GE Analytical Instruments SIEVERSM9 Total Organic Carbon Analyzer User Manual DLM 77000 01 EN MC9 MC2

GE Analytical Instruments, Inc. Total Organic Carbon Analyzer DLM 77000 01 EN MC9 MC2

User Manual

Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 20141 of 211Red text = Writer NotesCyan text = SME QuestionsMagenta text = M9 OnlyOlive text = M5310C Only
Printed in USA ©2014 The Americas Europe/Middle East/Africa Asia Pacific6060 Spine Road Unit 3, Mercury Way 7/F, Building 1, No. 1 Hua Tuo Rd.Boulder, CO 80301-3687 USA Urmston, Manchester, M41 7LY ZhangJiang Hi-Tech Park, PudongT +1 800 255 6964 United Kingdom Shanghai China 201203T +1 303 444 2009 T +44 0 161 864 6800 T + 8621 38777735F +1 303 444 9543 F +44 0 161 864 6829 F + 8621 38777469www.geinstruments.com geai.europe@ge.com geai.asia@ge.comtechsupport@geinstruments.com
Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 20143 of 211Identification RecordsAnalyzer serial number1: _________________________Analyzer serial number1: _________________________Date Analyzer Received and Installed2: _________________________1. The serial number is located on the rear panel of the Laboratory and Portable Analyzers, and on the side panel of the On-Line TOC Analyzer.2. This is the warranty date.
Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 20144 of 211Table of ContentsIdentification Records . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3Sievers M9 and M9e TOC Analyzers. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16Sievers M5310 C TOC Analyzer. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16Document Revision History. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16Trademarks and Patents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16Confidentiality . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17Declaration of Conformity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17Standard Limited Warranty . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17Chapter 1: Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23Chapter 2: System Specifications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25Sievers M9 and M9e On-Line TOC Analyzers. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25Sievers M5310 C On-Line TOC Analyzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27Sievers MC9 and MC9e Laboratory TOC Analyzers. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29Sievers M5310 C Laboratory TOC Analyzer. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31Sievers M9 and M9e Portable TOC Analyzers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33Chapter 3: System Overview. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37The Sample Flow Path . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38CO2 Transfer Modules . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41The Analyzer’s Major Subsystems. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42Sample Inlet System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 43The iOS System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44Inorganic Carbon Remover (ICR). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45Chemical Reagent System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46Oxidizer Reactor. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46CO2 Measurement Module . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47Fluidics Module. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48Electronics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49
Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 20145 of 211Electronic Controller and Processing Boards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49Data/User Controller (DUC) Board . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50Instrument Controller Board . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 51Fluidics Controller Board . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53Dual Cell Signal Processor (DCSP) Board . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54I/O Controller Board . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55Single-Cell Signal Processor Board . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56Touch Panel Display . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57Radio Frequency ID (RFID). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57Optional Configurations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59Sample Conductivity. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 60Two-Stream Inlet . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 60Inorganic Carbon Remover (ICR). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61Turbo Operation Mode. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61Optional Accessories. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61Point-of-Service (POS) Printer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61GE Autosampler and Sievers DataPro Software . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 62Sievers DataPro Software . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 62Secure Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63DataGuard Software . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64Chapter 4: Installation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65Installation Instructions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65Step 1: Unpack and Inspect the Analyzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 66Additional Equipment Requirements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67Step 2: Complete the Identification Records . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 68Step 3: Select a Location for the Analyzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 68Sievers On-Line TOC Analyzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 68Sievers Laboratory and Portable TOC Analyzers. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 71On-Line Sampling . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 72GE Autosampler System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 72Step 4: Install Power and I/O Control Wiring . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 72Installing the Power Source . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73Power Cord Installation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73
Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 20146 of 211Conduit Installation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73To wire the AC conduit . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74Installing I/O Control Wiring. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75Installing Serial and 4-20 mA Analog Outputs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76To install 4-20 mA and alarm outputs — On-Line TOC Analyzer. . . . . . . . . . . . . . . . . . . . . 76To install 4-20 mA and alarm outputs — Portable TOC Analyzer . . . . . . . . . . . . . . . . . . . . 77Pinout Tables and Wiring Diagrams . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 78Installing the Remote Start (Binary Input) Connection. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80To install the binary input connections. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81Step 5: Install the Reagent Cartridges . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81To install the reagent cartridges—Laboratory and Portable TOC Analyzers . . . . . . . . . . 82To install the reagent cartridges—On-Line TOC Analyzer . . . . . . . . . . . . . . . . . . . . . . . . . . . 84Step 6: Install the DI Water System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85To fill the DI water reservoir. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86To set the DI resin cartridge and prime the DI pump . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87To prime the DI Water pump. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87Step 7: Install Ethernet and External Devices . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89Installing an Ethernet Connection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89To install the Ethernet Connection. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89Installing a USB Connection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90USB Device Port . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90To install a USB connection — Device Port (Optional) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90USB Host Ports . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 91To install a USB Host port connection — GE Autosampler (Optional) . . . . . . . . . . . . . . . . 91To install a USB Host port connection — Printer (Optional) . . . . . . . . . . . . . . . . . . . . . . . . . 91To install a USB Host port connection — Portable USB Memory Device. . . . . . . . . . . . . . 92Installing a Printer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 92To install a USB POS printer. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 92To configure the printer in the Analyzer. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 92Step 8: Connect an On-Line Sample Inlet System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 93To connect the inlet tubing to the iOS. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94Step 9: Install the Waste Outlet (Laboratory Model) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 97To install the waste outlet . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 97Step 10: Configure Basic Analyzer Settings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98Powering On and Off the Analyzer. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98
Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 20147 of 211To power On the Analyzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99To power Off the Analyzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99Enabling Password Protection or DataGuard (Optional). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99To enable Password Protection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100To enable DataGuard . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100To create a new Administrator Account (DataGuard Only) . . . . . . . . . . . . . . . . . . . . . . . . 101To deactivate the Default Administrator account . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101Naming the Analyzer Location (Optional) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 102To name an Analyzer Location . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 102Setting the Analyzer Mode and Reagent Flow Rates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 102To set the Analyzer mode and reagent flow rates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 102Setting Up the Data History . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 103To set up the Data History . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 103Activating the Ethernet Connection and Modbus. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 103To activate the Ethernet Connection and Modbus . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 103Setting Up the Printer (Optional) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 104To set up the printer. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 104Enabling Turbo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 104To enable Turbo. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 104Exporting and Printing System Constants. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 104To export the settings to a comma-separated text file . . . . . . . . . . . . . . . . . . . . . . . . . . . . 104To print a copy of the settings. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105Setting up the Data I/O . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105To set up the Data I/O . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105Step 11: Flush and Rinse the Analyzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105To flush the reagent syringes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105To rinse the sample flow path. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 107How to Install Valco Tube Fittings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 110Step 12: Install a GE Autosampler . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 110Chapter 5: Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113Miscellaneous Notes for Sections to Add . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113To sample using the iOS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113Sampling Using a Sipper Tube. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 114Grab Sample Installation — From a Sampling Container . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 114To collect grab samples from a container . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 114
Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 20148 of 211Introduction to the Analyzer Screens. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 115Navigating in the Screens. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 116Buttons . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 116Tabs and Scrolling . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 117Field Selections. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 118Using The Home Screen. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 118Creating Sample Setup Configurations OVERVIEW . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119Understanding Analysis Time . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119Fast Flush and Normal Flush . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119Selecting a Measurement Mode . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119Setting Reagent Flow Rates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119Using an ICR . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 120Running Samples in Turbo Mode . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 120Fast Flush Normal Flush . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 120To create or change a Sampling Method? — GRAB MODE . . . . . . . . . . . . . . . . . . . . . . . . . 120To create or change a Sampling Method? — ONLINE MODE . . . . . . . . . . . . . . . . . . . . . . . 123Running a sample . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 126To run a sample. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 126Reviewing the Home Screen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 127Viewing Consumables Levels. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 128Shutting Down the Instrument . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 128Using the Protocols Screen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 128Using The Configuration Screen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 129Overview information. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 129System Settings (Constants) Export. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 129To export system settings (constants). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 129The Result Preferences Tab . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 130To set result preferences. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 130The Environment Preferences Tab. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 131To set the language . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 131To set environment preferences. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 132The Keyword Search Tab . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 133To set keyword search options . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 133The System Setup Tab . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134Setting the System Clock. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134To set the system clock . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 135Configuring a Printer. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 135To configure a printer connection (optional). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 135
Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 20149 of 211Configuring the Network . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 136To configure the network connection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 136Configuring 4-20mA output . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 137To configure the 4-20mA output (optional) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 137Configuring Binary I/O Input. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 137To configure the binary I/O input (optional) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 137Pharmacopoeia Overview. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138Selecting a Pharmacopoeia Monograph . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 140To specify the pharmacopoeia (optional). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 140Using The Maintenance Screen. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 141Overview. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 141Settings (Constants) Export . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 142To export system settings (constants). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 142The Consumables Tab . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 142To renew an expiration date . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 142The Error History Tab . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143To view error and warning history . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143The Diagnostics Tab . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 145The Advanced Tab. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 146Cleaning the Analyzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 146To clean the external housing. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 146To clean the touchscreen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147Flushing the syringes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147Upgrading the Firmware. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147Activating DataGuard and Turbo Options. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 148Calibrating the Touch Panel. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 148Backing up the Database . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149Using The Data View Screen. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149Using the Security/DataGuard Screen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149Using the Help Screen. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149Using the Ethernet Connection and Modbus . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149Using The Security/DataGuard Screen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 150Chapter 6: Password Protection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153
Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201410 of 211Chapter 7: Calibration and Verification . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155 Using The Protocols Screen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155Protocol 1 test . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 156Test SingleSource. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 156heading 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 156heading 3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 156Chapter 8: Maintenance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 159Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 159Interior Views of the Analyzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160Using The Maintenance Screen. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160Overview. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160Performing Routine Maintenance Tasks. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 161Flushing Reagent Syringes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 161To flush the reagent syringes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 161Maintaining the DI Water Reservoir Level . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 162To fill the DI water reservoir. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 162Cleaning the Analyzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 162To clean the external housing. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 162To clean the touchscreen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 162Replacing Consumables Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 163Maintenance Schedule . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 163Tracking Consumables Expiration Dates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 163To renew an expiration date . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164Replacing Consumable Items . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164Replacing the Resin Cartridge . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165To replace the resin cartridge . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165Replacing the Chemical Reagents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165To replace the reagent cartridges . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165Replacing the UV Lamp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165To replace the UV Lamp . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165Replacing the Pump Heads . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165To replace the pump heads . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165Replacing the In-Line Filter Element . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165
Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201411 of 211To replace the in-line filter element . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 166Replacing the ICR Chemical Trap (ICR users ONLY). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 166To replace the chemical trap. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 166Chapter 9: Troubleshooting . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 167Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 167The Diagnostics Tab . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 167Warning and Error Messages. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 167Overfilling the DI Water reservoir . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 168To drain excess water from the DI water reservoir. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 168The Error History Tab . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 169To view error and warning history . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 169The Diagnostics Tab . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 170Chapter 10: Turbo Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 173Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 173Appendix A: WARNINGS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 175English. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 175Hazardous Material Disposal. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 179Operational Cautions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 179中文 (Chinese). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 181有害物质处理 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 182操作注意事项 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 183日本語 (Japanese). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 184有害物質処分 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 186操作上の注意 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 186Deutsch . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 188ENTSORGUNG VON GEFAHRSTOFFEN. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 190VORSICHTSMASSNAHMEN BEIM BETRIEB. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 191Français . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 192PRÉCAUTIONS DE FONCTIONNEMENT. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 195Italiano . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 197SMALTIMENTO DI MATERIALI PERICOLOSI . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 199AVVERTENZE PER IL FUNZIONAMENTO. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 200Español . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 201DESECHO DE MATERIALES PELIGROSOS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 203PRECAUCIONES OPERATIVAS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 204Portuguese . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205DESCARTE DE MATERIAIS PERIGOSOS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 207
Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201412 of 211CUIDADOS OPERACIONAIS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 207Appendix B: Modbus Map . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 209Using PuTTY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 209To install the serial connection:. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 209
Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201413 of 211List of TablesTable 1 Sample Inlet Systems by Analyzer Model . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 43Table 2 Serial and 4-20 mA Outputs (J4). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79Table 3 Alarm Outputs (J6) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80Table 4 Binary Inputs (Terminal BlockJ5) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81Table 5 Recommended Acid Flow Rates. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119Table 6 Recommended Oxidizer Flow Rates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 120
Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201414 of 211List of FiguresFigure 1 Analyzer Schematic—On-Line and Portable Models . . . . . . . . . . . . . . . . . . . . . . . . . . 38Figure 2 Analyzer Schematic—Laboratory Model . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39Figure 3 Sample Flow through the CO2 Transfer Module . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41Figure 4 The Analyzer’s Major Subsystems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42Figure 5 The Analyzer’s Major Subsystems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 43Figure 6 Electronics Block Diagram — Sievers M9 and M9eTOC Analyzers . . . . . . . . . . . . . 49Figure 7 Sievers M5310 C TOC Analyzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49Figure 8 The Data/User Controller (DUC) Board . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50Figure 9 The Instrument Controller Board . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 51Figure 10 Ethernet and USB Port Locations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52Figure 11 The Fluidics Controller Board . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53Figure 12 The Dual Cell Signal Processor (DCSP) Board . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54Figure 13 The I/O Controller Board . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55Figure 14 The Single-Cell Signal Processor Board . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56Figure 15 Required Installation Clearances — On-Line TOC Analyzer . . . . . . . . . . . . . . . . . . . . 69Figure 16 Left Side Dimensions — On-Line TOC Analyzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70Figure 17 Right Side Dimensions — On-Line TOC Analyzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 71Figure 18 Wiring AC Power Conduit . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75Figure 19 Wiring 4-20 mA Connections . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 78Figure 20 Wiring Option for Binary Input Using Analyzer’s Internal Supply . . . . . . . . . . . . . . . 81Figure 21 Wiring Option for Binary Input Using External Supply . . . . . . . . . . . . . . . . . . . . . . . . . 81Figure 22 Inserting the DI Loop Fill Tube . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87Figure 23 Filling the DI Water Reservoir. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87Figure 24 DI Cartridge Inlet Fittings for Priming Activity. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88Figure 25 DI Cartridge Positioning for Analyzer Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88Figure 26 USB Ports . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 92Figure 27 iOS Waste Outlet Fitting — On-Line and Portable TOC Analyzers . . . . . . . . . . . . . 94Figure 28 This iOS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95Figure 29 Flow Rate Adjustment Screw . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 96Figure 30 Waste Outlet Fitting — Laboratory TOC Analyzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98Figure 31 Modify Online Method Dialog Box . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 108
Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201415 of 211Figure 32 Modify Timed Online Method Dialog Box . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 108Figure 33 Modify TOC Removal Online Method Dialog Box. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 108Figure 34 Stainless Steel Tubing — Connecting the Analyzer and iOS. . . . . . . . . . . . . . . . . . . 110Figure 35 Nut and Ferrule Orientation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 110Figure 36 Modify Online Method Dialog Box . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 124Figure 37 Modify Timed Online Method Dialog Box . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 124Figure 38 Modify TOC Removal Online Method Dialog Box. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 124Figure 39 USB Connection Locations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149Figure 40 XX . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 150Figure 41 Interior Overview — On-Line TOC Analyzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160Figure 42 Interior Overview — Laboratory TOC Analyzer. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160Figure 43 Interior Overview — Portable TOC Analyzer. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160Figure 44 1-Year Maintenance Record Log . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 163Figure 45 Dispensing Bottle Tip . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 168
Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201416 of 211Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC AnalyzerDOCUMENT REVISION HISTORYDocument Version Firmware/Software Version DateDLM 77000-01 Rev. A 1.0 Product Release January 2014TRADEMARKS AND PATENTS*Sievers is a trademark of General Electric Company and may be registered in one or more countries.Allen® is a trademark of the Allen Manufacturing Company; HyperTerminal® is a registered trademark of Hilgraeve; Norprene® is a registered trademark of Norton Performance Plastics Corporation; Swagelok® is a registered trademark of the Swagelok Company. Microsoft Windows®, Windows XP®, Windows Vista®, Microsoft®, Excel®, and Internet Explorer® are registered trademarks of Microsoft Corporation.The Analyzer described in this manual is covered by one or more patents issued to and owned or pending by General Electric Company, including the following:;US 5132094 GB 0897538US 5443991 FR 0897538US 5820823 DE 0897538US 5798271 EP 0897530US 6228325 GB 0897530US 5902751 FR 0897530US 8003048 DE 0897530EP 0 471 067 US 5976468
Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201417 of 211CONFIDENTIALITYThe information contained in this manual may be confidential and proprietary, and is the property of GE Analytical Instruments. Information disclosed herein shall not be used to manufacture, construct, or otherwise reproduce the goods disclosed herein. The information disclosed herein shall not be disclosed to others or made public in any manner without the express written consent of GE Analytical Instruments.DECLARATION OF CONFORMITYA copy of the Declaration of Conformity for this product is available in the Library on our website:http://www.geinstruments.com/conformitySTANDARD LIMITED WARRANTYGE Analytical Instruments warrants its Sievers1products for defects in materials and workmanship. GE Analytical Instruments will, at its option, repair or replace instrument components that prove to be defective with new or remanufactured components (that is, equivalent to new). The warranty set forth is exclusive and no other warranty, whether written or oral, is expressed or implied.WARRANTY TERMThe GE Analytical Instruments warranty term is thirteen (13) months ex-works, or twelve (12) monthsfrom installation or start up by GE Analytical Instruments certified service personnel. In no event shallthe standard limited warranty coverage extend beyond thirteen (13) months from original shipmentdate.WARRANTY SERVICEWarranty Service is provided to customers through telephone support (1 800 255 6964), Monday -Friday, from 8:00 a.m. to 5:00 p.m. (Mountain Time), excluding all company and legal holidays.Telephone support is provided for troubleshooting and determination of parts to be shipped fromGE Analytical Instruments to the customer in order to return the product to operation. If telephoneEP 0897538 and other patents pending1Trademark of General Electric Company; may be registered in one or more countries.
Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201418 of 211support is not effective, the product may be returned to GE Analytical Instruments for repair orreplacement. In some instances, suitable instruments may be available for short duration loan orlease.GE Analytical Instruments warrants that any labor services provided shall conform to the reasonablestandards of technical competency and performance effective at the time of delivery. All serviceinterventions are to be reviewed and authorized as correct and complete at the completion of theservice by a customer representative, or designate. GE Analytical Instruments warrants these servicesfor 30 days after the authorization and will correct any qualifying deficiency in labor provided that thelabor service deficiency is exactly related to the originating event. No other remedy, other than theprovision of labor services, may be applicable.Repair components (parts and materials), but not consumables, provided in the course of a repair, orpurchased individually, are warranted for 90 days ex-works for materials and workmanship. In noevent will the incorporation of a warranted repair component into an instrument extend the wholeinstrument’s warranty beyond its original term.Consumables (e.g., dilution standards, verification solutions, and UV lamps, etc.) are warranted to theextent of their stated shelf life, provided these items are maintained within the stated environmentallimitations. Warranty claims for consumables and verification standards are limited to thereplacement of the defective items, prorated from the time of claim to the expiration of shelf life.SHIPPINGA Repair Authorization Number (RA) must be obtained from the Technical Support Group before anyproduct can be returned to the factory. GE Analytical Instruments will pay freight charges, exclusive ofany taxes and duties, for replacement or repaired products shipped to the customer site. Customersshall pay freight charges, including all taxes and duties, for all products returning toGE Analytical Instruments. Any product returned to the factory without an RA number will be returnedto the customer.LIMITATION OF REMEDIES AND LIABILITYThe foregoing warranty shall not apply to defects resulting from improper or inadequate installation,maintenance, adjustment, calibration, or operation by customer. Installation, maintenance,adjustment, calibration, or operation must be performed in accordance with instructions stated in theOperation and Maintenance Manual. Usage of non-recommended maintenance materials may void awarranty claim.The remedies provided herein are the customer's sole and exclusive remedies. In no event shallGE Analytical Instruments be liable for direct, indirect, special, incidental or consequential damages(including loss of profits) whether based on contract, tort, or any other legal theory. The Operationand Maintenance Manual is believed to be accurate at the time of publication and no responsibility istaken for any errors that may be present. In no event shall GE Analytical Instruments be liable forincidental or consequential damages in connection with or arising from the use of the manual and itsaccompanying related materials. Warranty is valid only for the original purchaser. This LimitedWarranty is not transferable from the original purchaser to any other party without the express
Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201419 of 211written consent from GE Analytical Instruments. GE Analytical Instruments specifically disclaims theimplied warranties of merchantability and fitness for a particular purpose.LIMITACIÓN DE REMEDIOS Y RESPONSABILIDADLa garantía anterior no se aplicará a los defectos que resulten de la realización incorrecta oinadecuada de la instalación, el mantenimiento, el ajuste, la calibración o el manejo por parte delcliente. La instalación, el mantenimiento, el ajuste, la calibración o el manejo deberán llevarse a cabode acuerdo con las instrucciones indicadas en el manual de funcionamiento y mantenimiento. El usode materiales de mantenimiento que no sean los recomendados puede anular una reclamación degarantía.Los remedios que aquí se indican serán los únicos los remedios para el cliente. En ningún casoGGE Analytical Instruments será responsable de daños directos, indirectos, especiales, incidentales oconsecuentes (incluida la pérdida de beneficios) ya sean contractuales, extracontractuales o basadoen cualquier otra teoría legal. Se considera que el manual de funcionamiento y mantenimiento esexacto en el momento de su publicación y no se acepta ninguna responsabilidad por los errores quepueda contener. En ningún caso será GE Analytical Instruments responsable de los daños incidentaleso consecuentes que resulten o estén relacionados con el uso del manual y los materiales que loacompañan. La garantía es únicamente válida para el comprador original. El comprador original nopuede transferir esta garantía limitada a ninguna otra parte sin el consentimiento expreso por escritode GE Analytical Instruments. GE Analytical Instruments renuncia específicamente a las garantíasimplícitas de comercialización e idoneidad para un determinado propósito.LIMITES DE CORRECTION ET DE FIABILITÉLa garantie susdite ne s’applique pas aux défauts résultants d’une installation, d’une maintenance,d’un réglage, d’un calibrage ou d’un fonctionnement inapproprié, opéré par l’utilisateur. L’installation,la maintenance, le réglage, le calibrage ou le fonctionnement doit être réalisé conformément auxinstructions du manuel de l’utilisateur et de maintenance. La mise en œuvre de procédures demaintenance non recommandées peut annuler toute disposition de garantie.Les procédures de correction indiquées dans le présent document sont les seuls remèdes du client. Legroupe GE Analytical Instruments ne saurait en aucun cas être tenu pour responsable de toutpréjudice direct, indirect ou spécial de quelque nature que ce soit (y compris, les pertes de bénéfices),qu’il soit fondé sur un contrat, sur un acte dommageable ou sur une autre théorie légale. Le manuelde l’opérateur et de maintenance est aussi précis que possible au moment de la publication et laresponsabilité du groupe ne saurait être engagée pour les éventuelles erreurs qu’il pourrait contenir.Le groupe GE Analytical Instruments ne saurait en aucun cas être tenu pour responsable despréjudices accidentels ou de quelque nature que ce soit, dus à l’utilisation du manuel ou de ladocumentation connexe. La garantie ne s’applique qu’à l’acquéreur d’origine. La garantie limitée nepeut être transférée par l’acquéreur d’origine à une autre partie sans l’autorisation expresse écrite dugroupe GE Analytical Instruments. GE Analytical Instruments exclut tout particulièrement lesgaranties implicites de commercialisation et d’adaptabilité dans un but spécifique.
Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201420 of 211BESCHRÄNKTE ANSPRÜCHE UND HAFTUNGDie vorangehende Garantie gilt nicht für Schäden, die aus unsachgemäßer oder unzureichenderInstallation, Wartung, Anpassung, Kalibrierung oder Betrieb durch den Kunden resultieren.Installation, Wartung, Anpassung, Kalibrierung oder Betrieb müssen gemäß den Anweisungen in derBedienungsanleitung durchgeführt werden. Durch die Verwendung von nicht empfohlenenWartungsmaterialien kann der Garantieanspruch erlöschen.Die hier erwähnten Ansprüche beziehen sich auf die einzigen und ausschließlichen Ansprüche desKunden. GE Analytical Instruments ist unter keinen Umständen verantwortlich für direkte, indirekte,besondere, zufällig entstandene oder Folgeschäden (einschließlich Verlust von Einkünften), die aufVertrag, unerlaubten Handlungen oder andere Rechtstheorien basieren. Die Bedienungsanleitung istzur Zeit der Veröffentlichung nach bestem Wissen korrekt, und es wird keine Verantwortung fürmögliche vorhandene Fehler übernommen. GE Analytical Instruments ist unter keinen Umständenhaftbar für zufällige oder Folgeschäden, die in Verbindung mit oder durch die Verwendung derBedienungsanleitung und begleitender Materialien entstehen. Die Garantie gilt nur für denursprünglichen Käufer. Die beschränkte Garantie lässt sich nicht ohne ausdrückliche schriftlicheGenehmigung von GE Analytical Instruments vom ursprünglichen Käufer auf eine andere Personübertragen. GE Analytical Instruments schließt besonders die konkludente Garantie derHandelsüblichkeit und Eignung für einen bestimmten Zweck aus.LIMITAZIONE DI RIMEDI E RESPONSABILITÀLa precedente garanzia non è valida per difetti risultanti da installazione, manutenzione, regolazione,taratura o utilizzo improprio o inadeguato da parte dell’utente. L’installazione, la manutenzione, laregolazione, la taratura o l’utilizzo deve essere conforme alle istruzioni indicate nel manuale d’uso emanutenzione. L’utilizzo di materiali di manutenzione diversi da quelli consigliati rende nullo unreclamo in garanzia.Gli unici rimedi spettanti all’utente sono quelli qui inclusi. In nessun caso GE Analytical Instrumentssarà responsabile per danni diretti, indiretti, speciali, accidentali o consequenziali (inclusa la perdita diprofitti) risultanti dall’applicazione del contratto, atto illecito o altra teoria legale. Il manuale d’uso emanutenzione è accurato al momento della pubblicazione e l’azienda non si assume alcunaresponsabilità per la presenza di eventuali errori. In nessun caso GE Analytical Instruments saràresponsabile per danni accidentali o consequenziali correlati o derivanti dall’utilizzo del manuale e dialtro materiale di supporto correlato. La garanzia è valida solo per l’acquirente originale. La presentegaranzia limitata non è trasferibile dall’acquirente originale a terzi senza l’espresso consenso scrittoda parte di GE Analytical Instruments. GE Analytical Instruments declina espressamente le garanzieimplicite di commerciabilità e idoneità a un particolare scopo.限定責任および救済前述の保証は、お客様による不適切または不十分な取り付け、保守、調整、校正、あるいは操作によって生じた不具合には適用されないものとします。 取り付け、保守、調整、校正、または操作は、Operation and Maintenance Manual ( 操作取扱説明書 )』に記載されている指示に従って行う必要があります。 推奨外の保守資材を使用すると、保証請求が無効になる場合があります。
Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201421 of 211ここで提供される救済は、お客様の唯一の排他的救済となります。 GE Analytical Instruments は、いかなる場合においても、直接的、間接的、特別的、付随的、または派生的損害（利益の逸失を含む）に対し、それが契約、不法行為、またはその他の法的理論に基づくものであるかどうかにかかわらず、一切責任を負いません。 Operation and Maintenance Manual ( 操作取扱説明書)』は、出版された時点で正確であるものと考えられており、万が一発生した誤りに対する責任は一切負いません。 GE Analytical Instruments は、いかなる場合においても、マニュアルまたはそれに付属の関連資料の使用に関連して、またはその使用が原因で発生した付随的または派生的損害にも一切責任を負いません。 保証は最初の購入者に対してのみ有効です。 本限定保証を、GE Analytical Instruments の書面による同意なしに、最初の購入者から第三者に譲渡することはできません。 GE Analytical Instruments は、商品性および特定の目的に対する適合性の黙示の保証を一切拒否します。赔偿与责任限制上述保证不适用于因客户不正确或不恰当的安装、维护、调整、校准或操作导致的故障。安装、维护、调整、校准或操作必须遵循操作与维护手册中的说明进行。使用非推荐的维护材料可能会导致保证失效。这里提供的赔偿为客户的唯一和独占赔偿。在任何情况下，GE Analytical Instruments 不对任何直接的、间接的、特殊的、偶发的或连带发生的损失 （包括利润损失）负责，无论这些损害是依据何种合同责任理论、侵权行为责任理论或其它法律理论进行推断的。操作与维护手册在出版时被认为是准确的， GE Analytical Instruments 不对其中可能存在的任何错误负责。在任何情况下， GE Analytical Instruments 均不对因使用该手册 （或与其使用有关）或相关材料导致的偶发或连带发生的损失负责。保证仅对原购买者有效。未经GE Analytical Instruments 明确书面同意，此有限保证不可由原购买者转让给任何其他方。GE Analytical Instruments 特此声明不提供任何关于特殊用途的适销性和适用性的暗示担保。
Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201422 of 211
1..............................................Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201423 of 211INTRODUCTIONThe Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer from GE Analytical Instruments includes patented1 high-sensitivity Analyzers used to measure the concentration of total organic carbon (TOC), total inorganic carbon (TIC), and total carbon (TC = TOC + TIC) in water samples.The Analyzer is based on the oxidation of organic compounds to form carbon dioxide (CO2) using UV radiation and a chemical oxidizing agent (ammonium persulfate). Carbon dioxide is measured using a sensitive, selective membrane-based conductometric detection technique as described by Godec et al. (R. Godec et al., “Method and Apparatus for the Determination of Dissolved Carbon in Water,” U.S. Patent No. 5,132,094). For each TOC measurement, the concentration of inorganic carbon species (CO2, HCO3-, and CO3-2) is determined and, after oxidation of the organic compounds, the total carbon (TC) content of the sample is measured. The concentration of the organic compounds is then calculated from the difference between the concentrations of TC and total inorganic carbon (TIC), generally referred to simply as inorganic carbon (IC).(TOC = TC - IC)You can use the Analyzer to monitor water samples ranging from high-purity water containing 0.03 parts per billion (ppb) TOC to water samples containing up to 50 parts per million (ppm) TOC. The Analyzer is easy to operate, with extremely low maintenance, and requiring no special training or chemical knowledge. The Analyzer is calibrated at the factory, and calibration remains stable for approximately one year. Recalibration and validation is easily performed at your location site.This manual presents operation and maintenance information for the Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer. This information, including step-by-step instructions, applies to ALL three models (On-Line, Lab, and Portable), except where specifically noted.1. For a complete list of patents issued to GE Analytical Instruments, see “Trademarks and Patents” on page 16.
INTRODUCTIONChapter 1Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201424 of 211THIS PAGE IS INTENTIONALLY LEFT BLANK.
2..............................................Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201425 of 211SYSTEM SPECIFICATIONSThis chapter provides a system specifications1 for each model (On-Line, Laboratory, and Portable) of the Sievers M9 and M9e TOC Analyzers areSievers M5310 C TOC Analyzer is included in this section.Sievers M9 and M9e On-Line TOC AnalyzersSamplingLINEAR RANGE 0.03 ppb – 50 ppm TOCPRECISION <1% of RSDACCURACY ±2% or ±0.5 ppb, whichever is greaterANALYSIS TIME 2 minSAMPLE FLOW RATE (NOMINAL)Analysis mode: 0.5 mL/minFast flush (between samples): 2.0 mL/min(optional) Turbo mode: 1.0 mL/minREQUIRED SAMPLE LINE FLOW RATE On-line mode: 50 mL - 300 mL/minSAMPLE TEMPERATURE 1 °C to 95 °C via iOS2 (withstands short-term steam exposure)AMBIENT TEMPERATURE 10 °C to 40 °CSAMPLE PRESSURE (IN IOS SYSTEM)Up to 250 psigCALIBRATION STABILITY Typically stable for 12 monthsCHEMICAL REAGENTS GE Analytical Instruments pre-packaged reagents: 300 mL acid and300 mL or 150 mL oxidizer1. Stated analytical performance is achievable under controlled laboratory conditions that minimize operator and standards errors.2. If the sample temperature and pressure are above 60° C and 100 psi, the Sievers M9 and M9e On-Line TOC Analyzers model with the Kymar or PVDF iOS is required.
SYSTEM SPECIFICATIONSChapter 2Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201426 of 211Turbo (Optional)LINEAR RANGE xxPRECISION xxACCURACY xxANALYSIS TIME xxElectronicsPOWER REQUIREMENTS 100-240 ±10% VAC, 100 VA, 50/60 HzDO NOT CHANGEFUSES No user-replaceable fusesOUTPUTS 4–20 mA, two alarms, binary output, Ethernet portINSTALLATION/OVER-VOLTAGE CATEGORY II RFID Radio tracking and controlling of reagents; Meets Part 15 of the FCCRules & Industry Canada license (exempt RSS standards)EnvironmentNORMAL OPERATING ENVIRONMENT Intended for indoor use ONLYMAXIMUM RELATIVE HUMIDITY Up to 95%, non-condensingMAXIMUM ALTITUDE 3,000 m (9,843 ft)POLLUTION DEGREE 2DISPLAY Color, touch-sensitive WVGA LCDSIZE 35.6 cm height x 22.3 cm width x 46.5 cm depth(14.0 in x 8.8 in x 18.3 in) 62.4 cm height x 45.2 cm width x 26.4 cm depth(24.6 in x 17.8 in x 10.4 in) 48.3 cm height x 19.2 cm width x 48.0 cm depth(19.0 in x 7.6 in x 18.9 in)WEIGHT 16.4 kg (36.2lb) CertificationsSAFETY CERTIFICATIONS CE, ETL listed. Conforms to UL Std. 61010-1Certified to CSA C22.2 No. 61010-1ISO?Any mention in addition to or instead of for CB Scheme.IP RATING IP 45
.................................SIEVERS M5310 C ON-LINE TOC ANALYZERSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201427 of 211Sievers M5310 C On-Line TOC AnalyzerSamplingLINEAR RANGE 0.03 ppb – 50 ppm TOCPRECISION <1% of RSDACCURACY ±2% or ±0.5 ppb, whichever is greaterANALYSIS TIME 2 minSAMPLE FLOW RATE (NOMINAL)Analysis mode: 0.5 mL/minFast flush (between samples): 2.0 mL/min(optional) Turbo mode: 1.0 mL/minREQUIRED SAMPLE LINE FLOW RATE On-line mode: 50 mL - 300 mL/minSAMPLE TEMPERATURE 1 °C to 95 °C via iOS3 (withstands short-term steam exposure)AMBIENT TEMPERATURE 10 °C to 40 °CSAMPLE PRESSURE (IN IOS SYSTEM)Up to 250 psigCALIBRATION STABILITY Typically stable for 12 monthsCHEMICAL REAGENTS GE Analytical Instruments pre-packaged reagents: 300 mL acid and300 mL or 150 mL oxidizerElectronicsPOWER REQUIREMENTS 100-240 ±10% VAC, 100 VA, 50/60 HzDO NOT CHANGEFUSES No user-replaceable fusesOUTPUTS 4–20 mA, two alarms, binary output, Ethernet port, and one USB deviceport4 and two USB host ports5INSTALLATION/OVER-VOLTAGE CATEGORY II RFID Radio tracking and controlling of reagents; Meets Part 15 of the FCCRules & Industry Canada license (exempt RSS standards)EnvironmentNORMAL OPERATING ENVIRONMENT Intended for indoor use ONLYMAXIMUM RELATIVE HUMIDITY Up to 95%, non-condensingMAXIMUM ALTITUDE 3,000 m (9,843 ft)3. If the sample temperature and pressure are above 60° C and 100 psi, the Sievers M9 and M9e On-Line TOC Analyzers model with the Kymar or PVDF iOS is required.4. The USB device port is used for connecting to a computer when operating with a GE Autosampler.5. The two USB host ports are used for connecting a GE Autosampler, printer, or portable USB memory device (for installing updates or exporting data),
SYSTEM SPECIFICATIONSChapter 2Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201428 of 211POLLUTION DEGREE 2DISPLAY Color, touch-sensitive WVGA LCDSIZE 35.6 cm height x 22.3 cm width x 46.5 cm depth(14.0 in x 8.8 in x 18.3 in) 62.4 cm height x 45.2 cm width x 26.4 cm depth(24.6 in x 17.8 in x 10.4 in) 48.3 cm height x 19.2 cm width x 48.0 cm depth(19.0 in x 7.6 in x 18.9 in)WEIGHT 16.4 kg (36.2lb) CertificationsSAFETY CERTIFICATIONS CE, ETL listed; Conforms to UL Std. 61010-1Certified to CSA C22.2 No. 61010-1ISO?Any mention in addition to or instead of for CB Scheme.IP RATING IP 45
.................................SIEVERS MC9 AND MC9e LABORATORY TOC ANALYZERSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201429 of 211Sievers MC9 and MC9e Laboratory TOC AnalyzersSamplingLINEAR RANGE 0.03 ppb – 50 ppm TOCPRECISION <1% of RSDACCURACY ±2% or ±0.5 ppb, whichever is greaterANALYSIS TIME 2 minSAMPLE FLOW RATE (NOMINAL)Analysis mode: 0.5 mL/minFast flush (between samples): 2.0 mL/min(optional) Turbo mode: 1.0 mL/minREQUIRED SAMPLE LINE FLOW RATE On-line mode: 50 mL - 300 mL/minSAMPLE TEMPERATURE 1 °C to 95 °C via iOS6 (withstands short-term steam exposure)AMBIENT TEMPERATURE 10 °C to 40 °CSAMPLE PRESSURE (IN IOS SYSTEM)Up to 250 psigCALIBRATION STABILITY Typically stable for 12 monthsCHEMICAL REAGENTS GE Analytical Instruments pre-packaged reagents: 300 mL acid and300 mL or 150 mL oxidizerTurbo (Optional)LINEAR RANGE xxPRECISION xxACCURACY xxANALYSIS TIME xxStage II Sample Conductivity (Optional)RAW CONDUCTIVITY RANGE 0.01 - 35 S/cmCONDUCTIVITY ACCURACY xCONDUCTIVITY PRECISION XMAXIMUM SAMPLE CONDUCTIVITY XElectronicsPOWER REQUIREMENTS 100-240 ±10% VAC, 100 VA, 50/60 Hz6. If the sample temperature and pressure are above 60° C and 100 psi, the Sievers M9 and M9e On-Line TOC Analyzers model with the Kymar or PVDF iOS is required.
SYSTEM SPECIFICATIONSChapter 2Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201430 of 211DO NOT CHANGEFUSES Replace with same type and size. T1.6 A, 250 VAC (SloBlo), size 5 x 20 mm (appliance inlet)OUTPUTS 4–20 mA, two alarms, binary output, Ethernet portINSTALLATION/OVER-VOLTAGE CATEGORY II RFID Radio tracking and controlling of reagents; Meets Part 15 of the FCCRules & Industry Canada license (exempt RSS standards)EnvironmentNORMAL OPERATING ENVIRONMENT Intended for indoor use ONLYMAXIMUM RELATIVE HUMIDITY Up to 95%, non-condensingMAXIMUM ALTITUDE 3,000 m (9,843 ft)POLLUTION DEGREE 2DISPLAY Color, touch-sensitive WVGA LCDSIZE 35.6 cm height x 22.3 cm width x 46.5 cm depth(14.0 in x 8.8 in x 18.3 in) 62.4 cm height x 45.2 cm width x 26.4 cm depth(24.6 in x 17.8 in x 10.4 in) 48.3 cm height x 19.2 cm width x 48.0 cm depth(19.0 in x 7.6 in x 18.9 in)WEIGHT 16.4 kg (36.2lb) CertificationsSAFETY CERTIFICATIONS CE, ETL listed; Conforms to UL Std. 61010-1Certified to CSA C22.2 No. 61010-1ISO?Any mention in addition to or instead of for CB Scheme.IP RATING IP 45
.................................SIEVERS M5310 C LABORATORY TOC ANALYZERSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201431 of 211Sievers M5310 C Laboratory TOC AnalyzerSamplingLINEAR RANGE 0.03 ppb – 50 ppm TOCPRECISION <1% of RSDACCURACY ±2% or ±0.5 ppb, whichever is greaterANALYSIS TIME 2 minSAMPLE FLOW RATE (NOMINAL)Analysis mode: 0.5 mL/minFast flush (between samples): 2.0 mL/min(optional) Turbo mode: 1.0 mL/minREQUIRED SAMPLE LINE FLOW RATE On-line mode: 50 mL - 300 mL/minSAMPLE TEMPERATURE 1 °C to 95 °C via iOS7 (withstands short-term steam exposure)AMBIENT TEMPERATURE 10 °C to 40 °CSAMPLE PRESSURE (IN IOS SYSTEM)Up to 250 psigCALIBRATION STABILITY Typically stable for 12 monthsCHEMICAL REAGENTS GE Analytical Instruments pre-packaged reagents: 300 mL acid and300 mL or 150 mL oxidizerStage II Sample Conductivity (Optional)RAW CONDUCTIVITY RANGE 0.01 - 35 S/cmCONDUCTIVITY ACCURACY xCONDUCTIVITY PRECISION XMAXIMUM SAMPLE CONDUCTIVITY XElectronicsPOWER REQUIREMENTS 100-240 ±10% VAC, 100 VA, 50/60 HzDO NOT CHANGEFUSES Replace with same type and size. T1.6 A, 250 VAC (SloBlo), size 5 x 20 mm (appliance inlet)OUTPUTS 4–20 mA, two alarms, binary output, Ethernet portINSTALLATION/OVER-VOLTAGE CATEGORY II RFID Radio tracking and controlling of reagents; Meets Part 15 of the FCCRules & Industry Canada license (exempt RSS standards)7. If the sample temperature and pressure are above 60° C and 100 psi, the Sievers M9 and M9e On-Line TOC Analyzers model with the Kymar or PVDF iOS is required.
SYSTEM SPECIFICATIONSChapter 2Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201432 of 211EnvironmentNORMAL OPERATING ENVIRONMENT Intended for indoor use ONLYMAXIMUM RELATIVE HUMIDITY Up to 95%, non-condensingMAXIMUM ALTITUDE 3,000 m (9,843 ft)POLLUTION DEGREE 2DISPLAY Color, touch-sensitive WVGA LCDSIZE 35.6 cm height x 22.3 cm width x 46.5 cm depth(14.0 in x 8.8 in x 18.3 in) 62.4 cm height x 45.2 cm width x 26.4 cm depth(24.6 in x 17.8 in x 10.4 in) 48.3 cm height x 19.2 cm width x 48.0 cm depth(19.0 in x 7.6 in x 18.9 in)WEIGHT 16.4 kg (36.2lb) CertificationsSAFETY CERTIFICATIONS CE, ETL listed; Conforms to UL Std. 61010-1Certified to CSA C22.2 No. 61010-1ISO?Any mention in addition to or instead of for CB Scheme.IP RATING IP 45
.................................SIEVERS M9 AND M9e PORTABLE TOC ANALYZERSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201433 of 211Sievers M9 and M9e Portable TOC AnalyzersSamplingLINEAR RANGE 0.03 ppb – 50 ppm TOCPRECISION <1% of RSDACCURACY ±2% or ±0.5 ppb, whichever is greaterANALYSIS TIME 2 minSAMPLE FLOW RATE (NOMINAL)Analysis mode: 0.5 mL/minFast flush (between samples): 2.0 mL/min(optional) Turbo mode: 1.0 mL/minREQUIRED SAMPLE LINE FLOW RATE On-line mode: 50 mL - 300 mL/minSAMPLE TEMPERATURE 1 °C to 95 °C via iOS8 (withstands short-term steam exposure)AMBIENT TEMPERATURE 10 °C to 40 °CSAMPLE PRESSURE (IN IOS SYSTEM)Up to 250 psigCALIBRATION STABILITY Typically stable for 12 monthsCHEMICAL REAGENTS GE Analytical Instruments pre-packaged reagents: 300 mL acid and300 mL or 150 mL oxidizerStage II Sample Conductivity (Optional)RAW CONDUCTIVITY RANGE 0.01 - 35 S/cmCONDUCTIVITY ACCURACY xCONDUCTIVITY PRECISION XMAXIMUM SAMPLE CONDUCTIVITY XTurbo (Optional)LINEAR RANGE xxPRECISION xxACCURACY xxANALYSIS TIME xxElectronicsPOWER REQUIREMENTS 100-240 ±10% VAC, 100 VA, 50/60 Hz8. If the sample temperature and pressure are above 60° C and 100 psi, the Sievers M9 and M9e On-Line TOC Analyzers model with the Kymar or PVDF iOS is required.
SYSTEM SPECIFICATIONSChapter 2Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201434 of 211DO NOT CHANGEFUSES Replace with same type and size. T1.6 A, 250 VAC (SloBlo), size 5 x 20 mm (appliance inlet)OUTPUTS 4–20 mA, two alarms, binary output, Ethernet portINSTALLATION/OVER-VOLTAGE CATEGORY II RFID Radio tracking and controlling of reagents; Meets Part 15 of the FCCRules & Industry Canada license (exempt RSS standards)EnvironmentNORMAL OPERATING ENVIRONMENT Intended for indoor use ONLYMAXIMUM RELATIVE HUMIDITY Up to 95%, non-condensingMAXIMUM ALTITUDE 3,000 m (9,843 ft)POLLUTION DEGREE 2DISPLAY Color, touch-sensitive WVGA LCDSIZE 35.6 cm height x 22.3 cm width x 46.5 cm depth(14.0 in x 8.8 in x 18.3 in) 62.4 cm height x 45.2 cm width x 26.4 cm depth(24.6 in x 17.8 in x 10.4 in) 48.3 cm height x 19.2 cm width x 48.0 cm depth(19.0 in x 7.6 in x 18.9 in)WEIGHT 16.4 kg (36.2lb) CertificationsSAFETY CERTIFICATIONS CE, ETL listed; Conforms to UL Std. 61010-1Certified to CSA C22.2 No. 61010-1ISO?Any mention in addition to or instead of for CB Scheme.IP RATING IP 45
.................................SIEVERS M9 AND M9e PORTABLE TOC ANALYZERSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201435 of 211Sievers M5310 C Portable TOC Analyzer SamplingLINEAR RANGE 0.03 ppb – 50 ppm TOCPRECISION <1% of RSDACCURACY ±2% or ±0.5 ppb, whichever is greaterANALYSIS TIME 2 minSAMPLE FLOW RATE (NOMINAL)Analysis mode: 0.5 mL/minFast flush (between samples): 2.0 mL/min(optional) Turbo mode: 1.0 mL/minREQUIRED SAMPLE LINE FLOW RATE On-line mode: 50 mL - 300 mL/minSAMPLE TEMPERATURE 1 °C to 95 °C via iOS9 (withstands short-term steam exposure)AMBIENT TEMPERATURE 10 °C to 40 °CSAMPLE PRESSURE (IN IOS SYSTEM)Up to 250 psigCALIBRATION STABILITY Typically stable for 12 monthsCHEMICAL REAGENTS GE Analytical Instruments pre-packaged reagents: 300 mL acid and300 mL or 150 mL oxidizerStage II Sample Conductivity (Optional)RAW CONDUCTIVITY RANGE 0.01 - 35 S/cmCONDUCTIVITY ACCURACY xCONDUCTIVITY PRECISION XMAXIMUM SAMPLE CONDUCTIVITY XElectronicsPOWER REQUIREMENTS 100-240 ±10% VAC, 100 VA, 50/60 HzDO NOT CHANGEFUSES Replace with same type and size. T1.6 A, 250 VAC (SloBlo), size 5 x 20 mm (appliance inlet)OUTPUTS 4–20 mA, two alarms, binary output, Ethernet portINSTALLATION/OVER-VOLTAGE CATEGORY II RFID Radio tracking and controlling of reagents; Meets Part 15 of the FCCRules & Industry Canada license (exempt RSS standards)9. If the sample temperature and pressure are above 60° C and 100 psi, the Sievers M9 and M9e On-Line TOC Analyzers model with the Kymar or PVDF iOS is required.
SYSTEM SPECIFICATIONSChapter 2Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201436 of 211EnvironmentNORMAL OPERATING ENVIRONMENT Intended for indoor use ONLYMAXIMUM RELATIVE HUMIDITY Up to 95%, non-condensingMAXIMUM ALTITUDE 3,000 m (9,843 ft)POLLUTION DEGREE 2DISPLAY Color, touch-sensitive WVGA LCDSIZE 35.6 cm height x 22.3 cm width x 46.5 cm depth(14.0 in x 8.8 in x 18.3 in) 62.4 cm height x 45.2 cm width x 26.4 cm depth(24.6 in x 17.8 in x 10.4 in) 48.3 cm height x 19.2 cm width x 48.0 cm depth(19.0 in x 7.6 in x 18.9 in)WEIGHT 16.4 kg (36.2lb) CertificationsSAFETY CERTIFICATIONS CE, ETL listed; Conforms to UL Std. 61010-1Certified to CSA C22.2 No. 61010-1ISO?Any mention in addition to or instead of for CB Scheme?IP RATING IP 45
3..............................................Sievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201437 of 211SYSTEM OVERVIEWThis chapter provides an overview of the Sievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer system, including:•The Sample Flow Path•The Analyzer’s Major Subsystems — Sample Inlet SystemInorganic Carbon Remover (ICR), Chemical Reagent System, Oxidizer Reactor, CO2 Measurement Module, Fluidics Module, and Electronics•Optional Configurations — Sample Conductivity, Two-Stream Inlet, Inorganic Carbon Remover (ICR), and Turbo Operation Mode•Optional Accessories — Point-of-Service (POS) Printer, GE Autosampler and Sievers DataPro Software, and DataGuard Software
SYSTEM OVERVIEWChapter 3Sievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201438 of 211THE SAMPLE FLOW PATHThis section provides an overview of the sample’s path through the Sievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer. As you read about the details of the process, you may find it helpful to periodically refer to Figure 1: Analyzer Schematic—On-Line and Portable Models and Figure 2: Analyzer Schematic—Laboratory ModelFigure 2: Analyzer Schematic—Laboratory Model, Figure 1: Analyzer Schematic—On-Line and Portable ModelsPLACEHOLDER FROM 500
.................................THE SAMPLE FLOW PATHSievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201439 of 211Figure 2: Analyzer Schematic—Laboratory ModelThe process begins by introducing sample into the Analyzer with a one or two-stream1 sample-line and inlet connection(s) for continuous monitoring with ALL models (On-Line, Lab, and Portable) of the Sievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer. Or, you can introduce discrete grab samples with one of the following model-specific sampling methods.•On-Line TOC Analyzer — Measure discrete grab samples by inserting a 40 mL sample vial into the iOS System, located on the right side of the instrument. You can also set up the On-Line TOC Analyzer for single grab samples to accommodate spot checks of TOC samples from various points in the water system. With this method, you will use a sipper tube2 and laboratory glassware (such as a flask or beaker).•Laboratory TOC Analyzer — Measure discrete grab samples by inserting a 40 mL sample vial into the vial port located on the front of the Analyzer, or by using the optional GE Autosampler to introduce samples from up to 120 vials. To establish the sample flow path, connect the needle’s attached sample tubing to the sample inlet port located on the back of the Analyzer. The Laboratory TOC Analyzer also accommodates single grab samples for spot checks of TOC samples from various points in the water system. With this method, you will use a sipper tube2 and laboratory glassware (such as a flask or beaker).•Portable TOC Analyzer — Measure discrete grab samples by inserting a 40 mL sample vial into the iOS System, or via a sipper tube bypassing the iOS System. You can also use the optional GE Autosampler to introduce samples from up to 120 vials. To establish the 1. A two-stream configuration is available as an option with the Sievers M5310 C TOC Analyzer.2. The preferred methods for sampling are on-line and grab samples using the iOS system or vial port. Testing using a grab method with a sipper tube and laboratory glassware shows additional risk for contamination by sample preparation and handling. Contamination can be minimized with this method by using good sampling techniques including covering the open portion of the glassware, sampling and analyzing in the absence of volatile organics, and using scrupulously clean glassware. For additional information, reference GE Analytical Instruments, “On-Line or Grab Sample Monitoring,” Application Note 300 00001 Rev. A, 2005.ADD GRAPHIC
SYSTEM OVERVIEWChapter 3Sievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201440 of 211sample flow path, connect the needle’s attached sample tubing to the sample inlet port located to the left of the iOS.As with the other models, you can set up the Portable TOC Analyzer for single grab samples to accommodate spot checks of TOC samples from various points in the water system. With this method, you will use a sipper tube2 and laboratory glassware (such as a flask or beaker).For step-by-step setup instructions, refer to “Sampling Using a Sipper Tube” on page 114.After sample is introduced into the Analyzer, 6M phosphoric acid (H3PO4) is injected into the sample3 at the programmed flow rate to reduce sample pH to 2. This allows for accurate measurement of TC and IC.An (optional) Inorganic Carbon Remover (ICR) may be used to remove excess IC by vacuum degasification. See “Inorganic Carbon Remover (ICR)” on page 45.See “Inorganic Carbon Remover (ICR)” on page 61 for more information on this optional configuration. If the ICR unit is utilized, additional acid may need to be added to the sample to remove excess IC by the ICR. The acidified sample is then combined4 with 15% ammonium persulfate [(NH4)2S2O8] to promote oxidation of the organics.5 The sample travels through a mixing coil and on to a stream splitter.The stream splitter divides the sample stream into two equal, but separate flows. One stream is processed for the measurement of IC. The other is processed for measurement of TC.The TC stream passes to an oxidation reactor where the sample is exposed to UV light. The combination of UV light and (depending on the application) persulfate oxidizes the organic compounds in the sample, converting carbon to CO2.The reactor is a spiral quartz tube wrapped around the UV lamp. The UV lamp emits light at 185 nm and 254 nm resulting in the formation of powerful chemical oxidizing agents in the form of hydroxyl radicals produced by the photolysis of water (equation 1) and persulfate (equations 2 and 3):H2O + hv (185 nm) →OH + H (1)S2O8-2 + hn (254 nm) →2 SO4-(2)SO4- + H2O →SO4- + OH (3)3. The phosphoric acid is referred to as Acid in the user interface.4. Depending on the application, some samples do NOT require the addition of persulfate. For example, when the TOC concentration in the sample is low (<1 ppm), complete oxidation can usually be achieved using only the hydroxyl radicals from the photolysis of water.5. The ammonium persulfate is referred to as Oxidizer in the user interface.
.................................THE SAMPLE FLOW PATHSievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201441 of 211The hydroxyl radicals (OH) will completely oxidize organic compounds, converting the carbon atoms of the organic compound into CO2 (equation 4):Organic Compounds + OH →CO2 + H2O(4)When the TOC concentration in the sample is low (<1 ppm), complete oxidation can usually be achieved using only the hydroxyl radicals from the photolysis of water (example 1) without the addition of persulfate.The IC stream passes through a delay coil, which is designed to make the total transit time of the IC stream through the Analyzer the same as the transit time of the TC stream through the Analyzer.CO2 Transfer ModulesFigure 3: Sample Flow through the CO2 Transfer ModuleWhen the TC stream exits the oxidation reactor and the IC stream exits the delay coil, each stream moves to the CO2 Transfer Module, and through its respective channel. The CO2 Transfer Module is our patented Sievers Selective Membrane Conductometric design, utilizing a gas-permeable membrane that allows the transfer of CO2 across the membrane. A graphic depiction of this technology representative for either the TC or IC channel is shown in Figure 3: Sample Flow through the CO2 Transfer Module on page 41. NOTE: If you are reading this manual in an Adobe® PDF® format, clickthe Figure 3 graphic to activate a flow animation, and click any of thenumbered processes for more information.The membrane for each respective channel separates the sample side of the Analyzer from the DI side. The DI side of the Analyzer is a closed loop, and consists of two conductivity cells (one for the TC stream and one for the IC stream), a DI water pump, a DI water reservoir, and an ion exchange resin bed.
SYSTEM OVERVIEWChapter 3Sievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201442 of 211CO2 from the sample passes through the membrane into the DI water supplied by the integrated DI Loop, while interfering compounds and other oxidation by-products are blocked by the membrane and remain on the sample side. The CO2 forms carbonic acid upon reaction with water, and the carbonic acid disassociates into hydrogen ions and bicarbonate ions (equation 5):CO2 + H2O ↔ H2CO3 ↔ H+ + HCO3-(5)DI water is continuously pumped through the DI side of the Analyzer, collecting the H+ and HCO3- ions and H2CO3 and CO2 molecules from the CO2 transfer modules, delivering it to the conductivity cell for measurement. Then the ion exchange resin removes the HCO3- and other ions. The water is then pumped back to the CO2 transfer module to repeat the sequence.The TC and IC conductivity cells each contain a thermistor, and all conductivity readings are temperature corrected. The CO2 from the TC and IC sample streams are measured by the respective conductivity cells, and the conductivity readings are used to calculate the concentration of TC and IC. After the values are measured, TOC is calculated as the difference (equation 6):TOC = TC - IC (6)THE ANALYZER’S MAJOR SUBSYSTEMSWith the sample flow path (presented in the previous section) in mind, let’s take a closer look inside the Analyzer. The Sievers M9 and M9eTOC Analyzers consistSievers M5310 C TOC Analyzer consists of sixseven major subsystems. Each subsystem is discussed briefly in this section.Figure 4: The Analyzer’s Major Subsystems
.................................THE ANALYZER’S MAJOR SUBSYSTEMSSievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201443 of 211 Figure 5: The Analyzer’s Major SubsystemsSample Inlet SystemThe sample inlet system introduces continuous sample into the Analyzer using a dual pump system and a one or two-stream sample line connection to the Analyzer’s sample inlet port(s). The two-stream inlet option enables efficient sampling of two independent sample sources, without the need to alter the initial inlet setup. This optional configuration is discussed in more detail in the "Optional Configurations"section, under “Two-Stream Inlet” on page 60.The Analyzer introduces discrete grab samples from the Integrated On-Line Sampling (iOS) System in both the On-Line and Portable TOC Analyzers, and from the vial port on the Laboratory TOC Analyzer. You can also use the GE Autosampler system to automatically introduce up to 120 vial samples from the unit’s vial rack(s) into the sample inlet port on the Laboratory and Portable TOC Analyzers. This optional system for high-volume laboratory applications is described in the section, “GE Autosampler and Sievers DataPro Software” on page 62.All Analyzer models also accommodate single grab samples for spot checks of TOC samples from various points in the water system using a sipper tube2 (on page 39) and laboratory glassware. A summary of available inlet systems by Analyzer model is included in the following Table 1.TABLE 1: SAMPLE INLET SYSTEMS BY ANALYZER MODELAvailable Inlet Systems Analyzer ModelContinuous On-Line Sampling On-Line and Portable TOC AnalyzersOn-Line Sample (iOS) System On-Line and Portable TOC Analyzers
SYSTEM OVERVIEWChapter 3Sievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201444 of 211For additional information on the optional iOS and GE Autosampler, see the following sections, "The iOS System" and “GE Autosampler and Sievers DataPro Software” on page 62“GE Autosampler and Sievers DataPro Software” on page 62.THE IOS SYSTEMThe patented Integrated On-Line Sampling (iOS) System enables easy introduction of external samples and standards. Simply stop analysis, slide the iOS System door open to the left, wait 30 seconds for sample to drain from the iOS System, and then insert a 40-mL vial containing sample or a standard. Grab Sampling by Vial Port Laboratory TOC AnalyzerGrab Sampling by Sipper Tube On-Line, Laboratory, and Portable Analyzers GE Autosampler Laboratory and Portable TOC AnalyzersTABLE 1: SAMPLE INLET SYSTEMS BY ANALYZER MODELAvailable Inlet Systems Analyzer Model
.................................THE ANALYZER’S MAJOR SUBSYSTEMSSievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201445 of 211You can conveniently switch between on-line sampling and discrete sampling using the iOS. After the initial iOS setup, you do NOT need to change the configuration to analyze a standard with the iOS System. This unique feature allows you to introduce calibration, validation, and system suitability standards directly without removing the instrument from the continuous sample source or changing the sample inlet configuration. The Analyzer automatically shuts off on-line water flow when it detects that the iOS door is closed and/or a vial is inserted into the iOS.The iOS operational steps are minimal and initial setup is brief, as described in “To sample using the iOS” on page 113 and “To connect the inlet tubing to the iOS” on page 94.For step-by-step instructions on spot checking TOC samples from other locations in the water system using a sipper tube2 (on page 39) and laboratory glassware (such as a beaker or flask), see “Grab Sample Installation — From a Sampling Container” on page 114.Inorganic Carbon Remover (ICR)To reduce high levels of inorganic carbon (IC) in sample streams with high IC/TOC ratios (such as raw surface and ground waters) before measurement, the Analyzer contains an inorganic carbon remover (ICR) for more accurate results. Typically, if the TOC is 10% or less of the IC concentration, the ICR is required. For example, if the IC is 1 ppm, then use the ICR if the TOC is 100 ppb or less for accurate TOC measurements. The Analyzer will calculate the TOC/IC ratio for each measurement. If this ratio is less than 0.1, the Analyzer issues a Warning message on the Touch Panel screen, which can also be viewed on the Warnings and Errors list. You can bypass the ICR at any time, as needed, using the ICR On/Off setting located on the Modify On-Line Method screen.The ICR consists of a Teflon® degassing module and a vacuum pump. In the sampling process, the Analyzer introduces the sample flow into the Analyzer and acid is added to the sample. The stream is then directed through the ICR’s Teflon degasser before continuing on through the Analyzer’s sample flow path. (See “The Sample Flow Path” on page 38.) Carbon PHOTO Placeholder
SYSTEM OVERVIEWChapter 3Sievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201446 of 211dioxide produced from the reaction of bicarbonate and carbonate with acid is removed from the sample stream by the vacuum. The sample is then returned to the Analyzer and is directed by the stream splitter for measurement of IC and TC. Approximately 98% of the IC is removed at concentrations up to 25 ppm. Chemical Reagent SystemPhosphoric acid (H3PO4) and ammonium persulfate [(NH4)2S2O8], referred to respectively as Acid and Oxidizer in the User Interface and this manual, are introduced as reagents into the sample at different points in the flow path. The Acid brings about a chemical reaction to reduce the sample pH to 2, which is needed in order to allow for the accurate measurement of TC and IC.The acidified sample is then combined with the Oxidizer to create oxidation of the organics, to promote accurate TC and IC measurements. The sample then goes through a mixing coil and on to a stream splitter, where it is divided into two separate flows for TC and IC processing. Separate cartridge reservoirs hold the Acid and Oxidizer inside the Analyzer on the fluidics (right) side. Each reservoir is connected to a needle-and-syringe pump mechanism. The Analyzer activates each syringe pump at pre-programmed intervals and lengths (using the Auto Reagent setting) to dispense the optimal amount of Acid and Oxidizer into the sample.The modular assembly of the chemical reagent system is designed for easy removal and replacement of the reagent cartridges. See “Replacing Consumable Items” on page 164.Oxidizer ReactorPHOTO PlaceholderPHOTO Placeholder
.................................THE ANALYZER’S MAJOR SUBSYSTEMSSievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201447 of 211After the acidified sample is combined with Oxidizer, the TC sample passes into the oxidizer reactor, a spiral quartz tube wrapped around an ultraviolet (UV) lamp. The UV lamp emits light at 185 nm and 254 nm, and this exposure along with the persulfate6 utilizes the UV-promoted photolysis of water to convert carbon to CO2.The UV lamp is a consumable item and replacement is recommended every six months to ensure the intensity of the beam. See “Replacing the UV Lamp” on page 165.CO2 Measurement ModuleAfter the TC stream passes the oxidizer reactor, and the IC stream simultaneously exits the delay coil, each stream moves to the CO2 measurement module. The CO2 measurement module consists of a:•Our patented CO2 Transfer manifold, a fluidics block with separate TC and IC channels to the gas-permeable membrane that allows the transfer of CO2•Two quartz conductivity cells, one for the TC channel and the other for the IC channel•Dual Conductivity Signal Processor (CSP), processing data from each TC and IC channelThe membrane separates the sample side of the Analyzer from the DI side. In each TC and IC stream channel, CO2 from the sample passes freely through the membrane to the DI side, while interfering compounds and oxidation by-products are blocked by the membrane and remain on the sample side, thus eliminating interference from non-carbon based compounds and byproducts. The CO2 that has passed through to the DI side reacts with water supplied by the integrated DI Loop to form carbonic acid. The carbonic acid disassociates into hydrogen ions and bicarbonate ions. The concentration of CO2 and ions increases until they both approach equilibrium on both sides of the membrane.6. When the TOC concentration in the sample is low (<1 ppm), complete oxidation can usually be achieved using only the hydroxyl radicals from the photolysis of water without the addition of persulfate.PHOTO Placeholder
SYSTEM OVERVIEWChapter 3Sievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201448 of 211The Analyzer opens the valve of each TC and IC channel in the CO2 transfer manifold, and CO2 and ions transfer to the respective conductivity cell. Each conductivity cell contains a thermistor, which the Analyzer uses to temperature-correct all conductivity readings. The conductivity readings are then used to calculate the concentration of TC and IC. TOC is calculated as the difference:TOC = TC - ICThe Analyzer pumps the sample remaining on the sample side out through the waste outlet. The water on the DI side continues through the DI loop, as described in the following section.Fluidics ModuleThe fluidics module subsystem contains the:•TC and IC sample pumps•DI water loop•DI water reservoir•Ion exchange resin column•Circulation pumpA dual-pump system (one for TC flow and one for IC) draws sample through the sample flow path in the Analyzer. (See “The Sample Flow Path” on page 38.)An enclosed DI water loop serves to deliver deionized water to the CO2 transfer module. The circulation pump continuously pushes deionized water from the DI water reservoir in a continuous loop into the CO2 transfer manifold (and through both the inside TC and IC channels), and then out the manifold to the related conductivity cell for measurement. The water continues on the loop path to the ion exchange resin column where CO2 and the ions are removed, producing freshly deionized water. This is then fed back into the DI side of the CO2 transfer module. And, the loop is repeated on a continuous basis while the Analyzer is running (whether or not you are sampling).
.................................THE ANALYZER’S MAJOR SUBSYSTEMSSievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201449 of 211ElectronicsFigure 6: Electronics Block Diagram — Sievers M9 and M9eTOC AnalyzersFigure 7: Sievers M5310 C TOC AnalyzerThe electronics subsystem of the Sievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer includes:•Electronic Controller and Processing Boards•Ethernet Port•USB Ports•Touch Panel Display•Radio Frequency ID (RFID)ELECTRONIC CONTROLLER AND PROCESSING BOARDSThe Analyzer controls all operations using six electronic boards designed with microcontrollers and microprocessors, as shown in Figure 6: Electronics Block Diagram — Sievers M9 and M9eTOC Analyzers. A brief description of the following electronic controller and processing boards is included in this section:
SYSTEM OVERVIEWChapter 3Sievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201450 of 211•Data/User Controller (DUC) Board•Instrument Controller Board•Fluidics Controller Board•Dual Cell Signal Processor (DCSP) Board•II/O Controller Board•Single-Cell Signal Processor BoardDATA/USER CONTROLLER (DUC) BOARD Figure 8: The Data/User Controller (DUC) BoardThe Analyzer uses the Data/User Controller (DUC) board to control the user interface, display, and data processing operations using a 64-bit microprocessor running at 1 GHz. The microprocessor has 1 GB of onboard Dynamic Random Access Memory (DRAM) and two card slots for USB flash memory cards. One slot holds a 1 GB program memory card and the other holds a 1 GB data memory card.The DUC board communicates with external devices and systems over Ethernet and USB serial interfaces. This board also controls the optional GE Autosampler and a GEAI-supported Point of Service (POS) printer.
.................................THE ANALYZER’S MAJOR SUBSYSTEMSSievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201451 of 211The DUC board controls power to the rest of the electronics in the Analyzer and communicates to the Instrument Control Board over a full-speed USB serial port.INSTRUMENT CONTROLLER BOARDFigure 9: The Instrument Controller BoardThe Analyzer uses the Instrument Controller Board to distribute power and communicate to the other circuit boards in the Analyzer. Power is distributed over a ribbon cable and communications are sent to the other circuit boards over a dual serial CAN bus.The Instrument Controller board also provides power to the UV lamp, monitors the output from the UV lamp, controls and monitors the (optional) Inorganic Carbon Remover (ICR), controls and monitors the reagent syringes, manages the Radio Frequency ID (RFID) tags on the reagent containers, monitors the vial door position, drives and monitors the vial door LED, and controls and monitors the sample valve.This board also contains connection ports for both Ethernet and USB. These ports are positioned for convenient access from outside the Analyzer, as follows:
SYSTEM OVERVIEWChapter 3Sievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201452 of 211Figure 10: Ethernet and USB Port LocationsUSB PortsThere are two types of USB ports:•One Device Port — This USB port is ONLY used for connecting a computer when operating with Sievers DataPro Software.•Host Port — This USB port is used for connecting a GE Autosampler, printer, or portable USB memory device.)For additional information, please refer to "USB Device Port" and “USB Host Ports” on page 91 in the "Installation" chapter in this manual.Ethernet PortThe Instrument Controller board also contains the Ethernet connection port. You can export historical data from the Analyzer to your computer or computer network via this Ethernet port, and using an Ethernet cable and the Modbus communications protocol. For more information on the types of data available for export, as well how-to instructions, refer to “Installing an Ethernet Connection” on page 89 and“Using the Ethernet Connection and Modbus” on page 149.PHOTO Placeholder
.................................THE ANALYZER’S MAJOR SUBSYSTEMSSievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201453 of 211FLUIDICS CONTROLLER BOARDFigure 11: The Fluidics Controller BoardThe Fluidics Controller Board is used to control and monitor the sample pumps and the sample valve. This board also monitors sample flow, the IOS flow switches, and the iOS vial door position.
SYSTEM OVERVIEWChapter 3Sievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201454 of 211DUAL CELL SIGNAL PROCESSOR (DCSP) BOARDFigure 12: The Dual Cell Signal Processor (DCSP) BoardThe Analyzer uses the Dual Cell Signal Processor (DCSP) Board to control and monitor the flow valve, measure the conductivity of the water in the IC and TC cells, and monitor the temperature of both cells and the manifold.
.................................THE ANALYZER’S MAJOR SUBSYSTEMSSievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201455 of 211I/O CONTROLLER BOARD(On-Line and Portable TOC Analyzers Only) Figure 13: The I/O Controller BoardThe I/O Board is an optional configuration for On-Line and Portable TOC Analyzers. This board provides three 4-20 mA current loop analog outputs, six alarm relay outputs, and one binary input to remotely control the start and stop of analysis.
SYSTEM OVERVIEWChapter 3Sievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201456 of 211The three 4-20 mA current loop analog outputs are independently isolated, so they may be connected to different remote locations [(such as multiple industrial control systems (ICS)] without causing inadvertent ground loops.SINGLE-CELL SIGNAL PROCESSOR BOARD(Laboratory and Portable TOC Analyzers Only)Figure 14: The Single-Cell Signal Processor BoardThe Single Cell Signal Processor (SCSP) Board is available as an optional configuration in Laboratory and Portable TOC Analyzers. This board measures the conductivity of the incoming water sample.
.................................THE ANALYZER’S MAJOR SUBSYSTEMSSievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201457 of 211Touch Panel DisplayThe Analyzer has a 7-in. diagonal touch panel display. This color touch panel consists of a Wide Video Graphics Array (WVGA) liquid crystal display (LCD), with a light emitting diode (LED) backlight and a resistive-touch panel. Use this touchscreen display to navigate through the Analyzer’s intuitive menu-driven interface. Simply touch the screen with your finger in a touch-and-lift motion. You can operate the resistive-touch panel even when you are wearing laboratory gloves.Radio Frequency ID (RFID)The Analyzer uses a Radio Frequency ID (RFID) antenna to obtain and track data from each Acid and Oxidizer reservoir cartridge. The antenna is located on the inside floor of the Analyzer near the front of the syringe assemblies. The RFID collects the following information from the labels on reagent cartridges sold by GE Analytical Instruments7:•Reagent type (Acid or Oxidizer)•Lot number•Part number•Initial and remaining volume•Manufactured date•Expiration dateThe Analyzer uses this information to automatically track the remaining volume, based on the number of syringe extractions. You can view the remaining Acid and Oxidizer level indicators on the Home screen. (See “Viewing Consumables Levels” on page 128.) The Analyzer also reminds you to replace each reagent reservoir by displaying a Warning message at the top of the screen when each reagent level reaches 10% of its original capacity, and an Error message when the reservoir reaches 5% capacity. For additional information, refer to “Warning and Error Messages” on page 167.7. GE Analytical Instruments directs operators to ONLY use reagents manufactured and sold by GE Analytical Instruments in the Analyzer, as these reagents and their cartridges have been designed for optimal operation and sampling results. The RFID does NOT read data from any other manufacturer’s label, and therefore will not be able to automatically track expiration volumes or other data. If using other manufacturer’s reagents, you can manually enter the installation date on the Consumables tab on the Maintenance screen, however, GE Analytical Instruments cannot guarantee optimal Analyzer operation or sampling results.
SYSTEM OVERVIEWChapter 3Sievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201458 of 211WARNINGSChanges or modifications not expressly approved by the party responsiblefor compliance could void the user's authority to operate the equipment.This device complies with Part 15 of the FCC Rules & Industry Canadalicense-exempt RSS standards. Operation is subject to the following twoconditions: (1) This device may not cause harmful interference, and (2) This device must accept any interference received, including interferencethat may cause undesired operation.The RFID antenna is a Part 15 & RSS-210 - Class A digital device: This equipment has been tested and found to comply with the limits for aClass A digital device, pursuant to part 15 of the FCC Rules. These limits aredesigned to provide reasonable protection against harmful interferencewhen the equipment is operated in a commercial environment. Thisequipment generates, uses, and can radiate radio frequency energy and, ifnot installed and used in accordance with the instruction manual, maycause harmful interference to radio communications. Operation of thisequipment in a residential area is likely to cause harmful interference inwhich case the user will be required to correct the interference at his ownexpense.This equipment complies with FCC electromagnetic radiation exposurelimits set forth for an uncontrolled environment. This equipment should beinstalled and operated with a minimum separation distance of 20cm (7 in.)between the RFID antenna and your body. The antenna is located on theinside floor of the Analyzer near the front of the syringe assemblies.
.................................OPTIONAL CONFIGURATIONSSievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201459 of 211OPTIONAL CONFIGURATIONSThe following optional configurations and accessories (including software) are available for the Sievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer:Configurations•Sample Conductivity •Two-Stream Inlet•Inorganic Carbon Remover (ICR)AVERTISSEMENTLes changements ou modifications à la radio RFID non explicitementapprouvés par la partie responsable de la conformité peuvent annulerl'autorité de l'utilisateur à utiliser l'équipement.Cet appareil est conforme à la Partie 15 de la réglementation FCC et desnormes RSS exemptes de licence d'Industry Canada. Le fonctionnementest assujetti aux deux conditions suivantes :(1) Cet appareil ne peut pas provoquer d'interférences nocives, et(2) Cet appareil doit accepter toute interférence reçue, y comprisl'interférence qui peut provoquer un fonctionnement indésirable.L'antenne RFID est un appareil digital conforme à la partie 15 et RSS-210 - Classe A : Cet appareil a été testé et a été trouvé conforme avecles limites d'un appareil digital de classe A, selon la partie 15 desnormes FCC. Ces limites sont conçues pour fournir une protectionraisonnable contre l'interférence nocive lorsque l'appareil fonctionnedans un environnement commercial. Cet appareil produit, utilise et peutémettre de l'énergie de fréquence radio et, s'il n'est pas installé et utiliséselon le manuel d'instruction, il peut provoquer une interférence nociveaux communications radio. Le fonctionnement de cet appareil dansune zone résidentielle peut probablement provoquer des interférencesnocives et, dans ce cas, l'utilisateur devra corriger l'interférence à sespropres frais.Cet appareil est conforme aux limites d'exposition de radiationélectromagnétique FCC établies pour un environnement non contrôlé.Cet appareil doit être installé et utilisé avec une distance de séparationminimum de 20cm (7 pouces) entre l'antenne RFID et le corps.L'antenne est située à l'intérieur du fond de l'analyseur à proximité de lapartie avant de la seringue.
SYSTEM OVERVIEWChapter 3Sievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201460 of 211•Turbo Operation ModeAccessories (including software)•Printer•GE Autosampler with Sievers DataPro Software•Sievers DataGuard Software•DataGuard Software for DataPro•Sievers DataGuard Software for M-Series AnalyzersSample Conductivity(Laboratory and Portable TOC Analyzers Only)The Sievers M9 and M9e Laboratory and Portable AnalyzersSievers M5310 C Laboratory and Portable TOC Analyzers can be configured to include a conductivity cell to measure and report the amount of conductivity in your samples. The conductivity cell is located at the beginning of the IC sample flow path and can detect a raw conductivity range between 0.01 - 35 S/cm. Pharmaceutical customers will find this range to meet USP Chapter <645> conductivity measurement. For additional conductivity specifications, refer to Chapter 2, "02-00_System Specifications.fm." Two-Stream Inlet(On-Line and Portable TOC Analyzers Only) The Sievers M5310 C Laboratory and Portable TOC Analyzers are available with a two-stream sample line connection to the Analyzer’s sample inlet port(s). The two-stream inlet option enables efficient sampling of two independent sample sources, without the need to alter the initial inlet setup. Just select one of the two streams to sample at a time using the Setup screen, and run the sample analysis for this stream. You can save one or more methods for Stream 1 and one or more methods for Stream 2 (each with unique settings) to use again. You can then easily switch between streams by just selecting the stream and method, and without having to re-plumbing the inlet.
.................................OPTIONAL ACCESSORIESSievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201461 of 211Inorganic Carbon Remover (ICR)To reduce high levels of inorganic carbon (IC) in sample streams with high IC/TOC ratios before measurement, GE Analytical Instruments offers an optional Analyzer configuration containing an inorganic carbon remover (ICR) for more accurate results. Typically, if the TOC is 10% or less of the IC concentration, the ICR is required. For example, if the IC is 1 ppm, then use the ICR if the TOC is 100 ppb or less for accurate TOC measurements. The Analyzer will calculate the TOC/IC ratio for each measurement. If this ratio is less than 0.1, the Analyzer issues a Warning message on the Touch Panel screen, which can also be viewed on the Warnings and Errors list. You can bypass the ICR at any time, as needed, using the ICR On/Off setting located on the Modify On-Line Method screen.The ICR consists of a Teflon® degassing module, a vacuum pump, and a carbon-and-soda lime trap. In the sampling process, the Analyzer introduces the sample flow into the Analyzer and acid is added to the sample as usual. The stream is then directed through the ICR’s Teflon degasser. Carbon dioxide produced from the reaction of bicarbonate and carbonate with acid is removed from the sample stream by the vacuum. The sample is then returned to the Analyzer and is directed by the stream splitter for measurement of IC and TC. Approximately 98% of the IC is removed at concentrations up to 25 ppm. The activated carbon-and-soda lime trap prevents contamination of the sample stream from organic compounds and CO2 in the atmosphere.Turbo Operation ModeA Turbo Sampling Mode is available as an optional configuration to Sievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer. This turbo mode is well suited to a wide range of reclaim water applications where quick process control feedback is required. The Turbo feature provides an expanded range of 0.20–10,000 ppb. TOC, IC, and TC measurements are updated every four seconds, assuring that even short-lived excursions are captured. OPTIONAL ACCESSORIESPoint-of-Service (POS) PrinterThe Analyzer is designed to work with the following USB point-of-service (POS) printers. Each is available as an optional accessory directly from GE Analytical Instruments:•Bixolon/Samsung SRP-275•Citizen CD-S500A•Epson TM-722OD
SYSTEM OVERVIEWChapter 3Sievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201462 of 211GE Autosampler and Sievers DataPro Software(Laboratory and Portable TOC Analyzers Only)Any M9e electronics industry application?The GE Autosampler system can be used to automatically transfer up to 120 vial samples from the unit’s vial rack(s) into the sample inlet port on a Sievers MC9 and MC9e Laboratory or Portable TOC AnalyzerSievers M5310 C Laboratory or Portable TOC Analyzer. Sampling results are displayed and stored on your computer via the Sievers DataPro Software.This optional system for high-volume laboratory applications consists of the following:•GE Autosampler•Sievers DataPro Software, running on a your computer with a Windows® Operating Systems [Windows XP (SP2 or higher), Windows 7, Windows 8, Windows Server 2008, or Windows Server 2012]7/8 Vamsi is providing which systems are supported on both 32-bit and 64-bit systems.•Sievers MC9 and MC9e Laboratory or Portable TOC Analyzer or Sievers M5310 C Laboratory or Portable TOC Analyzer•Printer (optional)SIEVERS DATAPRO SOFTWARESievers DataPro Software integrates the GE Autosampler with Sievers M9 and M9eTOC Analyzersthe Sievers M5310 C TOC Analyzer, giving you the ability to operate the GE Autosampler with up to two Analyzers. The software runs on the following Microsoft operating systems with a familiar Windows interface design:•Windows XP (SP2 or higher)•Windows 7•Windows 8•Windows Server 2008•Windows Server 20127/8 Vamsi is providing which systems are supported on both 32-bit and 64-bit systems.
.................................OPTIONAL ACCESSORIESSievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201463 of 211Automated User and System ProtocolsYou can use the Sievers DataPro Software to create automated customer user protocols and summary reports for running sample analyses. The following ready-to-use system protocols are also included in the software: •Single-Point Calibration (250 ppb M9 only-Is DP used by M9e market?), 1 ppm, 5 ppm, 25 ppm, 50 ppm)•Turbo Single-Point Calibration•Multi-Point Calibration•Single-Point Verification (250 ppb,1 ppm, 5 ppm, 10 ppm, 25 ppm, 50 ppm)•Turbo Single-Point Verification•System Suitability•Autoreagent Calibration (not in M5310 C?)•Autoreagent Verification•TC/IC Cell Conductivity Autozero•Accuracy/Precision (250 ppb, 1 ppm, 2 ppm, 5 ppm, 25 ppm, 50 ppm)•Autoreagent VerificationAdditionally, the following system protocols for Performance Qualification (PQ) activities are available with the optional Sievers M9 TOC Analyzers Validation Package, Volume II:•Accuracy and Precision (1 ppm, 2 ppm, 5 ppm, 10 ppm, 25 ppm, 50 ppm)•Linearity•Robustness•Specificity•JP•LOD/LOQ??•Validation?SECURE DATATo ensure the integrity of all protocol results, ALL result files are fixed and cannot be altered. You can then save the data to a network (or a static media such as CD or tape archive) to provide the secure environment required by the FDA.Sievers DataPro Software also supports 21 CFR Part 11 TOC Analyzer compliance by providing secure data, audit information, the ability to save results to a static media.
SYSTEM OVERVIEWChapter 3Sievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance Manual DLM 77000-01DLM 77100-01 EN Rev. A GE Analytical Instruments © 201464 of 211For additional information, refer to Sievers GE Autosampler Installation Guide and the Sievers M Series DataPro Software + DataGuard Software User Guide.DataGuard SoftwareSievers DataGuard Software for DataPro8 and Sievers DataGuard Software for M-Series Analyzers9 are available options offering a complete 21 CFR Part 11 TOC Analyzer compliance solution using the following:•Administratively controlled user-level security control•Electronic signatures that assign ownership to all controlled system actions•An audit trail system that records system changes including file creation, viewing, and modificationFor additional information, refer to the Sievers M Series DataPro Software + DataGuard Software User Guide.8. Sievers DataGuard Software for DataPro is compatible with Sievers Laboratory and Portable TOC Analyzers ONLY.9. Sievers DataGuard Software for M-Series Analyzers can be used directly with ALL? Laboratory and Portable TOC Analyzers in configurations not using a GE Autosampler.
4..............................................Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201465 of 2114INSTALLATIONOVERVIEWThis chapter provides installation instructions for the Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer, and applies to ALL models (On-Line, Laboratory, and Portable), except where noted. An interior overview diagram of each Analyzer model is provided for your reference in Chapter 8, "Maintenance." If you need additional assistance, contact GE Analytical Instruments Technical Support at 303.444-2009 or 888.245.2595. Technical Support in the United Kingdom is available at 44 (0) 161.864.6800. In other countries, visit www.geinstruments.com to locate your representative. Installation and training by a qualified service technician is also available. INSTALLATION INSTRUCTIONSPerform the following steps, in the listed order, to install and configure the Analyzer for operation.
INSTALLATIONChapter 4Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201466 of 211STEP 1: UNPACK AND INSPECT THE ANALYZERNOTE: Save ALL original packing materials! If you need to returnthe Analyzer now or in the future, you MUST pack it in theORIGINAL carton to ensure that no damage occurs duringshipment. Also, always insure the Analyzer in any returnshipments.Unpack the shipping carton(s) and verify that the shipment contains the following (Accessories Kits WIP):•Sievers M9 and M9e TOC Analyzers Operation and Maintenance Manual Sievers M5310 C TOC Analyzer Operation and Maintenance Manual•PVC tubing(On-Line and Portable TOC Analyzers Only) •Accessory Kit (Laboratory TOC Analyzer Only) •Teflon tubing, with fittings•Dispensing bottle (with attached filling fixture), and elbow fitting•Shut-off Fitting, 1/4”•C-flex tubing•1/4” Teflon tubing with in-line filter (GEAI or customer provided?)•Accessory Kit (On-Line and Portable TOC Analyzers Only) •Tubing with filter•Teflon tubing with fittings•Dispensing bottle (with attached DI reservoir filling fitting)•Shut-off fitting, 1/4”•C-flex tubingWarningsShipping boxes containing an Analyzer with built-in optionalcomponents may weigh over 40 lb—necessitating a two-personlift technique when handling. Such boxes are labeled with thiswarning, supporting OSHA standards intended to protectemployees from injury. We recommend that our customers use a two-person lift, andGE requires that ALL employees use this handling techniquewhen lifting items weighing over 40 lb.
.................................INSTALLATION INSTRUCTIONSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201467 of 211•1/4” Teflon tubing with in-line filter (GEAI or customer provided?)•Waste outlet fitting•Certificate of Calibration•DataGuard Activation key (optional)•Reagents carton (shipped separately)Additional Equipment RequirementsYou will also need to provide the following for the installation process:•ESD protection•3/4” OD plastic tubing for the waste outlet (in kit or customer supplied??)•Ethernet cable (optional)(On-Line TOC Analyzer Only)•Conduit connector (strain relief hubs) for power conduit wiring•Sealing washer for conduit connector•Ring terminal for AC conduit ground wire, 16-14 American Wire Gauge (AWG)•Insulated wire for AC power conduit1 (18-12 AWG), rated to 300 Volts. Strip length should be 8-9 mm (.33 in.) (Metallic conduit is required for the Analyzer to meet CE Mark electrical requirements.)•External circuit breaker or switch that disconnects both poles of the supply voltage, rated appropriately•Strain relief hub (conduit connector) and washer for I/O wiring•Analog (4-20 mA) recorder (optional)•Wire for 4-20 mA and alarm output (28-16 AWG), rated to 300 Volts(On-Line TOC Analyzer Only)•Mounting hardware to support the Analyzer — Mounting bolts should support four times the weight of the Analyzer [Total of 64.20 kg (141.50 lb)]. For more information, see “Step 3: Select a Location for the Analyzer.”(Portable TOC Analyzer Only) •Analog (4-20 mA) recorder (optional)1. Metallic conduit is required for the Analyzer to meet CE Mark electrical requirements.
INSTALLATIONChapter 4Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201468 of 211STEP 2: COMPLETE THE IDENTIFICATION RECORDSComplete the Identification Records information on page 4 by recording the Analyzer serial number and the date of installation. The serial number is located on the rear outside panel of Laboratory and Portable TOC Analyzers, and on the left outside panel of the On-Line TOC Analyzer.STEP 3: SELECT A LOCATION FOR THE ANALYZERThe enclosure for the On-Line TOC Analyzer is rated IP 45 to withstand the hazards of industrial process environments. The Portable TOC Analyzer is rated (a WIP) IP 21 for incidental exposure to water.Select a location away from direct sunlight and extreme temperatures. Avoid operating at elevated temperatures greater than 40 °C, which can prevent proper operation. Also avoid operating at temperatures lower than 10 °C, which can cause errors in the measurements. Make sure that the back of the Analyzer is protected from water spray to ensure the electrical and data connections remain dry.In addition to these general instructions, refer to the sections that follow for information pertaining to the specific model of your Analyzer.Sievers On-Line TOC AnalyzerSievers M9 or M9e On-Line TOC Analyzers are designed to be mounted on a wall or support stand. When selecting the location, mount the Analyzer so that the display screen is approximately at eye-level. For illustrations of required clearances, see Figures 15, 16, and 17. Allow a minimum of 5 cm clearance between the back of the Analyzer and the wall for heat dissipation. Plan for 30.5 cm of clearance on the sides, top, and bottom of the Analyzer for the plumbing and electrical connections. This clearance provides for the proper circulation for temperature and humidity control. You will need to provide hardware for mounting the Analyzer on a wall or instrument rack, as hardware should be selected based on site-specific circumstances. Choose mounting bolts to support four times the weight of the unit2 [total = 65.68 kg (144.80 lb)].2. 4 x 26.42 kg = 65.68 kg (4 x 35.2 lb = 144.80 lb)
.................................INSTALLATION INSTRUCTIONSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201469 of 211Figure 15: Required Installation Clearances — On-Line TOC Analyzer45017.7032712.952720.854621.54X 8.3 [305]12.0 [305]12.0 [305]12.0 [305]12.0 [450]17.7IN FRONT[50]2.0IN BACK
INSTALLATIONChapter 4Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201470 of 211Figure 16: Left Side Dimensions — On-Line TOC Analyzer1114.42068.144717.648519.121.8DATA INLETS41716.443717.2USB HOST PORTSUSB DEVICE PORT
.................................INSTALLATION INSTRUCTIONSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201471 of 211Figure 17: Right Side Dimensions — On-Line TOC AnalyzerSievers Laboratory and Portable TOC AnalyzersThe Analyzer is designed to be operated right-side up, resting on the rubber feet. Place the Analyzer on a clean, unobstructed surface that can accommodate the instrument’s dimensions and weight. For information regarding the specific specifications for your Analyzer model, refer to the corresponding model section under Chapter 2, "System Specifications." . Also, for proper heat dissipation, ensure that 16 cm is available at the rear and on both sides of the Analyzer.26510.450820.01977.841916.5893.522.921.8POWER INLET1566.11425.61/4" OD SWAGELOKINLET FITTING1/2" ID WASTE TUBE
INSTALLATIONChapter 4Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201472 of 211ON-LINE SAMPLINGFor on-line sampling in the Portable TOC Analyzer, place the Analyzer within 3 m of the sampling port or beaker to be tested. GE AUTOSAMPLER SYSTEMIf you will be using the Analyzer with an Autosampler system, allow approximately 1” of space between the GE Autosampler and Analyzer to ensure the proper functioning of both instruments. The front edge of the Autosampler should be parallel with the front edge of the Analyzer. Also, plan for room to accommodate a computer and (if applicable) a printer near the Analyzer and Autosampler. For more details, refer to the GE Autosampler Installation Guide.STEP 4: INSTALL POWER AND I/O CONTROL WIRINGThis section contains information about how to install power to the Analyzer. Both the Laboratory and Portable TOC Analyzers come supplied with power cords. The On-Line TOC Analyzer requires the installation of conduit to provide an external source of AC power, which is connected to the enclosure using a water-tight conduit connector. This type of electrical connection should be performed by a qualified electrician.This section also includes instructions for installing I/O control wiring, including: I/O controller board connections, 4-20 mA outputs, alarm outputs, and binary remote start and stop.The following step-by-step instructions are included for guiding the installation process:•Installing the Power Source•Power Cord Installation (Laboratory and Portable TOC Analyzers)•Power Conduit Installation (On-Line TOC Analyzer)•On and Off Powering Guidelines•Installing I/O Control WiringWarningTo avoid damaging the DI water pump, Do NOT turn theAnalyzer to On until Step 6: Install the DI Water System, after youhave completed Steps 5-7 to ensure the DI water reservoir isfilled and properly primed, as described in Step 6: Install the DIWater System.
.................................INSTALLATION INSTRUCTIONSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201473 of 211•I/O Controller Board Connections•4-20 mA Outputs•Alarm Outputs•Binary Remote Start/StopInstalling the Power SourceInstructions for connecting to a power source follow. Proceed to the section that applies to your specific model of Analyzer:•Laboratory and Portable Analyzers — “Power Cord Installation” section•On-Line Analyzers — “Conduit Installation” sectionPOWER CORD INSTALLATION(Laboratory and Portable TOC Analyzers Only)The Sievers M9 and M9e Laboratory and Portable Analyzers Sievers M5310 C Laboratory and Portable TOC Analyzers come supplied with power cords. Attach the connector end of the power cord into the connection labeled “Power” on the Analyzer, and then insert the plug end into a grounded power source. Make sure the cord is seated securely at both ends. CONDUIT INSTALLATION(On-Line TOC Analyzer Only)The Sievers M9 or M9e On-Line TOC Analyzers requireSievers M5310 C On-Line TOC Analyzer requires the installation of an external source of AC power connected to the enclosure using a water-tight conduit connector. The electrical connection MUST be performed by a qualified electrician. We recommend an external switch or circuit breaker to facilitate maintenance and servicing of the Analyzer. Install it near the Analyzer and clearly mark it as the disconnecting device for the Analyzer.WarningThe Analyzer requires an A/C mains supply of 100-240 volts, andrequires the correct power cord for safe operation. ONLY use thepower cord supplied in the Analyzer’s Accessory Kit with theAnalyzer, which meets this A/C mains supply requirement.
INSTALLATIONChapter 4Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201474 of 211To wire the AC conduitYou will need to provide the following:•Insulated wire for AC power conduit (18-12 AWG), rated to 300 Volts. Strip length should be 8-9 mm (.33 in.).•Metallic AC power conduit3 (optional)•Strain relief hub (conduit connector) and washer•Terminal ring for AC conduit ground wire, 16-14 American Wire Gauge (AWG)•External circuit breaker or switch that disconnects both poles of the supply voltage, rated appropriately (recommended)1. Before working with any of the Analyzer’s inside components, ensure that you are exercising ESD protection.2. Unlatch and open the door to the Analyzer (Push the release button first).3. Remove the electrical enclosure cover at the top of the instrument by using a Phillips-head (crosshead) screwdriver #2 to loosen the two captive screws securing the cover.4. Remove the cap from the pass-through port located on the right side-panel of the Analyzer. Squeeze the conical side of the cap, and then push it outside of the Analyzer.5. Route the AC power conduit1 through this same pass-through port, and secure a strain relief hub (conduit connector) and washer to the conduit and Analyzer bulkhead.6. Connect the conduit Line (brown or black wire) to the bottom of the Terminal block in the left port, and connect the Neutral (blue or white wire) in the right port. Refer to Figure 18: Wiring AC Power Conduit. When connecting the wire to the terminal block, loosen the screws on the front of the block and then insert the wires as designated. Tighten the screws to secure the wires.WarningElectrical conduit should be installed by a qualified electrician.Also, before installing any wiring inside the Analyzer, make sureyou are wearing ESD protection.3. Metallic conduit is required for the Analyzer to meet CE Mark electrical requirements
.................................INSTALLATION INSTRUCTIONSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201475 of 2117. After connecting the wires, pull on each connection gently to make sure the connection is secure.8. Attach a terminal ring to the grounding conductor (green OR green/yellow wire), and connect it to the ground stud. Figure 18: Wiring AC Power Conduit. 9. Replace the electrical enclosure cover at the top of the instrument, and using a Phillips-head (crosshead) screwdriver #2 to tighten the two captive screws for securing the cover.10. Close and latch the door to the Analyzer. (Or, proceed directly to the next section to install the I/O control wiring.)Figure 18: Wiring AC Power ConduitInstalling I/O Control Wiring (On-Line and Portable TOC Analyzers Only) An I/O Controller Board is available as an option in the Sievers M9 or M9e On-Line and Portable TOC AnalyzersSievers M5310 C On-Line and Portable TOC Analyzers. With this board, you can install up to three 4-20 mA analog outputs and four alarm outputs on the Analyzer. Additionally, you can wire one binary input connection for communicating remote start and stop commands to the Analyzer.
INSTALLATIONChapter 4Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201476 of 211The J4, J5, and J6 terminal blocks contain the following: •(J4) Serial and 4-20 mA Outputs 1-3 — Use these outputs to record Analyzer data. The analog output is calibrated at the factory prior to shipping. Each pin has a power isolation level of 500 V and is individually isolated, The maximum 4-20 mA load is 600 ohms.•(J5) Binary Input — Use these connections to execute “Start Analysis” and “Stop Analysis” commands to the Analyzer from a remote location, such as a Process Logic Control System or Center (PLC).•(J6) Alarm Output 1-4 — Use these outlets for alarm outputs. Each pin has a power isolation level of 500 V and is individually isolated. The maximum load for the alarm ports is 30 VDC at 1.0 A or 125 VAC at 0.5 A.INSTALLING SERIAL AND 4-20 MA ANALOG OUTPUTSThis section includes step-by-step instructions for wiring 4-20 mA and alarm connections. Pinout Tables and Wiring Diagrams are also provided for your reference.To install 4-20 mA and alarm outputs — On-Line TOC AnalyzerUse this instruction to install 4-20 mA and alarm output connections on the I/O board inside the On-Line TOC Analyzer.You will need a small flat-blade screwdriver and wire to complete this procedure. The wire should be 28-16 AWG, rated to 300 Volts. The strip length for each pin should be 8-9 mm (.33 in).1. Before working with any of the Analyzer’s inside components, ensure that you are exercising ESD protection.2. To access the I/O board, open the door to the Analyzer (push the release button and then pull the tab to unlatch). Remove the enclosure cover located on the back of the door by using a Phillips-head (crosshead) screwdriver #2 to loosen the two captive screws securing the cover. The I/O board is located behind the inside panel of the Analyzer’s door, and the board is mounted in the lower-left area of the door. 3. Remove the cap from the pass-through cut-out (labeled “XXX” Decision not final), located on the left side-panel. Squeeze the conical side of the cap, and then push it out of the Analyzer.WarningThe output and alarm connections should be installed by aqualified electrician. Also, before installing any wiring inside theAnalyzer, make sure you are wearing ESD protection.
.................................INSTALLATION INSTRUCTIONSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201477 of 2114. Route the cables to the terminal blocks through this pass-through port. Terminal block J4 is designated for 4-20 mA outputs and terminal block J6 is for the alarm outputs.To install the wires in a terminal block, first remove it from the I/O board. Note the orientation of the terminal block before removing it, and then firmly grasp the terminal block and pull it straight out from the terminal header on the board. 5. Identify the correct pin position for each wire you are installing according to Tables 2 and 3.6. Use a small, flat blade screwdriver to completely loosen the screw for that pin. (The screws are located underneath the terminal block.) Insert the wire into the clamp for the pin (located on the side of the terminal block), and then tighten the pin screw to secure the wire.7. Repeat steps 5 and 6 for each pin you will be using.8. Gently pull on each connection to make sure the connection is secure.9. Plug the terminal block into the terminal header on the I/O board.10. Repeat steps through 9 for each terminal block, as needed.To install 4-20 mA and alarm outputs — Portable TOC AnalyzerYou will need a small flat-blade screwdriver, a #2 Phillips head screwdriver, and wire to complete this procedure. The wire should be 28-16 AWG, rated to 300 Volts. The strip length for each pin should be 8-9 mm (.33 in).1. Before working with any of the Analyzer’s inside components, ensure that you are exercising ESD protection.2. To access the I/O board, detach the protective cover from the rear of the instrument by removing the two Phillips-head screws. The I/O board is mounted perpendicular to the back of the Analyzer, and the terminal blocks extend outside the instrument through cutouts in the housing. These terminal blocks are accessible from the back of the instrument and are labeled “Alarms,” “Binary,” and “4-20 mA.”3. To install the wires in a terminal block, first pull out the terminal block for ease in the installation process. Note the orientation of the terminal block before removing it, and then firmly grasp the terminal block and pull it straight out from the terminal header on the board. 4. Identify the correct pin location for each wire you are installing according to Tables 2 and 3.5. Use a small flat-blade screwdriver to completely loosen the screw for that pin. The screws are located underneath the terminal block. Insert the wire into the clamp
INSTALLATIONChapter 4Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201478 of 211for the pin (located on the side of the terminal block), and then tighten the pin screw to secure the wire.6. Repeat steps 4 and 5 for each pin you will be using.7. Gently pull on each connection to make sure the connection is secure.8. Plug the terminal block into the terminal header on the I/O board.9. Repeat steps 3 through 8 for each terminal block, as needed.10. Replace the Analyzer’s enclosure panel, making sure that the magnets are secured. PINOUT TABLES AND WIRING DIAGRAMSReference the following information, as needed, when wiring 4-20 mA outputs and alarms. Allen providing new wiring diagrams from Mike Cunningham.Figure 19: Wiring 4-20 mA Connections
.................................INSTALLATION INSTRUCTIONSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201479 of 211J4 Board WiringThe 4-20 mA analog outputs are isolated from system ground. You can configure the analog outputs to output IC, TC, or TOC.The 4-20 mA outputs are also individually isolated from each other, and therefore may be connected to multiple industrial control systems (ICS) with differences in ground potential..TABLE 2: SERIAL AND 4-20 MA OUTPUTS (J4)Pin Number Output1 #1 4-20 mA (Return) -2 #1 4-20 mA (Out) +3 #2 4-20 mA (Return) -4 #3 4-20 mA (Out) +5 #3 4-20 mA (Return) -6 #3 4-20 mA (Out) +
INSTALLATIONChapter 4Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201480 of 211J6 Board WiringThe alarm outputs are isolated from system ground and from each other. You can configure each of the alarm outputs.The outputs are implemented by relays, which are intended for low voltage use only. The maximum switching capacity (resistive load) is 62.5 VA, 33 Watts.* NC = normally closed, NO = normally openINSTALLING THE REMOTE START (BINARY INPUT) CONNECTIONThe remote start (binary input) connection is intended to execute “Start Analysis” and “Stop Analysis” commands to the Analyzer from a remote location, such as a Process Logic Control System or Center (PLC). J5 Board WiringThe J5 terminal block is used for the binary input. Refer to Table 20, “Wiring Option for Binary Input Using Analyzer’s Internal Supply for the pin references.The binary start/stop analysis input is isolated from system ground. You can configure the polarity of operation.The + input should be supplied with a voltage from +11 volts to +24 volts and the -input should be controlled by a relay or an open collector transistor.TABLE 3: ALARM OUTPUTS (J6)Pin Number Outputs1 Alarm 1 (Common) output2 Alarm 1 (NC*) output3 Alarm 1 (NO*) output4 Alarm 2 (Common) output5 Alarm 2 (NC*) output6 Alarm 2 (NO*) output7 Alarm 3 (Common) output8 Alarm 3 (NC*) output9 Alarm 3 (NO*) output10 Alarm 4 (Common) output11 Alarm 4 (NC*) output12 Alarm 4 (NO*) output
.................................INSTALLATION INSTRUCTIONSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201481 of 211TABLE 4: BINARY INPUTS (TERMINAL BLOCKJ5) NOTE: The +24 volts (0.5A max) and system ground are provided forlocal use only and are not intended for connections more than 15 ftaway from the analyzer.To install the binary input connectionsYou can wire the binary input connection in a variety of ways, such as the examples shown in Figure 20: Wiring Option for Binary Input Using Analyzer’s Internal Supply and Figure 21: Wiring Option for Binary Input Using External Supply.Before using the binary input connection, you must activate the Binary Input feature in the Analyzer firmware. You will do this later during the installation process in “Step 10: Configure Basic Analyzer Settings” on page 98.NOTE: Make sure to confirm the correct signal strength before settingthe Binary Input to On in order to avoid unexpectedly starting orstopping analysis. Figure 20: Wiring Option for Binary Input Using Analyzer’s Internal SupplyFigure 21: Wiring Option for Binary Input Using External SupplyPin Number Output1 +24 V2In+3In-4GND
INSTALLATIONChapter 4Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201482 of 211STEP 5: INSTALL THE REAGENT CARTRIDGESThe oxidizer and acid reagents are shipped separately from GE Analytical Instruments in specific packaging for safe transit. Carefully read the attached MSDS sheets prior to opening the packaging. You will find two reagent cartridges inside the packaging, one clearly identified as “OXIDIZER (15% ammonium persulfate and water” and one as “UN 1805 PHOSPORIC ACID SOLUTION.”After you install these reagent cartridges, the RFID antenna obtains and tracks data from each label attached to the Acid and Oxidizer reservoir cartridges, including: Reagent type (Acid or Oxidizer), lot number, part number, initial and remaining volume, manufactured date and expiration date. The Analyzer uses this information to automatically track the remaining volume, based on the number of syringe extractions. For additional information, see “Radio Frequency ID (RFID)” on page 57.The following instructions are specific to the Analyzer model. Refer to the applicable section for your instrument:•To install the reagent cartridges—Laboratory and Portable TOC Analyzers•To install the reagent cartridges—On-Line TOC AnalyzerKnow These Safety WarningsHazardous reagents (ammonium persulfate and phosphoricacid) are used in the Analyzer. Before installing a reagent, readthe corresponding Material Safety Data Sheet (MSDS) for properhandling precautions, and spill or leak procedures. The MSDS arecontained in the pouch located on the outside of the reagentshipping box.Installation of reagents and most Analyzer maintenancerequires access to the inside of the Analyzer. To avoid potentiallydangerous shock—BEFORE opening the Analyzer—first stop anyanalysis, stop the operating system (using HALT SYSTEM button inthe Analyzer’s firmware), and then turn off power anddisconnect from the power supply.To avoid exposure to the chemical reagents, wear acid-resistantgloves and safety goggles.Reagent containers are for single-use only. Do NOT refill. Anyrefilling or reusing of reagent containers will void all Analyzerand parts warranties, and nullify any performance claims.
.................................INSTALLATION INSTRUCTIONSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201483 of 211To install the reagent cartridges—Laboratory and Portable TOC Analyzers1. Before opening and working with the chemical reagents, and working inside the Analyzer, ensure that you are:•Ensure that Analyzer switch is Off and the power cord is disconnected. (You MUST always Halt the firmware before turning the power switch to Off.)•Wearing the recommended personal protective equipment (PPE), as outlined in the previous Safety Warning•Exercising electrostatic discharge (ESD) protection2. Open the Analyzer, as follows:•(Laboratory TOC Analyzer) — Remove the right side panel. Stabilize the instrument with one hand on the top panel, and then grasp the edge of the right side panel from the back of the Analyzer. Pull the entire panel away from the instrument. (The panel is attached to Analyzer by magnets.)•Portable TOC Analyzer — Remove the right side panel. Stabilize the instrument with one hand on the top handle, and then grasp the edge of the panel from the back of the Analyzer. Pull the entire right panel away from the instrument. (The panel is attached to Analyzer by magnets.)3. Locate and remove the reagent tray, and set it next to the Analyzer for the assembly process. Position the labeled side toward you with the cut-out end pointed toward the left (the front of the Analyzer). The tray is attached by magnets to the RFID antenna4 (rectangular) cover, which is located on the floor of the unit.4. Remove each reagent container from its shipping packaging.5. Stand each container on the long end next to the Analyzer for this connection process.Place the Oxidizer container in front position (for the convenience of earlier replacement anticipated by typical consumption timing). 6. Locate the acid supply line, indicated by the Acid label. Attach the supply-line PEEK nut to the inlet at the top of the acid reagent container, and then tighten finger-tight. Verify if Engineering is adding Acid label.(Delete later when new cartridge is implemented.) Slide the valve on the acid container to the open position by pushing the green button all the way in. Refer to the labeling on the container for proper positioning. 7. Locate the oxidizer supply line, indicated by the Oxidizer label. Attach the supply-line PEEK nut to the oxidizer container and tighten finger-tight.4. Radio Frequency ID used to track expiration dates off the reagent containers.
INSTALLATIONChapter 4Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201484 of 211(Delete later when new cartridge is implemented.) Slide the valve on the oxidizer container to the open position by pushing the green button all the way in. Refer to the labeling on the container for proper positioning.8. Verify that the labeled side of the reagent tray is facing you and the cut-out side of the tray is facing left toward the front of the Analyzer.9. Place the Acid container into the back compartment of the reagent tray, and then place the Oxidizer container into the front compartment of the reagent tray. Make sure to position the tubing-end of each container toward the cut-out side of the tray.10. Now, lift the entire reagent tray (with the Acid and Oxidizer containers in place), and set the tray back on the RFID antenna5 (rectangular) cover, which is located on the floor of the unit. The magnet feet of the tray fit into the corner grooves on the RFID cover. You will feel the magnets secure the tray into place.NOTE: When installing the reagent tray, make sure the labeledside of the tray is facing you and the tubing-ends of the reagentcontainers are pointed left (toward the front of the Analyzer).11. You will flush the reagent syringes later in the installation process, as described in “To flush the reagent syringes” on page 105,To install the reagent cartridges—On-Line TOC Analyzer1. Before opening and working with the chemical reagents, and working inside the Analyzer, ensure that:•The Power switch is Off and the power cord is disconnected (Laboratory and Portable TOC Analyzers), or the Mains turned off (On-Line TOC Analyzer). (You MUST always Halt the firmware to turn off power to the Analyzer.)•You are wearing the recommended personal protective equipment (acid-resistant gloves and safety goggles).•You are Exercising electrostatic discharge (ESD) protection1. Open the door to the Analyzer. Push the release button and then pull the tab to unlatch the door.2. Loosen the thumbscrews on the reagent housing cover, which is located on the (lower front) floor of the Analyzer. Lift the cover straight up to remove, and then set aside the cover during the assembly process.3. Remove each reagent container from its shipping packaging.5. Radio Frequency ID used to track expiration dates off the reagent containers.
.................................INSTALLATION INSTRUCTIONSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201485 of 2114. Locate the acid supply line, indicated by the Acid label. Attach the supply-line PEEK nut to the inlet at the top of the acid reagent container, and then tighten finger-tight. Verify if Engineering is adding Acid label.(Delete later when new cartridge is implemented.) Slide the valve on the acid container to the open position by pushing the green button all the way in. Refer to the labeling on the container for proper positioning. 5. Place the Acid container into the back compartment of the reagent tray, positioning the container horizontally with the tubing-end facing toward the right and open-side of the tray.6. Locate the oxidizer supply line, indicated by the Oxidizer label. Attach the supply-line PEEK nut to the oxidizer container and tighten finger-tight.(Delete later when new cartridge is implemented.) Slide the valve on the oxidizer container to the open position by pushing the green button all the way in. Refer to the labeling on the container for proper positioning.7. Place the Oxidizer container into the front compartment of the reagent tray, positioning the container horizontally with the tubing-end facing toward the right and open-side of the tray.8. Carefully lower the reagent housing cover over the reagents, sliding the guide pin (located toward the back and on top of the reagent cradle) through the guide hole on the cover.Also, make sure that the two tubing lines are carefully positioned between the cover and cradle-side cushions.9. Tighten the thumbscrews on the reagent housing cover to secure.10. You will flush the reagent syringes later in the installation process, as described in “To flush the reagent syringes” on page 105, STEP 6: INSTALL THE DI WATER SYSTEMThe Analyzer is shipped with an empty DI water reservoir and a (separately-packed) DI resin cartridge. You will need to fill the DI water reservoir with DI water. Next, you will need to install the DI resin cartridge into the Prime position and prime the DI water pump. After the priming process, you will move the DI resin cartridge into the Run position for normal Analyzer operation.WarningTo avoid damaging the DI water pump, Do NOT turn theAnalyzer to On before ensuring that the DI water reservoir isfilled and properly primed, as described in Step 6: Install the DIWater System.
INSTALLATIONChapter 4Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201486 of 211NOTE: Each port (Prime, Run, and DI Pump Outlet) has a metallatch to use when inserting and detaching a fitting. Press the latchand hold when inserting a fitting. This protects the fitting andopens the valve. Press the latch with your finger to release afitting and close the valve. When inserting or detaching the DIresin cartridge, insert or detach both end-fittings simultaneouslyto avoid damaging movement to the cartridge.To fill the DI water reservoir1. Before working inside the Analyzer, ensure that:•The Power switch is Off and the power cord is disconnected (Laboratory and Portable TOC Analyzers), or the Mains turned off (On-Line TOC Analyzer). (You MUST always Halt the system in the firmware before pressing the power switch to Off.)•You are wearing the recommended personal protective equipment (acid-resistant gloves and safety goggles).•You are Exercising electrostatic discharge (ESD) protection.2. Locate the following in the Analyzer’s Accessories Kit:•Dispensing bottle (with attached filling fixture)•Individual (loose) elbow fittingYou may also want to have a paper towel nearby, in case of any leakage during the installation and priming processes.3. Press the latch of the Prime port down and insert the individual (loose) elbow fitting,4. Unscrew the lid of the dispensing bottle (leaving the filling fixture attached to the top of the lid), and fill the bottle with low-TOC (<50 ppb) DI water. Replace and tighten the lid to secure it.5. Press the latch of the DI pump outlet up and insert the elbow-fitting end of the dispensing bottle into the DI pump outlet. (The outlet is located between the IC and TC sample pumps). Reference Figure 22: Inserting the DI Loop Fill Tube.)Gently squeeze the bottle to fill the DI reservoir, filling the DI reservoir until the water line reaches JUST BELOW the top of the reservoir, as shown in Figure 23: Filling the DI Water Reservoir. DO NOT OVERFILL.NOTE: It is important to ONLY fill the reservoir to the suggestedlevel. Otherwise, the water in the portion of the reservoir that youcan see may overflow to another level in the reservoir (which youcannot see from the viewing window). If you do overfill thereservoir, drain the excess water by following the troubleshooting
.................................INSTALLATION INSTRUCTIONSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201487 of 211procedure, “To drain excess water from the DI water reservoir” onpage 168. 6. Press the latch of the Prime port down to release the individual elbow fitting for removal. 7. Press the latch of the DI pump outlet up to release the dispensing bottle’s elbow-fitting for removal of the dispensing bottle accessory.8. Proceed to the next section to set the DI resin cartridge and prime the DI pump.Figure 22: Inserting the DI Loop Fill Tubegraphic showing cut-out area above the IC and TC sample pumps and DI pump outletFigure 23: Filling the DI Water ReservoirTo set the DI resin cartridge and prime the DI pumpYou will first install the DI resin cartridge into the Prime position and prime the DI water pump, and then reset the DI resin cartridge into the Run position for normal Analyzer operation.1. Ensure that the DI water reservoir is filled, according to the instructions in the previous section.2. Locate the DI resin cartridge in the Analyzer’s Accessories kit, and remove it from its shipping packaging.3. Install the DI resin cartridge. Press the latches on the Prime port and the DI Pump Outlet port. Insert the elbow-fitting ends of the cartridge into the ports.Verify that the ends are secure before moving to the next step. Refer to Figure 24: DI Cartridge Inlet Fittings for Priming Activity, as needed.4. Go to the next instruction section to prime the DI water pump.To prime the DI Water pumpWarningIn order to avoid the possibility of corrupting the systemdatabase, always FIRST halt system operations from within thefirmware before pushing the Analyzer’s power switch to the Offposition.
INSTALLATIONChapter 4Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201488 of 2111. Ensure that the DI resin cartridge is set in place with the top valve securely connected to the Prime position, according to the instructions in the previous section.2. Plug in the Analyzer’s power cord (Laboratory and Portable TOC Analyzers) or turn on the Mains (On-Line TOC Analyzer).3. Press the Analyzer’s power switch to the On position, and let the Analyzer run 10 minutes to allow the DI pump to circulate water in the DI loop.4. After 10 minutes, on the Home screen (in the Analyzer’s firmware), press the HALT SYSTEM button located in the lower-right portion of the screen. The Halt System dialog box appears.5. Turn the power switch to the Off position.6. View the reservoir water level and verify that the water level reaches JUST BELOW the top of the reservoir, as shown in Figure 23: Filling the DI Water Reservoir. 7. The water level may be lower than when you started, as water will circulate in the DI loop and saturate the DI resin cartridge during the priming process. Fill the DI reservoir with water if needed, repeating the procedure, “To fill the DI water reservoir” on page 86. You will also need to repeat this priming procedure beginning from step 1.8. After you have verified the that the water level has stabilized to JUST BELOW the top of the reservoir, remove the DI resin cartridge from the prime position. While holding the DI cartridge, simultaneously press the latches on the Prime port and the DI Pump Outlet port to eject the cartridge.9. Install the DI resin cartridge into the Run position. Press the latches on the Run port and the DI Pump Outlet port. Insert the elbow-fitting ends of the cartridge into the ports. Hold the cartridge tightly in place.Verify that the ends are secure before moving to the next step. 10. Do we want to run for any amount of time in Run position before moving to next installation step?11. Close and latch the Analyzer’s door (On-Line TOC Analyzer) or replace the panel (Laboratory and Portable TOC Analyzers Only).graphic. Figure 24: DI Cartridge Inlet Fittings for Priming Activity
.................................INSTALLATION INSTRUCTIONSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201489 of 211graphic. Figure 25: DI Cartridge Positioning for Analyzer OperationSTEP 7: INSTALL ETHERNET AND EXTERNAL DEVICESUpdate Intro•Installing an Ethernet connection•Installing a Printer•Installing USB connections•One Device Port (ONLY Used for connecting a computer when operating with Sievers DataPro Software.)•Host Port (Used for connecting a GE Autosampler, printer, or portable USB memory device.)Installing an Ethernet ConnectionYou can export historical data from the Analyzer to your computer or computer network via Ethernet, and using the Modbus communications protocol. For more information on the types of data available for export, as well how-to instructions, refer to “Using the Ethernet Connection and Modbus” on page 149.This section describes installing the Ethernet connection. You will then need to activate the Ethernet Connection in the Analyzer’s firmware later in “Step 10: Configure Basic Analyzer Settings.” You may need more assistance from your network administrator or Information Technology (IT) professional to configure PuTTY6 for working with exported data, or to configure the Modbus communications protocol when you are connecting to a PLC (Process Logic Control System or Center). NOTE: You can alternately export data directly to your computer using aUSB device connection, and use the optional DataPro Software to workwith the data. Refer to “Installing a USB Connection” on page 90 foradditional information.6. PuTTY is a free and open-source terminal emulator, serial console, and network file transfer protocol.
INSTALLATIONChapter 4Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201490 of 211To install the Ethernet ConnectionYou will need to provide either a cross-over Ethernet cable (for connecting directly to a computer) or a straight-through Ethernet cable (for connecting to a computer network).1. Attach one end of the Ethernet cable to the Ethernet port on the Analyzer, and then attach the other end of the cable either to an Ethernet port on the your network or to a computer.2. You will activate the Ethernet connection and Modbus later in “Step 10: Configure Basic Analyzer Settings” as described in the section, “To activate the Ethernet Connection and Modbus” on page 103.NOTE: The USB ports on the Analyzer are NOT intended forEthernet connectivity, and cannot not be used with an Ethernet toUSB adapter. For acceptable uses of the USB ports, refer to thenext section “Installing a USB Connection.”INSTALLING A USB CONNECTIONThe On-Line and Portable TOC Analyzers each contain three USB ports on the back of the instrument. One device port is labeled “USB Computer,” and two host ports are labeled “USB.” The (Laboratory TOC Analyzer) also contains three similar USB ports on the back of the instrument, as well as one additional USB host port on the front of the instrument, labeled “USB.” Refer to USB port locations in Figure 26: USB Ports, as needed.USB DEVICE PORTThe Analyzer has one USB device port (labeled “USB Computer”) for connecting the Analyzer directly to your computer, when using the optional DataPro Software to control the Analyzer and the GE Autosampler. The USB device port is uniquely shaped with a rounded square connector in contrast to the typical (flat) USB host connector. A USB-device to USB-host cable is included in the GE Autosampler Accessories Kit.NOTE: The USB Device port is intended solely for connecting theAnalyzer to the computer for operation with the DataProSoftware. It is NOT possible to export data to a computer throughthis USB Device port without the use of the DataPro Software.You can export data from the Analyzer to a USB portable drive usingone of the Host ports or through an Ethernet connection. Refer to “USBHost Ports” on page 91 or “Installing an Ethernet Connection” onpage 89, as needed.
.................................INSTALLATION INSTRUCTIONSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201491 of 211To install a USB connection — Device Port (Optional) 1. Install the DataPro Software on your computer now, or come back to and perform this instruction after you have installed the software. Instructions for installing the DataPro Software are included in the GE Autosampler Installation Guide.2. Locate one of the USB-Device to USB-Host cables in the GE Autosampler Accessories Kit. [You will use the other cable later in this section.)3. Connect the Device USB-Device connection end of the cable into the “Computer” USB port on the Analyzer.4. Connect the other end of the cable with the host USB connection end into your computer’s USB (host) port.5. “To install a USB Host port connection — GE Autosampler (Optional)” on page 91.]USB HOST PORTSThe On-Line and Portable TOC Analyzers have two USB host ports (labeled “USB”) on the back of the instrument. The (Laboratory TOC Analyzer) also contains two USB host ports (labeled “USB”) on the back of the instrument, as well one additional USB host port (labeled “USB”) on the front of the instrument. The USB host ports are designed for use with the following peripheral accessories:•GE Autosampler•Printer (Must be one of the specific brands/models identified in the “Installing a Printer” section.)•Portable USB memory deviceTo install a USB Host port connection — GE Autosampler (Optional) 1. Complete this instruction after you have installed the DataPro Software on your computer, or come back to and perform this instruction after you have installed the software.2. Ensure that you have connected the Analyzer to your computer, as described in “To install a USB connection — Device Port (Optional)” on page 90. 3. Locate the remaining USB-Device to USB-Host cable in the GE Autosampler Accessories Kit.4. Connect the Device-USB connection end of the cable into the “Computer” USB port on the GE Autosampler.
INSTALLATIONChapter 4Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201492 of 2115. Connect the other end of the cable with the host-USB connection end into one of the Analyzer’s USB (host) ports.To install a USB Host port connection — Printer (Optional)Refer to the section, “Installing a Printer” on page 92, for step-by-step instructions.To install a USB Host port connection — Portable USB Memory DeviceYou can export data from the Analyzer to a portable USB memory device using any of the USB Host ports on the Analyzer. Insert the USB memory device into a Host port, and then follow the step-by-step instructions for exporting data history included in “” on page 150.Graphic for USB Ports (three models)Figure 26: USB PortsInstalling a PrinterThe Analyzer is designed to work with the following USB point-of-service (POS) printers, which are available as an optional accessory directly from GE Analytical Instruments:•Bixolon/Samsung SRP-275•Citizen CD-S500A•Epson TM-722ODTo install a USB POS printer1. Connect the USB connector-end of the printer cable into one of the USB device ports (marked “USB”) on the Analyzer.2. Connect the other end of the cable into the printer.3. Consult the instructions that come with the printer for additional help, as needed.4. Continue to the next section to configure the printer in the Analyzer.To configure the printer in the Analyzer 1. Connect the printer to the Analyzer, as described in the previous section.2. On the Configuration screen, press the System Setup tab.3. Press PRINTER SETUP to display the Printer Configuration dialog.
.................................INSTALLATION INSTRUCTIONSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201493 of 2114. Select one of the following printers to install:•Bixolon/Samsung SRP-275•Citizen CD-S500A•Epson TM-722OD5. Press TEST PRINT to verify that printer is working.If the page does not print, verify that the printer you have installed is the exact brand and model selected on the Printer Configuration dialog, and that you have connected the cable as described in the previous section.6. Press OK to enable the printer.STEP 8: CONNECT AN ON-LINE SAMPLE INLET SYSTEM(On-Line and Portable TOC Analyzers Only) Add two-stream connection information.......The two-stream inlet option enables efficient sampling of two independent sample sources, without the need to alter the initial inlet setup. This optional configuration is discussed in more detail in the “Optional Configurations”section, under “Two-Stream Inlet” on page 60.NOTE: If you are using a GE Autosampler with your Laboratory orPortable TOC Analyzer model, DO NOT proceed with this section.Instead, refer to the GE Autosampler User Guide. The information forconnecting the sample tubing to the inlet port is located in the section,“Route the Sample Tubing.”Connect a sample inlet line to the integrated On-Line Sampling (iOS) for continuous on-line measuring. As part of the sample-inlet installation process, you will also install a waste line. With this inlet system installed, you can conveniently switch between on-line sampling and discrete sampling using vials in the iOS.There is no further installation required for On-Line and Portable TOC Analyzers to measure discrete grab samples from a vial. The iOS is ready for measuring grab samples without the need to disconnect the on-line inlet tubing. The Analyzer automatically shuts off on-line water flow when it detects that the iOS door is closed and/or a vial is inserted into the iOS.You will need to select an appropriate On-line or Grab measurement mode on the Setup screen in the Analyzer’s firmware, and then start the sampling on the Home screen. For complete step-by-step instructions, refer to “Running a sample” on page 126.NOTE: The Laboratory TOC Analyzer arrives ready to measure discretegrab samples using the vial port (located on the front) of the instrument.It is not designed for continuous on-line sampling. Go to the next
INSTALLATIONChapter 4Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201494 of 211section,“Step 9: Install the Waste Outlet (Laboratory Model)” onpage 97, to install the waste outlet.Figure 27: iOS Waste Outlet Fitting — On-Line and Portable TOC AnalyzersTo connect the inlet tubing to the iOSYou will need the 1/4” Teflon inlet tubing (with in-line filter) from the Analyzer’s Accessories Kit. You will also need to provide You will also need to provide 3/4” OD plastic waste tubing.Refer to Figure 28: This iOS, as needed, when performing this instruction.1. Ensure that the power to the Analyzer is Off and disconnected.2. Verify that the water source is disabled until you have completely installed the sample inlet system and the Analyzer is ready to begin analysis.3. Locate the 1/4" Teflon inlet tubing (with the in-line filter) in the Accessories Kit.4. Pull out the waste fitting from the bottom of the iOS to gain more working room for this procedure. You may need to twist it slightly to remove it.
.................................INSTALLATION INSTRUCTIONSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201495 of 2115. Connect the inlet tubing into the sample inlet on the iOS System. Using a 9/16" open-end wrench, secure the nut. Do NOT over-tighten the nut.6. Replace the waste outlet fitting (you removed in step 4) to the bottom of the iOS.7. Slide one end of the waste tubing over the waste outlet (barb) fitting, See iOS Waste Outlet Fitting — On-Line and Portable TOC Analyzers.8. Position the tubing for a gravity drain of the waste water, collecting the waste in a glass laboratory container or facility-approved waste or return line.9. Establish a water flow to the iOS System.10. Using a flow meter measure the flow rate, and then adjust to between 50-300 mL/min using the flow rate adjustment screw.NOTE: The flow rate is controlled by a needle valve, which you canadjust by turning the screw located on the iOS. Turn the screw clockwiseto decrease flow, or counter-clockwise to increase flow. (See Figure 29:Flow Rate Adjustment Screw.) Figure 28: This iOSWarningHazardous reagents (ammonium persulfate and phosphoric acid) areused in the Analyzer. The waste stream from the instrument is acidic andmust be disposed of properly. Consult your federal, state, and localgovernment regulations.Graphic placeholder showing iOS and the waste outlet fitting and inlet port
INSTALLATIONChapter 4Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201496 of 211Figure 29: Flow Rate Adjustment ScrewWarnings(On-Line and Portable TOC Analyzers) Operation of the Analyzerwithout the in-line filter on the sample inlet line will damage theAnalyzer and void the warranty. To avoid damaging the Analyzer,install the filter and replace the filter element, as needed.To avoid false TOC readings and possible damage to theAnalyzer, always make sure the sample is flowing through theiOS System and the DI water reservoir is filled before startinganalysis.
.................................INSTALLATION INSTRUCTIONSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201497 of 211STEP 9: INSTALL THE WASTE OUTLET (LABORATORY MODEL)(Laboratory TOC Analyzer Only) NOTE: If you have an On-Line or Portable TOC Analyzer, IGNORE thissection. Directions for installing the waste outlet are included as part ofthe previous section, “Step 8: Connect an On-Line Sample Inlet System”on page 93.To install the waste outletYou will need the 1/8” OD plastic waste tubing with Swagelok® fitting (provided in the Accessories Kit).1. Using a 7/16” open-end wrench, disconnect the nut that connects to the Waste port.2. Locate the 1/8” OD plastic waste tubing with Swagelok® fitting (provided in the Accessories Kit). 3. Attach the Swagelok® fitting to the Waste port, and use the 7/16” open-end wrench to tighten securely.4. Position the hose for a gravity drain7 of the waste water, collecting the waste in a glass laboratory container or facility-approved waste or return line.7. The collecting laboratory container or line should be positioned lower than the iOS waste outlet to facilitate a gravity-induced flow.WarningsHazardous reagents (ammonium persulfate and phosphoricacid) are used in the Analyzer. The waste stream from theinstrument is acidic and must be disposed of properly. Consultyour federal, state, and local government regulations.Graphic Placeholder
INSTALLATIONChapter 4Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201498 of 211Figure 30: Waste Outlet Fitting — Laboratory TOC AnalyzerSTEP 10: CONFIGURE BASIC ANALYZER SETTINGSALL OF THIS SECTION IS A WIPBefore placing your Analyzer into service, you will need to configure various basic settings in the Analyzer’s firmware using the intuitive touchscreen display (located on the front of the Analyzer). You will not need to change most of these settings unless you move the Analyzer, or reconfigure the operational environment. This section includes how to configure basic analyzer settings, including:•Powering On and Off the Analyzer•Enabling Password Protection or DataGuard (Optional)•Naming the Analyzer Location (Optional)•Setting the Analyzer Mode and Reagent Flow Rates•Setting Up the Data History•Setting Up the Printer (Optional)•Enabling Turbo•Exporting and Printing System Constants•Setting up the Data I/OPowering On and Off the AnalyzerEach Analyzer model (On-Line, Laboratory, and Portable) has and On/Off power switch8. However, before pushing the power switch to Off, you MUST first shut down the Analyzer’s operating system in the firmware in order to avoid the possibility of corrupting the database. You can then press the power switch to Off to complete the power-down cycle. When performing maintenance inside the Analyzer, we also recommend that you disconnect the power cord from the A/C outlet (Laboratory and Portable TOC Analyzers) or shut down the Mains power supply (On-Line TOC Analyzer).8. A power On/Off switch is located on the back of the Laboratory and Portable TOC Analyzers and on the side of the On-Line TOC Analyzer.
.................................INSTALLATION INSTRUCTIONSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 201499 of 211To power On the AnalyzerPress the power switch to On to initiate power in the Analyzer. The firmware screen illuminates for immediate operation.To power Off the Analyzer1. On the Home screen (in the Analyzer’s firmware), press the HALT SYSTEM button located in the lower-right portion of the screen. The Halt System dialog box appears.2. Press YES to confirm that you want to halt the Analyzer’s operating system. The system will automatically shut down and the screen will de-illuminate (go blank).3. Locate the power switch on the outside of the Analyzer, and press the power switch to Off to complete the power-down cycle. NOTE: The power cycle is NOT complete until you have pressed thepower switch to Off. This ensures that power to ALL circuit boards isdisconnected.4. If you are planning to perform maintenance inside the Analyzer, disconnect the Analyzer’s power cord from the A/C outlet (Laboratory and Portable TOC Analyzers) or shut down the Mains power supply (On-Line TOC Analyzer).Enabling Password Protection or DataGuard (Optional)Update this section with firmware development completionThe Sievers 900 Series of TOC Analyzers offers two levels of security, Password Protection and DataGuard. The Password Protection feature is included with ALL Analyzers and provides a WarningIn order to avoid the possibility of corrupting the systemdatabase, always FIRST halt system operations from within thefirmware before pushing the Analyzer’s power switch to the Offposition.
INSTALLATIONChapter 4Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014100 of 211basic level of security. The DataGuard feature is available as an upgrade and provides support for the electronic signature regulation 21 CFR Part 11. You can enable one of these security features, but not both.This section includes information for enabling Password Protection or DataGuard. Also included are instructions on how to create a new Administrator account, and how to deactivate the Default Administrator account. You should perform both of these procedures during the installation process. For additional information about Password Protection and DataGuard, refer to Chapter 6.To enable Password ProtectionNOTE: If you are planning to activate DataGuard, there is no needto additionally activate this Password Protection feature. Instead,go to next section, “To enable DataGuard.”1. Select the DataGuard tab.2. Press the ENABLE PASSWORD button.3. After Password Protection is enabled, the Analyzer will immediately require you to log in with the following default Administrator User ID and Password:•User ID: ADMIN•Password: GEAI4. For security purposes, change the default password. Select the DataGuard tab.5. Press the CHANGE PASSWORD button.6. Enter the old password (GEAI), and press ENTER.7. Enter a new password, and press ENTER.8. Verify the new password, and press ENTER.9. Record the new password in a secure location. ALL users will be required to enter this log in information to access the Analyzer’s menus. To enable DataGuard1. Insert the USB flash drive containing the DataGuard activation into the Analyzer’s USB port.2. Press the MENU button, select the Maintenance tab, and press the ADVANCED button.3. Press the ACTIVATE OPTIONS button.4. Press the OK button and wait for the Analyzer to detect the USB flash drive.5. Press the ACTIVATE button to enable DataGuard.
.................................INSTALLATION INSTRUCTIONSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014101 of 2116. After DataGuard is enabled, the Analyzer will immediately require you to log in with the default Administrator User ID and Password. Enter the following:•User ID: ADMIN•Password: GEAI7. Go to the next section and create a new Administrator account.To create a new Administrator Account (DataGuard Only)After you activate DataGuard, create a new Administrator Account to ensure Analyzer security. Step-by-step instructions follow.1. Press the MENU button and select the DataGuard tab.2. Press the ADD USER button.3. Specify a new User ID for the administrator and press the ENTER button.4. Specify the Password for the administrator User ID and press ENTER.5. Verify the Password and press ENTER.6. Press the USER LEVEL button and select Administrator.7. Press the PASSWORD EXPIRED button and select False.8. Press the BACK button.9. Press the LOGOUT button.10. Go to the next section and delete the default Administrator account.To deactivate the Default Administrator accountAfter you have created a new Administrator account, as described in the previous section, deactivate the Default Administrator account as follows. 1. Press the LOGIN button and enter the new User ID and Password you created in the previous section.2. Press the MENU button and select the DataGuard tab.3. Press the Edit User button.4. Use the arrow buttons to highlight the Default Administrator account and press OK.5. Press the User Status button and select Inactive.6. Press the Back button to return to the Menu screen.
INSTALLATIONChapter 4Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014102 of 211Naming the Analyzer Location (Optional)To name an Analyzer LocationYou can assign a name to the Analyzer, and this name will appear with printed and exported data. This is useful if you have multiple Analyzers at your facility and want to readily distinguish data collected from each unit.1. Select the MAINTENANCE tab.2. Press the ADVANCED button.3. Press the ADVANCED SETUP button.4. Press the LOCATION button.5. Use the keypad to specify a name for the Analyzer, and then press ENTER.6. Press the NUMBER button or ALPHA button to toggle between numbers and letters.7. Press the BACK button to return to the XX.8. Press the BACK button to return to the Maintenance tab.Setting the Analyzer Mode and Reagent Flow RatesNOTE: If you are using your Laboratory or Portable TOC Analyzermodel with a GE Autosampler, do NOT proceed with this section.The Analyzer mode and reagent flow rates will be controlled bythe DataPro Software.Set the Analyzer mode for either ON-LINE or GRAB measurements. By default, the Analyzer uses automatically-calculated reagent flow rates. However, if you know the specific flow rates you want to use for each reagent, you can manually set the flow rates according to Table 5 on page 93 and Table 6 on page 93. For more information on setting flow rates, see “Setting Reagent Flow Rates” on page 89. To set the Analyzer mode and reagent flow rates1. On the Home screen, press the SETUP button. The Modify Current Method screen appears, with the currently selected mode (GRAB or ONLINE) showing in the Measurement Mode field. 2. Press the Measurement Mode arrow to select another mode:•ON-LINE— Select to measure TOC continuously from a sample stream. •GRAB — Select to measure TOC directly from a sample flask or the vial port.The Method Name field and NEW button appear.
.................................INSTALLATION INSTRUCTIONSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014103 of 2113. Press the keys on the keypad to assign a name to the method you are defining, and then press OK.4. For more information on mode selection, see “Setup” on page 88.5. Press the CONFIGURE button.6. By default the Analyzer uses the reagent flow rates that are automatically calculated. If you know the specific flow rates you want to use for each reagent, you can manually set the flow rates, according to Table 5 on page 93 and Table 6 on page 93. For more information on setting flow rates, see “Setting Reagent Flow Rates” on page 89.7. Press the MENU button to exit and save your settings.Setting Up the Data HistoryTo set up the Data HistoryBefore taking measurements, review the Archive Data setting to ensure that data is collected in the best way for your environment. By default, data is stored in the Analyzer’s flash memory, so that all measurements will be retained. If you want to change the Archive Data setting, follow these steps:1. Select the DATA tab.2. Press the SETUP HISTORY button.3. Confirm that Archive Data is set to On.NOTE: If DataGuard is enabled, data must either be sent tostorage or the serial port. See xxx for more information.Activating the Ethernet Connection and ModbusTo activate the Ethernet Connection and Modbusxxxx1.2.
INSTALLATIONChapter 4Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014104 of 211Setting Up the Printer (Optional)To set up the printerIf you installed a printer in Step 6, configure the printer port to match the printer.1. Select the I/O tab and press the PRINTER button.2. Press the PRINTER button and select your printer model, either Citizen. Seiko, or Epson. If you do not have a printer, make sure No Printer is selected.3. Press the HEADER FREQ. button and select First Page to print a header only on the first page of output or select All Pages to print a header on all pages of output.4. Press the PRINT FREQ. button and select how often you would like to print TOC data information.Enabling TurboTo enable TurboBrief description of Turbo, optional accessory purchase from ...... Turn the Turbo indicator on1. ;lkjasdf2. a;lkjadfExporting and Printing System ConstantsCalibration constants, reagent flow rates, and other key parameters are stored in the Analyzer’s memory. You should export and print the factory settings for future reference.To export the settings to a comma-separated text file1. Select the MAINTENANCE tab.2. Press the ADVANCED button.3. Press the USB I/O button. Make sure that the USB flash memory drive from the Analyzer’s accessory kit is attached to the USB port, then press the SAVE SYSTEM button. Archive the exported files in a secure location on your computer.4. Press the BACK button and then press the MENU button.
.................................INSTALLATION INSTRUCTIONSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014105 of 211To print a copy of the settingsIf you have a printer attached to the Analyzer, you can print these settings for future reference by following these steps:1. Select the tab.2. Press the ADVANCED button.3. Press the PRINT CONSTANTS button.4. Press each of the four buttons, one at a time, to print the different constants.Setting up the Data I/OTo set up the Data I/OUPDATEIf you are installing binary input, alarms, or the 4-20 mA output, configure settings for those features now. Select the I/O tab and configure the appropriate settings. Note that you may need to consult with your remote operations center to determine some values. See page 99 through page 103 for details on configuring these settings.If you installed a 4-20 mA connection or a serial connection, configure the appropriate settings now. Refer to “Setting Up Analyzer Input and Output” on page 95 for additional information. Step 11: Flush and Rinse the AnalyzerBefore placing the Analyzer into normal operation, flush the reagents to remove any gas bubbles that may have formed in the reagent lines. Next, run the Analyzer in On-line mode for 12 hours to thoroughly rinse the sample flow path.To flush the reagent syringesIf using a flask water supply, you will need the sipper tubing (with Valco fitting) from the Analyzer’s Accessories Kit. and a 1/4" open-end wrench.1. Connect to a supply of low-TOC (<50 ppb) DI water in preparation for both this reagent flush and the Analyzer rinse (described in the next section, To rinse the sample flow path on page 107).Connect to one of the following supplies of low TOC (<50 ppb) DI water:•A continuously flowing on-line stream — No additional setup is required if you connected an inlet line from a continuous low TOC (<50 ppb) DI water source in Step 8: Connect an On-Line Sample Inlet System. Proceed to step 5.
INSTALLATIONChapter 4Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014106 of 211•A large flask (1000-2000 mL) (On-Line and Portable TOC Analyzers Only) — Bypass the iOS system by removing the stainless steel tubing that connects the iOS to the Analyzer. Then, attach a sipper tube to the Inlet port located on the back of the Analyzer. Proceed to step 2. •A large flask (1000-2000 mL) (Laboratory TOC Analyzer Only) — Attach a sipper tube to the Inlet port located on the back of the Analyzer. Proceed to step 3.2. Use a 1/4" open-end wrench to loosen the Valco nut that connects the stainless steel tubing from the IOS System to the sample Inlet port.Carefully pull the stainless steel tubing out of the sample Inlet port. See Figure 34: Stainless Steel Tubing — Connecting the Analyzer and iOS on page 110.3. Insert the sipper tube’s Valco fitting into the sample Inlet port, and then tighten the Valco nut until it is finger-tight. Using a 1/4” open-end wrench, tighten the nut an additional 1/8 turn.4. Place the other end of the sipper tube into a large flask containing 1000-2000 mL of low TOC (<50 ppb) DI water.5. Verify that the Analyzer is powered On.6. If you have an ICR, verify that the ICR is configured to On (see the Analyzer’s Setup screen).7. On the Maintenance screen, select the Advanced tab.8. Press FLUSH. The Flush screen appears.9. Press the Number of Times to Move the Syringe field, and select a number from 1-20. (The default value is 3).10. Press Flush. The Analyzer begins the syringe flush process and reports the time remaining on the screen.When the syringe flush concludes, xxxxx. 11. Halt the system within the firmware (Home screen) and turn the power switch to Off. 12. Visually inspect inside the Analyzer for any leaks, especially around the DI water reservoir. If a leak is detected, make sure all fittings are tight and secure. 13. Continue to the next section, “To rinse the sample flow path.”
.................................INSTALLATION INSTRUCTIONSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014107 of 211To rinse the sample flow pathBefore you begin, ensure that you have connected to a supply of low TOC (<50 ppb) DI water, as described in the previous section, “To flush the reagent syringes” on page 105.Create a Rinse Method1. On the HOME screen, press SETUP to display the Modify Method dialog box.Replace this screenshot.2. Select Online in the Measurement Mode field.
INSTALLATIONChapter 4Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014108 of 2113. Select one of the following in the MEASUREMENT MODE field to display the corresponding Modify Method dialog box:•Online — (Figure 31: Modify Online Method Dialog Box)•Online Timed — (Figure 33: Modify TOC Removal Online Method Dialog Box)•TOC Removal Online — (Figure 33: Modify TOC Removal Online Method Dialog Box)4. If you selected Online or Online Timed in the previous step, select Stream 1 or Stream 2 in the STREAM field. To set the measurement cycle (hh:mm) for Online Timed measurements, go to the Configuration screen, select the System Setup tab, and press ONLINE SETUP. After you have set the measurement cycle, return to the Modify TOC Removal Online Method Dialog Box5. If you selected TOC Removal Online in the previous step, select Influent or Effluent in the STREAM field.Figure 31: Modify Online Method Dialog Box Figure 32: Modify Timed Online Method Dialog BoxFigure 33: Modify TOC Removal Online Method Dialog Box
.................................INSTALLATION INSTRUCTIONSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014109 of 2116. To assign/name Influent or Effluent to a specific stream (Stream 1 or Stream 2), go to the Configuration screen, select the System Setup tab, and press ONLINE SETUP.7. Press the STREAM NAME field to display the alpha/numeric keypad. Use the keypad to enter RINSE, and then press OK.8. Set the Autoreagent indicators to Off.9. Press each of the following to display a numeric keypad. Use the keypad to enter 0, and then press OK.•ACID•OXIDIZER10. Press FLUSH to display a numeric keypad. Use the keypad to enter 720. (This value = 60 min X 12 hours.) Press OK.11. If your Analyzer has an ICR, set the indicator to Off.12. If you have purchased the Turbo mode configuration, set the TURBO indicator to Off. NOTE: Turbo (a product option available fromGE Analytical Instruments) must be installed and enabled beforethe Turbo feature is active on the screen. See “To enable Turbo” onpage 104.13. Press SAVE. This will overwrite the previous Online method file, and erase any earlier settings.14. Press APPLY to return to the HOME screen.Run an Analysis with the New RINSE Method1. On the HOME screen, press RUN to begin the rinse. The rinse will run for 12 hours.2. After the rinse completes, the XX appears.3. Press XXX to close the Summary screen.4. Do one of the following:•If you used a continuously flowing on-line stream — No additional steps are required. Your Analyzer is ready to begin normal sample analyses.•If you used a large flask (1000-2000 mL) (On-Line and Portable TOC Analyzers Only) — Reconnect the iOS system by reattaching the stainless steel tubing that connects the iOS to the Analyzer. Remove the sipper tube from the Inlet port located on the back of the Analyzer, and connect the inlet tubing from your on-line water source. (You can also choose not connect an on-line water source.)
INSTALLATIONChapter 4Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014110 of 211Your On-Line or Portable TOC Analyzer is ready to begin normal sample analyses.•If you used a large flask (1000-2000 mL) (Laboratory TOC Analyzer Only) — Remove the sipper tube from the Inlet port located on the back of the Analyzer.Your Laboratory TOC Analyzer is ready to begin normal sample analyses.Graphic placeholderFigure 34: Stainless Steel Tubing — Connecting the Analyzer and iOSHow to Install Valco Tube FittingsEvaluate where to place this section after determining which tubing the user will need to install a Valco fitting, and how many section reference the tubing installation.1. Locate the sipper, sample, or other tubing? from the Analyzer’s Accessories Kit? .2. Slide the Valco fitting and the ferrule onto the sample tubing. Leave at least several millimeters of tubing extend beyond the tip of the ferrule. Make sure the orientation of nut to ferrule is as show in Figure on page 110Figure 35: Nut and Ferrule Orientation3. Push the tubing into the Sample Inlet port on the Analyzer until there is resistance, and then hold the tubing in place.4. Still holding the tubing in place, slide the ferrule and nut down the tubing into the sample Inlet port and tighten the nut until it is finger-tight.5. Use a 1/4" open-end wrench to then turn the nut 1/4 turn past finger-tight. Do not over-tighten the fitting.NOTE: It is only necessary to turn the nut 1/4 past finger-tight toswage the nut on initial installation. During future operations, onlyturn the nut 1/8 turn past finger-tight.Graphic placeholderFigure 35: Nut and Ferrule OrientationSTEP 12: INSTALL A GE AUTOSAMPLERLaboratory and Portable TOC AnalyzersIf you are planning to use a GE Autosampler with your Analyzer, you can install it now. Refer to the GE Autosampler Installation Guide for complete installation instructions.
.................................INSTALLATION INSTRUCTIONSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014111 of 211
INSTALLATIONChapter 4Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014112 of 211
5..............................................Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014113 of 2115OPERATIONOVERVIEWTHIS CHAPTER IS NOT READY FOR REVIEW AT THIS TIME. Need to update with recent firmware changes/research.WIP notes only Add this info: to text in correct places:MISCELLANEOUS NOTES FOR SECTIONS TO ADDTo sample using the iOSWith the Analyzer configured in an on-line configuration (see xxx), you can conveniently switch between on-line sampling and discrete sampling using the iOS. You do NOT need to change the configuration to analyze a standard with the iOS System. The Analyzer automatically shuts off on-line water flow when it detects that the iOS door is closed and/or a vial is inserted into the iOS.The iOS is simple to use. Simply stop analysis, slide the iOS System door open to the left, wait 30 seconds for sample to drain from the iOS System, and then insert a 40-mL vial containing sample? or the standard. Also, refer to xx for additional calibrating and operation safety x xx when operating the iOS for the first time.Additionally (one time procedure or each time?), after you establish water flow to the iOS System, you should adjust the flow rate so that flow exiting the waste line is between 30 - 300 mL/min. The flow rate is controlled by a needle valve, which is adjusted by the screw on the iOS. Turn the screw clockwise to decrease flow, and turn the screw counter-clockwise to increase flow. How do you measure the flow rate? separate stand-alone flow meter?
OPERATIONChapter 5Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014114 of 211Always stop analysis before opening the iOS System door to avoid generating erroneous measurement data. If the flow sensor is On, opening the iOS System door while analysis is taking place causes the flow sensor to activate and halt analysis. If the flow sensor is Off, opening the iOS System door while analysis is taking place results in air being drawn into the Analyzer.WarningThe iOS System contains sharp needles designed to pierce the septa of sample vials. Do not put fingers or inappropriate materials into the iOS System.XXXXXSievers M9 and M9e TOC Analyzers Operation and Maintenance ManualSAMPLING USING A SIPPER TUBEThe Analyzer Configured for Use with a Sipper Tube (Grab Mode)The Vial PortThe vial port provides a convenient sample inlet for analyzing standards in 40-mL vials. You do not need to change the sample figuration to analyze a standard in the vial port. Simply stop analysis, slide the vial port door open, and insert the 40-mL vial containing the standard.Always stop analysis before opening the vial port door to avoid generating erroneous measurements. Opening the door while analysis is taking place results in air being drawn into the Analyzer.WarningThe vial port contains two sharp needles designed to pierce the septa of sample vials. Do not put fingers or inappropriate materials into the vial port.GRAB SAMPLE INSTALLATION — FROM A SAMPLING CONTAINERMove to operations chapterTo run grab samples from a container, collect the sample using a sipper tube connected to Analyzer’s Inlet port. If your Analyzer has an iOS system, you must bypass the iOS in the grab sample setup process, as described in the following instruction. To collect grab samples from a container1. If your Analyzer does NOT have an iOS, go directly to step 42. Locate the 1/16" OD stainless steel tubing that runs from the iOS System to the bulkhead fitting labeled Sample Inlet.
.................................INTRODUCTION TO THE ANALYZER SCREENSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014115 of 2113. Use a 1/4" open-end wrench to loosen the Valco® fitting at the Sample Inlet port. Carefully rotate the tubing away from the Analyzer so that tubing is clear of the inlet. 4. Locate the sipper tube (1/16" Teflon tubing with Valco nut) that is provided in the Accessories Kit.5. Insert the Valco fitting into the Sample Inlet port, located on the left side of the Analyzer.6. Tighten the Valco fitting until it is finger-tight, and then tighten an additional 1/8 turn using a 1/4" open-end wrench.7. Place the open end of the sipper tube into the sample container, making sure that the end of the tubing is immersed in the sample. 8. Place parafilm over the container opening. Do NOT push the sipper tube through the parafilm or it may clog the tube.9. Operate the Analyzer in Grab mode. For more information on Grab mode, see “Setting the Analyzer Mode” on page 88. INTRODUCTION TO THE ANALYZER SCREENSEDITING NOTE: Screen title does NOT show on Analyzer screen. Also, there are no arrows by tabs, as all tabs are sized smaller. Screen background color may be slightly different.The Analyzer's touchscreen display changes according to the screen you select from the Standard toolbar (located on left side of the screen). Simply press one of the following buttons on the Analyzer’s Standard Toolbar to display the related screen.
OPERATIONChapter 5Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014116 of 211Navigating in the ScreensYou will find using the Analyzer Display screens is easy and intuitive. When first using the Sievers M9 or M9e TOC AnalyzerSievers M5310 C TOC Analyzer, you may find the following navigational information helpful. BUTTONSScreens include various buttons that may either initiate an action (such as, to start sampling) or display a related screen or dialog box. The button appearance may vary as shown in the following examples. Buttons may change with xxx selections..... Seamless HyperlinksThe Home screen also contains some seamless (hidden) hyperlink functionality in the consumables level and warning and error alert areas. You can tap a consumables level indicator to display the Consumables tab on the Maintenance screen, or tap the warnings and HOME(For more screen details, go to page 118.)Indicators for DataGuard enabled and Password Protection. Research these furtherPROTOCOLS System Protocols and User Defined MethodsCalibration, Pharmacopoeia Tests,Municipal Test, Validation Refer to page X for more details.CONFIGURATION Single Point Calibration, Sample Conductivity, Multi-Point Calibration, TOC Autozero, TC / IC Cell Conductivity AutozeroMAINTENANCEDATA VIEWSECURITY /DATAGUARDHELP
.................................INTRODUCTION TO THE ANALYZER SCREENSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014117 of 211error alert area to display a separate dialog box with message details and functionality. To exit screen, you MUST either click OK (intuitively I want to exit instead. What happens when I click OK? It clears or does it remain for me to go back to? would I need to as a user?TABS AND SCROLLINGSeveral screens have individual tabs that you can press to display additional related screens. Left and right arrows appear if there are additional tabs extending beyond the screen view. To see these additional tabs, flick press? the right scroll arrow. You can than use the right and left scroll arrows to navigate to the various tabs, as needed. Some screens may also include scroll arrows (left, right, up, down) to enable viewing additional data that extends beyond the border of the screen. On Analyzer screen, there are no arrows by tabs, as all tabs are sized smaller.
OPERATIONChapter 5Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014118 of 211Field SelectionsTap the down arrow to display field options for selection....create one or more setup configurations measurement mode Grab or On-Line Name and save a method Select set number of repeats and rejects set acid and oxidizer levels More fast flush and normal flush timeAutoreagent on or offTurbo on or offICR on or offUSING THE HOME SCREENUse this screen to set up and run sample analyses of TOC measurements. The Analyzer reports the sampling status and data on this screen during the process. Any warnings or errors appear on the top right of the screen, which you can tap to view the specific message(s) and access to the Diagnosis screen. You can also monitor remaining consumables’ levels from the Home screen.
.................................USING THE HOME SCREENSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014119 of 211•Create sample setup configurations•Run a sample (view any errors).•Quick view consumables•Shut down the instrumentCreating Sample Setup Configurations OVERVIEWBefore you begin, useful overview information about xxxxxxxxxxxuseful in creating sample setup configurations....UNDERSTANDING ANALYSIS TIMEFAST FLUSH AND NORMAL FLUSH .SELECTING A MEASUREMENT MODEGrabTOC Removal GrabOn-Line....•Online•Online Timed•TOC Removal OnlineSETTING REAGENT FLOW RATESxxxxNOTE: For municipal applications, we recommend decreasing theacid flow rate to 1.0 µL/min for municipal water application with analkalinity of less than 100 mg/L CaCO3. Always check the pH of yourundiluted water to ensure it is below ph3, but not less than pH2.TABLE 5: RECOMMENDED ACID FLOW RATES
OPERATIONChapter 5Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014120 of 211DO we need to change the tables to reflect municipal water application flow rates only for the M5310 C manual?USING AN ICRxxxxRUNNING SAMPLES IN TURBO MODEAutoreagentManualFAST FLUSH NORMAL FLUSH;lkjasdfTo create or change a Sampling Method? — GRAB MODECreate and save to use .....include overview grab, TOC removal grab, online, online timed, xxxxTABLE 6: RECOMMENDED OXIDIZER FLOW RATES
.................................USING THE HOME SCREENSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014121 of 2111. On the Home screen, press SETUP to display the Modify Method dialog box.2. Select Grab or TOC Removal Grab in the Measurement Mode field.3. Do one of the following:•To create a new configuration — Press NEW to display the numeric keypad. Use the keypad to enter a name for the method, and then press OK. The new name appears in the Method name field.•To change an existing configuration — Select the configuration in the METHOD NAME field. Enter new values, as needed, in steps X to X, and then go to step X to save the changes.4. Select one of the following in the Measurement Mode field:•Grab•TOC Removal Grab — With this measurement mode selection, also select either Influent or Effluent in the Vial Name field.5. Do the following:•Press REPEATS to display the numeric keypad. Use the keypad to enter a value, and then press OK.•Press REJECTS to display the numeric keypad. Use the keypad to enter a value, and then press OK.6. To use the Autoreagent feature (RECOMMENDED), set the AUTOREAGENT indicator to On. The Oxidizer and Acid indicators are now inactive. The Analyzer will automatically calculate and implement the proper reagent flow rates.
OPERATIONChapter 5Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014122 of 211NOTE: Refer to Setting Reagent Flow Rates for more information onusing the Autoreagent feature.Can the user still modify the Autoreagent rate? RICHARD CHECKING 3/21 Kurt/Paul checking 4/10(Set in manual first and then autoreagent? 7. To manually set the flow rate of the reagents, do the following:•Verify that the Autoreagent indicator is set to Off to ensure that the ACID and OXIDIZER buttons are in an active state. •Press ACID to display the numeric keypad. Use the keypad to enter a value, and then press OK.•Press OXIDIZER to display the numeric keypad. Use the keypad to enter a value, and then press OK.NOTE: For recommended reagent rates, refer to Recommended AcidFlow Rates and Recommended Oxidizer Flow Rates on pagepage 120.8. To set a new value (the default value is XX) for a fast or normal flush time, press MORE to display the More Method Configuration dialog box. Do the following:•Press inside the Fast Flush Time field to display the numeric keypad. Enter a value (in minutes), and then press OK.•Press inside the Normal Flush Time field to display the numeric keypad. Enter a value (in minutes), and then press OK.9. To operate the Analyzer with an ICR, set the ICR indicator to On. Otherwise. if your instrument does NOT have an ICR (or you want to bypass the ICR), go to the next step.10. To operate the Analyzer in Turbo mode, set the TURBO indicator to On. Otherwise. if your instrument does NOT have Turbo (or you want to run in regular mode), go to the next step.For information on Turbo mode, see “Running Samples in Turbo Mode” on page 120.11. Do one of the following:•To save as the method name showing in the Method Name field — Press SAVE. This will overwrite any previous settings saved to this name.•To save as the method with a NEW name — Press SAVE AS to display the Enter Protocol Name dialog box. Use the alpha/numeric keypad to enter a unique name, and then press OK.ICR BUTTON DOES NOT WORKWhere do I schedule (are we having) autoreagent adjustments in On-Line Mode?
.................................USING THE HOME SCREENSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014123 of 211To create or change a Sampling Method? — ONLINE MODE1. On the HOME screen, press SETUP to display the Modify Method dialog box.2. Select Online in the Measurement Mode field.
OPERATIONChapter 5Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014124 of 2113. Select one of the following in the MEASUREMENT MODE field to display the corresponding Modify Method dialog box:•Online — (Figure 36: Modify Online Method Dialog Box)•Online Timed — (Figure 38: Modify TOC Removal Online Method Dialog Box)•TOC Removal Online — (Figure 38: Modify TOC Removal Online Method Dialog Box)4. If you selected Online or Online Timed in the previous step, select Stream 1 or Stream 2 in the STREAM field. To set the measurement cycle (hh:mm) for Online Timed measurements, go to the Configuration screen, select the System Setup tab, and press ONLINE SETUP. After you have set the measurement cycle, return to the Modify TOC Removal Online Method Dialog Box5. If you selected TOC Removal Online in the previous step, select Influent or Effluent in the STREAM field.Figure 36: Modify Online Method Dialog Box Figure 37: Modify Timed Online Method Dialog BoxFigure 38: Modify TOC Removal Online Method Dialog Box
.................................USING THE HOME SCREENSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014125 of 211To assign/name Influent or Effluent to a specific stream (Stream 1 or Stream 2), go to the Configuration screen, select the System Setup tab, and press ONLINE SETUP.6. Press inside the SAMPLE NAME field (located under the ACID and OXIDIZER buttons) to display the alpha/numeric keypad. Use the keypad to enter a name (such as XYZ Building Waste Line) for the Online method, and then press OK.7. To use the Autoreagent feature (RECOMMENDED), set the AUTOREAGENT indicator to On. The Oxidizer and Acid indicators are now inactive. The Analyzer will automatically calculate and implement the proper reagent flow rates. NOTE: Refer to Setting Reagent Flow Rates for more information onusing the Autoreagent feature.Can the user still modify the Autoreagent rate? RICHARD CHECKING 3/21(Set in manual first and then autoreagent? 8. To manually set the flow rate of the reagents, do the following:•Verify that the Autoreagent indicator is set to Off to ensure that the ACID and OXIDIZER buttons are in an active state. •Press ACID to display the numeric keypad. Use the keypad to enter a value, and then press OK.•Press OXIDIZER to display the numeric keypad. Use the keypad to enter a value, and then press OK.NOTE: For recommended reagent rates, refer to Recommended AcidFlow Rates and Recommended Oxidizer Flow Rates on pagepage 120.9. To set a value for a fast or normal flush time, press MORE to display the More Method Configuration dialog box. Do the following:•Press inside the Fast Flush Time field to display the numeric keypad. Enter a value (in minutes), and then press OK.•Press inside the Normal Flush Time field to display the numeric keypad. Enter a value (in minutes), and then press OK.10. To operate the Analyzer with an ICR, set the ICR indicator to On. Otherwise. if your instrument does NOT have an ICR (or you want to bypass the ICR), go to the next step.11. To operate the Analyzer in Turbo mode, set the TURBO indicator to On. Otherwise. if your instrument does NOT have Turbo (or you want to run in regular mode), go to the next step.
OPERATIONChapter 5Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014126 of 211NOTE: Turbo (a product option available fromGE Analytical Instruments) must be installed and enabled beforethe Turbo feature is active on the screen. See “To enable Turbo” onpage 104.12. Press SAVE. This will overwrite the previous Online method file, and erase any earlier settings.Running a sampleWIP overview.....Add note All setup and then run a sample?take TOC measurementTo run a sampleWhen taking a TOC measurement of your sample, you can assign a unique sample name.1. On the Home screen, press SETUP to display the Modify . . . Method dialog box.2. Select the measurement mode to use (Grab or TOC Removal Grab or On-Line) in the Measurement Mode field.3. Select the method to use in the METHOD NAME field.4. (Optional) Assign a sample name. Press inside the Sample Name field to display the numeric keypad. Use the keypad to enter a name for the sample, and then press OK. The new name appears in the Sample Name field.5. Click APPLY to use this method and return to the Home screen.
.................................USING THE HOME SCREENSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014127 of 2116. Press RUN to begin the sampling. The sampling progress and measurement data appears on the screen in real time. NOTE: For additional information on measurement status and data,refer to “Reviewing the Home Screen” on page 127.Reviewing the Home ScreenYou can also see an alert for active Warnings and Errors and percent indicators of remaining consumables’ levels. and start and stop sample analyses., open related messages (and go to Diagnostics screen. Data from your last measured sample staysA table containing data from the last measured sample appears on the Home screen to provides TOC (IC and TC) data along with mean standard deviation (S.D.) and relative standard deviation (RSD) of the sample.percent indicators of remaining consumables’ levels, Table Last MeasurementTOC (IC and TC)Last measuredAverageS.D.R.S.D.To the right, Consumables Life visual statusAcidOxidizerUV Lamp
OPERATIONChapter 5Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014128 of 211TubingResin BedSetup button(Arrow) Start AnalysisTime Until Next MeasurementCurrent SequenceShut Down buttonLower current date and timeVIEWING CONSUMABLES LEVELSQuick view consumablesSHUTTING DOWN THE INSTRUMENTWIP If they just power off, there is a danger of corrupting database. We are running an OS just like your computer. You don’t want to just power cycle.USING THE PROTOCOLS SCREENOverview and then cross-reference to Chapter 5 Password Protection and DataGuard
.................................USING THE CONFIGURATION SCREENSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014129 of 211USING THE CONFIGURATION SCREENOverview information;lkjasdfSystem Settings (Constants) ExportYou can save system settings for any tab on the screen XXXXX Suggest before and after?(Do you have to export for each tab? Or, does it automatically export constants from every tab?) An EXPORT button is available on each tab on the Configuration window. XXXXTo export system settings (constants)1. On the Configuration screen, select the appropriate Configuration window tab,2. Verify the options selected, and press SAVE if you make any changes.3. To export the saved configuration settings, do one of the following:•To export to a USB memory device — Insert the USB memory device into one of the Analyzer’s Host USB ports, and then press EXPORT. The settings will be exported to the USB memory device.•To export through an Ethernet connection — Press EXPORT. The settings will be exported to the designated MODBUS register via Ethernet. The data can then be accessed from your company’s SCADA system or a third-party data acquisition software.
OPERATIONChapter 5Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014130 of 211The Result Preferences TabUse this procedure to set your preferences for printing and exporting results, as well as to define settings for the trend graph. The trend graph appears on the Home screen, when the ON-LINE mode is selected as the Measurement Mode on the Modify Current Online Method dialog box. To set result preferences1. On the Configuration screen, select the Result Preferences tab.2. Select any or all of the following options to set your preferences for printing and exporting results:•Print Rejected Repetitions•Automatically Print Results•Automatically Export Results3. Select one of the following result display options for the type of data to graph:•TOC/IC/TC•TOC/TCond•TOC/rCond/Temp•rCond/Temp/tCond (This option shows measurements for conductivity only, and data is indicated on the X-axis.)4. Select one of the following time ranges for the data on the X-Axis:•1 Hour•2 Hours•4 Hours
.................................USING THE CONFIGURATION SCREENSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014131 of 211•8 Hours•1 Day•2 Days•1 Week5. Select one of the following options for the TOC range on the Y-Axis:•Auto — Select to have the Analyzer automatically calculates the appropriate TOC range.•Manual — Select to activate the Min and Max fields, and then enter a specific value in ppb units in each field.6. Press SAVE. Just for the tab or all tabs on screen?The Environment Preferences TabUse this tab to set the language xxx. You can assign a name to the Analyzer that appears on printed and exported data. a name, location, and service provider for the Analyzer. This feature is particularly useful if you have multiple Analyzers at your facility and want to easily distinguish data collected from each instrument. To set the languageTo change to a new language other than the default language configured at the factory, perform the following steps.1. On the Configuration screen, select the Environment Preferences tab.1. Select one of the preferred languages for the Analyzer:•English (1st position in language option list)•Simplified Chinese (2nd position in language option list)
OPERATIONChapter 5Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014132 of 211•Japanese (3rd position in language option list)2. Press SAVE (1st button on the lower-right of screen). 3. You must restart the Analyzer for this change to take effect. On the Home screen, press the SHUT DOWN button and then restart the Instrument.To set environment preferences1. On the Configuration screen, select the Environment Preferences tab.2. (Optional) To set the Analyzer Name and Location (and Service Provider? what is meant here?), Press inside each of the following fields to display the numeric keypad. Use the keypad to enter a name, and then press OK. The new name appears in the corresponding field.•Analyzer Name•Location•Service Provider3. Select or de-select the following display preferences:•Skip Self Check at System Startup•Screensaver4. Set the timing values for archiving and backing up data. Press inside each of the following fields to display the numeric keypad. Use the keypad to enter the value (in days), and then press OK. The new number of days appears in the corresponding field.•Archive Interval (Days)•Data Age (Days)•Backup Interval (Days)5. Select one of the following for the time formats to display:•01:42:58 (am/pm)•13:42:58 (24 Hour)6. Select one of the following date formats to display:•16 Jan 2012 (Text Based)•01/16/2012 (Month First)•16/01/2012 (Day First)•2012/01/16 (Year First)7. Press SAVE.
.................................USING THE CONFIGURATION SCREENSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014133 of 211The Keyword Search TabSelect parameter options for the keyword search and that is accessed through the Data History tab on the Configuration screen. Select whether to search ALL selected fields, or only the Sample Name or Method Name field. (Need help understanding the intent of these options, as the search seems to work the same for each option??) Is the system protocol result search for searching results in all of the following? Validation History, Pharmacopoeia History, Calibration History, and Data History ....whether to search ALL selected fields, or only the Protocol Name and Vial Name?To set keyword search options1. On the Configuration screen, select the Keyword Search tab.2. Select one of the following keyword search options:•Find Records which contain All the Keywords Entered•Find Records which contain Any of the Keywords Entered•Find Records which contain Exact Keywords Entered3. Select one of the following data history search options:•Search keywords in All the Selected Fields•Search keywords in either Sample Name or Method Name4. Select one of the following system protocol result search options:•Search Keywords in All the Selected Fields•Search Keywords in either Protocol Name or Vial Name5. Press SAVE.
OPERATIONChapter 5Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014134 of 211NOTE: For more information on MODBUS, refer to “Using theEthernet Connection and Modbus” on page 149.The System Setup TabXXX•Set System Clock•Printer Setup•Network Setup•4-20mA Output Setup•Binary I/O Setup•Phamacopoeia SetupSETTING THE SYSTEM CLOCK;lkjasdf;lkjasdf
.................................USING THE CONFIGURATION SCREENSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014135 of 211To set the system clock1. On the Configuration screen, select the System Setup tab.2. Press SET SYSTEM CLOCK to display the Set System clock dialog box.3. Using the calendar, set today’s current date.4. Using the numeric keypad to the right, set the current time and select either the AM or PM option.5. Press OK to accept the settings and return to the System Setup tab.6. Press another button to change the related setting.CONFIGURING A PRINTER;lkjasdfTo configure a printer connection (optional)Connect the printer as described in xxxx1. On the Configuration screen, select the System Setup tab.2. Press PRINTER SETUP to display the Printer Configuration dialog box.
OPERATIONChapter 5Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014136 of 2113. Select ENABLE PRINTER.4. Select one of the following printer models:•Bixolon/Samsung SRP-275•Citizen CD-S500A•Epson TM-U220D5. Press OK to accept the settings and return to the System Setup tab.CONFIGURING THE NETWORKlkjasdf;lkjasdfTo configure the network connectionConnect the xxx as described in xxxx. Work with your IT department to xxxx .1. On the CONFIGURATION screen, select the System Setup tab.2. Press NETWORK SETUP to display the Network Configuration dialog box.3. Select ENABLE NETWORK.4. To use a dynamic IP address, select Automatic, and then OK. Otherwise, to the next step.5. To use a fixed IP address, select MANUAL.6. Enter the IP and net mask addresses. Press inside each field to display the numeric keypad. Use the keypad to enter the appropriate number, and then press OK. The new number appears in the individual field.
.................................USING THE CONFIGURATION SCREENSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014137 of 2117. After you have entered the full IP Address and Net Mask addresses, press OK. A confirmation message appears.8. Press OK to confirm the restart. The Analyzer automatically shuts down and restarts in order to implement the new IP setting.CONFIGURING 4-20MA OUTPUT;lkjasdfTo configure the 4-20mA output (optional)Connect the xxx as described in xxxx.1. On the Configuration screen, select the System Setup tab.2. Press 4-20MA OUTPUT SETUP to display the 4-20mA Output Configuration dialog box.3. Select 4-20MA OUTPUT. (development WIP)4. Press OK to accept the settings and return to the System Setup tab.CONFIGURING BINARY I/O INPUT;lkjerTo configure the binary I/O input (optional)Connect the xxx as described in xxxx.
OPERATIONChapter 5Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014138 of 2111. On the Configuration screen, select the System Setup tab.2. Press BINARY I/O SETUP to display the Binary I/O Configuration dialog box.3. Select ENABLE BINARY INPUT.4. Select either the LOW or HIGH Polarity option,5. Press OK to accept the settings and return to the System Setup tab.PHARMACOPOEIA OVERVIEWBecause pharmacopoeia TOC and conductivity (consider changing terminology) monographs diverge, the Analyzer allows you to specify which pharmacopoeia monograph is applicable to your environment. (You can also use the Analyzer without selecting a pharmacopoeia.) (Does one of these apply as a default?).Pharmacopoeia monographs shape the criteria for Conductivity limits and pass/fail results, as well as temperature and conductivity guidelines.Pass/Fail ReportingThe TOC Analyzer will report a Pharmacopoeia “Pass” result, if all of the selected pharmacopoeia tests pass identified criteria and limits. The TOC Analyzer will report a Pharmacopoeia “Failure” result, if any of the selected tests fail. Conductivity and TOC tests can be independently tested with the alarms, an alarm can be set for each of TOC Limit, Cond Limit, or Limits. Limits will trigger if any of the TOC or conductivity tests fail. TOC Limit only if any of the TOC tests fail, and Cond Limit only if any of the conductivity tests fail.Pharmacopoeia OptionsYou can select any combination (or none) of the following Pharmacopoeia options:USP WFI/PW: The Analyzer meets the test requirements for the United States Pharmacopoeia (USP) monographs; USP<643> Total Organic Carbon and USP<645> Conductivity. The water passes the USP<643> TOC test if its measured TOC (ru) is not more than the Limit Response, (rs – rw). The water sample passes the Stage 1 conductivity test if the measured conductivity is not greater than the table value (at the first temperature in the chart that is not greater than the measured water temperature).
.................................USING THE CONFIGURATION SCREENSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014139 of 211EP WFI/HPW: The Analyzer meets the test requirements of the following European Pharmacopoeia (EP) monographs; EP (2.2.44) Total Organic Carbon in Water for Pharmaceutical Use and the Conductivity Requirements of the EP monographs “Water for Injections” (WFI) and “Water, Highly Purified” (HPW). The TOC test passes if the measured TOC of the pharmaceutical water sample is not less than the lower of the Limit Response or 500 ppbC (per the requirements of the EP WFI and HPW monographs). The Stage 1 conductivity test passes if the measured non-temperature compensated conductivity value is not greater that the conductivity value in the table for WFI at the next lower temperature (in the table), than the measured temperature of the water (Stage 1 test in the WFI or HPW monographs). CP WFI: The Analyzer meets the test requirements of the following Chinese Pharmacopoeia (CP) monographs; CP TOC Measurement in Pharmaceutical Water- Appendix VIII R for Water for Injection and CP Conductivity- Appendix VIII S for Water for Injection. The TOC test passes if the sample of WFI has a measured TOC value not greater than (rs – rw) or 0.50 g/L. The conductivity test passes Step 1 if the measured non-temperature compensated conductivity is not greater than the table conductivity value at the next lower temperature value in the table that is not greater than the measured temperature. IP WFI: The Analyzer meets the test requirements of the India Pharmacopoeia (IP) monographs for Water for Injection: IP 2.4.30 Total Organic Carbon in Water and IP 2.4.9 Conductivity for Water for Injections in Bulk. The TOC test is passed if the measured TOC of the sample (rt) is not greater than(rs – rw) or not more than 0.5 mg/L. The Stage 1 conductivity test is passed if the non-temperature corrected conductivity is not greater than the table value for WFI at the next lowest temperature value in the table that is not greater than the measured water temperature.JP TOC: The Analyzer meets the test requirements of the Japanese Pharmacopoeia (JP) monographs; JP<2.59> Total Organic Carbon for Water for Injection and Purified Water. The test passes if the measured Water for Injection or Purified Water sample TOC value is not greater than 0.50 mg/L.EP PW: The Analyzer meets the testing requirements of the following European Pharmacopoeia (EP) monograph for Purified Water (PW); EP<2.2.44 Total Organic Carbon in Water for Pharmaceutical Use and the Conductivity Requirements of the EP monographs “Water, Purified”. The TOC test passes if the measured TOC of the pharmaceutical water sample is not less than the lower of the Limit Response or 500 ppbC (per the requirements of the EP PW monograph). The conductivity test passes if the measured conductivity (not the temperature compensated conductivity) is not greater that the value in the “Temperature and Conductivity requirements table” (in the EP PW monograph) at the measured temperature of the water. For temperatures not listed in the table, he maximal permitted conductivity is calculated by interpolation between the next lower and next higher temperature data points in the table.CP PW: The Analyzer meets the testing requirements for the following Chinese Pharmacopoeia (CP) monographs; CP TOC Measurement in Pharmaceutical Water-
OPERATIONChapter 5Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014140 of 211Appendix VIII R for Water for Injection and CP Conductivity- Appendix VIII S for Water for Injection. The TOC test passes if the sample of WFI has a measured TOC value not greater than (rs – rw) or 0.50 g/L. The conductivity test passes if the measured conductivity (not the temperature compensated conductivity) is not greater that the value in the “Temperature and Conductivity requirements table” in the CP Conductivity- Appendix VIII S (for purified water) monograph at the measured temperature of the water. For temperatures not listed in the table, he maximal permitted conductivity is calculated by linear interpolation between the next lower and next higher temperature data points in the table.IP PW: The Analyzer meets the testing requirements of the India Pharmacopoeia (IP) monographs for Water for Injection: IP<2.4.30> Total Organic Carbon in Water and IP 2.4.9 and Conductivity IP<2.4.9> for Purified Water. The TOC test is passed if the measured TOC of the sample (rt) is not greater than (rs – rw) or not more than 0.5 mg/L. The conductivity test passes Step 1, if the measured non-temperature compensated conductivity is not greater than the conductivity value in the table for Purified Water at the next lower temperature value in the table, that is not greater than the measured temperature. JP COND: The Analyzer meets the testing requirements of the Japanese Pharmacopoeia (JP) Conductivity <2.51>. The test passes if the temperature corrected conductivity is not more than 2.1 uS/cm. SELECTING A PHARMACOPOEIA MONOGRAPHBecause pharmacopoeia TOC and conductivity monographs diverge, the Analyzer allows you to specify which pharmacopoeia monograph is applicable to your environment. You can also use the Analyzer without selecting a pharmacopoeia. Refer to XX for pharmacopoeia descriptions.To specify the pharmacopoeia (optional)1. On the Configuration screen, select the System Setup tab.2. Press PHARMACOPOEIA SETUP to display the Pharmacopoeia Configuration dialog box.(development WIP)3. Select one or more of the following pharmacopoeia options (in any combination). Or, to use the Analyzer without selecting a pharmacopoeia, deselect ALL of the options.4. Press OK to accept the settings and return to the System Setup tab.THE SAVE button is not active? Should it be? When to use it-after each dialog box, tab, other change?
.................................USING THE MAINTENANCE SCREENSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014141 of 211USING THE MAINTENANCE SCREENRevise this section by summarizing the sections that describe preventative maintenance, as this is detailed in the Maintenance Chapter. Also move the troubleshooting tasks to the Troubleshooting Chapter.OverviewUse this screen in the process of performing the following preventative maintenance tasks:•Enter and track consumables expiration (Consumables Tab)•Flush reagent syringes (Advanced Tab)•Temporarily disable the screen for cleaning (Advanced Tab)You will also use this Maintenance screen to access the tabs for the following operational maintenance tasks, as described in other chapters (as listed):•Error History Tab — Review the list of errors and warnings issued by the Analyzer during operation of the instrument. Step-by-step instructions, and error/warning descriptions, are included in Chapter 9, "Troubleshooting." •Diagnostics Tab — Use this tab to perform diagnostic activities when troubleshooting operational and analyses issues, Information and instructions are included in Chapter 9, "Troubleshooting." •Advanced Tab — Use this tab to upgrade firmware, activate options, back up the database, back up settings, archive the database, calibrate the touch panel, restore the database,
OPERATIONChapter 5Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014142 of 211and restore settings. This tab and the related step-by-step instructions are included in Chapter 5, "Operation." SETTINGS (CONSTANTS) EXPORTYou can save system settings for any tab on the screen XXXXX Suggest before and after?(Do you have to export for each tab? Or, does it automatically export constants from every tab?) An EXPORT button is available on each tab on the Configuration window. XXXXTo export system settings (constants)1. On the Maintenance screen, select the appropriate Maintenance tab,2. Verify the options selected, and press SAVE if you make any changes.3. To export the saved maintenance settings, do one of the following:•To export to a USB memory device — Insert the USB memory device into one of the Analyzer’s Host USB ports, and then press EXPORT. The settings will be exported to the USB memory device.•To export through an Ethernet connection — Press EXPORT. The settings will be exported to the designated MODBUS register via Ethernet. The data can then be accessed from your company’s SCADA system or a third-party data acquisition software.The Consumables TabYou can view the expiration date and number of remaining days for the following consumables on this tab:•Acid•Oxidizer•UV Lamp•Tubing•Resin BedA triangle icon appears next to the RENEW button to indicate the severity of the expiration date: green (adequate time frame) Is there a yellow(?), or red (Expiration nearing). Use this tab to reset the expiration date after replacing a consumable item.To renew an expiration dateAfter replacing the consumables item in the Analyzer.....
.................................SETTINGS (CONSTANTS) EXPORTSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014143 of 2111. On the Maintenance screen, select the Consumables tab.2. Press the RENEW button next to the consumable item you have replaced. (feature not yet implemented)3. xxx4. xxx5. Press SAVE.The Error History TabYou can use this tab to search and view a cumulative list of recent and historical errors and warnings.To view error and warning history1. Use the vertical scrollbar to move through a list of recent messages (listed most recent to oldest). Or, use one of the following buttons to scroll through the messages:•Use the UP and DOWN arrows to skip forward and backward by a page.•Use the START and END arrows to take you to the most recent or oldest message (respectively).2. To search for messages for a specific date, press the CALENDAR icon to display the Calendar dialog box. Use the navigation arrows (as needed) to locate the date, and then press the day to view.The Analyzer automatically returns you to the Validation History tab with any messages from the selected date displayed.
OPERATIONChapter 5Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014144 of 2113. To search for messages by a keyword, User ID, Is this separate from keyword or combined with/how? AND/OR the date acknowledged, press SEARCH. Can you change the categories by which to search by?The Search dialog box appears.Otherwise, go to step 4.4. (Return to verify these steps after Search development is completed.)To include a keyword or keyword string in the search, select KEYWORD SEARCH, and then press inside the Keyword Search field to display the alpha/numeric keypad. Type a word or string of words to find.The word (or string of words) appears in the Keyword Search field.5. To include a date range in the search, do the following:•Select DATE ACKNOWLEDGED, and then press inside the Start Date field to display the Start Date dialog box. Use the navigation arrows (as needed) to locate the date, and then press the first day in the range to view.The Analyzer automatically returns you to the Search dialog box. •Press inside the END DATE field to display the End Date dialog box. Use the navigation arrows (as needed) to locate the date, and then press the last day date in the range to view.6. Press SEARCH. The Analyzer returns to the Search dialog box, and displays the messages meeting the search criteria. (Return to modify these steps after Search development is completed.)7. Use the horizontal scrollbar to move to the right and back to left to view message information, such as Date Occurred, Message (Text), Acknowledged By, and Date Acknowledged.8. To view additional details of any message, select the message line and press DETAIL. A summary of the message appears including additional information, such as error level (Error or Warning) and module reported.9. Press OK to return to the Error History tab.
.................................SETTINGS (CONSTANTS) EXPORTSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014145 of 211The Diagnostics TabWIP•xxfluidics•xxcell conductivity•xxUV lamp•xxsystem diagnostics•xxcheck modules•xxanalog and binary I/O•xxtest printer•xxtest Ethernet port•xxtest USB port
OPERATIONChapter 5Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014146 of 211The Advanced TabUse the Advanced tab to xxxx•Disable the touchscreen while cleaning•Flush the syringes•upgrade firmware•activate options•calibrate touch panel•back up the database•restore database•archive databaseCleaning the AnalyzerThis section includes suggested cleaning supplies and instructions for cleaning the Analyzer’s external housing and touchscreen.To clean the external housingYou will need a clean, soft cloth dampened with water or a non-abrasive cleaner, and another clean, dry soft cloth.1. Turn off power to the Analyzer and disconnect it from the main power source.2. Wipe the external housing with a clean cloth dampened with water or a non-abrasive cleaner.
.................................SETTINGS (CONSTANTS) EXPORTSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014147 of 2113. Wipe dry with another clean, dry soft cloth.To clean the touchscreenYou will need a clean, soft (and dry) cloth or cotton pad. You may add a small amount of methanol or isopropyl alcohol to the cloth, but ensure that all solvent residue is removed first.1. Disable the screen for cleaning. On the Maintenance screen, select the Advanced tab.2. Press CLEAN SCREEN to temporarily disable the screen for 30 seconds. Repeat, as needed, if the 30-second time frame expires while cleaning.3. Wipe the touchscreen with a clean, soft (and dry) cloth or cotton pad.Flushing the syringesFirmware development in progress.Upgrading the FirmwareResearch - information is not available in Demo.WARNINGAlways apply liquid to the cloth directly, and do NOT spray liquids directly on the Analyzer.Do NOT use water or cleaners on the touchscreen, as water can damage or discolor the polarizer. Refer to the next section for recommendations on cleaning the touchscreen. WARNINGDo NOT use water as water can damage or discolor the polarizer. Clean any condensation or moisture immediately.
OPERATIONChapter 5Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014148 of 211Activating DataGuard and Turbo Options1. On the Maintenance screen, select the Advanced tab.1. Select the option or options to activate. add text about must purchase.2. Press CONTINUE to display the Login Dialog box.3. Development in progress?Calibrating the Touch PanelxxxxxUnder development1. ;lkjadf2. ;lkjadf3. ;lkjadf4.
.................................USING THE DATA VIEW SCREENSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014149 of 211Backing up the DatabasexxxxxIs the ability to perform this action set up in DataGuard (thus the user ID/password)?1. ;lkjadf2. ;lkjadf••back up the database•restore database•archive databaseUSING THE DATA VIEW SCREENexporting data historyUSING THE SECURITY/DATAGUARD SCREENOverview informationUSING THE HELP SCREENOverview InformationUSING THE ETHERNET CONNECTION AND MODBUSdifferent from 900Figure 39: USB Connection Locations
OPERATIONChapter 5Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN EN Rev. A GE Analytical Instruments © 2014150 of 211Figure 40: XXUSING THE SECURITY/DATAGUARD SCREENSeparate maintenance and troubleshooting chapter????
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6..............................................Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014153 of 211PASSWORD PROTECTIONOVERVIEWXXXXXAdd note DataGuard does NOT apply to MC3e.
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7..............................................Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014155 of 211CALIBRATION AND VERIFICATIONOVERVIEWXXXXXVerify not including System Suitability in 900e. USING THE PROTOCOLS SCREENSystem Protocols and User Defined MethodsSystem ProtocolsCalibrationSingle Point CalibrationSample ConductivityMulti-point CalibrationTOC AutozeroTC / IC Cell Conductivity AutozeroPharmacopoeia TestSystem SuitabilityAccuracy / Precision
CALIBRATION AND VERIFICATIONChapter 7Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014156 of 211ValidationPROTOCOL 1 TESTTEST SINGLESOURCE;lkjasdf;kljadsf•;lkjasdflkjasdf•asd;flkjasdf;lkjasdf•;lkjasdf;lkjasdfheading 2;lkjasdf;lkjasdfas;lkjsdfHEADING 3;lkjaadf;lkjasdf;lkjasdf;lkjafdHeading 4;lkj;lkj;kljasdf;lkjasdf;lkjasdf
.................................TEST SINGLESOURCESievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014157 of 211THIS PAGE IS INTENTIONALLY LEFT BLANK.
CALIBRATION AND VERIFICATIONChapter 7Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014158 of 211
8..............................................Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014159 of 211MAINTENANCEThis chapter is a WIP. An outline (as requested) is provided for the safety review.OVERVIEWTo ensure optimum performance of the Analyzer, perform the routine maintenance tasks described in this chapter, and follow the recommended maintenance schedule outlined in this chapter for the routine replacement of Analyzer consumables. Chemical reagents, the in-line filter, UV lamp, and pump tubing MUST be purchased from GE Analytical Instruments. NOTE: The use of reagents from other sources—or the failure toreplace the reagents on the prescribed replacement schedule—willinvalidate the Analyzer’s warranty.This chapter applies to ALL Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer instrument models, except where noted. Step-by-step instructions for replacing consumables are included, along with a convenient one-year Preventative Maintenance record log. See Figure 44: 1-Year Maintenance Record Log (in the following section) for the recommended maintenance schedule. Review and complete this record log to help you track and ensure that all required preventive maintenance is performed on a regular schedule.Service Kits for non-routine maintenance items are available from GE Analytical Instruments, and come with step-by-step instructions, as needed.If you need additional assistance when performing this preventative maintenance, contact GE Analytical Instruments Technical Support at 800.255.6964. Technical Support in the United
MAINTENANCEChapter 8Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014160 of 211Kingdom is available at 44 (0) 161 864 6800. In other countries, visit www.geinstruments.co to locate your representative. Training by a qualified service technician also can be provided.Interior Views of the AnalyzerLocate the diagram for your Analyzer model (On-Line, Laboratory, or Portable) in this section, and refer to it as needed for performing the preventative maintenance described in this chapter.Figure 41: Interior Overview — On-Line TOC AnalyzerFigure 42: Interior Overview — Laboratory TOC AnalyzerFigure 43: Interior Overview — Portable TOC AnalyzerUSING THE MAINTENANCE SCREENOverviewYou will use this screen in the process of performing the following preventative maintenance tasks:•Entering and tracking consumables expiration (Consumables Tab)•Flushing reagent syringes (Advanced Tab)•Temporarily disabling the screen for cleaning (Advanced Tab)
.................................PERFORMING ROUTINE MAINTENANCE TASKSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014161 of 211You will also use this Maintenance screen to access the tabs for the following operational maintenance tasks, as described in other chapters (as listed):•Error History Tab — Review the list of errors and warnings issued by the Analyzer during operation of the instrument. Step-by-step instructions, and error/warning descriptions, are included in Chapter 9, "Troubleshooting."•Diagnostics Tab — Use this tab to perform diagnostic activities when troubleshooting operational and analyses issues, Information and instructions are included in Chapter 9, "Troubleshooting."•Advanced Tab — Use this tab to upgrade firmware, activate options, back up the database, back up settings, archive the database, calibrate the touch panel, restore the database, and restore settings. This tab and the related step-by-step instructions are included in Chapter 5, "Operation."PERFORMING ROUTINE MAINTENANCE TASKS;lkjasdf;kljadsf:•Flushing Reagent Syringes•Maintaining the DI Water Reservoir Level•Cleaning the AnalyzerFlushing Reagent SyringesIf the Analyzer has not been used for over 24 hours, the decomposition of persulfate can produce oxygen bubbles in the syringe pump and the reagent addition lines. To prevent bubbles from entering the sample stream and interfering in the TOC measurement, a reagent flush is used to remove the bubbles and fill the syringe with fresh reagent. A reagent flush also is recommended after installing new chemical reagents.For the reagent flush, the Analyzer must be connected to a water supply. A 40-mL vial of water, or on-line water, may be used for the reagent flush. Firmware development in progress.xxxxUse the Advanced Tab .....To flush the reagent syringes1. ;lkjadsf2.
MAINTENANCEChapter 8Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014162 of 211Maintaining the DI Water Reservoir LevelPeriodically check xxxxx and fill the reservoir as neededSingle-source from Installation Chapter.To fill the DI water reservoir1. ;lkjasdf2. ;lkajsdf3. ;lkjasdfCleaning the AnalyzerAlong with replacing consumables, you will need to clean the house and touchscreen, as part of your routine preventative maintenance tasks.This section includes suggested cleaning supplies and instructions for cleaning the Analyzer’s external housing and touchscreen.To clean the external housingYou will need a clean, soft cloth dampened with water or a non-abrasive cleaner, and another clean, dry soft cloth.1. Turn off power to the Analyzer and disconnect it from the main power source.2. Wipe the external housing with a clean cloth dampened with water or a non-abrasive cleaner.3. Wipe dry with another clean, dry soft cloth.To clean the touchscreenYou will need a clean, soft (and dry) cloth or cotton pad. You may add a small amount of methanol or isopropyl alcohol to the cloth, but ensure that all solvent residue is removed first.WARNINGAlways apply liquid to the cloth directly, and do NOT spray liquids directly on the Analyzer.Do NOT use water or cleaners on the touchscreen, as water can damage or discolor the polarizer. Refer to the next section for recommendations on cleaning the touchscreen.
.................................REPLACING CONSUMABLES OVERVIEWSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014163 of 2111. Disable the screen for cleaning. On the Maintenance screen, select the Advanced tab.2. Press CLEAN SCREEN to temporarily disable the screen for 30 seconds. Repeat, as needed, if the 30-second time frame expires while cleaning.3. Wipe the touchscreen with a clean, soft (and dry) cloth or cotton pad.REPLACING CONSUMABLES OVERVIEWXXXXX:•Replacing Consumable Items•Replacing the UV Lamp•Replacing the Pump Heads•Replacing the Resin Cartridge•Replacing the UV Lamp•Replacing the In-Line Filter Element•Replacing the ICR Chemical Trap (ICR users ONLY)Maintenance SchedulexxxxxAdd Maintenance table - Mention reagent replacement data collected by RFIDWhy write these down when they are available in the instrument?chemical trap (ICR-optional) - 1 yr.Figure 44: 1-Year Maintenance Record LogTracking Consumables Expiration DatesYou can view the expiration date and number of remaining days for the following consumables on this tab:WARNINGDo NOT use water as water can damage or discolor the polarizer. Clean any condensation or moisture immediately.
MAINTENANCEChapter 8Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014164 of 211•Acid•Oxidizer•UV Lamp•Tubing•Resin BedA triangle icon appears next to the RENEW button to indicate the severity of the expiration date: green (adequate time frame) Is there a yellow(?), or red (Expiration nearing). Use this tab to reset the expiration date after replacing a consumable item.To renew an expiration dateInclude a note about the RFID tracking of Reagent Consumables. This Consumables section should only be used to enter older GE manufactured cartridges that do not include RFID technology (i.e. Model 900 cartridges).Include a second note that the Analyzer automatically configures reagent information using the RFID technology.After replacing the consumables item in the Analyzer.....1. On the Maintenance screen, select the Consumables tab.2. Press the RENEW button next to the consumable item you have replaced. (feature not yet implemented)3. xxx4. xxx5. Press SAVE.Replacing Consumable Items;lkjasdf;lkjasdf:•Replacing the Resin Cartridge•Replacing the Chemical Reagents•Replacing the UV Lamp•Replacing the Pump Heads•Replacing the In-Line Filter Element•Replacing the ICR Chemical Trap (ICR users ONLY)
.................................REPLACING CONSUMABLES OVERVIEWSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014165 of 211REPLACING THE RESIN CARTRIDGEReplacing the Ion Exchange xxxSingle-Source from the installation chapter.To replace the resin cartridge1. ;lkjadsf2.REPLACING THE CHEMICAL REAGENTS;lkjasdfFollow with flushing the reagent syringes as described in the previous section.To replace the reagent cartridges1. ;lkjadsf2.Using a vialREPLACING THE UV LAMP;lkjasdfTo replace the UV Lamp1. ;lkjadsf2.REPLACING THE PUMP HEADSxxxx(previously replacing the sample pump tubing...mention this advantage)To replace the pump heads1. ;lkjadsf2.REPLACING THE IN-LINE FILTER ELEMENTxxxx
MAINTENANCEChapter 8Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014166 of 211To replace the in-line filter element1. ;lkjadsf2.3.REPLACING THE ICR CHEMICAL TRAP (ICR USERS ONLY)xxxxTo replace the chemical trap1. ;lkjadsf2.3.4.
9..............................................Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014167 of 211TROUBLESHOOTINGOVERVIEWXXXXXThe Diagnostics TabWARNING AND ERROR MESSAGESAdd link messages.InspectConstants
TROUBLESHOOTINGChapter 9Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014168 of 211ErrorDiagnosticsICEFOMEFlow BackflowOxidizer DataUSING THE HELP SCREENOverfilling the DI Water reservoirxxxxxTo drain excess water from the DI water reservoirYou will need the Dispensing bottle (with attached filling fixture) and the individual (loose) elbow fitting from the Analyzer’s Accessories Kit. You will also need a flask or beaker (size?) to collect the excess DI water.1. Press the latch of the Prime port down and insert the individual (loose) elbow fitting,2. Remove the tip of the dispensing bottle from the tubing of the Dispensing bottle assembly. See Figure 45: Dispensing Bottle Tip.3. Press the latch of the DI pump outlet up and insert the elbow-fitting end of the tubing into the DI pump outlet. (The outlet is located between the IC and TC sample pumps). Reference Figure 22: Inserting the DI Loop Fill Tube.)4. Direct the other end of the tubing into a flask or beaker, located below the DI pump outlet. The water will automatically flow out the tubing in this gravity-drain position.5. Verify that the water line is JUST BELOW the top of the reservoir, as shown in Figure 23: Filling the DI Water Reservoir (with attached filling fixture).Figure 45: Dispensing Bottle Tip
.................................WARNING AND ERROR MESSAGESSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014169 of 211The Error History TabYou can use this tab to search and view a cumulative list of recent and historical errors and warnings.To view error and warning history1. Use the vertical scrollbar to move through a list of recent messages (listed most recent to oldest). Or, use one of the following buttons to scroll through the messages:•Use the UP and DOWN arrows to skip forward and backward by a page.•Use the START and END arrows to take you to the most recent or oldest message (respectively).2. To search for messages for a specific date, press the CALENDAR icon to display the Calendar dialog box. Use the navigation arrows (as needed) to locate the date, and then press the day to view.The Analyzer automatically returns you to the Validation History tab with any messages from the selected date displayed.3. To search for messages by a keyword, User ID, Is this separate from keyword or combined with/how? AND/OR the date acknowledged, press SEARCH. Can you change the categories by which to search by?The Search dialog box appears.Otherwise, go to step 4.4. (Return to verify these steps after Search development is completed.)To include a keyword or keyword string in the search, select KEYWORD SEARCH, and then press inside the Keyword Search field to display the alpha/numeric keypad. Type a word or string of words to find.The word (or string of words) appears in the Keyword Search field.
TROUBLESHOOTINGChapter 9Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014170 of 2115. To include a date range in the search, do the following:•Select DATE ACKNOWLEDGED, and then press inside the Start Date field to display the Start Date dialog box. Use the navigation arrows (as needed) to locate the date, and then press the first day in the range to view.The Analyzer automatically returns you to the Search dialog box. •Press inside the END DATE field to display the End Date dialog box. Use the navigation arrows (as needed) to locate the date, and then press the last day date in the range to view.6. Press SEARCH. The Analyzer returns to the Search dialog box, and displays the messages meeting the search criteria. (Return to modify these steps after Search development is completed.)7. Use the horizontal scrollbar to move to the right and back to left to view message information, such as Date Occurred, Message (Text), Acknowledged By, and Date Acknowledged.8. To view additional details of any message, select the message line and press DETAIL. A summary of the message appears including additional information, such as error level (Error or Warning) and module reported.9. Press OK to return to the Error History tab.The Diagnostics TabWIP•xxfluidics•xxcell conductivity•xxUV lamp
.................................WARNING AND ERROR MESSAGESSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014171 of 211•xxsystem diagnostics•xxcheck modules•xxanalog and binary I/O•xxtest printer•xxtest Ethernet port•xxtest USB port
TROUBLESHOOTINGChapter 9Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014172 of 211
10..............................................Sievers M9 and M9e TOC AnalyzersSievers M5310C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014173 of 211TURBO OPERATIONOVERVIEWXXXXX
TURBO OPERATIONChapter 10Sievers M9 and M9e TOC AnalyzersSievers M5310C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014174 of 211THIS PAGE IS INTENTIONALLY LEFT BLANK.
A..............................................Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014175 of 211Appendix A: WARNINGSWorking with IntertekEnglishWARNINGSShipping boxes containing an Analyzer with built-inoptional components may weigh over 40 lb —necessitating a two-person lift technique when handling.Such boxes are labeled with this warning, supportingOSHA standards intended to protect employees frominjury. We recommend that our customers use a two-person lift,and GE requires that ALL employees use this handlingtechnique when lifting items weighing over 40 lb.This symbol on the instrument indicates that the usershould refer to the manual for operating instructions.If this instrument is used in a manner not specified byGE Analytical Instruments, the safety protection providedby the instrument may be impaired.
WARNINGSAppendix ASievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014176 of 211(On-Line TOC Analyzer) This symbol indicates theprotective earth terminal (ground) for the Analyzer.The Analyzer requires an A/C mains supply of 100-240volts, and requires the correct power cord for safeoperation. ONLY use the power cord supplied in theAnalyzer’s Accessory Kit with the Analyzer, which meetsthis A/C mains supply requirements.For safety reasons and to avoid the possibility ofcorrupting the database, ALWAYS follow this procedurewhen shutting down the Analyzer. First stop analysis ANDstop the operating system (using the HALT SYSTEM buttonin the Analyzer’s firmware) BEFORE pressing theAnalyzer’s power switch to Off or unplugging the powercord, Any operation requiring access to the inside of theAnalyzer, including installation of maintenance items,could result in injury. To avoid potentially dangerousshock—BEFORE opening the Analyzer—first stop anyanalysis, stop the operating system (using HALT SYSTEMbutton in the Analyzer’s firmware), and then turn offpower and disconnect from the power supply Electrical conduit should be installed by a qualifiedelectrician. Also, before installing any wiring inside theAnalyzer, make sure you are wearing ESD protection.The output and alarm connections should be installed bya qualified electrician. Also, before installing any wiringinside the Analyzer, make sure you are wearing ESDprotection.This is a Class A product. In a domestic environment, thisproduct may cause electromagnetic interference in whichcase the user may be required to take adequatemeasures to correct the interference.To protect against accidental exposure to ultra-violetradiation, do not operate the UV lamp outside of itsprotective housing.WARNINGS
.................................WARNINGSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014177 of 211(On-Line and Portable TOC Analyzers) Water in the iOSSystem may be hot. Before inserting a vial into the iOSSystem after operating in on-line mode, slide the dooropen and wait 30 seconds to allow sample to completelydrain. Inserting a vial before draining can result in hotwater spray projecting upward out of the iOS System orvial port.The iOS System and vial ports contain sharp needlesdesigned to pierce the septa of sample vials. Do NOT putfingers or inappropriate materials into the iOS System orvial port.When servicing parts inside the Analyzer, ensure thatpower to the Analyzer is off, and keep hands clear of thereagent syringe assemblies. The syringes are controlledby moving parts that can pinch skin.(Laboratory and Portable TOC Analyzers) For continuedprotection against fire hazard, replace fuse with sametype and rating.WARNINGS
WARNINGSAppendix ASievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014178 of 211WARNINGSChanges or modifications to the RFID radio not expressly approved bythe party responsible for compliance could void the user's authority tooperate the equipment.This device complies with Part 15 of the FCC Rules & Industry Canadalicense-exempt RSS standards. Operation is subject to the following twoconditions: (1) This device may not cause harmful interference, and (2) This device must accept any interference received, includinginterference that may cause undesired operation.The RFID antenna is a Part 15 & RSS-210 - Class A digital device: This equipment has been tested and found to comply with the limits fora Class A digital device, pursuant to part 15 of the FCC Rules. Theselimits are designed to provide reasonable protection against harmfulinterference when the equipment is operated in a commercialenvironment. This equipment generates, uses, and can radiate radiofrequency energy and, if not installed and used in accordance with theinstruction manual, may cause harmful interference to radiocommunications. Operation of this equipment in a residential area islikely to cause harmful interference in which case the user will berequired to correct the interference at his own expense.This equipment complies with FCC electromagnetic radiation exposurelimits set forth for an uncontrolled environment. This equipment shouldbe installed and operated with a minimum separation distance of 20cm(7 in.) between the RFID antenna and your body. The antenna is locatedon the inside floor of the Analyzer near the front of the syringeassemblies.
.................................WARNINGSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014179 of 211HAZARDOUS MATERIAL DISPOSALThe following guidelines are provided to aid you in discarding and the disposal of hazardous substances related to the Sievers M9 and M9e TOC AnalyzersSievers M5310 C Analyzer.OPERATIONAL CAUTIONSTo ensure optimal sampling results and to protect the instrument from any damage, review and implement the following Caution statements.HAZARDOUS MATERIAL DISPOSALHazardous reagents (ammonium persulfate and phosphoric acid) areused in the Analyzer. The waste stream from the instrument is acidic andmust be disposed of properly. Consult your federal, state, and localgovernment regulations.The UV lamp and the display screen contain mercury and may beconsidered hazardous material in your local area. Dispose of these itemsin accordance with federal, state, or local government regulations.In the case of any broken or damaged UV lamp, handle the remains inaccordance with your organization’s toxic waste handling procedureand dispose of them in accordance with federal, state, or localgovernment regulations.This symbol indicates the European Union Directive 2002/96/ECfor waste electrical and electronic equipment (WEEE) requiresdisposing the Analyzer separately from standard waste.CAUTIONSMake sure the DI water Reservoir is full, particularly when runningsamples with high TOC or high salt concentrations. After running highTOC or salt samples, always rinse the Analyzer by running low-TOC DIwater through a sample cycle. To avoid false TOC readings and possible damage to the Analyzer,always make sure the sample inlet is open and the DI water reservoir isfilled before starting analysisOperation of the Analyzer without the in-line filter on the sample inletline will damage the Analyzer and void the warranty. To avoid damagingthe Analyzer, install the filter and replace the filter element, as needed.
WARNINGSAppendix ASievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014180 of 211To avoid false TOC readings and possible damage to the Analyzer,always make sure the sample is flowing through the iOS System and theDI water reservoir is filled before starting analysis.For performance within specifications on ozonated water systems, anOzone Destruct Kit must be purchased from GE Analytical Instrumentsand installed according to instructions.When cleaning the Analyzer, always apply liquid to the cloth directly,and do NOT spray liquids directly on the Analyzer.Do NOT use water or cleaners on the touchscreen, as water candamage or discolor the polarizer. Refer to the next section forrecommendations on cleaning the touchscreen. Wipe away any condensation immediately.CAUTIONS
.................................WARNINGSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014181 of 211中文 (Chinese)警告装有分析仪及内置可选组件的发货箱的重量可能超过40 磅，移动时需要由两个人抬起。此类重量的箱子贴有此警告，意在遵循保护员工免受伤害的 OSHA 标准。我们建议用户由两个人抬起重物，GE 要求所有员工在移动 40 磅重量以上的物体时，均采取两人抬起的方法。仪器上标有此符号表示用户应参考手册上的操作说明。如果该仪器以 GE Analytical Instruments 公司所未规定的方式使用，该仪器所提供的保护作用可能会被削弱。（在线型 TOC 分析仪）此符号表示分析仪的保护性接地端 （地线）。分析仪要求 100-240 伏的 A/ C 电源及正确的电源线，以保证安全工作。只可使用分析仪配件包中提供的电源线，该电源线符合分析仪的 A/ C 电源要求。出于安全考虑，并且为了避免损坏数据库，在关机时应始终按照以下操作程序。在将分析仪的电源开关切换到关闭或拔掉电源线之前，应首先停止分析，并且停止正在运行的系统 （用分析仪固件中的系统停机按键）。任何需要接触分析仪内部的操作，包括安装维修件，均可能导致人身伤害。为避免可能的电击伤害，在打开分析仪机壳之前，应首先停止任何分析，并停止正在运行的系统 （用分析仪固件中的系统停机按键），然后关闭电源开关，并断开电源连接。应由合格的电工来安装电气管路。在分析仪内安装和布线之前，应确保佩戴 ESD 保护。应由合格的电工来安装输出和警报连接。在分析仪内安装和布线之前，应确保佩戴 ESD 保护。
WARNINGSAppendix ASievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014182 of 211有害物质处理以下指导帮助您正确处理和弃置 Sievers M9 and M9eM5310 C TOC 分析仪使用的有害物质。本产品为 A 类产品。在家庭环境中，本产品可能导致电磁干扰，用户可能需要采取适当措施以减少干扰。为防止意外暴露在紫外线放射下而导致伤害，请勿将紫外线灯置于保护罩之外。（在线型和便携式TOC分析仪）iOS 系统中的水可能会很热。在在线模式下运行之后，请将门滑开，等待 30秒，使样品完全排空，然后将样品瓶插入 iOS 系统。如果在排空之前插入样品瓶，可能导致热水向上喷射出iOS 系统或样瓶端口。IOS 系统和试剂瓶槽含有两个锐利的针头，用于刺穿试样试剂瓶的封口膜。请不要将手指或其它不适当的物体放入 IOS 系统或试剂瓶槽。在维修分析仪中的部件时，应先确保关闭分析仪的电源，不可将手靠近试剂注射器部件。注射器由移动部件控制，可能会夹伤皮肤。（实验室型和便携式TOC分析仪）为预防火灾，请使用相同类型和规格的保险丝进行更换。有害物质处理此分析仪使用危险试剂 （过硫酸铵和磷酸）。分析仪排出的废液呈酸性，必须妥善处理。应按照联邦、州／省或地方政府的相关规定进行处理。紫外线灯和显示屏含有汞，在您所在的地区可能被视为危险材料。处理这些材料时，请遵循国家、州／省或地方政府的相关规定。如果紫外线灯破损或损坏，应根据您所在单位的有毒废料处理程序以及联邦、州／省或地方政府的相关规定进行处理。警告
.................................WARNINGSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014183 of 211操作注意事项为了确保最佳取样结果，并且保护仪器不受损坏，请阅读并执行注意事项。此符号表示根据欧盟废电机电子设备 (WEEE) 指令 2002/96/EC，分析仪应以不同于普通废品的方式处理。注意事项应确保 DI 水容器中装满水，特别是在测试高 TOC 或高盐浓度的试样时尤其如此。在测试完高 TOC 或高盐浓度的试样后，请务必使用低 TOC 的 DI 水冲洗样品环路。为避免 TOC 读数错误或损坏分析仪，在开始分析前必须保证试样进口打开且 DI 水容器已满。在进样管中没有安装联线过滤器的情况下操作分析仪，会损坏仪器并使保修失效。为了避免损坏分析仪，应安装过滤器，并根据需要按时更换滤芯。为了避免错误的 TOC 读数，为了避免损坏分析仪，在开始分析之前，请务必确保样品流经 iOS 系统，确保 DI 水容器中装满水。对于在臭氧水系统规格内的运行，必须从GE Analytical Instruments 购买臭氧破坏套件，并按说明进行安装。在清洁分析仪时，应将清洁液放在抹布上，不可将清洁液直接喷洒在分析仪上。不可在触摸屏上使用水或清洁剂，水可以使偏振片损坏或褪色。请参阅后面的章节了解触摸屏的清洁方法。应立即擦去触摸屏上的冷凝水。有害物质处理
WARNINGSAppendix ASievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014184 of 211日本語 (Japanese)警告内蔵のオプション コンポーネントを備えた分析装置を含む発送用箱は 40 lb (18 kg) を超える重さがある可能性があり、取り扱う時には 2 人で持ち上げる方法が必要になります。 このような箱にはこの警告が記されたラベルが貼られ、従業員を怪我から守ることを目的とした OSHA 基準に対応しています。お客様は 2 人で持ち上げる方法を用いることをお勧めします。そして GE では、40 lb (18 kg) を超える重さがある製品を持ち上げる時にはすべての従業員がこの取扱方法を用いることを求めています。機器についているこの記号は、ユーザーが操作指示書を参照する必要があることを示します。この機器が GE Analytical Instruments によって指定された方法で使用されなかった場合、機器に組み込まれた保護機能は損なわれます。(オンライン型 TOC 分析装置) このマークは、分析装置の保護アース端子 ( グランド ) を示しています。分析装置は 100 ～ 240 ボルトの A/C 主電源を必要とし、安全な運転のために正しい電源コードを必要とします。 分析装置アクセサリ キットに付属の電源コードのみを使用してください。このコードは A/C 主電源の要件を満足します。安全のため、そしてデータベースを破損する可能性を避けるため、分析装置の電源を切る時には必ずこの手順に従ってください。 分析装置の電源スイッチを押してオフ (Off) にするか、電源コードを抜く前に、まず分析を停止し、かつオペレーティング システムを停止します ( 分析装置のファームウェアのシステム停止 (HALT SYSTEM) ボタンを用いて )。保守品目の取り付けを含む、分析装置内部にアクセスするいかなる操作も、人身傷害につながる可能性があります。 分析装置を開ける前に、潜在的に危険な衝撃を避けるために、まず分析を停止し、オペレーティング システムを停止し ( 分析装置のファームウェアにあるシステム停止 (HALT SYSTEM) ボタンを用いて )、その後、電源を切り、電源供給から切り離します。
.................................WARNINGSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014185 of 211電気導管は、有資格の電気技術者が行ってください。 また、分析装置内部の配線を行う前に、静電気放電防止用ストラップを着用するようにしてください。出力および警報の接続は、有資格の電気技術者が行ってください。 また、分析装置内部の配線を行う前に、静電気放電防止用ストラップを着用するようにしてください。これはクラス A の製品です。 屋内環境においては、この製品は電磁干渉を発生することがあり、その場合はユーザーが適切な是正措置を取る必要があります。紫外線への偶発的な曝露から身を守るために、保護容器の外で UV ランプを作動させないでください。(オンライン型およびポータブル型 TOC 分析装置) iOS システム内の水が加熱している場合があります。 オンライン モードでの運転後にバイアルを iOS システムに挿入する前に、ドアをスライドさせて開け、30 秒間待ち、サンプルが完全に排水されるようにしてください。 排水前にバイアルを挿入すると、iOS システムまたはバイアル ポートから熱水が噴出するおそれがあります。iOS システムおよびバイアル ポートには、サンプル バイアルのセプタムを穿孔するように設計された鋭利なニードルが含まれています。 指や不適切な物質を iOS システムやバイアル ポートに入れないようにしてください。分析装置の内部にある部品を修理する際、分析装置への電源が切れていることを確認し、試薬シリンジ アセンブリに手を近付けないようにしてください。 シリンジは、指を挟む危険のある可動部品によって制御されています。(ラボ型およびポータブル型 TOC 分析装置) 火災の危険から引き続き守るために、同じ型式で定格のフューズと交換してください。警告
WARNINGSAppendix ASievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014186 of 211有害物質処分以下の指針は、SieversM9 and M9eM5310 C TOC 分析装置に関連した有害物質を廃棄および処分するうえで支援するために示されています。操作上の注意最適なサンプリング結果を確保するため、そして機器を損傷から守るために、以下の注意に関する記述を見直し、実践してください。有害物質処分分析装置には危険な試薬 ( 過硫酸アンモニウムやリン酸 ) が使用されています。 機器から出る排水は酸性であり正しい方法で廃棄する必要があります。 国、州、および地方自治体の政府規制に従ってください。UV ランプおよびディスプレイ画面には水銀が含まれており、地域によっては水銀が有害物質に指定されている場合があります。 これらの部品は、国や地方自治体の規制に従って処分してください。UV ランプが切れたか損傷を受けた場合は、社内の有害廃棄物取扱手順に従って残留物を取り扱い、国、都道府県、または地方自治体の規則に従って処分してください。この記号は、廃電気電子機器 (WEEE) に関する EU 指令 2002/96/EC では、標準の廃棄物とは別に分析装置を処分することを求めていることを示します。注意DI 水リザーバーが満杯になっていることを確認してください。特に、TOC または塩分の濃度が高いサンプルを使用する場合に重要です。 TOC または塩分の濃度が高いサンプルを使用した後は、サンプル サイクルを通じて 低 TOC の DI 水を流すことで、必ず分析装置を洗浄してください。 誤った TOC 測定値および分析装置に対する損傷の可能性を避けるために、分析を開始する前に、サンプル注入口が開いていて、DI 水リザーバーが満杯になっていることを必ず確認してください。サンプル注入口ラインにインライン フィルターを取り付けていない状態で分析装置を操作すると、分析装置に損傷を及ぼし、保証が無効になります。 分析装置の損傷を防ぐために、フィルターを取り付け、必要に応じてフィルター エレメントを交換してください。
.................................WARNINGSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014187 of 211誤った TOC 測定値や分析装置に対する損傷の可能性を避けるために、分析を開始する前に、サンプルが iOS システムを流れていて、DI 水リザーバーが満杯になっていることを必ず確認してください。オゾン処理水システムの仕様範囲内の性能を得るために、オゾン分解キットを GE Analytical Instruments から購入し、指示に従って取り付ける必要があります。分析装置を洗浄する場合、必ず液体は布に直接付けてください。そして、分析装置には液体を直接噴霧しないでください。水が偏光板に損傷を与えたり、変色させる可能性があるため、タッチスクリーンに水またはクリーナーを使用しないでください。 タッチスクリーンの洗浄に関する推奨事項については、次のセクションを参照してください。 凝縮物は直ちに拭き取ってください。注意
WARNINGSAppendix ASievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014188 of 211DeutschWARNUNGVersandkartons, die einen Analysator mit eingebauten optionalen Komponenten enthalten, können mehr als 40 Pfund wiegen; dies erfordert beim Verladen eine Hebetechnik mit zwei Personen. Solche Kartons sind mit diesem Warnhinweis gekennzeichnet, um Angestellte vor Verletzungen zu schützen und die OSHA-Standards zu erfüllen.Wir empfehlen unseren Kunden, ein Hebezeug für zwei Personen zu verwenden, und GE macht es zur Auflage, dass ALLE Mitarbeiter diese Technik beim Bewegen von Gegenständen mit einem Gewicht von mehr als 40 Pfund anwenden.Dieses Symbol auf dem Gerät zeigt an, dass der Benutzer die Betriebsanweisungen des Handbuchs lesen muss.Wenn das Gerät auf eine nicht von GE Analytical Instruments bezeichnete Weise verwendet wird, kann der Schutz, den das Gerät bietet, beeinträchtigt werden.(On-Line TOC-Analysator) Dieses Symbol zeigt die Schutzleiter (Masse)-Klemme des Analysators an. Der Analysator benötigt eine Energieversorgung mit 100-240 V Wechselstrom (AC) und es muss für einen sicheren Betrieb das richtige Netzkabel verwendet werden. Verwenden Sie AUSSCHLIESSLICH das mit dem Zubehörkit des Analysator gelieferte Netzkabel, das die AC-Energieversorgungsanforderungen erfüllt.Befolgen Sie zum Ausschalten des Analysators aus Sicherheitsgründen und um zu verhindern, dass die Datenbank beschädigt wird, IMMER das folgende Verfahren. Beenden Sie zuerst die Analyse UND beenden Sie das Betriebssystem (mit der Taste "SYSTEM STOPPEN" (HALT SYSTEM) in der Analysator-Firmware), BEVOR Sie den Netzschalter des Analysators auf Aus schalten oder das Netzkabel trennen.
.................................WARNINGSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014189 of 211Jeder Tätigkeit, die Zugang zum Inneren des Analysators erfordert, einschließlich Installation von Wartungsteilen, kann zu Verletzungen führen. Um einen gefährlichen Stromschlag zu vermeiden, beenden Sie zuerst – BEVOR Sie den Analysator öffnen – die Analyse und das Betriebssystem (mit der Taste "SYSTEM STOPPEN" (HALT SYSTEM) in der Analysator-Firmware), und schalten dann das Gerät aus und trennen es vom Netz.Elektrische Schaltkreise müssen von einem qualifizierten Elektriker installiert werden. Stellen Sie außerdem vor Installation von Verdrahtungen im Analysator sicher, dass Sie ESD-Schutz tragen.Die Ausgabe- und Alarmanschlüsse müssen von einem qualifizierten Elektriker installiert werden. Stellen Sie außerdem vor Installation von Verdrahtungen im Analysator sicher, dass Sie ESD-Schutz tragen.Es handelt sich um ein Klasse A-Produkt. In einer Wohngegend kann das Produkt Elektromagnetische Beeinflussung verursachen; in diesem Fall muss der Anwender möglicherweise geeignete Maßnahmen zum Beheben der Beeinflussung ergreifen.Betreiben Sie zum Schutz gegen versehentliche Exposition mit UV-Strahlung die UV-Lampe nicht außerhalb ihres Schutzgehäuses.(On-Line- und portable TOC-Analysatoren) Das Wasser im iOS-System kann heiß sein. Schieben Sie vor dem Einführen eines Röhrchens in das iOS-System nach Betrieb im Online-Modus die Tür auf und warten Sie 30 Sekunden, damit die Probe vollständig ablaufen kann. Das Einführen eines Röhrchens vor dem Abfließen kann dazu führen, dass heißes Wasser nach oben aus dem iOS-System oder dem Röhrchenport spritzt.Das iOS-System und die Röhrchenports enthalten spitze Nadeln zum Durchstechen der Septa von Probenröhrchen. Stecken Sie weder Finger noch ungeeignetes Material in das iOS-System oder einen Röhrchenport.WARNUNG
WARNINGSAppendix ASievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014190 of 211ENTSORGUNG VON GEFAHRSTOFFENFolgende Richtlinien werden als Anleitung zur Entsorgung von Gefahrstoffen bereitgestellt, die im Zusammenhang mit den Sievers M9 and M9eM5310 C TOC-Analysatoren auftreten.Stellen Sie vor dem Warten von Teilen im Analysator sicher, dass der Analysator ausgeschaltet ist und kommen Sie mit den Händen nicht in die Nähe der Reagenzienspritzen-Baugruppen. Die Spritzen werden durch bewegliche Teile gesteuert und können die Haut einklemmen.(Labor- und portable TOC-Analysatoren) Tauschen Sie eine Sicherung nur gegen eine Sicherung des gleichen Typs und mit den gleichen Nennwerten aus, damit der Schutz gegen Brandgefahr erhalten bleibt.ENTSORGUNG VON GEFAHRSTOFFENEs werden in dem Analysator gefährliche Reagenzien (Ammoniumpersulfat und Phosphorsäure) verwendet. Der Abfallfluss des Geräts ist sauer und muss regelgerecht entsorgt werden. Befolgen Sie die Regularien des Bundes, der Länder und der örtlichen Behörden.Die UV-Lampe und der Anzeigenbildschirm enthalten Quecksilber und können in Ihrem Gebiet als gefährliches Material eingestuft sein. Entsorgen Sie diese Teile gemäß den Regularien des Bundes, der Länder und der örtlichen Behörden.Behandeln Sie im Fall einer zerbrochenen oder beschädigten UV-Lampe die Überreste gemäß dem Verfahren für den Umgang mit toxischen Abfällen Ihrer Organisation und entsorgen Sie ihn gemäß den Regularien des Bundes, der Länder und der örtlichen Behörden.Dieses Symbol zeigt an, dass der Analysator zur Einhaltung der EU-Richtlinie 2002/96/EC zur Entsorgung von Elektro- und Elektronik-Altgeräten getrennt vom Normalmülle zu entsorgen ist.WARNUNG
.................................WARNINGSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014191 of 211VORSICHTSMASSNAHMEN BEIM BETRIEBLesen und befolgen Sie zur Gewährleistung optimaler Probenergebnisse und zum Schutz des Geräts vor Beschädigung die folgenden Vorsichtsmaßnahmen.VORSICHTSMASSNAHMENStellen Sie sicher, dass der DI-Wassertank gefüllt ist, insbesondere bei Probenläufen mit hohem TOC-Gehalt oder hohen Salzkonzentrationen. Spülen Sie den Analysator nach dem Lauf von Proben mit hohem TOC- oder Salzgehalt immer mit DI-Wasser mit niedrigem TOC-Gehalt über einen Probenzyklus.Stellen Sie zur Vermeidung falscher TOC-Messwerte und zur Vermeidung möglicher Schäden am Analysator immer sicher, dass der Probeneingang frei ist und der DI-Wassertank gefüllt ist, bevor Sie eine Analyse starten.Der Betrieb des Analysators ohne Inline-Filter am Probeneingang führt zur Beschädigung des Analysators und lässt die Garantie erlöschen. Installieren Sie zur Vermeidung von Schäden am Analysator den Filter und tauschen Sie das Filterelement entsprechend der Erfordernisse aus.Stellen Sie zur Vermeidung falscher TOC-Messwerte und möglicher Schäden am Analysator immer sicher, dass die Probe durch das iOS-System fließt und der DI-Wassertank gefüllt ist, bevor Sie eine Analyse starten.Zum Betrieb in ozonhaltigen Wasseranlagen innerhalb der Spezifikationen muss ein Ozonabbau (Ozone Destruct)-Kit von GE Analytical Instruments erworben und gemäß den Anweisungen installiert werden.Geben Sie zum Reinigen des Analysators die Flüssigkeit immer auf ein Tuch und sprühen Sie Flüssigkeiten nicht direkt auf den Analysator.Verwenden Sie für den Touchscreen KEIN Wasser und KEINE Reinigungsmittel, da Wasser den Polarisator beschädigen oder entfärben kann. Im nächsten Abschnitt finden sich Empfehlungen zum Reinigen des Touchscreens. Wischen Sie etwaige Kondensate sofort ab.
WARNINGSAppendix ASievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014192 of 211FrançaisAVERTISSEMENTLes boîtes de transport contenant un analyseur avec les composants incorporés en option peuvent peser plus de 40 lb — veuillez prévoir deux personnes pour les soulever. Ces boîtes sont étiquetées avec cet avertissement, selon les normes OSHA prévues pour protéger les employés contre les accidents.Nous recommandons que nos clients prévoient deux personnes pour la manipulation, et GE exige que TOUS les employés utilisent cette technique en soulevant les éléments pesant plus de 40 lb.Ce symbole présent sur l'instrument indique que l'utilisateur doit consulter le manuel pour le mode d'emploi.Si cet instrument est utilisé d'une manière non spécifiée par GE Analytical Instruments, la protection offerte par l'instrument peut s'en trouver affaiblie.(Analyseur COT En ligne) Ce symbole indique la prise de terre (masse) pour l'Analyseur.L'Analyseur nécessite une alimentation principale C/A de 100-240 volts, ainsi que le cordon d'alimentation adéquat pour un fonctionnement correct. Utilisez UNIQUEMENT le cordon d'alimentation fourni dans le kit d'accessoires de l'Analyseur, qui est conforme à ces exigences d'alimentation principale C/A.Pour des raisons de sécurité et pour éviter la possibilité de corrompre la base de données, vous devez TOUJOURS suivre cette procédure lors de mise hors tension de l'Analyseur. Arrêtez d'abord l'analyse ET arrêtez le système d'exploitation (en utilisant le bouton HALT SYSTEM dans le micrologiciel de l'Analyseur) AVANT d'appuyer le commutateur d'alimentation sur Off ou de débrancher le cordon d'alimentation,
.................................WARNINGSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014193 of 211Toute intervention nécessitant d'accéder à l'intérieur de l'analyseur, y compris l'installation d'éléments de maintenance, pourrait occasionner des blessures. Afin d'éviter les chocs potentiellement dangereux -AVANT d'ouvrir l'Analyseur- arrêtez d'abord l'analyse, arrêtez le système d'exploitation (en utilisant le bouton HALT SYSTEM dans le micrologiciel de l'Analyseur), et ensuite coupez l'alimentation et déconnectez la source d'alimentation.La canalisation électrique doit être installée par un technicien qualifié. De même, avant d'installer le câblage à l'intérieur de l'Analyseur, assurez-vous que vous portez la protection ESD.Les connexions de sortie et d'alarme doivent être installées par un technicien qualifié. De même, avant d'installer le câblage à l'intérieur de l'Analyseur, assurez-vous que vous portez la protection ESD.Ceci est un produit de classe A. Dans un environnement domestique, ce produit peut causer des interférences électromagnétiques, auquel cas l’utilisateur peut être contraint de prendre les mesures adéquates pour y remédier.Pour se protéger contre l'exposition accidentelle aux rayons ultraviolets, n'utilisez pas la lampe UV à l'extérieur du boîtier de protection.(Analyseurs COT En ligne et Portable) L'eau dans le système iOS System peut être chaude. Avant d'insérer une fiole dans le système iOS après avoir utilisé le mode en ligne, ouvrez en coulissant la porte et attendez 30 secondes pour permettre que l'échantillon sèche complètement. Si vous insérez une fiole avant le séchage vous risquez de recevoir un jet d'eau chaude pulvérisé vers le haut et hors du système iOS ou de l'orifice à fioles.Le système iOS et les orifices à fioles contiennent des aiguilles pointues conçues pour percer le septum des fioles à échantillon. NE placez PAS de matériels inappropriés dans le système iOS ou l'orifice à fioles.AVERTISSEMENT
WARNINGSAppendix ASievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014194 of 211Lors de la maintenance des pièces à l'intérieur de l'analyseur, assurez-vous que l'alimentation est sur off, et éloignez les mains du montage de la seringue à réactif. Les seringues sont contrôlées par des pièces mobiles qui peuvent piquer la peau.(Analyseurs COT Laboratoire et Portable) Pour assurer la protection contre le risque d'incendie, le fusible ne doit être remplacé qu'avec le même type et la même valeur nominale.AVERTISSEMENTLes changements ou modifications à la radio RFID non explicitementapprouvés par la partie responsable de la conformité peuvent annulerl'autorité de l'utilisateur à utiliser l'équipement.Cet appareil est conforme à la Partie 15 de la réglementation FCC et desnormes RSS exemptes de licence d'Industry Canada. Le fonctionnementest assujetti aux deux conditions suivantes :(1) Cet appareil ne peut pas provoquer d'interférences nocives, et(2) Cet appareil doit accepter toute interférence reçue, y comprisl'interférence qui peut provoquer un fonctionnement indésirable.L'antenne RFID est un appareil digital conforme à la partie 15 et RSS-210 - Classe A : Cet appareil a été testé et a été trouvé conforme avecles limites d'un appareil digital de classe A, selon la partie 15 desnormes FCC. Ces limites sont conçues pour fournir une protectionraisonnable contre l'interférence nocive lorsque l'appareil fonctionnedans un environnement commercial. Cet appareil produit, utilise et peutémettre de l'énergie de fréquence radio et, s'il n'est pas installé et utiliséselon le manuel d'instruction, il peut provoquer une interférence nociveaux communications radio. Le fonctionnement de cet appareil dansune zone résidentielle peut probablement provoquer des interférencesnocives et, dans ce cas, l'utilisateur devra corriger l'interférence à sespropres frais.Cet appareil est conforme aux limites d'exposition de radiationélectromagnétique FCC établies pour un environnement non contrôlé.Cet appareil doit être installé et utilisé avec une distance de séparationminimum de 20cm (7 pouces) entre l'antenne RFID et le corps.L'antenne est située à l'intérieur du fond de l'analyseur à proximité de lapartie avant de la seringue.AVERTISSEMENT
.................................WARNINGSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014195 of 211MISE AU REBUT DES MATÉRIAUX DANGEREUXLes directives suivantes sont fournies pour vous aider au ramassage et mise au rebut des substances dangereuses concernant les Analyseurs COT Sievers M9 and M9eM5310 C.PRÉCAUTIONS DE FONCTIONNEMENTAfin d'assurer des résultats d'échantillonnage optimaux et de protéger l'instrument de tout endommagement, révisez et mettez en œuvre les mises en garde suivantes.MISE AU REBUT DES MATÉRIAUX DANGEREUXDes réactifs dangereux (persulfate d'ammonium et acide phosphorique) sont utilisés dans l'Analyseur. Le flux de déchet de l'instrument est acide et doit être mis au rebut de manière adéquate. Consultez les règlementations fédérales, provinciales ou locales.La lampe UV et l'écran contiennent du mercure et peuvent être considérés des matériaux dangereux dans votre région. Mettez au rebut ces éléments selon les règlementations fédérales, provinciales ou locales.Dans le cas de lampe UV cassée ou endommagée, manipulez les restes selon les procédures de traitement des déchets de votre organisation et mettez-les au rebut selon les règlementations fédérales, provinciales ou locales.Ce symbole indique la Directive 95/46/CE de l'Union européenne relative aux déchets d'équipements électriques et électroniques (DEEE) et exige que l'Analyseur soit mis au rebut séparément des déchets standard.PRÉCAUTIONSAssurez-vous que le réservoir d'eau DI est rempli, en particulier avec des échantillons contenant des concentrations élevées de COT ou de sel. Avec des échantillons à concentrations élevées de COT ou de sel, rincez toujours l'analyseur en utilisant de l'eau DI à faible COT dans un cycle à échantillon.
WARNINGSAppendix ASievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014196 of 211Afin d'éviter de fausses lectures de COT et de possibles dommages à l'Analyseur, assurez-vous toujours que l'entrée de l'échantillon est ouverte et que le réservoir d'eau DI est rempli avant de démarrer l'analyse.L'utilisation de l'Analyseur sans le filtre en ligne sur la ligne d'entrée d'échantillons peut endommager l'Analyseur et invalider la garantie. Afin d'éviter d'endommager l'Analyseur, installez le filtre et remplacez l'élément de filtration, si nécessaire.Afin d'éviter de fausses lectures de COT et de possibles dommages à l'Analyseur, assurez-vous toujours que l'échantillon circule dans le système iOS et que le réservoir d'eau DI est rempli avant de démarrer l'analyse.Pour une performance selon les spécifications dans les systèmes d'eau ozonées, un kit de destruction de l'ozone doit être acquis auprès de GE Analytical Instruments et installé selon les instructions.Lors du nettoyage de l'Analyseur, appliquez toujours du liquide au chiffon directement, et NE pulvérisez PAS de liquide directement sur l'Analyseur.N'utilisez PAS d'eau ou de nettoyant sur l'écran tactile, l'eau peut endommager ou décolorer le polariseur. Consultez la section suivante pour lire les recommandations concernant le nettoyage de l'écran tactile. Essuyez immédiatement toute condensation.PRÉCAUTIONS
.................................WARNINGSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014197 of 211ItalianoAVVERTENZALe scatole contenenti l'Analizzatore con componenti integrati opzionali possono pesare oltre 40 lb (20 kg) e devono essere sollevate da due persone. Le scatole sono etichettate con questa avvertenza, in conformità agli standard OSHA per la tutela dei lavoratori dipendenti da lesioni.Raccomandiamo ai nostri clienti l'uso di tecniche di sollevamento a due persone. Inoltre, GE richiede a tutti i lavoratori dipendenti l'utilizzo di tali tecniche per il sollevamento di oggetti di peso superiore a 40 lb (20 kg).Questo simbolo, situato sullo strumento, indica che l'utente deve fare riferimento al manuale per le istruzioni d'uso.Se lo strumento viene utilizzato secondo modalità non indicate da GE Analytical Instruments, la protezione fornita dallo strumento potrebbe risultarne compromessa.(Analizzatore di TOC on-Line) Questo simbolo indica il terminale del conduttore di protezione (terra) dell'Analizzatore.L'Analizzatore richiede un'alimentazione principale CA da 100-240 V e il cavo di alimentazione adeguato per la sicurezza del funzionamento. Usare esclusivamente il cavo di alimentazione in dotazione con il kit di accessori dell'Analizzatore che soddisfa i requisiti dell'alimentazione principale CA.Per motivi di sicurezza e per evitare di corrompere il database, quando si arresta l'Analizzatore seguire sempre la seguente procedura. Arrestare l'analisi e il sistema operativo (usando il pulsante HALT SYSTEM (arresto sistema) nel firmware dell'Analizzatore) prima di premere l'interruttore dell'analizzatore su Off o di scollegare il cavo dell'alimentazione.
WARNINGSAppendix ASievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014198 of 211Le operazioni che comportano l'accesso alle parti interne dell'analizzatore, comprese la parti relative all'installazione e alla manutenzione, possono causare lesioni. Per evitare scosse potenzialmente pericolose, prima di aprire l'analizzatore, fermare l'analisi in corso, arrestare il sistema operativo (usando il pulsante HALT SYSTEM (arresto sistema) nel firmware dell'analizzatore), quindi spegnere l'alimentazione e scollegare l'analizzatore dall'alimentazione.La conduttura elettrica deve essere installata da un elettricista qualificato. Inoltre, prima di installare cavi all'interno dell'Analizzatore, assicurarsi di indossare protezioni ESD.I collegamenti di allarme e di output devono essere installati da un elettricista qualificato. Inoltre, prima di installare cavi all'interno dell'Analizzatore, assicurarsi di indossare protezioni ESD.Questo è un prodotto di Classe A. In un ambiente domestico, questo prodotto può causare interferenza elettromagnetica. In tal caso, l'utente deve adottare le misure adeguate per correggere l'interferenza.Per proteggersi dall'esposizione accidentale alle radiazioni ultraviolette, non azionare la lampada UV fuori dal suo alloggiamento protettivo.(Analizzatori di TOC On-Line e portatili) L'acqua all'interno del sistema iOS potrebbe essere calda. Prima di inserire una fiala all'interno del sistema iOS dopo il funzionamento in modalità on-line, aprire lo sportello e attendere 30 secondi per consentire al campione di prosciugarsi completamente. L'inserimento di una fiala prima del prosciugamento può comportare la fuoriuscita di spruzzi d'acqua verso l'alto dal sistema iOS o dalla porta della fiala.Il sistema iOS e le porte delle fiale contengono aghi taglienti studiati per perforare i setti delle fiale dei campioni. NON mettere le dita o materiali inappropriati all'interno del sistema iOS o della porta della fiala.AVVERTENZA
.................................WARNINGSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014199 of 211SMALTIMENTO DI MATERIALI PERICOLOSILe seguenti linee guida hanno lo scopo di aiutare l'utente a smaltire sostanze pericolose legate all'uso degli Analizzatori di TOC Sievers M9 and M9eM5310 C.Durante la manutenzione di componenti interni dell'Analizzatore, accertarsi che l'alimentazione dell'Analizzatore sia scollegata e tenere le mani lontane dal gruppo reagente con siringa. Le siringhe devono essere controllate spostando i componenti che potrebbero fregare la pelle.(Analizzatori di TOC portatili e da laboratorio) Per protezione continua contro i pericoli di incendio, sostituire il fusibile con uno dello stesso tipo e classificazione.SMALTIMENTO DI MATERIALI PERICOLOSIInsieme all'Analizzatore vengono usati reagenti pericolosi (persolfato di ammonio e acido fosforico). Il flusso di rifiuti dello strumento è acido e deve essere adeguatamente smaltito. Consultare la normativa federale, statale e locale.La lampada UV e lo schermo del display contengono mercurio e possono essere considerati pericolosi dalla normativa locale. Smaltire questi prodotti in conformità alla normativa federale, statale o locale.In caso di lampada UV rotta o danneggiata, gestire i resti seguendo la procedura per la gestione di rifiuti tossici della propria organizzazione e smaltirli in conformità alla normativa federale, statale o locale.Questo simbolo indica che la Direttiva 2002/96/CE dell'Unione Europa per lo smaltimento di apparecchiature elettriche ed elettroniche (AEE), prevede lo smaltimento dell'Analizzatore separatamente rispetto ai rifiuti standard.AVVERTENZA
WARNINGSAppendix ASievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014200 of 211AVVERTENZE PER IL FUNZIONAMENTOPer garantire risultati di campionamento ottimali e per proteggere lo strumento da danni, leggere e seguire le seguenti avvertenze.AVVERTENZEAccertarsi che il serbatoio di acqua distillata sia pieno, in particolare durante l'analisi di campioni con un elevato TOC o concentrazioni di sale elevate. Dopo l'analisi di campioni con concentrazioni di TOC o sale elevate, sciacquare l'Analizzatore facendo passare acqua distillata con TOC basso lungo il ciclo del campione.Per evitare letture TOC false e possibili danni all'Analizzatore, prima di iniziare l'analisi accertarsi che l'ingresso del campione sia aperto e che il serbatoio di acqua distillata sia pieno.Se si utilizza l'Analizzatore senza il filtro sulla linea d'ingresso del campione, si potrebbero arrecare danni all'Analizzatore e rendere nulla la garanzia. Per evitare danni all'Analizzatore, installare il filtro e sostituire l'elemento del filtro, secondo necessità.Per evitare letture TOC false e possibili danni all'Analizzatore, prima di iniziare l'analisi accertarsi che il campione stia scorrendo lungo il sistema iOS e che il serbatoio di acqua distillata sia pieno.Per prestazioni entro le specifiche su sistemi di acqua ozonati, acquistare un kit di distruzione dell'ozono da GE Analytical Instruments e installarlo seguendo le istruzioni.Durante la pulizia dell'analizzatore, applicare sempre il liquido sul panno invece di spruzzarlo direttamente sull'Analizzatore.NON usare acqua o detergenti sul touchscreen. L'acqua potrebbe danneggiare o decolorare il polarizzatore. Fare riferimento alla sezione successiva per raccomandazioni sulla pulizia del touchscreen. Rimuovere immediatamente la condensa.
.................................WARNINGSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014201 of 211EspañolADVERTENCIALas cajas de envío que contienen el Analizador con los componentes opcionales incorporados pueden pesar más de 18 kg (40 lb). Se necesita a dos personas para levantarlas cuando se las manipule. Las cajas presentan una etiqueta con esta advertencia, conforme a las normas OSHA destinadas a la protección del empleado contra lesiones.Recomendamos a nuestros clientes emplear la ayuda de dos personas y GE requiere que TODOS los empleados utilicen la técnica de manejo de materiales cuando se deban levantar elementos que superen los 18 kg (40 lb). Este símbolo en el instrumento indica que el usuario debe consultar el manual para conocer las instrucciones de funcionamiento.Si este instrumento se utiliza de una manera que no sea la especificada por GE Analytical Instruments, es posible que se vea disminuida la protección provista por el instrumento.(Analizador de TOC En Línea) Este símbolo indica el terminal de protección a tierra (masa) para el Analizador.El Analizador requiere una alimentación por red de CA de 100 a 240 voltios, y necesita el cable de energía correcto para un funcionamiento seguro del instrumento. Utilice SOLAMENTE el cable de energía suministrado en el Juego de Accesorios del Analizador junto con el Analizador, que cumple con estos requisitos de alimentación por red de CA.Por razones de seguridad y para evitar la posibilidad de corromper la base de datos, SIEMPRE siga este procedimiento cuando corte el Analizador. Primero pare el análisis Y detenga el sistema operativo (utilizando el botón Detener Sistema [Halt System] en el Firmware del Analizador) ANTES de pulsar el interruptor de energía del analizador en la posición Off o desenchufar el cable de energía.
WARNINGSAppendix ASievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014202 of 211Toda operación que necesite el acceso al interior del Analizador, incluyéndose la instalación de los elementos de mantenimiento, podría provocar lesiones. Para evitar el peligro de una posible descarga eléctrica, ANTES de abrir el Analizador, primero pare el análisis, detenga el sistema operativo (utilizando el botón Detener Sistema [HALT SYSTEM] en el Firmware del Analizador), y luego apague la energía y desconecte de la alimentación por red.Un electricista matriculado debe instalar un conductor eléctrico de tipo "conduit". Además, antes de instalar cualquier cableado dentro del Analizador, asegúrese de usar protección electrostática.La instalación de las conexiones para las salidas y alarmas debe ser instalada por un electricista matriculado. Además, antes de instalar cualquier cableado dentro del Analizador, asegúrese de usar protección electrostática.Este es un producto de Clase A. En un entorno doméstico, este producto puede causar interferencia electromagnética, en cuyo caso el usuario tal vez deba tomar medidas adecuadas para corregir dicha interferencia.Para proteger contra la exposición accidental a la radiación de rayos ultravioletas, no ponga a funcionar la lámpara UV fuera de su carcasa de protección.(Analizadores de TOC En Línea y Portátil) El agua en el Sistema iOS puede estar caliente. Antes de introducir un vial en el Sistema iOS después de hacer funcionar el instrumento en modo en línea, deslice la puerta para abrirla y espere 30 segundos para que la muestra drene totalmente. Cuando se introduce un vial antes de drenar puede que el agua caliente se expulse y salpique hacia arriba del Sistema iOS o el puerto de viales.El Sistema iOS y los puertos de viales contienen dos agujas filosas diseñadas para perforar los septa de los viales con las muestras. NO ponga los dedos o materiales inadecuados dentro del Sistema iOS o el puerto de viales.ADVERTENCIA
.................................WARNINGSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014203 of 211DESECHO DE MATERIALES PELIGROSOSLas directrices que se ofrecen a continuación sirven para ayudar a apartar y desechar las sustancias peligrosas relacionadas con los Analizadores de TOC Sievers M9 and M9eM5310 C.Cuando se realice el servicio de partes dentro del Analizador, asegúrese de que la energía al Analizador esté desconectada y mantenga las manos alejadas de los conjuntos de jeringa con reactivos. Las jeringas se controlan mediante partes móviles que puede pellizcar la piel.(Analizadores de TOC de laboratorio y portátil) Reemplace el fusible del mismo tipo y potencia para contar con una protección contra incendios.DESECHO DE MATERIALES PELIGROSOSEn el Analizador se utilizan reactivos peligrosos (persulfato de amonio y ácido fosfórico). El flujo de drenaje del instrumento es ácido y se debe desechar correctamente. Consulte la normativa del gobierno federal, estatal y local. La lámpara UV y la pantalla contienen mercurio y puede considerarse material peligroso en su área local. Deseche estos elementos de conformidad con la normativa del gobierno federal, estatal o local.Si la lámpara UV se rompe o deteriora, los restos de la misma deben manejarse de conformidad con el procedimiento de manejo de residuos tóxicos de su compañía y desecharse conforme a la normativa del gobierno federal, estatal o local.Este símbolo indica que para cumplir con la Directriz de la Unión Europea 96/2002/CE relacionada con el desecho de equipos eléctricos y electrónicos (WEEE), el Analizador deberá desecharse por separado de los residuos comunes.ADVERTENCIA
WARNINGSAppendix ASievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014204 of 211PRECAUCIONES OPERATIVASPara asegurar resultados óptimos en la toma de muestras y proteger el instrumento de todo daño, revise y ponga en práctica los siguientes enunciados relacionados con las Precauciones. PRECAUCIONESAsegúrese de que el reservorio de agua DI (pizeta) esté lleno, en especial cuando se analizan muestras con TOC elevado o altas concentraciones de sal. Después de analizar muestras con TOC elevado o alto contenido de sal, siempre enjuague del Analizador haciendo correr agua DI de bajo TOC por el ciclo de muestra.Para evitar lecturas falsas de TOC y posible daño en el Analizador, cerciórese siempre de que la entrada de muestra esté abierta y que el reservorio de agua DI (pizeta) esté lleno antes de comenzar con el análisis.El funcionamiento del Analizador sin el filtro en línea en el conducto de entrada de muestra dañará el Analizador y anulará la garantía. Para evitar los daños al Analizador, instale el filtro y reemplace elemento filtrante según sea necesario.Para evitar lecturas falsas de TOC y posible daño en el Analizador, cerciórese siempre de que la muestra fluya por el Sistema iOS y que el reservorio de agua DI (pizeta) esté lleno antes de comenzar con el análisis.Para lograr un rendimiento que cumpla con las especificaciones en los sistemas de agua ozonizada, se debe adquirir un Juego de Destrucción de Ozono en GE Analytical Instruments e instalarlo de acuerdo con las instrucciones.Cuando se limpie el Analizador, siempre ponga el líquido directamente en el paño y NO pulverice líquidos directamente sobre el Analizador.NO utilice agua ni limpiadores sobre la pantalla táctil, puesto que el agua puede deteriorar o decolorar el polarizador. Consulte con la sección siguiente para conocer las recomendaciones sobre la limpieza de la pantalla táctil. Seque toda condensación de inmediato.
.................................WARNINGSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014205 of 211PORTUGUESEAVISOAs embalagens de transporte que contêm um analisador com componentes opcionais integrados podem pesar mais de 18 kg e precisam que duas pessoas as levantem quando forem manuseadas. Essas embalagens apresentam etiquetas com este aviso para estarem de acordo com as normas OSHA de proteção de funcionários contra ferimentos.Nós recomendamos que nossos clientes usem duas pessoas ao levantá-las, e a GE requer que TODOS os funcionários usem essa técnica de manuseio quando levantam itens que pesam mais de 18 kg.Este símbolo no instrumento indica que o usuário deve consultar o manual para obter instruções de operação.Se o instrumento for usado de forma não especificada pela GE Analytical Instruments, a proteção fornecida pelo instrumento pode ser prejudicada.(On-Line TOC Analyzer) Este símbolo indica o terminal protetor de aterramento (terra) do analisador.O analisador requer uma fonte de alimentação A/C de 100-240 Volts e requer o cabo de energia correto para operar com segurança. Use APENAS o cabo de energia fornecido no kit de acessórios do analisador, que atende às exigências de fonte de alimentação A/C.Por razões de segurança e para evitar a possibilidade de corromper o banco de dados, siga SEMPRE este procedimento quando desligar o analisador: primeiro, interrompa a análise E pare o sistema operacional (use o botão PARAR SISTEMA no firmware do analisador) ANTES de posicionar o interruptor do analisador em Off ou desconectar o cabo de energia.
WARNINGSAppendix ASievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014206 of 211Qualquer operação que exija acesso ao interior do analisador, entre elas, a instalação de itens de manutenção, pode causar ferimentos. Para evitar possíveis choques perigosos, ANTES de abrir o analisador, interrompa a análise, pare o sistema operacional (use o botão PARAR SISTEMA no firmware do analisador), desligue a energia e desconecte a fonte de alimentação.O conduíte elétrico deve ser instalado por um eletricista qualificado. Além disso, antes de instalar qualquer fiação dentro do analisador, certifique-se de usar proteção contra descarga eletroestática.As conexões de saída e de alarme devem ser instaladas por um eletricista qualificado. Além disso, antes de instalar qualquer fiação dentro do analisador, certifique-se de usar proteção contra descarga eletroestática.Este é um produto Classe A. Em um ambiente doméstico, este produto pode causar interferência eletromagnética. Nesse caso, pode ser necessário que o usuário tome as medidas adequadas para corrigi-la.Para se proteger da exposição acidental à radiação ultravioleta, não opere a lâmpada UV fora da sua caixa de proteção.(Analisadores de TOC em linha e portáteis) A água no sistema iOS pode estar quente. Antes de introduzir um frasco no sistema iOS, depois de operar no modo em linha, abra a porta e espere 30 segundos para que a amostra drene completamente. Introduzir um frasco antes da drenagem pode causar a pulverização de água quente lançada do sistema iOS ou da porta do frasco.O sistema iOS e as portas de frascos contêm agulhas afiadas projetadas para perfurar as membranas dos frascos de amostra. NÃO coloque os dedos ou materiais impróprios no sistema iOS ou na porta de frasco.Quando fizer a manutenção de peças dentro do analisador, garanta que a energia do analisador esteja desligada e afaste as mãos dos conjuntos de seringas de reagentes. As seringas são controladas por peças que se movem que podem beliscar a pele.AVISO
.................................WARNINGSSievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014207 of 211DESCARTE DE MATERIAIS PERIGOSOSAs seguintes diretrizes são fornecidas para ajudar a eliminar e descartar substâncias perigosas relacionadas aos Analisadores de TOC Sievers M9 and M9eM5310 C.CUIDADOS OPERACIONAISPara garantir resultados ideais da amostragem e para proteger o instrumento contra danos, analise e implemente as seguintes indicações de cuidado.(Analisadores de TOC portáteis e de laboratório) Para ter proteção constante contra risco de incêndios, substitua o fusível por outro do mesmo tipo e categoria.DESCARTE DE MATERIAIS PERIGOSOSReagentes perigosos (persulfato de amônio e ácido fosfórico) são usados no analisador. O fluxo de resíduos do instrumento é acidífero e deve ser eliminado de forma adequada. Consulte as regulamentações dos governos federal, estadual ou local.A lâmpada UV e a tela contêm mercúrio e podem ser consideradas material perigoso na sua localidade. Descarte esses itens de acordo com as regulamentações dos governos federal, estadual ou local.Se a lâmpada UV quebrar ou for danificada, manuseie os vestígios de acordo com o procedimento de manipulação de resíduos tóxicos da organização e os descarte de acordo com as regulamentações do governo federal, estadual ou local.Este símbolo indica que a Diretiva da União Europeia 2002/96/EC para resíduos de equipamentos elétricos e eletrônicos (REEE) requer que o analisador seja descartado separadamente dos resíduos comuns.CUIDADOSCertifique-se de que o reservatório de água DI está cheio, especialmente, quando analisar amostras com TOC elevado ou concentrações altas de sal. Depois de analisar amostras com teor de sal ou TOC elevado, enxágue sempre o analisador operando um ciclo de amostra com água DI com TOC baixo.AVISO
WARNINGSAppendix ASievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014208 of 211Para evitar leituras de TOC falsas e possíveis danos ao analisador, verifique sempre se a entrada de amostras está aberta e se o reservatório de água deionizada está cheio antes de começar a análise.A operação do analisador sem filtro em linha na entrada de amostras danificará o analisador e cancelará a garantia. Para evitar danificar o analisador, instale o filtro e substitua o elemento de filtro quando necessário.Para evitar leituras de TOC falsas e possíveis danos ao analisador, verifique sempre se a amostra flui através do sistema iOS e se o reservatório de água deionizada está cheio antes de começar a análise.Para operar dentro das especificações para sistemas de água ozonizada, um kit Ozone Destruct deve ser adquirido na GE Analytical Instruments e instalado de acordo com as instruções.Quando limpar o analisador, aplique sempre o líquido no pano e NÃO pulverize líquidos diretamente no analisador.NÃO use água ou líquidos de limpeza na tela touchscreen, pois a água pode danificar ou descolorir o polarizador. Consulte a seção a seguir para obter recomendações para limpar a tela touchscreen. Limpe qualquer condensação imediatamente.CUIDADOS
B..............................................Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014209 of 211Appendix B: Modbus MapUSING PUTTYHyperTerminal is a Microsoft communications program that can be used to communicate with Ethernet devices, such as the Analyzer. To use HyperTerminal, you must first connect your Analyzer to the computer with a crossover Ethernet cable, or connect the Analyzer to your computer network using a straight-through Ethernet cable. Ethernet cables are available at many computer and office supply retail stores.To install the serial connection:1. For direct connection of the Analyzer to a PC, select the crossover Ethernet cable from the Accessories Kit. Attach one end to the Ethernet port on the back of the Analyzer, and the other end to an Ethernet port on the PC.2. For connection of the Analyzer to a network, select the straight-through Ethernet cable from the Accessories Kit. Attach one end of the cable to the Ethernet port on the back of the Analyzer, and plug the other end into a convenient network port.3. Open HyperTerminal on the PC. The Connection Description screen displays. Enter a name for the new connection and click OK.4. The Connect To screen then display. In the Connect using Field, select TCP/IP (Winsock). Then, in the Host Address field, enter the IP address of your Analyzer. The IP address is displayed on the System Info screen (Menu ® Maintenance ® System Info). 5. Next, enter the appropriate Port number for the type of information you are going to collect. 6. If you are collecting real-time data that will be generated during measurements you are planning to make, enter 10801. 7. If you are planning to save historical data (Data History, or Cal/Ver History) that you will export from the Analyzer, enter 10802. 8. Click the OK button. 9. To save the data from the Analyzer, select Transfer ® Capture Text. When prompted, specify the file name and location for saving the data file.10.
MODBUS MAPAppendix B Sievers M9 and M9e TOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014210 of 211
IndexSievers M9 and M9eTOC AnalyzersSievers M5310 C TOC Analyzer Operation and Maintenance ManualDLM 77000-01 DLM 77100-01 EN Rev. A GE Analytical Instruments © 2014211211 of 211IInstalling a USB Connection 90
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