Material Safety Data Sheet 16 Sections 717380 MSDS
717380 Msds 717380_MSDS 717380_MSDS MSDS s sunlightsupply 3:
2017-03-09
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MATERIAL SAFETY DATA SHEET — 16 Sections –4– Product Identifier SECTION 12 — ECOLOGICAL INFORMATION SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION [Aquatic Toxicity] Product Identifier Product Use [WHMIS Classification] Supernatural Brand Superleach 0-0-1 Not Controled Water soluble plant fertilizer Manufacturer’s Name Supplier’s Name Rapidgrow Industries Inc. Same as manufacturer. Street Address Street Address 20203 113B Ave. SECTION 13 — DISPOSAL CONSIDERATIONS City Province Maple Ridge Waste Disposal City Province BC Postal Code Emergency Telephone 604 465 1344/604 868 1689 V2X 0Z1 Date MSDS Prepared Postal Code Emergency Telephone MSDS Prepared By 2012-10-13 Phone Number 604 868 1698 Brian Franczuz SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Ingredients (specific) SECTION 14 — TRANSPORT INFORMATION Special Shipping Information PIN TDG [DOT] [IMO] [ICAO] % Magnesium Sulfate 97.8 7487-88-9 Potassium Chloride Potassium Sulfate 1.0 7447-40-7 1.0 7778-80-5 0.2 77-92-9 Citric Acid SECTION 15 — REGULATORY INFORMATION CAS Number LD50 of Ingredient (specify species and route) LC50 of Ingredient (specify species) ND Oral LD50: Acute 2500 g/kg [Guinea Pig], 2600 mg/kg [Rat}, 1500 mg/kg [Mouse] Oral LD50 Acute: 6600mg/kg [Rat] Oral LD50 Acute: 3000mg/kg [Rat] SECTION 3 — HAZARDS IDENTIFICATION [WHMIS Classification] [OSHA] Route of Entry [SERA] [TSCA] [Emergency Overview] ❐x Skin Contact x Skin Absorption ❐ ❐ x Eye Contact ❐ x Inhalation ❐x Ingestion Skin Contact - Irritation could occur with prolonged exposure to dry fertilizer or solution. Eye contact - Irritation This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by CPR. [WHMIS Symbols] [Potential Health Effects] SECTION 16 — OTHER INFORMATION could occur if dry fertilizer or solution contacts eyes. Inhalation - very low vapour activity, could produce noxious fumes and respiratory tract irritation if heated. Ingestion - Excessive ingestion may result in health hazard. Effects may include nausea, vomiting, diahrrea, weakness or convulsions. Skin Absorrption - Potassium Sulfate can be absorbed through the skin causing potential health hazard. SECTION 4 — FIRST AID MEASURES Skin Contact Remove contaminated clothing. Flush affected area with water for 15 minutes. Wash affected area with mild soap and water. Get medical attention if irritation develops or persists. Eye Contact Immediately flush eyes with plenty of water. Remove any contact lenses (if easy to do) and continue flushing for 15 minutes. Get medical attention if irritation develops or persists. Inhalation If ammonia gas is inhaled from heated fertilizer and breathing has stopped, begin artificial respiration. If breathing is laboured, bive oxygen and seek medical attention. Ingestion Immediately rinse mouth out with plenty of water. If within 30 minutes after ingestion, give person a small glass of water or milk. NEVER give anything by mouth to an unconscious person. Do not induce vomiting unless instructed to do so by a physician or poison center. Seek medical attention immediately. SAMPLE FORMAT PROVIDED BY THE WORKERS’ COMPENSATION BOARD OF BRITISH COLUMBIA 57M6 (6/99) [ Optional, not required under WHMIS ] Please continue on reverse side [ Optional, not required under WHMIS ] –2– Product Identifier SECTION 5 — FIRE FIGHTING MEASURES Flammable Means of Extinction SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES If yes, under which conditions? ❐ Yes –3– Product Identifier Physical State Odour and Appearance Odour Threshold (ppm) Specific Gravity Vapour Density (air = 1) Vapour Pressure (mmHg) Evaporation Rate Boiling Point (°C) Freezing Point (°C) pH Coefficient of Water/Oil Distribution [Solubility in Water] X No ❐ Use flooding quantities of water. Do not use water jet. Wear SCBA and full protective clothing if product is involved in a fire. This material is an oxidizer and therefore increases the intensity of any fire or combustable substance Flashpoint (°C) and Method Upper Flammable Limit (% by volume) Lower Flammable Limit (% by volume) NA NA Autoignition Temperature (°C) NA Explosion Data — Sensitivity to Impact Explosion Data — Sensitivity to Static Discharge ND Hazardous Combustion Products Ammonia, oxides of nitrogen and phosphorus, carbon monoxide, hydrogen cyanide. [NFPA] SECTION 10 — STABILITY AND REACTIVITY Chemical Stability If no, under which conditions? ❐ Yes ❐ No Incompatibility with Other Substances SECTION 6 — ACCIDENTAL RELEASE MEASURES If yes, which ones? ❐ Yes ❐ No Leak and Spill Procedures Contain the spill. Sweep up spilled material and use or dispose of in an approved manner. Prevent entry into waterways, sewers, basements or confined areas. Reactivity, and under what conditions? SECTION 7 — HANDLING AND STORAGE Hazardous Decomposition Products Handling Procedures and Equipment Avoid direct and prolonged contact with skin. SECTION 11 — TOXICOLOGICAL INFORMATION Storage Requirements Effects of Acute Exposure Store in cool, dry area in closed container or package. Keep containers closed at all times. Do not reuse containers. Store away from incompatible materials. Use with proper personal protective equipment. Keep out of reach of children. Effects of Chronic Exposure SECTION 8 — EXPOSURE CONTROL / PERSONAL PROTECTION Exposure Limits ❐ ACGIH TLV ❐ OSHA PEL ❐ Other (specify) Specific Engineering Controls (such as ventilation, enclosed process) Ventilate to control dust. Irritancy of Product Personal Protective Equipment x ❐ Gloves x ❐ Respirator x ❐ Eye ❐ Footwear If checked, please specify type ❐ Clothing ❐ Skin Sensitization Respiratory Sensitization Carcinogenicity — IARC Carcinogenicity — ACGIH Reproductive Toxicity Teratogenicity Embryotoxicity Mutagenicity Other Respiratory - Dust mask if conditions warrant. Eyes - Wear safety glasses to avoid eye contact. Do not wear contact lenses. Name of Synergistic Products/Effects Skin - Wear impermeable gloves to avoid skin contact. [ Optional, not required under WHMIS ] [ Optional, not required under WHMIS ] Please continue on reverse side –2– Product Identifier SECTION 5 — FIRE FIGHTING MEASURES Flammable SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES If yes, under which conditions? ❐ Yes –3– Product Identifier ❐ No Means of Extinction Physical State Odour and Appearance Solid Fine powder. NA Specific Gravity Vapour Density (air = 1) Vapour Pressure (mmHg) NA ND Flashpoint (°C) and Method Upper Flammable Limit (% by volume) Lower Flammable Limit (% by volume) Evaporation Rate Boiling Point (°C) Autoignition Temperature (°C) Explosion Data — Sensitivity to Impact Explosion Data — Sensitivity to Static Discharge pH ND Freezing Point (°C) NA NA ND Hazardous Combustion Products Odour Threshold (ppm) Coefficient of Water/Oil Distribution [Solubility in Water] SECTION 10 — STABILITY AND REACTIVITY [NFPA] Chemical Stability ❐ Yes If no, under which conditions? ❐x No Incompatibility with Other Substances SECTION 6 — ACCIDENTAL RELEASE MEASURES Exposure to heat may result in build up of dangerous pressure. Strong oxidizer, reacts violently upon contact of many organic substances, particularly paper and textile. If yes, which ones? x Yes ❐ ❐ No Strong acids, strong alkalies, oxidizers, organics. Leak and Spill Procedures Reactivity, and under what conditions? Moist, wet conditions. Fire. SECTION 7 — HANDLING AND STORAGE Hazardous Decomposition Products Handling Procedures and Equipment Ammonia, oxides of nitrogen and phosphorus, carbon monoxide, hydrogen cyanide, sulfur oxides (S0x), Including sulfur oxide and sulfur dioxide, oxides of magnesium. SECTION 11 — TOXICOLOGICAL INFORMATION Storage Requirements Effects of Acute Exposure Skin Contact - Irritation could occur with prolonged exposure to dry fertilizer or fertilizer solution. Contact with heated solution may cause thermal burns. Skin Absorption - Not known to be absorbed through the skin. Eye Contact - Irritation could occur if fertilizer solution is splashed in eyes or dry product contacts eyes. Heated material may cause thermal burns. Effects of Chronic Exposure Inhalation - Very low vapour activity. If heated could release ammonia gas. Can cause respiratory tract irritation. Ingestion - Excessive ingestion must occur before any health hazard results, effects of overexposure may include nausea, vomiting, diarrhea, weakness or convulsions. SECTION 8 — EXPOSURE CONTROL / PERSONAL PROTECTION Exposure Limits ❐ ACGIH TLV ❐ OSHA PEL ❐ Other (specify) Specific Engineering Controls (such as ventilation, enclosed process) Irritancy of Product Skin Sensitization Personal Protective Equipment ❐ Gloves ❐ Respirator ❐ Eye ❐ Footwear ❐ Clothing ❐ May cause minor irritation. Urea can cause allergic reaction in some individuals. May cause minor irritation. Carcinogenicity — IARC Other None known. Reproductive Toxicity If checked, please specify type None known. Embryotoxicity None known. Respiratory Sensitization Very low, if heated may cause irritation. Carcinogenicity — ACGIH None known. Teratogenicity None known. Mutagenicity None known. Name of Synergistic Products/Effects ND [ Optional, not required under WHMIS ] [ Optional, not required under WHMIS ] Please continue on reverse side SECTION 12 — ECOLOGICAL INFORMATION [Aquatic Toxicity] MATERIAL SAFETY DATA SHEET — 16 Sections –4– Product Identifier SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Prevent entry into waterways, sewers, basements or confined areas. Product Identifier The LC50/96 - hour values for fish are over 100mg/L [WHMIS Classification] Product Use SECTION 13 — DISPOSAL CONSIDERATIONS Manufacturer’s Name Supplier’s Name Street Address Street Address City Waste Disposal Province Postal Code Dispose of in non-crop areas away from waterways, in accordance with federal, provincial and local regulations. City Emergency Telephone Date MSDS Prepared Province Postal Code Emergency Telephone MSDS Prepared By Phone Number SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Ingredients (specific) SECTION 14 — TRANSPORT INFORMATION % CAS Number LD50 of Ingredient (specify species and route) LC50 of Ingredient (specify species) Special Shipping Information Not regulated by TDG. PIN TDG [DOT] [IMO] [ICAO] SECTION 15 — REGULATORY INFORMATION [WHMIS Classification] SECTION 3 — HAZARDS IDENTIFICATION [OSHA] Route of Entry [TSCA] [Emergency Overview] Class C Oxidizer [SERA] This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by CPR. ❐ Skin Contact ❐ Skin Absorption ❐ Eye Contact ❐ Inhalation ❐ Ingestion [WHMIS Symbols] [Potential Health Effects] SECTION 16 — OTHER INFORMATION NA = Not Applicable. ND = Not Determined. SECTION 4 — FIRST AID MEASURES Skin Contact Eye Contact Inhalation Ingestion SAMPLE FORMAT PROVIDED BY THE WORKERS’ COMPENSATION BOARD OF BRITISH COLUMBIA 57M6 (6/99) [ Optional, not required under WHMIS ] Please continue on reverse side [ Optional, not required under WHMIS ]
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