MATERIAL SAFETY DATA SHEET OF X Venerate XC SDS
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Page Count: 7
Document Control Number: MBI-SDS-0001
Revision: 3
Date Issued: 12 May 2016
SAFETY DATA SHEET
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: VENERATE™
REGISTRATION NO: 84059-14
MANUFACTURER: Marrone Bio Innovations
ADDRESS: 1540 Drew Avenue, Davis CA, 95618
EMERGENCY PHONE: INFOTRAC Chemical Response System
US and Canada 1-800-535-5053 (24 hours)
International 1-352-323-3500 (24 hours)
OTHER CALLS: Marrone Bio Innovations 530-750-2800 (9am to 5 pm PST)
FAX PHONE: Marrone Bio Innovations 530-750-2808
PRODUCT USE: Bio-based insecticide
SECTION 2: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW: May be minimally irritating to skin. If skin irritation occurs, get medical advice.
HAZARD SYMBOLS:
Pictogram
None
Signal Word
None
HAZARD STATEMENT: None
PRECAUTIONARY STATEMENTS: None
POTENTIAL ROUTES OF ENTRY: Oral, eye, and inhalation.
CARCINOGENICITY:
OSHA: Not listed ACGIH: Not listed NTP: Not listed. IARC: Not list
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
SYNONYM
(S): MBI-206 EP
ACTIVE INGREDIENT:
Heat-killed Burkholderia sp. strain A396
CAS NO.: None
% WT:
94.46
EXPOSURE LIMITS: None Established
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Document Control Number: MBI-SDS-0001
Revision: 3
Date Issued: 12 May 2016
SAFETY DATA SHEET
OTHER INGREDIENTS:
5.54 % inert, non-reactive
SECTION 4: FIRST AID MEASURES
EYES: Hold eye open and rinse slowly and gently with water for at least 15 minutes. Remove contact lenses, if
present, after the first 5 minutes, then continue rinsing eyes. Do not use an eye ointment. Call poison control
center or doctor for treatment advice.
SKIN: Remove contaminated clothing. Rinse skin immediately with plenty of water for at least 15-20 minutes. Call
a poison control center or doctor for treatment advice.
INGESTION: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of
water if able to swallow. Do not induce vomiting unless told to by a poison control center or physician. Do not give
anything by mouth to an unconscious person.
INHALATION: Remove person to fresh air. If the person is not breathing, call 911 or an ambulance, then give
artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for treatment.
SECTION 5: FIRE-FIGHTING MEASURES
FLAMMABLE LIMITS IN AIR, (% BY VOLUME)
UPPER: Not applicable.
LOWER: Not applicable.
FLASH POINT: Not applicable.
AUTOIGNITION TEMPERATURE: Not applicable.
NFPA HAZARD CLASSIFICATION
HEALTH: 0 FLAMMABILITY: 0 REACTIVITY: 0
HMIS HAZARD CLASSIFICATION
HEALTH: 0 FLAMMABILITY: 0 REACTIVITY: 0
EXTINGUISHING MEDIA: Use extinguishing media appropriate for the surrounding fire.
SPECIAL FIRE FIGHTING PROCEDURES: None
UNUSUAL FIRE AND EXPLOSION HAZARDS: None
HAZARDOUS DECOMPOSITION PRODUCTS: None
SECTION 6: ACCIDENTAL RELEASE MEASURES
ACCIDENTAL RELEASE MEASURES: Wear suitable clothing such as eye protection, long-sleeved shirt, pants
and shoes with socks. If spilled, contain - prevent run off into drains and waterways. Absorb liquid with an inert
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Document Control Number: MBI-SDS-0001
Revision: 3
Date Issued: 12 May 2016
SAFETY DATA SHEET
absorbent material. Seal absorbent material in a closed labeled container and dispose of in accordance with local
ordinances.
SECTION 7: HANDLING AND STORAGE
HANDLING AND STORAGE: Store in the closed, original container in a well-ventilated area out of direct
sunlight. Keep containers closed when not in use. Empty container completely and dispose of in accordance with all
applicable federal, state and local environmental regulations.
OTHER PRECAUTIONS: No special precautions.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: Spill controls should be provided for working with large quantities.
VENTILATION: No TLV assigned. Provide exhaust ventilation or other engineering controls to keep the
airborne concentrations of vapors and aerosols below the exposure levels. Ensure that eyewash stations and safety
showers are proximal to the work-station location.
RESPIRATORY PROTECTION: Use a dust/mist filtering respirator meeting NIOSH standards of at least N-95, R-
95 or P-95.
EYE PROTECTION: Safety goggles or glasses with side shields advisable when handling liquid.
SKIN PROTECTION: Wear gloves made of Latex or other impervious material.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Clothing to prevent prolonged skin contact as needed such
as long-sleeved shirt, long pants and shoes with socks.
WORK HYGIENIC PRACTICES: Wash any contamination from skin or eyes immediately. Wash hands and
exposed skin before eating, drinking, smoking, after work, or using the toilet.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
COLOR: Light brown
ODOR: Straw-like
pH: 6 to 8
DENSITY: 1 g/mL
SOLUBILITY IN WATER: Miscible in water
BOILING POINT/RANGE: Not determined
FREEZING/MELTING POINT: Not determined
FLASH POINT: Not determined
EVAPORATION RATE: Not determined
FLAMMABILITY (SOLID. GAS): Not determined
UPPER FLAMMABILITY LIMITS: Not determined
LOWER FLAMABILITY LIMITS: Not determined
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Document Control Number: MBI-SDS-0001
Revision: 3
Date Issued: 12 May 2016
SAFETY DATA SHEET
VAPOR PRESSURE: Not determined
VAPOR DENSITY: Not determined
RELATIVE DENSITY: Not determined
SOLUBILITY IN OTHER SOLVENTS: Not determined
PARTITION COEFFICIENT: Not determined
AUTOIGNITION TEMPERATURE: Not determined
DECOMPOSITION TEMPERATURE: Not determined
KINEMATIC VISCOSITY: Not determined
DYNAMIC VISCOSITY: Not determined
EXPLOSIVE PROPERTIES: Not determined
OXIDIZING PROPERTIES: Not determined
SECTION 10: STABILITY AND REACTIVITY
STABILITY: Stable.
INCOMPATIBILITY (MATERIAL TO AVOID): None known
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: None known
HAZARDOUS POLYMERIZATION: Not known to occur
CONDITIONS TO AVOID (POLYMERIZATION): None
SECTION 11: TOXICOLOGICAL INFORMATION
WARNING: This product may be harmful if swallowed. This product may be harmful in contact with skin. This
product may be harmful if inhaled.
ACUTE ORAL TOXICITY LD50: >5000 mg/kg (rat). Not classified
ACUTE DERMAL TOXICITY LD50: >5050 mg/kg (rat). Not classified
ACUTE INHALATION LC50: >5.22 mg/L (rat). Not classified
EYE IRRITATION: Non-irritating (rabbit). Not classified
SKIN IRRITATION: Minimally irritating (rabbit). Not classified
SKIN SENSITIZATION: Non-sensitizing (guinea pigs). Not classified
SECTION 12: ECOLOGICAL INFORMATION
This product is non-toxic or practically nontoxic (Category 4) to mammalian wildlife, beneficial insects and mites,
and freshwater aquatic life in short-term studies. Long-term data is unavailable.
Avian Acute Oral Toxicity: Bobwhite quail. LD50 >2000 mg/kg-bw. Non-toxic. Category 5
Toxicity to freshwater aquatic life: Rainbow trout (96-hour acute toxicity) EC50 > 1000 mg/L AI. Minimally
toxic. Category 4.
Daphnia magna (48-hour acute toxicity) EC50 = 28.8 mg/L. Category 3.
Unicellular green algae (72-hour growth inhibition) NOEC 1000 mg/L .
Category 4.
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Document Control Number: MBI-SDS-0001
Revision: 3
Date Issued: 12 May 2016
SAFETY DATA SHEET
Bees and beneficial insects: Honey bee (48-hour contact and oral acute toxicity) LD50 > 100 μg a.s./
bee. Non-toxic.
To minimize potential exposure to bees and other pollinating insects, do not apply while bees are foraging. Do not
allow product to drift to blooming crops or weeds if bees are foraging. Minimize spray drift away from the target
area to reduce effects to other non-target insects.
VENERATE PTO has been evaluated for toxicity to non-target insects in a variety of bioassays and on a variety of
crops under various normal growing conditions. However, testing all beneficial insects, in all situations, mixtures
and combinations, is not feasible. Prior to treating entire crop where the release of beneficial insects serve as part
of an Integrated Pest Management (IPM) program, consult with an extension specialist, a pest control advisor
(PCA) or with the product manufacturer.
For terrestrial uses only: Do not apply directly to water, or to areas where surface water is present, or to intertidal
areas below the mean high water mark. Do not contaminate water when disposing of equipment wash water or
rinsate.
Sensitive areas: The pesticide should only be applied when the potential for drift to adjacent sensitive areas (e.g.
residential areas, bodies of water, known habitat for threatened or endangered species, non-target crops) is minimal
(e.g. when wind is blowing away from the sensitive areas). Do not allow spray to drift from the application site and
contact people, structures people occupy at any time and the associated property, parks and recreation areas, non-
target crops, aquatic and wetland areas, woodlands, pastures, rangelands, or animals. Do not allow product to drift
to blooming crops or weeds if bees are foraging. Minimize spray drift away from the target area to reduce effects to
other non-target insects
Bioconcentration potential: This material is not expected to bioconcentrate in organisms.
SECTION 13: DISPOSAL CONSIDERATIONS
Do not reuse containers. Dispose of in accordance with all applicable federal, state, and local environmental
regulations.
SECTION 14: TRANSPORTATION INFORMATION
U.S. DOT: Not regulated
IATA DGR: Not regulated
IMDG: Not regulated
Freight Classification: Insecticide. See NMFTA code.
SECTION 15: REGULATORY INFORMATION
INTERNATIONAL REGULATIONS
TSCA: Exempt
U.S. FEDERAL REGULATIONS
CERCLA: Not applicable.
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Document Control Number: MBI-SDS-0001
Revision: 3
Date Issued: 12 May 2016
SAFETY DATA SHEET
SARA TITLE III HAZARD CLASSIFICATION SECTIONS 311 AND 312:
Immediate (acute) Health: None
Delayed (chronic) Health: None
Fire: None
Sudden Release of Pressure: None
Reactivity: None
SARA 313: Not determined
U.S. STATE REGULATIONS: None
US STATE RIGHT-TO-KNOW REGULATIONS:
New Jersey Right To Know Components
1-hexanol
CAS No.
111-27-3
Propylene glycol
CAS No.
57-55-6
Pennsylvania Right To Know Components
1-hexanol
CAS No.
111-27-3
Propylene glycol
CAS No.
57-55-6
California Proposition 65 This product does not contain any chemicals known to State of
California to cause cancer, birth defects, or any other reproductive
harm.
SECTION 16: OTHER INFORMATION
NFPA HAZARD CLASSIFICATION
HEALTH: 0 FLAMMABILITY: 0 REACTIVITY: 0
HMIS HAZARD CLASSIFICATION
HEALTH: 0 FLAMMABILITY: 0 REACTIVITY: 0
SPECIAL HAZARDS: Not Determined
Date Issued: 12 May 2016
Revision: 3
Revision Note: Update address, right to know, H and P statements, general
corporate document consistency
DISCLAIMER: IN NO EVENT SHALL MARRONE BIO INNOVATIONS BE LIABLE FOR ANY
INCIDENTAL, CONSEQUENTIAL OR SPECIAL DAMAGES. THE DATA PROVIDED IS FOR GENERAL
INFORMATION ONLY AND IS NOT INTENDED AS A COMPREHENSIVE GUIDE CONCERNING
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Document Control Number: MBI-SDS-0001
Revision: 3
Date Issued: 12 May 2016
SAFETY DATA SHEET
HAZARDS THAT MAY BE ASSOCIATED WITH THIS PRODUCT. USER ASSUMES ALL
RESPONSIBILITY FOR FOLLOWING PROPER SAFTEY PROTOCOL AND CONSULTING TRAINED
PERSONNEL FOR CONTROL AND CONTAINMENT.
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