454092

2016-12-16

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Version:
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Date of previous issue:
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SAFETY DATA SHEET
FOR INDUSTRIAL USE ONLY
GE281
Product name
:
GE281
Chemical name
:
Not available
Manufacturer/Importer/
Distributor Information
:
Momentive Amer Seal.
260 Hudson River Road
Waterford NY 12188
Contact person
:
4information@momentive.com
Telephone
:
General information
+1-800-295-2392
Emergency telephone number
Supplier
:
CHEMTREC
1-800-424-9300
Classification of the substance or
mixture
:
SKIN SENSITIZATION - Category 1
TOXIC TO REPRODUCTION - Category 1B
TOXIC TO REPRODUCTION - Category 1B
GHS label elements
Hazard pictograms
:
Signal word
:
Danger
Hazard statements
:
H317 May cause an allergic skin reaction.
H360F May damage fertility.
H360 May damage the unborn child.
Precautionary statements
General
:
Not applicable.
Prevention
:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and
understood.
Use personal protective equipment as required.
Wear protective gloves.
Avoid breathing dust.
Contaminated work clothing should not be allowed out of the
workplace.
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Response
:
IF exposed or concerned:
Get medical attention.
IF ON SKIN:
Wash with plenty of soap and water.
Wash contaminated clothing before reuse.
If skin irritation or rash occurs:
Get medical attention.
Storage
:
Store locked up.
Disposal
:
P501Dispose of contents and container in accordance with all local,
regional, national and international regulations.
Other hazards which do not
result in classification
:
Uncured product is irritating to eyes, skin, and respiratory tract.
Generates methanol during cure. Generates ammonia during cure.
Substance/mixture
:
Mixture
Chemical name
:
Not available
Hazardous ingredients
% by weight
CAS
number
Distillates (petroleum), hydrotreated middle
5 - 10
64742-46-7
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-
1 - 5
999-97-3
Tin, dibutylbis(2,4-pentanedionato-.kappa.O2,.kappa.O4)-,
(OC-6-11)-
0.1 - 1
22673-19-4
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Description of necessary first aid measures
Eye contact
:
Immediately flush eyes with plenty of water, occasionally lifting the
upper and lower eyelids. Check for and remove any contact lenses.
Continue to rinse for at least 10 minutes. Get medical attention if
irritation occurs.
Inhalation
:
Remove victim to fresh air and keep at rest in a position comfortable
for breathing. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel. It may be dangerous to the person providing aid
to give mouth-to-mouth resuscitation. Get medical attention. If
unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such
as a collar, tie, belt or waistband.
Skin contact
:
Wash with plenty of soap and water. Remove contaminated clothing
and shoes. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves. Continue to rinse for at least 10
minutes. Get medical attention. In the event of any complaints or
symptoms, avoid further exposure. Wash clothing before reuse.
Clean shoes thoroughly before reuse.
Ingestion
:
Wash out mouth with water. Remove dentures if any. Remove
victim to fresh air and keep at rest in a position comfortable for
breathing. If material has been swallowed and the exposed person is
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conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If
vomiting occurs, the head should be kept low so that vomit does not
enter the lungs. Get medical attention. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician
:
In case of inhalation of decomposition products in a fire, symptoms
may be delayed. The exposed person may need to be kept under
medical surveillance for 48 hours.
Specific treatments
:
No specific treatment.
Protection of first aid personnel
:
No action shall be taken involving any personal risk or without
suitable training. If it is suspected that fumes are still present, the
rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give
mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.
See toxicological information (Section 11)
Extinguishing media
Suitable extinguishing media
:
Use dry chemical, CO2, alcohol-resistant foam or water spray (fog).
Unsuitable extinguishing media
:
water jet
Specific hazards arising from the
chemical
:
No specific fire or explosion hazard.
Hazardous thermal
decomposition products
:
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
metal oxide/oxides
Measurements at temperatures above 150°C in presence of air
(oxygen) have shown that small amounts of formaldehyde are
formed due to oxidative degradation.
Special protective actions for fire-
fighters
:
Promptly isolate the scene by removing all persons from the vicinity
of the incident if there is a fire. No action shall be taken involving
any personal risk or without suitable training. Use water spray to
keep fire-exposed containers cool. Fire water contaminated with this
material must be contained and prevented from being discharged to
any waterway, sewer or drain.
Special protective equipment for
fire-fighters
:
Fire-fighters should wear appropriate protective equipment and self-
contained breathing apparatus (SCBA) with a full face-piece
operated in positive pressure mode.
Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
:
No action shall be taken involving any personal risk or without
suitable training. Evacuate surrounding areas. Keep unnecessary
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and unprotected personnel from entering. Do not touch or walk
through spilled material. Provide adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Put on
appropriate personal protective equipment.
For emergency responders
:
If specialised clothing is required to deal with the spillage, take note
of any information in Section 8 on suitable and unsuitable materials.
See also the information in "For non-emergency personnel".
Environmental precautions
:
Avoid dispersal of spilled material and runoff and contact with soil,
waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways,
soil or air).
Methods and material for containment and cleaning up
Small spill
:
Move containers from spill area. Vacuum or sweep up material and
place in a designated, labeled waste container. Dispose of via a
licensed waste disposal contractor. Note: see section 1 of SDS for
emergency contact information and section 13 of SDS for waste
disposal.
Large spill
:
Move containers from spill area. Approach release from upwind.
Prevent entry into sewers, water courses, basements or confined
areas. Vacuum or sweep up material and place in a designated,
labeled waste container. Dispose of via a licensed waste disposal
contractor. Note: see section 1 of SDS for emergency contact
information and section 13 of SDS for waste disposal.
Precautions for safe handling
Protective measures
:
Put on appropriate personal protective equipment (see section 8 of
SDS). Persons with a history of skin sensitization problems should
not be employed in any process in which this product is used. Avoid
exposure - obtain special instructions before use. Avoid exposure
during pregnancy. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing.
Do not ingest. Use only with adequate ventilation. Keep in the
original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Empty
containers retain product residue and can be hazardous.
Advice on general occupational
hygiene
:
Eating, drinking and smoking should be prohibited in areas where
this material is handled, stored and processed. Workers should wash
hands and face before eating, drinking and smoking. See also
Section 8 for additional information on hygiene measures.
Conditions for safe storage,
including any incompatibilities
:
Store in accordance with local regulations. Store in original
container protected from direct sunlight in a dry, cool and well-
ventilated area, away from incompatible materials (see section 10 of
SDS) and food and drink. Store locked up. Keep container tightly
closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent
leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination.
Control parameters
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Occupational exposure limits
None.
Appropriate engineering controls
:
If user operations generate dust, fumes, gas, vapor or mist, use
process enclosures, local exhaust ventilation or other engineering
controls to keep worker exposure to airborne contaminants below
any recommended or statutory limits.
Environmental exposure controls
:
Emissions from ventilation or work process equipment should be
checked to ensure they comply with the requirements of
environmental protection legislation. In some cases, fume scrubbers,
filters or engineering modifications to the process equipment will be
necessary to reduce emissions to acceptable levels.
Individual protection measures
Hygiene measures
:
Wash hands, forearms and face thoroughly after handling chemical
products, before eating, smoking and using the lavatory and at the
end of the working period. Appropriate techniques should be used to
remove potentially contaminated clothing. Contaminated work
clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations
and safety showers are close to the workstation location.
Eye/face protection
:
Safety eyewear complying with an approved standard should be
used when a risk assessment indicates this is necessary to avoid
exposure to liquid splashes, mists, gases or dusts.
Skin protection
Hand protection
:
Chemical-resistant, impervious gloves complying with an approved
standard should be worn at all times when handling chemical
products if a risk assessment indicates this is necessary. Considering
the parameters specified by the glove manufacturer, check during
use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material
may be different for different glove manufacturers. In the case of
mixtures, consisting of several substances, the protection time of the
gloves cannot be accurately estimated.
Body protection
:
Personal protective equipment for the body should be selected based
on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Other skin protection
:
Appropriate footwear and any additional skin protection measures
should be selected based on the task being performed and the risks
involved and should be approved by a specialist before handling this
product.
Respiratory protection
:
Use a properly fitted, particulate filter respirator complying with an
approved standard if a risk assessment indicates this is necessary.
Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working
limits of the selected respirator.
Appearance
Physical state
:
Solid
Color
:
White
Odor
:
ammonia
Odor threshold
:
Not available
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pH
:
Not applicable.
Melting point
:
Not available
Boiling point
:
Not available
Flash point
:
93.3 °C (199.94 °F) (Estimated.)
Burning time
:
Not available
Burning rate
:
Not available
Evaporation rate
:
Not available
Flammability (solid, gas)
:
Not available
Lower and upper explosive
(flammable) limits
:
Lower: Not available
Upper: Not available
Vapor pressure
:
Not applicable.
Vapor density
:
Not available
Relative density
:
1.02
Solubility
:
PARTIAL IN TOLUENE
Solubility in water
:
Insoluble
Partition coefficient: n-
octanol/water
:
Not available
Auto-ignition temperature
:
Not available
Decomposition temperature
:
Not available
SADT
:
Not available
Viscosity
:
Dynamic: Not available
Kinematic: Not available
Volatile organic content
:
2.2 % (w/w)
27 g/l
Other information
No additional information.
Reactivity
:
Stable under normal conditions.
Chemical stability
:
The product is stable.
Possibility of hazardous reactions
:
Under normal conditions of storage and use, hazardous reactions
will not occur.
Conditions to avoid
:
No specific data.
Incompatible materials
:
No specific data.
Hazardous decomposition
products
:
Under normal conditions of storage and use, hazardous
decomposition products should not be produced.
Information on toxicological effects
Acute toxicity
Product/ingredient name
Result
Species
Dose
Exposure
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-
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LD50 Oral
Rat
850 mg/kg
-
LC50
Inhalation
Rat
9 mg/l
4 h
Conclusion/Summary
:
Not determined
Irritation/Corrosion
Product/ingredient name
Result
Species
Score
Exposure
Observation
Silanamine, 1,1,1-trimethyl-N-
(trimethylsilyl)-
Skin -
Severe
irritant
Rabbit
-
Conclusion/Summary
Skin
:
Not determined
eyes
:
Not determined
Respiratory
:
Not determined
Sensitization
Conclusion/Summary
Skin
:
Not determined
Respiratory
:
Not determined
Mutagenicity
Conclusion/Summary
:
Not determined
Carcinogenicity
Conclusion/Summary
:
Not determined
Reproductive toxicity
Conclusion/Summary
:
Not determined
Teratogenicity
Conclusion/Summary
:
Not determined
Specific target organ toxicity (single exposure)
Product/ingredient name
Category
Route of exposure
Target organs
Tin, dibutylbis(2,4-
pentanedionato-
.kappa.O2,.kappa.O4)-, (OC-6-
11)-
Category 1
thymus
Specific target organ toxicity (repeated exposure)
Product/ingredient name
Category
Route of exposure
Target organs
Tin, dibutylbis(2,4-
pentanedionato-
.kappa.O2,.kappa.O4)-, (OC-6-
11)-
Category 1
thymus
Aspiration hazard
Product/ingredient name
Result
Distillates (petroleum), hydrotreated middle
ASPIRATION HAZARD - Category 1ASPIRATION
HAZARD - Category 1ASPIRATION HAZARD -
Category 1
Information on the likely routes of
:
Not available
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exposure
Potential acute health effects
Eye contact
:
No known significant effects or critical hazards.
Inhalation
:
Exposure to decomposition products may cause a health hazard.
Serious effects may be delayed following exposure.
Skin contact
:
May cause an allergic skin reaction.
Ingestion
:
No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact
:
No specific data.
Inhalation
:
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact
:
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion
:
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects
:
Not available
Potential delayed effects
:
Not available
Long term exposure
Potential immediate effects
:
Not available
Potential delayed effects
:
Not available
Potential chronic health effects
Conclusion/Summary
:
Not determined
General
:
Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels.
Carcinogenicity
:
No known significant effects or critical hazards.
Mutagenicity
:
No known significant effects or critical hazards.
Teratogenicity
:
May damage the unborn child.
Developmental effects
:
No known significant effects or critical hazards.
Fertility effects
:
May damage fertility.
Numerical measures of toxicity
Acute toxicity estimates
Not available
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Ecotoxicity
Conclusion/Summary
:
Not available
Persistence/degradability
Conclusion/Summary
:
Not available
Bioaccumulative potential
Product/ingredient name
Species
Exposure
LogPow
BCF
Potential
Silanamine, 1,1,1-trimethyl-N-
(trimethylsilyl)-
1.19
-
low
Mobility in soil
Soil/water partition coefficient
(KOC)
:
Not available
Other adverse effects
:
No known significant effects or critical hazards.
Disposal methods
:
The generation of waste should be avoided or minimized wherever
possible. Disposal of this product, solutions and any by-products
should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local
authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not
be disposed of untreated to the sewer unless fully compliant with
the requirements of all authorities with jurisdiction. Waste
packaging should be recycled. Incineration or landfill should only
be considered when recycling is not feasible. This material and its
container must be disposed of in a safe way. Care should be taken
when handling emptied containers that have not been cleaned or
rinsed out. Empty containers or liners may retain some product
residues. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
Special precautions for user
:
This product is not regarded as dangerous goods according to the
national and international regulations on the transport of dangerous
goods.
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15.Regulatory information
United States
U.S. Federal regulations
:
United States - TSCA 12(b) - Chemical export notification: None
required.
United States - TSCA 5(a)2 - Final significant new use rules: Not
listed
United States - TSCA 5(a)2 - Proposed significant new use rules:
Not listed
United States - TSCA 5(e) - Substances consent order: Not listed
SARA 311/312
Classification
:
Immediate (acute) health hazard
Delayed (chronic) health hazard
California Prop. 65:
:
WARNING: This product contains a chemical known to the State of
California to cause cancer., WARNING: This product contains less than
1% of a chemical known to the State of California to cause birth defects
or other reproductive harm.
Canada
WHMIS (Canada)
:
Class D-2A: Material causing other toxic effects (Very toxic).
Class D-2B: Material causing other toxic effects (Toxic).
International regulations
International lists
:
Australia inventory (AICS): All components are listed or exempted.
Canada inventory: All components are listed or exempted.
Japan inventory: Not determined.
China inventory (IECSC): All components are listed or exempted.
Korea inventory: All components are listed or exempted.
New Zealand Inventory (NZIoC): All components are listed or exempted.
Philippines inventory (PICCS): All components are listed or exempted.
United States inventory (TSCA 8b): All components are listed or exempted.
Taiwan inventory (CSNN): All components are listed or exempted.
Hazardous Material Information System III (U.S.A.) :
Health
2
Flammability
1
Physical hazards
0
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks,
and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs
under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a
fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings
Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Full text of abbreviated H
:
Not applicable.
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statements
History
Date of printing
:
05/28/2015
Date of issue/Date of revision
:
04/10/2015
Date of previous issue
:
03/19/2015
Version
:
1.2
Prepared by
:
Product Safety Stewardship
Key to abbreviations
:
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From
Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
RID = The Regulations concerning the International Carriage of Dangerous Goods
by Rail
UN = United Nations
References
:
Not available
Notice to reader
Unless otherwise specified in section 1, Momentive Products are intended for industrial application only. They
are not intended for specific medical applications, neither for long-lasting (> 30 days) implantation into the
human body, injected or directly ingested, nor for the manufacture of multiple usable contraceptives
Keep out of the reach of children.
Further Information
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and
belief at the date of its publication. The information given is designed only as a guidance for safe handling, use,
processing, storage, transportation, disposal and release and is not to be considered a warranty or quality
specification. The information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process, unless specified in the text.

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