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SAFETY DATA SHEET

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Important information

*** This Safety Data Sheet is only authorised for use by HP for HP Original products. Any unauthorised use of this Safety Data Sheet is strictly prohibited and may result in legal action being taken by HP. ***

1.1. Product identifier
Trade name or designation of the mixture

T6M26Series

Registration number Synonyms Issue date Version number Revision date Supersedes date

None. 12-Jun-2016 06 09-Apr-2020 04-Aug-2019

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses

Inkjet printing

Uses advised against

None known.

1.3. Details of the supplier of the safety data sheet

Company identification

HP Inc. UK Limited

Cain Road, Amen Corner

Amen Corner

Bracknell, Berkshire RG12 1HN

United Kingdom

Telephone

HP Inc. health effects line (Toll-free within the US) (Direct) HP Inc. Customer Care Line (Toll-free within the US) (Direct) Email: 1.4 Emergency telephone number

1-800-457-4209 1-760-710-0048
1-800-474-6836 1-208-323-2551 hpcustomer.inquiries@hp.com 1-760-710-0048

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 as amended This mixture does not meet the criteria for classification as hazardous according to Regulation (EC) 1272/2008.

2.2. Label elements

Label according to Regulation (EC) No. 1272/2008 as amended

Hazard pictograms

None.

Signal word

None.

Hazard statements

The mixture does not meet the criteria for classification.

Precautionary statements Prevention Response Storage Disposal
Supplemental label information

Not available.
Not available.
Not available.
Not available.
Contains mixture of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H-isothiazol-3-one (3:1), 1,2-Benzisothiazolin-3-one and 2,4,7,9-tetramethyl-5-decyne-4,7-diol. May produce an allergic reaction.

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2.3. Other hazards

Complete toxicity data are not available for this specific formulation.
Potential routes of overexposure to this product are skin and eye contact. Inhalation of vapor and ingestion are not expected to be significant routes of exposure for this product under normal use conditions.
None of the components present in this formulation at concentrations equal to or greater than 0.1% are listed by EU, MAK, IARC, NTP or OSHA.

SECTION 3: Composition/information on ingredients

3.2. Mixtures General information
Chemical name Water

Classification:

-

% 65-85

CAS-No. / EC No. REACH Registration No.

7732-18-5

-

231-791-2

Index No. -

2,4,7,9-Tetramethyl-5-decyne-4,7-diol <1

126-86-3

01-2119954390-39-XXXX

-

204-809-1

Classification:

Skin Sens. 1;H317, Eye Dam. 1;H318, Aquatic Chronic 3;H412

1,2-Benzisothiazolin-3-one

<0.05

2634-33-5 220-120-9

-

613-088-00-6

Classification:

Acute Tox. 4;H302, Skin Irrit. 2;H315, Skin Sens. 1;H317, Eye Dam. 1;H318, Aquatic Acute 1;H400

Mixture of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H-isothiazol-3-one (3:1)

<0.0015

55965-84-9 -

-

613-167-00-5

Classification:

Acute Tox. 3;H301, Acute Tox. 2;H310, Skin Corr. 1C;H314, Skin Sens. 1A;H317, Acute Tox. 2;H330, Aquatic Chronic 1;H410

Composition comments

This ink supply contains an aqueous ink formulation.

Notes

SECTION 4: First aid measures

General information

Not available.

4.1. Description of first aid measures

Inhalation

Move to fresh air. If symptoms persist, get medical attention.

Skin contact

Wash affected areas thoroughly with mild soap and water. Get medical attention if irritation develops or persists.

Eye contact

Do not rub eyes. Immediately flush with large amounts of clean, warm water (low pressure) for at least 15 minutes or until particles are removed. If irritation persists get medical attention.

Ingestion

If ingestion of a large amount does occur, seek medical attention.

4.2. Most important symptoms and effects, both acute and delayed

Not available.

4.3. Indication of any immediate medical attention and special treatment needed

Not available.

SECTION 5: Firefighting measures

General fire hazards

Not available.

5.1. Extinguishing media Suitable extinguishing media
Unsuitable extinguishing media
5.2. Special hazards arising from the substance or mixture

Dry chemical, CO2, water spray or regular foam. None known. Not available.

5.3. Advice for firefighters Special protective equipment for firefighters
Special fire fighting procedures

Not available. Not available.

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Specific methods

None established.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

For non-emergency

Wear appropriate personal protective equipment.

personnel

For emergency responders Not available.

6.2. Environmental precautions Do not let product enter drains. Do not flush into surface water or sanitary sewer system.

6.3. Methods and material for containment and cleaning up

Dike the spilled material, where this is possible. Absorb with inert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recover using pumps.

6.4. Reference to other sections

Not available.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Avoid contact with skin, eyes and clothing.

7.2. Conditions for safe storage, including any incompatibilities

Keep out of the reach of children. Keep away from excessive heat or cold.

7.3. Specific end use(s)

Not available.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters Occupational exposure limits Biological limit values Recommended monitoring procedures

No exposure limits noted for ingredient(s). No biological exposure limits noted for the ingredient(s). Not available.

Derived no effect levels (DNELs) Components

Type

Route

Value

2,4,7,9-Tetramethyl-5-decyne-4,7-diol (CAS Consumers 126-86-3)
Workers

Inhalation
Inhalation Inhalation Inhalation

1.29 mg/m3
0.43 mg/m3 5.28 mg/m3 1.76 mg/m3

Form Systemic short term
Systemic long term Systemic short term Systemic long term

Predicted no effect concentrations (PNECs)

Components

Type

2,4,7,9-Tetramethyl-5-decyne-4,7-diol (CAS Not applicable 126-86-3)

Route Freshwater

Value 0.04 mg/l

Intermittent Marine water Sediment Sediment Soil STP

0.4 mg/l 0.004 mg/l 0.32 mg/kg 0.032 mg/kg 0.028 mg/kg 7 mg/l

Form
Releases Freshwater Marine water Sewage Treatment Plant

Exposure guidelines

Exposure limits have not been established for this product.

8.2. Exposure controls

Appropriate engineering controls

Use in a well ventilated area.

Individual protection measures, such as personal protective equipment

General information

Use personal protective equipment to minimize exposure to skin and eye.

Eye/face protection

Not available.

Skin protection

- Hand protection - Other

Not available. Not available.

Respiratory protection

Not available.

Thermal hazards

Not available.

Hygiene measures

Handle in accordance with good industrial hygiene and safety practice.

Environmental exposure controls

Not available.

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SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Physical state Form Color
Odor

Liquid. Not available. Cyan Not available.

Odor threshold

Not available.

pH

9 - 10

Initial boiling point and boiling Not available. range

Flash point

> 230.0 °F (> 110.0 °C) Pensky-Martens Closed Cup US EPA Method 1020

Evaporation rate Flammability (solid, gas)

Not available. Not available.

Upper/lower flammability or explosive limits

Flammability limit - lower (%)

Not available.

Flammability limit - upper Not available. (%)

Vapor pressure

Not available.

Vapor density

Not available.

Solubility(ies) Solubility (water)

Not available.

Partition coefficient (n-octanol/water)

Not available.

Auto-ignition temperature

Not available.

Decomposition temperature

Not available.

Viscosity Explosive properties Oxidizing properties

Not available. Not available. Not determined

9.2. Other information VOC

< 7 g/L

SECTION 10: Stability and reactivity

10.1. Reactivity 10.2. Chemical stability 10.3. Possibility of hazardous reactions 10.4. Conditions to avoid 10.5. Incompatible materials 10.6. Hazardous decomposition products

Not available. Stable under recommended storage conditions. Will not occur.
Not available. Incompatible with strong bases and oxidizing agents. Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons.

SECTION 11: Toxicological information

General information

Not available.

Information on likely routes of exposure

Inhalation

Under normal conditions of intended use, this material is not expected to be an inhalation hazard.

Skin contact

Contact with skin may result in mild irritation.

Eye contact

Contact with eyes may result in mild irritation.

Ingestion

Health injuries are not known or expected under normal use.

Symptoms

Not available.

11.1. Information on toxicological effects

Acute toxicity Skin corrosion/irritation

Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met.

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Serious eye damage/eye irritation Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity single exposure
Specific target organ toxicity repeated exposure
Aspiration hazard Mixture versus substance information Other information

Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met. Not available.
Complete toxicity data are not available for this specific formulation Refer to Section 2 for potential health effects and Section 4 for first aid measures.

SECTION 12: Ecological information

12.1. Toxicity Aquatic toxicity Product T6M26Series
Aquatic Acute Fish

Not expected to be harmful to aquatic organisms. Species

Test Results

LC50

Fathead minnow (Pimephales promelas) > 750 mg/l, 96 hours

12.2. Persistence and degradability

Not available.

12.3. Bioaccumulative potential Not available.

Partition coefficient n-octanol/water (log Kow)

Not available.

Bioconcentration factor (BCF) Not available.

12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment

Not available. Not a PBT or vPvB substance or mixture.

12.6. Other adverse effects

Not available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods Residual waste Contaminated packaging EU waste code Disposal methods/information

Not available.
Not available.
Not available.
Do not allow this material to drain into sewers/water supplies. Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.

HP's Planet Partners (trademark) supplies recycling program enables simple, convenient recycling of HP original inkjet and LaserJet supplies. For more information and to determine if this service is available in your location, please visit http://www.hp.com/recycle.

SECTION 14: Transport information

DOT UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Packing group Environmental hazards Marine pollutant

Not available. Not Regulated
Not available. Not available.
No

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Special precautions for user Not available. IATA

UN number

Not available.

UN proper shipping name Not Regulated

Transport hazard class(es)

Class

Not available.

Subsidiary risk

-

Packing group

Not available.

Environmental hazards

No

Special precautions for user Not available.

IMDG

UN number

Not available.

UN proper shipping name Not Regulated

Transport hazard class(es)

Class Subsidiary risk Packing group Transport hazard class(es)

Not available. Not available.

Marine pollutant

No

EmS

Not available.

Special precautions for user Not available.

ADR

UN number

Not available.

UN proper shipping name Not Regulated

Transport hazard class(es)

Class

Not available.

Subsidiary risk

-

Hazard No. (ADR)

Not available.

Tunnel restriction code Not available.

Packing group

Not available.

Environmental hazards

No

Special precautions for user Not available.

Further information

Not a dangerous good under DOT, IATA, ADR, IMDG, or RID.

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code: Not applicable.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I and II, as amended Not listed.
Regulation (EC) No. 850/2004 On persistent organic pollutants, Annex I as amended Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 1 as amended Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 2 as amended Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 3 as amended Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex V as amended Not listed.
Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry, as amended Not listed.
Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA Not listed.
Authorizations
Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorization, as amended Not listed.
Restrictions on use

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Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended

Not listed. Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at work, as amended

Not listed.

Other EU regulations

Directive 2012/18/EU on major accident hazards involving dangerous substances, as amended

Not listed.

Other regulations Other information

All chemical substances in this HP product have been notified or are exempt from notification under chemical substances notification laws in the following countries: US (TSCA), EU (EINECS/ELINCS), Switzerland, Canada (DSL/NDSL), Australia, Japan, Philippines, South Korea, New Zealand, and China.
This Safety Data Sheet complies with the requirements of Regulation (EU) 2015/830. Classification according to Regulation (EC) No 1272/2008 as amended. Specific Provisions: Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC (in the amended version OJ L 396 from 29.05.2007 page 3 with further rectifications and amendments).

National regulations
15.2. Chemical safety assessment

Not available. See attached SUMI or GEIS document, if applicable.

SECTION 16: Other information

References

Regulation (EC) No. 1907/2006 of December 18, 2006 concerning the Registration, Evaluation, Authorization and Restriction of Chemicals (REACH) and establishing a European Chemicals Agency (REACH).

Regulation (EU) 2015/830 of May 28, 2015 amending Regulation (EC) No. 1907/2006.

Information on evaluation method leading to the classification of mixture Full text of any H-statements not written out in full under Sections 2 to 15
Revision information Training information

Regulation (EC) No. 1272/2008 of December 16, 2008 on classification, labeling and packaging of substances and mixtures, and amendments (CLP). The classification for health and environmental hazards is derived by a combination of calculation methods and test data, if available.
H301 Toxic if swallowed. H302 Harmful if swallowed. H310 Fatal in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H330 Fatal if inhaled. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. None. Follow training instructions when handling this material.

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Disclaimer Explanation of abbreviations

This Safety Data Sheet document is provided without charge to customers of HP. Data is the most current known to HP at the time of preparation of this document and is believed to be accurate. It should not be construed as guaranteeing specific properties of the products as described or suitability for a particular application. This document was prepared to the requirements of the jurisdiction specified in Section 1 above and may not meet regulatory requirements in other countries.
This safety data sheet is meant to convey information about HP inks (toners) provided in HP Original ink (toner) supplies. If our Safety Data Sheet has been provided to you with a refilled, remanufactured, compatible or other non-HP Original supply please be aware that the information contained herein was not meant to convey information about such products and there could be considerable differences from information in this document and the safety information for the product you purchased. Please contact the seller of the refilled, remanufactured or compatible supplies for applicable information, including information on personal protective equipment, exposure risks and safe handling guidance. HP does not accept refilled, remanufactured or compatible supplies in our recycling programs.

ACGIH CAS CERCLA CFR COC DOT EPCRA IARC NIOSH NTP OSHA PEL RCRA REC REL SARA STEL TCLP TLV TSCA VOC

American Conference of Governmental Industrial Hygienists Chemical Abstracts Service Comprehensive Environmental Response Compensation and Liability Act Code of Federal Regulations Cleveland Open Cup Department of Transportation Emergency Planning and Community Right-to-Know Act (aka SARA) International Agency for Research on Cancer National Institute for Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Resource Conservation and Recovery Act Recommended Recommended Exposure Limit Superfund Amendments and Reauthorization Act of 1986 Short-Term Exposure Limit Toxicity Characteristics Leaching Procedure Threshold Limit Value Toxic Substances Control Act Volatile Organic Compounds

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Safe Use of Mixture Information (SUMI)

--

Water Based Ink: WB01 *English*

Disclaimer This SUMI is a generic document for communicating conditions of safe use of a product in response to the REACH obligation. This document relates only to conditions of safe use and is not specific to a product. By adding this SUMI to a specific product SDS, the importer/formulator declares that the mixture can safely be used following the instructions below. Following occupational health legislation, the employer of workers remains responsible for communicating relevant use information to employees. When developing workplace instructions for employees, SUMI Sheets should always be considered in combination with the SDS and the label of the product. Derived No Effect Levels (DNEL) and Predicted No Effect Concentration (PNEC) values of substances derived from the Chemical Safety Assessment (CSA) will be given in section 8 of the SDS. The REACH registration number(s), where applicable, completes an extended product SDS.

Operational conditions Maximum duration Frequency of exposure Process conditions

Up to 8 hours per day < 240 days per year Covers use at ambient temperatures. Adequate ventilation should be provide for the areas where printing is performed. ANSI/ASHRAE Standard 62.1-2013 provides guidelines to ensure acceptable air quality in the workspace.

Avoid direct contact. Regular cleaning of equipment and work area. Supervision in place to check that Risk Management Measures are in place are being correctly used and Operational Conditions followed.

Risk management measures Conditions and measures related to Personal Protection Equipment, hygiene and health evaluation

Wear safety glasses with side shields (or goggles), if splashing is possible. Wear appropriate chemical resistent gloves: see section 8 of the SDS. Wear appropriate chemical resistent clothing. In case of inadequate ventilation wear respiratory protection.

Eye wash fountain and emergency showers are recommended. Avoid breathing mist/vapours. Avoid contact with skin, eyes and clothing. Training of workers in relation to proper use and maintenance of all Personal protection equipment (PPE) must be ensured.

Good practice advice Use personal protective equipment as required. Wash hands before breaks and after work. Keep good industrial hygiene and safety practice. Use only with adequate ventilation. Do no eat, drink or smoke when using this product. Wash contaminated clothing before reuse. Store at room temperature.
Environmental measures Do not allow this material to drain into sewers/water supplies. Dispose of waste material according to Local, State, Federal and Provincial Environmental Regulations. Ensure collection and disposal with appropriately licenced waste contractor. Use descriptors IS-Use at industrial sites PW-Widespread use by professional workers SU7-Printing and reproduction media PC18-Inks and Toners PROC1-Chemical production or refinery in closed process without likelihood of exposure or processes with equivalent containment conditions. PROC2-Chemical production or refinery in closed continuous process with occasional controlled exposure or processes with equivalent containment conditions

PROC3- Manufacture or formulation in the chemical industry in closed batch processes with occasional controlled exposure or processes with equivalent containment

condition

PROC8a-Transfer of substance or mixture (charging and discharging) at non-dedicated facilities

PROC8b-Transfer of substance or mixture (charging and discharging) at dedicated facilities ERC5-Use at industrial site leading to inclusion into/onto article ERC8c-Widespread use leading to inclusion into/onto article (indoor)

Additional information on product composition

In section 2 of the SDS as well as on the label, the classification of the mixture is provided. Most of the water based inks are "not classified". The classification of the mixture is based on the individuel ingredients and their concentration within the mixture.

All ingredients contributing to the classification are stated in Section 3 of the SDS.

Relevant limit values of ingredients on which the exposure assessment is based, are listed in section 8 of the SDS. The product may contain sensitizing ingredients that may cause allergic reaction to certain people.

Section 2 of the SDS states these ingredients where applicable.

WB01_English.pdf


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