AvonGroup
0900766b811bc3e9 CP1547 v1.6 RS 137-2238, 137-2239, 724-8903, 724-8912, 724-8915, 840-5526, 840-5529
RS CLP/GHS revision date 01/12/20
SAFETY DATA SHEET
(Following Regulations (EC) No 1907/2006 & (EC) No 1272/2008)
Date of first issue: 01 May 2011
Date of last revision: 27 November 2020
1 - Identification of Product
1.1 - Identification of Product
Tradenames: Superwool Plus Blanket
RS Part Numbers: 1372238, 1372239, 7248903, 7248912, 7248915, 8405526, 8405529
The above-mentioned products contain Alkaline-earth silicate wools (AES wools) Index Number: 650-016-00-2 Annex VI CAS number: 436083-99-7 Registration number: 01-2119457644-32-0000
1.2 - Use of Product
Application as thermal insulation, heat shields, heat containment, gaskets and expansion joints in industrial furnaces, ovens, kilns, boilers and other process equipment and in the aerospace, automotive and appliance industries, and as passive fire protection systems and fire stops. (Please refer to specific technical data sheet for more information)
1.3 - Identification of Company
UK RS Components Ltd Birchington Road Corby Northants NN17 9RS Tel: +44 (0) 845 850 9900 RCustomerServicesUK@rs-components.com
Ireland RS Components Ltd Glenview Industrial Estate Herberton Road Rialto Dublin 12 Tel No +353 (0) 1 415 3100 enquiries.ie@rs-components.com
1.4 - Emergency information
Tel: + 44 1865 407333 Language: English Opening hours: 24 hours
Tel: + +44 1235 239670 Language: English Opening hours: 24 hours
2 - Hazard Identification
2.1 - Classification of the substance/ mixture
2.1.1 CLASSIFICATION ACCORDING TO REGULATION (EC) NO 1272/2008 Not classified as hazardous according to Classification, Labelling and Packaging regulations (CLP) 1272/2008 EEC
2.2 - Labelling Elements
Not applicable
2.3 - Other hazards which do not result in classification
Mild mechanical irritation to skin, eyes and upper respiratory system may result from exposure. These effects are usually temporary
3 - Composition / Information on Ingredients
Description
These products in the form of bulk, blanket (pre-sized or not), strip, die-cut and modules, bloc, log (encapsulated or not), are made of AES wool (synthetic fibres, alk. earth silicate).
Composition
COMPONENT
% by CAS No. weight
REACH Registration Hazard Classification
Number
according to CLP
AES wool (synthetic fibres, 100 alk. earth silicate)
436083-99-7 01-2119457644-32 Note Q exonerated
Composition additional information Composition: * CAS definition: Alkaline earth silicate (AES) consisting of silica (50-82 wt%), calcia and magnesia (18-43 wt%), alumina and titania (less than 6 wt%), and trace oxides. None of the components are radioactive under the terms of European Directive Euratom 96/29. 4 - First-Aid measures 4.1 - Description of First Aid Measures. Skin Handling of this material may generate mild mechanical temporary skin irritation. If this occurs, rinse affected areas with water and wash gently. Do not rub or scratch exposed skin. Eyes In case of eye contact flush abundantly with water; have eye bath available. Do not rub eyes. Seek medical attention is irritation persists.
Nose and Throat If these become irritated move to a dust free area, drink water and blow nose. Seek medical attention if irritation persists. First aid additional information If symptoms persist, seek medical advice. 4.2 - Most Important symptoms and effects, both acute and delayed No symptoms or effects expected either acute or delayed 4.3 - Indication of any immediate medical attention and special treatment required No special treatment required, if exposure occurs wash exposed areas to avoid irritation. 5 - Fire-fighting measures 5.1 - Extinguishing media Use extinguishing agent suitable for surrounding combustible materials. 5.2 - Special hazards arising from the substance or mixture Non-combustible products. 5.3 - advice for firefighters Packaging and surrounding materials may be combustible. 6 - Accidental Release Measures 6.1 - Personal precautions, protective equipment and emergency procedures Where abnormally high dust concentrations occur, provide workers with appropriate protective equipment as detailed in section 8. Restrict access to the area to a minimum number of workers required. Restore the situation to normal as quickly as possible.
6.2 - Environmental precautions Prevent further dust dispersion for example by damping the materials. Do not flush spillage to drain and prevent from entering natural watercourses. Check for local regulations, which may apply
6.3 - Methods and materials for containment and clean up Pick up large pieces and use a vacuum cleaner. If brushes are used, ensure that the area is wetted down first. Do not use compressed air for clean-up. Do not allow to become windblown. 6.4 - Reference to other sections For further information, please refer to sections 7 and 8
7 - Handling and storage
7.1 - Precautions for safe handling
Handling can be a source of dust emission and therefore the processes should be designed to limit the amount of handling. Whenever possible, handling should be carried out under controlled conditions (i.e., using dust exhaust system). Regular good housekeeping will minimise secondary dust dispersal.
7.2 - Conditions for safe storage
Store in original packaging in a dry area. Always use sealed and clearly labelled containers. Avoid damaging containers. Reduce dust emission during unpacking.
7.3 - Specific end use
The main application of these products is as thermal insulation. Please refer to your local Morgan Thermal Ceramics' supplier.
8 - Risk Management Measures / Exposures Controls / Personal Protection
8.1 - Control parameters
Industrial hygiene standards and occupational exposure limits vary between countries and local jurisdictions. Check which exposure levels apply to your facility, and comply with local regulations. If no regulatory dust or other standards apply, a qualified industrial hygienist can assist with a specific workplace evaluation including recommendations for respiratory protection. Examples of exposure limits applying (in November 2014) in different countries are given below:
Country
MMVF
Source
Austria Belgium
Czech Republic Denmark Finland France Germany* Hungary Ireland Italy Luxembourg Netherlands Norway
Poland Spain Sweden
1 f/ml 10 mg/m3
1 f/ml 1 f/ml 1 f/ml 1 f/ml 1.25 mg/m3 1 f/ml 1 f/ml 1 f/ml 1 f/ml 1 f/ml 0.5 f/ml
2 f/ml 1 f/ml 1 f/ml
Grenzwerteverordnung Valeurs limites d'exposition professionnelle VLEP/ Grenswaarden voor beroepsmatige blootstelling GWBB
Grænseværdier for stoffer og materialer Finnish Ministry of Social Affairs and Health INRS TRGS900 EüM-SZCSM rendelet HAS - Eire
Règlement grand-ducal du 30 juillet 2002 Social and Economic Council of the Netherlands Veiledning om administrative normer for forurensning I arbeidsatmosfære Dziennik Ustaw 2010 INSHT Hygieniska gränsvärden och åtgärder mot luftföroreningar
Switzerland UK GCC South Africa
1 f/ml 2 f/ml 1 f/ml 5mg/m3
SUVA EH40/2005 Abu Dhabi OSHAD Regulation 1179 Hazardous Chemical Substances 2007
Information on monitoring procedures
United Kingdom
MDHS 59 specific for MMVF: "Man-made mineral fibre - Airborne number concentration by phasecontrast light microscopy" and MDHS 14/4 "General methods for sampling and gravimetric analysis of respirable and inhalable dust"
NIOSH
NIOSH 0500 "Particulates not otherwise regulate, total" NIOSH 0600 "Particulates not otherwise regulate, respirable" NIOSH 7400 "Asbestos and other fibres by PCM"
8.2 - Exposure controls
8.2.1 APPROPRIATE ENGINEERING CONTROLS
Review your applications in order to identify potential sources of dust exposure. Local exhaust ventilation, which collects dust at source, can be used. For example down draft tables, emission controlling tools and materials handling equipment. Keep the workplace clean. Use a vacuum cleaner. Avoid brushing and compressed air.
If necessary, consult an industrial hygienist to design workplace controls and practices. The use of products specially tailored to your application(s) will help to control dust. Some products can be delivered ready for use to avoid further cutting or machining. Some could be pre-treated or packaged to minimise or avoid dust release during handling. Consult your supplier for further details
8.2.2 - Personal Protective Equipment
Skin protection: Wear gloves and work clothes, which are loose fitting at the neck and wrists. Soiled clothes should be cleaned to remove excess fibres before being taken off (e.g. use vacuum cleaner, not compressed air). Wash work clothes separately from other clothing.
Eye protection: As necessary wear goggles or safety glasses with side shields.
Respiratory protection: For dust concentrations below the exposure limit value, RPE is not required but FFP2 respirators may be used on a voluntary basis. For short-term operations where excursions are less than ten times the limit value use FFP2 respirators. In case of higher concentrations or where the concentration is not known, please seek advice from your company and/or local Thermal Ceramics supplier.
Information and training of workers Workers should be trained on good working practices and informed on applicable local regulations.
8.2.3 - Environmental Exposure Controls
Refer to local, national or European applicable environmental standards for release to air water and soil. For waste, refer to section13
9 - Physical and chemical properties
Information on basic physical and chemical properties Appearance Odour Odour threshold pH Melting point/freezing point Initial boiling point and boiling point range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits Vapour pressure Vapour density Relative density Solubility(ies) Partition co-efficient: n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity Explosive properties Oxidising properties
Not applicable White fibre/blanket None Not Applicable Not applicable > 1200°C Not applicable Not applicable Not Applicable Not applicable Not applicable Not applicable Not Applicable 50-240 kg/m3 Less than 1 mg/l Not applicable Not applicable Not Applicable Not Applicable Not applicable Not applicable
10 - Stability and Reactivity 10.1 - Reactivity The material is stable and non-reactive. 10.2 - Chemical Stability AES is inorganic, stable and inert 10.3 - Possibility of Hazardous Reactions None 10.4 - Conditions to Avoid Please refer to handling and storage advice in Section 7 10.5 - Incompatible Materials None
10.6 - Hazardous decomposition products
Upon heating above 900°C for sustained periods, this amorphous material begins to transform to mixtures of crystalline phases. For further information please refer to Section 16.
11 - Toxicological information
Toxicokinetics, metabolism and distribution
11.1.1 BASIC TOXICOKINETICS Exposure is predominantly by inhalation or ingestion. Man-made vitreous fibres of a similar size to AES have not been shown to migrate from the lung and/or gut and do not become located in other organs of the body Fibres contained in the products listed in the title have been designed to be rapidly cleared from lung tissue. This low biopersistence has been confirmed in many studies on AES using EU protocol ECB/TM/27(rev 7). When inhaled, even at very high doses, they do not accumulate to any level capable of producing a serious adverse biological effect.
11.1 - Information on toxicological effects
In lifetime chronic studies there was no exposure-related effect more than would be seen with any "inert" dust. Subchronic studies at the highest doses achievable produced at worst a transient mild inflammatory response. Fibres with the same ability to persist in tissue do not produce tumours when injected into the peritoneal cavity of rats.
Irritant properties
Superwool fibres are negative when tested using approved methods (OECD TG 404). Like all manmade mineral fibres and some natural fibres, fibres contained in this product can produce a mild mechanical irritation resulting in temporary itching or rarely, in some sensitive individuals, in a slight temporary reddening. Unlike other irritant reactions this is not the result of allergy or chemical skin damage but is caused by mechanical effects.
12 - Ecological information
a - Ecotoxicity (aquatic and terrestrial, where available)
12.1 - Toxicity
These products are insoluble materials that remain stable overtime and are chemically identical to inorganic compounds found in the soil and sediment; they remain inert in the natural environment. No adverse effects of this material on the environment are anticipated.
12.2 - Persistence and degradability
Not established
12.3 - Bioaccumulative potential
Not established
12.4 - Mobility in soil
No information available
12.5 - Results of PBT and vPvB assessment
This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).
This mixture contains no substance considered to be very persistent and very bioaccumulative (vPvB).
12.6 - Other adverse effects
No additional information available
13 - Disposal Considerations
13.1 - Waste treatment methods
Waste from these materials may be generally disposed of at a landfill, which has been licensed for this purpose. Please refer to the European list (Decision N° 2000/532/CE as modified) to identify your appropriate waste number, and insure national and/or regional regulations are complied with.
Unless wetted, such a waste is normally dusty and so should be properly sealed in containers for disposal. At some authorised disposal sites, dusty waste may be treated differently in order to ensure they are dealt with promptly to avoid them being windblown. Check for any national and/or regional regulations, which may apply.
14 - Transport information
Transport
14.1. UN number Not Applicable
14.2. UN proper shipping name Not Applicable
14.3. Transport hazard class(es) Not Applicable
14.4. Packing group Not Applicable
14.5. Environmental hazards Not Applicable
14.6. Special precautions for user Not Applicable
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not Applicable
15 - Regulatory information
15.1 - Safety health and environment regulations/legislation specific for the substances or mixtures
EU regulations:
- Regulation (EC) No 1907/2006 dated 18th December 2006 on Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) - Regulation (EC) No 1272/2008 dated 20th January 2009 on classification, labelling and packaging of substances and mixtures (OJ L 353) - Annex of Regulation (EU) 2015/830 - Commission regulation (EC) No 790/2009 of 10 August 2009 amending, for the purposes of its adaptation to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures. - The 1st Adaptation to Technical Progress (ATP) to Regulation (EC) No 1272/2008 enters into force on 25 September 2009.
PROTECTION OF WORKERS Shall be in accordance with several European Directives as amended and their implementations by the Member States: a) Council Directive 89/391/EEC dated 12 June 1989 "on the introduction of measures to encourage improvements in the safety and health of workers at work" (OJEC (Official Journal of the European Community) L 183 of 29 June 1989, p.1). b) Council Directive 98/24/EC dated 7 April 1998 "on the protection of workers from the risks related to chemical agents at work" (OJEC L 131 of 5 May 1998, p.11).
OTHER POSSIBLE REGULATIONS Member States are in charge of implementing European Directives into their own national regulation within a period of time normally given in the Directive. Member States may impose more stringent requirements. Please always refer to any national regulation.
15.2 - Chemical Safety Assessment
A Chemical Safety Assessment has been carried out for AES and CSR can be provided on request.
16 - Other Information
Useful references
(The directives which are cited must be considered in their amended version) - Council Directive 89/391/EEC dated 12 June 1989 "on the introduction of measures to encourage improvements in the safety and health of workers at work" (OJEC L 183 of 29 June 1989, p.1). - Regulation (EC) No 1907/2006 dated 18th December 2006 on registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) - Regulation (EC) No 1272/2008 dated 20th January 2009 on classification, labelling and packaging of substances and mixtures (OJ L 353) - Council Directive 98/24/EC of 7 April 1998 "on the protection of the health and safety of workers from the risks related to chemical agents at work" (OJEC L 131 of 5 May 1998, p11).
Precautionary measures
Information on after service heated fibres
In almost all applications high temperature insulating wools products (HTIW) are used as an insulating material helping keeping up temperature at 900°C or more in a closed space. As only a thin layer of the insulation hot face side is exposed to high temperature, respirable dust generated during removal operations does not contain detectable levels of crystalline silica.
In applications where the material is heat socked, duration of heat exposure is normally short and a significant devitrification allowing CS to build up does not occur. This is the case for waste mould casting for instance.
Toxicological evaluation of the effect of the presence of CS in artificially heated HTIW material has not shown any increased toxicity in vitro. The results from different combinations of factors like increased brittleness of fibres, or micro crystals embedded in the glass structure of the fibre and therefore not biologically available may explain the lack of toxicological effects.
IARC evaluation as provided in Monograph 68 is not relevant as CS is not biologically available in after service HTIW and respirable dust generated during removal operations does not contain detectable levels of crystalline silica. http://www.iarc.fr/en/publications/pdfs-online/index.php
High concentrations of fibres and other dusts may be generated when after-service products are mechanically disturbed during operations such as wrecking. Therefore ECFIA recommends: a) Control measures are taken to reduce dust emissions; and b) All personnel directly involved wear an appropriate respirator to minimise exposure and comply with local regulatory limits.
CARE Program
The trade association representing the European high temperature insulation wool industry (ECFIA) has undertaken an extensive hygiene programme for High Temperature Insulation Wool (HTIW). The objectives are twofold: (i) to monitor workplace dust concentrations at both manufacturers' and customers' premises, and (ii) to document manufacturing and use of HTIW products from an industrial hygiene perspective in order to establish appropriate recommendations to reduce exposures. The initial results of the programme have been published. If you wish to participate in the CARE programme, contact ECFIA or your Thermal Ceramics' supplier.
Uses advised against
Website
For more information connect to: The Morgan Thermal Ceramics' website: (http://www.morganthermalceramics.com/) Or ECFIA's website: (http://www.ecfia.eu)
Revision Summary
Update to Section 3
Technical data sheets
For more information on individual products please see the relevant technical data sheet available from http://www.morganthermalceramics.com/downloads/datasheets
Other Information
NOTICE: The information presented herein is based on data considered to be accurate as of the date of preparation of this Material Safety Data Sheet. However safe as provided by law, no warranty or representation, express or implied, is made as to the accuracy or completeness of the foregoing data and safety information, nor is any authorisation given or implied to practice any patented invention without a licence. In addition, no responsibility can be assumed by the vendor for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices, or from any hazards inherent in the nature of the product (however, this shall not act to restrict the vendor's potential liability for negligence or under statute).
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