454092
2016-12-16
: Pdf 454092 454092 msds
Open the PDF directly: View PDF 
.
Page Count: 11
| Download | |
| Open PDF In Browser | View PDF |
454092
Page:1/11
SAFETY DATA SHEET
FOR INDUSTRIAL USE ONLY
GE281
Section 1. Product and company identification
Product name
Chemical name
:
:
GE281
Not available
Manufacturer/Importer/
Distributor Information
:
Momentive Amer Seal.
260 Hudson River Road
Waterford NY 12188
Contact person
:
4information@momentive.com
Telephone
:
General information
+1-800-295-2392
Emergency telephone number
Supplier
:
CHEMTREC
1-800-424-9300
Section 2. Hazards identification
Classification of the substance or
mixture
:
SKIN SENSITIZATION - Category 1
TOXIC TO REPRODUCTION - Category 1B
TOXIC TO REPRODUCTION - Category 1B
GHS label elements
Hazard pictograms
:
Signal word
Hazard statements
:
:
Danger
H317 May cause an allergic skin reaction.
H360F May damage fertility.
H360 May damage the unborn child.
General
:
Not applicable.
Prevention
:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and
understood.
Use personal protective equipment as required.
Wear protective gloves.
Avoid breathing dust.
Contaminated work clothing should not be allowed out of the
workplace.
Precautionary statements
Version:
1.2
Date of issue/Date of revision:
04/10/2015
Date of previous issue:
03/19/2015
Page:2/11
GE 281
Response
:
IF exposed or concerned:
Get medical attention.
IF ON SKIN:
Wash with plenty of soap and water.
Wash contaminated clothing before reuse.
If skin irritation or rash occurs:
Get medical attention.
Storage
:
Store locked up.
Disposal
:
P501Dispose of contents and container in accordance with all local,
regional, national and international regulations.
:
Uncured product is irritating to eyes, skin, and respiratory tract.
Generates methanol during cure. Generates ammonia during cure.
Other hazards which do not
result in classification
Section 3. Composition/information on ingredients
Substance/mixture
Chemical name
:
:
Mixture
Not available
Hazardous ingredients
% by weight
Distillates (petroleum), hydrotreated middle
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)Tin, dibutylbis(2,4-pentanedionato-.kappa.O2,.kappa.O4)-,
(OC-6-11)-
5 - 10
1-5
0.1 - 1
CAS
number
64742-46-7
999-97-3
22673-19-4
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Section 4. First aid measures
Description of necessary first aid measures
Eye contact
:
Inhalation
:
Skin contact
:
Ingestion
:
Version:
1.2
Immediately flush eyes with plenty of water, occasionally lifting the
upper and lower eyelids. Check for and remove any contact lenses.
Continue to rinse for at least 10 minutes. Get medical attention if
irritation occurs.
Remove victim to fresh air and keep at rest in a position comfortable
for breathing. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel. It may be dangerous to the person providing aid
to give mouth-to-mouth resuscitation. Get medical attention. If
unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such
as a collar, tie, belt or waistband.
Wash with plenty of soap and water. Remove contaminated clothing
and shoes. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves. Continue to rinse for at least 10
minutes. Get medical attention. In the event of any complaints or
symptoms, avoid further exposure. Wash clothing before reuse.
Clean shoes thoroughly before reuse.
Wash out mouth with water. Remove dentures if any. Remove
victim to fresh air and keep at rest in a position comfortable for
breathing. If material has been swallowed and the exposed person is
Date of issue/Date of revision:
04/10/2015
Date of previous issue:
03/19/2015
Page:3/11
GE 281
conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If
vomiting occurs, the head should be kept low so that vomit does not
enter the lungs. Get medical attention. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician
:
Specific treatments
Protection of first aid personnel
:
:
In case of inhalation of decomposition products in a fire, symptoms
may be delayed. The exposed person may need to be kept under
medical surveillance for 48 hours.
No specific treatment.
No action shall be taken involving any personal risk or without
suitable training. If it is suspected that fumes are still present, the
rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give
mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Extinguishing media
Suitable extinguishing media
Unsuitable extinguishing media
:
:
Use dry chemical, CO2, alcohol-resistant foam or water spray (fog).
water jet
Specific hazards arising from the
chemical
Hazardous thermal
decomposition products
:
No specific fire or explosion hazard.
:
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
metal oxide/oxides
Measurements at temperatures above 150°C in presence of air
(oxygen) have shown that small amounts of formaldehyde are
formed due to oxidative degradation.
Special protective actions for firefighters
:
Special protective equipment for
fire-fighters
:
Promptly isolate the scene by removing all persons from the vicinity
of the incident if there is a fire. No action shall be taken involving
any personal risk or without suitable training. Use water spray to
keep fire-exposed containers cool. Fire water contaminated with this
material must be contained and prevented from being discharged to
any waterway, sewer or drain.
Fire-fighters should wear appropriate protective equipment and selfcontained breathing apparatus (SCBA) with a full face-piece
operated in positive pressure mode.
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Version:
1.2
:
No action shall be taken involving any personal risk or without
suitable training. Evacuate surrounding areas. Keep unnecessary
Date of issue/Date of revision:
04/10/2015
Date of previous issue:
03/19/2015
Page:4/11
GE 281
For emergency responders
Environmental precautions
:
:
and unprotected personnel from entering. Do not touch or walk
through spilled material. Provide adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Put on
appropriate personal protective equipment.
If specialised clothing is required to deal with the spillage, take note
of any information in Section 8 on suitable and unsuitable materials.
See also the information in "For non-emergency personnel".
Avoid dispersal of spilled material and runoff and contact with soil,
waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways,
soil or air).
Methods and material for containment and cleaning up
Small spill
:
Large spill
:
Move containers from spill area. Vacuum or sweep up material and
place in a designated, labeled waste container. Dispose of via a
licensed waste disposal contractor. Note: see section 1 of SDS for
emergency contact information and section 13 of SDS for waste
disposal.
Move containers from spill area. Approach release from upwind.
Prevent entry into sewers, water courses, basements or confined
areas. Vacuum or sweep up material and place in a designated,
labeled waste container. Dispose of via a licensed waste disposal
contractor. Note: see section 1 of SDS for emergency contact
information and section 13 of SDS for waste disposal.
Section 7. Handling and storage
Precautions for safe handling
Protective measures
:
Advice on general occupational
hygiene
:
Conditions for safe storage,
including any incompatibilities
:
Put on appropriate personal protective equipment (see section 8 of
SDS). Persons with a history of skin sensitization problems should
not be employed in any process in which this product is used. Avoid
exposure - obtain special instructions before use. Avoid exposure
during pregnancy. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing.
Do not ingest. Use only with adequate ventilation. Keep in the
original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Empty
containers retain product residue and can be hazardous.
Eating, drinking and smoking should be prohibited in areas where
this material is handled, stored and processed. Workers should wash
hands and face before eating, drinking and smoking. See also
Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in original
container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see section 10 of
SDS) and food and drink. Store locked up. Keep container tightly
closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent
leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination.
Section 8. Exposure controls/personal protection
Control parameters
Version:
1.2
Date of issue/Date of revision:
04/10/2015
Date of previous issue:
03/19/2015
Page:5/11
GE 281
Occupational exposure limits
None.
Appropriate engineering controls
:
Environmental exposure controls
:
If user operations generate dust, fumes, gas, vapor or mist, use
process enclosures, local exhaust ventilation or other engineering
controls to keep worker exposure to airborne contaminants below
any recommended or statutory limits.
Emissions from ventilation or work process equipment should be
checked to ensure they comply with the requirements of
environmental protection legislation. In some cases, fume scrubbers,
filters or engineering modifications to the process equipment will be
necessary to reduce emissions to acceptable levels.
Individual protection measures
Hygiene measures
:
Eye/face protection
:
Wash hands, forearms and face thoroughly after handling chemical
products, before eating, smoking and using the lavatory and at the
end of the working period. Appropriate techniques should be used to
remove potentially contaminated clothing. Contaminated work
clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations
and safety showers are close to the workstation location.
Safety eyewear complying with an approved standard should be
used when a risk assessment indicates this is necessary to avoid
exposure to liquid splashes, mists, gases or dusts.
Skin protection
Hand protection
:
Body protection
:
Other skin protection
:
Respiratory protection
:
Chemical-resistant, impervious gloves complying with an approved
standard should be worn at all times when handling chemical
products if a risk assessment indicates this is necessary. Considering
the parameters specified by the glove manufacturer, check during
use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material
may be different for different glove manufacturers. In the case of
mixtures, consisting of several substances, the protection time of the
gloves cannot be accurately estimated.
Personal protective equipment for the body should be selected based
on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Appropriate footwear and any additional skin protection measures
should be selected based on the task being performed and the risks
involved and should be approved by a specialist before handling this
product.
Use a properly fitted, particulate filter respirator complying with an
approved standard if a risk assessment indicates this is necessary.
Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working
limits of the selected respirator.
Section 9. Physical and chemical properties
Appearance
Physical state
Color
:
:
Solid
White
Odor
Odor threshold
:
:
ammonia
Not available
Version:
1.2
Date of issue/Date of revision:
04/10/2015
Date of previous issue:
03/19/2015
Page:6/11
GE 281
pH
:
Not applicable.
Melting point
Boiling point
Flash point
:
:
:
Not available
Not available
93.3 °C (199.94 °F) (Estimated.)
Burning time
Burning rate
Evaporation rate
Flammability (solid, gas)
Lower and upper explosive
(flammable) limits
Vapor pressure
:
:
:
:
:
:
Not available
Not available
Not available
Not available
Lower: Not available
Upper: Not available
Not applicable.
Vapor density
Relative density
:
:
Not available
1.02
Solubility
:
PARTIAL IN TOLUENE
Solubility in water
:
Insoluble
Partition coefficient: noctanol/water
Auto-ignition temperature
Decomposition temperature
SADT
Viscosity
:
Not available
:
:
:
:
Volatile organic content
:
Not available
Not available
Not available
Dynamic: Not available
Kinematic: Not available
2.2 % (w/w)
27 g/l
Other information
No additional information.
Section 10. Stability and reactivity
Reactivity
:
Stable under normal conditions.
Chemical stability
:
The product is stable.
Possibility of hazardous reactions
:
Under normal conditions of storage and use, hazardous reactions
will not occur.
Conditions to avoid
:
No specific data.
Incompatible materials
:
No specific data.
Hazardous decomposition
products
:
Under normal conditions of storage and use, hazardous
decomposition products should not be produced.
Section 11. Toxicological information
Information on toxicological effects
Acute toxicity
Product/ingredient name Result
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)Version:
1.2
Species
Date of issue/Date of revision:
04/10/2015
Dose
Exposure
Date of previous issue:
03/19/2015
Page:7/11
GE 281
Conclusion/Summary
LD50 Oral
LC50
Inhalation
:
Rat
Rat
850 mg/kg
9 mg/l
4h
Not determined
Irritation/Corrosion
Product/ingredient name
Silanamine, 1,1,1-trimethyl-N(trimethylsilyl)Conclusion/Summary
Skin
eyes
Respiratory
Result
Skin Severe
irritant
Species
Rabbit
:
:
:
Not determined
Not determined
Not determined
:
:
Not determined
Not determined
:
Not determined
:
Not determined
:
Not determined
:
Not determined
Score
Exposure
Observation
-
Sensitization
Conclusion/Summary
Skin
Respiratory
Mutagenicity
Conclusion/Summary
Carcinogenicity
Conclusion/Summary
Reproductive toxicity
Conclusion/Summary
Teratogenicity
Conclusion/Summary
Specific target organ toxicity (single exposure)
Product/ingredient name
Category
Tin, dibutylbis(2,4Category 1
pentanedionato.kappa.O2,.kappa.O4)-, (OC-611)Specific target organ toxicity (repeated exposure)
Product/ingredient name
Category
Tin, dibutylbis(2,4Category 1
pentanedionato.kappa.O2,.kappa.O4)-, (OC-611)Aspiration hazard
Product/ingredient name
Distillates (petroleum), hydrotreated middle
Information on the likely routes of
Version:
1.2
:
Route of exposure
Target organs
thymus
Route of exposure
Target organs
thymus
Result
ASPIRATION HAZARD - Category 1ASPIRATION
HAZARD - Category 1ASPIRATION HAZARD Category 1
Not available
Date of issue/Date of revision:
04/10/2015
Date of previous issue:
03/19/2015
Page:8/11
GE 281
exposure
Potential acute health effects
Eye contact
Inhalation
:
:
Skin contact
Ingestion
:
:
No known significant effects or critical hazards.
Exposure to decomposition products may cause a health hazard.
Serious effects may be delayed following exposure.
May cause an allergic skin reaction.
No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact
Inhalation
:
:
Skin contact
:
Ingestion
:
No specific data.
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
:
:
Not available
Not available
:
:
Not available
Not available
Conclusion/Summary
:
Not determined
General
:
Carcinogenicity
Mutagenicity
Teratogenicity
Developmental effects
Fertility effects
:
:
:
:
:
Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
May damage the unborn child.
No known significant effects or critical hazards.
May damage fertility.
Potential immediate effects
Potential delayed effects
Long term exposure
Potential immediate effects
Potential delayed effects
Potential chronic health effects
Numerical measures of toxicity
Acute toxicity estimates
Not available
Version:
1.2
Date of issue/Date of revision:
04/10/2015
Date of previous issue:
03/19/2015
Page:9/11
GE 281
Section 12. Ecological information
Ecotoxicity
Conclusion/Summary
:
Not available
:
Not available
Persistence/degradability
Conclusion/Summary
Bioaccumulative potential
Product/ingredient name
Silanamine, 1,1,1-trimethyl-N(trimethylsilyl)-
Species
Exposure
LogPow
1.19
BCF
-
Potential
low
Mobility in soil
Soil/water partition coefficient
(KOC)
Other adverse effects
:
Not available
:
No known significant effects or critical hazards.
Section 13. Disposal considerations
Disposal methods
:
The generation of waste should be avoided or minimized wherever
possible. Disposal of this product, solutions and any by-products
should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local
authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not
be disposed of untreated to the sewer unless fully compliant with
the requirements of all authorities with jurisdiction. Waste
packaging should be recycled. Incineration or landfill should only
be considered when recycling is not feasible. This material and its
container must be disposed of in a safe way. Care should be taken
when handling emptied containers that have not been cleaned or
rinsed out. Empty containers or liners may retain some product
residues. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
Section 14. Transport information
Special precautions for user
Version:
1.2
:
This product is not regarded as dangerous goods according to the
national and international regulations on the transport of dangerous
goods.
Date of issue/Date of revision:
04/10/2015
Date of previous issue:
03/19/2015
Page:10/11
GE 281
15.Regulatory information
United States
U.S. Federal regulations
:
United States - TSCA 12(b) - Chemical export notification: None
required.
United States - TSCA 5(a)2 - Final significant new use rules: Not
listed
United States - TSCA 5(a)2 - Proposed significant new use rules:
Not listed
United States - TSCA 5(e) - Substances consent order: Not listed
SARA 311/312
Classification
:
California Prop. 65:
Immediate (acute) health hazard
Delayed (chronic) health hazard
:
WARNING: This product contains a chemical known to the State of
California to cause cancer., WARNING: This product contains less than
1% of a chemical known to the State of California to cause birth defects
or other reproductive harm.
:
Class D-2A: Material causing other toxic effects (Very toxic).
Class D-2B: Material causing other toxic effects (Toxic).
Canada
WHMIS (Canada)
International regulations
International lists
: Australia inventory (AICS): All components are listed or exempted.
Canada inventory: All components are listed or exempted.
Japan inventory: Not determined.
China inventory (IECSC): All components are listed or exempted.
Korea inventory: All components are listed or exempted.
New Zealand Inventory (NZIoC): All components are listed or exempted.
Philippines inventory (PICCS): All components are listed or exempted.
United States inventory (TSCA 8b): All components are listed or exempted.
Taiwan inventory (CSNN): All components are listed or exempted.
Section 16. Other information
Hazardous Material Information System III (U.S.A.) :
2
Health
1
Flammability
0
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks,
and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs
under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a
fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings
Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Full text of abbreviated H
Version:
1.2
:
Not applicable.
Date of issue/Date of revision:
04/10/2015
Date of previous issue:
03/19/2015
Page:11/11
GE 281
statements
History
Date of printing
Date of issue/Date of revision
Date of previous issue
Version
Prepared by
Key to abbreviations
:
:
:
:
:
:
References
:
05/28/2015
04/10/2015
03/19/2015
1.2
Product Safety Stewardship
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From
Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
RID = The Regulations concerning the International Carriage of Dangerous Goods
by Rail
UN = United Nations
Not available
Notice to reader
Unless otherwise specified in section 1, Momentive Products are intended for industrial application only. They
are not intended for specific medical applications, neither for long-lasting (> 30 days) implantation into the
human body, injected or directly ingested, nor for the manufacture of multiple usable contraceptives
Keep out of the reach of children.
Further Information
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and
belief at the date of its publication. The information given is designed only as a guidance for safe handling, use,
processing, storage, transportation, disposal and release and is not to be considered a warranty or quality
specification. The information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process, unless specified in the text.
Version:
1.2
Date of issue/Date of revision:
04/10/2015
Date of previous issue:
03/19/2015
Source Exif Data:
File Type : PDF File Type Extension : pdf MIME Type : application/pdf PDF Version : 1.5 Linearized : No Author : Pugh, Marc Comments : Company : Momentive Create Date : 2015:05:29 09:42:18-06:00 Modify Date : 2016:05:04 10:39:17-04:00 Momentive EDP Classification : Unclassified Source Modified : D:20150528191448 Subject : Titus GUID : cd4a30cf-5017-4b73-9e19-39b53c9cbe16 Word Version Generation : 14.0.4762.1000 Wwires 32 : 2005,110,130,378 Tagged PDF : Yes XMP Toolkit : Adobe XMP Core 5.6-c015 81.157285, 2014/12/12-00:43:15 Metadata Date : 2016:05:04 10:39:17-04:00 Creator Tool : Acrobat PDFMaker 10.1 for Word Document ID : uuid:786b05b1-864d-48d0-91e0-f0cd00a620b0 Instance ID : uuid:3cf81d7c-361d-4751-bec3-7a3961f7cfd1 Format : application/pdf Title : Description : Creator : Pugh, Marc Producer : Adobe PDF Library 10.0 Keywords : Word 0020 Version 00200028 Generation 0029: 14.0.4762.1000 Page Layout : OneColumn Page Count : 11EXIF Metadata provided by EXIF.tools