Honeywell Gas Detection Tubes And Sampling Handbook
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For Sales & Service Contact 2650 E. 40th Ave. • Denver, CO 80205 Phone 303-320-4764 • Fax 303-322-7242 1-800-833-7958 www.geotechenv.com Gas Detection Tubes and Sampling Handbook Table Of Contents www.honeywellanalytics.com TABLE OF CONTENTS 1. INTRODUCTION..................................................................................... 3 2. QUALITY ASSURANCE PROCEDURES................................... 5 3. OPERATION OF DETECTION TUBES AND PUMPS............................ 7 3.1 Hand Pump Description................................................................... 8 3.2 Tube Measurements…………………………………………............... 8 3.2.1 Tube Description and Packaging...................................... 8 3.2.2 Testing Hand Pump for Leaks........................................ 10 3.2.3 Measurement Procedure................................................ 10 3.2.4 Reading Tubes……………………………………............. 13 3.3 Maintenance of the LP-1200 Piston Hand Pump........................... 14 3.4 Selection of Sampling Pump.......................................................... 15 3.5 Operation and Maintenance of Remote Sampler........................... 15 4. TECHNICAL INFORMATION................................................................ 19 4.1 Theory of Operation....................................................................... 19 4.2 Explanation of Data Sheets........................................................... 20 4.3 Humidity, Temperature, Pressure and Matrix Effects..................... 22 5. DATA SHEETS FOR GAS DETECTION TUBES................................. 26 6. SPECIALTY TUBES............................................................................ 103 6.1 Smoke Generating Tubes............................................................ 103 7. APPENDICES..................................................................................... 105 7.1 Appendix 1. Alphabetical Tube List............................................. 105 7.2 Appendix 2. Tube List by Part Number....................................... 107 7.3 Appendix 3. Detectable Compounds........................................... 109 7.4 Appendix 4. Equivalent Tubes of Other Manufacturers............... 114 7.5 Appendix 5. Conversion Factors for Gas Concentrations........... 117 7.6 Appendix 6. Humidity Conversion Tables.................................... 118 7.7 Appendix 7. Warranty.................................................................. 119 7.8 Appendix 8. Honeywell Analytics Contacts................................. 120 1 INTRODUCTION WARNING The products described herein will perform as designed only if they are used, maintained, and serviced in accordance with the manufacturer’s instructions. Failure to use, maintain, and operate products properly can result in dangerously inaccurate readings. CAUTION: For safety reasons, the equipment described herein must be operated and serviced by qualified personnel only. Read and understand this instruction manual completely before operating or servicing. ATTENTION: Pour des raisons de sécurité, ces équipments Doivent être utilisés, entretenus et réparés uniquement par un personnel qualifié. Étudier le manuel d’instructions en entier avant d’utiliser, d’entretenir ou de réparer l’équipement. Custom Tubes Please contact Honeywell about the availability of custom tubes not included in this handbook. Contact information is included on page 128. Application & Technical Notes Honeywell’s web site includes the Application Notes and Technical Notes cited in this handbook, as well as many others. Visit our web site at: www. honeywellanalytics.com. © 2014 by Honeywell International. This handbook is fully protected by copyright, and no part of it may be reproduced in any form without the express written consent of Honeywell, 3775 N. First St., San Jose, CA 95134-1708 USA. 2 www.honeywellanalytics.com 1. INTRODUCTION Gas detection tubes operate in the following manner: An air sample is drawn through a tube containing a reagent, causing a color change. The concentration is then read from the length of the color stain in the reagent. The advantages of detection tubes over other analytical methods are simplicity of use, rapid response, low cost, and very low maintenance. Because each batch of Honeywell tubes is pre-calibrated, no calibration equipment is necessary. Errors are prevented by directly marking the calibration information on each tube, and accuracy is further ensured by controlling the volume of air sampled. Honeywell tubes are primarily of the narrow bore type and are designed for use with a Honeywell handoperated piston pump. Air sampling can also be performed using piston pumps, which latch into a precisely defined position to fix the volume. These pumps pull a strong vacuum initially and thus create substantially higher flowrate than the bellows pumps. Piston pumps generate a high flow initially followed by an approximately exponential decay, whereas bellows pumps provide a more steady flow initially followed by the slow decay. The difference in flow patterns means that the pumps cannot be interchanged between types. For example, piston pumps sometime cause a smearing of the color stain when used on tubes originally developed for bellows pumps. This occurs because the higher flow rates do not allow enough contact time to give sharp endpoints when a piston pump is used. For a period of time, attempts were made to improve accuracy by stabilizing the flow rate using rate-limiting orifices. Some manufacturers supplied as many as four different orifice sizes to match the particular tube being used. However, exchanging limiting orifices proved to be cumbersome and unnecessary as long as enough contact time was allowed to avoid smearing the stain. Therefore, limiting orifices have fallen out of use and it has now become standard practice to build the flow restriction into the tube itself. This is done by selecting the particle size of the support material and type of end plug that give a sampling time appropriate for the particular chemical reaction of the tube. www.honeywellanalytics.com 3 INTRODUCTION This handbook describes the use and performance of gas detection tubes and sampling pumps manufactured by Honeywell. Honeywell began manufacturing gas detection tubes in 1997 and is adding many new tubes to its product line each year. Modern production facilities and techniques allow us to offer high-quality tubes at a highly competitive price. INTRODUCTION As a result of these developments, modern tube/pump systems have stabilized into two categories: (1) low-vacuum bellows pumps with less flow resistance in the tubes, by virtue of being wider (~7 mm o.d.) and having larger particles, and (2) high-vacuum piston pumps with greater resistance in the tubes by being narrower (~5 mm) and having smaller particles. The bellows pump/tube systems tend to have faster sampling but require more pump strokes to complete a measurement, whereas the piston pump systems generally need fewer strokes but longer sampling time per stroke. Honeywell tubes are primarily of the narrow-bore type and are designed for use with a piston sampling pump. 4 www.honeywellanalytics.com 2. QUALITY ASSURANCE PROCEDURES FOR GAS DETECTION TUBE MANUFACTURE All Honeywell gas detection tubes are developed in an ISO 9001 certified facility and manufactured in an ISO 9001 certified factory. All procedures, work instructions, and quality records are documented and maintained to ensure tube quality. The procedures are outlined below. A. Tube Selection. Glass tubing is selected to fit a standard bore size to ensure uniform length of color change. C. Reagent Loading. Chemicals are chosen according to strict purity standards and loaded onto the support materials. Deposition of the chemicals onto the support follows a protocol developed specifically for each tube type. The loaded support material is then dried as needed for the reaction. D. Tube Filling and Sealing. End plugs are selected of materials that do not react with the reagent. The tubes are filled under conditions that minimize exposure to air, water vapor, or other gases that may affect the quality of the tubes. The tubes are then packed tightly by a combination of shaking and physical compression. The ends of the tubes are then melted closed using an automated flame sealer. Any necessary inert atmosphere is maintained through the tube-sealing process. E. Calibration. Each batch of tubes is calibrated independently of other batches. A series of standard gases are purchased or prepared by a variety of methods, including flow dilution of gas primary standards, permeation tubes, and diffusion tubes, or static dilution from liquid or gas primary standards. Multiple tubes are used to determine each calibration position, and these are then printed onto each tube in the batch with an automated printing machine. www.honeywellanalytics.com 5 QUALITY ASSURANCE B. Support Preparation. Silica, alumina, and other support materials are chosen from the highest quality available and sieved to yield a narrow particle size distribution. The supports are then further purified as necessary and dried to well-defined levels depending on the requirements of the tube reactions. OPERATION F. Packaging. The tubes and their technical data sheets are packed into labeled boxes with protective corrugated cardboard. G. Quality Control Sampling Plan. A portion of each batch is sent to the Honeywell's Quality Assurance Laboratory for independent QA testing. The most widely used tubes pass the accuracy criterion of ≤±15% of length of stain. A separate set of tubes is stored in the QA laboratory and the manufacturing facility for evaluation at later dates, if necessary. H. Accuracy and Precision. The accuracy is measured by testing at least five tubes and calculating the average deviation from the standard gas value. The precision is calculated as the standard deviation from the average value of the five measurements. All tubes meet the accuracy and precision criteria listed in Table 2-1: Table 2-1. Honeywell Tube Accuracy and Precision Specifications Conc. Range Precision CO, CO2, H2O , H2S, NH3, PH3, SO2 >50 ppm CO, H2O , H2S, NH3, PH3, SO2 Tube Type CO, Acetone, Benzene, MEK, Toluene, Xylene Cl2, ClO2, HCN, HCl, HF, NOx, NO2, RSH, RNH2, Butane, Diesel, Ethanol, Formaldehyde, Gasoline, Methyl Bromide, Ozone, Phenol, Trichloroethylene, Vinyl Chloride, others I. 6 Accuracy >20-100% Full Scale ≤20% Full Scale 10% 10% 12% <50 ppm 12% 15% 20% All 12% 15% 20% All 20% 20% 25% Interim Storage. Only batches that pass all quality assurance procedures are sent to interim storage, where they are maintained at 3-7°C (37 - 45°F) in darkness until shipment. www.honeywellanalytics.com 3. OPERATION OF DETECTION TUBES & PUMPS CAUTION: Wear safety glasses and gloves when opening tubes or handling open tubes with sharp edges. Failure to wear protective equipment may lead to cuts and other severe injuries to eyes and hands. Always test the pump for leaks immediately before using it for a series of measurements. Failure to test the pump for leakage may lead to dangerously inaccurate readings. Avoid contact with tube contents in case of accidental breakage. Exposure to tube contents can result in significant health hazards. Dispose of spent tubes according to local regulations. Review the reaction principle and other information listed in the Gas Detection Tube Data Sheet supplied to identify materials that may require special disposal procedures. (Data Sheets for all currently available Honeywell tubes are included in Chapter 5.) OPERATION www.honeywellanalytics.com 7 3.1 Hand Pump Description Figure 3-1. LP-1200 Hand Pump with tube inserted. The LP-1200 is a piston-type hand pump that draws a fixed volume of gas, selectable at either 50 mL or 100 mL by rotating the handle. A tight vacuum seal is formed by a greased plunger gasket. The tapered rubber inlet accommodates a range of tube diameters for different types of tubes. The inlet filter prevents glass pieces and dust from entering the shaft. An end-of-flow indicator in the handle turns white when the gas sampling is complete. A pump stroke counter is rotated to keep track of the number of strokes completed. 3.2 Tube Measurements OPERATION 3.2.1 Tube Description & Packaging Figure 3-2. Gas detection tube parts description. Top: Standard single tube. Bottom: Pretreatment tube connected to measurement tube with rubber connector. 1. Tube and Box. Figure 3-2 shows the key components of a Honeywell gas detection tube. The tubes are typically packaged in a box of 10 tubes. Each box has quick instructions on the back. Some tubes require preconditioning of the gas and are packaged with 5 pretreatment tubes and 5 measurement tubes for a total of 5 measurements. The concentration scale is printed on the tube and an arrow indicates the direction in which the gas must enter. The standard number of 100 mL 8 www.honeywellanalytics.com strokes is indicated on one side, along with the total sample volume, the unit of measure, the gas type, and the batch number. 2. Data Sheet. Each box is packaged with a Data Sheet that provides detailed information on the tube performance. Figure 3-3 is an excerpt of a typical data sheet. Complete data sheets are provided in Chapter 5 and discussed in detail in Chapters 4.2 and 4.3. Gas Detection Tube Data Sheet Hydrogen Sulfide H2S No. H-10-103-18 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor (CF) Extended Range 12.5 - 125 2 200 2x1 0.5 Standard Range 25 - 250 1 100 1 1 Extended Range 50 - 500 0.5 50 1 2 Figure 3-3. Excerpt of a Tube Data Sheet 3. Part Number. The 7-digit part number is indicated on the top right of the data sheet. The second 3 digits indicate the tube chemical type, and the last two digits number indicate the approximate range of the tube. The higher the number, the higher the range. www.honeywellanalytics.com 9 OPERATION 4. Sampling Volume and Time. Using the standard number of pump strokes, the concentration of the gas is read from stain length directly matched to the printed scale after the listed sampling time has elapsed. However, the range of the tube may be extended by using a smaller or larger sample volume. In such cases, the scale reading must be multiplied by a Correction Factor (CF) to adjust for the different sample size. For example, the Honeywell H-10-103-18 hydrogen sulfide tube has a standard range of 25-250 ppm. When used with the standard one stroke, the readings will correspond directly to the printed scale on the tube. When used with half a stroke, a Correction Factor (CF) of 2 is applied. An observed reading of 50 ppm then corresponds to an actual concentration of: 50 x 2 = 100 ppm OPERATION 5. Cross-sensitivity. Gas detection tubes are generally quite selective, but some compounds may interfere in the measurements. The Data Sheet lists possible interfering compounds; others may also exist. In most cases these compounds increase the stain length, but in some cases they decrease the stain length. The user must be aware of potential interferences, or incorrect readings may result. 3.2.2 Testing Hand Pump For Leaks Before a series of measurements, the pump used must be tested for leaks. Follow this procedure: 1. Insert an unopened tube snugly into the inlet of the aspirating pump. 2. Align the red dot on the plunger with the red dot on the pump shaft. 3. Pull the plunger one full stroke and wait 2 minutes. 4. Rotate the plunger dot away from the pump shaft alignment mark, and allow the plunger to be drawn back into the pump shaft. Keep your hand on the shaft to keep it from snapping back too suddenly. There are no leaks if the plunger returns to within 3 mm of its original position. If a leak is detected, refer to Section 3.3 for maintenance procedures. 3.2.3 Measurement Procedure 1. Break both ends of a new detection tube using the tip breaker on the side of the pump. Insert the tube until it stops, and then back off about 1 mm before breaking off the tip. The latter procedure allows the tip to fall into the tip reservoir at the end of the pump shaft. The reservoir can be emptied by opening the rubber cover on the opposite side of the pump. Break tube open at both ends. 10 www.honeywellanalytics.com 2. In cases where a pre-tube is provided (e.g., Benzene H-10-101-01 and NOx H-10-109-20), connect the pre-tube to the measurement tube using the rubber connector in the direction indicated on the tube. 3. Insert the measurement tube securely into the rubber pump inlet. Point the tube arrow towards the pump (see Figs. 3-1 and 3-2). Insert open tube with arrow pointing towards pump. 4. Select the sample volume desired and align the red dot on the plunger with the red dot on the pump shaft. Pull the handle quickly until it latches at ½ or 1 full stroke (50 or 100 mL) and wait for the sampling time indicated on the data sheet to allow the air to be drawn through the tube. The end-of-flow indicator is dark during sampling. Flow is complete when the end-of-flow indicator returns to its white color. Withdraw plunger sharply until it locks in place, and rotate stroke counter. End-of-flow indicator is dark when sampling (left) and white when sampling is complete (right). www.honeywellanalytics.com 11 OPERATION Wait for indicated sampling time when end-of-flow indicator turns white. OPERATION 5. For additional pump strokes, rotate the handle ¼ turn clockwise or counterclockwise and push it back fully without removing the tube from the pump. Then repeat Step 4. If additional strokes are needed, rotate plunger 90 degrees. Push plunger back into pump shaft without removing tube. Withdraw plunger for second stroke and repeat strokes as necessary. Remove and read tube; return plunger and stroke counter to original position; empty tube tip reservoir as necessary. 12 www.honeywellanalytics.com 3.2.4 Reading Tubes 1. The concentration of the compound being measured is read directly from the scale printed on the tube. 2. The reading is taken as the furthest distance along the tube that the color change just becomes visible. If the leading edge is diagonal instead of perpendicular to the axis of the tube, use the average of the minimum and maximum values. The three tubes shown in Figure 3-4 are all read as 0.9. Figure 3-4. Reading of various types of endpoints after sampling. 3. Read the tube immediately after gas sampling, as colors may change, fade, or disperse with time. 5. If humidity and temperature corrections are necessary as indicated on the Data Sheets, multiply the observed readings by the given Correction Factor(s) (CF) to obtain the true concentration. For more details and a theoretical discussion, see Chapter 4.3 on the effects of humidity and temperature. 6. The user must be aware of potential interfering compounds in the tube measurements. Interferences can be either positive or negative. CAUTION: Always examine the data sheet and other available information for possible interferences. Failure to consider interferences may lead to dangerously inaccurate readings. www.honeywellanalytics.com 13 OPERATION 4. If a non-standard number of pump strokes was used for sampling, multiply the reading by the Correction Factor given on the tube Data Sheet (Chapter 5). 3.3 Maintenance of the LP-1200 Piston Hand Pump Figure 3-5. Transparent view of LP-1200 pump showing internal parts. 1. Tube Tip Reservoir Remove the tube tip reservoir cover as needed to empty the broken glass reservoir that is in the pump end fitting. 2. Pump Inlet and Filter The rubber pump inlet can become worn with use and result in leaks. Unscrew the pump inlet nut and replace the rubber inlet. If the inlet is not replaced, inspect the inlet filter and replace or clean the filter when it becomes visibly dirty or if the end-of-flow indicator on the pump shows that the flow takes longer than recommended on the tube box. 3. Pump Mechanism The plunger gasket may leak if it is worn or not well lubricated. To replace the gasket: 1. 2. 3. 4. OPERATION Unscrew the pump end fitting on the handle side. Pull the plunger out of the pump shaft. Replace the gasket. Carefully push the plunger back into the shaft. Use a fine screwdriver or tweezers to help ease the gasket into the shaft. 5. Lubricate the inside of the shaft with vacuum grease to ensure a good seal. Caution: Do not overtighten the plunger gasket. It could cause a sudden loss of vacuum. The inlet check valve may cause leaks if worn or not lubricated. Unscrew the end fitting on the inlet side and pull out the disk-shaped rubber-inlet check valve. Replace as necessary, adding a light coat of grease around the hole. 14 www.honeywellanalytics.com Replace the outlet check valve gasket if there is resistance on the return stroke. Using the special tool or needle-nose pliers, unscrew the plunger tip from the plunger rod. Replace the O-ring, check valve gasket as necessary, and reassemble. Inspect the gasket ring in the inlet end fitting. If it is damaged, replace before screwing the end fitting back on. 3.4 Selection Of Sampling Pump Honeywell tubes are designed for operation with a Honeywell hand pump for drawing samples through Honeywell tubes. Pumps from different manufacturers may have different flow patterns or deliver different volumes, which can cause significant errors. For example, bellows hand pumps as supplied by MSA and Draeger have substantially different flow patterns. Caution: Use of a sampling pump other than a Honeywell hand pump may cause serious errors. Always test any pump for leaks before use. 3.5 Operation And Maintenance Of Remote Sampler 1. Installation Refer to Figure 3.7 for installation and part descriptions. Unscrew the pump adapter nut and remove the standard rubber tube adapter from the pump. Inspect the remote sampler to ensure that the porous metal filter is in place, and screw the pump adapter nut attached to the sampler into the pump. Store the standard nut and rubber adapter in a safe place for later use. www.honeywellanalytics.com 15 OPERATION The Detection Tube Remote Sampler is designed for use with Honeywell hand pumps for gas-detection tubes and adsorption tubes. The flexible Remote Sampler allows gases to be sampled through narrow apertures, down holes, or from other areas remotely located from the sampling pump. The sampler is available in two lengths, 15 feet (4.5 meters), p/n H-010-3009-015, and 35 feet (11 meters), p/n H-010-3009-035. OPERATION 2. Operation To ensure a good seal, insert the gas detection tube into the tube holder and twist the tube while pushing in. If the tube uses a pre-tube, insert the pre-tube into the pre-tube holder and push the pre-tube into the end of the standard tube holder. Secure the pre-tube holder using the rubber buckles. Lower the extension hose to the desired position. Figure 3-6. Installation of the remote sampling probe into the LP-1200 hand pump. 3. Correction Caution: In order to obtain accurate readings, the following corrective procedures must be employed when using the 35-foot (11-meter) remote sampler. The 35-foot (11-meter) remote sampler causes a slight delay and reduced reading because of the extra volume in the extension tubing. Increase the sample time by 30 seconds for a 2-minute tube, 20 seconds for a 1.5-minute tube, and by 15 seconds for a 1-minute tube. Then multiply the reading by 1.08 to obtain the corrected value. Corrections for the 15-foot (4.5-meter) remote sampler are unnecessary. 16 www.honeywellanalytics.com 4. Routine Maintenance a. Porous Metal Filter: The metal frit filter should be replaced when it becomes visibly dirty or if the end-of-flow indicator on the pump shows that the flow takes longer than recommended on the tube box. b. Leak Test: If a leak is discovered with either pump, first remove the probe and check the pump for leaks. Then examine the tubing and connections for the leak source, as follows: i. Hand Pump: Insert a sealed tube into the tube holder tightly. Pull 3 pump strokes to expel the air from inside the tubing. Pull a fourth stroke and wait for 2 minutes. Rotate the plunger dot away from the pump shaft alignment mark, and allow for the plunger to be drawn back into the pump shaft. Keep your hand on the shaft to prevent it from springing back too suddenly. If the plunger returns to within 3 mm of its original position, there are no leaks. OPERATION www.honeywellanalytics.com 17 OPERATION 18 www.honeywellanalytics.com 4. TECHNICAL INFORMATION 4.1 Gas Detection Tube Theory Of Operation • Acid-base reactions These include reactions of acidic gases like HCl and HF with bases, and reaction of alkaline vapors such as ammonia with an acid in the tube. A dye present in the tube changes color as the pH changes on exposure to the vapors. • Reduction-oxidation (Red-ox) reactions These generate an oxidized or reduced compound, which has a different color. The chlorine tube uses oxidative coupling of colorless o-toluidine to form an orange azodye. White di-iodine pentoxide is reduced by CO and many organic vapors to form deep brown-colored iodine. Orange chromium (VI) is reduced by many organic compounds to form brown or green-colored Cr(III) compounds. • Ligand-exchange reactions These generate new complexes that are more colored than the starting reagents. The most notable is the conversion of white lead acetate to brown-black lead sulfide in the detection of H2S. In the case of phosphine, the exchange of PH3 for the chlorine ligand of HgCl2 releases HCl, which then causes a pHdependent dye-color change. • Pre-layers or Pre-tubes These are used to condition the sample by controlling humidity, removing interferences, or transforming the analyte to another detectable compound. Examples include drying agents in NH3 and HCl tubes, organic removal by charcoal or oxidation in selective CO tubes, and oxidation of NO to NO2 in the nitrogen oxides tube. All Honeywell detection tubes are length-of-stain types. In these tubes, the reaction of the gas with the supported reagent is fast, compared to the transport of the bulk air sample through the tube. Therefore, all of the detected vapors are reacted within the tube. As a result, there is not a strong dependence of the readings on the rate at which the gas is sampled. However, a very high flow rate can cause some smearing to a high reading. Conversely, low flow rates are less likely to affect the stain www.honeywellanalytics.com 19 TECHNICAL INFORMATION Gas detection tubes operate on a chemical reaction between the vaporphase compound and a liquid or solid detecting reagent, which is supported on an inert matrix. The most common types of reactions are the following: TECHNICAL INFORMATION length, but can give low readings by concentrating the colored products in a shorter section of the tube. In cases of flow extremes, errors outside the standard 25% accuracy can be produced. Honeywell tubes are calibrated using Honeywell piston hand pumps. The flow during a single pump stroke initially rises sharply and then decays exponentially (see Figure 4-1). The best accuracy is therefore obtained when the flow through the tube mimics this profile. Figure 4-1. Piston pump internal pressure pattern. Data is offset by 2 seconds. 4.2 Explanation Of Data Sheets The Data Sheets supplied with each box of tubes give representative information applying to all batches. The Data Sheets include: 1. Standard and extended measurement ranges, pump strokes required, gas volumes required, sampling times, and the detection limit. The standard range and strokes apply to the calibration scale printed on the tubes. The range can usually be extended to higher or lower concentrations by reducing or increasing, respectively, the number of pump strokes. 2. Correction Factors (CF) for conditions of pump stroke, temperature, humidity, or gas type other than the standard conditions. The CF is multiplied by the observed reading to obtain the corrected concentration. 20 www.honeywellanalytics.com 3. Precision. This value is determined by measuring a standard gas sample with at least 5 randomly chosen tubes. Precision is reported as the standard deviation from the average of the 5 measurements. Precision is typically ≤±15%. (See Section 2 for complete table.) 5. Humidity. The effect on the reading as a function of humidity of the standard gas is listed. Any required Correction Factors are tabulated. 6. Temperature. The effect of temperature is determined by equilibrating the gas sample, tube, and pump to the test temperatures, typically 0°, 10°, 25°, and 40°C (32°, 50°, 77°, and 104°F). Any required Correction Factors are tabulated. If humidity has a measurable effect on the gas readings, the temperature tests are performed at constant relative humidity (not absolute humidity). Any temperature corrections should be multiplied by any humidity corrections to obtain true readings. 7. Storage Life. Samples of tubes are stored for extended periods to evaluate their accuracy at defined time periods to determine their storage life. The user should store tubes in darkness at 3° to 7°C (37° to 45°F) to maximize their shelf life. Freezing tubes (storage below 0°C, or 32°F) can damage some types and is not recommended. 8. Cross-Sensitivity. Tubes are challenged with a variety of possible interfering gases to quantitate their relative response. Although the tubes are highly selective, compounds that are chemically similar to a target compound sometimes show a positive interference. Others interfere with the measurement gas without showing a response on their own; for example, when acidic vapors coexist with basic vapors. Such information is listed in a separate note or column titled “Interferes in Mixtures.” The user should know as much about the sample environment as possible in order to make sound judgments regarding possible interferences; otherwise inaccurate readings may result. In some cases, a different color or pattern of the stain can clue the user to the presence of an interfering compound. www.honeywellanalytics.com 21 TECHNICAL INFORMATION 4. Linearity with number of pump strokes. Multiple strokes are measured with a gas standard with concentration at the low end of the tube. Tubes must have correlation coefficients (r2) >0.95 to be considered linear. TECHNICAL INFORMATION 4.3 Humidity, Temperature, Pressure, and Matrix Effects 1. Humidity Humidity has little effect on most tubes either because the reaction is insensitive to moisture or because drying agents are added to absorb the moisture in a pre-layer (see Figure 4-2). Humidity tends to have the greatest effect on compounds that are highly water-soluble, such as acids and bases. HF (hydrofluoric acid) is a notable example that requires humidity corrections; water-adsorbing prelayers cannot be used because they tend to be reactive with HF. The humidity effect tends to be greater as the concentration range of the tube is lowered. When correcting for humidity, the CF is multiplied by the reading in addition to multiplying by any temperature correction. Any necessary Correction Factors are listed in the individual tube data sheets. Note that the relative humidity at the measurement temperature defines the correction, rather than the absolute humidity. Figure 4-2. Effect of humidity on gas detection tube readings. 22 www.honeywellanalytics.com 2. Temperature Figure 4-3. Effect of temperature on gas detection tube readings. Additional factors occur in special cases. For example, pretube or prelayer reactions are sometimes more complete at higher temperatures, causing higher readings in the measurement layer. In some cases, the color of the stain can change. In the water vapor H-10-120-20 tube, the color stain is green at room temperature and a more purple color below room temperature. www.honeywellanalytics.com 23 TECHNICAL INFORMATION Temperature can affect gas tube readings in at least three ways. First, as the temperature increases, the gas density decreases, causing a tendency for the reading to decrease (see pressure effects described in the next section). Second, as the temperature increases, the reaction rate increases, causing the reading to be sharper and shorter. A third, balancing effect is that adsorption is often a prerequisite for reaction. Adsorption is weaker as temperature increases, and thus the reading can become longer. The interplay of these competing effects results in some stains that are longer with increasing temperature, and others that are shorter. TECHNICAL INFORMATION 3. Pressure Tubes change color in proportion to the mass of the compounds reaching the reagent (i.e, the absolute concentration). Therefore, as the pressure decreases at higher altitudes, the apparent response is reduced because there are fewer molecules per unit volume sampled. The conventional desired reading is in ppmv (parts per million by volume), which is a relative concentration, such as a mole or volume fraction (% of molecules of compound per molecules of total gas [air]), rather than an absolute concentration. All Honeywell tubes are calibrated at 1 atmosphere (760 mm Hg) pressure at sea level. • For tubes calibrated in absolute concentrations such as lbs./MMCF or mg/m3, no pressure corrections are needed. • For tubes calibrated in relative concentrations (e.g., ppm), correct for pressure using one of the following equations: Corrected reading = Observed Reading x 760 mm Hg Pressure (mm Hg) Corrected reading = Observed Reading x 101.3 kPa Pressure (kPa) Corrected reading = Observed Reading x 14.7 psia Pressure (psia) The pressure in mm Hg can be estimated as a function of altitude using the following equation: P (mm Hg) = 760exp(-0.1286[alt(km)]) below 2 km Example Correction Factors are listed in the following table as a function of altitude. Weather changes may also affect the atmospheric pressure, but the necessary corrections are usually <10%. 24 www.honeywellanalytics.com Example Location Altitude (feet) 0 1000 2000 3000 4000 5000 6000 7000 8000 9000 10000 Pressure, (mm Hg) 760 731 703 676 650 625 601 578 555 534 514 CF 1.00 1.04 1.08 1.12 1.17 1.22 1.27 1.32 1.37 1.42 1.48 4. Matrix Gas The matrix gas usually has little or no effect on the tube readings as long as the gas does not chemically react with the tube reagents or measured compound. Thus, readings in air, nitrogen, hydrogen, helium, or carbon dioxide give essentially the same results. However, the viscosity of the gas has a significant effect on the sampling time. Thus, for example, the sampling time of the CO H-10-102-18 tube is about half as long in pure hydrogen (viscosity 9.0 μPa-s) as it is in air (viscosity 18.6 μPa-s). Matrix Gas Air n-Butane Propane Hydrogen Ethane Acetylene Methane Carbon Dioxide Nitrogen Helium Oxygen Argon Neon Viscosity @ 27°C (μPa-s) 18.6 7.5 8.3 9.0 9.5 10.4 11.2 15.0 17.9 20.0 20.8 22.9 32.1 Sampling Time Relative to Air 1.00 0.40 0.45 0.48 0.51 0.56 0.60 0.81 0.96 1.08 1.12 1.23 1.73 Sampling Time for a 90 second Tube (seconds) 90 36 40 44 46 50 54 73 87 97 101 111 155 At a given viscosity, higher flow rates tend to give longer stains. However, this is often compensated by higher diffusion rates to the reactive surface in the less viscous gases, resulting in no significant effect on the readings. www.honeywellanalytics.com 25 TECHNICAL INFORMATION San Francisco, CA Atlanta, GA Spokane, WA Rapid City, SD Salt Lake City, UT Denver, CO Colo. Spgs., CO Santa Fe, NM Alta, UT Winter Park, CO Keystone, CO Altitude (km) 0 0.3 0.6 0.9 1.2 1.5 1.8 2.1 2.4 2.7 3.0 DATA SHEETS 5. DATA SHEETS FOR GAS DETECTION TUBES Acetone C3H6O No. H-10-111-40 Extended Range 0.05 - 1% 2 200 2x2 0.5 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Standard Range 0.1 - 2% 1 100 2 1 Extended Range 0.2 - 4% 0.5 50 1.5 2 Precision (Relative Standard Deviation)*: ≤ ±12% Linearity with No. of Pump Strokes: r2 = 0.992 Humidity: No effect 5 - 85% RH Temperature Range: Temp (°C/°F) Corr. Factor 0/32 1.25 0 - 40°C (32 - 104°F) 10/50 1.15 25/77 1.0 40/104 0.95 Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: Orange → Black Reaction Principle: CH3COCH3 + Cr(VI) + H2SO4 → Cr(III) + Oxidation Prods. Cross-sensitivity: Substance Methyl ethyl ketone Methyl propyl ketone Methyl isobutyl ketone CO CO2 CH4 NH3 H2S Ethyl Acetate Hexane Isobutylene Toluene Concentration (ppmv) Apparent Reading* Corr. Factor 0.6% 1.0% 1.0% 1.5% 1.5% 2.5% 5.0% 300 1.0% 0.24% 0.20% 400 0.55% 0.65% 0.40% 0 0 0 1.4% brown 0.5% diffuse# 0.85% diffuse# entire tube# entire tube# 0.3% diffuse# 1.1 1.5 2.5 3.6 - * Data based on Honeywell pumps and tubes used in standard range. # Faint black color over entire stain length. Ketones can be distinguished by their darker stains and sharp endpoints. Other Possible Interferences: Other hydrocarbons. 26 www.honeywellanalytics.com Amines RNH2 (CH3NH2) No. H-10-132-10 Extended Range 0.25 - 5 2 200 2x1 0.5 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Standard Range 0.5 - 10 1 100 1 1.0 Extended Range 1.0 - 20 0.5 50 1 2.0 Precision (Relative Standard Deviation)*: ≤ ±20% Linearity with No. of Pump Strokes: r2 = 0.997 Humidity: No effect 0 - 90% RH Temperature Range: 0 - 40°C (32 - 104°F) @ constant 50%RH. Temp (°C/°F) Corr. Factor 0/32 1.16 10/50 1.10 20/68 1.0 30/86 0.96 40/104 0.96 Cross-sensitivity: Substance Ammonia Methylamine Ethylamine Allyamine Diethylamine Trimethylamine Triethylamine Methylaziridine (Propylene imine) Ethylenediamine Ethanolamine Pyridine H 2S CO Isobutylene HCl Concentration (ppmv) Apparent Reading* Correction Factor 5 10 8 7.4 5 4.5 6 5 7 36 10 100 500 100 1000 6.0 10* 7.0 8.0 6.3 9.8 9.5 6.5 2.0# 4.1# Over range† 0 0 0 0£ 0.8 1.0 1.1 0.93 0.79 0.46 0.63 0.77 3.5 8.8 - * Data based on Honeywell pump and tubes used in standard range. This tube is calibrated using methylamine. # Deep purple with yellow stain at endpoint. † Slight color change to light pink. £ Interferes in mixtures. Other Possible Interferences: Other bases. www.honeywellanalytics.com 27 DATA SHEETS Storage Life: 1 year in darkness at 5-25°C (40-77°F). Refrigeration preferred. Color Change: Pink → Yellow Reaction Principle: 2RNH2 + H2SO4 → (RNH3)2SO4 DATA SHEETS Ammonia NH3 No. H-10-100-05 Extended Range Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Standard Range 0.5 - 15 2 200 2 x 1.5 0.55 1 - 30 1 100 1.5 1 Extended Range 2 – 60 0.5 50 1 2.4 Precision (Relative Standard Deviation)*: ≤ ± 12% Linearity with No. of Pump Strokes: r2 = 0.999 Humidity: The tubes are calibrated at 50% RH @ 24 °C (75 °F) % RH Corr. Factor < 5% 0.8 Temperature Range: Temp (°C/°F) Corr. Factor 0/32 0.9 10% 0.85 50% 1.0 80% 1.0 95% 1.0 0 - 40°C (32 - 104°F) @ constant 50%RH 10/50 0.95 25/77 1.0 35/95 1.1 Storage Life: 2 years in darkness at 5 - 25°C (40-77°F). Refrigeration preferred. Color Change: Purple → Beige Reaction Principle: Prelayer reduces humidity effects 3NH3 + H3PO4 → (NH4)3PO4 Cross-sensitivity: Substance Pyridine Diethylamine Hydrazine Methylhydrazine CO CO2 H 2S Hexane Isobutylene Toluene Concentration (ppmv) 10 20 20 20 100 20000 200 100 100 100 Apparent Reading* 15 18 2** 2.3** 0 0# 0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. ** These hydrazines can be measured using 2 strokes with a CF of 5. # 16000 ppm CO reduces the NH response by 30% in mixtures, 5000 ppm CO reduces 2 2 3 NH3 response by 10% in mixtures, and 1000 ppm CO2 has no effect. Other Possible Interferences: Amines and other bases. 28 www.honeywellanalytics.com Ammonia NH3 No. H-10-100-10 Extended Range 2.5 - 50 2 200 2x1 0.5 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Standard Range 5 - 100 1 100 1 1 Extended Range 10 – 200 0.5 50 1 2 Precision (Relative Standard Deviation)*: ≤ ± 12% Linearity with No. of Pump Strokes: r2 = 1.000 Humidity: @ 24 °C (75 °F) The tubes are calibrated at 50% RH. % RH Corr. Factor < 5% 0.7 20% 0.8 50% 1.0 70% 1.1 90% 1.3 Temperature Range: 0 - 35°C (32 - 95°F) @ constant 50% RH 0/32 0.8 10/50 1.0 24/75 1.0 34/93 1.0 Storage Life: 2 years in darkness at 3 - 10°C (37 - 50°F). Refrigeration required. Color Change: Purple → Beige Reaction Principle: Prelayer reduces humidity effects 3NH3 + H3PO4 → (NH4)3PO4 Cross-sensitivity: Substance Butylamine Diethylamine CO Concentration (ppmv) Apparent Reading* 100# 45 50# 60 250 0 100# 0 H2S 100# 0 SO2 50000 0 CH4 50000 0 CO2 200 0 NO2 100 0 Hexane 100 0 Isobutylene 100 0 Toluene * Data based on Honeywell pumps and tubes used in standard range. # At 50% RH. Other Possible Interferences: Amines and other bases. www.honeywellanalytics.com 29 DATA SHEETS Temp (°C/°F) Corr. Factor DATA SHEETS Ammonia NH3 No. H-10-100-12 Extended Range 5 - 130 2 200 2 x 1.5 0.5 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Standard Range 10-260 1 100 1.5 1 Extended Range 20 - 520 0.5 50 1 2 Precision (Relative Standard Deviation)*: ≤ ± 12% Linearity with No. of Pump Strokes: r2 = 1.000 Humidity: @ 22 °C (72 °F) The tubes are calibrated at 50% RH. % RH Corr. Factor < 5% 0.8 Temperature Range: Temp (°C/°F) Corr. Factor 0/32 0.8 10% 0.9 50% 1.0 70% 1.0 90% 1.0 0 - 40°C (32 - 104°F) @ constant 50%RH 10/50 1.0 22/72 1.0 40/104 1.0 Storage Life: 2 years in darkness at 3 - 10°C (37 - 50°F). Refrigeration required. Color Change: Purple → Beige Reaction Principle: Prelayer reduces humidity effects 3NH3 + H3PO4 → (NH4)3PO4 Cross-sensitivity: Substance Concentration (ppmv) Apparent Reading* Butylamine 200# 200 200# 260 Diethylamine 250 0 CO 100# 0 H2S 100# 0 SO2 50000 0 CH4 50000 0 CO2 200 0 NO2 100 0 Hexane 100 0 Isobutylene 100 0 Toluene * Data based on Honeywell pumps and tubes used in standard range. # At 50% RH. Other Possible Interferences: Amines and other bases. 30 www.honeywellanalytics.com Ammonia NH3 No. H-10-100-15 Extended Range 12 - 250 2 200 2x1 0.56 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Standard Range 25 - 500 1 100 1 1 Extended Range 50 - 1000 0.5 50 1 2 Precision (Relative Standard Deviation)*: ≤ ± 12% Linearity with No. of Pump Strokes: r2 = 0.998 Humidity: No effect at 10 - 90% RH. At <5% RH multiply the reading by 0.8. Temperature Range: 0 - 40°C (32 - 104°F) @ constant 50%RH. Temp (°C/°F) 0/32 10/50 24/75 40/104 Corr. Factor 1.3 1.0 1.0 1.2 Color Change: Purple → Beige Reaction Principle: Prelayer reduces humidity effects 3NH3 + H3PO4 → (NH4)3PO4 Cross-sensitivity: Substance Concentration (ppmv) Apparent Reading* 300# 100# 250 50000 250 500# 200 25000 1500 200 5000 200 90 0 0 0 0‡ 0 0 0 0 0 Butylamine Diethylamine CO CO2 H2S SO2 NO2 CH4 Hexane Toluene Isobutylene * Data based on Honeywell pumps and tubes used in standard range. # At 50% RH. ‡Reduces reading in mixtures Other Possible Interferences: Amines and other bases. www.honeywellanalytics.com 31 DATA SHEETS Storage Life: 2 years in darkness at 3 - 10°C (37 - 50°F). Refrigeration required. DATA SHEETS Ammonia NH3 No. H-10-100-40 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Extended Range Standard Range Extended Range 0.5 - 7.5% 2 200 2x2 0.5 1 - 15% 1 100 2 1 2 - 30% 0.5 50 1.5 2 Precision (Relative Standard Deviation)*: ≤ ± 10% Linearity with No. of Pump Strokes: r2 = 0.999 Humidity: 85% RH reduces the reading by about 25% compared to dry air Temperature Range: No effect 0 - 40°C (32 - 104°F) Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: Orange → Deep Purple Reaction Principle: 3NH3 + H3PO4 → (NH4)3PO4 Cross-sensitivity: Substance CO CO2 SO2 NO Hexane Isobutylene CH4 Concentration (ppmv) Apparent Reading* 3000 100000 200 100 100 1000 25000 0 0 0 0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. Other Possible Interferences: Amines and other bases 32 www.honeywellanalytics.com Benzene Specific C6H6 No. H-10-101-01 Extended Range 0.25 - 5 6 600 6x3 0.27 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Standard Range 0.5-10 3 300 3x3 1 Extended Range 1.5 - 30 1 100 3 4 Precision (Relative Standard Deviation)*: ≤±12% Humidity: No effect 0 - 95% RH Temperature Range: 0 - 40°C (32 - 104°F) 0/32 2.7 10/50 1.6 25/77 1.0 40/104 0.6 Storage Life: 1 year in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Brown Reaction Principle: Pretube removes interferences 2C6H6 + CH2O → diphenylmethane + H2O diphenylmethane + H2S2O7 → p-quinoid products Cross-sensitivity: Substance Isobutylene n-Hexane n-Heptane Toluene m-Xylene m-Xylene CH4 CO H 2S Concentration (ppmv) Apparent Reading* 100 500# 100 100 50 100 25000 10 25 0 0 0 0 0 5 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. # Hexane above 100 ppm will reduce the benzene response. Other Possible Interferences: Hydrocarbons and similar reducing gases. www.honeywellanalytics.com 33 DATA SHEETS Temp (°C/°F) Corr. Factor DATA SHEETS Benzene Specific C6H6 No. H-10-101-10 Extended Range 2.5 - 20 10 1000 10 x 3 0.5 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Standard Range 5 - 40 5 500 5x3 1 Extended Range 25 - 200 1 100 3 5 Precision (Relative Standard Deviation)*: ≤ ± 12% Humidity: No effect 5 - 100% RH Temperature Range: No effect 0 - 40°C (32 - 104°F) Storage Life: 1 year in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Light Brown Reaction Principle: Pretube removes interferences C6H6 + I2O5 + H2S2O7 → I2 + oxidation products Cross-sensitivity: Substance Isobutylene n-Hexane n-Octane Toluene m-Xylene β-Pinene CO H2S Concentration (ppmv) 100 10 100 35 50 50 10 25 Apparent Reading* ~2 (faint) 0 0 0# 0# ~2 (very faint) 7 0 * Data based on Honeywell pumps and tubes used in standard range. #With 10 strokes, toluene and xylene at 50 ppm read 2 ppm and 100 ppm octane reads ≤2 ppm. Other Data: Without the pretube the readings are 30% higher. 34 www.honeywellanalytics.com Benzene C6H6 No. H-10-101-20 Extended Range 2.5 - 50 2 200 2x2 0.5 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Standard Range 5 - 100 1 100 2 1 Extended Range 10 - 200 0.5 50 1.5 2 Precision (Relative Standard Deviation)*: ≤ ± 12% Linearity with No. of Pump Strokes: r2 = 0.992 Humidity: No effect 5 - 95% RH Temperature Range: Temp (°C/°F) Corr. Factor 0/32 0.8 0 - 40°C (32 - 104°F) 10/50 0.9 21/70 1.0 40/104 1.1 DATA SHEETS Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Light Brown Reaction Principle: C6H6 + I2O5 + H2S2O7 → I2 + oxidation products Cross-sensitivity: Substance CO CO2 H 2S NO NH3 CH4 SO2 Hexane Isobutylene Toluene o-Xylene Concentration (ppmv) 50 50000 50 100 100 25000 10 50 100 100 50 Apparent Reading* 40 0 20 40 0 0 0 >100 10 20 3 * Data based on Honeywell pumps and tubes used in standard range. Other Possible Interferences: Hydrocarbons and similar reducing gases. www.honeywellanalytics.com 35 DATA SHEETS 1,3-Butadiene CH2=CHCH=CH2 No. H-10-135-04 Extended Range 0.25-2.5 4 400 4x2 0.43 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Standard Range 0.5-5 2 200 2x2 1 Extended Range 1-10 1 100 2 2.4 Precision (Relative Standard Deviation)*: ≤ ± 15% Linearity with No. of Pump Strokes: r2 >0.998 Humidity Range: no effect 0 - 90% RH. Temperature Range: 0 - 40°C (32 - 104°F) Temp (°C/°F) 0/32 Corr. Factor 1.5 10/50 20/68 30/86 40/104 1.15 1.0 0.85 0.8 Storage Life: 2 years in darkness below 10°C (50°F). Refrigeration required. Color Change: Pink → White Reaction Principle: CH2=CHCH=CH2 + KMnO2 → Oxidation products Cross-sensitivity: Substance Isobutylene Ethylene Hexane Toluene CH4 CO2 CO H 2S SO2 NO NO2 NH3 HCN Concentration (ppmv) 5 10 100 100 75000 4000 400 30 5 8 10 50 10 Apparent Reading* 4.4 0** 0 0 0 0 0 0 0.5 1.9 0.5 0 0 *Data based on Honeywell and tubes used in standard range. ** The entire tube changes to very light pink, no boundary. Caution: Dispose of spent or expired tubes according to local regulations. Possibly hazardous materials are given under the section Reaction Principle. 36 www.honeywellanalytics.com n-Butane n-C4H10 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-137-30 Extended Range Standard Range Extended Range 12.5– 700 2 200 2 x 2.5 0.5 25 - 1400 1 100 2.5 1 50 - 2800 0.5 50 2 2 Precision (Relative Standard Deviation)*: ≤ ± 20% Linearity with No. of Pump Strokes: r2 >0.999 Humidity: No effect 5 - 100% RH. Temperature Range: No effect 0 - 40°C (32 - 104°F). Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Reaction Principle: C4H10 + K2Cr2O7 + H2SO4 → Cr(III) + Oxidation Products Cross-sensitivity: Substance CH4 Propane Isobutane Isobutylene n-Pentane n-Hexane CO H2S Ethanol Acetone Methyl Ethyl Ketone Concentration (ppmv) Apparent Reading* Correction Factor 25000 500 100 1500 200 1500 500 500 1000 1000 1000 0 ~650 (l.brown)# 20 ~15 80 (green)# 530 (green)# 0 90 ~3 ~9 ~8 ~0.8 ~5 ~100 2.5 2.8 5.6 >300 >100 >100 * Data based on Honeywell pumps and tubes used in standard range. # Propane gives light brown reading with very indistinct endpoint, butane gives moderately sharp endpoint, and pentane and hexane give sharp endpoints. Other Possible Interferences: Other hydrocarbons www.honeywellanalytics.com 37 DATA SHEETS Color Change: Yellow-Orange → Brown (greenish) DATA SHEETS Carbon Dioxide CO2 Extended Range 150 - 2500 2 200 2x2 0.5 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-104-30 Standard Range 300 - 5000 1 100 2 1 Extended Range 600 - 10000 0.5 50 1.5 2.3 Precision (Relative Standard Deviation)*: ≤ ± 10% Linearity with No. of Pump Strokes: r2 = 0.993 Humidity: No effect 5 - 85% RH Temperature Range: 0 - 40°C (32 - 104°F) Temp (°C/°F) Corr. Factor 0/32 0.90 10/50 0.95 21/70 1.0 40/104 0.95 Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Purple Reaction Principle: CO2 + H2NNH2 → H2NNHCO2H (pH indicator change) Cross-sensitivity: Substance CO SO2 SO2 NO NH3 H 2S Hexane Isobutylene Toluene Concentration (ppmv) Apparent Reading* 3000 2050 200 100 50,000 2000 1500 100 400 0 500 ~50 0 0 0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. Other Possible Interferences: Acid gases. Ammonia interferes in mixtures. 38 www.honeywellanalytics.com Carbon Dioxide CO2 Range (%) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-104-40 Extended Range Standard Range Extended Range 0.025 - 0.5% 2 200 2x2 0.5 0.05 - 1% 1 100 2 1 0.1 - 2% 0.5 50 1.5 2.3 Precision (Relative Standard Deviation)*: ≤ ± 10% Linearity with No. of Pump Strokes: r2 = 0.994 Humidity: No effect 5 - 85% RH Temperature Range: 0/32 1.2 10/50 1.1 21/70 1.0 40/104 0.75 DATA SHEETS Temp (°C/°F) Corr. Factor 0 - 40°C (32 - 104°F) Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Purple Reaction Principle: CO2 + H2NNH2 → H2NNHCO2H (pH indicator change) Cross-sensitivity: Substance CO SO2 NO NH3 CH4 H2S Hexane Isobutylene Benzene Toluene Concentration (ppmv) Apparent Reading* 250 10 100 10% 2.5% 0.5% 1200 100 100 400 0 0.1% 0 0 0 0.1% 0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. Other Possible Interferences: Acid gases. Ammonia interferes in mixtures. www.honeywellanalytics.com 39 DATA SHEETS Carbon Dioxide CO2 Extended Range 0.125 - 1.5% 2 200 2x2 0.5 Range (%) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-104-45 Standard Range 0.25 - 3% 1 100 2 1 Extended Range 0.5 - 6% 0.5 50 1.5 2.3 Precision (Relative Standard Deviation)*: ≤ ± 10% Linearity with No. of Pump Strokes: r2 = 0.999 Humidity: No effect 5 - 85% RH Temperature Range: Temp (°C/°F) Corr. Factor 0/32 0.85 0 - 40°C (32 - 104°F) 10/50 0.95 23/73 1.0 40/104 1.05 Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Purple Reaction Principle: CO2 + H2NNH2 → H2NNHCO2H (pH indicator change) Cross-sensitivity: Substance CO SO2 SO2 NO NH3 CH4 H2S Hexane Toluene Concentration (ppmv) Apparent Reading* 1.5% 5% 200 100 5% 2.5% 2000 1500 400 0 2.5% 0 0 0 0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. Other Possible Interferences: Acid gases. Ammonia interferes in mixtures. 40 www.honeywellanalytics.com Carbon Dioxide CO2 Range (%) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-104-50 Extended Range Extended Range Standard Range 0.25 - 5% 2 200 2 x 1.5 0.25 0.5 - 10% 1 100 1.5 0.5 1 - 20% 0.5 50 1 1 Precision (Relative Standard Deviation)*: ≤ ± 10% Linearity with No. of Pump Strokes: r2 ≥ 0.999 Humidity: No effect 5 - 100% RH Temperature Range: No effect 0 - 40°C (32 - 104°F) Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. DATA SHEETS Color Change: White → Purple Reaction Principle: CO2 + H2NNH2 → H2NNHCO2H (pH indicator change) Cross-sensitivity: Substance CO Concentration (ppmv) Apparent Reading* 3000 0 SO2 200 0 NO 100 0 NH3 300 0 CH4 25000 0 100 0 Hexane 1200 0 Isobutylene 100 0 Toluene 100 0 H 2S * Data based on Honeywell pumps and tubes used in standard range. Other Possible Interferences: Acid gases www.honeywellanalytics.com 41 DATA SHEETS Carbon Dioxide CO2 Range (%) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-104-60 Extended Range Extended Range Standard Range 1.25 - 10% 2 200 2 x 1.5 0.33 2.5 - 20% 1 100 1.5 0.6 5 - 40% 0.5 50 1 1 Precision (Relative Standard Deviation)*: ≤ ± 10% Humidity: No effect 5 - 100% RH Temperature Range: No effect 0 - 40°C (32 - 104°F) Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Purple Reaction Principle: CO2 + H2NNH2 → H2NNHCO2H (pH indicator change) Cross-sensitivity: Substance CO SO2 NO NH3 CH4 H 2S Hexane Isobutylene Toluene Concentration (ppmv) Apparent Reading* 40000 4000 100 500 25000 10000 1200 100 100 0 0.5 0 0 0 0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. Other Possible Interferences: Acid gases 42 www.honeywellanalytics.com Carbon Monoxide CO (Selective) Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-102-18 Extended Range Standard Range Extended Range 2.5 - 50 6 600 6x2 0.5 5 - 100 3 300 3x2 1 15 - 300 1 100 2 3.0 Precision (Relative Standard Deviation)*: ≤±15% Linearity with No. of Pump Strokes: r2 =0.999 Humidity: No effect 5 - 100% RH. Temperature Range: No effect between 0 - 40°C (32 - 104°F) Color Change: White → Light Brown Reaction Principle: Prelayer removes most interferences 5CO + I2O5 + H2S2O7 → I2 + CO2 + sulfur products Cross-sensitivity: Substance H2 NO H2S NH3 CH4 Hexane Isobutylene Toluene Trichloroethylene Concentration (ppmv) Apparent Reading* 100% 100 50 300 25000 100 100 100 25 0 0 0 0 0 12 0 0 16** * Data based on Honeywell pumps and tubes used in standard range. **Very light blue. Other Possible Interferences: Other hydrocarbons; most organic vapor interferences are eliminated by the pretreatment layer. www.honeywellanalytics.com 43 DATA SHEETS Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. DATA SHEETS Carbon Monoxide CO No. H-10-102-20 Extended Range Standard Range Extended Range 2.5 - 50 2 200 2x2 0.5 5 - 100 1 100 2 1 10 - 200 0.5 50 1.5 2 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Precision (Relative Standard Deviation)*: ≤±12% Linearity with No. of Pump Strokes: r2 >0.99 Humidity: No effect 5 - 100% RH. Temperature Range: 0 - 40°C (32 - 104°F) Temp (°C/°F) 0/32 10/50 25/77 40/104 Corr. Factor 0.80 0.83 1.0 1.15 Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Light Brown Ring Reaction Principle: 5CO + I2O5 + H2S2O7 → I2 + CO2 + sulfur products Cross-sensitivity: Substance NO H 2S NH3 CH4 Hexane Isobutylene Toluene Trichloroethylene Concentration (ppmv) Apparent Reading* 200 100 0 0 300 25000 100 0 0 0 100 100 25 0 0 20 (v faint) * Data based on Honeywell pumps and tubes used in standard range. Other Possible Interferences: Most hydrocarbon interferences are eliminated in the pretreatment layer. Can be used to measure CO in pure hydrogen. 44 www.honeywellanalytics.com Carbon Monoxide CO Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-102-30 Extended Range Standard Range Extended Range 10-250 2 200 2x2 0.5 20 - 500 1 100 2 1 40 - 1000 0.5 50 1.5 2 Cross-sensitivity: Substance NO H 2S NH3 CH4 Hexane Hexane Isobutylene Toluene Trichloroethylene Concentration (ppmv) Apparent Reading* 200 100 0 0 300 25000 100 400 100 100 25 0 0 0 18 0 0 15** * Data based on Honeywell pumps and tubes used in standard range. ** Very light green. Other Possible Interferences: Hydrocarbons and similar reducing gases. www.honeywellanalytics.com 45 DATA SHEETS Precision (Relative Standard Deviation)*: ≤±15% Linearity with No. of Pump Strokes: r2 = 0.999 Humidity: No effect 5 - 95% RH. Temperature Range: No effect 0 - 40°C (32 - 104°F) Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Light Brown Reaction Principle: Prelayer removes most interferences 5CO + I2O5 + H2S2O7 → I2 + CO2 + sulfur products DATA SHEETS Carbon Monoxide CO Range (%) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-102-45 Extended Range Standard Range Extended Range 0.1 - 2% 2 200 2 x 1.5 0.5 0.2 - 4% 1 100 1.5 1 0.4 - 8% 0.5 50 1 2.0 Precision (Relative Standard Deviation)*: ≤±10% Linearity with No. of Pump Strokes: r2 = 0.999 Humidity: No effect 5 - 100% RH. Temperature Range: No effect 0 - 40°C (32 - 104°F) Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Dark Brown Reaction Principle: 5CO + I2O5 + H2S2O7 → I2 + CO2 + sulfur products Cross-sensitivity: Substance H 2S NH3 CH4 Hexane Hexane Isobutylene Toluene Concentration (ppmv) Apparent Reading* 100 300 25000 600 1200 100 100 0 0 0 0.4% 1.2% 0 0 * Data based on Honeywell pumps and tubes used in standard range. Other Possible Interferences: Hydrocarbons and similar reducing gases. 46 www.honeywellanalytics.com Chlorine Cl2 No. H-10-106-10 Extended Range Standard Range Extended Range 0.25 - 4 2 200 2 x 2.5 0.5 0.5 - 8 1 100 2.5 1 1.0 - 16 0.5 50 2 2 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Precision (Relative Standard Deviation)*: ≤±20% Linearity with No. of Pump Strokes: r2 = 0.99 Humidity: No data Temperature Range: 0 - 40°C (32 - 104°F) Temp (°C/°F) 0/32 10/50 18/70 40/104 Corr. Factor ND ND 1.0 ND Color Change: White → Yellow Reaction Principle: Cl2 + o-Tolidine → Yellow colored product + HCl Cross-sensitivity: Substance ClO2 Concentration (ppmv) Apparent Reading* 1 2 CO2 15000 0 NH3 50000 0# NO2 5 7 CH4 25000 0 H 2S 250 0 Isobutylene 2000 0 * Data based on Honeywell pumps and tubes used in standard range. # Interferes in mixtures . Other Possible Interferences: Other oxidizing gases. www.honeywellanalytics.com 47 DATA SHEETS Storage Life: 1 year in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. DATA SHEETS Chlorine Cl2 No. H-10-106-20 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Extended Range Standard Range Extended Range 2.5 - 50 2 200 2x2 0.5 5 - 100 1 100 2 1 10 - 200 0.5 50 1.5 2 Precision (Relative Standard Deviation)*: ≤±20% Linearity with No. of Pump Strokes: r2 = 0.999 Humidity: No effect 0-90% RH Temperature Range: No effect between 0 - 40°C (32 - 104°F) Storage Life: 1 year in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Orange Reaction Principle: Cl2 + o-Tolidine → Orange colored product + HCl Cross-sensitivity: Substance ClO2 Concentration (ppmv) Apparent Reading* 10 9 CO 250 0 CO2 50000 0 NO 100 5 NH3 100 0 CH4 25000 0 H 2S 10 0 SO2 2000 0 Hexane 100 0 Isobutylene 100 0 Toluene 100 0 * Data based on Honeywell pumps and tubes used in standard range. Other Possible Interferences: Other oxidizing gases. 48 www.honeywellanalytics.com Chlorine Dioxide ClO2 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-130-10 Extended Range Standard Range Extended Range 0.05 - 2 5 500 5x2 0.19 0.25 - 15 1 100 2 1 0.5-30 0.5 50 1 2.1 Precision (Relative Standard Deviation)*: ≤±20% Humidity: No effect 10-90% RH Temperature Range: No effect 0 - 40°C (32 - 104°F) Storage Life: 1 year in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Yellow Cross-sensitivity: Substance Cl2 NO NO2 NH3 CH4 HCl H 2S CO CO2 Isobutylene Concentration (ppmv) Apparent Reading* 10 25 5 50000 10000 1000 2000 500 15000 2000 6 2 11 0 0 0 0 0 0 0 DATA SHEETS Reaction Principle: ClO2 + o-Tolidine → Yellow colored product * Data based on Honeywell pumps and tubes used in standard range. Other Possible Interferences: Bromine www.honeywellanalytics.com 49 DATA SHEETS Diesel & Jet Fuel No. H-10-143-10 Extended Range Standard Range Range (ppmv) Extended Range 0.5 - 25 No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor 4 400 4 x 1.5 1 Do not extend Do not extend Precision (Relative Standard Deviation)*: ≤±20% for undecane Humidity: 0 - 95%RH % RH Corr. Factor <5% 1.0 Temperature Range: Temp (°C/°F) Corr. Factor 30% 0.8 50% 0.7 80% 0.7 95% 0.7 0 - 40°C (32 - 104°F) 0/32 1.9 10/50 1.3 20/68 1.0 40/104 0.8 Storage Life: 1 year in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Brown-green Ring (Over-Range: White → Pale Yellow) Reaction Principle: CnHm + I2O5 + H2S2O7 → I2 + Oxidation Products Continued on next page 50 www.honeywellanalytics.com Diesel & Jet Fuel (continued) No. H-10-143-10 Concentration (ppmv) Apparent Reading* Correction Factor Undecane (C11H24) 25 25 1.0# Diesel, whole (Automotive or Marine) 50 20 2.5 Diesel vapors 10 ~20 ~0.4 JP-5, whole (kerosene) 25 22 1.1 JP-8, whole (kerosene) † 10 11.5 0.87† Gasoline, whole 25 10 2.5 CO2 10000 0 - CO 10 10 1.0 CH4 25000 0 - H 2S 60 0 - Butane 25 0 - Propane 100 0 - Hexane 25 0.5** ~50 Octane 5 10 0.5 Benzene 25 1** ~25 Toluene 25 0.5** ~50 Xylene 25 0.5 ~50 Styrene 20 0.4 ~50 Ethanol 2000 0 - Isopropanol 200 0 - Acetone 50 0 - DATA SHEETS Cross-sensitivity: Substance * Data based on Honeywell pumps and tubes used in standard range. Calibrated to undecane. ** Very faint brown stain. † Can use 1 stroke @ CF =7.2 or 2 strokes @ CF = 2.5. # Other Possible Interferences: No response to 50 ppm HCl, or 100 ppm SO2, NH3, or NO2. www.honeywellanalytics.com 51 Ethanol C2H5OH Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-141-30 Extended Range Standard Range Extended Range 50-200# 2 200 2x3 0.5# 100 - 2000 1 100 3 1 Do not extend # This CF only applies between 50-200 ppm; for higher concentrations use one stroke. Precision (Relative Standard Deviation)*: ≤±20% DATA SHEETS Linearity with No. of Pump Strokes: r2 = 0.87 True concentration (ppm) Humidity: No effect 0-95% RH Temperature Range: 0 - 40°C (32 - 104°F) Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: Orange Yellow → Pale Green Reaction Principle: C2H5OH + Cr(VI) + H2SO4 → Cr(III) + Oxidation Products Continued on next page 52 www.honeywellanalytics.com Ethanol C2H5OH (continued) Cross-sensitivity: Substance Methanol No. H-10-141-30 Concentration (ppmv) Apparent Reading* Correction Factor Isopropanol 1000 1000 1000 750 1.0 1.3 tert-Butanol 1000 1300 0.77 Methyl mercaptan 500 300 1.7 100 0 - CH4 25000 0 - CO2 5000 0 - CO 1000 0 - NH3 400 0 - NO 100 130 0.77 Benzene 100 0 - H2S n-Hexane 100 0 - Ethyl acetate 1000 0** - DATA SHEETS * Data based on Honeywell pumps and tubes used in standard range. ** Faint brown color over entire tube, but no effect on ethanol reading. Other Possible Interferences: Other alcohols and mercaptans. www.honeywellanalytics.com 53 DATA SHEETS Formaldehyde HCHO Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-121-05 Extended Range Standard Range Extended Range Do not extend 0.1 - 5 5 500 5x2 1 0.8 - 40 1 100 2 7.5 Precision (Relative Standard Deviation)*: ≤±20% Linearity with No. of Pump Strokes: r2 > 0.995 Humidity: 0 - 95% RH % RH Corr. Factor <5% 1.0 Temperature Range: 30% 0.85 50% 0.8 80% 0.75 0 - 40°C (32 - 104°F) Temp (°C/°F) 0/32 10/50 20/68 30/86 40/104 Corr. Factor 1.3 1.1 1.0 0.9 0.8 Storage Life: 2 years in darkness at 5 °C (40 - 77°F). Refrigeration preferred. Color Change: Yellow → Reddish brown Reaction Principle: 3HCHO + (NH2OH)3 • H3PO4 → H3PO4 + 3H2C=NOH + 3H2O H3PO4 + Base → Phosphate (dye color change) Cross-sensitivity: Substance Concentration (ppmv) Apparent Reading* Acetaldehyde Propionaldehyde Acetone Methyl ethyl ketone CH4 CO CO2 H 2S SO2 Hexane Toluene Isobutylene Isopropanol Phenol Styrene 3 3 3 3 25000 500 1000 100 100 2000 100 100 2000 25 20 3 3 Entire tube# Entire tube# 0 0 0 0 0 0 0 0.5 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. # Faint brown color over entire stain length. 100 ppm gives stronger color. Note: In dry air the background color may change: read only reddish-brown color. 54 www.honeywellanalytics.com Gasoline CnHm No. H-10-138-30 Extended Range 15 - 500 4 400 4x2 0.45 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Standard Range 30 - 1000 2 200 2x2 1 Extended Range 60 - 2000 1 100 2 2.5 Precision (Relative Standard Deviation)*: ≤±20% Linearity with No. of Pump Strokes: r2 = 0.999 Humidity: No effect 5 - 95% RH. Temperature Range: 0 - 40°C (32 - 104°F) Temp (°C/°F) Corr. Factor 0/32 1.6 10/50 1.24 22/72 1.0 40/104 0.83 Color Change: Orange → Dark Green Reaction Principle: Prelayer removes humidity CnHm + K2Cr2O7 + H2SO4 → Cr3+ + Oxidation Products Cross-sensitivity: Substance CH4 CO H 2S SO2 Acetone Ethanol Butane Isopar L Toluene Benzene Concentration (ppmv) Apparent Reading* 25000 500 100 500 1000 1000 1000 500 200 500 0 0 30 0 20 20 Entire tube 115 80 900 * Data based on Honeywell pumps and tubes used in standard range. Note: The tube is calibrated using heptane as a standard for gasoline. www.honeywellanalytics.com 55 DATA SHEETS Storage Life: 2 years in darkness at 5 - 25°C(40 - 77°F). Refrigeration preferred. DATA SHEETS Total Hydrocarbons HC Extended Range Range (ppmv) 25 - 500 No. of Pump Strokes 4 Sample Volume (mL) 400 Sample Time (min) 4x2 Correction Factor 0.5 Precision (Relative Standard Deviation)*: ≤±20% No. H-10-110-30 Standard Range 50 - 1000 2 200 2x2 1 Extended Range 100-2000 1 100 2 2 Linearity with No. of Pump Strokes: r2 = 0.994 Humidity: No effect 5 - 100% RH Temperature Range: Temp (°C/°F) Corr. Factor 0/32 1.2 0 - 40°C (32 - 104°F) 10/50 1.1 25/77 1.0 40/104 0.85 Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: Yellow-Orange → Green Reaction Principle: HC + Cr(VI) + H2SO4 → Cr(III) + Oxidation Products Cross-sensitivity: Substance Methane Ethylene Propane Isobutane n-Pentane n-Hexane n-Heptane n-Octane n-Decane Benzene Toluene Xylene Isobutylene Acetone Isopropanol Ethyl Acetate H 2S Concentration (ppmv) 25000 100 100 100 500 1200 1000 400 1000 500 1000 1000 1000 10000 1000 1000 1000 Apparent Reading* 0 165 Entire tube faint 100 700 870 525 103 500 Unclear endpoint 110 60 20 60 <20 <20 250 Corr. Factor 0.6 1.0 0.7 1.4 1.9 3.9 2.0 9 17 50 170 >50 >50 4.0 * Data based on Honeywell pumps and tubes used in standard range. Other Possible Interferences: No response to 3000 ppm CO, 300 ppm NH3, or 200 ppm SO2. 56 www.honeywellanalytics.com Hydrogen Chloride HCl Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-108-09 Extended Range Standard Range Extended Range 0.5 - 10 2 200 2x1 0.5 1 - 20 1 100 1 1 2 - 40 0.5 50 0.5 2 Precision (Relative Standard Deviation)*: ≤±20% Linearity with No. of Pump Strokes: r2 = 0.999 Humidity: Must be used @ <5% RH. Reading drops sharply above 5% RH. Temperature Range: No effect between 0 - 40°C (32 - 104°F) at <5%RH. Storage Life: 2 year in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Reaction Principle: HCl + Base → Chloride Salt + H2O (dye color change) Cross-sensitivity: Substance CO CO2 H 2S SO2 NO NO2 NH3 HF Cl2 CH4 Hexane Toluene Concentration (ppmv) 15,000 8,000 800 200 100 200 100 25 10 25,000 2400 400 Apparent Reading* 0 0 0 0 0 20 0 15 0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. Other Possible Interferences: Other acid vapors; amines and other bases. www.honeywellanalytics.com 57 DATA SHEETS Color Change: Yellow → Pink DATA SHEETS Hydrogen Chloride HCl Extended Range No.10-108-10 Standard Range Extended Range 1 - 20 1 100 1 1 2 - 40 0.5 50 0.5 2 Range (ppmv) 0.5 - 10 No. of Pump Strokes 2 Sample Volume (mL) 200 Sample Time (min) 2x1 Correction Factor 0.5 Precision (Relative Standard Deviation)*: ≤±20% Linearity with No. of Pump Strokes: r2 = 0.999 Humidity: Calibrated at 50% RH and 23 °C (73 °F). % Relative Humidity < 5% 30% 50% 70% 90% Correction Factor @ 10 ppmv 0.7 0.8 1.0 1.1 2.7 Temperature Range: No effect between 0 - 40°C (32 - 104°F) at <5% RH. Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: Yellow → Pink Reaction Principle: P retube reduces humidity HCl + NaOH → NaCl + H2O (dye color change) Cross-sensitivity: Substance CO CO2 H 2S SO2 NO NO2 NH3 HF Cl2 CH4 Hexane Toluene Concentration (ppmv) Apparent Reading* 15,000 8,000 800 200 100 200 100 25 10 25,000 2400 400 0 0 0 0 0 20 0^ 15 >20 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. ^Interferes in mixtures Other Possible Interferences: Other acid vapors; amines and other bases. 58 www.honeywellanalytics.com Hydrogen Chloride HCl Extended Range 10-250 2 200 2 x 1.5 0.5 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-108-22 Standard Range 20-500 1 100 1.5 1 Extended Range 40-1000 0.5 50 1.0 2.0 Precision (Relative Standard Deviation)*: ≤±20% Linearity with No. of Pump Strokes: r2 > 0.995 Humidity: No effect 5-95% RH. Temperature Range: No effect 0 - 40°C (32 - 104°F); at -20°C, the response is reduced by about 5%. DATA SHEETS Storage Life: 2 years in darkness at 5 °C (40°F). Refrigeration required. Color Change: Yellow → Red Reaction Principle: HCl + Base → Chloride (dye color change) Cross-sensitivity: Substance CH4 CO CO2 H 2S SO2 NO NO2 NH3 HF Cl2 Hexane Toluene Concentration (ppmv) Apparent Reading* 25000 500 1000 100 1000 200 100 100 100 200 2000 2000 0 0 0 0 0 0 0 0 0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. www.honeywellanalytics.com 59 DATA SHEETS Hydrogen Cyanide HCN Extended Range 1.25 - 30 4 400 4 x 2.5 0.4 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-126-10 Standard Range 2.5 - 60 2 200 2 x 2.5 1 Extended Range 5 - 120 1 100 2.5 2 Precision (Relative Standard Deviation)*: ≤±20% Linearity with No. of Pump Strokes: r2 >0.999 Humidity: 5% - 95%RH % Relative Humidity Correction Factor @ 10 ppmv < 5% 1.0 10% 1.0 50% 1.2 95% 1.4 Temperature Range: No effect 0 - 40°C (32 - 104°F) Storage Life: 1 year in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: Yellow → Red (ignore light orange color formed in clean air) Reaction Principle: 2HCN + HgCl2 → Hg(CN)2 + 2HCl HCl + Base → Chloride Salt + H2O (dye color change) Cross-sensitivity: Substance H2 CH4 CO H 2S HCl SO2 NH3 CO2 Concentration (ppmv) 2000 25000 300 100 100 20 50 5000 Apparent Reading* 0 0 0 <1# <1# 20# 0 0 * Data based on Honeywell pumps and tubes used in standard range. # Measured in dry gas; at >20% RH, no response is observed by these gases. Note: A light orange color may form when drawing in air with no HCN present. This color can be ignored and does not affect true HCN readings, which form a bright pinkish-red color. The color boundary is sharp in ambient, humid air and somewhat diffuse in very dry air. 60 www.honeywellanalytics.com Hydrogen Fluoride HF Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-105-10 Extended Range Standard Range Extended Range 0.25 - 10 8 800 8 x 0.5 0.4 0.5 - 20 4 400 4 x 0.5 1 1 - 40 2 200 2 x 0.5 1.6 Precision (Relative Standard Deviation)*: ≤±20% Linearity with No. of Pump Strokes: r2 = 0.98 Humidity: Calibrated at 50% RH and 23°C (73°F). % Relative Humidity Correction Factor 30% 0.3 40% 0.4 50% 1.0 60% 1.3 70% 1.6 80% 2.0 90% 2.6 Temperature Range: No effect 10 - 30°C (50 - 86°F) at constant 41% RH. DATA SHEETS Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration Preferred. Color Change: Beige → Purple Reaction Principle: HF + NaOH → NaF + H2O Cross-sensitivity: Substance CO CO2 NH3 NO H 2S SO2 CH4 HCl Cl2 Concentration (ppmv) Apparent Reading* 250 50000 300 100 800 200 25000 4 15 0 0 0^ 0 0 0 0 entire tube# entire tube# * Data based on Honeywell pumps and tubes used in standard range. Pink color over entire tube length. ^ May interfere in mixtures. # Other Possible Interferences: Other acid vapors; amines and other bases. No effect of 100 ppm toluene or 2400 ppm hexane. www.honeywellanalytics.com 61 DATA SHEETS Hydrogen Sulfide H2S Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Extended Range 0.1 - 1.5 2 200 2 x 1.5 0.5 No. H-10-103-04 Standard Range 0.2 - 3 1 100 1.5 1 Extended Range 0.4 - 6 0.5 50 1 2 Precision (Relative Standard Deviation)*: ≤±12% Linearity with No. of Pump Strokes: r2 = 0.999 Humidity: Tubes must be used @ <5% RH. Reading drops sharply above 5% RH. Temperature Range: No effect between 0 - 40°C (32 - 104°F). Storage Life: 1 year in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: Pale orange → Pink Reaction Principle: H2S + HgCl2 → Mercury sulfide product + HCl HCl + Base → Chloride Salt + H2O (dye color change) Cross-sensitivity: Substance Methyl mercaptan Butyl mercaptan NH3 NO2 SO2 CS2 CO Hexane Isobutylene Toluene Concentration (ppmv) Apparent Reading* 2 2 100 5 100 100 250 100 100 100 0.4 0.3 0 0 0 0 0 0 0^ 0 * Data based on Honeywell pumps and tubes used in standard range. ^ Reduces response when mixed with H2S. Other Possible Interferences: HCl and other acids and bases. 62 www.honeywellanalytics.com Hydrogen Sulfide H2S Extended Range 0.1 - 1.5 2 200 2x2 0.5 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-103-05 Standard Range 0.2 - 3 1 100 2 1 Extended Range 0.4 - 6 0.5 50 1 2 Precision (Relative Standard Deviation)*: ≤±12% Linearity with No. of Pump Strokes: r2 = 0.999 Humidity: No effect between 5 - 90% RH. Temperature Range: No effect between 0 - 40°C (32 - 104°F). Color Change: Pale orange → Pink Reaction Principle: Pretube eliminates humidity H2S + HgCl2 → Mercury sulfide product + HCl HCl + Base → Cross-sensitivity: Substance Methyl mercaptan Butyl mercaptan NH3 NO2 SO2 CS2 CO Hexane Isobutylene Toluene Chloride Salt + H2O (dye color change) Concentration (ppmv) 3 3 100 5 100 100 250 100 100 100 Apparent Reading* 0# 0# 0 0 0 0 0 0 0^ 0 * Data based on Honeywell pumps and tubes used in standard range. # Interferes at higher concentrations. ^ Reduces response when mixed with H2S. Other Possible Interferences: Acids and bases. www.honeywellanalytics.com 63 DATA SHEETS Storage Life: 1 year in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. DATA SHEETS Hydrogen Sulfide H2S Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Extended Range 0.25 – 1.75 2 200 2 x 1.5 0.25 No. H-10-103-06 Extended Range 0.5 – 3.5 1 100 1.5 0.5 Standard Range 1-7 0.5 50 1 1 Precision (Relative Standard Deviation)*: ≤±12% Humidity: Tubes must be used @ <5% RH. Reading drops sharply above 5% RH. Temperature Range: No effect between 0 - 40°C (32 - 104°F). Storage Life: 1 year in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: Pale orange → Pink Reaction Principle: H2S + HgCl2 → Mercury sulfide product + HCl HCl + Base → Chloride Salt + H2O (dye color change) Cross-sensitivity: Substance Methyl mercaptan Butyl mercaptan NH3 NO2 SO2 SO2 CS2 CO Hexane Isobutylene Toluene Concentration (ppmv) Apparent Reading* 2 2 100 5 100 2000 100 250 100 100 100 0.2 0.15 0 0 0 0# 0 0 0 0^ 0 * Data based on Honeywell pumps and tubes used in standard range. # Forms orange color over entire tube but pink H S reading is unaffected in mixtures. 2 ^ Reduces response when mixed with H2S. Other Possible Interferences: HCl and other acids and bases. 64 www.honeywellanalytics.com Hydrogen Sulfide H2S Extended Range 1.25 - 30 2 200 2 x 1.5 0.5 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-103-10 Standard Range 2.5 - 60 1 100 1.5 1 Extended Range 5 - 120 0.5 50 1 2 Precision (Relative Standard Deviation)*: ≤±12% Linearity with No. of Pump Strokes: r2 = 0.998 Humidity: No effect 5 - 85% RH Temperature Range: 0 - 40°C (32 - 104°F) Temp (°C/°F) Corr. Factor 0/32 0.95 10/50 0.95 25/77 1.0 40/104 1.2 Cross-sensitivity: Substance H2 CO CH4 NH3 NO2 SO2 SO2 CS2 Methyl mercaptan Diethyl sulfide Hexane Isobutylene Toluene Concentration (ppmv) Apparent Reading* 100% 250 25000 300 200 20 1800 100 100 100 100 100 100 0^ 0 0 0 0‡ 0 0† 0 0# 0 0 0^ 0 DATA SHEETS Storage Life: 1 year in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Light Brown Reaction Principle: H2S + Pb(OAc)2 → PbS + 2HOAc * Data based on Honeywell pumps and tubes used in standard range. ^ No effect in mixtures. ‡ Interferes in mixtures; may result in transient light brown H2S response. † Interferes in mixtures; high SO2 concentrations suppress H2S response. # Concentrations in the high % range leave a yellow color over the entire tube. www.honeywellanalytics.com 65 DATA SHEETS Hydrogen Sulfide H2S Extended Range 0 - 75 2 200 2 x 1.5 0.5 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-103-12 Standard Range 0 - 150 1 100 1.5 1 Extended Range 0 - 300 0.5 50 1 2 Precision (Relative Standard Deviation)*: ≤±12% Linearity with No. of Pump Strokes: r2 = 0.999 Humidity: No effect 5 - 85% RH Temperature Range: 0 - 40°C (32 - 104°F) Temp (°C/°F) Corr. Factor 0/32 0.88 10/50 0.96 24/75 1.0 40/104 1.1 Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Brown Reaction Principle: H2S + Pb(OAc)2 → PbS + 2HOAc Cross-sensitivity: Substance CO CH4 NH3 NO2 CS2 Methyl mercaptan Diethyl sulfide Isobutylene Toluene Concentration (ppmv) Apparent Reading* 250 25000 100 200 100 1000 100 100 100 0 0 0 0‡ 0 0# 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. ‡ Interferes in mixtures; may result in transient light brown H2S response. # No effect in mixtures. Concentrations in the high % range leave a yellow color over the entire tube. 66 www.honeywellanalytics.com Hydrogen Sulfide H2S Extended Range 5 - 60 2 200 2 x 1.5 0.5 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-103-15 Standard Range 10 - 120 1 100 1.5 1 Extended Range 20 - 240 0.5 50 1 2 Precision (Relative Standard Deviation)*: ≤±12% Linearity with No. of Pump Strokes: r2 = 0.999 Humidity: No effect 5 - 85% RH Temperature Range: Temp (°C/°F) Corr. Factor 0/32 0.88 0 - 40°C (32 - 104°F) 10/50 0.96 24/75 1.0 40/104 1.1 Color Change: White → Brown Reaction Principle: H2S + Pb(OAc)2 → PbS + 2HOAc Cross-sensitivity: Substance CO CH4 NH3 NO2 CS2 Methyl mercaptan Diethyl sulfide Isobutylene Toluene Concentration (ppmv) Apparent Reading* 250 25000 100 200 100 1000 100 100 100 0 0 0 0‡ 0 0# 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. ‡ Interferes in mixtures; may result in transient light brown H2S response. # No effect in mixtures. Concentrations in the high % range leave a yellow color over the entire tube. www.honeywellanalytics.com 67 DATA SHEETS Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. DATA SHEETS Hydrogen Sulfide H2S Extended Range 12.5 - 125 2 200 2x1 0.5 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-103-18 Standard Range 25 - 250 1 100 1 1 Extended Range 50 - 500 0.5 50 1 2 Precision (Relative Standard Deviation)*: ≤±12% Linearity with No. of Pump Strokes: r2 = 0.999 Humidity: No effect 5 - 85% RH Temperature Range: Temp (°C/°F) Corr. Factor 0/32 0.9 0 - 40°C (32 - 104°F) 10/50 0.9 23/73 1.0 40/104 1.1 Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Brown Reaction Principle: H2S + Pb(OAc)2 → PbS + 2HOAc Cross-sensitivity: Substance CO CH4 NH3 NO2 CS2 Methyl mercaptan Diethyl sulfide Isobutylene Toluene Concentration (ppmv) Apparent Reading* 250 25000 100 200 100 500 100 100 100 0 0 0 0‡ 0 0# 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. ‡ Interferes in mixtures; may result in transient brown H2S response. # Concentrations in the high % range leave a yellow color over the entire tube. 68 www.honeywellanalytics.com Hydrogen Sulfide H2S Extended Range 25 - 400 2 200 2x2 0.5 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-103-20 Standard Range 50 - 800 1 100 2 1 Extended Range 100 - 1600 0.5 50 1.5 2 Precision (Relative Standard Deviation)*: ≤±10% Linearity with No. of Pump Strokes: r2 = 0.989 Humidity: 80% RH reduces the reading by about 10% compared to dry air Temperature Range: Temp (°C/°F) Corr. Factor 0/32 1.0 0 - 40°C (32 - 104°F) 10/50 1.0 25/77 1.0 40/104 1.2 Cross-sensitivity: Substance CO CH4 NH3 NO2 SO2 CS2 Methyl mercaptan Diethyl sulfide Hexane Isobutylene Toluene Concentration (ppmv) Apparent Reading* 250 25000 300 200 20 100 500 1000 100 100 100 0 0 0 0‡ 0 0 <50 0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. ‡ Interferes in mixtures; may result in transient brown H2S response. www.honeywellanalytics.com 69 DATA SHEETS Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Dark Brown Reaction Principle: H2S + Pb(OAc)2 → PbS + 2HOAc DATA SHEETS Hydrogen Sulfide H2S Extended Range 50 - 1000 2 200 2x2 0.5 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-103-30 Standard Range 100 - 2000 1 100 2 1 Extended Range 200 - 4000 0.5 50 1.5 2 Precision (Relative Standard Deviation)*: ≤±10% Linearity with No. of Pump Strokes: r2 = 0.999 Humidity: No effect 5 - 85% RH Temperature Range: 0 - 40°C (32 - 104°F) Temp (°C/°F) Corr. Factor 0/32 0.88 10/50 0.93 25/77 1.0 40/104 1.2 Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Black Reaction Principle: H2S + Pb(OAc)2 → PbS + 2HOAc Cross-sensitivity: Substance CO CH4 NH3 NO2 SO2 CS2 Hexane Isobutylene Toluene Concentration (ppmv) Apparent Reading* 250 25000 300 200 20 100 100 100 100 0 0 0 0‡ 0 0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. ‡ Interferes in mixtures; may result in transient brown H2S response. Other Possible Interferences: No response to mercaptans and sulfides. 70 www.honeywellanalytics.com Hydrogen Sulfide H2S Extended Range 0.05 - 1% 2 200 2x2 0.5 Range (%) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-103-40 Standard Range 0.1 - 2% 1 100 2 1 Extended Range 0.2 - 4% 0.5 50 1.5 2 Precision (Relative Standard Deviation)*: ≤±10% Linearity with No. of Pump Strokes: r2 = 0.998 Humidity: No effect 5 - 85% RH Temperature Range: Temp (°C/°F) Corr. Factor 0/32 1.2 0 - 40°C (32 - 104°F) 18/64 1.1 25/77 1.0 40/104 1.0 Color Change: Light Blue → Black Reaction Principle: H2S + CuSO4 → CuS + H2SO4 Cross-sensitivity: Substance CO CH4 NO NO2 NH3 SO2 Methyl mercaptan Diethyl sulfide Isobutylene Toluene Hexane Concentration (ppmv) Apparent Reading* 3000 25000 100 200 300 20 0.1% 1000 100 100 1200 0 0 0 0 0 0 0.1%# 0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. # Concentrations in the high % range leave a yellow color over the entire tube. Other Possible Interferences: High Concentrations of ammonia; NO2 in mixtures. No response to CS2. www.honeywellanalytics.com 71 DATA SHEETS Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. DATA SHEETS Hydrogen Sulfide H2S No. H-10-103-50 Extended Range 0.5 - 10% 2 200 2 x 1.5 0.25 Range (%) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Extended Range 1 - 20% 1 100 1.5 0.5 Standard Range 2 - 40% 0.5 50 1.5 1 Precision (Relative Standard Deviation)*: ≤±10% Linearity with No. of Pump Strokes: r2 = 0.999 Humidity: No effect 5 - 85% RH Temperature Range: Temp (°C/°F) Corr. Factor 0/32 0.75 0 - 40°C (32 - 104°F) 10/50 1.0 18/64 1.0 40/104 1.0 Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: Light Blue → Black Reaction Principle: H2S + CuSO4 → CuS + H2SO4 Cross-sensitivity: Substance CO CO2 NO NH3 CH4 SO2 Isobutylene Hexane Benzene Toluene Concentration (ppmv) Apparent Reading* 250 5% 100 10% 2.5% 10 100 100 100 100 0 0 0 3.5% (blue) 0 0 0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. Other Possible Interferences: Mercaptans. No response to sulfides. Note: Time measurement to exactly 2 minutes for best accuracy. 72 www.honeywellanalytics.com Mercaptans RSH Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-129-20 Extended Range Standard Range Extended Range 2.5 - 60 2 200 2 x 2.0 0.5 5 - 120 1 100 2.0 1 10 - 240 0.5 50 1.0 2.1 Precision (Relative Standard Deviation)*: ≤±20% Linearity with No. of Pump Strokes: r2 = 0.999 Humidity: No effect between 5 - 90% RH. Temperature Range: No effect between 0 - 40°C (32 - 104°F) Storage Life: 1 year in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Reaction Principle: Cross-sensitivity: Substance H 2S CO Diethyl sulfide Ethyl mercaptan Propyl mercaptan Butyl mercaptan Acetylene Ethylene DATA SHEETS Color Change: White → Yellow 2RSH + PdSO4 → (RS)2Pd + H2SO4 Concentration (ppmv) Apparent Reading* 500 500 5000 60 60 60 2000 2000 01 02 303 60 60 29 04 05 Corr. Factor 1.0 1.0 2.0 - * Data based on Honeywell pumps and tubes used in standard range. 1 Up to 500 ppm H2S is trapped in the pretreatment layer. 2 Gray through the entire tube, will not affect RSH reading in mixtures. 3 Interferes in mixtures; may result in high response. 4 Pale brown through the entire tube, will not affect RSH reading in mixtures. 5 Light peach through the entire tube, will not affect RSH reading in mixtures. www.honeywellanalytics.com 73 DATA SHEETS Methyl Bromide CH3Br No. H-10-131-10 Extended Range Standard Range Extended Range 0.5-9 4 400 4x3 0.48 1-18 2 200 2x3 1.0 2-36 1 100 3 2.1 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Precision (Relative Standard Deviation)*: ≤±20% Linearity with No. of Pump Strokes: r2 = 0.997 Humidity: No effect 5 - 100% RH Temperature Range: 0 - 40°C (32 - 104°F) Temp (°C/°F) Corr. Factor 0/32 1.5 10/40 1.3 25/77 1.0 40/104 0.95 Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Orange Reaction Principle: Pre-tube : CH3Br + K2Cr2O7 + H2SO4 → Br2 + Other Prods Measurement Tube: Br2 + indicator dye → Orange product Cross-sensitivity: Substance Tetrachloroethylene Trichloroethylene Vinylidene Chloride Vinyl Chloride 3-Chloro-2-Methylpropene 1,2-Dichloroethane 1,1,1- Trichloroethane Cl2 NO NO2 CH4 CO CO2 Concentration (ppmv) 200 100 200 200 200 200 50 10 500 570 25000 500 5000 Apparent Reading* 13 4 47 5 4 0 4.5 21 0.6 1.0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. Other Possible Interferences: No response to 500 ppm propane, 100 ppm isobutylene or 1200 ppm hexane. 74 www.honeywellanalytics.com Methyl Bromide CH3Br No. H-10-131-30 Extended Range Standard Range Extended Range 10-150 2 200 2x2 0.43 20-300 1 100 2 1 40-600 0.5 50 2 x 0.5 2.2 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Precision (Relative Standard Deviation)*: ≤ ± 15% Linearity with No. of Pump Strokes: 0.999 Humidity: No effect 0 - 90% RH Temperature Range: 0 - 40°C (32 - 104°F) 0/32 1.7 10/50 1.3 20/68 1.0 30/86 0.8 40/104 0.7 Storage Life: 2 years in darkness at <10°C. Refrigeration preferred. Color Change: White → Orange-yellow Reaction Principle: Pretube: 2CH3Br + I2O5 + H2S2O7 → Br2 Measurement Tube: Br2 + o-Tolidine → Orange-yellow product Cross-sensitivity: Substance 1,2-Dibromoethane 1,3-Dibromopropane 1,1,1-Trichloroethane Trichloroethylene Cl2 Ethanol Ethyl acetate Acetone CH4 CO2 CO H 2S SO2 NO NO2 Concentration (ppmv) 300 600 300 80 80 10000 10000 10000 25000 5000 500 500 100 460 110 Apparent Reading* 600 700 30 15 63 0 0 0 0 0 0 0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. www.honeywellanalytics.com 75 DATA SHEETS Temp (°C/°F) Corr. Factor DATA SHEETS Methyl Ethyl Ketone C4H8O No. H-10-113-20 Extended Range 0.01 - 0.3% 6 600 6x2 0.5 Range (%) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Standard Range 0.02 - 0.6% 3 300 3x2 1 Extended Range 0.06 - 1.8% 1 100 2 3 Precision (Relative Standard Deviation)*: ≤±12% Linearity with No. of Pump Strokes: r2 = 0.996 Humidity: 85% RH increases the response by 15% compared to dry gas. Temperature Range: Temp (°C/°F) Corr. Factor 0/32 1.4 0 - 40°C (32 - 104°F) 10/50 1.3 25/77 1.0 40/104 0.7 Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: Orange → Black Reaction Principle: CH3COCH2CH3 + Cr(VI) + H2SO4 → Cr(III) + Oxidation Prods. Cross-sensitivity: Substance Concentration (ppmv) Apparent Reading* Corr. Factor Acetone 0.4% 0.5% 0.8 Methyl propyl ketone 1.0% 0.7% 1.4 Methyl isobutyl ketone CO CO2 1.0% 1.5% 1.5% 0.49% 0 0 2.0 - CH4 2.5% 0 - NH3 5.0% >0.3% brown - H2 S 250 0.2% diffuse# - Ethyl Acetate 1.0% >0.3% diffuse# - Hexane 0.24% entire tube# - Isobutylene 0.20% 0.5% 0.4 400 0.3% diffuse# - Toluene * Data based on Honeywell pumps and tubes used in standard range. # Faint black color. Ketones can be distinguished by their darker stains and sharp endpoints. Other Possible Interferences: Other hydrocarbons. 76 www.honeywellanalytics.com Nitric Acid HNO3 No. H-10-146-20 Extended Range 0.5-10 2 200 2x1 0.46 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Standard Range 1-20 1 100 1 1 Extended Range 2-40 0.5 50 0.5 2.1 Precision (Relative Standard Deviation)*: ≤ ± 20% Linearity with No. of Pump Strokes: r2 = 0.98 Humidity Range: 0 - 90% RH. Calibrated at 50% RH and 20°C (68°F) % Relative Humidity Correction Factor 0% 0.7 30% 0.8 50% 1.0 70% 1.3 80% 1.8 90% 1.9 Temperature Range: 0 - 40°C (32 - 104°F) 0/32 1.3 10/50 1.2 20/68 1.0 30/86 0.9 40/104 0.8 DATA SHEETS Temp(°C/°F) Corr. Factor Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: Yellow → Purple Reaction Principle: CH3HNO3 + Base → Dye color change Cross-sensitivity: Substance Concentration (ppmv) Apparent Reading* HCl 10 14 Cl2 5 13 HF 10 7 saturated ≤2 (v. pale) CO 250 0 CO2 50000 0 CH4 25000 0 NO 100 0 NO2 60 0 H 2S 60 0 SO2 200 0 HCN 60 0 Acetic Acid * Data based on Honeywell pumps and tubes used in standard range. Other Possible Interferences: Other acids may give a positive response and bases may give a negative response in mixtures. Headspace from 85% H3PO4 and H2SO4 give ≤1 ppm response because of their low volatility. www.honeywellanalytics.com 77 DATA SHEETS Nitrogen Dioxide NO2 Extended Range Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Do Not Extend No. H-10-117-10 Standard Range 0.5-30 1 100 1.5 1 Extended Range Do Not Extend Precision (Relative Standard Deviation)*: ≤±20% Linearity with No. of Pump Strokes: Non-linear, do not extend Humidity: No effect between 0-90%RH. Temperature Range: No effect between 0 - 40°C (32 - 104°F) Storage Life: 1 year in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Yellow Reaction Principle: NO2 + o-Tolidine → Nitrated yellow product Cross-sensitivity: Substance CO CO2 SO2 CH4 H 2S Acetone Benzene n-Hexane Isobutylene Toluene Cl2 NO Concentration (ppmv) Apparent Reading* 3000 200000 200 25000 100 10000 5 100 100 100 50 500 0 0 0 0 0 0 0 0 0 0 Entire tube˄ 1# * Data based on Honeywell pumps and tubes used in standard range. ˄ Cl2 results in light yellow stain. # NO results in orange stain. Other Possible Interferences: Reducing gases. 78 www.honeywellanalytics.com Nitrogen Oxides NOX No. H-10-109-20 (Separate Quantification) Extended Range Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor 0.5 - 25 2 200 2x3 0.5 Extended Range Standard Range 1-50 1 100 3 1 2-100 0.5 50 2.5 2 Precision (Relative Standard Deviation)*: ≤±20% Linearity with No. of Pump Strokes: r2 = 0.997 Humidity: 100% RH reduces the response by about 20% vs. dry air Temperature Range: 0/32 1.8 10/50 1.6 25/77 1.0 40/104 1.0 DATA SHEETS Temp (°C/°F) Corr. Factor 0 - 40°C (32 - 104°F) Storage Life: 1 year in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Yellow Reaction Principle: NO + CrO3 + H2SO4 → NO2 Pre-tube NO2 + o-Tolidine → Nitrated yellow product Cross-sensitivity: Substance CO CO2 SO2 CH4 H 2S Acetone Meas. tube Concentration (ppmv) Apparent Reading* 3000 10% 200 25000 100 10000 0 0 0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. Other Possible Interferences: Reducing gases. No response to 5 ppm benzene. No response to 1200 ppm hexane, 100 ppm isobutylene, or 100 ppm toluene. Separate Quantification: Sampling without the pre-tube gives NO2 only. Using the pre-tube gives the sum of NO + NO2. NO can be obtained by difference. www.honeywellanalytics.com 79 DATA SHEETS Ozone O3 No. H-10-133-03 Extended Range Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Do not extend Standard Range 0.05 – 0.6 5 500 5x2 1 Extended Range 0.15 – 1.8 1 100 2 3 Precision (Relative Standard Deviation)*: ≤±20% Linearity with No. of Pump Strokes: r2 = 0.990 Humidity: Calibration is based on approximately 50% relative humidity. Temperature Range: Temp (°C/°F) Corr. Factor 0/32 0.74 0 - 40°C (32 - 104°F) 10/50 1.0 20/68 1.0 40/104 1.1 Storage Life: 1 year in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: Blue → White Reaction Principle: 2O3 + C16H10N2O2 → 2C8H5NO2 + 2O2 Cross-sensitivity: Substance Cl2 Cl2 ClO2 CO CO2 CH4 SO2 H 2S NO NO2 Isobutylene Concentration (ppmv) Apparent Reading* <10 ≥10 1 100 10,000 70,000 100 120 5 1 100 0 ~0.1# entire tube# 0 0 0 0 0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. # Slight discoloration and unclear demarcation. Other Possible Interferences: Bromine and other oxidants. 80 www.honeywellanalytics.com Phenol C6H5OH Extended Range 0.5 - 11 4 400 4 x 1.5 0.45 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-139-05 Extended Range 2.4 - 60 1 100 1.5 2.4 Standard Range 1 - 25 2 200 2 x 1.5 1 Extended Range 7 - 180 0.5 50 1.0 7.2 Precision (Relative Standard Deviation)*: ≤±20% Linearity with No. of Pump Strokes: r2 = 0.996 Humidity: % Relative Humidity Correction Factor 10% 30% 50% 90% 1.0 1.25 1.6 1.8 DATA SHEETS True concentration (ppm) Temperature Range: 10 - 40°C (50 - 104°F) Storage Life: 1.5 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: Pale Yellow → Gray Reaction Principle: C6H5OH + Ce(NH4)2(NO3)6 → Cerium-Phenol complex Continued on next page www.honeywellanalytics.com 81 DATA SHEETS Phenol C6H5OH (continued) Cross-sensitivity: Substance No. H-10-139-05 Concentration (ppmv) Apparent Reading* H 2S 100 0 NH3 500 0 NO 400 0 NO2 400 0 SO2 200 0 CH4 25000 0 CO2 5000 0 CO 500 0 Formaldehyde (HCHO) 500 0 Acetone 2000 0 Isopropanol 2000 0 Isobutylene 100 0 n-Hexane 2000 0 Benzene 2000 0 Toluene 2000 0 Styrene 2000 0 * Data based on Honeywell pumps and tubes used in standard range. 82 www.honeywellanalytics.com Phosphine PH3 No. H-10-116-10 Extended Range Standard Range Extended Range 2.5 - 25 4 400 4 x 1.5 0.5 5 - 50 2 200 2 x 1.5 1 10 - 100 1 100 1.5 1.7 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Precision (Relative Standard Deviation)*: ≤±12% Linearity with No. of Pump Strokes: r2 = 0.997 Humidity: No effect 5 - 90% RH. Temperature Range: Temp (°C/°F) Corr. Factor 0/32 0.85 0 - 40°C (32 - 104°F) 10/50 0.90 25/77 1.0 40/104 1.0 Cross-sensitivity: Substance H 2S SO2 NO NH3 CO CO2 CH4 Hexane Toluene Concentration (ppmv) Apparent Reading* 50 200 100 100 100 50000 25000 1500 100 28 (l. brown) 0 0 0 0 0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. Other Possible Interferences: Strongly reducing gases. www.honeywellanalytics.com 83 DATA SHEETS Storage Life: 1 year in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Yellow Reaction Principle: 2PH3 + 6HgCl2 + 3H2O → Hg3P2•3HgCl2•3H2O + 6HCl DATA SHEETS Phosphine PH3 No. H-10-116-20 Extended Range 12.5 - 250 2 200 2 x 1.5 0.5 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Standard Range 25 - 500 1 100 1.5 1 Extended Range 50 - 1000 0.5 50 1 2 Precision (Relative Standard Deviation)*: ≤±12% Linearity with No. of Pump Strokes: r2 = 0.99 Humidity: No effect 5 - 80% RH. Temperature Range: Temp (°C/°F) Corr. Factor 0/32 0.85 0 - 40°C (32 - 104°F) 10/50 0.95 24/75 1.0 40/104 1.15 Storage Life: 1 year in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Yellow Reaction Principle: 2PH3 + 6HgCl2 + 3H2O → Hg3P2•3HgCl2•3H2O + 6HCl Cross-sensitivity: Substance H 2S SO2 NO NH3 CO CO2 CH4 Hexane Toluene Concentration (ppmv) Apparent Reading* 50 200 100 100 250 50000 25000 1500 100 35 (brown) 0 0 0 0 0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. Other Possible Interferences: Strongly reducing gases. 84 www.honeywellanalytics.com Phosphine PH3 No. H-10-116-25 Extended Range 25 - 500 2 200 2 x 1.5 0.5 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Standard Range 50 - 1000 1 100 1.5 1 Extended Range 100 - 2000 0.5 50 1 2 Precision (Relative Standard Deviation)*: ≤±10% Linearity with No. of Pump Strokes: r2 = 1.000 Humidity: No effect 5 - 80% RH. Temperature Range: No effect between 0-40°C (32 - 104°F) DATA SHEETS Storage Life: 1 year in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Yellow Reaction Principle: 2PH3 + 6HgCl2 + 3H2O → Hg3P2•3HgCl2•3H2O + 6HCl Cross-sensitivity: Substance H 2S SO2 NO NH3 CO CO2 CH4 Hexane Toluene Concentration (ppmv) Apparent Reading* 200 3940 100 100 250 50000 25000 1500 100 140 ‡ 0 0 0 0 0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. ‡ Interferes in mixtures; may result in transient light brown H2S response. Other Possible Interferences: Strongly reducing gases. www.honeywellanalytics.com 85 DATA SHEETS Sulfur Dioxide SO2 No. H-10-107-15 Extended Range Standard Range Extended Range 1 - 15 4 400 4x2 0.5 2 - 30 2 200 2x2 1 4 - 60 1 100 2 2 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Precision (Relative Standard Deviation)*: ≤±12% Linearity with No. of Pump Strokes: r2 = 0.991 Humidity: No effect 5 - 90% RH. Temperature Range: 0 - 40°C (32 - 104°F) Temp (°C/°F) 0/32 10/50 24/75 40/104 Corr. Factor 1.1 1.1 1.0 1.1 Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: Blue-green → Yellow Reaction Principle: SO2 + 2NaOH → Na2SO3 + H2O (pH indicator change) Cross-sensitivity: Substance CO CO2 NO NH3 H 2S PH3 HF CH4 Hexane Toluene Concentration (ppmv) Apparent Reading* 15000 50000 100 100 2000 30 50 25000 1500 400 0 0 0 2 (blue)# 3 (blue) 0 0.5 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. # Reduces reading in mixture. Other Possible Interferences: Acid gases. 86 www.honeywellanalytics.com Sulfur Dioxide SO2 No. H-10-107-20 Extended Range Standard Range Extended Range 2.5 - 50 2 200 2x2 0.5 5 - 100 1 100 2 1 10 - 200 0.5 50 1.5 2 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Precision (Relative Standard Deviation)*: ≤±12% Linearity with No. of Pump Strokes: r2 = 0.999 Humidity: No effect 5 - 50% RH; 100% RH reduces the response by about 25% Temperature Range: 0 - 40°C (32 - 104°F) Temp (°C/°F) 0/32 10/50 25/77 40/104 Corr. Factor 1.2 1.0 1.0 1.0 Color Change: Blue → Yellow Reaction Principle: SO2 + 2NaOH → Na2SO3 + H2O (pH indicator change) Cross-sensitivity: Substance CO CO2 NO NH3 CH4 H 2S Isobutylene Hexane Toluene Acetone Concentration (ppmv) Apparent Reading* 3000 10% 100 300 25000 100 100 1200 100 10000 0 0 0 0# 0 0 0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. # Reduces reading in mixture. Other Possible Interferences: Acid gases. www.honeywellanalytics.com 87 DATA SHEETS Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. DATA SHEETS Sulfur Dioxide SO2 No. H-10-107-25 Extended Range 50 - 900 2 200 2x2 0.5 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Standard Range 100 - 1800 1 100 2 1 Extended Range 200 - 3600 0.5 50 1.5 2 Precision (Relative Standard Deviation)*: ≤±10% Linearity with No. of Pump Strokes: r2 = 0.999 Humidity: No effect 5 - 85% RH. Temperature Range: Temp (°C/°F) Corr. Factor 0/32 1.1 0 - 40°C (32 - 104°F) 10/50 1.0 25/77 1.0 40/104 1.0 Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: Blue → Yellow Reaction Principle: SO2 + 2NaOH → Na2SO3 + H2O (pH indicator change) Cross-sensitivity: Substance CO CO2 NO NH3 CH4 H 2S Hexane Isobutylene Toluene Concentration (ppmv) Apparent Reading* 3000 10% 100 300 25000 100 1200 100 100 0 0 0 0# 0 0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. # Reduces reading in mixture. Other Possible Interferences: Acid gases. 88 www.honeywellanalytics.com Sulfur Dioxide SO2 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-107-30 Extended Range Extended Range Standard Range 50 - 1000 2 200 2x1 0.25 100 - 2000 1 100 1 0.5 200 - 4000 0.5 50 1 1 Precision (Relative Standard Deviation)*: ≤±10% Linearity with No. of Pump Strokes: r2 = 0.999 Humidity: No effect 5 - 50% RH; 100% RH reduces the response by about 40% Temperature Range: Temp (°C/°F) Corr. Factor 0/32 1.1 0 - 40°C (32 - 104°F) 10/50 1.0 25/77 1.0 40/104 1.0 Color Change: Blue → Yellow Reaction Principle: SO2 + 2NaOH → Na2SO3 + H2O (pH indicator change) Cross-sensitivity: Substance CO CO2 NO NH3 CH4 H 2S Hexane Isobutylene Toluene Concentration (ppmv) Apparent Reading* 3000 10% 100 300 25000 100 1200 100 100 0 0 0 0# 0 0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. # Reduces reading in mixture. Other Possible Interferences: Acid gases. www.honeywellanalytics.com 89 DATA SHEETS Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. DATA SHEETS Sulfur Dioxide SO2 No. H-10-107-40 Extended Range 0.1 – 2.5% 2 200 2x2 0.5 Range (%) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Standard Range 0.2 - 5% 1 100 2 1 Extended Range 0.4 - 10% 0.5 50 1.5 2 Precision (Relative Standard Deviation)*: ≤±10% Linearity with No. of Pump Strokes: r2 = 0.999 Humidity: No effect 5 - 90% RH Temperature Range: 0 - 40°C (32 - 104°F) Temp (°C/°F) 0/32 10/50 25/77 40/104 Corr. Factor 1.15 1.0 1.0 1.0 Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: Yellow → Green Reaction Principle: SO2 + Cr(VI) + H2O → H2SO4 + Cr(III) Cross-sensitivity: Substance CO CO2 NH3 CH4 H2S Hexane Isobutylene Benzene Concentration (ppmv) Apparent Reading* 3000 5% 5% 2.5% 50 1500 2000 100 0 0 2.3% # 0 0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. # Forms a bright yellow color and reduces reading in mixture. Other Possible Interferences: Reducing gases. 90 www.honeywellanalytics.com Toluene C7H8 No. H-10-114-20 Extended Range Range (ppmv) 5 - 150 2 No. of Pump Strokes 200 Sample Volume (mL) 2x2 Sample Time (min) 0.5 Correction Factor Precision (Relative Standard Deviation)*: ≤±12% Linearity with No. of Pump Strokes: r2 = 0.994 Humidity: No effect 0 - 90% RH Temperature Range: 0 - 40°C Temp (°C/°F) Corr. Factor 0/32 1.2 10/50 1.0 Standard Range Extended Range 10 - 300 1 100 2 1 20 - 600 0.5 50 1.5 2 (32 - 104°F) 25/77 1.0 40/104 1.1 Cross-sensitivity: Substance Benzene p-Xylene o-Xylene m-Xylene Ethylbenzene Styrene Ethylene Isobutylene Isobutylene Hexane CO CO2 H2S NH3 CH4 SO2 Concentration (ppmv) Apparent Reading* 95 100 100 100 100 100 100 100 2000 100 3000 15000 50 50000 25000 2050 110 green-brown 40 35 30 70 10 0 0 100 (faint) 7 (faint) 0 0 55 (faint ring) 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. Other Possible Interferences: Other aromatics and reducing agents. www.honeywellanalytics.com 91 DATA SHEETS Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: White → Brown Reaction Principle: C8H10 + I2O5 + H2SO4 → I2 + Oxidation Products DATA SHEETS Trichloroethylene CHCl=CCl2 No. H-10-119-20 Extended Range Range (ppmv) 2.5 - 50 2 No. of Pump Strokes 200 Sample Volume (mL) 2x3 Sample Time (min) 0.5 Correction Factor Precision (Relative Standard Deviation)*: ≤±20% Linearity with No. of Pump Strokes: r2 = 0.999 Humidity: No effect 0 - 95% RH Temperature Range: 0 - 40°C (32 - 104°F) Temp (°C/°F) Corr. Factor 0/32 1.6 10/50 1.3 25/77 1.0 Standard Range Extended Range 5 - 100 1 100 3 1 10 - 230 0.5 50 2 2.3 40/104 1.1 Storage Life: 1 year in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: Yellow → Purple Reaction Principle: Cl2C=CHCl + PbO2 + H2SO4 → HCl HCl + Base → Chloride (dye color change) Cross-sensitivity: Substance Tetrachloroethylene 1,2-Dichloroethylene Vinyl Chloride 1,1,2-Trichloroethane Acetone Toluene p-Xylene Cl2 HCl NO NO2 Concentration (ppmv) Apparent Reading* 40 100 100 100 1000 1000 1000 10 50 500 500 70 20 10 <0.5 0 0 0 10 (pale beige) 21 0 60 (pale beige) * Data based on Honeywell pumps and tubes used in standard range. Other Possible Interferences: Acid gases. No response to H2S, CO or CH4. Caution: Use of connector tubing other than that supplied may reduce response. 92 www.honeywellanalytics.com Vinyl Chloride CH2=CHCl No. H-10-128-10 Extended Range Standard Range Extended Range 0.5-10 2 200 2x3 0.42 1-20 1 100 3 1.0 2-40 0.5 50 3 2.2 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Precision (Relative Standard Deviation)*: ≤±20% Linearity with No. of Pump Strokes: r2 = 0.991 Humidity: No effect 5 - 100% RH Temperature Range: 0/32 2.5 10/50 1.3 (32 - 104°F) 25/77 1.0 40/104 0.8 Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: Yellow → Purple Reaction Principle: Pretube: C2H3Cl + K2Cr2O7 + H2SO4 → HCl + Other Prods Measurement Tube: HCl + indicator dye → reddish purple color Cross-sensitivity: Substance 1,3-Dichloropropylene 1,1-Dichloroethylene Trichloroethylene Tetrachloroethylene Ethyl Chloroformate Methyl Chloroformate 1,2-Dichloroethane Methyl chloride Chloroform Ethylene Benzene Concentration (ppmv) Apparent Reading* 20 10 10 60 40 120 100 2000 100 1000 600 20 16 3.5 1.5 0.4 0.1 0 0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. Other Possible Interferences: HCl, chlorinated hydrocarbons. No response to 500 ppm CO, 5000 ppm CO2, or 600 ppm toluene. www.honeywellanalytics.com 93 DATA SHEETS Temp (°C/°F) Corr. Factor 0 - 40°C DATA SHEETS Water Vapor (Pipeline) H2O Extended Range 1-5 4 400 4 x 1.5 min 4 x 45 sec 0.51 Range (lbs/MMCF) No. of Pump Strokes Sample Volume (mL) Sample Time (min) in air (sec) in natural gas Correction Factor No. H-10-120-10 Standard Range 2 - 10 2 200 2 x 1.5 min 2 x 45 sec 1 Extended Range 4 - 20 1 100 1.5 min 45 sec 2.22 Precision (Relative Standard Deviation)*: ≤±12% Linearity with No. of Pump Strokes: r2 = 0.99 Temperature Range: 0 - 40°C (32 - 104°F) Temp (°C/°F) Corr. Factor 0/32 1.1 10/50 1.0 23/73 1.0 40/104 0.9 Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F) Refrigeration preferred. Color Change: Yellow → Green Reaction Principle: H2O + Mg(ClO4)2 → Mg(ClO4)2•H2O Cross-sensitivity: Substance CH4 Propane (C3H8) Isobutylene Hexanes CO CO2 SO2 H2S NH3 HCl Ethylene glycol Triethylene glycol Methanol Toluene Concentration (ppmv) Reading* (lbs/ MMCF) 100% 10000 10000 3000 200 3000 1500 2000 100 300 saturated saturated 50 400 0 ≤2 0 0 0 0 0 ~1 entire tube 0 0 0 0‡ ~1 * Data based on Honeywell pumps and tubes used in standard range. ‡ Forms light green stain when methanol is above 70 ppm. Water can be measured in a mixture with methanol by reading the dark green stain only, ignoring the light green methanol stain beyond dark green end point. See Technical Note on page 96 for pictures. Other Possible Interferences: Amines, alcohols. No response to heptanes, octanes as present in “rich” natural gas or commonly called “condensate.” 94 www.honeywellanalytics.com Water Vapor (Pipeline) H2O No. H-10-120-20 Extended Range Standard Range Extended Range 3 - 20 2 200 2 x 1.5 0.45 6 - 40 1 100 1.5 1 12 - 80 0.5 50 1 2.3 Range (lbs/MMCF) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Precision (Relative Standard Deviation)*: ≤±20% Linearity with No. of Pump Strokes: r2 = 0.994 Temperature Range: Temp (°C/°F) Corr. Factor 0/32 1.3 0 - 40°C (32 - 104°F) 10/50 1.1 25/77 1.0 40/104 0.74 Cross-sensitivity: Substance CH4 CO CO2 SO2 H 2S NH3 HCl Methanol Gasoline Heptane Ethylene glycol Triethylene glycol Toluene Concentration (ppmv) Reading* (lbs/ MMCF) 100% 200 10% 1500 2000 250 300 80 saturated saturated saturated saturated saturated 0 0# 0# 0# <3# 35 0# 0‡ 0 0 0 0 0 * Data based on Honeywell pumps and tubes used in standard range. # No interference in mixtures with water vapor. ‡ No response below 80 ppm. Light green stain when methanol is above 80 ppm, 340 ppm alone reads ~30 lbs/MMCF. Water can be measured in a mixture with methanol by reading the dark green stain only, ignoring the light green methanol stain beyond the dark green end point. **Note: Color tends towards purple as temperature decreases. Other Possible Interferences: Amines, alcohols; no effect of 500 ppm PH3. www.honeywellanalytics.com 95 DATA SHEETS Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F) Refrigeration preferred Color Change: Yellow → Dark Green** Reaction Principle: H2O + Mg(ClO4)2 → Mg(ClO4)2•H2O DATA SHEETS Technical Note Effect of Methanol & Glycols on Water Vapor Tubes Introduction Colorimetric tubes for water vapor are commonly used to measure the humidity of natural gas because of their rapid response compared to instrumental methods. To minimize corrosion and to obtain a better selling price for the gas, water vapor levels are often reduced by passing the gas through a liquid scrubber containing ethylene glycol or triethylene glycol. In addition, methanol is sometimes added to the natural gas pipeline as an antifreeze so that ice does not accumulate during cold weather. This technical note describes how to read water vapor tubes that may have interference from these chemicals. Resistance to Glycol Response and “Rich” Gas Newer versions of Honeywell water vapor tubes have been improved to remove any response to ethylene glycol or triethylene glycol. These changes were implemented in the 6-40 lbs/MMCF tubes (p/n H-10-120-20) shipped after November 2003 and in the 2-10 lbs/MMCF tubes (p/n H-10-120-10) shipped after November 2004. Higher alkanes such as pentane, hexanes and octanes present in "rich" natural gas also cause no response. Effect of Methanol Methanol alone causes a light green response in both H-10-120-10 and H-10-120-20 tubes when its concentration is above about 80 ppm. When water and methanol are present together, a two-tone stain is seen. On the H-10-120-10 (2-10 lbs/MMCF) tubes, the water forms a medium-dark green stain followed by a light green stain for methanol (see Figure 1). H2O: 0 Methanol: 60 ppm H2O: 6 lbs/MMCF H2O: 0 Methanol: 60 ppm Methanol: 100 ppm H2O: 8 lbs/MMCF Methanol: 100 ppm Figure 1. Methanol response on H-10-120-10 (2-10 lbs/MMCF) tube. 96 www.honeywellanalytics.com On the H-10-120-20 (6-40 lbs/MMCF) tubes, the water forms a purple stain followed by a light green stain for methanol (see Figure 2). This light green color can be ignored and only the darker stain read to obtain the water vapor concentration. Methanol: 79 ppm H2O: 20 lbs/MMCF Methanol: 158 ppm H2O: 30 lbs/MMCF Methanol: 237 ppm H2O: 40 lbs/MMCF Methanol: 316 ppm DATA SHEETS H2O: 10 lbs/MMCF Figure 2. Methanol response on H-10-120-20 (6-40 lbs/MMCF) tube. 0°C/32°F H2O: 20 lbs/MMCF Methanol: 100 ppm 20°C/68°F H2O: 20 lbs/MMCF Methanol: 100 ppm 30°C/86°F H2O: 20 lbs/MMCF Methanol: 100 ppm Figure 3. Effect of Temperature on H-10-120-20 tube. Figure 3 shows that the color stain for water vapor is greener at higher temperatures and tends towards purple as the temperature is lowered. Therefore the distinction between methanol and water vapor response is clearer at lower temperatures. www.honeywellanalytics.com 97 DATA SHEETS Water Vapor (Metric) H2O Range (mg/L) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor No. H-10-120-30 Extended Range Standard Range Extended Range 0.025 - 0.5 2 200 2 x 1.5 0.46 0.05 - 1.0 1 100 1.5 1 0.1 - 2.0 0.5 50 1 2.1 Precision (Relative Standard Deviation)*: ≤±12% Linearity with No. of Pump Strokes: r2 = 0.999 Temperature Range: Temp (°C/°F) Corr. Factor 0/32 0.95 0 - 40°C (32 - 104°F) 10/50 0.95 25/77 1.0 40/104 1.0 Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F) Refrigeration preferred. Color Change: Yellow → Dark Green** Reaction Principle: H2O + Mg(ClO4)2 → Mg(ClO4)2•H2O Cross-sensitivity: Substance CH4 Propane (C3H8) CO CO2 SO2 H2S NH3 PH3 HCl Methanol Triethylene glycol Toluene Concentration (ppmv) Reading* (mg/L) 100% 10000 200 10% 1500 600 250 500 300 100 Saturated 400 0 0 0# 0# 0# 0# 0.6 0 0# ~0.02‡ ~0.05 <0.1 * Data based on Honeywell pumps and tubes used in standard range. # No interference in mixtures with water vapor. ‡ No response below 100 ppm. Positive interference when methanol is above 100 ppm. 250 ppm alone reads ~0.5 mg/L. ** Note: Read tube at end of dark green stain. Color tends towards purple as temperature decreases. Other Possible Interferences: Amines, alcohols. 98 www.honeywellanalytics.com Water Vapor (Metric) H2O No. H-10-120-40 Range (mg/L) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Extended Range Standard Range Extended Range 0.5 - 4 2 200 2 x 1.5 0.4 1 - 18 1 100 1.5 1 2 - 32 0.5 50 1 See Fig. 2 Precision (Relative Standard Deviation)*: ≤±20% Linearity with No. of Pump Strokes: r2 = 0.959 Temperature Range: Refer to Figures 1 and 2. Requires accurate temperature measurement. Storage Life: 1 year in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. Color Change: Yellow green → Purple DATA SHEETS Reaction Principle: H2O + Mg(ClO4)2 → Mg(ClO4)2•H2O Cross-sensitivity: Substance CH4 CO2 CO H 2S SO2 HCl NO2 NH3 PH3 Acetone Ethanol Concentration (ppmv) Reading* (mg/L) 25000 200000 500 1000 3500 2000 460 460 40 1000 2000 0 0 0 0 0 0 0 1 0 1 (green) 1.5 * Data based on Honeywell pumps and tubes used in standard range. Continued on next page www.honeywellanalytics.com 99 No. H-10-120-40 DATA SHEETS Water Vapor H2O (Continued) 100 www.honeywellanalytics.com Xylenes C8H10 No. H-10-112-20 Extended Range Standard Range Extended Range 5 - 100 4 400 4x2 0.5 10 - 200 2 200 2x2 1 20 - 400 1 100 2 2 Range (ppmv) No. of Pump Strokes Sample Volume (mL) Sample Time (min) Correction Factor Precision (Relative Standard Deviation)*: ≤±12% Linearity with No. of Pump Strokes: r2 = 0.991 Humidity: No effect 5 - 95% RH Temperature Range: Temp (°C/°F) Corr. Factor 0/32 2.4 0 - 40°C 10/50 1.4 (32 - 104°F) 21/70 1.0 40/104 1.7 Storage Life: 2 years in darkness at 5 - 25°C (40 - 77°F). Refrigeration preferred. DATA SHEETS Color Change: White → Reddish Brown Reaction Principle: C8H10 + I2O5 + H2SO4 → I2 + oxidation products Cross-sensitivity: Substance p-Xylene o-Xylene m-Xylene Toluene Benzene Hexane Isobutylene CO CO2 H2S NO NH3 CH4 SO2 Concentration (ppmv) Apparent Reading* 100 100 100 20 10 100 100 250 50000 5000 100 100 25000 10 100 40 (brown) 20 (brown) 50 (brown) 10 (v.faint) 0 0 0 0 0 3 (v.faint) 0 0 0 *Data based on Honeywell pumps and tubes used in standard range. Note: The tube is calibrated to p-xylene. Other Possible Interferences: Other aromatics. www.honeywellanalytics.com 101 DATA SHEETS 102 www.honeywellanalytics.com 6. SPECIALTY TUBES 6.1 Smoke Generating Tubes Smoke generating tubes are designed for use in respirator fit tests. These tubes are of the stannic chloride type required by OSHA for use in the irritant smoke fit test procedure. The tubes can also be used for visualizing air currents, such as in testing the performance of fume hoods or in detecting leaks from an air duct. 1. Operation Smoke tubes are operated by simply breaking open each end and inserting into a rubber squeeze bulb or other pump. Air pushed through the tube releases the stannic chloride, which decomposes on contact with moisture in the air to form a smoke. The tubes can be re-used until no more smoke is evolved. Rubber caps are provided to seal the tubes between uses. 2. Smoke Tube Kit The Smoke Tube Kit (Part no. H-010-0004-000) contains the following: • Aspirator bulb • Tube tip breaker • 1 Box of 6 smoke tubes • Soft carrying case www.honeywellanalytics.com 103 SPECIALTY TUBES Figure 6.1. Use of smoke tube for visualizing fume hood air currents. SPECIALTY TUBES Gas Generation Tube Data Sheet Irritant Smoke No. H-10-123-01 Color: A white smoke is generated. The tube changes from a dark reddish brown to a lighter reddish brown. The tube can be used repeatedly until it is spent. Keep the tube closed between uses with the supplied rubber caps. Reagent Type: Stannic chloride Reaction Principle: SnCl4 + H2O → stannic oxychlorides + 2HCl Humidity Range: 10 - 95% RH. The smoke generating life increases about 10% at 20% RH and decreases about 10% at 80% RH (incoming air humidity). Temperature Range: 0 - 40°C (32 - 104°F). As temperature decreases the smoke lasts longer and is less intense. Storage Life and Conditions: 2 years in darkness at 5 - 25°C (40 - 77°F) CAUTIONS ON USE: • Read, understand and comply with all labels, warnings and instructions accompanying these tubes before use. Failure to comply may cause serious injury or death. • For use in respirator fit testing according to OSHA 29 CFR 1910.134 (appendix A) and OSHA 1910.139. • Wear safety glasses and gloves to protect against chemical exposure and flying glass. Wear a respirator when exposed to smoke. Vapors are corrosive to skin and overexposure can result in serious injury or death. • DO NOT inhale smoke directly. If inhaled enough to cause coughing, remove victim to fresh air. If coughing persists, provide oxygen and contact a physician. • Use only in a well-ventilated area. DO NOT use in a confined space. • DO NOT use under a respirator fit testing hood or other enclosed space because fume concentrations may build up to levels that can cause serious injury or death. • Avoid contact of smoke with skin. DO NOT direct smoke stream directly at the skin during fit testing. If smoke contacts skin for prolonged time, skin burns can result; flush with copious amounts of water for 15 minutes and contact a physician. • If smoke contacts eyes, immediately flush with water for 15 minutes and contact a physician. Eyes should be kept tightly closed during fit testing. • Use only the pump(s) and flow rates specified in OSHA CFR 1910.134 and 29 CFR 1910.139. If the pump is operated at non-specified flow rates it could increase the smoke and fume concentrations and cause serious injury or death. • Do not use smoke tubes in areas that may contact food or food eating areas. Ingestion of tube contents or fodd exposed to smoke may cause serious injury or death. • Do not use for fit testing on persons with pre-existing respiratory or related medical conditions or are allergic to tin compounds or hydrochloric acid. • When using for visualizing air currents, avoid exposure to persons downstream of the air flow. Disposal: Dispose of spent or expired tubes according to local regulations. Each tube contains 1.0 g of stannic chloride before use. Tube contents generate hydrochloric acid on contact with water. 104 www.honeywellanalytics.com 7 APPENDICES Compound Acetone Amines Ammonia Benzene 1,3-Butadiene n-Butane Carbon Dioxide Carbon Monoxide Chlorine Chlorine Dioxide Diesel & Jet Fuel Ethanol Formaldehyde Gasoline Hydrocarbons Hydrogen Chloride Hydrogen Cyanide Hydrogen Fluoride Hydrogen Sulfide (ppmv unless noted) (ppmv unless noted) Total Meas. Range Standard Meas. Time H-10-111-40 H-10-132-10 H-10-100-05 H-10-100-10 H-10-100-12 H-10-100-15 H-10-100-40 H-10-101-01 H-10-101-10 H-10-101-20 H-10-135-04 H-10-137-30 H-10-104-30 H-10-104-40 H-10-104-45 H-10-104-50 H-10-104-60 H-10-102-18 H-10-102-20 H-10-102-30 H-10-102-45 H-10-106-10 H-10-106-20 H-10-130-10 H-10-143-10 H-10-141-30 H-10-121-05 H-10-138-30 H-10-110-30 H-10-108-09 H-10-108-10 H-10-108-22 H-10-126-10 H-10-105-10 0.1- 2% 0.5 - 10 1 - 30 5 - 100 10 - 260 25 - 500 1 - 15% 0.5 - 10 5 - 40 5 - 100 0.5 - 5 25 - 1400 300 - 5000 0.05 - 1% 0.25 - 3% 1 - 20% 5 - 40% 5 - 100 5 - 100 20 - 500 0.2 - 4% 0.5 - 8 5 - 100 0.25 - 15 0.25 - 25 100 - 2000 0.1 - 5 30 - 1000 50 - 1000 1 - 20 1 - 20 20 - 500 2.5 - 60 0.5 - 20 0.05 - 4% 0.25 - 20 0.5 - 60 2.5 - 200 5 - 520 12 - 1000 0.5 - 30% 0.25 - 30 2.5 - 200 2.5 - 200 0.25 - 10 12.5 - 2800 150 - 10000 0.025 - 2% 0.125 - 6% 0.25 - 20% 1.25 - 40% 2.5 - 300 2.5 - 200 10 - 1000 0.1 - 8% 0.25 - 16 2.5 - 200 0.05 - 30 N/A 50 - 2000 0.1 - 40 15 - 2000 25 - 2000 0.5 - 40 0.5 - 40 10 - 1000 1.25 - 120 0.25 - 40 1x2 1x1 1 x 1.5 1x1 1 x 1.5 1x1 1x2 3x3 5x3 1x2 2x2 1 x 2.5 1x2 1x2 1x2 0.5 x 1 0.5 x 1 3x3 1x2 1 x 1.5 0.5 x 1 1 x 2.5 1x2 1x2 4 x 1.5 1x3 5x2 2x2 2x2 1x1 1x1 1 x 1.5 2 x 2.5 4 x 0.5 H-10-103-04 H-10-103-05 0.2 - 3 0.2 - 3 0.1 - 6 0.1 - 6 1 x 1.5 1x2 Tube Number Standard Range www.honeywellanalytics.com (Strokes x min. per stroke) 105 APPENDICES 7.1 Appendix 1. Alphabetical Tube List APPENDICES Appendix 1 (Continued). Alphabetical Tube List Compound Hydrogen Sulfide (cont.) Tube Number Standard Range (ppmv unless noted) Total Meas. Range Standard Meas. Time (ppmv unless noted) (Strokes x min. per stroke) H-10-103-06 1-7 0.25 - 7 0.5 x 1 H-10-103-10 H-10-103-12 2.5 - 60 0 - 150 1.25 - 120 0 - 300 1 x 1.5 H-10-103-15 10 - 120 5 - 240 1 x 1.5 H-10-103-18 25 - 250 12.5 - 500 1x1 H-10-103-20 50 - 800 25 - 1600 1x2 H-10-103-30 100 - 2000 50 - 4000 1x2 H-10-103-40 0.1 - 2% 0.05 - 4% 1x2 H-10-103-50 2 - 40% 0.5 - 40% 0.5 x 2 Mercaptans H-10-129-20 5 - 120 2.5 - 240 1x2 Methyl Bromide H-10-131-10 H-10-131-30 1 - 18 20 - 300 0.5 - 36 10 - 600 2x3 1x2 3x2 Methyl Ethyl Ketone H-10-113-20 1 x 1.5 0.02 - 0.6% 0.01 - 1.8% Nitric Acid H-10-146-20 1 - 20 0.5 - 40 1x1 Nitrogen Dioxide H-10-117-10 0.5 - 30 N/A 1 x 1.5 Nitrogen Oxides H-10-109-20 1 - 50 0.5 - 100 1x3 Ozone H-10-133-03 0.05 - 0.6 0.05 - 1.8 5x2 Phenol H-10-139-05 1 - 25 0.5 - 180 2 x 1.5 Phosphine H-10-116-10 H-10-116-20 5 - 50 25 - 500 2.5 - 100 12.5 - 1000 2 x 1.5 1 x 1.5 H-10-116-25 50 - 1000 25 - 2000 1 x 1.5 H-10-107-15 H-10-107-20 2 - 30 5 - 100 1 - 60 2.5 - 200 2x2 1x2 H-10-107-25 100 - 1800 50 - 3600 1x2 H-10-107-30 200 - 4000 50 - 4000 0.5 x 1 H-10-107-40 0.2 - 5% 0.1 - 10% 1x2 H-10-114-20 10 - 300 5 - 600 1x2 Trichloroethylene H-10-119-20 5 - 100 2.5 - 230 1x3 Vinyl Chloride H-10-128-10 1 - 20 0.5 - 40 1x3 Water Vapor H-10-120-10 H-10-120-20 2-10 lbs/MMCF 6-40 lbs/MMCF 1-20 lbs/MMCF 3-80 lbs/MMCF 2 x 1.5 1 x 1.5 H-10-120-30 0.05 - 1 mg/L 0.025 - 2 mg/L 1 x 1.5 H-10-120-40 1 - 18 mg/L 0.5 - 32 mg/L 1 x 1.5 H-10-112-20 10 - 200 5 - 400 2x2 Sulfur Dioxide Toluene Xylenes 106 www.honeywellanalytics.com 7.2 Appendix 2. Tube List by Part Number H-10-100-05 H-10-100-10 H-10-100-12 H-10-100-15 H-10-100-40 H-10-101-01 H-10-101-10 H-10-101-20 H-10-102-18 H-10-102-20 H-10-102-30 H-10-102-45 H-10-103-04 H-10-103-05 H-10-103-06 H-10-103-10 H-10-103-12 H-10-103-15 H-10-103-18 H-10-103-20 H-10-103-30 H-10-103-40 H-10-103-50 H-10-104-30 H-10-104-40 H-10-104-45 H-10-104-50 H-10-104-60 H-10-105-10 H-10-106-10 H-10-106-20 H-10-107-15 H-10-107-20 H-10-107-25 H-10-107-30 H-10-107-40 H-10-108-09 H-10-108-10 H-10-108-22 H-10-109-20 H-10-110-30 H-10-111-40 H-10-112-20 Compound Ammonia Benzene Carbon Monoxide Hydrogen Sulfide Carbon Dioxide Hydrogen Fluoride Chlorine Sulfur Dioxide Hydrogen Chloride Nitrogen Oxides Hydrocarbons Acetone Xylenes Total Measurement Standard Range Range (ppmv unless noted) (ppmv unless noted) 1 - 30 5 - 100 10 - 260 25 - 500 1 - 15% 0.5 - 10 5 - 40 5 - 100 5 - 100 5 - 100 20 - 500 0.2 - 4% 0.2 - 3 0.2 - 3 1-7 2.5 - 60 0 - 150 10 - 120 25 - 250 50 - 800 100 - 2000 0.1 - 2% 2 - 40% 300 - 5000 0.05 - 1% 0.25 - 3% 1 - 20% 5 - 40% 0.5 - 20 0.5 - 8 5 - 100 2 - 30 5 - 100 100 - 1800 200 - 4000 0.2 - 5% 1 - 20 1 - 20 20 - 500 1 - 50 50 - 1000 0.1- 2% 10 - 200 www.honeywellanalytics.com 0.5 - 60 2.5 - 200 5 - 520 12 - 1000 0.5 - 30% 0.25 - 30 2.5 - 200 2.5 - 200 2.5 - 300 2.5 - 200 10 - 1000 0.1 - 8% 0.1 - 6 0.1 - 6 0.25 - 7 1.25 - 120 0 - 300 5 - 240 12.5 - 500 25 - 1600 50 - 4000 0.05 - 4% 0.5 - 40% 150 - 10000 0.025 - 2% 0.125 - 6% 0.25 - 20% 1.25 - 40% 0.25 - 40 0.25 - 16 2.5 - 200 1 - 60 2.5 - 200 50 - 3600 50 - 4000 0.1 - 10% 0.5 - 40 0.5 - 40 10 - 1000 0.5 - 100 25 - 2000 0.05 - 4% 5 - 400 107 APPENDICES Tube Number APPENDICES Appendix 2 (Continued). Tube List by Part Number Tube Number Compound H-10-113-20 H-10-114-20 H-10-116-10 H-10-116-20 H-10-116-25 H-10-117-10 H-10-119-20 H-10-120-10 H-10-120-20 H-10-120-30 H-10-120-40 H-10-121-05 H-10-126-10 H-10-128-10 H-10-129-20 H-10-130-10 H-10-131-10 H-10-131-30 H-10-132-10 H-10-133-03 H-10-135-04 H-10-137-30 H-10-138-30 H-10-139-05 H-10-141-30 H-10-143-10 H-10-146-20 Methyl Ethyl Ketone Toluene Phosphine 108 Nitrogen Dioxide Trichloroethylene Water Vapor Formaldehyde Hydrogen Cyanide Vinyl Chloride Mercaptans Chlorine Dioxide Methyl Bromide Amines Ozone 1,3-Butadiene n-Butane Gasoline Phenol Ethanol Diesel & Jet Fuel Nitric Acid Total Measurement Standard Range Range (ppmv unless noted) (ppmv unless noted) 0.02 - 0.6% 10 - 300 5 - 50 25 - 500 50 - 1000 0.5 - 30 5 - 100 2-10 lbs/MMCF 6-40 lbs/MMCF 0.05 - 1 mg/L 1 - 18 mg/L 0.1 - 5 2.5 - 60 1 - 20 5 - 120 0.25 - 15 1 - 18 20- 300 0.5 - 10 0.05 - 0.6 0.5 - 5 25 - 1400 30 - 1000 1 - 25 100 - 2000 0.25 - 25 1 - 20 www.honeywellanalytics.com 0.01 - 1.8% 5 - 600 2.5 - 100 12.5 - 1000 25 - 2000 N/A 2.5 - 230 1-20 lbs/MMCF 3-80 lbs/MMCF 0.025 - 2 mg/L 0.5 - 32 mg/L 0.1 - 40 1.25 - 120 0.5 - 40 2.5 - 240 0.05 - 30 0.5 - 36 10 - 600 0.25 - 20 0.05 - 1.8 0.25 - 10 12.5 - 2800 15 - 2000 0.5 - 180 50 - 2000 N/A 0.5 - 40 7.3 Appendix 3. Detectable Compounds Tube Used Ammonia Formaldehyde Acetone Methyl Ethyl Ketone Ammonia Allylamine Benzene Amines Hydrogen Sulfide Sulfur Dioxide Amines Benzene 1,3-Butadiene n-Butane t-Butanol 2-Butanone Butylamine Toluene Gasoline 1,3-Butadiene n-Butane Hydrocarbons Ethanol Methyl Ethyl Ketone Ammonia Butyl Mercaptan Mercaptans Hydrogen Sulfide Carbon Dioxide Carbon Dioxide Carbon Monoxide Carbon Monoxide Benzene Diesel & Jet Fuel Tube Number H-10-121-05 H-10-111-40 H-10-113-20 H-10-100-05 H-10-100-10 H-10-100-12 H-10-100-15 H-10-100-40 H-10-132-10 H-10-103-50 H-10-107-40 H-10-132-10 H-10-101-01 H-10-101-10 H-10-101-20 H-10-114-20 H-10-138-30 H-10-135-04 H-10-137-30 H-10-110-30 H-10-141-30 H-10-113-20 H-10-100-05 H-10-100-10 H-10-100-12 H-10-100-15 H-10-129-20 H-10-103-04 H-10-103-06 H-10-104-30 H-10-104-40 H-10-104-45 H-10-104-50 H-10-104-60 H-10-102-18 H-10-102-20 H-10-102-30 H-10-102-45 H-10-101-10 H-10-101-20 H-10-143-10 www.honeywellanalytics.com Standard Range (ppmv unless noted) 0.1 - 5 0.1- 2% 1 - 30 5 - 100 10 - 260 25 - 500 1 - 15% 0.5 - 10 5 - 40 5 - 100 0.5 - 5 25 - 1400 0.02 - 0.6% 300 - 5000 0.05 - 1% 0.25 - 3% 1 - 20% 5 - 40% 5 - 100 5 - 100 20 - 500 0.2 - 4% 109 APPENDICES Compound to be Measured Acetaldehyde Acetone APPENDICES Appendix 3 (Continued). Detectable Compounds Compound to be Measured Chloride Chlorine Chlorine Dioxide Tube Used Methyl Bromide Chlorine Chlorine Dioxide Methyl Bromide Chlorine Dioxide Chlorine n-Decane 1,2-Dibromoethane 1,3-Dibromopropane Diesel Fuel Diethylamine Hydrocarbons Methyl Bromide Methyl Bromide Diesel & Jet Fuel Amines Ammonia 1,1-Dichloroethylene Hydrocarbons Hydrogen Chloride Vinyl Chloride Methyl Bromide Trichloroethylene Vinyl Chloride Ethanol Amines Amines Toluene Hydrocarbons Amines Mercaptans Formaldehyde Gasoline Diesel & Jet Fuel Hydrocarbons Hydrocarbons Butane Carbon Monoxide Hydrocarbons Hydrogen Chloride Hydrogen Cyanide Nitric Acid Hydrogen Cyanide 1,2- Dichloroethylene 1,3-Dichloropropylene Ethanol Ethanolamine Ethylamine Ethylbenzene Ethylene Ethylenediamine Ethyl Mercaptan Formaldehyde Gasoline n-Heptane n-Hexane 110 Tube Number H-10-131-30 H-10-106-10 H-10-106-20 H-10-130-10 H-10-131-10 H-10-130-10 H-10-106-10 H-10-106-20 H-10-110-30 H-10-131-30 H-10-131-30 H-10-143-10 H-10-132-10 H-10-100-05 H-10-100-10 H-10-100-12 H-10-100-15 H-10-128-10 H-10-131-10 H-10-119-20 H-10-128-10 H-10-141-30 H-10-132-10 H-10-132-10 H-10-114-20 H-10-110-30 H-10-132-10 H-10-129-20 H-10-121-05 H-10-138-30 H-10-143-10 H-10-110-30 H-10-110-30 H-10-137-30 H-10-102-30 H-10-110-30 H-10-108-09 H-10-108-10 H-10-108-22 H-10-146-20 H-10-126-10 www.honeywellanalytics.com Standard Range (ppmv unless noted) 20- 300 0.5 - 8 5 - 100 0.25 - 15 20- 300 20- 300 0.5 - 25 0.5 - 10 1 - 20 100 - 2000 0.5 - 10 5 - 120 0.1 - 5 30 - 1000 50 - 1000 1 - 20 1 - 20 20 - 500 1 - 20 2.5 - 60 Appendix 3 (Continued). Detectable Compounds Hydrogen Fluoride Hydrogen Sulfide Tube Used Hydrogen Fluoride Hydrogen Chloride Nitric Acid Hydrogen Sulfide Benzene Gasoline Hydrocarbons Phosphine Isobutane Isobutylene Isopar L Isopropanol Jet Fuel JP-5, JP-8 Methanol Methylamine Methyl Bromide Hydrocarbons Butane Methyl Ethyl Ketone 1,3-Butadiene Gasoline Ethanol Diesel & Jet Fuel Ethanol Amines Methyl Bromide Methyl Ethyl Ketone (MEK) Methyl Ethyl Ketone Acetone Methyl Isobutyl Ketone Methyl Ethyl Ketone Acetone Methyl Mercaptan Mercaptans Ethanol Hydrogen Sulfide Hydrogen Sulfide Hydrogen Sulfide Methyl Propyl Ketone Methyl Ethyl Ketone Acetone Tube Number Standard Range (ppmv unless noted) H-10-105-10 H-10-108-09 H-10-146-20 H-10-103-04 H-10-103-05 H-10-103-06 H-10-103-10 H-10-103-12 H-10-103-15 H-10-103-18 H-10-103-20 H-10-103-30 H-10-103-40 H-10-103-50 H-10-101-20 H-10-138-30 H-10-110-30 H-10-116-10 H-10-116-20 H-10-116-25 H-10-110-30 H-10-137-30 H-10-113-20 H-10-135-04 H-10-138-30 H-10-141-30 H-10-143-10 H-10-141-30 H-10-132-10 H-10-131-10 H-10-131-30 H-10-113-20 H-10-111-40 H-10-113-20 H-10-111-40 H-10-129-20 H-10-141-30 H-10-103-04 H-10-103-06 H-10-103-40 H-10-113-20 H-10-111-40 0.5 - 20 www.honeywellanalytics.com 1 - 20 0.2 - 3 0.2 - 3 1-7 2.5 - 60 0 - 150 10 - 120 25 - 250 50 - 800 100 - 2000 0.1 – 2% 2 - 40% 50 - 1000 0.5 - 5 0.5 - 25 100 - 2000 0.5 - 10 1 - 18 20- 300 0.02 - 0.6% 5 - 120 111 APPENDICES Compound to be Measured APPENDICES Appendix 3 (Continued). Detectable Compounds Compound to be Measured Nitric Acid Nitric Oxide Nitrogen Dioxide Tube Used Nitric Acid Nitrogen Oxides Benzene Carbon Monoxide Carbon Monoxide Ethanol Nitrogen Dioxide Nitrogen Oxides Chlorine Perchloroethylene Petroleum Naphtha Phenol Phosphine Chlorine Dioxide Nitrogen Oxides Diesel & Jet Fuel Hydrocarbons Ozone Hydrocarbons Butane Trichloroethylene Hydrocarbons Phenol Phosphine Propionaldehyde Propane Propyleneimine Propyl Mercaptan Sulfur Dioxide Formaldehyde Butane Amines Mercaptans Sulfur Dioxide Nitrogen Oxides n-Octane Ozone n-Pentane Carbon Dioxide Styrene Tetrachloroethylene Toluene 112 Hydrogen Cyanide Toluene Trichloroethylene Toluene Benzene Gasoline Hydrocarbons Xylenes Tube Number Standard Range (ppmv unless noted) H-10-146-20 H-10-109-20 H-10-101-20 H-10-102-20 H-10-102-30 H-10-141-30 H-10-117-10 H-10-109-20 H-10-106-10 H-10-106-20 H-10-130-10 H-10-109-20 H-10-143-10 H-10-110-30 H-10-133-03 H-10-110-30 H-10-137-30 H-10-119-20 H-10-110-30 H-10-139-05 H-10-116-10 H-10-116-20 H-10-116-25 H-10-121-05 H-10-137-30 H-10-132-10 H-10-129-20 H-10-107-15 H-10-107-20 H-10-107-25 H-10-107-30 H-10-107-40 H-10-104-30 H-10-104-45 H-10-126-10 H-10-114-20 H-10-119-20 H-10-114-20 H-10-101-20 H-10-138-30 H-10-110-30 H-10-112-20 1 - 20 www.honeywellanalytics.com 0.5 - 30 1 - 50 1 - 50 0.05 – 0.6 1 - 25 5 - 50 25 - 500 50 - 1000 0.1 - 5 5 - 120 2 - 30 5 - 100 100 - 1800 200 - 4000 0.2 - 5% 10 - 300 Appendix 3 (Continued). Detectable Compounds 1,1,1-Trichloroethane Trichloroethylene Trimethylamine Undecane Water Vapor m-Xylene o-Xylene p-Xylene Tube Used Methyl Bromide Trichloroethylene Carbon Monoxide Carbon Monoxide Vinyl Chloride Amines Diesel & Jet Fuel Water Vapor Xylenes Toluene Xylenes Toluene Xylenes Toluene Tube Number H-10-131-10 H-10-119-20 H-10-102-20 H-10-102-30 H-10-128-10 H-10-132-10 H-10-143-10 H-10-120-10 H-10-120-20 H-10-120-30 H-10-120-40 H-10-112-20 H-10-114-20 H-10-112-20 H-10-114-20 H-10-112-20 H-10-114-20 www.honeywellanalytics.com Standard Range (ppmv unless noted) 5 - 100 0.5 - 25 2 - 10 lbs/MMCF 6 - 40 lbs/MMCF 0.05 - 1 mg/L 1 - 18 mg/L 10 - 200 113 APPENDICES Compound to be Measured 114 www.honeywellanalytics.com Compound Acetone Amines Ammonia Honeywell Tube # Range* H-10-111-40 0.1-2% H-10-132-10 0.5-10 H-10-100-10 1-30 H-10-100-10 5-100 H-10-100-12 10-260 H-10-100-15 25-500 H-10-100-40 1-15% Benzene H-10-101-01 0.5-10 H-10-101-10 5-40 H-10-101-20 5-100 1,3-Butadiene H-10-135-04 0.5 - 5 n-Butane H-10-137-30 25-1400 2-Butanone (MEK) H-10-113-20 0.02-0.6% Carbon Dioxide H-10-104-30 300-5,000 H-10-104-40 0.05-1% H-10-104-45 0.25-3% H-10-104-50 1-20% H-10-104-60 5-40% Carbon Monoxide H-10-102-18 5-100 H-10-102-20 5-100 H-10-102-30 20-500 H-10-102-45 0.2-4% Chlorine H-10-106-10 0.5-8 H-10-106-20 5-100 Chlorine Dioxide H-10-130-10 0.25-15 * Units are ppmv unless noted. 25-500 1-15% 0.5-10 1-20 5-60 0.5-5 25-1400 0.02-0.6% 300-5000 0.25-3% 1-10% 5-40% 5-100 5-50 25-500 0.2-5% 0.5-8 50-500 3M 3H 121SP 121SL 121 174LL 104 152 2LL 2L 2H 2HH 1LK 1LL 1La 1H 8La 8H Gastec Tube # Range* 151 0.01-0.8% 180L 0.5-10 3L 1-30 3La 5-100 5-200 4-100 0.1-2 500-6000 0.01-1.4% 300-7000 0.05-1.0% 0.1 - 2.6% 1-20% 5-50% 5-50 10-250 0.1-2.0% 0.5-10 50-140 1-20 118SB 118SC 168SE 221SA 139SB 126SC 126SB 126SA 126SH 126UH 106SB 106S 106SH 109SB 178S 116 Kitagawa Tube # Range* 102SC 0.01-4% 227S 1-20 105SD 1-20 105SC 5-130 105SC 10-260 105SB 50-900 105SA 0.5-10% 0.5-6% 1-20% 5-60% 8-150 5-150 0.3-5 50-500 6728411 CH20701 100-3000 8101811 CH23501 CH25101 CH20301 CH19701 6728511 0.5-10% 0.5-10 2-60 5-50 2-30 2-30 5-100 CH31901 8101841 8101231 6728071 6733231 6733231 8101941 Draeger Tube # Range* 7.4 Appendix 4. Equivalent Tubes of Other Manufacturers 5085-836 5085-822 5085-801 5086-812 803943 804423 803944 804133 5085-817 5085-841 5086-837 5086-814 813334 497606 487333 804419 5085-816 5085-814 5085-815 5086-835 5086-816 5085-845 804411 800300 804406 807024 804134 804405 0.25-15 50-1000 0.1-1.0% 2-30 0.5-7% 1-20% 100-3000 0.005-0.4% 5-100 20-1000 0.5-10% 1-25 4-55 10-500 MSA-AUER MSA # AUER # Range * 804141 5086-829 0.01-1% APPENDICES 115 Range* 0.5-25 100-2000 0.1-5 30-1000 50-1,000 1-20 1-20 20-500 2.5-60 0.5-20 0.2-3 0.2-3 1-7 2.5-60 0 - 150 10-120 25-250 50-800 100-2000 0.1-2% 2-40% 5-120 1-18 20- 300 1 - 20 Honeywell Tube # Diesel & Jet Fuel H-10-143-10 Ethanol H-10-141-30 Formaldehyde H-10-121-05 Gasoline H-10-138-30 Hydrocarbons H-10-110-30 Hydrogen Chloride H-10-108-09 H-10-108-10 H-10-108-22 Hydrogen Cyanide H-10-126-10 Hydrogen Fluoride H-10-105-10 Hydrogen Sulfide H-10-103-04 H-10-103-05 H-10-103-06 H-10-103-10 H-10-103-12 H-10-103-15 H-10-103-18 H-10-103-20 H-10-103-30 H-10-103-40 H-10-103-50 Mercaptans H-10-129-20 Methyl Bromide H-10-131-10 H-10-131-30 Nitric Acid H-10-146-20 * Units are ppmv unless noted. Compound 1-20 20-500 2.5-60 0.5-20 0.2-2 0.2-2 2.5-60 10-120 10-120 25-250 50-800 100-2000 0.1-2% 2-20% 5-120 1-18 20-300 1 - 20 4LL 4L 4L 4M 4HM 4H 4HH 4HT 70 136LA 136H 15L 100-2000 0.1-5 30-1000 200-3000 Range* Gastec 14L 14M 12L 17 4LT 4LT 112L 91L 101L 105 Tube # 5-60 10-200 10-200 5-1600 100-2000 0.2-7% 2-40% 5-140 1-10 10-500 2-20 120SC 120SA 120SH 120UH 164SA 157SC 157SA 233S 2-20 20-600 2-100 1-30 0.2-3 0.2-3 20-1000 0.1-4 500-6000 50-1400 Range* 120SD 120SB 120SB 173SB 173SA 112B 156S 120UP 120U 119U 171SC 110S 187S Tube # Kitagawa CH29101 CH28101 8101211 8101871 8101671 CH27301 6728311 CH29501 6728181 CH25701 CH30301 8101991 8101991 8101991 CH29801 6719001 6719001 6728821 CH29701 6733081 Tube # 100-2000 0.1-4.0% 2-20% 20-100 0.5-5 5-50 1-50 1-10 50-500 2-30 1.5-15 0.2-6 0.2-6 0.2-6 2-60 3-150 3-150 20-200 100-3000 0.5-5 Range* Draeger 5085-827 5086-815 5086-845 487340 804589 710391 5085-826 5085-826 5085-826 5085-824 5086-830 803945 804142 487339 487339 487339 5085-846 5086-818 5086-813 5085-898 2-100 10-80 100-4000 10-200 10-200 10-200 5-50 5-50 1-30 100-3000 1-10 30-600 AUER # Range * MSA-AUER 803948 804136 497649 492870 MSA # Appendix 4 (Continued). Equivalent Tubes of Other Manufacturers APPENDICES www.honeywellanalytics.com 116 www.honeywellanalytics.com 7J 6L H-10-120-30 0.05-1 mg/L 10-200 123 132SC 134SA 124SA 10-250 0.05-1 mg/L 143S 177U 6-40 lbs/MMCF 177UL 2-10 lbs/MMCF 177UR 1-20 5-100 10-300 Feb-50 10-400 1-60 8101321 6728531 8101721 6728541 8101701 6733161 5-1000 0.1-1 mg/L 6.4-128 lbs/ MMCF‡ 5-30 20-250 10-500 0.1-3.0% 200-3000 CH24201 20-300 6728491 0.1-2 mg/L 8101321 MMCF 3-80 lbs/ MMCF 2-12 lbs/ 0.4-12 5-150 50-400 5-90 1-20 CH21201 50-1000 8101801 8101641 0.05-0.7 CH31001 1.0-50 6733181 400-8000 8101531 20-200 1-25 40-1400 20-700 10-100 0.5-25 0.05-1 * Units are ppmv unless noted. ‡Actual scale on tubes is in mg/L, but is converted here to lbs/MMCF for ease of comparison. H-10-112-20 6LP H-10-120-20 6-40 lbs/MMCF Xylenes 6LLP H-10-120-10 2-10 lbs/MMCF Water Vapor 131La 132M H-10-128-10 1-20 5-100 H-10-119-20 Vinyl Chloride 122 Trichloroethylene 10-300 H-10-114-20 Toluene 103SB 103SC 103SD 121SC 121SC 121SB 183U 103SA 0.5-4% 100-1800 5-100 2-30 25-500 5-50 1-25 175U 182U H-10-107-40 0.2-5% 5H 5-200 0.05-0.6 Kitagawa Draeger Tube # Range* Tube # Range* 117SB 0.5-30 CH30001 0.5-10 H-10-107-30 200-4000 5M 50-1000 H-10-116-25 H-10-107-25 100-1800 25-500 H-10-116-20 7 60 5L 5-50 Phosphine H-10-107-20 5-100 H-10-139-05 1-25 H-10-116-10 Phenol 18L 10 5La H-10-133-03 0.05-0.6 Ozone Gastec Tube # Range* 9L 0.5-30 H-10-107-15 2-30 H-10-109-20 Jan-50 Nitrogen Oxides Sulfur Dioxide Honeywell Tube # Range* H-10-117-10 0.5-30 Compound Nitrogen Dioxide 488908 803950 487342 803947 497661 497662 487338 489119 485680 813778 804140 487341 5085-851 5085-837 5085-842 5085-828 5085-825 5085-813 5085-803 5085-831 5085-830 5086-838 5086-828 5085-805 1.4-9.1 lbs/MMCF‡ 5-70 20-250 5-1000 500-4000 5-120 1-25 50-2000 0.1-10 1-25 0.05-1 0.5-50 MSA-AUER MSA # AUER # Range * 487341 5085-805 0.5-50 Appendix 4 (Continued). Equivalent Tubes of Other Manufacturers APPENDICES To convert from the units on the left to the units on top, multiply by: To: From: Vol. % ppmv ppbv mg/m3 mg/L vol. % - 104 107 104(mw.P) MV 10 (mw.P) MV ppmv 10-4 - 103 (mw.P) MV 10-3(mw.P) MV ppbv 10-7 10-3 - 10-3(mw.P) MV 10-6(mw.P) MV mg/m3 10-4MV (mw.P) MV (mw.P) 103MV (mw.P) - 10-3 mg/L 0.1MV (mw.P) 103MV (mw.P) 106MV (mw.P) 103 - Key: P = pressure in atmospheres MV = molar volume of gas (for air, see table below) mw = molecular weight of compound in g/mole 1 Atmosphere Equivalents 1013 hPa 101.3 kPa 1.013 bar 1013 mbar 760 mm Hg 29.9 in. Hg 33.9 ft. H2O 14.7 psia Temp. (°C) Temp. (°F) Air Molar Volume (MV) -10 -5 0 5 10 15 20 25 30 35 40 45 50 14 23 32 41 50 59 68 77 86 95 104 113 122 21.59 22.00 22.41 22.82 23.23 23.64 24.05 24.46 24.87 25.28 25.69 26.10 26.51 www.honeywellanalytics.com 117 APPENDICES 7.5 Appendix 5. Conversion Factors for Gas Concentrations APPENDICES 7.6 Appendix 6. Humidity Conversion Tables Dew Pt. or Temp. °C °F -85 -80 -75 -70 -65 -60 -55 -50 -45 -40 -35 -30 -25 -20 -15 -10 -5 0 5 10 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 40 45 50 118 -121 -112 -103 -94 -85 -76 -67 -58 -49 -40 -31 -22 -13 -4 5 14 23 32 41 50 59 60.8 62.6 64.4 66.2 68 69.8 71.6 73.4 75.2 77 78.8 80.6 82.4 84.2 86 87.8 89.6 91.4 93.2 95 104 113 122 mg/L lbs/MMCF 0.0005 0.0011 0.0025 0.005 0.010 0.019 0.034 0.061 0.10 0.17 0.29 0.45 0.71 1.1 1.6 2.4 3.4 4.9 6.8 9.4 12.9 13.7 14.5 15.4 16.3 17.3 18.4 19.5 20.6 21.8 23.1 24.4 25.8 27.3 28.8 30.4 32.1 33.9 35.7 37.7 39.7 51.3 65.6 83.2 0.03 0.07 0.15 0.31 0.62 1.17 2.14 3.80 6.52 10.9 17.8 28.3 44.0 67.1 100 148 213 303 425 587 801 852 904 960 1019 1080 1145 1213 1285 1360 1439 1522 1609 1700 1796 1897 2002 2112 2227 2347 2474 3195 4088 5186 ppmv at 25°C 0.7 1.6 3.4 6.9 13.5 25.6 46.8 82.8 142 238 388 617 960 1464 2190 3218 4650 6615 9272 12816 17487 18581 19733 20947 22225 23569 24984 26471 28034 29677 31401 33211 35111 37103 39192 41381 43674 46075 48589 51219 53971 69707 89203 113153 www.honeywellanalytics.com %RH at 25°C 0.002% 0.005% 0.011% 0.02% 0.04% 0.08% 0.15% 0.26% 0.45% 0.76% 1.2% 2.0% 3.1% 4.7% 7.0% 10% 15% 21% 30% 41% 56% 59% 63% 67% 71% 75% 80% 84% 89% 95% 100% 106% 112% 118% 125% 132% 139% 147% 155% 163% 172% 222% 284% 360% %RH at 20°C 0.003% 0.007% 0.015% 0.031% 0.061% 0.12% 0.21% 0.37% 0.64% 1.1% 1.7% 2.8% 4.3% 6.6% 9.9% 14% 21% 30% 42% 58% 79% 84% 89% 94% 100% 106% 112% 119% 126% 134% 141% 149% 158% 167% 176% 186% 197% 207% 219% 230% 243% 314% 401% 509% 7.7 Appendix 7. Limited Product Warranty Honeywell's obligation under this warranty is limited to replacing or repairing, at Honeywell’s option, any defective or damaged part if returned to a Honeywell authorized factory repair center, with shipping charges prepaid by the buyer. To maintain warranty, Purchaser must perform maintenance and calibration as prescribed in the Operation and Maintenance manual. In the event of a defect or damage, Purchaser will notify a Honeywell designated factory repair center in advance and if trouble diagnosis procedures are unable to determine and remedy the condition, a Return Material Authorization (RMA) will be issued to assure proper repair and logistics tracking. Honeywell neither assumes nor authorizes any other firm or person to assume on Honeywell’s behalf any liability in any way connected with the sale of Honeywell products. Warranty does not extend to any equipment malfunction or damage that results from alteration, theft, misuse, abuse, abnormal use, or improper or unauthorized repairs. This express warranty shall extend to buyer of record only and not to sales made by buyer’s customers. Except for the warranty of title, the foregoing express warranty is in lieu of any and all other warranties, whether expressed or implied, including the implied warranties of fitness for a particular purpose and merchantability. Seller’s liability under the warranty provided herein exclusive of insurance process shall be limited to a refund of purchase price. www.honeywellanalytics.com 119 APPENDICES Honeywell warrants manual (hand-operated) pumps to be free of defects in workmanship for the life of use by the original owner. All other consumable items such as inlet filters, rubber inlets, plunger gaskets, which by their nature are consumed or depleted during normal operation, are excluded from this standard warranty. APPENDICES 7.8 Appendix 8. Honeywell Analytics Contacts North America and Latin America Honeywell Analytics 405 Barclay Blvd. Lincolnshire, IL USA 60069 Toll free: +1.888-749-8878 Fax: +1-817-274-8321 DetectGas@Honeywell.com Technical Support: +1-847-955-8200 Europe, Middle East, Africa and India Life Safety Distribution AG Javastrasse 2 8604 Hegnau Switzerland Tel: +41 (0)44 943 4300 Fax: +41 (0)44 943 4398 GasDetection@Honeywell.com Asia Pacific Customer Business Centre #701, Kolon Science Valley (1), 43 Digital-Ro Guro-Gu, Seoul, Korea Tel: +82-2-69090300 Fax: +82-2-69090329 Analytics.ap@honeywell.com 120 www.honeywellanalytics.com Notes ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ Honeywell Analytics Gas Detection Offerings Honeywell Analytics gas detectors protect people, assets and environment from toxic and combustible gas hazards, helping to create safer, more comfortable, secure and productive environments. Our strength derives from Honeywell’s leadership in sensor technology; in fact Honeywell operates four sensor manufacturing plants, supplying an entire industry with its core detective element. Portables Commercial Industrial High Tech/Government Single or multi-gas detectors ranging from compact, lightweight designs for personal protection to systems-based, networkable instrumentation for industrial hygiene. Renowned Sieger and Manning gas detection systems with advanced electrochemical, infrared and open path sensing technologies. Gas detection from standalone units to fully engineered, multi-point systems, all offering cost-effective regulatory compliance. Reliable gas and chemical detection including infrared spectroscopy (MST) with no cross interference, to Chemcassette paper-based solutions (MDA Scientific) offering detection down to parts per billion. Honeywell Analytics 405 Barclay Blvd. Lincolnshire, IL USA 60069 Toll free: +1 888 749 8878 Fax: +1 817 274 8321 DetectGas@honeywell.com www.honeywellanalytics.com H-010-4003-000 Rev: 03-2014 © 2014 Honeywell International Please Note: While every effort has been made to ensure accuracy in this publication, no responsibility can be accepted for errors or omissions. Data may change, as well as legislation, and you are strongly advised to obtain copies of the most recently issued regulations, standards, and guidelines. This publication is not intended to form the basis of a contract.
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