Rust Oleum GHS 16 Section SDS 455010

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455010
Date Printed: 10/9/2015

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Safety Data Sheet
* Trusted Quality Since 1921 *
www.rustoleum.com

1. Identification
Product Name:

COVERSTAIN 13-OZ 6 PK +SPRAY

Revision Date:

10/9/2015

Product Identifier:

3608

Supercedes Date:

10/8/2015

Product Use/Class:

Stain/Aerosol

Supplier:

Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA

Manufacturer:

Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA

Preparer:

Regulatory Department

Emergency Telephone:

24 Hour Hotline: 847-367-7700

2. Hazard Identification
Classification
Symbol(s) of Product

Signal Word
Danger

GHS HAZARD STATEMENTS
Flammable Aerosol, category 1
Compressed Gas
Eye Irritation, category 2
Germ Cell Mutagenicity, category 1B

H222
H280
H319
H340

Carcinogenicity, category 1B

H350

GHS LABEL PRECAUTIONARY
STATEMENTS
P201
P210
P211
P251
P281
P305+P351+P338

Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
May cause genetic defects. Classified as mutagenic Category 1 if one
ingredient is present at or above 0.1%. Applies to liquids, solids (w/w units)
and gases (v/v). The substance may also have its own exposure limit. Routes
of exposure are dependent on ingredient form.
May cause cancer. Classified as carcinogenic Category 1 on the basis of
epidemiological and/or animal data. Mixtures are classified as carcinogenic
when at least 1 ingredient has been classified as carcinogenic and is present
at 0.1% or above Routes of exposure are dependent on ingredient form.

Obtain special instructions before use.
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
Do not spray on an open flame or other ignition source.
Do not pierce or burn, even after use.
Use personal protective equipment as required.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.

Date Printed: 10/9/2015

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P308+P313
P337+P313
P410+P403
P410+P412

IF exposed or concerned: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Protect from sunlight. Store in a well-ventilated place.
Protect from sunlight. Do not expose to temperatures exceeding 50°C / 122°F.

3. Composition/Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name

CAS-No.

Wt.%
Range

GHS Symbols

GHS Statements

Propane
Acetone
Aliphatic Hydrocarbon
n-Butane
Limestone
Titanium Dioxide
Hydrous Magnesium Silicate
Naphtha, Petroleum, Hydrotreated Light
1-Nitropropane
Kaolin Clay
Xylene (mixed isomers)
Nitroethane
Ethylbenzene
Ethylene Glycol Monobutyl Ether

74-98-6
67-64-1
64742-89-8
106-97-8
1317-65-3
13463-67-7
14807-96-6
64742-49-0
108-03-2
1332-58-7
1330-20-7
79-24-3
100-41-4
111-76-2

10-25
10-25
10-25
2.5-10
2.5-10
2.5-10
2.5-10
2.5-10
1.0-2.5
1.0-2.5
1.0-2.5
1.0-2.5
0.1-1.0
0.1-1.0

GHS04
GHS02-GHS07
GHS08
GHS04
No Information
No Information
No Information
GHS08
GHS02-GHS07
No Information
GHS02-GHS07
GHS02-GHS07
GHS02-GHS07
GHS06

H280
H225-319-336
H304-340-350
H280
No Information
No Information
No Information
H304-340-350
H226-302-332
No Information
H226-315-319-332
H226-302-332
H225-332
H302-310-315-319-330

4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation
develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the
area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the
lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention.

5. Fire-fighting Measures
EXTINGUISHING MEDIA:

Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Water Fog

UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS LESS THAN 20°F. EXTREMELY FLAMMABLE LIQUID AND
VAPOR!Water spray may be ineffective. Closed containers may explode when exposed to extreme heat due to buildup of steam.
Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to
a source of ignition and flash back. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame.
Perforation of the pressurized container may cause bursting of the can. No unusual fire or explosion hazards noted.
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible
autoignition or explosion. Full protective equipment including self-contained breathing apparatus should be used. Evacuate area
and fight fire from a safe distance. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.

6. Accidental Release Measures

Date Printed: 10/9/2015

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STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use
combustible materials such as sawdust. Isolate the hazard area and deny entry to unnecessary and unprotected personnel.
Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to
local, state (provincial) and federal regulations. Do not incinerate closed containers. Ventilate area, isolate spilled material, and
remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state,
and federal regulations.

7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse.
Use only in a well-ventilated area. Use only with adequate ventilation. Follow all MSDS/label precautions even after container is
emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep containers tightly closed.
Isolate from heat, electrical equipment, sparks and open flame. Contents under pressure. Do not store above 120 ° F. Store large
quantities in buildings designed and protected for storage of NFPA Class I flammable liquids. Keep away from heat, sparks, flame
and sources of ignition. Contents under pressure. Do not expose to heat or store above 120 ° F. Avoid excess heat. Product
should be stored in tightly sealed containers and protected from heat, moisture, and foreign materials.

8. Exposure Controls/Personal Protection
Chemical Name
Propane
Acetone
Aliphatic Hydrocarbon
n-Butane
Limestone
Titanium Dioxide
Hydrous Magnesium Silicate
Naphtha, Petroleum,
Hydrotreated Light
1-Nitropropane
Kaolin Clay
Xylene (mixed isomers)
Nitroethane
Ethylbenzene
Ethylene Glycol Monobutyl Ether

CAS-No.

Weight %
Less Than

ACGIH TLVTWA

ACGIH TLVSTEL

OSHA PEL-TWA

OSHA PELCEILING

74-98-6
67-64-1
64742-89-8
106-97-8
1317-65-3
13463-67-7
14807-96-6

20.0
20.0
20.0
10.0
10.0
10.0
5.0

N.E.
250 ppm
N.E.
N.E.
N.E.
10 mg/m3
2 mg/m3

N.E.
500 ppm
N.E.
1000 ppm
N.E.
N.E.
N.E.

1000 ppm
1000 ppm
N.E.
N.E.
15 mg/m3
15 mg/m3
N.E.

N.E.
N.E.
N.E.
N.E.
N.E.
N.E.
N.E.

64742-49-0

5.0

N.E.

N.E.

N.E.

N.E.

108-03-2
1332-58-7
1330-20-7
79-24-3
100-41-4
111-76-2

5.0
5.0
5.0
5.0
1.0
1.0

25 ppm
2 mg/m3
100 ppm
100 ppm
20 ppm
20 ppm

N.E.
N.E.
150 ppm
N.E.
N.E.
N.E.

25 ppm
15 mg/m3
100 ppm
100 ppm
100 ppm
50 ppm

N.E.
N.E.
N.E.
N.E.
N.E.
N.E.

PERSONAL PROTECTION
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Use explosion-proof ventilation equipment. Provide general dilution of local exhaust
ventilation in volume and pattern to keep TLV of hazardous ingredients below acceptable limits. Prevent build-up of vapors by
opening all doors and windows to achieve cross-ventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must
be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with
organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to
exceed exposure limits.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Use impervious gloves to prevent skin contact and absorption
of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications. Refer to safety supervisor or industrial hygienist for further information
regarding personal protective equipment and its application.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing
immediately and launder before reuse.

Date Printed: 10/9/2015

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9. Physical and Chemical Properties
Appearance:
Odor:
Relative Density:
Freeze Point, °C:
Solubility in Water:
Decompostion Temp., °C:
Boiling Range, °C:
Flammability:
Evaporation Rate:
Vapor Density:

Aerosolized Mist
Solvent Like
0.837
N.D.
Slight
N.D.
-24 - 537
Supports Combustion
Faster than Ether
Heavier than Air

Physical State:
Odor Threshold:
pH:
Viscosity:
Partition Coefficient, noctanol/water:

Liquid
N.E.
N.A.
N.D.

Explosive Limits, vol%:
Flash Point, °C:
Auto-ignition Temp., °C:
Vapor Pressure:

0.9 - 13.0
-96
N.D.
N.D.

N.D.

(See "Other information" Section for abbreviation legend)

10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid temperatures above 120°F (49°C). Avoid contact with strong acid and strong bases. Avoid all
possible sources of ignition.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits
acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.

11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes Serious Eye Irritation
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Substance may cause slight skin irritation. May cause skin irritation.
Allergic reactions are possible. Prolonged or repeated contact may cause skin irritation.
EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful
if inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and
lungs. Prolonged or excessive inhalation may cause respiratory tract irritation.
EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed. Aspiration hazard if swallowed; can enter lungs and cause
damage.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: May cause central nervous system disorder (e.g., narcosis involving a
loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. High concentrations may lead to
central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage. Reports
have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage.
Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood
damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac
abnormalities and nervous system damage. IARC lists Ethylbenzene as a possible human carcinogen (group 2B). Contains
Titanium Dioxide. Titanium Dioxide is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC. No significant exposure to
Titanium Dioxide is thought to occur during the use of products in which Titanium Dioxide is bound to other materials, such as in
paints during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated
sanding of surfaces or spray mist and the actual concentration of Titanium Dioxide in the formula. (Ref: IARC Monograph, Vol. 93,
2010)
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUES
The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No.
Chemical Name
Oral LD50
Dermal LD50
74-98-6
Propane
N.I.
N.I.
67-64-1
Acetone
5800 mg/kg Rat
N.I.
64742-89-8
Aliphatic Hydrocarbon
N.I.
3000 mg/kg Rabbit
106-97-8
n-Butane
N.I.
N.I.
13463-67-7
Titanium Dioxide
>10000 mg/kg Rat
N.I.
64742-49-0
Naphtha, Petroleum, Hydrotreated Light
>5000 mg/kg Rat
>3160 mg/kg Rabbit
108-03-2
1-Nitropropane
455 mg/kg Rat
>2000 mg/kg Rabbit
1330-20-7
Xylene (mixed isomers)
3500 mg/kg Rat
>4350 mg/kg Rabbit

Vapor LC50
658 mg/L Rat
50.1 mg/L Rat
N.I.
658 mg/L Rat
N.I.
>4951 mg/L Rat
11.02 mg/L Rat
29.08 mg/L Rat

Date Printed: 10/9/2015
79-24-3
100-41-4
111-76-2

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Nitroethane
Ethylbenzene
Ethylene Glycol Monobutyl Ether

1625 mg/kg Rat
3500 mg/kg Rat
470 mg/kg Rat

N.I.
15400 mg/kg Rabbit
99 mg/kg Rabbit

N.I.
17.2 mg/L Rat
N.I.

N.I. - No Information

12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components. Product is a mixture of listed components.

13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not
allow to enter waterways, wastewater, soil, storm drains or sewer systems.

14. Transport Information
UN Number:
Proper Shipping Name:

Domestic (USDOT)

International (IMDG)

Air (IATA)

TDG (Canada)

N.A.
Paint Products in
Limited Quantities

1950

1950

Aerosols

Aerosols

N.A.
Paint Products in
Limited Quantities

Hazard Class:

N.A.

2.1

2.1

N.A.

Packing Group:

N.A.

N.A.

N.A.

N.A.

Limited Quantity:

Yes

Yes

Yes

Yes

15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Fire Hazard, Pressure Hazard, Acute Health Hazard, Chronic Health Hazard

Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:

Chemical Name

CAS-No.

Xylene (mixed isomers)
Ethylbenzene
Ethylene Glycol Monobutyl Ether

1330-20-7
100-41-4
111-76-2

Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported
from the United States:
No TSCA 12(b) components exist in this product.

Date Printed: 10/9/2015

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16. Other Information
HMIS RATINGS
Health:

2*

Flammability:

4

Physical Hazard:

0

Flammability:

4

Instability

0

Personal Protection:

X

NFPA RATINGS
Health:

2

VOLATILE ORGANIC COMPOUNDS, g/L:

525

SDS REVISION DATE:

10/9/2015

REASON FOR REVISION:

Substance and/or Product Properties Changed in Section(s):
03 - Composition/Information on Ingredients
11 - Toxicological Information
Substance Hazard Threshold % Changed
Statement(s) Changed

Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be
accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of
these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred
by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or
reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with
caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and
examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all
applicable international, federal, state, and local laws and regulations.



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