Material Safety Data Sheet 16 Sections 717324 MSDS

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MATERIAL SAFETY DATA SHEET — 16 Sections

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Product Identifier
SECTION 12 — ECOLOGICAL INFORMATION

SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Identifier
[WHMIS Classification]
Supernatural
Brand Gro Aqua
Class C - Oxidizer
11-6-16

[Aquatic Toxicity]

Product Use

Water soluble plant fertilizer

Manufacturer’s Name

Supplier’s Name

Rapidgrow Industries Inc.

Same as manufacturer.

Street Address

Street Address

20203 113B Ave.

SECTION 13 — DISPOSAL CONSIDERATIONS

City

Province

Maple Ridge

Waste Disposal

City

Province

BC

Postal Code

Emergency Telephone

604 465 1344/604 868 1698

V2X 0Z1
Date MSDS Prepared

Postal Code

Emergency Telephone

MSDS Prepared By

Phone Number

604 868 1698

Brian Franczuz

2012-10-12

SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS
SECTION 14 — TRANSPORT INFORMATION

Hazardous Ingredients (specific)

%

CAS Number

Potassium Nitrate

21

Calcium Nitrate

40

7757-79-1
10124 - 37 - 5
10034-96-5

Special Shipping Information

PIN

TDG

[DOT]

[IMO]

[ICAO]

SECTION 15 — REGULATORY INFORMATION

Manganese Sulfate

0.03

Zinc Sulfate
Copper Sulfate
Nitrilotricetic Acid

0.075
0.025
0.075

LD50 of Ingredient
(specify species and route)

Rat Oral, Rabbit Oral
Rat Oral / Rabbit,
Irritation eye
ND

Mouse/Oral
Rat/Oral
Rat/Oral

7446-19-7
7758-99-8
5064-31-3

LC50 of Ingredient
(specify species)

3750 mg/kg Rat
1901 mg/kg Rabbit
3900mg/kg Rat
500mg/kg severe
2200mg/kg Mouse
300mg/kg Rat
1658 mg/kg Rat

SECTION 3 — HAZARDS IDENTIFICATION

[WHMIS Classification]

[OSHA]

Route of Entry

[SERA]

[TSCA]

[Emergency Overview]

This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations (CPR) and the MSDS contains all of the information required by CPR.

SECTION 16 — OTHER INFORMATION

x Skin Contact
❐

❐ Skin Absorption

❐x Eye Contact

x❐ Inhalation

❐
x Ingestion

Skin contact - Irritation could occur with prolonged exposure to dry fertilizer or solution. Eye Contact [WHMIS
Symbols]
Irritation
could occur if dry fertilizer or solution contacts eyes. Inhalation - very low vapour activity, could
produce noxious fumes and respiratory tract irritation if heated. Ingestion - excessive ingestion may
[Potential Health Effects]
result in health hazard. Effects may include nausea, vomiting, diahrrea, weakness or convulsions.

SECTION 4 — FIRST AID MEASURES
Skin Contact
Remove contaminated clothing. Flush affected area with water for 15 minutes. Wash affected area with mild soap and water. Get medical attention if irritation develops or persists.

Eye Contact
Immediately flush eyes with plenty of water. Remove any contact lenses (if easy to do) and continue flushing for 15 minutes. Get medical attention if irritation develops or persists.

Inhalation
Remove person to fresh air. Seek medical attention immediately if breathing becomes difficult.

Ingestion Immediately rinse mouth out with plenty of water. If within 30 minutes after ingestion, give person a small glass of water or milk. NEVER give anything by mouth to an unconscious person. Do not induce
vomiting unless instructed to do so by a physician or poison center. Seek medical attention immediately.

SAMPLE FORMAT PROVIDED BY THE WORKERS’ COMPENSATION BOARD OF BRITISH COLUMBIA

57M6 (6/99)
[ Optional, not required under WHMIS ]

Please continue on reverse side
[ Optional, not required under WHMIS ]

–2–

Product Identifier
SECTION 5 — FIRE FIGHTING MEASURES
Flammable

Means of Extinction

SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES

If yes, under which conditions?

❐ Yes

–3–

Product Identifier
Physical State

Odour and Appearance

Odour Threshold (ppm)

Specific Gravity

Vapour Density (air = 1)

Vapour Pressure (mmHg)

Evaporation Rate

Boiling Point (°C)

Freezing Point (°C)

pH

Coefficient of Water/Oil Distribution

[Solubility in Water]

X No
❐

Use flooding quantities of water. Do not use water jet. Wear SCBA and full protective
clothing. This material is an oxidizer
and therefore increases the intensity of any fire or combustable substance

Flashpoint (°C) and Method

Upper Flammable Limit (% by volume)

Lower Flammable Limit (% by volume)

NA

NA
Autoignition Temperature (°C)

NA

Explosion Data — Sensitivity to Impact

Explosion Data — Sensitivity to Static Discharge

ND
Hazardous Combustion Products

SECTION 10 — STABILITY AND REACTIVITY

Nitrates, nitrites, ammonia, carbon monoxide, sulfur oxides.
[NFPA]

Chemical Stability

If no, under which conditions?

❐ Yes

❐ No

Incompatibility with Other Substances

SECTION 6 — ACCIDENTAL RELEASE MEASURES

If yes, which ones?

❐ Yes

❐ No

Leak and Spill Procedures

Contain the spill. Avoid contact with combustibles, organics and ignition sources. Sweep up spilled material and use or dispose of in an
approved manner. Prevent entry into waterways, sewers, basements or confined areas.
Reactivity, and under what conditions?

SECTION 7 — HANDLING AND STORAGE
Hazardous Decomposition Products

Handling Procedures and Equipment

Avoid direct and prolonged contact with skin.

SECTION 11 — TOXICOLOGICAL INFORMATION
Storage Requirements

Effects of Acute Exposure

Store in cool, dry area in closed container or package. Keep containers closed at all times. Do not reuse containers.
Store away from incompatible materials. Use with proper personal protective equipment. Keep out of reach of children.

Effects of Chronic Exposure

SECTION 8 — EXPOSURE CONTROL / PERSONAL PROTECTION
Exposure Limits

❐ ACGIH TLV

❐ OSHA PEL

❐ Other (specify)

Specific Engineering Controls (such as ventilation, enclosed process)

Ventilate to control dust.
Irritancy of Product

Personal Protective Equipment

x
❐

Gloves

x
❐

Respirator

x
❐

Eye

❐

Footwear

If checked, please specify type

❐

Clothing

❐

Skin Sensitization

Respiratory Sensitization

Carcinogenicity — IARC

Carcinogenicity — ACGIH

Reproductive Toxicity

Teratogenicity

Embryotoxicity

Mutagenicity

Other

Respiratory - Dust mask if conditions warrant.

Eyes - Wear safety glasses to avoid eye contact. Do not wear contact lenses.
Name of Synergistic Products/Effects

Skin - Wear impermeable gloves to avoid skin contact.
[ Optional, not required under WHMIS ]

[ Optional, not required under WHMIS ]

Please continue on reverse side

–2–

Product Identifier
SECTION 5 — FIRE FIGHTING MEASURES
Flammable

SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES

If yes, under which conditions?

❐ Yes

–3–

Product Identifier
Physical State

❐ No

Odour and Appearance

Means of Extinction

Odour Threshold (ppm)

white, yellowish powder

Solid
Specific Gravity

Vapour Density (air = 1)

NA
Vapour Pressure (mmHg)

NA

ND

ND

Flashpoint (°C) and Method

Upper Flammable Limit (% by volume)

Lower Flammable Limit (% by volume)

Evaporation Rate

Boiling Point (°C)

Freezing Point (°C)

ND

NA

Autoignition Temperature (°C)

Explosion Data — Sensitivity to Impact

Explosion Data — Sensitivity to Static Discharge

pH

Coefficient of Water/Oil Distribution

NA
[Solubility in Water]

ND
Hazardous Combustion Products

SECTION 10 — STABILITY AND REACTIVITY

[NFPA]

Chemical Stability

If no, under which conditions?

❐ Yes

❐xNo

Incompatibility with Other Substances

SECTION 6 — ACCIDENTAL RELEASE MEASURES

x Yes
❐

Leak and Spill Procedures

❐ No

Exposure to heat may result in build up of dangerous pressures.
If yes, whichoxidizer,
ones?
Strong
reacts violently upon contact of many organic
substances, particularly textile and paper.

Strong acids, strong alkalies, oxidizers, organics.

Reactivity, and under what conditions?

Moist, wet conditions, Fire.
SECTION 7 — HANDLING AND STORAGE
Hazardous Decomposition Products

Handling Procedures and Equipment

Ammonia, oxides of nitrogen
Avoid heat, flame, ignition sources, shock and incompatibles.
SECTION 11 — TOXICOLOGICAL INFORMATION
Storage Requirements

Effects of Acute Exposure

Skin Contact - Irritation could occur with prolonged exposure to dry fertilizer or fertilizer solution.
Skin Absorption - Not known to be absorbed through the skin.
Eye Contact - Irritation could occur if fertilizer solution is splashed in eyes or dry product contacts eyes.
Inhalation - Very ow vapour activity. If heated could release noxious fumes, can cause respiratory tract irritation.
Ingestion - Excessive ingestion must occur before any health hazard results, effects of overexposure may include nausea, vomiting,
Effects of Chronic Exposure diarrhea, weakness or convulsions.

SECTION 8 — EXPOSURE CONTROL / PERSONAL PROTECTION
Exposure Limits

❐ ACGIH TLV

❐ OSHA PEL

❐ Other (specify)

Specific Engineering Controls (such as ventilation, enclosed process)

Nitrilotriacetic Acid and it's salts were determined to be "possibly carcogenic to humans" by IARC a
compound which "may reasonably be anticipated to be a carcinogen" By NTP and a "select Carcinogen"
by OSHA. Boric Acid may cause birth defects and may impair male fertility, based on animal data.
Calcium Nitrate (10124-37-5) NTP Carcinogen no known, anticipated. IARC Category, none.
Oral Rat LD50: 3900 mg/kg. Irritation eye Rabbit 500mg/L 24H severe.
Irritancy of Product

May cause minor irritation

Skin Sensitization

May cause minor irritation
Personal Protective Equipment

❐

Gloves

❐

Respirator

❐

Eye

❐

Footwear

❐

Clothing

❐

Carcinogenicity — IARC
Other

None known.
Reproductive Toxicity

If checked, please specify type

None known.
Embryotoxicity

None known.

Respiratory Sensitization

Very low, if heated could cause irritation

Carcinogenicity — ACGIH

None known.
Teratogenicity

None known.
Mutagenicity

None known.

Name of Synergistic Products/Effects

ND
[ Optional, not required under WHMIS ]

[ Optional, not required under WHMIS ]

Please continue on reverse side

MATERIAL SAFETY DATA SHEET — 16 Sections

–4–

Product Identifier
SECTION 12 — ECOLOGICAL INFORMATION

SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

[Aquatic Toxicity]

Product Identifier

Prevent entry into waterways, sewers, basements or confined areas.
The LC50/96-hour values for fish are over 100mg/l.

[WHMIS Classification]

Product Use

SECTION 13 — DISPOSAL CONSIDERATIONS

Manufacturer’s Name

Supplier’s Name

Street Address

Street Address

City

Waste Disposal

Province

Postal Code

Dispose of in non-crop areas away from waterways, in accordance with federal, provincial and local regulations.

City

Emergency Telephone

Date MSDS Prepared

Province

Postal Code

Emergency Telephone

MSDS Prepared By

Phone Number

SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Ingredients (specific)

SECTION 14 — TRANSPORT INFORMATION
Special Shipping Information
Placard 5.1 oxidizer Packing Group III
Calcium nitrate mixture. UN#1454, Potassium Nitrate mixture. UN# 1486
TDG

[DOT]

[IMO]

[ICAO]

%

CAS Number

LD50 of Ingredient
(specify species and route)

LC50 of Ingredient
(specify species)

PIN

Domestic Land

SECTION 15 — REGULATORY INFORMATION

SECTION 3 — HAZARDS IDENTIFICATION

[WHMIS Classification]

[OSHA]

Route of Entry

[SERA]

[TSCA]

[Emergency Overview]

Class C oxidizer
311/312

❐ Skin Contact

❐ Skin Absorption

❐ Eye Contact

❐ Inhalation

❐ Ingestion

12(b)

This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations (CPR) and the MSDS contains all of the information required by CPR.

[WHMIS Symbols]

[Potential Health Effects]

SECTION 16 — OTHER INFORMATION
NA = Not Applicable.
ND = Not Determined.

SECTION 4 — FIRST AID MEASURES
Skin Contact

Eye Contact

Inhalation

Ingestion

SAMPLE FORMAT PROVIDED BY THE WORKERS’ COMPENSATION BOARD OF BRITISH COLUMBIA

57M6 (6/99)
[ Optional, not required under WHMIS ]

Please continue on reverse side
[ Optional, not required under WHMIS ]



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Page Count                      : 4
Title                           : Material safety data sheet -- 16 sections
Author                          : WCB of BC
Subject                         : Blank material safety data sheet - 16 sections
Producer                        : Mac OS X 10.7.5 Quartz PDFContext
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Create Date                     : 2012:11:05 14:12:56Z
Modify Date                     : 2012:11:05 14:12:56Z
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