MSDS No Spal Pro RSF A Pol SDS
2016-06-06
: Guide Spal-Pro Rsf A Pol Sds Spal-Pro RSF A Pol SDS POLYUREAS Metzger manuals Niagara-Library
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SAFETY DATA SHEET
Date Prepared : 06/29/2005
SDS No : SP RSF A
Date Revised : 03/18/2015
Revision No : 7
Spal-Pro RSF A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: Spal-Pro RSF A
MANUFACTURER
24 HR. EMERGENCY TELEPHONE NUMBERS
Metzger McGuire Company, Inc
807 Route 3-A
Bow, NH 03304
E-Mail:
info@metzgermcguire.com
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Skin Sensitization, Category 1
Environmental:
Acute Hazards to the Aquatic Environment, Category 2
Chronic Hazards to the Aquatic Environment, Category 2
GHS LABEL
Exclamation
mark
Environment
SIGNAL WORD: WARNING
HAZARD STATEMENTS
H317: May cause an allergic skin reaction.
H411: Toxic to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENT(S)
Prevention:
P261: Avoid breathing mist, vapors and spray.
P273: Avoid release to the environment.
P280: Wear protective gloves, protective clothing, eye protection and face protection.
Response:
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P391: Collect spillage.
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Poison Control Center (Medical) : (877) 800-5553
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3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Di-(methylthio)toluenediamine 10 - 15 106264-79-3
N,N,N',N'-Tetrakis(2-hydroxylpropyl)ethylenediamine ≤ 10 102-60-3
N,N'-dialkylamino-diphenylmethane ≤ 5 5285-60-9
4. FIRST AID MEASURES
EYES: Immediately flush eyes with plenty of water. Remove contact lenses, if present. Seek medical attention if irritation persists.
SKIN: Wash with soap and water. Seek medical attention if irritation persists.
INGESTION: Do not induce vomiting. Give one or two glasses of water to drink. Never give anything by mouth to an unconscious
person. If large amounts are swallowed or if symptoms develop, seek medical attention.
INHALATION: Move person to fresh air.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, foam, dry chemical or carbon dioxide. Do not spray water directly into container due to
danger of boilover.
HAZARDOUS COMBUSTION PRODUCTS: Carbon oxides, nitrogen oxides, and sulfur oxides.
FIRE FIGHTING EQUIPMENT: Exposed firefighters must wear NIOSH-approved positive pressure self-contained breathing
apparatus with full-face mask and full protective clothing.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Isolate the area and preventy entry of unnecessary and unprotected personnel. Do not walk through or otherwise
scatter spilled product. Absorb with dry chemical absorbent, earth, sand or any other inert material. Place in a chemical waste
container.
LARGE SPILL: Isolate the area and preventy entry of unnecessary and unprotected personnel. Do not walk through or otherwise
scatter spilled product. May be a slipping hazard. Create a dike or trench to contain product. Prevent entry into waterways,
sewers, basements or confined areas. Absorb with dry chemical absorbent, earth, sand or any other inert material. Place in a
chemical waste container.
SPECIAL PROTECTIVE EQUIPMENT: Wear protective equipment listed in Section 8.
7. HANDLING AND STORAGE
HANDLING: Do not get in eyes, on skin or on clothing. Wash hands before eating, drinking or smoking. Keep container closed
when not in use. Do not reseal if contaminated. Keep away from heat and flame.
STORAGE: Store in tightly closed containers in a cool, dry and well-ventilated area. Keep containers tightly sealed.
STORAGE TEMPERATURE: 4.4°C (40°F) Minimum to 37.8°C (100°F) Maximum
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS: If used at elevated temperatures or in confined space, ventilation may be required to control mists.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Wear a face shield and chemical safety glasses or goggles.
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Spal-Pro RSF A
SKIN: Wear impervious gloves. Cover exposed skin.
RESPIRATORY: None required in normal use.
WORK HYGIENIC PRACTICES: Avoid eating, drinking or smoking while using this material. Wash hands thoroughly after
handling.
9. PHYSICAL AND CHEMICAL PROPERTIES
ODOR: Slightly musty.
APPEARANCE: Liquid of various colors.
FLASH POINT AND METHOD: > 93.3°C (200°F)
AUTOIGNITION TEMPERATURE: Not established.
BOILING POINT: > 148.9°C (300°F)
FREEZING POINT: < 32°C (0°F)
SOLUBILITY IN WATER: Partial.
SPECIFIC GRAVITY: 1.07 to 1.09 (water = 1) at 23.3°C (74°F)
VISCOSITY #1: 1400 to 1700 Centipoise at 23.3°C (74°F)
10. STABILITY AND REACTIVITY
HAZARDOUS POLYMERIZATION: Will not occur.
STABILITY: Stable.
CONDITIONS TO AVOID: Moisture and high temperatures.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon oxides, nitrogen oxides, and sulfur oxides.
INCOMPATIBLE MATERIALS: Strong acids and strong oxidizers.
11. TOXICOLOGICAL INFORMATION
ACUTE
Chemical Name ORAL LD
50
(rat)
DERMAL LD
50
(rabbit)
Di-(methylthio)toluenediamine 1515 mg/kg > 2000 mg/kg
N,N,N',N'-Tetrakis(2-hydroxylpropyl)ethylenediamine 3280 mg/kg > 2000 mg/kg
N,N'-dialkylamino-diphenylmethane 1400 mg/kg 3090 mg/kg
CARCINOGENICITY
IARC: Not regulated as a carcinogen.
NTP: Not regulated as a carcinogen.
OSHA: Not regulated as a carcinogen.
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION: Di-(methylthio)toluenediamine: LC
50
(rainbow trout) 7.3 mg/L/96h; EC
50
(Daphnia
magna) 0.9 mg/L/48h
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Spal-Pro RSF A
COMMENTS: This product is toxic to aquatic organisms and can cause long term adverse effects in the aquatic environment.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Dispose in accordance with local, state, provincial or national regulations.
EMPTY CONTAINER: Decontaminate and pass to an approved drum recycler or destroy.
RCRA/EPA WASTE INFORMATION: If discarded in its purchased form, this material is not a RCRA hazardous waste.
GENERAL COMMENTS: The generation of waste should be avoided or minimized whenever possible. Chemical waste, even
small quantities, should never be poured into drains, sewers or waterways.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: Environmentally hazardous substance, liquid, NOS
TECHNICAL NAME: Aromatic amines
PRIMARY HAZARD CLASS/DIVISION: Class 9
UN/NA NUMBER: UN3082
PACKING GROUP: III
MARINE POLLUTANT #1: Di-(methylthio)toluenediamine
OTHER SHIPPING INFORMATION: In a container 119 gallons or less, this product is not regulated for ground transportation.
AIR (ICAO/IATA)
SHIPPING NAME: Not regulated.
VESSEL (IMO/IMDG)
SHIPPING NAME: Environmentally hazardous substance, liquid, NOS
TECHNICAL NAME: Aromatic amines
UN/NA NUMBER: UN3082
PRIMARY HAZARD CLASS/DIVISION: Class 9
PACKING GROUP: III
MARINE POLLUTANT #1: Di-(methylthio)toluenediamine
NOTE: Regulated as a marine pollutant. Limited quantity if less than or equal to 5 liters (1.3 gallons).
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
311/312 HAZARD CATEGORIES: Acute, Chronic.
313 REPORTABLE INGREDIENTS: None
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)
CERCLA REGULATORY: None
TSCA (TOXIC SUBSTANCE CONTROL ACT)
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Spal-Pro RSF A
TSCA REGULATORY: All components are in TSCA inventory.
RCRA STATUS: If discarded in its purchased form, this material is not a RCRA hazardous waste.
16. OTHER INFORMATION
PREPARED BY: L. Priest Date Revised: 03/18/2015
COMMENTS:
ACGIH American Conference of Governmental Industrial Hygienists
CAS Chemical Abstracts Service
EC
50
Median effective concentration
EINECS European Inventory of Existing Commercial Chemical Substances
GHS Globally Harmonized System of Classification and Labelling of Chemicals
IARC International Agency for Research on Cancer
IATA International Air Transport Association
ICAO International Civil Aviation Organization
IMDG International Maritime Dangerous Goods
IMO International Maritime Organization
LC
50
Lethal concentration to 50% of exposed laboratory animals
LD
50
Lethal dose to 50% of exposed laboratory animals
TWA Time-weighted average
TLV Threshold limit value
NIOSH US National Institute of Occupational Safety and Health
NE Not established
NTP US National Toxicology Program
OEL Occupational exposure limit
OSHA US Occupational Safety Health Administration
PEL Permissible exposure limit
RQ Reportable quantity
STEL Short term exposure limit
MANUFACTURER DISCLAIMER: The information in this SDS was obtained from sources that we believe are reliable. The
information is provided without warranty, implied or expressed, concerning accuracy. The manufacturer assumes no legal
responsibility for use or reliance on this information. This SDS is proveded solely for the purpose of converying health, safety
and environmental information. This SDS is not a specification data sheet. Some of the information and conclusions may be
derived from sources other than test data on the material itself.
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Spal-Pro RSF A
