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SAFETY DATA SHEET

352039

1. Product and Company Identification
Product identifier

Glisten Dishwasher Magic Machine Cleaner

Other means of identification

Not available

Recommended use

Dishwasher Cleaner and Disinfectant

Recommended restrictions

None known.

Manufacturer information

Iron Out dba Summit Brands
7201 Engle Road
Fort Wayne, IN 46804-5875 US
Phone: 260-483-2519
Emergency Phone: 1-800-424-9300 (CHEMTREC)

2. Hazards Identification
Physical hazards

Corrosive to metals

Category 1

Health hazards

Skin corrosion/irritation

Category 2

Serious eye damage/eye irritation

Category 2A

Environmental hazards

Not classified.

OSHA defined hazards

Not classified.

Label elements

Signal word

Warning

Hazard statement

May be corrosive to metals.
Causes skin irritation.
Causes serious eye irritation.

Precautionary statement
Prevention

Keep only in original container. Wash thoroughly after handling. Wear protective gloves. Wear
eye/face protection.

Response

Absorb spillage to prevent material damage.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
If on skin: Wash with plenty of water. If skin irritation occurs: Get medical advice/attention.
Specific treatment (see this label). Take off contaminated clothing and wash it before reuse.

Storage

Store in corrosive resistant container with a resistant inner liner.

Disposal

Dispose of waste and residues in accordance with local authority requirements.

Hazard(s) not otherwise
classified (HNOC)

None known.

Supplemental information

Not applicable.

3. Composition/Information on Ingredients
Mixture
Chemical name

Common name and synonyms

Citric Acid
Composition comments

CAS number

%

77-92-9

15 - 40

US GHS: The exact percentage (concentration) of composition has been withheld as a trade
secret in accordance with paragraph (i) of §1910.1200.

4. First Aid Measures
Inhalation

If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention.

Skin contact

If on skin: Wash with plenty of water. If skin irritation occurs: Get medical advice/attention. Take off
contaminated clothing and wash it before reuse. Specific treatment (see product label).
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Eye contact

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Issue date 06-September-2016

Ingestion
Most important
symptoms/effects, acute and
delayed

Rinse mouth. Do not induce vomiting. Get medical attention if symptoms occur. Never give
anything by mouth if victim is unconscious, or is convulsing. Obtain medical attention.
Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May
cause redness and pain.

Indication of immediate
medical attention and special
treatment needed

Provide general supportive measures and treat symptomatically. Keep victim under observation.
Symptoms may be delayed.

General information

Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. If you feel unwell, seek medical advice (show the label where possible). Show
this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of
reach of children.

5. Fire Fighting Measures
Suitable extinguishing media

Foam. Dry chemical. Carbon dioxide.

Unsuitable extinguishing
media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards arising from
the chemical

Firefighters should wear a self-contained breathing apparatus.

Special protective equipment
and precautions for firefighters

Firefighters should wear full protective clothing including self contained breathing apparatus.

Fire-fighting
equipment/instructions

Cool containers with flooding quantities of water until well after fire is out.

Specific methods

Use standard firefighting procedures and consider the hazards of other involved materials.

Hazardous combustion
products

May include and are not limited to: Oxides of carbon.

Explosion data
Sensitivity to mechanical
impact

Not available.

Sensitivity to static
discharge

Not available.

6. Accidental Release Measures
Personal precautions,
protective equipment and
emergency procedures

Methods and materials for
containment and cleaning up

Keep unnecessary personnel away. Keep out of low areas. Keep people away from and upwind of
spill/leak. Wear appropriate protective equipment and clothing during clean-up. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ensure
adequate ventilation. Local authorities should be advised if significant spillages cannot be
contained. For personal protection, see section 8 of the SDS.
Large Spills: Stop leak if you can do so without risk. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Absorb spillage to prevent material
damage. Absorb in vermiculite, dry sand or earth and place into containers. Use water spray to
reduce vapors or divert vapor cloud drift. Prevent entry into waterways, sewer, basements or
confined areas. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination. Never return spills to original containers for re-use.

Environmental precautions

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into
drains, water courses or onto the ground. Do not discharge into lakes, streams, ponds or public
waters.

7. Handling and Storage
Precautions for safe handling

Conditions for safe storage,
including any incompatibilities

Avoid prolonged exposure. Avoid contact with clothing. Provide adequate ventilation. Wear
appropriate personal protective equipment. Observe good industrial hygiene practices. Wash
thoroughly after handling. Use good industrial hygiene practices in handling this material. Avoid
contact with eyes and skin.
Store in corrosive resistant container with a resistant inner liner. Store in a closed container away
from incompatible materials. Keep only in the original container. Store in a cool, dry place out of
direct sunlight. Store away from incompatible materials (see Section 10 of the SDS). Keep out of
reach of children.

8. Exposure Controls/Personal Protection
Occupational exposure limits

No exposure limits noted for ingredient(s).

Biological limit values

No biological exposure limits noted for the ingredient(s).

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Issue date 06-September-2016

Appropriate engineering
controls

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Use
only under good ventilation conditions or with respiratory protection.

Individual protection measures, such as personal protective equipment
Safety goggles or glasses.
Eye/face protection
Skin protection
Hand protection

Rubber gloves. Confirm with a reputable supplier first.

Other

Wear appropriate chemical resistant clothing. As required by employer code.

Respiratory protection

Where exposure guideline levels may be exceeded, use an approved NIOSH respirator.

Thermal hazards

Not applicable.

General hygiene
considerations

Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Wash hands before breaks and immediately after handling
the product. Handle in accordance with good industrial hygiene and safety practice.

9. Physical and Chemical Properties
Appearance

Clear

Physical state

Liquid.

Form

Liquid

Color

Colorless

Odor

Citrus

Odor threshold

Not available.

pH

1.2 - 1.5

Melting point/freezing point

120 - 127 °F (48.89 - 52.78 °C) (wax plug)

Initial boiling point and boiling
range

Not available.

Pour point

Not available.

Specific gravity

1.109 - 1.121 g/ml

Partition coefficient
(n-octanol/water)

Not available.

Flash point

None

Evaporation rate

Not available.

Flammability (solid, gas)

Not applicable.

Upper/lower flammability or explosive limits
Flammability limit - lower
(%)

Not available.

Flammability limit - upper
(%)

Not available

Explosive limit - lower (%)

Not available.

Explosive limit - upper (%)

Not available.

Vapor pressure

Not available.

Vapor density

Not available.

Relative density

Not available.

Solubility(ies)

Not available.

Auto-ignition temperature

Not available.

Decomposition temperature

Not available.

Viscosity

2.117 centipoises

10. Stability and Reactivity
Reactivity

Reacts vigorously with alkaline material. This product may react with strong reducing agents.

Possibility of hazardous
reactions

Hazardous polymerization does not occur.

Chemical stability

Stable under recommended storage conditions.

Conditions to avoid

Reacts violently with strong alkaline substances. This product may react with reducing agents. Do
not mix with other chemicals.

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Issue date 06-September-2016

Incompatible materials
Hazardous decomposition
products

This product may react with reducing agents. Incompatible with bases. Caustics. Oxidizers.
Reducing agents.
May include and are not limited to: Oxides of carbon.

11. Toxicological Information
Routes of exposure

Eye, Skin contact, Ingestion.

Information on likely routes of exposure
Ingestion

Expected to be a low ingestion hazard.

Inhalation

No adverse effects due to inhalation are expected.

Skin contact

Causes skin irritation. This product is non-corrosive based on test data.

Eye contact

Causes serious eye irritation. This product is non-corrosive based on test data.

Symptoms related to the
physical, chemical and
toxicological characteristics

Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May
cause redness and pain.

Information on toxicological effects
Acute toxicity
Product

Species

Test Results

Glisten Dishwasher Magic Machine Cleaner (CAS Mixture)
Acute
Dermal
LD50

Rat

> 2000 mg/kg

Oral
LD50

Rat

> 5000 mg/kg

Species

Test Results

Components
Citric Acid (CAS 77-92-9)
Acute
Dermal
LD50

Not available

Inhalation
LC50

Not available

Oral
LD50

Mouse

5040 mg/kg

Rat

3000 mg/kg

Skin corrosion/irritation

Causes skin irritation.

Exposure minutes

Not available.

Erythema value

Not available.

Oedema value

Not available.

Serious eye damage/eye
irritation

Causes serious eye irritation. This product is non-corrosive based on test data.

Corneal opacity value

Not available.

Iris lesion value

Not available.

Conjunctival reddening
value

Not available.

Conjunctival oedema value

Not available.

Recover days

Not available.

Respiratory or skin sensitization
Respiratory sensitization

Not available.

Skin sensitization

This product is not expected to cause skin sensitization.

Germ cell mutagenicity

Non-hazardous by WHMIS/OSHA criteria.

Mutagenicity

Non-hazardous by WHMIS/OSHA criteria.

Carcinogenicity

Not classified or listed by IARC, NTP, OSHA and ACGIH.

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Non-hazardous by WHMIS/OSHA criteria.
Reproductive toxicity
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Issue date 06-September-2016

Teratogenicity

Non-hazardous by WHMIS/OSHA criteria.

Specific target organ toxicity single exposure

Not classified.

Specific target organ toxicity repeated exposure

Not classified.

Aspiration hazard

Not available.

Chronic effects

Non-hazardous by WHMIS/OSHA criteria.

Further information

Not available.

Name of Toxicologically
Synergistic Products

Not available.

12. Ecological Information
Ecotoxicity

Not available.

Persistence and degradability

No data is available on the degradability of this product.

Bioaccumulative potential

No data available.

Mobility in soil

No data available.

Mobility in general

Not available.

Other adverse effects

No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal Considerations
Disposal instructions

Local disposal regulations
Hazardous waste code
Waste from residues / unused
products
Contaminated packaging

Review federal, state/provincial, and local government requirements prior to disposal. Collect and
reclaim or dispose in sealed containers at licensed waste disposal site. This material and its
container must be disposed of as hazardous waste. Do not allow this material to drain into
sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used
container.
Dispose in accordance with all applicable regulations.
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.

14. Transport Information
Canada: TDG Proof of Classification: In accordance with Part 2.2.1 (SOR/2014-152) of the
Transportation of Dangerous Goods Regulations, we certify that the classification of this product
is correct as of the SDS date of issue. If applicable, the technical name and the classification of
the product will appear below.
U.S. Department of Transportation (DOT)
Basic shipping requirements:
UN3265
UN number
Corrosive liquid, acidic, organic, n.o.s.
Proper shipping name
Citric Acid
Technical name
Limited Quantity - US
Hazard class
III
Packing group
IB3, T7, TP1, TP28
Special provisions
Transportation of Dangerous Goods (TDG - Canada)
Basic shipping requirements:
UN3265
UN number
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Proper shipping name
Citric Acid
Technical name
Limited Quantity - Canada
Hazard class
III
Packing group
16
Special provisions
General

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Issue date 06-September-2016

DOT; TDG

15. Regulatory Information
Canadian federal regulations

This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations and the SDS contains all the information required by the Controlled Products
Regulations.

Canada WHMIS Ingredient Disclosure: Listed substance
Citric Acid (CAS 77-92-9)
Listed.
Export Control List (CEPA 1999, Schedule 3)
Not listed.
Greenhouse Gases
Not listed.
Precursor Control Regulations
Not regulated.
Exempt - Registered product - (DIN 02415569)
WHMIS classification
US federal regulations

This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
EPA Reg. # 9902-2
CAUTION: KEEP OUT OF THE REACH OF CHILDREN.
PRECAUTIONARY STATEMENTS: Hazardous to humans and domestic animals.
CAUTION: Harmful if absorbed through the skin. Causes moderate eye irritation. Avoid contact
with skin, eyes and clothing. Wash thoroughly with soap and water after handling and before
eating, drinking, chewing gum, using tobacco or using the toilet. DO NOT mix with chlorine bleach
or any other product as harmful fumes may result.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - Yes
Hazard categories
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
No
SARA 302 Extremely
hazardous substance
SARA 311/312 Hazardous
chemical

No

SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material
US state regulations
is not known to contain any chemicals currently listed as carcinogens or reproductive toxins.
US - Texas Effects Screening Levels: Listed substance
Citric Acid (CAS 77-92-9)
Listed.
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Issue date 06-September-2016

US. Massachusetts RTK - Substance List
Not regulated.
US. Pennsylvania RTK - Hazardous Substances
Not regulated.
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
Not Listed.
Inventory status
Country(s) or region
Canada

Inventory name
Domestic Substances List (DSL)

On inventory (yes/no)*
Yes

Canada

Non-Domestic Substances List (NDSL)

United States & Puerto Rico

Toxic Substances Control Act (TSCA) Inventory

No
Yes

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

16. Other Information
LEGEND

HEALTH

/

1

0
Severe
Serious
Moderate
Slight
Minimal

4
3
2
1
0

FLAMMABILITY

0

PHYSICAL HAZARD

0

PERSONAL
PROTECTION

X

1

0

Issue date

The data contained in this material safety data sheet was obtained from sources that were
technically accurate, reliable, and state of the art when this document was prepared. If data was
unavailable to complete certain sections, the absence of that data is identified in this document.
Because the supplier cannot know the exact circumstances during actual use of this product, other
hazards, exposure scenarios, disposal considerations, and regulations may apply and it is the
responsibility of the user to read and understand the product label and this document before use.
Do not use the product for purposes other than those stated in Section 1.
06-September-2016

Effective date

27-April-2015

Expiry date

27-April-2018

Further information
Prepared by

For an updated SDS, please contact the supplier/manufacturer listed on the first page of the
document.
Dell Tech Laboratories, Ltd. Phone: (519) 858-5021

Other information

Redbook revision # 14, 11/5/14

Disclaimer

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Issue date 06-September-2016



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