Material Safety Data Sheet 16 Sections 717324 MSDS
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2017-03-09
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MATERIAL SAFETY DATA SHEET — 16 Sections –4– Product Identifier SECTION 12 — ECOLOGICAL INFORMATION SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Identifier [WHMIS Classification] Supernatural Brand Gro Aqua Class C - Oxidizer 11-6-16 [Aquatic Toxicity] Product Use Water soluble plant fertilizer Manufacturer’s Name Supplier’s Name Rapidgrow Industries Inc. Same as manufacturer. Street Address Street Address 20203 113B Ave. SECTION 13 — DISPOSAL CONSIDERATIONS City Province Maple Ridge Waste Disposal City Province BC Postal Code Emergency Telephone 604 465 1344/604 868 1698 V2X 0Z1 Date MSDS Prepared Postal Code Emergency Telephone MSDS Prepared By Phone Number 604 868 1698 Brian Franczuz 2012-10-12 SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS SECTION 14 — TRANSPORT INFORMATION Hazardous Ingredients (specific) % CAS Number Potassium Nitrate 21 Calcium Nitrate 40 7757-79-1 10124 - 37 - 5 10034-96-5 Special Shipping Information PIN TDG [DOT] [IMO] [ICAO] SECTION 15 — REGULATORY INFORMATION Manganese Sulfate 0.03 Zinc Sulfate Copper Sulfate Nitrilotricetic Acid 0.075 0.025 0.075 LD50 of Ingredient (specify species and route) Rat Oral, Rabbit Oral Rat Oral / Rabbit, Irritation eye ND Mouse/Oral Rat/Oral Rat/Oral 7446-19-7 7758-99-8 5064-31-3 LC50 of Ingredient (specify species) 3750 mg/kg Rat 1901 mg/kg Rabbit 3900mg/kg Rat 500mg/kg severe 2200mg/kg Mouse 300mg/kg Rat 1658 mg/kg Rat SECTION 3 — HAZARDS IDENTIFICATION [WHMIS Classification] [OSHA] Route of Entry [SERA] [TSCA] [Emergency Overview] This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by CPR. SECTION 16 — OTHER INFORMATION x Skin Contact ❐ ❐ Skin Absorption ❐x Eye Contact x❐ Inhalation ❐ x Ingestion Skin contact - Irritation could occur with prolonged exposure to dry fertilizer or solution. Eye Contact [WHMIS Symbols] Irritation could occur if dry fertilizer or solution contacts eyes. Inhalation - very low vapour activity, could produce noxious fumes and respiratory tract irritation if heated. Ingestion - excessive ingestion may [Potential Health Effects] result in health hazard. Effects may include nausea, vomiting, diahrrea, weakness or convulsions. SECTION 4 — FIRST AID MEASURES Skin Contact Remove contaminated clothing. Flush affected area with water for 15 minutes. Wash affected area with mild soap and water. Get medical attention if irritation develops or persists. Eye Contact Immediately flush eyes with plenty of water. Remove any contact lenses (if easy to do) and continue flushing for 15 minutes. Get medical attention if irritation develops or persists. Inhalation Remove person to fresh air. Seek medical attention immediately if breathing becomes difficult. Ingestion Immediately rinse mouth out with plenty of water. If within 30 minutes after ingestion, give person a small glass of water or milk. NEVER give anything by mouth to an unconscious person. Do not induce vomiting unless instructed to do so by a physician or poison center. Seek medical attention immediately. SAMPLE FORMAT PROVIDED BY THE WORKERS’ COMPENSATION BOARD OF BRITISH COLUMBIA 57M6 (6/99) [ Optional, not required under WHMIS ] Please continue on reverse side [ Optional, not required under WHMIS ] –2– Product Identifier SECTION 5 — FIRE FIGHTING MEASURES Flammable Means of Extinction SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES If yes, under which conditions? ❐ Yes –3– Product Identifier Physical State Odour and Appearance Odour Threshold (ppm) Specific Gravity Vapour Density (air = 1) Vapour Pressure (mmHg) Evaporation Rate Boiling Point (°C) Freezing Point (°C) pH Coefficient of Water/Oil Distribution [Solubility in Water] X No ❐ Use flooding quantities of water. Do not use water jet. Wear SCBA and full protective clothing. This material is an oxidizer and therefore increases the intensity of any fire or combustable substance Flashpoint (°C) and Method Upper Flammable Limit (% by volume) Lower Flammable Limit (% by volume) NA NA Autoignition Temperature (°C) NA Explosion Data — Sensitivity to Impact Explosion Data — Sensitivity to Static Discharge ND Hazardous Combustion Products SECTION 10 — STABILITY AND REACTIVITY Nitrates, nitrites, ammonia, carbon monoxide, sulfur oxides. [NFPA] Chemical Stability If no, under which conditions? ❐ Yes ❐ No Incompatibility with Other Substances SECTION 6 — ACCIDENTAL RELEASE MEASURES If yes, which ones? ❐ Yes ❐ No Leak and Spill Procedures Contain the spill. Avoid contact with combustibles, organics and ignition sources. Sweep up spilled material and use or dispose of in an approved manner. Prevent entry into waterways, sewers, basements or confined areas. Reactivity, and under what conditions? SECTION 7 — HANDLING AND STORAGE Hazardous Decomposition Products Handling Procedures and Equipment Avoid direct and prolonged contact with skin. SECTION 11 — TOXICOLOGICAL INFORMATION Storage Requirements Effects of Acute Exposure Store in cool, dry area in closed container or package. Keep containers closed at all times. Do not reuse containers. Store away from incompatible materials. Use with proper personal protective equipment. Keep out of reach of children. Effects of Chronic Exposure SECTION 8 — EXPOSURE CONTROL / PERSONAL PROTECTION Exposure Limits ❐ ACGIH TLV ❐ OSHA PEL ❐ Other (specify) Specific Engineering Controls (such as ventilation, enclosed process) Ventilate to control dust. Irritancy of Product Personal Protective Equipment x ❐ Gloves x ❐ Respirator x ❐ Eye ❐ Footwear If checked, please specify type ❐ Clothing ❐ Skin Sensitization Respiratory Sensitization Carcinogenicity — IARC Carcinogenicity — ACGIH Reproductive Toxicity Teratogenicity Embryotoxicity Mutagenicity Other Respiratory - Dust mask if conditions warrant. Eyes - Wear safety glasses to avoid eye contact. Do not wear contact lenses. Name of Synergistic Products/Effects Skin - Wear impermeable gloves to avoid skin contact. [ Optional, not required under WHMIS ] [ Optional, not required under WHMIS ] Please continue on reverse side –2– Product Identifier SECTION 5 — FIRE FIGHTING MEASURES Flammable SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES If yes, under which conditions? ❐ Yes –3– Product Identifier Physical State ❐ No Odour and Appearance Means of Extinction Odour Threshold (ppm) white, yellowish powder Solid Specific Gravity Vapour Density (air = 1) NA Vapour Pressure (mmHg) NA ND ND Flashpoint (°C) and Method Upper Flammable Limit (% by volume) Lower Flammable Limit (% by volume) Evaporation Rate Boiling Point (°C) Freezing Point (°C) ND NA Autoignition Temperature (°C) Explosion Data — Sensitivity to Impact Explosion Data — Sensitivity to Static Discharge pH Coefficient of Water/Oil Distribution NA [Solubility in Water] ND Hazardous Combustion Products SECTION 10 — STABILITY AND REACTIVITY [NFPA] Chemical Stability If no, under which conditions? ❐ Yes ❐xNo Incompatibility with Other Substances SECTION 6 — ACCIDENTAL RELEASE MEASURES x Yes ❐ Leak and Spill Procedures ❐ No Exposure to heat may result in build up of dangerous pressures. If yes, whichoxidizer, ones? Strong reacts violently upon contact of many organic substances, particularly textile and paper. Strong acids, strong alkalies, oxidizers, organics. Reactivity, and under what conditions? Moist, wet conditions, Fire. SECTION 7 — HANDLING AND STORAGE Hazardous Decomposition Products Handling Procedures and Equipment Ammonia, oxides of nitrogen Avoid heat, flame, ignition sources, shock and incompatibles. SECTION 11 — TOXICOLOGICAL INFORMATION Storage Requirements Effects of Acute Exposure Skin Contact - Irritation could occur with prolonged exposure to dry fertilizer or fertilizer solution. Skin Absorption - Not known to be absorbed through the skin. Eye Contact - Irritation could occur if fertilizer solution is splashed in eyes or dry product contacts eyes. Inhalation - Very ow vapour activity. If heated could release noxious fumes, can cause respiratory tract irritation. Ingestion - Excessive ingestion must occur before any health hazard results, effects of overexposure may include nausea, vomiting, Effects of Chronic Exposure diarrhea, weakness or convulsions. SECTION 8 — EXPOSURE CONTROL / PERSONAL PROTECTION Exposure Limits ❐ ACGIH TLV ❐ OSHA PEL ❐ Other (specify) Specific Engineering Controls (such as ventilation, enclosed process) Nitrilotriacetic Acid and it's salts were determined to be "possibly carcogenic to humans" by IARC a compound which "may reasonably be anticipated to be a carcinogen" By NTP and a "select Carcinogen" by OSHA. Boric Acid may cause birth defects and may impair male fertility, based on animal data. Calcium Nitrate (10124-37-5) NTP Carcinogen no known, anticipated. IARC Category, none. Oral Rat LD50: 3900 mg/kg. Irritation eye Rabbit 500mg/L 24H severe. Irritancy of Product May cause minor irritation Skin Sensitization May cause minor irritation Personal Protective Equipment ❐ Gloves ❐ Respirator ❐ Eye ❐ Footwear ❐ Clothing ❐ Carcinogenicity — IARC Other None known. Reproductive Toxicity If checked, please specify type None known. Embryotoxicity None known. Respiratory Sensitization Very low, if heated could cause irritation Carcinogenicity — ACGIH None known. Teratogenicity None known. Mutagenicity None known. Name of Synergistic Products/Effects ND [ Optional, not required under WHMIS ] [ Optional, not required under WHMIS ] Please continue on reverse side MATERIAL SAFETY DATA SHEET — 16 Sections –4– Product Identifier SECTION 12 — ECOLOGICAL INFORMATION SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION [Aquatic Toxicity] Product Identifier Prevent entry into waterways, sewers, basements or confined areas. The LC50/96-hour values for fish are over 100mg/l. [WHMIS Classification] Product Use SECTION 13 — DISPOSAL CONSIDERATIONS Manufacturer’s Name Supplier’s Name Street Address Street Address City Waste Disposal Province Postal Code Dispose of in non-crop areas away from waterways, in accordance with federal, provincial and local regulations. City Emergency Telephone Date MSDS Prepared Province Postal Code Emergency Telephone MSDS Prepared By Phone Number SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Ingredients (specific) SECTION 14 — TRANSPORT INFORMATION Special Shipping Information Placard 5.1 oxidizer Packing Group III Calcium nitrate mixture. UN#1454, Potassium Nitrate mixture. UN# 1486 TDG [DOT] [IMO] [ICAO] % CAS Number LD50 of Ingredient (specify species and route) LC50 of Ingredient (specify species) PIN Domestic Land SECTION 15 — REGULATORY INFORMATION SECTION 3 — HAZARDS IDENTIFICATION [WHMIS Classification] [OSHA] Route of Entry [SERA] [TSCA] [Emergency Overview] Class C oxidizer 311/312 ❐ Skin Contact ❐ Skin Absorption ❐ Eye Contact ❐ Inhalation ❐ Ingestion 12(b) This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by CPR. [WHMIS Symbols] [Potential Health Effects] SECTION 16 — OTHER INFORMATION NA = Not Applicable. ND = Not Determined. SECTION 4 — FIRST AID MEASURES Skin Contact Eye Contact Inhalation Ingestion SAMPLE FORMAT PROVIDED BY THE WORKERS’ COMPENSATION BOARD OF BRITISH COLUMBIA 57M6 (6/99) [ Optional, not required under WHMIS ] Please continue on reverse side [ Optional, not required under WHMIS ]
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