and Physical Agents» indique que la silice cristalline, en terme de particule
aérodynamique, possède un diamètre de 4.0 microns.
La limite volatile tolérable pour la silice cristalline représente la fraction respirable.
La limite d'exposition permise et la limite volatile tolérable pour la silice cristalline, quartz, sont calculées par l'OSHA à
partir de la formule suivante : 10 mg/m3/(% SiO2 + 2). Les deux, la concentration et le pourcentage de quartz pour
l'application de ces limites, doivent être déterminées par le pourcentage de silice cristalline non capté lors du passage des
particules en suspension dans un capteur-sélecteur de micro-organismes ayant les caractéristiques suivantes :
|----------------------------------------------------------------------------|-------------------------------|
| .. Diamètre aérodynamique (sphère de densit é égale à l'unité) .| Pourcentage non capté |
|....................................................................................................| par un capteur-sélecteur |

00010421001 French

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|....................................................................................................| de micro-organisme |
| 2 ................................................................................................|.................90....................|
| 2.5 .............................................................................................|..................75...................|
| 3.5 .............................................................................................|..................50...................|
| 5.0 .............................................................................................|..................25...................|
| 10 ..............................................................................................|...................0....................|
Mesures de précaution: S'il vous plaît se référer aux autres sections et aux autres sous -sections de ce MSDS.
Contrôles d’ingénierie: Une ventilation locale près de la source d'émission peut être nécessaire pour maintenir la
concentration ambiante au-dessous des niveaux limites recommandés. Empêcher l'accumulation de poussière et les
vapeurs en ouvrant fenêtres et les portes ou utilise d'autres moyens pour assurer de l'entrée d'air fraîche pendant
l'application, séchant et sanding. Un ponçage humide est recommandé afin d’éviter de générer de la poussière.
Protection des voies respiratoires: Si la concentration dépasse les niveaux limites sp écifiés, il est recommandé
d'utiliser un respirateur à adduction d'air pur agr éé par NIOSH. Lorsque la concentration dépasse le facteur de protection
de ce type de respirateur, il peut être nécessaire d'utiliser un appareil respirateur autonome. Un programme de protection
respiratoire défini selon les normes de l ’OSHA 1910.134 et de l’ANSI Z88.2 doit être appliqu é à chaque fois que les
conditions sur les lieux de travail exigent de porter un respirateur. Lors de ponçage à sec, porter un respirateur approuvé
NIOSH/OSHA.
Le National Institute for Occupational Safety and Health (NIOSH) recommande que la limite d’exposition permise pour la
silice en suspension soit abaissée à 50 microgrammes par mètre cube d’air (0,05 mg/m3) tel que déterminé lors de
périodes de travail complètes pouvant aller jusqu’à 10 heures.
Protection de la peau: En cas d’utilisation excessive et répétée, porter des gants.
Protection des yeux: lunettes de sécurité avec protections latérales
Équipements de protection additionnels: inutile dans les conditions normales d'utilisation.
Pratiques hygiéniques: Enlever et laver les vêtements contaminés avant réutilisation.
Important:

Les limites d’exposition permises (LEP) décrites proviennent du Department of Labor des États-Unis, règlement final concernant les valeurs
d’exposition moyennes pondérées de l’OSHA
(CFR 29 1910.1000); ces limites peuvent varier selon les états.

Note:

Prendre tous les moyens selon les circonstances afin de prévenir ou réduire toute exposition de la peau des employés aux substances portant la mention
«OUI» dans la colonne «PEAU» du tableau ci-dessus. Utiliser des gants, une combinaison, des lunettes étanches, tout autre équipement de protection personnel
adéquat, les contrôles techniques et les pratiques appropriées au type de travail.

Section 9 - Propriétés physiques et chimiques
Point d’ébullition:
Odeur:
Apparence:

Pas Etabli.
Insignifiant
Pink

Densité de vapeur:
Limite de détection olfactive:
Taux d ’évaporation:

Plus lourd Qu'Aérer
Pas Etabli.
Plus lent Que Acétate de
n-Butyl
1.9

Solubilité dans l’eau
(H 2 O):
Point de congélation:
Pression de vapeur:
État physique:
Point d’éclair, º F:
Limite d ’explosibilité
inférieure, %:

Pas Etabli.

Poids spécifique:

Pas Etabli.
Pas Etabli.
Pâte
Plus grand que 200 degrés
Pas Etabli.

Taux de pH:
Entre 7,0 et 12,9
Viscosité:
Pas Etabli.
Inflammabilité:
Ininflammable
Méthode:
(Seta A Fermé la Tasse)
Limite d ’explosibilité supérieure, %:Pas Etabli.

Quand rapporté, la pression de vapeur de ce produit a été basé son maquillage de constituant théoriquement calculée et n'a pas été expérimentalement.
(Consulter la Section 16 pour conna ître la signification des abréviations)

Section 10 - Stabilité et réactivité

00010421001 French

Page 5 of 7

Conditions à éviter: Chaleur excessive ou froid excessif.
Incompatibilité: des oxydants forts des bases fortes
Produits de décomposition dangereux: Produits de d écomposition habituels : oxydes de carbone (COx) et oxydes
d’azote (NOx).
Risque de polym érisation: Aucune polymérisation dangereuse ne surviendra dans des conditions normales d’utilisation.
Stabilité: Stable dans des conditions normales

Section 11 - Propriétés toxicologiques
Produit DL50: Pas Etabli.
CASRN
107-21-1

Chemical Name

Produit CL50: Pas Etabli.
LD50

Éthylène glycol

LC50

Rat:4700 mg/kg

Rat:10876 mg/kg

Données significatives possiblement pertinentes à l’humain: Aucun.

Section 12 - Information écologique
Information écologique: Aucune dégradation de l'environnement n'est connue ou prévisible dans les conditions
normales d'utilisation.

Section 13 - Information sur la mise au rebut
Information concernant la mise au rebut: Disposer de ce matériau en respectant les lois fédérales, provinciales et
municipales. Les lois et restrictions provinciales et municipales sont complexes et peuvent différer des lois f édérales. La
responsabilité de la disposition appropriée des déchets appartient au propriétaire des déchets.
Code de mise au rebut de l ’Agence de protection de l’environnement (40 CFR Section 261): Aucun

Section 14 - Étiquetage selon le Ministère des Transports
Nom du produit expédié:
Nom technique:
Classe de danger:

Pas Réglé.
Pas Applicable
Pas Applicable

Groupe d’emballage:
Classe de transport:
Numéro UN/NA:

Pas Applicable
Pas Applicable
Pas Applicable

Note : L'information d'expédition fournie est applicable pour le transport de sol domestique seulement. La catégorisation
différente peut s'appliquer si exp édié via les autres modes de et/ou de transport aux destinations non résidentielles.

Section 15 - Information sur les règlements
CERCLA - Catégories de dangers selon le SARA:
Ce produit a été revu en conformité avec les «Catégories de dangers» établies par l’Agence de protection de
l’environnement et promulguées aux Sections 311 et 312 du Superfund Amendment and Reauthorization Act de 1986
(SARA Titre III). Selon les définitions applicables, il est considéré répondre aux catégories suivantes :
RISQUE DE SANTE IMMEDIAT, RISQUE DE SANTE CHRONIQUE
SARA Section 313:

00010421001 French

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Ce produit contient les substances suivantes assujetties aux normes de déclaration de la Section 313, du Titre III
de la Superfund Amendments and Reauthorization Act de 1986 et du 40 CFR partie 372:
Aucun
LOI SUR LE CONTRÔLE DES SUBSTANCES TOXIQUES:
Tous ingrédients dans ce produit sont ou sur la liste d'inventaire de TSCA, ou autrement exempter.
Ce produit contient les substances chimiques suivantes à déclarer selon les normes TSCA 12(B) si export é à l’extérieur
des États -Unis:
Aucun
New Jersey Right-to-Know:
Les substances suivantes sont non-dangereuses mais sont comptées parmi les 5 principaux ingrédients composant ce
produit:
Chemical Name

CAS Number

Eau

7732-18-5

Pennsylvania Right-to-Know:
Les substances suivantes sont non-dangereuses mais sont présentes à plus de 3% dans ce produit:
Chemical Name

CAS Number

Eau

7732-18-5

Proposition 65 de Californie:
AVERTISSEMENT : Ce produit contient des produits chimiques connus à l'Etat de Californie pour causer le cancer, des
anomalies congénitales ou d’autres problèmes reliés à la reproduction.

Section 16 - Autres informations
HMIS Classification des
dangers:
Santé: 1

Inflammabilité: 0

Réactivité: 0

Protection personnelle: X

COMPOSÉ ORGANIQUE VOLATIL (VOC), moins d'eau exempte moins: G/LITRE :
POIDS : POIDS % : 1.2

39.8

COMPOSÉ ORGANIQUE VOLATIL (VOC), moins d'eau exempte moins, moins LVP-VOCs:
0.3
RAISONS DE RÉVISION: Mise à jour p ériodique
Légende:
N.A. – Non applicable

LD50 – Dose létale 50

N.É. – Non établi

LC50 – Concentration létale 50

N.D. – Non déterminé

NJRTK – New Jersey Right-to -Know Law

OSHA – Occupational Safety and Health Administration

VOC – Composé organique volatil

LB/GALLON: 0.3

POIDS : POIDS %:

00010421001 French

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HMIS – Hazardous Materials Identification System

PEL – Limite d’exposition permise

TWA – Valeur d’exposition moyenne pondérée

TLV – Limite tolérable d’exposition

NTP – National Toxicology Program

F – Degré Fahrenheit

STEL – Limite d’exposition à court terme

C – Degré Celcius

CASRN – Numéro enregistré selon le Chemical Abstracts Service
ACGIH – American Conference of Governmental Industrial Hygienists
SARA – Superfund Amendments and Reauthorization Act de 1986
CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act

DAP croit que les données et renseignements stipulés dans cette fiche signal étique sont précis à la date de rédaction de cette fiche. Ces
données sont offertes en toute bonne foi et représente des valeurs standard sans toutefois être des sp écifications du produit. AUCUNE
GARANTIE SUR LA QUALITÉ MARCHANDE, GARANTIE D’APTITUDE POUR AUCUN TYPE D’EMPLOI
PARTICULIER OU TOUTE AUTRE FORME DE GARANTIE N’EST EXPRESSÉMENT OU IMPLICITEMENT
OFFERTE EN REGARD DES INFORMATIONS FOURNIES DANS CETTE FICHE OU DES INFORMATIONS
RELATIVES AU PRODUIT. Cette fiche est produite uniquement à titre de guide pour les personnes formées à cet effet afin qu’elles
puissent appliquer les procédures appropri ées de manutention auxquelles le produit réfère. Toutefois, c’est la responsabilité chaque
utilisateur de revoir les recommandations selon le contexte spécifique de l’utilisation prévue et de déterminer si ces proc édures sont
appropriées.
< Fin de la fiche signalétique >

MATERIAL SAFETY DATA SHEET
Date Printed: 07/16/2001
Product Code(s): 4130, 4132, 4136

Page:

________________________________________________________________________________
1.

CHEMICAL PRODUCT AND COMPANY INFORMATION

Product Name: Body Seam Tape
Product Code(s): 4130, 4132, 4136
Manufacturer/Supplier: TRANSTAR AUTOBODY TECHNOLOGIES
2040 Heiserman Dr.
Brighton, MI, 48114, USA

24 Hour Emergency Phone(s): 800-424-9300 (CHEMTREC), 613-996-6666 (CANUTEC)
Business Phone: 810-220-3000
Product Use: Sealant
MSDS Prepared By: V. Burgess Byrd
________________________________________________________________________________
2.

COMPOSITION/INFORMATION ON INGREDIENTS

Ingredient(s)
CAS Number
% by Weight
--------------------------------------------------------------------------2-Ethylhexyl Acrylate
103-11-7
65- 80%
Acrylic Acid, Glacial
79-10-7
5 - 10%
n-Vinyl Pyrollidone
88-12-0
0 - 5%
Isobornyl Acrylate
5888-33-5
0 - 5%
See Section 15. Regulatory Information for code descriptions
Weight percent (%) of 0.0 means chemical is in trace amounts.
________________________________________________________________________________
3.

HAZARDS IDENTIFICATION

CAUTION!

COMBUSTIBLE

HMIS Hazard Ratings: Health =0 , Flammability =1, Chemical Reactivity =0
Note: HMIS ratings involve data and interpretations that may vary
from company to company. They are intended only for rapid, general
identification of the magnitude of the specific hazard. To deal
adequately with the safe handling of this material, all the
information contained in this MSDS must be considered.
Potential Health Effects
Eyes: Minimal to slight irritation to the eyes.
and itching.

Exposure can cause redness

Skin: Slight irritation to the skin.
Inhalation: Minimal to slight irritation to the respiratory system.
Ingestion: Slight irritation to the digestive tract.
________________________________________________________________________________

1

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Date Printed: 07/16/2001
Product Code(s): 4130, 4132, 4136

Page:

________________________________________________________________________________
4.

FIRST AID MEASURES

Seek professional medical attention for all over-exposures and/or
persistent problems.
Eyes Contact: Flush eyes with clean water for a minimum of 15 minutes.
Seek medical attention.
Skin Contact: Wash exposed area thoroughly with soap and water.
Inhalation: Remove person from area to fresh air.
difficulty persists, seek medical attention.
Ingestion: DO NOT INDUCE VOMITTING.

If breathing

Seek immediate medical attention.

________________________________________________________________________________
5.

FIRE FIGHTING MEASURES

Flammable Properties
Flash Point: >200 Deg F, 93 Deg CMethod: TCC
Upper Explosive Limit (UEL): n/a
Lower Explosive Limit (LEL): n/a
Autoignition Temperature: No data
Extinguishing Media: Foam, Alcohol Foam, CO2, Dry Chemical, Water Fog,
Other.
Special Firefighting Procedures: Full fire fighter equipment including
SCBA should be worn to avoid skin contact and inhalation of
concentrated vapors. Minimize skin exposure. Highly toxic fumes may
be generated by thermal decomposition.
Hazardous Combustion Products: Carbon monoxide, carbon dioxide, oxides
of nitrogen.
Unusual Fire and Explosion Hazards: Vapors can travel to a source of
ignition and flash back. Closed containers may explode when exposed
to extreme heat or burst when contaminated with water (CO2 gas
evolved). Hazards apply to empty containers. Combustion generates
toxic fumes.
________________________________________________________________________________
6.

ACCIDENTAL RELEASE MEASURES

For large spills or transportation accidents involving release of this
product, contact the Emergency Response Center: 800-424-9300.
Eliminate all sources of ignition, provide adequate ventilation, dike
spill area and add absorbent earth or sawdust to spilled liquid. Sweep
up and dispose of in appropriate containers in accordance with
Federal, State and/or Local regulations.
________________________________________________________________________________
7.

HANDLING AND STORAGE

2

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Date Printed: 07/16/2001
Product Code(s): 4130, 4132, 4136

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________________________________________________________________________________
Use non-sparking tools when handling this material. Use in cool,
well-ventilated areas. Keep containers closed when not in use. Keep
away from excessive heat and open flames. Follow all MSDS/label
precautions even after container is emptied because they may retain
product residues. Store in a cool area away from heat and flames. Do
not reuse container when empty.
________________________________________________________________________________
8.

EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines
Chemical Name/Exposure Limits
CAS Number
--------------------------------------------------------------------------2-Ethylhexyl Acrylate
103-11-7
(OSHA PEL: 5 mg/m3)
Acrylic Acid, Glacial
79-10-7
(OSHA PEL: 10 ppm)
n-Vinyl Pyrollidone
88-12-0
(OSHA PEL: Not Est, ACGIH TLV: Not Est, OTHER: Not Est)
Isobornyl Acrylate
5888-33-5
(OSHA PEL: Not Est, ACGIH TLV: Not Est, OTHER: Not Est)
Engineering Controls: General mechanical ventilation or local exhaust
should be utilized to keep vapor concentrations below exposure limits
(PEL & TLV). Ventilation equipment must be explosion proof.
Respiratory Protection: Utilize engineering controls to reduce
emission levels below the time weighted exposure limits (ACGIH TLV &
OSHA PEL). Wear an approved respirator if exposure limits are above
the exposure limits listed above.
Eye Protection: Use safety glasses or splash goggles.
Skin Protection: Use chemical resistant gloves.
Safe Work Practices: Eye washes and safety showers in the workplace
are recommended. Avoid contact with skin and eyes. Avoid breathing
vapors. Wash hands thoroughly after using and before eating, drinking
or smoking. Employee education and training in the safe use and
handling of this product is required under the OSHA Hazard
Communication Standard 29CFR1200. Smoking in area where this material
is used should be strictly prohibited. Always use protective clothing
and equipment. Remove all contaminated clothing and wash thoroughly
when finished working. Keep food and drink away from material and
from area where material is being used.
________________________________________________________________________________
9.

PHYSICAL AND CHEMICAL PROPERTIES

Physical Form: Homogeneous mixture
Physical State: Solid
Color: Cloudy, colorless
Odor: Characteristic acylate odor.
Odor Threshold: No Data
Specific Gravity (water=1) 1.00
Vapor Pressure: No data

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MATERIAL SAFETY DATA SHEET
Date Printed: 07/16/2001
Product Code(s): 4130, 4132, 4136

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________________________________________________________________________________
Vapor Density: N/A
Material VOC:
0.00 lb/gl
0 g/l
Coating VOC:
0.00 lb/gl
0 g/l
Evaporation Rate: N/A
Boiling Point: n/a
Melting Point: No data
Freezing Point: No data
Viscosity at Ambient Temperature: No data
Solubility in Water: Insoluble
Octanol/Water Partition Coefficient: No data
pH: No data
________________________________________________________________________________
10.

STABILITY AND REACTIVITY

Stability: Stable
Incompatibility: Strong acids, strong bases and strong oxidizing
agents.
Hazardous Polymerization: WILL NOT OCCUR.
________________________________________________________________________________
11.

TOXICOLOGICAL INFORMATION

Effects of Exposure:
ACUTE:
INHALATION - Minimal odor present during normal material handling and
use.
EYE CONTACT - Mild irritation, tearing, redness.
SKIN CONTACT - Mild irritation possible.
INGESTION - May cause mild gastrointestinal irritation, vomiting,
nausea, & diarrhea.
CHRONIC:
No chronic health effects known.

Acute Toxicity Data: No data.
Carcinogenicity: NTP -No, IARC -No, OSHA -No
This product has not been tested for carcinogenic effects. Some
chemicals in this product may be identified by NTP, IARC and/or OSHA
as carcinogenic, indicated above as "Yes". No further information
available.
Teratology: No data.
Reproduction: No data.
Mutagenicity: No data.
________________________________________________________________________________
12.

ECOLOGICAL INFORMATION

No data.

4

MATERIAL SAFETY DATA SHEET
Date Printed: 07/16/2001
Product Code(s): 4130, 4132, 4136

Page:

________________________________________________________________________________
________________________________________________________________________________
13.

DISPOSAL CONSIDERATIONS

This product when disposed represents a non-hazardous waste, as
identified in 40CFR261. It is the responsibility of each waste
generator to identify the proper classification of their waste
streams.
________________________________________________________________________________
14.

TRANSPORT INFORMATION

The following transportation information is provided based on Transtar
Autobody Technologies interpretation of shipping regulations. Each
shipper is responsible for identifying, naming, marking and labeling
prior to offering for transport.
USA (DOT) Status: Not regulated
Water (IMDG) Status: Not regulated
Air (ICAO,IATA) Status: Not regulated
Canada (TDG) Status: Not regulated
________________________________________________________________________________
15.

REGULATORY INFORMATION

The information listed in this section is not all inclusive of all
regulations for this product or the chemical components of this
product.
US Federal Regulations
TSCA Status: All known major components of this product are listed on
the TSCA Inventory and/or are otherwise in compliance with TSCA.
SARA 302 (EHS) Status: No EHS chemicals present.
SARA 311/312 Status: No hazards to Emergency Responders identified.
SARA 313 Status: *** No toxic chemical(s) subject to the reporting
requirements of section 313 of Title III and of 40 CFR 372 are
present. ***
OSHA Status: This material meets the requirement of hazardous material
and is subject to 29CFR1910.1200.
USA State Information
California Proposition 65: This product does not contain chemical(s)
known to the State of California to cause cancer or birth defects or
other reproductive harm.
Pennsylvania RtK Status: This material contains chemical(s) subject to
notification under Pennsylvania Right to Know.
New Jersey RtK Status: This material contains chemical(s) subject to

5

MATERIAL SAFETY DATA SHEET
Date Printed: 07/16/2001
Product Code(s): 4130, 4132, 4136

Page:

________________________________________________________________________________
notification under New Jersey Right to Know.
Massachusetts RtK Status: This material contains chemical(s) subject
to notification under Massachusetts Right to Know.
Rhode Island RtK Status: This material contains chemical(s) subject to
notification under Rhode Island Right to Know.
International Regulations
Canada
DSL Status: All known major components of this product are listed on
the DSL Inventory and/or are otherwise in compliance with the DSL
WHMIS: E
EINECS Status: All components of this material are listed on the
EINECS Inventory.
________________________________________________________________________________
16.

OTHER INFORMATION

To the best of our knowledge, the information contained herein is
accurate, obtained from sources believed by Transtar Autobody
Technologies to be accurate. As with all chemicals, KEEP AWAY FROM
CHILDREN AND ANIMALS. FOR PROFESSIONAL USE ONLY. The hazard
information contained herein is offered solely for the consideration
of the user, subject to his own investigation and verification of
compliance with applicable regulations, including the safe use of the
product under every foreseeable condition.
________________________________________________________________________________

6

MATERIAL SAFETY DATA SHEET
WL30067
03 00
===========================================================================
Section 1 −− PRODUCT AND COMPANY IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT NUMBER
HMIS CODES
Health
1
WL30067
Flammability
0
Reactivity
0
PRODUCT NAME
WHITE LIGHTNING* 3006* Original Formula All Purpose Adhesive Caulk,
Clear
MANUFACTURER’S NAME
EMERGENCY TELEPHONE NO.
THE SHERWIN−WILLIAMS CO.
(216) 566−2917
Consumer Group − Industrial
Cleveland, OH 44115
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
03−APR−07
(216) 566−2902
===========================================================================
Section 2 −− COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
No ingredients in this product are hazardous as defined by the
Department of Labor.
===========================================================================
Section 3 −− HAZARDS IDENTIFICATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
In a confined area vapors in high concentration may cause headache,
nausea or dizziness.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.

Continued on page 2

WL30067
page 2
===========================================================================
Section 4 −− FIRST AID MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
EYES:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
SKIN: Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re−use.
INHALATION: If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
INGESTION: Do not induce vomiting.
Get medical attention immediately.
===========================================================================
Section 5 −− FIRE FIGHTING MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
FLASH POINT
LEL
UEL
Not Applicable
N.A.
N.A.
FLAMMABILITY CLASSIFICATION
Not Applicable
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Alcohol Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers may explode (due to the build−up of pressure) when
exposed to extreme heat.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self−contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build−up and possible autoignition or explosion when exposed to
extreme heat.
===========================================================================
Section 6 −− ACCIDENTAL RELEASE MEASURES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
===========================================================================
Section 7 −− HANDLING AND STORAGE
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STORAGE CATEGORY
Not Applicable
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep container closed when not in use. Transfer only to approved
containers with complete and appropriate labeling. Do not take internally.
Keep out of the reach of children.

Continued on page 3

WL30067
page 3
===========================================================================
Section 8 −− EXPOSURE CONTROLS/PERSONAL PROTECTION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
Removal of old paint by sanding, scraping or other means may generate
dust or fumes that contain lead. Exposure to lead dust or fumes may cause
brain damage or other adverse health effects, especially in children or
pregnant women. Controlling exposure to lead or other hazardous substances
requires the use of proper protective equipment, such as a properly fitted
respirator (NIOSH approved) and proper containment and cleanup. For more
information, call the National Lead Information Center at 1−800−424−LEAD
(in US) or contact your local health authority.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
Wear gloves which are recommended by glove supplier for protection
against materials in Section 2.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
===========================================================================
Section 9 −− PHYSICAL AND CHEMICAL PROPERTIES
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
PRODUCT WEIGHT
8.77 lb/gal
1050 g/l
SPECIFIC GRAVITY
1.06
BOILING POINT
212 − 213 F
100 − 100 C
MELTING POINT
Not Available
VOLATILE VOLUME
51 %
EVAPORATION RATE
Slower than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
8.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical − As Packaged)
0.26 lb/gal
31 g/l
Less Water and Federally Exempt Solvents
0.13 lb/gal
15 g/l
Emitted VOC

Continued on page 4

WL30067
page 4
===========================================================================
Section 10 −− STABILITY AND REACTIVITY
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
STABILITY −− Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
===========================================================================
Section 11 −− TOXICOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
TOXICOLOGY DATA
CAS No.
Ingredient Name
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
No LC50 or LD50 data available.
===========================================================================
Section 12 −− ECOLOGICAL INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
ECOTOXICOLOGICAL INFORMATION
No data available.
===========================================================================
Section 13 −− DISPOSAL CONSIDERATIONS
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
WASTE DISPOSAL METHOD
Waste from this product is not hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Incinerate in approved facility. Do not incinerate closed container.
Dispose of in accordance with Federal, State/Provincial, and Local
regulations regarding pollution.
===========================================================================
Section 14 −− TRANSPORT INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
US Ground (DOT)
Not Regulated for Transportation.
Canada (TDG)
Not Regulated for Transportation.
IMO
Not Regulated for Transportation.
===========================================================================
Section 15 −− REGULATORY INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION

Continued on page 5

WL30067
page 5
===========================================================================
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
No ingredients in this product are subject to SARA 313 (40 CFR 372.65C)
Supplier Notification.
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
===========================================================================
Section 16 −− OTHER INFORMATION
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

Material Safety Data Sheet - MSDS

Masking Tape

Section 1. Chemical Product and Company Identification
Masking Tape

Common Name

:

Synonym
Trade name
Manufactured for

: Not available.
: DT339.
: L.H. Dottie Company
6131 S. Garfield Avenue
Commerce, California 90040
Tel: (323) 725-1000

Code

: DT339

Validation Date
: 2004-10-24.
In Case of Emergency : (714) 739-1408

Section 2. Composition, Information on Ingredients
Name

CAS #

% by Weight

Polyethylene

9002-88-4

70-100

Exposure Limits

OSHA PEL (United States, 2002). Notes:
TWA: 5 mg/m3 8 hour(s). Form: Respirable dust
TWA: 15 mg/m3 8 hour(s). Form: Total dust
This material is classified as not hazardous under OSHA regulations. This product is an Article under the United States Hazard
Communication System. Therefore it is EXEMPTED from the regulatory requirements under HCS.
See Section 8 for Exposure Limits.
See Section 11 for Toxicological Data.

Section 3. Hazards Identification
Physical State and
Appearance
Emergency Overview

: Solid.

Potential Chronic Health
Effects

: CARCINOGENIC EFFECTS: Classified None. by NIOSH [Polyethylene]. Classified 3 (Not classifiable for
human.) by IARC [Polyethylene].
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
: Repeated or prolonged exposure is not known to aggravate medical condition.

: No specific hazard.
USE WITH CARE.
Follow good industrial hygiene practice.
: Ingestion.
Routes of Entry
Potential Acute Health Effects
Eyes : Non-irritating to the eyes.
Skin : Non-irritant for skin. Non-sensitizer for skin.
Inhalation : Not available.
Ingestion : Not available.

Medical Conditions
Aggravated by
Overexposure:
Over-exposure
: Not available.
signs/symptoms
See Section 11 for Toxicological Data.

Section 4. First Aid Measures
Eye Contact
Skin Contact
Inhalation
Ingestion
Notes to Physician

: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of
water for at least 15 minutes. Get medical attention if irritation occurs.
: In case of contact, immediately flush skin with plenty of water. Get medical attention.
: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical attention.
: Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to
an unconscious person. If large quantities of this material are swallowed, call a physician immediately.
: No specific antidote. Medical staff must contact Poison Information Center.

Continued on Next Page

Page: 2/5

Masking Tape

Section 5. Fire Fighting Measures
May be combustible at high temperature.
The lowest known value is >343°C (649.4°F) (Polyethylene).
Not available.
Not available.
These products are carbon oxides (CO, CO2).
Non-flammable in presence of heat.

Flammability of the Product
Auto-ignition Temperature
Flash Points
Flammable Limits
Products of Combustion
Fire Hazards in Presence of
Various Substances
Explosion Hazards in
Presence of Various
Substances
Fire Fighting Media
and Instructions
Protective Clothing (Fire)

:
:
:
:
:
:

Special Remarks on Fire
Hazards

: Not available.

: Risks of explosion of the product in presence of mechanical impact: Not applicable.
Risks of explosion of the product in presence of static discharge: Not applicable.
: SMALL FIRE: Use dry chemical powder.
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
: Be sure to use an approved/certified respirator or equivalent.

Section 6. Accidental Release Measures
Small Spill and Leak

Large Spill and Leak

: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and dispose of according to local and regional authority
requirements.
: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and allow to evacuate through the sanitary system.

Section 7. Handling and Storage
: After handling, always wash hands thoroughly with soap and water.
: Keep container in a cool, well-ventilated area. Do not store above 49°C (120.2°F).

Handling
Storage

Section 8. Exposure Controls, Personal Protection
Engineering Controls
Personal Protection
Eyes
Body
Respiratory
Hands
Feet
Protective Clothing
(Pictograms)
Personal Protection in Case
of a Large Spill
Exposure Limits
Product Name
Polyethylene

: No special ventilation requirements.
:
:
:
:
:

Not required.
Not required.
Not applicable.
Not applicable.
Not applicable.

:
: None, under normal conditions of uses.

Exposure Limits
OSHA PEL (United States, 2002). Notes:
TWA: 5 mg/m3 8 hour(s). Form: Respirable dust
TWA: 15 mg/m3 8 hour(s). Form: Total dust

Consult local authorities for acceptable exposure limits.

Section 9. Physical and Chemical Properties
Physical State and
Appearance
Color
Odor
Molecular Weight
Molecular Formula
pH (1% Soln/Water)

: Solid.
:
:
:
:
:

Multiple.
Acrylic. (Slight.)
Not applicable.
Not applicable.
Not applicable.

Continued on Next Page

Page: 3/5

Masking Tape
Boiling/Condensation Point
Melting/Freezing Point
Specific Gravity
Vapor Pressure
Vapor Density
Volatility
Odor Threshold
Evaporation Rate
VOC
Viscosity
LogKow
Solubility

:
:
:
:
:
:
:
:
:
:
:
:

Not available.
130.06 to 145.06°C (266.1 to 293.1°F) based on data for: Polyethylene.
1.1 (Water = 1)
Not available.
Not available.
0% (v/v).
Not available.
Not available.
0 (%)
Not available.
Not available.
Insoluble in cold water, hot water.

Section 10. Stability and Reactivity
Stability and Reactivity
Conditions of Instability
Incompatibility with
Various Substances
Hazardous Decomposition
Products
Hazardous Polymerization

: The product is stable.
: Not available.
: Not considered to be reactive.
: Not available.
: Will not occur.

Section 11. Toxicological Information
Chronic Effects on Humans

: CARCINOGENIC EFFECTS: Classified None. by NIOSH [Polyethylene]. Classified 3 (Not classifiable for
human.) by IARC [Polyethylene].
: Non-irritant for skin. Non-sensitizer for skin. Non-irritating to the eyes.

Other Toxic Effects on
Humans
Special Remarks on Toxicity : Not available.
to Animals
Special Remarks on Chronic : Not available.
Effects on Humans
Special Remarks on Other
Toxic Effects on Humans

: Not available.

Section 12. Ecological Information
BOD and COD
Biodegradable/OECD
Mobility
Products of Degradation
Toxicity of the Products of
Biodegradation
Special Remarks on the
Products of Biodegradation

:
:
:
:
:

Not available.
Not available.
Not available.
These products are carbon oxides (CO, CO2) and water.
The product itself and its products of degradation are not toxic.

: Not available.

Section 13. Disposal Considerations
Waste Information

: Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Consult your local or regional authorities.

Continued on Next Page

Page: 4/5

Masking Tape

Section 14. Transport Information
Regulatory Information

UN number

Proper shipping name

Class

Packing
Group

United States (DOT)

Not regulated.

-

-

-

-

IMDG Code

Not regulated.

-

-

-

-

IATA-DGR Class

Not regulated.

-

-

-

-

NAERG

Label

Additional
information

: Not applicable.

Section 15. Regulatory Information
HCS Classification
U.S. Federal Regulations

: Not controlled under the HCS (United States).
: TSCA 8(b) inventory: All components listed.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: No products were found.
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No products were found.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean air act (CAA) 112 accidental release prevention: No products were found.
Clean air act (CAA) 112 regulated flammable substances: No products were found.
Clean air act (CAA) 112 regulated toxic substances: No products were found.

SARA 313
Form R - Reporting
Requirements

: No products were found.

Supplier Notification

: No products were found.

State Regulations

:
California prop. 65: No products were found.

Section 16. Other Information
Label Requirements

: USE WITH CARE.

Hazardous Material
Information System
(U.S.A.)

Health
Fire Hazard
Reactivity
Personal Protection

0
1
0
C

National Fire
Protection
Association
(U.S.A.)

Health

0

1

Fire Hazard

0

Reactivity
Specific Hazard

References

: - 29CFR Part1910.1200 OSHA MSDS Requirements. - 49CFR Table List of Hazardous Materials, UN#,
Proper Shipping Names, PG. ANSI Z400.1, MSDS Standard, 2001. -Manufacturer's Material Safety Data
Sheet.

Responsible Name
Date of printing

:
:
:
:
:

Date of issue
Date of Previous Issue
Version

Kemika XXI Inc. +1-450-435-7475
2004-10-28.
2004-10-24.
No Previous Validation.
1

Notice to Reader

Continued on Next Page

Masking Tape

Page: 5/5

To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its
subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should
be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Page 1 of 6

Material
Safety
Data
Sheet

24 Hour Emergency Phone Numbers:
Medical: 1-800-327 -3874
1-513-558-5111
Transportation:
1-800-535-5053
1-352-323-3500

NOTE: National Response Center emergency numbers to be used only in the
event of chemical emergencies involving a spill, leak, fire, exposure or
accident involving chemicals.

IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of this
product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with requirements
of this standard. All abbreviated terms used in this MSDS are further described in Section 16.

Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en español a su solicitud.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.

Product Name:
Product UPC
Number:
Product Use/Class:
Manufacturer:

DAP WELDWOOD Multi-Purpose Floor Covering
Adhesive
7079800144, 7079800142, 7079800141, 7079800140,
7079872054, 7079872052, 7079872049
Latex Floor Covering Adhesive

Revision Date:

03/07/2005

Supercedes:

02/17/1999

MSDS Number:

00030807001

DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327 -8477 (non-emergency matters)

Section 2 - Composition / Information On Ingredients
Chemical Name
CASRN
Kaolin
1332-58-7
Petroleum hydrocarbon oil 64742-52-5
Urea
57-13 -6
Ethylene glycol
107-21-1
Titanium dioxide
13463-67-7
4-Vinylcyclohexene
100-40-3

WT%
15-40
10-30
1-5
1-5
0.1-1.0
<0.0006

ACGIH TWA
2 MGM3
N.E.
N.E.
N.E.
10 MGM3
0.1 PPM

ACGIH STEL
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.

ACGIH CEIL
N.E.
N.E.
N.E.
100 MGM3
N.E.
N.E.

OSHA TWA
N.E.
N.E.
N.E.
N.E.
15 MGM3
N.E.

OSHA STEL
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.

OSHA CEIL
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.

Skin
No
No
No
No
No
No

Exposure Notes:
Important:

Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary between

states.

Note:

An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent necessary
under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work practices

Section 3 - Hazards Identification
Emergency Overview: A white to off-white paste with a very slight ammonia odor. WARNING! May cause irritation to the

Page 2 of 6
respiratory tract. Harmful or fatal if swallowed. May cause eye, skin, nose, throat and respiratory tract irritation. This product
contains ethylene glycol.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: May cause eye irritation.
Effects Of Overexposure - Skin Contact: May cause skin irritation.
Effects Of Overexposure - Inhalation: Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous
membranes). Vapors may be irritating to eyes, nose, throat, and lungs. Prolonged, repeated, or high exposures may cause
weakness and depression of the central nervous system.
Effects Of Overexposure - Ingestion: If ingested, may cause vomiting, diarrhea, and depressed respiration. Aspiration of
material into the lungs due to vomiting can cause chemical pneumonitis, which can be fatal.
Effects Of Overexposure - Chronic Hazards: Ethylene Glycol may cause kidney and liver damage upon prolonged and
repeated overexposures. Studies have shown that repeated inhalation of ethylene glycol has produced adverse cardiovascular
changes in laboratory animals. Ethylene glycol has been shown to cause birth defects in laboratory animals. Prolonged or
repeated contact with skin results in irritation and dermatitis.
Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation
Medical Conditions which May be Aggravated by Exposure: None known.

Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical
attention immediately.
First Aid - Skin Contact: Wash off with soap and water.
First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If continued
breathing difficulty is experienced, get medical attention immediately.
First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
Note to Physician: None.
COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arise from any of the above routes of
entry.

Section 5 - Fire Fighting Measures
Flash Point, F: greater than 200 degrees
Fahrenheit
Method: (Seta Closed Cup)

Lower Explosive Limit, %: Not Established
Upper Explosive Limit, %: Not Established

Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam
Unusual Fire And Explosion Hazards: None known.
Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent)
and full protective gear. Use water spray to cool exposed surfaces.

Page 3 of 6

Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Wet dried
material before scraping up and place into containers.

Section 7 - Handling And Storage
Handling: Do not breathe vapors. Provide fresh air such that chemical odors cannot be detected during use and while drying.
Use in well ventilated area. Construction and repair activities can adversely affect indoor air quality. Consult with occupants or a
representative (i.e. maintenance, building manager, industrial hygienist, or safety officer) to determine ways to minimize impact.
Wash thoroughly after handling. Do not sand, dry sweep, dry scrape, drill, saw, beadblast, mechanically chip, pulverize or
otherwise machine existing resilient flooring, backing, lining felt, or asphaltic "cut -back" adhesives. These products may contain
either asbestos fibers or crystalline silica. Avoid creating dust. Inhalation of such dust is a cancer and respiratory tract hazard.
See current edition of the Resilient Floor Covering Institute's publication "Recommended Work Practices for Removal of
Resilient Floor Coverings", for detailed information and instructions addressed to the task of removing all resilient floor covering
materials. Avoid contact with eyes, skin and clothing.
Storage: Store containers away from excessive heat and freezing. Keep containers tightly closed. Store away from caustics
and oxidizers.

Section 8 - Exposure Controls / Personal Protection
Precautionary Measures: Please refer to other sections and subsections of this MSDS.
Engineering Controls: Provide sufficient general and/or local exhaust ventilation to maintain exposure below recommended
exposure limit. Use only in well-ventilated areas.
Respiratory Protection: A respiratory protection program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must
be followed whenever workplace conditions warrant a respirator's use. Respirator use is not expected to be necessary under
normal conditions of handling. In emergency situations, use of a NIOSH -approved respirator may be required.
Skin Protection: Wear rubber gloves.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: None.
Hygienic Practices: Although this product is not considered an eye irritant, inhalation hazard, or a skin contact hazard under
normal conditions, it is advisable that personnel minimize skin contact, inhalation of vapors and eye contact. Remove and wash
contaminated clothing before re-use.

Section 9 - Physical And Chemical Properties
Boiling Range:
Odor:
Appearance:
Solubility in H2O:
Freeze Point:
Vapor Pressure:
Physical State:

Not Established
Very Slight Ammonia
White to Off-White
Not Established
Not Established
Not Established
Paste

Vapor Density:
Odor Threshold:
Evaporation Rate:
Specific Gravity:
pH:
Viscosity:

Not Established
Not Established
Not Established
1.202
Between 7.0 and 12.0
Not Established

When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally.

Page 4 of 6
(See section 16 for abbreviation legend)

Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Strong oxidizing agents. Strong bases.
Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under normal conditions.

Section 11 - Toxicological Information
Product LD50: Not Established
CASRN
57-13-6
107-21-1
100-40-3

Chemical Name

Product LC50: Not Established
LD50

Urea
Ethylene glycol
4-Vinylcyclohexene

Rat:8471 mg/kg
Rat:4700 mg/kg
16620 mg/kg

LC50

WT%

------------Rat:10876 mg/kg
4000 ppm rat

1-5
1-5
<0.0006

Carcinogenicity:
CAS No.

Chemical Name

13463-67 -7

Titanium dioxide

100-40-3

4-Vinylcyclohexene

14808-60 -7

Silica, crystalline

ACGIH

OSHA

IARC

NTP

WT%

-----

-----

Classification not possible
from current data.

-----

0.1-1.0

-----

Possible carcinogen.

-----

<0.0006

-----

-----

Known carcinogen.

<0.00001

Confirmed animal
carcinogen with unknown
relevance to humans.
Suspected human
carcinogen.

Significant Data with Possible Relevance to Humans: None

Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.

Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local
regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the
owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): none

Section 14 - Transportation Information
DOT Proper Shipping
Name:
DOT Technical Name:
DOT Hazard Class:

None

Packing Group:

N.A.

None
N.A.

Hazard Subclass:
DOT UN/NA Number:

N.A.
None

Page 5 of 6
Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may apply if
shipped via other modes of transportation and/or to non-domestic destinations.

Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet
the following categories:
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund
Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name
Ethylene glycol

CAS Number

WT%

107-21-1

1-5

Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
Chemical Name

CAS Number

5-Chloro-2-methyl-4-isothazoli
2-Methyl-4-isothiazolin-3-one

26172-55 -4
2682-20-4

U.S. State Regulations:
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product:
Chemical Name
Water
Hydrocarbon Petroleum Resin
Butadiene-styrene copolymer

CAS Number
7732-18 -5
Proprietary
Proprietary

WT%
30-60
3-7
3-7

Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%:
Chemical Name
Water
Hydrocarbon Petroleum Resin
Butadiene-styrene copolymer

CAS Number
7732-18 -5
Proprietary
Proprietary

California Proposition 65:
Warning: The following ingredients present in the product are known to the State of California to cause cancer:

WT%
30-60
3-7
3-7

Page 6 of 6

Chemical Name

CAS Number

Definition

Date Listed

WT%

4-Vinylcyclohexene

100-40 -3

Carcinogenic.

Listed: May 1, 1996

<0.0006

Silica, crystalline

14808-60-7

Carcinogenic.

Listed: October 1, 1988

<0.00001

Warning: The following ingredients present in the product are known to the State of California to cause birth defects or other
reproductive harm:
None.

Section 16 - Other Information
HMIS Ratings:
Health: 1

Flammability: 1

VOLATILE ORGANIC COMPOUNDS, GR/LTR: 34.3

Reactivity: 0
LB/GAL: 0.3

Personal Protection: X
WT%: 1.557

REASON FOR REVISION: Periodic Update
Legend:

N.A. – Not Applicable

ACGIH – American Conference of Governmental Industrial Hygienists

N.E. – Not Established

SARA – Superfund Amendments and Reauthorization Act of 1986

N.D. – Not Determined

NJRTK – New Jersey Right-to-Know Law

VOC – Volatile Organic Compound

OSHA – Occupational Safety and Health Administration

PEL – Permissible Exposure Limit

HMIS – Hazardous Materials Identification System

TLV – Threshold Limit Value

NTP – National Toxicology Program

STEL – Short Term Exposure Limit

CEIL – Ceiling Exposure Limit

LD50 – Lethal Dose 50

LC50 – Lethal Concentration 50

F – Degree Fahrenheit

C – Degree Celcius

MSDS – Material Safety Data Sheet

CASRN – The Chemical Abstracts Service Registry Number

DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical values and
not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY PARTICULAR
PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE INFORMATION
HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this document is intended only as a
guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is therefore the
responsibility of the user to (i) review the recommendations with due consideration for the specific context of the intended use and (ii)
determine if they are appropriate.


Page 1 of 7

Hoja
de datos
de la seguridad
de los materiales

Números telefónicos de emergencia las 24 horas:
Emergencias médicas: 1-800-327-3874
1-513-558-5111
Transporte:
1-800-535-5053
1-352-323-3500

NOTA: Los números de emergencia del Centro de Respuesta Nacional s ólo
se deben usar en caso de emergencias químicas que involucren un
derramamiento, incendio, exposici ón o accidente que tengan que ver con
químicos

IMPORTANTE: Lea esta hoja de datos de la seguridad de los materiales antes de manipular o desechar este producto, y entregue esta información a
los empleados, clientes y usuarios de este producto. Este producto está cubierto por la norma de comunicación de riesgos OSHA, y este documento fue
preparado de acuerdo con los requisitos de dicha norma. Todos los términos abreviados utilizados en este documento se describen con más detalles en
la sección 16.

Sección 1 - Información del producto químico/ compañía
Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en español a su solicitud.
On peut demander cette MSDS a la langue Francaise Canadienne.

Nombre de
producto:
Número de UPC del
producto:
Uso/ clase del
producto:

DAP WELDWOOD Multi-Purpose Floor Covering
Adhesive
7079800144, 7079800142, 7079800141, 7079800140,
7079872054, 7079872052, 7079872049
Latex Floor Covering Adhesive

Fabricante:

DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327-8477 (asuntos de no emergencia)

Fecha de
revisión:
Reemplaza a:

03/07/2005
02/17/1999

Número de hoja 00030807001
de datos
(MSDS):

Sección 2 - Composición / Información sobre los Ingredientes
Nombre Químico
Caolín
Destilados (Petróleo), Fracción
Nafténica Pesada Tratada Con
Hidrógeno
Carbamida
Etilen Glicol
Dioxidodetitanio
4-Vinilciclohexeno

CASRN
1332 -58-7

Peso%
15 -40

ACGIH TWA ACGIH STEL ACGIH CEIL
2 MGM3
N.E.
N.E.

64742-52-5

10 -30

N.E.

N.E.

57 -13-6
107-21-1
13463-67-7
100-40-3

1-5
1-5
0.1-1.0
<0.0006

N.E.
N.E.
10 MGM3
0.1 PPM

N.E.
N.E.
N.E.
N.E.

OSHA TWA
N.E.

OSHA STEL
N.E.

OSHA CEIL
N.E.

Piel
No

N.E.

N.E.

N.E.

N.E.

No

N.E.
100 MGM3
N.E.
N.E.

N.E.
N.E.
15 MGM3
N.E.

N.E.
N.E.
N.E.
N.E.

N.E.
N.E.
N.E.
N.E.

No
No
No
No

Notas sobre la exposición:
Importante:

Los niveles de exposición permitidos (PEL) señalados son suministrados por el Dept. del Trabajo de EE.UU., Límites de la norma final OSHA (CFR 29
1910.1000); Estos límites pueden variar de estado a estado.

Nota:

Se debe evitar o reducir al máximo la exposición de la piel de un empleado a substancias que tengan "S Í" en la columna "PIEL" en la tabla anterior, seg ún lo
permitan las circunstancias mediante el uso de guantes, ropa de protecci ón, gafas de seguridad y otros equipos personales de protección, controles de ingeniería o
prácticas de trabajo.

Sección 3 - Identificación de riesgos

Page 2 of 7
Generalidades sobre las emergencias: Un blanco a la pasta de-blanco con un olor muy leve del amoniaco.
¡ADVERTENCIA! Puede causar irritaci ón de las vías respiratorias. Dañino o fatal si se traga. Podría causar irritación de los
ojos, piel, nariz, garganta y tracto respiratorio. Este producto contiene glicol de etileno.
Consulte otras secciones de la hoja de datos de seguridad de los materiales para m ás información detallada.
Efectos de la sobre exposición - Contacto visual: Podr ía causar irritación a los ojos.
Efectos de la sobre exposición - Contacto de la piel: Podría causar irritación de la piel.
Efectos de la sobre exposición - Inhalaci ón: La inhalaci ón puede causar irritación de las vías respiratorias (nariz, boca,
membranas mucosas). Los vapores pueden irritar los ojos, la nariz, la garganta y los pulmones. Las exposiciones prolongadas,
repetidas o elevadas pueden causar debilidad y depresi ón del sistema nervioso central.
Efectos de la sobre exposición - Ingestión: Si se ingiere, podría causar vómito, diarrea y respiración deprimida. La
aspiraci ón del material en los pulmones debido al vómito puede causar neumonitis química, lo que podría ser fatal.
Efectos de la sobre exposición - Riesgos crónicos: El glicol de etileno puede causar daño al riñón e hígado con la sobre
exposición prolongada y repetida. Los estudios han demostrado que la inhalación repetida al glicol de etileno ha producido
cambios cardiovasculares adversos en los animales de laboratorio. Se ha demostrado que el glicol de etileno causa defectos
de nacimiento en animales de laboratorio. El contacto prolongado o repetido con la piel resulta en irritación y dermatitis.
Ruta(s) principal de entrada: Piel el Contacto, Pele la Absorción,Aspiración
Condiciones m édicas que se pueden agravar a causa de la exposición: Ninguno conocido.

Sección 4 - Medidas de primeros auxilios
Primeros auxilios - Contacto visual: En caso de contacto, enjuague los ojos de inmediato con abundante agua por al menos
15 minutos. Obtenga atención médica de inmediato.
Primeros auxilios - Contacto de la piel: Lavar con agua y jabón.
Primeros auxilios - Inhalaci ón: Si se inhala, salga al aire fresco. Si se dificulta la respiración, abandone el área para obtener
aire fresco. Si se experimenta dificultad continua para respirar, busque atenci ón médica de inmediato.
Primeros auxilios - Ingestión: Si se traga, NO PROVOQUE EL VÓMITO. Obtenga atención médica de inmediato.
Nota para el médico: Sin informaci ón
COMENTARIOS: Llame para emergencias médicas al 1 -800-327-3874 si surgiera cualquier irritación o complicación de
cualquiera de las rutas de entrada anteriores.

Sección 5 - Medidas para combatir incendios
Punto de inflamaci ón, F: Más que 200 grados
Fahrenheit
Método: ( Seta Cerró Copa)

Límite explosivo menor, %: No Establecido
Límite explosivo mayor, %: No Establecido

Medios para extinguir: Bióxido de carbono, Seque Sustancia Química, Espuma
Riesgos inusuales de incendio y explosi ón: Ninguno conocido.
Procedimientos especiales para combatir incendios: Use un aparato para respiraci ón auto-contenida con demanda de

Page 3 of 7
presi ón (aprobado por el Instituto NIOSH o equivalente) y equipo completo de protecci ón. Use rociador de agua para enfriar las
superficies expuestas.

Sección 6 - Medidas en caso de emisión accidental
Pasos a seguir en el caso de emisión o derramamiento de materiales: Use el equipo de protección correcto según lo
especifica la Secci ón 8. Moje el material seco antes de raspar y coloque en contenedores.

Sección 7 - Manejo y almacenamiento
Manejo: No respire los vapores. Suministre aire fresco de manera que los olores de los químicos no se puedan detectar
durante el uso y mientras se seca. Usar en un área bien ventilada. Las actividades de construcci ón y de reparaciones pueden
afectar de manera adversa la calidad del aire en interiores. Consulte con los ocupantes o un representante (es decir,
mantenimiento, administrador de construcción, higienista industrial, u oficial de seguridad) para determinar las formas de
reducir el impacto.
Lave a fondo después de manipular. No lije, barra en seco, raspe en seco, perfore, asierre, pula, corte mecánicamente,
pulverice o una acci ón similar los revestimientos elásticos existentes, refuerzos, fieltro de forro, o adhesivos asfálticos "cut back". Estos productos pueden contener ya sea fibras de asbestos o sílice cristalino. Evite crear polvo. La inhalación de este
polvo es un riesgo de cáncer y de infección del tracto respiratorio. Consulte la edici ón actual de la publicaci ón del Instituto
Resilient Floor Covering: “Pr ácticas de trabajo recomendadas para retirar los revestimientos elásticos", para informaci ón e
instrucciones detalladas para la tarea de retirar todos los materiales de revestimiento elástico. Evite el contacto con los ojos, la
piel y la ropa.
Almacenamiento: Almacene los contenedores lejos del calor y congelamiento excesivos. Manténgase el recipiente bien
cerrado. Almacene lejos de substancias cáusticas y oxidantes.

Sección 8 - Controles de la exposición/ Protección personal
Medidas de precaución: Refiérase por favor a otras secciones y subdivisiones de este MSDS.
Controles de ingeniería: Ofrezca ventilación de escape general y/o local suficiente para mantener la exposición debajo del
límite recomendado. Utilícese solo en zonas bien ventiladas.
Protecci ón respiratoria: Se debe seguir un programa de protecci ón respiratoria que cumpla con los requisitos de OSHA
1910.134 y ANSI Z88.2 cada vez que las condiciones del lugar de trabajo exijan el uso de un respirador. No es de esperar que
sea necesario usar un aparato de respiraci ón bajo condiciones normales de manejo. En situaciones de emergencia, puede que
se requiera el uso de un aparato de respiraci ón aprobado por el NIOSH.
Protecci ón de la piel: Usar guantes de goma.
Protecci ón de la visión: Gafas de seguridad con protectores laterales.
Otro equipo de protección: Ninguno.
Prácticas higiénicas: No obstante este producto no se considera un irritante para los ojos, riesgo de inhalación o riesgo de
contacto con la piel bajo condiciones normales, se recomienda que el personal reduzca el contacto con la piel, la inhalación de
vapores y el contacto con los ojos. Quitar y lavar la ropa contaminada antes de reutilizar.

Sección 9 - Propiedades físicas y químicas
Rango de ebullición:

No Establecido

Densidad del vapor:

No Establecido

Page 4 of 7
Olor:

Amoniaco muy Leve

Umbral de olor:

No Establecido

Aspecto:

Blanco a De-Blanco

Índice de evaporación:

No Establecido

Solubilidad en H2O:

No Establecido

Gravedad específica:

1.202

Punto de congelamiento:

No Establecido

pH:

Entre 7,0 y 12,0

Presi ón del vapor:

No Establecido

Viscosidad:

No Establecido

Estado físico:

Pasta

(Ver sección 16 para la leyenda de las abreviaturas)

Sección 10 - Estabilidad y reactividad
Condiciones a evitar: Calentamiento y congelamiento excesivos.
Incompatibilidad: agentes oxidantes fuertes bases fuertes
Productos de descomposición peligrosa: Productos de descomposición normal, es decir, COx, NOx.
Polimerización peligrosa: No ocurrirá polimerización peligrosa bajo condiciones normales.
Estabilidad: Estable en condiciones normales

Sección 11 - Información toxicológica
LD50 del producto: No Establecido
CASRN
Nombre Químico
57-13-6
107-21-1
100-40-3

LC50 del producto: No Establecido
LD50
LC50

Carbamida
Etilen Glicol
4-Vinilciclohexeno

Rat:8471 mg/kg
Rat:4700 mg/kg
16620 mg/kg

------------Rat:10876 mg/kg
4000 ppm rat

Peso%
1-5
1-5
<0.0006

Carcinogenicidad:
Número
CAS

Nombre Químico

13463-67 -7

Dioxidodetitanio

100-40-3

4-Vinilciclohexeno

14808-60 -7

Silicecristalina

ACGIH

OSHA

IARC

NTP

Peso%

-----

-----

Clasificación no posible
de datos actuales.

-----

0.1-1.0

-----

Cancerígeno posible.

-----

<0.0006

-----

-----

Cancerígeno conocido.

<0.00001

Cancerígeno animal
confirmado con la
aplicabilidad desconocida a
humanos.
Cancerígeno humano
sospechado.

Datos significativos con posible relevancia para los humanos: Ninguno

Sección 12 - Información ecológica
Información ecológica: No se conocen ni esperan daños ecológicos bajo uso normal.

Sección 13 - Información sobre desechos
Información sobre desechos: Deseche los materiales de acuerdo con todas las normas federales, estatales y locales. Las
normas/ restricciones estatales y locales son complejas y pueden diferir de las normas federales. La responsabilidad de
eliminar los desechos correctamente recae en el propietario de los desechos.

Page 5 of 7
Código de desechos de EPA en caso de desecho (CFR 40 Sección 261): Ninguno

Sección 14 - Información sobre transporte
Nombre correcto para envío a
DOT:
Nombre técnico para DOT:
Clase de riesgo para DOT:

Ninguno

Grupo de empaque:

No Aplicable

Ninguno
No Aplicable

Sub-clase de riesgo:
Número UN/NA para DOT:

No Aplicable
Ninguno

Nota: La información del envío proporcionada es aplicable para el transporte doméstico del suelo sólo. Categorizaci ón diferente
puede aplicar si enviado vía otros modos del transporte y/o a destino no-domésticos.

Sección 15 - Información reglamentaria
Categoría de riesgo CERCLA - SARA:
Este producto ha sido revisado según las categorías de riesgo de EPA promulgadas según las secciones 311 y 312 de la Ley
de enmienda y reautorización de fondos especiales de 1986 (SARA, por sus iniciales en inglés, Título III) y se considera, según
las definiciones correspondientes, que cumple con las siguientes categorías:
Sección 313 de la ley SARA:
Este producto contiene las siguientes substancias sujeto a los requisitos de reporte de la sección 313 del título III de la ley
SARA de 1986 y 40 CFR parte 372:
Nombre Químico
Etilen Glicol

Número CAS

Peso%

107-21-1

1-5

Ley para el control de substancias tóxicas:
Todos ingredientes en este producto son o en lista de inventario de TSCA, o de otro modo exima.
Este producto contiene las siguientes substancias químicas de acuerdo con los requisitos de reporte de la ley TSCA 12(B) si es
exportado desde los Estados Unidos:
Nombre Químico

Número CAS

5-Chloro-2-Methyl-4-Isothazoli
2-Methyl-4-Isothiazolin-3-One

26172-55 -4
2682-20-4

Regulaciones estatales de EE.UU.:
Ley del Derecho a saberde New Jersey:
Los siguientes materiales no representan peligro, pero están entre los primeros cinco componentes de este producto:
Nombre Químico
Agua
Hydrocarbon Petroleum Resin
Copolymer De Estireno De Butadiene

Número CAS
7732-18 -5
Propietario
Propietario

Peso%
30-60
3-7
3-7

Ley del Derecho a saber de Pennsylvania:
Los siguientes ingredientes no peligrosos están presentes en el producto en una proporción mayor a 3%:
Nombre Químico

Número CAS

Peso%

Page 6 of 7
Agua
Hydrocarbon Petroleum Resin
Copolymer De Estireno De Butadiene

7732 -18-5
Propietario
Propietario

30-60
3-7
3-7

Propuesta 65 de California:
Advertencia: Los siguientes ingredientes presentes en el producto son conocidos para el Estado de California por causar
cáncer:
Nombre Químico
4-Vinilciclohexeno
Ester Etilico Del Acido 2 -Propenoico
Silicecristalina

Número CAS
100-40 -3
140-88 -5
14808-60-7

Definición

Fecha Listó

Peso%

Cancerígeno.
Cancerígeno.
Cancerígeno.

Listed: May 1, 1996
Listed: July 1, 1989
Listed: October 1, 1988

<0.0006
<0.0001
<0.00001

Advertencia: Los siguientes ingredientes presentes en el producto son conocidos para el Estado de California por causar
defectos de nacimiento u otros daños reproductivos:

Ninguno.

Sección 16 - Otra información
Índices HMIS:
Salud: 1

Inflamabilidad: 1

Reactividad: 0

COMPONENTES ORGÁNICOS VOLÁTILES, GR/LTR: 34.3 LB/GAL: 0.3

Protecci ón personal: X
WT%: 1.557

RAZÓN DE LA REVISIÓN: Periódico Actualiza
Leyenda:

N.A. - No aplica

ACGIH - Conferencia Americana de Higienistas Industriales gubernamentales

N.E. - No establecido

SARA - Ley Ley de enmienda y reautorizaci ón de fondos especiales de 1986 (SARA)

N.D. - No determinado

NJRTK - Ley del Derecho a saber de New Jersey

VOC - Componente orgánico volátil

OSHA - Administración de la seguridad y salud ocupacional

PEL - Límites permitidos de exposición

C - Grados centígrados

TLV - Valor del límite umbral

NTP - Programa nacional de toxicología

STEL - Límite de exposición a corto plazo

CEIL - Límite máximo de exposici ón

LD50 - Dosis letal 50

LC50 - Concentración letal 50

HMIS - Sistema de identificación de materiales peligrosos

MSDS - Hoja de datos de la seguridad de los materiales

CASRN - Número de registro de servicios de abstractos químicos

F - Grados Fahrenheit

DAP cree que los datos y las declaraciones contenidos en el presente son exactos hasta la fecha. Se ofrecen de buena fe como valores típicos
y no como las especificaciones del producto. NO SE OFRECE NINGUNA GARANT ÍA DE COMERCIABILIDAD, IDONEIDAD
PARA UN PROPÓSITO EN PARTICULAR O CUALQUIER OTRA GARANTÍA, EXPRESA O IMPLÍCITA, CON RESPECTO A
LA INFORMACIÓN SUMINISTRADA EN EL PRESENTE O DEL PRODUCTO AL CUAL LA INFORMACIÓN SE REFIERE.
Dado que este documento tiene la intención de ser una guía únicamente para el uso correcto y el manejo preventivo del producto de la
referencia por parte de personas correctamente entrenadas, es responsabilidad del usuario (i) revisar las recomendaciones con especial
consideración al contexto específico del uso que se pretende y (ii) determinar si son correctas.

Page 7 of 7


Page 1 of 7

Fiche
signalétique

24 heures – Numéros de téléphone en cas
d’urgence:
Urgence médicale:
1-800-327 -3874
1-513-558 -5111
Urgence transport:
1-800-535 -5053
1-352-323 -3500

NOTE: Les numéros de téléphone en cas d’urgence doivent être utilisés
uniquement lors de déversement, de fuite, d’incendie, d’exposition ou
d’accident impliquant des produits chimiques.

IMPORTANT: Lire attentivement cette fiche signalétique avant de manipuler ou de disposer de ce produit. Remettre ces informations aux employés,
clients et utilisateurs de ce produit. Ce produit est régit sous la gouverne de l’OSHA, Communication de renseignements à l’égard de matières
dangereuses, et ce document a été préparé pour répondre aux exigences de ces standards. Les significations pour toutes les abréviations utilisées dans
cette fiche signalétique sont décrites à la Section 16.

Section 1 – Identification du produit et de la compagnie
This MSDS is offered in English upon request.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.

Nom du produit:
Numéro UPC:
Utilisation du
produit/Classe:
Fabricant:

DAP WELDWOOD Multi-Purpose Floor Covering
Adhesive
7079800144, 7079800142, 7079800141, 7079800140,
7079872054, 7079872052, 7079872049
Latex Floor Covering Adhesive

Date de r évision: 03/07/2005
Date
02/17/1999
d’abrogation:
Numéro de fiche: 00030807001

DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327 -8477 ( Pour toute information non urgente)

Section 2 - Composition / Ingrédients dangereux
Nom Chimique
Kaolin
Distillat naphténique lourd hydrotraité
Urée
Éthylène glycol
Dioxyde de titane
4-Vinylcyclohexne

CASRN
1332 -58-7
64742-52-5
57-13-6
107-21 -1
13463-67-7
100-40 -3

Poids%
15-40
10-30
1-5
1-5
0.1-1.0
<0.0006

ACGIH TWA ACGIH STEL ACGIH CEIL
2 MGM3
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
100 MGM3
10 MGM3
N.E.
N.E.
0.1 PPM
N.E.
N.E.

OSHA TWA
N.E.
N.E.
N.E.
N.E.
15 MGM3
N.E.

OSHA STEL
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.

OSHA CEIL Peau
N.E.
Non
N.E.
Non
N.E.
Non
N.E.
Non
N.E.
Non
N.E.
Non

Notes concernant l’exposition:
Important:

Les limites d’exposition permises (LEP) décrites proviennent du Department of Labor des États-Unis, règlement final concernant les valeurs d’exposition
moyennes pondérées de l’OSHA
(CFR 29 1910.1000); ces limites peuvent varier selon les états.

Note:

Prendre tous les moyens selon les circonstances afin de prévenir ou réduire toute exposition de la peau des employés aux substances portant la mention «OUI»
dans la colonne «PEAU» du tableau ci-dessus. Utiliser des gants, une combinaison, des lunettes étanches, tout autre équipement de protection personnel adéquat, les
contrôles techniques et les pratiques appropriées au type de travail.

Section 3 – Identification des dangers

Page 2 of 7
Urgences générales: Un blanc à la pâte de-blanc avec une odeur d'ammoniaque tr ès insignifiante. AVERTISSEMENT ! Peut
provoquer une irritation des voies respiratoires. Nocif ou mortel si ingéré. Peut causer une irritation des yeux, de la peau, du
nez, de la gorge et des voies respiratoires. Ce produit contient du glycol d'éthyl ène.
Consulter les autres sections de cette fiche signalétique pour des informations plus détaillées.
Effets de surexposition – Contact oculaire: Peut causer une irritation des yeux.
Effets de surexposition – Contact cutané: Peut causer une irritation de la peau.
Effets de surexposition – Inhalation: L'inhalation de ce produit peut provoquer l'irritation des voies respiratoires (nez,
bouche, muqueuses). Les vapeurs peuvent être irritantes pour les yeux, le nez, la gorge et les poumons. L'exposition
prolongée, ou répétée, ou à de fortes concentrations peut provoquer un affaiblissement et une dépression du système nerveux
central.
Effets de surexposition – Ingestion: En cas d’ingestion, peut causer des vomissements, de la diarrhée et une diminution de
la capacité pulmonaire. L’aspiration de mat ériau dans les poumons lors de vomissements peut causer une pneumonie chimique
qui peut être mortelle.
Effets de surexposition – Dangers chroniques: Une exposition excessive et répétée à l’éthyl ène glycol peut causer des
lésions aux reins et au foie. Les études en laboratoire menées sur des animaux ont démontré que l’inhalation r épétée
d’éthyl ène glycol cause des changements néfastes du syst ème cardiovasculaire. Lors d’études en laboratoire sur les animaux,
il a été démontré que l ’éthyl ène glycol cause des anomalies congénitales. Un contact excessif et répété avec la peau peut
causer une irritation ou une dermatite.
Voie(s) d’absorption: Peau le Contact,

L'Absorption de peau, l'Inhalation

Problèmes médicaux aggravés lors d’exposition au produit : Aucune connue.

Section 4 – Premiers soins
Premiers soins – Contact oculaire: En cas de contact avec les yeux, rincer abondamment avec de l ’eau pendant au moins
15 minutes. Obtenir des soins médicaux immédiatement.
Premiers soins – Contact cutané: Laver avec de l'eau et du savon.
Premiers soins – Inhalation: En cas d’inhalation, transporter la personne exposée à l’air frais. Si elle a de la difficulté à
respirer, quitter les lieux afin d’obtenir de l’air frais. Si la difficulté à respirer persiste, obtenir des soins médicaux
immédiatement.
Premiers soins – Ingestion: En cas d’ingestion, NE PAS FAIRE VOMIR. Obtenir des soins m édicaux immédiatement.
Note au médecin: Pas d'information.
COMMENTAIRES: En cas d’apparition d’une irritation ou de complications suite à une exposition au produit, communiquer
immédiatement avec l’urgence m édicale au 1-800-327-3874.

Section 5 – Mesures de protection en cas d’incendie
Point d’éclair, º F ( º C ): Plus grand que 200
degrés Fahrenheit
Méthode: ( Seta A Fermé la Tasse)

Limite d ’explosibilité inférieure, %: Pas Etabli
Limite d ’explosibilité supérieure, %: Pas Etabli

Moyens d’extinction: Dioxyde de carbone, Sécher Chimique, Mousse

Page 3 of 7
Risques particuliers d’explosions ou d’ignition:

Aucun connu.

Procédures spéciales de lutte contre les incendies: Porter un respirateur autonome à pression d’air (approuvé NIOSH ou
équivalent) et un équipement de protection personnel complet. Utiliser une lance-brouillard afin de refroidir les contenants
expos és.

Section 6 – Mesures en cas de déversement accidentel
Procédures de nettoyage: Porter un équipement de protection personnel approprié tel que spécifié à la Section 8. Humidifier
le matériau sec avant de le gratter puis disposer dans un contenant.

Section 7 – Manutention et entreposage
Manutention: Éviter de respirer les vapeurs. Assurer l’entrée d’air frais de façon à éliminer les odeurs des produits chimiques
pendant l ’utilisation et le temps de séchage. Utilisez dans un espace bien aéré. Les activités de construction et de réparation
peuvent affecter la qualité de l’air à l’intérieur. Vérifier avec les occupants ou un de leurs représentants (responsable de
maintenance, gérant d’édifice, hygiéniste industriel ou responsable de sécurité) afin de déterminer les façons appropriées pour
en diminuer l’impact.
Laver vigoureusement après la manipulation. Ne pas poncer, balayer à sec, gratter à sec, percer, scier, utiliser un jet à billes,
buriner et pulvériser mécaniquement ou à l’aide de tout autre outil les couvre-planchers élastiques, les supports, les blindages
ou les adhésifs d’asphalte dilué existants. Ces produits peuvent contenir de l’amiante ou de la silice cristalline. Éviter de générer
de la poussière. Éviter d’inhaler cette poussi ère, elle est canc érigène et dangereuse pour les voies respiratoires. Pour de plus
amples informations concernant les pratiques d’enlèvement complet des couvre-planchers élastiques, consulter la r écente
édition du bulletin du Resilient Floor Covering Institute; "Le Travail recommand é Pratique pour l'Enlèvement de Couvertures de
Plancher Elastiques". Éviter tout contact avec les yeux, la peau et les vêtements.
Entreposage: Entreposer les contenants loin de la chaleur excessive ou du froid excessif. Conserver le récipient bien fermé.
Entreposer loin des produits caustiques et des agents oxydants.

Section 8 – Contrôles d’exposition / Protection personnelle
Mesures de précaution: S'il vous plaît se référer aux autres sections et aux autres sous -sections de ce MSDS.
Contrôles d’ingénierie: Faire fonctionner au maximum le système de ventilation central et/ou le système d’évacuation local
afin de maintenir le niveau des vapeurs organiques sous les limites d’exposition recommandées. Utiliser seulement dans des
zones bien ventilées.
Protection des voies respiratoires: Un programme de protection respiratoire défini selon les normes de l ’OSHA 1910.134 et
de l’ANSI Z88.2 doit être appliqué à chaque fois que les conditions sur les lieux de travail exigent de porter un respirateur. On
ne s'attend pas à ce qu'un masque soit nécessaire dans les conditions normales de manipulation. En cas de situation
d'urgence, un masque de type agréé par NIOSH peut être nécessaire.
Protection de la peau: Portez des gants en caoutchouc.
Protection des yeux: Lunettes étanches ou lunettes de s écurité avec boucliers latéraux.
Équipements de protection additionnels: Aucun.
Pratiques hygiéniques: Dans des conditions normales d’utilisation, même si ce produit n’est pas considéré ni un irritant pour
les yeux, ni un danger en cas d’inhalation ou de contact avec la peau, il est recommandé que le personnel minimise les risques
de contact avec les yeux et la peau et évite d’inhaler les vapeurs. Enlever et laver les vêtements contaminés avant réutilisation.

Page 4 of 7

Section 9 – Propriétés physiques et chimiques
Point d’ébullition:
Odeur:

Pas Etabli
L'Ammoniaque très Insignifiante

Apparence:

Blanc à De-Blanc

Solubilité dans l’eau (H2O):
Point de congélation:
Pression de vapeur:
État physique:

Pas Etabli
Pas Etabli
Pas Etabli
Pâte

Densité de vapeur:
Limite de détection
olfactive:
Taux d ’évaporation:
Poids spécifique:

Pas Etabli
Pas Etabli

Taux de pH:
Viscosité:

Entre 7,0 et 12,0
Pas Etabli

Pas Etabli
1.202

(Consulter la Section 16 pour conna ître la signification des abréviations))

Section 10 – Stabilité et réactivité
Conditions à éviter: Chaleur excessive ou froid excessif.
Incompatibilité: des oxydants forts des bases fortes
Produits de décomposition dangereux: Produits de d écomposition habituels : oxydes de carbone (COx) et oxydes d’azote
(NOx).
Risque de polym érisation: Aucune polymérisation dangereuse ne surviendra dans des conditions normales d’utilisation.
Stabilité: Stable dans des conditions normales

Section 11 – Propriétés toxicologiques
Produit DL50: Pas Etabli
CASRN
57-13-6
107-21-1
100-40-3

Nom Chimique

Produit CL50: Pas Etabli
LD50

Urée
Éthylène glycol
4-Vinylcyclohexne

Rat:8471 mg/kg
Rat:4700 mg/kg
16620 mg/kg

LC50

Poids%

------------Rat:10876 mg/kg
4000 ppm rat

1-5
1-5
<0.0006

Effets cancérig ènes:
Numéro
CAS

Nom Chimique

13463-67 -7

Dioxyde de titane

100-40-3

4-Vinylcyclohexne

14808-60 -7

Silice cristalline

ACGIH

OSHA

IARC

NTP

Poids%

-----

-----

Classification pas
possible des données
actuelles.

-----

0.1-1.0

-----

Cancérog ène possible.

-----

<0.0006

-----

-----

Cancérogène connue.

<0.00001

Confirmée canc érog ène
animale avec le pertinence
inconnu aux humains.
Présumée cancérogène
humaine.

Données significatives possiblement pertinentes à l’humain: Aucun

Section 12 – Information écologique
Information écologique: Aucune dégradation de l'environnement n'est connue ou prévisible dans les conditions normales
d'utilisation.

Page 5 of 7

Section 13 – Information sur la mise au rebut
Information concernant la mise au rebut: Disposer de ce matériau en respectant les lois fédérales, provinciales et
municipales. Les lois et restrictions provinciales et municipales sont complexes et peuvent différer des lois f édérales. La
responsabilité de la disposition appropriée des déchets appartient au propriétaire des déchets.
Code de mise au rebut de l ’Agence de protection de l’environnement (40 CFR Section 261): Aucun

Section 14 – Étiquetage selon le Ministère des Transports
Nom du produit expédié:
Nom technique:
Classe de danger:

Aucun
Aucun
Pas Applicable

Groupe d’emballage:
Classe de transport:
Numéro UN/NA:

Pas Applicable
Pas Applicable
Aucun

Note : L'information d'expédition fournie est applicable pour le transport de sol domestique seulement. La catégorisation
différente peut s'appliquer si exp édié via les autres modes de et/ou de transport aux destinations non résidentielles.

Section 15 – Information sur les règlements
CERCLA - Catégories de dangers selon le SARA:
Ce produit a été revu en conformité avec les «Catégories de dangers» établies par l’Agence de protection de l’environnement et
promulguées aux Sections 311 et 312 du Superfund Amendment and Reauthorization Act de 1986 (SARA Titre III). Selon les
définitions applicables, il est considéré répondre aux cat égories suivantes :
SARA SECTION 313 :
Ce produit contient les substances suivantes assujetties aux normes de déclaration de la Section 313, du Titre III de la
Superfund Amendments and Reauthorization Act de 1986 et du 40 CFR partie 372 :
Nom Chimique
Éthylène glycol

Numéro CAS
107-21-1

Poids%
1-5

LOI SUR LE CONTRÔLE DES SUBSTANCES TOXIQUES:
Tous ingrédients dans ce produit sont ou sur la liste d'inventaire de TSCA, ou autrement exempter.
Ce produit contient les substances chimiques suivantes à déclarer selon les normes TSCA 12(B) si export é à l’extérieur des
États-Unis:
Nom Chimique
Numéro CAS
5-Chloro-2-Methyl-4-Isothazoli
2-Methyl-4-Isothiazolin-3-One

26172-55 -4
2682-20-4

Lois particulières selon les états aux États-Unis:
NEW JERSEY RIGHT-TO-KNOW :
Les substances suivantes sont non-dangereuses mais sont comptées parmi les 5 principaux ingrédients composant ce produit:
Nom Chimique
Eau
Hydrocarbon Petroleum Resin
Copolymère de styrène et de butadiène

Numéro CAS
7732-18 -5
De propriété
De propriété

Poids%
30-60
3-7
3-7

Page 6 of 7
PENSYLVANIA RIGHT-TO-KNOW:
Les substances suivantes sont non-dangereuses mais sont présentes à plus de 3% dans ce produit:
Nom Chimique
Numéro CAS
Eau
Hydrocarbon Petroleum Resin
Copolymère de styrène et de butadiène

Poids%

7732-18 -5
De propriété
De propriété

30-60
3-7
3-7

PROPOSITION 65 DE CALIFORNIE:
AVERTISSEMENT ! Les produits chimiques list és ci-dessous et contenus dans ce produit sont reconnus par l’État de la
Californie pour causer le cancer:
Nom Chimique
Numéro CAS
Définition
Dater Enuméré
Poids%
4-Vinylcyclohexne
Silice cristalline

100-40 -3
14808-60-7

Cancérog ène.
Cancérog ène.

Listed: May 1, 1996
Listed: October 1, 1988

<0.0006
<0.00001

AVERTISSEMENT ! Les produits chimiques list és ci-dessous et contenus dans ce produit sont reconnus par l’État de la
Californie pour causer le cancer, des anomalies congénitales ou d’autres problèmes reliés à la reproduction:
Aucun.

Section 16 – Autres informations
Classification des
dangers:
Santé: 1

Inflammabilité: 1

COMPOSÉ ORGANIQUE VOLATIL, G/LITRE: 34.3

Réactivité: 0
LB/GALLON: 0.3

Protection personnelle: X
POIDS %: 1.557

RAISONS DE RÉVISION: Mise à jour p ériodique
Légende:

N.A. – Non applicable

ACGIH – American Conference of Governmental Industrial Hygienists

N.É. – Non établi

SARA – Superfund Amendments and Reauthorization Act de 1986

N.D. – Non déterminé

NJRTK – New Jersey Right-to-Know Law

VOC – Composé organique volatil

OSHA – Occupational Safety and Health Administration

PEL – Limite d’exposition permise

HMIS – Hazardous Materials Identification System

TLV – Limite tolérable d’exposition

TWA – Valeur d’exposition moyenne pondérée

NTP – National Toxicology Program

F – Degré Fahrenheit

STEL – Limite d’exposition à court terme

C – Degré Celcius

LD50 – Dose létale 50

LC50 – Concentration létale 50

CASRN – Numéro enregistré selon le Chemical Abstracts Service
CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act

DAP croit que les données et renseignements stipulés dans cette fiche signal étique sont précis à la date de rédaction de cette fiche. Ces
données sont offertes en toute bonne foi et représente des valeurs standard sans toutefois être des sp écifications du produit. AUCUNE
GARANTIE SUR LA QUALITÉ MARCHANDE, GARANTIE D’APTITUDE POUR AUCUN TYPE D’EMPLOI PARTICULIER
OU TOUTE AUTRE FORME DE GARANTIE N’EST EXPRESSÉMENT OU IMPLICITEMENT OFFERTE EN REGARD DES
INFORMATIONS FOURNIES DANS CETTE FICHE OU DES INFORMATIONS RELATIVES AU PRODUIT. Cette fiche est
produite uniquement à titre de guide pour les personnes form ées à cet effet afin qu’elles puissent appliquer les procédures appropriées de
manutention auxquelles le produit réfère. Toutefois, c’est la responsabilité chaque utilisateur de revoir les recommandations selon le contexte
spécifique de l’utilisation prévue et de déterminer si ces proc édures sont appropriées.

Page 7 of 7



MATERIAL SAFETY DATA SHEET
PRODUCT NAME: Roberts 7032 Cove Base Adhesive
Roberts MSDS Code #: 7032C
PRODUCT USES: For installing vinyl and rubber cove base

W.H.M.I.S. CLASSIFICATION: NON-CONTOLLED
V.O.C. CONTENT: 88g/L

SECTION I - MANUFACTURER IDENTIFICATION
MANUFACTURER'S NAME: ROBERTS COMPANY CANADA LTD.
ADDRESS: 2070 Steeles Ave. Bramalea, Ontario L6T 1A7
24 HOUR (CANUTEC) PHONE:
(613) 996-6666
DATE REVISED:
December 01/06
SECTION II - HAZARDOUS INGREDIENTS INFORMATION
COMPONENT
APPROX. %
MINERAL SPIRITS
5-10

UN#
1256

SECTION III – PHYSICAL DATA
BOILING POINT: 100° C FREEZING POINT: N/A
VAPOUR DENSITY (AIR=1):
4-5
VAPOUR PRESSURE (MM OF MERCURY):
Min. spirits 2 @ 20ºC
SOLUBILITY IN WATER:
Miscible
APPEARANCE AND ODOUR:
White, soft buttery paste, mild solvent odour.

NAME OF PREPARER: Technical Dept.
INFORMATION PHONE: (905) 791-4444
SOURCES USED: Raw material supplier M.S.D.S.
CAS#
8052-41-3

LD50

LC50
1,400 PPM 8HR., RAT

SPECIFIC GRAVITY (H20=1): 1.17 pH: 9.5 – 10.5
EVAPORATION RATE (BUTYL ACETATE=1): Slower
EVAPORATION RATE (ETHYL ACETATE=1): Slower
PERCENT VOLATILE: 46
ODOUR THRESHOLD (PPM): Not available

SECTION IV - FIRE AND EXPLOSION DATA
FLASHPOINT (specify method):
Over 200ºF
METHOD USED: P.M.C.C.
IMPACT SENSITIVITY: Insensitive
FLAMMABLE LIMITS (% BY VOLUME):
LOWER: 0.8-0.9 UPPER: 7
SENSITIVITY TO STATIC DISCHARGE: Vapours may be
FIRE EXTINGUISHING MEDIA: Foam, CO2, Dry Chemical
AUTO IGNITION TEMP: N/A
TDG FLAMMABILITY CLASSIFICATION: Not regulated.
SPECIAL FIRE-FIGHTING PROCEDURES: Poses minimal fire hazard. Must be heated substantially. Self-contained breathing apparatus should be worn for fires involving this product.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Flammable vapours, heavier than air, may be able to collect in confined spaces and pose a hazard.
SECTION V - REACTIVITY DATA
STABILITY:
Stable
INCOMPATIBILITY (Materials to avoid): Strong oxidizing agents
HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO2, and Hydrocarbons upon combustion.
HAZARDOUS POLYMERIZATION: Will not occur
SECTION VI – TOXICOLOGICAL PROPERTIES
SKIN CONTACT
X
SKIN ABSORPTION

CONDITIONS TO AVOID: Excessive Heat
CONDITIONS TO AVOID: None

ENTRY ROUTE TABLE
EYE CONTACT
X
INHALATION ACUTE

X

INHALATION CHRONIC

INGESTION

X

EFFECTS OF ACUTE EXPOSURE TO MATERIAL: Overexposure to vapours can cause eye, nose, throat irritation, dizziness, drowsiness, headache feelings of drunkenness, nausea, vomiting.
Massive overexposure can cause respiratory failure. Ingestion causes similar symptoms. Aspiration causes severe pneumonitis. Product is eye and skin irritant.
EFFECTS OF CHRONIC EXPOSURE TO MATERIAL: Prolonged or repeated contact with skin may cause drying and defatting of skin and dermatitis. Although unlikely to occur, overexposure to
vapours may cause corneal damage, photophobia. In rare cases, severe overexposure may sensitize heart muscles causing heart arrhythmia.
LD50 (SPECIFY SPECIES & ROUTE):
Not available
SENSITIZING CAPACITY:
May sensitize heart muscles. See above.

LC50 (SPECIFY SPECIES):
Not available
CARCINOGENICITY:
None

EXPOSURE LIMIT:
TLV-TWA, PPM MINERAL SPIRITS, 100
REPRODUCTIVITY EFFECTS:
None known

IRRITANCY:
Eye, nose, throat and skin irritant
SYNERGISTIC MATERIALS:
None known

SECTION VII – PREVENTATIVE MEASURES
RESPIRATORY PROTECTION (SPECIFY TYPE): Not required under normal conditions of use. If TLV is to be exceeded, employ an approved NIOSH/MSHA chemical cartridge respirator with
organic vapour cartridge. Consult your safety equipment supplier for respirator requirements.
VENTILATION: General dilution ventilation to keep vapours below TLV.
PROTECTIVE GLOVES: Solvent resistant gloves should be worn.
EYE PROTECTION: Goggles / glasses with side shields
OTHER PROTECTIVE EQUIPMENT: None required.
SPILL PROCEDURES: Provide adequate ventilation. Mechanically collect. Wash area with water. Prevent from entering sewers or waterways. Spilled material may cause slippery conditions.
Promptly report significant spills to appropriate authorities. Consult local regulations.
WASTE DISPOSAL METHOD: Destroy by incineration at an approved facility. Dried material only may be landfilled. Consult local regulations.
STORAGE & HANDLING PRECAUTIONS: Store in ventilated area as close to 70ºF as possible.
OTHER PRECAUTIONS: Keep containers closed when not in use. Keep out of reach of children.
SECTION VIII – FIRST AID MEASURES
INHALATION:
EYES:
SKIN:
INGESTION:

Remove to fresh air. If not breathing, trained personnel should administer artificial respiration. Obtain medical attention immediately.
Flush with water for 20 minutes holding eyelids open. Obtain medical attention immediately.
Wash with soap and water. Remove dried adhesive with mineral spirits followed by soap and water. Remove contaminated clothing and launder before re-use. Consult
physician if irritation develops.
Do not induce vomiting. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Contact physician immediately.

Henry 314 Multipurpose Ceramic Tile Adhesive

Page 1 of 5

SECTION 1 - PRODUCT IDENTIFICATION

MATERIAL SAFETY DATA SHEET

Manufacturer/Supplier identifier:

Use in case of emergency only:
CHEM-TEL – 1-800-255-3924
OR
1-813-248-0585 (call collect)

®

The W.W. Henry Company
400 Ardex Park Drive
Aliquippa, PA 15001
U.S.A.
Tel: (724) 203-8499

Visit our Website: http://www.wwhenry.com

Product identifier/Trade name:

HMIS Hazard Index:

Henry 314 Multipurpose Ceramic Tile Adhesive

HEALTH = 1 FLAMMABILITY = 1 REACTIVITY = 0
4 = Severe 3 = Serious 2 = Moderate 1 = Slight 0 = Minimal
WHMIS Classification:

D2B – Toxic material with other effects
CHEMICAL NAME

CHEMICAL FAMILY

CHEMICAL FORMULA

Not Applicable

Not Applicable

Not Applicable

TRADE NAME AND SYNONYMS

MOLECULAR WEIGHT

MATERIAL USE

Henry® 314

Not Applicable

Filled water-based adhesive

SECTION 2 - CHEMICAL COMPOSITION / HAZARDOUS INGREDIENTS
Hazardous Ingredients

Stoddard solvent

C.A.S.
Numbers

%
(weight)

8052-41-3

5-10

OSHA PEL
TWA
STEL

100 ppm

N/Av

ACGIH TLV
TWA
STEL

100 ppm

N/Av

This material is classified as hazardous under OSHA regulations (29CFR 1910.1200).

SECTION 3 - HAZARDS IDENTIFICATION
Emergency Overview

IRRITANT. White paste with mild hydrocarbon odor. May cause a moderate skin irritation. Vapours or mist may cause mild
respiratory tracts irritations and central nervous system (CNS) effects, such as headache, dizziness, intellectual impairment
and fatigue. May cause minor to moderate irritation to eyes.
POTENTIAL HEALTH EFFECTS:
Primary entry route(s):

Skin, eye, ingestion and inhalation.
Target organs:

None
Effects of short-term (acute) exposure:

Inhalation: Vapours or mist may cause mild irritations and central nervous system (CNS) effects, such as headache,
dizziness, intellectual impairment and fatigue.
Skin: May cause a moderate skin irritation. Prolonged contact may cause drying and cracking of the skin and

moderate irritations.
Eye: May cause minor to moderate irritation to eyes.
Ingestion: None expected. May cause nausea, and irritation to the mouth and digestive tract if ingested in large amounts.
Effects of long-term (chronic) exposure:

None expected.
Conditions aggravated by exposure:

Carcinogenic status:

Skin conditions.

See TOXICOLOGICAL INFORMATION, Section 11.

Additional health hazards:

Potential environmental effects:

For further information, see TOXICOLOGICAL INFORMATION,

See ECOLOGICAL INFORMATION (Section 12).

Henry 314 Multipurpose Ceramic Tile Adhesive

Page 2 of 5

Section 11.

SECTION 4 - FIRST AID MEASURES
Inhalation: In case of exposure to excessive quantities of dusts/vapours, remove victim to fresh air. Seek medical attention if
symptoms persist.
Skin contact: flush skin thoroughly with lukewarm water for at least 20 minutes. Under running water, remove contaminated
clothing. Call a physician if irritation persists.
Eye contact: Flush eyes thoroughly with lukewarm water for at least 20 minutes while holding the eyelid(s) open. Consult a
physician if pain, irritation or vision problems persist after treatment.
Ingestion: Do not induce vomiting. Never give anything by mouth if patient is unconscious. Seek medical attention if
symptoms develop.

SECTION 5 - FIRE FIGHTING MEASURES
Fire hazards/conditions of flammability:

Product is not flammable under normal conditions.
Flammability classification (OSHA 29 CFR 1910.1200):

Non-flammable.
Flash point (Method):

> 93.3oC / > 200oF (Setaflash Closed
Tester)

Lower flammable limit (% by volume):

Upper flammable limit (% by volume):

Not applicable

Not applicable

Auto-ignition temperature:

Hazardous combustion products:

N/Av

Carbon monoxide, carbon dioxide, and other toxic vapors and gases that are
common to thermal degradation or organic compounds.

Sensitivity to mechanical impact:

Sensitivity to static discharge:

N/Av

N/Av

Suitable extinguishing media:

Carbon dioxide, dry chemical powder, appropriate foam or water fog.
Special fire-fighting procedures/equipment:

Firefighters should wear proper chemically protective equipment and self-contained breathing apparatus. Move containers
from fire area if it can be done without risk. Closed containers may explode with the pressure building from the heat. Use water
to cool fire exposed containers. After fires have been extinguished, carefully clean all equipment and surfaces exposed to
fumes.

SECTION 6 - ACCIDENTAL RELEASE MEASURES
Personal precautions:

IRRITANT. Wear personal protective equipment during cleanup. Restrict access to area until completion of clean-up.
All
persons dealing with clean-up should wear the appropriate chemically protective equipment especially where exposure to vapor,
dust or fume is possible.
Spill response/Cleanup:

Ventilate area of spill or release. Eliminate all sources of ignition. Contain material, preventing it from entering sewer lines or
waterways. Use absorbents to assist the pick up of material. Scrape up product and place it into a container for disposal.
Residual of product, while still wet, can be cleaned up with warm soapy water. Notify the appropriate authorities as required.
Environmental precautions:

Do not allow material to be discharged into the atmosphere or into sewers or ground water.
Special spill response procedures:

If a spill/release in excess of EPA reportable quantity is made into the environment, immediately notify the national response
center in the United States (phone: 1-800-424-8002).
DOT/CERCLA Reportable quantity (RQ):

None to report.

Henry 314 Multipurpose Ceramic Tile Adhesive

Page 3 of 5

SECTION 7 - HANDLING AND STORAGE
Safe handling procedures:

IRRITANT. Wear suitable protective equipment. Use with adequate ventilation. Training the workers on the potential health
hazards associated with product vapor, dust or fume is important. Secondary inhalation exposures could occur when
cleaning equipment, or when removing or laundering the clothing. Do not breathe vapors, fumes or dust. Avoid contact with
eyes, skin and clothing. Keep away from flame, sparks and other ignition sources. Avoid and control operations which create
vapors/dusts.
Storage requirements:

Store in a cool (temperature below 32.2oC / 90oF), dry, well-ventilated area. No smoking in the area. Protect from damage.

SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
Engineering controls:

Use with adequate ventilation. Normal ambient ventilation should be sufficient.
PERSONAL PROTECTIVE EQUIPMENT

Respiratory Protection: Respiratory protection should not be required.
Skin protection and other protective equipment: Impervious gloves appropriate to the material if skin contact with product is
expected. Advice should be sought from glove suppliers. Where exposure to product is possible use protective clothing. An
eyewash fountain and safety shower should be made available in the immediate working area.
Eye / face protection: Wear safety glasses to prevent any product from entering the eyes.
Permissible exposure levels:

For individual ingredient exposure levels, see Section 2.
General Hygiene Considerations:

Avoid contact with eyes, skin and clothing. Avoid breathing vapors/dusts. Never eat, drink, or smoke in work areas. Clean
all equipment and clothing at end of each work shift.

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical state:

Odor and appearance:

Paste (liquid)

White paste with mild hydrocarbon odor.

Odor threshold:

Specific gravity (water = 1):

Vapor pressure:

N/Av

1.39

N/Av

Evaporation rate:

Slower than Ether

Boiling point:

Melting/freezing point:

100oC / 212oF

% volatile by volume:

pH:

N/Av

9.05

% volatile by weight:

25-35 % (30 min. at 135oC / 275oF)

N/Av

Vapor density:

Heavier than air
Solubility in water:

Dispersible

Coefficient of oil/water distribution:

Particle size:

N/Av

N/Av

Weight/Gallon:

11.5 lbs (water = 8.3 lbs)

Volatile Organic Content (VOC):

121 g/L calculated at 21oC / 70oF, SCAQMD

SECTION 10 – REACTIVITY AND STABILITY DATA
Stability and reactivity:

Stable under the recommended storage and handling conditions prescribed.
Polymerization:

Hazardous polymerization will not occur.
Conditions to avoid:

Temperatures above 32.2oC / 90oF.
Materials to avoid:
Strong oxidizing agents.
Hazardous decomposition products:
Carbon monoxide, carbon dioxide, and other toxic vapors and gases that are common to thermal degradation or organic
compounds.

Henry 314 Multipurpose Ceramic Tile Adhesive

Page 4 of 5

SECTION 11 - TOXICOLOGICAL INFORMATION
Toxicological data:

There is no available data for the product itself. See below for individual ingredient acute toxicity data.
Ingredients:
LD50 (route, species):
LC50 (species):
Stoddard Solvent
Not available.
Not available.
Carcinogenicity:

No ingredient classified as carcinogenic to humans by IARC, NTP, OSHA and ACGIH.
Teratogenicity, mutagenicity, other reproductive effects:

None known.
Sensitization to material:

Synergistic materials:

None known.

N/Av

Irritancy of material:

Moderate degree of irritation.
For more details, refer to Section 3.

SECTION 12 - ECOLOGICAL INFORMATION
Environmental effects:

N/Av
Important environmental characteristics:

N/Av
Aquatic toxicity:

N/Av

SECTION 13 - WASTE DISPOSAL
Handling and storage conditions for disposal:

Handle according to recommendations listed in Section 7.
Methods of disposal:

Dispose of in sealed containers in accordance with all applicable government regulations. Dispose in accordance with all
applicable federal, provincial, state and local regulations. Contact your local, state or federal environmental agency for specific
rules.
RCRA:

If this product, as supplied, becomes a waste, it may meet the criteria of a hazardous waste as defined under RCRA, Title 40
CFR 261. Waste classification should be determined by the end user of the product. For disposal of unused or waste material,
check with local, state and federal environmental agencies.

SECTION 14 - TRANSPORTATION INFORMATION
Transportation of Dangerous Goods (TDG) Information:

This product is not regulated according Canadian Regulations.
US DOT 49 CFR information:

This product is not regulated according to US Regulations.

SECTION 15 - REGULATORY INFORMATION
In Canada:
WHMIS information:

This product is controlled by WHMIS. It does meet the criteria for a controlled product provided in Part IV of the Controlled
Products Regulations (CPR).
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR)
and this MSDS contains all the information required by the CPR.
CEPA information:

Ingredient listed on the DSL/NDSL.

Henry 314 Multipurpose Ceramic Tile Adhesive

Page 5 of 5

SECTION 15 - REGULATORY INFORMATION continued
In U.S.A.:
TSCA information:

Ingredient listed on the TSCA inventory.
DOT/CERCLA Reportable Quantity (RQ):

None Reportable

SARA TITLE III:

Sec. 313, Toxic Chemicals Notification, 40 CFR 372: This material is not subject to the TSCA notification requirements,
since it does not contain any Toxic Chemical constituents above the minimum levels.
California Proposition 65:

This product does not contain chemicals known to the State of California to cause cancer or reproductive toxicity.
New Jersey Hazardous Substance Lists:

This product contains the following listed hazardous substances above threshold percentages:
Chemical Name CAS #
Stoddard solvent 8052-41-3

SECTION 16 - OTHER INFORMATION
Prepared by:

Telephone number:

Preparation date:

The W.W. Henry Company

(724) 203-8499

December 7, 2004

References:

1.
2.
3.
4.
5.
6.

ACGIH, Threshold Limit Values and Biological Exposure Indices for 2004.
International Agency for Research on Cancer Monographs, 2004.
Canadian Centre for Occupational Health and Safety, CCInfoWeb databases, 2004 (Chempendium and RTECs).
Material Safety Data Sheet from manufacturer.
US EPA Title III List of Lists – October 2001 version.
California Proposition 65 List – December 7, 2004 version.

Abbreviations:

ACGIH = American Conference of Governmental Industrial Hygienists
CAS = Chemical Abstract Service
CERCLA = Comprehensive Environmental Response, Compensation, and Liability Act of 1980
CFR = Code of Federal Regulations (Transportation in U.S.A.)
DOT = Department of Transport (U.S.A.)
DSL = Domestic Substance List
IARC = International Agency for Research on Cancer
N/Av = Not available.
N/Ap = Not applicable
NIOSH = National Institute for Occupational Safety and Health
NTP = National Toxicology Program (U.S.A.)
OSHA = Occupational Safety and Health Administration (U.S.A.)
PEL = Permissible Exposure Limit
RCRA = Resource Conservation and Recovery Act
SARA = Superfund Amendments & Reauthorization Act
STEL = Short-term Exposure Limit
TLV = Threshold Limit Value
TSCA = Toxic Substances Control Act
TWA = Time Weighted Average
WHMIS = Workplace Hazardous Materials Information System

The information presented herein is supplied as a guide to those who handle or use this product and has been
prepared in good faith by technically knowledgeable personnel. It is not intended to be all - inclusive. The
manner and conditions of use and handling may involve other and additional considerations. Safe work
practices must be employed when working with any materials. It is important that the end user makes a
determination regarding the adequacy of the safety procedures employed during the use of this product.
No warranty of any kind is given or implied. W.W. Henry Company will not be liable for any damages, losses,
injuries or consequential damages which may result from the use or reliance on any information contained
herein. This Material Safety Data Sheet is valid for three (3) years.
End of the MSDS

MATERIAL SAFETY DATA SHEET
PRODUCT NAME: Roberts 3200 White Cove Base Adhesive
PRODUCT USES: For installing vinyl and rubber cove base

W.H.M.I.S. CLASSIFICATION: NON-CONTOLLED
V.O.C. CONTENT: 88g/L

SECTION I - MANUFACTURER IDENTIFICATION
MANUFACTURER'S NAME: ROBERTS COMPANY CANADA LTD.
ADDRESS: 2070 Steeles Ave. Bramalea, Ontario L6T 1A7
24 HOUR (CANUTEC) PHONE:
(613) 996-6666
DATE REVISED:
06/30/02 (Product was discontinued in 2002. Replaced by 7032)

NAME OF PREPARER: Peter Sharko
INFORMATION PHONE: (905) 791-4444
SOURCES USED: Raw material supplier M.S.D.S.

SECTION II - HAZARDOUS INGREDIENTS INFORMATION
COMPONENT
APPROX. %
MINERAL SPIRITS
5-10

UN#
1256

SECTION III – PHYSICAL DATA
BOILING POINT: 100° CFREEZING POINT: N/A
VAPOUR DENSITY (AIR=1):
4-5
VAPOUR PRESSURE (MM OF MERCURY):
Min. spirits 2 @ 20ºC
SOLUBILITY IN WATER:
Miscible
APPEARANCE AND ODOUR:
White, soft buttery paste, mild solvent odour.

CAS#
8052-41-3

LD50

LC50
1,400 PPM 8HR., RAT

SPECIFIC GRAVITY (H20=1): 1.17 pH: 9.5 – 10.5
EVAPORATION RATE (BUTYL ACETATE=1): Slower
EVAPORATION RATE (ETHYL ACETATE=1): Slower
PERCENT VOLATILE: 46
ODOUR THRESHOLD (PPM): Not available

SECTION IV - FIRE AND EXPLOSION DATA
FLASHPOINT (specify method):
Over 200ºF
METHOD USED: P.M.C.C.
IMPACT SENSITIVITY: Insensitive
FLAMMABLE LIMITS (% BY VOLUME):
LOWER: 0.8-0.9 UPPER: 7
SENSITIVITY TO STATIC DISCHARGE: Vapours may be
FIRE EXTINGUISHING MEDIA: Foam, CO2, Dry Chemical
AUTO IGNITION TEMP: N/A
TDG FLAMMABILITY CLASSIFICATION: Not regulated.
SPECIAL FIRE-FIGHTING PROCEDURES: Poses minimal fire hazard. Must be heated substantially. Self-contained breathing apparatus should be worn for fires involving this product.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Flammable vapours, heavier than air, may be able to collect in confined spaces and pose a hazard.
SECTION V - REACTIVITY DATA
STABILITY:
Stable
INCOMPATIBILITY (Materials to avoid): Strong oxidizing agents
HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO2, and Hydrocarbons upon combustion.
HAZARDOUS POLYMERIZATION: Will not occur
SECTION VI – TOXICOLOGICAL PROPERTIES
SKIN CONTACT
X
SKIN ABSORPTION

CONDITIONS TO AVOID: Excessive Heat
CONDITIONS TO AVOID: None

ENTRY ROUTE TABLE
EYE CONTACT
X
INHALATION ACUTE

X

INHALATION CHRONIC

INGESTION

X

EFFECTS OF ACUTE EXPOSURE TO MATERIAL: Overexposure to vapours can cause eye, nose, throat irritation, dizziness, drowsiness, headache feelings of drunkenness, nausea, vomiting.
Massive overexposure can cause respiratory failure. Ingestion causes similar symptoms. Aspiration causes severe pneumonitis. Product is eye and skin irritant.
EFFECTS OF CHRONIC EXPOSURE TO MATERIAL: Prolonged or repeated contact with skin may cause drying and defatting of skin and dermatitis. Although unlikely to occur, overexposure to
vapours may cause corneal damage, photophobia. In rare cases, severe overexposure may sensitize heart muscles causing heart arrhythmia.
LD50 (SPECIFY SPECIES & ROUTE):
Not available
SENSITIZING CAPACITY:
May sensitize heart muscles. See above.

LC50 (SPECIFY SPECIES):
Not available
CARCINOGENICITY:
None

EXPOSURE LIMIT:
TLV-TWA, PPM MINERAL SPIRITS, 100
REPRODUCTIVITY EFFECTS:
None known

IRRITANCY:
Eye, nose, throat and skin irritant
SYNERGISTIC MATERIALS:
None known

SECTION VII – PREVENTATIVE MEASURES
RESPIRATORY PROTECTION (SPECIFY TYPE): Not required under normal conditions of use. If TLV is to be exceeded, employ an approved NIOSH/MSHA chemical cartridge respirator with
organic vapour cartridge. Consult your safety equipment supplier for respirator requirements.
VENTILATION: General dilution ventilation to keep vapours below TLV.
PROTECTIVE GLOVES: Solvent resistant gloves should be worn.
EYE PROTECTION: Goggles / glasses with side shields
OTHER PROTECTIVE EQUIPMENT: None required.
SPILL PROCEDURES: Provide adequate ventilation. Mechanically collect. Wash area with water. Prevent from entering sewers or waterways. Spilled material may cause slippery conditions.
Promptly report significant spills to appropriate authorities. Consult local regulations.
WASTE DISPOSAL METHOD: Destroy by incineration at an approved facility. Dried material only may be landfilled. Consult local regulations.
STORAGE & HANDLING PRECAUTIONS: Store in ventilated area as close to 70ºF as possible.
OTHER PRECAUTIONS: Keep containers closed when not in use. Keep out of reach of children.
SECTION VIII – FIRST AID MEASURES
INHALATION:
EYES:
SKIN:
INGESTION:

Remove to fresh air. If not breathing, trained personnel should administer artificial respiration. Obtain medical attention immediately.
Flush with water for 20 minutes holding eyelids open. Obtain medical attention immediately.
Wash with soap and water. Remove dried adhesive with mineral spirits followed by soap and water. Remove contaminated clothing and launder before re-use. Consult
physician if irritation develops.
Do not induce vomiting. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Contact physician immediately.

Page 1 of 6

Material
Safety
Data
Sheet

24 Hour Emergency Phone Numbers:
Medical: 1-800-327 -3874
1-513-558-5111
Transportation:
1-800-535-5053
1-352-323-3500

NOTE: National Response Center emergency numbers to be used only in the
event of chemical emergencies involving a spill, leak, fire, exposure or
accident involving chemicals.

IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of this
product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with requirements
of this standard. All abbreviated terms used in this MSDS are further described in Section 16.

Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en español a su solicitud.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.

Product Name:
Product UPC
Number:
Product Use/Class:
Manufacturer:

DAP WELDWOOD Multi-Purpose Floor Covering
Adhesive
7079800144, 7079800142, 7079800141, 7079800140,
7079872054, 7079872052, 7079872049
Latex Floor Covering Adhesive

Revision Date:

03/07/2005

Supercedes:

02/17/1999

MSDS Number:

00030807001

DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327 -8477 (non-emergency matters)

Section 2 - Composition / Information On Ingredients
Chemical Name
CASRN
Kaolin
1332-58-7
Petroleum hydrocarbon oil 64742-52-5
Urea
57-13 -6
Ethylene glycol
107-21-1
Titanium dioxide
13463-67-7
4-Vinylcyclohexene
100-40-3

WT%
15-40
10-30
1-5
1-5
0.1-1.0
<0.0006

ACGIH TWA
2 MGM3
N.E.
N.E.
N.E.
10 MGM3
0.1 PPM

ACGIH STEL
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.

ACGIH CEIL
N.E.
N.E.
N.E.
100 MGM3
N.E.
N.E.

OSHA TWA
N.E.
N.E.
N.E.
N.E.
15 MGM3
N.E.

OSHA STEL
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.

OSHA CEIL
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.

Skin
No
No
No
No
No
No

Exposure Notes:
Important:

Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary between

states.

Note:

An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent necessary
under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work practices

Section 3 - Hazards Identification
Emergency Overview: A white to off-white paste with a very slight ammonia odor. WARNING! May cause irritation to the

Page 2 of 6
respiratory tract. Harmful or fatal if swallowed. May cause eye, skin, nose, throat and respiratory tract irritation. This product
contains ethylene glycol.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: May cause eye irritation.
Effects Of Overexposure - Skin Contact: May cause skin irritation.
Effects Of Overexposure - Inhalation: Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous
membranes). Vapors may be irritating to eyes, nose, throat, and lungs. Prolonged, repeated, or high exposures may cause
weakness and depression of the central nervous system.
Effects Of Overexposure - Ingestion: If ingested, may cause vomiting, diarrhea, and depressed respiration. Aspiration of
material into the lungs due to vomiting can cause chemical pneumonitis, which can be fatal.
Effects Of Overexposure - Chronic Hazards: Ethylene Glycol may cause kidney and liver damage upon prolonged and
repeated overexposures. Studies have shown that repeated inhalation of ethylene glycol has produced adverse cardiovascular
changes in laboratory animals. Ethylene glycol has been shown to cause birth defects in laboratory animals. Prolonged or
repeated contact with skin results in irritation and dermatitis.
Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation
Medical Conditions which May be Aggravated by Exposure: None known.

Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical
attention immediately.
First Aid - Skin Contact: Wash off with soap and water.
First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If continued
breathing difficulty is experienced, get medical attention immediately.
First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
Note to Physician: None.
COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arise from any of the above routes of
entry.

Section 5 - Fire Fighting Measures
Flash Point, F: greater than 200 degrees
Fahrenheit
Method: (Seta Closed Cup)

Lower Explosive Limit, %: Not Established
Upper Explosive Limit, %: Not Established

Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam
Unusual Fire And Explosion Hazards: None known.
Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent)
and full protective gear. Use water spray to cool exposed surfaces.

Page 3 of 6

Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Wet dried
material before scraping up and place into containers.

Section 7 - Handling And Storage
Handling: Do not breathe vapors. Provide fresh air such that chemical odors cannot be detected during use and while drying.
Use in well ventilated area. Construction and repair activities can adversely affect indoor air quality. Consult with occupants or a
representative (i.e. maintenance, building manager, industrial hygienist, or safety officer) to determine ways to minimize impact.
Wash thoroughly after handling. Do not sand, dry sweep, dry scrape, drill, saw, beadblast, mechanically chip, pulverize or
otherwise machine existing resilient flooring, backing, lining felt, or asphaltic "cut -back" adhesives. These products may contain
either asbestos fibers or crystalline silica. Avoid creating dust. Inhalation of such dust is a cancer and respiratory tract hazard.
See current edition of the Resilient Floor Covering Institute's publication "Recommended Work Practices for Removal of
Resilient Floor Coverings", for detailed information and instructions addressed to the task of removing all resilient floor covering
materials. Avoid contact with eyes, skin and clothing.
Storage: Store containers away from excessive heat and freezing. Keep containers tightly closed. Store away from caustics
and oxidizers.

Section 8 - Exposure Controls / Personal Protection
Precautionary Measures: Please refer to other sections and subsections of this MSDS.
Engineering Controls: Provide sufficient general and/or local exhaust ventilation to maintain exposure below recommended
exposure limit. Use only in well-ventilated areas.
Respiratory Protection: A respiratory protection program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must
be followed whenever workplace conditions warrant a respirator's use. Respirator use is not expected to be necessary under
normal conditions of handling. In emergency situations, use of a NIOSH -approved respirator may be required.
Skin Protection: Wear rubber gloves.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: None.
Hygienic Practices: Although this product is not considered an eye irritant, inhalation hazard, or a skin contact hazard under
normal conditions, it is advisable that personnel minimize skin contact, inhalation of vapors and eye contact. Remove and wash
contaminated clothing before re-use.

Section 9 - Physical And Chemical Properties
Boiling Range:
Odor:
Appearance:
Solubility in H2O:
Freeze Point:
Vapor Pressure:
Physical State:

Not Established
Very Slight Ammonia
White to Off-White
Not Established
Not Established
Not Established
Paste

Vapor Density:
Odor Threshold:
Evaporation Rate:
Specific Gravity:
pH:
Viscosity:

Not Established
Not Established
Not Established
1.202
Between 7.0 and 12.0
Not Established

When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally.

Page 4 of 6
(See section 16 for abbreviation legend)

Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Strong oxidizing agents. Strong bases.
Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under normal conditions.

Section 11 - Toxicological Information
Product LD50: Not Established
CASRN
57-13-6
107-21-1
100-40-3

Chemical Name

Product LC50: Not Established
LD50

Urea
Ethylene glycol
4-Vinylcyclohexene

Rat:8471 mg/kg
Rat:4700 mg/kg
16620 mg/kg

LC50

WT%

------------Rat:10876 mg/kg
4000 ppm rat

1-5
1-5
<0.0006

Carcinogenicity:
CAS No.

Chemical Name

13463-67 -7

Titanium dioxide

100-40-3

4-Vinylcyclohexene

14808-60 -7

Silica, crystalline

ACGIH

OSHA

IARC

NTP

WT%

-----

-----

Classification not possible
from current data.

-----

0.1-1.0

-----

Possible carcinogen.

-----

<0.0006

-----

-----

Known carcinogen.

<0.00001

Confirmed animal
carcinogen with unknown
relevance to humans.
Suspected human
carcinogen.

Significant Data with Possible Relevance to Humans: None

Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.

Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local
regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the
owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): none

Section 14 - Transportation Information
DOT Proper Shipping
Name:
DOT Technical Name:
DOT Hazard Class:

None

Packing Group:

N.A.

None
N.A.

Hazard Subclass:
DOT UN/NA Number:

N.A.
None

Page 5 of 6
Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may apply if
shipped via other modes of transportation and/or to non-domestic destinations.

Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet
the following categories:
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund
Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name
Ethylene glycol

CAS Number

WT%

107-21-1

1-5

Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
Chemical Name

CAS Number

5-Chloro-2-methyl-4-isothazoli
2-Methyl-4-isothiazolin-3-one

26172-55 -4
2682-20-4

U.S. State Regulations:
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product:
Chemical Name
Water
Hydrocarbon Petroleum Resin
Butadiene-styrene copolymer

CAS Number
7732-18 -5
Proprietary
Proprietary

WT%
30-60
3-7
3-7

Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%:
Chemical Name
Water
Hydrocarbon Petroleum Resin
Butadiene-styrene copolymer

CAS Number
7732-18 -5
Proprietary
Proprietary

California Proposition 65:
Warning: The following ingredients present in the product are known to the State of California to cause cancer:

WT%
30-60
3-7
3-7

Page 6 of 6

Chemical Name

CAS Number

Definition

Date Listed

WT%

4-Vinylcyclohexene

100-40 -3

Carcinogenic.

Listed: May 1, 1996

<0.0006

Silica, crystalline

14808-60-7

Carcinogenic.

Listed: October 1, 1988

<0.00001

Warning: The following ingredients present in the product are known to the State of California to cause birth defects or other
reproductive harm:
None.

Section 16 - Other Information
HMIS Ratings:
Health: 1

Flammability: 1

VOLATILE ORGANIC COMPOUNDS, GR/LTR: 34.3

Reactivity: 0
LB/GAL: 0.3

Personal Protection: X
WT%: 1.557

REASON FOR REVISION: Periodic Update
Legend:

N.A. – Not Applicable

ACGIH – American Conference of Governmental Industrial Hygienists

N.E. – Not Established

SARA – Superfund Amendments and Reauthorization Act of 1986

N.D. – Not Determined

NJRTK – New Jersey Right-to-Know Law

VOC – Volatile Organic Compound

OSHA – Occupational Safety and Health Administration

PEL – Permissible Exposure Limit

HMIS – Hazardous Materials Identification System

TLV – Threshold Limit Value

NTP – National Toxicology Program

STEL – Short Term Exposure Limit

CEIL – Ceiling Exposure Limit

LD50 – Lethal Dose 50

LC50 – Lethal Concentration 50

F – Degree Fahrenheit

C – Degree Celcius

MSDS – Material Safety Data Sheet

CASRN – The Chemical Abstracts Service Registry Number

DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical values and
not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY PARTICULAR
PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE INFORMATION
HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this document is intended only as a
guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is therefore the
responsibility of the user to (i) review the recommendations with due consideration for the specific context of the intended use and (ii)
determine if they are appropriate.


Page 1 of 7

Hoja
de datos
de la seguridad
de los materiales

Números telefónicos de emergencia las 24 horas:
Emergencias médicas: 1-800-327-3874
1-513-558-5111
Transporte:
1-800-535-5053
1-352-323-3500

NOTA: Los números de emergencia del Centro de Respuesta Nacional s ólo
se deben usar en caso de emergencias químicas que involucren un
derramamiento, incendio, exposici ón o accidente que tengan que ver con
químicos

IMPORTANTE: Lea esta hoja de datos de la seguridad de los materiales antes de manipular o desechar este producto, y entregue esta información a
los empleados, clientes y usuarios de este producto. Este producto está cubierto por la norma de comunicación de riesgos OSHA, y este documento fue
preparado de acuerdo con los requisitos de dicha norma. Todos los términos abreviados utilizados en este documento se describen con más detalles en
la sección 16.

Sección 1 - Información del producto químico/ compañía
Esta hoja de datos de la seguridad de los materiales está disponible en francés canadiense y en español a su solicitud.
On peut demander cette MSDS a la langue Francaise Canadienne.

Nombre de
producto:
Número de UPC del
producto:
Uso/ clase del
producto:

DAP WELDWOOD Multi-Purpose Floor Covering
Adhesive
7079800144, 7079800142, 7079800141, 7079800140,
7079872054, 7079872052, 7079872049
Latex Floor Covering Adhesive

Fabricante:

DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327-8477 (asuntos de no emergencia)

Fecha de
revisión:
Reemplaza a:

03/07/2005
02/17/1999

Número de hoja 00030807001
de datos
(MSDS):

Sección 2 - Composición / Información sobre los Ingredientes
Nombre Químico
Caolín
Destilados (Petróleo), Fracción
Nafténica Pesada Tratada Con
Hidrógeno
Carbamida
Etilen Glicol
Dioxidodetitanio
4-Vinilciclohexeno

CASRN
1332 -58-7

Peso%
15 -40

ACGIH TWA ACGIH STEL ACGIH CEIL
2 MGM3
N.E.
N.E.

64742-52-5

10 -30

N.E.

N.E.

57 -13-6
107-21-1
13463-67-7
100-40-3

1-5
1-5
0.1-1.0
<0.0006

N.E.
N.E.
10 MGM3
0.1 PPM

N.E.
N.E.
N.E.
N.E.

OSHA TWA
N.E.

OSHA STEL
N.E.

OSHA CEIL
N.E.

Piel
No

N.E.

N.E.

N.E.

N.E.

No

N.E.
100 MGM3
N.E.
N.E.

N.E.
N.E.
15 MGM3
N.E.

N.E.
N.E.
N.E.
N.E.

N.E.
N.E.
N.E.
N.E.

No
No
No
No

Notas sobre la exposición:
Importante:

Los niveles de exposición permitidos (PEL) señalados son suministrados por el Dept. del Trabajo de EE.UU., Límites de la norma final OSHA (CFR 29
1910.1000); Estos límites pueden variar de estado a estado.

Nota:

Se debe evitar o reducir al máximo la exposición de la piel de un empleado a substancias que tengan "S Í" en la columna "PIEL" en la tabla anterior, seg ún lo
permitan las circunstancias mediante el uso de guantes, ropa de protecci ón, gafas de seguridad y otros equipos personales de protección, controles de ingeniería o
prácticas de trabajo.

Sección 3 - Identificación de riesgos

Page 2 of 7
Generalidades sobre las emergencias: Un blanco a la pasta de-blanco con un olor muy leve del amoniaco.
¡ADVERTENCIA! Puede causar irritaci ón de las vías respiratorias. Dañino o fatal si se traga. Podría causar irritación de los
ojos, piel, nariz, garganta y tracto respiratorio. Este producto contiene glicol de etileno.
Consulte otras secciones de la hoja de datos de seguridad de los materiales para m ás información detallada.
Efectos de la sobre exposición - Contacto visual: Podr ía causar irritación a los ojos.
Efectos de la sobre exposición - Contacto de la piel: Podría causar irritación de la piel.
Efectos de la sobre exposición - Inhalaci ón: La inhalaci ón puede causar irritación de las vías respiratorias (nariz, boca,
membranas mucosas). Los vapores pueden irritar los ojos, la nariz, la garganta y los pulmones. Las exposiciones prolongadas,
repetidas o elevadas pueden causar debilidad y depresi ón del sistema nervioso central.
Efectos de la sobre exposición - Ingestión: Si se ingiere, podría causar vómito, diarrea y respiración deprimida. La
aspiraci ón del material en los pulmones debido al vómito puede causar neumonitis química, lo que podría ser fatal.
Efectos de la sobre exposición - Riesgos crónicos: El glicol de etileno puede causar daño al riñón e hígado con la sobre
exposición prolongada y repetida. Los estudios han demostrado que la inhalación repetida al glicol de etileno ha producido
cambios cardiovasculares adversos en los animales de laboratorio. Se ha demostrado que el glicol de etileno causa defectos
de nacimiento en animales de laboratorio. El contacto prolongado o repetido con la piel resulta en irritación y dermatitis.
Ruta(s) principal de entrada: Piel el Contacto, Pele la Absorción,Aspiración
Condiciones m édicas que se pueden agravar a causa de la exposición: Ninguno conocido.

Sección 4 - Medidas de primeros auxilios
Primeros auxilios - Contacto visual: En caso de contacto, enjuague los ojos de inmediato con abundante agua por al menos
15 minutos. Obtenga atención médica de inmediato.
Primeros auxilios - Contacto de la piel: Lavar con agua y jabón.
Primeros auxilios - Inhalaci ón: Si se inhala, salga al aire fresco. Si se dificulta la respiración, abandone el área para obtener
aire fresco. Si se experimenta dificultad continua para respirar, busque atenci ón médica de inmediato.
Primeros auxilios - Ingestión: Si se traga, NO PROVOQUE EL VÓMITO. Obtenga atención médica de inmediato.
Nota para el médico: Sin informaci ón
COMENTARIOS: Llame para emergencias médicas al 1 -800-327-3874 si surgiera cualquier irritación o complicación de
cualquiera de las rutas de entrada anteriores.

Sección 5 - Medidas para combatir incendios
Punto de inflamaci ón, F: Más que 200 grados
Fahrenheit
Método: ( Seta Cerró Copa)

Límite explosivo menor, %: No Establecido
Límite explosivo mayor, %: No Establecido

Medios para extinguir: Bióxido de carbono, Seque Sustancia Química, Espuma
Riesgos inusuales de incendio y explosi ón: Ninguno conocido.
Procedimientos especiales para combatir incendios: Use un aparato para respiraci ón auto-contenida con demanda de

Page 3 of 7
presi ón (aprobado por el Instituto NIOSH o equivalente) y equipo completo de protecci ón. Use rociador de agua para enfriar las
superficies expuestas.

Sección 6 - Medidas en caso de emisión accidental
Pasos a seguir en el caso de emisión o derramamiento de materiales: Use el equipo de protección correcto según lo
especifica la Secci ón 8. Moje el material seco antes de raspar y coloque en contenedores.

Sección 7 - Manejo y almacenamiento
Manejo: No respire los vapores. Suministre aire fresco de manera que los olores de los químicos no se puedan detectar
durante el uso y mientras se seca. Usar en un área bien ventilada. Las actividades de construcci ón y de reparaciones pueden
afectar de manera adversa la calidad del aire en interiores. Consulte con los ocupantes o un representante (es decir,
mantenimiento, administrador de construcción, higienista industrial, u oficial de seguridad) para determinar las formas de
reducir el impacto.
Lave a fondo después de manipular. No lije, barra en seco, raspe en seco, perfore, asierre, pula, corte mecánicamente,
pulverice o una acci ón similar los revestimientos elásticos existentes, refuerzos, fieltro de forro, o adhesivos asfálticos "cut back". Estos productos pueden contener ya sea fibras de asbestos o sílice cristalino. Evite crear polvo. La inhalación de este
polvo es un riesgo de cáncer y de infección del tracto respiratorio. Consulte la edici ón actual de la publicaci ón del Instituto
Resilient Floor Covering: “Pr ácticas de trabajo recomendadas para retirar los revestimientos elásticos", para informaci ón e
instrucciones detalladas para la tarea de retirar todos los materiales de revestimiento elástico. Evite el contacto con los ojos, la
piel y la ropa.
Almacenamiento: Almacene los contenedores lejos del calor y congelamiento excesivos. Manténgase el recipiente bien
cerrado. Almacene lejos de substancias cáusticas y oxidantes.

Sección 8 - Controles de la exposición/ Protección personal
Medidas de precaución: Refiérase por favor a otras secciones y subdivisiones de este MSDS.
Controles de ingeniería: Ofrezca ventilación de escape general y/o local suficiente para mantener la exposición debajo del
límite recomendado. Utilícese solo en zonas bien ventiladas.
Protecci ón respiratoria: Se debe seguir un programa de protecci ón respiratoria que cumpla con los requisitos de OSHA
1910.134 y ANSI Z88.2 cada vez que las condiciones del lugar de trabajo exijan el uso de un respirador. No es de esperar que
sea necesario usar un aparato de respiraci ón bajo condiciones normales de manejo. En situaciones de emergencia, puede que
se requiera el uso de un aparato de respiraci ón aprobado por el NIOSH.
Protecci ón de la piel: Usar guantes de goma.
Protecci ón de la visión: Gafas de seguridad con protectores laterales.
Otro equipo de protección: Ninguno.
Prácticas higiénicas: No obstante este producto no se considera un irritante para los ojos, riesgo de inhalación o riesgo de
contacto con la piel bajo condiciones normales, se recomienda que el personal reduzca el contacto con la piel, la inhalación de
vapores y el contacto con los ojos. Quitar y lavar la ropa contaminada antes de reutilizar.

Sección 9 - Propiedades físicas y químicas
Rango de ebullición:

No Establecido

Densidad del vapor:

No Establecido

Page 4 of 7
Olor:

Amoniaco muy Leve

Umbral de olor:

No Establecido

Aspecto:

Blanco a De-Blanco

Índice de evaporación:

No Establecido

Solubilidad en H2O:

No Establecido

Gravedad específica:

1.202

Punto de congelamiento:

No Establecido

pH:

Entre 7,0 y 12,0

Presi ón del vapor:

No Establecido

Viscosidad:

No Establecido

Estado físico:

Pasta

(Ver sección 16 para la leyenda de las abreviaturas)

Sección 10 - Estabilidad y reactividad
Condiciones a evitar: Calentamiento y congelamiento excesivos.
Incompatibilidad: agentes oxidantes fuertes bases fuertes
Productos de descomposición peligrosa: Productos de descomposición normal, es decir, COx, NOx.
Polimerización peligrosa: No ocurrirá polimerización peligrosa bajo condiciones normales.
Estabilidad: Estable en condiciones normales

Sección 11 - Información toxicológica
LD50 del producto: No Establecido
CASRN
Nombre Químico
57-13-6
107-21-1
100-40-3

LC50 del producto: No Establecido
LD50
LC50

Carbamida
Etilen Glicol
4-Vinilciclohexeno

Rat:8471 mg/kg
Rat:4700 mg/kg
16620 mg/kg

------------Rat:10876 mg/kg
4000 ppm rat

Peso%
1-5
1-5
<0.0006

Carcinogenicidad:
Número
CAS

Nombre Químico

13463-67 -7

Dioxidodetitanio

100-40-3

4-Vinilciclohexeno

14808-60 -7

Silicecristalina

ACGIH

OSHA

IARC

NTP

Peso%

-----

-----

Clasificación no posible
de datos actuales.

-----

0.1-1.0

-----

Cancerígeno posible.

-----

<0.0006

-----

-----

Cancerígeno conocido.

<0.00001

Cancerígeno animal
confirmado con la
aplicabilidad desconocida a
humanos.
Cancerígeno humano
sospechado.

Datos significativos con posible relevancia para los humanos: Ninguno

Sección 12 - Información ecológica
Información ecológica: No se conocen ni esperan daños ecológicos bajo uso normal.

Sección 13 - Información sobre desechos
Información sobre desechos: Deseche los materiales de acuerdo con todas las normas federales, estatales y locales. Las
normas/ restricciones estatales y locales son complejas y pueden diferir de las normas federales. La responsabilidad de
eliminar los desechos correctamente recae en el propietario de los desechos.

Page 5 of 7
Código de desechos de EPA en caso de desecho (CFR 40 Sección 261): Ninguno

Sección 14 - Información sobre transporte
Nombre correcto para envío a
DOT:
Nombre técnico para DOT:
Clase de riesgo para DOT:

Ninguno

Grupo de empaque:

No Aplicable

Ninguno
No Aplicable

Sub-clase de riesgo:
Número UN/NA para DOT:

No Aplicable
Ninguno

Nota: La información del envío proporcionada es aplicable para el transporte doméstico del suelo sólo. Categorizaci ón diferente
puede aplicar si enviado vía otros modos del transporte y/o a destino no-domésticos.

Sección 15 - Información reglamentaria
Categoría de riesgo CERCLA - SARA:
Este producto ha sido revisado según las categorías de riesgo de EPA promulgadas según las secciones 311 y 312 de la Ley
de enmienda y reautorización de fondos especiales de 1986 (SARA, por sus iniciales en inglés, Título III) y se considera, según
las definiciones correspondientes, que cumple con las siguientes categorías:
Sección 313 de la ley SARA:
Este producto contiene las siguientes substancias sujeto a los requisitos de reporte de la sección 313 del título III de la ley
SARA de 1986 y 40 CFR parte 372:
Nombre Químico
Etilen Glicol

Número CAS

Peso%

107-21-1

1-5

Ley para el control de substancias tóxicas:
Todos ingredientes en este producto son o en lista de inventario de TSCA, o de otro modo exima.
Este producto contiene las siguientes substancias químicas de acuerdo con los requisitos de reporte de la ley TSCA 12(B) si es
exportado desde los Estados Unidos:
Nombre Químico

Número CAS

5-Chloro-2-Methyl-4-Isothazoli
2-Methyl-4-Isothiazolin-3-One

26172-55 -4
2682-20-4

Regulaciones estatales de EE.UU.:
Ley del Derecho a saberde New Jersey:
Los siguientes materiales no representan peligro, pero están entre los primeros cinco componentes de este producto:
Nombre Químico
Agua
Hydrocarbon Petroleum Resin
Copolymer De Estireno De Butadiene

Número CAS
7732-18 -5
Propietario
Propietario

Peso%
30-60
3-7
3-7

Ley del Derecho a saber de Pennsylvania:
Los siguientes ingredientes no peligrosos están presentes en el producto en una proporción mayor a 3%:
Nombre Químico

Número CAS

Peso%

Page 6 of 7
Agua
Hydrocarbon Petroleum Resin
Copolymer De Estireno De Butadiene

7732 -18-5
Propietario
Propietario

30-60
3-7
3-7

Propuesta 65 de California:
Advertencia: Los siguientes ingredientes presentes en el producto son conocidos para el Estado de California por causar
cáncer:
Nombre Químico
4-Vinilciclohexeno
Ester Etilico Del Acido 2 -Propenoico
Silicecristalina

Número CAS
100-40 -3
140-88 -5
14808-60-7

Definición

Fecha Listó

Peso%

Cancerígeno.
Cancerígeno.
Cancerígeno.

Listed: May 1, 1996
Listed: July 1, 1989
Listed: October 1, 1988

<0.0006
<0.0001
<0.00001

Advertencia: Los siguientes ingredientes presentes en el producto son conocidos para el Estado de California por causar
defectos de nacimiento u otros daños reproductivos:

Ninguno.

Sección 16 - Otra información
Índices HMIS:
Salud: 1

Inflamabilidad: 1

Reactividad: 0

COMPONENTES ORGÁNICOS VOLÁTILES, GR/LTR: 34.3 LB/GAL: 0.3

Protecci ón personal: X
WT%: 1.557

RAZÓN DE LA REVISIÓN: Periódico Actualiza
Leyenda:

N.A. - No aplica

ACGIH - Conferencia Americana de Higienistas Industriales gubernamentales

N.E. - No establecido

SARA - Ley Ley de enmienda y reautorizaci ón de fondos especiales de 1986 (SARA)

N.D. - No determinado

NJRTK - Ley del Derecho a saber de New Jersey

VOC - Componente orgánico volátil

OSHA - Administración de la seguridad y salud ocupacional

PEL - Límites permitidos de exposición

C - Grados centígrados

TLV - Valor del límite umbral

NTP - Programa nacional de toxicología

STEL - Límite de exposición a corto plazo

CEIL - Límite máximo de exposici ón

LD50 - Dosis letal 50

LC50 - Concentración letal 50

HMIS - Sistema de identificación de materiales peligrosos

MSDS - Hoja de datos de la seguridad de los materiales

CASRN - Número de registro de servicios de abstractos químicos

F - Grados Fahrenheit

DAP cree que los datos y las declaraciones contenidos en el presente son exactos hasta la fecha. Se ofrecen de buena fe como valores típicos
y no como las especificaciones del producto. NO SE OFRECE NINGUNA GARANT ÍA DE COMERCIABILIDAD, IDONEIDAD
PARA UN PROPÓSITO EN PARTICULAR O CUALQUIER OTRA GARANTÍA, EXPRESA O IMPLÍCITA, CON RESPECTO A
LA INFORMACIÓN SUMINISTRADA EN EL PRESENTE O DEL PRODUCTO AL CUAL LA INFORMACIÓN SE REFIERE.
Dado que este documento tiene la intención de ser una guía únicamente para el uso correcto y el manejo preventivo del producto de la
referencia por parte de personas correctamente entrenadas, es responsabilidad del usuario (i) revisar las recomendaciones con especial
consideración al contexto específico del uso que se pretende y (ii) determinar si son correctas.

Page 7 of 7


Page 1 of 7

Fiche
signalétique

24 heures – Numéros de téléphone en cas
d’urgence:
Urgence médicale:
1-800-327 -3874
1-513-558 -5111
Urgence transport:
1-800-535 -5053
1-352-323 -3500

NOTE: Les numéros de téléphone en cas d’urgence doivent être utilisés
uniquement lors de déversement, de fuite, d’incendie, d’exposition ou
d’accident impliquant des produits chimiques.

IMPORTANT: Lire attentivement cette fiche signalétique avant de manipuler ou de disposer de ce produit. Remettre ces informations aux employés,
clients et utilisateurs de ce produit. Ce produit est régit sous la gouverne de l’OSHA, Communication de renseignements à l’égard de matières
dangereuses, et ce document a été préparé pour répondre aux exigences de ces standards. Les significations pour toutes les abréviations utilisées dans
cette fiche signalétique sont décrites à la Section 16.

Section 1 – Identification du produit et de la compagnie
This MSDS is offered in English upon request.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.

Nom du produit:
Numéro UPC:
Utilisation du
produit/Classe:
Fabricant:

DAP WELDWOOD Multi-Purpose Floor Covering
Adhesive
7079800144, 7079800142, 7079800141, 7079800140,
7079872054, 7079872052, 7079872049
Latex Floor Covering Adhesive

Date de r évision: 03/07/2005
Date
02/17/1999
d’abrogation:
Numéro de fiche: 00030807001

DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327 -8477 ( Pour toute information non urgente)

Section 2 - Composition / Ingrédients dangereux
Nom Chimique
Kaolin
Distillat naphténique lourd hydrotraité
Urée
Éthylène glycol
Dioxyde de titane
4-Vinylcyclohexne

CASRN
1332 -58-7
64742-52-5
57-13-6
107-21 -1
13463-67-7
100-40 -3

Poids%
15-40
10-30
1-5
1-5
0.1-1.0
<0.0006

ACGIH TWA ACGIH STEL ACGIH CEIL
2 MGM3
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
100 MGM3
10 MGM3
N.E.
N.E.
0.1 PPM
N.E.
N.E.

OSHA TWA
N.E.
N.E.
N.E.
N.E.
15 MGM3
N.E.

OSHA STEL
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.

OSHA CEIL Peau
N.E.
Non
N.E.
Non
N.E.
Non
N.E.
Non
N.E.
Non
N.E.
Non

Notes concernant l’exposition:
Important:

Les limites d’exposition permises (LEP) décrites proviennent du Department of Labor des États-Unis, règlement final concernant les valeurs d’exposition
moyennes pondérées de l’OSHA
(CFR 29 1910.1000); ces limites peuvent varier selon les états.

Note:

Prendre tous les moyens selon les circonstances afin de prévenir ou réduire toute exposition de la peau des employés aux substances portant la mention «OUI»
dans la colonne «PEAU» du tableau ci-dessus. Utiliser des gants, une combinaison, des lunettes étanches, tout autre équipement de protection personnel adéquat, les
contrôles techniques et les pratiques appropriées au type de travail.

Section 3 – Identification des dangers

Page 2 of 7
Urgences générales: Un blanc à la pâte de-blanc avec une odeur d'ammoniaque tr ès insignifiante. AVERTISSEMENT ! Peut
provoquer une irritation des voies respiratoires. Nocif ou mortel si ingéré. Peut causer une irritation des yeux, de la peau, du
nez, de la gorge et des voies respiratoires. Ce produit contient du glycol d'éthyl ène.
Consulter les autres sections de cette fiche signalétique pour des informations plus détaillées.
Effets de surexposition – Contact oculaire: Peut causer une irritation des yeux.
Effets de surexposition – Contact cutané: Peut causer une irritation de la peau.
Effets de surexposition – Inhalation: L'inhalation de ce produit peut provoquer l'irritation des voies respiratoires (nez,
bouche, muqueuses). Les vapeurs peuvent être irritantes pour les yeux, le nez, la gorge et les poumons. L'exposition
prolongée, ou répétée, ou à de fortes concentrations peut provoquer un affaiblissement et une dépression du système nerveux
central.
Effets de surexposition – Ingestion: En cas d’ingestion, peut causer des vomissements, de la diarrhée et une diminution de
la capacité pulmonaire. L’aspiration de mat ériau dans les poumons lors de vomissements peut causer une pneumonie chimique
qui peut être mortelle.
Effets de surexposition – Dangers chroniques: Une exposition excessive et répétée à l’éthyl ène glycol peut causer des
lésions aux reins et au foie. Les études en laboratoire menées sur des animaux ont démontré que l’inhalation r épétée
d’éthyl ène glycol cause des changements néfastes du syst ème cardiovasculaire. Lors d’études en laboratoire sur les animaux,
il a été démontré que l ’éthyl ène glycol cause des anomalies congénitales. Un contact excessif et répété avec la peau peut
causer une irritation ou une dermatite.
Voie(s) d’absorption: Peau le Contact,

L'Absorption de peau, l'Inhalation

Problèmes médicaux aggravés lors d’exposition au produit : Aucune connue.

Section 4 – Premiers soins
Premiers soins – Contact oculaire: En cas de contact avec les yeux, rincer abondamment avec de l ’eau pendant au moins
15 minutes. Obtenir des soins médicaux immédiatement.
Premiers soins – Contact cutané: Laver avec de l'eau et du savon.
Premiers soins – Inhalation: En cas d’inhalation, transporter la personne exposée à l’air frais. Si elle a de la difficulté à
respirer, quitter les lieux afin d’obtenir de l’air frais. Si la difficulté à respirer persiste, obtenir des soins médicaux
immédiatement.
Premiers soins – Ingestion: En cas d’ingestion, NE PAS FAIRE VOMIR. Obtenir des soins m édicaux immédiatement.
Note au médecin: Pas d'information.
COMMENTAIRES: En cas d’apparition d’une irritation ou de complications suite à une exposition au produit, communiquer
immédiatement avec l’urgence m édicale au 1-800-327-3874.

Section 5 – Mesures de protection en cas d’incendie
Point d’éclair, º F ( º C ): Plus grand que 200
degrés Fahrenheit
Méthode: ( Seta A Fermé la Tasse)

Limite d ’explosibilité inférieure, %: Pas Etabli
Limite d ’explosibilité supérieure, %: Pas Etabli

Moyens d’extinction: Dioxyde de carbone, Sécher Chimique, Mousse

Page 3 of 7
Risques particuliers d’explosions ou d’ignition:

Aucun connu.

Procédures spéciales de lutte contre les incendies: Porter un respirateur autonome à pression d’air (approuvé NIOSH ou
équivalent) et un équipement de protection personnel complet. Utiliser une lance-brouillard afin de refroidir les contenants
expos és.

Section 6 – Mesures en cas de déversement accidentel
Procédures de nettoyage: Porter un équipement de protection personnel approprié tel que spécifié à la Section 8. Humidifier
le matériau sec avant de le gratter puis disposer dans un contenant.

Section 7 – Manutention et entreposage
Manutention: Éviter de respirer les vapeurs. Assurer l’entrée d’air frais de façon à éliminer les odeurs des produits chimiques
pendant l ’utilisation et le temps de séchage. Utilisez dans un espace bien aéré. Les activités de construction et de réparation
peuvent affecter la qualité de l’air à l’intérieur. Vérifier avec les occupants ou un de leurs représentants (responsable de
maintenance, gérant d’édifice, hygiéniste industriel ou responsable de sécurité) afin de déterminer les façons appropriées pour
en diminuer l’impact.
Laver vigoureusement après la manipulation. Ne pas poncer, balayer à sec, gratter à sec, percer, scier, utiliser un jet à billes,
buriner et pulvériser mécaniquement ou à l’aide de tout autre outil les couvre-planchers élastiques, les supports, les blindages
ou les adhésifs d’asphalte dilué existants. Ces produits peuvent contenir de l’amiante ou de la silice cristalline. Éviter de générer
de la poussière. Éviter d’inhaler cette poussi ère, elle est canc érigène et dangereuse pour les voies respiratoires. Pour de plus
amples informations concernant les pratiques d’enlèvement complet des couvre-planchers élastiques, consulter la r écente
édition du bulletin du Resilient Floor Covering Institute; "Le Travail recommand é Pratique pour l'Enlèvement de Couvertures de
Plancher Elastiques". Éviter tout contact avec les yeux, la peau et les vêtements.
Entreposage: Entreposer les contenants loin de la chaleur excessive ou du froid excessif. Conserver le récipient bien fermé.
Entreposer loin des produits caustiques et des agents oxydants.

Section 8 – Contrôles d’exposition / Protection personnelle
Mesures de précaution: S'il vous plaît se référer aux autres sections et aux autres sous -sections de ce MSDS.
Contrôles d’ingénierie: Faire fonctionner au maximum le système de ventilation central et/ou le système d’évacuation local
afin de maintenir le niveau des vapeurs organiques sous les limites d’exposition recommandées. Utiliser seulement dans des
zones bien ventilées.
Protection des voies respiratoires: Un programme de protection respiratoire défini selon les normes de l ’OSHA 1910.134 et
de l’ANSI Z88.2 doit être appliqué à chaque fois que les conditions sur les lieux de travail exigent de porter un respirateur. On
ne s'attend pas à ce qu'un masque soit nécessaire dans les conditions normales de manipulation. En cas de situation
d'urgence, un masque de type agréé par NIOSH peut être nécessaire.
Protection de la peau: Portez des gants en caoutchouc.
Protection des yeux: Lunettes étanches ou lunettes de s écurité avec boucliers latéraux.
Équipements de protection additionnels: Aucun.
Pratiques hygiéniques: Dans des conditions normales d’utilisation, même si ce produit n’est pas considéré ni un irritant pour
les yeux, ni un danger en cas d’inhalation ou de contact avec la peau, il est recommandé que le personnel minimise les risques
de contact avec les yeux et la peau et évite d’inhaler les vapeurs. Enlever et laver les vêtements contaminés avant réutilisation.

Page 4 of 7

Section 9 – Propriétés physiques et chimiques
Point d’ébullition:
Odeur:

Pas Etabli
L'Ammoniaque très Insignifiante

Apparence:

Blanc à De-Blanc

Solubilité dans l’eau (H2O):
Point de congélation:
Pression de vapeur:
État physique:

Pas Etabli
Pas Etabli
Pas Etabli
Pâte

Densité de vapeur:
Limite de détection
olfactive:
Taux d ’évaporation:
Poids spécifique:

Pas Etabli
Pas Etabli

Taux de pH:
Viscosité:

Entre 7,0 et 12,0
Pas Etabli

Pas Etabli
1.202

(Consulter la Section 16 pour conna ître la signification des abréviations))

Section 10 – Stabilité et réactivité
Conditions à éviter: Chaleur excessive ou froid excessif.
Incompatibilité: des oxydants forts des bases fortes
Produits de décomposition dangereux: Produits de d écomposition habituels : oxydes de carbone (COx) et oxydes d’azote
(NOx).
Risque de polym érisation: Aucune polymérisation dangereuse ne surviendra dans des conditions normales d’utilisation.
Stabilité: Stable dans des conditions normales

Section 11 – Propriétés toxicologiques
Produit DL50: Pas Etabli
CASRN
57-13-6
107-21-1
100-40-3

Nom Chimique

Produit CL50: Pas Etabli
LD50

Urée
Éthylène glycol
4-Vinylcyclohexne

Rat:8471 mg/kg
Rat:4700 mg/kg
16620 mg/kg

LC50

Poids%

------------Rat:10876 mg/kg
4000 ppm rat

1-5
1-5
<0.0006

Effets cancérig ènes:
Numéro
CAS

Nom Chimique

13463-67 -7

Dioxyde de titane

100-40-3

4-Vinylcyclohexne

14808-60 -7

Silice cristalline

ACGIH

OSHA

IARC

NTP

Poids%

-----

-----

Classification pas
possible des données
actuelles.

-----

0.1-1.0

-----

Cancérog ène possible.

-----

<0.0006

-----

-----

Cancérogène connue.

<0.00001

Confirmée canc érog ène
animale avec le pertinence
inconnu aux humains.
Présumée cancérogène
humaine.

Données significatives possiblement pertinentes à l’humain: Aucun

Section 12 – Information écologique
Information écologique: Aucune dégradation de l'environnement n'est connue ou prévisible dans les conditions normales
d'utilisation.

Page 5 of 7

Section 13 – Information sur la mise au rebut
Information concernant la mise au rebut: Disposer de ce matériau en respectant les lois fédérales, provinciales et
municipales. Les lois et restrictions provinciales et municipales sont complexes et peuvent différer des lois f édérales. La
responsabilité de la disposition appropriée des déchets appartient au propriétaire des déchets.
Code de mise au rebut de l ’Agence de protection de l’environnement (40 CFR Section 261): Aucun

Section 14 – Étiquetage selon le Ministère des Transports
Nom du produit expédié:
Nom technique:
Classe de danger:

Aucun
Aucun
Pas Applicable

Groupe d’emballage:
Classe de transport:
Numéro UN/NA:

Pas Applicable
Pas Applicable
Aucun

Note : L'information d'expédition fournie est applicable pour le transport de sol domestique seulement. La catégorisation
différente peut s'appliquer si exp édié via les autres modes de et/ou de transport aux destinations non résidentielles.

Section 15 – Information sur les règlements
CERCLA - Catégories de dangers selon le SARA:
Ce produit a été revu en conformité avec les «Catégories de dangers» établies par l’Agence de protection de l’environnement et
promulguées aux Sections 311 et 312 du Superfund Amendment and Reauthorization Act de 1986 (SARA Titre III). Selon les
définitions applicables, il est considéré répondre aux cat égories suivantes :
SARA SECTION 313 :
Ce produit contient les substances suivantes assujetties aux normes de déclaration de la Section 313, du Titre III de la
Superfund Amendments and Reauthorization Act de 1986 et du 40 CFR partie 372 :
Nom Chimique
Éthylène glycol

Numéro CAS
107-21-1

Poids%
1-5

LOI SUR LE CONTRÔLE DES SUBSTANCES TOXIQUES:
Tous ingrédients dans ce produit sont ou sur la liste d'inventaire de TSCA, ou autrement exempter.
Ce produit contient les substances chimiques suivantes à déclarer selon les normes TSCA 12(B) si export é à l’extérieur des
États-Unis:
Nom Chimique
Numéro CAS
5-Chloro-2-Methyl-4-Isothazoli
2-Methyl-4-Isothiazolin-3-One

26172-55 -4
2682-20-4

Lois particulières selon les états aux États-Unis:
NEW JERSEY RIGHT-TO-KNOW :
Les substances suivantes sont non-dangereuses mais sont comptées parmi les 5 principaux ingrédients composant ce produit:
Nom Chimique
Eau
Hydrocarbon Petroleum Resin
Copolymère de styrène et de butadiène

Numéro CAS
7732-18 -5
De propriété
De propriété

Poids%
30-60
3-7
3-7

Page 6 of 7
PENSYLVANIA RIGHT-TO-KNOW:
Les substances suivantes sont non-dangereuses mais sont présentes à plus de 3% dans ce produit:
Nom Chimique
Numéro CAS
Eau
Hydrocarbon Petroleum Resin
Copolymère de styrène et de butadiène

Poids%

7732-18 -5
De propriété
De propriété

30-60
3-7
3-7

PROPOSITION 65 DE CALIFORNIE:
AVERTISSEMENT ! Les produits chimiques list és ci-dessous et contenus dans ce produit sont reconnus par l’État de la
Californie pour causer le cancer:
Nom Chimique
Numéro CAS
Définition
Dater Enuméré
Poids%
4-Vinylcyclohexne
Silice cristalline

100-40 -3
14808-60-7

Cancérog ène.
Cancérog ène.

Listed: May 1, 1996
Listed: October 1, 1988

<0.0006
<0.00001

AVERTISSEMENT ! Les produits chimiques list és ci-dessous et contenus dans ce produit sont reconnus par l’État de la
Californie pour causer le cancer, des anomalies congénitales ou d’autres problèmes reliés à la reproduction:
Aucun.

Section 16 – Autres informations
Classification des
dangers:
Santé: 1

Inflammabilité: 1

COMPOSÉ ORGANIQUE VOLATIL, G/LITRE: 34.3

Réactivité: 0
LB/GALLON: 0.3

Protection personnelle: X
POIDS %: 1.557

RAISONS DE RÉVISION: Mise à jour p ériodique
Légende:

N.A. – Non applicable

ACGIH – American Conference of Governmental Industrial Hygienists

N.É. – Non établi

SARA – Superfund Amendments and Reauthorization Act de 1986

N.D. – Non déterminé

NJRTK – New Jersey Right-to-Know Law

VOC – Composé organique volatil

OSHA – Occupational Safety and Health Administration

PEL – Limite d’exposition permise

HMIS – Hazardous Materials Identification System

TLV – Limite tolérable d’exposition

TWA – Valeur d’exposition moyenne pondérée

NTP – National Toxicology Program

F – Degré Fahrenheit

STEL – Limite d’exposition à court terme

C – Degré Celcius

LD50 – Dose létale 50

LC50 – Concentration létale 50

CASRN – Numéro enregistré selon le Chemical Abstracts Service
CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act

DAP croit que les données et renseignements stipulés dans cette fiche signal étique sont précis à la date de rédaction de cette fiche. Ces
données sont offertes en toute bonne foi et représente des valeurs standard sans toutefois être des sp écifications du produit. AUCUNE
GARANTIE SUR LA QUALITÉ MARCHANDE, GARANTIE D’APTITUDE POUR AUCUN TYPE D’EMPLOI PARTICULIER
OU TOUTE AUTRE FORME DE GARANTIE N’EST EXPRESSÉMENT OU IMPLICITEMENT OFFERTE EN REGARD DES
INFORMATIONS FOURNIES DANS CETTE FICHE OU DES INFORMATIONS RELATIVES AU PRODUIT. Cette fiche est
produite uniquement à titre de guide pour les personnes form ées à cet effet afin qu’elles puissent appliquer les procédures appropriées de
manutention auxquelles le produit réfère. Toutefois, c’est la responsabilité chaque utilisateur de revoir les recommandations selon le contexte
spécifique de l’utilisation prévue et de déterminer si ces proc édures sont appropriées.

Page 7 of 7



MATERIAL SAFETY DATA SHEET
C-98
01 00
===========================================================================
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
--------------------------------------------------------------------------PRODUCT NUMBER
HMIS CODES
Health
1
C-98
Flammability
0
Reactivity
0
PRODUCT NAME
Multi-Purpose Floor Adhesive
MANUFACTURER'S NAME
EMERGENCY TELEPHONE NO.
THE SHERWIN-WILLIAMS COMPANY
(216) 566-2917
101 Prospect Avenue N.W.
Cleveland, OH 44115
DATE OF PREPARATION
INFORMATION TELEPHONE NO.
19-APR-07
(216) 566-2902
===========================================================================
Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
--------------------------------------------------------------------------28
1332-58-7 Kaolin
ACGIH TLV
2 mg/m3 as Resp. Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction
===========================================================================
Section 3 -- HAZARDS IDENTIFICATION
--------------------------------------------------------------------------ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
===========================================================================
Section 4 -- FIRST AID MEASURES
--------------------------------------------------------------------------EYES:
SKIN:
INHALATION:
INGESTION:

Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
Wash affected area thoroughly with soap and water.
If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
Do not induce vomiting.
Get medical attention immediately.

Continued on page 2

C-98
page 2
===========================================================================
Section 5 -- FIRE FIGHTING MEASURES
--------------------------------------------------------------------------FLASH POINT
LEL
UEL
Not Applicable
N.A.
N.A.
FLAMMABILITY CLASSIFICATION
Not Applicable
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Alcohol Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers may explode (due to the build-up of pressure) when
exposed to extreme heat.
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.
===========================================================================
Section 6 -- ACCIDENTAL RELEASE MEASURES
--------------------------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
===========================================================================
Section 7 -- HANDLING AND STORAGE
--------------------------------------------------------------------------STORAGE CATEGORY
Not Applicable
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep container closed when not in use. Transfer only to approved
containers with complete and appropriate labeling. Do not take internally.
Keep out of the reach of children.

Continued on page 3

C-98
page 3
===========================================================================
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
--------------------------------------------------------------------------PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
Removal of old paint by sanding, scraping or other means may generate
dust or fumes that contain lead. Exposure to lead dust or fumes may cause
brain damage or other adverse health effects, especially in children or
pregnant women. Controlling exposure to lead or other hazardous substances
requires the use of proper protective equipment, such as a properly fitted
respirator (NIOSH approved) and proper containment and cleanup. For more
information, call the National Lead Information Center at 1-800-424-LEAD
(in US) or contact your local health authority.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
Solvent resistant (B.F. Goodrich Holdfast No. 66 or equal)
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
===========================================================================
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
--------------------------------------------------------------------------PRODUCT WEIGHT
10.10 lb/gal
1210 g/l
SPECIFIC GRAVITY
1.22
BOILING POINT
212 - 213 F
100 - 100 C
MELTING POINT
Not Available
VOLATILE VOLUME
38 %
EVAPORATION RATE
Slower than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
0.00 lb/gal
0 g/l
Less Water and Federally Exempt Solvents
0.00 lb/gal
0 g/l
Emitted VOC

Continued on page 4

C-98
page 4
===========================================================================
Section 10 -- STABILITY AND REACTIVITY
--------------------------------------------------------------------------STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
===========================================================================
Section 11 -- TOXICOLOGICAL INFORMATION
--------------------------------------------------------------------------CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
--------------------------------------------------------------------------TOXICOLOGY DATA
CAS No.
Ingredient Name
--------------------------------------------------------------------------1332-58-7
Kaolin
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
===========================================================================
Section 12 -- ECOLOGICAL INFORMATION
--------------------------------------------------------------------------ECOTOXICOLOGICAL INFORMATION
No data available.
===========================================================================
Section 13 -- DISPOSAL CONSIDERATIONS
--------------------------------------------------------------------------WASTE DISPOSAL METHOD
Waste from this product is not hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Incinerate in approved facility. Do not incinerate closed container.
Dispose of in accordance with Federal, State/Provincial, and Local
regulations regarding pollution.
===========================================================================
Section 14 -- TRANSPORT INFORMATION
--------------------------------------------------------------------------US Ground (DOT)
Information is not Available
Canada (TDG)
Information is not Available
IMO
Information is not Available

Continued on page 5

C-98
page 5
===========================================================================
Section 15 -- REGULATORY INFORMATION
--------------------------------------------------------------------------SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
--------------------------------------------------------------------------No ingredients in this product are subject to SARA 313 (40 CFR 372.65C)
Supplier Notification.
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of
California to cause cancer.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
===========================================================================
Section 16 -- OTHER INFORMATION
--------------------------------------------------------------------------This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.

The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.

MAPEI® Material Safety Data Sheet (MSDS) - North America

Read complete MSDS prior to using product.

----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------Product Name:

Ultrabond ECO™ 575

Product Description: Premium Cove Base Adhesive
----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------IN THE EVENT OF A CHEMICAL EMERGENCY INVOLVING A SPILL, LEAK, FIRE, EXPLOSION, EXPOSURE OR ACCIDENT CONTACT THE
FOLLOWING NUMBERS:
EMERGENCY 24 HOUR NUMBER (USA) CHEMTREC 1-800-424-9300 (Canada) CANUTEC 1-613-996-6666
CONSUMER STATEMENT:
CAUTION
- EYE IRRITANT. NON-TOXIC.
WORK AND HYGIENE PRACTICE:
Remove contaminated clothing immediately. Wash hands, after each use and before eating, drinking, or using toiletries. Minimize contact of product
on skins.
________________________________________________________________________________________________________________________
I - GENERAL INFORMATION
MANUFACTURER:
USA and Puerto Rico
Canada
MAPEI INC.
MAPEI CORPORATION

II - PHYSICAL CHARACTERISTICS
0 g/L
Calculated VOC (See below.)
>212°F (>100°C)
Boiling Point
1,0
Vapor Pressure (mmHg)

1144 East Newport Center Drive

2900 Francis-Hughes Avenue

Deerfield Beach, FL 33442

Laval, QC H7L 3J5

Vapor Density (AIR=1)
Specific Gravity (H20=1)

Ph: (954) 246-8888

Ph: (450) 662-1212

Melting/Freezing Point (F)

N/E

Evaporation Rate (Butyl Acetate=1)
Solubility in water
pH (paste/liquid)

Same as water.
Soluble
8,0 - 10,0

Appearance and Odor

Beige paste. Slight odor of latex.

MSDS PREPARED BY:
Regulatory Affairs Department - MAPEI North America
REVISION DATE (YYYY/MM/DD): 2005/07/15
For most current MSDS, download document from: www.mapei.com

1,10 - 1,20
1,00 - 1,30

(VOC per CA South Coast Air Quality Management District, Rule 1168)
________________________________________________________________________________________________________________________
III - HAZARD ASSESSMENT
Hazardous Components
(specific chemical identity; common names):

OSHA (PEL)

ACGIH (TLVTWA)

Other Limits Recommended

% Percent
(Optional)

THIS PRODUCT CONTAINS NO HAZARDOUS INGREDIENTS AS DEFINED BY US OSHA HAZARD COMMUNICATION STANDARD - 29 CFR
1910.1200 OR SECTION 13 OF THE CANADIAN HAZARDOUS PRODUCTS ACT.
For California (Proposition 65): This product contains no chemicals reportable under Proposition 65.
All ingredients are listed within or exempted from US TSCA and Canadian DSL.
(USA) - HMIS (Hazardous Materials Identification System) Rating:

Health - 1

Fire - 0

Reactivity - 0

Protection - B

"*" = chronic effect

(Canada) - WHMIS (Workplace Hazardous Materials Information System) Classifications: Not regulated under WHMIS.
________________________________________________________________________________________________________________________
IV - TRANSPORTATION
By GROUND - USA and Puerto Rico (DOT):
Not Regulated

By SEA (IMDG):
Not Regulated

By GROUND - Canada (TDG):
Not Regulated

By AIR (IATA):
Not Regulated

________________________________________________________________________________________________________________________
V - FIRE AND EXPLOSION HAZARD DATA
Lower Explosive Limit (%) - N/E
Upper Explosive Limit (%) Flash Point: >212°F (>100°C)
Unusual Fire and Explosion Hazards - Some decomposition products may be harmful.

N/E

Extinguishing Media:
Will not burn except under extreme temperatures. Water spray, carbon dioxide, dry chemical or foam.
Special Fire Fighting Procedures:
Wear standard fire fighting gear with self-contained breathing apparatus.
________________________________________________________________________________________________________________________
VI - REACTIVITY DATA

Stability: Stable

Conditions to Avoid: None known.

----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------English Version on pages 2 and 3.
Page 2 of 7
Ultrabond ECO™ 575
Version Française à la pages 4 et 5.
La versión en Español en las páginas 6 y 7.

MSDS

Page 2 de 7
Páginas 2 de 7

Incompatibility (Materials to Avoid): Strong oxidizing agents, strong acids, and strong bases.
Hazard Decomposition of By-products: Carbon monoxide, carbon dioxide, oxides of nitrogen, and other unidentified organic compounds.
Polymerization: Will Not Occur
Conditions to Avoid: None known.
________________________________________________________________________________________________________________________
VII - HEALTH HAZARD DATA
Routes of entry during normal usage:

Inhalation? YES

Skin? YES

Ingestion?

NO

Health Hazards:
Acute:
No effects are suspected under normal professional use.
Chronic:

None known.

Carcinogenicity:

NTP - NO

IARC - NO

OSHA - NO

Signs and Symptoms of Overexposure:
No effects are suspected under normal professional use.
Medical Conditions That Can Be Aggravated by Exposure:
Allergies, skin and respiratory disorders. Product sensitivity.
________________________________________________________________________________________________________________________
VIII - EMERGENCY AND FIRST AID PROCEDURE
Eyes:

Flush with cool water for 15 minutes while holding eyelid open. If irritation persists, seek medical attention immediately.

Skin:

Avoid contact with skin. Remove contaminated clothing. Wash affected area thoroughly with soap and water. If irritation persists, seek
immediate medical attention.
Inhalation: Remove to fresh air if allowable concentrations of any of the hazardous ingredients are exceeded. If not breathing, trained personnel
should initiate artificial respirations and immediate medical attention should be obtained.
Ingestion: Do not induce vomiting. Do not give anything by mouth to an unconscious person. Seek medical attention immediately.
________________________________________________________________________________________________________________________
IX - PRECAUTIONS FOR SAFE HANDLING AND USE
Steps to be taken if Material is Leaked or Spilled:
Wear protective equipment. Contain by diking with inert absorbent materials and put into an approved waste container.
Waste Disposal Method: Dispose in accordance to local environmental regulation.
Precautions to be taken during Handling and Storage:
Keep container closed when not in use. Store at 60-95°F (15-35°C) and out of the sun. Use adequate ventilation to avoid breathing vapors when cover
is removed.
Avoid prolonged skins contact.
Other Precautions:
_______________________________________________________________________________________________________________________
X - CONTROL MEASURES
Respiratory Protection:
If workplace exposure limit of product is exceeded, a NIOSH/MSHA approved air supplied respirator is required in absence of proper environmental
control. Engineering or administrative controls should be implemented to reduce exposure.
Local Exhaust - Use in WELL VENTILATED areas only.
Mechanical - Use only intrinsically safe devices.
Ventilation:
Special -

N/A

Other -

N/A

Eye Protection: Safety glasses or goggles as necessary to prevent eye contact.
Protective Gloves: Impervious. (Nitrile, rubber, or better)
As needed to minimize contact with skin.
Other Protective Equipment:
_______________________________________________________________________________________________________________________
N/A="Not Applicable"

N/E="Not Established"

The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of these
data or the results to be obtained from the use thereof. MAPEI assumes no responsibility for personal injury or property damage to vendees, users, or
third parties caused by the material. Such vendees or users assume all risks associated with the use of the material.

----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------English Version on pages 2 and 3.
Page 3 of 7
Ultrabond ECO™ 575
Version Française à la pages 4 et 5.
La versión en Español en las páginas 6 y 7.

MSDS

Page 3 de 7
Páginas 3 de 7

MATERIAL SAFETY DATA SHEET

HAZARD RATINGS HMIS
Health

1

Flammability

0

Reactivity

0

PPE

X

1 CHEMICAL PRODUCT & COMPANY IDENTIFICATION
Product

DP60776

MSDS Name

D-650 CLEAR VCT ADH (EX LE-5000)

CAS #

Mixture

Product Use

DURABOND Flooring Adhesive

Generic Description

Rubber Emulsion

Manufacturer

BOSTIK FINDLEY, INC.
211 Boston Street
Middleton , MA 01949 USA

24 Hour Emergency Assistance
Phone:

1-800-227-0332

General Assistance
Phone:

1-978-777-0100

Phone:

1-978-777-0100

MSDS Assistance

2 COMPOSITION / INFORMATION ON INGREDIENTS
No hazardous ingredients as per 29 CFR 1910.1200.

3 HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Extended contact with this material may cause irritation to the skin, eyes, and mucous membranes.
POTENTIAL HEALTH EFFECTS
Skin Contact: Prolonged or repeated skin contact may cause irritation.
Eye Contact: May cause irritation with temporary redness with stinging and tearing.
Inhalation: This product is not expected to cause respiratory tract irritation under conditions of intended use.
Ingestion: Exposure is unlikely. This product can cause gastrointestinal irritation, nausea, vomiting, and diarrhea.
TARGET ORGANS
None known for product as a whole.

4 FIRST AID MEASURES
SKIN
Remove contaminated clothing to prevent further skin exposure and dispose of properly. In situations involving
considerable skin contact, place the contaminated person in a deluge shower for at least 15 minutes. For minor
exposures, wash thoroughly with soap and clean water. Get medical attention if irritation persists.
EYE
Immediately flush with plenty of water for at least 15 minutes, holding eyelids open at all times. Get medical
attention immediately.
MSDS Number
Label Number

24126

Product

DP60776

24126

NA = Not Available

ND = Not Determined

1/5

INHALATION
Not normally required. Remove to fresh air. Get medical attention if cough or other symptoms develop.
INGESTION
No harmful effect is anticipated. If ingested, get immediate medical attention. Do not induce vomiting unless
instructed to do so by medical personnel. Never give anything by mouth to a victim who is unconscious or is
having convulsions.
NOTES TO PHYSICIAN
None

5 FIRE FIGHTING MEASURES
HAZARDOUS COMBUSTION PRODUCTS
Decomposition can produce hazardous chemicals. Carbon monoxide, carbon dioxide, and other unknown
products may be produced during combustion.
EXTINGUISHING MEDIA
This product is a water dispersion and as such will not burn until all water has boiled away. Residual solid and
container can support combustion. Use dry chemical, carbon dioxide, water spray, or foam.
DUST EXPLOSION HAZARD
None Known
SENSITIVITY TO MECHANICAL IMPACT
None Known
SENSITIVITY TO STATIC DISCHARGE
None Known
UNUSUAL FIRE & EXPLOSION HAZARDS
During a fire, irritating and highly toxic gases may be generated during combustion or decomposition. High
temperatures can cause sealed containers to rupture due to a buildup of internal pressures. Cool with water.
FIRE FIGHTING EQUIPMENT/INSTRUCTIONS
Firefighters should wear full protective clothing including self contained breathing apparatus.
Flash Point

> 200 F (> 93 C)

6 ACCIDENTAL RELEASE MEASURES
EMERGENCY ACTION
Appropriate safety measures and protective equipment should be used. See Section 8. Do not discharge to lakes,
streams, ponds, or sewers. Dispose of in compliance with local, state, and federal regulations.
CLEAN-UP PROCEDURES
Scrape up the spilled material. Put material in suitable, covered, labeled containers. Wash site of spill with strong
soap solution.

7 HANDLING & STORAGE
For Commercial Use Only - Not Packaged or Labeled for Home Use!
MSDS Number
Label Number

24126

Product

DP60776

24126

NA = Not Available

ND = Not Determined

2/5

HANDLING
Wash hands thoroughly after handling, especially before eating, drinking, smoking, and using restroom facilities.
Wash contaminated goggles, face shields, and gloves. Professionally launder contaminated clothing before
re-use.

STORAGE
Keep material from freezing. Store under normal working temperatures in a well-ventilated area. Do not pressurize
drums. Avoid contact with any copper or brass.
EMPTY CONTAINER PRECAUTION
Attention! Follow label warnings even after container is emptied since empty containers may retain product
residues. Do not reuse empty container without professional cleaning for food, clothing, or products for human or
animal consumption, or where skin contact can occur.

8 EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
Local exhaust ventilation is recommended when vapors, mists, or dusts can be released.

EYE PROTECTION: PERSONAL PROTECTION EQUIPMENT (PPE)
Wear goggles or safety glasses with side shields.
SKIN PROTECTION: PERSONAL PROTECTION EQUIPMENT (PPE)
Wear protective impervious gloves to minimize skin exposure.
RESPIRATORY PROTECTION: PERSONAL PROTECTION EQUIPMENT (PPE)
None required where adequate ventilation conditions exist. If airborne concentrations are above the applicable
exposure limits, use NIOSH approved respiratory protection.
GENERAL
Eyewash fountains and emergency showers should be readily available.

9 PHYSICAL & CHEMICAL PROPERTIES
Boiling Point

212 F (100 C)

Solubility In Water

Disperses in Water

Freezing Point

32 F (0 C)

Density

1.028 g/cc

Odor Threshold

NA

Octanol/Water Coefficient

NA

Odor

Mild

Color

Clear

Physical State

Paste

Freeze Protect

No

MSDS Number
Label Number

24126

Product

DP60776

24126

NA = Not Available

ND = Not Determined

3/5

10 STABILITY & REACTIVITY
STABILITY/INCOMPATABILITY
Stable under normal conditions. Coagulation may occur following freezing, thawing, or boiling. Avoid water,
amines, strong bases, alcohols and metallics hydrides.
HAZARDOUS REACTIONS/DECOMPOSITION PRODUCTS
If product is burned carbon monoxide, carbon dioxide, and other unknown products may be produced.
HAZARDOUS POLYMERIZATION
Will not occur.
CONDITIONS TO AVOID
None.

11 TOXICOLOGICAL INFORMATION
TOXICOLOGICAL DATA
If any toxicological data is available, it will be listed below:
CARCINOGENICITY
No regulated ingredients.

12 ECOLOGICAL INFORMATION
VOC (Volatile Organic Compounds)

0 g/l

ECOTOXICOLOGICAL INFORMATION
No data available for this product.

13 DISPOSAL CONSIDERATIONS
We make no guarantee or warranty of any kind that the use or disposal of this product complies with all local,
state, or federal laws. It is also the obligation of each user of the product mentioned herein to determine and
comply with the requirements of all applicable statutes.
WASTE DISPOSAL
This product as supplied is not considered a hazardous waste under RCRA. Liquid adhesive should not be
disposed of in a landfill. Do not discharge to streams, lakes, ponds, or sewers. Disposal of unused portions of this
product and process waste containing this product should be done only after a careful evaluation and in
compliance with all federal, local, and state laws.

14 TRANSPORT INFORMATION
Proper Shipping Name
Hazard Class

Non-Regulated
Not Applicable

15 REGULATORY INFORMATION
All components are on the U.S. EPA TSCA Inventory List.
This MSDS is prepared and distributed pursuant to the Federal Hazard Communication Standard, 29 CFR
1910.1200.
MSDS Number
Label Number

24126

Product

DP60776

24126

NA = Not Available

ND = Not Determined

4/5

STATE REGULATIONS
If this product contains any ingredients listed under California Proposition 65, they will be noted below:
California - Prop. 65 - Cancer list
1,3-BUTADIENE
1,4-DIOXANE
SILICA, QUARTZ

106-99-0
carcinogen; initial date 4/1/88
123-91-1
carcinogen; initial date 1/1/88
14808-60-7 carcinogen (airborne particles of respirable size); initial date
10/1/88

INTERNATIONAL REGULATIONS
This is not a controlled product under the Canadian Workplace Hazardous Materials Information System (WHMIS).
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and
contains all the information required by the Controlled Products Regulations.
SARA 302 EXTREMELY HAZARDOUS SUBSTANCES
Not Regulated
SARA 311/312 HAZARD CATEGORIES
Immediate Hazard

No

Delayed Hazard

No

Fire Hazard

No

Pressure Hazard

No

Reactivity Hazard

No

SARA 313 TOXIC CHEMICALS
Not Regulated

16 OTHER INFORMATION
DISCLAIMER
The data in this MSDS has been compiled from publicly available sources. This data relates only to the
designated product and not to the use of said product in combination with other materials. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described herein, we
cannot guarantee that these are the only hazards which exist. Responsibility for proper precautions and safe use
of the product lies with the user. All data in this MSDS is typical of the product as a whole, and does not
represent any individual lot or batch, therefore, Bostik Findley, Inc. makes no warranty about the accuracy of the
data herein and assumes no liability for the use of such data. It is the responsibility of the user to comply with all
applicable federal, state, and local laws and regulations.
Issue Date

01-Jul-2002

Supercedes 11-Feb-2002

Prepared By

Aurora Flores

MSDS Sections Reviewed and/or Updated
Chemical Product & Company Identification: Product & Company Identification

MSDS Number
Label Number

24126

Product

DP60776

24126

NA = Not Available

ND = Not Determined

5/5

Material Safety Data Sheet

456

TYPE I
DUAL PURPOSE
FLOOR AND WALL
CERAMIC MASTIC

I. PRODUCT IDENTIFICATION
Number: 456
Name: APAC Type I Dual Purpose Floor and
Wall Ceramic Mastic
Class: Acrylic Emulsion Latex Adhesive
Emergency Telephone CHEMTREC:
800-424-9300
II. HMIS (0=minimal hazard; 4= severe)
Health = 1 Flammability = 0 Reactivity = 0
Pers. Prot. Equip: B
III. HAZARDOUS INGREDIENTS
Ingredient (CAS #) Percent: Occ. Exp. Lmt.
PEL TLV Units
Mineral Spirits
<4% 100 100 ppm
(8052-41-3)
IV. PHYSICAL DATA
BOILING RANGE: 212˚F. VAPOR PRESSURE:
heavier than air. EVAPORATION RATE: slower
than ether. WT/GAL.: 12.85 lbs. VOC: 56
gram/liter wet; 35 gram/liter dry coating solids.
Percent Solids: 70.5% Non-Photochemically
Reactive.
V. FIRE AND EXPLOSION HAZARD DATA
FLAMMABILITY CLASSIFICATION: Nonflammable.
FLASH
POINT:
>140˚F.
EXTINGUISHING MEDIA: Does not support
combustion in wet state. EXTINGUISHING
MEDIA: For dry adhesive – Foam, CO2, Dry
Chemical, Water Fog. UNUSUAL FIRE AND
EXPLOSION HAZARDS: none. SPECIAL FIRE
FIGHTING PROCEDURES: Self contained
positive pressure breathing apparatus.
VI. HEALTH HAZARD DATA
Product not considered carcinogenic by NPT,
IARC, or OSHA. EFFECTS OF OVEREXPOSURE:
May cause irritation to eyes, skin, and respiratory tract if inhaled. Ingestion: Ethylene Glycol
can cause gastrointestinal distress, nausea,
vomiting, diarrhea, and in sufficient quantities
death. PRIMARY ROUTES OF ENTRY: inhalation and ingestion. MEDICAL CONDITIONS
PRONE TO AGGRAVATION BY EXPOSURE:
none know. EMERGENCY FIRST AID PROCEDURES: Eye Contact – flush eye with water for
15 minutes. Skin Contact – wash thoroughly
with soap and water. Inhalation – remove to
fresh air, give oxygen. Contact physician or poison control center immediately. Ingestion – if
swallowed, DO NOT induce vomiting.

VII. REACTIVITY DATA
STABILITY: Stable. CONDITION TO AVOID:
Excessive heat or freezing temperatures.
INCOMPATIBILITY: (Materials to avoid) Strong
oxidizers, acids, and alkalis.
VIII. SPILL OR LEAK PROCEDURES
SPILLS: Scrape up excess and place in DOT
approved container. Remove to safe place
where material can dry. WASTE DISPOSAL
METHOD: Dispose of as per local, state and
federal regulations. Do not flush adhesive
down drains.
IX. SPECIAL PROTECTION INFORMATION:
VENTILATION: Use with adequate ventilation.
Open doors and windows to create cross
ventilation during use and until adhesive dries.
PROTECTIVE GLOVES: Use chemical-resistant
gloves if needed to avoid repeated or prolonged
skin contact. EYE PROTECTION: Use splash
goggles or face shield when eye contact may
occur. OTHER PROTECTIVE CLOTHING OR
EQUIPMENT: None required. WORK /
HYGIENIC PRACTICES: Thorough washing of
the skin with soap and water.
IX. SPECIAL PRECAUTIONS:
HANDLING AND STORING: Avoid extreme
heat or cold. OTHER PRECAUTIONS: Keep out
of reach of children. Use only as directed on
label. Close container after each use. Do not
reuse container. Avoid skin and eye contact.
X. TRANSPORTATION DATA
D.O.T.: unregulated
SHIPPING NAME: Adhesive
APAC believes that data set forth herein is accurate as of the date hereof, and makes no warranty with respect thereto and expressly disclaims all liability for reliance thereon. Such
data are offered solely for your consideration,
investigation and verification.
N/A not applicable or not available
N/K none known or not known

02-23-05

www.apacadhesives.com

All Purpose Adhesive Company • 2424 Lakeland Road • Dalton, GA 30721 • 800-747-APAC • Fax: 706-277-4157

MATERIAL SAFETY DATA SHEET
Date Prepared: September 29, 2005
1. PRODUCT/COMPANY IDENTIFICATION
Product Name:

Bonsal ® Superior Unsanded Tile Grout
(Various Colors)

Emergency Telephone:
800-424-9300 (Chemtrec) or
703-527-3887 (Outside USA)

Manufacturer’s Name & Address:
Bonsal American/ an Oldcastle Company
8201 Arrowridge Blvd.
Charlotte, NC 28273

Telephone Number for Information:
704-525-1621

2. EMERGENCY AND FIRST AID
EMERGENCY INFORMATION:

Bonsal® Superior Unsanded Tile Grout is a cementitious powder
blend. When in contact with moisture in eyes or on skin, or when
mixed with water, it becomes highly caustic (pH > 12) and will
damage or burn (as severely as third-degree) the eyes or skin.
Inhalation may cause irritation to the moist mucous membranes
of the nose, throat and upper respiratory system or may cause or
may aggravate certain lung diseases or conditions. Use exposure
controls or personal protection methods described in Section 12.

EYES:

Immediately flush eye thoroughly with water. Continue flushing
eye for at least 15 minutes, including under lids, to remove all
particles. Call physician immediately.

SKIN:

Wash skin with cool water and pH-neutral soap or a mild
detergent. Seek medical treatment if irritation or inflammation
develops or persists. Seek immediate medical treatment in the
event of burns.

INHALATION:

Remove person to fresh air. If breathing is difficult, administer
oxygen. If not breathing, give artificial respiration. Seek medical
help if coughing and other symptoms do not subside. Inhalation
of large amounts of Bonsal ® Superior Unsanded Tile Grout
require immediate medical attention.

INGESTION:

Do not induce vomiting. If conscious, have the victim drink
plenty of water and call a physician immediately.

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3. COMPOSITION INFORMATION
DESCRIPTION:

This product consists of a heterogeneous mixture of hydraulic
cement and sand. The major compounds are:
3CaO•SiO2
2CaO•SiO2
3CaO•Al2O3
4CaO•Al2O3•Fe2O3
CaSO4•2H2O
SiO2

Tricalcium Silicate
Dicalcium Silicate
Tricalcium Aluminate
Tetracalcium
aluminoferrite
Calcium Sulfate
dihydrate (Gypsum)
Silica Sand

CAS #12168-85-3
CAS #10034-77-2
CAS #12042-78-3
CAS #12068-35-8
CAS #7778-18-9
(CAS #13397-24-5)
CAS #14808-60-7

4. HAZARDOUS INGREDIENTS
COMPONENT

OSHA PEL

ACGIH TLV-TWA

NIOSH REL

-------------------Hydraulic Cement

------------------------5 mg respirable dust/m3
15 mg total dust/m3

-----------------------10 mg total dust/m3

------------------------

Calcium sulfate (CAS #7778-189) [Gypsum (CAS #13397-24-5)]

5 mg respirable dust/m3
15 mg total dust/m3

10 mg total dust/m3

_________

0.5 mg/m3

Iron oxide , Mineral Oxides,
and/or Carbon Black

Calcium carbonate (CAS #131765-3)

Magnesium oxide (CAS #130948-4)

Calcium oxide (CAS #1306-78-8)

Crystalline silica (CAS #1480860-7)

5 mg respirable dust/m3
15 mg total dust/m3

10 mg total dust/m3

15 mg total dust/m3

10 mg total dust/m3

5 mg/m3

2 mg/m3

10 mg of respirable dust/m3
% SiO2 + 2

0.5 mg respirable
quartz/m3

0.05 mg respirable quartz
dust/m3

TRACE INGREDIENTS:
Due to the use of substances mined from the earth’s crust, trace amounts of naturally occurring, potentially
harmful constituents may be detected during chemical analysis.

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5. HAZARD IDENTIFICATION
POTENTIAL HEALTH EFFECTS:

NOTE: Potential health effects may vary depending upon the
duration and degree of exposure. To reduce or eliminate health
hazards associated with this product, use exposure controls or
personal protection methods as described in Section 12.

EYE CONTACT:

(Acute/Chronic) Exposure to airborne dust may cause immediate
or delayed irritation or inflammation of the cornea. Eye contact by
larger amounts of dry powder or splashes of wet Unsanded Tile
Grout may cause effects ranging from moderate eye irritation to
chemical burns and blindness.

SKIN CONTACT:

(Acute) Exposure to dry Bonsal® Superior Unsanded Tile Grout
may cause drying of the skin with consequent mild irritation or
more significant effects attributable to aggravation of other
conditions. Discomfort or pain cannot be relied upon to alert a
person to a hazardous skin exposure.
(Chronic) Dry Bonsal® Superior Unsanded Tile Grout coming in
contact with wet skin or exposure to wet Unsanded Tile Grout may
cause more severe skin effects, including thickening, cracking or
fissuring of the skin. Prolonged exposure can cause severe skin
damage in the form of chemical (caustic) burns.
(Acute/Chronic) Some individuals may exhibit an allergic response
upon exposure to Bonsal® Superior Unsanded Tile Grout . The
response may appear in a variety of forms ranging from a mild
rash to severe skin ulcers.

INHALATION:

(Acute) Exposure to Bonsal® Superior Unsanded Tile Grout may
cause irritation to the moist mucous membranes of the nose, throat
and upper respiratory system. Pre-existing upper respiratory and
lung diseases may be aggravated by inhalation.
(Chronic) Inhalation exposure to free crystalline silica may cause
delayed lung injury including silicosis, a disabling and potentially
fatal lung disease, and/or cause or aggravate other lung diseases or
conditions.

INGESTION:

(Acute/Chronic) Internal discomfort or ill effects are possible if
large quantities are swallowed.

CARCINOGENIC POTENTIAL:

Bonsal® Superior Unsanded Tile Grout is not recognized as a
carcinogen by NTP, OSHA, or IARC. However, it may contain
trace amounts of heavy metals recognized as carcinogens by these
organizations. In addition, it also contains crystalline silica which
IARC classifies as a known human carcinogen (Group I). The
NTP, in it’s ninth Annual Report on Carcinogens, classified
“silica, crystalline (respirable)” as a known carcinogen. (See also
Sections 4 and 12.)

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6. ACCIDENTAL RELEASE MEASURES
Contain material to prevent contamination of soil, surface water or ground water. Use dry clean-up methods that do
not disperse dust into the air or entry into surface water. Material can be used if not contaminated. Place in an
appropriate labeled container for disposal or use. Avoid inhalation of dust and contact with skin and eyes. Use
exposure control and personal protection methods as described in Section 12.

7. PHYSICAL/CHEMICAL DATA
APPEARANCE/ODOR:

Gray, odorless

PHYSICAL STATE:

Solid (Powder mixed with sand.)

BOILING POINT:

> 1000°C

MELTING POINT:

> 1000°C

VAPOR PRESSURE:

Not applicable

VAPOR DENSITY:

Not applicable

pH (IN WATER)
(ASTM D 1293-95)

12 to 13

SOLUBILITY IN WATER:

Slightly soluble (0.1% to 1.0%)

SPECIFIC GRAVITY
(H2O = 1.0):

2.5 – 2.8

EVAPORATION RATE:

None

8. FIRE AND EXPLOSION
FLASH POINT:

None

LOWER EXPLOSIVE LIMIT:

None

AUTO IGNITION
TEMPERATURE:

Not combustible

UPPER EXPLOSIVE LIMIT:

None

FLAMMABLE LIMITS

Not applicable

SPECIAL FIRE FIGHTING
PROCEDURES:

None

EXTINGUISHING
MEDIA:

Not combustible

UNUSUAL FIRE AND
EXPLOSION HAZARDS:

None

HAZARDOUS
COMBUSTION
PRODUCTS:

None

9. STABILITY AND REACTIVITY DATA
STABILITY:

Product is stable. Keep dry until used.

CONDITIONS TO AVOID:

Unintentional contact with water. Contact with water will result
in hydration and produces (caustic) calcium hydroxide.

INCOMPATIBILITY:

Wet Unsanded Tile Grout is alkaline. As such, it is incompatible
with acids, ammonium salts and aluminum metal.

HAZARDOUS DECOMPOSITION:

Will not occur.

HAZARDOUS POLYMERIZATION:

Will not occur.

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10. PRECAUTIONS FOR HANDLING AND STORAGE
Keep dry until used. Handle and store in a manner so that
airborne dust does not exceed applicable exposure limits. Use
adequate ventilation and dust collection. Use exposure control
and personal protection methods as described in Section 12.

HANDLING AND STORAGE

11. TOXICOLOGICAL INFORMATION
See Section 5 for Hazard Identification. No recognized unusual toxicity to plants and animals.
Conditions aggravated by exposure: Eye disease, Skin disorders and Chronic Respiratory conditions.

12. EXPOSURE CONTROLS/PERSONAL PROTECTION
RESPIRATORY PROTECTION:

Use local exhaust or general dilution ventilation to control dust
levels below applicable exposure limits. Minimize dispersal of
dust into the air.
If local or general ventilation is not adequate to control dust
levels below applicable exposure limits or when dust causes
irritation or discomfort, use MSHA/NIOSH approved respirators.

EYE PROTECTION:

Wear safety glasses with side shields or goggles to avoid contact
with the eyes. In extremely dusty environments and
unpredictable environments, wear tight-fitting unvented or
indirectly vented goggles to avoid eye irritation or injury.
Contact lenses should not be worn when handling cement or
cement containing products.

SKIN PROTECTION:

Wear impervious abrasion- and alkali-resistant gloves, boots,
long-sleeved shirt, long pants or other protective clothing to
prevent skin contact. Promptly remove clothing dusty with dry
Unsanded Tile Grout or clothing dampened with moisture mixed
with Unsanded Tile Grout, and launder before re-use. If contact
occurs, wash areas contacted by material with pH neutral soap
and water.

13. DISPOSAL CONSIDERATIONS
DISPOSAL:

DO NOT DUMP INTO ANY SEWERS, ON THE GROUND,
OR INTO ANY BODY OF WATER. All disposal methods
must be in compliance with all Federal, State/ Provincial and
local laws and regulations. Regulations may vary in different
locations. Waste characterizations and compliance with
applicable laws are the responsibility solely of the waste
generator.

IF THIS MATERIAL AS PACKAGED, BECOMES A WASTE, IT DOES NOT MEET THE CRITERIA FOR A HAZARDOUS
WASTE AS DEFINED BY THE ENVIRONMENTAL PROTECTION AGENCY UNDER THE AUTHORITY OF THE RESOURCE
CONSERVATION AND RECOVER ACT (40CFR 261), DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATIONS.

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Comply with all applicable local, state and federal regulations for disposal of unusable or contaminated materials.
Dispose of packaging/containers according to local, state and federal regulations.

14. TRANSPORTATION DATA
Bonsal® Superior Unsanded Tile Grout is not hazardous under U.S. DOT or TDG regulations.

15. OTHER REGULATORY INFORMATION
Status under US OSHA Hazard
Communication Rule 29 CFR 1910.1200:

Bonsal® Superior Unsanded Tile Grout is considered a
hazardous chemical under this regulation and should be included
in the employer's hazard communication program.

Status under CERCLA/Superfund, 40 CFR
117 and 302:

Not listed.

Hazard Category under SARA (Title III),
Sections 311 and 312:

Bonsal® Superior Unsanded Tile Grout qualifies as a hazardous
substance with delayed health effects.

Status under SARA (Title III), Section 313:

Not subject to reporting requirements under Section 313.

Status under TSCA (as of May 1997):

Some substances in Bonsal® Superior Unsanded Tile Grout are
on the TSCA inventory list.

Status under the Federal Hazardous
Substances Act:

Bonsal® Superior Unsanded Tile Grout is a hazardous substance
subject to statutes promulgated under the subject act.

Status under California Proposition 65:

This product contains crystalline silica, a substance known to the
State of California to cause cancer. This product also may
contain trace amounts of heavy metals known to the State of
California to cause cancer, birth defects or other reproductive
harm.

Status under Canadian Environmental
Protection Act:

Not listed.

Status under Canadian WHMIS:

Bonsal® Superior Unsanded Tile Grout is considered to be a
hazardous material under the Hazardous Products Act as defined
by the Controlled Products Regulations (Class D2A, E Corrosive Material) and subject to the requirements of WHMIS.

16. OTHER INFORMATION
The information and recommendations contained herein are based upon data believed to be correct. However, no
guarantee or warranty of any kind, express or implied, is made with respect to the information contained herein. It is
the user’s obligation to determine the conditions of safe use of this product.

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