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2016-12-28
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SAFETY DATA SHEET
1. Product and Company Identification
Glisten Dishwasher Magic Machine CleanerProduct identifier
Not available
Other means of identification
Dishwasher Cleaner and Disinfectant
Recommended use
None known.
Recommended restrictions
Iron Out dba Summit Brands
7201 Engle Road
Fort Wayne, IN 46804-5875 US
Phone: 260-483-2519
Emergency Phone: 1-800-424-9300 (CHEMTREC)
Manufacturer information
2. Hazards Identification
Category 1Corrosive to metals
Physical hazards
Category 2Skin corrosion/irritation
Health hazards
Category 2ASerious eye damage/eye irritation
Not classified.
Environmental hazards
Not classified.
OSHA defined hazards
Label elements
Signal word Warning
Hazard statement May be corrosive to metals.
Causes skin irritation.
Causes serious eye irritation.
Precautionary statement
Prevention Keep only in original container. Wash thoroughly after handling. Wear protective gloves. Wear
eye/face protection.
Response Absorb spillage to prevent material damage.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
If on skin: Wash with plenty of water. If skin irritation occurs: Get medical advice/attention.
Specific treatment (see this label). Take off contaminated clothing and wash it before reuse.
Storage Store in corrosive resistant container with a resistant inner liner.
Disposal Dispose of waste and residues in accordance with local authority requirements.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information Not applicable.
3. Composition/Information on Ingredients
Mixture
CAS number %Common name and synonymsChemical name
77-92-9 15 - 40
Citric Acid
US GHS: The exact percentage (concentration) of composition has been withheld as a trade
secret in accordance with paragraph (i) of §1910.1200.
Composition comments
4. First Aid Measures
If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention.
Inhalation
If on skin: Wash with plenty of water. If skin irritation occurs: Get medical advice/attention. Take off
contaminated clothing and wash it before reuse. Specific treatment (see product label).
Skin contact
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Eye contact
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Rinse mouth. Do not induce vomiting. Get medical attention if symptoms occur. Never give
anything by mouth if victim is unconscious, or is convulsing. Obtain medical attention.
Ingestion
Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May
cause redness and pain.
Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically. Keep victim under observation.
Symptoms may be delayed.
Indication of immediate
medical attention and special
treatment needed
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. If you feel unwell, seek medical advice (show the label where possible). Show
this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of
reach of children.
General information
5. Fire Fighting Measures
Foam. Dry chemical. Carbon dioxide.
Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.
Unsuitable extinguishing
media
Firefighters should wear a self-contained breathing apparatus.
Specific hazards arising from
the chemical
Firefighters should wear full protective clothing including self contained breathing apparatus.
Special protective equipment
and precautions for firefighters
Cool containers with flooding quantities of water until well after fire is out.
Fire-fighting
equipment/instructions
Use standard firefighting procedures and consider the hazards of other involved materials.
Specific methods
May include and are not limited to: Oxides of carbon.
Hazardous combustion
products
Explosion data
Not available.
Sensitivity to mechanical
impact
Not available.
Sensitivity to static
discharge
6. Accidental Release Measures
Keep unnecessary personnel away. Keep out of low areas. Keep people away from and upwind of
spill/leak. Wear appropriate protective equipment and clothing during clean-up. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ensure
adequate ventilation. Local authorities should be advised if significant spillages cannot be
contained. For personal protection, see section 8 of the SDS.
Personal precautions,
protective equipment and
emergency procedures
Large Spills: Stop leak if you can do so without risk. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Absorb spillage to prevent material
damage. Absorb in vermiculite, dry sand or earth and place into containers. Use water spray to
reduce vapors or divert vapor cloud drift. Prevent entry into waterways, sewer, basements or
confined areas. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination. Never return spills to original containers for re-use.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Methods and materials for
containment and cleaning up
Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into
drains, water courses or onto the ground. Do not discharge into lakes, streams, ponds or public
waters.
Environmental precautions
7. Handling and Storage
Avoid prolonged exposure. Avoid contact with clothing. Provide adequate ventilation. Wear
appropriate personal protective equipment. Observe good industrial hygiene practices. Wash
thoroughly after handling. Use good industrial hygiene practices in handling this material. Avoid
contact with eyes and skin.
Precautions for safe handling
Store in corrosive resistant container with a resistant inner liner. Store in a closed container away
from incompatible materials. Keep only in the original container. Store in a cool, dry place out of
direct sunlight. Store away from incompatible materials (see Section 10 of the SDS). Keep out of
reach of children.
Conditions for safe storage,
including any incompatibilities
8. Exposure Controls/Personal Protection
No exposure limits noted for ingredient(s).
Occupational exposure limits
No biological exposure limits noted for the ingredient(s).
Biological limit values
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Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Use
only under good ventilation conditions or with respiratory protection.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Safety goggles or glasses.
Eye/face protection
Skin protection
Rubber gloves. Confirm with a reputable supplier first.
Hand protection
Wear appropriate chemical resistant clothing. As required by employer code.
Other
Where exposure guideline levels may be exceeded, use an approved NIOSH respirator.
Respiratory protection
Not applicable.
Thermal hazards
Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Wash hands before breaks and immediately after handling
the product. Handle in accordance with good industrial hygiene and safety practice.
General hygiene
considerations
9. Physical and Chemical Properties
Clear
Appearance
Liquid.
Physical state
Liquid
Form
Colorless
Color
Citrus
Odor
Odor threshold Not available.
pH 1.2 - 1.5
Melting point/freezing point 120 - 127 °F (48.89 - 52.78 °C) (wax plug)
Initial boiling point and boiling
range
Not available.
Pour point Not available.
Specific gravity 1.109 - 1.121 g/ml
Partition coefficient
(n-octanol/water)
Not available.
Flash point None
Evaporation rate Not available.
Not applicable.
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Not available.
Flammability limit - upper
(%)
Not available
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure Not available.
Vapor density Not available.
Relative density Not available.
Solubility(ies) Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity 2.117 centipoises
10. Stability and Reactivity
Reacts vigorously with alkaline material. This product may react with strong reducing agents.
Reactivity
Hazardous polymerization does not occur.
Possibility of hazardous
reactions
Stable under recommended storage conditions.
Chemical stability
Reacts violently with strong alkaline substances. This product may react with reducing agents. Do
not mix with other chemicals.
Conditions to avoid
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This product may react with reducing agents. Incompatible with bases. Caustics. Oxidizers.
Reducing agents.
Incompatible materials
May include and are not limited to: Oxides of carbon.
Hazardous decomposition
products
11. Toxicological Information
Routes of exposure Eye, Skin contact, Ingestion.
Information on likely routes of exposure
Ingestion Expected to be a low ingestion hazard.
Inhalation No adverse effects due to inhalation are expected.
Skin contact Causes skin irritation. This product is non-corrosive based on test data.
Eye contact Causes serious eye irritation. This product is non-corrosive based on test data.
Symptoms related to the
physical, chemical and
toxicological characteristics
Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May
cause redness and pain.
Information on toxicological effects
Acute toxicity
Test ResultsProduct Species
Glisten Dishwasher Magic Machine Cleaner (CAS Mixture)
LD50 Rat
Dermal
Acute
> 2000 mg/kg
LD50 Rat
Oral
> 5000 mg/kg
Test ResultsComponents Species
Citric Acid (CAS 77-92-9)
LD50 Not available
Dermal
Acute
LC50 Not available
Inhalation
LD50 Mouse
Oral
5040 mg/kg
Rat 3000 mg/kg
Causes skin irritation.
Skin corrosion/irritation
Exposure minutes Not available.
Erythema value Not available.
Oedema value Not available.
Causes serious eye irritation. This product is non-corrosive based on test data.
Serious eye damage/eye
irritation
Corneal opacity value Not available.
Iris lesion value Not available.
Conjunctival reddening
value
Not available.
Conjunctival oedema value Not available.
Recover days Not available.
Respiratory or skin sensitization
Respiratory sensitization Not available.
This product is not expected to cause skin sensitization.
Skin sensitization
Non-hazardous by WHMIS/OSHA criteria.
Germ cell mutagenicity
Non-hazardous by WHMIS/OSHA criteria.
Mutagenicity
Carcinogenicity Not classified or listed by IARC, NTP, OSHA and ACGIH.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Non-hazardous by WHMIS/OSHA criteria.
Reproductive toxicity
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Non-hazardous by WHMIS/OSHA criteria.
Teratogenicity
Specific target organ toxicity -
single exposure
Not classified.
Specific target organ toxicity -
repeated exposure
Not classified.
Aspiration hazard Not available.
Non-hazardous by WHMIS/OSHA criteria.
Chronic effects
Further information Not available.
Name of Toxicologically
Synergistic Products
Not available.
12. Ecological Information
Ecotoxicity Not available.
No data is available on the degradability of this product.
Persistence and degradability
No data available.
Bioaccumulative potential
No data available.
Mobility in soil
Not available.
Mobility in general
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal Considerations
Review federal, state/provincial, and local government requirements prior to disposal. Collect and
reclaim or dispose in sealed containers at licensed waste disposal site. This material and its
container must be disposed of as hazardous waste. Do not allow this material to drain into
sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used
container.
Disposal instructions
Dispose in accordance with all applicable regulations.
Local disposal regulations
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Hazardous waste code
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Waste from residues / unused
products
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
Contaminated packaging
14. Transport Information
Canada: TDG Proof of Classification: In accordance with Part 2.2.1 (SOR/2014-152) of the
Transportation of Dangerous Goods Regulations, we certify that the classification of this product
is correct as of the SDS date of issue. If applicable, the technical name and the classification of
the product will appear below.
General
U.S. Department of Transportation (DOT)
UN3265
UN number
Basic shipping requirements:
Corrosive liquid, acidic, organic, n.o.s.
Proper shipping name
Citric Acid
Technical name
Limited Quantity - US
Hazard class
III
Packing group
IB3, T7, TP1, TP28
Special provisions
Transportation of Dangerous Goods (TDG - Canada)
UN3265
UN number
Basic shipping requirements:
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Proper shipping name
Citric Acid
Technical name
Limited Quantity - Canada
Hazard class
III
Packing group
16
Special provisions
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DOT; TDG
15. Regulatory Information
This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations and the SDS contains all the information required by the Controlled Products
Regulations.
Canadian federal regulations
Canada WHMIS Ingredient Disclosure: Listed substance
Citric Acid (CAS 77-92-9) Listed.
Export Control List (CEPA 1999, Schedule 3)
Not listed.
Greenhouse Gases
Not listed.
Precursor Control Regulations
Not regulated.
Exempt - Registered product - (DIN 02415569)
WHMIS classification
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
EPA Reg. # 9902-2
CAUTION: KEEP OUT OF THE REACH OF CHILDREN.
PRECAUTIONARY STATEMENTS: Hazardous to humans and domestic animals.
CAUTION: Harmful if absorbed through the skin. Causes moderate eye irritation. Avoid contact
with skin, eyes and clothing. Wash thoroughly with soap and water after handling and before
eating, drinking, chewing gum, using tobacco or using the toilet. DO NOT mix with chlorine bleach
or any other product as harmful fumes may result.
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
Hazard categories
No
SARA 302 Extremely
hazardous substance
No
SARA 311/312 Hazardous
chemical
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material
is not known to contain any chemicals currently listed as carcinogens or reproductive toxins.
US state regulations
US - Texas Effects Screening Levels: Listed substance
Citric Acid (CAS 77-92-9) Listed.
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US. Massachusetts RTK - Substance List
Not regulated.
US. Pennsylvania RTK - Hazardous Substances
Not regulated.
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
Not Listed.
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
YesCanada Domestic Substances List (DSL)
NoCanada Non-Domestic Substances List (NDSL)
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
16. Other Information
0
0
1
1
0
X
HEALTH
FLAMMABILITY
PHYSICAL HAZARD
PERSONAL
PROTECTION
0
/
LEGEND
0
1
2
3
4Severe
Moderate
Slight
Minimal
Serious
The data contained in this material safety data sheet was obtained from sources that were
technically accurate, reliable, and state of the art when this document was prepared. If data was
unavailable to complete certain sections, the absence of that data is identified in this document.
Because the supplier cannot know the exact circumstances during actual use of this product, other
hazards, exposure scenarios, disposal considerations, and regulations may apply and it is the
responsibility of the user to read and understand the product label and this document before use.
Do not use the product for purposes other than those stated in Section 1.
Disclaimer
06-September-2016
Issue date
27-April-2015
Effective date
27-April-2018
Expiry date
For an updated SDS, please contact the supplier/manufacturer listed on the first page of the
document.
Further information
Dell Tech Laboratories, Ltd. Phone: (519) 858-5021
Prepared by
Redbook revision # 14, 11/5/14
Other information
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