CHEMMATE500 716464 MSDS
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2017-04-29
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Conforms to ANSI Z400.1-2004 Standard (United States). pH Down Material Safety Data Sheet 1 . Product and company identification Common name Material uses Supplier/Manufacturer In case of emergency : pH Down : pH control. : Technaflora Plant Products Ltd. 1533 Broadway Street, 125 Port Coquitlam, B.C. Canada, V3C 6P3 Tel. 604-468-4769 / 1-800-586-1211 : CHEMTREC, U.S. : (800) 424-9300 International: (703) 527-3887 2 . Hazards identification Physical state Odor Color Hazard status Emergency overview Routes of entry Potential acute health effects Eyes Skin Inhalation Ingestion Potential chronic health effects : : : : : Liquid. Odorless. Colorless. This material is classified as hazardous under OSHA regulations. DANGER ! CAUSES SEVERE RESPIRATORY TRACT, EYE AND SKIN BURNS. CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS: LUNGS, MUCOUS MEMBRANES, RESPIRATORY TRACT, SKIN, ENDOTHELIUM, EYE, LENS OR CORNEA, TEETH. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. : Dermal contact. Eye contact. Inhalation. Ingestion. : : : : : Severely corrosive to the eyes. Severely corrosive to the skin. Severely corrosive to the respiratory system. May cause burns to mouth, throat and stomach. Carcinogenic effects : Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Mutagenic effects : Not available. Teratogenic effects : Not available. Medical conditions : Repeated skin exposure can produce local skin destruction or dermatitis. Repeated or aggravated by overprolonged exposure to the substance can produce lung damage. Repeated or prolonged exposure contact with spray or mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to the substance can produce target organ damage. See toxicological information (section 11) 3 . Composition/information on ingredients United States Name CAS number Nitric Acid 7697-37-2 Date of issue : 08/31/2006 % 5 - 10 Page: 1/5 pH Down 4 . First aid measures Eye contact : Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 20 minutes. Get medical attention immediately. : In case of contact, immediately flush skin with plenty of water for at least 20 minutes. Get medical attention immediately. : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. : Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention immediately. : No specific antidote. Medical staff must contact Poison Control Center. Skin contact Inhalation Ingestion Notes to physician 5 . Fire-fighting measures Flammability of the product Extinguishing media Suitable Not suitable Special exposure hazards Special protective equipment for fire-fighters : Non-flammable. : : : : Use an extinguishing agent suitable for the surrounding fire. None known. No specific hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. 6 . Accidental release measures Personal precautions Environmental precautions Methods for cleaning up : Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment. : Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains and sewers. : If emergency personnel are unavailable, contain spilled material. For small spills, add absorbent (soil may be used in the absence of other suitable materials), scoop up material and place in a sealable, liquid-proof container for disposal. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal. 7 . Handling and storage Handling Storage : Do not get in eyes or on skin or clothing. Keep container closed. Use only with adequate ventilation. Do not breathe vapor or mist. Wash thoroughly after handling. : Keep container tightly closed. Keep container in a cool, well-ventilated area. 8 . Exposure controls/personal protection United States Product name Nitric Acid Date of issue Exposure limits ACGIH TLV (United States, 9/2004). STEL: 10 mg/m3 15 minute(s). Form: All forms. STEL: 4 ppm 15 minute(s). Form: All forms. TWA: 5.2 mg/m3 8 hour(s). Form: All forms. TWA: 2 ppm 8 hour(s). Form: All forms. NIOSH REL (United States, 12/2001). STEL: 10 mg/m3 15 minute(s). Form: All forms. STEL: 4 ppm 15 minute(s). Form: All forms. TWA: 5 mg/m3 10 hour(s). Form: All forms. TWA: 2 ppm 10 hour(s). Form: All forms. OSHA PEL (United States, 8/1997). TWA: 5 mg/m3 8 hour(s). Form: All forms. : 08/31/2006 Page: 2/5 pH Down TWA: 2 ppm 8 hour(s). Form: All forms. ACGIH TLV (United States, 1/2004). STEL: 10 mg/m3 15 minute(s). Form: All forms. STEL: 4 ppm 15 minute(s). Form: All forms. TWA: 5.2 mg/m3 8 hour(s). Form: All forms. TWA: 2 ppm 8 hour(s). Form: All forms. Engineering measures Personal protection Eyes Skin Respiratory Hands HMIS Code/Personal protective equipment : Use only with adequate ventilation. If user operations generate dust, fumes, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. : : : : Face shield. Synthetic apron. Boots. Vapor respirator. Nitrile rubber. : D Personal protection in case : Safety glasses, goggles or face shield. Impervious gloves. Full suit. Boots. Wear NIOSHof a large spill approved self-contained breathing apparatus or equivalent and full protective gear. Hygiene measures : Wash hands, forearms and face thoroughly after handling compounds and before eating, smoking and using the lavatory and at the end of the day. Follow good industrial hygiene practice. 9 . Physical and chemical properties Physical state Color Odor pH Boiling/condensation point : : : : : Melting/freezing point : Relative density Vapor pressure : : Vapor density Evaporation rate Solubility : : : Liquid. Colorless. Odorless. 0 to 0.5 [Acidic.] The lowest known value is 83.89°C (183°F) (Nitric Acid). Weighted average: 98.39°C (209.1°F) May start to solidify at 0°C (32°F) based on data for: Water. Weighted average: -4.11°C (24.6°F) Weighted average: 1.03 (Water = 1) The highest known value is 6.5 to 7.3 kPa (49 to 55 mm Hg) (at 20°C) (Nitric Acid). Weighted average: 2.76 kPa (20.7 mm Hg) (at 20°C) The highest known value is 0.62 (Air = 1) (Water). 0.36 (Water) compared with Butyl acetate. Highly soluble in water. 10 . Stability and reactivity Stability and reactivity Incompatibility with various substances Hazardous polymerization Conditions of reactivity Date of issue : The product is stable. : Reactive with oxidizing materials, metals and alkalis. : Will not occur. : None known. : 08/31/2006 Page: 3/5 pH Down 11 . Toxicological information Acute Effects Eyes Skin Inhalation Ingestion Potential chronic health effects Target organs : : : : : Severely corrosive to the eyes. Severely corrosive to the skin. Severely corrosive to the respiratory system. May cause burns to mouth, throat and stomach. Carcinogenic effects : Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Mutagenic effects : Not available. Teratogenic effects : Not available. : Contains material which causes damage to the following organs: lungs, mucous membranes, upper respiratory tract, skin, endothelium, eye, lens or cornea, teeth. 12 . Ecological information Environmental precautions Products of degradation Toxicity of the products of biodegradation : No known significant effects or critical hazards. : These products are nitrogen oxides. : The products of degradation are less toxic than the product itself. 13 . Disposal considerations : The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional and local authority requirements. Waste disposal 14 . Transport information NAERG Regulatory information : 157 Proper shipping name UN / IMDG / IATA Classification NITRIC ACID [other than red fuming, with not more than 70 percent nitric acid] Class UN number PG 8 UN2031 II Label 8 DOT Classification NITRIC ACID [other than red fuming, with not more than 70 percent nitric acid] 8 UN2031 II CORROSIVE 8 15 . Regulatory information United States HCS Classification U.S. Federal regulations Date of issue : Corrosive material Target organ effects : TSCA : All components listed. SARA 302/304/311/312 extremely hazardous substances: Nitric Acid SARA 302/304 emergency planning and notification: Nitric Acid SARA 302/304/311/312 hazardous chemicals: Nitric Acid SARA 311/312 MSDS distribution - chemical inventory - hazard identification: Nitric Acid: Fire hazard, reactive, Immediate (acute) health hazard Clean Water Act (CWA) 307: No products were found. Clean Water Act (CWA) 311: Nitric Acid : 08/31/2006 Page: 4/5 pH Down Clean Air Act (CAA) 112 accidental release prevention: Nitric Acid Clean Air Act (CAA) 112 regulated flammable substances: No products were found. Clean Air Act (CAA) 112 regulated toxic substances: Nitric Acid SARA 313 Form R - Reporting requirements Supplier notification Product name : Nitric Acid CAS number 7697-37-2 Concentration 5 - 10 : Nitric Acid 7697-37-2 5 - 10 SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed. State regulations : Pennsylvania RTK: Nitric Acid: (environmental hazard, generic environmental hazard) Massachusetts RTK: Nitric Acid New Jersey: Nitric Acid California prop. 65: No products were found. International lists : This product, (and its ingredients) is (are) listed on national inventories, or is (are) exempted from being listed, Australia (AICS), in Europe (EINECS/ELINCS), in Korea (TCCL), in Japan (METI), in the Philippines (RA6969). 16 . Other information Label requirements (U.S.A.) : CAUSES SEVERE RESPIRATORY TRACT, EYE AND SKIN BURNS. CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS: LUNGS, MUCOUS MEMBRANES, RESPIRATORY TRACT, SKIN, ENDOTHELIUM, EYE, LENS OR CORNEA, TEETH. Hazardous Material : Information System (U.S.A.) National Fire Protection Association (U.S.A.) HAZARD RATINGS HMIS RATING * Health 3 Fire hazard 0 Physical Hazard 0 Personal protection D : Flammability 0 Health 3 4- Extreme 3- Serious 2- Moderate 1- Slight 0- Minimal See section 8 for more detailed information on personal protection. 0 Reactivity Special References : ANSI Z400.1, MSDS Standard, 2004. - Manufacturer's Material Safety Data Sheet. 29CFR Part1910.1200 OSHA MSDS Requirements. - 49CFR Table List of Hazardous Materials, UN#, Proper Shipping Names, PG. : 08/31/2006 : 06/30/2004 : 2 Date of issue Date of previous issue Version Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue : 08/31/2006 Page: 5/5
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