SAFETY DATA SHEET
1. Identification
Important information Product identifier
*** This Safety Data Sheet is only authorised for use by HP for HP Original products. Any unauthorised use of this Safety Data Sheet is strictly prohibited and may result in legal action being taken by HP. ***
5184-6621
Other means of identification None.
Recommended use
Inkjet printing. For use only in inkjet printing
Recommended restrictions
None known.
Manufacturer/Importer/Supplier/Distributor information
HP Inc.
1501 Page Mill Road
Palo Alto, CA 94304-1112
United States
Telephone
650-857-1501
HP Inc. health effects line (Toll-free within the US) (Direct) HP Inc. Customer Care Line (Toll-free within the US) (Direct) Email:
1-800-457-4209 1-760-710-0048
1-800-474-6836 1-208-323-2551 hpcustomer.inquiries@hp.com
2. Hazard(s) identification
Physical hazards Health hazards
Environmental hazards OSHA defined hazards
Not classified.
Reproductive toxicity (fertility, the unborn child) Not classified.
Not classified.
Label elements
Category 1B
Signal word Hazard statement Precautionary statement
Prevention
Response Storage Disposal
Danger May damage fertility or the unborn child.
Wear protective gloves/protective clothing/eye protection. Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. IF exposed or concerned: Get medical advice/attention. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.
Material name: 5184-6621 12414 Version #: 04 Revision date: 17-Jun-2020 Issue date: 28-Jun-2015
SDS US
1 / 8
Hazard(s) not otherwise classified (HNOC)
Supplemental information
Carbon black is classified by the IARC as a Group 2B carcinogen (the substance is possibly carcinogenic to humans). Carbon black in this preparation, due to its bound form, does not present this carcinogenic risk. None of the other ingredients in this preparation are classified as carcinogens according to ACGIH, EU, IARC, MAK, NTP or OSHA. Potential routes of overexposure to this product are skin and eye contact. Inhalation of vapor and ingestion are not expected to be significant routes of exposure for this product under normal use conditions. Complete toxicity data are not available for this specific formulation.
2-pyrrolidone: OSHA Hazard Communication Standard cut-off value, Reproductive toxicity Category 1B, fertility or the unborn child 3%. Mixture classification threshold based on data related to developmental toxicity in animals. No adverse effects on sexual function or damage to fertility have been observed in an animal study. See Section 11.
3. Composition/information on ingredients
Mixtures Chemical name Water 2-pyrrolidone Substituted diol* Black Pigment*
Common name and synonyms
CAS number 7732-18-5 616-45-5 Proprietary* Proprietary*
% 60-70 <20 <10 <2.5
Composition comments
This ink supply contains an aqueous ink formulation. This product has been evaluated using criteria specified in 29 CFR 1910.1200 (Hazard Communication Standard).
Carbon black is present only in a bound form in this preparation.
2-pyrrolidone: OSHA Hazard Communication Standard cut-off value 3%. Mixture classification threshold based on data related to developmental toxicity in animals. No adverse effects on sexual function or damage to fertility have been observed in an animal study. See Section 11.
*Proprietary
4. First-aid measures
Inhalation Skin contact
Eye contact
Ingestion Most important symptoms/effects, acute and delayed
Remove to fresh air. If symptoms persist, get medical attention.
Wash affected areas thoroughly with mild soap and water. Get medical attention if irritation develops or persists. Do not rub eyes. Immediately flush with large amounts of clean, warm water (low pressure) for at least 15 minutes or until particles are removed. If irritation persists get medical attention. If ingestion of a large amount does occur, seek medical attention.
Not available.
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing media
Specific hazards arising from the chemical
Special protective equipment and precautions for firefighters
Specific methods
Dry chemical, CO2, water spray or regular foam. None known. Not applicable. Not available. None established.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Methods and materials for containment and cleaning up
Environmental precautions
Wear appropriate personal protective equipment.
Dike the spilled material, where this is possible. Absorb with inert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recover using pumps. Do not let product enter drains. Do not flush into surface water or sanitary sewer system.
Material name: 5184-6621 12414 Version #: 04 Revision date: 17-Jun-2020 Issue date: 28-Jun-2015
SDS US
2 / 8
7. Handling and storage
Precautions for safe handling Conditions for safe storage, including any incompatibilities
Avoid contact with skin, eyes and clothing. Keep out of the reach of children. Keep away from excessive heat or cold.
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
Type
Value
Black Pigment
PEL
3.5 mg/m3
US. ACGIH Threshold Limit Values Components
Type
Value
Form
Black Pigment
TWA
3 mg/m3
Inhalable fraction.
US. NIOSH: Pocket Guide to Chemical Hazards
Components
Type
Value
Black Pigment
TWA
0.1 mg/m3
Biological limit values
No biological exposure limits noted for the ingredient(s).
Exposure guidelines
Exposure limits have not been established for this product.
Appropriate engineering controls
Not available.
Individual protection measures, such as personal protective equipment
Eye/face protection
Not available.
Skin protection Hand protection
Not available.
Other
Use personal protective equipment to minimize exposure to skin and eye.
Respiratory protection
Not available.
Thermal hazards
Not available.
General hygiene considerations
Handle in accordance with good industrial hygiene and safety practice.
9. Physical and chemical properties
Appearance Physical state Form Color
Odor Odor threshold
Liquid. Not available. Black. Not available. Not available.
pH
9
Melting point/freezing point
Not available.
Initial boiling point and boiling Not available. range
Flash point Evaporation rate Flammability (solid, gas)
> 230.0 °F (> 110.0 °C) Pensky-Martens Closed Cup Not available. Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower (%)
Not available.
Flammability limit - upper (%)
Explosive limit - lower (%)
Not available. Not available.
Explosive limit - upper (%) Not available.
Vapor pressure
Not available.
Material name: 5184-6621 12414 Version #: 04 Revision date: 17-Jun-2020 Issue date: 28-Jun-2015
SDS US
3 / 8
Vapor density Solubility(ies)
Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Other information
Oxidizing properties Percent volatile Specific gravity VOC
Not available.
Not available. Not available.
Not available. Not available. Not available. For other VOC regulatory data/information see Section 15. Not determined 16 % estimated 1 k/L 256 g/l (Determined by EPA Method 24)
10. Stability and reactivity
Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products
Not available. Stable under recommended storage conditions. None known.
Not available. Incompatible with strong bases and oxidizing agents. Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons., fluorinated hydrocarbons and hydrogen fluoride.
11. Toxicological information
Information on likely routes of exposure
Inhalation
Under normal conditions of intended use, this material is not expected to be an inhalation hazard.
Skin contact
Contact with skin may result in mild irritation.
Eye contact
Contact with eyes may result in mild irritation.
Ingestion
Health injuries are not known or expected under normal use.
Symptoms related to the physical, chemical and toxicological characteristics
Not available.
Information on toxicological effects
Acute toxicity
Based on available data, the classification criteria are not met.
Components
Species
Test Results
2-pyrrolidone (CAS 616-45-5)
Acute
Oral
LD50
Rat
> 5000 mg/kg
Black Pigment
Acute
Oral
LD50
Rat
> 10000 mg/kg
Skin corrosion/irritation
Serious eye damage/eye irritation
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met. Not classified as an irritant according to, OECD 405.
Respiratory or skin sensitization Respiratory sensitization Based on available data, the classification criteria are not met.
Skin sensitization
Based on available data, the classification criteria are not met.
Germ cell mutagenicity
Based on available data, the classification criteria are not met. Negative, does not indicate mutagenic potential (Ames Test: Salmonella typhimurium)
Material name: 5184-6621 12414 Version #: 04 Revision date: 17-Jun-2020 Issue date: 28-Jun-2015
SDS US
4 / 8
Carcinogenicity
Based on available data, the classification criteria are not met.
Carbon black is classified as a carcinogen by the IARC (possibly carcinogenic to humans, Group 2B) and by the State of California under Proposition 65. In their evaluations of carbon black, both organizations indicate that exposure to carbon black, per se, does not occur when it remains bound within a product matrix, specifically, rubber, ink, or paint. Carbon black is present only in a bound form in this preparation.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed. US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity
May damage fertility or the unborn child.
Specific target organ toxicity single exposure
Specific target organ toxicity repeated exposure
Aspiration hazard
Further information
2-pyrrolidone: This component showed developmental effects only at high doses that were toxic to pregnant test animals (OECD Testing Guideline 414: Prenatal Developmental Toxicity Study). Uptake by people of small doses is not expected to cause developmental toxicity. This component has not caused adverse effects on sexual function or damage to fertility in an animal study (OECD Testing Guideline 443: Extended One-Generation Reproductive Toxicity Study). Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met. Complete toxicity data are not available for this specific formulation Refer to Section 2 for potential health effects and Section 4 for first aid measures.
12. Ecological information
Ecotoxicity
No information available.
Product 5184-6621
Aquatic Acute Fish
Species
Test Results
LC50
Fathead minnow (Pimephales promelas) > 750 mg/l, 96 hours
Components
Species
Test Results
2-pyrrolidone (CAS 616-45-5)
Aquatic
Crustacea
EC50
Water flea (Daphnia pulex)
13.21 mg/l, 48 hours
Persistence and degradability Bioaccumulative potential
Not available. Not available.
Partition coefficient n-octanol / water (log Kow) 2-pyrrolidone
Mobility in soil
Not available.
Other adverse effects
Not available.
-0.85
13. Disposal considerations
Disposal instructions
Do not allow this material to drain into sewers/water supplies. Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations. HP's Planet Partners (trademark) supplies recycling program enables simple, convenient recycling of HP original inkjet and LaserJet supplies. For more information and to determine if this service is available in your location, please visit http://www.hp.com/recycle.
14. Transport information
DOT UN number UN proper shipping name
Not available. Not Regulated
Material name: 5184-6621 12414 Version #: 04 Revision date: 17-Jun-2020 Issue date: 28-Jun-2015
SDS US
5 / 8
Transport hazard class(es)
Class Subsidiary risk Packing group Environmental hazards
Not available. Not available.
Marine pollutant
No
Special precautions for user Not available.
IATA
UN number
Not available.
UN proper shipping name Not Regulated
Transport hazard class(es)
Class
Not available.
Subsidiary risk
-
Packing group
Not available.
Environmental hazards
No
Special precautions for user Not available.
IMDG
UN number
Not available.
UN proper shipping name Not Regulated
Transport hazard class(es)
Class Subsidiary risk Packing group Transport hazard class(es)
Not available. Not available.
Marine pollutant
No
EmS
Not available.
Special precautions for user Not available.
ADR
UN number
Not available.
UN proper shipping name Not Regulated
Transport hazard class(es)
Class
Not available.
Subsidiary risk
-
Hazard No. (ADR)
Not available.
Tunnel restriction code Not available.
Packing group
Not available.
Environmental hazards
No
Special precautions for user Not available.
Further information
Not a dangerous good under DOT, IATA, ADR, IMDG, or RID.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC code: Not applicable.
15. Regulatory information
US federal regulations
US TSCA 12(b): Does not contain listed chemicals. US EPA TSCA Inventory: All chemical substances in this product comply with all rules or orders under TSCA.
Toxic Substances Control Act (TSCA)
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed. SARA 304 Emergency release notification
Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.
Material name: 5184-6621 12414 Version #: 04 Revision date: 17-Jun-2020 Issue date: 28-Jun-2015
SDS US
6 / 8
Superfund Amendments and Reauthorization Act of 1986 (SARA) SARA 302 Extremely hazardous substance Not listed.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
No intentionally added HAP substances. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act (SDWA)
Not regulated.
Other information
VOC content (less water, less exempt compounds) = 807 g/L (U.S. requirement, not for emissions) VOC data based on formulation (Organic compounds minus solids) US EPA Method 24
Regulatory information
All chemical substances in this HP product have been notified or are exempt from notification under chemical substances notification laws in the following countries: US (TSCA), EU (EINECS/ELINCS), Switzerland, Canada (DSL/NDSL), Australia, Japan, Philippines, South Korea, New Zealand, and China.
16. Other information, including date of preparation or last revision
Issue date Revision date Version # Other information
28-Jun-2015 17-Jun-2020
04 This SDS was prepared in accordance with USA OSHA Hazard Communications regulation (29 CFR 1910.1200).
Disclaimer
This Safety Data Sheet document is provided without charge to customers of HP. Data is the most current known to HP at the time of preparation of this document and is believed to be accurate. It should not be construed as guaranteeing specific properties of the products as described or suitability for a particular application. This document was prepared to the requirements of the jurisdiction specified in Section 1 above and may not meet regulatory requirements in other countries.
Revision information
This safety data sheet is meant to convey information about HP inks (toners) provided in HP Original ink (toner) supplies. If our Safety Data Sheet has been provided to you with a refilled, remanufactured, compatible or other non-HP Original supply please be aware that the information contained herein was not meant to convey information about such products and there could be considerable differences from information in this document and the safety information for the product you purchased. Please contact the seller of the refilled, remanufactured or compatible supplies for applicable information, including information on personal protective equipment, exposure risks and safe handling guidance. HP does not accept refilled, remanufactured or compatible supplies in our recycling programs.
Hazard(s) identification: Supplemental information Composition/information on ingredients: Composition comments Toxicological information: Reproductivity
Material name: 5184-6621 12414 Version #: 04 Revision date: 17-Jun-2020 Issue date: 28-Jun-2015
SDS US
7 / 8
Explanation of abbreviations
ACGIH CAS CERCLA CFR COC DOT EPCRA IARC NIOSH NTP OSHA PEL RCRA REC REL SARA STEL TCLP TLV TSCA VOC
American Conference of Governmental Industrial Hygienists Chemical Abstracts Service Comprehensive Environmental Response Compensation and Liability Act Code of Federal Regulations Cleveland Open Cup Department of Transportation Emergency Planning and Community Right-to-Know Act (aka SARA) International Agency for Research on Cancer National Institute for Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Resource Conservation and Recovery Act Recommended Recommended Exposure Limit Superfund Amendments and Reauthorization Act of 1986 Short-Term Exposure Limit Toxicity Characteristics Leaching Procedure Threshold Limit Value Toxic Substances Control Act Volatile Organic Compounds
Material name: 5184-6621 12414 Version #: 04 Revision date: 17-Jun-2020 Issue date: 28-Jun-2015
SDS US
8 / 8