SC DX200 51724622A V08.12 Titr Sensor Bro E
User Manual: SC-DX200
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Titration Sensors Titration Sensors pH Argentometry & Redox Photometry Conductivity Surfactants Reference Intelligent Sensors for All Titration Applications Experience & Innovation Extensive Experience with Innovative Titration Sensors Potentiometry is the method of choice for analytical identification of one or more substances in mixed phases. Reliable and durable titration sensors from METTLER TOLEDO with their variety of designs and perfectly matched reference systems, glass membranes and diaphragms, are suitable for a diversity of applications. Plug & Play means reliability With the comprehensive range of Plug & Play pH, platinum and silver titration sensors, any application challenge can be overcome. The Sensor Chip in the sensor head stores data such as sensor type, serial number, calibration data and usable life, which is automatically read out to the titrator setup when connected. That ensures, without any action on the part of the operator, that only the correct sensor with the specific, valid data is used. 2 Enormous capabilities METTLER TOLEDO has been a source of skills and expertise for the production of a vast range of titration sensors capable of meeting the specific analytical requirements of every industry for over 40 years. Precision and reliability Alongside experienced craftsmanship, maximum utility of automated production methods ensures the consistently high quality expected of the sensors. Guaranteed quality No sensor leaves the production facility untested. Only on successful completion of the final check do the sensors receive their individual quality certificates ready for dispatch. Strict guidelines regarding the slope or membrane glass resistance of the pH sensors guarantee ultimate performance. Smart design A clean diaphragm is a fundamental requirement for precise measurements. It is the interface between the reference system and the sample. If it is clogged with precipitation deposits, precise measurement cannot be guaranteed. The METTLER TOLEDO ARGENTHAL™ Ag/AgCl reference system with silver-ion trap keeps the reference electrolyte completely free of silver ions, preventing precipitation with sulfide, protein or TRIS buffer containing solutions. 3 Applications Application Examples from Practical Experience The following small selection of examples shows how the right combination of METTLER TOLEDO titration sensor and titrator provides the perfect solution for specific segment applications. Chemical Precise sulfuric acid content using the pH sensor DGi111-SC The precise determination of sulfuric acid concentration is of major significance not only for the chemical industry but for others too, as small differences can sometimes have serious consequences for product characteristics. A titration system consisting of T70 Excellence titrator, Rondo 20 sample changer and DGi111-SC pH sensor enables automated detection of 9% sulfuric acid concentration with a deviation of only 0.01% and an outstanding repeatability of only 0.05% in 6 sample series. Ultimate precision in routine analysis. Pharmaceutical Clotrimazole titration in acetic acid using the pH sensor DGi113-SC Important pharmaceuticals such as clotrimazole have to be titrated directly in non-aqueous solvents due to their low acidic strength. In accordance with the requirements of the European approved drugs list and USP, pure acetic acid is used as the solvent and perchloric acid as the titrant. The outstanding chemical stability and ease of regeneration of the DGi113-SC´s pH glass membrane guarantee the required durability under such demanding conditions. The high electrolyte flow from the moving plastic sleeve is essential for rapid response and stability of the sensor signal. The DGi113-SC has all the attributes required for precise results in non-aqueous titration applications. 4 Water Chloride titration in drinking water using the silver ring sensor DMi141-SC Chloride in water can occur naturally (e.g. mineral solutions such as brine) but can also be the result of contamination by fertilizer or waste water. Among other things, a high chloride content has a destructive effect on concrete and ferrous metals. With the DMi141-SC, chloride in water can be titrated with excellent repeatability (relative standard deviation < 0.5%) over a range of concentrations from 15 ppm to 1% using the appropiate concentration of silver nitrate titrant. Beverages Determining the pH and acidity of wine using the pH sensor DGi115-SC The pH and acidity of wine are essential parameters for assessing its quality. Laboratories have to analyze large numbers of wine samples for these two variables on a daily basis. A T70 and Rondo 20 sample changer with the DGi115-SC provide the means for mastering the task as precisely and efficiently as possible. Electroplating Automated nickel and hypophosphite titration using the DP5 Phototrode™ and platinum ring sensor DMi140-SC Tribological coatings for the automotive industry consist of metal or metal oxides electroplated or anodized from aqueous solutions. For quality assurance, the baths have to be checked every day. Nickel and hypophosphite/ orthophosphite are titrated in electroless nickel baths using the DP5 and the DMi140-SC, respectively. The two titrations are handled by two Rondo 20 sample changers that are controlled by a T90 Excellence titrator. At least 70 samples a day can be analyzed very efficiently and reliably. 5 Chemical Generalists and Specialists for the Chemical Industry In order to cope with the enormous breadth of analyses from raw materials to specialized chemicals, there is not only a need for versatile glass and metal sensors but also for specialized sensors in order to reliably titrate in a vast diversity of sample matrices. METTLER TOLEDO can supply the right solutions for these demands. DGi111-SC – the Multi-Talented Acid-Base Titration Sensor Up to date anywhere, any time The current data stored in the Sensor Chip such as slope and zero point, monitored sensor life span, etc. is available to the titrator as soon as it is connected. This information provides certainty that the DGi111-SC is always in the correct condition required for the application – regardless of which titrator it is connected. Mobility means flexibility The movable sleeve holder enables individual positioning of the sensor in the manual titration vessel or on the Rondo or Rondolino sample changer. That means that smaller sample volumes can be titrated in METTLER TOLEDO standard titration beakers or in Rondo 30 titration beakers. Simple yet stable reference The KCl-ARGENTHAL™ system reliably delivers stable sensor signals within a temperature range of 0 to 80 °C for the entire life of the sensor. The system is maintenance free and requires only regular filling with 3 M KCl. Reliable connection to the outside world A small ceramic pin creates the necessary conditions for slow, even outflow of the electrolyte. If samples with a high sulfide or protein content are avoided, no problems with clogging should be encountered. Quick stable signals and results The large HA-glass pH membrane has been optimized for rapid response times and stable signals. It delivers reliably repeatable results in aqueous systems. 6 DGi111-SC Order number: 51109500 pH application range: Temperature range: Membrane glass type: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: 0 –14 0 – 80 °C HA-taped Ceramic pin Glass ARGENTHAL™ 3 mol/L KCl S12 (DGi111-SC) S7 (DG111-SC) Plug & Play Sensor Chip 89596 (DG111-SC) Detection: Classic design: DGi102-Mini DGi101-SC DGi101-SC & DGi102-Mini – Micro Sensors for Macro Demands The DGi101-SC and DGi102-Mini are two powerful micro pH sensors with 3 mm or 6 mm shafts especially made for small sample volumes of 5 to 20 mL and for use on the Rondo 30 or Rondo 60 plus sample changers. With the moveable sleeve holder, the height can be adjusted. Samples containing sulfides can be titrated with no problem. The ARGENTHAL™ reference system with silver ion trap means there is no possibility of diaphragm clogging. DGi101-SC & DGi102-Mini Order number: pH application range: Temperature range: Membrane glass type: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: Detection: 51109507 (DGi101-SC) 51109508 (DGi102-Mini) 0 –14 0 –100 °C U-glass Ceramic pin Glass ARGENTHAL™ with silver ion trap 3 mol/L KCl S12 Plug & Play Sensor Chip DX202-SC Sb850-S7/120 Sb850-S7/120 & DX202-SC – where Others Fear to Tread This is a specific combination for acid-base titration in media containing hydrofluoric acid. The antimony pin of the Sb850 half cell is passivated by fluoride ions and is therefore resistant. Similarly, the plastic shaft of the DX202-SC reference is unaffected by hydrofluoric acid. Oxides that are only soluble in highly corrosive media can be titrated without any trouble. Sb850-S7/120 Order number: 59904405 pH application range: Temperature range: Sensor element: Diaphragm: Shaft material: Reference system: Connection: Detection: 0 –14 0 – 80 °C Antimony pin n/a Polypropylene External reference required S7 n/a DX202-SC Order number: 51109295 Detection range: Temperature range: Ext. diaphragm: Int. diaphragm: Shaft material: Reference system: Int. reference electrolyte: Bridge electrolyte: Connection: Detection: 0 – ±2000 mV 0 – 80 °C Glass fiber Glass fiber Polypropylene Ag/AgCl 3 mol/L KCl 3 mol/L KCl or 1 mol/L KNO3 S7 n/a 7 Petrochemical Flexibility and Durability for Difficult Petrochemical Samples The METTLER TOLEDO sensors for non-aqueous titrations are optimized for rapid response times and signal stabilization as well as for ruggedness and durability. As a result, they easily meet the requirements of oil standards such as ASTM, IP and DIN for the titration of petrochemical products. DGi116-Solvent – for the Most Exacting Demands No mistakes Because of its Plug & Play Sensor Chip, the DGi116-Solvent is immediately detected as soon as it is connected to the titrator. Mix-ups are not possible. Perfectly shielded The gold shielding on the inner reference provides perfect protection against electrostatic effects. The signal noise is substantially diminished and the result quality significantly improved. Reliable reference system The LiCl-ARGENTHAL™ system reliably delivers stable sensor signals within a temperature range of 0 to 60 °C for the entire life of the sensor. The system is maintenance free and requires only regular filling with 1 mol/L LiCl in ethanol. Stable signals and easy cleaning The movable ground glass junction ensures even flow of the electrolyte. The sensor signal stabilizes faster and titrations can be completed in a shorter time. The smooth glass surface prevents oil samples from sticking and considerably simplifies cleaning. Fast response times and durability The large spherical surface area of the glass membrane ensures low membrane resistance and homogeneous distribution of the potential. So, the response time and signal noise are reduced. Due to its chemical stability and easy regeneration, the A41 membrane glass is ideal for non-aqueous titrations in a pH range of 0 to 12. 8 DGi116-Solvent Order number: 51109505 pH application range: Temperature range: Membrane glass type: Diaphragm: 0 – 12 0 – 6 0 °C A41 spherical Shaft material: Reference system: Reference electrolyte: Connection: Detection: Ground glass (moveable) Glass LiCl-ARGENTHAL™ LiCl, 1 mol/L in ethanol S12 Plug & Play Sensor Chip DMi148-SC DMi148-SC – Maximum Versatility, Minimum Maintenance The DMi148-SC is ideally suited to detecting chloride and, by simply sulfidizing the silver ring, for titrating mercaptans in petrochemical products. Thanks to the pH glass reference, there is no diaphragm clogging and no electrolyte refilling. Automatically, other possible applications such as acid-base titration using the silver ring as reference are possible. DMi148-SC Order number: 51109532 pH application range: Temperature range: Sensor element: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: Detection: 0 –14 0 – 8 0 °C Silver ring n/a Glass pH glass membrane n/a S12 Plug & Play Sensor Chip DX200 DG300-SC DG300-SC & DX200 – Individually Adaptable With this combination, you have the option of working strictly according to ASTM D664 specifications for determining acid number or, creating a sensor adapted specifically to the sample and sample matrix. The DG300-SC half-cell reacts quickly and consistently to pH changes thanks to the large, spherical membrane. The DX200 with its replaceable bridge electrolyte and constant electrolyte flow from the ground glass junction is an individually adjustable reference ideally suited to non-aqueous media. DG300-SC Order number: 51109286 pH application range: Temperature range: Sensor element: Diaphragm: Shaft material: Reference system: Connection: Detection: 0 –14 0 – 10 0 °C pH glass membrane n/a Glass External reference required S7 n/a DX200 Order number: 51089935 Detection range: Temperature range: Ext. diaphragm: Int. diaphragm: Shaft material: Reference system: Int. reference electrolyte: Bridge electrolyte: 0 – ±2000 mV 0 – 80 °C Ground glass (moveable) Ceramic pin Glass ARGENTHAL™ 3 mol/L KCl 3 mol/L KCl 1 mol/L KNO3 1 mol/L LiCl in ethanol 1 m, 4 mm banana n/a Cable/connection: Detection: 9 Pharmaceutical/Biotechnology Controlled Safety and Precision for Pharmaceuticals Titrations on the purity of pharmaceutical constituents and active ingredients are fundamental to ensuring their effectiveness. METTLER TOLEDO titration sensors make the required application flexibility possible and offer reliability due to their intelligent design. This ensures maximum sensor life and minimal maintenance. DMi147-SC – Twice the Possibilities, Half the Work Reliable detection: All relevant sensor data for identification and status monitoring is immediately available to the titrator thanks to the Plug & Play Sensor Chip. Secure attachment With the standard glass sleeve holder, the sensor can be easily and securely positioned when fitted in the titration stand. Maintenance free reference system The DMi147-SC has no diaphragm as the pH glass membrane provides a constant reference potential for the platinum sensor in highly acidic and therefore adequately buffered conditions required for redox titrations. No refilling of electrolyte or cleaning of clogged diaphragms are necessary, adding up to ease-of-use, minimum maintenance and a long service life. Twice the capabilities The DMi147-SC combines two sensors, making it capable not only of redox titration using the platinum sensor but also of acid-base titration using the pH sensor. In the first case, the pH membrane is the reference, in the second the platinum ring. In both cases, the sample is not contaminated since there is no outflowing electrolyte. The question of the right choice of reference electrolyte is therefore super fluous. 10 DMi147-SC Order number: 51109522 Detection range: pH application range: Temperature range: Sensor element: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: Detection: 0 – ± 2000 mV 0 –14 0 – 80 °C Platinum ring n/a Glass pH glass membrane n/a S12 Plug & Play Sensor Chip DGi113-SC – Reliability for Non-Aqueous Titrations DGi113-SC The DGi113-SC is the sensor for the best results in acid-base titration of pharmaceuticals in non-aqueous media using a variety of titrants adapted to the sample matrix. DGi113-SC Order number: 51109502 pH range: Temperature range: Membrane glass type: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: 0 –12 0 –60 °C A41 cylindrical Moveable Tefzel® Glass LiCl-ARGENTHAL™ LiCl, 1 mol/L in ethanol S12 (DGi113-SC) S7 (DG113-SC) Plug & Play Sensor Chip 89632 (DG113-SC) Detection: Classic design: InLab®718 InLab®717 InLab®717 & InLab®718 – Tracking Down Fast-Moving Ions These two conductivity sensors, which can be connected directly to the conductivity card of an Excellence titrator, are suitable for conductometric acid-base or precipitation titrations. They can be used in low-ion aqueous or non-aqueous media. They enable rapid titration and feature zero-maintenance and outstanding durability. For direct measurement of conductivity, the appropriate InLab®710/731 or InLab®720/741 can be used according to sample type. More information is provided in the Lab Sensors brochure (order no. 51724332) or at www.mt.com/electrode-guide InLab®717 Order number: 51302401 Detection range: Temperature range: Shaft material: Cell constant: Cell type: Temperature sensor: Connection/cable: Detection: 10 µS/cm – 500 mS/cm 0–100 °C Epoxy Dependent on beaker geometry 4-pole platinum NTC Mini-Din, 1 m Presence checking InLab®718 Order number: 51340266 Detection range: Temperature range: Shaft material: Cell constant: Cell type: Temperature sensor: Connection/cable: Detection: 0.1–200 µS/cm -5–100 °C Epoxy Dependent on beaker geometry 2-pole platinum NTC Mini-Din, 1.2 m Presence checking 11 Water Precise Detection of Multiple Parameters in Water The importance of water in every area of life and industry is undisputed. The enormous variety of water types require analysis of different ions and parameters over a wide range of concentrations under constantly maintained conditions in accordance with strict regulations. That places exacting demands on the sensor systems but presents no problems for METTLER TOLEDO titration sensors. DGi117-Water – all Your Water Titration Needs in One Sensor No watering down of sensor data The pH sensor calibration data stored in the Sensor Chip of the DGi117-Water are transferred to the titrator as soon as it is connected. It can be automatically monitored if required, which means the sensor is always in optimum condition for precise, temperature-adjusted pH measurement and end point titrations. Maintenance free reference The double-junction design with a maintenance free internal reference system (KCl gel) enables replacement of the outer reference electrolyte (1 mol/L KCl) and therefore adaptation to the particular testing conditions. No interference The inner tube is electrically shielded by a gold coating, preventing interference from electrostatic charges which otherwise would cause high signal noise and drifting pH readings. High precision in low-ion media The electrolyte flow through the fixed glass junction remains stable between 5 and 20 µL/h. This guarantees accurate pH readings and only minimal contamination of the sample with electrolyte. All-inclusive Temperature-adjusted pH readings and end point titrations can be performed due to the integrated Pt1000 temperature sensor. Rapid results The LoT glass features low membrane resistance and ensures extremely fast response time. The thinwalled spherical design reduces electrical resistance even further. 12 DGi117-Water Order number: 51109506 pH application range: Temperature range: Membrane glass type: Ext. diaphragm: Int. diaphragm: Shaft material: Reference system: Int. reference electrolyte: Bridge electrolyte: Connection: Detection: 1 –11 0 –100 °C LoT spherical Ground glass Ceramic pin Glass ARGENTHAL™ KCl gel 1 mol/L KCl S12 Plug & Play Sensor Chip DMi144-SC – the Long Sensor for Chemical Oxygen Demand DMi144-SC Chemical oxygen demand (COD) titrations are best left to automated systems due to the harsh chemical conditions and high sample numbers. The DMi144-SC platinum ring sensor is capable of fully automated redox titrations directly in standard decomposition vessels with the Rondo 20 and COD kit. DMi144-SC Order number: 51109521 Detection range: Temperature range: Sensor element: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: Detection: 0 – ± 2000 mV 0 – 80 °C Platinum ring Ceramic pin Glass ARGENTHAL™ 3 mol/L KCl S12 Plug & Play Sensor Chip DMi141-SC DMi102-SC DMi102-SC & DMi141-SC – Precise Titration from ppm to % Chloride and More The DMi102-SC and DMi141-SC are silver ring sensors for similar applications, e.g. titrating any ions that form precipitations with silver. This includes all halides (Cl-, Br -, I-), pseudo-halides (CN-, SCN-, ...) and, after prior sulfidizing of the silver ring, sulfides and mercaptans over broad concentration ranges. The DMi141-SC is the generalist, the DMi102-SC is a rugged semimicrosensor for small sample volumes of 10 to 20 mL or for use on the Rondo 30 sample changer. DMi102-SC Order number: 51109533 Detection range: Temperature range: Sensor element: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: Detection: 0 – ± 2000 mV 0 – 80 °C Silver ring Ceramic pin Glass ARGENTHAL™ 1 mol/L KNO3 S12 Plug & Play Sensor Chip DMi141-SC Order number: 51109530 Detection range: Temperature range: Sensor element: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: 0 – ± 2000 mV 0 – 80 °C Silver ring Ceramic pin Glass ARGENTHAL™ 1 mol/L KNO3 S12 (DMi141-SC) S7 (DM141-SC) Plug & Play Sensor Chip 89599 (DM141-SC) Detection: Classic design: Precise ion-selective and conductivity measurements Full details of sodium, ammonia, calcium and other ion-selective sensors as well as the right choice of conductivity sensor for water analysis can be found in the Lab Sensors brochure (order no. 51724332) or at www.mt.com/electrode-guide. 13 Food & Beverage Reliable Results for Palatable Food The pH level, acidity and other parameters such as salt and Vitamin C content in food and beverages are essential in obtaining the right flavor and for nutritional validation. METTLER TOLEDO titration sensors guarantee food quality because the specific ingredients can be quickly and accurately titrated according to regulations. DGi115-SC – Optimized for Acid-Base Titration in Food and Beverages Reliable titration The sensor and calibration data stored in the Sensor Chip is always up to date and can be monitored. This guarantees that the DGi115-SC is always in good condition for pH testing or end point titrations. Controlled conditions Due to the ARGENTHAL™ reference system with silver ion trap, the reference electrolyte (3 mol/L KCl) is free of silver ions. There is no danger of food constituents such as sulfides or proteins clogging the diaphragm. Repeatable precise results The electrolyte flow through the fixed glass junction is constant and guarantees accurate and reproducible pH readings and end point titrations. Food ingredients sticking to the glass surface can be cleaned off easily. DGi115-SC Fast results The HA glass pH membrane features rapid response time, low alkali error and outstan ding mechanical durability. It is the right combination for consistently high performance. Order number: 51109504 pH application range: Temperature range: Membrane glass type: Diaphragm: Shaft material: Reference system: 0 –14 0 –100 °C HA cylindrical Ground glass Glass ARGENTHAL™ with silver ion trap 3 mol/L KCl S12 (DGi115-SC) S7 (DG115-SC) Plug & Play Sensor Chip 89806 (DG115-SC) Reference electrolyte: Connection: Detection: Classic design: 14 DM143-SC – Vitamin C, SO2 and More DM143-SC The DM143-SC is a simple, durable and zero-maintenance sensor primarily for redox titration of important food ingredients such as Vitamin C or free and total SO2 in wine. Depending on the method or regulations, titrations can be performed with either voltametric or amperometric indication. DM143-SC Order number: 51107699 Detection range: 0 – ± 2000 mV 0 – 200 µA 0 – 100 °C Double platinum pin n/a Glass n/a n/a S7 n/a Temperature range: Sensor element: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: Detection: DMi145-SC – Easy Detection of Chloride in Food DMi145-SC The DMi145-SC is an ideal silver ring sensor for chloride titrations in foods. Contamination or clogging with sticky foods such as ketchup or samples with high fat content are no problem thanks to the easy-to-clean moveable plastic diaphragm. The high electrolyte flow from the diaphragm enables chloride detection to ppm-accuracy in alcoholic solutions. DMi145-SC Order number: 51109531 Detection range: Temperature range: Sensor element: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: Detection: 0 – ± 2000 mV 0 – 80 °C Silver ring Moveable Tefzel® Glass ARGENTHAL™ 1 mol/L KNO3 S12 Plug & Play Sensor Chip 15 Electroplating & Electronics High Precision for Ultimate Functionality in Electroplating and Electronics Continuous monitoring of the metal ion, acid or anion content of electrochemical baths is important for obtaining durable coatings in electroplating processes or producing perfectly functioning circuit boards in the electronics industry. Tough and well-designed METTLER TOLEDO titration sensors are ideal for titrating in such demanding sample matrices. DP5 Phototrode™ – a Mini Rainbow for Metal Titrations and More 5 options for a full spectrum of titrations With a choice of 5 wavelengths comprising 520 nm, 555 nm, 590 nm, 620 nm and 660 nm, the DP5 can be individually adapted to the specific application. With a suitable color indicator, a wide range of complexometric titrations is possible, as well as acid/base, redox and turbidimetric titrations. This means that the cost benefits compared with more complex procedures such as AAS or ICP-AES can be fully exploited. Just like a normal sensor Thanks to its movable sleeve holder, the DP5 can be used like any other sensor in the titration vessel, either directly on the titrator or on a Rondo or Rondolino sample changer. It will even fit in Rondo 30 titration beakers. A long-term investment The polypropylene design of the sensor shaft is resistant against most aqueous and non-aqueous media. If ever there are incompatible solvent mixtures involved, you can change to a stainless steel shaft at any time. In either case, you will have a highly durable sensor which will provide you with reliable readings over the full length of its extensive service life. The right solution The DP5 is used where potentiometric titrations are not possible, where matrix effects corrupt the output signal of the sensor or where photometry is a specified requirement. It enables quick and easy titration because it requires neither conditioning stages nor time-consuming calibration or maintenance work. You just set the maximum transmission or absorption, and off you go. DP5 Phototrode™ Order number: 16 51109300 inc. region-specific power adaptor (Europe/USA/UK) and cable DGi112-Pro DGi112-Pro – Specifically Adaptable to the Sample The DGi112-Pro is a doublejunction pH sensor that enables replacement of both the reference and the bridge electrolyte for specific adaptation to the sample matrix. The HA glass membrane is distinguished by high durability and rapid response characteristics and the movable diaphragm prevents clogging and is easy to clean. Titration of acid mixtures in demanding electrochemical baths can be mastered with accurate results. DGi112-Pro Order number: 51109501 pH range: Temperature range: Membrane glass type: Ext. diaphragm: Int. diaphragm: Shaft material: Reference system: Int. reference electrolyte: Bridge electrolyte: 0 – 14 0 – 60 °C HA cylindrical Moveable Tefzel® Ceramic pin Glass ARGENTHAL™ 3 mol/L KCl 1 mol/L KCl 3 mol/L KNO3 S12 Plug & Play Sensor Chip Connection: Detection: DMi101-Mini DMi140-SC DMi140-SC & DMi101-Mini – the Perfect Choice for Redox Titration The DMi140-SC and DMi101-Mini are two platinum ring sensors for all types of redox titrations encountered in the electroplating or electronics industries, such as direct titration with cerium(IV)sulfate or back titrations with potassium iodide or ferrous(II) ammonium sulfate. The DMi140-SC is the generalist while the DMi101-Mini is a rugged semi-microsensor for small sample volumes of 10 to 20 mL or for use on the Rondo 30 sample changer. DMi140-SC Order number: 51109520 Detection range: Temperature range: Sensor element: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: 0 – ± 2000 mV 0 – 80 °C Platinum ring Ceramic pin Glass ARGENTHAL™ 3 mol/L KCl S12 (DMi140-SC) S7 (DM140-SC) Plug & Play Sensor Chip 89598 (DM140-SC) Detection: Classic design: DMi101-Mini Order number: 51109523 Detection range: Temperature range: Sensor element: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: Detection: 0 – ± 2000 mV 0 – 80 °C Platinum ring Ceramic pin Glass ARGENTHAL™ 3 mol/L KCl S12 Plug & Play Sensor Chip 17 Paper & Cellulose / Cosmetics Durability for Paper Production The process of pulp digestion has to be carefully controlled in order to obtain quality results without wasting time and money. Due to the vast production volumes, en ormous gains can be obtained from very minor changes to the pulping process. The METTLER TOLEDO sensor DGi114-SC provides the ideal means for titrations in the delignification process. DGi114-SC – the Tough pH Sensor for Harsh Environments Unmistakable Due to its Sensor Chip, the sensor is unmistakably identified. The up-to-date sensor and calibration data stored are immediately available to the titrator, so mistakes are a thing of the past. Stable conditions The ARGENTHAL™ reference system with 3 mol/L KCL electrolyte withstands high temperatures and frequent temperature changes – providing a long-lasting and stable reference system. Simple maintenance The movable diaphragm with its high electrolyte flow enables fast and reproducible potential adjustment and adds to the ease of cleaning and maintenance – all in all an optimum design for equivalence point titrations with difficult pulp samples. DGi114-SC Durability for reliable results The outstanding durability of the HA glass membrane makes it perfect for the demanding conditions of acid-base titrations of black, green or white liquors. 18 Order number: 51109503 pH application range: Temperature range: Membrane glass type: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: Detection: 0 –14 0 – 60 °C HA cylindrical Moveable Tefzel® Glass ARGENTHAL™ 3 mol/L KCl S12 Plug & Play Sensor Chip Surfactants in a Diversity of Cosmetic Products Due to constantly rising consumer demands, the composition of personal care products such as creams, shampoos or shower gels has become increasingly complex. Titrations of these samples have therefore become extremely exacting, demanding suitable methods combined with high-performing and versatile sensors: the METTLER TOLEDO DS800-TwoPhase and DS500 surfactant sensors. DS800-TwoPhase The Ultimate in Two-phase Titration Performance DS500 Specifically for Use in Aqueous Systems The DS800-TwoPhase is the sensor of choice for the titration of anionic and cationic surfactants in formulations, raw products, liquid detergents and shampoos using the two-phase titration method according to the EN 14480, 14668 and 14669 standards over a pH range from 1 to 12. The performance capabilities of the membrane remain entirely undiminished even after hundreds of titrations, resulting in reliable results over the full length of its extensive service life. With the sensor DS500, ionic surfactants can be easily titrated in aqueous matrices. Very often, a method based on precipitation titration between an anionic and a cationic surfactant is sufficient. Characteristic titration of that type can be performed in samples such as liquid detergent or household cleaners as well as in colored solutions and turbid suspensions in a pH range of 2 to 10. Non-ionic surfactants in raw products can also be precisely analysed with the DS500. DS800-TwoPhase Order number: 51109540 DS500 pH applic. range: Detection range: 1–12 <10 –5 mol/L to critical micelle concentration 0– 50 °C Polymer membrane <1 MΩ Order number: 51107670 pH applic. range: Detection range: 2 –10 <10 – 5 mol/L to critical micelle concentration 0 – 50 °C Polymer membrane <1 MΩ Temperature range: Sensor element: Membrane resistance: Shaft material: Reference system: Connection: Detection: Resistant to: POM External reference required S7 n/a Ketones (MIBK), hexane, toluene, ethanol Temperature range: Sensor element: Membrane resistance: Shaft material: Reference system: Connection: Detection: Resistant to: PVC External reference required S7 n/a Ethanol 19 Titration Excellence 20 Excellent Hardware and Firmware for Optimum Sensor Support The sensor inputs of the METTLER TOLEDO Excellence T50, T70 and T90 titrators and the Compact G20 titrator are optimized in terms of speed, signal-to-noise ratio and resolution. This ensures that in combination with the suitable sensor, stable pH level readings, pH-stating with tight tolerances or demanding titrations in complex substance mixtures can be performed to the highest quality standards. Fully equipped as standard Every Excellence titrator comes with a versatile pH sensor card. There are 2 Plug & Play compatible pH/mV sensor inputs, one of which also features current or voltage polarization, a Pt1000 temperature sensor input and a reference input. This means it has the facility for direct pH or ISE(pX) measurement, pH end point or pH/mV/pX equivalence point titrations as well as amperometric and voltametric titrations. If needed, more sensor cards can be added in the available slots. Expandable to conductivity With the unique conductivity sensor card, new application possibilities such as conductometric titrations or direct measurements can be easily and reliably done with the full functionality of a modern Excellence titrator – there is no need for an extra meter. The conductivity card features automatic detection of the conductivity sensor and an additional Plug & Play pH/mV sensor input. Ensuring performance capability In order to ensure the performance capabilities of the sensor inputs, they can be periodically adjusted with certified resistors and the test unit. The process is traceable, unambiguously documented, and guarantees identical measurement conditions for all the sensor inputs of a sensor card. A calibrated pH sensor can simply be switched from one input to the other without the need for recalibration. Automatic chemical detection In addition to the Plug & Play sensors the pH buffers used for sensor calibration are also automatically detected by the titrator. It makes no difference in which order the buffers are measured, saving time and providing certainty. Efficient method development The intelligent application modes of the titrators make method optimization easy. Just select the titration method and titration speed and the optimum control parameters are automatically set to suit the selected sensor – simple and efficient method development. 21 Accessories Properly Serviced and Connected Electrolyte and Cleaning Solutions METTLER TOLEDO offers an extensive range of electrolytes and cleaning solutions, which are indispensable for correct maintenance and care, and consequently for trouble-free and extended sensor life. Electrolytes for reference systems Order no. 25 mL Order no. 250 mL Order no. 6x250 mL KCl 3 mol/L solution for ARGENTHAL™ reference systems and as bridge electrolyte (DGi101-SC, DGi102-Mini, DG(i)111-SC, DMi101-Mini, DM(i)140-SC, DGi112-Pro, DGi114-SC, DG(i)115-SC, DX200, DX202-SC) 51343180 51340049 51340050 1 mol/L KNO3 (DMi102-SC, DM(i)141-SC, DMi145-SC, DX200, DX202-SC) 51343182 51340047 51340234 Solutions for reference systems: bridge electrolytes 1 mol/L KCl (DGi112-Pro, DGi117-Water, DX200, DX202-SC) 51343181 Solutions for surfactant sensors Inner electrolyte for the DS500 51107899 Inner electrolyte for the DS800-TwoPhase 51109542 Emulsifier for two-phase titration with the DS800-TwoPhase 51109543 Cleaning solutions Pepsin hydrochloric acid for cleaning protein contamination from diaphragms. Acting time approx. 1 hour 51340068 Thiourea solution for cleaning silver sulfide contamination from diaphragms. Acts to discoloration 51340070 Reactivation solution for regenerating pH glass sensors. Acting time 1 min 51340073 Conductivity standards Order no. 6x250 mL 84 µS/cm Order no. 250 mL Order no. 30 sachets of 20 mL 51302153 1413 µS/cm 51300259 51300138 51302049 12.88 mS/cm 51300260 51300139 51302050 Useful Accessories Whether a temperature sensor for temperature-compensated pH measurement or simply wetting caps for correct storage of titration sensors are required, METTLER TOLEDO offers useful accessories. 22 Accessory Description Order number DT1000 temperature sensor Pt1000 temperature sensor for temperature-compensation of pH-level readings 51109828 Wetting caps (minimum order 5 items) For sensors with shaft diameter of 12 mm 51340020 For sensors with ground diaphragm (DGi112-SC, DG(i)113-SC, DGi114-SC, DG(i)115-SC, DGi116-Solvent, DGi117-Water) 51340022 For sensors with shaft diameter of 8 mm (DGi102-Mini, DMi101-Mini, DMi102-SC) 51340021 For sensors with shaft diameter of 6 mm (DGi101-SC) 51340019 Cables for Plug & Play and Classic Sensors The METTLER TOLEDO Plug & Play sensors require a Plug & Play cable for connection to the titrators. This cable can also be used for classical sensors with the exception of the DM143-SC. Multiple shielding prevents electrostatic effects on the transmission of measurement and reference signals or the Sensor Chip data. Connection Cable length (cm) Designation Connector Order number 70 S12 grey 100 89601 Lemo 89602 160 51108034 70 51109544 Lemo/Pt1000 MultiPin™ 100 51109545 DM143-SC double platinum pin sensor: for this model, classic sensor cables are used, which can also be used with all classic sensors. As with the Plug & Play cables, the signal integrity is protected from interference effects. Connection Cable length (cm) S7 grey 100 Designation Connector Order number 70 51109183 Lemo 51109184 160 51109185 Buffer Solutions with Quality Test Certificate Any pH measurement and end point titration can only be as accurate as the buffer solutions used for calibrating the pH sensor. The internationally valid pH scale is defined according to the standard reference materials (SRMs) of the NIST (National Institute of Standards and Technology, USA). The buffer solutions supplied by METTLER TOLEDO are provided with a quality test certificate that guarantees the stated specifications and compliance with the standards. They are ideally suited for use in quality systems. You can download their test certificates from www.mt.com/buffer and the safety data sheets from www.mt.com/msds. Buffer solutions Standard pH buffer solutions pH buffer solutions according to NIST and DIN 19266 DKD certified buffer solutions Redox buffer solutions E (Ag/AgCl) 25 °C pH level at 25 °C Order no. 250 mL Order no. 6x250 mL Order no. 1000 mL Order no. 30 sachets of 30 mL 2.00 51340055 51319010 51319011 4.01 51340057 51340058 51340228 51302069 7.00 51340059 51340060 51340229 51302047 9.21 51300193 51300194 51340230 51302070 10.00 51340056 51340231 51340232 51302079 11.00 51340063 51319018 51319019 Rainbow I (3x10 sachets of 20 mL 4.01/7.00/9.21) 51302068 Rainbow II (3x10 sachets of 20 mL 4.01/7.00/10.00) 51302080 4.006 51340039 6.885 51340041 9.180 51340042 10.012 51340044 4.01 52118093 51319059 7.00 52118094 51319060 9.21 52118095 51319061 10.00 52118096 51319062 220 mV UH = 427 mV 51340065 51340081 23 Applications The Right Sensor by Industry and Application Using the table below (and on the following page) you can easily see which METTLER TOLEDO titration sensor is best for your particular industry and application. For more detailed information on the individual sensors refer to the indicated pages of the brochure. Industry Chemical Petrochemical Pharmaceutical/ Biotechnology 24 Titration application Titration type Acidic and basic solutions Acid-/base, aqueous, potentio- or conductometric Concentrated alkalis Acid-/base, aqueous Nitrating acids Acid-/base, non-aqueous SiO2 and Na2O in water glass Acid-/base, aqueous Acidity/alkalinity of polyols Acid-/base, non-aqueous Chlorine and chlorate in alkalis Redox, iodometric Chloride in alcohol solutions Precipitation Identification of indigo and hydrosulphite Redox, iodometric TAN according to ASTM D664, IP177, EN12634 Acid-/base, non-aqueous TBN according to ASTM D4739, IP276, ISO 3771, ASTM D2896 Acid-/base, non-aqueous Mercaptans in oils according to ASTM D3227, IP272, ISO 3012 Precipitation, non-aqueous Chloride in crude oil Precipitation, non-aqueous Bromine number according to ASTM D1159, IP130, ISO 3839 Redox, bromatometric Iodine value in biodiesel according to EN14111 Redox, iodometric Titration of oils according to IP400 Conductometric Epoxy value of polymers (ASTM D1652, DIN 53188) Acid-/base, non-aqueous Peroxide number in oils Redox, iodometric Acid numb. in B100 biodiesel (EN14104) or E85 bioethanol (ASTM D1613) Acid-/base, non-aqueous, potentio- or photometric Pharmaceutical constituents and active ingredients (aspartame, clotrimazole, etc.) Acid-/base, non-aqueous potentiometric, conductometric Pharmaceutical constituents and active ingredients (phenol, glycerine, ampicillin, vitamin E, etc.) Redox, bromatometric, iodometric, cerimetric Sulfonamides Redox, diazotitration Halides according to the European Pharmacopoeia and USP Precipitation Chloride in physiological solutions Precipitation, potentiometric Non-ionic surfactants in pharmaceutical products Precipitation, photometric (turbidity) Free acids in glycerine according to Pharmacopoeia 5.0 Acid-/base, aqueous Conductivity of purified water to USP26 Conductivity measurement DGi102-Mini DGi111-SC DGi112-Pro DGi-114-SC DGi115-SC DGi117-Water DG300-SC DGi113-SC DGi116-Solvent DMi101-Mini DMi140-SC DM144-SC DMi147-SC DMi102-SC DMi141-SC DMi145-SC DMi148-SC DM405-SC DS800-TwoPhase DS500 7 7 6 17 18 14 12 9 11 8 17 17 13 10 15 13 13 15 9 19 19 • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • InLab®718 Sb850 DX200 DX202-SC DX218, 219, 223, 240 DX264 InLab®710, 731 InLab®720, 741 Conductivity, titration Antimony Color Silver InLab®717 Platinum DP5 Phototrode™ DM143-SC DGi101-SC see brochure page pH Sur factant • Reference • • • • • • • • • ISE Conductivity, directmeasurement Sensor name 16 11 11 7 9 7 * * * * • • • • • • • • • • • • • • • • • • • • • * See Lab Sensors brochure (order no. 51724332) or www.mt.com/electrode-guide 25 Applications The Right Sensor by Industry and Application Industry Water Food & beverages Electronics/electroplating/engineering/ automotive Cosmetics Paper/cellulose, textiles Raw materials and precious metals Flavours, fragrances, food ingredients 26 Titration application Titration type Acidity/alkalinity of domestic, natural source and rainwater Acid-/base, aqueous Total hardness of water Complexometry, photometric and potentiometric Chemical oxygen demand (COD) Redox, chromatometric Perborate, percarbonate, persulfate in water Redox, iodometric Chlorine residues according to ASTM D1253 Redox, arsenometric, amperometric indication Chloride in water Precipitation Ammonia, fluoride, sodium and calcium in water Direct measurement Conductivity of domestic, natural source and rainwater Conductivity measurement Vitamin C in food and beverages Redox with amperometric or voltametric indication Acid content of fruit/vegetable juices, wine, milk, vinegar Acid-/base, aqueous Chloride in foods (ketchup, vegetable juices, spices) Precipitation Free and total sulfur dioxide in wine Redox, iodometric, voltametric indication Reducing sugar according to Rebelein Redox, iodometric Saponification no. of fats in oil, margarine, butter (DIN 53401) Acid-/base, aqueous Acid number of oils, margarine, fats Acid-/base, non-aqueous Peroxide number of edible oils and fats Redox, iodometric Anionic/cationic surfactants in coolant/lubricants Two-phase precipitation (EN14468, 14469, 14480) Nickel in electroless nickel baths Complexometry, photometric Hypophosphite/orthophosphite in electroless nickel baths Redox, iodometric Free cyanide in zinc baths Precipitation Acid mixtures in electrolysis baths Acid-/base, aqueous Cr(VI), Sn(II) in electrolysis baths Redox, iodometric Cu(II) and Zn(II) in electrolysis baths Complexometry, potentiometric Hydrogen peroxide Redox, cerimetric Anionic surfactants in liquid detergents Precipitation, single-phase, aqueous Anionic/cationic surfactants in cosmetic products Two-phase precipitation (EN14468, 14469, 14480) Non-ionic surfactants in raw materials Precipitation, photometric (turbidity) Betaine content in shampoo Acid-/base, non-aqueous ABC titration of white and green liquor Acid-/base, aqueous Sulfides in green and black liquor Precipitation Kappa number determination Redox, iodometric Gold Redox, cerimetric Silver in alloys Precipitation Al(III), Fe(III), Ca(II), Mg(II) in cement components (EN196-2) Complexometry, photometric Aldehydes in oil of lemons according to AOAC 955:32 Acid-/base, aqueous Peroxide number of etheric oils, essences Redox, iodometric • • • • • • • • • • • • DX200 DX202-SC DX218, 219, 223, 240 • Sb850 • InLab®718 • InLab®717 • DP5 Phototrode™ • DS500 • DS800-TwoPhase • DM405-SC • DMi148-SC 11 DMi145-SC DGi113-SC 9 DMi141-SC DG300-SC 12 DMi102-SC DGi117-Water 14 DM143-SC DGi115-SC 18 DMi147-SC DGi-114-SC 17 DM144-SC DGi112-Pro 6 DMi140-SC DGi111-SC 7 DMi101-Mini DGi102-Mini 7 DGi116-Solvent DGi101-SC see brochure page • • • • • • • • • • • • • • • • • • • • • • • • • Reference 8 17 17 13 10 15 13 13 15 9 19 19 16 11 11 7 9 7 * • • • • • • • • • • • InLab®720, 741 Antimony Sur factant Color Silver InLab®710, 731 Platinum DX264 pH Conductivity, titration ISE Conductivity, directmeasurement Sensor name * * * • • • • • • • • • • • • • • • • • • • • • * See Lab Sensors brochure (order no. 51724332) or www.mt.com/electrode-guide 27 Rondo sample changers Fully automated titration The METTLER TOLEDO Rondo sample changer platform used in conjunction with the Excellence titrators forms exceptionally versatile and high-performance titration systems. It is made possible by the modular design, the intuitive controls and the Plug & Play hardware. This means you can configure your day-to-day titrations with ease, start them at the press of a button and let them run automatically without intervention. LabX® titration software Everything under control METTLER TOLEDO LabX offers secure data archiving, efficient data management with control charts and individual search filters, and fast and clearly organized method development for all applicationrelated challenges. All installation, preparation and analysis tasks can be performed on a PC and are therefore fully recorded in the audit trail. All resources such as titrant calibration or titrant standards can be edited on the PC and printed out. Plug & Play sensors and burettes are automatically detected and all relevant data is monitored by LabX for time in service and expiration of calibration. www.mt.com For more information Mettler-Toledo AG, Analytical CH-8603 Schwerzenbach, Switzerland Tel. +41 44 806 77 11 Fax +41 44 806 72 40 Subject to technical changes © 08/2012 Mettler-Toledo AG, 51724622A Marketing Titration / MarCom Analytical Quality certificate. Development, production and testing according to ISO 9001. Environmental management system according to ISO 14001. “European conformity”. The CE conformity mark provides you with the assurance that our products comply with the EU directives.
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17:31:41+01:00, 2012:02:16 17:45:12+01:00, 2012:02:16 18:08:24+01:00, 2012:02:16 18:09:39+01:00, 2012:02:16 18:14:01+01:00, 2012:02:16 18:14:46+01:00, 2012:02:17 11:23:16+01:00, 2012:02:17 11:23:18+01:00, 2012:02:17 15:51:37+01:00, 2012:02:17 16:11:08+01:00, 2012:02:17 16:41:48+01:00, 2012:02:20 11:51:11+01:00, 2012:02:20 11:51:13+01:00, 2012:02:20 11:57:22+01:00, 2012:02:20 11:59:42+01:00, 2012:02:20 12:11:31+01:00, 2012:02:20 14:01:38+01:00, 2012:02:20 14:09:05+01:00, 2012:02:20 15:11:21+01:00, 2012:02:20 15:11:49+01:00, 2012:02:20 15:17:45+01:00, 2012:02:20 15:17:45+01:00, 2012:02:20 15:20:38+01:00, 2012:02:20 15:31:36+01:00, 2012:02:20 16:40:36+01:00, 2012:02:20 16:44:41+01:00, 2012:02:20 17:07:43+01:00, 2012:02:20 17:10+01:00, 2012:02:20 17:27:13+01:00, 2012:02:20 18:02:41+01:00, 2012:02:21 10:50:42+01:00, 2012:02:21 10:50:44+01:00, 2012:02:22 15:42:39+01:00, 2012:02:23 09:29:51+01:00, 2012:02:23 09:29:53+01:00, 2012:02:23 09:31:21+01:00, 2012:02:23 09:33:51+01:00, 2012:02:23 09:43:31+01:00, 2012:02:23 09:47:09+01:00, 2012:02:23 09:48:05+01:00, 2012:02:23 09:50:43+01:00, 2012:02:23 10:25:51+01:00, 2012:02:23 10:31:22+01:00, 2012:02:23 10:31:22+01:00, 2012:02:23 10:38:20+01:00, 2012:02:23 10:39:27+01:00, 2012:02:23 10:39:47+01:00, 2012:02:23 10:39:47+01:00, 2012:02:23 10:40:35+01:00, 2012:02:27 09:33+01:00, 2012:02:27 09:33:02+01:00, 2012:02:27 09:39:24+01:00, 2012:02:27 09:40:43+01:00, 2012:02:27 09:41:47+01:00, 2012:02:27 10:52:12+01:00, 2012:02:27 13:01:41+01:00, 2012:02:27 13:11+01:00, 2012:02:27 13:17:14+01:00, 2012:02:27 13:43:13+01:00, 2012:02:27 13:46:43+01:00, 2012:02:27 13:49:20+01:00, 2012:02:27 13:49:20+01:00, 2012:02:27 13:50:47+01:00, 2012:02:27 13:50:47+01:00, 2012:02:27 13:54:20+01:00, 2012:02:27 14:19:01+01:00, 2012:02:27 14:27:53+01:00, 2012:02:27 14:44:58+01:00, 2012:02:27 14:44:58+01:00, 2012:02:27 15:07:33+01:00, 2012:02:27 15:22:43+01:00, 2012:02:27 15:36:12+01:00, 2012:02:27 15:36:12+01:00, 2012:02:27 15:55:39+01:00, 2012:02:27 17:43:53+01:00, 2012:02:27 17:44:38+01:00, 2012:02:27 17:44:38+01:00, 2012:02:28 10:45:32+01:00, 2012:02:28 10:45:32+01:00, 2012:02:29 16:55:09+01:00, 2012:02:29 16:55:10+01:00, 2012:02:29 17:11:16+01:00, 2012:02:29 17:11:51+01:00, 2012:02:29 17:12:41+01:00, 2012:02:29 17:15:04+01:00, 2012:02:29 17:15:28+01:00, 2012:02:29 17:15:52+01:00, 2012:02:29 17:53:31+01:00, 2012:02:29 17:54:23+01:00, 2012:02:29 18:00:31+01:00, 2012:02:29 18:04:21+01:00, 2012:02:29 18:04:29+01:00, 2012:02:29 18:06:41+01:00, 2012:02:29 18:16:06+01:00, 2012:02:29 18:19:22+01:00, 2012:02:29 18:31:38+01:00, 2012:02:29 18:31:38+01:00, 2012:02:29 18:42:22+01:00, 2012:02:29 18:42:23+01:00, 2012:02:29 18:43:27+01:00, 2012:02:29 18:43:27+01:00, 2012:03:01 08:46+01:00, 2012:03:01 08:46+01:00, 2012:03:01 11:24:38+01:00, 2012:03:01 11:27:30+01:00, 2012:03:01 11:27:30+01:00, 2012:03:01 11:28:25+01:00, 2012:03:01 11:28:25+01:00, 2012:03:01 11:44:30+01:00, 2012:03:01 11:44:30+01:00, 2012:03:01 11:48:52+01:00, 2012:03:01 11:48:52+01:00, 2012:03:01 13:29:36+01:00, 2012:03:01 13:47:54+01:00, 2012:03:01 14:02:30+01:00, 2012:03:23 16:41:16+01:00, 2012:03:23 16:50:06+01:00, 2012:05:02 10:46:43+02:00, 2012:05:02 10:46:43+02:00, 2012:05:02 10:49:20+02:00, 2012:05:02 10:49:20+02:00, 2012:05:02 10:52:12+02:00, 2012:05:02 10:53:59+02:00, 2012:08:31 16:11:02+02:00, 2012:08:31 16:11:02+02:00, 2012:08:31 16:37:53+02:00, 2012:08:31 16:37:54+02:00 History Software Agent : Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 7.0, Adobe InDesign 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