Public Works Safety Data Sheets | Town of North Yarmouth ME
Hand Sanitizer SECTION 1. IDENTIFICATION Product identifier Chemical Name CAS No. Trade Name Product Codes Mixture Mixture Hand Sanitizer 8-HS-PR, 8-HS-SPRY, 4-HS-DP Relevant identified uses of the substance or mixture and uses advised against Identified Use(s) Hand Sanitizer Uses Advised Against None Company Identification The B'laster Corporation 8500 Sweet Valley Drive Valley View, OH 44125 Telephone Fax (216) 901-5800 (216) 901-5801 Emergency telephone number Emergency Phone No. CHEMTREC 24 hr. 1-800-424-9300 Recommended use of the chemical and restrictions on use Recommended use : Hand Sanitizer Restrictions on use None know Flammable liquids Eye irritation GHS Label element Hazard pictograms SECTION 2. HAZARDS IDENTIFICATION GHS Classification : Category 3 : Category 2A : Signal Word Hazard Statements : Warning : H226 Flammable liquid and vapor. H319 Causes serious eye irritation. Hand Sanitizer Precautionary Statements : Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container tightly closed. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ eye protection/ face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards Vapors may form explosive mixture with air. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous ingredients Chemical Name Ethanol Glycerol Hydrogen peroxide CAS-No. 64-17-5 56-81-5 7722-84-1 Concentration (%) v/v 80 1.45 0.125 SECTION 4. FIRST AID MEASURES General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice. If inhaled : If inhaled, remove to fresh air. Get medical attention if symptoms occur. Hand Sanitizer If swallowed Most important symptoms and effects, both acute and delayed Protection of first-aiders Notes to physician : If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water. : Causes serious eye irritation. : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists. : Treat symptomatically and supportively. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2) Unsuitable extinguishing media : High volume water jet Specific hazards during fire fighting : Do not use a solid water stream as it may scatter and spread fire. Flash back possible over considerable distance. Vapors may form explosive mixtures with air. Exposure to combustion products may be a hazard to health. Hazardous combustion prod- : Carbon oxides ucts Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area. Special protective equipment : In the event of fire, wear self-contained breathing apparatus. for fire-fighters Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Remove all sources of ignition. Use personal protective equipment. Follow safe handling advice and personal protective equipment recommendations. Environmental precautions : Discharge into the environment must be avoided. Hand Sanitizer Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for containment and cleaning up : Non-sparking tools should be used. Soak up with inert absorbent material. Suppress (knock down) gases/vapors/mists with a water spray jet. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements. SECTION 7. HANDLING AND STORAGE Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Local/Total ventilation : Use with local exhaust ventilation. Use only in an area equipped with explosion proof exhaust ventilation. Advice on safe handling : Do not breathe vapors or spray mist. Do not swallow. Do not get in eyes. Avoid prolonged or repeated contact with skin. Handle in accordance with good industrial hygiene and safety practice. Non-sparking tools should be used. Keep container tightly closed. Keep away from heat and sources of ignition. Take precautionary measures against static discharges. Take care to prevent spills, waste and minimize release to the environment. Conditions for safe storage : Keep in properly labeled containers. Keep tightly closed. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition. Materials to avoid : Do not store with the following product types: Strong oxidizing agents Hand Sanitizer Organic peroxides Flammable solids Pyrophoric liquids Pyrophoric solids Self-heating substances and mixtures Substances and mixtures which in contact with water emit flammable gases Explosives Gases SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Ingredients CAS-No. Value type (Form of exposure) Ethanol 64-17-5 TWA Ethanol 64-17-5 TWA Ethanol 64-17-5 STEL Control parameters / Permissible concentration 1,000 ppm 1,900 mg/m3 1,000 ppm 1,900 mg/m3 1,000 ppm Basis NIOSH REL OSHA Z-1 ACGIH Engineering measures : Minimize workplace exposure concentrations. Use only in an area equipped with explosion proof exhaust ventilation. Use with local exhaust ventilation. Personal protective equipment Respiratory protection : General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure Hand Sanitizer Hand protection Material Material Remarks Eye protection Skin and body protection Hygiene measures : Impervious gloves : Flame retardant gloves : Choose gloves to protect hands against chemicals depending on the concentration specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday. : Wear the following personal protective equipment: Safety goggles : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Wear the following personal protective equipment: Flame retardant antistatic protective clothing. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc). : Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Color : clear, Odor : Alcohol Odor Threshold : No data available pH : 6.5 - 8.5 Melting point/freezing point : No data available Initial boiling point and boiling : 73 °C range Hand Sanitizer Flash point Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapor pressure Relative vapor density Density : 25 °C : No data available : Not applicable : No data available : No data available : No data available : No data available : 0.881 g/cm3 Solubility(ies) Water solubility Partition coefficient: noctanol/water Autoignition temperature Decomposition temperature Viscosity Viscosity, kinematic Explosive properties Oxidizing properties : soluble : Not applicable : No data available : The substance or mixture is not classified self-reactive. : No data available : Not explosive : The substance or mixture is not classified as oxidizing. SECTION 10. STABILITY AND REACTIVITY Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : Flammable liquid and vapor. Vapors may form explosive mixture with air. Can react with strong oxidizing agents. Conditions to avoid : Heat, flames and sparks. Incompatible materials : Oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known. Hand Sanitizer SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Skin contact Ingestion Eye contact Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Ingredients: Ethanol: Acute oral toxicity Acute inhalation toxicity Propan-2-ol: Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity : LD50 (Rat): > 5,000 mg/kg : LC50 (Rat): 124.7 mg/l Exposure time: 4 h Test atmosphere: vapor : LD50 (Rat): > 5,000 mg/kg : LC50 (Rat): 72.6 mg/l Exposure time: 4 h Test atmosphere: vapor : LD50 (Rat): > 5,000 mg/kg Skin corrosion/irritation Not classified based on available information. Product: Result: No skin irritation Ingredients: Ethanol: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Ingredients: Hand Sanitizer Ethanol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Method: OECD Test Guideline 405 Respiratory or skin sensitization Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information. Product: Assessment: Does not cause skin sensitization. Ingredients: Ethanol: Test Type: Local lymph node assay (LLNA) Routes of exposure: Skin contact Species: Mouse Result: negative Germ cell mutagenicity Not classified based on available information. Ingredients: Ethanol: Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test Result: negative Genotoxicity in vivo : Test Type: Rodent dominant lethal test (germ cell) (in vivo) Species: Mouse Application Route: Ingestion Result: negative Hand Sanitizer IARC OSHA NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. Ingredients: Ethanol: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Mouse Application Route: Ingestion Method: OECD Test Guideline 416 Result: negative Effects on fetal development : Test Type: Embryo-fetal development Species: Rat Application Route: Ingestion Result: negative STOT-single exposure Not classified based on available information. STOT-repeated exposure Not classified based on available information. Repeated dose toxicity Ingredients: Ethanol: Species: Rat NOAEL: 2,400 mg/kg Application Route: Ingestion Exposure time: 2 y Aspiration toxicity Not classified based on available information. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Ingredients: Ethanol: Hand Sanitizer Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): > 1,000 mg/l Exposure time: 96 h Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 1,000 mg/l aquatic invertebrates Exposure time: 48 h Toxicity to algae : EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 9.6 mg/l aquatic invertebrates Exposure time: 9 d (Chronic toxicity) Toxicity to bacteria : EC50 (Photobacterium phosphoreum): 32.1 mg/l Exposure time: 0.25 h Persistence and degradability Ingredients: Ethanol: Biodegradability : Result: Readily biodegradable. Biodegradation: 84 % Exposure time: 20 d Bioaccumulative potential Ingredients: Ethanol: Partition coefficient: noctanol/water : log Pow: -0.35 Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues Contaminated packaging : Dispose of in accordance with local regulations. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not burn, or use a cutting torch on, the empty drum. Hand Sanitizer SECTION 14. TRANSPORT INFORMATION Domestic regulation DOT 49 CFR UN/ID/NA number : UN 1987 Proper shipping name Class Packing group Labels ERG Code Marine pollutant : ALCOHOLS, N.O.S. LTD QTY : 3 : III : LTD QTY : 127 : no SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Fire Hazard Acute Health Hazard SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : The following components are subject to reporting levels established by SARA Title III, Section 313: None US State Regulations Pennsylvania Right To Know Ethanol Water 64-17-5 7732-18-5 75- 90 % 10 - 30 % New Jersey Right To Know Ethanol Water California Prop 65 64-17-5 75 - 90 % 7732-18-5 10 - 30 % This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: Hand Sanitizer REACH TSCA DSL AICS : All ingredients (pre-)registered or exempt. : All chemical substances in this material are included on or exempted from listing on the TSCA Inventory of Chemical Substances. : All chemical substances in this product comply with the CEPA 1999 and NSNR and are on or exempt from listing on the Canadian Domestic Substances List (DSL). : All ingredients listed or exempt. Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), NECSI (Taiwan), TSCA (USA) SECTION 16. OTHER INFORMATION Further information NFPA: Flammability 3 2 0 Healt h Instability Special hazard. HMIS III: HEALTH 2 FLAMMABILITY 3 PHYSICAL HAZARD 0 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Full text of other abbreviations ACGIH ACGIH BEI NIOSH REL OSHA Z-1 ACGIH / TWA ACGIH / STEL NIOSH REL / TWA NIOSH REL / ST OSHA Z-1 / TWA : USA. ACGIH Threshold Limit Values (TLV) : ACGIH - Biological Exposure Indices (BEI) : USA. NIOSH Recommended Exposure Limits : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim- its for Air Contaminants : 8-hour, time-weighted average : Short-term exposure limit : Time-weighted average concentration for up to a 10-hour workday during a 40-hour workweek : STEL - 15-minute TWA exposure that should not be exceeded at any time during a workday : 8-hour time weighted average Hand Sanitizer Revision Date : 03/26/2020 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, unless specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, including an assessment of the appropriateness of the SDS material in the user's end product, if applicable.Microsoft Word for Microsoft 365