(\\\\dmzfile01\\Data\\HSE\\Clients\\ITW\\LPS\\atn\\sds_us\\default\\000730_D\222Gel\256 LPS Laboratories \(US SDS\)) 106927 MSD

2014-09-27

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SAFETY DATA SHEET
1. Identification
Product identifier D’Gel®
Other means of identification
Part Number 61244 / 32 / 01 / 55 / 96
Recommended use Not available.
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Manufacturer
Company name LPS Laboratories, a division of Illinois Tool Works, Inc.
Address 4647 Hugh Howell Rd.
Tucker, GA 30084
Country (U.S.A.)
Tel: +1 770-243-8800
In Case of Emergency 1-800-424-9300 (inside U.S.)
+001 703-527-3887 (outside U.S.)
Website
www.lpslabs.com
E-mail sds@lpslabs.com
2. Hazard(s) identification
Category 4Flammable liquids
Physical hazards
Category 2Skin corrosion/irritation
Health hazards
Category 1Sensitization, skin
Category 1Aspiration hazard
Not classified.
OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Combustible liquid. Causes skin irritation. May cause an allergic skin reaction. May be fatal if
swallowed and enters airways.
Precautionary statement
Prevention Keep away from flames and hot surfaces-No smoking. Wear protective gloves/eye protection/face
protection. Wash thoroughly after handling. Contaminated work clothing should not be allowed out
of the workplace. Avoid breathing dust/fume/gas/mist/vapors/spray.
Response IF SWALLOWED: Immediately call a POISON CENTER/doctor. Do NOT induce vomiting. IF ON
SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If
skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see this label).
Take off contaminated clothing and wash before reuse. In case of fire: Use appropriate media to
extinguish. Wash with plenty of soap and water.
Storage Store in a well-ventilated place. Keep cool. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Not classified.
Hazard(s) not otherwise
classified (HNOC)
Supplemental information
0.25% of the mixture consists of component(s) of unknown acute hazards to the aquatic environment. 0.25% of the mixture
consists of component(s) of unknown long-term hazards to the aquatic environment.
3. Composition/information on ingredients
Mixtures
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Material name: D’Gel®
730 Version #: 01 Issue date: 08-21-2013
SDS US
Hazardous components
CAS number %Chemical name Common name and synonyms
64742-47-8
Distillates Petroleum, Hydrotreated
Light
80 - < 90
5989-27-5
d-limonene 10 - < 20
577-11-7
Sodium dioctyl sulfosuccinate
Other components below reportable levels < 0.3
1 - < 3
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or
artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance.
Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other
proper respiratory medical device. Call a POISON CENTER or doctor/physician if you feel unwell.
Skin contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical attention if irritation develops and
persists.
Eye contact Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses.
Get medical attention if irritation develops and persists.
Ingestion Call a physician or poison control center immediately. Only induce vomiting at the instruction of
medical personnel. Never give anything by mouth to an unconscious person. If vomiting occurs,
keep head low so that stomach content doesn't get into the lungs.
Most important
symptoms/effects, acute and
delayed
Irritant effects. Symptoms may include stinging, tearing, redness, swelling, and blurred vision.
Defatting of the skin. Rash. Symptoms of overexposure can include shortness of breath,
drowsiness, headaches, confusion, decreased coordination, visual disturbances and vomiting, and
are reversible if exposure is stopped.
Indication of immediate
medical attention and special
treatment needed
Provide general supportive measures and treat symptomatically. In case of shortness of breath,
give oxygen. Keep victim under observation. Symptoms may be delayed.
General information In the case of accident or if you feel unwell, seek medical advice immediately (show the label
where possible). Ensure that medical personnel are aware of the material(s) involved, and take
precautions to protect themselves.
5. Fire-fighting measures
Suitable extinguishing media Alcohol resistant foam. Water fog. Dry chemical powder. Dry chemicals. Carbon dioxide (CO2).
Unsuitable extinguishing
media
Do not use water jet as an extinguisher, as this will spread the fire.
Specific hazards arising from
the chemical
By heating and fire, harmful vapors/gases may be formed.
Special protective equipment
and precautions for firefighters
Firefighters must use standard protective equipment including flame retardant coat, helmet with
face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protective
clothing will only provide limited protection.
Fire-fighting
equipment/instructions
Use standard firefighting procedures and consider the hazards of other involved materials. Move
containers from fire area if you can do so without risk. Cool containers exposed to heat with water
spray and remove container, if no risk is involved. Water runoff can cause environmental damage.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move
container from fire area if it can be done without risk. In the event of fire and/or explosion do not
breathe fumes.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).
Wear appropriate personal protective equipment. Do not touch damaged containers or spilled
material unless wearing appropriate protective clothing. Avoid inhalation of vapors or mists. Ensure
adequate ventilation. Local authorities should be advised if significant spillages cannot be
contained. Use personal protection recommended in Section 8 of the SDS.
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Material name: D’Gel®
730 Version #: 01 Issue date: 08-21-2013
SDS US
Methods and materials for
containment and cleaning up
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep
combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water.
This material is classified as a water pollutant under the Clean Water Act and should be prevented
from contaminating soil or from entering sewage and drainage systems which lead to waterways.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal. Use water spray to reduce vapors or divert vapor
cloud drift. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills in original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic
environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid
discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling Keep away from open flames, hot surfaces and sources of ignition. When using do not smoke.
Avoid breathing mist or vapor. Avoid contact with eyes. Avoid prolonged or repeated contact with
skin. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal
protective equipment. Observe good industrial hygiene practices. Wash hands thoroughly after
handling. Avoid release to the environment. Do not empty into drains.
Conditions for safe storage,
including any incompatibilities
Keep away from heat and sources of ignition. Keep container tightly closed. Store in a cool, dry
place out of direct sunlight. Store in a well-ventilated place. Keep in an area equipped with
sprinklers.
8. Exposure controls/personal protection
Occupational exposure limits
US. NIOSH: Pocket Guide to Chemical Hazards
ValueComponents Type
REL 100 mg/m3Distillate s Petroleum,
Hydrotreat ed Light (CAS
64742-47-8)
US. Workplace Environmental Exposure Level (WEEL) Guides
ValueComponents Type
TWA 165.5 mg/m3d-limonene (CAS
5989-27-5)
30 ppm
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering
controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles). Eye wash fountain is recommended.
Skin protection
Hand protection Chemical resistant gloves are recommended.
Other Avoid contact with clothing. Wear suitable protective clothing. Chemical resistant gloves.
Respiratory protection No personal respiratory protective equipment normally required. Use a positive-pressure
air-supplied respirator if there is any potential for an uncontrolled release, exposure levels are not
known, or any other circumstances where air-purifying respirators may not provide adequate
protection.
Thermal hazards Not applicable.
General hygiene
considerations
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such
as washing after handling the material and before eating, drinking, and/or smoking. Routinely
wash work clothing and protective equipment to remove contaminants.
9. Physical and chemical properties
Appearance Liquid.
Physical state Liquid.
Form Liquid.
Color Clear water-white
Odor Orange
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Material name: D’Gel®
730 Version #: 01 Issue date: 08-21-2013
SDS US
Odor threshold Not available.
pH Not applicable
Melting point/freezing point Not available.
Initial boiling point and boiling
range
379.4 °F (193 °C) @ 760mmHg
Flash point 161.60 °F (72.00 °C) Tag Closed Cup
Evaporation rate < 10 (BuAc = 100)
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
1.3 %
Flammability limit - upper
(%)
8.9 %
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure Not available.
Vapor density > 1 (air = 1)
Relative density Not available.
Solubility(ies) Miscible at all proportions
Partition coefficient
(n-octanol/water)
< 1
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity < 3 cSt @ 25°C
Other information
Percent volatile 97 %
Specific gravity 0.78 - 0.8 @ 20 °C
10. Stability and reactivity
Reactivity Strong oxidizing agents.
Chemical stability Material is stable under normal conditions. Instability caused by elevated temperatures.
Possibility of hazardous
reactions
Hazardous polymerization does not occur.
Conditions to avoid Avoid temperatures exceeding the flash point. Heat, flames and sparks.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition
products
Carbon oxides.
11. Toxicological information
Information on likely routes of exposure
Ingestion
May be harmful if swallowed.
Inhalation
May cause irritation to the respiratory system.
Skin contact
Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.
May be irritating to eyes.
Symptoms related to the
physical, chemical and
toxicological characteristics
Irritating to eyes, respiratory system and skin. Symptoms may include stinging, tearing, redness,
swelling, and blurred vision. Symptoms of overexposure may be headache, dizziness, tiredness,
nausea and vomiting.
Information on toxicological effects
Acute toxicity
Based on available data, the classification criteria are not met.
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye
irritation
Based on available data, the classification criteria are not met.
Respiratory sensitization
Based on available data, the classification criteria are not met.
Skin sensitization May cause sensitization by skin contact.
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Material name: D’Gel®
730 Version #: 01 Issue date: 08-21-2013
SDS US
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity
Based on available data, the classification criteria are not met.
IARC Monographs. Overall Evaluation of Carcinogenicity
d-limonene (CAS 5989-27-5) 3 Not classifiable as to carcinogenicity to humans.
Reproductive toxicity Based on available data, the classification criteria are not met.
Specific target organ toxicity -
single exposure
Based on available data, the classification criteria are not met.
Specific target organ toxicity -
repeated exposure
Based on available data, the classification criteria are not met.
Aspiration hazard
May be fatal if swallowed and enters airways.
Chronic effects Prolonged exposure may cause chronic effects.
12. Ecological information
Ecotoxicity Ecological injuries are not known or expected under normal use.
Persistence and degradability Not inherently biodegradable.
Bioaccumulative potential No data available for this product.
Partition coefficient n-octanol / water (log Kow)
D’Gel® < 1
d-limonene 4.232
Mobility in soil Not available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow
this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches
with chemical or used container. Dispose of contents/container in accordance with
local/regional/national/international regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused
products
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
14. Transport information
DOT
Not regulated as a hazardous material by DOT.
IATA
Not regulated as a dangerous good.
IMDG
Not regulated as a dangerous good.
Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
This substance/mixture is not intended to be transported in bulk.
15. Regulatory information
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
SARA 304 Emergency release notification
Not regulated.
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Material name: D’Gel®
730 Version #: 01 Issue date: 08-21-2013
SDS US
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely
hazardous substance
No
SARA 311/312 Hazardous
chemical
No
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
(SDWA)
Not regulated.
Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and
Chemical Code Number
Not listed.
Food and Drug
Administration (FDA)
Not regulated.
US state regulations
US. Massachusetts RTK - Substance List
Not regulated.
US. New Jersey Worker and Community Right-to-Know Act
Not regulated.
US. Pennsylvania RTK - Hazardous Substances
Not regulated.
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any
chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)
YesCanada Domestic Substances List (DSL)
NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)
NoEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)
NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)
YesKorea Existing Chemicals List (ECL)
YesNew Zealand New Zealand Inventory
YesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date 08-21-2013
Version # 01
Further information Not available.
NFPA ratings Health: 1
Flammability: 2
Instability: 0
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Material name: D’Gel®
730 Version #: 01 Issue date: 08-21-2013
SDS US
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
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Material name: D’Gel®
730 Version #: 01 Issue date: 08-21-2013
SDS US

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