Rust Oleum GHS 16 Section SDS 455010
2016-12-16
: Pdf 455010 455010 msds
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Page Count: 6
Date Printed: 10/9/2015
Safety Data Sheet
*Trusted Quality Since 1921 *
www.rustoleum.com
1. Identification
Product Name: COVERSTAIN 13-OZ 6 PK +SPRAY Revision Date: 10/9/2015
Product Identifier: 3608 Supercedes Date: 10/8/2015
Product Use/Class: Stain/Aerosol
Supplier: Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
Manufacturer: Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
Preparer: Regulatory Department
24 Hour Hotline: 847-367-7700
Emergency Telephone:
2. Hazard Identification
Classification
Symbol(s) of Product
Signal Word
Danger
GHS HAZARD STATEMENTS
Flammable Aerosol, category 1 H222 Extremely flammable aerosol.
Compressed Gas H280 Contains gas under pressure; may explode if heated.
Eye Irritation, category 2 H319 Causes serious eye irritation.
Germ Cell Mutagenicity, category 1B H340 May cause genetic defects. Classified as mutagenic Category 1 if one
ingredient is present at or above 0.1%. Applies to liquids, solids (w/w units)
and gases (v/v). The substance may also have its own exposure limit. Routes
of exposure are dependent on ingredient form.
Carcinogenicity, category 1B H350 May cause cancer. Classified as carcinogenic Category 1 on the basis of
epidemiological and/or animal data. Mixtures are classified as carcinogenic
when at least 1 ingredient has been classified as carcinogenic and is present
at 0.1% or above Routes of exposure are dependent on ingredient form.
GHS LABEL PRECAUTIONARY
STATEMENTS
P201 Obtain special instructions before use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P281 Use personal protective equipment as required.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
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455010
Date Printed: 10/9/2015
P308+P313 IF exposed or concerned: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P410+P403 Protect from sunlight. Store in a well-ventilated place.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50°C / 122°F.
3. Composition/Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.%
Range
GHS Symbols GHS Statements
Propane 10-25 GHS04 H280
74-98-6
Acetone 10-25 GHS02-GHS07 H225-319-336
67-64-1
Aliphatic Hydrocarbon 10-25 GHS08 H304-340-350
64742-89-8
n-Butane 2.5-10 GHS04 H280
106-97-8
Limestone 2.5-10 No Information No Information
1317-65-3
Titanium Dioxide 2.5-10 No Information No Information
13463-67-7
Hydrous Magnesium Silicate 2.5-10 No Information No Information
14807-96-6
Naphtha, Petroleum, Hydrotreated Light 2.5-10 GHS08 H304-340-350
64742-49-0
1-Nitropropane 1.0-2.5 GHS02-GHS07 H226-302-332
108-03-2
Kaolin Clay 1.0-2.5 No Information No Information
1332-58-7
Xylene (mixed isomers) 1.0-2.5 GHS02-GHS07 H226-315-319-332
1330-20-7
Nitroethane 1.0-2.5 GHS02-GHS07 H226-302-332
79-24-3
Ethylbenzene 0.1-1.0 GHS02-GHS07 H225-332
100-41-4
Ethylene Glycol Monobutyl Ether 0.1-1.0 GHS06 H302-310-315-319-330
111-76-2
4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation
develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the
area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the
lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention.
5. Fire-fighting Measures
EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS LESS THAN 20°F. EXTREMELY FLAMMABLE LIQUID AND
VAPOR!Water spray may be ineffective. Closed containers may explode when exposed to extreme heat due to buildup of steam.
Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to
a source of ignition and flash back. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame.
Perforation of the pressurized container may cause bursting of the can. No unusual fire or explosion hazards noted.
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible
autoignition or explosion. Full protective equipment including self-contained breathing apparatus should be used. Evacuate area
and fight fire from a safe distance. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.
6. Accidental Release Measures
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Date Printed: 10/9/2015
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use
combustible materials such as sawdust. Isolate the hazard area and deny entry to unnecessary and unprotected personnel.
Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to
local, state (provincial) and federal regulations. Do not incinerate closed containers. Ventilate area, isolate spilled material, and
remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state,
and federal regulations.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse.
Use only in a well-ventilated area. Use only with adequate ventilation. Follow all MSDS/label precautions even after container is
emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep containers tightly closed.
Isolate from heat, electrical equipment, sparks and open flame. Contents under pressure. Do not store above 120 ° F. Store large
quantities in buildings designed and protected for storage of NFPA Class I flammable liquids. Keep away from heat, sparks, flame
and sources of ignition. Contents under pressure. Do not expose to heat or store above 120 ° F. Avoid excess heat. Product
should be stored in tightly sealed containers and protected from heat, moisture, and foreign materials.
8. Exposure Controls/Personal Protection
Chemical Name CAS-No. Weight %
Less Than
ACGIH TLV-
TWA
ACGIH TLV-
STEL OSHA PEL-TWA OSHA PEL-
CEILING
Propane 74-98-6 20.0 N.E. N.E. 1000 ppm N.E.
Acetone 67-64-1 20.0 250 ppm 500 ppm 1000 ppm N.E.
Aliphatic Hydrocarbon 64742-89-8 20.0 N.E. N.E. N.E. N.E.
n-Butane 106-97-8 10.0 N.E. 1000 ppm N.E. N.E.
Limestone 1317-65-3 10.0 N.E. N.E. 15 mg/m3 N.E.
Titanium Dioxide 13463-67-7 10.0 10 mg/m3 N.E. 15 mg/m3 N.E.
Hydrous Magnesium Silicate 14807-96-6 5.0 2 mg/m3 N.E. N.E. N.E.
Naphtha, Petroleum,
Hydrotreated Light 64742-49-0 5.0 N.E. N.E. N.E. N.E.
1-Nitropropane 108-03-2 5.0 25 ppm N.E. 25 ppm N.E.
Kaolin Clay 1332-58-7 5.0 2 mg/m3 N.E. 15 mg/m3 N.E.
Xylene (mixed isomers) 1330-20-7 5.0 100 ppm 150 ppm 100 ppm N.E.
Nitroethane 79-24-3 5.0 100 ppm N.E. 100 ppm N.E.
Ethylbenzene 100-41-4 1.0 20 ppm N.E. 100 ppm N.E.
Ethylene Glycol Monobutyl Ether 111-76-2 1.0 20 ppm N.E. 50 ppm N.E.
PERSONAL PROTECTION
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Use explosion-proof ventilation equipment. Provide general dilution of local exhaust
ventilation in volume and pattern to keep TLV of hazardous ingredients below acceptable limits. Prevent build-up of vapors by
opening all doors and windows to achieve cross-ventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must
be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with
organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to
exceed exposure limits.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Use impervious gloves to prevent skin contact and absorption
of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications. Refer to safety supervisor or industrial hygienist for further information
regarding personal protective equipment and its application.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing
immediately and launder before reuse.
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Date Printed: 10/9/2015
9. Physical and Chemical Properties
Appearance: Aerosolized Mist Physical State: Liquid
Odor: Solvent Like Odor Threshold: N.E.
Relative Density: 0.837 pH: N.A.
Freeze Point, °C: N.D. Viscosity: N.D.
Solubility in Water: Slight Partition Coefficient, n-
octanol/water: N.D.
Decompostion Temp., °C: N.D.
Boiling Range, °C: -24 - 537 Explosive Limits, vol%: 0.9 - 13.0
Flammability: Supports Combustion Flash Point, °C: -96
Evaporation Rate: Faster than Ether Auto-ignition Temp., °C: N.D.
Vapor Density: Heavier than Air Vapor Pressure: N.D.
(See "Other information" Section for abbreviation legend)
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid temperatures above 120°F (49°C). Avoid contact with strong acid and strong bases. Avoid all
possible sources of ignition.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits
acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes Serious Eye Irritation
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Substance may cause slight skin irritation. May cause skin irritation.
Allergic reactions are possible. Prolonged or repeated contact may cause skin irritation.
EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful
if inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and
lungs. Prolonged or excessive inhalation may cause respiratory tract irritation.
EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed. Aspiration hazard if swallowed; can enter lungs and cause
damage.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: May cause central nervous system disorder (e.g., narcosis involving a
loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. High concentrations may lead to
central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage. Reports
have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage.
Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood
damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac
abnormalities and nervous system damage. IARC lists Ethylbenzene as a possible human carcinogen (group 2B). Contains
Titanium Dioxide. Titanium Dioxide is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC. No significant exposure to
Titanium Dioxide is thought to occur during the use of products in which Titanium Dioxide is bound to other materials, such as in
paints during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated
sanding of surfaces or spray mist and the actual concentration of Titanium Dioxide in the formula. (Ref: IARC Monograph, Vol. 93,
2010)
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUES
The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
74-98-6 Propane N.I. N.I. 658 mg/L Rat
67-64-1 Acetone 5800 mg/kg Rat N.I. 50.1 mg/L Rat
64742-89-8 Aliphatic Hydrocarbon N.I. 3000 mg/kg Rabbit N.I.
106-97-8 n-Butane N.I. N.I. 658 mg/L Rat
13463-67-7 Titanium Dioxide >10000 mg/kg Rat N.I. N.I.
64742-49-0 Naphtha, Petroleum, Hydrotreated Light >5000 mg/kg Rat >3160 mg/kg Rabbit >4951 mg/L Rat
108-03-2 1-Nitropropane 455 mg/kg Rat >2000 mg/kg Rabbit 11.02 mg/L Rat
1330-20-7 Xylene (mixed isomers) 3500 mg/kg Rat >4350 mg/kg Rabbit 29.08 mg/L Rat
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Date Printed: 10/9/2015
79-24-3 Nitroethane 1625 mg/kg Rat N.I. N.I.
100-41-4 Ethylbenzene 3500 mg/kg Rat 15400 mg/kg Rabbit 17.2 mg/L Rat
111-76-2 Ethylene Glycol Monobutyl Ether 470 mg/kg Rat 99 mg/kg Rabbit N.I.
N.I. - No Information
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components. Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not
allow to enter waterways, wastewater, soil, storm drains or sewer systems.
14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. 1950 1950 N.A.
Proper Shipping Name: Paint Products in
Limited Quantities Aerosols Aerosols Paint Products in
Limited Quantities
Hazard Class: N.A. 2.1 2.1 N.A.
Packing Group: N.A. N.A. N.A. N.A.
Limited Quantity: Yes Yes Yes Yes
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Fire Hazard, Pressure Hazard, Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS-No.
Xylene (mixed isomers) 1330-20-7
Ethylbenzene 100-41-4
Ethylene Glycol Monobutyl Ether 111-76-2
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported
from the United States:
No TSCA 12(b) components exist in this product.
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Date Printed: 10/9/2015
16. Other Information
HMIS RATINGS
Health: 2* Flammability: 4Physical Hazard: 0Personal Protection: X
NFPA RATINGS
Health: 2Flammability: 4Instability 0
VOLATILE ORGANIC COMPOUNDS, g/L: 525
SDS REVISION DATE: 10/9/2015
REASON FOR REVISION: Substance and/or Product Properties Changed in Section(s):
03 - Composition/Information on Ingredients
11 - Toxicological Information
Substance Hazard Threshold % Changed
Statement(s) Changed
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be
accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of
these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred
by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or
reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with
caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and
examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all
applicable international, federal, state, and local laws and regulations.
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