SAFETY DATA SHEET
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Important information
*** This Safety Data Sheet is only authorised for use by HP for HP Original products. Any unauthorised use of this Safety Data Sheet is strictly prohibited and may result in legal action being taken by HP. ***
1.1. Product identifier
Trade name or designation of the mixture
T6M26Series
Registration number Synonyms Issue date Version number Revision date Supersedes date
None. 12-Jun-2016 06 09-Apr-2020 04-Aug-2019
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Inkjet printing
Uses advised against
None known.
1.3. Details of the supplier of the safety data sheet
Company identification
HP Inc. UK Limited
Cain Road, Amen Corner
Amen Corner
Bracknell, Berkshire RG12 1HN
United Kingdom
Telephone
HP Inc. health effects line (Toll-free within the US) (Direct) HP Inc. Customer Care Line (Toll-free within the US) (Direct) Email: 1.4 Emergency telephone number
1-800-457-4209 1-760-710-0048
1-800-474-6836 1-208-323-2551 hpcustomer.inquiries@hp.com 1-760-710-0048
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 as amended This mixture does not meet the criteria for classification as hazardous according to Regulation (EC) 1272/2008.
2.2. Label elements
Label according to Regulation (EC) No. 1272/2008 as amended
Hazard pictograms
None.
Signal word
None.
Hazard statements
The mixture does not meet the criteria for classification.
Precautionary statements Prevention Response Storage Disposal
Supplemental label information
Not available.
Not available.
Not available.
Not available.
Contains mixture of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H-isothiazol-3-one (3:1), 1,2-Benzisothiazolin-3-one and 2,4,7,9-tetramethyl-5-decyne-4,7-diol. May produce an allergic reaction.
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2.3. Other hazards
Complete toxicity data are not available for this specific formulation.
Potential routes of overexposure to this product are skin and eye contact. Inhalation of vapor and ingestion are not expected to be significant routes of exposure for this product under normal use conditions.
None of the components present in this formulation at concentrations equal to or greater than 0.1% are listed by EU, MAK, IARC, NTP or OSHA.
SECTION 3: Composition/information on ingredients
3.2. Mixtures General information
Chemical name Water
Classification:
-
% 65-85
CAS-No. / EC No. REACH Registration No.
7732-18-5
-
231-791-2
Index No. -
2,4,7,9-Tetramethyl-5-decyne-4,7-diol <1
126-86-3
01-2119954390-39-XXXX
-
204-809-1
Classification:
Skin Sens. 1;H317, Eye Dam. 1;H318, Aquatic Chronic 3;H412
1,2-Benzisothiazolin-3-one
<0.05
2634-33-5 220-120-9
-
613-088-00-6
Classification:
Acute Tox. 4;H302, Skin Irrit. 2;H315, Skin Sens. 1;H317, Eye Dam. 1;H318, Aquatic Acute 1;H400
Mixture of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-2H-isothiazol-3-one (3:1)
<0.0015
55965-84-9 -
-
613-167-00-5
Classification:
Acute Tox. 3;H301, Acute Tox. 2;H310, Skin Corr. 1C;H314, Skin Sens. 1A;H317, Acute Tox. 2;H330, Aquatic Chronic 1;H410
Composition comments
This ink supply contains an aqueous ink formulation.
Notes
SECTION 4: First aid measures
General information
Not available.
4.1. Description of first aid measures
Inhalation
Move to fresh air. If symptoms persist, get medical attention.
Skin contact
Wash affected areas thoroughly with mild soap and water. Get medical attention if irritation develops or persists.
Eye contact
Do not rub eyes. Immediately flush with large amounts of clean, warm water (low pressure) for at least 15 minutes or until particles are removed. If irritation persists get medical attention.
Ingestion
If ingestion of a large amount does occur, seek medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Not available.
4.3. Indication of any immediate medical attention and special treatment needed
Not available.
SECTION 5: Firefighting measures
General fire hazards
Not available.
5.1. Extinguishing media Suitable extinguishing media
Unsuitable extinguishing media
5.2. Special hazards arising from the substance or mixture
Dry chemical, CO2, water spray or regular foam. None known. Not available.
5.3. Advice for firefighters Special protective equipment for firefighters
Special fire fighting procedures
Not available. Not available.
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Specific methods
None established.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency
Wear appropriate personal protective equipment.
personnel
For emergency responders Not available.
6.2. Environmental precautions Do not let product enter drains. Do not flush into surface water or sanitary sewer system.
6.3. Methods and material for containment and cleaning up
Dike the spilled material, where this is possible. Absorb with inert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recover using pumps.
6.4. Reference to other sections
Not available.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Avoid contact with skin, eyes and clothing.
7.2. Conditions for safe storage, including any incompatibilities
Keep out of the reach of children. Keep away from excessive heat or cold.
7.3. Specific end use(s)
Not available.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters Occupational exposure limits Biological limit values Recommended monitoring procedures
No exposure limits noted for ingredient(s). No biological exposure limits noted for the ingredient(s). Not available.
Derived no effect levels (DNELs) Components
Type
Route
Value
2,4,7,9-Tetramethyl-5-decyne-4,7-diol (CAS Consumers 126-86-3)
Workers
Inhalation
Inhalation Inhalation Inhalation
1.29 mg/m3
0.43 mg/m3 5.28 mg/m3 1.76 mg/m3
Form Systemic short term
Systemic long term Systemic short term Systemic long term
Predicted no effect concentrations (PNECs)
Components
Type
2,4,7,9-Tetramethyl-5-decyne-4,7-diol (CAS Not applicable 126-86-3)
Route Freshwater
Value 0.04 mg/l
Intermittent Marine water Sediment Sediment Soil STP
0.4 mg/l 0.004 mg/l 0.32 mg/kg 0.032 mg/kg 0.028 mg/kg 7 mg/l
Form
Releases Freshwater Marine water Sewage Treatment Plant
Exposure guidelines
Exposure limits have not been established for this product.
8.2. Exposure controls
Appropriate engineering controls
Use in a well ventilated area.
Individual protection measures, such as personal protective equipment
General information
Use personal protective equipment to minimize exposure to skin and eye.
Eye/face protection
Not available.
Skin protection
- Hand protection - Other
Not available. Not available.
Respiratory protection
Not available.
Thermal hazards
Not available.
Hygiene measures
Handle in accordance with good industrial hygiene and safety practice.
Environmental exposure controls
Not available.
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SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance Physical state Form Color
Odor
Liquid. Not available. Cyan Not available.
Odor threshold
Not available.
pH
9 - 10
Initial boiling point and boiling Not available. range
Flash point
> 230.0 °F (> 110.0 °C) Pensky-Martens Closed Cup US EPA Method 1020
Evaporation rate Flammability (solid, gas)
Not available. Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower (%)
Not available.
Flammability limit - upper Not available. (%)
Vapor pressure
Not available.
Vapor density
Not available.
Solubility(ies) Solubility (water)
Not available.
Partition coefficient (n-octanol/water)
Not available.
Auto-ignition temperature
Not available.
Decomposition temperature
Not available.
Viscosity Explosive properties Oxidizing properties
Not available. Not available. Not determined
9.2. Other information VOC
< 7 g/L
SECTION 10: Stability and reactivity
10.1. Reactivity 10.2. Chemical stability 10.3. Possibility of hazardous reactions 10.4. Conditions to avoid 10.5. Incompatible materials 10.6. Hazardous decomposition products
Not available. Stable under recommended storage conditions. Will not occur.
Not available. Incompatible with strong bases and oxidizing agents. Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons.
SECTION 11: Toxicological information
General information
Not available.
Information on likely routes of exposure
Inhalation
Under normal conditions of intended use, this material is not expected to be an inhalation hazard.
Skin contact
Contact with skin may result in mild irritation.
Eye contact
Contact with eyes may result in mild irritation.
Ingestion
Health injuries are not known or expected under normal use.
Symptoms
Not available.
11.1. Information on toxicological effects
Acute toxicity Skin corrosion/irritation
Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met.
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Serious eye damage/eye irritation Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity single exposure
Specific target organ toxicity repeated exposure
Aspiration hazard Mixture versus substance information Other information
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met. Not available.
Complete toxicity data are not available for this specific formulation Refer to Section 2 for potential health effects and Section 4 for first aid measures.
SECTION 12: Ecological information
12.1. Toxicity Aquatic toxicity Product T6M26Series
Aquatic Acute Fish
Not expected to be harmful to aquatic organisms. Species
Test Results
LC50
Fathead minnow (Pimephales promelas) > 750 mg/l, 96 hours
12.2. Persistence and degradability
Not available.
12.3. Bioaccumulative potential Not available.
Partition coefficient n-octanol/water (log Kow)
Not available.
Bioconcentration factor (BCF) Not available.
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
Not available. Not a PBT or vPvB substance or mixture.
12.6. Other adverse effects
Not available.
SECTION 13: Disposal considerations
13.1. Waste treatment methods Residual waste Contaminated packaging EU waste code Disposal methods/information
Not available.
Not available.
Not available.
Do not allow this material to drain into sewers/water supplies. Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
HP's Planet Partners (trademark) supplies recycling program enables simple, convenient recycling of HP original inkjet and LaserJet supplies. For more information and to determine if this service is available in your location, please visit http://www.hp.com/recycle.
SECTION 14: Transport information
DOT UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Packing group Environmental hazards Marine pollutant
Not available. Not Regulated
Not available. Not available.
No
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Special precautions for user Not available. IATA
UN number
Not available.
UN proper shipping name Not Regulated
Transport hazard class(es)
Class
Not available.
Subsidiary risk
-
Packing group
Not available.
Environmental hazards
No
Special precautions for user Not available.
IMDG
UN number
Not available.
UN proper shipping name Not Regulated
Transport hazard class(es)
Class Subsidiary risk Packing group Transport hazard class(es)
Not available. Not available.
Marine pollutant
No
EmS
Not available.
Special precautions for user Not available.
ADR
UN number
Not available.
UN proper shipping name Not Regulated
Transport hazard class(es)
Class
Not available.
Subsidiary risk
-
Hazard No. (ADR)
Not available.
Tunnel restriction code Not available.
Packing group
Not available.
Environmental hazards
No
Special precautions for user Not available.
Further information
Not a dangerous good under DOT, IATA, ADR, IMDG, or RID.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC code: Not applicable.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I and II, as amended Not listed.
Regulation (EC) No. 850/2004 On persistent organic pollutants, Annex I as amended Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 1 as amended Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 2 as amended Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 3 as amended Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex V as amended Not listed.
Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry, as amended Not listed.
Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA Not listed.
Authorizations
Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorization, as amended Not listed.
Restrictions on use
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Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended
Not listed. Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at work, as amended
Not listed.
Other EU regulations
Directive 2012/18/EU on major accident hazards involving dangerous substances, as amended
Not listed.
Other regulations Other information
All chemical substances in this HP product have been notified or are exempt from notification under chemical substances notification laws in the following countries: US (TSCA), EU (EINECS/ELINCS), Switzerland, Canada (DSL/NDSL), Australia, Japan, Philippines, South Korea, New Zealand, and China.
This Safety Data Sheet complies with the requirements of Regulation (EU) 2015/830. Classification according to Regulation (EC) No 1272/2008 as amended. Specific Provisions: Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC (in the amended version OJ L 396 from 29.05.2007 page 3 with further rectifications and amendments).
National regulations
15.2. Chemical safety assessment
Not available. See attached SUMI or GEIS document, if applicable.
SECTION 16: Other information
References
Regulation (EC) No. 1907/2006 of December 18, 2006 concerning the Registration, Evaluation, Authorization and Restriction of Chemicals (REACH) and establishing a European Chemicals Agency (REACH).
Regulation (EU) 2015/830 of May 28, 2015 amending Regulation (EC) No. 1907/2006.
Information on evaluation method leading to the classification of mixture Full text of any H-statements not written out in full under Sections 2 to 15
Revision information Training information
Regulation (EC) No. 1272/2008 of December 16, 2008 on classification, labeling and packaging of substances and mixtures, and amendments (CLP). The classification for health and environmental hazards is derived by a combination of calculation methods and test data, if available.
H301 Toxic if swallowed. H302 Harmful if swallowed. H310 Fatal in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H330 Fatal if inhaled. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. None. Follow training instructions when handling this material.
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Disclaimer Explanation of abbreviations
This Safety Data Sheet document is provided without charge to customers of HP. Data is the most current known to HP at the time of preparation of this document and is believed to be accurate. It should not be construed as guaranteeing specific properties of the products as described or suitability for a particular application. This document was prepared to the requirements of the jurisdiction specified in Section 1 above and may not meet regulatory requirements in other countries.
This safety data sheet is meant to convey information about HP inks (toners) provided in HP Original ink (toner) supplies. If our Safety Data Sheet has been provided to you with a refilled, remanufactured, compatible or other non-HP Original supply please be aware that the information contained herein was not meant to convey information about such products and there could be considerable differences from information in this document and the safety information for the product you purchased. Please contact the seller of the refilled, remanufactured or compatible supplies for applicable information, including information on personal protective equipment, exposure risks and safe handling guidance. HP does not accept refilled, remanufactured or compatible supplies in our recycling programs.
ACGIH CAS CERCLA CFR COC DOT EPCRA IARC NIOSH NTP OSHA PEL RCRA REC REL SARA STEL TCLP TLV TSCA VOC
American Conference of Governmental Industrial Hygienists Chemical Abstracts Service Comprehensive Environmental Response Compensation and Liability Act Code of Federal Regulations Cleveland Open Cup Department of Transportation Emergency Planning and Community Right-to-Know Act (aka SARA) International Agency for Research on Cancer National Institute for Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Resource Conservation and Recovery Act Recommended Recommended Exposure Limit Superfund Amendments and Reauthorization Act of 1986 Short-Term Exposure Limit Toxicity Characteristics Leaching Procedure Threshold Limit Value Toxic Substances Control Act Volatile Organic Compounds
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Safe Use of Mixture Information (SUMI)
--
Water Based Ink: WB01 *English*
Disclaimer This SUMI is a generic document for communicating conditions of safe use of a product in response to the REACH obligation. This document relates only to conditions of safe use and is not specific to a product. By adding this SUMI to a specific product SDS, the importer/formulator declares that the mixture can safely be used following the instructions below. Following occupational health legislation, the employer of workers remains responsible for communicating relevant use information to employees. When developing workplace instructions for employees, SUMI Sheets should always be considered in combination with the SDS and the label of the product. Derived No Effect Levels (DNEL) and Predicted No Effect Concentration (PNEC) values of substances derived from the Chemical Safety Assessment (CSA) will be given in section 8 of the SDS. The REACH registration number(s), where applicable, completes an extended product SDS.
Operational conditions Maximum duration Frequency of exposure Process conditions
Up to 8 hours per day < 240 days per year Covers use at ambient temperatures. Adequate ventilation should be provide for the areas where printing is performed. ANSI/ASHRAE Standard 62.1-2013 provides guidelines to ensure acceptable air quality in the workspace.
Avoid direct contact. Regular cleaning of equipment and work area. Supervision in place to check that Risk Management Measures are in place are being correctly used and Operational Conditions followed.
Risk management measures Conditions and measures related to Personal Protection Equipment, hygiene and health evaluation
Wear safety glasses with side shields (or goggles), if splashing is possible. Wear appropriate chemical resistent gloves: see section 8 of the SDS. Wear appropriate chemical resistent clothing. In case of inadequate ventilation wear respiratory protection.
Eye wash fountain and emergency showers are recommended. Avoid breathing mist/vapours. Avoid contact with skin, eyes and clothing. Training of workers in relation to proper use and maintenance of all Personal protection equipment (PPE) must be ensured.
Good practice advice Use personal protective equipment as required. Wash hands before breaks and after work. Keep good industrial hygiene and safety practice. Use only with adequate ventilation. Do no eat, drink or smoke when using this product. Wash contaminated clothing before reuse. Store at room temperature.
Environmental measures Do not allow this material to drain into sewers/water supplies. Dispose of waste material according to Local, State, Federal and Provincial Environmental Regulations. Ensure collection and disposal with appropriately licenced waste contractor. Use descriptors IS-Use at industrial sites PW-Widespread use by professional workers SU7-Printing and reproduction media PC18-Inks and Toners PROC1-Chemical production or refinery in closed process without likelihood of exposure or processes with equivalent containment conditions. PROC2-Chemical production or refinery in closed continuous process with occasional controlled exposure or processes with equivalent containment conditions
PROC3- Manufacture or formulation in the chemical industry in closed batch processes with occasional controlled exposure or processes with equivalent containment
condition
PROC8a-Transfer of substance or mixture (charging and discharging) at non-dedicated facilities
PROC8b-Transfer of substance or mixture (charging and discharging) at dedicated facilities ERC5-Use at industrial site leading to inclusion into/onto article ERC8c-Widespread use leading to inclusion into/onto article (indoor)
Additional information on product composition
In section 2 of the SDS as well as on the label, the classification of the mixture is provided. Most of the water based inks are "not classified". The classification of the mixture is based on the individuel ingredients and their concentration within the mixture.
All ingredients contributing to the classification are stated in Section 3 of the SDS.
Relevant limit values of ingredients on which the exposure assessment is based, are listed in section 8 of the SDS. The product may contain sensitizing ingredients that may cause allergic reaction to certain people.
Section 2 of the SDS states these ingredients where applicable.
WB01_English.pdf