CHEMMATE500 716464 MSDS

716464 Msds 716464_MSDS 716464_MSDS MSDS s sunlightsupply 3:

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Material Safety Data Sheet

Product and company identification1 .

Common name

pH control.Material uses

In case of emergency :

Supplier/Manufacturer : Technaflora Plant Products Ltd.

1533 Broadway Street, 125

Port Coquitlam, B.C.

Canada, V3C 6P3

Tel. 604-468-4769 / 1-800-586-1211

Conforms to ANSI Z400.1-2004 Standard (United States).

CHEMTREC, U.S. : (800) 424-9300 International: (703) 527-3887

Dermal contact. Eye contact. Inhalation. Ingestion.

Hazards identification

Routes of entry

Potential acute health effects

Severely corrosive to the respiratory system.

Severely corrosive to the eyes.

May cause burns to mouth, throat and stomach.

Severely corrosive to the skin.

Eyes

Skin

Inhalation

Ingestion

Physical state Liquid.

See toxicological information (section 11)

Medical conditions

aggravated by over-

exposure

Repeated skin exposure can produce local skin destruction or dermatitis. Repeated or

prolonged exposure to the substance can produce lung damage. Repeated or prolonged

contact with spray or mist may produce chronic eye irritation and severe skin irritation.

Repeated or prolonged exposure to the substance can produce target organ damage.

Odor : Odorless.

2 .

Emergency overview :DANGER !

CAUSES SEVERE RESPIRATORY TRACT, EYE AND SKIN BURNS.

CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS:

LUNGS, MUCOUS MEMBRANES, RESPIRATORY TRACT, SKIN, ENDOTHELIUM,

EYE, LENS OR CORNEA, TEETH.

Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Keep container

closed. Use only with adequate ventilation. Wash thoroughly after handling.

Potential chronic health

effects Carcinogenic effects : Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.

Mutagenic effects : Not available.

Teratogenic effects : Not available.

Color : Colorless.

This material is classified as hazardous under OSHA regulations.:Hazard status

Composition/information on ingredients3 .

%Name CAS number

United States

Nitric Acid 7697-37-2 5 - 10

Date of issue :08/31/2006 Page: 1/5

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First aid measures4 .

Eye contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with

plenty of water for at least 20 minutes. Get medical attention immediately.

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is

difficult, give oxygen. Get medical attention immediately.

Do not induce vomiting. Never give anything by mouth to an unconscious person. Get

medical attention immediately.

Skin contact

Inhalation

Ingestion

Notes to physician

:No specific antidote. Medical staff must contact Poison Control Center.

In case of contact, immediately flush skin with plenty of water for at least 20 minutes. Get

medical attention immediately.

Non-flammable.

Use an extinguishing agent suitable for the surrounding fire.

Fire-fighting measures

Flammability of the product

Extinguishing media

No specific hazard.

Special protective

equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing

apparatus (SCBA) with a full face-piece operated in positive pressure mode.

5 .

Special exposure hazards :

None known.

Suitable :

Not suitable :

Immediately contact emergency personnel. Keep unnecessary personnel away. Use

suitable protective equipment.

If emergency personnel are unavailable, contain spilled material. For small spills, add

absorbent (soil may be used in the absence of other suitable materials), scoop up

material and place in a sealable, liquid-proof container for disposal. For large spills, dike

spilled material or otherwise contain material to ensure runoff does not reach a waterway.

Place spilled material in an appropriate container for disposal.

Environmental precautions

Accidental release measures

:Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains and

sewers.

Personal precautions :

Methods for cleaning up :

6 .

Keep container tightly closed. Keep container in a cool, well-ventilated area.

Do not get in eyes or on skin or clothing. Keep container closed. Use only with adequate

ventilation. Do not breathe vapor or mist. Wash thoroughly after handling.

Handling and storage

Handling

Storage

7 .

Nitric Acid ACGIH TLV (United States, 9/2004).

STEL: 10 mg/m3 15 minute(s). Form: All forms.

STEL: 4 ppm 15 minute(s). Form: All forms.

TWA: 5.2 mg/m3 8 hour(s). Form: All forms.

TWA: 2 ppm 8 hour(s). Form: All forms.

NIOSH REL (United States, 12/2001).

STEL: 10 mg/m3 15 minute(s). Form: All forms.

STEL: 4 ppm 15 minute(s). Form: All forms.

TWA: 5 mg/m3 10 hour(s). Form: All forms.

TWA: 2 ppm 10 hour(s). Form: All forms.

OSHA PEL (United States, 8/1997).

TWA: 5 mg/m3 8 hour(s). Form: All forms.

Exposure controls/personal protection

Product name Exposure limits

United States

8 .

Date of issue :08/31/2006 Page: 2/5

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TWA: 2 ppm 8 hour(s). Form: All forms.

ACGIH TLV (United States, 1/2004).

STEL: 10 mg/m3 15 minute(s). Form: All forms.

STEL: 4 ppm 15 minute(s). Form: All forms.

TWA: 5.2 mg/m3 8 hour(s). Form: All forms.

TWA: 2 ppm 8 hour(s). Form: All forms.

Personal protection

Engineering measures : Use only with adequate ventilation. If user operations generate dust, fumes, vapor or

mist, use process enclosures, local exhaust ventilation or other engineering controls to

keep worker exposure to airborne contaminants below any recommended or statutory

limits.

Hygiene measures :

Personal protection in case

of a large spill :Safety glasses, goggles or face shield. Impervious gloves. Full suit. Boots. Wear NIOSH-

approved self-contained breathing apparatus or equivalent and full protective gear.

Wash hands, forearms and face thoroughly after handling compounds and before eating,

smoking and using the lavatory and at the end of the day. Follow good industrial hygiene

practice.

HMIS Code/Personal

protective equipment :D

Synthetic apron. Boots.

Nitrile rubber.

Vapor respirator.

Face shield.

Eyes

Skin

Respiratory

Hands

The lowest known value is 83.89°C (183°F) (Nitric Acid). Weighted average: 98.39°C

(209.1°F)

Liquid.

0 to 0.5 [Acidic.]

May start to solidify at 0°C (32°F) based on data for: Water. Weighted average: -4.11°C

(24.6°F)

Weighted average: 1.03 (Water = 1)

The highest known value is 0.62 (Air = 1) (Water).

The highest known value is 6.5 to 7.3 kPa (49 to 55 mm Hg) (at 20°C) (Nitric Acid).

Weighted average: 2.76 kPa (20.7 mm Hg) (at 20°C)

Odorless.

Colorless.

Boiling/condensation point

Melting/freezing point

0.36 (Water) compared with Butyl acetate.

Physical and chemical properties

Physical state

Relative density

Vapor pressure

Vapor density

Evaporation rate

Odor

Color

9 .

Highly soluble in water.Solubility :

The product is stable.

Reactive with oxidizing materials, metals and alkalis.

Will not occur.

Stability and reactivity

Incompatibility with various

substances

Hazardous polymerization

10 .

None known.Conditions of reactivity :

Date of issue :08/31/2006 Page: 3/5

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Toxicological information11 .

Eyes : Severely corrosive to the eyes.

Skin : Severely corrosive to the skin.

Inhalation : Severely corrosive to the respiratory system.

Ingestion :May cause burns to mouth, throat and stomach.

Acute Effects

Potential chronic health

effects :Carcinogenic effects : Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.

Mutagenic effects : Not available.

Teratogenic effects : Not available.

Target organs :Contains material which causes damage to the following organs: lungs, mucous

membranes, upper respiratory tract, skin, endothelium, eye, lens or cornea, teeth.

These products are nitrogen oxides.

The products of degradation are less toxic than the product itself.

Ecological information

Toxicity of the products of

biodegradation

Products of degradation :

Environmental precautions : No known significant effects or critical hazards.

12 .

The generation of waste should be avoided or minimized wherever possible. Avoid

dispersal of spilled material, runoff and contact with soil, waterways, drains and sewers.

Disposal of this product, solutions and any by-products should at all times comply with the

requirements of environmental protection and waste disposal legislation and any regional

and local authority requirements.

Waste disposal

Disposal considerations

13 .

Transport information14 .

NAERG :157

Regulatory

information

CORROSIVE

DOT Classification NITRIC ACID [other than red fuming, with not

more than 70 percent nitric acid] II

UN numberProper shipping name Class PG Label

UN2031

UN / IMDG / IATA

Classification UN2031NITRIC ACID [other than red fuming, with not

more than 70 percent nitric acid] 8II

Regulatory information

Clean Water Act (CWA) 307: No products were found.

Clean Water Act (CWA) 311: Nitric Acid

SARA 302/304/311/312 extremely hazardous substances: Nitric Acid

SARA 302/304 emergency planning and notification: Nitric Acid

SARA 302/304/311/312 hazardous chemicals: Nitric Acid

SARA 311/312 MSDS distribution - chemical inventory - hazard identification: Nitric Acid:

Fire hazard, reactive, Immediate (acute) health hazard

United States

15 .

HCS Classification

TSCA : All components listed.

Corrosive material

Target organ effects

U.S. Federal regulations :

Date of issue :08/31/2006 Page: 4/5

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Clean Air Act (CAA) 112 accidental release prevention: Nitric Acid

Clean Air Act (CAA) 112 regulated flammable substances: No products were found.

Clean Air Act (CAA) 112 regulated toxic substances: Nitric Acid

International lists :

SARA 313

Product name CAS number Concentration

SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall

include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.

Nitric Acid 7697-37-2 5 - 10

Form R - Reporting

requirements

Supplier notification

California prop. 65: No products were found.

Pennsylvania RTK: Nitric Acid: (environmental hazard, generic environmental hazard)

Massachusetts RTK: Nitric Acid

New Jersey: Nitric Acid

This product, (and its ingredients) is (are) listed on national inventories, or is (are)

exempted from being listed, Australia (AICS), in Europe (EINECS/ELINCS), in Korea

(TCCL), in Japan (METI), in the Philippines (RA6969).

State regulations :

Other information

Hazardous Material

Information System (U.S.A.)

National Fire Protection

Association (U.S.A.) Health

Special

Reactivity

Flammability

CAUSES SEVERE RESPIRATORY TRACT, EYE AND SKIN BURNS.

CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS:

LUNGS, MUCOUS MEMBRANES, RESPIRATORY TRACT, SKIN, ENDOTHELIUM, EYE,

LENS OR CORNEA, TEETH.

Label requirements (U.S.A.) :

16 .

ReferencesReferences

Date of issue

Date of previous issue

Version :

08/31/2006

06/30/2004

HMIS RATING

Physical Hazard

Health *3

Fire hazard

Personal protection D

ANSI Z400.1, MSDS Standard, 2004. - Manufacturer's Material Safety Data Sheet. -

29CFR Part1910.1200 OSHA MSDS Requirements. - 49CFR Table List of Hazardous

Materials, UN#, Proper Shipping Names, PG.

Notice to reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above named

supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the

information contained herein. Final determination of suitability of any material is the sole responsibility of the user.

All materials may present unknown hazards and should be used with caution. Although certain hazards are

described herein, we cannot guarantee that these are the only hazards that exist.

4- Extreme

3- Serious

2- Moderate

1- Slight

0- Minimal

See section 8 for more detailed

information on personal protection.

HAZARD RATINGS

Date of issue :08/31/2006 Page: 5/5

CHEMMATE500 716464 MSDS

716464 Msds 716464_MSDS 716464_MSDS MSDS s sunlightsupply 3:

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