1452 ; System Clean Inc SC 794 Heavy Duty Industrial Cleaner Degreaser SDS 081215x 1452System DegreaserSDS 081215 SCI R

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Date: August 12, 2015
SAFETY DATA
SHEET
SECT
ION 1 -
IDENT
IF
ICAT
ION
Product identifier used on the label: SC-794 Heavy Duty Industrial Cleaner/Degreaser
Other means of Identification: 1452
Recommended use of the chemical and restrictions on use: For professional use only.
Manufacturer/Supplier
System Clean Inc.
50602 N. Michigan Road
South Bend, IN 46637
www.systemcleaninc.com
Telephone: 800-890-0678
Fax: 574-273-3171
24 Hr. Emergency Tel. #: Chem Tel Inc 1-800-255-3924
SECT
ION 2 -
HAZ
ARDS
IDENT
IF
ICAT
ION
Classification of the chemical:
Skin corrosion/irritation Category 1 Sub-category B
Serious eye damage/eye irritation Category 1
Label elements:
Signal Word: Danger
Hazard statement(s): Causes severe skin burns and eye burns.
Precautionary statement(s)
Do not breathe dust/fume/gas/mist/vapors/spray
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Store locked up.
Dispose of contents/container to an approved waste disposal plant
If swallowed: Rinse mouth. Do NOT induce vomiting. Immediately call a poison center of doctor/physician.
If on skin (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash
contaminated clothing before reuse. Immediately call a poison center of doctor/physician.
If inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a
poison center of doctor/physician.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. Immediately call a poison control center of doctor/physician.
Hazard pictogram(s)
Other hazards not otherwise classified: None determined.
Unknown Acute Toxicity: 1.45% of the mixture consists of ingredient(s) of unknown toxicity.
SECT
ION 3 -
COMPOSIT
ION/INF
ORMAT
ION ON
INGREDIENT
S
Chemical Name, Common Name & Synonyms: CAS # Weight-%
Potassium hydroxide 1310-58-3 <5
D-Sodium Silicate Solution 1344-09-8 <1
EDTA 60-00-4 <1
Sodium hydroxide 1310-73-2 <1
Proprietary Proprietary <1
Triethanolamine 102-71-6 <1
** If the chemical name/CAS # is “proprietary” and/or the weight % is shown as a range, this information
had been withheld as a trade secret.
SECT
ION 4 -
F
IRST
-AID MEASURES
Description of first aid measures:
If swallowed: Rinse mouth. Do NOT induce vomiting. Immediately call a poison center or doctor/physician.
If on skin (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash
contaminated clothing before reuse.
If inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a
poison center or doctor/physician.
If in eyes: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or
doctor/physician.
Most Important symptoms and effects, both acute and delayed: Causes severe skin burns and eye damage.
Indication of any immediate medical attention and special treatment needed: Treat symptomatically
SECTION 5 - FIRE-FIGHTING MEASURES
Extinguishing media:
Suitable extinguishing media: Use extinguishable measures that are appropriate to local
circumstances and the surrounding environment.
Unsuitable extinguishing media: Not
determined.
Special hazards arising from the substance or mixture: Material is corrosive.
Special protective equipment and precautions for firefighters:
Protective equipment for fire-fighters: As in any fire, wear self-contained breathing apparatus
pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
Special fire-fighting procedures: Not applicable.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures: Use personal protective equipment as
required. Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See section 12, Ecological Information.
See Section 13: DISPOSAL CONSIDERATIONS.
Methods and material for containment and cleaning up: Prevent further leakage or spillage if safe to do so. Keep
in suitable, closed containers for disposal.
SECT
ION 7 -
HANDL
ING AND
ST
ORAGE
Precautions for safe handling: Handle in accordance with good industrial hygiene and safety practice. Use
personal protection recommended in Section 8. Avoid contact with skin, eyes or clothing. Do not breathe
dust/fumes/gas/vapors/spray. Wash face, hands, and any exposed skin thoroughly after handling.
Conditions for safe storage: Keep container tightly closed and store in a cool, dry and well-ventilated place. Keep
out of the reach of children. Store locked up.
Incompatible materials: Acids. Oxidizing agents. Bleach. Do not mix with other
chemicals or cleaners.
SECT
ION 8 – EXPOSURE
CONT
ROL
S AND PERSONAL
PROT
ECT
ION
Exposure Limits:
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Potassium hydroxide
1310-58-3 Ceiling: 2 mg/m
3
(vacated) Ceiling: 2 mg/m3Ceiling: 2 mg/m3
Sodium hydroxide
1310-73-2 Ceiling: 2 mg/m
3
TWA: 2 mg/m
3
(vacated) Ceiling: 2 mg/m3 IDLH: 10 mg/m3
Triethanolamine
102-71-6 TWA: 5 mg/m
3
-
Proprietary STEL: 400 ppm
TWA 200 ppm TWA: 400 ppm
TWA: 960 mg/m3
(vacated) TWA: 400 ppm
(vacated) TWA: 980 mg/m3
(vacated) STEL: 500 ppm
(vacated) STEL: 1225 mg/m3
Exposure controls:
Ventilation and engineering measures: Apply technical measures to comply with the occupational exposure
limits. Eyewash stations. Showers.
Respiratory protection: Ensure adequate ventilation, especially in confined areas.
Skin protection: Wear suitable protective clothing.
Eye face protection: Wear approved safety goggles where a splash hazard exists.
Other protective equipment: Not determined
General hygiene considerations: Handle in accordance with good industrial hygiene and safety practice.Wash
face, hands, and any exposed skin thoroughly after handling. Was contaminated clothing before reuse.
SECT
ION 9 - PHYSICAL AND CHEMICAL
PROPERT
IES
Appearance: Clear red liquid
Odor: Bland
Odor threshold: Not determined
pH: 13.2 (concentrate)
Melting/Freezing point: No applicable information available
Initial boiling point and boiling range: 100 ºC / 212 ºF
Flash point: None to boiling
Flashpoint (Method): No applicable information available
Evaporation rate (BuAe = 1): Similar to water
Flammability (solid, gas): Liquid- not applicable
Lower flammable limit (% by vol.): Not Flammable
Upper flammable limit (% by vol.): Not Flammable
Vapor pressure: No applicable information
available Vapor density: No applicable information
available Relative density: 8.82 lb/gal
Solubility in water: Soluble
Other solubility(ies): No applicable information available
Partition coefficient: No applicable information available
Auto ignition temperature: No applicable information available
Decomposition temperature: No applicable information available
Viscosity: Similar to water
Volatile organic Compounds (%VOC's): None
Other physical/chemical comments: No applicable information available
SECTION 10 - STABILITY AND REACTIVITY
Reactivity: Not normally reactive
Chemical stability: Stable
Possibility of hazardous reactions: No hazardous polymerization
Conditions to avoid: Keep out of reach of children. Do not use in areas without adequate ventilation. Avoid
contact with incompatible materials.
Incompatible materials: Acids. Oxidizing agents. Bleach. Do not mix with other chemicals or cleaners.
Hazardous decomposition products: None known based on information supplied.
SECT
ION 11 - TOXICOLOGICAL
INFORMAT
ION
Information on likely routes of exposure:
Routes of entry - inhalation:
Avoid breathing vapors or mists.
Routes of entry - skin & eye: Causes severe eye damage and skin burns.
Routes of entry - Ingestion: Do not taste or swallow.
Potential Health Effects:
Signs and symptoms of short term (acute) exposure:
Symptoms: Please see Section 4 of this SDS for symptoms.
Potential Chronic Health Effects:
Mutagenicity: Not expected to be mutagenic in humans.
Carcinogenicity: No components are listed as carcinogens by ACGIH, IARC, OSHA or NTP.
Chemical name ACGIH IARC NTP OSHA
Triethanolamine
102-71-6 Group 3
IARC (international Agency for Research on Cancer)
Group 3 IARC componenets are “not classifiable as human carcinogens”
OSHA (occupational Safety and Health Administration of the US Department of Labor)
X - Present
Reproductive effects: No applicable information available
Sensitization to material: Not applicable
Specific target organ effects: Not applicable
Medical conditions aggravated by overexposure: Not applicable
Toxicological data: Not applicable
See the following table for individual ingredient acute toxicity data.
Chemical name CAS # LD
50
(Oral, rat)
LD
50
(Dermal. Rabbit)
LC
50
(4hr, Inhal., rat)
Water 7732-18-5 > 90mL/kg
-
-
-
Potassium hydroxide 1310-58-3 = 214 mg/kg
-
-
Alkyl Phenol Ethoxylate - = 1310 mg/kg
= 2 mL/kg
-
D-Sodium Silicate Solution 1344-09-8 = 1153 mg/kg
>4640 mg/kg -
EDTA 60-00-4 =1700 mg/kg
-
-
Sodium hydroxide 1310-73-2 - =1350 mg/kg
-
Proprietary - =20000 mg/kg
=20800 mg/kg
-
Triethanolamine 102-71-6 =4190 mg/kg
> 2000 mg/kg
(Rabbit) > 16
mL/kg (rat)
-
Proprietary - =4396 mg/kg
=12800 mg/kg
(rat) =12870
mg/kg (Rabbit)
=72.6 mg/L 4 h
*All empty cells no applicable information available
Other important toxicological hazards: None reported.
SECT
ION 12 -
ECOL
OGICAL
INF
ORMAT
ION
Ecotoxicity: May be dangerous for the environment. No data is available on the product itself. Should not be
released into the environment.
Chemical Name Algae/aquatic
plants Fish Toxicity to
Microorganisms Crustacea
Potassium
hydroxide
1310-58-3
- 80: 96 h Gambusia
affinis mg/L LC50
static - -
D-Sodium Silica
Solution
1344-09-8
-
301-478: 96 h
Leppomis
macrochirus mg/L
LC50 3185: 96 h
Brachydanio rerio
mg/L LC50 semi-
static
- 216: 96 h Daphnia
magna mg/L EC50
EDTA
60-00-4
1.01: 72 h
Desmodesmus
subspicatus mg/L
EC50
34-62: 96 h Lepomis
macrochirus mg/L
LC50 static 44.2-
76.5: 96 h
Pimephales
promelas mg/L
LC50 static
- 113: 48 h Daphnia
magna mg/L EC50
Static
Sodium hydroxide
1310-73-2 -
45.4: 96 h
Oncorhynchus
mykiss mg/L LC50
static
- -
Proprietary
19000: 96 h
Pseudokirchneriella
subcapitata mg/L
EC50
51600: 96 h
Oncorhynchus
mykiss mg/L LC50
static 41 -47: 96 h
Oncorhynchus
mykiss mL/L LC50
static 51400: 96 h
Pimephales
promelas mg/L
LC50 static 710: 96
h Pimephales
promelas mg/L
LC50
-
10000: 24 h
Daphnia magna
mg/L EC50 1000:
48 h Daphnia
magna mg/L EC50
Static
Triethanolamine 216: 72 h 10600-13000: 96 h - 1386: 24 h Daphnia
102-71-6 Desmodesmus
subspicatus mg/L
EC50 169: 96 h
Desmodesmus
subspicatus mg/L
EC50
Pimephales
promelas mg/L
LC50 flow-though
1000: 9g h
Pimephales
promelas mg/L
LC50 static 450-
1000: 96 h Lepomis
macrochirus mg/L
LC50 static
magna mg/L EC50
Proprietary
1000: 96 h
Desmodesmus
subspicatus mg/L
EC50 1000: 72 h
Desmodesmus
subspicatus mg/L
EC50
9640: 96 h
Pimephales
promelas mg/L
LC50 flow-through
11130: 96 h
Pimephales
promelas mg/L
LC50 static
1400000: 96 h
Lepomis
macrochirus µg/L
LC50
- 13299: 48 h
Daphnia magna
mg/L EC50
Persistence and degradability: No applicable information available
Bioaccumulation potential: No applicable information available.
Mobility in soil:
Chemical Name Partition Coefficient
Potassium hydroxide
1310-58-3 0.83
Triethanolamine
102-71-6 -2.53
Other Adverse Environmental effects: No applicable information available.
SECT
ION 13 - DISPOSAL
CONSIDERAT
IONS
Handling for disposal: Disposal should be in accordance with applicable regional, national and local laws
and regulations.
Methods of disposal: Disposal should be in accordance with applicable regional, national and local laws
and regulations.
California Hazardous Waste Status:
Chemical Name California Hazardous Waste Status
Potassium hydroxide
1310-58-3 Toxic
Corrosive
Sodium hydroxide
1310-73-2 Toxic
Corrosive
RCRA: If this product, as supplied, becomes a waste in the United States, it may meet the criteria of a hazardous
waste UN defined under RCRA, Title 40 CFR 261. It is the responsibility of the waste generator to determine the
proper waste identification and disposal method. For disposal of unused or waste material, check with local, state
and federal environmental agencies.
SECT
ION 14 -
T
RANSPORT
AT
ION
INF
ORMAT
ION
US 49 CFR/DOT information:
UN No.: UN3266
UN Proper Shipping Name: Corrosive liquid, basic, inorganic, n.o.s. (contains Potassium hydroxide)
Transport Hazard Class(es): 8
Packing Group: II
Special Transportation Note: Please see current shipping paper for most up to date shipping
information, including exemptions and special circumstances. This material may meet the definition of a
marine pollutant.
SECT
ION 15 -
REGUL
AT
ORY
INFORMAT
ION
TSCA information: All listed ingredients appear on the Toxic Substances Control Act (TSCA) inventory.
European EINECs information: All ingredients listed appear on the European EINECs inventory.
Canadian Environmental Protection Act (CEPA) information: All ingredients listed appear on the Domestic
Substances List (DSL).
US Federal Regulations:
CERCLA: : This material, as supplied, contains one or more substances regulated as hazardous substances
under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR
302)
Chemical Name Hazardous Substances
RQs CERCLA/SARA RQ Reportable Quantity
Potassium hydroxide
1310-58-3 1000 lb - RQ 1000 lb final RQ
RQ 454 kg final RQ
EDTA
60-00-4 5000 lb - RQ 5000 lb final RQ
RQ 2270 kg final RQ
Sodium hydroxide
1310-73-2 1000 lb - RQ 1000 lb final RQ
RQ 454 kg final RQ
SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA).
This product does not contain any chemicals which are subject to the reporting requirements of the Act and
Title 40 of the Code of Federal Regulations, Part 372.
CWA (Clean Water Act): This product contains the following substances which are regulated pollutants
pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)
Component CWA – Reportable
Quantities CWA – Toxic
Pollutants CWA – Priority
Pollutants CWA –
Hazardouns
Substances
Potassium
hydroxide
1310-58-3 (<5)
1000 lb - - X
EDTA
60-00-4 (<1) 5000 lb - - X
Sodium hydroxide
1310-73-2 (<1) 1000 lb - - X
US State Regulations:
California Proposition 65: This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations:
Chemical Name New Jersey Massachusetts Pennsylvania
Potassium hydroxide
1310-58-3 X X X
EDTA
60-00-4 X X X
Proprietary X X
Triethanolamine
102-71-6 X X X
Proprietary X X X
SECTION 16 - OTHER INFORMATION
NFPA: Health Hazards Flammability Instability Special Hazards
3 0 0 Cor
HMIS: Health Hazards Flammability Phsyical Hazards Personal Protection
3 0 0 X
Legend:
ACGIH:
American Conference
of
Governmental Industrial
Hygienists
CAS:
Chemical Abstract
Services
CERCLA:
Comprehensive Environmental Response, Compensation, and Liability
Act of 1980
CFR:
Code
of
Federal
Regulations
CSA:
Canadian Standards
Association
DOT:
Department of
Transportation
ECOTOX:
U.S. EPA Ecotoxicology
Database
EINECS:
European Inventory
of Existing
Commercial chemical
Substances
EPA:
Environmental Protection
Agency
HSDB:
Hazardous Substances Data
Bank
IARC:
International Agency
for
Research on
Cancer
IUCLID:
International Uniform Chemical Information
Database
LC:
Lethal
Concentration
LD:
Lethal
Dose
NIOSH:
National Institute of Occupational Safety
and Health
NTP:
National Toxicology
Program
OECD:
Organization for
Economic Co operation and
Development
OSHA:
Occupational Safety and Health
Administration
PEL:
Permissible exposure
limit
RCRA:
Resource Conservation and
Recovery
Act
RTECS:
Registry of Toxic Effects
of
Chemical
Substances
SARA:
Superfund Amendments and
Reauthorization
Act
SDS:
Safety Data Sheet Material Safety Data
Sheet
STEL:
Short Term Exposure
Limit
TOG:
Canadian Transportation
of
Dangerous Goods Act &
Regulations
TLV:
Threshold
Limit Values
TWA:
Time Weighted
Average
WHMIS:
Workplace Hazardous Materials Identification
System
DISCLAIMER
Information
for this material
safety
data sheet was
obtained
from sources
considered technically accurate
and reliable. While every effort has been made to ensure full
disclosure
of product hazards, in some cases data is not
available
and is so stated. Since conditions of actual product use are beyond control of this supplier,
it
is
assumed
that users of
this
material have been
fully
trained
accordingly
to the
mandatory requirements
of GHS. No
warranty, expressed
or implied, is made and supplier will not be liable for
any losses,
injuries or consequential damages which
may
result from the use of, or
reliance
on, any
information contained
within this
form.
END OF DOCUMENT

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