(\\\\dmzfile01\\Data\\HSE\\Clients\\ITW\\LPS\\atn\\sds_us\\default\\000730_D\222Gel\256 LPS Laboratories \(US SDS\)) 106927 MSD
2014-09-27
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SAFETY DATA SHEET 1. Identification Product identifier D’Gel® Other means of identification Part Number 61244 / 32 / 01 / 55 / 96 Recommended use Not available. Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Manufacturer Company name Address Country In Case of Emergency Website E-mail LPS Laboratories, a division of Illinois Tool Works, Inc. 4647 Hugh Howell Rd. Tucker, GA 30084 (U.S.A.) Tel: +1 770-243-8800 1-800-424-9300 (inside U.S.) +001 703-527-3887 (outside U.S.) www.lpslabs.com sds@lpslabs.com 2. Hazard(s) identification Physical hazards Flammable liquids Category 4 Health hazards Skin corrosion/irritation Category 2 Sensitization, skin Category 1 Aspiration hazard Category 1 OSHA defined hazards Not classified. Label elements Signal word Danger Hazard statement Combustible liquid. Causes skin irritation. May cause an allergic skin reaction. May be fatal if swallowed and enters airways. Precautionary statement Prevention Keep away from flames and hot surfaces-No smoking. Wear protective gloves/eye protection/face protection. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid breathing dust/fume/gas/mist/vapors/spray. Response IF SWALLOWED: Immediately call a POISON CENTER/doctor. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see this label). Take off contaminated clothing and wash before reuse. In case of fire: Use appropriate media to extinguish. Wash with plenty of soap and water. Storage Store in a well-ventilated place. Keep cool. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) Not classified. Supplemental information 0.25% of the mixture consists of component(s) of unknown acute hazards to the aquatic environment. 0.25% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment. 3. Composition/information on ingredients Mixtures Material name: D’Gel® 730 Version #: 01 Issue date: 08-21-2013 SDS US 1/7 Hazardous components Chemical name Common name and synonyms CAS number % Distillates Petroleum, Hydrotreated Light 64742-47-8 80 - < 90 d-limonene 5989-27-5 10 - < 20 577-11-7 1-<3 Sodium dioctyl sulfosuccinate Other components below reportable levels < 0.3 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention if irritation develops and persists. Eye contact Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Get medical attention if irritation develops and persists. Ingestion Call a physician or poison control center immediately. Only induce vomiting at the instruction of medical personnel. Never give anything by mouth to an unconscious person. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Most important symptoms/effects, acute and delayed Irritant effects. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Defatting of the skin. Rash. Symptoms of overexposure can include shortness of breath, drowsiness, headaches, confusion, decreased coordination, visual disturbances and vomiting, and are reversible if exposure is stopped. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. In case of shortness of breath, give oxygen. Keep victim under observation. Symptoms may be delayed. General information In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Alcohol resistant foam. Water fog. Dry chemical powder. Dry chemicals. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical By heating and fire, harmful vapors/gases may be formed. Special protective equipment and precautions for firefighters Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protective clothing will only provide limited protection. Fire-fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. Cool containers exposed to heat with water spray and remove container, if no risk is involved. Water runoff can cause environmental damage. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move container from fire area if it can be done without risk. In the event of fire and/or explosion do not breathe fumes. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate personal protective equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Avoid inhalation of vapors or mists. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. Use personal protection recommended in Section 8 of the SDS. Material name: D’Gel® 730 Version #: 01 Issue date: 08-21-2013 SDS US 2/7 Methods and materials for containment and cleaning up Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. This material is classified as a water pollutant under the Clean Water Act and should be prevented from contaminating soil or from entering sewage and drainage systems which lead to waterways. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Use water spray to reduce vapors or divert vapor cloud drift. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills in original containers for re-use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Keep away from open flames, hot surfaces and sources of ignition. When using do not smoke. Avoid breathing mist or vapor. Avoid contact with eyes. Avoid prolonged or repeated contact with skin. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Wash hands thoroughly after handling. Avoid release to the environment. Do not empty into drains. Conditions for safe storage, including any incompatibilities Keep away from heat and sources of ignition. Keep container tightly closed. Store in a cool, dry place out of direct sunlight. Store in a well-ventilated place. Keep in an area equipped with sprinklers. 8. Exposure controls/personal protection Occupational exposure limits US. NIOSH: Pocket Guide to Chemical Hazards Components Type Distillates Petroleum, Hydrotreated Light (CAS 64742-47-8) REL US. Workplace Environmental Exposure Level (WEEL) Guides Components Type d-limonene (CAS 5989-27-5) TWA Value 100 mg/m3 Value 165.5 mg/m3 30 ppm Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Eye wash fountain is recommended. Skin protection Hand protection Other Chemical resistant gloves are recommended. Avoid contact with clothing. Wear suitable protective clothing. Chemical resistant gloves. Respiratory protection No personal respiratory protective equipment normally required. Use a positive-pressure air-supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air-purifying respirators may not provide adequate protection. Thermal hazards Not applicable. General hygiene considerations When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Liquid. Physical state Liquid. Form Liquid. Color Clear water-white Odor Orange Material name: D’Gel® 730 Version #: 01 Issue date: 08-21-2013 SDS US 3/7 Odor threshold Not available. pH Not applicable Melting point/freezing point Not available. Initial boiling point and boiling range 379.4 °F (193 °C) @ 760mmHg Flash point 161.60 °F (72.00 °C) Tag Closed Cup Evaporation rate < 10 (BuAc = 100) Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower (%) 1.3 % Flammability limit - upper (%) 8.9 % Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure Not available. Vapor density > 1 (air = 1) Relative density Not available. Solubility(ies) Miscible at all proportions Partition coefficient (n-octanol/water) <1 Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity < 3 cSt @ 25°C Other information Percent volatile 97 % Specific gravity 0.78 - 0.8 @ 20 °C 10. Stability and reactivity Reactivity Strong oxidizing agents. Chemical stability Material is stable under normal conditions. Instability caused by elevated temperatures. Possibility of hazardous reactions Hazardous polymerization does not occur. Conditions to avoid Avoid temperatures exceeding the flash point. Heat, flames and sparks. Incompatible materials Strong oxidizing agents. Hazardous decomposition products Carbon oxides. 11. Toxicological information Information on likely routes of exposure Ingestion May be harmful if swallowed. Inhalation May cause irritation to the respiratory system. Skin contact Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Eye contact May be irritating to eyes. Symptoms related to the physical, chemical and toxicological characteristics Irritating to eyes, respiratory system and skin. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Information on toxicological effects Acute toxicity Based on available data, the classification criteria are not met. Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye irritation Based on available data, the classification criteria are not met. Respiratory sensitization Based on available data, the classification criteria are not met. Skin sensitization May cause sensitization by skin contact. Material name: D’Gel® 730 Version #: 01 Issue date: 08-21-2013 SDS US 4/7 Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity Based on available data, the classification criteria are not met. IARC Monographs. Overall Evaluation of Carcinogenicity d-limonene (CAS 5989-27-5) 3 Not classifiable as to carcinogenicity to humans. Reproductive toxicity Based on available data, the classification criteria are not met. Specific target organ toxicity single exposure Based on available data, the classification criteria are not met. Specific target organ toxicity repeated exposure Based on available data, the classification criteria are not met. Aspiration hazard May be fatal if swallowed and enters airways. Chronic effects Prolonged exposure may cause chronic effects. 12. Ecological information Ecotoxicity Ecological injuries are not known or expected under normal use. Persistence and degradability Not inherently biodegradable. Bioaccumulative potential No data available for this product. Partition coefficient n-octanol / water (log Kow) D’Gel® d-limonene <1 4.232 Mobility in soil Not available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT Not regulated as a hazardous material by DOT. IATA Not regulated as a dangerous good. IMDG Not regulated as a dangerous good. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code This substance/mixture is not intended to be transported in bulk. 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. SARA 304 Emergency release notification Not regulated. Material name: D’Gel® 730 Version #: 01 Issue date: 08-21-2013 SDS US 5/7 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance No SARA 311/312 Hazardous chemical No Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Not listed. Food and Drug Administration (FDA) Not regulated. US state regulations US. Massachusetts RTK - Substance List Not regulated. US. New Jersey Worker and Community Right-to-Know Act Not regulated. US. Pennsylvania RTK - Hazardous Substances Not regulated. US. Rhode Island RTK Not regulated. US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Australia Inventory name Australian Inventory of Chemical Substances (AICS) Canada Domestic Substances List (DSL) Canada Non-Domestic Substances List (NDSL) China Inventory of Existing Chemical Substances in China (IECSC) Europe European Inventory of Existing Commercial Chemical Substances (EINECS) On inventory (yes/no)* Yes Yes No Yes No Europe European List of Notified Chemical Substances (ELINCS) Japan Inventory of Existing and New Chemical Substances (ENCS) Yes No Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 08-21-2013 Version # 01 Further information Not available. NFPA ratings Health: 1 Flammability: 2 Instability: 0 Material name: D’Gel® 730 Version #: 01 Issue date: 08-21-2013 SDS US 6/7 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Material name: D’Gel® 730 Version #: 01 Issue date: 08-21-2013 SDS US 7/7
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