Material Safety Data Sheet 16 Sections 717324 MSDS

717324 Msds 717324_MSDS 717324_MSDS MSDS s sunlightsupply 3:

2017-03-09

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MATERIAL SAFETY DATA SHEET — 16 Sections
SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Identifier [WHMIS Classification]
Product Use
Manufacturer’s Name Supplier’s Name
Street Address Street Address
City Province City Province
Postal Code Emergency Telephone Postal Code Emergency Telephone
Date MSDS Prepared MSDS Prepared By Phone Number
SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Ingredients (specific) % CAS Number LD50 of Ingredient LC50 of Ingredient
(specify species and route) (specify species)
SECTION 3 — HAZARDS IDENTIFICATION
Route of Entry
[Emergency Overview]
[WHMIS Symbols]
[Potential Health Effects]
SECTION 4 — FIRST AID MEASURES
Skin Contact
Eye Contact
Inhalation
Ingestion
SAMPLE FORMAT PROVIDED BY THE WORKERS’ COMPENSATION BOARD OF BRITISH COLUMBIA
57M6 (6/99) Please continue on reverse side
❐Skin Contact ❐Skin Absorption ❐Eye Contact ❐Inhalation ❐Ingestion
SECTION 12 — ECOLOGICAL INFORMATION
[Aquatic Toxicity]
SECTION 13 — DISPOSAL CONSIDERATIONS
Waste Disposal
SECTION 14 — TRANSPORT INFORMATION
Special Shipping Information
PIN
TDG [DOT]
[IMO] [ICAO]
SECTION 15 — REGULATORY INFORMATION
[WHMIS Classification] [OSHA]
[SERA] [TSCA]
This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations (CPR) and the MSDS contains all of the information required by CPR.
SECTION 16 — OTHER INFORMATION
– 4 –
[ Optional, not required under WHMIS ][ Optional, not required under WHMIS ]
Product Identifier
Supernatural Brand Gro Aqua
11-6-16
Water soluble plant fertilizer
Rapidgrow Industries Inc.
20203 113B Ave.
Maple Ridge
BC
V2X 0Z1
Same as manufacturer.
Immediately flush eyes with plenty of water. Remove any contact lenses (if easy to do) and continue flushing for 15 minutes. Get medical attention if irritation develops or persists.
Immediately rinse mouth out with plenty of water. If within 30 minutes after ingestion, give person a small glass of water or milk. NEVER give anything by mouth to an unconscious person. Do not induce
vomiting unless instructed to do so by a physician or poison center. Seek medical attention immediately.
Remove contaminated clothing. Flush affected area with water for 15 minutes. Wash affected area with mild soap and water. Get medical attention if irritation develops or persists.
Remove person to fresh air. Seek medical attention immediately if breathing becomes difficult.
Potassium Nitrate
7757-79-1
Class C - Oxidizer
x
x
x
x
Skin contact - Irritation could occur with prolonged exposure to dry fertilizer or solution. Eye Contact -
Irritation could occur if dry fertilizer or solution contacts eyes. Inhalation - very low vapour activity, could
produce noxious fumes and respiratory tract irritation if heated. Ingestion - excessive ingestion may
result in health hazard. Effects may include nausea, vomiting, diahrrea, weakness or convulsions.
Calcium Nitrate
10124 - 37 - 5
3750 mg/kg Rat
Rat Oral,
Rabbit Oral
Rat Oral / Rabbit,
Irritation eye
1901 mg/kg Rabbit
3900mg/kg Rat
500mg/kg severe
Manganese Sulfate
0.03
10034-96-5
ND
Zinc Sulfate
0.075
7446-19-7
Mouse/Oral
2200mg/kg Mouse
Copper Sulfate
0.025
7758-99-8
Rat/Oral
300mg/kg Rat
Nitrilotricetic Acid
0.075
5064-31-3
Rat/Oral
1658 mg/kg Rat
Brian Franczuz
604 868 1698
21
40
604 465 1344/604 868 1698
SECTION 5 — FIRE FIGHTING MEASURES
Flammable If yes, under which conditions?
Means of Extinction
Flashpoint (°C) and Method Upper Flammable Limit (% by volume) Lower Flammable Limit (% by volume)
Autoignition Temperature (°C) Explosion Data — Sensitivity to Impact Explosion Data — Sensitivity to Static Discharge
Hazardous Combustion Products
[NFPA]
SECTION 6 — ACCIDENTAL RELEASE MEASURES
Leak and Spill Procedures
SECTION 7 — HANDLING AND STORAGE
Handling Procedures and Equipment
Storage Requirements
SECTION 8 — EXPOSURE CONTROL / PERSONAL PROTECTION
Exposure Limits
❐ ACGIH TLV ❐ OSHA PEL ❐ Other (specify)
Specific Engineering Controls (such as ventilation, enclosed process)
Personal Protective Equipment
If checked, please specify type
❐Gloves ❐Respirator ❐Eye ❐Footwear ❐Clothing ❐Other
SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES
Physical State Odour and Appearance Odour Threshold (ppm)
Specific Gravity Vapour Density (air = 1) Vapour Pressure (mmHg)
Evaporation Rate Boiling Point (°C) Freezing Point (°C)
pH Coefficient of Water/Oil Distribution [Solubility in Water]
SECTION 10 — STABILITY AND REACTIVITY
Chemical Stability If no, under which conditions?
Incompatibility with Other Substances If yes, which ones?
Reactivity, and under what conditions?
Hazardous Decomposition Products
SECTION 11 — TOXICOLOGICAL INFORMATION
Effects of Acute Exposure
Effects of Chronic Exposure
Irritancy of Product
Skin Sensitization Respiratory Sensitization
Carcinogenicity — IARC Carcinogenicity — ACGIH
Reproductive Toxicity Teratogenicity
Embryotoxicity Mutagenicity
Name of Synergistic Products/Effects
Please continue on reverse side
❐Yes ❐No
❐Yes ❐No
– 2 – – 3 –
❐Yes ❐No
[ Optional, not required under WHMIS ]
[ Optional, not required under WHMIS ]
Product Identifier Product Identifier
X
Store in cool, dry area in closed container or package. Keep containers closed at all times. Do not reuse containers.
Store away from incompatible materials. Use with proper personal protective equipment. Keep out of reach of children.
Use flooding quantities of water. Do not use water jet. Wear SCBA and full protective
clothing. This material is an oxidizer
and therefore increases the intensity of any fire or combustable substance
Nitrates, nitrites, ammonia, carbon monoxide, sulfur oxides.
Contain the spill. Avoid contact with combustibles, organics and ignition sources. Sweep up spilled material and use or dispose of in an
approved manner. Prevent entry into waterways, sewers, basements or confined areas.
Ventilate to control dust.
x
x
x
Respiratory - Dust mask if conditions warrant.
Eyes - Wear safety glasses to avoid eye contact. Do not wear contact lenses.
Skin - Wear impermeable gloves to avoid skin contact.
Avoid direct and prolonged contact with skin.
NA
NA
NA
ND
SECTION 5 — FIRE FIGHTING MEASURES
Flammable If yes, under which conditions?
Means of Extinction
Flashpoint (°C) and Method Upper Flammable Limit (% by volume) Lower Flammable Limit (% by volume)
Autoignition Temperature (°C) Explosion Data — Sensitivity to Impact Explosion Data — Sensitivity to Static Discharge
Hazardous Combustion Products
[NFPA]
SECTION 6 — ACCIDENTAL RELEASE MEASURES
Leak and Spill Procedures
SECTION 7 — HANDLING AND STORAGE
Handling Procedures and Equipment
Storage Requirements
SECTION 8 — EXPOSURE CONTROL / PERSONAL PROTECTION
Exposure Limits
❐ ACGIH TLV ❐ OSHA PEL ❐ Other (specify)
Specific Engineering Controls (such as ventilation, enclosed process)
Personal Protective Equipment
If checked, please specify type
❐Gloves ❐Respirator ❐Eye ❐Footwear ❐Clothing ❐Other
SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES
Physical State Odour and Appearance Odour Threshold (ppm)
Specific Gravity Vapour Density (air = 1) Vapour Pressure (mmHg)
Evaporation Rate Boiling Point (°C) Freezing Point (°C)
pH Coefficient of Water/Oil Distribution [Solubility in Water]
SECTION 10 — STABILITY AND REACTIVITY
Chemical Stability If no, under which conditions?
Incompatibility with Other Substances If yes, which ones?
Reactivity, and under what conditions?
Hazardous Decomposition Products
SECTION 11 — TOXICOLOGICAL INFORMATION
Effects of Acute Exposure
Effects of Chronic Exposure
Irritancy of Product
Skin Sensitization Respiratory Sensitization
Carcinogenicity — IARC Carcinogenicity — ACGIH
Reproductive Toxicity Teratogenicity
Embryotoxicity Mutagenicity
Name of Synergistic Products/Effects
Please continue on reverse side
❐Yes ❐No
❐Yes ❐No
– 2 – – 3 –
❐Yes ❐No
[ Optional, not required under WHMIS ]
[ Optional, not required under WHMIS ]
Product Identifier Product Identifier
x
Strong acids, strong alkalies, oxidizers, organics.
None known.
None known.
None known.
None known.
None known.
ND
Solid
None known.
Skin Contact - Irritation could occur with prolonged exposure to dry fertilizer or fertilizer solution.
Skin Absorption - Not known to be absorbed through the skin.
Eye Contact - Irritation could occur if fertilizer solution is splashed in eyes or dry product contacts eyes.
Inhalation - Very ow vapour activity. If heated could release noxious fumes, can cause respiratory tract irritation.
Ingestion - Excessive ingestion must occur before any health hazard results, effects of overexposure may include nausea, vomiting,
diarrhea, weakness or convulsions.
ND
ND
ND
ND
NA
NA
NA
NA
white, yellowish powder
May cause minor irritation
May cause minor irritation
Very low, if heated could cause irritation
Nitrilotriacetic Acid and it's salts were determined to be "possibly carcogenic to humans" by IARC a
compound which "may reasonably be anticipated to be a carcinogen" By NTP and a "select Carcinogen"
by OSHA. Boric Acid may cause birth defects and may impair male fertility, based on animal data.
Calcium Nitrate (10124-37-5) NTP Carcinogen no known, anticipated. IARC Category, none.
Oral Rat LD50: 3900 mg/kg. Irritation eye Rabbit 500mg/L 24H severe.
Ammonia, oxides of nitrogen
x
Exposure to heat may result in build up of dangerous pressures.
Strong oxidizer, reacts violently upon contact of many organic
substances, particularly textile and paper.
Avoid heat, flame, ignition sources, shock and incompatibles.
Moist, wet conditions, Fire.
MATERIAL SAFETY DATA SHEET — 16 Sections
SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Identifier [WHMIS Classification]
Product Use
Manufacturer’s Name Supplier’s Name
Street Address Street Address
City Province City Province
Postal Code Emergency Telephone Postal Code Emergency Telephone
Date MSDS Prepared MSDS Prepared By Phone Number
SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Ingredients (specific) % CAS Number LD50 of Ingredient LC50 of Ingredient
(specify species and route) (specify species)
SECTION 3 — HAZARDS IDENTIFICATION
Route of Entry
[Emergency Overview]
[WHMIS Symbols]
[Potential Health Effects]
SECTION 4 — FIRST AID MEASURES
Skin Contact
Eye Contact
Inhalation
Ingestion
SAMPLE FORMAT PROVIDED BY THE WORKERS’ COMPENSATION BOARD OF BRITISH COLUMBIA
57M6 (6/99) Please continue on reverse side
❐Skin Contact ❐Skin Absorption ❐Eye Contact ❐Inhalation ❐Ingestion
SECTION 12 — ECOLOGICAL INFORMATION
[Aquatic Toxicity]
SECTION 13 — DISPOSAL CONSIDERATIONS
Waste Disposal
SECTION 14 — TRANSPORT INFORMATION
Special Shipping Information
PIN
TDG [DOT]
[IMO] [ICAO]
SECTION 15 — REGULATORY INFORMATION
[WHMIS Classification] [OSHA]
[SERA] [TSCA]
This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations (CPR) and the MSDS contains all of the information required by CPR.
SECTION 16 — OTHER INFORMATION
– 4 –
[ Optional, not required under WHMIS ][ Optional, not required under WHMIS ]
Product Identifier
Dispose of in non-crop areas away from waterways, in accordance with federal, provincial and local regulations.
NA = Not Applicable.
ND = Not Determined.
Prevent entry into waterways
, sewers, basements or confined areas.
Class C oxidizer
Calcium nitrate mixture. UN#1454, Potassium Nitrate mixture. UN# 1486
12(b)
311/312
The LC50/96-hour values for fish are over 100mg/l.
Domestic Land
Placard 5.1 oxidizer Packing Group III

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