MSDS No Spal Pro RSF A Pol SDS
2016-06-06
: Guide Spal-Pro Rsf A Pol Sds Spal-Pro RSF A Pol SDS POLYUREAS Metzger manuals Niagara-Library
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Page 1 of 5 SAFETY DATA SHEET Date Prepared : SDS No : Date Revised : Revision No : 06/29/2005 SP RSF A 03/18/2015 7 Spal-Pro RSF A 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Spal-Pro RSF A MANUFACTURER Metzger McGuire Company, Inc 807 Route 3-A Bow, NH 03304 E-Mail: info@metzgermcguire.com 24 HR. EMERGENCY TELEPHONE NUMBERS Poison Control Center (Medical) : (877) 800-5553 KUV &RQWLQHQWDO86 KUV 2XWVLGH&RQWLQHQWDO86 2. HAZARDS IDENTIFICATION GHS CLASSIFICATIONS Health: Skin Sensitization, Category 1 Environmental: Acute Hazards to the Aquatic Environment, Category 2 Chronic Hazards to the Aquatic Environment, Category 2 GHS LABEL Exclamation Environment mark SIGNAL WORD: WARNING HAZARD STATEMENTS H317: May cause an allergic skin reaction. H411: Toxic to aquatic life with long lasting effects. PRECAUTIONARY STATEMENT(S) Prevention: P261: Avoid breathing mist, vapors and spray. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing, eye protection and face protection. Response: P302+P352: IF ON SKIN: Wash with plenty of soap and water. P333+P313: If skin irritation or rash occurs: Get medical attention. P362+P364: Take off contaminated clothing and wash it before reuse. P391: Collect spillage. Page 2 of 5 Spal-Pro RSF A 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name Di-(methylthio)toluenediamine N,N,N',N'-Tetrakis(2-hydroxylpropyl)ethylenediamine N,N'-dialkylamino-diphenylmethane Wt.% CAS 10 - 15 106264-79-3 ≤ 10 102-60-3 ≤5 5285-60-9 4. FIRST AID MEASURES EYES: Immediately flush eyes with plenty of water. Remove contact lenses, if present. Seek medical attention if irritation persists. SKIN: Wash with soap and water. Seek medical attention if irritation persists. INGESTION: Do not induce vomiting. Give one or two glasses of water to drink. Never give anything by mouth to an unconscious person. If large amounts are swallowed or if symptoms develop, seek medical attention. INHALATION: Move person to fresh air. 5. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: Water spray, foam, dry chemical or carbon dioxide. Do not spray water directly into container due to danger of boilover. HAZARDOUS COMBUSTION PRODUCTS: Carbon oxides, nitrogen oxides, and sulfur oxides. FIRE FIGHTING EQUIPMENT: Exposed firefighters must wear NIOSH-approved positive pressure self-contained breathing apparatus with full-face mask and full protective clothing. 6. ACCIDENTAL RELEASE MEASURES SMALL SPILL: Isolate the area and preventy entry of unnecessary and unprotected personnel. Do not walk through or otherwise scatter spilled product. Absorb with dry chemical absorbent, earth, sand or any other inert material. Place in a chemical waste container. LARGE SPILL: Isolate the area and preventy entry of unnecessary and unprotected personnel. Do not walk through or otherwise scatter spilled product. May be a slipping hazard. Create a dike or trench to contain product. Prevent entry into waterways, sewers, basements or confined areas. Absorb with dry chemical absorbent, earth, sand or any other inert material. Place in a chemical waste container. SPECIAL PROTECTIVE EQUIPMENT: Wear protective equipment listed in Section 8. 7. HANDLING AND STORAGE HANDLING: Do not get in eyes, on skin or on clothing. Wash hands before eating, drinking or smoking. Keep container closed when not in use. Do not reseal if contaminated. Keep away from heat and flame. STORAGE: Store in tightly closed containers in a cool, dry and well-ventilated area. Keep containers tightly sealed. STORAGE TEMPERATURE: 4.4°C (40°F) Minimum to 37.8°C (100°F) Maximum 8. EXPOSURE CONTROLS / PERSONAL PROTECTION ENGINEERING CONTROLS: If used at elevated temperatures or in confined space, ventilation may be required to control mists. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: Wear a face shield and chemical safety glasses or goggles. Page 3 of 5 Spal-Pro RSF A SKIN: Wear impervious gloves. Cover exposed skin. RESPIRATORY: None required in normal use. WORK HYGIENIC PRACTICES: Avoid eating, drinking or smoking while using this material. Wash hands thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES ODOR: Slightly musty. APPEARANCE: Liquid of various colors. FLASH POINT AND METHOD: > 93.3°C (200°F) AUTOIGNITION TEMPERATURE: Not established. BOILING POINT: > 148.9°C (300°F) FREEZING POINT: < 32°C (0°F) SOLUBILITY IN WATER: Partial. SPECIFIC GRAVITY: 1.07 to 1.09 (water = 1) at 23.3°C (74°F) VISCOSITY #1: 1400 to 1700 Centipoise at 23.3°C (74°F) 10. STABILITY AND REACTIVITY HAZARDOUS POLYMERIZATION: Will not occur. STABILITY: Stable. CONDITIONS TO AVOID: Moisture and high temperatures. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon oxides, nitrogen oxides, and sulfur oxides. INCOMPATIBLE MATERIALS: Strong acids and strong oxidizers. 11. TOXICOLOGICAL INFORMATION ACUTE Chemical Name ORAL LD50 (rat) DERMAL LD50 (rabbit) Di-(methylthio)toluenediamine 1515 mg/kg > 2000 mg/kg N,N,N',N'-Tetrakis(2-hydroxylpropyl)ethylenediamine 3280 mg/kg > 2000 mg/kg N,N'-dialkylamino-diphenylmethane 1400 mg/kg 3090 mg/kg CARCINOGENICITY IARC: Not regulated as a carcinogen. NTP: Not regulated as a carcinogen. OSHA: Not regulated as a carcinogen. 12. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION: Di-(methylthio)toluenediamine: LC50 (rainbow trout) 7.3 mg/L/96h; EC50 (Daphnia magna) 0.9 mg/L/48h Page 4 of 5 Spal-Pro RSF A COMMENTS: This product is toxic to aquatic organisms and can cause long term adverse effects in the aquatic environment. 13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Dispose in accordance with local, state, provincial or national regulations. EMPTY CONTAINER: Decontaminate and pass to an approved drum recycler or destroy. RCRA/EPA WASTE INFORMATION: If discarded in its purchased form, this material is not a RCRA hazardous waste. GENERAL COMMENTS: The generation of waste should be avoided or minimized whenever possible. Chemical waste, even small quantities, should never be poured into drains, sewers or waterways. 14. TRANSPORT INFORMATION DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: Environmentally hazardous substance, liquid, NOS TECHNICAL NAME: Aromatic amines PRIMARY HAZARD CLASS/DIVISION: Class 9 UN/NA NUMBER: UN3082 PACKING GROUP: III MARINE POLLUTANT #1: Di-(methylthio)toluenediamine OTHER SHIPPING INFORMATION: In a container 119 gallons or less, this product is not regulated for ground transportation. AIR (ICAO/IATA) SHIPPING NAME: Not regulated. VESSEL (IMO/IMDG) SHIPPING NAME: Environmentally hazardous substance, liquid, NOS TECHNICAL NAME: Aromatic amines UN/NA NUMBER: UN3082 PRIMARY HAZARD CLASS/DIVISION: Class 9 PACKING GROUP: III MARINE POLLUTANT #1: Di-(methylthio)toluenediamine NOTE: Regulated as a marine pollutant. Limited quantity if less than or equal to 5 liters (1.3 gallons). 15. REGULATORY INFORMATION UNITED STATES SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) 311/312 HAZARD CATEGORIES: Acute, Chronic. 313 REPORTABLE INGREDIENTS: None CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT) CERCLA REGULATORY: None TSCA (TOXIC SUBSTANCE CONTROL ACT) Page 5 of 5 Spal-Pro RSF A TSCA REGULATORY: All components are in TSCA inventory. RCRA STATUS: If discarded in its purchased form, this material is not a RCRA hazardous waste. 16. OTHER INFORMATION PREPARED BY: L. Priest Date Revised: 03/18/2015 COMMENTS: ACGIH CAS EC50 EINECS GHS IARC IATA ICAO IMDG IMO LC50 LD50 TWA TLV NIOSH NE NTP OEL OSHA PEL RQ STEL American Conference of Governmental Industrial Hygienists Chemical Abstracts Service Median effective concentration European Inventory of Existing Commercial Chemical Substances Globally Harmonized System of Classification and Labelling of Chemicals International Agency for Research on Cancer International Air Transport Association International Civil Aviation Organization International Maritime Dangerous Goods International Maritime Organization Lethal concentration to 50% of exposed laboratory animals Lethal dose to 50% of exposed laboratory animals Time-weighted average Threshold limit value US National Institute of Occupational Safety and Health Not established US National Toxicology Program Occupational exposure limit US Occupational Safety Health Administration Permissible exposure limit Reportable quantity Short term exposure limit MANUFACTURER DISCLAIMER: The information in this SDS was obtained from sources that we believe are reliable. The information is provided without warranty, implied or expressed, concerning accuracy. The manufacturer assumes no legal responsibility for use or reliance on this information. This SDS is proveded solely for the purpose of converying health, safety and environmental information. This SDS is not a specification data sheet. Some of the information and conclusions may be derived from sources other than test data on the material itself.
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