MATERIAL SAFETY DATA SHEET OF X Regalia SDS

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Document Control Number: MBI-SDS-0050
Revision: 4
Date Issued: 23 Feb 2016
SAFETY DATA SHEET
Page 1 of 6
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: Regalia ® (lot code formats 106-O5-XXXXXX-XX or 1065-XXXX-XX)
REGISTRATION NO: 84059-3
MANUFACTURER: Marrone Bio Innovations
ADDRESS: 1540 Drew Ave., Davis, CA 95618
EMERGENCY PHONE: INFOTRAC Chemical Response System
US and Canada 1-800-535-5053 (24 hours)
International 1-352-323-3500 (24 hours)
OTHER CALLS: Marrone Bio Innovations 530-750-2800 (9am to 5 pm PST)
FAX PHONE: Marrone Bio Innovations 530-750-2808
PRODUCT USE: Bio-based fungicide
SECTION 2: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes eye irritation (Category 2B)
Mild skin irritation (Category 3)
Harmful if inhaled (Category 4)
Harmful to aquatic life (Category 3)
HAZARD SYMBOLS
Pictogram
Signal Word
Warning
HAZARD STATEMENTS
H316 Causes mild skin irritation
H320 Causes eye irritation
H332 Harmful if inhaled
H402 Harmful to aquatic life.
PRECAUTIONARY STATEMENTS.
P261 Avoid breathing dust, fumes, gas, mist, vapors or spray
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release into the environment.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable
for breathing.
P312 Call a doctor if you feel unwell.
Document Control Number: MBI-SDS-0050
Revision: 4
Date Issued: 23 Feb 2016
SAFETY DATA SHEET
Page 2 of 6
P305 + P351 + PP338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses if present, and easy to do. Continue rinsing.
P332 + P313 If skin irritation occurs, seek medical advice/ attention.
P337 + P313 If eye irritation persists: Get medical attention.
P501 Dispose of contents/ container to an approved waste disposal plant.
CARCINOGENICITY:
OSHA: Not listed ACGIH: Not listed NTP: Not listed. IARC: Not listed
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
Synonyms:
MBI-106-O5-SH, MBI-106-O5-HF
COMPONENT
CAS NUMBER
Reynoutria spp. Extract
N/A
Other (inert ingredients)
Several (Not applicable)
SECTION 4: FIRST AID MEASURES
EYES: Hold eye open and rinse slowly and gently with water for at least 15 minutes. Remove contact lenses, if
present, after the first 5 minutes, then continue rinsing eyes. Do not use an eye ointment. Call poison control
center or doctor for treatment advice.
SKIN: Remove contaminated clothing. Rinse skin immediately with plenty of water for at least 15-20 minutes. Call
a poison control center or doctor for treatment advice.
INGESTION: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of
water if able to swallow. Do not induce vomiting unless told to by a poison control center or physician. Do not give
anything by mouth to an unconscious person.
INHALATION: Remove person to fresh air. If the person is not breathing, call 911 or an ambulance, then give
artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for treatment.
SECTION 5: FIRE-FIGHTING MEASURES
FLAMMABLE LIMITS IN AIR, (% BY VOLUME)
UPPER: Not applicable.
LOWER: Not applicable.
IGNITABILITY: 205 °F or 96 °C
METHOD USED: METHOD USED: SW 1010
AUTOIGNITION TEMPERATURE: Not applicable.
EXTINGUISHING MEDIA: Use Foam, Carbon Dioxide, or Dry Chemical extinguishers.
SPECIAL FIRE FIGHTING PROCEDURES: None
Document Control Number: MBI-SDS-0050
Revision: 4
Date Issued: 23 Feb 2016
SAFETY DATA SHEET
Page 3 of 6
UNUSUAL FIRE AND EXPLOSION HAZARDS: None
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon dioxide, carbon monoxide, smoke, fumes, and
hydrocarbons and terpenes.
SECTION 6: ACCIDENTAL RELEASE MEASURES
ACCIDENTAL RELEASE MEASURES: Wear suitable clothing such as eye protection, long-sleeved shirt, pants
and shoes with socks. If spilled, contain - prevent run off into drains and waterways. Absorb liquid with an inert
absorbent material. Seal absorbent material in a closed labeled container and dispose of in accordance with local
ordinances.
SECTION 7: HANDLING AND STORAGE
HANDLING AND STORAGE: Store in the closed, original container in a well-ventilated area out of direct
sunlight. Keep containers closed when not in use. Empty container completely and dispose of in accordance with all
applicable federal, state and local environmental regulations.
OTHER PRECAUTIONS: No special precautions.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: Spill controls should be provided for working with large quantities.
VENTILATION: No TLV assigned. Provide exhaust ventilation or other engineering controls to keep the
airborne concentrations of vapors and aerosols below the exposure levels. Ensure that eyewash stations and safety
showers are proximal to the work-station location.
RESPIRATORY PROTECTION: Vapor respirator. Be sure to use an approved/certified respirator or equivalent.
EYE PROTECTION: Safety goggles or glasses with side shields advisable when handling liquid.
SKIN PROTECTION: Wear gloves made of Latex or other impervious material.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Clothing to prevent prolonged skin contact as needed such
as long-sleeved shirt, long pants and shoes with socks.
WORK HYGIENIC PRACTICES: Wash any contamination from skin or eyes immediately. Wash hands and
exposed skin before eating, drinking, smoking, after work, or using the toilet.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
COLOR: Brown
ODOR: Straw-like; spicy
pH: 4.9 to 6.5
DENSITY: 1.04 to 1.08 g/mL
SOLUBILITY IN WATER: Miscible in water
Document Control Number: MBI-SDS-0050
Revision: 4
Date Issued: 23 Feb 2016
SAFETY DATA SHEET
Page 4 of 6
BOILING POINT/RANGE: Not determined
FREEZING/MELTING POINT: Not determined
FLASH POINT: Not determined
EVAPORATION RATE: Not determined
FLAMMABILITY (SOLID. GAS): Not determined
UPPER FLAMMABILITY LIMITS: Not determined
LOWER FLAMABILITY LIMITS: Not determined
VAPOR PRESSURE: Not determined
VAPOR DENSITY: Not determined
RELATIVE DENSITY: Not determined
SOLUBILITY IN OTHER SOLVENTS: Not determined
PARTITION COEFFICIENT: Not determined
AUTOIGNITION TEMPERATURE: Not determined
DECOMPOSITION TEMPERATURE: Not determined
KINEMATIC VISCOSITY: Not determined
DYNAMIC VISCOSITY: Not determined
EXPLOSIVE PROPERTIES: Not determined
OXIDIZING PROPERTIES: Not determined
SECTION 10: STABILITY AND REACTIVITY
STABILITY: Stable.
INCOMPATIBILITY (MATERIAL TO AVOID): None known
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: None known
HAZARDOUS POLYMERIZATION: Not known to occur
CONDITIONS TO AVOID (POLYMERIZATION): None
SECTION 11: TOXICOLOGICAL INFORMATION
WARNING: This product causes eye irritation. This product causes mild skin irritation.
ACUTE ORAL TOXICITY LD50: >5000 mg/kg (rat). Not categorized
ACUTE DERMAL TOXICITY LD50: >5000 mg/kg (rabbit). Not categorized
ACUTE INHALATION LC50: >2.11 mg/L (rat). Category 4
EYE IRRITATION: Minimally irritating (rabbit). Category 2B
SKIN IRRITATION: Slightly irritating (rabbit). Category 3
SKIN SENSITIZATION: Non-sensitizing (guinea pigs). Not categorized
SECTION 12: ECOLOGICAL INFORMATION
This product poses acute toxicity to freshwater fish.
Avian Acute Oral Toxicity: Bobwhite quail. LD50 >2000 mg/kg-bw. Non-toxic. Category 5
Toxicity to freshwater aquatic life: Fathead minnow (96-hour acute) LC50 > 10.18 mg/L. Category 3
Rainbow trout (96-hour) EC50 = 17.885 mg/L Category 3
Daphnia magna (48-hour acute) EC50 = 50.0 mg/L AI. Category 3
Freshwater algae (72-hour acute) EC50 = 54.61 mg/L Category 3
Document Control Number: MBI-SDS-0050
Revision: 4
Date Issued: 23 Feb 2016
SAFETY DATA SHEET
Page 5 of 6
Do not apply directly to water, or to areas where surface water is present, or to intertidal areas below the mean high
water mark. Do not contaminate water when disposing of equipment wash water or rinsate.
Do not allow drift from the manufacturing site and contact people, structures people occupy at any time and the
associated property, parks and recreation areas, non-target crops, aquatic and wetland areas, woodlands, pastures,
rangelands, or animals. Minimize drift away from the manufacturing site.
Bioconcentration potential: This material is not expected to bioconcentrate in organisms.
SECTION 13: DISPOSAL CONSIDERATIONS
Do not reuse containers. Dispose of in accordance with all applicable federal, state, and local environmental
regulations.
SECTION 14: TRANSPORTATION INFORMATION
U.S. DOT: Not Regulated
IATA DGR: Not regulated
IMDG: Not Regulated
Freight Classification: Fungicide. See NMFTA code.
SECTION 15: REGULATORY INFORMATION
This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject
to certain labeling requirements under federal pesticide law. These requirements differ from the classification
criteria and hazardous information required for safety data sheets (SDS), and for workplace labels of non-pesticide
chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also
includes other important information, including directions for use.
CAUTION
Causes moderate eye irritation
INTERNATIONAL REGULATIONS
TSCA: Exempt
U.S. FEDERAL REGULATIONS
CERCLA: Not applicable.
SARA TITLE III HAZARD CLASSIFICATION SECTIONS 311 AND 312:
Immediate (acute) Health: None
Delayed (chronic) Health: None
Fire: None
Sudden Release of Pressure: None
Reactivity: None
SARA 313: Not determined
Document Control Number: MBI-SDS-0050
Revision: 4
Date Issued: 23 Feb 2016
SAFETY DATA SHEET
Page 6 of 6
U.S. STATE REGULATIONS: None
US STATE RIGHT-TO-KNOW REGULATIONS:
New Jersey Right To Know Components
Propylene glycol
CAS No.
57-55-6
Pennsylvania Right To Know Components
Propylene glycol
CAS No.
57-55-6
California Proposition 65
This product does not contain any chemicals known to State of
California to cause cancer, birth defects, or any other reproductive
harm.
SECTION 16: OTHER INFORMATION
NFPA HAZARD CLASSIFICATION
HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0
HMIS HAZARD CLASSIFICATION
HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0
SPECIAL HAZARDS: Not Determined
Date Issued: 23 Feb 2016
Revision Date: 4
Revision Note: Update lot code format
DISCLAIMER: IN NO EVENT SHALL MARRONE BIO INNOVATIONS BE LIABLE FOR ANY
INCIDENTAL, CONSEQUENTIAL OR SPECIAL DAMAGES. THE DATA PROVIDED IS FOR GENERAL
INFORMATION ONLY AND IS NOT INTENDED AS A COMPREHENSIVE GUIDE CONCERNING
HAZARDS THAT MAY BE ASSOCIATED WITH THIS PRODUCT. USER ASSUMES ALL
RESPONSIBILITY FOR FOLLOWING PROPER SAFTEY PROTOCOL AND CONSULTING TRAINED
PERSONNEL FOR CONTROL AND CONTAINMENT.

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