Datasheet for Bissell models including: Pro Oxy Spot Stain
Page Safety Data Sheet according to OSHA HCS 2012, 1272/2008/EC (CLP), and UN GHS Pro Oxy Spot & Stain , Adv Pro Spot & Stain Oxy, Professional
Safety Data Sheet according to OSHA HCS 2012, 1272/2008/EC (CLP), and UN GHS Pro Oxy Spot & Stain , Adv Pro Spot & Stain + Oxy, Professional Spot & Stain + Oxy, Adv Professional Spot & Stain + Oxy Print Date: 6/25/2021 Page 1 of 7 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Pro Oxy Spot & Stain, Advanced Pro Oxy Spot & Stain, Professional Spot & Stain + Oxy, Advanced Professional Spot & Stain + Oxy (2034, 2034C, 2038, 2038C, 2038W, 20389, 1609949, 1609950, 1615277, 1620733, 1620734) 1.2. Relevant identified uses of the substance or mixture and uses advised against Carpet or Upholstery cleaner 1.3. Details of the supplier of the substance or mixture BISSELL Homecare, Inc. PO Box 1888, Grand Rapids, MI 49501 (616) 453- 4451, www.BISSELL.com, SDS@BISSELL.com 1.4. Emergency telephone number Prosar (Medical) 1 866-303-6951 Chemtrec (US) 1 800-424-9300 acct 2808 Chemtrec (Int'l) 1 703-527-3887 SECTION 2: Hazard identification 2.1. Classification of the mixture and 2.2. Label elements Regulation Classification Pictogram Signal word CLP (EC) No Serious eye irritant Warning 1272/2008 (Category 2), H319 HCS 2012, UN GHS Eye irritant None (Category 2B), H318 Warning Hazard/ Risk, Precaution/ Safety Statements H319, Causes serious eye irritation P102, Keep out of reach of children. P305 + P351, If in eye: rinse cautiously with water for several minutes. P337 + P313, If eye irritation persists: get medical advice/attention. H318, Causes eye irritation P102, Keep out of reach of children. P305 + P351, If in eye: rinse cautiously with water for several minutes. P337 + P313, If eye irritation persists: get medical advice/attention. 2.3. Other hazards None known SECTION 3: Composition/information on ingredients 3.2 Mixtures Ingredient Percent Classification EC Number/ CAS Number Water 80 Not classified as hazardous 231-791-2/ 7732-18-5 Hydrogen Peroxide C9-C11 Alcohols ethoxylated (CLP) Ox. Liq. 1: H271, Skin Corr. 1A: H314, Acute Tox. 4: H302, Acute Tox. 4: H332, STOT single 5 expos. 3: H335; Aquatic Chronic 3: H412 (GHS) Ox. Liq. 1: H271, Skin Corr. 1A: H314, 231-765-0 / 7722-84-1 Acute Tox. 4: H302, Acute Tox. 4: H332, STOT single expos. 3: H335; Aquatic Chronic 3: H412 3 (CLP) Eye Irritant 1; H318 (GHS) Eye Irritant 1; H318 NA / 68439-46-3 Sodium Citrate 3 Not classified as hazardous 200-675-3 / 68-04-2 Safety Data Sheet according to OSHA HCS 2012, 1272/2008/EC (CLP), and UN GHS Pro Oxy Spot & Stain , Adv Pro Spot & Stain + Oxy, Professional Spot & Stain + Oxy, Adv Professional Spot & Stain + Oxy Print Date: 6/25/2021 Page 2 of 7 SECTION 3: Composition/information on ingredients, cont. 3.2 Mixtures, cont. Linear Alcohol Ethoxylate Sodium Caprylyl Sulfonate 3 (CLP) Eye Irritant 1; H318 (GHS) Eye Irritant 1; H318 2 (CLP) Eye Irritant 2; H319 (GHS) Eye Irritant 2A; H319 Proprietary polymer 226-195-4 / 5324-84-5 Acrylic Polymer 2 Not classified as hazardous Proprietary polymer Alkyl polyglucoside Sodium Polyacrylate Fragrance 2 2 0.5 (CLP) Eye Irritant 1; H318 (GHS) Eye Irritant 1; H318 (CLP) Eye Irritant 2; H319 (GHS) Eye Irritant 2A; H319 (CLP) Skin Sens. 1, H317; Aqua Chronic 2, H411 (GHS) Skin Sens. 1, H317; Aqua Chronic 2, H411 Proprietary polymer Proprietary polymer Blend For full text of the H-statements and other abbreviations see section 16 "Other information". SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: remove person to fresh air. If you are concerned, get medical advice. Skin contact: wash with soap and water. If you are concerned, get medical advice. Eye contact: flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If swallowed: rinse mouth, drink 1-2 glasses of water, do not induce vomiting. If you are concerned, get medical advice. Never give anything by mouth to an unconscious person. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1 Information on toxicological effects 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Extinguishing media Non-combustible. Use a fire fighting agent suitable for surrounding fire. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous decomposition during combustion: carbon monoxide, carbon dioxide, irritant vapors or gases, oxides of sulphur and oxygen. 5.3. Advice for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid contact with skin and eyes. 6.2. Environmental precautions Do not empty into drains / surface water / ground water 6.3. Methods and material for containment and cleaning up Remove with liquid-absorbing material (sand, peat, sawdust). Wash away residue with plenty of water. Dispose of contaminated material as waste according to Chapter 13. 6.4. Reference to other sections Refer to Section 8 and Section 13 for more information Safety Data Sheet according to OSHA HCS 2012, 1272/2008/EC (CLP), and UN GHS Pro Oxy Spot & Stain , Adv Pro Spot & Stain + Oxy, Professional Spot & Stain + Oxy, Adv Professional Spot & Stain + Oxy Print Date: 6/25/2021 Page 3 of 7 SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid skin and eye contact. See advice in chapter 8 7.2. Conditions for safe storage including any incompatibilities Keep out of the reach of children. Store in closed original container in a well-ventilated place 7.3. Specific end use(s) See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations. SECTION 8: Exposure controls/personal protection 8.1 Control parameters Occupational exposure limits, If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient PPM Hydrogen Peroxide 231765-0 / 7722-84-1 1 Hydrogen Peroxide 231765-0 / 7722-84-1 2 mg/ m3 1.4 Type Time weighted average; TWA 2..8 Short-term exposure limit; STEL Remark OSHA, NIOSH, UK HSE UK HSE UK HSC : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling Biological limit values: No biological limit values exist for any of the components listed in Section 3 SECTION 8: Exposure controls/personal protection, continued 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. 8.2.2. Personal protective equipment (PPE) Eye/face protection None required. Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Material Thickness (mm) Breakthrough Time Neoprene No data available No data available Nitrile rubber. No data available No data available Respiratory protection None required Safety Data Sheet according to OSHA HCS 2012, 1272/2008/EC (CLP), and UN GHS Pro Oxy Spot & Stain , Adv Pro Spot & Stain + Oxy, Professional Spot & Stain + Oxy, Adv Professional Spot & Stain + Oxy Print Date: 6/25/2021 Page 4 of 7 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Clear, light-straw liquid Physical state Liquid Odor Pleasant Odor Threshold > 50 mg/ m3 pH 4.5- 5.5 Flash Point Not flammable Melting Point/Range Not applicable Freezing point 0°C, 32°F Boiling Point/Range 100 °C, 212°F Autoignition None Temperature Flammability Limits in Air Not flammable Explosive properties Not explosive Oxidizing properties Vapor pressure Vapor density Density Partition coefficient Water solubility Viscosity Evaporation rate Decomposition Not oxidizing according to Regulation (CE) No 1272/2008 < 17.5 mmHg @ 20°C No information available 1.0 g/mL @ 20 °C < 1 Kow Completely Soluble@20 °C < 20 cP @ 20C >1 (BuAc = 1) None 9.2. Other information Volatile organic compounds (VOC) 0 g/l SECTION 10: Stability and reactivity 10.1 Reactivity Stable under normal conditions 10.2 Chemical stability Stable 10.3 Possibility of hazardous reactions No dangerous reaction known under conditions of normal use 10.4 Conditions to avoid Heat 10.5 Incompatible materials Combustible materials. Copper alloys, galvanized iron. Strong reducing agents. Heavy metals. Iron. Contact with metals, metallic ions, alkalis, reducing agents and organic matter may produce decomposition 10.6 Hazardous decomposition products Oxygen which supports combustion. Liable to produce overpressure in container. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information 11.1 Information on Toxicological effects Information given is based on product testing, and/or similar products, and/or components. The information below may not agree with the EU material classification in Section 2 and/or the ingredient classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition, statements and data presented in Section 11 are based on UN GHS calculation rules and classifications derived from BISSLL assessments. CMR effects: Not expected to be carcinogenic. Not considered a mutagenic hazard. No toxicity to reproduction Acute oral toxicity: LD50:> 2000 - 5000 mg / kg Species: rat Acute inhalation toxicity: LC50:> 20 mg / l Acute dermal toxicity: LD50:> 2000 - 5000 mg / kg Skin: Result: Not irritating. Eye irritation: Result: Causes serious eye irritation. Safety Data Sheet according to OSHA HCS 2012, 1272/2008/EC (CLP), and UN GHS Pro Oxy Spot & Stain , Adv Pro Spot & Stain + Oxy, Professional Spot & Stain + Oxy, Adv Professional Spot & Stain + Oxy Print Date: 6/25/2021 Page 5 of 7 SECTION 11: Toxicological information, continued 11.1 Information on Toxicological effects, continued Sensitization: Not expected to be a sensitizer Toxicity Repeated dose: Not expected to be a hazard. Target organ toxicity - repeated exposure: Not expected to be a hazard. SECTION 12: Ecological information 12.1. Toxicity Toxicity to fish: LC50:> 100-1000 mg / l, Exposure time: 96 h Species: Fish Toxicity to daphnia and other invertebrates that live in water: EC50:> 100 to 1000 mg / l, exposure time: 48 h Species: Daphnia magna, the value is estimated from tests on similar products. Toxicity to algae: EC50:> 100 to 1000 mg / l, Exposure time: 72 h Species: algae, the value is estimated from tests on similar products. 12.2. Persistence and degradability Biodegradability: Result: According to the results of tests of biodegradability this product is considered as being readily biodegradable. > 60%, Method: OECD Guide- line 301 D - Ready Biodegradability: Closed Bottle Test 12.3. Bioaccumulative potential Bioaccumulation: No accumulation expected 12.4. Mobility in soil If the product enters soil, one or more constituents will or may be mobile and may contaminate groundwater. 12.5. Results of the PBT and vPvB assessment Results of PBT assessment: This substance does not meet the Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria. 12.6. Other adverse effects No data available SECTION 13: Disposal considerations Waste from residues / unused products: The concentrated contents or contaminated packaging should be disposed of by a certified handler or according to the site permit. Release of waste to sewers is discouraged. Small amounts may be diluted with plenty of water and washed away. Dispose of bigger amounts in accordance with Local Authority requirements The cleaned packaging material is suitable for energy recovery or recycling in line with local legislation. Discharge used solutions to drain European Waste Catalogue: 20 01 30 - detergents other than those mentioned in 20 01 29. Empty packaging Recommendation: Non contaminated packagings may be recycled. Recommended cleansing agents: Water SECTION 14: Transportation information ADR: Not hazardous for transport. IMDG: Not hazardous for transport. IATA: Not hazardous for transport RID: Not hazardous for transport DOT: Not hazardous for transport SECTION 15: Regulatory information Safety Data Sheet according to OSHA HCS 2012, 1272/2008/EC (CLP), and UN GHS Pro Oxy Spot & Stain , Adv Pro Spot & Stain + Oxy, Professional Spot & Stain + Oxy, Adv Professional Spot & Stain + Oxy Print Date: 6/25/2021 Page 6 of 7 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Workplace Exposure Limits EH40. Commission Directive 2000/39/EC - indicative occupational exposure limit values Regulation (EC) No 1272/2008 Regulation on the Classification, Labeling and Packaging of Substances and Mixtures (as amended). Regulation (EC) No 1907/2006 Registration, Evaluation, Authorization and Restriction of Chemicals (as amended). Authorisations (Title VII Regulation 1907/2006) No specific authorisations are noted for this product. Restrictions (Title VIII Regulation 1907/2006) No specific restrictions of use are noted for this product. Detergent Regulation 648/2004/EC Water hazard classification (Germany): WGK 1 water pollutant (Self-assessment) slightly hazardous to water Global inventory/ Notification status CH INV: Y (positive listing) The composition contains a polymer. The monomers of this polymer has been noted. US.TSCA: Y (positive listing) All chemical substances in this product are either listed in TSCA inventory list or are in accordance with exceptions TSCA inventory list DSL: Y (positive listing) All components of this product are on the Canadian DSL list. AICS: Y (positive listing) Compliance with the inventory NZIoC: N (Negative listing) Compliance with the inventory ENCS: Y (positive listing) Compliance with the inventory ISHL: Y (positive listing) Compliance with the inventory KECI: Y (positive listing) Compliance with the inventory PICCS: Y (positive listing) Compliance with the inventory IECSC: Y (positive listing) Compliance with the inventory For explanation of abbreviations, see chapter 16. 15.2. Chemical Safety Assessment A Chemical Safety Assessment is not required for this mixture SECTION 16: Other information The labeling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: According to regulation (EC) No 1272/2008 H271 May cause fire or explosion; strong oxidizer H290 May be corrosive to metals. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction H318 Causes serious eye damage H319 H320 H332 H335 H411 H412 Causes serious eye irritation. Causes eye irritation Harmful if inhaled May cause respiratory irritation Toxic to aquatic life with long lasting effects Harmful to aquatic life with long lasting effects. Abbreviations CH INV Switzerland. New notified guest substances and preparations Declared US.TSCA United States TSCA Inventory DSL Canadian Domestic Substances List (DSL) AICS Australia Inventory of Chemical Substances (AICS) NZIoC New Zealand. Inventory of Chemical Substances ENCS Japan. ENCS - Existing and New Chemical Substances Inventory ISHL Japan. ISHL - Inventory of Chemical Substances (METI) SECTION 16: Other information, continued Abbreviations, continued KECI Korea. Korean Exisiting Chemicals Inventory (KECI) Safety Data Sheet according to OSHA HCS 2012, 1272/2008/EC (CLP), and UN GHS Pro Oxy Spot & Stain , Adv Pro Spot & Stain + Oxy, Professional Spot & Stain + Oxy, Adv Professional Spot & Stain + Oxy PICCS IECSC Philippines Inventory of Chemicals and Chemical Substances (PICCS) China Inventory of Existing Chemical Substances in China (IECSC) UK HSC : UK Health and Safety Commission ADR European Agreement concerning the International Carriage of Dangerous Goods by Road DOT Department of Transportation IATA International Air Transport Association IMDG International Maritime Code for Dangerous Goods OSHA Occupational Health Safety Association RID Regulation concerning the international carriage of dangerous goods by rail Print Date: 6/25/2021 Page 7 of 7 The information herein is presented in good faith and believed to be accurate as of the effective date shown below. However, no warranty, expressed or implied, is given. Regulatory requirements are subject to change and may differ from one location to another. It is the buyer's responsibility to ensure that its activities comply with federal, state or Provincial, and local laws. Effective Date: October 8, 2020 Supersedes: June 19, 2020 Prepared By: Don Mahaffy BISSELL Homecare, Inc. 2345 Walker Ave NW P.O. Box 1888 Grand Rapids, MI 49544 USA Tel: +1 (616) 453-4451 Fax: +1 (616) 453-1383 http://www.bissell.com/ SDS@BISSELL.com This SDS has been modified in the following sections: Model numberMicrosoft Word for Microsoft 365