1452 ; System Clean Inc SC 794 Heavy Duty Industrial Cleaner Degreaser SDS 081215x 1452System DegreaserSDS 081215 SCI R
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Date: August 12, 2015 SAFETY DATA SHEET SECT ION 1 - IDENT IF ICAT ION Product identifier used on the label: SC-794 Heavy Duty Industrial Cleaner/Degreaser Other means of Identification: 1 4 5 2 Recommended use of the chemical and restrictions on use: For professional use only. Manufacturer/Supplier System Clean Inc. 50602 N. Michigan Road South Bend, IN 46637 www.systemcleaninc.com Telephone: 800-890-0678 Fax: 574-273-3171 24 Hr. Emergency Tel. #: Chem Tel Inc 1-800-255-3924 SECT ION 2 - HAZ ARDS IDENT IF ICAT ION Classification of the chemical: Skin corrosion/irritation Serious eye damage/eye irritation Category 1 Sub-category B Category 1 Label elements: Signal Word: Danger Hazard statement(s): Causes severe skin burns and eye burns. Precautionary statement(s) Do not breathe dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Store locked up. Dispose of contents/container to an approved waste disposal plant If swallowed: Rinse mouth. Do NOT induce vomiting. Immediately call a poison center of doctor/physician. If on skin (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. Immediately call a poison center of doctor/physician. If inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a poison center of doctor/physician. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison control center of doctor/physician. Hazard pictogram(s) Other hazards not otherwise classified: None determined. Unknown Acute Toxicity: 1.45% of the mixture consists of ingredient(s) of unknown toxicity. SECT ION 3 - COMPOSIT ION/INF ORMAT ION ON INGREDIENT S Chemical Name, Common Name & Synonyms: CAS # Weight-% Potassium hydroxide D-Sodium Silicate Solution 1310-58-3 1344-09-8 <5 <1 EDTA 60-00-4 <1 Sodium hydroxide 1310-73-2 <1 Proprietary Proprietary <1 Triethanolamine 102-71-6 <1 ** If the chemical name/CAS # is “proprietary” and/or the weight % is shown as a range, this information had been withheld as a trade secret. SECT ION 4 - F IRST -AID MEASURES Description of first aid measures: If swallowed: Rinse mouth. Do NOT induce vomiting. Immediately call a poison center or doctor/physician. If on skin (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. If inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a poison center or doctor/physician. If in eyes: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician. Most Important symptoms and effects, both acute and delayed: Causes severe skin burns and eye damage. Indication of any immediate medical attention and special treatment needed: Treat symptomatically SECTION 5 - FIRE-FIGHTING MEASURES Extinguishing media: Suitable extinguishing media: Use extinguishable measures that are appropriate to local circumstances and the surrounding environment. Unsuitable determined. extinguishing media: Not Special hazards arising from the substance or mixture: Material is corrosive. Special protective equipment and precautions for firefighters: Protective equipment for fire-fighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Special fire-fighting procedures: Not applicable. SECTION 6 - ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Use personal protective equipment as required. Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See section 12, Ecological Information. See Section 13: DISPOSAL CONSIDERATIONS. Methods and material for containment and cleaning up: Prevent further leakage or spillage if safe to do so. Keep in suitable, closed containers for disposal. SECT ION 7 - HANDL ING AND ST ORAGE Precautions for safe handling: Handle in accordance with good industrial hygiene and safety practice. Use personal protection recommended in Section 8. Avoid contact with skin, eyes or clothing. Do not breathe dust/fumes/gas/vapors/spray. Wash face, hands, and any exposed skin thoroughly after handling. Conditions for safe storage: Keep container tightly closed and store in a cool, dry and well-ventilated place. Keep out of the reach of children. Store locked up. Incompatible materials: Acids. Oxidizing agents. Bleach. Do not mix with other chemicals or cleaners. SECT ION 8 – EXPOSURE CONT ROL S AND PERSONAL PROT ECT ION Chemical Name Exposure Limits: ACGIH TLV OSHA PEL Potassium hydroxide 1310-58-3 Ceiling: 2 mg/m 3 Sodium hydroxide 1310-73-2 Ceiling: 2 mg/m 3 Triethanolamine 102-71-6 TWA: 5 mg/m Proprietary 3 STEL: 400 ppm TWA 200 ppm NIOSH IDLH (vacated) Ceiling: 2 mg/m 3 Ceiling: 2 mg/m TWA: 2 mg/m 3 (vacated) Ceiling: 2 mg/m IDLH: 10 mg/m 3 3 3 - TWA: 400 ppm 3 TWA: 960 mg/m (vacated) TWA: 400 ppm 3 (vacated) TWA: 980 mg/m (vacated) STEL: 500 ppm 3 (vacated) STEL: 1225 mg/m Exposure controls: Ventilation and engineering measures: Apply technical measures to comply with the occupational exposure limits. Eyewash stations. Showers. Respiratory protection: Ensure adequate ventilation, especially in confined areas. Skin protection: Wear suitable protective clothing. Eye face protection: Wear approved safety goggles where a splash hazard exists. Other protective equipment: Not determined General hygiene considerations: Handle in accordance with good industrial hygiene and safety practice.Wash face, hands, and any exposed skin thoroughly after handling. Was contaminated clothing before reuse. SECT ION 9 - PHYSICAL AND CHEMICAL PROPERT IES Appearance: Clear red liquid Odor: Bland Odor threshold: Not determined pH: 13.2 (concentrate) Melting/Freezing point: No applicable information available Initial boiling point and boiling range: 100 ºC / 212 ºF Flash point: None to boiling Flashpoint (Method): No applicable information available Evaporation rate (BuAe = 1): Similar to water Flammability (solid, gas): Liquid- not applicable Lower flammable limit (% by vol.): Not Flammable Upper flammable limit (% by vol.): Not Flammable Vapor pressure: No applicable information available Vapor density: No applicable information available Relative density: 8.82 lb/gal Solubility in water: Soluble Other solubility(ies): No applicable information available Partition coefficient: No applicable information available Auto ignition temperature: No applicable information available Decomposition temperature: No applicable information available Viscosity: Similar to water Volatile organic Compounds (%VOC's): None Other physical/chemical comments: No applicable information available SECTION 10 - STABILITY AND REACTIVITY Reactivity: Not normally reactive Chemical stability: Stable Possibility of hazardous reactions: No hazardous polymerization Conditions to avoid: Keep out of reach of children. Do not use in areas without adequate ventilation. Avoid contact with incompatible materials. Incompatible materials: Acids. Oxidizing agents. Bleach. Do not mix with other chemicals or cleaners. Hazardous decomposition products: None known based on information supplied. SECT ION 11 - TOXICOLOGICAL INFORMAT ION Information on likely routes of exposure: Routes of entry - inhalation: Avoid breathing vapors or mists. Routes of entry - skin & eye: Causes severe eye damage and skin burns. Routes of entry - Ingestion: Do not taste or swallow. Potential Health Effects: Signs and symptoms of short term (acute) exposure: Symptoms: Please see Section 4 of this SDS for symptoms. Potential Chronic Health Effects: Mutagenicity: Not expected to be mutagenic in humans. Carcinogenicity: No components are listed as carcinogens by ACGIH, IARC, OSHA or NTP. Chemical name Triethanolamine 102-71-6 ACGIH IARC Group 3 NTP OSHA IARC (international Agency for Research on Cancer) Group 3 IARC componenets are “not classifiable as human carcinogens” OSHA (occupational Safety and Health Administration of the US Department of Labor) X - Present Reproductive effects: No applicable information available Sensitization to material: Not applicable Specific target organ effects: Not applicable Medical conditions aggravated by overexposure: Not applicable Toxicological data: Not applicable See the following table for individual ingredient acute toxicity data. Chemical name CAS # LD50 LD50 LC50 (Oral, rat) (Dermal. Rabbit) (4hr, Inhal., rat) - Water 7732-18-5 > 90mL/kg - Potassium hydroxide Alkyl Phenol Ethoxylate 1310-58-3 - = 214 mg/kg = 1310 mg/kg = 2 mL/kg D-Sodium Silicate Solution 1344-09-8 = 1153 mg/kg >4640 mg/kg - EDTA Sodium hydroxide Proprietary Triethanolamine 60-00-4 1310-73-2 102-71-6 =1700 mg/kg =20000 mg/kg =4190 mg/kg - Proprietary - =4396 mg/kg =1350 mg/kg =20800 mg/kg > 2000 mg/kg (Rabbit) > 16 mL/kg (rat) =12800 mg/kg (rat) =12870 mg/kg (Rabbit) =72.6 mg/L 4 h *All empty cells no applicable information available Other important toxicological hazards: None reported. SECT ION 12 - ECOL OGICAL INF ORMAT ION Ecotoxicity: May be dangerous for the environment. No data is available on the product itself. Should not be released into the environment. Chemical Name Algae/aquatic plants Fish Toxicity to Microorganisms Crustacea Potassium hydroxide 1310-58-3 - 80: 96 h Gambusia affinis mg/L LC50 static - - - 216: 96 h Daphnia magna mg/L EC50 - 113: 48 h Daphnia magna mg/L EC50 Static - - - 10000: 24 h Daphnia magna mg/L EC50 1000: 48 h Daphnia magna mg/L EC50 Static - 1386: 24 h Daphnia D-Sodium Silica Solution 1344-09-8 - EDTA 60-00-4 1.01: 72 h Desmodesmus subspicatus mg/L EC50 Sodium hydroxide 1310-73-2 - Proprietary 19000: 96 h Pseudokirchneriella subcapitata mg/L EC50 Triethanolamine 216: 72 h 301-478: 96 h Leppomis macrochirus mg/L LC50 3185: 96 h Brachydanio rerio mg/L LC50 semistatic 34-62: 96 h Lepomis macrochirus mg/L LC50 static 44.276.5: 96 h Pimephales promelas mg/L LC50 static 45.4: 96 h Oncorhynchus mykiss mg/L LC50 static 51600: 96 h Oncorhynchus mykiss mg/L LC50 static 41 -47: 96 h Oncorhynchus mykiss mL/L LC50 static 51400: 96 h Pimephales promelas mg/L LC50 static 710: 96 h Pimephales promelas mg/L LC50 10600-13000: 96 h 102-71-6 Proprietary Desmodesmus subspicatus mg/L EC50 169: 96 h Desmodesmus subspicatus mg/L EC50 1000: 96 h Desmodesmus subspicatus mg/L EC50 1000: 72 h Desmodesmus subspicatus mg/L EC50 Pimephales promelas mg/L LC50 flow-though 1000: 9g h Pimephales promelas mg/L LC50 static 4501000: 96 h Lepomis macrochirus mg/L LC50 static 9640: 96 h Pimephales promelas mg/L LC50 flow-through 11130: 96 h Pimephales promelas mg/L LC50 static 1400000: 96 h Lepomis macrochirus µg/L LC50 magna mg/L EC50 - 13299: 48 h Daphnia magna mg/L EC50 Persistence and degradability: No applicable information available Bioaccumulation potential: No applicable information available. Mobility in soil: Chemical Name Potassium hydroxide 1310-58-3 Triethanolamine 102-71-6 Partition Coefficient 0.83 -2.53 Other Adverse Environmental effects: No applicable information available. SECT ION 13 - DISPOSAL CONSIDERAT IONS Handling for disposal: Disposal should be in accordance with applicable regional, national and local laws and regulations. Methods of disposal: Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Status: Chemical Name Potassium hydroxide 1310-58-3 Sodium hydroxide 1310-73-2 California Hazardous Waste Status Toxic Corrosive Toxic Corrosive RCRA: If this product, as supplied, becomes a waste in the United States, it may meet the criteria of a hazardous waste UN defined under RCRA, Title 40 CFR 261. It is the responsibility of the waste generator to determine the proper waste identification and disposal method. For disposal of unused or waste material, check with local, state and federal environmental agencies. SECT ION 14 - T RANSPORT AT ION INF ORMAT ION US 49 CFR/DOT information: UN No.: UN3266 UN Proper Shipping Name: Corrosive liquid, basic, inorganic, n.o.s. (contains Potassium hydroxide) Transport Hazard Class(es): 8 Packing Group: II Special Transportation Note: Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. This material may meet the definition of a marine pollutant. SECT ION 15 - REGUL AT ORY INFORMAT ION TSCA information: All listed ingredients appear on the Toxic Substances Control Act (TSCA) inventory. European EINECs information: All ingredients listed appear on the European EINECs inventory. Canadian Environmental Protection Act (CEPA) information: All ingredients listed appear on the Domestic Substances List (DSL). US Federal Regulations: CERCLA: : This material, as supplied, contains one or more substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs 1000 lb CERCLA/SARA RQ Reportable Quantity - RQ 1000 lb final RQ RQ 454 kg final RQ EDTA 60-00-4 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ Sodium hydroxide 1310-73-2 1000 lb - RQ 1000 lb final RQ RQ 454 kg final RQ Potassium hydroxide 1310-58-3 SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. CWA (Clean Water Act): This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Component CWA – Reportable Quantities CWA – Toxic Pollutants CWA – Priority Pollutants Potassium hydroxide 1310-58-3 (<5) EDTA 60-00-4 (<1) Sodium hydroxide 1310-73-2 (<1) 1000 lb - - CWA – Hazardouns Substances X 5000 lb - - X 1000 lb - - X US State Regulations: California Proposition 65: This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations: Chemical Name Potassium hydroxide 1310-58-3 EDTA 60-00-4 Proprietary New Jersey X Massachusetts X Pennsylvania X X X X Triethanolamine 102-71-6 Proprietary X X X X X X X X SECTION 16 - OTHER INFORMATION NFPA: HMIS: Health Hazards 3 Health Hazards 3 Flammability 0 Flammability 0 Instability 0 Phsyical Hazards 0 Special Hazards Cor Personal Protection X Legend: ACGIH: American Conference of Governmental Industrial Hygienists CAS: Chemical Abstract Services CERCLA: Comprehensive Environmental Response, Compensation, and Liability Act of 1980 CFR: Code of Federal Regulations CSA: Canadian Standards Association DOT: Department of Transportation ECOTOX: U.S. EPA Ecotoxicology Database EINECS: European Inventory of Existing Commercial chemical Substances EPA: Environmental Protection Agency HSDB: Hazardous Substances Data Bank IARC: International Agency for Research on Cancer IUCLID: International Uniform Chemical Information Database LC: Lethal Concentration LD: Lethal Dose NIOSH: National Institute of Occupational Safety and Health NTP: National Toxicology Program OECD: Organization for Economic Co operation and Development OSHA: Occupational Safety and Health Administration PEL: Permissible exposure limit RCRA: Resource Conservation and Recovery Act RTECS: Registry of Toxic Effects of Chemical Substances SARA: Superfund Amendments and Reauthorization Act SDS: Safety Data Sheet Material Safety Data Sheet STEL: Short Term Exposure Limit TOG: Canadian Transportation of Dangerous Goods Act & Regulations TLV: Threshold Limit Values TWA: Time Weighted Average WHMIS: Workplace Hazardous Materials Identification System DISCLAIMER Information for this material safety data sheet was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of this supplier, it is assumed that users of this material have been fully trained accordingly to the mandatory requirements of GHS. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of, or reliance on, any information contained within this form. END OF DOCUMENT
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